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We encourage you to perform a real-time search of NLEBeta
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1

Electrodeless HID lamp study. Final report. [High intensity discharge  

SciTech Connect (OSTI)

High intensity discharge lamps excited by solenoidal electric fields (SEF/HID) were examined for their ability to give high brightness, high efficacy and good color. Frequency of operation was 13.56 MHz (ISM Band) and power to the lamp plasma ranged from about 400 to 1000 W. Radio frequency transformers with air cores and with air core complemented by ferrite material in the magnetic path were used to provide the voltage for excitation. Electrical properties of the matching network and the lamp plasma were measured or calculated and total light from the lamp was measured by an integrating sphere. Efficacies calculated from measurement were found to agree well with the positive column efficacies of conventional HID lamps containing only mercury, and with additives of sodium, thallium, and scandium iodide. Recommendations for future work are given.

Anderson, J.M.; Johnson, P.D.; Jones, C.E.; Rautenberg, T.H.

1985-01-01T23:59:59.000Z

2

Study of high frequency & low frequency electronic ballasts for HID lamps  

E-Print Network [OSTI]

High-intensity discharge (HID) lamp electronic ballasting is receiving increasing attention in the recent years as low wattage HID lighting systems are finding indoor applications. Advantages of high frequency electronic ballast for HID lamps...

Peng, Hua

1997-01-01T23:59:59.000Z

3

Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and  

E-Print Network [OSTI]

Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and HID (high-intensity discharge) lamps and all other mercury containing labeled for shipment to a recycling plant for mercury, glass and aluminum recovery. The beneficial re

Baker, Chris I.

4

MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM  

SciTech Connect (OSTI)

In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

V.K. Mathur

2003-02-01T23:59:59.000Z

5

Performance of "Ultra-High" Efficient Electronic Ballast for HID Lamps  

E-Print Network [OSTI]

. Index Terms--Electronic ballast, HID lamps, resonant inverter, power loss modeling, Silicon Carbide (Si of >95% for the ballast. Diode bridge rectifier EMI filter Resonant Inverter Power Factor Correction 75423, USA Abstract--A new electronic ballast circuit for High Intensity Discharge (HID) lamps

Tolbert, Leon M.

6

Max Tech and Beyond: High-Intensity Discharge Lamps  

SciTech Connect (OSTI)

High-intensity discharge (HID) lamps are most often found in industrial and commercial applications, and are the light source of choice in street and area lighting, and sports stadium illumination. HID lamps are produced in three types - mercury vapor (MV), high pressure sodium (HPS) and metal halide (MH). Of these, MV and MH are considered white-light sources (although the MV exhibits poor color rendering) and HPS produces a yellow-orange color light. A fourth lamp, low-pressure sodium (LPS), is not a HID lamp by definition, but it is used in similar applications and thus is often grouped with HID lamps. With the notable exception of MV which is comparatively inefficient and in decline in the US from both a sales and installed stock point of view; HPS, LPS and MH all have efficacies over 100 lumens per watt. The figure below presents the efficacy trends over time for commercially available HID lamps and LPS, starting with MV and LPS in 1930's followed by the development of HPS and MH in the 1960's. In HID lamps, light is generated by creating an electric arc between two electrodes in an arc tube. The particles in the arc are partially ionized, making them electrically conductive, and a light-emitting 'plasma' is created. This arc occurs within the arc tube, which for most HID lamps is enclosed within an evacuated outer bulb that thermally isolates and protects the hot arc tube from the surroundings. Unlike a fluorescent lamp that produces visible light through down-converting UV light with phosphors, the arc itself is the light source in an HID lamp, emitting visible radiation that is characteristic of the elements present in the plasma. Thus, the mixture of elements included in the arc tube is one critical factor determining the quality of the light emitted from the lamp, including its correlated color temperature (CCT) and color rendering index (CRI). Similar to fluorescent lamps, HID lamps require a ballast to start and maintain stable operating conditions, and this necessitates additional power beyond that used by the lamp itself. HID lamps offer important advantages compared to other lighting technologies, making them well suited for certain applications. HID lamps can be very efficient, have long operating lives, are relatively temperature-insensitive and produce a large quantity of light from a small package. For these reasons, HID lamps are often used when high levels of illumination are required over large areas and where operating and maintenance costs must be kept to a minimum. Furthermore, if the installation has a significant mounting height, high-power HID lamps can offer superior optical performance luminaires, reducing the number of lamps required to illuminate a given area. The indoor environments best suited to HID lamps are those with high ceilings, such as those commonly found in industrial spaces, warehouses, large retail spaces, sports halls and large public areas. Research into efficacy improvements for HID lighting technologies has generally followed market demand for these lamps, which is in decline for MV and LPS, has reached a plateau for HPS and is growing for MH. Several manufacturers interviewed for this study indicated that although solid-state lighting was now receiving the bulk of their company's R&D investment, there are still strong HID lamp research programs, which concentrate on MH technologies, with some limited amount of investment in HPS for specific niche applications (e.g., agricultural greenhouses). LPS and MV lamps are no longer being researched or improved in terms of efficacy or other performance attributes, although some consider MH HID lamps to be the next-generation MV lamp. Thus, the efficacy values of commercially available MV, LPS and HPS lamps are not expected to increase in the next 5 to 10 years. MH lamps, and more specifically, ceramic MH lamps are continuing to improve in efficacy as well as light quality, manufacturability and lamp life. Within an HID lamp, the light-producing plasma must be heated to sufficiently high temperatures to achieve high efficiencie

Scholand, Michael

2012-04-01T23:59:59.000Z

7

Application of vane-type resonator to microwave powered electrodeless HID lamp  

SciTech Connect (OSTI)

A cavity resonator has been generally used as microwave applicator for an electrodeless high intensity discharge (HID) lamp. The size of a cavity resonator is determined by the wavelength of a microwave applied. For example, for a microwave of 2.45 GHz, an inner diameter of more than about 76 mm is necessary for obtaining a microwave resonant field, and then the size of a plasma arc capable of maintaining a stable discharge is experimentally limited at about 15 mm and above. Accordingly the microwave powered electrodeless HID lamp device using cavity resonator is inappropriate in applications where a point light source is required. A vane-type resonator is generally known as an anode of a magnetron, which decides the oscillation frequency of the magnetron. The authors used 3-D finite element method simulation for a design of a vane-type resonator with parabolic reflector to obtain a desired resonant frequency. According to the results of the simulation, the sizes of a 4-vanes resonator with the parabolic reflector were decided, and the resonator made of aluminum and copper was prepared. An electrodeless lamp with InBr and Ar gas enclosed in a spherical quartz glass tube having an inner diameter of about 4 mm was also prepared, and was set at center portion of the resonator. The total luminous flux was about 2,150 lm at microwave input of 27 W. Incidentally, the CRI and Tc for this lamp were 93 and 10,200 K, respectively. Thus, it becomes possible to efficiently couple microwave energy with a smaller-sized electrodeless HID lamp than conventional.

Hochi, Akira; Takeda, Mamoru

1999-07-01T23:59:59.000Z

8

T-547: Microsoft Windows Human Interface Device (HID) Vulnerability  

Broader source: Energy.gov [DOE]

Microsoft Windows does not properly warn the user before enabling additional Human Interface Device (HID) functionality over USB, which allows user-assisted attackers to execute arbitrary programs via crafted USB data, as demonstrated by keyboard and mouse data sent by malware on a Smartphone that the user connected to the computer.

9

Visible-light active TiO2 for microwave assisted photocatalytic reactions using mercury electrodeless discharge lamps  

E-Print Network [OSTI]

activity was evaluated by the degradation of mono-chloroacetic acid in a microwave field using mercury with pure titania, the UV-Vis spectra of Ag+, Zr4+ and VO2+ doped titanium dioxide show significant absorption in visible region. The degradation efficiency of MCAA in a microwave field on these TiO2 layers

Cirkva, Vladimir

10

IEEE Power Electronics Specialists Conference, PESC-97, 39-45, St. Louis, 1997. A MHz Electronic Ballast for Automotive-Type HID Lamps  

E-Print Network [OSTI]

Ballast for Automotive-Type HID Lamps Michael Gulko and Sam Ben-Yaakov* Power Electronics Laboratory-Resonance Inverter (CS-PPRI) topology [2] as a ballast for low wattage HID lamps designated as automotive headlights lamp option to replace the conventional 'halogen' type headlights. Unfortunately, application of HID

11

HIGH INTENSITY DISCHARGE (HID) SOLID STATE BALLAST PROGRAM PHASE I FINAL REPORT  

E-Print Network [OSTI]

change in the output power for the solid state ballast asof the solid state ballast's constant output power withswitching power supplies such as the solid state ballast.

Ailing, W.R.

2013-01-01T23:59:59.000Z

12

HIGH INTENSITY DISCHARGE (HID) SOLID STATE BALLAST PROGRAM PHASE I FINAL REPORT  

E-Print Network [OSTI]

A trapazoid for each type and lamp wattage is published bylamp wattage for the core-coil ballast was measured with a dynamometer type

Ailing, W.R.

2013-01-01T23:59:59.000Z

13

Plasma spectroscopic study of an electrodeless HID lamp containing Tl and Zn  

SciTech Connect (OSTI)

Recently the electrodeless HID lamps excited by microwaves have been studied intensively. Tl is well known as a material having strong green emission lines. In this study, Tl spectra excited by microwaves were reported in the cases of Tl only and Tl + Zn. Using the Elenbaas`s method of high pressure Hg lamp, the cause of Tl continuous spectrum was examined. From the ratio of radiative intensities of two lines, an average arc temperature in the bulb was estimated. Then excitation level of the continuous emission spectrum near the 600nm wavelength was calculated from the dependence of the radiative intensities on these arc temperatures.

Takeda, Mamoru; Horii, Shigeru; Hochi, Akira [Matsushita Electric Industrial Co., Ltd., Kyoto (Japan). Lighting Research Lab.

1996-12-31T23:59:59.000Z

14

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents [OSTI]

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

15

Apparatus for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

1988-01-01T23:59:59.000Z

16

Mercury Thermometer Replacement Alternatives Thermometer Description Non-Mercury Non-Mercury Non-Mercury  

E-Print Network [OSTI]

Mercury Thermometer Replacement Alternatives Length Thermometer Description Non-Mercury Non-Mercury Non-Mercury Range / Division VWR-Enviro-Safe® Fisherbrand® Brooklyn Thermometer Company Inc. Total/A #12;Mercury Thermometer Replacement Alternatives Length Thermometer Description Non-Mercury Non

17

Environmental and health aspects of lighting: Mercury  

SciTech Connect (OSTI)

Most discharge lamps, including fluorescent lamps, metal halide lamps, and high pressure sodium lamps, contain Mercury, a toxic chemical. Lighting professionals need to be able to respond to questions about the direct hazards of Mercury from accidentally breaking lamps, and the potential environmental hazards of lamp operation and disposal. We calculated the exposures that could occur from an accidental breakage of lamps. Acute poisoning appears almost impossible. Under some circumstances a sealed environment, such as a space station, could be contaminated enough to make it unhealthy for long-term occupation. Mercury becomes a potential environmental hazard after it becomes methylated. Mercury is methylated in aquatic environments, where it may accumulate in fish, eventually rendering them toxic to people and other animals. Lighting causes Mercury to enter the environment directly from lamp disposal, and indirectly from power plant emissions. The environmental tradeoffs between incandescent and discharge lamps depend upon the amounts released by these two sources, their local concentrations, and their probabilities of being methylated. Indirect environmental effects of lighting also include the release of other heavy metals (Cadmium, Lead and Arsenic), and other air pollutants and carbon dioxide that are emitted by fossil fuel power plants. For a given light output, the level of power plant emissions depends upon the efficacy of the light source, and is thus much larger for incandescent lamps than for fluorescent or discharge lamps. As disposal and control technologies change the relative direct and indirect emissions from discharge and incandescent lamps will change.

Clear, R.; Berman, S.

1993-07-01T23:59:59.000Z

18

Atmospheric Mercury Deposition Impacts of Future Electric Power Generation  

E-Print Network [OSTI]

Atmospheric Mercury Deposition Impacts of Future Electric Power Generation Mark D. Cohen Physical fish consumption, and significant portions of the general population are believed to be consuming toxicologically significant levels of mercury (e.g., National Research Council, 2000). Historical discharges ­ e

19

Increased Mercury Bioaccumulation Follows Water Quality Improvement  

SciTech Connect (OSTI)

Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new waste treatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury increased over the period during which ecological metrics indicated improved water quality. In the system where waterborne mercury concentrations were at background levels, increased mercury bioaccumulation was probably a result of reduced aqueous selenium concentrations; however, the mechanisms for increased mercury accumulation in the other two streams remain under investigation. In each of the three systems, reduced inputs of metals and inorganic anions was followed by improvements in the health of aquatic invertebrate communities. However, this reduction in risk to aquatic invertebrates was accompanied by increased risk to humans and piscivorous wildlife related to increased mercury concentrations in fish.

Bogle, M.A.; Peterson, M.J.; Smith, J.G.; Southworth, G.R.

1999-09-15T23:59:59.000Z

20

Filter for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

A filter for enriching the .sup.196 Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The .sup.196 Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter.

Grossman, Mark W. (Belmont, MA); George, William A. (Gloucestor, MA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Filter for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

A filter is described for enriching the [sup 196]Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The [sup 196]Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is, less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter. 9 figs.

Grossman, M.W.; George, W.A.

1989-06-13T23:59:59.000Z

22

Mercury contamination extraction  

DOE Patents [OSTI]

Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

2009-09-15T23:59:59.000Z

23

Bioaccumulation of Mercury in Sharks  

E-Print Network [OSTI]

Bioaccumulation of Mercury in Sharks Part 1 b After you finish the video and the above questions Resources: EPA General Info on Mercury - http://www.epa.gov/mercury/about.htm FDA Mercury Levels in Seafood.htm World Health Organization Key Facts on Mercury - http://www.who.int/mediacentre/factsheets/fs361

Miami, University of

24

High intensity discharge device containing oxytrihalides  

DOE Patents [OSTI]

A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO[sub 2], with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube. 7 figs.

Lapatovich, W.P.; Keeffe, W.M.; Liebermann, R.W.; Maya, J.

1987-06-09T23:59:59.000Z

25

High intensity discharge device containing oxytrihalides  

DOE Patents [OSTI]

A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO.sub.2, with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube.

Lapatovich, Walter P. (Hudson, MA); Keeffe, William M. (Rockport, MA); Liebermann, Richard W. (Danvers, MA); Maya, Jakob (Brookline, MA)

1987-01-01T23:59:59.000Z

26

Source-attribution for atmospheric mercury deposition: Where does the mercury in mercury deposition come from?  

E-Print Network [OSTI]

1 Source-attribution for atmospheric mercury deposition: Where does the mercury in mercury of the Mercury Working Group, Office of Air Quality, Indiana Department of Environmental Management (IDEM) April 21, 2005 #12;2 For mercury, how important is atmospheric deposition relative to other loading

27

Mercury Calibration System  

SciTech Connect (OSTI)

U.S. Environmental Protection Agency (EPA) Performance Specification 12 in the Clean Air Mercury Rule (CAMR) states that a mercury CEM must be calibrated with National Institute for Standards and Technology (NIST)-traceable standards. In early 2009, a NIST traceable standard for elemental mercury CEM calibration still does not exist. Despite the vacature of CAMR by a Federal appeals court in early 2008, a NIST traceable standard is still needed for whatever regulation is implemented in the future. Thermo Fisher is a major vendor providing complete integrated mercury continuous emissions monitoring (CEM) systems to the industry. WRI is participating with EPA, EPRI, NIST, and Thermo Fisher towards the development of the criteria that will be used in the traceability protocols to be issued by EPA. An initial draft of an elemental mercury calibration traceability protocol was distributed for comment to the participating research groups and vendors on a limited basis in early May 2007. In August 2007, EPA issued an interim traceability protocol for elemental mercury calibrators. Various working drafts of the new interim traceability protocols were distributed in late 2008 and early 2009 to participants in the Mercury Standards Working Committee project. The protocols include sections on qualification and certification. The qualification section describes in general terms tests that must be conducted by the calibrator vendors to demonstrate that their calibration equipment meets the minimum requirements to be established by EPA for use in CAMR monitoring. Variables to be examined include linearity, ambient temperature, back pressure, ambient pressure, line voltage, and effects of shipping. None of the procedures were described in detail in the draft interim documents; however they describe what EPA would like to eventually develop. WRI is providing the data and results to EPA for use in developing revised experimental procedures and realistic acceptance criteria based on actual capabilities of the current calibration technology. As part of the current effort, WRI worked with Thermo Fisher elemental mercury calibrator units to conduct qualification experiments to demonstrate their performance characteristics under a variety of conditions and to demonstrate that they qualify for use in the CEM calibration program. Monitoring of speciated mercury is another concern of this research. The mercury emissions from coal-fired power plants are comprised of both elemental and oxidized mercury. Current CEM analyzers are designed to measure elemental mercury only. Oxidized mercury must first be converted to elemental mercury prior to entering the analyzer inlet in order to be measured. CEM systems must demonstrate the ability to measure both elemental and oxidized mercury. This requires the use of oxidized mercury generators with an efficient conversion of the oxidized mercury to elemental mercury. There are currently two basic types of mercuric chloride (HgCl{sub 2}) generators used for this purpose. One is an evaporative HgCl{sub 2} generator, which produces gas standards of known concentration by vaporization of aqueous HgCl{sub 2} solutions and quantitative mixing with a diluent carrier gas. The other is a device that converts the output from an elemental Hg generator to HgCl{sub 2} by means of a chemical reaction with chlorine gas. The Thermo Fisher oxidizer system involves reaction of elemental mercury vapor with chlorine gas at an elevated temperature. The draft interim protocol for oxidized mercury units involving reaction with chlorine gas requires the vendors to demonstrate high efficiency of oxidation of an elemental mercury stream from an elemental mercury vapor generator. The Thermo Fisher oxidizer unit is designed to operate at the power plant stack at the probe outlet. Following oxidation of elemental mercury from reaction with chlorine gas, a high temperature module reduces the mercuric chloride back to elemental mercury. WRI conducted work with a custom laboratory configured stand-alone oxidized mercury generator unit prov

John Schabron; Eric Kalberer; Joseph Rovani; Mark Sanderson; Ryan Boysen; William Schuster

2009-03-11T23:59:59.000Z

28

Process for low mercury coal  

DOE Patents [OSTI]

A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

1995-01-01T23:59:59.000Z

29

Process for low mercury coal  

DOE Patents [OSTI]

A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

1995-04-04T23:59:59.000Z

30

Mercury Detection with Gold Nanoparticles  

E-Print Network [OSTI]

R. J. Warmack, Detection of mercury vapor using resonatingA surface acoustic wave mercury vapor sensor, Ieee Trans.N. E. Selin, Integrating mercury science and policy in the

Crosby, Jeffrey

2013-01-01T23:59:59.000Z

31

Mercury Chamber Considerations  

E-Print Network [OSTI]

Mercury Chamber Considerations V. Graves IDS-NF Target Studies July 2011 #12;2 Managed by UT-Battelle for the U.S. Department of Energy Mercury Chamber Considerations, July 2011 Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment

McDonald, Kirk

32

Neutrino Factory Mercury Vessel  

E-Print Network [OSTI]

Neutrino Factory Mercury Vessel: Initial Cooling Calculations V. Graves Target Studies Nov 15, 2012 #12;2 Managed by UT-Battelle for the U.S. Department of Energy Cooling Calculations 15 Nov 2012 Target · Separates functionality, provides double mercury containment, simplifies design and remote handling · Each

McDonald, Kirk

33

Mercury in the environment  

ScienceCinema (OSTI)

Abbott works for Idaho National Laboratory as an environmental scientist. Using state-of-thescienceequipment, he continuously samples the air, looking for mercury. In turn, he'll analyzethis long-term data and try to figure out the mercury's point of or

Idaho National Laboratory - Mike Abbott

2010-01-08T23:59:59.000Z

34

Mercury Jet Studies Tristan Davenne  

E-Print Network [OSTI]

Mercury Jet Studies Tristan Davenne Rutherford Appleton Laboratory Joint UKNF, INO, UKIERI meeting mercury target and reported a radial velocity at surface of mercury jet due to proton beam is 36m/s #12;Numerical simulation of Sievers & Pugnat Result Click on image above to watch video of 2cm mercury target

McDonald, Kirk

35

Mercury Effects, Sources and Control Measures  

E-Print Network [OSTI]

Mercury Effects, Sources and Control Measures Prepared by Alan B. Jones, Brooks Rand, Ltd., Seattle ................................................................................................................................1 MERCURY SOURCES....................................................................................................................................................................................8 Mercury dumping from naval vessels

36

Mercury Sensing with Optically Responsive Gold Nanoparticles  

E-Print Network [OSTI]

We assume that the mass of mercury adsorbed at saturation istactics, nanoparticle based mercury sensing should advancemost sensitive method for mercury sensing. References "1!

James, Jay Zachary

2012-01-01T23:59:59.000Z

37

FINAL REPORT ON THE AQUATIC MERCURY ASSESSMENT STUDY  

SciTech Connect (OSTI)

In February 2000, the United States Environmental Protection Agency (EPA) Region 4 issued a proposed Total Maximum Daily Load (TMDL) for total mercury in the middle and lower Savannah River. The initial TMDL, which would have imposed a 1 ng/l mercury limit for discharges to the middle/lower Savannah River, was revised to 2.8 ng/l in the final TMDL released in February 2001. The TMDL was intended to protect people from the consumption of contaminated fish, which is the major route of mercury exposure to humans. The most bioaccumulative form of mercury is methylmercury, which is produced in aquatic environments by the action of microorganisms on inorganic mercury. Because of the environmental and economic significance of the mercury discharge limits that would have been imposed by the TMDL, the Savannah River Site (SRS) initiated several studies concerning: (1) mercury in SRS discharges, SRS streams and the Savannah River, (2) mercury bioaccumulation factors for Savannah River fish, (3) the use of clams to monitor the influence of mercury from tributary streams on biota in the Savannah River, and (4) mercury in rainwater falling on the SRS. The results of these studies are presented in detail in this report. The first study documented the occurrence, distribution and variation of total and methylmercury at SRS industrial outfalls, principal SRS streams and the Savannah River where it forms the border with the SRS. All of the analyses were performed using the EPA Method 1630/31 ultra low-level and contaminant-free techniques for measuring total and methylmercury. Total mercury at National Pollutant Discharge Elimination System (NPDES) outfalls ranged from 0.31-604 ng/l with a mean of 8.71 ng/l. Mercury-contaminated groundwater was the source for outfalls with significantly elevated mercury concentrations. Total mercury in SRS streams ranged from 0.95-15.7 ng/l. Mean total mercury levels in the streams varied from 2.39 ng/l in Pen Branch to 5.26 ng/l in Tims Branch. Methylmercury ranged from 0.002 ng/l in Upper Three Runs to 2.60 ng/l in Tims Branch. Total mercury in the Savannah River ranged from 0.62 ng/l to 43.9 ng/l, and methylmercury ranged from 0.036 ng/l to 7.54 ng/l. Both total and methylmercury concentrations were consistently high in the river near the mouth of Steel Creek. Total mercury was positively correlated with methylmercury (r = 0.88). Total mercury bound to particulates ranged from 41% to 57% in the river and from 28% to 90% in the streams. Particulate methylmercury varied from 9% to 37% in the river and from 6% to 79% in the streams. Small temporary pools in the Savannah River swamp area near and around Fourmile Branch had the highest concentrations observed in the Savannah River watershed, reaching 1,890 ng/l for total mercury and 34.0 ng/l for methylmercury. The second study developed a mercury bioaccumulation factor (BAF) for the Savannah River near SRS. A BAF is the ratio of the concentration of mercury in fish flesh to the concentration of mercury in the water. BAFs are important in the TMDL process because target concentrations for mercury in water are computed from BAFs. Mercury BAFs are known to differ substantially among fish species, water bodies, and possibly seasons. Knowledge of such variation is needed to determine a BAF that accurately represents average and extreme conditions in the water body under study. Analysis of fish tissue and aqueous methylmercury samples collected at a number of locations and over several seasons in a 110 km (68 mile) reach of the Savannah River demonstrated that BAFs for each species under study varied by factors of three to eight. Influences on BAF variability were location, habitat and season-related differences in fish mercury levels and seasonal differences in methylmercury levels in the water. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 10{sup 6} for largemouth bass, 1.4 x 10{sup 6} for sunfishes, and 2.5 x 10{sup 6} for white catfish. This study showed that determination of representative BAFs for large rivers requires the collect

Halverson, N

2008-09-30T23:59:59.000Z

38

High pressure discharges in cavities formed by microfabrication techniques  

SciTech Connect (OSTI)

High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. {copyright} {ital 1997 American Institute of Physics.}

Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J. [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)] [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)

1997-07-01T23:59:59.000Z

39

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1989-01-01T23:59:59.000Z

40

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figures.

Grossman, M.W.; George, W.A.

1991-06-18T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1988-01-01T23:59:59.000Z

42

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1991-01-01T23:59:59.000Z

43

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figs.

Grossman, M.W.; George, W.A.

1989-11-07T23:59:59.000Z

44

Method and apparatus for monitoring mercury emissions  

DOE Patents [OSTI]

A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber. 15 figs.

Durham, M.D.; Schlager, R.J.; Sappey, A.D.; Sagan, F.J.; Marmaro, R.W.; Wilson, K.G.

1997-10-21T23:59:59.000Z

45

Method and apparatus for monitoring mercury emissions  

DOE Patents [OSTI]

A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

Durham, Michael D. (Castle Rock, CO); Schlager, Richard J. (Aurora, CO); Sappey, Andrew D. (Golden, CO); Sagan, Francis J. (Lakewood, CO); Marmaro, Roger W. (Littleton, CO); Wilson, Kevin G. (Littleton, CO)

1997-01-01T23:59:59.000Z

46

Mercury CEM Calibration  

SciTech Connect (OSTI)

The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005, requires that calibration of mercury continuous emissions monitors (CEMs) be performed with NIST-traceable standards. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The traceability protocol will be written by EPA. Traceability will be based on the actual analysis of the output of each calibration unit at several concentration levels ranging from about 2-40 ug/m{sup 3}, and this analysis will be directly traceable to analyses by NIST using isotope dilution inductively coupled plasma/mass spectrometry (ID ICP/MS) through a chain of analyses linking the calibration unit in the power plant to the NIST ID ICP/MS. Prior to this project, NIST did not provide a recommended mercury vapor pressure equation or list mercury vapor pressure in its vapor pressure database. The NIST Physical and Chemical Properties Division in Boulder, Colorado was subcontracted under this project to study the issue in detail and to recommend a mercury vapor pressure equation that the vendors of mercury vapor pressure calibration units can use to calculate the elemental mercury vapor concentration in an equilibrium chamber at a particular temperature. As part of this study, a preliminary evaluation of calibration units from five vendors was made. The work was performed by NIST in Gaithersburg, MD and Joe Rovani from WRI who traveled to NIST as a Visiting Scientist.

John F. Schabron; Joseph F. Rovani; Susan S. Sorini

2007-03-31T23:59:59.000Z

47

Mercury CEM Calibration  

SciTech Connect (OSTI)

Mercury continuous emissions monitoring systems (CEMS) are being implemented in over 800 coal-fired power plant stacks. The power industry desires to conduct at least a full year of monitoring before the formal monitoring and reporting requirement begins on January 1, 2009. It is important for the industry to have available reliable, turnkey equipment from CEM vendors. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The generators are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 requires that calibration be performed with NIST-traceable standards (Federal Register 2007). Traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued an interim traceability protocol for elemental mercury generators (EPA 2007). The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The document is divided into two separate sections. The first deals with the qualification of generators by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the generator models that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma/mass spectrometry performed by NIST in Gaithersburg, MD. The outputs of mercury generators are compared to one another using a nesting procedure which allows direct comparison of one generator with another and eliminates analyzer variability effects. The qualification portion of the EPA interim traceability protocol requires the vendors to define generator performance as affected by variables such as pressure, temperature, line voltage, and shipping. WRI is focusing efforts to determine actual generator performance related to the variables defined in the qualification portion of the interim protocol. The protocol will then be further revised by EPA based on what can actually be achieved with the generators. Another focus of the study is to evaluate approaches for field verification of generator performance. Upcoming work includes evaluation of oxidized mercury calibration generators, for which a separate protocol will be prepared by EPA. In addition, the variability of the spectrometers/analyzers under various environmental conditions needs to be defined and understood better. A main objective of the current work is to provide data on the performance and capabilities of elemental mercury generator/calibration systems for the development of realistic NIST traceability protocols for mercury vapor standards for continuous emission CEM calibration. This work is providing a direct contribution to the enablement of continuous emissions monitoring at coal-fired power plants in conformance with the CAMR. EPA Specification 12 states that mercury CEMs must be calibrated with NIST-traceable standards (Federal Register 2005). The initial draft of an elemental mercury generator traceability protocol was circulated by EPA in May 2007 for comment, and an interim protocol was issued in August 2007 (EPA 2007). Initially it was assumed that the calibration and implementation of mercury CEMs would be relatively simple, and implementation would follow the implementation of the Clean Air Interstate Rule (CAIR) SO{sub 2} and NO{sub x} monitoring, and sulfur emissions cap and trade. However, mercury has proven to be significantly more difficult

John Schabron; Joseph Rovani; Mark Sanderson

2008-02-29T23:59:59.000Z

48

Mercury-Related Materials Studies  

E-Print Network [OSTI]

. Pawel, "Assessment of Cavitation-Erosion Resistance of Potential Pump Impeller Materials for Mercury of Cavitation Resistant Modifications to Type 316LN Stainless Steel in a Mercury Thermal Convection Loop," OakMercury-Related Materials Studies Van Graves IDS NF Ph M tiIDS-NF Phone Meeting Jan 26, 2010

McDonald, Kirk

49

Mercury-Related Materials Studies  

E-Print Network [OSTI]

Mercury-Related Materials Studies Van Graves IDS NF Ph M tiIDS-NF Phone Meeting Jan 26, 2010 #12 Evaluation of Cavitation Resistance of Type 316LN Stainless Steel in Mercury Using a Vibratory Horn," J. Nucl Pump Impeller Materials for Mercury Service at the Spallation Neutron Source," Oak Ridge National

McDonald, Kirk

50

Bioaccumulation of Mercury in Sharks  

E-Print Network [OSTI]

Bioaccumulation of Mercury in Sharks Part 2 a Using a subset of data collected on RJD shark research trips, you will analyze the mercury levels found in the Florida Sharks we catch. Based on your analysis, you will be able to conclude which species have the highest levels of mercury contamination

Miami, University of

51

Office of Environmental Health and Safety The University of Texas at Austin  

E-Print Network [OSTI]

202 Austin, Texas 78712 (512) 471-3511; Fax: (512) 471-6918 INFO SHEET Fluorescent Light Bulb Disposal such as small lamps, mercury vapor lamps, and other odd shaped fluorescent tubes. In the case of smaller bulbs Used Fluorescent, high intensity discharge (HID), and UV germicidal lamps are considered a hazardous

52

Wastewater Discharge Program (Maine)  

Broader source: Energy.gov [DOE]

The wastewater discharge regulations require that a license be obtained for the discharge of wastewater to a stream, river, wetland, or lake of the state, or to the ocean. Typical discharges...

53

Water displacement mercury pump  

DOE Patents [OSTI]

A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

Nielsen, Marshall G. (Woodside, CA)

1985-01-01T23:59:59.000Z

54

Water displacement mercury pump  

DOE Patents [OSTI]

A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

Nielsen, M.G.

1984-04-20T23:59:59.000Z

55

LONG-TERM CHANGES IN MERCURY CONCENTRATIONS IN FISH FROM THE MIDDLE SAVANNAH RIVER  

SciTech Connect (OSTI)

Total mercury levels were measured in largemouth bass (Micropterus salmoides), ''sunfishes'' (Lepomis spp)., and ''catfish'' (primarily Ameiurus spp.) from 1971 to 2004 in the middle reaches of the Savannah River, which drains the coastal plain of the southeastern U.S. Mercury levels were highest in 1971 but declined over the next ten years due to the mitigation of point sources of industrial pollution. Mercury levels began to increase in the 1980s as a possible consequence of mercury inputs from tributaries and associated wetlands where mercury concentrations were significantly elevated in water and fish. Mercury levels in Savannah River fish decreased sharply in 2001-2003 coincident with a severe drought in the Savannah River basin, but returned to previous levels in 2004 with the resumption of normal precipitation. Regression models showed that mercury levels in Savannah River fish changed significantly over time and were affected by river discharge. Despite temporal changes, there was little overall difference in Savannah River fish tissue mercury levels between 1971 and 2004.

Paller, M; Bill Littrell, B

2007-01-02T23:59:59.000Z

56

Mercury Information Clearinghouse  

SciTech Connect (OSTI)

The Canadian Electricity Association (CEA) identified a need and contracted the Energy & Environmental Research Center (EERC) to create and maintain an information clearinghouse on global research and development activities related to mercury emissions from coal-fired electric utilities. With the support of CEA, the Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates, and the U.S. Department of Energy (DOE), the EERC developed comprehensive quarterly information updates that provide a detailed assessment of developments in the various areas of mercury monitoring, control, policy, and research. A total of eight topical reports were completed and are summarized and updated in this final CEA quarterly report. The original quarterly reports can be viewed at the CEA Web site (www.ceamercuryprogram.ca). In addition to a comprehensive update of previous mercury-related topics, a review of results from the CEA Mercury Program is provided. Members of Canada's coal-fired electricity generation sector (ATCO Power, EPCOR, Manitoba Hydro, New Brunswick Power, Nova Scotia Power Inc., Ontario Power Generation, SaskPower, and TransAlta) and CEA, have compiled an extensive database of information from stack-, coal-, and ash-sampling activities. Data from this effort are also available at the CEA Web site and have provided critical information for establishing and reviewing a mercury standard for Canada that is protective of environment and public health and is cost-effective. Specific goals outlined for the CEA mercury program included the following: (1) Improve emission inventories and develop management options through an intensive 2-year coal-, ash-, and stack-sampling program; (2) Promote effective stack testing through the development of guidance material and the support of on-site training on the Ontario Hydro method for employees, government representatives, and contractors on an as-needed basis; (3) Strengthen laboratory analytical capabilities through analysis and quality assurance programs; and (4) Create and maintain an information clearinghouse to ensure that all parties can keep informed on global mercury research and development activities.

Chad A. Wocken; Michael J. Holmes; Dennis L. Laudal; Debra F. Pflughoeft-Hassett; Greg F. Weber; Nicholas V. C. Ralston; Stanley J. Miller; Grant E. Dunham; Edwin S. Olson; Laura J. Raymond; John H. Pavlish; Everett A. Sondreal; Steven A. Benson

2006-03-31T23:59:59.000Z

57

Oscillations in glow discharges  

E-Print Network [OSTI]

OSCILLATIONS IN GLOW DISCHARGES A Dissertation By Tom Prickett, Jr. June 1950 Approved as to style and content by Chairman of Committee OSCILLATIONS IN GLOW DISCHARGES A Dissertation By Tom Prickett, Jr* June 1950 OSCILLATIONS IN GLOW... 1950 CONTENTS Introduction ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 1 I. Review of Plasma Oscillations in Gas Discharges ? . . 2 II. Review of Relaxation Processes in Gas Discharges ? . 13 III. Report of Laboratory Investigation...

Prickett, Tom

1950-01-01T23:59:59.000Z

58

Mercury control in 2009  

SciTech Connect (OSTI)

Although activated carbon injection (ACI) has been proven to be effective for many configurations and is a preferred option at many plants sufficient quantities of powdered activated coking (PAC) must be available to meet future needs. The authors estimate that upcoming federal and state regulations will result in tripling the annual US demand for activated carbon to nearly 1.5 billion lb from approximately 450 million lb. Rapid expansion of US production capacity is required. Many PAC manufacturers are discussing expansion of their existing production capabilities. One company, ADA Carbon Solutions, is in the process of constructing the largest activated carbon facility in North America to meet the future demand for PAC as a sorbent for mercury control. Emission control technology development and commercialization is driven by regulation and legislation. Although ACI will not achieve > 90% mercury control at every plant, the expected required MACT legislation level, it offers promise as a low-cost primary mercury control technology option for many configurations and an important trim technology for others. ACI has emerged as the clear mercury-specific control option of choice, representing over 98% of the commercial mercury control system orders to date. As state regulations are implemented and the potential for a federal rule becomes more imminent, suppliers are continuing to develop technologies to improve the cost effectiveness and limit the balance of plant impacts associated with ACI and are developing additional PAC production capabilities to ensure that the industry's needs are met. The commercialisation of ACI is a clear example of industry, through the dedication of many individuals and companies with support from the DOE and EPRI, meeting the challenge of developing cost-effectively reducing emissions from coal-fired power plants. 7 refs., 1 fig.

Sjostrom, S.; Durham, M.; Bustard, J.; Martin, C. [ADA Environmental Solutions, Littleton, CO (United States)

2009-07-15T23:59:59.000Z

59

Biosequence Similarity Search on the Mercury System  

E-Print Network [OSTI]

Biosequence Similarity Search on the Mercury System Praveen Krishnamurthy, Jeremy Buhler, Roger Chamberlain, Mark Franklin, Kwame Gyang, and Joseph Lancaster, "Biosequence Similarity Search on the Mercury on the Mercury System Praveen Krishnamurthy, Jeremy Buhler, Roger Chamberlain, Mark Franklin, Kwame Gyang

Chamberlain, Roger

60

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

Greenhalgh, W.O.

