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1

Alkaline sorbent injection for mercury control  

DOE Patents (OSTI)

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2003-01-01T23:59:59.000Z

2

Alkaline sorbent injection for mercury control  

DOE Patents (OSTI)

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2002-01-01T23:59:59.000Z

3

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect

The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

Sharon Sjostrom

2005-12-30T23:59:59.000Z

4

Supported-sorbent injection. Final report  

SciTech Connect

A new retrofitable, wastefree acid-rain control concept was pilot-tested at Ohio Edison`s high-sulfur coal-fired R.E. Burger generating station at the 2-MWe level. During the project, moistened {open_quotes}supported{close_quotes} sorbents, made from a combination of lime and vermiculite or perlite, were injected into a humidified 6,500-acfm flue-gas slipstream. After the sorbents reacted with the sulfur dioxide in the flue gas, they were removed from ductwork with a cyclone and baghouse. The $1.0 million project was co-funded by Sorbent Technologies Corporation, the Ohio Edison Company, and the Ohio Coal Development Office. The project included a preliminary bench-scale testing phase, construction of the pilot plant, parametric studies, numerous series of recycle tests, and a long-term run. The project proceeded as anticipated and achieved its expected results. This duct injection technology successfully demonstrated SO{sub 2}-removal rates of 80 to 90% using reasonable stoichiometric injection ratios (2:1 Ca:S) and approach temperatures (20-25F). Under similar conditions, dry injection of hydrated lime alone typically only achieves 40 to 50% SO{sub 2} removal. During the testing, no difficulties were encountered with deposits in the ductwork or with particulate control, which have been problems in tests of other duct-injection schemes.

Nelson, S. Jr.

1997-07-01T23:59:59.000Z

5

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect

The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at DTE Energy's Monroe Power Plant, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program was to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000/lb mercury removed. The results from Monroe indicate that using DARCO{reg_sign} Hg would result in higher mercury removal (80%) at a sorbent cost of $18,000/lb mercury, or 70% lower than the benchmark. These results demonstrate that the goals established by DOE/NETL were exceeded during this test program. The increase in mercury removal over baseline conditions is defined for this program as a comparison in the outlet emissions measured using the Ontario Hydro method during the baseline and long-term test periods. The change in outlet emissions from baseline to long-term testing was 81%.

Sharon Sjostrom

2006-04-30T23:59:59.000Z

6

LIFAC sorbent injection desulfurization demonstration project  

SciTech Connect

In December 1990, the US Department of Energy selected 13 projects for funding under the Federal Clean Coal Technology Program (Round 3). One of the projects selected was the project sponsored by LIFAC North America, (LIFAC NA), titled LIFAC Sorbent Injection Desulfurization Demonstration Project.'' The host site for this $17 million, three-phase project is Richmond Power and Light's Whitewater Valley Unit No. 2 in Richmond, Indiana. The LIFAC technology uses upper-furnace limestone injection with patented humidification of the flue gas to remove 75--80% of the sulfur dioxide (SO{sub 2}) in the flue gas. In November 1990, after a ten (10) month negotiation period, LIFAC NA and the US DOE entered into a Cooperative Agreement for the design, construction, and demonstration of the LIFAC system. This report is the first Technical Progress Report covering the period from project execution through the end of December 1990. Due to the power plant's planned outage schedule, and the time needed for engineering, design and procurement of critical equipment, DOE and LIFAC NA agreed to execute the Design Phase of the project in August 1990, with DOE funding contingent upon final signing of the Cooperative Agreement.

Not Available

1991-01-01T23:59:59.000Z

7

NETL: Mercury Emissions Control Technologies - Sorbent Injection for Small  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas URS Group and their test team will evaluate sorbent injection for mercury control on sites with low-SCA ESPs, burning low sulfur Eastern bituminous coals. Full-scale tests will be performed at Plant Yates Units 1 and 2 to evaluate sorbent injection performance across a cold-side ESP/wet FGD and a cold-side ESP with a dual NH3/SO3 flue gas conditioning system, respectively. Short-term parametric tests on Units 1 and 2 will provide data on the effect of sorbent injection rate on mercury removal and ash/FGD byproduct composition. Tests on Unit 2 will also evaluate the effect of dual-flue gas conditioning on sorbent injection performance. Results from a one-month injection test on Unit 1 will provide insight to the long-term performance and variability of this process as well as any effects on plant operations. The goals of the long-term testing are to obtain sufficient operational data on removal efficiency over time, effects on the ESP and balance of plant equipment, and on injection equipment operation to prove process viability.

8

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect

ADA-ES, Inc., with support from DOE/NETL, EPRI, and industry partners, studied mercury control options at six coal-fired power plants. The overall objective of the this test program was to evaluate the capabilities of activated carbon injection at six plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, American Electric Power's Conesville Station Unit 6, and Labadie Power Plant Unit 2. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The financial goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000 per pound of mercury removed. Results from testing at Holcomb, Laramie, Meramec, Labadie, and Monroe indicate the DOE goal was successfully achieved. However, further improvements for plants with conditions similar to Conesville are recommended that would improve both mercury removal performance and economics.

Sharon Sjostrom

2008-06-30T23:59:59.000Z

9

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

Gary M. Blythe

2001-11-06T23:59:59.000Z

10

Field Demonstration of Enhanced Sorbent Injection for Mercury Control  

SciTech Connect

Alstom Power Inc. has conducted a DOE/NETL-sponsored program (under DOE Cooperative Agreement No. DE-FC26-04NT42306) to demonstrate Mer-Cure{trademark}, one of Alstom's mercury control technologies for coal-fired boilers. Mer-Cure{trademark} utilizes a small amount of Mer-Clean{trademark} sorbent that is injected into the flue gas stream for oxidation and adsorption of gaseous mercury. Mer-Clean{trademark} sorbents are carbon-based and prepared with chemical additives that promote oxidation and capture of mercury. Mer-Cure{trademark} is unique in that the sorbent is injected into an environment where the mercury capture kinetics is accelerated. This full-scale demonstration program was comprised of three seven-week long test campaigns at three host sites including PacifiCorp's 240-MW{sub e} Dave Johnston Unit No.3 burning a Powder River Basin (PRB) coal, Basin Electric's 220-MW{sub e} Leland Olds Unit No.1 burning a North Dakota lignite, and Reliant Energy's 170-MW{sub e} Portland Unit No.1 burning an Eastern bituminous coal. All three boilers are equipped with electrostatic precipitators. The goals for this Round 2 program, established by DOE/NETL under the original solicitation, were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the previous target of $60,000/lb mercury removed. The results for all three host sites indicated that Mer-Cure{trademark} technology could achieve mercury removal of 90%. The estimated mercury removal costs were 25-92% lower than the benchmark of $60,000/lb mercury removed. The estimated costs for control, at sorbent cost of $1.25 to $2.00/lb respectively, are as follows: (1) Dave Johnston Unit No.3--$2,650 to $4,328/lb Hg removed (92.8% less than $60k/lb); (2) Leland Olds Unit No.1--$8,680 to $13,860/lb Hg removed (76.7% less than $60k/lb); and (3) Portland Unit No.1--$28,540 to $45,065/lb Hg removed (24.9% less than $60k/lb). In summary, the results from demonstration testing at all three host sites show that the goals established by DOE/NETL were exceeded during this test program. Mercury removal performance4 of greater than 90% reduction was above the 50-70% reduction goal, and mercury removal cost of 25-92% lower than the benchmark was above the 25 to 50% cost reduction goal.

Shin Kang; Robert Schrecengost

2009-01-07T23:59:59.000Z

11

LIFAC Sorbent Injection Desulfurization Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

41 41 LIFAC Sorbent Injection Desulfurization Demonstration Project: A DOE Assessment January 2001 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 website: www.netl.doe.gov Disclaimer 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference

12

Direct sulfur recovery during sorbent regeneration. Final report  

SciTech Connect

The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

1993-08-01T23:59:59.000Z

13

Using high temperature baghouses to enhance desulfurization following economizer sorbent injection  

SciTech Connect

In order to explore the potential of using high temperature baghouses to enhance SO{sub 2} removal following upstream sorbent injection, an integrated two-stage reactor system has been built. It consists of an injection stage and a filtration stage. Distinct from one-stage fixed-bed reactors, sorbent particles in this system are initially converted under controlled injection conditions before entering the filtration reactor chamber. By the aid of the system, several unique features regarding the gas-solid reactions in the baghouse after economizer zone sorbent injection have been revealed. Results have shown that the appropriate usage of a high temperature baghouse may substantially enhance the performance of the process. The further SO{sub 2} removal in the baghouse is comprehensively affected by both the conditions in the injection zone and those in the baghouse.

Li, G.; Keener, T.C. [Univ. of Cincinnati, OH (United States). Dept. of Civil and Environmental Engineering

1995-12-31T23:59:59.000Z

14

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect

This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO[sub x] and SO[sub x] emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO[sub x] to molecular nitrogen (N[sub 2]) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO[sub x] emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO[sub x]. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO[sub 4], an injection temperature of about 1230[degrees]C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H[sub 2]0 added for humidification. The calcium sulfate or sulfite products are collected together with unreacted sorbent fly ash by the electrostatic precipitator. The specific goal of this project is to demonstrate NO[sub x] and SO[sub x] emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-11-16T23:59:59.000Z

15

Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorbent InjectIon for Small eSP Sorbent InjectIon for Small eSP mercury control In low Sulfur eaStern bItumInouS coal flue GaS Background Full-scale field testing has demonstrated the effectiveness of activated carbon injection (ACI) as a mercury-specific control technology for certain coal-fired power plants, depending on the plant's coal feedstock and existing air pollution control device configuration. In a typical configuration, powdered activated carbon (PAC) is injected downstream of the plant's air heater and upstream of the existing particulate control device - either an electrostatic precipitator (ESP) or a fabric filter (FF). The PAC adsorbs the mercury from the combustion flue gas and is subsequently captured along with the fly ash in the ESP or FF. ACI can have some negative side

16

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (sox) and oxides of nitrogen (NO[sub x]). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO[sub x] and SO[sub x] emissions. Gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO[sub x] to molecular nitrogen (N[sub 2]) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO[sub x] emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO[sub x]. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO[sub 4], an injection temperature of about 1230[degrees]C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H[sub 2]O added for humidification. The specific goal of this project is to demonstrate NO[sub x] and SO[sub x] emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-07-27T23:59:59.000Z

17

MODELING POWDERED SORBENT INJECTION IN COMBINATION WITHE FABRIC FILTER FOR THE CONTROL OF MERCURY EMISSIONS  

NLE Websites -- All DOE Office Websites (Extended Search)

POWDERED SORBENT INJECTION IN POWDERED SORBENT INJECTION IN COMBINATION WITH FABRIC FILTER FOR THE CONTROL OF MERCURY EMISSIONS Joseph R. V. Flora Department of Civil and Environmental Engineering University of South Carolina, Columbia, SC 29208 Richard A. Hargis, William J. O'Dowd, Henry W. Pennline National Energy Technology Laboratory, U.S. Department of Energy P.O. Box, 10940, Pittsburgh, PA 15236 Radisav D. Vidic * Department of Civil and Environmental Engineering University of Pittsburgh, Pittsburgh, PA 15261 ABSTRACT A two-stage mathematical model for mercury removal using powdered activated carbon injection upstream of a baghouse filter was developed, with the first stage accounting for removal in the ductwork and the second stage accounting for additional removal due to the

18

Premixed direct injection disk  

DOE Patents (OSTI)

A fuel/air mixing disk for use in a fuel/air mixing combustor assembly is provided. The disk includes a first face, a second face, and at least one fuel plenum disposed therebetween. A plurality of fuel/air mixing tubes extend through the pre-mixing disk, each mixing tube including an outer tube wall extending axially along a tube axis and in fluid communication with the at least one fuel plenum. At least a portion of the plurality of fuel/air mixing tubes further includes at least one fuel injection hole have a fuel injection hole diameter extending through said outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

York, William David; Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin; Zuo, Baifang; Uhm, Jong Ho

2013-04-23T23:59:59.000Z

19

Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

None

1998-09-01T23:59:59.000Z

20

Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

None

1998-06-01T23:59:59.000Z

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21

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO[sub x]) and sulfur (SO[sub x]) on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO[sub x] and 50 percent in SO[sub x] emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO[sub x] is converted to N[sub 2]. The combustion process is completed by overfire air addition. So[sub x] emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO[sub x] as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting; (2) Construction and Startup; and, (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel.

Not Available

1992-10-15T23:59:59.000Z

22

Advanced in-duct sorbent injection for SO{sub 2} control. Topical report number 3, Subtask 2.3: Sorbent optimization  

SciTech Connect

The objective of this research project is to develop second-generation duct injection technology as a cost-effective compliance option for the 1990 Clean Air Act Amendments. Specific process performance goals are to achieve 90% SO{sub 2} removal and 60% sorbent utilization efficiency. Research is focused on the Advanced Coolside process, which has shown the potential of achieving these targets. The objective of Subtask 2.3, Sorbent Optimization, was to explore means of improving performance and economics of the Advanced Coolside process through optimizing the sorbent system. Pilot plant tests of commercial and specially prepared hydrated limes showed that the process is relatively insensitive to sorbent source. This can be an important economic advantage, allowing the use of the lowest cost sorbent available at a site. A pilot plant hydration study conducted in cooperation with Dravo Lime Company further indicated the relative insensitivity of process performance to lime source and to lime physical properties. Pilot plant tests indicated that the use of very small amounts of additives in the Advanced Coolside process can improve performance under some circumstances; however, additives are not necessary to exceed process performance targets.

Rosenhoover, W.A.; Maskew, J.T.; Withum, J.A.; Stouffer, M.R.

1994-11-01T23:59:59.000Z

23

Premixed direct injection nozzle  

DOE Patents (OSTI)

An injection nozzle having a main body portion with an outer peripheral wall is disclosed. The nozzle includes a plurality of fuel/air mixing tubes disposed within the main body portion and a fuel flow passage fluidly connected to the plurality of fuel/air mixing tubes. Fuel and air are partially premixed inside the plurality of the tubes. A second body portion, having an outer peripheral wall extending between a first end and an opposite second end, is connected to the main body portion. The partially premixed fuel and air mixture from the first body portion gets further mixed inside the second body portion. The second body portion converges from the first end toward said second end. The second body portion also includes cooling passages that extend along all the walls around the second body to provide thermal damage resistance for occasional flame flash back into the second body.

Zuo, Baifang (Simpsonville, SC); Johnson, Thomas Edward (Greer, SC); Lacy, Benjamin Paul (Greer, SC); Ziminsky, Willy Steve (Simpsonville, SC)

2011-02-15T23:59:59.000Z

24

Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control  

SciTech Connect

Public Service Company of Colorado and ADA Technologies, Inc. have performed a study of the injection of activated carbon for the removal of vapor-phase mercury from coal-fired flue gas streams. The project was completed under contract to the US Department of Energy's National Energy Technology Laboratory, with contributions from EPRI and Public Service Company. The prime contractor for the project was Public Service Company, with ADA Technologies as the major subcontractor providing technical support to all aspects of the project. The research and development effort was conducted in two phases. In Phase I a pilot facility was fabricated and tests were performed using dry carbon-based sorbent injection for mercury control on a coal-fired flue gas slipstream extracted from an operating power plant. Phase II was designed to move carbon injection technology towards commercial application on coal-fired power plants by addressing key reliability and operability concerns. Phase II field work included further development work with the Phase I pilot and mercury measurements on several of PSCo's coal-fired generating units. In addition, tests were run on collected sorbent plus fly ash to evaluate the impact of the activated carbon sorbent on the disposal of fly ash. An economic analysis was performed where pilot plant test data was used to develop a model to predict estimated costs of mercury removal from plants burning western coals. Testing in the pilot plant was undertaken to quantify the effects of plant configuration, flue gas temperature, and activated carbon injection rate on mercury removal. All three variables were found to significantly impact the mercury removal efficiency in the pilot. The trends were clear: mercury removal rates increased with decreasing flue gas temperature and with increasing carbon injection rates. Mercury removal was much more efficient with reverse-gas and pulse-jet baghouse configurations than with an ESP as the particulate control device. The native fly ash of the host unit provided significant mercury removal capacity, so that the activated carbon sorbent served as an incremental mercury removal mechanism. Tests run to characterize the waste product, a combination of fly ash and activated carbon on which mercury was present, showed that mercury and other RCRA metals of interest were all below Toxic Characteristic Leaching Procedure (TCLP) regulatory limits in the leachate. The presence of activated carbon in the fly ash was shown to have an effect on the use of fly ash as an additive in the manufacture of concrete, which could limit the salability of fly ash from a plant where activated carbon was used for mercury control.

Jim Butz; Terry Hunt

2005-11-01T23:59:59.000Z

25

Staged direct injection diesel engine  

DOE Patents (OSTI)

A diesel engine having staged injection for using lower cetane number fuels than No. 2 diesel fuel. The engine includes a main fuel injector and a pilot fuel injector. Pilot and main fuel may be the same fuel. The pilot injector injects from five to fifteen percent of the total fuel at timings from 20.degree. to 180.degree. BTDC depending upon the quantity of pilot fuel injected, the fuel cetane number and speed and load. The pilot fuel injector is directed toward the centerline of the diesel cylinder and at an angle toward the top of the piston, avoiding the walls of the cylinder. Stratification of the early injected pilot fuel is needed to reduce the fuel-air mixing rate, prevent loss of pilot fuel to quench zones, and keep the fuel-air mixture from becoming too fuel lean to become effective. In one embodiment, the pilot fuel injector includes a single hole for injection of the fuel and is directed at approximately 48.degree. below the head of the cylinder.

Baker, Quentin A. (San Antonio, TX)

1985-01-01T23:59:59.000Z

26

Enhancing the Use of Coals by Gas Reburning-Sorbent Injection  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 Enhancing the Use of Coals by Gas Reburning-Sorbent Injection A DOE Assessment January 2001 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 website: www.netl.doe.gov Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial

27

INVESTIGATION AND DEMONSTRATION OF DRY CARBON-BASED SORBENT INJECTION FOR MERCURY CONTROL  

SciTech Connect

This quarterly report describes the activities that have taken place during the first full quarter of the Phase II project ''Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control''. Modifications were completed and sampling began at the 600 acfm pilot-scale particulate control module (PCM) located at the Comanche Station in Pueblo, CO. The PCM was configured as an electrostatic precipitator for these tests. A Perkin-Elmer flue gas mercury analyzer was installed on-site and operated. Initial test results using both manual sampling methodology and the mercury analyzer are presented herein. Preparations were made during this period for full-scale mercury testing of several PSCo units. A site visit was made to Arapahoe and Cherokee Generating Stations to determine sample locations and to develop a test plan.

Terry Hunt; Mark Fox; Lillian Stan; Sheila Haythornthwaite; Justin Smith; Jason Ruhl

1998-10-01T23:59:59.000Z

28

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (SO{sub x}) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Because of cost growth and lack of available funding, no further work has been done after Phase 1 at site B; the wall fired unit.

Not Available

1992-02-07T23:59:59.000Z

29

carbon sequestration via direct injection  

NLE Websites -- All DOE Office Websites (Extended Search)

SEQUESTRATION VIA DIRECT INJECTION SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams INTRODUCTION The build-up of carbon dioxide (CO 2 ) and other greenhouse gases in the Earth's atmosphere has caused concern about possible global climate change. As a result, international negotiations have produced the Framework Convention on Climate Change (FCCC), completed during the 1992 Earth Summit in Rio de Janeiro. The treaty, which the United States has ratified, calls for the "stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system." The primary greenhouse gas is CO 2 , which is estimated to contribute to over two-thirds of any climate change. The primary source of CO

30

Field evaluation of natural gas and dry sorbent injection for MWC emissions control  

SciTech Connect

The Institute of Gas Technology (IGT), in cooperation with the Olmsted Waste-to-Energy Facility (OWEF) and with subcontracted engineering services from the Energy and Environmental Research Corporation (EER), has completed the detailed engineering and preparation of construction specifications for an Emissions Reduction Testing System (ERTS). The ERTS has been designed for retrofit to one of two 100-ton/day municipal waste combustors at the OWEF, located in Rochester, Minnesota. The purpose of the retrofit is to conduct a field evaluation of a combined natural gas and sorbent injection process (IGT`s METHANE de-TOX{sup SM}, IGT Patent No. 5,105,747) for reducing the emissions of oxides of nitrogen (NO{sub x}), hydrochloric acid (HCI), oxides of sulfur (SO{sub x}), carbon monoxide (CO), total hydrocarbons (THC), and chlorinated hydrocarbons (dioxin/furans). In addition, the design includes modifications for the control of heavy metals (HM). Development of the process should allow the waste-to-energy industry to meet the Federal New Source Performance Standards for these pollutants at significantly lower costs when compared to existing technology of Thermal deNO{sub x} combined with spray dryer scrubber/fabric filters. Additionally, the process should reduce boiler corrosion and increase both the thermal and power production efficiency of the facility.

Wohadlo, S.; Abbasi, H.; Cygan, D. [Institute of Gas Technology, Chicago, IL (United States)] Institute of Gas Technology, Chicago, IL (United States)

1993-10-01T23:59:59.000Z

31

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 20, July 1--September 30, 1992  

SciTech Connect

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}) on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. So{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting; (2) Construction and Startup; and, (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel.

Not Available

1992-10-15T23:59:59.000Z

32

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

in Gasoline Turbocharged Direct Injection (GTDI) engine technology in the near term as a cost effective, high volume, fuel economy solution, marketed globally as EcoBoost...

33

Enhancing the use of coals by gas reburning-sorbent injection. Environmental monitoring quarterly report No. 9, July 1--September 30, 1992  

SciTech Connect

This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO{sub 4}, an injection temperature of about 1230{degrees}C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H{sub 2}0 added for humidification. The calcium sulfate or sulfite products are collected together with unreacted sorbent fly ash by the electrostatic precipitator. The specific goal of this project is to demonstrate NO{sub x} and SO{sub x} emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-11-16T23:59:59.000Z

34

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report, January 1--March 31, 1996  

SciTech Connect

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel. Phase I of the project commenced on June 5, 1987. Phases I, II and III for the Illinois Power Project have been completed; Phases I and II for the CWLP project have been completed; Phase III is in progress. All site activities have been completed with the exception of restoration at CWLP.

NONE

1996-04-15T23:59:59.000Z

35

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 33, October 1--December 31, 1995  

SciTech Connect

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub 2}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, shed through the formation of an industry, and (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel. Phase 1 of the project commenced on June 5, 1987. Phases 1, 2 and 3 for the Illinois Power Project have been completed; Phases 1 and 2 for the CWLP project have been completed; Phase 3 is in progress. All site activities have been completed with the exception of restoration at CWLP.

NONE

1996-01-15T23:59:59.000Z

36

Investigation of Direct Injection Vehicle Particulate Matter...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emissions This study focuses primarily on particulate matter mass analysis of a gasoline direct injection engine in a test cell with a chassis dynamometer. p-10gibbs.pdf...

37

Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report  

SciTech Connect

A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

NONE

1996-03-01T23:59:59.000Z

38

Enhancing the use of coals by gas reburning-sorbent injection. Environmental monitoring quarterly report No. 8, April 1--June 30, 1992  

SciTech Connect

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (sox) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions. Gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO{sub 4}, an injection temperature of about 1230{degrees}C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H{sub 2}O added for humidification. The specific goal of this project is to demonstrate NO{sub x} and SO{sub x} emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-07-27T23:59:59.000Z

39

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

40

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 6, October 1--December 31, 1991  

SciTech Connect

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (SO{sub x}) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Because of cost growth and lack of available funding, no further work has been done after Phase 1 at site B; the wall fired unit.

Not Available

1992-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

European Lean Gasoline Direct Injection Vehicle Benchmark  

SciTech Connect

Lean Gasoline Direct Injection (LGDI) combustion is a promising technical path for achieving significant improvements in fuel efficiency while meeting future emissions requirements. Though Stoichiometric Gasoline Direct Injection (SGDI) technology is commercially available in a few vehicles on the American market, LGDI vehicles are not, but can be found in Europe. Oak Ridge National Laboratory (ORNL) obtained a European BMW 1-series fitted with a 2.0l LGDI engine. The vehicle was instrumented and commissioned on a chassis dynamometer. The engine and after-treatment performance and emissions were characterized over US drive cycles (Federal Test Procedure (FTP), the Highway Fuel Economy Test (HFET), and US06 Supplemental Federal Test Procedure (US06)) and steady state mappings. The vehicle micro hybrid features (engine stop-start and intelligent alternator) were benchmarked as well during the course of that study. The data was analyzed to quantify the benefits and drawbacks of the lean gasoline direct injection and micro hybrid technologies from a fuel economy and emissions perspectives with respect to the US market. Additionally that data will be formatted to develop, substantiate, and exercise vehicle simulations with conventional and advanced powertrains.

Chambon, Paul H [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Edwards, Kevin Dean [ORNL] [ORNL; Norman, Kevin M [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

2011-01-01T23:59:59.000Z

42

Enhancing the use of coals by Gas Reburning: Sorbent injection. [Quarterly report], July 28--October 1, 1993  

SciTech Connect

Energy and Environmental Research Corporation (EER) has completed demonstrations of Gas Reburning-Sorbent Injection (GR-SI) at two field sites. The discussions which follow pertain to measurements taken from the demonstration at City Water, Light and Power`s (CWLP) Lakeside Station Unit 7 in Springfield, Illinois. Environmental monitoring was conducted for two purposes, to satisfy the requirements of operating permits granted by the Illinois Environmental Protection Agency (IEPA) and to verify environmental acceptability of the GR-SI process. The GR-SI demonstration program at Lakeside Unit 7 was performed in three phases. Phase I -- Design and Permitting, entailed characterization of the host boiler, then finalization of process and engineering, design of the GR-SI system. Phase I was initiated in June 1987 and completed in March 1989. Phase II -- Construction and Startup, was initiated upon completion of design tasks and was completed in February 1993. Phase III -- Operation, Data Collection, Reporting and Disposition, was conducted from July 1993 to June 1994. In Phase III, the GR-SI system performance was evaluated initially through optimization tests, which are short-term tests in which specific operating parameters are varied to determine their impact on emissions and boiler performance. The optimization testing included GR only tests, SI only tests, and GR-SI tests. Results from these tests, carried out from July 28 to October 1, 1993, are presented in this report. Following Optimization testing, long-term GR-SI operation was initiated to demonstrate the combined technology over an extended period with the unit under dispatch load control. Long-term GR-SI testing was conducted from October 4, 1993 to June 3, 1994. The long-term environmental monitoring data are presented in a separate report.

NONE

1995-02-01T23:59:59.000Z

43

Direct tuyere injection of oxygen for enhanced coal combustion  

SciTech Connect

Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

1996-12-31T23:59:59.000Z

44

Gasoline direct injection: Actual trends and future strategies for injection and combustion systems  

SciTech Connect

Recent developments have raised increased interest on the concept of gasoline direct injection as the most promising future strategy for fuel economy improvement of SI engines. The general requirements for mixture preparation and combustion systems in a GDI engine are presented in view of known and actual systems regarding fuel economy and emission potential. The characteristics of the actually favored injection systems are discussed and guidelines for the development of appropriate combustion systems are derived. The differences between such mixture preparation strategies as air distributed fuel and fuel wall impingement are discussed, leading to the alternative approach to the problem of mixture preparation with the fully air distributing concept of direct mixture injection.

Fraidl, G.K.; Piock, W.F.; Wirth, M.

1996-09-01T23:59:59.000Z

45

New, high-capacity, calcium-based sorbents: Calcium silicate sorbents. Final report  

SciTech Connect

A search is being carried out for new calcium-based SO{sub 2} sorbents for induct injection. More specifically, a search is being carried out for induct injection calcium silicate sorbents that are highly cost effective. The objectives of the past year were to study the sorption of SO{sub 2} by representative calcium silicates, to study the composition of the Ca(OH){sub 2}-fly ash sorbent, and to install a humidity sensor in the sorption system.

Kenney, M.E.; Chiang, Ray-Kuang

1993-09-30T23:59:59.000Z

46

Engines - Spark Ignition Engines - Direct Injection - Omnivorous Engine  

NLE Websites -- All DOE Office Websites (Extended Search)

Direct Injection, Spark-Ignited Engines Direct Injection, Spark-Ignited Engines Omnivorous Engine Omnivorous Engine Setup Omnivorous Engine Setup New engine technology has made possible engines that will operate on a wide variety of fuel inputs, from gasoline to naptha to ethanol to methanol, without driver intervention. Although flexible fuel vehicles have been produced in the millions, their engines have always been optimized for gasoline operation while accepting significant performance and efficiency degradations when using the alternative fuel. This project seeks to combine in-cylinder measurement technology, and advanced controls to optimize spark timing, the quantity and timing of injected fuel, to produce an "omnivorous engine"--one that will be able to run on any liquid spark ignition fuel with optimal efficiency and low

47

Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 3, April 1, 1995--June 30, 1995  

SciTech Connect

The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

Wendt, J.O.L.

1995-09-06T23:59:59.000Z

48

Sorbents for the oxidation and removal of mercury  

DOE Patents (OSTI)

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

2008-10-14T23:59:59.000Z

49

Sorbents for the oxidation and removal of mercury  

DOE Patents (OSTI)

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

2014-09-02T23:59:59.000Z

50

Calibraton of a Directly Injected Natural Gas HD Engine for Class...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Calibraton of a Directly Injected Natural Gas HD Engine for Class 8 Truck Applications Calibraton of a Directly Injected Natural Gas HD Engine for Class 8 Truck Applications This...

51

Fact #720: March 26, 2012 Eleven Percent of New Light Trucks Sold have Gasoline Direct Injection  

Energy.gov (U.S. Department of Energy (DOE))

Gasoline direct fuel injection (GDI) allows fuel to be injected directly into the cylinder so the timing and shape of the fuel mist can be controlled more precisely. The improved combustion and...

52

Direct Injection Compression Ignition Diesel Automotive Technology Education GATE Program  

SciTech Connect

The underlying goal of this prqject was to provide multi-disciplinary engineering training for graduate students in the area of internal combustion engines, specifically in direct injection compression ignition engines. The program was designed to educate highly qualified engineers and scientists that will seek to overcome teclmological barriers preventing the development and production of cost-effective high-efficiency vehicles for the U.S. market. Fu1iher, these highly qualified engineers and scientists will foster an educational process to train a future workforce of automotive engineering professionals who are knowledgeable about and have experience in developing and commercializing critical advanced automotive teclmologies. Eight objectives were defmed to accomplish this goal: 1. Develop an interdisciplinary internal co1nbustion engine curriculum emphasizing direct injected combustion ignited diesel engines. 2. Encourage and promote interdisciplinary interaction of the faculty. 3. Offer a Ph.D. degree in internal combustion engines based upon an interdisciplinary cuniculum. 4. Promote strong interaction with indusuy, develop a sense of responsibility with industry and pursue a self sustaining program. 5. Establish collaborative arrangements and network universities active in internal combustion engine study. 6. Further Enhance a First Class educational facility. 7. Establish 'off-campus' M.S. and Ph.D. engine programs of study at various indusuial sites. 8. Extend and Enhance the Graduate Experience.

Carl L. Anderson

2006-09-25T23:59:59.000Z

53

Iron beam acceleration using direct plasma injection scheme  

SciTech Connect

A new set of vanes of radio frequency quadrupole (RFQ) accelerator was commissioned using highly charged iron beam. To supply high intensity heavy ion beams to the RFQ, direct plasma injection scheme (DPIS) with a confinement solenoid was adopted. One of the difficulties to utilize the combination of DPIS and a solenoid field is a complexity of electro magnetic field at the beam extraction region, since biasing high static electric field for ion extraction, RFQ focusing field, and the solenoid magnetic field fill the same space simultaneously. To mitigate the complexity, a newly designed magnetic field clamps were used. The intense iron beam was observed with bunched structure and the total accelerated current reached 2.5 nC.

Okamura, M., E-mail: okamura@bnl.gov [Brookhaven National Laboratory, Upton, New York 11973 (United States); RIKEN-BNL Research Center, Upton, New York 11973 (United States); Kanesue, T. [Brookhaven National Laboratory, Upton, New York 11973 (United States)] [Brookhaven National Laboratory, Upton, New York 11973 (United States); Yamamoto, T. [Waseda University, Shinjuku, Tokyo 169-8555 (Japan)] [Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Fuwa, Y. [Kyoto University, Uji, Kyoto 611-0011 (Japan) [Kyoto University, Uji, Kyoto 611-0011 (Japan); RIKEN, Wako, Saitama 351-0198 (Japan)

2014-02-15T23:59:59.000Z

54

Multiple Injection and Boosting Benefits for Improved Fuel Consumption on a Spray Guided Direct Injection Gasoline Engine  

Science Journals Connector (OSTI)

The combination of turbocharging and direct injection offers a significant potential for SI engines to improve fuel consumption, specific power output, raw emissions and ... shows the latest results of the T-SGDI...

Jason King; Oliver Böcker

2013-01-01T23:59:59.000Z

55

Effect of stratified water injection on exhaust gases and fuel consumption of a direct injection diesel engine  

Science Journals Connector (OSTI)

The direct injection Diesel engine with its specific fuel consumption of about 200 g/kWh is one of the most efficient thermal engines. However in case of relatively low CH...x...concentration in the exhaust gas t...

Rainer Pauls; Christof Simon

2004-01-01T23:59:59.000Z

56

3-Cylinder Turbocharged Gasoline Direct Injection: A High Value Solution for Euro VI Emissions  

Energy.gov (U.S. Department of Energy (DOE))

3-cylindery gasoline direct injection engines offer similar value in CO2 reduction capability (Euros/% CO2 reduction) at a significantly lower on-cost.

57

Premixed direct injection nozzle for highly reactive fuels  

DOE Patents (OSTI)

A fuel/air mixing tube for use in a fuel/air mixing tube bundle is provided. The fuel/air mixing tube includes an outer tube wall extending axially along a tube axis between an inlet end and an exit end, the outer tube wall having a thickness extending between an inner tube surface having a inner diameter and an outer tube surface having an outer tube diameter. The tube further includes at least one fuel injection hole having a fuel injection hole diameter extending through the outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin Paul; York, William David; Uhm, Jong Ho; Zuo, Baifang

2013-09-24T23:59:59.000Z

58

Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle  

DOE Patents (OSTI)

A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

2013-12-17T23:59:59.000Z

59

Investigation of Cluster-Nozzle Concepts for Direct Injection Diesel Engines  

E-Print Network (OSTI)

Investigation of Cluster-Nozzle Concepts for Direct Injection Diesel Engines Von der Fakultät für Investigation of Cluster-Nozzle Concepts for Direct Injection Diesel Engines WICHTIG: D 82 überprüfen !!! #12" in Zusammenarbeit mit General Motors R&D and Strategic Planning, Warren, MI, USA durchgeführt. Ein Teil der Arbeit

Peters, Norbert

60

New high-capacity, calcium-based sorbents, calcium silicate sorbents. Final report  

SciTech Connect

A search is being carried out for new calcium-based SO{sub 2} sorbents for induct injection. More specifically, a search is being carried out for induct injection calcium silicate sorbents that are highly cost effective. The current year objectives include the study of sorbents made by hydrating ordinary or Type I portland cement or portland cement clinker (a cement intermediate) under carefully selected conditions. Results of this study show that an excellent portland cement sorbent can be prepared by milling cement at 120{degrees}C at 600 rpm for 15 minutes with MgO-stabilized ZrO{sub 2} beads. They also show that clinker, which is cheaper than cement can be used interchangeably with cement as a starting material. Further, it is clear that while a high surface area may be a desirable property of a good sorbent, it is not a requisite property. Among the hydration reaction variables, milling time is highly important, reaction temperature is important and stirring rate and silicate-to-H{sub 2}O ratio are moderately important. The components of hydrated cement sorbent are various combinations of C-S-H, calcium silicate hydrate:Ca(OH){sub 2};AFm. a phase in hydrated cement.

Kenney, M.E.

1996-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Direct injection tunnel spectroscopy of a p-n junction Edward M. Likovich,1  

E-Print Network (OSTI)

Direct injection tunnel spectroscopy of a p-n junction Edward M. Likovich,1 Kasey J. Russell,1,a tunnel injection of electrons. In contrast to the metal-base transistor design of conventional ballistic the semiconductor before they scatter and thermal- ize to the chemical potential of the base layer. For systems

Russell, Kasey

62

NETL: Mercury Emissions Control Technologies - Evaluation of Sorbent  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Sorbent Injection for Mercury Control Evaluation of Sorbent Injection for Mercury Control ADA Environmental Solutions will evaluate injection of activated carbon and other sorbents to remove mercury for a variety of coal and air pollution control equipment configurations. The scope of work is for 36 months and intended to gather operating data that will document actual performance levels and accurate cost information to assess the costs of controlling mercury from coal fired utilities. Testing will be conducted at four different host sites that represent a significant percentage of unit configurations. The subsequent cost analyses will include capital costs, by-product utilization issues, sorbent usage, any necessary enhancements, such as SO3 control or flue gas conditioning, balance of plant, manpower requirements and waste issues. The host sites are Sunflower Electric's Holcomb Station, Ontario Power Generation's Nanticoke Station, AmerenUE's Meramec Station and American Electric Power's (AEP) Conesville Station.

63

Desulfurization sorbent regeneration  

DOE Patents (OSTI)

A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

Jalan, V.M.; Frost, D.G.

1982-07-07T23:59:59.000Z

64

A Detailed Multi-Zone Thermodynamic Simulation For Direct-Injection Diesel Engine Combustion  

E-Print Network (OSTI)

A detailed multi-zone thermodynamic simulation has been developed for the direct-injection (DI) diesel engine combustion process. For the purpose of predicting heterogeneous type combustion systems, the model explores the formation of pre...

