National Library of Energy BETA

Sample records for disciplines chemical dynamics

  1. Sandia Energy - Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Dynamics Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry Chemical Dynamics Chemical DynamicsAshley Otero2015-10-28T02:45:37+00:00...

  2. Nonlinear chemical dynamics Francesc Sagusa

    E-Print Network [OSTI]

    Epstein, Irving R.

    Nonlinear chemical dynamics Francesc Saguésa and Irving R. Epsteinb a Departament de Química Física March 2003 The interdisciplinary field of nonlinear chemical dynamics has grown significantly in breadth an overview of some of the key results of nonlinear chemical dynamics, with emphasis on those areas most

  3. Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron

    E-Print Network [OSTI]

    Leone, Stephen R.

    2010-01-01

    novel measurements of chemical dynamics for clusters, Chemical Dynamics, Molecular Energetics, and Kinetics at theUniversity of California Chemical Sciences Division,

  4. Gas-phase chemical dynamics

    SciTech Connect (OSTI)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  5. Annual Report 2000. Chemical Structure and Dynamics

    SciTech Connect (OSTI)

    Colson, Steven D.; McDowell, Robin S.

    2001-04-15

    This annual report describes the research and accomplishments of the Chemical Structure and Dynamics Program in the year 2000, one of six research programs at the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) - a multidisciplinary, national scientific user facility and research organization. The Chemical Structure and Dynamics (CS&D) program is meeting the need for a fundamental, molecular-level understanding by 1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; 2) developing a multidisciplinary capability for describing interfacial chemical processes relevant to environmental chemistry; and 3) developing state-of-the-art research and analytical methods for characterizing complex materials of the types found in natural and contaminated systems.

  6. Chemical structure and dynamics: Annual report 1996

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1997-03-01

    The Chemical Structure and Dynamics (CS&D) program is a major component of the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of-the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for characterizing waste tanks and pollutant distributions, and for detecting and monitoring trace atmospheric species.

  7. Chemical structure and dynamics. Annual report 1995

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1996-05-01

    The Chemical Structure and Dynamics program is a major component of Pacific Northwest National Laboratory`s Environmental Molecular Sciences Laboratory (EMSL), providing a state-of-the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for the characterization of waste tanks and pollutant distributions, and for detection and monitoring of trace atmospheric species.

  8. Chemical weathering and chemical denudation dynamics through ecosystem development and disturbance

    E-Print Network [OSTI]

    Vermont, University of

    '' experiments to test the predictions of both disciplines regarding the influence of tree growth and harvest) denudation-dominated loss of nutrient reserves after harvest by disruption of biotic regulation. Overall to other phases such as soil water, clays, and biomass [Drever, 1997]. Chemical denudation (or chemical

  9. Chemical Structure and Dynamics annual report 1997

    SciTech Connect (OSTI)

    Colson, S.D.; McDowell, R.S.

    1998-03-01

    The Chemical Structure and Dynamics (CS and D) program is a major component of the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of-the-art collaborative facility for studies of chemical structure and dynamics. The authors respond to the need for a fundamental, molecular level understanding of chemistry at a wide variety of environmentally important interfaces by: (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage; and (3) developing state-of-the-art analytical methods for characterizing complex materials of the types found in stored wastes and contaminated soils, and for detecting and monitoring trace atmospheric species. The focus of the research is defined primarily by DOE`s environmental problems: fate and transport of contaminants in the subsurface environment, processing and storage of waste materials, cellular effects of chemical and radiological insult, and atmospheric chemistry as it relates to air quality and global change. Twenty-seven projects are described under the following topical sections: Reaction mechanisms at interfaces; High-energy processes at environmental interfaces; Cluster models of the condensed phase; and Miscellaneous.

  10. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluid Dynamics, January 1999 ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January 1999 cfdroadmap.pdf More Documents & Publications 3-D Combustion...

  11. Annual Report 1998: Chemical Structure and Dynamics

    SciTech Connect (OSTI)

    SD Colson; RS McDowell

    1999-05-10

    The Chemical Structure and Dynamics (CS&D) program is a major component of the William R. Wiley Environmental Molecular Sciences Labo- ratory (EMSL), developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of- the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interracial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in envi- ronmental chemistry and in nuclear waste proc- essing and storage; and (3) developing state-of- the-art analytical methods for characterizing com- plex materials of the types found in stored wastes and contaminated soils, and for detecting and monitoring trace atmospheric species. Our program aims at achieving a quantitative understanding of chemical reactions at interfaces and, more generally, in condensed media, compa- rable to that currently available for gas-phase reactions. This understanding will form the basis for the development of a priori theories for pre- dicting macroscopic chemical behavior in con- densed and heterogeneous media, which will add significantly to the value of field-scale envi- ronmental models, predictions of short- and long- term nuclear waste storage stabilities, and other areas related to the primary missions of the U.S. Department of Energy (DOE).

  12. Chemical structure and dynamics. Annual report 1994

    SciTech Connect (OSTI)

    Colson, S.D.

    1995-07-01

    The Chemical Structure and Dynamics program was organized as a major component of Pacific Northwest Laboratory`s Environmental and Molecular Sciences Laboratory (EMSL), a state-of-the-art collaborative facility for studies of chemical structure and dynamics. Our program responds to the need for a fundamental, molecular-level understanding of chemistry at the wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces, and (2) developing a multidisciplinary capability for describing interfacial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in environmental chemistry and in nuclear waste processing and storage. This research effort was initiated in 1989 and will continue to evolve over the next few years into a program of rigorous studies of fundamental molecular processes in model systems, such as well-characterized surfaces, single-component solutions, clusters, and biological molecules; and studies of complex systems found in the environment (multispecies, multiphase solutions; solid/liquid, liquid/liquid, and gas/surface interfaces; colloidal dispersions; ultrafine aerosols; and functioning biological systems). The success of this program will result in the achievement of a quantitative understanding of chemical reactions at interfaces, and more generally in condensed media, that is comparable to that currently available for gas-phase reactions. This understanding will form the basis for the development of a priori theories for predictions of macroscopic chemical behavior in condensed and heterogeneous media, adding significantly to the value of field-scale environmental models, the prediction of short- and long-term nuclear waste storage stabilities, and other problems related to the primary missions of the DOE.

  13. Theoretical studies of chemical reaction dynamics

    SciTech Connect (OSTI)

    Schatz, G.C. [Argonne National Laboratory, IL (United States)

    1993-12-01

    This collaborative program with the Theoretical Chemistry Group at Argonne involves theoretical studies of gas phase chemical reactions and related energy transfer and photodissociation processes. Many of the reactions studied are of direct relevance to combustion; others are selected they provide important examples of special dynamical processes, or are of relevance to experimental measurements. Both classical trajectory and quantum reactive scattering methods are used for these studies, and the types of information determined range from thermal rate constants to state to state differential cross sections.

  14. Molecular dynamics study of fracture accompanied by chemical reaction

    E-Print Network [OSTI]

    Krivtsov, Anton M.

    Molecular dynamics study of fracture accompanied by chemical reaction Anton M. Krivtsov akrivtsov@bk.ru Abstract A molecular dynamics model for fracture accompanied by chemical reac- tion is suggested. Crack of the initial and new specimen surfaces during the fracture process is taken into account. It is pos- tulated

  15. Quantum dynamics of fast chemical reactions

    SciTech Connect (OSTI)

    Light, J.C. [Univ. of Chicago, IL (United States)

    1993-12-01

    The aims of this research are to explore, develop, and apply theoretical methods for the evaluation of the dynamics of gas phase collision processes, primarily chemical reactions. The primary theoretical tools developed for this work have been quantum scattering theory, both in time dependent and time independent forms. Over the past several years, the authors have developed and applied methods for the direct quantum evaluation of thermal rate constants, applying these to the evaluation of the hydrogen isotopic exchange reactions, applied wave packet propagation techniques to the dissociation of Rydberg H{sub 3}, incorporated optical potentials into the evaluation of thermal rate constants, evaluated the use of optical potentials for state-to-state reaction probability evaluations, and, most recently, have developed quantum approaches for electronically non-adiabatic reactions which may be applied to simplify calculations of reactive, but electronically adiabatic systems. Evaluation of the thermal rate constants and the dissociation of H{sub 3} were reported last year, and have now been published.

  16. Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron

    SciTech Connect (OSTI)

    Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.

    2010-03-14

    Scientists at the Chemical Dynamics Beamline of the Advanced Light Source in Berkeley are continuously reinventing synchrotron investigations of physical chemistry and chemical physics with vacuum ultraviolet light. One of the unique aspects of a synchrotron for chemical physics research is the widely tunable vacuum ultraviolet light that permits threshold ionization of large molecules with minimal fragmentation. This provides novel opportunities to assess molecular energetics and reaction mechanisms, even beyond simple gas phase molecules. In this perspective, significant new directions utilizing the capabilities at the Chemical Dynamics Beamline are presented, along with an outlook for future synchrotron and free electron laser science in chemical dynamics. Among the established and emerging fields of investigations are cluster and biological molecule spectroscopy and structure, combustion flame chemistry mechanisms, radical kinetics and product isomer dynamics, aerosol heterogeneous chemistry, planetary and interstellar chemistry, and secondary neutral ion-beam desorption imaging of biological matter and materials chemistry.

  17. THE JOURNAL OF CHEMICAL PHYSICS 139, 175101 (2013) Dynamic neutron scattering from conformational dynamics. I. Theory

    E-Print Network [OSTI]

    2013-01-01

    #12;THE JOURNAL OF CHEMICAL PHYSICS 139, 175101 (2013) Dynamic neutron scattering from, a conformational dynamics theory of dynamical neutron and X-ray scattering is developed, follow- ing our previous spectroscopy (dynamic neutron scattering) probes time correlations on the sub pico- to microsec- ond timescales

  18. Uncertain dynamics in nonlinear chemical reactions Jichang Wang,a

    E-Print Network [OSTI]

    Showalter, Kenneth

    Uncertain dynamics in nonlinear chemical reactions Jichang Wang,a Hongyan Sun,b Stephen K. Scottc a dissociation reaction of the autocatalytic species, B ! X + Y, followed by a recombination reaction, X + Y ! C evolution of the system. 1. Introduction The study of nonlinear chemical kinetics has flourished in the past

  19. Reaction ensemble molecular dynamics: Direct simulation of the dynamic equilibrium properties of chemically reacting mixtures

    E-Print Network [OSTI]

    Lisal, Martin

    diffusion) as well as reaction equilibria for chemically reacting mixtures. DOI: 10.1103/PhysRevE.70.) on chemical reaction equilibria is critical in many fields of science including mixture separationReaction ensemble molecular dynamics: Direct simulation of the dynamic equilibrium properties

  20. Designing a service science discipline with discipline

    E-Print Network [OSTI]

    Glushko, Robert J.

    in what IBM began to call, in late 2004, service science, management and engineering--or simply SSME. 3 in information and computing technol- ogy, industrial engineering, business strategy, eco- nomics, lawDesigning a service science discipline with discipline & R. J. Glushko This paper relates our

  1. Simulation of chemical reaction dynamics on an NMR quantum computer

    E-Print Network [OSTI]

    Dawei Lu; Nanyang Xu; Ruixue Xu; Hongwei Chen; Jiangbin Gong; Xinhua Peng; Jiangfeng Du

    2011-05-21

    Quantum simulation can beat current classical computers with minimally a few tens of qubits and will likely become the first practical use of a quantum computer. One promising application of quantum simulation is to attack challenging quantum chemistry problems. Here we report an experimental demonstration that a small nuclear-magnetic-resonance (NMR) quantum computer is already able to simulate the dynamics of a prototype chemical reaction. The experimental results agree well with classical simulations. We conclude that the quantum simulation of chemical reaction dynamics not computable on current classical computers is feasible in the near future.

  2. Administering Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2015-05-14

    The order provides requirements and responsibilities for administering work force discipline and corrective actions. Supersedes DOE O 3750.1.

  3. Chemical dynamics in the gas phase: Time-dependent quantum mechanics of chemical reactions

    SciTech Connect (OSTI)

    Gray, S.K. [Argonne National Laboratory, IL (United States)

    1993-12-01

    A major goal of this research is to obtain an understanding of the molecular reaction dynamics of three and four atom chemical reactions using numerically accurate quantum dynamics. This work involves: (i) the development and/or improvement of accurate quantum mechanical methods for the calculation and analysis of the properties of chemical reactions (e.g., rate constants and product distributions), and (ii) the determination of accurate dynamical results for selected chemical systems, which allow one to compare directly with experiment, determine the reliability of the underlying potential energy surfaces, and test the validity of approximate theories. This research emphasizes the use of recently developed time-dependent quantum mechanical methods, i.e. wave packet methods.

  4. Computational Chemical Dynamics of Complex Systems University of Minnesota

    E-Print Network [OSTI]

    Truhlar, Donald G

    Computational Chemical Dynamics of Complex Systems University of Minnesota Accuracy of density functionals for Pd(PH3)2L complexes where L is ethene or a conjugated CnHn+2 system (n = 4, 6, 8, and 10) Pd large when the size of the conjugated system is increased. We carried out accurate benchmark

  5. Molecular Dynamics Simulations of Solutions at Constant Chemical Potential

    E-Print Network [OSTI]

    Perego, Claudio; Parrinello, Michele

    2015-01-01

    Molecular Dynamics studies of chemical processes in solution are of great value in a wide spectrum of applications, that range from nano-technology to pharmaceutical chemistry. However, these calculations are affected by severe finite-size effects, such as the solution being depleted as the chemical process proceeds, that influence the outcome of the simulations. To overcome these limitations, one must allow the system to exchange molecules with a macroscopic reservoir, thus sampling a Grand-Canonical ensemble. Despite the fact that different remedies have been proposed, this still represents a key challenge in molecular simulations. In the present work we propose the C$\\mu$MD method, which introduces an external force that controls the environment of the chemical process of interest. This external force, drawing molecules from a finite reservoir, maintains the chemical potential constant in the region where the process takes place. We have applied the C$\\mu$MD method to the paradigmatic case of urea crystall...

  6. THE JOURNAL OF CHEMICAL PHYSICS 139, 175102 (2013) Dynamic neutron scattering from conformational dynamics. II. Application

    E-Print Network [OSTI]

    2013-01-01

    #12;THE JOURNAL OF CHEMICAL PHYSICS 139, 175102 (2013) Dynamic neutron scattering from; accepted 12 September 2013; published online 1 November 2013) Neutron scattering experiments directly probe.1063/1.4824071] I. INTRODUCTION Dynamic neutron scattering is a direct probe of the inter- nal, conformational

  7. Administering Workforce Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-10-27

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  8. Introduction to Computational Fluid Dynamics 424512 E #2 -rz maj 2015 bo Akademi Univ -Chemical Engineering

    E-Print Network [OSTI]

    Zevenhoven, Ron

    .zevenhoven@abo.fi Introduction to Computational Fluid Dynamics 424512 E #2 - rz maj 2015 Åbo Akademi Univ - Chemical Engineering Dynamics 424512 E #2 - rz maj 2015 Åbo Akademi Univ - Chemical Engineering Thermal and Flow Engineering Introduction to Computational Fluid Dynamics 424512 E #2 - rz maj 2015 Åbo Akademi Univ - Chemical Engineering

  9. Chemistry 231 Fall 2013 Chemistry 231, Chemical Kinetics and Molecular Reaction Dynamics

    E-Print Network [OSTI]

    Continetti, Robert E.

    Chemistry 231 Fall 2013 Chemistry 231, Chemical Kinetics and Molecular Reaction Dynamics Dept chemical kinetics, the connection between chemical kinetics and molecular reaction dynamics as well as some and Hase, Prentice Hall (1999) 4. Chemical Kinetics, K.J. Laidler, McGraw Hill (1965) 5. Gas Phase Reaction

  10. Molecular dynamics simulations of a chemical reaction; conditions for local equilibrium in a temperature gradient

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Molecular dynamics simulations of a chemical reaction; conditions for local equilibrium have examined a simple chemical reaction in a temperature gradient; 2F $ F2. A mechanical model molecular dynamics simulations showed that the chemical reaction is in local thermodynamic as well

  11. Influence of Chemical Reactions on the Nonlinear Dynamics of Dissipative Flows

    E-Print Network [OSTI]

    A. R. Karimov; A. M. Korshunov; V. V. Beklemishev

    2015-04-16

    The nonlinear dynamics of resistive flow with a chemical reaction is studied. Proceeding from the Lagrangian description, the influence of a chemical reaction on the development of fluid singularities is considered.

  12. Analysis of forward and inverse problems in chemical dynamics and spectroscopy

    SciTech Connect (OSTI)

    Rabitz, H. [Princeton Univ., NJ (United States)

    1993-12-01

    The overall scope of this research concerns the development and application of forward and inverse analysis tools for problems in chemical dynamics and chemical kinetics. The chemical dynamics work is specifically associated with relating features in potential surfaces and resultant dynamical behavior. The analogous inverse research aims to provide stable algorithms for extracting potential surfaces from laboratory data. In the case of chemical kinetics, the focus is on the development of systematic means to reduce the complexity of chemical kinetic models. Recent progress in these directions is summarized below.

  13. Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1983-03-23

    The order provides guidance and procedures and states responsibilities for maintaining work force discipline in DOE. Chg 1, dated 3-11-85; Chg 2, dated 1-6-86; Chg 3, dated 3-21-89; Chg 4, dated 8-2-90; Chg 5, dated 3-9-92; Chg 6, dated 8-21-92, cancels Chg 5.

  14. Chemical and dynamical discontinuity at the extratropical tropopause based on START08 and WACCM analyses

    E-Print Network [OSTI]

    Pan, Laura

    Chemical and dynamical discontinuity at the extratropical tropopause based on START08 and WACCM gas gradients of O3 and CO, the discontinuity in the chemical composition of the upper troposphere (UT good consistency between the chemical discontinuity in trace gas distributions and the PV gradientbased

  15. Introduction to Computational Fluid Dynamics 424512 E #5-rz maj 2015 bo Akademi Univ -Chemical Engineering

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ://users.abo.fi/rzevenho/kursRZ.html#FPS Introduction to Computational Fluid Dynamics 424512 E #5- rz maj 2015 Åbo Akademi Univ - Chemical Engineering - Chemical Engineering Thermal and Flow Engineering - Biskopsgatan 8, 20500 Turku 3/70 Fluid flow around 2015 Åbo Akademi Univ - Chemical Engineering Thermal and Flow Engineering - Biskopsgatan 8, 20500 Turku

  16. Chemical Imaging and Dynamical Studies of Reactivity and Emergent...

    Office of Scientific and Technical Information (OSTI)

    uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted...

  17. The Development of Dynamic Operational Risk Assessment in Oil/Gas and Chemical Industries 

    E-Print Network [OSTI]

    Yang, Xiaole

    2011-08-08

    In oil/gas and chemical industries, dynamics is one of the most essential characteristics of any process. Time-dependent response is involved in most steps of both the physical/engineering processes and the equipment ...

  18. Exciplex funnel resonances in chemical reaction dynamics: The nonadiabatic tunneling case associated with an avoided

    E-Print Network [OSTI]

    Truhlar, Donald G

    Exciplex funnel resonances in chemical reaction dynamics: The nonadiabatic tunneling case mechanical calculations on a one-dimensional model of a chemical reaction with an electronically excited diabat and metastable trapping (resonances). Particular emphasis is placed on the eect of the funnel

  19. Microsoft Word - Dynamic Chemical Imaging at Nanoscale bh

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carried out using linear voltammetry at two consecutive sweep rates, V 1 and V 2 . Images were acquired at different x-ray photon energies and cell potentials, and chemical...

  20. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January 1999

    Broader source: Energy.gov [DOE]

    As the 21st century approaches, the chemical industry faces considerable economic, environmental and societal challenges. CFD can assist the design and optimization of new and existing processes and products.

  1. Regulation 2: Student Discipline REGULATION 2: STUDENT DISCIPLINE

    E-Print Network [OSTI]

    Sussex, University of

    Regulation 2: Student Discipline 6 REGULATION 2: STUDENT DISCIPLINE 1. Definitions In this Regulation: The University means the University of Sussex. Council means Council of the University. Senate to the regulations of the affiliated institution, and excluding students in attendance at the Brighton and Sussex

  2. Electronic processes in fast thermite chemical reactions: A first-principles molecular dynamics study

    E-Print Network [OSTI]

    Southern California, University of

    Electronic processes in fast thermite chemical reactions: A first-principles molecular dynamics composites. We have investigated the thermite reaction of Fe2O3 with aluminum by molecular dynamics as thermite reaction, is widely utilized in the synthesis and processing of materials 1 . In addition

  3. Software Engineering Discipline November 1992

    E-Print Network [OSTI]

    Berry, Daniel M.

    Software Engineering Discipline November 1992 Daniel M. Berry ESC-TR-92-034 Academic Legitimacy Legitimacy of the Software Engineering Discipline Daniel M. Berry MSE Project Approved for public release Distribution unlimited Software Engineering Institute Carnegie Mellon University Pittsburgh, Pennsylvania 15213

  4. Computational fluid dynamic simulations of chemical looping fuel reactors utilizing gaseous fuels

    SciTech Connect (OSTI)

    Mahalatkar, K.; Kuhlman, J.; Huckaby, E.D.; O'Brien, T.

    2011-01-01

    A computational fluid dynamic(CFD) model for the fuel reactor of chemical looping combustion technology has been developed,withspecialfocusonaccuratelyrepresentingtheheterogeneous chemicalreactions.Acontinuumtwo-fluidmodelwasusedtodescribeboththegasandsolidphases. Detailedsub-modelstoaccountforfluid–particleandparticle–particleinteractionforceswerealso incorporated.Twoexperimentalcaseswereanalyzedinthisstudy(Son andKim,2006; Mattisonetal., 2001). SimulationswerecarriedouttotestthecapabilityoftheCFDmodeltocapturechangesinoutletgas concentrationswithchangesinnumberofparameterssuchassuperficialvelocity,metaloxide concentration,reactortemperature,etc.Fortheexperimentsof Mattissonetal.(2001), detailedtime varyingoutletconcentrationvalueswerecompared,anditwasfoundthatCFDsimulationsprovideda reasonablematchwiththisdata.

  5. FLUID DYNAMICAL AND MODELING ISSUES OF CHEMICAL FLOODING FOR ENHANCED OIL RECOVERY

    E-Print Network [OSTI]

    Daripa, Prabir

    of the objective functions in tertiary oil recovery by polymer flooding is the "op- timal" viscous profileFLUID DYNAMICAL AND MODELING ISSUES OF CHEMICAL FLOODING FOR ENHANCED OIL RECOVERY Prabir Daripa are succinctly summarized including characteri- zation of the optimal flooding scheme that leads to maximum oil

  6. Constant centrifugal potential approximation for atom-diatom chemical reaction dynamics

    E-Print Network [OSTI]

    Takada, Shoji

    Constant centrifugal potential approximation for atom-diatom chemical reaction dynamics Kengo,Myodaiji, Okazaki 444. Japan (Received 28 September 1993; accepted 8 December 1993) The constant centrifugal of such practically useful approxima- tions the constant centrifugal potential approximation (CCPA) (or the energy

  7. A combined quantum-classical dynamics method for calculating thermal rate constants of chemical reactions in solution

    E-Print Network [OSTI]

    Truong, Thanh N.

    -flux correlation function for calculating the thermal rate constants of chemical reactions in solution in this study would provide a complete tool for studying the quantum dynamics of chemical reactions the thermal chemical reaction rate constants. Furthermore, we also employ an efficient and accurate quantum

  8. Chemical spots and their dynamical evolution on HgMn stars

    E-Print Network [OSTI]

    Korhonen, Heidi; Briquet, Maryline; Gonzalez, Federico; Savanov, Igor

    2010-01-01

    Our recent studies of late B-type stars with HgMn peculiarity revealed for the first time the presence of fast dynamical evolution of chemical spots on their surfaces. These observations suggest a hitherto unknown physical process operating in the stars with radiative outer envelopes. Furthermore, we have also discovered existence of magnetic fields on these stars that have up to now been thought to be non-magnetic. Here we will discuss the dynamical spot evolution on HD 11753 and our new results on magnetic fields on AR Aur.

  9. Applications of recurrence quantified analysis to study the dynamics of chaotic chemical reaction

    E-Print Network [OSTI]

    H. Castellini; L. Romanelli

    2002-11-28

    Recurrence plot is a quite easy tool to be used in time series analysis,in particular for measuring unstable periodic orbits embedded in a chaotic dynamical system. Recurrence quantified analysis (RQA) is an advance tool that allows the study of intrinsic complexity of dynamical system with a set of few parameters. We use RQA for measuring chaotic transitions of NADH chemical reaction and determine numerically its characteristic parameters such as: Correlation integral, information entropy, Maximal Lyapunov's exponent, etc. For this work we have developed command sets with performance better than TISEAN package

  10. Origin of chemical and dynamical properties of the Galactic thick disk

    E-Print Network [OSTI]

    Bekki, Kenji

    2011-01-01

    We adopt a scenario in which the Galactic thick disk was formed by minor merging between the first generation of the Galactic thin disk (FGTD) and a dwarf galaxy about 9 Gyr ago and thereby investigate chemical and dynamical properties of the Galactic thick disk. In this scenario, the dynamical properties of the thick disk have long been influenced both by the mass growth of the second generation of the Galactic thin disk (i.e., the present thin disk) and by its non-axisymmetric structures. On the other hand, the early star formation history and chemical evolution of the thin disk was influenced by the remaining gas of the thick disk. Based on N-body simulations and chemical evolution models, we investigate the radial metallicity gradient, structural and kinematical properties, and detailed chemical abundance patterns of the thick disk. Our numerical simulations show that the ancient minor merger event can significantly flatten the original radial metallicity gradient of the FGTD, in particular, in the outer ...

  11. ORIGIN OF CHEMICAL AND DYNAMICAL PROPERTIES OF THE GALACTIC THICK DISK

    SciTech Connect (OSTI)

    Bekki, Kenji [ICRAR, M468, University of Western Australia, Crawley, Western Australia, 6009 (Australia); Tsujimoto, Takuji [National Astronomical Observatory, Mitaka-shi, Tokyo 181-8588 (Japan)

    2011-09-01

    We adopt a scenario in which the Galactic thick disk was formed by minor merging between the first generation of the Galactic thin disk (FGTD) and a dwarf galaxy about {approx}9 Gyr ago and thereby investigate chemical and dynamical properties of the Galactic thick disk. In this scenario, the dynamical properties of the thick disk have long been influenced both by the mass growth of the second generation of the Galactic thin disk (i.e., the present thin disk) and by its non-axisymmetric structures. On the other hand, the early star formation history and chemical evolution of the thin disk was influenced by the remaining gas of the thick disk. Based on N-body simulations and chemical evolution models, we investigate the radial metallicity gradient, structural and kinematical properties, and detailed chemical abundance patterns of the thick disk. Our numerical simulations show that the ancient minor merger event can significantly flatten the original radial metallicity gradient of the FGTD, in particular, in the outer part, and also can be responsible for migration of inner metal-rich stars into the outer part (R > 10 kpc). The simulations show that the central region of the thick disk can develop a bar due to dynamical effects of a separate bar in the thin disk. Whether or not rotational velocities (V{sub {phi}}) can correlate with metallicities ([Fe/H]) for the simulated thick disks depends on the initial metallicity gradients of the FGTDs. The simulated orbital eccentricity distributions in the thick disk for models with higher mass ratios ({approx}0.2) and lower orbital eccentricities ({approx}0.5) of minor mergers are in good agreement with the corresponding observations. The simulated V{sub {phi}}-|z| relation of the thick disk in models with low orbital inclination angles of mergers are also in good agreement with the latest observational results. The vertical metallicity gradient of the simulated thick disk is rather flat or very weakly negative in the solar neighborhood. Our Galactic chemical evolution models show that if we choose two distinctive timescales for star formation in the thin and thick disks, then the models can explain both the observed metallicity distribution functions and correlations between [Mg/Fe] and [Fe/H] for the two disks in a self-consistent manner. We discuss how the early star formation history and chemical evolution of the Galactic thin disk can be influenced by the pre-existing thick disk.

  12. Studying chemical reactions in biological systems with MBN Explorer: implementation of molecular mechanics with dynamical topology

    E-Print Network [OSTI]

    Sushko, Gennady B; Verkhovtsev, Alexey V; Volkov, Sergey N; Solov'yov, Andrey V

    2015-01-01

    The concept of molecular mechanics force field has nowadays been widely accepted for studying various processes in biomolecular systems. In this paper we suggest a modification for the standard CHARMM force field, that permits simulations of systems with dynamically changing molecular topologies. The implementation of the modified force field was carried out in the popular program MBN Explorer, and, to support the development, in this paper we provide several case studies where dynamical topology is necessary. In particular, it is shown, that the modified molecular mechanics force field can be applied for studying processes where rupture of chemical bonds plays an essential role, e.g., in irradiation or collision induced damage, transformation and fragmentation processes involving biomolecular systems.