1987-02-27T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

Greenhalgh, Wilbur O. (Richland, WA)

1989-01-01T23:59:59.000Z

62

Mercury Strategic Plan Outfall 200 Mercury Treatment Facility  

Office of Environmental Management (EM)

Partial LMR * Alpha-5 LMR & Bldg Characterization * S&M mercury removal * Hg waterfishsediment studies * Technology Development Plan * Debris treatability study * Fate and...

63

Innovative Mercury Treatment Benefits Stream, Fish | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Mercury Treatment Benefits Stream, Fish Innovative Mercury Treatment Benefits Stream, Fish October 1, 2012 - 12:00pm Addthis Oak Ridge scientists Kelly Roy, left, and Trent Jett...

64

Neutrino Factory Mercury Flow Loop  

E-Print Network [OSTI]

Neutrino Factory Mercury Flow Loop V. GravesV. Graves C. Caldwell IDS-NF Videoconference March 9, 2010 #12;Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94 2 liter/min 24 9 gpm)mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment showed that a pump

McDonald, Kirk

65

Mercury Detection with Gold Nanoparticles  

E-Print Network [OSTI]

samples by cold vapor-atomic absorption spectrometry, J.S. Gucer, Direct atomic absorption determination of mercuryL. A. Vasilieva, Direct atomic absorption determination of

Crosby, Jeffrey

2013-01-01T23:59:59.000Z

66

Apparatus for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

Grossman, M.W.; Speer, R.; George, W.A.

1991-07-16T23:59:59.000Z

67

Method for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

Grossman, M.W.; Speer, R.; George, W.A.

1991-04-09T23:59:59.000Z

68

Method for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA); George, William A. (Rockport, MA)

1991-01-01T23:59:59.000Z

69

Apparatus for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA); George, William A. (Rockport, MA)

1991-01-01T23:59:59.000Z

70

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

2009-01-20T23:59:59.000Z

71

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-Ger (El Cerrito, CA); Liu, Shou-Heng (Kaohsiung, TW); Liu, Zhao-Rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

2011-08-30T23:59:59.000Z

72

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Bejing, CN); Yan, Naiqiang (Burkeley, CA)

2010-07-13T23:59:59.000Z

73

Direct Discharge Permit (Vermont)  

Broader source: Energy.gov [DOE]

A direct discharge permit is required if a project involves the discharge of pollutants to state waters. For generation purposes, this involves the withdrawal of surface water for cooling purposes...

74

RMP Mercury Strategy 06-03-09.doc Page 1 of 5 RMP MERCURY STRATEGY  

E-Print Network [OSTI]

RMP Mercury Strategy 06-03-09.doc Page 1 of 5 RMP MERCURY STRATEGY Mercury is a pollutant of high the information most urgently needed by managers to find remedies to the Bay's mercury problem. The focus of total mercury in the Bay are expected to slowly decline over coming decades. The premise

75

Stanford University Mercury Thermometer Replacement  

E-Print Network [OSTI]

Stanford University Mercury Thermometer Replacement Program Instructions for Reuniting Separated Fluid Column of Non-Mercury Thermometer Heating Method Heat the thermometers bulb in an upright position of the thermometer. Note that over filling the expansion chamber will break the thermometer. Tap the thermometer

76

Atmospheric Mercury: Emissions, Transport/Fate,  

E-Print Network [OSTI]

, global...) Is "emissions trading" workable and ethical? Is the recently promulgated Clean Air Mercury

77

Mercury Speciation in the Presence of Polysulfides  

E-Print Network [OSTI]

Mercury Speciation in the Presence of Polysulfides J E N N Y A Y L A J A Y , * , F R A N C¸ O I Environmental mercury methylation appears modulated by sulfide concentrations, possibly via changes in mercury, there has been much recent interest in quantifying the chemical speciation and lipid solubility of mercury

Morel, François M. M.

78

Methods for dispensing mercury into devices  

DOE Patents [OSTI]

A process for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg.sub.2 Cl.sub.2 and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1987-04-28T23:59:59.000Z

79

Mercury and the Gold Country Angler Survey  

E-Print Network [OSTI]

#12;#12;Mercury and the Gold Rush #12;#12;#12;#12;#12;#12;#12;#12;#12;Gold Country Angler Survey A Pilot Study to Assess Mercury Exposure from Sport Fish Consumption in the Sierra Nevada Carrie Monohan, Ph.D. #12;Mercury and the Gold Rush Deer Creek 1908 Greenhorn Creek 2011 Mercury was used during

80

Mercury Pollution in the Marine Environment  

E-Print Network [OSTI]

Mercury Pollution in the Marine Environment The Coastal and Marine Mercury Ecosystem Research stakeholders to form C-MERC, the Coastal and Marine Mercury Ecosystem Research Collaborative. The goal was to review current knowledge--and knowledge gaps--relating to a global environmental health problem, mercury

Shepherd, Simon

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Methods for dispensing mercury into devices  

DOE Patents [OSTI]

A process is described for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg[sub 2]Cl[sub 2] and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury. 2 figs.

Grossman, M.W.; George, W.A.

1987-04-28T23:59:59.000Z

82

Mercury Spill Information and Response Guidance  

E-Print Network [OSTI]

Mercury Spill Information and Response Guidance Background Information Mercury can be found, plumbing traps and vacuum pumps. When mercury is spilled, it forms beads or droplets that can accumulate mercury vapors can be very dangerous, depending on the amount inhaled and the length of exposure

Holland, Jeffrey

83

Mercury Isotope Fractionation by Environmental Transport and Transformation Processes  

E-Print Network [OSTI]

measurements of atomic mercury. Applied Physics B, 87(2),M. & Covelli, S. , 2000. Mercury speciation in sedimentsarea of the Idrija mercury mine, Slovenia. Environmental

Koster van Groos, Paul Gijsbert

2011-01-01T23:59:59.000Z

84

Fluorescent sensor for mercury  

DOE Patents [OSTI]

The present invention provides a sensor for detecting mercury, comprising: a first polynucleotide, comprising a first region, and a second region, a second polynucleotide, a third polynucleotide, a fluorophore, and a quencher, wherein the third polynucleotide is optionally linked to the second region; the fluorophore is linked to the first polynucleotide and the quencher is linked to the second polynucleotide, or the fluorophore is linked to the second polynucleotide and the quencher is linked to the first polynucleotide; the first region and the second region hybridize to the second polynucleotide; and the second region binds to the third polynucleotide in the presence of Hg.sup.2+ ions.

Wang, Zidong (Urbana, IL); Lee, Jung Heon (Evanston, IL); Lu, Yi (Champaign, IL)

2011-11-22T23:59:59.000Z

85

Achieving very low mercury levels in refinery wastewater by membrane filtration.  

SciTech Connect (OSTI)

Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W. (Center for Nanoscale Materials); ( ES)

2012-05-15T23:59:59.000Z

86

Mercury's moment of inertia from spin and gravity data  

E-Print Network [OSTI]

2006), Evolution of Mercurys obliquity, Icarus, 181, 327longitude librations of Mercury, Icarus, 207, 11 of 11The free librations of Mercury and the size of its inner

2012-01-01T23:59:59.000Z

87

Mercury in the Anthropocene Ocean  

E-Print Network [OSTI]

The toxic metal mercury is present only at trace levels in the ocean, but it accumulates in fish at concentrations high enough to pose a threat to human and environmental health. Human activity has dramatically altered the ...

Lamborg, Carl

88

In situ mercury stabilization  

SciTech Connect (OSTI)

BNL Royalty Project Internal Status Report. The funds from the allotment of royalty income were used to experimentally explore feasibility of related, potential new techniques based on the Environmental Sciences Department successful technology licensed for the ex situ treatment of mercury. Specifically, this work is exploring the concept of using Sulfur Polymer Cement (SPC) in an in situ application to stabilize and/or remove mercury (Hg) from surficial soil. Patent disclosure forms have been filed for this process. Soil was artificially spiked with 500 ppm Hg and a series of experiments were set up in which SPC rods were placed in the center of a mass of this soil. Some experiments were conducted at 20 C and others at 50 C. After times ranging from 11 to 24 days, these experiments were opened, photographed and the soil was sampled from discrete locations in the containers. The soil and SPC samples were analyzed for Fe and Hg by x-ray fluorescence. The Hg profile in the soil was significantly altered, with concentrations along the outer edge of the soil reduced by as much as 80% from the starting concentration. Conversely, closer to the treatment rod containing SPC, concentrations of Hg were significantly increased over the original concentration. Preliminary results for elevated temperature sample are shown graphically in Figure 2. Apparently the Hg had migrated toward the SPC and reacted with sulfur to form Hg S. This appears to be a reaction between gaseous phases of both S and Hg, with Hg having a greater vapor pressure. The concentration of low solubility HgS (i.e., low leaching properties) developed within 11 days at 50 C and 21 days at 20 C, confirming the potential of this concept.

Fuhrmann, M.; Kalb, P.; Adams, J.

2004-09-01T23:59:59.000Z

89

IntroductionIntroduction Mercury: Monitoring Patients with ParkinsonMercury: Monitoring Patients with Parkinson''s Diseases Disease  

E-Print Network [OSTI]

IntroductionIntroduction Mercury: Monitoring Patients with ParkinsonMercury: Monitoring Patients's Disease EvaluationEvaluation Mercury ArchitectureMercury Architecture Mercury is a wireless sensor network and disconnections Node Behavior Hardware PlatformHardware Platform Usage Scenario InternetInternet http://fiji.eecs.harvard.edu/Mercury

Chen, Yiling

90

Longitudinal discharge laser electrodes  

DOE Patents [OSTI]

The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window. 2 figs.

Warner, B.E.; Miller, J.L.; Ault, E.R.

1994-08-23T23:59:59.000Z

91

Mercury-Mercury Tunneling Junctions. 1. Electron Tunneling Across Symmetric and Asymmetric Alkanethiolate Bilayers  

E-Print Network [OSTI]

Mercury-Mercury Tunneling Junctions. 1. Electron Tunneling Across Symmetric and Asymmetric by bringing in contact two small (3 ? 10-3 cm2) mercury drop electrodes in a 5-20% (v/v) hexadecane solution incorporating alkanethiolate-type monolayer films. The results reported below convince us that the mercury

Majda, Marcin

92

Mercury switch with non-wettable electrodes  

DOE Patents [OSTI]

A mercury switch device comprising a pool of mercury and a plurality of electrical contacts made of or coated with a non-wettable material such as titanium diboride.

Karnowsky, Maurice M. (Albulquerque, NM); Yost, Frederick G. (Carlsbad, NM)

1987-01-01T23:59:59.000Z

93

Method for the removal and recovery of mercury  

DOE Patents [OSTI]

The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

Easterly, C.E.; Vass, A.A.; Tyndall, R.L.

1997-01-28T23:59:59.000Z

94

Method for the removal and recovery of mercury  

DOE Patents [OSTI]

The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

Easterly, Clay E. (Knoxville, TN); Vass, Arpad A. (Oak Ridge, TN); Tyndall, Richard L. (Clinton, TN)

1997-01-01T23:59:59.000Z

95

Mercury bioaccumulation in Lavaca Bay, Texas  

E-Print Network [OSTI]

(waves), and human activities (dredging and shrimping) can potentially release mercury to the overlying water (LINDBERG and HARRISS, 1977; CRANSTON, 1976). The solubility, reactivity, and toxicity of mercury is dependent on its form. Divalent mercury... MERCURY BIOACCUMULATION IN LAVACA BAY, TEXAS A Thesis by SALLY JO PALMER Submitted to the Office of Graduate Studies of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1992 Major...

Palmer, Sally Jo

1992-01-01T23:59:59.000Z

96

2003 Mercury Computer Systems, Inc. Data Reorganization  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Data Reorganization Interface (DRI) Data Reorganization Interface (DRI) Kenneth Cain Jr. Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC Mercury Computer Systems, Inc. Status update for the DRI-1.0 standard since Sep. 2002 publication Outline

Kepner, Jeremy

97

3, 35253541, 2003 Modelling of Mercury  

E-Print Network [OSTI]

ACPD 3, 3525­3541, 2003 Modelling of Mercury with the Danish Eulerian Hemispheric Model J. H and Physics Discussions Modelling of mercury with the Danish Eulerian Hemispheric Model J. H. Christensen, J Correspondence to: J. H. Christensen (jc@dmu.dk) 3525 #12;ACPD 3, 3525­3541, 2003 Modelling of Mercury

Paris-Sud XI, Université de

98

Constraining Mercury Oxidation Using Wet Deposition  

E-Print Network [OSTI]

Constraining Mercury Oxidation Using Wet Deposition Noelle E. Selin and Christopher D. Holmes mercury oxidation [Selin & Jacob, Atmos. Env. 2008] 30 60 90 120 150 30 60 90 120 150 30 60 90 120 150 30 Influences on Mercury Wet Deposition · Hg wet dep = f(precipitation, [Hg(II)+Hg(P)]) Correlation (r2) between

Selin, Noelle Eckley

99

Atmospheric Chemistry, Modeling, and Biogeochemistry of Mercury  

E-Print Network [OSTI]

Atmospheric Chemistry, Modeling, and Biogeochemistry of Mercury Noelle Eckley Selin *Reprinted from Mercury in the Environment: Pattern and Process (Chapter 5) pp. 73-80 Copyright © 2012 with kind, and Biogeochemistry of Mercury NOELLE ECKLEY SELIN and their distribution in the atmosphere. This includes

100

Mercury: Recovering Forgotten Passwords Using Personal Devices  

E-Print Network [OSTI]

Mercury: Recovering Forgotten Passwords Using Personal Devices Mohammad Mannan1 , David Barrera2, and to allow forgotten passwords to be securely restored, we present a scheme called Mercury. Its primary mode and revealed to the user. A prototype implementation of Mercury is available as an Android application. 1

Van Oorschot, Paul

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

2003 Mercury Computer Systems, Inc. Delivered Performance  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Delivered Performance Predictions and Trends for RISC Applications Luke Cico (lcico@mc.com) Mark Merritt (mmerritt@mc.com) Mercury Computer Systems, Inc. Chelmsford, MA 01824 #12;© 2003 Mercury Computer Systems, Inc. Goals of PresentationGoals of Presentation

Kepner, Jeremy

102

REPLACE YOUR MERCURY THERMOMETERS BEFORE THEY BREAK!  

E-Print Network [OSTI]

REPLACE YOUR MERCURY THERMOMETERS BEFORE THEY BREAK! Did you know, mercury from broken thermometers to the local environment, if broken thermometers in sinks eventually end at the sanitary sewer plant. Broken mercury thermometers create hazardous waste that is costly to clean up and costly to dispose of. Other

103

Mercury Continuous Emmission Monitor Calibration  

SciTech Connect (OSTI)

Mercury continuous emissions monitoring systems (CEMs) are being implemented in over 800 coal-fired power plant stacks throughput the U.S. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor calibrators/generators. These devices are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 and vacated by a Federal appeals court in early 2008 required that calibration be performed with NIST-traceable standards. Despite the vacature, mercury emissions regulations in the future will require NIST traceable calibration standards, and EPA does not want to interrupt the effort towards developing NIST traceability protocols. The traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued a conceptual interim traceability protocol for elemental mercury calibrators. The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The EPA traceability protocol document is divided into two separate sections. The first deals with the qualification of calibrator models by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the calibrators that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma/mass spectrometry (ID/ICP/MS) performed by NIST in Gaithersburg, MD. The outputs of mercury calibrators are compared to one another using a nesting procedure which allows direct comparison of one calibrator with another at specific concentrations and eliminates analyzer variability effects. The qualification portion of the EPA interim traceability protocol requires the vendors to define calibrator performance as affected by variables such as pressure, temperature, line voltage, and shipping. In 2007 WRI developed and conducted a series of simplified qualification experiments to determine actual calibrator performance related to the variables defined in the qualification portion of the interim protocol.

John Schabron; Eric Kalberer; Ryan Boysen; William Schuster; Joseph Rovani

2009-03-12T23:59:59.000Z

104

Glow discharge detector  

DOE Patents [OSTI]

A highly sensitive electronic ion cell for the measurement of trace elements in He carrier gas which involves glow discharge. A constant wave (CW) glow discharge detector which is controlled through a biased resistor, can detect the change of electron density caused by impurities in the He carrier gas by many orders of magnitude larger than that caused by direct ionization or electron capture. The glow discharge detector utilizes a floating pseudo-electrode to form a probe in or near the plasma. By using this probe, the large variation of electron density due to trace amounts of impurities can be directly measured.

Koo, Jackson C. (San Ramon, CA); Yu, Conrad M. (Antioch, CA)

2002-01-01T23:59:59.000Z

105

Capacitor discharge pulse analysis.  

SciTech Connect (OSTI)

Capacitors used in firing sets and other high discharge current applications are discharge tested to verify performance of the capacitor against the application requirements. Parameters such as capacitance, inductance, rise time, pulse width, peak current and current reversal must be verified to ensure that the capacitor will meet the application needs. This report summarizes an analysis performed on the discharge current data to extract these parameters by fitting a second-order system model to the discharge data and using this fit to determine the resulting performance metrics. Details of the theory and implementation are presented. Using the best-fit second-order system model to extract these metrics results in less sensitivity to noise in the measured data and allows for direct extraction of the total series resistance, inductance, and capacitance.

Baker, Michael Sean; Griffiths, Stewart K.; Tanner, Danelle Mary

2013-08-01T23:59:59.000Z

106

Remediation of Mercury-Contaminated Storm Sewer Sediments from the West End Mercury Area at the Y-12 National Security Complex in Oak Ridge, Tennessee - 12061  

SciTech Connect (OSTI)

The Y-12 National Security Complex in Oak Ridge, TN has faced an ongoing challenge from mercury entrapped in soils beneath and adjacent to buildings, storm sewers, and process pipelines. Previous actions to reduce the quantity and/or mobilization of mercury-contaminated media have included plugging of building floor drains, cleaning of sediment and sludge from sumps, manholes, drain lines, and storm sewers, lining/relining of storm sewers and replacement of a portion of the storm sewer trunk line, re-routing and removal of process piping, and installation of the Central Mercury Treatment System to capture and treat contaminated sump water. Despite the success of these actions, mercury flux in the storm sewer out-falls that discharge to Upper East Fork Poplar Creek (UEFPC) continues to pose a threat to long-term water quality. A video camera survey of the storm sewer network revealed several sections of storm sewer that had large cracks, separations, swells, and accumulations of sediment/sludge and debris. The selected remedy was to clean and line the sections of storm sewer pipe that were determined to be primary contributors to the mercury flux in the storm sewer out-falls. The project, referred to as the West End Mercury Area (WEMA) Storm Sewer Remediation Project, included cleaning sediment and debris from over 2,460 meters of storm sewer pipe followed by the installation of nearly 366 meters of cure-in-place pipe (CIPP) liner. One of the greatest challenges to the success of this project was the high cost of disposal associated with the mercury-contaminated sludge and wastewater generated from the storm sewer cleaning process. A contractor designed and operated an on-site wastewater pre-treatment system that successfully reduced mercury levels in 191 cubic meters of sludge to levels that allowed it to be disposed at Nevada Nuclear Security Site (NNSS) disposal cell as a non-hazardous, low-level waste. The system was also effective at pre-treating over 1,514,000 liters of wastewater to levels that met the waste acceptance criteria for the on-site West End [wastewater] Treatment Facility (WETF). This paper describes the storm sewer cleaning and lining process and the methods used to process the mercury-contaminated sludge and wastewater, as well as several 'lessons learned' that would be relevant to any future projects involving storm sewer cleaning and debris remediation. (authors)

Tremaine, Diana [Science and Ecology Corporation, Knoxville, Tennessee, 37931 (United States); Douglas, Steven G. [B and W Y-12, Oak Ridge, Tennessee, 37831 (United States)

2012-07-01T23:59:59.000Z

107

Apparatus for control of mercury  

DOE Patents [OSTI]

A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH)

2001-01-01T23:59:59.000Z

108

All mercury lamps contain small amounts of mercury. An electric current passes through the lamp and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our environment from heavy  

E-Print Network [OSTI]

All mercury lamps contain small amounts of mercury. An electric current passes through the lamp and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our the environment by recycling universal wastes, contact EH&S at (949) 824-6200 or visit: www.ehs.uci.edu Mercury

George, Steven C.

109

An assessment of methyl mercury and volatile mercury in land-applied sewage sludge  

SciTech Connect (OSTI)

In 1993, the US Environmental Protection Agency issued regulations covering the land-application of municipal sewage sludge. These regulations established maximum pollutant concentrations and were based upon a risk assessment of human exposure. Mercury, assumed to be inorganic and non-volatile, was one pollutant evaluated. From April, 1995 through February, 1996, the authors studied the species of mercury contaminating municipal sludge applied to land, and the potential for volatilization of mercury from land-applied sludge. Methyl mercury was found at 0.1% of total mercury concentrations and was emitted from land-applied sludge to the atmosphere. Elemental mercury (Hg) was formed in land-applied sludge via the reduction of oxidized mercury and was also emitted to the atmosphere. Hg emission from land-applied sludge was significantly elevated over background soil emission. Methyl mercury is more toxic and more highly bioaccumulated than inorganic mercury, and warrants assessment considering these special criteria. Additionally, mercury emission from sludge-amended soil may lead to the contamination of other environmental media with significant concentrations of the metal. Although these pathways were not evaluated in the regulatory risk assessment, they are an important consideration for evaluating the risks from mercury in land-applied sludge. This presentation will summarize the results of a re-assessment of US EPA regulations regarding the land-application of municipal sewage sludge using data on methyl mercury toxicity and mercury transport in the atmosphere.

Carpi, A. [Cornell Univ., Ithaca, NY (United States); Lindberg, S.E. [Oak Ridge National Lab., TN (United States)

1995-12-31T23:59:59.000Z

110

A Mercury orientation model including non-zero obliquity and librations  

E-Print Network [OSTI]

Long-period forcing of Mercurys libration in longitude.M. : Resonant forcing of Mercurys libration in longitude.A revised control network for Mercury. J. Geophys. Res. 104,

Margot, Jean-Luc

2009-01-01T23:59:59.000Z

111

Mercury emissions from municipal solid waste combustors  

SciTech Connect (OSTI)

This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

Not Available

1993-05-01T23:59:59.000Z

112

Atmospheric Mercury Deposition during the Last 270 Years: A  

E-Print Network [OSTI]

Atmospheric Mercury Deposition during the Last 270 Years: A Glacial Ice Core Record of Natural, and U.S. Geological Survey, Wisconsin District Mercury Research Laboratory, Middleton, Wisconsin 53562 Mercury (Hg) contamination of aquatic ecosystems and subsequent methylmercury bioaccumulation

113

Mercury-Contaminated Hydraulic Mining Debris in San Francisco Bay  

E-Print Network [OSTI]

S, and Flegal AR 2008. Mercury in the San Francisco Estuary.may 2010 Mercury-Contaminated Hydraulic Mining Debris in Sancontaminants such as ele- mental mercury and cyanide used in

Bouse, Robin M; Fuller, Christopher C; Luoma, Sam; Hornberger, Michelle I; Jaffe, Bruce E; Smith, Richard E

2010-01-01T23:59:59.000Z

114

Control of mercury methylation in wetlands through iron addition  

E-Print Network [OSTI]

Mason, R. P. ; Flegal, A. R. , Mercury speciation in the SanP. ; Flegal, A. R. , Decadal mercury trends in San FranciscoP. G. ; Nelson, D. C. , Mercury methylation from unexpected

Sedlak, David L; Ulrich, Patrick D

2009-01-01T23:59:59.000Z

115

Longitudinal discharge laser baffles  

DOE Patents [OSTI]

The IR baffles placed between the window and the electrode of a longitudinal discharge laser improve laser performance by intercepting off-axis IR radiation from the laser and in doing so reduce window heating and subsequent optical distortion of the laser beam. 1 fig.

Warner, B.E.; Ault, E.R.

1994-06-07T23:59:59.000Z

116

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

117

Amended Silicated for Mercury Control  

SciTech Connect (OSTI)

Amended Silicates{trademark}, a powdered, noncarbon mercury-control sorbent, was tested at Duke Energy's Miami Fort Station, Unit 6 during the first quarter of 2006. Unit 6 is a 175-MW boiler with a cold-side electrostatic precipitator (ESP). The plant burns run-of-the-river eastern bituminous coal with typical ash contents ranging from 8-15% and sulfur contents from 1.6-2.6% on an as-received basis. The performance of the Amended Silicates sorbent was compared with that for powdered activated carbon (PAC). The trial began with a period of baseline monitoring during which no sorbent was injected. Sampling during this and subsequent periods indicated mercury capture by the native fly ash was less than 10%. After the baseline period, Amended Silicates sorbent was injected at several different ratios, followed by a 30-day trial at a fixed injection ratio of 5-6 lb/MMACF. After this period, PAC was injected to provide a comparison. Approximately 40% mercury control was achieved for both the Amended Silicates sorbent and PAC at injection ratios of 5-6 lbs/MMACF. Higher injection ratios did not achieve significantly increased removal. Similar removal efficiencies have been reported for PAC injection trials at other plants with cold-side ESPs, most notably for plants using medium to high sulfur coal. Sorbent injection did not detrimentally impact plant operations and testing confirmed that the use of Amended Silicates sorbent does not degrade fly ash quality (unlike PAC). The cost for mercury control using either PAC or Amended Silicates sorbent was estimated to be equivalent if fly ash sales are not a consideration. However, if the plant did sell fly ash, the effective cost for mercury control could more than double if those sales were no longer possible, due to lost by-product sales and additional cost for waste disposal. Accordingly, the use of Amended Silicates sorbent could reduce the overall cost of mercury control by 50% or more versus PAC for locations where fly ash is sold as a by-product.

James Butz; Thomas Broderick; Craig Turchi

2006-12-31T23:59:59.000Z

118

Remediation of Mercury and Industrial Contaminants Applied Field...  

Office of Environmental Management (EM)

Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research...

119

Mercury/Waterfilling: Optimum Power Allocation with Arbitrary Input Constellations  

E-Print Network [OSTI]

Mercury/Waterfilling: Optimum Power Allocation with Arbitrary Input Constellations Angel Lozano gives the power allocation policy, referred to as mercury/waterfilling, that maximizes the sum mutual

Verdú, Sergio

120

Process for removing mercury from aqueous solutions  

DOE Patents [OSTI]

A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

Googin, J.M.; Napier, J.M.; Makarewicz, M.A.; Meredith, P.F.

1985-03-04T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Process for removing mercury from aqueous solutions  

DOE Patents [OSTI]

A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Makarewicz, Mark A. (Knoxville, TN); Meredith, Paul F. (Knoxville, TN)

1986-01-01T23:59:59.000Z

122

Mercury Geochemical, Groundwater Geochemical, And Radiometric...  

Open Energy Info (EERE)

Prospects In Northern Nevada Abstract Ground water sampling, desorbed mercury soil geochemical surveys and a radiometric geophysical survey was conducted in conjunction...

123

Alkaline sorbent injection for mercury control  

DOE Patents [OSTI]

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2003-01-01T23:59:59.000Z

124

Alkaline sorbent injection for mercury control  

DOE Patents [OSTI]

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2002-01-01T23:59:59.000Z

125

Mercury Sensing with Optically Responsive Gold Nanoparticles  

E-Print Network [OSTI]

1.1.5 Mercury detection Atomic absorption 19 and atomicsacrifices in simplicity. Atomic absorption or fluorescencedown to low nanogram masses. Atomic absorption/fluorescence

James, Jay Zachary

2012-01-01T23:59:59.000Z

126

Mercury concentrations in Maine sport fishes  

SciTech Connect (OSTI)

To assess mercury contamination of fish in Maine, fish were collected from 120 randomly selected lakes. The collection goal for each lake was five fish of the single most common sport fish species within the size range commonly harvested by anglers. Skinless, boneless fillets of fish from each lake were composited, homogenized, and analyzed for total mercury. The two most abundant species, brook trout Salvelinus fontinalis and smallmouth bass Micropterus dolomieu, were also analyzed individually. The composite fish analyses indicate high concentrations of mercury, particularly in large and long-lived nonsalmonid species. Chain pickerel Esox niger, smallmouth bass, largemouth bass Micropterus salmoides, and white perch Morone americana had the highest average mercury concentrations, and brook trout and yellow perch Perca flavescens had the lowest. The mean species composite mercury concentration was positively correlated with a factor incorporating the average size and age of the fish. Lakes containing fish with high mercury concentrations were not clustered near known industrial or population centers but were commonest in the area within 150 km of the seacoast, reflecting the geographical distribution of species that contained higher mercury concentrations. Stocked and wild brook trout were not different in length or weight, but wild fish were older and had higher mercury concentrations. Fish populations maintained by frequent introductions of hatchery-produced fish and subject to high angler exploitation rates may consist of younger fish with lower exposure to environmental mercury and thus contain lower concentrations than wild populations.

Stafford, C.P. [Univ. of Maine, Orono, ME (United States)] [Univ. of Maine, Orono, ME (United States); Haines, T.A. [Geological Survey, Orono, ME (United States)] [Geological Survey, Orono, ME (United States)

1997-01-01T23:59:59.000Z

127

A SPICE Compatible Model of High Intensity Discharge Lamps  

E-Print Network [OSTI]

from the arc's * Corresponding author behavior of HID lamps. This model are derived from the arc-linear resistance of the lamp, is the global specific conductance of the plasma, V is the volume of the plasma, L is the length of plasma and S is the cross section. ~ Vin G1 Lamp Model Ballast v(lamp) i(lamp) Analytical

128

Water Pollutant Discharge Act (Illinois)  

Broader source: Energy.gov [DOE]

The discharge of oil in quantities which exceed the standards adopted by the Pollution Control Board, or the discharge of other pollutants directly or indirectly into the waters is prohibited....

129

Powerful glow discharge excilamp  

DOE Patents [OSTI]

A powerful glow discharge lamp comprising two coaxial tubes, the outer tube being optically transparent, with a cathode and anode placed at opposite ends of the tubes, the space between the tubes being filled with working gas. The electrodes are made as cylindrical tumblers placed in line to one other in such a way that one end of the cathode is inserted into the inner tube, one end of the anode coaxially covers the end of the outer tube, the inner tube penetrating and extending through the anode. The increased electrodes' surface area increases glow discharge electron current and, correspondingly, average radiation power of discharge plasma. The inner tube contains at least one cooling liquid tube placed along the axis of the inner tube along the entire lamp length to provide cathode cooling. The anode has a circumferential heat extracting radiator which removes heat from the anode. The invention is related to lighting engineering and can be applied for realization of photostimulated processes under the action of powerful radiation in required spectral range.

Tarasenko, Victor F. (Tomsk, RU); Panchenko, Aleksey N. (Tomsk, RU); Skakun, Victor S. (Tomsk, RU); Sosnin, Edward A. (Tomsk, RU); Wang, Francis T. (Danville, CA); Myers, Booth R. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

2002-01-01T23:59:59.000Z

130

Mercury Chamber NF-IDS Meeting  

E-Print Network [OSTI]

-Battelle for the U.S. Department of Energy Mercury Chamber Update Oct 2011 Starting Point: Coil and Shielding Concept IDS120H #12;3 Managed by UT-Battelle for the U.S. Department of Energy Mercury Chamber Update Oct 2011 · Penetrations (ports) into chamber ­ Nozzle ­ Hg drains (overflow and maintenance) ­ Vents (in and out) ­ Beam

McDonald, Kirk

131

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER  

E-Print Network [OSTI]

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER Van Graves , ORNL, Oak Ridge, TN 37830 Factory is a free-stream mercury jet within a 20-T magnetic field being impacted by an 8-GeV proton beam. A pool of mercury serves as a receiving reservoir for the mercury and a dump for the unexpended proton

McDonald, Kirk

132

Thursday, March 15, 2007 POSTER SESSION II: MERCURY  

E-Print Network [OSTI]

Thursday, March 15, 2007 POSTER SESSION II: MERCURY 6:30 p.m. Fitness Center Dombard A. J. Hauck S. A. II Despinning Plus Global Contraction and the Orientation of Lobate Scarps on Mercury [#2026] We thermal models of Mercury. King S. D. A Possible Connection Between Convection in Mercury's Mantle

Rathbun, Julie A.

133

2003 Mercury Computer Systems, Inc. Optimizing System Compute  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Optimizing System Compute Density for Deployed HPEC Electronics Engineering Mercury Computer Systems, Inc. rbanton@mc.com Richard Jaenicke, Director, Product Marketing Mercury Computer Systems, Inc. rjaenicke@mc.com #12;2 © 2002 Mercury Computer Systems, Inc.© 2003

Kepner, Jeremy

134

Laser Altimeter Observations from MESSENGER's First Mercury Flyby  

E-Print Network [OSTI]

REPORT Laser Altimeter Observations from MESSENGER's First Mercury Flyby Maria T. Zuber,1 * David E Barnouin-Jha,8 John K. Harmon10 A 3200-kilometers-long profile of Mercury by the Mercury Laser Altimeter compensated. Sampled craters on Mercury are shallower than their counterparts on the Moon, at least in part

Hauck II, Steven A.

135

Mercury capture by aerosol transformation in combustion environments. Appendix 5  

SciTech Connect (OSTI)

Aerosol transformation of elemental mercury by oxidizing mercury in the air is investigated in this study by varying temperature and residence time. The experimental results show that mercury oxidation is not important at the temperature range and time scale studied. The rate of mercury oxidation is too slow that the capture of mercury vapor by transforming it into mercury oxide in aerosol phase is not practical in real systems. Studies are needed for alternative approaches to capture mercury vapor such as the use of sorbent materials.

NONE

1997-02-01T23:59:59.000Z

136

Figure 2: The mercury jet target geometry. The proton beam and mercury jet cross at z=-37.5 cm.  

E-Print Network [OSTI]

Figure 2: The mercury jet target geometry. The proton beam and mercury jet cross at z=-37.5 cm. Figure 3: The layout of multiple proton beam entry directions relative to mercury jet at z=-75 cm. A PION of a free liquid mercury jet with an intense proton beam. We study the variation of meson production

McDonald, Kirk

137

Large discharge-volume, silent discharge spark plug  

DOE Patents [OSTI]

A large discharge-volume spark plug for providing self-limiting microdischarges. The apparatus includes a generally spark plug-shaped arrangement of a pair of electrodes, where either of the two coaxial electrodes is substantially shielded by a dielectric barrier from a direct discharge from the other electrode, the unshielded electrode and the dielectric barrier forming an annular volume in which self-terminating microdischarges occur when alternating high voltage is applied to the center electrode. The large area over which the discharges occur, and the large number of possible discharges within the period of an engine cycle, make the present silent discharge plasma spark plug suitable for use as an ignition source for engines. In the situation, where a single discharge is effective in causing ignition of the combustible gases, a conventional single-polarity, single-pulse, spark plug voltage supply may be used.

Kang, Michael (Los Alamos, NM)

1995-01-01T23:59:59.000Z

138

Treatment of mercury containing waste  

DOE Patents [OSTI]

A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

Kalb, Paul D. (Wading River, NY); Melamed, Dan (Gaithersburg, MD); Patel, Bhavesh R (Elmhurst, NY); Fuhrmann, Mark (Babylon, NY)

2002-01-01T23:59:59.000Z

139

DFJ Mercury | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentratingRenewable Solutions LLC JumpCrow Lake Wind JumpCuttings AnalysisDCDFJ Mercury Jump to:

140

Development of an electromagnetically actuated mercury microvalve  

SciTech Connect (OSTI)

The development of microscale fluid handling components has been recognized as a crucial element in the design of microscale chemical detection systems. Recently, work has been undertaken at Sandia National Laboratories to construct a valve that uses a small mercury droplet to control the flow of gas through capillary passages. Electromagnetic forces that are provided by small permanent magnets and a current supply are used to drive the mercury into position. Driving the mercury droplet into a tapered passage halts gas flow through a capillary, while surface tension forces prevent the mercury from passing through the passage. Models have been developed to describe the movement of the mercury droplet and the sealing of the gas passage, and millimeter-scale units have been tested to explore design options. Predictions from the model show that a valve with 10 micron sized features can seal against pressures up to 1.5 atmospheres. Experiments have highlighted the promise of mercury valves and demonstrated problems that can arise from contamination of the mercury.

Adkins, D.R.; Wong, C.C.

1998-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Fish mercury distribution in Massachusetts, USA lakes  

SciTech Connect (OSTI)

The sediment, water, and three species of fish from 24 of Massachusetts' (relatively) least-impacted water bodies were sampled to determine the patterns of variation in edible tissue mercury concentrations and the relationships of these patterns to characteristics of the water, sediment, and water bodies (lake, wetland, and watershed areas). Sampling was apportioned among three different ecological subregions and among lakes of differing trophic status. The authors sought to partition the variance to discover if these broadly defined concepts are suitable predictors of mercury levels in fish. Average muscle mercury concentrations were 0.15 mg/kg wet weight in the bottom-feeding brown bullheads (Ameriurus nebulosus); 0.31 mg/kg in the omnivorous yellow perch (Perca flavescens); and 0.39 mg/kg in the predaceous largemouth bass (Micropterus salmoides). Statistically significant differences in fish mercury concentrations between ecological subregions in Massachusetts, USA, existed only in yellow perch. The productivity level of the lakes (as deduced from Carlson's Trophic Status Index) was not a strong predictor of tissue mercury concentrations in any species. pH was a highly (inversely) correlated environmental variable with yellow perch and brown bullhead tissue mercury. Largemouth bass tissue mercury concentrations were most highly correlated with the weight of the fish (+), lake size (+), and source area sizes (+). Properties of individual lakes appear more important for determining fish tissue mercury concentrations than do small-scale ecoregional differences. Species that show major mercury variation with size or trophic level may not be good choices for use in evaluating the importance of environmental variables.