Xue, Xingyu 1985-

2012-11-15T23:59:59.000Z

65

Numerical modeling of combustion processes and pollutant formations in direct-injection diesel engines  

Science Journals Connector (OSTI)

The Representative Interactive Flamelet (RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection...X formation including thermal NO path, pro...

Seong-Ku Kim; Joon Kyu Lee; Yong-Mo Kim; Jae-Hyun Ahn

2002-07-01T23:59:59.000Z

66

Combustion and emissions of a direct injection gasoline engine using biofuels.  

E-Print Network (OSTI)

??Impact of biofuel (2-methlyfuran, 2,5-dimethylfuran and ethanol) on the performance of a gasoline direct injection engine has been investigated. MF demonstrates better knock resistance properties… (more)

Wang, Chongming

2014-01-01T23:59:59.000Z

67

New high-capacity, calcium-based sorbents, calcium silicate sorbents. Final report, 1993--August 31, 1994  

SciTech Connect

A search is being carried out for new calcium-based S0{sub 2} sorbents for induct injection. More specifically, a search is being carried out for induct injection calcium silicate sorbents that are highly cost effective. The objectives for the current year include the study of sorbents made from Ca(OH){sub 2}, from mixtures of Ca(OH){sub 2} and SiO{sub 2}, and from portland cement. They also include the study of sorbents made from model compounds. During this year, sorbents prepared from Ca(OH){sub 2} and from mixtures of Ca(OH){sub 2} and fumed SiO{sub 2} were investigated. The results show that very good SiO{sub 2}-modified Ca(OH){sub 2} sorbents in which the Si-to-Ca reactant ratio is low can be prepared from Ca(OH){sub 2} and fumed SiO{sub 2}. Sorbents prepared from Ca(OH){sub 2} and natural SiO{sub 2} or natural SiO{sub 2} sources were also studied. The results obtained show that very good SiO{sub 2}-modified Ca(OH){sub 2} sorbents and calcium silicate hydrate sorbents, C-S-H sorbents, can be prepared from Ca(OH){sub 2} and diatomite, pumice or perlite, minerals that are readily available. In addition. sorbents prepared from Ca{sub 3}SiO{sub 5} and {beta}-Ca{sub 2}SiO{sub 4} and from mixtures of these compounds and SiO{sub 2} were studied. The results secured demonstrate that very good C-S-H rich sorbents can be prepared from these compounds and from mixtures of them with SiO{sub 2}. They also provide information useful for interpreting the cement sorbent results. Sorbents prepared from cement and from mixtures of cement and natural SiO{sub 2} or SiO{sub 2} sources were investigated as well. The results secured show that cement and mixtures of it with diatomite, pumice or perlite rapidly yield excellent sorbents with the proper reaction conditions.

Kenney, M.C.; Chiang, R.K.; Fillgrove, K.L. [Case Western Reserve Univ., Cleveland, OH (United States)

1995-02-01T23:59:59.000Z

68

Quantitative in-cylinder NO-LIF imaging in a realistic gasoline engine with spray-guided direct injection  

E-Print Network (OSTI)

Quantitative in-cylinder NO-LIF imaging in a realistic gasoline engine with spray-guided direct of engines with gasoline direct injection. Exhaust gas aftertreatment requires storage catalysts fractions in a gasoline engine with spray-guided direct injection using laser-induced fluorescence (LIF

Lee, Tonghun

69

2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection  

E-Print Network (OSTI)

2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection Engines Using In (FFVs) are able to operate on a blend of ethanol and gasoline in any volumetric concen- tration of up to 85% ethanol (93% in Brazil). The estima- tion of ethanol content is crucial for optimized and robust

Stefanopoulou, Anna

70

CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams  

E-Print Network (OSTI)

CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams and sequestration. Carbon sequestration is often associated with the planting of trees. As they mature, the trees INTRODUCTION The build-up of carbon dioxide (CO2) and other greenhouse gases in the Earth's atmosphere has

71

Numerical Modeling and Experimental Study of Combustion and Soot Formation in a Direct Injection Diesel Engine  

Science Journals Connector (OSTI)

Numerical Modeling and Experimental Study of Combustion and Soot Formation in a Direct Injection Diesel Engine ... The major problems associated with diesel engines are the high levels of nitrogen oxides (NOX) and particulate emissions. ... (11)?Flagan, R. C.; Seinfeld, J. H. Fundamentals of Air Pollution Engineering; Prentice Hall Inc.:? New York, 1988. ...

T. L. Chan; X. B. Cheng

2007-04-10T23:59:59.000Z

72

Formation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride Films  

E-Print Network (OSTI)

. Published April 28, 2010. Metal silicides such as TiSi2 and CoSi2 have been commonly used as the contactsFormation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride as the intermediate for subsequent conversion into nickel silicide NiSi , which is a key material for source, drain

73

Exhaust Emissions and Combustion Characteristics of a Direct Injection (DI) Diesel Engine Fueled with Methanol?Diesel Fuel Blends at Different Injection Timings  

Science Journals Connector (OSTI)

Exhaust Emissions and Combustion Characteristics of a Direct Injection (DI) Diesel Engine Fueled with Methanol?Diesel Fuel Blends at Different Injection Timings ... Because of their fuel economy and high reliability, compression-ignition (CI) engines known as diesel engines have been penetrating a number of markets around the world. ...

Mustafa Canakci; Cenk Sayin; Metin Gumus

2008-09-27T23:59:59.000Z

74

Application of semi-direct injection for spark-ignition engine  

Science Journals Connector (OSTI)

This paper proposes an application of a motorcycle engine lean-burn system for improving engine efficiency and reducing exhaust emissions. This Semi-Direct Injection (SDI) system consists of a high swirl charge, injection during intake-valve opening, and air-assisted fuel injection. The fuel enters the cylinder directly through the intake valve near the middle intake stroke for a richer mixture around the spark plug. A 125 cc, 4-valve, Port-Fuel-Injection (PFI) engine was retrofitted by designing a control plate to enhance the swirl. The swirl ratio was increased to 3.8 and the lean limit was extended to 1.7 of lambda (excess air ratio). The engine was tested at the low-load region, which includes most operation points of the ECE-40 driving cycle. A complete engine performance map was conducted for comparison between SDI and original PFI engines. The results show that Brake-Specific Fuel Consumption (BSFC) decreased by 11.3%. Brake-specific exhaust emissions of NOx and CO decreased by 32.0% and 92.9%, respectively. The HC emission increased by 47.7%.

Yuh-Yih Wu; Bo-Chiuan Chen; Anh-Trung Tran

2010-01-01T23:59:59.000Z

75

FY2001 Progress Report for the Spark Ignition Direct Injection R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

SPARK IGNITION, SPARK IGNITION, DIRECT INJECTION ENGINE R&D 2 0 0 1 A N N U A L P R O G R E S S R E P O R T U.S. Department of Energy Energy Efficiency and Renewable Energy Office of Transportation Technologies A C K N O W L E D G E M E N T We would like to express our sincere appreciation to Argonne National Laboratory and Computer Systems Management, Inc., for their artistic and technical contributions in preparing and publishing this report. In addition, we would like to thank all our program participants for their contributions to the programs and all the authors who prepared the project abstracts that comprise this report. U.S. Department of Energy Office of Transportation Technologies 1000 Independence Avenue, S.W. Washington, DC 20585-0121 FY 2001 Progress Report for the Spark Ignition Direct Injection R&D Program

76

FY2002 Progress Report for Fuels for Advanced Compression Ignition Direct Injection (CIDI) Engines  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuels for Advanced Compression Fuels for Advanced Compression Ignition Direct Injection (CIDI) Engines Energy Efficiency and Renewable Energy Office of FreedomCAR and Vehicle Technologies Approved by Stephen Goguen November 2002 Fuels for Advanced CIDI Engines FY 2002 Progress Report iii CONTENTS CONTENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iii INDEX OF PRIMARY CONTACTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v I. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 II. FUEL/LUBRICANT EFFECTS TESTING ON ENGINE PERFORMANCE . . . . . . . . . 13 A. Oil Consumption Contribution to CIDI PM Emissions during Transient Operation . . . . . . . . . . . . . . . . . . . .13

77

Development of Innovative Combustion Processes for a Direct-Injection Diesel Engine  

SciTech Connect

In support of the Partnership for a New Generation Vehicle (PNGV) emissions and fuel economy goals, a small-bore, high-speed, direct-injection (HSDI) diesel facility in which to conduct research into the physics of the combustion process relevant to these engines has been developed. The characteristics of this facility are described, and the motivation for selecting these characteristics and their relation to high efficiency, low-emission HSDI engine technology is discussed.

John Dec; Paul Miles

1999-01-01T23:59:59.000Z

78

Performance and Emissions of Direct Injection Diesel Engine Fueled with Diesel Fuel Containing Dissolved Methane  

Science Journals Connector (OSTI)

State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China ... soot and nitrogen oxides, from direct injection Diesel engines, engineers have proposed various solns., one of which is the use of a gaseous fuel as a partial supplement for liq. ... (16)?Heywood, J. B. Internal Combustion Engine Fundamentals; McGraw-Hill:? New York, 1988. ...

Junqiang Zhang; Deming Jiang; Zuohua Huang; Xibin Wang; Qi Wei

2006-01-19T23:59:59.000Z

79

New Phenomenological Six-Zone Combustion Model for Direct-Injection Diesel Engines  

Science Journals Connector (OSTI)

New Phenomenological Six-Zone Combustion Model for Direct-Injection Diesel Engines ... Nevertheless, to comply with ever more stringent emission standards, particularly regarding NOx and particulate matter (PM) emissions, such as EURO 6 in Europe, diesel engine manufacturers have to find new in-cylinder combustion strategies and/or complex after-treatment devices to reduce their emissions. ... Heywood, J. B. Internal Combustion Engines Fundamentals; McGraw-Hill: New York, 1988. ...

Alain Maiboom; Xavier Tauzia; Samiur Rahman Shah; Jean-François Hétet

2009-01-09T23:59:59.000Z

80

Determination of desorption efficiency utilizing direct injection: a dynamic calibration system and phase equilibrium  

E-Print Network (OSTI)

) Ronald H. Williams B. S. , Purdue University B. S. , University of Arkansas Chairman of Advisory Committee: Dr . R. B. Konzen Three methods for determining desorption efficiency for or ganic solvents adsorbed on activated charcoal were compared.... The three methods involved a dynamic calibra- tion system, direct injection, and phase equilibrium. The methods differed in the manner in which the analyte was placed on the adsorbent. The desorption efficiencies ob- tained using the dynamic calibration...

Williams, Ronald H

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Modified clay sorbents  

DOE Patents (OSTI)

A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

Fogler, H. Scott (Ann Arbor, MI); Srinivasan, Keeran R. (Livonia, MI)

1990-01-01T23:59:59.000Z

82

ASSESSMENT OF LOW COST NOVEL SORBENTS FOR COAL-FIRED POWER PLANT MERCURY CONTROL  

SciTech Connect

The injection of sorbents upstream of a particulate control device is one of the most promising methods for controlling mercury emissions from coal-fired utility boilers with electrostatic precipitators and fabric filters. Studies carried out at the bench-, pilot-, and full-scale have shown that a wide variety of factors may influence sorbent mercury removal effectiveness. These factors include mercury species, flue gas composition, process conditions, existing pollution control equipment design, and sorbent characteristics. The objective of the program is to obtain the necessary information to assess the viability of lower cost alternatives to commercially available activated carbon for mercury control in coal-fired utilities. Prior to injection testing, a number of sorbents were tested in a slipstream fixed-bed device both in the laboratory and at two field sites. Based upon the performance of the sorbents in a fixed-bed device and the estimated cost of mercury control using each sorbent, seventeen sorbents were chosen for screening in a slipstream injection system at a site burning a Western bituminous coal/petcoke blend, five were chosen for screening at a site burning a subbituminous Powder River Basin (PRB) coal, and nineteen sorbents were evaluated at a third site burning a PRB coal. Sorbents evaluated during the program were of various materials, including: activated carbons, treated carbons, other non-activated carbons, and non-carbon material. The economics and performance of the novel sorbents evaluated demonstrate that there are alternatives to the commercial standard. Smaller enterprises may have the opportunity to provide lower price mercury sorbents to power generation customers under the right set of circumstances.

Sharon Sjostrom

2004-03-01T23:59:59.000Z

83

An experimental investigation of high performance natural gas engine with direct injection  

Science Journals Connector (OSTI)

This paper presents experimental results of a new compressed natural gas direct injection (CNG-DI) engine that has been developed from modification of a multi cylinder gasoline port injection (PI) engine. The original gasoline-PI engine was also modified to a CNG bi-fuel system. The test results obtained from CNG fuel using two different systems (i.e. bi-fuel and DI) have been investigated and compared with the original gasoline engine. The objective of this investigation is to compare the test results between CNG-DI, with CNG-BI and gasoline-PI engines with the same displacement volume. It was found that the CNG-DI engine produces similar brake power at 6000 rpm and wide open throttle (WOT) but produces higher brake power at part load condition as compared to the original gasoline. The CNG-BI engine produces 23% lower brake power than the CNG-DI engine. The average brake specific fuel consumption (BSFC) of the CNG-DI engine was 0.28% and 8% lower than gasoline-PI and CNG-BI engines respectively. The CNG-DI engine reduces 42% \\{NOx\\} emission as compared to the base engine. However, the CNG-DI engine produces higher HC and CO emissions as compared to the base engine. This paper discusses a review on the direct injection (DI) natural gas engine with new information along with other investigations.

M.A. Kalam; H.H. Masjuki

2011-01-01T23:59:59.000Z

84

Uranium Sequestration via Phosphate Infiltration/Injection Test...  

NLE Websites -- All DOE Office Websites (Extended Search)

- Immediate sequestration - Stable mineral form * Apatite formation - Sorbent for uranium - Conversion to autunite 5 Advantages of Phosphate Technology * Direct treatment...

85

Controlling combustion noise in direct injection diesel engine through mechanical vibration measurement  

Science Journals Connector (OSTI)

The next generations of direct injection diesel engines have greatly improved their performances compared with petrol engines. However, one of the pending subjects is the noise and vibration levels, due to working cycle itself. The design effort to reduce the emissions of noise and vibration transmitted to the vehicle's driver could be lessened because of the assembly process variation. In this paper, a procedure to control this variation has been suggested in order to maintain noise and vibration performances within the limits of design.

J.A. Calvo; V. Diaz; J.L. San Roman

2005-01-01T23:59:59.000Z

86

Experimental Study of Diesel Fuel Effects on Direct Injection (DI) Diesel Engine Performance and Pollutant Emissions  

Science Journals Connector (OSTI)

Experimental Study of Diesel Fuel Effects on Direct Injection (DI) Diesel Engine Performance and Pollutant Emissions ... The test fuels indicate variable hydrocarbon composition and physical and chemical properties, and they were prepared under a European Union research program aiming to identify future fuel formulations for use in modern DI diesel engines. ... 1,2,4-9,13,14,16,17,24-26 In general, there is an interrelation between the molecular structure (paraffins, olefins, napthenes, and aromatic hydrocarbons), the chemical properties (cetane number, ignition point, etc.), and the physical properties (density, viscosity, surface tension, etc.) of the diesel fuel. ...

Theodoros C. Zannis; Dimitrios T. Hountalas; Roussos G. Papagiannakis

2007-07-19T23:59:59.000Z

87

Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends  

E-Print Network (OSTI)

The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

Kar, Kenneth

88

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends  

E-Print Network (OSTI)

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

Dimou, Iason

89

High Capacity Immobilized Amine Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Capacity Immobilized Amine Sorbents Capacity Immobilized Amine Sorbents Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,288,136 entitled "High Capacity Immobilized Amine Sorbents." Disclosed in this patent is the invention of a method that facilitates the production of low-cost carbon dioxide (CO 2 ) sorbents for use in large-scale gas-solid processes. This method treats an amine to increase the number of secondary amine groups and impregnates the amine in a porous solid support. As a result of this improvement, the method increases CO 2 capture capacity and decreases the cost of using an amine-enriched solid sorbent in CO 2 capture systems. Overview The U.S. Department of Energy has placed a high priority on the separation

90

Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells  

E-Print Network (OSTI)

70-108B One Cyclotron Road Berkeley, California 94720 December 2, 1997 Key Words: Proton Exchange Membrane fuel cells, humidification, gas distribution, direct liquid water injection, interdigitated flow fields. * Corresponding... of the catalyst layers were made of waterproof, carbon fiber cloths. Liquid water was injected by two metering pumps into two heated stainless steel coils, where it was preheated to the cell operating temperatures, and then directly into the gas streams...

Wood, D. L.; Yi, Y. S.; Nguyen, Trung Van

1998-01-01T23:59:59.000Z

91

Linear accelerator design study with direct plasma injection scheme for warm dense matter  

SciTech Connect

Warm Dense Matter (WDM) is a challenging science field, which is related to heavy ion inertial fusion and planetary science. It is difficult to expect the behavior because the state with high density and low temperature is completely different from ideal condition. The well-defined WDM generation is required to understand it. Moderate energy ion beams ({approx} MeV/u) slightly above Bragg peak is an advantageous method for WDM because of the uniform energy deposition. Direct Plasma Injection Scheme (DPIS) with a Interdigital H-mode (IH) accelerator has a potential for the beam parameter. We show feasible parameters of the IH accelerator for WDM. WDM physics is a challenging science and is strongly related to Heavy Ion Fusion science. WDM formation by Direct Plasma Injection Scheme (DPIS) with IH accelerator, which is a compact system, is proposed. Feasible parameters for IH accelerator are shown for WDM state. These represents that DPIS with IH accelerator can access a different parameter region of WDM.

Kondo, K.; Kanesue, T; Okamura, M.

2011-03-28T23:59:59.000Z

92

Experimental investigation of direct injection charge cooling in optical GDI engine using tracer-based PLIF technique  

Science Journals Connector (OSTI)

Abstract Investigation of direct injection charge cooling effects is indispensable in design and development of new combustion systems for Gasoline Direct Injection (GDI) engines. The charge cooling can be utilized to increase engine volumetric efficiency or compression ratio. It can be employed to suppress pre-ignition of highly boosted downsized engines or knocking combustion of naturally aspirated engines. The main purpose of this work was to develop an experimental setup for quantitative measurements of charge cooling during fuel injection process inside the combustion chamber of a GDI engine with optical access. For this purpose a tracer-based two-line Planar Laser Induced Fluorescence (PLIF) technique was implemented for the measurements. A specially designed Constant Volume Chamber (CVC) was utilized for quasi in situ calibration measurement so in-cylinder charge temperature measurements can be achieved independent of the photophysical model of dopant tracer. The thermometry technique was evaluated by measurements of average in-cylinder charge temperature during compression stroke for both motoring and firing cycles and comparing the results with temperature values calculated from in-cylinder pressure data assuming a polytropic compression. The PLIF technique was successfully utilized to quantify the extend of global temperature decrease as a result of direct injection charge cooling of two injection timings of 90 and 250 °CA ATDC and two injection quantities of 10 and 30 mg/cycle. Test results demonstrated the capability of the two-line PLIF thermometry technique in quantitative study of direct injection charge cooling effects.

Mohammadreza Anbari Attar; Mohammad Reza Herfatmanesh; Hua Zhao; Alasdair Cairns

2014-01-01T23:59:59.000Z

93

Performance and exhaust emissions of a two-stroke spark-ignition engine with a direct-injection system  

Science Journals Connector (OSTI)

A direct fuel-injection system has been adapted to a small two-stroke spark-ignition engine to prevent the charge from flowing through the cylinder during the scavenging process. The injection system consists of a jerk-type pump and a single-hole nozzle which supplies gasoline to the cylinder. Engine tests were carried out for comparison with the carburettor version of the same engine. The results show that the direct-injection version can achieve greatly improved thermal efficiency and lower HC and CO emissions without intake throttling. In addition, NOx can be reduced to a much lower level than that of the ordinary four-stroke engine. Heat release analysis and high-speed photography indicate that stratified charge combustion takes place in the direct-injection engine.

Yasuhiro Daisho; Takeshi Saito; Noriaki Ishibe; Mitsuhiro Tsukada; Masashi Yukawa

1991-01-01T23:59:59.000Z

94

Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts  

DOE Patents (OSTI)

A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

Gangwal, S.; Jothimurugesan, K.

1999-07-27T23:59:59.000Z

95

Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts  

DOE Patents (OSTI)

A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption processes, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gasses from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or "passivating" the heavy metals on the spent FCC catalyst as an intermediate step.

Gangwal, Santosh (Cary, NC); Jothimurugesan, Kandaswamy (Hampton, VA)

1999-01-01T23:59:59.000Z

96

Direct injection of ionospheric O sup + into the dayside low latitude boundary layer  

SciTech Connect

Observations from the AMPTE/Charge Composition Explorer (AMPTE/CCE) indicate the presence of two distinct O{sup +} populations in the dayside subsolar low latitude boundary layer during some periods of northward Interplanetary Magnetic Field (IMF). The first population is O{sup +} convected into the boundary layer from the outer magnetosphere and has been reported previously. It is suggested here that the new, second, O{sup +} population is injected into the dayside boundary layer directly from the high latitude ionosphere. This second population can have a significant density and distinct characteristics such as field-aligned flow relative to boundary layer H{sup +} that modify both the plasma composition and dynamics in the low latitude boundary layer. {copyright} American Geophysical Union 1989

Fuselier, S.A.; Klumpar, D.M.; Peterson, W.K.; Shelley, E.G. (Lockheed Palo Alto Research Laboratory, Palo Alto, California (US))

1989-10-01T23:59:59.000Z

97

High capacity immobilized amine sorbents  

DOE Patents (OSTI)

A method is provided for making low-cost CO.sub.2 sorbents that can be used in large-scale gas-solid processes. The improved method entails treating an amine to increase the number of secondary amine groups and impregnating the amine in a porous solid support. The method increases the CO.sub.2 capture capacity and decreases the cost of utilizing an amine-enriched solid sorbent in CO.sub.2 capture systems.

Gray, McMahan L. (Pittsburgh, PA); Champagne, Kenneth J. (Fredericktown, PA); Soong, Yee (Monroeville, PA); Filburn, Thomas (Granby, CT)

2007-10-30T23:59:59.000Z

98

Optical-Engine Study of a Low-Temperature Combustion Strategy Employing a Dual-Row, Narrow-Included-Angle Nozzle and Early, Direct Injection of Diesel Fuel  

Energy.gov (U.S. Department of Energy (DOE))

Insight into mechanisms causing observed sharp emissions increase with diesel fuel injection is gained through experiments in an optical engine employing a similar low-temperature combustion strategy of early, direct injection of diesel fuel.

99

Comparison of propane and methane performance and emissions in a turbocharged direct injection dual fuel engine  

SciTech Connect

With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

2011-04-20T23:59:59.000Z

100

sorbent-rti | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Solid Sorbents for Post-Combustion CO2 Capture Project No.: DE-FE0007707 RTI International is developing and demonstrating an advanced, solid sorbent-based CO2 capture...

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)  

SciTech Connect

This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

Shum, S.

1993-05-01T23:59:59.000Z

102

Sorbent characterization for FBC application  

SciTech Connect

Fluidized-bed boilers operating at both atmospheric and elevated pressures have received considerable attention from utilities and independent power producers because of their ability to remove SO{sub 2} from the flue gas during combustion and to minimize NO{sub x} production. The technology has advanced rapidly in the 1980s because of its adaptability to a range of fuel types, boiler capacities, and operating conditions without seriously compromising efficiency or performance. A sorbent, typically limestone or dolostone, is used in the fluidized-bed boiler to capture the combustion-generated SO{sub 2}. Many CFBC boiler operators are now realizing that optimizing sorbent usage is important for economical and environmentally acceptable operation of their plants. It is reported (mostly based on studies using a few sorbents) that particle size, porosity and pore size distribution, extent of sulfation, combustor temperature, pressure and CaCO{sub 3} content affect extent of sulfation.

Pisupati, S.V.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States)

1994-12-31T23:59:59.000Z

103

Analysis of the injection process in direct injected natural gas engines. Part 1: Study of unconfined and in-cylinder plume behavior  

SciTech Connect

A study of natural gas (NG) direct injection (DI) processes has been performed using multidimensional computational fluid dynamics analysis. The purpose was to improve the understanding of mixing in DI NG engines. Calculations of injection into a constant-volume chamber were performed to document unconfined plume behavior. A full three-dimensional calculation of injection into a medium heavy-duty diesel engine cylinder was also performed to study plume behavior in engine geometries. The structure of the NG plume is characterized by a core of unmixed fuel confined to the near-field of the jet. This core contains the bulk of the unmixed fuel and is mixed by the turbulence generated by the jet shear layer. The NG plume development in the engine is dominated by combustion chamber surface interactions. A Coanda effect causes plume attachment to the cylinder head, which has a detrimental impact on mixing. Unconfined plume calculations with different nozzle hole sizes demonstrate that smaller nozzle holes are more effective at mixing the fuel and air.

Jennings, M.J.; Jeske, F.R. (Ricardo North America, Burr Ridge, IL (United States))

1994-10-01T23:59:59.000Z

104

Formation of Nickel Silicide from Direct-liquid-injection Chemical-vapor-deposited Nickel Nitride Films  

SciTech Connect

Smooth, continuous, and highly conformal nickel nitride (NiN{sub x}) films were deposited by direct liquid injection (DLI)-chemical vapor deposition (CVD) using a solution of bis(N,N{prime}-di-tert-butylacetamidinato)nickel(II) in tetrahydronaphthalene as the nickel (Ni) source and ammonia (NH{sub 3}) as the coreactant gas. The DLI-CVD NiNx films grown on HF-last (100) silicon and on highly doped polysilicon substrates served as the intermediate for subsequent conversion into nickel silicide (NiSi), which is a key material for source, drain, and gate contacts in microelectronic devices. Rapid thermal annealing in the forming gas of DLI-CVD NiNx films formed continuous NiSi films at temperatures above 400 C. The resistivity of the NiSi films was 15{mu}{Omega} cm, close to the value for bulk crystals. The NiSi films have remarkably smooth and sharp interfaces with underlying Si substrates, thereby producing contacts for transistors with a higher drive current and a lower junction leakage. Resistivity and synchrotron X-ray diffraction in real-time during annealing of NiNx films showed the formation of a NiSi film at about 440 C, which is morphologically stable up to about 650 C. These NiSi films could find applications in future nanoscale complementary metal oxide semiconductor devices or three-dimensional metal-oxide-semiconductor devices such as Fin-type field effect transistors for the 22 nm technology node and beyond.

Li, Z.; Gordon, R; Li, H; Shenai, D; Lavoie, C

2010-01-01T23:59:59.000Z

105

Hydrocarbon emissions in a homogeneous direct-injection spark engine : gasoline and gasohol  

E-Print Network (OSTI)

In order to better understand the effects on hydrocarbon emissions of loading, engine temperature, fuel type, and injection timing, a series of experiments was performed. The effect of loading was observed by running the ...

Tharp, Ronald S

2008-01-01T23:59:59.000Z

106

Power, Efficiency, and Emissions Optimization of a Single Cylinder Direct-Injected Diesel Engine for Testing of Alternative Fuels through Heat Release Modeling  

E-Print Network (OSTI)

Power, Efficiency, and Emissions Optimization of a Single Cylinder Direct-Injected Diesel Engine for Testing of Alternative Fuels through Heat Release Modeling BY Jonathan Michael Stearns Mattson Submitted to the graduate degree program..., Efficiency, and Emissions Optimization of a Single Cylinder Direct-Injected Diesel Engine for Testing of Alternative Fuels through Heat Release Modeling BY Jonathan Michael Stearns Mattson...

Mattson, Jonathan Michael Stearns

2013-08-31T23:59:59.000Z

107

Long-Term Demonstration of Sorbent Enhancement Additive Technology for Mercury Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Long-Term DemonsTraTion of sorbenT Long-Term DemonsTraTion of sorbenT enhancemenT aDDiTive TechnoLogy for mercury conTroL Background The 2005 Clean Air Mercury Rule will require significant reductions in mercury emissions from coal-fired power plants. The combustion of subbituminous coals typically results in higher fractions of elemental mercury emissions than the combustion of bituminous coals. This complicates mercury capture efforts, particularly for technologies using powdered activated carbon (PAC) injection, because elemental mercury is not readily captured by PAC injection alone. In short, unmodified PACs are better suited for bituminous coals than for subbituminous coals. Various proprietary sorbent enhancement additives (SEA) have been developed to increase the mercury reactivity of PACs, and perhaps fly

108

Advanced Utility Mercury-Sorbent Field-Testing Program  

SciTech Connect

This report summarizes the work conducted from September 1, 2003 through December 31, 2007 on the project entitled Advanced Utility Mercury-Sorbent Field-Testing Program. The project covers the testing at the Detroit Edison St. Clair Plant and the Duke Power Cliffside and Buck Stations. The St. Clair Plant used a blend of subbituminous and bituminous coal and controlled the particulate emissions by means of a cold-side ESP. The Duke Power Stations used bituminous coals and controlled their particulate emissions by means of hot-side ESPs. The testing at the Detroit Edison St. Clair Plant demonstrated that mercury sorbents could be used to achieve high mercury removal rates with low injection rates at facilities that burn subbituminous coal. A mercury removal rate of 94% was achieved at an injection rate of 3 lb/MMacf over the thirty day long-term test. Prior to this test, it was believed that the mercury in flue gas of this type would be the most difficult to capture. This is not the case. The testing at the two Duke Power Stations proved that carbon- based mercury sorbents can be used to control the mercury emissions from boilers with hot-side ESPs. It was known that plain PACs did not have any mercury capacity at elevated temperatures but that brominated B-PAC did. The mercury removal rate varies with the operation but it appears that mercury removal rates equal to or greater than 50% are achievable in facilities equipped with hot-side ESPs. As part of the program, both sorbent injection equipment and sorbent production equipment was acquired and operated. This equipment performed very well during this program. In addition, mercury instruments were acquired for this program. These instruments worked well in the flue gas at the St. Clair Plant but not as well in the flue gas at the Duke Power Stations. It is believed that the difference in the amount of oxidized mercury, more at Duke Power, was the difference in instrument performance. Much of the equipment was purchased used and all of the equipment has nearly reached the end of its useful service.

Ronald Landreth

2007-12-31T23:59:59.000Z

109

Ultrafast and quantitative X-tomography and simulation of hollow-cone gasoline direct-injection sprays.  

SciTech Connect

Gasoline direct injection (GDI) has the potential to greatly improve internal combustion engine performance through precise control of the injection rate, timing, and combustion of the fuel. A thorough characterization of the hydrodynamics of fuel injection has to come from a precise, quantitative analysis of the sprays, especially in the near-nozzle region. A lack of knowledge of the fuel-spray dynamics has severely limited computational modeling of the sprays and design of improved injection systems. Previously, the structure and dynamics of highly transient fuel sprays have never been visualized or reconstructed in three dimensions (3D) due to numerous technical difficulties. By using an ultrafast x-ray detector and intense monochromatic x-ray beams from synchrotron radiation, the fine structures and dynamics of 1-ms GDI fuel sprays from an outwardly opening nozzle were elucidated by a newly developed, ultrafast, microsecond computed microtomography (CT) technique. In a time-resolved manner, many detailed features associated with the transient fuel flows are readily observable in the quantitatively reconstructed 3D fuel spray density distribution as a result of the quantitative CT technique. More importantly, a computational fluid dynamics (CFD) simulation based on the Taylor analogy breakup (TAB) model has also been performed using the boundary and initial conditions obtained from the experiment data. The experimental and numerical results are in good agreement quantitatively. These results not only reveal the characteristics of the GDI fuel sprays with unprecedented detail, but will also facilitate realistic computational fluid dynamic simulations in highly transient, multiphase systems.

Liu, X.; Im, K-S; Wang, Y.; Wang, J.; Tate, M.W.; Ercan, A.; Schuette, D.R.; Gruner, S.M. (X-Ray Science Division); (Cornell Univ.)

2007-01-01T23:59:59.000Z

110

Photopatternable sorbent and functionalized films  

DOE Patents (OSTI)

A composition containing a polymer, a crosslinker and a photo-activatable catalyst is placed on a substrate. The composition is exposed to a predetermined pattern of light, leaving an unexposed region. The light causes the polymer to become crosslinked by hydrosilylation. A solvent is used to remove the unexposed composition from the substrate, leaving the exposed pattern to become a sorbent polymer film that will absorb a predetermined chemical species when exposed to such chemical species.

Grate, Jay W. (West Richland, WA); Nelson, David A. (Richland, WA)

2006-01-31T23:59:59.000Z

111

Near-frictionless carbon coatings for spark-ignited direct-injected fuel systems. Final report, January 2002.  

SciTech Connect

This report describes an investigation by the Tribology Section of Argonne National Laboratory (ANL) into the use of near-frictionless carbon (NFC) coatings for spark-ignited, direct-injected (SIDI) engine fuel systems. Direct injection is being pursued in order to improve fuel efficiency and enhance control over, and flexibility of, spark-ignited engines. SIDI technology is being investigated by the Partnership for a New Generation of Vehicles (PNGV) as one route towards meeting both efficiency goals and more stringent emissions standards. Friction and wear of fuel injector and pump parts were identified as issues impeding adoption of SIDI by the OTT workshop on ''Research Needs Related to CIDI and SIDI Fuel Systems'' and the resulting report, Research Needs Related to Fuel Injection Systems in CIDI and SIDI Engines. The following conclusions were reached: (1) Argonne's NFC coatings consistently reduced friction and wear in existing and reformulated gasolines. (2) Compared to three commercial DLC coatings, NFC provided the best friction reduction and protection from wear in gasoline and alternative fuels. (3) NFC was successfully deposited on production fuel injectors. (4) Customized wear tests were performed to simulate the operating environment of fuel injectors. (5) Industry standard lubricity test results were consistent with customized wear tests in showing the friction and wear reduction of NFC and the lubricity of fuels. (6) Failure of NFC coatings by tensile crack opening or spallation did not occur, and issues with adhesion to steel substrates were eliminated. (7) This work addressed several of the current research needs of the OAAT SIDI program, as defined by the OTT report Research Needs Related to Fuel Injection Systems in CIDI and SIDI Engines.

Hershberger, J.; Ozturk, O.; Ajayi, O. O.; Woodford, J. B.; Erdemir, A.; Fenske, G. R.

2002-04-05T23:59:59.000Z

112

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines  

Energy.gov (U.S. Department of Energy (DOE))

Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

113

Method for Regeneration of Immobilized Amine Sorbents for Use...  

NLE Websites -- All DOE Office Websites (Extended Search)

Method for Regeneration of Immobilized Amine Sorbents for Use in CO 2 Capture Opportunity Research is currently active on the patent-pending technology "Regenerable Sorbent...

114

Determination of Depleted Uranium in Urine via Isotope Ratio Measurements Using Large-Bore Direct Injection High Efficiency Nebulizer–Inductively Coupled Plasma Mass Spectrometry  

Science Journals Connector (OSTI)

Inductively coupled plasma mass spectrometry (ICP-MS), coupled with a large-bore direct injection high efficiency nebulizer (LB-DIHEN), was utilized to determine the concentration and...

Westphal, Craig S; McLean, John A; Hakspiel, Shelly J; Jackson, William E; McClain, David E; Montaser, Akbar

2004-01-01T23:59:59.000Z

115

Combustion analysis of a direct injection diesel engine when fuelled with sunflower methyl ester and its diesel blends  

Science Journals Connector (OSTI)

Uncertainty in the availability of petroleum-based fuels in the near future and stringent pollution norms have triggered a search for renewable and clean-burning fuels. The use of vegetable oil as an alternative fuel has for long been in the pipeline, but its direct use has been limited because of its higher viscosity. In this work, sunflower oil was taken as feedstock and the feasibility of sunflower oil methyl ester (SFME) as an alternative fuel for diesel engines was investigated. Tests were conducted in a 4.4 kW, single cylinder, naturally aspirated direct injection diesel engine. It was observed that the premixed combustion phase of SFME and its blends were less intense compared with diesel oil. In addition, it was observed that SFME and its blends had slightly lower thermal efficiency and lower tailpipe emissions than diesel oil.

G. Lakshmi Narayana Rao; S. Saravanan; P. Selva Ilavarasi; G. Devasagayam

2009-01-01T23:59:59.000Z

116

Method for Regeneration of Immobilized Amine Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Regeneration of Immobilized Amine Sorbents Regeneration of Immobilized Amine Sorbents for Use in CO 2 Capture Opportunity Research is currently active on the patent-pending technology "Regenerable Sorbent Technique for Capturing CO 2 Using Immobilized Amine Sorbents." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Carbon sequestration entails a multi-step process in which anthropogenic CO 2 emissions are captured from CO 2 -laden process gas streams and perma- nently stored. Carbon capture is a critical step in the process and accounts for a considerable portion of the overall cost. Newly developed, high-capacity amine-based sorbents offer many advantages over existing technology

117

Sorption of petroleum products by carbon sorbents  

SciTech Connect

A comparative study of the adsorption of petroleum products by micro- and macroporous carbon sorbents was performed. For this purpose, four carbon sorbent samples prepared from various raw materials by various processing techniques were used. The following raw materials were used: (1) fuel mill from the Mezinoskoe deposit; (2) wood waste, shaving and sawdust in ratio (%) of 50:50; and (3) low-caking gas coal of the 2G group from the mine im.Kirova in the Kuznetsk Basin. The pore structures and adsorption capacities of these sorbents for petroleum products were studied. It was found that the adsorption of petroleum products on porous and nonporous carbon sorbents occurred in different manners. In this case, macroporous sorbents with a weakly developed structure of sorbing micro- and mesopores exhibited a maximum capacity for petroleum products.

M.A. Perederii; Y.I. Kurakov; I.N. Malikov; S.V. Molchanov [Institute for Fossil Fuels, Moscow (Russian Federation)

2009-07-01T23:59:59.000Z

118

Highly Attrition Resistant Zinc Oxide-Based Sorbents for H2S Removal by Spray Drying Technique  

SciTech Connect

Primary issues for the fluidized-bed/transport reactor process are high attrition resistant sorbent, its high sorption capacity and regenerability, durability, and cost. The overall objective of this project is the development of a superior attrition resistant zinc oxide-based sorbent for hot gas cleanup in integrated coal gasification combined cycle (IGCC). Sorbents applicable to a fluidized-bed hot gas desulfurization process must have a high attrition resistance to withstand the fast solid circulation between a desulfurizer and a regenerator, fast kinetic reactions, and high sulfur sorption capacity. The oxidative regeneration of zinc-based sorbent usually initiated at greater than 600 C with highly exothermic nature causing deactivation of sorbent as well as complication of sulfidation process by side reaction. Focusing on solving the sorbent attrition and regenerability of zinc oxide-based sorbent, we have adapted multi-binder matrices and direct incorporation of regeneration promoter. The sorbent forming was done with a spray drying technique that is easily scalable to commercial quantity.

Ryu, C.K.; Lee, J.B.; Ahn, D.H.; Kim, J.J.; Yi, C.K.

2002-09-19T23:59:59.000Z

119

An Experimental Study on the Two-Stage Combustion Characteristics of a Direct-Injection-Type HCCI Engine  

Science Journals Connector (OSTI)

Department of Mechanical Engineering, Hanyang University, 1271 Sa-1 Dong, Sangrok-gu Ansan-si, Gyenggi-do, 426-791, Korea ... This research was achieved using a direct-injection-type diesel method during the intake stroke in real single-cylinder engines, and observations were made regarding the cool and hot flame characteristics, according to the air:fuel ratio and engine speed (given in units of rpm), an additive that influences the auto-ignition and the start times, and the combustion and emission characteristics, according to these times. ... This work was supported by the “Development of techniques on the fundamental and practical use of a HCCI” project at Korea Automotive Technology Institute, 2004. ...

Kihyung Lee; Changsik Lee; Jeaduk Ryu; Hyungmin Kim

2005-02-12T23:59:59.000Z

120

Carbon Dioxide Capture Process with Regenerable Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Dioxide Capture Process with Regenerable Sorbents Dioxide Capture Process with Regenerable Sorbents sorbent material. Additionally, the design of the system incorporates a cross- flow moving-bed reactor where the gas flows horizontally through a "panel" of solid sorbent that is slowly moving down-wards under gravity flow. With the expanded use of fossil fuels expected throughout the world, the increase in CO 2 emissions may prove to contribute even more significantly to global climate change. To address this problem, carbon sequestration scientists and engineers have proposed a number of methods to remove CO 2 from gas streams, such as chemical absorption with a solvent, membrane separation, and cryogenic fractionation. However, all of these methods are expensive and possibly cost-prohibitive for a specific application.

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Adsorption and Ultrasound-Assisted Sorbent Regeneration  

SciTech Connect

This work was conducted for the department of Energy. In this work, we developed a class of new sorbents that were highly sulfur selective and had high sulfur capacities. The study consisted of two sections. Development of the new sorbents is described in Section 1, and Section was a fundamental study, conducted for a better understanding for desulfurization of jet fuels. More details of the results are given blow separately for the two sections.

Yuhe Wang; Liping Ma; Ralph T. Yang

2006-09-30T23:59:59.000Z

122

SciTech Connect: Evaluation of Dry Sorbent Injection Technology...  

Office of Scientific and Technical Information (OSTI)

DOE National Energy Technology Laboratory with URS as the prime contractor. Illinois Clean Coal Institute and The University of Illinois Urbana-Champaign were project co-funders....

123

Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 2  

SciTech Connect

This report summarizes the results of Phase 2 of this contract. The authors completed four tasks under this phase of the subcontract. (1) They developed a computational fluid dynamics (CFD) model of a 3500 direct injected natural gas (DING) engine gas injection/combustion system and used it to identify DING ignition/combustion system improvements. The results were a 20% improvement in efficiency compared to Phase 1 testing. (2) The authors designed and procured the components for a 3126 DING engine (300 hp) and finished assembling it. During preliminary testing, the engine ran successfully at low loads for approximately 2 hours before injector tip and check failures terminated the test. The problems are solvable; however, this phase of the program was terminated. (3) They developed a Decision & Risk Analysis model to compare DING engine technology with various other engine technologies in a number of commercial applications. The model shows the most likely commercial applications for DING technology and can also be used to identify the sensitivity of variables that impact commercial viability. (4) MVE, Inc., completed a preliminary design concept study that examines the major design issues involved in making a reliable and durable 3,000 psi LNG pump. A primary concern is the life of pump seals and piston rings. Plans for the next phase of this program (Phase 3) have been put on indefinite hold. Caterpillar has decided not to fund further DING work at this time due to limited current market potential for the DING engine. However, based on results from this program, the authors believe that DI natural gas technology is viable for allowing a natural gas-fueled engine to achieve diesel power density and thermal efficiency for both the near and long terms.

Cox, G.B.; DelVecchio, K.A.; Hays, W.J.; Hiltner, J.D.; Nagaraj, R.; Emmer, C.

2000-03-02T23:59:59.000Z

124

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

125

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

126

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

127

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

128

Enhanced durability of high-temperature desulfurization sorbents for moving-bed applications. Option 2 Program: Development and testing of zinc titanate sorbents  

SciTech Connect

One of the most advantageous configurations of the integrated gasification combined cycle (IGCC) power system is coupling it with a hot gas cleanup for the more efficient production of electric power in an environmentally acceptable manner. In conventional gasification cleanup systems, closely heat exchangers are necessary to cool down the fuel gases for cleaning, sometimes as low as 200--300{degree}F, and to reheat the gases prior to injection into the turbine. The result is significant losses in efficiency for the overall power cycle. High-temperature coal gas cleanup in the IGCC system can be operated near 1000{degree}F or higher, i.e., at conditions compatible with the gasifier and turbine components, resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for IGCC power systems in which mixed-metal oxides are currently being used as desulfurization sorbents. The objective of this contract is to identify and test fabrication methods and sorbent chemical compositions that enhance the long-term chemical reactivity and mechanical durability of zinc ferrite and other novel sorbents for moving-bed, high-temperature desulfurization of coal-derived gases. Zinc ferrite was studied under the base program of this contract. In the next phase of this program novel sorbents, particularly zinc titanate-based sorbents, are being studied under the remaining optional programs. This topical report summarizes only the work performed under the Option 2 program. In the course of carrying out the program, more than 25 zinc titanate formulations have been prepared and characterized to identify formulations exhibiting enhanced properties over the baseline zinc titanate formulation selected by the US Department of Energy.

Ayala, R.E.

1993-04-01T23:59:59.000Z

129

Brominated Sorbents for Small Cold-Side ESPs, Hot-Side ESPs and Fly Ash Use in Concrete  

SciTech Connect

This report summarizes the work conducted from September 16, 2005 through December 31, 2008 on the project entitled �Brominated Sorbents for Small Cold-Side ESPs, Hot-Side ESPs and Fly Ash Use in Concrete�. The project covers testing at three host sites: Progress Energy H.F. Lee Station and the Midwest Generation Crawford and Will County Stations. At Progress Energy Lee 1, parametric tests were performed both with and without SO{sub 3} injection in order to determine the impact on the mercury sorbent performance. In addition, tests were performed on the hot-side of the air preheater, before the SO{sub 3} is injected, with H-PAC� sorbents designed for use at elevated temperatures. The BPAC� injection provided the expected mercury removal when the SO{sub 3} injection was off. A mercury removal rate due to sorbent of more than 80% was achieved at an injection rate of 8 lb/MMacf. The operation with SO{sub 3} injection greatly reduced the mercury sorbent performance. An important learning came from the injection of H-PAC� on the hot-side of the air preheater before the SO{sub 3} injection location. The H-PAC� injected in this manner appeared to be independent of the SO{sub 3} injection and provided better mercury removal than with injecting on the cold-side with SO{sub 3} injection. Consequently, one solution for plants like Lee, with SO{sub 3} injection, or plants with SO{sub 3} generated by the SCR catalyst, is to inject H-PAC� on the hot-side before the SO{sub 3} is in the flue gas. Even better performance is possible by injecting on the cold-side without the SO{sub 3}, however. During the parametric testing, it was discovered that the injection of B-PAC� (or H-PAC�) was having a positive impact upon ESP performance. It was decided to perform a 3-day continuous injection run with B-PAC� in order to determine whether Lee 1 could operate without SO{sub 3} injection. If the test proved positive, the continuous injection would continue as part of the long-term test. The injection of B-PAC� did allow for the operation of Lee 1 without SO{sub 3} injection and the long-term test was conducted from March 8 through April 7, 2006. The total mercury removal for the 30-day long-term test, excluding the first day when SO{sub 3} was injected and the last day when a plain PAC was used, averaged 85%. The achievement of 85% Hg removal over the 30 days longterm test is another milestone in the history of achievement of the Albemarle Environmental f/k/a Sorbent Technologies Corporation B-PAC� sorbent. A clear indication of the impact of B-PAC� on opacity came at the end of the long-term test. It was hoped that Lee 1 could be operated for several days after the end of the long-term test. It took less than a day before the opacity began to increase. The discovery that B-PAC� can improve ESP performance while capturing a large amount of mercury is another milestone for the B-PAC� mercury sorbent. The parametric testing at the Midwest Generation Crawford Station was divided into two phases; the first using C-PAC�, the concrete friendly sorbent, and the other using nonconcrete friendly materials. The first phase of the parametric tests was conducted before the long-term test. The second phase of the parametric testing was performed after the long-term test in order to avoid contaminating the fly ash containing the concrete friendly sorbents. The parametric test began with an injection rate of 1 lb/MMacf and, after a period to allow the mercury concentration to stabilize, the rate was increased to 3 lb/MMacf. The Hg removal for this test was about 60% due to sorbent and 69% total at the injection rate of 1 lb/MMacf and 80% due to sorbent and 84% total for the 3 lb/MMacf injection rate. The average total vapor phase mercury removal for the first 21 days of the long-term test was 82% at an injection rate o

Ronald Landreth

2008-06-30T23:59:59.000Z

130

Sulfur tolerant highly durable CO.sub.2 sorbents  

SciTech Connect

A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent containing calcium oxide (CaO) and at least one refractory dopant having a Tammann temperature greater than about 530.degree. C., wherein the refractory dopant enhances resistance to sintering, thereby conserving performance of the sorbent at temperatures of at least about 530.degree. C. Also provided are doped CaO sorbents for the capture of carbon dioxide in the presence of SO.sub.2.

Smirniotis, Panagiotis G. (Cincinnati, OH); Lu, Hong (Urbana, IL)

2012-02-14T23:59:59.000Z

131

Effect of Fuel Injection Timing on the Emissions of a Direct-Injection (DI) Diesel Engine Fueled with Canola Oil Methyl Ester?Diesel Fuel Blends  

Science Journals Connector (OSTI)

(3, 4) A lot of researchers have reported that using biodiesel as a fuel in diesel engines causes a diminution in harmful exhaust emissions as well as equivalent engine performance with diesel fuel. ... Engine tests have been carried out with the aim of obtaining comparative measures of torque, power, specific fuel consumption and emissions such as CO, smoke d. and NOx to evaluate and compute the behavior of the diesel engine running on the above-mentioned fuels. ... Ma, Z.; Huang, Z. H.; Li, C.; Wang, X. B.; Miao, H.Effects of fuel injection timing on combustion and emission characteristics of a diesel engine fueled with diesel?propane blends Energy Fuels 2007, 21 ( 3) 1504– 1510 ...

Cenk Sayin; Metin Gumus; Mustafa Canakci

2010-03-11T23:59:59.000Z

132

Topical Report 5: Sorbent Performance Report  

SciTech Connect

ADA-ES has completed an extensive sorbent screening program funded primarily through DOE NETL cooperative agreement DE-NT0005649 with support from EPRI and industry cost-share participants. Tests were completed on simulated and actual flue gas. The overall project objective is to address the viability and accelerate development of a solid-based postcombustion CO2 capture technology that can be retrofit to the existing fleet of coal-fired power plants. An important component of the viability assessment was to evaluate the state of development of sorbents and measure key performance characteristics under realistic operating conditions.

Krutka, Holly; Sjostrom, Sharon

2011-05-31T23:59:59.000Z

133

Analysis of ignition behavior in a turbocharged direct injection dual fuel engine using propane and methane as primary fuels  

SciTech Connect

This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (���© pilot �¢���¼ 0.2-0.6 and ���© overall �¢���¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant ���© pilot (> 0.5), increasing ���© overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing ���© overall (at constant ���© pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

2011-10-05T23:59:59.000Z

134

The effect of ethanol-water fumigation on the performance and emissions from a direct-injection diesel engine.  

E-Print Network (OSTI)

??The effect of ethanol fumigation and water injection on the performance and exhaust emissions from a 1.9-liter Volkswagen TDI diesel engine was investigated. The engine… (more)

Olson, André Louis

2010-01-01T23:59:59.000Z

135

Capture of carbon dioxide by solid amine sorbents  

Science Journals Connector (OSTI)

The reaction of tetraethylorthrosilcate (TEOS) with y-aminopropyltriethoxysilane (APTS) has produced stable solid amine sorbents for the capture of carbon dioxide. The resulting amine-enriched silicon sorbent (SBA-15) has been proven to be competitive with existing environmental CO2 controlled life sorbents based on the immobilised amine technology. XPS analysis has indicated that the amine groups (N1s Peak) were incorporated onto the surfaces of this amine-based sorbent in the range of 7%. The performance of the SBA-15 was comparable to the commercially available immobilised amine sorbent (IAS).

M.L. Gray; Y. Soong; K.J. Champagne; H.W. Pennline; J. Baltrus; R.W. Stevens Jr.; R. Khatri; S.S.C. Chuang

2004-01-01T23:59:59.000Z

136

Carbon dioxide capture process with regenerable sorbents  

DOE Patents (OSTI)

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

137

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

138

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. In this report, the reactivity of AHI-5 was examined. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 70 {micro}m particles are reacted with 9000-18000 ppm hydrogen sulfide at 350-500 C. The range of space time of reaction gas mixtures is 0.071-0.088 s. The range of reaction duration is 4-10800 s.

K.C. Kwon

2001-01-01T23:59:59.000Z

139

Study of mixture formation and early flame development in a research GDI (gasoline direct injection) engine through numerical simulation and UV-digital imaging  

Science Journals Connector (OSTI)

Abstract The analysis of the mixture formation and early combustion processes in a slightly lean burn gasoline direct injection (GDI) engine is performed by using experimental and numerical techniques. UV–visible natural emission digital imaging is applied in the optically accessible combustion chamber of a research engine. This is equipped with the four-valve head and the same injection system of a commercial turbocharged engine. Optical accessibility is obtained through a quartz window placed on the piston head. Numerical simulations are performed by means of a 3D model developed within the AVL FireTM environment, which exploits an in-house developed sub-model for simulating the spray dynamics. Tests are carried out using commercial gasoline. The cyclic variability of the engine is first analysed in order to properly define a reference average pressure cycle to be used for the validation of the numerical model. This last is then proved as being highly predictive as the start of injection is moved in the working cycle. The main effects of the injection and ignition timing on the characteristic flame development angles, namely on the flame initiation and propagation, are analysed. Flame initiation is visualised both numerically and experimentally.

M. Costa; L. Marchitto; S.S. Merola; U. Sorge

2014-01-01T23:59:59.000Z

140

Layered solid sorbents for carbon dioxide capture  

DOE Patents (OSTI)

A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

2014-11-18T23:59:59.000Z

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to obtain the most current and comprehensive results.


141

Direct Probing of Charge Injection and Polarization-Controlled Ionic Mobility on Ferroelectric LiNbO3 Surfaces  

SciTech Connect

Mapping surface potential with time-resolved Kelvin Probe Force Microscopy (tr-KPFM) in LiNbO3 periodically-poled single crystal revealed activation of the surface ionic subsystem. Electric fields higher than certain threshold value but lower than the switching field induce injection of charge from the biased electrode, formation of an active region in its vicinity and uneven distribution of screening charge on the opposite ferroelectric domains. Tr-KPFM technique allows investigating these phenomena in details.

Strelcov, Evgheni [ORNL] [ORNL; Ievlev, Dr. Anton [Ural State University, Russia] [Ural State University, Russia; Jesse, Stephen [ORNL] [ORNL; Kravchenko, Ivan I [ORNL] [ORNL; Shur, V.Y. [Institute of Physics and Applied Mathematics, Ural State University] [Institute of Physics and Applied Mathematics, Ural State University; Kalinin, Sergei V [ORNL] [ORNL

2014-01-01T23:59:59.000Z

142

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect

This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

2006-09-30T23:59:59.000Z

143

ADVANCED SORBENT DEVELOPMENT PROGRAM DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS  

SciTech Connect

The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000 F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.'s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration temperatures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent development at General Electric's Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

R.E Ayala; V.S. Venkataramani; Javad Abbasian; Rachid B. Slimane; Brett E. Williams; Minoo K. Zarnegar; James R. Wangerow; Andy H. Hill

2000-03-31T23:59:59.000Z

144

ADVANCED SORBENT DEVELOPMENT PROGRAM; DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS  

SciTech Connect

The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 °C (900-1000 °F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.?s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 °C (650 °F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 °C (650-1000 °F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 °C (700 °F) to 538 °C (1000 °F) and regeneration tempera-tures up to 760 °C (1400 °F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent develop-ment at General Electric?s Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

R.E. AYALA; V.S. VENKATARAMANI

1998-09-30T23:59:59.000Z

145

Manganese-based sorbents for coal gas desulfurization  

SciTech Connect

The intent of this study is to perform a preliminary screening on a particular Mn-based sorbent, CST-939 (from Chemetals), for hot gas desulfurization. The purpose of the preliminary screening is to determine which temperature and type of coal gas this sorbent demonstrates the greatest capacity and efficiency for sulfur removal. The following conclusions were made from the data collected on the CST-939 sorbent: The sorbent efficiency and capacity are much greater at 343{degrees}C (650{degrees}F) than at 871{degrees}C (1,600{degrees}F). The sorbent efficiency and capacity are much greater in the presence of the more highly-reducing Shell gas than with the less-reducing KRW gas. The sorbent showed tremendous capacity for sulfur pickup, with actual loadings as high as 21 weight percent. Oxidative regeneration at 871{degrees}C (1,600{degrees}F) appeared to decompose sulfate; however, unusually high SO{sub 2} release during the second sulfidations and/or reductive regenerations indicated incomplete regeneration. The average crush strength of the reacted sorbent did not indicate any loss of strength as compared to the fresh sorbent. Superior sorbent performance was obtained in the presence of simulated Shell gas at 538{degrees}C (1,000{degrees}F).

Gasper-Galvin, L.D.; Fisher, E.P. [USDOE Morgantown Energy Technology Center, WV (United States); Goyette, W.J. [Chemetals, Inc., Baltimore, MD (United States)

1996-12-31T23:59:59.000Z

146

Sorbents and Carbon-Based Materials for Hydrogen Storage Research...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for storing hydrogen in high-surface-area sorbents such as hybrid carbon nanotubes, aerogels, and nanofibers, as well as metal-organic frameworks and conducting polymers. A...

147

Influence of Biodiesel Fuel on the Combustion and Emission Formation in a Direct Injection (DI) Diesel Engine  

Science Journals Connector (OSTI)

The injector needle lift trace at low engine speed was almost identical for both fuels, while at maximum engine speed, a shorter injection delay was observed for biodiesel fuel and the injector needle opened earlier as with D2 fuel. ... Figure 1 Comparison of the engine torque (M), fuel consumption (Gh), and brake specific energy consumption (ge) at full load for biodiesel fuel (BD) and D2 fuel in (a) TAM and (b) MAN engines. ... (7)?Sanatore, A.; Cardone, M.; Rocco, V.; Prati, M. V. A comparative analysis of combustion process in DI diesel engine fueled with biodiesel and diesel fuel. ...

Ales Hribernik; Breda Kegl

2007-05-01T23:59:59.000Z

148

A Low Cost, High Capacity Regenerable Sorbent for Pre-combustion CO{sub 2} Capture  

SciTech Connect

The overall objective of the proposed research is to develop a low cost, high capacity CO{sub 2} sorbent and demonstrate its technical and economic viability for pre-combustion CO{sub 2} capture. The specific objectives supporting our research plan were to optimize the chemical structure and physical properties of the sorbent, scale-up its production using high throughput manufacturing equipment and bulk raw materials and then evaluate its performance, first in bench-scale experiments and then in slipstream tests using actual coal-derived synthesis gas. One of the objectives of the laboratory-scale evaluations was to demonstrate the life and durability of the sorbent for over 10,000 cycles and to assess the impact of contaminants (such as sulfur) on its performance. In the field tests, our objective was to demonstrate the operation of the sorbent using actual coal-derived synthesis gas streams generated by air-blown and oxygen-blown commercial and pilot-scale coal gasifiers (the CO{sub 2} partial pressure in these gas streams is significantly different, which directly impacts the operating conditions hence the performance of the sorbent). To support the field demonstration work, TDA collaborated with Phillips 66 and Southern Company to carry out two separate field tests using actual coal-derived synthesis gas at the Wabash River IGCC Power Plant in Terre Haute, IN and the National Carbon Capture Center (NCCC) in Wilsonville, AL. In collaboration with the University of California, Irvine (UCI), a detailed engineering and economic analysis for the new CO{sub 2} capture system was also proposed to be carried out using Aspen PlusTM simulation software, and estimate its effect on the plant efficiency.

Alptekin, Gokhan

2012-09-30T23:59:59.000Z

149

Comparison of PM emissions from a gasoline direct injected (GDI) vehicle and a port fuel injected (PFI) vehicle measured by electrical low pressure impactor (ELPI) with two fuels: Gasoline and M15 methanol gasoline  

Science Journals Connector (OSTI)

Two Euro 4 gasoline passenger vehicles (one gasoline direct injected vehicle and one port fuel injected vehicle) were tested over the cold start New European Driving Cycle (NEDC). Each vehicle was respectively fueled with gasoline and M15 methanol gasoline. Particle number concentrations were measured by the electrical low pressure impactor (ELPI). Particle masses were measured by gravimetric method and estimated from the number distributions using two density distributions (one is constant with the particle size and one is power law related with the size). The first 7 stages of ELPI were used for estimation. The results show that for each vehicle, PM masses measured by gravimetric method, the total PM numbers measured by ELPI and estimated PM masses for M15 are lower than those for gasoline. For each kind of fuel, PM masses by two methods and total PM numbers from the GDI vehicle are higher than those from the PFI one. PM number distribution curves of the four vehicle/fuel combinations are similar. All decline gradually and the maximum number of each curve occurs in the first stage. More than 99.9% numbers locate in the first 8 stages of which diameters are less than 1 ?m. PM number emissions correlate well with the acceleration of the two vehicles. The estimated particle masses were much lower than the gravimetric measurements.

Bin Liang; Yunshan Ge; Jianwei Tan; Xiukun Han; Liping Gao; Lijun Hao; Wentao Ye; Peipei Dai

2013-01-01T23:59:59.000Z

150

Analysis of an extremely fast valve opening camless system to improve transient performance in a turbocharged high speed direct injection diesel engine  

Science Journals Connector (OSTI)

This article describes a theoretical study on the performance optimisation of a high speed direct injection turbocharged diesel engine equipped with an electro-hydraulic variable valve actuation 'camless' system. This system provides extremely fast valve opening and closing slopes. Thus, its potential for recovering part of the energy lost in the valves by reducing gas flow sonic conditions in the valve throat has been investigated. This study has been mainly focused on the analysis of engine performance during a load transient evolution, but the full load steady state attained at the end of the load transient has been also discussed. The results of this investigation have confirmed important improvements in engine performance during the load transient owing to less energy being lost across the valves, which directly results in more energy being available in the turbine. This benefit has also been observed at full load steady state conditions.

J. Benajes; J.R. Serrano; V. Dolz; R. Novella

2009-01-01T23:59:59.000Z

151

Functionalized sorbent for chemical separations and sequential forming process  

DOE Patents (OSTI)

A highly functionalized sorbent and sequential process for making are disclosed. The sorbent includes organic short-length amino silanes and organic oligomeric polyfunctional amino silanes that are dispersed within pores of a porous support that form a 3-dimensional structure containing highly functionalized active binding sites for sorption of analytes.

Fryxell, Glen E. (Kennewick, WA); Zemanian, Thomas S. (Richland, WA)

2012-03-20T23:59:59.000Z

152

NETL: Mercury Emissions Control Technologies - Advanced Mercury Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Mercury Sorbents with Low Impact on Power Plant Operations Advanced Mercury Sorbents with Low Impact on Power Plant Operations Apogee Scientific, Inc. (Apogee) will lead a Team comprised of Southern Company Services, TXU, Tennessee Valley Authority, EPRI, URS Group, University of Illinois-Illinois State Geological Survey (ISGS), Southern Research Institute (SRI), Calgon Carbon, and TDA Research, Inc., to evaluate a number of advanced sorbents for removing vapor-phase mercury from coal-fired flue gas that have minimal impact on by-product utilization and/or on existing particulate collection devices (PCD). The main objective of this program is to evaluate several advanced sorbents for removing mercury from coal-fired flue gas while posing minimal impact on plant operations through three advanced sorbent concepts: 1) Sorbents which minimize impact on concrete production through selective chemical passivation of activated carbon and use of non-carbon material, 2) sorbents that minimize baghouse pressure drop and ESP emissions, and 3) sorbents that can be recovered and reused.

153

Modeling the Effect of Fuel Ethanol Concentration on Cylinder Pressure Evolution in Direct-Injection Flex-Fuel Engines  

E-Print Network (OSTI)

Modeling the Effect of Fuel Ethanol Concentration on Cylinder Pressure Evolution in Direct the fuel vaporization pro- cess for ethanol-gasoline fuel blends and the associated charge cooling effect experimental cylinder pressure for different gasoline-ethanol blends and various speeds and loads on a 2.0 L

Stefanopoulou, Anna

154

High-pressure late cycle direct injection of natural gas in a rail medium speed diesel engine  

SciTech Connect

The performance of an Electro-Motive Division (EMD) 567B, two-cylinder locomotive research engine, when operated on high-pressure/late-cycle injection of natural gas, is presented in this paper. A redesign and fabrication of the fuel system was undertaken to facilitate the consumption of natural gas. A small percentage of No.2 diesel fuel (DF-2) was used to ignite the natural gas. Engine performance, while running natural gas, resulted in matching rated speed and power with slightly lower thermal efficiency. Full power was achieved with a ratio of 99 percent natural gas and 1 percent diesel fuel. However, at high natural gas to diesel fuel ratios, audible knock was detected. The primary objective of the project was to establish technical feasibility of, and basic technology for, operating medium-speed rail diesel engines on high-pressure natural gas. Secondary objectives were to attain adequate engine performance levels for rail application, develop a system oriented toward retrofit of in-service locomotives, and realize any potential improvements in thermal efficiency due to use of the high-pressure/late-cycle approach.

Wakenell, J.F.; O'Neal, G.B.; Baker, Q.A.

1987-01-01T23:59:59.000Z

155

Study Reveals Fuel Injection Timing Impact on Particle Number Emissions (Fact Sheet)  

SciTech Connect

Start of injection can improve environmental performance of fuel-efficient gasoline direct injection engines.

Not Available

2012-12-01T23:59:59.000Z

156

Syngas (H2/CO) in a spark-ignition direct-injection engine. Part 1: Combustion, performance and emissions comparison with CNG  

Science Journals Connector (OSTI)

Abstract The combustion, performance, and emissions of syngas (H2/CO) in a four-stroke, direct-injection, spark-ignition engine were experimentally investigated. The engine was operated at various speeds, ranging from 1500 to 2400 rev/min, with the throttle being held in the wide-open position. The start of fuel injection was fixed at 180° before the top dead center, and the ignition advance was set at the maximal brake torque. The air/fuel ratio was varied from the technically possible lowest excess air ratio (?) to lean operation limits. The results indicated that a wider air/fuel operating ratio is possible with syngas with a very low coefficient of variation. The syngas produced a higher in-cylinder peak pressure and heat-release rate peak and faster combustion than for CNG. However, CNG produced a higher brake thermal efficiency (BTE) and lower brake specific fuel consumption (BSFC). The BTE and BSFC of the syngas were on par to those of CNG at higher speeds. For the syngas, the total hydrocarbon emission was negligible at all load conditions, and the carbon monoxide emission was negligible at higher loads and increased under lower load conditions. However, the emission of nitrogen oxides was higher at higher loads with syngas.

Ftwi Yohaness Hagos; A. Rashid A. Aziz; Shaharin A. Sulaiman

2014-01-01T23:59:59.000Z

157

SOx/NOx sorbent and process of use  

DOE Patents (OSTI)

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

158

Octahedral molecular sieve sorbents and catalysts  

DOE Patents (OSTI)

Octahedral molecular sieve sorbents and catalysts are disclosed, including silver hollandite and cryptomelane. These materials can be used, for example, to catalyze the oxidation of CO.sub.x (e.g., CO), NO.sub.x (e.g., NO), hydrocarbons (e.g., C.sub.3H.sub.6) and/or sulfur-containing compounds. The disclosed materials also may be used to catalyze other reactions, such as the reduction of NO.sub.2. In some cases, the disclosed materials are capable of sorbing certain products from the reactions they catalyze. Silver hollandite, in particular, can be used to remove a substantial portion of certain sulfur-containing compounds from a gas or liquid by catalysis and/or sorption. The gas or liquid can be, for example, natural gas or a liquid hydrocarbon.

Li, Liyu [Richland, WA; King, David L [Richland, WA

2010-04-20T23:59:59.000Z

159

Regenerable Immobilized Aminosilane Sorbents for Carbon Dioxide Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Immobilized Aminosilane Sorbents Immobilized Aminosilane Sorbents for Carbon Dioxide Capture Opportunity Research is currently active on the patent-pending technology titled "Regenerable Immobilized Aminosilane Sorbents for Carbon Dioxide Capture." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Carbon sequestration entails a multi-step process in which CO 2 is first separated / captured from gas streams followed by permanent storage. Carbon capture represents a critical step in the process and accounts for a considerable portion of the overall cost. Newly developed, high capacity amine-based sorbents offer many advantages over existing technology including increased CO

160

sorbent-univerisity-north-dakota | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

of North Dakota (UND) is scaling up and demonstrating a solid sorbent technology for carbon dioxide (CO2) capture and separation from coal combustion-derived flue gas. The...

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
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161

eval-solid-sorbent | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Solid Sorbents as a Retrofit Technology for CO2 Capture Project No.: DE-FE0004343 3-D model and Photograph of 1 kW System 3-D model and Photograph of 1 kW System...

162

Process for preparing zinc oxide-based sorbents  

DOE Patents (OSTI)

The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasad (Durham, NC)

2011-06-07T23:59:59.000Z

163

Direct  

NLE Websites -- All DOE Office Websites (Extended Search)

interactions, and the pollutant emission is hence directly proportional to the bulk neutral density. Simultaneously monitoring the total emission at 1040 nm and the...

164

Development of a Catalyst/Sorbent for Methane Reforming  

SciTech Connect

This project led to the further development of a combined catalyst and sorbent for improving the process technology required for converting CH{sub 4} and/or CO into H{sub 2} while simultaneously separating the CO{sub 2} byproduct all in a single step. The new material is in the form of core-in-shell pellets such that each pellet consists of a CaO core surrounded by an alumina-based shell capable of supporting a Ni catalyst. The Ni is capable of catalyzing the reactions of steam with CH{sub 4} or CO to produce H{sub 2} and CO{sub 2}, whereas the CaO is capable of absorbing the CO{sub 2} as it is produced. The absorption of CO{sub 2} eliminates the reaction inhibiting effects of CO{sub 2} and provides a means for recovering the CO{sub 2} in a useful form. The present work showed that the lifecycle performance of the sorbent can be improved either by incorporating a specific amount of MgO in the material or by calcining CaO derived from limestone at 1100 C for an extended period. It also showed how to prepare a strong shell material with a large surface area required for supporting an active Ni catalyst. The method combines graded particles of {alpha}-alumina with noncrystalline alumina having a large specific surface area together with a strength promoting additive followed by controlled calcination. Two different additives produced good results: 3 {micro}m limestone and lanthanum nitrate which were converted to their respective oxides upon calcination. The oxides partially reacted with the alumina to form aluminates which probably accounted for the strength enhancing properties of the additives. The use of lanthanum made it possible to calcine the shell material at a lower temperature, which was less detrimental to the surface area, but still capable of producing a strong shell. Core-in-shell pellets made with the improved shell materials and impregnated with a Ni catalyst were used for steam reforming CH{sub 4} at different temperatures and pressures. Under all conditions tested, the CH{sub 4} conversion was large (>80%) and nearly equal to the predicted thermodynamic equilibrium level as long as CO{sub 2} was being rapidly absorbed. Similar results were obtained with both shell material additives. Limited lifecycle tests of the pellets also produced similar results that were not affected by the choice of additive. However, during each lifecycle test the period during which CO{sub 2} was rapidly absorbed declined from cycle to cycle which directly affected the corresponding period when CH{sub 4} was reformed rapidly. Therefore, the results showed a continuing need for improving the lifecycle performance of the sorbent. Core-in-shell pellets with the improved shell materials were also utilized for conducting the water gas shift reaction in a single step. Three different catalyst formulations were tested. The best results were achieved with a Ni catalyst, which proved capable of catalyzing the reaction whether CO{sub 2} was being absorbed or not. The calcined alumina shell material by itself also proved to be a very good catalyst for the reaction as long as CO{sub 2} was being fully absorbed by the core material. However, neither the alumina nor a third formulation containing Fe{sub 2}O{sub 3} were good catalysts for the reaction when CO{sub 2} was not absorbed by the core material. Furthermore, the Fe{sub 2}O{sub 3}-containing catalyst was not as good as the other two catalysts when CO{sub 2} was being absorbed.

B.H. Shans; T.D. Wheelock; Justinus Satrio; Karl Albrecht; Tanya Harris Janine Keeley; Ben Silva; Aaron Shell; Molly Lohry; Zachary Beversdorf

2008-12-31T23:59:59.000Z

165

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

1998-10-31T23:59:59.000Z

166

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

SciTech Connect

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

167

Enhanced durability of desulfurization sorbents for fluidized-bed applications  

SciTech Connect

To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

Gupta, R.P.; Gangwal, S.K.

1992-11-01T23:59:59.000Z

168

Enhanced durability of desulfurization sorbents for fluidized-bed applications  

SciTech Connect

To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

Gupta, R.P.; Gangwal, S.K.

1992-11-01T23:59:59.000Z

169

Experimental investigation of the effect of combined hydrogen and diesel combustion on the particulate size distribution from a high speed direct injection diesel engine  

Science Journals Connector (OSTI)

The effects of hydrogen addition and exhaust gas recirculation (EGR) levels on the exhaust particulate matter size distribution in a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4-cylinder, direct injection engine equipped with a modern high-pressure common rail. A nano-Micro-Orifice Uniform Deposit Impactor (nano-MOUDI) was used in this work to study the particulate matter size distribution. All tests were conducted at the set operating point of 1,500 rpm. The experimental work showed that the particulate matter size distribution was not dramatically altered by the addition of EGR, but the main peak was shifted towards the nucleation mode with the addition of hydrogen. The addition of hydrogen increases the emissions of nitrogen oxides (NOx), but reduces the emissions of unburnt hydrocarbons (THC). Conversely, the addition of EGR reduces NOx, but can increase THC. Hydrogen addition increases the peak cylinder pressure and the maximum rate of pressure rise.

L. McWilliam; A. Megaritis

2009-01-01T23:59:59.000Z

170

Artificial neural networks based prediction of performance and exhaust emissions in direct injection engine using castor oil biodiesel-diesel blends  

Science Journals Connector (OSTI)

In this study the performance and emission characteristics of a direct injection diesel engine using castor oil biodiesel (COB)-diesel blended fuels were investigated experimentally and then predicted by artificial neural networks. For this aim castor oil was converted to its biodiesel via transesterification approach. Then the effects of the biodiesel percentage in blend engine load and speed on brake power brake specific fuel consumption (BSFC) nitrogen oxides (NOx) carbon dioxide (CO2) carbon monoxide (CO) and particle matter (PM) have been considered. Fuel blends with various percentages of biodiesel (0% 5% 10% 15% 20% 25% and 30%) at various engine speeds and loads were tested. The results indicated that blends of COB with diesel fuel provide admissible engine performance; on the other side emissions decreased so much. Two types of neural networks a group method of data handling (GMDH) and feed forward were used for modeling of the diesel engine to predict brake power BSFC and exhaust emissions such as CO CO2 NOx and PM values. The comparison results demonstrate the superiority of the feed forward neural networkmodels over GMDH type models in terms of the statistical measures in the training and testing data but in the number of hidden neurons and model simplicity GMDH models are preferred.

