National Library of Energy BETA

Sample records for direct methanol fuel

  1. Air Breathing Direct Methanol Fuel Cell

    DOE Patents [OSTI]

    Ren; Xiaoming

    2003-07-22

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  2. Direct Methanol Fuel Cells - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Methanol Fuel Cells Los Alamos National Laboratory Contact LANL About This Technology Direct methanol fuel cells provide an alternative power source for mobile devices. Direct methanol fuel cells provide an alternative power source for mobile devices. Technology Marketing SummaryLANL has developed an intellectual property portfolio in Direct Methanol Fuel Cells that may permit companies to participate in the emerging DMFC market while minimizing R&D risks and expenditures. Our

  3. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  4. Methods of conditioning direct methanol fuel cells

    DOE Patents [OSTI]

    Rice, Cynthia; Ren, Xiaoming; Gottesfeld, Shimshon

    2005-11-08

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  5. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell ...

  6. Novel Materials for High Efficiency Direct Methanol Fuel Cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects ...

  7. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  8. Direct Methanol Fuel Cell Corporation DMFCC | Open Energy Information

    Open Energy Info (EERE)

    Methanol Fuel Cell Corporation DMFCC Jump to: navigation, search Name: Direct Methanol Fuel Cell Corporation (DMFCC) Place: Altadena, California Zip: 91001 Product: DMFCC is...

  9. Enhanced methanol utilization in direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2001-10-02

    The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

  10. Improved Direct Methanol Fuel Cell Stack

    SciTech Connect (OSTI)

    Wilson, Mahlon S.; Ramsey, John C.

    2005-03-08

    A stack of direct methanol fuel cells exhibiting a circular footprint. A cathode and anode manifold, tie-bolt penetrations and tie-bolts are located within the circular footprint. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet and outlet cathode manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold, where the serpentine channels of the anode are orthogonal to the serpentine channels of the cathode. Located between the two plates is the fuel cell active region.

  11. Direct methanol fuel cell and system

    DOE Patents [OSTI]

    Wilson, Mahlon S.

    2004-10-26

    A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

  12. Novel Materials for High Efficiency Direct Methanol Fuel Cells | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 roger_arkema_kickoff.pdf (394.12 KB) More Documents & Publications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Advance Patent Waiver W(A)2010-028 Durable, Low Cost, Improved Fuel Cell Membranes

  13. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the presentation slides from Arkema at the July 17, 2012, Fuel Cell Technologies Program webinar, "Fuel Cells for Portable Power." Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides (790.15 KB) More Documents & Publications

  14. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides More Documents & Publications Novel Materials for High Efficiency Direct ...

  15. Methods of Conditioning Direct Methanol Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Find More Like This Return to Search Methods of Conditioning Direct Methanol Fuel Cells Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode

  16. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 dinh-gennett_topic_5a_dmfc_nrel_kickoff.pdf (1.41 MB) More Documents & Publications Advanced Materials and Concepts for Portable Power Fuel Cells Introduction to DMFCs - Advanced Materials and Concepts for Portable Power Fuel Cells

  17. On direct and indirect methanol fuel cells for transportation applications

    SciTech Connect (OSTI)

    Ren, Xiaoming; Wilson, M.S.; Gottesfeld, S.

    1995-09-01

    Power densities in electrolyte Direct Methanol Fuel Cells have been achieved which are only three times lower than those achieved with similar reformate/air fuel cells. Remaining issues are: improved anode catalyst activity, demonstrated long-term stable performance, and high fuel efficiencies.

  18. Improved Flow-Field Structures for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Gurau, Bogdan

    2013-05-31

    The direct methanol fuel cell (DMFC) is ideal if high energy-density liquid fuels are required. Liquid fuels have advantages over compressed hydrogen including higher energy density and ease of handling. Although state-of-the-art DMFCs exhibit manageable degradation rates, excessive fuel crossover diminishes system energy and power density. Although use of dilute methanol mitigates crossover, the concomitant lowering of the gross fuel energy density (GFED) demands a complex balance-of-plant (BOP) that includes higher flow rates, external exhaust recirculation, etc. An alternative approach is redesign of the fuel delivery system to accommodate concentrated methanol. NuVant Systems Inc. (NuVant) will maximize the GFED by design and assembly of a DMFC that uses near neat methanol. The approach is to tune the diffusion of highly concentrated methanol (to the anode catalytic layer) to the back-diffusion of water formed at the cathode (i.e. in situ generation of dilute methanol at the anode layer). Crossover will be minimized without compromising the GFED by innovative integration of the anode flow-field and the diffusion layer. The integrated flow-field-diffusion-layers (IFDLs) will widen the current and potential DMFC operating ranges and enable the use of cathodes optimized for hydrogen-air fuel cells.

  19. High specific power, direct methanol fuel cell stack

    SciTech Connect (OSTI)

    Ramsey, John C.; Wilson, Mahlon S.

    2007-05-08

    The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

  20. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin; Zelenay, Piotr

    2006-03-21

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  1. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin; Zelenay, Piotr

    2006-09-05

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  2. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

    2013-12-31

    Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

  3. Recent advances in high-performance direct methanol fuel cells

    SciTech Connect (OSTI)

    Narayanan, S.R.; Chun, W.; Valdez, T.I.

    1996-12-31

    Direct methanol fuel cells for portable power applications have been advanced significantly under DARPA- and ARO-sponsored programs over the last five years. A liquid-feed direct methanol fuel cell developed under these programs, employs a proton exchange membrane as electrolyte and operates on aqueous solutions of methanol with air or oxygen as the oxidant. Power densities as high as 320 mW/cm{sup 2} have been demonstrated. Demonstration of five-cell stack based on the liquid-feed concept have been successfully performed by Giner Inc. and the Jet Propulsion Laboratory. Over 2000 hours of life-testing have been completed on these stacks. These fuel cells have been also been demonstrated by USC to operate on alternate fuels such as trimethoxymethane, dimethoxymethane and trioxane. Reduction in the parasitic loss of fuel across the fuel cell, a phenomenon termed as {open_quotes}fuel crossover{close_quotes} has been achieved using polymer membranes developed at USC. As a result efficiencies as high as 40% is considered attainable with this type of fuel cell. The state-of-development has reached a point where it is now been actively considered for stationary, portable and transportation applications. The research and development issues have been the subject of several previous articles and the present article is an attempt to summarize the key advances in this technology.

  4. Performance of direct methanol polymer electrolyte fuel cell

    SciTech Connect (OSTI)

    Shin, Dong Ryul; Jung, Doo Hwan; Lee, Chang Hyeong; Chun, Young Gab

    1996-12-31

    Direct methanol fuel cells (DMFC) using polymer electrolyte membrane are promising candidate for application of portable power sources and transportation applications because they do not require any fuel processing equipment and can be operated at low temperature of 60{degrees}C - 130{degrees}C. Elimination of the fuel processor results in simpler design, higher operation reliability, lower weight volume, and lower capital and operating cost. However, methanol as a fuel is relatively electrochemical inert, so that kinetics of the methanol oxidation is too slow. Platinum and Pt-based binary alloy electrodes have been extensively studied for methanol electro-oxidation in acid electrolyte at ambient and elevated temperatures. Particularly, unsupported carbon Pt-Ru catalyst was found to be superior to the anode of DMFC using a proton exchange membrane electrolyte (Nafion). The objective of this study is to develop the high performance DNTC. This paper summarizes the results from half cell and single cell tests, which focus on the electrode manufacturing process, catalyst selection, and operating conditions of single cell such as methanol concentration, temperature and pressure.

  5. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.; Gennett, T.

    2010-06-11

    This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

  6. Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing

    SciTech Connect (OSTI)

    Fletcher, James H.; Cox, Philip; Harrington, William J; Campbell, Joseph L

    2013-09-03

    ABSTRACT Project Title: Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing PROJECT OBJECTIVE The objective of the project was to advance portable fuel cell system technology towards the commercial targets of power density, energy density and lifetime. These targets were laid out in the DOE’s R&D roadmap to develop an advanced direct methanol fuel cell power supply that meets commercial entry requirements. Such a power supply will enable mobile computers to operate non-stop, unplugged from the wall power outlet, by using the high energy density of methanol fuel contained in a replaceable fuel cartridge. Specifically this project focused on balance-of-plant component integration and miniaturization, as well as extensive component, subassembly and integrated system durability and validation testing. This design has resulted in a pre-production power supply design and a prototype that meet the rigorous demands of consumer electronic applications. PROJECT TASKS The proposed work plan was designed to meet the project objectives, which corresponded directly with the objectives outlined in the Funding Opportunity Announcement: To engineer the fuel cell balance-of-plant and packaging to meet the needs of consumer electronic systems, specifically at power levels required for mobile computing. UNF used existing balance-of-plant component technologies developed under its current US Army CERDEC project, as well as a previous DOE project completed by PolyFuel, to further refine them to both miniaturize and integrate their functionality to increase the system power density and energy density. Benefits of UNF’s novel passive water recycling MEA (membrane electrode assembly) and the simplified system architecture it enabled formed the foundation of the design approach. The package design was hardened to address orientation independence, shock, vibration, and environmental requirements. Fuel cartridge and fuel subsystems were improved to ensure effective fuel

  7. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number: Arkema Inc. (1281) This presentation does not contain any proprietary, confidential, or otherwise restricted information Novel Materials for High Efficiency Direct Methanol ...

  8. Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications

    SciTech Connect (OSTI)

    Carlstrom, Charles, M., Jr.

    2009-07-07

    This report is the final technical report for DOE Program DE-FC36-04GO14301 titled “Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications”. Due to the public nature of this report some of the content reported in confidential reports and meetings to the DOE is not covered in detail in this report and some of the content has been normalized to not show actual values. There is a comparison of the projects accomplishments with the objectives, an overview of some of the key subsystem work, and a review of the three levels of prototypes demonstrated during the program. There is also a description of the eventual commercial product and market this work is leading towards. The work completed under this program has significantly increased the understanding of how Direct Methanol Fuel Cells (DMFC) can be deployed successfully to power consumer electronic devices. The prototype testing has demonstrated the benefits a direct methanol fuel cell system has over batteries typically used for powering consumer electronic devices. Three generations of prototypes have been developed and tested for performance, robustness and life. The technologies researched and utilized in the fuel cell stack and related subsystems for these prototypes are leveraged from advances in other industries such as the hydrogen fueled PEM fuel cell industry. The work under this program advanced the state of the art of direct methanol fuel cells. The system developed by MTI micro fuel cells aided by this program differs significantly from conventional DMFC designs and offers compelling advantages in the areas of performance, life, size, and simplicity. The program has progressed as planned resulting in the completion of the scope of work and available funding in December 2008. All 18 of the final P3 prototypes builds have been tested and the results showed significant improvements over P2 prototypes in build yield, initial performance, and durability. The systems have

  9. New Catalysts for Direct Methanol Oxidation Fuel Cells

    SciTech Connect (OSTI)

    Adzic, Radoslav

    1998-08-01

    A new class of efficient electrocatalytic materials based on platinum - metal oxide systems has been synthetized and characterized by several techniques. Best activity was found with NiWO{sub 4}-, CoWO{sub 4}-, and RuO{sub 2}- srpported platinum catalysts. A very similar activity at room temperature was observed with the electrodes prepared with the catalyst obtained from International Fuel Cells Inc. for the same Pt loading. Surprisingly, the two tungstates per se show a small activity for methanol oxidation without any Pt loading. Synthesis of NiWO{sub 4} and CoWO{sub 4} were carried out by solid-state reactions. FTIR spectroscopy shows that the tungstates contain a certain amount of physically adsorbed water even after heating samples at 200{degrees}C. A direct relationship between the activity for methanol oxidation and the amount of adsorbed water on those oxides has been found. The Ru(0001) single crystal shows a very small activity for CO adsorption and oxidation, in contrast to the behavior of polycrystalline Ru. In situ extended x-ray absorption fine structure spectroscopy (EXAFS) and x-ray absorption near edge spectroscopy (XANES) showed that the OH adsorption on Ru in the Pt-Ru alloy appears to be the limiting step in methanol oxidation. This does not occur for Pt-RuO{SUB 2} electrocatalyst, which explains its advantages over the Pt-Ru alloys. The IFCC electrocatalyst has the properties of the Pt-Ru alloy.

  10. SHAPE SELECTIVE NANOCATALYSTS FOR DIRECT METHANOL FUEL CELL APPLICATIONS

    SciTech Connect (OSTI)

    Murph, S.

    2012-09-12

    While gold and platinum have long been recognized for their beauty and value, researchers at the Savannah River National Laboratory (SRNL) are working on the nano-level to use these elements for creative solutions to our nation's energy and security needs. Multiinterdisciplinary teams consisting of chemists, materials scientists, physicists, computational scientists, and engineers are exploring unchartered territories with shape-selective nanocatalysts for the development of novel, cost effective and environmentally friendly energy solutions to meet global energy needs. This nanotechnology is vital, particularly as it relates to fuel cells.SRNL researchers have taken process, chemical, and materials discoveries and translated them for technological solution and deployment. The group has developed state-of-the art shape-selective core-shell-alloy-type gold-platinum nanostructures with outstanding catalytic capabilities that address many of the shortcomings of the Direct Methanol Fuel Cell (DMFC). The newly developed nanostructures not only busted the performance of the platinum catalyst, but also reduced the material cost and overall weight of the fuel cell.

  11. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol as an alternative transportation fuel in the US: Options for sustainable and/or energy-secure transportation L. Bromberg and W.K. Cheng Prepared by the Sloan Automotive Laboratory Massachusetts Institute of Technology Cambridge MA 02139 September 27, 2010 Finalized November 2, 2010 Revised November 28, 2010 Final report UT-Battelle Subcontract Number:4000096701 1 Abstract Methanol has been promoted as an alternative transportation fuel from time to time over the past forty years. In

  12. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Wensheng He, David Mountz, Tao Zhang, Chris Roger July 17, 2012 2 Outline Background on Arkema's polyvinylidene fluoride (PVDF) blend membrane technology Overview of membrane properties and performance Summary 3 Membrane Technology Polymer Blend * Kynar ® PVDF * Chemical and electrochemical stability * Mechanical strength * Excellent barrier against methanol * Polyelectrolyte * H + conduction and water uptake

  13. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Rossmeisl, Jan; Ferrin, Peter A.; Tritsaris, Georgios A.; Nilekar, Anand U.; Koh, Shirlaine; Bae, Sang Eun; Brankovic, Stanko R.; Strasser, Peter; Mavrikakis, Manos

    2012-06-13

    Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties: (1) the ability to activate methanol, (2) the ability to activate water, and (3) the ability to react off surface intermediates (such as CO* and OH*). Based on this analysis, an alloy catalyst made up of Cu and Pt should have a synergistic effect facilitating the activity towards methanol electro-oxidation. Using these two reactivity descriptors, a surface PtCu3 alloy is proposed to have the best catalytic properties of the PtCu model catalysts tested, similar to those of a PtRu bulk alloy. To validate the model, experiments on a Pt(111) surface modified with different amounts of Cu adatoms are performed. Adding Cu to a Pt(111) surface increases the methanol oxidation current by more than a factor of three, supporting our theoretical predictions for improved electrocatalysts.

  14. Polymer electrolyte direct methanol fuel cells: an option for transportation applications

    SciTech Connect (OSTI)

    Gottesfeld, S.; Cleghorn, S.J.C.; Ren, X.; Springer, T.E.; Wilson, M.S.; Zawodzinski, T.A.

    1996-10-01

    PEFCs most frequently considered for electric vehicles have been based on either hydrogen carried aboard, or steam-reforming of methanol on board to produce H2 + CO2. Direct methanol fuel cells (DMFCs), which use a liquid methanol fuel feed, completely avoid the complexity and weight penalties of the reformer, but have not been considered a serious option until recently, because of much lower power densities. Recent advances in DMFCs have been dramatic, however, with the DMFC reaching power densities which are significant fractions of those provided by reformate/air fuel cells. Use of established Pt-Ru anode electrocatalysts and Pt cathode electrocatalysts in polymer electrolyte DMFCs has resulted in enhanced DMFC performance, particularly when operated above 100 C and when catalyst layer composition and structure are optimized. The higher DMFC power densities recently achieved provide a new basis for considering DMFCs for transportation applications.

  15. The effect of operation and design parameters on the performance of the direct methanol fuel cell

    SciTech Connect (OSTI)

    Simpson, S.F.; Cisar, A.; Franaszczuk, K.

    1996-12-31

    Fuel cell technology continues to receive considerable attention as a potential replacement for fossil fuels as a primary source of terrestrial power. Ideally, such power systems would operate at relatively low temperatures (< 100{degrees}C) which suggests strongly the use of cell technology based upon the proton exchange membrane (PEM). Without question, hydrogen is a very desirable fuel choice for these types of systems, because of its high energy density. However, the difficulties associated with the production and routine handling of hydrogen limit severely its commercial use at present. The direct methanol fuel cell (DMFC) is a particularly attractive alternative to the use of the hydrogen/oxygen cell. Although not as high as hydrogen, the energy density of methanol is the highest among the organic fuels. Furthermore, because of the similarity in liquid handling requirements between methanol and gasoline, a significant portion of the infrastructure necessary for the marketing and distribution of the fuel is already in place. Other inherent attributes of the DMFC which include rapid start-up and operation with little or no emission or noise signature have led to an intense DMFC research effort over the past twenty years and, indeed, the DMFC has even been referred to as {open_quotes}the electrochemist`s dream{close_quotes}.

  16. Alternative Fuels Data Center: Methanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Methanol to someone by E-mail Share Alternative Fuels Data Center: Methanol on Facebook Tweet about Alternative Fuels Data Center: Methanol on Twitter Bookmark Alternative Fuels Data Center: Methanol on Google Bookmark Alternative Fuels Data Center: Methanol on Delicious Rank Alternative Fuels Data Center: Methanol on Digg Find More places to share Alternative Fuels Data Center: Methanol on AddThis.com... More in this section... Biobutanol Dimethyl Ether Methanol Renewable Hydrocarbon Biofuels

  17. X-ray absorption and electrochemical studies of direct methanol fuel cell catalysts

    SciTech Connect (OSTI)

    Zurawski, D.J.; Aldykiewicz, A.J. Jr.; Baxter, S.F.; Krumpelt, M.

    1996-12-31

    In order for polymer electrolyte fuel cells to operate directly on methanol instead of hydrogen, a distinct advantage for portable applications, methanol oxidation must be catalyzed effectively in the acidic environment of the cell. Platinum-ruthenium and platinum-ruthenium oxide are generally considered to be the most active catalysts for this purpose. The presence of ruthenium significantly enhances the activity of platinum in these catalysts, for reasons not yet fully understood. We are using X-ray absorption spectroscopy (XAS) and electrochemical techniques to evaluate the mechanisms proposed to account for this enhancement in order to further improve the catalyst`s activity. We are considering three enhancement mechanisms. An intermediate in the oxidation of methanol on platinum is carbon monoxide and its oxidation is the rate-determining step in the overall oxidation mechanism. It has been proposed that ruthenium facilitates the removal of carbon monoxide from the platinum surface. First, it has been proposed that ruthenium decreases the strength of the platinum-carbon monoxide bond. Carbon monoxide bonds to the catalyst by interacting with the d-band of platinum, therefore a change in the d-band occupancy of platinum as a result of alloying may influence the bond strength of carbon monoxide. Another proposed enhancement mechanism involves lowering of the potential for the formation of the CO-oxidizing species. Finally, the binary catalysts may have a structure which is more conducive to the methanol dehydrogenation and carbon monoxide reactions. Based on these three proposed enhancement mechanisms, a goal of this study is to correlate catalyst electronic properties, structure, and oxidation state with the performance of proton-exchange membrane (Nafion) direct methanol fuel cells.

  18. Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology

    DOE Patents [OSTI]

    Cornelius, Christopher J.

    2006-04-04

    A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

  19. TUNING OF SIZE AND SHAPE OF AU-PT NANOCATALYST FOR DIRECT METHANOL FUEL CELLS

    SciTech Connect (OSTI)

    Murph, S.

    2011-04-20

    In this paper, we report the precise control of the size, shape and surface morphology of Au-Pt nanocatalysts (cubes, blocks, octahedrons and dogbones) synthesized via a seed-mediated approach. Gold 'seeds' of different aspect ratios (1 to 4.2), grown by a silver-assisted approach, were used as templates for high-yield production of novel Au-Pt nanocatalysts at a low temperature (40 C). Characterization by electron microscopy (SEM, TEM, HRTEM), energy dispersive X-ray analysis (EDX), UV-Vis spectroscopy, zeta-potential (surface charge), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS) were used to better understand their physico-chemical properties, preferred reactivities and underlying nanoparticle growth mechanism. A rotating disk electrode was used to evaluate the Au-Pt nanocatalysts electrochemical performance in the oxygen reduction reaction (ORR) and the methanol oxidation reaction (MOR) of direct methanol fuel cells. The results indicate the Au-Pt dogbones are partially and in some cases completely unaffected by methanol poisoning during the evaluation of the ORR. The ORR performance of the octahedron particles in the absence of MeOH is superior to that of the Au-Pt dogbones and Pt-black, however its performance is affected by the presence of MeOH.

  20. Methanol as a fuel for commercial vehicles

    SciTech Connect (OSTI)

    Heinrich, W.; Marquardt, K.J.; Schaefer, A.J.

    1986-01-01

    This paper discusses two possibilities for using methanol in heavy-duty engines. If the engine is modified according to the fuel properties, pure methanol can be used as fuel for a spark ignition methanol-gas engine. When the fuel is adapted to meet the requirements of the engine additized methanol serves as a fuel for an only slightly modified direct-injection diesel engine. The comparison takes into consideration fuel cost, convertibility of vehicles already in use, operational safety and reliability, requirements regarding fuel production and distribution, conventional fuel/alternative fuel reversibility, and environmental aspects.

  1. SHAPE SELECTIVE NANO-CATALYSTS: TOWARD DIRECT METHANOL FUEL CELLS APPLICATIONS

    SciTech Connect (OSTI)

    Murph, S.

    2010-06-16

    A series of bimetallic core-shell-alloy type Au-Pt nanomaterials with various morphologies, aspect ratios and compositions, were produced in a heterogenous epitaxial fashion. Gold nanoparticles with well-controlled particle size and shape, e.g. spheres, rods and cubes, were used as 'seeds' for platinum growth in the presence of a mild reducing agent, ascorbic acid and a cationic surfactant cethyltrimethyl ammonium bromide (CTAB). The reactions take place in air and water, and are quick, economical and amenable for scaling up. The synthesized nanocatalysts were characterized by electron microscopy techniques and energy dispersive X-ray analysis. Nafion membranes were embedded with the Au-Pt nanomaterials and analyzed by atomic force microscopy (AFM) and scanning electron microscopy (SEM) for their potential in direct methanol fuel cells applications.

  2. Catalyst inks and method of application for direct methanol fuel cells

    DOE Patents [OSTI]

    Zelenay, Piotr; Davey, John; Ren, Xiaoming; Gottesfeld, Shimshon; Thomas, Sharon C.

    2004-02-24

    Inks are formulated for forming anode and cathode catalyst layers and applied to anode and cathode sides of a membrane for a direct methanol fuel cell. The inks comprise a Pt catalyst for the cathode and a Pt--Ru catalyst for the anode, purified water in an amount 4 to 20 times that of the catalyst by weight, and a perfluorosulfonic acid ionomer in an amount effective to provide an ionomer content in the anode and cathode surfaces of 20% to 80% by volume. The inks are prepared in a two-step process while cooling and agitating the solutions. The final solution is placed in a cooler and continuously agitated while spraying the solution over the anode or cathode surface of the membrane as determined by the catalyst content.

  3. Analysis of the electrochemical characteristics of a direct methanol fuel cell based on a Pt-Ru/C anode catalyst

    SciTech Connect (OSTI)

    Arico, A.S.; Creti, P.; Mantegna, R.

    1996-12-31

    This paper deals with a vapour-feed direct methanol fuel cell (DMFC) based on a Nafion 117{reg_sign} solid polymer electrolyte. Pt-Ru/C and Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Structure and surface chemistry of catalysts were investigated by X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Membrane/electrode assembly (M&E) was prepared by using a {open_quotes}paste process{close_quotes} method. Electrical power densities of about 150 mW cm{sup -2} were obtained at 95{degrees} C with Pt loadings of 0.8 and 0.5 mg cm{sup -2} at anode and cathode respectively.

  4. The Development of Methanol Industry and Methanol Fuel in China

    SciTech Connect (OSTI)

    Li, W.Y.; Li, Z.; Xie, K.C.

    2009-07-01

    In 2007, China firmly established itself as the driver of the global methanol industry. The country became the world's largest methanol producer and consumer. The development of the methanol industry and methanol fuel in China is reviewed in this article. China is rich in coal but is short on oil and natural gas; unfortunately, transportation development will need more and more oil to provide the fuel. Methanol is becoming a dominant alternative fuel. China is showing the rest of the world how cleaner transportation fuels can be made from coal.

  5. Effects of piston surface treatments on performance and emissions of a methanol-fueled, direct injection, stratified charge engine

    SciTech Connect (OSTI)

    West, B.; Green, J.B.

    1994-07-01

    The purpose of this study was to investigate the effects of thermal barrier coatings and/or surface treatments on the performance and emissions of a methanol-fueled, direct-injection, stratified-charge (DISC) engine. A Ricardo Hydra Mark III engine was used for this work and in previous experiments at Oak Ridge National Laboratory (ORNL). The primary focus of the study was to examine the effects of various piston insert surface treatments on hydrocarbon (HC) and oxides of nitrogen (NO{sub x}) emissions. Previous studies have shown that engines of this class have a tendency to perform poorly at low loads and have high unburned fuel emissions. A blank aluminum piston was modified to employ removable piston bowl inserts. Four different inserts were tested in the experiment: aluminum, stainless steel with a 1.27-mm (0.050-in.) air gap (to act as a thermal barrier), and two stainless steel/air-gap inserts with coatings. Two stainless steel inserts were dimensionally modified to account for the coating thickness (1.27-mm) and coated identically with partially stabilized zirconia (PSZ). One of the coated inserts then had an additional seal-coat applied. The coated inserts were otherwise identical to the stainless steel/air-gap insert (i.e., they employed the same 1.27-mm air gap). Thermal barrier coatings were employed in an attempt to increase combustion chamber surface temperatures, thereby reducing wall quenching and promoting more complete combustion of the fuel in the quench zone. The seal-coat was applied to the zirconia to reduce the surface porosity; previous research suggested that despite the possibly higher surface temperatures obtainable with a ceramic coating, the high surface area of a plasma-sprayed coating may actually allow fuel to adhere to the surface and increase the unburned fuel emissions and fuel consumption.

  6. Direct Methanol Fuel Cell Power Supply For All-Day True Wireless Mobile Computing

    SciTech Connect (OSTI)

    Brian Wells

    2008-11-30

    PolyFuel has developed state-of-the-art portable fuel cell technology for the portable computing market. A novel approach to passive water recycling within the MEA has led to significant system simplification and size reduction. Miniature stack technology with very high area utilization and minimalist seals has been developed. A highly integrated balance of plant with very low parasitic losses has been constructed around the new stack design. Demonstration prototype systems integrated with laptop computers have been shown in recent months to leading OEM computer manufacturers. PolyFuel intends to provide this technology to its customers as a reference design as a means of accelerating the commercialization of portable fuel cell technology. The primary goal of the project was to match the energy density of a commercial lithium ion battery for laptop computers. PolyFuel made large strides against this goal and has now demonstrated 270 Wh/liter compared with lithium ion energy densities of 300 Wh/liter. Further, more incremental, improvements in energy density are envisioned with an additional 20-30% gains possible in each of the next two years given further research and development.

  7. Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion

    SciTech Connect (OSTI)

    Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

    2012-08-14

    We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

  8. Investigation of methanol oxidation on a highly active and stable Pt–Sn electrocatalyst supported on carbon–polyaniline composite for application in a passive direct methanol fuel cell

    SciTech Connect (OSTI)

    Amani, Mitra; Kazemeini, Mohammad; Hamedanian, Mahboobeh; Pahlavanzadeh, Hassan; Gharibi, Hussein

    2015-08-15

    Highlights: • PtSn/C-PANI performed superior in the MOR compared with a commercial PtRu/C. • Catalytic activity of PtRu/C was highly reduced during the accelerated durability test. • Anode of the PtSn/C-PANI in a passive DMFC lowered methanol crossover by 30%. - Abstract: Polyaniline fiber (PANI) was synthesized and utilized to fabricate a vulcan–polyaniline (C-PANI) composite. Pt/C-PANI and PtSn/C-PANI electro-catalysts with different Pt:Sn atomic ratios were prepared by the impregnation method. These electro-catalysts, along with commercial PtRu/C (Electrochem), were characterized with respect to their structural and electrochemical properties in methanol oxidation reaction (MOR). PtSn(70:30)/C-PANI showed excellent performance in MOR, the obtained maximum current density being about 40% and 50% higher than that for PtRu/C and Pt/C-PANI, respectively. It was also found that the CO tolerance and stability of PtSn(70:30)/C-PANI was considerably higher than that of PtRu/C. Finally, the performance of these two materials was compared in a passive direct methanol fuel cell (DMFC). The DMFC test results demonstrated that the membrane electrode assembly (MEA) prepared using PtSn(70:30)/C-PANI anode catalyst performed more satisfactorily in terms of maximum power density and lower methanol crossover.

  9. Comparison of Pt-based binary and ternary alloy anode catalysts for polymer electrolyte direct methanol fuel cells

    SciTech Connect (OSTI)

    Liu, R.; Ley, K.L.; Pu, C.

    1996-12-31

    As an anode catalyst, Pt is highly active for the adsorption and dehydrogenation of methanol, however, the surface is poisoned by CO. To oxidize CO to CO{sub 2}, a second oxygen atom is required from an adjacent adsorbed water molecule. Bifunctional alloys composed of Pt and a second metal M, able to activate H{sub 2}O (forming -OH{sub ads}) at low potentials, are candidate materials for methanol electro-oxidation catalysts A proposed mechanism is: Figure 2 shows that metals which enhance methanol oxidation activity when alloyed with Pt have similar M-O bond strengths (see bold print), suggesting that the best binary alloy catalysts have second metals that are optimized with respect to the ability to oxidatively adsorb water. and the ability to dissociate M-O bonds to yield CO{sub 2}.

  10. Methanol-fueled transit bus demonstration

    SciTech Connect (OSTI)

    Jackson, M.D.; Fong, D.W.; Powars, C.A.; Smith, K.D.

    1983-01-01

    This paper summarizes the results of a California study to investigate the technical, environmental, and economic viability of using coal-derived fuels for transportation. Since nearly all of California's major urban areas have pollution problems, emphasis is placed on those options which are capable of achieving low exhaust emissions. A broad range of fuels are considered, including solids, gases, and liquids. Methanol, used in heavy-duty engines designed for this fuel, meets California's environmental, economic, and technical requirements for clean coal fuels. The combination has lower exhaust emissions than conventional Diesels -- smoke is eliminated and NO/SUB x/ and CO emissions are reduced. Further, thermal efficiencies comparable or exceeding conventional Diesels are possible. A demonstration of this new technology is now underway. Transit buses will be purchased with the objective of demonstrating alternative methanol engine designs. Economic viability in transit operations will be established.

  11. Removal of sulfur contaminants in methanol for fuel cell applications

    SciTech Connect (OSTI)

    Lee, S.H.D.; Kumar, R.; Sederquist, R.

    1996-12-31

    Fuel cell power plants are being developed for transit bus and passenger car applications that use methanol as the on-board fuel. Commodity methanol by itself contains very little sulfur; however, it may occasionally be contaminated with up to about 1% diesel fuel or gasoline in current liquid-fuel distribution systems, leading to the presence of sulfur in the methanol fuel. This sulfur must be removed because of its deleterious effect on the reforming catalysts. International Fuel Cells has set the allowable sulfur limit in the methanol fuel at less than 1 ppm. The equilibrium adsorption isotherm and breakthrough data were used to assess the feasibility of developing a granular activated carbon adsorber for the removal of sulfur from transportation fuel cell systems.

  12. NREL Teams with Industry to Validate Methanol Fuel Cell Technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Teams with Industry to Validate Methanol Fuel Cell Technology February 18, 2011 The ... The total cost of the project is just over 2 million; NREL will contribute 900,000 to ...

  13. Low contaminant formic acid fuel for direct liquid fuel cell

    DOE Patents [OSTI]

    Masel, Richard I.; Zhu, Yimin; Kahn, Zakia; Man, Malcolm

    2009-11-17

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  14. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  15. DME: The next market breakthrough or a methanol-related fuel

    SciTech Connect (OSTI)

    Gradassi, M.J.; Basu, A.; Fleisch, T.H.; Masin, J.G.

    1995-12-31

    Amoco has been involved for several years in the development of technology for the synthesis of liquid fuels from remote natural gas. In a recent collaborative work with Haldor Topsoe S/A, AVL LIST GmbH and Navistar, Amoco identified Dimethyl Ether (DME) as a new, ultraclean alternative fuel for diesel engines. DME can be handled like liquefied petroleum gas (LPG), itself an important alternative transportation fuel. However, unlike most other fuels, the raw exhaust of diesel engines fueled with DME satisfies California 1998 ULEV (Ultra Low Emission Vehicle) standards, now. DME`s greenhouse gas emissions, measured from cradle-to-grave, are lowest among all transportation fuel alternatives. Today, DME is manufactured from methanol and is used primarily as an aerosol propellant because of its attractive physical properties and its environmentally benign characteristics. Haldor Topsoe S/A developed a process for the direct production of DME from natural gas. The process can be used for the large scale manufacture of DME using predominantly single-train process units. When manufactured at large scale, DME can be produced and marketed at a cost comparable to conventional transportation fuels. The market driven demand for DME as a transportation fuel is envisioned to grow in three stages. Initially, DME is envisioned to be produced via methanol dehydration, followed by retrofits, and lastly by large scale dedicated plants. DME fuel demonstration fleet tests are scheduled to commence during 1996. Today`s methanol producer likely also will be tomorrow`s DME producer.

  16. Development of a bench scale test to evaluate lubricants for use with methanol-fueled engines

    SciTech Connect (OSTI)

    Shah, R.; Klaus, E.; Duda, J.L.

    1996-10-01

    In methanol-fueled diesel engines, the crankcase lubricant is used to lubricate both the engine and the fuel injector system. Crankcase lubricants including some designed for methanol-fueled engines are not completely compatible with the methanol fuel. In order to test the effect of methanol extraction on diesel engine lubricant performance, two extraction protocols were developed: one to simulate the fuel injector (1000 parts of methanol to one part of lubricant) and the other to simulate an extreme case of methanol contamination in the crank-case (one part of methanol to five parts of lubricant). The extracted samples of the lubricant were stripped to remove the methanol. The samples were then evaluated for changes in oxidative stability and lubricity. 12 refs., 3 figs., 8 tabs.

  17. Fuel and power coproduction: The Liquid Phase Methanol (LPMEOH{trademark}) process demonstration at Kingsport

    SciTech Connect (OSTI)

    Drown, D.P.; Brown, W.R.; Heydorn, E.C.; Moore, R.B.; Schaub, E.S.; Brown, D.M.; Jones, W.C.; Kornosky, R.M.

    1997-12-31

    The Liquid Phase Methanol (LPMEOH{trademark}) process uses a slurry bubble column reactor to convert syngas (primarily a mixture of carbon monoxide and hydrogen) to methanol. Because of its superior heat management, the process is able to be designed to directly handle the carbon monoxide (CO)-rich syngas characteristic of the gasification of coal, petroleum coke, residual oil, wastes, or of other hydrocarbon feedstocks. When added to an integrated gasification combined cycle (IGCC) power plant, the LPMEOH{trademark} process converts a portion of the CO-rich syngas produced by the gasifier to methanol, and the remainder of the unconverted gas is used to fuel the gas turbine combined-cycle power plant. The LPMEOH{trademark} process has the flexibility to operate in a daily electricity demand load-following manner. Coproduction of power and methanol via IGCC and the LPMEOH{trademark} process provides opportunities for energy storage for electrical demand peak shaving, clean fuel for export, and/or chemical methanol sales.

  18. Aldehyde and unburned fuel emission measurements from a methanol-fueled Texaco stratified charge engine

    SciTech Connect (OSTI)

    Kim, C.; Foster, D.E.

    1985-04-01

    A Texaco L-163S TCCS (Texaco Controlled Combustion System) engine was operated with pure methanol to investigate the origin of unburned fuel (UBF) and formaldehyde emissions. Both continuous and time-resolved exhaust gas sampling methods were used to measure UBF and formaldehyde concentrations. Fuel impingement is believed to be an additional source of UBF emissions from this methanol-fueled TCCS engine. At increased load we believe that it is the primary source of the UBF emissions. Formaldehyde emissions were found to originate in the cylinder gases, especially at low load. However the formation of aldehydes in the exhaust port after leaving the cylinder does occur and becomes more important as the load increases. Increasing the engine load resulted in a decrease in UBF emissions but in most cases increased the formaldehyde emissions. Increased engine speed resulted in slightly increased UBF and formaldehyde emissions.

  19. Methanol as an alternative transportation fuel in the U.S.

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Methanol as an alternative transportation fuel in the US: Options for sustainable and/or energy-secure transportation L. Bromberg and W.K. Cheng Prepared by the Sloan Automotive Laboratory Massachusetts Institute of Technology Cambridge MA 02139 September 27, 2010 Finalized November 2, 2010 Revised November 28, 2010 Final report UT-Battelle Subcontract Number:4000096701 1 Abstract Methanol has been promoted as an alternative transportation fuel from time to time over the past forty years. In

  20. The Methanol Economy Project

    SciTech Connect (OSTI)

    Olah, George; Prakash, G. K.