  13. The Dynamical and Chemical Evolution of Dwarf Spheroidal Galaxies with GEAR

    E-Print Network [OSTI]

    Revaz, Yves

    2011-01-01

    We present a fully parallel chemo-dynamical Tree/SPH code, GEAR, which allows to perform high resolution simulations with detailed chemical diagnostics. Starting from the public version of Gadget-2, we included the complex treatment of the baryon physics: gas cooling, star formation law, chemical evolution and supernovae feedback. We qualified the performances of GEAR with the case of dSph galaxies. GEAR conserves the total energy budget of the systems to better than 5% over 14Gyr and proved excellent convergence of the results with numerical resolution. We showed that models of dSphs in a static Euclidean space, where the expansion of the universe is neglected are valid. In addition, we tackled some of the existing open questions in the field, like the stellar mass fraction of dSphs and its link with the predicted dark matter halo mass function, the effect of the supernova feedback, the spatial distribution of the stellar populations, and the origin of the diversity in star formation histories and chemical a...

  14. PhD Chemical Engineering MS Chemical Engineering

    E-Print Network [OSTI]

    Collins, Gary S.

    1 PhD Chemical Engineering MS Chemical Engineering Bylaws Gene and Linda Voiland School of Chemical Engineering and Bioengineering College of Engineering and Architecture Approved by Voiland School facultyD Chemical Engineering, MS Chemical Engineering B. Discipline: Edgar, et al.1 provide a succinct description

  15. Software Engineering, an established Accreditable Engineering Discipline

    E-Print Network [OSTI]

    Szabados, Barna

    Software Engineering, an established Accreditable Engineering Discipline By B.Szabados, P.Eng, Mc of the Canadian Engineering Accreditation Board (CEAB), as well as at a workshop at the NCDEAS meeting in September 1997. 1. INTRODUCTION In the late seventies, the discipline of Computer Engineering has evolved

  16. A Molecular Dynamics Study of Chemical Reactions of Solid Pentaerythritol Tetranitrate at Extreme Conditions

    SciTech Connect (OSTI)

    Wu, C J; Manaa, M R; Fried, L E

    2006-05-30

    We have carried out density functional based tight binding (DFTB) molecular dynamics (MD) simulation to study energetic reactions of solid Pentaerythritol Tetranitrate (PETN) at conditions approximating the Chapman-Jouguet (CJ) detonation state. We found that the initial decomposition of PETN molecular solid is characterized by uni-molecular dissociation of the NO{sub 2}groups. Interestingly, energy release from this powerful high explosive was found to proceed in several stages. The large portion of early stage energy release was found to be associated with the formation of H{sub 2}O molecules within a few picoseconds of reaction. It took nearly four times as long for majority of CO{sub 2} products to form, accompanied by a slow oscillatory conversion between CO and CO{sub 2}. The production of N{sub 2} starts after NO{sub 2} loses its oxygen atoms to hydrogen or carbon atoms to form H{sub 2}O or CO. We identified many intermediate species that emerge and contribute to reaction kinetics, and compared our simulation with a thermo-chemical equilibrium calculation. In addition, a detailed chemical kinetics of formation of H{sub 2}O, CO, and CO{sub 2} were developed. Rate constants of formations of H{sub 2}O, CO{sub 2} and N{sub 2} were reported.

  17. Sandia Energy - Scattering Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scattering Dynamics Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry Chemical Dynamics Scattering Dynamics Scattering DynamicsAshley...

  18. REPRESENTING AEROSOL DYNAMICS AND PROPERTIES IN CHEMICAL TRANSPORT MODELS BY THE METHOD OF MOMENTS

    E-Print Network [OSTI]

    shortwave (solar) radiation, affecting climate (Charlson et al., 1992; Schwartz, 1996) and visibility this distribution and its evolution in chemical transport models. Atmospheric chemical transport models to date

  19. THE JOURNAL OF CHEMICAL PHYSICS 138, 244310 (2013) Molecular dynamics simulations for CO2 spectra. IV. Collisional line-mixing

    E-Print Network [OSTI]

    Boyer, Edmond

    2013-01-01

    atmosphere of Venus (about 96.5% of CO2) where the pressure is high (up to 90 bar). Similarly, narrow involving CO2 with a few for the pure gas in the infrared at high pressure12­17 and Raman Q branches.4THE JOURNAL OF CHEMICAL PHYSICS 138, 244310 (2013) Molecular dynamics simulations for CO2 spectra

  20. THE JOURNAL OF CHEMICAL PHYSICS 142, 212408 (2015) Dynamics of water, methanol, and ethanol in a room temperature

    E-Print Network [OSTI]

    Fayer, Michael D.

    2015-01-01

    THE JOURNAL OF CHEMICAL PHYSICS 142, 212408 (2015) Dynamics of water, methanol, and ethanol with increasing alkyl chain length: water, methanol, and ethanol, diluted to low concentration in the room is increased: 23 ps for water, 28 ps for methanol, and 34 ps for ethanol. Although in each case, only a single

  1. The Department of Chemical Engineering's graduate program at Texas Tech University is dynamic and internationally visible.

    E-Print Network [OSTI]

    Rock, Chris

    RESEARCH The Department of Chemical Engineering's graduate program at Texas Tech University and Sustainability · Polymers and Materials · Simulation and Modeling in Chemical Engineering GRADUATE PROGRAMS of Science in Chemical Engineering A written thesis and a minimum of 24 hours of graduate-level coursework

  2. At Rice, the Department of Electrical and Computer Engineering (ECE) is a dynamic and broad disci-pline that uses principles in mathematics, physics, and chemistry to address the challenges in engineer-

    E-Print Network [OSTI]

    Natelson, Douglas

    At Rice, the Department of Electrical and Computer Engineering (ECE) is a dynamic and broad disci and formal. THE PROGRAMS The Electrical and Computer Engineering graduate program is the second largest of Electrical Engineering (M.E.E.), Master of Science (M.S.), and Doctor of Philosophy (Ph.D). These degrees

  3. The Dynamics of Fluid Flow and Associated Chemical Fluxes at Active Continental Margins

    E-Print Network [OSTI]

    Solomon, Evan A

    2007-01-01

    mixture of fluids introduced during drilling and in situfluid and sediment Ba concentrations from Ocean Drillingof drilling indicators (IR imagery and pore fluid chemical

  4. The Dynamics of fluid flow and associated chemical fluxes at active continental margins

    E-Print Network [OSTI]

    Solomon, Evan Alan

    2007-01-01

    mixture of fluids introduced during drilling and in situfluid and sediment Ba concentrations from Ocean Drillingof drilling indicators (IR imagery and pore fluid chemical

  5. Coupled molecular dynamics-Monte Carlo model to study the role of chemical processes during laser ablation of polymeric materials

    SciTech Connect (OSTI)

    Prasad, Manish; Conforti, Patrick F.; Garrison, Barbara J.

    2007-08-28

    The coarse grained chemical reaction model is enhanced to build a molecular dynamics (MD) simulation framework with an embedded Monte Carlo (MC) based reaction scheme. The MC scheme utilizes predetermined reaction chemistry, energetics, and rate kinetics of materials to incorporate chemical reactions occurring in a substrate into the MD simulation. The kinetics information is utilized to set the probabilities for the types of reactions to perform based on radical survival times and reaction rates. Implementing a reaction involves changing the reactants species types which alters their interaction potentials and thus produces the required energy change. We discuss the application of this method to study the initiation of ultraviolet laser ablation in poly(methyl methacrylate). The use of this scheme enables the modeling of all possible photoexcitation pathways in the polymer. It also permits a direct study of the role of thermal, mechanical, and chemical processes that can set off ablation. We demonstrate that the role of laser induced heating, thermomechanical stresses, pressure wave formation and relaxation, and thermochemical decomposition of the polymer substrate can be investigated directly by suitably choosing the potential energy and chemical reaction energy landscape. The results highlight the usefulness of such a modeling approach by showing that various processes in polymer ablation are intricately linked leading to the transformation of the substrate and its ejection. The method, in principle, can be utilized to study systems where chemical reactions are expected to play a dominant role or interact strongly with other physical processes.

  6. Behaviors That Result in Employee Discipline

    E-Print Network [OSTI]

    Oliver, Douglas L.

    would much rather you be productive and happy on the job. Most employers have resources to help is not punishment. The goal of discipline is to deter a re- peat of the performance problem (quality of work your concerns confidentially with an employee assistance professional can help. Human resources is also

  7. Academic Legitimacy of the Software Engineering Discipline

    E-Print Network [OSTI]

    Berry, Daniel M.

    Academic Legitimacy of the Software Engineering Discipline Daniel M. Berry Software Engineering the academic substance of software engineering. It identifies the basic research questions and the methods used engineering. The article then discusses at length what about software makes its production so difficult

  8. Computational fluid dynamics modeling of chemical looping combustion process with calcium sulphate oxygen carrier - article no. A19

    SciTech Connect (OSTI)

    Baosheng Jin; Rui Xiao; Zhongyi Deng; Qilei Song [Southeast University (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

    2009-07-01

    To concentrate CO{sub 2} in combustion processes by efficient and energy-saving ways is a first and very important step for its sequestration. Chemical looping combustion (CLC) could easily achieve this goal. A chemical-looping combustion system consists of a fuel reactor and an air reactor. Two reactors in the form of interconnected fluidized beds are used in the process: (1) a fuel reactor where the oxygen carrier is reduced by reaction with the fuel, and (2) an air reactor where the reduced oxygen carrier from the fuel reactor is oxidized with air. The outlet gas from the fuel reactor consists of CO{sub 2} and H{sub 2}O, while the outlet gas stream from the air reactor contains only N{sub 2} and some unused O{sub 2}. The water in combustion products can be easily removed by condensation and pure carbon dioxide is obtained without any loss of energy for separation. Until now, there is little literature about mathematical modeling of chemical-looping combustion using the computational fluid dynamics (CFD) approach. In this work, the reaction kinetic model of the fuel reactor (CaSO{sub 4}+ H{sub 2}) is developed by means of the commercial code FLUENT and the effects of partial pressure of H{sub 2} (concentration of H{sub 2}) on chemical looping combustion performance are also studied. The results show that the concentration of H{sub 2} could enhance the CLC performance.

  9. Phase Diagram of Dynamical Twisted Mass Wilson Fermions at Finite Isospin Chemical Potential

    E-Print Network [OSTI]

    Janssen, Oliver; Splittorff, K; Verbaarschot, Jacobus J M; Zafeiropoulos, Savvas

    2015-01-01

    We consider the phase diagram of twisted mass Wilson fermions of two-flavor QCD in the parameter space of the quark mass, the isospin chemical potential, the twist angle and the lattice spacing. This work extends earlier studies in the continuum and those at zero chemical potential. We evaluate the phase diagram as well as the spectrum of the (pseudo-)Goldstone bosons using the chiral Lagrangian for twisted mass Wilson fermions at non-zero isospin chemical potential. The phases are obtained from a mean field analysis. At zero twist angle we find that already an infinitesimal isospin chemical potential destroys the Aoki phase. The reason is that in this phase we have massless Goldstone bosons with a non-zero isospin charge. At finite twist angle only two different phases are present, one phase which is continuously connected to the Bose condensed phase at non-zero chemical potential and another phase which is continuously connected to the normal phase. For either zero or maximal twist the phase diagram is more...

  10. HCI as an Inter-Discipline

    E-Print Network [OSTI]

    Blackwell, Alan F.

    2015-04-18

    and contributing to other disciplines. Author Keywords Interdisciplinarity, innovation, collaboration ACM Classification Keywords H.5.0 HCI – General; K.4.1 Computers and Society - Public Policy Issues What is the Problem? In 2014, Liu et al [13] published a... of such projects, in terms of the CHI submission categories, therefore depends on making analogies between the kinds of ‘interactivity’ associated with digital technologies, and the way that ‘interactivity’ might be interpreted in these other contexts. Crucible: A...

  11. Development and application of chemical tools for investigating dynamic processes in cell migration

    E-Print Network [OSTI]

    Goguen, Brenda Nicole

    2011-01-01

    Cell migration is a dynamic process essential for many fundamental physiological functions, including wound repair and the immune response. Migration relies on precisely orchestrated events that are regulated in a spatially ...

  12. The three different phases in the dynamics of chemical reaction networks and their relationship to cancer

    E-Print Network [OSTI]

    David B. Saakian; Laurent Schwartz

    2012-12-04

    We investigate the catalytic reactions model used in cell modeling. The reaction kinetic is defined through the energies of different species of molecules following random independent distribution. The related statistical physics model has three phases and these three phases emerged in the dynamics: fast dynamics phase, slow dynamic phase and ultra-slow dynamic phase. The phenomenon we found is a rather general, does not depend on the details of the model. We assume as a hypothesis that the transition between these phases (glassiness degrees) is related to cancer. The imbalance in the rate of processes between key aspects of the cell (gene regulation, protein-protein interaction, metabolical networks) creates a change in the fine tuning between these key aspects, affects the logics of the cell and initiates cancer. It is probable that cancer is a change of phase resulting from increased and deregulated metabolic reactions.

  13. DISCIPLINE AND TERMINATION POLICY Employees covered by this policy

    E-Print Network [OSTI]

    DISCIPLINE AND TERMINATION POLICY Employees covered by this policy This policy applies to all non to discipline, suspend with or without pay, or terminate employees for just cause. Just cause includes to discipline or termination for just cause, the University reserves the right to demote, suspend or terminate

  14. Quantitative Determination of Chemical Processes by Dynamic Nuclear Polarization Enhanced Nuclear Magnetic Resonance Spectroscopy 

    E-Print Network [OSTI]

    Zeng, Haifeng

    2012-07-16

    of indirect spectral dimensions similarly to conventional 2D NMR. Additionally, small flip angle pulses can be used to obtain a succession of scans separated in time. A model describing the combined effects of the evolution of a chemical process and of spin...

  15. THE JOURNAL OF CHEMICAL PHYSICS 134, 174504 (2011) Exciton dynamics in chromophore aggregates with correlated environment

    E-Print Network [OSTI]

    Mukamel, Shaul

    2011-01-01

    conversion unit in the form of delocalized molec- ular excitations must compete with nonradiative energy dis conversion ap- paratus, which is made of photon harvesting antennae and chemical energy generators- rounding protein units.7,8 The environment-induced fluctua- tions of molecular transition energies cause

  16. Chemical accelerator studies of reaction dynamics: Ar^+ + CH4 ? ArH^+ + CH3

    E-Print Network [OSTI]

    Wyatt, J. R.; Strattan, L. W.; Snyder, S. C.; Hierl, Peter M.

    1975-01-01

    Chemical accelerator studies on isotopic variants of the reaction Ar+ + CH4 ? ArH+ + CH3 are reported. Velocity and angular distributions of the ionic product as a function of initial translational energy have been measured over the energy range 0...

  17. Quantum Chemical Analysis of the Excited State Dynamics of Hydrated Electrons

    E-Print Network [OSTI]

    P. O. J. Scherer; Sighart F. Fischer

    2006-02-01

    Quantum calculations are performed for an anion water cluster representing the first hydration shell of the solvated electron in solution. The absorption spectra from the ground state, the instant excited states and the relaxed excited states are calculated including CI-SD interactions. Analytic expressions for the nonadiabatic relaxation are presented. It is shown that the 50fs dynamics recently observed after s->p excitation is best accounted for if it is identified with the internal conversion, preceded by an adiabatic relaxation within the excited p state. In addition, transient absorptions found in the infrared are qualitatively reproduced by these calculations .

  18. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  19. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Assessing Habitat Quality of

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  20. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note

  1. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology and imple- #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  2. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Relationships between Elevation and Slope

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  3. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  4. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Combined Snowpack and

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture, BCMOF 1 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  5. Production of cold formaldehyde molecules for study and control of chemical reaction dynamics with hydroxyl radicals

    E-Print Network [OSTI]

    Hudson, E R; Sawyer, B C; Taatjes, C A; Lewandowski, H J; Bochinski, J R; Bohn, J L; Ye, J; Hudson, Eric R.; Ticknor, Christopher; Sawyer, Brian C.; Taatjes, Craig A.; Bohn, John L.; Ye, Jun

    2005-01-01

    We propose a method for controlling a class of low temperature chemical reactions. Specifically, we show the hydrogen abstraction channel in the reaction of formaldehyde (H$_{2}$CO) and the hydroxyl radical (OH) can be controlled through either the molecular state or an external electric field. We also outline experiments for investigating and demonstrating control over this important reaction. To this end, we report the first Stark deceleration of the H$_{2}$CO molecule. We have decelerated a molecular beam of H$_{2}$CO essentially to rest, producing cold molecule packets at a temperature of 100 mK with a few million molecules in the packet at a density of $\\sim10^{6}$ cm$^{-3}$.

  6. 3-D Simulations of the Chemical and Dynamical Evolution of the Galactic Bulge

    E-Print Network [OSTI]

    Naohito Nakasato; Ken'ichi Nomoto

    2003-01-21

    A three-dimensional hydrodynamical N-body model for the formation of the Galaxy is presented with special attention to the formation of the bulge component. Starting with cosmologically motivated initial conditions, we obtain a qualitatively similar stellar system to the Galaxy. Then we analyze the chemical and kinematic properties of the bulge stars in our model and find qualitative agreement with observational data. The early evolution of our model has revealed that most bulge stars form during the sub-galactic merger (merger component of the bulge stars). Because of the strong star burst induced by the merger, the metallicity distribution function of such stars becomes as wide as observed. We find that another group of the bulge stars forms later in the inner region of the disk (non-merger component of the bulge stars). Because of the difference in the formation epoch, the main source of iron for this group of stars is different from the merger component. Iron in the merger and non-merger components comes mainly from Type II and Type Ia supernovae, respectively. Since a Type Ia supernova ejects $\\sim$ 10 times more iron than a Type II supernova, [Fe/H] of the non-merger component tends to be higher than that of the merger component, which widens the metallicity distribution function. From these results, we suggest that the Galactic bulge consists of two chemically different components; one has formed quickly through the sub-galactic clump merger in the proto-galaxy and the other has formed gradually in the inner disk.

  7. A common-view disciplined oscillator

    SciTech Connect (OSTI)

    Lombardi, Michael A.; Dahlen, Aaron P.

    2010-05-15

    This paper describes a common-view disciplined oscillator (CVDO) that locks to a reference time scale through the use of common-view global positioning system (GPS) satellite measurements. The CVDO employs a proportional-integral-derivative controller that obtains near real-time common-view GPS measurements from the internet and provides steering corrections to a local oscillator. A CVDO can be locked to any time scale that makes real-time common-view data available and can serve as a high-accuracy, self-calibrating frequency and time standard. Measurement results are presented where a CVDO is locked to UTC(NIST), the coordinated universal time scale maintained at the National Institute of Standards and Technology in Boulder, Colorado.

  8. Les autres disciplines toile artificielle fusion nuclaireenvironnement espionnage foudre

    E-Print Network [OSTI]

    Hennequin, Daniel

    Les autres disciplines étoile artificielle fusion nucléaireenvironnement espionnage foudre barrière froidsAmiens codes barreschaud et froid cinémaChauvet contrefaçonCD datamatrix DVD écrans LCDdécoupe

  9. fll INTRODUCTION Solid mechanics is a fundamental discipline which, in

    E-Print Network [OSTI]

    , solid mechanics is a central discipline for hydrocarbon resource extraction by drilling, hydraulic aggregates, whether in the form of artificially struc- tured composites or conventional engineering materials

  10. DRAFT - DOE O 333.1, Administering Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  11. Application of computational fluid dynamics to regional dosimetry of inhaled chemicals in the upper respiratory tract of the rat

    SciTech Connect (OSTI)

    Kimbell, J.S.; Gross, E.A.; Joyner, D.R.; Godo, M.N.; Morgan, K.T. (Chemical Industry Institute of Toxicology, Research Triangle Park, NC (United States))

    1993-08-01

    For certain inhaled air pollutants, such as reactive, water soluble gases, the distribution of nasal lesions observed in F344 rats may be closely related to regional gas uptake patterns in the nose. These uptake patterns can be influenced by the currents of air flowing through the upper respiratory tract during the breathing cycle. Since data on respiratory tract lesions in F344 rats are extrapolated to humans to make predictions of risk to human health, a better understanding of the factors affecting these responses is needed. To assess potential effects of nasal airflow on lesion location and severity, a methodology was developed for creation of computer simulations of steady-state airflow and gas transport using a three-dimensional finite element grid reconstructed from serial step-sections of the nasal passages of a male F344 rat. Simulations on a supercomputer used the computational fluid dynamics package FIDAP (FDI, Evanston, IL). Distinct streams of bulk flow evident in the simulations matched inspiratory streams reported for the F344 rat. Moreover, simulated regional flow velocities matched measured velocities in concurrent laboratory experiments with a hollow nasal mold. Computer-predicted flows were used in simulations of gas transport to nasal passage walls, with formaldehyde as a test case. Results from the uptake simulations were compared with the reported distribution of formaldehyde-induced nasal lesions observed in the F344 rat, and indicated that airflow-driven uptake patterns probably play an important role in determining the location of certain nasal lesions induced by formaldehyde. This work demonstrated the feasibility of applying computational fluid dynamics to airflow-driven dosimetry of inhaled chemicals in the upper respiratory tract.

  12. Cycle time variability for a network under two queueing disciplines 

    E-Print Network [OSTI]

    Vasquez Pariente, Marta Irene

    1996-01-01

    A network of three single-server queues is investigated. Performance of two queueing disciplines is compared on the basis of the mean and variance of the network cycle time. The two queueing disciplines are first-in-system first-out (FISFO...

  13. CIP, Discipline 0101 Agricultural Business and Management. 3

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    CIP, Discipline Average Salary N Average Salary N Average Salary N Average Salary N 0101 and rank that OPA reported to the Oklahoma State University Faculty Salary Survey for Fall 2014. Included disciplines include faculty from multiple departments and colleges. Salaries are not reported

  14. Sandia Energy - Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumniProjects Caterpillar, Sandia CRADA

  15. Penn State Multi-Discipline Tribology Group and Energy Institute Studies.

    SciTech Connect (OSTI)

    Perez, Joseph

    2001-08-05

    This presentation is a summary of the current research activities on fuels and lubricants in the Multi-discipline Tribology group and the engine test group in the Combustion Laboratory of the Pennsylvania State University. The progress areas discussed in this summary include those found in Table 1. Table 1. RESEARCH AREAS: Diesel Engine Emission Reduction; Oxygenated Fuels; Improved Friction Fuels; Vegetable Oil Lubricants; Extended Drain Lubricants; Effect of Chemical Structure on Friction and Wear. The research is of interest either directly or indirectly to the goal of this workshop, diesel engine emissions reduction. The current projects at Penn State in the areas listed above will be discussed.

  16. Theories of the Archive from Across the Disciplines

    E-Print Network [OSTI]

    Manoff, Marlene

    Creative and compelling theoretical formulations of the archive have emerged from a host of disciplines in the last decade. Derrida and Foucault, as well as many other humanists and social scientists, have initiated a ...

  17. Program Admission Policy: Defining Entrance Requirements For Engineering Disciplines

    E-Print Network [OSTI]

    Saskatchewan, University of

    Program Admission Policy: Defining Entrance Requirements For Engineering Disciplines Academic Affairs Responsibility: Dean, College of Engineering Authorization: Student Academic Affairs Committee, College of Engineering Approval Date: October 31, 2014 Amended: - Revisions Effective date of this policy

  18. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology-748-1331. mdeact@shaw.ca #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  19. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Rd., Black Creek, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology

  20. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.for.gov.bc.ca/vancouvr/research/research_index.htm #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  1. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Airphotos to Interpret

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture March 2004 Research Section, Coast Forest Region, BCMOF 1 Research Disciplines: Ecology ~ Geology

  2. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  3. Real-Time Molecular Monitoring of Chemical Environment in Obligate Anaerobes during Oxygen Adaptive Response

    E-Print Network [OSTI]

    Holman, Hoi-Ying N.

    2009-01-01

    chemical environment by continuously monitoring the dynamicsMolecular Monitoring of Chemical Environment in Obligate

  4. Master of Chemical Engineering/ Master of Business Administration

    E-Print Network [OSTI]

    Gao, Guang R.

    Master of Chemical Engineering/ Master of Business Administration A Dual Degree Program Rationale degree programs (both thesis and non- thesis) in each of the engineering disciplines (chemical, civil in the MBA program. The creation of a dual Master of Chemical Engineering/MBA program will allow 15 credits

  5. THE JOURNAL OF CHEMICAL PHYSICS 142, 054301 (2015) Predicting the effect of angular momentum on the dissociation dynamics

    E-Print Network [OSTI]

    Butler, Laurie J.

    2015-01-01

    are excellent. The results demonstrate the importance of considering the precession of the angular velocityTHE JOURNAL OF CHEMICAL PHYSICS 142, 054301 (2015) Predicting the effect of angular momentum the endoergicity. We test the model predictions using previous velocity map imaging and crossed laser

  6. THE JOURNAL OF CHEMICAL PHYSICS 134, 034703 (2011) Determination of the sticking coefficient and scattering dynamics of water

    E-Print Network [OSTI]

    Sibener, Steven

    2011-01-01

    and scattering dynamics of water on ice using molecular beam techniques K. D. Gibson, Daniel R. Killelea, Hanqiu on crystalline D2O ice was determined for incident trans- lational energies between 0.3 and 0.7 eV and for H2O for precise control of the incident angle and energy. Experiments were also performed to measure the intensity

  7. West Virginia University 1 Department of Chemical Engineering

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    gasification combined cycle (IGCC), Chemical looping, Fuel cells (SOFC & PEM), Optimization, Dynamic modeling

  8. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note EN-007

  9. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Silvicultural Treatments for Enhancing

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS EXECUTIVE SUMMARY

  10. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Biology, Ecology, and Management

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS ABSTRACT

  11. THEORY OF CHEMICAL REACTION ANTONIO LAGANA

    E-Print Network [OSTI]

    Auzinsh, Marcis

    THEORY OF CHEMICAL REACTION DYNAMICS Edited by: ANTONIO LAGANA Department of Chemistry University Theoretical treatment of the dynamics of chemical reactions has undergone a spectacular development during the NATO Advanced Research Work- shop on the Theory of the Dynamics of Chemical Reactions in Balatonf

  12. Physical and chemical dynamics of the hydrogeologic system in wetlands along the southern shore of Lake Michigan

    SciTech Connect (OSTI)

    Doss, P.K.

    1991-01-01

    The Miller Woods wetland system is established in the progradational beach deposits along the shore of Lake Michigan in the Indiana Dunes National Lakeshore. Long-term study of a detailed monitoring network has identified the large and small scale characteristics of the physical and chemical hydrogeology of the wetland system. The wetlands and related ground water display a complex hydrogeologic behavior, the transient nature of which is a function of stresses imposed by climatic factors and evapotranspiration. Transient hydrogeologic features vary in their scale and include mobile hydrologic boundaries that shift through time and space, and individual wetlands that regularly change their hydrologic regime and function within the whole wetland system. A conceptual model is developed that links different types of hydrologic behavior with different physical characteristics imposed by the progradational nature of the wetland system. Most waters in Miller Woods are near neutral pH, calcium bicarbonate type. Smaller-scale variations in the chemistry of bicarbonate, sulfate, and some metals result from micro and macrobiological influences. Observable impacts on water chemistry have occurred in some parts of the study area as a result of a nearby industrial landfill. Concentrations of essentially all ions are enriched, and found at their maximum values in the vicinity of the landfill.

  13. Qualitative Aspects of the Solutions of a Mathematical Model for the Dynamic Analysis of the Reversible Chemical Reaction SO2(g)+1/2O2(g)SO3(g) in a Catalytic Reactor

    E-Print Network [OSTI]

    Angulo Wilfredo; Contreras Joyne

    2014-12-19

    We present some qualitative aspects concerning the solution to the mathematical model describing the dynamical behavior of the reversible chemical reaction SO2(g)+1/2O2(g)SO3(g) carried out in a catalytic reactor used in the process of sulfuric acid production.

  14. Qualitative Aspects of the Solutions of a Mathematical Model for the Dynamic Analysis of the Reversible Chemical Reaction SO2(g)+1/2O2(g)SO3(g) in a Catalytic Reactor

    E-Print Network [OSTI]

    Wilfredo, Angulo

    2014-01-01

    We present some qualitative aspects concerning the solution to the mathematical model describing the dynamical behavior of the reversible chemical reaction SO2(g)+1/2O2(g)SO3(g) carried out in a catalytic reactor used in the process of sulfuric acid production.