M. H. Shojaeefard; M. M. Etghani; M. Akbari; A. Khalkhali; B. Ghobadian

2012-01-01T23:59:59.000Z

171

Effect of palm methyl ester-diesel blends performance and emission of a single-cylinder direct-injection diesel engine  

Science Journals Connector (OSTI)

The purpose of this study is to investigate engine performance and exhaust emission when using several blends of neat palm oil methyl ester (POME) with conventional diesel (D2) in a small direct injection diesel engine and to compare the outcomes to that of the D2 fuel. Engine performances exhaust emissions and some other important parameters were observed as a function of engine load and speed. In addition the effect of modifying compression ratio was also carried out in this study. From the engine experimental work neat and blended fuels behaved comparably to diesel (D2) in terms of fuel consumption thermal efficiency and rate of heat released. Smoke density showed better results than that emitted by D2 operating under similar conditions due to the presence of inherited oxygen and lower sulphur content in the biofuel and its blends. The emissions of CO CO2 and HC were also lower using blended mixtures and in its neat form. However NOx concentrations were found to be slight higher for POME and its blends and this was largely due to higher viscosity of POME and possibly the presence of nitrogen in the palm methyl ester. General observation indicates that biofuel blends can be use without many difficulties in this type of engine but for optimized operation minor modifications to the engine and its auxiliaries are required.

Mazlan Said; Azhar Abdul Aziz

2012-01-01T23:59:59.000Z

172

Emissions and fuel economy of a vehicle with a spark-ignition, direct-injection engine : Mitsubishi Legnum GDI{trademark}.  

SciTech Connect

A 1997 Mitsubishi Legnum station wagon with a 150-hp, 1.8-L, spark-ignition, direct-injection (SIDI) engine was tested for emissions by using the FTP-75, HWFET, SC03, and US06 test cycles and four different fuels. The purpose of the tests was to obtain fuel-economy and emissions data on SIDI vehicles and to compare the measurements obtained with those of a port-fuel-injection (PFI) vehicle. The PFI vehicle chosen for the comparison was a 1995 Dodge Neon, which meets the Partnership for a New Generation of Vehicles (PNGV) emissions goals of nonmethane hydrocarbons (NMHC) less than 0.125 g/mi, carbon monoxide (CO) less than 1.7 g/mi, nitrogen oxides (NO{sub x} ) less than 0.2 g/mi, and particulate matter (PM) less than 0.01 g/mi. The Mitsubishi was manufactured for sale in Japan and was not certified to meet current US emissions regulations. Results show that the SIDI vehicle can provide up to 24% better fuel economy than the PFI vehicle does, with correspondingly lower greenhouse gas emissions. The SIDI vehicle as designed does not meet the PNGV goals for NMHC or NO{sub x} emissions, but it does meet the goal for CO emissions. Meeting the goal for PM emissions appears to be contingent upon using low-sulfur fuel and an oxidation catalyst. One reason for the difficulty in meeting the NMHC and NO{sub x} goals is the slow (200 s) warm-up of the catalyst. Catalyst warm-up time is primarily a matter of design. The SIDI engine produces more NMHC and NO{sub x} than the PFI engine does, which puts a greater burden on the catalyst to meet the emissions goals than is the case with the PFI engine. Oxidation of NMHC is aided by unconsumed oxygen in the exhaust when the SIDI engine operates in stratified-charge mode, but the same unconsumed oxygen inhibits chemical reduction of NO{sub x} . Thus, meeting the NO{sub x} emissions goal is likely to be the greatest challenge for the SIDI engine.

Cole, R. L.; Poola, R. B.; Sekar, R.

1999-04-08T23:59:59.000Z

173

Preparation and selection of Fe-Cu sorbent for COS removal in syngas  

Science Journals Connector (OSTI)

A series of iron-based sorbents prepared with iron trioxide hydrate, cupric oxide by a novel method was studied in a fixed-bed reactor for COS removal from syngas at moderate temperature. In addition, the sorbent...

Bowu Cheng; Zhaofei Cao; Yong Bai…

2010-12-01T23:59:59.000Z

174

Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power - Fact Sheet, 2011 Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power - Fact Sheet, 2011 TDA...

175

R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen Storage Technologies Workshops R&D Strategies for Compressed, Cryo-Compressed and Cryo-Sorbent Hydrogen...

176

Sorbents and Carbon-Based Materials for Hydrogen Storage Research and Development  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy's research and development on sorbents and carbon-based materials for hydrogen storage targets breakthrough concepts for storing hydrogen in high-surface-area sorbents...

177

A Reusable Calcium-Based Sorbent for Desulfurizing Hot Coal Gas  

SciTech Connect

The overall objective of this project has been to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas. The sorbent should be strong, durable, inexpensive to manufacture, and capable of being reused many times. To achieve these objectives the project has focused on the development of the very promising core-in-shell sorbent.

Wheelock, T.D.; Hasler, D.J.L.

2002-09-19T23:59:59.000Z

178

NETL: IEP - Post-Combustion CO2 Emissions Control - Low Cost Sorbent for  

NLE Websites -- All DOE Office Websites (Extended Search)

Low Cost Sorbent for Capturing CO2 Emissions Generated by Existing Coal-Fired Power Plants Low Cost Sorbent for Capturing CO2 Emissions Generated by Existing Coal-Fired Power Plants Project No.: DE-NT0005497 TDA sorbent test equipment TDA sorbent test equipment. TDA Research Inc. will produce and evaluate a low-cost solid sorbent developed in prior laboratory testing. The process uses an alkalized alumina adsorbent to capture carbon dioxide (CO2) at intermediate temperature and near ambient pressure. The physical adsorbent is regenerated with low-pressure steam. Although the regeneration is primarily by concentration swing, the adsorption of steam on the sorbent during regeneration also provides approximately 8°C to 10°C of temperature swing, further enhancing the regeneration rate. The sorbent is transferred between two moving bed reactors. Cycling results in gas

179

Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorbents for Removal of Carbon Dioxide from Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 6,908,497 entitled "Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures." Disclosed in this patent is a new low-cost carbon dioxide (CO 2 ) sorbent that can be used in large-scale gas-solid processes. Researchers have developed a new method to prepare these sorbents by treating substrates with an amine and/or an ether in a way that either one comprises at least 50 weight percent of the sorbent. The sorbent captures compounds contained in gaseous fluids through chemisorptions and/or

180

NETL: Evaluation of Dry Sorbent Technology for Pre-Combustion CO2 Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Dry Sorbent Technology for Pre-Combustion CO2 Capture Evaluation of Dry Sorbent Technology for Pre-Combustion CO2 Capture Project No.: DE-FE0000465 Scanning Electron Microsopy (SEM) and Transmission Electron Miscroscopy (TEM) images of a multi-functional sorbent synthesized by a novel method. Scanning Electron Microsopy (SEM) and Transmission Electron Miscroscopy (TEM) images of a multi-functional sorbent synthesized by a novel method. URS and the University of Illinois at Urbana-Champaign are investigating a dry sorbent process configured to combine the water-gas-shift (WGS) reaction with carbon dioxide (CO2) removal for coal gasification systems. A combination of process simulation modeling and sorbent molecular and thermodynamic analyses will be performed to predict optimal sorbent properties and identify optimal operating temperature and pressure ranges

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Injection-Induced Earthquakes  

Science Journals Connector (OSTI)

...sounds safe enough. But if the deep aquifer system was originally underpressured...directed toward protection of potable aquifers by requiring injection into formations...much smaller magnitudes. The largest fracking-induced earthquakes (24, 26) have all been below the damage...

William L. Ellsworth

2013-07-12T23:59:59.000Z

182

Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents  

SciTech Connect

Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

2007-06-30T23:59:59.000Z

183

Tevatron injection timing  

SciTech Connect

Bunched beam transfer from one accelerator to another requires coordination and synchronization of many ramped devices. During collider operation timing issues are more complicated since one has to switch from proton injection devices to antiproton injection devices. Proton and antiproton transfers are clearly distinct sequences since protons and antiprotons circulate in opposite directions in the Main Ring (MR) and in the Tevatron. The time bumps are different, the kicker firing delays are different, the kickers and lambertson magnets are different, etc. Antiprotons are too precious to be used for tuning purposes, therefore protons are transferred from the Tevatron back into the Main Ring, tracing the path of antiprotons backwards. This tuning operation is called ``reverse injection.`` Previously, the reverse injection was handled in one supercycle. One batch of uncoalesced bunches was injected into the Tevatron and ejected after 40 seconds. Then the orbit closure was performed in the MR. In the new scheme the lambertson magnets have to be moved and separator polarities have to be switched, activities that cannot be completed in one supercycle. Therefore, the reverse injection sequence was changed. This involved the redefinition of TVBS clock event $D8 as MRBS $D8 thus making it possible to inject 6 proton batches (or coalesced bunches) and eject them one at a time on command, performing orbit closure each time in the MR. Injection devices are clock event driven. The TCLK is used as the reference clock. Certain TCLK events are triggered by the MR beam synchronized clock (MRBS) events. Some delays are measured in terms of MRBS ticks and MR revolutions. See Appendix A for a brief description of the beam synchronized clocks.

Saritepe, S.; Annala, G.

1993-06-01T23:59:59.000Z

184

Development of Novel Carbon Sorbents for CO2 Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sorbents Carbon Sorbents for CO 2 Capture Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) Research and Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal re- serves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D Program portfolio of post- and oxy-combustion carbon dioxide (CO 2 ) emissions control technologies and CO 2 compression is focused on advancing technological options for the existing fleet of coal-fired power plants in the event of carbon constraints. Pulverized coal (PC)-fired power plants are large, stationary sources of CO

185

Adsorption and Desorption of CO2 on Solid Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

ADSORPTION AND DESORPTION OF CO ON SOLID SORBENTS ADSORPTION AND DESORPTION OF CO ON SOLID SORBENTS 2 Ranjani Siriwardane (rsiiw@netl.doe.gov; 304-285-4513) Ming Shen (mshen@netl.doe.gov; 304-285-4112) Edward Fisher (efishe@netl.doe.gov; 304-285-4011) James Poston (jposto@netl.doe.gov; 304-285-4635) Abolghasem Shamsi (ashams@netl.doe.gov; 304-285-4360) U.S. Department of Energy, National Energy Technology Laboratory, 3610 Collins Ferry Road, P.O.Box 880, Morgantown, WV 26507-0880 INTRODUCTION Fossil fuels supply more than 98% of the world's energy needs. However, the combustion of fossil fuels is one of the major sources of the green house gas CO . It is necessary to develop 2 technologies that will allow us to utilize the fossil fuels while reducing the emissions of green house gases. Commercial CO capture technology that exists today is very expensive and energy

186

Method for removing metal ions from solution with titanate sorbents  

DOE Patents (OSTI)

A method for removing metal ions from solution comprises the steps of providing titanate particles by spray-drying a solution or slurry comprising sorbent titanates having a particle size up to 20 micrometers, optionally in the presence of polymer free of cellulose functionality as binder, said sorbent being active towards heavy metals from Periodic Table (CAS version) Groups IA, IIA, IB, IIB, IIIB, and VIII, to provide monodisperse, substantially spherical particles in a yield of at least 70 percent of theoretical yield and having a particle size distribution in the range of 1 to 500 micrometers. The particles can be used free flowing in columns or beds, or entrapped in a nonwoven, fibrous web or matrix or a cast porous membrane, to selectively remove metal ions from aqueous or organic liquid.

Lundquist, Susan H. (White Bear Township, MN); White, Lloyd R. (Minneapolis, MN)

1999-01-01T23:59:59.000Z

187

NETL Patented CO2-Removal Sorbents Promise Power and Cost Savings |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Patented CO2-Removal Sorbents Promise Power and Cost Savings Patented CO2-Removal Sorbents Promise Power and Cost Savings NETL Patented CO2-Removal Sorbents Promise Power and Cost Savings May 30, 2012 - 1:00pm Addthis Washington, DC - Carbon dioxide removal sorbents developed by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) could result in power and cost savings for users of some heating, ventilation and air conditioning (HVAC) systems under a recently signed license agreement. NETL, the research and development laboratory for DOE's Office of Fossil Energy, entered into a patent license agreement with Boston-based Enverid Systems Inc. for NETL-developed solid sorbents that remove CO2 from gas streams. NETL's sorbents will be incorporated into an Enverid product called EnClaire™, which adds on to HVAC systems to reduce power

188

Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power Improving Desulfurization to Enable Fuel Cell Utilization of Digester Gases This project will develop a new,...

189

Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power- Fact Sheet, 2011  

Energy.gov (U.S. Department of Energy (DOE))

Factsheet describing project objective to develop a new, high-capacity, expendable sorbent to remove sulfur species from anaerobic digester gas

190

Partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal at a medium temperature  

SciTech Connect

Laboratory experiments were conducted to investigate the reactivity of partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal. Sulfation tests were performed at 550{sup o}C using a fixed bed reactor under conditions simulating economizer zone injection flue gas desulfurization. Activation experiments were conducted with water or steam using a range of temperatures between 100 and 550{sup o}C. The results showed that the reactivity of the sorbents was closely related to the content of Ca(OH){sub 2} formed in the activation process, which varied with the water or steam temperature. The sulfur dioxide capture capacity of Ca(OH){sub 2} in the sorbent is higher than that of CaO at a medium temperature. Water or steam temperatures in the range of 100-200{sup o}C are favorable to the formation of Ca(OH){sub 2} from CaO. 15 refs., 8 figs., 2 tabs.

Liming Shi; Xuchang Xu [Tsinghua University, Beijing (China). Department of Thermal Engineering

2005-12-01T23:59:59.000Z

191

Assessment of Low Cost Novel Mercury Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Testing of Mercury Control Technologies Testing of Mercury Control Technologies for Coal-Fired Power Plants by Thomas J. Feeley, III 1. , Lynn A. Brickett 1. , B. Andrew O'Palko 1. , and James T. Murphy 2. 1. U.S. Department of Energy, National Energy Technology Laboratory 2. Science Applications International Corporation The U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) is conducting a comprehensive research, development, and demonstration (RD&D) program directed at advancing the performance and economics of mercury control technologies for coal- fired power plants. The program also includes evaluating the fate of mercury in coal by-products and studying the transport and transformation of mercury in power plant plumes. This paper presents results from ongoing full-scale and slip-stream field testing of several mercury control

192

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

193

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

194

Nanoclay-Based Solid Sorbents for CO2 Capture  

Science Journals Connector (OSTI)

Nanoclay-Based Solid Sorbents for CO2 Capture ... As seen from the figure, the untreated nanoclay shows very little CO2 capture, while amine-treated nanoclays show considerably higher CO2 capture capacities, demonstrating the effectiveness of the amine treatment. ... The CO2 sorption capacity increases as the temperature is increased from 50 to 85 °C, and it reaches as high as 7.5% at 85 °C for the nanoclay treated with both APTMS and PEI, although the nanoclays treated with either APTMS or PEI show about 6% CO2 capture capacity. ...

Elliot A. Roth; Sushant Agarwal; Rakesh K. Gupta

2013-03-19T23:59:59.000Z

195

Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test August 21, 2012 - 1:00pm Addthis Washington, DC - The successful bench-scale test of a novel carbon dioxide (CO2) capturing sorbent promises to further advance the process as a possible technological option for reducing CO2 emissions from coal-fired power plants. The new sorbent, BrightBlack™, was originally developed for a different application by Advanced Technology Materials Inc. (ATMI) , a subcontractor to SRI for the Department of Energy (DOE)-sponsored test at the University of Toledo. Through partnering with the Office of Fossil Energy's National Energy Technology Laboratory (NETL) and others, SRI developed a method to

196

Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test Novel Sorbent Achieves 90 Percent Carbon Capture in DOE-Sponsored Test August 21, 2012 - 1:00pm Addthis Washington, DC - The successful bench-scale test of a novel carbon dioxide (CO2) capturing sorbent promises to further advance the process as a possible technological option for reducing CO2 emissions from coal-fired power plants. The new sorbent, BrightBlack™, was originally developed for a different application by Advanced Technology Materials Inc. (ATMI) , a subcontractor to SRI for the Department of Energy (DOE)-sponsored test at the University of Toledo. Through partnering with the Office of Fossil Energy's National Energy Technology Laboratory (NETL) and others, SRI developed a method to

197

Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases  

DOE Patents (OSTI)

Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

Nelson, Sidney (Hudson, OH)

2011-02-15T23:59:59.000Z

198

Investigations on emission characteristics of the pongamia biodiesel–diesel blend fuelled twin cylinder compression ignition direct injection engine using exhaust gas recirculation methodology and dimethyl carbonate as additive  

Science Journals Connector (OSTI)

Experiments were carried out on a twin cylinder direct injection compression ignition engine using pongamia biodiesel–diesel blend as fuel with exhaust gas recirculation (EGR) and dimethyl carbonate (DMC) as additive. The experimental results showed that pongamia biodiesel–diesel blend fuelled engine with EGR and DMC can simultaneously reduce smoke and nitric oxide ( NO x ) emission. The NO x emission was reduced by about 17.68% for 10% of EGR introduction and about 13.55% increase in smoke emission. When dimethyl carbonate was added with EGR the engine emits lower smoke with lesser NO x emission and it showed that the smoke reduction rate had a linear relationship with DMC percentage. The carbon monoxide (CO) and hydrocarbon (HC) emissions also decreased when DMC was added. However the addition of DMC with EGR caused an increase in both BSEC and BTE.

M. Pandian; S. P. Sivapirakasam; M. Udayakumar

2010-01-01T23:59:59.000Z

199

Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures  

NLE Websites -- All DOE Office Websites (Extended Search)

Organoclay Sorbent for Removal of Carbon Dioxide from Gas Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures Contact NETL Technology Transfer Group techtransfer@netl.doe.gov October 2012 Significance * Energy mixing is maximized * Mobilizing of the particulates is complete * No "dead zones" exist * Packing of material is minimized * Eroding effects are significantly reduced Applications * Mixing nuclear waste at Hanford * Any similar industrial process involving heavy solids in a carrier fluid Opportunity Research is currently active on the patent-pending technology "Organoclay Sorbent for Removal of Carbon Dioxide from

200

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

202

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

203

Original articles: Sorption properties of a fibrous polypropylene-polyacrylic acid sorbent and its analytical application  

SciTech Connect

The advantages of fibrous sorbents and their growing role in the preconcentration of trace elements have repeatedly been noted elsewhere. The sorption properties of a sorbent are known to be determined by the nature of its functional groups. In this communication, the authors shall present the results of a study of the sorption properties of a fibrous sorbent based on polypropylene and polyacrylic acid (PP-PAA) which contains carboxyl groups as functional groups, with respect to bismuth(III), zirconium, and titanium (IV), and they shall describe a procedure for the preconcentration of bismuth from solutions of copper alloys followed by its photometric determination.

Chaprasova, L.V.; Shesterova, I.P.; Vaisova, M.; Turabov, N.; Kurbanov, Sh.A. [Tashkent State Univ. (Russian Federation)

1994-03-20T23:59:59.000Z

204

Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications  

DOE Patents (OSTI)

A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.

Gay, McMahan; Choi, Sunho; Jones, Christopher W

2014-09-16T23:59:59.000Z

205

Regenerable MgO-based sorbent for high temperature CO2 removal from syngas: 3. CO2 capture and sorbent enhanced water gas shift reaction  

Science Journals Connector (OSTI)

Abstract Regenerable MgO-based sorbent, which was prepared and evaluated in the thermogravimetric analyzer (TGA) in part 1, was also evaluated in high-pressure packed-bed unit in CO2/N2/H2O mixture and simulated pre-combustion syngas environment. In CO2/N2/H2O environment, the CO2 absorption capacity of the sorbent increases with increasing temperatures from 6.7% at 350 °C to 9.5% 450 °C. The sorbent is capable of achieving over 95% CO2 capture and 40% conversion in the water gas shift (WGS) reaction, which should be attributed to positive effect of WGS reaction in producing CO2 during the process. The sorbent reactivity and absorption capacity toward CO2, as well as its WGS catalytic activity decreases with increasing temperature. The maximum pre-breakthrough WGS conversion occurs at 350 °C, which diminishes as the sorbent is carbonated. The variable diffusivity shrinking core reaction model coupled with the two-fluid computational fluid dynamics (CFD) model was shown to accurately predict the break-through gas compositions at different operating conditions.

Emadoddin Abbasi; Armin Hassanzadeh; Shahin Zarghami; Hamid Arastoopour; Javad Abbasian

2014-01-01T23:59:59.000Z

206

Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer to Commercialization Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer to Commercialization March 23, 2011 - 1:00pm Addthis Washington, DC - Two new patented sorbents used for carbon dioxide (CO2) capture from coal-based power plants have moved closer to commercialization as a result of a licensing agreement between the Office of Fossil Energy's (FE) National Energy Technology Laboratory (NETL) and ADA Environmental Solutions (ADA-ES). The nonexclusive agreement facilitates negotiations on intellectual property rights, protects proprietary information, and grants non-exclusive licensing of the new technology. Under federal regulations, NETL is authorized to obtain, maintain, and own patent protection for its

207

Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer to Commercialization Licensing Agreement Moves Two NETL-Patented Carbon Capture Sorbents Closer to Commercialization March 23, 2011 - 1:00pm Addthis Washington, DC - Two new patented sorbents used for carbon dioxide (CO2) capture from coal-based power plants have moved closer to commercialization as a result of a licensing agreement between the Office of Fossil Energy's (FE) National Energy Technology Laboratory (NETL) and ADA Environmental Solutions (ADA-ES). The nonexclusive agreement facilitates negotiations on intellectual property rights, protects proprietary information, and grants non-exclusive licensing of the new technology. Under federal regulations, NETL is authorized to obtain, maintain, and own patent protection for its

208

Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

develop a low-cost, high-capacity expendable sorbent to remove both sulfur species in biogas to ppb levels, making its use possible in a fuel cell CHP unit The high...

209

Analysis of Hydroxide Sorbents for CO2 Capture from Warm Syngas  

Science Journals Connector (OSTI)

Analysis of Hydroxide Sorbents for CO2 Capture from Warm Syngas ... (1, 2) However, conventional coal combustion releases large amounts of the greenhouse gas CO2 into the atmosphere. ...

David J. Couling; Ujjal Das; William H. Green

2012-09-04T23:59:59.000Z

210

Zinc-oxide-based sorbents and processes for preparing and using same  

DOE Patents (OSTI)

Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasael (Durham, NC)

2010-03-23T23:59:59.000Z

211

Theoretical Predictions of the thermodynamic Properties of Solid Sorbents Capture CO2 Applications  

SciTech Connect

We are establishing a theoretical procedure to identify most potential candidates of CO{sub 2} solid sorbents from a large solid material databank to meet the DOE programmatic goal for energy conversion; and to explore the optimal working conditions for the promising CO{sub 2} solid sorbents, especially from room to warm T ranges with optimal energy usage, used for both pre- and post-combustion capture technologies.

Duan, Yuhua; Sorescu, Dan; Luebke David; Pennline, Henry

2012-05-02T23:59:59.000Z

212

NETL: Pilot Testing of a Highly Effective Pre-Combustion Sorbent-Based  

NLE Websites -- All DOE Office Websites (Extended Search)

Pilot Testing of a Highly Effective Pre-Combustion Sorbent-Based Carbon Capture System Pilot Testing of a Highly Effective Pre-Combustion Sorbent-Based Carbon Capture System Project No.: DE-FE0013105 TDA is developing a new sorbent-based pre-combustion carbon capture technology for integrated gasification combined cycle (IGCC) power plants. The process, which was evaluated at bench-scale under a previous effort, uses an advanced physical adsorbent that selectively removes CO2 from coal derived synthesis gas (syngas) above the dew point of the gas. The sorbent consists of a mesoporous carbon grafted with surface functional groups that remove CO2 via an acid-base interaction. The reactor design will be optimized by using computational fluid dynamics and adsorption modeling to improve the pressure swing adsorption cycle sequence. The research will include: two 0.1 MWe tests with a fully-equipped prototype unit using actual synthesis gas to prove the viability of the new technology; long-term sorbent life evaluation in a bench-scale setup of 20,000 cycles; the fabrication of a pilot-scale testing unit that will contain eight sorbent reactors; and the design of a CO2 purification sub-system. The CO2 removal technology will significantly improve (3 to 4 percent) the IGCC process efficiency needed for economically viable production of power from coal.

213

Novel Sorbent-Based Process for High Temperature Trace Metal Removal  

SciTech Connect

The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

Gokhan Alptekin

2008-09-30T23:59:59.000Z

214

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

combustion system includes "micro" stratified charge capability Air Flow & Air Fuel Spatial & Temporal Evolution "Micro" Stratified Charge * Overall Lean Homogeneous * Early...

215

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Company proposed a 4 year project addressing the solicitation from the Department of Energy Recovery Act - Systems Level Technology Development, Integration, and Demonstration...

216

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace065rinkevich2011...

217

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace065weaver2012...

218

Development of Novel Sorbents for Uranium Extraction from Seawater  

SciTech Connect

As the uranium resource in terrestrial ores is limited, it is difficult to ensure a long-term sustainable nuclear energy technology. The oceans contain approximately 4.5 billion tons of uranium, which is one thousand times the amount of uranium in terrestrial ores. Development of technologies to recover the uranium from seawater would greatly improve the uranium resource availability, sustaining the fuel supply for nuclear energy. Several methods have been previously evaluated including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons such as cost effectiveness, long term stability, and selectivity. Recent research has focused on the amidoxime functional group as a promising candidate for uranium sorption. Polymer beads and fibers have been functionalized with amidoxime functional groups, and uranium adsorption capacities as high as 1.5 g U/kg adsorbent have recently been reported with these types of materials. As uranium concentration in seawater is only ~3 ppb, great improvements to uranium collection systems must be made in order to make uranium extraction from seawater economically feasible. This proposed research intends to develop transformative technologies for economic uranium extraction from seawater. The Lin group will design advanced porous supports by taking advantage of recent breakthroughs in nanoscience and nanotechnology and incorporate high densities of well-designed chelators into such nanoporous supports to allow selective and efficient binding of uranyl ions from seawater. Several classes of nanoporous materials, including mesoporous silica nanoparticles (MSNs), mesoporous carbon nanoparticles (MCNs), meta-organic frameworks (MOFs), and covalent-organic frameworks (COFs), will be synthesized. Selective uranium-binding liagnds such as amidoxime will be incorporated into the nanoporous materials to afford a new generation of sorbent materials that will be evaluated for their uranium extraction efficiency. The initial testing of these materials for uranium binding will be carried out in the Lin group, but more detailed sorption studies will be carried out by Dr. Taylor-Pashow of Savannah River National Laboratory in order to obtain quantitative uranyl sorption selectivity and kinetics data for the proposed materials. The proposed nanostructured sorbent materials are expected to have higher binding capacities, enhanced extraction kinetics, optimal stripping efficiency for uranyl ions, and enhanced mechanical and chemical stabilities. This transformative research will significantly impact uranium extraction from seawater as well as benefit DOE’s efforts on environmental remediation by developing new materials and providing knowledge for enriching and sequestering ultralow concentrations of other metals.

Lin, Wenbin; Taylor-Pashow, Kathryn

2014-01-08T23:59:59.000Z

219

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70 in mass% of chalcogel), dissolved into dimethyl sulfoxide, and dropped into deionized water to form pellets of a porous PAN-chalcogel hybrid material. Pellets of these hybrid sorbents, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to adsorb iodine gas under both concentrated and dilute conditions. Both the SnSp and SnSg chalcogels showed very high maximum iodine loadings at 67.2 and 68.3 mass%. The maximum iodine loadings in the SnS33 and SnS50 were high at 32.8 and 53.5 mass%. In all cases, X-ray diffraction results showed the formation of Sn-I phases of SnI4 and SnI4(S8)2 revealing that the iodine binding in these materials is mainly due to a chemisorption process although some evidence also exists that supports a physisorption process.

Riley, Brian J.; Pierce, David A.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Garn, Troy; Law, Jack; Kanatzidis, Mercouri G.

2014-04-16T23:59:59.000Z

220

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70; # = mass% of chalcogel), dissolved in dimethyl sulfoxide, and added dropwise to deionized water to form pellets of a porous PAN-chalcogel hybrid material. These pellets, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to capture iodine gas under both dynamic (dilute) and static (concentrated) conditions. Both SnSp and SnSg chalcogels showed very high iodine loadings at 67.2 and 68.3 mass%, respectively. The SnS50 hybrid sorbent demonstrated a high, although slightly reduced, maximum iodine loading (53.5 mass%) with greatly improved mechanical rigidity. In all cases, X-ray diffraction results showed the formation of crystalline SnI4 and SnI4(S8)2, revealing that the iodine binding in these materials is mainly due to a chemisorption process, although a small amount of physisorption was observed.

Brian J. Riley; David A. Pierce; Jaehun Chun; Josef Matyas; William C. Lepry; Troy G. Garn; Jack D. Law; Mercouri G. Kanatzidis

2014-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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221

Fluidized bed injection assembly for coal gasification  

DOE Patents (OSTI)

A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

1981-01-01T23:59:59.000Z

222

NETL: A Low-Cost, High-Capacity Regenerable Sorbent for CO2 Capture From  

NLE Websites -- All DOE Office Websites (Extended Search)

A Low Cost, High Capacity Regenerable Sorbent for CO2 Capture from Existing Coal-Fired Power Plants A Low Cost, High Capacity Regenerable Sorbent for CO2 Capture from Existing Coal-Fired Power Plants Project No.: DE-FE0007580 TDA Research, Inc is developing a low cost, high capacity CO2 adsorbent and demonstrating its technical and economic viability for post-combustion CO2 capture for existing pulverized coal-fired power plants. TDA is using an advanced physical adsorbent to selectively remove CO2 from flue gas. The sorbent exhibits a much higher affinity to adsorb CO2 than N2, H2O or O2, enabling effective CO2 separation from the flue gas. The sorbent binds CO2 more strongly than common adsorbents, providing the chemical potential needed to remove the CO2, however, because CO2 does not form a true covalent bond with the surface sites, regeneration can be carried out with only a small energy input. The heat input to regenerate the sorbent is only 4.9 kcal per mol of CO2, which is much lower than that for chemical absorbents or amine based solvents.

223

Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994  

SciTech Connect

The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

Hepworth, M.T.; Slimane, R.B.

1994-11-01T23:59:59.000Z

224

Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors  

SciTech Connect

The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

1980-09-01T23:59:59.000Z

225

Theoretical Screening of Solid Sorbents for CO{sub 2} Capture Applications  

SciTech Connect

The work reported in this presentation was establishing a theoretical procedure to identify most potential candidates of CO{sub 2} solid sorbents from a large solid material databank; and to explore the optimal working conditions for the promised CO{sub 2} solid sorbents and provide guidelines to the experimentalists. Our methodology can predict thermodynamic properties of solid materials and their CO{sub 2} capture reactions. Single solid may not satisfy the industrial operating conditions as CO{sub 2} sorbent, however, by mixing two or more solids, the new formed solid may satisfy the industrial needs. By exploring series of lithium silicates with different Li{sub 2}O/SiO{sub 2} ratio, we found that with decreasing Li{sub 2}O/SiO{sub 2} ratio the corresponding silicate has a lower turnover temperature and vice versa. Compared to pure MgO, the Na{sub 2}CO{sub 3}, K{sub 2}CO{sub 3} and CaCO{sub 3} promoted MgO sorbent has a higher turnover T. These results provide guidelines to synthesize sorbent materials by mixing different solids with different ratio.

Duan, Y [NETL

2013-08-07T23:59:59.000Z

226

Novel regenerable magnesium hydroxide sorbents for CO2 capture at warm gas temperatures  

SciTech Connect

A novel sorbent consisting of Mg(OH)2 was developed for carbon dioxide (CO2) capture at 200-315 °C suitable for CO2 capture applications such as coal gasification systems. Thermodynamic analysis conducted with the FactSage software package indicated that the Mg(OH)2 sorbent system is highly favorable for CO2 capture up to 400 °C at 30 atm. MgCO3 formed during sorption decomposes to release CO2 at temperatures as low as 375 °C up to 20 atm. MgO rehydroxylation to form Mg(OH)2 is possible at temperatures up to 300 °C at 20 atm. The experimental data show that the sorbent is regenerable at 375 °C at high pressure and that steam does not affect the sorbent performance. A multicycle test conducted in a high-pressure fixed-bed flow reactor at 200 °C with 28% CO2 showed stable reactivity during the cyclic tests. The capture capacity also increased with increasing pressure. The sorbent is unique because it exhibits a high CO2 capture capacity of more than 3 mol/kg at 200 °C and also is regenerable at a low temperature of 375 °C and high pressure. High-pressure regeneration is advantageous because the CO2 compression costs required for sequestration can be reduced.

Siriwardane, R.; Stevens, R.

2009-01-01T23:59:59.000Z

227

Study Reveals Fuel Injection Timing Impact on Particle Number...  

NLE Websites -- All DOE Office Websites (Extended Search)

increasingly turning to gasoline direct injection (GDI) coupled with turbocharging as a cost-effective option for improving the efficiency and performance of gasoline engines....

228

Current Injection Spiral-Shaped Chaotic Microcavity Quantum Cascade Lasers  

Science Journals Connector (OSTI)

We report room temperature operation of current-injection quantum cascade lasers with spiral-shaped chaotic microresonators, capable of directional, single mode emission, operating...

Belkin, Mikhail A; Audet, Ross M; Fan, Jonathan A; Capasso, Federico; Narimanov, Evgenii; Bour, D; Corzine, S; Zhu, J; Höfler, G

229

Rich catalytic injection  

DOE Patents (OSTI)

A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

Veninger, Albert (Coventry, CT)

2008-12-30T23:59:59.000Z

230

Partially Sulfated Lime-Fly Ash Sorbents Activated by Water or Steam for SO2 Removal at a Medium Temperature  

Science Journals Connector (OSTI)

Partially Sulfated Lime-Fly Ash Sorbents Activated by Water or Steam for SO2 Removal at a Medium Temperature ... The low utilization of calcium-based sorbent is caused by the formation of calcium sulfite or sulfate, which have larger molar volumes than CaO or Ca(OH)2. ... ignition?loss ...

Liming Shi; Xuchang Xu

2005-08-23T23:59:59.000Z

231

CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents  

SciTech Connect

The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

2012-08-31T23:59:59.000Z

232

Stabilization of spent sorbents from coal gasification. Final technical report, September 1, 1992--August 31, 1993  

SciTech Connect

The objective of this investigation was to determine the rates of reactions involving partially sulfided dolomite and oxygen, which is needed for the design of the reactor system for the stabilization of sulfide-containing solid wastes from gasification of high sulfur coals. To achieve this objective, samples of partially sulfided dolomite were reacted with oxygen at a variety of operating conditions in a fluidized-bed reactor. The effect of external diffusion was eliminated by using small quantities of the sorbent and maintaining a high flow rate of the reactant gas. The reacted sorbents were analyzed to determine the extent of conversion as a function of operating variables including sorbent particle size, reaction temperature and pressure, and oxygen concentration. The results of sulfation tests indicate that the rate of reaction increases with increasing temperature, increasing oxygen partial pressure, and decreasing sorbent particle size. The rate of the sulfation reaction can be described by a diffuse interface model where both chemical reaction and intraparticle diffusion control the reaction rate. The kinetic model of the sulfation reaction was used to determine the requirements for the reactor system, i.e., reactor size and operating conditions, for successful stabilization of sulfide-containing solid wastes from gasification of high sulfur coals (with in-bed desulfurization using calcium based sorbents). The results indicate that the rate of reaction is fast enough to allow essentially complete sulfation in reactors with acceptable dimensions. The optimum sulfation temperature appears to be around 800{degrees}C for high pressure as well as atmospheric stabilization of the spent sorbents.

Abbasian, J.; Hill, A.H.; Rue, D.M.; Wangerow, J.R. [Institute of Gas Technology, Chicago, IL (United States)

1993-12-31T23:59:59.000Z

233

DEVELOPMENT OF A HYDROGEN MORDENITE SORBENT FOR THE CAPTURE OF KRYPTON FROM USED NUCLEAR FUEL REPROCESSING OFF-GAS STREAMS  

SciTech Connect

A novel new sorbent for the separation of krypton from off-gas streams resulting from the reprocessing of used nuclear fuel has been developed and evaluated. A hydrogen mordenite powder was successfully incorporated into a macroporous polymer binder and formed into spherical beads. The engineered form sorbent retained the characteristic surface area and microporosity indicative of mordenite powder. The sorbent was evaluated for krypton adsorption capacities utilizing thermal swing operations achieving capacities of 100 mmol of krypton per kilogram of sorbent at a temperature of 191 K. A krypton adsorption isotherm was also obtained at 191 K with varying krypton feed gas concentrations. Adsorption/desorption cycling effects were also evaluated with results indicating that the sorbent experienced no decrease in krypton capacity throughout testing.

