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1

Carbon Dioxide Sequestration by Direct Mineral Carbonation: Results...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration by Direct Mineral Carbonation: Results from Recent Studies and Current Status W.K. OConnor (oconnor@alrc.doe.gov) D.C. Dahlin (dahlin@alrc.doe.gov) D.N Nilsen...

2

NETL Mineral Carbonation Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Overview Overview Mineral Carbonation Workshop August 8, 2001 Carl O. Bauer, Associate Laboratory Director Descriptor - include initials, /org#/date We Are: * One of DOE's 15 national laboratories * Government owned and operated * Sites in Oklahoma, Pennsylvania, and West Virginia * Over 1,100 federal and support contractor employees * FY01 budget of $774 million July 2001 Descriptor - include initials, /org#/date Sites in Pennsylvania, West Virginia, Oklahoma Morgantown, WV Pittsburgh, PA Tulsa, OK Descriptor - include initials, /org#/date Our Mission * Resolve the environmental, supply, and reliability constraints of producing and using fossil resources to provide Americans with a stronger economy, healthier environment, and more secure future * Support development and deployment of environmental technologies that reduce

3

Multiphase Sequestration Geochemistry: Model for Mineral Carbonation  

SciTech Connect

Carbonation of formation minerals converts low viscosity supercritical CO2 injected into deep saline reservoirs for geologic sequestration into an immobile form. Until recently the scientific focus of mineralization reactions with reservoir rocks has been those that follow an aqueous-mediated dissolution/precipitation mechanism, driven by the sharp reduction in pH that occurs with CO2 partitioning into the aqueous phase. For sedimentary basin formations the kinetics of aqueous-mediated dissolution/precipitation reactions are sufficiently slow to make the role of mineralization trapping insignificant over a century period. For basaltic saline formations aqueous-phase mineralization progresses at a substantially higher rate, making the role of mineralization trapping significant, if not dominant, over a century period. The overlooked mineralization reactions for both sedimentary and basaltic saline formations, however, are those that occur in liquid or supercritical CO2 phase; where, dissolved water appears to play a catalyst role in the formation of carbonate minerals. A model is proposed in this paper that describes mineral carbonation over sequestration reservoir conditions ranging from dissolved CO2 in aqueous brine to dissolved water in supercritical CO2. The model theory is based on a review of recent experiments directed at understanding the role of water in mineral carbonation reactions of interest in geologic sequestration systems occurring under low water contents.

White, Mark D.; McGrail, B. Peter; Schaef, Herbert T.; Hu, Jian Z.; Hoyt, David W.; Felmy, Andrew R.; Rosso, Kevin M.; Wurstner, Signe K.

2011-04-01T23:59:59.000Z

4

Reduction of carbon dioxide emissions by mineral carbonation  

Science Conference Proceedings (OSTI)

The study investigates the technologies that have the potential to provide feasible reduction of carbon dioxide (CO2) from a reference power plant. Particular focus has been given to mineral carbonation (at 1 bar) in which magnesium (Mg) and/or ... Keywords: carbon dioxide, emissions, mineral carbonation

C. J. Sturgeon; M. G. Rasul; Ashfaque Ahmed Chowdhury

2010-02-01T23:59:59.000Z

5

Integrating Steel Production with Mineral Carbon Sequestration  

Science Conference Proceedings (OSTI)

The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

2008-05-01T23:59:59.000Z

6

Carbon Dioxide Sequestration: Aqueous Mineral Carbonation Studies...  

NLE Websites -- All DOE Office Websites (Extended Search)

appears independent of test time * Agitation phenomena (?) Solid product passes EPA TCLP Pittsburgh, PA, August 8, 2001 National Energy Technology Laboratory: Mineral...

7

Carbon dioxide sequestration in cement kiln dust through mineral carbonation  

Science Conference Proceedings (OSTI)

Carbon sequestration through the formation of carbonates is a potential means to reduce CO{sub 2} emissions. Alkaline industrial solid wastes typically have high mass fractions of reactive oxides that may not require preprocessing, making them an attractive source material for mineral carbonation. The degree of mineral carbonation achievable in cement kiln dust (CKD) under ambient temperatures and pressures was examined through a series of batch and column experiments. The overall extent and potential mechanisms and rate behavior of the carbonation process were assessed through a complementary set of analytical and empirical methods, including mass change, thermal analysis, and X-ray diffraction. The carbonation reactions were carried out primarily through the reaction of CO{sub 2} with Ca(OH){sub 2}, and CaCO{sub 3} was observed as the predominant carbonation product. A sequestration extent of over 60% was observed within 8 h of reaction without any modifications to the waste. Sequestration appears to follow unreacted core model theory where reaction kinetics are controlled by a first-order rate constant at early times; however, as carbonation progresses, the kinetics of the reaction are attenuated by the extent of the reaction due to diffusion control, with the extent of conversion never reaching completion. 35 refs., 3 figs., 1 tab.

Deborah N. Huntzinger; John S. Gierke; S. Komar Kawatra; Timothy C. Eisele; Lawrence L. Sutter [University of Michigan, Ann Arbor, MI (United States). Department of Civil and Environmental Engineering

2009-03-15T23:59:59.000Z

8

SkyMine Carbon Mineralization Pilot Project  

Science Conference Proceedings (OSTI)

This Topical Report addresses accomplishments achieved during Phase 1 of the SkyMine{reg_sign} Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO{sub 2} from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO{sub 2} to products having commercial value (i.e., beneficial use), show the economic viability of the CO{sub 2} capture and conversion process, and thereby advance the technology to a point of readiness for commercial scale demonstration and proliferation. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at commercial scale. The primary objectives of Phase 1 of the project were to elaborate proven SkyMine{reg_sign} process chemistry to commercial pilot-scale operation and complete the preliminary design ('Reference Plant Design') for the pilot plant to be built and operated in Phase 2. Additionally, during Phase 1, information necessary to inform a DOE determination regarding NEPA requirements for the project was developed, and a comprehensive carbon lifecycle analysis was completed. These items were included in the formal application for funding under Phase 2. All Phase 1 objectives were successfully met on schedule and within budget.

Joe Jones; Clive Barton; Mark Clayton; Al Yablonsky; David Legere

2010-09-30T23:59:59.000Z

9

Carbonate Mineralization of Volcanic Province Basalts  

Science Conference Proceedings (OSTI)

Flood basalts are receiving increasing attention as possible host formations for geologic sequestration of anthropogenic CO2, with studies underway in the United States, India, Iceland, and Canada. As an extension of our previous experiments with Columbia River basalt, basalts from the eastern United States, India, and South Africa were reacted with aqueous dissolved CO2 and aqueous dissolved CO2-H2S mixtures under supercritical CO2 (scCO2) conditions to study the geochemical reactions resulting from injection of CO2 in such formations. The results of these studies are consistent with cation release behavior measured in our previous experiments (in press) for basalt samples tested in single pass flow through dissolution experiments under dilute solution and mildly acidic conditions. Despite the basalt samples having similar bulk chemistry, mineralogy and apparent dissolution kinetics, long-term static experiments show significant differences in rates of mineralization as well as compositions and morphologies of precipitates that form when the basalts are reacted with CO2-saturated water. For example, basalt from the Newark Basin in the United States was by far the most reactive of any basalt tested to date. Carbonate reaction products for the Newark Basin basalt were globular in form and contained significantly more Fe than the secondary carbonates that precipitated on the other basalt samples. In comparison, the post-reacted samples associated with the Columbia River basalts from the United States contained calcite grains with classic dogtooth spar morphology and trace cation substitution (Mg and Mn). Carbonation of the other basalts produced precipitates with compositions that varied chemically throughout the entire testing period. Examination of polished cross sections of the reacted grains by scanning electron microscopy and energy dispersive x-ray spectroscopy show precipitate overgrowths with varying chemical compositions. Compositional differences in the precipitates suggest changes in fluid chemistry unique to the dissolution behavior of each basalt sample reacted with CO2-saturated water. The Karoo basalt from South Africa appeared the least reactive, with very limited mineralization occurring during the testing with CO2-saturated water. The relative reactivity of different basalt samples were unexpectedly different in the experiments conducted using aqueous dissolved CO2-H2S mixtures versus those reacted with aqueous dissolved CO2 mixtures. For example, the Karoo basalt was highly reactive in the presence of aqueous dissolved CO2-H2S, as evident by small nodules of carbonate coating the basalt grains after 181 days of testing. However the most reactive basalt in CO2-H2O, Newark Basin, formed limited amounts of carbonate precipitates in the presence of aqueous dissolved CO2-H2S mixture. Basalt reactivity in CO2-H2O mixtures appears to be controlled by the composition of the glassy mesostasis, which is the most reactive component in the basalt rock. With the addition of H2S to the CO2-H2O system, basalt reactivity appears to be controlled by precipitation of coatings of insoluble Fe sulfides.

Schaef, Herbert T.; McGrail, B. Peter; Owen, Antionette T.

2010-03-31T23:59:59.000Z

10

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone  

Open Energy Info (EERE)

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Details Activities (3) Areas (1) Regions (0) Abstract: Oxygen and carbon isotope ratios were measured for hydrothermal minerals (silica, clay and calcite) from fractures and vugs in altered rhyolite, located between 28 and 129 m below surface (in situ temperatures ranging from 81 to 199°C) in Yellowstone drill holes. The purpose of this study was to investigate the mechanism of formation of these minerals. The Δ18O values of the thirty-two analyzed silica samples (quartz, chalcedony, α-cristobalite, and β-cristobalite) range from -7.5 to +2.8‰. About one

11

A disconnect between O horizon and mineral soil carbon - Implications for soil C sequestration  

Science Conference Proceedings (OSTI)

Changing inputs of carbon to soil is one means of potentially increasing carbon sequestration in soils for the purpose of mitigating projected increases in atmospheric CO{sub 2} concentrations. The effect of manipulations of aboveground carbon input on soil carbon storage was tested in a temperate, deciduous forest in east Tennessee, USA. A 4.5-year experiment included exclusion of aboveground litterfall and supplemental litter additions (three times ambient) in an upland and a valley that differed in soil nitrogen availability. The estimated decomposition rate of the carbon stock in the O horizon was greater in the valley than in the upland due to higher litter quality (i.e., lower C/N ratios). Short-term litter exclusion or addition had no effect on carbon stock in the mineral soil, measured to a depth of 30 cm, or the partitioning of carbon in the mineral soil between particulate- and mineral-associated organic matter. A two-compartment model was used to interpret results from the field experiments. Field data and a sensitivity analysis of the model were consistent with little carbon transfer between the O horizon and the mineral soil. Increasing aboveground carbon input does not appear to be an effective means of promoting carbon sequestration in forest soil at the location of the present study because a disconnect exists in carbon dynamics between O horizon and mineral soil. Factors that directly increase inputs to belowground soil carbon, via roots, or reduce decomposition rates of organic matter are more likely to benefit efforts to increase carbon sequestration in forests where carbon dynamics in the O horizon are uncoupled from the mineral soil.

Garten Jr, Charles T [ORNL

2009-01-01T23:59:59.000Z

12

Chemically Accelerated Carbon Mineralization: Chemical and Biological Catalytic Enhancement of Weathering of Silicate Minerals as Novel Carbon Capture and Storage  

SciTech Connect

IMPACCT Project: Columbia University is developing a process to pull CO2 out of the exhaust gas of coal-fired power plants and turn it into a solid that can be easily and safely transported, stored above ground, or integrated into value-added products (e.g. paper filler, plastic filler, construction materials, etc.). In nature, the reaction of CO2 with various minerals over long periods of time will yield a solid carbonatethis process is known as carbon mineralization. The use of carbon mineralization as a CO2 capture and storage method is limited by the speeds at which these minerals can be dissolved and CO2 can be hydrated. To facilitate this, Columbia University is using a unique process and a combination of chemical catalysts which increase the mineral dissolution rate, and the enzymatic catalyst carbonic anhydrase which speeds up the hydration of CO2.

2010-07-01T23:59:59.000Z

13

Direct Carbon Fuel Cell Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Direct Carbon Fuel Cell Workshop Direct Carbon Fuel Cell Workshop July 30, 2003 Table of Contents Disclaimer Papers and Presentations Carbon Anode Electrochemistry Carbon Conversion Fuel Cells Coal Preprocessing Prior to Introduction Into the Fuel Cell Potential Market Applications for Direct Carbon Fuel Cells Discussion of Key R&D Needs Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

14

Reaction Kinetics of CO2 Carbonation with Mg-Rich Minerals  

SciTech Connect

Due to their low price, wide availability, and stability of the resulting carbonates, Mg-rich minerals are promising materials for carbonating CO{sub 2}. Direct carbonation of CO{sub 2} with Mg-rich minerals reported in this research for the first time could be considerably superior to conventional liquid extraction processes from an energy consumption perspective due to its avoidance of the use of a large amount of water with high specific heat capacity and latent heat of vaporization. Kinetic models of the reactions of the direct CO{sub 2} carbonation with Mg-rich minerals and within simulated flue gas environments are important to the scale-up of reactor designs. Unfortunately, such models have not been made available thus far. This research was initiated to fill that gap. Magnesium silicate (Mg{sub 2}SiO{sub 4}), a representative compound in Mg-rich minerals, was used to study CO{sub 2} carbonation reaction kinetics under given simulated flue gas conditions. It was found that the chosen sorbent deactivation model fits well the experimental data collected under given conditions. A reaction order of 1 with respect to CO{sub 2} is obtained from experimental data. The Arrhenius form of CO{sub 2} carbonation with Mg{sub 2}SiO{sub 4} is established based on changes in the rate constants of the chosen deactivation model as a function of temperature.

Kwon, Dr. Soonchul [Georgia Institute of Technology; Fan, Maohong [University of Wyoming, Laramie; DaCosta, Dr. Herbert F.M. [Chem-Innovations Inc; Russell, Dr. Armistead [Georgia Institute of Technology; Tsouris, Costas [ORNL

2011-01-01T23:59:59.000Z

15

carbon sequestration via direct injection  

NLE Websites -- All DOE Office Websites (Extended Search)

SEQUESTRATION VIA DIRECT INJECTION SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams INTRODUCTION The build-up of carbon dioxide (CO 2 ) and other greenhouse gases in the Earth's atmosphere has caused concern about possible global climate change. As a result, international negotiations have produced the Framework Convention on Climate Change (FCCC), completed during the 1992 Earth Summit in Rio de Janeiro. The treaty, which the United States has ratified, calls for the "stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system." The primary greenhouse gas is CO 2 , which is estimated to contribute to over two-thirds of any climate change. The primary source of CO

16

A method for permanent CO2 mineral carbonation  

SciTech Connect

The Albany Research Center (ARC) of the U.S. Department of Energy (DOE) has been conducting research to investigate the feasibility of mineral carbonation as a method for carbon dioxide (CO2) sequestration. The research is part of a Mineral Carbonation Study Program within the Office of Fossil Energy in DOE. Other participants in this Program include DOE?s Los Alamos National Laboratory and National Energy Technology Laboratory, Arizona State University, and Science Applications International Corporation. The research has focused on ex-situ mineral carbonation in an aqueous system. The process developed at ARC reacts a slurry of magnesium silicate mineral with supercritical CO2 to produce a solid magnesium carbonate product. To date, olivine and serpentine have been used as the mineral reactant, but other magnesium silicates could be used as well. The process is designed to simulate the natural serpentinization reaction of ultramafic minerals, and consequently, these results may also be applicable to strategies for in-situ geological sequestration. Baseline tests were begun in distilled water on ground products of foundry-grade olivine. Tests conducted at 150 C and subcritical CO2 pressures (50 atm) resulted in very slow conversion to carbonate. Increasing the partial pressure of CO2 to supercritical (>73 atm) conditions, coupled with agitation of the slurry and gas dispersion within the water column, resulted in significant improvement in the extent of reaction in much shorter reaction times. A change from distilled water to a bicarbonate/salt solution further improved the rate and extent of reaction. When serpentine, a hydrated mineral, was used instead of olivine, extent of reaction was poor until heat treatment was included prior to the carbonation reaction. Removal of the chemically bound water resulted in conversion to carbonate similar to those obtained with olivine. Recent results have shown that conversions of nearly 80 pct are achievable after 30 minutes at test conditions of 155 C and 185 atm CO2 in a bicarbonate/salt solution. The results from the current studies suggest that reaction kinetics can be further improved. Future tests will examine additional pressure/temperature regimes, various pretreatment options,and solution modifications.

Dahlin, David C.; O'Connor, William K.; Nilsen, David N.; Rush, G.E.; Walters, Richard P.; Turner, Paul C.

2000-01-01T23:59:59.000Z

17

Development of a CO2 Sequestration Module by Integrating Mineral Activation and Aqueous Carbonation  

SciTech Connect

Mineral carbonation is a promising concept for permanent CO{sub 2} sequestration due to the vast natural abundance of the raw materials and the permanent storage of CO{sub 2} in solid form as carbonates. The sequestration of CO{sub 2} through the employment of magnesium silicates--olivine and serpentine--is beyond the proof of concept stage. For the work done in this project, serpentine was chosen as the feedstock mineral due to its abundance and availability. Although the reactivity of olivine is greater than that of serpentine, physical and chemical treatments have been shown to increase greatly the reactivity of serpentine. The primary drawback to mineral carbonation is reaction kinetics. To accelerate the carbonation, aqueous processes are preferred, where the minerals are first dissolved in solution. In aqueous carbonation, the key step is the dissolution rate of the mineral, where the mineral dissolution reaction is likely to be surface-controlled. The relatively low reactivity of serpentine has warranted research into physical and chemical treatments that have been shown to greatly increase its reactivity. The use of sulfuric acid as an accelerating medium for the removal of magnesium from serpentine has been investigated. To accelerate the dissolution process, the mineral can be ground to very fine particle size, <37 {micro}m, but this is a very energy-intensive process. Previous work in our laboratory showed that chemical surface activation helps to dissolve magnesium from the serpentine (of particle size {approx} 100 {micro}m) and that the carbonation reaction can be conducted under mild conditions (20 C and 4.6 MPa) compared to previous studies that required >185 C, >13 MPa, and <37 {micro}m particle size. This work also showed that over 70% of the magnesium can be extracted at ambient temperature, leaving an amorphous silica with surface area of about 330 m{sup 2}/g. The overall objective of this research program is to optimize the active carbonation process to design an integrated CO{sub 2} sequestration module. A parametric study was conducted to optimize conditions for mineral activation, in which serpentine and sulfuric acid were reacted. The study focused on the effects of varying the acid concentration, particle size, and reaction time. The reaction yield was as high as 48% with a 5 M acid concentration, with lower values directly corresponding to lower acid concentrations. Significant improvements in the removal of moisture, as well as in the dissolution, can be realized with comminution of particles to a D{sub 50} less than 125 ?m. A minimum threshold of 3 M concentration of sulfuric acid was found to exist in terms of removal of moisture from serpentine. The effect of reaction time was insignificant. The treated serpentine had low BET surface areas. Results demonstrated that acid concentration provided primary control on the dissolution via the removal of water, which is closely correlated with the extraction of magnesium from serpentine. Single-variable experimentation demonstrated dissolution enhancements with increased reaction time and temperature. An increase in magnesium dissolution of 46% and 70%, relative to a baseline test, occurred for increased reaction time and temperature, respectively. In addition to the challenges presented by the dissolution of serpentine, another challenge is the subsequent carbonation of the magnesium ions. A stable hydration sphere for the magnesium ion reduces the carbonation kinetics by obstructing the formation of the carbonation products. Accordingly, this research has evaluated the solubility of carbon dioxide in aqueous solution, the interaction between the dissociation products of carbon dioxide, and the carbonation potential of the magnesium ion.

George Alexander; Parvana Aksoy; John Andresen; Mercedes Maroto-Valer; Harold Schobert

2006-08-14T23:59:59.000Z

18

Carbon aerogel electrodes for direct energy conversion  

DOE Patents (OSTI)

A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome.

Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

1997-01-01T23:59:59.000Z

19

Carbon aerogel electrodes for direct energy conversion  

DOE Patents (OSTI)

A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes is described, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome. 1 fig.

Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

1997-02-11T23:59:59.000Z

20

Assessment of Direct Carbon Fuel Cells  

Science Conference Proceedings (OSTI)

Fuel cells have been under development for stationary power applications because of their high fuel efficiency and low emission characteristics. Research and development of direct carbon fuel cells (DCFC) that can use carbon as a fuel have been identified as an emerging option that needs further assessment and test validation. This project is one of several EPRI fuel cell projects that is investigating the technical and performance characteristics of fuel cells and their potential to impact electric util...

2005-02-16T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Developing a Mechanistic Understanding of Lamellar Hydroxide Mineral Carbonation Reaction Processes to Reduce CO2 Mineral Sequestration Process Cost  

NLE Websites -- All DOE Office Websites (Extended Search)

Mechanistic Understanding of Lamellar Hydroxide Mechanistic Understanding of Lamellar Hydroxide Mineral Carbonation Reaction Processes to Reduce CO 2 Mineral Sequestration Process Cost Michael J. McKelvy (mckelvy@asu.edu; 480-965-4535), Andrew V. G. Chizmeshya (chizmesh@asu.edu; 480-965-6072), Hamdallah Bearat (Hamdallah.Bearat@asu.edu; 480-965-2624), Renu Sharma (Renu.Sharma@asu.edu; 480-965-4541), and Ray W. Carpenter (carpenter@asu.edu; 480-965-4549) Center for Solid State Science and Science and Engineering of Materials PhD Program, P.O. Box 871704, Arizona State University, Tempe, Arizona 85287 USA ABSTRACT The potential environmental effects of increasing atmospheric CO 2 levels are of major worldwide concern. One alternative for managing CO 2 emissions is carbon sequestration: the capture and secure confinement of CO

22

Research on Using Carbide Slag to Mineralize the Carbon Dioxide ...  

Science Conference Proceedings (OSTI)

... we come up with the crafts of using waste calcium carbide to mineralize CO2 in electrolytic aluminum waste gas, design and make out Venturi gas-liquid-solid...

23

Solar-grade silicon by directional solidification in carbon crucibles  

Science Conference Proceedings (OSTI)

Directional solidification of silicon in carbon crucibles was achieved by using two variations of the Bridgman-Stockbarger method. One was a static technique wherein liquid silicon in a carbon crucible was positioned in a tamperature gradient of about ...

T. F. Ciszek; G. H. Schwuttke; K. H. Yang

1979-05-01T23:59:59.000Z

24

Directed-Assembly of Carbon Nanotubes (CNTs)  

Alex Zettl and Yan Mei Wang have taken another step toward enabling the commercialization of nanoscale carbon-based electronic ...

25

DIRECT OBSERVATION OF CARBON NANOTUBE GROWTH ...  

Science Conference Proceedings (OSTI)

... Carbon nanotubes (CNTs) provide two particularly exciting prospects. ... particular, the relationship between the nucleating/growing nanotube and the ...

26

Carbon fuel particles used in direct carbon conversion fuel cells  

SciTech Connect

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F.; Cherepy, Nerine

2012-10-09T23:59:59.000Z

27

Carbon fuel particles used in direct carbon conversion fuel cells  

SciTech Connect

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

2012-01-24T23:59:59.000Z

28

Carbon fuel particles used in direct carbon conversion fuel cells  

Science Conference Proceedings (OSTI)

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

2011-08-16T23:59:59.000Z

29

Interaction of Rock Minerals with Carbon Dioxide and Brine: ...  

NLE Websites -- All DOE Office Websites (Extended Search)

behavior and to predict carbonate precipitation under equilibrium conditions. An expanded thermochemical database from Lawrence Berkley Laboratory is now being used to evaluate...

30

Development of a CO2 Sequestration Module by Integrating Mineral Activation and Aqueous Carbonation  

Science Conference Proceedings (OSTI)

Mineral carbonation is a promising concept for permanent CO{sub 2} sequestration due to the vast natural abundance of the raw materials and the permanent storage of CO{sub 2} in solid form as carbonates. The sequestration of CO{sub 2} through the employment of magnesium silicates--olivine and serpentine--is beyond the proof of concept stage. For the work done in this project, serpentine was chosen as the feedstock mineral due to its abundance and availability. Although the reactivity of olivine is greater than that of serpentine, physical and chemical treatments have been shown to increase greatly the reactivity of serpentine. The primary drawback to mineral carbonation is reaction kinetics. To accelerate the carbonation, aqueous processes are preferred, where the minerals are first dissolved in solution. In aqueous carbonation, the key step is the dissolution rate of the mineral, where the mineral dissolution reaction is likely to be surface-controlled. The relatively low reactivity of serpentine has warranted research into physical and chemical treatments that have been shown to greatly increase its reactivity. The use of sulfuric acid as an accelerating medium for the removal of magnesium from serpentine has been investigated. To accelerate the dissolution process, the mineral can be ground to very fine particle size, 185 C, >13 MPa, and control on the dissolution via the removal of water, which is closely correlated with the extraction of magnesium from serpentine. Single-variable experimentation demonstrated dissolution enhancements with increased reaction time and temperature. An increase in magnesium dissolution of 46% and 70%, relative to a baseline test, occurred for increased reaction time and temperature, respectively. In addition to the challenges presented by the dissolution of serpentine, another challenge is the subsequent carbonation of the magnesium ions. A stable hydration sphere for the magnesium ion reduces the carbonation kinetics by obstructing the formation of the carbonation products. Accordingly, this research has evaluated the solubility of carbon dioxide in aqueous solution, the interaction between the dissociation products of carbon dioxide, and the carbonation potential of the magnesium ion.

George Alexander; Parvana Aksoy; John Andresen; Mercedes Maroto-Valer; Harold Schobert

2006-08-14T23:59:59.000Z

31

Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System  

Science Conference Proceedings (OSTI)

A conceptual model of CO2 injection in bedded sandstone-shale sequences has been developed using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments. Numerical simulations were performed with the reactive fluid flow and geochemical transport code TOUGHREACT to analyze mass transfer between sandstone and shale layers and CO2 immobilization through carbonate precipitation. Results indicate that most CO2 sequestration occurs in the sandstone. The major CO2 trapping minerals are dawsonite and ankerite. The CO2 mineral-trapping capacity after 100,000 years reaches about 90 kg per cubic meter of the medium. The CO2 trapping capacity depends on primary mineral composition. Precipitation of siderite and ankerite requires Fe+2 supplied mainly by chlorite and some by hematite dissolution and reduction. Precipitation of dawsonite requires Na+ provided by oligoclase dissolution. The initial abundance of chlorite and oligoclase therefore affects the CO2 mineral trapping capacity. The sequestration time required depends on the kinetic rate of mineral dissolution and precipitation. Dawsonite reaction kinetics is not well understood, and sensitivity regarding the precipitation rate was examined. The addition of CO2 as secondary carbonates results in decreased porosity. The leaching of chemical constituents from the interior of the shale causes slightly increased porosity. The limited information currently available for the mineralogy of natural high-pressure CO2 gas reservoirs is also generally consistent with our simulation. The ''numerical experiments'' give a detailed understanding of the dynamic evolution of a sandstone-shale geochemical system.

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2004-07-09T23:59:59.000Z

32

Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2  

E-Print Network (OSTI)

Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1 #12;TKK-ENY-9 June 2002 3 Preface This volume contains the two progress reports for the project "CO2 preparation, to be submitted to a technical journal #12;TKK-ENY-9 June 2002 5 Part 1 : Progress report August

Zevenhoven, Ron

33

emissions: mineral carbonation and Finnish pulp and paper industry (CO2  

E-Print Network (OSTI)

- ation of slags from iron- and steel industry" pre- sented at the 4th Nordic Mini-symposium on CO2CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use of serpentinites in energy and metal industry (ECOSERP) Carl-Johan Fogelholm, Project leader, professor Sanni

Zevenhoven, Ron

34

Calibrating the ChemCam LIBS for Carbonate Minerals on Mars  

DOE R&D Accomplishments (OSTI)

The ChemCam instrument suite on board the NASA Mars Science Laboratory (MSL) rover includes the first LIBS instrument for extraterrestrial applications. Here we examine carbonate minerals in a simulated martian environment using the LIDS technique in order to better understand the in situ signature of these materials on Mars. Both chemical composition and rock type are determined using multivariate analysis (MVA) techniques. Composition is confirmed using scanning electron microscopy (SEM) techniques. Our initial results suggest that ChemCam can recognize and differentiate between carbonate materials on Mars.

Wiens, Roger C.; Clegg, Samuel M.; Ollila, Ann M.; Barefield, James E.; Lanza, Nina; Newsom, Horton E.

2009-00-00T23:59:59.000Z

35

Innovative Carbon Dioxide Sequestration from Flue Gas Using an In-Duct Scrubber Coupled with Alkaline Clay Mineralization  

NLE Websites -- All DOE Office Websites (Extended Search)

Innovative Carbon Dioxide Sequestration Innovative Carbon Dioxide Sequestration from Flue Gas Using an In-Duct Scrubber Coupled with Alkaline Clay Mineralization Background The United States Department of Energy (DOE) is leading an effort to find novel approaches to reduce carbon dioxide (CO 2 ) emissions from industrial sources. The Industrial Carbon Capture and Sequestration (ICCS) program is funded by the American Recovery and Reinvestment Act (ARRA) to encourage development of processes that

36

Low dissolved organic carbon input from fresh litter to deep mineral soils  

SciTech Connect

Dissolved organic carbon (DOC) leached from recent litter in the forest floor has been suggested to be an important source of C to the mineral soil of forest ecosystems. In order to determine the rate at which this flux of C occurs we have taken advantage of a local release of 14C at Oak Ridge National Laboratory Reservation, USA (latitude N 35 58'; longitude W 84 16'). Eight replicate 7x7 m plots were estab lished at four field sites on the reservation in an upland oak forest setting. Half of the plots were provided with 14C-enriched litter (?14C ?1000 ), and the other half with near-background litter (?14C ?220 ) over multiple years. Differences in the labeled leaf litter were used to quantify the movement of litter derived DOC through the soil profile. Soil solutions were collected over several years with tension lysimeters at 15 and 70 cm depth and measured for DOC concentration and 14C abundance. The net amount of DOC retained between 15 and 70 cm was 1.5-6 g m-2 y-1. There were significant effects of the litter additions on the 14C abundance in the DOC, but the net transport of 14C from the added litter was small. The difference in ?14C between the treatments with enriched and near-background litter was only about 130 at both depths, which is small compared with the difference in ?14C in the added litter. The primary source of DOC within the mineral soil must therefore have been either the Oe/Oa horizon or the organic matter in the mineral soil. Over a 2-year time frame, leaching of DOC from recent litter did not have a major impact on the C stock in the mineral soil below 15 cm in this ecosystem.

Froeberg, Mats J [ORNL; Jardine, Philip M [ORNL; Hanson, Paul J [ORNL; Swanston, Christopher [ORNL; Todd Jr, Donald E [ORNL; Phillips, Jana Randolph [ORNL; Garten Jr, Charles T [ORNL

2007-01-01T23:59:59.000Z

37

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

Science Conference Proceedings (OSTI)

Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

Brent Constantz; Randy Seeker; Martin Devenney

2010-06-30T23:59:59.000Z

38

Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes  

Science Conference Proceedings (OSTI)

We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

Steiner, S A; Baumann, T F; Kong, J; Satcher, J H; Dresselhaus, M S

2007-02-15T23:59:59.000Z

39

Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes  

DOE R&D Accomplishments (OSTI)

We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

Steiner, S. A.; Baumann, T. F.; Kong, J.; Satcher, J. H.; Dresselhaus, M. S.

2007-02-20T23:59:59.000Z

40

Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System  

E-Print Network (OSTI)

relevant to geologic carbon sequestration. 2002 GeologicalNational Conference on Carbon Sequestration. Washington, DC.model for geological carbon sequestration, 2002 Geological

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Fundamental study of CO2-H2O-mineral interactions for carbon sequestration, with emphasis on the nature of the supercritical fluid-mineral interface.  

SciTech Connect

In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration, interfacial processes at the supercritical fluid-mineral interface will strongly affect core- and reservoir-scale hydrologic properties. Experimental and theoretical studies have shown that water films will form on mineral surfaces in supercritical CO2, but will be thinner than those that form in vadose zone environments at any given matric potential. The theoretical model presented here allows assessment of water saturation as a function of matric potential, a critical step for evaluating relative permeabilities the CO2 sequestration environment. The experimental water adsorption studies, using Quartz Crystal Microbalance and Fourier Transform Infrared Spectroscopy methods, confirm the major conclusions of the adsorption/condensation model. Additional data provided by the FTIR study is that CO2 intercalation into clays, if it occurs, does not involve carbonate or bicarbonate formation, or significant restriction of CO2 mobility. We have shown that the water film that forms in supercritical CO2 is reactive with common rock-forming minerals, including albite, orthoclase, labradorite, and muscovite. The experimental data indicate that reactivity is a function of water film thickness; at an activity of water of 0.9, the greatest extent of reaction in scCO2 occurred in areas (step edges, surface pits) where capillary condensation thickened the water films. This suggests that dissolution/precipitation reactions may occur preferentially in small pores and pore throats, where it may have a disproportionately large effect on rock hydrologic properties. Finally, a theoretical model is presented here that describes the formation and movement of CO2 ganglia in porous media, allowing assessment of the effect of pore size and structural heterogeneity on capillary trapping efficiency. The model results also suggest possible engineering approaches for optimizing trapping capacity and for monitoring ganglion formation in the subsurface.

Bryan, Charles R.; Dewers, Thomas A.; Heath, Jason E.; Wang, Yifeng; Matteo, Edward N.; Meserole, Stephen P.; Tallant, David Robert

2013-09-01T23:59:59.000Z

42

Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels  

DOE Green Energy (OSTI)

This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

Turgut Gur

2010-04-30T23:59:59.000Z

43

Direct Carbon Conversion: Review of Production and Electrochemical Conversion of Reactive Carbons, Economics and Potential Impact on the Carbon Cycle  

SciTech Connect

Concerns over global warning have motivated the search for more efficient technologies for electric power generation from fossil fuels. Today, 90% of electric power is produced from coal, petroleum or natural gas. Higher efficiency reduces the carbon dioxide emissions per unit of electric energy. Exercising an option of deep geologic or ocean sequestration for the CO{sub 2} byproduct would reduce emissions further and partially forestall global warming. We introduce an innovative concept for conversion of fossil fuels to electricity at efficiencies in the range of 70-85% (based on standard enthalpy of the combustion reaction). These levels exceed the performance of common utility plants by up to a factor of two. These levels are also in excess of the efficiencies of combined cycle plants and of advanced fuel cells now operated on the pilot scale. The core of the concept is direct carbon conversion a process that is similar to that a fuel cell but differs in that synthesized forms of carbon, not hydrogen, are used as fuel. The cell sustains the reaction, C + O{sub 2} = CO{sub 2} (E {approx} 1.0 V, T = 800 C). The fuel is in the form of fine particulates ({approx}100 nm) distributed by entrainment in a flow of CO{sub 2} to the cells to form a slurry of carbon in the melt. The byproduct stream of CO{sub 2} is pure. It affords the option of sequestration without additional separation costs, or can be reused in secondary oil or gas recovery. Our experimental program has discovered carbon materials with orders of magnitude spreads in anode reactivity reflected in cell power density. One class of materials yields energy at about 1 kW/m{sup 2} sufficiently high to make practical the use of the cell in electric utility applications. The carbons used in such cells are highly disordered on the nanometer scale (2-30 nm), relative to graphite. Such disordered or turbostratic carbons can be produced by controlled pyrolysis (thermal decomposition) of hydrocarbons extracted from coal, petroleum or natural gas. For coal and lignite, such hydrocarbons may be produced by cyclic hydrogenation (hydropyrolysis), with the recycle of the hydrogen intermediate following pyrolysis. Starting with common CH{sub x} feedstock for carbon black manufacture, the ash entrained into the carbon (<0.03%) does not jeopardize cell life or enter into the economic estimates for power generation. The value of carbon (relative to hydrogen) as an electrochemical fuel derives from thermodynamic aspects of the C/O{sub 2} reaction. First, the entropy change of the C/O{sub 2} reaction is nearly zero, allowing theoretical efficiencies ({Delta}G(T)/{Delta}H{sub i298}) of 100% (cf. H{sub 2}/O{sub 2} theoretical efficiency of 70%). Second, the thermodynamic activity of the carbon fuel and the CO{sub 2} product are spatially and temporally invariant. This allows 100% utilization of the carbon fuel in single pass (cf. hydrogen utilizations of 75-85%). The carbodmelt slurry is non-explosive at operating temperatures. The total energy efficiency for the C/O{sub 2} is roughly 80% for cell operation at practical rates. In summary, what gives this route its fundamental advantage in energy conversion is that it derives the greatest possible fraction of energy of the fossil resource from an electrochemical reaction (C+O{sub 2} = CO{sub 2}) that is comparatively simple to operate at efficiencies of 80%, in a single-pass cell configuration without bottoming turbine cycles.

