Sample records for discharge hid mercury

  1. Electrodeless HID lamp study. Final report. [High intensity discharge

    SciTech Connect (OSTI)

    Anderson, J.M.; Johnson, P.D.; Jones, C.E.; Rautenberg, T.H.

    1985-01-01T23:59:59.000Z

    High intensity discharge lamps excited by solenoidal electric fields (SEF/HID) were examined for their ability to give high brightness, high efficacy and good color. Frequency of operation was 13.56 MHz (ISM Band) and power to the lamp plasma ranged from about 400 to 1000 W. Radio frequency transformers with air cores and with air core complemented by ferrite material in the magnetic path were used to provide the voltage for excitation. Electrical properties of the matching network and the lamp plasma were measured or calculated and total light from the lamp was measured by an integrating sphere. Efficacies calculated from measurement were found to agree well with the positive column efficacies of conventional HID lamps containing only mercury, and with additives of sodium, thallium, and scandium iodide. Recommendations for future work are given.

  2. Study of high frequency & low frequency electronic ballasts for HID lamps

    E-Print Network [OSTI]

    Peng, Hua

    1997-01-01T23:59:59.000Z

    High-intensity discharge (HID) lamp electronic ballasting is receiving increasing attention in the recent years as low wattage HID lighting systems are finding indoor applications. Advantages of high frequency electronic ballast for HID lamps...

  3. MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM

    SciTech Connect (OSTI)

    V.K. Mathur

    2003-02-01T23:59:59.000Z

    In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

  4. Groundwater Discharge of Mercury to California Coastal Waters

    E-Print Network [OSTI]

    Flegal, Russell; Paytan, Adina; Black, Frank

    2009-01-01T23:59:59.000Z

    R. 2009. Submarine groundwater discharge of total mercuryof nutrient-enriched fresh groundwater at Stinson Beach,Priya Ganguli collects groundwater at Elkhorn Slough. Coal-

  5. Max Tech and Beyond: High-Intensity Discharge Lamps

    SciTech Connect (OSTI)

    Scholand, Michael

    2012-04-01T23:59:59.000Z

    High-intensity discharge (HID) lamps are most often found in industrial and commercial applications, and are the light source of choice in street and area lighting, and sports stadium illumination. HID lamps are produced in three types - mercury vapor (MV), high pressure sodium (HPS) and metal halide (MH). Of these, MV and MH are considered white-light sources (although the MV exhibits poor color rendering) and HPS produces a yellow-orange color light. A fourth lamp, low-pressure sodium (LPS), is not a HID lamp by definition, but it is used in similar applications and thus is often grouped with HID lamps. With the notable exception of MV which is comparatively inefficient and in decline in the US from both a sales and installed stock point of view; HPS, LPS and MH all have efficacies over 100 lumens per watt. The figure below presents the efficacy trends over time for commercially available HID lamps and LPS, starting with MV and LPS in 1930's followed by the development of HPS and MH in the 1960's. In HID lamps, light is generated by creating an electric arc between two electrodes in an arc tube. The particles in the arc are partially ionized, making them electrically conductive, and a light-emitting 'plasma' is created. This arc occurs within the arc tube, which for most HID lamps is enclosed within an evacuated outer bulb that thermally isolates and protects the hot arc tube from the surroundings. Unlike a fluorescent lamp that produces visible light through down-converting UV light with phosphors, the arc itself is the light source in an HID lamp, emitting visible radiation that is characteristic of the elements present in the plasma. Thus, the mixture of elements included in the arc tube is one critical factor determining the quality of the light emitted from the lamp, including its correlated color temperature (CCT) and color rendering index (CRI). Similar to fluorescent lamps, HID lamps require a ballast to start and maintain stable operating conditions, and this necessitates additional power beyond that used by the lamp itself. HID lamps offer important advantages compared to other lighting technologies, making them well suited for certain applications. HID lamps can be very efficient, have long operating lives, are relatively temperature-insensitive and produce a large quantity of light from a small package. For these reasons, HID lamps are often used when high levels of illumination are required over large areas and where operating and maintenance costs must be kept to a minimum. Furthermore, if the installation has a significant mounting height, high-power HID lamps can offer superior optical performance luminaires, reducing the number of lamps required to illuminate a given area. The indoor environments best suited to HID lamps are those with high ceilings, such as those commonly found in industrial spaces, warehouses, large retail spaces, sports halls and large public areas. Research into efficacy improvements for HID lighting technologies has generally followed market demand for these lamps, which is in decline for MV and LPS, has reached a plateau for HPS and is growing for MH. Several manufacturers interviewed for this study indicated that although solid-state lighting was now receiving the bulk of their company's R&D investment, there are still strong HID lamp research programs, which concentrate on MH technologies, with some limited amount of investment in HPS for specific niche applications (e.g., agricultural greenhouses). LPS and MV lamps are no longer being researched or improved in terms of efficacy or other performance attributes, although some consider MH HID lamps to be the next-generation MV lamp. Thus, the efficacy values of commercially available MV, LPS and HPS lamps are not expected to increase in the next 5 to 10 years. MH lamps, and more specifically, ceramic MH lamps are continuing to improve in efficacy as well as light quality, manufacturability and lamp life. Within an HID lamp, the light-producing plasma must be heated to sufficiently high temperatures to achieve high efficiencie

  6. Application of vane-type resonator to microwave powered electrodeless HID lamp

    SciTech Connect (OSTI)

    Hochi, Akira; Takeda, Mamoru

    1999-07-01T23:59:59.000Z

    A cavity resonator has been generally used as microwave applicator for an electrodeless high intensity discharge (HID) lamp. The size of a cavity resonator is determined by the wavelength of a microwave applied. For example, for a microwave of 2.45 GHz, an inner diameter of more than about 76 mm is necessary for obtaining a microwave resonant field, and then the size of a plasma arc capable of maintaining a stable discharge is experimentally limited at about 15 mm and above. Accordingly the microwave powered electrodeless HID lamp device using cavity resonator is inappropriate in applications where a point light source is required. A vane-type resonator is generally known as an anode of a magnetron, which decides the oscillation frequency of the magnetron. The authors used 3-D finite element method simulation for a design of a vane-type resonator with parabolic reflector to obtain a desired resonant frequency. According to the results of the simulation, the sizes of a 4-vanes resonator with the parabolic reflector were decided, and the resonator made of aluminum and copper was prepared. An electrodeless lamp with InBr and Ar gas enclosed in a spherical quartz glass tube having an inner diameter of about 4 mm was also prepared, and was set at center portion of the resonator. The total luminous flux was about 2,150 lm at microwave input of 27 W. Incidentally, the CRI and Tc for this lamp were 93 and 10,200 K, respectively. Thus, it becomes possible to efficiently couple microwave energy with a smaller-sized electrodeless HID lamp than conventional.

  7. T-547: Microsoft Windows Human Interface Device (HID) Vulnerability

    Broader source: Energy.gov [DOE]

    Microsoft Windows does not properly warn the user before enabling additional Human Interface Device (HID) functionality over USB, which allows user-assisted attackers to execute arbitrary programs via crafted USB data, as demonstrated by keyboard and mouse data sent by malware on a Smartphone that the user connected to the computer.

  8. HIGH INTENSITY DISCHARGE (HID) SOLID STATE BALLAST PROGRAM PHASE I FINAL REPORT

    E-Print Network [OSTI]

    Ailing, W.R.

    2013-01-01T23:59:59.000Z

    A trapazoid for each type and lamp wattage is published bylamp wattage for the core-coil ballast was measured with a dynamometer type

  9. HIGH INTENSITY DISCHARGE (HID) SOLID STATE BALLAST PROGRAM PHASE I FINAL REPORT

    E-Print Network [OSTI]

    Ailing, W.R.

    2013-01-01T23:59:59.000Z

    change in the output power for the solid state ballast asof the solid state ballast's constant output power withswitching power supplies such as the solid state ballast.

  10. Patterns of mercury and methylmercury bioaccumulation in fish species downstream of a long-term mercury-contaminated site in the lower Ebro River

    E-Print Network [OSTI]

    García-Berthou, Emili

    Patterns of mercury and methylmercury bioaccumulation in fish species downstream of a long that the highest biological impact attributable to mercury pollution occurred downstream of the discharge site mercury (THg) and methylmercury (MeHg) at the discharge site and downstream points. Multiple

  11. Plasma spectroscopic study of an electrodeless HID lamp containing Tl and Zn

    SciTech Connect (OSTI)

    Takeda, Mamoru; Horii, Shigeru; Hochi, Akira [Matsushita Electric Industrial Co., Ltd., Kyoto (Japan). Lighting Research Lab.

    1996-12-31T23:59:59.000Z

    Recently the electrodeless HID lamps excited by microwaves have been studied intensively. Tl is well known as a material having strong green emission lines. In this study, Tl spectra excited by microwaves were reported in the cases of Tl only and Tl + Zn. Using the Elenbaas`s method of high pressure Hg lamp, the cause of Tl continuous spectrum was examined. From the ratio of radiative intensities of two lines, an average arc temperature in the bulb was estimated. Then excitation level of the continuous emission spectrum near the 600nm wavelength was calculated from the dependence of the radiative intensities on these arc temperatures.

  12. Apparatus for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

    1988-01-01T23:59:59.000Z

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  13. Environmental and health aspects of lighting: Mercury

    SciTech Connect (OSTI)

    Clear, R.; Berman, S.

    1993-07-01T23:59:59.000Z

    Most discharge lamps, including fluorescent lamps, metal halide lamps, and high pressure sodium lamps, contain Mercury, a toxic chemical. Lighting professionals need to be able to respond to questions about the direct hazards of Mercury from accidentally breaking lamps, and the potential environmental hazards of lamp operation and disposal. We calculated the exposures that could occur from an accidental breakage of lamps. Acute poisoning appears almost impossible. Under some circumstances a sealed environment, such as a space station, could be contaminated enough to make it unhealthy for long-term occupation. Mercury becomes a potential environmental hazard after it becomes methylated. Mercury is methylated in aquatic environments, where it may accumulate in fish, eventually rendering them toxic to people and other animals. Lighting causes Mercury to enter the environment directly from lamp disposal, and indirectly from power plant emissions. The environmental tradeoffs between incandescent and discharge lamps depend upon the amounts released by these two sources, their local concentrations, and their probabilities of being methylated. Indirect environmental effects of lighting also include the release of other heavy metals (Cadmium, Lead and Arsenic), and other air pollutants and carbon dioxide that are emitted by fossil fuel power plants. For a given light output, the level of power plant emissions depends upon the efficacy of the light source, and is thus much larger for incandescent lamps than for fluorescent or discharge lamps. As disposal and control technologies change the relative direct and indirect emissions from discharge and incandescent lamps will change.

  14. Increased Mercury Bioaccumulation Follows Water Quality Improvement

    SciTech Connect (OSTI)

    Bogle, M.A.; Peterson, M.J.; Smith, J.G.; Southworth, G.R.

    1999-09-15T23:59:59.000Z

    Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new waste treatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury increased over the period during which ecological metrics indicated improved water quality. In the system where waterborne mercury concentrations were at background levels, increased mercury bioaccumulation was probably a result of reduced aqueous selenium concentrations; however, the mechanisms for increased mercury accumulation in the other two streams remain under investigation. In each of the three systems, reduced inputs of metals and inorganic anions was followed by improvements in the health of aquatic invertebrate communities. However, this reduction in risk to aquatic invertebrates was accompanied by increased risk to humans and piscivorous wildlife related to increased mercury concentrations in fish.

  15. Filter for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucestor, MA)

    1989-01-01T23:59:59.000Z

    A filter for enriching the .sup.196 Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The .sup.196 Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter.

  16. Mercury contamination extraction

    DOE Patents [OSTI]

    Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

    2009-09-15T23:59:59.000Z

    Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

  17. IEEE Power Electronics Specialists Conference, PESC-97, 39-45, St. Louis, 1997. A MHz Electronic Ballast for Automotive-Type HID Lamps

    E-Print Network [OSTI]

    Ballast for Automotive-Type HID Lamps Michael Gulko and Sam Ben-Yaakov* Power Electronics Laboratory lamps designated for automotive headlight applications was investigated theoretically, by simulation and experimentally. The study reveals that a based ballast (CS-PPRI) complies with the automotive requirement of very

  18. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

    1995-01-01T23:59:59.000Z

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  19. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04T23:59:59.000Z

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  20. High intensity discharge device containing oxytrihalides

    DOE Patents [OSTI]

    Lapatovich, W.P.; Keeffe, W.M.; Liebermann, R.W.; Maya, J.

    1987-06-09T23:59:59.000Z

    A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO[sub 2], with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube. 7 figs.

  1. Mercury in the environment

    ScienceCinema (OSTI)

    Idaho National Laboratory - Mike Abbott

    2010-01-08T23:59:59.000Z

    Abbott works for Idaho National Laboratory as an environmental scientist. Using state-of-thescienceequipment, he continuously samples the air, looking for mercury. In turn, he'll analyzethis long-term data and try to figure out the mercury's point of or

  2. Neutrino Factory Mercury Vessel

    E-Print Network [OSTI]

    McDonald, Kirk

    Neutrino Factory Mercury Vessel: Initial Cooling Calculations V. Graves Target Studies Nov 15, 2012 #12;2 Managed by UT-Battelle for the U.S. Department of Energy Cooling Calculations 15 Nov 2012 Target · Separates functionality, provides double mercury containment, simplifies design and remote handling · Each

  3. FINAL REPORT ON THE AQUATIC MERCURY ASSESSMENT STUDY

    SciTech Connect (OSTI)

    Halverson, N

    2008-09-30T23:59:59.000Z

    In February 2000, the United States Environmental Protection Agency (EPA) Region 4 issued a proposed Total Maximum Daily Load (TMDL) for total mercury in the middle and lower Savannah River. The initial TMDL, which would have imposed a 1 ng/l mercury limit for discharges to the middle/lower Savannah River, was revised to 2.8 ng/l in the final TMDL released in February 2001. The TMDL was intended to protect people from the consumption of contaminated fish, which is the major route of mercury exposure to humans. The most bioaccumulative form of mercury is methylmercury, which is produced in aquatic environments by the action of microorganisms on inorganic mercury. Because of the environmental and economic significance of the mercury discharge limits that would have been imposed by the TMDL, the Savannah River Site (SRS) initiated several studies concerning: (1) mercury in SRS discharges, SRS streams and the Savannah River, (2) mercury bioaccumulation factors for Savannah River fish, (3) the use of clams to monitor the influence of mercury from tributary streams on biota in the Savannah River, and (4) mercury in rainwater falling on the SRS. The results of these studies are presented in detail in this report. The first study documented the occurrence, distribution and variation of total and methylmercury at SRS industrial outfalls, principal SRS streams and the Savannah River where it forms the border with the SRS. All of the analyses were performed using the EPA Method 1630/31 ultra low-level and contaminant-free techniques for measuring total and methylmercury. Total mercury at National Pollutant Discharge Elimination System (NPDES) outfalls ranged from 0.31-604 ng/l with a mean of 8.71 ng/l. Mercury-contaminated groundwater was the source for outfalls with significantly elevated mercury concentrations. Total mercury in SRS streams ranged from 0.95-15.7 ng/l. Mean total mercury levels in the streams varied from 2.39 ng/l in Pen Branch to 5.26 ng/l in Tims Branch. Methylmercury ranged from 0.002 ng/l in Upper Three Runs to 2.60 ng/l in Tims Branch. Total mercury in the Savannah River ranged from 0.62 ng/l to 43.9 ng/l, and methylmercury ranged from 0.036 ng/l to 7.54 ng/l. Both total and methylmercury concentrations were consistently high in the river near the mouth of Steel Creek. Total mercury was positively correlated with methylmercury (r = 0.88). Total mercury bound to particulates ranged from 41% to 57% in the river and from 28% to 90% in the streams. Particulate methylmercury varied from 9% to 37% in the river and from 6% to 79% in the streams. Small temporary pools in the Savannah River swamp area near and around Fourmile Branch had the highest concentrations observed in the Savannah River watershed, reaching 1,890 ng/l for total mercury and 34.0 ng/l for methylmercury. The second study developed a mercury bioaccumulation factor (BAF) for the Savannah River near SRS. A BAF is the ratio of the concentration of mercury in fish flesh to the concentration of mercury in the water. BAFs are important in the TMDL process because target concentrations for mercury in water are computed from BAFs. Mercury BAFs are known to differ substantially among fish species, water bodies, and possibly seasons. Knowledge of such variation is needed to determine a BAF that accurately represents average and extreme conditions in the water body under study. Analysis of fish tissue and aqueous methylmercury samples collected at a number of locations and over several seasons in a 110 km (68 mile) reach of the Savannah River demonstrated that BAFs for each species under study varied by factors of three to eight. Influences on BAF variability were location, habitat and season-related differences in fish mercury levels and seasonal differences in methylmercury levels in the water. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 10{sup 6} for largemouth bass, 1.4 x 10{sup 6} for sunfishes, and 2.5 x 10{sup 6} for white catfish. This study showed that determination of representative BAFs for large rivers requires the collect

  4. High pressure discharges in cavities formed by microfabrication techniques

    SciTech Connect (OSTI)

    Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J. [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)] [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)

    1997-07-01T23:59:59.000Z

    High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. {copyright} {ital 1997 American Institute of Physics.}

  5. Method and apparatus for monitoring mercury emissions

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Sappey, A.D.; Sagan, F.J.; Marmaro, R.W.; Wilson, K.G.

    1997-10-21T23:59:59.000Z

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber. 15 figs.

  6. Method and apparatus for monitoring mercury emissions

    DOE Patents [OSTI]

    Durham, Michael D. (Castle Rock, CO); Schlager, Richard J. (Aurora, CO); Sappey, Andrew D. (Golden, CO); Sagan, Francis J. (Lakewood, CO); Marmaro, Roger W. (Littleton, CO); Wilson, Kevin G. (Littleton, CO)

    1997-01-01T23:59:59.000Z

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

  7. Mercury CEM Calibration

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani; Susan S. Sorini

    2007-03-31T23:59:59.000Z

    The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005, requires that calibration of mercury continuous emissions monitors (CEMs) be performed with NIST-traceable standards. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The traceability protocol will be written by EPA. Traceability will be based on the actual analysis of the output of each calibration unit at several concentration levels ranging from about 2-40 ug/m{sup 3}, and this analysis will be directly traceable to analyses by NIST using isotope dilution inductively coupled plasma/mass spectrometry (ID ICP/MS) through a chain of analyses linking the calibration unit in the power plant to the NIST ID ICP/MS. Prior to this project, NIST did not provide a recommended mercury vapor pressure equation or list mercury vapor pressure in its vapor pressure database. The NIST Physical and Chemical Properties Division in Boulder, Colorado was subcontracted under this project to study the issue in detail and to recommend a mercury vapor pressure equation that the vendors of mercury vapor pressure calibration units can use to calculate the elemental mercury vapor concentration in an equilibrium chamber at a particular temperature. As part of this study, a preliminary evaluation of calibration units from five vendors was made. The work was performed by NIST in Gaithersburg, MD and Joe Rovani from WRI who traveled to NIST as a Visiting Scientist.

  8. Sources of Mercury to East Fork Poplar Creek Downstream from the Y-12 National Security Complex: Inventories and Export Rates

    SciTech Connect (OSTI)

    Southworth, George R [ORNL; Greeley Jr, Mark Stephen [ORNL; Peterson, Mark J [ORNL; Lowe, Kenneth Alan [ORNL; Ketelle, Richard H [ORNL; Floyd, Stephanie B [ORNL

    2010-02-01T23:59:59.000Z

    East Fork Poplar Creek (EFPC) in Oak Ridge, Tennessee, has been heavily contaminated with mercury (also referred to as Hg) since the 1950s as a result of historical activities at the U.S. Department of Energy (DOE) Y-12 National Security Complex (formerly the Oak Ridge Y-12 Plant and hereinafter referred to as Y-12). During the period from 1950 to 1963, spills and leaks of elemental mercury (Hg{sup 0}) contaminated soil, building foundations, and subsurface drainage pathways at the site, while intentional discharges of mercury-laden wastewater added 100 metric tons of mercury directly to the creek (Turner and Southworth 1999). The inventory of mercury estimated to be lost to soil and rock within the facility was 194 metric tons, with another estimated 70 metric tons deposited in floodplain soils along the 25 km length of EFPC (Turner and Southworth 1999). Remedial actions within the facility reduced mercury concentrations in EFPC water at the Y-12 boundary from > 2500 ng/L to about 600 ng/L by 1999 (Southworth et al. 2000). Further actions have reduced average total mercury concentration at that site to {approx}300 ng/L (2009 RER). Additional source control measures planned for future implementation within the facility include sediment/soil removal, storm drain relining, and restriction of rainfall infiltration within mercury-contaminated areas. Recent plans to demolish contaminated buildings within the former mercury-use areas provide an opportunity to reconstruct the storm drain system to prevent the entry of mercury-contaminated water into the flow of EFPC. Such actions have the potential to reduce mercury inputs from the industrial complex by perhaps as much as another 80%. The transformation and bioaccumulation of mercury in the EFPC ecosystem has been a perplexing subject since intensive investigation of the issue began in the mid 1980s. Although EFPC was highly contaminated with mercury (waterborne mercury exceeded background levels by 1000-fold, mercury in sediments by more than 2000-fold) in the 1980s, mercury concentrations in EFPC fish exceeded those in fish from regional reference sites by only a little more than 10-fold. This apparent low bioavailability of mercury in EFPC, coupled with a downstream pattern of mercury in fish in which mercury decreased in proportion to dilution of the upstream source, lead to the assumption that mercury in fish would respond to decreased inputs of dissolved mercury to the stream's headwaters. However, during the past two decades when mercury inputs were decreasing, mercury concentrations in fish in Lower EFPC (LEFPC) downstream of Y-12 increased while those in Upper EFPC (UEFPC) decreased. The key assumption of the ongoing cleanup efforts, and concentration goal for waterborne mercury were both called into question by the long-term monitoring data. The large inventory of mercury within the watershed downstream presents a concern that the successful treatment of sources in the headwaters may not be sufficient to reduce mercury bioaccumulation within the system to desired levels. The relative importance of headwater versus floodplain mercury sources in contributing to mercury bioaccumulation in EFPC is unknown. A mercury transport study conducted by the Tennessee Valley Authority (TVA) in 1984 estimated that floodplain sources contributed about 80% of the total annual mercury export from the EFPC system (ORTF 1985). Most of the floodplain inputs were associated with wet weather, high flow events, while much of the headwater flux occurred under baseflow conditions. Thus, day-to-day exposure of biota to waterborne mercury was assumed to be primarily determined by the Y-12 source. The objective of this study was to evaluate the results of recent studies and monitoring within the EFPC drainage with a focus on discerning the magnitude of floodplain mercury sources and how long these sources might continue to contaminate the system after headwater sources are eliminated or greatly reduced.

  9. Water displacement mercury pump

    DOE Patents [OSTI]

    Nielsen, Marshall G. (Woodside, CA)

    1985-01-01T23:59:59.000Z

    A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

  10. Enhanced mercury oxidation

    SciTech Connect (OSTI)

    Gretta, W.J.; Wu, S.; Kikkawa, H. [Hitachi Power Systems America, Basting Ridge, NJ (United States)

    2009-06-15T23:59:59.000Z

    A new catalyst offers a new way to enhance mercury control from bituminous coal-fired power plants. Hitachi has developed an SCR catalyst which satisfies high Hg{sup 0} oxidation and low SO{sub 2} oxidation requirements under high temperatures (716 to 770 F). This triple action catalysts, TRAC can significantly enhance mercury oxidation and reduce or eliminate the need for additional mercury control measures such as activated carbon injection. After laboratory testing, pilot-scale tests confirmed an activity of 1.4-1.7 times higher than that of conventional SCR catalyst. The new catalyst has been successfully applied in a commercial PRB-fired boiler without the need for halogens to be added to the fuel feed or flue gas. 2 figs.

  11. LONG-TERM CHANGES IN MERCURY CONCENTRATIONS IN FISH FROM THE MIDDLE SAVANNAH RIVER

    SciTech Connect (OSTI)

    Paller, M; Bill Littrell, B

    2007-01-02T23:59:59.000Z

    Total mercury levels were measured in largemouth bass (Micropterus salmoides), ''sunfishes'' (Lepomis spp)., and ''catfish'' (primarily Ameiurus spp.) from 1971 to 2004 in the middle reaches of the Savannah River, which drains the coastal plain of the southeastern U.S. Mercury levels were highest in 1971 but declined over the next ten years due to the mitigation of point sources of industrial pollution. Mercury levels began to increase in the 1980s as a possible consequence of mercury inputs from tributaries and associated wetlands where mercury concentrations were significantly elevated in water and fish. Mercury levels in Savannah River fish decreased sharply in 2001-2003 coincident with a severe drought in the Savannah River basin, but returned to previous levels in 2004 with the resumption of normal precipitation. Regression models showed that mercury levels in Savannah River fish changed significantly over time and were affected by river discharge. Despite temporal changes, there was little overall difference in Savannah River fish tissue mercury levels between 1971 and 2004.

  12. Wastewater Discharge Program (Maine)

    Broader source: Energy.gov [DOE]

    The wastewater discharge regulations require that a license be obtained for the discharge of wastewater to a stream, river, wetland, or lake of the state, or to the ocean. Typical discharges...

  13. Mercury Information Clearinghouse

    SciTech Connect (OSTI)

    Chad A. Wocken; Michael J. Holmes; Dennis L. Laudal; Debra F. Pflughoeft-Hassett; Greg F. Weber; Nicholas V. C. Ralston; Stanley J. Miller; Grant E. Dunham; Edwin S. Olson; Laura J. Raymond; John H. Pavlish; Everett A. Sondreal; Steven A. Benson

    2006-03-31T23:59:59.000Z

    The Canadian Electricity Association (CEA) identified a need and contracted the Energy & Environmental Research Center (EERC) to create and maintain an information clearinghouse on global research and development activities related to mercury emissions from coal-fired electric utilities. With the support of CEA, the Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates, and the U.S. Department of Energy (DOE), the EERC developed comprehensive quarterly information updates that provide a detailed assessment of developments in the various areas of mercury monitoring, control, policy, and research. A total of eight topical reports were completed and are summarized and updated in this final CEA quarterly report. The original quarterly reports can be viewed at the CEA Web site (www.ceamercuryprogram.ca). In addition to a comprehensive update of previous mercury-related topics, a review of results from the CEA Mercury Program is provided. Members of Canada's coal-fired electricity generation sector (ATCO Power, EPCOR, Manitoba Hydro, New Brunswick Power, Nova Scotia Power Inc., Ontario Power Generation, SaskPower, and TransAlta) and CEA, have compiled an extensive database of information from stack-, coal-, and ash-sampling activities. Data from this effort are also available at the CEA Web site and have provided critical information for establishing and reviewing a mercury standard for Canada that is protective of environment and public health and is cost-effective. Specific goals outlined for the CEA mercury program included the following: (1) Improve emission inventories and develop management options through an intensive 2-year coal-, ash-, and stack-sampling program; (2) Promote effective stack testing through the development of guidance material and the support of on-site training on the Ontario Hydro method for employees, government representatives, and contractors on an as-needed basis; (3) Strengthen laboratory analytical capabilities through analysis and quality assurance programs; and (4) Create and maintain an information clearinghouse to ensure that all parties can keep informed on global mercury research and development activities.

  14. Mercury control in 2009

    SciTech Connect (OSTI)

    Sjostrom, S.; Durham, M.; Bustard, J.; Martin, C. [ADA Environmental Solutions, Littleton, CO (United States)

    2009-07-15T23:59:59.000Z

    Although activated carbon injection (ACI) has been proven to be effective for many configurations and is a preferred option at many plants sufficient quantities of powdered activated coking (PAC) must be available to meet future needs. The authors estimate that upcoming federal and state regulations will result in tripling the annual US demand for activated carbon to nearly 1.5 billion lb from approximately 450 million lb. Rapid expansion of US production capacity is required. Many PAC manufacturers are discussing expansion of their existing production capabilities. One company, ADA Carbon Solutions, is in the process of constructing the largest activated carbon facility in North America to meet the future demand for PAC as a sorbent for mercury control. Emission control technology development and commercialization is driven by regulation and legislation. Although ACI will not achieve > 90% mercury control at every plant, the expected required MACT legislation level, it offers promise as a low-cost primary mercury control technology option for many configurations and an important trim technology for others. ACI has emerged as the clear mercury-specific control option of choice, representing over 98% of the commercial mercury control system orders to date. As state regulations are implemented and the potential for a federal rule becomes more imminent, suppliers are continuing to develop technologies to improve the cost effectiveness and limit the balance of plant impacts associated with ACI and are developing additional PAC production capabilities to ensure that the industry's needs are met. The commercialisation of ACI is a clear example of industry, through the dedication of many individuals and companies with support from the DOE and EPRI, meeting the challenge of developing cost-effectively reducing emissions from coal-fired power plants. 7 refs., 1 fig.

  15. Recovery of mercury from acid waste residues

    DOE Patents [OSTI]

    Greenhalgh, W.O.

    1987-02-27T23:59:59.000Z

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

  16. Mercury Strategic Plan Outfall 200 Mercury Treatment Facility

    Office of Environmental Management (EM)

    Partial LMR * Alpha-5 LMR & Bldg Characterization * S&M mercury removal * Hg waterfishsediment studies * Technology Development Plan * Debris treatability study * Fate and...

  17. Development of a real-time monitor of mercury in combustor flues based on Active Nitrogen Energy Transfer (ANET)

    SciTech Connect (OSTI)

    Piper, L.G.; Fraser, M.E.; Davis, S.J. [Physical Sciences, Inc., Andover, MA (United States)

    1995-12-31T23:59:59.000Z

    This paper reports preliminary results from a development program to design and field test a prototype instrument for real-time mercury detection in combustor flue gases. This system has sub parts-per-billion sensitivity for Hg detection, can differentiate elemental mercury from mercuric chloride, and has a high tolerance toward particulates. The five major systems (sampling, discharge, detection, calibration, and data acquisition and control) which comprise the instrument are described, and design and preliminary test results are outlined.

  18. Innovative Mercury Treatment Benefits Stream, Fish | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mercury Treatment Benefits Stream, Fish Innovative Mercury Treatment Benefits Stream, Fish October 1, 2012 - 12:00pm Addthis Oak Ridge scientists Kelly Roy, left, and Trent Jett...

  19. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2009-01-20T23:59:59.000Z

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  20. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, Shou-Heng (Kaohsiung, TW); Liu, Zhao-Rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2011-08-30T23:59:59.000Z

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  1. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Bejing, CN); Yan, Naiqiang (Burkeley, CA)

    2010-07-13T23:59:59.000Z

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  2. Method for mercury refinement

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-04-09T23:59:59.000Z

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  3. Apparatus for mercury refinement

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-07-16T23:59:59.000Z

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  4. Method for mercury refinement

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA); George, William A. (Rockport, MA)

    1991-01-01T23:59:59.000Z

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  5. Apparatus for mercury refinement

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA); George, William A. (Rockport, MA)

    1991-01-01T23:59:59.000Z

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  6. Neutrino Factory Mercury Flow Loop

    E-Print Network [OSTI]

    McDonald, Kirk

    ­ Could require double containment of mercury ­ Chase will certainly have a drain back into hot cell Decay 2010 #12;Hg Flow Overflow · Minimize pressure drops through piping Overflow Mercury Drain drops Gravity Drain Beam Dumptransitioning to 1 cm nozzle · Actual NF Hg inventory may reach SNS Gravity Drain

  7. Atmospheric Mercury: Emissions, Transport/Fate,

    E-Print Network [OSTI]

    , global...) Is "emissions trading" workable and ethical? Is the recently promulgated Clean Air Mercury

  8. Direct Discharge Permit (Vermont)

    Broader source: Energy.gov [DOE]

    A direct discharge permit is required if a project involves the discharge of pollutants to state waters. For generation purposes, this involves the withdrawal of surface water for cooling purposes...

  9. Evaluating Mercury Concentrations in Midwest Fish in Relationship to Mercury Emission Sources

    E-Print Network [OSTI]

    Robichaud, Jeffery

    2008-12-19T23:59:59.000Z

    based on Regions. (EPRI, 2006) Once mercury enters water via deposition (or runoff containing deposited mercury), mercury will either volatize into the atmosphere, settle into sediments or enter the food chain. It enters the food chain via...

  10. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13T23:59:59.000Z

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  11. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect (OSTI)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W. (Center for Nanoscale Materials); ( ES)

    2012-05-15T23:59:59.000Z

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  12. MERCURY STABILITY IN THE ENVIRONMENT

    SciTech Connect (OSTI)

    John H. Pavlish

    1999-07-01T23:59:59.000Z

    The 1990 Clean Air Act Amendments (CAAAs) require the U.S. Environmental Protection Agency (EPA) to determine whether the presence of mercury and 188 other trace substances, referred to as air toxics or hazardous air pollutants (HAPs), in the stack emissions from fossil fuel-fired electric utility power plants poses an unacceptable public health risk (1). The EPA's conclusions and recommendations were presented in two reports: Mercury Study Report to Congress and Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units-Final Report to Congress. The first congressional report addressed both human health and the environmental effects of anthropogenic mercury emissions, while the second report addressed the risk to public health posed by emissions of HAPs from steam electricity-generating units. The National Institute of Environmental Health Sciences is also required by the CAAAs to investigate mercury and determine a safe threshold level of exposure. Recently the National Academy of Sciences has also been commissioned by Congress to complete a report, based the available scientific evidence, regarding safe threshold levels of mercury exposure. Although the EPA reports did not state that mercury controls on coal-fired electric power stations should be required given the current state of the art, they did indicate that EPA views mercury as a potential threat to human health. It is likely that major sources of mercury emissions, including fossil-fired combustion systems, will be controlled at some point. In fact, municipal waste combustion units are already regulated. In anticipation of additional control measures, much research has been done (and continues) regarding the development of control technologies for mercury emitted from stationary sources to the atmosphere. Most approaches taken to date involve sorbent injection technologies or improve upon removal of mercury using existing technologies such as flue gas desulfurization scrubbers, fabric filters, and electrostatic precipitators. Depending on the fly ash chemistry and the form of mercury present in the flue gas, some of these existing technologies can be effective at capturing vapor-phase mercury from the flue gas stream. Although much research has been done on enhancing the removal of mercury from flue gas streams, little research has focused on what happens to the mercury when it is captured and converted and/or transferred to a solid or aqueous solution. The stability (or mobility) of mercury in this final process is critical and leads to the questions, What impact will the increased concentration of mercury have on utilization, disposal, and reuse? and Is the mercury removed from the flue gas really removed from the environment or rereleased at a later point? To help answer these questions, the Energy & Environmental Research Center (EERC) as part of the U.S. Department of Energy (DOE) Base Cooperative Agreement did a series of experiments using thermal desorption and leaching techniques. This report presents the results from these tests.

  13. Long-Term Management and Storage of Elemental Mercury | Department...

    Energy Savers [EERE]

    Mercury Long-Term Management and Storage of Elemental Mercury In addition to banning the export of elemental mercury from the United States as of January 1, 2013, the Mercury...

  14. Mercury in the Anthropocene Ocean

    E-Print Network [OSTI]

    Lamborg, Carl

    The toxic metal mercury is present only at trace levels in the ocean, but it accumulates in fish at concentrations high enough to pose a threat to human and environmental health. Human activity has dramatically altered the ...

  15. Oscillations in glow discharges

    E-Print Network [OSTI]

    Prickett, Tom

    1950-01-01T23:59:59.000Z

    1950 CONTENTS Introduction ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 1 I. Review of Plasma Oscillations in Gas Discharges ? . . 2 II. Review of Relaxation Processes in Gas Discharges ? . 13 III. Report of Laboratory Investigation... 179540 LIST OF FIGURES Figure Page 1. Sketch of Plasma Space in which Electrons are given Displacements in the X-direction ? ? ? ? ? ? 5 2* Early Circuit Arrangement of Discharge Study ? ? ? ? ? 19 3, Flow Diagram of the Experimental System...

  16. Mercury-contaminated sludge treatment by dredging in Minamata Bay

    SciTech Connect (OSTI)

    Yoshinaga, Kiyoto [Ministry of Transport, Niigata (Japan)

    1995-12-31T23:59:59.000Z

    To eradicate Minamata Disease, caused by the discharge of sewage containing methyl mercury and its accumulation in fish and shellfish through the food cycle, a large-scale sediment disposal project was conducted with special care taken to prevent new pollution resulting from the project itself. The basic approach to sediment disposal was to construct a highly watertight revetment to reclaim the inner area of the bay and then confine sediment dredged from the remaining contaminated area in the reclamation area through surface treatment. Before sediment disposal, boundary nets were installed to enclose the work area to prevent the mixing of contaminated and noncontaminated fish. Dredging work was successfully carried out by using four cutterless suction dredgers, newly developed in advance for minimizing resuspension of sediments. Dredged material was discharged into the reclamation area, filled up to sea level, and covered with a sandproof membrane, lightweight volcanic ash earth, and mountain soil.

  17. Mercury abatement report on the US Department of Energy Oak Ridge Y- 12 Plant for fiscal year 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    This Annual Mercury Abatement Report for fiscal year 1995 summarizes the status of activities and the levels of mercury contamination in East Fork Poplar Creek (EFPC) resulting from activities at the US Department of Energy`s Oak Ridge Y-12 Plant. The report outlines the status of the on-going project activities in support of project compliance, the results of the ongoing sampling and characterization efforts, the biological monitoring activities, and our conclusions relative to the progress in demonstrating compliance with the National Pollutant Discharge Elimination (NPDES) permit. Overall, the pace of mercury activities at the Y-12 Plant is ahead of the compliance schedules in the NPDES permit and new and exciting opportunities are being recognized for achieving additional mercury reductions. These opportunities were not felt to be achievable several years ago.

  18. Method for the removal and recovery of mercury

    DOE Patents [OSTI]

    Easterly, C.E.; Vass, A.A.; Tyndall, R.L.

    1997-01-28T23:59:59.000Z

    The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

  19. Longitudinal discharge laser electrodes

    DOE Patents [OSTI]

    Warner, B.E.; Miller, J.L.; Ault, E.R.

    1994-08-23T23:59:59.000Z

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window. 2 figs.

  20. Mercury bioaccumulation in Lavaca Bay, Texas

    E-Print Network [OSTI]

    Palmer, Sally Jo

    1992-01-01T23:59:59.000Z

    (waves), and human activities (dredging and shrimping) can potentially release mercury to the overlying water (LINDBERG and HARRISS, 1977; CRANSTON, 1976). The solubility, reactivity, and toxicity of mercury is dependent on its form. Divalent mercury... MERCURY BIOACCUMULATION IN LAVACA BAY, TEXAS A Thesis by SALLY JO PALMER Submitted to the Office of Graduate Studies of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1992 Major...

  1. REPLACE YOUR MERCURY THERMOMETERS BEFORE THEY BREAK!

    E-Print Network [OSTI]

    presents a hazard for faculty, staff, and students in laboratory areas? Mercury also presents a hazard mercury thermometers create hazardous waste that is costly to clean up and costly to dispose of. Other generating hazardous waste from spill clean-up. · Mercury is volatile at room temperature with vapors

  2. Apparatus for control of mercury

    DOE Patents [OSTI]

    Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH)

    2001-01-01T23:59:59.000Z

    A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

  3. Capacitor discharge pulse analysis.

    SciTech Connect (OSTI)

    Baker, Michael Sean; Griffiths, Stewart K.; Tanner, Danelle Mary

    2013-08-01T23:59:59.000Z

    Capacitors used in firing sets and other high discharge current applications are discharge tested to verify performance of the capacitor against the application requirements. Parameters such as capacitance, inductance, rise time, pulse width, peak current and current reversal must be verified to ensure that the capacitor will meet the application needs. This report summarizes an analysis performed on the discharge current data to extract these parameters by fitting a second-order system model to the discharge data and using this fit to determine the resulting performance metrics. Details of the theory and implementation are presented. Using the best-fit second-order system model to extract these metrics results in less sensitivity to noise in the measured data and allows for direct extraction of the total series resistance, inductance, and capacitance.

  4. Marine biogeochemistry of mercury

    SciTech Connect (OSTI)

    Gill, G.A.

    1986-01-01T23:59:59.000Z

    Noncontaminating sample collection and handling procedures and accurate and sensitive analysis methods were developed to measure sub-picomolar Hg concentrations in seawater. Reliable and diagnostic oceanographic Hg distributions were obtained, permitting major processes governing the marine biogeochemistry of Hg to be identified. Mercury concentrations in the northwest Atlantic, central Pacific, southeast Pacific, and Tasman Sea ranged from 0.5 to 12 pM. Vertical Hg distributions often exhibited a maximum within or near the main thermocline. At similar depths, Hg concentrations in the northwest Atlantic Ocean were elevated compared to the N. Pacific Ocean. This pattern appears to result from a combination of enhanced supply of Hg to the northwest Atlantic by rainfall and scavenging removal along deep water circulation pathways. These observations are supported by geochemical steady-state box modelling which predicts a relatively short mean residence time for Hg in the oceans; demonstrating the reactive nature of Hg in seawater and precluding significant involvement in nutrient-type recyclic. Evidence for the rapid removal of Hg from seawater was obtained at two locations. Surface seawater Hg measurements along 160/sup 0/ W (20/sup 0/N to 20/sup 0/S) showed a depression in the equatorial upwelling area which correlated well with the transect region exhibiting low /sup 234/Th//sup 238/U activity ratios. This relationship implies that Hg will be scavenged and removed from surface seawater in biologically productive oceanic zones. Further, a broad minimum in the vertical distribution of Hg was observed to coincide with the intense oxygen minimum zone in the water column in coastal waters off Peru.

  5. 5/23/13 EBSCOhost ehis.ebscohost.com.libproxy.mit.edu/ehost/delivery?sid=24f6d6e6-10b5-495d-90c9-221fc19a83fe%40sessionmgr114&vid=5&hid=107 1/2

    E-Print Network [OSTI]

    Deutch, John

    technological applications. Secretary of Energy James Watkins has argued that "it takes vision and courage-221fc19a83fe%40sessionmgr114&vid=5&hid=107 1/2 Database: Section: Record: 1 A supercollision of interests. By: Deutch, John M. Technology Review (00401692). Nov/Dec92, Vol. 95 Issue 8, p66. 1p. 1 Black

  6. Mercury emissions from municipal solid waste combustors

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

  7. Source-attribution for atmospheric mercury deposition: Where does the mercury in mercury deposition come from?

    E-Print Network [OSTI]

    ;13 #12;14 #12;15 #12;16 Estimated Speciation Profile for 1999 U.S. Atmospheric Anthropogenic Mercury speciation profile Even within a given source type, there can be big differences ­ depending on process type, fuels and raw materials, pollution control equipment, etc. #12;18 Estimated 1999 U.S. Atmospheric

  8. Source-apportionment for atmospheric mercury deposition: Where does the mercury in mercury deposition come from?

    E-Print Network [OSTI]

    (p) #12;For emissions of Hg(II) #12;Estimated Speciation Profile for 1999 U.S. Atmospheric Anthropogenic Mercury Emissions #12;Each type of source has a very different emissions speciation profile Even within a given source type, there can be big differences ­ depending on process type, fuels and raw materials

  9. Amended Silicated for Mercury Control

    SciTech Connect (OSTI)

    James Butz; Thomas Broderick; Craig Turchi

    2006-12-31T23:59:59.000Z

    Amended Silicates{trademark}, a powdered, noncarbon mercury-control sorbent, was tested at Duke Energy's Miami Fort Station, Unit 6 during the first quarter of 2006. Unit 6 is a 175-MW boiler with a cold-side electrostatic precipitator (ESP). The plant burns run-of-the-river eastern bituminous coal with typical ash contents ranging from 8-15% and sulfur contents from 1.6-2.6% on an as-received basis. The performance of the Amended Silicates sorbent was compared with that for powdered activated carbon (PAC). The trial began with a period of baseline monitoring during which no sorbent was injected. Sampling during this and subsequent periods indicated mercury capture by the native fly ash was less than 10%. After the baseline period, Amended Silicates sorbent was injected at several different ratios, followed by a 30-day trial at a fixed injection ratio of 5-6 lb/MMACF. After this period, PAC was injected to provide a comparison. Approximately 40% mercury control was achieved for both the Amended Silicates sorbent and PAC at injection ratios of 5-6 lbs/MMACF. Higher injection ratios did not achieve significantly increased removal. Similar removal efficiencies have been reported for PAC injection trials at other plants with cold-side ESPs, most notably for plants using medium to high sulfur coal. Sorbent injection did not detrimentally impact plant operations and testing confirmed that the use of Amended Silicates sorbent does not degrade fly ash quality (unlike PAC). The cost for mercury control using either PAC or Amended Silicates sorbent was estimated to be equivalent if fly ash sales are not a consideration. However, if the plant did sell fly ash, the effective cost for mercury control could more than double if those sales were no longer possible, due to lost by-product sales and additional cost for waste disposal. Accordingly, the use of Amended Silicates sorbent could reduce the overall cost of mercury control by 50% or more versus PAC for locations where fly ash is sold as a by-product.

  10. Mercury Replacement Program It is the policy of California State University, Fullerton to remove mercury containing

    E-Print Network [OSTI]

    de Lijser, Peter

    decomposes. As a liquid metal at room temperature, mercury has been widely used throughout industry. Man, smelting, scrap metal processing and incineration or land disposal of mercury products or waste. #12 occurring element. This silver-colored liquid metal can be found in rocks, soil and the ocean. Mercury can

  11. Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake

    E-Print Network [OSTI]

    Borguet, Eric

    promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

  12. anthropogenic mercury emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anthropogenic emission of mercury is directly adopted from global mercury emission inventory Pacyna et al., 2005. The anthropogenic emissions are shown in annual averaged...

  13. THE EFFECT OF MERCURY CONTROLS ON WALLBOARD MANUFACTURE

    SciTech Connect (OSTI)

    Sandra Meischen

    2004-07-01T23:59:59.000Z

    Pending EPA regulations may mandate 70 to 90% mercury removal efficiency from utility flue gas. A mercury control option is the trapping of oxidized mercury in wet flue gas desulfurization systems (FGD). The potential doubling of mercury in the FGD material and its effect on mercury volatility at temperatures common to wallboard manufacture is a concern that could limit the growing byproduct use of FGD material. Prediction of mercury fate is limited by lack of information on the mercury form in the FGD material. The parts per billion mercury concentrations prevent the identification of mercury compounds by common analytical methods. A sensitive analytical method, cold vapor atomic fluorescence, coupled with leaching and thermodecomposition methods were evaluated for their potential to identify mercury compounds in FGD material. The results of the study suggest that the mercury form is dominated by the calcium sulfate matrix and is probably associated with the sulfate form in the FGD material. Additionally, to determine the effect of high mercury concentration FGD material on wallboard manufacture, a laboratory FGD unit was built to trap the oxidized mercury generated in a simulated flue gas. Although the laboratory prepared FGD material did not contain the mercury concentrations anticipated, further thermal tests determined that mercury begins to evolve from FGD material at 380 to 390 F, consequently dropping the drying temperature should mitigate mercury evolution if necessary. Mercury evolution is also diminished as the weight of the wallboard sample increased. Consequently, mercury evolution may not be a significant problem in wallboard manufacture.

  14. EIS-0423: Storage and Management of Elemental Mercury | Department...

    Office of Environmental Management (EM)

    23: Storage and Management of Elemental Mercury EIS-0423: Storage and Management of Elemental Mercury Summary This EIS evaluates the environmental impacts associated with the...

  15. Mercury Emission Measurement at a CFB Plant

    SciTech Connect (OSTI)

    John Pavlish; Jeffrey Thompson; Lucinda Hamre

    2009-02-28T23:59:59.000Z

    In response to pending regulation to control mercury emissions in the United States and Canada, several projects have been conducted to perform accurate mass balances at pulverized coal (pc)-fired utilities. Part of the mercury mass balance always includes total gaseous mercury as well as a determination of the speciation of the mercury emissions and a concentration bound to the particulate matter. This information then becomes useful in applying mercury control strategies, since the elemental mercury has traditionally been difficult to control by most technologies. In this instance, oxidation technologies have proven most beneficial for increased capture. Despite many years of mercury measurement and control projects at pc-fired units, far less work has been done on circulating fluidized-bed (CFB) units, which are able to combust a variety of feedstocks, including cofiring coal with biomass. Indeed, these units have proven to be more problematic because it is very difficult to obtain a reliable mercury mass balance. These units tend to have very different temperature profiles than pc-fired utility boilers. The flexibility of CFB units also tends to be an issue when a mercury balance is determined, since the mercury inputs to the system come from the bed material and a variety of fuels, which can have quite variable chemistry, especially for mercury. In addition, as an integral part of the CFB operation, the system employs a feedback loop to circulate the bed material through the combustor and the solids collection system (the primary cyclone), thereby subjecting particulate-bound metals to higher temperatures again. Despite these issues, CFB boilers generally emit very little mercury and show good native capture. The Energy & Environmental Research Center is carrying out this project for Metso Power in order to characterize the fate of mercury across the unit at Rosebud Plant, an industrial user of CFB technology from Metso. Appropriate solids were collected, and flue gas samples were obtained using the Ontario Hydro method, mercury continuous emission monitors, and sorbent trap methods. In addition, chlorine and fluorine were determined for solids and in the flue gas stream. Results of this project have indicated a very good mercury mass balance for Rosebud Plant, indicating 105 {+-} 19%, which is well within acceptable limits. The mercury flow through the system was shown to be primarily in with the coal and out with the flue gas, which falls outside of the norm for CFB boilers.

  16. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2003-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  17. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2002-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  18. Mercury concentrations in Maine sport fishes

    SciTech Connect (OSTI)

    Stafford, C.P. [Univ. of Maine, Orono, ME (United States)] [Univ. of Maine, Orono, ME (United States); Haines, T.A. [Geological Survey, Orono, ME (United States)] [Geological Survey, Orono, ME (United States)

    1997-01-01T23:59:59.000Z

    To assess mercury contamination of fish in Maine, fish were collected from 120 randomly selected lakes. The collection goal for each lake was five fish of the single most common sport fish species within the size range commonly harvested by anglers. Skinless, boneless fillets of fish from each lake were composited, homogenized, and analyzed for total mercury. The two most abundant species, brook trout Salvelinus fontinalis and smallmouth bass Micropterus dolomieu, were also analyzed individually. The composite fish analyses indicate high concentrations of mercury, particularly in large and long-lived nonsalmonid species. Chain pickerel Esox niger, smallmouth bass, largemouth bass Micropterus salmoides, and white perch Morone americana had the highest average mercury concentrations, and brook trout and yellow perch Perca flavescens had the lowest. The mean species composite mercury concentration was positively correlated with a factor incorporating the average size and age of the fish. Lakes containing fish with high mercury concentrations were not clustered near known industrial or population centers but were commonest in the area within 150 km of the seacoast, reflecting the geographical distribution of species that contained higher mercury concentrations. Stocked and wild brook trout were not different in length or weight, but wild fish were older and had higher mercury concentrations. Fish populations maintained by frequent introductions of hatchery-produced fish and subject to high angler exploitation rates may consist of younger fish with lower exposure to environmental mercury and thus contain lower concentrations than wild populations.

  19. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01T23:59:59.000Z

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  20. Longitudinal discharge laser baffles

    DOE Patents [OSTI]

    Warner, B.E.; Ault, E.R.

    1994-06-07T23:59:59.000Z

    The IR baffles placed between the window and the electrode of a longitudinal discharge laser improve laser performance by intercepting off-axis IR radiation from the laser and in doing so reduce window heating and subsequent optical distortion of the laser beam. 1 fig.

  1. Water Pollutant Discharge Act (Illinois)

    Broader source: Energy.gov [DOE]

    The discharge of oil in quantities which exceed the standards adopted by the Pollution Control Board, or the discharge of other pollutants directly or indirectly into the waters is prohibited....

  2. Future trends in environmental mercury concentrations: implications

    E-Print Network [OSTI]

    's Integrated Global System Model. Through this integrated model, the Program seeks to: discover new and climate projections; critically and quantitatively analyze environmental management and policy proposals to growth in the legacy reservoirs of mercury in oceanic and terrestrial ecosystems. Seawater mercury

  3. MERCURY RELEASE FROM DISTURBED ANOXIC SOILS

    SciTech Connect (OSTI)

    Jaroslav Solc; Bethany A. Bolles

    2001-07-16T23:59:59.000Z

    The primary objectives of experiments conducted at the Energy & Environmental Research Center (EERC) were to provide information on the secondary release of mercury from contaminated anoxic sediments to an aqueous environment after disturbance/change of in situ physical conditions and to evaluate its migration and partitioning under controlled conditions, including implications of these processes for treatment of contaminated soils. Experimental work included (1) characterization of the mercury-contaminated sediment; (2) field bench-scale dredging simulation; (3) laboratory column study to evaluate a longer-term response to sediment disturbance; (4) mercury volatilization from sediment during controlled drying; (5) resaturation experiments to evaluate the potential for secondary release of residual mercury after disturbance, transport, drying, and resaturation, which simulate a typical scenario during soil excavation and transport to waste disposal facilities; and (6) mercury speciation and potential for methylation during column incubation experiments.

  4. Powerful glow discharge excilamp

    DOE Patents [OSTI]

    Tarasenko, Victor F. (Tomsk, RU); Panchenko, Aleksey N. (Tomsk, RU); Skakun, Victor S. (Tomsk, RU); Sosnin, Edward A. (Tomsk, RU); Wang, Francis T. (Danville, CA); Myers, Booth R. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01T23:59:59.000Z

    A powerful glow discharge lamp comprising two coaxial tubes, the outer tube being optically transparent, with a cathode and anode placed at opposite ends of the tubes, the space between the tubes being filled with working gas. The electrodes are made as cylindrical tumblers placed in line to one other in such a way that one end of the cathode is inserted into the inner tube, one end of the anode coaxially covers the end of the outer tube, the inner tube penetrating and extending through the anode. The increased electrodes' surface area increases glow discharge electron current and, correspondingly, average radiation power of discharge plasma. The inner tube contains at least one cooling liquid tube placed along the axis of the inner tube along the entire lamp length to provide cathode cooling. The anode has a circumferential heat extracting radiator which removes heat from the anode. The invention is related to lighting engineering and can be applied for realization of photostimulated processes under the action of powerful radiation in required spectral range.

  5. All mercury lamps contain small amounts of mercury. An electric current passes through the lamp and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our environment from heavy

    E-Print Network [OSTI]

    George, Steven C.

    and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our the environment by recycling universal wastes, contact EH&S at (949) 824-6200 or visit: www.ehs.uci.edu Mercury lamp recycling separates a number of materials for further use in new products. · The mercury is reused

  6. Potential for Increased Mercury Accumulation in the Estuary Food Web

    E-Print Network [OSTI]

    Davis, Jay A; Yee, Donald; Collins, Joshua N.; Schwarzbach, Steven E.; Luoma, Samuel N

    2003-01-01T23:59:59.000Z

    of mercury in the Patuxent River estuary. Biogeochemistrysalinity gradient in the Patuxent River estuary. These high

  7. Mercury capture by aerosol transformation in combustion environments. Appendix 5

    SciTech Connect (OSTI)

    NONE

    1997-02-01T23:59:59.000Z

    Aerosol transformation of elemental mercury by oxidizing mercury in the air is investigated in this study by varying temperature and residence time. The experimental results show that mercury oxidation is not important at the temperature range and time scale studied. The rate of mercury oxidation is too slow that the capture of mercury vapor by transforming it into mercury oxide in aerosol phase is not practical in real systems. Studies are needed for alternative approaches to capture mercury vapor such as the use of sorbent materials.

  8. The effect of the operation modes of a gas discharge low-pressure amalgam lamp on the intensity of generation of 185 nm UV vacuum radiation

    SciTech Connect (OSTI)

    Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute of High Temperatures (Russian Federation); Drozdov, L. A., E-mail: lit@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V. [ZAO LIT (Russian Federation); Kudryavtsev, N. N.; Sobur, D. A., E-mail: soburda@gmail.com [Moscow Institute for Physics and Technology (Russian Federation)

    2011-12-15T23:59:59.000Z

    The effect of the discharge current, mercury vapor pressure, and the inert gas pressure on the intensity and efficiency of the 185 nm line generation are considered. The spectra of the UV radiation (vacuum ultraviolet) transmission by protective coatings from the oxides of rare earth metals and aluminum are investigated.

  9. Treatment of mercury containing waste

    DOE Patents [OSTI]

    Kalb, Paul D. (Wading River, NY); Melamed, Dan (Gaithersburg, MD); Patel, Bhavesh R (Elmhurst, NY); Fuhrmann, Mark (Babylon, NY)

    2002-01-01T23:59:59.000Z

    A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

  10. Accumulation of mercury in selected plant species grown in soils contaminated with different mercury compounds

    SciTech Connect (OSTI)

    Su, Yi; Han, Fengxiang; Shiyab, Safwan; Chen, Jian; Monts, David L. [Institute for Clean Energy Technology (ICET), Mississippi State University, 205 Research Blvd, Starkville, MS 39759 (United States)

    2007-07-01T23:59:59.000Z

    The objective of our research is to screen and search for suitable plant species for phyto-remediation of mercury-contaminated soil. Currently our effort is specifically focused on mercury removal from the U.S. Department of Energy (DOE) sites, where mercury contamination is a major concern. In order to cost effectively implement mercury remediation efforts, it is necessary now to obtain an improved understanding of biological means of removing mercury and mercury compounds.. Phyto-remediation is a technology that uses various plants to degrade, extract, contain, or immobilize contaminants from soil and water. In particular, phyto-extraction is the uptake of contaminants by plant roots and translocation within the plants to shoots or leaves. Contaminants are generally removed by harvesting the plants. We have investigated phyto-extraction of mercury from contaminated soil by using some of the known metal-accumulating plants since no natural plant species with mercury hyper-accumulating properties has yet been identified. Different natural plant species have been studied for mercury uptake, accumulation, toxicity and overall mercury removal efficiency. Various mercury compounds, such as HgS, HgCl{sub 2}, and Hg(NO{sub 3}){sub 2}, were used as contaminant sources. Different types of soil were examined and chosen for phyto-remediation experiments. We have applied microscopy and diffuse reflectance spectrometry as well as conventional analytical chemistry to monitor the phyto-remediation processes of mercury uptake, translocation and accumulation, and the physiological impact of mercury contaminants on selected plant species. Our results indicate that certain plant species, such as beard grass (Polypogon monospeliensis), accumulated a very limited amount of mercury in the shoots (<65 mg/kg), even though root mercury accumulation is significant (maximum 2298 mg/kg). Consequently, this plant species may not be suitable for mercury phyto-remediation. Other plant species, such as Indian mustard (Brassica juncea), a well-studied metal accumulator, exhibited severe chlorosis symptoms during some experiments. Among all the plant species studied, Chinese brake fern (Pteris vittata) accumulated significant amount of mercury in both roots and shoots and hence may be considered as a potential candidate for mercury phyto-extraction. During one experiment, Chinese brake ferns accumulated 540 mg/kg and 1469 mg/kg in shoots after 18 days of growing in soils treated with 500 parts-per-million (ppm) and 1000 ppm HgCl{sub 2} powder, respectively; no visual stress symptoms were observed. We also studied mercury phyto-remediation using aged soils that contained HgS, HgCl{sub 2}, or Hg(NO{sub 3}){sub 2}. We have found that up to hundreds of ppm mercury can be accumulated in the roots of Indian mustard plants grown with soil contaminated by mercury sulfide; HgS is assumed to be the most stable and also the predominant mercury form in flood plain soils. We have also started to investigate different mercury uptake mechanisms, such as root uptake of soil contaminant and foliar mercury accumulation from ambient air. We have observed mercury translocation from roots to shoot for Chinese fern and two Indian mustard varieties. (authors)

  11. PERIODIC GLOW DISCHARGE REPORT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeeding access toTest andOptimize832 2.860SelectedGLOW DISCHARGE REPORT

  12. Fish mercury distribution in Massachusetts, USA lakes

    SciTech Connect (OSTI)

    Rose, J.; Hutcheson, M.S.; West, C.R.; Pancorbo, O.; Hulme, K.; Cooperman, A.; DeCesare, G.; Isaac, R.; Screpetis, A.

    1999-07-01T23:59:59.000Z

    The sediment, water, and three species of fish from 24 of Massachusetts' (relatively) least-impacted water bodies were sampled to determine the patterns of variation in edible tissue mercury concentrations and the relationships of these patterns to characteristics of the water, sediment, and water bodies (lake, wetland, and watershed areas). Sampling was apportioned among three different ecological subregions and among lakes of differing trophic status. The authors sought to partition the variance to discover if these broadly defined concepts are suitable predictors of mercury levels in fish. Average muscle mercury concentrations were 0.15 mg/kg wet weight in the bottom-feeding brown bullheads (Ameriurus nebulosus); 0.31 mg/kg in the omnivorous yellow perch (Perca flavescens); and 0.39 mg/kg in the predaceous largemouth bass (Micropterus salmoides). Statistically significant differences in fish mercury concentrations between ecological subregions in Massachusetts, USA, existed only in yellow perch. The productivity level of the lakes (as deduced from Carlson's Trophic Status Index) was not a strong predictor of tissue mercury concentrations in any species. pH was a highly (inversely) correlated environmental variable with yellow perch and brown bullhead tissue mercury. Largemouth bass tissue mercury concentrations were most highly correlated with the weight of the fish (+), lake size (+), and source area sizes (+). Properties of individual lakes appear more important for determining fish tissue mercury concentrations than do small-scale ecoregional differences. Species that show major mercury variation with size or trophic level may not be good choices for use in evaluating the importance of environmental variables.

  13. 5/23/13 EBSCOhost ehis.ebscohost.com.libproxy.mit.edu/ehost/delivery?sid=24f6d6e6-10b5-495d-90c9-221fc19a83fe%40sessionmgr114&vid=5&hid=107 1/2

    E-Print Network [OSTI]

    Deutch, John

    -221fc19a83fe%40sessionmgr114&vid=5&hid=107 1/2 Database: Section: Record: 1 Cool thoughts on global warming. By: Deutch, J.M. Technology Review (00401692). May/Jun92, Vol. 95 Issue 4, p73. 1p. 1 Black on actions-such as those encouraging energy efficiency-that cost little and that have other benefits besides

  14. 5/23/13 EBSCOhost ehis.ebscohost.com.libproxy.mit.edu/ehost/delivery?sid=24f6d6e6-10b5-495d-90c9-221fc19a83fe%40sessionmgr114&vid=7&hid=107 1/2

    E-Print Network [OSTI]

    Deutch, John

    strike plan, and the number and types of nuclear delivery systems required to meet future security needs power. U.S. nuclear forces can deter aggression in unstable regions of the world. Saddam Hussein hasd6e6-10b5-495d-90c9-221fc19a83fe%40sessionmgr114&vid=7&hid=107 2/2 hard-line leadership of China

  15. 10.1177/0270467603259787ARTICLEBULLETIN OF SCIENCE, TECHNOLOGY & SOCIETY / October 2003Roe / FISHING FOR IDENTITY Fishing for Identity: Mercury Contamination

    E-Print Network [OSTI]

    Delaware, University of

    of mercury in the United States. During 1999, total mercury emis- sions from power plant emissions exceeded (HG0 ), inorganic mercury (HG2+ ), and methyl mercury (MeHg), methyl mercury poses the greatest threat

  16. Interim Results from a Study of the Impacts of Tin (II) Based Mercury Treatment in a Small Stream Ecosystem: Tims Branch, Savannah River Site

    SciTech Connect (OSTI)

    Looney, Brian [Savannah River National Laboratory (SRNL); BryanJr., Larry [Savannah River Ecology Laboratory; Mathews, Teresa J [ORNL; Peterson, Mark J [ORNL; Roy, W Kelly [ORNL; Jett, Robert T [ORNL; Smith, John G [ORNL

    2012-03-01T23:59:59.000Z

    A research team is assessing the impacts of an innovative mercury treatment system in Tims Branch, a small southeastern stream. The treatment system, installed in 2007, reduces and removes inorganic mercury from water using tin(II) (stannous) chloride addition followed by air stripping. The system results in discharge of inorganic tin to the ecosystem. This screening study is based on historical information combined with measurements of contaminant concentrations in water, fish, sediment, biofilms and invertebrates. Initial mercury data indicate that first few years of mercury treatment resulted in a significant decrease in mercury concentration in an upper trophic level fish, redfin pickerel, at all sampling locations in the impacted reach. For example, the whole body mercury concentration in redfin pickerel collected from the most impacted pond decreased approximately 72% between 2006 (pre-treatment) and 2010 (post-treatment). Over this same period, mercury concentrations in the fillet of redfin pickerel in this pond were estimated to have decreased from approximately 1.45 {micro}g/g (wet weight basis) to 0.45 {micro}g/g - a decrease from 4.8x to 1.5x the current EPA guideline concentration for mercury in fillet (0.3 {micro}g/g). Thermodynamic modeling, scanning electron microscopy, and other sampling data for tin suggest that particulate tin (IV) oxides are a significant geochemical species entering the ecosystem with elevated levels of tin measured in surficial sediments and biofilms. Detectable increases in tin in sediments and biofilms extended approximately 3km from the discharge location. Tin oxides are recalcitrant solids that are relatively non-toxic and resistant to dissolution. Work continues to develop and validate methods to analyze total tin in the collected biota samples. In general, the interim results of this screening study suggest that the treatment process has performed as predicted and that the concentration of mercury in upper trophic level fish, as a surrogate for all of the underlying transport and transformation processes in a complex ecosystem, has declined as a direct result of the elimination of inorganic mercury inputs. Inorganic tin released to the ecosystem has been found in compartments where particles accumulate with notable levels measured in biofilms.

  17. Determination of the spatial characteristics of an RF electrodeless discharge by the method of emission tomography

    SciTech Connect (OSTI)

    Denisova, N. V. [Russian Academy of Sciences, Institute of Theoretical and Applied Mechanics, Siberian Division (Russian Federation); Revalde, G.; Skudra, A. [University of Latvia, Institute of Atomic physics and Spectroscopy (Latvia)

    2006-11-15T23:59:59.000Z

    The spatial distribution of the density of mercury atoms in the 7{sup 3}S state in a spherical RF electrode-less gas-discharge lamp is reconstructed by the method of emission tomography. The local values of the corresponding emission coefficients, which are proportional to the density of mercury atoms in the 7{sup 3}S state, are determined from integral (over the plasma volume) measurements of the lamp radiation at a wavelength of 546.1 nm with the help of an algorithm based on the maximum entropy method. The results obtained show that, for all of the operating modes under study, the profile of the density of mercury atoms in the 7{sup 3}S state has a minimum in the center of the lamp and a maximum near its wall. At a generator current of 100 mA and cold-spot temperature of 41 deg. C, the density of mercury atoms in the 7{sup 3}S state is observed to drop substantially both in the center of the lamp and near its wall, the density in the center being reduced to almost zero. An explanation of this phenomenon is proposed.

  18. Mercury sorbent delivery system for flue gas

    SciTech Connect (OSTI)

    Klunder; ,Edgar B. (Bethel Park, PA)

    2009-02-24T23:59:59.000Z

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  19. Advances in Lighting

    E-Print Network [OSTI]

    Tumber, A. J.

    1981-01-01T23:59:59.000Z

    colour rendition. The quartz-halogen incandescent lam s operate at higher temperatures, and have a somewhat higher efficacy, but they are rarely used except for special applicati ns. 3-2 High Intensity Discharge Lamps. Mercury is the grandfather... of the H.I.D. lamps. Its blue-green light, has been used almost exclusively for streetlighti and, often with colour-improving phospho it is still being used in industrial and commercial applications. Reactor-type ballasted mercury lamps can now...

  20. VEE-0020- In the Matter of Mercury Fuel Service, Inc.

    Broader source: Energy.gov [DOE]

    On April 9, 1996, Mercury Fuel Service, Inc. (Mercury) of Waterbury, Connecticut, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE)....

  1. Removal of mercury from coal via a microbial pretreatment process

    DOE Patents [OSTI]

    Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

    2011-08-16T23:59:59.000Z

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  2. Dissolved gaseous mercury behavior in shallow water estuaries

    E-Print Network [OSTI]

    Landin, Charles Melchor

    2009-05-15T23:59:59.000Z

    The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While...

  3. Nested-grid simulation of mercury over North America

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    Chemistry and Physics Nested-grid simulation of mercury overY. Zhang et al. : Nested-grid simulation of mercury overand Chen, S. -Y. : Plume-in-grid modeling of atmospheric

  4. Seismic effects of the Caloris basin impact, Mercury

    E-Print Network [OSTI]

    Lü, Jiangning

    2011-01-01T23:59:59.000Z

    Striking geological features on Mercury's surface have been linked to tectonic disruption associated with the Caloris impact and have the potential to provide information on the interior structure of Mercury. The unusual ...

  5. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2005-12-30T23:59:59.000Z

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

  6. Capillary discharge source

    DOE Patents [OSTI]

    Bender, III, Howard Albert

    2003-11-25T23:59:59.000Z

    Debris generation from an EUV electric discharge plasma source device can be significantly reduced or essentially eliminated by encasing the electrodes with dielectric or electrically insulating material so that the electrodes are shielded from the plasma, and additionally by providing a path for the radiation to exit wherein the electrodes are not exposed to the area where the radiation is collected. The device includes: (a) a body, which is made of an electrically insulating material, that defines a capillary bore that has a proximal end and a distal end and that defines at least one radiation exit; (b) a first electrode that defines a first channel that has a first inlet end that is connected to a source of gas and a first outlet end that is in communication with the capillary bore, wherein the first electrode is positioned at the distal end of the capillary bore; (c) a second electrode that defines a second channel that has a second inlet end that is in communication with the capillary bore and an outlet end, wherein the second electrode is positioned at the proximal end of the capillary bore; and (d) a source of electric potential that is connected across the first and second electrodes, wherein radiation generated within the capillary bore is emitted through the at least one radiation exit and wherein the first electrode and second electrode are shielded from the emitted radiation.

  7. Wetting of mercury electrode by crude oil in surfactant solutions

    SciTech Connect (OSTI)

    Kuvshinov, V.A.; Altumina, L.K.; Genkina, L.F.

    1985-09-01T23:59:59.000Z

    A study has been made of electrosurface phenomena in the system consisting of crude oil, mercury, and a surfactant solution. The type of relationship between the wetting of mercury by oil in surfactant solutions and the electric potential of the mercury has been determined. Feasibility has been demonstrated for the use of the mercury/oil/surfactant solution system as a model in studying the oil-displacing capabilities of various surfactants.

  8. DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site Is Preferred for Long-Term Mercury Storage

    Broader source: Energy.gov [DOE]

    WASHINGTON – The Department of Energy has prepared a Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement to analyze the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven locations

  9. Optical frequency standards based on mercury and aluminum ions

    E-Print Network [OSTI]

    Optical frequency standards based on mercury and aluminum ions W. M. Itano, J. C. Bergquist, A-16 . Keywords: aluminum, atomic clocks, frequency standards, ion traps, mercury 1. INTRODUCTION Optical frequency standards based on the mercury ion and, more recently, the aluminum ion are under devel- opment

  10. Core-mantle interactions for Mercury

    E-Print Network [OSTI]

    Lemaitre, B Noyelles J Dufey A

    2010-01-01T23:59:59.000Z

    Mercury is the target of two space missions: MESSENGER (NASA) which orbit insertion is planned for March 2011, and ESA/JAXA BepiColombo, that should be launched in 2014. Their instruments will observe the surface of the planet with a high accuracy (about 1 arcsec for BepiColombo), what motivates studying its rotation. Mercury is assumed to be composed of a rigid mantle and an at least partially molten core. We here study the influence of the core-mantle interactions on the rotation perturbed by the solar gravitational interaction, by modeling the core as an ellipsoidal cavity filled with inviscid fluid of constant uniform density and vorticity. We use both analytical (Lie transforms) and numerical tools to study this rotation, with different shapes of the core. We express in particular the proper frequencies of the system, because they characterize the response of Mercury to the different solicitations, due to the orbital motion of Mercury around the Sun. We show that the longitudinal motion of Mercury is not...

  11. Mercury in shallow Savannah River Plant soil

    SciTech Connect (OSTI)

    Carlton, W.H.; Price, V.; Cook, J.R.

    1988-10-01T23:59:59.000Z

    Soil concentrations of adsorbed mercury at 999 sites at the Savannah River Plant (SRP) were determined by Microseeps Limited of Indianola, PA. The sites were in and around the 643-C Burial Ground, at the Savannah River Swamp adjacent to TNX Area, and at a background area. The Burial Ground was chosen as a test site because of a history of disposal of radioactive mercury there prior to 1968. Extremely low traces of mercury have been detected in the water table beneath the Burial Ground. Although the mercury concentrations at the majority of these sites are at background levels, several areas appear to be anomalously high. In particular, an area of large magnitude anomaly was found in the northwest part of the Burial Ground. Three other single point anomalies and several other areas of more subtle but consistently high values were also found. Several sites with anomalous mercury levels were found in an area of the Savannah River flood plain adjacent to TNX Area.

  12. Groundwater Discharge Permit and Registration (New Hampshire)

    Broader source: Energy.gov [DOE]

    The Groundwater Discharge Permitting and Registration Program seeks to protect groundwater quality by establishing standards, criteria, and procedures for wastewater discharges. The program...

  13. Industrial Discharge Permits (District of Columbia)

    Broader source: Energy.gov [DOE]

    All businesses and government agencies discharging process wastewater to the public sewer system must report their activities to DC Water's Pretreatment Center. Wastewater discharge permits are...

  14. Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and

    E-Print Network [OSTI]

    Baker, Chris I.

    Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium labeled for shipment to a recycling plant for mercury, glass and aluminum recovery. The beneficial re can be recycled infinitely without losing its purity or strength. While the primary end product

  15. Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle*

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle-1062 The absorption of elemental Hg vapor into aqueous solution containing Hg(II) was measured in a stirred cell at 25 °C. For mercury absorption in Hg(II) obtained by HgCl2 injection, the presence of HNO3 greatly

  16. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01T23:59:59.000Z

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  17. Geochemical, Genetic, and Community Controls on Mercury

    SciTech Connect (OSTI)

    Wall, Judy D.

    2014-11-10T23:59:59.000Z

    The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

  18. Emerging technologies and approaches to minimize discharges into Lake Michigan, phase 2 module 4 report.

    SciTech Connect (OSTI)

    Negri, M.C.; Gillenwater, P.; Urgun-Demirtas, M.; Nnanna, G.; Yu, J.; Jannotta, I, (Energy Systems); (Purdue University Calumet)

    2012-04-19T23:59:59.000Z

    The Great Lakes Initiative (GLI) established the new water quality-based discharge criteria for mercury (Hg), thereby increasing the need for many municipal and industrial wastewater treatment plants in the region to lower the mercury in their effluents. Information on deployable technologies to satisfy these requirements for industrial and municipal dischargers in the Great lakes region is scarce. Therefore, BP funded Purdue University Calumet and Argonne to identify deployable Hg removal technologies to meet the GLI discharge criterion at its Whiting Refinery in Indiana. The joint PUC/Argonne project was divided into 2 phases. Results from Phase I and Phase II Modules 1-3 have been previously reported. This report summarizes the work done in Phase 3 Module 4, which consisted of the pilot scale testing of Hg removal technologies previously selected in Module 3. The pilot testing was an Argonne/PUC jointly directed project that was hosted at and funded by the BP refinery in Whiting, IN. As two organizations were involved in data analysis and interpretation, this report combines two independent sets of evaluations of the testing that was done, prepared respectively by Argonne and Purdue. Each organization retains sole responsibility for its respective analysis conclusions and recommendations. Based on Module 3 bench testing with pre-Effluent To Lake (pre-ETL) and clarifier effluent (CE) samples from the Whiting refinery, three different technologies were chosen for pilot testing: (1) Ultrafiltration (using GE ZeeWeed(reg sign) Technology, 0.04 {mu}m pore size and made up of PVDF) for particulate mercury removal; (2) Adsorption using Mersorb(reg sign) LW, a sulfur-impregnated activated carbon, for dissolved mercury removal if present and (3) The Blue PRO(reg sign) reactive filtration process for both particulate and dissolved (if present) mercury removal. The ultrafiltration and the Blue PRO(reg sign) reactive filtration pilot studies were done simultaneously at the BP Whiting refinery using a slipstream of wastewater taken just prior to the Effluent to lake (pre-ETL) outfall. It was the intention of this pilot testing to demonstrate proof of concept, i.e. can the discharge limits obtained at bench scale be consistently met at the pilot scale. Although Mersorb(reg sign) LW was selected for dissolved mercury removal testing, this technology was not pilot tested because of a lack of dissolved mercury in the test wastewater during the pilot study. The overall objective of this pilot testing was to demonstrate the effectiveness of the tested technologies with continuous and varying feed conditions to meet the GLI criterion (1.3 ppt). Optimization for full-scale design was outside of the scope of this work. In addition to demonstrating whether the Hg criterion can be met, information on residue generation rate, frequency of backwashing and other maintenance issues were collected to better understand the implications for a full-scale system.

  19. Phytoremediation of ionic and methyl mercury pollution

    SciTech Connect (OSTI)

    Meagher, R.B.

    1998-06-01T23:59:59.000Z

    'The long-term objective of the research is to manipulate single-gene traits into plants, enabling them to process heavy metals and remediate heavy-metal pollution by resistance, sequestration, removal, and management of these contaminants. The authors are focused on mercury pollution as a case study of this plant genetic engineering approach. The working hypothesis behind this proposal was that transgenic plants expressing both the bacterial organo mercury lyase (merB) and the mercuric ion reductase gene (merA) will: (A) remove the mercury from polluted sites and (B) prevent methyl mercury from entering the food chain. The results from the research are so positive that the technology will undoubtedly be applied in the very near future to cleaning large mercury contaminates sites. Many such sites were not remediable previously due to the excessive costs and the negative environmental impact of conventional mechanical-chemical technologies. At the time this grant was awarded 20 months ago, the authors had successfully engineered a small model plant, Arabidopsis thaliana, to use a highly modified bacterial mercuric ion reductase gene, merA9, to detoxify ionic mercury (Hg(II)), reducing it to much less toxic and volatile metallic Hg(0) (Rugh et al., 1996). Seeds from these plants germinate, grow, and set seed at normal growth rates on levels of Hg(II) that are lethal to normal plants. In assays on transgenic seedlings suspended in a solution of Hg(II), 10 ng of Hg(0) was evolved per min per mg wet weight of plant tissue. At that time, the authors had no information on expression of merA in any other plant species, nor had the authors tested merB in any plant. However, the results were so startlingly positive and well received that they clearly presaged a paradigm shift in the field of environmental remediation.'

  20. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

    2014-09-02T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  1. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25T23:59:59.000Z

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  2. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2008-10-14T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  3. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2012-05-01T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  4. The development and field testing of a passive mercury dosimeter

    E-Print Network [OSTI]

    Zahray, Robert Karl

    1982-01-01T23:59:59.000Z

    for mercury vapor, and the recovery of the mercury and subsequent analysis is a very simple and reliable procedure. The equipmenc required in this procedure is the same as the equipment re- quired for the hopcalite tube analysis; therefore the two systems... flask. The mercury was reduced from Hg to Hg and the result- ing mercury vapor was recirculated through the sample flask and the atomic absorption cell until a maximum reading in absorbance units was obtained. The absorbance of the solution of mercury...

  5. MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Ye Zhuang; Stanley J. Miller

    2005-05-01T23:59:59.000Z

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control. An additional task was included in this project to evaluate mercury oxidation upstream of a dry scrubber by using mercury oxidants. This project demonstrated at the pilot-scale level a technology that provides a cost-effective technique to control mercury and, at the same time, greatly enhances fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution for improved fine particulate control combined with effective mercury control for a large segment of the U.S. utility industry as well as other industries.

  6. Magnetic dipole discharges. III. Instabilities

    SciTech Connect (OSTI)

    Stenzel, R. L.; Urrutia, J. M. [Department of Physics and Astronomy, University of California Los Angeles, California 90095-1547 (United States)] [Department of Physics and Astronomy, University of California Los Angeles, California 90095-1547 (United States); Ionita, C.; Schrittwieser, R. [Institute for Ion Physics and Applied Physics, University of Innsbruck A-6020 Innsbruck (Austria)] [Institute for Ion Physics and Applied Physics, University of Innsbruck A-6020 Innsbruck (Austria)

    2013-08-15T23:59:59.000Z

    Instabilities in a cross-field discharge around a permanent magnet have been investigated. The permanent magnet serves as a cold cathode and the chamber wall as an anode. The magnet is biased strongly negative and emits secondary electrons due to impact of energetic ions. The electrons outside the sheath are confined by the strong dipolar magnetic field and by the ion-rich sheath surrounding the magnet. The electron energy peaks in the equatorial plane where most ionization occurs and the ions are trapped in a negative potential well. The discharge mechanism is the same as that of cylindrical and planar magnetrons, but here extended to a 3-D cathode geometry using a single dipole magnet. While the basic properties of the discharge are presented in a companion paper, the present focus is on various observed instabilities. The first is an ion sheath instability which oscillates the plasma potential outside the sheath below the ion plasma frequency. It arises in ion-rich sheaths with low electron supply, which is the case for low secondary emission yields. Sheath oscillations modulate the discharge current creating oscillating magnetic fields. The second instability is current-driven ion sound turbulence due to counter-streaming electrons and ions. The fluctuations have a broad spectrum and short correlation lengths in all directions. The third type of fluctuations is spiky potential and current oscillations in high density discharges. These appear to be due to unstable emission properties of the magnetron cathode.

  7. Journal of Engineering Mathematics Optimal discharging in a branched estuary Optimal discharging in a branched estuary

    E-Print Network [OSTI]

    that returns to the discharge site is less polluted than would 1 #12;Journal of Engineering Mathematics OptimalJournal of Engineering Mathematics Optimal discharging in a branched estuary Optimal discharging the proximity of the discharge site to the branching and upon how the rate of discharge is adjusted. Explicit

  8. Mercury Nozzle Status V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    . DEPARTMENT OF ENERGY Hg Jet Design Meeting ­ 15 Nov 2004 Flow Issues · High flow in small diameter thin-wall ­ 15 Nov 2004 Design Issues · Desire mechanically attached nozzle for changeout during cold testingMercury Nozzle Status V.B. Graves Hg Jet Design Meeting Princeton University Nov 15, 2004 #12;OAK

  9. MERcury Intense Target (MERIT) Van Graves, ORNL

    E-Print Network [OSTI]

    McDonald, Kirk

    OF ENERGY Airline Hydraulics 28 Oct 2005 Hg System Schematic Double Window (2) Primary Containment SecondaryMERcury Intense Target (MERIT) Overview Van Graves, ORNL Syringe Procurement Kickoff Meeting Airline Hydraulics Bensalem, PA Oct 28, 2005 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT

  10. A NASA Discovery Mission Mercury Orbit Insertion

    E-Print Network [OSTI]

    major systems provide critical backup. Passive thermal design utilizing ceramic-cloth sunshade requires. Custom solar arrays produce power at safe operating temperatures near Mercury. MESSENGER is designedMercuryandextendedfrom before the end of heavy bombardment to the second half of solar system history

  11. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2008-06-30T23:59:59.000Z

    ADA-ES, Inc., with support from DOE/NETL, EPRI, and industry partners, studied mercury control options at six coal-fired power plants. The overall objective of the this test program was to evaluate the capabilities of activated carbon injection at six plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, American Electric Power's Conesville Station Unit 6, and Labadie Power Plant Unit 2. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The financial goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000 per pound of mercury removed. Results from testing at Holcomb, Laramie, Meramec, Labadie, and Monroe indicate the DOE goal was successfully achieved. However, further improvements for plants with conditions similar to Conesville are recommended that would improve both mercury removal performance and economics.

  12. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2006-04-30T23:59:59.000Z

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at DTE Energy's Monroe Power Plant, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program was to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000/lb mercury removed. The results from Monroe indicate that using DARCO{reg_sign} Hg would result in higher mercury removal (80%) at a sorbent cost of $18,000/lb mercury, or 70% lower than the benchmark. These results demonstrate that the goals established by DOE/NETL were exceeded during this test program. The increase in mercury removal over baseline conditions is defined for this program as a comparison in the outlet emissions measured using the Ontario Hydro method during the baseline and long-term test periods. The change in outlet emissions from baseline to long-term testing was 81%.

  13. Constricted glow discharge plasma source

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA); Anders, Simone (Albany, CA); Dickinson, Michael (San Leandro, CA); Rubin, Michael (Berkeley, CA); Newman, Nathan (Winnetka, IL)

    2000-01-01T23:59:59.000Z

    A constricted glow discharge chamber and method are disclosed. The polarity and geometry of the constricted glow discharge plasma source is set so that the contamination and energy of the ions discharged from the source are minimized. The several sources can be mounted in parallel and in series to provide a sustained ultra low source of ions in a plasma with contamination below practical detection limits. The source is suitable for applying films of nitrides such as gallium nitride and oxides such as tungsten oxide and for enriching other substances in material surfaces such as oxygen and water vapor, which are difficult process as plasma in any known devices and methods. The source can also be used to assist the deposition of films such as metal films by providing low-energy ions such as argon ions.

  14. Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria

    SciTech Connect (OSTI)

    Hu, Haiyan [ORNL] [ORNL; Lin, Hui [ORNL] [ORNL; Zheng, Wang [ORNL] [ORNL; Tomanicek, Stephen J [ORNL] [ORNL; Johs, Alexander [ORNL] [ORNL; Feng, Xinbin [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Gu, Baohua [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Methylmercury is a neurotoxin that poses significant health risks to humans. Some anaerobic sulphate- and iron-reducing bacteria can methylate oxidized forms of mercury, generating methylmercury1-4. One strain of sulphate-reducing bacteria (Desulfovibrio desulfuricans ND132) can also methylate elemental mercury5. The prevalence of this trait among different bacterial strains and species remains unclear, however. Here, we compare the ability of two strains of the sulphate-reducing bacterium Desulfovibrio and one strain of the iron-reducing bacterium Geobacter to oxidise and methylate elemental mercury in a series of laboratory incubations. Experiments were carried out under dark, anaerobic conditions, in the presence of environmentally-relevant concentrations of elemental mercury. We report differences in the ability of these organisms to oxidise and methylate elemental mercury. In line with recent findings5, we show that Desulfovibrio desulfuricans ND132 can both oxidise and methylate elemental mercury. However, the rate of methylation of elemental mercury is only about one third the rate of methylation of oxidized mercury. We also show that Desulfovibrio alaskensis G20 can oxidise, but not methylate, elemental mercury. Geobacter sulfurreducens PCA is able to oxidise and methylate elemental mercury in the presence of cysteine. We suggest that the activity of methylating and non-methylating bacteria may together enhance the formation of methylmercury in anaerobic environments.

  15. Influences on Mercury Bioaccumulation Factors for the Savannah River

    SciTech Connect (OSTI)

    Paller, M.H.

    2003-05-06T23:59:59.000Z

    Mercury TMDLs (Total Maximum Daily Loads) are a regulatory instrument designed to reduce the amount of mercury entering a water body and ultimately to control the bioaccumulation of mercury in fish. TMDLs are based on a BAF (bioaccumulation factor), which is the ratio of methyl mercury in fish to dissolved methyl mercury in water. Analysis of fish tissue and aqueous methyl mercury samples collected at a number of locations and over several seasons in a 118 km reach of the Savannah River demonstrated that species specific BAFs varied by factors of three to eight. Factors contributing to BAF variability were location, habitat and season related differences in fish muscle tissue mercury levels and seasonal differences in dissolved methyl mercury levels. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 106 for largemouth bass, 1.4 x 106 for sunfishes, and 2.5 x 106 for white catfish. Inaccurate and imprecise BAFs can result in unnecessary economic impact or insufficient protection of human health. Determination of representative and precise BAFs for mercury in fish from large rivers necessitates collecting large and approximately equal numbers of fish and aqueous methyl mercury samples over a seasonal cycle from the entire area and all habitats to be represented by the TMDL.

  16. Mercury Control with Calcium-Based Sorbents and Oxidizing Agents

    SciTech Connect (OSTI)

    Thomas K. Gale

    2005-07-01T23:59:59.000Z

    This Final Report contains the test descriptions, results, analysis, correlations, theoretical descriptions, and model derivations produced from many different investigations performed on a project funded by the U.S. Department of Energy, to investigate calcium-based sorbents and injection of oxidizing agents for the removal of mercury. Among the technologies were (a) calcium-based sorbents in general, (b) oxidant-additive sorbents developed originally at the EPA, and (c) optimized calcium/carbon synergism for mercury-removal enhancement. In addition, (d) sodium-tetrasulfide injection was found to effectively capture both forms of mercury across baghouses and ESPs, and has since been demonstrated at a slipstream treating PRB coal. It has been shown that sodium-tetrasulfide had little impact on the foam index of PRB flyash, which may indicate that sodium-tetrasulfide injection could be used at power plants without affecting flyash sales. Another technology, (e) coal blending, was shown to be an effective means of increasing mercury removal, by optimizing the concentration of calcium and carbon in the flyash. In addition to the investigation and validation of multiple mercury-control technologies (a through e above), important fundamental mechanism governing mercury kinetics in flue gas were elucidated. For example, it was shown, for the range of chlorine and unburned-carbon (UBC) concentrations in coal-fired utilities, that chlorine has much less effect on mercury oxidation and removal than UBC in the flyash. Unburned carbon enhances mercury oxidation in the flue gas by reacting with HCl to form chlorinated-carbon sites, which then react with elemental mercury to form mercuric chloride, which subsequently desorbs back into the flue gas. Calcium was found to enhance mercury removal by stabilizing the oxidized mercury formed on carbon surfaces. Finally, a model was developed to describe these mercury adsorption, desorption, oxidation, and removal mechanisms, including the synergistic enhancement of mercury removal by calcium.

  17. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    None

    2005-09-29T23:59:59.000Z

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  18. Compact monolithic capacitive discharge unit

    DOE Patents [OSTI]

    Roesler, Alexander W. (Tijeras, NM); Vernon, George E. (Rio Rancho, NM); Hoke, Darren A. (Albuquerque, NM); De Marquis, Virginia K. (Tijeras, NM); Harris, Steven M. (Albuquerque, NM)

    2007-06-26T23:59:59.000Z

    A compact monolithic capacitive discharge unit (CDU) is disclosed in which a thyristor switch and a flyback charging circuit are both sandwiched about a ceramic energy storage capacitor. The result is a compact rugged assembly which provides a low-inductance current discharge path. The flyback charging circuit preferably includes a low-temperature co-fired ceramic transformer. The CDU can further include one or more ceramic substrates for enclosing the thyristor switch and for holding various passive components used in the flyback charging circuit. A load such as a detonator can also be attached directly to the CDU.

  19. State Waste Discharge Permit application, 183-N Backwash Discharge Pond

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173--216 (or 173--218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE91NM-177 requires a series of permitting activities for liquid effluent discharges. Liquid effluents on the Hanford Site have been classified as Phase I, Phase II, and Miscellaneous Streams. The Consent Order No. DE91NM-177 establishes milestones for State Waste Discharge Permit application submittals for all Phase I and Phase II streams, as well as the following 11 Miscellaneous Streams as identified in Table 4 of the Consent Order No. DE91NM-177.

  20. Mercury Emissions Control Technologies (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    The Annual Energy Outlook 2006 reference case assumes that states will comply with the requirements of the Environmental Protection Agency's new Clean Air Mercury Rule (CAMR) regulation. CAMR is a two-phase program, with a Phase I cap of 38 tons of mercury emitted from all U.S. power plants in 2010 and a Phase II cap of 15 tons in 2018. Mercury emissions in the electricity generation sector in 2003 are estimated at around 50 tons. Generators have a variety of options to meet the mercury limits, such as: switching to coal with a lower mercury content, relying on flue gas desulfurization or selective catalytic reduction equipment to reduce mercury emissions, or installing conventional activated carbon injection (ACI) technology.

  1. Characteristics of mercury desorption from sorbents at elevated temperatures

    SciTech Connect (OSTI)

    Ho, T.C.; Yang, P.; Kuo, T.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering

    1998-12-31T23:59:59.000Z

    This study investigated the dynamic desorption characteristics of mercury during the thermal treatment of mercury-loaded sorbents at elevated temperatures under fixed-bed operations. Experiments were carried out in a 25.4 mm ID quartz bed enclosed in an electric furnace. Elemental mercury and mercuric chloride were tested with activated carbon and bauxite. The experimental results indicated that mercury desorption from sorbents was strongly affected by the desorption temperature and the mercury-sorbent pair. Elemental mercury was observed to desorb faster than mercuric chloride and activated carbon appeared to have higher desorption limits than bauxite at low temperatures. A kinetic model considering the mechanisms of surface equilibrium, pore diffusion and external mass transfer was proposed to simulate the observed desorption profiles. The model was found to describe reasonably well the experimental results.

  2. Mercury control for coal-fired power plants

    SciTech Connect (OSTI)

    Haase, P.

    2005-06-30T23:59:59.000Z

    On 15 March 2005 the US Environmental Protection Agency issued its Clean Air Mercury Rule (CAMP) to regulate mercury emissions from coal-fired power plants. EPRI is working with the US Department of Energy and the power industry to develop mercury control technologies needed to meet the final 2018 emission limits. Some improvements can be made by modifying existing SO{sub 2} or NOx control devices. Precombustion cleaning reduces mercury content of eastern coals by about one third. Adding a little halogen is another technology being researched - this promotes oxidation improving short-term mercury capture. EPRI is developing the TOXECON{trademark} technology to address a major problem of using sorbents to control mercury emissions: contamination of fly ash. 5 figs.

  3. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect (OSTI)

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14T23:59:59.000Z

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

  4. Comparative analysis of discharges into Lake Michigan, Phase I - Southern Lake Michigan.

    SciTech Connect (OSTI)

    Veil, J. A.; Elcock, D.; Gasper, J. R.; Environmental Science Division

    2008-06-30T23:59:59.000Z

    BP Products North America Inc. (BP) owns and operates a petroleum refinery located on approximately 1,700 acres in Whiting, East Chicago, and Hammond, Indiana, near the southern tip of Lake Michigan. BP provided funding to Purdue University-Calumet Water Institute (Purdue) and Argonne National Laboratory (Argonne) to conduct studies related to wastewater treatment and discharges. Purdue and Argonne are working jointly to identify and characterize technologies that BP could use to meet the previous discharge permit limits for total suspended solids (TSS) and ammonia after refinery modernization. In addition to the technology characterization work, Argonne conducted a separate project task, which is the subject of this report. In Phase I of a two-part study, Argonne estimated the current levels of discharge to southern Lake Michigan from significant point and nonpoint sources in Illinois, Indiana, and portions of Michigan. The study does not consider all of the chemicals that are discharged. Rather, it is narrowly focused on a selected group of pollutants, referred to as the 'target pollutants'. These include: TSS, ammonia, total and hexavalent chromium, mercury, vanadium, and selenium. In Phase II of the study, Argonne will expand the analysis to cover the entire Lake Michigan drainage basin.

  5. High-Intensity Discharge Lighting Basics | Department of Energy

    Energy Savers [EERE]

    lighting. Mercury vapor lamps provide about 50 lumens per watt. They cast a very cool bluegreen white light. Most indoor mercury vapor lamps in arenas and gymnasiums have been...

  6. Thief carbon catalyst for oxidation of mercury in effluent stream

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2011-12-06T23:59:59.000Z

    A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

  7. A study of the solubility of mercury in liquid hydrocarbons 

    E-Print Network [OSTI]

    McFarlane, David Larimer

    1991-01-01T23:59:59.000Z

    . For these measurements a high power, narrow linewidth, pulsed, multiple laser system was utilized for generating the required UV radiation. The results provide solubility curves for the hydrocarbons which demonstrate the temperature dependence of mercury solubility... Spectrometer . . . 4 Partial Energy Level Diagram of Mercury . . . . . , . . 5 Schematic of the Spectra Physics Model 380D Ring Dye Laser System 6 Four - Stage Pulsed Dye Amplifier 7 Laser System for Detection of Mercury Using Two Photon Absorption 8...

  8. Dissolved gaseous mercury behavior in shallow water estuaries

    E-Print Network [OSTI]

    Landin, Charles Melchor

    2008-10-10T23:59:59.000Z

    of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While this makes DGM.... Based on information obtained in freshwater systems, one can hypothesize that processes affecting DGM cycling are similar in estuarine systems. The hypothesis that was tested in this research is as follows: Dissolved gaseous mercury concentrations...

  9. Redesigning Marsh Creek Dam to allow Chinook salmon passage, flood protection, and mercury sedimentation

    E-Print Network [OSTI]

    McNulty, M. Eliza; Wickland, Matthew

    2003-01-01T23:59:59.000Z

    J. E. , 1998. Marsh Creek Watershed Mercury Assessmentbe possible for all of Marsh Creek to be an accessible andD. , unpublished. Marsh Creek mercury assessment and

  10. Gold Mining Impacts on Food Chain Mercury in Northwestern Sierra Nevada Streams

    E-Print Network [OSTI]

    Slotton, Darell G; Ayers, Shaun M; Reuter, John E; Goldman, Charles R

    1995-01-01T23:59:59.000Z

    KEYWORDS,' mercury, gold, mining, trout, invertebrates,GOLD MINING IMPACTS ON FOOD CHAIN MERCURY IN NORTHWESTERNduring the course of gold mining in the Gold Rush period of

  11. ORNL research reveals new challenges for mercury cleanup | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mercury to methylmercury, a neurotoxin that can penetrate skin and at high doses affect brain and muscle tissue, causing paralysis and brain damage. The discovery of how...