  15. Exploring the Intersections of School Discipline, Discrimination, Connectedness, and Mental Health for African American High School Students

    E-Print Network [OSTI]

    Forrester, Kandace

    2015-01-01

    Kozol, J. (1991). Savage inequalities. Harper Perennial: NewExclusionary Discipline Inequalities: Magnitude of theContributing to Discipline Inequalities   Consequences and

  16. Chemical leukoderma

    E-Print Network [OSTI]

    O'Reilly, Kathryn E; Patel, Utpal; Chu, Julie; Patel, Rishi; Machler, Brian C

    2011-01-01

    the first report, to date, of chemical leukoderma that wasreview on biological, chemical and clinical aspects. Pigment4. Briganti S, et al. Chemical and instrumental approaches

  17. Atomistic Molecular Dynamics Simulations of Chemical Force David L. Patrick,*, John F. Flanagan, IV, Patrick Kohl, and Ruth M. Lynden-Bell

    E-Print Network [OSTI]

    Patrick, David L.

    to control the chemistry of the probe or to prevent the formation of a contamination layer. Chemical force

  18. The way that information professionals describe their own discipline: a comparison of thesaurus descriptors

    E-Print Network [OSTI]

    Liang, Huizhi "Elly"

    : a comparison of thesaurus descriptors. New Library World, 105(11), 429-435. A brief discussion of discipline information professionals and their professions are described in several of the thesauri that are the tools presently undertaking research into discipline formation in the information professions in order

  19. Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline

    E-Print Network [OSTI]

    Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline DOI: 10*a Since its inception, the discipline of microfluidics has been harnessed for innovations-effect of stereotyping microfluidics as a platform for medical diagnostics and miniaturized lab processes

  20. A molecular dynamics study of the graphitization ability of transition metals for catalysis of carbon nanotube growth via chemical vapor deposition

    E-Print Network [OSTI]

    Elliott, James

    of carbon nanotube growth via chemical vapor deposition Yasushi Shibuta a,*, James A. Elliott b a Department for carbon nanotube growth via chemical vapor deposition has been investigated via classical molecular and graphene sheet was found to be higher than for clusters comprising cobalt or nickel, since the high energy

  1. Studies in combustion dynamics

    SciTech Connect (OSTI)

    Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  2. Multi-discipline Waste Acceptance Process at the Nevada National Security Site - 13573

    SciTech Connect (OSTI)

    Carilli, Jhon T. [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States)] [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States); Krenzien, Susan K. [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)] [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)

    2013-07-01

    The Nevada National Security Site low-level radioactive waste disposal facility acceptance process requires multiple disciplines to ensure the protection of workers, the public, and the environment. These disciplines, which include waste acceptance, nuclear criticality, safety, permitting, operations, and performance assessment, combine into the overall waste acceptance process to assess low-level radioactive waste streams for disposal at the Area 5 Radioactive Waste Management Site. Four waste streams recently highlighted the integration of these disciplines: the Oak Ridge Radioisotope Thermoelectric Generators and Consolidated Edison Uranium Solidification Project material, West Valley Melter, and classified waste. (authors)

  3. Communication: Ro-vibrational control of chemical reactivity in H+CH{sub 4}? H{sub 2}+CH{sub 3} : Full-dimensional quantum dynamics calculations and a sudden model

    SciTech Connect (OSTI)

    Welsch, Ralph Manthe, Uwe

    2014-08-07

    The mode-selective chemistry of the title reaction is studied by full-dimensional quantum dynamics simulation on an accurate ab initio potential energy surface for vanishing total angular momentum. Using a rigorous transition state based approach and multi-configurational time-dependent Hartree wave packet propagation, initial state-selected reaction probabilities for many ro-vibrational states of methane are calculated. The theoretical results are compared with experimental trends seen in reactions of methane. An intuitive interpretation of the ro-vibrational control of the chemical reactivity provided by a sudden model based on the quantum transition state concept is discussed.

  4. Connecting graduate students with experts in a given discipline is vital to

    E-Print Network [OSTI]

    Rose, William I.

    Connecting graduate students with experts in a given discipline is vital to their success but has site provided a unique resource of current research articles and ideas that were vital for ongoing

  5. DOE Chair of Excellence Professorship in Environmental Disciplines

    SciTech Connect (OSTI)

    Shoou-Yuh Chang

    2013-01-31

    The United States (US) nuclear weapons program during the Cold War left a legacy of radioactive, hazardous, chemical wastes and facilities that may seriously harm the environment and people even today. Widespread public concern about the environmental pollution has created an extraordinary demand for the treatment and disposal of wastes in a manner to protect the public health and safety. The pollution abatement and environmental protection require an understanding of technical, regulatory, economic, permitting, institutional, and public policy issues. Scientists and engineers have a major role in this national effort to clean our environment, especially in developing alternative solutions and evaluation criteria and designing the necessary facilities to implement the solutions. The objective of the DOE Chair of Excellence project is to develop a high quality educational and research program in environmental engineering at North Carolina A&T State University (A&T). This project aims to increase the number of graduate and undergraduate students trained in environmental areas while developing a faculty concentrated in environmental education and research. Although A&T had a well developed environmental program prior to the Massie Chair grant, A&T's goal is to become a model of excellence in environmental engineering through the program's support. The program will provide a catalyst to enhance collaboration of faculty and students among various engineering departments to work together in a focus research area. The collaboration will be expanded to other programs at A&T. The past research focus areas include: hazardous and radioactive waste treatment and disposal fate and transport of hazardous chemicals in the environment innovative technologies for hazardous waste site remediation pollution prevention Starting from 2005, the new research focus was in the improvement of accuracy for radioactive contaminant transport models by ensemble based data assimilation. The specific objectives are to: 1). improve model accuracy for use in minimizing health and environmental risk, and 2). improve the decision making process in the selection and application of available technologies for long-term monitoring and safeguard operation at NNSA sites.

  6. CHEMICAL ENGINEERING AND MANUFACTURING CHEMICAL ENGINEERING

    E-Print Network [OSTI]

    Provancher, William

    CHEMICAL ENGINEERING AND MANUFACTURING CHEMICAL ENGINEERING Objective Chemical Engineers of chemicals. This lesson introduces students to one component of chemical engineering: food processing, and a chemical engineer 2. How chemical engineers are involved in food production 3. That chemical engineers need

  7. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1991-07-02

    Sensors responsive to small changes in the concentration of chemical species are disclosed. The sensors comprise a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment. They are operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical response. 9 figures.

  8. Volume 75, number 1 CHEMICAL PHYSICS LETTERS 1 October 1980 ISOMERIZATION DYNAMICS lN LiQUlDS BY MOLECULAR DYNAMlCS*

    E-Print Network [OSTI]

    Berne, Bruce J.

    are made of lsomerlzatlon dynamrcs of lz-butane dissolved m hquld CC14 and m a r&ud matrl\\ Rate constants,-CH, 2 _cH kz_ (gauche) " (trans) .CH, m wfuch n-butane undergoes a gauche-trans Isomen- zahon. The stage for this work is set by our previous molecular dynamics and Monte Carlo studies of n- butane in hquid Ccl, [l

  9. DOE contractor's meeting on chemical toxicity

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The Office of Health and Environmental Research (OHER) is required to determine the potential health and environmental effects associated with energy production and use. To ensure appropriate communication among investigators and scientific disciplines that these research studies represent, OHER has sponsored workshops. This document provides a compilation of activities at the Third Annual DOE/OHER Workshop. This year's workshop was broadened to include all OHER activities identified as within the chemical effects area. The workshop consisted of eight sessions entitled Isolation and Detection of Toxic chemicals; Adduct Formation and Repair; Chemical Toxicity (Posters); Metabolism and Genotoxicity; Inhalation Toxicology; Gene Regulation; Metals Toxicity; and Biological Mechanisms. This document contains abstracts of the information presented by session.

  10. AIAA 20010064 Multi-Flexible-Body Dynamic Analysis of

    E-Print Network [OSTI]

    Patil, Mayuresh

    disciplines, including, atmospheric modeling, wind-turbine struc- tural and aerodynamic modeling, energyAIAA 2001­0064 Multi-Flexible-Body Dynamic Analysis of Horizontal-Axis Wind Turbines Mayuresh J-0150 ABSTRACT A dynamic stability analysis is presented for a horizontal-axis wind turbine modeled as a multi

  11. The IceCube Data Acquisition Software: Lessons Learned during Distributed, Collaborative, Multi-Disciplined Software Development.

    E-Print Network [OSTI]

    Beattie, Keith

    2008-01-01

    et. al. , “Manifesto for Agile Software Development” http://Icecube Data Acquisition Software: Lessons Learned DuringMulti-Disciplined Software Development K S Beattie 1 , C T

  12. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1992-06-09

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material. 12 figs.

  13. Wind power is a rapidly growing and evolving field that crosses traditional academic disciplines and increasingly

    E-Print Network [OSTI]

    Firestone, Jeremy

    Wind power is a rapidly growing and evolving field that crosses traditional academic disciplines to locate wind power projects, the economics and regulatory policies governing wind power and the complex wind projects. Interdisciplinary Research and Education The Wind Power Science, Engineering and Policy

  14. EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused on understanding the

    E-Print Network [OSTI]

    Krylov, Anna I.

    EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused this understanding to read the record of earth history written in rocks and sediments, and on developing models by humans. Opportunities for Students Sigma Gamma Epsilon: The Omega Chapter of the national honorary earth

  15. What is Software Engineering? Software Engineering is the discipline providing methods and tools for the construction

    E-Print Network [OSTI]

    Briand, Lionel C.

    What is Software Engineering? Software Engineering is the discipline providing methods and tools of engineering to software. What does Software Engineering Involve? It involves the elicitation of the system are also required to run successful projects and construct quality systems. Why is Software Engineering

  16. Rand medical discipline focused on har-nessing the power of stem cells and the

    E-Print Network [OSTI]

    Rand medical discipline focused on har- nessing the power of stem cells and the body's own regenerative capabilities to restore function to damaged cells, tissues and organs. to develop into specialized cells and tissues. types they hope to transplant into patients to repair or replace damaged or destroyed

  17. C H A P T E R Evo-devo as a discipline

    E-Print Network [OSTI]

    Müller, Gerd B.

    C H A P T E R Evo-devo as a discipline Gerd B. Müller Since its inception in the early s, evo distinctdiscipline itisoftenunclearwhatconstitutesits conceptualdistinc- tiveness. Does evo-devo have its own set and evolution? That is, in which way do the goals, the empirical programs and the theories of evo-devo research

  18. CTR SHEET Sheet 1 of 1 TITLE: Logistic flow DISCIPLINE: Renewable Marine Energy

    E-Print Network [OSTI]

    of any Renewable Marine Energy (RME) Project installation phase, like any other offshore projectCTR CTR04 CTR SHEET Sheet 1 of 1 TITLE: Logistic flow DISCIPLINE: Renewable Marine Energy ­ Shiping foundations. From a selected project, the student will have to develop an in house tool dedicated to logistic

  19. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.Understanding how the hydrologic cycle is affected by climate, trees and plants, soils, geology, topography, springs, or any Figure 1. The hydrologic cycle, or water cycle (courtesy of the US Geological Survey

  20. 1 Geography One of the social and behavioral sciences disciplines in the

    E-Print Network [OSTI]

    Vertes, Akos

    1 Geography GEOGRAPHY One of the social and behavioral sciences disciplines in the Columbian College of Arts and Sciences, GW's geography program investigates how people in different places interact with the environment and how the environment influences their lives. Geography majors understand society

  1. 32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation

    E-Print Network [OSTI]

    32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation 32) in the administration of the discipline and dismissal policy and regulation. 2.00 APPROVAL PROCEDURE 2.01 A supervisor that is available for review. Following the review, AgriLife Human Resources will, in keeping with System Regulation

  2. Photoconduction efficiencies and dynamics in GaN nanowires grown by chemical vapor deposition and molecular beam epitaxy: A comparison study

    SciTech Connect (OSTI)

    Chen, R. S. [Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China); Tsai, H. Y. [Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China); Huang, Y. S. [Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China); Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China); Chen, Y. T. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China); Chen, L. C. [Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan (China); Chen, K. H. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China); Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan (China)

    2012-09-10

    The normalized gains, which determines the intrinsic photoconduction (PC) efficiencies, have been defined and compared for the gallium nitride (GaN) nanowires (NWs) grown by chemical vapor deposition (CVD) and molecular beam epitaxy (MBE). By excluding the contributions of experimental parameters and under the same light intensity, the CVD-grown GaN NWs exhibit the normalized gain which is near two orders of magnitude higher than that of the MBE-ones. The temperature-dependent time-resolved photocurrent measurement further indicates that the higher photoconduction efficiency in the CVD-GaN NWs is originated from the longer carrier lifetime induced by the higher barrier height ({phi}{sub B} = 160 {+-} 30 mV) of surface band bending. In addition, the experimentally estimated barrier height at 20 {+-} 2 mV for the MBE-GaN NWs, which is much lower than the theoretical value, is inferred to be resulted from the lower density of charged surface states on the non-polar side walls.

  3. Chemical Occurrences

    Broader source: Energy.gov [DOE]

    Classification of Chemical Occurrence Reports into the following four classes: Occurrences characterized by serious energy release, injury or exposure requiring medical treatment, or severe environmental damage, Occurrences characterized by minor injury or exposure, or reportable environmental release, Occurrences that were near misses including notable safety violations and Minor occurrences.

  4. Chemical Evolution

    E-Print Network [OSTI]

    Francesca Matteucci

    2007-04-05

    In this series of lectures we first describe the basic ingredients of galactic chemical evolution and discuss both analytical and numerical models. Then we compare model results for the Milky Way, Dwarf Irregulars, Quasars and the Intra-Cluster- Medium with abundances derived from emission lines. These comparisons allow us to put strong constraints on the stellar nucleosynthesis and the mechanisms of galaxy formation.

  5. Real-Time Chemical Imaging of Bacterial Biofilm Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to probe the chemical underpinnings of developing bacterial biofilms. Almost all bacteria can form biofilms-dynamic communities of cells enclosed in self-produced matrices of...

  6. Real-Time Chemical Imaging of Bacterial Biofilm Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has led to unprecedented study of dynamic processes. The ability to image the chemical reactions in living cells in real time, especially in parallel with fluorescence...

  7. Determining Interconnections in Chemical Reaction Networks Antonis Papachristodoulou and Ben Recht

    E-Print Network [OSTI]

    Recht, Ben

    Determining Interconnections in Chemical Reaction Networks Antonis Papachristodoulou and Ben Recht Abstract-- We present a methodology for robust determina- tion of chemical reaction network' dynamics. We illustrate our methodology on a hypothetical chemical reaction network under various

  8. Chemical sciences, annual report 1993

    SciTech Connect (OSTI)

    Not Available

    1994-10-01

    The Chemical Sciences Division (CSD) is one of eleven research Divisions of the Lawrence Berkeley Laboratory, a DOE National Laboratory. In FY 1993, the Division made considerable progress on developing two end-stations and a beamline to advance combustion dynamics at the Advanced Light Source (ALS). In support of DOE`s national role in combustion research and chemical science, the beamline effort will enable researchers from around the world to make fundamental advances in understanding the structure and reactivity of critical reaction intermediates and transients, and in understanding the dynamics of elementary chemical reactions. The Division has continued to place a strong emphasis on full compliance with environmental health and safety guidelines and regulations and has made progress in technology transfer to industry. Finally, the Division has begun a new program in advanced battery research and development that should help strengthen industrial competitiveness both at home and abroad.

  9. Chemical Reactions at Surfaces

    SciTech Connect (OSTI)

    Michael Henderson and Nancy Ryan Gray

    2010-04-14

    Chemical reactions at surfaces underlie some of the most important processes of today, including catalysis, energy conversion, microelectronics, human health and the environment. Understanding surface chemical reactions at a fundamental level is at the core of the field of surface science. The Gordon Research Conference on Chemical Reactions at Surfaces is one of the premiere meetings in the field. The program this year will cover a broad range of topics, including heterogeneous catalysis and surface chemistry, surfaces in environmental chemistry and energy conversion, reactions at the liquid-solid and liquid-gas interface, electronic materials growth and surface modification, biological interfaces, and electrons and photons at surfaces. An exciting program is planned, with contributions from outstanding speakers and discussion leaders from the international scientific community. The conference provides a dynamic environment with ample time for discussion and interaction. Attendees are encouraged to present posters; the poster sessions are historically well attended and stimulate additional discussions. The conference provides an excellent opportunity for junior researchers (e.g. graduate students or postdocs) to present their work and interact with established leaders in the field.

  10. Chemical Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecoveryplanning CareerNationalCNMSTHEmaterials |Chemical

  11. Disproportionality fills in the gaps: Connections between achievement, discipline and special education in the School-to-Prison Pipeline

    E-Print Network [OSTI]

    Annamma, Subini; Morrison, Deb; Jackson, Darrell

    2014-01-01

    discipline, and the school to prison pipeline. Journal ofD. (2010). The school-to-prison-pipeline: Structuring legalFund (2005). School to prison pipeline. Retrieved from

  12. Chemical composition of Earth-like planets

    E-Print Network [OSTI]

    Ronco, M P; Marboeuf, U; Alibert, Y; de Elía, G C; Guilera, O M

    2015-01-01

    Models of planet formation are mainly focused on the accretion and dynamical processes of the planets, neglecting their chemical composition. In this work, we calculate the condensation sequence of the different chemical elements for a low-mass protoplanetary disk around a solar-type star. We incorporate this sequence of chemical elements (refractory and volatile elements) in our semi-analytical model of planet formation which calculates the formation of a planetary system during its gaseous phase. The results of the semi-analytical model (final distributions of embryos and planetesimals) are used as initial conditions to develope N-body simulations that compute the post-oligarchic formation of terrestrial-type planets. The results of our simulations show that the chemical composition of the planets that remain in the habitable zone has similar characteristics to the chemical composition of the Earth. However, exist differences that can be associated to the dynamical environment in which they were formed.

  13. Protein-directed dynamic combinatorial chemistry 

    E-Print Network [OSTI]

    Bhat, Venugopal T.

    2011-11-23

    Dynamic combinatorial chemistry (DCC) is a novel approach to medicinal chemistry which integrates the synthesis and screening of small molecule libraries into a single step. The concept uses reversible chemical reactions to present a dynamic library...

  14. Chemical Accelerators The phrase "chemical accelerators"

    E-Print Network [OSTI]

    Meetings Chemical Accelerators The phrase "chemical accelerators" is scarcely older than for one or two dozen people grew to include nearly a hundred. Chemical accelerators is a name sug- gested by one of us for devices that produce beams of chemically interesting species at relative kinetic

  15. Efficient Dynamic Contracts: Enabling A Poor borrower To Get Out of Poverty Trap

    E-Print Network [OSTI]

    Bandyopadhyay, Antar

    of poverty trap is synonymous to getting loan from the formal sector. The MFI discipline the borrower to saveEfficient Dynamic Contracts: Enabling A Poor borrower To Get Out of Poverty Trap Dyotona Dasgupta, New Delhi 110016, India Keywords: Dynamic Contracts, Progressive Lending, Collateral, Poverty Trap

  16. Theoretical Chemical Dynamics Post-Doctoral Researcher

    E-Print Network [OSTI]

    Simons, Jack

    . Applications include solar energy catalysis, electron/radiation damage to biomolecules, and fundamental ion, UT (USA) Start Date: Ongoing, effective immediately Term: 1 year, renewable upon review Description

  17. CHEMICAL ENGINEERING Curriculum Notes

    E-Print Network [OSTI]

    Mohan, Chilukuri K.

    CHEMICAL ENGINEERING Curriculum Notes 2013-2014 1. Chemical engineering students must complete not included in the required chemical engineering curriculum. All technical electives are subject to approval be in chemical engineering. 2. Chemical engineering students must complete a minimum of 18 credits in the Social

  18. Laser induced chemical reactions

    E-Print Network [OSTI]

    Orel, Ann E.

    2010-01-01

    the simplest prototype chemical reaction, and since it is soLASER ENHANCEMENT OF CHEMICAL REACTIONS A. B. C. D. E.Laser Inhibition of Chemical Reaction Effect of Isotopic

  19. Microfluidic chemical reaction circuits

    DOE Patents [OSTI]

    Lee, Chung-cheng (Irvine, CA); Sui, Guodong (Los Angeles, CA); Elizarov, Arkadij (Valley Village, CA); Kolb, Hartmuth C. (Playa del Rey, CA); Huang, Jiang (San Jose, CA); Heath, James R. (South Pasadena, CA); Phelps, Michael E. (Los Angeles, CA); Quake, Stephen R. (Stanford, CA); Tseng, Hsian-rong (Los Angeles, CA); Wyatt, Paul (Tipperary, IE); Daridon, Antoine (Mont-Sur-Rolle, CH)

    2012-06-26

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  20. ITP Chemicals: Chemical Industry of the Future: New Biocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Industry of the Future: New Biocatalysts: Essential Tools for a Sustainable 21st Century Chemical Industry ITP Chemicals: Chemical Industry of the Future: New...

  1. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  2. Chemical Industry Corrosion Management

    SciTech Connect (OSTI)

    2003-02-01

    Improved Corrosion Management Could Provide Significant Cost and Energy Savings for the Chemical Industry. In the chemical industry, corrosion is often responsible for significant shutdown and maintenance costs.

  3. Enhanced Chemical Cleaning

    Office of Environmental Management (EM)

    Enhanced Chemical Cleaning Renee H. Spires Enhanced Chemical Cleaning Project Manager July 29, 2009 Tank Waste Corporate Board 2 Objective Provide an overview of the ECC process...

  4. Global Dynamic Optimization Adam Benjamin Singer

    E-Print Network [OSTI]

    in Chemical Engineering Abstract My thesis focuses on global optimization of nonconvex integral objectiveGlobal Dynamic Optimization by Adam Benjamin Singer Submitted to the Department of Chemical Engineering in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemical

  5. Chemical Sciences Division annual report 1994

    SciTech Connect (OSTI)

    1995-06-01

    The division is one of ten LBL research divisions. It is composed of individual research groups organized into 5 scientific areas: chemical physics, inorganic/organometallic chemistry, actinide chemistry, atomic physics, and chemical engineering. Studies include structure and reactivity of critical reaction intermediates, transients and dynamics of elementary chemical reactions, and heterogeneous and homogeneous catalysis. Work for others included studies of superconducting properties of high-{Tc} oxides. In FY 1994, the division neared completion of two end-stations and a beamline for the Advanced Light Source, which will be used for combustion and other studies. This document presents summaries of the studies.

  6. Chemical Management Contacts

    Broader source: Energy.gov [DOE]

    Contacts for additional information on Chemical Management and brief description on Energy Facility Contractors Group

  7. UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members.

    E-Print Network [OSTI]

    Wu, Shin-Tson

    UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members. (1) Just cause shall be defined as: (a) Incompetence; or (b) Misconduct. (2) Termination and Suspension. (a) The appointment of a non-unit faculty or an A&P staff member may be terminated or suspended during its term

  8. Part II: Regulations concerning students and their programmes of study The University of Nottingham -Code of Discipline for Students

    E-Print Network [OSTI]

    Aickelin, Uwe

    set out in turn the Ordinance governing Discipline, the regulations governing the conduct of students to check disorderly or improper conduct or any breach of disciplinary regulations occurring of disorderly or improper conduct in a classroom, laboratory or other room in the University or in the course

  9. ;login: DECEMBER 2011 13 Hacker-driven exploitation research has developed into a discipline of its own,

    E-Print Network [OSTI]

    Locasto, Michael E.

    ;login: DECEMBER 2011 13 Hacker-driven exploitation research has developed into a discipline of its and fulfilled the need of such practical exploration in real systems that we must trust . Hacker research has believe it is time to bring the hacker craft of finding and programming "weird machines" inside targets

  10. PINS chemical identification software

    DOE Patents [OSTI]

    Caffrey, Augustine J.; Krebs, Kennth M.

    2004-09-14

    An apparatus and method for identifying a chemical compound. A neutron source delivers neutrons into the chemical compound. The nuclei of chemical elements constituting the chemical compound emit gamma rays upon interaction with the neutrons. The gamma rays are characteristic of the chemical elements constituting the chemical compound. A spectrum of the gamma rays is generated having a detection count and an energy scale. The energy scale is calibrated by comparing peaks in the spectrum to energies of pre-selected chemical elements in the spectrum. A least-squares fit completes the calibration. The chemical elements constituting the chemical compound can be readily determined, which then allows for identification of the chemical compound.

  11. Log-domain circuit models of chemical reactions

    E-Print Network [OSTI]

    Mandal, Soumyajit

    We exploit the detailed similarities between electronics and chemistry to develop efficient, scalable bipolar or subthreshold log-domain circuits that are dynamically equivalent to networks of chemical reactions. Our ...

  12. Temporal variability in chemical cycling of the subterranean estuary and associated chemical loading to the coastal ocean

    E-Print Network [OSTI]

    Gonneea, Meagan Joan Eagle

    2014-01-01

    At the land-ocean interface, terrestrial groundwater interacts with seawater to form a subterranean estuary, which can play host to dynamic biogeochemical cycling of nutrients, trace metals and radionuclides. This chemically ...

  13. Spectroscopical Analysis of Mechano-chemically Activated Surfaces 

    E-Print Network [OSTI]

    Cooper, Rodrigo

    2012-10-19

    methods. The dynamics and kinetics of mechano-chemically activated surfaces will be studied using x-ray spectroscopy methods. Mechano-chemical interactions can be quantified through the study of electron energies. X-ray spectroscopy is a useful method...

  14. A Corpuscular Picture of Electrons in Chemical Bond

    E-Print Network [OSTI]

    Ando, Koji

    2015-01-01

    We introduce a theory of chemical bond with a corpuscular picture of electrons. It employs a minimal set of localized electron wave packets with 'floating and breathing' degrees of freedom and the spin-coupling of non-orthogonal valence-bond theory. It accurately describes chemical bonds in ground and excited states of spin singlet and triplet, in a distinct manner from conventional theories, indicating potential for establishing a dynamical theory of electrons in chemical bonds.

  15. CHINESE JOURNAL OF CHEMICAL PHYSICS VOLUME 22, NUMBER 6 DECEMBER 27, 2009 Quantitative Surface Chirality Detection with Sum Frequency Generation

    E-Print Network [OSTI]

    Liu, Shilin

    CHINESE JOURNAL OF CHEMICAL PHYSICS VOLUME 22, NUMBER 6 DECEMBER 27, 2009 ARTICLE Quantitative of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China the chiral Part of the special issue for "the Chinese Chemical Society's 11th National Chemical Dynamics

  16. Chemical Industry Bandwidth Study

    SciTech Connect (OSTI)

    none,

    2006-12-01

    The Chemical Bandwidth Study provides a snapshot of potentially recoverable energy losses during chemical manufacturing. The advantage of this study is the use of "exergy" analysis as a tool for pinpointing inefficiencies.

  17. Chemicals Industry Vision

    SciTech Connect (OSTI)

    none,

    1996-12-01

    Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

  18. Capacitive chemical sensor

    DOE Patents [OSTI]

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  19. Chemical Sciences Division - CSD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CSD Chemical Sciences Division CSD Organization Contact List Search Other Links Research Areas Research Highlights Organization Contacts Publications Awards Employment...

  20. MECS 2006- Chemicals

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Chemicals Sector (NAICS 325) with Total Energy Input, October 2012 (MECS 2006)

  1. innovation across a broad range of disciplines by world-class faculty

    E-Print Network [OSTI]

    Rutowski, Ronald L.

    of Matter, Transport and Energy Annual Report 2012-2013 aerospace chemical materials science mechanical #12 engineering (computational mechanics) m.s. mechanical engineering ph.d. mechanical engineering solar energy engineering & commercialization program director: Pat Phelan professional science master's program materials

  2. Chemical Zeolites Combinatorial . . .

    E-Print Network [OSTI]

    Servatius, Brigitte

    Chemical Zeolites Combinatorial . . . Realization 2d Zeolites Finite Zeolites The Layer . . . Holes University (Brigitte Servatius -- WPI) #12;Chemical Zeolites Combinatorial . . . Realization 2d Zeolites. Chemical Zeolites · crystalline solid · units: Si + 4O Si O O O O · two covalent bonds per oxygen #12

  3. Department of Chemical Engineering

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    Developing Leaders of Innovation Department of Chemical Engineering #12;At the University of Virginia, we educate students in traditional and nontraditional areas of chemical engineering, giving them.Va. Department of Chemical Engineering benefit from a modern academic curriculum and state

  4. Equilibrium Chemical Engines

    E-Print Network [OSTI]

    Tatsuo Shibata; Shin-ichi Sasa

    1997-10-30

    An equilibrium reversible cycle with a certain engine to transduce the energy of any chemical reaction into mechanical energy is proposed. The efficiency for chemical energy transduction is also defined so as to be compared with Carnot efficiency. Relevance to the study of protein motors is discussed. KEYWORDS: Chemical thermodynamics, Engine, Efficiency, Molecular machine.

  5. HARVARD UNIVERSITY CHEMICAL BIOLOGY

    E-Print Network [OSTI]

    Church, George M.

    HARVARD UNIVERSITY CHEMICAL BIOLOGY PHD PROGRAM 2013-2014 Student Handbook #12;Program Contacts at the beginning of each semester. Laboratory Rotations Students in the Chemical Biology Program are expected an interest in having Chemical Biology Program Students in their labs. Students may rotate in the labs

  6. Review of the National Research Council report ''Major Facilities for Materials Research and Related Disciplines''

    SciTech Connect (OSTI)

    Not Available

    1985-06-01

    The National Research Council-National Academy of Sciences report on ''Major Facilities for Materials Research and Related Disciplines'' recommends that new facilities and upgrades of existing facilities are very important to the nation. At the request of the Secretary of Energy, the Energy Research Advisory Board has reviewed this report and finds that the Department of Energy is responsible for the majority of these projects to carry out its missions in energy, national defense, and science and technology. Therefore, we recommend that the Department should place a high priority on requesting the new funds necessary to fulfill these responsibilities in the next decade. The energy and defense missions of the Department will be best served by this approach. This responsibility requires strong coordination with other funding agencies through a shared advisory and decision-making process. The review recommends immediate implementation of new capabilities at existing DOE facilities (the neutron experimental halls at Brookhaven and Los Alamos and the new synchrotron insertion devices at Stanford and Brookhaven) as a cost effective way of maintaining the Nation's leading role in neutron scattering and synchrotron radiation research. It also recommends the immediate initiation of non-site-specific research and development for the proposed 6 GeV synchrotron and advanced steady state neutron source. This pre-construction work should be sufficient to ensure that these facilities will be constructed in a timely fashion at design goals and with well identified costs. Other recommendations concern advancing the Nation's leading capabilities in synchrotron produced ultraviolet radiation and spallation neutron research. A budget scenario is developed.

  7. Introductive Backgrounds of Modern Quantum Mathematics with Application to Nonlinear Dynamical Systems

    E-Print Network [OSTI]

    Anatoliy K. Prykarpatsky; Nikolai N. Bogolubov; Jolanta Golenia; Ufuk Taneri

    2009-02-25

    Introductive backgrounds of a new mathematical physics discipline - Quantum Mathematics - are discussed and analyzed both from historical and analytical points of view. The magic properties of the second quantization method, invented by V. Fock in 1932, are demonstrated, and an impressive application to the nonlinear dynamical systems theory is considered.

  8. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01

    V. , Ed. , Safety in the Chemical Laboratory. J. Chem.£d. Amer/can Chemical Society. Easlon. PA. 18042. Vol. Lof Laboratory Safety. the Chemical Rubber Company Cleveland.

  9. Siphons in Chemical Reaction Networks

    E-Print Network [OSTI]

    Shiu, Anne; Sturmfels, Bernd

    2010-01-01

    strongly-connected chemical reaction, and the compu- tationcredited. Siphons in Chemical Reaction Networks Referencesto persistence analysis in chemical reaction networks. In:

  10. FOCUS ISSUE: Nonlinear dynamics related to polymeric systems Overview: Nonlinear dynamics related to polymeric systems

    E-Print Network [OSTI]

    Epstein, Irving R.

    FOCUS ISSUE: Nonlinear dynamics related to polymeric systems Overview: Nonlinear dynamics related is another promising practical application of nonlinear chemical dynamics. In this issue we focus on non is known about nonlinear phenom- ena in polymeric systems. One reason for the lack of interest in nonlinear

  11. Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Napp, Nils

    Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN The Wyss Institute for Biologically Inspired Engineering June 2015 #12;Wyss Institute Chemical Hygiene Plan TABLE OF CONTENTS 1.0 POLICY..........................................................................................2 2.1 CHEMICAL HYGIENE OFFICER

  12. Published on the Web 03/18/2011 www.pubs.acs.org/accounts Vol. 45, No. 1 ' 2012 ' 314 ' ACCOUNTS OF CHEMICAL RESEARCH ' 3 10.1021/ar2000088 & 2011 American Chemical Society

    E-Print Network [OSTI]

    Fayer, Michael D.

    OF CHEMICAL RESEARCH ' 3 10.1021/ar2000088 & 2011 American Chemical Society Dynamics of Water Interacting component of many chemical processes, in fields as diverse as biology and geology. Water in chemical, biological, and other systems frequently occurs in very crowded situations: the confined water must interact

  13. Degree Requirements for B.S. in Chemical Engineering at Wayne State University Molecular Engineering and Nanotechnology Option

    E-Print Network [OSTI]

    Berdichevsky, Victor

    Degree Requirements for B.S. in Chemical Engineering at Wayne State University Molecular ­ Research Preparation I 1 CHE 3820 ­ Chemical Engineering Laboratory 2 CHE 4200 ­ Product and Process Design 3 CHE 4600 ­ Process Dynamics and Simulation 2 CHE 4860 ­ Chemical Engineering Seminar II 1 Chemical

  14. From the portfolio to the diagram : architectural discourse and the transformation of the discipline of architecture in America, 1918-1943

    E-Print Network [OSTI]

    Pae, Hy?ng-min.

    1993-01-01

    This dissertation is an historical inquiry into the concomitant transformations of architectural discourse and the discipline of architecture in America. It proceeds on the theoretical assumption that the documents produced ...

  15. Degree Requirements for B.S. in Chemical Engineering at Wayne State University Biological Engineering Option

    E-Print Network [OSTI]

    Berdichevsky, Victor

    Degree Requirements for B.S. in Chemical Engineering at Wayne State University Biological CHE 5811 - Research Preparation I 1 CHE 3820 ­ Chemical Engineering Laboratory 2 CHE 4200 ­ Product and Process Design 3 CHE 4600 ­ Process Dynamics and Simulation 2 CHE 4860 ­ Chemical Engineering Seminar II 1

  16. Time-resolved UPS: a new experimental technique for the study of surface chemical reactions

    E-Print Network [OSTI]

    Bauer, Michael

    Time-resolved UPS: a new experimental technique for the study of surface chemical reactions the dynamics of surface chemical reactions using photoemission spectroscopy. In this paper we describe details. Keywords: Visible and ultraviolet photoelectron spectroscopy; Surface chemical reaction; Oxygen; Platinum 1

  17. Homogenization induced by chaotic mixing and diffusion in an oscillatory chemical reaction I. Z. Kiss,1,

    E-Print Network [OSTI]

    Kiss, Istvan Zoltan

    Homogenization induced by chaotic mixing and diffusion in an oscillatory chemical reaction I. Z dynamics corresponding to an oscillatory chemical reaction coupled with diffusion and chaotic advection as a synchronization of these local oscillators. The specific chemical reaction that we consider is the chlorine

  18. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  19. Chemical Cleaning Program Review

    Office of Environmental Management (EM)

    Chemical Cleaning Program Review Neil Davis Deputy Program Manager Waste Removal & Tank Closure July 29, 2009 SRR-STI-2009-00464 2 Contents Regulatory drivers Process overview...

  20. Apparatus for chemical synthesis

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Herring, J. Stephen (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID)

    2011-05-10

    A method and apparatus for forming a chemical hydride is described and which includes a pseudo-plasma-electrolysis reactor which is operable to receive a solution capable of forming a chemical hydride and which further includes a cathode and a movable anode, and wherein the anode is moved into and out of fluidic, ohmic electrical contact with the solution capable of forming a chemical hydride and which further, when energized produces an oxygen plasma which facilitates the formation of a chemical hydride in the solution.

  1. Tortuous path chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Adkins, Douglas R. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); Simonson, Robert J. (Cedar Crest, NM)

    2010-09-21

    A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.

  2. Quantitative genetic activity graphical profiles for use in chemical evaluation

    SciTech Connect (OSTI)

    Waters, M.D.; Stack, H.F.; Garrett, N.E.; Jackson, M.A.

    1990-12-31

    A graphic approach, terms a Genetic Activity Profile (GAP), was developed to display a matrix of data on the genetic and related effects of selected chemical agents. The profiles provide a visual overview of the quantitative (doses) and qualitative (test results) data for each chemical. Either the lowest effective dose or highest ineffective dose is recorded for each agent and bioassay. Up to 200 different test systems are represented across the GAP. Bioassay systems are organized according to the phylogeny of the test organisms and the end points of genetic activity. The methodology for producing and evaluating genetic activity profile was developed in collaboration with the International Agency for Research on Cancer (IARC). Data on individual chemicals were compiles by IARC and by the US Environmental Protection Agency (EPA). Data are available on 343 compounds selected from volumes 1-53 of the IARC Monographs and on 115 compounds identified as Superfund Priority Substances. Software to display the GAPs on an IBM-compatible personal computer is available from the authors. Structurally similar compounds frequently display qualitatively and quantitatively similar profiles of genetic activity. Through examination of the patterns of GAPs of pairs and groups of chemicals, it is possible to make more informed decisions regarding the selection of test batteries to be used in evaluation of chemical analogs. GAPs provided useful data for development of weight-of-evidence hazard ranking schemes. Also, some knowledge of the potential genetic activity of complex environmental mixtures may be gained from an assessment of the genetic activity profiles of component chemicals. The fundamental techniques and computer programs devised for the GAP database may be used to develop similar databases in other disciplines. 36 refs., 2 figs.

  3. Chemical process hazards analysis

    SciTech Connect (OSTI)

    1996-02-01

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  4. ITP Chemicals: Chemical Bandwidth Study - Energy Analysis: A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Bandwidth Study - Energy Analysis: A Powerful Tool for Identifying Process Inefficiencies in the U.S. Chemical Industry, Industrial Technologies Program, DRAFT Summary...

  5. Safety Issues Chemical Storage

    E-Print Network [OSTI]

    Cohen, Robert E.

    Safety Issues · Chemical Storage ·Store in compatible containers that are in good condition to store separately. #12;Safety Issues · Flammable liquid storage -Store bulk quantities in flammable storage cabinets -UL approved Flammable Storage Refrigerators are required for cold storage · Provide

  6. Fuzzy Chemical Abstract Machines

    E-Print Network [OSTI]

    Syropoulos, Apostolos

    2009-01-01

    Fuzzy set theory opens new vistas in computability theory and here I show this by defining a new computational metaphor--the fuzzy chemical metaphor. This metaphor is an extension of the chemical metaphor. In particular, I introduce the idea of a state of a system as a solution of fuzzy molecules, that is molecules that are not just different but rather similar, that react according to a set of fuzzy reaction rules. These notions become precise by introducing fuzzy labeled transition systems. Solutions of fuzzy molecules and fuzzy reaction rules are used to define the general notion of a fuzzy chemical abstract machine, which is a {\\em realization} of the fuzzy chemical metaphor. Based on the idea that these machines can be used to describe the operational semantics of process calculi and algebras that include fuzziness as a fundamental property, I present a toy calculus that is a fuzzy equivalent of the $\\pi$-calculus.

  7. Chemical Processing White Papers

    E-Print Network [OSTI]

    Nair, Sankar

    hydrogen from hydrocarbon mixtures, and propylene from propane, and if scaled up, could cut the cost fibers as a platform," says Sankar Nair, a professor in the School of Chemical & Biomolecular Engineering

  8. 219-S chemical compatibility

    SciTech Connect (OSTI)

    GOODWIN, L.D.

    1999-08-31

    This document consists of tables of the materials that make up the ''wetted'' parts of the 219-S waste handling facility and a combination of manufacturer lists of chemicals that are not recommended.

  9. Chemical Hygiene Michigan State University

    E-Print Network [OSTI]

    Isaacs, Rufus

    Chemical Hygiene Plan Michigan State University Environmental Health and Safety Engineering 2014 #12;ii Michigan State University Chemical Hygiene Plan Table of Contents 1.0 SCOPE.................................................................................................... 1 1.4 HAZARDOUS CHEMICAL DEFINITIONS

  10. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01

    IUPAC) or the Chemical Abstracts Service (CA,S} -'lee ofTerms CAS Number Chemical Abstract Service registry number,is indicated. CAS Number: Chemical Abstract Service registry

  11. CHEMICAL ENGINEERING Program of Study

    E-Print Network [OSTI]

    Thomas, Andrew

    CHEMICAL ENGINEERING Program of Study Research Facilities Financial Aid Applying Correspondence The Department of Chemical Engineering and Biological Engineering has well-established programs at both area of chemical engineering and include both fundamental and applied topics. The Department has

  12. Two-Color QCD with Chiral Chemical Potential

    E-Print Network [OSTI]

    V. V. Braguta; V. A. Goy; E. -M. Ilgenfritz; A. Yu. Kotov; A. V. Molochkov; M. Muller-Preussker; B. Petersson; A. Schreiber

    2014-11-19

    The phase diagram of two-color QCD with a chiral chemical potential is studied on the lattice. The focus is on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulations are carried out with dynamical staggered fermions without rooting. The dependence of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented.

  13. Siphons in Chemical Reaction Networks

    E-Print Network [OSTI]

    Shiu, Anne; Sturmfels, Bernd

    2010-01-01

    source are credited. Siphons in Chemical Reaction Networksalgorithms for minimal siphons in Petri nets based on placewe characterize the minimal siphons of a chemical reaction

  14. Chemical Organization Theory as a Theoretical Base for Chemical Computing

    E-Print Network [OSTI]

    Dittrich, Peter

    Chemical Organization Theory as a Theoretical Base for Chemical Computing NAOKI MATSUMARU, FLORIAN-07743 Jena, Germany http://www.minet.uni-jena.de/csb/ Submitted 14 November 2005 In chemical computing- gramming chemical systems a theoretical method to cope with that emergent behavior is desired

  15. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    ) Principles of probability and statistics, random variables and random functions. Application to chemical) CHE 442 Chemical Reactor Analysis (3, Fa) Basic concepts of chemical kinetics and chemical reactor to Separation Pro- cesses (3, Sp) Use of equilibrium phase relations and principles of material and energy

  16. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    Introduction to Separation Processes (3, Sp) Use of equilibrium phase relations and principles of material by petition only. 405 Applications of Probability and Statistics for Chemical Engineers (3, Fa) Principles Chemical Reactor Analysis (3, Fa) Basic concepts of chemical kinetics and chemical reactor design

  17. Chemical Engineering Is Chemical Engineering right for me?

    E-Print Network [OSTI]

    Martin, Ralph R.

    Chemical Engineering Is Chemical Engineering right for me? If you are interested in the uses and processes surrounding the engineering of new and raw materials, a degree in Chemical Engineering may be well suited to you. The Chemical Engineering degree programme will focus on the development of products

  18. Magnetic fields, spots and weather in chemically peculiar stars

    E-Print Network [OSTI]

    O. Kochukhov

    2007-11-30

    New observational techniques and sophisticated modelling methods has led to dramatic breakthroughs in our understanding of the interplay between the surface magnetism, atomic diffusion and atmospheric dynamics in chemically peculiar stars. Magnetic Doppler images, constructed using spectropolarimetric observations of Ap stars in all four Stokes parameters, reveal the presence of small-scale field topologies. Abundance Doppler mapping has been perfected to the level where distributions of many different chemical elements can be deduced self-consistently for one star. The inferred chemical spot structures are diverse and do not always trace underlying magnetic field geometry. Moreover, horizontal chemical inhomogeneities are discovered in non-magnetic CP stars and evolving chemical spots are observed for the first time in the bright mercury-manganese star alpha And. These results show that in addition to magnetic fields, another important non-magnetic structure formation mechanism acts in CP stars.

  19. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, S.P.

    1999-03-02

    A dispenser is disclosed for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 {micro}m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (ca. 200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments. 4 figs.

  20. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA)

    1999-03-02

    A dispenser for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 .mu.m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (.about.200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments.

  1. Chemical Engineering and Materials Science

    E-Print Network [OSTI]

    Berdichevsky, Victor

    Chemical Engineering and Materials Science COLLEGE of ENGINEERING DepartmentofChemicalEngineering-credit EDGE Engineering Entrepreneur Certificate Program is a great addition to a chemical engineering t engineering.wayne.edu/che #12;What is chemical engineering? Imagine saving the lives of pediatric patients

  2. Stochastic Chemical Reactions in Micro-domains

    E-Print Network [OSTI]

    D. Holcman; Z. Schuss

    2004-12-25

    Traditional chemical kinetics may be inappropriate to describe chemical reactions in micro-domains involving only a small number of substrate and reactant molecules. Starting with the stochastic dynamics of the molecules, we derive a master-diffusion equation for the joint probability density of a mobile reactant and the number of bound substrate in a confined domain. We use the equation to calculate the fluctuations in the number of bound substrate molecules as a function of initial reactant distribution. A second model is presented based on a Markov description of the binding and unbinding and on the mean first passage time of a molecule to a small portion of the boundary. These models can be used for the description of noise due to gating of ionic channels by random binding and unbinding of ligands in biological sensor cells, such as olfactory cilia, photo-receptors, hair cells in the cochlea.

  3. Simple Dynamic Gasifier Model That Runs in Aspen Dynamics

    SciTech Connect (OSTI)

    Robinson, P.J.; Luyben, W.L. [Lehigh University, Bethlehem, PA (United States). Dept. of Chemical Engineering

    2008-10-15

    Gasification (or partial oxidation) is a vital component of 'clean coal' technology. Sulfur and nitrogen emissions can be reduced, overall energy efficiency is increased, and carbon dioxide recovery and sequestration are facilitated. Gasification units in an electric power generation plant produce a fuel for driving combustion turbines. Gasification units in a chemical plant generate gas, which can be used to produce a wide spectrum of chemical products. Future plants are predicted to be hybrid power/chemical plants with gasification as the key unit operation. The widely used process simulator Aspen Plus provides a library of models that can be used to develop an overall gasifier model that handles solids. So steady-state design and optimization studies of processes with gasifiers can be undertaken. This paper presents a simple approximate method for achieving the objective of having a gasifier model that can be exported into Aspen Dynamics. The basic idea is to use a high molecular weight hydrocarbon that is present in the Aspen library as a pseudofuel. This component should have the same 1:1 hydrogen-to-carbon ratio that is found in coal and biomass. For many plantwide dynamic studies, a rigorous high-fidelity dynamic model of the gasifier is not needed because its dynamics are very fast and the gasifier gas volume is a relatively small fraction of the total volume of the entire plant. The proposed approximate model captures the essential macroscale thermal, flow, composition, and pressure dynamics. This paper does not attempt to optimize the design or control of gasifiers but merely presents an idea of how to dynamically simulate coal gasification in an approximate way.

  4. NETL - Chemical Looping Reactor

    SciTech Connect (OSTI)

    2013-07-24

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  5. NETL - Chemical Looping Reactor

    ScienceCinema (OSTI)

    None

    2014-06-26

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  6. Nonlinear Dynamics, Psychology, and Life Sciences, Vol.10, No.3, pp.405-407. 2006 Society for Chaos Theory in Psychology & Life Sciences

    E-Print Network [OSTI]

    Sprott, Julien Clinton

    405 Nonlinear Dynamics, Psychology, and Life Sciences, Vol.10, No.3, pp.405-407. © 2006 Society for Chaos Theory in Psychology & Life Sciences Book Review Images of a Complex World: The Art and Poetry Theory in Psychology and Life Sciences, practitioners in diverse disciplines have come together to foster

  7. Building robust chemical reaction mechanisms : next generation of automatic model construction software

    E-Print Network [OSTI]

    Song, Jing, 1972-

    2004-01-01

    Building proper reaction mechanisms is crucial to model the system dynamic properties for many industrial processes with complex chemical reaction phenomena. Because of the complexity of a reaction mechanism, computer-aided ...

  8. Design and development of a network architecture for a chemical sensor network

    E-Print Network [OSTI]

    Cheung, Jimmy

    2005-01-01

    A real-time continuous chemical sensor network can obtain detailed data to analyze the dynamic behavior of water systems such as a lake. The behaviors of interest to us in Upper Mystic Lake are the effects of stratification ...

  9. Spectroscopic probes of vibrationally excited molecules at chemically significant energies

    SciTech Connect (OSTI)

    Rizzo, T.R. [Univ. of Rochester, NY (United States)

    1993-12-01

    This project involves the application of multiple-resonance spectroscopic techniques for investigating energy transfer and dissociation dynamics of highly vibrationally excited molecules. Two major goals of this work are: (1) to provide information on potential energy surfaces of combustion related molecules at chemically significant energies, and (2) to test theoretical modes of unimolecular dissociation rates critically via quantum-state resolved measurements.

  10. 21 April 2000 Z .Chemical Physics Letters 321 2000 4348

    E-Print Network [OSTI]

    Hong, Mei

    21 April 2000 Z .Chemical Physics Letters 321 2000 43­48 www and Engineering, UniÕersity of Massachusetts, Amherst, MA 01003, USA Received 27 January 2000; in final form 6 March 2000 Abstract A solid-state NMR exchange technique for detecting slow segmental dynamics

  11. 26 May 2000 Z .Chemical Physics Letters 322 2000 351357

    E-Print Network [OSTI]

    Kim, Myung Soo

    26 May 2000 Z .Chemical Physics Letters 322 2000 351­357 www.elsevier.nlrlocatercplett Classical March 2000 Abstract Intramolecular dynamics of HOD was investigated by the classical trajectory method and mode selective chemistry is discussed. q 2000 Elsevier Science B.V. All rights reserved. 1

  12. 29 October 1999 Z .Chemical Physics Letters 312 1999 399406

    E-Print Network [OSTI]

    Fayer, Michael D.

    29 October 1999 Z .Chemical Physics Letters 312 1999 399­406 www.elsevier.nlrlocatercplett Non Research, Massachusetts Institute of Technology, Cambridge, MA 02139, USA Received 12 July 1999; in final form 13 August 1999 Abstract Z . Z y1.The intramolecular vibrational dynamics of the asymmetric CO

  13. Schools of Architecture | Afirca: Connecting Disciplines in Design + Development 1 For over 25 years the Center for African Studies at the University of Florida has organized annual

    E-Print Network [OSTI]

    Mair, Bernard A.

    Africa-related programs on the campus and beyond. School of Architecture, College of Design, Construction#12;Schools of Architecture | Afirca: Connecting Disciplines in Design + Development 1 For over 25, especially in southern Africa. She also worked hard to foster the development of African Studies

  14. SECTION SEVEN DEFINITION OF TERMS Additional Subject Group of related modules within an academic discipline which is taken in addition to

    E-Print Network [OSTI]

    Davies, Christopher

    SECTION SEVEN DEFINITION OF TERMS Additional Subject Group of related modules within an academic(s). Single / Double / Triple module Unit of study with a value of 10/20/30 credits. Subject Group of related modules within one academic discipline. Timetable Group Groups within which a module's teaching and other

  15. CHEMICAL ENGINEERING Graduation Checklist Bachelor of Science in Chemical Engineering

    E-Print Network [OSTI]

    Zallen, Richard

    CHEMICAL ENGINEERING Graduation Checklist Bachelor of Science in Chemical Engineering College of Engineering For Students Graduating in Calendar Year 2014 (Co-op students graduating in Calendar Year 2015

  16. Appendix H. Chemicals Appendix H. Chemicals H-3

    E-Print Network [OSTI]

    Pennycook, Steve

    . Through the use of chemicals, we can increase food production, cure diseases, build more efficient houses for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  17. Appendix B: Chemicals Appendix B: Chemicals B-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people materials used for the construction of homes may contain chemicals such as formaldehyde (in some insulation

  18. Appendix G. Chemicals Appendix G. Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    . Through the use of chemicals, we can increase food production, cure diseases, build more efficient houses for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  19. Dynamic imaging with electron microscopy

    ScienceCinema (OSTI)

    Campbell, Geoffrey; McKeown, Joe; Santala, Melissa

    2014-05-30

    Livermore researchers have perfected an electron microscope to study fast-evolving material processes and chemical reactions. By applying engineering, microscopy, and laser expertise to the decades-old technology of electron microscopy, the dynamic transmission electron microscope (DTEM) team has developed a technique that can capture images of phenomena that are both very small and very fast. DTEM uses a precisely timed laser pulse to achieve a short but intense electron beam for imaging. When synchronized with a dynamic event in the microscope's field of view, DTEM allows scientists to record and measure material changes in action. A new movie-mode capability, which earned a 2013 R&D 100 Award from R&D Magazine, uses up to nine laser pulses to sequentially capture fast, irreversible, even one-of-a-kind material changes at the nanometer scale. DTEM projects are advancing basic and applied materials research, including such areas as nanostructure growth, phase transformations, and chemical reactions.

  20. "Health, Aging and Environments" aims to bring together the resonant fields of health studies, gerontology, aging studies and other disciplines that focus on social studies of health, aging, and

    E-Print Network [OSTI]

    Haykin, Simon

    "Health, Aging and Environments" aims to bring together the resonant fields of health studies, gerontology, aging studies and other disciplines that focus on social studies of health, aging, and environments, in the broadest sense. Such disciplines include, but are not limited to, health and social

  1. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01

    Radioactive Hazardous or Other Location LBL On-Site Bldgs.hazardous chemicals usedin the laboratory: and (v} The locationhazardous chemicals are present: and. (irl}The location and

  2. Devices for collecting chemical compounds

    SciTech Connect (OSTI)

    Scott, Jill R; Groenewold, Gary S

    2013-12-24

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  3. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  4. A growing and dynamic field at Boise State that encompasses a range of disciplines and has led to new patents, partnerships and research awards

    E-Print Network [OSTI]

    Barrash, Warren

    and overseas to develop and test new, non-invasive methods to map the subsurface SENSORS R E S E A R C H Antiferromagnetic Hematite Nanoparticles · Mercury Selective Electrode · Chalcogenide Glass Ionizing Radiation blood test > RADIATION SENSORS that remotely detect radiation levels > NANOPARTICLE- BASED SENSORS

  5. LLNL Chemical Kinetics Modeling Group

    SciTech Connect (OSTI)

    Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

    2008-09-24

    The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

  6. Earth materials and earth dynamics

    SciTech Connect (OSTI)

    Bennett, K; Shankland, T. [and others

    2000-11-01

    In the project ''Earth Materials and Earth Dynamics'' we linked fundamental and exploratory, experimental, theoretical, and computational research programs to shed light on the current and past states of the dynamic Earth. Our objective was to combine different geological, geochemical, geophysical, and materials science analyses with numerical techniques to illuminate active processes in the Earth. These processes include fluid-rock interactions that form and modify the lithosphere, non-linear wave attenuations in rocks that drive plate tectonics and perturb the earth's surface, dynamic recrystallization of olivine that deforms the upper mantle, development of texture in high-pressure olivine polymorphs that create anisotropic velocity regions in the convecting upper mantle and transition zone, and the intense chemical reactions between the mantle and core. We measured physical properties such as texture and nonlinear elasticity, equation of states at simultaneous pressures and temperatures, magnetic spins and bonding, chemical permeability, and thermal-chemical feedback to better characterize earth materials. We artificially generated seismic waves, numerically modeled fluid flow and transport in rock systems and modified polycrystal plasticity theory to interpret measured physical properties and integrate them into our understanding of the Earth. This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL).

  7. Programmability of Chemical Reaction Networks

    E-Print Network [OSTI]

    Winfree, Erik

    Programmability of Chemical Reaction Networks Matthew Cook1 , David Soloveichik2 , Erik Winfree2 Chemical Reaction Networks (SCRNs), a for- mal model that considers a set of chemical reactions acting Logic Circuits, Vector Addition Systems, Petri Nets, Gate Implementability, Primitive Recursive

  8. CHEMICAL LABORATORY SAFETY AND METHODOLOGY

    E-Print Network [OSTI]

    Northern British Columbia, University of

    CHEMICAL LABORATORY SAFETY AND METHODOLOGY MANUAL August 2013 #12;ii Emergency Numbers UNBC Prince-Emergency Numbers UNBC Prince George Campus Chemstores 6472 Chemical Safety 6472 Radiation Safety 6472 Biological the safe use, storage, handling, waste and emergency management of chemicals on the University of Northern

  9. Qualitative Theory and Chemical Explanation

    E-Print Network [OSTI]

    Weisberg, Michael

    Abstract Roald Hoffmann and other theorists claim that we we ought to use highly idealized chemical modelsQualitative Theory and Chemical Explanation Michael Weisberg Stanford University February 15, 2003 ("qualitative models") in order to in- crease our understanding of chemical phenomena, even though other models

  10. 48 Chemical Engineering Education Incorporating

    E-Print Network [OSTI]

    Hesketh, Robert

    48 Chemical Engineering Education Incorporating GREEN ENGINEERING Into a Material and Energy prob- lems in chemical engineering. Problems of the type that can be used to motivate the student-mail: wilkes@umich.edu), Chemical Engineering Department, University of Michigan, Ann Arbor, MI 48109

  11. Ultrafast Laser Spectroscopyof Chemical Reactions

    E-Print Network [OSTI]

    Zewail, Ahmed

    Ultrafast Laser Spectroscopyof Chemical Reactions - Joseph L. Kneeand AhmedH. Zewail California of chemical physics is to understand how chemi- cal reactions complete their journey from reactants to prod at the molecular level. The making of new bonds (and the breaking of old ones) in elementary chemical reactions

  12. Dynamic Reconstruction

    E-Print Network [OSTI]

    Horn, Berthold Klaus Paul

    Dynamic reconstruction is a method for generating images or image sequences from data obtained using moving radiation detection systems. While coded apertures are used as examples of the underlying information collection ...

  13. Theoretical studies of the dynamics of chemical reactions

    SciTech Connect (OSTI)

    Wagner, A.F. [Argonne National Laboratory, IL (United States)

    1993-12-01

    Recent research effort has focussed on several reactions pertinent to combustion. The formation of the formyl radical from atomic hydrogen and carbon monoxide, recombination of alkyl radicals and halo-alkyl radicals with halogen atoms, and the thermal dissociation of hydrogen cyanide and acetylene have been studied by modeling. In addition, the inelastic collisions of NCO with helium have been investigated.

  14. Chemical and Dynamical Characteristics of Stratosphere-Troposphere Exchange 

    E-Print Network [OSTI]

    Homeyer, Cameron Ross

    2012-10-19

    of convective injection into the observed stratospheric intrusion (as in Fig. 27b). The airplane symbol is the aircraft location at the radar analysis time with the nose pointing in the ight direction. The white diamond shows the location of the radar... (as in gure 32b). The airplane symbol in each map is the aircraft location at the radar analysis time with the nose pointing in the ight direction. The white diamonds in each map show the location of the radar...

  15. Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTechin Complex Interfacial Systems. Final

  16. Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTechin Complex Interfacial Systems. Finalin

  17. Chemical kinetics modeling

    SciTech Connect (OSTI)

    Westbrook, C.K.; Pitz, W.J. [Lawrence Livermore National Laboratory, CA (United States)

    1993-12-01

    This project emphasizes numerical modeling of chemical kinetics of combustion, including applications in both practical combustion systems and in controlled laboratory experiments. Elementary reaction rate parameters are combined into mechanisms which then describe the overall reaction of the fuels being studied. Detailed sensitivity analyses are used to identify those reaction rates and product species distributions to which the results are most sensitive and therefore warrant the greatest attention from other experimental and theoretical research programs. Experimental data from a variety of environments are combined together to validate the reaction mechanisms, including results from laminar flames, shock tubes, flow systems, detonations, and even internal combustion engines.

  18. Chemical sensing flow probe

    DOE Patents [OSTI]

    Laguna, G.R.; Peter, F.J.; Butler, M.A.

    1999-02-16

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir. 7 figs.

  19. Chemical sensing flow probe

    DOE Patents [OSTI]

    Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

    1999-01-01

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

  20. Sandia Energy - Chemical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen GenerationTechnologies |EducationChemical Sciences Home Energy

  1. Carbon Emissions: Chemicals Industry

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948California (MillionThousandChemicals Industry

  2. CHEMICAL SIGNATURES FOR SUPERHEAVY ELEMENTARY PARTICLES

    E-Print Network [OSTI]

    Cahn, Robert N.

    2014-01-01

    of the Elements, Journal of Chemical Education, publishers,1977). weights, these new chemicals might have undergoneisotopes up to 17 Gev CHEMICAL SIGNATURES FOR SUPERHEAVY

  3. Chemical & Engineering Materials | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical and Engineering Materials SHARE Chemical and Engineering Materials Neutron-based research at SNS and HFIR in Chemical and Engineering Materials strives to understand the...

  4. Storage by Scientific Discipline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|SensitiveAprilPhoton Source Parameters StorageHeat & Cool »

  5. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate intallation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  6. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  7. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to faciliate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  8. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1981-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  9. Gas phase chemical detection with an integrated chemical analysis system

    SciTech Connect (OSTI)

    CASALNUOVO,STEPHEN A.; FRYE-MASON,GREGORY CHARLES; KOTTENSTETTE,RICHARD; HELLER,EDWIN J.; MATZKE,CAROLYN M.; LEWIS,PATRICK R.; MANGINELL,RONALD P.; BACA,ALBERT G.; HIETALA,VINCENT M.

    2000-04-12

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  10. 198 Chemical Engineering Education AN INTRODUCTION TO

    E-Print Network [OSTI]

    Hesketh, Robert

    198 Chemical Engineering Education AN INTRODUCTION TO DRUG DELIVERY FOR CHEMICAL ENGINEERS- maceutical sciences, engineering, and chemistry. Chemical en- gineers play an important role in this exciting- dergraduate chemical engineering students are rarely exposed to drug delivery through their coursework

  11. Gas Phase Chemical Detection with an Integrated Chemical Analysis System

    SciTech Connect (OSTI)

    Baca, Albert G.; Casalnuovo, Stephen A.; Frye-Mason, Gregory C.; Heller, Edwin J.; Hietala, Susan L.; Hietala, Vincent M.; Kottenstette, Richard J.; Lewis, Patrick R.; Manginell, Ronald P.; Matzke, Carloyn M.; Reno, John L.; Sasaki, Darryl Y.; Schubert, W. Kent

    1999-07-08

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample concentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described. The design and performance of novel micromachined acoustic wave devices, with the potential for improved chemical sensitivity, are also described.

  12. SIAM conference on applications of dynamical systems

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    A conference (Oct.15--19, 1992, Snowbird, Utah; sponsored by SIAM (Society for Industrial and Applied Mathematics) Activity Group on Dynamical Systems) was held that highlighted recent developments in applied dynamical systems. The main lectures and minisymposia covered theory about chaotic motion, applications in high energy physics and heart fibrillations, turbulent motion, Henon map and attractor, integrable problems in classical physics, pattern formation in chemical reactions, etc. The conference fostered an exchange between mathematicians working on theoretical issues of modern dynamical systems and applied scientists. This two-part document contains abstracts, conference program, and an author index.

  13. Solutia: Massachusetts Chemical Manufacturer Uses SECURE Methodology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solutia: Massachusetts Chemical Manufacturer Uses SECURE Methodology to Identify Potential Reductions in Utility and Process Energy Consumption Solutia: Massachusetts Chemical...

  14. Chemical Burn Secondary to Propofol Extravasation

    E-Print Network [OSTI]

    Sharma, Rahul; Yoshikawa, Hana; Abisaab, Josyann

    2012-01-01

    IN E MERGENCY M EDICINE Chemical Burn Secondary to Propofolof Emergency Medicine Chemical Burn Secondary to Propofol

  15. Interdisciplinary: Chemical Engineer/Mechanical Engineer (Pathways...

    Energy Savers [EERE]

    Interdisciplinary: Chemical EngineerMechanical Engineer (Pathways Recent Graduate Program) Interdisciplinary: Chemical EngineerMechanical Engineer (Pathways Recent Graduate...

  16. Multidimensional simulation and chemical kinetics development...

    Energy Savers [EERE]

    Multidimensional simulation and chemical kinetics development for high efficiency clean combustion engines Multidimensional simulation and chemical kinetics development for high...

  17. Annu. Rev. Phys. Chem. 1997. 48:71144 FEMTOSECOND DYNAMICS

    E-Print Network [OSTI]

    Harris, Charles B.

    of Chemistry, University of California, Berkeley, California 94720, and Chemical Sciences Division, E. O. Lawrence Berkeley National Laboratory, Berkeley, California 94720 KEY WORDS: carrier dynamics, metal, transport properties, and dynamics of excited electrons at surfaces and interfaces are important in surface

  18. Dynamic Modelling for Control of Fuel Cells Federico Zenith

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Dynamic Modelling for Control of Fuel Cells Federico Zenith Sigurd Skogestad Department of Chemical Engineering Norwegian University of Science and Technology ( ntnu) Trondheim Abstract Fuel-cell dynamics have been investigated with a variable-resistance board applied to a high temperature polymer fuel cell

  19. The unfought chemical war

    SciTech Connect (OSTI)

    Freeman, K. (Pennsylvania State Univ., University Park (United States))

    1991-12-01

    In December 1943, in the middle of the scorching northern Australia summer, a young Australian commando, Tom Mitchell, sweated in his respirator and gas-protective clothing as he got ready to take part in a mustard-gas experiment. He grimly watched six US aircraft, B-24 Liberators, drop bombs filled with mustard gas on Brook Island, near Innisfail in the state of Queensland. Ten minutes later, Mitchell was rushing around the island to tend sampling equipment. But a few hours later, he and another Australian soldier were ordered back onto the island - this time, stripped of their respirators and protective clothing. They were forced to camp on the island from dusk to dawn in ordinary clothing without any safety equipment. Mitchell now suffers from lung and heart disease. Last year, nearly 47 years after he was burned, Mitchell settled with the Australian government for $25,000 (Australian). Publicity over his lawsuit, filed in 1981, along with revelations made in a documentary film broadcast in Australia in 1989, has prompted thousands of other Australian survivors of chemical-warfare tests to ask the Australian Department of Veterans Affairs for disability benefits. Veterans of chemical-warfare tests are also breaking their silence in the United States and Canada, stepping forward to seek compensation for their injuries. The impetus behind the US revelations came from a campaign begun in 1989 by Cong. Porter Goss, a Florida Republican, to win benefits for four participants in US Navy mustard-gas tests. During a flurry of publicity in mid-June 1991, the Department of Veterans Affairs announced that it was relaxing its rules to make it easier for World War 2 mustard-gas victims to collect benefits. In Canada, an information hot line run by the Department of National Defense in 1988 and a 1989 book by John Bryden, Deadly Allies: Canada's Secret War 1937-1947, brought the tests to national attention.

  20. Chemical heat pump

    DOE Patents [OSTI]

    Greiner, Leonard (2750-C Segerstrom Ave., Santa Ana, CA 92704)

    1980-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer. The heat pump part of the system heats or cools a house or other structure through a combination of evaporation and absorption or, conversely, condensation and desorption, in a pair of containers. A set of automatic controls change the system for operation during winter and summer months and for daytime and nighttime operation to satisfactorily heat and cool a house during an entire year. The absorber chamber is subjected to solar heating during regeneration cycles and is covered by one or more layers of glass or other transparent material. Daytime home air used for heating the home is passed at appropriate flow rates between the absorber container and the first transparent cover layer in heat transfer relationship in a manner that greatly reduce eddies and resultant heat loss from the absorbant surface to ambient atmosphere.

  1. Two-Color QCD with Non-zero Chiral Chemical Potential

    E-Print Network [OSTI]

    V. V. Braguta; V. A. Goy; E. -M. Ilgenfritz; A. Yu. Kotov; A. V. Molochkov; M. Muller-Preussker; B. Petersson

    2015-03-23

    The phase diagram of two-color QCD with non-zero chiral chemical potential is studied by means of lattice simulation. We focus on the influence of a chiral chemical potential on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulation is carried out with dynamical staggered fermions without rooting. The dependences of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented. The critical temperature is observed to increase with increasing chiral chemical potential.

  2. Noise-induced multistability in chemical systems: Discrete vs Continuum modeling

    E-Print Network [OSTI]

    Andrew Duncan; Shuohao Liao; Tomas Vejchodsky; Radek Erban; Ramon Grima

    2014-07-31

    The noisy dynamics of chemical systems is commonly studied using either the chemical master equation (CME) or the chemical Fokker-Planck equation (CFPE). The latter is a continuum approximation of the discrete CME approach. We here show that the CFPE may fail to capture the CME's prediction of noise-induced multistability. In particular we find a simple chemical system for which the CME's marginal probability distribution changes from unimodal to multimodal as the system-size decreases below a critical value, while the CFPE's marginal probability distribution is unimodal for all physically meaningful system sizes.

  3. Reaction dynamics in polyatomic molecular systems

    SciTech Connect (OSTI)

    Miller, W.H. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    The goal of this program is the development of theoretical methods and models for describing the dynamics of chemical reactions, with specific interest for application to polyatomic molecular systems of special interest and relevance. There is interest in developing the most rigorous possible theoretical approaches and also in more approximate treatments that are more readily applicable to complex systems.

  4. Understanding chemical reactions within a generalized Hamilton-Jacobi framework

    E-Print Network [OSTI]

    A. S. Sanz; X. Gimenez; J. M. Bofill; S. Miret-Artes

    2009-08-13

    Reaction paths and classical and quantum trajectories are studied within a generalized Hamilton-Jacobi framework, which allows to put on equal footing topology and dynamics in chemical reactivity problems. In doing so, we show how high-dimensional problems could be dealt with by means of Caratheodory plots or how trajectory-based quantum-classical analyses reveal unexpected discrepancies. As a working model, we consider the reaction dynamics associated with a Mueller-Brown potential energy surface, where we focus on the relationship between reaction paths and trajectories as well as on reaction probability calculations from classical and quantum trajectories.

  5. Chemical Engineering | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical and Engineering Materials Clean Energy Nuclear Sciences Computer Science Earth and Atmospheric Sciences Materials Science and Engineering Mathematics Physics Environment...

  6. Chemical substructure analysis in toxicology

    SciTech Connect (OSTI)

    Beauchamp, R.O. Jr.

    1990-12-31

    A preliminary examination of chemical-substructure analysis (CSA) demonstrates the effective use of the Chemical Abstracts compound connectivity file in conjunction with the bibliographic file for relating chemical structures to biological activity. The importance of considering the role of metabolic intermediates under a variety of conditions is illustrated, suggesting structures that should be examined that may exhibit potential activity. This CSA technique, which utilizes existing large files accessible with online personal computers, is recommended for use as another tool in examining chemicals in drugs. 2 refs., 4 figs.

  7. Bioengineering/Chemical Engineering Building,

    E-Print Network [OSTI]

    Bogyo, Matthew

    BioE/ChemE Building Bioengineering/Chemical Engineering Building, Under Construction Lucile Packard Graduate Residences Sterling Quad Mirrielees Pearce Mitchell Houses Stanford Hospital Varsity Lot Jordan

  8. FAQS Reference Guide- Chemical Processing

    Office of Energy Efficiency and Renewable Energy (EERE)

    This reference guide addresses the competency statements in the February 2010 edition of DOE-STD-1176-2010, Chemical Processing Functional Area Qualification Standard.

  9. Markers of chemically induced cancer

    SciTech Connect (OSTI)

    Freeman, G.; Milman, H.A. (eds.)

    1984-01-01

    This book is a concise review and evaluation of available data for recognizing and measuring markers of cancer or oncogenesis provoked in vivo by chemicals using relatively short-term experiments in animals. This review focuses on biochemical and immunological changes that correlate with carcinogenicity. Such ''markers,'' if occurring early enough, may be used to predict the onset of cancer in experimental animals exposed to potential chemical carcinogens long before morphological changes are seen. It is by examining all the information available about the potential carcinogenicity of chemicals that proper decisions can be made towards limiting the risk of cancer due to exposure to chemical carcinogens.

  10. Process Intensification - Chemical Sector Focus

    Office of Environmental Management (EM)

    with opportunity space in 76 chemicals, petroleum refining, plastics, forest products, oil and gas production, and food industries 77 among others. PI innovation could deliver...

  11. Chemical engineers design, control and optimize large-scale chemical,

    E-Print Network [OSTI]

    Rohs, Remo

    of equilibrium phase relations and principles of material and energy balance for design, operation of Probability and Statistics for Chemical Engineers (3, Fa) Principles of probability and statistics, random to Biomaterials and Tissue Engineering (3, Fa) (Enroll in BME 410) CHE 442 Chemical Reactor Analysis (3, Fa) Basic

  12. INCOMPATIBLE CHEMICAL LIST PRUDENT PRACTICES FOR HANDLING CHEMICALS IN LABORATORIES

    E-Print Network [OSTI]

    Zhang, Zhongfei "Mark"

    of Incompatible Chemicals CHEMICAL IS INCOMPATIBLE WITH Acetic Acid Chromic acid, nitric acid, hydroxyl compounds, finely divided organic or combustible materials Chromic acid and chromium trioxide Acetic acid Acetylene, fulminic acid, ammonia Nitrates Sulfuric acid Nitric acid (concentrated) Acetic acid, aniline

  13. UCI Chemical Hygiene Plan i August 2014 CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    UCI Chemical Hygiene Plan i August 2014 CHEMICAL HYGIENE PLAN University of California, Irvine Environmental Health and Safety 4600 Health Sciences Road, Irvine, California 92697-2725 (949) 824-6200, Fax......................................................................................5-1 Chapter 6: Inventory, Labeling, Storage, , and Transport

  14. Dynamical equilibration in strongly-interacting parton-hadron matter

    E-Print Network [OSTI]

    Vitalii Ozvenchuk; Elena Bratkovskaya; Olena Linnyk; Mark Gorenstein; Wolfgang Cassing

    2010-12-31

    We study the kinetic and chemical equilibration in 'infinite' parton-hadron matter within the Parton-Hadron-String Dynamics transport approach, which is based on a dynamical quasiparticle model for partons matched to reproduce lattice-QCD results - including the partonic equation of state - in thermodynamic equilibrium. The 'infinite' matter is simulated within a cubic box with periodic boundary conditions initialized at different baryon density (or chemical potential) and energy density. The transition from initially pure partonic matter to hadronic degrees of freedom (or vice versa) occurs dynamically by interactions. Different thermodynamical distributions of the strongly-interacting quark-gluon plasma (sQGP) are addressed and discussed.

  15. Gas-Phase Molecular Dynamics: High Resolution Spectroscopy and Collision Dynamics of Transient Species

    SciTech Connect (OSTI)

    Hall,G.E.; Sears, T.J.

    2009-04-03

    This research is carried out as part of the Gas-Phase Molecular Dynamics program in the Chemistry Department at Brookhaven National Laboratory. High-resolution spectroscopy, augmented by theoretical and computational methods, is used to investigate the structure and collision dynamics of chemical intermediates in the elementary gas-phase reactions involved in combustion chemistry. Applications and methods development are equally important experimental components of this work.

  16. Levitation is a useful scientific tool to study materials in extreme, metastable and often tran-sient states, encompassing a wide range of disciplines from pharmaceutics to nuclear safety.

    E-Print Network [OSTI]

    Kilian, Kristopher A.

    - sient states, encompassing a wide range of disciplines from pharmaceutics to nuclear safety. Acoustic, simulating the melting of a nuclear fuel rod. Future plans to alter the oxidation state of levitat- ed oxide

  17. A Chemical Kinetic Model of Transcriptional Elongation

    E-Print Network [OSTI]

    Yujiro Richard Yamada; Charles S. Peskin

    2006-05-23

    A chemical kinetic model of the elongation dynamics of RNA polymerase along a DNA sequence is introduced. The proposed model governs the discrete movement of the RNA polymerase along a DNA template, with no consideration given to elastic effects. The model's novel concept is a ``look-ahead'' feature, in which nucleotides bind reversibly to the DNA prior to being incorporated covalently into the nascent RNA chain. Results are presented for specific DNA sequences that have been used in single-molecule experiments of the random walk of RNA polymerase along DNA. By replicating the data analysis algorithm from the experimental procedure, the model produces velocity histograms, enabling direct comparison with these published results.

  18. Ångström-scale chemically powered motors

    E-Print Network [OSTI]

    Peter H. Colberg; Raymond Kapral

    2014-05-16

    Like their larger micron-scale counterparts, {\\AA}ngstr\\"om-scale chemically self-propelled motors use asymmetric catalytic activity to produce self-generated concentration gradients that lead to directed motion. Unlike their micron-scale counterparts, the sizes of {\\AA}ngstr\\"om-scale motors are comparable to the solvent molecules in which they move, they are dominated by fluctuations, and they operate on very different time scales. These new features are studied using molecular dynamics simulations of small sphere dimer motors. We show that the ballistic regime is dominated by the thermal speed but the diffusion coefficients of these motors are orders of magnitude larger than inactive dimers. Such small motors may find applications in nano-confined systems or perhaps eventually in the cell.

  19. Clare Reimers Professor, Chemical Oceanography

    E-Print Network [OSTI]

    Kurapov, Alexander

    Clare Reimers Professor, Chemical Oceanography Clare Reimers, Professor of Chemical Oceanography research, education and outreach in fields including geology, oceanography, atmospheric sciences, volcanism in 1976 from the University of Virginia. She received an MS in Oceanography in 1978 and a PhD in 1982 from

  20. Chemical Evolution in Omega Centauri

    E-Print Network [OSTI]

    Verne V. Smith

    2003-10-22

    The globular cluster Omega Centauri displays evidence of a complex star formation history and peculiar internal chemical evolution, setting it apart from essentially all other globular clusters of the Milky Way. In this review we discuss the nature of the chemical evolution that has occurred within Omega Cen and attempt to construct a simple scenario to explain its chemistry.

  1. Method of forming a chemical composition

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); Klingler, Kerry M. (Idaho Falls, ID); Zollinger, William T. (Idaho Falls, ID); Wendt, Kraig M. (Idaho Falls, ID)

    2007-10-09

    A method of forming a chemical composition such as a chemical hydride is described and which includes the steps of selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of hydrogen; and exposing the selected composition to an amount of ionizing radiation to encourage the changing of the chemical bonds of the selected composition, and chemically reacting the selected composition with the source of hydrogen to facilitate the formation of a chemical hydride.

  2. Chemical analysis quality assurance at the Idaho Chemical Processing Plant

    SciTech Connect (OSTI)

    Hand, R.L.; Anselmo, R.W.; Black, D.B.; Jacobson, J.J.; Lewis, L.C.; Marushia, P.C.; Spraktes, F.W.; Zack, N.R.

    1985-01-01

    The Idaho Chemical Processing Plant (ICPP) is a uranium reprocessing facility operated by Westinghouse Idaho Nuclear Company for the Department of Energy at the Idaho National Engineering Laboratory (INEL). The chemical analysis support required for the plant processes is provided by a chemical analysis staff of 67 chemists, analysts, and support personnel. The documentation and defense of the chemical analysis data at the ICPP has evolved into a complete chemical analysis quality assurance program with training/qualification and requalification, chemical analysis procedures, records management and chemical analysis methods quality control as major elements. The quality assurance procedures are implemented on a central analytical computer system. The individual features provided by the computer system are automatic method selection for process streams, automation of method calculations, automatic assignment of bias and precision estimates at analysis levels to all method results, analyst specific daily requalification or with-method-use requalification, untrained or unqualified analyst method lockout, statistical testing of process stream results for replicate agreement, automatic testing of process results against pre-established operating, safety, or failure limits at varying confidence levels, and automatic transfer and report of analysis data plus the results of all statistical testing to the Production Department.

  3. THE JOURNAL OF CHEMICAL PHYSICS 135, 084103 (2011) How accurate are the nonlinear chemical Fokker-Planck and chemical

    E-Print Network [OSTI]

    Straube, Arthur V.

    2011-01-01

    THE JOURNAL OF CHEMICAL PHYSICS 135, 084103 (2011) How accurate are the nonlinear chemical Fokker-Planck and chemical Langevin equations? Ramon Grima,1,a) Philipp Thomas,1,2 and Arthur V. Straube2 1 School August 2011) The chemical Fokker-Planck equation and the corresponding chemical Langevin equation are com

  4. Hierarchical Dynamic Models

    E-Print Network [OSTI]

    Penny, Will

    Hierarchical Dynamic Models Will Penny OU Processes Embedding OU(2) process Dynamic Models Hierarchical Dynamic Models Will Penny 26th May 2011 #12;Hierarchical Dynamic Models Will Penny OU Processes Dynamic Models Will Penny OU Processes Embedding OU(2) process Dynamic Models Generalised coordinates

  5. Experimental characterization and chemical kinetics study of chemical looping combustion

    E-Print Network [OSTI]

    Chen, Tianjiao, S.M. Massachusetts Institute of Technology

    2014-01-01

    Chemical looping combustion (CLC) is one of the most promising technologies to achieve carbon capture in fossil fuel power generation plants. A novel rotary-bed reactor concept was proposed by Zhao et. al. [1] in 2013. It ...

  6. Appendix G: Chemicals Appendix G: Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people such as formaldehyde (in some insulation materials), asbestos (formerly used in insulations and ceiling tiles

  7. Appendix H: Chemicals Appendix H: Chemicals H-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people such as formaldehyde (in some insulation materials), asbestos (formerly used in insulations and ceiling tiles

  8. Appendix G. Chemicals Appendix G. Chemicals G-3

    E-Print Network [OSTI]

    Pennycook, Steve

    of chemicals, we can increase food production, cure diseases, build more efficient houses, and send people such as formaldehyde (in some insulation materials), asbestos (formerly used in insulations and ceiling tiles

  9. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1993-07-06

    Coatings and sensors are described having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  10. Laser MicroChemical Shaping of Silicon

    E-Print Network [OSTI]

    Burns, Michael J.

    Laser MicroChemical Shaping of Silicon MURI Workshop Feb 28, 2005 Michael J. Burns, Ph.D. LMC Product Manager #12;FEI Copyright © 2005 Vectra LMC 9900 2 Laser Micro Chemical (LMC) ·Use of laser light to induce local chemical reactions. ·Both Laser Chemical Etching (LCE) and Laser Chemical Deposition (LCD

  11. Chemical Safety Why are you here

    E-Print Network [OSTI]

    Krovi, Venkat

    Chemical Safety in the Laboratory #12;Why are you here · Work with Chemicals · Generate Hazardous Wastes · May have to respond to Chemical Spills #12;Goals Reduce injuries and illnesses related to chemical use Protect the environment Safely manage chemical wastes Comply with local, state and federal

  12. Chemical Hydrogen Storage Center Center of Excellence

    E-Print Network [OSTI]

    Carver, Jeffrey C.

    Chemical Hydrogen Storage Center Center of Excellence for Chemical Hydrogen Storage William Tumas proprietary or confidential information #12;2 Chemical Hydrogen Storage Center Overview Project Start Date: FY Barriers Addressed #12;3 Chemical Hydrogen Storage Center Chemical Hydrogen Storage Center National

  13. Chemical microreactor and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan (Livermore, CA)

    2011-08-09

    A method for forming a chemical microreactor includes forming at least one capillary microchannel in a substrate having at least one inlet and at least one outlet, integrating at least one heater into the chemical microreactor, interfacing the capillary microchannel with a liquid chemical reservoir at the inlet of the capillary microchannel, and interfacing the capillary microchannel with a porous membrane near the outlet of the capillary microchannel, the porous membrane being positioned beyond the outlet of the capillary microchannel, wherein the porous membrane has at least one catalyst material imbedded therein.

  14. Information flow within stochastic dynamical systems

    E-Print Network [OSTI]

    X. San Liang

    2007-10-05

    Information flow or information transfer is an important concept in dynamical systems which has applications in a wide variety of scientific disciplines. In this study, we show that a rigorous formalism can be established in the context of a generic stochastic dynamical system. The resulting measure of of information transfer possesses a property of transfer asymmetry and, when the stochastic perturbation to the receiving component does not rely on the giving component, has a form same as that for the corresponding deterministic system. An application with a two-dimensional system is presented, and the resulting transfers are just as expected. A remarkable observation is that, for two highly correlated time series, there could be no information transfer from one certain series, say $x_2$, to the other ($x_1$). That is to say, the evolution of $x_1$ may have nothing to do with $x_2$, even though $x_1$ and $x_2$ are highly correlated. Information transfer analysis thus extends the traditional notion of correlation analysis by providing a quantitative measure of causality between time series.

  15. Use of comparative genomics approaches to characterize interspecies differences in response to environmental chemicals: Challenges, opportunities, and research needs

    SciTech Connect (OSTI)

    Burgess-Herbert, Sarah L.; Euling, Susan Y.

    2013-09-15

    A critical challenge for environmental chemical risk assessment is the characterization and reduction of uncertainties introduced when extrapolating inferences from one species to another. The purpose of this article is to explore the challenges, opportunities, and research needs surrounding the issue of how genomics data and computational and systems level approaches can be applied to inform differences in response to environmental chemical exposure across species. We propose that the data, tools, and evolutionary framework of comparative genomics be adapted to inform interspecies differences in chemical mechanisms of action. We compare and contrast existing approaches, from disciplines as varied as evolutionary biology, systems biology, mathematics, and computer science, that can be used, modified, and combined in new ways to discover and characterize interspecies differences in chemical mechanism of action which, in turn, can be explored for application to risk assessment. We consider how genetic, protein, pathway, and network information can be interrogated from an evolutionary biology perspective to effectively characterize variations in biological processes of toxicological relevance among organisms. We conclude that comparative genomics approaches show promise for characterizing interspecies differences in mechanisms of action, and further, for improving our understanding of the uncertainties inherent in extrapolating inferences across species in both ecological and human health risk assessment. To achieve long-term relevance and consistent use in environmental chemical risk assessment, improved bioinformatics tools, computational methods robust to data gaps, and quantitative approaches for conducting extrapolations across species are critically needed. Specific areas ripe for research to address these needs are recommended.

  16. Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds

    E-Print Network [OSTI]

    Truhlar, Donald G

    Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds Science the hydroxyl oxygen and alcoholic hydrogen stabilizes the transition state. Chemical & Engineering News ISSN 0009-2347 Copyright © 2010 American Chemical Society #12;

  17. Chemical and Biological Engineering Department Code 1 Department of Chemical & Biological Engineering

    E-Print Network [OSTI]

    Dandy, David

    Chemical and Biological Engineering Department Code 1 CODE of the Department of Chemical of Chemical & Biological Engineering. For clarity of presentation, some passages are copied directly from shall offer an undergraduate chemical and biological engineering program of technological, scientific

  18. Bioengineering/Chemical Engineering Building,

    E-Print Network [OSTI]

    Straight, Aaron

    BioE/ChemE Building S-3 Parking Struct. 3 Bioengineering/Chemical Engineering Building, Under Hall Cowell Houses Schwab Residential Center Lyman Graduate Residences Sterling Quad Mirrielees Pearce

  19. Nonlinear response theory in chemical kinetics

    E-Print Network [OSTI]

    Kryvohuz, M; Mukamel, S

    2014-01-01

    ?D(t) are D 0 (t) = (1) Chemical reactions, N h i ( x , t) iOF NONLINEAR RESPONSE THEORY TO CHEMICAL KINETICS Equation (non- linear responses of chemical systems to perturbations

  20. Status of Chemical Freeze-Out

    E-Print Network [OSTI]

    J. Cleymans; H. Oeschler; K. Redlich; S. Wheaton

    2006-07-14

    The status of the energy dependence of the chemical freeze-out temperature and chemical potential obtained in heavy ion collisions is presented. Recent proposals for chemical freeze-out conditions are compared.

  1. Tribo-Chemical Modeling of Copper CMP

    E-Print Network [OSTI]

    Tripathi, Shantanu; Doyle, Fiona; Dornfeld, David

    2006-01-01

    TRIBO-CHEMICAL MODELING OF COPPER CMP Shantanu Tripathi 1 ,an integrated tribo-chemical model of copper CMP thatThe role of glycine in the chemical mechanical planarization

  2. CHEMICAL ENGINEERING 2014-2016 CATALOG

    E-Print Network [OSTI]

    Lightsey, Glenn

    CHEMICAL ENGINEERING 2014-2016 CATALOG (catalog valid until August 2022) Suggested Arrangement ..............................1 CHE 317, Intro to Chemical Engineering Analysis...................3 CH 353, Physical Chemistry Hours Spring Semester Semester Hours CHE 264, Chemical Engineering Process & Projects Lab........2 CHE

  3. Department of Chemical and Petroleum Engineering

    E-Print Network [OSTI]

    Department of Chemical and Petroleum Engineering 2012 "Fueling Tomorrow's Economy" Presentation ENVIRONMENTALBIOMEDICAL OILANDGAS Department of Chemical & Petroleum Engineering 2 Presentation Outline Program Details ­ Chemical Engineering Petroleum Minor Biomedical Specialization Energy and the Environment Specialization

  4. Appendix G. Chemicals Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    chemicals. Through the use of chemicals, we can increase food production, cure diseases, build more for the construction of homes may contain chemicals such as formaldehyde (in some insulation materials), asbestos

  5. LABORATORY CHEMICAL WASTE DISPOSAL POSTER (Post Near Chemical Waste Storage Area)

    E-Print Network [OSTI]

    WSTPS.rtf LABORATORY CHEMICAL WASTE DISPOSAL POSTER (Post Near Chemical Waste Storage Area) Excess Chemicals and Chemical Wastes · Toxic and Flammable Chemicals - These cannot go down the drain. Call Environmental Health and Safety (EHSO) at x-2723 for collection. · Corrosive Chemicals (Acids & Bases) - When

  6. Keeping Tabs on the World's Dangerous Chemicals

    Office of Energy Efficiency and Renewable Energy (EERE)

    Sandia chemical engineer Nancy Jackson has worked in laboratories around the world to help ensure that chemicals are used safely and kept secure.

  7. Nanoscale Chemical Imaging of a Working Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of chemical processes. Watching Catalysts at Work Catalysts-substances that speed up chemical reactions without themselves being consumed-are essential to the production of...

  8. Chemical and Petroleum Engineering Enrollment Form for _______________________

    E-Print Network [OSTI]

    Chemical and Petroleum Engineering Enrollment Form for _______________________ Semester, Year Name _____________________________________ KUID _______________ Major: Chemical Petroleum (circle one) Degree Program: BS MS PhD Curriculum Option

  9. Nanoscale Chemical Imaging of a Working Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Chemical Imaging of a Working Catalyst Print The heterogeneous catalysts used in most chemical processes typically consist of nanoscale metal or metal oxide particles...

  10. Nanoscale Chemical Imaging of a Working Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Chemical Imaging of a Working Catalyst Nanoscale Chemical Imaging of a Working Catalyst Print Wednesday, 28 January 2009 00:00 The heterogeneous catalysts used in most...

  11. Chemical Homogeneity in Collinder 261 and Implications for Chemical Tagging

    E-Print Network [OSTI]

    G. M. De Silva; K. C. Freeman; M. Asplund; J. Bland-Hawthorn; M. S. Bessell; R. Collet

    2006-11-28

    This paper presents abundances for 12 red giants of the old open cluster Collinder 261 based on spectra from VLT/UVES. Abundances were derived for Na, Mg, Si, Ca, Mn, Fe, Ni, Zr and Ba. We find the cluster has a solar-level metallicity of [Fe/H] = -0.03 dex. However some alpha elements were found to be enhanced. The star-to-star scatter was consistent with the expected measurement uncertainty for all elements. The observed rms scatter is as follows: Na = 0.07, Mg = 0.05, Si = 0.06, Ca = 0.05, Mn = 0.03, Fe = 0.02, Ni = 0.04, Zr = 0.12, and Ba = 0.03 dex. The intrinsic scatter was estimated to be less than 0.05 dex. Such high levels of homogeneity indicate that chemical information remains preserved in this old open cluster. We use the chemical homogeneity we have now established in Cr 261, Hyades and the HR1614 moving group to examine the uniqueness of the individual cluster abundance patterns, ie. chemical signatures. We demonstrate that the three studied clusters have unique chemical signatures, and discuss how other such signatures may be searched for in the future. Our findings support the prospect of chemically tagging disk stars to common formation sites in order to unravel the dissipative history of the Galactic disk.

  12. Chemical and Biological Engineering Department of Chemical and Biological Engineering

    E-Print Network [OSTI]

    Heller, Barbara

    Issues Particle Processing Pharmaceutical Engineering Polymer Science and Engineering Process Operation in Polymer Science and Engineering: David Venerus, Director Engineering Center for Diabetes Research and Engineering Lab Center of Excellence in Polymer Science and Engineering Lab Computational Fluid Dynamics Lab

  13. Ultrafast studies of solution dynamics

    SciTech Connect (OSTI)

    Woodruff, W.H.; Dyer, R.B.; Callender, R.H.

    1997-10-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Fast chemical dynamics generally must be initiated photochemically. This limits the applicability of modern laser methods for following the structural changes that occur during chemical and biological reactions to those systems that have an electronic chromophore that has a significant yield of photoproduct when excited. This project has developed a new and entirely general approach to ultrafast initiation of reactions in solution: laser-induced temperature jump (T-jump). The results open entire new fields of study of ultrafast molecular dynamics in solution. The authors have demonstrated the T-jump technique on time scales of 50 ps and longer, and have applied it to study of the fast events in protein folding. They find that a general lifetime of alpha-helix formation is ca 100 ns, and that tertiary folds (in apomyoglobin) form in ca 100 {mu}s.

  14. Dynamic Testing of Gasifier Refractory

    SciTech Connect (OSTI)

    Michael D. Mann; Devdutt Shukla; John P. Hurley

    2003-09-27

    The University of North Dakota (UND) Chemical Engineering Department in conjunction with the UND Energy & Environmental Research Center (EERC) have initiated a program to thoroughly examine the combined chemical (reaction and phase change) and physical (erosion) effects experienced by a variety of refractory materials during both normal operation and thermal cycling under slagging coal gasification conditions. The goal of this work is to devise a mechanism of refractory loss under these conditions. The controlled-atmospheric dynamic corrodent application furnace (CADCAF) is being utilized to simulate refractory/slag interactions under dynamic conditions that more realistically simulate the environment in a slagging coal gasifier than any of the static tests used previously by refractory manufacturers and researchers. Shakedown testing of the CADCAF is in progress. Samples of slag and refractory from the Tampa Electric Polk Power Station have been obtained for testing in the CADCAF. The slag has been dried and sieved to the size needed for our flowing slag corrosion tests. Testing is expected to begin in October.

  15. Dynamic Testing of Gasifier Refractory

    SciTech Connect (OSTI)

    Michael D. Mann; Devdutt Shukla; Xi Hong; John P. Hurley

    2004-09-27

    The University of North Dakota (UND) Chemical Engineering Department in conjunction with the UND Energy & Environmental Research Center (EERC) have initiated a program to thoroughly examine the combined chemical (reaction and phase change) and physical (erosion) effects experienced by a variety of refractory materials during both normal operation and thermal cycling under slagging coal gasification conditions. The goal of this work is to devise a mechanism of refractory loss under these conditions. The controlled-atmospheric dynamic corrodent application furnace (CADCAF) is being utilized to simulate refractory/slag interactions under dynamic conditions that more realistically simulate the environment in a slagging coal gasifier than any of the static tests used previously by refractory manufacturers and researchers. Shakedown testing of the CADCAF has been completed. Samples of slag and refractory from the Tampa Electric Polk Power Station have been obtained for testing in the CADCAF. The slag has been dried and sieved to the size needed for our flowing slag corrosion tests. Screening tests are in currently in progress. Detailed analysis of corrosion rates from the first tests is in progress.

  16. Chemical Hygiene and Safety Plan

    SciTech Connect (OSTI)

    Berkner, K.

    1992-08-01

    The objective of this Chemical Hygiene and Safety Plan (CHSP) is to provide specific guidance to all LBL employees and contractors who use hazardous chemicals. This Plan, when implemented, fulfills the requirements of both the Federal OSHA Laboratory Standard (29 CFR 1910.1450) for laboratory workers, and the Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) for non-laboratory operations (e.g., shops). It sets forth safety procedures and describes how LBL employees are informed about the potential chemical hazards in their work areas so they can avoid harmful exposures and safeguard their health. Generally, communication of this Plan will occur through training and the Plan will serve as a the framework and reference guide for that training.

  17. Uncoated microcantilevers as chemical sensors

    DOE Patents [OSTI]

    Thundat, Thomas G. (Knoxville, TN)

    2001-01-01

    A method and device are provided for chemical sensing using cantilevers that do not use chemically deposited, chemically specific layers. This novel device utilizes the adsorption-induced variation in the surfaces states on a cantilever. The methodology involves exciting charge carriers into or out of the surface states with photons having increasing discrete levels of energy. The excitation energy is provided as discrete levels of photon energy by scanning the wavelength of an exciting source that is illuminating the cantilever surface. When the charge carriers are excited into or out of the surface states, the cantilever bending changes due to changes in surface stress. The amount of cantilever bending with respect to an identical cantilever as a function of excitation energy is used to determine the energy levels associated with adsorbates.

  18. Chemical Hygiene Plan For University of Florida

    E-Print Network [OSTI]

    Slatton, Clint

    Chemical Hygiene Plan For University of Florida Laboratories This is a site specific Chemical Reviewed August 2007 Revised August 2007 #12;2 I. Introduction This Chemical Hygiene Plan has been with UF laboratory chemical operations and is intended to meet the requirements of the OSHA Laboratory

  19. Chemical Hygiene Plan (The OSHA Laboratory Standard)

    E-Print Network [OSTI]

    Walker, Lawrence R.

    Chemical Hygiene Plan (The OSHA Laboratory Standard) Contact: Chemical Hygiene Safety Officer Risk Management & Safety University of Nevada Las Vegas (702) 895-4226 #12;Updated 4/27/2015 ii Chemical Hygiene of the Chemical Hygiene Plan .................................3 D. Permissible Exposure Limits and Threshold

  20. Chemical Hygiene Plan 1.0 Introduction

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Chemical Hygiene Plan 1.0 Introduction Satisfying Cal-OSHA (Title 8 CCR 5191) and campus regulations, this Chemical Hygiene Plan includes safety information specific to the Center for Nano and Micro chemicals and gasses available. If you have any questions about this Chemical Hygiene Plan, please email

  1. 94 Chemical Engineering Education MICROMIXING EXPERIMENTS

    E-Print Network [OSTI]

    Hesketh, Robert

    94 Chemical Engineering Education MICROMIXING EXPERIMENTS In the Introductory Chemical Reaction aspects of chemical re- action engineering. A major priority in industrial reac- tors[1] is to optimize of the introductory undergraduate chemical reaction engineer- ing course, but the experiments described in this paper

  2. Celebrating Singularities: Mathematics and Chemical Engineering

    E-Print Network [OSTI]

    Chang, Hsueh-Chia

    Celebrating Singularities: Mathematics and Chemical Engineering Yunshan Wang, Xinguang Cheng, and Hsueh-Chia Chang Dept. of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame problems in chemical engineering. VC 2013 American Institute of Chemical Engineers AIChE J, 59: 1830

  3. Department of Chemical and Petroleum Engineering

    E-Print Network [OSTI]

    Habib, Ayman

    Methane, Tight Gas ­ Chemical & Petrochemical Industries ­ Growing Biomedical Industry Broad, Flexible

  4. Institute of Chemical Engineering page 1 Chemical Process Engineering

    E-Print Network [OSTI]

    Auzinger, Winfried

    as well as catalytic tar removal from producer gas originating from thermo-chemical hydrocarbon conversion of hydrocarbons in secondary units · Research and development on novel of gas cleaning technologies #12;Institute at TU Wien: · Development and research on novel gasification processes · Measurement results and data

  5. Highly Hazardous Chemicals and Chemical Spills EPA Compliance Fact Sheet

    E-Print Network [OSTI]

    Wikswo, John

    will be the direct cost charged to VEHS by our disposal contractor. VEHS does not mark up the disposal charges chemicals in your laboratory, leave them alone and notify VEHS immediately to arrange for disposal. Highly spills must be disposed of as hazardous waste. · Clean up spills when they happen or contact VEHS

  6. Speeding chemical reactions by focusing

    E-Print Network [OSTI]

    A. M. Lacasta; L. Ramirez-Piscina; J. M. Sancho; K. Lindenberg

    2012-12-13

    We present numerical results for a chemical reaction of colloidal particles which are transported by a laminar fluid and are focused by periodic obstacles in such a way that the two components are well mixed and consequently the chemical reaction is speeded up. The roles of the various system parameters (diffusion coefficients, reaction rate, obstacles sizes) are studied. We show that focusing speeds up the reaction from the diffusion limited rate (t to the power -1/2) to very close to the perfect mixing rate, (t to the power -1).

  7. Method for producing chemical energy

    DOE Patents [OSTI]

    Jorgensen, Betty S.; Danen, Wayne C.

    2004-09-21

    Fluoroalkylsilane-coated metal particles having a central metal core, a buffer layer surrounding the core, and a fluoroalkylsilane layer attached to the buffer layer are prepared by combining a chemically reactive fluoroalkylsilane compound with an oxide coated metal particle having a hydroxylated surface. The resulting fluoroalkylsilane layer that coats the particles provides them with excellent resistance to aging. The particles can be blended with oxidant particles to form energetic powder that releases chemical energy when the buffer layer is physically disrupted so that the reductant metal core can react with the oxidant.

  8. Spatiotemporal dynamics of photoexcited quasiparticles in two-dimensional crystals studied by ultrafast laser techniques

    E-Print Network [OSTI]

    Kumar, Nardeep

    2014-12-31

    dynamics. First, a second harmonic generation technique that can be used to find the crystalline orientation, thickness uniformity, layer stacking, and single-crystal domain size is discussed, with results presented on exfoliated and chemical vapor...

  9. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, Tuan (Knoxville, TN)

    1994-01-01

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation.

  10. Molecular beam studies of reaction dynamics

    SciTech Connect (OSTI)

    Lee, Y.T. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    The major thrust of this research project is to elucidate detailed dynamics of simple elementary reactions that are theoretically important and to unravel the mechanism of complex chemical reactions or photochemical processes that play important roles in many macroscopic processes. Molecular beams of reactants are used to study individual reactive encounters between molecules or to monitor photodissociation events in a collision-free environment. Most of the information is derived from measurement of the product fragment energy, angular, and state distributions. Recent activities are centered on the mechanisms of elementary chemical reactions involving oxygen atoms with unsaturated hydrocarbons, the dynamics of endothermic substitution reactions, the dependence of the chemical reactivity of electronically excited atoms on the alignment of excited orbitals, the primary photochemical processes of polyatomic molecules, intramolecular energy transfer of chemically activated and locally excited molecules, the energetics of free radicals that are important to combustion processes, the infrared-absorption spectra of carbonium ions and hydrated hydronium ions, and bond-selective photodissociation through electric excitation.

  11. POISON SPIDER FIELD CHEMICAL FLOOD PROJECT, WYOMING

    SciTech Connect (OSTI)

    Douglas Arnell; Malcolm Pitts; Jie Qi

    2004-11-01

    A reservoir engineering and geologic study concluded that approximate 7,852,000 bbls of target oil exits in Poison Spider. Field pore volume, OOIP, and initial oil saturation are defined. Potential injection water has a total dissolved solids content of 1,275 mg/L with no measurable divalent cations. If the Lakota water consistently has no measurable cations, the injection water does not require softening to dissolve alkali. Produced water total dissolved solids were 2,835 mg/L and less than 20 mg/L hardness as the sum of divalent cations. Produced water requires softening to dissolve chemicals. Softened produced water was used to dissolve chemicals in these evaluations. Crude oil API gravity varies across the field from 19.7 to 22.2 degrees with a dead oil viscosity of 95 to 280 cp at 75 F. Interfacial tension reductions of up to 21,025 fold (0.001 dyne/cm) were developed with fifteen alkaline-surfactant combinations at some alkali concentration. An additional three alkaline-surfactant combinations reduced the interfacial tension greater than 5,000 fold. NaOH generally produced the lowest interfacial tension values. Interfacial tension values of less than 0.021 dyne/cm were maintained when the solutions were diluted with produced water to about 60%. Na{sub 2}CO{sub 3} when mixed with surfactants did not reduce interfacial tension values to levels at which incremental oil can be expected. NaOH without surfactant interfacial tension reduction is at a level where some additional oil might be recovered. Most of the alkaline-surfactant-polymer solutions producing ultra low interfacial tension gave type II- phase behavior. Only two solutions produced type III phase behavior. Produced water dilution resulted in maintenance of phase type for a number of solutions at produced water dilutions exceeding 80% dilution. The average loss of phase type occurred at 80% dilution. Linear corefloods were performed to determine relative permeability end points, chemical-rock compatibility, polymer injectivity, dynamic chemical retention by rock, and recommended injected polymer concentration. Average initial oil saturation was 0.796 Vp. Produced water injection recovered 53% OOIP leaving an average residual oil saturation of 0.375 Vp. Poison Spider rock was strongly water-wet with a mobility ratio for produced water displacing the 280 cp crude oil of 8.6. Core was not sensitive to either alkali or surfactant injection. Injectivity increased 60 to 80% with alkali plus surfactant injection. Low and medium molecular weight polyacrylamide polymers (Flopaam 3330S and Flopaam 3430S) dissolved in either an alkaline-surfactant solution or softened produced water injected and flowed through Poison Spider rock. Recommended injected polyacrylamide concentration is 2,100 mg/L for both polymers for a unit mobility ratio. Radial corefloods were performed to evaluate oil recovery efficiency of different chemical solutions. Waterflood oil recovery averaged 46.4 OOIP and alkaline-surfactant-polymer flood oil recovery averaged an additional 18.1% OIP for a total of 64.6% OOIP. Oil cut change due to injection of a 1.5 wt% Na{sub 2}CO{sub 3} plus 0.05 wt% Petrostep B-100 plus 0.05 wt% Stepantan AS1216 plus 2100 mg/L Flopaam 3430S was from 2% to a peak of 23.5%. Additional study might determine the impact on oil recovery of a lower polymer concentration. An alkaline-surfactant-polymer flood field implementation outline report was written.

  12. Homeostasis in Chemical Reaction Pathways

    E-Print Network [OSTI]

    V. A. Malyshev; A. D. Manita; A. A. Zamyatin

    2011-12-25

    We consider stochastic models of chemical reaction networks with time dependent input rates and several types of molecules. We prove that, in despite of strong time dependence of input rates, there is a kind of homeostasis phenomenon: far away from input nodes the mean numbers of molecules of each type become approximately constant (do not depend on time).

  13. Extended range chemical sensing apparatus

    DOE Patents [OSTI]

    Hughes, R.C.; Schubert, W.K.

    1994-01-18

    An apparatus is described for sensing chemicals over extended range of concentrations. In particular, first and second sensors each having separate, but overlapping ranges for sensing concentrations of hydrogen are provided. Preferably, the first sensor is a MOS solid state device wherein the metal electrode or gate is a nickel alloy. The second sensor is a chemiresistor comprising a nickel alloy. 6 figures.

  14. CompositionsCHEMICAL Mallet Library

    E-Print Network [OSTI]

    CompositionsCHEMICAL Mallet Library Chairman's Corner Computer facility opens West wing renovation fall 1996 chemistry & biochemistry departmental newsletter The Chemistry Library has existed almost- istry Department and of the General Libraries, from modest beginnings in the late 19th century

  15. UB DEPARTMENT OF CHEMICAL AND BIOLOGICAL ENGINEERING BS in Chemical and Biological Engineering

    E-Print Network [OSTI]

    Krovi, Venkat

    UB DEPARTMENT OF CHEMICAL AND BIOLOGICAL ENGINEERING BS in Chemical and Biological EngineeringD (all in Chemical Engineering) · Average ChE starting salary: $66,000 (BS) · A five-year BS in Chemical by teaching assistants: 0 What Do Chemical and Biological Engineers Do? CBE graduates apply chemistry to make

  16. Nano Res. 2011, 4(12): 124212471242 Chemical Versus Thermal Folding of Graphene Edges

    E-Print Network [OSTI]

    Simons, Jack

    Nano Res. 2011, 4(12): 1242­12471242 Chemical Versus Thermal Folding of Graphene Edges Ninghai Su dynamics (MD) simulations, we have investigated the kinetics of the graphene edge folding processV/Å (or about 120 meV per edge atom) for folding the edges of intrinsic clean single-layer graphene (SLG

  17. Collective Surfing of Chemically Active Particles Hassan Masoud1,2,*

    E-Print Network [OSTI]

    Shelley, Michael

    . This energy may come from chemical energy and the work done on the fluid can be used for self-propulsion. Most, New York 10012, USA 2 Department of Mechanical and Aerospace Engineering, Princeton University the collective dynamics of immotile particles bound to a 2D surface atop a 3D fluid layer. These particles

  18. A timescale investigation of volatile chemical retention during hydrometeor freezing: Nonrime freezing

    E-Print Network [OSTI]

    Jacobson, Mark

    transport regime and is nonmonotonic due to the competing effects of ventilation on heat and mass transport--constituent transport and chemistry; 3354 Meteorology and Atmospheric Dynamics: Precipitation (1854); KEYWORDS: ice mechanism of precipitation development in cold clouds. Chemical solutes originally dissolved

  19. Transactions Dynamic Article Links

    E-Print Network [OSTI]

    -density solids have been utilized in catalysis,18,19 gas storage,20 and chemical separations,21 where their large

  20. CHEMICAL ABUNDANCES IN CLUSTERS OF GALAXIES

    E-Print Network [OSTI]

    Francesca Matteucci; Brad K. Gibson

    1995-03-14

    We study the origin of iron and alpha-elements (O, Mg, Si) in clusters of galaxies. In particular, we discuss the [O/Fe] ratio and the iron mass-to-luminosity ratio in the intracluster medium (ICM) and their link to the chemical and dynamical evolution of elliptical and lenticular galaxies. We adopt a detailed model of galactic evolution incorporating the development of supernovae- driven galactic winds which pollute the ICM with enriched ejecta. We demonstrate \\it quantitatively \\rm the crucial dependence upon the assumed stellar initial mass function in determining the evolution of the mass and abundances ratios of heavy elements in typical model ICMs. We show that completely opposite behaviours of [alpha/Fe] ratios (\\ie positive versus negative ratios) can be obtained by varying the initial mass function without altering the classic assumptions regarding type Ia supernovae progenitors or their nucleosynthesis. Our results indicate that models incorporating somewhat flatter-than-Salpeter initial mass functions (ie x approx 1, as opposed to x=1.35) are preferred, provided the intracluster medium iron mass-to-luminosity ratio, preliminary [alpha/Fe]>0 ASCA results, and present-day type Ia supernovae rates, are to be matched. A simple Virgo cluster simulation which adheres to these constraints shows that approx 70% of the measured ICM iron mass has its origin in type II supernovae, with the remainder being synthesized in type Ia systems.

  1. Simulation of quantum interference by reactions of chemical type

    E-Print Network [OSTI]

    Yuri Ozhigov

    2003-11-06

    A quantum unitary evolution alternated with measurements is simulated by a bubble filled with fictitious particles called amplitude quanta that move chaotically and can be transformed by the simple rules that look like chemical reactions. A basic state of simulated system is treated as a collision of the two corresponding amplitude quanta, that gives the quantum statistics of measurements. The movement of the external membrane of the bubble corresponds to the classical dynamics of the simulated system. Measurements are treated as the membrane perforations and they are completely determined by initial conditions. An identity of particles and an entanglement is simulated by the membranes touching. The required memory grows linearly where the number of particles increases, but entangled states of the big number of particles can be simulated. The method can be used for a visualization of quantum dynamics.

  2. Chemical compositions, methods of making the chemical compositions, and structures made from the chemical compositions

    DOE Patents [OSTI]

    Yang, Lei; Cheng, Zhe; Liu, Ze; Liu, Meilin

    2015-01-13

    Embodiments of the present disclosure include chemical compositions, structures, anodes, cathodes, electrolytes for solid oxide fuel cells, solid oxide fuel cells, fuel cells, fuel cell membranes, separation membranes, catalytic membranes, sensors, coatings for electrolytes, electrodes, membranes, and catalysts, and the like, are disclosed.

  3. Passive in-situ chemical sensor

    DOE Patents [OSTI]

    Morrell, Jonathan S. (Farragut, TN); Ripley, Edward B. (Knoxville, TN)

    2012-02-14

    A chemical sensor for assessing a chemical of interest. In typical embodiments the chemical sensor includes a first thermocouple and second thermocouple. A reactive component is typically disposed proximal to the second thermal couple, and is selected to react with the chemical of interest and generate a temperature variation that may be detected by a comparison of a temperature sensed by the second thermocouple compared with a concurrent temperature detected by the first thermocouple. Further disclosed is a method for assessing a chemical of interest and a method for identifying a reaction temperature for a chemical of interest in a system.

  4. Olefin recovery via chemical absorption

    SciTech Connect (OSTI)

    Barchas, R.

    1998-06-01

    The recovery of fight olefins in petrochemical plants has generally been accomplished through cryogenic distillation, a process which is very capital and energy intensive. In an effort to simplify the recovery process and reduce its cost, BP Chemicals has developed a chemical absorption technology based on an aqueous silver nitrate solution. Stone & Webster is now marketing, licensing, and engineering the technology. The process is commercially ready for recovering olefins from olefin derivative plant vent gases, such as vents from polyethylene, polypropylene, ethylene oxide, and synthetic ethanol units. The process can also be used to debottleneck C{sub 2} or C{sub 3} splinters, or to improve olefin product purity. This paper presents the olefin recovery imp technology, discusses its applications, and presents economics for the recovery of ethylene and propylene.

  5. Geometric description of chemical reactions

    E-Print Network [OSTI]

    Hernando Quevedo; Diego Tapias

    2013-01-02

    We use the formalism of Geometrothermodynamics to describe chemical reactions in the context of equilibrium thermodynamics. Any chemical reaction in a closed system is shown to be described by a geodesic in a $2-$dimensional manifold that can be interpreted as the equilibrium space of the reaction. We first show this in the particular cases of a reaction with only two species corresponding to either two ideal gases or two van der Waals gases. We then consider the case of a reaction with an arbitrary number of species. The initial equilibrium state of the geodesic is determined by the initial conditions of the reaction. The final equilibrium state, which follows from a thermodynamic analysis of the reaction, is shown to correspond to a coordinate singularity of the thermodynamic metric which describes the equilibrium manifold.

  6. Monte Carlo Studies of Nonequilibrium Vacancy Mediated Dynamics in Binary Alloys

    E-Print Network [OSTI]

    Wong-Ekkabut, Jirasak

    . This gives rise to the fundamental questions in both disciplines. Crucial to metallurgy, the domain

  7. The Graduate School Programs of Study The Graduate School at the University of Maine (UMaine) offers programs leading to the doctoral degree in the following disciplines

    E-Print Network [OSTI]

    Thomas, Andrew

    and environmental policy, biochemistry and molecular biology; biological sciences; biomedical engineering; biomedical sciences; chemical engineering; chemistry; civil engineering; clinical psychology; communication engineering; engineering in the sciences (interdisciplinary Ph.D.); food and nutrition sciences; forest

  8. ELIGIBLE DISCIPLINES FOR QEII-GSST PURPOSES The QEII-GSST program supports graduate students enrolled in research master's and doctoral

    E-Print Network [OSTI]

    Engineering) · Systems and Industrial Engineering (may include Systems/Design Engineering and Operational. Applied Sciences: · Aerospace (may include Aeronautical Engineering) · Biomedical Engineering · Chemical Engineering · Civil Engineering and Architecture (may include Landscape Architecture) · Computer Engineering

  9. Chemical logging of geothermal wells

    DOE Patents [OSTI]

    Allen, Charles A. (Idaho Falls, ID); McAtee, Richard E. (Idaho Falls, ID)

    1981-01-01

    The presence of geothermal aquifers can be detected while drilling in geothermal formations by maintaining a chemical log of the ratio of the concentrations of calcium to carbonate and bicarbonate ions in the return drilling fluid. A continuous increase in the ratio of the concentrations of calcium to carbonate and bicarbonate ions is indicative of the existence of a warm or hot geothermal aquifer at some increased depth.

  10. Siphons in chemical reaction networks

    E-Print Network [OSTI]

    Shiu, Anne

    2009-01-01

    Siphons in a chemical reaction system are subsets of the species that have the potential of being absent in a steady state. We present a characterization of minimal siphons in terms of primary decomposition of binomial ideals, we explore the underlying geometry, and we demonstrate the effective computation of siphons using computer algebra software. This leads to a new method for determining whether given initial concentrations allow for various boundary steady states.

  11. Computational modelling in chemical engineering

    E-Print Network [OSTI]

    Kraft, Markus

    2008-08-27

    Dynamic Gauging DNS of a flame kernel Flow in a oscillatory flow reactor. Pom-Pom equation for polydisperse polystyren Markus Kraft mk306@cam.ac.uk Engine optimisation •Increase Efficiency reduce carbon dioxide •Reduce Emission soot,NOx, unburnt...

  12. Ocean Engineering Two Year Graduate Course Schedule Graduate students from both the ocean and mechanical engineering programs may take courses from either discipline. The current schedule of courses for ocean

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Ocean Engineering Two Year Graduate Course Schedule Graduate students from both the ocean and mechanical engineering programs may take courses from either discipline. The current schedule of courses for ocean engineering is given below: Spring 2014 Summer 2014 Fall 2014 Spring 2015 Summer 2015 Fall 2015

  13. The Honor and Discipline Committee reports to the College each year about the nature of the cases it has heard, the judgments it has made, and the penalties it has determined.

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    The Honor and Discipline Committee reports to the College each year about the nature of the cases it has heard, the judgments it has made, and the penalties it has determined. This report covers-2008 year. Following this report is a report on disciplinary activity in the Dean's Office. Report

  14. Reaction Dynamics and Spectroscopy of Hydrocarbons in Plasma

    SciTech Connect (OSTI)

    Braams, Bastiaan J.

    2014-03-24

    This grant supported research in theoretical and computational Chemical Physics that resulted in numerous publications on fitting ab initio potential energy surfaces and dipole moment surfaces of polyatomic molecules and cations. This work made use of novel fitting methods that ensures that these surfaces are invariant with respect to all permutations of like atoms. The surfaces were used in various dynamics calculations, ranging from quantum vibrational dynamics to(quasi)classical trajectory calculations of reaction dynamics. A number of these studies were done in collaboration with experimental groups where the theoretical analyses turned out to be essential to give a proper understanding of the experimental results.

  15. Theoretical and Experimental Evaluation of Chemical Reactivity 

    E-Print Network [OSTI]

    Wang, Qingsheng

    2011-10-21

    theoretical and experimental methods. Methylcyclopentadiene (MCP) and Hydroxylamine (HA) are selected as representatives of unsaturated hydrocarbons and self-reacting chemicals, respectively. Chemical reactivity of MCP, including isomerization, dimerization...

  16. Alternative Energy Department of Chemical Engineering

    E-Print Network [OSTI]

    Mahon, Bradford Z.

    Alternative Energy Department of Chemical Engineering Graduate Handbook 2013-2014 Gina Eagan, Graduate Program Coordinator Professor Matthew Yates, Director of Alternative Energy #12;University of Rochester Graduate Handbook Alternative Energy updated August, 2013 Department of Chemical Engineering Page

  17. Alternative Energy Department of Chemical Engineering

    E-Print Network [OSTI]

    Cantlon, Jessica F.

    Alternative Energy Department of Chemical Engineering Graduate Handbook 2014-2015 Victoria Heberling, Graduate Program Coordinator Professor Matthew Yates, Director of Alternative Energy #12;University of Rochester Graduate Handbook Alternative Energy updated August, 2013 Department of Chemical

  18. Future scenarios for green chemical supply chains

    E-Print Network [OSTI]

    Arora, Vibhu, M. Eng. Massachusetts Institute of Technology

    2013-01-01

    We live in an age where industrial chemicals are central to the modem economy serving as the basis for all man-made fibers, life-science chemicals and consumer products. Owing to globalization, the industry has grown to ...

  19. SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology)

    E-Print Network [OSTI]

    Wang, Hai

    SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology) Undergraduate Hometown.D. in chemical engineering with an emphasis in nanotechnology. Lindsay stands out as a very well-balanced student

  20. GENERALIZED TOPOLOGIES: HYPERGRAPHS, CHEMICAL REACTIONS, AND

    E-Print Network [OSTI]

    Flamm, Christoph

    topological spaces have applications in various applied domains of computer science, including digital image types or chemical species. A chemical reaction is a transformation rule of the form xX s- ,xx xX s

  1. Chemical and Petroleum Engineering Petroleum Engineering Minor

    E-Print Network [OSTI]

    Chemical and Petroleum Engineering Petroleum Engineering Minor Students pursuing a BSc in Mechanical Engineering or Chemical Engineering can broaden their skills by taking a minor in petroleum engineering. Energy is the largest

  2. Studying the Solar System's Chemical Recipe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studying the Solar System's Chemical Recipe Studying the Solar System's Chemical Recipe Print Tuesday, 26 March 2013 00:00 To study the origins of different isotope ratios among...

  3. Systematic approach for chemical reactivity evaluation 

    E-Print Network [OSTI]

    Aldeeb, Abdulrehman Ahmed

    2004-09-30

    incidents, and have harmed people, property, and the environment. Evaluation of reactive chemical hazards is critical to design and operate safer chemical plant processes. Much effort is needed for experimental techniques, mainly calorimetric analysis...

  4. Department of Energy, Environmental & Chemical Engineering

    E-Print Network [OSTI]

    Subramanian, Venkat

    . R. Chen and Dr. P. Biswas. summer 2010 : india-- international experience in energy, environmentalDepartment of Energy, Environmental & Chemical Engineering Opportunities for Undergraduate Students laboratory is a good way to expand your classroom experience. department of energy, environmental & chemical

  5. CHEMICAL SENSORS School of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Sherrill, David

    students. Prerequisites include an introductory course in physical or analytical chemistry, undergraduateCHEMICAL SENSORS CHEM 6282 School of Chemistry and Biochemistry Chemical sensors is an interdisciplinary topic covering area of science and engineering that lies between chemistry, physics, materials

  6. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  7. Searching for the Solar System's Chemical Recipe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Searching for the Solar System's Chemical Recipe Searching for the Solar System's Chemical Recipe Print Wednesday, 20 February 2013 00:00 The ratio of isotopes in elements like...

  8. ITP Chemicals: Industrial Feedstock Flexibility Workshop Results...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Feedstock Flexibility Workshop Results, December 2009 ITP Chemicals: Industrial Feedstock Flexibility Workshop Results, December 2009 feedstockworkshopreport.pdf More...

  9. Chemical Free Water Analysis with Nanoelectrode Arrays

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2013-06-05

    Electrochemical analysis is a highly sensitive, chemically selective method for identifying and quantifying many different chemicals in water.  Previous art required  field samples be transported to a laboratory where additional chemicals would be added before the analysis could be performed.  Sandia National Laboratories has invented an electrochemical analysis method that has eliminated the need to add chemicals to the testing process while increasing the...

  10. CHEMICAL BIODYNAMICS DIVISION ANNUAL REPORT 1978

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    chemical Conversion and Storage of Solar Energy. Cambridge,Conversion and Storage of Solar Energy. Cambridge, England.

  11. Plant behavioural ecology: dynamic plasticity in secondary metabolites

    E-Print Network [OSTI]

    Aschehoug, Erik

    Plant behavioural ecology: dynamic plasticity in secondary metabolites KERRY L. METLEN, ERIK T induction and attenuation of plant secondary metabolites occur as chemically mediated root foraging, plant growth. Rapid and reversible secondary metabolite production and release is also a key mechanism by which

  12. Dynamic Salting Route Optimisation using Evolutionary Computation Hisashi Handa

    E-Print Network [OSTI]

    Yao, Xin

    , if salt is spread when it is not actually required, there are unnecessary financial and environ- mental realises daily dynamic routing and it will yield considerable ben- efits for areas with a marginal ice effective use of resources (i.e. treat- ment vehicles, personnel and de-icing chemical material). The aim

  13. International Symposium on Structure and Dynamics of Heterogeneous Systems

    E-Print Network [OSTI]

    Duisburg-Essen, Universität

    on light-activated proteins, water, melting and transport Chairman: P. Entel 13:30­14:10 Norbert Hampp (Chemistry Department, Nagoya University, Nagoya, Japan) Water dynamics, fluctuation, freezing and chemical transport in single-molecule junctions 19:00­21:00 SNACKS, BEVERAGES AND POSTER SHOW Friday, November 29

  14. Gas-Phase Molecular Dynamics: High Resolution Spectroscopy and Collision Dynamics of Transient Species

    SciTech Connect (OSTI)

    Hall G. E.; Goncharov, V.

    2012-05-29

    This research is carried out as part of the Gas-Phase Molecular Dynamics program in the Chemistry Department at Brookhaven National Laboratory. Chemical intermediates in the elementary gas-phase reactions involved in combustion chemistry are investigated by high resolution spectroscopic tools. Production, reaction, and energy transfer processes are investigated by transient, double resonance, polarization and saturation spectroscopies, with an emphasis on technique development and connection with theory, as well as specific molecular properties.

  15. Gas-Phase Molecular Dynamics: High Resolution Spectroscopy and Collision Dynamics of Transient Species

    SciTech Connect (OSTI)

    Hall, G.E.

    2011-05-31

    This research is carried out as part of the Gas-Phase Molecular Dynamics program in the Chemistry Department at Brookhaven National Laboratory. Chemical intermediates in the elementary gas-phase reactions involved in combustion chemistry are investigated by high resolution spectroscopic tools. Production, reaction, and energy transfer processes are investigated by transient, double resonance, polarization and saturation spectroscopies, with an emphasis on technique development and connection with theory, as well as specific molecular properties.

  16. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  17. Chemical Oceanography MSCI/GEOL 782

    E-Print Network [OSTI]

    1 Chemical Oceanography MSCI/GEOL 782 Instructor: Dr. Claudia Benitez-Nelson Email: cbnelson: Tues/Thurs from 8:30 to 9:45 in EWSC 209 Website: http://blackboard.sc.edu/ Text: Chemical Oceanography by Emerson and Hedges (PDF's online) Non-required , but useful texts: Chemical Oceanography by Frank Millero

  18. A Chemical Edcation Leo P. Kadanoff1

    E-Print Network [OSTI]

    Kadanoff, Leo P.

    A Chemical Edcation by Leo P. Kadanoff1 Uncle Tungsten by Oliver Sacks Alfred A. Knopf, New York Oliver's extensive and foolhardy chemical experiments. In a home basement laboratory, he acquaints himself with the properties of the different chemical elements by the classic process of mixing

  19. Chemical Hygiene Policy Procedure: 6.05

    E-Print Network [OSTI]

    Jia, Songtao

    Chemical Hygiene Policy Procedure: 6.05 Version: 1.0 Created: 6/15/2013 1 A. Purpose: The Chemical Hygiene policy establishes Columbia University's position for the protection of laboratory workers Chemicals in Laboratories, also referred to as the Laboratory Standard. This policy provides current general

  20. Montana State University 1 Department of Chemical

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Montana State University 1 Department of Chemical and Biological Engineering Department of Science in Chemical Engineering degree and a Master of Science degree in Environmental Engineering, with options available in Chemical Engineering and Environmental Engineering. Admission (M.S. and Ph

  1. Basic Chemical Safety and Laboratory Survival Skills

    E-Print Network [OSTI]

    Sherrill, David

    1 Basic Chemical Safety and Laboratory Survival Skills For anyone working in Georgia Tech Laboratories Deborah Wolfe-Lopez Laboratory and Chemical Safety Manager Georgia Tech EHS 404-382-2964 2010 #12 Hazardous Chemical Protection and Right to Know Law (RTK) RTK is the Georgia State Equivalent of the Federal

  2. Geophysics of Chemical Heterogeneity in the Mantle

    E-Print Network [OSTI]

    Stixrude, Lars

    , transition zone Abstract Chemical heterogeneity, produced by the near-surface rock cycle and dom- inatedGeophysics of Chemical Heterogeneity in the Mantle Lars Stixrude and Carolina Lithgow. This lithologic-scale chemical het- erogeneity may survive in the mantle for as long as the age of Earth because

  3. Classical Coordination Mechanisms in the Chemical Model

    E-Print Network [OSTI]

    Fradet, Pascal

    great souvenir! Abstract Originally, the chemical model of computation has been proposed as a sim- pleClassical Coordination Mechanisms in the Chemical Model J.-P. Ban^atre P. Fradet Y. Radenac-Pierre Ban^atre) had with Gilles on topics related with programming in general and chemical programming

  4. A Topological Approach to Chemical Organizations

    E-Print Network [OSTI]

    Stadler, Peter F.

    The Santa Fe Institute, 1399 Hyde Park Rd., Santa Fe NM 87501 Abstract Large chemical reaction networks. This abstract representation in turn suggest to explore the chemical meaning of well-established topological.g. in the Chemical Abstract Machine [7]. A wide variety of different computa- tional paradigms has been used

  5. Chemical Evolution of Galaxies: a problem of

    E-Print Network [OSTI]

    ?umer, Slobodan

    Chemical Evolution of Galaxies: a problem of Astroarchaelogy Francesca Matteucci, Trieste University Lubljana, February 24, 2014 #12;Chemical Evolution of Galaxies Beatrice Tinsley (27 January 1941- 23 March 1981) She started the field of galactic chemical evolution #12;Collaborators: #12;Outline

  6. Chemical Reactor Analysis and Optimal Digestion

    E-Print Network [OSTI]

    Jumars, Pete

    derived from basic principles o f chemical reactor analysis and design Deborah L. Penry and Peter in terms of chemical reactor components and then use principles of reactor design to identify variablesJ 310 Chemical Reactor Analysis and Optimal Digestion An optimal digestion theory can be readily

  7. QANU Research Review Chemical Engineering 3TU

    E-Print Network [OSTI]

    Theune, Mariët

    QANU Research Review Chemical Engineering 3TU QANU, November 2009 #12;2 QANU / Research Review Chemical Engineering 3TU Quality Assurance Netherlands Universities (QANU) Catharijnesingel 56 PO Box 8035 / Research Review Chemical Engineering 3TU Contents Foreword 5 Preface 7 1. The review Committee

  8. 138 Chemical Engineering Education FLUIDIZED BED

    E-Print Network [OSTI]

    Hesketh, Robert

    138 Chemical Engineering Education FLUIDIZED BED POLYMER COATING EXPERIMENT ROBERT P. HESKETH, C,2] and is a highly visual experiment in chemical engineering pro- cesses and experimentation. In addition for the chemical engineering profession. The field encom- passes many technologies, ranging from polymerization

  9. Third International Symposium ENGINEERING OF CHEMICAL COMPLEXITY

    E-Print Network [OSTI]

    Rudzick, Oliver

    Third International Symposium ENGINEERING OF CHEMICAL COMPLEXITY Program 4 May, Tuesday 16:00 ­ 20:45 ­ 11:15 Coffee break Session chair: R. Kapral 11:15 M. Britton "Probing chemical waves and patterns "Anomalous dispersion in chemical reaction-diffusion systems" 15:10 S. Müller "Hydrodynamic instability

  10. Chemical and Biological Engineering Summary of Actions

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Chemical and Biological Engineering Summary of Actions 2014-2015 Concern Recommendation Action Follow-up 1. The department name is Chemical and Biological Engineering. An analysis of student Biological Engineering programs. 4. The second semester of the senior capstone sequence in Chemical

  11. Vanderbilt Department of Chemical and Biomolecular Engineering

    E-Print Network [OSTI]

    Vanderbilt Department of Chemical and Biomolecular Engineering #12;2 Plasmonics and Nanophotonics Graduate work in chemical and biomolecular engineering provides an opportunity for study and research at the cutting edge--to contribute to shaping a new model of what chemical engineers do. All faculty members

  12. 192 Chemical Engineering Education IS PROCESS SIMULATION

    E-Print Network [OSTI]

    Hesketh, Robert

    192 Chemical Engineering Education IS PROCESS SIMULATION USED EFFECTIVELY IN ChE COURSES? KEVIN D of specific methods of effective use of these tools in chemical engineering courses, both from the literature and from the authors' experience. DISCUSSION In the past, most chemical engineering programs viewed process

  13. Computing Resources at Chemical and Biochemical Engineering

    E-Print Network [OSTI]

    Muzzio, Fernando J.

    Computing Resources at Chemical and Biochemical Engineering Note that use of all Rutgers University) consists of 18 Windows NT Workstations and is primarily reserved for classroom use for Chemical Engineering at Chemical and Biochemical Engineering. DSV Lab. The DSV lab consists of 60 Sun UltraSparc 10 computers. Each

  14. Chemical Engineering at McMaster University

    E-Print Network [OSTI]

    Thompson, Michael

    Chemical Engineering at McMaster University The Formative Years: A Brief History 1958-1982 Cameron. Woods #12;Copyright 2011 © Department of Chemical Engineering, McMaster University, Hamilton, Ontario, L. Photographs are reproduced by courtesy of the Faculty of Engineering and the Department of Chemical

  15. Chemical Engineering BEng (Hons) Key details

    E-Print Network [OSTI]

    Painter, Kevin

    Chemical Engineering BEng (Hons) Key details Duration: Full-time: 3 years (BEng) / 4 years (BEng Hons) Delivery type: Day Intake date: September Fees: 58000 AED per year Overview Chemical engineering successful and thriving types of business in the world. Chemical engineers play a vital role in achieving

  16. CHEMICAL REMOVAL OF BIOMASS FROM WASTE AIR BIOTRICKLING FILTERS: SCREENING OF CHEMICALS

    E-Print Network [OSTI]

    CHEMICAL REMOVAL OF BIOMASS FROM WASTE AIR BIOTRICKLING FILTERS: SCREENING OF CHEMICALS OF POTENTIAL INTEREST H. H. J. COX and M. A. DESHUSSES* Department of Chemical and Environmental Engineering October 1998) AbstractÐA protocol was developed to rapidly assess the eciency of chemical washing

  17. Z .Chemical Geology 145 1998 325394 The chemical composition of subducting sediment and its

    E-Print Network [OSTI]

    Langmuir, Charles H.

    Z .Chemical Geology 145 1998 325­394 The chemical composition of subducting sediment and its heterogeneity all require a better understanding of the mass and chemical fluxes associated with subducting sediments. We have evaluated subducting sediments on a global basis in order to better define their chemical

  18. Using chemical tracers in hillslope soils to estimate the importance of chemical denudation under

    E-Print Network [OSTI]

    Mudd, Simon Marius

    Using chemical tracers in hillslope soils to estimate the importance of chemical denudation under mass. The model includes both sediment transport and chemical denudation. A simplified two-phase model is developed; the two phases are a chemically immobile phase, which has far lower solubility than the bulk soil

  19. Chemical engineers design, control and optimize large-scale chemical, physicochemical and

    E-Print Network [OSTI]

    Rohs, Remo

    Introduction to Separation Processes (3, Sp) Use of equilibrium phase relations and principles of material by petition only. 405 Applications of Probability and Statistics for Chemical Engineers (3, Fa) Principles Chemical Reactor Analysis (4, Fa) Basic concepts of chemical kinetics and chemical reactor design

  20. The Chemical Engineering Ph.D. Program Department of Chemical Engineering

    E-Print Network [OSTI]

    Firestone, Jeremy

    The Chemical Engineering Ph.D. Program Department of Chemical Engineering University of Delaware of chemical engineering fundamentals and their application. The requirements set out below represent a foundation of technical knowledge in chemical engineering. This knowledge should be obtained in a way

  1. Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds

    E-Print Network [OSTI]

    Zare, Richard N.

    Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds Latest News News | Chemical & Engineering News http://pubs.acs.org/cen/news/87/i24/8724news1.html 1 of 2 6 for the Advancement of Science, and the Association for Women in Science. Chemical & Engineering News ISSN 0009

  2. 8 Chemical Engineering Education first met Robert Hesketh at the 1992 Chemical Engineering Sum-

    E-Print Network [OSTI]

    Hesketh, Robert

    #12;8 Chemical Engineering Education I first met Robert Hesketh at the 1992 Chemical Engineering the opportunity to hire him as one of the found- ing members of the Rowan Chemical Engineering Department! During sources. As one of the founding faculty members of the College of Engineer- ing and Chemical Engineering

  3. Open Innovation in Chemical Engineering The technological and business principles of Open Innovation in the chemical

    E-Print Network [OSTI]

    Engineering The technological and business principles of Open Innovation in the chemical industry: inventions in Closed and Open Innovation Open innovation business models in the chemical engineering. Open innovation companies working in the neighborhood of chemical engineering. Examples of open innovation in the chemical

  4. Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds

    E-Print Network [OSTI]

    Zare, Richard N.

    Chemical & Engineering News Serving the chemical, life sciences and laboratory worlds Cover Story | Chemical & Engineering News http://pubs.acs.org/cen/coverstory/88/8812cover2.html 1 of 5 3/22/2010 09 fail. Fostering Creativity | Cover Story | Chemical & Engineering News http

  5. M. Bahrami ENSC 461 (S 11) Chemical Reactions 1 Chemical Reactions

    E-Print Network [OSTI]

    Bahrami, Majid

    M. Bahrami ENSC 461 (S 11) Chemical Reactions 1 Chemical Reactions When analyzing reacting systemsHm. For example octane is C8H18. Combustion: is a chemical reaction during which a fuel is oxidized and a large.28 #12;M. Bahrami ENSC 461 (S 11) Chemical Reactions 2 Where N is the number of moles and M is the molar

  6. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1994-12-27

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation. The invention also relates to the fabrication of protective clothing materials. 13 figures.

  7. Chemical kinetics and combustion modeling

    SciTech Connect (OSTI)

    Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

  8. Microcomponent chemical process sheet architecture

    DOE Patents [OSTI]

    Wegeng, Robert S. (Richland, WA); Drost, M. Kevin (Richland, WA); Call, Charles J. (Pasco, WA); Birmingham, Joseph G. (Richland, WA); McDonald, Carolyn Evans (Richland, WA); Kurath, Dean E. (Benton County, WA); Friedrich, Michele (Prosser, WA)

    1998-01-01

    The invention is a microcomponent sheet architecture wherein macroscale unit processes are performed by microscale components. The sheet architecture may be a single laminate with a plurality of separate microcomponent sections or the sheet architecture may be a plurality of laminates with one or more microcomponent sections on each laminate. Each microcomponent or plurality of like microcomponents perform at least one chemical process unit operation. A first laminate having a plurality of like first microcomponents is combined with at least a second laminate having a plurality of like second microcomponents thereby combining at least two unit operations to achieve a system operation.

  9. Microcomponent chemical process sheet architecture

    DOE Patents [OSTI]

    Wegeng, R.S.; Drost, M.K.; Call, C.J.; Birmingham, J.G.; McDonald, C.E.; Kurath, D.E.; Friedrich, M.

    1998-09-22

    The invention is a microcomponent sheet architecture wherein macroscale unit processes are performed by microscale components. The sheet architecture may be a single laminate with a plurality of separate microcomponent sections or the sheet architecture may be a plurality of laminates with one or more microcomponent sections on each laminate. Each microcomponent or plurality of like microcomponents perform at least one chemical process unit operation. A first laminate having a plurality of like first microcomponents is combined with at least a second laminate having a plurality of like second microcomponents thereby combining at least two unit operations to achieve a system operation. 26 figs.

  10. Chemical Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene NetworkNuclear SecurityChattan ooga Eag le ForChemCamChemical

  11. Chemical Physics | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene NetworkNuclear SecurityChattan ooga Eag leChemical

  12. Chemical Resources | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMayARM-0501 Marine StratusChemCamChemical Resources

  13. Inventure Chemicals | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimenMakingBiofuelsInformationSocietyInvensysChemicals Jump

  14. Chemical Looping | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR JumpMaine: EnergyEnergy InformationChemical Looping Jump

  15. Chemical Science | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeVehicle ReplacementStatesA CaseNovemberto3:2:8:Chemical Science

  16. Isomer-Specific Biodegradation and Chemical Oxidation of Nonylphenol

    E-Print Network [OSTI]

    Lu, Zhijiang

    2014-01-01

    in U.S. sewage sludges and chemical fate in outdoor soilendocrine disrupting chemicals by potassium permanganate inconfidential 2006 IUR company/chemical records." Retrieved

  17. Chemical burn caused by topical application of garlic under occlusion

    E-Print Network [OSTI]

    Xu, Shuai; Heller, Marissa; Wu, Peggy A; Nambudiri, Vinod E

    2014-01-01

    Number 1 January 2014 Letter Chemical burn caused by topicalan unusually severe case of chemical burn following garlicirritant contact dermatitis, chemical burn, allium sativum

  18. Controlled Chemical Doping of Semiconductor Nanocrystals Using Redox Buffers

    E-Print Network [OSTI]

    Engel, Jesse H.

    2014-01-01

    Controlled Chemical Doping of Semiconductor Nanocrys- talsHerein, we demonstrate a chemical strategy for the con-dope the nanocrystal solid. Chemical doping methods reported

  19. Dissection of Plant Defense Mechanisms Using Chemical and Molecular Genomics

    E-Print Network [OSTI]

    Rodriguez-Salus, Melinda Sue

    2012-01-01

    of auxins by a chemical genomics approach." Journal ofadvances in chemical genomics." Current Medicinal Chemistrymolecular and chemical genomics." Phytopathology 97(7): S58-

  20. Modeling Exposure to Persistent Chemicals in Hazard and Risk Assessment

    E-Print Network [OSTI]

    Cowan-Ellsberry, Christina E.

    2010-01-01

    Chemicals in Hazard and Risk Assessment Christina E. Cowan-implications for chemical risk assessment. J Environ MonitJM. 2006. Screening level risk assessment model for chemical

  1. The Microscopic Linear Dynamics

    E-Print Network [OSTI]

    Penny, Will

    The Microscopic Brain Will Penny Linear Dynamics Exponentials Matrix Exponential Eigendecomposition References The Microscopic Brain Will Penny 7th April 2011 #12;The Microscopic Brain Will Penny Linear;The Microscopic Brain Will Penny Linear Dynamics Exponentials Matrix Exponential Eigendecomposition

  2. Categorical Introduction to Dynamical Systems Symbolic Dynamical Systems

    E-Print Network [OSTI]

    Kahng, Byung-Jay

    Categorical Introduction to Dynamical Systems Symbolic Dynamical Systems Symbolic Embedding Examples Results Embeddings in Symbolic Dynamical Systems Jonathan Jaquette Swarthmore College July 22, 2009 Jonathan Jaquette Embeddings in Symbolic Dynamical Systems #12;Categorical Introduction

  3. Intramolecular and nonlinear dynamics

    SciTech Connect (OSTI)

    Davis, M.J. [Argonne National Laboratory, IL (United States)

    1993-12-01

    Research in this program focuses on three interconnected areas. The first involves the study of intramolecular dynamics, particularly of highly excited systems. The second area involves the use of nonlinear dynamics as a tool for the study of molecular dynamics and complex kinetics. The third area is the study of the classical/quantum correspondence for highly excited systems, particularly systems exhibiting classical chaos.

  4. TOWARD CHEMICAL CONSTRAINTS ON HOT JUPITER MIGRATION

    SciTech Connect (OSTI)

    Madhusudhan, Nikku; Amin, Mustafa A.; Kennedy, Grant M., E-mail: nmadhu@ast.cam.ac.uk [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom)

    2014-10-10

    The origin of hot Jupiters—gas giant exoplanets orbiting very close to their host stars—is a long-standing puzzle. Planet formation theories suggest that such planets are unlikely to have formed in situ but instead may have formed at large orbital separations beyond the snow line and migrated inward to their present orbits. Two competing hypotheses suggest that the planets migrated either through interaction with the protoplanetary disk during their formation, or by disk-free mechanisms such as gravitational interactions with a third body. Observations of eccentricities and spin-orbit misalignments of hot Jupiter systems have been unable to differentiate between the two hypotheses. In the present work, we suggest that chemical depletions in hot Jupiter atmospheres might be able to constrain their migration mechanisms. We find that sub-solar carbon and oxygen abundances in Jovian-mass hot Jupiters around Sun-like stars are hard to explain by disk migration. Instead, such abundances are more readily explained by giant planets forming at large orbital separations, either by core accretion or gravitational instability, and migrating to close-in orbits via disk-free mechanisms involving dynamical encounters. Such planets also contain solar or super-solar C/O ratios. On the contrary, hot Jupiters with super-solar O and C abundances can be explained by a variety of formation-migration pathways which, however, lead to solar or sub-solar C/O ratios. Current estimates of low oxygen abundances in hot Jupiter atmospheres may be indicative of disk-free migration mechanisms. We discuss open questions in this area which future studies will need to investigate.

  5. Protein Dynamics and Biocatalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The methods we use are based on the physical and chemical principles of statistical mechanics and quantum mechanics, and they are implemented in computational form using...

  6. From Single-Cell Genetic Architecture to Cell Population Dynamics: Quantitatively Decomposing the Effects of Different Population

    E-Print Network [OSTI]

    Bernard, Samuel

    From Single-Cell Genetic Architecture to Cell Population Dynamics: Quantitatively Decomposing Architecture Nikos V. Mantzaris Department of Chemical and Biomolecular Engineering, Rice University, Houston with positive feedback architecture. The framework consists of three vastly different mathematical formulations

  7. Introduction Dynamical properties of (-)-transformation Dynamical properties of

    E-Print Network [OSTI]

    /04/2010 Digital expansions, dynamics and tilings, Aussois Dynamical properties of the (-)-transformation 1/17 #12 of (-)-transformation Digital expansions, dynamics and tilings, Aussois Dynamical properties of the (-)-transformation 2/17 #12;Introduction Dynamical properties of (-)-transformation Introduction Digital expansions, dynamics

  8. Chemical heat pump and chemical energy storage system

    DOE Patents [OSTI]

    Clark, Edward C. (Woodinville, WA); Huxtable, Douglas D. (Bothell, WA)

    1985-08-06

    A chemical heat pump and storage system employs sulfuric acid and water. In one form, the system includes a generator and condenser, an evaporator and absorber, aqueous acid solution storage and water storage. During a charging cycle, heat is provided to the generator from a heat source to concentrate the acid solution while heat is removed from the condenser to condense the water vapor produced in the generator. Water is then stored in the storage tank. Heat is thus stored in the form of chemical energy in the concentrated acid. The heat removed from the water vapor can be supplied to a heat load of proper temperature or can be rejected. During a discharge cycle, water in the evaporator is supplied with heat to generate water vapor, which is transmitted to the absorber where it is condensed and absorbed into the concentrated acid. Both heats of dilution and condensation of water are removed from the thus diluted acid. During the discharge cycle the system functions as a heat pump in which heat is added to the system at a low temperature and removed from the system at a high temperature. The diluted acid is stored in an acid storage tank or is routed directly to the generator for reconcentration. The generator, condenser, evaporator, and absorber all are operated under pressure conditions specified by the desired temperature levels for a given application. The storage tanks, however, can be maintained at or near ambient pressure conditions. In another form, the heat pump system is employed to provide usable heat from waste process heat by upgrading the temperature of the waste heat.