Cooper, J F; Cherepy, N; Upadhye, R; Pasternak, A; Steinberg, M

2000-12-12T23:59:59.000Z

44

Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems  

SciTech Connect

Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power generation in the range of 0.5 to 50 MW is small engines fueled with natural gas or liquid fuels or in the bulk power markets supplied usually by remote central station power plants with capacities of 250-1250 MW that deliver electricity to customers via the transmission and distribution grid. New power generation technology must be able to offer a significant cost advantage over existing technologies serving the same market to attract the interest of investors that are needed to provide funding for the development, demonstration, and commercialization of the technology. That path is both lengthy and expensive. One of the key drivers for any new power generation technology is the relative amount of pollutant emissions of all types, particularly those that are currently regulated or may soon be regulated. The new focus on greenhouse gas emissions offers a window of opportunity to DCFC technology because of its much higher conversion efficiency and the production of a very concentrated stream of CO{sub 2} in the product gas. This should offer a major competitive advantage if CO{sub 2} emissions are constrained by regulation in the future. The cost of CO{sub 2} capture, liquefaction, and pressurization has the potential to be much less costly with DCFC technology compared to other currently available forms of fossil fuel power generation.

Wolk, R

2004-04-23T23:59:59.000Z

45

Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems  

DOE Green Energy (OSTI)

Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power generation in the range of 0.5 to 50 MW is small engines fueled with natural gas or liquid fuels or in the bulk power markets supplied usually by remote central station power plants with capacities of 250-1250 MW that deliver electricity to customers via the transmission and distribution grid. New power generation technology must be able to offer a significant cost advantage over existing technologies serving the same market to attract the interest of investors that are needed to provide funding for the development, demonstration, and commercialization of the technology. That path is both lengthy and expensive. One of the key drivers for any new power generation technology is the relative amount of pollutant emissions of all types, particularly those that are currently regulated or may soon be regulated. The new focus on greenhouse gas emissions offers a window of opportunity to DCFC technology because of its much higher conversion efficiency and the production of a very concentrated stream of CO{sub 2} in the product gas. This should offer a major competitive advantage if CO{sub 2} emissions are constrained by regulation in the future. The cost of CO{sub 2} capture, liquefaction, and pressurization has the potential to be much less costly with DCFC technology compared to other currently available forms of fossil fuel power generation.

Wolk, R

2004-04-23T23:59:59.000Z

46

Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality  

Science Conference Proceedings (OSTI)

The effect of carbon functionality on the electrocatalytic performance of carbon black-supported, Pt-based, direct methanol fuel cell cathodes was investigated. Polarization data show that cathodes with nitrogen and sulfur functionality have enhanced catalytic activity toward oxygen reduction. Transmission electron microscopy results indicate that this behavior may be ascribed to a platinum particle size effect.

Roy, S.C.; Christensen, P.A.; Hamnett, A.; Thomas, K.M.; Trapp, V. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1996-10-01T23:59:59.000Z

47

Evaluation of the environmental viability of direct injection schemes for ocean carbon sequestration  

E-Print Network (OSTI)

This thesis evaluates the expected impact of several promising schemes for ocean carbon sequestration by direct injection of CO2, and serves as an update to the assessment by Auerbach et al. (1997) and Caulfield et al. ...

Israelsson, Peter H. (Peter Hampus), 1973-

2008-01-01T23:59:59.000Z

48

Direct electrochemical conversion of carbon: systems for efficient conversion of fossil fuels to electricity  

DOE Green Energy (OSTI)

The direct electrochemical conversion of carbon involves discharge of suspensions of reactive carbon particles in a molten salt electrolyte against an oxygen (air) cathode. (Figure 1). The free energy and the enthalpy of the oxidation reaction are nearly identical. This allows theoretical efficiencies ({Delta}G(T)/{Delta}H) to approach 100% at temperatures from 500 to 800 C. Entropy heat losses are therefore negligible. The activities of the elemental carbon and of the carbon dioxide product are uniform throughout the fuel cell and constant over discharge time. This stabilizes cell EMF and allows full utilization of the carbon fuel in a single pass. Finally, the energy cost for pyrolysis of hydrocarbons is generally very low compared with that of steam reforming or water gas reactions. Direct electrochemical conversion of carbon might be compared with molten carbonate fuel cell using carbon rather than hydrogen. However, there are important differences. There is no hydrogen involved (except from trace water contamination). The mixture of molten carbonate and carbon is not highly flammable. The carbon is introduced in as a particulate, rather than as a high volume flow of hydrogen. At the relatively low rates of discharge (about 1 kA/m{sup 2}), the stoichiometric requirements for carbon dioxide by the cathodic reaction may be met by diffusion across the thin electrolyte gap. We report recent experimental work at LLNL using melt slurries of reactive carbons produced by the thermal decomposition of hydrocarbons. We have found that anodic reactivity of carbon in mixed carbonate melts depends strongly on form, structure and nano-scale disorder of the materials, which are fixed by the hydrocarbon starting material and the conditions of pyrolysis. Thus otherwise chemically pure carbons made by hydrocarbon pyrolysis show rates at fixed potentials that span an order of magnitude, while this range lies 1-2 orders of magnitude higher than the current density of graphite plate electrodes. One carbon materials was identified which delivered anode current densities of 1 kA/m{sup 2} at 0.8 V (i.e., 80% efficiency, based on the standard enthalpy of carbon/oxygen reaction, and assuming full conversion), which we believe to be sufficiently great to allow practical application in fuel cell arrays. Since the hydrocarbon starting materials are ''ash free,'' entrainment of ash into the melt is not limiting. Finally, the use of fine carbon particulates in slurries avoids cost and logistics of carbon electrode manufacture and distribution.

Cooper, J F; Cherepy, N; Krueger, R

2000-08-10T23:59:59.000Z

49

Direct template synthesis of mesoporous carbon and its application to supercapacitor electrodes  

SciTech Connect

A direct templating method which is facile, inexpensive and suitable for the large scale production of mesoporous carbon is reported herein. A meso-structure surfactant/silicate template was made in a solution phase and resorcinol-formaldehyde as a carbon precursor was incorporated into the template solution. After aging, carbonization and hydrofluoric acid (HF) etching, mesoporous carbon was obtained. Using X-ray diffraction, scanning and transmission electron microscopy and nitrogen sorption, the synthesis mechanism of the mesoporous carbon was elucidated. According to the small angle X-ray scattering measurements, the surface became smoother after the removal of the silica, indicating that the silica was mostly located at the pore surface of the carbon. Also, the calculation of the pore volume demonstrated that the silica was transferred into the pores of the carbon without structural collapse during HF etching. When the prepared mesoporous carbon was applied to a supercapacitor electrode, the rectangular shape of the cyclic voltammogram was less collapsed, even at a high scan rate, which is indicative of its high rate capability. This was due to the low resistance of the electrolyte in the pores (3.8 {Omega} cm{sup 2}), which was smaller than that of conventional activated carbon electrodes and even comparable to that of ordered mesoporous carbon electrodes. This improved performance was probably due to the well developed mesoporosity and high pore connectivity of the prepared mesoporous carbon.

Yoon, Songhun, E-mail: yoonshun@krict.re.kr [Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology (KRICT), Sinseongno 19, Yuseong, Daejeon 305-600 (Korea, Republic of); Oh, Seung M. [Research Center for Energy Conversion and Storage (RCECS), School of Chemical and Biological Engineering and Institute of Chemical Process, College of Engineering, Seoul National University, Seoul 151-744 (Korea, Republic of); Lee, Chulwee [Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology (KRICT), Sinseongno 19, Yuseong, Daejeon 305-600 (Korea, Republic of)

2009-08-05T23:59:59.000Z

50

Direct electrochemical conversion of carbon anode fuels in molton salt media  

DOE Green Energy (OSTI)

We are conducting research into the direct electrochemical conversion of reactive carbons into electricity--with experimental evidence of total efficiencies exceeding 80% of the heat of combustion of carbon. Together with technologies for extraction of reactive carbons from broad based fossil fuels, direct carbon conversion addresses the objectives of DOE's ''21st Century Fuel Cell'' with exceptionally high efficiency (>70% based on standard heat of reaction, {Delta}H{sub std}), as well as broader objectives of managing CO{sub 2} emissions. We are exploring the reactivity of a wide range of carbons derived from diverse sources, including pyrolyzed hydrocarbons, petroleum cokes, purified coals and biochars, and relating their electrochemical reactivity to nano/microstructural characteristics.

Cherepy, N; Krueger, R; Cooper, J F

2001-01-17T23:59:59.000Z

51

Direct Conversion of Carbon Fuels in a Molten Carbonate Fuel Cell  

DOE Green Energy (OSTI)

Anodes of elemental carbon may be discharged in a galvanic cell using a molten carbonate electrolyte, a nickel-foam anode-current collector, and a porous nickel air cathode to achieve power densities of 40-100 mW/cm{sup 2}. We report cell and anode polarization, surface area, primary particle size and a crystallization index for nine particulate carbon samples derived from fuel oil, methane, coal, charred biological material and petroleum coke. At 800 C, current densities of 50-125 mA/cm{sup 2} were measured at a representative cell voltage of 0.8 V. Power densities for cells with two carbon-anode materials were found to be nearly the same on scales of 2.8- and 60 cm{sup 2} active area. Constant current operation of a small cell was accompanied by constant voltage during multiple tests of 10-30 hour duration. Cell voltage fell off after the carbon inventory was consumed. Three different cathode structures are compared, indicating that an LLNL fabricated porous nickel electrode with <10 {micro}m pores provides improved rates compared with nickel foam with 100-300 {micro}m pores. Petroleum coke containing substantial sulfur and ash discharges at a slightly lower rate than purified petroleum coke. The sulfur leads to degradation of the anode current collector over time. A conceptual model for electrochemical reactivity of carbon is presented which indicates the importance of (1) bulk lattice disorder, which continually provides surface reactive sites during anodic dissolution and (2) electrical conductivity, which lowers the ohmic component of anode polarization.

Cherepy, N J; Fiet, K J; Krueger, R; Jankowski, A F; Cooper, J F

2004-01-28T23:59:59.000Z

52

Fluid dynamics of sinking carbon dioxide hydrate particle releases for direct ocean carbon sequestration  

E-Print Network (OSTI)

One strategy to remove anthropogenic CO? from the atmosphere to mitigate climate change is by direct ocean injection. Liquid CO? can react with seawater to form solid partially reacted CO? hydrate composite particles (pure ...

Chow, Aaron C. (Aaron Chunghin), 1978-

2008-01-01T23:59:59.000Z

53

Predicting and Evaluating the Effectiveness of Ocean Carbon Sequestration by Direct Injection  

Science Conference Proceedings (OSTI)

Direct injection of CO{sub 2} into the ocean is a potentially effective carbon sequestration strategy. Therefore, we want to understand the effectiveness of oceanic injection and develop the appropriate analytic framework to allow us to compare the effectiveness of this strategy with other carbon management options. Here, after a brief review of direct oceanic injection, we estimate the effectiveness of ocean carbon sequestration using one dimensional and three dimensional ocean models. We discuss a new measure of effectiveness of carbon sequestration in a leaky reservoir, which we denote sequestration potential. The sequestration potential is the fraction of global warning cost avoided by sequestration in a reservoir. We show how these measures apply to permanent sequestration and sequestration in leaky reservoirs, such as the oceans, terrestrial biosphere, and some geologic formations. Under the assumptions of a constant cost of carbon emission and a 4% discount rate, injecting 900 m deep in the ocean avoids {approx}90% of the global warming cost associated with atmospheric emission; an injection 1700 m deep would avoid > 99 % of the global warming cost. Hence, for discount rates in the range commonly used by commercial enterprises, oceanic direct injection may be nearly as economically effective as permanent sequestration at avoiding global warming costs.

Caldeira, K; Herzog, H J; Wickett, M E

2001-04-24T23:59:59.000Z

54

A carbon riveted Pt/Graphene catalyst with high stability for direct methanol fuel cell  

Science Conference Proceedings (OSTI)

Pt/Graphene catalyst was prepared by microwave-assisted polyol process, and carbonization was riveted onto the catalyst surface to enhance the catalyst stability. The physical properties of the obtained catalysts were characterized by X-ray diffraction ... Keywords: Direct methanol fuel cell, Methanol electrooxidation, Pt/Graphene, Stability

Xiaowei Liu, Jialin Duan, Hailong Chen, Yufeng Zhang, Xuelin Zhang

2013-10-01T23:59:59.000Z

55

SPOUTED BED ELECTRODES (SBE) FOR DIRECT UTILIZATION OF CARBON IN FUEL CELLS  

DOE Green Energy (OSTI)

This Phase I project was focused on an investigation of spouted bed particulate electrodes for the direct utilization of solid carbon in fuel cells. This approach involves the use of a circulating carbon particle/molten carbonate slurry in the cell that provides a few critical functions: it (1) fuels the cell continuously with entrained carbon particles; (2) brings particles to the anode surfaces hydrodynamically; (3) removes ash from the anode surfaces and the cell hydrodynamically; (4) provides a facile means of cell temperature control due to its large thermal capacitance; (5) provides for electrolyte maintenance and control in the electrode separator(s); and (6) can (potentially) improve carbon conversion rates by ''pre-activating'' carbon particle surfaces via formation of intermediate oxygen surface complexes in the bulk molten carbonate. The approach of this scoping project was twofold: (1) adaptation and application of a CFD code, originally developed to simulate particle circulation in spouted bed electrolytic reactors, to carbon particle circulation in DCFC systems; and (2) experimental investigation of the hydrodynamics of carbon slurry circulation in DCFC systems using simulated slurry mixtures. The CFD model results demonstrated that slurry recirculation can be used to hydrodynamically feed carbon particles to anode surfaces. Variations of internal configurations were investigated in order to explore effects on contacting. It was shown that good contacting with inclined surfaces could be achieved even when the particles are of the same density as the molten carbonate. The use of CO{sub 2} product gas from the fuel cell as a ''lift-gas'' to circulate the slurry was also investigated with the model. The results showed that this is an effective method of slurry circulation; it entrains carbon particles more effectively in the draft duct and produces a somewhat slower recirculation rate, and thus higher residence times on anode surfaces, and can be controlled completely via pressure balance. Experimental investigations in a rectangular spouted vessel hydrodynamics apparatus (SVHA) showed that hydrodynamics can be used to control the circulation, residence time, and distribution of carbon within the spouted bed, as well as provide good particle contact with anode surfaces. This was shown to be a function of viscosity, carbon loading, and particle size, as well as relative densities. Higher viscosities and smaller particle sizes favor more efficient particle entrainment in the draft duct, and particle recirculation. Both the computational and experimental results are consistent with each another and exhibit the same general qualitative behavior. Based upon this work, a design of a prototype SBE/DCFC cell was developed and is presented.

J.M. Calo

2004-12-01T23:59:59.000Z

56

High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation  

SciTech Connect

Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power generation cycles are: (1) increased efficiency by a factor of up to 2 over many conventional fossil fuel steam plants, (2) reduced power generation cost, especially for increasing fossil fuel cost, (3) reduced CO2 emission per kWh, and (4) direct sequestration or reuse (e.g., in enhanced oil or NG recovery) of the CO{sub 2} product.

Steinberg, M; Cooper, J F; Cherepy, N

2002-01-02T23:59:59.000Z

57

CO2 Mineral Sequestration Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration Studies Sequestration Studies Introduction, Issues and Plans Philip Goldberg National Energy Technology Laboratory Workshop on CO 2 Sequestration with Minerals August 8, 2001 Mineral Sequestration Program Research effort seeks to refine and validate a promising CO 2 sequestration technology option, mineral sequestration also known as mineral carbonation Goals: * Understand the fundamental mechanisms involved in mineral carbonation * Generate data to support process development * Operate continuous, integrated small-scale process unit to support design Current Partnerships In order to effectively develop Mineral Sequestration, a multi-laboratory Working Group was formed in the Summer of 1998, participants include: * Albany Research Center * Arizona State University * Los Alamos National Laboratory

58

MODELING AND DESIGN FOR A DIRECT CARBON FUEL CELL WITH ENTRAINED FUEL AND OXIDIZER  

DOE Green Energy (OSTI)

The novel molten carbonate fuel cell design described in this report uses porous bed electrodes. Molten carbonate, with carbon fuel particles and oxidizer entrained, is circulated through the electrodes. Carbon may be reacted directly, without gasification, in a molten carbonate fuel cell. The cathode reaction is 2CO{sub 2} + O{sub 2} 4e{sup -} {yields} 2CO{sub 3}{sup =}, while the anode reaction can be either C + 2CO{sub 3}{sup =} {yields} 3CO{sub 2} + 4e{sup -} or 2C + CO{sub 3}{sup =} {yields} 3CO + 2e{sup -}. The direct carbon fuel cell has an advantage over fuel cells using coal-derived synthesis gas in that it provides better overall efficiency and reduces equipment requirements. Also, the liquid electrolyte provides a means for transporting the solid carbon. The porous bed cell makes use of this carbon transport ability of the molten salt electrolyte. A one-dimensional model has been developed for predicting the performance of this cell. For the cathode, dependent variables are superficial O{sub 2} and CO{sub 2} fluxes in the gas phase, superficial O{sub 2} and CO{sub 2} fluxes in the liquid phase, superficial current density through the electrolyte, and electrolyte potential. The variables are related by correlations, from the literature, for gas-liquid mass transfer, liquid-solid mass transfer, cathode current density, electrode overpotential, and resistivity of a liquid with entrained gas. For the anode, dependent variables are superficial CO{sub 2} flux in the gas phase, superficial CO{sub 2} flux in the liquid phase, superficial C flux, superficial current density through the electrolyte, and electrolyte potential. The same types of correlations relate the variables as in the cathode, with the addition of a correlation for resistivity of a fluidized bed. CO production is not considered, and axial dispersion is neglected. The model shows behavior typical of porous bed electrodes used in electrochemical processes. Efficiency is comparable to that of membrane electrode fuel cells. Effective bed depths are on the order of 1-5 centimeter, giving power/volume lower than for membrane electrode cells. The porous bed design, however, uses less expensive materials and is more resistant to fouling by coal impurities. The model will be used in the second phase of the project to design a laboratory-scale prototype cell. The prototype cell will demonstrate the concept and provide experimental data for improving the model.

Alan A. Kornhauser; Ritesh Agarwal

2005-04-01T23:59:59.000Z

59

Mineral Sequestration Utilizing Industrial By-Products, Residues, and Minerals  

NLE Websites -- All DOE Office Websites (Extended Search)

J. Fauth and Yee Soong J. Fauth and Yee Soong U.S. Department of Energy National Energy Technology Laboratory Pittsburgh PA, 15236-0940 Mineral Sequestration Workshop National Energy Technology Laboratory August 8, 2001 Mineral Sequestration Utilizing Industrial By-Products, Residues, and Minerals Mineral Sequestration Workshop, U.S. Department of Energy, NETL, August 8, 2001 Overview * Introduction - Objective - Goals - NETL Facilities * Effect of Solution Chemistry on Carbonation Efficiency - Buffered Solution + NaCl - Buffered Solution + MEA * Effect of Pretreatment on Carbonation Efficiency - Thermal Treatments - Chemical Treatments * Carbonation Reaction with Ultramafic Minerals - Serpentine - Olivine Mineral Sequestration Workshop, U.S. Department of Energy, NETL, August 8, 2001 Overview * Carbonation Reaction with Industrial By-products

60

The sensitivity of tropical convective precipitation to the direct radiative forcings of black carbon aerosols emitted from major regions  

E-Print Network (OSTI)

Previous works have suggested that the direct radiative forcing (DRF) of black carbon (BC) aerosols are able to force a significant change in tropical convective precipitation ranging from the Pacific and Indian Ocean to ...

Wang, Chien

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61

Localized and directed lateral growth of carbon nanotubes from a porous template  

Science Conference Proceedings (OSTI)

We report on the growth of laterally oriented carbon nanotubes with both positional and directional control. The growth was done by chemical vapor deposition from Fe/Mo catalyst embedded inside a porous silicon medium which was formed electrochemically on the vertical faces of etched posts on a silicon substrate. A solution containing the catalyst was allowed to diffuse into the porous medium only in lithographically defined areas. Nanotubes grew only in the patterned areas with a preferred orientation normal to the edges of the etched posts.

S. J. Wind; R. Martel; Ph. Avouris

2002-01-01T23:59:59.000Z

62

Combined Power Generation and Carbon Sequestration Using Direct FuelCell  

DOE Green Energy (OSTI)

The unique chemistry of carbonate fuel cell offers an innovative approach for separation of carbon dioxide from greenhouse gases (GHG). The carbonate fuel cell system also produces electric power at high efficiency. The simultaneous generation of power and sequestration of greenhouse gases offer an attractive scenario for re-powering the existing coal-fueled power plants, in which the carbonate fuel cell would separate the carbon dioxide from the flue gas and would generate additional pollutant-free electric power. Development of this system is concurrent with emergence of Direct FuelCell{reg_sign} (DFC{reg_sign}) technology for generation of electric power from fossil fuels. DFC is based on carbonate fuel cell featuring internal reforming. This technology has been deployed in MW-scale power plants and is readily available as a manufactured product. This final report describes the results of the conceptualization study conducted to assess the DFC-based system concept for separation of CO2 from GHG. Design and development studies were focused on integration of the DFC systems with coal-based power plants, which emit large amounts of GHG. In parallel to the system design and simulation activities, operation of laboratory scale DFC verified the technical concept and provided input to the design activity. The system was studied to determine its effectiveness in capturing more than ninety percent of CO2 from the flue gases. Cost analysis was performed to estimate the change in cost of electricity for a 200 MW pulverized coal boiler steam cycle plant retrofitted with the DFC-based CO2 separation system producing an additional 127 MW of electric power. The cost increments as percentage of levelized cost of electricity were estimated for a range of separation plant installations per year and a range of natural gas cost. The parametric envelope meeting the goal (<20% increase in COE) was identified. Results of this feasibility study indicated that DFC-based separation systems have the potential for capturing at least 90% of the emissions from the greenhouse gases generated by power plants and other industrial exhaust streams, and yet entail in less than 20% increase in the cost of energy services for long-term deployment (beyond 2012). The anticipated cost of energy increase is in line with DOE's goal for post-combustion systems as outlined in the ''Carbon Capture and Sequestration Systems Analysis Guidelines'', published by NETL, April 2005. During the course of this study certain enabling technologies were identified and the needs for further research and development were discussed.

Hossein Ghezel-Ayagh

2006-03-01T23:59:59.000Z

63

Carbon Fibers and Carbon Nanotubes - Programmaster.org  

Science Conference Proceedings (OSTI)

Feb 17, 2010 ... Polymer Nanocomposites: Carbon Fibers and Carbon Nanotubes Sponsored by: The Minerals, Metals and Materials Society Program...

64

Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity  

DOE Green Energy (OSTI)

We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

2001-03-07T23:59:59.000Z

65

Optimization and Comparison of Direct and Indirect Supercritical Carbon Dioxide Power Plant Cycles for Nuclear Applications  

Science Conference Proceedings (OSTI)

There have been a number of studies involving the use of gases operating in the supercritical mode for power production and process heat applications. Supercritical carbon dioxide (CO2) is particularly attractive because it is capable of achieving relatively high power conversion cycle efficiencies in the temperature range between 550 C and 750 C. Therefore, it has the potential for use with any type of high-temperature nuclear reactor concept, assuming reactor core outlet temperatures of at least 550 C. The particular power cycle investigated in this paper is a supercritical CO2 Recompression Brayton Cycle. The CO2 Recompression Brayton Cycle can be used as either a direct or indirect power conversion cycle, depending on the reactor type and reactor outlet temperature. The advantage of this cycle when compared to the helium Brayton cycle is the lower required operating temperature; 550 C versus 850 C. However, the supercritical CO2 Recompression Brayton Cycle requires an operating pressure in the range of 20 MPa, which is considerably higher than the required helium Brayton cycle operating pressure of 8 MPa. This paper presents results of analyses performed using the UniSim process analyses software to evaluate the performance of both a direct and indirect supercritical CO2 Brayton Recompression cycle for different reactor outlet temperatures. The direct supercritical CO2 cycle transferred heat directly from a 600 MWt reactor to the supercritical CO2 working fluid supplied to the turbine generator at approximately 20 MPa. The indirect supercritical CO2 cycle assumed a helium-cooled Very High Temperature Reactor (VHTR), operating at a primary system pressure of approximately 7.0 MPa, delivered heat through an intermediate heat exchanger to the secondary indirect supercritical CO2 Brayton Recompression cycle, again operating at a pressure of about 20 MPa. For both the direct and indirect cycles, sensitivity calculations were performed for reactor outlet temperature between 550 C and 850 C. The UniSim models used realistic component parameters and operating conditions to model the complete reactor and power conversion systems. CO2 properties were evaluated, and the operating ranges of the cycles were adjusted to take advantage of the rapidly changing properties of CO2 near the critical point. The results of the analyses showed that, for the direct supercritical CO2 power cycle, thermal efficiencies in the range of 40 to 50% can be achieved. For the indirect supercritical CO2 power cycle, thermal efficiencies were approximately 10% lower than those obtained for the direct cycle over the same reactor outlet temperature range.

Edwin A. Harvego; Michael G. McKellar

2011-11-01T23:59:59.000Z

66

Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.  

DOE Green Energy (OSTI)

The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is compatible with much of the existing fuel infrastructure.

Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

2009-01-01T23:59:59.000Z

67

Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids  

SciTech Connect

Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

2010-07-12T23:59:59.000Z

68

Effect of fresh green waste and green waste compost on mineral nitrogen, nitrous oxide and carbon dioxide from a Vertisol  

Science Conference Proceedings (OSTI)

Incorporation of organic waste amendments to a horticultural soil, prior to expected risk periods, could immobilise mineral N, ultimately reducing nitrogen (N) losses as nitrous oxide (N{sub 2}O) and leaching. Two organic waste amendments were selected, a fresh green waste (FGW) and green waste compost (GWC) as they had suitable biochemical attributes to initiate N immobilisation into the microbial biomass and organic N forms. These characteristics include a high C:N ratio (FGW 44:1, GWC 35:1), low total N (14%). Both products were applied at 3 t C/ha to a high N (plus N fertiliser) or low N (no fertiliser addition) Vertisol soil in PVC columns. Cumulative N{sub 2}O production over the 28 day incubation from the control soil was 1.5 mg/N{sub 2}O/m{sup 2}, and 11 mg/N{sub 2}O/m{sup 2} from the control + N. The N{sub 2}O emission decreased with GWC addition (P < 0.05) for the high N soil, reducing cumulative N{sub 2}O emissions by 38% by the conclusion of the incubation. Analysis of mineral N concentrations at 7, 14 and 28 days identified that both FGW and GWC induced microbial immobilisation of N in the first 7 days of incubation regardless of whether the soil environment was initially high or low in N; with the FGW immobilising up to 30% of available N. It is likely that the reduced mineral N due to N immobilisation led to a reduced substrate for N{sub 2}O production during the first week of the trial, when soil N{sub 2}O emissions peaked. An additional finding was that FGW + N did not decrease cumulative N{sub 2}O emissions compared to the control + N, potentially due to the fact that it stimulated microbial respiration resulting in anaerobic micro sites in the soil and ultimately N{sub 2}O production via denitrification. Therefore, both materials could be used as post harvest amendments in horticulture to minimise N loss through nitrate-N leaching in the risk periods between crop rotations. The mature GWC has potential to reduce N{sub 2}O, an important greenhouse gas.

Vaughan, Sarah M., E-mail: s.vaughan@uq.edu.au [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Dalal, Ram C. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Department of Environment and Resource Management, 80 Meiers Rd., Indooroopilly, QLD 4068 (Australia); Harper, Stephen M. [Department of Employment, Economic Development and Innovation, Warrego Highway, Gatton, QLD 4343 (Australia); Menzies, Neal W. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia)

2011-08-15T23:59:59.000Z

69

Method for direct production of carbon disulfide and hydrogen from hydrocarbons and hydrogen sulfide feedstock  

DOE Patents (OSTI)

A method for converting hydrocarbons and hydrogen sulfide to carbon disulfide and hydrogen is provided comprising contacting the hydrocarbons and hydrogen sulfide to a bi-functional catalyst residing in a controlled atmosphere for a time and at a temperature sufficient to produce carbon disulfide and hydrogen. Also provided is a catalyst for converting carbon sulfides and hydrogen sulfides to gasoline range hydrocarbons comprising a mixture containing a zeolite catalyst and a hydrogenating catalyst.

Miao, Frank Q.; Erekson, Erek James

1998-12-01T23:59:59.000Z

70

Advanced Research Power Program--CO2 Mineral Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration Sequestration Robert Romanosky National Energy Technology Laboratory Mineral Carbonation Workshop August 8, 2001 Advanced Research Power Program Descriptor - include initials, /org#/date Mineral Sequestration Research Research effort seeks to refine and validate a promising CO 2 sequestration technology option, mineral sequestration also known as mineral carbonation Descriptor - include initials, /org#/date What is Mineral Carbonation * Reaction of CO 2 with Mg or Ca containing minerals to form carbonates * Lowest energy state of carbon is a carbonate and not CO 2 * Occurs naturally in nature as weathering of rock * Already proven on large scale - Carbonate formation linked to formation of the early atmosphere Descriptor - include initials, /org#/date Advantages of Mineral Carbonation

71

Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts  

E-Print Network (OSTI)

extent of mineralization Carbon dioxide levels produced as athe formation of carbon dioxide and water. The concentrationformaldehyde and carbon dioxide concentrations were recorded

Sidheswaran, Meera A.

2012-01-01T23:59:59.000Z

72

Soil Minerals  

NLE Websites -- All DOE Office Websites (Extended Search)

Soil Minerals Soil Minerals Nature Bulletin No. 707 March 2, 1963 Forest Preserve District of Cook County Seymour Simon, President Roberts Mann, Conservation Editor SOIL MINERALS We all depend upon the land Our food is obtained from plants and animals -- bread and meat, potatoes and fish, fruit and eggs and milk and the rest of it. Our livestock feed on plants and plant products such as grass and grain. Plants, by means of their root systems, take moisture and nutrients from the soils on which they grow. Their food values, for us or for animals that furnish us food, depend upon the available nutrients in those soils. Soils contain solids, water and air. The solids, the bulk of a soil -- except in purely organic types such as peat and muck -- are mostly mineral materials. Ordinarily they also contain some organic material: decayed and decaying remains of plants and animals.

73

Final report : LDRD project 79824 carbon nanotube sorting via DNA-directed self-assembly.  

SciTech Connect

Single-wall carbon nanotubes (SWNTs) have shown great promise in novel applications in molecular electronics, biohazard detection, and composite materials. Commercially synthesized nanotubes exhibit a wide dispersion of geometries and conductivities, and tend to aggregate. Hence the key to using these materials is the ability to solubilize and sort carbon nanotubes according to their geometric/electronic properties. One of the most effective dispersants is single-stranded DNA (ssDNA), but there are many outstanding questions regarding the interaction between nucleic acids and SWNTs. In this work we focus on the interactions of SWNTs with single monomers of nucleic acids, as a first step to answering these outstanding questions. We use atomistic molecular dynamics simulations to calculate the binding energy of six different nucleotide monophosphates (NMPs) to a (6,0) single-wall carbon nanotube in aqueous solution. We find that the binding energies are generally favorable, of the order of a few kcal/mol. The binding energies of the different NMPs were very similar in salt solution, whereas we found a range of binding energies for NMPs in pure water. The binding energies are sensitive to the details of the association of the sodium ions with the phosphate groups and also to the average conformations of the nucleotides. We use electronic structure (Density Functional Theory (DFT) and Moller-Plesset second order perturbation to uncorrelated Hartree Fock theory (MP2)) methods to complement the classical force field study. With judicious choices of DFT exchange correlation functionals, we find that DFT, MP2, and classical force field predictions are in qualitative and even quantitative agreement; all three methods should give reliable and valid predictions. However, in one important case, the interactions between ions and metallic carbon nanotubes--the SWNT polarization-induced affinity for ions, neglected in most classical force field studies, is found to be extremely large (on the order of electron volts) and may have important consequences for various SWNT applications. Finally, the adsorption of NMPs onto single-walled carbon nanotubes were studied experimentally. The nanotubes were sonicated in the presence of the nucleotides at various weight fractions and centrifuged before examining the ultraviolet absorbance of the resulting supernatant. A distinct Langmuir adsorption isotherm was obtained for each nucleotide. All of the nucleotides differ in their saturation value as well as their initial slope, which we attribute to differences both in nucleotide structure and in the binding ability of different types or clusters of tubes. Results from this simple system provide insights toward development of dispersion and separation methods for nanotubes: strongly binding nucleotides are likely to help disperse, whereas weaker ones may provide selectivity that may be beneficial to a separation process.

Robinson, David B; Leung, Kevin; Rempe, Susan B.; Dossa, Paul D.; Frischknecht, Amalie Lucile; Martin, Marcus Gary

2007-10-01T23:59:59.000Z

74

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

David a. Lang David a. Lang Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4881 david.lang@netl.doe.gov andrew chizmeshya Arizona State University Center for Solid State Science Tempe, AZ 85287-1704 480-965-6072 chizmesh@asu.edu A Novel ApproAch to MiNerAl cArboNAtioN: eNhANciNg cArboNAtioN While AvoidiNg MiNerAl pretreAtMeNt process cost Background Carbonation of the widely occurring minerals of the olivine group, such as forsterite (Mg 2 SiO 4 ), is a potential large-scale sequestration process that converts CO 2 into the environmentally benign mineral magnesite (MgCO 3 ). Because the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is the key to economic viability. Previous

75

Landscape level differences in soil carbon and nitrogen: implications for soil carbon sequestration  

SciTech Connect

The objective of this research was to understand how land cover and topography act, independently or together, as determinants of soil carbon and nitrogen storage over a complex terrain. Such information could help to direct land management for the purpose of carbon sequestration. Soils were sampled under different land covers and at different topographic positions on the mostly forested 14,000 ha Oak Ridge Reservation in Tennessee, USA. Most of the soil carbon stock, to a 40-cm soil depth, was found to reside in the surface 20 cm of mineral soil. Surface soil carbon and nitrogen stocks were partitioned into particulate ({ge}53 {micro}m) and mineral-associated organic matter (<53 {micro}m). Generally, soils under pasture had greater nitrogen availability, greater carbon and nitrogen stocks, and lower C:N ratios than soils under transitional vegetation and forests. The effects of topography were usually secondary to those of land cover. Because of greater soil carbon stocks, and greater allocation of soil carbon to mineral-associated organic matter (a long-term pool), we conclude that soil carbon sequestration, but not necessarily total ecosystem carbon storage, is greater under pastures than under forests. The implications of landscape-level variation in soil carbon and nitrogen for carbon sequestration are discussed at several different levels: (1) nitrogen limitations to soil carbon storage; (2) controls on soil carbon turnover as a result of litter chemistry and soil carbon partitioning; (3) residual effects of past land use history; and (4) statistical limitations to the quantification of soil carbon stocks.

Garten Jr, Charles T [ORNL; Ashwood, Tom L [ORNL

2002-12-01T23:59:59.000Z

76

Directed Self-assembly of Nanoparticles at the Polymer Surface by Highly Compressible Supercritical Carbon Dioxide  

Science Conference Proceedings (OSTI)

We report a versatile route for self-assembly of polymer-soluble nanoparticles at the polymer surface using highly compressible supercritical carbon dioxide (scCO{sub 2}). Polystyrene and poly(methyl methacrylate)-based nanocomposite thin films with functionalized polyhedral oligomeric silsesquioxane and phenyl C{sub 61} butyric acid methyl ester nanoparticles were prepared on Si substrates and exposed to scCO{sub 2} at different pressures under the isothermal condition of 36 C. The resultant structures could be then preserved by the vitrification process of the glassy polymers via quick pressure quench to atmospheric pressure and subsequently characterized by using various surface sensitive experimental techniques in air. We found that the surface segregation of these nanoparticles is induced in the close vicinity of P = 8.2 MPa where the excess absorption of the fluid into the polymers maximizes. However, when the film thickness becomes less than about 4R{sub g} thick (where R{sub g} is the radius of polymer gyration), the uniform dispersion of the nanoparticles is favorable instead even at the same CO{sub 2} conditions. We clarify that the phase transition is correlated with the emergence of a concentration gradient of the fluid at the polymer/CO{sub 2} interface and is a general phenomenon for different polymer-nanoparticle interactions.

M Asada; P Gin; M Endoh; S Satija; T Taniguchi; T Koga

2011-12-31T23:59:59.000Z

77

Heterogeneous Reactions on Mineral Dust: Surface Reactions of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactions on Mineral Dust: Surface Reactions of Sulfur Dioxide, Ozone, Nitric and Acetic Acid on Oxide and Carbonate Particles Speaker(s): Vicki Grassian Date: June 14,...