Mitchell Greenhalgh; Troy G. Garn; Jack D. Law

2014-04-01T23:59:59.000Z

234

Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams  

DOE Patents (OSTI)

A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

Siriwardane, Ranjani V. (Morgantown, WV)

2008-01-01T23:59:59.000Z

235

High-Performance Sorbents for Carbon Dioxide Capture from Air  

SciTech Connect

This project has focused on capture of CO{sub 2} from ambient air (“air capture”). If this process is technically and economically feasible, it could potentially contribute to net reduction of CO{sub 2} emissions in ways that are complementary to better developed techniques for CO{sub 2} from concentrated point sources. We focused on cyclic adsorption processes for CO{sub 2} capture from air in which the entire cycle is performed at moderate temperatures. The project involved both experimental studies of sorbent materials and process level modeling of cyclic air capture processes. In our experimental work, a series of amine-functionalized silica adsorbents were prepared and characterized to determine the impact of molecular architecture on CO{sub 2} capture. Some key findings were: • Amine functionalized silicas can be prepared with high enough CO{sub 2} capacities under ambient conditions to merit consideration for use in air capture processes. • Primary amines are better candidates for CO{sub 2} capture than secondary or tertiary amines, both in terms of amine efficiency for CO{sub 2} adsorption and enhanced water affinity. • Mechanistic understanding of degradation of these materials can enable control of molecular architecture to significantly improve material stability. Our process modeling work provided the first publically available cost and energy estimates for cyclic adsorption processes for air capture of CO{sub 2}. Some key findings were: • Cycles based on diurnal ambient heating and cooling cannot yield useful purities or amounts of captured CO{sub 2}. • Cycles based on steam desorption at 110 oC can yield CO{sub 2} purities of ~88%. • The energy requirements for cycles using steam desorption are dominated by needs for thermal input, which results in lower costs than energy input in the form of electricity. Cyclic processes with operational costs of less than $100 tCO{sub 2}-net were described, and these results point to process and material improvements that could substantially reduce these costs. The most critical conclusions from our work are that (i) CO{sub 2} capture from ambient air using moderate temperature cyclic adsorption processes is technically feasible and (ii) the operational costs of realistic versions of these processes are moderate enough to encourage future development of this technology. Because of the very modest net investment that has been made in R&D associated with this approach from all sources worldwide (relative to the massive public and private investment that has been made in technologies for CO{sub 2} from concentrated point sources), our results strongly suggest that continued development of air capture is justified.

Sholl, David; Jones, Christopher

2013-03-13T23:59:59.000Z

236

Long-Term Carbon Injection Field Test for 90% Mercury Removal for a PRB Unit a Spray Dryer and Fabric Filter  

SciTech Connect

The power industry in the U.S. is faced with meeting regulations to reduce the emissions of mercury compounds from coal-fired plants. Injecting a sorbent such as powdered activated carbon (PAC) into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. The purpose of this test program was to evaluate the long-term mercury removal capability, long-term mercury emissions variability, and operating and maintenance (O&M) costs associated with sorbent injection on a configuration being considered for many new plants. Testing was conducted by ADA Environmental Solutions (ADA) at Rocky Mountain Power’s (RMP) Hardin Station through funding provided by DOE/NETL, RMP, and other industry partners. The Hardin Station is a new plant rated at 121 MW gross that was first brought online in April of 2006. Hardin fires a Powder River Basin (PRB) coal and is configured with selective catalytic reduction (SCR) for NOx control, a spray dryer absorber (SDA) for SO2 control, and a fabric filter (FF) for particulate control. Based upon previous testing at PRB sites with SCRs, very little additional mercury oxidation from the SCR was expected at Hardin. In addition, based upon results from DOE/NETL Phase II Round I testing at Holcomb Station and results from similarly configured sites, low native mercury removal was expected across the SDA and FF. The main goal of this project was met—sorbent injection was used to economically and effectively achieve 90% mercury control as measured from the air heater (AH) outlet to the stack for a period of ten months. This goal was achieved with DARCO® Hg-LH, Calgon FLUEPAC®-MC PLUS and ADA Power PAC PREMIUM brominated activated carbons at nominal loadings of 1.5–2.5 lb/MMacf. An economic analysis determined the twenty-year levelized cost to be 0.87 mills/kW-hr, or $15,000/lb Hg removed. No detrimental effects on other equipment or plant operations were observed. The results of this project also filled a data gap for plants firing PRB coal and configured with an SCR, SDA, and FF, as many new plants are being designed today. Another goal of the project was to evaluate, on a short-term basis, the mercury removal associated with coal additives and coal blending with western bituminous coal. The additive test showed that, at this site, the coal additive known as KNX was affective at increasing mercury removal while decreasing sorbent usage. Coal blending was conducted with two different western bituminous coals, and West Elk coal increased native capture from nominally 10% to 50%. Two additional co-benefits were discovered at this site. First, it was found that native capture increased from nominally 10% at full load to 50% at low load. The effect is believed to be due to an increase in mercury oxidation across the SCR caused by a corresponding decrease in ammonia injection when the plant reduces load. Less ammonia means more active oxidation sites in the SCR for the mercury. The second co-benefit was the finding that high ammonia concentrations can have a negative impact on mercury removal by powdered activated carbon. For a period of time, the plant operated with a high excess of ammonia injection necessitated by the plugging of one-third of the SCR. Under these conditions and at high load, the mercury control system could not maintain 90% removal even at the maximum feed rate of 3.5 lb/MMacf (pounds of mercury per million actual cubic feet). The plant was able to demonstrate that mercury removal was directly related to the ammonia injection rate in a series of tests where the ammonia rate was decreased, causing a corresponding increase in mercury removal. Also, after the SCR was refurbished and ammonia injection levels returned to normal, the mercury removal performance also returned to normal. Another goal of the project was to install a commercial-grade activated carbon injection (ACI) system and integrate it with new-generation continuous emissions monitors for mercury (Hg-CEMs) to allow automatic feedback control on outlet me

Sjostrom, Sharon; Amrhein, Jerry

2009-04-30T23:59:59.000Z

237

NETL: SO2-Resistent Immobilized Amine Sorbents for CO2 Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Post-Combustion CO2 Emissions Control Post-Combustion CO2 Emissions Control SO2-Resistent Immobilized Amine Sorbents for CO2 Capture Project No.: DE-FE0001780 DOE is partnering with the University of Akron (Akron) to conduct research and training to develop an effective solid amine sorbent for large scale post-combustion CO2 capture from power plant flue gas. Sorbent materials developed by Akron consist of immobilized carbon and hydrogen structures (paraffin) distributed inside of the amine pores and aromatic amines located on the external surface and the pore mouth of the sorbent. The immobilized paraffinic amines have been shown to display excellent CO2 capture capacity by adsorbing CO2 at temperatures below 55 °C and releasing it at temperatures between 80-120 °C. This effort will focus on increasing scientific understanding of the chemical and physical principles affecting amines deposited on a series of porous solids that generally have large pore space, high surface area, and/or high thermal conductivity.

238

Amino Acid-Functionalized Ionic Liquid Solid Sorbents for Post-Combustion Carbon Capture  

Science Journals Connector (OSTI)

Amino Acid-Functionalized Ionic Liquid Solid Sorbents for Post-Combustion Carbon Capture ... Amino acid ionic liquids (AAILs) are potential green substitutes of aqueous amine solutions for carbon dioxide (CO2) capture. ... However, the viscous nature of AAILs greatly hinders their further development in CO2 capture applications. ...

Xianfeng Wang; Novruz G. Akhmedov; Yuhua Duan; David Luebke; David Hopkinson; Bingyun Li

2013-08-08T23:59:59.000Z

239

Screening Evaluation of Alternate Sorbents and Methods for Strontium and Actinide Removal from Alkaline Salt Solution  

SciTech Connect

This report describes results from screening tests evaluating strontium and actinide removal characteristics of three different titanium-containing sorbents, crystalline silicotitanate (CST) manufactured by UPO, SrTreat(R) offered by Fortum Engineering, sodium nonatitanate developed by Clearfield and coworkers at Texas A and M University and offered commercially by Honeywell. We also report results from an alternate removal method, coprecipitation.

Hobbs, D.T.

2001-04-17T23:59:59.000Z

240

A Regenerable Calcium-Based Core-in-Shell Sorbent for Desulfurizing Hot Coal Gas  

Science Journals Connector (OSTI)

Other materials used in the sorbent formulations included reagent-grade calcium carbonate from the Fisher Co. and calcium sulfate hemihydrate obtained as commercial-grade plaster of Paris. ... Once coated, the pellets were allowed to tumble for 2.0 h to consolidate the coating. ...

T. T. Akiti, Jr.; K. P. Constant; L. K. Doraiswamy; T. D. Wheelock

2002-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage  

E-Print Network (OSTI)

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage Long Pan coordination structures represent a promising new entry to the field of hydrogen storage materials.2 To fully that effectively store hydrogen are needed for use in fuel cell powered vehicles. Among the various candidate

Li, Jing

242

Orthogonal ion injection apparatus and process  

DOE Patents (OSTI)

An orthogonal ion injection apparatus and process are described in which ions are directly injected into an ion guide orthogonal to the ion guide axis through an inlet opening located on a side of the ion guide. The end of the heated capillary is placed inside the ion guide such that the ions are directly injected into DC and RF fields inside the ion guide, which efficiently confines ions inside the ion guide. Liquid droplets created by the ionization source that are carried through the capillary into the ion guide are removed from the ion guide by a strong directional gas flow through an inlet opening on the opposite side of the ion guide. Strong DC and RF fields divert ions into the ion guide. In-guide orthogonal injection yields a noise level that is a factor of 1.5 to 2 lower than conventional inline injection known in the art. Signal intensities for low m/z ions are greater compared to convention inline injection under the same processing conditions.

Kurulugama, Ruwan T; Belov, Mikhail E

2014-04-15T23:59:59.000Z

243

Activated Carbon Injection  

ScienceCinema (OSTI)

History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

None

2014-07-22T23:59:59.000Z

244

Underground Injection Control (Louisiana)  

Energy.gov (U.S. Department of Energy (DOE))

The Injection and Mining Division (IMD) has the responsibility of implementing two major federal environmental programs which were statutorily charged to the Office of Conservation: the Underground...

245

NEUTRAL-BEAM INJECTION  

E-Print Network (OSTI)

energy, coming from an electron source, are injected intodischarges. In an electron bombardment source electrons ofsimply called electron bombardment sources (Kaufman, 1974).

Kunkel, W.B.

2012-01-01T23:59:59.000Z

246

Activated Carbon Injection  

SciTech Connect

History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

None

2014-07-16T23:59:59.000Z

247

Desulfurization behavior of iron-based sorbent with MgO and TiO{sub 2} additive in hot coal gas  

SciTech Connect

The sulfidation behaviors of iron-based sorbent with MgO and MgO-TiO{sub 2} are studied under different isothermal conditions from 623 to 873 K in a fixed bed reactor. The results of sorbents sulfidation experiments indicate that the sorbents with MgO and TiO{sub 2} additives are more attractive than those without additives for desulfurization of hot coal gas. The sulfur capacity (16.17, 18.45, and 19.68 g S/100 g sorbent) of M1F, M3F, and M5F sorbent containing 1, 3, and 5% MgO, respectively, is obviously bigger than that (15.02 g S/100 g sorbent) of M0F without additive. The feasible sulfidation temperature range for M3F sorbent is 773-873 K. The M3F sorbent is optimally regenerated at the temperature of 873 K, under the gas containing 2% oxygen, 15% steam and N{sub 2}, in the space velocity of 2500 h{sup -1}. The sorbent regenerated is also well performed in the second sulfidation (the effective sulfur capacities of 17.98 g S/100 g sorbents and the efficiency of removal sulfur of 99%). The capacity to remove sulfur decreases with steam content increasing in feeding gas from 0 to 10%, but it can restrain the formation of carbon and iron carbide. The addition of TiO{sub 2} in sorbent can shift the optimal sulfidation temperature lower. The iron-based sorbent with 3% MgO and 10% TiO{sub 2} (MFT) is active to the deep removal of H{sub 2}S and COS, especially in the temperature range of 673-723 K. The sulfur removal capacity of MFT sorbent is 21.60 g S/100 g sorbent. 16 refs., 12 figs., 8 tabs.

Weiren Bao; Zong-you Zhang; Xiu-rong Ren; Fan Li; Li-ping Chang [Taiyuan University of Technology, Taiyuan (China). Key Laboratory of Coal Science and Technology

2009-07-15T23:59:59.000Z

248

Cross-flow, filter-sorbent catalyst for particulate, SO sub 2 and NO sub x control  

SciTech Connect

This report describes work performed on a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particle filter, an SO {sub 2} sorbent, and a NO {sub x} reduction catalyst. One critical element of the R D program is the development of mixed metal oxide materials that serve as combined SO {sub 2} sorbents and NO {sub x} reduction catalysts. In this seventh quarterly progress report, we summarize the performance characteristics of three promising sorbent/catalyst materials tested in powder form.

Benedek, K. (Little (Arthur D.), Inc., Cambridge, MA (United States)); Flytzani-Stephanopoulos, M. (Massachusetts Inst. of Tech., Cambridge, MA (United States))

1992-01-01T23:59:59.000Z

249

Evaluation of Solid Sorbents as a Retrofit Technology for CO2 Capture from Coal-Fired Power Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Solid Sorbents as a Solid Sorbents as a Retrofit Technology for CO 2 Capture from Coal-fired Power Plants Background Retrofitting the current fleet of pulverized coal (PC)-fired power plants for the separation and sequestration of carbon dioxide (CO 2 ) is one of the most significant challenges for effective, long-term carbon management. Post-combustion CO 2 capture using solid-sorbent based technologies is a potential resolution to this challenge that could be appropriate for both new and existing PC-fired power plant

250

Novel sorbents for removal of gadolinium-based contrast agents in sorbent dialysis and hemoperfusion: preventive approaches to nephrogenic systemic fibrosis  

SciTech Connect

Gd based contrast agents in many forms of organocomplex have recently been linked to a debilitating and a potentially fatal skin disease called Nephrogenic Systemic Fibrosis (NSF) in patients with renal failures. Free Gd released from the complexes by transmetallation is believed to be the most important trigger for NSF. Removal of Gd complex from the patients immediately after the contrast study would prevent the dissociation of Gd and should eliminate NSF as a complication. Although removal of Gd based contrast agents may be accomplished with conventional hemodialysis, it requires three hemodialysis sessions at 3 hours each to remove 98% of the contrast agents. In this work, mesoporous silica material that are functionalized with 1-hydroxy-2-pyridinone (1,2-HOPO-SAMMS®) has been evaluated for effective removal of both free and chelated Gd (Magnevist, a brand of gadopentetate dimeglumine) from the dialysate and sodium chloride solution. The material has high affinity, rapid removal rate, and large sorption capacity for both free and chelated Gd, the properties that are far superior to those of activated carbon and zirconium phosphate currently used in the state-of-the-art sorbent dialysis systems. 99% of both free and chelated Gd would be removed in a single pass thru the sorbent bed of 1,2-HOPO-SAMMS®. The sorbent provides an effective and predicable strategy for removing Gd from patients with impaired renal function, thus it would allow for the continued use of contrast MRI while removing the risk of NSF and would represent a safe alternative to traditional contrast studies in the patient population.

Yantasee, Wassana; Fryxell, Glen E.; Porter, George A.; Pattamakomsan, Kanda; Sukwarotwat, Vichaya; Chouyyok, Wilaiwan; Koonsiripaiboon, View; Xu, Jide; Raymond, Kenneth N.

2010-02-01T23:59:59.000Z

251

A Study of the Zn-based Desulfurization Sorbents for H2S Removal in the IGCC  

Science Journals Connector (OSTI)

Recently, the possibility for the simultaneous removal of H2S and NH3...on the Zn–Ti-based sorbents has been tested by various researchers using several additives like Co, Ni, Fe, Mo and ... W. However, the resea...

Suk Yong Jung; Soo Chool Lee; Hee Kwon Jun; Jae Chang Kim

2013-06-01T23:59:59.000Z

252

Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride  

SciTech Connect

The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

1981-07-01T23:59:59.000Z

253

Boron nitride nanotubes as novel sorbent for solid-phase microextraction of polycyclic aromatic hydrocarbons in environmental water samples  

Science Journals Connector (OSTI)

Boron nitride nanotube (BNNT) is a novel material that shows potential ability in capturing organic pollutants. In this study, BNNTs fixed on a stainless steel fiber by a sol–gel technique were used as sorbent fo...

Meizhen Fu; Hanzhu Xing; Xiangfeng Chen…

2014-09-01T23:59:59.000Z

254

Regeneration of carboxylic acid-laden basic sorbents by leaching with a volatile base in an organic solvent  

DOE Patents (OSTI)

Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with an organic solution of alkylamine thus forming an alkylamine/carboxylic acid complex which is decomposed with improved efficiency to the desired carboxylic acid and the alkylamine. Carbon dioxide addition can be used to improve the adsorption or the carboxylic acids by the solid phase sorbent.

King, C. Judson (Kensington, CA); Husson, Scott M. (Berkeley, CA)

1999-01-01T23:59:59.000Z

255

Injection-Induced Earthquakes  

Science Journals Connector (OSTI)

...injected into the reservoir under high pressure...core samples of the reservoir rocks and in situ determination...fracture-dominated porosity of less than 6...Implications for reservoir fracture permeability . AAPG Bull. 93...

William L. Ellsworth

2013-07-12T23:59:59.000Z

256

Injection Laser System  

NLE Websites -- All DOE Office Websites (Extended Search)

Injection Laser System For each of NIF's 192 beams: The pulse shape as a function of time must be generated with a high degree of precision The energy delivered to the target must...

257

Assessment of sorbent reactivation by water hydration for fluidized bed combustion application  

SciTech Connect

Disposal of fluidized bed combustion (FBC) solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to its operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in situ sulfur removal. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely the bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40{sup o}C and 80{sup o}C and for curing times ranging from 15 minutes to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials

Fabio Montagnaro; Piero Salatino; Fabrizio Scala; Yinghai Wu; Edward J. Anthony; Lufei Jia [Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant'Angelo, Naples (Italy). Dipartimento di Chimica

2006-06-15T23:59:59.000Z

258

Proof of concept testing of an integrated dry injection system for SO{sub 2}/NO{sub x} control. Final report  

SciTech Connect

The integrated Dry Injection Process (IDIP) consists of combustion modification using low NO{sub x} burners to reduce NO{sub x} emissions, dry injection of hydrated line at economizer temperatures for primary capture of SO{sub 2}, dry injection of a commercial grade sodium bicarbonate at the air heater exit for additional SO{sub 2} and NO{sub x} removal, and humidification for precipitator conditioning. IDIP offers the potential for simultaneously achieving 90% SO{sub 2} removal, and 65% NO{sub x} removal from a high sulfur flue gas. The process is well suited for new or retrofit applications since it can be incorporated within existing economizer and downstream ductwork. Subscale tests were performed in order to identify the best calcium and sodium sorbents. These tests involved the injection of calcium hydroxide and sodium sorbents at various points of the flue gas system downstream of a 0.25 MM BTU/hr. coal fired combustor, and the gas residence times, cooling rates and temperatures were comparable to those found for full-scale utility boilers. These tests verified that a high surface area hydrated lime provides maximum sorbent utilization and identified an alcohol-water hydrated lime as yielding the highest surface area and the best SO{sub 2} removal capability. The tests also identified sodium bicarbonate to be somewhat more effective than sodium sesquicarbonate for SO{sub 2} removal. The proof of concept demonstration was conducted on the large combustor at the Riley Stoker Research Facility in Worcester, MA. When economically compared to conventional limestone slurry scrubbing on a 300 MW plant, the dry injection process shows lower capital cost but higher operating cost. Hydrated lime injection can be less costly than limestone scrubbing when two or more of the following conditions exist: plant is small (less than 100MW); yearly operating hours are small (less than 3000); and the remaining plant lifetime is small (less than 10 years).

Helfritch, D.J.; Bortz, S.J. [Research-Cottrell, Inc., Somerville, NJ (United States); Beittel, R. [Riley Stoker Corp., Worcester, MA (United States)

1994-03-01T23:59:59.000Z

259

CO2 Capture from Flue Gas Using SOlid Molecular Basket Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

from Flue Gas Using Solid from Flue Gas Using Solid Molecular Basket Sorbents Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-

260

XAFS Investigation of Mercury Sorption on Carbon-based and Other Sorbent Materials  

Science Journals Connector (OSTI)

The sorption of mercury from simulated coal combustion flue gases on coal-derived chars, activated carbons, and zeolites has been examined using mercury LIII XAFS spectroscopy. The energy difference between the two inflection points (IPD) in the mercury XANES spectra has been shown to be a sensitive indicator of the local structure around the mercury adsorbed on the sorbent. The value of the IPD appears to reflect the form of mercury added to the flue gas and to be sensitive to acidic gaseous species such as HCl and H2SO4 that may be present in the flue gas, whether from addition to the flue gas or from the sulfur and chlorine in the coal. The data suggest that well-defined mercury species are not formed on carbon-based sorbents, but rather the structure and chemistry of the sorbed mercury species reflect the different anionic species present in the flue gas, as well as any activating element on the sorbent itself.

Frank E. Huggins; Nora Yap; Gerald P. Huffman

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, [April--June 1995  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. The present study aims to determine the effects of ammonia on the sulfation of the sorbent and to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents. In this quarter runs for methane regeneration were completed. The data obtained were evaluated and interpreted. When the sulfated sorbent was regenerated with methane coke formation on the sorbent was observed. Treatment of fresh sorbent with methane also resulted in coking. Coke formed on the sorbent disappeared very rapidly after the methane flow was replaced with nitrogen. The order of the regeneration reaction with respect to methane was estimated as 0:76 and the activation energy of the reaction was estimated as 130 kJ/mol. During repeated sulfation-regeneration cycles the decrease in the sulfur capacity after the first cycle was slightly more when regeneration was done with methane compared to that observed with hydrogen regeneration. In the subsequent 4 cycles, the ceria sorbent preserved its sulfur capacity. The regenerated sorbent was able to capture 1.5 sulfur atoms per cerium atom in less than an hour of sulfation, compared to S/Ce of 2.5 for fresh sorbents and 2 for sorbents regenerated with hydrogen.

Akyurtlu, A.; Akyurtlu, J.F.

1995-07-01T23:59:59.000Z

262

Optimization of Injection Scheduling in  

E-Print Network (OSTI)

SGP-TR-I12 Optimization of Injection Scheduling in Geothermal Fields James Lovekin May 1987&injection optimization problem is broke$ into two subpmbkm:(1) choosing a configuration of injectorsfrom an existing set is defined as the fieldwide break- through lindex, B. Injection is optimized by choosing injection wells

Stanford University

263

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines...

264

Replenishing data descriptors in a DMA injection FIFO buffer  

DOE Patents (OSTI)

Methods, apparatus, and products are disclosed for replenishing data descriptors in a Direct Memory Access (`DMA`) injection first-in-first-out (`FIFO`) buffer that include: determining, by a messaging module on an origin compute node, whether a number of data descriptors in a DMA injection FIFO buffer exceeds a predetermined threshold, each data descriptor specifying an application message for transmission to a target compute node; queuing, by the messaging module, a plurality of new data descriptors in a pending descriptor queue if the number of the data descriptors in the DMA injection FIFO buffer exceeds the predetermined threshold; establishing, by the messaging module, interrupt criteria that specify when to replenish the injection FIFO buffer with the plurality of new data descriptors in the pending descriptor queue; and injecting, by the messaging module, the plurality of new data descriptors into the injection FIFO buffer in dependence upon the interrupt criteria.

Archer, Charles J. (Rochester, MN); Blocksome, Michael A. (Rochester, MN); Cernohous, Bob R. (Rochester, MN); Heidelberger, Philip (Cortlandt Manor, NY); Kumar, Sameer (White Plains, NY); Parker, Jeffrey J. (Rochester, MN)

2011-10-11T23:59:59.000Z

265

Theoretical calculating the thermodynamic properties of solid sorbents for CO{sub 2} capture applications  

SciTech Connect

Since current technologies for capturing CO{sub 2} to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO{sub 2} sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO{sub 2} capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we first introduce our screening methodology and the results on a testing set of solids with known thermodynamic properties to validate our methodology. Then, by applying our computational method to several different kinds of solid systems, we demonstrate that our methodology can predict the useful information to help developing CO{sub 2} capture Technologies.

Duan, Yuhua

2012-11-02T23:59:59.000Z

266

Theoretical Screening of Mixed Solid Sorbent for Applications to CO{sub 2} Capture Technology  

SciTech Connect

Since current technologies for capturing CO{sub 2} to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO{sub 2} sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO{sub 2} capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we apply our screening methodology to mixing solid systems to adjust the turnover temperature to help on developing CO{sub 2} capture Technologies.

Duan, Yuhua

2014-03-30T23:59:59.000Z

267

Pressurized feed-injection spray-forming apparatus  

DOE Patents (OSTI)

A spray apparatus and method for injecting a heated, pressurized liquid in a first predetermined direction into a pressurized gas flow that is flowing in a second predetermined direction, to provide for atomizing and admixing the liquid with the gas to form a two-phase mixture. A valve is also disposed within the injected liquid conduit to provide for a pulsed injection of the liquid and timed deposit of the atomized gas phase. Preferred embodiments include multiple liquid feed ports and reservoirs to provide for multiphase mixtures of metals, ceramics, and polymers.

Berry, Ray A. (Idaho Falls, ID); Fincke, James R. (Idaho Falls, ID); McHugh, Kevin M. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

268

Pressurized feed-injection spray-forming apparatus  

DOE Patents (OSTI)

A spray apparatus and method are disclosed for injecting a heated, pressurized liquid in a first predetermined direction into a pressurized gas flow that is flowing in a second predetermined direction, to provide for atomizing and admixing the liquid with the gas to form a two-phase mixture. A valve is also disposed within the injected liquid conduit to provide for a pulsed injection of the liquid and timed deposit of the atomized gas phase. Preferred embodiments include multiple liquid feed ports and reservoirs to provide for multiphase mixtures of metals, ceramics, and polymers. 22 figs.

Berry, R.A.; Fincke, J.R.; McHugh, K.M.

1995-08-29T23:59:59.000Z

269

An attrition-resistant zinc titanate sorbent for sulfur. Final technical report, September 1, 1992--August 31, 1993  

SciTech Connect

In the continuing search for good sorbent materials to remove sulfur for hot, coal-derived gases, zinc titanate sorbents have shown great promise. The objective of this project was to extend the work of prior investigators by developing improvements in the compressive strength and, therefore, the cycle life of these sorbents while maintaining good chemical reactivity. Fifteen formulations were prepared and evaluated. The best properties were obtained by blending relatively course (two micron) ZnO and TiO{sub 2} powders to obtain a composition of 50%Zn{sub 2}TiO{sub 4}-50%TiO{sub 2}. When sintered at 1000{degrees}C, it had a compressive strength of 28 MPa or 147 N/mm, which is four times higher than values obtained by prior investigators. It also performed well in thermogravimetric analysis measurements of reactivity, both in screening tests and in simulated coal gas.

Swisher, J.H. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes

1993-12-31T23:59:59.000Z

270

Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode  

SciTech Connect

Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

2012-07-01T23:59:59.000Z

271

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents (OSTI)

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

272

LONG-TERM DEMONSTRATION OF SORBENT ENHANCEMENT ADDITIVE TECHNOLOGY FOR MERCURY CONTROL  

SciTech Connect

Long-term demonstration tests of advanced sorbent enhancement additive (SEA) technologies have been completed at five coal-fired power plants. The targeted removal rate was 90% from baseline conditions at all five stations. The plants included Hawthorn Unit 5, Mill Creek Unit 4, San Miguel Unit 1, Centralia Unit 2, and Hoot Lake Unit 2. The materials tested included powdered activated carbon, treated carbon, scrubber additives, and SEAs. In only one case (San Miguel) was >90% removal not attainable. The reemission of mercury from the scrubber at this facility prevented >90% capture.

Jason D. Laumb; Dennis L. Laudal; Grant E. Dunham; John P. Kay; Christopher L. Martin; Jeffrey S. Thompson; Nicholas B. Lentz; Alexander Azenkeng; Kevin C. Galbreath; Lucinda L. Hamre

2011-05-27T23:59:59.000Z

273

Theoretical Screening of Solid Sorbents for CO{sub 2} Capture  

SciTech Connect

By combining thermodynamic database searches with density functional theory and lattice phonon dynamics, a screening methodology was developed to identify promising solid sorbent candidates for CO{sub 2} capture. This methodology has been used to screen hundreds of solid compounds and some of the promising candidates to date have been reported in literature. This screening methodology is particularly relevant for the case of materials for which experimental thermodynamic data is not available. Such areas of interest are represented by the case of solid mixtures and doped materials, where thermodynamic data are generally not available but for which the crystallographic structure is known or can be easily determined.

Duan, Y [NETL; Sorescu, D C [NETL; Luebke, D [NETL; Morreale, B [NETL; Li, B Y; Zhang, B; Johnson, J K; Zhang, K; Li, X S; King, D

2013-04-11T23:59:59.000Z

274

Injection-controlled laser resonator  

DOE Patents (OSTI)

A new injection-controlled laser resonator incorporates self-filtering and self-imaging characteristics with an efficient injection scheme. A low-divergence laser signal is injected into the resonator, which enables the injection signal to be converted to the desired resonator modes before the main laser pulse starts. This injection technique and resonator design enable the laser cavity to improve the quality of the injection signal through self-filtering before the main laser pulse starts. The self-imaging property of the present resonator reduces the cavity induced diffraction effects and, in turn, improves the laser beam quality. 5 figs.

Chang, J.J.

1995-07-18T23:59:59.000Z

275

Development of a Dry Sorbent-Based Post Combustion CO2 Capture Technology for Retrofit in Existing Power Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Dry Sorbent-Based Dry Sorbent-Based Post Combustion CO 2 Capture Technology for Retrofit in Existing Power Plants Background Currently available commercial processes to remove carbon dioxide (CO 2 ) from flue gas streams are costly and energy intensive. RTI International is heading a research team to continue development and scale-up of an innovative process for CO 2 capture that has significant potential to be less expensive and less energy intensive than conventional technologies. The "Dry Carbonate Process" utilizes a dry,

276

Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas  

SciTech Connect

Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

2010-01-01T23:59:59.000Z

277

Sorption kinetics for phenol and nitro-substituted toxic phenols from aqueous solution using clay as sorbent material  

Science Journals Connector (OSTI)

This study examined the effectiveness of less-expensive sorbent clay in removing phenols from wastewater by sorption. Batch kinetic experiment showed that phenol and nitro-substituted phenols (o-, m- and p-) sorption on clay was rapid and equilibrium was achieved within 2 h. The kinetics of sorption was found to be of pseudo-second order reaction. The influences of various factors, such as particle size, pH, concentration and temperature on the sorption capacity have been studied. This study showed that clay could be used as an efficient sorbent material for the sorption of phenols from aqueous solution.

Preeti Sagar Nayak; B.K. Singh

2010-01-01T23:59:59.000Z

278

Multi-phase CFD modeling of solid sorbent carbon capture system  

SciTech Connect

Computational fluid dynamics (CFD) simulations are used to investigate a low temperature post-combustion carbon capture reactor. The CFD models are based on a small scale solid sorbent carbon capture reactor design from ADA-ES and Southern Company. The reactor is a fluidized bed design based on a silica-supported amine sorbent. CFD models using both Eulerian–Eulerian and Eulerian–Lagrangian multi-phase modeling methods are developed to investigate the hydrodynamics and adsorption of carbon dioxide in the reactor. Models developed in both FLUENT® and BARRACUDA are presented to explore the strengths and weaknesses of state of the art CFD codes for modeling multi-phase carbon capture reactors. The results of the simulations show that the FLUENT® Eulerian–Lagrangian simulations (DDPM) are unstable for the given reactor design; while the BARRACUDA Eulerian–Lagrangian model is able to simulate the system given appropriate simplifying assumptions. FLUENT® Eulerian–Eulerian simulations also provide a stable solution for the carbon capture reactor given the appropriate simplifying assumptions.

Ryan, E. M.; DeCroix, D.; Breault, Ronald W. [U.S. DOE; Xu, W.; Huckaby, E. David [U.S. DOE

2013-01-01T23:59:59.000Z

279

Multi-Phase CFD Modeling of Solid Sorbent Carbon Capture System  

SciTech Connect

Computational fluid dynamics (CFD) simulations are used to investigate a low temperature post-combustion carbon capture reactor. The CFD models are based on a small scale solid sorbent carbon capture reactor design from ADA-ES and Southern Company. The reactor is a fluidized bed design based on a silica-supported amine sorbent. CFD models using both Eulerian-Eulerian and Eulerian-Lagrangian multi-phase modeling methods are developed to investigate the hydrodynamics and adsorption of carbon dioxide in the reactor. Models developed in both FLUENT® and BARRACUDA are presented to explore the strengths and weaknesses of state of the art CFD codes for modeling multi-phase carbon capture reactors. The results of the simulations show that the FLUENT® Eulerian-Lagrangian simulations (DDPM) are unstable for the given reactor design; while the BARRACUDA Eulerian-Lagrangian model is able to simulate the system given appropriate simplifying assumptions. FLUENT® Eulerian-Eulerian simulations also provide a stable solution for the carbon capture reactor given the appropriate simplifying assumptions.

Ryan, Emily M.; DeCroix, David; Breault, Ronald W.; Xu, Wei; Huckaby, E. D.; Saha, Kringan; Darteville, Sebastien; Sun, Xin

2013-07-30T23:59:59.000Z

280

Liquid Propane Injection Applications  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

282

Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants  

SciTech Connect

TDA Research, Inc. has developed a novel sorbent based post-combustion CO{sub 2} removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO{sub 2} capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO{sub 2} produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO{sub 2} produced with the lowest possible increase in the cost of energy. .

Elliott, Jeannine

2013-08-31T23:59:59.000Z

283

Evaluation of hybrid polymer containing iron oxides as As(III) and As(V) sorbent for drinking water purification  

Science Journals Connector (OSTI)

Abstract The objective of this paper was to evaluate the possibility of utilization of a novel hybrid polymer containing iron oxides as an arsenate and arsenite sorbent in water treatment. This material was primarily obtained as a by-product in the water de-ironing process by means of N-chlorosulfonamide polymers. The sorption properties of the hybrid polymer, including pH and coexisting ions’ influence on arsenic removal efficiency, were examined using kinetic and equilibrium experiments in a batch regime. In the column process, conducted with As-spiked natural water containing both As(III) and As(V), the breakthrough of the sorbent bed occurred after the solution amounting to about 4800 bed volumes passed through the column. The regeneration and re-use of the sorbent with NaOH and NaCl solution was also studied, indicating the possibility of repeated use of the sorbent with only a slight decrease in its sorptive properties for four cycles.

Daniel Oci?ski; Irena Jacukowicz-Sobala; Jerzy Raczyk; El?bieta Kocio?ek-Balawejder

2014-01-01T23:59:59.000Z

284

Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation  

SciTech Connect

Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-07-01T23:59:59.000Z

285

Cross-flow, filter-sorbent catalyst for particulate, SO sub 2 and NO sub x control  

SciTech Connect

This synopsis describes a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particulate filter, an SO{sub 2} sorbent, and a NO{sub x} reduction catalyst.

Not Available

1990-03-01T23:59:59.000Z

286

Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Gokhan O. Alptekin, PhD Robert Copeland, PhD Gokhan O. Alptekin, PhD Robert Copeland, PhD (Primary Contact) TDA Research, Inc TDA Research, Inc 12345 W. 52 nd Avenue 12345 W. 52 nd Avenue Wheat Ridge, CO 80033 Wheat Ridge, CO 80033 Email: copeland@tda.com Email: galptekin@tda.com Tel: (303) 940-2323 Tel: (303) 940-2349 Fax: (303) 422-7763 Fax: (303) 422-7763 Margarita Dubovik Yevgenia Gershanovich TDA Research, Inc TDA Research, Inc 12345 W. 52 nd Avenue 12345 W. 52 nd Avenue Wheat Ridge, CO 80033 Wheat Ridge, CO 80033 Email: dubovik@tda.com Email: ygershan@tda.com Tel: (303) 940-2316 Tel: (303) 940-2346 Fax: (303) 422-7763 Fax: (303) 422-7763 Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

287

Experimental Target Injection and Tracking System  

SciTech Connect

Targets must be injected into an IFE power plant with an accuracy of and plusmn; 5 mm at a rate of approximately 5 to 10 each second. Targets must be tracked very accurately to allow driver beams to be aligned with defined points on the targets with accuracy {+-}200{mu}m for indirect drive and {+-}20{mu}m for direct drive. An experimental target injection and tracking system has been designed and is being constructed at General Atomics to investigate injection and tracking of both direct drive and indirect drive targets. The design is modular to allow testing of alternate target acceleration and tracking methods. The injector system will be used as a tool for testing the survivability of various target designs and provide feed back to the target designers. This 30 m long system will be the centerpiece of a Facility for developing IFE target fabrication and injection technologies. A high-speed high-flow gas valve (designed and built by Oak Ridge National Laboratory) will provide helium propellant gas to the targets. To avoid target damage from excessive acceleration, an 8 m gun barrel is being built to achieve 400 m/s target speed while not exceeding 10,000 m/s{sup 2} acceleration. Direct-drive targets are protected in the barrel by sabots that are spring loaded to separate into two halves after acceleration. A sabot deflector directs the sabot halves away from the target injection path. Gas expansion chambers and orifices, keep propellant gas out of the target-tracking region. Targets will be optically tracked with laser beams and line scan cameras. High-speed computations will calculate target position in less than 2 ms based on the output from the line-scan cameras. Target position and arrival time to a plane in the reaction chamber center will be predicted in real-time based on early target position measurements. The system design, construction progress, and early testing results will be presented.

Petzoldt, R.W. [General Atomics (United States); Alexander, N.B. [General Atomics (United States); Drake, T.J. [General Atomics (United States); Goodin, D.T. [General Atomics (United States); Stemke, R.W. [General Atomics (United States); Jonestrask, K

2003-07-15T23:59:59.000Z

288

Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants  

SciTech Connect

This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

2003-12-31T23:59:59.000Z

289

Underground Injection Control Rule (Vermont)  

Energy.gov (U.S. Department of Energy (DOE))

This rule regulates injection wells, including wells used by generators of hazardous or radioactive wastes, disposal wells within an underground source of drinking water, recovery of geothermal...