Rose, J.; Hutcheson, M.S.; West, C.R.; Pancorbo, O.; Hulme, K.; Cooperman, A.; DeCesare, G.; Isaac, R.; Screpetis, A.

1999-07-01T23:59:59.000Z

142

Advances in Lighting  

E-Print Network [OSTI]

colour rendition. The quartz-halogen incandescent lam s operate at higher temperatures, and have a somewhat higher efficacy, but they are rarely used except for special applicati ns. 3-2 High Intensity Discharge Lamps. Mercury is the grandfather... of the H.I.D. lamps. Its blue-green light, has been used almost exclusively for streetlighti and, often with colour-improving phospho it is still being used in industrial and commercial applications. Reactor-type ballasted mercury lamps can now...

Tumber, A. J.

1981-01-01T23:59:59.000Z

143

Evaluating Mercury Concentrations in Midwest Fish in Relationship to Mercury Emission Sources  

E-Print Network [OSTI]

International Energy Outlook estimates that world usage of coal will grow from 132 quadrillion British Thermal Units (BTU) in 2008 to over 202 quadrillion BTU in 2030 (USDOE, 2008). Even with improved mercury controls on power plants, this increase..., it is worthwhile to further examine the relationships between local sources of mercury and elevated concentrations of mercury in fish since these relationships may better inform control strategies, siting concerns, and overall energy policies. The author...

Robichaud, Jeffery

2008-12-19T23:59:59.000Z

144

Phytoremediation of Ionic and Methyl Mercury P  

SciTech Connect (OSTI)

Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB (organomercury lyase) extract methylmercury from their growth substrate and degrade it to less toxic ionic mercury. They grow on concentrations of methylmercury that kill normal plants and accumulate low levels of ionic mercury. (2) Transgenic plants expressing merA (mercuric ion reductase) extract and electrochemically reduce toxic, reactive ionic mercury to much less toxic and volatile metallic mercury. This metal transformation is driven by the powerful photosynthetic reducing capacity of higher plants that generates excess NADPH using solar energy. MerA plants grow vigorously on levels of ionic mercury that kill control plants. Plants expressing both merB and merA degrade high levels of methylmercury and volatilize metallic mercury. These properties were shown to be genetically stable for several generations in the two plant species examined. Our work demonstrates that native trees, shrubs, and grasses can be engineered to remediate the most abundant toxic mercury pollutants. Building on these data our working hypothesis for the next grant period is that transgenic plants expressing the bacterial merB and merA genes will (a) remove mercury from polluted soil and water and (b) prevent methylmercury from entering the food chain. Our specific aims center on understanding the mechanisms by which plants process the various forms of mercury and volatilize or transpire mercury vapor. This information will allow us to improve the design of our current phytoremediation strategies. As an alternative to volatilizing mercury, we are using several new genes to construct plants that will hyperaccumulate mercury in above-ground tissues for later harvest. The Department of Energy's Oak Ridge National Laboratory and Brookhaven National Laboratory have sites with significant levels of mercury contamination that could be cleaned by applying the scientific discoveries and new phytoremediation technologies described in this proposal. The knowledge and expertise gained by engineering plants to hyperaccumulate mercury can be applied to the remediation of other heavy metals pollutants (e.g., arsenic, cesium, cadmium, chromium, lead, strontium, technetium, uranium) found at several DOE facilities.

Meagher, Richard B.

1999-06-01T23:59:59.000Z

145

Determination of the spatial characteristics of an RF electrodeless discharge by the method of emission tomography  

SciTech Connect (OSTI)

The spatial distribution of the density of mercury atoms in the 7{sup 3}S state in a spherical RF electrode-less gas-discharge lamp is reconstructed by the method of emission tomography. The local values of the corresponding emission coefficients, which are proportional to the density of mercury atoms in the 7{sup 3}S state, are determined from integral (over the plasma volume) measurements of the lamp radiation at a wavelength of 546.1 nm with the help of an algorithm based on the maximum entropy method. The results obtained show that, for all of the operating modes under study, the profile of the density of mercury atoms in the 7{sup 3}S state has a minimum in the center of the lamp and a maximum near its wall. At a generator current of 100 mA and cold-spot temperature of 41 deg. C, the density of mercury atoms in the 7{sup 3}S state is observed to drop substantially both in the center of the lamp and near its wall, the density in the center being reduced to almost zero. An explanation of this phenomenon is proposed.

Denisova, N. V. [Russian Academy of Sciences, Institute of Theoretical and Applied Mechanics, Siberian Division (Russian Federation); Revalde, G.; Skudra, A. [University of Latvia, Institute of Atomic physics and Spectroscopy (Latvia)

2006-11-15T23:59:59.000Z

146

10.1177/0270467603259787ARTICLEBULLETIN OF SCIENCE, TECHNOLOGY & SOCIETY / October 2003Roe / FISHING FOR IDENTITY Fishing for Identity: Mercury Contamination  

E-Print Network [OSTI]

of mercury in the United States. During 1999, total mercury emis- sions from power plant emissions exceeded (HG0 ), inorganic mercury (HG2+ ), and methyl mercury (MeHg), methyl mercury poses the greatest threat

Delaware, University of

147

Interim Results from a Study of the Impacts of Tin (II) Based Mercury Treatment in a Small Stream Ecosystem: Tims Branch, Savannah River Site  

SciTech Connect (OSTI)

A research team is assessing the impacts of an innovative mercury treatment system in Tims Branch, a small southeastern stream. The treatment system, installed in 2007, reduces and removes inorganic mercury from water using tin(II) (stannous) chloride addition followed by air stripping. The system results in discharge of inorganic tin to the ecosystem. This screening study is based on historical information combined with measurements of contaminant concentrations in water, fish, sediment, biofilms and invertebrates. Initial mercury data indicate that first few years of mercury treatment resulted in a significant decrease in mercury concentration in an upper trophic level fish, redfin pickerel, at all sampling locations in the impacted reach. For example, the whole body mercury concentration in redfin pickerel collected from the most impacted pond decreased approximately 72% between 2006 (pre-treatment) and 2010 (post-treatment). Over this same period, mercury concentrations in the fillet of redfin pickerel in this pond were estimated to have decreased from approximately 1.45 {micro}g/g (wet weight basis) to 0.45 {micro}g/g - a decrease from 4.8x to 1.5x the current EPA guideline concentration for mercury in fillet (0.3 {micro}g/g). Thermodynamic modeling, scanning electron microscopy, and other sampling data for tin suggest that particulate tin (IV) oxides are a significant geochemical species entering the ecosystem with elevated levels of tin measured in surficial sediments and biofilms. Detectable increases in tin in sediments and biofilms extended approximately 3km from the discharge location. Tin oxides are recalcitrant solids that are relatively non-toxic and resistant to dissolution. Work continues to develop and validate methods to analyze total tin in the collected biota samples. In general, the interim results of this screening study suggest that the treatment process has performed as predicted and that the concentration of mercury in upper trophic level fish, as a surrogate for all of the underlying transport and transformation processes in a complex ecosystem, has declined as a direct result of the elimination of inorganic mercury inputs. Inorganic tin released to the ecosystem has been found in compartments where particles accumulate with notable levels measured in biofilms.

Looney, Brian [Savannah River National Laboratory (SRNL); BryanJr., Larry [Savannah River Ecology Laboratory; Mathews, Teresa J [ORNL; Peterson, Mark J [ORNL; Roy, W Kelly [ORNL; Jett, Robert T [ORNL; Smith, John G [ORNL

2012-03-01T23:59:59.000Z

148

Future trends in environmental mercury concentrations: implications  

E-Print Network [OSTI]

Future trends in environmental mercury concentrations: implications for prevention strategies interactions among natural and human climate system components; objectively assess uncertainty in economic, monitor and verify greenhouse gas emissions and climatic impacts. This reprint is one of a series intended

149

Mercury sorbent delivery system for flue gas  

DOE Patents [OSTI]

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Klunder; ,Edgar B. (Bethel Park, PA)

2009-02-24T23:59:59.000Z

150

Differential pressure pin discharge apparatus  

DOE Patents [OSTI]

Disclosed is a discharge assembly for allowing elongate pins to be discharged from an area of relatively low pressure to an area of relatively greater pressure. The discharge assembly includes a duck valve having a lip piece made of flexible material. The flexible lip piece responds to a fluctuating pressure created downstream by an aspirator. The aspirator reduces the downstream pressure sensed by the duck valve when the discharge assembly is in the open position. This allows elongate pins to be moved through the duck valve with no backflow because the aspirator pressure is less than the pressure in the low pressure area from which the pins originate. Closure of the assembly causes the aspirator static pressure to force the flexible duck valve lip piece into a tightly sealed position also preventing backflow. The discharge assembly can be easily controlled using a single control valve which blocks the flow of aspirator gas and closes the pin passageway extending through the assembly.

Oakley, David J. (Richland, WA)

1987-01-01T23:59:59.000Z

151

Symplectic Integrator Mercury: Bug Report  

E-Print Network [OSTI]

We report on a problem found in MERCURY, a hybrid symplectic integrator used for dynamical problems in Astronomy. The variable that keeps track of bodies' statuses is uninitialised, which can result in bodies disappearing from simulations in a non-physical manner. Some FORTRAN compilers implicitly initialise variables, preventing simulations from having this problem. With other compilers, simulations with a suitably large maximum number of bodies parameter value are also unaffected. Otherwise, the problem manifests at the first event after the integrator is started, whether from scratch or continuing a previously stopped simulation. Although the problem does not manifest in some conditions, explicitly initialising the variable solves the problem in a permanent and unconditional manner.

K. de Souza Torres; D. R. Anderson

2008-08-04T23:59:59.000Z

152

Detection of concealed mercury with thermal neutrons  

SciTech Connect (OSTI)

In the United States today, governments at all levels and the citizenry are paying increasing attention to the effects, both real and hypothetical, of industrial activity on the environment. Responsible modem industries, reflecting this heightened public and regulatory awareness, are either substituting benign materials for hazardous ones, or using hazardous materials only under carefully controlled conditions. In addition, present-day environmental consciousness dictates that we deal responsibly with legacy wastes. The decontamination and decommissioning (D&D) of facilities at which mercury was used or processed presents a variety of challenges. Elemental mercury is a liquid at room temperature and readily evaporates in air. In large mercury-laden buildings, droplets may evaporate from one area only to recondense in other cooler areas. The rate of evaporation is a function of humidity and temperature; consequently, different parts of a building may be sources or sinks of mercury at different times of the day or even the year. Additionally, although mercury oxidizes in air, the oxides decompose upon heating. Hence, oxides contained within pipes or equipment, may be decomposed when those pipes and equipment are cut with saws or torches. Furthermore, mercury seeps through the pores and cracks in concrete blocks and pads, and collects as puddles and blobs in void spaces within and under them.

Bell, Z.W.

1994-08-18T23:59:59.000Z

153

Capillary discharge source  

DOE Patents [OSTI]

Debris generation from an EUV electric discharge plasma source device can be significantly reduced or essentially eliminated by encasing the electrodes with dielectric or electrically insulating material so that the electrodes are shielded from the plasma, and additionally by providing a path for the radiation to exit wherein the electrodes are not exposed to the area where the radiation is collected. The device includes: (a) a body, which is made of an electrically insulating material, that defines a capillary bore that has a proximal end and a distal end and that defines at least one radiation exit; (b) a first electrode that defines a first channel that has a first inlet end that is connected to a source of gas and a first outlet end that is in communication with the capillary bore, wherein the first electrode is positioned at the distal end of the capillary bore; (c) a second electrode that defines a second channel that has a second inlet end that is in communication with the capillary bore and an outlet end, wherein the second electrode is positioned at the proximal end of the capillary bore; and (d) a source of electric potential that is connected across the first and second electrodes, wherein radiation generated within the capillary bore is emitted through the at least one radiation exit and wherein the first electrode and second electrode are shielded from the emitted radiation.

Bender, III, Howard Albert

2003-11-25T23:59:59.000Z

154

VEE-0020- In the Matter of Mercury Fuel Service, Inc.  

Broader source: Energy.gov [DOE]

On April 9, 1996, Mercury Fuel Service, Inc. (Mercury) of Waterbury, Connecticut, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE)....

155

Seismic effects of the Caloris basin impact, Mercury  

E-Print Network [OSTI]

Striking geological features on Mercury's surface have been linked to tectonic disruption associated with the Caloris impact and have the potential to provide information on the interior structure of Mercury. The unusual ...

L, Jiangning

2011-01-01T23:59:59.000Z

156

Nested-grid simulation of mercury over North America  

E-Print Network [OSTI]

Chemistry and Physics Nested-grid simulation of mercury overY. Zhang et al. : Nested-grid simulation of mercury overand Chen, S. -Y. : Plume-in-grid modeling of atmospheric

2012-01-01T23:59:59.000Z

157

Removal of mercury from coal via a microbial pretreatment process  

SciTech Connect (OSTI)

A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

2011-08-16T23:59:59.000Z

158

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect (OSTI)

The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

Sharon Sjostrom

2005-12-30T23:59:59.000Z

159

Industrial Discharge Permits (District of Columbia)  

Broader source: Energy.gov [DOE]

All businesses and government agencies discharging process wastewater to the public sewer system must report their activities to DC Water's Pretreatment Center. Wastewater discharge permits are...

160

Groundwater Discharge Permit and Registration (New Hampshire)  

Broader source: Energy.gov [DOE]

The Groundwater Discharge Permitting and Registration Program seeks to protect groundwater quality by establishing standards, criteria, and procedures for wastewater discharges. The program...

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Discharge cell for ozone generator  

DOE Patents [OSTI]

A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

Nakatsuka, Suguru (Amagasaki, JP)

2000-01-01T23:59:59.000Z

162

DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site Is Preferred for Long-Term Mercury Storage  

Broader source: Energy.gov [DOE]

WASHINGTON The Department of Energy has prepared a Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement to analyze the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven locations

163

Optical frequency standards based on mercury and aluminum ions  

E-Print Network [OSTI]

Optical frequency standards based on mercury and aluminum ions W. M. Itano, J. C. Bergquist, A-16 . Keywords: aluminum, atomic clocks, frequency standards, ion traps, mercury 1. INTRODUCTION Optical frequency standards based on the mercury ion and, more recently, the aluminum ion are under devel- opment

164

Mercury: Supporting Scalable Multi-Attribute Range Queries  

E-Print Network [OSTI]

Mercury: Supporting Scalable Multi-Attribute Range Queries Ashwin R. Bharambe Mukesh Agrawal 15213 Abstract This paper presents the design of Mercury, a scalable protocol for supporting multi-attribute range- based searches. Mercury differs from previous range-based query systems in that it supports mul

Keinan, Alon

165

Mercury/Waterfilling for Fixed Wireless OFDM Angel Lozano  

E-Print Network [OSTI]

Mercury/Waterfilling for Fixed Wireless OFDM Systems Angel Lozano Bell Labs (Lucent Technologies- mation is then given by the more general mercury/waterfilling policy. This paper illustrates the usance of mercury/waterfilling on frequency-selective OFDM channels with QAM constellations and it quantifies

Verdú, Sergio

166

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER  

E-Print Network [OSTI]

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER (IPAC12, WEPPD038) The target station a 15-20 T superconducting magnet. The target itself is a free mercury jet, moving at 20 m/s at an small angle to the magnetic axis, so as later to be collected in a mercury pool/beam dump. The replaceable

McDonald, Kirk

167

Powering Mercury's dynamo J.-P. Williams,1  

E-Print Network [OSTI]

Powering Mercury's dynamo J.-P. Williams,1 O. Aharonson,1 and F. Nimmo2 Received 6 July 2007 magnetic field of Mercury has implications for the interior structure of the planet and its thermal (2007), Powering Mercury's dynamo, Geophys. Res. Lett., 34, L21201, doi:10.1029/ 2007GL031164. 1

Nimmo, Francis

168

2003 Mercury Computer Systems, Inc. Session 5: Current &  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Session 5: Current & Emerging Standards Session 5: Current & Emerging Standards Craig Lund, Chief Technology Officer Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC) Conference September 2003 #12;© 2003 Mercury Computer Systems, Inc. Agenda

Kepner, Jeremy

169

Wednesday, March 25, 2009 SPECIAL SESSION: MESSENGER AT MERCURY  

E-Print Network [OSTI]

Wednesday, March 25, 2009 SPECIAL SESSION: MESSENGER AT MERCURY: A GLOBAL PERSPECTIVE. T. MESSENGER's Newly Global Perspective on Mercury: Some Implications for Interior Evolution [#1750] MESSENGER's first two flybys of Mercury have revealed a planet with a richer history of magmatism

Rathbun, Julie A.

170

Exploring Mercury: Scientific Results from the MESSENGER Mission  

E-Print Network [OSTI]

#12;Exploring Mercury: Scientific Results from the MESSENGER Mission Larry R. Nittler Carnegie-Cahill · MESSENGER Science Team, Engineers, Mission Operations (APL) #12;Mars Mercury · Naked-eye planet, but very difficult to observe due to proximity to Sun May 12, 2011, from NZ (M. White, Flickr) Mercury Venus Jupiter

Rhoads, James

171

2003 Mercury Computer Systems, Inc. Beamforming for Radar  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Beamforming for Radar Systems on COTS Heterogeneous ComputingHeterogeneous Computing PlatformsPlatforms Jeffrey A. Rudin Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC) Conference September 23, 2003 #12;2© 2003 Mercury Computer Systems, Inc. Outline

Kepner, Jeremy

172

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from a global 3D land.S. National Science Foundation Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since

Selin, Noelle Eckley

173

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta  

E-Print Network [OSTI]

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta STFC Rutherford Appleton Laboratory, UK 2nd Princeton-Oxford High Power Target Meeting 6-7 November-2008 #12;Mercury beam dump design from NUFACT Feasibility Study #12;Peter Loveridge, November-2008 Mercury beam dump design from NUFACT

McDonald, Kirk

174

Mercury Concentrations in Fish from the San Francisco Bay Area  

E-Print Network [OSTI]

Mercury Concentrations in Fish from the San Francisco Bay Area San Francisco Bay Regional Water on composite samples · Some mercury analysis on individual largemouth bass · Size targets #12;Tomales Bay Study chemical analyses (Hg and organics) conducted on composite samples · Some mercury analysis on individual

175

Mercury's thermo-chemical evolution from numerical models constrained  

E-Print Network [OSTI]

Mercury's thermo-chemical evolution from numerical models constrained by MESSENGER observations Globe de Paris, France #12;Basics facts about Mercury · Semi-major axis: 0.39 AU · 3:2 spin Earth!) · Black body temperature: 440 K #12;Exploration of Mercury Mariner10 ·First spacecraft to use

Cerveny, Vlastislav

176

Mercury exosphere I. Global circulation model of its sodium component  

E-Print Network [OSTI]

Mercury exosphere I. Global circulation model of its sodium component Francois Leblanc a,*, R 2010 Accepted 27 April 2010 Available online 5 May 2010 Keywords: Mercury, Atmosphere Aeronomy a b s t r a c t Our understanding of Mercury's sodium exosphere has improved considerably in the last 5

Johnson, Robert E.

177

Mercury warning given to north state anglers By Ryan Sabalow  

E-Print Network [OSTI]

Mercury warning given to north state anglers By Ryan Sabalow Monday, June 7, 2010 A new study the highest levels of mercury contamination in the state. Although anglers arent being warned to wean,905 fish in 272 of Californias popular lakes and reservoirs for mercury, PCBs, DDT and other contaminants

178

Mercury reuses several external software tools developed by ORNL  

E-Print Network [OSTI]

Mercury reuses several external software tools developed by ORNL DAAC and other organizations-on,canopychemistryaccpclimatecollectionseoslandvalidationFIFEFIFEfollow-on fluxnethydroclimatologycollectionsmodelarchivenetprimaryproductivityNPPNBIIMAST- DCUSANPNIABINDataONEWENDI Mercury's architecture includes 1) a harvesting engine was packaged in such a way that all the Mercury projects will use the same harvester scripts, but each project

179

Mercury and Freon: Temperature Emulation and Management for Server Systems  

E-Print Network [OSTI]

Mercury and Freon: Temperature Emulation and Management for Server Systems Taliver Heath Dept by simulators and real measurements. In this paper, we introduce Mercury, a soft- ware suite that avoids data. Most importantly, Mercury runs the entire software stack natively, enables repeatable experiments

Bianchini, Ricardo

180

Thursday, March 26, 2009 POSTER SESSION II: MERCURY  

E-Print Network [OSTI]

Thursday, March 26, 2009 POSTER SESSION II: MERCURY 6:30 p.m. Town Center Exhibit Area Gómez-Perez N. Wicht J. Magnetic Field at Mercury: Effects of External Sources on Planetary Dynamos [#1634] In Mercury, magnetospheric currents induce a magnetic field at the top of the core. We study dynamo

Rathbun, Julie A.

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Mercury: Supporting Scalable Multi-Attribute Range Ashwin R. Bharambe  

E-Print Network [OSTI]

Mercury: Supporting Scalable Multi-Attribute Range Queries Ashwin R. Bharambe ashu Carnegie Mellon University Pittsburgh, PA 15213 ABSTRACT This paper presents the design of Mercury, a scalable pro- tocol for supporting multi-attribute range-based searches. Mercury differs from previous

Krishnamurthy, Arvind

182

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta Chris Densham  

E-Print Network [OSTI]

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta Chris Densham STFC Rutherford Appleton Laboratory, UK 1st joint meeting of EUROnu WP2 (Superbeam) and NF-IDS target 15-17 December-2008 #12;Mercury beam dump design from NUFACT Feasibility Study #12;Peter Loveridge, November-2008 Mercury beam dump

McDonald, Kirk

183

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from global modeling Noelle Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since industrialization Major anthropogenic

Selin, Noelle Eckley

184

Tuesday, March 14, 2006 POSTER SESSION I: MERCURY  

E-Print Network [OSTI]

Tuesday, March 14, 2006 POSTER SESSION I: MERCURY 7:00 p.m. Fitness Center Helbert J. Moroz L. V for the MERTIS Instrument on the ESA BepiColombo Mission to Mercury [#1662] The MERTIS instrument on BepiColombo will study the surface of Mercury in the TIR. We will present a list of analog material compiled to support

Rathbun, Julie A.

185

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from Global Modeling Noelle #12;MERCURY IN THE ENVIRONMENT: OUTLINE 1. Deposition to the United States results from a mix of local and global sources, depending on the location 2. Historical and present releases of mercury will continue

Selin, Noelle Eckley

186

MESSENGER observations of magnetopause structure and dynamics at Mercury  

E-Print Network [OSTI]

MESSENGER observations of magnetopause structure and dynamics at Mercury Gina A. DiBraccio,1 James December 2012; accepted 10 January 2013; published 1 March 2013. [1] On 18 March 2011, MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) became the first spacecraft to orbit Mercury

Salzman, Daniel

187

HID Laboratories Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to:Photon Place:Net JumpStrategy | Open EnergyHawaiiH2GoHERA USA

188

Emerging technologies and approaches to minimize discharges into Lake Michigan, phase 2 module 4 report.  

SciTech Connect (OSTI)

The Great Lakes Initiative (GLI) established the new water quality-based discharge criteria for mercury (Hg), thereby increasing the need for many municipal and industrial wastewater treatment plants in the region to lower the mercury in their effluents. Information on deployable technologies to satisfy these requirements for industrial and municipal dischargers in the Great lakes region is scarce. Therefore, BP funded Purdue University Calumet and Argonne to identify deployable Hg removal technologies to meet the GLI discharge criterion at its Whiting Refinery in Indiana. The joint PUC/Argonne project was divided into 2 phases. Results from Phase I and Phase II Modules 1-3 have been previously reported. This report summarizes the work done in Phase 3 Module 4, which consisted of the pilot scale testing of Hg removal technologies previously selected in Module 3. The pilot testing was an Argonne/PUC jointly directed project that was hosted at and funded by the BP refinery in Whiting, IN. As two organizations were involved in data analysis and interpretation, this report combines two independent sets of evaluations of the testing that was done, prepared respectively by Argonne and Purdue. Each organization retains sole responsibility for its respective analysis conclusions and recommendations. Based on Module 3 bench testing with pre-Effluent To Lake (pre-ETL) and clarifier effluent (CE) samples from the Whiting refinery, three different technologies were chosen for pilot testing: (1) Ultrafiltration (using GE ZeeWeed(reg sign) Technology, 0.04 {mu}m pore size and made up of PVDF) for particulate mercury removal; (2) Adsorption using Mersorb(reg sign) LW, a sulfur-impregnated activated carbon, for dissolved mercury removal if present and (3) The Blue PRO(reg sign) reactive filtration process for both particulate and dissolved (if present) mercury removal. The ultrafiltration and the Blue PRO(reg sign) reactive filtration pilot studies were done simultaneously at the BP Whiting refinery using a slipstream of wastewater taken just prior to the Effluent to lake (pre-ETL) outfall. It was the intention of this pilot testing to demonstrate proof of concept, i.e. can the discharge limits obtained at bench scale be consistently met at the pilot scale. Although Mersorb(reg sign) LW was selected for dissolved mercury removal testing, this technology was not pilot tested because of a lack of dissolved mercury in the test wastewater during the pilot study. The overall objective of this pilot testing was to demonstrate the effectiveness of the tested technologies with continuous and varying feed conditions to meet the GLI criterion (1.3 ppt). Optimization for full-scale design was outside of the scope of this work. In addition to demonstrating whether the Hg criterion can be met, information on residue generation rate, frequency of backwashing and other maintenance issues were collected to better understand the implications for a full-scale system.

Negri, M.C.; Gillenwater, P.; Urgun-Demirtas, M.; Nnanna, G.; Yu, J.; Jannotta, I, (Energy Systems); (Purdue University Calumet)

2012-04-19T23:59:59.000Z

189

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle*  

E-Print Network [OSTI]

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle-1062 The absorption of elemental Hg vapor into aqueous solution containing Hg(II) was measured in a stirred cell at 25 °C. For mercury absorption in Hg(II) obtained by HgCl2 injection, the presence of HNO3 greatly

Rochelle, Gary T.

190

Geochemical, Genetic, and Community Controls on Mercury  

SciTech Connect (OSTI)

The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

Wall, Judy D.

2014-11-10T23:59:59.000Z

191

Sorbents for the oxidation and removal of mercury  

DOE Patents [OSTI]

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

2014-09-02T23:59:59.000Z

192

Method for high temperature mercury capture from gas streams  

DOE Patents [OSTI]

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

193

Sorbents for the oxidation and removal of mercury  

DOE Patents [OSTI]

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

2008-10-14T23:59:59.000Z

194

Sorbents for the oxidation and removal of mercury  

DOE Patents [OSTI]

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

2012-05-01T23:59:59.000Z

195

MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR  

SciTech Connect (OSTI)

This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control. An additional task was included in this project to evaluate mercury oxidation upstream of a dry scrubber by using mercury oxidants. This project demonstrated at the pilot-scale level a technology that provides a cost-effective technique to control mercury and, at the same time, greatly enhances fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution for improved fine particulate control combined with effective mercury control for a large segment of the U.S. utility industry as well as other industries.

Ye Zhuang; Stanley J. Miller

2005-05-01T23:59:59.000Z

196

FY09 assessment of mercury reduction at SNL/NM.  

SciTech Connect (OSTI)

This assessment takes the result of the FY08 performance target baseline of mercury at Sandia National Laboratories/New Mexico, and records the steps taken in FY09 to collect additional data, encourage the voluntary reduction of mercury, and measure success. Elemental (metallic) mercury and all of its compounds are toxic, and exposure to excessive levels can permanently damage or fatally injure the brain and kidneys. Elemental mercury can also be absorbed through the skin and cause allergic reactions. Ingestion of inorganic mercury compounds can cause severe renal and gastrointestinal damage. Organic compounds of mercury such as methyl mercury, created when elemental mercury enters the environment, are considered the most toxic forms of the element. Exposures to very small amounts of these compounds can result in devastating neurological damage and death.1 SNL/NM is required to report annually on the site wide inventory of mercury for the Environmental Protection Agency's (EPA) Toxics Release Inventory (TRI) Program, as the site's inventory is excess of the ten pound reportable threshold quantity. In the fiscal year 2008 (FY08) Pollution Prevention Program Plan, Section 5.3 Reduction of Environmental Releases, a performance target stated was to establish a baseline of mercury, its principle uses, and annual quantity or inventory. This was accomplished on July 29, 2008 by recording the current status of mercury in the Chemical Information System (CIS).

McCord, Samuel Adam

2010-02-01T23:59:59.000Z

197

Mercury emissions control technologies for mixed waste thermal treatment  

SciTech Connect (OSTI)

EPA has identified wet scrubbing at low mercury feedrates, as well as carbon adsorption via carbon injection into the offgas or via flow through fixed carbon beds, as control technologies that can be used to meet the proposed Maximum Achievable Control Technology (MACT) rule limit for mercury emissions from hazardous waste incinerators. DOE is currently funding demonstrations of gold amalgamation that may also control mercury to the desired levels. Performance data from a variety of sources was reviewed to determine ranges of achievable mercury control. Preliminary costs were estimated for using these technologies to control mercury emissions from mixed waste incineration. Mercury emissions control for mixed waste incineration may need to be more efficient than for incineration of other hazardous wastes because of higher mercury concentrations in some mixed waste streams. However, mercury control performance data for wet scrubbing and carbon adsorption is highly variable. More information is needed to demonstrate control efficiencies that are achievable under various design and operating conditions for wet scrubbing, carbon adsorption, and gold amalgamation technologies. Given certain assumptions made in this study, capital costs, operating costs, and lifecycle costs for carbon injection, carbon beds, and gold amalgamation generally vary for different assumed mercury feedrates and for different offgas flowrates. Assuming that these technologies can in fact provide the necessary mercury control performance, each of these technologies may be less costly than the others for certain mercury feedrates and the offgas flowrates.

Chambers, A.; Knecht, M.; Soelberg, N.; Eaton, D. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.; Roberts, D.; Broderick, T. [ADA Technologies, Englewood, CO (United States)

1997-12-31T23:59:59.000Z

198

Global change and mercury cycling: Challenges for implementing a global mercury treaty  

E-Print Network [OSTI]

The Minamata Convention aims to protect human health and the environment from anthropogenic emissions and releases of mercury. In the present study, the provisions of the Minamata Convention are examined to assess their ...

Selin, Noelle Eckley

199

Journal of Engineering Mathematics Optimal discharging in a branched estuary Optimal discharging in a branched estuary  

E-Print Network [OSTI]

that returns to the discharge site is less polluted than would 1 #12;Journal of Engineering Mathematics OptimalJournal of Engineering Mathematics Optimal discharging in a branched estuary Optimal discharging the proximity of the discharge site to the branching and upon how the rate of discharge is adjusted. Explicit

200

DOI: 10.1002/chem.200701895 A Highly Selective Colorimetric Aqueous Sensor for Mercury  

E-Print Network [OSTI]

to methyl mercury, adding this potent neuro- toxin to the food chain.[4­6] Mercury poisoning causes serious Mercury poisoning remains a significant threat to human health, yet global mercury emissions continue of mercury poisoning requires new methods of detection that are sen- sitive and selective. Here we report

Tew, Gregory N.

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

MERCURY IN TUNAS: A REVIEW C. L. PETERSON, W. L. KLAWE, AND G. D. SHARp!  

E-Print Network [OSTI]

MERCURY IN TUNAS: A REVIEW C. L. PETERSON, W. L. KLAWE, AND G. D. SHARp! ABSTRACT Mercury not significantly altered the mercury content of the high seas where most tunas are captured. Mercury compounds importance of these pathways in tunas is unknown. Mercury occurs in tuna principally in the form

202

Mercury Exchange Program Summary: The Office of Research Safety (ORS) proudly presents  

E-Print Network [OSTI]

Mercury Exchange Program Summary: The Office of Research Safety (ORS) proudly presents the Mercury Exchange Program. This is a great program that enables laboratories to exchange their intact mercury thermometers, manometers, and other mercury-containing devices for non-mercury devices at no cost. The key

Duchowski, Andrew T.

203

Mercury Monitoring in California Sport Fish: A Historical Review and Recommendations for the Future  

E-Print Network [OSTI]

Mercury Monitoring in California Sport Fish: A Historical Review and Recommendations for the Future with unusually severe and widespread mercury contamination due to extensive mercury and gold mining in the 1800s. Mercury monitoring in California sport sh began in 1969. Since that time, a substantial amount of mercury

204

Constricted glow discharge plasma source  

DOE Patents [OSTI]

A constricted glow discharge chamber and method are disclosed. The polarity and geometry of the constricted glow discharge plasma source is set so that the contamination and energy of the ions discharged from the source are minimized. The several sources can be mounted in parallel and in series to provide a sustained ultra low source of ions in a plasma with contamination below practical detection limits. The source is suitable for applying films of nitrides such as gallium nitride and oxides such as tungsten oxide and for enriching other substances in material surfaces such as oxygen and water vapor, which are difficult process as plasma in any known devices and methods. The source can also be used to assist the deposition of films such as metal films by providing low-energy ions such as argon ions.

Anders, Andre (Albany, CA); Anders, Simone (Albany, CA); Dickinson, Michael (San Leandro, CA); Rubin, Michael (Berkeley, CA); Newman, Nathan (Winnetka, IL)

2000-01-01T23:59:59.000Z

205

Compact monolithic capacitive discharge unit  

DOE Patents [OSTI]

A compact monolithic capacitive discharge unit (CDU) is disclosed in which a thyristor switch and a flyback charging circuit are both sandwiched about a ceramic energy storage capacitor. The result is a compact rugged assembly which provides a low-inductance current discharge path. The flyback charging circuit preferably includes a low-temperature co-fired ceramic transformer. The CDU can further include one or more ceramic substrates for enclosing the thyristor switch and for holding various passive components used in the flyback charging circuit. A load such as a detonator can also be attached directly to the CDU.

Roesler, Alexander W. (Tijeras, NM); Vernon, George E. (Rio Rancho, NM); Hoke, Darren A. (Albuquerque, NM); De Marquis, Virginia K. (Tijeras, NM); Harris, Steven M. (Albuquerque, NM)

2007-06-26T23:59:59.000Z

206

State Waste Discharge Permit application, 183-N Backwash Discharge Pond  

SciTech Connect (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173--216 (or 173--218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE91NM-177 requires a series of permitting activities for liquid effluent discharges. Liquid effluents on the Hanford Site have been classified as Phase I, Phase II, and Miscellaneous Streams. The Consent Order No. DE91NM-177 establishes milestones for State Waste Discharge Permit application submittals for all Phase I and Phase II streams, as well as the following 11 Miscellaneous Streams as identified in Table 4 of the Consent Order No. DE91NM-177.

Not Available

1994-06-01T23:59:59.000Z

207

A NASA Discovery Mission Mercury Orbit Insertion  

E-Print Network [OSTI]

major systems provide critical backup. Passive thermal design utilizing ceramic-cloth sunshade requires. Custom solar arrays produce power at safe operating temperatures near Mercury. MESSENGER is designedMercuryandextendedfrom before the end of heavy bombardment to the second half of solar system history

208

Mercury Nozzle Status V.B. Graves  

E-Print Network [OSTI]

. DEPARTMENT OF ENERGY Hg Jet Design Meeting 15 Nov 2004 Flow Issues High flow in small diameter thin-wall 15 Nov 2004 Design Issues Desire mechanically attached nozzle for changeout during cold testingMercury Nozzle Status V.B. Graves Hg Jet Design Meeting Princeton University Nov 15, 2004 #12;OAK

McDonald, Kirk

209

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect (OSTI)

ADA-ES, Inc., with support from DOE/NETL, EPRI, and industry partners, studied mercury control options at six coal-fired power plants. The overall objective of the this test program was to evaluate the capabilities of activated carbon injection at six plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, American Electric Power's Conesville Station Unit 6, and Labadie Power Plant Unit 2. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The financial goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000 per pound of mercury removed. Results from testing at Holcomb, Laramie, Meramec, Labadie, and Monroe indicate the DOE goal was successfully achieved. However, further improvements for plants with conditions similar to Conesville are recommended that would improve both mercury removal performance and economics.

Sharon Sjostrom

2008-06-30T23:59:59.000Z

210

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect (OSTI)

The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at DTE Energy's Monroe Power Plant, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program was to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000/lb mercury removed. The results from Monroe indicate that using DARCO{reg_sign} Hg would result in higher mercury removal (80%) at a sorbent cost of $18,000/lb mercury, or 70% lower than the benchmark. These results demonstrate that the goals established by DOE/NETL were exceeded during this test program. The increase in mercury removal over baseline conditions is defined for this program as a comparison in the outlet emissions measured using the Ontario Hydro method during the baseline and long-term test periods. The change in outlet emissions from baseline to long-term testing was 81%.

Sharon Sjostrom

2006-04-30T23:59:59.000Z

211

MERCURY SPECIATION SAMPLING AT NEW CENTURY ENERGY'S VALMONT STATION  

SciTech Connect (OSTI)

The 1990 Clean Air Act Amendments required the U.S. Environmental Protection Agency (EPA) to determine whether the presence of mercury in the stack emissions from fossil fuel-fired electric utility power plants poses an unacceptable public health risk. EPA's conclusions and recommendations were presented in the ''Mercury Study Report to Congress'' and ''Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units''. The first report addressed both the human health and environmental effects of anthropogenic mercury emissions, while the second addressed the risk to public health posed by the emission of mercury and other hazardous air pollutants from steam electric generating units. Although these reports did not state that mercury controls on coal-fired electric power stations would be required given the current state of the art, they did indicate that the EPA views mercury as a potential threat to human health. Therefore, it was concluded that mercury controls at some point may be necessary. EPA also indicated that additional research/information was necessary before any definitive statement could be made. In an effort to determine the amount and types of mercury being emitted into the atmosphere by coal-fired power plants, EPA in late 1998 issued an information collection request (ICR) that required all coal-fired power plants to analyze their coal and submit the results to EPA on a quarterly basis. In addition, about 85 power stations were required to measure the speciated mercury concentration in the flue gas. These plants were selected on the basis of plant configuration and coal type. The Valmont Station owned and operated by New Century Energy in Boulder, Colorado, was selected for detailed mercury speciation of the flue gas as part of the ICR process. New Century Energy, in a tailored collaboration with EPRI and the U.S. Department of Energy, contracted with the Energy & Environmental Research Center (EERC) to do a study evaluating the behavior of mercury at the Valmont Station. The activities conducted at the Valmont Station by the EERC not only included the sampling needed to meet the requirements of the ICR, but involved a much more extensive mercury research program. The following objectives for the sampling at New Century Energy's Valmont Station were accomplished: (1) Successfully complete all of the mercury sampling and reporting requirements of the ICR. (2) Determine the variability in mercury concentrations at the stack using mercury continuous emission monitors (CEMs). (3) Calculate mercury mass balances and emission rates. (4) Determine the mercury concentration in the fly ash as a function of particle size. (5) Determine the impact of a fabric filter on mercury emissions for a western bituminous coal.

Dennis L. Laudal

2000-04-01T23:59:59.000Z

212

Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria  

SciTech Connect (OSTI)

Methylmercury is a neurotoxin that poses significant health risks to humans. Some anaerobic sulphate- and iron-reducing bacteria can methylate oxidized forms of mercury, generating methylmercury1-4. One strain of sulphate-reducing bacteria (Desulfovibrio desulfuricans ND132) can also methylate elemental mercury5. The prevalence of this trait among different bacterial strains and species remains unclear, however. Here, we compare the ability of two strains of the sulphate-reducing bacterium Desulfovibrio and one strain of the iron-reducing bacterium Geobacter to oxidise and methylate elemental mercury in a series of laboratory incubations. Experiments were carried out under dark, anaerobic conditions, in the presence of environmentally-relevant concentrations of elemental mercury. We report differences in the ability of these organisms to oxidise and methylate elemental mercury. In line with recent findings5, we show that Desulfovibrio desulfuricans ND132 can both oxidise and methylate elemental mercury. However, the rate of methylation of elemental mercury is only about one third the rate of methylation of oxidized mercury. We also show that Desulfovibrio alaskensis G20 can oxidise, but not methylate, elemental mercury. Geobacter sulfurreducens PCA is able to oxidise and methylate elemental mercury in the presence of cysteine. We suggest that the activity of methylating and non-methylating bacteria may together enhance the formation of methylmercury in anaerobic environments.

Hu, Haiyan [ORNL] [ORNL; Lin, Hui [ORNL] [ORNL; Zheng, Wang [ORNL] [ORNL; Tomanicek, Stephen J [ORNL] [ORNL; Johs, Alexander [ORNL] [ORNL; Feng, Xinbin [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Gu, Baohua [ORNL] [ORNL

2013-01-01T23:59:59.000Z

213

Influences on Mercury Bioaccumulation Factors for the Savannah River  

SciTech Connect (OSTI)

Mercury TMDLs (Total Maximum Daily Loads) are a regulatory instrument designed to reduce the amount of mercury entering a water body and ultimately to control the bioaccumulation of mercury in fish. TMDLs are based on a BAF (bioaccumulation factor), which is the ratio of methyl mercury in fish to dissolved methyl mercury in water. Analysis of fish tissue and aqueous methyl mercury samples collected at a number of locations and over several seasons in a 118 km reach of the Savannah River demonstrated that species specific BAFs varied by factors of three to eight. Factors contributing to BAF variability were location, habitat and season related differences in fish muscle tissue mercury levels and seasonal differences in dissolved methyl mercury levels. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 106 for largemouth bass, 1.4 x 106 for sunfishes, and 2.5 x 106 for white catfish. Inaccurate and imprecise BAFs can result in unnecessary economic impact or insufficient protection of human health. Determination of representative and precise BAFs for mercury in fish from large rivers necessitates collecting large and approximately equal numbers of fish and aqueous methyl mercury samples over a seasonal cycle from the entire area and all habitats to be represented by the TMDL.

Paller, M.H.

2003-05-06T23:59:59.000Z

214

Total Mercury, Methylmercury, Methylmercury Production Potential, and Ancillary Streambed-Sediment and Pore-  

E-Print Network [OSTI]

Total Mercury, Methylmercury, Methylmercury Production Potential, and Ancillary Streambed Oak Creek, Wisconsin (center). (All photographs by the authors.) #12;Total Mercury, Methylmercury.E., 2008, Total mercury, methylmercury, methylmercury production potential, and ancillary streambed

215

ROTATION OF MERCURY: THEORETICAL ANALYSIS OF THE DYNAMICS OF A RIGID ELLIPSOIDAL PLANET  

E-Print Network [OSTI]

Laboratory ROTATION OF MERCURY: THEDRETICAL ANALYSIS OF THEW -7405-eng-48 ROTATION OF MERCURY: THEORETICAL ANALYSIS OFfor the rotation of Mercury is sho'ln to imply locked-in

Laslett, L. Jackson

2008-01-01T23:59:59.000Z

216

Mercury and Methylmercury in the San Francisco Bay area: land-use impact and indicators  

E-Print Network [OSTI]

R.P. , and Flegal A. R. 2003, Mercury speciation in the SanAbdrashitova S. A. , 2001, Mercury in Aquatic Environment: A222 Hydrology for Planner Mercury and Methylmercury in the

Kim, Hyojin

2008-01-01T23:59:59.000Z

217

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

M. and Chang, B. , 1974; Mercury Monitor for Ambient Air,E. Poulson INTRODUCTION Mercury emissions from fossil-fuelHarley, R. A. , 1973; Mercury Balance on a Large Pulverized

Fox, J. P.

2012-01-01T23:59:59.000Z

218

Comparative analysis of discharges into Lake Michigan, Phase I - Southern Lake Michigan.  

SciTech Connect (OSTI)

BP Products North America Inc. (BP) owns and operates a petroleum refinery located on approximately 1,700 acres in Whiting, East Chicago, and Hammond, Indiana, near the southern tip of Lake Michigan. BP provided funding to Purdue University-Calumet Water Institute (Purdue) and Argonne National Laboratory (Argonne) to conduct studies related to wastewater treatment and discharges. Purdue and Argonne are working jointly to identify and characterize technologies that BP could use to meet the previous discharge permit limits for total suspended solids (TSS) and ammonia after refinery modernization. In addition to the technology characterization work, Argonne conducted a separate project task, which is the subject of this report. In Phase I of a two-part study, Argonne estimated the current levels of discharge to southern Lake Michigan from significant point and nonpoint sources in Illinois, Indiana, and portions of Michigan. The study does not consider all of the chemicals that are discharged. Rather, it is narrowly focused on a selected group of pollutants, referred to as the 'target pollutants'. These include: TSS, ammonia, total and hexavalent chromium, mercury, vanadium, and selenium. In Phase II of the study, Argonne will expand the analysis to cover the entire Lake Michigan drainage basin.

Veil, J. A.; Elcock, D.; Gasper, J. R.; Environmental Science Division

2008-06-30T23:59:59.000Z

219

Oxidation of Mercury in Products of Coal Combustion  

SciTech Connect (OSTI)

Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

2009-09-14T23:59:59.000Z

220

Mercury Emissions Control Technologies (released in AEO2006)  

Reports and Publications (EIA)

The Annual Energy Outlook 2006 reference case assumes that states will comply with the requirements of the Environmental Protection Agency's new Clean Air Mercury Rule (CAMR) regulation. CAMR is a two-phase program, with a Phase I cap of 38 tons of mercury emitted from all U.S. power plants in 2010 and a Phase II cap of 15 tons in 2018. Mercury emissions in the electricity generation sector in 2003 are estimated at around 50 tons. Generators have a variety of options to meet the mercury limits, such as: switching to coal with a lower mercury content, relying on flue gas desulfurization or selective catalytic reduction equipment to reduce mercury emissions, or installing conventional activated carbon injection (ACI) technology.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Characteristics of mercury desorption from sorbents at elevated temperatures  

SciTech Connect (OSTI)

This study investigated the dynamic desorption characteristics of mercury during the thermal treatment of mercury-loaded sorbents at elevated temperatures under fixed-bed operations. Experiments were carried out in a 25.4 mm ID quartz bed enclosed in an electric furnace. Elemental mercury and mercuric chloride were tested with activated carbon and bauxite. The experimental results indicated that mercury desorption from sorbents was strongly affected by the desorption temperature and the mercury-sorbent pair. Elemental mercury was observed to desorb faster than mercuric chloride and activated carbon appeared to have higher desorption limits than bauxite at low temperatures. A kinetic model considering the mechanisms of surface equilibrium, pore diffusion and external mass transfer was proposed to simulate the observed desorption profiles. The model was found to describe reasonably well the experimental results.

Ho, T.C.; Yang, P.; Kuo, T.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering

1998-12-31T23:59:59.000Z

222

Mercury control for coal-fired power plants  

SciTech Connect (OSTI)

On 15 March 2005 the US Environmental Protection Agency issued its Clean Air Mercury Rule (CAMP) to regulate mercury emissions from coal-fired power plants. EPRI is working with the US Department of Energy and the power industry to develop mercury control technologies needed to meet the final 2018 emission limits. Some improvements can be made by modifying existing SO{sub 2} or NOx control devices. Precombustion cleaning reduces mercury content of eastern coals by about one third. Adding a little halogen is another technology being researched - this promotes oxidation improving short-term mercury capture. EPRI is developing the TOXECON{trademark} technology to address a major problem of using sorbents to control mercury emissions: contamination of fly ash. 5 figs.

Haase, P.

2005-06-30T23:59:59.000Z

223

Experimental Diagnostics and Modeling of Microplasma Discharges  

E-Print Network [OSTI]

;Challenge · Difficult to perform conventional diagnostics in micro-plasma discharges because of their small size. Optical diagnostics are most convenient. #12;Plasma Processing Laboratory Experimental SetupExperimental Diagnostics and Modeling of Microplasma Discharges Department of Chemical

Economou, Demetre J.

224

Oklahoma Pollutant Discharge Elimination System Act (Oklahoma)  

Broader source: Energy.gov [DOE]

The Department of Environmental Quality regulates facilities that discharge any pollutant into waters of the state. Permits must be acquired before the discharge of any pollutants into state waters...

225

State Surface Water Discharge Permits (New Hampshire)  

Broader source: Energy.gov [DOE]

Rules apply to the discharge of all pollutants from a point source to surface waters of the state. The rule does not apply to facilities that require both a state discharge permit and a federal...

226

E-Print Network 3.0 - advanced mercury control Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Francisco Estuary Institute Collection: Environmental Sciences and Ecology 3 MERCURY POLLUTION PREVENTION IN MINNESOTA Emily Ray Moore Summary: applications Mercury in glass...

227

E-Print Network 3.0 - aquatic mercury assessment Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sea Grant Institute in consultation with the panel chairs. Summary: the assessment of fish-mercury responses to changes in mercury loadings. High net methylation rates in...

228

E-Print Network 3.0 - air pollution mercury Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mercury Search Powered by Explorit Topic List Advanced Search Sample search results for: air pollution mercury Page: << < 1 2 3 4 5 > >> 1 Environment, Health and Safety...

229

Thief carbon catalyst for oxidation of mercury in effluent stream  

SciTech Connect (OSTI)

A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2011-12-06T23:59:59.000Z

230

The development and field testing of a passive mercury dosimeter  

E-Print Network [OSTI]

there is a need for me- (1) th d o s for monicoring mercury exposutes, and a number of methods have been devised. These sampling methods may be divided into two classifi- cations, active and passive, based upon the system used to move the air..., and a suitable means of analysis is used to determine the amount of mercury collected. From this information the mercury in air concentration is readily calculated. Collection media used include glass tubes packed with hopcalite, ( activated charcoal...

Zahray, Robert Karl

1982-01-01T23:59:59.000Z

231

ORNL research reveals new challenges for mercury cleanup | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Jennifer Brouner Communications 865.241.0709 ORNL research reveals new challenges for mercury cleanup ORNL researchers are learning more about the microbial processes that convert...

232

Mercury Vapor At Lassen Volcanic National Park Area (Varekamp...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lassen Volcanic National Park Area (Varekamp & Buseck, 1983) Exploration...

233

EIS-0423: Storage and Management of Elemental Mercury | Department...  

Energy Savers [EERE]

for managing and storing elemental mercury at seven candidate locations (i.e., Colorado, Idaho, Missouri, Nevada, South Carolina, Texas, and Washington). The U.S....

234

anthropogenic mercury emissions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

marine boundary layer Palmer, Paul 25 MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT University of California eScholarship Repository Summary: Effluents for...

235

2, 22872325, 2005 discharge+sediment  

E-Print Network [OSTI]

HESSD 2, 2287­2325, 2005 Water discharge+sediment flux changes in Lower Mekon River X. X. Lu and R Sciences Water discharge and sediment flux changes in the Lower Mekong River X. X. Lu and R. Y. Siew­2325, 2005 Water discharge+sediment flux changes in Lower Mekon River X. X. Lu and R. Y. Siew Title Page

Paris-Sud XI, Université de

236

An evaluation of elemental mercury vapor exposure to children due to silver-mercury dental amalgam restorations  

E-Print Network [OSTI]

AN EVALUATION OF ELEMENTAL MERCURY VAPOR EXPOSURE TO CHILDREN DUE TO SILVER-MERCURY DENTAL AMALGAM RESTORATIONS A Thesis By RONALD DALE TAYLOR Submitted to the Office of Graduate Studies College Texas A&M University in partial fulfillment.... . . . . 1X LIST OF FIGURES. I. INTRODUCTION. II ' LITERATURE REVIEW Dental Mercury Toxicology Body Burden. Inhalation Exposure. Childhood Exposure III. METHODOLOGY. . . . 3 5 . . . 8 . . . 10 . . . 14 . 16 Human Research Committee...

Taylor, Ronald Dale

1989-01-01T23:59:59.000Z

237

State waste discharge permit application for cooling water and condensate discharges  

SciTech Connect (OSTI)

The following presents the Categorical State Waste Discharge Permit (SWDP) Application for the Cooling Water and Condensate Discharges on the Hanford Site. This application is intended to cover existing cooling water and condensate discharges as well as similar future discharges meeting the criteria set forth in this document.

Haggard, R.D.

1996-08-12T23:59:59.000Z

238

Mercury Specie and Multi-Pollutant Control  

SciTech Connect (OSTI)

This project was awarded to demonstrate the ability to affect and optimize mercury speciation and multi-pollutant control using non-intrusive advanced sensor and optimization technologies. The intent was to demonstrate plant-wide optimization systems on a large coal fired steam electric power plant in order to minimize emissions, including mercury (Hg), while maximizing efficiency and maintaining saleable byproducts. Advanced solutions utilizing state-of-the-art sensors and neural network-based optimization and control technologies were proposed to maximize the removal of mercury vapor from the boiler flue gas thereby resulting in lower uncontrolled releases of mercury into the atmosphere. Budget Period 1 (Phase I) - Included the installation of sensors, software system design and establishment of the as-found baseline operating metrics for pre-project and post-project data comparison. Budget Period 2 (Phase II) - Software was installed, data communications links from the sensors were verified, and modifications required to integrate the software system to the DCS were performed. Budget Period 3 (Phase III) - Included the validation and demonstration of all control systems and software, and the comparison of the optimized test results with the targets established for the project site. This report represents the final technical report for the project, covering the entire award period and representing the final results compared to project goals. NeuCo shouldered 61% of the total project cost; while DOE shouldered the remaining 39%. The DOE requires repayment of its investment. This repayment will result from commercial sales of the products developed under the project. NRG's Limestone power plant (formerly owned by Texas Genco) contributed the host site, human resources, and engineering support to ensure the project's success.

Rob James; Virgil Joffrion; John McDermott; Steve Piche

2010-05-31T23:59:59.000Z

239

Langmuir Films of Polycyclic Molecules on Mercury  

SciTech Connect (OSTI)

Langmuir films (LFs) of biphenyl and anthracene derivatives on the surface of liquid mercury were studied by surface-specific X-ray and surface tension measurements. Phases of lying-down, side-lying and standing-up molecules were found, some of which exhibit long-range lateral order. The molecular symmetry and the position and nature of the side-, end-, and headgroups are shown to dominate the structural evolution of the LFs with surface coverage.

Tamam,L.; Kraack, H.; Sloutskin, E.; Ocko, B.; Pershan, P.; Deutsch, M.

2007-01-01T23:59:59.000Z

240

Method and apparatus for dispensing small quantities of mercury from evacuated and sealed glass capsules  

DOE Patents [OSTI]

A technique for opening an evacuated and sealed glass capsule containing a material that is to be dispensed which has a relatively high vapor pressure such as mercury. The capsule is typically disposed in a discharge tube envelope. The technique involves the use of a first light source imaged along the capsule and a second light source imaged across the capsule substantially transversely to the imaging of the first light source. Means are provided for constraining a segment of the capsule along its length with the constraining means being positioned to correspond with the imaging of the second light source. These light sources are preferably incandescent projection lamps. The constraining means is preferably a multiple looped wire support.

Grossman, Mark W. (Framingham, MA); George, William A. (Rockport, MA); Pai, Robert Y. (Hamilton, MA)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Method and apparatus for dispensing small quantities of mercury from evacuated and sealed glass capsules  

DOE Patents [OSTI]

A technique is disclosed for opening an evacuated and sealed glass capsule containing a material that is to be dispensed which has a relatively high vapor pressure such as mercury. The capsule is typically disposed in a discharge tube envelope. The technique involves the use of a first light source imaged along the capsule and a second light source imaged across the capsule substantially transversely to the imaging of the first light source. Means are provided for constraining a segment of the capsule along its length with the constraining means being positioned to correspond with the imaging of the second light source. These light sources are preferably incandescent projection lamps. The constraining means is preferably a multiple looped wire support. 6 figs.

Grossman, M.W.; George, W.A.; Pai, R.Y.

1985-08-13T23:59:59.000Z

242

The free precession and libration of Mercury  

E-Print Network [OSTI]

An analysis based on the direct torque equations including tidal dissipation and a viscous core-mantle coupling is used to determine the damping time scales of O(10^5) years for free precession of the spin about the Cassini state and free libration in longitude for Mercury. The core-mantle coupling dominates the damping over the tides by one to two orders of magnitude for the plausible parameters chosen. The short damping times compared with the age of the solar system means we must find recent or on-going excitation mechanisms if such free motions are found by the current radar experiments or the future measurement by the MESSENGER and BepiColombo spacecraft that will orbit Mercury. We also show that the average precession rate is increased by about 30% over that obtained from the traditional precession constant because of a spin-orbit resonance induced contribution by the C_{22} term in the expansion of the gravitational field. The C_{22} contribution also causes the path of the spin during the precession to be slightly elliptical with a variation in the precession rate that is a maximum when the obliquity is a minimum. An observable free precession will compromise the determination of obliquity of the Cassini state and hence of C/MR^2 for Mercury, but a detected free libration will not compromise the determination of the forced libration amplitude and thus the verification of a liquid core

S. J. Peale

2005-07-06T23:59:59.000Z

243

Gravitomagnetism and the Earth-Mercury range  

E-Print Network [OSTI]

We numerically work out the impact of the general relativistic Lense-Thirring effect on the Earth-Mercury range caused by the gravitomagnetic field of the rotating Sun. The peak-to peak nominal amplitude of the resulting time-varying signal amounts to 1.75 10^1 m over a temporal interval 2 yr. Future interplanetary laser ranging facilities should reach a cm-level in ranging to Mercury over comparable timescales; for example, the BepiColombo mission, to be launched in 2014, should reach a 4.5 - 10 cm level over 1 - 8 yr. We looked also at other Newtonian (solar quadrupole mass moment, ring of the minor asteroids, Ceres, Pallas, Vesta, Trans-Neptunian Objects) and post-Newtonian (gravitoelectric Schwarzschild solar field) dynamical effects on the Earth-Mercury range. They act as sources of systematic errors for the Lense-Thirring signal which, in turn, if not properly modeled, may bias the recovery of some key parameters of such other dynamical features of motion. Their nominal peak-to-peak amplitudes are as large as 4 10^5 m (Schwarzschild), 3 10^2 m (Sun's quadrupole), 8 10^1 m (Ceres, Pallas, Vesta), 4 m (ring of minor asteroids), 8 10^-1 m (Trans-Neptunian Objects). Their temporal patterns are different with respect to that of the gravitomagnetic signal.

Lorenzo Iorio

2011-08-29T23:59:59.000Z

244

Analysis of Halogen-Mercury Reactions in Flue Gas  

SciTech Connect (OSTI)

Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

2010-01-01T23:59:59.000Z

245

The dynamics of mercury flow in a curved pipe  

E-Print Network [OSTI]

The dynamics of mercury flow in a curved pipe Yan Zhan Foluso LadeindeFoluso Ladeinde 11 of the problem Pi t ff t· Pipe curvature effect · Laminar flow in the mercury supply pipe l i· Conclusion #12 Project. · Target delivery systems involves pipe curvature, axially- d d t di l di t d l l th tdependent

McDonald, Kirk

246

Method for removal of mercury from various gas streams  

DOE Patents [OSTI]

The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

Granite, E.J.; Pennline, H.W.

2003-06-10T23:59:59.000Z

247

SNS Experimental Facilities Oak Ridge SNS Mercury Target Issues and  

E-Print Network [OSTI]

SNS Experimental Facilities Oak Ridge SNS Mercury Target Issues and Development Program J. R. Haines October 30, 2000 #12;SNS Experimental Facilities Oak Ridge2 Outline · SNS Target Requirements;SNS Experimental Facilities Oak Ridge3 Mercury Target Requirements · 2 MW average proton beam power

McDonald, Kirk

248

Mercury removal in utility wet scrubber using a chelating agent  

DOE Patents [OSTI]

A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

Amrhein, Gerald T. (Louisville, OH)

2001-01-01T23:59:59.000Z

249

Activated carbon injection - a mercury control success story  

SciTech Connect (OSTI)

Almost 100 full-scale activated carbon injection (ACI) systems have been ordered by US electric utilities. These systems have the potential to remove over 90% of the mercury in flue, at a cost below $10,000 per pound of mercury removal. Field trials of ACI systems arm outlined. 1 fig.

NONE

2008-07-01T23:59:59.000Z

250

Narrow gap electronegative capacitive discharges  

SciTech Connect (OSTI)

Narrow gap electronegative (EN) capacitive discharges are widely used in industry and have unique features not found in conventional discharges. In this paper, plasma parameters are determined over a range of decreasing gap length L from values for which an electropositive (EP) edge exists (2-region case) to smaller L-values for which the EN region connects directly to the sheath (1-region case). Parametric studies are performed at applied voltage V{sub rf}=500 V for pressures of 10, 25, 50, and 100 mTorr, and additionally at 50 mTorr for 1000 and 2000 V. Numerical results are given for a parallel plate oxygen discharge using a planar 1D3v (1 spatial dimension, 3 velocity components) particle-in-cell (PIC) code. New interesting phenomena are found for the case in which an EP edge does not exist. This 1-region case has not previously been investigated in detail, either numerically or analytically. In particular, attachment in the sheaths is important, and the central electron density n{sub e0} is depressed below the density n{sub esh} at the sheath edge. The sheath oscillations also extend into the EN core, creating an edge region lying within the sheath and not characterized by the standard diffusion in an EN plasma. An analytical model is developed using minimal inputs from the PIC results, and compared to the PIC results for a base case at V{sub rf}=500 V and 50 mTorr, showing good agreement. Selected comparisons are made at the other voltages and pressures. A self-consistent model is also developed and compared to the PIC results, giving reasonable agreement.

Kawamura, E.; Lieberman, M. A.; Lichtenberg, A. J. [Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, California 94720 (United States)] [Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, California 94720 (United States)

2013-10-15T23:59:59.000Z

251

Non-storm water discharges technical report  

SciTech Connect (OSTI)

Lawrence Livermore National Laboratory (LLNL) submitted a Notice of Intent to the California State Water Resources Control Board (hereafter State Board) to discharge storm water associated with industrial activities under the California General Industrial Activity Storm Water National Pollutant Elimination System Discharge Permit (hereafter General Permit). As required by the General Permit, LLNL provided initial notification of non-storm water discharges to the Central Valley Regional Water Quality Control Board (hereafter Regional Board) on October 2, 1992. Additional findings and progress towards corrective actions were reported in subsequent annual monitoring reports. LLNL was granted until March 27, 1995, three years from the Notice of Intent submission date, to eliminate or permit the non-storm water discharges. On May 20, 1994, the Regional Board issued Waste Discharge Requirements (WDR Board Order No. 94-131, NPDES No. CA0081396) to LLNL for discharges of non-contact cooling tower wastewater and storm water related to industrial activities. As a result of the issuance of WDR 94-131, LLNL rescinded its coverage under the General Permit. WDR 94-131 allowed continued non-storm water discharges and requested a technical report describing the discharges LLNL seeks to permit. For the described discharges, LLNL anticipates the Regional Board will either waive Waste Discharge Requirements as allowed for in The Water Quality Control Plan for the California Regional Water Quality Control Board, Central Valley Region (hereafter Basin Plan) or amend Board Order 94-131 as appropriate.

Mathews, S.

1994-07-01T23:59:59.000Z

252

Strategies for the Engineered Phytoremediation of Mercury and Arsenic Pollution  

SciTech Connect (OSTI)

Phytoremediation is the use of plants to extract, transport, detoxify and/or sequester pollutants of the land, water or air. Mercury and arsenic are among the worst environmental pollutants, adversely affecting the health of hundreds of millions of people worldwide. We have demonstrated that plants can be engineered to take up and tolerate several times the levels of mercury and arsenic that would kill most plant species. Starting with methylmercury and/or ionic mercury contamination, mercury is detoxified, stored below or above ground, and even volatilized as part of the transpiration process and keeping it out of the food chain. Initial efforts with arsenate demonstrate that it can be taken up, transported aboveground, electrochemically reduced to arsenite in leaves and sequestered in thiol-rich peptide complexes. The transgenic mercury remediation strategies also worked in cultivated and wild plant species like canola, rice and cottonwood.

Dhankher, Om Parkash; Meagher, Richard B.

2003-03-26T23:59:59.000Z

253

E-Print Network 3.0 - acute mercury inhalation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OF Summary: ECONOMIC COMMISSION FOR EUROPE Geneva HEMISPHERIC TRANSPORT OF AIR POLLUTION 2010 PART B: MERCURY... ......

254

E-Print Network 3.0 - abandoned halkoy mercury Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OF Summary: ECONOMIC COMMISSION FOR EUROPE Geneva HEMISPHERIC TRANSPORT OF AIR POLLUTION 2010 PART B: MERCURY... ......

255

Mercury Free UCI Environmental Health and Safety (EH&S) is sponsoring a  

E-Print Network [OSTI]

Thermometer Exchange Program to: · Reduce the health and environmental risks of mercury pollution, · ReduceMercury Free UCI Environmental Health and Safety (EH&S) is sponsoring a Laboratory Mercury. Principal Investigator Name: Lab Contact Name: Phone: Building: Room: 1. Number of Intact Mercury

George, Steven C.

256

Appendix: Mercury Emissions used in CAM-Chem/Hg model. 1. Anthropogenic emissions  

E-Print Network [OSTI]

Appendix: Mercury Emissions used in CAM-Chem/Hg model. 1. Anthropogenic emissions The anthropogenic emission of mercury is directly adopted from global mercury emission inventory [Pacyna et al., 2005]. The anthropogenic emissions are shown in annual averaged total mercury emissions. (Unit: µg/m2 /day) 2. Land

Meskhidze, Nicholas

257

Lifestyle and Mercury Contamination of Amerindian Populations along the Beni River  

E-Print Network [OSTI]

1 Lifestyle and Mercury Contamination of Amerindian Populations along the Beni River (Lowland (Corresponding author), M.D., Ph.D. Abstract The objective of this paper was to document mercury contamination at the foothills of the Andes. Hair mercury content (H-Hg) served as a bioindicator of mercury contamination

Paris-Sud XI, Université de

258

Apparatus and method for removing mercury vapor from a gas stream  

DOE Patents [OSTI]

A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

Ganesan, Kumar (Butte, MT)

2008-01-01T23:59:59.000Z

259

DESIGN OF THE MERCURY HANDLING SYSTEM FOR A MUON COLLIDER/NEUTRINO FACTORY TARGET  

E-Print Network [OSTI]

DESIGN OF THE MERCURY HANDLING SYSTEM FOR A MUON COLLIDER/NEUTRINO FACTORY TARGET V.B. Graves , Oak is a free mercury jet within a 20-T magnetic field being impacted by an 8-GeV proton beam. A pool of mercury serves as a receiving reservoir for the mercury and a dump for the unexpended proton beam. Modifications

McDonald, Kirk

260

Wavelengths, Energy Level Classifications, and Energy Levels for the Spectrum of Neutral Mercury  

E-Print Network [OSTI]

Wavelengths, Energy Level Classifications, and Energy Levels for the Spectrum of Neutral Mercury E of neutral mercury Hg I for both the single isotope 198 Hg and for mercury in its natural isotopic abundance of neutral mercury for both 198 Hg and the natural isotopic mixture. Tabular data for 105 classified lines

Magee, Joseph W.

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Mercury Trends in Multiple Fish Species in the Everglades Protection Area  

E-Print Network [OSTI]

Mercury Trends in Multiple Fish Species in the Everglades Protection Area Major Paper Nicole M. Howard Spring 2011 Soil and Water Science Department #12;2 Introduction Mercury in the South Florida-alkali facilities. When mercury-containing materials are burned or incinerated, mercury is released in gaseous

Ma, Lena

262

A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR  

SciTech Connect (OSTI)

Previous work on the detection of mercury using the cavity ring-down (CRD) technique has concentrated on the detection and characterization of the desired mercury transition. Interferent species present in flue gas emissions have been tested as well as a simulated flue gas stream. Additionally, work has been done on different mercury species such as the elemental and oxidized forms. The next phase of the effort deals with the actual sampling system. This sampling system will be responsible for acquiring a sample stream from the flue gas stack, taking it to the CRD cavity where it will be analyzed and returning the gas stream to the stack. In the process of transporting the sample gas stream every effort must be taken to minimize any losses of mercury to the walls of the sampling system as well as maintaining the mercury in its specific state (i.e. elemental, oxidized, or other mercury compounds). SRD first evaluated a number of commercially available sampling systems. These systems ranged from a complete sampling system to a number of individual components for specific tasks. SRD engineers used some commercially available components and designed a sampling system suited to the needs of the CRD instrument. This included components such as a pyrolysis oven to convert all forms of mercury to elemental mercury, a calibration air source to ensure mirror alignment and quality of the mirror surfaces, and a pumping system to maintain the CRD cavity pressure from atmospheric pressure (760 torr) down to about 50 torr. SRD also began evaluating methods for the CRD instrument to automatically find the center of a mercury transition. This procedure is necessary as the instrument must periodically measure the baseline losses of the cavity off of the mercury resonance and then return to the center of the transition to accurately measure the mercury concentration. This procedure is somewhat complicated due to the isotopic structure of the 254 nm mercury transition. As a result of 6 isotopes and hyperfine splittings there are 5 individual peaks that can be resolved by the CRD instrument. SRD tested a derivative method with both simulated data and actual data taken with the CRD apparatus. Initial tests indicate that this method is successful in automatically finding the center of the mercury transitions.

Christopher C. Carter, Ph.D.

2003-06-30T23:59:59.000Z

263

Site Discharge Pollution Prevention Plan (SDPPP)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SDPPP Individual Permit: Site Discharge Pollution Prevention Plan (SDPPP) The 2012 SDPPP update fully incorporates all changes made during the year and reflects changes projected...

264

EPA - National Pollutant Discharge Elimination System General...  

Open Energy Info (EERE)

General Permit for Discharges from Construction Activities Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: EPA -...

265

Device for generation of pulsed corona discharge  

DOE Patents [OSTI]

The invention is a method and system for the generation of high voltage, pulsed, periodic corona discharges capable of being used in the presence of conductive liquid droplets. The method and system can be used, for example, in different devices for cleaning of gaseous or liquid media using pulsed corona discharge. Specially designed electrodes and an inductor increase the efficiency of the system, permit the plasma chemical oxidation of detrimental impurities, and increase the range of stable discharge operations in the presence of droplets of water or other conductive liquids in the discharge chamber.

Gutsol, Alexander F. (San Ramon, CA); Fridman, Alexander (Marlton, NJ); Blank, Kenneth (Philadelphia, PA); Korobtsev, Sergey (Moscow, RU); Shiryaevsky, Valery (Moscow, RU); Medvedev, Dmitry (Moscow, RU)

2012-05-08T23:59:59.000Z

266

Oil and Hazardous Substance Discharge Preparedness (Minnesota)  

Broader source: Energy.gov [DOE]

Anyone who owns or operates a vessel or facility that transports, stores, or otherwise handles hazardous wastes must take reasonable steps to prevent the discharge of those materials.

267

Leaching of Phase II Mercury Control Technology By-Products  

SciTech Connect (OSTI)

The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

Hesbach, P.A.; Kachur, E.K.

2007-07-01T23:59:59.000Z

268

Fundamentals of Mercury Oxidation in Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

2005-08-01T23:59:59.000Z

269

ElectricOIL discharge and post-discharge kinetics experiments and modeling  

E-Print Network [OSTI]

oxygen, ozone, and other excited species adds levels of complexity to the singlet oxygen generator (SOG has been obtained by a near resonant energy transfer from O2(a1 ) produced using a lowpressure oxygen/helium/nitric-oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic

Carroll, David L.

270

Advanced Utility Mercury-Sorbent Field-Testing Program  

SciTech Connect (OSTI)

This report summarizes the work conducted from September 1, 2003 through December 31, 2007 on the project entitled Advanced Utility Mercury-Sorbent Field-Testing Program. The project covers the testing at the Detroit Edison St. Clair Plant and the Duke Power Cliffside and Buck Stations. The St. Clair Plant used a blend of subbituminous and bituminous coal and controlled the particulate emissions by means of a cold-side ESP. The Duke Power Stations used bituminous coals and controlled their particulate emissions by means of hot-side ESPs. The testing at the Detroit Edison St. Clair Plant demonstrated that mercury sorbents could be used to achieve high mercury removal rates with low injection rates at facilities that burn subbituminous coal. A mercury removal rate of 94% was achieved at an injection rate of 3 lb/MMacf over the thirty day long-term test. Prior to this test, it was believed that the mercury in flue gas of this type would be the most difficult to capture. This is not the case. The testing at the two Duke Power Stations proved that carbon- based mercury sorbents can be used to control the mercury emissions from boilers with hot-side ESPs. It was known that plain PACs did not have any mercury capacity at elevated temperatures but that brominated B-PAC did. The mercury removal rate varies with the operation but it appears that mercury removal rates equal to or greater than 50% are achievable in facilities equipped with hot-side ESPs. As part of the program, both sorbent injection equipment and sorbent production equipment was acquired and operated. This equipment performed very well during this program. In addition, mercury instruments were acquired for this program. These instruments worked well in the flue gas at the St. Clair Plant but not as well in the flue gas at the Duke Power Stations. It is believed that the difference in the amount of oxidized mercury, more at Duke Power, was the difference in instrument performance. Much of the equipment was purchased used and all of the equipment has nearly reached the end of its useful service.

Ronald Landreth

2007-12-31T23:59:59.000Z

271

Proton induced activation in mercury: Comparison of measurements and calculations  

SciTech Connect (OSTI)

Measurements and simulations of the proton beam interaction with the mercury target were performed to support Spallation Neutron Source design. Due to the abundance of isotopes produced in mercury, the long delay between the irradiation and the measurements, and the self-shielding of the mercury sample, the measurements were difficult to perform and the activities of several isotopes have large uncertainties. Calculations predicted the activities of the most reliably measured isotopes within 20%/40%; however, some large discrepancies were observed for some isotopes for which the measurements were considered less reliable. Predicted dose rates were in very good agreement with the measurements.

Remec, Igor [ORNL; Glasgow, David C [ORNL; Haines, John R [ORNL; Johnson, Jeffrey O [ORNL

2008-01-01T23:59:59.000Z

272

Mixed Waste Focus Area mercury contamination product line: An integrated approach to mercury waste treatment and disposal  

SciTech Connect (OSTI)

The US Department of Energy (DOE) Mixed Waste Focus Area (MWFA) is tasked with ensuring that solutions are available for the mixed waste treatment problems of the DOE complex. During the MWFA`s initial technical baseline development process, three of the top four technology deficiencies identified were related to the need for amalgamation, stabilization, and separation/removal technologies for the treatment of mercury and mercury-contaminated mixed waste. The focus area grouped mercury-waste-treatment activities into the mercury contamination product line under which development, demonstration, and deployment efforts are coordinated to provide tested technologies to meet the site needs. The Mercury Working Group (HgWG), a selected group of representatives from DOE sites with significant mercury waste inventories, is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these areas. Based on the scope and magnitude of the mercury mixed waste problem, as defined by HgWG, solicitations and contract awards have been made to the private sector to demonstrate amalgamation and stabilization processes using actual mixed wastes. Development efforts are currently being funded under the product line that will address DOE`s needs for separation/removal processes. This paper discusses the technology selection process, development activities, and the accomplishments of the MWFA to date through these various activities.