  12. State Surface Water Discharge Permits (New Hampshire)

    Broader source: Energy.gov [DOE]

    Rules apply to the discharge of all pollutants from a point source to surface waters of the state. The rule does not apply to facilities that require both a state discharge permit and a federal...

  13. Oklahoma Pollutant Discharge Elimination System Act (Oklahoma)

    Broader source: Energy.gov [DOE]

    The Department of Environmental Quality regulates facilities that discharge any pollutant into waters of the state. Permits must be acquired before the discharge of any pollutants into state waters...

  14. Plasma Structure and Behavior of Miniature Ring-Cusp Discharges

    E-Print Network [OSTI]

    Mao, Hann-Shin

    2013-01-01T23:59:59.000Z

    Basic Ion Thruster Discharge ChamberSimulations for an Ion Engine Discharge Chamber,” J. Propul.Model of an Ion Thruster Discharge Chamber,” in 39th AIAA

  15. Mercury Specie and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Rob James; Virgil Joffrion; John McDermott; Steve Piche

    2010-05-31T23:59:59.000Z

    This project was awarded to demonstrate the ability to affect and optimize mercury speciation and multi-pollutant control using non-intrusive advanced sensor and optimization technologies. The intent was to demonstrate plant-wide optimization systems on a large coal fired steam electric power plant in order to minimize emissions, including mercury (Hg), while maximizing efficiency and maintaining saleable byproducts. Advanced solutions utilizing state-of-the-art sensors and neural network-based optimization and control technologies were proposed to maximize the removal of mercury vapor from the boiler flue gas thereby resulting in lower uncontrolled releases of mercury into the atmosphere. Budget Period 1 (Phase I) - Included the installation of sensors, software system design and establishment of the as-found baseline operating metrics for pre-project and post-project data comparison. Budget Period 2 (Phase II) - Software was installed, data communications links from the sensors were verified, and modifications required to integrate the software system to the DCS were performed. Budget Period 3 (Phase III) - Included the validation and demonstration of all control systems and software, and the comparison of the optimized test results with the targets established for the project site. This report represents the final technical report for the project, covering the entire award period and representing the final results compared to project goals. NeuCo shouldered 61% of the total project cost; while DOE shouldered the remaining 39%. The DOE requires repayment of its investment. This repayment will result from commercial sales of the products developed under the project. NRG's Limestone power plant (formerly owned by Texas Genco) contributed the host site, human resources, and engineering support to ensure the project's success.

  16. Method and apparatus for dispensing small quantities of mercury from evacuated and sealed glass capsules

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.; Pai, R.Y.

    1985-08-13T23:59:59.000Z

    A technique is disclosed for opening an evacuated and sealed glass capsule containing a material that is to be dispensed which has a relatively high vapor pressure such as mercury. The capsule is typically disposed in a discharge tube envelope. The technique involves the use of a first light source imaged along the capsule and a second light source imaged across the capsule substantially transversely to the imaging of the first light source. Means are provided for constraining a segment of the capsule along its length with the constraining means being positioned to correspond with the imaging of the second light source. These light sources are preferably incandescent projection lamps. The constraining means is preferably a multiple looped wire support. 6 figs.

  17. Analysis of Halogen-Mercury Reactions in Flue Gas

    SciTech Connect (OSTI)

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

    2010-01-01T23:59:59.000Z

    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

  18. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, Gordon E. (Albuquerque, NM)

    1998-01-01T23:59:59.000Z

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

  19. State waste discharge permit application for cooling water and condensate discharges

    SciTech Connect (OSTI)

    Haggard, R.D.

    1996-08-12T23:59:59.000Z

    The following presents the Categorical State Waste Discharge Permit (SWDP) Application for the Cooling Water and Condensate Discharges on the Hanford Site. This application is intended to cover existing cooling water and condensate discharges as well as similar future discharges meeting the criteria set forth in this document.

  20. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31T23:59:59.000Z

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  1. HID Laboratories Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI ReferenceJumpEnergyStrategy | Open Energy Sector:Ergenics Inc

  2. Evaluation of Regenerated Catalyst for Mercury Speciation

    SciTech Connect (OSTI)

    Dennis Laudal

    2007-06-01T23:59:59.000Z

    In March of 2005, U.S. Environmental Protection Agency (EPA) promulgated the Clean Air Mercury Rule (CAMR). Mercury from coal-fired power plants was to be reduced from the current 48 to 38 tons/yr by 2010 and then 15 tons/yr by 2018. It is expected that the first phase reduction of {approx}21% will be achieved by cobenefits that will occur as a result of installing additional selective catalytic reduction (SCR) and flue gas desulfurization (FGD) systems to meet the new Clean Air Interstate Rule (CAIR). Detroit Edison (DTE) is installing SCR at all four units at its Monroe Station and will eventually install wet-FGD systems. As such, the Electric Power Research Institute (EPRI), the U.S. Department of Energy (DOE), and DTE have contracted with the Energy & Environmental Research Center (EERC) to determine the extent of mercury oxidation that occurs at Monroe Station. The EERC originally did mercury speciation sampling at Monroe Station in 2004 and then went back in 2005 to determine if any changes occurred as a result of catalyst aging. During the second test, in addition to measuring the mercury speciation at the inlet and outlet of the SCR, the EERC also completed sampling at a location between the catalyst layers. The results are shown in Table 1. In Table 1, the results show that {approx}40% of the Hg was in oxidized form (Hg{sup 2+}) at the inlet and nearly 100% Hg{sup 2+} at the outlet. The results at the midpoint were between 40% and 100%. As part of their overall strategy to reduce SCR costs, utilities and SCR vendors are attempting to regenerate catalyst layers that have degenerated over time. If these regenerated catalysts are used, the question remains as to the effect this process will have on the ability of these catalysts to oxidize mercury as well as reduce NO{sub x}. The current project is designed to measure the Hg speciation across an SCR using a regenerated catalyst. The results were compared to previous results to determine what, if any, changes occurred. Two series of tests were completed: one early in the ozone season (July 2006) and the second near the end (September 2006). The goal of this project is to determine the effect SCR catalyst regeneration has on Hg speciation and emissions from combustion of a blend of eastern bituminous and Powder River Basin (PRB) coal at DTE's Monroe Station. Specific objectives include the following: (1) Compare the Hg speciation results at the inlet and outlet of the SCR. Determine the change in the concentration of oxidized Hg across the SCR. In addition, determine if the number of catalyst layers has any effect. (2) Compare results from previous testing to determine if there are changes in mercury speciation as a result of catalyst regeneration. (3) Determine the overall speciated Hg emissions (from a separate project funded by DTE).

  3. Gravity Field and Internal Structure of Mercury from MESSENGER

    E-Print Network [OSTI]

    Zuber, Maria

    ,5 Mark E. Perry,11 David D. Rowlands,5 Sander Goossens,12 James W. Head,13 Anthony H. Taylor14 RadioGravity Field and Internal Structure of Mercury from MESSENGER David E. Smith,1 Maria T. Zuber,1 tracking of the MESSENGER spacecraft has provided a model of Mercury's gravity field. In the northern

  4. Implications of mercury interactions with band-gap semiconductor oxides

    SciTech Connect (OSTI)

    Granite, E.J.; King, W.P.; Stanko, D.C.; Pennline, H.W.

    2008-09-01T23:59:59.000Z

    Titanium dioxide is a well-known photooxidation catalyst. It will oxidize mercury in the presence of ultraviolet light from the sun and oxygen and/or moisture to form mercuric oxide. Several companies manufacture self-cleaning windows. These windows have a transparent coating of titanium dioxide. The titanium dioxide is capable of destroying organic contaminants in air in the presence of ultraviolet light from the sun, thereby keeping the windows clean. The commercially available self-cleaning windows were used to sequester mercury from oxygen–nitrogen mixtures. Samples of the self-cleaning glass were placed into specially designed photo-reactors in order to study the removal of elemental mercury from oxygen–nitrogen mixtures resembling air. The possibility of removing mercury from ambient air with a self-cleaning glass apparatus is examined. The intensity of 365-nm ultraviolet light was similar to the natural intensity from sunlight in the Pittsburgh region. Passive removal of mercury from the air may represent an option in lieu of, or in addition to, point source clean-up at combustion facilities. There are several common band-gap semiconductor oxide photocatalysts. Sunlight (both the ultraviolet and visible light components) and band-gap semiconductor particles may have a small impact on the global cycle of mercury in the environment. The potential environmental consequences of mercury interactions with band-gap semiconductor oxides are discussed. Heterogeneous photooxidation might impact the global transport of elemental mercury emanating from flue gases.

  5. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T. (Louisville, OH)

    2001-01-01T23:59:59.000Z

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  6. Method for removal of mercury from various gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2003-06-10T23:59:59.000Z

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  7. Activated carbon injection - a mercury control success story

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    Almost 100 full-scale activated carbon injection (ACI) systems have been ordered by US electric utilities. These systems have the potential to remove over 90% of the mercury in flue, at a cost below $10,000 per pound of mercury removal. Field trials of ACI systems arm outlined. 1 fig.

  8. Genome Sequence of Mercury-Methylating and Pleomorphic Desulfovibrio africanus

    E-Print Network [OSTI]

    Genome Sequence of Mercury-Methylating and Pleomorphic Desulfovibrio africanus Contact: Steven D. africanus genome sequence to allow us to gain insights into the physiological states genomics using the sequence information for D. africanus and the previously sequenced mercury methylator D

  9. Mercury emission behavior during isolated coal particle combustion

    E-Print Network [OSTI]

    Puchakayala, Madhu Babu

    2009-05-15T23:59:59.000Z

    Of all the trace elements emitted during coal combustion, mercury is most problematic. Mercury from the atmosphere enters into oceanic and terrestrial waters. Part of the inorganic Hg in water is converted into organic Hg (CH3Hg), which is toxic...

  10. PyMercury: Interactive Python for the Mercury Monte Carlo Particle Transport Code

    SciTech Connect (OSTI)

    Iandola, F N; O'Brien, M J; Procassini, R J

    2010-11-29T23:59:59.000Z

    Monte Carlo particle transport applications are often written in low-level languages (C/C++) for optimal performance on clusters and supercomputers. However, this development approach often sacrifices straightforward usability and testing in the interest of fast application performance. To improve usability, some high-performance computing applications employ mixed-language programming with high-level and low-level languages. In this study, we consider the benefits of incorporating an interactive Python interface into a Monte Carlo application. With PyMercury, a new Python extension to the Mercury general-purpose Monte Carlo particle transport code, we improve application usability without diminishing performance. In two case studies, we illustrate how PyMercury improves usability and simplifies testing and validation in a Monte Carlo application. In short, PyMercury demonstrates the value of interactive Python for Monte Carlo particle transport applications. In the future, we expect interactive Python to play an increasingly significant role in Monte Carlo usage and testing.

  11. Lifestyle and Mercury Contamination of Amerindian Populations along the Beni River

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Lifestyle and Mercury Contamination of Amerindian Populations along the Beni River (Lowland (Corresponding author), M.D., Ph.D. Abstract The objective of this paper was to document mercury contamination at the foothills of the Andes. Hair mercury content (H-Hg) served as a bioindicator of mercury contamination

  12. Emissions of airborne toxics from coal-fired boilers: Mercury

    SciTech Connect (OSTI)

    Huang, H.S.; Livengood, C.D.; Zaromb, S.

    1991-09-01T23:59:59.000Z

    Concerns over emissions of hazardous air Pollutants (air toxics) have emerged as a major environmental issue, and the authority of the US Environmental Protection Agency to regulate such pollutants was greatly expanded through the Clean Air Act Amendments of 1990. Mercury has been singled out for particular attention because of concerns over possible effects of emissions on human health. This report evaluates available published information on the mercury content of coals mined in the United States, on mercury emitted in coal combustion, and on the efficacy of various environmental control technologies for controlling airborne emissions. Anthracite and bituminous coals have the highest mean-mercury concentrations, with subbituminous coals having the lowest. However, all coal types show very significant variations in mercury concentrations. Mercury emissions from coal combustion are not well-characterized, particularly with regard to determination of specific mercury compounds. Variations in emission rates of more than an order of magnitude have been reported for some boiler types. Data on the capture of mercury by environmental control technologies are available primarily for systems with electrostatic precipitators, where removals of approximately 20% to over 50% have been reported. Reported removals for wet flue-gas-desulfurization systems range between 35 and 95%, while spray-dryer/fabric-filter systems have given removals of 75 to 99% on municipal incinerators. In all cases, better data are needed before any definitive judgments can be made. This report briefly reviews several areas of research that may lead to improvements in mercury control for existing flue-gas-clean-up technologies and summarizes the status of techniques for measuring mercury emissions from combustion sources.

  13. Narrow gap electronegative capacitive discharges

    SciTech Connect (OSTI)

    Kawamura, E.; Lieberman, M. A.; Lichtenberg, A. J. [Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, California 94720 (United States)] [Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, California 94720 (United States)

    2013-10-15T23:59:59.000Z

    Narrow gap electronegative (EN) capacitive discharges are widely used in industry and have unique features not found in conventional discharges. In this paper, plasma parameters are determined over a range of decreasing gap length L from values for which an electropositive (EP) edge exists (2-region case) to smaller L-values for which the EN region connects directly to the sheath (1-region case). Parametric studies are performed at applied voltage V{sub rf}=500 V for pressures of 10, 25, 50, and 100 mTorr, and additionally at 50 mTorr for 1000 and 2000 V. Numerical results are given for a parallel plate oxygen discharge using a planar 1D3v (1 spatial dimension, 3 velocity components) particle-in-cell (PIC) code. New interesting phenomena are found for the case in which an EP edge does not exist. This 1-region case has not previously been investigated in detail, either numerically or analytically. In particular, attachment in the sheaths is important, and the central electron density n{sub e0} is depressed below the density n{sub esh} at the sheath edge. The sheath oscillations also extend into the EN core, creating an edge region lying within the sheath and not characterized by the standard diffusion in an EN plasma. An analytical model is developed using minimal inputs from the PIC results, and compared to the PIC results for a base case at V{sub rf}=500 V and 50 mTorr, showing good agreement. Selected comparisons are made at the other voltages and pressures. A self-consistent model is also developed and compared to the PIC results, giving reasonable agreement.

  14. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-04-14T23:59:59.000Z

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

  15. Multiple discharge cylindrical pump collector

    DOE Patents [OSTI]

    Dunn, Charlton (Calabasas, CA); Bremner, Robert J. (Woodland Hills, CA); Meng, Sen Y. (Reseda, CA)

    1989-01-01T23:59:59.000Z

    A space-saving discharge collector 40 for the rotary pump 28 of a pool-type nuclear reactor 10. An annular collector 50 is located radially outboard for an impeller 44. The annular collector 50 as a closed outer periphery 52 for collecting the fluid from the impeller 44 and producing a uniform circumferential flow of the fluid. Turning means comprising a plurality of individual passageways 54 are located in an axial position relative to the annular collector 50 for receiving the fluid from the annular collector 50 and turning it into a substantially axial direction.

  16. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-03-10T23:59:59.000Z

    A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

  17. Non-storm water discharges technical report

    SciTech Connect (OSTI)

    Mathews, S.

    1994-07-01T23:59:59.000Z

    Lawrence Livermore National Laboratory (LLNL) submitted a Notice of Intent to the California State Water Resources Control Board (hereafter State Board) to discharge storm water associated with industrial activities under the California General Industrial Activity Storm Water National Pollutant Elimination System Discharge Permit (hereafter General Permit). As required by the General Permit, LLNL provided initial notification of non-storm water discharges to the Central Valley Regional Water Quality Control Board (hereafter Regional Board) on October 2, 1992. Additional findings and progress towards corrective actions were reported in subsequent annual monitoring reports. LLNL was granted until March 27, 1995, three years from the Notice of Intent submission date, to eliminate or permit the non-storm water discharges. On May 20, 1994, the Regional Board issued Waste Discharge Requirements (WDR Board Order No. 94-131, NPDES No. CA0081396) to LLNL for discharges of non-contact cooling tower wastewater and storm water related to industrial activities. As a result of the issuance of WDR 94-131, LLNL rescinded its coverage under the General Permit. WDR 94-131 allowed continued non-storm water discharges and requested a technical report describing the discharges LLNL seeks to permit. For the described discharges, LLNL anticipates the Regional Board will either waive Waste Discharge Requirements as allowed for in The Water Quality Control Plan for the California Regional Water Quality Control Board, Central Valley Region (hereafter Basin Plan) or amend Board Order 94-131 as appropriate.

  18. Category:Mercury Vapor | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, click here. Category:Conceptual ModelLists forMercury Vapor page? For detailed

  19. ccpi_mercury | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 Mesaba EnergyFinalMercury

  20. A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR

    SciTech Connect (OSTI)

    Christopher C. Carter, Ph.D.

    2003-06-30T23:59:59.000Z

    Previous work on the detection of mercury using the cavity ring-down (CRD) technique has concentrated on the detection and characterization of the desired mercury transition. Interferent species present in flue gas emissions have been tested as well as a simulated flue gas stream. Additionally, work has been done on different mercury species such as the elemental and oxidized forms. The next phase of the effort deals with the actual sampling system. This sampling system will be responsible for acquiring a sample stream from the flue gas stack, taking it to the CRD cavity where it will be analyzed and returning the gas stream to the stack. In the process of transporting the sample gas stream every effort must be taken to minimize any losses of mercury to the walls of the sampling system as well as maintaining the mercury in its specific state (i.e. elemental, oxidized, or other mercury compounds). SRD first evaluated a number of commercially available sampling systems. These systems ranged from a complete sampling system to a number of individual components for specific tasks. SRD engineers used some commercially available components and designed a sampling system suited to the needs of the CRD instrument. This included components such as a pyrolysis oven to convert all forms of mercury to elemental mercury, a calibration air source to ensure mirror alignment and quality of the mirror surfaces, and a pumping system to maintain the CRD cavity pressure from atmospheric pressure (760 torr) down to about 50 torr. SRD also began evaluating methods for the CRD instrument to automatically find the center of a mercury transition. This procedure is necessary as the instrument must periodically measure the baseline losses of the cavity off of the mercury resonance and then return to the center of the transition to accurately measure the mercury concentration. This procedure is somewhat complicated due to the isotopic structure of the 254 nm mercury transition. As a result of 6 isotopes and hyperfine splittings there are 5 individual peaks that can be resolved by the CRD instrument. SRD tested a derivative method with both simulated data and actual data taken with the CRD apparatus. Initial tests indicate that this method is successful in automatically finding the center of the mercury transitions.

  1. Leaching of Phase II Mercury Control Technology By-Products

    SciTech Connect (OSTI)

    Hesbach, P.A.; Kachur, E.K.

    2007-07-01T23:59:59.000Z

    The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

  2. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2005-08-01T23:59:59.000Z

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

  3. EPA - National Pollutant Discharge Elimination System General...

    Open Energy Info (EERE)

    General Permit for Discharges from Construction Activities Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: EPA -...

  4. Hawaii National Pollutant Discharge Elimination System (NPDES...

    Open Energy Info (EERE)

    LibraryAdd to library PermittingRegulatory Guidance - Supplemental Material: Hawaii National Pollutant Discharge Elimination System (NPDES) Permit PacketPermittingRegulatory...

  5. Site Discharge Pollution Prevention Plan (SDPPP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SDPPP Individual Permit: Site Discharge Pollution Prevention Plan (SDPPP) The 2012 SDPPP update fully incorporates all changes made during the year and reflects changes projected...

  6. Device for generation of pulsed corona discharge

    DOE Patents [OSTI]

    Gutsol, Alexander F. (San Ramon, CA); Fridman, Alexander (Marlton, NJ); Blank, Kenneth (Philadelphia, PA); Korobtsev, Sergey (Moscow, RU); Shiryaevsky, Valery (Moscow, RU); Medvedev, Dmitry (Moscow, RU)

    2012-05-08T23:59:59.000Z

    The invention is a method and system for the generation of high voltage, pulsed, periodic corona discharges capable of being used in the presence of conductive liquid droplets. The method and system can be used, for example, in different devices for cleaning of gaseous or liquid media using pulsed corona discharge. Specially designed electrodes and an inductor increase the efficiency of the system, permit the plasma chemical oxidation of detrimental impurities, and increase the range of stable discharge operations in the presence of droplets of water or other conductive liquids in the discharge chamber.

  7. Oil and Hazardous Substance Discharge Preparedness (Minnesota)

    Broader source: Energy.gov [DOE]

    Anyone who owns or operates a vessel or facility that transports, stores, or otherwise handles hazardous wastes must take reasonable steps to prevent the discharge of those materials.

  8. Proton induced activation in mercury: Comparison of measurements and calculations

    SciTech Connect (OSTI)

    Remec, Igor [ORNL; Glasgow, David C [ORNL; Haines, John R [ORNL; Johnson, Jeffrey O [ORNL

    2008-01-01T23:59:59.000Z

    Measurements and simulations of the proton beam interaction with the mercury target were performed to support Spallation Neutron Source design. Due to the abundance of isotopes produced in mercury, the long delay between the irradiation and the measurements, and the self-shielding of the mercury sample, the measurements were difficult to perform and the activities of several isotopes have large uncertainties. Calculations predicted the activities of the most reliably measured isotopes within 20%/40%; however, some large discrepancies were observed for some isotopes for which the measurements were considered less reliable. Predicted dose rates were in very good agreement with the measurements.

  9. BEHAVIOR OF MERCURY DURING DWPF CHEMICAL PROCESS CELL PROCESSING

    SciTech Connect (OSTI)

    Zamecnik, J.; Koopman, D.

    2012-04-09T23:59:59.000Z

    The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower retention of mercury in the slurry. Both recovery of mercury in the offgas system and removal (segregation + recovery) from the slurry correlate with slurry consistency. Higher slurry consistency results in better retention of Hg in the slurry (less segregation) and better recovery in the offgas system, but the relationships of recovery and retention with consistency are sludge dependent. Some correlation with slurry yield stress and acid stoichiometry was also found. Better retention of mercury in the slurry results in better recovery in the offgas system because the mercury in the slurry is stripped more easily than the segregated mercury at the bottom of the vessel. Although better retention gives better recovery, the time to reach a particular slurry mercury content (wt%) is longer than if the retention is poorer because the segregation is faster. The segregation of mercury is generally a faster process than stripping. The stripping factor (mass of water evaporated per mass of mercury stripped) of mercury at the start of boiling were found to be less than 1000 compared to the assumed design basis value of 750 (the theoretical factor is 250). However, within two hours, this value increased to at least 2000 lb water per lb Hg. For runs with higher mercury recovery in the offgas system, the stripping factor remained around 2000, but runs with low recovery had stripping factors of 4000 to 40,000. DWPF data shows similar trends with the stripping factor value increasing during boiling. These high values correspond to high segregation and low retention of mercury in the sludge. The stripping factor for a pure Hg metal bead in water was found to be about 10,000 lb/lb. About 10-36% of the total Hg evaporated in a SRAT cycle was refluxed back to the SRAT during formic acid addition and boiling. Mercury is dissolved as a result of nitric acid formation from absorption of NO{sub x}. The actual solubility of dissolved mercury in the acidic condensate is about 100 times higher than the actual concentrations measured. Mercury metal present in the MWWT from previous batch

  10. ElectricOIL discharge and post-discharge kinetics experiments and modeling

    E-Print Network [OSTI]

    Carroll, David L.

    oxygen, ozone, and other excited species adds levels of complexity to the singlet oxygen generator (SOG has been obtained by a near resonant energy transfer from O2(a1 ) produced using a low­pressure oxygen/helium/nitric-oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic

  11. Mercury Delivery System Tony Gabriel, Phil Spampinato

    E-Print Network [OSTI]

    McDonald, Kirk

    Concept Hydraulic Fluid Cylinder (3000 psi) Hg Cylinder (1000 psi) Hg Discharge Hg Inlet #12;6 OAK RIDGE losses isolated to hydraulic system - Flow losses identical to those in pump system #12;8 OAK RIDGE Motor 20 20 hp * 5% inefficiency 1 19 42 42 1 1 Hyd Pump energy performed on piston = press

  12. Plasma discharge self-cleaning filtration system

    DOE Patents [OSTI]

    Cho, Young I.; Fridman, Alexander; Gutsol, Alexander F.; Yang, Yong

    2014-07-22T23:59:59.000Z

    The present invention is directed to a novel method for cleaning a filter surface using a plasma discharge self-cleaning filtration system. The method involves utilizing plasma discharges to induce short electric pulses of nanoseconds duration at high voltages. These electrical pulses generate strong Shockwaves that disintegrate and dislodge particulate matter located on the surface of the filter.

  13. Ultralow Level Mercury Treatment Using Chemical Reduction and Air Stripping

    SciTech Connect (OSTI)

    Looney, B.B.

    2001-02-23T23:59:59.000Z

    The overall objective of this work is to develop a reasonable and cost-effective approach to meet the emerging mercury standards, especially for high volume outfalls with concentrations below the drinking water standard.

  14. Mercury Isotope Fractionation by Environmental Transport and Transformation Processes

    E-Print Network [OSTI]

    Koster van Groos, Paul Gijsbert

    2011-01-01T23:59:59.000Z

    measuring Hg 0 that permeated PVC tubing and matching this26 Chapter 3 Elemental Mercury Diffusion in a PVC29 Figure 3.2 The setup for diffusion in PVC

  15. assessing mercury levels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 STATE FISH SURVEY FINDS MERCURY LEVELS DOWN By Alex Breitler Environmental Sciences and Ecology...

  16. Transformations of mercury in the marine water column

    E-Print Network [OSTI]

    Munson, Kathleen M. (Kathleen May)

    2014-01-01T23:59:59.000Z

    Methylation of mercury (Hg) in the marine water column has been hypothesized to serve as the primary source of the bioaccumulating chemical species monomethylmercury (MMHg) to marine food webs. Despite decades of research ...

  17. An investigation of sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Haddad, G.J.; Hargis, R.A. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center

    1998-12-31T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from a carrier gas. An on-line atomic fluorescence spectrophotometer, used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  18. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, S.A.; Glish, G.L.

    1989-07-18T23:59:59.000Z

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

  19. Helium corona-assisted air discharge

    SciTech Connect (OSTI)

    Jiang Nan; Gao Lei; Ji Ailing; Cao Zexian [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2011-10-15T23:59:59.000Z

    Operation of atmospheric discharge of electronegative gases including air at low voltages yet without consuming any inert gas will enormously promote the application of non-thermal plasmas. By taking advantage of the low onset voltage for helium corona, air discharge was successfully launched at much reduced voltages with a needle-plate system partly contained in a helium-filled glass bulb--for a needle-plate distance of 12 mm, 1.0 kV suffices. Ultraviolet emission from helium corona facilitates the discharging of air, and the discharge current manifests distinct features such as relatively broad Trichel pulses in both half periods. This design allows safe and economic implementation of atmospheric discharge of electronegative gases, which will find a broad palette of applications in surface modification, plasma medicine and gas treatment, etc.

  20. Treatment of Mercury Contaminated Oil from the Mound Site

    SciTech Connect (OSTI)

    Klasson, KT

    2000-11-09T23:59:59.000Z

    Over one thousand gallons of tritiated oil, at various contamination levels, are stored in the Main Hill Tritium Facility at the Miamisburg Environmental Management Project (MEMP), commonly referred to as Mound Site. This tritiated oil is to be characterized for hazardous materials and radioactive contamination. Most of the hazardous materials are expected to be in the form of heavy metals, i.e., mercury, silver, lead, chromium, etc, but transuranic materials and PCBs could also be in some oils. Waste oils, found to contain heavy metals as well as being radioactively contaminated, are considered as mixed wastes and are controlled by Resource Conservation and Recovery Act (RCRA) regulations. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory (PNNL) for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds. The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury.

  1. Noble metal catalysts for oxidation of mercury in flue gas

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2008-04-01T23:59:59.000Z

    The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

  2. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; MILIAN, L.; LIPFERT, F.; SUBRAMANIAM, S.; BLAKE, R.

    2005-09-21T23:59:59.000Z

    Mercury is a neurotoxin that accumulates in the food chain and is therefore a health concern. The primary human exposure pathway is through fish consumption. Coal-fired power plants emit mercury and there is uncertainty over whether this creates localized hot spots of mercury leading to substantially higher levels of mercury in water bodies and therefore higher exposure. To obtain direct evidence of local deposition patterns, soil and vegetations samples from around three U.S. coal-fired power plants were collected and analyzed for evidence of hot spots and for correlation with model predictions of deposition. At all three sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. It was estimated that less than 2% of the total mercury emissions from these plants deposited within 15 km of these plants. These small percentages of deposition are consistent with the literature review findings of only minor perturbations in environmental levels, as opposed to hot spots, near the plants. The major objective of the sampling studies was to determine if there was evidence for hot spots of mercury deposition around coal-fired power plants. From a public health perspective, such a hot spot must be large enough to insure that it did not occur by chance, and it must increase mercury concentrations to a level in which health effects are a concern in a water body large enough to support a population of subsistence fishers. The results of this study suggest that neither of these conditions has been met.

  3. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F.; Reynolds, John G.; Fox, Glenn A.

    2004-02-24T23:59:59.000Z

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  4. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F. (Tracy, CA); Reynolds, John G. (San Ramon, CA); Fox, Glenn A. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  5. Method and apparatus for controlling the flow rate of mercury in a flow system

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

    1991-01-01T23:59:59.000Z

    A method for increasing the mercury flow rate to a photochemical mercury enrichment utilizing an entrainment system comprises the steps of passing a carrier gas over a pool of mercury maintained at a first temperature T1, wherein the carrier gas entrains mercury vapor; passing said mercury vapor entrained carrier gas to a second temperature zone T2 having temperature less than T1 to condense said entrained mercury vapor, thereby producing a saturated Hg condition in the carrier gas; and passing said saturated Hg carrier gas to said photochemical enrichment reactor.

  6. MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.

    2001-01-01T23:59:59.000Z

    Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

  7. Mercury and cause of death in great white herons

    SciTech Connect (OSTI)

    Spalding, M.G.; Sundlof, S.F. (Univ. of Florida, Gainesville, FL (United States)); Djork, R.D.; Powell, G.V.N. (National Audobon Research, Tavernier, FL (United States))

    1994-10-01T23:59:59.000Z

    Mercury contamination is suspected to adversely affect wading birds in southern Florida. To determine the magnitude of contamination associated with cause of death we followed 3 adult and 19 juvenile radio-tagged great white herons (Ardea herodias occidentalis), recovered them soon after death, and determined liver mercury content and cause of death. Birds that died from acute causes had less (P < 0.001) mercury in their livers (geometric [bar x] [GM] = 1.77 ppm wet mass [wm], range 0.6-4.0 ppm, n = 9) than did those that died of chronic, often multiple, diseases (GM = 9.76 ppm, range 2.9-59.4 ppm, n = 13). Juvenile herons that migrated to mainland Florida accumulated more (P = 0.009) mercury in their livers than those that did not migrate. Kidney disease and gout were present in birds that died with >25 ppm wm liver mercury. Although detrimental to the health of wading birds, mercury contamination is presumably more detrimental to their reproductive efforts; therefore, an understanding of its ill effects is important in the management of these birds. 29 refs., 1 fig.

  8. Density functional theory study of mercury adsorption on metal surfaces

    SciTech Connect (OSTI)

    Steckel, J.A.

    2008-01-01T23:59:59.000Z

    Density functional theory #1;DFT#2; calculations are used to characterize the interaction of mercury with copper, nickel, palladium, platinum, silver, and gold surfaces. Mercury binds relatively strongly to all the metal surfaces studied, with binding energies up to #3;1 eV for Pt and Pd. DFT calculations underestimate the energy of adsorption with respect to available experimental data. Plane-wave DFT results using the local density approximation and the Perdew-Wang 1991 and Perdew-Burke-Ernzerhof parametrizations of the generalized gradient approximation indicate that binding of mercury at hollow sites is preferred over binding at top or bridge sites. The interaction with mercury in order of increasing reactivity over the six metals studied is Ag #1;Au#1;Cu#1;Ni#1;Pt#1;Pd. Binding is stronger on the #1;001#2; faces of the metal surfaces, where mercury is situated in fourfold hollow sites as opposed to the threefold hollow sites on #1;111#2; faces. In general, mercury adsorption leads to decreases in the work function; adsorbate-induced work function changes are particularly dramatic on Pt.

  9. Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System

    E-Print Network [OSTI]

    Carroll, David L.

    Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

  10. Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases

    DOE Patents [OSTI]

    Nelson, Sidney (Hudson, OH)

    2011-02-15T23:59:59.000Z

    Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

  11. Mercury Emission Control Technologies for PPL Montana-Colstrip Testing

    SciTech Connect (OSTI)

    John P. Kay; Michael L. Jones; Steven A. Benson

    2007-04-01T23:59:59.000Z

    The Energy & Environmental Research Center (EERC) was asked by PPL Montana LLC (PPL) to provide assistance and develop an approach to identify cost-effective options for mercury control at its coal-fired power plants. The work conducted focused on baseline mercury level and speciation measurement, short-term parametric testing, and week long testing of mercury control technology at Colstrip Unit 3. Three techniques and various combinations of these techniques were identified as viable options for mercury control. The options included oxidizing agents or sorbent enhancement additives (SEAs) such as chlorine-based SEA1 and an EERC proprietary SEA2 with and without activated carbon injection. Baseline mercury emissions from Colstrip Unit 3 are comparatively low relative to other Powder River Basin (PRB) coal-fired systems and were found to range from 5 to 6.5 g/Nm3 (2.9 to 3.8 lb/TBtu), with a rough value of approximately 80% being elemental upstream of the scrubber and higher than 95% being elemental at the outlet. Levels in the stack were also greater than 95% elemental. Baseline mercury removal across the scrubber is fairly variable but generally tends to be about 5% to 10%. Parametric results of carbon injection alone yielded minimal reduction in Hg emissions. SEA1 injection resulted in 20% additional reduction over baseline with the maximum rate of 400 ppm (3 gal/min). Week long testing was conducted with the combination of SEA2 and carbon, with injection rates of 75 ppm (10.3 lb/hr) and 1.5 lb/MMacf (40 lb/hr), respectively. Reduction was found to be an additional 30% and, overall during the testing period, was measured to be 38% across the scrubber. The novel additive injection method, known as novel SEA2, is several orders of magnitude safer and less expensive than current SEA2 injection methods. However, used in conjunction with this plant configuration, the technology did not demonstrate a significant level of mercury reduction. Near-future use of this technique at Colstrip is not seen. All the additives injected resulted in some reduction in mercury emissions. However, the target reduction of 55% was not achieved. The primary reason for the lower removal rates is because of the lower levels of mercury in the flue gas stream and the lower capture level of fine particles by the scrubbers (relative to that for larger particles). The reaction and interaction of the SEA materials is with the finer fraction of the fly ash, because the SEA materials are vaporized during the combustion or reaction process and condense on the surfaces of entrained particles or form very small particles. Mercury will have a tendency to react and interact with the finer fraction of entrained ash and sorbent as a result of the higher surface areas of the finer particles. The ability to capture the finer fraction of fly ash is the key to controlling mercury. Cost estimates for mercury removal based on the performance of each sorbent during this project are projected to be extremely high. When viewed on a dollar-per-pound-of-mercury removed basis activated carbon was projected to cost nearly $1.2 million per pound of mercury removed. This value is roughly six times the cost of other sorbent-enhancing agents, which were projected to be closer to $200,000 per pound of mercury removed.

  12. An evaluation of elemental mercury vapor exposure to children due to silver-mercury dental amalgam restorations

    E-Print Network [OSTI]

    Taylor, Ronald Dale

    1989-01-01T23:59:59.000Z

    was shown to decrease an average of 33. 1% five minutes after cessation of stimulation. Elemental mercury vapor inhaled from dental restorations may be considered a function of such activities as chewing and eating patterns, oral-nasal breathing ratio... active ingredients for children than for adults. It is logical to conclude that the concerns for exposure to elemental mercury vapor include children because dental restorations are often performed during childhood. Many young individuals stimulate...

  13. Discharge lamp with reflective jacket

    DOE Patents [OSTI]

    MacLennan, Donald A. (Gaithersburg, MD); Turner, Brian P. (Damascus, MD); Kipling, Kent (Gaithersburg, MD)

    2001-01-01T23:59:59.000Z

    A discharge lamp includes an envelope, a fill which emits light when excited disposed in the envelope, a source of excitation power coupled to the fill to excite the fill and cause the fill to emit light, and a reflector disposed around the envelope and defining an opening, the reflector being configured to reflect some of the light emitted by the fill back into the fill while allowing some light to exit through the opening. The reflector may be made from a material having a similar thermal index of expansion as compared to the envelope and which is closely spaced to the envelope. The envelope material may be quartz and the reflector material may be either silica or alumina. The reflector may be formed as a jacket having a rigid structure which does not adhere to the envelope. The lamp may further include an optical clement spaced from the envelope and configured to reflect an unwanted component of light which exited the envelope back into the envelope through the opening in the reflector. Light which can be beneficially recaptured includes selected wavelength regions, a selected polarization, and selected angular components.

  14. Fluid jet electric discharge source

    DOE Patents [OSTI]

    Bender, Howard A. (Ripon, CA)

    2006-04-25T23:59:59.000Z

    A fluid jet or filament source and a pair of coaxial high voltage electrodes, in combination, comprise an electrical discharge system to produce radiation and, in particular, EUV radiation. The fluid jet source is composed of at least two serially connected reservoirs, a first reservoir into which a fluid, that can be either a liquid or a gas, can be fed at some pressure higher than atmospheric and a second reservoir maintained at a lower pressure than the first. The fluid is allowed to expand through an aperture into a high vacuum region between a pair of coaxial electrodes. This second expansion produces a narrow well-directed fluid jet whose size is dependent on the size and configuration of the apertures and the pressure used in the reservoir. At some time during the flow of the fluid filament, a high voltage pulse is applied to the electrodes to excite the fluid to form a plasma which provides the desired radiation; the wavelength of the radiation being determined by the composition of the fluid.

  15. Characterization of mercury-enriched coal combustion residues from electric utilities using enhanced sorbents for mercury control

    SciTech Connect (OSTI)

    Sanchez, F.; Keeney, R.; Kosson, D.; Delapp, R. [Vanderbilt University, Nashville, TN (United States). Dept. of Civil and Environmental Engineering

    2006-02-15T23:59:59.000Z

    This report evaluates changes that may occur to coal-fired power plant air pollution control residues from the use of activated carbon and other enhanced sorbents for reducing air emissions of mercury and evaluates the potential for captured pollutants leaching during the disposal or use of these residues. Leaching of mercury, arsenic, and selenium during land disposal or beneficial use of coal combustion residues (CCRs) is the environmental impact pathway evaluated in this report. Coal combustion residues refer collectively to fly ash and other air pollution control solid residues generated during the combustion of coal collected through the associated air pollution control system. This research is part of an on-going effort by US Environmental protection Agency (EPA) to use a holistic approach to account for the fate of mercury and other metals in coal throughout the life-cycle stages of CCR management. This report focuses on facilities that use injected sorbents for mercury control. It includes four facilities with activated carbon injection (ACI) and two facilities using brominated ACI. Fly ash has been obtained from each facility with and without operation of the sorbent injection technology for mercury control. Each fly ash sampled was evaluated in the laboratory for leaching as a function of pH and liquid-to-solid ratio. Mercury, arsenic and selenium were the primary constituent of interest; results for these elements are presented here. 30 refs., 30 figs., 14 tabs., 10 apps.

  16. Treatment of Mercury Contaminated Oil from Sandia National Laboratory

    SciTech Connect (OSTI)

    Klasson, KT

    2002-05-28T23:59:59.000Z

    First Article Tests of a stabilization method for greater than 260 mg mercury/kg oil were performed under a treatability study. This alternative treatment technology will address treatment of U.S. Department of Energy (DOE) organics (mainly used pump oil) contaminated with mercury and other heavy metals. Some of the oil is also co-contaminated with tritium, other radionuclides, and hazardous materials. The technology is based on contacting the oil with a sorbent powder (Self-Assembled Mercaptan on Mesoporous Support, SAMMS), proven to adsorb heavy metals, followed by stabilization of the oil/powder mixture using a stabilization agent (Nochar N990). Two variations of the treatment technology were included in the treatability study. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents [1]. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds [1] The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury. Nochar's N990 Petrobond (Nochar, Inc., Indianapolis, IN) is an oil stabilization agent, specifically formulated for stabilizing vacuum pump oil, which has fewer volatile organics than many other oils. This material is a non-uniform granular powder that resembles ground Styrofoam plastics. This material has previously been used by itself and in combination with SAMMS to stabilize oil containing low levels of mercury {approx}50 mg/kg in surrogate waste studies [2].

  17. Mercury in Fish Collected Upstream and Downstream of Los Alamos National Laboratory, New Mexico: 1991--2004.

    SciTech Connect (OSTI)

    P.R. Fresquez

    2004-10-15T23:59:59.000Z

    Small amounts of mercury (Hg) may exist in some canyon drainage systems within Los Alamos National Laboratory lands as a result of past discharges of untreated effluents. This paper reports on the concentrations of Hg in muscle (fillets) of various types of fish species collected downstream of LANL's influence from 1991 through 2004. The mean Hg concentration in fish from Cochiti reservoir (0.22 {micro}g/g wet weight), which is located downstream of LANL, was similar to fish collected from a reservoir upstream of LANL (Abiquiu) (0.26 {micro}g/g wet weight). Mercury concentrations in fish collected from both reservoirs exhibited significantly (Abiquiu = p < 0.05 and Cochiti = p < 0.10) decreasing trends over time. Predator fish like the northern pike (Esox lucius) contained significantly higher concentrations of Hg (0.39 {micro}g/g wet weight) than bottom-feeding fish like the white sucker (Catostomus commersoni) (0.10 {micro}g/g wet weight).

  18. EPA - Ground Water Discharges (EPA's Underground Injection Control...

    Open Energy Info (EERE)

    Discharges (EPA's Underground Injection Control Program) webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: EPA - Ground Water Discharges (EPA's...

  19. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    Sludge drying & inceneration plants 3200 gm/day In-Situ Oiloil shale plant is over four times the allowable mercury emission for mercury ore processing plants and sludge

  20. Quantifying the health and economic impacts of mercury : an integrated assessment approach

    E-Print Network [OSTI]

    Giang, Amanda (Amanda Chi Wen)

    2013-01-01T23:59:59.000Z

    Mercury is a toxic pollutant that endangers human and ecosystem health. Especially potent in the form of methyl mercury, exposure is known to lead to adverse neurological effects, and, a growing body of evidence suggests, ...

  1. Method and apparatus for controlling the flow rate of mercury in a flow system

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.

    1991-01-01T23:59:59.000Z

    This patent describes a process for increasing the mercury flow rate {ital Q{sub Hg}} to a photochemical mercury enrichment process. It comprises: utilizing an entrainment system having a temperature regulated pool of mercury, a bubbler or sparger system, and a carrier gas for entraining mercury vapor; passing the carrier gas over a pool of mercury maintained at a first temperature, T{sub 1} wherein the carrier gas entrains mercury vapor; and passing the mercury vapor entrained carrier gas to a second temperature zone, maintained at a temperature T{sub 2}, such that T{sub 2} is less than T{sub 1}, in which the entrained mercury vapor is condensed, thereby producing a saturated Hg conditioning the carrier gas; and passing the saturated Hg carrier gas to the photochemical enrichment reactor, yielding a high flow rate {ital Q{sub Hg}}.

  2. Argonne/EPA system captures mercury from air in gold shops |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the mercury vaporizes. The vaporized mercury is directed outside the shop into the open air where it descends onto homes, water and food of the local populations. Image credit:...

  3. REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION

    SciTech Connect (OSTI)

    John C. Kramlich; Rebecca N. Sliger

    2000-08-26T23:59:59.000Z

    Oxidized mercury has been shown to be more easily removed from power plant flue gas by existing air pollution control equipment (e.g., wet scrubbers) than elemental mercury. The factors that determine how mercury is converted to the oxidized form in practical systems are, however, unknown. The present research focuses on developing an elementary, homogeneous mechanism that describes the oxidation of mercury by chlorine species as it occurs in practical furnaces. The goal is to use this mechanism (1) as a component in an overall homogeneous/heterogeneous mechanism that describes mercury behavior, and (2) to suggest low cost/low impact means of promoting mercury oxidation in furnaces. The results suggest an important role for Hg+Cl {r_arrow} HgCl and HgCl + Cl {r_arrow} HgCl{sub 2}. Here, the Cl is derived by radical attack on HCl in the high-temperature environment. The results suggest that the oxidation occurs during the time that the gases cool to room temperature. The high Cl concentrations from the flame persist into the quench region and provide for the oxidation of Hg to HgCl{sub 2} under lower temperatures where the products are stable. Under this mechanism, no significant HgCl{sub 2} is actually present at the higher temperatures where oxidized mercury is often reported in the literature (e.g., 900 C). Instead, all oxidation occurs as these gases are quenched. The results suggest that means of promoting Cl concentrations in the furnace will increase oxidation.

  4. Mercury Methylation at Mercury Mines In The Humboldt River Basin, Nevada, USA

    SciTech Connect (OSTI)

    Gray, John E. (U.S. Geological Survey); Crock, James G. (U.S. Geological Survey); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

    2002-12-01T23:59:59.000Z

    Total Hg and methylmercury concentrations were measured in mine-waste calcines (retorted ore), sediment, and water samples collected in and around abandoned mercury mines in western Nevada to evaluate Hg methylation at the mines and in the Humboldt River basin. Mine-waste calcines contain total Hg concentrations as high as 14 000?g/g. Stream-sediment samples collected within 1 km of the mercury mines contain total Hg concentrations as high as 170?g/g, whereas stream sediments collected>5 km from the mines, and those collected from the Humboldt River and regional baseline sites, contain total Hg concentrations<0.5?g/g. Similarly, methylmercury concentrations in mine-waste calcines are locally as high as 96 ng/g, but methylmercury contents in stream-sediments collected downstream from the mines and from the Humboldt River are lower, ranging from<0.05 to 0.95 ng/g. Stream-water samples collected below two mines studied contain total Hg concentrations ranging from 6 to 2000 ng/L, whereas total Hg in Humboldt River water was generally lower ranging from 2.1 to 9.0 ng/L. Methylmercury concentrations in the Humboldt River water were the lowest in this study (<0.02-0.27 ng/L). Although total Hg and methylmercury concentrations are locally high in mine-waste calcines, there is significant dilution of Hg and lower Hg methylation down gradient from the mines, especially in the sediments and water collected from the Humboldt River, which is> 8 km from any mercury mines. Our data indicate little transference of Hg and methylmercury from the sediment to the water column due to the lack of mine runoff in this desert climate.

  5. Note: Production of a mercury beam with an electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Vondrasek, R.; Pardo, R.; Scott, R. [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)] [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)

    2013-11-15T23:59:59.000Z

    An electron cyclotron resonance ion source has been utilized to produce mercury beams with intensities of 4.5 e?A of {sup 202}Hg{sup 29+} and 3.0 e?A of {sup 202}Hg{sup 31+} from natural abundance mercury metal. The production technique relies on the evaporation of liquid mercury into the source plasma vacuum region and utilizes elemental mercury instead of a volatile organic compound as the neutral feed material.

  6. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  7. q < 1 discharges in Tokapole II

    SciTech Connect (OSTI)

    Osborne, T. H.; Dexter, R. N.; Prager, S. C.

    1981-01-01T23:59:59.000Z

    Observations are reported of discharges in which safety factor q values are obtained as low as 0.4 in Tokapole II, a tokamak with a four-node poloidal divertor configuration.

  8. Glow discharge plasma deposition of thin films

    DOE Patents [OSTI]

    Weakliem, Herbert A. (Pennington, NJ); Vossen, Jr., John L. (Bridgewater, NJ)

    1984-05-29T23:59:59.000Z

    A glow discharge plasma reactor for deposition of thin films from a reactive RF glow discharge is provided with a screen positioned between the walls of the chamber and the cathode to confine the glow discharge region to within the region defined by the screen and the cathode. A substrate for receiving deposition material from a reactive gas is positioned outside the screened region. The screen is electrically connected to the system ground to thereby serve as the anode of the system. The energy of the reactive gas species is reduced as they diffuse through the screen to the substrate. Reactive gas is conducted directly into the glow discharge region through a centrally positioned distribution head to reduce contamination effects otherwise caused by secondary reaction products and impurities deposited on the reactor walls.

  9. Environmental constituents of Electrical Discharge Machining

    E-Print Network [OSTI]

    Cho, Margaret H. (Margaret Hyunjoo), 1982-

    2004-01-01T23:59:59.000Z

    Electrical Discharge Machining (EDM) is a non-traditional process that uses no mechanical forces to machine metals. It is extremely useful in machining hard materials. With the advantages EDM has to offer and its presence ...

  10. Catalyst Additives to Enhance Mercury Oxidation and Capture

    SciTech Connect (OSTI)

    Thomas K. Gale

    2006-06-30T23:59:59.000Z

    Catalysis is the key fundamental ingredient to convert elemental mercury in coal-fired power stations into its oxidized forms that are more easily captured by sorbents, ESPs, baghouses, and wet scrubbers, whether the catalyst be unburned carbon (UBC) in the ash or vanadium pentoxide in SCR catalysts. This project has investigated several different types of catalysts that enhance mercury oxidation in several different ways. The stated objective of this project in the Statement of Objectives included testing duct-injection catalysts, catalyst-sorbent hybrids, and coated low-pressure-drop screens. Several different types of catalysts were considered for duct injection, including different forms of iron and carbon. Duct-injection catalysts would have to be inexpensive catalysts, as they would not be recycled. Iron and calcium had been shown to catalyze mercury oxidation in published bench-scale tests. However, as determined from results of an on-going EPRI/EPA project at Southern Research, while iron and calcium did catalyze mercury oxidation, the activity of these catalysts was orders of magnitude below that of carbon and had little impact in the short residence times available for duct-injected catalysts or catalyst-sorbent hybrids. In fact, the only catalyst found to be effective enough for duct injection was carbon, which is also used to capture mercury and remove it from the flue gas. It was discovered that carbon itself is an effective catalyst-sorbent hybrid. Bench-scale carbon-catalyst tests were conducted, to obtain kinetic rates of mercury adsorption (a key step in the catalytic oxidation of mercury by carbon) for different forms of carbon. All carbon types investigated behaved in a similar manner with respect to mercury sorption, including the effect of temperature and chlorine concentration. Activated carbon was more effective at adsorbing mercury than carbon black and unburned carbon (UBC), because their internal surface area of activated carbon was greater. Catalyst coating of low-pressure-drop screens was of particular interest as this project was being developed. However, it was discovered that URS was already heavily involved in the pursuit of this same technology, being funded by DOE, and reporting significant success. Hence, testing of SCR catalysts became a major focus of the project. Three different commercial SCR catalysts were examined for their ability to oxidize mercury in simulated flue-gas. Similar performance was observed from each of the three commercial catalysts, both in terms of mercury oxidation and SO{sub 3} generation. Ammonia injection hindered mercury oxidation at low HCl concentrations (i.e., {approx}2 ppmv), yet had little impact on mercury oxidation at higher HCl concentrations. On the other hand, SO{sub 2} oxidation was significantly reduced by the presence of ammonia at both low and high concentrations of HCl.

  11. ALTERNATIVE FIELD METHODS TO TREAT MERCURY IN SOIL

    SciTech Connect (OSTI)

    Ernie F. Stine

    2002-08-14T23:59:59.000Z

    The Department of Energy (DOE) currently has mercury (Hg) contaminated materials and soils at the various sites. Figure 1-1 (from http://www.ct.ornl.gov/stcg.hg/) shows the estimated distribution of mercury contaminated waste at the various DOE sites. Oak Ridge and Idaho sites have the largest deposits of contaminated materials. The majorities of these contaminated materials are soils, sludges, debris, and waste waters. This project concerns treatment of mercury contaminated soils. The technology is applicable to many DOE sites, in-particular, the Y-12 National Security Complex in Oak Ridge Tennessee and Idaho National Engineering and Environmental Laboratory (INEEL). These sites have the majority of the soils and sediments contaminated with mercury. The soils may also be contaminated with other hazardous metals and radionuclides. At the Y12 plant, the baseline treatment method for mercury contaminated soil is low temperature thermal desorption (LTTD), followed by on-site landfill disposal. LTTD is relatively expensive (estimated cost of treatment which exclude disposal cost for the collect mercury is greater than $740/per cubic yard [cy] at Y-12), does not treat any of the metal or radionuclides. DOE is seeking a less costly alternative to the baseline technology. As described in the solicitation (DE-RA-01NT41030), this project initially focused on evaluating cost-effective in-situ alternatives to stabilize or remove the mercury (Hg) contamination from high-clay content soil. It was believed that ex-situ treatment of soil contaminated with significant quantities of free-liquid mercury might pose challenges during excavation and handling. Such challenges may include controlling potential mercury vapors and containing liquid mercury beads. As described below, the focus of this project was expanded to include consideration of ex-situ treatment after award of the contract to International Technology Corporation (IT). After award of the contract, IT became part of Shaw E&I. The company will be denoted as ''IT'' for the rest of the document since the original contract was awarded to IT. This report details IT, Knoxville, TN and its subcontractor Nuclear Fuels Services (NFS) study to investigate alternative mercury treatment technology. The IT/NFS team demonstrated two processes for the amalgamation/stabilization/fixation of mercury and potentially Resource Conservation Recovery Act (RCRA) and radionuclide-contaminated soils. This project was to identify and demonstrate remedial methods to clean up mercury-contaminated soil using established treatment chemistries on soil from the Oak Ridge Reservation, Y-12 National Security Complex, the off-site David Witherspoon properties, and/or other similarly contaminated sites. Soil from the basement of Y-12 Plant Alpha 2 Building at the Oak Ridge Reservation was received at IT and NFS on December 20, 2001. Soils from the other locations were not investigated. The soil had background levels of radioactivity and had all eight RCRA metals well below the Toxicity Characteristic (TC) criteria. This project addresses the new DOE Environmental Management Thrust 2 ''Alternative Approaches to Current High Risk/High Cost Baselines''. Successful completion of this project will provide a step-change in DOE's treatment ability.

  12. Glow discharge based device for solving mazes

    SciTech Connect (OSTI)

    Dubinov, Alexander E., E-mail: dubinov-ae@yandex.ru; Mironenko, Maxim S.; Selemir, Victor D. [Russian Federal Nuclear Center ? All-Russian Scientific and Research Institute of Experimental Physics (RFNC-VNIIEF), Sarov, Nizhni Novgorod region 607188 (Russian Federation); Sarov Institute of Physics and Technology (SarFTI) of National Research Nuclear University “MEPhI,” Sarov, Nizhni Novgorod region 607188 (Russian Federation); Maksimov, Artem N.; Pylayev, Nikolay A. [Russian Federal Nuclear Center ? All-Russian Scientific and Research Institute of Experimental Physics (RFNC-VNIIEF), Sarov, Nizhni Novgorod region 607188 (Russian Federation)

    2014-09-15T23:59:59.000Z

    A glow discharge based device for solving mazes has been designed and tested. The device consists of a gas discharge chamber and maze-transformer of radial-azimuth type. It allows changing of the maze pattern in a short period of time (within several minutes). The device has been tested with low pressure air. Once switched on, a glow discharge has been shown to find the shortest way through the maze from the very first attempt, even if there is a section with potential barrier for electrons on the way. It has been found that ionization waves (striations) can be excited in the maze along the length of the plasma channel. The dependancy of discharge voltage on the length of the optimal path through the maze has been measured. A reduction in discharge voltage with one or two potential barriers present has been found and explained. The dependency of the magnitude of discharge ignition voltage on the length of the optimal path through the maze has been measured. The reduction of the ignition voltage with the presence of one or two potential barriers has been observed and explained.

  13. The control of mercury vapor using biotrickling filters Ligy Philip a,b,1

    E-Print Network [OSTI]

    The control of mercury vapor using biotrickling filters Ligy Philip a,b,1 , Marc A. Deshusses b mechanisms existed. Sulfur oxidizing bacteria biotrickling filters were the most effective in controlling phase bioreactor; Mercury control; Combustion gases 1. Introduction Mercury (Hg) is a hazardous chemical

  14. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

    2006-10-10T23:59:59.000Z

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  15. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08T23:59:59.000Z

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  16. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Huang, Hann-Sheng (Darien, IL)

    1999-01-01T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

  17. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  18. Mercury Oxidation via Catalytic Barrier Filters Phase II

    SciTech Connect (OSTI)

    Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

    2007-09-30T23:59:59.000Z

    In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

  19. Progress in Creating Stabilized Gas Layers in Flowing Liquid Mercury

    SciTech Connect (OSTI)

    Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL; Abdou, Ashraf A [ORNL; D'Urso, Brian R [ORNL; West, David L [ORNL

    2009-01-01T23:59:59.000Z

    The Spallation Neutron Source (SNS) facility in Oak Ridge, Tennessee uses a liquid mercury target that is bombarded with protons to produce a pulsed neutron beam for materials research and development. In order to mitigate expected cavitation damage erosion (CDE) of the containment vessel, a two-phase flow arrangement of the target has been proposed and was earlier proven to be effective in significantly reducing CDE in non-prototypical target bodies. This arrangement involves covering the beam "window", through which the high-energy proton beam passes, with a protective layer of gas. The difficulty lies in establishing a stable gas/liquid interface that is oriented vertically with the window and holds up to the strong buoyancy force and the turbulent mercury flow field. Three approaches to establishing the gas wall have been investigated in isothermal mercury/gas testing on a prototypical geometry and flow: (1) free gas layer approach, (2) porous wall approach, and (3) surface-modified approach. The latter two of these approaches show success in that a stabilized gas layer is produced. Both of these successful approaches capitalize on the high surface energy of liquid mercury by increasing the surface area of the solid wall, thus increasing gas hold up at the wall. In this paper, a summary of these experiments and findings is presented as well as a description of the path forward toward incorporating the stabilized gas layer approach into a feasible gas/mercury SNS target design.

  20. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

    2003-02-18T23:59:59.000Z

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  1. REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION

    SciTech Connect (OSTI)

    John C. Kramlich; Rebecca N. Sliger; David J. Going

    1999-08-06T23:59:59.000Z

    Mercury emission compliance presents one of the major potential challenges raised by the 1990 Clean Air Act Amendments. Simple ways of controlling emissions have not been identified. The variability in the field data suggest that inherent mercury emissions may be reduced if the source of this inherent capture can be identified and controlled. The key mechanisms appear to involve the oxidation of mercury to Hg{sup 2}, generally producing the more reactive HgCl{sub 2}, followed by its capture by certain components of the fly ash or char, or in the air pollution control equipment. This research focuses on identifying the rate-limiting steps associated with the oxidation step. Work in this reporting period focused on the refinement of the rate constants used in the kinetic mechanism for mercury oxidation. The possible reactions leading to mercury oxidation are reviewed. Rate constants for these reactions are discussed, using both literature sources and detailed estimates. The resulting mechanism represents the best present picture of the overall chlorine homogeneous oxidation chemistry. Application of this mechanism to the data will be explored in the subsequent reporting period. Work conducted under the present grant has been the subject of two meeting papers presented during the reporting period (Sliger et al., 1998a,b).

  2. Low-Cost Options for Moderate Levels of Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2006-03-31T23:59:59.000Z

    On March 15, 2005, EPA issued the Clean Air Mercury Rule, requiring phased-in reductions of mercury emissions from electric power generators. ADA-ES, Inc., with support from DOE/NETL and industry partners, is conducting evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. DOE/NETL targets for total mercury removal are {ge}55% (lignite), {ge}65% (subbituminous), and {ge}80% (bituminous). Based on work done to date at various scales, meeting the removal targets appears feasible. However, work needs to progress to more thoroughly document and test these promising technologies at full scale. This is the final site report for tests conducted at MidAmerican's Louisa Station, one of three sites evaluated in this DOE/NETL program. The other two sites in the program are MidAmerican's Council Bluff Station and Entergy's Independence Station. MidAmerican's Louisa Station burns Powder River Basin (PRB) coal and employs hot-side electrostatic precipitators with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal.

  3. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect (OSTI)

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie [University of Michigan, Ann Arbor, MI (United States). Department of Geological Sciences

    2008-11-15T23:59:59.000Z

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  4. The thief process for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Freeman, M.C.; Hargis, R.A.; O'Dowd, W.J.; Pennline, H.W.

    2007-09-01T23:59:59.000Z

    The Thief Process is a cost-effective variation to activated carbon injection (ACI) for removal of mercury from flue gas. In this scheme, partially combusted coal from the furnace of a pulverized coal power generation plant is extracted by a lance and then re-injected into the ductwork downstream of the air preheater. Recent results on a 500-lb/h pilot-scale combustion facility show similar removals of mercury for both the Thief Process and ACI. The tests conducted to date at laboratory, bench, and pilot-scales demonstrate that the Thief sorbents exhibit capacities for mercury from flue gas streams that are comparable to those exhibited by commercially available activated carbons. A patent for the process was issued in February 2003. The Thief sorbents are cheaper than commercially-available activated carbons; exhibit excellent capacities for mercury; and the overall process holds great potential for reducing the cost of mercury removal from flue gas. The Thief Process was licensed to Mobotec USA, Inc. in May of 2005.

  5. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    2000-04-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, the capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons as well as novel sorbents were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  6. Magnetic dipole discharges. II. Cathode and anode spot discharges and probe diagnostics

    SciTech Connect (OSTI)

    Stenzel, R. L.; Urrutia, J. M. [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States)] [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States); Ionita, C.; Schrittwieser, R. [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)] [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)

    2013-08-15T23:59:59.000Z

    The high current regime of a magnetron-type discharge has been investigated. The discharge uses a permanent magnet as a cold cathode which emits secondary electrons while the chamber wall or a grounded electrode serves as the anode. As the discharge voltage is increased, the magnet develops cathode spots, which are short duration arcs that provide copious electrons to increase the discharge current dramatically. Short (1 ?s), high current (200 A) and high voltage (750 V) discharge pulses are produced in a relaxation instability between the plasma and a charging capacitor. Spots are also observed on a negatively biased plane Langmuir probe. The probe current pulses are as large as those on the magnet, implying that the high discharge current does not depend on the cathode surface area but on the properties of the spots. The fast current pulses produce large inductive voltages, which can reverse the electrical polarity of the magnet and temporarily operate it as an anode. The discharge current may also oscillate at the frequency determined by the charging capacitor and the discharge circuit inductance. Each half cycle of high-current current pulses exhibits a fast (?10 ns) current rise when a spot is formed. It induces high frequency (10–100 MHz) transients and ringing oscillations in probes and current circuits. Most probes behave like unmatched antennas for the electromagnetic pulses of spot discharges. Examples are shown to distinguish the source of oscillations and some rf characteristics of Langmuir probes.

  7. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31T23:59:59.000Z

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  8. MERCURY LEVELS IN HAWAIIAN PREDATORY PEI-AGIC FISHES AND THEIR PREY ASA FUNCTION OF DEPTH AND ECOLOGY

    E-Print Network [OSTI]

    Luther, Douglas S.

    ,and location of captute, hower.ef, details regardrngthe nature of mercury bioaccumulationareincomplcte

  9. Clean Air Mercury Rule (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01T23:59:59.000Z

    On February 8, 2008, a three-judge panel on the D.C. Circuit of the U.S. Court of Appeals issued a decision to vacate the Clean Air Mercury Rule (CAMR). In its ruling, the panel cited the history of hazardous air pollutant regulation under Section 112 of the Clean Air Act (CAA). Section 112, as written by Congress, listed emitted mercury as a hazardous air pollutant that must be subject to regulation unless it can be proved harmless to public welfare and the environment. In 2000, the Environmental Protection Agency ruled that mercury was indeed hazardous and must be regulated under Section 112 and, therefore, subjected to the best available control technology for mitigation.

  10. Mercury capture by distinct fly ash carbon forms

    SciTech Connect (OSTI)

    Hower, J.C.; Maroto-Valer, M.M.; Taulbee, D.N.; Sakulpitakphon, T.

    1999-07-01T23:59:59.000Z

    Carbon was separated from the fly ash from a Kentucky power plant using density gradient centrifugation. Using a lithium heterolpolytungstate high-density media, relative concentrations of inertinite (up to 85% vol.), isotropic carbon (up to 79% vol.), and anisotropic carbon (up to 76% vol.) were isolated from the original fly ash. Mercury concentration was lowest in the parent fly ash (which contains non-carbon components); followed by inertinite, isotropic coke, mixed isotropic-anisotropic coke fraction, and, with the highest concentration, the anisotropic coke concentrate. The latter order corresponds to the increase in BET surface area of the fly ash carbons. Previous studies have demonstrated the capture of mercury by fly ash carbon. This study confirms prior work demonstrating the varying role of carbon types in the capture, implying that variability in the carbon content influences the amount of mercury retained on the fly ash.

  11. Catalysts for oxidation of mercury in flue gas

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2010-08-17T23:59:59.000Z

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  12. Helium and mercury in the central Seward Peninsula

    SciTech Connect (OSTI)

    Wescott, E.; Ruscetta, C.A.; Foley, D. (eds.)

    1981-05-01T23:59:59.000Z

    The central Seward Peninsula, Alaska, has one Known Geothermal Resource Area (KGRA) at Pilgrim Springs, and has recent volcanic flows, fault systems, topographic and tectonic features which can be explained by a rift model. As part of a geothermal reconnaissance of the area we used helium and mercury concentrations in soil as indicators of geothermal resources. The largest helium concentrations were found in the vicinity of the Pilgrims Springs KGRA, and indicate prime drilling sites. Five profile lines were run across the suspected rift system. Significant helium anomalies were found on several of the traverses, where future exploration might be concentrated. Mercury values showed a great range of variability on the traverses, and seem unreliable as geothermal indicators except in the vicinity of the Pilgrim Springs. Permafrost at the surface resulting in variations in sampling depth may contribute to the mercury variations.

  13. DIRECT MEASUREMENT OF MERCURY REACTIONS IN COAL POWER PLANT PLUMES

    SciTech Connect (OSTI)

    Leonard Levin

    2006-06-01T23:59:59.000Z

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-02NT41422 and specifically addresses Program Area of Interest: No.5--Environmental and Water Resources. The project team includes the Electric Power Research Institute (EPRI) as the contractor and the University of North Dakota Energy & Environmental Research Center (EERC) and Frontier Geosciences as subcontractors. Wisconsin Energies and its Pleasant Prairie Power Plant acted as host for the field-testing portion of the research. The project is aimed at clarifying the role, rates, and end results of chemical transformations that may occur to mercury that has been emitted from elevated stacks of coal-fired electric power plants. Mercury emitted from power plants emerges in either its elemental, divalent, or particulate-bound form. Deposition of the divalent form is more likely to occur closer to the source than that of the other two forms, due to its solubility in water. Thus, if chemical transformations occur in the stack emissions plume, measurements in the stack may mischaracterize the fate of the material. Initial field and pilot plant measurements have shown significant and rapid chemical reduction of divalent to elemental mercury may occur in these plumes. Mercury models currently assume that the chemical form of mercury occurring in stacks is the same as that which enters the free atmosphere, with no alteration occurring in the emissions plume. Recent data indicate otherwise, but need to be evaluated at full operating scale under field conditions. Prestbo and others have demonstrated the likelihood of significant mercury chemical reactions occurring in power plant plumes (Prestbo et al., 1999; MDNR-PPRP, 2000; EERC, 2001). This experiment will thus increase our understanding of mercury atmospheric chemistry, allowing informed decisions regarding source attribution. The experiment was carried out during the period August 22-September 5, 2003. The experimental site was the Pleasant Prairie Power Plant in Pleasant Prairie, Wisconsin, just west of Kenosha. The experiment involved using an aircraft to capture emissions and document chemistry changes in the plume. While using the airplane for sampling, supplemental fast-response sensors for NOx, connected to data loggers, were used to gauge entry and exit times and transect intervals through plume emissions material. The Frontier Geosciences Static Plume Dilution Chamber (SPDC) was employed simultaneously adjacent to the stack to correlate its findings with the aircraft sampling, as well as providing evaluation of the SPDC as a rapid, less costly sampler for mercury chemistry. A complementary stack plume method, the Dynamic Plume Dilution (DPD) was used in the latter portion of the experiment to measure mercury speciation to observe any mercury reduction reaction with respect to both the reaction time (5 to 30 seconds) and dilution ratio. In addition, stack sampling using the ''Ontario Hydro'' wet chemistry method and continuous mercury monitors (CMM) were used to establish the baseline chemistry in the stack. Comparisons among stack, SPDC, DPD and aircraft measurements allow establishment of whether significant chemical changes to mercury occur in the plume, and of the verisimilitude of the SPDC and DPD methods. This progress report summarizes activities during a period of results review from the stack/aircraft subcontractor, data analysis and synthesis, and preparation and presentation of preliminary results to technical and oversight meetings.

  14. Measurements of Gas Bubble Size Distributions in Flowing Liquid Mercury

    SciTech Connect (OSTI)

    Wendel, Mark W [ORNL; Riemer, Bernie [ORNL; Abdou, Ashraf A [ORNL

    2012-01-01T23:59:59.000Z

    ABSTRACT Pressure waves created in liquid mercury pulsed spallation targets have been shown to induce cavitation damage on the target container. One way to mitigate such damage would be to absorb the pressure pulse energy into a dispersed population of small bubbles, however, measuring such a population in mercury is difficult since it is opaque and the mercury is involved in a turbulent flow. Ultrasonic measurements have been attempted on these types of flows, but the flow noise can interfere with the measurement, and the results are unverifiable and often unrealistic. Recently, a flow loop was built and operated at Oak Ridge National Labarotory to assess the capability of various bubbler designs to deliver an adequate population of bubbles to mitigate cavitation damage. The invented diagnostic technique involves flowing the mercury with entrained gas bubbles in a steady state through a horizontal piping section with a glass-window observation port located on the top. The mercury flow is then suddenly stopped and the bubbles are allowed to settle on the glass due to buoyancy. Using a bright-field illumination and a high-speed camera, the arriving bubbles are detected and counted, and then the images can be processed to determine the bubble populations. After using this technique to collect data on each bubbler, bubble size distributions were built for the purpose of quantifying bubbler performance, allowing the selection of the best bubbler options. This paper presents the novel procedure, photographic technique, sample visual results and some example bubble size distributions. The best bubbler options were subsequently used in proton beam irradiation tests performed at the Los Alamos National Laboratory. The cavitation damage results from the irradiated test plates in contact with the mercury are available for correlation with the bubble populations. The most effective mitigating population can now be designed into prototypical geometries for implementation into an actual SNS target.

  15. REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION

    SciTech Connect (OSTI)

    John C. Kramlich; Rebecca N. Sliger; David J. Going

    1999-08-06T23:59:59.000Z

    Mercury emission compliance presents one of the major potential challenges raised by the 1990 Clean Air Act Amendments. Simple ways of controlling emissions have not been identified. The variability in the field data suggest that inherent mercury emissions may be reduced if the source of this inherent capture can be identified and controlled. The key mechanisms appear to involve the oxidation of mercury to Hg{sup 2}, generally producing the more reactive HgCl{sub 2}, followed by its capture by certain components of the fly ash or char, or in the air pollution control equipment. This research focuses on identifying the rate-limiting steps associated with the oxidation step. Work in this reporting period focused on testing of the kinetic mechanism reported in the previous semiannual report, and the interpretation of data (both ours and literature). This model yields good qualitative agreement with the data and indicates that mercury oxidation occurs during the thermal quench of the combustion gases. The model also suggests that atomic chlorine is the key oxidizing species. The oxidation is limited to a temperature window between 700-400 C that is defined by the overlap of (1) a region of significant superequilibrium Cl concentration, and (2) a region where oxidized mercury is favored by equilibrium. Above 700 C reverse reactions effectively limit oxidized mercury concentrations. Below 400 C, atomic chlorine concentrations are too low to support further oxidation. The implication of these results are that homogeneous oxidation is governed primarily by (1) HCl concentration, (2) quench rate, and (3) background gas composition. Work conducted under the present grant has been the subject of one journal paper that was accepted for publication during the reporting period (Sliger et al., 1999).

  16. Atmospheric Mercury Concentrations Near Salmon Falls Creek Reservoir - Phase 1

    SciTech Connect (OSTI)

    M. L. Abbott

    2005-10-01T23:59:59.000Z

    Elemental and reactive gaseous mercury (EGM/RGM) were measured in ambient air concentrations over a two-week period in July/August 2005 near Salmon Falls Creek Reservoir, a popular fishery located 50 km southwest of Twin Falls, Idaho. A fish consumption advisory for mercury was posted at the reservoir in 2002 by the Idaho Department of Health and Welfare. The air measurements were part of a multi-media (water, sediment, precipitation, air) study initiated by the Idaho Department of Environmental Quality and the U.S. Environmental Protection Agency (EPA) Region 10 to identify potential sources of mercury contamination to the reservoir. The sampling site is located about 150 km northeast of large gold mining operations in Nevada, which are known to emit large amounts of mercury to the atmosphere (est. 2,200 kg/y from EPA 2003 Toxic Release Inventory). The work was co-funded by the Idaho National Laboratory’s Community Assistance Program and has a secondary objective to better understand mercury inputs to the environment near the INL, which lies approximately 230 km to the northeast. Sampling results showed that both EGM and RGM concentrations were significantly elevated (~ 30 – 70%, P<0.05) compared to known regional background concentrations. Elevated short-term RGM concentrations (the primary form that deposits) were likely due to atmospheric oxidation of high EGM concentrations, which suggests that EGM loading from upwind sources could increase Hg deposition in the area. Back-trajectory analyses indicated that elevated EGM and RGM occurred when air parcels came out of north-central and northeastern Nevada. One EGM peak occurred when the air parcels came out of northwestern Utah. Background concentrations occurred when the air was from upwind locations in Idaho (both northwest and northeast). Based on 2003 EPA Toxic Release Inventory data, it is likely that most of the observed peaks were from Nevada gold mine sources. Emissions from known large natural mercury sources in that area cannot account for the observed EGM peaks due to their diffuse source geometry and the large (170 km) transport distance involved. The EGM peak originating from northwestern Utah air may be from three known mercury sources west of Salt Lake City (Kennecott, US Magnesium, Clean Harbors Aragonite) and/or the 1600 MW coal-fired Intermountain Power plant near Delta. However, the relative importance of these short-term peaks for long-term watershed mercury loading (critical factor affecting fish concentrations) is not known, and there is a need to better quantify the annual frequency and magnitude of these different inputs over a longer period of time.

  17. A study of the solubility of mercury in liquid hydrocarbons

    E-Print Network [OSTI]

    McFarlane, David Larimer

    1991-01-01T23:59:59.000Z

    mercury by precipitating HgS out of solution and measuring the metcury activity on a Gieger counter. A second but similar method used by Moser and Voigt used metallic Hg&cs which was obtained by reduction of mercumus nitrate with hypophosphorus acid...A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARIhKR MCFARLANE Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  18. Analytical Methods for Measuring Mercury in Water, Sediment and Biota

    SciTech Connect (OSTI)

    Lasorsa, Brenda K.; Gill, Gary A.; Horvat, Milena

    2012-06-07T23:59:59.000Z

    Mercury (Hg) exists in a large number of physical and chemical forms with a wide range of properties. Conversion between these different forms provides the basis for mercury's complex distribution pattern in local and global cycles and for its biological enrichment and effects. Since the 1960’s, the growing awareness of environmental mercury pollution has stimulated the development of more accurate, precise and efficient methods of determining mercury and its compounds in a wide variety of matrices. During recent years new analytical techniques have become available that have contributed significantly to the understanding of mercury chemistry in natural systems. In particular, these include ultra sensitive and specific analytical equipment and contamination-free methodologies. These improvements allow for the determination of total mercury as well as major species of mercury to be made in water, sediments and soils, and biota. Analytical methods are selected depending on the nature of the sample, the concentration levels of mercury, and what species or fraction is to be quantified. The terms “speciation” and “fractionation” in analytical chemistry were addressed by the International Union for Pure and Applied Chemistry (IUPAC) which published guidelines (Templeton et al., 2000) or recommendations for the definition of speciation analysis. "Speciation analysis is the analytical activity of identifying and/or measuring the quantities of one or more individual chemical species in a sample. The chemical species are specific forms of an element defined as to isotopic composition, electronic or oxidation state, and/or complex or molecular structure. The speciation of an element is the distribution of an element amongst defined chemical species in a system. In case that it is not possible to determine the concentration of the different individual chemical species that sum up the total concentration of an element in a given matrix, meaning it is impossible to determine the speciation, it is a useful practice to do fractionation instead. Fractionation is the process of classification of an analyte or a group of analytes from a certain sample according to physical (e.g. size, solubility) or chemical (e.g. bonding, reactivity) properties."

  19. A survey of mercury in the Gulf of Mexico

    E-Print Network [OSTI]

    Custodi, George Louis

    1971-01-01T23:59:59.000Z

    and a dual channel atomic absorp- tion spectrophotcmeter with autcmatic bacI:-gz ound cor ection The sensitivity of the analyses was les . 0 ~ 03 pg HggL with a. relative precision of + 1. 6: at 0, & p~ IIg/L. A zone of, high concentration... River were highes averaging 0 ~ "ig p:s/L, indicating that the Mississipni River, because of its high annual volume, is a major source of mercury for the Gulf with other rivers being minor contributors' mercury analyses of sediments showed...

  20. Mercury cleanup efforts intensify | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from aRod EggertMercury cleanup efforts ... Mercury

  1. Optimizing Technology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-01-31T23:59:59.000Z

    Revised maps and associated data show potential mercury, sulfur, and chlorine emissions for U.S. coal by county of origin. Existing coal mining and coal washing practices result in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Selection of low-mercury coal is a good mercury control option for plants having hot-side ESP, cold-side ESP, or hot-side ESP/FGD emission controls. Chlorine content is more important for plants having cold-side ESP/FGD or SDA/FF controls; optimum net mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions.

  2. Central peaking of magnetized gas discharges

    SciTech Connect (OSTI)

    Chen, Francis F. [Electrical Engineering Department, University of California, Los Angeles, California 90095 (United States)] [Electrical Engineering Department, University of California, Los Angeles, California 90095 (United States); Curreli, Davide [Department of Nuclear, Plasma and Radiological Engineering, University of Illinois at Urbana Champaign, Urbana, Illinois 61801 (United States)] [Department of Nuclear, Plasma and Radiological Engineering, University of Illinois at Urbana Champaign, Urbana, Illinois 61801 (United States)

    2013-05-15T23:59:59.000Z

    Partially ionized gas discharges used in industry are often driven by radiofrequency (rf) power applied at the periphery of a cylinder. It is found that the plasma density n is usually flat or peaked on axis even if the skin depth of the rf field is thin compared with the chamber radius a. Previous attempts at explaining this did not account for the finite length of the discharge and the boundary conditions at the endplates. A simple 1D model is used to focus on the basic mechanism: the short-circuit effect. It is found that a strong electric field (E-field) scaled to electron temperature T{sub e}, drives the ions inward. The resulting density profile is peaked on axis and has a shape independent of pressure or discharge radius. This “universal” profile is not affected by a dc magnetic field (B-field) as long as the ion Larmor radius is larger than a.

  3. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    SciTech Connect (OSTI)

    Charles Mones

    2006-12-01T23:59:59.000Z

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

  4. Residual dust charges in discharge afterglow

    SciTech Connect (OSTI)

    Coueedel, L.; Mikikian, M.; Boufendi, L.; Samarian, A. A. [GREMI - Groupe de Recherches sur l'Energetique des Milieux Ionises, CNRS/Universite d'Orleans, 14 rue d'Issoudun, 45067 Orleans Cedex 2 (France); School of Physics A28, University of Sydney, NSW 2006 (Australia)

    2006-08-15T23:59:59.000Z

    An on-ground measurement of dust-particle residual charges in the afterglow of a dusty plasma was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force. It was found that positively charged, negatively charged, and neutral dust particles coexisted for more than 1 min after the discharge was switched off. The mean residual charge for 200-nm-radius particles was measured. The dust particle mean charge is about -5e at a pressure of 1.2 mbar and about -3e at a pressure of 0.4 mbar.

  5. Emerging technologies and approaches to minimize discharges into Lake Michigan Phase 2, Module 3 report.

    SciTech Connect (OSTI)

    Negri, M. C.; Gillenwater, P.; Urgun Demirtas, M. (Energy Systems)

    2011-05-11T23:59:59.000Z

    Purdue University Calumet (Purdue) and Argonne National Laboratory (Argonne) have conducted an independent study to identify deployable technologies that could help the BP Whiting Refinery, and other petroleum refineries, meet future wastewater discharge limits. This study has been funded by BP. Each organization tested a subset of the target technologies and retains sole responsibility for its respective test design and implementation, quality assurance and control, test results obtained from each of the technologies, and corresponding conclusions and recommendations. This project was divided in two phases and modules. This report summarizes the work conducted by Argonne in Phase II Module 3 (Bench Scale Testing). Other Modules are discussed elsewhere (Emerging Technologies and Approaches to Minimize Discharges into Lake Michigan, Phase 2, Modules 1-3 Report, April 2011, prepared for BP Americas by the Argonne - Purdue Task Force). The goal of this project was to identify and assess available and emerging wastewater treatment technologies for removing mercury and vanadium from the Whiting Refinery wastewater and to conduct bench-scale tests to provide comparable, transparent, and uniform results across the broad range of technologies tested. After the bench-scale testing phase, a previously developed decision matrix was refined and applied by Argonne to process and review test data to estimate and compare the preliminary performance, engineering configuration, preliminary cost, energy usage, and waste generation of technologies that were shown to be able to remove Hg and/or V to below the target limit at the bench scale. The data were used as the basis to identify the best candidates for further testing at the bench or pilot scale on a slip stream of effluent to lake (ETL) or clarifier effluent (CE) at the Whiting Refinery to determine whether future limits could be met and to generate other pertinent data for scale-up and sustainability evaluation. As a result of this technology assessment, Argonne identified several technologies that, at the bench-scale, could achieve the targeted performance for the removal of mercury and vanadium. A subset of those technologies were recommended for further testing either at the bench scale or at the pilot scale to determine whether future discharge limits could be met at the pilot-scale. The objectives of this project module are to: (1) Test at the bench-scale a subset of the technologies previously identified in Module 1 for the removal of target heavy metals down to 1.3 ppt Hg and 280 ppb V; (2) Review and process bench-scale test results on the basis of the end-point performance measures matrix to determine preliminary comparative performance, cost-effectiveness, and potential engineering configuration of tested technologies; (3) Assess the technological feasibility and readiness of the identified technologies for implementation at the Whiting Refinery; and (4) Select technically and economically feasible mercury- and vanadium-removal technologies and vendors to be recommended for pilot-scale testing at the Whiting Refinery.

  6. Impact of Surface Heterogeneity on Mercury Uptake by Carbonaceous

    E-Print Network [OSTI]

    Borguet, Eric

    pyrolytic graphite, HOPG) under ultrahigh vacuum (UHV) conditions and fixed bed adsorption by activated to the environment from fossil fuel burning and various combustion processes (i.e., mu- nicipal, medical combustion. Once emitted to the environment, mercury can be deposited locally or globally to create a long

  7. Gas Bubble Formation in Stagnant and Flowing Mercury

    SciTech Connect (OSTI)

    Wendel, Mark W [ORNL] [ORNL; Abdou, Ashraf A [ORNL] [ORNL; Riemer, Bernie [ORNL] [ORNL; Felde, David K [ORNL] [ORNL

    2007-01-01T23:59:59.000Z

    Investigations in the area of two-phase flow at the Oak Ridge National Laboratory's (ORNL) Spallation Neutron Source (SNS) facility are progressing. It is expected that the target vessel lifetime could be extended by introducing gas into the liquid mercury target. As part of an effort to validate the two-phase computational fluid dynamics (CFD) model, simulations and experiments of gas injection in stagnant and flowing mercury have been completed. The volume of fluid (VOF) method as implemented in ANSYS-CFX, was used to simulate the unsteady two-phase flow of gas injection into stagnant mercury. Bubbles produced at the upwards-oriented vertical gas injector were measured with proton radiography at the Los Alamos Neutron Science Center. The comparison of the CFD results to the radiographic images shows good agreement for bubble sizes and shapes at various stages of the bubble growth, detachment, and gravitational rise. Although several gas flows were measured, this paper focuses on the case with a gas flow rate of 8 cc/min through the 100-micron-diameter injector needle. The acoustic waves emitted due to the detachment of the bubble and during subsequent bubble oscillations were recorded with a microphone, providing a precise measurement of the bubble sizes. As the mercury flow rate increases, the drag force causes earlier bubble detachment and therefore smaller bubbles.

  8. Numerical Simulation of Bubble Formation in Co-Flowing Mercury

    SciTech Connect (OSTI)

    Abdou, Ashraf A [ORNL; Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL

    2008-01-01T23:59:59.000Z

    In this work, we present computational fluid dynamics (CFD) simulations of helium bubble formation and detachment at a submerged needle in stagnant and co-flowing mercury. Since mercury is opaque, visualization of internal gas bubbles was done with proton radiography (pRad) at the Los Alamos Neutron Science Center (LANSCE2). The acoustic waves emitted at the time of detachment and during subsequent oscillations of the bubble were recorded with a microphone. The Volume of Fluid (VOF) model was used to simulate the unsteady two-phase flow of gas injection in mercury. The VOF model is validated by comparing detailed bubble sizes and shapes at various stages of the bubble growth and detachment, with the experimental measurements at different gas flow rates and mercury velocities. The experimental and computational results show a two-stage bubble formation. The first stage involves growing bubble around the needle, and the second follows as the buoyancy overcomes wall adhesion. The comparison of predicted and measured bubble sizes and shapes at various stages of the bubble growth and detachment is in good agreement.

  9. Atmospheric Mercury Deposition Impacts of Future Electric Power Generation

    E-Print Network [OSTI]

    , a number of scenarios for future emissions from coal-fired electricity generation plants in the UnitedAtmospheric Mercury Deposition Impacts of Future Electric Power Generation Mark D. Cohen Physical on 2000 data submitted to Environment Canada's National Pollutant Release Inventory (NPRI). Finally

  10. Cage diffusion in liquid mercury Yaspal S. Badyal

    E-Print Network [OSTI]

    Montfrooij, Wouter

    University, Massachusetts 02138, USA Ignatz M. de Schepper Interfaculty Reactor Institute, TU Delft, 2629 JB(q,E). It is believed that cage diffusion plays an important part in the dynamics of real fluids, such as noble gas on the fast short-time decay mechanism of liquid mercury pertinent to cage diffu- sion. Recent neutron

  11. Contaminated identities: Mercury and marginalization in Ghana's artisanal mining sector

    E-Print Network [OSTI]

    Singha, Kamini

    mining; Political ecology; Ecohealth; Environmental justice; Ghana 1. Introduction Artisanal and smallContaminated identities: Mercury and marginalization in Ghana's artisanal mining sector Petra and multifaceted policy problem that underlies the current conflictual aspects in the small-scale mining sector

  12. MERCURY IN THE ENVIRONMENT: Transport, Fate and Policy

    E-Print Network [OSTI]

    Selin, Noelle Eckley

    Division and Department of Earth, Atmospheric and Planetary Sciences Massachusetts Institute of Technology increased 3-5X since industrialization Major anthropogenic source is stationary combustion (coal evidence to warrant international action U.S.: Clean Air Mercury Rule: established "cap and trade" approach

  13. Final Report - Molecular Mechanisms of Bacterial Mercury Transformation - UCSF

    SciTech Connect (OSTI)

    Miller, Susan M. [UCSF

    2014-04-24T23:59:59.000Z

    The bacterial mercury resistance (mer) operon functions in Hg biogeochemistry and bioremediation by converting reactive inorganic Hg(II) and organic [RHg(II)]1+ mercurials to relatively inert monoatomic mercury vapor, Hg(0). Its genes regulate operon expression (MerR, MerD, MerOP), import Hg(II) (MerT, MerP, and MerC), and demethylate (MerB) and reduce (MerA) mercurials. We focus on how these components interact with each other and with the host cell to allow cells to survive and detoxify Hg compounds. Understanding how this ubiquitous detoxification system fits into the biology and ecology of its bacterial host is essential to guide interventions that support and enhance Hg remediation. In the current overall project we focused on two aspects of this system: (1) investigations of the energetics of Hg(II)-ligand binding interactions, and (2) both experimental and computational approaches to investigating the molecular mechanisms of Hg(II) acquisition by MerA and intramolecular transfer of Hg(II) prior to reduction within the MerA enzyme active site. Computational work was led by Prof. Jeremy Smith and took place at the University of Tennessee, while experimental work on MerA was led by Prof. Susan Miller and took place at the University of California San Francisco.

  14. A Cavity Ring-Down Spectroscopy Mercury Continuous Emission Monitor

    SciTech Connect (OSTI)

    Christopher C. Carter

    2004-12-15T23:59:59.000Z

    The Sensor Research & Development Corporation (SRD) has undertaken the development of a Continuous Emissions Monitor (CEM) for mercury based on the technique of Cavity Ring-Down Spectroscopy (CRD). The project involved building an instrument for the detection of trace levels of mercury in the flue gas emissions from coal-fired power plants. The project has occurred over two phases. The first phase concentrated on the development of the ringdown cavity and the actual detection of mercury. The second phase dealt with the construction and integration of the sampling system, used to carry the sample from the flue stack to the CRD cavity, into the overall CRD instrument. The project incorporated a Pulsed Alexandrite Laser (PAL) system from Light Age Incorporated as the source to produce the desired narrow band 254 nm ultra-violet (UV) radiation. This laser system was seeded with a diode laser to bring the linewidth of the output beam from about 150 GHz to less than 60 MHz for the fundamental beam. Through a variety of non-linear optics the 761 nm fundamental beam is converted into the 254 nm beam needed for mercury detection. Detection of the mercury transition was verified by the identification of the characteristic natural isotopic structure observed at lower cavity pressures. The five characteristic peaks, due to both natural isotopic abundance and hyperfine splitting, provided a unique identifier for mercury. SRD scientists were able to detect mercury in air down below 10 parts-per-trillion by volume (pptr). This value is dependent on the pressure and temperature within the CRD cavity at the time of detection. Sulfur dioxide (SO{sub 2}) absorbs UV radiation in the same spectral region as mercury, which is a significant problem for most mercury detection equipment. However, SRD has not only been able to determine accurate mercury concentrations in the presence of SO{sub 2}, but the CRD instrument can in fact determine the SO{sub 2} concentration as well. Detection of mercury down to the low hundreds of pptr has been accomplished in the presence of SO{sub 2} at concentration levels much higher than that found in typical flue gas emissions. SRD scientists extended the interferent testing to each individual component found in flue gas. It was found that only SO{sub 2} had a significant effect on the ring-down decay curve. Upon completion of testing the components of flue gas individually a simulated flue gas stream was used to test to the CRD instrument. The result showed accurate detection of mercury down to levels below 100 pptr in a simulated flue gas stream with the concentrations of the various components above that found in a typical untreated flue gas. A sampling system was designed and integrated into the CRD instrument to carry the sample from the flue gas stack to the CRD cavity. The sampling system was constructed so that it could be placed very close to the sampling port. SRD scientists were able to couple the UV laser light into an optical fiber, which is then sent to the sampling system. This allows the laser system to be isolated from the sampling system. Initial long-term testing revealed a couple of problems related to the stability of the output frequency of the laser system. These problems have been successfully dealt with by incorporating specific software solutions into the overall data acquisition program. The project culminated in a field test conducted at the DOE/NETL pilot plant facility in Pittsburgh, Pennsylvania. The object of the test was the evaluation of a cavity ringdown spectrometer constructed for the detection of TOTAL vapor phase mercury as a continuous emission monitor (CEM). Although there is the potential for the instrument to determine the amount of speciation between neutral elemental mercury (Hg{sup (o)}) and oxidized mercury (Hg{sup (+2)}), the initial test plan was to concentrate on the measurement of the total mercury. Another added benefit is that the measurements will report the sulfur dioxide (SO 2) concentration throughout the test. This report concludes the technical work asso

  15. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    1999-07-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  16. Dark Oxidation of Dissolved and Liquid Elemental Mercury in Aquatic

    E-Print Network [OSTI]

    Morel, François M. M.

    Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada Elemental mercury (Hg0) can be found in liquid that this oxidation is greatly enhanced by solar radiation, par- ticularly-sterilized, treated with chloroform, or filtered prior to exposure to light. Laboratory experiments have also shown

  17. Discovery of Scandium, Titanium, Mercury, and Einsteinium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; A. Bury; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Currently, twenty-three scandium, twenty-five titanium, forty mercury and seventeen einsteinium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  18. Mercury Surface, Space Environment, Geochemistry, and Ranging Mission

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    ·Carnegie Institution of Washington ·NASA Goddard Space Flight Center ·University of Michigan ·Southwest's atmosphere generated? Does Mercury have ice at its poles? Combining an ultraviolet spectrometer and infrared McClintock Other organizations involved: ·The Johns Hopkins University Applied Physics Laboratory

  19. Predictable SCR co-benefits for mercury control

    SciTech Connect (OSTI)

    Pritchard, S. [Cormtech Inc. (USA)

    2009-01-15T23:59:59.000Z

    A test program, performed in cooperation with Dominion Power and the Babcock and Wilcox Co., was executed at Dominion Power's Mount Storm power plant in Grant County, W. Va. The program was focused on both the selective catalytic reduction (SCR) catalyst capability to oxide mercury as well as the scrubber's capability to capture and retain the oxidized mercury. This article focuses on the SCR catalyst performance aspects. The Mount Storm site consists of three units totaling approximately 1,660 MW. All units are equipped with SCR systems for NOx control. A full-scale test to evaluate the effect of the SCR was performed on Unit 2, a 550 MWT-fired boiler firing a medium sulfur bituminous coal. This test program demonstrated that the presence of an SCR catalyst can significantly affect the mercury speciation profile. Observation showed that in the absence of an SCR catalyst, the extent of oxidation of element a mercury at the inlet of the flue gas desulfurization system was about 64%. The presence of a Cornertech SCR catalyst improved this oxidation to levels greater than 95% almost all of which was captured by the downstream wet FGD system. Cornertech's proprietary SCR Hg oxidation model was used to accurately predict the field results. 1 ref., 2 figs., 1 tab.

  20. Fate of Mercury in Synthetic Gypsum Used for Wallboard Production

    SciTech Connect (OSTI)

    Jessica Sanderson

    2007-12-31T23:59:59.000Z

    This report presents and discusses results from the project 'Fate of Mercury in Synthetic Gypsum Used for Wallboard Production', performed at five different full-scale commercial wallboard plants. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies involve the capture of mercury in FGD systems. The objective of this study has been to determine whether any mercury is released into the atmosphere at wallboard manufacturing plants when the synthetic gypsum material is used as a feedstock for wallboard production. The project has been co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope included seven discrete tasks, each including a test conducted at various USG wallboard plants using synthetic gypsum from different wet FGD systems. The project was originally composed of five tasks, which were to include (1) a base-case test, then variations representing differing power plant: (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5,could not be conducted as planned and instead was conducted at conditions similar to Task 3. Subsequently an opportunity arose to test gypsum produced from the Task 5 FGD system, but with an additive expected to impact the stability of mercury, so Task 6 was added to the project. Finally, Task 7 was added to evaluate synthetic gypsum produced at a power plant from an additional coal type. In the project, process stacks in the wallboard plant were sampled using the Ontario Hydro method. In every task, the stack locations sampled included a gypsum dryer and a gypsum calciner. In Tasks 1 and 4 through 7, the stack of the dryer for the wet wallboard product was also tested. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. These results and process data were used to construct mercury mass balances across the wallboard plants. The results from the project showed a wide range of percentage mercury losses from the synthetic gypsum feedstocks as measured by the Ontario Hydro method at the process stacks, ranging from 2% to 55% of the mercury in the gypsum feedstock. For the tasks exceeding 10% mercury loss across the wallboard plant, most of the loss occurred across the gypsum calciner. When total wallboard emissions remained below 10%, the primary emission location varied with a much less pronounced difference in emission between the gypsum dryer, calciner and board dryer. For all seven tasks, the majority of the mercury emissions were measured to be in the elemental form (Hg{sup 0}). Overall, the measured mercury loss mass rates ranged from 0.01 to 0.17 grams of mercury per dry ton of synthetic gypsum processed, or 0.01 to 0.4 pounds of mercury released per million square feet of wallboard produced from synthetic gypsum. The Coal Combustion Product Production and Use Survey from the American Coal Ash Association (ACAA) indicate that 7,579,187 short tons of synthetic gypsum were used for wallboard production in 2006. Extrapolating the results of this study to the ACAA industry usage rate, we estimate that mercury releases from wallboard production plants in 2006 ranged between 150 to 3000 pounds for the entire U.S. wallboard industry. With only seven sets of wallboard plant measurements, it is difficult to draw firm conclusions about what variables impact the mercury loss percentages across the wallboard plants. One significant o

  1. Chemistry of Mercury Species and Their Control in Coal Combustion

    SciTech Connect (OSTI)

    None

    1997-08-30T23:59:59.000Z

    The objectives for this reporting period are: 1) The study of mercury capture mechanism by using titania sorbent and ultraviolet (UV) light, and the study of structural difference between titania particle generated by both thermal Oxidation at 1000EC and by reacting with water vapor at room temperature. 2) Measurement of ultra-fine particle size distribution in flue gas after burning coal.

  2. air pollution mercury: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    air pollution mercury First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Environmental Pollution Air...

  3. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Musich, Mark; Swanson, Michael; Dunham, Grant; Stanislowski, Joshua

    2010-10-05T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m{sup 3}). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  4. ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS

    SciTech Connect (OSTI)

    Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski

    2010-07-31T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m3). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  5. Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511

    SciTech Connect (OSTI)

    Behrouzi, Aria [Savannah River Remediation, LLC (United States); Zamecnik, Jack [Savannah River National Laboratory, Aiken, South Carolina, 29808 (United States)

    2012-07-01T23:59:59.000Z

    The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively purified and collected in the Mercury Purification Cell (MPC) since 2008. A significant cleaning campaign aims to bring the MPC back up to facility housekeeping standards. Two significant investigations are being undertaken to restore mercury collection. The SMECT mercury pump has been removed from the tank and will be functionally tested. Also, research is being conducted by the Savannah River National Laboratory to determine the effects of antifoam addition on the behavior of mercury. These path forward items will help us better understand what is occurring in the mercury collection system and ultimately lead to an improved DWPF production rate and mercury recovery rate. (authors)

  6. Mercury stabilization in chemically bonded phosphate ceramics

    SciTech Connect (OSTI)

    Wagh, A. S.; Singh, D.; Jeong, S. Y.

    2000-04-04T23:59:59.000Z

    Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out. This paper discusses the authors experience on bench-scale stabilization of various US Department of Energy (DOE) waste streams containing Hg in the CBPC process. This process was developed to treat DOE's mixed waste streams. It is a room-temperature-setting process based on an acid-base reaction between magnesium oxide and monopotassium phosphate solution that forms a dense ceramic within hours. For Hg stabilization, addition of a small amount (< 1 wt.%) of Na{sub 2}S or K{sub 2}S is sufficient in the binder composition. Here the Toxicity Characteristic Leaching Procedure (TCLP) results on CBPC waste forms of surrogate waste streams representing secondary Hg containing wastes such as combustion residues and Delphi DETOX{trademark} residues are presented. The results show that although the current limit on leaching of Hg is 0.2 mg/L, the results from the CBPC waste forms are at least one order lower than this stringent limit. Encouraged by these results on surrogate wastes, they treated actual low-level Hg-containing mixed waste from their facility at Idaho. TCLP results on this waste are presented here. The efficient stabilization in all these cases is attributed to chemical immobilization as both a sulfide (cinnabar) and a phosphate, followed by its physical encapsulation in a dense matrix of the ceramic.

  7. Selenium inhibits the phytotoxicity of mercury in garlic (Allium sativum)

    SciTech Connect (OSTI)

    Zhao, Jiating [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Gao, Yuxi, E-mail: gaoyx@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Li, Yu-Feng; Hu, Yi; Peng, Xiaomin [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Dong, Yuanxing [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China)] [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China); Li, Bai; Chen, Chunying [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Chai, Zhifang, E-mail: chaizf@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

    2013-08-15T23:59:59.000Z

    To investigate the influence of selenium on mercury phytotoxicity, the levels of selenium and mercury were analyzed with inductively coupled plasma-mass spectrometry (ICP-MS) in garlic tissues upon exposure to different dosages of inorganic mercury (Hg{sup 2+}) and selenite (SeO{sub 3}{sup 2?}) or selenate (SeO{sub 4}{sup 2?}). The distributions of selenium and mercury were examined with micro-synchrotron radiation X-ray fluorescence (?-SRXRF), and the mercury speciation was investigated with micro-X-ray absorption near edge structure (?-XANES). The results show that Se at higher exposure levels (>1 mg/L of SeO{sub 3}{sup 2?} or SeO{sub 4}{sup 2?}) would significantly inhibit the absorption and transportation of Hg when Hg{sup 2+} levels are higher than 1 mg/L in culture media. SeO{sub 3}{sup 2?} and SeO{sub 4}{sup 2?} were found to be equally effective in reducing Hg accumulation in garlic. The inhibition of Hg uptake by Se correlates well with the influence of Se on Hg phytotoxicity as indicated by the growth inhibition factor. Elemental imaging using ?-SRXRF also shows that Se could inhibit the accumulation and translocation of Hg in garlic. ?-XANES analysis shows that Hg is mainly present in the forms of Hg–S bonding as Hg(GSH){sub 2} and Hg(Met){sub 2}. Se exposure elicited decrease of Hg–S bonding in the form of Hg(GSH){sub 2}, together with Se-mediated alteration of Hg absorption, transportation and accumulation, may account for attenuated Hg phytotoxicity by Se in garlic. -- Highlights: ? Hg phytotoxicity can be mitigated by Se supplement in garlic growth. ? Se can inhibit the accumulation and transportation of Hg in garlic tissues. ? Localization and speciation of Hg in garlic can be modified by Se.

  8. The electrodeless discharge at atmospheric pressure

    SciTech Connect (OSTI)

    Laroussi, M.

    1999-07-01T23:59:59.000Z

    Recently the generation and applications of atmospheric pressure plasmas received increased interest in the plasma research community. Applications such as the surface modification of materials, and the decontamination of matter have been under investigation. In this context, the authors introduce a new means of generating an atmospheric pressure discharge, which is suitable for use in the above-mentioned applications, and in the treatment of undesirable or polluting gases, such as VOC's. This device is a capacitively coupled discharge. It is basically made of a non-conducting tube with two independent loops of wire wrapped around it, and separated by a distance d. A stable discharge is generated inside the tube when an AC voltage of few hundred volts to few kilovolts, at a frequency of few kilohertz, is applied between the loops. One end of the tube is completely open to the outside air, and a seed gas (generally a noble gas such as Helium) is introduced in the tube. The plasma generated with this method is weakly ionized, cold, and is maintained by a relatively low input power (few tens of watts, depending on the size of the tube). In this paper, the discharge electrical characteristics, its radiation emission characteristics, and the measurement of relevant plasma parameters will be presented.

  9. Ternary gas mixture for diffuse discharge switch

    DOE Patents [OSTI]

    Christophorou, Loucas G. (Oak Ridge, TN); Hunter, Scott R. (Oak Ridge, TN)

    1988-01-01T23:59:59.000Z

    A new diffuse discharge gas switch wherein a mixture of gases is used to take advantage of desirable properties of the respective gases. There is a conducting gas, an insulating gas, and a third gas that has low ionization energy resulting in a net increase in the number of electrons available to produce a current.

  10. Selective partitioning of mercury from co-extracted actinides in a simulated acidic ICPP waste stream

    SciTech Connect (OSTI)

    Brewer, K.N.; Herbst, R.S.; Tranter, T.J. [and others

    1995-12-01T23:59:59.000Z

    The TRUEX process is being evaluated at the Idaho Chemical Processing Plant (ICPP) as a means to partition the actinides from acidic sodium-bearing waste (SBW). The mercury content of this waste averages 1 g/l. Because the chemistry of mercury has not been extensively evaluated in the TRUEX process, mercury was singled out as an element of interest. Radioactive mercury, {sup 203}Hg, was spiked into a simulated solution of SBW containing 1 g/l mercury. Successive extraction batch contacts with the mercury spiked waste simulant and successive scrubbing and stripping batch contacts of the mercury loaded TRUEX solvent (0.2 M CMPO-1.4 M TBP in dodecane) show that mercury will extract into and strip from the solvent. The extraction distribution coefficient for mercury, as HgCl{sub 2} from SBW having a nitric acid concentration of 1.4 M and a chloride concentration of 0.035 M was found to be 3. The stripping distribution coefficient was found to be 0.5 with 5 M HNO{sub 3} and 0.077 with 0.25 M Na{sub 2}CO{sub 3}. An experimental flowsheet was designed from the batch contact tests and tested counter-currently using 5.5 cm centrifugal contactors. Results from the counter-current test show that mercury can be removed from the acidic mixed SBW simulant and recovered separately from the actinides.

  11. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect (OSTI)

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R. [University of Cincinnati, Cincinnati, OH (United States). Department of Chemical and Materials Engineering

    2009-08-15T23:59:59.000Z

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  12. Figure 2: The mercury jet target geometry. The proton beam and mercury jet cross at z=-37.5 cm.

    E-Print Network [OSTI]

    McDonald, Kirk

    that the meson production loss is negligible (beta functions of 0.3m or greater. ENERGY DEPOSITION by the focusing of the proton beam. The energy deposition in the capture system is determined and the shielding. These muons are first produced by focusing a proton beam on to a liquid mercury target, where low-energy pions

  13. Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Page 1 Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks

    E-Print Network [OSTI]

    energy through temperature and pressure to drive the mercury into a vapor phase. Mercury is a heavy metal, and is regulated in drinking water by the EPA through the Safe Drinking Water Act (SDWA). If an on-line lamp break historically the U.S. has been skeptical to implement UV into drinking water systems, many areas of Europe

  14. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    SciTech Connect (OSTI)

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31T23:59:59.000Z

    The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

  15. Low-Cost Options for Moderate Levels of Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2008-02-09T23:59:59.000Z

    This is the final technical report for a three-site project that is part of an overall program funded by the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL) and industry partners to obtain the necessary information to assess the feasibility and costs of controlling mercury from coal-fired utility plants. This report summarizes results from tests conducted at MidAmerican's Louisa Generating Station and Entergy's Independence Steam Electric Station (ISES) and sorbent screening at MidAmerican's Council Bluffs Energy Center (CBEC) (subsequently renamed Walter Scott Energy Center (WSEC)). Detailed results for Independence and Louisa are presented in the respective Topical Reports. As no full-scale testing was conducted at CBEC, screening updates were provided in the quarterly updates to DOE. ADA-ES, Inc., with support from DOE/NETL, EPRI, and other industry partners, has conducted evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. An overview of each plant configuration is presented: (1) MidAmerican's Louisa Generating Station burns Powder River Basin (PRB) coal in its 700-MW Unit 1 and employs hot-side electrostatic precipitators (ESPs) with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal. (2) MidAmerican's Council Bluffs Energy Center typically burns PRB coal in its 88-MW Unit 2. It employs a hot-side ESP for particulate control. Solid sorbents were screened for hot-side injection. (3) Entergy's Independence Steam Electric Station typically burns PRB coal in its 880-MW Unit 2. Various sorbent injection tests were conducted on 1/8 to 1/32 of the flue gas stream either within or in front of one of four ESP boxes (SCA = 542 ft{sup 2}/kacfm), specifically ESP B. Initial mercury control evaluations indicated that although significant mercury control could be achieved by using the TOXECON II{trademark} design, the sorbent concentration required was higher than expected, possibly due to poor sorbent distribution. Subsequently, the original injection grid design was modeled and the results revealed that the sorbent distribution pattern was determined by the grid design, fluctuations in flue gas flow rates, and the structure of the ESP box. To improve sorbent distribution, the injection grid and delivery system were redesigned and the effectiveness of the redesigned system was evaluated. This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase II project with the goal of developing mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. Results from testing at Independence indicate that the DOE goal was successfully achieved. Further improvements in the process are recommended, however. Results from testing at Louisa indicate that the DOE goal was not achievable using the tested high-temperature sorbent. Sorbent screening at Council Bluffs also indicated that traditional solid sorbents may not achieve significant mercury removal in hot-side applications.

  16. Montana Facilities Which Do Not Discharge Process Wastewater...

    Open Energy Info (EERE)

    Which Do Not Discharge Process Wastewater (MDEQ Form 2E) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Montana Facilities Which Do Not Discharge Process...

  17. Experimental investigation of electron multipactor discharges at very high frequency

    E-Print Network [OSTI]

    Graves, Timothy P. (Timothy Paul)

    2006-01-01T23:59:59.000Z

    Multipactor discharges are a resonant condition in which electrons impact a surface in phase with an alternating electric field. The discharge is sustained by electron multiplication from secondary emission. As motivation, ...

  18. Treatability study for removal of leachable mercury in crushed fluorescent lamps

    SciTech Connect (OSTI)

    Bostick, W.D.; Beck, D.E.; Bowser, K.T. [and others

    1996-02-01T23:59:59.000Z

    Nonserviceable fluorescent lamps removed from radiological control areas at the Oak Ridge Department of Energy facilities have been crushed and are currently managed as mixed waste (hazardous and radiologically contaminated). We present proposed treatment flowsheets and supporting treatability study data for conditioning this solid waste residue so that it can qualify for disposal in a sanitary landfill. Mercury in spent fluorescent lamps occurs primarily as condensate on high-surface-area phosphor material. It can be solubilized with excess oxidants (e.g., hypochlorite solution) and stabilized by complexation with halide ions. Soluble mercury in dechlorinated saline solution is effectively removed by cementation with zero-valent iron in the form of steel wool. In packed column dynamic flow testing, soluble mercury was reduced to mercury metal and insoluble calomel, loading > 1.2 g of mercury per grain of steel wool before an appreciable breakthrough of soluble mercury in the effluent.

  19. Demonstration Results on the Effects of Mercury Speciation on the Stabilization of Wastes

    SciTech Connect (OSTI)

    Conley, T.B.; Hulet, G.A.; Morris, M.I.; Osborne-Lee, I.W.

    1999-06-01T23:59:59.000Z

    Mercury-contaminated wastes are currently being stored at approximately 19 Department of Energy sites, the volume of which is estimated to be about 16m(sup)3. These wastes exist in various forms including soil, sludges, and debris, which present a particular challenge regarding possible mercury stabilization methods. This reports provides the test results of three vendors, Allied Technology Group, IT Corporation, and Nuclear Fuel Services, Inc., that demonstrate the effects of mercury speciation on the stabilization of the mercury wastes. Mercury present in concentrations that exceed 260 parts per million must be removed by extraction methods and requires stabilization to ensure that the final wasteforms leach less than 0.2mg/L of mercury by the Toxicity Characteristic Leaching Procedure or 0.025 mg/L using the Universal Treatment Standard.

  20. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect (OSTI)

    Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

    2009-05-01T23:59:59.000Z

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  1. Atmospheric Mercury near Salmon Falls Creek Reservoir in Southern Idaho

    SciTech Connect (OSTI)

    Michael L. Abbott; Jeffrey J. Einerson

    2007-12-01T23:59:59.000Z

    Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over two-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran mercury analyzers. GEM, RGM, and particulate mercury (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize mercury air concentrations in the southern Idaho area for the first time, estimate mercury dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m-3) and RGM (8.1 ± 5.6 pg m-3) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m-3, 3.2 ± 2.9 pg m-3 for GEM, RGM respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m-3). Seasonally-averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s-1 for GEM (spring, summer, fall, and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s-1 for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 µg m-2, or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2 – 12 ng m-3) and RGM (50 - 150 pg m-3) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicated predominant source directions from the southeast (western Utah, northeastern Nevada) through the southwest (north-central Nevada) with fewer inputs from the northwest (southeastern Oregon and southwestern Idaho).

  2. MERCURY CONTROL WITH THE ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Stanley J. Miller; Ye Zhuang; Michelle R. Olderbak

    2002-11-01T23:59:59.000Z

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addresses Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team includes the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and is now marketed as the ADVANCED HYBRID{trademark} Filter by Gore. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The AHPC appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas-solid contactor. The objective of the three-task project is to demonstrate 90% total mercury control in the AHPC at a lower cost than current mercury control estimates. The approach includes bench-scale batch testing that ties the new work to previous results and links results with larger-scale pilot testing with real flue gas on a coal-fired combustion system, pilot-scale testing on a coal-fired combustion system with both a pulse-jet baghouse and an AHPC to prove or disprove the research hypotheses, and field demonstration pilot-scale testing at a utility power plant to prove scaleup and demonstrate longer-term mercury control. This project, if successful, will demonstrate at the pilot-scale level a technology that would provide a cost-effective technique to accomplish control of mercury emissions and, at the same time, greatly enhance fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution to a large segment of the U.S. utility industry as well as other industries requiring mercury control.

  3. Residual dust charges in discharge afterglow L. Couedel,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force

  4. Spectra of Ions Produced by Corona Discharges

    SciTech Connect (OSTI)

    Skalny, J.; Hortvath, G. [Department of Experimental Physics, Comenius University, Mlynska dolina F-2, 84248 Bratislava (Slovakia); Mason, N. J. [Open University, Department of Physics and Astronomy, Walton Hall, Milton Keynes MK7 6AA (United Kingdom)

    2006-12-01T23:59:59.000Z

    A mass spectrometric study of ions extracted from both positive and negative DC corona discharges, initiated in point-to plane electrode system, has been carried out in ambient air at low air pressure (5 - 30) kPa. The average relative humidity of air was typically 40-50 %. Ions were extracted through a small orifice in the plane electrode into an intermediate gap where the low pressure prevented further ion-molecule reactions. Mass analysis of negative ions formed in the negative corona discharge using ambient air has shown that the yield of individual ions is strongly affected by trace concentrations of ozone, nitrogen oxides, carbon dioxide and water vapour. In dry air the CO{sub 3}{sup -} ion was found to be dominant. In presence of water this is converted very efficiently to cluster ions CO{sub 3}{sup -}{center_dot}(H{sub 2}O){sub n} containing one and more water molecules. The yield of O{sub 3}{sup -}{center_dot}(H{sub 2}O){sub n} clusters or core ions was found to be considerably lower than in some other studies at atmospheric pressure. The mass spectrum of ions extracted from drift region of a positive corona discharge was simpler being dominantly cluster ions H3O+{center_dot}(H2O)n most probably formed from O{sub 2}{sup +} ions, a two step process being active if water molecules are present in the discharge gap even at relatively low concentration.

  5. Gas mixture for diffuse-discharge switch

    DOE Patents [OSTI]

    Christophorou, L.G.; Carter, J.G.; Hunter, S.R.

    1982-08-31T23:59:59.000Z

    Gaseous medium in a diffuse-discharge switch of a high-energy pulse generator is formed of argon combined with a compound selected from the group consisting of CF/sub 4/, C/sub 2/F/sub 6/, C/sub 3/F/sub 8/, n-C/sub 4/F/sub 10/, WF/sub 6/, (CF/sub 3/)/sub 2/S and (CF/sub 3/)/sub 2/O.

  6. Reel danger: power plant mercury pollution and the fish we eat

    SciTech Connect (OSTI)

    Figdor, E. [US Public Interest Research Group Education Fund (US PIRG) for Clear the Air, Washington, DC (United States)

    2004-08-15T23:59:59.000Z

    This study is based on the first available data from US EPA's ongoing National Study of Chemical Residues in Lake Fish Tissue. From 1999-2001, EPA collected approximately two composite samples of one predator fish species and one bottom-dwelling fish species at 260 lakes, for a total of 520 composite samples, or 2,547 fish. It was found that every fish tested was contaminated with mercury. 55% of the fish tested contained mercury levels that exceed EPA's 'safe' limit for women of childbearing age, and 76% exceeded the safe limit for children under age three. Predator fish, including smallmouth bass, walleye, largemouth bass, lake trout, and Northern pike, had the highest average mercury concentrations. Coal-fired power plants are the single largest source of mercury emissions, contributing 41% of US mercury emissions. They released 90,370 pounds of mercury into the air in 2002, the most recent year for which EPA data are available. In January 2004, the Bush administration issued a proposal for regulating mercury from power plants. In the author's opinion, the EPA's proposal would delay even modest reductions in mercury emissions from power plants until after 2025. In contrast, the Clean Air Act calls for the maximum achievable reductions by 2008. It is recommended that the Bush administration reverse course and require coal-fired power plants to reduce mercury emissions by at least 90% by 2008. 79 refs., 4 figs., 11 tabs., 3 apps.

  7. Packaging a liquid metal ESD with micro-scale Mercury droplet.

    SciTech Connect (OSTI)

    Barnard, Casey Anderson

    2011-08-01T23:59:59.000Z

    A liquid metal ESD is being developed to provide electrical switching at different acceleration levels. The metal will act as both proof mass and electric contact. Mercury is chosen to comply with operation parameters. There are many challenges surrounding the deposition and containment of micro scale mercury droplets. Novel methods of micro liquid transfer are developed to deliver controllable amounts of mercury to the appropriate channels in volumes under 1 uL. Issues of hermetic sealing and avoidance of mercury contamination are also addressed.

  8. Continuous mercury monitor for thermal treatment and waste-to-energy operations

    SciTech Connect (OSTI)

    Schlager, R.J.; Wilson, K.G.; Sappey, A.D.; Anderson, G.L.; Sagan, F.J. [ADA Technologies, Inc., Englewood, CO (United States)

    1996-12-31T23:59:59.000Z

    Treating wastes by thermal means offers benefits in terms of reducing waste volumes and in recovering energy values from the wastes. Thermal treatment has been an effective technology for a number of years, and is being used more in the US. Significant sources of waste in the US are municipal solid waste, hospital wastes, hazardous wastes, and wastes generated form the DOE complex. Mercury is found in these wastes and is emitted as a pollutant from sources that treat these materials thermally. Because of mercury`s toxicity, there is a considerable amount of activity aimed at its regulation and control. One of the key elements to effectively control the release of mercury is the ability to continuously monitor its concentration from emitting sources. ADA Technologies is developing a continuous monitoring system for measuring these emissions in real time. A real-time analyzer will assure that compliance limits are met and that emissions are kept as low as possible. Because mercury is emitted from sources in several different forms, such as elemental mercury and mercuric chloride, provisions have been incorporated in the analyzer that will allow for the measurement of all mercury compounds. The system will provide a number of advantages over existing test methods: (1) it will provide a real-time measure of emissions rates; (2) it will assure facility operators, regulators, and the public that emissions control systems are working at peak efficiency; and (3) it will provide information as to the nature of the emitted mercury (elemental mercury or speciated compounds).

  9. FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report

    SciTech Connect (OSTI)

    Searcy, K; Bltyhe, G M; Steen, W A

    2012-02-28T23:59:59.000Z

    Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

  10. Capacitor discharge process for welding braided cable

    DOE Patents [OSTI]

    Wilson, Rick D. (Corvallis, OR)

    1995-01-01T23:59:59.000Z

    A capacitor discharge process for welding a braided cable formed from a plurality of individual cable strands to a solid metallic electrically conductive member comprises the steps of: (a) preparing the electrically conductive member for welding by bevelling one of its end portions while leaving an ignition projection extending outwardly from the apex of the bevel; (b) clamping the electrically conductive member in a cathode fixture; (c) connecting the electrically conductive member clamped in the cathode fixture to a capacitor bank capable of being charged to a preselected voltage value; (d) preparing the braided cable for welding by wrapping one of its end portions with a metallic sheet to form a retaining ring operable to maintain the individual strands of the braided cable in fixed position within the retaining ring; (e) clamping the braided cable and the retaining ring as a unit in an anode fixture so that the wrapped end portion of the braided cable faces the ignition projection of the electrically conductive member; and (f) moving the cathode fixture towards the anode fixture until the ignition projection of the electrically conductive member contacts the end portion of the braided cable thereby allowing the capacitor bank to discharge through the electrically conductive member and through the braided cable and causing the electrically conductive member to be welded to the braided cable via capacitor discharge action.

  11. Magnetism in Lithium–Oxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13T23:59:59.000Z

    Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  12. General Relativity Problem of Mercury's Perihelion Advance Revisited

    E-Print Network [OSTI]

    Vankov, Anatoli A

    2010-01-01T23:59:59.000Z

    The work is devoted to the critical analysis of theoretical prediction and astronomical observation of GR effects, first of all, the Mercury's perihelion advance. In the first part, the methodological issues of observations are discussed including a practice of observations, a method of recognizing the relativistic properties of the effect and recovering it from bulk of raw data, a parametric observational model, and finally, methods of assessment of the effect value and statistical level of confidence. In the second part, the Mercury's perihelion advance and other theoretical problems are discussed in relationship with the GR physical foundations. Controversies in literature devoted to the GR tests are analyzed. The unified GR approach to particles and photons is discussed with the emphasis on the GR classical tests. Finally, the alternative theory of relativistic effect treatment is presented.

  13. General Relativity Problem of Mercury's Perihelion Advance Revisited

    E-Print Network [OSTI]

    Anatoli A. Vankov

    2010-08-10T23:59:59.000Z

    The work is devoted to the critical analysis of theoretical prediction and astronomical observation of GR effects, first of all, the Mercury's perihelion advance. In the first part, the methodological issues of observations are discussed including a practice of observations, a method of recognizing the relativistic properties of the effect and recovering it from bulk of raw data, a parametric observational model, and finally, methods of assessment of the effect value and statistical level of confidence. In the second part, the Mercury's perihelion advance and other theoretical problems are discussed in relationship with the GR physical foundations. Controversies in literature devoted to the GR tests are analyzed. The unified GR approach to particles and photons is discussed with the emphasis on the GR classical tests. Finally, the alternative theory of relativistic effect treatment is presented.

  14. Stimulation of erythrocyte phosphatidylserine exposure by mercury ions

    SciTech Connect (OSTI)

    Eisele, Kerstin [Department of Physiology, University of Tuebingen (Germany); Lang, Philipp A. [Department of Physiology, University of Tuebingen (Germany); Kempe, Daniela S. [Department of Physiology, University of Tuebingen (Germany); Klarl, Barbara A. [Department of Physiology, University of Tuebingen (Germany); Niemoeller, Olivier [Department of Physiology, University of Tuebingen (Germany); Wieder, Thomas [Department of Physiology, University of Tuebingen (Germany); Huber, Stephan M. [Department of Physiology, University of Tuebingen (Germany); Duranton, Christophe [Department of Physiology, University of Tuebingen (Germany); Lang, Florian [Department of Physiology, University of Tuebingen (Germany)]. E-mail: florian.lang@uni-tuebingen.de

    2006-01-15T23:59:59.000Z

    The sequelae of mercury intoxication include induction of apoptosis. In nucleated cells, Hg{sup 2+}-induced apoptosis involves mitochondrial damage. The present study has been performed to elucidate effects of Hg{sup 2+} in erythrocytes which lack mitochondria but are able to undergo apoptosis-like alterations of the cell membrane. Previous studies have documented that activation of a Ca{sup 2+}-sensitive erythrocyte scramblase leads to exposure of phosphatidylserine at the erythrocyte surface, a typical feature of apoptotic cells. The erythrocyte scramblase is activated by osmotic shock, oxidative stress and/or energy depletion which increase cytosolic Ca{sup 2+} activity and/or activate a sphingomyelinase leading to formation of ceramide. Ceramide sensitizes the scramblase to Ca{sup 2+}. The present experiments explored the effect of Hg{sup 2+} ions on erythrocytes. Phosphatidylserine exposure after mercury treatment was estimated from annexin binding as determined in FACS analysis. Exposure to Hg{sup 2+} (1 {mu}M) indeed significantly increased annexin binding from 2.3 {+-} 0.5% (control condition) to 23 {+-} 6% (n = 6). This effect was paralleled by activation of a clotrimazole-sensitive K{sup +}-selective conductance as measured by patch-clamp recordings and by transient cell shrinkage. Further experiments revealed also an increase of ceramide formation by {approx}66% (n = 7) after challenge with mercury (1 {mu}M). In conclusion, mercury ions activate a clotrimazole-sensitive K{sup +}-selective conductance leading to transient cell shrinkage. Moreover, Hg{sup 2+} increases ceramide formation. The observed mechanisms could similarly participate in the triggering of apoptosis in nucleated cells by Hg{sup 2+}.

  15. Mercury Contamination in Pelagic Fishes of the Gulf of Mexico

    E-Print Network [OSTI]

    Kuklyte, Ligita

    2012-10-19T23:59:59.000Z

    radiation and moisture. At higher pH and temperature Hg mobilization and emission from soil increases (Gabriel & Williamson 2004). Mercury is deposited into aquatic ecosystems by the same processes. In surface waters it occurs as dissolved free ions...), length at year one (cm) and percentage (%) of bony fish in their diet. Species name Trophic adult position Max age Max length Length at year one Fish % in diet References blackfin tuna 4.13 5 93 45 70% (Doray et al. 2004) (Robert...

  16. Semi-continuous detection of mercury in gases

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2011-12-06T23:59:59.000Z

    A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

  17. Kinetics of Mercury(II) Adsorption and Desorption on Soil

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Mercury(II) Adsorption and Desorption on Soil Y U J U N Y I N , H E R B E R T E . A L L of Delaware, Newark, Delaware 19716 D O N A L D L . S P A R K S Department of Plant and Soil Sciences kinetics of Hg(II) on four soils at pH 6 were investigated to discern the mechanisms controlling

  18. Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum

    SciTech Connect (OSTI)

    Hensman, Carl, E., P.h.D; Baker, Trevor

    2008-06-16T23:59:59.000Z

    Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

  19. Mercury toxicokinetics-dependency on strain and gender

    SciTech Connect (OSTI)

    Ekstrand, Jimmy [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Nielsen, Jesper B. [Department of Environmental Medicine, University of Southern Denmark, DK-5000 Odense C (Denmark); Havarinasab, Said [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Zalups, Rudolfs K. [Division of Basic Medical Sciences, Mercer University School of Medicine, 1550 College Street, Macon, GA 31207 (United States); Soederkvist, Peter [Cell Biology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Hultman, Per, E-mail: perhu@imk.liu.s [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden)

    2010-03-15T23:59:59.000Z

    Mercury (Hg) exposure from dental amalgam fillings and thimerosal in vaccines is not a major health hazard, but adverse health effects cannot be ruled out in a small and more susceptible part of the exposed population. Individual differences in toxicokinetics may explain susceptibility to mercury. Inbred, H-2-congenic A.SW and B10.S mice and their F1- and F2-hybrids were given HgCl{sub 2} with 2.0 mg Hg/L drinking water and traces of {sup 203}Hg. Whole-body retention (WBR) was monitored until steady state after 5 weeks, when the organ Hg content was assessed. Despite similar Hg intake, A.SW males attained a 20-30% significantly higher WBR and 2- to 5-fold higher total renal Hg retention/concentration than A.SW females and B10.S mice. A selective renal Hg accumulation but of lower magnitude was seen also in B10.S males compared with females. Differences in WBR and organ Hg accumulation are therefore regulated by non-H-2 genes and gender. Lymph nodes lacked the strain- and gender-dependent Hg accumulation profile of kidney, liver and spleen. After 15 days without Hg A.SW mice showed a 4-fold higher WBR and liver Hg concentration, but 11-fold higher renal Hg concentration, showing the key role for the kidneys in explaining the slower Hg elimination in A.SW mice. The trait causing higher mercury accumulation was not dominantly inherited in the F1 hybrids. F2 mice showed a large inter-individual variation in Hg accumulation, showing that multiple genetic factors influence the Hg toxicokinetics in the mouse. The genetically heterogeneous human population may therefore show a large variation in mercury toxicokinetics.

  20. Survey of mercury, cadmium and lead content of household batteries

    SciTech Connect (OSTI)

    Recknagel, Sebastian, E-mail: sebastian.recknagel@bam.de [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willstätter-Straße 11, D-12489 Berlin (Germany); Radant, Hendrik [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willstätter-Straße 11, D-12489 Berlin (Germany); Kohlmeyer, Regina [German Federal Environment Agency (UBA), Section III 1.6 Extended Producer Responsibility, Wörlitzer Platz 1, D-06844 Dessau-Roßlau (Germany)

    2014-01-15T23:59:59.000Z

    Highlights: • A well selected sample of 146 batteries was analysed for its heavy metals content. • A comparison was made between heavy metals contents in batteries in 2006 and 2011. • No significant change after implementation of the new EU Batteries Directive. • Severe differences in heavy metal contents were found in different battery-types. - Abstract: The objective of this work was to provide updated information on the development of the potential impact of heavy metal containing batteries on municipal waste and battery recycling processes following transposition of the new EU Batteries Directive 2006/66/EC. A representative sample of 146 different types of commercially available dry and button cells as well as lithium-ion accumulators for mobile phones were analysed for their mercury (Hg)-, cadmium (Cd)- and lead (Pb)-contents. The methods used for preparing the cells and analysing the heavy metals Hg, Cd, and Pb were either developed during a former study or newly developed. Several batteries contained higher mass fractions of mercury or cadmium than the EU limits. Only half of the batteries with mercury and/or lead fractions above the marking thresholds were labelled. Alkaline–manganese mono-cells and Li-ion accumulators, on average, contained the lowest heavy metal concentrations, while zinc–carbon batteries, on average, contained the highest levels.

  1. JV Task 96 - Phase 2 - Investigating the Importance of the Mercury-Selenium Interaction

    SciTech Connect (OSTI)

    Nicholas Ralston; Laura Raymond

    2008-03-01T23:59:59.000Z

    In order to improve the understanding of the mercury issue, it is vital to study mercury's effects on selenium physiology. While mercury present in the environment or food sources may pose health risks, the protective effects of selenium have not been adequately considered in establishing regulatory policy. Numerous studies report that vulnerability to mercury toxicity is inversely proportional to selenium status or level. However, selenium status has not been considered in the development of the reference dosage levels for mercury exposure. Experimental animals fed low-selenium diets are far more vulnerable to mercury toxicity than animals fed normal selenium, and animals fed selenium-rich diets are even more resistant. Selenium-dependent enzymes in brain and endocrine tissues can be impaired by excessive mercury exposure, apparently because mercury has an extremely high binding affinity for selenium. When selenium becomes bound to mercury, it is unable to participate in the metabolic cycling of selenoprotein synthesis. Because of mercury-dependent impairments of selenoprotein synthesis, various antioxidant and regulatory functions in brain biochemistry are compromised. This report details a 2-year multiclient-funded research program designed to examine the interactions between mercury and selenium in animal models. The studies explored the effects of dietary intakes of toxic amounts of methylmercury and the protective effects of the normal dietary range of selenium in counteracting mercury toxicity. This study finds that the amounts of selenium present in ocean fish are sufficient to protect against far larger quantities of methylmercury than those present in typical seafoods. Toxic effects of methylmercury exposure were not directly proportional to mercury concentrations in blood, brain, or any other tissues. Instead, mercury toxicity was proportional to molar ratios of mercury relative to selenium. In order to accurately assess risk associated with methylmercury or mercury exposures, mercury-selenium ratios appear to be far more accurate and effective in identifying risk and protecting human and environmental health. This study also finds that methylmercury toxicity can be effectively treated by dietary selenium, preventing the death and progressive disabilities that otherwise occur in methylmercury-treated subjects. Remarkably, the positive response to selenium therapy was essentially equivalent regardless of whether or not toxic amounts of methylmercury were still administered. The findings of the Physiologically Oriented Integration of Nutrients and Toxins (POINT) models of the effects of mercury and selenium developed in this project are consistent with the hypothesis that mercury toxicity arises because of mercury-dependent inhibition of selenium availability in brain and endocrine tissues. This appears to occur through synergistic effects of mercury-dependent inhibition of selenium transport to these tissues and selective sequestration of the selenium present in the tissues. Compromised transport of selenium to the brain and endocrine tissues would be particularly hazardous to the developing fetus because the rapidly growing tissues of the child have no selenium reserves. Therefore, maternal consumption of foods with high mercury-selenium ratios is hazardous. In summation, methylmercury exposure is unlikely to cause harm in populations that eat selenium-rich diets but may cause harm among populations that consume certain foods that have methylmercury present in excess of selenium.

  2. In situ measurements of speciated atmospheric mercury and the identification of source regions in the Mexico City Metropolitan Area

    E-Print Network [OSTI]

    Rutter, A. P.

    In order to expand the currently limited understanding of atmospheric mercury source-receptor relationships in the Mexico City Metropolitan Area, real time measurements of atmospheric mercury were made at a downtown urban ...

  3. Sensitive glow discharge ion source for aerosol and gas analysis

    DOE Patents [OSTI]

    Reilly, Peter T. A. (Knoxville, TN)

    2007-08-14T23:59:59.000Z

    A high sensitivity glow discharge ion source system for analyzing particles includes an aerodynamic lens having a plurality of constrictions for receiving an aerosol including at least one analyte particle in a carrier gas and focusing the analyte particles into a collimated particle beam. A separator separates the carrier gas from the analyte particle beam, wherein the analyte particle beam or vapors derived from the analyte particle beam are selectively transmitted out of from the separator. A glow discharge ionization source includes a discharge chamber having an entrance orifice for receiving the analyte particle beam or analyte vapors, and a target electrode and discharge electrode therein. An electric field applied between the target electrode and discharge electrode generates an analyte ion stream from the analyte vapors, which is directed out of the discharge chamber through an exit orifice, such as to a mass spectrometer. High analyte sensitivity is obtained by pumping the discharge chamber exclusively through the exit orifice and the entrance orifice.

  4. Phenomena of oscillations in atmospheric pressure direct current glow discharges

    SciTech Connect (OSTI)

    Liu, Fu-cheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Yan, Wen; Wang, De-zhen [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-12-15T23:59:59.000Z

    Self-sustained oscillations in a dc glow discharge with a semiconductor layer at atmospheric pressure were investigated by means of a one-dimensional fluid model. It is found that the dc glow discharge initially becomes unstable in the subnormal glow region and gives rise to oscillations of plasma parameters. A variety of oscillations with one or more frequencies have been observed under different conditions. The discharge oscillates between the glow discharge mode and the Townsend discharge mode in the oscillations with large amplitude while operates in the subnormal glow discharge mode all the while in the oscillations with small amplitude. Fourier Transform spectra of oscillations reveal the transition mechanism between different oscillations. The effects of semiconductor conductivity on the oscillation frequency of the dominant mode, gas voltage, as well as the discharge current have also been analyzed.

  5. Glutathione enzyme and selenoprotein polymorphisms associate with mercury biomarker levels in Michigan dental professionals

    SciTech Connect (OSTI)

    Goodrich, Jaclyn M.; Wang, Yi [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Gillespie, Brenda [Department of Biostatistics, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Biostatistics, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Werner, Robert [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States) [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Department of Physical Medicine and Rehabilitation, University of Michigan, 325 E. Eisenhower Parkway Suite 100, Ann Arbor, MI 48108 (United States); Franzblau, Alfred [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Basu, Niladri, E-mail: niladri@umich.edu [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)

    2011-12-15T23:59:59.000Z

    Mercury is a potent toxicant of concern to both the general public and occupationally exposed workers (e.g., dentists). Recent studies suggest that several genes mediating the toxicokinetics of mercury are polymorphic in humans and may influence inter-individual variability in mercury accumulation. This work hypothesizes that polymorphisms in key glutathione synthesizing enzyme, glutathione s-transferase, and selenoprotein genes underlie inter-individual differences in mercury body burden as assessed by analytical mercury measurement in urine and hair, biomarkers of elemental mercury and methylmercury, respectively. Urine and hair samples were collected from a population of dental professionals (n = 515), and total mercury content was measured. Average urine (1.06 {+-} 1.24 ug/L) and hair mercury levels (0.49 {+-} 0.63 ug/g) were similar to national U.S. population averages. Taqman assays were used to genotype DNA from buccal swab samples at 15 polymorphic sites in genes implicated in mercury metabolism. Linear regression modeling assessed the ability of polymorphisms to modify the relationship between mercury biomarker levels and exposure sources (e.g., amalgams, fish consumption). Five polymorphisms were significantly associated with urine mercury levels (GSTT1 deletion), hair mercury levels (GSTP1-105, GSTP1-114, GSS 5 Prime ), or both (SEPP1 3 Prime UTR). Overall, this study suggests that polymorphisms in selenoproteins and glutathione-related genes may influence elimination of mercury in the urine and hair or mercury retention following exposures to elemental mercury (via dental amalgams) and methylmercury (via fish consumption). -- Highlights: Black-Right-Pointing-Pointer We explore the influence of 15 polymorphisms on urine and hair Hg levels. Black-Right-Pointing-Pointer Urine and hair Hg levels in dental professionals were similar to the US population. Black-Right-Pointing-Pointer GSTT1 and SEPP1 polymorphisms associated with urine Hg levels. Black-Right-Pointing-Pointer Accumulation of Hg in hair following exposure from fish was modified by genotype. Black-Right-Pointing-Pointer GSTP1, GSS, and SEPP1 polymorphisms influenced Hg accumulation in hair.

  6. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    SciTech Connect (OSTI)

    Gary Blythe; John Currie; David DeBerry

    2008-03-31T23:59:59.000Z

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

  7. State waste discharge permit application: Hydrotest, maintenance and construction discharges. Revision 0

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    On December 23, 1991, the US DOE< Richland Operation Office (RL) and the Washington State Department of Ecology (Ecology) agreed to adhere to the provisions of the Department of Ecology Consent Order No. DE91NM-177 (216 Consent Order) (Ecology and US DOE 1991). The 216 Consent Order list regulatory milestones for liquid effluent streams at the Hanford Site and requires compliance with the permitting requirements of Washington Administrative Code. Hanford Site liquid effluent streams discharging to the soil column have been categorized on the 216 Consent Order as follows: Phase I Streams; Phase II Streams; Miscellaneous Streams. Phase I and Phase II Streams were initially addressed in two report. Miscellaneous Streams are subject to the requirements of several milestones identified in the 216 Consent Order. This document constitutes the Categorical State Waste Discharge Permit application for hydrotest,maintenance and construction discharges throughout the Hanford Site. This categorical permit application form was prepared and approved by Ecology.

  8. Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA

    SciTech Connect (OSTI)

    Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

    2003-05-01T23:59:59.000Z

    Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

  9. Fate of Mercury in Synthetic Gypsum Used for Wallboard Production

    SciTech Connect (OSTI)

    Jessica Marshall Sanderson

    2006-06-01T23:59:59.000Z

    This report presents and discusses results from Task 5 of the study ''Fate of Mercury in Synthetic Gypsum Used for Wallboard Production,'' performed at a full-scale commercial wallboard plant. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. The FGD process is used to control the sulfur dioxide emissions which would result in acid rain if not controlled. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies developed for power plants involve the capture of mercury in FGD systems. The objective of this study is to determine whether any mercury is released into the atmosphere when the synthetic gypsum material is used as a feedstock for wallboard production. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope includes five discrete tasks, each conducted at various USG wallboard plants using synthetic gypsum from different FGD systems. The five tasks were to include (1) a baseline test, then variations representing differing power plant (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5, which was to evaluate gypsum produced from an alternate FGD reagent, could not be conducted as planned. Instead, Task 5 was conducted at conditions similar to a previous task, Task 3, although with gypsum from an alternate FGD system. In this project, process stacks in the wallboard plant have been sampled using the Ontario Hydro method. The stack locations sampled for each task include a dryer for the wet gypsum as it enters the plant and a gypsum calciner. The stack of the dryer for the wet wallboard product was also tested as part of this task, and was tested as part of Tasks 1 and 4. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. The Ontario Hydro results, process sample mercury concentration data, and process data were used to construct mercury mass balances across the wallboard plants. Task 5 was conducted at a wallboard plant processing synthetic gypsum from a power plant that fires Eastern bituminous coal. The power plant is equipped with a selective catalytic reduction (SCR) system for NOX emissions control, but the SCR was bypassed during the time period the gypsum tested was produced. The power plant has a single-loop, open spray tower, limestone reagent FGD system, with forced oxidation conducted in a reaction tank integral with the FGD absorber. The FGD system has gypsum fines blow down as part of the dewatering step. Gypsum fines blow down is believed to be an important variable that impacts the amount of mercury in the gypsum byproduct and possibly its stability during the wallboard process. The results of the Task 5 stack testing, as measured by the Ontario Hydro method, detected that an average of 51% of the incoming mercury in the FGD gypsum was emitted during wallboard production. These losses were distributed as 2% or less each across the wet gypsum dryer and product wallboard dryer, and about 50% across the gypsum calciner. Emissions were similar to what Task 3 results showed, on both a percentage and a mass basis, for gypsum produced by a power plant firing bituminous coal and also having gypsum fines blow down as part of the FGD dewatering scheme. As was seen in the Task 1 through 4 results, most of the mercury detected in the stack testing on the wet gypsum dryer and kettle calciner was in the form of elemental mercury. In the wallboard dryer kiln, a more signific

  10. Does proximity to coal-fired power plants influence fish tissue mercury?

    E-Print Network [OSTI]

    Does proximity to coal-fired power plants influence fish tissue mercury? Dana K. Sackett · D. Derek+Business Media, LLC 2010 Abstract Much of the mercury contamination in aquatic biota originates from coal of contaminated fish. In this study, we quantified the relative importance of proximity to coal-fired power plants

  11. Mercury Contamination from Hydraulic Placer-Gold Mining in the Dutch Flat Mining

    E-Print Network [OSTI]

    179 Mercury Contamination from Hydraulic Placer-Gold Mining in the Dutch Flat Mining District at historic gold mining sites represents a potential risk to human health and the environment. Elemental mercury (quicksilver) was used extensively for the recovery of gold at both placer and hardrock mines

  12. High Mercury Concentrations Reflect Trophic Ecology of Three Deep-Water Chondrichthyans

    E-Print Network [OSTI]

    Newman, Michael C.

    High Mercury Concentrations Reflect Trophic Ecology of Three Deep-Water Chondrichthyans Michael C concentrations were explored for three deep-water chondrichthyans (Etmopterus princeps, Cen- troscymnus position in the trophic web (as indicated by differences in d15 N). Mercury is a major contaminant

  13. Mercury speciation in Galveston Bay, Texas: the importance of complexation by natural organic ligands

    E-Print Network [OSTI]

    Han, Seunghee

    2005-02-17T23:59:59.000Z

    of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2004 Major Subject: Oceanography MERCURY SPECIATION IN GALVESTON BAY, TEXAS: THE IMPORTANCE OF COMPLEXATION BY NATURAL ORGANIC LIGANDS A Dissertation by SEUNGHEE HAN.... Cifuentes (Member) Paul A. Lindahl (Member) Wilford D. Gardner (Head of Department) December 2004 Major Subject: Oceanography iii ABSTRACT Mercury Speciation in Galveston Bay, Texas: The Importance of Complexation...

  14. A Critical Review on the Heterogeneous Catalytic Oxidation of Elemental Mercury in Flue Gases

    E-Print Network [OSTI]

    Guo, John Zhanhu

    to tremors, inability to walk, convulsions, and death.1,2 Coal-fired utility boilers, which release more than), are the largest source of mercury pollution.3 However, on average only about 40% of the mercury entering a coal-fired toxic air pollution from coal and oil-fired power plants. The final rule established that the power

  15. Mercury in the Great Lakes Region Sponsored by the Commission for Environmental Cooperation's

    E-Print Network [OSTI]

    .S. 2020 baseline inventory for mercury emissions from coal-fired power plants: · estimated emissions from inventory for mercury emissions from coal-fired power plants: · Projected emissions in 2020 from U for coal combustion at coal- fired power plants: · technology advances slowly · limited action with respect

  16. Mercury in the Atmosphere, Snow and Melt Water Ponds in the North

    E-Print Network [OSTI]

    Jacob, Daniel J.

    . Introduction Compared to most heavy metals, mercury behaves excepMercury in the Atmosphere, Snow and Melt Water Ponds in the North Atlantic Ocean during Arctic dominant species, with a northern hemispheric back- ground concentration of 1.7 ng/m3 (3). Under these same

  17. Magnesium-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling

    E-Print Network [OSTI]

    Hauck II, Steven A.

    Magnesium-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling December 2012. [1] We have conducted petrologic modeling of MESSENGER-derived compositions and analog-rich crustal compositions on Mercury: Implications for magmatism from petrologic modeling, J. Geophys. Res

  18. Mercury: A second-generation KrF laser for inertial fusion research

    SciTech Connect (OSTI)

    Bigio, I.J.; York, G.; McLeod, J.; Czuchlewski, J.; Rose, E.; Hanson, D.E.; Kurnit, N.A.; McCown, A.

    1992-10-01T23:59:59.000Z

    The ``Mercury`` KrF laser facility at Los Alamos is being built with the benefit of lessons learned from the Aurora KrF laser. An increased understanding of KrF laser engineering, and the designed implementation of system flexibility, will permit Mercury to serve as a testbed for a variety of advanced KrF technology concepts.

  19. Mercury: A second-generation KrF laser for inertial fusion research

    SciTech Connect (OSTI)

    Bigio, I.J.; York, G.; McLeod, J.; Czuchlewski, J.; Rose, E.; Hanson, D.E.; Kurnit, N.A.; McCown, A.

    1992-01-01T23:59:59.000Z

    The Mercury'' KrF laser facility at Los Alamos is being built with the benefit of lessons learned from the Aurora KrF laser. An increased understanding of KrF laser engineering, and the designed implementation of system flexibility, will permit Mercury to serve as a testbed for a variety of advanced KrF technology concepts.

  20. Spatial assessment of net mercury emissions from the use of fluorescent bulbs

    SciTech Connect (OSTI)

    Matthew J. Eckelman; Paul T. Anastas; Julie B. Zimmerman [Yale University, New Haven, CT (United States). Department of Chemical Engineering

    2008-11-15T23:59:59.000Z

    While fluorescent lighting is an important technology for reducing electrical energy demand, mercury used in the bulbs is an ongoing concern. Using state and country level data, net emissions of mercury from the marginal use of fluorescent lightbulbs are examined for a base year of 2004 for each of the 50 United States and 130 countries. Combustion of coal for electric power generation is generally the largest source of atmospheric mercury pollution; reduction in electricity demand from the substitution of incandescent bulbs with fluorescents leads to reduced mercury emissions during the use of the bulb. This analysis considers the local mix of power sources, coal quality, thermal conversion efficiencies, distribution losses, and any mercury control technologies that might be in place. Emissions of mercury from production and end-of-life treatment of the bulbs are also considered, providing a life-cycle perspective. Net reductions in mercury over the entire life cycle range from -1.2 to 97 mg per bulb depending on the country. The consequences for atmospheric mercury emissions of several policy scenarios are also discussed. 46 refs., 4 figs., 3 tabs.

  1. Mercury(II) Sorption to Two Florida Everglades Peats: Evidence for

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Mercury(II) Sorption to Two Florida Everglades Peats: Evidence for Strong and Weak Binding and Competition by Dissolved Organic Matter Released from the Peat R . T O D D D R E X E L , M A R K U S H A I 80309 The binding of mercury(II) to two peats from Florida Everglades sites with different rates

  2. Long-term records of atmospheric deposition of mercury in peat cores

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Long-term records of atmospheric deposition of mercury in peat cores from Arctic, and comparisonD dissertation February 2004 #12;Long-term records of atmospheric deposition of mercury in peat cores from Arctic in southern Ontario recorded by peat cores from three bogs: comparison with natural "background" values (past

  3. Yale's Environment School Power Plants Big Influence in Regional Mercury Emissions Introduction Knowledge

    E-Print Network [OSTI]

    Lee, Xuhui

    Yale's Environment School · Power Plants Big Influence in Regional Mercury Emissions Introduction Power Plants Big Influence in Regional Mercury Emissions Related Topics: News Releases; Publications winters and a correspondent decrease in the need for regional power plants to burn coal could partially

  4. Mercury Releases to Air and Rivers Contaminate Ocean Fish: Dartmouth-Led Effort Publishes Major Findings

    E-Print Network [OSTI]

    Myers, Lawrence C.

    Mercury Releases to Air and Rivers Contaminate Ocean Fish: Dartmouth-Led Effort Publishes Major and in Sources to Seafood: Mercury Pollution in the Marine Environment-- a companion report by the Dartmouth released into the air and then deposited into oceans, contaminates seafood commonly eaten by people

  5. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    mercury emissions gm/day Reference COAL-FIRED POWER PLANTScoal-fired power plants and chlor- shale alkali and within the range of emissionscoal-fired power plant boilers. Table 9 compares standards and guidelines for gaseous and aqueous mercury emissions

  6. Mercury Issues and Complexities in Oak Ridge, Tennessee; Redefining the Conceptual Model - 12277

    SciTech Connect (OSTI)

    Peterson, Mark; Southworth, George; Watson, David [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Looney, Brian; Eddy-Dilek, Carol [Savannah River National Laboratory, Aiken, South Carolina 29808 (United States); Ketelle, Richard [Restoration Services Inc., Oak Ridge, Tennessee 37831 (United States)

    2012-07-01T23:59:59.000Z

    Releases of mercury from an industrial facility in Oak Ridge, Tennessee in the 1950's and early 1960's resulted in contamination of soil and groundwater within the facility, as well as downstream surface waters. Remediation efforts, which began in the 1980's, have decreased waterborne mercury concentrations near the facility, but elevated levels of mercury remain in the soil, sediment, water, and biota. Widespread distribution of mercury sources and complex mercury transport pathways are some of many challenges at the site. For effective environmental management and closure decision making relative to mercury contamination at the facilities, an up-to-date conceptual model of mercury source areas, processes, likely flow paths, and flux was deemed necessary. Recent facility and reconfiguration efforts, site characterizations, remedial actions, and research are facilitating the collection of new mercury data in Oak Ridge. To develop the current model, a multi-organizational team reviewed existing conceptual models from a variety of sources, consolidated historical data and source information, gathered input from local experts with extensive site knowledge, and used recently collected mercury data from a variety of sampling programs. The developed site conceptual model indicates that the nature and extent of mercury concentration and contaminant flux has significantly changed in the ten years since flux-based conceptual models were used for previous remedial action decisions. A new water treatment system has effectively reduced mercury inputs to the creek and is removing substantially greater quantities of mercury from groundwater than was expected. However, fish concentrations in downstream waters have not responded to decreased water concentrations in the stream. Flux from one large out-fall at the creek's headwaters appears to be a greater percentage of the overall flux leaving the site than previous years, albeit year to year variation in flux is large, and the many small sources of mercury identified in the model may also be important if the goal is to reach very low mercury levels in stream water and fish. The conceptual model is a key reference in helping to prioritize future remedial actions, defining future monitoring, conducting numerical modeling efforts, and evaluating research needs. (authors)

  7. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, D.D.; MORRIS, S.M.; BANDO, A.; ET AL.

    2004-03-30T23:59:59.000Z

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. There are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows (Lopez et al. 2003)). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around two mid-size coal fired power plants. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. These programs found the following: (1) At both sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Kincaid plant, there was excess soil Hg along heavily traveled roads. The spatial pattern of soil mercury concentrations did not match the pattern of vegetation Hg concentrations at either plant. (2) At both sites, the subsurface (5-10 cm) samples the Hg concentration correlated strongly with the surface samples (0-5 cm). Average subsurface sample concentrations were slightly less than the surface samples, however, the difference was not statistically significant. (3) An unequivocal definition of background Hg was not possible at either site. Using various assumed background soil mercury concentrations, the percentage of mercury deposited within 10 km of the plant ranged between 1.4 and 8.5% of the RGM emissions. Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. Estimates of the percentage of total Hg deposition ranged between 0.3 and 1.7%. These small percentages of deposition are consistent with the empirical findings of only minor perturbations in environmental levels, as opposed to ''hot spots'', near the plants. The major objective of this study was to determine if there was evidence for ''hot spots'' of mercury deposition around coal-fired power plants. Although the term has been used extensively, it has never been defined. From a public health perspective, such a ''hot spot'' must be large enough to insure that it did not occur by chance, and it must affect water bodies large enough to support a population of subsistence fishers. The results of this study support the hypothesis

  8. The retention time of inorganic mercury in the brain — A systematic review of the evidence

    SciTech Connect (OSTI)

    Rooney, James P.K., E-mail: jrooney@rcsi.ie

    2014-02-01T23:59:59.000Z

    Reports from human case studies indicate a half-life for inorganic mercury in the brain in the order of years—contradicting older radioisotope studies that estimated half-lives in the order of weeks to months in duration. This study systematically reviews available evidence on the retention time of inorganic mercury in humans and primates to better understand this conflicting evidence. A broad search strategy was used to capture 16,539 abstracts on the Pubmed database. Abstracts were screened to include only study types containing relevant information. 131 studies of interest were identified. Only 1 primate study made a numeric estimate for the half-life of inorganic mercury (227–540 days). Eighteen human mercury poisoning cases were followed up long term including autopsy. Brain inorganic mercury concentrations at death were consistent with a half-life of several years or longer. 5 radionucleotide studies were found, one of which estimated head half-life (21 days). This estimate has sometimes been misinterpreted to be equivalent to brain half-life—which ignores several confounding factors including limited radioactive half-life and radioactive decay from surrounding tissues including circulating blood. No autopsy cohort study estimated a half-life for inorganic mercury, although some noted bioaccumulation of brain mercury with age. Modelling studies provided some extreme estimates (69 days vs 22 years). Estimates from modelling studies appear sensitive to model assumptions, however predications based on a long half-life (27.4 years) are consistent with autopsy findings. In summary, shorter estimates of half-life are not supported by evidence from animal studies, human case studies, or modelling studies based on appropriate assumptions. Evidence from such studies point to a half-life of inorganic mercury in human brains of several years to several decades. This finding carries important implications for pharmcokinetic modelling of mercury and potentially for the regulatory toxicology of mercury.

  9. Low current plasmatron fuel converter having enlarged volume discharges

    DOE Patents [OSTI]

    Rabinovich, Alexander (Swampscott, MA); Alexeev, Nikolai (Moscow, RU); Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Samokhin, Andrei (Moscow, RU)

    2009-10-06T23:59:59.000Z

    A novel apparatus and method is disclosed for a plasmatron fuel converter ("plasmatron") that efficiently uses electrical energy to produce hydrogen rich gas. The volume and shape of the plasma discharge is controlled by a fluid flow established in a plasma discharge volume. A plasmatron according to this invention produces a substantially large effective plasma discharge volume allowing for substantially greater volumetric efficiency in the initiation of chemical reactions within a volume of bulk fluid reactant flowing through the plasmatron.

  10. Low current plasmatron fuel converter having enlarged volume discharges

    DOE Patents [OSTI]

    Rabinovich, Alexander; Alexeev, Nikolai; Bromberg, Leslie; Cohn, Daniel R.; Samokhin, Andrei

    2005-04-19T23:59:59.000Z

    A novel apparatus and method is disclosed for a plasmatron fuel converter (""plasmatron"") that efficiently uses electrical energy to produce hydrogen rich gas. The volume and shape of the plasma discharge is controlled by a fluid flow established in a plasma discharge volume. A plasmatron according to this invention produces a substantially large effective plasma discharge volume allowing for substantially greater volumetric efficiency in the initiation of chemical reactions within a volume of bulk fluid reactant flowing through the plasmatron.

  11. Molecular structure and dynamics in bacterial mercury resistance

    SciTech Connect (OSTI)

    Johs, Alexander [ORNL] [ORNL; Shi, Liang [ORNL] [ORNL; Miller, Susan M [ORNL] [ORNL; Summers, Anne O [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL

    2008-01-01T23:59:59.000Z

    Bacteria participate significantly in mercury transformation in natural and industrial environments. Previous studies have shown that bacterial mercury resistance is mediated by the mer operon, typically located on transposons or plasmids. It encodes specific genes that facilitate uptake of mercury species, cleavage of organomercurials, and reduction of Hg(II) to Hg(0). Expression of mer operon genes is regulated by MerR, a metal-responsive regulator protein on the level of transcription. In vitro studies have shown that MerR forms a non-transcribing pre-initiation complex with RNA polymerase and the promoter DNA. Binding of Hg(II) induces conformational changes in MerR and other components of the complex resulting in the transcription of mer operon genes. As part of ongoing investigations on allosteric conformational changes induced by Hg(II) in dimeric MerR, and the implications on the binding of RNA polymerase to the promoter of the mer operon, we applied small angle scattering to study the regulatory mechanism of MerR in the presence and absence of Hg(II). Our results show that in the presence of Hg(II) the MerR dimer undergoes a significant reorientation from a compact state to a conformation revealing two distinct domains. Bacterial reduction of Hg(II) can also occur at concentrations too low to induce mer operon functions. Dissimilatory metal reducing bacteria, such as Shewanella and Geobacter are able to reduce Hg(II) in the presence of mineral oxides. This process has been linked to the activity of outer membrane multiheme cytochromes. We isolated and purified a decaheme outer membrane cytochrome OmcA from Shewanella oneidensis MR-1 and characterized its envelope shape in solution by small angle x-ray scattering. Structural features were identified and compared to homology models. These results show that OmcA is an elongated macromolecule consisting of separate modules, which may be connected by flexible linkers.

  12. Notice of Intent (NOI) for Storm Water Discharges Associated...

    Open Energy Info (EERE)

    Intent (NOI) for Storm Water Discharges Associated with Construction Activities under TPDES General Permit (TXR150000) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  13. abnormal glow discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29 Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup Texas A&M University - TxSpace Summary: ......

  14. atmospheric glow discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    34 Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup Texas A&M University - TxSpace Summary: ......

  15. ablation glow discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29 Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup Texas A&M University - TxSpace Summary: ......

  16. analytical glow discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29 Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup Texas A&M University - TxSpace Summary: ......

  17. WAC - 173 - 221 - Discharge Standards and Effluent Limitations...

    Open Energy Info (EERE)

    WAC - 173 - 221 - Discharge Standards and Effluent Limitations for Domestic Wastewater Facilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document-...

  18. File:CDPHE Industrial Individual Wastewater Discharge Permit...

    Open Energy Info (EERE)

    Industrial Individual Wastewater Discharge Permit Application.pdf Jump to: navigation, search File File history File usage Metadata File:CDPHE Industrial Individual Wastewater...

  19. WAC - 173 - 220 - National Pollutant Discharge Elimination System...

    Open Energy Info (EERE)

    Reference LibraryAdd to library Legal Document- RegulationRegulation: WAC - 173 - 220 - National Pollutant Discharge Elimination System Permit ProgramLegal Published NA Year...

  20. Point Source Discharges to Surface Waters (North Carolina)

    Broader source: Energy.gov [DOE]

    This rule requires permits for control of sources of water pollution by providing the requirements and procedures for application and issuance of state National Pollutant Discharge Elimination...

  1. atmospheric pressure discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de 367 Journal of Photochemistry and Photobiology A: Chemistry 140 (2001) 185189 The electrodeless discharge lamp: a prospective tool for photochemistry Chemistry Websites...

  2. atmospheric pressure discharges: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de 367 Journal of Photochemistry and Photobiology A: Chemistry 140 (2001) 185189 The electrodeless discharge lamp: a prospective tool for photochemistry Chemistry Websites...

  3. Oklahoma Pollutant Discharge Elimination System (OPDES) Standards (Oklahoma)

    Broader source: Energy.gov [DOE]

    This program of the Water Quality Division of the Department of Environmental Quality sets the point source, biosolids (sewage sludge), and stormwater permitting standards for discharges to the...

  4. Notice of Intent for Stormwater Discharges Associated with Constructio...

    Open Energy Info (EERE)

    of Intent for Stormwater Discharges Associated with Construction Activity on Moderate Risk Sites Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Notice...

  5. Notice of Intent for Stormwater Discharges Associated with Constructio...

    Open Energy Info (EERE)

    Notice of Intent for Stormwater Discharges Associated with Construction Activity on Low Risk Sites Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal...

  6. Cathode fall measurement in a dielectric barrier discharge in helium

    SciTech Connect (OSTI)

    Hao, Yanpeng; Zheng, Bin; Liu, Yaoge [School of Electric Power, South China University of Technology, Guangzhou 510640 (China)] [School of Electric Power, South China University of Technology, Guangzhou 510640 (China)

    2013-11-15T23:59:59.000Z

    A method based on the “zero-length voltage” extrapolation is proposed to measure cathode fall in a dielectric barrier discharge. Starting, stable, and discharge-maintaining voltages were measured to obtain the extrapolation zero-length voltage. Under our experimental conditions, the “zero-length voltage” gave a cathode fall of about 185 V. Based on the known thickness of the cathode fall region, the spatial distribution of the electric field strength in dielectric barrier discharge in atmospheric helium is determined. The strong cathode fall with a maximum field value of approximately 9.25 kV/cm was typical for the glow mode of the discharge.

  7. The Physiologic Effects of Multiple Simultaneous Electronic Control Device Discharges

    E-Print Network [OSTI]

    Dawes, Donald M.; Ho, Jeffrey D; Reardon, Robert F; Sweeney, James D; Miner, James R

    2010-01-01T23:59:59.000Z

    physiologic effects of conducted electrical weapon dischargePhysiological effects of a conducted electrical weapon onLL, et al. Respiratory effect of prolonged electrical weapon

  8. Treated wastewater discharged from municipal wastewater treatment plants (WWTPs) contains

    E-Print Network [OSTI]

    Fay, Noah

    Treated wastewater discharged from municipal wastewater treatment plants (WWTPs) contains plants radically improve the overall quality of the treated wastewa- ter compared to secondary plants

  9. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters- Lessons Learned From Mammoth Mountain, USA Jump to: navigation, search OpenEI Reference LibraryAdd to...

  10. Hydrothermal Heat Discharge In The Cascade Range, Northwestern...

    Open Energy Info (EERE)

    United States Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hydrothermal Heat Discharge In The Cascade Range, Northwestern United States...

  11. Techniques for Mercury Control and Measurement in Gasification Systems

    SciTech Connect (OSTI)

    Granite, E.J.; King, W.P.; Pennline, H.W.

    2002-09-20T23:59:59.000Z

    A major concern for power systems that use coal as an energy source is the air emissions from the plant. Although certain air emissions are currently regulated, the emergence of new regulations for other pollutants are on the horizon. Gasification is an important strategy for increasing the utilization of abundant domestic coal reserves. The Department of Energy envisions increased use of gasification in the United States during the next twenty years. As such, the DOE Gasification Technologies Program will strive to approach a near-zero emissions goal with respect to pollutants. The mercury research detailed in this proposal addresses the Gas Cleaning and Conditioning program technology area.

  12. Fate of Mercury in Synthetic Gypsum Used for Wallboard Production

    SciTech Connect (OSTI)

    Jessica Sanderson; Gary M. Blythe; Mandi Richardson

    2006-12-01T23:59:59.000Z

    This report presents and discusses results from Task 6 of the study 'Fate of Mercury in Synthetic Gypsum Used for Wallboard Production,' performed at a full-scale commercial wallboard plant. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies involve the capture of mercury in FGD systems. The objective of this study is to determine whether any mercury is released into the atmosphere when the synthetic gypsum material is used as a feedstock for wallboard production. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope now includes six discrete tasks, each conducted at various USG wallboard plants using synthetic gypsum from different FGD systems. The project was originally composed of five tasks, which were to include (1) a baseline test, then variations representing differing power plant: (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5, which was to include testing with an alternate FGD reagent, could not be conducted as planned. Instead, Task 5 was conducted at conditions similar to Task 3, although with gypsum from an alternate FGD system. Subsequent to conducting Task 5 under these revised conditions, an opportunity arose to test gypsum produced at the same FGD system, but with an additive (Degussa Corporation's TMT-15) being used in the FGD system. TMT-15 was expected to impact the stability of mercury in synthetic gypsum used to produce wallboard, so Task 6 was added to the project to test this theory. In this project, process stacks in the wallboard plant have been sampled using the Ontario Hydro method. For every task, the stack locations sampled have included a dryer for the wet gypsum as it enters the plant and a gypsum calciner. For Tasks 1, 4, 5 and 6, the stack of the dryer for the wet wallboard product was also tested. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. The Ontario Hydro results, process sample mercury concentration data, and process data were used to construct mercury mass balances across the wallboard plants. Task 6 was conducted at a wallboard plant processing synthetic gypsum from a power plant that fires Eastern bituminous coal. The power plant has a single-loop, open spray tower limestone forced oxidation FGD system, with the forced oxidation conducted in the reaction tank integral with the FGD absorber. The FGD system has gypsum fines blow down as part of the dewatering step. The power plant is equipped with a selective catalytic reduction (SCR) system for NOX emissions control, and the SCR was in service during the time period the gypsum tested was produced. Also, as mentioned above, Degussa additive TMT-15 was being added to the FGD system when this gypsum was produced. The results of the Task 6 stack testing, as measured by the Ontario Hydro method, detected that an average of 55% of the incoming mercury was emitted during wallboard production. These losses were distributed as about 4% across the dryer mill, 6% across the board dryer kiln, and 45% across the kettle calciner. Emissions were similar to what Task 5 results showed on a percentage basis, but about 30% lower on a mass basis. The same power plant FGD system produced the synthetic gypsum used in Task 5 (with no use of TMT-15) and in Task 6 (with TMT-15 added to the FGD system). The lower emissions on a mass basis appeared

  13. "Seeing" Mercury Methylation in Progress

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfiresImpurityRotation; 13-2808-1,TransmissionMercury in the

  14. The Mercury Export Ban Act of 2008 requires

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2Uranium Transferon theTed Donat About Us Ted Donat - ofEnergyMercury Export

  15. Microsoft PowerPoint - DOELM_Mercury_Storage.ppt

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTuba City, Arizona, DisposalFourthNrr-osams ADMIN551 - g9.1 06/13Mercury

  16. Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Jim Butz; Terry Hunt

    2005-11-01T23:59:59.000Z

    Public Service Company of Colorado and ADA Technologies, Inc. have performed a study of the injection of activated carbon for the removal of vapor-phase mercury from coal-fired flue gas streams. The project was completed under contract to the US Department of Energy's National Energy Technology Laboratory, with contributions from EPRI and Public Service Company. The prime contractor for the project was Public Service Company, with ADA Technologies as the major subcontractor providing technical support to all aspects of the project. The research and development effort was conducted in two phases. In Phase I a pilot facility was fabricated and tests were performed using dry carbon-based sorbent injection for mercury control on a coal-fired flue gas slipstream extracted from an operating power plant. Phase II was designed to move carbon injection technology towards commercial application on coal-fired power plants by addressing key reliability and operability concerns. Phase II field work included further development work with the Phase I pilot and mercury measurements on several of PSCo's coal-fired generating units. In addition, tests were run on collected sorbent plus fly ash to evaluate the impact of the activated carbon sorbent on the disposal of fly ash. An economic analysis was performed where pilot plant test data was used to develop a model to predict estimated costs of mercury removal from plants burning western coals. Testing in the pilot plant was undertaken to quantify the effects of plant configuration, flue gas temperature, and activated carbon injection rate on mercury removal. All three variables were found to significantly impact the mercury removal efficiency in the pilot. The trends were clear: mercury removal rates increased with decreasing flue gas temperature and with increasing carbon injection rates. Mercury removal was much more efficient with reverse-gas and pulse-jet baghouse configurations than with an ESP as the particulate control device. The native fly ash of the host unit provided significant mercury removal capacity, so that the activated carbon sorbent served as an incremental mercury removal mechanism. Tests run to characterize the waste product, a combination of fly ash and activated carbon on which mercury was present, showed that mercury and other RCRA metals of interest were all below Toxic Characteristic Leaching Procedure (TCLP) regulatory limits in the leachate. The presence of activated carbon in the fly ash was shown to have an effect on the use of fly ash as an additive in the manufacture of concrete, which could limit the salability of fly ash from a plant where activated carbon was used for mercury control.

  17. Hair mercury concentrations and associated factors in an electronic waste recycling area, Guiyu, China

    SciTech Connect (OSTI)

    Ni, Wenqing [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)] [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Chen, Yaowen [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China)] [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China); Huang, Yue; Wang, Xiaoling [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)] [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Zhang, Gairong [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China)] [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China); Luo, Jiayi [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)] [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Wu, Kusheng, E-mail: kswu@stu.edu.cn [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)] [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)

    2014-01-15T23:59:59.000Z

    Objective: Toxic heavy metals are released to the environment constantly from unregulated electronic waste (e-waste) recycling in Guiyu, China, and thus may contribute to the elevation of mercury (Hg) and other heavy metals levels in human hair. We aimed to investigate concentrations of mercury in hair from Guiyu and potential risk factors and compared them with those from a control area where no e-waste processing occurs. Methods: A total of 285 human hair samples were collected from three villages (including Beilin, Xianma, and Huamei) of Guiyu (n=205) and the control area, Jinping district of Shantou city (n=80). All the volunteers were administered a questionnaire regarding socio-demographic characteristics and other possible factors contributed to hair mercury concentration. Hair mercury concentration was analyzed by hydride generation atomic fluorescence spectrometry (AFS). Results: Our results suggested that hair mercury concentrations in volunteers of Guiyu (median, 0.99; range, 0.18–3.98 ?g/g) were significantly higher than those of Jinping (median, 0.59; range, 0.12–1.63 ?g/g). We also observed a higher over-limit ratio (>1 ?g/g according to USEPA) in Guiyu than in Jinping (48.29% vs. 11.25%, P<0.001). Logistic regression model showed that the variables of living house also served as an e-waste workshop, work related to e-waste, family income, time of residence in Guiyu, the distance between home and waste incineration, and fish intake were associated with hair mercury concentration. After multiple stepwise regression analysis, in the Guiyu samples, hair mercury concentration was found positively associated with the time residence in Guiyu (?=0.299, P<0.001), and frequency of shellfish intake (?=0.184, P=0.016); and negatively associated with the distance between home and waste incineration (?=?0.190, P=0.015) and whether house also served as e-waste workshop (?=?0.278, P=0.001). Conclusions: This study investigated human mercury exposure and suggested elevated hair mercury concentrations in an e-waste recycling area, Guiyu, China. Living in Guiyu for a long time and work related to e-waste may primarily contribute to the high hair mercury concentrations. -- Highlights: • Mercury levels in hair samples from Guiyu and risk factors were assessed. • The recruitments from Guiyu were exposed to high levels of mercury. • Primitive e-waste recycling resulted in high mercury exposure of local people.

  18. Ordered dust structures in a glow discharge

    SciTech Connect (OSTI)

    Karasev, V. Yu., E-mail: plasmadust@yandex.ru; Ivanov, A. Yu.; Dzlieva, E. S.; Eikhval'd, A. I. [St. Petersburg State University, Institute of Physics (Russian Federation)

    2008-02-15T23:59:59.000Z

    Highly ordered three-dimensional dust structures are created in a striated glow discharge, and their horizontal cross-sectional images are analyzed. Calculated correlation functions, local correlation parameters, and corresponding approximations are used to classify the state of a structure according to the Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) two-dimensional melting theory and a phenomenological approach. An orientational map based on an orientational parameter is proposed to expose domains in a cross section of a structure. It is shown that a plasma crystal is a polycrystal consisting of hexagonal domains (crystallites). Thermophoretic forces are used to create corners of various angles in the perimeter of the structure. Transition between hexagonal and square cell shapes is observed.

  19. Extreme-UV electrical discharge source

    DOE Patents [OSTI]

    Fornaciari, Neal R. (Tracey, CA); Nygren, Richard E. (Los Ranchos de Albuquerque, NM); Ulrickson, Michael A. (Albuquerque, NM)

    2002-01-01T23:59:59.000Z

    An extreme ultraviolet and soft x-ray radiation electric capillary discharge source that includes a boron nitride housing defining a capillary bore that is positioned between two electrodes one of which is connected to a source of electric potential can generate a high EUV and soft x-ray radiation flux from the capillary bore outlet with minimal debris. The electrode that is positioned adjacent the capillary bore outlet is typically grounded. Pyrolytic boron nitride, highly oriented pyrolytic boron nitride, and cubic boron nitride are particularly suited. The boron nitride capillary bore can be configured as an insert that is encased in an exterior housing that is constructed of a thermally conductive material. Positioning the ground electrode sufficiently close to the capillary bore outlet also reduces bore erosion.

  20. General Conditions Applicable to Water Discharge Permits and Procedures and Criteria for Issuing Water Discharge Permits (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations describe permit and facility requirements for facilities which discharge wastewater. Facility construction, expansion, alteration, production increases, or process modifications...

  1. PRELIMINARY FIELD EVALUATION OF MERCURY CONTROL USING COMBUSTION MODIFICATIONS

    SciTech Connect (OSTI)

    Vitali Lissianski; Antonio Marquez

    2004-02-19T23:59:59.000Z

    In this project General Electric Energy and Environmental Research Corporation conducts a preliminary field evaluation of a novel technology, referred to as Hg/NO{sub x}, that can reduce emissions of both mercury (Hg) and oxides of nitrogen (NO{sub x}) from coal-fired power plants. The evaluation takes place in Green Station Unit 2 operated by Western Kentucky Energy. Reduction of Hg and NO{sub x} emissions in Unit 2 is achieved using coal reburning. Activities during first project year (January 23, 2003--January 22, 2004) included measurements of baseline Hg emissions in Unit 2 and pilot-scale testing. Baseline testing of Hg emissions in Green Unit 2 has been completed. Two fuels were tested with OFA system operating at minimum air flow. Mercury emissions were measured at ESP inlet and outlet, and at the stack using Ontario Hydro revised method. Testing demonstrated that baseline Hg reductions at ESP outlet and stack were 30-45% and 70-80%, respectively. Pilot-scale testing demonstrated good agreement with baseline measurements in Unit 2. Testing showed that fuel composition had an effect on the efficiency of Hg absorption on fly ash. Maximum achieved Hg removal in reburning was close to 90%. Maximum achieved Hg reduction at air staging conditions was 60%. Testing also demonstrated that lowering ESP temperature improved efficiency of Hg removal.

  2. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Michael L. Swanson; Grant E. Dunham; Mark A. Musich

    2007-02-01T23:59:59.000Z

    Three potential additives for controlling mercury emissions from syngas at temperatures ranging from 350 to 500 F (177 to 260 C) were developed. Current efforts are being directed at increasing the effective working temperature for these sorbents and also being able to either eliminate any potential mercury desorption or trying to engineer a trace metal removal system that can utilize the observed desorption process to repeatedly regenerate the same sorbent monolith for extended use. Project results also indicate that one of these same sorbents can also successfully be utilized for arsenic removal. Capture of the hydrogen selenide in the passivated tubing at elevated temperatures has resulted in limited results on the effective control of hydrogen selenide with these current sorbents, although lower-temperature results are promising. Preliminary economic analysis suggests that these Corning monoliths potentially could be more cost-effective than the conventional cold-gas (presulfided activated carbon beds) technology currently being utilized. Recent Hg-loading results might suggest that the annualized costs might be as high as 2.5 times the cost of the conventional technology. However, this annualized cost does not take into account the significantly improved thermal efficiency of any plant utilizing the warm-gas monolith technology currently being developed.

  3. Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Volume1

    SciTech Connect (OSTI)

    Not Available

    2011-01-01T23:59:59.000Z

    Pursuant to the Mercury Export Ban Act of 2008 (P.L. 110-414), DOE was directed to designate a facility or facilities for the long-term management and storage of elemental mercury generated within the United States. Therefore, DOE has analyzed the storage of up to 10,000 metric tons (11,000 tons) of elemental mercury in a facility(ies) constructed and operated in accordance with the Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act (74 FR 31723).DOE prepared this Final Mercury Storage EIS in accordance with the National Environmental Policy Act of 1969 (NEPA), as amended (42 U.S.C. 4321 et seq.), the Council on Environmental Quality (CEQ) implementing regulations (40 CFR 1500–1508), and DOE’s NEPA implementing procedures (10 CFR 1021) to evaluate reasonable alternatives for a facility(ies) for the long-term management and storage of elemental mercury. This Final Mercury Storage EIS analyzes the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven candidate locations:Grand Junction Disposal Site near Grand Junction, Colorado; Hanford Site near Richland, Washington; Hawthorne Army Depot near Hawthorne, Nevada; Idaho National Laboratory near Idaho Falls, Idaho;Kansas City Plant in Kansas City, Missouri; Savannah River Site near Aiken, South Carolina; and Waste Control Specialists, LLC, site near Andrews, Texas. As required by CEQ NEPA regulations, the No Action Alternative was also analyzed as a basis for comparison. DOE intends to decide (1) where to locate the elemental mercury storage facility(ies) and (2) whether to use existing buildings, new buildings, or a combination of existing and new buildings. DOE’s Preferred Alternative for the long-term management and storage of mercury is the Waste Control Specialists, LLC, site near Andrews, Texas.

  4. Influence of water chemistry on mercury concentration in largemouth bass from Florida lakes

    SciTech Connect (OSTI)

    Lange, T.R.; Royals, H.E.; Connor, L.L. (Florida Game and Freshwater Fish Commission, Eustic (United States))

    1993-01-01T23:59:59.000Z

    Harvestable-size largemouth bass Micropterus salmoides were collected from 53 Florida lakes to determine relationships between mercury concentration in fish and physical and chemical lake characteristics. Diverse lakes with a broad range of sizes (15-181,000 hectares), pH (3.6-9.1), and alkalinities (1.2-128 mg/L as CaCO[sub 3]) were sampled. Total mercury concentrations in axial muscle of individual fish ranged from 0.04 to 2.04 [mu]g/g wet weight and were positively correlated with fish age (strongest correlation) and size. There was no difference in the rate of mercury accumulation by age between the sexes, even though females grew faster. Chemical characteristics of lakes strongly influenced the bioaccumulation of mercury in largemouth bass. Mercury concentrations, standardized to age-3 fish for comparison among lakes, ranged from 0.04 to 1.53 [mu]g/g and were negatively correlated with alkalinity, calcium, chlorophyll a, conductance, magnesium, pH, total hardness, total nitrogen, and total phosphorus. No significant correlations were observed between the standardized fish mercury concentration and lake color, secchi transparency, tannic acid, or surface area. Linear regression revealed that pH accounted for 41% of the variation in the standardized fish mercury concentration. Multiple regression revealed that chlorophyll a and alkalinity accounted for 45% of the variation in the standardized fish mercury concentration. Mercury concentrations were significantly higher in lakes with either pH less than 7, alkalinity less than 20 mg/L as CaCO[sub 3], or chlorophyll a less than 10 [mu]g/L. 56 refs., 4 figs., 4 tabs.

  5. Combined homo- and heterogeneous model for mercury speciation in pulverized fuel combustion flue gases

    SciTech Connect (OSTI)

    Shishir P. Sable; Wiebren de Jong; Hartmut Spliethoff [Delft University Technology, Delft (Netherlands). Section Energy Technology, Department of Process and Energy

    2008-01-15T23:59:59.000Z

    A new model is developed to predict Hg{sup 0}, Hg{sup +}, Hg{sup 2+}, and Hg{sub p} in the post-combustion zone upstream of a particulate control device (PCD) in pulverized coal-fired power plants. The model incorporates reactions of mercury with chlorinating agents (HCl) and other gaseous species and simultaneous adsorption of oxidized mercury (HgCl{sub 2}) on fly ash particles in the cooling of flue gases. The homogeneous kinetic model from the literature has been revised to understand the effect of the NO + OH + M {longleftrightarrow} HONO + M reaction on mercury oxidation. Because it is a pressure-dependent reaction, the choice of proper reaction rates was very critical. It was found that mercury oxidation reduces from 100 to 0% while going from high- to low-pressure limit rates with 100 ppmv NO. The heterogeneous model describes selective in-duct Langmuir-Hinshelwood adsorption of mercury chloride on ash particles. The heterogeneous model has been built using Fortran and linked to Chemkin 4.0. The final predictions of elemental, oxidized, and particulate mercury were compared to mercury speciation from power plant data. Information collection request (ICR) data were used for this comparison. The model results follow very similar trends compared to those of the plant data; however, quantitative deviation was considerable. These deviations are due to the errors in the measurement of mercury upstream of PCD, lack of adsorption kinetic data, accurate homogeneous reaction mechanisms, and certain modeling assumptions. The model definitely follows a new approach for the prediction of mercury speciation, and further refinement will improve the model significantly. 43 refs., 1 figs., 6 tabs.

  6. Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Volume 2

    SciTech Connect (OSTI)

    Not Available

    2011-01-01T23:59:59.000Z

    Pursuant to the Mercury Export Ban Act of 2008 (P.L. 110-414), DOE was directed to designate a facility or facilities for the long-term management and storage of elemental mercury generated within the United States. Therefore, DOE has analyzed the storage of up to 10,000 metric tons (11,000 tons) of elemental mercury in a facility(ies) constructed and operated in accordance with the Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act (74 FR 31723). DOE prepared this Final Mercury Storage EIS in accordance with the National Environmental Policy Act of 1969 (NEPA), as amended (42 U.S.C. 4321 et seq.), the Council on Environmental Quality (CEQ) implementing regulations (40 CFR 1500–1508), and DOE’s NEPA implementing procedures (10 CFR 1021) to evaluate reasonable alternatives for a facility(ies) for the long-term management and storage of elemental mercury. This Final Mercury Storage EIS analyzes the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven candidate locations: Grand Junction Disposal Site near Grand Junction, Colorado; Hanford Site near Richland, Washington; Hawthorne Army Depot near Hawthorne, Nevada; Idaho National Laboratory near Idaho Falls, Idaho; Kansas City Plant in Kansas City, Missouri; Savannah River Site near Aiken, South Carolina; and Waste Control Specialists, LLC, site near Andrews, Texas. As required by CEQ NEPA regulations, the No Action Alternative was also analyzed as a basis for comparison. DOE intends to decide (1) where to locate the elemental mercury storage facility(ies) and (2) whether to use existing buildings, new buildings, or a combination of existing and new buildings. DOE’s Preferred Alternative for the long-term management and storage of mercury is the Waste Control Specialists, LLC, site near Andrews, Texas.

  7. State Waste Discharge Permit application for industrial discharge to land: 200 East Area W-252 streams

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    This document constitutes the WAC 173-216 State Waste Discharge Permit application for six W-252 liquid effluent streams at the Hanford Site. Appendices B through H correspond to Section B through H in the permit application form. Within each appendix, sections correspond directly to the respective questions on the application form. The appendices include: Product or service information; Plant operational characteristics; Water consumption and waterloss; Wastewater information; Stormwater; Other information; and Site assessment.

  8. Evaluation of MerCAP for Power Plant Mercury Control

    SciTech Connect (OSTI)

    Carl Richardson

    2008-09-30T23:59:59.000Z

    This report is submitted to the U.S. Department of Energy National Energy Technology Laboratory (DOE-NETL) as part of Cooperative Agreement DE-FC26-03NT41993, 'Evaluation of EPRI's MerCAP{trademark} Technology for Power Plant Mercury Control'. This project has investigated the mercury removal performance of EPRI's Mercury Capture by Amalgamation Process (MerCAP{trademark}) technology. Test programs were conducted to evaluate gold-based MerCAP{trademark} at Great River Energy's Stanton Station Unit 10 (Site 1), which fired both North Dakota lignite (NDL) and Power River Basin (PRB) coal during the testing period, and at Georgia Power's Plant Yates Unit 1 (Site 2) [Georgia Power is a subsidiary of The Southern Company] which fires a low sulfur Eastern bituminous coal. Additional tests were carried out at Alabama Power's Plant Miller, which fires Powder River Basin Coal, to evaluate a carbon-based MerCAP{trademark} process for removing mercury from flue gas downstream of an electrostatic precipitator [Alabama Power is a subsidiary of The Southern Company]. A full-scale gold-based sorbent array was installed in the clean-air plenum of a single baghouse compartment at GRE's Stanton Station Unit 10, thereby treating 1/10th of the unit's exhaust gas flow. The substrates that were installed were electroplated gold screens oriented parallel to the flue gas flow. The sorbent array was initially installed in late August of 2004, operating continuously until its removal in July 2006, after nearly 23 months. The initial 4 months of operation were conducted while the host unit was burning North Dakota lignite (NDL). In November 2004, the host unit switched fuel to burn Powder River Basin (PRB) subbituminous coal and continued to burn the PRB fuel for the final 19 months of this program. Tests were conducted at Site 1 to evaluate the impacts of flue gas flow rate, sorbent plate spacing, sorbent pre-cleaning and regeneration, and spray dryer operation on MerCAP{trademark} performance. At Site 2, a pilot-scale array was installed in a horizontal reactor chamber designed to treat approximately 2800 acfm of flue gas obtained from downstream of the plant's flue gas desulfurization (FGD) system. The initial MerCAP{trademark} array was installed at Plant Yates in January 2004, operating continuously for several weeks before a catastrophic system failure resulting from a failed flue gas fan. A second MerCAP{trademark} array was installed in July 2006 and operated for one month before being shut down for a reasons pertaining to system performance and host site scheduling. A longer-term continuous-operation test was then conducted during the summer and fall of 2007. Tests were conducted to evaluate the impacts of flue gas flow rate, sorbent space velocity, and sorbent rinsing frequency on mercury removal performance. Detailed characterization of treated sorbent plates was carried out in an attempt to understand the nature of reactions leading to excessive corrosion of the substrate surfaces.

  9. An ultra miniature pinch-focus discharge Leopoldo Soto1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Abstract As a way to investigate the minimum energy to produce a pinch plasma focus discharge, an ultra optimized plasma foci. It is interesting note that plasma parameters practically constant in plasma focusAn ultra miniature pinch-focus discharge Leopoldo Soto1 , Cristian Pavez1, 2 , Mario Barbaglia3

  10. Characteristics of a corona discharge with a hot corona electrode

    SciTech Connect (OSTI)

    Kulumbaev, E. B.; Lelevkin, V. M.; Niyazaliev, I. A.; Tokarev, A. V. [Kyrgyz-Russian Slavic University (Kyrgyzstan)

    2011-08-15T23:59:59.000Z

    The effect of the temperature of the corona electrode on the electrical characteristics of a corona discharge was studied experimentally. A modified Townsend formula for the current-voltage characteristic of a one-dimensional corona is proposed. Gasdynamic and thermal characteristics of a positive corona discharge in a coaxial electrode system are calculated. The calculated results are compared with the experimental data.

  11. Faraday Accelerator with Radio-frequency Assisted Discharge (FARAD)

    E-Print Network [OSTI]

    Choueiri, Edgar

    rights reserved. #12;Abstract A new electrodeless accelerator concept, called Faraday Accelerator with Radio-frequency Assisted Discharge (FARAD), that relies on an RF-assisted discharge to produce a plasma, an applied magnetic field to guide the plasma into the acceleration region, and an induced current sheet

  12. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, Gary (Gloucester, VA); D'Silva, Arthur P. (Ames, IA); Fassel, Velmer A. (Ames, IA)

    1986-05-06T23:59:59.000Z

    An apparatus for providing a simple, low-frequency electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  13. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, G.; D'Silva, A.P.; Fassel, V.A.

    1985-04-05T23:59:59.000Z

    An apparatus for providing a simple, low-frequency, electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  14. Discharge indices for water quality loads Richard M. Vogel

    E-Print Network [OSTI]

    Vogel, Richard M.

    : effective discharge, transport, sediment, constituents, rating curve, half-load Citation: Vogel, R. M., J. RDischarge indices for water quality loads Richard M. Vogel Department of Civil and Environmental load is ultimately the quantity of interest, we define a new index, the half-load discharge, which

  15. Modeling and Experimental Studies of Mercury Oxidation and Adsorption in a Fixed-Bed Reactor

    SciTech Connect (OSTI)

    Paula A. Buitrago, Mike Morrill, JoAnn S. Lighty, Geoffrey D.; Silcox,

    2009-06-15T23:59:59.000Z

    This report presents experimental and modeling mercury oxidation and adsorption data. Fixed-bed and single-particle models of mercury adsorption were developed. The experimental data were obtained with two reactors: a 300- W, methane-fired, tubular, quartz-lined reactor for studying homogeneous oxidation reactions and a fixed-bed reactor, also of quartz, for studying heterogeneous reactions. The latter was attached to the exit of the former to provide realistic combustion gases. The fixed-bed reactor contained one gram of coconut-shell carbon and remained at a temperature of 150oC. All methane, air, SO2, and halogen species were introduced through the burner to produce a radical pool representative of real combustion systems. A Tekran 2537A Analyzer coupled with a wet conditioning system provided speciated mercury concentrations. At 150°C and in the absence of HCl or HBr, the mercury uptake was about 20%. The addition of 50 ppm HCl caused complete capture of all elemental and oxidized mercury species. In the absence of halogens, SO2 increased the mercury adsorption efficiency to up to 30 percent. The extent of adsorption decreased with increasing SO2 concentration when halogens were present. Increasing the HCl concentration to 100 ppm lessened the effect of SO2. The fixed-bed model incorporates Langmuir adsorption kinetics and was developed to predict adsorption of elemental mercury and the effect of multiple flue gas components. This model neglects intraparticle diffusional resistances and is only applicable to pulverized carbon sorbents. It roughly describes experimental data from the literature. The current version includes the ability to account for competitive adsorption between mercury, SO2, and NO2. The single particle model simulates in-flight sorbent capture of elemental mercury. This model was developed to include Langmuir and Freundlich isotherms, rate equations, sorbent feed rate, and intraparticle diffusion. The Freundlich isotherm more accurately described in-flight mercury capture. Using these parameters, very little intraparticle diffusion was evident. Consistent with other data, smaller particles resulted in higher mercury uptake due to available surface area. Therefore, it is important to capture the particle size distribution in the model. At typical full-scale sorbent feed rates, the calculations underpredicted adsorption, suggesting that wall effects can account for as much as 50 percent of the removal, making it an important factor in entrained-mercury adsorption models.

  16. Hanford Identification (HID) PIA, Richland Operations Office | Department

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently20,000 RussianBy: Thomas P. D'Agostino,GlenLearning and DevelopmentDepartmentof

  17. RAPID/Roadmap/18-HI-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to: navigation, search RAPIDaUT-abb <HI-d

  18. RAPID/Roadmap/3-HI-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to: navigation, searche < (1)NV-a3ed <

  19. RAPID/Roadmap/6-HI-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to: navigation, searcheWA-a < RAPID‎cd

  20. RAPID/Roadmap/14-HI-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformation TexasTexas)ID-a <RAPID/Roadmap/14adFD-cad

  1. State Waste Discharge Permit application: 400 Area Septic System

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affects groundwater or has the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 400 Area Septic System. The influent to the system is domestic waste water. Although the 400 Area Septic System is not a Public Owned Treatment Works, the Public Owned Treatment Works application is more applicable than the application for industrial waste water. Therefore, the State Waste Discharge Permit application for Public Owned Treatment Works Discharges to Land was used.

  2. State Waste Discharge Permit application: 200-E Powerhouse Ash Pit

    SciTech Connect (OSTI)

    Atencio, B.P.

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department and Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-E Powerhouse Ash Pit. The 200-E Powerhouse Ash Waste Water discharges to the 200-E Powerhouse Ash Pit via dedicated pipelines. The 200-E Ash Waste Water is the only discharge to the 200-E Powerhouse Ash Pit. The 200-E Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

  3. State Waste Discharge Permit application: 200-W Powerhouse Ash Pit

    SciTech Connect (OSTI)

    Atencio, B.P.

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

  4. Parallel vacuum arc discharge with microhollow array dielectric and anode

    SciTech Connect (OSTI)

    Feng, Jinghua; Zhou, Lin; Fu, Yuecheng; Zhang, Jianhua; Xu, Rongkun; Chen, Faxin; Li, Linbo; Meng, Shijian, E-mail: mengshijian04@126.com [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China)

    2014-07-15T23:59:59.000Z

    An electrode configuration with microhollow array dielectric and anode was developed to obtain parallel vacuum arc discharge. Compared with the conventional electrodes, more than 10 parallel microhollow discharges were ignited for the new configuration, which increased the discharge area significantly and made the cathode eroded more uniformly. The vacuum discharge channel number could be increased effectively by decreasing the distances between holes or increasing the arc current. Experimental results revealed that plasmas ejected from the adjacent hollow and the relatively high arc voltage were two key factors leading to the parallel discharge. The characteristics of plasmas in the microhollow were investigated as well. The spectral line intensity and electron density of plasmas in microhollow increased obviously with the decease of the microhollow diameter.

  5. Plasma mixing glow discharge device for analytical applications

    DOE Patents [OSTI]

    Pinnaduwage, L.A.

    1999-04-20T23:59:59.000Z

    An instrument for analyzing a sample has an enclosure that forms a chamber containing an anode which divides the chamber into a discharge region and an analysis region. A gas inlet and outlet are provided to introduce and exhaust a rare gas into the discharge region. A cathode within the discharge region has a plurality of pins projecting in a geometric pattern toward the anode for exciting the gas and producing a plasma discharge between the cathode and the anode. Low energy electrons (e.g. <0.5 eV) pass into the analysis region through an aperture. The sample to be analyzed is placed into the analysis region and bombarded by the metastable rare gas atoms and the low energy electrons extracted into from the discharge region. A mass or optical spectrometer can be coupled to a port of the analysis region to analyze the resulting ions and light emission. 3 figs.

  6. Plasma mixing glow discharge device for analytical applications

    DOE Patents [OSTI]

    Pinnaduwage, Lal A. (Knoxville, TN)

    1999-01-01T23:59:59.000Z

    An instrument for analyzing a sample has an enclosure that forms a chamber containing an anode which divides the chamber into a discharge region and an analysis region. A gas inlet and outlet are provided to introduce and exhaust a rare gas into the discharge region. A cathode within the discharge region has a plurality of pins projecting in a geometric pattern toward the anode for exciting the gas and producing a plasma discharge between the cathode and the anode. Low energy electrons (e.g. <0.5 eV) pass into the analysis region through an aperture. The sample to be analyzed is placed into the analysis region and bombarded by the metastable rare gas atoms and the low energy electrons extracted into from the discharge region. A mass or optical spectrometer can be coupled to a port of the analysis region to analyze the resulting ions and light emission.

  7. Progress and Future Plans for Mercury Remediation at the Y-12 National Security Complex, Oak Ridge, Tennessee - 13059

    SciTech Connect (OSTI)

    Wilkerson, Laura O. [DOE Oak Ridge, P.O. Box 2001, Oak Ridge, TN 37831 (United States)] [DOE Oak Ridge, P.O. Box 2001, Oak Ridge, TN 37831 (United States); DePaoli, Susan M. [Pro2Serve, 1100 Bethel Valley Rd., Oak Ridge, TN 37830 (United States)] [Pro2Serve, 1100 Bethel Valley Rd., Oak Ridge, TN 37830 (United States); Turner, Ralph [P.O. Box 421, Squamish, BC V8B 0A4 (United States)] [P.O. Box 421, Squamish, BC V8B 0A4 (United States)

    2013-07-01T23:59:59.000Z

    The U.S. Department of Energy (DOE), along with the Tennessee Department of Environment and Conservation (TDEC) and the U.S. Environmental Protection Agency (EPA), has identified mercury contamination at the Y-12 National Security Complex (Y-12) as the highest priority cleanup risk on the Oak Ridge Reservation (ORR). The historic loss of mercury to the environment dwarfs any other contaminant release on the ORR. Efforts over the last 20 years to reduce mercury levels leaving the site in the surface waters of Upper East Fork Poplar Creek (UEFPC) have not resulted in a corresponding decrease in mercury concentrations in fish. Further reductions in mercury surface water concentrations are needed. Recent stimulus funding through the American Recovery and Reinvestment Act of 2009 (ARRA) has supported several major efforts involving mercury cleanup at Y-12. Near-term implementation activities are being pursued with remaining funds and include design of a centrally located mercury treatment facility for waterborne mercury, treatability studies on mercury-contaminated soils, and free mercury removal from storm drains. Out-year source removal will entail demolition/disposal of several massive uranium processing facilities along with removal and disposal of underlying contaminated soil. As a National Priorities List (NPL) site, cleanup is implemented under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and directed by the Federal Facility Agreement (FFA) between DOE, EPA, and TDEC. The CERCLA process is followed to plan, reach approval, implement, and monitor the cleanup. (authors)

  8. Advanced Materials for Mercury 50 Gas Turbine Combustion System

    SciTech Connect (OSTI)

    Price, Jeffrey

    2008-09-30T23:59:59.000Z

    Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated before down-selection to the most promising candidate materials for field evaluation. Preliminary, component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing was used to validated engine performance prior to field evaluation at a Qualcomm Inc. cogeneration site located in San Diego, California. To ensure that the CFCC liners with the EBC proposed under this program would meet the target life, field evaluations of ceramic matrix composite liners in Centaur{reg_sign} 50 gas turbine engines, which had previously been conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), was continued under this program at commercial end-user sites under Program Subtask 1A - Extended CFCC Materials Durability Testing. The goal of these field demonstrations was to demonstrate significant component life, with milestones of 20,000 and 30,000 hours. Solar personnel monitor the condition of the liners at the field demonstration sites through periodic borescope inspections and emissions measurements. This program was highly successful at evaluating advanced materials and down-selecting promising solutions for use in gas turbine combustions systems. The addition of the advanced materials technology has enabled the predicted life of the Mercury 50 combustion system to reach 30,000 hours, which is Solar's typical time before overhaul for production engines. In particular, a 40 mil thick advanced Thermal Barrier Coating (TBC) system was selected over various other TBC systems, ODS liners and CFCC liners for the 4,000-hour field evaluation under the program. This advanced TBC is now production bill-of-material at various thicknesses up to 40 mils for all of Solar's advanced backside-cooled combustor liners (Centaur 50, Taurus 60, Mars 100, Taurus 70,

  9. Low-voltage gas-discharge device

    DOE Patents [OSTI]

    Kovarik, V.J.; Hershcovitch, A.; Prelec, K.

    1982-06-08T23:59:59.000Z

    An electronic device of the type wherein current flow is conducted by an ionized gas comprising a cathode of the type heated by ionic bombardment, an anode, means for maintaining a predetermined pressure in the region between the anode and the cathode and means for maintaining a field in the region is described. The field, which is preferably a combined magnetic and electric field, is oriented so that the mean distance traveled by electrons before reaching the anode is increased. Because of this increased distance traveled electrons moving to the anode will ionize a large number of gas atoms, thus reducing the voltage necessary to initiate gas breakdown. In a preferred embodiment the anode is a main hollow cathode and the cathode is a smaller igniter hollow cathode located within and coaxial with the main hollow cathode. An axial magnetic field is provided in the region between the hollow cathodes in order to facilitate gas breakdown in that region and initiate plasma discharge from the main hollow cathode.

  10. Nanoparticle synthesis in pulsed low temperature discharges

    SciTech Connect (OSTI)

    Buss, R.J.

    1996-06-01T23:59:59.000Z

    Silicon nitride powders with an average size as low as 7 nm are synthesized in a pulsed radio frequency glow discharge. The as-synthesized silicon nitride powder from a silane/ammonia plasma has a high hydrogen content and is sensitive to oxidation in air. Post-plasma heating of the powder in a vacuum results in nitrogen loss, giving silicon-rich powder. In contrast, heat treatment at 800 C for 20 minutes in an ammonia atmosphere (200 Torr pressure) yields a hydrogen-free powder which is stable with respect to atmospheric oxidation. Several approaches to synthesizing silicon carbide nano-size powders are presented. Experiments using silane/hydrocarbon plasmas produce particles with a high hydrogen content as demonstrated by Fourier transform infrared analysis. The hydrogen is present as both CH and SiH functionality. These powders are extremely air-sensitive. A second approach uses a gas mixture of methyltrichlorosilane and hydrogen. The particles have a low hydrogen content and resist oxidation. Particle morphology of the silicon carbide is more spherical and there is less agglomeration than is observed in the silicon nitride powder.

  11. Blockage of IL-6 secretion in glia by lead and mercury

    E-Print Network [OSTI]

    Pourrajabi, Nima Matthew

    2003-01-01T23:59:59.000Z

    Mercury (Hg) and lead (Pb) are toxic to the development and function of the central nervous system (CNS). Interleukin-6 (IL 6) produced by astroglia protects neurons from damage in many progressive degenerative disorders. IL-6 secretion...

  12. Emissions, Monitoring and Control of Mercury from Subbituminous Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Alan Bland; Kumar Sellakumar; Craig Cormylo

    2007-08-01T23:59:59.000Z

    The Subbituminous Energy Coalition (SEC) identified a need to re-test stack gas emissions from power plants that burn subbituminous coal relative to compliance with the EPA mercury control regulations for coal-fired plants. In addition, the SEC has also identified the specialized monitoring needs associated with mercury continuous emissions monitors (CEM). The overall objectives of the program were to develop and demonstrate solutions for the unique emission characteristics found when burning subbituminous coals. The program was executed in two phases; Phase I of the project covered mercury emission testing programs at ten subbituminous coal-fired plants. Phase II compared the performance of continuous emission monitors for mercury at subbituminous coal-fired power plants and is reported separately. Western Research Institute and a number of SEC members have partnered with Eta Energy and Air Pollution Testing to assess the Phase I objective. Results of the mercury (Hg) source sampling at ten power plants burning subbituminous coal concluded Hg emissions measurements from Powder River Basin (PBR) coal-fired units showed large variations during both ICR and SEC testing. Mercury captures across the Air Pollution Control Devices (APCDs) present much more reliable numbers (i.e., the mercury captures across the APCDs are positive numbers as one would expect compared to negative removal across the APCDs for the ICR data). Three of the seven units tested in the SEC study had previously shown negative removals in the ICR testing. The average emission rate is 6.08 lb/TBtu for seven ICR units compared to 5.18 lb/TBtu for ten units in the SEC testing. Out of the ten (10) SEC units, Nelson Dewey Unit 1, burned a subbituminous coal and petcoke blend thus lowering the total emission rate by generating less elemental mercury. The major difference between the ICR and SEC data is in the APCD performance and the mercury closure around the APCD. The average mercury removal values across the APCDs are 2.1% and 39.4% with standard deviations (STDs) of 1990 and 75%, respectively for the ICR and SEC tests. This clearly demonstrates that variability is an issue irrespective of using 'similar' fuels at the plants and the same source sampling team measuring the species. The study also concluded that elemental mercury is the main Hg specie that needs to be controlled. 2004 technologies such as activated carbon injection (ACI) may capture up to 60% with double digit lb/MMacf addition of sorbent. PRB coal-fired units have an Hg input of 7-15 lb/TBtu; hence, these units must operate at over 60% mercury efficiency in order to bring the emission level below 5.8 lb/TBtu. This was non-achievable with the best technology available as of 2004. Other key findings include: (1) Conventional particulate collectors, such as Cold-side Electro-Static Precipitators (CESPs), Hot-side Electro-Static Precipitator (HESP), and Fabric Filter (FF) remove nearly all of the particulate bound mercury; (2) CESPs perform better highlighting the flue gas temperature effect on the mercury removal. Impact of speciation with flue gas cooling is apparent; (3) SDA's do not help in enhancing adsorption of mercury vapor species; and (4) Due to consistently low chlorine values in fuels, it was not possible to analyze the impact of chlorine. In summary, it is difficult to predict the speciation at two plants that burn the same fuel. Non-fuel issues, such as flue gas cooling, impact the speciation and consequently mercury capture potential.

  13. Re-Implementing a Machine Learning Program in Mercury Gregory D. Weber

    E-Print Network [OSTI]

    Weber, Gregory D.

    Re-Implementing a Machine Learning Program in Mercury Gregory D. Weber Computer Science Department. Motivation During the course of testing the machine learning pro- gram ICN (Weber 2003), it became clear

  14. Selective extraction of copper, mercury, silver and palladium ions from water using hydrophobic ionic liquids.

    E-Print Network [OSTI]

    Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; Von Stosch, Moritz; Prausnitz, John M.

    2008-01-01T23:59:59.000Z

    for metal-ion extraction from water. All ionic liquids (useful for extraction of cations from water. 9-15 Previoussingle extraction of mercury in water with either [3MOPYR

  15. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,E . • 1977; Mercury in Oil Shale from the Mahogany Zone the

  16. A Solid-State 199Hg NMR Study of Mercury Halides

    E-Print Network [OSTI]

    Taylor, Robert E; Bai, Shi; Dybowski, Cecil

    2011-01-01T23:59:59.000Z

    550 (1998), 89-99. [25] R. E. Taylor, C. T. Carver, R. E.7 (1997), 333-336. [33] R. E. Taylor, Concepts Magn. Reson.Study of Mercury Halides R. E. Taylor 1 *, Shi Bai 2 , and

  17. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . • 1977; Mercury in Oil Shale from the Mahogany Zone

  18. Geophysical insights into the histories of Venus, Mercury and the Moon

    E-Print Network [OSTI]

    James, Peter Benjamin

    2014-01-01T23:59:59.000Z

    Gravity and topography data provide a powerful tool for studying the interiors of rocky planetary bodies. In this thesis I study three such bodies - Venus, Mercury and the Moon - and I use the gravity and topography data ...

  19. VALIDATION OF MERCURY CEMS WHEN COFIRING BIOMASS AT MADISON ELECTRIC'S BLOUNT STATION

    SciTech Connect (OSTI)

    Dennis L. Laudal; Jeffrey S. Thompson

    2000-09-30T23:59:59.000Z

    The state of Wisconsin has been concerned about mercury deposition into its lakes and streams and has been evaluating strategies to reduce mercury emissions. As part of this effort, the Blount Station, owned and operated by Madison Gas and Electric Company (MGE), has undergone a project to evaluate the effects and potential mercury emissions reduction of cofiring preconsumer waste. MGE owns and operates the Blount Generating Station located in central Madison, Wisconsin. At present, Blount operates with nine boilers and six turbine generators. The two largest boilers at Blount produce 400,000 pounds of steam per hour at 950 F and 1250 psi. These larger boilers, MGE's Boiler Nos. 8 and 9, have the capability of cofiring both paper and plastic. MGE's Blount Generating Station was one of the first electric generating stations in the United States to retrofit its existing steam boilers to successfully burn refuse-derived fuel and other alternate fuels including waste paper and wood. It is the No. 9 boiler that was the focus of this project to determine the effect of cofiring PDF (plastic- and paper-derived fuel) on speciated mercury emissions. The project was laid out to compare four different fuel combinations: (1) coal feed only, (2) coal with plastic, (3) coal with paper, and (4) coal with paper and plastic. The design was to run the boiler for 2 days at each condition, thus allowing four samples to be taken at each condition. This plan was aimed at getting at least three representative samples at each condition and allowed for difficulties in sampling and boiler operation. The following objectives were accomplished as part of the project to determine the effects of cofiring PDF on mercury emissions and speciation at MGE Blount Station: Successfully completed all of the mercury sampling for each of the four boiler/PDF conditions using the Ontario Hydro (OH) mercury speciation method; Determined mercury concentrations at the stack location using mercury continuous emission monitors (CEMs) for each of the four boiler/PDF conditions; Calculated the overall mercury mass balance for each of the runs; Determined chlorine concentrations at the stack location using EPA Method 26A for each of the four boiler/PDF conditions; and Calculated speciated mercury flow to determine removal and/or transformations before its exiting the unit at the stack for each of the four boiler/PDF conditions.

  20. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

    2010-12-31T23:59:59.000Z

    This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed-structure mercury sorbent upstream. This final report presents and discusses detailed results from all of these efforts, and makes a number of conclusions about what was learned through these efforts.

  1. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01T23:59:59.000Z

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  2. Regulations for the Rhode Island Pollutant Discharge Elimination System (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations aim to protect surface water from pollutant discharges. They describe allowable discharges in the state that are subject to permits, discharges which may be made without permits,...

  3. Properties of water surface discharge at different pulse repetition rates

    SciTech Connect (OSTI)

    Ruma,; Yoshihara, K. [Graduate School of Science and Technology, Kumamoto University, Kumamoto 860-8555 (Japan); Hosseini, S. H. R., E-mail: hosseini@kumamoto-u.ac.jp; Sakugawa, T.; Akiyama, H. [Graduate School of Science and Technology, Kumamoto University, Kumamoto 860-8555 (Japan); Institute of Pulsed Power Science, Kumamoto University, Kumamoto 860-8555 (Japan); Akiyama, M. [Department of Electrical and Electronic Engineering, Kagoshima University, Kagoshima 890-0065 (Japan); Lukeš, P. [Institute of Plasma Physics, AS CR, Prague, Prague 18200 (Czech Republic)

    2014-09-28T23:59:59.000Z

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000?Hz, with 0.5?J per pulse energy output at 25?kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H{sub 2}O{sub 2}) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H{sub 2}O{sub 2} and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  4. Mercury and the estuarine clam, Rangia cuneata (Mollusca - Bivalvia): uptake and release, survival and osmoregulation

    E-Print Network [OSTI]

    Dillon, T. M

    1976-01-01T23:59:59.000Z

    MERCURY AND THE ESTUARINE CLAM, Rancaia cuneata (MOLLUSCA:BIVALVIA): UPTAKE AND RELEASE, SURVIVAL AND OSMOREGULATION. A Thesis by Thomas Mitchell Dillon Submitted to the Graduate Colleage of Texas A8M University in partial fulfillment... as to style and content by: Co ai of Commi e Co-Chairman of Committee Head of Department December 1976 ABSTRACT Mercury and the Estuarine Clam, Rancaia cuneata (Mollusca:Bivalvia): Uptake and Release, Survival and Dsmoregulation. (December 1976) Thomas...

  5. Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J

    2008-07-01T23:59:59.000Z

    The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

  6. Trace element distribution and mercury speciation in a pilot-scale coal combustor burning Blacksville coal

    SciTech Connect (OSTI)

    Hargis, R.A.; Pennline, H.W. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technical Center

    1997-12-31T23:59:59.000Z

    A series of tests have been conducted on a nominal 500-pound-per-hour, pilot-scale combustion unit to characterize trace element emissions and mercury speciation. The coal fired during the testing was a Blacksville {number_sign}2, medium-sulfur coal, similar to that used by other researchers investigating mercury speciation. A description of the pilot unit operating conditions during the testing is provided. A summary of the gas/solid distribution of trace elements at various locations within the system, material balances, and baghouse removal efficiencies is also supplied. EPA Method 29 was used to determine trace element and speciated mercury concentrations before and after the baghouse. A comparison of these results with past trace element results from this unit and with the findings of other researchers who have used Blacksville coal is also presented. The pilot-scale combustion unit has been characterized in terms of trace element distribution during two tests while burning a medium-sulfur bituminous Blacksville coal. EPA sampling methodology at the inlet to the baghouse and at the stack was used. Results indicate that most of the elements are removed across the baghouse with the exception of mercury and selenium. Both of these elements were found predominantly in the vapor phase. The average mercury speciation revealed that the vapor-phase mercury was primarily in the oxidized form, which is consistent with the findings of other research with Blacksville coal. Material recoveries for most of the elements were very good. The average recovery for mercury further validates that this pilot unit will be a viable system for mercury sampling and control methods.

  7. A kinetic approach to the catalytic oxidation of mercury in flue gas

    SciTech Connect (OSTI)

    Albert A. Presto; Evan J. Granite; Andrew Karash; Richard A. Hargis; William J. O'Dowd; Henry W. Pennline [U.S. Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

    2006-10-15T23:59:59.000Z

    Four mercury oxidation catalysts were tested in a packed bed reactor in the presence of flue gas generated by the NETL 500 lb/h coal combustor. The four catalysts tested were Ir, Ir/HCl, Darco FGD activated carbon, and Thief/HCl. The Thief/HCl and Darco converted the highest percentage of the inlet mercury; however, the high conversion in these experiments was aided by larger catalyst loadings than in the Ir and Ir/HCl experiments. We propose a method for analyzing mercury oxidation catalyst results in a kinetic framework using the bulk reaction rate for oxidized mercury formation normalized by either the catalyst mass or surface area. Results reported for fractional mercury oxidation are strongly influenced by the specific experimental conditions and are therefore difficult to translate from experiment to experiment. The catalyst-normalized results allow for more quantitative analysis of mercury oxidation catalyst data and are the first step in creating a predictive model that will allow for efficient scaling up from laboratory-scale to larger-scale studies. 34 refs., 1 fig., 3 tabs.

  8. Behavior of mercury in the formic acid vent condenser. Final report

    SciTech Connect (OSTI)

    Zamecnik, J.R.

    1996-07-22T23:59:59.000Z

    The concentrations of mercury at the FAVC inlet and exit were measured during the BL1 and PX6 runs of the Integrated DWPF Melter System (IDMS) with the HEME bypassed and without the ammonia scrubber. The results showed that mercury concentrations of approximately 1.02-12.7 (mean 5.74) times saturation occurred at the FAVC exit. The concentration of mercury at the FAVC inlet was found to be 0.66-6.2 times the saturation value (based on the SRAT condenser exit). In the PX7 run, the ammonia scrubber was used and the FAVC HEME was not bypassed. The results from this run showed that the FAVC inlet concentrations again were above saturation (1.45-15.5 times saturation), but that the FAVC exit concentrations were only 0.02-0.41 times saturation (except for one data point at 1.61 times saturation). Operation of the FAVC without the HEME could therefore result in FAVC exit mercury concentrations of greater than 5.74 times saturation, which would result in DWPF emitting greater than 405 lb/yr of mercury at 100 percent attainment; this quantity is well in excess of the permit limit of 175 lb/yr (for all of DWPF). However, with the HEME in place, the emissions are predicted to be only about 40 lb/yr for an FAVC exit temperature of 10 degrees C. The experimental results also indicate that the ammonia scrubbers have little effect on the removal of mercury.

  9. Development Of Chemical Reduction And Air Stripping Processes To Remove Mercury From Wastewater

    SciTech Connect (OSTI)

    Jackson, Dennis G.; Looney, Brian B.; Craig, Robert R.; Thompson, Martha C.; Kmetz, Thomas F.

    2013-07-10T23:59:59.000Z

    This study evaluates the removal of mercury from wastewater using chemical reduction and air stripping using a full-scale treatment system at the Savannah River Site. The existing water treatment system utilizes air stripping as the unit operation to remove organic compounds from groundwater that also contains mercury (C ~ 250 ng/L). The baseline air stripping process was ineffective in removing mercury and the water exceeded a proposed limit of 51 ng/L. To test an enhancement to the existing treatment modality a continuous dose of reducing agent was injected for 6-hours at the inlet of the air stripper. This action resulted in the chemical reduction of mercury to Hg(0), a species that is removable with the existing unit operation. During the injection period a 94% decrease in concentration was observed and the effluent satisfied proposed limits. The process was optimized over a 2-day period by sequentially evaluating dose rates ranging from 0.64X to 297X stoichiometry. A minimum dose of 16X stoichiometry was necessary to initiate the reduction reaction that facilitated the mercury removal. Competing electron acceptors likely inhibited the reaction at the lower 1 doses, which prevented removal by air stripping. These results indicate that chemical reduction coupled with air stripping can effectively treat large-volumes of water to emerging part per trillion regulatory standards for mercury.

  10. Adsorption and electrode reactions of disulfonated anthraquinones at mercury electrodes

    SciTech Connect (OSTI)

    He, P.; Crooks, R.M.; Faulkner, L.R. (Univ. of Illinois, Urbana (USA))

    1990-02-08T23:59:59.000Z

    Three sulfonated compounds were examined; 2,6-anthraquinonedisulfonate, sodium salt (2,6-AQDS); 1,5-anthraquinone- disulfonate, sodium salt (1,5-AQDS); and 2-anthraquinonemonosulfonate, sodium salt (2-AQMS). Extensive studies of 2,6-AQDS were carried out. This compound undergoes reversible charge exchange with the electrode in an adsorbed state. Electrocapillary curves show that desorption occurs near -0.8 V vs Ag/AgCl, KCl (1 M). Chronocoulometry and cyclic voltammetry were used to evaluate surface coverage vs the concentration of 2,6-AQDS in 0.1 M HNO{sub 3}. Under all conditions, the adsorbed couple shows a standard potential more positive than that for the couple involving dissolved species; hence, the reduced form is the more strongly adsorbed. Effects of pH were examined extensively. In solutions with 2,6-AQDS concentrations above 2 {times} 10{sup 5} M an extremely sharp, reversible pair of spikes develops in the cyclic voltammetry for the adsorbed couple. The spikes are not seen for 1,5-AQDS, but other aspects of behavior for 1,5-AQDS are similar to those of 2,6-AQDS. The Origin of the spikes is discussed via a model involving hydrogen-bonded aggregates. Extensive exposure of a mercury surface to high concentrations of 2,6-AQDS produces a catalytic effect on the electrode reaction involving the dissolved quinone. Further exposure causes an inhibition of the same process. These effects are attributed to the growth of extended films on the mercury.

  11. Entrainment by Spatiotemporal Chaos in Glow Discharge-Semiconductor Systems

    E-Print Network [OSTI]

    Marat Akhmet; Ismail Rafatov; Mehmet Onur Fen

    2014-06-15T23:59:59.000Z

    Entrainment of limit cycles by chaos [1] is discovered numerically through specially designed unidirectional coupling of two glow discharge-semiconductor systems. By utilizing the auxiliary system approach [2], it is verified that the phenomenon is not a chaos synchronization. Simulations demonstrate various aspects of the chaos appearance in both drive and response systems. Chaotic control is through the external circuit equation and governs the electrical potential on the boundary. The expandability of the theory to collectives of glow discharge systems is discussed, and this increases the potential of applications of the results. Moreover, the research completes the previous discussion of the chaos appearance in a glow discharge-semiconductor system [3].

  12. Permit Program Regulating Discharge of Nondomestic Wastewater into a POTW (Ohio)

    Broader source: Energy.gov [DOE]

    Any significant industrial user is required to apply for and obtain an individual indirect discharge permit if they discharge water or waste into a publicly owned treatment works.

  13. LOCAL IMPACTS OF MERCURY EMISSIONS FROM THE MONTICELLO COAL FIRED POWER PLANT.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; ADAMS, J.; MILIAN, L.; SUBRAMANIAN, S.; FEAGIN, L.; WILLIAMS, J.; BOYD, A.

    2006-10-31T23:59:59.000Z

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as currently proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury ''hot spots'', using two types of evidence. First, the world-wide literature was searched for reports of deposition around mercury sources, including coal-fired power plants. Second, soil samples from around two mid-sized U.S. coal-fired power plants were collected and analyzed for evidence of ''hot spots'' and for correlation with model predictions of deposition. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (A) local soil concentration Hg increments of 30%-60%, (B) sediment increments of 18-30%, (C) wet deposition increments of 11-12%, and (D) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around the Monticello coal fired power plant. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. The study found the following: (1) There was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Monticello plant, excess soil Hg was associated with soil characteristics with higher values near the lake. Vegetation concentration showed some correlation with soil concentrations having higher mercury in vegetation when the soil mercury. (2) Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. The total deposition within 50 Km of the plant was predicted to be 4.2% of the total emitted. In the deposition, RGM is responsible for 98.7% of the total deposition, elemental mercury accounts for 1.1% and particulate mercury accounts for 0.2%. Less than 1% of the elemental mercury emitted was predicted to deposit within 50 km.

  14. Mercury in the Northeastern Chukchi Sea: Distribution patterns in seawater and sediments and biomagnification in the benthic food web

    SciTech Connect (OSTI)

    Fox, Austin L.; Hughes, Emily A.; Trocine, R. P.; Trefry, John; Schonberg, Susan V.; McTigue, Nathan D.; Lasorsa, Brenda K.; Konar, Brenda; Cooper, L. W.

    2014-04-01T23:59:59.000Z

    Mercury contamination in the atmosphere, snow and marine mammals of the Artic has been a continuing environmental concern and the focus of many investigations.

  15. Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”

    SciTech Connect (OSTI)

    Granite, E.J.; Presto, A.A.

    2008-09-01T23:59:59.000Z

    A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

  16. Recent Approaches to Modeling Transport of Mercury in Surface Water and Groundwater - Case Study in Upper East Fork Poplar Creek, Oak Ridge, TN - 13349

    SciTech Connect (OSTI)

    Bostick, Kent; Daniel, Anamary [Professional Project Services, Inc., Bethel Valley Road, Oak Ridge, TN, 37922 (United States)] [Professional Project Services, Inc., Bethel Valley Road, Oak Ridge, TN, 37922 (United States); Tachiev, Georgio [Florida International University, Applied Research Center 10555 W. Flagler St., EC 2100 Miami Florida 33174 (United States)] [Florida International University, Applied Research Center 10555 W. Flagler St., EC 2100 Miami Florida 33174 (United States); Malek-Mohammadi, Siamak [Bradley University, 413A Jobst Hall, Preoria, IL 61625 (United States)] [Bradley University, 413A Jobst Hall, Preoria, IL 61625 (United States)

    2013-07-01T23:59:59.000Z

    In this case study, groundwater/surface water modeling was used to determine efficacy of stabilization in place with hydrologic isolation for remediation of mercury contaminated areas in the Upper East Fork Poplar Creek (UEFPC) Watershed in Oak Ridge, TN. The modeling simulates the potential for mercury in soil to contaminate groundwater above industrial use risk standards and to contribute to surface water contamination. The modeling approach is unique in that it couples watershed hydrology with the total mercury transport and provides a tool for analysis of changes in mercury load related to daily precipitation, evaporation, and runoff from storms. The model also allows for simulation of colloidal transport of total mercury in surface water. Previous models for the watershed only simulated average yearly conditions and dissolved concentrations that are not sufficient for predicting mercury flux under variable flow conditions that control colloidal transport of mercury in the watershed. The transport of mercury from groundwater to surface water from mercury sources identified from information in the Oak Ridge Environmental Information System was simulated using a watershed scale model calibrated to match observed daily creek flow, total suspended solids and mercury fluxes. Mercury sources at the former Building 81-10 area, where mercury was previously retorted, were modeled using a telescopic refined mesh with boundary conditions extracted from the watershed model. Modeling on a watershed scale indicated that only source excavation for soils/sediment in the vicinity of UEFPC had any effect on mercury flux in surface water. The simulations showed that colloidal transport contributed 85 percent of the total mercury flux leaving the UEFPC watershed under high flow conditions. Simulation of dissolved mercury transport from liquid elemental mercury and adsorbed sources in soil at former Building 81-10 indicated that dissolved concentrations are orders of magnitude below a target industrial groundwater concentration beneath the source and would not influence concentrations in surface water at Station 17. This analysis addressed only shallow concentrations in soil and the shallow groundwater flow path in soil and unconsolidated sediments to UEFPC. Other mercury sources may occur in bedrock and transport though bedrock to UEFPC may contribute to the mercury flux at Station 17. Generally mercury in the source areas adjacent to the stream and in sediment that is eroding can contribute to the flux of mercury in surface water. Because colloidally adsorbed mercury can be transported in surface water, actions that trap colloids and or hydrologically isolate surface water runoff from source areas would reduce the flux of mercury in surface water. Mercury in soil is highly adsorbed and transport in the groundwater system is very limited under porous media conditions. (authors)

  17. UPDES General Permit for Discharges from Construction Activities...

    Open Energy Info (EERE)

    Discharges from Construction Activities (Permit No. UTRC00000) Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: UPDES General Permit...

  18. AZPDES General Permit for Stormwater Discharges Associated with...

    Open Energy Info (EERE)

    Stormwater Discharges Associated with Construction Activity (Permit No. AZG2013-001) Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther:...

  19. Neutral Gas Expansion in a Cylindrical Helicon Discharge Chamber

    E-Print Network [OSTI]

    Walker, Mitchell

    ­1500 G) magnetic field parallel to the axis of the tube. In many helicon experiments for basic plasma research, the discharge chamber is composed of a small diameter (2­10 cm), relatively long (0.5­1.75 m

  20. arc discharge lamp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TR, were determined. It was found that there is no local LTE in this arc discharge air plasma during its spacetime evolution, and effects of strong non-izothermality have a...

  1. Equilibrium theory of cylindrical discharges with special application to helicons

    E-Print Network [OSTI]

    Chen, Francis F.

    ) Radiofrequency discharges used in industry often have centrally peaked plasma density profiles n(r) although, and radiative transport. The book by Delcroix5 covers these local properties, including cross sections, and goes

  2. Use of microalgae to remove pollutants from power plant discharges

    DOE Patents [OSTI]

    Wilde, Edward W. (1833 Pisgah Rd., North Augusta, SC 29841); Benemann, John R. (2741 O'Harte, San Pablo, CA 94806); Weissman, Joseph C. (2086 N. Porpoise Pt. La., Vero Beach, FL 32963); Tillett, David M. (911-3 Coquina La., Vero Beach, FL 32963)

    1991-01-01T23:59:59.000Z

    A method and system for removing pollutants dissolved in the aqueous discharge of a plant, such as a power plant, from a body of water having known hydraulogy and physicochemical characteristics, the method comprising (a) modifying the hydraulic system of the body of water including use of physical barriers to define a zone in a portion of the body of water which zone includes the discharge point and where the water has a range of physicochemical characteristics; (b) selecting a large and preferably filamentous, planktonically growing strain of algae adapted to absorb the particular pollutants and genetically dominating algae at the physicochemical characteristics of the zone; (c) establishing a colony of the selected algal strain in the zone; (d) harvesting a portion of the colony; and (e) reinnoculating the zone near the discharge point with a fraction of the harvested portion. The fraction used for reinnoculation can be adjusted to balance the rate of pollutant removal to the rate of pollutant discharge.

  3. Nitrogen Atmospheric Pressure Post Discharges for Surface Biological Decontamination inside

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Nitrogen Atmospheric Pressure Post Discharges for Surface Biological Decontamination inside Small) (PET) capillary tubes of different shapes and lengths and decontamination of flow tubes, both for several years at the Orsay Plasma Lab. Its biological decontamination efficiency has been demonstrated

  4. Discharging a DC bus capacitor of an electrical converter system

    DOE Patents [OSTI]

    Kajouke, Lateef A; Perisic, Milun; Ransom, Ray M

    2014-10-14T23:59:59.000Z

    A system and method of discharging a bus capacitor of a bidirectional matrix converter of a vehicle are presented here. The method begins by electrically shorting the AC interface of the converter after an AC energy source is disconnected from the AC interface. The method continues by arranging a plurality of switching elements of a second energy conversion module into a discharge configuration to establish an electrical current path from a first terminal of an isolation module, through an inductive element, and to a second terminal of the isolation module. The method also modulates a plurality of switching elements of a first energy conversion module, while maintaining the discharge configuration of the second energy conversion module, to at least partially discharge a DC bus capacitor.

  5. Qualification of the Nippon Instrumentation for use in Measuring Mercury at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Edwards, T.; Mahannah, R.

    2011-07-05T23:59:59.000Z

    The Nippon Mercury/RA-3000 system installed in 221-S M-14 has been qualified for use. The qualification was a side-by-side comparison of the Nippon Mercury/RA-3000 system with the currently used Bacharach Mercury Analyzer. The side-by-side testing included standards for instrument calibration verifications, spiked samples and unspiked samples. The standards were traceable back to the National Institute of Standards and Technology (NIST). The side-by-side work included the analysis of Sludge Receipt and Adjustment Tank (SRAT) Receipt, SRAT Product, and Slurry Mix Evaporator (SME) samples. With the qualification of the Nippon Mercury/RA-3000 system in M-14, the DWPF lab will be able to perform a head to head comparison of a second Nippon Mercury/RA-3000 system once the system is installed. The Defense Waste Processing Facility (DWPF) analyzes receipt and product samples from the Sludge Receipt and Adjustment Tank (SRAT) to determine the mercury (Hg) concentration in the sludge slurry. The SRAT receipt is typically sampled and analyzed for the first ten SRAT batches of a new sludge batch to obtain an average Hg concentration. This average Hg concentration is then used to determine the amount of steam stripping required during the concentration/reflux step of the SRAT cycle to achieve a less than 0.6 wt% Hg in the SRAT product solids. After processing is complete, the SRAT product is sampled and analyzed for mercury to ensure that the mercury concentration does not exceed the 0.45 wt% limit in the Slurry Mix Evaporator (SME). The DWPF Laboratory utilizes Bacharach Analyzers to support these Hg analyses at this facility. These analyzers are more than 10 years old, and they are no longer supported by the manufacturer. Due to these difficulties, the Bacharach Analyzers are to be replaced by new Nippon Mercury/RA-3000 systems. DWPF issued a Technical Task Request (TTR) for the Savannah River National Laboratory (SRNL) to assist in the qualification of the new systems. SRNL prepared a task technical and quality assurance (TT&QA) plan that outlined the activities that are necessary and sufficient to meet the objectives of the TTR. In addition, TT&QA plan also included a test plan that provided guidance to the DWPF Lab in collecting the data needed to qualify the new Nippon Mercury/RA-3000 systems.

  6. Discharge source with gas curtain for protecting optics from particles

    DOE Patents [OSTI]

    Fornaciari, Neal R.; Kanouff, Michael P.

    2004-03-30T23:59:59.000Z

    A gas curtain device is employed to deflect debris that is generated by an extreme ultraviolet and soft x-ray radiation discharge source such as an electric discharge plasma source. The gas curtain device projects a stream of gas over the path of the radiation to deflect debris particles into a direction that is different from that of the path of the radiation. The gas curtain can be employed to prevent debris accumulation on the optics used in photolithography.

  7. Mode transition of a Hall thruster discharge plasma

    SciTech Connect (OSTI)

    Hara, Kentaro, E-mail: kenhara@umich.edu; Sekerak, Michael J., E-mail: msekerak@umich.edu; Boyd, Iain D.; Gallimore, Alec D. [University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-05-28T23:59:59.000Z

    A Hall thruster is a cross-field plasma device used for spacecraft propulsion. An important unresolved issue in the development of Hall thrusters concerns the effect of discharge oscillations in the range of 10–30?kHz on their performance. The use of a high speed Langmuir probe system and ultra-fast imaging of the discharge plasma of a Hall thruster suggests that the discharge oscillation mode, often called the breathing mode, is strongly correlated to an axial global ionization mode. Stabilization of the global oscillation mode is achieved as the magnetic field is increased and azimuthally rotating spokes are observed. A hybrid-direct kinetic simulation that takes into account the transport of electronically excited atoms is used to model the discharge plasma of a Hall thruster. The predicted mode transition agrees with experiments in terms of the mean discharge current, the amplitude of discharge current oscillation, and the breathing mode frequency. It is observed that the stabilization of the global oscillation mode is associated with reduced electron transport that suppresses the ionization process inside the channel. As the Joule heating balances the other loss terms including the effects of wall loss and inelastic collisions, the ionization oscillation is damped, and the discharge oscillation stabilizes. A wide range of the stable operation is supported by the formation of a space charge saturated sheath that stabilizes the electron axial drift and balances the Joule heating as the magnetic field increases. Finally, it is indicated from the numerical results that there is a strong correlation between the emitted light intensity and the discharge current.

  8. Spent nuclear fuel discharges from U.S. reactors 1994

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    Spent Nuclear Fuel Discharges from US Reactors 1994 provides current statistical data on fuel assemblies irradiated at commercial nuclear reactors operating in the US. This year`s report provides data on the current inventories and storage capacities at these reactors. Detailed statistics on the data are presented in four chapters that highlight 1994 spent fuel discharges, storage capacities and inventories, canister and nonfuel component data, and assembly characteristics. Five appendices, a glossary, and bibliography are also included. 10 figs., 34 tabs.

  9. Self-pulsing of hollow cathode discharge in various gases

    SciTech Connect (OSTI)

    Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

    2014-07-15T23:59:59.000Z

    In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

  10. State waste discharge permit application, 200-E chemical drain field

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect ground would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE 91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. This document presents the State Waste Discharge Permit (SWDP) application for the 200-E Chemical Drain Field. Waste water from the 272-E Building enters the process sewer line directly through a floor drain, while waste water from the 2703-E Building is collected in two floor drains, (north and south) that act as sumps and are discharged periodically. The 272-E and 2703-E Buildings constitute the only discharges to the process sewer line and the 200-E Chemical Drain Field.

  11. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum; J.E. Locke; S.C. Tseng

    2005-03-01T23:59:59.000Z

    There is concern that mercury (Hg) in coal combustion by-products might be emitted into the environment during processing to other products or after the disposal/landfill of these by-products. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications and may result in additional, costly disposal regulations. In this program, CONSOL conducted a comprehensive sampling and analytical program to include ash, flue gas desulfurization (FGD) sludge, and coal combustion by-products. This work is necessary to help identify potential problems and solutions important to energy production from fossil fuels. The program objective was to evaluate the potential for mercury emissions by leaching or volatilization, to determine if mercury enters the water surrounding an active FGD disposal site and an active fly ash slurry impoundment site, and to provide data that will allow a scientific assessment of the issue. Toxicity Characteristic Leaching Procedure (TCLP) test results showed that mercury did not leach from coal, bottom ash, fly ash, spray dryer/fabric filter ash or forced oxidation gypsum (FOG) in amounts leading to concentrations greater than the detection limit of the TCLP method (1.0 ng/mL). Mercury was detected at very low concentrations in acidic leachates from all of the fixated and more than half of the unfixated FGD sludge samples, and one of the synthetic aggregate samples. Mercury was not detected in leachates from any sample when deionized water (DI water) was the leaching solution. Mercury did not leach from electrostatic precipitator (ESP) fly ash samples collected during activated carbon injection for mercury control in amounts greater than the detection limit of the TCLP method (1.0 ng/mL). Volatilization tests could not detect mercury loss from fly ash, spray dryer/fabric filter ash, unfixated FGD sludge, or forced oxidation gypsum; the mercury concentration of these samples all increased, possibly due to absorption from ambient surroundings. Mercury loss of 18-26% was detected after 3 and 6 months at 100 F and 140 F from samples of the fixated FGD sludge. Water samples were collected from existing ground water monitoring wells around an active FGD disposal site (8 wells) and an active fly ash slurry impoundment (14 wells). These were wells that the plants have installed to comply with ground water monitoring requirements of their permits. Mercury was not detected in any of the water samples collected from monitoring wells at either site. A literature review concluded that coal combustion byproducts can be disposed of in properly designed landfills that minimize the potentially negative impacts of water intrusion that carries dissolved organic matter (DOM). Dissolved organic matter and sulfate-reducing bacteria can promote the transformation of elemental or oxidized mercury into methyl mercury. The landfill should be properly designed and capped with clays or similar materials to minimize the wet-dry cycles that promote the release of methylmercury.

  12. Technology demonstration for reducing mercury emissions from small-scale gold refining facilities.

    SciTech Connect (OSTI)

    Habegger, L. J.; Fernandez, L. E.; Engle, M.; Bailey, J. L.; Peterson, D. P.; MacDonell, M. M.; U.S. Environmental Protection Agency

    2008-06-30T23:59:59.000Z

    Gold that is brought from artisanal and small-scale gold mining areas to gold shops for processing and sale typically contains 5-40% mercury. The uncontrolled removal of the residual mercury in gold shops by using high-temperature evaporation can be a significant source of mercury emissions in urban areas where the shops are located. Emissions from gold shop hoods during a burn can exceed 1,000 mg/m{sup 3}. Because the saturation concentration of mercury vapor at operating temperatures at the hood exhaust is less than 100 mg/m{sup 3}, the dominant component of the exhaust is in the form of aerosol or liquid particles. The U.S. Environmental Protection Agency (EPA), with technical support from Argonne National Laboratory (Argonne), has completed a project to design and test a technology to remove the dominant aerosol component in the emissions from gold shops. The objective was to demonstrate a technology that could be manufactured at low cost and by using locally available materials and manufacturing capabilities. Six prototypes designed by Argonne were locally manufactured, installed, and tested in gold shops in Itaituba and Creporizao, Brazil. The initial prototype design incorporated a pebble bed as the media for collecting the mercury aerosols, and a mercury collection efficiency of over 90% was demonstrated. Though achieving high efficiencies, the initial prototype was determined to have practical disadvantages such as excessive weight, a somewhat complex construction, and high costs (>US$1,000). To further simplify the construction, operation, and associated costs, a second prototype design was developed in which the pebble bed was replaced with slotted steel baffle plates. The system was designed to have flexibility for installation in various hood configurations. The second prototype with the baffle plate design was installed and tested in several different hood/exhaust systems to determine the optimal installation configuration. The significance of coagulation and collection of the mercury aerosols in exhaust ducts, which is dependent on the hood and collector configuration, was also evaluated. Prototype demonstration tests verified the theoretical basis for mercury aerosol capture that can be used to optimize the baffle plate design, flow rates, and hood exhaust ducts and plenum to achieve 80% or higher removal efficiencies. Results indicated that installation configuration significantly influences a system's capture efficiency. Configurations that retained existing inlet ducts resulted in system efficiencies of more than 80%, whereas installation configurations without inlet ducts significantly reduced capture efficiency. As an alternative to increasing the volume of inlet ducts, the number of baffle plates in the system baffle assembly could be doubled to increase efficiency. Recommended installation and operation procedures were developed on the basis of these results. A water-based mercury capture system developed in Indonesia for installation in smaller shops was also tested and shown to be effective for certain applications. The cost of construction and installation of the baffle plate prototype was approximately US$400. These costs were reported as acceptable by local gold shop owners and government regulators, and were significantly lower than the cost of an alternate charcoal/copper mesh mercury filter available in the region, which costs about US$10,000. A sampling procedure that consists of a particle filter combined with a vapor analyzer was demonstrated as an effective procedure for analyzing both the aerosol and vapor components of the mercury concentrations. Two key findings for enhancing higher mercury collection were identified. First, the aerosol/vapor mercury emissions must be given sufficient time for the mercury particles to coagulate to a size that can be readily captured by the baffle plates. An interval of at least 6 seconds of transit time between the point of evaporation and contact with the slotted baffle plates is recommended. Some particles will also deposit in the exhaust ducts

  13. FULL-SCALE TESTING OF ENHANCED MERCURY CONTROL TECHNOLOGIES FOR WET FGD SYSTEMS

    SciTech Connect (OSTI)

    D.K. McDonald; G.T. Amrhein; G.A. Kudlac; D. Madden Yurchison

    2003-05-07T23:59:59.000Z

    Wet flue gas desulfurization (wet FGD) systems are currently installed on about 25% of the coal-fired utility generating capacity in the U.S., representing about 15% of the number of coal-fired units. Depending on the effect of operating parameters such as mercury content of the coal, form of mercury (elemental or oxidized) in the flue gas, scrubber spray tower configuration, liquid-to-gas ratio, and slurry chemistry, FGD systems can provide cost-effective, near-term mercury emissions control options with a proven history of commercial operation. For boilers already equipped with FGD systems, the incremental cost of any vapor phase mercury removal achieved is minimal. To be widely accepted and implemented, technical approaches that improve mercury removal performance for wet FGD systems should also have low incremental costs and have little or no impact on operation and SO{sub 2} removal performance. The ultimate goal of the Full-scale Testing of Enhanced Mercury Control for Wet FGD Systems Program was to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The program was funded by the U.S. Department of Energy's National Energy Technology Laboratory, the Ohio Coal Development Office within the Ohio Department of Development, and Babcock & Wilcox. Host sites and associated support were provided by Michigan South Central Power Agency (MSCPA) and Cinergy. Field-testing was completed at two commercial coal-fired utilities with wet FGD systems: (1) MSCPA's 55 MW{sub e} Endicott Station and (2) Cinergy's 1300 MW{sub e} Zimmer Station. Testing was conducted at these two locations because of the large differences in size and wet scrubber chemistry. Endicott employs a limestone, forced oxidation (LSFO) wet FGD system, whereas Zimmer uses Thiosorbic{reg_sign} Lime (magnesium enhanced lime) and ex situ oxidation. Both locations burn Ohio bituminous coal.

  14. Exploring the structural basis for selenium/mercury antagonism in Allium fistulosum

    SciTech Connect (OSTI)

    McNear, Jr., David H.; Afton, Scott E.; Caruso, Joseph A. (UCIN); (Kentucky)

    2012-12-10T23:59:59.000Z

    While continuing efforts are devoted to studying the mutually protective effect of mercury and selenium in mammals, few studies have investigated the mercury-selenium antagonism in plants. In this study, we report the metabolic fate of mercury and selenium in Allium fistulosum (green onion) after supplementation with sodium selenite and mercuric chloride. Analysis of homogenized root extracts via capillary reversed phase chromatography coupled with inductively coupled plasma mass spectrometry (capRPLC-ICP-MS) suggests the formation of a mercury-selenium containing compound. Micro-focused synchrotron X-ray fluorescence mapping of freshly excised roots show Hg sequestered on the root surface and outlining individual root cells, while Se is more evenly distributed throughout the root. There are also discrete Hg-only, Se-only regions and an overall strong correlation between Hg and Se throughout the root. Analysis of the X-ray absorption near edge structure (XANES) spectra show a 'background' of methylselenocysteine within the root with discrete spots of SeO{sub 3}{sup 2-}, Se{sup 0} and solid HgSe on the root surface. Mercury outlining individual root cells is possibly binding to sulfhydryl groups or plasma membrane or cell wall proteins, and in some places reacting with reduced selenium in the rhizosphere to form a mercury(II) selenide species. Together with the formation of the root-bound mercury(II) selenide species, we also report on the formation of cinnabar (HgS) and Hg{sup 0} in the rhizosphere. The results presented herein shed light on the intricate chemical and biological processes occurring within the rhizosphere that influence Hg and Se bioavailability and will be instrumental in predicting the fate and assisting in the remediation of these metals in the environment and informing whether or not fruit and vegetable food selection from aerial plant compartments or roots from plants grown in Hg contaminated soils, are safe for consumption.

  15. The current state of the science related to the re-release of mercury from coal combustion products

    SciTech Connect (OSTI)

    Debra F. Pflughoeft-Hassett; David J. Hassett; Loreal V. Heebink; Tera D. Buckley [University of North Dakota Energy and Environmental Research Center (EERC) (United States)

    2006-07-01T23:59:59.000Z

    The stability of mercury associated with CCPs is an issue that has only recently been under investigation but has become a prominent question as the industry strives to determine if current management options for CCPs will need to be modified. Mercury and other air toxic elements can be present in fly ash, FGD material and bottom ash and boiler slag. Mercury concentrations ranging from {lt} 0.01 to 2.41 ppm in fly ash and from 0.001 to 0.342 ppm in bottom ash have been reported. Stability of mercury must be evaluated by tests that include 1) direct leachability; 2) vapor-phase release at ambient and elevated temperatures; and 3) microbiologically induced leachability and vapor-phase release. The amount of mercury leached from currently produced CCPs is extremely low and does not appear to represent an environmental or re-release hazard. Concentrations of mercury in leachates from fly ashes and FGD material using either the toxicity characteristic leaching procedure (TCLP) or the synthetic groundwater leaching procedure (SGLP) are generally below detection limits. The release of mercury vapor from CCPs resulting from the use of mercury control technologies has been evaluated on a limited basis. Research indicates that mercury bound to the ash or activated carbon is fairly stable. The EERC found that organomercury species were detected at very low levels both in the vapor and leachate generated from the microbiologically mediated release experiments. The current state of the science indicates that mercury associated with CCPs is stable and highly unlikely to be released under most management conditions, including utilisation and disposal. The exception to this is exposure to high temperatures such as those that may be achieved in cement and wallboard production. Therefore, existing CCPs management options are expected to be environmentally sound options for CCPs from systems with mercury control technologies installed. 2 refs., 2 photos.

  16. Cadmium, lead and mercury exposure in non smoking pregnant women

    SciTech Connect (OSTI)

    Hinwood, A.L., E-mail: a.hinwood@ecu.edu.au [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Callan, A.C.; Ramalingam, M.; Boyce, M. [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia)] [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Heyworth, J. [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia)] [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia); McCafferty, P. [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia)] [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia); Odland, J.Ř. [Department of Community Medicine, University of Tromsř, N-9037 Tromsř (Norway)] [Department of Community Medicine, University of Tromsř, N-9037 Tromsř (Norway)

    2013-10-15T23:59:59.000Z

    Recent literature suggests that exposure to low concentrations of heavy metals may affect both maternal and child health. This study aimed to determine the biological heavy metals concentrations of pregnant women as well as environmental and dietary factors that may influence exposure concentrations. One hundred and seventy three pregnant women were recruited from Western Australia, each providing a sample of blood, first morning void urine, residential soil, dust and drinking water samples. Participants also completed a questionnaire which included a food frequency component. All biological and environmental samples were analysed for heavy metals using ICP-MS. Biological and environmental concentrations of lead and mercury were generally low (Median Pb Drinking Water (DW) 0.04 µg/L; Pb soil <3.0 µg/g; Pb dust 16.5 µg/g; Pb blood 3.67 µg/L; Pb urine 0.55; µg/L Hg DW <0.03; Hg soil <1.0 µg/g; Hg dust <1.0 µg/g; Hg blood 0.46 µg/L; Hg urine <0.40 µg/L). Cadmium concentrations were low in environmental samples (Median CdDW 0.02 µg/L; Cdsoil <0.30 ug/g; Cddust <0.30) but elevated in urine samples (Median 0.55 µg/L, creatinine corrected 0.70 µg/g (range <0.2–7.06 µg/g creatinine) compared with other studies of pregnant women. Predictors of increased biological metals concentrations in regression models for blood cadmium were residing in the Great Southern region of Western Australia and not using iron/folic acid supplements and for urinary cadmium was having lower household annual income. However, these factors explained little of the variation in respective biological metals concentrations. The importance of establishing factors that influence low human exposure concentrations is becoming critical in efforts to reduce exposures and hence the potential for adverse health effects. -- Highlights: • Biological heavy metals concentrations in women in their 3rd trimester of pregnancy. • Exposure assessment including environmental, lifestyle and activity data. • Urinary cadmium concentrations were elevated in this group of pregnant women. • Blood lead and mercury concentrations were below recommended biological guideline values.

  17. Helium Ash Simulation Studies with Divertor Helium Pumping in JET Internal Transport Barrier Discharges

    E-Print Network [OSTI]

    Helium Ash Simulation Studies with Divertor Helium Pumping in JET Internal Transport Barrier Discharges

  18. CFD Validation of Gas Injection in Flowing Mercury over Vertical Smooth and Grooved Wall

    SciTech Connect (OSTI)

    Abdou, Ashraf A [ORNL; Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL

    2009-01-01T23:59:59.000Z

    The Spallation Neutron Source (SNS) is an accelerator-based neutron source at Oak Ridge National Laboratory (ORNL).The nuclear spallation reaction occurs when a proton beam hits liquid mercury. This interaction causes thermal expansion of the liquid mercury which produces high pressure waves. When these pressure waves hit the target vessel wall, cavitation can occur and erode the wall. Research and development efforts at SNS include creation of a vertical protective gas layer between the flowing liquid mercury and target vessel wall to mitigate the cavitation damage erosion and extend the life time of the target. Since mercury is opaque, computational fluid dynamics (CFD) can be used as a diagnostic tool to see inside the liquid mercury and guide the experimental efforts. In this study, CFD simulations of three dimensional, unsteady, turbulent, two-phase flow of helium gas injection in flowing liquid mercury over smooth, vertically grooved and horizontally grooved walls are carried out with the commercially available CFD code Fluent-12 from ANSYS. The Volume of Fluid (VOF) model is used to track the helium-mercury interface. V-shaped vertical and horizontal grooves with 0.5 mm pitch and about 0.7 mm depth were machined in the transparent wall of acrylic test sections. Flow visualization data of helium gas coverage through transparent test sections is obtained with a high-speed camera at the ORNL target test facility (TTF). The helium gas mass flow rate is 8 mg/min and introduced through a 0.5 mm diameter port. The local mercury velocity is 0.9 m/s. In this paper, the helium gas flow rate and the local mercury velocity are kept constant for the three cases. Time integration of predicted helium gas volume fraction over time is done to evaluate the gas coverage and calculate the average thickness of the helium gas layer. The predicted time-integrated gas coverage over vertically grooved and horizontally grooved test sections is better than over a smooth wall. The simulations show that the helium gas is trapped inside the grooves. The predicted time-averaged gas coverage is in good qualitative agreement with the measured gas coverage.

  19. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31T23:59:59.000Z

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  20. Mercury Removal at Idaho National Engineering and Environmental Laboratory's New Waste Calcining Facility

    SciTech Connect (OSTI)

    Ashworth, Samuel Clay; Wood, R. A.; Taylor, D. D.; Sieme, D. D.

    2000-03-01T23:59:59.000Z

    Technologies were investigated to determine viable processes for removing mercury from the calciner (NWCF) offgas system at the Idaho National Engineering and Environmental Laboratory. Technologies for gas phase and aqueous phase treatment were evaluated. The technologies determined are intended to meet EPA Maximum Achievable Control Technology (MACT) requirements under the Clean Air Act and Resource Conservation and Recovery Act (RCRA). Currently, mercury accumulation in the calciner off-gas scrubbing system is transferred to the tank farm. These transfers lead to accumulation in the liquid heels of the tanks. The principal objective for aqueous phase mercury removal is heel mercury reduction. The system presents a challenge to traditional methods because of the presence of nitrogen oxides in the gas phase and high nitric acid in the aqueous scrubbing solution. Many old and new technologies were evaluated including sorbents and absorption in the gas phase and ion exchange, membranes/sorption, galvanic methods, and UV reduction in the aqueous phase. Process modifications and feed pre-treatment were also evaluated. Various properties of mercury and its compounds were summarized and speciation was predicted based on thermodynamics. Three systems (process modification, NOxidizer combustor, and electrochemical aqueous phase treatment) and additional technology testing were recommended.

  1. Sorbents for mercury capture from fuel gas with application to gasification systems

    SciTech Connect (OSTI)

    Granite, E.J.; Myers, C.R.; King, W.P.; Stanko, D.C.; Pennline, H.W. [US DOE, Pittsburgh, PA (United States)

    2006-06-21T23:59:59.000Z

    In regard to gasification for power generation, the removal of mercury by sorbents at elevated temperatures preserves the higher thermal efficiency of the integrated gasification combined cycle system. Unfortunately, most sorbents display poor capacity for elemental mercury at elevated temperatures. Previous experience with sorbents in flue gas has allowed for judicious selection of potential high-temperature candidate sorbents. The capacities of many sorbents for elemental mercury from nitrogen, as well as from four different simulated fuel gases at temperatures of 204-371{sup o}C, have been determined. The simulated fuel gas compositions contain varying concentrations of carbon monoxide, hydrogen, carbon dioxide, moisture, and hydrogen sulfide. Promising high-temperature sorbent candidates have been identified. Palladium sorbents seem to be the most promising for high-temperature capture of mercury and other trace elements from fuel gases. A collaborative research and development agreement has been initiated between the Department of Energy's National Energy Technology Laboratory (NETL) and Johnson Matthey for optimization of the sorbents for trace element capture from high-temperature fuel gas. Future directions for mercury sorbent development for fuel gas application will be discussed.

  2. MERCURY REMOVAL FROM DOE SOLID MIXED WASTE USING THE GEMEP(sm) TECHNOLOGY

    SciTech Connect (OSTI)

    None

    1999-03-01T23:59:59.000Z

    Under the sponsorship of the Federal Energy Technology Center (FETC), Metcalf and Eddy (M and E), in association with General Electric Corporate Research and Development Center (GE-CRD), Colorado Minerals Research Institute (CMRI), and Oak Ridge National Laboratory (ORNL), conducted laboratory-scale and bench-scale tests of the General Electric Mercury Extraction Process technology on two mercury-contaminated mixed solid wastes from U. S. Department of Energy sites: sediment from the East Fork of Poplar Creek, Oak Ridge (samples supplied by Oak Ridge National Laboratory), and drummed soils from Idaho National Environmental and Engineering Laboratory (INEEL). Fluorescent lamps provided by GE-CRD were also studied. The GEMEP technology, invented and patented by the General Electric Company, uses an extraction solution composed of aqueous potassium iodide plus iodine to remove mercury from soils and other wastes. The extraction solution is regenerated by chemical oxidation and reused, after the solubilized mercury is removed from solution by reducing it to the metallic state. The results of the laboratory- and bench-scale testing conducted for this project included: (1) GEMEP extraction tests to optimize extraction conditions and determine the extent of co-extraction of radionuclides; (2) pre-screening (pre-segregation) tests to determine if initial separation steps could be used effectively to reduce the volume of material needing GEMEP extraction; and (3) demonstration of the complete extraction, mercury recovery, and iodine recovery and regeneration process (known as locked-cycle testing).

  3. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30T23:59:59.000Z

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  4. Assessment of mercury emissions from the Afton copper smelter, British Columbia, Canada

    SciTech Connect (OSTI)

    Robertson, J.D.; Price, C.J.

    1986-07-01T23:59:59.000Z

    The afton Copper Smelter adjacent to Kamloops, British Columbia, Canada commenced operation in 1978 and employed a mercury scrubbing system. Two years of preproduction studies, which included monitoring for mercury in ambient air, water, soil, and vegetation were performed. The results from similar studies conducted during four full years (1978-81) and two partial years (1982-83) of production are presented in the data analysis. These programs illustrated that the most frequent ground impingement occurred within a 1.6-3.2-km radius of the source, and that the levels decreased with increasing distance from the source to a maximum radius of 8 km. The results of a comprehensive source monitoring program illustrated that the average mercury emission levels ranged from 3.2 to 6.8 kg/calendar day during 1979-81, and that the majority of the emissions were in a vapor form. The ambient monitoring data acquired when smelter operations were significantly reduced indicate a quick recovery to preproduction levels in virtually all monitored parameters and at most monitored sites. The integrated results from all mercury monitoring programs illustrate the environmental impact from mercury emissions which were two to four times the permit standard of 1.8 kg/day.

  5. Food chain dynamics and potential ecological risks of mercury at the Carson River site

    SciTech Connect (OSTI)

    Peterson, S.C. [Ecology and Environment, Inc., Lancaster, NY (United States)

    1995-12-31T23:59:59.000Z

    The USEPA is conducting a remedial investigation of mercury contamination in the Carson River watershed, located near Carson City in central west Nevada. As a component of this investigation, water, sediment, and tissue samples were collected for mercury speciation and other analyses. Tissues analyses from the seven site-investigation areas and four background areas include: whole-body and fillet analyses of five species of fish, composite and individual analyses of three species of benthic macroinvertebrates, blood, feather and liver analyses of two bird species, composite analyses of zooplankton, and whole-body analyses of lizards. The data are used to develop site-specific estimates of mercury bioaccumulation in aquatic food chains of riverine/riparian, open-water, and mudflat habitats at the Carson River site. Because the behavior and food chain dynamics of mercury in semi-arid ecosystems of the southwestern US is poorly understood, these data can be compared and contrasted with bioaccumulation estimates derived from well-studied ecosystems such as northern temperate lakes. Potential ecological risks of mercury exposure through the food chain and through ingestion of and contact with contaminated media are evaluated for important wildlife receptors occurring at the Carson River site.

  6. Rules and Regulations Pertaining to a User Fee System for Point Source Dischargers that Discharge Pollutants into the Waters of the State (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations establish a user fee system for point source dischargers that discharge pollutants into the surface waters of the State. The funds from such fees are used by the Department of...

  7. Very high efficacy electrodeless high intensity discharge lamps

    DOE Patents [OSTI]

    Johnson, Peter D. (Schenectady, NY)

    1987-01-01T23:59:59.000Z

    An electrodeless arc lamp comprises an outer jacket hermetically sealing and thermally protecting an arc tube inside which has an upwardly convex bottom center section. The absence of chemically reactive electrode material makes it possible to use metal halides other than iodides. The tube contains chlorides, bromides or a mixture thereof of scandium and sodium in a nearly equimolar relationship in addition to mercury and an inert gas. Good color balance can be obtained at reduced reservoir temperature and with less power loss. Reduction in wall temperature makes it possible to attain longer lamp life.

  8. Very high efficacy electrodeless high intensity discharge lamps

    DOE Patents [OSTI]

    Johnson, P.D.

    1985-10-03T23:59:59.000Z

    An electrodeless arc lamp comprises an outer jacket hermetically sealing and thermally protecting an arc tube inside which has an upwardly convex bottom center section. The absence of chemically reactive electrode material makes it possible to use metal halides other than iodides. The tube contains chlorides, bromides or a mixture thereof of scandium and sodium in a nearly equimolar relationship in addition to mercury and an inert gas. Good color balance can be obtained at reduced reservoir temperature and with less power loss. Reduction in wall temperature makes it possible to attain longer lamp life.

  9. Preliminary Field Evaluation of Mercury Control Using Combustion Modifications

    SciTech Connect (OSTI)

    V. Lissianski; P. Maly; T. Marquez

    2005-01-22T23:59:59.000Z

    In this project EER conducted a preliminary field evaluation of the integrated approach for mercury (Hg) and NO{sub x} control. The approach enhanced the 'naturally occurring' Hg capture by fly ash through combustion optimization, increasing carbon in ash content, and lowering ESP temperature. The evaluation took place in Green Station Units 1 and 2 located near Henderson, Kentucky and operated by Western Kentucky Energy. Units 1 and 2 are equipped with cold-side ESPs and wet scrubbers. Green Station Units 1 and 2 typically fire two types of fuel: a bituminous coal and a blend of bituminous coals based on availability. Testing of Hg emissions in Unit 2 without reburning system in operation and at minimum OFA demonstrated that efficiencies of Hg reduction downstream of the ESP were 30-40%. Testing also demonstrated that OFA system operation at 22% air resulted in 10% incremental increase in Hg removal efficiency at the ESP outlet. About 80% of Hg in flue gas at ESP outlet was present in the oxidized form. Testing of Hg emissions under reburning conditions showed that Hg emissions decreased with LOI increase and ESP temperature decrease. Testing demonstrated that maximum Hg reduction downstream of ESP was 40-45% at ESP temperatures higher than 300 F and 60-80% at ESP temperatures lower than 300 F. The program objective to demonstrate 80% Hg removal at the ESP outlet has been met.

  10. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01T23:59:59.000Z

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  11. Constraining spacetime torsion with the Moon and Mercury

    SciTech Connect (OSTI)

    March, Riccardo; Bellettini, Giovanni; Tauraso, Roberto; Dell'Agnello, Simone [Istituto per le Applicazioni del Calcolo, CNR, Via dei Taurini 19, 00185 Roma, Italy, and INFN - Laboratori Nazionali di Frascati (LNF), via E. Fermi 40 Frascati, 00044 Roma (Italy); Dipartimento di Matematica, Universita di Roma ''Tor Vergata'', via della Ricerca Scientifica 1, 00133 Roma, Italy, and INFN - Laboratori Nazionali di Frascati (LNF), via E. Fermi 40 Frascati, 00044 Roma (Italy); Dipartimento di Matematica, Universita di Roma 'Tor Vergata', via della Ricerca Scientifica 1, 00133 Roma, Italy, and INFN - Laboratori Nazionali di Frascati (LNF), via E. Fermi 40 Frascati, 00044 Roma (Italy); INFN - Laboratori Nazionali di Frascati (LNF), via E. Fermi 40 Frascati, 00044 Roma (Italy)

    2011-05-15T23:59:59.000Z

    We report a search for new gravitational physics phenomena based on Riemann-Cartan theory of general relativity including spacetime torsion. Starting from the parametrized torsion framework of Mao, Tegmark, Guth, and Cabi, we analyze the motion of test bodies in the presence of torsion, and, in particular, we compute the corrections to the perihelion advance and to the orbital geodetic precession of a satellite. We consider the motion of a test body in a spherically symmetric field, and the motion of a satellite in the gravitational field of the Sun and the Earth. We describe the torsion field by means of three parameters, and we make use of the autoparallel trajectories, which in general differ from geodesics when torsion is present. We derive the specific approximate expression of the corresponding system of ordinary differential equations, which are then solved with methods of celestial mechanics. We calculate the secular variations of the longitudes of the node and of the pericenter of the satellite. The computed secular variations show how the corrections to the perihelion advance and to the orbital de Sitter effect depend on the torsion parameters. All computations are performed under the assumptions of weak field and slow motion. To test our predictions, we use the measurements of the Moon's geodetic precession from lunar laser ranging data, and the measurements of Mercury's perihelion advance from planetary radar ranging data. These measurements are then used to constrain suitable linear combinations of the torsion parameters.

  12. Temporal modulation of plasma species in atmospheric dielectric barrier discharges

    SciTech Connect (OSTI)

    Yang, Aijun; Wang, Xiaohua, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn; Liu, Dingxin; Rong, Mingzhe, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049 (China); Kong, Michael G. [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049 (China); Frank Reidy Research Center for Bioelectrics, Department of Electrical and Computer Engineering, Old Dominion University, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2014-07-15T23:59:59.000Z

    The atmospheric pressure dielectric barrier discharge in helium is a pulsed discharge in nature and the moment of maximum species densities is almost consistent with peak discharge current density. In this paper, a one-dimensional fluid model is used to investigate the temporal structure of plasma species in an atmospheric He-N{sub 2} dielectric barrier discharge (DBD). It is demonstrated that there exist microsecond delays of the moments of the maximum electron and ion densities from the peak of discharge current density. These time delays are caused by a competition between the electron impact and Penning ionizations, modulated by the N{sub 2} level in the plasma-forming gas. Besides, significant electron wall losses lead to the DBD being more positively charged and, with a distinct temporal separation in the peak electron and cation densities, the plasma is characterized with repetitive bursts of net positive charges. The temporal details of ionic and reactive plasma species may provide a new idea for some biological processes.

  13. J. Phys. III IYance 7 (1997) 927-936 APRIL 1997, PAGE 927 A Stable Discharge Glow in Gas Discharge System with

    E-Print Network [OSTI]

    Boyer, Edmond

    1997-01-01T23:59:59.000Z

    have been stud- ied in a wide range of the gas pressure p (21.3-466.5 hPa) and of interJ. Phys. III IYance 7 (1997) 927-936 APRIL 1997, PAGE 927 A Stable Discharge Glow in Gas Discharge.40.Sx Metal-semiconductor-metal structures Abstract. A dc discharge generated between parallel plate

  14. Demonstration of An Integrated Approach to Mercury Control at Lee Station

    SciTech Connect (OSTI)

    Vitali Lissianski; Pete Maly

    2007-12-31T23:59:59.000Z

    General Electric (GE) has developed an approach whereby native mercury reduction on fly ash can be improved by optimizing the combustion system. This approach eliminates carbon-rich areas in the combustion zone, making the combustion process more uniform, and allows increasing carbon content in fly ash without significant increase in CO emissions. Since boiler excess O{sub 2} can be also reduced as a result of optimized combustion, this process reduces NO{sub x} emissions. Because combustion optimization improves native mercury reduction on fly ash, it can reduce requirements for activated carbon injection (ACI) when integrated with sorbent injection for more efficient mercury control. The approach can be tailored to specific unit configurations and coal types for optimal performance. This report describes results of a U.S. DOE sponsored project designed to evaluate the effect of combustion conditions on 'native' mercury capture on fly ash and integrate combustion optimization for improved mercury and NO{sub x} reduction with ACI. The technology evaluation took place in Lee Station Unit 3 located in Goldsboro, NC and operated by Progress Energy. Unit 3 burns a low-sulfur Eastern bituminous coal and is a 250 MW opposed-wall fired unit equipped with an ESP with a specific collection area of 249 ft{sup 2}/kacfm. Unit 3 is equipped with SO{sub 3} injection for ESP conditioning. The technical goal of the project was to evaluate the technology's ability to achieve 70% mercury reduction below the baseline emission value of 2.9 lb/TBtu, which was equivalent to 80% mercury reduction relative to the mercury concentration in the coal. The strategy to achieve the 70% incremental improvement in mercury removal in Unit 3 was (1) to enhance 'naturally' occurring fly ash mercury capture by optimizing the combustion process and using duct humidification to reduce flue gas temperatures at the ESP inlet, and (2) to use ACI in front of the ESP to further reduce mercury emissions. The program was comprised of field and pilot-scale tests, engineering studies and consisted of eight tasks. As part of the program, GE conducted pilot-scale evaluation of sorbent effect on mercury reduction, supplied and installed adjustable riffle boxes to assist in combustion optimization, performed combustion optimization, supplied mobile sorbent injection and flue gas humidification systems, conducted CFD modeling of sorbent injection and flue gas humidification, and performed mercury testing including a continuous 30-day sorbent injection trial. Combustion optimization was the first step in reduction of mercury emissions. Goals of combustion optimization activities were to improve 'native' mercury capture on fly ash and reduce NO{sub x}. Combustion optimization included balancing of coal flow through individual burners to eliminate zones of carbon-rich combustion, air flow balancing, and burner adjustments. As part of the project, the original riffle boxes were replaced with Foster-Wheeler's adjustable riffle boxes to allow for biasing the coal flow between the coal pipes. A 10-point CO/O{sub 2}/NO{sub x} grid was installed in the primary superheater region of the back pass to assist in these activities. Testing of mercury emissions before and after combustion optimization demonstrated that mercury emissions were reduced from 2.9 lb/TBtu to 1.8 lb/TBtu due to boiler operation differences in conjunction with combustion optimization, a 38% improvement in 'native' mercury capture on fly ash. Native mercury reduction from coal was {approx}42% at baseline conditions and 64% at optimized combustion conditions. As a result of combustion optimization NO{sub x} emissions were reduced by 18%. A three-dimensional CFD model was developed to study the flow distribution and sorbent injection in the post air heater duct in Lee Station Unit 3. Modeling of the flow pattern exiting the air pre-heater demonstrated that because of the duct transition from a circular opening at the exit of air-pre-heater to a rectangular ESP inlet duct, flow separation occurred at the corners afte

  15. Full-Scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System

    SciTech Connect (OSTI)

    Gary Blythe; Jennifer Paradis

    2010-06-30T23:59:59.000Z

    This document presents and discusses results from Cooperative Agreement DE-FC26-06NT42778, 'Full-scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System,' which was conducted over the time-period July 24, 2006 through June 30, 2010. The objective of the project was to demonstrate at full scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in pulverized-coal-fired flue gas. Oxidized mercury is removed downstream in wet flue gas desulfurization (FGD) absorbers and collected with the byproducts from the FGD system. The project was co-funded by EPRI, the Lower Colorado River Authority (LCRA), who also provided the host site, Great River Energy, Johnson Matthey, Southern Company, Salt River Project (SRP), the Tennessee Valley Authority (TVA), NRG Energy, Ontario Power and Westar. URS Group was the prime contractor and also provided cofunding. The scope of this project included installing and testing a gold-based catalyst upstream of one full-scale wet FGD absorber module (about 200-MW scale) at LCRA's Fayette Power Project (FPP) Unit 3, which fires Powder River Basin coal. Installation of the catalyst involved modifying the ductwork upstream of one of three wet FGD absorbers on Unit 3, Absorber C. The FGD system uses limestone reagent, operates with forced sulfite oxidation, and normally runs with two FGD modules in service and one spare. The full-scale catalyst test was planned for 24 months to provide catalyst life data. Over the test period, data were collected on catalyst pressure drop, elemental mercury oxidation across the catalyst module, and mercury capture by the downstream wet FGD absorber. The demonstration period began on May 6, 2008 with plans for the catalyst to remain in service until May 5, 2010. However, because of continual increases in pressure drop across the catalyst and concerns that further increases would adversely affect Unit 3 operations, LCRA decided to end the demonstration early, during a planned unit outage. On October 2, 2009, Unit 3 was taken out of service for a fall outage and the catalyst upstream of Absorber C was removed. This ended the demonstration after approximately 17 months of the planned 24 months of operation. This report discusses reasons for the pressure drop increase and potential measures to mitigate such problems in any future application of this technology. Mercury oxidation and capture measurements were made on Unit 3 four times during the 17-month demonstration. Measurements were performed across the catalyst and Absorber C and 'baseline' measurements were performed across Absorber A or B, which did not have a catalyst upstream. Results are presented in the report from all four sets of measurements during the demonstration period. These results include elemental mercury oxidation across the catalyst, mercury capture across Absorber C downstream of the catalyst, baseline mercury capture across Absorber A or B, and mercury re-emissions across both absorbers in service. Also presented in the report are estimates of the average mercury control performance of the oxidation catalyst technology over the 17-month demonstration period and the resulting mercury control costs.

  16. Pulsed discharge ionization source for miniature ion mobility spectrometers

    DOE Patents [OSTI]

    Xu, Jun; Ramsey, J. Michael; Whitten, William B.

    2004-11-23T23:59:59.000Z

    A method and apparatus is disclosed for flowing a sample gas and a reactant gas (38, 43) past a corona discharge electrode (26) situated at a first location in an ion drift chamber (24), applying a pulsed voltage waveform comprising a varying pulse component and a dc bias component to the corona discharge electrode (26) to cause a corona which in turn produces ions from the sample gas and the reactant gas, applying a dc bias to the ion drift chamber (24) to cause the ions to drift to a second location (25) in the ion drift chamber (24), detecting the ions at the second location (25) in the drift chamber (24), and timing the period for the ions to drift from the corona discharge electrode to the selected location in the drift chamber.

  17. State Waste Discharge Permit application, 100-N Sewage Lagoon

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173--216 (or 173--218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE 91NM-177, (Ecology and DOE-RL 1991). This document constitutes the State Waste Discharge Permit application for the 100-N Sewage Lagoon. Since the influent to the sewer lagoon is domestic waste water, the State Waste Discharge Permit application for Public Owned Treatment Works Discharges to Land was used. Although the 100-N Sewage Lagoon is not a Public Owned Treatment Works, the Public Owned Treatment Works application is more applicable than the application for industrial waste water. The 100-N Sewage Lagoon serves the 100-N Area and other Hanford Site areas by receiving domestic waste from two sources. A network of sanitary sewer piping and lift stations transfers domestic waste water from the 100-N Area buildings directly to the 100-N Sewage Lagoon. Waste is also received by trucks that transport domestic waste pumped from on site septic tanks and holding tanks. Three ponds comprise the 100-N Sewage Lagoon treatment system. These include a lined aeration pond and stabilization pond, as well as an unlined infiltration pond. Both piped-in and trucked-in domestic waste is discharged directly into the aeration pond.

  18. Accumulation of mercury and PCBs in quillback rockfish (Sebastes maliger) from Puget Sound, Washington, USA

    SciTech Connect (OSTI)

    West, J.E.; O`Neill, S.M. [Washington State Dept. of Fish and Wildlife, Olympia, WA (United States)

    1995-12-31T23:59:59.000Z

    The Washington Department of Fish and Wildlife is conducting a long-term study designed to identify and monitor levels of contaminants in Puget Sound fish resources as one component of the ongoing Puget Sound Ambient Monitoring Program (PSAMP). Here the authors summarize results from three years of monitoring contaminants in quillback rockfish (Sebastes maliger) and present models for bioaccumulation of persistent pollutants. This species was selected for monitoring because they are long-lived and nonmigratory, occupy a relatively high position in the demersal food web, and are important to Washington fisheries. Muscle tissue from quillback rockfish was sampled from 1991 through 1993 at three PSAMP stations in the Puget Sound (San Juan Islands [SJI], North-Central Puget Sound [NCPS] and Central Puget Sound [CPS]). Two persistent pollutants--mercury and polychlorinated biphenyls (PCBS)--were present consistently in quillback rockfish. Maximum concentrations of mercury in composite-samples were 0.51, 0.41 and 0.47 mg/kg for SJI, NCPS and CPS, respectively. One composite exceeded the World Health Organization action limit for mercury in fish tissue (0.5 mg/kg). The US Environmental Protection Agency (EPA) screening level for mercury in fish is 0.6 mg/kg. Seven composite-samples contained a single group of PCBs (aroclor 1260) which exceeded the EPA screening level for total aroclors (10 {micro}g/kg). Stepwise linear regression was used to model the effects of fish age, size, percent lipids, and collection site on accumulation of mercury and aroclor 1260 in quillback rockfish. Of these variables, age and length (as growth rate) of rockfish were the primary determinants of mercury concentration in quillback rockfish; age of rockfish and collection site were the primary determinants of PCB concentrations.

  19. Full Scale Field Trial of the Low Temperature Mercury Capture Process

    SciTech Connect (OSTI)

    James Locke; Richard Winschel

    2011-09-30T23:59:59.000Z

    CONSOL Energy Inc., with partial funding from the Department of Energy (DOE) National Energy Technology Laboratory, designed a full-scale installation for a field trial of the Low-Temperature Mercury Control (LTMC) process, which has the ability to reduce mercury emissions from coal-fired power plants by over 90 percent, by cooling flue gas temperatures to approximately 230 °F and absorbing the mercury on the native carbon in the fly ash, as was recently demonstrated by CONSOL R&D on a slip-stream pilot plant at the Allegheny Energy Mitchell Station with partial support by DOE. LTMC has the potential to remove over 90 percent of the flue gas mercury at a cost at least an order of magnitude lower (on a $/lb mercury removed basis) than activated carbon injection. The technology is suitable for retrofitting to existing and new plants, and, although it is best suited to bituminous coal-fired plants, it may have some applicability to the full range of coal types. Installation plans were altered and moved from the original project host site, PPL Martins Creek plant, to a second host site at Allegheny Energyâ??s R. Paul Smith plant, before installation actually occurred at the Jamestown (New York) Board of Public Utilities (BPU) Samuel A. Carlson (Carlson) Municipal Generating Station Unit 12, where the LTMC system was operated on a limited basis. At Carlson, over 60% mercury removal was demonstrated by cooling the flue gas to 220-230 °F at the ESP inlet via humidification. The host unit ESP operation was unaffected by the humidification and performed satisfactorily at low temperature conditions.

  20. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-10-04T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems, during the time period July 1, 2002 through September 30, 2002. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project co-funders. URS Group is the prime contractor. The mercury catalytic oxidation process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates in a stable form with the byproducts from the FGD system. The coprecipitated mercury does not appear to adversely affect the disposal or reuse properties of the FGD byproduct. The current project will test previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, so as to provide engineering data for future full-scale designs. The pilot-scale tests will continue for up to 14 months at each of two sites to provide longer-term catalyst life data. This is the fourth full reporting period for the subject Cooperative Agreement. During this period, most of the project efforts were related to completing, installing and starting up the pilot unit, completing laboratory runs to size catalysts, and procuring catalysts for the pilot unit. This technical progress report provides an update on these efforts.

  1. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-07-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,'' during the time-period April 1, 2003 through June 30, 2003. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project cofunders. URS Group is the prime contractor. The mercury control process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates with the byproducts from the FGD system. The current project is testing previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, to provide engineering data for future full-scale designs. The pilot-scale tests will continue for approximately 14 months at each of two sites to provide longer-term catalyst life data. This is the seventh full reporting period for the subject Cooperative Agreement. During this period, project efforts included continued operation of the first pilot unit, conducting catalyst activity measurements, installing sonic horns for on-line catalyst cleaning, and installing the fourth catalyst, all for the GRE Coal Creek site. CPS began installation of the second mercury oxidation catalyst pilot unit at their Spruce Plant during the quarter. Laboratory efforts were conducted to support catalyst selection for that second pilot unit. This technical progress report provides an update on these efforts.

  2. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-07-17T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems, during the time period April 1, 2002 through June 30, 2002. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project co-funders. URS Group is the prime contractor. The mercury catalytic oxidation process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates in a stable form with the byproducts from the FGD system. The co-precipitated mercury does not appear to adversely affect the disposal or reuse properties of the FGD byproduct. The current project will test previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, so as to provide engineering data for future full-scale designs. The pilot-scale tests will continue for up to 14 months at each of two sites to provide longer-term catalyst life data. This is the third full reporting period for the subject Cooperative Agreement. During this period, most of the project efforts were related to constructing the pilot unit and conducting laboratory runs to help size catalysts for the pilot unit. This technical progress report provides an update on these two efforts.

  3. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-01-21T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems, during the time period October 1, 2002 through December 31, 2002. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project co-funders. URS Group is the prime contractor. The mercury catalytic oxidation process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates with the byproducts from the FGD system. The co-precipitated mercury does not appear to adversely affect the disposal or reuse properties of the FGD byproduct. The current project testing previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, to provide engineering data for future fullscale designs. The pilot-scale tests will continue for up to 14 months at each of two sites to provide longer-term catalyst life data. This is the fifth full reporting period for the subject Cooperative Agreement. During this period, project efforts included starting up the pilot unit with three catalysts at the first site, conducting catalyst activity measurements, completing comprehensive flue gas sampling and analyses, and procuring additional catalysts for the pilot unit. This technical progress report provides an update on these efforts.

  4. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg.sup.196 enrichment

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA)

    1993-01-01T23:59:59.000Z

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg.sup.196 isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  5. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg[sup 196] enrichment

    DOE Patents [OSTI]

    Grossman, M.W.

    1993-02-16T23:59:59.000Z

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg[sup 196] isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  6. Features of plasma glow in low pressure terahertz gas discharge

    SciTech Connect (OSTI)

    Bratman, V. L.; Golubev, S. V.; Izotov, I. V.; Kalynov, Yu. K.; Koldanov, V. A.; Razin, S. V. [Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod 603950 (Russian Federation)] [Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod 603950 (Russian Federation); Litvak, A. G.; Sidorov, A. V.; Skalyga, V. A.; Zorin, V. G. [Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod 603950 (Russian Federation) [Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod 603950 (Russian Federation); Lobachevsky State University of Nizhny Novgorod (UNN), 23 Gagarina st., 603950 Nizhny Novgorod (Russian Federation)

    2013-12-15T23:59:59.000Z

    Investigations of the low pressure (1–100 Torr) gas discharge in the powerful (1 kW) quasi-optical terahertz (0.55 THz) wave beams were made. An intense afterglow was observed after the end of gyrotron terahertz radiation pulse. Afterglow duration significantly exceeded radiation pulse length (8 ?s). This phenomenon could be explained by the strong dependence of the collisional-radiative recombination rate (that is supposed to be the most likely mechanism of electron losses from the low pressure terahertz gas discharge) on electron temperature.

  7. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, Robert C. (Santa Fe, NM); Quigley, Gerard P. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source. A contamination-free VUV light source having a 225 cm.sup.2 emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm.sup.2 at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing.

  8. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, R.C.; Quigley, G.P.

    1996-12-17T23:59:59.000Z

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

  9. High-order harmonic generation in a capillary discharge

    DOE Patents [OSTI]

    Rocca, Jorge J.; Kapteyn, Henry C.; Mumane, Margaret M.; Gaudiosi, David; Grisham, Michael E.; Popmintchev, Tenio V.; Reagan, Brendan A.

    2010-06-01T23:59:59.000Z

    A pre-ionized medium created by a capillary discharge results in more efficient use of laser energy in high-order harmonic generation (HHG) from ions. It extends the cutoff photon energy, and reduces the distortion of the laser pulse as it propagates down the waveguide. The observed enhancements result from a combination of reduced ionization energy loss and reduced ionization-induced defocusing of the driving laser as well as waveguiding of the driving laser pulse. The discharge plasma also provides a means to spectrally tune the harmonics by tailoring the initial level of ionization of the medium.

  10. Time-dependent dielectric breakdown measurements of porous organosilicate glass using mercury and solid metal probes

    SciTech Connect (OSTI)

    Pei, Dongfei; Nichols, Michael T.; Shohet, J. Leon, E-mail: shohet@engr.wisc.edu [Plasma Processing and Technology Laboratory, Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); King, Sean W.; Clarke, James S. [Intel Corporation, Hillsboro, Oregon 97124 (United States); Nishi, Yoshio [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

    2014-09-01T23:59:59.000Z

    Time-dependent dielectric breakdown (TDDB) is one of the major concerns for low-k dielectric materials. During plasma processing, low-k dielectrics are subjected to vacuum ultraviolet photon radiation and charged-particle bombardment. To examine the change of TDDB properties, time-to-breakdown measurements are made to porous SiCOH before and after plasma exposure. Significant discrepancies between mercury and solid-metal probes are observed and have been shown to be attributed to mercury diffusion into the dielectric porosities.

  11. Field analytical techniques for mercury in soils technology evaluation. Topical report, November 1994--March 1997

    SciTech Connect (OSTI)

    Solc, J.; Harju, J.A.; Grisanti, A.A.

    1998-02-01T23:59:59.000Z

    This report presents the evaluation of the four field analytical techniques for mercury detection in soils, namely (1) an anodic stripping voltametry technique (ASV) developed and tested by General Electric Corporation; (2) a static headspace analysis (SHSA) technique developed and tested by Dr. Ralph Turner of Oak Ridge National Laboratory; (3) the BiMelyze{reg_sign} Mercury Immunoassay (Bio) developed and tested by BioNebraska, Inc.; and (4) a transportable x-ray fluorescence (XRF) instrument/technique developed and tested by Spectrace, Inc.

  12. Airflow influence on the discharge performance of dielectric barrier discharge plasma actuators

    SciTech Connect (OSTI)

    Kriegseis, J.; Tropea, C. [Institute of Fluid Mechanics and Aerodynamics, Technische Universitaet Darmstadt, Flughafenstr. 19, D-64347 Griesheim (Germany); Center of Smart Interfaces, Technische Universitaet Darmstadt, Flughafenstr. 19, D-64347 Griesheim (Germany); Grundmann, S. [Center of Smart Interfaces, Technische Universitaet Darmstadt, Flughafenstr. 19, D-64347 Griesheim (Germany)

    2012-07-15T23:59:59.000Z

    In the present work, the effect of the airflow on the performance of dielectric barrier discharge plasma-actuators is investigated experimentally. In order to analyze the actuator's performance, luminosity measurements have been carried out simultaneously with the recording of the relevant electrical parameters. A performance drop of about 10% is observed for the entire measured parameter range at a flow speed of M = 0.145 (U{sub {infinity}}=50 m/s). This insight is of particular importance, since the plasma-actuator control authority is already significantly reduced at this modest speed level. The results at higher Mach numbers (0.4

  13. Regenerative process for removal of mercury and other heavy metals from gases containing H.sub.2 and/or CO

    DOE Patents [OSTI]

    Jadhav, Raja A. (Naperville, IL)

    2009-07-07T23:59:59.000Z

    A method for removal of mercury from a gaseous stream containing the mercury, hydrogen and/or CO, and hydrogen sulfide and/or carbonyl sulfide in which a dispersed Cu-containing sorbent is contacted with the gaseous stream at a temperature in the range of about 25.degree. C. to about 300.degree. C. until the sorbent is spent. The spent sorbent is contacted with a desorbing gaseous stream at a temperature equal to or higher than the temperature at which the mercury adsorption is carried out, producing a regenerated sorbent and an exhaust gas comprising released mercury. The released mercury in the exhaust gas is captured using a high-capacity sorbent, such as sulfur-impregnated activated carbon, at a temperature less than about 100.degree. C. The regenerated sorbent may then be used to capture additional mercury from the mercury-containing gaseous stream.

  14. The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver

    SciTech Connect (OSTI)

    Bessinger, Brad; Apps, John A.

    2003-03-23T23:59:59.000Z

    A comprehensive thermodynamic database based on the Helgeson-Kirkham-Flowers (HKF) equation of state was developed for metal complexes in hydrothermal systems. Because this equation of state has been shown to accurately predict standard partial molal thermodynamic properties of aqueous species at elevated temperatures and pressures, this study provides the necessary foundation for future exploration into transport and depositional processes in polymetallic ore deposits. The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver sulfide and hydroxide complexes were derived from experimental equilibrium constants using nonlinear regression calculations. In order to ensure that the resulting parameters were internally consistent, those experiments utilizing incompatible thermodynamic data were re-speciated prior to regression. Because new experimental studies were used to revise the HKF parameters for H2S0 and HS-1, those metal complexes for which HKF parameters had been previously derived were also updated. It was found that predicted thermodynamic properties of metal complexes are consistent with linear correlations between standard partial molal thermodynamic properties. This result allowed assessment of several complexes for which experimental data necessary to perform regression calculations was limited. Oxygen fugacity-temperature diagrams were calculated to illustrate how thermodynamic data improves our understanding of depositional processes. Predicted thermodynamic properties were used to investigate metal transport in Carlin-type gold deposits. Assuming a linear relationship between temperature and pressure, metals are predicted to predominantly be transported as sulfide complexes at a total aqueous sulfur concentration of 0.05 m. Also, the presence of arsenic and antimony mineral phases in the deposits are shown to restrict mineralization within a limited range of chemical conditions. Finally, at a lesser aqueous sulfur concentration of 0.01 m, host rock sulfidation can explain the origin of arsenic and antimony minerals within the paragenetic sequence.

  15. In Situ Mercury Stabilization (ISMS) Treatment: Technology Maturation Project Phase I Status Report

    SciTech Connect (OSTI)

    Kalb,P.D.; Milian, L.

    2008-03-01T23:59:59.000Z

    Mercury (Hg) was used to separate lithium-6 isotope for weapons production at the Y-12 Plant in Oak Ridge in the 1950s and 1960s. As much as two million pounds of elemental mercury was 'lost' or unaccounted for and a large portion of that material is believed to have entered the environment. The DOE site office in Oak Ridge has identified Hg pollution in soils, sediments, and streams as the most significant environmental challenge currently faced. In industry, large amounts of mercury have been used to manufacture products (e.g., fluorescent light bulbs, thermometers) and for chemical processing (e.g., production of chlorine and alkali via mercury electrochemical cells) and many of these industrial sites are now polluted with mercury contaminated soil as a result of previous releases and/or inadvertent leaks. Remediation techniques for Hg contaminated soils are either based on thermal desorption and recovery of the mercury or excavation and shipping of large volumes of material to remote facilities for treatment and disposal. Both of these alternatives are extremely costly. The Brookhaven National Laboratory (BNL) Environmental Research & Technology Division (ERTD) has demonstrated, in laboratory-scale experiments, the viability of treating mercury contaminated soils by means of sulfide treatment rods inserted into the soil through a process known as In Situ Mercury Stabilization (ISMS). This approach is partly based on BNL's patented and successfully licensed ex situ process for Hg treatment, Sulfur Polymer Stabilization/Solidification (SPSS) which converts Hg to the more stable sulfide form. The original experiments showed that Hg homogeneously distributed in soil rapidly migrates to form a high concentration zone of chemically stable mercuric sulfide near the treatment rods while concentrations of Hg in surrounding areas away from the treatment rods are depleted to acceptable levels. BSA has subsequently filed for patent protection on the ISMS technology. If further developed it has the potential for large-scale in-situ treatment of contaminated soils that could substantially reduce the prohibitive cost of thermal desorption and/or excavation and disposal. Licensing and spin-off technology development opportunities would then be viable. Depending on performance and regulatory acceptance, the treated mercury could either be excavated for disposal elsewhere or left in place as a stable alternative. Excavated spent treatment rods could be processed by the SPSS process to reduce the potential for dispersion and lower leachability even further. The Phase I objectives of the In Situ Mercury Stabilization Treatment Process Technology Maturation Project were to: (1) replicate the original bench-scale results that formed the basis for BNL's patent application, i.e., mercury contamination in soil will migrate to and react with 'rods' containing sulfur and/or sulfur compounds, (2) provide enough information to evaluate a decision to conduct further development, and (3) establish some of the critical parameters that require further technology maturation during Phase II. The information contained in this report summarizes the work conducted in Phase I to meet these objectives.

  16. The Homogeneus Forcing of Mercury Oxidation to provide Low-Cost Capture

    SciTech Connect (OSTI)

    John Kramlich; Linda Castiglone

    2007-06-30T23:59:59.000Z

    Trace amounts of mercury are found in all coals. During combustion, or during thermal treatment in advanced coal processes, this mercury is vaporized and can be released to the atmosphere with the ultimate combustion products. This has been a cause for concern for a number of years, and has resulted in a determination by the EPA to regulate and control these emissions. Present technology does not, however, provide inexpensive ways to capture or remove mercury. Mercury that exits the furnace in the oxidized form (HgCl{sub 2}) is known to much more easily captured in existing pollution control equipment (e.g., wet scrubbers for SO{sub 2}), principally due to its high solubility in water. Work funded by DOE has helped understand the chemical kinetic processes that lead to mercury oxidation in furnaces. The scenario is as follows. In the flame the mercury is quantitatively vaporized as elemental mercury. Also, the chlorine in the fuel is released as HCl. The direct reaction Hg+HCl is, however, far too slow to be of practical consequence in oxidation. The high temperature region does supports a small concentration of atomic chlorine. As the gases cool (either in the furnace convective passes, in the quench prior to cold gas cleanup, or within a sample probe), the decay in Cl atom is constrained by the slowness of the principal recombination reaction, Cl+Cl+M{yields}Cl{sub 2}+M. This allows chlorine atom to hold a temporary, local superequilibrium concentration . Once the gases drop below about 550 C, the mercury equilibrium shifts to favor HgCl{sub 2} over Hg, and this superequilibrium chlorine atom promotes oxidation via the fast reactions Hg+Cl+M{yields}HgCl+M, HgCl+Cl+M{yields}HgCl{sub 2}+M, and HgCl+Cl{sub 2}{yields}HgCl{sub 2}+Cl. Thus, the high temperature region provides the Cl needed for the reaction, while the quench region allows the Cl to persist and oxidize the mercury in the absence of decomposition reactions that would destroy the HgCl{sub 2}. Promoting mercury oxidation is one means of getting moderate-efficiency, 'free' mercury capture when wet gas cleanup systems are already in place. The chemical kinetic model we developed to describe the oxidation process suggests that in fuel lean gases, the introduction of trace amounts of H{sub 2} within the quench region leads to higher Cl concentrations via chain branching. The amount of additive, and the temperature at the addition point are critical. We investigated this process in a high-temperature quartz flow reactor. The results do indicate a substantial amount of promotion of oxidation with the introduction of relatively small amounts of hydrogen at around 1000 K ({approx}100 ppm relative to the furnace gas). In practical systems the source of this hydrogen is likely to be a small natural gas steam reformer. This would also produce CO, so co-injection of CO was also tested. The CO did not provide any additional promotion, and in some cases led to a reduction in oxidation. We also examined the influence of NO and SO{sub 2} on the promotion process. We did not see any influence under the conditions examined. The present results were for a 0.5 s, isothermal plug flow environment. The next step should be to determine the appropriate injection point for the hydrogen and the performance under realistic temperature quench conditions. This could be accomplished first by chemical kinetic modeling, and then by tunnel flow experiment.

  17. High-speed micro-electro-discharge machining.

    SciTech Connect (OSTI)

    Chandrasekar, Srinivasan Dr. (.School of Industrial Engineering, West Lafayette, IN); Moylan, Shawn P. (School of Industrial Engineering, West Lafayette, IN); Benavides, Gilbert Lawrence

    2005-09-01T23:59:59.000Z

    When two electrodes are in close proximity in a dielectric liquid, application of a voltage pulse can produce a spark discharge between them, resulting in a small amount of material removal from both electrodes. Pulsed application of the voltage at discharge energies in the range of micro-Joules results in the continuous material removal process known as micro-electro-discharge machining (micro-EDM). Spark erosion by micro-EDM provides significant opportunities for producing small features and micro-components such as nozzle holes, slots, shafts and gears in virtually any conductive material. If the speed and precision of micro-EDM processes can be significantly enhanced, then they have the potential to be used for a wide variety of micro-machining applications including fabrication of microelectromechanical system (MEMS) components. Toward this end, a better understanding of the impacts the various machining parameters have on material removal has been established through a single discharge study of micro-EDM and a parametric study of small hole making by micro-EDM. The main avenues for improving the speed and efficiency of the micro-EDM process are in the areas of more controlled pulse generation in the power supply and more controlled positioning of the tool electrode during the machining process. Further investigation of the micro-EDM process in three dimensions leads to important design rules, specifically the smallest feature size attainable by the process.

  18. Condenser for extreme-UV lithography with discharge source

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Kubiak, Glenn D. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    Condenser system, for use with a ringfield camera in projection lithography, employs quasi grazing-incidence collector mirrors that are coated with a suitable reflective metal such as ruthenium to collect radiation from a discharge source to minimize the effect of contaminant accumulation on the collecting mirrors.

  19. SYNAPTIC MECHANISMS Weber's law implies neural discharge more regular than

    E-Print Network [OSTI]

    Feng, Jianfeng

    SYNAPTIC MECHANISMS Weber's law implies neural discharge more regular than a Poisson process Jing, interspike interval, psychophysical law, spike rate Abstract Weber's law is one of the basic laws established. In this paper, we carried out an analysis on the spike train statistics when Weber's law holds

  20. COLLISIONLESS ELECTRON HEATING IN RF GAS DISCHARGES: I. QUASILINEAR THEORY

    E-Print Network [OSTI]

    Kaganovich, Igor

    COLLISIONLESS ELECTRON HEATING IN RF GAS DISCHARGES: I. QUASILINEAR THEORY Yu.M. Aliev1 , I an interest in mechanisms of electron heating and power deposition in the plasma main- tained by radio{frequency (rf) electric elds. A modern trend in plasma technology aims at decreasing the gas pressures down