  9. Cycle structure in SR and DSR graphs: implications for multiple equilibria and stable oscillation in chemical reaction networks

    E-Print Network [OSTI]

    Banaji, Murad

    2010-01-01

    Associated with a chemical reaction network is a natural labelled bipartite multigraph termed an SR graph, and its directed version, the DSR graph. These objects are closely related to Petri nets. The construction of SR and DSR graphs for chemical reaction networks is presented. Conclusions about asymptotic behaviour of the associated dynamical systems which can be drawn easily from the graphs are discussed. In particular, theorems on ruling out the possibility of multiple equilibria or stable oscillation in chemical reaction networks based on computations on SR/DSR graphs are presented. These include both published and new results. The power and limitations of such results are illustrated via several examples.

  10. Persistence of transition state structure in chemical reactions driven by fields oscillating in time

    E-Print Network [OSTI]

    Galen T. Craven; Thomas Bartsch; Rigoberto Hernandez

    2014-04-29

    Chemical reactions subjected to time-varying external forces cannot generally be described through a fixed bottleneck near the transition state barrier or dividing surface. A naive dividing surface attached to the instantaneous, but moving, barrier top also fails to be recrossing-free. We construct a moving dividing surface in phase space over a transition state trajectory. This surface is recrossing-free for both Hamiltonian and dissipative dynamics. This is confirmed even for strongly anharmonic barriers using simulation. The power of transition state theory is thereby applicable to chemical reactions and other activated processes even when the bottlenecks are time-dependent and move across space.

  11. Self-propelled motion of a fluid droplet under chemical reaction

    E-Print Network [OSTI]

    Shunsuke Yabunaka; Takao Ohta; Natsuhiko Yoshinaga

    2012-03-03

    We study self-propelled dynamics of a droplet due to a Marangoni effect and chemical reactions in a binary fluid with a dilute third component of chemical product which affects the interfacial energy of a droplet. The equation for the migration velocity of the center of mass of a droplet is derived in the limit of an infinitesimally thin inter- face. We found that there is a bifurcation from a motionless state to a propagating state of droplet by changing the strength of the Marangoni effect.

  12. 10 Questions for a Chemical Engineer: Alan Zacher | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 Questions for a Chemical Engineer: Alan Zacher 10 Questions for a Chemical Engineer: Alan Zacher March 24, 2011 - 1:39pm Addthis Chemical engineer Alan Zacher Chemical engineer...

  13. Heterodyne lidar for chemical sensing

    SciTech Connect (OSTI)

    Oldenborg, R. C. (Richard C.); Tiee, J. J. (Joe J.); Shimada, T. (Tsutomu); Wilson, C. W. (Carl W.); Remelius, D. K. (Dennis K.); Fox, Jay; Swim, Cynthia

    2004-01-01

    The overall objective is to assess the detection performance of LWIR (long wavelength infrared) coherent Lidar systems that potentially possess enhanced effluent detection capabilities. Previous work conducted by Los Alamos has demonstrated that infrared DIfferential Absorption Lidar (DIAL) is capable of detecting chemicals in plumes from long standoff ranges. Our DIAL approach relied on the reflectivity of topographical targets to provide a strong return signal. With the inherent advantage of applying heterodyne transceivers to approach single-photon detection in LWIR, it is projected that marked improvements in detection range or in spatial coverage can be attained. In some cases, the added photon detection sensitivity could be utilized for sensing 'soft targets', such as atmospheric and threat aerosols where return signal strength is drastically reduced, as opposed to topographical targets. This would allow range resolved measurements and could lead to the mitigation of the limiting source of noise due to spectral/spatial/temporal variability of the ground scene. The ability to distinguish normal variations in the background from true chemical signatures is crucial to the further development of sensitive remote chemical sensing technologies. One main difficulty in demonstrating coherent DIAL detection is the development of suitable heterodyne transceivers that can achieve rapid multi-wavelength tuning required for obtaining spectral signature information. LANL has recently devised a novel multi-wavelength heterodyne transceiver concept that addresses this issue. A 5-KHz prototype coherent CO{sub 2} transceiver has been constructed and is being now used to help address important issues in remote CBW agent standoff detection. Laboratory measurements of signal-to-noise ratio (SNR) will be reported. Since the heterodyne detection scheme fundamentally has poor shot-to-shot signal statistics, in order to achieve sensitive detection limits, favorable averaging statistics have to be validated. The baseline coherent DIAL detection sensitivity that can be achieved averaging multiple laser pulses and by comparisons of different wavelengths will be demonstrated. Factors that are presently limiting performance and attempts to circumvent these issues will be discussed.

  14. Exoplanetary Geophysics -- An Emerging Discipline

    E-Print Network [OSTI]

    Laughlin, Gregory

    2015-01-01

    Thousands of extrasolar planets have been discovered, and it is clear that the galactic planetary census draws on a diversity greatly exceeding that exhibited by the solar system's planets. We review significant landmarks in the chronology of extrasolar planet detection, and we give an overview of the varied observational techniques that are brought to bear. We then discuss the properties of the currently known distribution, using the mass-period diagram as a guide to delineating hot Jupiters, eccentric giant planets, and a third, highly populous, category that we term "ungiants", planets having masses less than 30 Earth masses and orbital periods less than 100 days. We then move to a discussion of the bulk compositions of the extrasolar planets. We discuss the long-standing problem of radius anomalies among giant planets, as well as issues posed by the unexpectedly large range in sizes observed for planets with masses somewhat greater than Earth's. We discuss the use of transit observations to probe the atmo...

  15. Work Force Discipline--Withdrawn

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-04-05

    Withdrawn 4-26-14. Significant changes from the Order include the deletion of material included in other documents such as statutes and Federal regulations. In addition, an updated Table of Penalties now includes Smoking, Cyber Security, Standards of Conduct or other Ethical Violations, and the incorporation of the Travel and Purchase Card Guidance dated January 2003.

  16. The 2011 Dynamics of Molecular Collisions Conference

    SciTech Connect (OSTI)

    Nesbitt, David J.

    2011-07-11

    The Dynamics of Molecular Collisions Conference focuses on all aspects of molecular collisions--experimental & theoretical studies of elastic, inelastic, & reactive encounters involving atoms, molecules, ions, clusters, & surfaces--as well as half collisions--photodissociation, photo-induced reaction, & photodesorption. The scientific program for the meeting in 2011 included exciting advances in both the core & multidisciplinary forefronts of the study of molecular collision processes. Following the format of the 2009 meeting, we also invited sessions in special topics that involve interfacial dynamics, novel emerging spectroscopies, chemical dynamics in atmospheric, combustion & interstellar environments, as well as a session devoted to theoretical & experimental advances in ultracold molecular samples. Researchers working inside & outside the traditional core topics of the meeting are encouraged to join the conference. We invite contributions of work that seeks understanding of how inter & intra-molecular forces determine the dynamics of the phenomena under study. In addition to invited oral sessions & contributed poster sessions, the scientific program included a formal session consisting of five contributed talks selected from the submitted poster abstracts. The DMC has distinguished itself by having the Herschbach Medal Symposium as part of the meeting format. This tradition of the Herschbach Medal was first started in the 2007 meeting chaired by David Chandler, based on a generous donation of funds & artwork design by Professor Dudley Herschbach himself. There are two such awards made, one for experimental & one for theoretical contributions to the field of Molecular Collision Dynamics, broadly defined. The symposium is always held on the last night of the meeting & has the awardees are asked to deliver an invited lecture on their work. The 2011 Herschbach Medal was dedicated to the contributions of two long standing leaders in Chemical Physics, Professor Yuan T. Lee & Professor George Schatz. Professor Lee’s research has been based on the development & use of advanced chemical kinetics & molecular beams to investigate & manipulate the behavior of fundamental chemical reactions. Lee’s work has been recognized by many awards, including the Nobel Prize for Chemistry in 1986, as well as Sloan Fellow, Dreyfus Scholar, Fellowship in the American Academy of Arts & Sciences, Fellowship in the American Physical Society, Guggenheim Fellow, Member National Academy of Sciences, Member Academia Sinica, E.O. Lawrence Award, Miller Professor, Berkeley, Fairchild Distinguished Scholar, Harrison Howe Award, Peter Debye Award, & the National Medal of Science. Lee also has served as the President of the Academia Sinica in Taiwan (ROC). Professor Schatz’s research group is interested in using theory & computation to describe physical phenomena in a broad range of applications relevant to chemistry, physics, biology & engineering. Among the types of applications that we interested are: optical properties of nanoparticles & nanoparticle assemblies; using theory to model polymer properties; DNA structure, thermodynamics & dynamics; modeling self assembly & nanopatterning; & gas phase reaction dynamics. Among his many awards & distinctions have been appointment as an Alfred P. Sloan Research Fellow, Camille & Henry Dreyfus Teacher-Scholar, the Fresenius Award, Fellow of the American Physical Society, the Max Planck Research Award, Fellowship in the American Association for the Advancement of Science, & election to the International Academy of Quantum Molecular Sciences & the American Academy of Arts & Sciences. Dr Schatz is also lauded for his highly successful work as Editor for the Journal of Physical Chemistry. We requested $10,000 from DOE in support of this meeting. The money was distributed widely among the student & post doctoral fellows & some used to attract the very best scientists in the field. The organizers were committed to encouraging women & minorities as well as encourage the field of Chemical Physics in scientific

  17. Chemical microreactor and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan

    2005-11-01

    A chemical microreactor suitable for generation of hydrogen fuel from liquid sources such as ammonia, methanol, and butane through steam reforming processes when mixed with an appropriate amount of water contains capillary microchannels with integrated resistive heaters to facilitate the occurrence of catalytic steam reforming reactions. One such microreactor employs a packed catalyst capillary microchannel and at least one porous membrane. Another employs a porous membrane with a large surface area or a porous membrane support structure containing a plurality of porous membranes having a large surface area in the aggregate, i.e., greater than about 1 m.sup.2 /cm.sup.3. The packed catalyst capillary microchannels, porous membranes and porous membrane support structures may be formed by a variety of methods.

  18. Vertical flow chemical detection portal

    DOE Patents [OSTI]

    Linker, Kevin L. (Albuquerque, NM); Hannum, David W. (Albuquerque, NM); Conrad, Frank James (Russellville, SC)

    1999-01-01

    A portal apparatus for screening objects or persons for the presence of trace amounts of chemical substances such as illicit drugs or explosives. The apparatus has a test space, in which a person may stand, defined by two generally upright sides spanned by a horizontal transom. One or more fans in the transom generate a downward air flow (uni-directional) within the test space. The air flows downwardly from a high pressure upper zone, past the object or person to be screened. Air moving past the object dislodges from the surface thereof both volatile and nonvolatile particles of the target substance. The particles are entrained into the air flow which continues flowing downward to a lower zone of reduced pressure, where the particle-bearing air stream is directed out of the test space and toward preconcentrator and detection components. The sides of the portal are specially configured to partially contain and maintain the air flow.

  19. Vertical flow chemical detection portal

    DOE Patents [OSTI]

    Linker, K.L.; Hannum, D.W.; Conrad, F.J.

    1999-06-22

    A portal apparatus is described for screening objects or persons for the presence of trace amounts of chemical substances such as illicit drugs or explosives. The apparatus has a test space, in which a person may stand, defined by two generally upright sides spanned by a horizontal transom. One or more fans in the transom generate a downward air flow (uni-directional) within the test space. The air flows downwardly from a high pressure upper zone, past the object or person to be screened. Air moving past the object dislodges from the surface thereof both volatile and nonvolatile particles of the target substance. The particles are entrained into the air flow which continues flowing downward to a lower zone of reduced pressure, where the particle-bearing air stream is directed out of the test space and toward preconcentrator and detection components. The sides of the portal are specially configured to partially contain and maintain the air flow. 3 figs.

  20. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-11-24

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  1. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-06-23

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  2. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77379)

    1987-01-01

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing he evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  3. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77389)

    1987-01-01

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  4. CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics

    SciTech Connect (OSTI)

    Kee, R.J.; Rupley, F.M.; Meeks, E.; Miller, J.A.

    1996-05-01

    This document is the user`s manual for the third-generation CHEMKIN package. CHEMKIN is a software package whose purpose is to facilitate the formation, solution, and interpretation of problems involving elementary gas-phase chemical kinetics. It provides a flexible and powerful tool for incorporating complex chemical kinetics into simulations of fluid dynamics. The package consists of two major software components: an Interpreter and a Gas-Phase Subroutine Library. The Interpreter is a program that reads a symbolic description of an elementary, user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Gas-Phase Subroutine Library. This library is a collection of about 100 highly modular FORTRAN subroutines that may be called to return information on equations of state, thermodynamic properties, and chemical production rates. CHEMKIN-III includes capabilities for treating multi-fluid plasma systems, that are not in thermal equilibrium. These new capabilities allow researchers to describe chemistry systems that are characterized by more than one temperature, in which reactions may depend on temperatures associated with different species; i.e. reactions may be driven by collisions with electrons, ions, or charge-neutral species. These new features have been implemented in such a way as to require little or no changes to CHEMKIN implementation for systems in thermal equilibrium, where all species share the same gas temperature. CHEMKIN-III now has the capability to handle weakly ionized plasma chemistry, especially for application related to advanced semiconductor processing.

  5. Do open clusters have distinguishable chemical signatures?

    E-Print Network [OSTI]

    Blanco-Cuaresma, S; Heiter, U

    2015-01-01

    Past studies have already shown that stars in open clusters are chemically homogeneous (e.g. De Silva et al. 2006, 2007 and 2009). These results support the idea that stars born from the same giant molecular cloud should have the same chemical composition. In this context, the chemical tagging technique was proposed by Freeman et al. 2002. The principle is to recover disrupted stellar clusters by looking only to the stellar chemical composition. In order to evaluate the feasibility of this approach, it is necessary to test if we can distinguish between stars born from different molecular clouds. For this purpose, we studied the chemical composition of stars in 32 old and intermediate-age open clusters, and we applied machine learning algorithms to recover the original cluster by only considering the chemical signatures.

  6. Electrostatic thin film chemical and biological sensor

    DOE Patents [OSTI]

    Prelas, Mark A. (Columbia, MO); Ghosh, Tushar K. (Columbia, MO); Tompson, Jr., Robert V. (Columbia, MO); Viswanath, Dabir (Columbia, MO); Loyalka, Sudarshan K. (Columbia, MO)

    2010-01-19

    A chemical and biological agent sensor includes an electrostatic thin film supported by a substrate. The film includes an electrostatic charged surface to attract predetermined biological and chemical agents of interest. A charge collector associated with said electrostatic thin film collects charge associated with surface defects in the electrostatic film induced by the predetermined biological and chemical agents of interest. A preferred sensing system includes a charge based deep level transient spectroscopy system to read out charges from the film and match responses to data sets regarding the agents of interest. A method for sensing biological and chemical agents includes providing a thin sensing film having a predetermined electrostatic charge. The film is exposed to an environment suspected of containing the biological and chemical agents. Quantum surface effects on the film are measured. Biological and/or chemical agents can be detected, identified and quantified based on the measured quantum surface effects.

  7. Dynamic Response Optimization of Complex Multibody Systems in a Penalty Formulation using Adjoint Sensitivity

    E-Print Network [OSTI]

    Yitao Zhu; Daniel Dopico; Corina Sandu; Adrian Sandu

    2014-10-30

    Multibody dynamics simulations are currently widely accepted as valuable means for dynamic performance analysis of mechanical systems. The evolution of theoretical and computational aspects of the multibody dynamics discipline make it conducive these days for other types of applications, in addition to pure simulations. One very important such application is design optimization. A very important first step towards design optimization is sensitivity analysis of multibody system dynamics. Dynamic sensitivities are often calculated by means of finite differences. Depending of the number of parameters involved, this procedure can be computationally expensive. Moreover, in many cases, the results suffer from low accuracy when real perturbations are used. The main contribution to the state-of-the-art brought by this study is the development of the adjoint sensitivity approach of multibody systems in the context of the penalty formulation. The theory developed is demonstrated on one academic case study, a five-bar mechanism, and on one real-life system, a 14-DOF vehicle model. The five-bar mechanism is used to illustrate the sensitivity approach derived in this paper. The full vehicle model is used to demonstrate the capability of the new approach developed to perform sensitivity analysis and gradient-based optimization for large and complex multibody systems with respect to multiple design parameters.

  8. Studying the Solar System's Chemical Recipe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    published work, the group performed VUV experiments on sulfur, using the results to build a model of chemical evolution in the primitive solar nebula that could yield the...

  9. Solutia: Massachusetts Chemical Manufacturer Uses SECURE Methodology...

    Broader source: Energy.gov (indexed) [DOE]

    plant-wide energy assessment conducted at the Solutia Inc. chemical production facility in Springfield, Massachusetts. The assessment focused on finding ways to reduce the plant's...

  10. Chemical Sciences Division | Advanced Materials |ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analysis, chemical imaging, neutron science, polymer science, and interfacial science. Theory is closely integrated with materials synthesis and characterization to gain new...

  11. Chemical Sciences, Geosciences, & Biosciences Program | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences, Geosciences, and Biosciences Program The Department of Energy's Office of Basic Energy Sciences' Chemical Sciences, Geosciences and Biosciences (CSGB) activities at...

  12. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Kim, Duck O.

    Biological Safety Officer Ergonomic Specialist 2723 Radiation Safety 2250 Facilities Management Office 2125. ANNUAL REVIEW AND EVALUATION OF EFFECTIVENESS OF THE CHEMICAL HYGIENE PLAN 9. HAZARD COMMUNICATION PLAN

  13. Alumni & Industry Magazine Chemical Engineering & Applied Chemistry

    E-Print Network [OSTI]

    Prodiæ, Aleksandar

    grease, waste animal fats, recycled veg- etable oils and agricultural seed oils into biodiesel. BioxAlumni & Industry Magazine Chemical Engineering & Applied Chemistry University of Toronto Volume 10

  14. Microbend fiber-optic chemical sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    2002-01-01

    A microbend fiber-optic chemical sensor for detecting chemicals in a sample, and a method for its use, is disclosed. The sensor comprises at least one optical fiber having a microbend section (a section of small undulations in its axis), for transmitting and receiving light. In transmission, light guided through the microbend section scatters out of the fiber core and interacts, either directly or indirectly, with the chemical in the sample, inducing fluorescence radiation. Fluorescence radiation is scattered back into the microbend section and returned to an optical detector for determining characteristics of the fluorescence radiation quantifying the presence of a specific chemical.

  15. CHEMICAL ENGINEERING 2012-2014 CATALOG

    E-Print Network [OSTI]

    Texas at Austin, University of

    Semester Semester Hours CH 302, Principles of Chemistry II ...........................................3 CH...........................4 CHE 372, Chemical Reactor Analysis and Design....................3 American History

  16. Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    Broader source: Energy.gov [DOE]

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

  17. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  18. Integrated Chemical Geothermometry System for Geothermal Exploration

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

  19. Chemical and Materials Sciences Building | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modern laboratory and office space for ORNL researchers who are studying and developing materials and chemical processes for energy-related technologies, including advanced...

  20. Studying the Solar System's Chemical Recipe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studying the Solar System's Chemical Recipe Print To study the origins of different isotope ratios among the elements that make up today's smorgasbord of planets, moons, comets,...

  1. Department of Chemical and Biological Engineering

    E-Print Network [OSTI]

    Torquato, Salvatore

    Department of Chemical and Biological Engineering Undergraduate Handbook Academic Year 2014, pharmaceuticals, semiconductors, adhesives, biopolymers, artificial kidneys, oil refineries, solar panels

  2. Chemically stabilized ionomers containing inorganic fillers

    DOE Patents [OSTI]

    Roelofs, Mark Gerrit

    2013-12-31

    Ionomeric polymers that are chemically stabilized and contain inorganic fillers are prepared, and show reduced degradation. The ionomers care useful in membranes and electrochemical cells.

  3. ORISE: Chemical Stockpile Emergency Preparedness Program Exercise...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exercise Trending Tool ORISE-developed tool improves information sharing between Chemical Stockpile Emergency Preparedness Program partners The Oak Ridge Institute for Science and...

  4. ORISE: Chemical Stockpile Emergency Preparedness Program Exercise...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Stockpile Emergency Preparedness Program Exercise Training and Analysis Tool Training Tool Improves Information Sharing Between CSEPP and its Response Partners In 2006,...

  5. Evaluation Of Chemical Geothermometers For Calculating Reservoir...

    Open Energy Info (EERE)

    Evaluation Of Chemical Geothermometers For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  6. Methods and compounds for chemical ligation

    DOE Patents [OSTI]

    Church, George M.; Sismour, A. Michael

    2013-07-09

    Compositions and methods for chemical ligation are provided. Methods for nucleic acid sequencing, nucleic acid assembly and nucleic acid synthesis are also provided.

  7. High Efficiency Modular Chemical Processes (HEMCP)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - ADVANCED MANUFACTURING OFFICE High Efficiency Modular Chemical Processes (HEMCP) Modular Process Intensification Framework for R&D Targets Advanced Manufacturing Office...

  8. Dynamical principles in neuroscience

    SciTech Connect (OSTI)

    Rabinovich, Mikhail I.; Varona, Pablo; Selverston, Allen I.; Abarbanel, Henry D. I.

    2006-10-15

    Dynamical modeling of neural systems and brain functions has a history of success over the last half century. This includes, for example, the explanation and prediction of some features of neural rhythmic behaviors. Many interesting dynamical models of learning and memory based on physiological experiments have been suggested over the last two decades. Dynamical models even of consciousness now exist. Usually these models and results are based on traditional approaches and paradigms of nonlinear dynamics including dynamical chaos. Neural systems are, however, an unusual subject for nonlinear dynamics for several reasons: (i) Even the simplest neural network, with only a few neurons and synaptic connections, has an enormous number of variables and control parameters. These make neural systems adaptive and flexible, and are critical to their biological function. (ii) In contrast to traditional physical systems described by well-known basic principles, first principles governing the dynamics of neural systems are unknown. (iii) Many different neural systems exhibit similar dynamics despite having different architectures and different levels of complexity. (iv) The network architecture and connection strengths are usually not known in detail and therefore the dynamical analysis must, in some sense, be probabilistic. (v) Since nervous systems are able to organize behavior based on sensory inputs, the dynamical modeling of these systems has to explain the transformation of temporal information into combinatorial or combinatorial-temporal codes, and vice versa, for memory and recognition. In this review these problems are discussed in the context of addressing the stimulating questions: What can neuroscience learn from nonlinear dynamics, and what can nonlinear dynamics learn from neuroscience?.

  9. Chemical Engineering and Chemical Technology 1 Faculty of Engineering, Department of

    E-Print Network [OSTI]

    for planning, design and control of processes. The department offers world-class facilities for both research chemical synthesis and production. MEng in Chemical Engineering with a Year Abroad1 The MEng course

  10. Dynamic Instruction Fusion

    E-Print Network [OSTI]

    Lee, Ian

    2012-01-01

    SANTA CRUZ DYNAMIC INSTRUCTION FUSION A thesis submitted in4 2.2 Instruction Fusion & Complex10 3.1 Fusion Selection

  11. Elliptical Galaxy Dynamics

    E-Print Network [OSTI]

    David Merritt

    1998-11-06

    A review of elliptical galaxy dynamics, with a focus on nonintegrable models. Topics covered include torus construction; modelling axisymmetric galaxies; triaxiality; collisionless relaxation; and collective instabilities.

  12. CHINESE JOURNAL OF CHEMICAL PHYSICS VOLUME 21, NUMBER 4 AUGUST 27, 2008 Vibrational Spectra and Adsorption of Trisiloxane Superspreading

    E-Print Network [OSTI]

    Liu, Shilin

    CHINESE JOURNAL OF CHEMICAL PHYSICS VOLUME 21, NUMBER 4 AUGUST 27, 2008 ARTICLE Vibrational Spectra, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences hydrophobic surfaces [2]. One of the com- Also graduate student of the Graduate University of the Chinese

  13. THE JOURNAL OF CHEMICAL PHYSICS 140, 144702 (2014) Theory of third-order spectroscopic methods to extract detailed molecular

    E-Print Network [OSTI]

    Fayer, Michael D.

    2014-01-01

    THE JOURNAL OF CHEMICAL PHYSICS 140, 144702 (2014) Theory of third-order spectroscopic methods to extract detailed molecular orientational dynamics for planar surfaces and other uniaxial systems Jun) experiments. In this article we provide a model-independent theory to extract orientational correlation

  14. Origin of Cosmic Chemical Abundances

    E-Print Network [OSTI]

    Maio, Umberto

    2015-01-01

    Cosmological N-body hydrodynamic computations following atomic and molecular chemistry (e$^-$, H, H$^+$, H$^-$, He, He$^+$, He$^{++}$, D, D$^+$, H$_2$, H$_2^+$, HD, HeH$^+$), gas cooling, star formation and production of heavy elements (C, N, O, Ne, Mg, Si, S, Ca, Fe, etc.) from stars covering a range of mass and metallicity are used to explore the origin of several chemical abundance patterns and to study both the metal and molecular content during simulated galaxy assembly. The resulting trends show a remarkable similarity to up-to-date observations of the most metal-poor damped Lyman-$\\alpha$ absorbers at redshift $z\\gtrsim 2$. These exhibit a transient nature and represent collapsing gaseous structures captured while cooling is becoming effective in lowering the temperature below $\\sim 10^4\\,\\rm K$, before they are disrupted by episodes of star formation or tidal effects. Our theoretical results agree with the available data for typical elemental ratios, such as [C/O], [Si/Fe], [O/Fe], [Si/O], [Fe/H], [O/...

  15. 2005 Chemical Reactions at Surfaces

    SciTech Connect (OSTI)

    Cynthia M. Friend

    2006-03-14

    The Gordon Research Conference (GRC) on 2005 Chemical Reactions at Surfaces was held at Ventura Beach Marriott, Ventura California from February 13, 2005 through February 18, 2005. The Conference was well-attended with 124 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. In designing the formal speakers program, emphasis was placed on current unpublished research and discussion of the future target areas in this field. There was a conscious effort to stimulate lively discussion about the key issues in the field today. Time for formal presentations was limited in the interest of group discussions. In order that more scientists could communicate their most recent results, poster presentation time was scheduled. Attached is a copy of the formal schedule and speaker program and the poster program. In addition to these formal interactions, 'free time' was scheduled to allow informal discussions. Such discussions are fostering new collaborations and joint efforts in the field.

  16. Queuing models System dynamics models

    E-Print Network [OSTI]

    Glushko, Robert J.

    "procure") raw materials (chemicals, ores, grains, ...) or components Transform the materials or assemble

  17. Entropy production for mechanically or chemically driven biomolecules

    E-Print Network [OSTI]

    Tim Schmiedl; Thomas Speck; Udo Seifert

    2006-01-27

    Entropy production along a single stochastic trajectory of a biomolecule is discussed for two different sources of non-equilibrium. For a molecule manipulated mechanically by an AFM or an optical tweezer, entropy production (or annihilation) occurs in the molecular conformation proper or in the surrounding medium. Within a Langevin dynamics, a unique identification of these two contributions is possible. The total entropy change obeys an integral fluctuation theorem and a class of further exact relations, which we prove for arbitrarily coupled slow degrees of freedom including hydrodynamic interactions. These theoretical results can therefore also be applied to driven colloidal systems. For transitions between different internal conformations of a biomolecule involving unbalanced chemical reactions, we provide a thermodynamically consistent formulation and identify again the two sources of entropy production, which obey similar exact relations. We clarify the particular role degenerate states have in such a description.

  18. Chemical Sputtering of Fusion Plasma-Facing Carbon Surfaces

    SciTech Connect (OSTI)

    Krstic, Predrag; Stuart, Steven J.; Reinhold, Carlos O.

    2006-12-01

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. We perform molecular dynamics simulations of the chemical sputtering of deuterated amorphous carbon surfaces irradiated by low energy deuterium atoms and molecules ( ? 30 eV/D). Particular attention was paid to the proper preparation of the surfaces, as well as to the internal (rovibrational) state of impinging molecules. Sputtered hydrocarbons are analyzed with respect to their mass, kinetic energy and angular distribution. The sputtering yields are in good agreement with recent experimental results.

  19. Safety Topic Chemical Hood General purpose: prevent exposure to toxic, irritating, or noxious chemical

    E-Print Network [OSTI]

    Cohen, Robert E.

    Safety Topic ­ Chemical Hood General purpose: prevent exposure to toxic, irritating, or noxious chemical vapors and gases. A face velocity of 100 feet per minute (fpm) provides efficient vapor capture the better. (T) (F) A chemical hood can be used for storage of volatile, flammable, or odiferous materials

  20. Chemical engineers design, control and optimize large-scale chemical, physicochemical and

    E-Print Network [OSTI]

    Rohs, Remo

    Introduction to Separation Processes (3, Sp) Use of equilibrium phase relations and principles of material by petition only. 405 Applications of Probability and Statistics for Chemical Engineers (3, Fa) Principles 226. #12;41 CHEMICAL & MATERIALS SCIENCE 442 Chemical Reactor Analysis (4, Fa) Basic concepts