290

Underground Injection Control Regulations (Kansas)  

Energy.gov (U.S. Department of Energy (DOE))

This article prohibits injection of hazardous or radioactive wastes into or above an underground source of drinking water, establishes permit conditions and states regulations for design,...

291

Injectivity Test | Open Energy Information  

Open Energy Info (EERE)

Injectivity Test Injectivity Test Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Injectivity Test Details Activities (7) Areas (6) Regions (0) NEPA(1) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Permeability of the well Thermal: Dictionary.png Injectivity Test: A well testing technique conducted upon completion of a well. Water is pumped into the well at a constant rate until a stable pressure is reached then the pump is turned off and the rate at which pressure decreases is measured. The pressure measurements are graphed and well permeability can

292

Evaluation of Type I cement sorbent slurries in the U.C. pilot spray dryer facility. Final report, November 1, 1994--February 28, 1996  

SciTech Connect

This research was focused on evaluating hydrated cement sorbents in the U. C. pilot spray dryer. The main goal of this work was to determine the hydration conditions resulting in reactive hydrated cement sorbents. Hydration of cement was achieved by stirring or by grinding in a ball mill at either room temperature or elevated temperatures. Also, the effects of several additives were studied. Additives investigated include calcium chloride, natural diatomite, calcined diatomaceous earth, and fumed silica. The performance of these sorbents was compared with conventional slaked lime. Further, the specific surface area and pore volume of the dried SDA sorbents were measured and compared to reactivity. Bench-scale tests were performed to obtain a more detailed picture of the development of the aforementioned physical properties as a function of hydration time.

Keener, T.C.; Khang, S.J.

1996-07-31T23:59:59.000Z

293

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, April 1, 1994--June 30, 1994  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which can easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Department of Energy`s Pittsburgh Energy Technology Center (PETC) and UOP/Shell have developed processes which both employ copper oxide-based sorbents in different reactor configurations. More recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has a potentially higher sulfur capture capacity than copper. It is readily available at a moderate cost. Although it is more expensive than copper oxide, since the cost of metal oxide is a small fraction of the total sorbent cost this may not be a significant factor. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.

1994-07-01T23:59:59.000Z

294

Pilot-scale testing of a new sorbent for combined SO{sub 2}/NO{sub x} removal. Final report  

SciTech Connect

A new regenerable sorbent concept for SO{sub 2} and NOx removal was pilot-tested at Ohio Edison`s Edgewater generating station at a 1.5 to 2-MW(e) level. A radial panel-bed filter of a new dry, granular sorbent was exposed to flue gas and regenerated in an experimental proof-of-concept program. The project was successful in demonstrating the new sorbent`s ability to achieve 90% SO{sub 2} removal, 30% NOx removal, and over 80% removal of residual particulates with realistic approach temperatures and low pressure drops. Based on the results of this project, the retrofit cost of this technology is expected to be on the order of $400 per ton of SO{sub 2} and $900 per ton of NOx removed. This assumes that gas distribution is even and methane regeneration is used for a 30% average utilization. For a 2.5%-sulfur Ohio coal, this translates to a cost of approximately $17 per ton of coal. Two by-product streams were generated in the process that was tested: a solid, spent-sorbent stream and a highly-concentrated SO{sub 2} or elemental-sulfur stream. While not within the scope of the project, it was found possible to process these streams into useful products. The spent sorbent materials were shown to be excellent substrates for soil amendments; the elemental sulfur produced is innocuous and eminently marketable.

Nelson, S. Jr. [Sorbent Technologies Corp., Twinsburg, OH (United States)

1994-06-01T23:59:59.000Z

295

Preparation of sorbents containing ettringite phase from concrete sludge and their performance in removing borate and fluoride ions from waste water  

Science Journals Connector (OSTI)

Concrete sludge is an industrial waste slurry containing hydrated cement, aggregates and water. Solid sorbents containing ettringite, Ca6Al2(SO4)3(OH)12·26H2O, were prepared from concrete sludge by adding various amounts of aluminum sulfate to enhance ettringite formation. Anion exchange performance of the sorbents was examined using model waste waters containing boron or fluoride ions. The removal behavior depended on the calcium/aluminum ratio and the heat treatment temperature after drying. For the same Ca/Al ratio, improved removal performance was observed for sorbents treated at higher temperatures. The highest removal capacity was found when the sorbent was prepared with a molar ratio of Ca/Al of 3.2 and heat treatment at 175 °C. The final concentrations of boron and fluoride were 6.3 mg-B/L, and less than 4 mg-F/L for initial concentrations of 100 mg-B/L and 300 mg-F/L. Treatment of the sorbents at higher temperature dehydrated the ettringite phase to form metaettringite phase. The sorbents prepared in the present study can be used in a boron and fluoride removal process that meets the effluent standard in Japan.

Yusuke Tsunashima; Atsushi Iizuka; Junichiro Akimoto; Teruhisa Hongo; Akihiro Yamasaki

2012-01-01T23:59:59.000Z

296

Advanced Modeling of Direct-Injection Diesel Engines  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

calculation. It strongly influences the atomization and break-up processes, the spray penetration, the inter-phase transfer processes, and the droplet-droplet interaction. The...

297

Advanced Modeling of Direct-Injection Diesel Engines | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Engines 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deerzellat.pdf More Documents & Publications Effects of Ambient Density and...

298

Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications  

Energy.gov (U.S. Department of Energy (DOE))

Specific designs and material properties have to be developed for gasoline particulate filters based on the different engine and exhaust gas characteristic of gasoline engines compared to diesel engines, e.g., generally lower levels of engine-out particulate emissions or higher GDI exhaust gas temperatures

299

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development  

Energy.gov (U.S. Department of Energy (DOE))

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

300

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development  

Energy.gov (U.S. Department of Energy (DOE))

2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Turbocharged Spark Ignited Direct Injection - A Fuel Economy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

- A Fuel Economy Solution for The US Turbocharged SIDI is the most promising advanced gasoline technology; combines existing & proven technologies in a synergistic manner, offers...

302

Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development  

Energy.gov (U.S. Department of Energy (DOE))

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

303

Development of Al-stabilized CaO–nickel hybrid sorbent–catalyst for sorption-enhanced steam methane reforming  

Science Journals Connector (OSTI)

Abstract In this work, Al-stabilized CaO–Ni hybrid sorbent–catalysts integrated in a single particle with various nickel loadings (12, 18 and 25 wt% NiO) were developed and tested in cyclic hydrogen production by sorption-enhanced steam methane reforming (SESMR) process. A simple wet-mixing technique based on limestone acidification and two-step calcination was employed to produce hybrid materials with different nickel loadings. All developed materials were characterized by BET, XRD, SEM and TEM and studied during 25 CO2 sorption/regeneration cycles as well as for 10 SESMR cycles. Based on both CO2 sorption and SESMR results, it was concluded that the proposed hybrid sorbent–catalyst with NiO loading of 25 wt% led to the best performances: (i) CaO molar conversion is 41.2% at the end of the 25th sorption cycle and (ii) average CH4 conversion and H2 production efficiency during 10 SESMR cycles are remarkable (99.1% and 96.1%, respectively). For the most efficient hybrid sorbent–catalyst (25 wt% NiO), the influence of CH4 flow rate and steam to carbon ratio (S/C) was also investigated, as well as its behavior during long-term cyclic operation of SESMR (30 cycles), where the H2 production time was just limited to pre-breakthrough period. The very efficient performance (average of H2 yield 97.3%) of the proposed hybrid sorbent–catalyst material in long-term operation confirmed its high potential for use in SESMR process.

Hamid R. Radfarnia; Maria C. Iliuta

2014-01-01T23:59:59.000Z

304

Development of a Dry Sorbent-based Post-Combustion CO2 Capture Technology for Retrofit in Existing Power Plants  

SciTech Connect

The objective of this research and development (R&D) project was to further the development of a solid sorbent-based CO2 capture process based on sodium carbonate (i.e. the Dry Carbonate Process) that is capable of capturing>90% of the CO2 as a nearly pure stream from coal-fired power plant flue gas with <35% increase in the cost of electrictiy (ICOE).

Nelson, Thomas; Coleman, Luke; Anderson, Matthew; Gupta, Raghubir; Herr, Joshua; Kalluri, Ranjeeth; Pavani, Maruthi

2009-12-31T23:59:59.000Z

305

Hydrogen production by sorption-enhanced steam methane reforming process using CaO-Zr/Ni bifunctional sorbent–catalyst  

Science Journals Connector (OSTI)

Abstract A bifunctional CaO-Zr/Ni (13, 18, and 20.5 wt% NiO) sorbent–catalyst was developed using the wet-mixing/sonication technique and applied for hydrogen production by sorption-enhanced steam methane reforming (SESMR), an intensified process that integrates hydrogen production with CO2 capture. The material was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and N2 physisorption (BET). CO2 sorption efficiency of the developed materials was evaluated during 25 CO2 sorption/regeneration cycles. The prepared sorbent–catalysts were then applied in the SESMR during 10 reaction cycles. The results showed that the bifunctional sorbent–catalyst with 20.5 wt% NiO loading presented the most suitable activity. The H2 yield of ?91% at the end of the 10th SESMR cycle is considerably higher than equilibrium H2 yield that could be obtained by traditional steam methane reforming.

Hamid R. Radfarnia; Maria C. Iliuta

2014-01-01T23:59:59.000Z

306

Development of an injection augmentation program at the Dixie Valley,  

Open Energy Info (EERE)

an injection augmentation program at the Dixie Valley, an injection augmentation program at the Dixie Valley, Nevada geothermal field Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Development of an injection augmentation program at the Dixie Valley, Nevada geothermal field Abstract Evaporative cooling at geothermal power plants generally reduces reservoir pressures even if all available geothermal liquids are reinjected. Controlled programs of injecting non geothermal waters directly into reservoirs have been tested or implemented at only four fields, three of them being vapor dominated. At the liquid-dominated Dixie Valley geothermal field an unsuccessful search for a large volume source of warm,chemically desirable fluid for augmentation was conducted.After determining water

307

Injection nozzle for a turbomachine  

DOE Patents (OSTI)

A turbomachine includes a compressor, a combustor operatively connected to the compressor, an end cover mounted to the combustor, and an injection nozzle assembly operatively connected to the combustor. The injection nozzle assembly includes a first end portion that extends to a second end portion, and a plurality of tube elements provided at the second end portion. Each of the plurality of tube elements defining a fluid passage includes a body having a first end section that extends to a second end section. The second end section projects beyond the second end portion of the injection nozzle assembly.

Uhm, Jong Ho; Johnson, Thomas Edward; Kim, Kwanwoo

2012-09-11T23:59:59.000Z

308

Investigation of combined SO{sub 2}/NO{sub x} removal by Ceria Sorbents. Quarterly technical progress report, January 1, 1994--March 31, 1994  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which an easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Department of Energy`s Pittsburgh Energy Technology Center (PETC) and UOP/Shell have developed processes which both employ copper oxide-based sorbents in different reactor configurations, namely, former uses a regenerative fluidized bed while the latter employs a cyclic fixed bed contactor. More recent studies at PETC considered cerium oxide as an alternate sorbent to CuO{sup (1,2)}. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has potentially higher sulfur capture capacity than copper. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.; Akyurtlu, J.F.

1994-07-01T23:59:59.000Z

309

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, January 1993--March 1993  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which an easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Department of Energy`s Pittsburgh Energy Technology Center (PETC) and UOP/Shell have developed processes which both employ copper oxide-based sorbents in different reactor configurations, namely, former uses a regenerative fluidized bed while the latter employs a cyclic fixed bed contactor. More recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has a potentially higher sulfur capture capacity than copper. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.; Akyurtlu, J.F.

1994-06-01T23:59:59.000Z

310

Investigation of combined SO{sub 2}/NO{sub x} removal by Ceria sorbents. Quarterly technical progress report, July 1994--September 1994  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x}removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which an easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has a potentially higher sulfur capture capacity than copper. It is readily available at a moderate cost. Although it is more expensive than copper oxide, since the cost of metal oxide is a small fraction of the total sorbent cost this may not be a significant factor. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.

1994-10-01T23:59:59.000Z

311

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, October 1993--December 1993  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases as a competitive cost; produce a concentrated stream of SO{sub 2} which can easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Department of Energy`s Pittsburgh Energy Technology Center (PETC) and UOP/Shell have developed processes which both employ copper oxide-based sorbents in different reactor configurations, namely, former uses a regenerative fluidized bed while the latter employs a cyclic fixed bed contactor. More recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has a potentially higher sulfur capture capacity than copper. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.

1994-06-01T23:59:59.000Z

312

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, April 1, 1993--June 30, 1993  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which can easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has a potentially higher sulfur capture capacity than copper. It is readily available at a moderate cost. Although it is more expensive than copper oxide, since the cost of metal oxide is a small fraction of the total sorbent cost this may not be a significant factor. The objective of this research is to determine the effects of ammonia on the sulfation of the sorbent; to determine the effects of fly ash on the sulfation and regeneration of the sorbent; to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents; to model reactor configurations for a commercial scale combined CeO{sub 2}/Al{sub 2}O{sub 3} sorbent; and to study alternative designs, effects of design variables on the performance of the facility, and the economics of the process using the developed model.

Akyurtlu, A.

1993-06-01T23:59:59.000Z

313

Category:Injectivity Test | Open Energy Information  

Open Energy Info (EERE)

Sign Up Search Category Edit History Facebook icon Twitter icon Category:Injectivity Test Jump to: navigation, search Geothermalpower.jpg Looking for the Injectivity Test page?...

314

Spheromak injection into a tokamak  

Science Journals Connector (OSTI)

Recent results from the Caltech spheromak injection experiment [to appear in Phys. Rev. Lett.] are reported. First current drive by spheromak injection into the ENCORE tokamak as a result of the process of magnetic helicity injection is observed. An initial 30% increase in plasma current is observed followed by a drop by a factor of 3 because of sudden plasma cooling. Second spheromak injection results in an increase of tokamak central density by a factor of 6. The high?current/high?density discharge is terminated by a sharp peaking of the density profile followed by an interchange instability. In a second experiment the spheromak is injected into the magnetized toroidal vacuum vessel (with no tokamak plasma) fitted with magnetic probe arrays. An m=1 (nonaxisymmetric) magnetic structure forms in the vessel after the spheromak undergoes a double tilt; once in the cylindrical entrance between gun and tokamak then again in the tokamak vessel. In the absence of net toroidal flux the structure develops a helical pitch (the sense of pitch depends on the helicity sign). Experiments with a number of refractory metal electrode coatings have shown that tungsten and chrome coatings provide some improvement in spheromak parameters. Design details of a larger higher?current spheromak gun with a new accelerator section are also discussed.

M. R. Brown; P. M. Bellan

1990-01-01T23:59:59.000Z

315

Subtask 4.27 - Evaluation of the Multielement Sorbent Trap (MEST) Method at an Illinois Coal-Fired Plant  

SciTech Connect

Owners of fossil fuel-fired power plants face the challenge of measuring stack emissions of trace metals and acid gases at much lower levels than in the past as a result of increasingly stringent regulations. In the United States, the current reference methods for trace metals and halogens are wet-chemistry methods, U.S. Environmental Protection Agency (EPA) Methods 29 and 26 or 26A, respectively. As a possible alternative to the EPA methods, the Energy & Environmental Research Center (EERC) has developed a novel multielement sorbent trap (MEST) method to be used to sample for trace elements and/or halogens. Sorbent traps offer a potentially advantageous alternative to the existing sampling methods, as they are simpler to use and do not require expensive, breakable glassware or handling and shipping of hazardous reagents. Field tests comparing two sorbent trap applications (MEST-H for hydrochloric acid and MEST-M for trace metals) with the reference methods were conducted at two power plant units fueled by Illinois Basin bituminous coal. For hydrochloric acid, MEST measured concentrations comparable to EPA Method 26A at two power plant units, one with and one without a wet flue gas desulfurization scrubber. MEST-H provided lower detection limits for hydrochloric acid than the reference method. Results from a dry stack unit had better comparability between methods than results from a wet stack unit. This result was attributed to the very low emissions in the latter unit, as well as the difficulty of sampling in a saturated flue gas. Based on these results, the MEST-H sorbent traps appear to be a good candidate to serve as an alternative to Method 26A (or 26). For metals, the MEST trap gave lower detection limits compared to EPA Method 29 and produced comparable data for antimony, arsenic, beryllium, cobalt, manganese, selenium, and mercury for most test runs. However, the sorbent material produced elevated blanks for cadmium, nickel, lead, and chromium at levels that would interfere with accurate measurement at U.S. hazardous air pollutant emission limits for existing coal-fired power plant units. Longer sampling times employed during this test program did appear to improve comparative results for these metals. Although the sorbent contribution to the sample was reduced through improved trap design, additional research is still needed to explore lower-background materials before the MEST-M application can be considered as a potential alternative method for all of the trace metals. This subtask was funded through the EERC–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Electric Power Research Institute, the Illinois Clean Coal Institute, Southern Illinois Power Company, and the Center for Air Toxic Metals Affiliates Program.

Pavlish, John; Thompson, Jeffrey; Dunham, Grant

2014-09-30T23:59:59.000Z

316

How carbon-based sorbents will impact fly ash utilization and disposal  

SciTech Connect

The injection of activated carbon flue gas to control mercury emissions will result in a fly ash and activated carbon mixture. The potential impact of this on coal combustion product disposal and utilization is discussed. The full paper (and references) are available at www.acaa-usa.org. 1 tab., 2 photos.

Pflughoeft-Hassett, D.F.; Hassett, D.J.; Buckley, T.D.; Heebink, L.V.; Pavlish, J.H. [Energy and Environmental Research Center (United States)

2008-07-01T23:59:59.000Z

317

Well injection valve with retractable choke  

SciTech Connect

An injection valve is described for use in a well conduit consisting of: a housing having a bore, a valve closure member in the bore moving between open and closed positions, a flow tube telescopically movable in the housing for controlling the movement of the valve closure member, means for biasing the flow tube in a direction for allowing the valve closure member to move to the closed position, an expandable and contractible fluid restriction connected to the flow tube and extending into the bore for moving the flow tube to the open position in response to injection fluid, but allowing the passage of well tools through the valve, the restriction contractible in response to fluid flow, the restriction includes, segments movable into and out of the bore, and biasing means yieldably urging the segments into the bore, a no-go shoulder on the flow tube, and releasable lockout means between the flow tube and the housing for locking the flow tube and valve in the open position.

Pringle, R.E.

1986-07-22T23:59:59.000Z

318

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, October--December, 1994  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. The present study aims to determine the effects of ammonia on the sulfation of the sorbent and to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents. The sulfation experiments indicated that 100% conversion of ceria could be attained. Activation energy for the sulfation reaction was found to be 19 kJ/mol. The rate of sulfation reaction is first order with respect to SO{sub 2} and solid reactant concentrations. For regeneration with hydrogen, the activation energy and the reaction order with respect to hydrogen was found to be 114 kJ/mol and 0.56, respectively. The ceria sorbent preserved its activity and structural stability after 6 cycles. The information obtained from these studies will be used to develop models for reactor-regenerator configurations. Subsequently, the SO{sub 2}/NO{sub x} removal facility will be integrated into the power production process using a commercial process simulation software. In this quarter of the project, the main focus was on the performance of the experimental program for the regeneration of the ceria sorbent by hydrogen and evaluation of experimental results.

Akyurtlu, A.; Akyurtlu, J.F.

1995-01-01T23:59:59.000Z

319

Linked Injectives and Ore Localizations  

Science Journals Connector (OSTI)

......injective right (Z?//)-module. By (a), L is ^-divisible and hence ^-divisible. Consider xeE and c e ^ such that xceL. Then xc = yc for some yeL, whence x = y and so xeL. Thus E/L is ^-torsion-free. In view of Lemma 1.1, we investigate......

K. R. Goodearl

1988-06-01T23:59:59.000Z

320

Sequential injection gas guns for accelerating projectiles  

DOE Patents (OSTI)

Gas guns and methods for accelerating projectiles through such gas guns are described. More particularly, gas guns having a first injection port located proximate a breech end of a barrel and a second injection port located longitudinally between the first injection port and a muzzle end of the barrel are described. Additionally, modular gas guns that include a plurality of modules are described, wherein each module may include a barrel segment having one or more longitudinally spaced injection ports. Also, methods of accelerating a projectile through a gas gun, such as injecting a first pressurized gas into a barrel through a first injection port to accelerate the projectile and propel the projectile down the barrel past a second injection port and injecting a second pressurized gas into the barrel through the second injection port after passage of the projectile and to further accelerate the projectile are described.

Lacy, Jeffrey M. (Idaho Falls, ID); Chu, Henry S. (Idaho Falls, ID); Novascone, Stephen R. (Idaho Falls, ID)

2011-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Injection of Zero Valent Iron into an Unconfined Aquifer Using Shear-Thinning Fluids  

SciTech Connect

Approximately 190 kg of two micron-diameter zero-valent iron (ZVI) particles were injected into a test zone in the top two meters of an unconfined aquifer within a trichloroethene (TCE) source area. A shear-thinning fluid was used to enhance ZVI delivery in the subsurface to a radial distance of up to four meters from a single injection well. The ZVI particles were mixed in-line with the injection water, shear-thinning fluid, and a low concentration of surfactant. ZVI was observed at each of the seven monitoring wells within the targeted radius of influence during injection. Additionally, all wells within the targeted zone showed low TCE concentrations and primarily dechlorination products present 44 days after injection. These results suggest that ZVI can be directly injected into an aquifer with shear-thinning fluids and extends the applicability of ZVI to situations where other emplacement methods may not be viable.

Truex, Michael J.; Vermeul, Vincent R.; Mendoza, Donaldo P.; Fritz, Brad G.; Mackley, Rob D.; Oostrom, Martinus; Wietsma, Thomas W.; Macbeth, Tamzen

2011-02-18T23:59:59.000Z

322

A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays  

SciTech Connect

Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

323

Injection Technology for Marine Diesel Engines  

Science Journals Connector (OSTI)

The introduction of new emission limits faces modern injection systems with new challenges. Increasing the system pressures puts higher loads on the injection components as regards stability, wear and temperature...

Dr. Rolf Leonhard; Dr.-Ing. Marcus Parche…

2011-04-01T23:59:59.000Z

324

An environmental analysis of injection molding  

E-Print Network (OSTI)

This thesis investigates injection molding from an environmental standpoint, yielding a system-level environmental analysis of the process. There are three main objectives: analyze the energy consumption trends in injection ...

Thiriez, Alexandre

2006-01-01T23:59:59.000Z

325

SQL Injection Attacks and Defense, 2 edition  

Science Journals Connector (OSTI)

SQL Injection Attacks and Defense, First Edition: Winner of the Best Book Bejtlich Read Award "SQL injection is probably the number one problem for any server-side application, and this book unequaled in its coverage." żżRichard ...

Justin Clarke; Kevvie Fowler; Erlend Oftedal; Rodrigo Marcos Alvarez; Dave Hartley; Alexander Kornbrust; Gary O'Leary-Steele; Alberto Revelli; Sumit Siddharth; Marco Slaviero

2009-06-01T23:59:59.000Z

326

Engines - Fuel Injection and Spray Research - Gasoline Sprays  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasoline Sprays Gasoline Sprays Animated image of fuel emerging from a gasoline injector Animated image of fuel emerging from a gasoline injector (simulated environment). Some newer automobiles in the U.S. use gasoline direct injection (GDI) engines. These advanced gasoline engines inject the fuel directly into the engine cylinder rather than into the intake port. These engines can achieve higher fuel efficiency, but they depend on a precise fuel/air mixture at the spark plug to initiate ignition. This leads to more stringent requirements on spray quality and reproducibility. GDI also enables new combustion strategies for gasoline engines such as lean burn engines that use less fuel and air. Lean burn engines may achieve efficiencies near those of diesels while producing low emissions. This

327

A Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture  

E-Print Network (OSTI)

looping is selected as the model cycle because of its suitability for solar-driven carbon dioxide captureA Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture Lindsey Yue and Wojciech Lipi´nski, The Australian

328

Cross-flow, filter-sorbent catalyst for particulate, SO{sub 2} and NO{sub x} control. First quarterly technical progress report, 1990  

SciTech Connect

This synopsis describes a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particulate filter, an SO{sub 2} sorbent, and a NO{sub x} reduction catalyst.

Not Available

1990-03-01T23:59:59.000Z

329

Effect of High-Pressure Impregnation on Structure Variation and Desulfurization Property of a Zn-Based Sorbent Prepared Using Lignite as a Support  

Science Journals Connector (OSTI)

Effect of High-Pressure Impregnation on Structure Variation and Desulfurization Property of a Zn-Based Sorbent Prepared Using Lignite as a Support ... Lignite reserves are relatively abundant in China; however, its utilization is significantly limited because of its high water content and low calorific value. ...

Xiurong Ren; Qiang He; Yurong Dong; Meijun Wang; Liping Chang; Weiren Bao

2014-06-10T23:59:59.000Z

330

Liquid Propane Injection Applications | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Liquid propane injection technology meets manufacturingassembly guidelines, maintenancerepair strategy, and regulations, with same functionality, horsepower, and torque as...

331

ELECTRON INJECTION INTO CYCLIC ACCELERATOR USING  

E-Print Network (OSTI)

ELECTRON INJECTION INTO CYCLIC ACCELERATOR USING LASER WAKEFIELD ACCELERATION Ya. V. Getmanov, O. A acceleration #12;Storage ring with laser injection CYCLIC ACCELERATOR RF Electron injection The LWFA beam ­ accelerating light, 5 ­ accelerated electrons, 6 ­fast kicker - + accelerating laser pulse evaporatinglaser

332

Numerical Simulation of Cooling Gas Injection Using  

E-Print Network (OSTI)

Numerical Simulation of Cooling Gas Injection Using Adaptive Multiscale Techniques Wolfgang Dahmen: finite volume method, film cooling, cooling gas injection, multiscale techniques, grid adaptation AMS@igpm.rwth-aachen.de (Thomas Gotzen) #12;Numerical simulation of cooling gas injection using adaptive multiscale techniques

333

Mechanical injection of magnetic helicity during spheromak formation  

Science Journals Connector (OSTI)

Experimental evidence is reported for the presence of oppositely rotating plasma cells during spheromak formation. The toroidal rotations are caused by j×B forces and cause a twisting of axial (i.e., poloidal) magnetic field into the toroidal direction. Calculations of the magnetic helicity input are consistent with measured helicity values. This method of flux conversion can be interpreted as a mechanical source of magnetic helicity injection possibly useful for magnetic confinement of plasmas.

B. Barrow and G. C. Goldenbaum

1990-03-19T23:59:59.000Z

334

Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, January 1995--March 1995  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x}using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. The present study aims to determine the effects of ammonia on the sulfation of the sorbent and to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents. The sulfation experiments indicated that 100 % conversion of ceria can be attained. Activation energy for the sulfation reaction was found to be 19 kJ/mol. The rate of sulfation reaction is first order with respect to SO{sub 2} and solid reactant concentrations. For regeneration with hydrogen, the activation energy and the reaction order with respect to hydrogen was found to be 114 kJ/mol and 0.56, respectively. The ceria sorbent preserved its activity and structural stability after 6 cycles. In the last quarter regeneration with methane was studied. Since regeneration with methane is more complicated than regeneration with hydrogen, the evaluation of data needs the development of new methods. The information obtained from these studies will be used to develop models for reactor-regenerator configurations. Subsequently, the SO{sub 2}/NO{sub x} removal facility will be integrated into the power production process using a commercial process simulation software.

Akyurtlu, A.; Akyurtlu, J.F.

1995-04-01T23:59:59.000Z

335

TAILORING INORGANIC SORBENTS FOR SRS STRONTIUM AND ACTINIDE SEPARATIONS: OPTIMIZED MONOSODIUM TITANATE PHASE II FINAL REPORT  

SciTech Connect

This document provides a final report of Phase II testing activities for the development of a modified monosodium titanate (MST) that exhibits improved strontium and actinide removal characteristics compared to the baseline MST material. The activities included determining the key synthesis conditions for preparation of the modified MST, preparation of the modified MST at a larger scale by a commercial vendor, demonstration of the strontium and actinide removal characteristics with actual tank waste supernate and measurement of filtration characteristics. Key findings and conclusions include the following. Testing evaluated three synthetic methods and eleven process parameters for the optimum synthesis conditions for the preparation on an improved form of MST. We selected the post synthesis method (Method 3) for continued development based on overall sorbate removal performance. We successfully prepared three batches of the modified MST using Method 3 procedure at a 25-gram scale. The laboratory prepared modified MST exhibited increased sorption kinetics with simulated and actual waste solutions and similar filtration characteristics to the baseline MST. Characterization of the modified MST indicated that the post synthesis treatment did not significantly alter the particle size distribution, but did significantly increase the surface area and porosity compared to the original MST. Testing indicated that the modified MST exhibits reduced affinity for uranium compared to the baseline MST, reducing risk of fissile loading. Shelf-life testing indicated no change in strontium and actinide performance removal after storing the modified MST for 12-months at ambient laboratory temperature. The material releases oxygen during the synthesis and continues to offgas after the synthesis at a rapidly diminishing rate until below a measurable rate after 4 months. Optima Chemical Group LLC prepared a 15-kilogram batch of the modified MST using the post synthesis procedure (Method 3). Performance testing with simulated and actual waste solutions indicated that the material performs as well as or better than batches of modified MST prepared at the laboratory-scale. Particle size data of the vendor-prepared modified MST indicates a broader distribution centered at a larger particle size and microscopy shows more irregular particle morphology compared to the baseline MST and laboratory prepared modified MST. Stirred-cell (i.e., dead-end) filter testing revealed similar filtration rates relative to the baseline MST for both the laboratory and vendor-prepared modified MST materials. Crossflow filtration testing indicated that with MST-only slurries, the baseline MST produced between 30-100% higher flux than the vendor-prepared modified MST at lower solids loadings and comparable flux at higher solids loadings. With sludge-MST slurries, the modified MST produced 1.5-2.2 times higher flux than the baseline MST at all solids loadings. Based on these findings we conclude that the modified MST represents a much improved sorbent for the separation of strontium and actinides from alkaline waste solutions and recommend continued development of the material as a replacement for the baseline MST for waste treatment facilities at the Savannah River Site.

Hobbs, D; Thomas Peters, T; Michael Poirier, M; Mark Barnes, M; Major Thompson, M; Samuel Fink, S

2007-06-29T23:59:59.000Z

336

Allergy Injection Policy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Allergy Injection Policy Allergy Injection Policy Allergy Injection Policy Millions of Americans suffer from perennial and seasonal allergic rhinitis. Allergy immunotherapy is an effective way to reduce or eliminate the symptoms of allergic rhinitis by desensitizing the patient to the allergen(s) by giving escalating doses of an extract via regular injections. Receiving weekly injections at a private physician's office is time consuming, reduces productivity, and can quickly deplete an employee's earned leave. FOH offers the convenience of receiving allergy injections at the OHC as a physician-prescribed service, reducing time away from work for many federal employees. Allergy Injection Policy.pdf More Documents & Publications Physician Treatment Order Handicapped Parking Guidance

337

Dynamic modeling and transient studies of a solid-sorbent adsorber for CO{sub 2} capture  

SciTech Connect

The U.S. Department of Energy’s Carbon Capture Simulation Initiative (CCSI) is dedicated to accelerating the commercialization of carbon capture technologies from discovery to development, demonstration, and ultimately the widespread deployment to hundreds of power plants. In this multi-lab initiative in partnership with academic and industrial institutions, the National Energy Technology Laboratory (NETL) leads the development of a multi-scale modeling and simulation toolset for rapid evaluation and deployment of carbon capture systems. One element of the CCSI is focused on optimizing the operation and control of carbon capture systems since this can have a significant impact on the extent and the rate at which commercial-scale capture processes will be scaled-up, deployed, and used in the years to come. Capture processes must be capable of operating over a wide range of transient events, malfunctions, and disturbances, as well as under uncertainties. As part of this work, dynamic simulation and control models, methods, and tools are being developed for CO{sub 2} capture and compression processes and their integration with a baseline commercial-scale supercritical pulverized coal (SCPC) power plant. Solid-sorbent-based post-combustion capture technology was chosen as the first industry challenge problem for CCSI because significant work remains to define and optimize the reactors and processes needed for successful sorbent capture systems. Sorbents offer an advantage because they can reduce the regeneration energy associated with CO{sub 2} capture, thus reducing the parasitic load. In view of this, the current paper focuses on development of a dynamic model of a solid-sorbent CO{sub 2} adsorber-reactor and an analysis of its transient performance with respect to several typical process disturbances. A one-dimensional, non-isothermal, pressure-driven dynamic model of a two-stage bubbling fluidized bed (BFB) adsorber-reactor is developed in Aspen Custom Modeler (ACM). The BFB stages are of overflow-type configuration where the solids leave the stage by flowing over the overflow-weir. Each bed is divided into three regions, namely emulsion, bubble, and cloud-wake regions. In all three regions, the model considers mass and energy balances. Along with the models of the BFB stages, models of other associated hardware are developed and integrated in a single flowsheet. A valid pressure-flow network is developed and a lower-level control system is designed so that the overall CO{sub 2} capture can be maintained at a desired level in face of the typical disturbances. The dynamic model is used for studying the transient responses of a number of important process variables as a result of the disturbances that are typical of post-combustion CO{sub 2} capture processes.

Modekurti, Srinivasarao [WVU; Bhattacharyya, Debangsu [WVU; Zitney, Stephen E. [U.S. DOE

2012-01-01T23:59:59.000Z

338

Alteration of permeability by fine particle movement -- A water injectivity problem  

SciTech Connect

Siri field is located off shore of Iran in the Persian Gulf and is producing from the Mishrif Formation, which is common between Iran and United Arab Emirates. Existence of an active aquifer and other appropriate conditions led to the decision of a water injection program. Sea water from the Persian Gulf was found to be compatible with the formation water and was directly injected into the formation after passing through 10 micron filters. Water injectivity was drastically decreased from an initial injection rate of 9,100 bbl/day to 2,200 bbl/day within six years. Because of the severe injectivity loss, the water injection was stopped. An experimental investigation was undertaken to look into the possible causes of the injectivity loss. Two sets of experimental investigations were undertaken with different objectives in mind. In the first part glass bead packs were used to test the experimental set up and to observe the general behavior of fine particle movement in porous media. In the second part a core plug from the field and sea water were used to determine the possible cause of injectivity loss in the field. The experiments were conducted with injection rates of 0.9 cm{sup 3}/s to 3.1 cm{sup 3}/s. Particles of bentonite were suspended in the injected water to simulate fine particles migration in porous media. The particles were injected at concentrations ranged from 20 g/l to 40 g/l. It was observed that the build up in flow resistance was mostly due to the frontal face plugging. Particles of bentonite and alumina were added to the glass beads to study the effect of particles initially present in the glass beads pack medium. Field and laboratory data clearly indicate the importance of the water quality in a waterflood project. Experimental data suggest that a smaller size filter should have been implemented to avoid the injectivity loss.

Asghari, K.; Kharrat, R.; Vossoughi, S.

1995-11-01T23:59:59.000Z

339

Resistivity measurements before and after injection Test 5 at Raft River  

Open Energy Info (EERE)

measurements before and after injection Test 5 at Raft River measurements before and after injection Test 5 at Raft River KGRA, Idaho. Final report Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Resistivity measurements before and after injection Test 5 at Raft River KGRA, Idaho. Final report Details Activities (2) Areas (1) Regions (0) Abstract: Resistivity measurements were made prior to, and after an injection test at Raft River KGRA, Idaho. The objectives of the resistivity measurements were to determine if measureable changes could be observed and whether they could be used to infer the direction of fluid flow. Most of the apparent resistivity changes observed after the injection phase of Test 5 are smaller than the estimated standard deviation of the measurements. However, the contour map of the changes suggest an anomalous trend to the

340

Long distance transmission of SC-FDMA signals by directly-modulated OIL-VCSEL  

Science Journals Connector (OSTI)

We demonstrate the long distance transmission of single-carrier frequency division multiple address signals by directly-modulated optically injection-locked ...

Guo, Peng; Zhang, Cheng; Li, Juhao; Yang, Weijian; Parekh, Devang; Chang-Hasnain, Connie J; Hu, Weiwei; Xu, Anshi; Chen, Zhangyuan

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Ideal magnetohydrodynamic simulations of low beta compact toroid injection into a hot strongly magnetized plasma  

SciTech Connect

We present results from three-dimensional ideal magnetohydrodynamic simulations of low {beta} compact toroid (CT) injection into a hot strongly magnetized plasma, with the aim of providing insight into CT fueling of a tokamak with parameters relevant for ITER (International Thermonuclear Experimental Reactor). A regime is identified in terms of CT injection speed and CT-to-background magnetic field ratio that appears promising for precise core fueling. Shock-dominated regimes, which are probably unfavorable for tokamak fueling, are also identified. The CT penetration depth is proportional to the CT injection speed and density. The entire CT evolution can be divided into three stages: (1) initial penetration, (2) compression in the direction of propagation and reconnection, and (3) coming to rest and spreading in the direction perpendicular to injection. Tilting of the CT is not observed due to the fast transit time of the CT across the background plasma.

Liu, Wei [Los Alamos National Laboratory; Hsu, Scott [Los Alamos National Laboratory; Li, Hui [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

342

Liquid Propane Injection Technology Conductive to Today's North...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

343

Theory of diffusion and sorption of various substances through a biporous sorbent membrane for the case of a constant concentration difference at its boundaries and a linear sorption isotherm. I. Case of an exponential kinetic function for the microporous zones  

Science Journals Connector (OSTI)

An analytical solution has been obtained for the passage of the sorbed substance through a membrane of a biporous sorbent for the case of constant concentration differences of the sorptive on its boundaries and a...