Hulet, G.A. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Conley, T.B.; Morris, M.I. [Oak Ridge National Lab., TN (United States)

1998-07-01T23:59:59.000Z

273

Plasma discharge self-cleaning filtration system  

DOE Patents [OSTI]

The present invention is directed to a novel method for cleaning a filter surface using a plasma discharge self-cleaning filtration system. The method involves utilizing plasma discharges to induce short electric pulses of nanoseconds duration at high voltages. These electrical pulses generate strong Shockwaves that disintegrate and dislodge particulate matter located on the surface of the filter.

Cho, Young I.; Fridman, Alexander; Gutsol, Alexander F.; Yang, Yong

2014-07-22T23:59:59.000Z

274

Kinetic Effects In Hall Thruster Discharge  

E-Print Network [OSTI]

of a capacitive discharge. 4 capacitive discharge. For more info: V. Godyak, IEEE TPS 34, 755 (2006). #12 th twall interactions in Hall thrusters Large electron temperature andE JH~1cm secondary electron emission result in large particle and wall losses to the wall E , Jz z Br H~1cm 120 eV High SEE BN channel

Kaganovich, Igor

275

Atmospheric sampling glow discharge ionization source  

DOE Patents [OSTI]

An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

McLuckey, S.A.; Glish, G.L.

1989-07-18T23:59:59.000Z

276

BEHAVIOR OF MERCURY DURING DWPF CHEMICAL PROCESS CELL PROCESSING  

SciTech Connect (OSTI)

The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower retention of mercury in the slurry. Both recovery of mercury in the offgas system and removal (segregation + recovery) from the slurry correlate with slurry consistency. Higher slurry consistency results in better retention of Hg in the slurry (less segregation) and better recovery in the offgas system, but the relationships of recovery and retention with consistency are sludge dependent. Some correlation with slurry yield stress and acid stoichiometry was also found. Better retention of mercury in the slurry results in better recovery in the offgas system because the mercury in the slurry is stripped more easily than the segregated mercury at the bottom of the vessel. Although better retention gives better recovery, the time to reach a particular slurry mercury content (wt%) is longer than if the retention is poorer because the segregation is faster. The segregation of mercury is generally a faster process than stripping. The stripping factor (mass of water evaporated per mass of mercury stripped) of mercury at the start of boiling were found to be less than 1000 compared to the assumed design basis value of 750 (the theoretical factor is 250). However, within two hours, this value increased to at least 2000 lb water per lb Hg. For runs with higher mercury recovery in the offgas system, the stripping factor remained around 2000, but runs with low recovery had stripping factors of 4000 to 40,000. DWPF data shows similar trends with the stripping factor value increasing during boiling. These high values correspond to high segregation and low retention of mercury in the sludge. The stripping factor for a pure Hg metal bead in water was found to be about 10,000 lb/lb. About 10-36% of the total Hg evaporated in a SRAT cycle was refluxed back to the SRAT during formic acid addition and boiling. Mercury is dissolved as a result of nitric acid formation from absorption of NO{sub x}. The actual solubility of dissolved mercury in the acidic condensate is about 100 times higher than the actual concentrations measured. Mercury metal present in the MWWT from previous batch

Zamecnik, J.; Koopman, D.

2012-04-09T23:59:59.000Z

277

Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Page 1 Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks  

E-Print Network [OSTI]

Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Page 1 Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Heidi Borchers University of New Hampshire, Environmental Ultraviolet (UV) lamps generate ultraviolet light through the vaporization of elemental mercury, by using

278

Patterns of mercury and methylmercury bioaccumulation in fish species downstream of a long-term mercury-contaminated site in the lower Ebro River  

E-Print Network [OSTI]

Patterns of mercury and methylmercury bioaccumulation in fish species downstream of a long-term mercury-contaminated site in the lower Ebro River (NE Spain) Luis Carrasco a , Carlos Barata a , Emili Received in revised form 4 May 2011 Accepted 6 May 2011 Available online 12 June 2011 Keywords: Mercury

García-Berthou, Emili

279

Mercury Delivery System Tony Gabriel, Phil Spampinato  

E-Print Network [OSTI]

Concept Hydraulic Fluid Cylinder (3000 psi) Hg Cylinder (1000 psi) Hg Discharge Hg Inlet #12;6 OAK RIDGE losses isolated to hydraulic system - Flow losses identical to those in pump system #12;8 OAK RIDGE Motor 20 20 hp * 5% inefficiency 1 19 42 42 1 1 Hyd Pump energy performed on piston = press

McDonald, Kirk

280

Evaluation of Background Mercury Concentrations in the SRS Groundwater System  

SciTech Connect (OSTI)

Mercury analyses associated with the A-01 Outfall have highlighted the importance of developing an understanding of mercury in the Savannah River Site groundwater system and associated surface water streams. This activity is critical based upon the fact that the EPA Ambient Water Quality Criteria (AWQC) for this constituent is 0.012mg/L, a level that is well below conventional detection limits of 0.1 to 0.2 mg/L. A first step in this process is obtained by utilizing the existing investment in groundwater mercury concentrations (20,242 records) maintained in the SRS geographical information management system (GIMS) database. Careful use of these data provides a technically defensible initial estimate for total recoverable mercury in background and contaminated SRS wells.

Looney, B.B.

1999-03-03T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Long-Term Management and Storage of Elemental Mercury | Department...  

Office of Environmental Management (EM)

Mercury Export Ban Act of 2008 (MEBA) (Public Law No. 110-414) requires the Department of Energy (DOE) to establish a facility for the long-term management and storage of elemental...

282

Mercury Isotope Fractionation by Environmental Transport and Transformation Processes  

E-Print Network [OSTI]

measuring Hg 0 that permeated PVC tubing and matching this26 Chapter 3 Elemental Mercury Diffusion in a PVC29 Figure 3.2 The setup for diffusion in PVC

Koster van Groos, Paul Gijsbert

2011-01-01T23:59:59.000Z

283

Transformations of mercury in the marine water column  

E-Print Network [OSTI]

Methylation of mercury (Hg) in the marine water column has been hypothesized to serve as the primary source of the bioaccumulating chemical species monomethylmercury (MMHg) to marine food webs. Despite decades of research ...

Munson, Kathleen M. (Kathleen May)

2014-01-01T23:59:59.000Z

284

Surface Mercury Geochemistry As A Guide To Volcanic Vent Structure...  

Open Energy Info (EERE)

to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Surface Mercury Geochemistry As A Guide To Volcanic Vent Structure And Zones Of High Heat Flow In The...

285

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System  

E-Print Network [OSTI]

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

Carroll, David L.

286

Discharge lamp with reflective jacket  

DOE Patents [OSTI]

A discharge lamp includes an envelope, a fill which emits light when excited disposed in the envelope, a source of excitation power coupled to the fill to excite the fill and cause the fill to emit light, and a reflector disposed around the envelope and defining an opening, the reflector being configured to reflect some of the light emitted by the fill back into the fill while allowing some light to exit through the opening. The reflector may be made from a material having a similar thermal index of expansion as compared to the envelope and which is closely spaced to the envelope. The envelope material may be quartz and the reflector material may be either silica or alumina. The reflector may be formed as a jacket having a rigid structure which does not adhere to the envelope. The lamp may further include an optical clement spaced from the envelope and configured to reflect an unwanted component of light which exited the envelope back into the envelope through the opening in the reflector. Light which can be beneficially recaptured includes selected wavelength regions, a selected polarization, and selected angular components.

MacLennan, Donald A. (Gaithersburg, MD); Turner, Brian P. (Damascus, MD); Kipling, Kent (Gaithersburg, MD)

2001-01-01T23:59:59.000Z

287

Fluid jet electric discharge source  

DOE Patents [OSTI]

A fluid jet or filament source and a pair of coaxial high voltage electrodes, in combination, comprise an electrical discharge system to produce radiation and, in particular, EUV radiation. The fluid jet source is composed of at least two serially connected reservoirs, a first reservoir into which a fluid, that can be either a liquid or a gas, can be fed at some pressure higher than atmospheric and a second reservoir maintained at a lower pressure than the first. The fluid is allowed to expand through an aperture into a high vacuum region between a pair of coaxial electrodes. This second expansion produces a narrow well-directed fluid jet whose size is dependent on the size and configuration of the apertures and the pressure used in the reservoir. At some time during the flow of the fluid filament, a high voltage pulse is applied to the electrodes to excite the fluid to form a plasma which provides the desired radiation; the wavelength of the radiation being determined by the composition of the fluid.

Bender, Howard A. (Ripon, CA)

2006-04-25T23:59:59.000Z

288

Noble metal catalysts for oxidation of mercury in flue gas  

SciTech Connect (OSTI)

The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

Presto, A.A.; Granite, E.J.

2008-04-01T23:59:59.000Z

289

A survey of mercury in the Gulf of Mexico  

E-Print Network [OSTI]

' artificial levels of mercury, which have accumulated as the result of man's activities. In keeping with this philosophy or concept, an oxidation procedure must then be adopted which would be effective enough to digest all organic matter including...A SURVEY OF MERCURY IN TIU' GULF OF MEXICO A Thesis GEORGE LOUIS CUSTODI Sutznitted to the Graduate Colic. e cf Texas Ac";-. M Univer. sit;, in partial fulfillment of' the quirement fo-, . MASTER OF SCIENCE Decor@her 1971 Major Suh, ject...

Custodi, George Louis

1971-01-01T23:59:59.000Z

290

Thiacrown polymers for removal of mercury from waste streams  

DOE Patents [OSTI]

Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

Baumann, Theodore F. (Tracy, CA); Reynolds, John G. (San Ramon, CA); Fox, Glenn A. (Livermore, CA)

2002-01-01T23:59:59.000Z

291

Mercury Contamination in Pelagic Fishes of the Gulf of Mexico  

E-Print Network [OSTI]

2 Map of sampling locations at the docks and offshore from ` Freeport and Port Aransas, Texas, and Venice, Louisiana, in the NW of Gulf of Mexico. .................................................................... 11 3 Mean Hg concentration...). Figure 1 Mercury cycling and bioaccumulation in aquatic system (Engstrom 2007). Elemental Hg can be oxidized by chemical reactions that depend on ozone, solar energy and water content in the atmosphere. Mercury oxidation is a photochemical 6...

Kuklyte, Ligita

2012-10-19T23:59:59.000Z

292

Treatment of Mercury Contaminated Oil from the Mound Site  

SciTech Connect (OSTI)

Over one thousand gallons of tritiated oil, at various contamination levels, are stored in the Main Hill Tritium Facility at the Miamisburg Environmental Management Project (MEMP), commonly referred to as Mound Site. This tritiated oil is to be characterized for hazardous materials and radioactive contamination. Most of the hazardous materials are expected to be in the form of heavy metals, i.e., mercury, silver, lead, chromium, etc, but transuranic materials and PCBs could also be in some oils. Waste oils, found to contain heavy metals as well as being radioactively contaminated, are considered as mixed wastes and are controlled by Resource Conservation and Recovery Act (RCRA) regulations. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory (PNNL) for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds. The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury.

Klasson, KT

2000-11-09T23:59:59.000Z

293

Electrolytic recovery of mercury enriched in isotopic abundance  

DOE Patents [OSTI]

The present invention is directed to a method of electrolytically extracting liquid mercury from HgO or Hg.sub.2 Cl.sub.2. Additionally there are disclosed two related techniques associated with the present invention, namely (1) a technique for selectively removing product from different regions of a long photochemical reactor (photoreactor) and (2) a method of accurately measuring the total quantity of mercury formed as either HgO or Hg.sub.2 Cl.sub.2.

Grossman, Mark W. (Belmont, MA)

1991-01-01T23:59:59.000Z

294

Method and apparatus for controlling the flow rate of mercury in a flow system  

DOE Patents [OSTI]

A method for increasing the mercury flow rate to a photochemical mercury enrichment utilizing an entrainment system comprises the steps of passing a carrier gas over a pool of mercury maintained at a first temperature T1, wherein the carrier gas entrains mercury vapor; passing said mercury vapor entrained carrier gas to a second temperature zone T2 having temperature less than T1 to condense said entrained mercury vapor, thereby producing a saturated Hg condition in the carrier gas; and passing said saturated Hg carrier gas to said photochemical enrichment reactor.

Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

1991-01-01T23:59:59.000Z

295

Mercury control challenge for industrial boiler MACT affected facilities  

SciTech Connect (OSTI)

An industrial coal-fired boiler facility conducted a test program to evaluate the effectiveness of sorbent injection on mercury removal ahead of a fabric filter with an inlet flue gas temperature of 375{sup o}F. The results of the sorbent injection testing are essentially inconclusive relative to providing the facility with enough data upon which to base the design and implementation of permanent sorbent injection system(s). The mercury removal performance of the sorbents was significantly less than expected. The data suggests that 50 percent mercury removal across a baghouse with flue gas temperatures at or above 375{sup o}F and containing moderate levels of SO{sub 3} may be very difficult to achieve with activated carbon sorbent injection alone. The challenge many coal-fired industrial facilities may face is the implementation of additional measures beyond sorbent injection to achieve high levels of mercury removal that will likely be required by the upcoming new Industrial Boiler MACT rule. To counter the negative effects of high flue gas temperature on mercury removal with sorbents, it may be necessary to retrofit additional boiler heat transfer surface or spray cooling of the flue gas upstream of the baghouse. Furthermore, to counter the negative effect of moderate or high SO{sub 3} levels in the flue gas on mercury removal, it may be necessary to also inject sorbents, such as trona or hydrated lime, to reduce the SO{sub 3} concentrations in the flue gas. 2 refs., 1 tab.

NONE

2009-09-15T23:59:59.000Z

296

MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT  

SciTech Connect (OSTI)

Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

M.A. Ebadian, Ph.D.

2001-01-01T23:59:59.000Z

297

Mercury and cause of death in great white herons  

SciTech Connect (OSTI)

Mercury contamination is suspected to adversely affect wading birds in southern Florida. To determine the magnitude of contamination associated with cause of death we followed 3 adult and 19 juvenile radio-tagged great white herons (Ardea herodias occidentalis), recovered them soon after death, and determined liver mercury content and cause of death. Birds that died from acute causes had less (P < 0.001) mercury in their livers (geometric [bar x] [GM] = 1.77 ppm wet mass [wm], range 0.6-4.0 ppm, n = 9) than did those that died of chronic, often multiple, diseases (GM = 9.76 ppm, range 2.9-59.4 ppm, n = 13). Juvenile herons that migrated to mainland Florida accumulated more (P = 0.009) mercury in their livers than those that did not migrate. Kidney disease and gout were present in birds that died with >25 ppm wm liver mercury. Although detrimental to the health of wading birds, mercury contamination is presumably more detrimental to their reproductive efforts; therefore, an understanding of its ill effects is important in the management of these birds. 29 refs., 1 fig.

Spalding, M.G.; Sundlof, S.F. (Univ. of Florida, Gainesville, FL (United States)); Djork, R.D.; Powell, G.V.N. (National Audobon Research, Tavernier, FL (United States))

1994-10-01T23:59:59.000Z

298

Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases  

DOE Patents [OSTI]

Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

Nelson, Sidney (Hudson, OH)

2011-02-15T23:59:59.000Z

299

Direct Measurement of Mercury Reactions In Coal Power Plant Plumes  

SciTech Connect (OSTI)

Recent field and pilot-scale results indicate that divalent mercury emitted from power plants may rapidly transform to elemental mercury within the power plant plumes. Simulations of mercury chemistry in plumes based on measured rates to date have improved regional model fits to Mercury Deposition Network wet deposition data for particular years, while not degrading model verification fits for remaining years of the ensemble. The years with improved fit are those with simulated deposition in grid cells in the State of Pennsylvania that have matching MDN station data significantly less than the model values. This project seeks to establish a full-scale data basis for whether or not significant reduction or oxidation reactions occur to mercury emitted from coal-fired power plants, and what numerical redox rate should apply for extension to other sources and for modeling of power plant mercury plumes locally, regionally, and nationally. Although in-stack mercury (Hg) speciation measurements are essential to the development of control technologies and to provide data for input into atmospheric fate and transport models, the determination of speciation in a cooling coal combustion plume is more relevant for use in estimating Hg fate and effects through the atmosphere. It is mercury transformations that may occur in the plume that determine the eventual rate and patterns of mercury deposited to the earth's surface. A necessary first step in developing a supportable approach to modeling any such transformations is to directly measure the forms and concentrations of mercury from the stack exit downwind to full dispersion in the atmosphere. As a result, a study was sponsored by EPRI and jointly funded by EPRI, the U.S Department of Energy (DOE), and the Wisconsin Department of Administration. The study was designed to further our understanding of plume chemistry. The study was carried out at the We Energies Pleasant Prairie Power Plant, Pleasant Prairie, Wisconsin, just west of Kenosha. Aircraft and ground measurements support the occurrence of a reduction in the fraction of reactive gaseous mercury (RGM) (with a corresponding increase in elemental mercury) as part of the Total Gaseous Mercury (TGM) emitted from the Pleasant Prairie stack. This occurrence is based on comparison of the RGM concentrations in the plume (at standard conditions) compared to the RGM in the stack. There was found to be a 44% drop in the fraction of RGM between the stack exit and the first sampling arc and a 66% reduction from the stack to the 5-mile sampling arc, with no additional drop between the 5- and 10-mile arcs. Smaller-scale experiments in both test chambers and pilot-scale coal combustor exhaust streams have indicated the presence of rapid and relatively complete reduction reactions converting divalent into elemental mercury within power plant plumes prior to full dispersion in the atmosphere. These measurements, however, have been unable to identify whether the reactions occur during plume rise from physical to virtual stack height (during positive thermal buoyancy). The presence, rate, completeness, ubiquity, and dependence on source characteristics of these reactions, however, must be demonstrated in plume environments associated with fully operational power plants. That requirement, to capture either the reactions or the reaction products of chemistry that may be occurring very close to stack exits in highly turbulent environments, constrains the precision and reproducibility with which such full-scale experiments can be carried out. The work described here is one of several initial steps required to test whether, and in what direction, such rapid mercury redox reactions might be occurring in such plumes.

Leonard Levin

2005-12-31T23:59:59.000Z

300

Mercury Emission Control Technologies for PPL Montana-Colstrip Testing  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) was asked by PPL Montana LLC (PPL) to provide assistance and develop an approach to identify cost-effective options for mercury control at its coal-fired power plants. The work conducted focused on baseline mercury level and speciation measurement, short-term parametric testing, and week long testing of mercury control technology at Colstrip Unit 3. Three techniques and various combinations of these techniques were identified as viable options for mercury control. The options included oxidizing agents or sorbent enhancement additives (SEAs) such as chlorine-based SEA1 and an EERC proprietary SEA2 with and without activated carbon injection. Baseline mercury emissions from Colstrip Unit 3 are comparatively low relative to other Powder River Basin (PRB) coal-fired systems and were found to range from 5 to 6.5 g/Nm3 (2.9 to 3.8 lb/TBtu), with a rough value of approximately 80% being elemental upstream of the scrubber and higher than 95% being elemental at the outlet. Levels in the stack were also greater than 95% elemental. Baseline mercury removal across the scrubber is fairly variable but generally tends to be about 5% to 10%. Parametric results of carbon injection alone yielded minimal reduction in Hg emissions. SEA1 injection resulted in 20% additional reduction over baseline with the maximum rate of 400 ppm (3 gal/min). Week long testing was conducted with the combination of SEA2 and carbon, with injection rates of 75 ppm (10.3 lb/hr) and 1.5 lb/MMacf (40 lb/hr), respectively. Reduction was found to be an additional 30% and, overall during the testing period, was measured to be 38% across the scrubber. The novel additive injection method, known as novel SEA2, is several orders of magnitude safer and less expensive than current SEA2 injection methods. However, used in conjunction with this plant configuration, the technology did not demonstrate a significant level of mercury reduction. Near-future use of this technique at Colstrip is not seen. All the additives injected resulted in some reduction in mercury emissions. However, the target reduction of 55% was not achieved. The primary reason for the lower removal rates is because of the lower levels of mercury in the flue gas stream and the lower capture level of fine particles by the scrubbers (relative to that for larger particles). The reaction and interaction of the SEA materials is with the finer fraction of the fly ash, because the SEA materials are vaporized during the combustion or reaction process and condense on the surfaces of entrained particles or form very small particles. Mercury will have a tendency to react and interact with the finer fraction of entrained ash and sorbent as a result of the higher surface areas of the finer particles. The ability to capture the finer fraction of fly ash is the key to controlling mercury. Cost estimates for mercury removal based on the performance of each sorbent during this project are projected to be extremely high. When viewed on a dollar-per-pound-of-mercury removed basis activated carbon was projected to cost nearly $1.2 million per pound of mercury removed. This value is roughly six times the cost of other sorbent-enhancing agents, which were projected to be closer to $200,000 per pound of mercury removed.

John P. Kay; Michael L. Jones; Steven A. Benson

2007-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Treatment of Mercury Contaminated Oil from Sandia National Laboratory  

SciTech Connect (OSTI)

First Article Tests of a stabilization method for greater than 260 mg mercury/kg oil were performed under a treatability study. This alternative treatment technology will address treatment of U.S. Department of Energy (DOE) organics (mainly used pump oil) contaminated with mercury and other heavy metals. Some of the oil is also co-contaminated with tritium, other radionuclides, and hazardous materials. The technology is based on contacting the oil with a sorbent powder (Self-Assembled Mercaptan on Mesoporous Support, SAMMS), proven to adsorb heavy metals, followed by stabilization of the oil/powder mixture using a stabilization agent (Nochar N990). Two variations of the treatment technology were included in the treatability study. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents [1]. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds [1] The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury. Nochar's N990 Petrobond (Nochar, Inc., Indianapolis, IN) is an oil stabilization agent, specifically formulated for stabilizing vacuum pump oil, which has fewer volatile organics than many other oils. This material is a non-uniform granular powder that resembles ground Styrofoam plastics. This material has previously been used by itself and in combination with SAMMS to stabilize oil containing low levels of mercury {approx}50 mg/kg in surrogate waste studies [2].

Klasson, KT

2002-05-28T23:59:59.000Z

302

Glow discharge plasma deposition of thin films  

DOE Patents [OSTI]

A glow discharge plasma reactor for deposition of thin films from a reactive RF glow discharge is provided with a screen positioned between the walls of the chamber and the cathode to confine the glow discharge region to within the region defined by the screen and the cathode. A substrate for receiving deposition material from a reactive gas is positioned outside the screened region. The screen is electrically connected to the system ground to thereby serve as the anode of the system. The energy of the reactive gas species is reduced as they diffuse through the screen to the substrate. Reactive gas is conducted directly into the glow discharge region through a centrally positioned distribution head to reduce contamination effects otherwise caused by secondary reaction products and impurities deposited on the reactor walls.

Weakliem, Herbert A. (Pennington, NJ); Vossen, Jr., John L. (Bridgewater, NJ)

1984-05-29T23:59:59.000Z

303

Mercury in Fish Collected Upstream and Downstream of Los Alamos National Laboratory, New Mexico: 1991--2004.  

SciTech Connect (OSTI)

Small amounts of mercury (Hg) may exist in some canyon drainage systems within Los Alamos National Laboratory lands as a result of past discharges of untreated effluents. This paper reports on the concentrations of Hg in muscle (fillets) of various types of fish species collected downstream of LANL's influence from 1991 through 2004. The mean Hg concentration in fish from Cochiti reservoir (0.22 {micro}g/g wet weight), which is located downstream of LANL, was similar to fish collected from a reservoir upstream of LANL (Abiquiu) (0.26 {micro}g/g wet weight). Mercury concentrations in fish collected from both reservoirs exhibited significantly (Abiquiu = p < 0.05 and Cochiti = p < 0.10) decreasing trends over time. Predator fish like the northern pike (Esox lucius) contained significantly higher concentrations of Hg (0.39 {micro}g/g wet weight) than bottom-feeding fish like the white sucker (Catostomus commersoni) (0.10 {micro}g/g wet weight).

P.R. Fresquez

2004-10-15T23:59:59.000Z

304

Discharge dynamics of pin-to-plate dielectric barrier discharge at atmospheric pressure  

SciTech Connect (OSTI)

The discharge dynamics of pin-to-plate dielectric barrier discharge was studied in atmospheric helium at 20 kHz. The discharge was predominately ignited in positive half cycle of applied voltage with sinusoidal waveform. The temporal evolution of the discharge was investigated vertically along the discharge gap and radically on the dielectric surface by time resolved imaging. It is found that a discharge column with a diameter of 2 mm was ignited above the pin electrode and expanded toward a plate electrode. On the dielectric surface with space charge accumulation, plasma disk in terms of plasma ring was formed with radius up to 25 mm. The expansion velocity of plasma ring can reach a hypersonic speed of 3.0 km/s. The ionization wave due to electron diffusion is considered to be the mechanism for plasma ring formation and dynamics.

Sun Liqun [College of Science, Donghua University, Shanghai 201620 (China); Huang, Xiaojiang [College of Science, Donghua University, Shanghai 201620 (China); Member of Magnetic Confinement Fusion Research Center, Ministry of Education of the People's Republic of China, Shanghai 201620 (China); Zhang Jie [College of Science, Donghua University, Shanghai 201620 (China); State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620 (China); Zhang Jing; Shi, J. J. [College of Science, Donghua University, Shanghai 201620 (China); State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620 (China); Member of Magnetic Confinement Fusion Research Center, Ministry of Education of the People's Republic of China, Shanghai 201620 (China)

2010-11-15T23:59:59.000Z

305

Impedance response to induced epileptiform discharges  

E-Print Network [OSTI]

Subject: Bioengineering IMPEDANCE RESPONSE TO INDUCED EPILEPTIFORM DISCHARGES A Thesis by TERRY LYNN GERBER Approved as to style and content by erald E. Miller ( irman of Committee) William A. H an (Member) / , I / vW C' (gp frt 't- Thomas... W. Adair (Member) Newton C. Ellis (Head of Department) May 1984 ABSTRACT Impedance Response to Induced Epileptiform Discharges. (May 1984) Terry Lynn Gerber, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. Gerald E. Miller...

Gerber, Terry Lynn

2012-06-07T23:59:59.000Z

306

Argonne/EPA system captures mercury from air in gold shops |...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the mercury vaporizes. The vaporized mercury is directed outside the shop into the open air where it descends onto homes, water and food of the local populations. Image credit:...

307

Quantifying the health and economic impacts of mercury : an integrated assessment approach  

E-Print Network [OSTI]

Mercury is a toxic pollutant that endangers human and ecosystem health. Especially potent in the form of methyl mercury, exposure is known to lead to adverse neurological effects, and, a growing body of evidence suggests, ...

Giang, Amanda (Amanda Chi Wen)

2013-01-01T23:59:59.000Z

308

Trimeric perfluoro-ortho-phenylene mercury as a building block for supramolecular materials  

E-Print Network [OSTI]

Trimeric perfluoro-ortho-phenylene mercury (1) constitutes one of the simplest trifunctional Lewis acidic hosts. Cooperative effects arising from the proximity of the mercury(II) centers, the electron-withdrawing properties of the backbone...

Haneline, Mason Reames

2006-04-12T23:59:59.000Z

309

E-Print Network 3.0 - arsenic cadmium mercury Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CARR,AND H. MILLER. 1972. Total... mercury. (Lond.)254:238-239. 12;LUNDE, G. 1970. Analysis of arsenic and selenium in marine raw materials... MERCURY AND SELENIUM IN BLUE...

310

E-Print Network 3.0 - aluminum mercuric mercury Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(II) mercuric mercury, doubly ionized (Hg2... . Mercury (among other heavy metals) is toxic to living organisms that have not de- veloped mechanisms... to cope with it. As one...

311

REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION  

SciTech Connect (OSTI)

Oxidized mercury has been shown to be more easily removed from power plant flue gas by existing air pollution control equipment (e.g., wet scrubbers) than elemental mercury. The factors that determine how mercury is converted to the oxidized form in practical systems are, however, unknown. The present research focuses on developing an elementary, homogeneous mechanism that describes the oxidation of mercury by chlorine species as it occurs in practical furnaces. The goal is to use this mechanism (1) as a component in an overall homogeneous/heterogeneous mechanism that describes mercury behavior, and (2) to suggest low cost/low impact means of promoting mercury oxidation in furnaces. The results suggest an important role for Hg+Cl {r_arrow} HgCl and HgCl + Cl {r_arrow} HgCl{sub 2}. Here, the Cl is derived by radical attack on HCl in the high-temperature environment. The results suggest that the oxidation occurs during the time that the gases cool to room temperature. The high Cl concentrations from the flame persist into the quench region and provide for the oxidation of Hg to HgCl{sub 2} under lower temperatures where the products are stable. Under this mechanism, no significant HgCl{sub 2} is actually present at the higher temperatures where oxidized mercury is often reported in the literature (e.g., 900 C). Instead, all oxidation occurs as these gases are quenched. The results suggest that means of promoting Cl concentrations in the furnace will increase oxidation.

John C. Kramlich; Rebecca N. Sliger

2000-08-26T23:59:59.000Z

312

Mercury Methylation at Mercury Mines In The Humboldt River Basin, Nevada, USA  

SciTech Connect (OSTI)

Total Hg and methylmercury concentrations were measured in mine-waste calcines (retorted ore), sediment, and water samples collected in and around abandoned mercury mines in western Nevada to evaluate Hg methylation at the mines and in the Humboldt River basin. Mine-waste calcines contain total Hg concentrations as high as 14 000?g/g. Stream-sediment samples collected within 1 km of the mercury mines contain total Hg concentrations as high as 170?g/g, whereas stream sediments collected>5 km from the mines, and those collected from the Humboldt River and regional baseline sites, contain total Hg concentrations<0.5?g/g. Similarly, methylmercury concentrations in mine-waste calcines are locally as high as 96 ng/g, but methylmercury contents in stream-sediments collected downstream from the mines and from the Humboldt River are lower, ranging from<0.05 to 0.95 ng/g. Stream-water samples collected below two mines studied contain total Hg concentrations ranging from 6 to 2000 ng/L, whereas total Hg in Humboldt River water was generally lower ranging from 2.1 to 9.0 ng/L. Methylmercury concentrations in the Humboldt River water were the lowest in this study (<0.02-0.27 ng/L). Although total Hg and methylmercury concentrations are locally high in mine-waste calcines, there is significant dilution of Hg and lower Hg methylation down gradient from the mines, especially in the sediments and water collected from the Humboldt River, which is> 8 km from any mercury mines. Our data indicate little transference of Hg and methylmercury from the sediment to the water column due to the lack of mine runoff in this desert climate.

Gray, John E. (U.S. Geological Survey); Crock, James G. (U.S. Geological Survey); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2002-12-01T23:59:59.000Z

313

Magnetic dipole discharges. II. Cathode and anode spot discharges and probe diagnostics  

SciTech Connect (OSTI)

The high current regime of a magnetron-type discharge has been investigated. The discharge uses a permanent magnet as a cold cathode which emits secondary electrons while the chamber wall or a grounded electrode serves as the anode. As the discharge voltage is increased, the magnet develops cathode spots, which are short duration arcs that provide copious electrons to increase the discharge current dramatically. Short (1 ?s), high current (200 A) and high voltage (750 V) discharge pulses are produced in a relaxation instability between the plasma and a charging capacitor. Spots are also observed on a negatively biased plane Langmuir probe. The probe current pulses are as large as those on the magnet, implying that the high discharge current does not depend on the cathode surface area but on the properties of the spots. The fast current pulses produce large inductive voltages, which can reverse the electrical polarity of the magnet and temporarily operate it as an anode. The discharge current may also oscillate at the frequency determined by the charging capacitor and the discharge circuit inductance. Each half cycle of high-current current pulses exhibits a fast (?10 ns) current rise when a spot is formed. It induces high frequency (10100 MHz) transients and ringing oscillations in probes and current circuits. Most probes behave like unmatched antennas for the electromagnetic pulses of spot discharges. Examples are shown to distinguish the source of oscillations and some rf characteristics of Langmuir probes.

Stenzel, R. L.; Urrutia, J. M. [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States)] [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States); Ionita, C.; Schrittwieser, R. [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)] [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)

2013-08-15T23:59:59.000Z

314

Note: Production of a mercury beam with an electron cyclotron resonance ion source  

SciTech Connect (OSTI)

An electron cyclotron resonance ion source has been utilized to produce mercury beams with intensities of 4.5 e?A of {sup 202}Hg{sup 29+} and 3.0 e?A of {sup 202}Hg{sup 31+} from natural abundance mercury metal. The production technique relies on the evaporation of liquid mercury into the source plasma vacuum region and utilizes elemental mercury instead of a volatile organic compound as the neutral feed material.

Vondrasek, R.; Pardo, R.; Scott, R. [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)] [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)

2013-11-15T23:59:59.000Z

315

Method for the removal of elemental mercury from a gas stream  

DOE Patents [OSTI]

A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

Mendelsohn, M.H.; Huang, H.S.

1999-05-04T23:59:59.000Z

316

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents [OSTI]

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

317

Mercury Flow through a Long Curved Pipe Wenhai Li & Foluso Ladeinde  

E-Print Network [OSTI]

Mercury Flow through a Long Curved Pipe Wenhai Li & Foluso Ladeinde Department of Mechanical Engineering Stony Brook University Summary The flow of mercury in a long, curved pipe is simulated that includes the effects of the viscosity of mercury, turbulence in the pipe, pressure force, and pipe friction

McDonald, Kirk

318

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents [OSTI]

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

319

Mercury Reduces Avian Reproductive Success and Imposes Selection: An Experimental Study with Adult-or  

E-Print Network [OSTI]

Mercury Reduces Avian Reproductive Success and Imposes Selection: An Experimental Study with Adult, United States of America Abstract Mercury is a global pollutant that biomagnifies in food webs, placing that songbirds are frequently exposed to mercury pollution. Our objective was to determine the effects

Swaddle, John

320

Anal. Chem. 1993, 65, 375-379 Analytical Utility of the Iridium-Based Mercury  

E-Print Network [OSTI]

Anal. Chem. 1993, 65, 375-379 Analytical Utility of the Iridium-Based Mercury over several days use. The applicationof SWASV theory for mercury film electrodes is shown The mercury electrode in ita many forms has been the overwhelmingsubstrate-of-choicefor electrochemistrysince

Kounaves, Samuel P.

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

MERCURY CYCLING IN LAKE GORDON AND LAKE PEDDER, TASMANIA (AUSTRALIA). I: IN-LAKE PROCESSES  

E-Print Network [OSTI]

MERCURY CYCLING IN LAKE GORDON AND LAKE PEDDER, TASMANIA (AUSTRALIA). I: IN-LAKE PROCESSES KARL C; accepted 2 December 2002) Abstract. The processes affecting the concentrations of total mercury (total Hg- vestigated. Surface concentrations of total mercury (total Hg) were temporally and spatially uniform in both

Canberra, University of

322

Dietary mercury exposure causes decreased escape takeoff flight performance and increased molt rate in European starlings  

E-Print Network [OSTI]

Dietary mercury exposure causes decreased escape takeoff flight performance and increased molt rate 2014 ? Springer Science+Business Media New York 2014 Abstract Mercury is a widespread and persistent that forage from primarily terrestrial sources have shown evidence of bioaccumula- tion of mercury, but little

Swaddle, John

323

Temperature dependence of the structure of Langmuir films of normal-alkanes on liquid mercury  

E-Print Network [OSTI]

Temperature dependence of the structure of Langmuir films of normal-alkanes on liquid mercury H phase behavior of Langmuir films of n-alkanes CH3(CH2)n 2CH3 , denote Cn on mercury was studied surface normal, alkanes on mercury are always oriented surface parallel and show no long-range in

Ocko, Ben

324

Methylation of Mercury by Bacteria Exposed to Dissolved, Nanoparticulate, and Microparticulate Mercuric Sulfides  

E-Print Network [OSTI]

Methylation of Mercury by Bacteria Exposed to Dissolved, Nanoparticulate, and Microparticulate in the environment is partly controlled by the bioavailability of inorganic divalent mercury (Hg(II)) to anaerobic matter to form chemical species that include organic-coated mercury sulfide nanoparticles as reaction

325

San Francisco Estuary Institute Regional Watershed Program Concentrations and Loads of Mercury,  

E-Print Network [OSTI]

San Francisco Estuary Institute Regional Watershed Program Concentrations and Loads of Mercury #12;McKee, Leatherbarrow, and Oram, 2005 i CONCENTRATIONS AND LOADS OF MERCURY, PCBs, AND OC. Concentrations and loads of mercury, PCBs, and OC pesticides in the lower Guadalupe River, San Jose, California

326

Mercury and Sulfur Dynamics in the SPRUCE Experiment Brandy Toner1  

E-Print Network [OSTI]

Mercury and Sulfur Dynamics in the SPRUCE Experiment Brandy Toner1 , Randy Kolka2 , Steve Sebestyen will lead studies assessing the influence of SPRUCE treatments on the cycling of THg, MeHg and S. Mercury. Mercury levels are determined by complex interactions between deposition, chemical transformation

327

(mercury.yukawa.kyoto-u.ac.jp)ssh Permission denied (publickey).  

E-Print Network [OSTI]

SSH Q&A (mercury.yukawa.kyoto-u.ac.jp)ssh Permission denied (publickey). (1) ID ID ID (2) ssh -i () ssh -i $HOME/.ssh/id_yitp_rsa (UID)@mercury.yukawa.kyoto-u.ac.jp (3) (1)(2) Permission denied support@yukawa.kyoto-u.ac.jp (mercury

Shimizu, Akira

328

Mercury: A Scalable Publish-Subscribe System for Internet Ashwin R. Bharambe  

E-Print Network [OSTI]

Mercury: A Scalable Publish-Subscribe System for Internet Games Ashwin R. Bharambe ashu-subscribe system. We present the design of Mercury, a completely distributed publish-subscribe system, which of communication building block for distributed multiplayer games. Our system, called Mercury, provide

Goldstein, Seth Copen

329

Generalized Mercury/Waterfilling for Multiple-Input Multiple-Output Channels  

E-Print Network [OSTI]

Generalized Mercury/Waterfilling for Multiple-Input Multiple-Output Channels Fernando P procedure that generalizes the mercury/waterfilling algorithm, previously proposed for parallel non-interfering chan- nels. In this generalization the mercury level accounts for the sub- optimal (non-Gaussian) input

Verdú, Sergio

330

Method for the removal of elemental mercury from a gas stream  

DOE Patents [OSTI]

A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

Mendelsohn, Marshall H. (Downers Grove, IL); Huang, Hann-Sheng (Darien, IL)

1999-01-01T23:59:59.000Z

331

Mercury Contamination from Hydraulic Placer-Gold Mining in the Dutch Flat Mining  

E-Print Network [OSTI]

179 Mercury Contamination from Hydraulic Placer-Gold Mining in the Dutch Flat Mining District, California By Michael P. Hunerlach, James J. Rytuba, and Charles N. Alpers ABSTRACT Mercury contamination mercury (quicksilver) was used extensively for the recovery of gold at both placer and hardrock mines

332

Mercury-Contaminated Sediments Affect Amphipod Feeding Mirco Bundschuh Jochen P. Zubrod Frank Seitz  

E-Print Network [OSTI]

Mercury-Contaminated Sediments Affect Amphipod Feeding Mirco Bundschuh · Jochen P. Zubrod · Frank River, Virginia, was contaminated with mercury during the first half of the 20th century. As increased concentrations of mercury have persisted, researchers have carefully studied its distribution in the river biota

Newman, Michael C.

333

Changes in mercury bioaccumulation in an apex predator in response to removal of an introduced competitor  

E-Print Network [OSTI]

Changes in mercury bioaccumulation in an apex predator in response to removal of an introduced and decreased mercury concentrations in remaining fish. Instead, we observed a significant increase in lake web structure can influence MeHg concentrations in top predators. Keywords Mercury Á Food web Á Fish

Kraft, Clifford E.

334

Mercury: A Wearable Sensor Network Platform for High-fidelity Motion Analysis  

E-Print Network [OSTI]

Mercury: A Wearable Sensor Network Platform for High-fidelity Motion Analysis Konrad Lorincz, Bor This paper describes Mercury, a wearable, wireless sen- sor platform for motion analysis of patients being to previous systems intended for short-term use in a laboratory, Mercury is designed to sup- port long

Chen, Yiling

335

WDM school, January 14, 2008 Equation of State for Fluid Mercury  

E-Print Network [OSTI]

1 WDM school, January 14, 2008 Equation of State for Fluid Mercury Based on Interatomic Many, Fluid Metals (Princeton, 1999) elements Tc (K) Pc (bar) c (g/cm3) Mercury (Hg) Cesium (Cs) Rubidium (Rb.30 divalent monovalent (alkali) Importance of mercury -- lowest critical temperature -- critical point

336

Mercury: A Memory-Constrained Spatio-temporal Real-time Search on Microblogs  

E-Print Network [OSTI]

Mercury: A Memory-Constrained Spatio-temporal Real-time Search on Microblogs Amr Magdy1§ , Mohamed Mercury; a system for real-time support of top-k spatio-temporal queries on microblogs, where users are able to browse recent microblogs near their locations. With high arrival rates of microblogs, Mercury

Bernstein, Phil

337

386 Anal. Chem. 1987, 59,386-389 Square Wave Anodic Stripping Voltammetry at the Mercury  

E-Print Network [OSTI]

386 Anal. Chem. 1987, 59,386-389 Square Wave Anodic Stripping Voltammetry at the Mercury Film treatment of square wave anodic stripping voltammetry at a mercury film electrode Is presented. Nu- merlcal) frequency ( f ) and amount of metal depostted In the mercury layer (9R) and glves a response 6 tlmes

Kounaves, Samuel P.

338

MERCURY IN FISH AND SHELLFISH OF THE NORTHEAST PACIFIC. II. SABLEFISH, ANOPLOPOMA FIMBRIA  

E-Print Network [OSTI]

MERCURY IN FISH AND SHELLFISH OF THE NORTHEAST PACIFIC. II. SABLEFISH, ANOPLOPOMA FIMBRIA ALICE S several locations in Alaska, Washington, Oregon, and California were analyzed for their mercury content. Mean mercury level in this species varied with the geographical location of catch, showing a gradual

339

Mercury in the Northern Crayfish, Orconectes virilis (Hagen), in New England, USA  

E-Print Network [OSTI]

Mercury in the Northern Crayfish, Orconectes virilis (Hagen), in New England, USA CHRIS M. PENNUTO of mercury bioavail- ability in aquatic ecosystems. In this study, we assessed the effects of drainage basin, habitat type, size class, and sex on mercury concentrations in the northern crayfish, Orconectes virilis

Pennuto, Chris

340

Frequently Asked Questions Information on Compact Fluorescent Light Bulbs (CFLs) and Mercury  

E-Print Network [OSTI]

Frequently Asked Questions Information on Compact Fluorescent Light Bulbs (CFLs) and Mercury emissions equivalent to those of more than 800,000 cars. Do CFLs contain mercury? CFLs contain a very small amount of mercury sealed within the glass tubing ­ an average of 5 milligrams ­ about the amount

Jia, Songtao

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Evaluation of the origin hypotheses of Pantheon Fossae, central Caloris basin, Mercury  

E-Print Network [OSTI]

Evaluation of the origin hypotheses of Pantheon Fossae, central Caloris basin, Mercury Christian April 2010 Keywords: Mercury Tectonics a b s t r a c t The origin of Pantheon Fossae, a complex structure consisting of radial graben in the center of the Caloris basin, Mercury, has been debated since

Nahm, Amanda

342

Atmospheric Mercury in the Great Lakes Region An Evaluation of the Community Multiscale Air Quality  

E-Print Network [OSTI]

Atmospheric Mercury in the Great Lakes Region An Evaluation of the Community Multiscale Air Quality Tracey Holloway #12;i Abstract Atmospheric mercury is a significant source for methylmercury (Me. In order to control MeHg exposures, policy-makers need a clear understanding of the atmospheric mercury

Wisconsin at Madison, University of

343

Multiuser Mercury/waterfilling for Downlink OFDM with Arbitrary Signal Constellations  

E-Print Network [OSTI]

Multiuser Mercury/waterfilling for Downlink OFDM with Arbitrary Signal Constellations Angel Lozano tracked by the base station, adopts the form of a multiuser mercury/waterfilling procedure that generalizes the single-user mercury/waterfilling introduced in [1]. I. INTRODUCTION There is, of late, great

Lozano, Angel

344

MESSENGER and Mariner 10 flyby observations of magnetotail structure and dynamics at Mercury  

E-Print Network [OSTI]

MESSENGER and Mariner 10 flyby observations of magnetotail structure and dynamics at Mercury James January 2012. [1] The first (M1), second (M2), and third (M3) MESSENGER flybys of Mercury traversed the planet's magnetotail from 1.25 to 3.25 RM downstream of the planet, where RM is Mercury's radius (2440 km

California at Berkeley, University of

345

Mission Overview MESSENGER is a scientific investigation of the planet Mercury.  

E-Print Network [OSTI]

Mission Overview MESSENGER is a scientific investigation of the planet Mercury. Understanding Mercury,and the forces that have shaped it,is fundamental to understanding the terrestrial planets and their evolution. The MESSENGER (MErcury Surface,Space ENvironment, GEochemistry,and Ranging) mission will orbit

346

Procedures for Collecting and Processing Streambed Sediment and Pore Water for Analysis of Mercury as  

E-Print Network [OSTI]

Procedures for Collecting and Processing Streambed Sediment and Pore Water for Analysis of Mercury Streambed Sediment and Pore Water for Analysis of Mercury as Part of the National Water-Quality Assessment for collecting and processing streambed sediment and pore water for analysis of mercury as part of the National

347

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance of anaerobes  

E-Print Network [OSTI]

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance Keywords: Methylmercury Oxygen minimum zone Arabian Sea Equatorial Eastern Pacific Mercury methylation Although a large fraction of the world's population is exposed to mercury through consumption of marine

Morel, François M. M.

348

Mercury Species and Other Selected Constituent Concentrations in Water, Sediment, and Biota of  

E-Print Network [OSTI]

Mercury Species and Other Selected Constituent Concentrations in Water, Sediment, and Biota Data Series 658 #12;#12;Mercury Species and Other Selected Constituent Concentrations in Water.J., 2012, Mercury species and other selected constituent concentrations in water, sediment, and biota

349

Mercury biogeochemistry: paradigm shifts, outstanding issues and research needs1 Jeroen E. Sonke1  

E-Print Network [OSTI]

Mercury biogeochemistry: paradigm shifts, outstanding issues and research needs1 Jeroen E. Sonke1.dommergue@ujf-grenoble.fr7 In press with Elsevier's Compte Rendus Geoscience8 Abstract9 Half a century of mercury research has provided scientists and policy makers with detailed10 understanding of mercury toxicology

Dintrans, Boris

350

The control of mercury vapor using biotrickling filters Ligy Philip a,b,1  

E-Print Network [OSTI]

The control of mercury vapor using biotrickling filters Ligy Philip a,b,1 , Marc A. Deshusses b August 2007 Abstract The feasibility of using biotrickling filters for the removal of mercury vapor from. In particular, the biotrickling filters with sulfur oxidizing bacteria were able to remove 100% of mercury vapor

351

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ Measurements  

E-Print Network [OSTI]

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, respectively--together predicted 94 % of the observed variability in measured total mercury concentra- tion

Boss, Emmanuel S.

352

The Sulfate-Reducing Bacterium Desulfovibrio desulfuricans ND132 as a Model for Understanding Bacterial Mercury  

E-Print Network [OSTI]

Bacterial Mercury Methylation Contact: Cynthia Gilmour (gilmourc@si.edu, 443-482-2498) DOE/Office of Science/Biological & Environmental Research ·The ORNL Mercury Science Focus Area is developing the Hg-methylating bacterium as a model for understanding bacterial mercury methylation. Appl. Environ. Microbiol. 77:3938-3951 (doi:10

353

DESIGN OF THE MERCURY HANDLING SYSTEM FOR A MUON COLLIDER/NEUTRINO FACTORY TARGET  

E-Print Network [OSTI]

DESIGN OF THE MERCURY HANDLING SYSTEM FOR A MUON COLLIDER/NEUTRINO FACTORY TARGET (IPAC13, THPFI092) The baseline target concept for a Muon Collider or Neutrino Factory is a free mercury jet within a 20-T magnetic field being impacted by an 8-GeV proton beam. A pool of mercury serves as a receiving reservoir

McDonald, Kirk

354

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams  

E-Print Network [OSTI]

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams Research The influences of uranium (U), mercury (Hg) and methylmercury (MeHg) on the microbial community. #12;High concentrations of uranium, inorganic mercury, Hg(II) and methymercury (MeHg) have been

355

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect (OSTI)

Catalysis is the key fundamental ingredient to convert elemental mercury in coal-fired power stations into its oxidized forms that are more easily captured by sorbents, ESPs, baghouses, and wet scrubbers, whether the catalyst be unburned carbon (UBC) in the ash or vanadium pentoxide in SCR catalysts. This project has investigated several different types of catalysts that enhance mercury oxidation in several different ways. The stated objective of this project in the Statement of Objectives included testing duct-injection catalysts, catalyst-sorbent hybrids, and coated low-pressure-drop screens. Several different types of catalysts were considered for duct injection, including different forms of iron and carbon. Duct-injection catalysts would have to be inexpensive catalysts, as they would not be recycled. Iron and calcium had been shown to catalyze mercury oxidation in published bench-scale tests. However, as determined from results of an on-going EPRI/EPA project at Southern Research, while iron and calcium did catalyze mercury oxidation, the activity of these catalysts was orders of magnitude below that of carbon and had little impact in the short residence times available for duct-injected catalysts or catalyst-sorbent hybrids. In fact, the only catalyst found to be effective enough for duct injection was carbon, which is also used to capture mercury and remove it from the flue gas. It was discovered that carbon itself is an effective catalyst-sorbent hybrid. Bench-scale carbon-catalyst tests were conducted, to obtain kinetic rates of mercury adsorption (a key step in the catalytic oxidation of mercury by carbon) for different forms of carbon. All carbon types investigated behaved in a similar manner with respect to mercury sorption, including the effect of temperature and chlorine concentration. Activated carbon was more effective at adsorbing mercury than carbon black and unburned carbon (UBC), because their internal surface area of activated carbon was greater. Catalyst coating of low-pressure-drop screens was of particular interest as this project was being developed. However, it was discovered that URS was already heavily involved in the pursuit of this same technology, being funded by DOE, and reporting significant success. Hence, testing of SCR catalysts became a major focus of the project. Three different commercial SCR catalysts were examined for their ability to oxidize mercury in simulated flue-gas. Similar performance was observed from each of the three commercial catalysts, both in terms of mercury oxidation and SO{sub 3} generation. Ammonia injection hindered mercury oxidation at low HCl concentrations (i.e., {approx}2 ppmv), yet had little impact on mercury oxidation at higher HCl concentrations. On the other hand, SO{sub 2} oxidation was significantly reduced by the presence of ammonia at both low and high concentrations of HCl.

Thomas K. Gale

2006-06-30T23:59:59.000Z

356

Thief process for the removal of mercury from flue gas  

DOE Patents [OSTI]

A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

2003-02-18T23:59:59.000Z

357

Low-Cost Options for Moderate Levels of Mercury Control  

SciTech Connect (OSTI)

On March 15, 2005, EPA issued the Clean Air Mercury Rule, requiring phased-in reductions of mercury emissions from electric power generators. ADA-ES, Inc., with support from DOE/NETL and industry partners, is conducting evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. DOE/NETL targets for total mercury removal are {ge}55% (lignite), {ge}65% (subbituminous), and {ge}80% (bituminous). Based on work done to date at various scales, meeting the removal targets appears feasible. However, work needs to progress to more thoroughly document and test these promising technologies at full scale. This is the final site report for tests conducted at MidAmerican's Louisa Station, one of three sites evaluated in this DOE/NETL program. The other two sites in the program are MidAmerican's Council Bluff Station and Entergy's Independence Station. MidAmerican's Louisa Station burns Powder River Basin (PRB) coal and employs hot-side electrostatic precipitators with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal.

Sharon Sjostrom

2006-03-31T23:59:59.000Z

358

Natural mercury isotope variation in coal deposits and organic soils  

SciTech Connect (OSTI)

There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie [University of Michigan, Ann Arbor, MI (United States). Department of Geological Sciences

2008-11-15T23:59:59.000Z

359

REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION  

SciTech Connect (OSTI)

Mercury emission compliance presents one of the major potential challenges raised by the 1990 Clean Air Act Amendments. Simple ways of controlling emissions have not been identified. The variability in the field data suggest that inherent mercury emissions may be reduced if the source of this inherent capture can be identified and controlled. The key mechanisms appear to involve the oxidation of mercury to Hg{sup 2}, generally producing the more reactive HgCl{sub 2}, followed by its capture by certain components of the fly ash or char, or in the air pollution control equipment. This research focuses on identifying the rate-limiting steps associated with the oxidation step. Work in this reporting period focused on the refinement of the rate constants used in the kinetic mechanism for mercury oxidation. The possible reactions leading to mercury oxidation are reviewed. Rate constants for these reactions are discussed, using both literature sources and detailed estimates. The resulting mechanism represents the best present picture of the overall chlorine homogeneous oxidation chemistry. Application of this mechanism to the data will be explored in the subsequent reporting period. Work conducted under the present grant has been the subject of two meeting papers presented during the reporting period (Sliger et al., 1998a,b).

John C. Kramlich; Rebecca N. Sliger; David J. Going

1999-08-06T23:59:59.000Z

360

Mercury Oxidation via Catalytic Barrier Filters Phase II  

SciTech Connect (OSTI)

In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

2007-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Progress in Creating Stabilized Gas Layers in Flowing Liquid Mercury  

SciTech Connect (OSTI)

The Spallation Neutron Source (SNS) facility in Oak Ridge, Tennessee uses a liquid mercury target that is bombarded with protons to produce a pulsed neutron beam for materials research and development. In order to mitigate expected cavitation damage erosion (CDE) of the containment vessel, a two-phase flow arrangement of the target has been proposed and was earlier proven to be effective in significantly reducing CDE in non-prototypical target bodies. This arrangement involves covering the beam "window", through which the high-energy proton beam passes, with a protective layer of gas. The difficulty lies in establishing a stable gas/liquid interface that is oriented vertically with the window and holds up to the strong buoyancy force and the turbulent mercury flow field. Three approaches to establishing the gas wall have been investigated in isothermal mercury/gas testing on a prototypical geometry and flow: (1) free gas layer approach, (2) porous wall approach, and (3) surface-modified approach. The latter two of these approaches show success in that a stabilized gas layer is produced. Both of these successful approaches capitalize on the high surface energy of liquid mercury by increasing the surface area of the solid wall, thus increasing gas hold up at the wall. In this paper, a summary of these experiments and findings is presented as well as a description of the path forward toward incorporating the stabilized gas layer approach into a feasible gas/mercury SNS target design.

Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL; Abdou, Ashraf A [ORNL; D'Urso, Brian R [ORNL; West, David L [ORNL

2009-01-01T23:59:59.000Z

362

Molecular Mechanisms of Bacterial Mercury Transformation  

SciTech Connect (OSTI)

Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources. Defining the factors that determine the relative affinities of different ligands for the mercuric ion, Hg2+, is critical to understanding its speciation, transformation, and bioaccumulation in the environment. Here, we used quantum chemistry to dissect the relative binding free energies for a series of inorganic anion complexes of Hg2+. The results show that, whereas in the gas phase the binding affinity of two identical anionic ligands (forming HgL2) increases with ligand (L) hardness, in contrast, in the aqueous phase the affinity increases with ligand softness. This switch in affinity upon hydration is shown to result mostly from interactions with only a small number (e.g. one or two) of water molecules. The results yield a clear, robust periodic trend within the chalcogenide and halide groups and are in agreement with the well-known experimentally observed preference of Hg2+ for soft ligands. By comparing the Hg2+ binding of one with two anions, the gas phase preferences are found to arise from the enhancement of reactivity of the cationic complex (HgL+) with the hardness of L. The approach establishes a theoretical basis for understanding Hg speciation in the biosphere.

smith, jeremy

2014-04-15T23:59:59.000Z

363

Xenon in Mercury-Manganese Stars  

E-Print Network [OSTI]

Previous studies of elemental abundances in Mercury-Manganese (HgMn) stars have occasionally reported the presence of lines of the ionized rare noble gas Xe II, especially in a few of the hottest stars with Teff ~ 13000--15000 K. A new study of this element has been undertaken using observations from Lick Observatory's Hamilton Echelle Spectrograph. In this work, the spectrum synthesis program UCLSYN has been used to undertake abundance analysis assuming LTE. We find that in the Smith & Dworetsky sample of HgMn stars, Xe is vastly over-abundant in 21 of 22 HgMn stars studied, by factors of 3.1--4.8 dex. There does not appear to be a significant correlation of Xe abundance with Teff. A comparison sample of normal late B stars shows no sign of Xe II lines that could be detected, consistent with the expected weakness of lines at normal abundance. The main reason for the previous lack of widespread detection in HgMn stars is probably due to the strongest lines being at longer wavelengths than the photographic blue. The lines used in this work were 4603.03A, 4844.33A and 5292.22A.

M. M. Dworetsky; J. L. Persaud; K. Patel

2008-01-16T23:59:59.000Z

364

MERCURY LEVELS IN HAWAIIAN PREDATORY PEI-AGIC FISHES AND THEIR PREY ASA FUNCTION OF DEPTH AND ECOLOGY  

E-Print Network [OSTI]

,and location of captute, hower.ef, details regardrngthe nature of mercury bioaccumulationareincomplcte

Luther, Douglas S.

365

Accumulation of mercury in the tissues of the common octopus Octopus vulgaris (L.) in two localities on the Portuguese coast  

E-Print Network [OSTI]

1 Accumulation of mercury in the tissues of the common octopus Octopus vulgaris (L.) in two 340 (2005) 113- 122" DOI : 10.1016/j.scitotenv.2004.08.012 #12;2 Abstract: Mercury concentrations were mercury concentrations in different tissues were examined as were correlations between mercury levels

Paris-Sud XI, Université de

366

Mercury Spills EHS Contact: Kate Lumley-Sapanski (kxl3@psu.edu) 814-865-6391  

E-Print Network [OSTI]

Mercury Spills EHS Contact: Kate Lumley-Sapanski (kxl3@psu.edu) 814-865-6391 Michael Burke (mjb7 Not Enter ­Mercury Spill" · Call EHS immediately When to Report: For large mercury spills (i.e. manometers) or spills in areas where loose mercury could be heated (>90 F degrees) and vapors released and call EHS

Maroncelli, Mark

367

Catalysts for oxidation of mercury in flue gas  

DOE Patents [OSTI]

Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2010-08-17T23:59:59.000Z

368

Helium and mercury in the central Seward Peninsula  

SciTech Connect (OSTI)

The central Seward Peninsula, Alaska, has one Known Geothermal Resource Area (KGRA) at Pilgrim Springs, and has recent volcanic flows, fault systems, topographic and tectonic features which can be explained by a rift model. As part of a geothermal reconnaissance of the area we used helium and mercury concentrations in soil as indicators of geothermal resources. The largest helium concentrations were found in the vicinity of the Pilgrims Springs KGRA, and indicate prime drilling sites. Five profile lines were run across the suspected rift system. Significant helium anomalies were found on several of the traverses, where future exploration might be concentrated. Mercury values showed a great range of variability on the traverses, and seem unreliable as geothermal indicators except in the vicinity of the Pilgrim Springs. Permafrost at the surface resulting in variations in sampling depth may contribute to the mercury variations.

Wescott, E.; Ruscetta, C.A.; Foley, D. (eds.)

1981-05-01T23:59:59.000Z

369

Clean Air Mercury Rule (released in AEO2009)  

Reports and Publications (EIA)

On February 8, 2008, a three-judge panel on the D.C. Circuit of the U.S. Court of Appeals issued a decision to vacate the Clean Air Mercury Rule (CAMR). In its ruling, the panel cited the history of hazardous air pollutant regulation under Section 112 of the Clean Air Act (CAA). Section 112, as written by Congress, listed emitted mercury as a hazardous air pollutant that must be subject to regulation unless it can be proved harmless to public welfare and the environment. In 2000, the Environmental Protection Agency ruled that mercury was indeed hazardous and must be regulated under Section 112 and, therefore, subjected to the best available control technology for mitigation.

2009-01-01T23:59:59.000Z

370

Mercury capture by distinct fly ash carbon forms  

SciTech Connect (OSTI)

Carbon was separated from the fly ash from a Kentucky power plant using density gradient centrifugation. Using a lithium heterolpolytungstate high-density media, relative concentrations of inertinite (up to 85% vol.), isotropic carbon (up to 79% vol.), and anisotropic carbon (up to 76% vol.) were isolated from the original fly ash. Mercury concentration was lowest in the parent fly ash (which contains non-carbon components); followed by inertinite, isotropic coke, mixed isotropic-anisotropic coke fraction, and, with the highest concentration, the anisotropic coke concentrate. The latter order corresponds to the increase in BET surface area of the fly ash carbons. Previous studies have demonstrated the capture of mercury by fly ash carbon. This study confirms prior work demonstrating the varying role of carbon types in the capture, implying that variability in the carbon content influences the amount of mercury retained on the fly ash.

Hower, J.C.; Maroto-Valer, M.M.; Taulbee, D.N.; Sakulpitakphon, T.

1999-07-01T23:59:59.000Z

371

DIRECT MEASUREMENT OF MERCURY REACTIONS IN COAL POWER PLANT PLUMES  

SciTech Connect (OSTI)

This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-02NT41422 and specifically addresses Program Area of Interest: No.5--Environmental and Water Resources. The project team includes the Electric Power Research Institute (EPRI) as the contractor and the University of North Dakota Energy & Environmental Research Center (EERC) and Frontier Geosciences as subcontractors. Wisconsin Energies and its Pleasant Prairie Power Plant acted as host for the field-testing portion of the research. The project is aimed at clarifying the role, rates, and end results of chemical transformations that may occur to mercury that has been emitted from elevated stacks of coal-fired electric power plants. Mercury emitted from power plants emerges in either its elemental, divalent, or particulate-bound form. Deposition of the divalent form is more likely to occur closer to the source than that of the other two forms, due to its solubility in water. Thus, if chemical transformations occur in the stack emissions plume, measurements in the stack may mischaracterize the fate of the material. Initial field and pilot plant measurements have shown significant and rapid chemical reduction of divalent to elemental mercury may occur in these plumes. Mercury models currently assume that the chemical form of mercury occurring in stacks is the same as that which enters the free atmosphere, with no alteration occurring in the emissions plume. Recent data indicate otherwise, but need to be evaluated at full operating scale under field conditions. Prestbo and others have demonstrated the likelihood of significant mercury chemical reactions occurring in power plant plumes (Prestbo et al., 1999; MDNR-PPRP, 2000; EERC, 2001). This experiment will thus increase our understanding of mercury atmospheric chemistry, allowing informed decisions regarding source attribution. The experiment was carried out during the period August 22-September 5, 2003. The experimental site was the Pleasant Prairie Power Plant in Pleasant Prairie, Wisconsin, just west of Kenosha. The experiment involved using an aircraft to capture emissions and document chemistry changes in the plume. While using the airplane for sampling, supplemental fast-response sensors for NOx, connected to data loggers, were used to gauge entry and exit times and transect intervals through plume emissions material. The Frontier Geosciences Static Plume Dilution Chamber (SPDC) was employed simultaneously adjacent to the stack to correlate its findings with the aircraft sampling, as well as providing evaluation of the SPDC as a rapid, less costly sampler for mercury chemistry. A complementary stack plume method, the Dynamic Plume Dilution (DPD) was used in the latter portion of the experiment to measure mercury speciation to observe any mercury reduction reaction with respect to both the reaction time (5 to 30 seconds) and dilution ratio. In addition, stack sampling using the ''Ontario Hydro'' wet chemistry method and continuous mercury monitors (CMM) were used to establish the baseline chemistry in the stack. Comparisons among stack, SPDC, DPD and aircraft measurements allow establishment of whether significant chemical changes to mercury occur in the plume, and of the verisimilitude of the SPDC and DPD methods. This progress report summarizes activities during a period of results review from the stack/aircraft subcontractor, data analysis and synthesis, and preparation and presentation of preliminary results to technical and oversight meetings.

Leonard Levin

2006-06-01T23:59:59.000Z

372

REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION  

SciTech Connect (OSTI)

Mercury emission compliance presents one of the major potential challenges raised by the 1990 Clean Air Act Amendments. Simple ways of controlling emissions have not been identified. The variability in the field data suggest that inherent mercury emissions may be reduced if the source of this inherent capture can be identified and controlled. The key mechanisms appear to involve the oxidation of mercury to Hg{sup 2}, generally producing the more reactive HgCl{sub 2}, followed by its capture by certain components of the fly ash or char, or in the air pollution control equipment. This research focuses on identifying the rate-limiting steps associated with the oxidation step. Work in this reporting period focused on testing of the kinetic mechanism reported in the previous semiannual report, and the interpretation of data (both ours and literature). This model yields good qualitative agreement with the data and indicates that mercury oxidation occurs during the thermal quench of the combustion gases. The model also suggests that atomic chlorine is the key oxidizing species. The oxidation is limited to a temperature window between 700-400 C that is defined by the overlap of (1) a region of significant superequilibrium Cl concentration, and (2) a region where oxidized mercury is favored by equilibrium. Above 700 C reverse reactions effectively limit oxidized mercury concentrations. Below 400 C, atomic chlorine concentrations are too low to support further oxidation. The implication of these results are that homogeneous oxidation is governed primarily by (1) HCl concentration, (2) quench rate, and (3) background gas composition. Work conducted under the present grant has been the subject of one journal paper that was accepted for publication during the reporting period (Sliger et al., 1999).

John C. Kramlich; Rebecca N. Sliger; David J. Going

1999-08-06T23:59:59.000Z

373

Measurements of Gas Bubble Size Distributions in Flowing Liquid Mercury  

SciTech Connect (OSTI)

ABSTRACT Pressure waves created in liquid mercury pulsed spallation targets have been shown to induce cavitation damage on the target container. One way to mitigate such damage would be to absorb the pressure pulse energy into a dispersed population of small bubbles, however, measuring such a population in mercury is difficult since it is opaque and the mercury is involved in a turbulent flow. Ultrasonic measurements have been attempted on these types of flows, but the flow noise can interfere with the measurement, and the results are unverifiable and often unrealistic. Recently, a flow loop was built and operated at Oak Ridge National Labarotory to assess the capability of various bubbler designs to deliver an adequate population of bubbles to mitigate cavitation damage. The invented diagnostic technique involves flowing the mercury with entrained gas bubbles in a steady state through a horizontal piping section with a glass-window observation port located on the top. The mercury flow is then suddenly stopped and the bubbles are allowed to settle on the glass due to buoyancy. Using a bright-field illumination and a high-speed camera, the arriving bubbles are detected and counted, and then the images can be processed to determine the bubble populations. After using this technique to collect data on each bubbler, bubble size distributions were built for the purpose of quantifying bubbler performance, allowing the selection of the best bubbler options. This paper presents the novel procedure, photographic technique, sample visual results and some example bubble size distributions. The best bubbler options were subsequently used in proton beam irradiation tests performed at the Los Alamos National Laboratory. The cavitation damage results from the irradiated test plates in contact with the mercury are available for correlation with the bubble populations. The most effective mitigating population can now be designed into prototypical geometries for implementation into an actual SNS target.

Wendel, Mark W [ORNL; Riemer, Bernie [ORNL; Abdou, Ashraf A [ORNL

2012-01-01T23:59:59.000Z

374

Analytical Methods for Measuring Mercury in Water, Sediment and Biota  

SciTech Connect (OSTI)

Mercury (Hg) exists in a large number of physical and chemical forms with a wide range of properties. Conversion between these different forms provides the basis for mercury's complex distribution pattern in local and global cycles and for its biological enrichment and effects. Since the 1960s, the growing awareness of environmental mercury pollution has stimulated the development of more accurate, precise and efficient methods of determining mercury and its compounds in a wide variety of matrices. During recent years new analytical techniques have become available that have contributed significantly to the understanding of mercury chemistry in natural systems. In particular, these include ultra sensitive and specific analytical equipment and contamination-free methodologies. These improvements allow for the determination of total mercury as well as major species of mercury to be made in water, sediments and soils, and biota. Analytical methods are selected depending on the nature of the sample, the concentration levels of mercury, and what species or fraction is to be quantified. The terms speciation and fractionation in analytical chemistry were addressed by the International Union for Pure and Applied Chemistry (IUPAC) which published guidelines (Templeton et al., 2000) or recommendations for the definition of speciation analysis. "Speciation analysis is the analytical activity of identifying and/or measuring the quantities of one or more individual chemical species in a sample. The chemical species are specific forms of an element defined as to isotopic composition, electronic or oxidation state, and/or complex or molecular structure. The speciation of an element is the distribution of an element amongst defined chemical species in a system. In case that it is not possible to determine the concentration of the different individual chemical species that sum up the total concentration of an element in a given matrix, meaning it is impossible to determine the speciation, it is a useful practice to do fractionation instead. Fractionation is the process of classification of an analyte or a group of analytes from a certain sample according to physical (e.g. size, solubility) or chemical (e.g. bonding, reactivity) properties."

Lasorsa, Brenda K.; Gill, Gary A.; Horvat, Milena

2012-06-07T23:59:59.000Z

375

A study of the solubility of mercury in liquid hydrocarbons  

E-Print Network [OSTI]

mercury by precipitating HgS out of solution and measuring the metcury activity on a Gieger counter. A second but similar method used by Moser and Voigt used metallic Hg&cs which was obtained by reduction of mercumus nitrate with hypophosphorus acid...A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARIhKR MCFARLANE Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

McFarlane, David Larimer

1991-01-01T23:59:59.000Z

376

Atmospheric Mercury Concentrations Near Salmon Falls Creek Reservoir - Phase 1  

SciTech Connect (OSTI)

Elemental and reactive gaseous mercury (EGM/RGM) were measured in ambient air concentrations over a two-week period in July/August 2005 near Salmon Falls Creek Reservoir, a popular fishery located 50 km southwest of Twin Falls, Idaho. A fish consumption advisory for mercury was posted at the reservoir in 2002 by the Idaho Department of Health and Welfare. The air measurements were part of a multi-media (water, sediment, precipitation, air) study initiated by the Idaho Department of Environmental Quality and the U.S. Environmental Protection Agency (EPA) Region 10 to identify potential sources of mercury contamination to the reservoir. The sampling site is located about 150 km northeast of large gold mining operations in Nevada, which are known to emit large amounts of mercury to the atmosphere (est. 2,200 kg/y from EPA 2003 Toxic Release Inventory). The work was co-funded by the Idaho National Laboratorys Community Assistance Program and has a secondary objective to better understand mercury inputs to the environment near the INL, which lies approximately 230 km to the northeast. Sampling results showed that both EGM and RGM concentrations were significantly elevated (~ 30 70%, P<0.05) compared to known regional background concentrations. Elevated short-term RGM concentrations (the primary form that deposits) were likely due to atmospheric oxidation of high EGM concentrations, which suggests that EGM loading from upwind sources could increase Hg deposition in the area. Back-trajectory analyses indicated that elevated EGM and RGM occurred when air parcels came out of north-central and northeastern Nevada. One EGM peak occurred when the air parcels came out of northwestern Utah. Background concentrations occurred when the air was from upwind locations in Idaho (both northwest and northeast). Based on 2003 EPA Toxic Release Inventory data, it is likely that most of the observed peaks were from Nevada gold mine sources. Emissions from known large natural mercury sources in that area cannot account for the observed EGM peaks due to their diffuse source geometry and the large (170 km) transport distance involved. The EGM peak originating from northwestern Utah air may be from three known mercury sources west of Salt Lake City (Kennecott, US Magnesium, Clean Harbors Aragonite) and/or the 1600 MW coal-fired Intermountain Power plant near Delta. However, the relative importance of these short-term peaks for long-term watershed mercury loading (critical factor affecting fish concentrations) is not known, and there is a need to better quantify the annual frequency and magnitude of these different inputs over a longer period of time.

M. L. Abbott

2005-10-01T23:59:59.000Z

377

The impact of modern headlamps on the design of sag vertical curves  

E-Print Network [OSTI]

to the lens. The housing serves as a reflector and lens, and is made of plastic. These lamps may be comprised of different light emitting diode?s (LEDs), high intensity discharge (HID) lamps, and halogen lamps. Halogen headlamps are further comprised... on. HID lamps produce more light compared to halogen lamps (22). Also, HID lamps have a sharper horizontal cut-off beam pattern further reducing the portion of lighted highway on sag curves (25). Light emitting diode is another headlamp...

Gogula, Madhuri

2006-08-16T23:59:59.000Z

378

Residual dust charges in discharge afterglow  

SciTech Connect (OSTI)

An on-ground measurement of dust-particle residual charges in the afterglow of a dusty plasma was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force. It was found that positively charged, negatively charged, and neutral dust particles coexisted for more than 1 min after the discharge was switched off. The mean residual charge for 200-nm-radius particles was measured. The dust particle mean charge is about -5e at a pressure of 1.2 mbar and about -3e at a pressure of 0.4 mbar.

Coueedel, L.; Mikikian, M.; Boufendi, L.; Samarian, A. A. [GREMI - Groupe de Recherches sur l'Energetique des Milieux Ionises, CNRS/Universite d'Orleans, 14 rue d'Issoudun, 45067 Orleans Cedex 2 (France); School of Physics A28, University of Sydney, NSW 2006 (Australia)

2006-08-15T23:59:59.000Z

379

Optimizing Technology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants  

SciTech Connect (OSTI)

Revised maps and associated data show potential mercury, sulfur, and chlorine emissions for U.S. coal by county of origin. Existing coal mining and coal washing practices result in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Selection of low-mercury coal is a good mercury control option for plants having hot-side ESP, cold-side ESP, or hot-side ESP/FGD emission controls. Chlorine content is more important for plants having cold-side ESP/FGD or SDA/FF controls; optimum net mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions.

Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

2005-01-31T23:59:59.000Z

380

Final disposal options for mercury/uranium mixed wastes from the Oak Ridge Reservation  

SciTech Connect (OSTI)

Laboratory testing was completed on chemical stabilization and physical encapsulation methods that are applicable (to comply with federal and state regulations) to the final disposal of both hazardous and mixed hazardous elemental mercury waste that is in either of the following categories: (1) waste generated during decontamination and decommissioning (D and D) activities on mercury-contaminated buildings, such as Building 9201-4 at the Oak Ridge Y-12 Plant, or (2) waste stored and regulated under either the Federal Facilities Compliance Agreement or the Federal Facilities Compliance Act. Methods were used that produced copper-mercury, zinc-mercury, and sulfur-mercury materials at room temperature by dry mixing techniques. Toxicity Characteristic Leaching Procedure (TCLP) results for mercury on batches of both the copper-mercury and the sulfur-mercury amalgams consistently produced leachates with less than the 0.2-mg/L Resource Conservation and Recovery Act (RCRA) regulatory limit for mercury. The results clearly showed that the reaction of mercury with sulfur at room temperature produces black mercuric sulfide, a material that is well suited for land disposal. The results also showed that the copper-mercury and zinc-mercury amalgams had major adverse properties that make them undesirable for land disposal. In particular, they reacted readily in air to form oxides and liberate elemental mercury. Another major finding of this study is that sulfur polymer cement is potentially useful as a physical encapsulating agent for mercuric sulfide. This material provides a barrier in addition to the chemical stabilization that further prevents mercury, in the form of mercuric sulfide, from migrating into the environment.

Gorin, A.H.; Leckey, J.H.; Nulf, L.E.

1994-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device  

SciTech Connect (OSTI)

Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

Charles Mones

2006-12-01T23:59:59.000Z

382

Emerging technologies and approaches to minimize discharges into Lake Michigan Phase 2, Module 3 report.  

SciTech Connect (OSTI)

Purdue University Calumet (Purdue) and Argonne National Laboratory (Argonne) have conducted an independent study to identify deployable technologies that could help the BP Whiting Refinery, and other petroleum refineries, meet future wastewater discharge limits. This study has been funded by BP. Each organization tested a subset of the target technologies and retains sole responsibility for its respective test design and implementation, quality assurance and control, test results obtained from each of the technologies, and corresponding conclusions and recommendations. This project was divided in two phases and modules. This report summarizes the work conducted by Argonne in Phase II Module 3 (Bench Scale Testing). Other Modules are discussed elsewhere (Emerging Technologies and Approaches to Minimize Discharges into Lake Michigan, Phase 2, Modules 1-3 Report, April 2011, prepared for BP Americas by the Argonne - Purdue Task Force). The goal of this project was to identify and assess available and emerging wastewater treatment technologies for removing mercury and vanadium from the Whiting Refinery wastewater and to conduct bench-scale tests to provide comparable, transparent, and uniform results across the broad range of technologies tested. After the bench-scale testing phase, a previously developed decision matrix was refined and applied by Argonne to process and review test data to estimate and compare the preliminary performance, engineering configuration, preliminary cost, energy usage, and waste generation of technologies that were shown to be able to remove Hg and/or V to below the target limit at the bench scale. The data were used as the basis to identify the best candidates for further testing at the bench or pilot scale on a slip stream of effluent to lake (ETL) or clarifier effluent (CE) at the Whiting Refinery to determine whether future limits could be met and to generate other pertinent data for scale-up and sustainability evaluation. As a result of this technology assessment, Argonne identified several technologies that, at the bench-scale, could achieve the targeted performance for the removal of mercury and vanadium. A subset of those technologies were recommended for further testing either at the bench scale or at the pilot scale to determine whether future discharge limits could be met at the pilot-scale. The objectives of this project module are to: (1) Test at the bench-scale a subset of the technologies previously identified in Module 1 for the removal of target heavy metals down to 1.3 ppt Hg and 280 ppb V; (2) Review and process bench-scale test results on the basis of the end-point performance measures matrix to determine preliminary comparative performance, cost-effectiveness, and potential engineering configuration of tested technologies; (3) Assess the technological feasibility and readiness of the identified technologies for implementation at the Whiting Refinery; and (4) Select technically and economically feasible mercury- and vanadium-removal technologies and vendors to be recommended for pilot-scale testing at the Whiting Refinery.

Negri, M. C.; Gillenwater, P.; Urgun Demirtas, M. (Energy Systems)

2011-05-11T23:59:59.000Z

383

Ternary gas mixture for diffuse discharge switch  

DOE Patents [OSTI]

A new diffuse discharge gas switch wherein a mixture of gases is used to take advantage of desirable properties of the respective gases. There is a conducting gas, an insulating gas, and a third gas that has low ionization energy resulting in a net increase in the number of electrons available to produce a current.

Christophorou, Loucas G. (Oak Ridge, TN); Hunter, Scott R. (Oak Ridge, TN)

1988-01-01T23:59:59.000Z

384

Electrostatic precipitator having high strength discharge electrode  

SciTech Connect (OSTI)

There is disclosed an electrostatic precipitator with a discharge electrode having dimensional and configuration characteristics which provide high field strength and high current density particularly in a wet electrostatic precipitator. The round cylindrical collector tube of length (L) and with an inner diameter (D) has a coaxially positioned discharge electrode having an electrode supporting mast of a diameter from 0.25 to 40 D with an electrically conducting closed screw fli secured to the mast. The screw flight has an overall diameter (D) of from 0.33 to 0.67 D with a pitch of from d-d/2 to d-d and an overall length of from one screw revolution to l-(D-d), preferably one-half L or less and most preferably one to two revolutions. The short screw flight is economical and readily adjusted. The screw flight has a thickness of from about 0.05 to 15 inch and has a symmetrically curved outer edge. Collector tube is flared at its lower end to direct water away from the electrode mast as the water is discharged from the tube. The discharge electrode is supported from above and centered by means of adjustable tie rods at its lower end.

Bakke, E.; Willett, H.P.

1983-06-21T23:59:59.000Z

385

The electrodeless discharge at atmospheric pressure  

SciTech Connect (OSTI)

Recently the generation and applications of atmospheric pressure plasmas received increased interest in the plasma research community. Applications such as the surface modification of materials, and the decontamination of matter have been under investigation. In this context, the authors introduce a new means of generating an atmospheric pressure discharge, which is suitable for use in the above-mentioned applications, and in the treatment of undesirable or polluting gases, such as VOC's. This device is a capacitively coupled discharge. It is basically made of a non-conducting tube with two independent loops of wire wrapped around it, and separated by a distance d. A stable discharge is generated inside the tube when an AC voltage of few hundred volts to few kilovolts, at a frequency of few kilohertz, is applied between the loops. One end of the tube is completely open to the outside air, and a seed gas (generally a noble gas such as Helium) is introduced in the tube. The plasma generated with this method is weakly ionized, cold, and is maintained by a relatively low input power (few tens of watts, depending on the size of the tube). In this paper, the discharge electrical characteristics, its radiation emission characteristics, and the measurement of relevant plasma parameters will be presented.

Laroussi, M.

1999-07-01T23:59:59.000Z

386

Fate of Mercury in Synthetic Gypsum Used for Wallboard Production  

SciTech Connect (OSTI)

This report presents and discusses results from the project 'Fate of Mercury in Synthetic Gypsum Used for Wallboard Production', performed at five different full-scale commercial wallboard plants. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies involve the capture of mercury in FGD systems. The objective of this study has been to determine whether any mercury is released into the atmosphere at wallboard manufacturing plants when the synthetic gypsum material is used as a feedstock for wallboard production. The project has been co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope included seven discrete tasks, each including a test conducted at various USG wallboard plants using synthetic gypsum from different wet FGD systems. The project was originally composed of five tasks, which were to include (1) a base-case test, then variations representing differing power plant: (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5,could not be conducted as planned and instead was conducted at conditions similar to Task 3. Subsequently an opportunity arose to test gypsum produced from the Task 5 FGD system, but with an additive expected to impact the stability of mercury, so Task 6 was added to the project. Finally, Task 7 was added to evaluate synthetic gypsum produced at a power plant from an additional coal type. In the project, process stacks in the wallboard plant were sampled using the Ontario Hydro method. In every task, the stack locations sampled included a gypsum dryer and a gypsum calciner. In Tasks 1 and 4 through 7, the stack of the dryer for the wet wallboard product was also tested. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. These results and process data were used to construct mercury mass balances across the wallboard plants. The results from the project showed a wide range of percentage mercury losses from the synthetic gypsum feedstocks as measured by the Ontario Hydro method at the process stacks, ranging from 2% to 55% of the mercury in the gypsum feedstock. For the tasks exceeding 10% mercury loss across the wallboard plant, most of the loss occurred across the gypsum calciner. When total wallboard emissions remained below 10%, the primary emission location varied with a much less pronounced difference in emission between the gypsum dryer, calciner and board dryer. For all seven tasks, the majority of the mercury emissions were measured to be in the elemental form (Hg{sup 0}). Overall, the measured mercury loss mass rates ranged from 0.01 to 0.17 grams of mercury per dry ton of synthetic gypsum processed, or 0.01 to 0.4 pounds of mercury released per million square feet of wallboard produced from synthetic gypsum. The Coal Combustion Product Production and Use Survey from the American Coal Ash Association (ACAA) indicate that 7,579,187 short tons of synthetic gypsum were used for wallboard production in 2006. Extrapolating the results of this study to the ACAA industry usage rate, we estimate that mercury releases from wallboard production plants in 2006 ranged between 150 to 3000 pounds for the entire U.S. wallboard industry. With only seven sets of wallboard plant measurements, it is difficult to draw firm conclusions about what variables impact the mercury loss percentages across the wallboard plants. One significant o

Jessica Sanderson

2007-12-31T23:59:59.000Z

387

DATABASE Open Access Regional distribution of mercury in sediments  

E-Print Network [OSTI]

DATABASE Open Access Regional distribution of mercury in sediments of the main rivers of French led to locally high concentrations in soils and sediments. The present study maps the levels of Hg concentrations in river sediments from five main rivers of French Guiana (Approuague River, Comté River, Mana

Boyer, Edmond

388

Dark Oxidation of Dissolved and Liquid Elemental Mercury in Aquatic  

E-Print Network [OSTI]

Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada Elemental mercury (Hg0) can be found in liquid that this oxidation is greatly enhanced by solar radiation, par- ticularly-sterilized, treated with chloroform, or filtered prior to exposure to light. Laboratory experiments have also shown

Morel, Franois M. M.

389

EFFECTS OF LONG-TERM MERCURY EXPOSURE ON HEMATOLOGY OF  

E-Print Network [OSTI]

is limited; even the response of the species to mercury, perhaps the most widely studied heavy metal, has America; hence, it is subjected to considerable domestic and industrial pollution. Even higher pollutant- lution is a problem, the striped bass may be a particularly appropriate indicator species for pollution

390

UNCERTAINTY IN PALEOECOLOGICAL STUDIES OF MERCURY IN SEDIMENT CORES  

E-Print Network [OSTI]

and required corrections for remaining water content. Frozen sediments did not lose Hg during a 72-day storage of the analysis (while adhering to strict QA/QC criteria) produced compounded uncertainties of ±11 and ±29% in Hg to correctly evaluate trends and remediation efforts. Keywords: Florida Everglades, Lake Erie, mercury

Gottgens, Hans

391

Water and Mercury Pipe Flow Simulation in FLUENTSimulation in FLUENT  

E-Print Network [OSTI]

Water and Mercury Pipe Flow Simulation in FLUENTSimulation in FLUENT Yan Zhan, Foluso Ladeinde Stony Brook University thSep.21th , 2010 #12;OutlineOutline · Straight Pipe flowStraight Pipe flow · Curved pipe flow #12;OutlineOutline · Straight Pipe flowStraight Pipe flow · Curved pipe flow #12

McDonald, Kirk

392

Final Report - Molecular Mechanisms of Bacterial Mercury Transformation - UCSF  

SciTech Connect (OSTI)

The bacterial mercury resistance (mer) operon functions in Hg biogeochemistry and bioremediation by converting reactive inorganic Hg(II) and organic [RHg(II)]1+ mercurials to relatively inert monoatomic mercury vapor, Hg(0). Its genes regulate operon expression (MerR, MerD, MerOP), import Hg(II) (MerT, MerP, and MerC), and demethylate (MerB) and reduce (MerA) mercurials. We focus on how these components interact with each other and with the host cell to allow cells to survive and detoxify Hg compounds. Understanding how this ubiquitous detoxification system fits into the biology and ecology of its bacterial host is essential to guide interventions that support and enhance Hg remediation. In the current overall project we focused on two aspects of this system: (1) investigations of the energetics of Hg(II)-ligand binding interactions, and (2) both experimental and computational approaches to investigating the molecular mechanisms of Hg(II) acquisition by MerA and intramolecular transfer of Hg(II) prior to reduction within the MerA enzyme active site. Computational work was led by Prof. Jeremy Smith and took place at the University of Tennessee, while experimental work on MerA was led by Prof. Susan Miller and took place at the University of California San Francisco.

Miller, Susan M. [UCSF

2014-04-24T23:59:59.000Z

393

MERCURY IN THE ENVIRONMENT: Transport, Fate and Policy  

E-Print Network [OSTI]

Division and Department of Earth, Atmospheric and Planetary Sciences Massachusetts Institute of Technology increased 3-5X since industrialization Major anthropogenic source is stationary combustion (coal evidence to warrant international action U.S.: Clean Air Mercury Rule: established "cap and trade" approach

Selin, Noelle Eckley

394

Mercury Surface, Space Environment, Geochemistry, and Ranging Mission  

E-Print Network [OSTI]

Carnegie Institution of Washington NASA Goddard Space Flight Center University of Michigan Southwest's atmosphere generated? Does Mercury have ice at its poles? Combining an ultraviolet spectrometer and infrared McClintock Other organizations involved: The Johns Hopkins University Applied Physics Laboratory

Mojzsis, Stephen J.

395

Mercury emission behavior during isolated coal particle combustion  

E-Print Network [OSTI]

ppb and 140ppb. In order to understand the basic process of formulation of HgCl2 and Hg0 a numerical model is developed in the current work to simulate in the detail i) heating ii) transient pyrolysis of coal and evolution of mercury and chlorine, iii...

Puchakayala, Madhu Babu

2009-05-15T23:59:59.000Z

396

Impact of Surface Heterogeneity on Mercury Uptake by Carbonaceous  

E-Print Network [OSTI]

pyrolytic graphite, HOPG) under ultrahigh vacuum (UHV) conditions and fixed bed adsorption by activated to the environment from fossil fuel burning and various combustion processes (i.e., mu- nicipal, medical combustion. Once emitted to the environment, mercury can be deposited locally or globally to create a long

Borguet, Eric

397

Chemistry of Mercury Species and Their Control in Coal Combustion  

SciTech Connect (OSTI)

The objectives for this reporting period are: 1) The study of mercury capture mechanism by using titania sorbent and ultraviolet (UV) light, and the study of structural difference between titania particle generated by both thermal Oxidation at 1000EC and by reacting with water vapor at room temperature. 2) Measurement of ultra-fine particle size distribution in flue gas after burning coal.

None

1997-08-30T23:59:59.000Z

398

Cage diffusion in liquid mercury Yaspal S. Badyal  

E-Print Network [OSTI]

University, Massachusetts 02138, USA Ignatz M. de Schepper Interfaculty Reactor Institute, TU Delft, 2629 JB(q,E). It is believed that cage diffusion plays an important part in the dynamics of real fluids, such as noble gas on the fast short-time decay mechanism of liquid mercury pertinent to cage diffu- sion. Recent neutron

Montfrooij, Wouter

399

Investigation of modified speciation for enhanced control of mercury  

SciTech Connect (OSTI)

Mercury was identified as a hazardous air pollutant in Title 3 of the 1990 Clean Air Act Amendments. It has been singled out for particular scrutiny because of its behavior in the environment (bioaccumulation) and its potential for deleterious effects on humans and wildlife. After studying the sources of mercury in the environment, the US Environmental Protection Agency has concluded that coal-fired boilers generate a significant fraction of the total anthropogenic emissions. Therefore, the agency is currently considering whether to impose mercury control requirements on coal-fired boilers in the electric utility industry. However, the costs for potential control measures (such as sorbent injection) can be extremely high. Mercury removal with chloric acid solutions was tested. The presence of NO increased Hg removal. It appeared that both gas-gas and gas-liquids reactions were operating, with the gas-phase reactions involving NO becoming increasingly important as the solute concentration was raised. From these studies, it was concluded that even higher Hg{sup 0} removals could be obtained if more of the reagent was made available for reaction in the gas phase. For this reason (and also to simulate a more real-world duct-injection process) a new series of tests was initiated in which an ultrasonic atomizer was used to inject small droplets of the oxidizing solutions into a flowing gas stream containing Hg{sup 0} vapors and other typical flue-gas components. The results of those tests are described in this paper.

Livengood, C.D.; Mendelsohn, M.H.

1998-08-01T23:59:59.000Z

400

Gas Bubble Formation in Stagnant and Flowing Mercury  

SciTech Connect (OSTI)

Investigations in the area of two-phase flow at the Oak Ridge National Laboratory's (ORNL) Spallation Neutron Source (SNS) facility are progressing. It is expected that the target vessel lifetime could be extended by introducing gas into the liquid mercury target. As part of an effort to validate the two-phase computational fluid dynamics (CFD) model, simulations and experiments of gas injection in stagnant and flowing mercury have been completed. The volume of fluid (VOF) method as implemented in ANSYS-CFX, was used to simulate the unsteady two-phase flow of gas injection into stagnant mercury. Bubbles produced at the upwards-oriented vertical gas injector were measured with proton radiography at the Los Alamos Neutron Science Center. The comparison of the CFD results to the radiographic images shows good agreement for bubble sizes and shapes at various stages of the bubble growth, detachment, and gravitational rise. Although several gas flows were measured, this paper focuses on the case with a gas flow rate of 8 cc/min through the 100-micron-diameter injector needle. The acoustic waves emitted due to the detachment of the bubble and during subsequent bubble oscillations were recorded with a microphone, providing a precise measurement of the bubble sizes. As the mercury flow rate increases, the drag force causes earlier bubble detachment and therefore smaller bubbles.

Wendel, Mark W [ORNL] [ORNL; Abdou, Ashraf A [ORNL] [ORNL; Riemer, Bernie [ORNL] [ORNL; Felde, David K [ORNL] [ORNL

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Numerical Simulation of Bubble Formation in Co-Flowing Mercury  

SciTech Connect (OSTI)

In this work, we present computational fluid dynamics (CFD) simulations of helium bubble formation and detachment at a submerged needle in stagnant and co-flowing mercury. Since mercury is opaque, visualization of internal gas bubbles was done with proton radiography (pRad) at the Los Alamos Neutron Science Center (LANSCE2). The acoustic waves emitted at the time of detachment and during subsequent oscillations of the bubble were recorded with a microphone. The Volume of Fluid (VOF) model was used to simulate the unsteady two-phase flow of gas injection in mercury. The VOF model is validated by comparing detailed bubble sizes and shapes at various stages of the bubble growth and detachment, with the experimental measurements at different gas flow rates and mercury velocities. The experimental and computational results show a two-stage bubble formation. The first stage involves growing bubble around the needle, and the second follows as the buoyancy overcomes wall adhesion. The comparison of predicted and measured bubble sizes and shapes at various stages of the bubble growth and detachment is in good agreement.

Abdou, Ashraf A [ORNL; Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL

2008-01-01T23:59:59.000Z

402

Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511  

SciTech Connect (OSTI)

The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively purified and collected in the Mercury Purification Cell (MPC) since 2008. A significant cleaning campaign aims to bring the MPC back up to facility housekeeping standards. Two significant investigations are being undertaken to restore mercury collection. The SMECT mercury pump has been removed from the tank and will be functionally tested. Also, research is being conducted by the Savannah River National Laboratory to determine the effects of antifoam addition on the behavior of mercury. These path forward items will help us better understand what is occurring in the mercury collection system and ultimately lead to an improved DWPF production rate and mercury recovery rate. (authors)

Behrouzi, Aria [Savannah River Remediation, LLC (United States); Zamecnik, Jack [Savannah River National Laboratory, Aiken, South Carolina, 29808 (United States)

2012-07-01T23:59:59.000Z

403

Mercury stabilization in chemically bonded phosphate ceramics  

SciTech Connect (OSTI)

Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out. This paper discusses the authors experience on bench-scale stabilization of various US Department of Energy (DOE) waste streams containing Hg in the CBPC process. This process was developed to treat DOE's mixed waste streams. It is a room-temperature-setting process based on an acid-base reaction between magnesium oxide and monopotassium phosphate solution that forms a dense ceramic within hours. For Hg stabilization, addition of a small amount (< 1 wt.%) of Na{sub 2}S or K{sub 2}S is sufficient in the binder composition. Here the Toxicity Characteristic Leaching Procedure (TCLP) results on CBPC waste forms of surrogate waste streams representing secondary Hg containing wastes such as combustion residues and Delphi DETOX{trademark} residues are presented. The results show that although the current limit on leaching of Hg is 0.2 mg/L, the results from the CBPC waste forms are at least one order lower than this stringent limit. Encouraged by these results on surrogate wastes, they treated actual low-level Hg-containing mixed waste from their facility at Idaho. TCLP results on this waste are presented here. The efficient stabilization in all these cases is attributed to chemical immobilization as both a sulfide (cinnabar) and a phosphate, followed by its physical encapsulation in a dense matrix of the ceramic.

Wagh, A. S.; Singh, D.; Jeong, S. Y.

2000-04-04T23:59:59.000Z

404

Selenium inhibits the phytotoxicity of mercury in garlic (Allium sativum)  

SciTech Connect (OSTI)

To investigate the influence of selenium on mercury phytotoxicity, the levels of selenium and mercury were analyzed with inductively coupled plasma-mass spectrometry (ICP-MS) in garlic tissues upon exposure to different dosages of inorganic mercury (Hg{sup 2+}) and selenite (SeO{sub 3}{sup 2?}) or selenate (SeO{sub 4}{sup 2?}). The distributions of selenium and mercury were examined with micro-synchrotron radiation X-ray fluorescence (?-SRXRF), and the mercury speciation was investigated with micro-X-ray absorption near edge structure (?-XANES). The results show that Se at higher exposure levels (>1 mg/L of SeO{sub 3}{sup 2?} or SeO{sub 4}{sup 2?}) would significantly inhibit the absorption and transportation of Hg when Hg{sup 2+} levels are higher than 1 mg/L in culture media. SeO{sub 3}{sup 2?} and SeO{sub 4}{sup 2?} were found to be equally effective in reducing Hg accumulation in garlic. The inhibition of Hg uptake by Se correlates well with the influence of Se on Hg phytotoxicity as indicated by the growth inhibition factor. Elemental imaging using ?-SRXRF also shows that Se could inhibit the accumulation and translocation of Hg in garlic. ?-XANES analysis shows that Hg is mainly present in the forms of HgS bonding as Hg(GSH){sub 2} and Hg(Met){sub 2}. Se exposure elicited decrease of HgS bonding in the form of Hg(GSH){sub 2}, together with Se-mediated alteration of Hg absorption, transportation and accumulation, may account for attenuated Hg phytotoxicity by Se in garlic. -- Highlights: ? Hg phytotoxicity can be mitigated by Se supplement in garlic growth. ? Se can inhibit the accumulation and transportation of Hg in garlic tissues. ? Localization and speciation of Hg in garlic can be modified by Se.

Zhao, Jiating [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Gao, Yuxi, E-mail: gaoyx@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Li, Yu-Feng; Hu, Yi; Peng, Xiaomin [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Dong, Yuanxing [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China)] [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China); Li, Bai; Chen, Chunying [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Chai, Zhifang, E-mail: chaizf@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

2013-08-15T23:59:59.000Z

405

Selective partitioning of mercury from co-extracted actinides in a simulated acidic ICPP waste stream  

SciTech Connect (OSTI)

The TRUEX process is being evaluated at the Idaho Chemical Processing Plant (ICPP) as a means to partition the actinides from acidic sodium-bearing waste (SBW). The mercury content of this waste averages 1 g/l. Because the chemistry of mercury has not been extensively evaluated in the TRUEX process, mercury was singled out as an element of interest. Radioactive mercury, {sup 203}Hg, was spiked into a simulated solution of SBW containing 1 g/l mercury. Successive extraction batch contacts with the mercury spiked waste simulant and successive scrubbing and stripping batch contacts of the mercury loaded TRUEX solvent (0.2 M CMPO-1.4 M TBP in dodecane) show that mercury will extract into and strip from the solvent. The extraction distribution coefficient for mercury, as HgCl{sub 2} from SBW having a nitric acid concentration of 1.4 M and a chloride concentration of 0.035 M was found to be 3. The stripping distribution coefficient was found to be 0.5 with 5 M HNO{sub 3} and 0.077 with 0.25 M Na{sub 2}CO{sub 3}. An experimental flowsheet was designed from the batch contact tests and tested counter-currently using 5.5 cm centrifugal contactors. Results from the counter-current test show that mercury can be removed from the acidic mixed SBW simulant and recovered separately from the actinides.

Brewer, K.N.; Herbst, R.S.; Tranter, T.J. [and others

1995-12-01T23:59:59.000Z

406

Experimental investigation of electron multipactor discharges at very high frequency  

E-Print Network [OSTI]

Multipactor discharges are a resonant condition in which electrons impact a surface in phase with an alternating electric field. The discharge is sustained by electron multiplication from secondary emission. As motivation, ...

Graves, Timothy P. (Timothy Paul)

2006-01-01T23:59:59.000Z

407

Montana Facilities Which Do Not Discharge Process Wastewater...  

Open Energy Info (EERE)

Which Do Not Discharge Process Wastewater (MDEQ Form 2E) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Montana Facilities Which Do Not Discharge Process...

408

Residual dust charges in discharge afterglow L. Couedel,  

E-Print Network [OSTI]

was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force

Paris-Sud XI, Universit de

409

Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton  

SciTech Connect (OSTI)

The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

2007-03-31T23:59:59.000Z

410

Low-Cost Options for Moderate Levels of Mercury Control  

SciTech Connect (OSTI)

This is the final technical report for a three-site project that is part of an overall program funded by the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL) and industry partners to obtain the necessary information to assess the feasibility and costs of controlling mercury from coal-fired utility plants. This report summarizes results from tests conducted at MidAmerican's Louisa Generating Station and Entergy's Independence Steam Electric Station (ISES) and sorbent screening at MidAmerican's Council Bluffs Energy Center (CBEC) (subsequently renamed Walter Scott Energy Center (WSEC)). Detailed results for Independence and Louisa are presented in the respective Topical Reports. As no full-scale testing was conducted at CBEC, screening updates were provided in the quarterly updates to DOE. ADA-ES, Inc., with support from DOE/NETL, EPRI, and other industry partners, has conducted evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. An overview of each plant configuration is presented: (1) MidAmerican's Louisa Generating Station burns Powder River Basin (PRB) coal in its 700-MW Unit 1 and employs hot-side electrostatic precipitators (ESPs) with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal. (2) MidAmerican's Council Bluffs Energy Center typically burns PRB coal in its 88-MW Unit 2. It employs a hot-side ESP for particulate control. Solid sorbents were screened for hot-side injection. (3) Entergy's Independence Steam Electric Station typically burns PRB coal in its 880-MW Unit 2. Various sorbent injection tests were conducted on 1/8 to 1/32 of the flue gas stream either within or in front of one of four ESP boxes (SCA = 542 ft{sup 2}/kacfm), specifically ESP B. Initial mercury control evaluations indicated that although significant mercury control could be achieved by using the TOXECON II{trademark} design, the sorbent concentration required was higher than expected, possibly due to poor sorbent distribution. Subsequently, the original injection grid design was modeled and the results revealed that the sorbent distribution pattern was determined by the grid design, fluctuations in flue gas flow rates, and the structure of the ESP box. To improve sorbent distribution, the injection grid and delivery system were redesigned and the effectiveness of the redesigned system was evaluated. This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase II project with the goal of developing mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. Results from testing at Independence indicate that the DOE goal was successfully achieved. Further improvements in the process are recommended, however. Results from testing at Louisa indicate that the DOE goal was not achievable using the tested high-temperature sorbent. Sorbent screening at Council Bluffs also indicated that traditional solid sorbents may not achieve significant mercury removal in hot-side applications.

Sharon Sjostrom

2008-02-09T23:59:59.000Z

411

Hanford Identification (HID) PIA, Richland Operations Office | Department  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecemberGlossary ofGroundwaterHC Policy andHQTargets |of

412

RAPID/Roadmap/18-HI-d | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExploration JumpSanyalTempWellheadWahkiakumNV-a Nonpoint7-FD-a Wild8-HI-b RCRA 18HIB

413

RAPID/Roadmap/3-HI-d | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExploration JumpSanyalTempWellheadWahkiakumNV-a20-AK-a WellAK-g UtilityHI-d Use and

414

RAPID/Roadmap/6-HI-d | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-g Grant of Access Permit5-ID-a Drilling and Well5-OR-a6AK-bHI-c

415

RAPID/Roadmap/14-HI-d | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, search RAPIDColorado < RAPID‎ |1-TX-a13-ID-a State14-FD-c EPA

416

Gas mixture for diffuse-discharge switch  

DOE Patents [OSTI]

Gaseous medium in a diffuse-discharge switch of a high-energy pulse generator is formed of argon combined with a compound selected from the group consisting of CF/sub 4/, C/sub 2/F/sub 6/, C/sub 3/F/sub 8/, n-C/sub 4/F/sub 10/, WF/sub 6/, (CF/sub 3/)/sub 2/S and (CF/sub 3/)/sub 2/O.

Christophorou, L.G.; Carter, J.G.; Hunter, S.R.

1982-08-31T23:59:59.000Z

417

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dryer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the seventh in a series of topical reports, describes the results and analysis of mercury sampling performed on a 1,300 MW unit burning a bituminous coal containing three percent sulfur. The unit was equipped with an ESP and a limestone-based wet FGD to control particulate and SO2 emissions, respectively. At the time of sampling an SCR was not installed on this unit. Four sampling tests were performed in September 2003. Flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. The results show that the FGD inlet flue gas oxidized:elemental mercury ratio was roughly 2:1, with 66% oxidized mercury and 34% elemental mercury. Mercury removal, on a coal-to-stack basis, was 53%. The average Hg concentration in the stack flue gas was 4.09 {micro}g/m{sup 3}. The average stack mercury emission was 3.47 Ib/TBtu. The mercury material balance closures ranged from 87% to 108%, with an average of 97%. A sampling program similar to this one was performed on a similar unit (at the same plant) that was equipped with an SCR for NOx control. Comparison of the results from the two units show that the SCR increases the percentage of mercury that is in the oxidized form, which, in turn, lends to more of the total mercury being removed in the wet scrubber. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NOx, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal.

J.A. Withum; S.C. Tseng; J.E. Locke

2005-11-01T23:59:59.000Z

418

Environmental chamber measurements of mercury flux from coal utilization by-products  

SciTech Connect (OSTI)

An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

2009-05-01T23:59:59.000Z

419

Demonstration Results on the Effects of Mercury Speciation on the Stabilization of Wastes  

SciTech Connect (OSTI)

Mercury-contaminated wastes are currently being stored at approximately 19 Department of Energy sites, the volume of which is estimated to be about 16m(sup)3. These wastes exist in various forms including soil, sludges, and debris, which present a particular challenge regarding possible mercury stabilization methods. This reports provides the test results of three vendors, Allied Technology Group, IT Corporation, and Nuclear Fuel Services, Inc., that demonstrate the effects of mercury speciation on the stabilization of the mercury wastes. Mercury present in concentrations that exceed 260 parts per million must be removed by extraction methods and requires stabilization to ensure that the final wasteforms leach less than 0.2mg/L of mercury by the Toxicity Characteristic Leaching Procedure or 0.025 mg/L using the Universal Treatment Standard.

Conley, T.B.; Hulet, G.A.; Morris, M.I.; Osborne-Lee, I.W.

1999-06-01T23:59:59.000Z

420

Treatability study for removal of leachable mercury in crushed fluorescent lamps  

SciTech Connect (OSTI)

Nonserviceable fluorescent lamps removed from radiological control areas at the Oak Ridge Department of Energy facilities have been crushed and are currently managed as mixed waste (hazardous and radiologically contaminated). We present proposed treatment flowsheets and supporting treatability study data for conditioning this solid waste residue so that it can qualify for disposal in a sanitary landfill. Mercury in spent fluorescent lamps occurs primarily as condensate on high-surface-area phosphor material. It can be solubilized with excess oxidants (e.g., hypochlorite solution) and stabilized by complexation with halide ions. Soluble mercury in dechlorinated saline solution is effectively removed by cementation with zero-valent iron in the form of steel wool. In packed column dynamic flow testing, soluble mercury was reduced to mercury metal and insoluble calomel, loading > 1.2 g of mercury per grain of steel wool before an appreciable breakthrough of soluble mercury in the effluent.

Bostick, W.D.; Beck, D.E.; Bowser, K.T. [and others

1996-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Magnetism in LithiumOxygen Discharge Product  

SciTech Connect (OSTI)

Nonaqueous lithiumoxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithiumoxygen batteries. We demonstrate that the major discharge product formed in the lithiumoxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

2013-05-13T23:59:59.000Z

422

Capacitor discharge process for welding braided cable  

DOE Patents [OSTI]

A capacitor discharge process for welding a braided cable formed from a plurality of individual cable strands to a solid metallic electrically conductive member comprises the steps of: (a) preparing the electrically conductive member for welding by bevelling one of its end portions while leaving an ignition projection extending outwardly from the apex of the bevel; (b) clamping the electrically conductive member in a cathode fixture; (c) connecting the electrically conductive member clamped in the cathode fixture to a capacitor bank capable of being charged to a preselected voltage value; (d) preparing the braided cable for welding by wrapping one of its end portions with a metallic sheet to form a retaining ring operable to maintain the individual strands of the braided cable in fixed position within the retaining ring; (e) clamping the braided cable and the retaining ring as a unit in an anode fixture so that the wrapped end portion of the braided cable faces the ignition projection of the electrically conductive member; and (f) moving the cathode fixture towards the anode fixture until the ignition projection of the electrically conductive member contacts the end portion of the braided cable thereby allowing the capacitor bank to discharge through the electrically conductive member and through the braided cable and causing the electrically conductive member to be welded to the braided cable via capacitor discharge action.

Wilson, Rick D. (Corvallis, OR)

1995-01-01T23:59:59.000Z

423

MERCURY CONTROL WITH THE ADVANCED HYBRID PARTICULATE COLLECTOR  

SciTech Connect (OSTI)

This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addresses Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team includes the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and is now marketed as the ADVANCED HYBRID{trademark} Filter by Gore. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The AHPC appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas-solid contactor. The objective of the three-task project is to demonstrate 90% total mercury control in the AHPC at a lower cost than current mercury control estimates. The approach includes bench-scale batch testing that ties the new work to previous results and links results with larger-scale pilot testing with real flue gas on a coal-fired combustion system, pilot-scale testing on a coal-fired combustion system with both a pulse-jet baghouse and an AHPC to prove or disprove the research hypotheses, and field demonstration pilot-scale testing at a utility power plant to prove scaleup and demonstrate longer-term mercury control. This project, if successful, will demonstrate at the pilot-scale level a technology that would provide a cost-effective technique to accomplish control of mercury emissions and, at the same time, greatly enhance fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution to a large segment of the U.S. utility industry as well as other industries requiring mercury control.

Stanley J. Miller; Ye Zhuang; Michelle R. Olderbak

2002-11-01T23:59:59.000Z

424

Atmospheric Mercury near Salmon Falls Creek Reservoir in Southern Idaho  

SciTech Connect (OSTI)

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over two-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran mercury analyzers. GEM, RGM, and particulate mercury (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize mercury air concentrations in the southern Idaho area for the first time, estimate mercury dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 0.9 ng m-3) and RGM (8.1 5.6 pg m-3) concentrations occurring in the summer and lower values in the winter (1.32 0.3 ng m-3, 3.2 2.9 pg m-3 for GEM, RGM respectively). The summer-average HgP concentrations were generally below detection limit (0.6 1 pg m-3). Seasonally-averaged deposition velocities calculated using a resistance model were 0.034 0.032, 0.043 0.040, 0.00084 0.0017 and 0.00036 0.0011 cm s-1 for GEM (spring, summer, fall, and winter, respectively) and 0.50 0.39, 0.40 0.31, 0.51 0.43 and 0.76 0.57 cm s-1 for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 3.3 g m-2, or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2 12 ng m-3) and RGM (50 - 150 pg m-3) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicated predominant source directions from the southeast (western Utah, northeastern Nevada) through the southwest (north-central Nevada) with fewer inputs from the northwest (southeastern Oregon and southwestern Idaho).

Michael L. Abbott; Jeffrey J. Einerson

2007-12-01T23:59:59.000Z

425

Mercury's moment of inertia from spin and gravity data Jean-Luc Margot,1,2  

E-Print Network [OSTI]

Mercury's moment of inertia from spin and gravity data Jean-Luc Margot,1,2 Stanton J. Peale,3 Sean of Mercury at 35 epochs between 2002 and 2012 reveal that its spin axis is tilted by (2.04 ? 0.08) arc min with respect to the orbit normal. The direction of the tilt suggests that Mercury is in or near a Cassini state

Hauck II, Steven A.

426

190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal Halide Lamp  

E-Print Network [OSTI]

lamp has been investigated using a two-dimensional, plasma transport model. Im- ages are presented- charge devices, lighting, plasma applications. METAL halide high-intensity-discharge (HID) lamps op- erate as high-pressure thermal arcs [1]. The cold fills of HID lamps are typically 50­100 torr of a rare

Kushner, Mark

427

Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H.sub.2 O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg.sub.2 Cl.sub.2. The method for doing this involves dissolving a precise amount of Hg.sub.2 Cl.sub.2 in an electrolyte solution comprised of concentrated HCl and H.sub.2 O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1987-01-01T23:59:59.000Z

428

Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process is described for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H[sub 2]O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg[sub 2]Cl[sub 2]. The method for doing this involves dissolving a precise amount of Hg[sub 2]Cl[sub 2] in an electrolyte solution comprised of concentrated HCl and H[sub 2]O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg. 1 fig.

Grossman, M.W.; George, W.A.

1987-07-07T23:59:59.000Z

429

Sources of atmospheric mercury in the tropics: continuous observations at a coastal site in Suriname  

E-Print Network [OSTI]

to mercury pollution in Suriname including oxidation byat a coastal site in Suriname 1 , D. Wip 2 , T. Warneke 1 ,de Kom Universiteit van Suriname, Paramaribo, Suriname 3

Muller, D.; Wip, D.; Warneke, T.; Holmes, C. D; Dastoor, A.; Notholt, J.

2012-01-01T23:59:59.000Z

430

Environmental Toxicology INTER-AND INTRASPECIFIC VARIATION IN MERCURY BIOACCUMULATION BY SNAKES  

E-Print Network [OSTI]

--Reptiles Heavy metals Pollution Trophic position Stable isotopes INTRODUCTION Although the ecological value change, and environmental pollution [6]. Heavy metal contaminants such as mercury (Hg) are a major

Willson. J.D.

431

E-Print Network 3.0 - amalgam mercury exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

recycling. Amalgamating kits: These are sold by numerous safety... and lab supply vendors. In brief, the amalgamating powder is sprinkled over the droplets of mercury... ,...

432

E-Print Network 3.0 - assessing mercury levels Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

have an incomplete understanding of the transfer of ... Source: Toledo, University of - Lake Erie Center Collection: Geosciences ; Environmental Sciences and Ecology 51 Mercury in...

433

FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report  

SciTech Connect (OSTI)

Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

Searcy, K; Bltyhe, G M; Steen, W A

2012-02-28T23:59:59.000Z

434

E-Print Network 3.0 - atmospheric mercury deposition Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Program Collection: Geosciences ; Environmental Sciences and Ecology 32 Global 3-D land-ocean-atmosphere model for mercury: present-day vs. pre-industrial1 cycles and...

435

E-Print Network 3.0 - atmospheric mercury models Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

or distribute Atmospheric and Geologic Sources of Mercury Kejimkujik Park has no direct industrial... is atmospheric deposition. The global ... Source: O'Driscoll, Nelson -...

436

Correlations Between Gene Expression and Mercury Levels in Blood of Boys With and Without Autism  

E-Print Network [OSTI]

Molecular markers of heavy metal toxicitya new paradigm for2006). Mercury is a toxic and hazardous heavy metal that is

2011-01-01T23:59:59.000Z

437

Reel danger: power plant mercury pollution and the fish we eat  

SciTech Connect (OSTI)

This study is based on the first available data from US EPA's ongoing National Study of Chemical Residues in Lake Fish Tissue. From 1999-2001, EPA collected approximately two composite samples of one predator fish species and one bottom-dwelling fish species at 260 lakes, for a total of 520 composite samples, or 2,547 fish. It was found that every fish tested was contaminated with mercury. 55% of the fish tested contained mercury levels that exceed EPA's 'safe' limit for women of childbearing age, and 76% exceeded the safe limit for children under age three. Predator fish, including smallmouth bass, walleye, largemouth bass, lake trout, and Northern pike, had the highest average mercury concentrations. Coal-fired power plants are the single largest source of mercury emissions, contributing 41% of US mercury emissions. They released 90,370 pounds of mercury into the air in 2002, the most recent year for which EPA data are available. In January 2004, the Bush administration issued a proposal for regulating mercury from power plants. In the author's opinion, the EPA's proposal would delay even modest reductions in mercury emissions from power plants until after 2025. In contrast, the Clean Air Act calls for the maximum achievable reductions by 2008. It is recommended that the Bush administration reverse course and require coal-fired power plants to reduce mercury emissions by at least 90% by 2008. 79 refs., 4 figs., 11 tabs., 3 apps.

Figdor, E. [US Public Interest Research Group Education Fund (US PIRG) for Clear the Air, Washington, DC (United States)

2004-08-15T23:59:59.000Z

438

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

439

Sensitive glow discharge ion source for aerosol and gas analysis  

DOE Patents [OSTI]

A high sensitivity glow discharge ion source system for analyzing particles includes an aerodynamic lens having a plurality of constrictions for receiving an aerosol including at least one analyte particle in a carrier gas and focusing the analyte particles into a collimated particle beam. A separator separates the carrier gas from the analyte particle beam, wherein the analyte particle beam or vapors derived from the analyte particle beam are selectively transmitted out of from the separator. A glow discharge ionization source includes a discharge chamber having an entrance orifice for receiving the analyte particle beam or analyte vapors, and a target electrode and discharge electrode therein. An electric field applied between the target electrode and discharge electrode generates an analyte ion stream from the analyte vapors, which is directed out of the discharge chamber through an exit orifice, such as to a mass spectrometer. High analyte sensitivity is obtained by pumping the discharge chamber exclusively through the exit orifice and the entrance orifice.

Reilly, Peter T. A. (Knoxville, TN)

2007-08-14T23:59:59.000Z

440

Phenomena of oscillations in atmospheric pressure direct current glow discharges  

SciTech Connect (OSTI)

Self-sustained oscillations in a dc glow discharge with a semiconductor layer at atmospheric pressure were investigated by means of a one-dimensional fluid model. It is found that the dc glow discharge initially becomes unstable in the subnormal glow region and gives rise to oscillations of plasma parameters. A variety of oscillations with one or more frequencies have been observed under different conditions. The discharge oscillates between the glow discharge mode and the Townsend discharge mode in the oscillations with large amplitude while operates in the subnormal glow discharge mode all the while in the oscillations with small amplitude. Fourier Transform spectra of oscillations reveal the transition mechanism between different oscillations. The effects of semiconductor conductivity on the oscillation frequency of the dominant mode, gas voltage, as well as the discharge current have also been analyzed.

Liu, Fu-cheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Yan, Wen; Wang, De-zhen [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

2013-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "discharge hid mercury" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Method of preparing mercury with an arbitrary isotopic distribution  

DOE Patents [OSTI]

This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg[sub 2]Cl[sub 2], corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H[sub 2]O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H[sub 2]O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered. 1 fig.

Grossman, M.W.; George, W.A.

1986-12-16T23:59:59.000Z

442

Method of preparing mercury with an arbitrary isotopic distribution  

DOE Patents [OSTI]

This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg.sub.2 Cl.sub.2, corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H.sub.2 O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H.sub.2 O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1986-01-01T23:59:59.000Z

443

Semi-continuous detection of mercury in gases  

DOE Patents [OSTI]

A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2011-12-06T23:59:59.000Z

444

Kinetics of Mercury(II) Adsorption and Desorption on Soil  

E-Print Network [OSTI]

Kinetics of Mercury(II) Adsorption and Desorption on Soil Y U J U N Y I N , H E R B E R T E . A L L of Delaware, Newark, Delaware 19716 D O N A L D L . S P A R K S Department of Plant and Soil Sciences kinetics of Hg(II) on four soils at pH 6 were investigated to discern the mechanisms controlling

Sparks, Donald L.

445

Stimulation of erythrocyte phosphatidylserine exposure by mercury ions  

SciTech Connect (OSTI)

The sequelae of mercury intoxication include induction of apoptosis. In nucleated cells, Hg{sup 2+}-induced apoptosis involves mitochondrial damage. The present study has been performed to elucidate effects of Hg{sup 2+} in erythrocytes which lack mitochondria but are able to undergo apoptosis-like alterations of the cell membrane. Previous studies have documented that activation of a Ca{sup 2+}-sensitive erythrocyte scramblase leads to exposure of phosphatidylserine at the erythrocyte surface, a typical feature of apoptotic cells. The erythrocyte scramblase is activated by osmotic shock, oxidative stress and/or energy depletion which increase cytosolic Ca{sup 2+} activity and/or activate a sphingomyelinase leading to formation of ceramide. Ceramide sensitizes the scramblase to Ca{sup 2+}. The present experiments explored the effect of Hg{sup 2+} ions on erythrocytes. Phosphatidylserine exposure after mercury treatment was estimated from annexin binding as determined in FACS analysis. Exposure to Hg{sup 2+} (1 {mu}M) indeed significantly increased annexin binding from 2.3 {+-} 0.5% (control condition) to 23 {+-} 6% (n = 6). This effect was paralleled by activation of a clotrimazole-sensitive K{sup +}-selective conductance as measured by patch-clamp recordings and by transient cell shrinkage. Further experiments revealed also an increase of ceramide formation by {approx}66% (n = 7) after challenge with mercury (1 {mu}M). In conclusion, mercury ions activate a clotrimazole-sensitive K{sup +}-selective conductance leading to transient cell shrinkage. Moreover, Hg{sup 2+} increases ceramide formation. The observed mechanisms could similarly participate in the triggering of apoptosis in nucleated cells by Hg{sup 2+}.

Eisele, Kerstin [Department of Physiology, University of Tuebingen (Germany); Lang, Philipp A. [Department of Physiology, University of Tuebingen (Germany); Kempe, Daniela S. [Department of Physiology, University of Tuebingen (Germany); Klarl, Barbara A. [Department of Physiology, University of Tuebingen (Germany); Niemoeller, Olivier [Department of Physiology, University of Tuebingen (Germany); Wieder, Thomas [Department of Physiology, University of Tuebingen (Germany); Huber, Stephan M. [Department of Physiology, University of Tuebingen (Germany); Duranton, Christophe [Department of Physiology, University of Tuebingen (Germany); Lang, Florian [Department of Physiology, University of Tuebingen (Germany)]. E-mail: florian.lang@uni-tuebingen.de

2006-01-15T23:59:59.000Z

446

Mercury toxicokinetics-dependency on strain and gender  

SciTech Connect (OSTI)

Mercury (Hg) exposure from dental amalgam fillings and thimerosal in vaccines is not a major health hazard, but adverse health effects cannot be ruled out in a small and more susceptible part of the exposed population. Individual differences in toxicokinetics may explain susceptibility to mercury. Inbred, H-2-congenic A.SW and B10.S mice and their F1- and F2-hybrids were given HgCl{sub 2} with 2.0 mg Hg/L drinking water and traces of {sup 203}Hg. Whole-body retention (WBR) was monitored until steady state after 5 weeks, when the organ Hg content was assessed. Despite similar Hg intake, A.SW males attained a 20-30% significantly higher WBR and 2- to 5-fold higher total renal Hg retention/concentration than A.SW females and B10.S mice. A selective renal Hg accumulation but of lower magnitude was seen also in B10.S males compared with females. Differences in WBR and organ Hg accumulation are therefore regulated by non-H-2 genes and gender. Lymph nodes lacked the strain- and gender-dependent Hg accumulation profile of kidney, liver and spleen. After 15 days without Hg A.SW mice showed a 4-fold higher WBR and liver Hg concentration, but 11-fold higher renal Hg concentration, showing the key role for the kidneys in explaining the slower Hg elimination in A.SW mice. The trait causing higher mercury accumulation was not dominantly inherited in the F1 hybrids. F2 mice showed a large inter-individual variation in Hg accumulation, showing that multiple genetic factors influence the Hg toxicokinetics in the mouse. The genetically heterogeneous human population may therefore show a large variation in mercury toxicokinetics.

Ekstrand, Jimmy [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Nielsen, Jesper B. [Department of Environmental Medicine, University of Southern Denmark, DK-5000 Odense C (Denmark); Havarinasab, Said [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Zalups, Rudolfs K. [Division of Basic Medical Sciences, Mercer University School of Medicine, 1550 College Street, Macon, GA 31207 (United States); Soederkvist, Peter [Cell Biology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden); Hultman, Per, E-mail: perhu@imk.liu.s [Molecular and Immunological Pathology, Department of Clinical and Experimental Medicine, Linkoeping University, SE-581 85 Linkoeping (Sweden)

2010-03-15T23:59:59.000Z

447

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

448

Mercury and tritium removal from DOE waste oils  

SciTech Connect (OSTI)

This work covers the investigation of vacuum extraction as a means to remove tritiated contamination as well as the removal via sorption of dissolved mercury from contaminated oils. The radiation damage in oils from tritium causes production of hydrogen, methane, and low-molecular-weight hydrocarbons. When tritium gas is present in the oil, the tritium atom is incorporated into the formed hydrocarbons. The transformer industry measures gas content/composition of transformer oils as a diagnostic tool for the transformers` condition. The analytical approach (ASTM D3612-90) used for these measurements is vacuum extraction of all gases (H{sub 2}, N{sub 2}, O{sub 2}, CO, CO{sub 2}, etc.) followed by analysis of the evolved gas mixture. This extraction method will be adapted to remove dissolved gases (including tritium) from the SRS vacuum pump oil. It may be necessary to heat (60{degrees}C to 70{degrees}C) the oil during vacuum extraction to remove tritiated water. A method described in the procedures is a stripper column extraction, in which a carrier gas (argon) is used to remove dissolved gases from oil that is dispersed on high surface area beads. This method appears promising for scale-up as a treatment process, and a modified process is also being used as a dewatering technique by SD Myers, Inc. (a transformer consulting company) for transformers in the field by a mobile unit. Although some mercury may be removed during the vacuum extraction, the most common technique for removing mercury from oil is by using sulfur-impregnated activated carbon (SIAC). SIAC is currently being used by the petroleum industry to remove mercury from hydrocarbon mixtures, but the sorbent has not been previously tested on DOE vacuum oil waste. It is anticipated that a final process will be similar to technologies used by the petroleum industry and is comparable to ion exchange operations in large column-type reactors.

Klasson, E.T. [Oak Ridge National Lab., TN (United States)

1997-10-01T23:59:59.000Z

449

State waste discharge permit application: Hydrotest, maintenance and construction discharges. Revision 0  

SciTech Connect (OSTI)

On December 23, 1991, the US DOE< Richland Operation Office (RL) and the Washington State Department of Ecology (Ecology) agreed to adhere to the provisions of the Department of Ecology Consent Order No. DE91NM-177 (216 Consent Order) (Ecology and US DOE 1991). The 216 Consent Order list regulatory milestones for liquid effluent streams at the Hanford Site and requires compliance with the permitting requirements of Washington Administrative Code. Hanford Site liquid effluent streams discharging to the soil column have been categorized on the 216 Consent Order as follows: Phase I Streams; Phase II Streams; Miscellaneous Streams. Phase I and Phase II Streams were initially addressed in two report. Miscellaneous Streams are subject to the requirements of several milestones identified in the 216 Consent Order. This document constitutes the Categorical State Waste Discharge Permit application for hydrotest,maintenance and construction discharges throughout the Hanford Site. This categorical permit application form was prepared and approved by Ecology.

NONE

1995-11-01T23:59:59.000Z

450

Survey of mercury, cadmium and lead content of household batteries  

SciTech Connect (OSTI)

Highlights: A well selected sample of 146 batteries was analysed for its heavy metals content. A comparison was made between heavy metals contents in batteries in 2006 and 2011. No significant change after implementation of the new EU Batteries Directive. Severe differences in heavy metal contents were found in different battery-types. - Abstract: The objective of this work was to provide updated information on the development of the potential impact of heavy metal containing batteries on municipal waste and battery recycling processes following transposition of the new EU Batteries Directive 2006/66/EC. A representative sample of 146 different types of commercially available dry and button cells as well as lithium-ion accumulators for mobile phones were analysed for their mercury (Hg)-, cadmium (Cd)- and lead (Pb)-contents. The methods used for preparing the cells and analysing the heavy metals Hg, Cd, and Pb were either developed during a former study or newly developed. Several batteries contained higher mass fractions of mercury or cadmium than the EU limits. Only half of the batteries with mercury and/or lead fractions above the marking thresholds were labelled. Alkalinemanganese mono-cells and Li-ion accumulators, on average, contained the lowest heavy metal concentrations, while zinccarbon batteries, on average, contained the highest levels.

Recknagel, Sebastian, E-mail: sebastian.recknagel@bam.de [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willsttter-Strae 11, D-12489 Berlin (Germany); Radant, Hendrik [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willsttter-Strae 11, D-12489 Berlin (Germany); Kohlmeyer, Regina [German Federal Environment Agency (UBA), Section III 1.6 Extended Producer Responsibility, Wrlitzer Platz 1, D-06844 Dessau-Rolau (Germany)

2014-01-15T23:59:59.000Z

451

JV Task 96 - Phase 2 - Investigating the Importance of the Mercury-Selenium Interaction  

SciTech Connect (OSTI)

In order to improve the understanding of the mercury issue, it is vital to study mercury's effects on selenium physiology. While mercury present in the environment or food sources may pose health risks, the protective effects of selenium have not been adequately considered in establishing regulatory policy. Numerous studies report that vulnerability to mercury toxicity is inversely proportional to selenium status or level. However, selenium status has not been considered in the development of the reference dosage levels for mercury exposure. Experimental animals fed low-selenium diets are far more vulnerable to mercury toxicity than animals fed normal selenium, and animals fed selenium-rich diets are even more resistant. Selenium-dependent enzymes in brain and endocrine tissues can be impaired by excessive mercury exposure, apparently because mercury has an extremely high binding affinity for selenium. When selenium becomes bound to mercury, it is unable to participate in the metabolic cycling of selenoprotein synthesis. Because of mercury-dependent impairments of selenoprotein synthesis, various antioxidant and regulatory functions in brain biochemistry are compromised. This report details a 2-year multiclient-funded research program designed to examine the interactions between mercury and selenium in animal models. The studies explored the effects of dietary intakes of toxic amounts of methylmercury and the protective effects of the normal dietary range of selenium in counteracting mercury toxicity. This study finds that the amounts of selenium present in ocean fish are sufficient to protect against far larger quantities of methylmercury than those present in typical seafoods. Toxic effects of methylmercury exposure were not directly proportional to mercury concentrations in blood, brain, or any other tissues. Instead, mercury toxicity was proportional to molar ratios of mercury relative to selenium. In order to accurately assess risk associated with methylmercury or mercury exposures, mercury-selenium ratios appear to be far more accurate and effective in identifying risk and protecting human and environmental health. This study also finds that methylmercury toxicity can be effectively treated by dietary selenium, preventing the death and progressive disabilities that otherwise occur in methylmercury-treated subjects. Remarkably, the positive response to selenium therapy was essentially equivalent regardless of whether or not toxic amounts of methylmercury were still administered. The findings of the Physiologically Oriented Integration of Nutrients and Toxins (POINT) models of the effects of mercury and selenium developed in this project are consistent with the hypothesis that mercury toxicity arises because of mercury-dependent inhibition of selenium availability in brain and endocrine tissues. This appears to occur through synergistic effects of mercury-dependent inhibition of selenium transport to these tissues and selective sequestration of the selenium present in the tissues. Compromised transport of selenium to the brain and endocrine tissues would be particularly hazardous to the developing fetus because the rapidly growing tissues of the child have no selenium reserves. Therefore, maternal consumption of foods with high mercury-selenium ratios is hazardous. In summation, methylmercury exposure is unlikely to cause harm in populations that eat selenium-rich diets but may cause harm among populations that consume certain foods that have methylmercury present in excess of selenium.

Nicholas Ralston; Laura Raymond

2008-03-01T23:59:59.000Z

452

Identification and measurement of neutron-absorbing elements on Mercury's David J. Lawrence a,*, William C. Feldman b  

E-Print Network [OSTI]

Identification and measurement of neutron-absorbing elements on Mercury's surface David J. Lawrence be an important discriminator for testing whether Mercury's high bulk metal fraction stemmed from aerodynamic drag

Nittler, Larry R.

453

Mercury's magnetospheric magnetic field after the first two MESSENGER flybys Igor I. Alexeev a,*, Elena S. Belenkaya a  

E-Print Network [OSTI]

is offset from Mercury's center by 405 km in the north- ward direction. The dipole inclination to Mercury smaller than Earth's surface magnetic field (Ness et al., 1974). The higher solar wind pressure

Johnson, Catherine Louise

454

In situ measurements of speciated atmospheric mercury and the identification of source regions in the Mexico City Metropolitan Area  

E-Print Network [OSTI]

In order to expand the currently limited understanding of atmospheric mercury source-receptor relationships in the Mexico City Metropolitan Area, real time measurements of atmospheric mercury were made at a downtown urban ...

Rutter, A. P.

455

Demonstration of New Technologies Required for the Treatment of Mixed Waste Contaminated with {ge}260 ppm Mercury  

SciTech Connect (OSTI)

The Resource Conservation and Recovery Act (RCRA) defines several categories of mercury wastes, each of which has a defined technology or concentration-based treatment standard, or universal treatment standard (UTS). RCRA defines mercury hazardous wastes as any waste that has a TCLP value for mercury of 0.2 mg/L or greater. Three of these categories, all nonwastewaters, fall within the scope of this report on new technologies to treat mercury-contaminated wastes: wastes as elemental mercury; hazardous wastes with less than 260 mg/kg [parts per million (ppm)] mercury; and hazardous wastes with 260 ppm or more of mercury. While this report deals specifically with the last category--hazardous wastes with 260 ppm or more of mercury--the other two categories will be discussed briefly so that the full range of mercury treatment challenges can be understood. The treatment methods for these three categories are as follows: Waste as elemental mercury--RCRA identifies amalgamation (AMLGM) as the treatment standard for radioactive elemental mercury. However, radioactive mercury condensates from retorting (RMERC) processes also require amalgamation. In addition, incineration (IMERC) and RMERC processes that produce residues with >260 ppm of radioactive mercury contamination and that fail the RCRA toxicity characteristic leaching procedure (TCLP) limit for mercury (0.20 mg/L) require RMERC, followed by AMLGM of the condensate. Waste with <260 ppm mercury--No specific treatment method is specified for hazardous wastes containing <260 ppm. However, RCRA regulations require that such wastes (other than RMERC residues) that exceed a TCLP mercury concentration of 0.20 mg/L be treated by a suitable method to meet the TCLP limit for mercury of 0.025 mg/L. RMERC residues must meet the TCLP value of {ge}0.20 mg/L, or be stabilized and meet the {ge}0.025 mg/L limit. Waste with {ge}260 ppm mercury--For hazardous wastes with mercury contaminant concentrations {ge}260 ppm and RCRA-regulated organic contaminants (other than incinerator residues), incineration or retorting (IMERC or RMERC) is the treatment standard. For wastes with mercury contaminant concentrations {ge}260 ppm that are inorganic, including incinerator and retort residues, RMERC is the treatment standard. Mercury hazardous waste contaminated with {ge}260 ppm mercury is the primary focus of this report.

Morris, M.I.

2002-02-06T23:59:59.000Z

456

Glutathione enzyme and selenoprotein polymorphisms associate with mercury biomarker levels in Michigan dental professionals  

SciTech Connect (OSTI)

Mercury is a potent toxicant of concern to both the general public and occupationally exposed workers (e.g., dentists). Recent studies suggest that several genes mediating the toxicokinetics of mercury are polymorphic in humans and may influence inter-individual variability in mercury accumulation. This work hypothesizes that polymorphisms in key glutathione synthesizing enzyme, glutathione s-transferase, and selenoprotein genes underlie inter-individual differences in mercury body burden as assessed by analytical mercury measurement in urine and hair, biomarkers of elemental mercury and methylmercury, respectively. Urine and hair samples were collected from a population of dental professionals (n = 515), and total mercury content was measured. Average urine (1.06 {+-} 1.24 ug/L) and hair mercury levels (0.49 {+-} 0.63 ug/g) were similar to national U.S. population averages. Taqman assays were used to genotype DNA from buccal swab samples at 15 polymorphic sites in genes implicated in mercury metabolism. Linear regression modeling assessed the ability of polymorphisms to modify the relationship between mercury biomarker levels and exposure sources (e.g., amalgams, fish consumption). Five polymorphisms were significantly associated with urine mercury levels (GSTT1 deletion), hair mercury levels (GSTP1-105, GSTP1-114, GSS 5 Prime ), or both (SEPP1 3 Prime UTR). Overall, this study suggests that polymorphisms in selenoproteins and glutathione-related genes may influence elimination of mercury in the urine and hair or mercury retention following exposures to elemental mercury (via dental amalgams) and methylmercury (via fish consumption). -- Highlights: Black-Right-Pointing-Pointer We explore the influence of 15 polymorphisms on urine and hair Hg levels. Black-Right-Pointing-Pointer Urine and hair Hg levels in dental professionals were similar to the US population. Black-Right-Pointing-Pointer GSTT1 and SEPP1 polymorphisms associated with urine Hg levels. Black-Right-Pointing-Pointer Accumulation of Hg in hair following exposure from fish was modified by genotype. Black-Right-Pointing-Pointer GSTP1, GSS, and SEPP1 polymorphisms influenced Hg accumulation in hair.

Goodrich, Jaclyn M.; Wang, Yi [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Gillespie, Brenda [Department of Biostatistics, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Biostatistics, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Werner, Robert [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States) [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Department of Physical Medicine and Rehabilitation, University of Michigan, 325 E. Eisenhower Parkway Suite 100, Ann Arbor, MI 48108 (United States); Franzblau, Alfred [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States); Basu, Niladri, E-mail: niladri@umich.edu [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)] [Department of Environmental Health Sciences, University of Michigan School of Public Health, 1415 Washington Heights, Ann Arbor, MI 48109 (United States)

2011-12-15T23:59:59.000Z

457

The removal of mercury from solid mixed waste using chemical leaching processes  

SciTech Connect (OSTI)

The focus of this research was to evaluate chemical leaching as a technique to treat soils, sediments, and glass contaminated with either elemental mercury or a combination of several mercury species. Potassium iodide/iodine solutions were investigated as chemical leaching agents for contaminated soils and sediments. Clean, synthetic soil material and surrogate storm sewer sediments contaminated with mercury were treated with KI/I{sub 2} solutions. It was observed that these leaching solutions could reduce the mercury concentration in soil and sediments by 99.8%. Evaluation of selected posttreatment sediment samples revealed that leachable mercury levels in the treated solids exceeded RCRA requirements. The results of these studies suggest that KI/I{sub 2} leaching is a treatment process that can be used to remove large quantities of mercury from contaminated soils and sediments and may be the only treatment required if treatment goals are established on Hg residual concentrations in solid matrices. Fluorescent bulbs were used to simulate mercury contaminated glass mixed waste. To achieve mercury contamination levels similar to those found in larger bulbs such as those used in DOE facilities a small amount of Hg was added to the crushed bulbs. The most effective agents for leaching mercury from the crushed fluorescent bulbs were KI/I{sub 2}, NaOCl, and NaBr + acid. Radionuclide surrogates were added to both the EPA synthetic soil material and the crushed fluorescent bulbs to determine the fate of radionuclides following chemical leaching with the leaching agents determined to be the most promising. These experiments revealed that although over 98% of the dosed mercury solubilized and was found in the leaching solution, no Cerium was measured in the posttreatment leaching solution. This finding suggest that Uranium, for which Ce was used as a surrogate, would not solubilize during leaching of mercury contaminated soil or glass.

Gates, D.D.; Chao, K.K.; Cameron, P.A.

1995-07-01T23:59:59.000Z

458

Analysis of radiofrequency discharges in plasma  

DOE Patents [OSTI]

Separation of laser optogalvanic signals in plasma into two components: (1) an ionization rate change component, and (2) a photoacoustic mediated component. This separation of components may be performed even when the two components overlap in time, by measuring time-resolved laser optogalvanic signals in an rf discharge plasma as the rf frequency is varied near the electrical resonance peak of the plasma and associated driving/detecting circuits. A novel spectrometer may be constructed to make these measurements. Such a spectrometer would be useful in better understanding and controlling such processes as plasma etching and plasma deposition. 15 figs.

Kumar, D.; McGlynn, S.P.

1992-08-04T23:59:59.000Z

459

Process for combined control of mercury and nitric oxide.  

SciTech Connect (OSTI)

Continuing concern about the effects of mercury in the environment may lead to requirements for the control of mercury emissions from coal-fired power plants. If such controls are mandated, the use of existing flue-gas cleanup systems, such as wet scrubbers currently employed for flue-gas desulfurization, would be desirable, Such scrubbers have been shown to be effective for capturing oxidized forms of mercury, but cannot capture the very insoluble elemental mercury (Hg{sup 0}) that can form a significant fraction of the total emissions. At Argonne National Laboratory, we have proposed and tested a concept for enhancing removal of Hg{sup 0}, as well as nitric oxide, through introduction of an oxidizing agent into the flue gas upstream of a scrubber, which readily absorbs the soluble reaction products. Recently, we developed a new method for introducing the oxidizing agent into the flue-gas stream that dramatically improved reactant utilization. The oxidizing agent employed was NOXSORB{trademark}, which is a commercial product containing chloric acid and sodium chlorate. When a dilute solution of this agent was introduced into a gas stream containing Hg{sup 0} and other typical flue-gas species at 300 F, we found that about 100% of the mercury was removed from the gas phase and recovered in process liquids. At the same time, approximately 80% of the nitric oxide was removed. The effect of sulfur dioxide on this process was also investigated and the results showed that it slightly decreased the amount of Hg{sup 0} oxidized while appearing to increase the removal of nitric oxide from the gas phase. We are currently testing the effects of variations in NOXSORB{trademark} concentration, sulfur dioxide concentration, nitric oxide concentration, and reaction time (residence time). Preliminary economic projections based on the results to date indicate that the chemical cost for nitric oxide oxidation could be less than $5,000/ton removed, while for Hg{sup 0} oxidation it would be about $20,000/lb removed.

Livengood, C. D.; Mendelsohn, M. H.

1999-11-03T23:59:59.000Z

460

CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT  

SciTech Connect (OSTI)

Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according tohe Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB carbon can sorb Hg up to 19 wt% of the carbon mass, and (c) the spent carbon retained almost all (98 99.99%) of the Hg; but when even a small fraction of the total Hg dissolves, the spent carbon can fail the TCLP test when the spent carbon contains high Hg concentrations. Localized areas in a carbon bed that become heated through heat of adsorption, to temperatures where oxidation occurs, are referred to as bed hot spots. Carbon bed hot spots must be avoided in processes that treat radioactive and mixed waste. Key to carbon bed hot spot mitigation are (a) designing for sufficient gas velocity, for avoiding gas flow maldistribution, and for sufficient but not excessive bed depth, (b) monitoring and control of inlet gas flowrate, temperature, and composition, (c) monitoring and control of in-bed and bed outlet gas temperatures, and (d) most important, monitoring of bed outlet CO concentrations. An increase of CO levels in the off-gas downstream of the carbon bed to levels about 50-100 ppm higher than the inlet CO concentration indicate CO formation in the bed, caused by carbon bed hot spots. Corrective actions must be implemented quickly if bed hot spots are detected, using a graded approach and sequence starting with corrective actions that are simple, quick, cause the least impact to the process, and are easiest to recover from. Multiple high and high-high alarm levels should be used, with appropriate corrective actions for each level.

Nick Soelberg; Joe Enneking

2010-11-01T23:59:59.000Z

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461

Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA  

SciTech Connect (OSTI)

Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2003-05-01T23:59:59.000Z

462

Fate of Mercury in Synthetic Gypsum Used for Wallboard Production  

SciTech Connect (OSTI)

This report presents and discusses results from Task 5 of the study ''Fate of Mercury in Synthetic Gypsum Used for Wallboard Production,'' performed at a full-scale commercial wallboard plant. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. The FGD process is used to control the sulfur dioxide emissions which would result in acid rain if not controlled. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies developed for power plants involve the capture of mercury in FGD systems. The objective of this study is to determine whether any mercury is released into the atmosphere when the synthetic gypsum material is used as a feedstock for wallboard production. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope includes five discrete tasks, each conducted at various USG wallboard plants using synthetic gypsum from different FGD systems. The five tasks were to include (1) a baseline test, then variations representing differing power plant (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5, which was to evaluate gypsum produced from an alternate FGD reagent, could not be conducted as planned. Instead, Task 5 was conducted at conditions similar to a previous task, Task 3, although with gypsum from an alternate FGD system. In this project, process stacks in the wallboard plant have been sampled using the Ontario Hydro method. The stack locations sampled for each task include a dryer for the wet gypsum as it enters the plant and a gypsum calciner. The stack of the dryer for the wet wallboard product was also tested as part of this task, and was tested as part of Tasks 1 and 4. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. The Ontario Hydro results, process sample mercury concentration data, and process data were used to construct mercury mass balances across the wallboard plants. Task 5 was conducted at a wallboard plant processing synthetic gypsum from a power plant that fires Eastern bituminous coal. The power plant is equipped with a selective catalytic reduction (SCR) system for NOX emissions control, but the SCR was bypassed during the time period the gypsum tested was produced. The power plant has a single-loop, open spray tower, limestone reagent FGD system, with forced oxidation conducted in a reaction tank integral with the FGD absorber. The FGD system has gypsum fines blow down as part of the dewatering step. Gypsum fines blow down is believed to be an important variable that impacts the amount of mercury in the gypsum byproduct and possibly its stability during the wallboard process. The results of the Task 5 stack testing, as measured by the Ontario Hydro method, detected that an average of 51% of the incoming mercury in the FGD gypsum was emitted during wallboard production. These losses were distributed as 2% or less each across the wet gypsum dryer and product wallboard dryer, and about 50% across the gypsum calciner. Emissions were similar to what Task 3 results showed, on both a percentage and a mass basis, for gypsum produced by a power plant firing bituminous coal and also having gypsum fines blow down as part of the FGD dewatering scheme. As was seen in the Task 1 through 4 results, most of the mercury detected in the stack testing on the wet gypsum dryer and kettle calciner was in the form of elemental mercury. In the wallboard dryer kiln, a more signific

Jessica Marshall Sanderson

2006-06-01T23:59:59.000Z

463

Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that these data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the ninth in a series of topical reports, describes the results and analysis of mercury sampling performed on Unit 1 at Plant 7, a 566 MW unit burning a bituminous coal containing 3.6% sulfur. The unit is equipped with a SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions, respectively. Four sampling tests were performed in August 2004 during ozone season with the SCR operating; flue gas mercury speciation and concentrations were determined at the SCR inlet, SCR outlet, air heater outlet (ESP inlet), ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Three sampling tests were also performed in November 2004 during non-ozone season with the SCR bypassed; flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet). Process samples for material balances were collected during the flue gas measurements. The results show that, at the point where the flue gas enters the FGD, a greater percentage of the mercury was in the oxidized form when the SCR was operating compared to when the SCR was bypassed (97% vs 91%). This higher level of oxidation resulted in higher mercury removals in the FGD because the FGD removed 90-94% of the oxidized mercury in both cases. Total coal-to-stack mercury removal was 86% with the SCR operating, and 73% with the SCR bypassed. The average mercury mass balance closure was 81% during the ozone season tests and 87% during the non-ozone season tests.

J. A. Withum; S. C. Tseng; J. E. Locke

2006-01-31T23:59:59.000Z

464

Mercury's sodium exosphere: Magnetospheric ion recycling Service d'Aeronomie du CNRS/IPSL, Verrie`res-Le-Buisson, France  

E-Print Network [OSTI]

Mercury's sodium exosphere: Magnetospheric ion recycling F. Leblanc Service d'Ae´ronomie du CNRS December 2003. [1] A three-dimensional Monte Carlo model of Mercury's neutral sodium exosphere was used in the surface concentration of sodium along Mercury's motion around the Sun [Leblanc and Johnson, 2003]. Four

Johnson, Robert E.

465

Z .Spectrochimica Acta Part B 56 2001 419 430 The effects of oxygen on the detection of mercury using  

E-Print Network [OSTI]

Z .Spectrochimica Acta Part B 56 2001 419 430 The effects of oxygen on the detection of mercury; accepted 27 February 2001 Abstract A systematic study of the processes associated with mercury atomic emission in a laser-induced plasma and the interactions of mercury with oxygen species is presented

Hahn, David W.

466

Feather mercury concentrations and physiological condition of great egret and white ibis nestlings in the Florida Everglades  

E-Print Network [OSTI]

Feather mercury concentrations and physiological condition of great egret and white ibis nestlings 2008 Available online 13 February 2009 Mercury contamination in the Florida Everglades has reportedly leading to population-level effects. We assessed feather mercury levels in great egret (Ardea alba; n=91

Gawlik, Dale E.

467

The Mercury Project: A Feasibility Study for Internet Robots Ken Goldberg, Steve Gentner, Carl Sutter, and Jeff Wiegley  

E-Print Network [OSTI]

The Mercury Project: A Feasibility Study for Internet Robots Ken Goldberg, Steve Gentner, Carl-available interface that can make teleoperated resources accessible to a broad range of users. The Mercury Project into the sand to view the newly cleared region. To our knowledge, the Mercury Project was the first system

Goldberg, Ken

468

Managing mercury bioaccumula0on in fish: lessons learned from 20 years of monitoring in Oak Ridge, TN  

E-Print Network [OSTI]

2/7/13 1 Managing mercury bioaccumula0on in fish: lessons learned from 20 Poplar Creek White Oak Creek Outline · Mercury in the aqua0c environment · Mercury at Oak Ridge: · East Fork Poplar Creek vs White Oak Creek · Other

Gray, Matthew

469

2001 Mercury Computer Systems, Inc. UML 2.0 Redux for HPECUML 2.0 Redux for HPEC  

E-Print Network [OSTI]

© 2001 Mercury Computer Systems, Inc. UML 2.0 Redux for HPECUML 2.0 Redux for HPEC Dr. Jeffrey E. Smith Mercury Computer Systems, Inc. Manfred Koethe 88solutions Corp. High Performance Embedded Computing (HPEC) Conference September 25, 2003 #12;2© 2003 Mercury Computer Systems, Inc. UML Overview

Kepner, Jeremy

470

Accumulation of mercury in the tissues of the common octopus Octopus vulgaris (L.) in two localities on the Portuguese coast  

E-Print Network [OSTI]

Accumulation of mercury in the tissues of the common octopus Octopus vulgaris (L.) in two August 2004 Abstract Mercury concentrations were measured in tissues of 12 individuals of Octopus, gills, mantle, arms, and gonads). Correlations between mercury concentrations in different tissues were

Pierce, Graham