78

A Thermodynamic Model for Predicting Mineral Reactivity in Supercritical Carbon Dioxide: I. Phase Behavior of Carbon Dioxide - Water - Chloride Salt Systems Across the H2O-Rich to the CO2-Rich Regions  

Science Conference Proceedings (OSTI)

Phase equilibria in mixtures containing carbon dioxide, water, and chloride salts have been investigated using a combination of solubility measurements and thermodynamic modeling. The solubility of water in the CO2-rich phase of ternary mixtures of CO2, H2O and NaCl or CaCl2 was determined, using near infrared spectroscopy, at 90 atm and 40 to 100 C. These measurements fill a gap in the experimental database for CO2 water salt systems, for which phase composition data have been available only for the H2O-rich phases. A thermodynamic model for CO2 water salt systems has been constructed on the basis of the previously developed Mixed-Solvent Electrolyte (MSE) framework, which is capable of modeling aqueous solutions over broad ranges of temperature and pressure, is valid to high electrolyte concentrations, treats mixed-phase systems (with both scCO2 and water present) and can predict the thermodynamic properties of dry and partially water-saturated supercritical CO2 over broad ranges of temperature and pressure. Within the MSE framework the standard-state properties are calculated from the Helgeson-Kirkham-Flowers equation of state whereas the excess Gibbs energy includes a long-range electrostatic interaction term expressed by a Pitzer-Debye-Hckel equation, a virial coefficient-type term for interactions between ions and a short-range term for interactions involving neutral molecules. The parameters of the MSE model have been evaluated using literature data for both the H2O-rich and CO2-rich phases in the CO2 - H2O binary and for the H2O-rich phase in the CO2 - H2O - NaCl / KCl / CaCl2 / MgCl2 ternary and multicompontent systems. The model accurately represents the properties of these systems at temperatures from 0C to 300 C and pressures up to ~4000 atm. Further, the solubilities of H2O in CO2-rich phases that are predicted by the model are in agreement with the new measurements for the CO2 - H2O - NaCl and CO2 - H2O - CaCl2 systems. Thus, the model can be used to predict the effect of various salts on the water content and water activity in CO2-rich phases on the basis of parameters determined from the properties of aqueous systems. Given the importance of water activity in CO2-rich phases for mineral reactivity, the model can be used as a foundation for predicting mineral transformations across the entire CO2/H2O composition range from aqueous solution to anhydrous scCO2. An example application using the model is presented which involves the transformation of forsterite to nesquehonite as a function of temperature and water content in the CO2-rich phase.

Springer, Ronald D.; Wang, Zheming; Anderko, Andre; Wang, Peiming; Felmy, Andrew R.

2012-09-05T23:59:59.000Z

79

Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels  

DOE Green Energy (OSTI)

This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

Steven Markovich

2010-06-30T23:59:59.000Z

80

A Novel Approach to Experimental Studies of Mineral DIsoolution Kinetics  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel ApproAch to experimeNtAl Novel ApproAch to experimeNtAl StudieS of miNerAl diSSolutioN KiNeticS Background DOE is conducting pilot CO 2 injection tests to evaluate the concept of geologic sequestration. One strategy that has the potential to enhance CO 2 solubility and reduce the risk of CO 2 leaking back to the surface is dissolution of indigenous minerals in the geological formation and formation of secondary carbonate precipitates. This both increases the brine pH and immobilizes the CO 2 . Clearly, the rates at which these dissolution and precipitation reactions occur directly determine the efficiency of this option. However, one of the fundamental problems in modern geochemistry is the persistent two to five orders of magnitude discrepancy between laboratory-measured and field-derived

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell  

DOE Patents (OSTI)

A membrane electrode assembly (MEA) of the invention comprises an anode and a cathode and a proton conductive membrane therebetween, the anode and the cathode each comprising a patterned sheet of longitudinally aligned transition metal-containing carbon nanotubes, wherein the carbon nanotubes are in contact with and are aligned generally perpendicular to the membrane, wherein a catalytically active transition metal is incorporated throughout the nanotubes.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL)

2012-03-20T23:59:59.000Z

82

CO2 Mineral Sequestration Studies in US  

NLE Websites -- All DOE Office Websites (Extended Search)

Mineral Sequestration Studies in US Mineral Sequestration Studies in US Philip Goldberg 1 , Zhong-Ying Chen 2 , William O'Connor 3 , Richard Walters 3 , and Hans Ziock 4 1 National Energy Technology Laboratory, P.O. Box 10940, Pittsburgh, PA 15236, goldberg@netl.doe.gov, (412)386-5806 2 Science Applications International Corporation, 1710 Goodridge Dr. McLean, VA, zhong- ying.chen@saic.com, (703)676-7328 3 Albany Research Center, Albany, OR oconner@arc.doe.gov, walters@alrc.doe, (541)967-5834 4 Los Alamos National Laboratory, Los Alamos, NM, ksl@lanl.gov, ziock@lanl.gov, (505)667- 7265 Abstract Carbon sequestration by reacting naturally occurring Mg and Ca containing minerals with CO 2 to form carbonates has many unique advantages. Most notably is the fact that carbonates have a lower energy state than CO

83

RIETVELD REFINEMENT OF REAL STRUCTURE PARAMETERS OF DISORDERED CLAY MINERALS IN  

E-Print Network (OSTI)

-conventional hydrocarbons in Germany) Germany's potential for shale oil and shale gas NIKO seal gas-rich shale shale: sedimentary rock which contains quartz, carbonates and clay minerals #12;clay minerals in shales quartz

Magee, Joseph W.

84

New Directing Groups for Metal-Catalyzed Asymmetric CarbonCarbon Bond-Forming Processes: Stereoconvergent AlkylAlkyl Suzuki Cross-Couplings of Unactivated Electrophiles  

E-Print Network (OSTI)

The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as directing groups in Ni-catalyzed Suzuki reactions has been exploited in the development of catalytic asymmetric methods for ...

Wilsily, Ashraf

85

High-Temperature Co-electrolysis of Steam and Carbon Dioxide for Direct Production of Syngas; Equilibrium Model and Single-Cell Tests  

DOE Green Energy (OSTI)

An experimental study has been completed to assess the performance of single solid-oxide electrolysis cells operating over a temperature range of 800 to 850C in the coelectrolysis mode, simultaneously electrolyzing steam and carbon dioxide for the direct production of syngas. The experiments were performed over a range of inlet flow rates of steam, carbon dioxide, hydrogen and nitrogen and over a range of current densities (-0.1 to 0.25 A/cm2) using single electrolyte-supported button electrolysis cells. Steam and carbon dioxide consumption rates associated with electrolysis were measured directly using inlet and outlet dewpoint instrumentation and a gas chromatograph, respectively. Cell operating potentials and cell current were varied using a programmable power supply. Measured values of open-cell potential and outlet gas composition are compared to predictions obtained from a chemical equilibrium coelectrolysis model. Model predictions of outlet gas composition based on an effective equilibrium temperature are shown to agree well with measurements. Cell area-specific resistance values were similar for steam electrolysis and coelectrolysis.

O'Brien, J. E.; Stoots, C. M.; Herring, J. S.; Hartvigsen, J. J.

2007-07-01T23:59:59.000Z

86

Innovative Concepts for Beneficial Reuse of Carbon Dioxide | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Innovative Concepts for Beneficial Reuse of Carbon Dioxide Innovative Concepts for Beneficial Reuse of Carbon Dioxide Innovative Concepts for Beneficial Reuse of Carbon Dioxide Funding for 12 projects to test innovative concepts for the beneficial use of carbon dioxide (CO2) was announced by the U.S. Department of Energy. The awards are part of $1.4 billion in funding from the American Recovery and Reinvestment Act (ARRA) for projects that will capture carbon dioxide from industrial sources. These 12 projects will engage in a first phase feasibility study that will examine beneficial uses in a variety of ways, including mineralization to carbonates directly through conversion of CO2 in flue gas; the use of CO2 from power plants or industrial applications to grow algae/biomass; and conversion of CO2 to fuels and chemicals. Each project will be subject to

87

The Role of Hydrate Films in the Effectiveness of Direct CO2 Injection as an Ocean Carbon Sequestration Strategy  

DOE Green Energy (OSTI)

About one-third of the carbon dioxide (2 Pg C/yr of 6 Pg C/yr) we emit into the atmosphere is already being sequestered naturally by the ocean by the process of CO{sub 2} gas transfer across the air-sea interface. Over twenty years ago Brewer (1978) and Chen and Millero (1979) presented the first fundamental estimates of anthropogenic CO{sub 2} in the ocean based the hypothesis of CO{sub 2} penetration along isopycnal surfaces and observations of total inorganic carbon (TCO2) and total alkalinity (TA). At that time the anthropogenic CO{sub 2} signal was not as large as today and given the uncertainty of the approach, the uncertainties of the results were generally regarded as relatively large. However, since then, variations of this approach have been used to estimate anthropogenic CO{sub 2} in many areas of the world ocean. A recent modeling study using the DOCS model, confirms that penetration along isopycnal surfaces is the dominate mode of natural carbon sequestration by the ocean.

Goyet, C

2004-05-06T23:59:59.000Z

88

Pd modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to FDCA  

Science Conference Proceedings (OSTI)

We show that the modification of a gold/carbon catalyst with Pt or Pd produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). This finding is a significant advance over current conversion technology because of the technological importance of FDCA. Indeed, FDCA has been identified as one of twelve potential building blocks for the production of value added chemicals derived from biosources.1 FDCA is a potential replacement source of terephthalic acid, the monomer presently used for the production of polyethylene terephthalate (PET) and derived from hydrocarbon sources.2

Villa, Alberto [Universita di Milano, Italy; Schiavoni, Marco [University of Milan and INFN, Milano, Italy; Campisi, Sebastiano [University of Milan and INFN, Milano, Italy; Veith, Gabriel M [ORNL; Prati, Laura [Universita di Milano, Italy

2013-01-01T23:59:59.000Z

89

Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell  

DOE Patents (OSTI)

A method of making a membrane electrode assembly (MEA) having an anode and a cathode and a proton conductive membrane there between. A bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated in the nanotubes forms at least one portion of the MEA and is in contact with the membrane. A combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into a first reaction zone maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is transmitted to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes. The nanotubes are in contact with a portion of the MEA at production or being positioned in contact thereafter. Methods of forming a PEMFC are also disclosed.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Willow brook, IL)

2010-07-20T23:59:59.000Z

90

Development of an advanced gas-fired mineral-wool melter. Annual report, January-December 1988  

SciTech Connect

A gas-fired mineral-wool melter was designed to provide a melting technology option to the existing coke-fired cupola melters used by the mineral wool industry. Over the past few years, mineral-wool producers have been increasingly pressured to reduce their level of pollutant gaseous emissions. Including the fuel consumption for an afterburner required with a cupola melter, the direct production costs for fuel currently range from $32 to $44 per ton of melted product; dependent on the effectiveness of a heat-recovery system. The estimated direct fuel cost for a gas-fired mineral-wool melter could be as low as $16 per ton. The configuration of the prototype melter contributes to the energy savings because waste heat is reclaimed by preheating the feedstock in a counterflow shaft. Besides the beneficial decrease in energy costs, the proposed gas-fired melter will virtually eliminate carbon monoxide and unburned hydrocarbon emissions as well as substantially reduce emissions of hydrogen sulfide. Finally, with an improved capability to process the melted product at a controlled temperature and flow rate, the gas-fired melter should improve the overall quality of the mineral fiber product compared to the state-of-the-art coke-fired cupola melter.

Vereecke, F.J.; Thekdi, A.C.

1989-06-01T23:59:59.000Z

91

Non-Carbon Materials in Cathodes  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Electrode Technology for Aluminum Production: Non-Carbon Materials in Cathodes Sponsored by: The Minerals, Metals and Materials Society,...

92

Carbon Capture and Storage  

Science Conference Proceedings (OSTI)

Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several key documents written in the last three years that provide information on the status, economics, technology, and impact of CCS. These are cited throughout this text and identified as key references at the end of this manuscript. When coupled with improvements in energy efficiency, renewable energy supplies, and nuclear power, CCS help dramatically reduce current and future emissions (US CCTP 2005, MIT 2007). If CCS is not available as a carbon management option, it will be much more difficult and much more expensive to stabilize atmospheric CO{sub 2} emissions. Recent estimates put the cost of carbon abatement without CCS to be 30-80% higher that if CCS were to be available (Edmonds et al. 2004).

Friedmann, S

2007-10-03T23:59:59.000Z

93

Characterization of Minerals  

Science Conference Proceedings (OSTI)

Mar 7, 2013 ... A Minimum Pollution, Low Energy Process for the Recovery of Cobalt and Copper from Complex Sulphide Minerals: Yotamu Hara1; 1Leeds...

94

A Novel Approach to Experimental Studies of Mineral Dissolution Kinetics  

SciTech Connect

Currently, DOE is conducting pilot CO{sub 2} injection tests to evaluate the concept of geological sequestration. The injected CO{sub 2} is expected to react with the host rocks and these reactions can potentially alter the porosity, permeability, and mechanical properties of the host or cap rocks. Reactions can also result in precipitation of carbonate-containing minerals that favorably and permanently trap CO{sub 2} underground. Many numerical models have been used to predict these reactions for the carbon sequestration program. However, a firm experimental basis for predicting silicate reaction kinetics in CO{sub 2} injected geological formations is urgently needed to assure the reliability of the geochemical models used for the assessments of carbon sequestration strategies. The funded experimental and theoretical study attempts to resolve this outstanding scientific issue by novel experimental design and theoretical interpretation of silicate dissolution rates at conditions pertinent to geological carbon sequestration. In this four year research grant (three years plus a one year no cost extension), seven (7) laboratory experiments of CO{sub 2}-rock-water interactions were carried out. An experimental design allowed the collection of water samples during experiments in situ and thus prevented back reactions. Analysis of the in situ samples delineated the temporal evolution of aqueous chemistry because of CO{sub 2}-rock-water interactions. The solid products of the experiments were retrieved at the end of the experimental run, and analyzed with a suite of advanced analytical and electron microscopic techniques (i.e., atomic resolution transmission electron microscopy (TEM), scanning electron microscopy (SEM), electron microprobe, X-ray diffraction, X-ray photoelectron spectroscopy (XPS)). As a result, the research project probably has produced one of the best data sets for CO{sub 2}-rock-water interactions in terms of both aqueous solution chemistry and solid characterization. Three experiments were performed using the Navajo sandstone. Navajo sandstone is geologically equivalent to the Nugget sandstone, which is a target formation for a regional partnership injection project. Our experiments provided the experimental data on the potential CO{sub 2}-rock-water interactions that are likely to occur in the aquifer. Geochemical modeling was performed to interpret the experimental results. Our single mineral (feldspar) experiments addressed a basic research need. i.e., the coupled nature of dissolution and precipitation reactions, which has universal implication to the reaction kinetics as it applied to CO{sub 2} sequestration. Our whole rock experiments (Navajo sandstone) addressed the applied research component, e.g., reacting Navajo sandstone with brine and CO{sub 2} has direct relevance on the activities of a number of regional partnerships. The following are the major findings from this project: (1) The project generated a large amount of experimental data that is central to evaluating CO{sub 2}-water-rock interactions and providing ground truth to predictive models, which have been used and will inevitably be increasingly more used in carbon sequestration. (2) Results from the feldspar experiments demonstrated stronger coupling between dissolution and precipitation reactions. We show that the partial equilibrium assumption did not hold in the feldspar hydrolysis experiments (Zhu and Lu, submitted, Appendix A-2). The precipitation of clay minerals influenced dissolution of primary silicate in a much stronger way as previously envisioned. Therefore, our experimental data indicated a much more complex chemical kinetics as it has been applied to carbon sequestration program in terms of preliminary predictive models of CO{sub 2}-rock-water interactions. Adopting this complexity (strong coupling) may influence estimates of mineral trapping and porosity/permeability for geological carbon sequestration. In general, our knowledge of the coupling of different reactions is poor, and we must consider the uncertainties resultin

Chen Zhu

2008-08-31T23:59:59.000Z

95

Continuous air Agglomeration Method for high Carbon fly ash Beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

1998-09-29T23:59:59.000Z

96

NUMERICALLY SIMULATING CARBONATE MINERALIZATION OF BASALT WITH ...  

Hanford Company, SD-BWI-DP-044, Rev. 0, Richland, Washington. Deutsch, C. V., and A. G. Journel (1997), GSLIB: Geostatistical Software Library and ...

97

Carbon Dioxide Management - Programmaster.org  

Science Conference Proceedings (OSTI)

Thermodynamic Phase Stability in Gasification Carbon Feedstock Slags ... industrial coal/petcoke feedstock blends in simulated gasifier environments. ... sludge mineralization of calcium and invent a core device for multi-level jet carbonation.

98

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

99

Carbon Films Produced from Ionic Liquid Carbon Precursors ...  

The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ...

100

Minerals Yearbook, 1988. Boron  

Science Conference Proceedings (OSTI)

U.S. production and sales of boron minerals and chemicals decreased during the year. Glass-fiber insulation was the largest use for borates, followed by sales to distributors, textile-grade glass fibers, and borosilicate glasses. California was the only domestic source of boron minerals. The report discusses the following: domestic data coverage; legislation and government programs; domestic production; comsumption and uses; prices; foreign trade; world capacity; world review--Argentina, Chile, France, Italy, Turkey, United Kingdom; Technology.

Lyday, P.A.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Source category survey: mineral wool manufacturing industry. Final report  

SciTech Connect

This report contains background information which was used for determining the need for new source performance standards (NSPS) for the mineral wool manufacturing industry in accordance with Section 111 of the Clean Air Act. Air pollution emissions and growth trends of the mineral wool industry are examined. Manufacturing processes, control strategies, and state and local air pollution regulations are discussed. The impact of a potential NSPS on particulate and carbon monoxide emissions is calculated.

Not Available

1980-06-01T23:59:59.000Z

102

Chemistry of organic carbon in soil with relationship to the global carbon cycle  

SciTech Connect

Various ecosystem disturbances alter the balances between production of organic matter and its decomposition and therefore change the amount of carbon in soil. The most severe perturbation is conversion of natural vegetation to cultivated crops. Conversion of natural vegetation to cultivated crops results in a lowered input of slowly decomposing material which causes a reduction in overall carbon levels. Disruption of soil matrix structure by cultivation leads to lowered physical protection of organic matter resulting in an increased net mineralization rate of soil carbon. Climate change is another perturbation that affects the amount and composition of plant production, litter inputs, and decomposition regimes but does not affect soil structure directly. Nevertheless, large changes in soil carbon storage are probable with anticipated CO2 induced climate change, particularly in northern latitudes where anticipated climate change will be greatest (MacCracken and Luther 1985) and large amounts of soil organic matter are found. It is impossible, given the current state of knowledge of soil organic matter processes and transformations to develop detailed process models of soil carbon dynamics. Largely phenomenological models appear to be developing into predictive tools for understanding the role of soil organic matter in the global carbon cycle. In particular, these models will be useful in quantifying soil carbon changes due to human land-use and to anticipated global climate and vegetation changes. 47 refs., 7 figs., 2 tabs.

Post, W.M. III

1988-01-01T23:59:59.000Z

103

Laser Assisted Direct Local Synthesis of Semiconducting Nanowires  

E-Print Network (OSTI)

electrically driven lasers," Nature 421 (6920), 241-245 (Hsu, A. Bushmaker et al. , "Laser Directed Growth of Carbon-al. , "Scanning focused laser activation of carbon nanotube

RYU, SANG GIL

2010-01-01T23:59:59.000Z

104

MINERAL COUNTY COMMISSIONERS  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Board of Board of MINERAL COUNTY COMMISSIONERS Telephone: 702-945-2446 Fax: 702-945-0706 P.O. Box 4150 Hawthorne, Nevada 89415 JACKIE WALLIS, Chairman GOVERNING BOARD FOR THE TOWNS OF DAN DILLARD, Vice Chairman HAWTHORNE, LUNING AND MINA BOB LYBARGER, Member LIQUOR BOARD GAMING BOARD U.S. Department of Energy Office of General Counsel, GC-52 1000 Independence Ave. S.W. Washington, DC 20585 Dear Sirs: Attached are the comments for modification of the Price-Anderson Act Notice of Inquiry(NOI) provided to the Board of Mineral County Commissioners, in a letter dated January

105

Bioleaching of Minerals  

Science Conference Proceedings (OSTI)

Bioleaching is the term used to describe the microbial dissolution of metals from minerals. The commercial bioleaching of metals, particularly those hosted in sulfide minerals, is supported by the technical disciplines of biohydrometallurgy, hydrometallurgy, pyrometallurgy, chemistry, electrochemistry, and chemical engineering. The study of the natural weathering of these same minerals, above and below ground, is also linked to the fields of geomicrobiology and biogeochemistry. Studies of abandoned and disused mines indicate that the alterations of the natural environment due to man's activities leave as remnants microbiological activity that continues the biologically mediated release of metals from the host rock (acid rock drainage; ARD). A significant fraction of the world's copper, gold and uranium is now recovered by exploiting native or introduced microbial communities. While some members of these unique communities have been extensively studied for the past 50 years, our knowledge of the composition of these communities, and the function of the individual species present remains relatively limited. Nevertheless, bioleaching represents a major strategy in mineral resource recovery whose importance will increase as ore reserves decline in quality, become more difficult to process (due to increased depth, increased need for comminution, for example), and as environmental considerations eliminate traditional physical processes such as smelting, which have served the mining industry for hundreds of years.

F. Roberto

2002-02-01T23:59:59.000Z

106

US Minerals Databrowser | Open Energy Information  

Open Energy Info (EERE)

US Minerals Databrowser AgencyCompany Organization Jonathan Callahan Resource Type Maps Website http:mazamascience.comMiner References US Minerals Databrowser1 The US...

107

Mapping evaporate minerals by ASTER  

Science Conference Proceedings (OSTI)

Evaporate minerals are important industrial raw materials that have been used in diverse industries for many years. As one of the most extensively used evaporate minerals, gypsum is an important raw material in the construction, agriculture, textile, ...

N. Serkan Oztan; M. Lutfi Suzen

2011-03-01T23:59:59.000Z

108

Selective flotation of phosphate minerals with hydroxamate collectors  

DOE Patents (OSTI)

A method is disclosed for separating phosphate minerals from a mineral mixture, particularly from high-dolomite containing phosphate ores. The method involves conditioning the mineral mixture by contacting in an aqueous in environment with a collector in an amount sufficient for promoting flotation of phosphate minerals. The collector is a hydroxamate compound of the formula; ##STR1## wherein R is generally hydrophobic and chosen such that the collector has solubility or dispersion properties it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms. M is a cation, typically hydrogen, an alkali metal or an alkaline earth metal. Preferably, the collector also comprises an alcohol of the formula, R'--OH wherein R' is generally hydrophobic and chosen such that the collector has solubility or dispersion properties so that it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms.

Miller, Jan D. (Salt Lake City, UT); Wang, Xuming (Salt Lake City, UT); Li, Minhua (Salt Lake City, UT)

2002-01-01T23:59:59.000Z

109

Hearing protection for miners  

Science Conference Proceedings (OSTI)

A NIOSH analysis showed that at age 50 approximately 90% of coal miners have a hearing impairment, yet noise included hearing loss is 100% preventable. The article discusses requirements of the MSHA regulations, 30 CFR Part 62 - occupational noise exposure (2000) and a 2008-MSHA document describing technologically achievable and promising controls for several types of mining machinery. Hearing protection is still required for exposure to greater than 90 dBA. These are now commercially available ways to determine how much attenuation an individual gets from a given hearing protector, known as 'fit testing'. 3 refs., 1 fig., 1 tab., 1 photo.

Schulz, T. [Sperian Hearing Protection (United States)

2008-10-15T23:59:59.000Z

110

Accelerated Technique for Carbon Mesoporous Materials - Energy ...  

Patent 8,114,510: Mesoporous carbon materials The invention is directed to a method for fabricating a mesoporous carbon material, the method ...

111

Natural materials for carbon capture.  

Science Conference Proceedings (OSTI)

Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

Myshakin, Evgeniy M. (National Energy Technology Laboratory, Pittsburgh, PA); Romanov, Vyacheslav N. (National Energy Technology Laboratory, Pittsburgh, PA); Cygan, Randall Timothy

2010-11-01T23:59:59.000Z

112

Minerals yearbook: The mineral industry of Mexico. 1988 international review  

SciTech Connect

Mexico is one of the major mineral-producing countries in the world, continuing in 1988 a role that the nation had assumed since the first European settlement of the Western Hemisphere. With respect to nonfuel minerals, Mexico was the world's leading producer of bismuth and silver; was among the top 5 producers of barite, fluorspar, graphite, molybdenum, and strontium; and was among the top 10 producers of antimony, white arsenic, cadmium, copper, lead, manganese, mercury, salt, selenium, sulfur, and zinc. In the mineral fuels sector, Mexico was the sixth largest producer of crude oil and ranked eighth in terms of proven oil reserves. In addition, Mexico was the largest foreign supplier of crude oil and cement to the United States. Topics discussed in the report include: Government policies and programs; Production; Trade; Commodity review--Metals, Industrial minerals, and Mineral fuels.

Machamer, J.F.

1988-01-01T23:59:59.000Z

113

Inducing Mineral Precipitation in Groundwater by Addition of Phosphate  

SciTech Connect

Induced precipitation of phosphate minerals to scavenge trace metals and radionuclides from groundwater is a potential remediation approach for contaminated aquifers. Phosphate minerals can sequester trace elements by primary mineral formation, solid solution formation and/or adsorption, and they are poorly soluble under many environmental conditions, making them attractive for long-term sustainable remediation. The success of such engineered schemes will depend on the particular mineral phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for induced phosphate mineral precipitation rely on the stimulation of native groundwater populations, we also tested the effect of bacterial cells (initial densities of 105 and 107 ml-1) within the precipitation medium. We also tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM). The experiments showed that the general progression of mineral precipitation was similar under all of the conditions, with initial formation of amorphous calcium carbonate, and transformation to poorly crystalline hydroxyapatite (HAP) by the end of the week-long experiments. The presence of the bacterial cells appeared to delay precipitation, although by the end of 7 days the overall extent of precipitation was similar for all of the treatments. The stoichiometry of the final precipitates as well as results of Rietveld refinement of x-ray diffraction data indicated that the treatments including organic acids and bacterial cells resulted in increased distortion of the HAP crystal lattice, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the phosphate minerals was decreased in the treatments with cells and organic acids, compared to the control. The results of the experiments enable a greater understanding of the challenges associated with phosphate-based remediation schemes for contaminated environments.

Karen E. Wright; Yoshiko Fujita; Thomas Hartmann; Mark Conrad

2011-10-01T23:59:59.000Z

114

Mineral Deformation at Earth's Core-Mantle Boundary  

NLE Websites -- All DOE Office Websites (Extended Search)

Mineral Deformation at Earth's Core-Mantle Boundary Print Mineral Deformation at Earth's Core-Mantle Boundary Print Earth is a dynamic planet in which convection takes place on the scale of thousands of kilometers. Because Earth is mostly solid (except for its liquid-iron outer core), this convection causes deformation of solid rocks by plastic flow. At the core-mantle boundary (CMB), 2900 km deep, seismologists have discovered that seismic waves travel faster in certain directions. This seismic anisotropy appears to be related to the deformation of the constituent minerals. To understand the deformation mechanisms of mineral phases at this depth, researchers from Yale and UC Berkeley re-created the ultrahigh pressures of the deep Earth at ALS Beamline 12.2.2 while conducting in situ x-ray diffraction experiments to probe changes in crystal orientations.

115

Mineral Deformation at Earth's Core-Mantle Boundary  

NLE Websites -- All DOE Office Websites (Extended Search)

Mineral Deformation at Earth's Core-Mantle Boundary Print Mineral Deformation at Earth's Core-Mantle Boundary Print Earth is a dynamic planet in which convection takes place on the scale of thousands of kilometers. Because Earth is mostly solid (except for its liquid-iron outer core), this convection causes deformation of solid rocks by plastic flow. At the core-mantle boundary (CMB), 2900 km deep, seismologists have discovered that seismic waves travel faster in certain directions. This seismic anisotropy appears to be related to the deformation of the constituent minerals. To understand the deformation mechanisms of mineral phases at this depth, researchers from Yale and UC Berkeley re-created the ultrahigh pressures of the deep Earth at ALS Beamline 12.2.2 while conducting in situ x-ray diffraction experiments to probe changes in crystal orientations.

116

Mineral Deformation at Earth's Core-Mantle Boundary  

NLE Websites -- All DOE Office Websites (Extended Search)

Mineral Deformation at Earth's Core-Mantle Boundary Print Mineral Deformation at Earth's Core-Mantle Boundary Print Earth is a dynamic planet in which convection takes place on the scale of thousands of kilometers. Because Earth is mostly solid (except for its liquid-iron outer core), this convection causes deformation of solid rocks by plastic flow. At the core-mantle boundary (CMB), 2900 km deep, seismologists have discovered that seismic waves travel faster in certain directions. This seismic anisotropy appears to be related to the deformation of the constituent minerals. To understand the deformation mechanisms of mineral phases at this depth, researchers from Yale and UC Berkeley re-created the ultrahigh pressures of the deep Earth at ALS Beamline 12.2.2 while conducting in situ x-ray diffraction experiments to probe changes in crystal orientations.

117

Hyperspectral Mineral Mapping For Geothermal Exploration On The Pyramid  

Open Energy Info (EERE)

Hyperspectral Mineral Mapping For Geothermal Exploration On The Pyramid Hyperspectral Mineral Mapping For Geothermal Exploration On The Pyramid Lake Paiute Reservation, Nevada Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Hyperspectral Mineral Mapping For Geothermal Exploration On The Pyramid Lake Paiute Reservation, Nevada Details Activities (2) Areas (1) Regions (0) Abstract: Over 2000 km2 (772 mi2) of 5 m resolution Hymap hyperspectral data was acquired over the Pyramid Lake Paiute Reservation in the Fall of 2004. Subsequent image processing and data analysis has identified reflectance spectra for alunite, kaolinite/halloysite, illite, gypsum, vegetation, and carbonate. A portable spectrometer is being used for in situ validation, along with laboratory measurements and X-ray diffraction analyses of samples collected in the field. We are in the process of

118

Reconnaissance geological and mineral resource map of northern Sierra Madre Occidental, Mexico  

SciTech Connect

The northern Sierra Madre Occidental (SMO) map (scale 1:500,000) comprises 305,000 km/sup 2/ in the states of Chihuahau and Sonora. The centrally-located plateau section is divided into an upper, predominantly rhyolitic sequence, overlying an andesite-rich interval, directly correlatable with Tertiary volcanic units in central and southern SMO, respectively (Clark, 1983; 1984). Precambrian rocks occur in both flanks of SMO, either in the subsurface or surface exposures. They are succeeded by Early and Late Paleozoic sedimentary strata in Sonora and by a more discontinuous sequence in western Chihuahua. Mesozoic strata are dominated by Cretaceous carbonate sequences in central Chihuahua, and by late Triassic - Early Jurassic continental and Jurassic magmatic arc deposits in Sonora. Late Mesozoic - Early Cenozoic batholiths were emplaced in numerous localities in Sonora, whereas only isolated granitoid stocks are exposed in Chihuahua. Widespread lavas of basaltic composition are Late Tertiary to Quaternary in age. Late Cenozoic unconsolidated clastic deposits fill basins and constitute the coastal plain on the west. The main mineralizing epoch occurred in Late Cretaceous - Early Tertiary time, is aligned in northwesterly-trending belts and included numerous porphyry (Cu-Mo) deposits, scattered contact metasomatic (Cu-W) ores and a fissure-vein (Ag-Au) assemblage in the western margin; a (Pb-Zn-Ag) assemblage in fissure-veins and manto-chimney deposits, manganese and volcanogenic uranium ores in the eastern flank. Important industrial minerals and rocks include graphite, fluorspar and building materials.

Clark, K.F.

1985-01-01T23:59:59.000Z

119

Carbon fuel cells with carbon corrosion suppression  

Science Conference Proceedings (OSTI)

An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

Cooper, John F. (Oakland, CA)

2012-04-10T23:59:59.000Z

120

The Role of Transport Phenomena in the Direct Oxidation of Solid Fuels.  

E-Print Network (OSTI)

?? Direct carbon fuel cells have shown promise for stationary power generation by utilizing the direct oxidation of a solid carbon fuel source at the (more)

Banas, Charles J

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Optimization of Mineral Activation for CO2 sequestration Hui X. Ou, McNair Scholar, Pennsylvania State University  

E-Print Network (OSTI)

estuaries; increased biodiversity; enhanced recovery oil and methane; and the development of exportable technologies to help the U.S. economy (DOE, 1999). Mineral carbonation, which involves the reaction of CO2

Omiecinski, Curtis

122

Feasibility Studies of Direct CO2 Sequestration with Minerals  

NLE Websites -- All DOE Office Websites (Extended Search)

slurry density Operational parameters Required mixing intensity (solids suspension and gas dispersion) Attainable extent of reaction Materials of construction (corrosion and...

123

Hot-gas cleanup for molten carbonate fuel cells-dechlorination and soot formation. Final report, May 19, 1981-July 19, 1983  

DOE Green Energy (OSTI)

Two separate aspects of hot-gas conditioning for molten carbonate fuel cells (MCFC) were investigated under this contract: potential high temperature chloride sorbent materials were sreened and tested and carbon deposition on MCFC components was studied experimentally to determine guidelines for maximizing MCFC efficiency while avoiding carbon fouling. Natural minerals containing sodium carbonate were identified as the most promising candidates for economical removal of chlorides from coal gasifier effluents at temperatures of about 800 K (980/sup 0/F). The mineral Shortite was tested in a fixed bed and found to perform remarkably well with no calcination. Using Shortite we were able to achieve the program goal of less than 1 ppmV chlorides at 800 K. Shortite is an abundant mineral with no competing commercial demand, so it should provide an economical chloride cleanup sorbent. Measurements showed that carbon deposition can occur in the equilibrium carbon freee region because of the relative rates of the relevant reactions. On all surfaces tested, the Boudouard carbon formation reaction is much faster than the water-gas shift reaction which is much faster than the methanation reaction. This means that the normal practice of adding steam to prevent carbon formation will only succeed if flows are slow enough for the water shift reaction to go substantially to completion. More direct suppression of carbon formation can be achieved by CO/sub 2/ addition through anode recycle to force the Boudouard reaction backward. Addition of steam or CO/sub 2/ must be minimized to attain the highest possible MCFC efficiency. 28 references, 31 figures, 22 tables.

Ham, D.; Gelb, A.; Lord, G.; Simons, G.

1984-01-01T23:59:59.000Z

124

Growth and Characterization of Complex Mineral Surfaces  

SciTech Connect

Precipitation of mineral aggregates near the Earth's surface or in subsurface fractures and cavities often produces complex microstructures and surface morphologies. Here we demonstrate how a simple surface normal growth (SNG) process may produce microstructures and surface morphologies very similar to those observed in some natural carbonate systems. A simple SNG model was used to fit observed surfaces, thus providing information about the growth history and also about the frequency and spatial distribution of nucleation events during growth. The SNG model can be extended to systems in which the symmetry of precipitation is broken, for example by fluid flow. We show how a simple modification of the SNG model in which the local growth rate depends on the distance from a fluid source and the local slope or fluid flow rate, produces growth structures with many similarities to natural travertine deposits.

P. Meakin; E. Jettestuen; B. Jamtveit; Y. Y. Podladchikov; S. deVilliers; H. E. F. Amundsen

2006-09-01T23:59:59.000Z

125

ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING  

SciTech Connect

Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coal-fired power assumes that the resulting CO{sub 2} emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO{sub 2} levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO{sub 2} emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO{sub 2} emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO{sub 2} as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO{sub 2} mineral sequestration--the conversion of stationary-source CO{sub 2} emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO{sub 3} and CaCO{sub 3})--has recently emerged as one of the most promising sequestration options, providing permanent CO{sub 2} disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO{sub 2} under controlled conditions. This produces a mineral carbonate which (1) is environmentally benign, (2) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (3) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO{sub 2} mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH){sub 2}. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO{sub 2} mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach will provide a deeper understanding of the key reaction mechanisms than either individual approach can alone. Ab initio techniques will also significantly advance our understanding of atomic-level processes at the solid/solution interface by e

A.V.G. Chizmeshya

2003-12-19T23:59:59.000Z

126

ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING  

SciTech Connect

Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coalfired power assumes that the resulting CO{sub 2} emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO{sub 2} levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO{sub 2} emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO{sub 2} emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO{sub 2} as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO{sub 2} mineral sequestration--the conversion of stationary-source CO{sub 2} emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO{sub 3} and CaCO{sub 3})--has recently emerged as one of the most promising sequestration options, providing permanent CO{sub 2} disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO{sub 2} under controlled conditions. This produces a mineral carbonate which (i) is environmentally benign, (ii) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (iii) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO{sub 2} mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH){sub 2}. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO{sub 2} mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach will provide a deeper understanding of the key reaction mechanisms than either individual approach can alone. Ab initio techniques will also significantly advance our understanding of atomic-level processes at the solid/solution interface by

A.V.G. Chizmeshya

2002-12-19T23:59:59.000Z

127

ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING  

SciTech Connect

Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coal-fired power assumes that the resulting CO2 emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO2 levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO2 emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO2 emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO2 as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO2 mineral sequestration--the conversion of stationary-source CO2 emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO3 and CaCO3)--has recently emerged as one of the most promising sequestration options, providing permanent CO2 disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO2 under controlled conditions. This produces a mineral carbonate which (1) is environmentally benign, (2) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (3) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO2 mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH)2. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO2 mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach has provided a deeper understanding of the key reaction mechanisms than either individual approach can alone. We used ab initio techniques to significantly advance our understanding of atomic-level processes at the solid/solution interface by elucidating the origin of vibrational, electronic, x-ray and electron energy loss sp

A.V.G. Chizmeshya; M.J. McKelvy; G.H. Wolf; R.W. Carpenter; D.A. Gormley; J.R. Diefenbacher; R. Marzke

2006-03-01T23:59:59.000Z

128

Geochemistry of Magnesium Silicate Carbonation in an Aqueous Medium  

NLE Websites -- All DOE Office Websites (Extended Search)

Geochemistry of Magnesium Silicate Geochemistry of Magnesium Silicate Carbonation in an Aqueous Medium (Carbon Mineralization) Jon Benner, Deb Bergfeld, Dave Bish, Darrin Byler, Bill Carey, Steve Chipera, George Guthrie, Klaus Lackner, Hans Ziock Hydrology, Geochemistry, Geology Group Los Alamos National Laboratory LA-UR-01-4206 Approved for public release; distribution is unlimited George Guthrie gguthrie@lanl.gov 505-665-6340 Mineral Carbonation: Conversion of CO 2 into Carbonates * alkali carbonates too soluble * alkaline earth carbonates ideal sources: Ca-silicates (feldspar) Mg-silicates (olivine, serpentine, clays) Mg 2+ + CO 3 2- => MgCO 3 Mg 2 SiO 4 + 4H + => 2Mg 2+ + SiO 2(aq) Ultramafic rocks are an abundant Mg source (~0.2 km) 3 serpentine / GW-yr Challenges for Mineral-Carbonation

129

Mesoporous carbon materials  

SciTech Connect

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

Dai, Sheng; Wang, Xiqing

2013-08-20T23:59:59.000Z

130

New Geophysical Technique for Mineral Exploration and Mineral Discrimination Based on Electromagnetic Methods  

DOE Green Energy (OSTI)

The research during the first two years of the project was focused on developing the foundations of a new geophysical technique for mineral exploration and mineral discrimination, based on electromagnetic (EM) methods. The developed new technique is based on examining the spectral induced polarization effects in electromagnetic data using effective-medium theory and advanced methods of 3-D modeling and inversion. The analysis of IP phenomena is usually based on models with frequency dependent complex conductivity distribution. In this project, we have developed a rigorous physical/mathematical model of heterogeneous conductive media based on the effective-medium approach. The new generalized effective-medium theory of IP effect (GEMTIP) provides a unified mathematical method to study heterogeneity, multi-phase structure, and polarizability of rocks. The geoelectrical parameters of a new composite conductivity model are determined by the intrinsic petrophysical and geometrical characteristics of composite media: mineralization and/or fluid content of rocks, matrix composition, porosity, anisotropy, and polarizability of formations. The new GEMTIP model of multi-phase conductive media provides a quantitative tool for evaluation of the type of mineralization, and the volume content of different minerals using electromagnetic data. We have developed a 3-D EM-IP modeling algorithm using the integral equation (IE) method. Our IE forward modeling software is based on the contraction IE method, which improves the convergence rate of the iterative solvers. This code can handle various types of sources and receivers to compute the effect of a complex resistivity model. We have demonstrated that the generalized effective-medium theory of induced polarization (GEMTIP) in combination with the IE forward modeling method can be used for rock-scale forward modeling from grain-scale parameters. The numerical modeling study clearly demonstrates how the various complex resistivity models manifest differently in the observed EM data. These modeling studies lay a background for future development of the IP inversion method, directed at determining the electrical conductivity and the intrinsic chargeability distributions, as well as the other parameters of the relaxation model simultaneously. The new technology introduced in this project can be used for the discrimination between uneconomic mineral deposits and the location of zones of economic mineralization and geothermal resources.

Michael S. Zhdanov

2009-03-09T23:59:59.000Z

131

Tribology of earthmoving, mining, and minerals processing  

Science Conference Proceedings (OSTI)

Earthmoving, mining, and minerals processing each involve frequent, and often severe, mechanical interactions between metals, and between metals and abrasive nonmetallic and metallic materials (i.e., mineral bearing ores). The abrasive nature of ores causes significant wear to extracting, handling, and processing equipment. Consequently, wear in earthmoving, mining, and minerals processing operations results in the removal of large amounts of material from the wear surfaces of scraping, digging, and ore processing equipment. From an energy point of view, material wear of this nature is classified as an indirect tribological loss (Imhoff et al., 1985). Additionally, a significant amount of energy is expended to overcome frictional forces in the operation of all earthmoving, mining, and minerals processing machinery (i.e., a direct tribological loss). However, in these particular processes, wear losses are more than five times those of frictional losses. In general, the amount of material lost from a particular component in these operations, before it becomes unserviceable, is far greater than that which can be tolerated in typical metal-to-metal wear situations (e.g., lubricated bearing-shaft wear couples in machinery). Consequently, much of the equipment used in earthmoving, mining, and ore processing makes use of easily replaceable or repairable, and preferably low-cost, wear components. The mechanisms by which metal-to-metal and abrasive wear occurs, and the relationships between material properties and wear behavior, are reasonably well-understood in general terms. However, the specific wear mechanisms/wear material interactions that occur during earthmoving, digging, and the processing of ore are more complex, and depend on the wear material, and on the nature of abrasive, the type of loading, and the environment. As a result of this general knowledge, reliable predictions can be made regarding the performance of particular materials under a range of in-service operating conditions. This knowledge has allowed the rational selection of wear-resistant materials for use as earthmoving, mining, and minerals processing components, and new wear-resistant materials can be designed using our knowledge of the impact and abrasion mechanisms encountered in the day-to-day operation of components used in these operations.

Hawk, Jeffrey A.; Wilson, Rick D.

2001-01-01T23:59:59.000Z

132

BIOMINERALIZATION FOR CARBON SEQUESTRATION T. J. Phelps and Y. Roh  

E-Print Network (OSTI)

of the controlling factors, rate and extent of carbonate mineral precipitation will significantly advance our while carbon dioxide is liberated to the atmosphere. While previous strategies dealt the sulfur in the coal) and/or reject kiln dust. Carbon dioxide from the plant could be bubbled through

133

MINERAL: A program for the propagation of analytical uncertainty through mineral formula recalculations  

Science Conference Proceedings (OSTI)

MINERAL (MINeral ERror AnaLysis) is a MATLAB^(R) based program that performs mineral formula recalculations and calculates the error on formula unit cations though the propagation of analytical uncertainties. The program is focused on 9 common mineral ... Keywords: Error, Mineral recalculation, Uncertainty

Sarah M. H. De Angelis; Owen K. Neill

2012-11-01T23:59:59.000Z

134

CRYSTAL CHEMISTRY OF HYDROUS MINERALS  

DOE Green Energy (OSTI)

Hydrogen has long been appreciated for its role in geological processes of the Earth's crust. However, its role in Earth's deep interior has been neglected in most geophysical thinking. Yet it is now believed that most of our planet's hydrogen may be locked up in high pressure phases of hydrous silicate minerals within the Earth's mantle. This rocky interior (approximately 7/8 of Earth's volume) is conjectured to contain 1-2 orders of magnitude more water than the more obvious oceans (the ''hydrosphere'') and atmosphere. This project is aimed at using the capability of neutron scattering from hydrogen to study the crystal chemistry and stability of hydrogen-bearing minerals at high pressures and temperatures. At the most basic level this is a study of the atomic position and hydrogen bond itself. We have conducted experimental runs on hydrous minerals under high pressure and high temperature conditions. The crystallographic structure of hydrous minerals at extreme conditions and its structural stability, and hydrogen bond at high P-T conditions are the fundamental questions to be addressed. The behavior of the hydrous minerals in the deep interior of the Earth has been discussed.

Y. ZHAO; ET AL

2001-02-01T23:59:59.000Z

135

Iowa State Mining and Mineral Resources Research Institute  

SciTech Connect

This final report describes the activities of the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) at Iowa State University for the period July 1, 1989, to June 30, 1990. Activities include research in mining- and mineral-related areas, education and training of scientists and engineers in these fields, administration of the Institute, and cooperative interactions with industry, government agencies, and other research centers. During this period, ISMMRRI has supported research efforts to: (1) Investigate methods of leaching zinc from sphalerite-containing ores. (2) Study the geochemistry and geology of an Archean gold deposit and of a gold-telluride deposit. (3) Enchance how-quality aggregates for use in construction. (4) Pre-clean coal by triboelectric charging in a fluidized-bed. (5) Characterize the crystal/grain alignment during processing of yttrium-barium-copper-perovskite (1-2-3) superconductors. (5) Study the fluid inclusion properties of a fluorite district. (6) Study the impacts of surface mining on community planning. (7) Assess the hydrophobicity of coal and pyrite for beneficiation. (8) Investigate the use of photoacoustic absorption spectroscopy for monitoring unburnt carbon in the exhaust gas from coal-fired boilers. The education and training program continued within the interdepartmental graduate minor in mineral resources includes courses in such areas as mining methods, mineral processing, industrial minerals, extractive metallurgy, coal science and technology, and reclamation of mined land. In addition, ISMMRRI hosted the 3rd International Conference on Processing and Utilization of High-Sulfur Coals in Ames, Iowa. The Institute continues to interact with industry in order to foster increased cooperation between academia and the mining and mineral community.

Not Available

1990-08-01T23:59:59.000Z

136

New Geophysical Technique for Mineral Exploration and Mineral Discrimination Based on Electromagnetic Methods  

DOE Green Energy (OSTI)

The research during the first year of the project was focused on developing the foundations of a new geophysical technique for mineral exploration and mineral discrimination, based on electromagnetic (EM) methods. The proposed new technique is based on examining the spectral induced polarization effects in electromagnetic data using modern distributed acquisition systems and advanced methods of 3-D inversion. The analysis of IP phenomena is usually based on models with frequency dependent complex conductivity distribution. One of the most popular is the Cole-Cole relaxation model. In this progress report we have constructed and analyzed a different physical and mathematical model of the IP effect based on the effective-medium theory. We have developed a rigorous mathematical model of multi-phase conductive media, which can provide a quantitative tool for evaluation of the type of mineralization, using the conductivity relaxation model parameters. The parameters of the new conductivity relaxation model can be used for discrimination of the different types of rock formations, which is an important goal in mineral exploration. The solution of this problem requires development of an effective numerical method for EM forward modeling in 3-D inhomogeneous media. During the first year of the project we have developed a prototype 3-D IP modeling algorithm using the integral equation (IP) method. Our IE forward modeling code INTEM3DIP is based on the contraction IE method, which improves the convergence rate of the iterative solvers. This code can handle various types of sources and receivers to compute the effect of a complex resistivity model. We have tested the working version of the INTEM3DIP code for computer simulation of the IP data for several models including a southwest US porphyry model and a Kambalda-style nickel sulfide deposit. The numerical modeling study clearly demonstrates how the various complex resistivity models manifest differently in the observed EM data. These modeling studies lay a background for future development of the IP inversion method, directed at determining the electrical conductivity and the intrinsic chargeability distributions, as well as the other parameters of the relaxation model simultaneously. The new technology envisioned in this proposal, will be used for the discrimination of different rocks, and in this way will provide an ability to distinguish between uneconomic mineral deposits and the location of zones of economic mineralization and geothermal resources.

Michael S. Zhdanov

2005-03-09T23:59:59.000Z

137

JGI - Directions  

NLE Websites -- All DOE Office Websites (Extended Search)

Map to JGI Directions from Directions from key local start points, public transit Home > About Us > Map to JGI UC logo DOE logo Contact Us Credits Disclaimer Access...

138

Steel Mesh Coated with Carbon Nanotubes: Its Superhydrophobicity ...  

Science Conference Proceedings (OSTI)

Oil, on the other hand, completely wet the SS-CNTs mesh. Simple ... Application of Biomass Waste Materials in the Nano Mineral Synthesis .... of Iron-Carbon Nanocomposites by Laser Power Variation Throughout the Laser Pyrolysis Process.

139

High temperature mineral fiber binder  

SciTech Connect

A modified phenol formaldehyde condensate is reacted with boric acid and cured in the presence of a polyfunctional nitrogeneous compound to provide a binder for mineral wool fibers which is particularly suited for thermal insulation products intended for high temperature service.

Miedaner, P.M.

1980-11-25T23:59:59.000Z

140

Production of precipitated calcium carbonate from industrial by-product slags (Slag2PCC)  

E-Print Network (OSTI)

a commercial carbonate product by mineral carbonation could allow for higher process costs than what the CO2 a commercial calcium carbonate product should contain as little impurities as possible. Solution temperatureC Carbonation at 30 ºC (XCa = 68 %) Thickener Condenser Acetic acid 5.2 kg Gel residue 1.1 kg NaOH, 2.6 kg

Zevenhoven, Ron

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Mineral Transformation and Biomass Accumulation Associated With  

E-Print Network (OSTI)

Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

Hubbard, Susan

142

REO Mineral Separation from Silicates and Carbonates Host ...  

Science Conference Proceedings (OSTI)

Current Korean R&D and Investment Strategies in Response to REE Demand & Supply Concerns Development of a High Recovery Process Flowsheet for...

143

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...  

Open Energy Info (EERE)

are consistent with deposition during transient boiling or rock-water exchange (fracturing) events. Author(s): N. C. Sturchio, T. E. C. Keith, K. Muehlenbachs Published:...

144

Valorisation of Thermal Residues by Intensified Mineral Carbonation  

Science Conference Proceedings (OSTI)

Selective Recovery of Gold from E-wastes by Using Cellulosic Wastes Stabilization of Chromium-Based Slags with FeS2 and FeSO4 Sulphide Precipitation...

145

Independent Mineral Processing Project Technical Due Diligence  

Science Conference Proceedings (OSTI)

Presentation Title, Independent Mineral Processing Project Technical Due Diligence ... CRIMM Energy-saving Magnetic Separation Equipment and Industrial...

146

Evolution of the quaternary magmatic system, Mineral Mountains, Utah: Interpretations from chemical and experimental modeling  

DOE Green Energy (OSTI)

The evolution of silicic magmas in the upper crust is characterized by the establishment of chemical and thermal gradients in the upper portion of magma chambers. The chemical changes observed in rhyolite magmas erupted over a period of 300,000 years in the Mineral Mountains are similar to those recorded at Twin Peaks, Utah, and in the spatially zoned Bishop Tuff from Long Valley, California. Chemical and fluid dynamic models indicate that cooling of a silicic magma body from the top and sides can result in the formation of a roof zone above a convecting region which is chemically and thermally stratified, as well as highly fractionated and water rich. Crystallization experiments have been performed with sodium carbonate solutions as an analog to crystallization in magmatic systems. Top and side cooling of a homogeneous sodium carbonate solution results in crystallization along the top and sides and upward convection of sodium carbonate-depleted fluid. A stably stratified roof zone, which is increasingly water rich and cooler upwards, develops over a thermally and chemically homogeneous convecting region. Crystallization at the top ultimately ceases, and continued upward convection of water-rich fluid causes a slight undersaturation adjacent to the roof despite cooler temperatures. By analogy, crystallization at the margins of a magma chamber and buoyant rise of the fractionated boundary layer into the roof zone can account for the chemical evolution of the magma system at the Mineral Mountains. To produce compositionally stratified silicic magmas requires thermal input to a silicic system via mafic magmas. The small volume, phenocryst-poor rhyolite magma which persisted for at least 300,000 years in the Mineral Mountains requires the presence of a continued thermal input from a mafic magma source. The presence of silicic lavas signifies that there is a substantial thermal anomaly both in the crust and upper mantle. The production of silicic lavas requires (1) the heating of the lower crust to near the solidus for silicic melts, (2) partial fusion by the additional convective transfer of heat from the mantle by injection of the basaltic magma, (3) continued input of heat in excess of the conductive and convective heat loss to allow the crustal melt to grow to some critical size so that it can rise buoyantly into the upper crust. In the Mineral Mountains there has been an inadequate prolonged thermal flux to produce caldera-forming eruptions. Moreover, the distributed extension in the Basin and Range allows for the propagation of small volumes of magma upward probably in dike-like bodies parallel to the direction of maximum horizontal compressive stress. The erupted lavas represent a highly differentiated and presumably small fraction of the total volume of silicic magma which is contained at considerable depth.

Nash, W.P.; Crecraft, H.R.

1982-09-01T23:59:59.000Z

147

Recovery Act: Carbon Dioxide-Water Emulsion for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxid  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide-Water Carbon Dioxide-Water Emulsion for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide Background The U.S. Department of Energy (DOE) distributed a portion of American Recovery and Reinvestment Act (ARRA) funds to advance technologies for chemical conversion of carbon dioxide (CO 2 ) captured from industrial sources. The focus of the research projects is permanent sequestration of CO 2 through mineralization or development

148

Quarterly minerals outlook, June 1983  

Science Conference Proceedings (OSTI)

An overview is presented of the mineral industry of Wyoming. Petroleum production shows a slight annual decline. Many producers have been shutting in their natural gas wells due to the sharp decline in demand. Activities in the base, precious, and ferrous metals industry are summarized. Uranium and trona production is down from the previous year. Other minerals mentioned are gypsum, limestone, bentonite, and phosphorus. Production of coal is given by county. Electric utilities have not used all the coal they bought last year, and construction of several power plants have been delayed indefinitely. Underground coal gasification projects are mentioned. Tables present production forecasts for coal to 1990, for oil and gas to 1988, and for uranium and trona to 1987. 5 tables.

Glass, G.B.

1983-01-01T23:59:59.000Z

149

Wyoming mineral development monitoring system  

Science Conference Proceedings (OSTI)

The monitoring system covers, or will cover, all segments of the mineral industry except oil and gas exploration under one of eight main sections: coal uranium, bentonite, power plants, refineries, gas plants, synthetic fuels, trona, and others. Projects are grouped alphabetically by county and indexed by county, commodity, and company. Index maps all the location of projects within the state. A notebook format allows easy updating of information on ownership, production, numbers of employees, contracts, etc.

Not Available

1984-01-01T23:59:59.000Z

150

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network (OSTI)

strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush

Rollins, Andrew M.

151

The effects of harvesting intensity on soil CO2 efflux and carbon content in an east Texas bottomland hardwood ecosystem  

E-Print Network (OSTI)

Soil respiration rates have been used as an indicator of soil community activity around the world. An increasing number of studies have been performed using soil respiration rates as a measure of man's impacts on the environment, including forest land. I examined the effects of harvest intensity on in situ and mineral soil respiration, along with total soil and soluble organic carbon, were examined in a bottomland hardwood forest. Treatments included a clearcut, a partial cut, and a non-harvested control. I hypothesized that respiration rates would vary directly with harvest intensity. The sodalime absorption technique was used for determining in situ respiration and the wet alkali method was used for measuring mineral soil respiration in the lab. Soil temperature and moisture content were also measured. Sampling occurred between 6 and 22 months after harvesting. Total soil and soluble organic carbon analyses were performed every three sampling periods beginning with period 6. Total soil organic carbon content was determined by the Walkley-Black method, an acid digest procedure. Soluble organic carbon content was determined from cold-water extracts analyzed with a total organic carbon analyzer. Results indicated that harvesting significantly (a=0.05) increased in situ respiration during most sampling periods. This effect was attributed to the revegetation of the site creating an increase in live root and associated microflora activity in the soil following harvesting. In situ respiration varied directly with soil temperature and inversely with soil moisture. Harvesting effects on mineral soil respiration were less clear and showed trends in only some months. Harvesting significantly (a=0.05) increased the amount of total organic carbon in the top 15 cm, whereas overall soluble organic carbon levels were not significantly affected. I feel that even though harvesting has significantly effected soil respiration rates, this increase will not adversely affect atmospheric C02 levels. Published data show that when temperate forests are allowed to regrow immediately after harvest, carbon assimilated in growing vegetation is greater than the C02 lost from the soil.

Londo, Andrew James

1995-01-01T23:59:59.000Z

152

Accuracy in quantitative phase analysis of complex mineral ...  

Science Conference Proceedings (OSTI)

... Soil formed on a parent material rich in ferromagnesian minerals and amorphous soil minerals Petroleum shale Nickel laterite Bauxite ...

2013-06-07T23:59:59.000Z

153

Minerals  

Science Conference Proceedings (OSTI)

Title, Author, Publisher, Product Type, In Stock, Date Published. Add to Cart, Image, Click on Title to view details, Member (Student) Price, Non-member Price.

154

Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide  

Open Energy Info (EERE)

Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions Project Description Supercritical CO2 is currently becoming a more common fluid for extracting volatile oil and fragrance compounds from various raw materials that are used in perfumery. Furthermore, its use as a heat transmission fluid is very attractive because of the greater uptake capability of heat from hot reservoir rock, compared with that of water. However, one concern was the reactivity of CO2 with clay and rock minerals in aqueous and non-aqueous environments. So if this reaction leads to the formation of water-soluble carbonates, such formation could be detrimental to the integrity of wellbore infrastructure.

155

JGI - Directions  

NLE Websites -- All DOE Office Websites (Extended Search)

Directions Address DOE Joint Genome Institute 2800 Mitchell Drive Walnut Creek, CA 94598 From Oakland Airport Follow Airport exit signs onto AIRPORT DR. Turn RIGHT onto HEGENBERGER...

156

CARBON TETRACHLORIDE  

E-Print Network (OSTI)

This fact sheet answers the most frequently asked health questions (FAQs) about carbon tetrachloride.

unknown authors

2005-01-01T23:59:59.000Z

157

NETL: Carbon Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sequestration Partnerships Regional Carbon Sequestration Partnership (RCSP) Programmatic Points of Contact Carbon Storage Program Infrastructure Coordinator Carbon Storage...

158

High performance ultracapacitors with carbon nanomaterials and ionic liquids  

DOE Patents (OSTI)

The present invention is directed to the use of carbon nanotubes and/or electrolyte structures in various electrochemical devices, such as ultracapacitors having an ionic liquid electrolyte. The carbon nanotubes are preferably aligned carbon nanotubes. Compared to randomly entangled carbon nanotubes, aligned carbon nanotubes can have better defined pore structures and higher specific surface areas.

Lu, Wen; Henry, Kent Douglas

2012-10-09T23:59:59.000Z

159

Mining and minerals policy: 1976 bicentennial edition  

DOE Green Energy (OSTI)

The report is organized into three basic parts. The first part, the Executive Summary, provides a brief description of the major topics and lists the issues and recommendations. The report then is divided into two sections. Section I, Summary, is comprised of three chapters: Increased Energy Security; Metals and Nonmetallic Minerals; and Trends and Events. Section II, Issues in Energy and Minerals Policy, is comprised of seven chapters: Federal Leasing; The Federal Role in Reducing the Fiscal Impacts of Energy Development; Availability of Federal Lands for Mineral Exploration and Development; Environmental Issues and the Mineral Industry; Developments in International Minerals Trade and Investment; Ocean Mining; and The Development of New Tools for Energy and Minerals Policy Analysis. (MCW)

Not Available

1976-07-01T23:59:59.000Z

160

Critical Minerals Policy Act (S. 1113)  

Science Conference Proceedings (OSTI)

Jul 23, 2012 ... surveys and production to research and recycling and, in particular, to see that additional critical mineral supplies can ... Exploration. Strategic...

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Roadmap to the Project: Uranium Miners Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

suggested revisions of criteria for the compensation of lung cancer among underground uranium miners from the eligible regions of the U.S. Radioactive radon (more specifically...

162

Introducing International Minerals Innovation Institute of Saskatchewan  

Science Conference Proceedings (OSTI)

Cross Pollination between Industry and Engineering Programs/Students in Manitoba Improving the Health & Performance of Miners Working at Moderate to

163

Mineral Processing Technology DevelopmentChallenges and ...  

Science Conference Proceedings (OSTI)

Cross Pollination between Industry and Engineering Programs/Students in Manitoba Improving the Health & Performance of Miners Working at Moderate to

164

World Economics of Selected Industrial Minerals  

Science Conference Proceedings (OSTI)

Jan 1, 1971 ... It is a very interesting field, different in many respects from metals and certainly far different from petroleum. The minerals chosen are celestite,...

165

Carbon dioxide disposal in solid form  

SciTech Connect

Coal reserves can provide for the world`s energy needs for centuries. However, coal`s long term use may be severely curtailed if the emission of carbon dioxide into the atmosphere is not eliminated. We present a safe and permanent method of carbon dioxide disposal that is based on combining carbon dioxide chemically with abundant raw materials to form stable carbonate minerals. We discuss the availability of raw materials and potential process designs. We consider our initial rough cost estimate of about 3{cents}/kWh encouraging. The availability of a carbon dioxide fixation technology would serve as insurance in case global warming, or the perception of global warming, causes severe restrictions on carbon dioxide emissions. If the increased energy demand of a growing world population is to be satisfied from coal, the implementation of such a technology would quite likely be unavoidable.

Lackner, K.S.; Butt, D.P.; Sharp, D.H. [Los Alamos National Lab., NM (United States); Wendt, C.H. [Auxon Corp., (United States)

1995-12-31T23:59:59.000Z

166

Minerals yearbook: Mineral industries of Africa. Volume 3. 1992 international review  

SciTech Connect

The 53 countries that constituted Africa in 1992 accounted for a significant portion of total world output of a number of mineral commodities. Among the most significant mineral commodities produced in Africa were andalusite, antimony, asbestos, bauxite, chromite, coal, cobalt, copper, diamond, fluorspar, gold, lithium minerals, manganese, phosphate, platinum-group metals, the titanium minerals-ilmenite and rutile, vanadium, vermiculite, uranium, and zircon. Chromite, cobalt, and manganese, were not mined in the Untied States.

Not Available

1992-01-01T23:59:59.000Z

167

Wall-rock alteration and uranium mineralization in parts of Thomas Range Mining District, San Juan County, Utah, and its significance in mineral exploration  

SciTech Connect

Several important uranium deposits associated with fluorspar and beryllium are located in parts of Thomas Range area. the mineralization is found in dolomites and dolomitic limestones of Paleozoic age and sandstones, tuffs, and rhyolites belonging to the Tertiary Spor Mountain and Topaz Mountain Formations. The pipes, veins, and nodules of fluorspar are replaced by uranium. Veins and disseminations of radioactive fluorspar and opal and overgrowths of secondary minerals are found in rhyolites, tuffs, carbonate rocks, and breccias. The radioactivity in sandstones and conglomerates emanates from weeksite, beta-uranophane, zircon, gummite, and zircon. It also occurs as highly oxidized rare aphanitic grains disseminated in a few ore deposits. The results of the present investigations may influence the initiation of future exploration programs in the Thomas Range mining district. Hydrothermal fluids of deep-seated magmatic origin rich in U, V, Th, Be, and F reacted with the country rocks. The nature and sequence of wall-rock alteration and its paragenetic relationship with the ores have been determined. The mineralization is confined to the altered zones. The ore bodies in the sedimentary rocks and the breccias are located in the fault zones. More than 1000 faults are present in the area, greatly complicating mineral prospecting. The wall-rock alteration is very conspicuous and can be used as a valuable tool in mineral exploration.

Mohammad, H.

1985-05-01T23:59:59.000Z

168

Exploration for uranium deposits, Grants mineral belt  

Science Conference Proceedings (OSTI)

Uranium ore deposits in the Grants mineral belt, New Mexico, occur in fluvial sandstones in the Morrison Formation (Jurassic). Uranium mineralization is concentrated by a dark-gray to black substance that has been identified as humate, which is derived from decaying vegetation. Black ore is truncated by overlying sandstone in at least three ore deposits, documenting an early age for mineralization. Ore deposits in the Grants mineral belt vary greatly in size and shape, tend to occur in clusters, and often present difficult drill targets. Current exploration is largely a matter of drilling in stages to distinguish favorable from unfavorable ground on a wide spacing, to seek mineralization in favorable ground, and to conduct close-spaced drilling in mineralized areas. Criteria for favorability differ among exploration groups but generally include 1) presence of a host sandstone, 2) anomalous mineralization, 3) color of the host rock, 4) presence of carbonaceous matter, and 5) position of the area relative to mineralized trends. A description of the drilling sequence, from ore discovery to the development of a mine at the Johnny M deposit (in the east part of the Ambrosia Lake district), exemplifies the problem of predicting where orebodies may occur. A study of the drill data at the Johnny M indicates the uranium ore is not related to specific geologic features other than humate, which is commonly associated with coalified plant fragments in mudstone-rich parts of the host sandstone.

Fitch, D.C.

1980-01-01T23:59:59.000Z

169

Method for the Production of Mineral Wool andIron from Serpentine Ore  

NLE Websites -- All DOE Office Websites (Extended Search)

the Production of Mineral Wool and Iron from the Production of Mineral Wool and Iron from Serpentine Ore Overview This invention discloses a method to fabricate a product that has the potential to replace asbestos, which harbors health and environmental risks, with magnesium silicate-based mineral wools. The mineral wool product yields advantages similar to asbestos while eliminating its inherent detriments. Since the late 19th century and into the late 20th century, asbestos has been a commonly used building material for home and industrial use. The popularity of its use can be traced to advantages of high resistance to heat, aversion to electrical and chemical damage, high mechanical strength, and excellent acoustical properties. Despite those advantages, asbestos has been directly

170

Nevada Division of Minerals | Open Energy Information  

Open Energy Info (EERE)

Nevada Division of Minerals Nevada Division of Minerals Jump to: navigation, search Logo: Nevada Division of Minerals Name Nevada Division of Minerals Address 400 W. King St. #106 Place Carson City, Nevada Zip 89703 Website http://minerals.state.nv.us/ Coordinates 39.16409°, -119.7699779° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.16409,"lon":-119.7699779,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

171

Direct insolation models  

DOE Green Energy (OSTI)

Several recently published models of the direct component of the broadband insolation are compared for clear sky conditions. The comparison includes seven simple models and one rigorous model that is used as a basis for determining accuracy. Where possible, the comparison is made between the results of each model for each atmospheric constituent (H/sub 2/O, CO/sub 2/, O/sub 3/, O/sub 2/, aerosol and molecular scattering) separately as well as for the combined effect of all of the constituents. Two optimum simple models of varying degrees of complexity are developed as a result of this comparison. The study indicates: aerosols dominate the attenuation of the direct beam for reasonable atmospheric conditions; molecular scattering is next in importance; water vapor is an important absorber; and carbon dioxide and oxygen are relatively unimportant as attenuators of the broadband solar energy.

Bird, R.; Hulstrom, R.L.

1980-01-01T23:59:59.000Z

172

Analysis of Mineral Trapping for CO2 Disposal in Deep Aquifers  

Office of Scientific and Technical Information (OSTI)

Reactive Geochemical Transport Simulation to Study Mineral Trapping Reactive Geochemical Transport Simulation to Study Mineral Trapping for CO 2 Disposal in Deep Saline Arenaceous Aquifers Tianfu Xu, John A. Apps, and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA Abstract. A reactive fluid flow and geochemical transport numerical model for evaluating long-term CO 2 disposal in deep aquifers has been developed. Using this model, we performed a number of sensitivity simulations under CO 2 injection conditions for a commonly encountered Gulf Coast sediment to analyze the impact of CO 2 immobilization through carbonate precipitation. Geochemical models are needed because alteration of the predominant host rock aluminosilicate minerals is very slow and is not

173

Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor-Dominated  

Open Energy Info (EERE)

Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor-Dominated Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor-Dominated Hydrothermal System At The Geysers, Sonoma County, California Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor-Dominated Hydrothermal System At The Geysers, Sonoma County, California Details Activities (5) Areas (1) Regions (0) Abstract: The Geysers, a vapor-dominated hydrothermal system, is developed in host rock of the Franciscan Formation, which contains veins of quartz and calcite whose Δ18O values record the temperatures and isotopic compositions of fluids prevailing during at least two different episodes of rock-fluid interaction. The first episode took place at about 200°C, during which marine silica and carbonate apparently interacted with ocean

174

Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cycle Carbon Cycle Latest Global Carbon Budget Estimates Including CDIAC Estimates Terrestrial Carbon Management Data Sets and Analyses Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Monthly Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (2012) Monthly Fossil-Fuel CO2 Emissions: Isomass (δ 13C) of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Estimates of Monthly CO2 Emissions and Associated 13C/12C Values

175

Carbon Isotopes  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Carbon Isotopes Atmospheric Trace Gases » Carbon Isotopes Carbon Isotopes Gateway Pages to Isotopes Data Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane 800,000 Deuterium Record and Shorter Records of Various Isotopic Species from Ice Cores Carbon-13 13C in CO Measurements from Niwot Ridge, Colorado and Montana de Oro, California (Tyler) 13C in CO2 NOAA/CMDL Flask Network (White and Vaughn) CSIRO GASLAB Flask Network (Allison, Francey, and Krummel) CSIRO in situ measurements at Cape Grim, Tasmania (Francey and Allison) Scripps Institution of Oceanography (Keeling et al.) 13C in CH4 NOAA/CMDL Flask Network (Miller and White) Northern & Southern Hemisphere Sites (Quay and Stutsman) Northern & Southern Hemisphere Sites (Stevens)

176

Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility  

SciTech Connect

With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

Metz, Paul; Bolz, Patricia

2013-03-25T23:59:59.000Z

177

Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures  

By incorporating amines inside clay containing quaternary ammonium salts (organoclay) minerals, this invention has created a way to prepare sorbents that capture carbon dioxide (CO2) from low temperature and low pressure gas streams. In this process, ...

178

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

Science Conference Proceedings (OSTI)

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

179

Illinois mineral industry in 1984 and review of preliminary mineral production data for 1985. Illinois mineral notes  

SciTech Connect

The annual output and value of Illinois minerals extracted, processed, and manufactured into products in 1984 are summarized in the report. Materials used in manufacturing were not necessarily extracted within the state. Coal continued to be the leading commodity in terms of value; oil ranked second; stone and sand and gravel ranked third and fourth; fluorspar was fifth. Nationally, Illinois ranked eighteenth in value of nonfuel mineral production. It remained the principal U.S. producer of fluorspar, tripoli, and industrial sand and led in the manufacture of iron-oxide pigments. In stone and peat production, the state ranked fourth. Preliminary data for 1985 indicate that the value of minerals mined was $2,947.8 million, a decrease of 6.1 percent from the $3,138.0 million in 1984. Detailed production summaries and analyses--including maps, tables, and graphs--for all mineral commodities are based on data available for 1984.

Samson, I.E.; Bhagwat, S.B.

1986-01-01T23:59:59.000Z

180

Vietnam National Coal Mineral Industries Group Vinacomin | Open...  

Open Energy Info (EERE)

Coal Mineral Industries Group Vinacomin Jump to: navigation, search Name Vietnam National Coal-Mineral Industries Group (Vinacomin) Place Vietnam Product Vietnam-based project...

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Oil, Gas, and Minerals, Exploration and Production, Lease of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oil, Gas, and Minerals, Exploration and Production, Lease of Public Land (Iowa) Oil, Gas, and Minerals, Exploration and Production, Lease of Public Land (Iowa) Eligibility Utility...

182

DOE - Office of Legacy Management -- International Minerals and...  

Office of Legacy Management (LM)

International Minerals and Chemical Corp - Pilot Plant - FL 02 FUSRAP Considered Sites Site: International Minerals and Chemical Corp - Pilot Plant (FL.02) Designated Name: Not...

183

Relations Of Ammonium Minerals At Several Hydrothermal Systems...  

Open Energy Info (EERE)

minerals at known hydrothermal systems is critical for the proper interpretation of remote sensing data and for testing of possible links to mineralization. Submicroscopic...

184

"Terrywallaceite" now in official roster of known minerals  

NLE Websites -- All DOE Office Websites (Extended Search)

metallic-black crystals of Terrywallaceite were found in the Julcani Mining District of Peru. June 8, 2011 The mineral "Terrywallaceite" The mineral "Terrywallaceite" I am honored...

185

Underground radio technology saves miners and emergency response...  

NLE Websites -- All DOE Office Websites (Extended Search)

Underground radio technology saves miners and emergency response personnel Underground radio technology saves miners and emergency response personnel Founded through LANL, Vital...

186

Transition metal-catalyzed process for addition of amines to carbon-carbon double bonds  

DOE Patents (OSTI)

The present invention is directed to a process for addition of amines to carbon-carbon double bonds in a substrate, comprising: reacting an amine with a compound containing at least one carbon-carbon double bond in the presence a transition metal catalyst under reaction conditions effective to form a product having a covalent bond between the amine and a carbon atom of the former carbon-carbon double bond. The transition metal catalyst comprises a Group 8 metal and a ligand containing one or more 2-electron donor atoms. The present invention is also directed to enantioselective reactions of amine compounds with compounds containing carbon-carbon double bonds, and a calorimetric assay to evaluate potential catalysts in these reactions.

Hartwig, John F. (Durham, CT); Kawatsura, Motoi (Chatham, NJ); Loeber, Oliver (New Haven, CT)

2002-01-01T23:59:59.000Z

187

A study of dermatitis in trona miners and millers  

Science Conference Proceedings (OSTI)

Trona (sodium sesquicarbonate) is mined from an underground deposit in Wyoming and processed for use in the manufacture of glass, paper, and detergents, and in chemical applications. Trona dust is alkaline (pH 10.5) and may have an irritant effect on the respiratory airways, mucous membranes, and the skin. One hundred forty-two underground miners and 88 surface workers from one trona facility participated voluntarily in an epidemiologic and clinical study. Their mean age was 37.6 and their mean working period, 10.0 years. One half of the study participants complained of skin symptoms; dermatologic symptoms increased from twofold to fifteenfold after the subjects began trona mining. Trona dermatitis consists of pruritic, erythematous, raised, dry, and fissured lesions commonly affecting the hands, arms, and legs. A dose-response relationship was observed among underground workers. Patch testing with 10% aqueous trona and sodium carbonate was negative, suggesting that the dermatitis was primarily irritant in nature.

Rom, W.N.; Moshell, A.; Greaves, W.; Bang, K.M.; Holthouser, M.; Campbell, D.; Bernstein, R.

1983-04-01T23:59:59.000Z

188

Process for removal of mineral particulates from coal-derived liquids  

SciTech Connect

Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

McDowell, William J. (Knoxville, TN)

1980-01-01T23:59:59.000Z

189

Analysis of Potential Leakage Pathways and Mineralization within Caprocks for Geologic Storage of CO(sub 2}  

Science Conference Proceedings (OSTI)

We used a multifaceted approach to investigate the nature of caprocks above, and the interface between, reservoir-?quality rocks that might serve as targets for carbon storage. Fieldwork in southeastern Utah examined the regional-? to m-?scale nature of faults and fractures across the sedimentiological interfaces. We also used microscopic analyses and mechanical modeling to examine the question as to how the contacts between units interact, and how fractures may allow fluids to move from reservoirs to caprock. Regional-?scale analyses using ASTER data enabled us to identify location of alteration, which led to site-?specific studies of deformation and fluid flow. In the Jurassic Carmel Formation, a seal for the Navajo Sandstone, we evaluated mesoscale variability in fracture density and morphology and variability in elastic moduli in the Jurassic Carmel Formation, a proposed seal to the underlying Navajo Sandstone for CO{sub 2} geosequestration. By combining mechano-?stratigraphic outcrop observations with elastic moduli derived from wireline log data, we characterize the variability in fracture pattern and morphology with the observed variability in rock strength within this heterolithic top seal. Outcrop inventories of discontinuities show fracture densities decrease as bed thickness increases and fracture propagation morphology across lithologic interfaces vary with changing interface type. Dynamic elastic moduli, calculated from wireline log data, show that Youngs modulus varies by up to 40 GPa across depositional interfaces, and by an average of 3 GPa across the reservoir/seal interface. We expect that the mesoscale changes in rock strength will affect the distributions of localized stress and thereby influence fracture propagation and fluid flow behavior within the seal. These data provide a means to closely tie outcrop observations to those derived from subsurface data and estimates of subsurface rock strength. We also studied damage zones associated normal faults in the Permian Cedar Mesa Sandstone, southeastern Utah. These faults are characterized by a single slip surfaces and damage zones containing deformation bands, veins, and joints. Field observations include crosscutting relationships, permeability increase, rock strength decrease, and ultraviolet light induced mineral fluorescence within the damage zone. These field observations combined with the interpreted paragenetic sequence from petrographic analysis, suggests a deformation history of reactivation and several mineralization events in an otherwise low-?permeability fault. All deformation bands and veins fluoresce under ultraviolet light, suggesting connectivity and a shared mineralization history. Pre-?existing deformation features act as loci for younger deformation and mineralization events, this fault and its damage zone illustrate the importance of the fault damage zone to subsurface fluid flow. We model a simplified stress history in order to understand the importance of rock properties and magnitude of tectonic stress on the deformation features within the damage zone. The moderate confining pressures, possible variations in pore pressure, and the porous, fine-?grained nature of the Cedar Mesa Sandstone results in a fault damage zone characterized by enhanced permeability, subsurface fluid flow, and mineralization. Structural setting greatly influences fracture spacing and orientation. Three structural settings were examined and include fault proximity, a fold limb of constant dip, and a setting proximal to the syncline hinge. Fracture spacing and dominant fracture orientation vary at each setting and distinctions between regional and local paleo-?stress directions can be made. Joints on the fold limb strike normal to the fold axis/bedding and are interpreted to be sub-?parallel to the maximum regional paleo-?stress direction as there is no fold related strain. Joints proximal to faults and the syncline hinge may have formed under local stress conditions associated with folding and faulting, and

Evans, James

2012-11-30T23:59:59.000Z

190

Minerals on School and Public Lands  

Energy.gov (U.S. Department of Energy (DOE))

The Commissioner of School and Public Lands is authorized to lease the mineral interests of such lands for development. Section 5-7 of the SD Codified Laws describes provisions for the leasing of...

191

Hydrothermal alteration mineral mapping using hyperspectral imagery...  

Open Energy Info (EERE)

front of the Stillwater Mountain Range inDixie Valley, Nevada. Analysis of this data set reveals that severaloutcrops of these altered minerals exist in the area, and thatone...

192

Oil, Gas, and Metallic Minerals (Iowa)  

Energy.gov (U.S. Department of Energy (DOE))

Operators of oil, gas, and metallic mineral exploration and production operations are required to obtain a drilling permit from the Iowa Department of Natural Resources and file specific forms with...

193

Sustainable growth and valuation of mineral reserves  

E-Print Network (OSTI)

The annual change in the value of an in-ground mineral is equal to the increase or decrease of inventories ("reserves"), multiplied by the market value of a reserve unit. The limited shrinking resource base does not exist. ...

Adelman, Morris Albert

1994-01-01T23:59:59.000Z

194

Water and Energy in Mineral Processing  

Science Conference Proceedings (OSTI)

The theme will be "Water and energy in mineral processing". ... Analysis of Polymer Adsorption on Hematite Using Zeta Potential Distributions ... Trends with Selection and Sizing Large Flotation Circuits- What's Available in the Market Place.

195

Mineral Leases by Political Subdivisions (Texas)  

Energy.gov (U.S. Department of Energy (DOE))

This legislation authorizes local political subdivisions to lease lands they own for the development of mineral interests, including coal and lignite. A public hearing process is required prior to...

196

Uranium mineralization in fluorine-enriched volcanic rocks  

Science Conference Proceedings (OSTI)

Several uranium and other lithophile element deposits are located within or adjacent to small middle to late Cenozoic, fluorine-rich rhyolitic dome complexes. Examples studied include Spor Mountain, Utah (Be-U-F), the Honeycomb Hills, Utah (Be-U), the Wah Wah Mountains, Utah (U-F), and the Black Range-Sierra Cuchillo, New Mexico (Sn-Be-W-F). The formation of these and similar deposits begins with the emplacement of a rhyolitic magma, enriched in lithophile metals and complexing fluorine, that rises to a shallow crustal level, where its roof zone may become further enriched in volatiles and the ore elements. During initial explosive volcanic activity, aprons of lithicrich tuffs are erupted around the vents. These early pyroclastic deposits commonly host the mineralization, due to their initial enrichment in the lithophile elements, their permeability, and the reactivity of their foreign lithic inclusions (particularly carbonate rocks). The pyroclastics are capped and preserved by thick topaz rhyolite domes and flows that can serve as a source of heat and of additional quantities of ore elements. Devitrification, vapor-phase crystallization, or fumarolic alteration may free the ore elements from the glassy matrix and place them in a form readily leached by percolating meteoric waters. Heat from the rhyolitic sheets drives such waters through the system, generally into and up the vents and out through the early tuffs. Secondary alteration zones (K-feldspar, sericite, silica, clays, fluorite, carbonate, and zeolites) and economic mineral concentrations may form in response to this low temperature (less than 200 C) circulation. After cooling, meteoric water continues to migrate through the system, modifying the distribution and concentration of the ore elements (especially uranium).

Burt, D.M.; Sheridan, M.F.; Bikun, J.; Christiansen, E.; Correa, B.; Murphy, B.; Self, S.

1980-09-01T23:59:59.000Z

197

Carbon Nanotubes  

Science Conference Proceedings (OSTI)

Carbon Nanotubes. Sponsored by: TMS Electronic, Magnetic and Photonic Materials Division Date and Time: Sunday, February 13, 2005 ~ 8:30 am-5:00 pm

198

Carbon Nanomaterials  

Science Conference Proceedings (OSTI)

Mar 12, 2012 ... The graphene film was spin-coated using carbon nanotubes to form the cathode of the field emission device. A phosphor coated graphene-PET...

199

Geochronologic studies in the Grants mineral belt  

SciTech Connect

Geologic observation coupled with radiometric age dating can be used to assess ages of ore formation and, in some cases, ages of sedimentation in the Grants mineral belt. Rb-Sr studies indicate the earliest mineralization is trend ore at Ambrosia Lake and Smith Lake, dated at 139 +- 9.5 m.y. This date is similar to that for barren-rock montmorillonite from the Jackpile sandstone (Late Jurassic): 142 +- 14 m.y.; it may be used, with caution, to indicate the minimum age of sedimentation for the Morrison Formation. Geologic evidence indicates epigenetic rather than syngenetic ore formation. Barren-rock montmorillonites from Ambrosia Lake yield a poorly defined isochron of 132 +- 26 m.y. Early formed ore at the Jackpile-Paguate mine, Laguna district, was remobilized and reprecipitated at 113 +- 7 m.y. This date is older than the range of dates for the Dakota Formation (Cretaceous) and Mancos Shale. The 113 +- 7 m.y. mid-Cretaceous date for the Jackpile-Paguate ore is consistent with geologic evidence; geologic control suggests that other ore deposits are post-Late Jurassic but pre-Dakota Formation. Based on geologic evidence, mineralization in the Dakota Formation is thought to be very young. Laramide mineralization (60 to 70 m.y.) is evidenced by the presence of some stack ore. At least one uranium deposit, located partly in oxidized ground at the main redox front of the Grants mineral belt, may represent Tertiary mineralization; the clay-mineral Rb-Sr systematics of this deposit have been severely perturbed. Younger mineralization is indicated by U-Pb dates on uranophane (9 to 10 m.y.), and Pleistocene mineralization is noted for some ore. U-Pb dates of U/sup 4 +/ -rich ore minerals cluster between 80 and 100 m.y., although some are as old as 140 to 150 m.y. K-Ar dates on clay minerals range from 49 to 138 m.y. The reasons for this scatter are not known, although loss of radiogenic /sup 40/Ar due to burial is probable.

Brookins, D.G.

1980-01-01T23:59:59.000Z

200

Absorbents for Mineral Oil Spill Cleanup  

Science Conference Proceedings (OSTI)

Residual mineral oil on the ground surface following electrical equipment spills is often removed using a surface application of an absorbent material. Traditional absorbent products include clays, sawdust-like products, silica-based products, and various organic industry byproduct materials. After the material has had time to absorb the mineral oil on the ground surface, it is removed and normally sent to a landfill with a liner and leachate collection system designed to Subtitle D standards for municip...

2011-08-23T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Mineral Wool Production Monitoring Using Neural Networks  

E-Print Network (OSTI)

Homogeneity of the primary layer in mineral wool production process is required for high quality products. State-of-the-art measurement techniques for the evaluation of primary layer homogeneity are very slow and can only be applied after the product is manufactured. We present here a method that enables on-line monitoring and control and is based on experimental modeling using neural networks. The experimental method is based on image acquisition and image processing of the mineral wool primary layer structure. As a estimator of the mineral wool primary layer structure and quality, the weight of the primary wool layer is used, measured by an on- line weighting device in four locations of the conveyor belt. The instrumentation of on- line weighting device was upgraded for the purpose of the present experiment and enabled high speed acquisition of all measurement channels. The structure of the mineral wool primary layer was measured by visualization of the modified entrance to the on- line balance using a CCD camera. All data channels were simultaneously sampled. Radial basis neural networks are used for prediction. The structure of the mineral wool primary layer is predicted on the basis of experimentally provided weights data. The learning set consists of weights- images pairs. The prediction of the mineral wool primary layer structure consists of providing only weights. A good agreement between statistical properties of measured and modeled structures of the primary wool layer like spatial homogeneity of the primary mineral wool layer thickness, is shown. The results of the study confirm that the time- delayed vector of weights bears enough information for the monitoring of the production process. The modeling of primary mineral wool structure is of lesser quality due to high dimensionality of the modeled variable.

Marko Ho?evar; Brane irok; Bogdan Blagojevi?

2005-01-01T23:59:59.000Z

202

Minerals yearbook: Mineral industries of Africa. Volume 3. 1990 international review  

SciTech Connect

The 53 countries that constituted Africa in 1990 accounted for a significant portion of total world output of a number of mineral commodities. Among the most significant to be produced in Africa were andalusite, antimony, asbestos, bauxite, chromite, coal, cobalt, copper, diamond, fluorspar, gold, lithium minerals, manganese, phosphate, platinum-group metals, the titanium minerals--ilmenite and rutile, vanadium, vermiculite, uranium, and zircon. Several of these, chromite, cobalt, diamond, and manganese, were not produced in the United States.

Not Available

1990-01-01T23:59:59.000Z

203

Carbons for lithium ion cells prepared using sepiolite as an inorganic template.  

DOE Green Energy (OSTI)

Carbon anodes for Li ion cells have been prepared by the in situ polymerization of olefins such as propylene and ethylene in the channels of sepiolite clay mineral. Upon dissolution of the inorganic framework, a disordered carbon was obtained. The carbon was tested as anode in coin cells, yielding a reversible capacity of 633 mAh/g, 1.70 times higher than the capacity delivered by graphitic carbon, assuming 100% efficiency. The coulombic efficiency was higher than 90%.

Sandi, G.

1998-12-09T23:59:59.000Z

204

Number, Mass and Volume Distributions of Mineral Aerosol and Soils of the Sahara  

Science Conference Proceedings (OSTI)

A direct method will be described to determine the complete mineral size distribution in aerosol (xylene-insoluble component) and soils (water-insoluble component) covering a size range from 0.01 up to 100 ?m and 1000 ?m radius, respectively, by ...

Guillaume A. d'Almeida; Lothar Schtz

1983-02-01T23:59:59.000Z

205

Mineral and water resources of Nevada  

SciTech Connect

The mineral and water resources of Nevada are summarily described in this report. Following a general description of the mineral industry and of the geology of the State as a whole, the occurrence, distribution, and relative importance of individual commodities are discussed in some detail. All mineral commodities are described that are known to occur in Nevada and that might have economic significance in the foreseeable future, whether or not they have been mined. In the description of the geology of the State, a section on economic geology describes the distribution of the metallic and nonmetallic mineral deposits both areally and with respect to the general geologic features. A knowledge of the pattern of distribution of known mineral deposits of various types is essential to the successful search for new ore bodies. A section on mineral exploration discusses the methods and problems of exploration, and also considers which commodities in Nevada offer the greatest promise of new discoveries in the future. Water resources are described rather fully in this report; water in this generally arid part of the Great Basin is vital to the economy of the State and to the well-being of its people. Sources of waterpower and geothermal power are also discussed. (auth)

1974-01-01T23:59:59.000Z

206

Illinois mineral industry in 1978, and review of preliminary mineral production data for 1979  

SciTech Connect

This annual report of mineral production in Illinois in 1978 summarizes the output and value of minerals mined, and processed in Illinois, and of mineral products manufactured but not necessarily mined in Illinois. The total value of production in all three categories was $3170.7 million. The total value of mineral materials mined was $1637.0 million, with the mineral fuels-coal, crude oil, and natural gas-contributing 80.7 percent of the total value. Processed mineral materials were valued at $1206.9 million, and mineral products manufactured totaled $326.8 million in 1978. Coal continued to be the leading commodity in terms of value; oil ranked second; stone and sand and gravel, used largely for construction, ranked third and fourth; and fluorspar was fifth. Illinois remained the leading US producer of fluorspar, tripoli, and industrial sand, and ranked third in stone and peat, fifth in bituminous coal, sixth in total sand and gravel. Preliminary data indicate that the value of minerals mined in 1979 reached an all time high of $2131.0 million, from $1637.0 million in 1978. Detailed production summaries and analyses-including maps, tables, and graphs-are given for all mineral commodities.

Samson, I.

1981-02-01T23:59:59.000Z

207

Carbon Sequestration 101  

NLE Websites -- All DOE Office Websites (Extended Search)

Perspectives on Carbon Capture and Storage Perspectives on Carbon Capture and Storage - Directions, Challenges, and Opportunities Thomas J. Feeley, III National Energy Technology Laboratory Carbon Capture and Storage November 13-15, 2007 Austin, Texas C Capture & Storage, Austin, TX Nov. 13-15, 2007 U.S. Fossil Fuel Reserves / Production Ratio 250+ Year Supply at Current Demand Levels ! 258 11.7 9.7 0 100 200 300 Coal Oil Natural Gas Anthracite & Bituminous Sub- Bituminous & Lignite Sources: BP Statistical Review, June 2004, - for coal reserves data - World Energy Council; EIA, Advance Summary U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Reserves, 2003 Annual Report, September 22, 2004 - for oil and gas reserves data. C Capture & Storage, Austin, TX Nov. 13-15, 2007 80 120 160 200 240 1970 1975 1980

208

Carbon Materials Breakout Group  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Breakout Group Process Materials Breakout Group Process * Day 2, Thursday - Review results of Day 1 and modify if needed - Identify critical R&D needs - Outline R&D plan with key milestones - Report results to plenary Carbon Materials Breakout Group * Key Results - Target: get the science right to engineer carbon materials for hydrogen storage * Integrate theory, experiment, engineering * Understand mechanisms, effects, and interactions ranging from physisorption to chemisorption - Theory * Provide "directional" guidance for experiments (and vice- versa) * Provide baseline theory to elucidate parameters affecting the number and type of binding sites and the heat of their interaction with H2 (∆H ) for a broad range of (highly) modified carbon materials

209

NETL: Carbon Storage - Carbon Sequestration Leadership Forum  

NLE Websites -- All DOE Office Websites (Extended Search)

CSLF Carbon Storage Carbon Sequestration Leadership Forum CSLF Logo The Carbon Sequestration Leadership Forum (CSLF) is a voluntary climate initiative of industrially developed and...

210

Injection of CO2 with H2S and SO2 and Subsequent Mineral Trapping in Sandstone-Shale Formation  

Science Conference Proceedings (OSTI)

Carbon dioxide (CO{sub 2}) injection into deep geologic formations can potentially reduce atmospheric emissions of greenhouse gases. Sequestering less-pure CO{sub 2} waste streams (containing H{sub 2}S and/or SO{sub 2}) would be less expensive or would require less energy than separating CO{sub 2} from flue gas or a coal gasification process. The long-term interaction of these injected acid gases with shale-confining layers of a sandstone injection zone has not been well investigated. We therefore have developed a conceptual model of injection of CO{sub 2} with H{sub 2}S and/or SO{sub 2} into a sandstone-shale sequence, using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments of the United States. We have performed numerical simulations of a 1-D radial well region considering sandstone alone and a 2-D model using a sandstone-shale sequence under acid-gas injection conditions. Results indicate that shale plays a limited role in mineral alteration and sequestration of gases within a sandstone horizon for short time periods (10,000 years in present simulations). The co-injection of SO{sub 2} results in different pH distribution, mineral alteration patterns, and CO{sub 2} mineral sequestration than the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Simulations generate a zonal distribution of mineral alteration and formation of carbon and sulfur trapping minerals that depends on the pH distribution. The co-injection of SO{sub 2} results in a larger and stronger acidified zone close to the well. Precipitation of carbon trapping minerals occurs within the higher pH regions beyond the acidified zones. In contrast, sulfur trapping minerals are stable at low pH ranges (below 5) within the front of the acidified zone. Corrosion and well abandonment due to the co-injection of SO{sub 2} could be important issues. Significant CO{sub 2} is sequestered in ankerite and dawsonite, and some in siderite. The CO{sub 2} mineral-trapping capability can reach 80 kg per cubic meter of medium. Most sulfur is trapped through alunite precipitation, although some is trapped by anhydrite precipitation and minor amount of pyrite. The addition of the acid gases and induced mineral alteration result in changes in porosity. The limited information currently available on the mineralogy of natural high-pressure acid-gas reservoirs is generally consistent with our simulations.

Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

2004-09-07T23:59:59.000Z

211

Method for the Production of Mineral Wool and Iron from Serpentine Ore  

mineral wools. The mineral wool product yields advantages similar to asbestos while eliminating its inherent detriments.

212

Carbon films produced from ionic liquid carbon precursors  

Science Conference Proceedings (OSTI)

The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

Dai, Sheng; Luo, Huimin; Lee, Je Seung

2013-11-05T23:59:59.000Z

213

THE BLACK-EARED MINER A DECADE OF RECOVERY  

E-Print Network (OSTI)

THE BLACK-EARED MINER A DECADE OF RECOVERY David Baker-Gabb 2007 #12;Copyright © 2007. All or otherwise without prior written permission. The Black-eared Miner. A Decade of Recovery. © 2007 Black-eared Miner Recovery Team. Recommended citation: Baker-Gabb, D. (2007). The Black-eared Miner. A Decade

Frappell, Peter

214

A Method for Detecting Miners in Underground Coal Mine Videos  

Science Conference Proceedings (OSTI)

Detecting miners in underground coal mine videos is significant for the production safety. But, the miners are very similar to the background in underground coal mine videos, it is difficult to detect. In this paper, we proposed a method to detect miners ... Keywords: moving detection, miner detection, underground coal mine video

Limei Cai; Jiansheng Qian

2009-12-01T23:59:59.000Z

215

Yemen Ministry of Oil and Minerals | Open Energy Information  

Open Energy Info (EERE)

Yemen Ministry of Oil and Minerals Yemen Ministry of Oil and Minerals Jump to: navigation, search Logo: Yemen Ministry of Oil and Minerals Country Yemen Name Yemen Ministry of Oil and Minerals Website http://www.mom.gov.ye/en/ References Yemen Ministry of Oil and Minerals Website[1] The Yemen Ministry of Oil and Minerals Website contains some content in English. Associated Organizations Yemeni Company for Oil-Product Distribution Petroleum Exploration and Production Authority Safr Company for Scouting Production Operations Organization of Oil Scouting Aden Refinery Company Yemen Company for Oil Refining Yemen Investments Company for Oil & Mineral Geological Land Survey & Mineral Wealth Organization References ↑ "Yemen Ministry of Oil and Minerals Website" Retrieved from "http://en.openei.org/w/index.php?title=Yemen_Ministry_of_Oil_and_Minerals&oldid=334954"

216

Mining and Minerals Policy Act of 1970 | Open Energy Information  

Open Energy Info (EERE)

and Minerals Policy Act of 1970 and Minerals Policy Act of 1970 Jump to: navigation, search Statute Name Mining and Minerals Policy Act of 1970 Year 1970 Url Actof1970.jpg Description An amendment to the Mineral Leasing Act References Mining and Minerals Policy Act of 1970[1] The Mining and Minerals Policy Act of 1970 (30 U.S.C. § 21 et seq.) - An amendment to the Mineral Leasing Act, this statute encompasses both hard rock mining and oil and gas and established modern federal policy regarding mineral resources in the United States. The Act articulates a national interest to foster and encourage private enterprise while mitigating adverse environmental impacts. References ↑ "Mining and Minerals Policy Act of 1970" Retrieved from "http://en.openei.org/w/index.php?title=Mining_and_Minerals_Policy_Act_of_1970&oldid=334610"

217

MINERAL RESOURCES Mineral Resources is divided into two subsections: general and  

E-Print Network (OSTI)

: subsidies and tax incentives; regulations; research programs; and mining laws. The energy minerals; geothermal energy; coal; and other miscellaneous energy technology. General Folder 363. Mineral Resources-1965. Statement of Assistant Secretary of Interior C. Girard Davidson before the House Subcommittee on Mines

US Army Corps of Engineers

218

The Influence of Reduced Carbon on Alloy 718  

Science Conference Proceedings (OSTI)

at .008% carbon. Therefore, reducing carbon has the potential for improving. LCF life. Toughness, as ... towards reducing carbides. The most direct approach to eliminate carbides as LCF initiation sites ..... and Nickel-Iron. Base Superalloys",.

219

Method for producing carbon nanotubes  

DOE Patents (OSTI)

Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

Phillips, Jonathan (Santa Fe, NM); Perry, William L. (Jemez Springs, NM); Chen, Chun-Ku (Albuquerque, NM)

2006-02-14T23:59:59.000Z

220

Shale caprock integrity under carbon sequestration conditions  

Science Conference Proceedings (OSTI)

Carbon sequestration technology requires injection and storage of large volumes of carbon dioxide ( CO 2 ) in subsurface geological formations. Shale caprock which constitutes more than 60% of effective seals for geologic hydrocarbon bearing formations are therefore of considerable interest in underground CO 2 storage into depleted oil and gas formations. This study investigated experimentally shale caprocks geophysical and geochemical behavior when in contact with aqueous CO 2 over a long period of time. The primary concern is a potential increase in hydraulic conductivity of clay-rich rocks as a result of acidic brine-rock minerals geochemical interactions. Both

Abiola Olabode; Lauren Bentley; Mileva Radonjic

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cycle Print E-mail U.S. Carbon Cycle Science Program U.S. Carbon Cycle Science Program The U.S. Carbon Cycle Science Program, in consultation with the Carbon Cycle...

222

Illinois mineral industry in 1981-83 and review of preliminary mineral production data for 1984. Illinois mineral notes  

SciTech Connect

The output and value of minerals mined, processed, and manufactured into products in Illinois are summarized in this report for 1981-83. Materials used in manufacturing were not necessarily extracted within the state. Coal continued to be the leading commodity in terms of value. Oil ranked second; stone, third; sand and gravel, fourth; and fluorspar, fifth.

Samson, I.E.; Bhagwat, S.B.

1985-01-01T23:59:59.000Z

223

Coal Energy Conversion with Aquifer-Based Carbon Sequestration: An Approach to Electric Power Generation with  

E-Print Network (OSTI)

Coal Energy Conversion with Aquifer-Based Carbon Sequestration: An Approach to Electric Power an impermeable seal to prevent it from escaping the aquifer. The proposed alternative technology processes coal carbon and non-mineral coal combustion products in the process. This stream is denser than the aquifer

Nur, Amos

224

waste recycling in mineral and metallurgical industries  

Science Conference Proceedings (OSTI)

A Computer Simulation of an Agitation Mill Abrasion Process for Waste Printed ... Effect of Electricity Mix and Ore Grade on the Carbon Footprint of Chilean...

225

Characterization of Minerals, Metals and Materials 2014  

Science Conference Proceedings (OSTI)

Jul 15, 2013... carbon, electronic, magnetic and optical materials, energy materials, ... Comparison between Bio-composite Based on Green HDPE/ Brazil...

226

Property:MineralManager | Open Energy Information  

Open Energy Info (EERE)

MineralManager MineralManager Jump to: navigation, search Property Name MineralManager Property Type Page Pages using the property "MineralManager" Showing 25 pages using this property. (previous 25) (next 25) B BLM-NV-WN-ES-08-01-1310, NV-020-08-01 + BLM + C CA-017-05-051 + BLM + CA-170-02-15 + BLM + CA-650-2005-086 + BLM + CA-670-2010-107 + BLM + CA-670-2010-CX + BLM + D DOE-EA-1733 + California + DOE-EA-1759 + Naknek Electric Association + DOE-EA-1849 + BLM + DOE-EIS-0298 + BLM + DOI-BLM-CA-C050-2009-0005-EA + BLM + DOI-BLM-CA-EA-2002-??? + BLM + DOI-BLM-CA-ES-2013-002+1793-EIS + BLM +, BLM + DOI-BLM-ID-220-2009-EA-3709 + BLM + DOI-BLM-ID-B010-2010-0083-CX + BLM + DOI-BLM-ID-I020-2012-0017-CX + BLM + DOI-BLM-ID-T020-2012-0003-CX + BLM + DOI-BLM-NM-L000-2012-0020-DNA + BLM +

227

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and...

228

Effects of physical and geochemical heterogeneities on mineral transformation and biomass accumulation during uranium bioremediation at Rifle, Colorado  

E-Print Network (OSTI)

2009. Mineral transformation and biomass accumulation duringof mineral precipitates and biomass during bioremediation aton mineral transformation and biomass accumulation during

Li, Li

2010-01-01T23:59:59.000Z

229

Carbon supercapacitors  

SciTech Connect

Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

Delnick, F.M.

1993-11-01T23:59:59.000Z

230

Carbon particles  

DOE Patents (OSTI)

A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

Hunt, Arlon J. (Oakland, CA)

1984-01-01T23:59:59.000Z

231

On leakage and seepage from geological carbon sequestration sites  

SciTech Connect

Geologic carbon sequestration is one strategy for reducing the rate of increase of global atmospheric carbon dioxide (CO{sub 2} ) concentrations (IEA, 1997; Reichle, 2000). As used here, the term geologic carbon sequestration refers to the direct injection of supercritical CO{sub 2} deep into subsurface target formations. These target formations will typically be either depleted oil and gas reservoirs, or brine-filled permeable formations referred to here as brine formations. Injected CO{sub 2} will tend to be trapped by one or more of the following mechanisms: (1) permeability trapping, for example when buoyant supercritical CO{sub 2} rises until trapped by a confining caprock; (2) solubility trapping, for example when CO{sub 2} dissolves into the aqueous phase in water-saturated formations, or (3) mineralogic trapping, such as occurs when CO{sub 2} reacts to produce stable carbonate minerals. When CO{sub 2} is trapped in the subsurface by any of these mechanisms, it is effectively sequestered away from the atmosphere where it would otherwise act as a greenhouse gas. The purpose of this report is to summarize our work aimed at quantifying potential CO{sub 2} seepage due to leakage from geologic carbon sequestration sites. The approach we take is to present first the relevant properties of CO{sub 2} over the range of conditions from the deep subsurface to the vadose zone (Section 2), and then discuss conceptual models for how leakage might occur (Section 3). The discussion includes consideration of gas reservoir and natural gas storage analogs, along with some simple estimates of seepage based on assumed leakage rates. The conceptual model discussion provides the background for the modeling approach wherein we focus on simulating transport in the vadose zone, the last potential barrier to CO{sub 2} seepage (Section 4). Because of the potentially wide range of possible properties of actual future geologic sequestration sites, we carry out sensitivity analyses by means of numerical simulation and derive the trends in seepage flux and near-surface CO{sub 2} concentrations that will arise from variations in fundamental hydrogeological properties.

Oldenburg, C.M.; Unger, A.J.A.; Hepple, R.P.; Jordan, P.D.

2002-07-18T23:59:59.000Z

232

Carbon microtubes  

DOE Patents (OSTI)

A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

2011-06-14T23:59:59.000Z

233

Workshop on Carbon Sequestration Science - Ocean Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Ocean Carbon Ocean Carbon Sequestration Howard Herzog MIT Energy Laboratory May 24, 2001 Ocean Carbon Sequestration Options * The direct injection of a relatively pure CO 2 stream that has been generated, for example, at a power plant or from an industrial process * The enhancement of the net oceanic uptake from the atmosphere, for example, through iron fertilization The DOE Center for Research on Ocean Carbon Sequestration (DOCS) * Established July 1999 * Centered at LBNL and LLNL * Participants S Eric Adams MIT S Jim Barry MBARI S Jim Bishop DOCS Scientific Co-director LBNL S Ken Caldeira DOCS Scientific Co-director LLNL S Sallie Chisholm MIT S Kenneth Coale Moss Landing Marine Laboratory S Russ Davis Scripps Institution of Oceanography S Paul Falkowski Rutgers S Howard Herzog MIT S Gerard Nihous Pacific International Center for High Technology Research

234

Process for removing carbon from uranium  

DOE Patents (OSTI)

Carbon contamination is removed from uranium and uranium alloys by heating in inert atmosphere to 700.degree.-1900.degree.C in effective contact with yttrium to cause carbon in the uranium to react with the yttrium. The yttrium is either in direct contact with the contaminated uranium or in indirect contact by means of an intermediate transport medium.

Powell, George L. (Oak Ridge, TN); Holcombe, Jr., Cressie E. (Knoxville, TN)

1976-01-01T23:59:59.000Z

235

Fluidization Technologies for the Mineral, Materials, and Energy ...  

Science Conference Proceedings (OSTI)

About this Symposium. Meeting, 2014 TMS Annual Meeting & Exhibition. Symposium, Fluidization Technologies for the Mineral, Materials, and Energy Industries.

236

Calculation of fluid-mineral equilibria using the simplex algorithm  

Science Conference Proceedings (OSTI)

Keywords: CHILLER, K-feldspar, PATH, SIMCALC, SIMPLEX, equilibria, fluid-mineral, geochemistry, hydrolysis, mass transfer, paragenesis

J. R. Wood

1993-01-01T23:59:59.000Z

237

Mineral Oil Transport and Fate Investigation at Franklin Station  

Science Conference Proceedings (OSTI)

This report presents results of an investigation to evaluate the fate and transport of mineral oil in the subsurface of a substation. Understanding subsurface migration of mineral oil will help utilities who are involved in cleanup of past mineral oil spills and leaks.

1998-12-31T23:59:59.000Z

238

West Virginia University College of Engineering and Mineral Resources  

E-Print Network (OSTI)

of designing and managing a modern coal or mineral mining operation, or continuing into research, banking, law or consulting. Fields of Study Surface Mining - Extracting minerals and coal from the earth's surface safely of extracting minerals from the earth. Materials Handling - Efficiently and safely moving people, equipment

Mohaghegh, Shahab

239

Carbon | Open Energy Information  

Open Energy Info (EERE)

Carbon Sector Retrieved from "http:en.openei.orgwindex.php?titleCarbon&oldid271960" Categories: Articles with outstanding TODO tasks...

240

Carbon Sequestration Monitoring Activities  

SciTech Connect

In its 'Carbon Sequestration Technology Roadmap and Program Plan 2007' the U.S. Department of Energy (DOE)'s Office of Fossil Energy National Energy Technology Laboratory (NETL) identified as a major objective extended field tests to fully characterize potential carbon dioxide (CO{sub 2}) storage sites and to demonstrate the long-term storage of sequestered carbon (p. 5). Among the challenges in this area are 'improved understanding of CO{sub 2} flow and trapping within the reservoir and the development and deployment of technologies such as simulation models and monitoring systems' (p. 20). The University of Wyoming (UW), following consultations with the NETL, the Wyoming State Geological Survey, and the Governor's office, identified potential for geologic sequestration of impure carbon dioxide (CO{sub 2}) in deep reservoirs of the Moxa Arch. The Moxa Arch is a 120-mile long north-south trending anticline plunging beneath the Wyoming Thrust Belt on the north and bounded on the south by the Uinta Mountains. Several oil and gas fields along the Moxa Arch contain accumulations of natural CO{sub 2}. The largest of these is the La Barge Platform, which encompasses approximately 800 square miles. Several formations may be suitable for storage of impure CO{sub 2} gas, foremost among them the Madison Limestone, Bighorn Dolomite, and Nugget Sandstone. This project responded to the challenges described above by preparing a geological site characterization study on the Moxa Arch. The project included four priority research areas: (A) geological characterization of geologic structure of the Arch, the fault, and fracture patterns of the target formations and caprocks, (B) experimental characterization of carbon dioxide-brine-rock reactions that may occur, (C) optimization of geophysical and numerical models necessary for measurement, monitoring and verification (MMV), and (D) a preliminary performance assessment. Research work to accomplish these goals was coordinated by one administrative task under the direction of Dr. Carol Frost, Professor of Geology and Geophysics (Task 1.0), and one task devoted to designing and creating an interdisciplinary, project-specific carbon cyberinfrastructure to support collaborative carbon dioxide sequestration research among University of Wyoming scientists and their collaborators, performed by Jeff Hammerlinck, Director of the Wyoming Geographic Information Science Center at the University of Wyoming (Task 1.5). The results of these tasks are presented in the Introduction and in Chapter 1, respectively.

Carol Frost

2010-11-30T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Development of an advanced gas-fired mineral wool melter. Final report, October 1987-December 1990  

SciTech Connect

A gas-fired mineral wool melter was successfully designed and tested. The test results clearly show that the gas-fired melter offers significant advantages over the current state-of-the-art system, the coke-fired cupola. The primary benefits offered are: lower energy costs, fewer airborne pollutant emissions, virtual elimination of solid waste generation and superior control and quality of the resultant melt stream. Specifically, the unit eliminates the emission of carbon monoxide, hydrogen sulfide and hydrocarbons. Emissions of SOx and particulate are substantially reduced as well. The generation of solid wastes is eliminated through the gas-fired melters ability to utilize untreated process wastes as a feedstock.

Vereecke, F.J.; Gardner, K.M.; Thekdi, A.C.; Swift, M.D.

1990-12-01T23:59:59.000Z

242

Reaction mechanisms for enhancing mineral sequestration of CO{sub 2}  

Science Conference Proceedings (OSTI)

Storage of CO{sub 2} through mineral sequestration using olivine has been shown to produce environmentally benign carbonates. However, due to the formation of a rate-limiting reaction product layer, the rate of reaction is insufficient for large-scale applications. We report the results of altering the reactant solution composition and the resultant reaction mechanism to enhance the reaction rate. The products were analyzed for total carbon content with thermal decomposition analysis, product phase compositions with Debye-Scherrer X-ray powder diffraction (XRD), surface morphology with scanning electron microscopy (SEM), and composition with energy dispersive X-ray spectroscopy (EDXS). Carbon analysis showed that an increase in bicarbonate ion activity increased the olivine to carbonate conversion rate. The fastest conversion rate, 63% conversion in one hour, occurred in a solution of 5.5 M KHCO{sub 3}. Additionally, SEM confirmed that when the bicarbonate ion activity was increased, magnesium carbonate product particles significantly increased in both number density and size and the rate passivating-reaction layer exfoliation was augmented. 30 refs., 5 figs., 1 tab.

Karalee Jarvis; R.W. Carpenter; Todd Windman; Youngchul Kim; Ryan Nunez; Firas Alawneh [Arizona State University, Tempe, AR (United States). School of Materials

2009-08-15T23:59:59.000Z

243

EU Metric Directive  

Science Conference Proceedings (OSTI)

... View EU Metric Directive Commission Services Working Document PDF ... of European Union (EU) Meeting on Metric Directives (2005); Packaging ...

2012-12-13T23:59:59.000Z

244

Mineral ecophysiological evidence for microbial activity in banded iron formation  

Science Conference Proceedings (OSTI)

The phosphorus composition of banded-iron formations (BIFs) has been used as a proxy for Precambrian seawater composition and the paleoeredox state of Earth's surface environment. However, it is unclear whether the phosphorus in BIFs originally entered the sediment as a sorbed component of the iron oxyhydroxide particles, or whether it was incorporated into the biomass of marine phytoplankton. We conducted high-resolution mineral analyses and report here the first detection of an Fe(III) acetate salt, as well as nanocrystals of apatite in association with magnetite, in the 2.48 Ga Dales Gorge Member of the Brockman Iron Formation (a BIF), Hamersley, Western Australia. The clusters of apatite are similar in size and morphology to biogenic apatite crystals resulting from biomass decay in Phanerozoic marine sediments, while the formation of an Fe(III) acetate salt and magnetite not only implies the original presence of biomass in the BIF sediments, but also that organic carbon likely served as an electron donor during bacterial Fe(III) reduction. This study is important because it suggests that phytoplankton may have played a key role in the transfer of phosphorus (and other trace elements) from the photic zone to the seafloor.

Li, Dr. Yi-Liang [University of Tennessee, Knoxville (UTK); Konhauser, Dr, Kurt [University of Alberta; Cole, David R [ORNL; Phelps, Tommy Joe [ORNL

2011-01-01T23:59:59.000Z

245

Carbon Additionality: Discussion Paper  

E-Print Network (OSTI)

Carbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 CarbonFix Standard (CFS) 28 Climate, Community and Biodiversity Standard (CCBS) 28 Forest Carbon Standard (FCS) 28

246

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-4966 jose.figueroa@netl.doe.gov Kevin o'Brien Principal Investigator SRI International Materials Research Laboratory 333 Ravenswood Avenue Menlo Park, AK 94025 650-859-3528 kevin.obrien@sri.com Fabrication and Scale-Up oF polybenzimidazole - baSed membrane SyStem For pre - combUStion captUre oF carbon dioxide Background In order to effectively sequester carbon dioxide (CO 2 ) from a gasification plant, there must be an economically viable method for removing the CO 2 from other gases. While CO 2 separation technologies currently exist, their effectiveness is limited. Amine-based separation technologies work only at low temperatures, while pressure-swing absorption and cryogenic distillation consume significantly

247

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

andrea Mcnemar andrea Mcnemar National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 304-285-2024 andrea.mcnemar@netl.doe.gov Gregory J. Elbring Principal Investigator Sandia National Laboratory P.O. Box 5800 Albuquerque, NM 87185 505-844-4904 gjelbri@sandia.gov GeoloGic SequeStration of carbon DioxiDe in a DepleteD oil reServoir: a comprehenSive moDelinG anD Site monitorinG project Background The use of carbon dioxide (CO 2 ) to enhance oil recovery (EOR) is a familiar and frequently used technique in the United States. The oil and gas industry has significant experience with well drilling and injecting CO 2 into oil-bearing formations to enhance production. While using similar techniques as in oil production, this sequestration field

248

Indian Mineral Development Act of 1982 | Open Energy Information  

Open Energy Info (EERE)

Mineral Development Act of 1982 Mineral Development Act of 1982 Jump to: navigation, search Statute Name Indian Mineral Development Act Year 1982 Url IndianDevelopment1982.jpg Description Provides for tribes to enter into energy development agreements with DOI approval References Indian Mineral Development Act of 1982[1] Bureau of Indian Affairs[2] The Indian Mineral Development Act of 1982 (IMDA) 25 U.S.C. Secs. 2101-2108 was enacted to provide Indian tribes with flexibilty in the development and sale of mineral resources. S.Rep. No. 97-472, 97th Cong.2d Sess. 2 (1982). Foremost among the beneficial effects of IMDA was the opportunity for Indian tribes to enter into joint venture agreements with mineral developers. The contractual relationships permitted by IMDA were designed to meet two objectives: First, to further the policy of self-determination

249

Relations Of Ammonium Minerals At Several Hydrothermal Systems In The  

Open Energy Info (EERE)

Relations Of Ammonium Minerals At Several Hydrothermal Systems In The Relations Of Ammonium Minerals At Several Hydrothermal Systems In The Western Us Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Relations Of Ammonium Minerals At Several Hydrothermal Systems In The Western Us Details Activities (5) Areas (1) Regions (0) Abstract: Ammonium bound to silicate and sulfate minerals has recently been located at several major hydrothermal systems in the western U.S. utilizing newly-discovered near-infrared spectral properties. Knowledge of the origin and mineralogic relations of ammonium minerals at known hydrothermal systems is critical for the proper interpretation of remote sensing data and for testing of possible links to mineralization. Submicroscopic analysis of ammonium minerals from two mercury- and gold-bearing

250

New Species of Cyanobacteria Forms Intracellular Carbonates  

NLE Websites -- All DOE Office Websites (Extended Search)

New Species of Cyanobacteria Forms Intracellular Carbonates Print New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated CaCO3 biomineralization, the mechanistic details of this process are still poorly understood. Scientists agree that calcification in cyanobacteria is an extracellular process: Photosynthesizing cells commonly export the photosynthesis byproduct CO32- outside their cells where it bonds with an alkaline earth metal like Ca2+. The cyanobacteria recently found in Lake Alchichica, however, forms amorphous Ca-, Mg-, Sr- and Ba-rich carbonates intracellularly. This discovery significantly modifies the traditional view of how bacteria induce CaCO3 precipitation and may improve understanding of the fossil record by hinting at ancient traces of life in rocks, or designing new routes for sequestering CO2 or 90Sr in minerals.

251

New Species of Cyanobacteria Forms Intracellular Carbonates  

NLE Websites -- All DOE Office Websites (Extended Search)

New Species of Cyanobacteria New Species of Cyanobacteria Forms Intracellular Carbonates New Species of Cyanobacteria Forms Intracellular Carbonates Print Wednesday, 30 January 2013 00:00 A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated CaCO3 biomineralization, the mechanistic details of this process are still poorly understood. Scientists agree that calcification in cyanobacteria is an extracellular process: Photosynthesizing cells commonly export the photosynthesis byproduct CO32- outside their cells where it bonds with an alkaline earth metal like Ca2+. The cyanobacteria recently found in Lake Alchichica, however, forms amorphous Ca-, Mg-, Sr- and Ba-rich carbonates intracellularly. This discovery significantly modifies the traditional view of how bacteria induce CaCO3 precipitation and may improve understanding of the fossil record by hinting at ancient traces of life in rocks, or designing new routes for sequestering CO2 or 90Sr in minerals.

252

New Species of Cyanobacteria Forms Intracellular Carbonates  

NLE Websites -- All DOE Office Websites (Extended Search)

New Species of Cyanobacteria Forms Intracellular Carbonates Print New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated CaCO3 biomineralization, the mechanistic details of this process are still poorly understood. Scientists agree that calcification in cyanobacteria is an extracellular process: Photosynthesizing cells commonly export the photosynthesis byproduct CO32- outside their cells where it bonds with an alkaline earth metal like Ca2+. The cyanobacteria recently found in Lake Alchichica, however, forms amorphous Ca-, Mg-, Sr- and Ba-rich carbonates intracellularly. This discovery significantly modifies the traditional view of how bacteria induce CaCO3 precipitation and may improve understanding of the fossil record by hinting at ancient traces of life in rocks, or designing new routes for sequestering CO2 or 90Sr in minerals.

253

New Species of Cyanobacteria Forms Intracellular Carbonates  

NLE Websites -- All DOE Office Websites (Extended Search)

New Species of Cyanobacteria Forms Intracellular Carbonates Print New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated CaCO3 biomineralization, the mechanistic details of this process are still poorly understood. Scientists agree that calcification in cyanobacteria is an extracellular process: Photosynthesizing cells commonly export the photosynthesis byproduct CO32- outside their cells where it bonds with an alkaline earth metal like Ca2+. The cyanobacteria recently found in Lake Alchichica, however, forms amorphous Ca-, Mg-, Sr- and Ba-rich carbonates intracellularly. This discovery significantly modifies the traditional view of how bacteria induce CaCO3 precipitation and may improve understanding of the fossil record by hinting at ancient traces of life in rocks, or designing new routes for sequestering CO2 or 90Sr in minerals.

254

Nanostructuring of Microporous Carbons with Carbon Nanotubes for ...  

Science Conference Proceedings (OSTI)

Presentation Title, Nanostructuring of Microporous Carbons with Carbon Nanotubes for Efficient Carbon Dioxide Capture. Author(s), Stephen C. Hawkins, ...

255

Roadmap to the Project: Uranium Miners Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Roadmap DOE Roadmap Experiments List Oral Histories Records Series Descriptions Overview Documents Declassified Documents Project Events ACHRE Report Uranium Miners Resources Building Public Trust Department of Defense Report FINAL REPORT OF THE RADIATION EXPOSURE COMPENSATION ACT COMMITTEE SUBMITTED TO THE HUMAN RADIATION INTERAGENCY WORKING GROUP JULY, 1996 CONTENTS Executive Summary Proposed Amendments to the Statute Recommended Modifications to the Department of Justice Regulations Introduction Issues Relating to Compensation for Lung Cancer Statutory and Regulatory Framework for Compensation Fairness of the Present Statutory Compensation Criteria Alternative Compensation Criteria Description of the Relative Risk Model Used to Derive Proposed Alternative Criteria, and Model Parameters

256

Carbon Steels  

Science Conference Proceedings (OSTI)

Table 1   Corrosion rates of carbon steel at various locations...Vancouver Island, BC, Canada Rural marine 13 0.5 Detroit, MI Industrial 14.5 0.57 Fort Amidor Pier, CZ Marine 14.5 0.57 Morenci, MI Urban 19.5 0.77 Potter County, PA Rural 20 0.8 Waterbury, CT Industrial 22.8 0.89 State College, PA Rural 23 0.9 Montreal, QC, Canada Urban 23 0.9 Durham, NH Rural 28 1.1...

257

Mineral revenues: the 1983 report on receipts from Federal and Indian leases with summary data from 1920 to 1983  

DOE Green Energy (OSTI)

Tables and figures abound for: mineral revenue management in 1983; offshore federal mineral revenues; onshore federal mineral revenues; Indian mineral revenues; distribution of federal and Indian mineral revenues; plus appended lease management data. (PSB)

Not Available

1984-01-01T23:59:59.000Z

258

Aerosol organic carbon to black carbon ratios: Analysis of published...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aerosol organic carbon to black carbon ratios: Analysis of published data and implications for climate forcing Title Aerosol organic carbon to black carbon ratios: Analysis of...

259

Mineral Test Hole Regulatory Act (Tennessee) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Mineral Test Hole Regulatory Act (Tennessee) Mineral Test Hole Regulatory Act (Tennessee) Mineral Test Hole Regulatory Act (Tennessee) < Back Eligibility Commercial Construction Developer Fuel Distributor Industrial Installer/Contractor Investor-Owned Utility Municipal/Public Utility Utility Program Info State Tennessee Program Type Environmental Regulations Siting and Permitting Provider Tennessee Department Of Environment and Conservation The Mineral Hole Regulatory Act is applicable to any person (individual, corporation, company, association, joint venture, partnership, receiver, trustee, guardian, executor, administrator, personal representative or private organization of any kind) who wishes to drill a mineral test hole (any hole in excess of one hundred (100) feet drilled during the exploration for minerals but shall exclude auger drilling in surficial or

260

Thermally Speciated Mercury in Mineral Exploration | Open Energy  

Open Energy Info (EERE)

Thermally Speciated Mercury in Mineral Exploration Thermally Speciated Mercury in Mineral Exploration Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Thermally Speciated Mercury in Mineral Exploration Abstract Abstract unavailable. Author S.C. Smith Conference IGES; Dublin, CA; 2003/09/01 Published IGES, 2003 DOI Not Provided Check for DOI availability: http://crossref.org Citation S.C. Smith. 2003. Thermally Speciated Mercury in Mineral Exploration. In: Programs & Abstracts: Soil and Regolith Geochemistry in the Search for Mineral Deposits. IGES; 2003/09/01; Dublin, CA. Dublin, CA: IGES; p. 78 Retrieved from "http://en.openei.org/w/index.php?title=Thermally_Speciated_Mercury_in_Mineral_Exploration&oldid=681717" Categories: References Geothermal References

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Radioactive Mineral Occurences in Nevada | Open Energy Information  

Open Energy Info (EERE)

Radioactive Mineral Occurences in Nevada Radioactive Mineral Occurences in Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Radioactive Mineral Occurences in Nevada Abstract Abstract unavailable. Author Larry J. Garside Organization Nevada Bureau of Mines and Geology Published Nevada Bureau of Mines and Geology, 1973 Report Number Open File Report 94-2 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Radioactive Mineral Occurences in Nevada Citation Larry J. Garside (Nevada Bureau of Mines and Geology). 1973. Radioactive Mineral Occurences in Nevada. Reno, NV: Nevada Bureau of Mines and Geology. Report No.: Open File Report 94-2. Retrieved from "http://en.openei.org/w/index.php?title=Radioactive_Mineral_Occurences_in_Nevada&oldid=690513"

262

Roadmap to the Project: Uranium Miners Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

EXECUTIVE SUMMARY EXECUTIVE SUMMARY On October 15, 1990, Congress passed the Radiation Exposure Compensation Act of 1990 (RECA), which provided for compassionate payments to individuals who suffered from specified diseases presumably as a result of exposure to radiation in connection with the federal government's nuclear weapons testing program. Among those eligible for compensation under the Act are individuals who were employed in underground uranium mines in Arizona, Colorado, New Mexico, Utah or Wyoming during the 1947 to 1971 time period, who were exposed to specified minimum levels of radon, and who contracted specified lung disorders. The Department of Justice administers the RECA through the Radiation Exposure Compensation Program (Program). The provisions of the RECA defining compensation for uranium miners have been characterized by critics as unfair and inconsistent with current scientific information. The regulations of the Department of Justice implementing the statute have also been criticized as being unnecessarily stringent and unreasonably burdensome. These criticisms were noted, and in some cases affirmed, by the President's Advisory Committee on Human Radiation Experiments, charged by the President to investigate the history of human radiation experimentation conducted by the federal government during the Cold War period. In its Final Report, issued on October 3, 1995, the Advisory Committee recommended, among other things, that the Administration review the provisions of RECA governing compensation for uranium miners and the implementing regulations to ensure that they are fair, consistent with current scientific evidence, and compatible with the objectives of the Act.

263

Principles Governing Departmental Directives  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ELEMENTS FROM: SAMUEL W. BODMA 4 SUBJECT: Principles Governing Departmental Directives The Department of Energy uses directives as its primary means to establish,...

264

directed acyclic word graph  

Science Conference Proceedings (OSTI)

... and R. Verin, Direct Construction of Compact Directed Acyclic Word Graphs, 8th Annual Symposium, CPM 97, Aarhus, Denmark, 116-129, 1997. ...

2013-08-23T23:59:59.000Z

265

Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy  

SciTech Connect

The capture and storage of carbon dioxide and other greenhouse gases in deep geologic formations represents one of the most promising options for mitigating the impacts of greenhouse gases on global warming. In this regard, mineral-fluid interactions are of prime importance since such reactions can result in the long term sequestration of CO2 by trapping in mineral phases. Recently it has been recognized that interactions with neat to water-saturated non-aqueous fluids are of prime importance in understanding mineralization reactions since the introduced CO2 is likely to contain water initially or soon after injection and the supercritical CO2 (scCO2) is less dense than the aqueous phase which can result in a buoyant scCO2 plume contacting the isolating caprock. As a result, unraveling the molecular/microscopic mechanisms of mineral transformation in neat to water saturated scCO2 has taken on an added important. In this study, we are examining the interfacial reactions of the olivine mineral forsterite (Mg2SiO4) over a range of water contents up to and including complete water saturation in scCO2. The surface precipitates that form on the reacted forsterite grains are extremely fragile and difficult to experimentally characterize. In order to address this issue we have developed experimental protocols for preparing and imaging electron-transparent samples from fragile structures. These electron-transparent samples are then examined using a combination of STEM/EDX, FIB-TEM, and helium ion microscope (HIM) imaging (Figures 1-3). This combination of capabilities has provided unique insight into the geochemical processes that occur on scCO2 reacted mineral surfaces. The experimental procedures and protocols that have been developed also have useful applications for examining fragile structures on a wide variety of materials. This research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research located at Pacific Northwest National Laboratory.

Arey, Bruce W.; Kovarik, Libor; Wang, Zheming; Felmy, Andrew R.

2011-10-10T23:59:59.000Z

266

Water-bearing minerals on mars: source of observed mid-latitude water?  

DOE Green Energy (OSTI)

The Odyssey spacecraft documented the existence of heterogeneously distributed hydrogen at martian mid-latitudes, suggesting that large areas of the near-equatorial highlands contain near-surface deposits of 'chemically and/or physically bound H20 and/or OH' in amounts up to 3 .8% equivalent H20. Shallow occurrences of water ice are not stable near the martian equator, making the hydrogen deposits at these latitudes somewhat enigmatic. Clay minerals and zeolites have both been proposed as possible water-bearing constituents on Mars, and both are common terrestrial alteration products of hydrovolcanic basaltic ashes and palagonitic material comparable to those that may be widespread on Mars. Smectites within martian meteorites, attributed to hydrous alteration on Mars rather than on Earth, provide direct evidence of clay minerals from Mars. In addition, new thermal emission spectrometer (TES) data provide good evidence for unspecified zeolites in martian surface dust [6] . The nature of the hydrogen-containing material observed in the equatorial martian regolith is of particular importance to the question of whether hydrous minerals have formed in the past on Mars. Also, whether these minerals exist in a hydrated (i .e., containing H2O molecules in their structures) or dehydrated state is a crucial question . The existence of hydrous minerals is also important in connection with their possible role in affecting the diurnal variation of the martian atmosphere, in their potential role in unraveling the paleohydrology and paleobiology of Mars, and in their possible use as a water resource to support exploration of the martian mid-latitudes.

Bish, D. L. (David L.); Carey, J. W. (James W.); Fialips, C. I. (Clair I.)

2003-01-01T23:59:59.000Z

267

Biogas yield and quality improvement and purification with natural minerals.  

E-Print Network (OSTI)

??Research goal and objective. To investigate the possibilities of the use of mineral raw materials of local origin for the purification of biogas produced from (more)

?iutelyt?, R?ta

2013-01-01T23:59:59.000Z

268

DOE - Office of Legacy Management -- Heavy Minerals Inc - IL...  

Office of Legacy Management (LM)

Subject: FUSRAP Considered Site Recommendation; July 9, 1990. IL.14-2 - Heavy Minerals Co. Letter; Wyatt to Faulkner; Subject: Crude Thorium Hydroxide Proposal; December 1, 1954...

269

Investigation on Mineral, Microstructure and Activity of Coal Gangue ...  

Science Conference Proceedings (OSTI)

In this study, seven coal gangue samples covering a wide range of chemical composition were collected from Shanxi Province, China. The mineral composition...

270

Climate VISION: Private Sector Initiatives: Minerals: GHG Information  

Office of Scientific and Technical Information (OSTI)

Read the Industrial Minerals Association - North America (IMA-NA) 2011 Greenhouse Gas and Energy Survey Industry Summary for the period from 2000 to 2010 (PDF 16 KB)...

271

Hyperspectral mineral mapping in support of geothermal exploration...  

Open Energy Info (EERE)

2004 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Hyperspectral mineral mapping in support of geothermal exploration- Examples...

272

Epithermal Gold Mineralization and a Geothermal Resource at Blue...  

Open Energy Info (EERE)

1991 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain,...

273

Mineralization of Synthetic Polymer Scaffolds: A Bottom-Up ...  

Mineralization of Synthetic Polymer Scaffolds: A Bottom-Up Approach for the Development of Artificial Bone Jie Song,*,, Viengkham Malathong, and Carolyn R ...

274

Improving the Health & Performance of Miners Working at Moderate ...  

Science Conference Proceedings (OSTI)

Cross Pollination between Industry and Engineering Programs/Students in Manitoba Improving the Health & Performance of Miners Working at Moderate to

275

Optimization on Compression Strength of Resin Mineral Composite  

Science Conference Proceedings (OSTI)

Abstract Scope, Using natural granite particles as aggregate and organic resin as binder, resin mineral composite (RMC) has good vibration damping properties...

276

Climate VISION: PrivateSector Initiatives: Minerals - Industry...  

Office of Scientific and Technical Information (OSTI)

together to achieve common goals. Industrial minerals - ball clay, bentonite, borates, feldspar, industrial sand, mica, soda ash and talc - are a miraculous gift from times past....

277

Reclamation of Land Used for Mineral Mining (Virginia)  

Energy.gov (U.S. Department of Energy (DOE))

This legislation aims to provide for the rehabilitation and conservation of land affected by the mining of minerals through proper planning, proper use of appropriate methods of mining,...

278

Application of Biomass Waste Materials in the Nano Mineral Synthesis  

Science Conference Proceedings (OSTI)

Some of the biomass waste material were effectively applied to the nano-sized minerals synthesis under conrolled boundry experimenta conditions.

279

Energy Efficiency in Mineral Processing Industry Using High ...  

Science Conference Proceedings (OSTI)

Presentation Title, Energy Efficiency in Mineral Processing Industry Using High ... These studies were prepared by Tetra Tech on eight different projects at...

280

A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...  

Open Energy Info (EERE)

A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal...

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Climate VISION: Private Sector Initiatives: Minerals: GHG Inventory...  

Office of Scientific and Technical Information (OSTI)

GHG Inventory Protocols Read the Industrial Minerals Association - North America (IMA-NA) Borates and Soda Ash Sections Greenhouse Gas Inventory Protocol (PDF 75 KB) Download...

282

Climate VISION: PrivateSector Initiatives: Minerals - Resources...  

Office of Scientific and Technical Information (OSTI)

of IntentAgreements Work Plans GHG Information GHG Inventory Protocols Resources & Links Energy Management Industry Associations Software Tools Results Minerals - Resources &...

283

The porincytochrome model for microbe-to-mineral electron transfer  

Science Conference Proceedings (OSTI)

Many species of bacteria can couple anaerobic growth to the respiratory reduction of insoluble minerals containing Fe(III) or Mn(III/IV). It has been suggested that in Shewanella species electrons cross the outer membrane to extracellular substrates via 'porin-cytochrome' electron transport modules. The molecular structure of an outer-membrane extracellular-facing deca-haem terminus for such a module has recently been resolved. It is debated how, once outside the cells, electrons are transferred from outer-membrane cytochromes to insoluble electron sinks. This may occur directly or by assemblies of cytochromes, perhaps functioning as 'nanowires', or via electron shuttles. Here we review recent work in this field and explore whether it allows for unification of the electron transport mechanisms supporting extracellular mineral respiration in Shewanella that may extend into other genera of Gram-negative bacteria.

Richardson, David J.; Butt, Julea N.; Fredrickson, Jim K.; Zachara, John M.; Shi, Liang; Edwards, Marcus J.; White, Gaye F.; Baiden, Nanakow; Gates, Andrew J.; Marritt, Sophie; Clarke, Thomas A.

2012-05-30T23:59:59.000Z

284

Carbon Sequestration Project Portfolio  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Carbon Storage 2011 Carbon Storage Project Portfolio Table of Contents CARBON STORAGE OVERVIEW Carbon Storage Program Contacts [PDF-26KB] Carbon Storage Projects National Map [PDF-169KB] State Projects Summary Table [PDF-39KB] Carbon Storage Program Structure [PDF-181KB] Selected Carbon Sequestration Program Papers and Publications The U.S. Department of Energy's R&D Program to Reduce Greenhouse Gas Emissions Through Beneficial Uses of Carbon Dioxide (2011) [PDF-3.3MB] Greenhouse Gas Science and Technology Carbon Capture and Sequestration: The U.S. Department of Energy's R&D Efforts to Characterize Opportunities for Deep Geologic Storage of Carbon Dioxide in Offshore Resources (2011) [PDF-445KB]

285

Photophysics of carbon nanotubes  

E-Print Network (OSTI)

This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

Samsonidze, Georgii G

2007-01-01T23:59:59.000Z

286

Carbon Dioxide (CO2)  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide (CO2) Carbon Dioxide (CO2) Gateway Pages to Carbon Dioxide Data Modern records and ice core records back 2000 years 800,000 year records from ice cores Other...

287

Direct process for explosives  

SciTech Connect

A direct process of making ethylenediamine dinitrate through the reaction of ethylenediamine and ammonium nitrate.

Akst, Irving B. (1032 Duncan St., Pampa, TX 79065); Stinecipher, Mary M. (324 Connie St., Los Alamos, NM 87544)

1982-01-01T23:59:59.000Z

288

Direct-Current Resistivity Survey | Open Energy Information  

Open Energy Info (EERE)

Direct-Current Resistivity Survey Direct-Current Resistivity Survey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Direct-Current Resistivity Survey Details Activities (65) Areas (34) Regions (4) NEPA(0) Exploration Technique Information Exploration Group: Geophysical Techniques Exploration Sub Group: Electrical Techniques Parent Exploration Technique: Electrical Techniques Information Provided by Technique Lithology: Rock type, mineral and clay content may be inferred. Stratigraphic/Structural: Determination of fracture zones, faults, depth to groundwater aquifers. Hydrological: Resistivity influenced by porosity, permeability, fluid saturation, fluid type and phase state of the pore water. Thermal: Resistivity influenced by temperature.[1] Cost Information

289

Method of making carbon-carbon composites  

DOE Patents (OSTI)

A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

1993-01-01T23:59:59.000Z

290

In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide  

SciTech Connect

In geologic carbon sequestration, while part of the injected carbon dioxide will dissolve into host brine, some will remain as neat to water saturated super critical CO2 (scCO2) near the well bore and at the caprock, especially in the short-term life cycle of the sequestration site. Little is known about the reactivity of minerals with scCO2 containing variable concentrations of water. In this study, we used high-pressure infrared spectroscopy to examine the carbonation of brucite (Mg(OH)2) in situ over a 24 hr reaction period with scCO2 containing water concentrations between 0% and 100% saturation, at temperatures of 35, 50, and 70 C, and at a pressure of 100 bar. Little or no detectable carbonation was observed when brucite was reacted with neat scCO2. Higher water concentrations and higher temperatures led to greater brucite carbonation rates and larger extents of conversion to magnesium carbonate products. The only observed carbonation product at 35 C was nesquehonite (MgCO3 3H2O). Mixtures of nesquehonite and magnesite (MgCO3) were detected at 50 C, but magnesite was more prevalent with increasing water concentration. Both an amorphous hydrated magnesium carbonate solid and magnesite were detected at 70 C, but magnesite predominated with increasing water concentration. The identity of the magnesium carbonate products appears strongly linked to magnesium water exchange kinetics through temperature and water availability effects.

Loring, John S.; Thompson, Christopher J.; Zhang, Changyong; Wang, Zheming; Schaef, Herbert T.; Rosso, Kevin M.

2012-04-25T23:59:59.000Z

291

Carbon Nanotube Nanocomposites, Methods of Making Carbon ...  

This technology describes methods to fabricate supercapacitors using aligned carbon nanotubes that are decorated with metal oxide or nitride ...

292

DOE Carbon Sequestration Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sequestration Program Charles E. Schmidt Carbon Sequestration Product Manager National Energy Technology Laboratory David J. Beecy Director, Office of Environmental Systems...

293

Foreign Direct Investment  

Gasoline and Diesel Fuel Update (EIA)

Investment Investment Foreign Direct Investment Foreign Direct Investment Foreign Direct Investment in U.S. Energy in U.S. Energy in U.S. Energy in U.S. Energy in 1999 in 1999 in 1999 in 1999 June 2001 ii iii Contents Foreign Affiliates' Role in U.S. Energy Industry Operations ..............................................................................1 Foreign Direct Investment: The International Transactions Accounts ..............................................................8 U.S. Companies' Direct Investment Abroad in Energy ......................................................................................14 Conclusion...............................................................................................................................................................19

294

Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production  

E-Print Network (OSTI)

#12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

Narasayya, Vivek

295

Carbon Code Requirements for voluntary carbon sequestration projects  

E-Print Network (OSTI)

Woodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July of group schemes 8 2.6 Monitoring 9 2.7 Carbon statements and reporting 9 2.8 Woodland Carbon Code trademark 10 3. Carbon sequestration 11 3.1 Units of carbon calculation 11 3.2 Carbon baseline 11 3.3 Carbon

296

Carbon Code Requirements for voluntary carbon sequestration projects  

E-Print Network (OSTI)

Woodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.1 July.6 Monitoring 8 2.7 Carbon statements and reporting 8 2.8 Woodland Carbon Code trademark 9 3. Carbon sequestration 10 3.1 Units of carbon calculation 10 3.2 Carbon baseline 10 3.3 Carbon leakage 11 3.4 Project

297

Liquid Tin Anode Direct Coal Fuel Cell - CellTech Power  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Tin Anode Direct Coal Liquid Tin Anode Direct Coal Fuel Cell-CellTech Power Background Direct carbon solid oxide fuel cells (SOFCs) offer a theoretical efficiency advantage over traditional SOFCs operating on gasified carbon (syngas). CellTech Power LLC (CellTech) has been developing a liquid tin anode (LTA) SOFC that can directly convert carbonaceous fuels including coal into electricity without gasification. One of the most significant impediments

298

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation  

SciTech Connect

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

2011-07-15T23:59:59.000Z

299

Geophysical Monitoring and Reactive Transport Modeling of Ureolytically-Driven Calcium Carbonate Precipitation  

Science Conference Proceedings (OSTI)

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH4+ production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Yuxin Wu; Jonathan B. Ajo-Franklin; Nicolas Spycher; Susan S. Hubbard; Guoxiang Zhang; Kenneth H. Williams; Joanna Taylor; Yoshiko Fujita; Robert Smith

2011-09-01T23:59:59.000Z

300

Composite carbon foam electrode  

DOE Patents (OSTI)

Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Composite carbon foam electrode  

DOE Patents (OSTI)

Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

1997-05-06T23:59:59.000Z

302

Building materials using binders and solid combustible minerals  

Science Conference Proceedings (OSTI)

Local materials including low-quality solid combustible minerals and their wastes, are being used to cheapen building costs. The author reviews the use of solid combustible minerals and their carbonaceous wastes as nonbaking binders of the lime-pozzolana type in the production of building and other materials.

Gorlov, E.G.

1982-01-01T23:59:59.000Z

303

Mineral formation during simulated leaks of Hanford waste tanks  

E-Print Network (OSTI)

Mineral formation during simulated leaks of Hanford waste tanks Youjun Deng a , James B. Harsh a at the US DOE Hanford Site, Washington, caus- ing mineral dissolution and re-precipitation upon contact mimicking tank leak conditions at the US DOE Hanford Site. In batch experiments, Si-rich solutions

Flury, Markus

304

Use of hybrid intelligent computing in mineral resources evaluation  

Science Conference Proceedings (OSTI)

Mineral resources are a formal quantification of naturally occurring materials. Estimation of resource parameters such as grade and thickness may be carried out using different methodologies. In this paper, a soft methodology, which is artificial neural ... Keywords: Fuzzy-neural network, Grade estimation, Hybrid modelling, Mineral resource

B. Tutmez

2009-06-01T23:59:59.000Z

305

Direct current sputtering of boron from boron/carbon mixtures  

DOE Patents (OSTI)

A method for coating a substrate with boron by sputtering includes lowering the electrical resistance of a boron-containing rod to allow electrical conduction in the rod; placing the boron-containing rod inside a vacuum chamber containing substrate material to be coated; applying an electrical potential between the boron target material and the vacuum chamber; countering a current avalanche that commences when the conduction heating rate exceeds the cooling rate, and until a steady equilibrium heating current is reached and coating the substrate material with boron by sputtering from the boron-containing rod.

Timberlake, J.R.; Manos, D.; Nartowitz, E.

1993-12-31T23:59:59.000Z

306

Experimental Characterization of a Direct Carbon Solid Oxide Fuel ...  

Science Conference Proceedings (OSTI)

To more rationally guide the design of liquid tin anode SOFCs, research at NETL has focused on measuring the kinetic parameters of the liquid tin anode under...

307

Isotope Geochemistry Of Minerals And Fluids From Newberry Volcano, Oregon |  

Open Energy Info (EERE)

Isotope Geochemistry Of Minerals And Fluids From Newberry Volcano, Oregon Isotope Geochemistry Of Minerals And Fluids From Newberry Volcano, Oregon Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Isotope Geochemistry Of Minerals And Fluids From Newberry Volcano, Oregon Details Activities (2) Areas (1) Regions (0) Abstract: Isotopic compositions were determined for hydrothermal quartz, calcite, and siderite from core samples of the Newberry 2 drill hole, Oregon. The Δ15O values for these minerals decrease with increasing temperatures. The values indicate that these hydrothermal minerals precipitated in isotopic equilibrium with water currently present in the reservoirs. The Δ18O values of quartz and calcite from the andesite and basalt flows (700-932 m) have isotopic values which require that the equilibrated water Δ18O values increase slightly (- 11.3 to -9.2‰) with

308

Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain,  

Open Energy Info (EERE)

Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Abstract Shallow exploration drilling on the west flank of Blue Mountain discovered sub economic gold mineralization and a spatially associated active geothermal system. The gold mineralization is an unusual example of an acid sulfate type epithermal system developed in pre Tertiary sedimentary host rocks. The geothermal system is largely unexplored but is unusual in that surface manifestation s typically associated with active geothermal system are not present. Authors Andrew J. Parr and Timothy J. Percival

309

Hydrothermal alteration mineral mapping using hyperspectral imagery in  

Open Energy Info (EERE)

alteration mineral mapping using hyperspectral imagery in alteration mineral mapping using hyperspectral imagery in Dixie Valley, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hydrothermal alteration mineral mapping using hyperspectral imagery in Dixie Valley, Nevada Abstract Hyperspectral (HyMap) data was used to map the location ofoutcrops of high temperature, hydrothermally alterated minerals(including alunite, pyrophyllite, and hematite) along a 15 kmswath of the eastern front of the Stillwater Mountain Range inDixie Valley, Nevada. Analysis of this data set reveals that severaloutcrops of these altered minerals exist in the area, and thatone outcrop, roughly 1 square kilometer in area, shows abundanthigh temperature alteration. Structural analysis of the alteredregion using a

310

Mineral Leasing Act of 1920 | Open Energy Information  

Open Energy Info (EERE)

Leasing Act of 1920 Leasing Act of 1920 Jump to: navigation, search Statute Name Mineral Leasing Act of 1920 Year 1920 Url MineralLeasingAct.jpg Description The Mineral Leasing Act established the authority of the Secretary of the Interior to oversee oil and gas operations on federal land. References Federal Oil and Gas Statutes[1] Mineral Leasing Act of 1920 (30 U.S.C. § 181 et seq.) - The Mineral Leasing Act established the authority of the Secretary of the Interior to oversee oil and gas operations on federal land. "The Secretary of the Interior is authorized to prescribe necessary and proper rules and regulations and to do any and all things necessary to carry out and accomplish the purposes of this Act." 30 U.S.C. § 189 References ↑ "Federal Oil and Gas Statutes"

311

Minerals on Public Lands (Texas) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Minerals on Public Lands (Texas) Minerals on Public Lands (Texas) Minerals on Public Lands (Texas) < Back Eligibility Utility Fed. Government Commercial Investor-Owned Utility Industrial Construction Municipal/Public Utility Local Government Rural Electric Cooperative Tribal Government Program Info State Texas Program Type Siting and Permitting Provider Texas General Land Office Any tract of land that belongs to the state, including islands, salt and freshwater lakes, bays, inlets, marshes, and reefs owned by the state within tidewater limits, the part of the Gulf of Mexico within the state's jurisdiction, unsold surveyed public school land, rivers and channels that belong to the state, and land sold with a reservation of minerals to the state are subject to prospect by any person for those minerals which are

312

Cementation process for minerals recovery from Salton Sea geothermal brines  

DOE Green Energy (OSTI)

The potential for minerals recovery from a 1000-MWe combined geothermal power and minerals recovery plant in the Salton Sea is examined. While the possible value of minerals recovered would substantially exceed the revenue from power production, information is insufficient to carry out a detailed economic analysis. The recovery of precious metals - silver, gold, and platinum - is the most important factor in determining the economics of a minerals recovery plant; however, the precious metals content of the brines is not certain. Such a power plant could recover 14 to 31% of the US demand for manganese and substantial amounts of zinc and lead. Previous work on minerals extraction from Salton Sea brines is also reviewed and a new process, based on a fluidized-bed cementation reaction with metallic iron, is proposed. This process would recover the precious metals, lead, and tin present in the brines.

Maimoni, A.

1982-01-26T23:59:59.000Z

313

Probabilistic neural networks applied to mineral potential mapping for platinum group elements in the Serra Leste region, Carajs Mineral Province, Brazil  

Science Conference Proceedings (OSTI)

This work presents an application of probabilistic neural networks to map the potential for platinum group elements (PGE) mineralization sites in the northeast portion of the Carajas Mineral Province (CMP), Brazilian Amazon. Geological and geophysical ... Keywords: Carajs Mineral Province, Leave-one-out test, Mineral potential mapping, Probabilistic neural network

Emilson Pereira Leite; Carlos Roberto de Souza Filho

2009-03-01T23:59:59.000Z

314

The Woodland Carbon Code  

E-Print Network (OSTI)

The Woodland Carbon Code While society must continue to make every effort to reduce greenhouse gas a role by removing carbon dioxide from the atmosphere. The potential of woodlands to soak up carbon to help compensate for their carbon emissions. But before investing in such projects, people want to know

315

Mechanomutable Carbon Nanotube Arrays  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2010 TMS Annual Meeting & Exhibition. Symposium , Polymer Nanocomposites. Presentation Title, Mechanomutable Carbon...

316

Acetylenic carbon allotrope  

DOE Patents (OSTI)

A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

1998-01-01T23:59:59.000Z

317

Acetylenic carbon allotrope  

DOE Patents (OSTI)

A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

Lagow, R.J.

1998-02-10T23:59:59.000Z

318

Acetylenic carbon allotrope  

DOE Patents (OSTI)

A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

1999-01-01T23:59:59.000Z

319

Direct Photons at RHIC  

E-Print Network (OSTI)

Abstract. The PHENIX experiment has measured direct photons in ? sNN = 200 GeV Au+Au collisions and p+p collisions. The fraction of photons due to direct

Saskia Mioduszewski; Phenix Collaboration

2004-01-01T23:59:59.000Z

320

Direct Loan Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

The Connecticut Development Authoritys Direct Loan Program provides direct senior and subordinated loans and mezzanine investments to companies creating or maintaining jobs. Up to $20,000 per job...

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Direct process for explosives  

DOE Patents (OSTI)

A direct process of making ethylenediamine dinitrate through the reaction of ethylenediamine and ammonium nitrate is described.

Akst, I.B.; Stinecipher, M.M.

1982-10-12T23:59:59.000Z

322

Ferrosilicon smelting in a direct current furnace  

DOE Patents (OSTI)

The present invention is a process for smelting ferrosilicon alloy. The process comprises adding a carbon source and tailings comprising oxides of silicon and iron to a substantially closed furnace. Heat is supplied to the furnace by striking a direct current arc between a cathode electrode and an anode functional hearth. In a preferred embodiment of the present invention, the cathode electrode is hollow and feed to the substantially closed furnace is through the hollow electrode. 1 figure.

Dosaj, V.D.; May, J.B.

1992-12-29T23:59:59.000Z

323

The estimation of the number of underground coal miners and the annual dose to coal miners in China  

Science Conference Proceedings (OSTI)

This paper introduces an estimation method for the number of underground coal miners and the annual dose to coal miners in China. It shows that there are about 6 million underground miners at present and the proportion is about 1, 1 and 4 million for national key coal mines, state-owned local coal mines, and township and private-ownership coal mines, respectively. The collective dose is about 1.65 X 10{sup 4} person-Sv y{sup -1}, of which township and private-ownership coal mines contribute about 91%. This paper also points out that the 2000 UNSCEAR report gives the number of miners of coal production and their collective dose, which are underestimated greatly because the report only includes the number of underground miners in national key coal mines, which only accounts for 1/6 of the workers all working under the best ventilation conditions in China.

Liu, F.D.; Pan, Z.Q.; Liu, S.L.; Chen, L.; Ma, J.Z.; Yang, M.L.; Wang, N.P. [China Institute of Atomic Energy, Beijing (China)

2007-08-15T23:59:59.000Z

324

INCCA: Integrated Climate and Carbon  

SciTech Connect

The INCCA (Integrated Climate and Carbon) initiative will develop and apply the ability to simulate the fate and climate impact of fossil fuel-derived carbon dioxide (CO{sub 2}) and aerosols on a global scale. Coupled climate and carbon cycle modeling like that proposed for INCCA is required to understand and predict the future environmental impacts of fossil fuel burning. At present, atmospheric CO{sub 2} concentrations are prescribed, not simulated, in large climate models. Credible simulations of the entire climate system, however, need to predict time-evolving atmospheric greenhouse forcing using anthropogenic emissions as the fundamental input. Predicting atmospheric COS concentrations represents a substantial scientific advance because there are large natural sources and sinks of carbon that are likely to change as a result of climate change. Both terrestrial (e.g., vegetation on land) and oceanic components of the carbon cycle are known to be sensitive to climate change. Estimates of the amount of man-made CO{sub 2} that will accumulate in the atmosphere depend on understanding the carbon cycle. For this reason, models that use CO{sub 2} emissions, not prescribed atmospheric concentrations, as fundamental inputs are required to directly address greenhouse-related questions of interest to policymakers. INCCA is uniquely positioned to make rapid progress in this high-priority area of global change modeling and prediction because we can leverage previous and ongoing LLNL developments, and use existing component models that are well-developed and published. The need for a vastly improved carbon dioxide prediction capability is appreciated by the DOE. As the US Accelerated Climate Prediction Initiative (ACPI) progresses, we expect the DOE will emphasize the carbon cycle as the next major department-level earth science focus. INCCA will position LLNL for substantial additional funding as this new focus is realized. In the limited time since our LDRD funding was first received (1 November 2000) we have made good progress in acquisition and testing of component models, applications of the terrestrial biosphere model, enhancements to the ocean carbon cycle model and development of the fossil fuel aerosol model.

Thompson, S L

2001-03-13T23:59:59.000Z

325

Can hydrous minerals account for the observed mid-latitude water on Mars?  

DOE Green Energy (OSTI)

Great interest was generated with the discovery by the Odyssey spacecraft OC heterogeneously distributed hydrogcn at martian mid-latitudes, suggesting that large areas of the near-equatorial highlands contain near-surface deposits of 'chemically and/or physically bound 1120 and/or OH' in amounts up to 3.8% equivalent H20. More recent interpretations of the Odyssey data using new calibrations suggest that some near-equatorial areas, such as Arabia Terra, contain up to 8.5f I .3% water-equivalent hydrogen. Such shallow occurrences (minerals and zeolites, have been proposed as possible M20-bearing constituents on Mars, and both groups of minerals are common terrestrial alteration products of hydrovolcanic basaltic ashes and palagonitic material comparable io those that may be widespread on Mars. Smectites within martian meteorites, attributed to hydrous alteration on Mars rather than on Earth, provide direct evidence of clay minerals from Mars. In addition, new thermal emission spectrometer (TES) data provide evidence for unspecified zeolites in martian surface dust, and concluded that spectral deconvolution of MGS TES and Mariner 9 IRIS data is consistent with the presence of zeolite in the martian surface dust.

Bish, D. L. (David L.); Vaniman, D. T. (David T.); Fialips, C. I. (Clair I.); Carey, J. W. (James W.); Feldman, W. C. (William C.)

2003-01-01T23:59:59.000Z

326

Glossary: Energy-Related Carbon Emissions  

U.S. Energy Information Administration (EIA)

Carbon Sequestration: The fixation of atmospheric carbon dioxide in a carbon sink through biological or physical processes. Carbon Sink: ...

327

Regional Carbon Sequestration Partnerships | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation Carbon Capture and Storage Regional Carbon Sequestration Partnerships Regional Carbon Sequestration Partnerships DOE's Regional Carbon Sequestration...

328

DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS  

Science Conference Proceedings (OSTI)

There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have conducted adsorption, phase behavior and wettability studies. Addition of Na{sub 2}CO{sub 3} decreases IFT with a minimum at about 0.2 M. Addition of surfactant decreases IFT further. In the absence of surfactant the minerals are oil wet after aging with crude oil. Addition of surfactant solution decreases the contact angle to intermediate wettability. Addition of Na{sub 2}CO{sub 3} decreases anionic surfactant adsorption on calcite surface. Plans for the next quarter include conducting adsorption, phase behavior and wettability studies.

Kishore K. Mohanty

2003-07-01T23:59:59.000Z

329

DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS  

SciTech Connect

There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. We have conducted adsorption, phase behavior, interfacial tension (IFT) and wettability studies. Addition of Na{sub 2}CO{sub 3} decreases IFT with a minimum at about 0.2 M. Addition of surfactant decreases IFT further. In the absence of surfactant the minerals are oil-wet after aging with crude oil. Addition of surfactant solution decreases the contact angle to intermediate-wet for many surfactants and water-wet for one surfactant. Addition of Na{sub 2}CO{sub 3} decreases anionic surfactant adsorption on calcite surface. Plans for the next quarter include conducting core adsorption, phase behavior, wettability and mobilization studies.

Kishore K. Mohanty

2003-07-01T23:59:59.000Z

330

On carbon footprints and growing energy use  

SciTech Connect

Could fractional reductions in the carbon footprint of a growing organization lead to a corresponding real reduction in atmospheric CO{sub 2} emissions in the next ten years? Curtis M. Oldenburg, head of the Geologic Carbon Sequestration Program of LBNLs Earth Sciences Division, considers his own organization's carbon footprint and answers this critical question? In addressing the problem of energy-related greenhouse gas (GHG) emissions and climate change, it is essential that we understand which activities are producing GHGs and the scale of emission for each activity, so that reduction efforts can be efficiently targeted. The GHG emissions to the atmosphere of an individual or group are referred to as the carbon footprint. This terminology is entirely appropriate, because 85% of the global marketed energy supply comes from carbon-rich fossil fuel sources whose combustion produces CO{sub 2}, the main GHG causing global climate change. Furthermore, the direct relation between CO2 emissions and fossil fuels as they are used today makes energy consumption a useful proxy for carbon footprint. It would seem to be a simple matter to reduce energy consumption across the board, both individually and collectively, to help reduce our carbon footprints and therefore solve the energyclimate crisis. But just how much can we reduce carbon footprints when broader forces, such as growth in energy use, cause the total footprint to simultaneously expand? In this feature, I present a calculation of the carbon footprint of the Earth Sciences Division (ESD), the division in which I work at Lawrence Berkeley National Laboratory (LBNL), and discuss the potential for reducing this carbon footprint. It will be apparent that in terms of potential future carbon footprint reductions under projections of expected growth, ESD may be thought of as a microcosm of the situation of the world as a whole, in which alternatives to the business-as-usual use of fossil fuels are needed if absolute GHG emission reductions are to be achieved.

Oldenburg, C.M.

2011-06-01T23:59:59.000Z

331

Waste treatment by selective mineral ion exchanger  

Science Conference Proceedings (OSTI)

STMI, subsidiary company of the AREVA Group with over 40 years in the D and D business, has been continuously innovating and developing new decontamination techniques, with the objectives of achieving more efficient decontaminations on a growing spectrum of media. In the field of liquid waste treatment, STMI manufactures uses and commercialises selective inorganic ion exchangers (RAN). These are hydrated synthetic inorganic compounds prepared from very pure raw materials. Different types of RANs (POLYAN, OXTAIN, Fe-Cu, Fe-CoK, Si-Fe-CoK) can be used to trap a large number of radioactive elements in contaminated effluents. Different implementations could be applied depending on technical conditions. STMI's offers consist in building global solution and preliminary design of installation either in dispersed form (batch) or in column (cartridge filtration). Those products are used all over the world not only in the nuclear business (Canada, US, Belgium, France...) but also in other fields. Indeed, it provides competitive solutions to many domains of application especially water pollution control, liquid waste treatment in the nuclear business by decreasing the activity level of waste. The following paper will focus on the theoretical principle of the mineral exchanger, its implementation and the feed back collected by STMI. (author)

Polito, Aurelie [Areva NC - BUA STMI, 1 route de la Noue - 91196 Gif sur Yvette, Cedex (France)

2007-07-01T23:59:59.000Z

332

Assessment of industrial minerals and rocks in the controlled area  

Science Conference Proceedings (OSTI)

Yucca Mountain in Nye County, Nevada, is a potential site for a permanent repository for high-level nuclear waste in Miocene ash flow tuff. The Yucca Mountain controlled area occupies approximately 98 km{sup 2} that includes the potential repository site. The Yucca Mountain controlled area is located within the southwestern Nevada volcanic field, a large area of Miocene volcanism that includes at least four major calderas or cauldrons. It is sited on a remnant of a Neogene volcanic plateau that was centered around the Timber Mountain caldera complex. The Yucca Mountain region contains many occurrences of valuable or potentially valuable industrial minerals, including deposits with past or current production of construction aggregate, borate minerals, clay, building stone, fluorspar, silicate, and zeolites. The existence of these deposits in the region and the occurrence of certain mineral materials at Yucca Mountain, indicate that the controlled area may have potential for industrial mineral and rock deposits. Consideration of the industrial mineral potential within the Yucca Mountain controlled area is mainly based on petrographic and lithologic studies of samples from drill holes in Yucca Mountain. Clay minerals, zeolites, fluorite, and barite, as minerals that are produced economically in Nevada, have been identified in samples from drill holes in Yucca Mountain.

Castor, S.B. [Nevada Bureau of Mines and Geology, Reno, NV (United States); Lock, D.E. [Mackay School of Mines, Reno, NV (United States)

1996-08-01T23:59:59.000Z

333

Big Sky Carbon Sequestration Partnership  

Science Conference Proceedings (OSTI)

The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO2 utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research agenda in Carbon Sequestration. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other DOE regional partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound MMV is critical for public acceptance of these technologies. Deliverables for the 7th Quarter reporting period include (1) for the geological efforts: Reports on Technology Needs and Action Plan on the Evaluation of Geological Sinks and Pilot Project Deployment (Deliverables 2 and 3), and Report on the Feasibility of Mineralization Trapping in the Snake River Plain Basin (Deliverable 14); (2) for the terrestrial efforts: Report on the Evaluation of Terrestrial Sinks and a Report of the Best Production Practices for Soil C Sequestration (Deliverables 8 and 15). In addition, the 7th Quarter activities for the Partnership included further development of the proposed activities for the deployment and demonstration phase of the carbon sequestration pilots including geological and terrestrial pilots, expansion of the Partnership to encompass regions and institutions that are complimentary to the steps we have identified, building greater collaborations with industry and stakeholders in the region, contributed to outreach efforts that spanned all partnerships, co-authorship on the Carbon Capture and Separation report, and developed a regional basis to address future energy opportunities in the region. The deliverables and activities are discussed in the following sections and appended to this report. The education and outreach efforts have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The public website has been expanded and integrated with the GIS carbon atlas. We have made presentations to stakeholders and policy makers including two tribal sequestration workshops, and made connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmental

Susan M. Capalbo

2005-11-01T23:59:59.000Z

334

Electron Microscopy of Carbon Nanotube Composites  

Science Conference Proceedings (OSTI)

Electron Microscopy of Carbon Nanotube Composites. Summary: Carbon nanomaterials such as carbon nanotubes (CNTs ...

2013-07-01T23:59:59.000Z

335

Quantitative room-temperature mineralization of airborne formaldehyde using  

NLE Websites -- All DOE Office Websites (Extended Search)

Quantitative room-temperature mineralization of airborne formaldehyde using Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts Title Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts Publication Type Journal Article Year of Publication 2011 Authors Sidheswaran, Meera A., Hugo Destaillats, Douglas P. Sullivan, Joern Larsen, and William J. Fisk Journal Applied Catalysis B - Environmental Issue 107 Pagination 34-41 Date Published 2011 Keywords commercial building ventilation & indoor environmental quality group, commercial building ventilation and indoor environmental quality group, energy analysis and environmental impacts department, indoor environment department, indoor environment group DOI 10.1016/j.apcatb.2011.06.032 Attachment Size

336

doi:10.1016/j.gca.2005.02.010 Mobile ions on carbonate surfaces  

E-Print Network (OSTI)

reported in this paper, we employ a new approach to study the density and the mobility of surface ionsdoi:10.1016/j.gca.2005.02.010 Mobile ions on carbonate surfaces TREAVOR A. KENDALL and SCOT T the dissolution and growth of minerals. The present study investigates the density and the mobility of surface

337

Mineral transformation and biomass accumulation associated with uranium bioremediation at Rifle, Colorado  

E-Print Network (OSTI)

phase transformation and biomass accumulation associatedMineral Transformation and Biomass Accumulation Associatedof new mineral phases and biomass. Word count: 5496 (text) +

Li, L.

2009-01-01T23:59:59.000Z

338

The influence of macrostructure and other physical characteristics on compressive parameters of mineral wool products.  

E-Print Network (OSTI)

??The dissertation investigates the influence of macrostructure and other physical properties on mineral wool compressive parameters. The subject of the research is rigid mineral wool (more)

Buska,; Andrius

2010-01-01T23:59:59.000Z

339

Michael Heine, SGL Group - The Carbon Company, Carbon Fibers...  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Fibers in Lightweight Systems for Wind Energy and Automotive Applications: Availability and Challenges for the Future Michael Heine, SGL Group - The Carbon Company, Carbon...

340

Carbon Efficiency, Carbon Reduction Potential, and Economic Developmen...  

Open Energy Info (EERE)

Carbon Reduction Potential, and Economic Development in the People's Republic of China Jump to: navigation, search Tool Summary Name: Carbon Efficiency, Carbon Reduction...

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Carbon Ion Pump for Carbon Dioxide Removal  

coal fired power plants; oil or gas fired power plants; cement production; bio-fuel combustion; Separation of carbon dioxide from other combustion ...

342

Carbon Management and Carbon Dioxide Reduction  

Science Conference Proceedings (OSTI)

Cost-Effective Gas Stream Component Analysis Techniques and Strategies for Carbon Capture Systems from Oxy-Fuel Combustion (An Overview).

343

Big Sky Carbon Sequestration Partnership  

SciTech Connect

The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I are organized into four areas: (1) Evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; (2) Development of GIS-based reporting framework that links with national networks; (3) Design of an integrated suite of monitoring, measuring, and verification technologies, market-based opportunities for carbon management, and an economic/risk assessment framework; (referred to below as the Advanced Concepts component of the Phase I efforts) and (4) Initiation of a comprehensive education and outreach program. As a result of the Phase I activities, the groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that complements the ongoing DOE research agenda in Carbon Sequestration. The geology of the Big Sky Carbon Sequestration Partnership Region is favorable for the potential sequestration of enormous volume of CO{sub 2}. The United States Geological Survey (USGS 1995) identified 10 geologic provinces and 111 plays in the region. These provinces and plays include both sedimentary rock types characteristic of oil, gas, and coal productions as well as large areas of mafic volcanic rocks. Of the 10 provinces and 111 plays, 1 province and 4 plays are located within Idaho. The remaining 9 provinces and 107 plays are dominated by sedimentary rocks and located in the states of Montana and Wyoming. The potential sequestration capacity of the 9 sedimentary provinces within the region ranges from 25,000 to almost 900,000 million metric tons of CO{sub 2}. Overall every sedimentary formation investigated has significant potential to sequester large amounts of CO{sub 2}. Simulations conducted to evaluate mineral trapping potential of mafic volcanic rock formations located in the Idaho province suggest that supercritical CO{sub 2} is converted to solid carbonate mineral within a few hundred years and permanently entombs the carbon. Although MMV for this rock type may be challenging, a carefully chosen combination of geophysical and geochemical techniques should allow assessment of the fate of CO{sub 2} in deep basalt hosted aquifers. Terrestrial carbon sequestration relies on land management practices and technologies to remove atmospheric CO{sub 2} where it is stored in trees, plants, and soil. This indirect sequestration can be implemented today and is on the front line of voluntary, market-based approaches to reduce CO{sub 2} emissions. Initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil Carbon (C) on rangelands, and forested, agricultural, and reclaimed lands. Rangelands can store up to an additional 0.05 mt C/ha/yr, while the croplands are on average four times that amount. Estimates of technical potential for soil sequestration within the region in cropland are in the range of 2.0 M mt C/yr over 20 year time horizon. This is equivalent to approximately 7.0 M mt CO{sub 2}e/yr. The forestry sinks are well documented, and the potential in the Big Sky region ranges from 9-15 M mt CO{sub 2} equivalent per year. Value-added benefits include enhanced yields, reduced erosion, and increased wildlife habitat. Thus the terrestrial sinks provide a viable, environmentally beneficial, and relatively low cost sink that is available to sequester C in the current time frame. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological and terrestrial sequestration re

Susan Capalbo

2005-12-31T23:59:59.000Z

344

Direct Biohydrometallurgical Extraction of Iron from Ore  

Science Conference Proceedings (OSTI)

A completely novel approach to iron extraction was investigated, based on reductive leaching of iron by anaerobic bacteria. Microorganisms were collected from an anaerobic bog where natural seepage of dissolved iron was observed. This mixed culture was used to reduce insoluble iron in a magnetite ore to the soluble ferrous (Fe{sup +2}) state. While dissolution rates were slow, concentrations of dissolved iron as high as 3487 mg/l could be reached if sufficient time was allowed. A factorial study of the effects of trace nutrients and different forms of organic matter indicated that the best dissolution rates and highest dissolved iron concentrations were achieved using soluble carbohydrate (sucrose) as the bacterial food source, and that nutrients other than nitrogen, phosphorus, potassium, sodium, and acetate were not necessary. A key factor in reaching high levels of dissolved iron was maintaining a high level of carbon dioxide in solution, since the solubility of iron carbonates increases markedly as the quantity of dissolved carbon dioxide increases. Once the iron is dissolved, it has been demonstrated that the ferrous iron can then be electroplated from solution, provided that the concentration of iron is sufficiently high and the hydrogen ion concentration is sufficiently low. However, if the leaching solution is electrolyzed directly, organic matter precipitates at the cathode along with the metallic iron. To prevent this problem, the ferrous iron should be separated from the bulk solution in a more concentrated, purified form. One route to accomplishing this is to take advantage of the change in solubility of ferrous iron as a function of carbon dioxide concentration. By cycling the concentration of carbon dioxide in solution, it is possible to produce an iron-rich concentrate that should be suitable for electrolysis. This represents the first viable hydrometallurgical method for leaching iron directly from ore and producing metallic iron.

T.C. Eisele

2005-10-01T23:59:59.000Z

345

Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society (June 2007)  

Science Conference Proceedings (OSTI)

Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society was held in early June 2007 in beautiful and historic Santa Fe, New Mexico, USA. Santa Fe provided an idyllic location in the southwestern United States for the attendees to enjoy technical and social sessions while soaking up the diverse culture and wonderful climate of New MexicoThe Land of Enchantment. The meeting included a large and varied group of scientists, sharing knowledge and ideas, benefitting from technical interactions, and enjoying the wonderful historic and enchanted environs of Santa Fe. Including significant number of international scientists, the meeting was attended by approximately two hundred participants. The meeting included three days of technical sessions (oral and poster presentations), three days of field trips to clay and geological sites of northern New Mexico, and a full day workshop on the stabilization of carbon by clays. Details can be found at the meeting web site: www.sandia.gov/clay.

Randall T. Cygan

2007-06-01T23:59:59.000Z

346

Questions and Answers - What two minerals is the sun made out of?  

NLE Websites -- All DOE Office Websites (Extended Search)

can I explain the Quantum/Wavetheory to my class? can I explain the Quantum/Wave<br>theory to my class? Previous Question (How can I explain the Quantum/Wave theory to my class?) Questions and Answers Main Index Next Question (What is an atom? What are atoms made of?) What is an atom? Whatare atoms made of? What two minerals is the sun made out of? The sun doesn't contain any minerals at all - it's too hot for big molecules to stay together. The sun is made up of two main elements, hydrogen and helium. Hydrogen makes up about 92% of all of the atoms in the sun while helium makes up about 7.8%. Oxygen, carbon, neon and nitrogen make up most of the remaining 0.2%. Author: Steve Gagnon, Science Education Specialist (Other answers by Steve Gagnon) Related Pages: What is plasma? How do you know plasma is real if you can't see it

347

Metallic carbon materials  

DOE Patents (OSTI)

Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

Cohen, Marvin Lou (Berkeley, CA); Crespi, Vincent Henry (Darien, IL); Louie, Steven Gwon Sheng (Berkeley, CA); Zettl, Alexander Karlwalter (Kensington, CA)

1999-01-01T23:59:59.000Z

348

Direct Photons at RHIC  

E-Print Network (OSTI)

The PHENIX experiment has measured direct photons in $\\sqrt{s_{NN}} = 200$ GeV Au+Au collisions and p+p collisions. The fraction of photons due to direct production in Au+Au collisions is shown as a function of $p_T$ and centrality. This measurement is compared with expectation from pQCD calculations. Other possible sources of direct photons are discussed.

S. Mioduszewski; for the PHENIX Collaboration

2004-09-29T23:59:59.000Z

349

NETL: Regional Carbon Sequestration Partnerships  

NLE Websites -- All DOE Office Websites (Extended Search)

RCSP Carbon Storage Regional Carbon Sequestration Partnerships In 2003, the U.S. Department of Energy (DOE) awarded cooperative agreements to seven Regional Carbon Sequestration...

350

Carbon Nanostructure-Based Sensors  

E-Print Network (OSTI)

Control of Single-Walled Carbon Nanotube Functionalization.M. S. Characterizing carbon nanotube samples with resonancewith a Single-Walled Carbon Nanotube Capacitor. Science

Sarkar, Tapan

2012-01-01T23:59:59.000Z

351

Carbonate thermochemical cycle for the production of hydrogen  

DOE Patents (OSTI)

The present invention is directed to a thermochemical method for the production of hydrogen from water. The method includes reacting a multi-valent metal oxide, water and a carbonate to produce an alkali metal-multi-valent metal oxide compound, carbon dioxide, and hydrogen.

Collins, Jack L (Knoxville, TN); Dole, Leslie R (Knoxville, TN); Ferrada, Juan J (Knoxville, TN); Forsberg, Charles W (Oak Ridge, TN); Haire, Marvin J (Oak Ridge, TN); Hunt, Rodney D (Oak Ridge, TN); Lewis Jr., Benjamin E (Knoxville, TN); Wymer, Raymond G (Oak Ridge, TN)

2010-02-23T23:59:59.000Z

352

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

DOE Green Energy (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of carbon electrodes for Direct Carbon Fuel Cells (DCFC), and on carbon foam composites used in ballistic armor, as well as the hydrotreatment of solvents used in the basic solvent extraction process. A major goal is the production of 1500 pounds of binder pitch, corresponding to about 3000 pounds of hydrotreated solvent.

Elliot B. Kennel; Quentin C. Berg; Stephen P. Carpenter; Dady Dadyburjor; Jason C. Hissam; Manoj Katakdaunde; Liviu Magean; Abha Saddawi; Alfred H. Stiller; John W. Zondlo

2006-03-07T23:59:59.000Z

353

Carbon nanotube field effect transistors for power application  

E-Print Network (OSTI)

Carbon nanotubes (CNTs) are nanometer-diameter cylinders formed from rolled-up graphene sheets which have found widespread interests due to their many excellent electrical properties. In particular, most of them are direct ...

Pan, Tao, S.M. Massachusetts Institute of Technology

2007-01-01T23:59:59.000Z

354

Building and testing organized architectures of carbon nanotubes  

Science Conference Proceedings (OSTI)

This paper will focus on the directed assembly of multiwalled carbon nanotubes on various substrates into highly organized structures that include vertically and horizontally oriented arrays, ordered fibers and porous membranes. The concept of growing ...

R. Vajtai; Bingqing Wei; Yung Joon Jung; Anyuan Cao; S. K. Biswas; G. Ramanath; P. M. Ajayan

2003-12-01T23:59:59.000Z

355

Geology and Mineral Deposits of Churchill County, Nevada | Open Energy  

Open Energy Info (EERE)

Geology and Mineral Deposits of Churchill County, Nevada Geology and Mineral Deposits of Churchill County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geology and Mineral Deposits of Churchill County, Nevada Abstract Churchill County, in west-central Nevada, is an area of varied topography and geology that has had a rather small total mineral production. The western part of the county is dominated by the broad low valley of the Carson Sink, which is underlain by deposits of Lake Lahontan. The bordering mountain ranges to the west and south are of low relief and underlain largely by Tertiary volcanic and sedimentary units. Pre-Tertiary rocks are extensively exposed east of the Carson Sink in the Stillwater Range, Clan Alpine Mountains, Augusta Mountains, and New Pass Mountains. The eastern

356

Stewart Mineral Springs Pool & Spa Low Temperature Geothermal Facility |  

Open Energy Info (EERE)

Mineral Springs Pool & Spa Low Temperature Geothermal Facility Mineral Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Stewart Mineral Springs Pool & Spa Low Temperature Geothermal Facility Facility Stewart Mineral Springs Sector Geothermal energy Type Pool and Spa Location Weed, California Coordinates 41.4226498°, -122.3861269° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

357

Removal of mineral matter including pyrite from coal  

SciTech Connect

Mineral matter, including pyrite, is removed from coal by treatment of the coal with aqueous alkali at a temperature of about 175.degree. to 350.degree. C, followed by acidification with strong acid.

Reggel, Leslie (Pittsburgh, PA); Raymond, Raphael (Bethel Park, PA); Blaustein, Bernard D. (Pittsburgh, PA)

1976-11-23T23:59:59.000Z

358

Mercury Contents of Natural Thermal and Mineral Fluids, In- U...  

Open Energy Info (EERE)

Office, 1970 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Mercury Contents of Natural Thermal and Mineral Fluids, In- U.S. Geological...

359

CRITICAL MINERALS AND EMERGING ENERGY TECHNOLOGIES Statement of  

E-Print Network (OSTI)

as in compact-fluorescent light bulbs. These technological developments raise two concerns. First Minerals, and the U.S. Economy2 It was in this light that the standing Committee on Earth Resources

360

Phosphate-mineral interactions and potential consequences for nutrient cycling  

E-Print Network (OSTI)

Biogeochemical cycling of phosphate is a key component in the overall production rate of coastal ecosystems. Mineral phases in the near-shore sediments play a significant role in the return of phosphate remineralized in ...

Oates, Richard Hunter

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

DOE - Office of Legacy Management -- Foote Mineral Co - PA 27  

NLE Websites -- All DOE Office Websites (Extended Search)

Foote Mineral Co - PA 27 Foote Mineral Co - PA 27 FUSRAP Considered Sites Site: Foote Mineral Co. (PA.27 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Exton , Pennsylvania PA.27-1 Evaluation Year: 1987 PA.27-1 Site Operations: Processed rare earth, principally zirconium and monazite sand was processed on a pilot-plant scale. PA.27-2 Site Disposition: Eliminated - Limited quantity of material handled - Potential for contamination considered remote PA.27-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Zirconium, Possibly Uranium PA.27-1 PA.27-2 PA.27-3 Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to Foote Mineral Co.

362

Indian Mineral Leasing Act of 1938 | Open Energy Information  

Open Energy Info (EERE)

Act of 1938 Act of 1938 Jump to: navigation, search Statute Name Indian Mineral Leasing Act Year 1938 Url IndianMineralLeasing1938.jpg Description Provides for leasing of minerals on tribal lands References IMLA[1] United States v. Navajo Nation[2] The Indian Mineral Leasing Act of 1938 (IMLA) provides that "[u]nallotted lands within any Indian reservation," or otherwise under federal jurisdiction, "may, with the approval of the Secretary [of the Interior (Secretary)] ... , be leased for mining purposes, by authority of the tribal council or other authorized spokesmen for such Indians." 25 U.S.C. § 396a. The Act aims to provide Indian tribes with a profitable source of revenue and to foster tribal self-determination by giving Indians a greater

363

Hyperspectral mineral mapping in support of geothermal exploration-  

Open Energy Info (EERE)

mineral mapping in support of geothermal exploration- mineral mapping in support of geothermal exploration- Examples from Long Valley Caldera, CA and Dixie Valley, NV, USA Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Hyperspectral mineral mapping in support of geothermal exploration- Examples from Long Valley Caldera, CA and Dixie Valley, NV, USA Abstract N/A Authors B. A. Martini, E. A. Silver, W. L. Pickles and P. A. Cocks Conference Geothermal Resources Council Annual Meeting; Morelia, Mexico; 2004 Published Geothermal Resources Council Annual Meeting;, 2004 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Hyperspectral mineral mapping in support of geothermal exploration- Examples from Long Valley Caldera, CA and Dixie Valley, NV, USA

364

Effects Of Porosity And Mineral Composition On Cement Alteration During Geological Carbon Sequestration.  

E-Print Network (OSTI)

??With increasing concentrations of greenhouse gases such as CO2, it is likely that major climate change will occur by the end of the century if (more)

Brunet, Jean-patrick

2013-01-01T23:59:59.000Z

365

The impact of mineral fertilizers on the carbon footprint of crop production  

E-Print Network (OSTI)

emissions in fertiliser production. IFS (The InternationalImpact of Agricultural Crop Production using the Life CycleN fertilizer rates in cereal production. Europ. J. Agronomy

Brentrup, Frank

2009-01-01T23:59:59.000Z

366

Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2  

E-Print Network (OSTI)

(Centrifugal) Electric motors (for driving pumps) Flow measuring devices (meters) Primary sedimentation tanks

Paris-Sud XI, Université de

367

Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System  

E-Print Network (OSTI)

microfractures in geopressured shales. AAPG Bulletin 77(8),Porosimetry measurement of shale fabric and its relationshipof intra-aquifer shales and the relative effectiveness of

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2004-01-01T23:59:59.000Z

368

The impact of mineral fertilizers on the carbon footprint of crop production  

E-Print Network (OSTI)

Impact of Agricultural Crop Production using the Life Cyclefield with the harvested crops and the nutrients supplied bysee Fig. 1). Supply of crop residues & organic fertilizer

Brentrup, Frank

2009-01-01T23:59:59.000Z

369

Direct Photons at RHIC  

E-Print Network (OSTI)

A brief overview of direct-photon measurements in p+p and Au+Au collisions at sqrt(s_NN) = 200 GeV with the PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) is given. Direct-photon yields for pT > 4 GeV/c and photon-hadron azimuthal correlations were determined with the aid of an electromagnetic calorimeter. By detecting e+e- pairs from the internal conversion of virtual photons direct-photon yields were measured between 1 direct-photon yield in this range.

Klaus Reygers; for the PHENIX Collaboration

2009-08-17T23:59:59.000Z

370

Direct energy conversion systems  

SciTech Connect

The potential importance of direct energy conversion to the long-term development of fusion power is discussed with stress on the possibility of alleviating waste heat problems. This is envisioned to be crucial for any central power station in the 21st century. Two approaches to direct conversion, i.e., direct collection and magnetic expansion, are reviewed. While other techniques may be possible, none have received sufficient study to allow evaluation. It is stressed that, due to the intimate connection between the type of fusion fuel, the confinement scheme, direct conversion, and the coupling technique, all four element must be optimized simultaneously for high overall efficiency.

Miley, G.H.

1978-01-01T23:59:59.000Z

371

Absorbents for Mineral Oil Spill Cleanup, Phase 3: Field Performance  

Science Conference Proceedings (OSTI)

Residual mineral oil on the ground surface following electrical equipment spills is often removed using a surface application of an absorbent material. Traditional absorbent products include clays, sawdust-like products, silica-based products, and various organic industry byproduct materials. This project was performed in three phases. Phase 1 included testing to measure overall mineral oil absorption efficiency of 24 absorbents. In Phase 2, absorbents studied in Phase 1 were further ...

2012-12-10T23:59:59.000Z

372

Mineral processing techniques for recycling investment casting shell  

Science Conference Proceedings (OSTI)

The Albany Research Center of the U.S. Department of Energy used materials characterization and minerals beneficiation methods to separate and beneficially modify spent investment-mold components to identify recycling opportunities and minimize environmentally sensitive wastes. The physical and chemical characteristics of the shell materials were determined and used to guide bench-scale research to separate reusable components by mineral-beneficiation techniques. Successfully concentrated shell materials were evaluated for possible use in new markets.

Dahlin, Cheryl L.; Nilsen, David N.; Dahlin, David C.; Hunt, Alton H.; Collins, W. Keith

2002-01-01T23:59:59.000Z

373

Comparison of Forest Soil Carbon Dynamics at Five Sites Along a Latitudinal Gradient  

SciTech Connect

Carbon stocks, and C:N ratios, were measured in the forest floor, mineral soil, and two mineral soil fractions (particulate and mineral-associated organic matter, POM and MOM, respectively) at five forest sites, ranging from 60 to 100 years old, along a latitudinal gradient in the eastern United States. Sampling at four sites was replicated over two consecutive years. For many measurements (like forest floor carbon stocks, cumulative soil organic carbon stocks to 20 cm, and the fraction of whole soil carbon in POM), there was no significant difference between years at each site despite the use of somewhat different sampling methods. With one exception, forest floor and mineral soil carbon stocks increased from warm, southern, sites (with fine-textured soils) to northern, cool, sites (with more coarse-textured soils). The exception was a northern site, with less than 10% silt-clay content, that had a soil organic carbon stock similar to those measured at southern sites. Soil carbon at each site was partitioned into two pools (labile and stable) on the basis of carbon measured in the forest floor and POM and MOM fractions from the mineral soil. A two-compartment steady-state model, with randomly varying parameter values, was used in probabilistic calculations to estimate the turnover time of labile soil organic carbon (MRTU) and the annual transfer of labile carbon to stable carbon (k2) at each site in two different years. Based on empirical data, the turnover time of stable soil carbon (MRTS) was determined by mean annual temperature and increased from 30 to 100 years from south to north. Moving from south to north, MRTU increased from approximately 5 to 14 years. Consistent with prior studies, 13C enrichment factors ( ) from the Rayleigh equation, that describe the rate of change in 13C through the soil profile, were an indicator of soil carbon turnover times along the latitudinal gradient. Consistent with its role in stabilization of soil organic carbon, silt-clay content along the gradient was positively correlated (r = 0.91; P 0.001) with parameter k2. Mean annual temperature was indicated as the environmental factor most strongly associated with south to north differences in the storage and turnover of labile soil carbon. However, soil texture appeared to override the influence of temperature when there was too little silt-clay content to stabilize labile soil carbon and thereby protect it from decomposition. Irrespective of latitudinal differences in measured soil carbon stocks, each study site had a relatively high proportion of labile soil carbon (approximately 50% of whole soil carbon to a depth of 20 cm). Depending on unknown temperature sensitivities, large labile pools of forest soil carbon are potentially at risk of depletion by decomposition in a warming climate, and losses could be disproportionately higher from coarse textured forest soils.

Garten Jr, Charles T [ORNL

2011-01-01T23:59:59.000Z

374

Method of making carbon-carbon composites  

DOE Patents (OSTI)

A process for making a carbon-carbon composite having a combination of high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizable woven cloth are covered with petroleum or coal tar pitch and pressed at a temperature a few degrees above the softening point of the pitch to form a green laminated composite. The green composite is restrained in a suitable fixture and heated slowly to carbonize the pitch binder. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnation step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3000.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. to 1300.degree. C. at a reduced pressure for approximately one hundred and fifty (150) hours.

Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

1991-01-01T23:59:59.000Z

375

Iowa State Mining and Mineral Resources Research Institute  

SciTech Connect

During 1990--1991, the Iowa State Mining and Mineral Resources Research Institute (ISMMRRI) has worked diligently to further the objectives of the Mineral Institute Program. About 70% of our Allotment Grant funding goes toward research and education of graduate students within the participating departments of the university. It is our goal to encourage graduate students in diverse fields such as agronomy, engineering, geology, landscape architecture, and many others to pursue a career in mining- and mineral-related fields by preparing them to either enter the private or public sectors. During the 1990 calendar year, ISMMRRI granted research assistantships to 17 graduate students to perform research in topics relating to mineral exploration, characterization and processing, extractive metallurgy, mining engineering, fuel science, mineral waste management, and mined-land reclamation. Research areas include the following: Fluid-inclusion studies on fluorspar mineral deposits in an actively mined region; Geochemical modeling of gold and gold-telluride deposits; Characterization of coal particles for surface-based beneficiation; Impact of surface mining and reclamation of a gypsum deposit area on the surrounding community; Stress-strain response of fine coal particles during transport and storage; Recovery of metal values from mining wastes using bioleaching; Coal beneficiation utilizing triboelectric charging in a fast fluidized bed; and Mathematical modeling of breakage for optimum sizing during crushing of rock.

Not Available

1991-08-01T23:59:59.000Z

376

An Index-Based Approach to Assessing Recalcitrance and Soil Carbon Sequestration Potential of Engineered Black Carbons (Biochars)  

Science Conference Proceedings (OSTI)

The ability of engineered black carbons (or biochars) to resist abiotic and, or biotic degradation (herein referred to as recalcitrance) is crucial to their successful deployment as a soil carbon sequestration strategy. A new recalcitrance index, the R{sub 50}, for assessing biochar quality for carbon sequestration is proposed. The R{sub 50} is based on the relative thermal stability of a given biochar to that of graphite and was developed and evaluated with a variety of biochars (n = 59), and soot-like black carbons. Comparison of R{sub 50}, with biochar physicochemical properties and biochar-C mineralization revealed the existence of a quantifiable relationship between R{sub 50} and biochar recalcitrance. As presented here, the R{sub 50} is immediately applicable to pre-land application screening of biochars into Class A (R{sub 50} {>=} 0.70), Class B (0.50 {biochars would have carbon sequestration potential comparable to soot/graphite and uncharred plant biomass, respectively, while Class B biochars would have intermediate carbon sequestration potential. We believe that the coupling of the R{sub 50}, to an index-based degradation, and an economic model could provide a suitable framework in which to comprehensively assess soil carbon sequestration in biochars.

Harvey, Omar R.; Kuo, Li-Jung; Zimmerman, Andrew R.; Louchouarn, Patrick; Amonette, James E.; Herbert, Bruce

2012-01-10T23:59:59.000Z

377

Quantifying Carbon Cycle Feedbacks  

Science Conference Proceedings (OSTI)

Perturbations to the carbon cycle could constitute large feedbacks on future changes in atmospheric CO2 concentration and climate. This paper demonstrates how carbon cycle feedback can be expressed in formally similar ways to climate feedback, ...

J. M. Gregory; C. D. Jones; P. Cadule; P. Friedlingstein

2009-10-01T23:59:59.000Z

378

Carbon Monoxide Safety Tips  

E-Print Network (OSTI)

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist.

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

379

NETL: Carbon Storage Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

2013 Carbon Storage Newsletter PDF-571KB has been posted. 08.27.2013 Publications August 2013 Carbon Storage Newsletter PDF-1.1MB has been posted. 08.15.2013 News Ancient...

380

Carbon nanotube nanoelectrode arrays  

DOE Patents (OSTI)

The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

Ren, Zhifeng (Newton, MA); Lin, Yuehe (Richland, WA); Yantasee, Wassana (Richland, WA); Liu, Guodong (Fargo, ND); Lu, Fang (Burlingame, CA); Tu, Yi (Camarillo, CA)

2008-11-18T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Terrestrial Carbon Management  

NLE Websites -- All DOE Office Websites (Extended Search)

Terrestrial Carbon Management Data Sets and Analyses Terrestrial Carbon Management Data Sets and Analyses Carbon Accumulation with Cropland Management Influence of Agricultural Management on Soil Organic Carbon: A Compendium and Assessment of Canadian Studies (VandenBygaart et al., Agriculture and Agri-Food Canada) Soil Carbon Sequestration by Tillage and Crop Rotation: A Global Data Analysis (West and Post, Oak Ridge National Laboratory) Preliminary Estimates of the Potential for Carbon Mitigation in European Soils Through No-Till Farming (Smith et al., University of Aberdeen, United Kingdom) Potential for Carbon Sequestration in European Soils: Preliminary Estimates for Five Scenarios Using Results from Long-Term Experiments (Smith et al., University of Aberdeen, United Kingdom) Carbon Accumulation with Grassland Management

382

The Importance of Carbon Footprint Estimation Boundaries  

E-Print Network (OSTI)

emissions), and direct emissions plus industry energy inputs are, on average, only 26% of the total supply from purchased energy, with less focus on supply chainemissions an industry are, on average, only 14% of the total supply chain carbon emissions (often called Tier 1

Kammen, Daniel M.

383

Carbon Footprint and Carbon Deficit Analysis of Iron and Steel ...  

Science Conference Proceedings (OSTI)

Symposium, Energy Technologies and Carbon Dioxide Management. Presentation Title ... Study on Capture, Recovery and Utilization of Carbon Dioxide.

384

Measurement of carbon for carbon sequestration and site monitoring  

Science Conference Proceedings (OSTI)

A 2 to 6 degree C increase in global temperature by 2050 has been predicted due to the production of greenhouse gases that is directly linked to human activities. This has encouraged an increase in the international efforts on ways to reduce anthropogenic emissions of greenhouse gases particularly carbon dioxide (CO{sub 2}) as evidence for the link between atmospheric greenhouse gases and climate change has been established. Suggestion that soils and vegetation could be managed to increase their uptake and storage of CO{sub 2}, and thus become 'land carbon sinks' is an incentive for scientists to undertake the ability to measure and quantify the carbon in soils and vegetation to establish base-line quantities present at this time. The verification of the permanence of these carbon sinks has raised some concern regarding the accuracy of their long-term existence. Out of the total percentage of carbon that is potentially sequestered in the terrestrial land mass, only 25% of that is sequestered above ground and almost 75% is hypothesized to be sequestered underground. Soil is composed of solids, liquids, and gases which is similar to a three-phase system. The gross chemical composition of soil organic carbon (SOC) consists of 65% humic substances that are amorphous, dark-colored, complex, polyelectrolyte-like materials that range in molecular weight from a few hundred to several thousand Daltons. The very complex structure of humic and fulvic acid makes it difficult to obtain a spectral signature for all soils in general. The humic acids of different soils have been observed to have polymeric structure, appearing as rings, chains and clusters as seen in electron microscope observations. The humification processes of the soils will decide the sizes of their macromolecules that range from 60-500 angstroms. The percentage of the humus that occurs in the light brown soils is much lower than the humus present in dark brown soils. The humus of forest soils is characterized by a high content of fulvic acids while the humus of peat and grassland soils is high in humic acids. Similarly it is well known that the amount of carbon present in forest soils is lower than the amount present in grassland soils.

Martin, Madhavi Z [ORNL; Wullschleger, Stan D [ORNL; Garten Jr, Charles T [ORNL; Palumbo, Anthony Vito [ORNL

2007-01-01T23:59:59.000Z

385

Directed light fabrication of rhenium components  

SciTech Connect

Directed Light Fabrication (DLF) is a direct metal deposition process that fuses powder, delivered by gas into the focal zone of a high powered laser beam to form fully dense near-net shaped components. This is accomplished in one step without the use of molds, dies, forming, pressing, sintering or forging equipment. DLF is performed in a high purity inert environment free from the contaminants associated with conventional processing such as oxide and carbon pickup, lubricants, binding agents, cooling or cleaning agents. Applications using rhenium have historically been limited in part by its workability and cost. This study demonstrates the ability to fuse rhenium metal powder, using a DLF machine, into free standing rods and describes the associated parameter study. Microstructural comparisons between DLF deposited rhenium and commercial rhenium sheet product is performed. This research combined with existing DLF technology demonstrates the feasibility of forming complex rhenium, metal shapes directly from powder.

Milewski, J.O.; Thoma, D.J.; Lewis, G.K.

1997-02-01T23:59:59.000Z

386

direct_deposit_111609  

NLE Websites -- All DOE Office Websites (Extended Search)

PROTECT YOUR BANKING INFORMATION: PROTECT YOUR BANKING INFORMATION: DO NOT complete this form until you are ready to submit it to the Payroll Department. DIRECT DEPOSIT REQUEST Directions: 1. Provide required information neatly, legibly; 2. If Checking Account Direct Deposit, include a voided check. a. DO NOT submit a deposit slip! 3. If Savings Account Direct Deposit, include a copy of savings card. 4. Sign this form; 5. Inter-office mail it to Craft Payroll at "P238." DIRECT DEPOSITION AUTHORIZATION I hereby authorize Los Alamos National Laboratory, hereinafter called The Laboratory, to initiate credit entries and, if necessary, debit entries and adjustments for any credit entries in error to my account listed on this form. If deposit is for:

387

Directions and Maps  

NLE Websites -- All DOE Office Websites (Extended Search)

Directions & Maps Directions & Maps Plan Your Visit Visit About the Museum Museum Hours Directions & Maps When to Visit Arrange for a Visit Around Los Alamos Contact Us invisible utility element Directions and Maps Aerial View of Los Alamos Aerial approach to the Los Alamos airport Where we're located Los Alamos (elevation 7,355 feet) is perched high atop the Pajarito Plateau in the Jemez Mountains, 35 miles northwest of Santa Fe. The Bradbury Science Museum is located in downtown Los Alamos at the corner of Central Avenue and 15th Street. If you're driving here and using GPS navigation, our address is 1350 Central Avenue, Los Alamos, NM 87544. How to get here From Albuquerque take I-25 north to Santa Fe (take NM 599 for most direct route), then US 84/285 north to Pojoaque. At Pojoaque take the NM 502 exit

388

Carbon Dioxide Compression  

Science Conference Proceedings (OSTI)

Page 1. C opyright 2009 Carbon Dioxide Compression DOE EPRI NIST ... Greenhouse gas sequestration Page 5. 5 C opyright 2009 ...

2013-04-22T23:59:59.000Z

389

Carbon Mitigation Measurements  

Science Conference Proceedings (OSTI)

... sustainable technologies such as CO 2 capture and sequestration (CCS ... property diagnostic tools (under realistic conditions for carbon capture from ...

2012-10-04T23:59:59.000Z

390

Big Sky Carbon Atlas  

DOE Data Explorer (OSTI)

(Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

Carbon Sequestration Partnership, Big Sky [BSCSP; ,

391

Electrocatalysts on Carbon Nanoparticles  

Carbon nanostructures offer extremely high surface areas and so are attractive candidates to support dispersed catalysts. These nanostructures, ...

392

Low Carbon Fuel Standards  

E-Print Network (OSTI)

land-use changes. When biofuel production increases, land ison carbon releases. If biofuel production does not result in

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

393

Minerals yearbook: Mineral industries of the Middle East. Volume 3. 1989 international review  

SciTech Connect

The production and processing of crude petroleum and natural gas are the dominant economic sectors of the Middle East. The 15 countries that constitute the region accounted for 26% of world crude petroleum output, 17% of world natural gas plant liquid production, and almost 5% of world dry natural gas production. About 66% of total world crude petroleum reserves and 31% of total world natural gas reserves are in the Middle East. U.S. imports of mineral-based materials from the region were primarily energy products. U.S. net oil imports from the Middle East, which include crude petroleum, natural gas liquids, and petroleum refinery products, were about 26% of total U.S. net oil imports or about 680 million barrels in 1989.

Not Available

1989-01-01T23:59:59.000Z

394

Formation of Carbon Dwarfs  

E-Print Network (OSTI)

We consider the formation of dwarf carbon stars via accretion from a carbon AGB companion in light of the new 107 object sample of Downes et al. (2004). This sample is now large enough to allow good mass determination via comparison of a composite spectrum to theoretical atmospheric models. Carbon dwarfs of spectral type M are indeed main sequence M dwarfs with enhanced metallicity and carbon abundance. We also calculate the predicted abundance of both M and of F/G carbon dwarfs, and show that the latter should be falsifiable in the near future.

Charles L. Steinhardt; Dimitar D. Sasselov

2005-02-08T23:59:59.000Z

395

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM CARBON DIOXIDE SEQUESTRATION  

DOE Green Energy (OSTI)

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds or bioreactors to abate CO{sub 2} emissions from power plants.

V. J. Fabry

2003-10-30T23:59:59.000Z

396

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

DOE Green Energy (OSTI)

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds or bioreactors to abate CO{sub 2} emissions from power plants.

V.J. Fabry

2004-10-30T23:59:59.000Z

397

CALCIUM CARBONATE PRODUCTION BY COCCOLITHAPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V. J.Fabry

2004-01-30T23:59:59.000Z

398

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2001-12-15T23:59:59.000Z

399

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2003-07-15T23:59:59.000Z

400

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2001-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "direct mineral carbonation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2003-04-15T23:59:59.000Z

402

Calcium Carbonate Production by Coccolithophorid Algae in Long Term, Carbon Dioxide Sequestration  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry

2005-04-29T23:59:59.000Z

403

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2002-12-15T23:59:59.000Z

404

Calcium Carbonate Production by Coccolithophorid Algae in Long Term, Carbon Dioxide Sequestration  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V. J. Fabry

2006-06-30T23:59:59.000Z

405

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2002-07-09T23:59:59.000Z

406

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids ? single-celled, marine algae that are the major global producers of calcium carbonate ? to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V. J. Fabry

2005-01-24T23:59:59.000Z

407

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids single-celled, marine algae that are the major global producers of calcium carbonate to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry

2001-07-01T23:59:59.000Z

408

CALCIUM CARBONATE PRODUCTION BY COCCOLITHOPHORID ALGAE IN LONG TERM, CARBON DIOXIDE SEQUESTRATION  

SciTech Connect

Predictions of increasing levels of anthropogenic carbon dioxide (CO{sub 2}) and the specter of global warming have intensified research efforts to identify ways to sequester carbon. A number of novel avenues of research are being considered, including bioprocessing methods to promote and accelerate biosequestration of CO{sub 2} from the environment through the growth of organisms such as coccolithophorids, which are capable of sequestering CO{sub 2} relatively permanently. Calcium and magnesium carbonates are currently the only proven, long-term storage reservoirs for carbon. Whereas organic carbon is readily oxidized and releases CO{sub 2} through microbial decomposition on land and in the sea, carbonates can sequester carbon over geologic time scales. This proposal investigates the use of coccolithophorids--single-celled, marine algae that are the major global producers of calcium carbonate--to sequester CO{sub 2} emissions from power plants. Cultivation of coccolithophorids for calcium carbonate (CaCO{sub 3}) precipitation is environmentally benign and results in a stable product with potential commercial value. Because this method of carbon sequestration does not impact natural ecosystem dynamics, it avoids controversial issues of public acceptability and legality associated with other options such as direct injection of CO{sub 2} into the sea and ocean fertilization. Consequently, cultivation of coccolithophorids could be carried out immediately and the amount of carbon sequestered as CaCO{sub 3} could be readily quantified. The significant advantages of this approach warrant its serious investigation. The major goals of the proposed research are to identify the growth conditions that will result in the maximum amount of CO{sub 2} sequestration through coccolithophorid calcite production and to evaluate the costs/benefits of using coccolithophorid cultivation ponds to abate CO{sub 2} emissions from power plants.

V.J. Fabry, Ph.D.

2002-04-05T23:59:59.000Z

409

Surface Wind Direction Variability  

Science Conference Proceedings (OSTI)

Common large shifts of wind direction in the weak-wind nocturnal boundary layer are poorly understood and are not adequately captured by numerical models and statistical parameterizations. The current study examines 15 datasets representing a ...

Larry Mahrt

2011-01-01T23:59:59.000Z

410

2013 FCMN Directions  

Science Conference Proceedings (OSTI)

... $100 (one way). Driving directions: Take I-95S to Exit 4B towards Washington.Merge onto I-495 to Exit 27 towards Silver Spring.Slight right onto ...

2013-02-27T23:59:59.000Z

411

Direct nuclear pumped laser  

DOE Patents (OSTI)

There is provided a direct nuclear pumped gas laser in which the lasing mechanism is collisional radiated recombination of ions. The gas laser active medium is a mixture of the gases, with one example being neon and nitrogen.

Miley, George H. (Champagne, IL); Wells, William E. (Urbana, IL); DeYoung, Russell J. (Hampton, VA)

1978-01-01T23:59:59.000Z

412

Maps & Directions | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Maps & Directions ORNL is located in Roane County, Tennessee, about 7 miles from the center of the city of Oak Ridge and about 25 miles from the McGhee Tyson Airport near...

413

NETL: Carbon Storage FAQs  

NLE Websites -- All DOE Office Websites (Extended Search)

different options for CO2 storage? different options for CO2 storage? Oil and gas reservoirs, many containing carbon dioxide (CO2), as well as natural deposits of almost pure CO2, can be found in many places in the United States and around the world. These are examples of long-term storage of CO2 by nature, where "long term" means millions of years. Their existence demonstrates that naturally occurring geologic formations and structures of various kinds are capable of securely storing CO2 deep in the subsurface for very long periods of time. Because of the economic importance of oil and gas, scientists and engineers have studied these natural deposits for many decades in order to understand the physical and chemical processes which led to their formation. There are also many decades of engineering experience in subsurface operations similar to those needed for CO2 storage. The most directly applicable experience comes from the oil industry, which, for 40 years, has injected CO2 in depleted oil reservoirs for the recovery of additional product through enhanced oil recovery (EOR). Additional experience comes from natural gas storage operations, which have utilized depleted gas reservoirs, as well as reservoirs containing only water. Scientists and engineers are now combining the knowledge obtained from study of natural deposits with experience from analogous operations as a basis for studying the potential for large-scale storage of CO2 in the deep subsurface.

414

Refrigerant directly cooled capacitors  

DOE Patents (OSTI)

The invention is a direct contact refrigerant cooling system using a refrigerant floating loop having a refrigerant and refrigeration devices. The cooling system has at least one hermetic container disposed in the refrigerant floating loop. The hermetic container has at least one electronic component selected from the group consisting of capacitors, power electronic switches and gating signal module. The refrigerant is in direct contact with the electronic component.

Hsu, John S. (Oak Ridge, TN); Seiber, Larry E. (Oak Ridge, TN); Marlino, Laura D. (Oak Ridge, TN); Ayers, Curtis W. (Kingston, TN)

2007-09-11T23:59:59.000Z

415

Outline Development of Direct PCR Benefits of Direct PCR ...  

Science Conference Proceedings (OSTI)

... 1 Direct PCR Amplification of STR Loci: Protocols and Performance ... Benefits of direct PCR Collection media: FTA and 903 paper ...

2011-05-31T23:59:59.000Z

416

Coke mineral transformations in the experimental blast furnace  

SciTech Connect

Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development (CCSD)

2008-09-15T23:59:59.000Z

417

Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon fiber  

E-Print Network (OSTI)

Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon Accepted 14 January 2010 Available online 20 January 2010 A B S T R A C T Single-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) membranes (buckypaper) and carbon nanofiber (CNF) paper

Das, Suman

418

Potential net soil N mineralization and decomposition of glycine-13C in forest soils along an elevation gradient  

SciTech Connect

The objective of this research was to better understand patterns of soil nitrogen (N) availability and soil organic matter (SOM) decomposition in forest soils across an elevation gradient (235-1670 m) in the southern Appalachian Mountains. Laboratory studies were used to determine the potential rate of net soil N mineralization and in situ studies of {sup 13}C-labelled glycine were used to infer differences in decomposition rates. Nitrogen stocks, surface soil (0-5 cm) N concentrations, and the pool of potentially mineralizable surface soil N tended to increase from low to high elevations. Rates of potential net soil N mineralization were not significantly correlated with elevation. Increasing soil N availability with elevation is primarily due to greater soil N stocks and lower substrate C-to-N ratios, rather than differences in potential net soil N mineralization rates. The loss rate of {sup 13}C from labelled soils (0-20 cm) was inversely related to study site elevation (r = -0.85; P < 0.05) and directly related to mean annual temperature (+0.86; P<0.05). The results indicated different patterns of potential net soil N mineralization and {sup 13}C loss along the elevation gradient. The different patterns can be explained within a framework of climate, substrate chemistry, and coupled soil C and N stocks. Although less SOM decomposition is indicated at cool, high-elevation sites, low substrate C-to-N ratios in these N-rich systems result in more N release (N mineralization) for each unit of C converted to CO{sub 2} by soil microorganisms.

Garten Jr, Charles T [ORNL

2004-09-01T23:59:59.000Z

419

Composition and decomposition of soybean and sorghum tissues grown under elevated atmospheric carbon dioxide  

Science Conference Proceedings (OSTI)

It has been hypothesized that changes in both quantity and quality of plant residue inputs to soils as atmospheric carbon dioxide (CO{sub 2}) concentration increases may alter carbon (C) and nitrogen (N) turnover rates and pool sizes. We determined the effect of elevated atmospheric CO{sub 2} on plant tissue quality, and how modifications in tissue quality affect C and N mineralization. Soybean and sorghum were grown under elevated (704.96 {plus_minus} 0.33 {mu}mol CO{sub 2} mol{sup {minus}1}) and ambient (357.44 {plus_minus} 0.12 {mu}mol CO{sub 2} mol{sup {minus}1}) atmospheric CO{sub 2} in open-top chambers. Leaf and stem tissues were separated form harvested plants and analyzed for C,N, lignin, and cellulose. Tissues were applied to Norfolk loamy sand (fine-loamy, siliceous, thermic Typic Kandiudult) and aerobically incubated for 70-d to determine C and N mineralization, C turnover, relative N mineralization, and C/N mineralized. Elevated CO{sub 2} had no effect on plant residue C concentration, but N concentration of soybean leaves and stems and sorghum stems was reduced; however, CO{sub 2} enrichment increased C/N ratio and lignin concentration for only sorghum stems and soybean leaves, respectively. Source of plant residue (i.e., produced under either elevated or ambient CO{sub 2}) had no impact on soil C turnover, relative N mineralization, cumulative C and N mineralization, and C/N mineralized. These data suggest that increasing atmospheric CO{sub 2} will have little effect on composition or decomposition of field crop residues. Thus, since CO{sub 2} enrichment results in increased photosynthetic C fixation, the possibility exists for increased soil C storage under field crops in an elevated CO{sub 2} world. 29 refs., 4 figs., 4 tabs.

Henning, F.P. [Cooperative Ext. Serv., Dunwoody, GA (United States); Wood, C.W. [Auburn Univ., AL (United States); Rogers, H.H.; Runion, G.B.; Prior, S.A. [National Soil Dynamics Lab., Auburn, AL (United States)

1996-07-01T23:59:59.000Z

420

Carbon dioxide sensor  

SciTech Connect

The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

2011-11-15T23:59:59.000Z

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421

Buckhorn Mineral Wells Pool & Spa Low Temperature Geothermal Facility |  

Open Energy Info (EERE)

Buckhorn Mineral Wells Pool & Spa Low Temperature Geothermal Facility Buckhorn Mineral Wells Pool & Spa Low Temperature Geothermal Facility Facility Buckhorn Mineral Wells Sector Geothermal energy Type Pool and Spa Location Mesa, Arizona Coordinates 33.4222685°, -111.8226402° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

422

Mineral Recovery from Geothermal Fluids | Open Energy Information  

Open Energy Info (EERE)

Mineral Recovery from Geothermal Fluids Mineral Recovery from Geothermal Fluids Jump to: navigation, search Geothermal ARRA Funded Projects for Mineral Recovery from Geothermal Fluids Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":false,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

423

Underground radio technology saves miners and emergency response personnel  

NLE Websites -- All DOE Office Websites (Extended Search)

Underground radio technology saves miners and emergency response Underground radio technology saves miners and emergency response personnel Underground radio technology saves miners and emergency response personnel Founded through LANL, Vital Alert Technologies, Inc. (Vital Alert) has launched a wireless, two-way real-time voice communication system that is effective through 1,000+ feet of solid rock. April 3, 2012 Vital Alert's C1000 mine and tunnel radios use magnetic induction, advanced digital communications techniques and ultra-low frequency transmission to wirelessly provide reliable 2-way voice, text, or data links through rock strata and other solid media. Vital Alert's C1000 mine and tunnel radios use magnetic induction, advanced digital communications techniques and ultra-low frequency transmission to wirelessly provide reliable 2-way voice, text, or data links through rock

424

STATE OF OREGON DEPARTMENT OF GEOLOGY AND MINERAL INDUSTRIES  

NLE Websites -- All DOE Office Websites (Extended Search)

OREGON OREGON DEPARTMENT OF GEOLOGY AND MINERAL INDUSTRIES Portland, Oregon 97201 910 State Office Building r DOE/ID/12526--T2 OPEN-FILE REPORT 0-86-3 DE87 013077 INVESTIGATION OF THE TEIERMAL REGIME AND GEOLOGIC HISTORY OF THE DRILLING IN THE CASCADE RANGE CASCADE VOLCANIC ARC: FIRST PHASE OF A PROGRAM FOR SCIENTIFIC Prepared by George R . Priest Oregon Department of Geology and Mineral Industries Preparation and publication of this document were supported b the Ore on Department of Geology and Mineral Industries and Grant No. DE-%G07-841&.2526 from the U . S . Department of Energy DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees,

425

DOE - Office of Legacy Management -- International Minerals and Chemical  

Office of Legacy Management (LM)

International Minerals and Chemical International Minerals and Chemical Corp - Pilot Plant - FL 02 FUSRAP Considered Sites Site: International Minerals and Chemical Corp - Pilot Plant (FL.02) Designated Name: Not Designated Alternate Name: None Location: Mulberry , Florida FL.02-1 Evaluation Year: 1985 FL.02-2 Site Operations: Erected and operated a pilot plant to process material from the leached zone of the Florida pebble phosphate field for the recovery of uranium and other saleable products and also conducted experimental investigations to recover uranium from phosphates. FL.02-3 FL.02-4 Site Disposition: Eliminated - No Authority FL.02-6 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium FL.02-3 FL.02-4 Radiological Survey(s): Yes FL.02-1

426

Lung cancer epidemiology in New Mexico uranium miners  

SciTech Connect

This investigation assesses the health effects of radon progeny exposure in New Mexico uranium miners. Cumulative exposures sustained by most New Mexico miners are well below those received earlier in the Colorado Plateau. This project utilizes the research opportunity offered by New Mexico miners to address unresolved issues related to radon progeny exposure: (1) the lung cancer risk of lower levels of exposure, (2) interaction between radon progeny exposure and cigarette smoking in the causation of lung cancer, (3) the relationship between lung cancer histologic type and radon progeny exposure, and (4) possible effects of radon progeny exposure other than lung cancer. A cohort study of 3800 men with at least one year of underground uranium mining experience in New Mexico is in progress. Results are discussed.

Samet, J.M.

1991-11-01T23:59:59.000Z

427

Hyperspectral Mineral Mapping In Support Of Geothermal Exploration-  

Open Energy Info (EERE)

Mineral Mapping In Support Of Geothermal Exploration- Mineral Mapping In Support Of Geothermal Exploration- Examples From Long Valley Caldera, Ca And Dixie Valley, Nv, Usa Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Book: Hyperspectral Mineral Mapping In Support Of Geothermal Exploration- Examples From Long Valley Caldera, Ca And Dixie Valley, Nv, Usa Details Activities (2) Areas (2) Regions (0) Abstract: Growing interest and exploration dollars within the geothermal sector have paved the way for increasingly sophisticated suites of geophysical and geochemical tools and methodologies. The efforts to characterize and assess known geothermal fields and find new, previously unknown resources has been aided by the advent of higher spatial resolution airborne geophysics (e.g. aeromagnetics), development of new seismic

428

Life cycle assessment and biomass carbon accounting  

U.S. Energy Information Administration (EIA) Indexed Site

Biomass feedstocks Biomass feedstocks and the climate implications of bioenergy Steven Hamburg Environmental Defense Fund Slides adapted from Reid Miner NCASI On the landscape, the single-plot looks like this 75 Harvested and burned for energy In year zero, the plot is harvested and the wood is burned for energy 1.1 Year 1 After regeneration begins, the growing biomass sequesters small amounts of CO2 annually 2.1 Year 2 2.8 Year 3 ??? Year X, until next harvest Σ = . Over time, if carbon stocks are returned to pre-harvest levels... ...the net emissions over this time are zero. single plot analysis Net Cumulative CO2 combustion emissions Cumulative CO2 combustion emissions Time Time Biomass energy Fossil fuel energy single plot analysis Net Cumulative CO2 combustion emissions Cumulative

429

Direct Photons at RHIC  

E-Print Network (OSTI)

Direct photons are ideal tools to investigate kinematical and thermodynamical conditions of heavy ion collisions since they are emitted from all stages of the collision and once produced they leave the interaction region without further modification by the medium. The PHENIX experiment at RHIC has measured direct photon production in p+p and Au+Au collisions at 200 GeV over a wide transverse momentum ($p_T$) range. The $p$ + $p$ measurements allow a fundamental test of QCD, and serve as a baseline when we try to disentangle more complex mechanisms producing high $p_T$ direct photons in Au+Au. As for thermal photons in Au+Au we overcome the difficulties due to the large background from hadronic decays by measuring "almost real" virtual photons which appear as low invariant mass $e^+e^-$ pairs: a significant excess of direct photons is measured above the above next-to-leading order perturbative quantum chromodynamics calculations. Additional insights on the origin of direct photons can be gained with the study of the azimuthal anisotropy which benefits from the increased statistics and reaction plane resolution achieved in RHIC Year-7 data.

G. David; for the PHENIX Collaboration

2008-10-06T23:59:59.000Z

430

ARM - Field Campaign - Characterization of Black Carbon Mixing State  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsCharacterization of Black Carbon Mixing State govCampaignsCharacterization of Black Carbon Mixing State Related Campaigns Characterization of Black Carbon Mixing State - II 2014.02.15, Sedlacek, OSC Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Characterization of Black Carbon Mixing State 2012.11.01 - 2013.06.14 Lead Scientist : Arthur Sedlacek For data sets, see below. Description The objective of the proposed experiments was to characterize the mixing state of black carbon produced in biomass burning using the single particle soot photometer (SP2). The large uncertainty associated with black carbon (BC) direct forcing is due, in part, to the dependence of light absorption of BC-containing particles on the position of the BC aggregate within the particle. It is

431

Carbon activation process for increased surface accessibility in electrochemical capacitors  

DOE Patents (OSTI)

A process for making carbon film or powder suitable for double capacitor electrodes having a capacitance of up to about 300 F/cm.sup.3 is disclosed. This is accomplished by treating in aqueous nitric acid for a period of about 5 to 15 minutes thin carbon films obtained by carbonizing carbon-containing polymeric material having a high degree of molecular directionality, such as polyimide film, then heating the treated carbon film in a non-oxidizing atmosphere at a non-graphitizing temperature of at least 350.degree. C. for about 20 minutes, and repeating alternately the nitric acid step and the heating step from 7 to 10 times. Capacitors made with this carbon may find uses ranging from electronic devices to electric vehicle applications.

Doughty, Daniel H. (Albuquerque, NM); Eisenmann, Erhard T. (Belpre, OH)

2001-01-01T23:59:59.000Z

432

Direct conversion technology  

DOE Green Energy (OSTI)

The overall objective of the Direct Conversion Technology task is to develop an experimentally verified technology base for promising direct conversion systems that have potential application for energy conservation in the end-use sectors. This report contains progress of research on the Alkali Metal Thermal-to-Electric Converter (AMTEC) and on the Two-Phase Liquid-Metal MHD Electrical Generator (LMMHD) for the period January 1, 1991 through December 31, 1991. Research on AMTEC and on LMMHD was initiated during October 1987. Reports prepared on previous occasions (Refs. 1--5) contain descriptive and performance discussions of the following direct conversion concepts: thermoelectric, pyroelectric, thermionic, thermophotovoltaic, thermoacoustic, thermomagnetic, thermoelastic (Nitionol heat engine); and also, more complete descriptive discussions of AMTEC and LMMHD systems.

Massier, P.F.; Back, L.H.; Ryan, M.A.; Fabris, G.

1992-01-07T23:59:59.000Z

433

Carbon-based Fuel Cell  

DOE Green Energy (OSTI)

The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

Steven S. C. Chuang

2005-08-31T23:59:59.000Z

434

Direct Conversion Technology  

DOE Green Energy (OSTI)

The overall objective of the Direct Conversion Technology task is to develop an experimentally verified technology base for promising direct conversion systems that have potential application for energy conservation in the end-use sectors. Initially, two systems were selected for exploratory research and advanced development. These are Alkali Metal Thermal-to-Electric Converter (AMTEC) and Two-Phase Liquid Metal MD Generator (LMMHD). This report describes progress that has been made during the first six months of 1992 on research activities associated with these two systems. (GHH)

Back, L.H.; Fabris, G.; Ryan, M.A.

1992-07-01T23:59:59.000Z

435

Carbon Emissions: Paper Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Paper Industry Paper Industry Carbon Emissions in the Paper Industry The Industry at a Glance, 1994 (SIC Code: 26) Total Energy-Related Emissions: 31.6 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 8.5% Total First Use of Energy: 2,665 trillion Btu -- Pct. of All Manufacturers: 12.3% -- Pct. Renewable Energy: 47.7% Carbon Intensity: 11.88 MMTC per quadrillion Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 31.6 Net Electricity 11.0

436

Carbon Emissions: Food Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Food Industry Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 6.6% Total First Use of Energy: 1,193 trillion Btu -- Pct. of All Manufacturers: 5.5% Carbon Intensity: 20.44 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 24.4 Net Electricity 9.8 Natural Gas 9.1 Coal 4.2 All Other Sources 1.3 Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998

437

Carbon Emissions: Chemicals Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Chemicals Industry Chemicals Industry Carbon Emissions in the Chemicals Industry The Industry at a Glance, 1994 (SIC Code: 28) Total Energy-Related Emissions: 78.3 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 21.1% -- Nonfuel Emissions: 12.0 MMTC Total First Use of Energy: 5,328 trillion Btu -- Pct. of All Manufacturers: 24.6% Energy Sources Used As Feedstocks: 2,297 trillion Btu -- LPG: 1,365 trillion Btu -- Natural Gas: 674 trillion Btu Carbon Intensity: 14.70 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 78.3 Natural Gas 32.1

438

The Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Carbon Cycle The Carbon Cycle The global carbon cycle involves the carbon in and exchanging between the earth's atmosphere, fossil fuels, the oceans, and the vegetation and soils of the earth's terrestrial ecosystems. image Each year, the world's terrestrial ecosystems withdraw carbon from the atmosphere through photosynthesis and add it again through respiration and decay. A more detailed look at the global carbon cycle for the 1990s is shown below. The main annual fluxes in GtC yr-1 are: pre-industrial "natural" fluxes in black and "anthropogenic" fluxes in red (modified from Sarmiento and Gruber, 2006, with changes in pool sizes from Sabine et al., 2004a). The net terrestrial loss of -39 GtC is inferred from cumulative fossil fuel emissions minus atmospheric increase minus ocean storage. The loss of

439

NETL: Carbon Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Storage Technologies Carbon Storage (formerly referred to as the "Carbon Sequestration Program") Program Overview For quick navigation of NETL's Carbon Storage Program website, please click on the image. NETL's Carbon Storage Program Fossil fuels are considered the most dependable, cost-effective energy source in the world. The availability of these fuels to provide clean, affordable energy is essential for domestic and global prosperity and security well into the 21st century. However, a balance is needed between energy security and concerns over the impacts o