V. I. Ulin; P. P. Zolotarev; A. I. Pilipenko

1980-08-01T23:59:59.000Z

344

Directives Help  

Directives, Delegations, and Requirements

All DOE directives are available through this site. While it may seem overwhelming, given the number of documents, we have provided a number of ways in which you may get to the information you need.

345

Rare-earth neutral metal injection into an electron beam ion trap plasma  

SciTech Connect

We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures ?10{sup ?7} Torr at ?1000?°C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap.

Magee, E. W., E-mail: magee1@llnl.gov; Beiersdorfer, P.; Brown, G. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hell, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Dr. Remeis-Sternwarte and ECAP, Universität Erlangen-Nürnberg, 96049 Bamberg (Germany)

2014-11-15T23:59:59.000Z

346

Impact of fuel and injection system on particle emissions from a GDI engine  

Science Journals Connector (OSTI)

Abstract In recent years, particulate emissions from the gasoline direct injection (GDI) engine, especially the ultrafine particulates, have become a subject of concern. In this study, the impact of fuel (gasoline versus ethanol) and injection system (injection pressure and injector condition) on particle emissions was investigated in a single cylinder spray-guided GDI research engine, under the operating conditions of stoichiometric air/fuel ratio, 1500 rpm engine speed and 3.5–8.5 bar IMEP. The results show that, in a spray guided GDI engine, ethanol combustion yields much lower particle mass (PM) but higher particle number (PN) emissions, compared to gasoline. Depending on the fuel used, the PM and PN emissions respond differently to injection pressure and injector condition. For gasoline, the injection system has a significant impact on the PM and PN emissions. High injection pressure and clean injector condition are both essential for low particle emissions. Compared to gasoline, the particle emissions from ethanol combustion is less sensitive to the injection system, due to its higher volatility and diffusive combustion which produces less soot. Furthermore, a PM and PN trade-off was observed when using gasoline and ethanol, and when using high injection pressures.

Chongming Wang; Hongming Xu; Jose Martin Herreros; Jianxin Wang; Roger Cracknell

2014-01-01T23:59:59.000Z

347

Underground Injection Control Permits and Registrations (Texas) |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

You are here You are here Home » Underground Injection Control Permits and Registrations (Texas) Underground Injection Control Permits and Registrations (Texas) < Back Eligibility Utility Agricultural Investor-Owned Utility State/Provincial Govt Industrial Construction Municipal/Public Utility Local Government Installer/Contractor Rural Electric Cooperative Fuel Distributor Savings Category Buying & Making Electricity Program Info State Texas Program Type Environmental Regulations Safety and Operational Guidelines Provider Texas Commission on Environmental Quality Chapter 27 of the Texas Water Code (the Injection Well Act) defines an "injection well" as "an artificial excavation or opening in the ground made by digging, boring, drilling, jetting, driving, or some other

348

Low Temperature Catalyst for Fuel Injection System  

Energy.gov (U.S. Department of Energy (DOE))

A low temperature oxidation catalyst applied to a DOC and DPF combined with a unique fuel injection system remove soot from a diesel exhaust system.

349

NONLINEAR MAGNETOHYDRODYNAMICS OF AC HELICITY INJECTION  

NLE Websites -- All DOE Office Websites (Extended Search)

parameter: the driving fre- quency . The lower the frequency, the greater the classical penetration and the higher the helicity injection rate. On the other hand, the field...

350

Energy-efficient control in injection molding.  

E-Print Network (OSTI)

??As an energy-intensive process, in injection molding, energy cost is one of the major cost components. The energy expenditure during molding can be divided into… (more)

Yao, Ke

2008-01-01T23:59:59.000Z

351

Hawaii Underground Injection Control Permitting Webpage | Open...  

Open Energy Info (EERE)

Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Hawaii Underground Injection Control Permitting Webpage Author State of Hawaii Department of...

352

Cascaded injection resonator for coherent beam combining of laser arrays  

DOE Patents (OSTI)

The invention provides a cascaded injection resonator for coherent beam combining of laser arrays. The resonator comprises a plurality of laser emitters arranged along at least one plane and a beam sampler for reflecting at least a portion of each laser beam that impinges on the beam sampler, the portion of each laser beam from one of the laser emitters being reflected back to another one of the laser emitters to cause a beam to be generated from the other one of the laser emitters to the beam reflector. The beam sampler also transmits a portion of each laser beam to produce a laser output beam such that a plurality of laser output beams of the same frequency are produced. An injection laser beam is directed to a first laser emitter to begin a process of generating and reflecting a laser beam from one laser emitter to another laser emitter in the plurality. A method of practicing the invention is also disclosed.

Kireev, Vassili [Sunnyvale, CA; Liu, Yun; Protopopescu, Vladimir [Knoxville, TN; Braiman, Yehuda [Oak Ridge, TN

2008-10-21T23:59:59.000Z

353

Suppression of super-knock in TC-GDI engine using two-stage injection in intake stroke (TSII)  

Science Journals Connector (OSTI)

Turbocharging and direct injection are main technologies used for energy-saving gasoline engines. But the biggest challenge is super-knock, whose mechanism is unclear and has no effective strategy to suppress thi...

Zhi Wang; YaQi Xu; JianXin Wang

2014-01-01T23:59:59.000Z

354

Direct memory access transfer completion notification  

DOE Patents (OSTI)

Methods, compute nodes, and computer program products are provided for direct memory access (`DMA`) transfer completion notification. Embodiments include determining, by an origin DMA engine on an origin compute node, whether a data descriptor for an application message to be sent to a target compute node is currently in an injection first-in-first-out (`FIFO`) buffer in dependence upon a sequence number previously associated with the data descriptor, the total number of descriptors currently in the injection FIFO buffer, and the current sequence number for the newest data descriptor stored in the injection FIFO buffer; and notifying a processor core on the origin DMA engine that the message has been sent if the data descriptor for the message is not currently in the injection FIFO buffer.

Chen, Dong (Croton on Hudson, NY); Giampapa, Mark E. (Irvington, NY); Heidelberger, Philip (Cortlandt Manor, NY); Kumar, Sameer (White Plains, NY); Parker, Jeffrey J. (Rochester, MN); Steinmacher-Burow, Burkhard D. (Esslingen, DE); Vranas, Pavlos (Danville, CA)

2010-07-27T23:59:59.000Z

355

Sorbent Testing for the Solidification of Organic Process Waste streams from the Radiochemical Engineering Development Center at Oak Ridge National Laboratory  

SciTech Connect

The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating various sorbents to solidify the radioactive liquid organic waste from the Radiochemical Engineering Development Center (REDC) at Oak Ridge National Laboratory (ORNL). REDC recovers and purifies heavy elements (berkelium, californium, einsteinium, and fermium) from irradiated targets for research and industrial applications. Both aqueous and organic waste streams are discharged from REDC. Organic waste is generated from the plutonium/uranium extraction (PUREX), Cleanex, and Pubex processes.1 The PUREX waste derives from an organic-aqueous isotope separation process for plutonium and uranium fission products, the Cleanex waste derives from the removal of fission products and other impurities from the americium/curium product, and the Pubex waste is derived from the separation process of plutonium from dissolved targets. An aqueous waste stream is also produced from these separation processes. MSE has been tasked to test a grouting formula for the aqueous waste stream that includes specially formulated radioactive shielding materials developed by Science and Technology Applications, LLC. This paper will focus on the sorbent testing work. Based on work performed at Savannah River Site (SRS) (Refs. 1, 2), ORNL tested and evaluated three sorbents capable of solidifying the PUREX, Pubex, and Cleanex waste streams and a composite of the three organic waste streams: Imbiber Beads{sup R} IMB230301 (Imbiber Beads), Nochar A610 Petro Bond, and Petroset II Granular{sup TM} (Petroset II-G). Surrogates of the PUREX, Pubex, Cleanex, and a composite organic waste were used for the bench-scale testing. Recommendations resulting from the ORNL testing included follow-on testing by MSE for two of the three sorbents: Nochar Petro Bond and Petroset II-G. MSE recommended that another clay sorbent, Organoclay BM-QT-199, be added to the test sequence. The sorbent/surrogate combinations were tested at bench scale, 19-liter (L) [5-gallon (gal)] bucket scale, and 208-L (55-gal) drum scale. The testing performed by MSE will help ORNL select the right solidification materials and wasteform generation methods for the design of a new treatment facility. The results could also be used to help demonstrate that ORNL could meet the waste acceptance criteria for the ultimate disposal site for the waste-forms. The organics will be solidified as transuranic waste for disposal at the Waste Isolation Pilot Plant, and the aqueous waste stream will be grouted and disposed of at the Nevada Test Site as low-level waste if real waste testing indicates similar results to the surrogate testing. The objective of this work was to identify a sorbent capable of solidifying PUREX, Pubex, and Cleanex organic wastes individually and a composite of the three organic waste streams. The sorbent and surrogate combinations must also be compatible with processing equipment and maintain stability under a variety of conditions that could occur during storage/shipment of the solidified wastes. (authors)

Bickford, J.; Foote, M. [MSE Technology Applications, Inc., Montana (United States); Taylor, P. [Oak Ridge National Laboratory, Oak Ridge, Tennessee (United States)

2008-07-01T23:59:59.000Z

356

Bench-scale Development of an Advanced Solid sorbent-based CO2 Capture Process for Coal-fired Power Plalnts  

NLE Websites -- All DOE Office Websites (Extended Search)

scale Development of an scale Development of an Advanced Solid Sorbent-based CO 2 Capture Process for Coal-fired Power Plants Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current

357

Mitigation of thermoacoustic instability utilizing steady air injection near the flame anchoring zone  

SciTech Connect

The objective of this work is to investigate the effectiveness of steady air injection near the flame anchoring zone in suppressing thermoacoustic instabilities driven by flame-vortex interaction mechanism. We perform a systematic experimental study which involves using two different configurations of air injection in an atmospheric pressure backward-facing step combustor. The first configuration utilizes a row of micro-diameter holes allowing for air injection in the cross-stream direction just upstream of the step. The second configuration utilizes an array of micro-diameter holes located on the face of the step, allowing for air injection in the streamwise direction. The effects of each of these configurations are analyzed to determine which one is more effective in suppressing thermoacoustic instabilities at different operating conditions. The tests are conducted while varying the equivalence ratio and the inlet temperature. The secondary air temperature is always the same as the inlet temperature. We used pure propane or propane/hydrogen mixtures as fuels. Combustion dynamics are explored through simultaneous pressure and heat release-rate measurements, and high-speed video images. When the equivalence ratio of the reactant mixture is high, it causes the flame to flashback towards the inlet channel. When air is injected in the cross-stream direction, the flame anchors slightly upstream of the step, which suppresses the instability. When air is injected in the streamwise direction near the edge of step, thermoacoustic instability could be eliminated at an optimum secondary air flow rate, which depends on the operating conditions. When effective, the streamwise air injection prevents the shedding of an unsteady vortex, thus eliminating the flame-vortex interaction mechanism and resulting in a compact, stable flame to form near the step. (author)

Murat Altay, H.; Hudgins, Duane E.; Speth, Raymond L.; Annaswamy, Anuradha M.; Ghoniem, Ahmed F. [Massachusetts Institute of Technology, Department of Mechanical Engineering, Cambridge, MA 02139 (United States)

2010-04-15T23:59:59.000Z

358

MEASURED TRANSVERSE COUPLING IMPEDANCE OF RHIC INJECTION AND ABORT KICKERS.  

SciTech Connect

Concerns regarding possible transverse instabilities in RHIC and the SNS pointed to the need for measurements of the transverse coupling impedance of ring components. The impedance of the RHIC injection and abort kicker was measured using the conventional method based on the S{sub 21} forward transmission coefficient. A commercial 450 {Omega} twin-wire Lecher line were used and the data was interpreted via the log-formula. All measurements, were performed in test stands fully representing operational conditions including pulsed power supplies and connecting cables. The measured values for the transverse coupling impedance in kick direction and perpendicular to it are comparable in magnitude, but differ from Handbook predictions.

HAHN,H.; DAVINO,D.

2001-06-18T23:59:59.000Z

359

Sorbent Testing For Solidification of Process Waste streams from the Radiochemical Engineering Development Center at Oak Ridge National Laboratory  

SciTech Connect

The U.S. Department of Energy (DOE) tasked MSE Technology Applications, Inc. (MSE) to evaluate sorbents identified by Oak Ridge National Laboratory (ORNL) to solidify the radioactive liquid organic waste from the Radiochemical Engineering Development Center (REDC) at ORNL. REDC recovers and purifies heavy elements (berkelium, californium, einsteinium, and fermium) from irradiated targets for research and industrial applications. Both organic and aqueous waste streams are discharged from REDC. The organic waste is generated from the plutonium/uranium extraction (Purex), Cleanex, and Pubex processes. The Purex waste derives from an organic-aqueous isotope separation process for plutonium and uranium fission products, the Cleanex waste derives from the removal of fission products and other impurities from the americium/curium product, and the Pubex waste is derived from the separation process of plutonium from dissolved targets. MSE had also been tasked to test a grouting formula for the aqueous waste stream that includes radioactive shielding material. The aqueous waste is a mixture of the raffinate streams from the various extraction processes plus the caustic solution that is used to dissolve the aluminum cladding from the irradiated targets. (authors)

Bickford, J. [MSE Technology Applications, Inc., MT (United States); Taylor, P. [Oak Ridge National Laboratory, Oak Ridge, TN (United States)

2007-07-01T23:59:59.000Z

360

Drilling Waste Management Fact Sheet: Slurry Injection of Drilling Wastes  

NLE Websites -- All DOE Office Websites (Extended Search)

Slurry Injection Slurry Injection Fact Sheet - Slurry Injection of Drilling Wastes Underground Injection of Drilling Wastes Several different approaches are used for injecting drilling wastes into underground formations for permanent disposal. Salt caverns are described in a separate fact sheet. This fact sheet focuses on slurry injection technology, which involves grinding or processing solids into small particles, mixing them with water or some other liquid to make a slurry, and injecting the slurry into an underground formation at pressures high enough to fracture the rock. The process referred to here as slurry injection has been given other designations by different authors, including slurry fracture injection (this descriptive term is copyrighted by a company that provides slurry injection services), fracture slurry injection, drilled cuttings injection, cuttings reinjection, and grind and inject.

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures  

SciTech Connect

The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

2013-01-01T23:59:59.000Z

362

Mercury Vapor Release from Broken Compact Fluorescent Lamps and In Situ Capture by New Nanomaterial Sorbents  

Science Journals Connector (OSTI)

There is one report of Hg poisoning (acrodynia) in a child exposed to broken tube-type fluorescents in a detailed case study presented by Tunnessen et al. (6). ... Similar release patterns but lower amounts were seen for spent bulbs (example result 90 ?g in 24 h) or from the fracture site of a new bulb after glass removal to simulate cleanup. ... Artificial lighting systems are transitioning from incandescent to compact fluorescent lamp (CFL) and light-emitting diode (LED) bulbs in response to the U.S. Energy Independence and Security Act and the EU Ecodesign Directive, which leads to energy ... ...

Natalie C. Johnson; Shawn Manchester; Love Sarin; Yuming Gao; Indrek Kulaots; Robert H. Hurt

2008-06-27T23:59:59.000Z

363

Airfoil lance apparatus for homogeneous humidification and sorbent dispersion in a gas stream  

DOE Patents (OSTI)

An apparatus for spraying an atomized mixture into a gas stream comprises a stream line airfoil member having a large radius leading edge and a small radius trailing edge. A nozzle assembly pierces the trailing edge of the airfoil member and is concentrically surrounded by a nacelle which directs shielding gas from the interior of the airfoil member around the nozzle assembly. Flowable medium to be atomized and atomizing gas for atomizing the medium are supplied in concentric conduits to the nozzle. A plurality of nozzles each surrounded by a nacelle are spaced along the trailing edge of the airfoil member. 3 figs.

Myers, R.B.; Yagiela, A.S.

1990-12-25T23:59:59.000Z

364

INJECTION OF SUPERNOVA DUST IN NEARBY PROTOPLANETARY DISKS  

SciTech Connect

The early solar system contained a number of short-lived radionuclides (SLRs) such as {sup 26}Al with half-lives <15 Myr. The one-time presence of {sup 60}Fe strongly suggests that the source of these radionuclides was a nearby supernova. In this paper, we investigate the 'aerogel' model, which hypothesizes that the solar system's SLRs were injected directly into the solar system's protoplanetary disk from a supernova within the same star-forming region. Previous work has shown that disks generally survive the impact of supernova ejecta, but also that little gaseous ejecta can be injected into the disk. The aerogel model hypothesizes that radionuclides in the ejecta condensed into micron-sized dust grains that were injected directly into the solar nebula disk. Here, we discuss the density structure of supernova ejecta and the observational support for dust condensation in the ejecta. We argue that supernova ejecta are clumpy and describe a model to quantify this clumpiness. We also argue that infrared observations may be underestimating the fraction of material that condenses into dust. Building on calculations of how supernova ejecta interact with protoplanetary disks, we calculate the efficiency with which dust grains in the ejecta are injected into a disk. We find that about 70% of material in grains roughly 0.4 {mu}m in diameter can be injected into disks. If ejecta are clumpy, the solar nebula was struck by a clump with higher-than-average {sup 26}Al and {sup 60}Fe, and these elements condensed efficiently into large grains, then the abundances of SLRs in the early solar system can be explained, even if the disk lies 2 pc from the supernova explosion. The probability that all these factors are met is low, perhaps {approx}10{sup -3}-10{sup -2}, and receiving as much {sup 26}Al and {sup 60}Fe as the solar system did may be a rare event. Still, the aerogel model remains a viable explanation for the origins of the radionuclides in the early solar system, and may be the most plausible one.

Ouellette, N. [Department of Physics, Arizona State University, P.O. Box 871504, Tempe, AZ 85287-1504 (United States); Desch, S. J.; Hester, J. J. [School of Earth and Space Exploration, Arizona State University, P.O. Box 871404, Tempe, AZ 85287-1404 (United States)

2010-03-10T23:59:59.000Z

365

Integrated injection-locked semiconductor diode laser  

DOE Patents (OSTI)

A continuous wave integrated injection-locked high-power diode laser array is provided with an on-chip independently-controlled master laser. The integrated injection locked high-power diode laser array is capable of continuous wave lasing in a single near-diffraction limited output beam at single-facet power levels up to 125 mW (250 mW total). Electronic steering of the array emission over an angle of 0.5 degrees is obtained by varying current to the master laser. The master laser injects a laser beam into the slave array by reflection of a rear facet. 18 figures.

Hadley, G.R.; Hohimer, J.P.; Owyoung, A.

1991-02-19T23:59:59.000Z

366

Integrated injection-locked semiconductor diode laser  

DOE Patents (OSTI)

A continuous wave integrated injection-locked high-power diode laser array is provided with an on-chip independently-controlled master laser. The integrated injection locked high-power diode laser array is capable of continuous wave lasing in a single near-diffraction limited output beam at single-facet power levels up to 125 mW (250 mW total). Electronic steering of the array emission over an angle of 0.5 degrees is obtained by varying current to the master laser. The master laser injects a laser beam into the slave array by reflection of a rear facet.

Hadley, G. Ronald (Albuquerque, NM); Hohimer, John P. (Albuquerque, NM); Owyoung, Adelbert (Albuquerque, NM)

1991-01-01T23:59:59.000Z

367

Direct costing  

E-Print Network (OSTI)

oau 5e reduced. Under the same oonOitions, even ~Me on a bread scale entails not mere1y the conduct of the direct oyeraticns cf yrccessing the materials into finished products, but also the performance of auxiliary functions. these may 'ba power y... purposes have been advanced as folkway le Most of a o03RyaxO' 8 products Grc usual13r sold at prices which oovex' full product costs y plus 861ling a%el administrative expenses, plus normal profit. The inventoi~ valuate. on should be consistent...

Browning, Donald Bullock

2012-06-07T23:59:59.000Z

368

Injection of Electrons and Holes into Nanostructures  

NLE Websites -- All DOE Office Websites (Extended Search)

Injection of Electrons and Holes into Nanostructures Injection of Electrons and Holes into Nanostructures This program targets fundamental understanding of nanoscale charge transfer processes. The proposed work draws on the strengths of the Brookhaven Chemistry Department in the areas of electron transfer experiment and theory, and extends the area of inquiry to nanoscale processes. Electron/hole injection into a wire, a nanocrystal, a nanotube or other nanostructure in solution may be brought about by light absorption, by an electron pulse (pulse radiolysis, LEAF), by a chemical reagent, or through an electrode. These processes are being studied by transient methods by following conductivity, current, but most generally, spectroscopic changes in the solutions to determine the dynamics of charge injection. The observed transient spectra can also provide values for electron-transfer coupling elements and energetics. Theoretical/computational studies can help in materials design and in the interpretation of the experimental results. The experimental systems being examined include molecular wires and metal nanoclusters.

369

Injection Locking Techniques for Spectrum Analysis  

SciTech Connect

Wideband spectrum analysis supports future communication systems that reconfigure and adapt to the capacity of the spectral environment. While test equipment manufacturers offer wideband spectrum analyzers with excellent sensitivity and resolution, these spectrum analyzers typically cannot offer acceptable size, weight, and power (SWAP). CMOS integrated circuits offer the potential to fully integrate spectrum analysis capability with analog front-end circuitry and digital signal processing on a single chip. Unfortunately, CMOS lacks high-Q passives and wideband resonator tunability that is necessary for heterodyne implementations of spectrum analyzers. As an alternative to the heterodyne receiver architectures, two nonlinear methods for performing wideband, low-power spectrum analysis are presented. The first method involves injecting the spectrum of interest into an array of injection-locked oscillators. The second method employs the closed loop dynamics of both injection locking and phase locking to independently estimate the injected frequency and power.

Gathma, Timothy D.; Buckwalter, James F. [Department of Electrical and Computer Engineering, University of California San Diego, 9500 Gilman Dr., La Jolla, CA 9209 (United States)

2011-04-19T23:59:59.000Z

370

Resonantly pumped optical pumping injection cavity lasers  

E-Print Network (OSTI)

An optical parametric oscillator is tuned to the resonance wavelength of the etalon in an optical pumping injection cavity (OPIC) laser with a type-II "W" active region, thereby minimizing the threshold pump intensity and ...

Santilli, Michael Robert; McAlpine, T. C.; Greene, K. R.; Olafsen, L. J.; Bewley, W. W.; Felix, C. L.; Vurgaftman, I.; Meyer, J. R.; Lee, H.; Martinelli, R. U.

2004-11-01T23:59:59.000Z

371

Injection Technologies for Fault Attacks on Microprocessors  

Science Journals Connector (OSTI)

The fault injection technique we will analyze in detail in Sect. 16.3, is the constant under-powering of a computing device. By running the chip with a depleted power supply, the attacker is able to insert transi...

Alessandro Barenghi; Guido M. Bertoni; Luca Breveglieri…

2012-01-01T23:59:59.000Z

372

Efficient Spin Injection into Silicon and the Role of the Schottky Barrier  

E-Print Network (OSTI)

Implementing spin functionalities in Si, and understanding the fundamental processes of spin injection and detection, are the main challenges in spintronics. Here we demonstrate large spin polarizations at room temperature, 34% in n-type and 10% in p-type degenerate Si bands, using a narrow Schottky and a SiO2 tunnel barrier in a direct tunneling regime. Furthermore, by increasing the width of the Schottky barrier in non-degenerate p-type Si, we observed a systematic sign reversal of the Hanle signal in the low bias regime. This dramatic change in the spin injection and detection processes with increased Schottky barrier resistance may be due to a decoupling of the spins in the interface states from the bulk band of Si, yielding a transition from a direct to a localized state assisted tunneling. Our study provides a deeper insight into the spin transport phenomenon, which should be considered for electrical spin injection into any semiconductor.

André Dankert; Ravi S. Dulal; Saroj P. Dash

2014-03-12T23:59:59.000Z

373

Smart Materials for Fuel Injection Actuation  

SciTech Connect

The demands of stringent emissions and a robust engine dynamic torque response characteristic require innovative, accurate and repeatable control of the fuel injection event. Recent advances in piezo-material actuators have warranted the pursuit of its application to advanced heavy-duty truck fuel injection systems. This presentation will report on design and testing of an advanced electronic unit injector for the Detroit Diesel Series 60 truck engine.

Hakim, Nabil

2000-08-20T23:59:59.000Z

374

Proper Injection Techniques in Dairy Cattle  

E-Print Network (OSTI)

tissue reaction. Don?t inject more than 10 cc (ml) in one site. If more ? medication must be given, use several injection sites. Use the recommended route of administration. There ? are three main routs of administration. Subcutaneously (SQ... sunlight and in a controlled environment. When finished vaccinating for ? the day, properly dispose of any remaining vaccine. Once a vaccine vial is opened, the expiration date is void. Using sanitary methods Protect needles and medicines ? from dust...

Villarino, Mario A.

2009-05-04T23:59:59.000Z

375

An investigation of high pressure/late cycle injection of CNG (compressed natural gas) as a fuel for rail applications  

SciTech Connect

This report describes a demonstration effort to investigate the use of natural gas in a medium-speed diesel engine. The effort was unique in the sense that natural gas was injected directly into the combustion chamber late in the compression stroke, as a high pressure gas rather than through low pressure fumigation or low pressure injection early in the compression stroke. Tests were performed on a laboratory two-cylinder, two-stroke cycle medium-speed diesel engine in an attempt to define its ability to operate on the high pressure/late cycle injection concept and to define the performance and emission characteristics of the engine under such operation. A small quantity of No.-2 diesel fuel was injected into the cylinder slightly before the gas injection to be used as an ignition source for the gas. Pilot (diesel fuel) and main (natural gas) timing and injection duration were systematically varied to optimize engine performance. The test demonstrated that the medium-speed engine was capable of attaining full rated speed and load (unlike the low pressure approach) with very low percentages of pilot injection with the absence of knock. Thermal efficiency was as much as 10 percent less than thermal efficiency levels obtained with neat diesel fuel. This was primarily due to the placement and injection characteristics of the pilot and main injectors. Optimization of the injection system would undoubtedly result in increased thermal efficiency. 11 figs., 4 tabs.

Wakenell, J.F.; O'Neal, G.G.; Baker, Q.A.; Urban, C.M.

1988-04-01T23:59:59.000Z

376

Injection System and Engine Strategies for Advanced Emission...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Injection System and Engine Strategies for Advanced Emission Standards Injection System and Engine Strategies for Advanced Emission Standards Presentation given at DEER 2006,...

377

Vehicle Technologies Office Merit Review 2014: Fuel Injection...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Injection and Spray Research Using X-Ray Diagnostics Vehicle Technologies Office Merit Review 2014: Fuel Injection and Spray Research Using X-Ray Diagnostics Presentation...

378

Injection risk behavior among women syringe exchangers in San Francisco.  

E-Print Network (OSTI)

injection supplies (cotton, cookers, water, and bleach),injection equipment, such as cookers, cottons, and rinsepartners, n=148 Shared cooker, cotton, or rinse water

Lum, Paula J; Sears, Clare; Guydish, Joseph

2005-01-01T23:59:59.000Z

379

Alabama Injection Project Aimed at Enhanced Oil Recovery, Testing...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alabama Injection Project Aimed at Enhanced Oil Recovery, Testing Important Geologic CO2 Storage Alabama Injection Project Aimed at Enhanced Oil Recovery, Testing Important...

380

Shaking from Injection?Induced Earthquakes in the Central and Eastern United States  

Science Journals Connector (OSTI)

...Ellsworth (2013), hydraulic fracturing or fracking, itself appears to induce only small...largest earthquake associated directly with fracking was an M w-3.8 event in the Horn...waste fluid by injection into subsurface aquifers triggers earthquake swarm in central...

Susan E. Hough

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Transonic Combustion ?- Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine  

Energy.gov (U.S. Department of Energy (DOE))

Novel fuel injection equipment enables knock-free ignition with low noise and smoke in compression-ignition engines and low-particulates in spark-ignition engines.

382

Opacity reduction using hydrated lime injection  

SciTech Connect

The purpose of this investigation is to study the effects of injecting dry hydrated lime into flue gas to reduce sulfur trioxide (SO{sub 3}) concentrations and consequently stack opacity at the University of Missouri, Columbia power plant. Burning of high sulfur coal (approx. 4% by weight) at the power plant resulted in opacity violations. The opacity problem was due to sulfuric acid mist (H{sub 2}SO{sub 4}) forming at the stack from high SO{sub 3} concentrations. As a result of light scattering by the mist, a visible plume leaves the stack. Therefore, reducing high concentrations of SO{sub 3} reduces the sulfuric acid mist and consequently the opacity problem. The current hydrated lime injection system has reduced the opacity to acceptable limits. To reduce SO{sub 3} concentrations, dry hydrated lime is injected into the flue gas upstream of a particulate collection device (baghouse) and downstream of the induced draft fan. The lime is periodically injected into the flue via a pneumatic piping system. The hydrated lime is transported down the flue and deposited on the filter bags in the baghouse. As the hydrated lime is deposited on the bags a filter cake is established. The reaction between the SO{sub 3} and the hydrated lime takes place on the filter bags. The hydrated lime injection system has resulted in at least 95% reduction in the SO{sub 3} concentration. Low capital equipment requirements and operating cost coupled with easy installation and maintenance makes the system very attractive to industries with similar problems. This paper documents the hydrated lime injection system and tests the effectiveness of the system on SO{sub 3} removal and subsequent opacity reduction. Measurements Of SO{sub 3} concentrations, flue gas velocities, and temperatures have been performed at the duct work and baghouse. A complete analysis of the hydrated lime injection system is provided.

Wolf, D.E.; Seaba, J.P. [Univ. of Missouri, Columbia, MO (United States)

1993-12-31T23:59:59.000Z

383

Study of the control strategies on soot reduction under early-injection conditions on a diesel engine  

Science Journals Connector (OSTI)

Abstract To explore the more effective method to fulfill soot reduction challenges of early-injection conditions, different engine operating parameters such as intake pressure, exhaust gas recirculation (EGR), equivalence ratio, intake temperature, coolant temperature, injection pressure and fuel properties such as using the blends of diesel/gasoline, diesel/n-butanol and dual-fuel were investigated on a diesel engine. A wide range of injection timing from 5° CA to ?70° CA ATDC were tested, which covered both conventional diesel injection and early-injection conditions. Results showed that the soot emission increased as the injection timing was advanced from ?35° CA to ?55° CA ATDC, which was attributed to that more spray liquid was out of the piston bowl and impinged on the piston top and cylinder liner. The soot emission decreased as the injection timing further advanced from ?55° to ?70° CA ATDC, which was attributed to the suppressed soot formation. Although more advanced injection (?55° to ?70° CA ATDC) decreased soot emissions, the combustion efficiency was deteriorated. EGR combined with higher intake pressure resulted in lower soot emissions than that of sole EGR control under the same equivalence ratio. Increasing intake temperature and coolant temperature reduced soot emissions at the injection timing later than ?55° CA ATDC but barely affected the soot peak-value. Increasing injection pressure had little impact on soot emissions at early-injection conditions. Regarding to fuel properties, employing the diesel/gasoline and diesel/n-butanol blends dramatically reduced soot emissions and the smokeless combustion was achieved by using pure gasoline or n-heptane. Soot peak-value of diesel/gasoline combustion was higher than that of diesel/n-butanol at low diesel replacement ratio (30%), while for high replacement ratio (70%) the opposite trend was presented. The dual-fuel injection composed by port-injection of gasoline and direct-injection of diesel was more effective in reducing soot emissions than that of single direct-injection under the same gasoline/diesel ratio.

Haifeng Liu; Shuaiying Ma; Zhong Zhang; Zunqing Zheng; Mingfa Yao

2015-01-01T23:59:59.000Z

384

Effects of O{sub 2} and SO{sub 2} on the Capture Capacity of a Primary-Amine Based Polymeric CO{sub 2} Sorbent  

SciTech Connect

Post combustion CO{sub 2} capture is most commonly carried out using an amine solution that results in a high parasitic energy cost in the stripper unit due to the need to heat the water which comprises a majority of the amine solution. It is also well known that amine solvents suffer from stability issues due to amine leaching and poisoning by flue gas impurities. Solid sorbents provide an alternative to solvent systems that would potentially reduce the energy penalty of carbon capture. However, the cost of using a particular sorbent is greatly affected by the usable lifetime of the sorbent. This work investigated the stability of a primary amine-functionalized ion exchange resin in the presence of O{sub 2} and SO{sub 2}, both of which are constituents of flue gas that have been shown to cause degradation of various amines in solvent processes. The CO{sub 2} capture capacity was measured over multiple capture cycles under continuous exposure to two simulated flue gas streams, one containing 12 vol% CO{sub 2}, 4% O{sub 2}, 84% N{sub 2}, and the other containing 12.5 vol% CO{sub 2}, 4% O{sub 2}, 431 ppm SO{sub 2}, balance N{sub 2} using a custom-built packed bed reactor. The resin maintained its CO{sub 2} capture capacity of 1.31 mol/kg over 17 capture cycles in the presence of O{sub 2} without SO{sub 2}. However, the CO{sub 2} capture capacity of the resin decreased rapidly under exposure to SO{sub 2} by an amount of 1.3 mol/kg over 9 capture cycles. Elemental analysis revealed the resin adsorbed 1.0 mol/kg of SO{sub 2}. Thermal regeneration was determined to not be possible. The poisoned resin was, however, partially regenerated with exposure to 1.5M NaOH for 3 days resulting in a 43% removal of sulfur, determined through elemental analysis, and a 35% recovery of CO{sub 2} capture capacity. Evidence was also found for amine loss upon prolonged (7 days) continuous exposure to high temperatures (120 #14;C) in air. It is concluded that desulfurization of the flue gas stream prior to CO{sub 2} capture will greatly improve the economic viability of using this solid sorbent in a post-combustion CO{sub 2} capture process.

Hallenbeck, Alexander P.; Kitchin, John R.

2013-08-01T23:59:59.000Z

385

Carbon Filter Process for Flue-Gas Carbon Capture on Carbonaceous Sorbents: Field Tests of Steam-Aided Vacuum Swing Adsorption  

Science Journals Connector (OSTI)

The final 30 cycles are performed at Pawnee Station, owned by Xcel Energy, in Brush, CO. ... This work was funded by Wyoming’s Enhanced Oil Recovery Institute, Supercritical Fluids LLC, the state of Wyoming’s Clean Coal Program administered by the University of Wyoming’s School of Energy Resources, the Electric Power Research Institute, Pacificorp Energy, Xcel Energy, and a discretionary fund of one of the authors (Maciej Radosz). ... The authors also thank Mr. Ryan Taucher, Pacificorp Energy’s Jim Bridger Power Plant, WY, Mr. Barry Andrews, Xcel Energy’s Pawnee Station, CO, and Dr. Xin Hu, who characterized the sorbents. ...

Bryce Dutcher; Kaspars Krutkramelis; Hertanto Adidharma; Maciej Radosz

2012-03-20T23:59:59.000Z

386

In Situ Infrared Study of the Effect of Amine Density on the Nature of Adsorbed CO2 on Amine-Functionalized Solid Sorbents  

Science Journals Connector (OSTI)

Danon et al. observed that the absorbance band formed at 1701 cm–1 during CO2 adsorption on densely loaded APTES/SBA-15 (DAPS) sorbent shifted to higher frequencies (1714 cm–1) after evacuation of CO2, which they assigned to the surface-bound carbamate species instead of carbamic acid. ... Danon, A.; Stair, P. C.; Weitz, E.FTIR Study of CO2 Adsorption on Amine-Grafted SBA-15: Elucidation of Adsorbed Species J. Phys. ... Danon, Alon; Stair, Peter C.; Weitz, Eric ...

Uma Tumuluri; Mathew Isenberg; Chung-Sung Tan; Steven S. C. Chuang

2014-06-04T23:59:59.000Z

387

Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993  

SciTech Connect

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

Crelling, J.C.

1993-12-31T23:59:59.000Z

388

Magnetic reconnection process in transient coaxial helicity injection  

SciTech Connect

The physics of magnetic reconnection and fast flux closure in transient coaxial helicity injection experiments in NSTX is examined using resistive MHD simulations. These simulations have been performed using the NIMROD code with fixed boundary flux (including NSTX poloidal coil currents) in the NSTX experimental geometry. Simulations show that an X point is formed in the injector region, followed by formation of closed flux surfaces within 0.5 ms after the driven injector voltage and injector current begin to rapidly decrease. As the injector voltage is turned off, the field lines tend to untwist in the toroidal direction and magnetic field compression exerts a radial J × B force and generates a bi-directional radial E{sub toroidal}×B{sub poloidal} pinch flow to bring oppositely directed field lines closer together to reconnect. At sufficiently low magnetic diffusivity (high Lundquist number), and with a sufficiently narrow injector flux footprint width, the oppositely directed field lines have sufficient time to reconnect (before dissipating), leading to the formation of closed flux surfaces. The reconnection process is shown to have transient Sweet-Parker characteristics.

Ebrahimi, F. [Department of Astrophysical Sciences, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Astrophysical Sciences, Princeton University, Princeton, New Jersey 08544 (United States); Hooper, E. B. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Sovinec, C. R. [University of Wisconsin, Madison, Wisconsin 53706 (United States)] [University of Wisconsin, Madison, Wisconsin 53706 (United States); Raman, R. [University of Washington, Seattle, Washington 98195 (United States)] [University of Washington, Seattle, Washington 98195 (United States)

2013-09-15T23:59:59.000Z

389

Research on a Two-Stage Split Injection Control Strategy for Reducing the HC Emission from a GDI Engine during Hot Start  

Science Journals Connector (OSTI)

The start-stop technology is one of the fuel saving strategies at city driving condition, and the gasoline direct injection (GDI) engine can obtain thermal efficiency improvements and fewer heat losses due to the stratified-charge combustion realized ... Keywords: Hydrocarbon emission, engine control, Two-stage, Split injection, start-stop

Shichun Yang; Chong Wang; Chunming Zhao; Kun Deng

2013-12-01T23:59:59.000Z

390

Definition: Injectivity Test | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Injectivity Test Jump to: navigation, search Dictionary.png Injectivity Test A well testing technique conducted upon completion of a well. Water is pumped into the well at a constant rate until a stable pressure is reached then the pump is turned off and the rate at which pressure decreases is measured. The pressure measurements are graphed and well permeability can be calculated.[1] References ↑ https://pangea.stanford.edu/ERE/pdf/IGAstandard/ISS/2008Croatia/Hole03.pdf Ret LikeLike UnlikeLike You and one other like this.One person likes this. Sign Up to see what your friends like. rieved from "http://en.openei.org/w/index.php?title=Definition:Injectivity_Test&oldid=688681"

391

Interaction between Injection Points during Hydraulic Fracturing  

E-Print Network (OSTI)

We present a model of the hydraulic fracturing of heterogeneous poroelastic media. The formalism is an effective continuum model that captures the coupled dynamics of the fluid pressure and the fractured rock matrix and models both the tensile and shear failure of the rock. As an application of the formalism, we study the geomechanical stress interaction between two injection points during hydraulic fracturing (hydrofracking) and how this interaction influences the fracturing process. For injection points that are separated by less than a critical correlation length, we find that the fracturing process around each point is strongly correlated with the position of the neighboring point. The magnitude of the correlation length depends on the degree of heterogeneity of the rock and is on the order of 30-45 m for rocks with low permeabilities. In the strongly correlated regime, we predict a novel effective fracture-force that attracts the fractures toward the neighboring injection point.

Hals, Kjetil M D

2012-01-01T23:59:59.000Z

392

Multistaged stokes injected Raman capillary waveguide amplifier  

DOE Patents (OSTI)

A multistaged Stokes injected Raman capillary waveguide amplifier for providing a high gain Stokes output signal. The amplifier uses a plurality of optically coupled capillary waveguide amplifiers and one or more regenerative amplifiers to increase Stokes gain to a level sufficient for power amplification. Power amplification is provided by a multifocused Raman gain cell or a large diameter capillary waveguide. An external source of CO.sub.2 laser radiation can be injected into each of the capillary waveguide amplifier stages to increase Raman gain. Devices for injecting external sources of CO.sub.2 radiation include: dichroic mirrors, prisms, gratings and Ge Brewster plates. Alternatively, the CO.sub.2 input radiation to the first stage can be coupled and amplified between successive stages.

Kurnit, Norman A. (Santa Fe, NM)

1980-01-01T23:59:59.000Z

393

Mixed Mode Fuel Injector And Injection System  

DOE Patents (OSTI)

A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set that are controlled respectively by first and second three way needle control valves. Each fuel injector includes first and second concentric needle valve members. One of the needle valve members moves to an open position for a homogenous charge injection event, while the other needle valve member moves to an open position for a conventional injection event. The fuel injector has the ability to operate in a homogenous charge mode with a homogenous charge spray pattern, a conventional mode with a conventional spray pattern or a mixed mode.

Stewart, Chris Lee (Normal, IL); Tian, Ye (Bloomington, IL); Wang, Lifeng (Normal, IL); Shafer, Scott F. (Morton, IL)

2005-12-27T23:59:59.000Z

394

300 Area Uranium Stabilization Through Polyphosphate Injection: Final Report  

SciTech Connect

The objective of the treatability test was to evaluate the efficacy of using polyphosphate injections to treat uranium-contaminated groundwater in situ. A test site consisting of an injection well and 15 monitoring wells was installed in the 300 Area near the process trenches that had previously received uranium-bearing effluents. This report summarizes the work on the polyphosphate injection project, including bench-scale laboratory studies, a field injection test, and the subsequent analysis and interpretation of the results. Previous laboratory tests have demonstrated that when a soluble form of polyphosphate is injected into uranium-bearing saturated porous media, immobilization of uranium occurs due to formation of an insoluble uranyl phosphate, autunite [Ca(UO2)2(PO4)2•nH2O]. These tests were conducted at conditions expected for the aquifer and used Hanford soils and groundwater containing very low concentrations of uranium (10-6 M). Because autunite sequesters uranium in the oxidized form U(VI) rather than forcing reduction to U(IV), the possibility of re-oxidation and subsequent re-mobilization is negated. Extensive testing demonstrated the very low solubility and slow dissolution kinetics of autunite. In addition to autunite, excess phosphorous may result in apatite mineral formation, which provides a long-term source of treatment capacity. Phosphate arrival response data indicate that, under site conditions, the polyphosphate amendment could be effectively distributed over a relatively large lateral extent, with wells located at a radial distance of 23 m (75 ft) reaching from between 40% and 60% of the injection concentration. Given these phosphate transport characteristics, direct treatment of uranium through the formation of uranyl-phosphate mineral phases (i.e., autunite) could likely be effectively implemented at full field scale. However, formation of calcium-phosphate mineral phases using the selected three-phase approach was problematic. Although amendment arrival response data indicate some degree of overlap between the reactive species and thus potential for the formation of calcium-phosphate mineral phases (i.e., apatite formation), the efficiency of this treatment approach was relatively poor. In general, uranium performance monitoring results support the hypothesis that limited long-term treatment capacity (i.e., apatite formation) was established during the injection test. Two separate overarching issues affect the efficacy of apatite remediation for uranium sequestration within the 300 Area: 1) the efficacy of apatite for sequestering uranium under the present geochemical and hydrodynamic conditions, and 2) the formation and emplacement of apatite via polyphosphate technology. In addition, the long-term stability of uranium sequestered via apatite is dependent on the chemical speciation of uranium, surface speciation of apatite, and the mechanism of retention, which is highly susceptible to dynamic geochemical conditions. It was expected that uranium sequestration in the presence of hydroxyapatite would occur by sorption and/or surface complexation until all surface sites have been depleted, but that the high carbonate concentrations in the 300 Area would act to inhibit the transformation of sorbed uranium to chernikovite and/or autunite. Adsorption of uranium by apatite was never considered a viable approach for in situ uranium sequestration in and of itself, because by definition, this is a reversible reaction. The efficacy of uranium sequestration by apatite assumes that the adsorbed uranium would subsequently convert to autunite, or other stable uranium phases. Because this appears to not be the case in the 300 Area aquifer, even in locations near the river, apatite may have limited efficacy for the retention and long-term immobilization of uranium at the 300 Area site..

Vermeul, Vincent R.; Bjornstad, Bruce N.; Fritz, Brad G.; Fruchter, Jonathan S.; Mackley, Rob D.; Newcomer, Darrell R.; Mendoza, Donaldo P.; Rockhold, Mark L.; Wellman, Dawn M.; Williams, Mark D.

2009-06-30T23:59:59.000Z

395

Evidence for Separatrix Formation and Sustainment with Steady Inductive Helicity Injection  

Science Journals Connector (OSTI)

The first sustainment of toroidal plasma current of 50 kA at up to 3 times the injected currents, added in quadrature, using steady inductive helicity injection is described. Separatrix currents—currents not linking the helicity injectors—are sustained up to 40 kA. Decreases in the n=1 toroidal mode of the poloidal magnetic field at higher current amplifications indicate more quiescent, direct toroidal current drive. Results are achieved in HIT-SI (with a spheromak of major radius 0.3 m) during deuterium operations immediately after helium operation. These results represent a breakthrough in the development of this new current drive method for magnetic confinement fusion.

B. S. Victor; T. R. Jarboe; A. C. Hossack; D. A. Ennis; B. A. Nelson; R. J. Smith; C. Akcay; C. J. Hansen; G. J. Marklin; N. K. Hicks; J. S. Wrobel

2011-10-12T23:59:59.000Z

396

Spin-Electricity Conversion Induced by Spin Injection into Topological Insulators  

Science Journals Connector (OSTI)

We report successful spin injection into the surface states of topological insulators by using a spin pumping technique. By measuring the voltage that shows up across the samples as a result of spin pumping, we demonstrate that a spin-electricity conversion effect takes place in the surface states of bulk-insulating topological insulators Bi1.5Sb0.5Te1.7Se1.3 and Sn-doped Bi2Te2Se. In this process, the injected spins are converted into a charge current along the Hall direction due to the spin-momentum locking on the surface state.

Y. Shiomi; K. Nomura; Y. Kajiwara; K. Eto; M. Novak; Kouji Segawa; Yoichi Ando; E. Saitoh

2014-11-03T23:59:59.000Z

397

Integrated dry NO{sub x}/SO{sub 2} emissions control systems: Advanced retractable injection lance SNCR test report. NOELL ARIL test period: April 20, 1995--December 21, 1995; DPSC test period: August 16--26, 1996  

SciTech Connect

The test site is Arapahoe Generating Station Unit 4, a 100 MWe down-fired utility boiler burning a low-sulfur western coal. The project goal is to demonstrate up to 70% reductions in NOx and SO{sub 2} emission through the integration of: (1) down-fired low-NOx burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NOx removal; and (3) dry sorbent injection and duct humidification for SO{sub 2} removal. This report documents the third phase of SNCR tests, where an additional injection location was installed to increase the low-load NOx removal performance. The new injectors consist of a pair of retractable in-furnace lances which were designed to provide a high degree of load following flexibility through on-line adjustments of the injection angle. With the new lances, NOx removals in excess of 35% are achievable at the same load and HN{sub 3} slip limit. At loads of 43 to 60 MWe, NOx removals with the lances range from 37--52%. At loads greater than 60 MWe, the wall-injection location is more efficient, and at loads of 70 to 100 MWe, NOx removals range from 37--41%. The coal mill-in-service pattern was found to have a large effect on both NOx removal and NH{sub 3} slip for injection at the new lance location. At 60 MWe, the NOx removal at the 10 ppm NH{sub 3} slip limit ranges from 28--52% depending on the mill-in-service pattern. Biasing the coal mills to provide uniform combustion conditions ahead of the injection location was found to be the best option for improving SNCR system performance under these conditions.

Muzio, L.J.; Smith, R.A. [Fossil Energy Research Corp., Laguna Hills, CA (United States)] [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Co. of Colorado, Denver, CO (United States)] [Public Service Co. of Colorado, Denver, CO (United States)

1997-04-01T23:59:59.000Z

398

Predicting the spatial extent of injection-induced zones of enhanced permeability at the Northwest Geysers EGS Demonstration Project  

SciTech Connect

We present the results of coupled thermal, hydraulic, and mechanical (THM) modeling of a proposed stimulation injection associated with an Enhanced Geothermal System (EGS) demonstration project at the northwest part of The Geysers geothermal field, California. The project aims at creating an EGS by directly and systematically injecting cool water at relatively low pressure into a known High Temperature (about 280 to 350 C) Zone (HTZ) located under the conventional (240 C) steam reservoir at depths below 3 km. Accurate micro-earthquake monitoring from the start of the injection will be used as a tool for tracking the development of the EGS. We first analyzed historic injection and micro-earthquake data from an injection well (Aidlin 11), located about 3 miles to the west of the new EGS demonstration area. Thereafter, we used the same modeling approach to predict the likely extent of the zone of enhanced permeability for a proposed initial injection in two wells (Prati State 31 and Prati 32) at the new EGS demonstration area. Our modeling indicates that the proposed injection scheme will provide additional steam production in the area by creating a zone of permeability enhancement extending about 0.5 km from each injection well which will connect to the overlying conventional steam reservoir.

Rutqvist, J.; Oldenburg, C.M.; Dobson, P.F.

2010-02-01T23:59:59.000Z

399

On the flat length of injective modules  

Science Journals Connector (OSTI)

......that I has a projective resolution of length n + m and hence pdRI n + m. Therefore, spli R n + m, as needed. The second inequality...n - 1. Proof. Let I be an injective left R-module. Then pdRI spli R n and hence Corol- lary 2.12 implies that fdRI n......

Ioannis Emmanouil; Olympia Talelli

2011-10-01T23:59:59.000Z

400

Enhanced oil recovery using hydrogen peroxide injection  

SciTech Connect

NOVATEC received an US Patent on a novel method to recovery viscous oil by hydrogen peroxide injection. The process appears to offer several significant improvements over existing thermal methods of oil recovery. Tejas joined NOVATEC to test the process in the laboratory and to develop oil field applications and procedures.

Moss, J.T. Jr.; Moss, J.T.

1995-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Accounting for Remaining Injected Fracturing Fluid  

E-Print Network (OSTI)

The technology of multi-stage fracturing of horizontal wells made the development of shale gas reservoirs become greatly successful during the past decades. A large amount of fracturing fluid, usually from 53,000 bbls to 81,400 bbls, is injected...

Zhang, Yannan

2013-12-06T23:59:59.000Z

402

Refueling Tokamaks by Injection of Compact Toroids  

Science Journals Connector (OSTI)

It is shown that transverse injection of a hypervelocity high-density spheromak plasmoid into a tokamak plasma may be a viable fueling scheme. Three important processes occur and are discussed individually: establishment of equilibrium, slowing down, and disassembly of the compact toroid.

P. B. Parks

1988-09-19T23:59:59.000Z

403

Injection of solids to lift coastal areas  

Science Journals Connector (OSTI)

...used to inject sand into oil or gas reservoirs because the...in sandstone (Western Missouri) at depths ranging from...Delavaud2006Use of vegetable oil and silica powder for scale...seismicity near the Lacq gas field southwestern FranceJ...

2010-01-01T23:59:59.000Z

404

Passive safety injection system using borated water  

DOE Patents (OSTI)

A passive safety injection system relies on differences in water density to induce natural circulatory flow patterns which help maintain prescribed concentrations of boric acid in borated water, and prevents boron from accumulating in the reactor vessel and possibly preventing heat transfer.

Conway, Lawrence E. (Allegheny, PA); Schulz, Terry L. (Westmoreland, PA)

1993-01-01T23:59:59.000Z

405

Injection of solids to lift coastal areas  

Science Journals Connector (OSTI)

...formations, although additional investigations are needed to improve this...Sparks2006An experimental investigation of sill formation and propagation...fracturing soil to improve remedial actions NTIS report PB91-181818Washington...D. Bolton2004Laboratory investigation of multiple injection into...

2010-01-01T23:59:59.000Z

406

A study on Raman Injection Laser  

E-Print Network (OSTI)

The Raman Injection Laser is a new type of laser which is based on triply resonant stimulated Raman scattering between quantum confined states within the active region of a Quantum Cascade Laser that serves as an internal optical pump. The Raman...

Liu, Debin

2005-11-01T23:59:59.000Z

407

Treatability Test Plan for 300 Area Uranium Stabilization through Polyphosphate Injection  

SciTech Connect

The U.S. Department of Energy has initiated a study into possible options for stabilizing uranium at the 300 Area using polyphosphate injection. As part of this effort, PNNL will perform bench- and field-scale treatability testing designed to evaluate the efficacy of using polyphosphate injections to reduced uranium concentrations in the groundwater to meet drinking water standards (30 ug/L) in situ. This technology works by forming phosphate minerals (autunite and apatite) in the aquifer that directly sequester the existing aqueous uranium in autunite minerals and precipitates apatite minerals for sorption and long term treatment of uranium migrating into the treatment zone, thus reducing current and future aqueous uranium concentrations. Polyphosphate injection was selected for testing based on technology screening as part of the 300-FF-5 Phase III Feasibility Study for treatment of uranium in the 300-Area.

Vermeul, Vincent R.; Williams, Mark D.; Fritz, Brad G.; Mackley, Rob D.; Mendoza, Donaldo P.; Newcomer, Darrell R.; Rockhold, Mark L.; Williams, Bruce A.; Wellman, Dawn M.

2007-06-01T23:59:59.000Z

408

Simultaneous removal of H2S and COS using Zn-based solid sorbents in the bench-scale continuous hot gas desulfurization system integrated with a coal gasifier  

Science Journals Connector (OSTI)

A bench-scale continuous hot gas desulfurization system using Zn-based solid sorbents was developed to remove H2S and COS simultaneously in a 110 Nm3.../h of real coal-gasified syngas. The bench-scale unit, which...

Young Cheol Park; Sung-Ho Jo; Ho-Jung Ryu…

2012-12-01T23:59:59.000Z

409

Feasibility of Injection/Extraction Systems for Muon FFAG Rings in the Neutrino Factory  

SciTech Connect

Non-scaling FFAG rings have been proposed for muon acceleration in a neutrino factory. In order to achieve small orbit excursion and small time of flight variation, lattices with a very compact cell structure and short straight sections are required. The resulting geometry places very challenging constraints on the injection/extraction systems. The feasibility of injection/extraction is discussed and various implementations focusing on minimization of kicker/septum strength are presented. The injection and extraction systems in the nonscaling FFAG for muon acceleration in a neutrino factory were studied in the ring based on FODO lattice. The vertical direction was found to be preferential for both injection and extraction, which allows for lower kicker strengths and facilitates the distribution of kickers due to a lower phase advance per cell in comparison with the horizontal plane. It is possible to design mirror-symmetric schemes in which the kickers can be reused for both signs of muons. The disadvantage of these solutions is a need for special magnets with large aperture in the injection/extraction region due to the large kicked beam oscillations. The strengths of the required kickers are still very challenging and the fields in the septum magnets dictates the need for a superconducting design.

Pasternak, J.; Berg, J.; Aslaninejad, M.; Kelliher, D.; Machida, S.

2010-12-01T23:59:59.000Z

410

BEAMS3D Neutral Beam Injection Model  

SciTech Connect

With the advent of applied 3D fi elds in Tokamaks and modern high performance stellarators, a need has arisen to address non-axisymmetric effects on neutral beam heating and fueling. We report on the development of a fully 3D neutral beam injection (NBI) model, BEAMS3D, which addresses this need by coupling 3D equilibria to a guiding center code capable of modeling neutral and charged particle trajectories across the separatrix and into the plasma core. Ionization, neutralization, charge-exchange, viscous velocity reduction, and pitch angle scattering are modeled with the ADAS atomic physics database [1]. Benchmark calculations are presented to validate the collisionless particle orbits, neutral beam injection model, frictional drag, and pitch angle scattering effects. A calculation of neutral beam heating in the NCSX device is performed, highlighting the capability of the code to handle 3D magnetic fields.

Lazerson, Samuel

2014-04-14T23:59:59.000Z

411

Terahertz graphene lasers: Injection versus optical pumping  

SciTech Connect

We analyze the formation of nonequilibrium states in optically pumped graphene layers and in forward-biased graphene structures with lateral p-i-n junctions and consider the conditions of population inversion and lasing. The model used accounts for intraband and interband relaxation processes as well as deviation of the optical phonon system from equilibrium. As shown, optical pumping suffers from a significant heating of both the electron-hole plasma and the optical phonon system, which can suppress the formation of population inversion. In the graphene structures with p-i-n junction, the injected electrons and holes have relatively low energies, so that the effect of cooling can be rather pronounced, providing a significant advantage of the injection pumping in realization of graphene terahertz lasers.

Ryzhii, Victor; Otsuji, Taiichi [Research Institute for Electrical Communication, Tohoku University, Sendai 980-8577 (Japan); Ryzhii, Maxim [Computational Nanoelectronics Laboratory, University of Aizu, Aizu-Wakamatsu 965-8580 (Japan); Mitin, Vladimir [Department of Electrical Engineering, University at Buffalo, SUNY, Buffalo, New York 14260-1920 (United States)

2013-12-04T23:59:59.000Z

412

Spheromak Formation by Steady Inductive Helicity Injection  

Science Journals Connector (OSTI)

A spheromak is formed for the first time using a new steady state inductive helicity injection method. Using two inductive injectors with odd symmetry and oscillating at 5.8 kHz, a steady state spheromak with even symmetry is formed and sustained through nonlinear relaxation. A spheromak with about 13 kA of toroidal current is formed and sustained using about 3 MW of power. This is a much lower power threshold for spheromak production than required for electrode-based helicity injection. Internal magnetic probe data, including oscillations driven by the injectors, agree with the plasma being in the Taylor state. The agreement is remarkable considering the only fitting parameter is the amplitude of the spheromak component of the state.

T. R. Jarboe; W. T. Hamp; G. J. Marklin; B. A. Nelson; R. G. O’Neill; A. J. Redd; P. E. Sieck; R. J. Smith; J. S. Wrobel

2006-09-15T23:59:59.000Z

413

Waterflooding injectate design systems and methods  

DOE Patents (OSTI)

A method of designing an injectate to be used in a waterflooding operation is disclosed. One aspect includes specifying data representative of chemical characteristics of a liquid hydrocarbon, a connate, and a reservoir rock, of a subterranean reservoir. Charged species at an interface of the liquid hydrocarbon are determined based on the specified data by evaluating at least one chemical reaction. Charged species at an interface of the reservoir rock are determined based on the specified data by evaluating at least one chemical reaction. An extent of surface complexation between the charged species at the interfaces of the liquid hydrocarbon and the reservoir rock is determined by evaluating at least one surface complexation reaction. The injectate is designed and is operable to decrease the extent of surface complexation between the charged species at interfaces of the liquid hydrocarbon and the reservoir rock. Other methods, apparatus, and systems are disclosed.

Brady, Patrick V.; Krumhansl, James L.

2014-08-19T23:59:59.000Z

414

Improved Water Flooding through Injection Brine Modification  

SciTech Connect

Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman; (U of Wyoming)

2003-01-01T23:59:59.000Z

415

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

416

Injection and Extraction Lines for the ILC Damping Rings  

E-Print Network (OSTI)

INJECTION AND EXTRACTION LINES FOR THE ILC DAMPING RINGS ?the injection and extraction lines into and out of the ILCas the design for the abort line. Due to changes of the geo-

Reichel, Ina

2008-01-01T23:59:59.000Z

417

Liquid Propane Injection Technology Conductive to Today's North American Specification  

Energy.gov (U.S. Department of Energy (DOE))

Liquid propane injection technology can offer the same power, torque, and environmental vehicle performance while reducing imports of foreign oil

418

Impact of Extreme Injection Pressure and EGR on the Combustion...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Analyse of the Injection System * Simulation * Hydraulic Characterisation * Optical Spray Diagnostics Engine Investigations * Experimental Results * Optical Combustion...

419

Trapping of Gun-Injected Plasma by a Tokamak  

Science Journals Connector (OSTI)

It is shown that a plasma produced by a Marshall gun can be injected into and trapped by a tokamak plasma. Gun injection raises the line-averaged density and peaks the density profile. Trapping of the gun-injected plasma is explainable in terms of a depolarization current mechanism.

A. W. Leonard; R. N. Dexter; J. C. Sprott

1986-07-21T23:59:59.000Z

420

Gun Injection into a Microwave Plasma J. C. Sprott  

E-Print Network (OSTI)

Gun Injection into a Microwave Plasma by J. C. Sprott May, 1970 Plasma Studies University high densities by rapid pulsed gun injection. TIlis no te describes measurements made -Cwo years ago in which a gun plasma was injected into a background microwave plasma of variable density in the toroidal

Sprott, Julien Clinton

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Near-surface groundwater responses to injection of geothermal wastes  

SciTech Connect

This report assesses the feasibility of injection as an alternative for geothermal wastewater disposal and analyzes hydrologic controls governing the upward migration of injected fluids. Injection experiences at several geothermal developments are presented including the following: Raft River Valley, Salton Sea, East Mesa, Otake, Hatchobaru, and Ahuachapan geothermal fields.

Arnold, S.C.

1984-06-01T23:59:59.000Z

422

Electron Cloud at Injection Region BNL/SNS TECHNICAL NOTE  

E-Print Network (OSTI)

's tangential plane. The stripped electrons from the injection beam cause about 145W thermal damage. They haveElectron Cloud at Injection Region BNL/SNS TECHNICAL NOTE NO. 143 Y.Y. Lee, G. Mahler, W. Meng, D, NEW YORK 11973 #12;1 ELECTRON CLOUD AT INJECTION REGEION Y.Y. Lee, G. Mahler, W. Meng, D. Raparia, L

423

Transient injection-locking of an unstable ring dye laser  

SciTech Connect

The transient injection-locking properties of an unstable ring resonator dye laser have been investigated. When a narrow line optical pulse was injected into the ring resonator, the energy emitted from the ring increased and the lasing spectrum narrowed to that of the injected pulse. However, the polarization control of the emitted radiation was incomplete.

Harris, D.G.; Waite, T.R.; Holmes, D.A. (Rockwell International, Rocketdyne Division, Canoga Park, California 91303 (USA))

1990-04-20T23:59:59.000Z

424

Injection Solvent Effect on Peak Height in Ion Exchange HPLC  

Science Journals Connector (OSTI)

......2. To further evaluate the effect of the injection volume only...injection volume were varied. Effect of weak injection solvent There...same eluent ion strength. The effect of eluent ion strength. Figure...nitrate in the mobile phase. 418 ship of the peak height of phenylacetate......

Hyunjoo Kim Lee; Norman E. Hoffman

1992-10-01T23:59:59.000Z

425

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP  

E-Print Network (OSTI)

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP M. LAMAND Claudine LAB in the injection site. Copper per os dosing is efficient for treating deficient animals (Lamand et al., 1969 consuming. Therefore we tried to per- fect a copper and zinc deficiency treatment allowing the injection

Paris-Sud XI, Université de

426

Experimental Investigation of Optimal Timing of the Diesel Engine Injection Pump Using Biodiesel Fuel  

Science Journals Connector (OSTI)

University of Maribor, Faculty of Mechanical Engineering, Smetanova 17, SI-2000 Maribor ... Compared to mineral diesel, biodiesel and biodiesel blends in general show lower CO, smoke, and HC emissions but higher NOx emission and higher specific fuel consumption. ... In this sense, to gain knowledge about the implications of its use, waste olive oil Me ester was evaluated as a fuel for diesel engines during a 50 h short-term performance test in a diesel direct-injection Perkins engine. ...

Breda Kegl

2006-05-03T23:59:59.000Z

427

Mode-locked terahertz quantum cascade laser by direct phase synchronization  

SciTech Connect

Mode-locking of a terahertz quantum cascade laser is achieved using multimode injection seeding. Contrary to standard methods that rely on gain modulation, here a fixed phase relationship is directly imprinted to the laser modes. In this work, we demonstrate the generation of 9 ps phase mode-locked pulses around 2.75 THz. A direct measurement of the emitted field phase shows that it results from the phase of the initial injection.

Maussang, K.; Maysonnave, J.; Jukam, N.; Freeman, J. R.; Cavalié, P.; Dhillon, S. S.; Tignon, J. [Laboratoire Pierre Aigrain, Ecole Normale Supérieure, CNRS (UMR 8551), Université P. et M. Curie, Université D. Diderot, 75005 Paris (France); Khanna, S. P.; Linfield, E. H.; Davies, A. G. [School of Electronic and Electrical Engineering, University of Leeds, Leeds LS9 2JT (United Kingdom); Beere, H. E.; Ritchie, D. A. [University of Cambridge, Cavendish Lab, Cambridge CB3 0HE (United Kingdom)

2013-12-04T23:59:59.000Z

428

Proof of concept testing of an integrated dry injection system for SO2/NOx control  

SciTech Connect

The objective of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the temperature range of 200{degrees}F--400{degrees}F. Identify the best NO{sub 2} suppressing additive among the group of ammonia, urea, and activated carbon.

Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States)); Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))

1991-01-01T23:59:59.000Z

429

Evaluation of the effects of contaminant injection location and injection method on the determination of overall relative room ventilation efficiency  

E-Print Network (OSTI)

. Figure 3. Figure 4. Figure 5. Figure 6. Calculation of zeroeth moment Calculation of first moment. . 29 30 Diagram of flows in and out of a perfectly mixed room. 30 Floor plan of test room. 31 Carbon dioxide concentration versus time for supply... duct injection point and pulse injection method. 32 Example of use of moments to determine mean age of air. . . . 29 Figure 7. Carbon dioxide concentration versus time for short circuit injection point and pulse injection method. 32 Figure 8...

Pierce, Stephen Dale

1994-01-01T23:59:59.000Z

430

Measurements of injected impurity assimilation during massive gas injection experiments in DIII-D  

SciTech Connect

Impurities (H-2, D-2, He, Ne or Ar) injected into steady (non-disrupting) discharges with massive gas injection (MGI) are shown to mix into the plasma core dominantly via magnetohydrodynamic activity during the plasma thermal quench (TQ). Mixing efficiencies of injected impurities into the plasma core are measured to be of order 0.05-0.4. 0D modelling of the experiments is found to reproduce observed TQ and current quench durations reasonably well (typically within +/- 25% or so), although shutdown onset times are underestimated (by around 2 x). Preliminary 0D modelling of ITER based on DIII-D mixing efficiencies suggests that MGI will work well in ITER with regard to disruption heat load and vessel force mitigation, but may not collisionally suppress runaway electrons.

Hollmann, E. M. [University of California, San Diego; Jernigan, T. C. [Oak Ridge National Laboratory (ORNL); Parks, P. B. [General Atomics; Boedo, J.A. [University of California, San Diego; Evans, T. E. [General Atomics, San Diego; Groth, M. [Lawrence Livermore National Laboratory (LLNL); Humphreys, D A [General Atomics, San Diego; James, A. N. [University of California, San Diego; Lanctot, M J [Columbia University; Nishijima, D. [University of California, San Diego; Rudakov, D.L. [University of California, San Diego; Scott, H A [Lawrence Livermore National Laboratory (LLNL); Strait, E. J. [General Atomics; Van Zeeland, Michael [General Atomics; Wesley, J. C. [General Atomics; West, J C [General Atomics, San Diego; Wu, W [General Atomics, San Diego; Yu, J.H. [University of California, San Diego

2008-01-01T23:59:59.000Z

431

E-Print Network 3.0 - ar injection experiment Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

in 553AR. The cumulative steam injected after 400 days on injection and the injection rate both similar... ... Source: Patzek, Tadeusz W. - Department of Petroleum and...

432

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents (OSTI)

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

433

Direct memory access transfer completion notification  

DOE Patents (OSTI)

Methods, apparatus, and products are disclosed for DMA transfer completion notification that include: inserting, by an origin DMA engine on an origin compute node in an injection FIFO buffer, a data descriptor for an application message to be transferred to a target compute node on behalf of an application on the origin compute node; inserting, by the origin DMA engine, a completion notification descriptor in the injection FIFO buffer after the data descriptor for the message, the completion notification descriptor specifying an address of a completion notification field in application storage for the application; transferring, by the origin DMA engine to the target compute node, the message in dependence upon the data descriptor; and notifying, by the origin DMA engine, the application that the transfer of the message is complete, including performing a local direct put operation to store predesignated notification data at the address of the completion notification field.

Archer, Charles J. (Rochester, MN); Blocksome, Michael A. (Rochester, MN); Parker, Jeffrey J. (Rochester, MN)

2010-08-17T23:59:59.000Z

434

Partially Premixed Combustion in a Diesel Engine Induced by a Pilot Injection at the Low-pressure Top Dead Center  

Science Journals Connector (OSTI)

The engine used in this research is a single-cylinder, four-stroke, direct-injection diesel research engine since this type of facility generates much more accurate data compared to multicylinder engines. ... Aside from those considerations on the general evolution of ISFC with respect to the EPI ratio, a peak of ISFC appears at EPI ratio of 30%. ... (Professional Engineering Publishing Ltd.) ...

Jesús Benajes; Ricardo Novella; Antonio García; Simon Arthozoul

2009-05-07T23:59:59.000Z

435

Admixture enhanced controlled low-strength material for direct underwater injection with minimal cross-contamination  

SciTech Connect

Commercially available admixtures have been developed for placing traditional concrete products under water. This paper evaluates adapting anti-washout admixture (AWA) and high range water reducing admixture (HRWRA) products to enhance controlled low-strength materials (CLSMs) for underwater placement. A simple experimental scale model (based on dynamic and geometric similitude) of typical grout pump emplacement equipment has been developed to determine the percentage of cementing material washed out. The objective of this study was to identify proportions of admixtures and underwater CLSM emplacement procedures which would minimize the cross-contamination of the displaced water while maintaining the advantages of CLSM. Since the displaced water from radioactively contaminated systems must be subsequently treated prior to release to the environment, the amount of cross-contamination is important for cases in which cementing material could form hard sludges in a water treatment facility and contaminate the in-place CLSM stabilization medium.

Hepworth, H.K.; Davidson, J.S.; Hooyman, J.L.

1997-03-01T23:59:59.000Z

436

Turbocharged Spark Ignited Direct Injection- A Fuel Economy Solution for The US  

Energy.gov (U.S. Department of Energy (DOE))

Turbocharged SIDI is the most promising advanced gasoline technology; combines existing & proven technologies in a synergistic manner, offers double digit fuel economy benefits, much lower cost than diesel or hybrid.

437

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection  

Energy.gov (U.S. Department of Energy (DOE))

This fact sheet describes a new technology with the potential to reduce operating costs and increase productivity in bar and flat-rolled products for the steel industry.

438

Evaluation of Oxydiesel as a Fuel for Direct-Injection Compression-Ignition Engines  

E-Print Network (OSTI)

speed and maximum power for 500 hours on a blend of ethanol, No. 2 diesel, and an additive as compared and diesel with a special additive, has been shown to be a promising new alternative fuel for existing diesel the mixing of diesel fuel with ethanol. The Illinois DCCA has embarked on a widespread research program

Illinois at Urbana-Champaign, University of

439

Mixing Correlations for Smoke and Fuel Consumption of Direct Injection Engines  

Science Journals Connector (OSTI)

The mixing of fuel with air in a diesel engine strongly dictates the specific fuel consumption and exhaust smoke. Many experimental studies reported the optimum swirl for a given diesel engine at a given operatin...

P. A. Lakshminarayanan; Yogesh V. Aghav

2010-01-01T23:59:59.000Z

440

Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions  

Energy.gov (U.S. Department of Energy (DOE))

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

Note: This page contains sample records for the topic "direct sorbent injection" from the National Library of EnergyBeta (NLEBeta).
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441

Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions  

Energy.gov (U.S. Department of Energy (DOE))

2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

442

Improving gasoline direct injection (GDI) engine efficiency and emissions with hydrogen from exhaust gas fuel reforming  

Science Journals Connector (OSTI)

Abstract Exhaust gas fuel reforming has been identified as a thermochemical energy recovery technology with potential to improve gasoline engine efficiency, and thereby reduce CO2 in addition to other gaseous and particulate matter (PM) emissions. The principle relies on achieving energy recovery from the hot exhaust stream by endothermic catalytic reforming of gasoline and a fraction of the engine exhaust gas. The hydrogen-rich reformate has higher enthalpy than the gasoline fed to the reformer and is recirculated to the intake manifold, i.e. reformed exhaust gas recirculation (REGR). The REGR system was simulated by supplying hydrogen and carbon monoxide (CO) into a conventional EGR system. The hydrogen and CO concentrations in the REGR stream were selected to be achievable in practice at typical gasoline exhaust temperatures. Emphasis was placed on comparing REGR to the baseline gasoline engine, and also to conventional EGR. The results demonstrate the potential of REGR to simultaneously increase thermal efficiency, reduce gaseous emissions and decrease PM formation.

Daniel Fennell; Jose Herreros; Athanasios Tsolakis

2014-01-01T23:59:59.000Z

443

Laser-induced ignition and combustion in a SI engine with direct injection  

Science Journals Connector (OSTI)

Laser-induced ignition has shown huge advantages for the combustion ... (KIT) to investigate the potential of the laser-induced ignition. The emphasis was on improving combustion initiation...

Dipl.-Ing. Volker Gross; Dr.-Ing. Heiko Kubach…

2010-07-01T23:59:59.000Z

444

Vehicle Technologies Office Merit Review 2014: Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Ford Motor Companyh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced gasoline...

445

Determination of Volatile Compounds in Cider Spirits by Gas Chromatography with Direct Injection  

Science Journals Connector (OSTI)

......described for cider and wine distillates (4,5...used were of analytical quality, of at least 97% purity...liquid chromatography quality) was purchased from...levels of above 1 g/L) increases. Moreover, the life...repercussion on the aromatic quality. Sci. Aliments 22......

Roberto Rodríguez Madrera; Belén Suárez Valles

2007-08-01T23:59:59.000Z

446

Directives Quarterly Updates  

Directives, Delegations, and Requirements

Listings of new Justification Memoranda and new or revised Directives that have been posted to the DOE Directives, Delegations, and Requirements Portal. Updated quarterly.

447

Another face of DIRECT  

E-Print Network (OSTI)

authors, see for example, tree-Direct [5]. This paper ..... [4] J.M. Gablonsky, Modifications of the DIRECT Algorithm, Ph.D. Thesis, North Carolina State. University ...

chiter

2007-08-01T23:59:59.000Z

448

Duct injection technology prototype development: Nozzle development Subtask 4. 1, Atomizer specifications for duct injection technology  

SciTech Connect

Babcock Wilcox has conducted a program to identify atomizers appropriate for successful in-duct injection of humidification water and lime slurries. The purpose of this program was to identify and quantify atomizer spray and performance criteria that affect the operations and reliability of the in-duct SO{sub 2} removal process, and compare commercially available atomizers to these criteria.

Not Available

1992-02-01T23:59:59.000Z

449

GAS INJECTION/WELL STIMULATION PROJECT  

SciTech Connect

Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional