Sample records for disciplines chemical dynamics

  1. Site-Specific Raman Spectroscopy and Chemical Dynamics of Nanoscale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raman Spectroscopy and Chemical Dynamics of Nanoscale Interstitial Systems. Site-Specific Raman Spectroscopy and Chemical Dynamics of Nanoscale Interstitial Systems. Abstract:...

  2. Gas-phase chemical dynamics

    SciTech Connect (OSTI)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01T23:59:59.000Z

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  3. Chemical structure and dynamics: Annual report 1996

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1997-03-01T23:59:59.000Z

    The Chemical Structure and Dynamics (CS&D) program is a major component of the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of-the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for characterizing waste tanks and pollutant distributions, and for detecting and monitoring trace atmospheric species.

  4. Annual Report 2000. Chemical Structure and Dynamics

    SciTech Connect (OSTI)

    Colson, Steven D.; McDowell, Robin S.

    2001-04-15T23:59:59.000Z

    This annual report describes the research and accomplishments of the Chemical Structure and Dynamics Program in the year 2000, one of six research programs at the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) - a multidisciplinary, national scientific user facility and research organization. The Chemical Structure and Dynamics (CS&D) program is meeting the need for a fundamental, molecular-level understanding by 1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; 2) developing a multidisciplinary capability for describing interfacial chemical processes relevant to environmental chemistry; and 3) developing state-of-the-art research and analytical methods for characterizing complex materials of the types found in natural and contaminated systems.

  5. Chemical structure and dynamics. Annual report 1995

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1996-05-01T23:59:59.000Z

    The Chemical Structure and Dynamics program is a major component of Pacific Northwest National Laboratory`s Environmental Molecular Sciences Laboratory (EMSL), providing a state-of-the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for the characterization of waste tanks and pollutant distributions, and for detection and monitoring of trace atmospheric species.

  6. Chemical structure and dynamics: Annual report 1993

    SciTech Connect (OSTI)

    Colson, S.D.

    1994-07-01T23:59:59.000Z

    The Chemical Structure and Dynamics program responds to the need for a fundamental, molecular-level understanding of chemistry at the wide variety of environmentally-important interfaces. The research program is built around the established relationship between structure, thermodynamics, and kinetics. This research effort continues to evolve into a program of rigorous studies of fundamental molecular processes in model systems (e.g., well-characterized surfaces, single-component solutions, clusters, and biological molecules), and studies of complex systems found in the environment. Experimental studies of molecular and supramolecular structures and thermodynamics are key to understanding the nature of matter, and lead to direct comparison with computational results. Kinetic and mechanistic measurements, combined with real-time dynamics measurements of atomic and molecular motions during chemical reactions, provide for a molecular-level description of chemical reactions. The anticipated results of this work are the achievement of a quantitative understanding of chemical processes at complex interfaces, the development of new techniques for the detection and measurement of species at such interfaces, and the interpretation and extrapolation of the observations in terms of models of interfacial chemistry. The Chemical Structure and Dynamics research program includes five areas described in detail in this report: Reaction mechanisms at solid interfaces; Solution and solution interfaces; Structure and dynamics of biological systems; Analytical methods development; and atmospheric chemistry. Extended abstracts are presented for 23 studies.

  7. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluid Dynamics, January 1999 ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January 1999 cfdroadmap.pdf More Documents & Publications A Workshop to Identify...

  8. Chemical Structure and Dynamics annual report 1997

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1998-03-01T23:59:59.000Z

    The Chemical Structure and Dynamics (CS and D) program is a major component of the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of-the-art collaborative facility for studies of chemical structure and dynamics. The authors respond to the need for a fundamental, molecular level understanding of chemistry at a wide variety of environmentally important interfaces by: (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for characterizing complex materials of the types found in stored wastes and contaminated soils, and for detecting and monitoring trace atmospheric species. The focus of the research is defined primarily by DOE`s environmental problems: fate and transport of contaminants in the subsurface environment, processing and storage of waste materials, cellular effects of chemical and radiological insult, and atmospheric chemistry as it relates to air quality and global change. Twenty-seven projects are described under the following topical sections: Reaction mechanisms at interfaces; High-energy processes at environmental interfaces; Cluster models of the condensed phase; and Miscellaneous.

  9. Annual Report 1998: Chemical Structure and Dynamics

    SciTech Connect (OSTI)

    SD Colson; RS McDowell

    1999-05-10T23:59:59.000Z

    The Chemical Structure and Dynamics (CS&D) program is a major component of the William R. Wiley Environmental Molecular Sciences Labo- ratory (EMSL), developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of- the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interracial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in envi- ronmental chemistry and in nuclear waste proc- essing and storage; and (3) developing state-of- the-art analytical methods for characterizing com- plex materials of the types found in stored wastes and contaminated soils, and for detecting and monitoring trace atmospheric species. Our program aims at achieving a quantitative understanding of chemical reactions at interfaces and, more generally, in condensed media, compa- rable to that currently available for gas-phase reactions. This understanding will form the basis for the development of a priori theories for pre- dicting macroscopic chemical behavior in con- densed and heterogeneous media, which will add significantly to the value of field-scale envi- ronmental models, predictions of short- and long- term nuclear waste storage stabilities, and other areas related to the primary missions of the U.S. Department of Energy (DOE).

  10. Theoretical studies of chemical reaction dynamics

    SciTech Connect (OSTI)

    Schatz, G.C. [Argonne National Laboratory, IL (United States)

    1993-12-01T23:59:59.000Z

    This collaborative program with the Theoretical Chemistry Group at Argonne involves theoretical studies of gas phase chemical reactions and related energy transfer and photodissociation processes. Many of the reactions studied are of direct relevance to combustion; others are selected they provide important examples of special dynamical processes, or are of relevance to experimental measurements. Both classical trajectory and quantum reactive scattering methods are used for these studies, and the types of information determined range from thermal rate constants to state to state differential cross sections.

  11. SURFACE CHARACTERIZATION OF CHEMICALLY MODIFIED WOOD: DYNAMIC WETTABILITY1

    E-Print Network [OSTI]

    wetting slope and K value) were used to illustrate the dynamic wetting process. Dynamic contact angle the dynamic wettability of wood surfaces modified with different coupling agents. Keywords: Chemical articles on dynamic wetting process for wood adhesion have been published (Scheikl and Dunky 1998

  12. Quantum dynamics of fast chemical reactions

    SciTech Connect (OSTI)

    Light, J.C. [Univ. of Chicago, IL (United States)

    1993-12-01T23:59:59.000Z

    The aims of this research are to explore, develop, and apply theoretical methods for the evaluation of the dynamics of gas phase collision processes, primarily chemical reactions. The primary theoretical tools developed for this work have been quantum scattering theory, both in time dependent and time independent forms. Over the past several years, the authors have developed and applied methods for the direct quantum evaluation of thermal rate constants, applying these to the evaluation of the hydrogen isotopic exchange reactions, applied wave packet propagation techniques to the dissociation of Rydberg H{sub 3}, incorporated optical potentials into the evaluation of thermal rate constants, evaluated the use of optical potentials for state-to-state reaction probability evaluations, and, most recently, have developed quantum approaches for electronically non-adiabatic reactions which may be applied to simplify calculations of reactive, but electronically adiabatic systems. Evaluation of the thermal rate constants and the dissociation of H{sub 3} were reported last year, and have now been published.

  13. Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron

    SciTech Connect (OSTI)

    Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.

    2010-03-14T23:59:59.000Z

    Scientists at the Chemical Dynamics Beamline of the Advanced Light Source in Berkeley are continuously reinventing synchrotron investigations of physical chemistry and chemical physics with vacuum ultraviolet light. One of the unique aspects of a synchrotron for chemical physics research is the widely tunable vacuum ultraviolet light that permits threshold ionization of large molecules with minimal fragmentation. This provides novel opportunities to assess molecular energetics and reaction mechanisms, even beyond simple gas phase molecules. In this perspective, significant new directions utilizing the capabilities at the Chemical Dynamics Beamline are presented, along with an outlook for future synchrotron and free electron laser science in chemical dynamics. Among the established and emerging fields of investigations are cluster and biological molecule spectroscopy and structure, combustion flame chemistry mechanisms, radical kinetics and product isomer dynamics, aerosol heterogeneous chemistry, planetary and interstellar chemistry, and secondary neutral ion-beam desorption imaging of biological matter and materials chemistry.

  14. Analyzing the Dynamics of Chemical Networking Protocols

    E-Print Network [OSTI]

    Vetter, Thomas

    from several well-established fields, such as model linearization proposed in Metabolic Control congestion control protocol and highlight formerly unknown protocol features. Keywords: dynamic analysis;1 Introduction Predicting and controlling the dynamics of communication protocols are difficult but important

  15. Chemical Dynamics at Metal Surfaces: The Role of Electronic Excitation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Dynamics at Metal Surfaces: The Role of Electronic Excitations Mar 06 2015 11:00 AM - 12:00 PM John Tully, Yale University, New Haven, Connecticut Joint Institute for...

  16. Designing a service science discipline with discipline

    E-Print Network [OSTI]

    Glushko, Robert J.

    in what IBM began to call, in late 2004, service science, management and engineering--or simply SSME. 3 in information and computing technol- ogy, industrial engineering, business strategy, eco- nomics, lawDesigning a service science discipline with discipline & R. J. Glushko This paper relates our

  17. THE JOURNAL OF CHEMICAL PHYSICS 139, 175101 (2013) Dynamic neutron scattering from conformational dynamics. I. Theory

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    #12;THE JOURNAL OF CHEMICAL PHYSICS 139, 175101 (2013) Dynamic neutron scattering from, a conformational dynamics theory of dynamical neutron and X-ray scattering is developed, follow- ing our previous spectroscopy (dynamic neutron scattering) probes time correlations on the sub pico- to microsec- ond timescales

  18. Fluid dynamic issues in continuous wave short wavelength chemical lasers

    SciTech Connect (OSTI)

    Mikatarian, R.R.; Jumper, E.J.; Woolhiser, C.

    1988-01-01T23:59:59.000Z

    This paper addresses fluid dynamic issues of concern in the design and development of Continuous Wave (CW) Short Wavelength Chemical Lasers (SWCLs). Short Wavelength Chemical Laser technology is in its research stage and SWCL concepts are in their evolving mode. Researchers are presently addressing candidate chemical systems and activation concepts. Since these lasers will be flowing systems, it is necessary to discuss both the probable fluid dynamics issues, because of the inherent complexities fluid dynamicist can support this activity. In addition to addressing the SWCL fluid dynamic issues, this paper will review past fluid dynamic activities in high energy lasers and discuss additional research still required. This paper will also address the various levels of fluid dynamic modeling and how these models can be applied in studying the fluid dynamics of Short Wavelength Chemical Lasers. Where it is felt that specific fluid methodologies are not available, but are required in order to conduct specific analyses, they will be defined. 34 refs., 6 figs., 1 tab.

  19. Chemical dynamics in the gas phase: Time-dependent quantum mechanics of chemical reactions

    SciTech Connect (OSTI)

    Gray, S.K. [Argonne National Laboratory, IL (United States)

    1993-12-01T23:59:59.000Z

    A major goal of this research is to obtain an understanding of the molecular reaction dynamics of three and four atom chemical reactions using numerically accurate quantum dynamics. This work involves: (i) the development and/or improvement of accurate quantum mechanical methods for the calculation and analysis of the properties of chemical reactions (e.g., rate constants and product distributions), and (ii) the determination of accurate dynamical results for selected chemical systems, which allow one to compare directly with experiment, determine the reliability of the underlying potential energy surfaces, and test the validity of approximate theories. This research emphasizes the use of recently developed time-dependent quantum mechanical methods, i.e. wave packet methods.

  20. Administering Workforce Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-10-27T23:59:59.000Z

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  1. Gas-Phase Molecular Dynamics: Theoretical Studies In Spectroscopy and Chemical Dynamics

    SciTech Connect (OSTI)

    Yu H. G.; Muckerman, J.T.

    2012-05-29T23:59:59.000Z

    The main goal of this program is the development and application of computational methods for studying chemical reaction dynamics and molecular spectroscopy in the gas phase. We are interested in developing rigorous quantum dynamics algorithms for small polyatomic systems and in implementing approximate approaches for complex ones. Particular focus is on the dynamics and kinetics of chemical reactions and on the rovibrational spectra of species involved in combustion processes. This research also explores the potential energy surfaces of these systems of interest using state-of-the-art quantum chemistry methods, and extends them to understand some important properties of materials in condensed phases and interstellar medium as well as in combustion environments.

  2. Solid-State Halogen Atom Source for Chemical Dynamics and Etching...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Halogen Atom Source for Chemical Dynamics and Etching. Solid-State Halogen Atom Source for Chemical Dynamics and Etching. Abstract: We describe a solid state Br atom source for...

  3. Magnetic Sensitivity and Entanglement Dynamics of the Chemical Compass

    E-Print Network [OSTI]

    I. K. Kominis

    2012-07-25T23:59:59.000Z

    We present the quantum limits to the magnetic sensitivity of a new kind of magnetometer based on biochemical reactions. Radical-ion-pair reactions, the biochemical system underlying the chemical compass, are shown to offer a new and unique physical realization of a magnetic field sensor competitive to modern atomic or condensed matter magnetometers. We elaborate on the quantum coherence and entanglement dynamics of this sensor, showing that they provide the physical basis for testing our understanding of the fundamental quantum dynamics of radical-ion-pair reactions.

  4. Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1983-03-23T23:59:59.000Z

    The order provides guidance and procedures and states responsibilities for maintaining work force discipline in DOE. Chg 1, dated 3-11-85; Chg 2, dated 1-6-86; Chg 3, dated 3-21-89; Chg 4, dated 8-2-90; Chg 5, dated 3-9-92; Chg 6, dated 8-21-92, cancels Chg 5.

  5. Analysis of forward and inverse problems in chemical dynamics and spectroscopy

    SciTech Connect (OSTI)

    Rabitz, H. [Princeton Univ., NJ (United States)

    1993-12-01T23:59:59.000Z

    The overall scope of this research concerns the development and application of forward and inverse analysis tools for problems in chemical dynamics and chemical kinetics. The chemical dynamics work is specifically associated with relating features in potential surfaces and resultant dynamical behavior. The analogous inverse research aims to provide stable algorithms for extracting potential surfaces from laboratory data. In the case of chemical kinetics, the focus is on the development of systematic means to reduce the complexity of chemical kinetic models. Recent progress in these directions is summarized below.

  6. A Case Study of Chemical Organization Theory Applied to Virus Dynamics

    E-Print Network [OSTI]

    Dittrich, Peter

    A Case Study of Chemical Organization Theory Applied to Virus Dynamics Naoki Matsumaru1 , Pietro, Venezia, Italia * corresponding author Abstract. Chemical organization theory has been proposed to provide and Horn [10]. Here, we introduce chemical organization theory [11, 12] as another method to analyse

  7. Toward Structural Dynamics: Protein Motions Viewed by Chemical Shift Modulations and Direct Detection of CN

    E-Print Network [OSTI]

    Toward Structural Dynamics: Protein Motions Viewed by Chemical Shift Modulations and Direct of anti-correlated fluctuations) in R-helices. This extends the prospects of structure- dynamics, several groups have proposed to investigate the existence of structure-dynamics relationships. We like

  8. Regulation 2: Student Discipline REGULATION 2: STUDENT DISCIPLINE

    E-Print Network [OSTI]

    Sussex, University of

    Regulation 2: Student Discipline 6 REGULATION 2: STUDENT DISCIPLINE 1. Definitions In this Regulation: The University means the University of Sussex. Council means Council of the University. Senate to the regulations of the affiliated institution, and excluding students in attendance at the Brighton and Sussex

  9. Dynamics of excitation pulses with attractive interaction: Kinematic analysis and chemical wave experiments

    E-Print Network [OSTI]

    Steinbock, Oliver

    Dynamics of excitation pulses with attractive interaction: Kinematic analysis and chemical wave present a theoretical analysis of stacking and destacking wave trains in excitable reaction-diffusion systems with anomalous velocity-wavelength dependence. For linearized dispersion relations, kinematic

  10. FLUID DYNAMICAL AND MODELING ISSUES OF CHEMICAL FLOODING FOR ENHANCED OIL RECOVERY

    E-Print Network [OSTI]

    Daripa, Prabir

    FLUID DYNAMICAL AND MODELING ISSUES OF CHEMICAL FLOODING FOR ENHANCED OIL RECOVERY Prabir Daripa developed flows in enhanced oil recovery (EOR). In a recent exhaustive study [Transport in Porous Media, 93 fluid flows that occur in porous media during tertiary dis- placement process of chemical enhanced oil

  11. Electronic processes in fast thermite chemical reactions: A first-principles molecular dynamics study

    E-Print Network [OSTI]

    Southern California, University of

    Electronic processes in fast thermite chemical reactions: A first-principles molecular dynamics composites. We have investigated the thermite reaction of Fe2O3 with aluminum by molecular dynamics as thermite reaction, is widely utilized in the synthesis and processing of materials 1 . In addition

  12. Chemical and Dynamical Characteristics of Stratosphere-Troposphere Exchange

    E-Print Network [OSTI]

    Homeyer, Cameron Ross

    2012-10-19T23:59:59.000Z

    -resolution model analyses and backward trajectory calculations. In situ chemical observations of the tropospheric intrusions are used to estimate the mixing timescales of the observed intrusions through use of a simple box model and trace species with different...

  13. Technical Report TR-013 March 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-013 Hydrology March 2001 Roberts Creek Study Forest: Pre-harvest chemical characteristics of three S6 creeks-751-7001 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  14. Computational fluid dynamic simulations of chemical looping fuel reactors utilizing gaseous fuels

    SciTech Connect (OSTI)

    Mahalatkar, K.; Kuhlman, J.; Huckaby, E.D.; O'Brien, T.

    2011-01-01T23:59:59.000Z

    A computational fluid dynamic(CFD) model for the fuel reactor of chemical looping combustion technology has been developed,withspecialfocusonaccuratelyrepresentingtheheterogeneous chemicalreactions.Acontinuumtwo-fluidmodelwasusedtodescribeboththegasandsolidphases. Detailedsub-modelstoaccountforfluidĖparticleandparticleĖparticleinteractionforceswerealso incorporated.Twoexperimentalcaseswereanalyzedinthisstudy(Son andKim,2006; Mattisonetal., 2001). SimulationswerecarriedouttotestthecapabilityoftheCFDmodeltocapturechangesinoutletgas concentrationswithchangesinnumberofparameterssuchassuperficialvelocity,metaloxide concentration,reactortemperature,etc.Fortheexperimentsof Mattissonetal.(2001), detailedtime varyingoutletconcentrationvalueswerecompared,anditwasfoundthatCFDsimulationsprovideda reasonablematchwiththisdata.

  15. Are We Closing the School Discipline Gap?

    E-Print Network [OSTI]

    Losen, Daniel; Hodson, Cheri; Keith II, Michael A; Morrison, Katrina; Belway, Shakti

    2015-01-01T23:59:59.000Z

    D.J. , (Ed). Closing the School Discipline Gap: EquitableBooth, E.A. (2011). Breaking schoolsí rules: A statewidestudy of how school discipline relates to studentsí success

  16. ORIGIN OF CHEMICAL AND DYNAMICAL PROPERTIES OF THE GALACTIC THICK DISK

    SciTech Connect (OSTI)

    Bekki, Kenji [ICRAR, M468, University of Western Australia, Crawley, Western Australia, 6009 (Australia); Tsujimoto, Takuji [National Astronomical Observatory, Mitaka-shi, Tokyo 181-8588 (Japan)

    2011-09-01T23:59:59.000Z

    We adopt a scenario in which the Galactic thick disk was formed by minor merging between the first generation of the Galactic thin disk (FGTD) and a dwarf galaxy about {approx}9 Gyr ago and thereby investigate chemical and dynamical properties of the Galactic thick disk. In this scenario, the dynamical properties of the thick disk have long been influenced both by the mass growth of the second generation of the Galactic thin disk (i.e., the present thin disk) and by its non-axisymmetric structures. On the other hand, the early star formation history and chemical evolution of the thin disk was influenced by the remaining gas of the thick disk. Based on N-body simulations and chemical evolution models, we investigate the radial metallicity gradient, structural and kinematical properties, and detailed chemical abundance patterns of the thick disk. Our numerical simulations show that the ancient minor merger event can significantly flatten the original radial metallicity gradient of the FGTD, in particular, in the outer part, and also can be responsible for migration of inner metal-rich stars into the outer part (R > 10 kpc). The simulations show that the central region of the thick disk can develop a bar due to dynamical effects of a separate bar in the thin disk. Whether or not rotational velocities (V{sub {phi}}) can correlate with metallicities ([Fe/H]) for the simulated thick disks depends on the initial metallicity gradients of the FGTDs. The simulated orbital eccentricity distributions in the thick disk for models with higher mass ratios ({approx}0.2) and lower orbital eccentricities ({approx}0.5) of minor mergers are in good agreement with the corresponding observations. The simulated V{sub {phi}}-|z| relation of the thick disk in models with low orbital inclination angles of mergers are also in good agreement with the latest observational results. The vertical metallicity gradient of the simulated thick disk is rather flat or very weakly negative in the solar neighborhood. Our Galactic chemical evolution models show that if we choose two distinctive timescales for star formation in the thin and thick disks, then the models can explain both the observed metallicity distribution functions and correlations between [Mg/Fe] and [Fe/H] for the two disks in a self-consistent manner. We discuss how the early star formation history and chemical evolution of the Galactic thin disk can be influenced by the pre-existing thick disk.

  17. NERSC HPSS Storage by Scientific Discipline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage by Scientific Discipline Troubleshooting IO Resources for Scientific Applications at NERSC Optimizing IO performance on the Lustre file system IO Formats Science...

  18. Interrogation and control of condensed phase chemical dynamics with linearly chirped pulses: I2 in solid Kr

    E-Print Network [OSTI]

    Apkarian, V. Ara

    Interrogation and control of condensed phase chemical dynamics with linearly chirped pulses: I2, Irvine, California 92717 Received 19 October 1995; accepted 30 January 1996 The effect of linearly pulse chirp, is a measure of the controllability of the evolving dynamics. In the particular case

  19. The Puzzle of Discipline: An Examination of African American Disproportionality in School Discipline and Student Performance

    E-Print Network [OSTI]

    Butler, Bettie Ray

    2012-07-16T23:59:59.000Z

    The intent of this study was to systematically investigate the relationship between African American disproportionality in school discipline which is the overrepresentation of students for exclusionary discipline practices (i.e., out-of-school...

  20. Live Cell Chemical Profiling of Temporal Redox Dynamics in a Photoautotrophic Cyanobacterium

    SciTech Connect (OSTI)

    Sadler, Natalie C.; Melnicki, Matthew R.; Serres, Margrethe H.; Merkley, Eric D.; Chrisler, William B.; Hill, Eric A.; Romine, Margaret F.; Kim, Sangtae; Zink, Erika M.; Datta, Suchitra; Smith, Richard D.; Beliaev, Alex S.; Konopka, Allan; Wright, Aaron T.

    2014-01-01T23:59:59.000Z

    Protein reduction-oxidation (redox) modification is an important mechanism that allows microorganisms to sense environmental changes and initiate cellular responses. We have developed a quantitative chemical probe approach for live cell labeling of proteins that are sensitive to redox modifications. We utilize this in vivo strategy to identify 176 proteins undergoing ~5-10 fold dynamic redox change in response to nutrient limitation and subsequent replenishment in the photoautotrophic cyanobacterium, Synechococcus sp. PCC 7002. We detect redox changes in as little as 30 seconds after nutrient perturbation, and oscillations in reduction and oxidation for 60 minutes following the perturbation. Many of the proteins undergoing dynamic redox transformations participate in the major components for the production (photosystems and electron transport chains) or consumption (Calvin-Benson cycle and protein synthesis) of reductant and/or energy in photosynthetic organisms. Thus, our in vivo approach reveals new redox-susceptible proteins, in addition to validating those previously identified in vitro.

  1. Software Engineering, an established Accreditable Engineering Discipline

    E-Print Network [OSTI]

    Szabados, Barna

    Software Engineering, an established Accreditable Engineering Discipline By B.Szabados, P.Eng, Mc of the Canadian Engineering Accreditation Board (CEAB), as well as at a workshop at the NCDEAS meeting in September 1997. 1. INTRODUCTION In the late seventies, the discipline of Computer Engineering has evolved

  2. An infrared free-electron laser for the Chemical Dynamics Research Laboratory

    SciTech Connect (OSTI)

    Vaughan, D. (comp.)

    1992-04-01T23:59:59.000Z

    This document describes a free-electron laser (FEL) proposed as part of the Chemical Dynamics Research Laboratory (CDRL), a user facility that also incorporates several advanced lasers of conventional design and two beamlines for the ALS. The FEL itself addresses the needs of the chemical sciences community for a high-brightness, tunable source covering a broad region of the infrared spectrum -- from 3 to 50 {mu}m. All of these sources, together with a variety of sophisticated experimental stations, will be housed in a new building to be located adjacent to the ALS. The radiation sources can be synchronized to permit powerful two-color, pump-probe experiments that will further our fundamental understanding of chemical dynamics at the molecular level, especially those aspects relevant to practical issues in combustion chemistry. The technical approach adopted in this design makes use of superconducting radiofrequency (SCRF) accelerating structures. The primary motivation for adopting this approach was to meet the user requirement for wavelength stability equal to one part in 10{sup 4}. Previous studies concluded that a wavelength stability of only one part in 10{sup 3} could be achieved with currently available room-temperature technology. In addition, the superconducting design operates in a continuous-wave (cw) mode and hence offers considerably higher average optical output power. It also allows for various pulse-gating configurations that will permit simultaneous multiuser operations. A summary of the comparative performance attainable with room-temperature and superconducting designs is given. The FEL described in this report provides a continuous train of 30-ps micropulses, with 100{mu}J of optical energy per micropulse, at a repetition rate of 6.1 MHz. The device can also deliver pulses at a cw repetition rate of 12.2 MHz, with a peak power of 50 {mu}J per micropulse. 70 ref.

  3. An infrared free-electron laser for the Chemical Dynamics Research Laboratory. Design report

    SciTech Connect (OSTI)

    Vaughan, D. [comp.

    1992-04-01T23:59:59.000Z

    This document describes a free-electron laser (FEL) proposed as part of the Chemical Dynamics Research Laboratory (CDRL), a user facility that also incorporates several advanced lasers of conventional design and two beamlines for the ALS. The FEL itself addresses the needs of the chemical sciences community for a high-brightness, tunable source covering a broad region of the infrared spectrum -- from 3 to 50 {mu}m. All of these sources, together with a variety of sophisticated experimental stations, will be housed in a new building to be located adjacent to the ALS. The radiation sources can be synchronized to permit powerful two-color, pump-probe experiments that will further our fundamental understanding of chemical dynamics at the molecular level, especially those aspects relevant to practical issues in combustion chemistry. The technical approach adopted in this design makes use of superconducting radiofrequency (SCRF) accelerating structures. The primary motivation for adopting this approach was to meet the user requirement for wavelength stability equal to one part in 10{sup 4}. Previous studies concluded that a wavelength stability of only one part in 10{sup 3} could be achieved with currently available room-temperature technology. In addition, the superconducting design operates in a continuous-wave (cw) mode and hence offers considerably higher average optical output power. It also allows for various pulse-gating configurations that will permit simultaneous multiuser operations. A summary of the comparative performance attainable with room-temperature and superconducting designs is given. The FEL described in this report provides a continuous train of 30-ps micropulses, with 100{mu}J of optical energy per micropulse, at a repetition rate of 6.1 MHz. The device can also deliver pulses at a cw repetition rate of 12.2 MHz, with a peak power of 50 {mu}J per micropulse. 70 ref.

  4. THE JOURNAL OF CHEMICAL PHYSICS 138, 244310 (2013) Molecular dynamics simulations for CO2 spectra. IV. Collisional line-mixing

    E-Print Network [OSTI]

    Boyer, Edmond

    2013-01-01T23:59:59.000Z

    atmosphere of Venus (about 96.5% of CO2) where the pressure is high (up to 90 bar). Similarly, narrow involving CO2 with a few for the pure gas in the infrared at high pressure12≠17 and Raman Q branches.4THE JOURNAL OF CHEMICAL PHYSICS 138, 244310 (2013) Molecular dynamics simulations for CO2 spectra

  5. STATE OF THE DISCIPLINE POVERTY, RACE, AND

    E-Print Network [OSTI]

    Shyy, Wei

    STATE OF THE DISCIPLINE POVERTY, RACE, AND ANTIPOVERTY POLICY BEFORE AND AFTER HURRICANE KATRINA1 response toward those affected, it did not lead to a serious discourse about the nature of poverty earnings are lower and poverty rates are higher for African Americans than for Whites, the economic

  6. Behaviors That Result in Employee Discipline

    E-Print Network [OSTI]

    Oliver, Douglas L.

    would much rather you be productive and happy on the job. Most employers have resources to help is not punishment. The goal of discipline is to deter a re- peat of the performance problem (quality of work your concerns confidentially with an employee assistance professional can help. Human resources is also

  7. DISCIPLINE OF RADIATION THERAPY SAFETY DOCUMENT

    E-Print Network [OSTI]

    O'Mahony, Donal E.

    DISCIPLINE OF RADIATION THERAPY SAFETY DOCUMENT Contents Page 1. Health & Safety arrangements 1 Inspection 1.4 Hazard Reporting 1.5 Security in College 1.6 Out of Hours Working 1.7 Management of Work.7 Management of Work-related Stress Those experiencing symptoms of work-related stress should raise this matter

  8. ChemicalPhysicsLetters270 (1997) 476-483 Electrostatics by Brownian dynamics

    E-Print Network [OSTI]

    Agmon, Noam

    ELSEVIER 30May 1997 ChemicalPhysicsLetters270 (1997) 476-483 CHEMICAL PHYSICS LETTERS, Jerusalem 91904, Israel Received26 December1996;in finalform31 March1997 Abstract The isomorphism between is demonstrated in simple illustrative calculations. © 1997 Elsevier Science B.V. 1. Introduction Electrostatic

  9. DISCIPLINE AND TERMINATION POLICY Employees covered by this policy

    E-Print Network [OSTI]

    DISCIPLINE AND TERMINATION POLICY Employees covered by this policy This policy applies to all non to discipline, suspend with or without pay, or terminate employees for just cause. Just cause includes to discipline or termination for just cause, the University reserves the right to demote, suspend or terminate

  10. Computational fluid dynamics modeling of chemical looping combustion process with calcium sulphate oxygen carrier - article no. A19

    SciTech Connect (OSTI)

    Baosheng Jin; Rui Xiao; Zhongyi Deng; Qilei Song [Southeast University (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

    2009-07-01T23:59:59.000Z

    To concentrate CO{sub 2} in combustion processes by efficient and energy-saving ways is a first and very important step for its sequestration. Chemical looping combustion (CLC) could easily achieve this goal. A chemical-looping combustion system consists of a fuel reactor and an air reactor. Two reactors in the form of interconnected fluidized beds are used in the process: (1) a fuel reactor where the oxygen carrier is reduced by reaction with the fuel, and (2) an air reactor where the reduced oxygen carrier from the fuel reactor is oxidized with air. The outlet gas from the fuel reactor consists of CO{sub 2} and H{sub 2}O, while the outlet gas stream from the air reactor contains only N{sub 2} and some unused O{sub 2}. The water in combustion products can be easily removed by condensation and pure carbon dioxide is obtained without any loss of energy for separation. Until now, there is little literature about mathematical modeling of chemical-looping combustion using the computational fluid dynamics (CFD) approach. In this work, the reaction kinetic model of the fuel reactor (CaSO{sub 4}+ H{sub 2}) is developed by means of the commercial code FLUENT and the effects of partial pressure of H{sub 2} (concentration of H{sub 2}) on chemical looping combustion performance are also studied. The results show that the concentration of H{sub 2} could enhance the CLC performance.

  11. Quantitative Determination of Chemical Processes by Dynamic Nuclear Polarization Enhanced Nuclear Magnetic Resonance Spectroscopy

    E-Print Network [OSTI]

    Zeng, Haifeng

    2012-07-16T23:59:59.000Z

    . The binding of fluorinated ligands to the protease trypsin was studied through the observation of various NMR parameter changes, such as line width, signal intensity and chemical shift of the ligands. Intermolecular polarization transfer from hyperpolarized...

  12. Master of Engineering (ME), Major: Chemical Engineering

    E-Print Network [OSTI]

    Shihadeh, Alan

    Master of Engineering (ME), Major: Chemical Engineering Apply Now The Chemical Engineering Program to the following degrees: Master of Engineering, major Chemical Engineering The ME program will be open to students with a Bachelor of Engineering (BE) in Chemical Engineering, or other related disciplines

  13. Quantitative Determination of Chemical Processes by Dynamic Nuclear Polarization Enhanced Nuclear Magnetic Resonance Spectroscopy†

    E-Print Network [OSTI]

    Zeng, Haifeng

    2012-07-16T23:59:59.000Z

    Dissolution dynamic nuclear polarization (DNP) provides several orders of magnitude of NMR signal enhancement by converting the much larger electron spin polarization to nuclear spin polarization. Polarization occurs at ...

  14. Development and application of chemical tools for investigating dynamic processes in cell migration

    E-Print Network [OSTI]

    Goguen, Brenda Nicole

    2011-01-01T23:59:59.000Z

    Cell migration is a dynamic process essential for many fundamental physiological functions, including wound repair and the immune response. Migration relies on precisely orchestrated events that are regulated in a spatially ...

  15. >> engineering.wustl.edu Across Disciplines.

    E-Print Network [OSTI]

    Subramanian, Venkat

    : >> Alternative energy, environmental engineering and sustainable technology >> Biotechnology >> Imaging Science & Engineering >> Electrical & Systems Engineering >> Energy, Environmental & Chemical Engineering in the fields of biotechnology and plant science. #12;

  16. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology and imple- #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  17. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Combined Snowpack and

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture, BCMOF 1 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  18. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  19. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  20. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note

  1. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Assessing Habitat Quality of

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  2. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Relationships between Elevation and Slope

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  3. The VENUS/NWChem Software Package. Tight Coupling Between Chemical Dynamics Simulations and Electronic Structure Theory

    SciTech Connect (OSTI)

    Lourderaj, Upakarasamy; Sun, Rui; De Jong, Wibe A.; Windus, Theresa L.; Hase, William L.

    2014-03-01T23:59:59.000Z

    The interface for VENUS and NWChem, and the resulting software package for direct dynamics simulations are described. The coupling of the two codes is considered to be a tight coupling. The two codes are compiled and linked together and act as one executable with data being passed between the two codes through routine calls. The advantages of this type of coupling are discussed. The interface has been designed to have as little interference as possible with the core codes of both VENUS and NWChem. VENUS is the code that propagates the direct dynamics trajectories and, therefore, is the program that drives the overall execution of VENUS/NWChem. VENUS has remained an essentially sequential code, which uses the highly parallel structure of NWChem. Subroutines of the interface which accomplish the data transmission and communication between the two computer programs are described. Recent examples of the use of VENUS/NWChem for direct dynamics simulations are summarized.

  4. Physically and chemically stable ionic liquid-infused textured surfaces showing excellent dynamic omniphobicity

    SciTech Connect (OSTI)

    Miranda, Daniel F.; Urata, Chihiro; Masheder, Benjamin; Dunderdale, Gary J.; Hozumi, Atsushi, E-mail: a.hozumi@aist.go.jp [National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Anagahora, Shimo-Shidami, Moriyama-ku, Nagoya, Aichi 463-8560 (Japan); Yagihashi, Makoto [Nagoya Municipal Industrial Research Institute, Rokuban, Atsuta-ku, Nagoya 456-0058 (Japan)

    2014-05-01T23:59:59.000Z

    A fluorinated and hydrophobic ionic liquid (IL), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, effectively served as an advantageous lubricating liquid for the preparation of physically and chemically stable omniphobic surfaces based on slippery liquid-infused porous surfaces. Here, we used particulate microstructures as supports, prepared by the chemical vapor deposition of 1,3,5,7-tetramethylcyclotetrasiloxane and subsequent surface modification with (3-aminopropyl)triethoxysilane. Confirmed by SEM and contact angle measurements, the resulting IL-infused microtextured surfaces are smooth and not only water but also various low surface tension liquids can easily slide off at low substrate tilt angles of <5į, even after exposure to high temperature, vacuum, and UV irradiation.

  5. fll INTRODUCTION Solid mechanics is a fundamental discipline which, in

    E-Print Network [OSTI]

    generation technologies such as fusion, nuclear and gas turbine power, aerospace and surface trans- nortation, solid mechanics is a central discipline for hydrocarbon resource extraction by drilling, hydraulic

  6. DRAFT - DOE O 333.1, Administering Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  7. Modeling particle formation during low-pressure silane oxidation: Detailed chemical kinetics and aerosol dynamics

    E-Print Network [OSTI]

    Zachariah, Michael R.

    that the generation of SiOHx species from fast gas- phase reactions can significantly degrade film quality. Based conservation equations and a moment-type aerosol dynamics model were formulated for a batch reactor undergoing to impurity diffusion.1 During LPCVD film deposition rates are limited by the gas-phase nucleation

  8. REPRESENTING AEROSOL DYNAMICS AND PROPERTIES IN CHEMICAL TRANSPORT MODELS BY THE METHOD OF MOMENTS.

    SciTech Connect (OSTI)

    SCHWARTZ,S.E.; MCGRAW,R.; BENKOVITZ,C.M.; WRIGHT,D.L.

    2001-04-01T23:59:59.000Z

    Atmospheric aerosols, suspensions of solid or liquid particles, are an important multi-phase system. Aerosols scatter and absorb shortwave (solar) radiation, affecting climate (Charlson et al., 1992; Schwartz, 1996) and visibility; nucleate cloud droplet formation, modifying the reflectivity of clouds (Twomey et al., 1984; Schwartz and Slingo, 1996) as well as contributing to composition of cloudwater and to wet deposition (Seinfeld and Pandis, 1998); and affect human health through inhalation (NRC, 1998). Existing and prospective air quality regulations impose standards on concentrations of atmospheric aerosols to protect human health and welfare (EPA, 1998). Chemical transport and transformation models representing the loading and geographical distribution of aerosols and precursor gases are needed to permit development of effective and efficient strategies for meeting air quality standards, and for examining aerosol effects on climate retrospectively and prospectively for different emissions scenarios. Important aerosol properties and processes depend on their size distribution: light scattering, cloud nucleating properties, dry deposition, and penetration into airways of lungs. The evolution of the mass loading itself depends on particle size because of the size dependence of growth and removal processes. For these reasons it is increasingly recognized that chemical transport and transformation models must represent not just the mass loading of atmospheric particulate matter but also the aerosol microphysical properties and the evolution of these properties if aerosols are to be accurately represented in these models. If the size distribution of the aerosol is known, a given property can be evaluated as the integral of the appropriate kernel function over the size distribution. This has motivated the approach of determining aerosol size distribution, and of explicitly representing this distribution and its evolution in chemical transport models.

  9. The Development of Dynamic Operational Risk Assessment in Oil/Gas and Chemical Industries

    E-Print Network [OSTI]

    Yang, Xiaole

    2011-08-08T23:59:59.000Z

    by regulations for the use and execution of risk analysis in 1991[16]. QRA became an official requirement for offshore after the Piper Alpha platform disaster that took place in 1988. Lord Cullen in his report recommended QRA as a technique to provide a... than 500,000 people to MIC and other chemicals. It killed at least 3,800 people and caused significant morbidity and premature death for many thousands more. An explosion and resulting fire in the Piper Alpha disaster[4] destroyed the oil production...

  10. Cycle time variability for a network under two queueing disciplines

    E-Print Network [OSTI]

    Vasquez Pariente, Marta Irene

    1996-01-01T23:59:59.000Z

    A network of three single-server queues is investigated. Performance of two queueing disciplines is compared on the basis of the mean and variance of the network cycle time. The two queueing disciplines are first-in-system first-out (FISFO...

  11. Dynamic behavior of chemical exchange column in a water detritiation system for a fusion reactor

    SciTech Connect (OSTI)

    Yamanishi, T.; Iwai, Y. [Tritium Engineering Group, JAEA, Tokai, Ibaraki, 319-1195 (Japan)

    2008-07-15T23:59:59.000Z

    The dynamic behavior of a CECE column used for a demonstration reactor (DEMO) plant has been studied. In the case where the column was filled with natural water, the time required to achieve steady state was almost the same as that for the column operated under the total reflux mode. The manipulated variables were flow rate of the bottom stream for the control of the bottom tritium concentration, and flow rate of the hydrogen stream for the control of the top tritium concentration. For both the variables, the response curve was expressed by the first-order lag system, and a PID controller could be applied. (authors)

  12. Quantum Chemical Analysis of the Excited State Dynamics of Hydrated Electrons

    E-Print Network [OSTI]

    P. O. J. Scherer; Sighart F. Fischer

    2006-02-01T23:59:59.000Z

    Quantum calculations are performed for an anion water cluster representing the first hydration shell of the solvated electron in solution. The absorption spectra from the ground state, the instant excited states and the relaxed excited states are calculated including CI-SD interactions. Analytic expressions for the nonadiabatic relaxation are presented. It is shown that the 50fs dynamics recently observed after s->p excitation is best accounted for if it is identified with the internal conversion, preceded by an adiabatic relaxation within the excited p state. In addition, transient absorptions found in the infrared are qualitatively reproduced by these calculations .

  13. High-explosive properties from classical molecular dynamics simulations and quantum-chemical computations

    SciTech Connect (OSTI)

    Sewell, T. D. (Thomas D.); Gan, C. K. (Chee Kwan); Jaramillo, E. (Eugenio); Strachan, A. H. (Alejandro H.)

    2004-01-01T23:59:59.000Z

    We are using classical molecular dynamics and condensed phase electronic-structure methods to predict some of the thermophysical and mechanical properties that are needed as input to realistic mesoscale models for plastic-bonded explosives. The main materials studied to date are HMX, PETN, Estane copolymer, and bi(2,2-dinitropropyl) formal/acetal (BDNPF/A). Emphasis is placed on non-reactive properties and thermodynamic states relevant to cookoff and shock initiation phenomena. Both crystal and liquid-state properties are of interest. Typical simulation sizes and times are {approx}10{sup 2} molecules and 2-10 ns, respectively. The overarching goal is to develop internally consistent model thermodynamic and elastic mechanical descriptions for the materials. Prioritization among the set of properties amenable to atomistic simulation is made based on ongoing interactions with mesoscale modelers at Los Alamos and elsewhere. Recent work will be summarized and our view of profitable directions for future research will be discussed, including preliminary results for large-scale molecular dynamics simulations of shock response of crystalline HMX.

  14. An infrared free electron laser system for the proposed Chemical Dynamics Research Laboratory at LBL based on a 500 MHz superconducting linac

    SciTech Connect (OSTI)

    Kim, K.J.; Byrns, R.; Chattopadhyay, S.; Donahue, R.; Edighoffer, J.; Gough, R.; Hoyer, E.; Leemans, W.; Staples, J.; Taylor, B.; Xie, M.

    1992-09-01T23:59:59.000Z

    We describe a new design of the Infrared Free Electron Laser (IRFEL) for the proposed Chemical Dynamics Research Laboratory (CDRL) at LBL. The design and choice of parameters are dictated by the unique requirements of the CDRL scientific program. The accelerator system is based on the 500 MHz superconducting cavity technology to achieve a wavelength stability of 10{sup {minus}4}.

  15. An infrared free electron laser system for the proposed Chemical Dynamics Research Laboratory at LBL based on a 500 MHz superconducting linac

    SciTech Connect (OSTI)

    Kim, K.J.; Byrns, R.; Chattopadhyay, S.; Donahue, R.; Edighoffer, J.; Gough, R.; Hoyer, E.; Leemans, W.; Staples, J.; Taylor, B.; Xie, M.

    1992-09-01T23:59:59.000Z

    We describe a new design of the Infrared Free Electron Laser (IRFEL) for the proposed Chemical Dynamics Research Laboratory (CDRL) at LBL. The design and choice of parameters are dictated by the unique requirements of the CDRL scientific program. The accelerator system is based on the 500 MHz superconducting cavity technology to achieve a wavelength stability of 10[sup [minus]4].

  16. Penn State Multi-Discipline Tribology Group and Energy Institute Studies.

    SciTech Connect (OSTI)

    Perez, Joseph

    2001-08-05T23:59:59.000Z

    This presentation is a summary of the current research activities on fuels and lubricants in the Multi-discipline Tribology group and the engine test group in the Combustion Laboratory of the Pennsylvania State University. The progress areas discussed in this summary include those found in Table 1. Table 1. RESEARCH AREAS: Diesel Engine Emission Reduction; Oxygenated Fuels; Improved Friction Fuels; Vegetable Oil Lubricants; Extended Drain Lubricants; Effect of Chemical Structure on Friction and Wear. The research is of interest either directly or indirectly to the goal of this workshop, diesel engine emissions reduction. The current projects at Penn State in the areas listed above will be discussed.

  17. Electrical Engineering is a diverse discipline encompassing computer and information

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE ∑ Electrical Engineering

  18. Electrical Engineering is a diverse discipline encompassing computer and information

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE Electrical Engineering Bachelor

  19. Master of Science (MS), Major: Chemical Engineering Apply Now

    E-Print Network [OSTI]

    Shihadeh, Alan

    Master of Science (MS), Major: Chemical Engineering Apply Now The Chemical Engineering Program to the following degrees: Master of Science, major Chemical Engineering The MS program will be open to students with a Bachelor of Science (BS) in Chemical Engineering, or other related disciplines. The MS program will also

  20. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Airphotos to Interpret

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture March 2004 Research Section, Coast Forest Region, BCMOF 1 Research Disciplines: Ecology ~ Geology

  1. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology-748-1331. mdeact@shaw.ca #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  2. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.for.gov.bc.ca/vancouvr/research/research_index.htm #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  3. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.for.gov.bc.ca/vancouvr/research/research_index.htm #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  4. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  5. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Rd., Black Creek, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology

  6. Sustainable Future Stevens students bridged disciplines to advance

    E-Print Network [OSTI]

    Yang, Eui-Hyeok

    Building a Sustainable Future Stevens students bridged disciplines to advance sustainable living which collects and analyzes data to preserve energy and teach occupants to live more sustainably of our sustainable future. 4stevens.edu/ecohabit (1) Ecohabit was the only competition house that used

  7. Towards a Discipline of Geospatial Distributed Event Based Systems

    E-Print Network [OSTI]

    Heaton, Thomas H.

    Towards a Discipline of Geospatial Distributed Event Based Systems Annie Liu Computer Science, Caltech 1200 E California Blvd Pasadena, CA 91125, USA mani@cms.caltech.edu ABSTRACT A geospatial system is one in which the state space in- cludes one, two or three-dimensional space and time. A geospatial

  8. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Hudson and Axel Anderson KEYWORDS: Water management, Coastal watersheds, hydrological modeling CITATIONPractice. ResearchSection,Coast ForestRegion, BCMOF,Nanaimo, BC. Extension Note EN-022. EN-022 Hydrology March 2006

  9. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology,Tsitika Watershed.Research Section,CoastForest Region,BCMOF, Nanaimo, BC. Extension Note EN-021. EN-021 Hydrology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note EN-021 March 2006 Forest Research

  10. For immediate release --October 1, 2014 New media practices converge across disciplines

    E-Print Network [OSTI]

    Hossain, Shahadat

    For immediate release -- October 1, 2014 New media practices converge across disciplines Students entering the field of new media might not be aware of all the ways new media tools are being used across disciplines

  11. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS SUMMARY

  12. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Biology, Ecology, and Management

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS ABSTRACT

  13. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note EN-007

  14. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Silvicultural Treatments for Enhancing

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS EXECUTIVE SUMMARY

  15. Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex Interfacial Systems. Final Technical Report

    SciTech Connect (OSTI)

    Sibener, Steven J. [University of Chicago, IL (United States)] [University of Chicago, IL (United States)

    2014-03-11T23:59:59.000Z

    This research program explored the efficacy of using molecular-level manipulation, imaging and scanning tunneling spectroscopy in conjunction with supersonic molecular beam gas-surface scattering to significantly enhance our understanding of chemical processes occurring on well-characterized interfaces. One program focus was on the spatially-resolved emergent behavior of complex reaction systems as a function of the local geometry and density of adsorbate-substrate systems under reaction conditions. Another focus was on elucidating the emergent electronic and related reactivity characteristics of intentionally constructed single and multicomponent atom- and nanoparticle-based materials. We also examined emergent chirality and self-organization in adsorbed molecular systems where collective interactions between adsorbates and the supporting interface lead to spatial symmetry breaking. In many of these studies we combined the advantages of scanning tunneling (STM) and atomic force (AFM) imaging, scanning tunneling local electronic spectroscopy (STS), and reactive supersonic molecular beams to elucidate precise details of interfacial reactivity that had not been observed by more traditional surface science methods. Using these methods, it was possible to examine, for example, the differential reactivity of molecules adsorbed at different bonding sites in conjunction with how reactivity is modified by the local configuration of nearby adsorbates. At the core of this effort was the goal of significantly extending our understanding of interfacial atomic-scale interactions to create, with intent, molecular assemblies and materials with advanced chemical and physical properties. This ambitious program addressed several key topics in DOE Grand Challenge Science, including emergent chemical and physical properties in condensed phase systems, novel uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted national science objectives in the areas of chemical energy production and advanced materials development.

  16. THE JOURNAL OF CHEMICAL PHYSICS 134, 054512 (2011) Water dynamics in small reverse micelles in two solvents: Two-dimensional

    E-Print Network [OSTI]

    Fayer, Michael D.

    = 2 (1.7 nm diameter) Aerosol-OT (AOT)/water reverse micelles in carbon tetrachloride and in isooctane that the reverse micelle dynamics are the same within experimental error regardless of whether isooctane or carbon tetrachloride is used as the organic phase. Two time scales are observed in the vibrational echo data, 1 and 10

  17. A DISCIPLINED APPROACH TO ACCIDENT ANALYSIS DEVELOPMENT AND CONTROL SELECTION

    SciTech Connect (OSTI)

    Ortner, T; Mukesh Gupta, M

    2007-04-13T23:59:59.000Z

    The development and use of a Safety Input Review Committee (SIRC) process promotes consistent and disciplined Accident Analysis (AA) development to ensure that it accurately reflects facility design and operation; and that the credited controls are effective and implementable. Lessons learned from past efforts were reviewed and factored into the development of this new process. The implementation of the SIRC process has eliminated many of the problems previously encountered during Safety Basis (SB) document development. This process has been subsequently adopted for use by several Savannah River Site (SRS) facilities with similar results and expanded to support other analysis activities.

  18. Fluid dynamics, particulate segregation, chemical processes, and natural ore analog discussions that relate to the potential for criticality in Hanford tanks

    SciTech Connect (OSTI)

    Barney, G.S.

    1996-09-27T23:59:59.000Z

    This report presents an in-depth review of the potential for nuclear criticality to occur in Hanford defense waste tanks during past, current and future safe storage and maintenance operations. The report also briefly discusses the potential impacts of proposed retrieval activities, although retrieval was not a main focus of scope. After thorough review of fluid dynamic aspects that focus on particle segregation, chemical aspects that focus on solubility and adsorption processes that might concentrate plutonium and/or separate plutonium from the neutron absorbers in the tank waste, and ore-body formation and mining operations, the interdisciplinary team has come to the conclusion that there is negligible risk of nuclear critically under existing storage conditions in Hanford site underground waste storage tanks. Further, for the accident scenarios considered an accidental criticality is incredible.

  19. Design of a superconducting linear accelerator for an Infrared Free Electron Laser of the proposed Chemical Dynamics Research Laboratory at LBL

    SciTech Connect (OSTI)

    Chattopadhyay, S.; Byrns, R.; Donahue, R.; Edighoffer, J.; Gough, R.; Hoyer, E.; Kim, K.J.; Leemans, W.; Staples, J.; Taylor, B.; Xie, M.

    1992-08-01T23:59:59.000Z

    An accelerator complex has recently been designed at LBL as part of an Infrared Free Electron Laser facility in support of a proposed Chemical Dynamics Research Laboratory. We will outline the choice of parameters and design philosophy, which are strongly driven by the demand of reliable and spectrally stable operation of the FEL for very special scientific experiments. The design is based on a 500 MHz recirculating superconducting electron linac with highest energy reach of about 60 MeV. The accelerator is injected with beams prepared by a specially designed gun-buncher system and incorporates a near-isochronous and achromatic recirculation line tunable over a wide range of beam energies. The stability issues considered to arrive at the specific design will be outlined.

  20. Technical Report TR-014 May 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife just like Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  1. Qualitative Aspects of the Solutions of a Mathematical Model for the Dynamic Analysis of the Reversible Chemical Reaction SO2(g)+1/2O2(g)SO3(g) in a Catalytic Reactor

    E-Print Network [OSTI]

    Angulo Wilfredo; Contreras Joyne

    2014-12-19T23:59:59.000Z

    We present some qualitative aspects concerning the solution to the mathematical model describing the dynamical behavior of the reversible chemical reaction SO2(g)+1/2O2(g)SO3(g) carried out in a catalytic reactor used in the process of sulfuric acid production.

  2. Dynamic

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell: Gas productionDynamic , and Static ,

  3. DEPARTMENT OF CHEMICAL AND PETROLEUM ENGINEERING Research at the Schulich School of Engineering

    E-Print Network [OSTI]

    Calgary, University of

    DEPARTMENT OF CHEMICAL AND PETROLEUM ENGINEERING Research at the Schulich School of Engineering #12;The research programs in the department of chemical and petroleum engineering are known is a multidisciplinary field of research that spans chemical, civil, mechanical and petroleum engineering disciplines

  4. COOEE bitumen: chemical aging

    E-Print Network [OSTI]

    Lemarchand, Claire A; Dyre, Jeppe C; Hansen, Jesper S

    2013-01-01T23:59:59.000Z

    We study chemical aging in "COOEE bitumen" using molecular dynamic simulations. The model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: "2 resins $\\rightarrow$ 1 asphaltene". Molecular dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging reaction, are performed. The stress autocorrelation function, the fluid structure, the rotational dynamics of the plane aromatic molecules, and the diffusivity of each molecule, are determined for the four different compositions. The aging reaction causes a significant dynamics slowdown, which is correlated to the aggregation of asphaltene molecules in larger and dynamically slower nanoaggregates. Finally, a detailed description of the role of each molecule types in the aggregation and aging processes is given.

  5. Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline

    E-Print Network [OSTI]

    Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline DOI: 10*a Since its inception, the discipline of microfluidics has been harnessed for innovations-effect of stereotyping microfluidics as a platform for medical diagnostics and miniaturized lab processes

  6. P U R S U I T A N D P R O M O T I O N O F S C I E N C E CHEMICAL ENGINEERING VS OTHER

    E-Print Network [OSTI]

    Srinivasan, N.

    P U R S U I T A N D P R O M O T I O N O F S C I E N C E CHEMICAL ENGINEERING VS OTHER ENGINEERING DISCIPLINES Chemical engineering had a unique start, in con- trast to the other engineering disciplines was that universities took a lead and started courses in Chemical Engineering and Chemical Technology. These were

  7. Disease Ecology: Community Structure and Pathogen Dynamics [Review

    E-Print Network [OSTI]

    Peterson, A. Townsend

    2007-01-01T23:59:59.000Z

    BOOKS & MEDIA Disease Ecology: Community Structure and Pathogen Dynamics Sharon K. Collinge and Chris Ray, editors Oxford University Press, Cary, North Carolina, 2006 ISBN: 0198567073 Pages: 227; Price: US $124.50 The disciplines of community...

  8. Multi-discipline Waste Acceptance Process at the Nevada National Security Site - 13573

    SciTech Connect (OSTI)

    Carilli, Jhon T. [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States)] [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States); Krenzien, Susan K. [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)] [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)

    2013-07-01T23:59:59.000Z

    The Nevada National Security Site low-level radioactive waste disposal facility acceptance process requires multiple disciplines to ensure the protection of workers, the public, and the environment. These disciplines, which include waste acceptance, nuclear criticality, safety, permitting, operations, and performance assessment, combine into the overall waste acceptance process to assess low-level radioactive waste streams for disposal at the Area 5 Radioactive Waste Management Site. Four waste streams recently highlighted the integration of these disciplines: the Oak Ridge Radioisotope Thermoelectric Generators and Consolidated Edison Uranium Solidification Project material, West Valley Melter, and classified waste. (authors)

  9. Technical Report TR-014 May 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-014 Tools9T 6E9, 250-751-7001 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  10. Electrical Engineering is a diverse discipline encompassing computer and information systems, controls, lasers,

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE ∑ Electrical Engineering

  11. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering (EE) is a diverse discipline encompassing computer, photonics, and quantum information processing. MAJORS & AREAS OF EMPHASIS ∑ ElectricalEngineering ∑ ComputerEngineering)Algorithmsandcomputationalmeth- odsforefficientsolutionofengineeringproblems. Introductiontoengineeringsoftwaretools. EE 200L Foundations of Electrical Engineer- ing Systems

  12. Why Should I Study Engineering? Georgia Southern offers three engineering disciplines Civil, Electrical and Mechanical.

    E-Print Network [OSTI]

    Hutcheon, James M.

    , Electrical and Mechanical. Engineers plan, design, develop, test and analyze infrastructure components (CivilWhy Should I Study Engineering? Georgia Southern offers three engineering disciplines ≠ Civil), electronic systems (Electrical), and systems with moving parts (Mechanical) that affect and improve people

  13. electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    62 electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering. Programs Available ∑ Electrical Engineering Bachelor of Science 131 units ∑ Computer Engineering

  14. electrical (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    66 electrical (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunica- tions. The Electrical Technology and the Signal and Image Processing institute. Programs Available ∑ Electrical Engineering

  15. electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    62 electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Process- ing institute. Programs Available ∑ Electrical Engineering

  16. To appear in Topics in Cognitive Science How Can Philosophy be a True Cognitive Science Discipline?

    E-Print Network [OSTI]

    Bechtel, William

    and cognitive neuroscience. Second, analyses of mental representation address both their vehicle in the autonomous disciplines. Indeed, for those discussions that do not afford linkage to the rest of cognitive

  17. Studies in combustion dynamics

    SciTech Connect (OSTI)

    Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  18. The relationship of parental consistency in discipline to locus of control in preschoolers

    E-Print Network [OSTI]

    Schmidt, Corliss Theresa

    1979-01-01T23:59:59.000Z

    THE RELATIONSHIP OF PARENTAL CONSISTENCY IN DISCIPLINE TO LOCUS OF CONTROL IN PRESCHOOLERS A Thesis by CORLISS THERESA SCHMIDT Submitted to the Graduate College of Texas AIIM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIEI'ICE August 1979 Major Subject: Psychology THE RELATIONSHIP OF PARENTAL CONSISTENCY IN DISCIPLINE TO LOCUS OF CONTROL IN PRESCHOOLERS A Thesis by CORLISS THERESA SCHMIDT Approved as to style and content by: ( a a of Committee...

  19. Innovations in Companion Animal Health Introducing dynamic new treatments, developing stronger diagnostic tools, pioneering veterinary disciplines,

    E-Print Network [OSTI]

    Schladow, S. Geoffrey

    that school faculty members have achieved. The vital role of taurine in the feline diet ≠ Veterinary nutritionists collaborating with cardiologists in the clinic first documented the link between a lack of dietary the Comparative Cancer Center were the first to identify a protein that appears to play a key role

  20. 1.23 Constraints on Seismic Models from Other Disciplines Implications for Mantle Dynamics and

    E-Print Network [OSTI]

    Long, Bernard

    , and different algorithms for inverting the global seis- mic data. A review of the recent advances in global surface 817 1.23.2.3.5 Boundary conditions at CMB 819 1.23.2.3.6 Determining viscous flow Green functions Response Functions for the Mantle 824 1.23.2.5 Depth Dependence of Mantle Viscosity 825 1.23.3 Modeling

  1. Technical Report TR-011 March 2000 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-011 Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife #12;Technical ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Page Summary

  2. Modelling and simulation of multidisciplinary dynamic systems Lead: A. Fakri.

    E-Print Network [OSTI]

    Baudoin, Geneviève

    Modelling and simulation of multidisciplinary dynamic systems Lead: A. Fakri. Permanent members: P. Integration of various engineering disciplines and the consideration of the dynamic control need a concurrent suited for the energy exchanges to study multidisciplinary dynamic engineering systems modelling. Our

  3. Design of a Superconducting Linear Accelerator for an Infrared Free Electron Laser of the Proposed Chemical Dynamics Research Laboratory at LBL

    E-Print Network [OSTI]

    Chattopadhyay, S.

    2011-01-01T23:59:59.000Z

    see "An Infrared Free-Electron Laser for CDRL," LBL Pub-FOR AN INFRARED FREE ELECTRON LASER OF 1HE PROPOSED CHEMICALFOR AN INFRARED FREE ELECTRON LASER OF THE PROPOSED CHEMICAL

  4. DOE Chair of Excellence Professorship in Environmental Disciplines

    SciTech Connect (OSTI)

    Shoou-Yuh Chang

    2013-01-31T23:59:59.000Z

    The United States (US) nuclear weapons program during the Cold War left a legacy of radioactive, hazardous, chemical wastes and facilities that may seriously harm the environment and people even today. Widespread public concern about the environmental pollution has created an extraordinary demand for the treatment and disposal of wastes in a manner to protect the public health and safety. The pollution abatement and environmental protection require an understanding of technical, regulatory, economic, permitting, institutional, and public policy issues. Scientists and engineers have a major role in this national effort to clean our environment, especially in developing alternative solutions and evaluation criteria and designing the necessary facilities to implement the solutions. The objective of the DOE Chair of Excellence project is to develop a high quality educational and research program in environmental engineering at North Carolina A&T State University (A&T). This project aims to increase the number of graduate and undergraduate students trained in environmental areas while developing a faculty concentrated in environmental education and research. Although A&T had a well developed environmental program prior to the Massie Chair grant, A&T's goal is to become a model of excellence in environmental engineering through the program's support. The program will provide a catalyst to enhance collaboration of faculty and students among various engineering departments to work together in a focus research area. The collaboration will be expanded to other programs at A&T. The past research focus areas include: hazardous and radioactive waste treatment and disposal fate and transport of hazardous chemicals in the environment innovative technologies for hazardous waste site remediation pollution prevention Starting from 2005, the new research focus was in the improvement of accuracy for radioactive contaminant transport models by ensemble based data assimilation. The specific objectives are to: 1). improve model accuracy for use in minimizing health and environmental risk, and 2). improve the decision making process in the selection and application of available technologies for long-term monitoring and safeguard operation at NNSA sites.

  5. EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused on understanding the

    E-Print Network [OSTI]

    Krylov, Anna I.

    EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused this understanding to read the record of earth history written in rocks and sediments, and on developing models by humans. Opportunities for Students Sigma Gamma Epsilon: The Omega Chapter of the national honorary earth

  6. 1.14 Note: Actual time to complete varies by discipline and departmental requirements. Dissertation Timeline

    E-Print Network [OSTI]

    Papalambros, Panos

    1.14 Note: Actual time to complete varies by discipline and departmental requirements. Dissertation Timeline STUDENT SERVICES: ACADEMIC RECORDS & DISSERTATIONS 915 E. Washington Street ∑ 0120 Rackham://wolverineaccess.umich.edu/ 6 months prior to Group Pre-Defense Review Rackham Format Guidelines http://www.rackham.umich.edu/downloads/oard-dissertation

  7. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 electrical Electrical Engineering (EE) is a diverse discipline encompassing computer information processing. ProgrAmS AVAilAble ∑ ElectricalEngineering Bachelor of Science 131 units ∑ ComputerEngineeringand Computer Science Bachelor of Science (see page 69) 132 units ∑ ElectricalEngineering(Computers) degree

  8. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 electrical Electrical Engineering (EE) is a diverse discipline encompassing computer information processing. mAjorS & AreAS of emPhASiS ∑ ElectricalEngineering ∑ ComputerEngineering& Computer Science (see page 69) ∑ ElectricalEngineering Emphasis in Computers See pages 76-77 for the curriculum

  9. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.Understanding how the hydrologic cycle is affected by climate, trees and plants, soils, geology, topography, springs, or any Figure 1. The hydrologic cycle, or water cycle (courtesy of the US Geological Survey

  10. The NU Transportation Center Icarus Society presents.... "Airline Capacity Discipline: Where and

    E-Print Network [OSTI]

    Bustamante, Fabi√°n E.

    The NU Transportation Center Icarus Society presents.... "Airline Capacity Discipline: Where and to What Extent? Aaron J. Gellman Professor of Transportation Northwestern University Transportation Center and Kellogg School of Management Thursday Nov. 29, 2012 3:00 pm Location: Transportation Center Chambers Hall

  11. Wind power is a rapidly growing and evolving field that crosses traditional academic disciplines and increasingly

    E-Print Network [OSTI]

    Delaware, University of

    ways in which society's understanding and acceptance of renewable energy power generation can impactWind power is a rapidly growing and evolving field that crosses traditional academic disciplines and increasingly requires practitioners who understand the relationships among the various components of wind

  12. DOE contractor's meeting on chemical toxicity

    SciTech Connect (OSTI)

    Not Available

    1987-01-01T23:59:59.000Z

    The Office of Health and Environmental Research (OHER) is required to determine the potential health and environmental effects associated with energy production and use. To ensure appropriate communication among investigators and scientific disciplines that these research studies represent, OHER has sponsored workshops. This document provides a compilation of activities at the Third Annual DOE/OHER Workshop. This year's workshop was broadened to include all OHER activities identified as within the chemical effects area. The workshop consisted of eight sessions entitled Isolation and Detection of Toxic chemicals; Adduct Formation and Repair; Chemical Toxicity (Posters); Metabolism and Genotoxicity; Inhalation Toxicology; Gene Regulation; Metals Toxicity; and Biological Mechanisms. This document contains abstracts of the information presented by session.

  13. 32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation

    E-Print Network [OSTI]

    32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation 32) in the administration of the discipline and dismissal policy and regulation. 2.00 APPROVAL PROCEDURE 2.01 A supervisor that is available for review. Following the review, AgriLife Human Resources will, in keeping with System Regulation

  14. Chemical Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Science Compton double ionization of helium in the region of the cross-section maximum B. Krssig, R.W. Dunford, D.S. Gemmell, S. Hasegawa, E.P. Kanter, H....

  15. Disciplines Atmosphere

    E-Print Network [OSTI]

    Laurini, Robert

    Ultraviolet X-Rays Gamma-Rays Visible Red Orange Yellow Green Blue Violet 0,7 Ķm 0,4 Ķm Waves #12;Satellites of pollution (air, water, etc.) ∑ etc. #12;http://www.sbg.ac.at/geo/idrisi/gis_environmental_modeling/sf_papers/brendan_mackey/mackey_paper.html #12;Contents ∑ 1 ≠ Data acquisition ∑ 2 ≠ Environmental data modelling ∑ 3 ≠ Continuous data ∑ 4 ≠ XML

  16. attractive analytical chemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mohammed, Saada 2008-01-01 13 Dynamics of excitation pulses with attractive interaction: Kinematic analysis and chemical wave experiments Chemistry Websites Summary: in these...

  17. CHEMICAL ENGINEERING DEPARTMENT AND GRADUATE SCHOOL

    E-Print Network [OSTI]

    Lu, Chang

    . Department of Chemical Engineering Elective Courses ChE 5064 Solids and Solid Surfaces ChE 5084 Heterogeneous Catalysis ChE 5164 Process Dynamics and Simulation ChE 5214 Polymeric Biomaterials ChE 5224 Advanced Polymer

  18. advanced dynamic neutron: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M. Ali Alpar 2005-05-04 11 THE JOURNAL OF CHEMICAL PHYSICS 139, 175101 (2013) Dynamic neutron scattering from conformational dynamics. I. Theory Biology and Medicine Websites...

  19. Chemical Occurrences

    Broader source: Energy.gov [DOE]

    Classification of Chemical Occurrence Reports into the following four classes: Occurrences characterized by serious energy release, injury or exposure requiring medical treatment, or severe environmental damage, Occurrences characterized by minor injury or exposure, or reportable environmental release, Occurrences that were near misses including notable safety violations and Minor occurrences.

  20. Chemical Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms AboutRESEARCH CAPABILITIES Thematerials | Center forChemical

  1. Chemical composition of Earth-like planets

    E-Print Network [OSTI]

    Ronco, M P; Marboeuf, U; Alibert, Y; de ElŪa, G C; Guilera, O M

    2015-01-01T23:59:59.000Z

    Models of planet formation are mainly focused on the accretion and dynamical processes of the planets, neglecting their chemical composition. In this work, we calculate the condensation sequence of the different chemical elements for a low-mass protoplanetary disk around a solar-type star. We incorporate this sequence of chemical elements (refractory and volatile elements) in our semi-analytical model of planet formation which calculates the formation of a planetary system during its gaseous phase. The results of the semi-analytical model (final distributions of embryos and planetesimals) are used as initial conditions to develope N-body simulations that compute the post-oligarchic formation of terrestrial-type planets. The results of our simulations show that the chemical composition of the planets that remain in the habitable zone has similar characteristics to the chemical composition of the Earth. However, exist differences that can be associated to the dynamical environment in which they were formed.

  2. September 11, 2008 12:55 Dynamical Systems monotonereacs Dynamical Systems

    E-Print Network [OSTI]

    Banaji,. Murad

    September 11, 2008 12:55 Dynamical Systems monotonereacs Dynamical Systems Vol. 00, No. 00, Month 200x, 1­30 RESEARCH ARTICLE Monotonicity in chemical reaction systems Murad Banajia, a Department) This paper discusses the question of when the dynamical systems arising from chemical reac- tion networks

  3. Efficient Dynamic Contracts: Enabling A Poor borrower To Get Out of Poverty Trap

    E-Print Network [OSTI]

    Bandyopadhyay, Antar

    of poverty trap is synonymous to getting loan from the formal sector. The MFI discipline the borrower to saveEfficient Dynamic Contracts: Enabling A Poor borrower To Get Out of Poverty Trap Dyotona Dasgupta, New Delhi 110016, India Keywords: Dynamic Contracts, Progressive Lending, Collateral, Poverty Trap

  4. Model-Driven Dynamic Control of Embedded Wireless Sensor Networks

    E-Print Network [OSTI]

    Agarwal, Pankaj K.

    Model-Driven Dynamic Control of Embedded Wireless Sensor Networks Paul G. Flikkema1 , Pankaj K-generation wireless sensor networks may revolution- ize understanding of environmental change by assimilating heteroge of wireless sensor networks is now becoming a mature research field. As a result, the discipline is undergoing

  5. Chemical dynamics in time and energy space

    SciTech Connect (OSTI)

    Myers, J.D.

    1993-04-01T23:59:59.000Z

    The development of a versatile picosecond ultraviolet/vacuum ultraviolet temporal spectrometer and its potential use for measuring internal energy redistribution in isolated molecules are described in detail. A detailed description of the double-pass Nd:YAG amplifier and the dye amplifiers is given with the pulse energies achieved in the visible, ultraviolet, and vacuum ultraviolet. The amplified visible pulses are shown to be of sub-picosecond duration and near transform limited. The instrument`s temporal response ({le}10 ps) is derived from an instrument limited measurement of the dissociation lifetime of methyl iodide at 266 nm. The methyl iodide experiment is used to discuss the various sources of noise and background signals that are intrinsic to this type of experiment. Non-time-resolved experiments measuring the branching ratio and kinetic energy distributions of products from the 193 nm photodissociation of cyclopentadiene and thiophene are presented. These studies were done using the molecular beam Photofragment Translational Spectroscopy (PTS) technique. The results from the cyclopentadiene experiment confirm that H atom elimination to yield the cyclopentadienyl radical is the dominant dissociation channel. A barrier of {ge}5 kcal/mol can be understood in terms of the delocalization of the radical electron of the cyclopentadienyl fragment. A concerted elimination yielding cyclopropene and acetylene was also observed and is proposed to occur via a bicyclo-[2.1.0]pent-2-ene intermediate. Two other channels, yielding acetylene plus the CH{sub 2}CHCH triplet carbene, and CH{sub 2} plus 1-buten-3-yne, are postulated to occur via ring opening. The implications of the experimental results for bulk thermal oxidation and pyrolysis models are discussed. The thiophene experiment shows six competing dissociation channels. The postulated intermediates for the various thiophene dissociation channels include bicyclo, ring opened, and possibly ring contracted forms.

  6. Microfluidic chemical reaction circuits

    SciTech Connect (OSTI)

    Lee, Chung-cheng (Irvine, CA); Sui, Guodong (Los Angeles, CA); Elizarov, Arkadij (Valley Village, CA); Kolb, Hartmuth C. (Playa del Rey, CA); Huang, Jiang (San Jose, CA); Heath, James R. (South Pasadena, CA); Phelps, Michael E. (Los Angeles, CA); Quake, Stephen R. (Stanford, CA); Tseng, Hsian-rong (Los Angeles, CA); Wyatt, Paul (Tipperary, IE); Daridon, Antoine (Mont-Sur-Rolle, CH)

    2012-06-26T23:59:59.000Z

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  7. Computational Chemical Materials Engineering

    E-Print Network [OSTI]

    Home Computational Chemical and Materials Engineering Tahir Cagin Chemical Engineering Department through processing for improving their performance for engineering applications ∑ Use and develop with usable ≠ Chemical ≠ Electronic ≠ Optical ≠ Magnetic ≠ Transport, thermal and mechanical properties

  8. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  9. Animal Health Diagnostic Center Test and Fee Schedule Test Name Test Fee Discipline Test Days Lag** Samples Container Coolant Comments

    E-Print Network [OSTI]

    Keinan, Alon

    Animal Health Diagnostic Center Test and Fee Schedule Test Name Test Fee Discipline Test Days Lag** Samples Container Coolant Comments Equine Tests Equine Tests Acid Fast Stain (for bacteria) M-F 1-2 days 1 4 hours for equine. For more information, see Equine Cushing's Tests or AppendixC. For Equine only

  10. FUNDAMENTAL IMPACTS A Study of the Cross-Discipline and Societal Benefits of UK Research in Particle Physics

    E-Print Network [OSTI]

    Crowther, Paul

    a wide variety of other disciplines, particularly those in the medical and life sciences. Despite prodigious advances in our knowledge of fundamental physics, there remain many unanswered questions that will require significant technological innovation to address. This innovation will enable advances to be made

  11. UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members.

    E-Print Network [OSTI]

    Van Stryland, Eric

    UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members. (1) Just cause shall be defined as: (a) Incompetence; or (b) Misconduct. (2) Termination and Suspension. (a) The appointment of a non-unit faculty or an A&P staff member may be terminated or suspended during its term

  12. chemical analysis | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemical analysis chemical analysis Leads No leads are available at this time. Microstructure and Cs Behavior of Ba-Doped Aluminosilicate Pollucite Irradiated with F+ Ions....

  13. Incremental Integration Tools for Chemical Engineering: An Industrial Application of Triple Graph

    E-Print Network [OSTI]

    Westfechtel, Bernhard

    and the components of the chemical plant, simulation models for steady-state and dynamic simulations, etc. Design representations of a chemical plant have to be kept consistent with each other. Incremental integration tools). In chemical engineering design, a chemical plant is described from different per- spectives by a set

  14. Chemical Sciences Division annual report 1994

    SciTech Connect (OSTI)

    NONE

    1995-06-01T23:59:59.000Z

    The division is one of ten LBL research divisions. It is composed of individual research groups organized into 5 scientific areas: chemical physics, inorganic/organometallic chemistry, actinide chemistry, atomic physics, and chemical engineering. Studies include structure and reactivity of critical reaction intermediates, transients and dynamics of elementary chemical reactions, and heterogeneous and homogeneous catalysis. Work for others included studies of superconducting properties of high-{Tc} oxides. In FY 1994, the division neared completion of two end-stations and a beamline for the Advanced Light Source, which will be used for combustion and other studies. This document presents summaries of the studies.

  15. Eects of thermo-chemical mantle convection on the thermal evolution of the Earth's core

    E-Print Network [OSTI]

    Tackley, Paul J.

    E°ects of thermo-chemical mantle convection on the thermal evolution of the Earth's core Takashi in the core with a fully dynamic thermo-chemical mantle convection model is developed to investigate

  16. Guidance Document Reactive Chemicals

    E-Print Network [OSTI]

    showers and chillers. Health Hazards: The reactive chemicals are grouped primarily because of the physical

  17. Chemical Management Contacts

    Broader source: Energy.gov [DOE]

    Contacts for additional information on Chemical Management and brief description on Energy Facility Contractors Group

  18. PINS chemical identification software

    DOE Patents [OSTI]

    Caffrey, Augustine J.; Krebs, Kennth M.

    2004-09-14T23:59:59.000Z

    An apparatus and method for identifying a chemical compound. A neutron source delivers neutrons into the chemical compound. The nuclei of chemical elements constituting the chemical compound emit gamma rays upon interaction with the neutrons. The gamma rays are characteristic of the chemical elements constituting the chemical compound. A spectrum of the gamma rays is generated having a detection count and an energy scale. The energy scale is calibrated by comparing peaks in the spectrum to energies of pre-selected chemical elements in the spectrum. A least-squares fit completes the calibration. The chemical elements constituting the chemical compound can be readily determined, which then allows for identification of the chemical compound.

  19. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    , Biochemical, Environmental, Petroleum Engineering and Nantoechnology. CHEMICAL&MATERIALSSCIENCE CHE OVERVIEW of Science 131 units · Chemical Engineering (Petroleum) Bachelor of Science 136 units · Chemical Engineering38 Chemical engineers design, control and optimize large-scale chemical, physicochemical

  20. >> engineering.wustl.edu Across Disciplines. Across the World.TM

    E-Print Network [OSTI]

    Subramanian, Venkat

    .wustl.edu | 1 We aim to prepare you for leadership roles. Today's college students want to have an impact in Lopata Gallery; Department of Energy, Environmental & Chemical Engineering guest seminar held in Brauer studies, visual communications, political science, history, entrepreneurship, foreign language, dance

  1. Log-domain circuit models of chemical reactions

    E-Print Network [OSTI]

    Mandal, Soumyajit

    We exploit the detailed similarities between electronics and chemistry to develop efficient, scalable bipolar or subthreshold log-domain circuits that are dynamically equivalent to networks of chemical reactions. Our ...

  2. On line chemical composition of analyzer development

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    This status report details progress made on the development of an on-line chemical analyzer. Dynamic studies of the distillation column, approval of testing plans, installation of a sample cell and raman analyzer, design of computerized control systems are described. Information on seminars and published papers is also included. (GHH)

  3. Temporal variability in chemical cycling of the subterranean estuary and associated chemical loading to the coastal ocean

    E-Print Network [OSTI]

    Gonneea, Meagan Joan Eagle

    2014-01-01T23:59:59.000Z

    At the land-ocean interface, terrestrial groundwater interacts with seawater to form a subterranean estuary, which can play host to dynamic biogeochemical cycling of nutrients, trace metals and radionuclides. This chemically ...

  4. PNNL Chemical Hydride Capabilities

    Broader source: Energy.gov (indexed) [DOE]

    * Quantum chemistry, density functional theory, Car- Parinello, ab initio dynamics, variational transition state theory, molecular dynamics Strategy * Bring some of the...

  5. Reference: Dittrich, P., P. Speroni di Fenizio (2005), Chemical Organization Theory, arXiv:q-bio.MN/0501016 Chemical organization theory: Towards a theory of con-

    E-Print Network [OSTI]

    Dittrich, Peter

    2005-01-01T23:59:59.000Z

    Reference: Dittrich, P., P. Speroni di Fenizio (2005), Chemical Organization Theory, arXiv:q-bio.MN/0501016 Chemical organization theory: Towards a theory of con- structive dynamical systems Peter Dittrich. The theory consists of two parts. The first part introduces the concept of a chemical organization

  6. Capacitive chemical sensor

    DOE Patents [OSTI]

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27T23:59:59.000Z

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  7. Chemistry 455 Chemical Nanotechnology

    E-Print Network [OSTI]

    Rohs, Remo

    Chemistry 455 Chemical Nanotechnology 4 units Prof. Richard Brutchey, Fall 2014 (Lecture = 12:00≠12:50 pm MWF) CHEM 455 is an upper-division undergraduate course in Chemical Nanotechnology. The intent

  8. and Chemical Engineering

    E-Print Network [OSTI]

    Prinz, Friedrich B.

    is constructing a new building that will house the Department of Chemical Engineering and the DepartmentBiological and Chemical Engineering Building #12;2 Biological and Chemical Engineering Building sta and Engineering Quad, the new building will be part of a neighborhood of four buildings that house a community

  9. Equilibrium Chemical Engines

    E-Print Network [OSTI]

    Tatsuo Shibata; Shin-ichi Sasa

    1997-10-30T23:59:59.000Z

    An equilibrium reversible cycle with a certain engine to transduce the energy of any chemical reaction into mechanical energy is proposed. The efficiency for chemical energy transduction is also defined so as to be compared with Carnot efficiency. Relevance to the study of protein motors is discussed. KEYWORDS: Chemical thermodynamics, Engine, Efficiency, Molecular machine.

  10. Department of Chemical Engineering

    E-Print Network [OSTI]

    Acton, Scott

    Developing Leaders of Innovation Department of Chemical Engineering #12;At the University of Virginia, we educate students in traditional and nontraditional areas of chemical engineering, giving them.Va. Department of Chemical Engineering benefit from a modern academic curriculum and state

  11. PHYSICS DIVISION CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Kemner, Ken

    PHYSICS DIVISION CHEMICAL HYGIENE PLAN 2008 Prepared by _________________________________________________ T. Mullen Physics Division Chemical Hygiene Officer Reviewed by ___________________________________________________ J. Woodring Site Chemical Hygiene Officer Approved

  12. Technical Report TR-012 March 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-012: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife #12;Technical Report TR ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Page Summary 2 Keywords 2

  13. From the portfolio to the diagram : architectural discourse and the transformation of the discipline of architecture in America, 1918-1943

    E-Print Network [OSTI]

    Pae, Hy?ng-min.

    1993-01-01T23:59:59.000Z

    This dissertation is an historical inquiry into the concomitant transformations of architectural discourse and the discipline of architecture in America. It proceeds on the theoretical assumption that the documents produced ...

  14. Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Napp, Nils

    Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN The Wyss Institute for Biologically Inspired Engineering June 2014 #12;Wyss Institute Chemical Hygiene Plan TABLE OF CONTENTS 1.0 POLICY.......................................................................................... 2 2.1 CHEMICAL HYGIENE OFFICER

  15. Highly Hazardous Chemicals and Chemical Spills EPA Compliance Fact Sheet

    E-Print Network [OSTI]

    Wikswo, John

    Highly Hazardous Chemicals and Chemical Spills EPA Compliance Fact Sheet Vanderbilt Environmental.safety.vanderbilt.edu HIGHLY HAZARDOUS CHEMICAL WASTES Certain chemical wastes must be handled by special procedures due to their highly hazardous nature. These chemicals include expired isopropyl and ethyl ethers (these chemicals

  16. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    Emphasis in Nanotechnology · ChemicalEngineering Emphasis in Petroleum Engineering · ChemicalEngineering38 Chemical engineers design, control and optimize large-scale chemical, physicochemical and electronics fields. Chemical Engineers are employed in areas as diverse as the chemical, materials, energy

  17. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    · ChemicalEngineering (Nanotechnology) Bachelor of Science 131 units · ChemicalEngineering(Petroleum38 Chemical engineers design, control and optimize large-scale chemical, physicochemical and electronics fields. Chemical Engineers are employed in areas as diverse as the chemical, pharmaceutical

  18. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    in Nanotechnology · ChemicalEngineering Emphasis in Petroleum Engineering · ChemicalEngineering Emphasis in Polymers38 Chemical engineers design, control and optimize large-scale chemical, physicochemical and electronics fields. Chemical Engineers are employed in areas as diverse as the chemical, pharmaceutical

  19. 45 2013-14 Suggested Course Plan CHEMICAL (POLYMERS/MATERIALS)

    E-Print Network [OSTI]

    Zhou, Chongwu

    . to Separation Processes CHE 405: Probability and Statistics for CHE or iSE 460: Engineering Economy or bUAD 301: Chemical Process Dynamics CHE 472: Polymer Science & Engineering CHE 476: Chemical Engineering Materials GEN ED. iv GEN ED. v GEN ED. vi EnGInEERInG (60 unITS) CHE 120: Intro. to Chemical Engineering CHE 205

  20. 49 2012-13SuggestedCoursePlan CHEMICAL (POLYMERS/MATERIALS)

    E-Print Network [OSTI]

    Zhou, Chongwu

    . to Separation Processes CHE 405: Probability and Statistics for CHE or ISE 460: Engineering Economy or BUAD 301: Chemical Process Dynamics CHE 472: Polymer Science & Engineering CHE 476: Chemical Engineering Materials. II GEN ED. IV GEN ED. V GEN ED. VI ENGINEERING (60 UNITS) CHE 120: Intro. to Chemical Engineering CHE

  1. THERMO-CHEMICAL STRUCTURE OF THE LOWER MANTLE: SEISMOLOGICAL EVIDENCE AND

    E-Print Network [OSTI]

    Tackley, Paul J.

    CHAPTER 11 THERMO-CHEMICAL STRUCTURE OF THE LOWER MANTLE: SEISMOLOGICAL EVIDENCE AND CONSEQUENCES and numerical modeling of thermo- chemical convection to infer robust features on mantle structure and dynamics. The tomographic maps of thermo-chemical variations were computed using a new approach that combines a careful

  2. Chemometrics review for chemical sensor development, task 7 report

    SciTech Connect (OSTI)

    NONE

    1994-05-01T23:59:59.000Z

    This report, the seventh in a series on the evaluation of several chemical sensors for use in the U.S. Department of Energy`s (DOE`s) site characterization and monitoring programs, concentrates on the potential use of chemometrics techniques in analysis of sensor data. Chemometrics is the chemical discipline that uses mathematical, statistical, and other methods that employ formal logic to: design or select optimal measurement procedures and experiments and provide maximum relevant chemical information by analyzing chemical data. The report emphasizes the latter aspect. In a formal sense, two distinct phases are in chemometrics applications to analytical chemistry problems: (1) the exploratory data analysis phase and (2) the calibration and prediction phase. For use in real-world problems, it is wise to add a third aspect - the independent validation and verification phase. In practical applications, such as the ERWM work, and in order of decreasing difficulties, the most difficult tasks in chemometrics are: establishing the necessary infrastructure (to manage sampling records, data handling, and data storage and related aspects), exploring data analysis, and solving calibration problems, especially for nonlinear models. Chemometrics techniques are different for what are called zeroth-, first-, and second-order systems, and the details depend on the form of the assumed functional relationship between the measured response and the concentrations of components in mixtures. In general, linear relationships can be handled relatively easily, but nonlinear relationships can be difficult.

  3. New Methods for Quantum Mechanical Reaction Dynamics

    E-Print Network [OSTI]

    Thompson, Ward H.

    2010-01-01T23:59:59.000Z

    8136 (1992). [166] W . H . Thompson and W . H . M i l l e9205 (1995). [168] W . H . Thompson and W . H . M i l l eReaction Dynamics Ward H. Thompson Chemical Sciences

  4. Excimer laser chemical problems

    SciTech Connect (OSTI)

    Tennant, R.; Peterson, N.

    1982-01-01T23:59:59.000Z

    Techniques need to be developed to maintain XeF and XeCl laser performance over long periods of time without degradation resulting from chemical processes occurring within the laser. The dominant chemical issues include optical damage, corrosions of laser materials, gas contamination, and control of halogen concentration. Each of these issues are discussed and summarized. The methods of minimizing or controlling the chemical processes involved are presented.

  5. EMSL - chemical analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemical-analysis en Microstructure and Cs Behavior of Ba-Doped Aluminosilicate Pollucite Irradiated with F+ Ions. http:www.emsl.pnl.govemslwebpublications...

  6. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22T23:59:59.000Z

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  7. Apparatus for chemical synthesis

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Herring, J. Stephen (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID)

    2011-05-10T23:59:59.000Z

    A method and apparatus for forming a chemical hydride is described and which includes a pseudo-plasma-electrolysis reactor which is operable to receive a solution capable of forming a chemical hydride and which further includes a cathode and a movable anode, and wherein the anode is moved into and out of fluidic, ohmic electrical contact with the solution capable of forming a chemical hydride and which further, when energized produces an oxygen plasma which facilitates the formation of a chemical hydride in the solution.

  8. Chemical Accelerators The phrase "chemical accelerators"

    E-Print Network [OSTI]

    Zare, Richard N.

    bonds, 2 to 10 ev). The methods that have revealed this richness and order of medium- and high-energy, mass spectrometry. While hot-atom studies overcome the energy limitations of thermochemical methods energies of a few electron volts. Most studies of chemical kinetics made by traditional thermochemical

  9. CHEMICAL ABBREVIATION KEY ABBREVIATION CHEMICAL NAME HAZARDS

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Corrosive - base LiCl Lithium chloride Harmful MeOH Methanol Flammable #12;CHEMICAL ABBREVIATION KEY Irritant destain Methanol,acetic acid,H2O Flammable, Corrosive - acid DI H2O Deionized water DCM FeCl3 Iron(III) chloride Corrosive - acid FeSO4 Iron(II) sulfate Toxic H2O Water HCl Hydrochloric

  10. Tortuous path chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Adkins, Douglas R. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); Simonson, Robert J. (Cedar Crest, NM)

    2010-09-21T23:59:59.000Z

    A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.

  11. Quantitative genetic activity graphical profiles for use in chemical evaluation

    SciTech Connect (OSTI)

    Waters, M.D. [Environmental Protection Agency, Washington, DC (United States); Stack, H.F.; Garrett, N.E.; Jackson, M.A. [Environmental Health Research and Testing, Inc., Research Triangle Park, NC (United States)

    1990-12-31T23:59:59.000Z

    A graphic approach, terms a Genetic Activity Profile (GAP), was developed to display a matrix of data on the genetic and related effects of selected chemical agents. The profiles provide a visual overview of the quantitative (doses) and qualitative (test results) data for each chemical. Either the lowest effective dose or highest ineffective dose is recorded for each agent and bioassay. Up to 200 different test systems are represented across the GAP. Bioassay systems are organized according to the phylogeny of the test organisms and the end points of genetic activity. The methodology for producing and evaluating genetic activity profile was developed in collaboration with the International Agency for Research on Cancer (IARC). Data on individual chemicals were compiles by IARC and by the US Environmental Protection Agency (EPA). Data are available on 343 compounds selected from volumes 1-53 of the IARC Monographs and on 115 compounds identified as Superfund Priority Substances. Software to display the GAPs on an IBM-compatible personal computer is available from the authors. Structurally similar compounds frequently display qualitatively and quantitatively similar profiles of genetic activity. Through examination of the patterns of GAPs of pairs and groups of chemicals, it is possible to make more informed decisions regarding the selection of test batteries to be used in evaluation of chemical analogs. GAPs provided useful data for development of weight-of-evidence hazard ranking schemes. Also, some knowledge of the potential genetic activity of complex environmental mixtures may be gained from an assessment of the genetic activity profiles of component chemicals. The fundamental techniques and computer programs devised for the GAP database may be used to develop similar databases in other disciplines. 36 refs., 2 figs.

  12. Chemical process hazards analysis

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  13. ITP Chemicals: Chemical Bandwidth Study - Energy Analysis: A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Bandwidth Study - Energy Analysis: A Powerful Tool for Identifying Process Inefficiencies in the U.S. Chemical Industry, Industrial Technologies Program, DRAFT Summary...

  14. ANALYTICAL METHODS in CHEMICAL ECOLOGY

    E-Print Network [OSTI]

    ANALYTICAL METHODS in CHEMICAL ECOLOGY a post graduate course (doktorandkurs) when: February 10 ≠ 28, 2014 where: Chemical Ecology, Plant Protection Biology, Swedish University of Agriculture (SLU to modern analytical methods used in Chemical Ecological and Ecotoxicological research, such as: methods

  15. Safety Issues Chemical Storage

    E-Print Network [OSTI]

    Cohen, Robert E.

    Safety Issues ∑ Chemical Storage ∑Store in compatible containers that are in good condition to store separately. #12;Safety Issues ∑ Flammable liquid storage -Store bulk quantities in flammable storage cabinets -UL approved Flammable Storage Refrigerators are required for cold storage ∑ Provide

  16. Appendix G. Chemicals Appendix G. Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals chemicals result from the direct or indirect actions of humans. Build- ing materials used for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  17. Appendix H. Chemicals Appendix H. Chemicals H-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals chemicals result from the direct or indirect actions of humans. Build- ing materials used for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  18. PhD Chemical Engineering MS Chemical Engineering

    E-Print Network [OSTI]

    Collins, Gary S.

    phenomena in nature and technology. The chemical engineer leverages knowledge of molecular processes across1 PhD Chemical Engineering MS Chemical Engineering Bylaws Gene and Linda Voiland School of Chemical Engineering and Bioengineering College of Engineering and Architecture Approved by Voiland School faculty

  19. Magnetic fields, spots and weather in chemically peculiar stars

    E-Print Network [OSTI]

    O. Kochukhov

    2007-11-30T23:59:59.000Z

    New observational techniques and sophisticated modelling methods has led to dramatic breakthroughs in our understanding of the interplay between the surface magnetism, atomic diffusion and atmospheric dynamics in chemically peculiar stars. Magnetic Doppler images, constructed using spectropolarimetric observations of Ap stars in all four Stokes parameters, reveal the presence of small-scale field topologies. Abundance Doppler mapping has been perfected to the level where distributions of many different chemical elements can be deduced self-consistently for one star. The inferred chemical spot structures are diverse and do not always trace underlying magnetic field geometry. Moreover, horizontal chemical inhomogeneities are discovered in non-magnetic CP stars and evolving chemical spots are observed for the first time in the bright mercury-manganese star alpha And. These results show that in addition to magnetic fields, another important non-magnetic structure formation mechanism acts in CP stars.

  20. SECTION SEVEN DEFINITION OF TERMS Additional Subject Group of related modules within an academic discipline which is taken in addition to

    E-Print Network [OSTI]

    Davies, Christopher

    SECTION SEVEN DEFINITION OF TERMS Additional Subject Group of related modules within an academic(s). Single / Double / Triple module Unit of study with a value of 10/20/30 credits. Subject Group of related modules within one academic discipline. Timetable Group Groups within which a module's teaching and other

  1. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01T23:59:59.000Z

    G-31 Fluorocarbonhydrocarbons, and (3) fluorocarbon solvents. However, aHigh Hazard Chemicals Fluorocarbon Solvents Fluorocarbon

  2. November 2006 CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Bordenstein, Seth

    .0 DEPARTMENTAL SAFETY MANAGEMENT 4.1 CHEMISTRY SAFETY COMMITTEE 4.2 TRAINING 4.3 CHEMICAL SAFETY PROTOCOLS 4.2 CHEMICAL HAZARD INFORMATION 6.3 CHEMICAL STORAGE IN LABORATORIES 6.4 WORKING WITH PARTICULARLY HAZARDOUS PROCEDURES 6.8 CHEMICAL WASTE DISPOSAL 6.9 COMPRESSED GASES 6.10 CRYOGENIC LIQUIDS #12;November 2006 3 6

  3. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA)

    1999-03-02T23:59:59.000Z

    A dispenser for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 .mu.m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (.about.200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments.

  4. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, S.P.

    1999-03-02T23:59:59.000Z

    A dispenser is disclosed for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 {micro}m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (ca. 200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments. 4 figs.

  5. The IceCube Data Acquisition Software: Lessons Learned during Distributed, Collaborative, Multi-Disciplined Software Development.

    SciTech Connect (OSTI)

    Beattie, Keith S; Beattie, Keith; Day Ph.D., Christopher; Glowacki, Dave; Hanson Ph.D., Kael; Jacobsen Ph.D., John; McParland, Charles; Patton Ph.D., Simon

    2007-09-21T23:59:59.000Z

    In this experiential paper we report on lessons learned during the development ofthe data acquisition software for the IceCube project - specifically, how to effectively address the unique challenges presented by a distributed, collaborative, multi-institutional, multi-disciplined project such as this. While development progress in software projects is often described solely in terms of technical issues, our experience indicates that non- and quasi-technical interactions play a substantial role in the effectiveness of large software development efforts. These include: selection and management of multiple software development methodologies, the effective useof various collaborative communication tools, project management structure and roles, and the impact and apparent importance of these elements when viewed through the differing perspectives of hardware, software, scientific and project office roles. Even in areas clearly technical in nature, success is still influenced by non-technical issues that can escape close attention. In particular we describe our experiences on software requirements specification, development methodologies and communication tools. We make observations on what tools and techniques have and have not been effective in this geographically disperse (including the South Pole) collaboration and offer suggestions on how similarly structured future projects may build upon our experiences.

  6. Building robust chemical reaction mechanisms : next generation of automatic model construction software

    E-Print Network [OSTI]

    Song, Jing, 1972-

    2004-01-01T23:59:59.000Z

    Building proper reaction mechanisms is crucial to model the system dynamic properties for many industrial processes with complex chemical reaction phenomena. Because of the complexity of a reaction mechanism, computer-aided ...

  7. Chemo -- Dynamical evolution of disk galaxies, smoothed particles hydrodynamics approach

    E-Print Network [OSTI]

    Peter Berczik

    1998-10-20T23:59:59.000Z

    A new Chemo -- Dynamical Smoothed Particle Hydrodynamic (CD -- SPH) code is presented. The disk galaxy is described as a multi -- fragmented gas and star system, embedded into the cold dark matter halo. The star formation (SF) process, SNII, SNIa and PN events as well as chemical enrichment of gas have been considered within the framework of standard SPH model. Using this model we try to describe the dynamical and chemical evolution of triaxial disk -- like galaxies. It is found that such approach provides a realistic description of the process of formation, chemical and dynamical evolution of disk galaxies over the cosmological timescale.

  8. Chemical Engineering The George R. Brown School of Engineering

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    Equipment Design CENG 404 Process Design CENG 411/412 Thermodynamics I and II CENG 443 Chemical Engineering Lab II CENG 470 Process Dynamics and Control Mathematics MATH 101/102 Single Variable Calculus I, thermodynamics, kinetics, reactor design, process control, and process design. Course electives may be used

  9. Chemical Engineering The George R. Brown School of Engineering

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    CENG 401/402 Transport Phenomena I and II CENG 403 Equipment Design CENG 404 Process Design CENG 411/412 Thermodynamics I and II CENG 443 Chemical Engineering Lab II CENG 470 Process Dynamics and Control Mathematics, thermodynamics, kinetics, reactor design, process control, and process design. Course electives may be used

  10. Feasibility of Organizations -A Refinement of Chemical Organization Theory

    E-Print Network [OSTI]

    Hinze, Thomas

    Feasibility of Organizations - A Refinement of Chemical Organization Theory with Application to P a theorem providing a criteria for an unfeasible organization. This is a refinement of organization theory organization. Key words: reaction networks, constructive dynamical systems, chem- ical organization theory

  11. Spectroscopic probes of vibrationally excited molecules at chemically significant energies

    SciTech Connect (OSTI)

    Rizzo, T.R. [Univ. of Rochester, NY (United States)

    1993-12-01T23:59:59.000Z

    This project involves the application of multiple-resonance spectroscopic techniques for investigating energy transfer and dissociation dynamics of highly vibrationally excited molecules. Two major goals of this work are: (1) to provide information on potential energy surfaces of combustion related molecules at chemically significant energies, and (2) to test theoretical modes of unimolecular dissociation rates critically via quantum-state resolved measurements.

  12. 19 September 1997 Z .Chemical Physics Letters 276 1997 269273

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    19 September 1997 Z .Chemical Physics Letters 276 1997 269­273 On the threshold behavior in laser 8 April 1997; in final form 17 June 1997 Abstract The microscopic mechanisms of the fluence that determine the dynamics of laser ablation. q 1997 Elsevier Science B.V. The interaction of laser pulses

  13. NETL - Chemical Looping Reactor

    ScienceCinema (OSTI)

    None

    2014-06-26T23:59:59.000Z

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  14. NETL - Chemical Looping Reactor

    SciTech Connect (OSTI)

    None

    2013-07-24T23:59:59.000Z

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  15. Chemical and Biochemical

    E-Print Network [OSTI]

    Neimark, Alexander V.

    - nology fields where they can test the side effects of antibiotics or develop agricultural chemicals clean drinking water to a village in Kenya, a country experiencing its worst drought in 20 years," said and three collab- orating institutions to improve the manufacture of pharmaceutical, food, and agricultural

  16. Viscous Flow Over a Chemically Patterned Surface

    E-Print Network [OSTI]

    J. E. Sprittles; Y. D. Shikhmurzaev

    2009-04-07T23:59:59.000Z

    The classical fluid dynamics boundary condition of no-slip suggests that variation in the wettability of a solid should not affect the flow of an adjacent liquid. However experiments and molecular dynamics simulations indicate that this is not the case. In this paper we show how flow over a solid substrate with variations of wettability can be described in a continuum framework using the interface formation theory developed earlier. Results demonstrate that a shear flow over a perfectly flat solid surface is disturbed by a change in its wettability, i.e. by a change in the chemistry of the solid substrate. The magnitude of the effect is shown to be proportional to cos(t1)-cos(t2) where t1 and t2 are the equilibrium contact angles that a liquid-gas free surface would form with the two chemically different parts of the solid surface.

  17. Simple Dynamic Gasifier Model That Runs in Aspen Dynamics

    SciTech Connect (OSTI)

    Robinson, P.J.; Luyben, W.L. [Lehigh University, Bethlehem, PA (United States). Dept. of Chemical Engineering

    2008-10-15T23:59:59.000Z

    Gasification (or partial oxidation) is a vital component of 'clean coal' technology. Sulfur and nitrogen emissions can be reduced, overall energy efficiency is increased, and carbon dioxide recovery and sequestration are facilitated. Gasification units in an electric power generation plant produce a fuel for driving combustion turbines. Gasification units in a chemical plant generate gas, which can be used to produce a wide spectrum of chemical products. Future plants are predicted to be hybrid power/chemical plants with gasification as the key unit operation. The widely used process simulator Aspen Plus provides a library of models that can be used to develop an overall gasifier model that handles solids. So steady-state design and optimization studies of processes with gasifiers can be undertaken. This paper presents a simple approximate method for achieving the objective of having a gasifier model that can be exported into Aspen Dynamics. The basic idea is to use a high molecular weight hydrocarbon that is present in the Aspen library as a pseudofuel. This component should have the same 1:1 hydrogen-to-carbon ratio that is found in coal and biomass. For many plantwide dynamic studies, a rigorous high-fidelity dynamic model of the gasifier is not needed because its dynamics are very fast and the gasifier gas volume is a relatively small fraction of the total volume of the entire plant. The proposed approximate model captures the essential macroscale thermal, flow, composition, and pressure dynamics. This paper does not attempt to optimize the design or control of gasifiers but merely presents an idea of how to dynamically simulate coal gasification in an approximate way.

  18. Electronic Spectroscopy & Dynamics

    SciTech Connect (OSTI)

    Mark Maroncelli, Nancy Ryan Gray

    2010-06-08T23:59:59.000Z

    The Gordon Research Conference (GRC) on Electronic Spectroscopy and Dynamics was held at Colby College, Waterville, NH from 07/19/2009 thru 07/24/2009. The Conference was well-attended with participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. The GRC on Electronic Spectroscopy & Dynamics showcases some of the most recent experimental and theoretical developments in electronic spectroscopy that probes the structure and dynamics of isolated molecules, molecules embedded in clusters and condensed phases, and bulk materials. Electronic spectroscopy is an important tool in many fields of research, and this GRC brings together experts having diverse backgrounds in physics, chemistry, biophysics, and materials science, making the meeting an excellent opportunity for the interdisciplinary exchange of ideas and techniques. Topics covered in this GRC include high-resolution spectroscopy, biological molecules in the gas phase, electronic structure theory for excited states, multi-chromophore and single-molecule spectroscopies, and excited state dynamics in chemical and biological systems.

  19. Appendix G. Chemicals Appendix G. Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    actions of humans. Building materials used for the construction of homes may contain chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals. Through the use of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people

  20. Appendix G: Chemicals Appendix G: Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    actions of humans. Building materials used for the construction of homes may contain chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals. Through the use of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people

  1. Appendix H: Chemicals Appendix H: Chemicals H-3

    E-Print Network [OSTI]

    Pennycook, Steve

    actions of humans. Building materials used for the construction of homes may contain chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals. Through the use of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people

  2. Appendix B: Chemicals Appendix B: Chemicals B-3

    E-Print Network [OSTI]

    Pennycook, Steve

    such as pharmaceuticals, building materials, housewares, pesticides, and industrial chemicals. Through the use materials used for the construction of homes may contain chemicals such as formaldehyde (in some insulation of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people

  3. Complex Dynamics

    E-Print Network [OSTI]

    Complex Dynamics Bernardo Da Costa, Koushik Ramachandran, Jingjing Qu, and I had a two semester learning seminar in complex analysis and potential†...

  4. AGRI-SCIENCE CHEMICAL BIOLOGY

    E-Print Network [OSTI]

    photosynthetic efficiency Improve chemical agronomic and agro-ecological control measures Modelling through translation of chemical biology tools and technologies Control weeds, disease and pests Minimise a platform to steer future research and policy directions. ∑ Encourage external outreach to engage

  5. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01T23:59:59.000Z

    Radioactive Hazardous or Other Location LBL On-Site Bldgs.hazardous chemicals usedin the laboratory: and (v} The locationhazardous chemicals are present: and. (irl}The location and

  6. CHEMICAL STORAGE: MYTHS VERSUS REALITY

    SciTech Connect (OSTI)

    Simmons, F

    2007-03-19T23:59:59.000Z

    A large number of resources explaining proper chemical storage are available. These resources include books, databases/tables, and articles that explain various aspects of chemical storage including compatible chemical storage, signage, and regulatory requirements. Another source is the chemical manufacturer or distributor who provides storage information in the form of icons or color coding schemes on container labels. Despite the availability of these resources, chemical accidents stemming from improper storage, according to recent reports (1) (2), make up almost 25% of all chemical accidents. This relatively high percentage of chemical storage accidents suggests that these publications and color coding schemes although helpful, still provide incomplete information that may not completely mitigate storage risks. This manuscript will explore some ways published storage information may be incomplete, examine the associated risks, and suggest methods to help further eliminate chemical storage risks.

  7. Devices for collecting chemical compounds

    DOE Patents [OSTI]

    Scott, Jill R; Groenewold, Gary S

    2013-12-24T23:59:59.000Z

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  8. Cotton Harvest-Aid Chemicals.

    E-Print Network [OSTI]

    Metzer, Robert B.; Supak, James

    1987-01-01T23:59:59.000Z

    of Application Managing Harvest-Aid Program Secondary Growth Insect Control Care of Equipment Safety with Chemicals Guide for Using Cotton Harvest Aids Defoliants Desiccants Mixtures Plant Regulators-Conditioners 3 3 4 4 4 4 5 5 6 7 7 COTTON... HARVEST-AID CHEMICALS Robert B. Metzer and James Supak* As the name implies, harvest-aid chemicals pre pare the cotton crop for harvest by reducing foliage and plant moisture that interfere with harvesting operations. Harvest-aid chemicals...

  9. Dynamic imaging with electron microscopy

    ScienceCinema (OSTI)

    Campbell, Geoffrey; McKeown, Joe; Santala, Melissa

    2014-05-30T23:59:59.000Z

    Livermore researchers have perfected an electron microscope to study fast-evolving material processes and chemical reactions. By applying engineering, microscopy, and laser expertise to the decades-old technology of electron microscopy, the dynamic transmission electron microscope (DTEM) team has developed a technique that can capture images of phenomena that are both very small and very fast. DTEM uses a precisely timed laser pulse to achieve a short but intense electron beam for imaging. When synchronized with a dynamic event in the microscope's field of view, DTEM allows scientists to record and measure material changes in action. A new movie-mode capability, which earned a 2013 R&D 100 Award from R&D Magazine, uses up to nine laser pulses to sequentially capture fast, irreversible, even one-of-a-kind material changes at the nanometer scale. DTEM projects are advancing basic and applied materials research, including such areas as nanostructure growth, phase transformations, and chemical reactions.

  10. PARALLEL DYNAMICMESH LAGRANGIAN METHOD FOR SIMULATION FLOWS WITH DYNAMIC INTERFACES

    E-Print Network [OSTI]

    Antaki, James F.

    the aerospace, automotive, biomedical, chemical, marine, materials, wind engineering sciences. These include, material description motion results in dynamic meshes, become hopelessly distorted unless regularly large≠amplitude vibrations such flexible aerodynamic components high aspect wings blades; mixtures

  11. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01T23:59:59.000Z

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  12. CHEMICAL HYGIENE LAB SPECIFIC INFORMATION

    E-Print Network [OSTI]

    Bigelow, Stephen

    1 CHEMICAL HYGIENE PLAN (CHP) LAB SPECIFIC INFORMATION & STANDARD OPERATING PROCEDURES (SOPs____________________19 #12;3 Introduction 12/4/2013 This is the Chemical Hygiene Plan (CHP) for the Materials Research University of California at Santa Barbara Spectroscopy Department Chemical Hygiene Plan NMR and EPR

  13. CHEMICAL HYGIENE LAB SPECIFIC INFORMATION

    E-Print Network [OSTI]

    Bigelow, Stephen

    1 CHEMICAL HYGIENE PLAN (CHP) LAB SPECIFIC INFORMATION & STANDARD OPERATING PROCEDURES (SOPs______________________19 #12;3 Introduction 10/23/09 This is the Chemical Hygiene Plan (CHP) for the Materials Research Department Chemical Hygiene Plan NMR Laboratory Form Version 8/6/98 1. General Laboratory Information

  14. Chemical & Engineering Materials | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical & Engineering Materials SHARE Chemical and Engineering Materials Neutron-based research at SNS and HFIR in Chemical and Engineering Materials strives to understand the...

  15. Earth materials and earth dynamics

    SciTech Connect (OSTI)

    Bennett, K; Shankland, T. [and others

    2000-11-01T23:59:59.000Z

    In the project ''Earth Materials and Earth Dynamics'' we linked fundamental and exploratory, experimental, theoretical, and computational research programs to shed light on the current and past states of the dynamic Earth. Our objective was to combine different geological, geochemical, geophysical, and materials science analyses with numerical techniques to illuminate active processes in the Earth. These processes include fluid-rock interactions that form and modify the lithosphere, non-linear wave attenuations in rocks that drive plate tectonics and perturb the earth's surface, dynamic recrystallization of olivine that deforms the upper mantle, development of texture in high-pressure olivine polymorphs that create anisotropic velocity regions in the convecting upper mantle and transition zone, and the intense chemical reactions between the mantle and core. We measured physical properties such as texture and nonlinear elasticity, equation of states at simultaneous pressures and temperatures, magnetic spins and bonding, chemical permeability, and thermal-chemical feedback to better characterize earth materials. We artificially generated seismic waves, numerically modeled fluid flow and transport in rock systems and modified polycrystal plasticity theory to interpret measured physical properties and integrate them into our understanding of the Earth. This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL).

  16. Chemical sensing flow probe

    DOE Patents [OSTI]

    Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

    1999-01-01T23:59:59.000Z

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

  17. Chemical sensor system

    DOE Patents [OSTI]

    Darrow, Christopher B. (Pleasanton, CA); Satcher, Jr., Joe H. (Modesto, CA); Lane, Stephen M. (Oakland, CA); Lee, Abraham P. (Walnut Creek, CA); Wang, Amy W. (Berkeley, CA)

    2002-01-01T23:59:59.000Z

    An implantable chemical sensor system for medical applications is described which permits selective recognition of an analyte using an expandable biocompatible sensor, such as a polymer, that undergoes a dimensional change in the presence of the analyte. The expandable polymer is incorporated into an electronic circuit component that changes its properties (e.g., frequency) when the polymer changes dimension. As the circuit changes its characteristics, an external interrogator transmits a signal transdermally to the transducer, and the concentration of the analyte is determined from the measured changes in the circuit. This invention may be used for minimally invasive monitoring of blood glucose levels in diabetic patients.

  18. Chemical kinetics modeling

    SciTech Connect (OSTI)

    Westbrook, C.K.; Pitz, W.J. [Lawrence Livermore National Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    This project emphasizes numerical modeling of chemical kinetics of combustion, including applications in both practical combustion systems and in controlled laboratory experiments. Elementary reaction rate parameters are combined into mechanisms which then describe the overall reaction of the fuels being studied. Detailed sensitivity analyses are used to identify those reaction rates and product species distributions to which the results are most sensitive and therefore warrant the greatest attention from other experimental and theoretical research programs. Experimental data from a variety of environments are combined together to validate the reaction mechanisms, including results from laminar flames, shock tubes, flow systems, detonations, and even internal combustion engines.

  19. Carbon Emissions: Chemicals Industry

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321Spain (Million Cubic Feet) Cameron,Chemicals

  20. Enhanced Chemical Cleaning

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan Departmentof EnergyPublic LawEnergyEnhanced Chemical Cleaning

  1. Sandia Energy - Chemical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclear Press ReleasesInApplied & ComputationalBriefChemical

  2. Baytown Xylene Fractionation Energy Reduction using Dynamic Matrix Control (DMC)

    E-Print Network [OSTI]

    Hokanson, D.

    2014-01-01T23:59:59.000Z

    Technology Conference New Orleans, LA. May 20-23, 2014 2Outline ē Baytown Chemical Complex ē Xylene Fractionation Overview ē Dynamic Matrix Control ē Results ē Benefits/Wrap-Up ESL-IE-14-05-33 Proceedings of the Thrity-Sixth Industrial Energy Technology... Conference New Orleans, LA. May 20-23, 2014 3Baytown Chemical / Refining Complex ExxonMobil Baytown Refining & Chemical Complex ē One of worldís largest integrated, most technologically advanced petroleum/petrochemical complexes, in operation since 1919...

  3. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01T23:59:59.000Z

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  4. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01T23:59:59.000Z

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate intallation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  5. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01T23:59:59.000Z

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to faciliate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  6. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1981-01-01T23:59:59.000Z

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  7. Theoretical studies of the dynamics of chemical reactions

    SciTech Connect (OSTI)

    Wagner, A.F. [Argonne National Laboratory, IL (United States)

    1993-12-01T23:59:59.000Z

    Recent research effort has focussed on several reactions pertinent to combustion. The formation of the formyl radical from atomic hydrogen and carbon monoxide, recombination of alkyl radicals and halo-alkyl radicals with halogen atoms, and the thermal dissociation of hydrogen cyanide and acetylene have been studied by modeling. In addition, the inelastic collisions of NCO with helium have been investigated.

  8. Microsoft Word - Dynamic Chemical Imaging at Nanoscale bh

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to engineers striving to reduce the amount of inactive materials such as conductive additives and binders so as to increase the energy density of a system. In this study,...

  9. THE DYNAMICS OF CHEMICAL REACTORS WITH HEAT INTEGRATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1958 analyzed the stability of the steady states of autothermal reactors. Author to whom correspondence behavior in autothermal reactors was pre- sented by Reilly an Schmitz 1966,1967 and Pareja and Reilly 1969

  10. THE DYNAMICS OF CHEMICAL REACTORS WITH HEAT INTEGRATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    ) and Aris and Amundson (1958) analyzed the stability of the steady states of autothermal reactors. \\Lambda: 47≠7359≠4080. Limit cycle behavior in autothermal reactors was pre≠ sented by Reilly an Schmitz (1966

  11. Chemical and Dynamical Characteristics of Stratosphere-Troposphere Exchange†

    E-Print Network [OSTI]

    Homeyer, Cameron Ross

    2012-10-19T23:59:59.000Z

    frequent irreversible transport associated with tropospheric intrusions. We also present a 30-year climatology (1981-2010) of anticyclonically and cyclonically sheared Rossby wave-breaking events along the boundary of the tropics in the 350-500 K potential...

  12. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGENDDepartmentSeptember 20092009 | Department

  13. Microsoft Word - Dynamic Chemical Imaging at Nanoscale bh

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLove Your1 SECTION A. Project Title:404 2.1 Advanced TokamakDraft)

  14. Chemicals for Plant Disease Control at Home

    E-Print Network [OSTI]

    Ong, Kevin

    2007-10-30T23:59:59.000Z

    common chemical names and the corresponding chemical name for each active ingredient. Kevin Ong* ?Assistant Professor and Extension Plant Pathologist, The Texas A&M University System Table 1. Plant disease control chemicals. Common name Chemical name 1...

  15. Chemical engineers design, control and optimize large-scale chemical, physicochemical and

    E-Print Network [OSTI]

    Rohs, Remo

    , Biochemical, Environmental, Petroleum Engineering and Nantoechnology. CHEMICAL&MATERIALSSCIENCE CHE OVERVIEW of Science 131 units · Chemical Engineering (Petroleum) Bachelor of Science 136 units · Chemical Engineering38 Chemical engineers design, control and optimize large-scale chemical, physicochemical

  16. MASS SPECTROMETRIC APPROACHES FOR CHEMICAL CHARACTERISATION OF...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MASS SPECTROMETRIC APPROACHES FOR CHEMICAL CHARACTERISATION OF ATMOSPHERIC AEROSOLS: CRITICAL REVIEW OF MOST RECENT ADVANCES. MASS SPECTROMETRIC APPROACHES FOR CHEMICAL...

  17. NATIONAL INSTITUTES OF Chemical Hygiene Plan

    E-Print Network [OSTI]

    Bandettini, Peter A.

    NATIONAL INSTITUTES OF HEALTH Chemical Hygiene Plan Division of Occupational Health Chemical Hygiene Plan Evaluation and Record Keeping

  18. Introduction Linear Dynamics

    E-Print Network [OSTI]

    Zeghib, Abdelghani

    Introduction Results Linear Dynamics Lorentz Dynamics Actions of discrete groups on stationary Piccione) Geodeycos Meeting, Lyon, 28-30 April 2010 Abdelghani Zeghib Dynamics on Lorentz manifolds #12;Introduction Results Linear Dynamics Lorentz Dynamics Motivations and questions Examples 1 Introduction

  19. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS ≠ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177≠217, 1997. Abstract Distillation column dynamics and control has been viewed these, the feasibility of using the distillate≠bottom structure for control (which was believed

  20. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed, the feasibility of using the distillate-bottomstructure for control which was believed to be impossible

  1. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2750-C Segerstrom Ave., Santa Ana, CA 92704)

    1980-01-01T23:59:59.000Z

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer. The heat pump part of the system heats or cools a house or other structure through a combination of evaporation and absorption or, conversely, condensation and desorption, in a pair of containers. A set of automatic controls change the system for operation during winter and summer months and for daytime and nighttime operation to satisfactorily heat and cool a house during an entire year. The absorber chamber is subjected to solar heating during regeneration cycles and is covered by one or more layers of glass or other transparent material. Daytime home air used for heating the home is passed at appropriate flow rates between the absorber container and the first transparent cover layer in heat transfer relationship in a manner that greatly reduce eddies and resultant heat loss from the absorbant surface to ambient atmosphere.

  2. Introduction to the application of the dynamical systems theory in the study of the dynamics of cosmological models of dark energy

    E-Print Network [OSTI]

    GarcŪa-Salcedo, Ricardo; Horta-Rangel, Francisco A; Quiros, Israel; Sanchez-GuzmŠn, Daniel

    2015-01-01T23:59:59.000Z

    The theory of the dynamical systems is a very complex subject which has brought several surprises in the recent past in connection with the theory of chaos and fractals. The application of the tools of the dynamical systems in cosmological settings is less known in spite of the amount of published scientific papers on this subject. In this paper a -- mostly pedagogical -- introduction to the application in cosmology of the basic tools of the dynamical systems theory is presented. It is shown that, in spite of their amazing simplicity, these allow to extract essential information on the asymptotic dynamics of a wide variety of cosmological models. The power of these tools is illustrated within the context of the so called $\\Lambda$CDM and scalar field models of dark energy. This paper is suitable for teachers, undergraduate and postgraduate students from physics and mathematics disciplines.

  3. SIAM conference on applications of dynamical systems

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    A conference (Oct.15--19, 1992, Snowbird, Utah; sponsored by SIAM (Society for Industrial and Applied Mathematics) Activity Group on Dynamical Systems) was held that highlighted recent developments in applied dynamical systems. The main lectures and minisymposia covered theory about chaotic motion, applications in high energy physics and heart fibrillations, turbulent motion, Henon map and attractor, integrable problems in classical physics, pattern formation in chemical reactions, etc. The conference fostered an exchange between mathematicians working on theoretical issues of modern dynamical systems and applied scientists. This two-part document contains abstracts, conference program, and an author index.

  4. Chemical substructure analysis in toxicology

    SciTech Connect (OSTI)

    Beauchamp, R.O. Jr. [Center for Information on Toxicology and Environment, Raleigh, NC (United States)

    1990-12-31T23:59:59.000Z

    A preliminary examination of chemical-substructure analysis (CSA) demonstrates the effective use of the Chemical Abstracts compound connectivity file in conjunction with the bibliographic file for relating chemical structures to biological activity. The importance of considering the role of metabolic intermediates under a variety of conditions is illustrated, suggesting structures that should be examined that may exhibit potential activity. This CSA technique, which utilizes existing large files accessible with online personal computers, is recommended for use as another tool in examining chemicals in drugs. 2 refs., 4 figs.

  5. FAQS Reference Guide- Chemical Processing

    Broader source: Energy.gov [DOE]

    This reference guide addresses the competency statements in the February 2010 edition of DOE-STD-1176-2010, Chemical Processing Functional Area Qualification Standard.

  6. Process Intensification - Chemical Sector Focus

    Broader source: Energy.gov (indexed) [DOE]

    cost and risk in chemical manufacturing facilities. 24 25 At the core of PI is the optimization of process performance by focusing on molecular level kinetics, 26...

  7. Reaction dynamics in polyatomic molecular systems

    SciTech Connect (OSTI)

    Miller, W.H. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    The goal of this program is the development of theoretical methods and models for describing the dynamics of chemical reactions, with specific interest for application to polyatomic molecular systems of special interest and relevance. There is interest in developing the most rigorous possible theoretical approaches and also in more approximate treatments that are more readily applicable to complex systems.

  8. Chemical Biology Chemical Screening for Hair Cell Loss and Protection

    E-Print Network [OSTI]

    Rubel, Edwin

    Chemical Biology Chemical Screening for Hair Cell Loss and Protection in the Zebrafish Lateral Line Rubel,1,2 and David W. Raible1,4 Abstract In humans, most hearing loss results from death of hair cells, the mechanosensory receptors of the inner ear. Two goals of current hearing research are to protect hair cells from

  9. Chemical Evolution in Omega Centauri

    E-Print Network [OSTI]

    Verne V. Smith

    2003-10-22T23:59:59.000Z

    The globular cluster Omega Centauri displays evidence of a complex star formation history and peculiar internal chemical evolution, setting it apart from essentially all other globular clusters of the Milky Way. In this review we discuss the nature of the chemical evolution that has occurred within Omega Cen and attempt to construct a simple scenario to explain its chemistry.

  10. CHEMICAL HYGIENE LAB SPECIFIC INFORMATION

    E-Print Network [OSTI]

    Sideris, Thomas C.

    1 CHEMICAL HYGIENE PLAN (CHP) LAB SPECIFIC INFORMATION & STANDARD OPERATING PROCEDURES (SOPs____________________19 #12;3 Introduction 12/4/2013 This is the Chemical Hygiene Plan (CHP) for the Materials Research Hygiene Plan NMR and EPR Laboratory Form Version 8/6/98 1. General Laboratory Information Laboratory Name

  11. Method of forming a chemical composition

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); Klingler, Kerry M. (Idaho Falls, ID); Zollinger, William T. (Idaho Falls, ID); Wendt, Kraig M. (Idaho Falls, ID)

    2007-10-09T23:59:59.000Z

    A method of forming a chemical composition such as a chemical hydride is described and which includes the steps of selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of hydrogen; and exposing the selected composition to an amount of ionizing radiation to encourage the changing of the chemical bonds of the selected composition, and chemically reacting the selected composition with the source of hydrogen to facilitate the formation of a chemical hydride.

  12. Chemical analysis quality assurance at the Idaho Chemical Processing Plant

    SciTech Connect (OSTI)

    Hand, R.L.; Anselmo, R.W.; Black, D.B.; Jacobson, J.J.; Lewis, L.C.; Marushia, P.C.; Spraktes, F.W.; Zack, N.R.

    1985-01-01T23:59:59.000Z

    The Idaho Chemical Processing Plant (ICPP) is a uranium reprocessing facility operated by Westinghouse Idaho Nuclear Company for the Department of Energy at the Idaho National Engineering Laboratory (INEL). The chemical analysis support required for the plant processes is provided by a chemical analysis staff of 67 chemists, analysts, and support personnel. The documentation and defense of the chemical analysis data at the ICPP has evolved into a complete chemical analysis quality assurance program with training/qualification and requalification, chemical analysis procedures, records management and chemical analysis methods quality control as major elements. The quality assurance procedures are implemented on a central analytical computer system. The individual features provided by the computer system are automatic method selection for process streams, automation of method calculations, automatic assignment of bias and precision estimates at analysis levels to all method results, analyst specific daily requalification or with-method-use requalification, untrained or unqualified analyst method lockout, statistical testing of process stream results for replicate agreement, automatic testing of process results against pre-established operating, safety, or failure limits at varying confidence levels, and automatic transfer and report of analysis data plus the results of all statistical testing to the Production Department.

  13. 45 2014-15 Suggested Course Plan ChemICal (polYmeRs/maTeRIals)

    E-Print Network [OSTI]

    Zhou, Chongwu

    Processes ChE 405: Probability and Statistics for CHE or ISE 460: Engineering Economy or BUAD 301: Technical Dynamics ChE 472: Polymer Science & Engineering ChE 476: Chemical Engineering Materials or mASC 310. V GEN ED. VI engIneeRIng (60 unITs) ChE 120: Intro. to Chemical Engineering ChE 205: Numerical

  14. Semiclassical molecular dynamics simulations of excited state double-proton transfer in 7-azaindole dimers

    E-Print Network [OSTI]

    Miller, William H.

    Semiclassical molecular dynamics simulations of excited state double-proton transfer in 7-azaindole chemical re- action. In this paper we report the first application of molecular dynamics simulation methods to model the excited state double-proton transfer dynamics involved in the tau- tomerization reaction

  15. Chemical Hydrogen Storage Center Center of Excellence

    E-Print Network [OSTI]

    Carver, Jeffrey C.

    Chemical Hydrogen Storage Center Center of Excellence for Chemical Hydrogen Storage William Tumas proprietary or confidential information #12;2 Chemical Hydrogen Storage Center Overview Project Start Date: FY Barriers Addressed #12;3 Chemical Hydrogen Storage Center Chemical Hydrogen Storage Center National

  16. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1993-07-06T23:59:59.000Z

    Coatings and sensors are described having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  17. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, Gregory C. (P.O. Box 763, Cedar Crest, NM 87008); Brinker, C. Jeffrey (14 Eagle Nest Dr., NE., Albuquerque, NM 87122); Doughty, Daniel H. (11724 Woodmar La., NE., Albuquerque, NM 87111); Bein, Thomas (1114 Princeton Dr., NE., Albuquerque, NM 87106); Moller, Karin (1114 Princeton Dr., NE., Albuquerque, NM 87106)

    1993-01-01T23:59:59.000Z

    Coatings and sensors having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  18. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, Gregory C. (Bernalillo County, NM); Brinker, C. Jeffrey (Albuquerque, NM); Doughty, Daniel H. (Albuquerque, NM); Bein, Thomas (Albuquerque, NM); Moller, Karin (Albuquerque, NM)

    1996-01-01T23:59:59.000Z

    Coatings and sensors having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  19. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1996-12-31T23:59:59.000Z

    Coatings and sensors are disclosed having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided. 7 figs.

  20. Use of comparative genomics approaches to characterize interspecies differences in response to environmental chemicals: Challenges, opportunities, and research needs

    SciTech Connect (OSTI)

    Burgess-Herbert, Sarah L., E-mail: sarah.burgess@alum.mit.edu [American Association for the Advancement of Science (AAAS) Science and Technology Policy Fellow at the US Environmental Protection Agency (EPA), 2009Ė10 (United States); Euling, Susan Y. [National Center for Environmental Assessment, Office of Research and Development, US Environmental Protection Agency, Washington, DC 20460 (United States)

    2013-09-15T23:59:59.000Z

    A critical challenge for environmental chemical risk assessment is the characterization and reduction of uncertainties introduced when extrapolating inferences from one species to another. The purpose of this article is to explore the challenges, opportunities, and research needs surrounding the issue of how genomics data and computational and systems level approaches can be applied to inform differences in response to environmental chemical exposure across species. We propose that the data, tools, and evolutionary framework of comparative genomics be adapted to inform interspecies differences in chemical mechanisms of action. We compare and contrast existing approaches, from disciplines as varied as evolutionary biology, systems biology, mathematics, and computer science, that can be used, modified, and combined in new ways to discover and characterize interspecies differences in chemical mechanism of action which, in turn, can be explored for application to risk assessment. We consider how genetic, protein, pathway, and network information can be interrogated from an evolutionary biology perspective to effectively characterize variations in biological processes of toxicological relevance among organisms. We conclude that comparative genomics approaches show promise for characterizing interspecies differences in mechanisms of action, and further, for improving our understanding of the uncertainties inherent in extrapolating inferences across species in both ecological and human health risk assessment. To achieve long-term relevance and consistent use in environmental chemical risk assessment, improved bioinformatics tools, computational methods robust to data gaps, and quantitative approaches for conducting extrapolations across species are critically needed. Specific areas ripe for research to address these needs are recommended.

  1. Experimental characterization and chemical kinetics study of chemical looping combustion

    E-Print Network [OSTI]

    Chen, Tianjiao, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Chemical looping combustion (CLC) is one of the most promising technologies to achieve carbon capture in fossil fuel power generation plants. A novel rotary-bed reactor concept was proposed by Zhao et. al. [1] in 2013. It ...

  2. Dynamical transitions of turing patterns.

    SciTech Connect (OSTI)

    Kaper, H. G.; Wang, S.; Yari, M.; Mathematics and Computer Science; Indiana Univ.

    2009-01-01T23:59:59.000Z

    This paper is concerned with the formation and persistence of spatiotemporal patterns in binary mixtures of chemically reacting species, where one of the species is an activator, the other an inhibitor of the chemical reaction. The system of reaction-diffusion equations is reduced to a finite system of ordinary differential equations by a variant of the centre-manifold reduction method. The reduced system fully describes the local dynamics of the original system near transition points at the onset of instability. The attractor-bifurcation theory is used to give a complete characterization of the bifurcated objects in terms of the physical parameters of the problem. The results are illustrated for the Schnakenberg model.

  3. Non-planar chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P. (Albuquerque, NM); Adkins, Douglas R. (Albuquerque, NM); Sokolowski, Sara S. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM)

    2006-10-10T23:59:59.000Z

    A non-planar chemical preconcentrator comprises a high-surface area, low mass, three-dimensional, flow-through sorption support structure that can be coated or packed with a sorptive material. The sorptive material can collect and concentrate a chemical analyte from a fluid stream and rapidly release it as a very narrow temporal plug for improved separations in a microanalytical system. The non-planar chemical preconcentrator retains most of the thermal and fabrication benefits of a planar preconcentrator, but has improved ruggedness and uptake, while reducing sorptive coating concerns and extending the range of collectible analytes.

  4. Chemical and Biological Engineering Department Code 1 Department of Chemical & Biological Engineering

    E-Print Network [OSTI]

    Chemical and Biological Engineering Department Code 1 CODE of the Department of Chemical of Chemical & Biological Engineering. For clarity of presentation, some passages are copied directly from shall offer an undergraduate chemical and biological engineering program of technological, scientific

  5. Biomedical | Chemical & Biomolecular | Civil & Environmental | Electrical & Computer | Industrial | Mechanical | Petroleum Careers in Chemical Engineering

    E-Print Network [OSTI]

    Azevedo, Ricardo

    | Mechanical | Petroleum Careers in Chemical Engineering Career opportunities in chemical engineering that new chemical engineering graduates have an average starting salary of $67,600. The University from industry professionals and participate in activities that promote engineering. Chemical

  6. Introduction to Dynamic Distributed

    E-Print Network [OSTI]

    Roma "La Sapienza", Universitŗ di

    Introduction to Dynamic Distributed SystemsSystems #12;Outline Introduction Churn Building Applications in Dynamic Distributed Systems RegistersRegisters Eventual Leader election Connectivity in Dynamic Distributed Systems #12;Dynamic Distributed Systems: Context & Motivations Advent of Complex Distributed

  7. Flavor Dynamics

    E-Print Network [OSTI]

    Michael Murray; for the BRAHMS Collaboration

    2007-10-24T23:59:59.000Z

    The purpose of BRAHMS is to survey the dynamics of relativistic heavy ion (as well as pp and d-A) collisions over a very wide range of rapidity and transverse momentum. The sum of these data may give us a glimpse of the initial state of the system, its transverse and longitudinal evolution and how the nature of the system changes with time. Here I will concentrate on the origin and dynamics of the light flavors, i.e. the creation and transport of the up, down and strange quarks. The results presented here are certainly not the end of the story. It is my hope that in a few years new detectors will reveal the rapidity dependence of the charm and bottom quarks.

  8. DEPARTMENT OF ENVIRONMENTAL HEALTH & SAFETY CHEMICAL HYGIENE

    E-Print Network [OSTI]

    Firestone, Jeremy

    DEPARTMENT OF ENVIRONMENTAL HEALTH & SAFETY CHEMICAL HYGIENE PLAN #12, 2014 #12;University of Delaware Department of Environmental Health & Safety Chemical Hygiene) #12;University of Delaware Department of Environmental Health & Safety Chemical Hygiene Plan

  9. California Institute of Technology CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Faraon, Andrei

    California Institute of Technology CHEMICAL HYGIENE PLAN Caltech Environment, Health, and Safety: safety@caltech.edu Website: www.safety.caltech.edu #12;CHEMICAL HYGIENE PLAN ≠ AUGUST 2013 Page 2 of 45 CHEMICAL HYGIENE PLAN Table of Contents INTRODUCTION

  10. chemical (CHE) CHE overview programs available

    E-Print Network [OSTI]

    Rohs, Remo

    , Environmental, Manufacturing and Petroleum En- gineering. Programs Available · Chemical Engineering Bachelor Engineering (Environmental) Bachelor of Science 135 units · Chemical Engineering (Petroleum) Bachelor of Science 136 units · Chemical Engineering (Polymer Science) Bachelor of Science 136 units · Petroleum

  11. New Science for Chemicals Policy

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    of the State-of-the-Science of Endocrine Disruptors (WHO,461, 472 (2009). 17. NRC, Science and Decisions: AdvancingPOLICYFORUM SCIENCE AND REGULATION New Science for Chemicals

  12. Mass-sensitive chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P. (Albuquerque, NM); Adkins, Douglas R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM)

    2007-01-30T23:59:59.000Z

    A microfabricated mass-sensitive chemical preconcentrator actively measures the mass of a sample on an acoustic microbalance during the collection process. The microbalance comprises a chemically sensitive interface for collecting the sample thereon and an acoustic-based physical transducer that provides an electrical output that is proportional to the mass of the collected sample. The acoustic microbalance preferably comprises a pivot plate resonator. A resistive heating element can be disposed on the chemically sensitive interface to rapidly heat and release the collected sample for further analysis. Therefore, the mass-sensitive chemical preconcentrator can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  13. Chemo-Dynamical SPH code for evolution of star forming disk galaxies

    E-Print Network [OSTI]

    Peter Berczik

    1999-07-27T23:59:59.000Z

    A new Chemo-Dynamical Smoothed Particle Hydrodynamic (CD-SPH) code is presented. The disk galaxy is described as a multi-fragmented gas and star system, embedded in a cold dark matter halo with a rigid potential field. The star formation (SF) process, SNII, SNIa and PN events, and the chemical enrichment of gas, have all been considered within the framework of the standard SPH model, which we use to describe the dynamical and chemical evolution of triaxial disk-like galaxies. It is found that such approach provides a realistic description of the process of formation, chemical and dynamical evolution of disk galaxies over a cosmological timescale.

  14. Modeling the star formation in galaxies using the Chemo - dynamical SPH code

    E-Print Network [OSTI]

    Peter Berczik

    2000-07-19T23:59:59.000Z

    A new Chemo - Dynamical Smoothed Particle Hydrodynamic (CD - SPH) code is presented. The disk galaxy is described as a multi - fragmented gas and star system, embedded in a cold dark matter halo. The star formation (SF) process, SNII, SNIa and PN events as well as chemical enrichment of gas have been considered within the framework of the standard SPH model. Using this model we describe the dynamical and chemical evolution of triaxial disk - like galaxies. It is found that such approach provides a realistic description of the process of formation, chemical and dynamical evolution of disk galaxies over a cosmological timescale.

  15. CHEN 3600 Computer-Aided Chemical Engineering Chemical Engineering Department Notes 4

    E-Print Network [OSTI]

    Clement, Prabhakar

    CHEN 3600 ≠ Computer-Aided Chemical Engineering Chemical Engineering Department Notes 4 EWE-Aided Chemical Engineering Chemical Engineering Department Notes 4 EWE: "Engineering With Excel" Larsen Page 2 will be added using "cutting and pasting". #12;CHEN 3600 ≠ Computer-Aided Chemical Engineering Chemical

  16. Sandia National Laboratories: MOgene Green Chemicals LLC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOgene Green Chemicals LLC Sandia to Partner with MOgene Green Chemicals on ARPA-E REMOTE Project On October 2, 2013, in Energy, News, News & Events, Partnership, Research &...

  17. Multidimensional simulation and chemical kinetics development...

    Broader source: Energy.gov (indexed) [DOE]

    Developing chemical kinetic mechanisms and applying them to simulating engine combustion processes. deer09aceves.pdf More Documents & Publications Chemical Kinetic Research on...

  18. Sandia Researchers Develop Promising Chemical Technology for...

    Energy Savers [EERE]

    Sandia Researchers Develop Promising Chemical Technology for Energy Storage Sandia Researchers Develop Promising Chemical Technology for Energy Storage March 7, 2012 - 9:50am...

  19. Correlations Between Optical, Chemical and Physical Properties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Correlations Between Optical, Chemical and Physical Properties of Biomass Burn Aerosols. Correlations Between Optical, Chemical and Physical Properties of Biomass Burn Aerosols....

  20. Keeping Tabs on the World's Dangerous Chemicals

    Broader source: Energy.gov [DOE]

    Sandia chemical engineer Nancy Jackson has worked in laboratories around the world to help ensure that chemicals are used safely and kept secure.

  1. LANSCE | Lujan Center | Chemical & Sample Prep

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical & Sample Preparation For general questions, please contact the Lujan Center Chemical and Sample Preparation Laboratory responsible: Charles Kelsey | ckelsey@lanl.gov |...

  2. Chemically strengthened protection glasses for the applications of space solar cells

    SciTech Connect (OSTI)

    Wang, H. F., E-mail: whf2008@dhu.edu.cn [College of Material Science and Engineering, Donghua University, 2999 North Renmin Road, Songjiang District, Shanghai 201620 (China); Xing, G. Z., E-mail: guozhong.xing@unsw.edu.au; Zhang, L.; Li, S. [School of Materials Science and Engineering, The University of New South Wales, Sydney, New South Wales 2052 (Australia)] [School of Materials Science and Engineering, The University of New South Wales, Sydney, New South Wales 2052 (Australia); Wang, X. Y. [Department of Civil Engineering, Northeast Dianli University, Jilin 132012 (China)] [Department of Civil Engineering, Northeast Dianli University, Jilin 132012 (China); Zhang, L. L. [Zhuhai College of Jilin University, Zhuhai, Guangdong, 519041 (China)] [Zhuhai College of Jilin University, Zhuhai, Guangdong, 519041 (China)

    2014-04-15T23:59:59.000Z

    The effects of chemically strengthened processing and the ion beam irradiation on the mechanical characteristics of space solar cell protection glasses are investigated using dynamic mechanical analysis and micro hardness instrument; also the corresponding optical properties were analyzed by utilizing the UV/visible spectrophotometer. The results suggest that the flexural strength, fracture toughness and surface characteristics are enhanced via the chemical strengthening process. Importantly, such process has a trivial influence with ?0.2% degradation on the transparency of chemically strengthened glasses in the band range of 350 ? 1000 nm, while exhibits an excellent resistance on radiation damage by ion beams bombardment, demonstrating an outstanding durability in the space radiation environment.

  3. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Oliver, Douglas L.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Officer Biological (Accident Reports) 2204 Bioengineering 2965 #12;TABLE OF CONTENTS CHEMICAL HYGIENE PLAN (CHP) (4/2007) 1

  4. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Kim, Duck O.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals and Safety Numbers Research Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Human Resources (Accident Reports) 4589 Clinical Engineering 2964 #12;TABLE OF CONTENTS CHEMICAL HYGIENE

  5. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Kim, Duck O.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals and Safety Numbers Research Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Human Resources (Accident Reports) 4589 Bioengineering 2965 #12;TABLE OF CONTENTS CHEMICAL HYGIENE PLAN

  6. Northern California Nanotechnology Center Chemical Hygiene Plan

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Northern California Nanotechnology Center Chemical Hygiene Plan Rev 11/12 Page 1 Northern California Nanotechnology Center Chemical Hygiene Plan 1.0 Introduction Cal-OSHA (Title 8 CCR 5191) and campus regulations require that all laboratories have a written Chemical Hygiene Plan. The Chemical

  7. Chemical Hygiene Plan 1.0 Introduction

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Chemical Hygiene Plan 1.0 Introduction Satisfying Cal-OSHA (Title 8 CCR 5191) and campus regulations, this Chemical Hygiene Plan includes safety information specific to the Center for Nano and Micro chemicals and gasses available. If you have any questions about this Chemical Hygiene Plan, please email

  8. Dimension Reduction of Chemical Process Simulation Data

    E-Print Network [OSTI]

    Truemper, Klaus

    of a laminar methane/air combustion process described by 29 chemical species, 3 thermodynamic properties] for the computational effort carried out for some 3-dimensional models. Reduced chemical schemes, for example, ILDM-based memory as well. These chemical schemes are based on an analysis of chemical pathways that identifies

  9. Dynamic Testing of Gasifier Refractory

    SciTech Connect (OSTI)

    Michael D. Mann; Devdutt Shukla; Xi Hong; John P. Hurley

    2004-09-27T23:59:59.000Z

    The University of North Dakota (UND) Chemical Engineering Department in conjunction with the UND Energy & Environmental Research Center (EERC) have initiated a program to thoroughly examine the combined chemical (reaction and phase change) and physical (erosion) effects experienced by a variety of refractory materials during both normal operation and thermal cycling under slagging coal gasification conditions. The goal of this work is to devise a mechanism of refractory loss under these conditions. The controlled-atmospheric dynamic corrodent application furnace (CADCAF) is being utilized to simulate refractory/slag interactions under dynamic conditions that more realistically simulate the environment in a slagging coal gasifier than any of the static tests used previously by refractory manufacturers and researchers. Shakedown testing of the CADCAF has been completed. Samples of slag and refractory from the Tampa Electric Polk Power Station have been obtained for testing in the CADCAF. The slag has been dried and sieved to the size needed for our flowing slag corrosion tests. Screening tests are in currently in progress. Detailed analysis of corrosion rates from the first tests is in progress.

  10. Dynamic Testing of Gasifier Refractory

    SciTech Connect (OSTI)

    Michael D. Mann; Devdutt Shukla; John P. Hurley

    2003-09-27T23:59:59.000Z

    The University of North Dakota (UND) Chemical Engineering Department in conjunction with the UND Energy & Environmental Research Center (EERC) have initiated a program to thoroughly examine the combined chemical (reaction and phase change) and physical (erosion) effects experienced by a variety of refractory materials during both normal operation and thermal cycling under slagging coal gasification conditions. The goal of this work is to devise a mechanism of refractory loss under these conditions. The controlled-atmospheric dynamic corrodent application furnace (CADCAF) is being utilized to simulate refractory/slag interactions under dynamic conditions that more realistically simulate the environment in a slagging coal gasifier than any of the static tests used previously by refractory manufacturers and researchers. Shakedown testing of the CADCAF is in progress. Samples of slag and refractory from the Tampa Electric Polk Power Station have been obtained for testing in the CADCAF. The slag has been dried and sieved to the size needed for our flowing slag corrosion tests. Testing is expected to begin in October.

  11. Ultrafast studies of solution dynamics

    SciTech Connect (OSTI)

    Woodruff, W.H.; Dyer, R.B. [Los Alamos National Lab., NM (United States); Callender, R.H. [City Univ. of New York, NY (United States). Dept. of Physics

    1997-10-01T23:59:59.000Z

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Fast chemical dynamics generally must be initiated photochemically. This limits the applicability of modern laser methods for following the structural changes that occur during chemical and biological reactions to those systems that have an electronic chromophore that has a significant yield of photoproduct when excited. This project has developed a new and entirely general approach to ultrafast initiation of reactions in solution: laser-induced temperature jump (T-jump). The results open entire new fields of study of ultrafast molecular dynamics in solution. The authors have demonstrated the T-jump technique on time scales of 50 ps and longer, and have applied it to study of the fast events in protein folding. They find that a general lifetime of alpha-helix formation is ca 100 ns, and that tertiary folds (in apomyoglobin) form in ca 100 {mu}s.

  12. Chemical Hygiene and Safety Plan

    SciTech Connect (OSTI)

    Berkner, K.

    1992-08-01T23:59:59.000Z

    The objective of this Chemical Hygiene and Safety Plan (CHSP) is to provide specific guidance to all LBL employees and contractors who use hazardous chemicals. This Plan, when implemented, fulfills the requirements of both the Federal OSHA Laboratory Standard (29 CFR 1910.1450) for laboratory workers, and the Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) for non-laboratory operations (e.g., shops). It sets forth safety procedures and describes how LBL employees are informed about the potential chemical hazards in their work areas so they can avoid harmful exposures and safeguard their health. Generally, communication of this Plan will occur through training and the Plan will serve as a the framework and reference guide for that training.

  13. Uncoated microcantilevers as chemical sensors

    DOE Patents [OSTI]

    Thundat, Thomas G. (Knoxville, TN)

    2001-01-01T23:59:59.000Z

    A method and device are provided for chemical sensing using cantilevers that do not use chemically deposited, chemically specific layers. This novel device utilizes the adsorption-induced variation in the surfaces states on a cantilever. The methodology involves exciting charge carriers into or out of the surface states with photons having increasing discrete levels of energy. The excitation energy is provided as discrete levels of photon energy by scanning the wavelength of an exciting source that is illuminating the cantilever surface. When the charge carriers are excited into or out of the surface states, the cantilever bending changes due to changes in surface stress. The amount of cantilever bending with respect to an identical cantilever as a function of excitation energy is used to determine the energy levels associated with adsorbates.

  14. Thematic Questions about Chemical Elements Nature of the chemical elements

    E-Print Network [OSTI]

    Polly, David

    Environment Element Synthesis: Exploration of Chemical Fundamentals Element Synthesis and Isotopes ∑ Elemental thorium uranium Relativeabundance(Si=106)Relative Abundance in the Sun ∑ non-uniform trend G302.protons 90 234Th 145 #12;5 Alpha Decay - Loss of He Atom ∑ Decay of Uranium-238 to Thorium-234 G302

  15. Method for producing chemical energy

    DOE Patents [OSTI]

    Jorgensen, Betty S.; Danen, Wayne C.

    2004-09-21T23:59:59.000Z

    Fluoroalkylsilane-coated metal particles having a central metal core, a buffer layer surrounding the core, and a fluoroalkylsilane layer attached to the buffer layer are prepared by combining a chemically reactive fluoroalkylsilane compound with an oxide coated metal particle having a hydroxylated surface. The resulting fluoroalkylsilane layer that coats the particles provides them with excellent resistance to aging. The particles can be blended with oxidant particles to form energetic powder that releases chemical energy when the buffer layer is physically disrupted so that the reductant metal core can react with the oxidant.

  16. Recycling and surplus chemical programs

    SciTech Connect (OSTI)

    Harper, T.J.

    1993-05-01T23:59:59.000Z

    In 1988, 45 years of defense production came to a close at the US Department of Energy (DOE) Hanford Site. The mission of the Hanford Site was formally changed to environmental restoration and remediation. Westinghouse Hanford Company (WHC) is the management and operations (M&O) contractor leading the cleanup. Within the framework of future Site cleanup, Hanford recycling and surplus chemical programs are making a viable contribution today to waste minimization, diversion of materials from the waste stream, and setting a standard for future operations. This paper focuses on two successful efforts: paper recycling and surplus chemical sales.

  17. Hyperbolic Dynamics Todd Fisher

    E-Print Network [OSTI]

    Fisher, Todd

    Hyperbolic Dynamics Todd Fisher tfisher@math.umd.edu Department of Mathematics University of Maryland, College Park Hyperbolic Dynamics ≠ p. 1/3 #12;What is a dynamical system? Phase space X, elements possible states Hyperbolic Dynamics ≠ p. 2/3 #12;What is a dynamical system? Phase space X, elements

  18. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, Tuan (Knoxville, TN)

    1994-01-01T23:59:59.000Z

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation.

  19. Dynamic Testing of Gasifier Refractory

    SciTech Connect (OSTI)

    Michael D. Mann; John P. Hurley

    2002-09-27T23:59:59.000Z

    As DOE continues to advance new power systems, materials issues are often pivotal in determining the ultimate efficiency that can be reached in the system. Refractory performance in slagging gasification represents one of these issues. The University of North Dakota (UND) Chemical Engineering Department in conjunction with the UND Energy & Environmental Research Center (EERC) have initiated a program to thoroughly examine the combined chemical (reaction and phase change) and physical (erosion) effects experienced by a variety of refractory materials during both normal operation and thermal cycling under slagging coal gasification conditions. The goal of this work is to devise a mechanism of refractory loss under these conditions. The focus of the proposed work is to test the corrosion resistance of commercially available refractories to flowing coal slag, and propose the mechanisms of corrosion for the conditions studied. Corrosion is the degradation of material surfaces or grain boundaries by chemical reactions with melts, liquids, or gases, causing loss of material and consequently a decrease in strength of the structure. In order to develop methods of reducing corrosion, the microstructure that is attacked must be identified along with the mechanism and rates of attack. Once these are identified, methods for reducing corrosion rates can be developed. The work will take advantage of equipment and experimental techniques developed at the EERC under funding from several DOE programs. The controlled-atmospheric dynamic corrodent application furnace (CADCAF) will be utilized to simulate refractory/slag interactions under dynamic conditions that more realistically simulate the environment in a slagging coal gasifier than any of the static tests used previously by refractory manufacturers and researchers. To date, efforts have focused on final shakedown of the CADCAF and obtaining representative samples of slag and refractory for testing.

  20. POISON SPIDER FIELD CHEMICAL FLOOD PROJECT, WYOMING

    SciTech Connect (OSTI)

    Douglas Arnell; Malcolm Pitts; Jie Qi

    2004-11-01T23:59:59.000Z

    A reservoir engineering and geologic study concluded that approximate 7,852,000 bbls of target oil exits in Poison Spider. Field pore volume, OOIP, and initial oil saturation are defined. Potential injection water has a total dissolved solids content of 1,275 mg/L with no measurable divalent cations. If the Lakota water consistently has no measurable cations, the injection water does not require softening to dissolve alkali. Produced water total dissolved solids were 2,835 mg/L and less than 20 mg/L hardness as the sum of divalent cations. Produced water requires softening to dissolve chemicals. Softened produced water was used to dissolve chemicals in these evaluations. Crude oil API gravity varies across the field from 19.7 to 22.2 degrees with a dead oil viscosity of 95 to 280 cp at 75 F. Interfacial tension reductions of up to 21,025 fold (0.001 dyne/cm) were developed with fifteen alkaline-surfactant combinations at some alkali concentration. An additional three alkaline-surfactant combinations reduced the interfacial tension greater than 5,000 fold. NaOH generally produced the lowest interfacial tension values. Interfacial tension values of less than 0.021 dyne/cm were maintained when the solutions were diluted with produced water to about 60%. Na{sub 2}CO{sub 3} when mixed with surfactants did not reduce interfacial tension values to levels at which incremental oil can be expected. NaOH without surfactant interfacial tension reduction is at a level where some additional oil might be recovered. Most of the alkaline-surfactant-polymer solutions producing ultra low interfacial tension gave type II- phase behavior. Only two solutions produced type III phase behavior. Produced water dilution resulted in maintenance of phase type for a number of solutions at produced water dilutions exceeding 80% dilution. The average loss of phase type occurred at 80% dilution. Linear corefloods were performed to determine relative permeability end points, chemical-rock compatibility, polymer injectivity, dynamic chemical retention by rock, and recommended injected polymer concentration. Average initial oil saturation was 0.796 Vp. Produced water injection recovered 53% OOIP leaving an average residual oil saturation of 0.375 Vp. Poison Spider rock was strongly water-wet with a mobility ratio for produced water displacing the 280 cp crude oil of 8.6. Core was not sensitive to either alkali or surfactant injection. Injectivity increased 60 to 80% with alkali plus surfactant injection. Low and medium molecular weight polyacrylamide polymers (Flopaam 3330S and Flopaam 3430S) dissolved in either an alkaline-surfactant solution or softened produced water injected and flowed through Poison Spider rock. Recommended injected polyacrylamide concentration is 2,100 mg/L for both polymers for a unit mobility ratio. Radial corefloods were performed to evaluate oil recovery efficiency of different chemical solutions. Waterflood oil recovery averaged 46.4 OOIP and alkaline-surfactant-polymer flood oil recovery averaged an additional 18.1% OIP for a total of 64.6% OOIP. Oil cut change due to injection of a 1.5 wt% Na{sub 2}CO{sub 3} plus 0.05 wt% Petrostep B-100 plus 0.05 wt% Stepantan AS1216 plus 2100 mg/L Flopaam 3430S was from 2% to a peak of 23.5%. Additional study might determine the impact on oil recovery of a lower polymer concentration. An alkaline-surfactant-polymer flood field implementation outline report was written.

  1. Chemical Engineering and Chemical Technology 1 Faculty of Engineering, Department of

    E-Print Network [OSTI]

    skills and knowledge in the chemical, engineering and socio-economic aspects of drug and specialityChemical Engineering and Chemical Technology 1 Faculty of Engineering, Department of --Chemical Engineering and Chemical Technology This publication refers to the session 2009≠10. The information given

  2. Direct numerical simulation of a reacting turbulent channel flow with thermo-chemical ablation

    E-Print Network [OSTI]

    Nicoud, Franck

    species; 2) pyrolysis of the composite material resin (series of chemical reactions arising and multicompo- nent physics, multi-phase flow dynamics, thermo-structural mechanics of composite materials attack. Graphite and carbon-carbon composites are widely used because they offer excellent thermo

  3. On line chemical composition of analyzer development. Status report, February 1, 1992--April 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    This status report details progress made on the development of an on-line chemical analyzer. Dynamic studies of the distillation column, approval of testing plans, installation of a sample cell and raman analyzer, design of computerized control systems are described. Information on seminars and published papers is also included. (GHH)

  4. A timescale investigation of volatile chemical retention during hydrometeor freezing: Nonrime freezing

    E-Print Network [OSTI]

    Jacobson, Mark

    transport regime and is nonmonotonic due to the competing effects of ventilation on heat and mass transport--constituent transport and chemistry; 3354 Meteorology and Atmospheric Dynamics: Precipitation (1854); KEYWORDS: ice mechanism of precipitation development in cold clouds. Chemical solutes originally dissolved

  5. STABILITY OF CHEMICAL REACTIONS IN A CSTR WITH DELAYED RECYCLE STREAM

    E-Print Network [OSTI]

    Lehman, Brad

    STABILITY OF CHEMICAL REACTIONS IN A CSTR WITH DELAYED RECYCLE STREAM Brad Lehman' Departmentof. Severalof these papers alsoinclude the effectsof a recycle stream on the reactors dynamic response, and hence the cost of reaction, its use is widespread in industry. For example, recycling is almost always

  6. Extended range chemical sensing apparatus

    DOE Patents [OSTI]

    Hughes, Robert C. (Albuquerque, NM); Schubert, W. Kent (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    An apparatus for sensing chemicals over extended range of concentrations. In particular, first and second sensors each having separate, but overlapping ranges for sensing concentrations of hydrogen are provided. Preferably, the first sensor is a MOS solid state device wherein the metal electrode or gate is a nickel alloy. The second sensor is a chemiresistor comprising a nickel alloy.

  7. Qualitative Theory and Chemical Explanation

    E-Print Network [OSTI]

    Weisberg, Michael

    Abstract Roald Hoffmann and other theorists claim that we we ought to use highly idealized chemical models defend Hoffmann's norm for modelling. Many thanks to Michael Friedman, Robin Hendry, Ben Kerr, Deena to thank Roald Hoffmann who has been an in- spiring mentor and who's reflections on the philosophical

  8. CompositionsCHEMICAL Mallet Library

    E-Print Network [OSTI]

    CompositionsCHEMICAL Mallet Library Chairman's Corner Computer facility opens West wing renovation fall 1996 chemistry & biochemistry departmental newsletter The Chemistry Library has existed almost- istry Department and of the General Libraries, from modest beginnings in the late 19th century

  9. Extended range chemical sensing apparatus

    DOE Patents [OSTI]

    Hughes, R.C.; Schubert, W.K.

    1994-01-18T23:59:59.000Z

    An apparatus is described for sensing chemicals over extended range of concentrations. In particular, first and second sensors each having separate, but overlapping ranges for sensing concentrations of hydrogen are provided. Preferably, the first sensor is a MOS solid state device wherein the metal electrode or gate is a nickel alloy. The second sensor is a chemiresistor comprising a nickel alloy. 6 figures.

  10. The Microscopic Linear Dynamics

    E-Print Network [OSTI]

    Penny, Will

    The Microscopic Brain Will Penny Linear Dynamics Exponentials Matrix Exponential Eigendecomposition Dynamical Modes Nodes State Space Saddles Oscillations Spirals Centres Offsets Retinal Circuit Nullclines Stability Spiking Neurons Fitzhugh-Nagumo Nonlinear Dynamics Linearization Nonlinear Oscillation Excitable

  11. Molecular beam studies of reaction dynamics

    SciTech Connect (OSTI)

    Lee, Y.T. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    The major thrust of this research project is to elucidate detailed dynamics of simple elementary reactions that are theoretically important and to unravel the mechanism of complex chemical reactions or photochemical processes that play important roles in many macroscopic processes. Molecular beams of reactants are used to study individual reactive encounters between molecules or to monitor photodissociation events in a collision-free environment. Most of the information is derived from measurement of the product fragment energy, angular, and state distributions. Recent activities are centered on the mechanisms of elementary chemical reactions involving oxygen atoms with unsaturated hydrocarbons, the dynamics of endothermic substitution reactions, the dependence of the chemical reactivity of electronically excited atoms on the alignment of excited orbitals, the primary photochemical processes of polyatomic molecules, intramolecular energy transfer of chemically activated and locally excited molecules, the energetics of free radicals that are important to combustion processes, the infrared-absorption spectra of carbonium ions and hydrated hydronium ions, and bond-selective photodissociation through electric excitation.

  12. Dynamics of inelastic and reactive gas-surface collisions

    SciTech Connect (OSTI)

    Smoliar, L.A.

    1995-04-01T23:59:59.000Z

    The dynamics of inelastic and reactive collisions in atomic beam-surface scattering are presented. The inelastic scattering of hyperthermal rare gaseous atoms from three alkali halide surfaces (LiF, NaCl, GI)was studied to understand mechanical energy transfer in unreactive systems. The dynamics of the chemical reaction in the scattering of H(D) atoms from the surfaces of LIF(001) and the basal plane of graphite were also studied.

  13. Protein Dynamics and Biocatalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protein Dynamics and Biocatalysis Protein Dynamics and Biocatalysis 1998 Annual Report Grand Challenge Projects biocatalysis.gif A model of the Michaelis complex for the TEM-1...

  14. Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds

    E-Print Network [OSTI]

    Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds Awards Home of Catalysis Science & Technology (Probationary). Chemical & Engineering Or Petroleum Chemistry February 1, 2010 Volume 88, Number 5 p. 42 Sponsored by the George A. Olah Endowment

  15. Chemical engineers design, control and optimize large-scale chemical, physicochemical and

    E-Print Network [OSTI]

    Rohs, Remo

    Science, Biochemical, Environmental and Petroleum Engineering. CHEMICAL & MATERIALS SCIENCE CHE OVERVIEW (Environmental) Bachelor of Science 135 units Chemical Engineering (Petroleum) Bachelor of Science 136 units Chemical Engineering (Polymer Science) Bachelor of Science 136 units Petroleum Engineering minor

  16. CHEMICAL ABUNDANCES IN CLUSTERS OF GALAXIES

    E-Print Network [OSTI]

    Francesca Matteucci; Brad K. Gibson

    1995-03-14T23:59:59.000Z

    We study the origin of iron and alpha-elements (O, Mg, Si) in clusters of galaxies. In particular, we discuss the [O/Fe] ratio and the iron mass-to-luminosity ratio in the intracluster medium (ICM) and their link to the chemical and dynamical evolution of elliptical and lenticular galaxies. We adopt a detailed model of galactic evolution incorporating the development of supernovae- driven galactic winds which pollute the ICM with enriched ejecta. We demonstrate \\it quantitatively \\rm the crucial dependence upon the assumed stellar initial mass function in determining the evolution of the mass and abundances ratios of heavy elements in typical model ICMs. We show that completely opposite behaviours of [alpha/Fe] ratios (\\ie positive versus negative ratios) can be obtained by varying the initial mass function without altering the classic assumptions regarding type Ia supernovae progenitors or their nucleosynthesis. Our results indicate that models incorporating somewhat flatter-than-Salpeter initial mass functions (ie x approx 1, as opposed to x=1.35) are preferred, provided the intracluster medium iron mass-to-luminosity ratio, preliminary [alpha/Fe]>0 ASCA results, and present-day type Ia supernovae rates, are to be matched. A simple Virgo cluster simulation which adheres to these constraints shows that approx 70% of the measured ICM iron mass has its origin in type II supernovae, with the remainder being synthesized in type Ia systems.

  17. Semiclassical analysis of quantum dynamics

    E-Print Network [OSTI]

    Siyang Yang

    2011-11-15T23:59:59.000Z

    Simulating the molecular dynamics (MD) using classical or semi-classical trajectories provides important details for the understanding of many chemical reactions, protein folding, drug design, and solvation effects. MD simulations using trajectories have achieved great successes in the computer simulations of various systems, but it is difficult to incorporate quantum effects in a robust way. Therefore, improving quantum wavepacket dynamics and incorporating nonadiabatic transitions and quantum effects into classical and semi-classical molecular dynamics is critical as well as challenging. In this paper, we present a MD scheme in which a new set of equations of motion (EOM) are proposed to effectively propagate nuclear trajectories while conserving quantum mechanical energy which is critical for describing quantum effects like tunneling. The new quantum EOM is tested on a one-state one-dimensional and a two-state two-dimensional model nonadiabatic systems. The global quantum force experienced by each trajectory promotes energy redistribution among the bundle of trajectories, and thus helps the individual trajectory tunnel through the potential barrier higher than the energy of the trajectory itself. Construction of the new quantum force and EOM also provides a better way to treat the issue of back-reaction in mixed quantum-classical (MQC) methods, i.e. self-consistency between quantum degrees of freedom (DOF) and classical DOF.

  18. Chemical tracking at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Costain, D.B.

    1994-04-01T23:59:59.000Z

    EG&G Rocky Flats, Inc., has developed a chemical tracking system to support compliance with the Emergency Planning and community Right-to-Know Act (EPCRA) at the Rocky Flats Plant. This system, referred to as the EPCRA Chemical Control system (ECCS), uses bar code technology to uniquely identify and track the receipt, distribution, and use of chemicals. Chemical inventories are conducted using hand-held electronic scanners to update a site wide chemical database on a VAX 6000 computer. Information from the ECCS supports preparation of the EPCRA Tier II and Form R reports on chemical storage and use.

  19. ITP Chemicals: Energy and Environmental Profile of the U.S. Chemical...

    Broader source: Energy.gov (indexed) [DOE]

    profilefull.pdf More Documents & Publications Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries ITP Chemicals:...

  20. The chemical enrichment of the ICM from hydrodynamical simulations

    E-Print Network [OSTI]

    S. Borgani; D. Fabjan; L. Tornatore; S. Schindler; K. Dolag; A. Diaferio

    2008-01-07T23:59:59.000Z

    The study of the metal enrichment of the intra-cluster and inter-galactic media (ICM and IGM) represents a direct means to reconstruct the past history of star formation, the role of feedback processes and the gas-dynamical processes which determine the evolution of the cosmic baryons. In this paper we review the approaches that have been followed so far to model the enrichment of the ICM in a cosmological context. While our presentation will be focused on the role played by hydrodynamical simulations, we will also discuss other approaches based on semi-analytical models of galaxy formation, also critically discussing pros and cons of the different methods. We will first review the concept of the model of chemical evolution to be implemented in any chemo-dynamical description. We will emphasise how the predictions of this model critically depend on the choice of the stellar initial mass function, on the stellar life-times and on the stellar yields. We will then overview the comparisons presented so far between X-ray observations of the ICM enrichment and model predictions. We will show how the most recent chemo-dynamical models are able to capture the basic features of the observed metal content of the ICM and its evolution. We will conclude by highlighting the open questions in this study and the direction of improvements for cosmological chemo-dynamical models of the next generation.

  1. Biotreatment techniques get chemical help

    SciTech Connect (OSTI)

    Elizardo, K. (Solvay Interox, Houston, TX (United States))

    1993-11-01T23:59:59.000Z

    Biological treatment methods for contaminated soils and groundwater, including landfarming, pump-and-treat bioreactors and in situ bioremediation, are using hydrogen peroxide (H[sub 2]O[sub 2]) as an oxidant to reduce cleanup time and save money. Some examples of how the chemical is being used include the following: recent studies indicate peroxygen compounds, such as calcium peroxide, can be used to chemically aerate soils in landfarming applications. Pump-and-treat bioreactor systems for treating halogenated aliphatics can use an H[sub 2]O[sub 2] solution to deliver oxygen to oxygen-deficient systems. The solution has proven effective for improving bioreactor efficiency during limited oxygen solubility; in situ peroxidation can be used to partially oxidize soil contaminants to reduce their toxicity and enhance their biodegradability in the unsaturated zone prior to in situ bioremediation.

  2. Chemical logging of geothermal wells

    DOE Patents [OSTI]

    Allen, Charles A. (Idaho Falls, ID); McAtee, Richard E. (Idaho Falls, ID)

    1981-01-01T23:59:59.000Z

    The presence of geothermal aquifers can be detected while drilling in geothermal formations by maintaining a chemical log of the ratio of the concentrations of calcium to carbonate and bicarbonate ions in the return drilling fluid. A continuous increase in the ratio of the concentrations of calcium to carbonate and bicarbonate ions is indicative of the existence of a warm or hot geothermal aquifer at some increased depth.

  3. Chemical Science | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeIdleBiological ScienceCareers Careers ComeChemical Science

  4. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01T23:59:59.000Z

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  5. Alternative Energy Department of Chemical Engineering

    E-Print Network [OSTI]

    Cantlon, Jessica F.

    Alternative Energy Department of Chemical Engineering Graduate Handbook 2014-2015 Victoria Heberling, Graduate Program Coordinator Professor Matthew Yates, Director of Alternative Energy #12;University of Rochester Graduate Handbook Alternative Energy updated August, 2013 Department of Chemical

  6. Alternative Energy Department of Chemical Engineering

    E-Print Network [OSTI]

    Mahon, Bradford Z.

    Alternative Energy Department of Chemical Engineering Graduate Handbook 2013-2014 Gina Eagan, Graduate Program Coordinator Professor Matthew Yates, Director of Alternative Energy #12;University of Rochester Graduate Handbook Alternative Energy updated August, 2013 Department of Chemical Engineering Page

  7. Studying the Solar System's Chemical Recipe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studying the Solar System's Chemical Recipe Studying the Solar System's Chemical Recipe Print Tuesday, 26 March 2013 00:00 To study the origins of different isotope ratios among...

  8. Environmental toxicity of complex chemical mixtures

    E-Print Network [OSTI]

    Gillespie, Annika Margaret

    2009-05-15T23:59:59.000Z

    and inorganic constituents, as well as the pharmacokinetics and potential interactions of chemical mixtures. This research was conducted to investigate the potential genotoxic effects of complex chemical mixtures of polycyclic aromatic hydrocarbons (PAHs...

  9. Future scenarios for green chemical supply chains

    E-Print Network [OSTI]

    Arora, Vibhu, M. Eng. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    We live in an age where industrial chemicals are central to the modem economy serving as the basis for all man-made fibers, life-science chemicals and consumer products. Owing to globalization, the industry has grown to ...

  10. Basic Chemical Safety and Laboratory Survival Skills

    E-Print Network [OSTI]

    Gallivan, Martha A.

    : Reagent bottles, Squirt bottles, spray bottles Label must have name of chemical and hazard information (s handling chemicals Lab coat must cover the wearer to the knees Plastic aprons are allowed only

  11. SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology)

    E-Print Network [OSTI]

    Wang, Hai

    SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology) Undergraduate Hometown.D. in chemical engineering with an emphasis in nanotechnology. Lindsay stands out as a very well-balanced student

  12. Dynamics of Motivations

    E-Print Network [OSTI]

    Knoll, JŲrn

    Dynamics of Resonances GSI, 18.05.2005 Motivations Thermal Equilibrium -N- vectormesons Di-leptons Towards dynamics Conserving -functional Gradient ap- proximation Quantum Kinetic Equation Summary Dynamics. Voskresensky1,3 1GSI 2Kurchatov Inst. (Moscow) 3Moscow Ins. for Physics and Engineering #12;Dynamics

  13. Dynamics on Lorentz manifolds

    E-Print Network [OSTI]

    Zeghib, Abdelghani

    Dynamics on Lorentz manifolds Abdelghani Zeghib Introduction Motivations and questions Examples Results Results Previous results Linear Dynamics General considerations Furstenberg Lemma Lorentz Dynamics://www.umpa.ens-lyon.fr/~zeghib/ (joint work with Paolo Piccione) #12;Dynamics on Lorentz manifolds Abdelghani Zeghib Introduction

  14. Introduction Basic dynamics

    E-Print Network [OSTI]

    LaCasce, Joseph H.

    Introduction Basic dynamics The Gulf Stream The thermohaline circulation Ocean currents: some misconceptions and some dynamics Joe LaCasce Dept. Geosciences October 30, 2012 Joe LaCasce Dept. Geosciences Ocean currents: some misconceptions and some dynamics #12;Introduction Basic dynamics The Gulf Stream

  15. Integrated Chemical Geothermometry System for Geothermal Exploration

    Broader source: Energy.gov (indexed) [DOE]

    interpretations) * Reduce exploration and development costs Innovation * Numerical optimization of multicomponent chemical geothermometry at multiple locations * Integration with...

  16. 442013-14 Suggested Course Plan CHEMICAL (PETROLEUM)

    E-Print Network [OSTI]

    Zhou, Chongwu

    442013-14 Suggested Course Plan CHEMICAL (PETROLEUM) FIRST YEAR FALL: 18 units SPRING: 18 units. to Chemical Engineering CHE 205: Numerical Methods in Chemical Engineering CHE 330: Chemical Engr: Chemical Reactor Analysis CHE 443: Viscous Flow CHE 444AL: Chemical Engineering Lab CHE 444bL: Chemical

  17. 482012-13SuggestedCoursePlan CHEMICAL (PETROLEUM)

    E-Print Network [OSTI]

    Zhou, Chongwu

    482012-13SuggestedCoursePlan CHEMICAL (PETROLEUM) FIRST YEAR FALL: 18 units SPRING: 18 units SECOND. to Chemical Engineering CHE 205: Numerical Methods in Chemical Engineering CHE 330: Chemical Engr: Chemical Reactor Analysis CHE 443: Viscous Flow CHE 444AL: Chemical Engineering Lab CHE 444BL: Chemical

  18. Appendix G. Chemicals Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    by the development of chemicals such as pharmaceuticals, building materials, housewares, pesticides, and industrial more hazardous chemicals result from the direct or indirect actions of humans. Building materials used for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  19. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097≠10129, 2007 Chemical ozone loss in the Arctic winter 1991≠1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991≠1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991≠1992 S. Tilmes et al. Title Page Abstract Introduction

  20. INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING

    E-Print Network [OSTI]

    Palanki, Srinivas

    INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING Volume 4 2006 Article A19 Design of a Fuel for automotive ap- plications, using methane as a fuel, are analyzed. Basic chemical engineering principles methane to generate hydrogen, are analyzed. In particular, basic chemical engineering principles

  1. Chemical Hygiene Policy Procedure: 6.05

    E-Print Network [OSTI]

    Jia, Songtao

    Chemical Hygiene Policy Procedure: 6.05 Version: 1.0 Created: 6/15/2013 1 A. Purpose: The Chemical Hygiene policy establishes Columbia University's position for the protection of laboratory workers and emergency response. For details and further requirements consult the Columbia University Chemical Hygiene

  2. Chemical Hygiene Plan For University of Florida

    E-Print Network [OSTI]

    Slatton, Clint

    Chemical Hygiene Plan For University of Florida Laboratories This is a site specific Chemical Hygiene Plan for: Laboratory or Room number(s): Building: Principal Investigator/Lab Manager: Department Reviewed August 2007 Revised August 2007 #12;2 I. Introduction This Chemical Hygiene Plan has been

  3. UNIVERSITY OF ARKANSAS CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Li, Jiali

    UNIVERSITY OF ARKANSAS CHEMICAL HYGIENE PLAN OFFICE OF ENVIRONMENTAL HEALTH AND SAFETY FACILITIES Record Keeping 82 Appendix I: Chemical Hygiene at the 90-day Accumulation Facility 84 Appendix II: List and Safety (EH&S) in accordance with Federal and State regulations provides this Chemical Hygiene Plan

  4. Chemical Hygiene Plan UNIVERSITY OF CALIFORNIA, IRVINE

    E-Print Network [OSTI]

    Burke, Peter

    Chemical Hygiene Plan For UNIVERSITY OF CALIFORNIA, IRVINE The Henry Samueli School of Engineering INTEGRATED NANOSYSTEMS RESEARCH FACILITY 1 #12;Table of Contents List of Abbreviations 1.0 Chemical Hygiene Plan for the INRF Research Laboratory 1.1 Facility Description 1.2 Introduction to the Chemical Hygiene

  5. CHEMICAL HYGIENE PLAN LAB SPECIFIC INFORMATION

    E-Print Network [OSTI]

    Bigelow, Stephen

    CHEMICAL HYGIENE PLAN (CHP) LAB SPECIFIC INFORMATION & STANDARD OPERATING PROCEDURES (SOPs/23/09 This is the Chemical Hygiene Plan (CHP) for the Materials Research Laboratory (MRL) Spectroscopy Facility. All labs Chemical Hygiene Plan NMR Laboratory Form Version 8/6/98 1. General Laboratory Information Laboratory Name

  6. Introductory Computing: The Design Discipline

    E-Print Network [OSTI]

    Proulx, Viera K.

    in the context of information systems · Didactics: Systematic problem solving · Didactics: Information and data: the connection · Didactics: Design of abstractions = libraries · Didactics: Libraries for the beginners 2 #12 language context Systematic didactics for program design Connection between information and data Test

  7. Introductory Computing: The Design Discipline

    E-Print Network [OSTI]

    Proulx, Viera K.

    in the context of information systems · Didactics: algebra and programming · Information and data: the connection;6 Simple language context Systematic didactics for program design Connection between information and data with the given (input) data and output data Didactics: Algebra and Programing #12;9 Didactics of the design

  8. Exoplanetary Geophysics -- An Emerging Discipline

    E-Print Network [OSTI]

    Laughlin, Gregory

    2015-01-01T23:59:59.000Z

    Thousands of extrasolar planets have been discovered, and it is clear that the galactic planetary census draws on a diversity greatly exceeding that exhibited by the solar system's planets. We review significant landmarks in the chronology of extrasolar planet detection, and we give an overview of the varied observational techniques that are brought to bear. We then discuss the properties of the currently known distribution, using the mass-period diagram as a guide to delineating hot Jupiters, eccentric giant planets, and a third, highly populous, category that we term "ungiants", planets having masses less than 30 Earth masses and orbital periods less than 100 days. We then move to a discussion of the bulk compositions of the extrasolar planets. We discuss the long-standing problem of radius anomalies among giant planets, as well as issues posed by the unexpectedly large range in sizes observed for planets with masses somewhat greater than Earth's. We discuss the use of transit observations to probe the atmo...

  9. Work Force Discipline--Withdrawn

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-04-05T23:59:59.000Z

    Withdrawn 4-26-14. Significant changes from the Order include the deletion of material included in other documents such as statutes and Federal regulations. In addition, an updated Table of Penalties now includes Smoking, Cyber Security, Standards of Conduct or other Ethical Violations, and the incorporation of the Travel and Purchase Card Guidance dated January 2003.

  10. Reaction Dynamics and Spectroscopy of Hydrocarbons in Plasma

    SciTech Connect (OSTI)

    Braams, Bastiaan J.

    2014-03-24T23:59:59.000Z

    This grant supported research in theoretical and computational Chemical Physics that resulted in numerous publications on fitting ab initio potential energy surfaces and dipole moment surfaces of polyatomic molecules and cations. This work made use of novel fitting methods that ensures that these surfaces are invariant with respect to all permutations of like atoms. The surfaces were used in various dynamics calculations, ranging from quantum vibrational dynamics to(quasi)classical trajectory calculations of reaction dynamics. A number of these studies were done in collaboration with experimental groups where the theoretical analyses turned out to be essential to give a proper understanding of the experimental results.

  11. DYNAMICS OF STOICHIOMETRIC BACTERIA-ALGAE INTERACTIONS IN THE EPILIMNION

    E-Print Network [OSTI]

    Smith, Hal

    the highly varying nutritional quality of plant resources for consumer-resource dynamics. Solar energy (for and multiple chemical elements in ecological interactions ([37]). It is observed that plant quality can. Specifically, if the quantity of an essential element in plant biomass is lower than the minimum threshold

  12. NDN, VOLUME TRANSMISSION, AND SELF-ORGANIZATION IN BRAIN DYNAMICS

    E-Print Network [OSTI]

    Freeman, Walter J.

    with neural network theory as proposed by Hebb in his 1949 classic The Organization of Behavior where heNDN, VOLUME TRANSMISSION, AND SELF- ORGANIZATION IN BRAIN DYNAMICS WALTER J FREEMAN Department chemical gradients; and order parameters that control self-organization of large populations of neurons

  13. International Symposium on Structure and Dynamics of Heterogeneous Systems

    E-Print Network [OSTI]

    Duisburg-Essen, Universitšt

    on light-activated proteins, water, melting and transport Chairman: P. Entel 13:30≠14:10 Norbert Hampp (Chemistry Department, Nagoya University, Nagoya, Japan) Water dynamics, fluctuation, freezing and chemical transport in single-molecule junctions 19:00≠21:00 SNACKS, BEVERAGES AND POSTER SHOW Friday, November 29

  14. CRAD, Chemical Management Implementation - June 30, 2011 | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Chemical Management Implementation - June 30, 2011 CRAD, Chemical Management Implementation - June 30, 2011 June 30, 2011 Chemical Management Implementation Inspection Criteria,...

  15. Dissection of Plant Defense Mechanisms Using Chemical and Molecular Genomics

    E-Print Network [OSTI]

    Rodriguez-Salus, Melinda Sue

    2012-01-01T23:59:59.000Z

    of auxins by a chemical genomics approach." Journal ofadvances in chemical genomics." Current Medicinal Chemistrymolecular and chemical genomics." Phytopathology 97(7): S58-

  16. Global Optimization of Chemical Reactors and Kinetic Optimization

    E-Print Network [OSTI]

    ALHUSSEINI, ZAYNA ISHAQ

    2013-01-01T23:59:59.000Z

    Computers and Chemical Engineering, 24, 67-79. [9] Zhou,Critical cfstrs. Chemical Engineering Science. 2000b; 55,17:region theory. Chemical Engineering Science.. 1999; 54:

  17. Gas-Phase Molecular Dynamics: High Resolution Spectroscopy and Collision Dynamics of Transient Species

    SciTech Connect (OSTI)

    Hall, G.E.

    2011-05-31T23:59:59.000Z

    This research is carried out as part of the Gas-Phase Molecular Dynamics program in the Chemistry Department at Brookhaven National Laboratory. Chemical intermediates in the elementary gas-phase reactions involved in combustion chemistry are investigated by high resolution spectroscopic tools. Production, reaction, and energy transfer processes are investigated by transient, double resonance, polarization and saturation spectroscopies, with an emphasis on technique development and connection with theory, as well as specific molecular properties.

  18. Drama in Dynamics: Boom, Splash, and Speed

    SciTech Connect (OSTI)

    Heather Marie Netzloff

    2004-12-19T23:59:59.000Z

    The full nature of chemistry and physics cannot be captured by static calculations alone. Dynamics calculations allow the simulation of time-dependent phenomena. This facilitates both comparisons with experimental data and the prediction and interpretation of details not easily obtainable from experiments. Simulations thus provide a direct link between theory and experiment, between microscopic details of a system and macroscopic observed properties. Many types of dynamics calculations exist. The most important distinction between the methods and the decision of which method to use can be described in terms of the size and type of molecule/reaction under consideration and the type and level of accuracy required in the final properties of interest. These considerations must be balanced with available computational codes and resources as simulations to mimic ''real-life'' may require many time steps. As indicated in the title, the theme of this thesis is dynamics. The goal is to utilize the best type of dynamics for the system under study while trying to perform dynamics in the most accurate way possible. As a quantum chemist, this involves some level of first principles calculations by default. Very accurate calculations of small molecules and molecular systems are now possible with relatively high-level ab initio quantum chemistry. For example, a quantum chemical potential energy surface (PES) can be developed ''on-the-fly'' with dynamic reaction path (DRP) methods. In this way a classical trajectory is developed without prior knowledge of the PES. In order to treat solvation processes and the condensed phase, large numbers of molecules are required, especially in predicting bulk behavior. The Effective Fragment Potential (EFP) method for solvation decreases the cost of a fully quantum mechanical calculation by dividing a chemical system into an ab initio region that contains the solute and an ''effective fragment'' region that contains the remaining solvent molecules. But, despite the reduced cost relative to fully QM calculations, the EFP method, due to its complex, QM-based potential, does require more computation time than simple interaction potentials, especially when the method is used for large scale molecular dynamics simulations. Thus, the EFP method was parallelized to facilitate these calculations within the quantum chemistry program GAMESS. The EFP method provides relative energies and structures that are in excellent agreement with the analogous fully quantum results for small water clusters. The ability of the method to predict bulk water properties with a comparable accuracy is assessed by performing EFP molecular dynamics simulations. Molecular dynamics simulations can provide properties that are directly comparable with experimental results, for example radial distribution functions. The molecular PES is a fundamental starting point for chemical reaction dynamics. Many methods can be used to obtain a PES; for example, assuming a global functional form for the PES or, as mentioned above, performing ''on-the-fly'' dynamics with Al or semi-empirical calculations at every molecular configuration. But as the size of the system grows, using electronic structure theory to build a PES and, therefore, study reaction dynamics becomes virtually impossible. The program Grow builds a PES as an interpolation of Al data; the goal is to attempt to produce an accurate PES with the smallest number of Al calculations. The Grow-GAMESS interface was developed to obtain the Al data from GAMESS. Classical or quantum dynamics can be performed on the resulting surface. The interface includes the novel capability to build multi-reference PESs; these types of calculations are applicable to problems ranging from atmospheric chemistry to photochemical reaction mechanisms in organic and inorganic chemistry to fundamental biological phenomena such as photosynthesis.

  19. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1994-12-27T23:59:59.000Z

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation. The invention also relates to the fabrication of protective clothing materials. 13 figures.

  20. Chemical Enrichment at High Redshifts

    E-Print Network [OSTI]

    Snigdha Das; Pushpa Khare

    1998-08-09T23:59:59.000Z

    We have tried to understand the recent observations related to metallicity in Ly $\\alpha$ forest clouds in the framework of the two component model suggested by Chiba & Nath (1997). We find that even if the mini-halos were chemically enriched by an earlier generation of stars, to have [C/H] $\\simeq$ -2.5, the number of C IV lines with column density $>10^{12} cm^{-2}$, contributed by the mini-halos, at the redshift of 3, would be only about 10% of the total number of lines, for a chemical enrichment rate of $(1+z)^{-3}$ in the galaxies. Recently reported absence of heavy element lines associated with most of the Ly $\\alpha$ lines with H I column density between $10^{13.5} cm^{-2}$ and $10^{14} cm^{-2}$ by Lu et al (1998), if correct, gives an upper limit on [C/H]=-3.7, not only in the mini-halos, but also in the outer parts of galactic halos. This is consistent with the results of numerical simulations, according to which, the chemical elements associated with the Ly $\\alpha$ clouds are formed in situ in clouds, rather than in an earlier generation of stars. However, the mean value of $7 \\times 10^{-3}$ for the column density ratio of C IV and H I, determined by Cowie and Songaila (1998) for low Lyman alpha optical depths, implies an abundance of [C/H] =-2.5 in mini-halos as well as in most of the region in galactic halos, presumably enriched by an earlier generation of stars. The redshift and column density distribution of C IV has been shown to be in reasonable agreement with the observations.

  1. UCR Chemical Hygiene Plan, ver 2012.09.10 page 1 of 55 UCR Chemistry Department Chemical Hygiene Plan

    E-Print Network [OSTI]

    Reed, Christopher A.

    UCR Chemical Hygiene Plan, ver 2012.09.10 page 1 of 55 UCR Chemistry Department Chemical Hygiene Plan UCR CHEMISTRY DEPARTMENT CHEMICAL HYGIENE PLAN

  2. Overview of chemical vapor infiltration

    SciTech Connect (OSTI)

    Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

    1993-06-01T23:59:59.000Z

    Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

  3. Chemical kinetics and combustion modeling

    SciTech Connect (OSTI)

    Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

  4. Microcomponent chemical process sheet architecture

    DOE Patents [OSTI]

    Wegeng, R.S.; Drost, M.K.; Call, C.J.; Birmingham, J.G.; McDonald, C.E.; Kurath, D.E.; Friedrich, M.

    1998-09-22T23:59:59.000Z

    The invention is a microcomponent sheet architecture wherein macroscale unit processes are performed by microscale components. The sheet architecture may be a single laminate with a plurality of separate microcomponent sections or the sheet architecture may be a plurality of laminates with one or more microcomponent sections on each laminate. Each microcomponent or plurality of like microcomponents perform at least one chemical process unit operation. A first laminate having a plurality of like first microcomponents is combined with at least a second laminate having a plurality of like second microcomponents thereby combining at least two unit operations to achieve a system operation. 26 figs.

  5. Microcomponent chemical process sheet architecture

    DOE Patents [OSTI]

    Wegeng, Robert S. (Richland, WA); Drost, M. Kevin (Richland, WA); Call, Charles J. (Pasco, WA); Birmingham, Joseph G. (Richland, WA); McDonald, Carolyn Evans (Richland, WA); Kurath, Dean E. (Benton County, WA); Friedrich, Michele (Prosser, WA)

    1998-01-01T23:59:59.000Z

    The invention is a microcomponent sheet architecture wherein macroscale unit processes are performed by microscale components. The sheet architecture may be a single laminate with a plurality of separate microcomponent sections or the sheet architecture may be a plurality of laminates with one or more microcomponent sections on each laminate. Each microcomponent or plurality of like microcomponents perform at least one chemical process unit operation. A first laminate having a plurality of like first microcomponents is combined with at least a second laminate having a plurality of like second microcomponents thereby combining at least two unit operations to achieve a system operation.

  6. Chemical Engineering | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization of SelectiveBrownFirst martian Chemical

  7. Chemical Resources | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization of SelectiveBrownFirst martianChemical

  8. Chemical Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of the Rotating 2015Analysis ofChemical

  9. chemicals | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2theChemical Methods

  10. A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. II. Performance and applications for reaction dynamics

    E-Print Network [OSTI]

    Abeysekera, Chamara

    This second paper in a series of two reports on the performance of a new instrument for studying chemical reaction dynamics and kinetics at low temperatures. Our approach employs chirped-pulse Fourier-transform microwave ...

  11. PHYSICAL REVIEW E 83, 046405 (2011) Dynamic model of streamer coupling for the homogeneity of glowlike dielectric barrier discharges

    E-Print Network [OSTI]

    Economou, Demetre J.

    2011-01-01T23:59:59.000Z

    PHYSICAL REVIEW E 83, 046405 (2011) Dynamic model of streamer coupling for the homogeneity. Economou Department of Chemical and Biomolecular Engineering, Plasma Processing Laboratory, University 2011; published 18 April 2011) A streamer coupling theory is developed to describe the formation

  12. Helium in Chemically Peculiar Stars

    E-Print Network [OSTI]

    F. Leone

    1998-05-05T23:59:59.000Z

    For the purpose of deriving the helium abundances in chemically peculiar stars, the importance of assuming a correct helium abundance has been investigated for determining the effective temperature and gravity of main sequence B-type stars, making full use of the present capability of reproducing their helium lines. Even if the flux distribution of main sequence B-type stars appears to depend only on the effective temperature for any helium abundance, the effective temperature, gravity and helium abundance have to be determined simultaneously by matching the Balmer line profiles. New MULTI NLTE calculations, performed adopting ATLAS9 model atmospheres and updated helium atomic parameters, reproduce most of the observed equivalent widths of neutral helium lines for main sequence B-type stars and they make us confident of the possibility to correctly derive the helium abundance in chemically peculiar stars. An application of previous methods to the helium rich star HD 37017 shows that helium could be stratified in the magnetic pole regions, as expected in the framework of the diffusion theory in the presence of mass loss.

  13. Persistence of transition state structure in chemical reactions driven by fields oscillating in time

    E-Print Network [OSTI]

    Galen T. Craven; Thomas Bartsch; Rigoberto Hernandez

    2014-04-29T23:59:59.000Z

    Chemical reactions subjected to time-varying external forces cannot generally be described through a fixed bottleneck near the transition state barrier or dividing surface. A naive dividing surface attached to the instantaneous, but moving, barrier top also fails to be recrossing-free. We construct a moving dividing surface in phase space over a transition state trajectory. This surface is recrossing-free for both Hamiltonian and dissipative dynamics. This is confirmed even for strongly anharmonic barriers using simulation. The power of transition state theory is thereby applicable to chemical reactions and other activated processes even when the bottlenecks are time-dependent and move across space.

  14. Spectroscopical Analysis of Mechano-chemically Activated Surfaces†

    E-Print Network [OSTI]

    Cooper, Rodrigo

    2012-10-19T23:59:59.000Z

    Mechano-chemical activation is fundamentally different than chemical activation in that energy is added to alter the state of bond energy instead of exciting electrons to produce a chemical reaction. Mechano-chemical ...

  15. DEPARTMENT OF CHEMICAL & PETROLEUM ENGINEERING UNIVERSITY OF CALGARY

    E-Print Network [OSTI]

    Sinnamon, Gordon J.

    DEPARTMENT OF CHEMICAL & PETROLEUM ENGINEERING UNIVERSITY OF CALGARY SCHULICH.UCALGARY.CA/CHEMICAL/ (403) 220-5751 Department Of Chemical & Petroleum Engineering ZANDMER DISTINGUISHED LECTURE SERIES 2014 Lecture Series in Chemical & Petroleum Engineering is designed to attract internationally renowned

  16. Undergraduate Bulletin 2014-15 Energy, Environmental and Chemical Engineering

    E-Print Network [OSTI]

    Subramanian, Venkat

    Undergraduate Bulletin 2014-15 Energy, Environmental and Chemical Engineering (09/02/14) 1 Energy, Environmental and Chemical Engineering About Energy, Environmental and Chemical Engineering Our department focuses on environmental engineering, energy systems engineering and chemical engineering. We provide

  17. Tariffs with Dynamic Supply Response

    E-Print Network [OSTI]

    Karp, Larry

    1985-01-01T23:59:59.000Z

    Giannini FDN iibrary TARIFFS WITH DYNAMIC SUPPLY RESWNSEpaper studies the optimal tariff in a dynamic framework. Thesellers, the optimal tariff is dynam- ically inconsistent;

  18. Chemical heat pump and chemical energy storage system

    DOE Patents [OSTI]

    Clark, Edward C. (Woodinville, WA); Huxtable, Douglas D. (Bothell, WA)

    1985-08-06T23:59:59.000Z

    A chemical heat pump and storage system employs sulfuric acid and water. In one form, the system includes a generator and condenser, an evaporator and absorber, aqueous acid solution storage and water storage. During a charging cycle, heat is provided to the generator from a heat source to concentrate the acid solution while heat is removed from the condenser to condense the water vapor produced in the generator. Water is then stored in the storage tank. Heat is thus stored in the form of chemical energy in the concentrated acid. The heat removed from the water vapor can be supplied to a heat load of proper temperature or can be rejected. During a discharge cycle, water in the evaporator is supplied with heat to generate water vapor, which is transmitted to the absorber where it is condensed and absorbed into the concentrated acid. Both heats of dilution and condensation of water are removed from the thus diluted acid. During the discharge cycle the system functions as a heat pump in which heat is added to the system at a low temperature and removed from the system at a high temperature. The diluted acid is stored in an acid storage tank or is routed directly to the generator for reconcentration. The generator, condenser, evaporator, and absorber all are operated under pressure conditions specified by the desired temperature levels for a given application. The storage tanks, however, can be maintained at or near ambient pressure conditions. In another form, the heat pump system is employed to provide usable heat from waste process heat by upgrading the temperature of the waste heat.

  19. Chemical Hygiene Planh UNIVERSITY OF AlASKA

    E-Print Network [OSTI]

    Hartman, Chris

    Chemical Hygiene Planh ∑ UNIVERSITY OF AlASKA ∑ ∑ FAIRBANKS INTRODUCTION.....................................................................................................3 C Chemical Hygiene Officer (CHO ................................................................................................................... 5 B Personal Hygiene

  20. Dynamics of structural priming†

    E-Print Network [OSTI]

    Malhotra, Gaurav

    2009-01-01T23:59:59.000Z

    for understanding various aspects of syntactic priming. Cognitive processes are modelled as dynamical systems that can change their behaviour when they process information. We use these dynamical systems to investigate how each episode of language comprehension...

  1. CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics

    SciTech Connect (OSTI)

    Kee, R.J.; Rupley, F.M.; Meeks, E.; Miller, J.A.

    1996-05-01T23:59:59.000Z

    This document is the user`s manual for the third-generation CHEMKIN package. CHEMKIN is a software package whose purpose is to facilitate the formation, solution, and interpretation of problems involving elementary gas-phase chemical kinetics. It provides a flexible and powerful tool for incorporating complex chemical kinetics into simulations of fluid dynamics. The package consists of two major software components: an Interpreter and a Gas-Phase Subroutine Library. The Interpreter is a program that reads a symbolic description of an elementary, user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Gas-Phase Subroutine Library. This library is a collection of about 100 highly modular FORTRAN subroutines that may be called to return information on equations of state, thermodynamic properties, and chemical production rates. CHEMKIN-III includes capabilities for treating multi-fluid plasma systems, that are not in thermal equilibrium. These new capabilities allow researchers to describe chemistry systems that are characterized by more than one temperature, in which reactions may depend on temperatures associated with different species; i.e. reactions may be driven by collisions with electrons, ions, or charge-neutral species. These new features have been implemented in such a way as to require little or no changes to CHEMKIN implementation for systems in thermal equilibrium, where all species share the same gas temperature. CHEMKIN-III now has the capability to handle weakly ionized plasma chemistry, especially for application related to advanced semiconductor processing.

  2. Categorical Introduction to Dynamical Systems Symbolic Dynamical Systems

    E-Print Network [OSTI]

    Kahng, Byung-Jay

    Categorical Introduction to Dynamical Systems Symbolic Dynamical Systems Symbolic Embedding Examples Results Embeddings in Symbolic Dynamical Systems Jonathan Jaquette Swarthmore College July 22, 2009 Jonathan Jaquette Embeddings in Symbolic Dynamical Systems #12;Categorical Introduction

  3. Dynamics of Carroll Particles

    E-Print Network [OSTI]

    Eric Bergshoeff; Joaquim Gomis; Giorgio Longhi

    2014-05-31T23:59:59.000Z

    We investigate particles whose dynamics is invariant under the Carroll group. Although a single free such Carroll particle has no non-trivial dynamics (`the Carroll particle does not move') we show that there exists non-trivial dynamics for a set of interacting Carroll particles. Furthermore, we gauge the Carroll algebra and couple the Carroll particle to these gauge fields. It turns out that for such a coupled system even a single Carroll particle can have non-trivial dynamics.

  4. Hierarchical Network Structure Promotes Dynamical Robustness

    E-Print Network [OSTI]

    Cameron Smith; Raymond S. Puzio; Aviv Bergman

    2014-12-01T23:59:59.000Z

    The analysis of dynamical systems that attempts to model chemical reaction, gene-regulatory, population, and ecosystem networks all rely on models having interacting components. When the details of these interactions are unknown for biological systems of interest, one effective approach is to study the dynamical properties of an ensemble of models determined by evolutionary constraints that may apply to all such systems. One such constraint is that of dynamical robustness. Despite previous investigations, the relationship between dynamical robustness-an important functional characteristic of many biological systems-and network structure is poorly understood. Here we analyze the stability and robustness of a large class of dynamical systems and demonstrate that the most hierarchical network structures, those equivalent to the total ordering, are the most robust. In particular, we determine the probability distribution of robustness over system connectivity and show that robustness is maximized by maximizing the number of links between strongly connected components of the graph representing the underlying system connectivity. We demonstrate that this can be understood in terms of the fact that permutation of strongly connected components is a fundamental symmetry of dynamical robustness, which applies to networks of any number of components and is independent of the distribution from which the strengths of interconnection among components are sampled. The classification of dynamical robustness based upon a purely topological property provides a fundamental organizing principle that can be used in the context of experimental validation to select among models that break or preserve network hierarchy. This result contributes to an explanation for the observation of hierarchical modularity in biological networks at all scales.

  5. Electrostatic thin film chemical and biological sensor

    DOE Patents [OSTI]

    Prelas, Mark A. (Columbia, MO); Ghosh, Tushar K. (Columbia, MO); Tompson, Jr., Robert V. (Columbia, MO); Viswanath, Dabir (Columbia, MO); Loyalka, Sudarshan K. (Columbia, MO)

    2010-01-19T23:59:59.000Z

    A chemical and biological agent sensor includes an electrostatic thin film supported by a substrate. The film includes an electrostatic charged surface to attract predetermined biological and chemical agents of interest. A charge collector associated with said electrostatic thin film collects charge associated with surface defects in the electrostatic film induced by the predetermined biological and chemical agents of interest. A preferred sensing system includes a charge based deep level transient spectroscopy system to read out charges from the film and match responses to data sets regarding the agents of interest. A method for sensing biological and chemical agents includes providing a thin sensing film having a predetermined electrostatic charge. The film is exposed to an environment suspected of containing the biological and chemical agents. Quantum surface effects on the film are measured. Biological and/or chemical agents can be detected, identified and quantified based on the measured quantum surface effects.

  6. Toxic chemical considerations for tank farm releases

    SciTech Connect (OSTI)

    Van Keuren, J.C.; Davis, J.S., Westinghouse Hanford

    1996-08-01T23:59:59.000Z

    This topical report contains technical information used to determine the accident consequences of releases of toxic chemical and gases for the Tank Farm Final Safety Analysis report (FSAR).It does not provide results for specific accident scenarios but does provide information for use in those calculations including chemicals to be considered, chemical concentrations, chemical limits and a method of summing the fractional contributions of each chemical. Tank farm composites evaluated were liquids and solids for double shell tanks, single shell tanks, all solids,all liquids, headspace gases, and 241-C-106 solids. Emergency response planning guidelines (ERPGs) were used as the limits.Where ERPGs were not available for the chemicals of interest, surrogate ERPGs were developed. Revision 2 includes updated sample data, an executive summary, and some editorial revisions.

  7. Dynamics of Anisotropic Universes

    E-Print Network [OSTI]

    Jerome Perez

    2006-03-30T23:59:59.000Z

    We present a general study of the dynamical properties of Anisotropic Bianchi Universes in the context of Einstein General Relativity. Integrability results using Kovalevskaya exponents are reported and connected to general knowledge about Bianchi dynamics. Finally, dynamics toward singularity in Bianchi type VIII and IX universes are showed to be equivalent in some precise sence.

  8. Social Dynamics Introduction

    E-Print Network [OSTI]

    Barrett, Jeffrey A.

    Social Dynamics Introduction Part I: Correlation and the Social Contract Introduction to part I 1: University of Utah Press. 47-69. Part II: Importance of Dynamics Introduction to part II 1. Trust, Risk Significance of Some Simple Evolutionary Models (2000) Philosophy of Science 67: 94-113. 4. Dynamics

  9. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  10. Intramolecular and nonlinear dynamics

    SciTech Connect (OSTI)

    Davis, M.J. [Argonne National Laboratory, IL (United States)

    1993-12-01T23:59:59.000Z

    Research in this program focuses on three interconnected areas. The first involves the study of intramolecular dynamics, particularly of highly excited systems. The second area involves the use of nonlinear dynamics as a tool for the study of molecular dynamics and complex kinetics. The third area is the study of the classical/quantum correspondence for highly excited systems, particularly systems exhibiting classical chaos.

  11. Cybersecurity Dynamics Shouhuai Xu

    E-Print Network [OSTI]

    Xu, Shouhuai

    Antonio ABSTRACT We explore the emerging field of Cybersecurity Dynamics, a candidate foundation been driving the study of security for decades -- the idea of cybersecurity dynamics emergedCybersecurity Dynamics Shouhuai Xu Department of Computer Science, University of Texas at San

  12. 17. METAPOPULATION DYNAMICS OF

    E-Print Network [OSTI]

    17. METAPOPULATION DYNAMICS OF INFECTIOUS DISEASES Matt J. Keeling, Ottar N. BjÝrnstad, and Bryan T resonances for the dynamics of parasites. This is particularly true for microparasitic infections" growth of the parasite population. Thus, at the scale of the host popu- lation, infectious dynamics bears

  13. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-11-24T23:59:59.000Z

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  14. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77389)

    1987-01-01T23:59:59.000Z

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  15. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77379)

    1987-01-01T23:59:59.000Z

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing he evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  16. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-06-23T23:59:59.000Z

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  17. Chemical microreactor and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan

    2005-11-01T23:59:59.000Z

    A chemical microreactor suitable for generation of hydrogen fuel from liquid sources such as ammonia, methanol, and butane through steam reforming processes when mixed with an appropriate amount of water contains capillary microchannels with integrated resistive heaters to facilitate the occurrence of catalytic steam reforming reactions. One such microreactor employs a packed catalyst capillary microchannel and at least one porous membrane. Another employs a porous membrane with a large surface area or a porous membrane support structure containing a plurality of porous membranes having a large surface area in the aggregate, i.e., greater than about 1 m.sup.2 /cm.sup.3. The packed catalyst capillary microchannels, porous membranes and porous membrane support structures may be formed by a variety of methods.

  18. Vertical flow chemical detection portal

    DOE Patents [OSTI]

    Linker, K.L.; Hannum, D.W.; Conrad, F.J.

    1999-06-22T23:59:59.000Z

    A portal apparatus is described for screening objects or persons for the presence of trace amounts of chemical substances such as illicit drugs or explosives. The apparatus has a test space, in which a person may stand, defined by two generally upright sides spanned by a horizontal transom. One or more fans in the transom generate a downward air flow (uni-directional) within the test space. The air flows downwardly from a high pressure upper zone, past the object or person to be screened. Air moving past the object dislodges from the surface thereof both volatile and nonvolatile particles of the target substance. The particles are entrained into the air flow which continues flowing downward to a lower zone of reduced pressure, where the particle-bearing air stream is directed out of the test space and toward preconcentrator and detection components. The sides of the portal are specially configured to partially contain and maintain the air flow. 3 figs.

  19. Slow dynamics and anomalous nonlinear fast dynamics in diverse solids

    E-Print Network [OSTI]

    Slow dynamics and anomalous nonlinear fast dynamics in diverse solids Paul Johnsona) Geophysics study of anomalous nonlinear fast dynamics and slow dynamics in a number of solids. Observations are presented from seven diverse materials showing that anomalous nonlinear fast dynamics ANFD and slow dynamics

  20. The Chemical Engineer's Role in Economic Recovery

    E-Print Network [OSTI]

    Felch, D. E.; Stine, L. O.; Vickers, A. G.

    1984-01-01T23:59:59.000Z

    Chemical engineers must lead industry to a clearer view of the thermodynamic potential of existing plants and more realistic expectations for emerging new technologies...

  1. ORISE: Chemical Stockpile Emergency Preparedness Program Exercise...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Stockpile Emergency Preparedness Program Exercise Training and Analysis Tool Training Tool Improves Information Sharing Between CSEPP and its Response Partners In 2006,...

  2. Chemical and Microstructural Effects in Electrode Polarization

    SciTech Connect (OSTI)

    Virkar, A.; Armstrong, T.; Radhakrishman, R.; Ramanan, G.; Zhao, F.; Singhal, S.

    2005-01-28T23:59:59.000Z

    This presentation discusses the chemical and microstructural effects in electrode polarization and a relative comparison of contributions of the various polarizations in anode-supported cells.

  3. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  4. Chemical Characterization of Individual Particles and Residuals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Individual Particles and Residuals of Cloud Droplets and Ice Crystals Collected On Board Research Chemical Characterization of Individual Particles and Residuals of Cloud Droplets...

  5. Climate VISION: Private Sector Initiatives: Chemical Manufacturing...

    Office of Scientific and Technical Information (OSTI)

    chemicals, forest products (such as paper and wood products), glass, metal casting, petroleum and coal products, and steel. As soon as the current briefs are available, we...

  6. Methods and compounds for chemical ligation

    DOE Patents [OSTI]

    Church, George M.; Sismour, A. Michael

    2013-07-09T23:59:59.000Z

    Compositions and methods for chemical ligation are provided. Methods for nucleic acid sequencing, nucleic acid assembly and nucleic acid synthesis are also provided.

  7. Climate VISION: Private Sector Initiatives: Chemical Manufacturing

    Office of Scientific and Technical Information (OSTI)

    American Chemistry Council (ACC), representing 85% of the chemical industry production in the U.S., has agreed American Chemistry Council Logo to an overall greenhouse gas...

  8. Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    Broader source: Energy.gov [DOE]

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

  9. CHEMICAL ENGINEERING 2014-2016 CATALOG

    E-Print Network [OSTI]

    Lightsey, Glenn

    Semester Semester Hours CH 302, Principles of Chemistry II ...........................................3 CH...........................4 CHE 372, Chemical Reactor Analysis and Design....................3 American History

  10. CHEMICAL ENGINEERING 2012-2014 CATALOG

    E-Print Network [OSTI]

    Texas at Austin, University of

    Semester Semester Hours CH 302, Principles of Chemistry II ...........................................3 CH...........................4 CHE 372, Chemical Reactor Analysis and Design....................3 American History

  11. Evaluation Of Chemical Geothermometers For Calculating Reservoir...

    Open Energy Info (EERE)

    For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Evaluation Of Chemical...

  12. Chemical Characterization of Crude Petroleum Using Nanospray...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    solvents that are rarely used for petroleum characterization. Citation: Eckert PA, PJ Roach, A Laskin, and J Laskin.2012."Chemical Characterization of Crude Petroleum Using...

  13. Distribution Category: Atomic, Molecular, and Chemical Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic, Molecular, and Chemical Physics (UC-411) ARGONNE NATIONAL LABORATORY 9700 South Cass Avenue Argonne, TIlinois 60439 ANLI APSILS-151 RESULTS OF DESIGN CALCULATIONS FOR THE...

  14. Microbend fiber-optic chemical sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    2002-01-01T23:59:59.000Z

    A microbend fiber-optic chemical sensor for detecting chemicals in a sample, and a method for its use, is disclosed. The sensor comprises at least one optical fiber having a microbend section (a section of small undulations in its axis), for transmitting and receiving light. In transmission, light guided through the microbend section scatters out of the fiber core and interacts, either directly or indirectly, with the chemical in the sample, inducing fluorescence radiation. Fluorescence radiation is scattered back into the microbend section and returned to an optical detector for determining characteristics of the fluorescence radiation quantifying the presence of a specific chemical.

  15. Chemically stabilized ionomers containing inorganic fillers

    DOE Patents [OSTI]

    Roelofs, Mark Gerrit

    2013-12-31T23:59:59.000Z

    Ionomeric polymers that are chemically stabilized and contain inorganic fillers are prepared, and show reduced degradation. The ionomers care useful in membranes and electrochemical cells.

  16. Nanoscale Chemical Imaging of a Working Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from electron microscopy to identify the chemical species present for an iron-based Fischer-Tropsch synthesis catalyst and to image their distribution on the nanoscale. When...

  17. Integrated Chemical Geothermometry System for Geothermal Exploration

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

  18. Dynamic Response Optimization of Complex Multibody Systems in a Penalty Formulation using Adjoint Sensitivity

    E-Print Network [OSTI]

    Yitao Zhu; Daniel Dopico; Corina Sandu; Adrian Sandu

    2014-10-30T23:59:59.000Z

    Multibody dynamics simulations are currently widely accepted as valuable means for dynamic performance analysis of mechanical systems. The evolution of theoretical and computational aspects of the multibody dynamics discipline make it conducive these days for other types of applications, in addition to pure simulations. One very important such application is design optimization. A very important first step towards design optimization is sensitivity analysis of multibody system dynamics. Dynamic sensitivities are often calculated by means of finite differences. Depending of the number of parameters involved, this procedure can be computationally expensive. Moreover, in many cases, the results suffer from low accuracy when real perturbations are used. The main contribution to the state-of-the-art brought by this study is the development of the adjoint sensitivity approach of multibody systems in the context of the penalty formulation. The theory developed is demonstrated on one academic case study, a five-bar mechanism, and on one real-life system, a 14-DOF vehicle model. The five-bar mechanism is used to illustrate the sensitivity approach derived in this paper. The full vehicle model is used to demonstrate the capability of the new approach developed to perform sensitivity analysis and gradient-based optimization for large and complex multibody systems with respect to multiple design parameters.

  19. CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II

    E-Print Network [OSTI]

    Zhang, Yuanlin

    CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II CH E 3330 Engineering Materials Science CH E 4342 Polymer Physics Engineering Thermodynamics I M E 3311 Materials Science M E 3322 Engineering Thermodynamics II M

  20. Developing and Integrating Sustainable Chemical Processes into Existing Petro-Chemical Plant Complexes

    E-Print Network [OSTI]

    Pike, Ralph W.

    Developing and Integrating Sustainable Chemical Processes into Existing Petro-Chemical Plant Complexes #12;Outline ∑ Introduction to Sustainable Development ∑ Research Vision ∑ Biomass conversion of biotechnology in existing plant complex ∑ Conclusions #12;Sustainability Sustainability refers to integrating

  1. Endocrine Active Chemicals, Pharmaceuticals, and Other Chemicals of Concern in Surface Water, Wastewater-

    E-Print Network [OSTI]

    , Wastewater- Treatment Plant Effluent, and Bed Sediment, and Biological Characteristics in Selected Streams Water, Wastewater- Treatment Plant Effluent, and Bed Sediment, and Biological Characteristics Chemicals, Pharmaceuticals, and Other Chemicals of Concern in Surface Water, Wastewater- Treatment Plant

  2. THE JOURNAL OF CHEMICAL PHYSICS 140, 204905 (2014) Precursory signatures of protein folding/unfolding: From time series

    E-Print Network [OSTI]

    2014-01-01T23:59:59.000Z

    THE JOURNAL OF CHEMICAL PHYSICS 140, 204905 (2014) Precursory signatures of protein folding conformation. The present study looks for precursory signatures of protein folding/unfolding within these rapid the important role played by weaker correlations in such protein folding dynamics. © 2014 AIP Publishing LLC

  3. Dynamical friction in modified Newtonian dynamics

    E-Print Network [OSTI]

    C. Nipoti; L. Ciotti; J. Binney; P. Londrillo

    2008-03-31T23:59:59.000Z

    We have tested a previous analytical estimate of the dynamical friction timescale in Modified Newtonian Dynamics (MOND) with fully non-linear N-body simulations. The simulations confirm that the dynamical friction timescale is significantly shorter in MOND than in equivalent Newtonian systems, i.e. systems with the same phase-space distribution of baryons and additional dark matter. An apparent conflict between this result and the long timescales determined for bars to slow and mergers to be completed in previous N-body simulations of MOND systems is explained. The confirmation of the short dynamical-friction timescale in MOND underlines the challenge that the Fornax dwarf spheroidal poses to the viability of MOND.

  4. Development of Computational Approaches for Simulation and Advanced Controls for Hybrid Combustion-Gasification Chemical Looping

    SciTech Connect (OSTI)

    Joshi, Abhinaya; Lou, Xinsheng; Neuschaefer, Carl; Chaudry, Majid; Quinn, Joseph

    2012-07-31T23:59:59.000Z

    This document provides the results of the project through September 2009. The Phase I project has recently been extended from September 2009 to March 2011. The project extension will begin work on Chemical Looping (CL) Prototype modeling and advanced control design exploration in preparation for a scale-up phase. The results to date include: successful development of dual loop chemical looping process models and dynamic simulation software tools, development and test of several advanced control concepts and applications for Chemical Looping transport control and investigation of several sensor concepts and establishment of two feasible sensor candidates recommended for further prototype development and controls integration. There are three sections in this summary and conclusions. Section 1 presents the project scope and objectives. Section 2 highlights the detailed accomplishments by project task area. Section 3 provides conclusions to date and recommendations for future work.

  5. The Chemical Engineering Ph.D. Program Department of Chemical Engineering

    E-Print Network [OSTI]

    Firestone, Jeremy

    and engineering knowledge in a particular area of scholarship. The conduct of this research, as well a foundation of technical knowledge in chemical engineering. This knowledge should be obtained in a wayThe Chemical Engineering Ph.D. Program Department of Chemical Engineering University of Delaware

  6. Nuclear Chemical EngineeringNuclear Chemical Engineering (Prof.(Prof. MikaelMikael Nilsson)Nilsson)

    E-Print Network [OSTI]

    Mease, Kenneth D.

    Nuclear Chemical EngineeringNuclear Chemical Engineering (Prof.(Prof. MikaelMikael Nilsson for future nuclear waste reprocessing. Projects include new methods and chemicals used in solvent extraction knowledge for separation of different elements in spent nuclear fuel. Radioanalytical techniques and online

  7. Nuclear Chemical EngineeringNuclear Chemical Engineering (Prof. Mikael Nilsson)(Prof. Mikael Nilsson)

    E-Print Network [OSTI]

    Mease, Kenneth D.

    Nuclear Chemical EngineeringNuclear Chemical Engineering (Prof. Mikael Nilsson)(Prof. Mikael for future nuclear waste reprocessing. Projects include new methods and chemicals used in solvent extraction knowledge for separation of different elements in spent nuclear fuel. Radioanalytical techniques and online

  8. Chemical Hygiene Plan The purpose of the Chemical Hygiene Plan (CHP) is to outline laboratory work

    E-Print Network [OSTI]

    de Lijser, Peter

    Chemical Hygiene Plan I. Policy The purpose of the Chemical Hygiene Plan (CHP) is to outline The Chemical Hygiene Plan, required to comply with provisions of CCR Title 8 ß5191 et al: A. Standard Operating engineering controls, the use of personnel protective equipment and hygiene practices. C. A requirement

  9. Temperature effects on chemical structure and motion in coal. Final report

    SciTech Connect (OSTI)

    Maciel, G.E.

    1996-09-30T23:59:59.000Z

    The objective of this project was to apply recently developed, state-of-the-art nuclear magnetic resonance (NMR) techniques to examine in situ changes in the chemical structure and molecular/macromolecular motion in coal as the temperature is increased above room temperature. Although alterations in the chemical structure of coal have been studied previously by {sup 13}C NMR, using quenched samples, the goal of this project was to examine these chemical structural changes, and changes in molecular/macromolecular mobility that may precede or accompany the chemical changes, at elevated temperatures, using modern {sup 13}C and {sup 1}H NMR techniques, especially {sup 1}H dipolar-dephasing techniques and related experiments pioneered in the laboratory for examining pyridine-saturated coals. This project consisted of the following four primary segments and related efforts on matters relevant to the first four tasks. (1) {sup 1}H NMR characterization of coal structure and mobility as a function of temperature variation over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (2) {sup 1}H NMR characterization of coal structure, mobility and conversion as a function of temperature variation over a temperature range (240--500 C) for which chemical transformations of coal are known to occur. (3) {sup 13}C NMR investigation of coal structure/mobility as a function of temperature over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (4) {sup 13}C NMR investigation of coal structure, dynamics and conversion as a function of temperature variation over a range (240--500 C) for which chemical transformations of coal are known to occur. (5) Related matters relevant to the first four tasks: (a) {sup 1}H CRAMPS NMR characterization of oil shales and their kerogen concentrates; and (b) improved quantitation in {sup 13}C MAS characterization of coals.

  10. Chemical Safety Vulnerability Working Group Report

    SciTech Connect (OSTI)

    Not Available

    1994-09-01T23:59:59.000Z

    This report marks the culmination of a 4-month review conducted to identify chemical safety vulnerabilities existing at DOE facilities. This review is an integral part of DOE's efforts to raise its commitment to chemical safety to the same level as that for nuclear safety.

  11. Chemical Transport Policy Virginia Tech Chemistry Department

    E-Print Network [OSTI]

    Crawford, T. Daniel

    Chemical Transport Policy Virginia Tech Chemistry Department This policy was enacted. The purpose of this policy is to ensure the safety of personnel transporting chemicals and anyone who might be affected by a problem occurring during such transport. The policy also helps to shield stockroom personnel

  12. The Chemical Formula of a Magnetotactic Bacterium

    E-Print Network [OSTI]

    Mittal, Aditya

    ARTICLE The Chemical Formula of a Magnetotactic Bacterium Mohit Naresh,1 Sayoni Das,1 Prashant allowed fascinating discoveries of elemental formulae of a few species that have guided the modern views in bioreactors has resulted in the discovery of the chemical formula of the magnetotactic bacterium. By devel

  13. hz.genium.com Proper Chemical Storage

    E-Print Network [OSTI]

    Cohen, Robert E.

    Lab Safety 1 hz.genium.com #12;Proper Chemical Storage ∑ Store in compatible groups. Consult above flammables and reactives. ∑ Label storage areas, and label all chemicals being stored. ∑ Store hazardous with contents. ∑ Lids should be tightly closed. ∑ Secondary containment for floor storage. ∑ Do not store

  14. Chemical Reactor Models of Digestion Modulation

    E-Print Network [OSTI]

    Logan, David

    Chemical Reactor Models of Digestion Modulation William Wolesensky & J. David Logan Department give an overview of the application of chemical reactor theory to models of digestion processes and indicate how those models extend to eco-physiological questions of modulation of digestion and feeding

  15. GULF OF MEXICO PHYSICAL AND CHEMICAL DATA

    E-Print Network [OSTI]

    -^ ^ / GULF OF MEXICO PHYSICAL AND CHEMICAL DATA FROM ALASKA CRUISES Marine Biological Laboratory, Commissioner GULF OF MEXICO PHYSICAL AND CHEMICAL DATA FROM ALASKA CRUISES Compiled by Albert Collier Fishery OF THE GULF OF MEXICO By Kenneth H. Driimmond and George B. Austin, Jr. Department of Oceanography The A. & M

  16. Computing Resources at Chemical and Biochemical Engineering

    E-Print Network [OSTI]

    Main Site Dept. of Chemical and Biochemical Engineering, 98 Brett Road Piscataway, NJ 08854-8058 PhoneComputing Resources at Chemical and Biochemical Engineering Note that use of all Rutgers University at: http://rucs.rutgers.edu/acceptable- use.html. Microlab. The PC Microlab (Engineering Room C233

  17. Department of Chemical and Petroleum Engineering

    E-Print Network [OSTI]

    Habib, Ayman

    Real World Process from Inception to Pre-construction ­ Apply Concepts Learned in Class to Industrial Quality and Air Pollution Control Chemical Engineering Energy & Env. Specialization #12;CHEMICAL World-Class Industry ­ Oil and Gas Exploration & Recovery ­ Heavy Oil & Bitumen ­ Natural Gas, Coal Bed

  18. GUIDELINES FOR HANDLING HAZARDOUS CHEMICAL WASTE

    E-Print Network [OSTI]

    Tennessee, University of

    GUIDELINES FOR HANDLING HAZARDOUS CHEMICAL WASTE The proper management of hazardous waste and regulatory compliance are achieved: 1. Make sure that no hazardous materials are placed into regular solid in the departmental chemical hygiene plan (CHP) before you begin to use hazardous substances. 3. Make sure you know

  19. College of Engineering CME Chemical Engineering

    E-Print Network [OSTI]

    MacAdam, Keith

    College of Engineering CME Chemical Engineering KEY: # = new course * = course changed = course dropped University of Kentucky 2013-2014 Undergraduate Bulletin 1 CME 006 THE ENGINEERING PROFESSION (JUNIOR AND SENIOR). (0) Activities of the Student Chapter of the American Institute of Chemical Engineers

  20. Thomas F. Edgar Professor of Chemical Engineering

    E-Print Network [OSTI]

    Lightsey, Glenn

    Thomas F. Edgar Professor of Chemical Engineering The University of Texas at Austin (1/23/13) Thomas F. Edgar is the George T. and Gladys H. Abell Chair in Chemical Engineering at the University.D. from Princeton University. Edgar worked as a process engineer with the Continental Oil Company before

  1. CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings

    E-Print Network [OSTI]

    Sherrill, David

    CHEM 6471 CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings 9:35 ≠ 10:55 am, Tuesday and Thursday of October 22-26 Textbooks Molecular Thermodynamics by D.A McQuarrie and J.D. Simon, University Science Books the laws of classical thermodynamics and some of their chemical applications. It also covers basic

  2. Conservation in a Gulf Coast Chemical Plant

    E-Print Network [OSTI]

    Murray, F.

    1983-01-01T23:59:59.000Z

    The MCA reports chemical industry energy compared to 1972 to be 24.2% (1981 data). This paper will describe the activity of one Gulf Coast chemical industry plant which has reduced consumption by 41%. Improvements have been made via energy...

  3. Department of Energy, Environmental & Chemical Engineering

    E-Print Network [OSTI]

    Subramanian, Venkat

    Department of Energy, Environmental & Chemical Engineering Opportunities for Undergraduate Students laboratory is a good way to expand your classroom experience. department of energy, environmental & chemicalIndustryPlantTour.Thedepartmentoffers twoplanttourseachfall. Cover: International Experience Brazil 2012 in sugar can mill, Usina Ester, Campina, Brazil #12

  4. Chemical Reactor Analysis and Optimal Digestion

    E-Print Network [OSTI]

    Jumars, Pete

    J 310 Chemical Reactor Analysis and Optimal Digestion An optimal digestion theory can be readily derived from basic principles o f chemical reactor analysis and design Deborah L. Penry and Peter a reactor and an operating strategy that maximize the yield or yield rate of desired reaction products

  5. Use and Misuse of Chemical Reactivity Spreadsheets

    SciTech Connect (OSTI)

    Simmons, F

    2005-09-20T23:59:59.000Z

    Misidentifying chemical hazards can have serious deleterious effects. Consequences of not identifying a chemical are obvious and include fires, explosions, injury to workers, etc. Consequences of identifying hazards that are really not present can be equally as bad. Misidentifying hazards can result in increased work with loss of productivity, increased expenses, utilization/consumption of scarce resources, and the potential to modify the work to include chemicals or processes that are actually more hazardous than those originally proposed. For these reasons, accurate hazard identification is critical to any safety program. Hazard identification in the world of chemistry is, at best, a daunting task. The knowing or understanding, of the reactions between any of approximately twelve million known chemicals that may be hazardous, is the reason for this task being so arduous. Other variables, such as adding other reactants/contaminants or changing conditions (e.g., temperature, pressure, or concentration), make hazard determination something many would construe as being more than impossibly difficult. Despite these complexities, people who do not have an extensive background in the chemical sciences can be called upon to perform chemical hazard identification. Because hazard identification in the area of chemical safety is so burdensome and because people with a wide variety of training are called upon to perform this work, tools are required to aid in chemical hazard identification. Many tools have been developed. Unfortunately, many of these tools are not seen as the limited resource that they are and are used inappropriately.

  6. Excellence in biotechnology for fuels and chemicals

    SciTech Connect (OSTI)

    Neufeld, S.

    1999-04-23T23:59:59.000Z

    The Biotechnology Center for Fuels and Chemicals (BCFC) leads a national effort, in cooperation with industry, to develop innovative, market-driven biotechnologies for producing fuels and chemicals from renewable resources. The BCFC researchers focus on using bioprocesses to convert renewable biomass feedstocks into valuable products.

  7. Heavy quark scattering and quenching in a QCD medium at finite temperature and chemical potential

    E-Print Network [OSTI]

    Berrehrah, H; Cassing, W; Gossiaux, P B; Aichelin, J

    2015-01-01T23:59:59.000Z

    The heavy quark collisional scattering on partons of the quark gluon plasma (QGP) is studied in a QCD medium at finite temperature and chemical potential. We evaluate the effects of finite parton masses and widths, finite temperature $T$ and quark chemical potential $\\mu_q$ on the different elastic cross sections for dynamical quasi-particles (on- and off-shell particles in the QGP medium as described by the dynamical quasi-particles model "DQPM") using the leading order Born diagrams. Our results show clearly the decrease of the $qQ$ and $gQ$ total elastic cross sections when the temperature and the quark chemical potential increase. These effects are amplified for finite $\\mu_q$ at temperatures lower than the corresponding critical temperature $T_c (\\mu_q)$. Using these cross sections we, furthermore, estimate the energy loss and longitudinal and transverse momentum transfers of a heavy quark propagating in a finite temperature and chemical potential medium. Accordingly, we have shown that the transport pro...

  8. 2005 Chemical Reactions at Surfaces

    SciTech Connect (OSTI)

    Cynthia M. Friend

    2006-03-14T23:59:59.000Z

    The Gordon Research Conference (GRC) on 2005 Chemical Reactions at Surfaces was held at Ventura Beach Marriott, Ventura California from February 13, 2005 through February 18, 2005. The Conference was well-attended with 124 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. In designing the formal speakers program, emphasis was placed on current unpublished research and discussion of the future target areas in this field. There was a conscious effort to stimulate lively discussion about the key issues in the field today. Time for formal presentations was limited in the interest of group discussions. In order that more scientists could communicate their most recent results, poster presentation time was scheduled. Attached is a copy of the formal schedule and speaker program and the poster program. In addition to these formal interactions, 'free time' was scheduled to allow informal discussions. Such discussions are fostering new collaborations and joint efforts in the field.

  9. Microsecond time-scale dynamics from relaxation in the rotating frame: experiments using spin lock with alternating phase

    E-Print Network [OSTI]

    Skrynnikov, Nikolai

    be made that 180į pulses refocus the chemical shift evolution and thus prevent the build-up of randomlyMicrosecond time-scale dynamics from relaxation in the rotating frame: experiments using spin lockřūņxřūxřūņxř . . ., is proposed as a new technique to probe microsecond time-scale dynamics. A series of R1q measurements using

  10. Surface wave chemical detector using optical radiation

    DOE Patents [OSTI]

    Thundat, Thomas G.; Warmack, Robert J.

    2007-07-17T23:59:59.000Z

    A surface wave chemical detector comprising at least one surface wave substrate, each of said substrates having a surface wave and at least one measurable surface wave parameter; means for exposing said surface wave substrate to an unknown sample of at least one chemical to be analyzed, said substrate adsorbing said at least one chemical to be sensed if present in said sample; a source of radiation for radiating said surface wave substrate with different wavelengths of said radiation, said surface wave parameter being changed by said adsorbing; and means for recording signals representative of said surface wave parameter of each of said surface wave substrates responsive to said radiation of said different wavelengths, measurable changes of said parameter due to adsorbing said chemical defining a unique signature of a detected chemical.

  11. Efficient electronic structure calculation for molecular ionization dynamics at high x-ray intensity

    E-Print Network [OSTI]

    Hao, Yajiang; Hanasaki, Kota; Son, Sang-Kil; Santra, Robin

    2015-01-01T23:59:59.000Z

    We present the implementation of an electronic-structure approach dedicated to ionization dynamics of molecules interacting with x-ray free-electron laser (XFEL) pulses. In our scheme, molecular orbitals for molecular core-hole states are represented by linear combination of numerical atomic orbitals that are solutions of corresponding atomic core-hole states. We demonstrate that our scheme efficiently calculates all possible multiple-hole configurations of molecules formed during XFEL pulses. The present method is suitable to investigate x-ray multiphoton multiple ionization dynamics and accompanying nuclear dynamics, providing essential information on the chemical dynamics relevant for high-intensity x-ray imaging.

  12. Exposure Levels for Chemical Threat Compounds; Information to Facilitate Chemical Incident Response

    SciTech Connect (OSTI)

    Hauschild, Veronique [U.S. Army Public Health Command] [U.S. Army Public Health Command; Watson, Annetta Paule [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Exposure Standards, Limits and Guidelines for Chemical Threat Compunds ABSTRACT Exposure criteria for chemical warfare (CW) agents and certain toxic industrial chemicals (TICs) used as CW agents (such as chlorine fill in an improvised explosive device) have been developed for protection of the civilian general public, civilian employees in chemical agent processing facilities and deployed military populations. In addition, compound-specific concentrations have been developed to serve as how clean is clean enough clearance criteria guiding facility recovery following chemical terrorist or other hazardous release events. Such criteria are also useful to verify compound absence, identify containment boundaries and expedite facility recovery following chemical threat release. There is no single right value or concentration appropriate for all chemical hazard control applications. It is acknowledged that locating and comparing the many sources of CW agent and TIC exposure criteria has not been previously well-defined. This paper summarizes many of these estimates and assembles critical documentation regarding their derivation and use.

  13. Chemical compatibility screening test results

    SciTech Connect (OSTI)

    Nigrey, P.J.; Dickens, T.G.

    1997-12-01T23:59:59.000Z

    A program for evaluating packaging components that may be used in transporting mixed-waste forms has been developed and the first phase has been completed. This effort involved the screening of ten plastic materials in four simulant mixed-waste types. These plastics were butadiene-acrylonitrile copolymer rubber, cross-linked polyethylene (XLPE), epichlorohydrin rubber, ethylene-propylene rubber (EPDM), fluorocarbon (Viton or Kel-F), polytetrafluoroethylene, high-density polyethylene (HDPE), isobutylene-isoprene copolymer rubber (butyl), polypropylene, and styrene-butadiene rubber (SBR). The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The testing protocol involved exposing the respective materials to 286,000 rads of gamma radiation followed by 14-day exposures to the waste types at 60{degrees}C. The seal materials were tested using vapor transport rate (VTR) measurements while the liner materials were tested using specific gravity as a metric. For these tests, a screening criterion of 0.9 g/hr/m{sup 2} for VTR and a specific gravity change of 10% was used. Based on this work, it was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only Viton passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. For specific gravity testing of liner materials, the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE offered the greatest resistance to the combination of radiation and chemicals.

  14. West Virginia University 1 Department of Chemical Engineering

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    West Virginia University 1 Department of Chemical Engineering Degrees Offered ∑ Masters of Science in Chemical Engineering ∑ Masters of Science in Engineering with a major in Chemical Engineering ∑ Doctor of Philosophy with a major in Chemical Engineering The Department of Chemical Engineering, with fourteen active

  15. Center for Nano and Micro Manufacturing Chemical Hygiene Plan

    E-Print Network [OSTI]

    Woodall, Jerry M.

    Center for Nano and Micro Manufacturing Chemical Hygiene Plan Vers. 12/13 Page 1 Chemical Hygiene have a written Chemical Hygiene Plan. The Chemical Hygiene Plan includes laboratory-specific hazards. If you have any questions about this Chemical Hygiene Plan, please email Corey Wolin at cdwolin

  16. Shape Dynamics. An Introduction

    E-Print Network [OSTI]

    Julian Barbour

    2011-05-01T23:59:59.000Z

    Shape dynamics is a completely background-independent universal framework of dynamical theories from which all absolute elements have been eliminated. For particles, only the variables that describe the shapes of the instantaneous particle configurations are dynamical. In the case of Riemannian three-geometries, the only dynamical variables are the parts of the metric that determine angles. The local scale factor plays no role. This leads to a shape-dynamic theory of gravity in which the four-dimensional diffeomorphism invariance of general relativity is replaced by three-dimensional diffeomorphism invariance and three-dimensional conformal invariance. Despite this difference of symmetry groups, it is remarkable that the predictions of the two theories -- shape dynamics and general relativity -- agree on spacetime foliations by hypersurfaces of constant mean extrinsic curvature. However, the two theories are distinct, with shape dynamics having a much more restrictive set of solutions. There are indications that the symmetry group of shape dynamics makes it more amenable to quantization and thus to the creation of quantum gravity. This introduction presents in simple terms the arguments for shape dynamics, its implementation techniques, and a survey of existing results.

  17. Dynamic Instruction Fusion

    E-Print Network [OSTI]

    Lee, Ian

    2012-01-01T23:59:59.000Z

    SANTA CRUZ DYNAMIC INSTRUCTION FUSION A thesis submitted in4 2.2 Instruction Fusion & Complex10 3.1 Fusion Selection

  18. Nanoindentation Under Dynamic Conditions

    E-Print Network [OSTI]

    Wheeler, Jeffrey M

    2009-05-22T23:59:59.000Z

    ............................................................................................ 98† 6.3.1† Data Analysis ........................................................................................... 99† 6.3.2† Dynamic Compliance ............................................................................. 103† 6.3.3† Strain Rates...

  19. Chemical Enrichment from Massive Stars in Starbursts

    E-Print Network [OSTI]

    Henry A. Kobulnicky

    1999-01-20T23:59:59.000Z

    The warm ionized gas in low-mass, metal-poor starforming galaxies is chemically homogeneous despite the prevalence of large H II regions which contain hundreds of evolved massive stars, supernovae, and Wolf-Rayet stars with chemically-enriched winds. Galaxies with large Wolf-Rayet star content are chemically indistinguishable from other vigorously star-forming galaxies. Furthermore, no significant localized chemical fluctuations are present in the vicinity of young star clusters, despite large expected chemical yields of massive stars. An ad-hoc fine-tuning of the release, dispersal and mixing of the massive star ejecta could give rise to the observed homogeneity, but a more probable explanation is that fresh ejecta from massive stars reside in a hard-to-observe hot or cold phase. In any case, the observed chemical homogeneity indicates that heavy elements which have already mixed with the warm interstellar medium (thus accessible to optical spectroscopy) are homogeneously dispersed over scales exceeding 1 kpc. Mixing of fresh ejecta with the surrounding warm ISM apparently requires longer than the lifetimes of typical H II regions (>10^7 yrs). The lack of observed localized chemical enrichments is consistent with a scenario whereby freshly-synthesized metals from massive stars are expelled into the halos of galaxies in a hot, 10^6 K phase by supernova-driven winds before they cool and ``rain'' back down upon the galaxy, creating gradual enrichments on spatial scales >1 kpc.

  20. The photodissociation and reaction dynamics of vibrationally excited molecules

    SciTech Connect (OSTI)

    Crim, F.F. [Univ. of Wisconsin, Madison (United States)

    1993-12-01T23:59:59.000Z

    This research determines the nature of highly vibrationally excited molecules, their unimolecular reactions, and their photodissociation dynamics. The goal is to characterize vibrationally excited molecules and to exploit that understanding to discover and control their chemical pathways. Most recently the author has used a combination of vibrational overtone excitation and laser induced fluorescence both to characterize vibrationally excited molecules and to study their photodissociation dynamics. The author has also begun laser induced grating spectroscopy experiments designed to obtain the electronic absorption spectra of highly vibrationally excited molecules.

  1. Platform Chemicals from an Oilseed Biorefinery

    SciTech Connect (OSTI)

    Tupy, Mike; Schrodi Yann

    2006-11-06T23:59:59.000Z

    The US chemical industry is $460 billion in size where a $150 billion segment of which is non-oxygenated chemicals that is sourced today via petroleum but is addressable by a renewable feedstock if one considers a more chemically reduced feedstock such as vegetable oils. Vegetable oil, due to its chemical functionality, provides a largely untapped opportunity as a renewable chemical source to replace petroleum-derived chemicals and produce platform chemicals unavailable today. This project examined the fertile intersection between the rich building blocks provided by vegetable oils and the enhanced chemical modification capability provided by metathesis chemistry. The technology advanced in this study is the process of ethylene cross-metathesis (referred to as ethenolysis) with vegetable oil and vegetable oil derivatives to manufacture the platform-chemical 9-decenoic acid (or 9DA) and olefin co-products. The project team meet its goals of demonstrating improved catalyst efficiencies of several multiples, deepening the mechanistic understanding of metathesis, synthesis and screening of dozens of new catalysts, designing and modeling commercial processes, and estimating production costs. One demonstrable result of the study was a step change improvement in catalyst turnover number in the ethenolysis of methyl oleate as reported here. We met our key measurable of producing 100 lbs of 9DA at the pilot-scale, which demonstrated ability to scale-up ethenolysis. DOE Project funding had significant positive impact on development of metathetically modified vegetable oils more broadly as the Cargill/Materia partnership, that was able to initiate primarily due to DOE funding, has succeeded in commercializing products, validating metathesis as a platform technology, and expanding a diverse products portfolio in high value and in large volume markets. Opportunities have expanded and business development has gained considerable momentum and enabled further expansion of the Materia/Cargill relationship. This project exceeded expectations and is having immediate impact on DOE success by replacing petroleum products with renewables in a large volume application today.

  2. CHEMICAL SAFETY: ASKING THE RIGHT QUESTIONS

    SciTech Connect (OSTI)

    Simmons, F

    2008-08-05T23:59:59.000Z

    Recent reports have shown that, despite efforts to the contrary, chemical accidents continue to occur at an unacceptable rate and there is no evidence that this rate is decreasing. Based on this observation, one can conclude that previous analyses have not accurately identified and implemented appropriate fixes to eliminate identified root causes for chemical events. Based on this, it is time to reevaluate chemical accident data with a fresh eye and determine (a) what corrective actions have already been identified but have not been implemented, (b) what other root causes may be involved, and (c) what new corrective actions should be taken to eliminate these newly identified root causes.

  3. Chemical safety: asking the right questions

    SciTech Connect (OSTI)

    Whyte, Helena M [Los Alamos National Laboratory; Quigley, David [Y-12/NSC; Simmons, Fred [SRS; Freshwater, David [DOE/NNSA; Robertson, Janeen [LLNL

    2008-01-01T23:59:59.000Z

    Recent reports have shown that, despite efforts to the contrary, chemical accidents continue to occur at an unacceptable rate and there is no evidence that this rate is decreasing. Based on this observation, one can conclude that previous analyses have not accurately identified and implemented appropriate fixes to eliminate identified root causes for chemical events. Based on this, it is time to reevaluate chemical accident data with a fresh eye and determine (a) what corrective actions have already been identified but have not been implemented, (b) what other root causes may be involved, and (c) what new corrective actions should be taken to eliminate these newly identified root causes.

  4. Chemically modified graphite for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1998-05-26T23:59:59.000Z

    This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (1) the electrode, (2) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (3) a counter electrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes. 3 figs.

  5. Development of High Temperature/High Sensitivity Novel Chemical Resistive Sensor

    SciTech Connect (OSTI)

    Chen, Chonglin; Nash, Patrick; Ma, Chunrui; Enriquez, Erik; Wang, Haibing; Xu, Xing; Bao, Shangyong; Collins, Gregory

    2013-08-13T23:59:59.000Z

    The research has been focused to design, fabricate, and develop high temperature/high sensitivity novel multifunctional chemical sensors for the selective detection of fossil energy gases used in power and fuel systems. By systematically studying the physical properties of the LnBaCo{sub 2}O{sub 5+d} (LBCO) [Ln=Pr or La] thin?films, a new concept chemical sensor based high temperature chemical resistant change has been developed for the application for the next generation highly efficient and near zero emission power generation technologies. We also discovered that the superfast chemical dynamic behavior and an ultrafast surface exchange kinetics in the highly epitaxial LBCO thin films. Furthermore, our research indicates that hydrogen can superfast diffuse in the ordered oxygen vacancy structures in the highly epitaxial LBCO thin films, which suggest that the LBCO thin film not only can be an excellent candidate for the fabrication of high temperature ultra sensitive chemical sensors and control systems for power and fuel monitoring systems, but also can be an excellent candidate for the low temperature solid oxide fuel cell anode and cathode materials.

  6. Coalescence and Chemical Equilibrium in Multifragmentation at...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M. Veselsky, Invited Talk, Fifth International Conference on Dynamical Aspects of Nuclear Fission, Casta-Papiernicka, Slovak Republic (October 2001). VII-2 Fission Time Scales...

  7. Northwest National Laboratory's Chemical Imaging Initiative is...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulating streamflow and river dynamics. When coupled with established land and Earth system models, MOSART outperforms other river routing models and provides the basis for a...

  8. Chemical Hydrogen Storage R & D | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Storage Chemical Hydrogen Storage R & D Chemical Hydrogen Storage R & D DOE's chemical hydrogen storage R&D is focused on developing low-cost energy-efficient...

  9. Generalized models as a universal approach to the analysis of nonlinear dynamical systems

    E-Print Network [OSTI]

    Thilo Gross; Ulrike Feudel

    2006-01-29T23:59:59.000Z

    We present a universal approach to the investigation of the dynamics in generalized models. In these models the processes that are taken into account are not restricted to specific functional forms. Therefore a single generalized models can describe a class of systems which share a similar structure. Despite this generality, the proposed approach allows us to study the dynamical properties of generalized models efficiently in the framework of local bifurcation theory. The approach is based on a normalization procedure that is used to identify natural parameters of the system. The Jacobian in a steady state is then derived as a function of these parameters. The analytical computation of local bifurcations using computer algebra reveals conditions for the local asymptotic stability of steady states and provides certain insights on the global dynamics of the system. The proposed approach yields a close connection between modelling and nonlinear dynamics. We illustrate the investigation of generalized models by considering examples from three different disciplines of science: a socio-economic model of dynastic cycles in china, a model for a coupled laser system and a general ecological food web.

  10. Dynamic strength of concrete

    SciTech Connect (OSTI)

    Logunova, V.A.; Rudenko, V.V.; Radionov, A.K.; Sokolov, I.B.

    1994-12-01T23:59:59.000Z

    Recommendations for evaluating the dynamic strength of concrete structures at hydroelectric power stations are given. Both existing and planned structures are addressed. Equations are provided for determing the design compressive and tensile strength of concrete. A formula is provided for determining design dynamic strength of concrete of various ages under uniform compression. 3 refs., 1 fig., 2 tabs.

  11. Chemical Additive Selection in Matrix Acidizing

    E-Print Network [OSTI]

    Weidner, Jason 1981-

    2011-05-09T23:59:59.000Z

    This work proposes to survey new chemical knowledge, developed since 1984, on fluid additives used in matrix stimulation treatments of carbonate and sandstone petroleum reservoirs and describes one method of organizing this new knowledge in a...

  12. Chemical vapor infiltration using microwave energy

    DOE Patents [OSTI]

    Devlin, David J. (Los Alamos, NM); Currier, Robert P. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Barbero, Robert S. (Santa Cruz, NM)

    1993-01-01T23:59:59.000Z

    A method for producing reinforced ceramic composite articles by means of chemical vapor infiltration and deposition in which an inverted temperature gradient is utilized. Microwave energy is the source of heat for the process.

  13. Chemical and Petroleum Engineering Petroleum Engineering Minor

    E-Print Network [OSTI]

    Calgary, University of

    electives in Petroleum Reservoir Engineering and Petroleum Production Engineering Chemical and Petroleum Engineering Petroleum Engineering Minor Students their skills by taking a minor in petroleum engineering. Energy is the largest

  14. Electric Power Reliability in Chemical Plants

    E-Print Network [OSTI]

    Cross, M. B.

    The quality and reliability of utility-generated electric power is presently receiving a great deal of attention from the chemical and refining industry. What changes have taken place to make electric power reliability a major topic of discussion...

  15. Chemical sensor with oscillating cantilevered probe

    DOE Patents [OSTI]

    Adams, Jesse D

    2013-02-05T23:59:59.000Z

    The invention provides a method of detecting a chemical species with an oscillating cantilevered probe. A cantilevered beam is driven into oscillation with a drive mechanism coupled to the cantilevered beam. A free end of the oscillating cantilevered beam is tapped against a mechanical stop coupled to a base end of the cantilevered beam. An amplitude of the oscillating cantilevered beam is measured with a sense mechanism coupled to the cantilevered beam. A treated portion of the cantilevered beam is exposed to the chemical species, wherein the cantilevered beam bends when exposed to the chemical species. A second amplitude of the oscillating cantilevered beam is measured, and the chemical species is determined based on the measured amplitudes.

  16. Climate VISION: Private Sector Initiatives: Chemical Manufacturing...

    Office of Scientific and Technical Information (OSTI)

    target for the U.S. (7%) and the EU (8%). During the same period, chemical industry production rose 41%. As a result, GHG emissions intensity improved 38%. Indirect greenhouse gas...

  17. Frontiers in Chemical Imaging Seminar Series

    E-Print Network [OSTI]

    Frontiers in Chemical Imaging Seminar Series On the trail of the Chimera The Atom the Chimera is still elusive. 1. Thomas F. Kelly and David J. Larson. Ann Rev. Materials Res 42 (2012) 1. 2

  18. Sensor for detecting and differentiating chemical analytes

    DOE Patents [OSTI]

    Yi, Dechang (Metuchen, NJ); Senesac, Lawrence R. (Knoxville, TN); Thundat, Thomas G. (Knoxville, TN)

    2011-07-05T23:59:59.000Z

    A sensor for detecting and differentiating chemical analytes includes a microscale body having a first end and a second end and a surface between the ends for adsorbing a chemical analyte. The surface includes at least one conductive heating track for heating the chemical analyte and also a conductive response track, which is electrically isolated from the heating track, for producing a thermal response signal from the chemical analyte. The heating track is electrically connected with a voltage source and the response track is electrically connected with a signal recorder. The microscale body is restrained at the first end and the second end and is substantially isolated from its surroundings therebetween, thus having a bridge configuration.

  19. BIOMEDICAL ENGINEERING CHEMICAL AND BIOLOGICAL ENGINEERING

    E-Print Network [OSTI]

    Heller, Barbara

    BIOMEDICAL ENGINEERING CHEMICAL AND BIOLOGICAL ENGINEERING CIVIL, ARCHITECTURAL, AND ENVIRONMENTAL ENGINEERING ELECTRICAL AND COMPUTER ENGINEERING MECHANICAL, MATERIALS, AND AEROSPACE ENGINEERING COLLEGE OF ENGINEERING IIT ARMOUR #12;WHY ENGINEERINGAT IIT ARMOUR? Five Departments. One Distinctive Educational

  20. Chemical vapor deposition of antimicrobial polymer coatings

    E-Print Network [OSTI]

    Martin, Tyler Philip, 1977-

    2007-01-01T23:59:59.000Z

    There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...