    2014-02-01

    The Methanol Economy Project is based on the concept of replacing fossil fuels with methanol generated either from renewable resources or abundant natural (shale) gas. The full methanol cycle was investigated in this project, from production of methanol through bromination of methane, bireforming of methane to syngas, CO2 capture using supported amines, co-electrolysis of CO2 and water to formate and syngas, decomposition of formate to CO2 and H2, and use of formic acid in a direct formic acid fuel cell. Each of these projects achieved milestones and provided new insights into their respective fields.

  1. Fuel processor for fuel cell power system. [Conversion of methanol into hydrogen

    DOE Patents [OSTI]

    Vanderborgh, N.E.; Springer, T.E.; Huff, J.R.

    1986-01-28

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  2. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  3. Fuel Cell System Challenges Utilizing Natural Gas and Methanol

    Broader source: Energy.gov (indexed) [DOE]

    Smarter Solutions for a Clean Energy Future Fuel Cell System Challenges Utilizing Natural Gas ... fuel processing hardware and system integration March 19, 2014 2 NASDAQ:BLDP TSX:BLD ...

  4. Methanol with dimethyl ether ignition promotor as fuel for compression ignition engines

    SciTech Connect (OSTI)

    Brook, D.L.; Cipolat, D.; Rallis, C.J.

    1984-08-01

    Reduction of the world dependence upon crude oil necessitates the use of long term alternative fuels for internal combustion engines. Alcohols appear to offer a solution as in the short term they can be manufactured from natural gas and coal, while ultimately they may be produced from agricultural products. A fair measure of success has been achieved in using alcohols in spark ignition engines. However the more widely used compression ignition engines cannot utilize unmodified pure alcohols. The current techniques for using alcohol fuels in compression ignition engines all have a number of shortcomings. This paper describes a novel technique where an ignition promotor, dimethyl ether (DME), is used to increase the cetane rating of methanol. The systems particular advantage is that the DME can be catalyzed from the methanol base fuel, in situ. This fuel system matches the performance characteristics of diesel oil fuel.

  5. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  6. FTP Emissions Test Results from Flexible-Fuel Methanol Dodge Spirits and Ford Econoline Vans

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    FTP Emissions Test Results from Flexible-Fuel Methanol Dodge Spirits and Ford Econoline Vans Kenneth J. Kelly, Brent K. Bailey, and Timothy C. Coburn National Renewable Energy Laboratory Wendy Clark Automotive Testing Laboratories, Inc. Leslie Eudy ManTech Environmental Technology, Inc. Peter Lissiuk Environmental Research and Development Corp. Presented at Society for Automotive Engineers International Spring Fuels and Lubricants Meeting Dearborn, MI May 6-8, 1996 The work described here was

  7. DAVID Fuel Cell Components SL | Open Energy Information

    Open Energy Info (EERE)

    manufacture and marketing of components and devices for PEM fuel cells, direct methanol fuel cells (DMFC) and fuel reformers. References: DAVID Fuel Cell Components SL1...

  8. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  9. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  10. Evaluation of a methanol-fueled (M85) turbocharged nissan sentra. Technical report

    SciTech Connect (OSTI)

    Blair, D.M.

    1988-05-01

    Section 211 of the Clean Air Act requires that the United States Environmental Protection Agency (EPA) play a key role in the introduction of new motor-vehicle fuels. The Emission Control Technology Division (ECTD), of the Office of Mobile Sources, EPA assesses technology that could be used to reduce mobile source emissions, including evaluation of alternate-fueled vehicles. A turbocharged Nissan Sentra was emission tested at the U.S. EPA Motor Vehicle Emissions Laboratory located in Ann Arbor, Michigan. This vehicle was designed by Nissan to operate on M85 (85% methanol/15% gasoline) fuel. The vehicle's chassis is a late-1986 configuration while the engine is based on a 1983 1.3-liter design. The report includes individual test results using methanol-vehicle procedures, calculation of exhaust emissions, and individual test results using gasoline-vehicle procedures.

  11. Early Markets: Fuel Cells for Material Handling Equipment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MHE can use Polymer Electrolyte Membrane (PEM) fuel cell systems, which can be fueled with hydrogen, or by using methanol in Direct Methanol Fuel Cells (DMFCs). The Case for Fuel ...

  12. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  13. Methanol as a fuel for a lean turbocharged spark ignition engine

    SciTech Connect (OSTI)

    Pannone, G.M.; Johnson, R.T.

    1989-01-01

    Lean turbocharged operation with methanol was characterized using a single-cylinder spark, ignition engine. Efficiency, exhaust emissions, and combustion properties were measured over a range of air/fuel ratios at two naturally-aspirated and three turbocharged conditions. When compared to stoichiometric, naturally-aspirated operation, the lean turbocharged conditions improved efficiency while reducing carbon monoxide and oxides of nitrogen emissions. However, unburned fuel and aldehyde emissions increased. If used in conjunction with an oxidizing catalyst and appropriate feedback controls, lean turbocharged operation has the potential of improving efficiency and exhaust emissions performance over a stoichiometric, three-way catalyst system.

  14. The use of dimethyl ether as a starting aid for methanol-fueled SI engines at low temperatures

    SciTech Connect (OSTI)

    Kozole, K.H.; Wallace, J.S

    1988-01-01

    Methanol-fueled SI engines have proven to be difficult to start at ambient temperatures below approximately 10/sup 0/C. The use of dimethyl ether (DME) is proposed to improve the cold starting performance of methanol-fueled SI engines. Tests to evaluate this idea were carried out with a modified single-cylinder CFR research engine having a compression ratio of 12:1. The engine was fueled with combinations of gaseous dimethyl ether and liquid methanol having DME mass fractions of 30%, 40%, 60% and 70%. For comparison, tests were also carried out with 100% methanol and with winter grade premium unleaded gasoline. Overall stoichiometric mixtures were used in all tests.

  15. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-06-30

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  16. Micro fuel cell

    SciTech Connect (OSTI)

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  17. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... SEM images of Pt nanoparticles on: (a) undoped, (b) Ar-doped and (c) N-doped HOPG; (d) particle diameter distribution of Pt nanoparticles on undoped,,Ar- and N- HOPG; (e) nearest ...

  18. Decision guide to farm fuel production: ethanol, methanol, or vegetable oils

    SciTech Connect (OSTI)

    Kerstetter, J.D.

    1984-09-01

    The purpose of this paper is to inform farmers of the choices they have today regarding production of motor vehicle fuels. Its intent is to inform farmers of what is involved in producing an alternative fuel, its compatibility with existing engines, the costs involved, and the markets for the fuel and any by-products. This paper is not a how-to-do-it manual or a policy document. Some of the data has been developed from the Appropriate Technology Small Grants Program managed by the Washington State Energy Office. Part One provides background information on Washington's fuel use patterns, highlighting the agricultural sector. In Part Two, general considerations common to all alternative fuels are covered. Part Three contains three detailed discussions of the alternative fuels most favored by Washington farmers for production and use - ethanol, vegetable oils, and methanol. The Appendix contains a brief summary of the 11 ethanol projects in Washington funded as a result of the Appropriate Technology Small Grants Program. 5 references, 12 figures, 2 tables.

  19. Durable Low Cost Improved Fuel Cell Membranes | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Durable, Low Cost, Improved Fuel Cell Membranes Novel Materials for High Efficiency Direct ...

  20. Comparison of unburned fuel and aldehyde emissions from a methanol-fueled stratified charge and homogeneous charge engine

    SciTech Connect (OSTI)

    Scull, N.; Kim, C.; Foster, D.E.

    1986-01-01

    This paper presents the results of an experimental program in which a Texaco L-163S engine was fueled with methanol and operated in its traditional stratified charge mode and then modified to run as a homogenous charge spark ignited engine. The primary data taken were the aldehyde and unburned fuel emissions (UBF). These data were taken using a continuous time-averaging sampling probe at the exhaust tank and at the exhaust port and with a rotary time-resolving sampling valve located at the exhaust port. The data indicate that for both the stratified charge and the homogeneous charge modes of operation formaldehyde was the only aldehyde detected in the exhaust and it primarily originated in the cylinder.

  1. A comparison of unburned fuel and aldehyde emissions from a methanol-fueled stratified charge and homogeneous charge engine

    SciTech Connect (OSTI)

    Foster, D.E.; Kim, C.; Scull, N.

    1987-03-01

    This paper presents the results of an experimental program in which a Texaco L-163S engine was fueled with methanol and operated in its traditional stratified charge mode and then modified to run as a homogeneous charge spark ignited engine. The primary data taken were the aldehyde and unburned fuel emissions (UBF). Those data were taken using a continuous time-averaging sampling probe at the exhaust tank and at the exhaust port and with a rotary time-resolving sampling valve located at the exhaust port. The data are for two loads, 138.1 kPa (20 psi) and 207.1 kPa (30 psi) BMEP and three speeds, 1000, 1400 and 1800 rpm. The data indicate that both the stratified charge and the homogeneous charge modes of operation formaldehyde was the only aldehyde detected in the exhaust and it primarily originated in the exhaust and it primarily originated in the cylinder. Over the load and speed ranges tested, the unburned fuel emission were higher and the formaldehyde emission lower when comparing the stratified charge to the homogeneous charge operation. Time resolved data at the exhaust port for the two modes of operation are compared. The homogeneous charge operation had a uniform concentration of both unburned fuel and formaldehyde over the exhaust stroke. The stratified charge data shows large changes in the unburned fuel and moderate changes in the aldehyde concentrations during the exhaust stroke.

  2. Chrysler Pentastar direct hydrogen fuel cell program

    SciTech Connect (OSTI)

    Kimble, M.; Deloney, D.

    1995-08-01

    The Chrysler Pentastar Electronics, Inc. Direct Hydrogen Fueled PEM Fuel Cell Hybrid Vehicle Program (DPHV) was initiated 1 July, 1994 with the following mission, {open_quotes}Design, fabricate, and test a Direct Hydrogen Fueled Proton Exchange Membrane (PEM) Fuel Cell System including onboard hydrogen storage, an efficient lightweight fuel cell, a gas management system, peak power augmentation and a complete system controls that can be economically mass produced and comply with all safety environmental and consumer requirements for vehicle applications for the 21st century.{close_quotes} The Conceptual Design for the entire system based upon the selection of an applicable vehicle and performance requirements that are consistent with the PNGV goals will be discussed. A Hydrogen Storage system that has been selected, packaged, and partially tested in accordance with perceived Hydrogen Safety and Infrastructure requirements will be discussed in addition to our Fuel Cell approach along with design of the {open_quotes}real{close_quotes} module. The Gas Management System and the Load Leveling System have been designed and the software programs have been developed and will be discussed along with a complete fuel cell test station that has the capability to test up to a 60 kW fuel cell system.

  3. DIRECT FUEL/CELL/TURBINE POWER PLANT

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2004-05-01

    This report includes the progress in development of Direct FuelCell/Turbine{reg_sign} (DFC/T{reg_sign}) power plants for generation of clean power at very high efficiencies. The DFC/T power system is based on an indirectly heated gas turbine to supplement fuel cell generated power. The DFC/T power generation concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, 60% on coal gas, minimal emissions, simplicity in design, direct reforming internal to the fuel cell, reduced carbon dioxide release to the environment, and potential cost competitiveness with existing combined cycle power plants. FCE successfully completed testing of the pre-alpha DFC/T hybrid power plant. This power plant was constructed by integration of a 250kW fuel cell stack and a microturbine. The tests of the cascaded fuel cell concept for achieving high fuel utilizations were completed. The tests demonstrated that the concept results in higher power plant efficiency. Also, the preliminary design of a 40 MW power plant including the key equipment layout and the site plan was completed.

  4. Turbocharged Spark Ignited Direct Injection - A Fuel Economy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbocharged Spark Ignited Direct Injection - A Fuel Economy Solution for The US Turbocharged Spark Ignited Direct Injection - A Fuel Economy Solution for The US Turbocharged SIDI ...

  5. Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems for Transportation ...

  6. DIRECT FUEL CELL/TURBINE POWER PLANT

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2004-11-01

    This report includes the progress in development of Direct FuelCell/Turbine{reg_sign} (DFC/T{reg_sign}) power plants for generation of clean power at very high efficiencies. The DFC/T power system is based on an indirectly heated gas turbine to supplement fuel cell generated power. The DFC/T power generation concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, 60% on coal gas, minimal emissions, simplicity in design, direct reforming internal to the fuel cell, reduced carbon dioxide release to the environment, and potential cost competitiveness with existing combined cycle power plants. The operation of sub-MW hybrid Direct FuelCell/Turbine power plant test facility with a Capstone C60 microturbine was initiated in March 2003. The inclusion of the C60 microturbine extended the range of operation of the hybrid power plant to higher current densities (higher power) than achieved in previous tests using a 30kW microturbine. The design of multi-MW DFC/T hybrid systems, approaching 75% efficiency on natural gas, was initiated. A new concept was developed based on clusters of One-MW fuel cell modules as the building blocks. System analyses were performed, including systems for near-term deployment and power plants with long-term ultra high efficiency objectives. Preliminary assessment of the fuel cell cluster concept, including power plant layout for a 14MW power plant, was performed.

  7. Direct FuelCell/Turbine Power Plant

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2004-11-19

    This report includes the progress in development of Direct Fuel Cell/Turbine. (DFC/T.) power plants for generation of clean power at very high efficiencies. The DFC/T power system is based on an indirectly heated gas turbine to supplement fuel cell generated power. The DFC/T power generation concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, 60% on coal gas, minimal emissions, simplicity in design, direct reforming internal to the fuel cell, reduced carbon dioxide release to the environment, and potential cost competitiveness with existing combined cycle power plants. FCE successfully completed testing of the pre-alpha sub-MW DFC/T power plant. This power plant was constructed by integration of a 250kW fuel cell stack and a microturbine. Following these proof-of-concept tests, a stand-alone test of the microturbine verified the turbine power output expectations at an elevated (representative of the packaged unit condition) turbine inlet temperature. Preliminary design of the packaged sub-MW alpha DFC/T unit has been completed and procurement activity has been initiated. The preliminary design of a 40 MW power plant including the key equipment layout and the site plan was completed. A preliminary cost estimate for the 40 MW DFC/T plant has also been prepared. The tests of the cascaded fuel cell concept for achieving high fuel utilizations were completed. The tests demonstrated that the concept results in higher power plant efficiency. Alternate stack flow geometries for increased power output/fuel utilization capabilities are also being evaluated.

  8. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  9. Ejector device for direct injection fuel jet

    DOE Patents [OSTI]

    Upatnieks, Ansis

    2006-05-30

    Disclosed is a device for increasing entrainment and mixing in an air/fuel zone of a direct fuel injection system. The device comprises an ejector nozzle in the form of an inverted funnel whose central axis is aligned along the central axis of a fuel injector jet and whose narrow end is placed just above the jet outlet. It is found that effective ejector performance is achieved when the ejector geometry is adjusted such that it comprises a funnel whose interior surface diverges about 7.degree. to about 9.degree. away from the funnel central axis, wherein the funnel inlet diameter is about 2 to about 3 times the diameter of the injected fuel plume as the fuel plume reaches the ejector inlet, and wherein the funnel length equal to about 1 to about 4 times the ejector inlet diameter. Moreover, the ejector is most effectively disposed at a separation distance away from the fuel jet equal to about 1 to about 2 time the ejector inlet diameter.

  10. DIRECT FUEL CELL/TURBINE POWER PLANT

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2003-05-23

    In this reporting period, a milestone was achieved by commencement of testing and operation of the sub-scale hybrid direct fuel cell/turbine (DFC/T{reg_sign}) power plant. The operation was initiated subsequent to the completion of the construction of the balance-of-plant (BOP) and implementation of process and control tests of the BOP for the subscale DFC/T hybrid system. The construction efforts consisted of finishing the power plant insulation and completion of the plant instrumentation including the wiring and tubing required for process measurement and control. The preparation work also included the development of procedures for facility shake down, conditioning and load testing of the fuel cell, integration of the microturbine, and fuel cell/gas turbine load tests. At conclusion of the construction, the process and control (PAC) tests of BOP, including the microturbine, were initiated.

  11. Liquid phase fluid dynamic (methanol) run in the LaPorte alternative fuels development unit

    SciTech Connect (OSTI)

    Bharat L. Bhatt

    1997-05-01

    A fluid dynamic study was successfully completed in a bubble column at DOE's Alternative Fuels Development Unit (AFDU) in LaPorte, Texas. Significant fluid dynamic information was gathered at pilot scale during three weeks of Liquid Phase Methanol (LPMEOJP) operations in June 1995. In addition to the usual nuclear density and temperature measurements, unique differential pressure data were collected using Sandia's high-speed data acquisition system to gain insight on flow regime characteristics and bubble size distribution. Statistical analysis of the fluctuations in the pressure data suggests that the column was being operated in the churn turbulent regime at most of the velocities considered. Dynamic gas disengagement experiments showed a different behavior than seen in low-pressure, cold-flow work. Operation with a superficial gas velocity of 1.2 ft/sec was achieved during this run, with stable fluid dynamics and catalyst performance. Improvements included for catalyst activation in the design of the Clean Coal III LPMEOH{trademark} plant at Kingsport, Tennessee, were also confirmed. In addition, an alternate catalyst was demonstrated for LPMEOH{trademark}.

  12. Rapid starting methanol reactor system

    DOE Patents [OSTI]

    Chludzinski, Paul J.; Dantowitz, Philip; McElroy, James F.

    1984-01-01

    The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

  13. Direct FuelCell/Turbine Power Plant

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2008-09-30

    This report summarizes the progress made in development of Direct FuelCell/Turbine (DFC/T{reg_sign}) power plants for generation of clean power at very high efficiencies. The DFC/T system employs an indirectly heated Turbine Generator to supplement fuel cell generated power. The concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, minimal emissions, reduced carbon dioxide release to the environment, simplicity in design, direct reforming internal to the fuel cell, and potential cost competitiveness with existing combined cycle power plants. Proof-of-concept tests using a sub-MW-class DFC/T power plant at FuelCell Energy's (FCE) Danbury facility were conducted to validate the feasibility of the concept and to measure its potential for electric power production. A 400 kW-class power plant test facility was designed and retrofitted to conduct the tests. The initial series of tests involved integration of a full-size (250 kW) Direct FuelCell stack with a 30 kW Capstone microturbine. The operational aspects of the hybrid system in relation to the integration of the microturbine with the fuel cell, process flow and thermal balances, and control strategies for power cycling of the system, were investigated. A subsequent series of tests included operation of the sub-MW Direct FuelCell/Turbine power plant with a Capstone C60 microturbine. The C60 microturbine extended the range of operation of the hybrid power plant to higher current densities (higher power) than achieved in initial tests using the 30kW microturbine. The proof-of-concept test results confirmed the stability and controllability of operating a fullsize (250 kW) fuel cell stack in combination with a microturbine. Thermal management of the system was confirmed and power plant operation, using the microturbine as the only source of fresh air supply to the

  14. Pneumatic direct cylinder fuel injection system

    SciTech Connect (OSTI)

    Reinke, P.E.

    1988-09-20

    This patent describes a pneumatic direct cylinder fuel injection system for use in an internal combustion engine of the type having an engine block means with an air induction means for supplying induction air to cylinders in the engine block means, with each cylinder having a piston reciprocable therein so as to define a combustion chamber which includes a stratified charge chamber as a portion thereof, the system including a plurality of pneumatic injectors, with the pneumatic injector being supported by the engine block means in position to discharge an air/fuel mixture into an associate stratified charge chamber, each of the pneumatic injectors including a body means terminating at one end thereof in a nozzle body, a bore means through the body means and the nozzle body, a valve seat encircling the bore means at the outboard free end of the nozzle body, the opposite end of the bore means being connectable to a source of air at a predetermined pressure, a poppet valve operatively positioned in the bore means. The poppet value includes a head movable between an open position and closed position relative to the valve seat and a stem extending from the head and defining with the bore means an air passage, control means operatively associated with the poppet valve to normally maintain the poppet valve in the closed position and being operative to permit movement of the poppet valve to the open position and, an electromagnetic fuel injector operatively positioned in the body means for injecting pressurized fuel into the air passage upstream of the head of the poppet valve in terms of the direction of air flow through the air passage during a compression stroke of the piston in the associate cylinder, the arrangement being such that when the compression pressure reaches a predetermined pressure the poppet valve will be moved to the valve closed position.

  15. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ...

  16. Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

    SciTech Connect (OSTI)

    Turgut Gur

    2010-04-30

    This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2

  17. Injector spray characterization of methanol in reciprocating engines

    SciTech Connect (OSTI)

    Dodge, L.; Naegeli, D.

    1994-06-01

    This report covers a study that addressed cold-starting problems in alcohol-fueled, spark-ignition engines by using fine-spray port-fuel injectors to inject fuel directly into the cylinder. This task included development and characterization of some very fine-spray, port-fuel injectors for a methanol-fueled spark-ignition engine. After determining the spray characteristics, a computational study was performed to estimate the evaporation rate of the methanol fuel spray under cold-starting and steady-state conditions.

  18. DIRECT FUEL CELL/TURBINE POWER PLANT

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2003-05-22

    Project activities were focused on the design and construction the sub-scale hybrid Direct Fuel Cell/turbine (DFC/T{reg_sign}) power plant and modification of a Capstone Simple Cycle Model 330 microturbine. The power plant design work included preparation of system flow sheet and performing computer simulations based on conservation of mass and energy. The results of the simulation analyses were utilized to prepare data sheets and specifications for balance-of-plant equipment. Process flow diagram (PFD) and piping and instrumentation diagrams (P&ID) were also completed. The steady state simulation results were used to develop design information for modifying the control functions, and for sizing the heat exchangers required for recuperating the waste heat from the power plant. Line and valve sizes for the interconnecting pipes between the microturbine and the heat recuperators were also identified.

  19. Fuel Cells News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    transportation and novel membranes and non-platinum group metal catalysts for direct methanol as well as hydrogen fuel cells. November 13, 2013 Energy Department Announces up...

  20. New Directions in Fuels Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels Technology New Directions in Fuels Technology All fuels have their pros and cons that become evident at large scale, and while biofuels are a critical part of the energy future, they are not the only solution deer09_wright.pdf (828.49 KB) More Documents & Publications Drop In Fuels: Where the Road Leads After Petroleum Thermochemical Conversion Proceeses to Aviation Fuels

  1. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  2. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  3. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  4. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  5. Discovery of methanol electro-oxidation catalysts by combinatorial analysis

    SciTech Connect (OSTI)

    Mallouk, T.E.; Reddington, E.; Pu, C.

    1996-12-31

    Hydrogen fuel cells are likely to become a major energy source in the next century, but they are not ideal for all applications. A safe alternative fuel with a high energy density will be necessary for transportation and mobile applications. Direct methanol-air fuel cells (DMFCs) are an attractive alternative to hydrogen fuel cells because of the high energy density and low cost of methanol as a fuel. However, in order for DMFCs to become commercially viable, better electrocatalysts for the anode reaction need to be developed. This paper describes a combinatorial technique for generating an array of electrodes with varying metal compositions.

  6. Turbocharged Spark Ignited Direct Injection - A Fuel Economy Solution for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The US | Department of Energy Turbocharged Spark Ignited Direct Injection - A Fuel Economy Solution for The US Turbocharged Spark Ignited Direct Injection - A Fuel Economy Solution for The US Turbocharged SIDI is the most promising advanced gasoline technology; combines existing & proven technologies in a synergistic manner, offers double digit fuel economy benefits, much lower cost than diesel or hybrid. deer09_whitaker.pdf (488.25 KB) More Documents & Publications E85 Optimized

  7. Intercooling effects of methanol on turbocharged diesel engine performance and exhaust emissions

    SciTech Connect (OSTI)

    Saito, T.; Daisho, Y.; Aoki, Y.; Kawase, N.

    1984-01-01

    From the viewpoint of utilizing methanol fuel in an automotive turbocharged direct-injection diesel engine, an intercooling system supplying liquid methanol has been devised and its effects on engine performance and exhaust gas emissions have been investigated. With an electronically controlled injector in this system, methanol as a supplementary fuel to diesel fuel can be injected into the intake pipe in order to intercool a hot air charge compressed by the turbocharger. It has been confirmed that especially at heavy load conditions, methanol-intercooling can yield a higher thermal efficiency, and lower nox and smoke emissions simultaneously, compared with three other cases without using methanol: natural aspiration and the cases with and without an ordinary intercooler. However, methanol fueling must be avoided at lower loads since sacrifices in efficiency and hydrocarbon emissions are involved.

  8. SFC Smart Fuel Cell AG | Open Energy Information

    Open Energy Info (EERE)

    Zip: D-85649 Product: Smart Fuel Cell designs, develops and manufactures direct methanol fuel cell systems. References: SFC Smart Fuel Cell AG1 This article is a stub. You...

  9. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  10. Fuel Cells (Project FC-041): DOE Hydrogen Program 2011 Annual...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Advanced Direct Methanol Fuel Cell Anode Catalysts Huyen Dinh; National Renewable Energy Laboratory Brief ... A similar approach for oxygen reduction reaction (ORR) catalysis ...

  11. MTI MicroFuel Cells Inc | Open Energy Information

    Open Energy Info (EERE)

    York Zip: NY 12205 Product: Has developed a patented, miniaturised proprietary direct methanol fuel cell (DMFC) technology called Mobion. Coordinates: 42.707237, -89.436378...

  12. Durable, Low Cost, Improved Fuel Cell Membranes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durable, Low Cost, Improved Fuel Cell Membranes Durable, Low Cost, Improved Fuel Cell Membranes This presentation, which focuses on fuel cell membranes, was given by Michel Foure of Arkema at a meeting on new fuel cell projects in February 2007. new_fc_foure_arkema.pdf (168.93 KB) More Documents & Publications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Novel Materials for High Efficiency Direct Methanol Fuel Cells High Temperature Membrane Working

  13. Economics of Direct Hydrogen Polymer Electrolyte Membrane Fuel Cell Systems

    SciTech Connect (OSTI)

    Mahadevan, Kathyayani

    2011-10-04

    Battelle's Economic Analysis of PEM Fuel Cell Systems project was initiated in 2003 to evaluate the technology and markets that are near-term and potentially could support the transition to fuel cells in automotive markets. The objective of Battelle?s project was to assist the DOE in developing fuel cell systems for pre-automotive applications by analyzing the technical, economic, and market drivers of direct hydrogen PEM fuel cell adoption. The project was executed over a 6-year period (2003 to 2010) and a variety of analyses were completed in that period. The analyses presented in the final report include: Commercialization scenarios for stationary generation through 2015 (2004); Stakeholder feedback on technology status and performance status of fuel cell systems (2004); Development of manufacturing costs of stationary PEM fuel cell systems for backup power markets (2004); Identification of near-term and mid-term markets for PEM fuel cells (2006); Development of the value proposition and market opportunity of PEM fuel cells in near-term markets by assessing the lifecycle cost of PEM fuel cells as compared to conventional alternatives used in the marketplace and modeling market penetration (2006); Development of the value proposition of PEM fuel cells in government markets (2007); Development of the value proposition and opportunity for large fuel cell system application at data centers and wastewater treatment plants (2008); Update of the manufacturing costs of PEM fuel cells for backup power applications (2009).

  14. Future Directions in Engines and Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Future directions in engines and fuels, powertrains and vehicle system review. PDF icon deer10tatur.pdf More Documents & Publications A View from the Bridge Boosting Small Engines...

  15. PolyFuel Inc | Open Energy Information

    Open Energy Info (EERE)

    California Zip: 94043 Product: Polyfuel specialises in membrane technology for direct methanol fuel cells. References: PolyFuel Inc1 This article is a stub. You can help OpenEI...

  16. INERT-MATRIX FUEL: ACTINIDE ''BURINGIN'' AND DIRECT DISPOSAL

    SciTech Connect (OSTI)

    Rodney C. Ewing; Lumin Wang

    2002-10-30

    Excess actinides result from the dismantlement of nuclear weapons (Pu) and the reprocessing of commercial spent nuclear fuel (mainly 241 Am, 244 Cm and 237 Np). In Europe, Canada and Japan studies have determined much improved efficiencies for burnup of actinides using inert-matrix fuels. This innovative approach also considers the properties of the inert-matrix fuel as a nuclear waste form for direct disposal after one-cycle of burn-up. Direct disposal can considerably reduce cost, processing requirements, and radiation exposure to workers.

  17. Dynamic simulation of a direct carbonate fuel cell power plant

    SciTech Connect (OSTI)

    Ernest, J.B.; Ghezel-Ayagh, H.; Kush, A.K.

    1996-12-31

    Fuel Cell Engineering Corporation (FCE) is commercializing a 2.85 MW Direct carbonate Fuel Cell (DFC) power plant. The commercialization sequence has already progressed through construction and operation of the first commercial-scale DFC power plant on a U.S. electric utility, the 2 MW Santa Clara Demonstration Project (SCDP), and the completion of the early phases of a Commercial Plant design. A 400 kW fuel cell stack Test Facility is being built at Energy Research Corporation (ERC), FCE`s parent company, which will be capable of testing commercial-sized fuel cell stacks in an integrated plant configuration. Fluor Daniel, Inc. provided engineering, procurement, and construction services for SCDP and has jointly developed the Commercial Plant design with FCE, focusing on the balance-of-plant (BOP) equipment outside of the fuel cell modules. This paper provides a brief orientation to the dynamic simulation of a fuel cell power plant and the benefits offered.

  18. DIRECT FUEL CELL/TURBINE POWER PLANT

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2003-05-27

    The subMW hybrid DFC/T power plant facility was upgraded with a Capstone C60 microturbine and a state-of-the-art full size fuel cell stack. The integration of the larger microturbine extended the capability of the hybrid power plant to operate at high power ratings with a single gas turbine without the need for supplementary air. The objectives of this phase of subMW hybrid power plant tests are to support the development of process and control and to provide the insight for the design of the packaged subMW hybrid demonstration units. The development of the ultra high efficiency multi-MW power plants was focused on the design of 40 MW power plants with efficiencies approaching 75% (LHV of natural gas). The design efforts included thermodynamic cycle analysis of key gas turbine parameters such as compression ratio.

  19. Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Direct H2 PEM Fuel Cell Systems for Transportation Applications: 2013 Update Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation Applications: ...

  20. Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and ...

  1. Gamma Ray Mirrors for Direct Measurement of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Pivovaroff, Dr. Michael J.; Ziock, Klaus-Peter; Harrison, Mark J; Soufli, Regina

    2014-01-01

    Direct measurement of the amount of Pu and U in spent nuclear fuel represents a challenge for the safeguards community. Ideally, the characteristic gamma-ray emission lines from different isotopes provide an observable suitable for this task. However, these lines are generally lost in the fierce flux of radiation emitted by the fuel. The rates are so high that detector dead times limit measurements to only very small solid angles of the fuel. Only through the use of carefully designed view ports and long dwell times are such measurements possible. Recent advances in multilayer grazing-incidence gamma-ray optics provide one possible means of overcoming this difficulty. With a proper optical and coating design, such optics can serve as a notch filter, passing only narrow regions of the overall spectrum to a fully shielded detector that does not view the spent fuel directly. We report on the design of a mirror system and a number of experimental measurements.

  2. New Directions in Engines and Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuels New Directions in Engines and Fuels Mobility based predominately on petroleum faces severe and imminent constraints as petroleum production and deliverability are inadequate to supply an economically developing world and a collective will and constancy of purpose are required to solve these problems deer09_smyth.pdf (1.06 MB) More Documents & Publications GM's Perspective on Advanced Biofuels Market Drivers for Biofuels Biofuels & Greenhouse Gas Emissions: Myths versus Facts

  3. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  4. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir; Kumar, Romesh; Krumpelt, Michael

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  5. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  6. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir; Kumar, Romesh; Krumpelt, Michael

    2001-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  7. High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation

    SciTech Connect (OSTI)

    Steinberg, M; Cooper, J F; Cherepy, N

    2002-01-02

    Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power

  8. Low temperature methanol process

    SciTech Connect (OSTI)

    O'Hare, T.E.; Sapienza, R.S.; Mahajan, D.; Skaperdas, G.T.

    1986-06-01

    The world's abundant natural gas resources could provide methanol in fuel quantities to the utility system. Natural gas liquefaction is the current major option available for international export transport of natural gas. Gas production is on the increase and international trade even more so, with LNG making most progress. The further penetration of natural gas into distant markets can be substantially increased by a new methanol synthesis process under development. The new methanol process is made possible by the discovery of a catalyst that drops synthesis temperatures from about 275/sup 0/C to about 100/sup 0/C. Furthermore, the new catalyst is a liquid phase system, which permits the synthesis reaction to proceed at fully isothermal conditions. Therefore, the new low temperature liquid catalyst can convert synthesis gas completely to methanol in a single pass through the methanol synthesis reactor. This characteristic leads to a further major improvement in the methanol plant. Atmospheric nitrogen can be tolerated in the synthesis gas, and still the volume of gas fed to the reactor can be smaller than the volume of gas that must be fed to the reactor when accommodating the very low conversions furnished by the best of currently available catalysts. The energy disadvantage of the methanol option must be balanced against the advantage of a much lower capital investment requirement made possible by the new BNL synthesis. Preliminary estimates show that methanol conversion and shipping require an investment for liquefaction to methanol, and shipping liquefied methanol that can range from 35 to 50% of that needed for the LNG plant and LNG shipping fleet.

  9. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications: 2007 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update This report estimates fuel cell system cost ...

  10. Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation of Direct H 2 PEM Fuel Cell Systems for Transportation ... Jason Marcinkoski of DOE's Office of Energy Efficiency and Renewable Energy (EERE) Fuel ...

  11. Direct Conversion of Biomass into Transportation Fuels - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Direct Conversion of Biomass into Transportation Fuels Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing SummaryLos Alamos National Laboratory is developing a portfolio of technologies related to catalytic processes for converting oligosaccharides into hydrocarbons under mild conditions.DescriptionWe are seeking a co-development partner interested in teaming to further develop the technology, including pursuit of Federal-funding opportunities, and

  12. Methane conversion for highway fuel (Methanol Plantship Project), interim report. Resource materials. Report for November 1991-May 1992

    SciTech Connect (OSTI)

    Fink, C.; Jackson, I.; Wright, S.; Booras, P.; Linaweaver, P.

    1997-01-01

    The report presents partial results of a study undertaken to respond to PL 101-516; that law provided funding for `phase II of the development/design work on a floating methanol production plantship to advance work already completed under phase I of the project, which was authorized by section 152 of the Surface Transportation Act of 1982.` Phase I determined the feasibility of producing large volumes of low-cost methanol aboard a plantship. The interim report includes: an examination of the impact of recent permitting, licensing, and environmental regulations on methanol plantship (MPS) design and operation; analysis of other recent MPS design studies and updating of the process technology; and revision and updating of an economic analysis which continues to demonstrate the project`s viability.

  13. Transportation fuels from wood

    SciTech Connect (OSTI)

    Baker, E.G.; Elliott, D.C.; Stevens, D.J.

    1980-01-01

    The various methods of producing transportation fuels from wood are evaluated in this paper. These methods include direct liquefaction schemes such as hydrolysis/fermentation, pyrolysis, and thermochemical liquefaction. Indirect liquefaction techniques involve gasification followed by liquid fuels synthesis such as methanol synthesis or the Fischer-Tropsch synthesis. The cost of transportation fuels produced by the various methods are compared. In addition, three ongoing programs at Pacific Northwest Laboratory dealing with liquid fuels from wood are described.

  14. Platinum Nickel Nanowires as Methanol Oxidation Electrocatalysts

    SciTech Connect (OSTI)

    Alia, Shaun M.; Pylypenko, Svitlana; Neyerlin, Kenneth C.; Kocha, Shyam S.; Pivovar, Bryan S.

    2015-08-27

    We investigated platinum(Pt) nickel (Ni) nanowires (PtNiNWs) as methanol oxidation reaction (MOR) catalysts in rotating disk electrode (RDE) half-cells under acidic conditions. Pt-ruthenium (Ru) nanoparticles have long been the state of the art MOR catalyst for direct methanol fuel cells (DMFCs) where Ru provides oxophilic sites, lowering the potential for carbon monoxide oxidation and the MOR onset. Ru, however, is a precious metal that has long term durability concerns. Ni/Ni oxide species offer a potential to replace Ru in MOR electrocatalysis. PtNiNWs were investigated for MOR and oxygen annealing was investigated as a route to improve catalyst performance (mass activity 65% greater) and stability to potential cycling. Our results presented show that PtNiNWs offer significant promise in the area, but also result in Ni ion leaching that is a concern requiring further evaluation in fuel cells.

  15. Platinum Nickel Nanowires as Methanol Oxidation Electrocatalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alia, Shaun M.; Pylypenko, Svitlana; Neyerlin, Kenneth C.; Kocha, Shyam S.; Pivovar, Bryan S.

    2015-08-27

    We investigated platinum(Pt) nickel (Ni) nanowires (PtNiNWs) as methanol oxidation reaction (MOR) catalysts in rotating disk electrode (RDE) half-cells under acidic conditions. Pt-ruthenium (Ru) nanoparticles have long been the state of the art MOR catalyst for direct methanol fuel cells (DMFCs) where Ru provides oxophilic sites, lowering the potential for carbon monoxide oxidation and the MOR onset. Ru, however, is a precious metal that has long term durability concerns. Ni/Ni oxide species offer a potential to replace Ru in MOR electrocatalysis. PtNiNWs were investigated for MOR and oxygen annealing was investigated as a route to improve catalyst performance (mass activitymore » 65% greater) and stability to potential cycling. Our results presented show that PtNiNWs offer significant promise in the area, but also result in Ni ion leaching that is a concern requiring further evaluation in fuel cells.« less

  16. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    reports on the status of mass production cost estimation for direct hydrogen PEM fuel cell systems. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for ...

  17. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application

    Broader source: Energy.gov [DOE]

    This presentation reports on the status of mass production cost estimation for direct hydrogen PEM fuel cell systems.

  18. Liquid Tin Anode Direct Coal Fuel Cell Final Program Report

    SciTech Connect (OSTI)

    Tao, Thomas

    2012-01-26

    This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

  19. SBIR/STTR Phase I Release 2 Technical Topics Announced for FY14 Fuel Cell Topics Included

    Broader source: Energy.gov [DOE]

    Phase I Release 2 technical topics include prototype fuel cell-battery electric hybrid trucks for waste transportation and novel membranes and non-platinum group metal catalysts for direct methanol as well as hydrogen fuel cells.

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Dispenser Labeling Requirement All equipment used to dispense motor fuel containing at least 1% ethanol or methanol must be clearly labeled to inform customers that the fuel contains ethanol or methanol. (Reference Texas Statutes, Agriculture Code 17.051

  1. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  2. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    estimates fuel cell system cost for systems produced in the years 2006, 2010, and 2015, and is the ... Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for ...

  3. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Applications: 2007 Update | Department of Energy Applications: 2007 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update This report estimates fuel cell system cost for systems produced in the years 2007, 2010, and 2015, and is the first annual update of a comprehensive automotive fuel cell cost analysis. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update (3.19

  4. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Markets | Department of Energy Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets July 9th presentation for the U.S. DOE HFCIT bi-montly informational call series for state and regional initiatives mahadevan.pdf (1.13 MB) More Documents & Publications Full Fuel-Cycle Comparison of Forklift Propulsion Systems Early Markets: Fuel Cells for Material Handling

  5. OTEC energy via methanol production

    SciTech Connect (OSTI)

    Avery, W.H.; Richards, D.; Niemeyer, W.G.; Shoemaker, J.D.

    1983-01-01

    The conceptual design of an 160 MW/sub e/ OTEC plantship has been documented; it is designed to produce 1000 tonne/day of fuel-grade methanol from coal slurry shipped to the plantship, using oxygen and hydrogen from the on-board electrolysis of water. Data and components are used that were derived by Brown and Root Development, Inc. (BARDI) in designing a barge-mounted plant to make methanol from natural gas for Litton Industries and in the design and construction of a coal-to-ammonia demonstration plant in operation at Muscle Shoals, Alabama, for the Tennessee Valley Authority (TVA). The OTEC-methanol plant design is based on the use of the Texaco gasifier and Lurgi synthesis units. The sale price of OTEC methanol delivered to port from this first-of-a-kind plant is estimated to be marginally competitive with methanol from other sources at current market prices.

  6. Methanol | Open Energy Information

    Open Energy Info (EERE)

    Methanol Jump to: navigation, search TODO: Add description List of Methanol Incentives Retrieved from "http:en.openei.orgwindex.php?titleMethanol&oldid267176" Feedback...

  7. Premixed direct injection nozzle for highly reactive fuels

    DOE Patents [OSTI]

    Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin Paul; York, William David; Uhm, Jong Ho; Zuo, Baifang

    2013-09-24

    A fuel/air mixing tube for use in a fuel/air mixing tube bundle is provided. The fuel/air mixing tube includes an outer tube wall extending axially along a tube axis between an inlet end and an exit end, the outer tube wall having a thickness extending between an inner tube surface having a inner diameter and an outer tube surface having an outer tube diameter. The tube further includes at least one fuel injection hole having a fuel injection hole diameter extending through the outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    It contains estimates for material and manufacturing cost of complete 80 kWnet direct hydrogen proton exchange membrane fuel cell systems suitable for powering light duty ...

  9. Preliminary study on direct recycling of spent PWR fuel in PWR...

    Office of Scientific and Technical Information (OSTI)

    Preliminary study on direct recycling of spent PWR fuel in PWR system Citation Details ... conference on advances in nuclear science and engineering, Bali (Indonesia), 14-17 ...

  10. US Spent (Used) Fuel Status, Management and Likely Directions- 12522

    SciTech Connect (OSTI)

    Jardine, Leslie J.

    2012-07-01

    As of 2010, the US has accumulated 65,200 MTU (42,300 MTU of PWR's; 23,000 MTU of BWR's) of spent (irradiated or used) fuel from 104 operating commercial nuclear power plants situated at 65 sites in 31 States and from previously shutdown commercial nuclear power plants. Further, the Department of Energy (DOE) has responsibility for an additional 2458 MTU of DOE-owned defense and non defense spent fuel from naval nuclear power reactors, various non-commercial test reactors and reactor demonstrations. The US has no centralized large spent fuel storage facility for either commercial spent fuel or DOE-owned spent fuel. The 65,200 MTU of US spent fuel is being safely stored by US utilities at numerous reactor sites in (wet) pools or (dry) metal or concrete casks. As of November 2010, the US had 63 'independent spent fuel storage installations' (or ISFSI's) licensed by the US Nuclear Regulatory Commission located at 57 sites in 33 states. Over 1400 casks loaded with spent fuel for dry storage are at these licensed ISFSI's; 47 sites are located at commercial reactor sites and 10 are located 'away' from a reactor (AFR's) site. DOE's small fraction of a 2458 MTU spent fuel inventory, which is not commercial spent fuel, is with the exception of 2 MTU, being stored at 4 sites in 4 States. The decades old US policy of a 'once through' fuel cycle with no recycle of spent fuel was set into a state of 'mass confusion or disruption' when the new US President Obama's administration started in early 2010 stopping the only US geologic disposal repository at the Yucca Mountain site in the State of Nevada from being developed and licensed. The practical result is that US nuclear power plant operators will have to continue to be responsible for managing and storing their own spent fuel for an indefinite period of time at many different sites in order to continue to generate electricity because there is no current US government plan, schedule or policy for taking possession of

  11. U.S. Department of Energy Fuel Cell Activities: Progress and Future Directions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Fuel Cell Activities: Progress and Future Directions Total Energy USA Houston, Texas Dr. Sunita Satyapal 11/27/2012 Director, Office of Fuel Cell Technologies Energy Efficiency and Renewable Energy U.S. Department of Energy Overview Fuel Cells - An Emerging Global Industry United States 46% Germany 7% Korea 7% Canada 3% Taiwan 1% Great Britain 1% France 1% Other 3% Japan 31% Fuel Cell Patents Geographic Distribution 2002-2011 Top 10 companies: GM, Honda, Samsung,

  12. Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems

    SciTech Connect (OSTI)

    Wolk, R

    2004-04-23

    Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power

  13. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Applications: 2010 Update | Department of Energy Applications: 2010 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2010 Update This report is the fourth annual update of a comprehensive automotive fuel cell cost analysis. It contains estimates for material and manufacturing costs of complete 80 kWnet direct-hydrogen proton exchange membrane fuel cell systems suitable for powering light-duty automobiles. Mass Production Cost

  14. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  15. List of Other Alternative Fuel Vehicles Incentives | Open Energy...

    Open Energy Info (EERE)

    Fuels Renewable Fuel Vehicles Other Alternative Fuel Vehicles Refueling Stations Ethanol Methanol Biodiesel No Alternative Vehicle Conversion Credits - Corporate (Louisiana)...

  16. Future Directions in Engines and Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The vision of the VW group for the future of diesel engines and future fuels is presented. PDF icon deer10sjohnson.pdf More Documents & Publications The Diesel Engine Powering ...

  17. INERT-MATRIX FUEL: ACTINIDE ''BURINGIN'' AND DIRECT DISPOSAL...

    Office of Scientific and Technical Information (OSTI)

    Excess actinides result from the dismantlement of nuclear weapons (Pu) and the reprocessing of commercial spent nuclear fuel (mainly 241 Am, 244 Cm and 237 Np). In Europe, Canada ...

  18. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    SciTech Connect (OSTI)

    Ogden, J.; Steinbugler, M.; Kreutz, T.

    1997-12-31

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  19. Liquid methanol under a static electric field

    SciTech Connect (OSTI)

    Cassone, Giuseppe; Giaquinta, Paolo V.; Saija, Franz; Saitta, A. Marco

    2015-02-07

    We report on an ab initio molecular dynamics study of liquid methanol under the effect of a static electric field. We found that the hydrogen-bond structure of methanol is more robust and persistent for field intensities below the molecular dissociation threshold whose value (?0.31 V/) turns out to be moderately larger than the corresponding estimate obtained for liquid water. A sustained ionic current, with ohmic current-voltage behavior, flows in this material for field intensities above 0.36 V/, as is also the case of water, but the resulting ionic conductivity (?0.40 S cm{sup ?1}) is at least one order of magnitude lower than that of water, a circumstance that evidences a lower efficiency of proton transfer processes. We surmise that this study may be relevant for the understanding of the properties and functioning of technological materials which exploit ionic conduction, such as direct-methanol fuel cells and Nafion membranes.

  20. Future Directions in Engines and Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research on improving the efficiency of HD/MD/LD diesel engines with alternative fuels is presented deer10_eckerle.pdf (384.38 KB) More Documents & Publications Vehicle Technologies Office Merit Review 2015: SuperTruck Program: Engine Project Review SuperTruck Program: Engine Project Review View from the Bridge: Commercial Vehicle Perspective

  1. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  2. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  3. Advanced Materials and Concepts for Portable Power Fuel Cells | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy and Concepts for Portable Power Fuel Cells Advanced Materials and Concepts for Portable Power Fuel Cells These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. 9_lanl_zelenay.pdf (2.69 MB) More Documents & Publications Introduction to DMFCs - Advanced Materials and Concepts for Portable Power Fuel Cells Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts New MEA Materials for Improved DMFC Performance, Durability and

  4. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence; Blum, David B.

    1986-01-01

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  5. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence; Blum, David B.

    1987-01-01

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  6. From Gasoline to Grassoline: Microbes Produce Fuels Directly from Biomass

    DOE R&D Accomplishments [OSTI]

    Yarris, Lynn

    2011-03-28

    A microbe that can produce an advanced biofuel directly from biomass was developed by researchers with the U.S. Department of Energy's Joint BioEnergy Institute.

  7. Sulfur-tolerant anode material for direct hydrocarbon solid oxide fuel cells

    DOE Patents [OSTI]

    Chen, Fanglin; Yang, Chenghao; Yang, Zhibin

    2016-08-02

    In one aspect, the present subject matter is directed to a composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy.

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    It contains estimates for material and manufacturing costs of complete 80 kWnet direct-hydrogen proton exchange membrane fuel cell systems suitable for powering light-duty ...

  9. PEM fuel cells for transportation and stationary power generation applications

    SciTech Connect (OSTI)

    Cleghorn, S.J.; Ren, X.; Springer, T.E.; Wilson, M.S.; Zawodzinski, C.; Zawodzinski, T.A. Jr.; Gottesfeld, S.

    1996-05-01

    We describe recent activities at LANL devoted to polymer electrolyte fuel cells in the contexts of stationary power generation and transportation applications. A low cost/high performance hydrogen or reformate/air stack technology is being developed based on ultralow Pt loadings and on non-machined, inexpensive elements for flow-fields and bipolar plates. On board methanol reforming is compared to the option of direct methanol fuel cells because of recent significant power density increases demonstrated in the latter.

  10. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alternative fuels are defined as methanol, ethanol, natural gas, liquefied petroleum gas (propane), coal-derived liquid fuels, hydrogen, electricity, biodiesel, renewable diesel,...

  11. High pressure injection and atomization characteristics of methanol

    SciTech Connect (OSTI)

    Aigal, A.K.; Pundir, B.P.; Khatchian, A.S.

    1986-01-01

    Research on conversion of diesel engines for operation on methanol is, currently, of worldwide interest. Due to requirements of higher cyclic delivery of methanol and changes in fuel properties e.g. compressibility, wave propagation velocity, viscosity, surface tension, density etc., injection and atomization characteristics of methanol are expected to be different from diesel. From the equation of continuity and forces acting on the injection system elements and applying the principles of similarity, modifications required in the injection system were identified. Methanol injection and atomization characteristics were studied with a modified injection system and compared with those observed with diesel fuel. Methanol gave more favourable cyclic delivery characteristics than diesel. Laser diffraction technique was used to study time and space resolved drop size distribution in methanol and diesel sprays. With methanol, drop size distribution were, generally, much narrower and droplets were smaller than diesel. Spatial distribution of drop size in methanol spray showed somewhat different trends than for diesel.

  12. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets Kathya Mahadevan, Battelle July 11, 2007 2 Project Objectives To assist DOE in developing fuel cell systems by analyzing the technical, economic, and market drivers of direct hydrogen PEM fuel cell (H-PEMFC) adoption. 2006 support included the following: * Market segmentation of 1-250 kW H-PEMFC into near-term (2008) and mid-term (2012) market opportunities * Lifecycle cost analysis of H-PEMFC and competing

  13. The Economics of Reprocessing Versus Direct Disposal of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Bunn, Matthew; Holdren, John P.; Fetter, Steve; Zwaan, Bob van der

    2005-06-15

    We assess the economics of reprocessing versus direct disposal of spent fuel. The uranium price at which reprocessing spent fuel from light water reactors (LWRs) and recycling the resulting plutonium and uranium in LWRs would become economic is estimated for a range of reprocessing prices and other fuel cycle costs. The contribution of both fuel cycle options to the cost of electricity is also estimated. A similar analysis is performed to compare fast neutron reactors (FRs) with LWRs. We review available information about various fuel cycle costs, as well as the quantities of uranium likely to be recoverable at a range of future prices. We conclude that the once-through LWR fuel cycle is likely to remain significantly cheaper than recycling in either LWRs or FRs for at least the next 50 yr, even with substantial growth in nuclear power.

  14. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications: Conceptual vehicle design report pure fuel cell powertrain vehicle

    SciTech Connect (OSTI)

    Oei, D.; Kinnelly, A.; Sims, R.; Sulek, M.; Wernette, D.

    1997-02-01

    In partial fulfillment of the Department of Energy (DOE) Contract No. DE-AC02-94CE50389, {open_quotes}Direct-Hydrogen-Fueled Proton-Exchange-Membrane (PEM) Fuel Cell for Transportation Applications{close_quotes}, this preliminary report addresses the conceptual design and packaging of a fuel cell-only powered vehicle. Three classes of vehicles are considered in this design and packaging exercise, the Aspire representing the small vehicle class, the Taurus or Aluminum Intensive Vehicle (AIV) Sable representing the mid-size vehicle and the E-150 Econoline representing the van-size class. A fuel cell system spreadsheet model and Ford`s Corporate Vehicle Simulation Program (CVSP) were utilized to determine the size and the weight of the fuel cell required to power a particular size vehicle. The fuel cell power system must meet the required performance criteria for each vehicle. In this vehicle design and packaging exercise, the following assumptions were made: fuel cell power system density of 0.33 kW/kg and 0.33 kg/liter, platinum catalyst loading less than or equal to 0.25 mg/cm{sup 2} total and hydrogen tanks containing gaseous hydrogen under 340 atm (5000 psia) pressure. The fuel cell power system includes gas conditioning, thermal management, humidity control, and blowers or compressors, where appropriate. This conceptual design of a fuel cell-only powered vehicle will help in the determination of the propulsion system requirements for a vehicle powered by a PEMFC engine in lieu of the internal combustion (IC) engine. Only basic performance level requirements are considered for the three classes of vehicles in this report. Each vehicle will contain one or more hydrogen storage tanks and hydrogen fuel for 560 km (350 mi) driving range. Under these circumstances, the packaging of a fuel cell-only powered vehicle is increasingly difficult as the vehicle size diminishes.

  15. Fuel-tolerance tests with the Ford PROCO engine

    SciTech Connect (OSTI)

    Choma, M.A.; Havstad, P.H.; Simko, A.O.; Stockhausen, W.F.

    1981-01-01

    A variety of fuel tolerance tests were conducted utilizing Ford's PROCO engine, a direct fuel injection stratified charge engine developed for light duty vehicles. These engine tests were run on the dynamometer and in vehicles. Data indicate an 89 RON octane requirement, relatively low sensitivity to volatility characteristics and good fuel economy, emission control and operability on a certain range of petroleum fuel and alcohol mixes including 100% methanol. Fuels such as JP-4 and Diesel fuel are not at present suitable for this engine. There were no engine modifications tested that might improve the match between the engine and a particular fuel. The 100% methanol test was conducted with a modified fuel injection pump. Durability aspects including compatibility of various fuels with the materials in the fuel system were not addressed.

  16. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that

  17. Fuel-cycle energy and emissions impacts of tripled fuel economy vehicles

    SciTech Connect (OSTI)

    Mintz, M.M.; Wang, M.Q.; Vyas, A.D.

    1998-12-31

    This paper presents estimates of the full cycle energy and emissions impacts of light-duty vehicles with tripled fuel economy (3X vehicles) as currently being developed by the Partnership for a New Generation of Vehicles (PNGV). Seven engine and fuel combinations were analyzed: reformulated gasoline, methanol, and ethanol in spark-ignition, direct-injection engines; low sulfur diesel and dimethyl ether in compression-ignition, direct-injection engines; and hydrogen and methanol in fuel-cell vehicles. The fuel efficiency gain by 3X vehicles translated directly into reductions in total energy demand, petroleum demand, and carbon dioxide emissions. The combination of fuel substitution and fuel efficiency resulted in substantial reductions in emissions of nitrogen oxide, carbon monoxide, volatile organic compounds, sulfur oxide, and particulate matter smaller than 10 microns, particularly under the High Market Share Scenario.

  18. Shock waves generated by high-pressure fuel sprays directly imaged by x-radiography.

    SciTech Connect (OSTI)

    Wang, J.; MacPhee, A.; Powell, C. F.; Yue, Y.; Narayanan, S.; Tate, M. W.; Renzi, M. J.; Ercan, A.; Fontes, E.; Gruner, S. M.; Walther, J.; Schaller, J.

    2001-12-20

    Synchrotron x-radiography and a novel fast x-ray detector are used to visualize the detailed, time-resolved structure of the fluid jets generated by a high pressure diesel-fuel injection. An understanding of the structure of the high-pressure spray is important in optimizing the injection process to increase fuel efficiency and reduce pollutants. It is shown that x-radiography can provide a quantitative measure of the mass distribution of the fuel. Such analysis has been impossible with optical imaging due to the multiple-scattering of visible light by small atomized fuel droplets surrounding the jet. In addition, direct visualization of the jet-induced shock wave proves that the fuel jets become supersonic under appropriate injection conditions. The radiographic images also allow quantitative analysis of the thermodynamic properties of the shock wave.

  19. Federal Methanol Fleet Project final report

    SciTech Connect (OSTI)

    West, B.H.; McGill, R.N.; Hillis, S.L.; Hodgson, J.W.

    1993-03-01

    The Federal Methanol Fleet Project concluded with the termination of data collection from the three fleet sites in February 1991. The Lawrence Berkeley Laboratory (LBL) completed five years of operation, Argonne National Laboratory (ANL) completed its fourth year in the project, and Oak Ridge National Laboratory (ORNL) completed its third. Twenty of the thirty-nine vehicles in the fleet were powered by fuel methanol (typically M85, 85 % methanol, 15 % unleaded gasoline, although the LBL fleet used M88), and the remaining control vehicles were comparable gasoline vehicles. Over 2.2 million km (1.4 million miles) were accumulated on the fleet vehicles in routine government service. Data collected over the years have included vehicle mileage and fuel economy, engine oil analysis, emissions, vehicle maintenance, and driver acceptance. Fuel economies (on an energy basis) of the methanol and gasoline vehicles of the same type were comparable throughout the fleet testing. Engine oil analysis has revealed higher accumulation rates of iron and other metals in the oil of the methanol vehicles, although no significant engine damage has been attributed to the higher metal content. Vehicles of both fuel types have experienced degradation in their emission control systems, however, the methanol vehicles seem to have degraded their catalytic converters at a higher rate. The methanol vehicles have required more maintenance than their gasoline counterparts, in most cases, although the higher levels of maintenance cannot be attributed to ``fuel-related`` repairs. According to the daily driver logs and results from several surveys, drivers of the fleet vehicles at all three sites were generally satisfied with the methanol vehicles.

  20. Federal Methanol Fleet Project final report

    SciTech Connect (OSTI)

    West, B.H.; McGill, R.N. ); Hillis, S.L.; Hodgson, J.W. )

    1993-03-01

    The Federal Methanol Fleet Project concluded with the termination of data collection from the three fleet sites in February 1991. The Lawrence Berkeley Laboratory (LBL) completed five years of operation, Argonne National Laboratory (ANL) completed its fourth year in the project, and Oak Ridge National Laboratory (ORNL) completed its third. Twenty of the thirty-nine vehicles in the fleet were powered by fuel methanol (typically M85, 85 % methanol, 15 % unleaded gasoline, although the LBL fleet used M88), and the remaining control vehicles were comparable gasoline vehicles. Over 2.2 million km (1.4 million miles) were accumulated on the fleet vehicles in routine government service. Data collected over the years have included vehicle mileage and fuel economy, engine oil analysis, emissions, vehicle maintenance, and driver acceptance. Fuel economies (on an energy basis) of the methanol and gasoline vehicles of the same type were comparable throughout the fleet testing. Engine oil analysis has revealed higher accumulation rates of iron and other metals in the oil of the methanol vehicles, although no significant engine damage has been attributed to the higher metal content. Vehicles of both fuel types have experienced degradation in their emission control systems, however, the methanol vehicles seem to have degraded their catalytic converters at a higher rate. The methanol vehicles have required more maintenance than their gasoline counterparts, in most cases, although the higher levels of maintenance cannot be attributed to fuel-related'' repairs. According to the daily driver logs and results from several surveys, drivers of the fleet vehicles at all three sites were generally satisfied with the methanol vehicles.

  1. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H 2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update March 26, 2009 v.30.2021.052209 Prepared by: Brian D. James & Jeffrey A. Kalinoski One Virginia Square 3601 Wilson Boulevard, Suite 650 Arlington, Virginia 22201 703-243-3383 Prepared for: Contract No. GS-10F-0099J to the U.S. Department of Energy Energy Efficiency and Renewable Energy Office Hydrogen, Fuel Cells & Infrastructure Technologies Program Foreword Energy security is

  2. Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation of Direct H 2 PEM Fuel Cell Systems for Transportation Applications: 2012 Update October 18, 2012 Prepared By: Brian D. James Andrew B. Spisak Revision 4 2 Sponsorship and Acknowledgements This research was conducted under Award Number DE-EE0005236 to the US Department of Energy. The authors wish to thank Dr. Dimitrios Papageorgopoulos and Mr. Jason Marcinkoski of DOE's Office of Energy Efficiency and Renewable Energy (EERE) Fuel Cell Technologies (FCT) Program

  3. Methane conversion for highway fuel use (Methanol Plantship Project). Volume 1. Final report. Resource materials. Report for May 1992-May 1993

    SciTech Connect (OSTI)

    Fink, C.; Jackson, I.; Wright, S.; Booras, P.; Wise, A.

    1997-01-01

    The report presents results from a study undertaken to respond to PL 101-516. The law provided funding for `phase II of the development/design work on a floating methanol production plantship to advance work already completed under phase I of the project, which was authorized by section 152 of the Surface Transportation Act of 1982.` Phase I determined the feasibility of producing large volumes of low-cost methanol aboard a plantship. The report consists of two volumes: the final report FHWA-RD-93-091 and the Executive Summary FHWA-RD-93-092.

  4. Materials issues in solid oxide fuel cell systems

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  5. List of Renewable Fuel Vehicles Incentives | Open Energy Information

    Open Energy Info (EERE)

    Fuels Renewable Fuel Vehicles Other Alternative Fuel Vehicles Refueling Stations Ethanol Methanol Biodiesel No Alternative Fuels Loan Program (Kansas) State Loan Program Kansas...

  6. Alcohol fuels program technical review

    SciTech Connect (OSTI)

    1981-07-01

    The last issue of the Alcohol Fuels Process R/D Newsletter contained a work breakdown structure (WBS) of the SERI Alcohol Fuels Program that stressed the subcontracted portion of the program and discussed the SERI biotechnology in-house program. This issue shows the WBS for the in-house programs and contains highlights for the remaining in-house tasks, that is, methanol production research, alcohol utilization research, and membrane research. The methanol production research activity consists of two elements: development of a pressurized oxygen gasifier and synthesis of catalytic materials to more efficiently convert synthesis gas to methanol and higher alcohols. A report is included (Finegold et al. 1981) that details the experimental apparatus and recent results obtained from the gasifier. The catalysis research is principally directed toward producing novel organometallic compounds for use as a homogeneous catalyst. The utilization research is directed toward the development of novel engine systems that use pure alcohol for fuel. Reforming methanol and ethanol catalytically to produce H/sub 2/ and CO gas for use as a fuel offers performance and efficiency advantages over burning alcohol directly as fuel in an engine. An application of this approach is also detailed at the end of this section. Another area of utilization is the use of fuel cells in transportation. In-house researchers investigating alternate electrolyte systems are exploring the direct and indirect use of alcohols in fuel cells. A workshop is being organized to explore potential applications of fuel cells in the transportation sector. The membrane research group is equipping to evaluate alcohol/water separation membranes and is also establishing cost estimation and energy utilization figures for use in alcohol plant design.

  7. Direct measurement of U-235 in spent fuel rods with Gamma-ray mirrors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruz, J.; Alameda, J.B.; Decker, T.A.; Descalle, M.A.; Fernandez-Perea, M.; Hill, R.M.; Kisner, Roger A; Melin, Alexander M; Patton, Bruce W; Soufli, R.; et al

    2015-01-01

    Direct measurement of plutonium and uranium X-rays and gamma-rays is a highly desirable nondestructive analysis method for the use in reprocessing fuel environments. The high background and intense radiation from spent fuel make direct measurements difficult to implement since the relatively low activity of uranium and plutonium is masked by the high activity from fission products. To overcome this problem, we make use of a grazing incidence optic to selectively reflect K-alpha and K-beta fluorescence of Special Nuclear Materials (SNM) into a high-purity position-sensitive germanium detector and obtain their relative ratios. (C) 2014 Elsevier B.V. All rights reserved.

  8. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  9. Fuel injection characteristics and combustion behavior of a direct-injection stratified-charge engine

    SciTech Connect (OSTI)

    Balles, E.N.; Ekchian, J.A.; Heywood, J.B.

    1984-01-01

    High levels of hydrocarbon emissions during light load operation keep the direct injection stratified charge engine from commercial application. Previous analytical work has identified several possible hydrocarbon emissions mechanisms which can result from poor in-cylinder fuel distribution. Poor fuel distribution can be caused by erratic fuel injection. Experiments conducted on a single cylinder disc engine show a dramatic increase in the cycle to cycle variation in injection characteristics as engine load decreases. This is accompanied by an increase in cycle to cycle variation in combustion behavior suggesting that degradation in combustion results from the degradation in the quality of the injection event. Examination of combustion and injection characteristics on a cycle by cycle basis shows that, at light load, IMEP and heat release do not correlate with the amount of fuel injected into the cylinder. There are strong indications that individual cycles undergo partial or complete misfire.

  10. High-Areal-Density Fuel Assembly in Direct-Drive Cryogenic Implosions

    SciTech Connect (OSTI)

    Sangster, T.C.; Goncharov, V.N.; Radha, P.B.; Smalyuk, V.A.; Betti, R.; Craxton, R.S.; Delettrez, J.A.; Edgell, D.H.; Glebov, V.Yu.; Harding, D.R.; Jacobs-Perkins, D.; Knauer, J.P.; Marshall, F.J.; McCrory, R.L.; McKenty, P.W.; Meyerhofer, D.D.; Regan, S.P.; Seka, W.; Short, R.W.; Skupsky, S.; Soures, J.M.; Stoeckl, C.; Yaakobi, B.

    2008-05-27

    The first observation of ignition-relevant areal-density deuterium from implosions of capsules with cryogenic fuel layers at ignition-relevant adiabats is reported. The experiments were performed on the 60-beam, 30-kJUV OMEGA Laser System [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. Neutron-averaged areal densities of 202+-7 mg/cm^2 and 182+-7 mg/cm^2 (corresponding to estimated peak fuel densities in excess of 100 g/cm^3) were inferred using an 18-kJ direct-drive pulse designed to put the converging fuel on an adiabat of 2.5. These areal densities are in good agreement with the predictions of hydrodynamic simulations indicating that the fuel adiabat can be accurately controlled under ignition-relevant conditions.

  11. THE ECONOMICS OF REPROCESSING vs DIRECT DISPOSAL OF SPENT NUCLEAR FUEL

    SciTech Connect (OSTI)

    Matthew Bunn; Steve Fetter; John P. Holdren; Bob van der Zwaan

    2003-07-01

    This report assesses the economics of reprocessing versus direct disposal of spent nuclear fuel. The breakeven uranium price at which reprocessing spent nuclear fuel from existing light-water reactors (LWRs) and recycling the resulting plutonium and uranium in LWRs would become economic is assessed, using central estimates of the costs of different elements of the nuclear fuel cycle (and other fuel cycle input parameters), for a wide range of range of potential reprocessing prices. Sensitivity analysis is performed, showing that the conclusions reached are robust across a wide range of input parameters. The contribution of direct disposal or reprocessing and recycling to electricity cost is also assessed. The choice of particular central estimates and ranges for the input parameters of the fuel cycle model is justified through a review of the relevant literature. The impact of different fuel cycle approaches on the volume needed for geologic repositories is briefly discussed, as are the issues surrounding the possibility of performing separations and transmutation on spent nuclear fuel to reduce the need for additional repositories. A similar analysis is then performed of the breakeven uranium price at which deploying fast neutron breeder reactors would become competitive compared with a once-through fuel cycle in LWRs, for a range of possible differences in capital cost between LWRs and fast neutron reactors. Sensitivity analysis is again provided, as are an analysis of the contribution to electricity cost, and a justification of the choices of central estimates and ranges for the input parameters. The equations used in the economic model are derived and explained in an appendix. Another appendix assesses the quantities of uranium likely to be recoverable worldwide in the future at a range of different possible future prices.

  12. Performance and emissions of non-petroleum fuels in a direct-injection stratified charge Sl engine

    SciTech Connect (OSTI)

    Freeman, L.E.; Chui, G.K.; Roby, R.J.

    1982-10-01

    Seven fuels derived from coal and shale resources were evaluated using a direct-injection stratified charge engine. The fuels were refined to different degrees which ranged from those typical of gasoline blending components to those similar to current gasoline. Results showed that fuels refined to have properties similar to gasoline performed like gasoline. The less refined fuels were limited in performance. The total carbon monoxide and the hydrocarbon emissions varied with the volatility of the fuels. Most fuels with a higher overall distillation curve generally gave higher hydrocarbon and carbon monoxide emissions. The NOx emissions increased with the percent aromatics in the fuels. The hydrocarbon emissions were found to increase with fuel viscosity. Within the range of engine operation, nearly all the fuels evaluated gave satisfactory performance. With some modifications, even the less refined fuels can be potentially suitable for use in this engine.

  13. Modifications for use of methanol or methanol-gasoline blends in automotive vehicles, September 1976-January 1980

    SciTech Connect (OSTI)

    Patterson, D.J.; Bolt, J.A.; Cole, D.E.

    1980-01-01

    Methanol or blends of methanol and gasoline as automotive fuels may be attractive means for extending the nation's petroleum reserves. The present study was aimed at identifying potential problems and solutions for this use of methanol. Retrofitting of existing vehicles as well as future vehicle design have been considered. The use of ethanol or higher alcohols was not addressed in this study but will be included at a later date. Several potentially serious problems have been identified with methanol use. The most attractive solutions depend upon an integrated combination of vehicle modifications and fuel design. No vehicle problems were found which could not be solved with relatively minor developments of existing technology providing the methanol or blend fuel was itself engineered to ameliorate the solution. Research needs have been identified in the areas of lubrication and materials. These, while apparently solvable, must precede use of methanol or methanol-gasoline blends as motor fuels. Because of the substantial costs and complexities of a retrofitting program, use of methanol must be evaluated in relation to other petroleum-saving alternatives. Future vehicles can be designed initially to operate satisfactorily on these alternate fuels. However a specific fuel composition must be specified around which the future engines and vehicles can be designed.

  14. High efficiency direct fuel cell hybrid power cycle for near term application

    SciTech Connect (OSTI)

    Steinfeld, G.; Maru, H.C.; Sanderson, R.A.

    1996-12-31

    Direct carbonate fuel cells being developed by Energy Research Corporation can generate power at an efficiency approaching 60% LHV. This unique fuel cell technology can consume natural gas and other hydrocarbon based fuels directly without requiring an external reformer, thus providing a simpler and inherently efficient power generation system. A 2 MW power plant demonstration of this technology has been initiated at an installation in the city of Santa Clara in California. A 2.85 MW commercial configuration shown in Figure 1 is presently being developed. The complete plant includes the carbonate fuel cell modules, an inverter, transformer and switchgear, a heat recovery unit and supporting instrument air and water treatment systems. The emission levels for this 2.85 MW plant are projected to be orders of magnitude below existing or proposed standards. The 30 year levelized cost of electricity, without inflation, is projected to be approximately 5{cents}/kW-h assuming capital cost for the carbonate fuel cell system of $1000/kW.

  15. Making the case for direct hydrogen storage in fuel cell vehicles

    SciTech Connect (OSTI)

    James, B.D.; Thomas, C.E.; Baum, G.N.; Lomas, F.D. Jr.; Kuhn, I.F. Jr.

    1997-12-31

    Three obstacles to the introduction of direct hydrogen fuel cell vehicles are often states: (1) inadequate onboard hydrogen storage leading to limited vehicle range; (2) lack of an hydrogen infrastructure, and (3) cost of the entire fuel cell system. This paper will address the first point with analysis of the problem/proposed solutions for the remaining two obstacles addressed in other papers. Results of a recent study conducted by Directed Technologies Inc. will be briefly presented. The study, as part of Ford Motor Company/DOE PEM Fuel Cell Program, examines multiple pure hydrogen onboard storage systems on the basis of weight, volume, cost, and complexity. Compressed gas, liquid, carbon adsorption, and metal hydride storage are all examined with compressed hydrogen storage at 5,000 psia being judged the lowest-risk, highest benefit, near-term option. These results are combined with recent fuel cell vehicle drive cycle simulations to estimate the onboard hydrogen storage requirement for full vehicle range (380 miles on the combined Federal driving schedule). The results indicate that a PNGV-like vehicle using powertrain weights and performance realistically available by the 2004 PNGV target data can achieve approximate fuel economy equivalent to 100 mpg on gasoline (100 mpg{sub eq}) and requires storage of approximately 3.6 kg hydrogen for full vehicle storage quantity allows 5,000 psia onboard storage without altering the vehicle exterior lines or appreciably encroaching on the passenger or trunk compartments.

  16. Promising Fuel Cycle Options for R&D – Results, Insights, and Future Directions

    SciTech Connect (OSTI)

    Wigeland, Roald Arnold

    2015-05-01

    The Fuel Cycle Options (FCO) campaign in the U.S. DOE Fuel Cycle Research & Development Program conducted a detailed evaluation and screening of nuclear fuel cycles. The process for this study was described at the 2014 ICAPP meeting. This paper reports on detailed insights and questions from the results of the study. The comprehensive study identified continuous recycle in fast reactors as the most promising option, using either U/Pu or U/TRU recycle, and potentially in combination with thermal reactors, as reported at the ICAPP 2014 meeting. This paper describes the examination of the results in detail that indicated that there was essentially no difference in benefit between U/Pu and U/TRU recycle, prompting questions about the desirability of pursuing the more complex U/TRU approach given that the estimated greater challenges for development and deployment. The results will be reported from the current effort that further explores what, if any, benefits of TRU recycle (minor actinides in addition to plutonium recycle) may be in order to inform decisions on future R&D directions. The study also identified continuous recycle using thorium-based fuel cycles as potentially promising, in either fast or thermal systems, but with lesser benefit. Detailed examination of these results indicated that the lesser benefit was confined to only a few of the evaluation metrics, identifying the conditions under which thorium-based fuel cycles would be promising to pursue. For the most promising fuel cycles, the FCO is also conducting analyses on the potential transition to such fuel cycles to identify the issues, challenges, and the timing for critical decisions that would need to be made to avoid unnecessary delay in deployment, including investigation of issues such as the effects of a temporary lack of plutonium fuel resources or supporting infrastructure. These studies are placed in the context of an overall analysis approach designed to provide comprehensive information to

  17. Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids

    SciTech Connect (OSTI)

    2010-07-12

    Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

  18. Analysis of ignition behavior in a turbocharged direct injection dual fuel engine using propane and methane as primary fuels

    SciTech Connect (OSTI)

    Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-10-05

    This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (Ω pilot ∼ 0.2-0.6 and Ω overall ∼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant Ω pilot (> 0.5), increasing Ω overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing Ω overall (at constant Ω pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

  19. Comparison of Propane and Methane Performance and Emissions in a Turbocharged Direct Injection Dual Fuel Engine

    SciTech Connect (OSTI)

    Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-01-01

    With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

  20. Electrolytic synthesis of methanol from CO.sub.2

    DOE Patents [OSTI]

    Steinberg, Meyer

    1976-01-01

    A method and system for synthesizing methanol from the CO.sub.2 in air using electric power. The CO.sub.2 is absorbed by a solution of KOH to form K.sub.2 CO.sub.3 which is electrolyzed to produce methanol, a liquid hydrocarbon fuel.

  1. Hydrocarbons from methanol

    SciTech Connect (OSTI)

    Chang, C.D.

    1983-01-01

    During the early 1970s, the conversion of methanol to hydrocarbons emerged as a viable industrial process due to two events: the discovery by workers at Mobil Oil Company of the selective catalytic conversion of methanol to high octane gasoline over zeolite catalysts and the 1973 Arab oil embargo. This survey attempts to comprehensively cover the journal literature and selectively cover the patent literature dealing with the theoretical aspects of the methanol conversion. 178 references. (BLM)

  2. Conceptual design report for a Direct Hydrogen Proton Exchange Membrane Fuel Cell for transportation application

    SciTech Connect (OSTI)

    1995-09-05

    This report presents the conceptual design for a Direct-Hydrogen-Fueled Proton Exchange Membrane (PEM) Fuel Cell System for transportation applications. The design is based on the initial selection of the Chrysler LH sedan as the target vehicle with a 50 kW (gross) PEM Fuel Cell Stack (FCS) as the primary power source, a battery-powered Load Leveling Unit (LLU) for surge power requirements, an on-board hydrogen storage subsystem containing high pressure gaseous storage, a Gas Management Subsystem (GMS) to manage the hydrogen and air supplies for the FCS, and electronic controllers to control the electrical system. The design process has been dedicated to the use of Design-to-Cost (DTC) principles. The Direct Hydrogen-Powered PEM Fuel Cell Stack Hybrid Vehicle (DPHV) system is designed to operate on the Federal Urban Driving Schedule (FUDS) and Hiway Cycles. These cycles have been used to evaluate the vehicle performance with regard to range and hydrogen usage. The major constraints for the DPHV vehicle are vehicle and battery weight, transparency of the power system and drive train to the user, equivalence of fuel and life cycle costs to conventional vehicles, and vehicle range. The energy and power requirements are derived by the capability of the DPHV system to achieve an acceleration from 0 to 60 MPH within 12 seconds, and the capability to achieve and maintain a speed of 55 MPH on a grade of seven percent. The conceptual design for the DPHV vehicle is shown in a figure. A detailed description of the Hydrogen Storage Subsystem is given in section 4. A detailed description of the FCS Subsystem and GMS is given in section 3. A detailed description of the LLU, selection of the LLU energy source, and the power controller designs is given in section 5.

  3. Range Fuels Commercial-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The Range Fuels commercial-scale biorefinery will use a variety of feedstocks to create cellulosic ethanol, methanol, and power.

  4. Transesterification of waste vegetable oil under pulse sonication using ethanol, methanol and ethanol–methanol mixtures

    SciTech Connect (OSTI)

    Martinez-Guerra, Edith; Gude, Veera Gnaneswar

    2014-12-15

    Highlights: • Pulse sonication effect on transesterification of waste vegetable oil was studied. • Effects of ethanol, methanol, and alcohol mixtures on FAMEs yield were evaluated. • Effect of ultrasonic intensity, power density, and its output rates were evaluated. • Alcohol mixtures resulted in higher biodiesel yields due to better solubility. - Abstract: This study reports on the effects of direct pulse sonication and the type of alcohol (methanol and ethanol) on the transesterification reaction of waste vegetable oil without any external heating or mechanical mixing. Biodiesel yields and optimum process conditions for the transesterification reaction involving ethanol, methanol, and ethanol–methanol mixtures were evaluated. The effects of ultrasonic power densities (by varying sample volumes), power output rates (in W), and ultrasonic intensities (by varying the reactor size) were studied for transesterification reaction with ethanol, methanol and ethanol–methanol (50%-50%) mixtures. The optimum process conditions for ethanol or methanol based transesterification reaction of waste vegetable oil were determined as: 9:1 alcohol to oil ratio, 1% wt. catalyst amount, 1–2 min reaction time at a power output rate between 75 and 150 W. It was shown that the transesterification reactions using ethanol–methanol mixtures resulted in biodiesel yields as high as >99% at lower power density and ultrasound intensity when compared to ethanol or methanol based transesterification reactions.

  5. Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.

    SciTech Connect (OSTI)

    Allendorf, Mark D.; Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

    2009-01-01

    The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is

  6. Development of alkaline fuel cells.

    SciTech Connect (OSTI)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  7. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications. 2009 Update

    SciTech Connect (OSTI)

    James, Brian D.; Kalinoski, Jeffrey A.; Baum, Kevin N.

    2010-01-01

    This report is the third annual update of a comprehensive automotive fuel cell cost analysis. It contains estimates for material and manufacturing cost of complete 80 kWnet direct hydrogen proton exchange membrane fuel cell systems suitable for powering light duty automobiles.

  8. Mass Production Cost Estimation For Direct H2 PEM Fuel Cell Systesm for Automotive Applications. 2010 Update

    SciTech Connect (OSTI)

    James, Brian D.; Kalinoski, Jeffrey A.; Baum, Kevin N.

    2010-09-30

    This report is the fourth annual update of a comprehensive automotive fuel cell cost analysis. It contains estimates for material and manufacturing costs of complete 80 kWnet direct-hydrogen proton exchange membrane fuel cell systems suitable for powering light-duty automobiles.

  9. Combined Power Generation and Carbon Sequestration Using Direct FuelCell

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2006-03-01

    The unique chemistry of carbonate fuel cell offers an innovative approach for separation of carbon dioxide from greenhouse gases (GHG). The carbonate fuel cell system also produces electric power at high efficiency. The simultaneous generation of power and sequestration of greenhouse gases offer an attractive scenario for re-powering the existing coal-fueled power plants, in which the carbonate fuel cell would separate the carbon dioxide from the flue gas and would generate additional pollutant-free electric power. Development of this system is concurrent with emergence of Direct FuelCell{reg_sign} (DFC{reg_sign}) technology for generation of electric power from fossil fuels. DFC is based on carbonate fuel cell featuring internal reforming. This technology has been deployed in MW-scale power plants and is readily available as a manufactured product. This final report describes the results of the conceptualization study conducted to assess the DFC-based system concept for separation of CO2 from GHG. Design and development studies were focused on integration of the DFC systems with coal-based power plants, which emit large amounts of GHG. In parallel to the system design and simulation activities, operation of laboratory scale DFC verified the technical concept and provided input to the design activity. The system was studied to determine its effectiveness in capturing more than ninety percent of CO2 from the flue gases. Cost analysis was performed to estimate the change in cost of electricity for a 200 MW pulverized coal boiler steam cycle plant retrofitted with the DFC-based CO2 separation system producing an additional 127 MW of electric power. The cost increments as percentage of levelized cost of electricity were estimated for a range of separation plant installations per year and a range of natural gas cost. The parametric envelope meeting the goal (<20% increase in COE) was identified. Results of this feasibility study indicated that DFC-based separation

  10. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2009 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report is the third annual update of a comprehensive automotive fuel cell cost analysis. It contains estimates for material and manufacturing cost of complete 80 kWnet direct hydrogen proton exch

  11. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application: 2009 Update

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report is the third annual update of a comprehensive automotive fuel cell cost analysis conducted by Directed Technologies (DTI), under contract to the US Department of Energy (DOE).

  12. Technology development goals for automotive fuel cell power systems. Final report, Appendix B-2

    SciTech Connect (OSTI)

    Thomas, C.E.; James, B.D.

    1995-07-01

    Directed Technologies, Inc. has previously submitted a detailed technical assessment and concept design for a mid-size, five-passenger fuel cell electric vehicle (FCEV), under contract to the Argonne National Laboratory. As a supplement to that contract, DTI has reviewed the literature and conducted a preliminary evaluation of two energy carriers for the FCEV: hydrogen and methanol. This report compares the estimated fuel efficiency, cost of producing and delivering the fuel, and the resultant life cycle costs of the FCEV when fueled directly by hydrogen and when fueled by methanol with on-board reforming to produce the required hydrogen-rich gas for the fuel cell. This work will be supplemented and expanded under the Ford contract with the Department of Energy to develop the FCEV and its fuel infrastructure.

  13. Methanol production from eucalyptus wood chips. Attachment V. The Florida eucalyptus energy farm: environmental impacts

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01

    The overall environmental impact of the eucalyptus to methanol energy system in Florida is assessed. The environmental impacts associated with the following steps of the process are considered: (1) the greenhouse and laboratory; (2) the eucalyptus plantation; (3) transporting the mature logs; (4) the hammermill; and (5) the methanol synthesis plant. Next, the environmental effects of methanol as an undiluted motor fuel, methanol as a gasoline blend, and gasoline as motor fuels are compared. Finally, the environmental effects of the eucalypt gasification/methanol synthesis system are compared to the coal liquefaction and conversion system.

  14. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  15. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1990-01-01

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  16. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1991-02-12

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  17. Startup, testing, and operation of the Santa Clara 2MW direct carbonate fuel cell demonstration plant

    SciTech Connect (OSTI)

    Skok, A.J.; Leo, A.J.; O`Shea, T.P.

    1996-12-31

    The Santa Clara Demonstration Project (SCDP) is a collaboration between several utility organizations, Fuel Cell Engineering Corporation (FCE), and the U.S. Dept. Of Energy aimed at the demonstration of Energy Research Corporation`s (ERC) direct carbonate fuel cell (DFC) technology. ERC has been pursuing the development of the DFC for commercialization near the end of this decade, and this project is an integral part of the ERC commercialization effort. The objective of the Santa Clara Demonstration Project is to provide the first full, commercial scale demonstration of this technology. The approach ERC has taken in the commercialization of the DFC is described in detail elsewhere. An aggressive core technology development program is in place which is focused by ongoing interaction with customers and vendors to optimize the design of the commercial power plant. ERC has selected a 2.85 MW power plant unit for initial market entry. Two ERC subsidiaries are supporting the commercialization effort: the Fuel Cell Manufacturing Corporation (FCMC) and the Fuel Cell Engineering Corporation (FCE). FCMC manufactures carbonate stacks and multi-stack modules, currently from its production facility in Torrington, CT. FCE is responsible for power plant design, integration of all subsystems, sales/marketing, and client services. FCE is serving as the prime contractor for the design, construction, and testing of the SCDP Plant. FCMC has manufactured the multi-stack submodules used in the DC power section of the plant. Fluor Daniel Inc. (FDI) served as the architect-engineer subcontractor for the design and construction of the plant and provided support to the design of the multi-stack submodules. FDI is also assisting the ERC companies in commercial power plant design.

  18. Assessment of PNGV fuels infrastructure. Phase 1 report: Additional capital needs and fuel-cycle energy and emissions impacts

    SciTech Connect (OSTI)

    Wang, M.; Stork, K.; Vyas, A.; Mintz, M.; Singh, M.; Johnson, L.

    1997-01-01

    This report presents the methodologies and results of Argonne`s assessment of additional capital needs and the fuel-cycle energy and emissions impacts of using six different fuels in the vehicles with tripled fuel economy (3X vehicles) that the Partnership for a New Generation of Vehicles is currently investigating. The six fuels included in this study are reformulated gasoline, low-sulfur diesel, methanol, ethanol, dimethyl ether, and hydrogen. Reformulated gasoline, methanol, and ethanol are assumed to be burned in spark-ignition, direct-injection engines. Diesel and dimethyl ether are assumed to be burned in compression-ignition, direct-injection engines. Hydrogen and methanol are assumed to be used in fuel-cell vehicles. The authors have analyzed fuels infrastructure impacts under a 3X vehicle low market share scenario and a high market share scenario. The assessment shows that if 3X vehicles are mass-introduced, a considerable amount of capital investment will be needed to build new fuel production plants and to establish distribution infrastructure for methanol, ethanol, dimethyl ether, and hydrogen. Capital needs for production facilities will far exceed those for distribution infrastructure. Among the four fuels, hydrogen will bear the largest capital needs. The fuel efficiency gain by 3X vehicles translates directly into reductions in total energy demand, fossil energy demand, and CO{sub 2} emissions. The combination of fuel substitution and fuel efficiency results in substantial petroleum displacement and large reductions in emissions of nitrogen oxide, carbon monoxide, volatile organic compounds, sulfur oxide, and particulate matter of size smaller than 10 microns.

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Use and Vehicle Acquisition Requirements State agency fleets with more than 15 vehicles, excluding emergency and law enforcement vehicles, may not purchase or lease a motor vehicle unless the vehicle uses compressed or liquefied natural gas, propane, ethanol or fuel blends of at least 85% ethanol (E85), methanol or fuel blends of at least 85% methanol (M85), biodiesel or fuel blends of at least 20% biodiesel (B20), or electricity (including plug-in hybrid electric vehicles).

  20. Fuel-cycle energy and emissions impacts of tripled fuel-economy vehicles

    SciTech Connect (OSTI)

    Mintz, M. M.; Vyas, A. D.; Wang, M. Q.

    1997-12-18

    This paper presents estimates of the fill fuel-cycle energy and emissions impacts of light-duty vehicles with tripled fuel economy (3X vehicles) as currently being developed by the Partnership for a New Generation of Vehicles (PNGV). Seven engine and fuel combinations were analyzed: reformulated gasoline, methanol, and ethanol in spark-ignition, direct-injection engines; low-sulfur diesel and dimethyl ether in compression-ignition, direct-injection engines; and hydrogen and methanol in fuel-cell vehicles. Results were obtained for three scenarios: a Reference Scenario without PNGVs, a High Market Share Scenario in which PNGVs account for 60% of new light-duty vehicle sales by 2030, and a Low Market Share Scenario in which PNGVs account for half as many sales by 2030. Under the higher of these two, the fuel-efficiency gain by 3X vehicles translated directly into a nearly 50% reduction in total energy demand, petroleum demand, and carbon dioxide emissions. The combination of fuel substitution and fuel efficiency resulted in substantial reductions in emissions of nitrogen oxide (NO{sub x}), carbon monoxide (CO), volatile organic compounds (VOCs), sulfur oxide, (SO{sub x}), and particulate matter smaller than 10 microns (PM{sub 10}) for most of the engine-fuel combinations examined. The key exceptions were diesel- and ethanol-fueled vehicles for which PM{sub 10} emissions increased.

  1. Fuel Cells for Portable Power: 1. Introduction to DMFCs; 2. Advanced Materials and Concepts for Portable Power Fuel Cells

    SciTech Connect (OSTI)

    Zelenay, Piotr

    2012-07-16

    Thanks to generally less stringent cost constraints, portable power fuel cells, the direct methanol fuel cell (DMFC) in particular, promise earlier market penetration than higher power polymer electrolyte fuel cells (PEFCs) for the automotive and stationary applications. However, a large-scale commercialization of DMFC-based power systems beyond niche applications already targeted by developers will depend on improvements to fuel cell performance and performance durability as well as on the reduction in cost, especially of the portable systems on the higher end of the power spectrum (100-250 W). In this part of the webinar, we will focus on the development of advanced materials (catalysts, membranes, electrode structures, and membrane electrode assemblies) and fuel cell operating concepts capable of fulfilling two key targets for portable power systems: the system cost of $5/W and overall fuel conversion efficiency of 2.0-2.5 kWh/L. Presented research will concentrate on the development of new methanol oxidation catalysts, hydrocarbon membranes with reduced methanol crossover, and improvements to component durability. Time permitted, we will also present a few highlights from the development of electrocatalysts for the oxidation of two alternative fuels for the direct-feed fuel cells: ethanol and dimethyl ether.

  2. Direct Experimental Evaluation of the Grain Boundaries Gas Content in PWR fuels: New Insight and Perspective of the ADAGIO Technique

    SciTech Connect (OSTI)

    Pontillon, Y.; Noirot, J.; Caillot, L.

    2007-07-01

    Over the last decades, many analytical experiments (in-pile and out-of-pile) have underlined the active role of the inter-granular gases on the global fuel transient behavior under accidental conditions such as RIA and/or LOCA. In parallel, the improvement of fission gas release modeling in nuclear fuel performance codes needs direct experimental determination/validation regarding the local gas distribution inside the fuel sample. In this context, an experimental program, called 'ADAGIO' (French acronym for Discriminating Analysis of Accumulation of Inter-granular and Occluded Gas), has been initiated through a joint action of CEA, EDF and AREVA NP in order to develop a new device/technique for quantitative and direct measurement of local fission gas distribution within an irradiated fuel pellet. ADAGIO technique is based on the fact that fission gas inventory (intra and inter-granular parts) can be distinguished by controlled fuel oxidation, since grain boundaries oxidize faster than the bulk. The purpose of the current paper is to present both the methodology and the associated results of the ADAGIO program performed at CEA. It has been divided into two main parts: (i) feasibility (UO{sub 2} and MOX fuels), (ii) application on high burn up UO{sub 2} fuel. (authors)

  3. Introduction to DMFCs - Advanced Materials and Concepts for Portable Power Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Webinar July 17, 2012 1 Introduction to DMFCs Advanced Materials and Concepts for Portable Power Fuel Cells Piotr Zelenay Los Alamos National Laboratory, Los Alamos, New Mexico 87545, U.S.A. Fuel Cell Technologies Program Webinar - July 17, 2012 - The Fuel Choice P. Piela and P. Zelenay, Fuel Cell Review, 1, 17, 2004 Fuel Cell Technologies Program Webinar - July 17, 2012 2 Direct Methanol Fuel Cell Anode: Pt-Ru Cathode: Pt Membrane: e.g. Nafion ® 115 e - CH 3 OH H + H 2 O CH 3 OH

  4. Laboratory Directed Research and Development (LDRD) on Mono-uranium Nitride Fuel Development for SSTAR and Space Applications

    SciTech Connect (OSTI)

    Choi, J; Ebbinghaus, B; Meiers, T; Ahn, J

    2006-02-09

    The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development (LDRD) Project on Mono-Uranium Nitride Fuel Development for SSTAR and Space Applications. In fact, three out of the six GEN-IV reactor concepts consider using the nitride-based fuel, as shown in Table 1. SSTAR is a liquid-metal cooled, fast reactor. It uses nitride fuel in a sealed reactor vessel that could be shipped to the user and returned to the supplier having never been opened in its long operating lifetime. This sealed reactor concept envisions no fuel refueling nor on-site storage of spent fuel, and as a result, can greatly enhance proliferation resistance. However, the requirement for a sealed, long-life core imposes great challenges to research and development of the nitride fuel and its cladding. Cladding is an important interface between the fuel and coolant and a barrier to prevent fission gas release during normal and accidental conditions. In fabricating the nitride fuel rods and assemblies, the cladding material should be selected based on its the coolant-side corrosion properties, the chemical/physical interaction with the nitride fuel, as well as their thermal and neutronic properties. The US NASA space reactor, the

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85% or more of alcohol with gasoline; natural gas and liquid fuels domestically produced from natural gas; liquefied petroleum gas (propane); coal-derived liquid fuels; hydrogen; electricity; pure biodiesel (B100); fuels, other than alcohol, derived from biological materials; and P-Series fuels. In addition, the U.S.

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Labeling Requirements Alternative fuel dispensers must be labeled with information to help consumers make informed decisions about fueling a vehicle, including the name of the fuel and the minimum percentage of the main component of the fuel. Labels may also list the percentage of other fuel components. This requirement applies to, but is not limited to, the following fuel types: methanol, denatured ethanol, and/or other alcohols; mixtures containing 85% or more by volume of

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition and Specifications Alternative fuels include biofuel, ethanol, methanol, hydrogen, coal-derived liquid fuels, electricity, natural gas, propane gas, or a synthetic transportation fuel. Biofuel is defined as a renewable, biodegradable, combustible liquid or gaseous fuel derived from biomass or other renewable resources that can be used as transportation fuel, combustion fuel, or refinery feedstock and that meets ASTM specifications and federal quality requirements for

  8. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  9. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  10. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  11. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  12. GREET 1.5 - transportation fuel-cycle model - Vol. 1 : methodology...

    Office of Scientific and Technical Information (OSTI)

    ... SYSTEMS; FUEL CONSUMPTION; ETHERS; GREENHOUSE GASES; LIQUEFIED NATURAL GAS; AIR POLLUTION; FLY ASH; DIESEL FUELS; GASOLINE; LIQUEFIED PETROLEUM GASES; METHANOL; FUEL ...

  13. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications. Hydrogen vehicle safety report

    SciTech Connect (OSTI)

    Thomas, C.E.

    1997-05-01

    This report reviews the safety characteristics of hydrogen as an energy carrier for a fuel cell vehicle (FCV), with emphasis on high pressure gaseous hydrogen onboard storage. The authors consider normal operation of the vehicle in addition to refueling, collisions, operation in tunnels, and storage in garages. They identify the most likely risks and failure modes leading to hazardous conditions, and provide potential countermeasures in the vehicle design to prevent or substantially reduce the consequences of each plausible failure mode. They then compare the risks of hydrogen with those of more common motor vehicle fuels including gasoline, propane, and natural gas.

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium

  15. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  16. Fuel economy and range estimates for fuel cell powered automobiles

    SciTech Connect (OSTI)

    Steinbugler, M.; Ogden, J.

    1996-12-31

    While a number of automotive fuel cell applications have been demonstrated, including a golf cart, buses, and a van, these systems and others that have been proposed have utilized differing configurations ranging from direct hydrogen fuel cell-only power plants to fuel cell/battery hybrids operating on reformed methanol. To date there is no clear consensus on which configuration, from among the possible combinations of fuel cell, peaking device, and fuel type, is the most likely to be successfully commercialized. System simplicity favors direct hydrogen fuel cell vehicles, but infrastructure is lacking. Infrastructure favors a system using a liquid fuel with a fuel processor, but system integration and performance issues remain. A number of studies have analyzed particular configurations on either a system or vehicle scale. The objective of this work is to estimate, within a consistent framework, fuel economies and ranges for a variety of configurations using flexible models with the goal of identifying the most promising configurations and the most important areas for further research and development.

  17. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect (OSTI)

    Andile B. Mzinyati

    2007-09-15

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High Occupancy Vehicle (HOV) Lane Exemption States are allowed to exempt certified alternative fuel vehicles (AFVs) and plug-in electric vehicles (PEVs) from HOV lane requirements within the state. Eligible AFVs are defined as vehicles operating solely on methanol, denatured ethanol, or other alcohols; a mixture containing at least 85% methanol, denatured ethanol, or other alcohols; natural gas, propane, hydrogen, or coal derived liquid fuels; or fuels derived from biological materials. PEVs are

  19. The methanol industry`s missed opportunities

    SciTech Connect (OSTI)

    Stokes, C.A.

    1995-12-31

    Throughout its history the methanol industry has been backward in research and development and in industry cooperation on public image and regulatory matters. It has been extremely reticent as to the virtue of its product for new uses, especially for motor fuel. While this is perhaps understandable looking back, it is inexcusable looking forward. The industry needs to cooperate on a worldwide basis in research and market development, on the one hand, and in image-building and political influence, on the other, staying, of course, within the US and European and other regional antitrust regulations. Unless the industry develops the motor fuel market, and especially the exciting new approach through fuel cell operated EVs, to siphon off incremental capacity and keep plants running at 90% or more of capacity, it will continue to live in a price roller-coaster climate. A few low-cost producers will do reasonably well and the rest will just get along or drop out here and there along the way, as in the past. Having come so far from such a humble beginning, it is a shame not to realize the full potential that is clearly there: a potential to nearly double sales dollars without new plants and to produce from a plentiful resource, at least for the next half-century, all the methanol that can be imagined to be needed. Beyond that the industry can turn to renewable energy--the sun--via biomass growth, to make their product. In so doing, it can perhaps apply methanol as a plant growth stimulant, in effect making the product fully self-sustainable. The world needs to know what methanol can do to provide--economically and reliably--the things upon which a better life rests.

  20. Fuel cell development for transportation: Catalyst development

    SciTech Connect (OSTI)

    Doddapaneni, N.; Ingersoll, D.

    1996-12-31

    Fuel cells are being considered as alternative power sources for transportation and stationary applications. The degradation of commonly used electrode catalysts (e.g. Pt, Ag, and others) and corrosion of carbon substrates are making commercialization of fuel cells incorporating present day technologies economically problematic. Furthermore, due to the instability of the Pt catalyst, the performance of fuel cells declines on long-term operation. When methanol is used as the fuel, a voltage drop, as well as significant thermal management problems can be encountered, the later being due to chemical oxidation of methanol at the platinized carbon at the cathode. Though extensive work was conducted on platinized electrodes for both the oxidation and reduction reactions, due to the problems mentioned above, fuel cells have not been fully developed for widespread commercial use. Several investigators have previously evaluated metal macrocyclic complexes as alternative catalysts to Pt and Pt/Ru in fuel cells. Unfortunately, though they have demonstrated catalytic activity, these materials were found to be unstable on long term use in the fuel cell environment. In order to improve the long-term stability of metal macrocyclic complexes, we have chemically bonded these complexes to the carbon substrate, thereby enhancing their catalytic activity as well as their chemical stability in the fuel cell environment. We have designed, synthesized, and evaluated these catalysts for O{sub 2} reduction, H{sub 2} oxidation, and direct methanol oxidation in Proton Exchange Membrane (PEM) and aqueous carbonate fuel cells. These catalysts exhibited good catalytic activity and long-term stability. In this paper we confine our discussion to the initial performance results of some of these catalysts in H{sub 2}/O{sub 2} PEM fuel cells, including their long-term performance characteristics as well as CO poisoning effects on these catalysts.

  1. Analysis Models and Tools: Systems Analysis of Hydrogen and Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel cells can efficiently produce electricity from a number of domestic fuels, including bio-gas, natural gas, propane, methanol, diesel, and hydrogen. Compared with traditional ...

  2. List of Renewable Transportation Fuels Incentives | Open Energy...

    Open Energy Info (EERE)

    Wind Biomass Renewable Transportation Fuels Fuel Cells Ground Source Heat Pumps Ethanol Methanol Biodiesel No Community Energy Project Grants (Michigan) State Grant Program...

  3. Directed assembly of nanoparticles with capping ligands into...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are novel fuel membranes, solar photovoltaiccells, efficient design of ethanol or methanol based fuel cells, new materials for carbon dioxide storage, catalyticand...

  4. Direct Investigations of the Immobilization of Radionuclides in the Alteration Products of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Peter C. Burns; Robert J. Finch; David J. Wronkiewicz

    2004-12-27

    Safe disposal of the nation's nuclear waste in a geological repository involves unique scientific and engineering challenges owing to the very long-lived radioactivity of the waste. The repository must retain a variety of radionuclides that have vastly different chemical characters for several thousand years. Most of the radioactivity that will be housed in the proposed repository at Yucca Mountain will be associated with spent nuclear fuel, much of which is derived from commercial reactors. DOE is custodian of approximately 8000 tons of spent nuclear fuel that is also intended for eventual disposal in a geological repository. Unlike the spent fuel from commercial reactors, the DOE fuel is diverse in composition with more than 250 varieties. Safe disposal of spent fuel requires a detailed knowledge of its long-term behavior under repository conditions, as well as the fate of radionuclides released from the spent fuel as waste containers are breached.

  5. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    SciTech Connect (OSTI)

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  6. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets

    SciTech Connect (OSTI)

    Mahadevan, K.; Judd, K.; Stone, H.; Zewatsky, J.; Thomas, A.; Mahy, H.; Paul, D.

    2007-04-15

    This document provides information about near-term markets (such as for forklifts and telecommunications) for proton exchange membrane fuel cells.

  7. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document provides information about near-term markets (such as for forklifts and telecommunications) for proton exchange membrane fuel cells.

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... * Smaller compressor * No expander PEM Fuel Cell Stack * Abridged to 2 cells (from 186) ... Last Year Current Technology 500 000 SystemsYear Current Technology, 500,000 ...

  9. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  10. 2007 Fuel Cell Technologies Market Report

    SciTech Connect (OSTI)

    McMurphy, K.

    2009-07-01

    The fuel cell industry, which has experienced continued increases in sales, is an emerging clean energy industry with the potential for significant growth in the stationary, portable, and transportation sectors. Fuel cells produce electricity in a highly efficient electrochemical process from a variety of fuels with low to zero emissions. This report describes data compiled in 2008 on trends in the fuel cell industry for 2007 with some comparison to two previous years. The report begins with a discussion of worldwide trends in units shipped and financing for the fuel cell industry for 2007. It continues by focusing on the North American and U.S. markets. After providing this industry-wide overview, the report identifies trends for each of the major fuel cell applications -- stationary power, portable power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC), phosphoric acid fuel cell (PAFC), and direct-methanol fuel cell (DMFC) -- used for these applications.

  11. Evaluation of M85-fueled 1987 turbo Buick regals. Technical report

    SciTech Connect (OSTI)

    Blair, D.M.

    1987-12-01

    This report describes emission testing conducted at the EPA Motor Vehicle Emission Laboratory on two turbocharged Buick Regals which were converted to use M-85 fuel (methanol). These vehicles, converted to use methanol fuel, have the potential to create a consumer interest in methanol-fueled or flexible-fueled vehicles due to the increased performance possible when using methanol fuel in a turbocharged engine.

  12. Direct fired reciprocating engine and bottoming high temperature fuel cell hybrid

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Holcombe, Norman T.

    2006-02-07

    A system of a fuel cell bottoming an internal combustion engine. The engine exhaust gas may be combined in varying degrees with air and fed as input to a fuel cell. Reformer and oxidizers may be combined with heat exchangers to accommodate rich and lean burn conditions in the engine in peaking and base load conditions without producing high concentrations of harmful emissions.

  13. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures

    SciTech Connect (OSTI)

    Waller, F.J.

    1997-11-01

    Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

  14. Fuel cell integrated with steam reformer

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

    1987-01-01

    A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

  15. Directions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Directions Directions to HAZMAT Challenge LANL's HAZMAT Reesponse Ready Room and Training Facility are ready to welcome this year's Challengers Technical Area 64 - HAZMAT Response...

  16. Direct Hydrogen PEMFC Manufacturing Cost Estimation for Automotive Applications: Fuel Cell Tech Team Review

    Broader source: Energy.gov [DOE]

    This presentation reports on direct hydrogen PEMFC manufacturing cost estimation for automotive applications.

  17. Progress on Establishing the Feasibility of Lead Slowing Down Spectroscopy for Direct Measurement of Plutonium in Used Fuel

    SciTech Connect (OSTI)

    Kulisek, Jonathan A.; Anderson, Kevin K.; Bowyer, Sonya M.; Casella, Andrew M.; Gesh, Christopher J.; Smith, L. E.; Gavron, A.; Devlin, M.; O'Donnell, J. M.; Haight, R. C.; Danon, Yaron; Becker, Bjorn; Imel, G. R.; Beller, D.

    2012-07-19

    Developing a method for the accurate, direct, and independent assay of the fissile isotopes in bulk materials (such as used fuel) of next-generation domestic nuclear fuel cycles is a goal of the Office of Nuclear Energy, Fuel Cycle R&D, Material Protection and Control Technology (MPACT) Campaign. To meet this goal, MPACT continues to support a multi-institutional collaboration to address the feasibility of Lead Slowing Down Spectroscopy (LSDS) as an active nondestructive assay method that has the potential to provide independent, direct measurement of Pu and U isotopic masses in used fuel with an uncertainty considerably lower than the approximately 10% typical of today’s confirmatory assay methods. An LSDS is comprised of a stack of lead (typically 1-6 m3) in which materials to be measured are placed in the lead and a pulse of neutrons is injected. The neutrons in this pulse lose energy due to inelastic and (subsequently) elastic scattering and the average energy of the neutrons decreases as the time increases by a well-defined relationship. In the interrogation energy region (~0.1-1000 eV) the neutrons have little energy spread (~30%) about the average neutron energy. Due to this characteristic, the energy of the (assay) neutrons can then be determined by measuring the time elapsed since the neutron pulse. By measuring the induced fission neutrons emitted from the used fuel, it is possible to determine isotopic-mass content by unfolding the unique structure of isotopic resonances across the interrogation energy region. This paper will present efforts on the development of time-spectral analysis algorithms, fast neutron detector advances, and validation and testing measurements.

  18. A comparative experimental and computational study of methanol, ethanol, and n-butanol flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N.; Westbrook, Charles K.

    2010-10-15

    Laminar flame speeds and extinction strain rates of premixed methanol, ethanol, and n-butanol flames were determined experimentally in the counterflow configuration at atmospheric pressure and elevated unburned mixture temperatures. Additional measurements were conducted also to determine the laminar flame speeds of their n-alkane/air counterparts, namely methane, ethane, and n-butane in order to compare the effect of alkane and alcohol molecular structures on high-temperature flame kinetics. For both propagation and extinction experiments the flow velocities were determined using the digital particle image velocimetry method. Laminar flame speeds were derived through a non-linear extrapolation approach based on direct numerical simulations of the experiments. Two recently developed detailed kinetics models of n-butanol oxidation were used to simulate the experiments. The experimental results revealed that laminar flame speeds of ethanol/air and n-butanol/air flames are similar to those of their n-alkane/air counterparts, and that methane/air flames have consistently lower laminar flame speeds than methanol/air flames. The laminar flame speeds of methanol/air flames are considerably higher compared to both ethanol/air and n-butanol/air flames under fuel-rich conditions. Numerical simulations of n-butanol/air freely propagating flames, revealed discrepancies between the two kinetic models regarding the consumption pathways of n-butanol and its intermediates. (author)

  19. COMMERCIAL-SCALE DEMONSTRATION OF THE LIQUID PHASE METHANOL (LPMEOH) PROCESS

    SciTech Connect (OSTI)

    E.C. Heydorn; B.W. Diamond; R.D. Lilly

    2003-06-01

    This project, which was sponsored by the U.S. Department of Energy (DOE) under the Clean Coal Technology Program to demonstrate the production of methanol from coal-derived synthesis gas (syngas), has completed the 69-month operating phase of the program. The purpose of this Final Report for the ''Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process'' is to provide the public with details on the performance and economics of the technology. The LPMEOH{trademark} Demonstration Project was a $213.7 million cooperative agreement between the DOE and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The DOE's cost share was $92,708,370 with the remaining funds coming from the Partnership. The LPMEOH{trademark} demonstration unit is located at the Eastman Chemical Company (Eastman) chemicals-from-coal complex in Kingsport, Tennessee. The technology was the product of a cooperative development effort by Air Products and Chemicals, Inc. (Air Products) and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} Process is ideally suited for directly processing gases produced by modern coal gasifiers. Originally tested at the Alternative Fuels Development Unit (AFDU), a small, DOE-owned process development facility in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the methanol synthesis reaction to proceed at higher rates. The LPMEOH{trademark} Demonstration Project accomplished the objectives set out in the Cooperative Agreement with DOE for this Clean Coal Technology project

  20. Direct use of natural gas (methane) for conversion of carbonaceous raw materials to fuels and chemical feedstocks

    SciTech Connect (OSTI)

    Steinberg, M.

    1985-04-01

    It appears that natural gas is almost as abundant as petroleum, if not more so, as a natural resource in many parts of the world. Because of its rich hydrogen content, it is probably the lowest cost source of hydrogen wherever it is available. The most abundant fossil energy resource in the world appears to be coal, and the most abundant renewable resource appears to be biomass (trees and plants), both of which contain a deficiency of hydrogen. It is proposed to use natural gas in conjunction with coal and biomass to produce the preferred liquid fuel simulating petroleum products. Processes are described which include methanolysis that is the direct use of methane for gasification and liquefaction of coal and biomass, and for desulfurization of coal derived liquid and gases. The thermal decomposition of methane is described for hydrogen and carbon particulate production. A cyclical process is described for producing a clean particulate carbon from coal for use in a carbon-water-fuel-mix as a substitute diesel fuel or premium-grade boiler fuel. The hydrogen from methane can be used for flash hydropyrolysis or can be used to produce ammonia fertilizer. 7 refs., 3 figs., 5 tabs.

  1. Power conversion and quality of the Santa Clara 2 MW direct carbonate fuel cell demonstration plant

    SciTech Connect (OSTI)

    Skok, A.J.; Abueg, R.Z.; Schwartz, P.

    1996-12-31

    The Santa Clara Demonstration Project (SCDP) is the first application of a commercial-scale carbonate fuel cell power plant on a US electric utility system. It is also the largest fuel cell power plant ever operated in the United States. The 2MW plant, located in Santa Clara, California, utilizes carbonate fuel cell technology developed by Energy Research Corporation (ERC) of Danbury, Connecticut. The ultimate goal of a fuel cell power plant is to deliver usable power into an electrical distribution system. The power conversion sub-system does this for the Santa Clara Demonstration Plant. A description of this sub-system and its capabilities follows. The sub-system has demonstrated the capability to deliver real power, reactive power and to absorb reactive power on a utility grid. The sub-system can be operated in the same manner as a conventional rotating generator except with enhanced capabilities for reactive power. Measurements demonstrated the power quality from the plant in various operating modes was high quality utility grade power.

  2. Direction on characterization of fuel debris for defueling process in Fukushima Daiichi Nuclear Power Station

    SciTech Connect (OSTI)

    Yano, Kimihiko; Kitagaki, Toru; Ikeuchi, Hirotomo; Wakui, Ryohei; Higuchi, Hidetoshi; Kaji, Naoya; Koizumi, Kenji; Washiya, Tadahiro

    2013-07-01

    For the decommissioning of Fukushima Daiichi Nuclear Power Station (1F), defueling of the fuel debris in the reactor core of Units 1-3 is planned to start within 10 years. Preferential items in the characterization of the fuel debris were identified for this work, in which the procedure and handling tools were assumed on the basis of information on 1F and experience after the Three Mile Island Unit 2 (TMI-2) accident. The candidates for defueling tools for 1F were selected from among the TMI- 2 defueling tools. It was found that they could be categorized into six groups according to their operating principles. The important properties of the fuel debris for defueling were selected considering the effect of the target materials on the tool performance. The selected properties are shape, size, density, thermal conductivity, heat capacity, melting point, hardness, elastic modulus, and fracture toughness. Of these properties, the mechanical properties (hardness, elastic modulus, fracture toughness) were identified as preferential items, because too few data on these characteristics of fuel debris are available in past severe accident studies. (authors)

  3. Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report is the sixth annual update of a comprehensive automotive fuel cell cost analysis conducted by Strategic Analysis under contract to the U.S. Department of Energy. This 2012 update will cover current status technology updates since the 2011 report, as well as introduce a 2012 bus system analysis considered alongside the automotive system.

  4. Ni modified ceramic anodes for direct-methane solid oxide fuel cells

    DOE Patents [OSTI]

    Xiao, Guoliang; Chen, Fanglin

    2016-01-19

    In accordance with certain embodiments of the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes synthesizing a composition having a perovskite present therein. The method further includes applying the composition on an electrolyte support to form an anode and applying Ni to the composition on the anode.

  5. Directions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Directions Directions Call Hilton Santa Fe Buffalo Thunder at (505) 455-5555 for shuttle information from the airport and downtown Santa Fe. Driving Directions to Hilton Santa Fe Buffalo Thunder Hilton Santa Fe Buffalo Thunder is located 15 minutes north of Santa Fe. Directions from Albuquerque (bypassing downtown Santa Fe) Take Interstate 25 north towards Santa Fe for approximately 50 miles. From Interstate 25, exit right onto the 599 Northbound Bypass for approximately 14 miles and continue to

  6. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what

  7. Engineered Nanostructured MEA Technology for Low Temperature Fuel Cells

    SciTech Connect (OSTI)

    Zhu, Yimin

    2009-07-16

    The objective of this project is to develop a novel catalyst support technology based on unique engineered nanostructures for low temperature fuel cells which: (1) Achieves high catalyst activity and performance; (2) Improves catalyst durability over current technologies; and (3) Reduces catalyst cost. This project is directed at the development of durable catalysts supported by novel support that improves the catalyst utilization and hence reduce the catalyst loading. This project will develop a solid fundamental knowledge base necessary for the synthetic effort while at the same time demonstrating the catalyst advantages in Direct Methanol Fuel Cells (DMFCs).

  8. Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines

    Broader source: Energy.gov [DOE]

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  9. Microbial fuel cell treatment of fuel process wastewater (Patent...

    Office of Scientific and Technical Information (OSTI)

    Microbial fuel cell treatment of fuel process wastewater Title: Microbial fuel cell treatment of fuel process wastewater The present invention is directed to a method for cleansing ...

  10. Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project

    SciTech Connect (OSTI)

    1996-05-01

    The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

  11. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  12. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  13. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  15. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  16. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  17. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 31 for fourth quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  18. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 19 for first quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  19. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 23 for second quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  20. Recovery Act. Demonstration of a Pilot Integrated Biorefinery for the Efficient, Direct Conversion of Biomass to Diesel Fuel

    SciTech Connect (OSTI)

    Schuetzle, Dennis; Tamblyn, Greg; Caldwell, Matt; Hanbury, Orion; Schuetzle, Robert; Rodriguez, Ramer; Johnson, Alex; Deichert, Fred; Jorgensen, Roger; Struble, Doug

    2015-05-12

    The Renewable Energy Institute International, in collaboration with Greyrock Energy and Red Lion Bio-Energy (RLB) has successfully demonstrated operation of a 25 ton per day (tpd) nameplate capacity, pilot, pre-commercial-scale integrated biorefinery (IBR) plant for the direct production of premium, “drop-in”, synthetic fuels from agriculture and forest waste feedstocks using next-generation thermochemical and catalytic conversion technologies. The IBR plant was built and tested at the Energy Center, which is located in the University of Toledo Medical Campus in Toledo, Ohio.

  1. Alternative Fuels Data Center: Biobutanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biobutanol to someone by E-mail Share Alternative Fuels Data Center: Biobutanol on Facebook Tweet about Alternative Fuels Data Center: Biobutanol on Twitter Bookmark Alternative Fuels Data Center: Biobutanol on Google Bookmark Alternative Fuels Data Center: Biobutanol on Delicious Rank Alternative Fuels Data Center: Biobutanol on Digg Find More places to share Alternative Fuels Data Center: Biobutanol on AddThis.com... More in this section... Biobutanol Dimethyl Ether Methanol Renewable

  2. An ecosystem-scale perspective of the net land methanol flux. Synthesis of micrometeorological flux measurements

    SciTech Connect (OSTI)

    Wohlfahrt, G.; Amelynck, C.; Ammann, C.; Arneth, A.; Bamberger, I.; Goldstein, A. H.; Gu, L.; Guenther, A.; Hansel, A.; Heinesch, B.; Holst, T.; Hörtnagl, L.; Karl, T.; Laffineur, Q.; Neftel, A.; McKinney, K.; Munger, J. W.; Pallardy, S. G.; Schade, G. W.; Seco, R.; Schoon, N.

    2015-07-09

    Methanol is the second most abundant volatile organic compound in the troposphere and plays a significant role in atmospheric chemistry. While there is consensus about the dominant role of living plants as the major source and the reaction with OH as the major sink of methanol, global methanol budgets diverge considerably in terms of source/sink estimates, reflecting uncertainties in the approaches used to model and the empirical data used to separately constrain these terms. Here we compiled micrometeorological methanol flux data from eight different study sites and reviewed the corresponding literature in order to provide a first cross-site synthesis of the terrestrial ecosystem-scale methanol exchange and present an independent data-driven view of the land–atmosphere methanol exchange. Our study shows that the controls of plant growth on production, and thus the methanol emission magnitude, as well as stomatal conductance on the hourly methanol emission variability, established at the leaf level, hold across sites at the ecosystem level. Unequivocal evidence for bi-directional methanol exchange at the ecosystem scale is presented. Deposition, which at some sites even exceeds methanol emissions, represents an emerging feature of ecosystem-scale measurements and is likely related to environmental factors favouring the formation of surface wetness. Methanol may adsorb to or dissolve in this surface water and eventually be chemically or biologically removed from it. Management activities in agriculture and forestry are shown to increase local methanol emission by orders of magnitude; however, they are neglected at present in global budgets. While contemporary net land methanol budgets are overall consistent with the grand mean of the micrometeorological methanol flux measurements, we caution that the present approach of simulating methanol emission and deposition separately is prone to opposing systematic errors and does not allow for full advantage to be taken of

  3. An ecosystem-scale perspective of the net land methanol flux. Synthesis of micrometeorological flux measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wohlfahrt, G.; Amelynck, C.; Ammann, C.; Arneth, A.; Bamberger, I.; Goldstein, A. H.; Gu, L.; Guenther, A.; Hansel, A.; Heinesch, B.; et al

    2015-07-09

    Methanol is the second most abundant volatile organic compound in the troposphere and plays a significant role in atmospheric chemistry. While there is consensus about the dominant role of living plants as the major source and the reaction with OH as the major sink of methanol, global methanol budgets diverge considerably in terms of source/sink estimates, reflecting uncertainties in the approaches used to model and the empirical data used to separately constrain these terms. Here we compiled micrometeorological methanol flux data from eight different study sites and reviewed the corresponding literature in order to provide a first cross-site synthesis ofmore » the terrestrial ecosystem-scale methanol exchange and present an independent data-driven view of the land–atmosphere methanol exchange. Our study shows that the controls of plant growth on production, and thus the methanol emission magnitude, as well as stomatal conductance on the hourly methanol emission variability, established at the leaf level, hold across sites at the ecosystem level. Unequivocal evidence for bi-directional methanol exchange at the ecosystem scale is presented. Deposition, which at some sites even exceeds methanol emissions, represents an emerging feature of ecosystem-scale measurements and is likely related to environmental factors favouring the formation of surface wetness. Methanol may adsorb to or dissolve in this surface water and eventually be chemically or biologically removed from it. Management activities in agriculture and forestry are shown to increase local methanol emission by orders of magnitude; however, they are neglected at present in global budgets. While contemporary net land methanol budgets are overall consistent with the grand mean of the micrometeorological methanol flux measurements, we caution that the present approach of simulating methanol emission and deposition separately is prone to opposing systematic errors and does not allow for full advantage to be

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol and Methanol Tax Ethyl alcohol and methyl alcohol motor fuels are taxed at a rate of $0.14 per gallon when used as a motor fuel. Ethyl alcohol is defined as a motor fuel that is typically derived from agricultural products that have been denatured. Methyl alcohol is a motor fuel that is most commonly derived from wood products. (Reference South Dakota Statutes 10-47B-3 and 10-47B-4

  5. Consideration of critically when directly disposing highly enriched spent nuclear fuel in unsaturated tuff: Bounding estimates

    SciTech Connect (OSTI)

    Rechard, R.P.; Tierney, M.S.; Sanchez, L.C.; Martell, M.-A.

    1996-05-01

    This report presents one of 2 approaches (bounding calculations) which were used in a 1994 study to examine the possibility of a criticality in a repository. Bounding probabilities, although rough, point to the difficulty of creating conditions under which a critical mass could be assembled (container corrosion, separation of neutron absorbers from fissile material, collapse or precipitation of fissile material) and how significant the geochemical and hydrologic phenomena are. The study could not conceive of a mechanism consistent with conditions under which an atomic explosion could occur. Should a criticality occur in or near a container in the future, boundary consequence calculations showed that fissions from one critical event (<10{sup 20} fissions, if similar to aqueous and metal accidents and experiments) are quite small compared to the amount of fissions represented by the spent fuel itself. If it is assumed that the containers necessary to hold the highly enriched spent fuel went critical once per day for 1 million years, creating an energy release of about 10{sup 20} fissions, the number of fissions equals about 10{sup 28}, which corresponds to only 1% of the fission inventory in a repository containing 70,000 metric tons of heavy metal, the expected size for the proposed repository at Yucca Mountain, Nevada.

  6. Advanced technologies for co-processing fossil and biomass resources for transportation fuels and power generation

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Y.

    2004-07-01

    Over the past few decades, a number of processes have been proposed or are under development for coprocessing fossil fuel and biomass for transportation fuels and power generation. The paper gives a brief description of the following processes: the Hydrocarb system for converting biomass and other carbonaceous fuels to elemental carbon and hydrogen, methane or methanol; the Hynol process where the second step of the Hydrocarb process is replaced with a methane steam reformer to convert methane to CO and H{sub 2}S without deposition of carbon; the Carnol process where CO{sub 2} from coal and the biomass power plants is reacted with hydrogen to produce methanol; and advanced biomass high efficiency power generator cycle where a continuous plasma methane decomposition reactor (PDR) is used with direct carbon fuel cell to produce power and carbon and hydrogen. 13 refs., 5 figs., 2 tabs.

  7. Deactivation of methanol synthesis catalysts

    SciTech Connect (OSTI)

    Roberts, G.W.; Brown, D.M.; Hsiung, T.H.; Lewnard, J.J. (Air Products and Chemicals, Inc., Allentown, PA (United States))

    1993-08-01

    A novel methanol synthesis process, the liquid-phase methanol (LPMEOH) process, has been developed and scaled up to a nominal 380 kg/h (10 ton/day) pilot plant. The process is based on a gas-sparged slurry reactor instead of a conventional, fixed-bed reactor. The use of slurry reactors, which are essentially gradientless, greatly facilitated the interpretation and quantification of catalyst deactivation phenomena. With a poison-free, CO-rich feedstream, the rate of deactivation of the Cu/ZnO catalyst increased rapidly with temperature. At constant temperature, in the absence of poisons, the decline with time in the rate constant for methanol synthesis correlated with the loss of BET surface area. Iron carbonyl, nickel carbonyl, and carbonyl sulfide are severe and highly specific poisons for methanol-synthesis catalyst. There was a linear relationship between the catalyst activity loss and the concentration of metal or sulfur on the catalyst.

  8. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  9. Methanol tailgas combustor control method

    DOE Patents [OSTI]

    Hart-Predmore, David J.; Pettit, William H.

    2002-01-01

    A method for controlling the power and temperature and fuel source of a combustor in a fuel cell apparatus to supply heat to a fuel processor where the combustor has dual fuel inlet streams including a first fuel stream, and a second fuel stream of anode effluent from the fuel cell and reformate from the fuel processor. In all operating modes, an enthalpy balance is determined by regulating the amount of the first and/or second fuel streams and the quantity of the first air flow stream to support fuel processor power requirements.

  10. Well-to-wheels analysis of fuel-cell vehicle/fuel systems.

    SciTech Connect (OSTI)

    Wang, M.

    2002-01-22

    Major automobile companies worldwide are undertaking vigorous research and development efforts aimed at developing fuel-cell vehicles (FCVs). Proton membrane exchange (PEM)-based FCVs require hydrogen (H{sub 2}) as the fuel-cell (FC) fuel. Because production and distribution infrastructure for H{sub 2} off board FCVs as a transportation fuel does not exist yet, researchers are developing FCVs that can use hydrocarbon fuels, such as methanol (MeOH) and gasoline, for onboard production of H{sub 2} via fuel processors. Direct H{sub 2} FCVs have no vehicular emissions, while FCVs powered by hydrocarbon fuels have near-zero emissions of criteria pollutants and some carbon dioxide (CO{sub 2}) emissions. However, production of H{sub 2} can generate a large amount of emissions and suffer significant energy losses. A complete evaluation of the energy and emission impacts of FCVs requires an analysis of energy use and emissions during all stages, from energy feedstock wells to vehicle wheels--a so-called ''well-to-wheels'' (WTW) analysis. This paper focuses on FCVs powered by several transportation fuels. Gasoline vehicles (GVs) equipped with internal combustion engines (ICEs) are the baseline technology to which FCVs are compared. Table 1 lists the 13 fuel pathways included in this study. Petroleum-to-gasoline (with 30-ppm sulfur [S] content) is the baseline fuel pathway for GVs.

  11. Direct

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct removal of edge-localized pollutant emission in a near-infrared bremsstrahlung measurement J. K. Anderson, a) P. L. Andrew, b) B. E. Chapman, D. Craig, and D. J. Den Hartog Department of Physics, University of Wisconsin, 1150 University Avenue, Madison, Wisconsin 53706 ͑Presented on 10 July 2002͒ Visible and near-infrared electron-ion bremsstrahlung measurements in fusion research devices, used to determine the effective ionic charge (Z eff ), are often plagued by pollutant emission

  12. Market penetration scenarios for fuel cell vehicles

    SciTech Connect (OSTI)

    Thomas, C.E.; James, B.D.; Lomax, F.D. Jr.

    1997-12-31

    Fuel cell vehicles may create the first mass market for hydrogen as an energy carrier. Directed Technologies, Inc., working with the US Department of Energy hydrogen systems analysis team, has developed a time-dependent computer market penetration model. This model estimates the number of fuel cell vehicles that would be purchased over time as a function of their cost and the cost of hydrogen relative to the costs of competing vehicles and fuels. The model then calculates the return on investment for fuel cell vehicle manufacturers and hydrogen fuel suppliers. The model also projects the benefit/cost ratio for government--the ratio of societal benefits such as reduced oil consumption, reduced urban air pollution and reduced greenhouse gas emissions to the government cost for assisting the development of hydrogen energy and fuel cell vehicle technologies. The purpose of this model is to assist industry and government in choosing the best investment strategies to achieve significant return on investment and to maximize benefit/cost ratios. The model can illustrate trends and highlight the sensitivity of market penetration to various parameters such as fuel cell efficiency, cost, weight, and hydrogen cost. It can also illustrate the potential benefits of successful R and D and early demonstration projects. Results will be shown comparing the market penetration and return on investment estimates for direct hydrogen fuel cell vehicles compared to fuel cell vehicles with onboard fuel processors including methanol steam reformers and gasoline partial oxidation systems. Other alternative fueled vehicles including natural gas hybrids, direct injection diesels and hydrogen-powered internal combustion hybrid vehicles will also be analyzed.

  13. General circulation model calculations of the direct radiative forcing by anthropogenic sulfate and fossil-fuel soot aerosol

    SciTech Connect (OSTI)

    Haywood, J.M.; Roberts, D.L.; Slingo, A.

    1997-07-01

    A new radiation code within a general circulation model is used to assess the direct solar and thermal radiative forcing by sulfate aerosol of anthropogenic origin and soot aerosol from fossil-fuel burning. The radiative effects of different aerosol profiles, relative humidity parameterizations, chemical compositions, and internal and external mixtures of the two aerosol types are investigated. The contribution to the radiative forcing from cloudy sky regions is found to be negligible for sulfate aerosol; this is in contrast to recent studies where the cloudy sky contribution was estimated using a method in which the spatial correlation between cloud amount and sulfate burden was ignored. However, the radiative forcing due to fossil-fuel soot aerosol is enhanced in cloudy regions if soot aerosol exists within or above the cloud. The global solar radiative forcing due to sulfate aerosol is estimated to be -0.38 W m{sup -2} and the global thermal radiative forcing is estimated to be +0.01 W m{sup -2}. The hemispheric mean radiative forcings vary by only about 10% for reasonable assumptions about the chemical form of the sulfate aerosol and the relative humidity dependence; the uncertainties in the aerosol loading are far more significant. If a soot/sulfate mass ratio of 0.075 is assumed, then the global solar radiative forcing weakens to -0.18 W m{sup -2} for an external mixture and weakens further for an internal mixture. Additionally, the spatial distribution of the radiative forcing shows strong negative/positive forcing contrasts that may influence the dynamical response of the atmosphere. Although these results are extremely sensitive to the adopted soot/sulfate ratio and the assumed vertical profile, they indicate that fossil-fuel soot aerosol may exert a nonnegligible radiative forcing and emphasize the need to consider each anthropogenic aerosol species. 58 refs., 8 figs., 1 tab.

  14. Energy balances in the production and end-use of methanol derived from coal

    SciTech Connect (OSTI)

    1980-12-10

    Analysis is performed for three combinations of fuels, specifically: net petroleum gain (petroleum only); net premium fuel gain (natural gas and petroleum); and net energy gain (includes all fuels; does not include free energy from sun). The base case selected for evaluation was that of an energy-efficient coal-to-methanol plant located in Montana/Wyoming and using the Lurgi conversion process. The following variations of the base coal-methanol case are also analyzed: gasoline from coal with methanol as an intermediate step (Mobil-M); and methanol from coal (Texaco gasification process). For each process, computations are made for the product methanol as a replacement for unleaded gasoline in a conventional spark ignition engine and as a chemical feedstock. For the purpose of the energy analysis, computations are made for three situations regarding mileage of methanol/ gasoline compared to that of regular unleaded gasoline: mileage of the two fuels equal, mileage 4 percent better with gasohol, and mileage 4 percent worse with gasohol. The standard methodology described for the base case applies to all of the variations.

  15. Electrocatalysts for Alcohol Oxidation in Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electrocatalysts for Alcohol Oxidation in Fuel Cells Brookhaven National Laboratory Contact BNL About This Technology <p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the best commercially available catalyst for methanol oxidation.</p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the

  16. Commercial-scale demonstration of the Liquid Phase Methanol process. Technical progress report number 8, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1996-12-31

    The project involves the construction of an 80,000 gallon per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. Originally tested at a small (10 TPD), DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading.

  17. Final Progress Report: Direct Experiments on the Ocean Disposal of Fossil Fuel CO2.

    SciTech Connect (OSTI)

    James P. Barry; Peter G. Brewer

    2004-05-25

    OAK-B135 This report summarizes activities and results of investigations of the potential environmental consequences of direct injection of carbon dioxide into the deep-sea as a carbon sequestration method. Results of field experiments using small scale in situ releases of liquid CO2 are described in detail. The major conclusions of these experiments are that mortality rates of deep sea biota will vary depending on the concentrations of CO2 in deep ocean waters that result from a carbon sequestration project. Large changes in seawater acidity and carbon dioxide content near CO2 release sites will likely cause significant harm to deep-sea marine life. Smaller changes in seawater chemistry at greater distances from release sites will be less harmful, but may result in significant ecosystem changes.

  18. Fuel Cell Technologies Office Multi-Year Research, Development...

    Broader source: Energy.gov (indexed) [DOE]

    (use of diverse, domestic fuels, including hydrogen, natural gas, biogas, and methanol); reduced air pollution, criteria pollutants, water use; and highly reliable grid support. ...

  19. Evaluation of Ultra Clean Fuels from Natural Gas

    SciTech Connect (OSTI)

    Robert Abbott; Edward Casey; Etop Esen; Douglas Smith; Bruce Burke; Binh Nguyen; Samuel Tam; Paul Worhach; Mahabubul Alam; Juhun Song; James Szybist; Ragini Acharya; Vince Zello; David Morris; Patrick Flynn; Stephen Kirby; Krishan Bhatia; Jeff Gonder; Yun Wang; Wenpeng Liu; Hua Meng; Subramani Velu; Jian-Ping Shen, Weidong Gu; Elise Bickford; Chunshan Song; Chao-Yang Wang; Andre' Boehman

    2006-02-28

    ConocoPhillips, in conjunction with Nexant Inc., Penn State University, and Cummins Engine Co., joined with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) in a cooperative agreement to perform a comprehensive study of new ultra clean fuels (UCFs) produced from remote sources of natural gas. The project study consists of three primary tasks: an environmental Life Cycle Assessment (LCA), a Market Study, and a series of Engine Tests to evaluate the potential markets for Ultra Clean Fuels. The overall objective of DOE's Ultra Clean Transportation Fuels Initiative is to develop and deploy technologies that will produce ultra-clean burning transportation fuels for the 21st century from both petroleum and non-petroleum resources. These fuels will: (1) Enable vehicles to comply with future emission requirements; (2) Be compatible with the existing liquid fuels infrastructure; (3) Enable vehicle efficiencies to be significantly increased, with concomitantly reduced CO{sub 2} emissions; (4) Be obtainable from a fossil resource, alone or in combination with other hydrocarbon materials such as refinery wastes, municipal wastes, biomass, and coal; and (5) Be competitive with current petroleum fuels. The objectives of the ConocoPhillips Ultra Clean Fuels Project are to perform a comprehensive life cycle analysis and to conduct a market study on ultra clean fuels of commercial interest produced from natural gas, and, in addition, perform engine tests for Fisher-Tropsch diesel and methanol in neat, blended or special formulations to obtain data on emissions. This resulting data will be used to optimize fuel compositions and engine operation in order to minimize the release of atmospheric pollutants resulting from the fuel combustion. Development and testing of both direct and indirect methanol fuel cells was to be conducted and the optimum properties of a suitable fuel-grade methanol was to be defined. The results of the study are also applicable

  20. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 6, October 1--December 31, 1995

    SciTech Connect (OSTI)

    1996-12-31

    The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology will be integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading. An off-site product testing program will be conducted to demonstrate the suitability of the methanol product as a transportation fuel and as a fuel for stationary applications for small modular electric power generators for distributed power.

  1. Genome and Transcriptome of Clostridium phytofermentans, Catalyst for the Direct Conversion of Plant Feedstocks to Fuels

    SciTech Connect (OSTI)

    Petit, Elsa; Coppi, Maddalena V.; Hayes, James C.; Tolonen, Andrew C.; Warnick, Thomas; Latouf, William G.; Amisano, Danielle; Biddle, Amy; Mukherjee, Supratim; Ivanova, Natalia; Lykidis, Athanassios; Land, Miriam; Hauser, Loren; Kyrpides, Nikos; Henrissat, Bernard; Lau, Joanne; Schnell, Danny J.; Church, George M.; Leschine, Susan B.; Blanchard, Jeffrey L.

    2015-06-02

    Clostridium phytofermentans was isolated from forest soil and is distinguished by its capacity to directly ferment plant cell wall polysaccharides into ethanol as the primary product, suggesting that it possesses unusual catabolic pathways. The objective of our present study was to understand the molecular mechanisms of biomass conversion to ethanol in a single organism, Clostridium phytofermentans, by analyzing its complete genome and transcriptome during growth on plant carbohydrates. The saccharolytic versatility of C. phytofermentans is reflected in a diversity of genes encoding ATP-binding cassette sugar transporters and glycoside hydrolases, many of which may have been acquired through horizontal gene transfer. These genes are frequently organized as operons that may be controlled individually by the many transcriptional regulators identified in the genome. Preferential ethanol production may be due to high levels of expression of multiple ethanol dehydrogenases and additional pathways maximizing ethanol yield. The genome also encodes three different proteinaceous bacterial microcompartments with the capacity to compartmentalize pathways that divert fermentation intermediates to various products. Lastly, these characteristics make C. phytofermentans an attractive resource for improving the efficiency and speed of biomass conversion to biofuels.

  2. Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)

    SciTech Connect (OSTI)

    Quimby, J.M.

    1992-02-01

    The objective of this contract is to investigate the removal of So{sub x} and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for So{sub x} removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% So{sub x} removal efficiency. This research project is now in the second of a 3 phase (Phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell's, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: Design, procurement, and installation; Shakedown and startup; Reporting. Attempts to validate the concept of electrostatic agglomeration were not possible in the shakedown program before budget constraints halted the program. What was learned was that electrostatic precipitation is feasible in the temperature range of 1600--1800{degrees}F and at pressures above 10 atmospheres.

  3. Genome and Transcriptome of Clostridium phytofermentans, Catalyst for the Direct Conversion of Plant Feedstocks to Fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petit, Elsa; Coppi, Maddalena V.; Hayes, James C.; Tolonen, Andrew C.; Warnick, Thomas; Latouf, William G.; Amisano, Danielle; Biddle, Amy; Mukherjee, Supratim; Ivanova, Natalia; et al

    2015-06-02

    Clostridium phytofermentans was isolated from forest soil and is distinguished by its capacity to directly ferment plant cell wall polysaccharides into ethanol as the primary product, suggesting that it possesses unusual catabolic pathways. The objective of our present study was to understand the molecular mechanisms of biomass conversion to ethanol in a single organism, Clostridium phytofermentans, by analyzing its complete genome and transcriptome during growth on plant carbohydrates. The saccharolytic versatility of C. phytofermentans is reflected in a diversity of genes encoding ATP-binding cassette sugar transporters and glycoside hydrolases, many of which may have been acquired through horizontal gene transfer.more » These genes are frequently organized as operons that may be controlled individually by the many transcriptional regulators identified in the genome. Preferential ethanol production may be due to high levels of expression of multiple ethanol dehydrogenases and additional pathways maximizing ethanol yield. The genome also encodes three different proteinaceous bacterial microcompartments with the capacity to compartmentalize pathways that divert fermentation intermediates to various products. Lastly, these characteristics make C. phytofermentans an attractive resource for improving the efficiency and speed of biomass conversion to biofuels.« less

  4. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report estimates fuel cell system cost for systems produced in the years 2006, 2010, and 2015, and is the second annual update of a comprehensive automotive fuel cell cost analysis.

  5. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report estimates fuel cell system cost for systems produced in the years 2007, 2010, and 2015, and is the first annual update of a comprehensive automotive fuel cell cost analysis.

  6. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications. 2008 Update

    SciTech Connect (OSTI)

    James, Brian D.; Kalinoski, Jeffrey A.

    2009-03-26

    This report estimates fuel cell system cost for systems produced in the years 2006, 2010, and 2015, and is the second annual update of a comprehensive automotive fuel cell cost analysis.

  7. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update

    Broader source: Energy.gov [DOE]

    Report estimates fuel cell system cost for systems produced in the years 2006, 2010, and 2015, and is the second annual update of a comprehensive automotive fuel cell cost analysis.

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update

    SciTech Connect (OSTI)

    James, Brian D.; Kalinoski, Jeffrey A.

    2008-02-29

    This report estimates fuel cell system cost for systems produced in the years 2007, 2010, and 2015, and is the first annual update of a comprehensive automotive fuel cell cost analysis.

  9. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  10. Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)

    SciTech Connect (OSTI)

    Tarud, J.; Phillips, S.

    2011-08-01

    This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

  11. List of Methanol Incentives | Open Energy Information

    Open Energy Info (EERE)

    Commercial Industrial Anaerobic Digestion Biodiesel Biomass CHPCogeneration Ethanol Hydrogen Landfill Gas Methanol Microturbines Municipal Solid Waste Yes Business Energy Tax...

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Vehicle (AFV) Parking Space Regulation An individual is not allowed to park a motor vehicle within any parking space specifically designated for public parking and fueling of AFVs unless the motor vehicle is an AFV fueled by electricity, natural gas, methanol, propane, gasoline blended with at least 85% ethanol (E85), or other fuel the Oregon Department of Energy approves. Eligible AFVs must also be in the process of fueling or charging to park in the space. A person found responsible for a

  13. Methanol market slowly tightens as Brazil starts soaking up material

    SciTech Connect (OSTI)

    Young, I.

    1992-11-25

    Although the US methanol market's response to mandated oxygen requirements in reformulated gasoline has been disappointing, the European market has surprisingly been tightening in recent weeks and looks set for a price rise in first-quarter 1993. The tightness is being felt mainly in the Mediterranean market, where the Libyan methanol plant is running at only 70% because of problems with gas feedstock supplies. More significantly, the Brazilian government has now given the go-ahead for a yearlong extension on imports of methanol for use as an ethanol replacement in fuel blending. The new authorization sets a monthly import limit of 48,000 m.t. during that period. Libya is an important supplier of methanol to the Brazilian market and has already shipped about 20,000 m.t. since the authorization was given. Another major supplier to Brazil is Russia, from its two giant 750,000-m.t./year plants at Gubakha and Tomsk. The material is shipped from the terminal at Yuzhnyy on the Black Sea, in Ukrainian territory since the collapse of the Soviet Union.

  14. Romania program targets methanol and Fischer-Tropsch research

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    Currently, the chemical organic industry, the petrochemical and engine fuels industry in Romania are entirely based on hydrocarbons from oil. To reduce the oil dependence of this sector and to ensure the stipulated growth rate of 8-9%, research and development programs have been set up with a view to the diversification of raw materials. In research on hydrocarbons from alcohol conversion, three process variants are known, i.e. olefins from methanol, gasolines from methanol and a combined gasolines and aromatic hydrocarbons from methanol. The Romanian process of methanol conversion to hydrocarbons is very flexible, with all the variants mentioned being carried out in the same plant by modifying the catalysts. In research on hydrocarbons from synthesis gas a modern process is being developed for gasification of brown coal in a fluidized bed, under pressure, in the presence of oxygen and water vapors. In the field of carbon oxide hydrogenation, studies have been carried out on selective Fischer-Tropsch processes in which the reaction products are high value hydrocarbon fractions.

  15. Fuels Technologies

    Office of Environmental Management (EM)

    Displacement of petroleum n Approach n Example Project Accomplishments n Research Directions Fuels Technologies R&D Budget by Activities Major Activities FY 2007 ...

  16. European Fuel Cells R&D Review. Final report, Purchase Order No. 062014

    SciTech Connect (OSTI)

    Michael, P.D.; Maguire, J.

    1994-09-01

    Aim of the Review is to present a statement on the status of fuel cell development in Europe, addressing the research, development and demonstration (RD&D) and commercialization activities being undertaken, identifying key European organizations active in development and commercialization of fuel cells and detailing their future plans. This document describes the RD&D activities in Europe on alkaline, phosphoric acid, polymer electrolyte, direct methanol, solid oxide, and molten carbonate fuel cell types. It describes the European Commission`s activities, its role in the European development of fuel cells, and its interaction with the national programs. It then presents a country-by-country breakdown. For each country, an overview is given, presented by fuel cell type. Scandinavian countries are covered in less detail. American organizations active in Europe, either in supplying fuel cell components, or in collaboration, are identified. Applications include transportation and cogeneration.

  17. Conversion of Methanol, Ethanol and Propanol over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-04

    Renewable fuel from lignocellulosic biomass has recently attracted more attention due to its environmental and the potential economic benefits over the crude oil [1]. In particular the production of fuel range hydrocarbon (HC) from alcohol generated lots of interest since the alcohol can be produced from biomass via thermochemical [2] (mixed alcohol from gasification derived synthesis gas) as well as the biochemical routes [3] (alcohol fermentation). Along with the development of ZSM5 synthesis and the discovery of methanol-to-gasoline (MTG) process by Mobil in 1970’s triggered lots of interest in research and development arena to understand the reaction mechanisms of alcohols over zeolites in particular ZSM5 [4]. More detailed research on methanol conversion was extensively reported [5] and in recent times the research work can be found on ethanol [6] and other alcohols as well but comprehensive comparison of catalyst activity and the deactivation mechanism of the conversion of various alcohols over zeolites has not been reported. The experiments were conducted on smaller alcohols such as methanol, ethanol and 1-propanol over HZSM5. The experimental results on the catalyst activity and the catalyst deactivation mechanism will be discussed.

  18. Fuel Effects on Combustion and Emissions of a Direct-Inection Diesel Engine Operating at Moderate to High Engine Speed and Load

    SciTech Connect (OSTI)

    Szybist, James P; Szymkowicz, Patrick G.; Northrop, William F

    2012-01-01

    It is advantageous to increase the specific power output of diesel engines and to operate them at higher load for a greater portion of a driving cycle to achieve better thermal efficiency and thus reduce vehicle fuel consumption. Such operation is limited by excessive smoke formation at retarded injection timing and high rates of cylinder pressure rise at more advanced timing. Given this window of operation, it is desired to understand the influence of fuel properties such that optimum combustion performance and emissions can be retained over the range of fuels commonly available in the marketplace. It has been shown in previous studies that varying cetane number (CN) of diesel fuel has little effect on ignition delay at high engine load due to the domination of high cylinder temperature on ignition kinetics. The work here experimentally confirms that finding but also shows that emissions and combustion performance vary according to fuel reactivity. Data are examined from a direct-injection single cylinder research engine for eight common diesel fuels including soy-based biodiesel blends at two high load operating points with no exhaust gas recirculation (EGR) and at a moderate load with four levels of EGR. It is shown in the work that at high engine load where combustion is controlled by mixing processes, CN and other fuel properties have little effect on engine performance, although lower CN fuels produce a small increase in noise, smoke and CO emissions. Biodiesel blends increase NOX emissions and decreases CO and smoke emissions at high load, but otherwise have little effect on performance. At moderate load, higher CN fuels are more tolerant to EGR due to their better chemical reactivity at retarded injection timing, but all fuels produce comparable thermal efficiency at advanced combustion phasing regardless of EGR. In contrast to the high load conditions, there was no increase in NOX emissions for biodiesel at the moderate load condition. It is concluded that

  19. Methanol production method and system

    DOE Patents [OSTI]

    Chen, Michael J.; Rathke, Jerome W.

    1984-01-01

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  20. Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation Applications: 2013 Update

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report is the seventh annual update of a comprehensive automotive fuel cell cost analysis conducted by Strategic Analysis under contract to the U.S. Department of Energy. The 2013 update covers fuel cell cost analysis of both light duty vehicle (automotive) and transit bus applications for only the current year (i.e., 2013).

  1. Ignition assist systems for direct-injected, diesel cycle, medium-duty alternative fuel engines: Final report phase 1

    SciTech Connect (OSTI)

    Chan, A.K.

    2000-02-23

    This report is a summary of the results of Phase 1 of this contract. The objective was to evaluate the potential of assist technologies for direct-injected alternative fuel engines vs. glow plug ignition assist. The goal was to demonstrate the feasibility of an ignition system life of 10,000 hours and a system cost of less than 50% of the glow plug system, while meeting or exceeding the engine thermal efficiency obtained with the glow plug system. There were three tasks in Phase 1. Under Task 1, a comprehensive review of feasible ignition options for DING engines was completed. The most promising options are: (1) AC and the ''SmartFire'' spark, which are both long-duration, low-power (LDLP) spark systems; (2) the short-duration, high-power (SDHP) spark system; (3) the micropilot injection ignition; and (4) the stratified charge plasma ignition. Efforts concentrated on investigating the AC spark, SmartFire spark, and short-duration/high-power spark systems. Using proprietary pricing information, the authors predicted that the commercial costs for the AC spark, the short-duration/high-power spark and SmartFire spark systems will be comparable (if not less) to the glow plug system. Task 2 involved designing and performing bench tests to determine the criteria for the ignition system and the prototype spark plug for Task 3. The two most important design criteria are the high voltage output requirement of the ignition system and the minimum electrical insulation requirement for the spark plug. Under Task 3, all the necessary hardware for the one-cylinder engine test was designed. The hardware includes modified 3126 cylinder heads, specially designed prototype spark plugs, ignition system electronics, and parts for the system installation. Two 3126 cylinder heads and the SmartFire ignition system were procured, and testing will begin in Phase 2 of this subcontract.

  2. Mass Production Cost Estimation For Direct H2 PEM Fuel Cell Systesm for Automotive Applications: 2010 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report is the fourth annual update of a comprehensive automotive fuel cell cost analysis. It contains estimates for material and manufacturing costs of complete 80 kWnet direct‐hydrogen proton ex

  3. Manufacturing Cost Analysis of 10 kW and 25 kW Direct Hydrogen Polymer Electrolyte Membrane (PEM) Fuel Cell for Material Handling Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MANUFACTURING COST ANALYSIS OF 10 KW AND 25 KW DIRECT HYDROGEN POLYMER ELECTROLYTE MEMBRANE (PEM) FUEL CELL FOR MATERIAL HANDLING APPLICATIONS Prepared by: BATTELLE Battelle Memorial Institute 505 King Avenue Columbus, OH 43201 Prepared for: U.S. Department of Energy Golden Field Office Golden, CO DOE Contract No. DE-EE0005250 March 25, 2013 This report is a work prepared for the United States Government by Battelle. In no event shall either the United States Government or Battelle have any

  4. Developments in the European methanol market

    SciTech Connect (OSTI)

    Speed, J.

    1995-12-31

    In the late eighties/early nineties the World Methanol Market was basically divided into three regional markets--America, Asia Pacific and Europe. These markets were interrelated but each had its own specific characteristics and traditional suppliers. Now the situation has changed; in the mid nineties there is a Global Methanol Market with global players and effective global pricing and the European market is governed by events world-wide. Europe is however a specific market with specific characteristics which are different from those of other markets although it is also part of the Global Market. Hence before the author focuses on Europe he looks at the World Market. The paper discusses world methanol production and consumption by region, world methanol consumption by end use, world methanol supply demand balance, the west European market, western European methanol production, methanol imports to W. Europe, the Former Soviet Union supplies, W. European methanol consumption by end use, MTBE in Europe, duties on methanol imports into W. Europe, investment in Europe, the effect of the 1994/95 price spike, and key issues for the future of the industry.

  5. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2003-01-01

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  6. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-04-20

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  7. Hydrogen production from the steam reforming of Dinethyl Ether and Methanol

    SciTech Connect (OSTI)

    Semelsberger, T. A.; Borup, R. L.

    2004-01-01

    This study investigates dimethyl ether (DME) steam reforming for the generation of hydrogen rich fuel cell feeds for fuel cell applications. Methanol has long been considered as a fuel for the generation of hydrogen rich fuel cell feeds due to its high energy density, low reforming temperature, and zero impurity content. However, it has not been accepted as the fuel of choice due its current limited availability, toxicity and corrosiveness. While methanol steam reforming for the generation of hydrogen rich fuel cell feeds has been extensively studied, the steam reforming of DME, CH{sub 3}OCH{sub 3} + 3H{sub 2}O = 2CO{sub 2} + 6H{sub 2}, has had limited research effort. DME is the simplest ether (CH{sub 3}OCH{sub 3}) and is a gas at ambient conditions. DME has physical properties similar to those of LPG fuels (i.e. propane and butane), resulting in similar storage and handling considerations. DME is currently used as an aerosol propellant and has been considercd as a diesel substitute due to the reduced NOx, SOx and particulate emissions. DME is also being considered as a substitute for LPG fuels, which is used extensively in Asia as a fuel for heating and cooking, and naptha, which is used for power generation. The potential advantages of both methanol and DME include low reforming temperature, decreased fuel proccssor startup energy, environmentally benign, visible flame, high heating value, and ease of storage and transportation. In addition, DME has the added advantages of low toxicity and being non-corrosive. Consequently, DME may be an ideal candidate for the generation of hydrogen rich fuel cell feeds for both automotive and portable power applications. The steam reforming of DME has been demonstrated to occur through a pair of reactions in series, where the first reaction is DME hydration followed by MeOH steam reforming to produce a hydrogen rich stream.

  8. Development of a New Class of Low Cost, High Frequency Link Direct DC to AC Converters for Solid Oxide Fuel Cells (SOFC)

    SciTech Connect (OSTI)

    Prasad Enjeti; J.W. Howze

    2003-12-01

    This project proposes to design and develop a new class of power converters (direct DC to AC) to drastically improve performance and optimize the cost, size, weight and volume of the DC to AC converter in SOFC systems. The proposed topologies employ a high frequency link; direct DC to AC conversion approach. The direct DC to AC conversion approach is more efficient and operates without an intermediate dc-link stage. The absence of the dc-link, results in the elimination of bulky, aluminum electrolytic capacitors, which in turn leads to a reduction in the cost, volume, size and weight of the power electronic converter. The feasibility of two direct DC to AC converter topologies and their suitability to meet SECA objectives will be investigated. Laboratory proto-type converters (3-5kW) will be designed and tested in Phase-1. A detailed design trade-off study along with the test results will be available in the form of a report for the evaluation of SECA Industrial partners. This project proposes to develop a new and innovative power converter technology suitable for Solid Oxide Fuel Cell (SOFC) power systems in accordance with SECA objectives. The proposed fuel cell inverter (FCI) employs state of the art power electronic devices configured in two unique topologies to achieve direct conversion of DC power (24-48V) available from a SOFC to AC power (120/240V, 60Hz) suitable for utility interface and powering stand alone loads. The primary objective is to realize cost effective fuel cell converter, which operates under a wide input voltage range, and output load swings with high efficiency and improved reliability.

  9. Air Liquide - Biogas & Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... the environment PT Loma WWTP, Biogas to Fuel Cell Power BioFuels Energy Biogas to BioMethane to 4.5 MW Fuel Cell Power 3 FCE Fuel Cells 2 via directed Biomethane ...

  10. NREL Research on Converting Biomass to Liquid Fuels

    ScienceCinema (OSTI)

    None

    2013-05-29

    Unlike other renewable energy sources, biomass can be converted directly into liquid fuels, called "biofuels," to help meet transportation fuel needs. The two most common types of biofuels are ethanol and biodiesel. Today, ethanol is made from starches and sugars, but at the National Renewable Energy Laboratory (NREL) scientists are developing technology to allow it to be made from cellulose and hemicellulose, the fibrous material that makes up the bulk of most plant matter. Biodiesel is made by combining alcohol (usually methanol) with vegetable oil, animal fat, or recycled cooking grease. It can be used as an additive (typically 20%) to reduce vehicle emissions or in its pure form as a renewable alternative fuel for diesel engines. For a text version of this video visit http://www.nrel.gov/learning/re_biofuels.html

  11. Techno-economic Analysis for the Conversion of Lignocellulosic Biomass to Gasoline via the Methanol-to-Gasoline (MTG) Process

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-05-01

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). With gasification technology, biomass can be converted to gasoline via methanol synthesis and methanol-to-gasoline (MTG) technologies. Producing a gasoline product that is infrastructure ready has much potential. Although the MTG technology has been commercially demonstrated with natural gas conversion, combining MTG with biomass gasification has not been shown. Therefore, a techno-economic evaluation for a biomass MTG process based on currently available technology was developed to provide information about benefits and risks of this technology. The economic assumptions used in this report are consistent with previous U.S. Department of Energy Office of Biomass Programs techno-economic assessments. The feedstock is assumed to be wood chips at 2000 metric ton/day (dry basis). Two kinds of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. The gasoline selling prices (2008 USD) excluding taxes were estimated to be $3.20/gallon and $3.68/gallon for indirectly-heated gasified and directly-heated. This suggests that a process based on existing technology is economic only when crude prices are above $100/bbl. However, improvements in syngas cleanup combined with consolidated gasoline synthesis can potentially reduce the capital cost. In addition, improved synthesis catalysts and reactor design may allow increased yield.

  12. Development of alternative fuels from coal derived syngas. Topical report: Task 2.2, Demonstration of a one-step slurry-phase process for the production of dimethyl ether/methanol mixtures at the LaPorte Alternative Fuels Development Unit

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    This report documents engineering, modification, and operations efforts of demonstration of dimethyl-ether/methanol coproduction in a slurry-phase reactor, carried out in a 2-ft diameter bubble column reactor. Equipment modifications made it possible to remove the product DME and by-product CO{sub 2} from the reactor effluent. Coproduction of dimethyl-ether (DME) and methanol (MeOH) was accomplished in the slurry reactor by physically mixing two different catalysts. The catalyst used to produce MeOH from syngas was manufactured by BASF (type S3-86); the catalyst used to convert MeOH to DME was Catapal {gamma}-alumina. Ratio of MeOH to DME catalysts determined the selectivity towards DME. The demonstration sought to study effect of cocatalyst ratio on product selectivity. Three different proportions of DME catalyst were examined: 0, 6.6, and 19.3 wt % alumina. At each catalyst proportion, the plant was operated at two different gas space velocities. Some process variables were maintained at fixed conditions; most important variables included: reactor temperature (482F), reactor pressure (750 psig), and reactor feed gas composition (35% H{sub 2}, 51% CO,13% CO{sub 2} 1% other, nominal-molar basis).

  13. Platinum-ruthenium nanotubes and platinum-ruthenium coated copper nanowires as efficient catalysts for electro-oxidation of methanol

    SciTech Connect (OSTI)

    Zheng, Jie; Cullen, David A.; Forest, Robert V.; Wittkopf, Jarrid A.; Zhuang, Zhongbin; Zheng, Whenchao; Chen, Jingguang G.; Yan, Yushan

    2015-01-15

    The sluggish kinetics of methanol oxidation reaction (MOR) is a major barrier to the commercialization of direct methanol fuel cells (DMFCs). In this study, we report a facile synthesis of platinum–ruthenium nanotubes (PtRuNTs) and platinum–ruthenium-coated copper nanowires (PtRu/CuNWs) by galvanic displacement reaction using copper nanowires as a template. The PtRu compositional effect on MOR is investigated; the optimum Pt/Ru bulk atomic ratio is about 4 and surface atomic ratio about 1 for both PtRuNTs and PtRu/CuNWs. Enhanced specific MOR activities are observed on both PtRuNTs and PtRu/CuNWs compared with the benchmark commercial carbon-supported PtRu catalyst (PtRu/C, Hispec 12100). Finally, x-ray photoelectron spectroscopy (XPS) reveals a larger extent of electron transfer from Ru to Pt on PtRu/CuNWs, which may lead to a modification of the d-band center of Pt and consequently a weaker bonding of CO (the poisoning intermediate) on Pt and a higher MOR activity on PtRu/CuNWs.

  14. Platinum-ruthenium nanotubes and platinum-ruthenium coated copper nanowires as efficient catalysts for electro-oxidation of methanol

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Jie; Cullen, David A.; Forest, Robert V.; Wittkopf, Jarrid A.; Zhuang, Zhongbin; Zheng, Whenchao; Chen, Jingguang G.; Yan, Yushan

    2015-01-15

    The sluggish kinetics of methanol oxidation reaction (MOR) is a major barrier to the commercialization of direct methanol fuel cells (DMFCs). In this study, we report a facile synthesis of platinum–ruthenium nanotubes (PtRuNTs) and platinum–ruthenium-coated copper nanowires (PtRu/CuNWs) by galvanic displacement reaction using copper nanowires as a template. The PtRu compositional effect on MOR is investigated; the optimum Pt/Ru bulk atomic ratio is about 4 and surface atomic ratio about 1 for both PtRuNTs and PtRu/CuNWs. Enhanced specific MOR activities are observed on both PtRuNTs and PtRu/CuNWs compared with the benchmark commercial carbon-supported PtRu catalyst (PtRu/C, Hispec 12100). Finally, x-raymore » photoelectron spectroscopy (XPS) reveals a larger extent of electron transfer from Ru to Pt on PtRu/CuNWs, which may lead to a modification of the d-band center of Pt and consequently a weaker bonding of CO (the poisoning intermediate) on Pt and a higher MOR activity on PtRu/CuNWs.« less

  15. A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2014-02-21

    The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H{sub 2}Bioil) using supplementary hydrogen (H{sub 2}) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H{sub 2} is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H{sub 2}Bioil process for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygenation were constructed, completing Task A. These reactors were capable of operation under a wide-range of conditions; enabling process studies that lead to identification of optimum process conditions. Model compounds representing biomass pyrolysis products were studied, completing Task B. These studies were critical in identifying and developing HDO catalysts to target specific oxygen functional groups. These process and model compound catalyst studies enabled identification of catalysts that achieved 100% deoxygenation of the real biomass feedstock, sorghum, to form hydrocarbons in high yields as part of Task C. The work completed during this grant has identified and validated the novel and commercially scalable H2Bioil process for production of hydrocarbon fuels from biomass. Studies on model compounds as well as real biomass

  16. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.; Upadhye, Ravindra S.; Havstad, Mark A.

    2011-08-09

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  17. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, James F.; Chludzinski, Paul J.; Dantowitz, Philip

    1987-01-01

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

  18. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

    1987-04-14

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

  19. EMC Electropolishing TEM Samples Using Perchloric Acid and Methanol |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory EMC Electropolishing TEM Samples Using Perchloric Acid and Methanol PDF icon Electropolishing_Using_Perchloric_Acid_and_Methanol

  20. Transport diffusion of liquid water and methanol through membranes...

    Office of Scientific and Technical Information (OSTI)

    Transport diffusion of liquid water and methanol through membranes Citation Details In-Document Search Title: Transport diffusion of liquid water and methanol through membranes The ...

  1. Alcohol Fuels Program technical review, Spring 1984

    SciTech Connect (OSTI)

    Not Available

    1984-10-01

    The alcohol fuels program consists of in-house and subcontracted research for the conversion of lignocellulosic biomass into fuel alcohols via thermoconversion and bioconversion technologies. In the thermoconversion area, the SERI gasifier has been operated on a one-ton per day scale and produces a clean, medium-Btu gas that can be used to manufacture methanol with a relatively small gas-water shift reaction requirement. Recent research has produced catalysts that make methanol and a mixture of higher alcohols from the biomass-derived synthetic gas. Three hydrolysis processes have emerged as candidates for more focused research. They are: a high-temperature, dilute-acid, plug-flow approach based on the Dartmouth reactor; steam explosion pretreatment followed by hydrolysis using the RUT-C30 fungal organism; and direct microbial conversion of the cellulose to ethanol using bacteria in a single or mixed culture. Modeling studies, including parametric and sensitivity analyses, have recently been completed. The results of these studies will lead to a better definition of the present state-of-the-art for these processes and provide a framework for establishing the research and process engineering issues that still need resolution. In addition to these modeling studies, economic feasibility studies are being carried out by commercial engineering firms. Their results will supplement and add commercial validity to the program results. The feasibility contractors will provide input at two levels: Technical and economic assessment of the current state-of-the-art in alcohol production from lignocellulosic biomass via thermoconversion to produce methanol and higher alcohol mixtures and bioconversion to produce ethanol; and identification of research areas having the potential to significantly reduce the cost of production of alcohols.

  2. Assessment of costs and benefits of flexible and alternative fuel use in the US transportation sector

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    The DOE is conducting a comprehensive technical analysis of a flexible-fuel transportation system in the United States -- that is, a system that could easily switch between petroleum and another fuel, depending on price and availability. The DOE Alternative Fuels Assessment is aimed directly at questions of energy security and fuel availability, but covers a wide range of issues. This report examines environmental, health, and safety concerns associated with a switch to alternative- and flexible-fuel vehicles. Three potential alternatives to oil-based fuels in the transportation sector are considered: methanol, compressed natural gas (CNG), and electricity. The objective is to describe and discuss qualitatively potential environmental, health, and safety issues that would accompany widespread use of these three fuels. This report presents the results of exhaustive literature reviews; discussions with specialists in the vehicular and fuel-production industries and with Federal, State, and local officials; and recent information from in-use fleet tests. Each chapter deals with the end-use and process emissions of air pollutants, presenting an overview of the potential air pollution contribution of the fuel --relative to that of gasoline and diesel fuel -- in various applications. Carbon monoxide, particulate matter, ozone precursors, and carbon dioxide are emphasized. 67 refs., 6 figs. , 8 tabs.

  3. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14

    investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. During the reporting period, effort continues on identifying potential technologies for removing contaminants from synthesis gas to the level required by methanol synthesis. A liquid phase Claus process and a direct sulfur oxidation process were evaluated. Preliminary discussion was held with interested parties on cooperating on RD&T in Phase II of the project. Also, significant progress was made during the period in the submission of project deliverables. A meeting was held at DOE's National Energy Technology Laboratory in Morgantown between GEC and the DOE IMPPCCT Project Manager on the status of the project, and reached an agreement on the best way to wrap up Phase I and transition into the Phase II RD&T. Potential projects for the Phase II, cost, and fund availability were also discussed.

  4. Novel Catalyst Support Materials for PEM Fuel Cells: Current Status and Future Prospects

    SciTech Connect (OSTI)

    Shao, Yuyan; Liu, Jun; Wang, Yong; Lin, Yuehe

    2008-12-15

    The catalyst supports exhibit great influence on the cost, performance, and durability of polymer electrolyte membrane (PEM) fuel cells. This review paper is to summarize several important kinds of novel support materials for PEM fuel cells (including direct methanol fuel cell, DMFC): nanostructured carbon materials (carbon nanotubes/carbon nanofibers, mesoporous carbon), conductive doped diamonds and nanodiamonds, conductive oxides (tin oxide/indium tin oxide, titanium oxide, tungsten oxide) and carbides (tungsten carbides). The advantages and disadvantages, the acting mechanism to promote electrocatalysis, and the strategies to improve present catalyst support materials and to search for new ones are discussed. This is expected to throw light on future development of catalyst support for PEM fuel cells.

  5. Demonstration of fuel hot-spot pressure in excess of 50 Gbar for direct-drive, layered deuterium-tritium implosions on OMEGA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Regan, S. P.; Goncharov, V. N.; Igumenshchev, I. V.; Sangster, T. C.; Betti, R.; Bose, A.; Boehly, T. R.; Bonino, M. J.; Campbell, E. M.; Cao, D.; et al

    2016-07-07

    A record fuel hot-spot pressure Phs = 56±7 Gbar was inferred from x-ray and nuclear diagnostics for direct-drive inertial confinement fusion cryogenic, layered deuterium–tritium implosions on the 60-beam, 30-kJ, 351-nm OMEGA Laser System. When hydrodynamically scaled to the energy of the National Ignition Facility (NIF), these implosions achieved a Lawson parameter ~60% of the value required for ignition [A. Bose et al., Phys. Rev. E (in press)], similar to indirect-drive implosions [R. Betti et al., Phys. Rev. Lett. 114, 255003 (2015)], and nearly half of the direct-drive ignition-threshold pressure. Relative to symmetric, one-dimensional simulations, the inferred hot-spot pressure is ~40%more » lower. Furthermore, three-dimensional simulations suggest that low-mode distortion of the hot spot seeded by laser-drive nonuniformity and target-positioning error reduces target performance.« less

  6. UK group plans major methanol project

    SciTech Connect (OSTI)

    1996-07-31

    International Offshore Chemicals (IOC; Aberdeen, UK), a project development and management company, has formed a consortium to seek permission to build a 2,500-m.t./day methanol plant near the St. Fergus terminal in northeast Scotland. Robert Spiers, technical adviser to IOC, tells CW that the $255-million plant, based on the ICI process, would begin production in second-quarter 1999. The key market would be Europe. Jacobs Engineering and Davy are negotiating for the construction contract. Spiers says Europe imports 3 million m.t./year of methanol, and-even with Statoil`s plant under construction in Norway-there is room for more. ICI is the UK`s only producer of methanol. Another company, reportedly Kemira, may build a 360,000-m.t./year ammonia plant nearby if the methanol scheme goes ahead.

  7. Direct Measurement of Initial Enrichment and Burn-up of Spent Fuel Assembly with a Differential Die-Away Technique Based Instrument

    SciTech Connect (OSTI)

    Henzl, Vladimir; Swinhoe, Martyn T.; Tobin, Stephen J.

    2012-07-16

    A key objective of the Next Generation Safeguards Initiative (NGSI) is to utilize non-destructive assay (NDA) techniques to determine the elemental plutonium (Pu) content in a commercial-grade nuclear spent fuel assembly (SFA). In the third year of the NGSI Spent Fuel NDA project, the research focus is on the integration of a few NDA techniques. One of the reoccurring challenges to the accurate determination of Pu content has been the explicit dependence of the measured signal on the presence of neutron absorbers which build up in the assembly in accordance with its operating and irradiation history. The history of any SFA is often summarized by the parameters of burn-up (BU), initial enrichment (IE) and cooling time (CT). While such parameters can typically be provided by the operator, the ability to directly measure and verify them would significantly enhance the autonomy of the IAEA inspectorate. Within this paper, we demonstrate that an instrument based on a Differential Die-Away technique is in principle capable of direct measurement of IE and, should the CT be known, also the BU.

  8. 15.11.21 Methanol - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an electrochemical reduction of carbon dioxide exclusively to methanol Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of CO2 to Methanol: Empirical (DEMS) Corroboration of a Computational (DFT) Prediction. Electrocatalysis, DOI: 10.1007/s12678-015-0276-8 (2015). With kind permission from Springer Science+Business Media: Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of carbon dioxide to

  9. 15.11.21 RH Methanol - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an electrochemical reduction of carbon dioxide exclusively to methanol Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of CO2 to Methanol: Empirical (DEMS) Corroboration of a Computational (DFT) Prediction. Electrocatalysis, DOI: 10.1007/s12678-015-0276-8 (2015). With kind permission from Springer Science+Business Media: Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of carbon dioxide to

  10. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    SciTech Connect (OSTI)

    Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

    2008-05-12

    In this work we report on thevacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuumultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  11. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    SciTech Connect (OSTI)

    Kostko, Oleg; Belau, Leonid; Wilson, Kevin R.; Ahmed, Musahid

    2008-04-24

    In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  12. Integrated low emissions cleanup system for direct coal fueled turbines (Moving bed, fluid bed contactor/ceramic filter)

    SciTech Connect (OSTI)

    Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.

    1992-01-20

    The United States Department of Energy, Morgantown Energy Research Center (DOE/METC), is sponsoring the development of direct coal-fired turbine power plants as part of their Heat Engines program. A major technical challenge remaining for the development of the direct coal-fired turbine is high-temperature combustion gas cleaning to meet environmental standards for sulfur oxides and particulate emissions, as well as to provide acceptable turbine life. The Westinghouse Electric Corporation, Science Technology Center, is evaluating two Integrated Low Emissions Cleanup (ILEC) concepts that have been configured to meet this technical challenge: a baseline ceramic barrier filter ILEC concept, and a fluidized bed ILEC concept. These ILEC concepts simultaneously control sulfur, particulate, and alkali contaminants in the high-pressure combustion gases at turbine inlet temperatures up to 2300{degrees}F. This document reports the status of a program in the seventeenth quarter to develop this ILEC technology for direct coal-fired turbine power plants.

  13. Unbiased water and methanol maser surveys of NGC 1333

    SciTech Connect (OSTI)

    Lyo, A-Ran; Kim, Jongsoo; Byun, Do-Young; Lee, Ho-Gyu

    2014-11-01

    We present the results of unbiased 22 GHz H{sub 2}O water and 44 GHz class I CH{sub 3}OH methanol maser surveys in the central 7' 10' area of NGC 1333 and two additional mapping observations of a 22 GHz water maser in a ?3' 3' area of the IRAS4A region. In the 22 GHz water maser survey of NGC 1333 with a sensitivity of ? ? 0.3 Jy, we confirmed the detection of masers toward H{sub 2}O(B) in the region of HH 7-11 and IRAS4B. We also detected new water masers located ?20'' away in the western direction of IRAS4B or ?25'' away in the southern direction of IRAS4A. We could not, however, find young stellar objects or molecular outflows associated with them. They showed two different velocity components of ?0 and ?16 km s{sup 1}, which are blue- and redshifted relative to the adopted systemic velocity of ?7 km s{sup 1} for NGC 1333. They also showed time variabilities in both intensity and velocity from multi-epoch observations and an anti-correlation between the intensities of the blue- and redshifted velocity components. We suggest that the unidentified power source of these masers might be found in the earliest evolutionary stage of star formation, before the onset of molecular outflows. Finding this kind of water maser is only possible through an unbiased blind survey. In the 44 GHz methanol maser survey with a sensitivity of ? ? 0.5 Jy, we confirmed masers toward IRAS4A2 and the eastern shock region of IRAS2A. Both sources are also detected in 95 and 132 GHz methanol maser lines. In addition, we had new detections of methanol masers at 95 and 132 GHz toward IRAS4B. In terms of the isotropic luminosity, we detected methanol maser sources brighter than ?5 10{sup 25} erg s{sup 1} from our unbiased survey.

  14. The origin of organic pollutants from the combustion of alternative fuels: Phase IV report

    SciTech Connect (OSTI)

    Taylor, P.H.; Dellinger, B.; Sidhu, S.K.

    1997-06-01

    As part of the US-DOE`s on-going interest in the use of alternative automotive fuels, the University of Dayton Research Institute has been conducting research on pollutant emissions resulting from the combustion of candidate fuels. This research, under the direction and sponsorship of the NREL, has been concerned primarily with the combustion of compressed natural gas, liquefied petroleum gas (LPG), methanol, and ethanol. In the first 24 months of this program, studies of the oxygen rich, stoichiometric, and fuel-rich thermal degradation of these fuels in the temperature range of 300 to 1100{degrees}C at atmospheric pressure and for reaction times of 1.0 and 2.0 s were completed. Trace organic products were identified and quantified for each fuel as a function of temperature. The results of these studies agreed well with the results of tail-pipe emission studies in that the types and quantity of emissions measured in both the laboratory and engine tests were shown to be very similar under certain operating conditions. However, some chemicals were observed in the laboratory studies that were not observed in the engine studies and vice versa. This result is important in that it has implications concerning the origin of these emissions. Experiments concerning the NO perturbed oxidation of methanol, M85, ethanol, and E85 indicated the presence of complex oxidation chemistry. At mild temperatures, NO addition resulted in enhanced fuel conversion. At elevated temperatures, an inhibitory effect was observed through increased yields of both partial oxidation and pyrolysis-type reaction products. Comparison of flow reactor product distributions with engine test results generally indicated improved comparisons when NO was added to the fuel. Analysis of secondary components of alcohol fuels resulted in some unexpected observations. Several previously unidentified species were observed in these experiments which may impact atmospheric reactivity assessments of these fuels.

  15. Multiple fuel supply system for an internal combustion engine

    DOE Patents [OSTI]

    Crothers, William T.

    1977-01-01

    A multiple fuel supply or an internal combustion engine wherein phase separation of components is deliberately induced. The resulting separation permits the use of a single fuel tank to supply components of either or both phases to the engine. Specifically, phase separation of a gasoline/methanol blend is induced by the addition of a minor amount of water sufficient to guarantee separation into an upper gasoline phase and a lower methanol/water phase. A single fuel tank holds the two-phase liquid with separate fuel pickups and separate level indicators for each phase. Either gasoline or methanol, or both, can be supplied to the engine as required by predetermined parameters. A fuel supply system for a phase-separated multiple fuel supply contained in a single fuel tank is described.

  16. Emissions and fuel economy of a vehicle with a spark-ignition, direct-injection engine : Mitsubishi Legnum GDI{trademark}.

    SciTech Connect (OSTI)

    Cole, R. L.; Poola, R. B.; Sekar, R.

    1999-04-08

    A 1997 Mitsubishi Legnum station wagon with a 150-hp, 1.8-L, spark-ignition, direct-injection (SIDI) engine was tested for emissions by using the FTP-75, HWFET, SC03, and US06 test cycles and four different fuels. The purpose of the tests was to obtain fuel-economy and emissions data on SIDI vehicles and to compare the measurements obtained with those of a port-fuel-injection (PFI) vehicle. The PFI vehicle chosen for the comparison was a 1995 Dodge Neon, which meets the Partnership for a New Generation of Vehicles (PNGV) emissions goals of nonmethane hydrocarbons (NMHC) less than 0.125 g/mi, carbon monoxide (CO) less than 1.7 g/mi, nitrogen oxides (NO{sub x} ) less than 0.2 g/mi, and particulate matter (PM) less than 0.01 g/mi. The Mitsubishi was manufactured for sale in Japan and was not certified to meet current US emissions regulations. Results show that the SIDI vehicle can provide up to 24% better fuel economy than the PFI vehicle does, with correspondingly lower greenhouse gas emissions. The SIDI vehicle as designed does not meet the PNGV goals for NMHC or NO{sub x} emissions, but it does meet the goal for CO emissions. Meeting the goal for PM emissions appears to be contingent upon using low-sulfur fuel and an oxidation catalyst. One reason for the difficulty in meeting the NMHC and NO{sub x} goals is the slow (200 s) warm-up of the catalyst. Catalyst warm-up time is primarily a matter of design. The SIDI engine produces more NMHC and NO{sub x} than the PFI engine does, which puts a greater burden on the catalyst to meet the emissions goals than is the case with the PFI engine. Oxidation of NMHC is aided by unconsumed oxygen in the exhaust when the SIDI engine operates in stratified-charge mode, but the same unconsumed oxygen inhibits chemical reduction of NO{sub x} . Thus, meeting the NO{sub x} emissions goal is likely to be the greatest challenge for the SIDI engine.

  17. Fuel cells for transportation program: FY1997 national laboratory annual report

    SciTech Connect (OSTI)

    1997-12-31

    The Department of Energy (DOE) Fuel Cells for Transportation Program is structured to effectively implement the research and development (R and D) required for highly efficient, low or zero emission fuel cell power systems to be a viable replacement for the internal combustion engine in automobiles. The Program is part of the Partnership for a New Generation of Vehicles (PNGV), a government-industry initiative aimed at development of an 80 mile-per-gallon vehicle. This Annual Report summarizes the technical accomplishments of the laboratories during 1997. Participants include: Argonne National Laboratory (ANL), Brookhaven National Laboratory (BNL), Lawrence Berkeley National Laboratory (LBNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), Pacific Northwest National Laboratory (PNNL), and the National Renewable Energy Laboratory (NREL). During 1997, the laboratory R and D included one project on solid oxide fuel cells; this project has since been terminated to focus Department resources on PEM fuel cells. The technical component of this report is divided into five key areas: fuel cell stack research and development; fuel processing; fuel cell modeling, testing, and evaluation; direct methanol PEM fuel cells; and solid oxide fuel cells.

  18. Vaporized alcohol fuel boosts engine efficiency

    SciTech Connect (OSTI)

    Hardenburg, H.O.; Bergmann, H.K.; Metsch, H.I.; Schaefer, A.J.

    1983-02-01

    An effort is being made at Daimler-Benz AG to utilize the special characteristics of vaporized methanol and ethanol in an alcohol-gas spark-ignited engine. Describes laboratory testing which demonstrates that waste heat recovery and very lean air/fuel mixtures improve the efficiency and economy of a spark-ignition engine running on alcohol vapors. Presents graph comparing performance and torque of the alcohol-gas and diesel engines. Finds that the fuel consumption of the methanol-fueled version approaches that of a diesel engine, with other advantages including low engine noise, good acceleration, and favorable exhaust emissions.

  19. Fuel cells and fuel cell catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Rice, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2006-11-07

    A direct organic fuel cell includes a formic acid fuel solution having between about 10% and about 95% formic acid. The formic acid is oxidized at an anode. The anode may include a Pt/Pd catalyst that promotes the direct oxidation of the formic acid via a direct reaction path that does not include formation of a CO intermediate.

  20. Dimethyl ether production from methanol and/or syngas

    DOE Patents [OSTI]

    Dagle, Robert A; Wang, Yong; Baker, Eddie G; Hu, Jianli

    2015-02-17

    Disclosed are methods for producing dimethyl ether (DME) from methanol and for producing DME directly from syngas, such as syngas from biomass. Also disclosed are apparatus for DME production. The disclosed processes generally function at higher temperatures with lower contact times and at lower pressures than conventional processes so as to produce higher DME yields than do conventional processes. Certain embodiments of the processes are carried out in reactors providing greater surface to volume ratios than the presently used DME reactors. Certain embodiments of the processes are carried out in systems comprising multiple microchannel reactors.

  1. Fuel cell market applications

    SciTech Connect (OSTI)

    Williams, M.C.

    1995-12-31

    This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

  2. The low-temperature partial oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Argonne`s partial-oxidation reformer (APOR) is a compact, lightweight, rapid-start, and dynamically responsive device to convert liquid fuels to H{sub 2} for use in automotive fuel cells. An APOR catalyst for methanol has been developed and tested; catalysts for other fuels are being evaluated. Simple in design, operation, and control, the APOR can help develop efficient fuel cell propulsion systems.

  3. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    SciTech Connect (OSTI)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEM imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.

  4. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEMmore » imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.« less

  5. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    SciTech Connect (OSTI)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and mediumhigh (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEM imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.

  6. CARB/SQAQMD cooperative methanol vehicle development program: Phase 1. Final report

    SciTech Connect (OSTI)

    1996-04-01

    This project was structured as a jointly-funded effort by the California Air Resources Board and the South Coast Air Quality Management District. The purpose of the Phase I work effort was to develop and evaluate an electronic alcohol injection system for DI passenger car engines. The deliverable was the evaluation, design and fabrication of a methanol compatible, electronically controlled fuel injection system, including modification/ adaptation of the engine control unit, and the ensuing functional engine testing. The technology that has been developed under this contract represents a near-production level injection system featuring electronic control of both the injection timing and quantity, closed loop EGR, and glow plug power. This development represents a significant technical progression in terms of the potential for passenger car vehicles to meet future emissions standards with methanol fueled DI engines.

  7. Preventing CO poisoning in fuel cells

    DOE Patents [OSTI]

    Gottesfeld, Shimshon

    1990-01-01

    Proton exchange membrane (PEM) fuel cell performance with CO contamination of the H.sub.2 fuel stream is substantially improved by injecting O.sub.2 into the fuel stream ahead of the fuel cell. It is found that a surface reaction occurs even at PEM operating temperatures below about 100.degree. C. to oxidatively remove the CO and restore electrode surface area for the H.sub.2 reaction to generate current. Using an O.sub.2 injection, a suitable fuel stream for a PEM fuel cell can be formed from a methanol source using conventional reforming processes for producing H.sub.2.

  8. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  9. Fuel Cell Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells » Fuel Cell Systems Fuel Cell Systems The design of fuel cell systems is complex, and can vary significantly depending upon fuel cell type and application. However, several basic components are found in many fuel cell systems: Fuel cell stack Fuel processor Power conditioners Air compressors Humidifiers Fuel Cell Stack The fuel cell stack is the heart of a fuel cell power system. It generates electricity in the form of direct current (DC) from electro-chemical reactions that take place in

  10. Gas Diffusion Electrodes for Fuel Cells - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Hydrogen and Fuel Cell Hydrogen and Fuel Cell Advanced Materials Advanced Materials Find More Like This Return to Search Gas Diffusion Electrodes for Fuel Cells Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (778 KB) Technology Marketing SummaryA unique gas diffusion electrode technique resulting in little to no leftover methanol, therefore increasing the overall effectiveness and

  11. FUEL ELEMENT

    DOE Patents [OSTI]

    Bean, R.W.

    1963-11-19

    A ceramic fuel element for a nuclear reactor that has improved structural stability as well as improved cooling and fission product retention characteristics is presented. The fuel element includes a plurality of stacked hollow ceramic moderator blocks arranged along a tubular raetallic shroud that encloses a series of axially apertured moderator cylinders spaced inwardly of the shroud. A plurality of ceramic nuclear fuel rods are arranged in the annular space between the shroud and cylinders of moderator and appropriate support means and means for directing gas coolant through the annular space are also provided. (AEC)

  12. Utiization of alternate fuels in diesel engines

    SciTech Connect (OSTI)

    Lestz, S.S.

    1980-09-01

    Accomplishments during three years entitled The Utilization of Alternate Fuels in Diesel Engines are summarized. Experiments were designed and test equipment set-up for the purpose of evaluating the use of methanol as a fumigant for light-duty Diesel engine service. The major experimental results were obtained from a multicylinder automotive Diesel engine. However, fundamental studies employing a GC/micro-reactor and a constant volume combustion bomb were also started. The purpose of this work was to measure some of the chemical and physical properties of methanol and methanol-air mixtures. The laminar flame velocity for various mixtures has been measured in the combustion bomb and thermal degradation studies have begun in the GC/micro-reactor. An Oldsmobile 5.7 liter V/8 Diesel engine was fumigated with methanol in amounts up to 40% of the fuel energy. The primary objectives of the study were to determine the effect of methanol fumigation on fuel efficiency, smoke, nitric oxide emission, and the occurrence of severe knock. An assessment of the biological activity for samples of the raw exhaust particulate and its soluble organic extract was also made using boh the Ames Salmonella typhimurium test and the B. subtilis Comptest. Generally, methanol fumigation was found to decrease NO emission for all conditions, to have a slight effect on smoke opacity, and to have a beneficial effect on fuel efficiency at higher loads. Also at higher loads, the methanol was found to induce what was defined as knock limited operation. The biological activity of the raw particulate matter was fond to be less than that of its soluble organic extract. However, for both the fumigation of methanol did enhance the biological activity.

  13. Dual Tank Fuel System

    SciTech Connect (OSTI)

    Wagner, Richard William; Burkhard, James Frank; Dauer, Kenneth John

    1999-11-16

    A dual tank fuel system has primary and secondary fuel tanks, with the primary tank including a filler pipe to receive fuel and a discharge line to deliver fuel to an engine, and with a balance pipe interconnecting the primary tank and the secondary tank. The balance pipe opens close to the bottom of each tank to direct fuel from the primary tank to the secondary tank as the primary tank is filled, and to direct fuel from the secondary tank to the primary tank as fuel is discharged from the primary tank through the discharge line. A vent line has branches connected to each tank to direct fuel vapor from the tanks as the tanks are filled, and to admit air to the tanks as fuel is delivered to the engine.

  14. Methanol sensor operated in a passive mode

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2002-01-01

    A sensor outputs a signal related to a concentration of methanol in an aqueous solution adjacent the sensor. A membrane electrode assembly (MEA) is included with an anode side and a cathode side. An anode current collector supports the anode side of the MEA and has a flow channel therethrough for flowing a stream of the aqueous solution and forms a physical barrier to control access of the methanol to the anode side of the MEA. A cathode current collector supports the cathode side of the MEA and is configured for air access to the cathode side of the MEA. A current sensor is connected to measure the current in a short circuit across the sensor electrodes to provide an output signal functionally related to the concentration of methanol in the aqueous solution.

  15. Thermally integrated staged methanol reformer and method

    SciTech Connect (OSTI)

    Skala, Glenn William; Hart-Predmore, David James; Pettit, William Henry; Borup, Rodney Lynn

    2001-01-01

    A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

  16. New methanol plant for Kharg Island

    SciTech Connect (OSTI)

    Alperowicz, N.

    1992-04-08

    Iran`s National Petrochemical Co. (NPC; Teheran) plans to set up a world scale export-oriented methanol plant on Kharg Island in the Persian Gulf. It says discussions are being held with three Western groups - C. Itoh (Tokyo), H & G (London), and Uhde (Dortmund) - to supply the 660,000-m.t./year facility. The estimated $150-million project would be repaid through export of methanol within three to four years. NPC hopes to conclude talks this year. Strategically located, Kharg Island is described as a good location in peacetime. It already serves as an oil terminal. NPC has an LPG and sulfur complex there.

  17. 37 GHz METHANOL MASERS : HORSEMEN OF THE APOCALYPSE FOR THE CLASS II METHANOL MASER PHASE?

    SciTech Connect (OSTI)

    Ellingsen, S. P.; Breen, S. L.; Sobolev, A. M.; Voronkov, M. A.; Caswell, J. L.; Lo, N.

    2011-12-01

    We report the results of a search for class II methanol masers at 37.7, 38.3, and 38.5 GHz toward a sample of 70 high-mass star formation regions. We primarily searched toward regions known to show emission either from the 107 GHz class II methanol maser transition, or from the 6.035 GHz excited OH transition. We detected maser emission from 13 sources in the 37.7 GHz transition, eight of these being new detections. We detected maser emission from three sources in the 38 GHz transitions, one of which is a new detection. We find that 37.7 GHz methanol masers are only associated with the most luminous 6.7 and 12.2 GHz methanol maser sources, which in turn are hypothesized to be the oldest class II methanol sources. We suggest that the 37.7 GHz methanol masers are associated with a brief evolutionary phase (of 1000-4000 years) prior to the cessation of class II methanol maser activity in the associated high-mass star formation region.

  18. Reducing fuel consumption on the field, by continuously measuring fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    quality on electronically fuel injected engines. | Department of Energy fuel consumption on the field, by continuously measuring fuel quality on electronically fuel injected engines. Reducing fuel consumption on the field, by continuously measuring fuel quality on electronically fuel injected engines. Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. p-03_flot.pdf (270.06 KB) More Documents &

  19. Liquid phase methanol reactor staging process for the production of methanol

    DOE Patents [OSTI]

    Bonnell, Leo W.; Perka, Alan T.; Roberts, George W.

    1988-01-01

    The present invention is a process for the production of methanol from a syngas feed containing carbon monoxide, carbon dioxide and hydrogen. Basically, the process is the combination of two liquid phase methanol reactors into a staging process, such that each reactor is operated to favor a particular reaction mechanism. In the first reactor, the operation is controlled to favor the hydrogenation of carbon monoxide, and in the second reactor, the operation is controlled so as to favor the hydrogenation of carbon dioxide. This staging process results in substantial increases in methanol yield.

  20. Direct comparison between X-ray nanotomography and scanning electron microscopy for the microstructure characterization of a solid oxide fuel cell anode

    SciTech Connect (OSTI)

    Quey, R.; Suhonen, H.; Laurencin, J.; Cloetens, P.; Bleuet, P.

    2013-04-15

    X-ray computed nanotomography (nano-CT) and scanning electron microscopy (SEM) have been applied to characterize the microstructure of a Solid Oxide Fuel Cell (SOFC) anode. A direct comparison between the results of both methods is conducted on the same region of the microstructure to assess the spatial resolution of the nano-CT microstructure, SEM being taken as a reference. A registration procedure is proposed to find out the position of the SEM image within the nano-CT volume. It involves a second SEM observation, which is taken along an orthogonal direction and gives an estimate reference SEM image position, which is then refined by an automated optimization procedure. This enables an unbiased comparison between the cell porosity morphologies provided by both methods. In the present experiment, nano-CT is shown to underestimate the number of pores smaller than 1 ?m and overestimate the size of the pores larger than 1.5 ?m. - Highlights: ? X-ray computed nanotomography (nano-CT) and SEM are used to characterize an SOFC anode. ? A methodology is proposed to compare the nano-CT and SEM data on the same region. ? The spatial resolution of the nano-CT data is assessed from that comparison.

  1. Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

    SciTech Connect (OSTI)

    Grabow, Lars C.; Mavrikakis, Manos

    2011-03-04

    We present a comprehensive mean-field microkinetic model for the methanol synthesis and water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic acid (HCOOH) and hydroxymethoxy (CH?O?) and allows for the formation of formic acid (HCOOH), formaldehyde (CH?O), and methyl formate (HCOOCH?) as byproducts. All input model parameters were initially derived from periodic, self-consistent, GGA-PW91 density functional theory calculations on the Cu(111) surface and subsequently fitted to published experimentalmethanol synthesis rate data, which were collected under realistic conditions on a commercial Cu/ZnO/Al?O? catalyst. We find that the WGS reaction follows the carboxyl (COOH)-mediated path and that both CO and CO? hydrogenation pathways are active for methanol synthesis. Under typical industrial methanol synthesis conditions, CO? hydrogenation is responsible for ?2/3 of the methanol produced. The intermediates of the CO? pathway for methanol synthesis include HCOO*, HCOOH*, CH?O?*, CH?O*, and CH?O*. The formation of formate (HCOO*) from CO?* and H* on Cu(111) does not involve an intermediate carbonate (CO?*) species, and hydrogenation of HCOO* leads to HCOOH* instead of dioxymethylene (H?CO?*). The effect of CO is not only promotional; CO* is also hydrogenated in significant amounts to HCO*, CH?O *, CH?O*, and CH?OH*. We considered two possibilities for CO promotion: (a) removal of OH* via COOH* to form CO? and hydrogen (WGS), and (b) CO-assisted hydrogenation of various surface intermediates, with HCO* being the H-donor. Only the former mechanism contributes to methanol formation, but its effect is small compared with that of direct CO hydrogenation to methanol. Overall, methanol synthesis rates are limited by methoxy (CH?O*) formation at low CO?/(CO+CO?) ratios and by CH?O* hydrogenation in CO?-rich feeds. CH?O* hydrogenation is the common slow step for both the CO and the CO? methanol synthesis routes; the relative contribution of

  2. Synthetic carbonaceous fuels and feedstocks

    DOE Patents [OSTI]

    Steinberg, Meyer

    1980-01-01

    This invention relates to the use of a three compartment electrolytic cell in the production of synthetic carbonaceous fuels and chemical feedstocks such as gasoline, methane and methanol by electrolyzing an aqueous sodium carbonate/bicarbonate solution, obtained from scrubbing atmospheric carbon dioxide with an aqueous sodium hydroxide solution, whereby the hydrogen generated at the cathode and the carbon dioxide liberated in the center compartment are combined thermocatalytically into methanol and gasoline blends. The oxygen generated at the anode is preferably vented into the atmosphere, and the regenerated sodium hydroxide produced at the cathode is reused for scrubbing the CO.sub.2 from the atmosphere.

  3. Methanex, Hoechst Celanese dissolve methanol partnership

    SciTech Connect (OSTI)

    Morris, G.D.L.

    1993-03-31

    One of the many joint venture alliances recently announced in the petrochemical sector is ending in divorce. Hoechst Celanese Chemical (Dallas) and Methanex Corp. (Vancouver) are in the process of dissolving the partnership they had formed to restart Hoechst Celanese's methanol plant at Clear Lake, TX. Hoechst Celanese says it is actively seeking replacement partners and has several likely prospects, while Methanex is concentrating on its other ventures. Those include its just-completed acquisition of Fletcher Challenge's (Auckland, NZ) methanol business and a joint venture with American Cyanamid to convert an ammonia plant at Fortier, LA to methanol. Methanex will still be the world's largest producer of methanol. Officially, the negotiations between Methanex and Hoechst Celanese just broke down over the last month or so,' says Steve Yurich, operations manager for the Clear Lake plant. Market sources, however, say that Methanex found itself with too many irons in the fire' and pulled out before it ran into financial or perhaps even antitrust difficulties.

  4. Correlating the chemical composition and size of various metal oxide substrates with the catalytic activity and stability of as-deposited Pt nanoparticles for the methanol oxidation reaction

    SciTech Connect (OSTI)

    Megan E. Scofield; Wong, Stanislaus S.; Koenigsmann, Christopher; Bobb-Semple, Dara; Tao, Jing; Tong, Xiao; Wang, Lei; Lewis, Crystal S.; Vuklmirovic, Miomir; Zhu, Yimei; Adzic, Radoslav R.

    2015-12-09

    The performance of electrode materials in conventional direct alcohol fuel cells (DAFC) is constrained by (i) the low activity of the catalyst materials relative to their overall cost, (ii) the poisoning of the active sites due to the presence of partially oxidized carbon species (such as but not limited to CO, formate, and acetate) produced during small molecule oxidation, and (iii) the lack of catalytic stability and durability on the underlying commercial carbon support. Therefore, as a viable alternative, we have synthesized various metal oxide and perovskite materials of different sizes and chemical compositions as supports for Pt nanoparticles (NPs). Our results including unique mechanistic studies demonstrate that the SrRuO3 substrate with immobilized Pt NPs at its surface evinces the best methanol oxidation performance as compared with all of the other substrate materials tested herein, including commercial carbon itself. In addition, data from electron energy loss spectroscopy (EELS) and X-ray photoelectron spectroscopy (XPS) confirmed the presence of electron transfer from bound Pt NPs to surface Ru species within the SrRuO3 substrate itself, thereby suggesting that favorable metal support interactions are responsible for the increased methanol oxidation reaction (MOR) activity of Pt species with respect to the underlying SrRuO3 composite catalyst material.

  5. Correlating the chemical composition and size of various metal oxide substrates with the catalytic activity and stability of as-deposited Pt nanoparticles for the methanol oxidation reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Megan E. Scofield; Wong, Stanislaus S.; Koenigsmann, Christopher; Bobb-Semple, Dara; Tao, Jing; Tong, Xiao; Wang, Lei; Lewis, Crystal S.; Vuklmirovic, Miomir; Zhu, Yimei; et al

    2015-12-09

    The performance of electrode materials in conventional direct alcohol fuel cells (DAFC) is constrained by (i) the low activity of the catalyst materials relative to their overall cost, (ii) the poisoning of the active sites due to the presence of partially oxidized carbon species (such as but not limited to CO, formate, and acetate) produced during small molecule oxidation, and (iii) the lack of catalytic stability and durability on the underlying commercial carbon support. Therefore, as a viable alternative, we have synthesized various metal oxide and perovskite materials of different sizes and chemical compositions as supports for Pt nanoparticles (NPs).more » Our results including unique mechanistic studies demonstrate that the SrRuO3 substrate with immobilized Pt NPs at its surface evinces the best methanol oxidation performance as compared with all of the other substrate materials tested herein, including commercial carbon itself. In addition, data from electron energy loss spectroscopy (EELS) and X-ray photoelectron spectroscopy (XPS) confirmed the presence of electron transfer from bound Pt NPs to surface Ru species within the SrRuO3 substrate itself, thereby suggesting that favorable metal support interactions are responsible for the increased methanol oxidation reaction (MOR) activity of Pt species with respect to the underlying SrRuO3 composite catalyst material.« less

  6. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  7. CO{sub 2} mitigation and fuel production

    SciTech Connect (OSTI)

    Steinberg, M.

    1997-07-07

    Methanol as an alternative transportation fuel appears to be an effective intermediate agent, for reducing CO{sub 2} from the utility power and the transportation sectors. On the utilization side, methanol as a liquid fuel fits in well with the current infrastructure for storage and delivery to the automotive sector with better efficiency. On the production side, CO{sub 2} from fossil fuel plants together with natural gas and biomass can be used as feedstocks for methanol synthesis with reduced CO{sub 2}. Over the past several years, processes have emerged which have varying degrees of CO{sub 2} emission reduction depending on the feedstocks used for methanol synthesis process. This paper reviews the methanol processes from the point of view of production efficiency and CO{sub 2} emissions reduction. The processes include: (1) the Hydrocarb Process which primarily utilizes coal and natural gas and stores carbon, and (2) the Hynol Process which utilizes biomass (including carbonaceous wastes, municipal solid waste (MSW)) or coal and natural gas, and (3) the Carnol Process which utilizes natural gas and CO{sub 2} recovered from fossil fuel fired powered plant stacks, especially coal fired plants. The Carnol System consists of power generation, methanol production and methanol utilization as an automotive fuel. The efficiency and CO{sub 2} emissions for the entire system are compared to the conventional system of petroleum derived automotive fuel (gasoline) and coal fired power generation plants. CO{sub 2} reduction by as much as 56% and 77% can be achieved when methanol is used in internal combustion and fuel cell automotive vehicles, respectively.

  8. Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways

    SciTech Connect (OSTI)

    2012-02-15

    PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.

  9. Methanol production from Eucalyptus wood chips. Final report

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01

    This feasibility study includes all phases of methanol production from seedling to delivery of finished methanol. The study examines: production of 55 million, high quality, Eucalyptus seedlings through tissue culture; establishment of a Eucalyptus energy plantation on approximately 70,000 acres; engineering for a 100 million gallon-per-day methanol production facility; potential environmental impacts of the whole project; safety and health aspects of producing and using methanol; and development of site specific cost estimates.

  10. Final environmental assessment for the Liquid Phase Methanol (LPMEOH{trademark}) Project

    SciTech Connect (OSTI)

    1995-06-01

    The proposed project is to demonstrate on a commercial scale the production of methanol from coal-derived synthesis gas using the LPMEOH{trademark} process. The methanol produced during this demonstration will be used as a chemical feedstock (on-site) and/or as an alternative fuel in stationary and transportation applications (off-site). In addition, the production of dimethyl ether (DME) as a mixed co-product with methanol may be demonstrated for a six month period under the proposed project pending the results of laboratory/pilot-scale research on scale-up. The DME would be used as fuel in on-site boilers. The proposed LPMEOH facility would occupy approximately 0.6 acres of the 3,890-acre Eastman Chemical facility in Kingsport, TN. The effects of the proposed project include changes in air emissions, wastewater discharge, cooling water discharge, liquid waste quantities, transportation activities, socioeconomic effects, and quantity of solids for disposal. No substantive negative impacts or environmental concerns were identified.

  11. Fuel processor for fuel cell power system

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Springer, Thomas E.; Huff, James R.

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  12. Fuel cell generator

    DOE Patents [OSTI]

    Isenberg, Arnold O.

    1983-01-01

    High temperature solid oxide electrolyte fuel cell generators which allow controlled leakage among plural chambers in a sealed housing. Depleted oxidant and fuel are directly reacted in one chamber to combust remaining fuel and preheat incoming reactants. The cells are preferably electrically arranged in a series-parallel configuration.

  13. Direct Hydrogen PEMFC Manufacturing Cost Estimation for Automotive...

    Broader source: Energy.gov (indexed) [DOE]

    and Fuel Cells Program Record 14014: Fuel Cell System Cost - 2014 Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation Applications: 2013 Update

  14. Identification and Characterization of Near-Term Direct Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets ... Full Fuel-Cycle Comparison of Forklift Propulsion Systems Early Markets: Fuel Cells ...

  15. Fuel cell generator with fuel electrodes that control on-cell fuel reformation

    DOE Patents [OSTI]

    Ruka, Roswell J.; Basel, Richard A.; Zhang, Gong

    2011-10-25

    A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

  16. Proceedings of the 1995 SAE alternative fuels conference. P-294

    SciTech Connect (OSTI)

    1995-12-31

    This volume contains 32 papers and five panel discussions related to the fuel substitution of trucks, automobiles, buses, cargo handling equipment, diesel passenger cars, and pickup trucks. Fuels discussed include liquefied natural gas, natural gas, ethanol fuels, methanol fuels, dimethyl ether, methyl esters from various sources (rape oil, used cooking oils, soya, and canola oils), hydrogen fuels, and biodiesel. Other topics include fuel cell powered vehicles, infrastructure requirements for fuel substitution, and economics. Papers have been processed separately for inclusion on the data base.

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Signage The Ohio Turnpike Commission allows businesses to place their logos on directional signs within the right-of-way of state turnpikes. An alternative fuel retailer may include a marking or symbol within their logo indicating that it sells one or more types of alternative fuel. Alternative fuels are defined as E85, fuel blends containing at least 20% biodiesel (B20), natural gas, propane, hydrogen, or any fuel that the U.S. Department of Energy determines, by final rule, to be

  18. A survey of processes for producing hydrogen fuel from different sources for automotive-propulsion fuel cells

    SciTech Connect (OSTI)

    Brown, L.F.

    1996-03-01

    Seven common fuels are compared for their utility as hydrogen sources for proton-exchange-membrane fuel cells used in automotive propulsion. Methanol, natural gas, gasoline, diesel fuel, aviation jet fuel, ethanol, and hydrogen are the fuels considered. Except for the steam reforming of methanol and using pure hydrogen, all processes for generating hydrogen from these fuels require temperatures over 1000 K at some point. With the same two exceptions, all processes require water-gas shift reactors of significant size. All processes require low-sulfur or zero-sulfur fuels, and this may add cost to some of them. Fuels produced by steam reforming contain {approximately}70-80% hydrogen, those by partial oxidation {approximately}35-45%. The lower percentages may adversely affect cell performance. Theoretical input energies do not differ markedly among the various processes for generating hydrogen from organic-chemical fuels. Pure hydrogen has severe distribution and storage problems. As a result, the steam reforming of methanol is the leading candidate process for on-board generation of hydrogen for automotive propulsion. If methanol unavailability or a high price demands an alternative process, steam reforming appears preferable to partial oxidation for this purpose.

  19. Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

  20. Two dimensional point of use fuel cell : a final LDRD project report.

    SciTech Connect (OSTI)

    Zavadil, Kevin Robert; Hickner, Michael A.; Gross, Matthew L.

    2011-03-01

    The Proliferation Assessment (program area - Things Thin) within the Defense Systems and Assessment Investment Area desires high energy density and long-lived power sources with moderate currents (mA) that can be used as building blocks in platforms for the continuous monitoring of chemical, biological, and radiological agents. Fuel cells can be an optimum choice for a power source because of the high energy densities that are possible with liquid fuels. Additionally, power generation and fuel storage can be decoupled in a fuel cell for independent control of energy and power density for customized, application-driven power solutions. Direct methanol fuel cells (DMFC) are explored as a possible concept to develop into ultrathin or two-dimensional power sources. New developments in nanotechnology, advanced fabrication techniques, and materials science are exploited to create a planar DMFC that could be co-located with electronics in a chip format. Carbon nanotubes and pyrolyzed polymers are used as building block electrodes - porous, mechanically compliant current collectors. Directed assembly methods including surface functionalization and layer-by-layer deposition with polyelectrolytes are used to pattern, build, and add functionality to these electrodes. These same techniques are used to incorporate nanoscale selective electrocatalyst into the carbon electrodes to provide a high density of active electron transfer sites for the methanol oxidation and oxygen reduction reactions. The resulting electrodes are characterized in terms of their physical properties, electrocatalytic function, and selectivity to better understand how processing impacts their performance attributes. The basic function of a membrane electrode assembly is demonstrated for several prototype devices.

  1. Direct Internal Reformation and Mass Transport in the Solid Oxide Fuel Cell Anode: A Pore-Scale Lattice Boltzmann Study with Detailed Reaction Kinetics

    SciTech Connect (OSTI)

    Grew, Kyle N.; Joshi, Abhijit S.; Chiu, W. K. S.

    2010-11-30

    The solid oxide fuel cell (SOFC) allows the conversion of chemical energy that is stored in a given fuel, including light hydrocarbons, to electrical power. Hydrocarbon fuels, such as methane, are logistically favourable and provide high energy densities. However, the use of these fuels often results in a decreased efficiency and life. An improved understanding of the reactive flow in the SOFC anode can help address these issues. In this study, the transport and heterogeneous internal reformation of a methane based fuel is addressed. The effect of the SOFC anode's complex structure on transport and reactions is shown to exhibit a complicated interplay between the local molar concentrations and the anode structure. Strong coupling between the phenomenological microstructures and local reformation reaction rates are recognised in this study, suggesting the extension to actual microstructures may provide new insights into the reformation processes.

  2. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOTH) Process

    SciTech Connect (OSTI)

    1998-12-21

    The Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOI-P Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. During this quarter, initial planning and procurement work continued on the seven project sites which have been accepted for participation in the off-site, product-use test program. Approximately 12,000 gallons of fuel-grade methanol (98+ wt% methanol, 4 wt% water) produced during operation on carbon monoxide (CO)-rich syngas at the LPMEOW Demonstration Unit was loaded into trailers and shipped off-site for Mure product-use testing. At one of the projects, three buses have been tested on chemical-grade methanol and on fhel-grade methanol from the LPMEOW Demonstration Project. During the reporting period, planning for a proof-of-concept test run of the Liquid Phase Dimethyl Ether (LPDME~ Process at the Alternative Fuels Development Unit (AFDU) in LaPorte, TX continued. The commercial catalyst manufacturer (Calsicat) has prepared the first batch of dehydration catalyst in large-scale equipment. Air Products will test a sample of this material in the laboratory autoclave. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laborato~ autoclave), was monitored for the initial extended operation at the lower initial reactor operating temperature of 235oC. At this condition, the decrease in catalyst activity with time from the period 20 December 1997 through 27 January 1998 occurred at a rate of 1.0% per

  3. Vehicular fuels and additives for the future

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    Interest in automotive fuel is resurging. Automobile fuels must increasingly deal with clean air regulations and ozone problems. Furthermore, feedstocks become heavier,as refinery production changes, as more unleaded is produced, and as an increasing number of pollution regulations must be satisfied greater attention will be paid to better mixtures, solvents, additives, and neat methanol. BCC report analyzes developments technologies, markets, players and the political/regulations aspects of this important market. Study also assesses the advantages and drawbacks of methanol, ethanol, MTBE and other additives which have their place as octane enhancers and fuel substitutes-all now deeply involved in the gasoline modification battle. Other issues addressed are subsidies, farm lobbying, imports, pricing, economics, Detroit's response, neat fuel testing projects, volatility problems vs. fewer ozone-forming hydrocarbon species, and emission ratings.

  4. WABASH RIVER IMPPCCT, INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES

    SciTech Connect (OSTI)

    Doug Strickland

    2001-09-28

    In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the Gasification Engineering Corporation and an Industrial Consortium are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an Early Entrance Coproduction Plant located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, financial, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility Study and conceptual design for an integrated demonstration facility and for fence-line commercial plants operated at The Dow Chemical Company or Dow Corning Corporation chemical plant locations (i.e. the Commercial Embodiment Plant or CEP) (2) Research, development, and testing to address any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at

  5. Direct Visualization of Spray and Combustion Inside a DI-SI Engine and Its Implications to Flex-Fuel VVT Operations

    Broader source: Energy.gov [DOE]

    Fuel, injection timing, and valve deactivation in a DI optical accessible engine with side-mounted, multi-hole injector are investigated using CFD and high-speed imaging of sprays and combustion.

  6. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Alonso-Vante, Nicolas (Buxerolles, FR); Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

    2009-09-15

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  7. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Zelenay, Piotr; Choi, Jong-Ho; Alonso-Vante, Nicolas; Wieckowski, Andrzej; Cao, Dianxue

    2010-08-24

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  8. Performance assessment of the direct disposal in unsaturated tuff or spent nuclear fuel and high-level waste owned by USDOE: Volume 2, Methodology and results

    SciTech Connect (OSTI)

    Rechard, R.P.

    1995-03-01

    This assessment studied the performance of high-level radioactive waste and spent nuclear fuel in a hypothetical repository in unsaturated tuff. The results of this 10-month study are intended to help guide the Office of Environment Management of the US Department of Energy (DOE) on how to prepare its wastes for eventual permanent disposal. The waste forms comprised spent fuel and high-level waste currently stored at the Idaho National Engineering Laboratory (INEL) and the Hanford reservations. About 700 metric tons heavy metal (MTHM) of the waste under study is stored at INEL, including graphite spent nuclear fuel, highly enriched uranium spent fuel, low enriched uranium spent fuel, and calcined high-level waste. About 2100 MTHM of weapons production fuel, currently stored on the Hanford reservation, was also included. The behavior of the waste was analyzed by waste form and also as a group of waste forms in the hypothetical tuff repository. When the waste forms were studied together, the repository was assumed also to contain about 9200 MTHM high-level waste in borosilicate glass from three DOE sites. The addition of the borosilicate glass, which has already been proposed as a final waste form, brought the total to about 12,000 MTHM.

  9. Activation of catalysts for synthesizing methanol from synthesis gas

    DOE Patents [OSTI]

    Blum, David B.; Gelbein, Abraham P.

    1985-01-01

    A method for activating a methanol synthesis catalyst is disclosed. In this method, the catalyst is slurried in an inert liquid and is activated by a reducing gas stream. The activation step occurs in-situ. That is, it is conducted in the same reactor as is the subsequent step of synthesizing methanol from a methanol gas stream catalyzed by the activated catalyst still dispersed in a slurry.

  10. Analysis of on-board fuel processing designs for PEM fuel cell vehicles

    SciTech Connect (OSTI)

    Kartha, S.; Fischer, S.; Kreutz, T.

    1996-12-31

    As a liquid fuel with weight and volume energy densities comparable to those of gasoline, methanol is an attractive energy carrier for mobile power systems. It is available without contaminants such as sulfur, and can be easily reformed at relatively low temperatures with inexpensive catalysts. This study is concerned with comparing the net efficiencies of PEM fuel cell vehicles fueled with methanol and hydrogen, using fuel cell system models developed using ASPEN chemical process simulation software. For both the methanol and hydrogen systems, base case designs are developed and several variations are considered that differ with respect to the degree of system integration for recovery of heat and compressive work. The methanol systems are based on steam reforming with the water-gas shift reaction and preferential oxidation, and the hydrogen systems are based on compressed hydrogen. This analysis is an exercise in optimizing the system design for each fuel, which ultimately entails balancing system efficiency against a host of other considerations, including system complexity, performance, cost, reliability, weight and volume.

  11. Fuel Cell Power Plant Experience Naval Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy/ Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC March 29, 2011 FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. *FuelCell Energy, Inc. *Renewable and Liquid Fuels Experience *HTPEM Fuel Cell Stack for Shipboard APU *Solid Oxide Experience and Applications DOE-ONR Workshop FuelCell Energy, the FuelCell

  12. Spiral cooled fuel nozzle

    DOE Patents [OSTI]

    Fox, Timothy; Schilp, Reinhard

    2012-09-25

    A fuel nozzle for delivery of fuel to a gas turbine engine. The fuel nozzle includes an outer nozzle wall and a center body located centrally within the nozzle wall. A gap is defined between an inner wall surface of the nozzle wall and an outer body surface of the center body for providing fuel flow in a longitudinal direction from an inlet end to an outlet end of the fuel nozzle. A turbulating feature is defined on at least one of the central body and the inner wall for causing at least a portion of the fuel flow in the gap to flow transverse to the longitudinal direction. The gap is effective to provide a substantially uniform temperature distribution along the nozzle wall in the circumferential direction.

  13. Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report

    SciTech Connect (OSTI)

    Dombek, B.D.

    1996-03-01

    The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  15. Organic fuel cells and fuel cell conducting sheets

    DOE Patents [OSTI]

    Masel, Richard I.; Ha, Su; Adams, Brian

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  16. Alternative transportation fuels

    SciTech Connect (OSTI)

    Askew, W.S.; McNamara, T.M.; Maxfield, D.P.

    1980-01-01

    The commercialization of alternative fuels is analyzed. Following a synopsis of US energy use, the concept of commercialization, the impacts of supply shortages and demand inelasticity upon commercialization, and the status of alternative fuels commercialization to date in the US are discussed. The US energy market is viewed as essentially numerous submarkets. The interrelationship among these submarkets precludes the need to commercialize for a specific fuel/use. However, the level of consumption, the projected growth in demand, and the inordinate dependence upon foreign fuels dictate that additional fuel supplies in general be brought to the US energy marketplace. Commercialization efforts encompass a range of measures designed to accelerate the arrival of technologies or products in the marketplace. As discussed in this paper, such a union of willing buyers and willing sellers requires that three general conditions be met: product quality comparable to existing products; price competitiveness; and adequate availability of supply. Product comparability presently appears to be the least problematic of these three requirements. Ethanol/gasoline and methanol/gasoline blends, for example, demonstrate the fact that alternative fuel technologies exist. Yet price and availability (i.e., production capacity) remain major obstacles. Given inelasticity (with respect to price) in the US and abroad, supply shortages - actual or contrived - generate upward price pressure and should make once-unattractive alternative fuels more price competitive. It is noted, however, that actual price competitiveness has been slow to occur and that even with price competitiveness, the lengthy time frame needed to achieve significant production capacity limits the near-term impact of alternative fuels.

  17. Staged direct injection diesel engine

    DOE Patents [OSTI]

    Baker, Quentin A.

    1985-01-01

    A diesel engine having staged injection for using lower cetane number fuels than No. 2 diesel fuel. The engine includes a main fuel injector and a pilot fuel injector. Pilot and main fuel may be the same fuel. The pilot injector injects from five to fifteen percent of the total fuel at timings from 20.degree. to 180.degree. BTDC depending upon the quantity of pilot fuel injected, the fuel cetane number and speed and load. The pilot fuel injector is directed toward the centerline of the diesel cylinder and at an angle toward the top of the piston, avoiding the walls of the cylinder. Stratification of the early injected pilot fuel is needed to reduce the fuel-air mixing rate, prevent loss of pilot fuel to quench zones, and keep the fuel-air mixture from becoming too fuel lean to become effective. In one embodiment, the pilot fuel injector includes a single hole for injection of the fuel and is directed at approximately 48.degree. below the head of the cylinder.

  18. Fuel Options

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production Market Transformation Fuel Cells Predictive Simulation of Engines ... Twitter Google + Vimeo Newsletter Signup SlideShare Fuel Options HomeCapabilitiesFuel ...

  19. Combustor with two stage primary fuel assembly

    DOE Patents [OSTI]

    Sharifi, Mehran; Zolyomi, Wendel; Whidden, Graydon Lane

    2000-01-01

    A combustor for a gas turbine having first and second passages for pre-mixing primary fuel and air supplied to a primary combustion zone. The flow of fuel to the first and second pre-mixing passages is separately regulated using a single annular fuel distribution ring having first and second row of fuel discharge ports. The interior portion of the fuel distribution ring is divided by a baffle into first and second fuel distribution manifolds and is located upstream of the inlets to the two pre-mixing passages. The annular fuel distribution ring is supplied with fuel by an annular fuel supply manifold, the interior portion of which is divided by a baffle into first and second fuel supply manifolds. A first flow of fuel is regulated by a first control valve and directed to the first fuel supply manifold, from which the fuel is distributed to first fuel supply tubes that direct it to the first fuel distribution manifold. From the first fuel distribution manifold, the first flow of fuel is distributed to the first row of fuel discharge ports, which direct it into the first pre-mixing passage. A second flow of fuel is regulated by a second control valve and directed to the second fuel supply manifold, from which the fuel is distributed to second fuel supply tubes that direct it to the second fuel distribution manifold. From the second fuel distribution manifold, the second flow of fuel is distributed to the second row of fuel discharge ports, which direct it into the second pre-mixing passage.

  20. Fuel cells for transportation applications. Progress report, January 1-December 31, 1981

    SciTech Connect (OSTI)

    Huff, J.R.

    1982-06-01

    The aims of the program are to use the fuel cell's high efficiency, low pollution (both air and noise), and ability to use nonpetroleum fuels to develop a prototype vehicle power plant with the following characteristics: better than vehicles powered by an internal combustion engine (ICE); purchase cost competitive with ICE vehicles and superior maintenance cost; range, performance, and refueling time equivalent to ICE vehicles; and utilization of methanol or some other nonpetroleum-based fuel that can be easily distributed and stored. The fuel cell technologies currently being assessed for potential vehicle use are: phosphoric acid electrolyte fuel cells (PAFC); solid polymer electrolyte (SPE) fuel cells; and super acid electrolyte fuel cells. From these alternatives, one or two technologies will be selected for further electrochemical research with emphasis directed at the requirements peculiar to vehicles. In addition, a verification effort will be closely coupled with the electrochemical basic research program, which both have the objectives of reducing or eliminating platinum requirements, developing improved and/or less costly electrolytes, and increasing cell performance. The results of the assessments of the PAFC and the SPE fuel cell systems substantiate the technical feasibility of using these two systems in vehicular applications. Initial results indicate substantial energy savings from using fuel cell power plants in heavy-duty freight locomotives and inland waterway push-tow boats. More information is needed on the operational duty cycles of these applications to complete the assessment and suggest what research is required. Adsorption studies on cathodes in various acids confirmed the concept that to improve the oxygen electrode performances, neutral or anionic species must not be allowed to adsorb. Various means of achieving this are being explored. (WHK)

  1. Microbial fuel cell treatment of fuel process wastewater

    DOE Patents [OSTI]

    Borole, Abhijeet P; Tsouris, Constantino

    2013-12-03

    The present invention is directed to a method for cleansing fuel processing effluent containing carbonaceous compounds and inorganic salts, the method comprising contacting the fuel processing effluent with an anode of a microbial fuel ell, the anode containing microbes thereon which oxidatively degrade one or more of the carbonaceous compounds while producing electrical energy from the oxidative degradation, and directing the produced electrical energy to drive an electrosorption mechanism that operates to reduce the concentration of one or more inorganic salts in the fuel processing effluent, wherein the anode is in electrical communication with a cathode of the microbial fuel cell. The invention is also directed to an apparatus for practicing the method.

  2. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-09-30

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1--6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  3. Low temperature catalyst system for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.

    1984-04-20

    This patent discloses a catalyst and process useful at low temperatures (150/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen. The catalyst components are used in slurry form and comprise (1) a complex reducing agent derived from the component structure NaH-ROH-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms and (2) a metal carbonyl of a group VI (Mo, Cr, W) metal. For the first component, Nic is preferred (where M = Ni and R = tertiary amyl). For the second component, Mo(CO)/sub 6/ is preferred. The mixture is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  4. Long-term methanol vehicle test program. Final subcontract report, 1 November 1992--1 February 1995

    SciTech Connect (OSTI)

    Jones, J.C.; Maxwell, T.T.

    1995-09-01

    Work was sperformed to determine effects of methanol fuel on engine performance and exhaust emissions during long-term use in a 1988 Chevrolet Corsica. Engine wear, gasket performance, fuel economy, emissions level, oil consumption, and overall vehicle performance were monitored over 22,000 miles. Baselines were established at the beginning for comparison: engine was disassembled, bearing/ring clearances and cam profiles were measured. Higher flow rate fuel injectors from AC Rochester were installed and the computer system calibrated for M100 fuel. The vehicle durability test increased oil consumption by 26% under cold-start conditions, 9% under hot start. Oil consumption under hot start was higher than under cold start by as much as 56%; effect of component temperatures on oil viscosity appears to be the cause. It is recommended that oil consumption of a gasoline-fueled vehicle be measured in order to normalize the effect of methanol operation on oil consumption, and to study the effect of steady-state and transient conditions on oil consumption.

  5. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  6. The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1990-02-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fueling Infrastructure Tax Credit For tax years beginning on or after January 1, 2015, an income tax credit is available for the cost of constructing a qualified alternative fueling station. The credit is 20% of the costs directly associated with the purchase and installation of any alternative fuel storage and dispensing equipment or electric vehicle supply equipment (EVSE), up to $1,500 for individuals or $20,000 for businesses. Tax credits may be carried forward for two years and

  8. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  9. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W.; Wender, Irving; Palekar, Vishwesh M.

    1993-01-01

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  10. Tilted fuel cell apparatus

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine; Krueger, Roger L.

    2005-04-12

    Bipolar, tilted embodiments of high temperature, molten electrolyte electrochemical cells capable of directly converting carbon fuel to electrical energy are disclosed herein. The bipolar, tilted configurations minimize the electrical resistance between one cell and others connected in electrical series. The tilted configuration also allows continuous refueling of carbon fuel.

  11. Preliminary Simulations for Geometric Optimization of a High-Energy Delayed Gamma Spectrometer for Direct Assay of Pu in Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Kulisek, Jonathan A.; Campbell, Luke W.; Rodriguez, Douglas C.

    2012-06-07

    High-energy, beta-delayed gamma-ray spectroscopy is under investigation as part of the Next Generation Safeguard Initiative effort to develop non-destructive assay instruments for plutonium mass quantification in spent nuclear fuel assemblies. Results obtained to date indicate that individual isotope-specific signatures contained in the delayed gamma-ray spectra can potentially be used to quantify the total fissile content and individual weight fractions of fissile and fertile nuclides present in spent fuel. Adequate assay precision for inventory analysis can be obtained using a neutron generator of sufficient strength and currently available detection technology. In an attempt to optimize the geometric configuration and material composition for a delayed gamma measurement on spent fuel, the current study applies MCNPX, a Monte Carlo radiation transport code, in order to obtain the best signal-to-noise ratio. Results are presented for optimizing the neutron spectrum tailoring material, geometries to maximize thermal or fast fissions from a given neutron source, and detector location to allow an acceptable delayed gamma-ray signal while achieving a reasonable detector lifetime while operating in a high-energy neutron field. This work is supported in part by the Next Generation Safeguards Initiative, Office of Nuclear Safeguards and Security, National Nuclear Security Administration.

  12. Fuel vaporization improves fuel economy of alcohol-burning Sl engines

    SciTech Connect (OSTI)

    Hardenberg, H.O.; Metsch, H.I.; Schaefer, A.J.

    1982-10-01

    Fuel vaporization and combustion of the thereby achieved homogeneous mixtures improve the overall efficiency of SI engines in comparison to operation with liquid fuels. The improvements result from a recovery of waste heat and the thus achieved greater usable energy of the fuel, which is increased by the heat of vaporization over the lower calorific value of the liquid fuel, and from the fact that very lean mixtures can be burnt without misfiring. The favorable fuel economy of the air/fuel-vapor mixture-aspirating engine is explained with the aid of engine cycle computation which also enables comparison of different combustion processes. Consideration of common substances shows that methanol is the fuel best suited for this type of SI engine.

  13. The low-temperature partial-oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Passenger cars powered by fuel cell propulsion systems with high efficiency offer superior fuel economy, very low to zero pollutant emissions, and the option to operate on alternative and/or renewable fuels. Although the fuel cell operates on hydrogen, a liquid fuel such as methanol or gasoline is more attractive for automotive use because of the convenience in handling and vehicle refueling. Such a liquid fuel must be dynamically converted (reformed) to hydrogen on board the vehicle in real time to meet fluctuating power demands. This paper describes the low-temperature Argonne partial-oxidation reformer (APOR) developed for this application. The APOR is a rapid-start, compact, lightweight, catalytic device that is efficient and dynamically responsive. The reformer is easily controlled by varying the feed rates of the fuel, water, and air to satisfy the rapidly changing system power demands during the vehicle`s driving cycle.

  14. Fuel Tables.indd

    Gasoline and Diesel Fuel Update (EIA)

    Where shown, (s) Physical unit value less than 0.5 or Btu value less than 0.05. Notes: * There are no direct fuel costs for hydroelectric power. * Totals may not equal sum of ...

  15. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Where shown, (s) Physical unit value less than 0.5 or Btu value less than 0.05. Notes: * There are no direct fuel costs for wind energy. * Totals may not equal sum of components ...

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    The incentive must first be taken as a credit against the blender's fuel tax liability; any excess over this tax liability may be claimed as a direct payment from the IRS. Claims ...

  17. Injector having multiple fuel pegs

    DOE Patents [OSTI]

    Hadley, Mark Allan; Felling, David Kenton

    2013-04-30

    A fuel injector is provided, including a fuel injector body, a plurality of fuel vanes, and a plurality of fuel pegs. The injector body includes a manifold and an inlet. The manifold is configured for receiving fuel, and the inlet is configured for receiving air. The fuel vanes are located within the injector body and are positioned in a direction that is generally parallel with a longitudinal axis of the injector body to orient the air flowing from the inlet. The plurality of fuel pegs are fluidly connected to the manifold and are arranged within the plurality of fuel vanes. The plurality of fuel pegs are each spaced at a distance that is about equal between each of the plurality of fuel pegs.

  18. Alternatives to traditional transportation fuels 1994. Volume 1

    SciTech Connect (OSTI)

    1996-02-01

    In this report, alternative and replacement fuels are defined in accordance with the EPACT. Section 301 of the EPACT defines alternative fuels as: methanol, denatured ethanol, and other alcohols; mixtures containing 85% or more (or such other percentage, but not less than 70%, as determined by the Secretary of Energy, by rule, to provide for requirements relating to cold start, safety, or vehicle functions) by volume of methanol, denatured ethanol, and other alcohols with gasoline or other fuels; natural gas; liquefied petroleum gas; hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials; electricity (including electricity from solar energy); and any other fuel the Secretary determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. The EPACT defines replacement fuels as the portion of any motor fuel that is methanol, ethanol, or other alcohols, natural gas, liquefied petroleum gas, hydrogen, coal-derived liquid fuels, fuels (other than alcohol) derived from biological materials, electricity (including electricity from solar energy), ethers, or any other fuel the Secretary of Energy determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. This report covers only those alternative and replacement fuels cited in the EPACT that are currently commercially available or produced in significant quantities for vehicle demonstration purposes. Information about other fuels, such as hydrogen and biodiesel, will be included in later reports as those fuels become more widely used. Annual data are presented for 1992 to 1996. Data for 1996 are based on plans or projections for 1996.

  19. Synthesis of methanol and dimethyl ether from syngas over Pd/ZnO/Al2O3 catalysts

    SciTech Connect (OSTI)

    Lebarbier, Vanessa M.; Dagle, Robert A.; Kovarik, Libor; Lizarazo-Adarme, Jair A.; King, David L.; Palo, Daniel R.

    2012-01-01

    A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250C to 380C. High temperatures (e.g. 380C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSVs and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pd particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

  20. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.; Mahajan, Devinder

    1986-01-01

    A catalyst and process useful at low temperatures (below about 160.degree. C.) and preferably in the range 80.degree.-120.degree. C. used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa--M(OAc).sub.2 where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M=Ni and R=tertiary amyl). Mo(CO).sub.6 is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  1. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-10-28

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is NiC (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  2. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1985-03-12

    A catalyst and process useful at low temperatures (below about 160/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH-RONa-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)/sub 6/ is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  3. Evaluation of Alternate Materials for Coated Particle Fuels for the Gas-Cooled Fast Reactor. Laboratory Directed Research and Development Program FY 2006 Final Report

    SciTech Connect (OSTI)

    Paul A. Demkowicz; Karen Wright; Jian Gan; David Petti; Todd Allen; Jake Blanchard

    2006-09-01

    Candidate ceramic materials were studied to determine their suitability as Gas-Cooled Fast Reactor particle fuel coatings. The ceramics examined in this work were: TiC, TiN, ZrC, ZrN, AlN, and SiC. The studies focused on (i) chemical reactivity of the ceramics with fission products palladium and rhodium, (ii) the thermomechanical stresses that develop in the fuel coatings from a variety of causes during burnup, and (iii) the radiation resiliency of the materials. The chemical reactivity of TiC, TiN, ZrC, and ZrN with Pd and Rh were all found to be much lower than that of SiC. A number of important chemical behaviors were observed at the ceramic-metal interfaces, including the formation of specific intermetallic phases and a variation in reaction rates for the different ceramics investigated. Based on the data collected in this work, the nitride ceramics (TiN and ZrN) exhibit chemical behavior that is characterized by lower reaction rates with Pd and Rh than the carbides TiC and ZrC. The thermomechanical stresses in spherical fuel particle ceramic coatings were modeled using finite element analysis, and included contributions from differential thermal expansion, fission gas pressure, fuel kernel swelling, and thermal creep. In general the tangential stresses in the coatings during full reactor operation are tensile, with ZrC showing the lowest values among TiC, ZrC, and SiC (TiN and ZrN were excluded from the comprehensive calculations due to a lack of available materials data). The work has highlighted the fact that thermal creep plays a critical role in the development of the stress state of the coatings by relaxing many of the stresses at high temperatures. To perform ion irradiations of sample materials, an irradiation beamline and high-temperature sample irradiation stage was constructed at the University of Wisconsins 1.7MV Tandem Accelerator Facility. This facility is now capable of irradiating of materials to high dose while controlling sample temperature

  4. Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O

    SciTech Connect (OSTI)

    Zhao, Yafan; Yang, Yong; Mims, Charles A.; Peden, Charles HF; Li, Jun; Mei, Donghai

    2011-05-31

    Methanol synthesis from CO2 hydrogenation on supported Cu catalysts is of considerable importance in the chemical and energy industries. Although extensive experimental and theoretical efforts have been carried out in the past decades, the most fundamental questions such as the reaction mechanisms and the key reaction intermediates are still in debate. In the present work, a comprehensive reaction network for CO2 hydrogenation to methanol on Cu(111) was studied using periodic density functional theory (DFT) calculations. All of the elementary reaction steps in the reaction network were identified in an unbiased way with the dimer method. Our calculation results show that methanol synthesis from direct hydrogenation of formate on Cu(111) is not feasible due to the high activation barriers for some of the elementary steps. Instead, we find that CO2 hydrogenation to hydrocarboxyl (trans-COOH) is kinetically more favorable than formate in the presence of H2O via a unique proton transfer mechanism. The trans-COOH is then converted into hydroxymethylidyne (COH) via dihydroxycarbene (COHOH) intermediates, followed by three consecutive hydrogenation steps to form hydroxymethylene (HCOH), hydroxymethyl (H2COH), and methanol. This is consistent with recent experimental observations [1], which indicate that direct hydrogenation of formate will not produce methanol under dry hydrogen conditions. Thus, both experiment and computational modeling clearly demonstrate the important role of trace amounts of water in methanol synthesis from CO2 hydrogenation on Cu catalysts. The proposed methanol synthesis route on Cu(111) not only provides new insights into methanol synthesis chemistry, but also demonstrates again that spectroscopically observed surface species are often not critical reaction intermediates but rather spectator species. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  5. Manufacturing Cost Analysis of 100 and 250 kW Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Both polymer electrolyte membrane (PEM) fuel cell stacks and solid oxide fuel cell (SOFC) ... kW Direct Hydrogen Polymer Electrolyte Membrane (PEM) Fuel Cell for Material Handling ...

  6. Alternative fuels: Promise or Problem

    SciTech Connect (OSTI)

    Moyad, A. )

    1989-11-01

    The Bush administration's proposals to revamp the Clean Air Act received mixed reviews. The alternative fuels proposal in the administration's bill, if passed, would mandate the sale of so-called clean-fueled vehicles (CFVs) in the nine worst ozone non-attainment areas in the country. In areas failing to plan for reductions of volatile organic compounds (VOCs) and toxic air chemicals equivalent to those outlined in the Bush proposal, a total of 500,000 CFVs would have to be sold in 1995, 750,000 in 1996, and 1,000,000 each year from 1997-2004. What is unclear, however, is who will manufacture, sell, or purchase these vehicles. The paper discusses the pros and cons of ethanol, methanol, and compressed natural gas (CNG), the major alternative fuels being considered as supplements or replacements for gasoline.

  7. Capital requirements and fuel-cycle energy and emissions impacts of potential PNGV fuels.

    SciTech Connect (OSTI)

    Johnson, L.; Mintz, M.; Singh, M.; Stork, K.; Vyas, A.; Wang, M.

    1999-03-11

    Our study reveals that supplying gasoline-equivalent demand for the low-market-share scenario requires a capital investment of less than $40 billion for all fuels except H{sub 2}, which will require a total cumulative investment of $150 billion. By contrast, cumulative capital investments under the high-market-share scenario are $50 billion for LNG, $90 billion for ethanol, $100 billion for methanol, $160 billion for CNG and DME, and $560 billion for H{sub 2}. Although these substantial capital requirements are spread over many years, their magnitude could pose a challenge to the widespread introduction of 3X vehicles. Fossil fuel use by US light-duty vehicles declines significantly with introduction of 3X vehicles because of fuel-efficiency improvements for 3X vehicles and because of fuel substitution (which applies to the nonpetroleum-fueled alternatives). Petroleum use for light-duty vehicles in 2030 is reduced by as much as 45% relative to the reference scenario. GHG emissions follow a similar pattern. Total GHG emissions decline by 25-30% with most of the propulsion system/fuel alternatives. For those using renewable fuels (i.e., ethanol and H{sub 2} from solar energy), GHG emissions drop by 33% (H{sub 2}) and 45% (ethanol). Among urban air pollutants, urban NOX emissions decline slightly for 3X vehicles using CIDI and SIDI engines and drop substantially for fuel-cell vehicles. Urban CO emissions decline for CIDI and FCV alternatives, while VOC emissions drop significantly for all alternatives except RFG-, methanol-, and ethanol-fueled SIDI engines. With the exception of CIDI engines fueled by RFD, FT50, or B20 (which increase urban PM{sub 10} emissions by over 30%), all propulsion system/fuel alternatives reduce urban PM{sub 10} emissions. Reductions are approximately 15-20% for fuel cells and for methanol-, ethanol-, CNG-, or LPG-fueled SIDI engines. Table 3 qualitatively summarizes impacts of the 13 alternatives on capital requirements and on energy use and

  8. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (ceria) in contact with copper will form metal-oxide interfaces that allow the adsorption and activation of CO2, opening a new reaction pathway for the synthesis of methanol....

  9. Synthesis of Pt{sub 3}Sn alloy nanoparticles and their catalysis for electro-oxidation of CO and methanol.

    SciTech Connect (OSTI)

    Liu, Y.; Li, D.; Stamenkovic, V. R.; Soled, S.; Henao, J. D.; Sun, S.

    2011-11-04

    Monodisperse Pt{sub 3}Sn alloy nanoparticles (NPs) were synthesized by a controlled coreduction of Pt(II) acetylacetonate and Sn(II) acetylacetonate at 180-280 C in 1-octadecene. In the synthesis, oleylamine was used as a reducing agent, and oleylamine/oleic acid served as surfactants. The sizes of the Pt{sub 3}Sn NPs were tuned from 4 to 7 nm by controlling the metal salt injection temperatures from 180 to 240 C. These monodisperse Pt3Sn NPs were highly active for CO and methanol oxidation in 0.1 M HClO{sub 4} solutions, and their activity and stability could be further improved by a postsynthesis thermal treatment at 400 C in Ar + 5% H{sub 2} for 1 h. They are promising as a practical catalyst for CO and methanol oxidation reactions in polymer electrolyte membrane fuel cell conditions.

  10. Fuels From Sunlight Hub | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels From Sunlight Hub Fuels From Sunlight Hub August 1, 2010 - 4:11pm Addthis Researchers from across disciplines are working together to create energy and fuels directly from sunlight, and create a process that's economically viable. Researchers from across disciplines are working together to create energy and fuels directly from sunlight, and create a process that's economically viable. The Solar Energy-to-Fuels Conversion Challenge Designing highly efficient, non-biological, energy

  11. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{sup trademark}) process. Third quarterly report, 1996

    SciTech Connect (OSTI)

    1997-09-01

    The Liquid Phase Methanol (LPMEOH)(TM) demonstration project at King sport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L. P. (the Partnership). A demonstration unit producing 80,000 gallons per day (260 TPD) of methanol is being designed and constructed at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. The Partnership will own and operate the facility for the four year demonstration period. This project is sponsored under the DOE`s Clean Coal Technology Program, and its primary objective is to `demonstrate the production of methanol using the LPMEOH(TM) Process in conjunction with an integrated coal gasification facility.` The project will also demonstrate the suitability of the methanol produced for use as a chemical feedstock or as a low-sulfur dioxide, low-nitrogen oxides alternative fuel in stationary and transportation applications. The project may also demonstrate the production of dimethyl ether (DME) as a mixed coproduct with methanol, if laboratory- and pilot-scale research and market verification studies show promising results. If implemented, the DME would be produced during the last six months of the four year demonstration period. The LPMEOH(TM) process is the product of a cooperative development effort by Air Products and the DOE in a program that started in 1981. It was successfully piloted at a 10-TPD rate in the DOE-owned experimental unit at Air Products` LaPorte, Texas, site. This demonstration project is the culmination of that extensive cooperative development effort.

  12. Fuel axial relocation in ballooning fuel rods. [PWR; BWR

    SciTech Connect (OSTI)

    Siefken, L.J.

    1983-01-01

    Fuel movement, in the longitudinal direction in ballooning fuel rods, shifts the position of heat generation and may cause an increase in cladding temperature in the ballooning region. This paper summarizes the axial fuel relocation data obtained in fuel rod tests conducted in the United States and the Federal Republic of Germany, describes a model for calculating fuel axial relocation, and gives a quantitative analysis of the impact of fuel relocation on cladding temperature. The amount of fuel relocation in 18 ballooned fuel rods was determined from neutron radiographs, niobium gamma decay counts, and photomicrographs. The fuel rods had burnups in the range of 0 to 35,000 MWd/t and cladding hoop strains varying from 0 to 72%.

  13. Methanol synthesis on ZnO(0001{sup }). IV. Reaction mechanisms and electronic structure

    SciTech Connect (OSTI)

    Frenzel, Johannes Marx, Dominik

    2014-09-28

    Methanol synthesis from CO and H{sub 2} over ZnO, which requires high temperatures and high pressures giving rise to a complex interplay of physical and chemical processes over this heterogeneous catalyst surface, is investigated using ab initio simulations. The redox properties of the surrounding gas phase are known to directly impact on the catalyst properties and thus, set the overall catalytic reactivity of this easily reducible oxide material. In Paper III of our series [J. Kiss, J. Frenzel, N. N. Nair, B. Meyer, and D. Marx, J. Chem. Phys. 134, 064710 (2011)] we have qualitatively shown that for the partially hydroxylated and defective ZnO(0001{sup }) surface there exists an intricate network of surface chemical reactions. In the present study, we employ advanced molecular dynamics techniques to resolve in detail this reaction network in terms of elementary steps on the defective surface, which is in stepwise equilibrium with the gas phase. The two individual reduction steps were investigated by ab initio metadynamics sampling of free energy landscapes in three-dimensional reaction subspaces. By also sampling adsorption and desorption processes and thus molecular species that are in the gas phase but close to the surface, our approach successfully generated several alternative pathways of methanol synthesis. The obtained results suggest an Eley-Rideal mechanism for both reduction steps, thus involving near-surface molecules from the gas phase, to give methanol preferentially over a strongly reduced catalyst surface, while important side reactions are of Langmuir-Hinshelwood type. Catalyst re-reduction by H{sub 2} stemming from the gas phase is a crucial process after each reduction step in order to maintain the catalyst's activity toward methanol formation and to close the catalytic cycle in some reaction channels. Furthermore, the role of oxygen vacancies, side reactions, and spectator species is investigated and mechanistic details are discussed based on

  14. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W.; Karnesky, Richard A.; Leggett, Robert D.; Baker, Ronald B.

    1989-10-03

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  15. Fuel pin

    DOE Patents [OSTI]

    Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

    1987-11-24

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  16. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Karnesky, Richard A. (Richland, WA); Leggett, Robert D. (Richland, WA); Baker, Ronald B. (Richland, WA)

    1989-01-01

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  17. Integrated low emissions cleanup system for direct coal fueled turbines (Moving bed, fluid bed contactor/ceramic filter). Seventeenth quarterly status report, October--December 1991

    SciTech Connect (OSTI)

    Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.

    1992-01-20

    The United States Department of Energy, Morgantown Energy Research Center (DOE/METC), is sponsoring the development of direct coal-fired turbine power plants as part of their Heat Engines program. A major technical challenge remaining for the development of the direct coal-fired turbine is high-temperature combustion gas cleaning to meet environmental standards for sulfur oxides and particulate emissions, as well as to provide acceptable turbine life. The Westinghouse Electric Corporation, Science & Technology Center, is evaluating two Integrated Low Emissions Cleanup (ILEC) concepts that have been configured to meet this technical challenge: a baseline ceramic barrier filter ILEC concept, and a fluidized bed ILEC concept. These ILEC concepts simultaneously control sulfur, particulate, and alkali contaminants in the high-pressure combustion gases at turbine inlet temperatures up to 2300{degrees}F. This document reports the status of a program in the seventeenth quarter to develop this ILEC technology for direct coal-fired turbine power plants.

  18. Commercial-scale demonstration of the liquid phase methanol (LPMEOH{trademark}) process. Technical progress report No. 3, October 1, 1994--March 31, 1995

    SciTech Connect (OSTI)

    1995-12-31

    The Liquid Phase Methanol (LPMEOH{trademark}) demonstration project at Kingsport, Tennessee is a $213.7 million cooperative agreement between the US Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). A facility producing 260 TPD of methanol will be designed and constructed at a site located at the Eastman Chemical complex in Kingsport, Tennessee. The Partnership will own and operate the facility for the four-year demonstration facility operational period. This project is sponsored under the DOE`s Clean Coal Technology Program, and its primary objective is to ``demonstrate the production of methanol using the LPMEOH{trademark} process in conjunction with an integrated coal gasification facility.`` The project will also demonstrate the suitability of the methanol produced for use as a chemical feedstock or as a low sulfur dioxide, low nitrogen oxides alternative fuel in stationary and transportation applications. The project may also demonstrate the production of dimethyl ether (DME) as a mixed coproduct with methanol, if laboratory- and pilot-scale research shows promising results. If implemented, the DME would be produced during the last six months of the operations phase. During the period 1 October 1994 to 31 March 1995, the project team completed essentially all the activities necessary to start detailed design. Major accomplishments in these activities are discussed.

  19. Alternative Fuels Data Center: Fuel Prices

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicles Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Prices to someone by E-mail Share Alternative Fuels Data Center: Fuel Prices on Facebook Tweet about Alternative Fuels Data Center: Fuel Prices on Twitter Bookmark Alternative Fuels Data Center: Fuel Prices on Google Bookmark Alternative Fuels Data Center: Fuel Prices on Delicious Rank Alternative Fuels Data Center: Fuel Prices on Digg Find More places to share Alternative Fuels Data Center: Fuel

  20. Study Reveals Fuel Injection Timing Impact on Particle Number...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Start of injection can improve environmental performance of fuel-efficient gasoline direct injection engines. In an ongoing quest to meet ever-more-rigorous fuel economy and ...

  1. Requirements for status for volume fuel cell manufacturing |...

    Broader source: Energy.gov (indexed) [DOE]

    Backup Power Applications Direct Hydrogen PEMFC Manufacturing Cost Estimation for Automotive Applications: Fuel Cell Tech Team Review Fuel Cell Manufacturing: American Energy and ...

  2. Hydrogen and Fuel Cell Activities: 5th International Conference...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Cell Activities: Progress and Future Directions: Total Energy USA 2012 DOE Hydrogen and Fuel Cell Overview: January 2011 National Petroleum Council ...

  3. Identification and Characterization of Near-Term Direct Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets ... More Documents & Publications Full Fuel-Cycle Comparison of Forklift Propulsion Systems ...

  4. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    1996-12-31

    The Liquid Phase Methanol (LPMEOH(TM)) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The LPMEOIWM Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. During this quarter, the Cooperative Agreement was modified (Mod AO11) on 8 October 1996, authorizing the transition born Budget Period No. 2 (Design and Construction) to the . final Budget Period (Commissioning, Start-up, and Operation), A draft Topical Report on Process Economics Studies concludes that methanol coproduction with integrated gasification combined cycle (IGCC) electric power utilizing the LPMEOW process technology, will be competitive in serving local market needs. Planning for a proof-of- concept test run of the liquid phase dimethyl ether (DME) process at the LaPorte Alternative Fuels Development Unit (AFDU) was recommended; and a deeision to proceed is pending. Construction (Task 2.2) is 97'Mo complete, asof31 December 1996. Completion of pipe pressure testing has taken longer than expected. This will delay completion of construction by about three weeks. Commissioning activities (Task 2.3) commenced in mid-October of 1996, and the demonstration unit is scheduled to be mechanically complete on 24 January 1997.

  5. Structural and thermodynamic properties of the CmIII ion solvated by water and methanol

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelley, Morgan P.; Yang, Ping; Clark, Sue B.; Clark, Aurora E.

    2016-04-27

    The geometric and electronic structures of the 9-coordinate Cm3+ ion solvated with both water and methanol are systematically investigated in the gas phase at each possible solvent-shell composition and configuration using density functional theory and second-order Møller–Plesset perturbation theory. Ab initio molecular dynamics simulations are employed to assess the effects of second and third solvent shells on the gas-phase structure. The ion–solvent dissociation energy for methanol is greater than that of water, potentially because of increased charge donation to the ion made possible by the electron-rich methyl group. Further, the ion–solvent dissociation energy and the ion–solvent distance are shown tomore » be dependent on the solvent-shell composition. Furthermore, this has implications for solvent exchange, which is generally the rate-limiting step in complexation reactions utilized in the separation of curium from complex metal mixtures that derive from the advanced nuclear fuel cycle.« less

  6. HIGH ENERGY LIQUID FUELS FROM PLANTS

    SciTech Connect (OSTI)

    Nemethy, E. K.; Otvos, J. W.; Calvin, M.

    1980-10-01

    The heptane extract of Euphorbia lathyris has a low oxygen content and a heat valve of 42 MJ/kg which is comparable to that of crude oil (44 MJ/kg). These qualities indicate a potential for use as fuel or chemical feedstock material. Therefore we have investigated the chemical composition of this fraction in some detail. Since the amoun of the methanol fraction is quite substantial we have also identified the major components of this fraction.

  7. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Syngas Upgrading to Hydrocarbon Fuels Technology Pathway Syngas Upgrading to Hydrocarbon Fuels Technology Pathway This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates

  8. Alternative Fuels Data Center: Emerging Fuels

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Emerging Fuels to someone by E-mail Share Alternative Fuels Data Center: Emerging Fuels on Facebook Tweet about Alternative Fuels Data Center: Emerging Fuels on Twitter Bookmark Alternative Fuels Data Center: Emerging Fuels on Google Bookmark Alternative Fuels Data Center: Emerging Fuels on Delicious Rank Alternative Fuels Data Center: Emerging Fuels on Digg Find More places to share Alternative

  9. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in

  10. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on

  11. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  12. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  13. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations

  14. Alternative Fuels Data Center: Propane Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Google Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Delicious Rank Alternative Fuels Data Center: Propane Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Propane Fueling Stations on

  15. Direct conversion of algal biomass to biofuel

    DOE Patents [OSTI]

    Deng, Shuguang; Patil, Prafulla D; Gude, Veera Gnaneswar

    2014-10-14

    A method and system for providing direct conversion of algal biomass. Optionally, the method and system can be used to directly convert dry algal biomass to biodiesels under microwave irradiation by combining the reaction and combining steps. Alternatively, wet algae can be directly processed and converted to fatty acid methyl esters, which have the major components of biodiesels, by reacting with methanol at predetermined pressure and temperature ranges.

  16. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  17. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Reformer Development Putting the 'Fuel' in Fuel Cells Subir Roychoudhury Precision Combustion, Inc. (PCI), North Haven, CT Shipboard Fuel Cell Workshop March 29, 2011 ...

  18. Update to Assessment of Direct Disposal in Unsaturated Tuff of Spent Nuclear Fuel and High-Level Waste Owned by U.S. Department of Energy

    SciTech Connect (OSTI)

    P. D. Wheatley; R. P. Rechard

    1998-09-01

    The overall purpose of this study is to provide information and guidance to the Office of Environmental Management of the U.S. Department of Energy (DOE) about the level of characterization necessary to dispose of DOE-owned spent nuclear fuel (SNF). The disposal option modeled was codisposal of DOE SNF with defense high-level waste (DHLW). A specific goal was to demonstrate the influence of DOE SNF, expected to be minor, in a predominately commercial repository using modeling conditions similar to those currently assumed by the Yucca Mountain Project (YMP). A performance assessment (PA) was chosen as the method of analysis. The performance metric for this analysis (referred to as the 1997 PA) was dose to an individual; the time period of interest was 100,000 yr. Results indicated that cumulative releases of 99Tc and 237Np (primary contributors to human dose) from commercial SNF exceed those of DOE SNF both on a per MTHM and per package basis. Thus, if commercial SNF can meet regulatory performance criteria for dose to an individual, then the DOE SNF can also meet the criteria. This result is due in large part to lower burnup of the DOE SNF (less time for irradiation) and to the DOE SNF's small percentage of the total activity (1.5%) and mass (3.8%) of waste in the potential repository. Consistent with the analyses performed for the YMP, the 1997 PA assumed all cladding as failed, which also contributed to the relatively poor performance of commercial SNF compared to DOE SNF.

  19. Transportation Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels DOE would invest $52 million to fund a major fleet transformation at Idaho National Laboratory, along with the installation of nine fuel management systems, purchase of additional flex fuel cars and one E85 ethanol fueling station. Transportation projects, such as the acquisition of highly efficient and alternative-fuel vehicles, are not authorized by ESPC legislation. DOE has twice proportion of medium vehicles and three times as many heavy vehicles as compared to the Federal agency

  20. Biomass fuel use in agriculture under alternative fuel prices

    SciTech Connect (OSTI)

    Bjornstad, D.J.; Hillsman, E.L.; Tepel, R.C.

    1984-11-01

    A linear programming model is used to analyze cost-competitiveness of biomass fuels in agricultural applications for the projected year 1990. With all else held constant, the prices of conventional fuels are increased and analytically compared to prices for biomass fuel products across a variety of end uses. Potential penetration of biomass fuels is measured as the share of each conventional fuel for which cost savings could be realized by substituting biomass fuels. This study examines the cost competitiveness of biomass fuels produced on farms, relative to conventional fuels (diesel, gasoline, natural gas, LPG, fuel oil, and electricity), as the prices of conventional fuels change. The study is targeted at the year 1990 and considers only fuel use in the agricultural sector. The method of analysis is to project fuel demands for ten farm operations in the year 1990 and to match these with biomass fuel substitutes from ten feedstock and nine process alternatives. In all, 61 feedstock/process combinations are possible. The matching of fuel demands and biomass fuels occurs in a linear programming model that seeks to meet fuel demands at minimum cost. Two types of biomass fuel facilities are considered, assuming a decentralized fuel distribution system. The first includes on-farm production units such as oil presses, low-Btu gasifiers, biogas digestors and direct combustion units. The second type of facility would be run by a farm co-operative. The primary data describing the biomass technologies are cost per unit output, where costs are calculated as first-year capital charges, plus al l allocable operating expenses, less any by-products of value. All costs assume commercial purchase of equipment. Homemade or makeshift installations are not considered. 1 reference.

  1. The origin of organic pollutants from the combustion of alternative fuels: Phase 5/6 report

    SciTech Connect (OSTI)

    Sidhu, S.; Graham, J.; Taylor, P.; Dellinger, B.

    1998-05-01

    As part of the US Department of Energy National Renewable Energy Laboratory program on alternative automotive fuels, the subcontractor has been conducting studies on the origin and fate of organic pollutants from the combustion of alternative fuels. Laboratory experiments were conducted simulating cold start of four alterative fuels (compressed natural gas, liquefied petroleum gas, methanol-gasoline mix, and ethanol-gasoline mix) using a commercial three-way catalyst under fuel-lean conditions. This report summarizes the results of these experiments. It appears that temperature of the catalyst is a more important parameter for fuel conversion and pollutant formation than oxygen concentration or fuel composition.

  2. Direct Conversion of Syngas-to-Hydrocarbons over Higher Alcohols Synthesis Catalysts Mixed with HZSM-5

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Dagle, Robert A.; Li, Jinjing; Deshmane, Chinmay A.; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-09-10

    The synthesis of hydrocarbon fuels directly from synthesis gas (i.e. one step process) was investigated with a catalytic system comprised of HZSM-5 physically mixed with either a methanol synthesis catalyst or a higher alcohols synthesis (HAS) catalyst. The metal sites of the methanol or HAS synthesis catalyst enable the conversion of syngas to alcohols, whereas HZSM-5 provides acid sites required for methanol dehydration, and dimethyl ether-to-hydrocarbons reactions. Catalytic performance for HZSM-5 when mixed with either a 5 wt.% Pd/ZnO/Al2O3 methanol synthesis catalyst or a HAS catalyst was evaluated at 300C, 70 bars, GHSV=700 h-1 and H2/CO=1 using a HZSM-5: alcohols synthesis catalyst weight ratio of 3:1. The major difference observed between the methanol synthesis and HAS catalyst mixtures was found in the production of durene which is an undesirable byproduct. While durene formation is negligible with any of the HAS catalysts mixed with the HZSM-5 evaluated in this study, it represents almost 50% of the C5+ fraction for the methanol synthesis catalyst (5 wt.% Pd/ZnO/Al2O3 ) mixed with HZSM-5. This presents an advantage for using HAS catalysts over the methanol synthesis catalyst to minimize the durene by-product. The yield toward the desired C5+ hydrocarbons is thus twice higher with selected HAS catalysts as compared to when HZSM-5 is mixed with 5 wt.% Pd/ZnO/Al2O3. Among all the HAS catalysts evaluated in this study, a catalyst with 0.5 wt.% Pd/FeCoCu catalyst was found the most promising due to higher production of C5+ hydrocarbons and low durene formation. The efficiency of the one-step process was thus further evaluated using the HZSM-5: 0.5 wt.% Pd/FeCoCu catalyst mixture under a number of process conditions to maximize liquid hydrocarbons product yield. At 300oC, 70 bars, GHSV = 700 h-1 and HZSM-5: 0.5 wt.% Pd/FeCoCu = 3:1 (wt.), the C5+ fraction represents 48.5% of the hydrocarbons. Unfortunately, it is more difficult to achieve higher selectivity to

  3. PEM fuel cell stack performance using dilute hydrogen mixture. Implications on electrochemical engine system performance and design

    SciTech Connect (OSTI)

    Inbody, M.A.; Vanderborgh, N.E.; Hedstrom, J.C.; Tafoya, J.I.

    1996-12-31

    Onboard fuel processing to generate a hydrogen-rich fuel for PEM fuel cells is being considered as an alternative to stored hydrogen fuel for transportation applications. If successful, this approach, contrasted to operating with onboard hydrogen, utilizes the existing fuels infrastructure and provides required vehicle range. One attractive, commercial liquid fuels option is steam reforming of methanol. However, expanding the liquid methanol infrastructure will take both time and capital. Consequently technology is also being developed to utilize existing transportation fuels, such as gasoline or diesel, to power PEM fuel cell systems. Steam reforming of methanol generates a mixture with a dry gas composition of 75% hydrogen and 25% carbon dioxide. Steam reforming, autothermal reforming, and partial oxidation reforming of C{sub 2} and larger hydrocarbons produces a mixture with a more dilute hydrogen concentration (65%-40%) along with carbon dioxide ({approx}20%) and nitrogen ({approx}10%-40%). Performance of PEM fuel cell stacks on these dilute hydrogen mixtures will affect the overall electrochemical engine system design as well as the overall efficiency. The Los Alamos Fuel Cell Stack Test facility was used to access the performance of a PEM Fuel cell stack over the range of gas compositions chosen to replicate anode feeds from various fuel processing options for hydrocarbon and alcohol fuels. The focus of the experiments was on the anode performance with dilute hydrogen mixtures with carbon dioxide and nitrogen diluents. Performance with other anode feed contaminants, such as carbon monoxide, are not reported here.

  4. Emission control cost-effectiveness of alternative-fuel vehicles

    SciTech Connect (OSTI)

    Wang, Q.; Sperling, D.; Olmstead, J.

    1993-06-14

    Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. Emission control cost-effectiveness presented in dollars per ton of emission reduction was calculated for each alternative-fuel vehicle types from the estimated vehicle life-cycle emission reductions and costs. Among various alternative-fuel vehicle types, compressed natural gas vehicles are the most cost-effective vehicle type in controlling vehicle emissions. Dedicated methanol vehicles are the next most cost-effective vehicle type. The cost-effectiveness of electric vehicles depends on improvements in electric vehicle battery technology. With low-cost, high-performance batteries, electric vehicles are more cost-effective than methanol, ethanol, and liquified petroleum gas vehicles.

  5. Density Functional Studies of Methanol Decomposition on Subnanometer Pd Clusters

    SciTech Connect (OSTI)

    Mehmood, Faisal; Greeley, Jeffrey P.; Curtiss, Larry A.

    2009-12-31

    A density functional theory study of the decomposition of methanol on subnanometer palladium clusters (primarily Pd4) is presented. Methanol dehydrogenation through C-H bond breaking to form hydroxymethyl (CH2OH) as the initial step, followed by steps involving formation of hydroxymethylene (CHOH), formyl (CHO), and carbon monoxide (CO), is found to be the most favorable reaction pathway. A competing dehydrogenation pathway with O-H bond breaking as the first step, followed by formation of methoxy (CH3O) and formaldehyde (CH2O), is slightly less favorable. In contrast, pathways involving C-O bond cleavage are much less energetically favorable, and no feasible pathways involving C-O bond formation to yield dimethyl ether (CH3OCH3) are found. Comparisons of the results are made with methanol decomposition products adsorbed on more extended Pd surfaces; all reaction intermediates are found to bind slightly more strongly to the clusters than to the surfaces.

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive WEX fleet card. The program offers a rebate of $0.05 per gallon for purchases of more than 500 gallons of biofuel per month. The rebate is applied at the end of each monthly billing cycle. For more

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive Fleet Card. The program offers a rebate of $0.03 per gallon for purchases of less than 1,000 gallons of biofuel per month, and $0.05 per gallon for purchases of 1,000 gallons or more per month. The rebate is

  8. Automated fuel pin loading system

    DOE Patents [OSTI]

    Christiansen, D.W.; Brown, W.F.; Steffen, J.M.

    An automated loading system for nuclear reactor fuel elements utilizes a gravity feed conveyor which permits individual fuel pins to roll along a constrained path perpendicular to their respective lengths. The individual lengths of fuel cladding are directed onto movable transports, where they are aligned coaxially with the axes of associated handling equipment at appropriate production stations. Each fuel pin can be be reciprocated axially and/or rotated about its axis as required during handling steps. The fuel pins are inerted as a batch prior to welding of end caps by one of two disclosed welding systems.

  9. Automated fuel pin loading system

    DOE Patents [OSTI]

    Christiansen, David W.; Brown, William F.; Steffen, Jim M.

    1985-01-01

    An automated loading system for nuclear reactor fuel elements utilizes a gravity feed conveyor which permits individual fuel pins to roll along a constrained path perpendicular to their respective lengths. The individual lengths of fuel cladding are directed onto movable transports, where they are aligned coaxially with the axes of associated handling equipment at appropriate production stations. Each fuel pin can be reciprocated axially and/or rotated about its axis as required during handling steps. The fuel pins are inserted as a batch prior to welding of end caps by one of two disclosed welding systems.

  10. Developing Low-Cost, Highly Efficient Heat Recovery for Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Illustration courtesy of FuelCell Energy, Inc. Project Description The goal of this ... It is now be- ing incorporated into FuelCell Energy's commercial Direct FuelCell ...

  11. Emissions of greenhouse gases from the use of transportation fuels and electricity

    SciTech Connect (OSTI)

    DeLuchi, M.A. )

    1991-11-01

    This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

  12. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 1, Main text

    SciTech Connect (OSTI)

    DeLuchi, M.A.

    1991-11-01

    This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

  13. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator

  14. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert C. Tsang

    2004-03-26

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy in July 2003. The project has completed Phase I, and is currently in Phase II of development. The two project phases include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations; and (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The Phase I of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase II is supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The WREL integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the

  15. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Thomas Lynch

    2004-01-07

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and

  16. Alternative Fuels Data Center: Flexible Fuel Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Flexible Fuel Vehicles to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicles on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicles on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicles on Digg

  17. Performance and emissions characteristics of alternative fuels in spark ignition engines

    SciTech Connect (OSTI)

    Swain, M.R.; Maxwell, R.L.; Swain, M.N.; Bedsworth, K.; Adt, R.R. Jr.; Pappas, J.M.

    1984-01-01

    A formal ongoing program to characterize the performance and exhaust characteristics of automotive-type powerplants fueled by conventional and alternative fuels is reported. This report contains the information obtained during the past three years when four alternative fuels and two baseline fuels were evaluated in three engines. The four alternative fuels were a simulated gasoline made to represent coal derived gasoline, methyl aryl ethers blended at the 10% level in an unleaded gasoline, gasoline made from methanol, and a blend of Indolene plus methanol and higher alcohols. The two baseline fuels were, Indolene and Gulf unleaded regular gasoline. The engines tested were a pre-mixed carbureted SI (spark ignition) engine, a carbureted three-valve stratified-charge SI engine and a pre-mixed carbureted SI engine with a closed-loop three-way catalyst emission control system.

  18. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  19. Modeling of polymer electrolyte fuel cell systems

    SciTech Connect (OSTI)

    Kumar, R.; Ahluwalia, R.; Geyer, H.K.; Krumpelt, M.

    1993-09-01

    Propulsion systems based on the polymer electrolyte fuel cell (PEFC) are being developed. This paper reports an analysis undertaken to design improved PEFC systems. A reference system design with some variants were set up for a methanol-fueled PEFC propulsion system. Efficiency improves from 38.4 to 44.1% as cell current density goes from 0.75 to 0.45 A/cm{sup 2}, while fuel cell efficiency increases from 52.6 to 60.0%; to get a net power output of 80 kWe, the active fuel cell area must increase from 18.8 to 27.3 m{sup 2}. Three parametric studies were conducted on the off-design performance of the reference system.

  20. Commercial-Scale Demonstration of the Liquid Phase Methanol (LOMEOH(TM)) Process

    SciTech Connect (OSTI)

    1996-03-31

    started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOHTM process is ideally suited for directly processing gases produced by modern day coal gasifiers. Originally tested at a small 3,200 gallons per day, DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates.