Sample records for dioxide water vapor

  1. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    (for water: the SPC-, SPC/E-, and TIP4P-potential models; for carbon dioxide: the EPM2 potential model dioxide are calculated. For water, the SPC- and TIP4P-models give superior results for the vapor pressure when compared to the SPC/E-model. The vapor liquid equilibrium of the binary mixture carbon dioxide

  2. Tropospheric water vapor and climate sensitivity

    SciTech Connect (OSTI)

    Schneider, E.K.; Kirtman, B.P.; Lindzen, R.S. [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)] [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)

    1999-06-01T23:59:59.000Z

    Estimates are made of the effect of changes in tropospheric water vapor on the climate sensitivity to doubled carbon dioxide (CO{sub 2}) using a coarse resolution atmospheric general circulation model coupled to a slab mixed layer ocean. The sensitivity of the model to doubled CO{sub 2} is found as the difference between the equilibrium responses for control and doubled CO{sub 2} cases. Clouds are specified to isolate the water vapor feedback. Experiments in which the water vapor distribution is specified rather than internally calculated are used to find the contribution of water vapor in various layers and latitude belts to the sensitivity. The contribution of water vapor in layers of equal mass to the climate sensitivity varies by about a factor of 2 with height, with the largest contribution coming from layers between 450 and 750 mb, and the smallest from layers above 230 mb. The positive feedback on the global mean surface temperature response to doubled CO{sub 2} from water vapor above 750 mb is about 2.6 times as large as that from water vapor below 750 mb. The feedback on global mean surface temperature due to water vapor in the extratropical free troposphere is about 50% larger than the feedback due to the lower-latitude free troposphere water vapor. Several important sources of nonlinearity of the radiative heating rates were identified in the process of constructing the specified cloud and water vapor fields. These are (1) the interaction of clouds and solar radiation, which produces much more reflection of solar radiation for time mean clouds than for the instantaneous clouds; (2) the correlation of clouds and water vapor, which produces less downward longwave radiation at the ground for correlated clouds and water vapor than when these fields are independent; and (3) the interaction of water vapor with long wave radiation, which produces less downward longwave radiation at the ground of the average over instantaneous water vapor distributions than of the time mean water vapor distribution.

  3. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  4. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)Productssondeadjustsondeadjust DocumentationARM Participation in SuomiNet The ARM62ARM Water Vapor IOP

  5. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and Materials Disposition3 Water Vapor Experiment Concludes The

  6. Hydrogen Cars and Water Vapor

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have, with discernible effects on people and ecosystems. The broad environmental effects of fuel cell vehicles. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solution

  7. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cadeddu, Maria

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  8. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1998-01-01T23:59:59.000Z

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

  9. Water vapor variability in the tropics and its links to dynamics and precipitation

    E-Print Network [OSTI]

    Allan, Richard P.

    dioxide doubling [e.g., Intergovernmental Panel on Climate Change (IPCC), 2001]. This uncertainty stems P. P. Shirshov Institute of Oceanology, Russian Academy of Sciences, Moscow, Russia Richard P. Allan to understanding feedbacks and processes operating within the climate system. Column-integrated water vapor (CWV

  10. Chemical Vapor Deposition of Silicon Dioxide by Direct-Current Corona Discharges in Dry Air

    E-Print Network [OSTI]

    Chen, Junhong

    Chemical Vapor Deposition of Silicon Dioxide by Direct-Current Corona Discharges in Dry Air, Si4O4(CH3)8) widely used as additives in personal care products. In both photocopiers and air in indoor air, the gas-phase processes limit the rate of deposition. KEY WORDS: Corona plasma; corona

  11. Intensities of electronic transitions in sulfur dioxide vapor

    E-Print Network [OSTI]

    McCray, James Arthur

    1955-01-01T23:59:59.000Z

    . Relation between Oscillator Strength and Probability Coefficient of Absorption . . . . . . . . . . . . . . . . 20 V. The Ultraviolet Spectrum of Sulfur Dioxide Gas . . . . . . 22 ) VI. Experimental Procedure and Computations . . . . . . . . . 23 U A... where )(e is defined as the dielectric constant of the medium. This equation holds for radiation which has a frequency sufficiently dif- ferent from that of the resonant frequencies of'the molecules of the medium, The polarizability o( of a molecule...

  12. Breath is a mixture of nitrogen, oxygen, carbon dioxide, water

    E-Print Network [OSTI]

    12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

  13. Phase effects for electrons in liquid water and water vapor

    SciTech Connect (OSTI)

    Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

    1988-01-01T23:59:59.000Z

    The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

  14. Isotopic composition of stratospheric water vapor: Measurements and photochemistry

    E-Print Network [OSTI]

    of magnitude between the surface and the tropopause, and isotopically heavy water is pref- erentially removedIsotopic composition of stratospheric water vapor: Measurements and photochemistry David G. Johnson composition of stratospheric water vapor that result from methane oxidation and reactions with O( ¢¡ ). We

  15. Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.; Viani, Brian

    2013-01-29T23:59:59.000Z

    A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

  16. Role of oxygen vacancies in water vapor chemisorption and CO oxidation on titania

    SciTech Connect (OSTI)

    Sengupta, G.; Chatterjee, R.N.; Maity, G.C. (Project and Development India Ltd. Sindri, Dhanbad, Bihar (India)); Satyanarayna, C.V.V. (RSIC, Bombay (India). Indian Inst. of Tech. Powai)

    1995-03-01T23:59:59.000Z

    Titanium dioxide is widely used as support for various important catalysts. Although nonstoichiometric titania behaves as an n-type semiconductor, the nature of the defect sites is not yet fully understood. In the present investigation the water vapor adsorption and carbon monoxide oxidation on TiO[sub 2] is explained considering oxygen vacancies as the major defect. It is also shown that incorporation of an Al[sup 3+] ion in TiO[sub 2] reduces the concentration of oxygen ion vacancies and inhibits the transformation of anatase to rutile.

  17. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01T23:59:59.000Z

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR?¢????s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument?¢????s robustness in a real-world situation.

  18. Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from MODIS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from such as cloud mask, atmos- pheric profiles, aerosol properties, total precipitable water, and cloud properties vapor amount, aerosol particles, and the subsequently formed clouds [9]. Barnes et al. [2] provide

  19. Water and Carbon Dioxide Adsorption at Olivine Surfaces

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

    2013-11-14T23:59:59.000Z

    Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

  20. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

    1995-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  1. Experimental Study of Water Vapor Adsorption on Geothermal

    E-Print Network [OSTI]

    Stanford University

    Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of PetroleumSGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

  2. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    This dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to identify to which extent...

  3. High-resolution terahertz atmospheric water vapor continuum measurements

    E-Print Network [OSTI]

    Massachusetts at Lowell, University of

    High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

  4. Balance of atmospheric water vapor over the Gulf of Mexico

    E-Print Network [OSTI]

    Hughes, Ralph Morgan

    1967-01-01T23:59:59.000Z

    / / / / I / o. i + B CAP C BBJ V S TPA PZA EHA Fig. 5. Vertical distribution of the average water-vapor flux normal to the perimeter of the Gulf of Nexico during Oct-Kov-Dec 1959. Plus values are inflow in kgm/sec-mb-. m. -o-I Pi C4 I / ~-o, i...BALANCE OF ATMOSPHERIC HATER VAPOR OVER THE GULF OF MEXICO A Thesis By RALPH MORGAN HUGHES Captain, USAF Submitted to the Graduate College of the Texas A&M University in partial fulf-'llment of the rec;uirements for the degree of MASTER...

  5. E-Print Network 3.0 - airs water vapor Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    water vapor Search Powered by Explorit Topic List Advanced Search Sample search results for: airs water vapor Page: << < 1 2 3 4 5 > >> 1 A laboratory experiment from the Little...

  6. Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point

    E-Print Network [OSTI]

    Magee, Joseph W.

    Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point Allan the vapor pressure of heavy water (D2O) from its triple point to its critical point. This work takes Institute of Physics. Key words: D2O; heavy water; ITS-90; vapor pressure. Contents 1. Introduction

  7. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD) by Microtops Atmospheric OpticalExperiment (VORTEX) govCampaignsVerification ofgovCampaignsWater

  8. ESA DUE GlobVapour water vapor products: Validation

    SciTech Connect (OSTI)

    Schneider, Nadine; Schroeder, Marc; Stengel, Martin [Deutscher Wetterdienst (DWD), KU22, Frankfurter Str. 135, 63067 Offenbach a. M (Germany); Lindstrot, Ramus; Preusker, Rene [Freie Universitaet Berlin (FUB), Carl-Heinrich-Becker-Weg 6-10, 12165 Berlin (Germany); Collaboration: ESA DUE GlobVapour Consortium

    2013-05-10T23:59:59.000Z

    The main objective of the European Space Agency (ESA) Data User Element (DUE) GlobVapour project was the development of multi-annual global water vapor data sets. Since water vapour is a key climate variable it is important to have a good understanding of its behavior in the climate system. The ESA DUE GlobVapour project provides water vapor data, including error estimates, based on carefully calibrated and inter-calibrated satellite radiances in response to user requirements for long time series satellite observations. ESA DUE GlobVapour total columnar water vapor (TCWV) products derived from GOME/SCIA/GOME-2 (1996-2008) and SSM/I+MERIS (2003-2008) have been validated for the mentioned period, using satellite-based (AIRS, ATOVS) and ground-based measurements (radiosondes and microwave radiometer). The validation results are discussed in the following. The technical specifications on bias (1 kg/m{sup 2} for SSMI+MERIS and 2 kg/m{sup 2} for GOME/SCIA/GOME-2) are generally met. For more information, documents and data download follow the link: www.globvapour.info.

  9. Water vapor and the dynamics of climate changes

    E-Print Network [OSTI]

    Schneider, Tapio; Levine, Xavier

    2009-01-01T23:59:59.000Z

    Water vapor is not only Earth's dominant greenhouse gas. Through the release of latent heat when it condenses, it also plays an active role in dynamic processes that shape the global circulation of the atmosphere and thus climate. Here we present an overview of how latent heat release affects atmosphere dynamics in a broad range of climates, ranging from extremely cold to extremely warm. Contrary to widely held beliefs, atmospheric circulation statistics can change non-monotonically with global-mean surface temperature, in part because of dynamic effects of water vapor. For example, the strengths of the tropical Hadley circulation and of zonally asymmetric tropical circulations, as well as the kinetic energy of extratropical baroclinic eddies, can be lower than they presently are both in much warmer climates and in much colder climates. We discuss how latent heat release is implicated in such circulation changes, particularly through its effect on the atmospheric static stability, and we illustrate the circul...

  10. Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere

    E-Print Network [OSTI]

    Olver, Peter

    dioxide Water vapor #12;Atmospheric composition (parts per million by volume) · Nitrogen (N2) 780Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere Bill Satzer 3M Company #12;Outline,840 · Oxygen (O2) 209,460 · Argon (Ar) 9340 · Carbon dioxide (CO2) 394 · Methane (CH4) 1.79 · Ozone (O3) 0

  11. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30T23:59:59.000Z

    This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

  12. Water-in-carbon dioxide emulsions: Formation and stability

    SciTech Connect (OSTI)

    Lee, C.T. Jr.; Psathas, P.A.; Johnston, K.P.; Grazia, J. de; Randolph, T.W.

    1999-09-28T23:59:59.000Z

    Stable water-in-carbon dioxide (W/C) emulsions, for either liquid or supercritical CO{sub 2} containing up to 70 vol % water, are formed with various molecular weight perfluoropolyether ammonium caroxylate surfactants. Water droplet sizes ranging from 3 to 10 {micro}m were determined by optical microscopy. From conductivity measurements, an inversion to C/W emulsions results from a decrease in CO{sub 2} density or salinity at constant pressure, a decrease in surfactant molecular weight, or an increase in temperature. Emulsions become more stable with a change in any of these formulation variables away from the balanced state, which increases interfacial tensions and interfacial tension gradient enhancing Marangoni-Gibbs stabilization. This type of stability is enhanced with an increase in the molecular weight of the surfactant tails, which increases the thickness of the stabilizing films between droplets. W/C emulsions formed with the 7,500 molecular weight surfactant were stable for several days.

  13. Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS

    SciTech Connect (OSTI)

    Braun, John

    2006-02-06T23:59:59.000Z

    Water vapor is a primary element in the Earths climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and its utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

  14. An optical water vapor sensor for unmanned aerial vehicles

    SciTech Connect (OSTI)

    Timothy A. Berkoff; Paul L. Kebabian; Robert A. McClatchy; Charles E. Kolb; Andrew Freedman

    1998-12-01T23:59:59.000Z

    The water vapor sensor developed by Aerodyne Research, based on the optical absorption of light at {approximately}935 nm, has been successfully demonstrated on board the Pacific Northwest National Laboratory's Gulfstream-1 research aircraft during the Department of Energy's ARM Intensive Operations Period in August 1998. Data taken during this field campaign show excellent agreement with a chilled mirror and Lyman-alpha hygrometers and measurements confirm the ability to measure rapid, absolute water vapor fluctuations with a high degree of instrument stability and accuracy, with a noise level as low 10 ppmv (1 Hz measurement bandwidth). The construction of this small, lightweight sensor contains several unique elements which result in several significant advantages when compared to other techniques. First, the low power consumption Argon discharge lamp provides an optical beam at a fixed wavelength without a need for temperature or precision current control. The multi-pass absorption cell developed for this instrument provides a compact, low cost method that can survive deployment in the field. Fiber-optic cables, which are used to convey to light between the absorption cell, light source, and detection modules enable remote placement of the absorption cell from the opto-electronics module. Finally, the sensor does not use any moving parts which removes a significant source of potential malfunction. The result is an instrument which maintained its calibration throughout the field measurement campaign, and was not affected by high vibration and large uncontrolled temperature excursions. We believe that the development of an accurate, fast response water vapor monitor described in this report will open up new avenues of aerial-vehicle-based atmospheric research which have been relatively unexplored due to the lack of suitable low-cost, light-weight instrumentation.

  15. Moisture burst structure in satellite water vapor imagery

    E-Print Network [OSTI]

    Ulsh, David Joel

    1988-01-01T23:59:59.000Z

    The moisture burst is a tropical synoptic-scale weather event that typically originates along the ITCZ and has been defined previously in window-channel infrared imagery. This research uses 6. 7-micrometer water vapor absorption band imagery to composite 35... moisture burst events during the North Pacific cool season of 1983-1984. Composite maps are constructed at four times, each 24 h apart, during the life cycle of the moisture burst. A comparative baseline is provided by an additional composite of 35 dates...

  16. enhanced) in water vapor. The distribution of water ice throughout the solar nebula may

    E-Print Network [OSTI]

    Utrecht, Universiteit

    enhanced) in water vapor. The distribution of water ice throughout the solar nebula may have varied Solar System (Univ. of Arizona Press, Tucson, AZ, 1988), p. 348. The time scale for settling of solids that are a few hundred times greater than that of the canonical solar nebula (14). Turbulent

  17. Water and Carbon Dioxide Adsorption at Olivine Surfaces. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and Materials Disposition3 Water Vapor Experiment Concludes

  18. The Water Vapor Abundance in Orion KL Outflows

    E-Print Network [OSTI]

    J. Cernicharo; J. R. Goicoechea; F. Daniel; M. R. Lerate; M. J. Barlow; B. M. Swinyard; E. van Dishoeck; T. L. Lim; S. Viti; J. Yates

    2006-08-16T23:59:59.000Z

    We present the detection and modeling of more than 70 far-IR pure rotational lines of water vapor, including the 18O and 17O isotopologues, towards Orion KL. Observations were performed with the Long Wavelength Spectrometer Fabry-Perot (LWS/FP; R~6800-9700) on board the Infrared Space Observatory (ISO) between ~43 and ~197 um. The water line profiles evolve from P-Cygni type profiles (even for the H2O18 lines) to pure emission at wavelengths above ~100 um. We find that most of the water emission/absorption arises from an extended flow of gas expanding at 25+-5 kms^-1. Non-local radiative transfer models show that much of the water excitation and line profile formation is driven by the dust continuum emission. The derived beam averaged water abundance is 2-3x10^-5. The inferred gas temperature Tk=80-100 K suggests that: (i) water could have been formed in the "plateau" by gas phase neutral-neutral reactions with activation barriers if the gas was previously heated (e.g. by shocks) to >500 K and/or (ii) H2O formation in the outflow is dominated by in-situ evaporation of grain water-ice mantles and/or (iii) H2O was formed in the innermost and warmer regions (e.g. the hot core) and was swept up in ~1000 yr, the dynamical timescale of the outflow.

  19. Cold Water Vapor in the Barnard 5 Molecular Cloud

    E-Print Network [OSTI]

    Wirstrm, E S; Persson, C M; Buckle, J V; Cordiner, M A; Takakuwa, S

    2014-01-01T23:59:59.000Z

    After more than 30 years of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds, however, there is only one region where cold (~10 K) water vapor has been detected - L1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at work -- likely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H2O (J = 1_10 - 1_01) at 556.9360 GHz toward two positions in the cold molecular cloud Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  20. Water Use Efficiency in Plant Growth and Ambient Carbon Dioxide Level

    E-Print Network [OSTI]

    van Bavel, C. H. M.

    TR-42 1972 Water Use Efficiency in Plant Growth and Ambient Carbon Dioxide Level C.H. M. van Bavel Texas Water Resources Institute Texas A&M University ...

  1. Water, Vapor, and Salt Dynamics in a Hot Repository

    SciTech Connect (OSTI)

    Bahrami, Davood; Danko, George [Department of Mining Engineering, University of Nevada, Reno, 1664 N. Virginia St., Reno, NV, 89557 (United States); Walton, John [Department of Civil Engineering, University of Texas at El Paso, 500 W. University, El Paso, TX, 79968 (United States)

    2007-07-01T23:59:59.000Z

    The purpose of this paper is to report the results of a new model study examining the high temperature nuclear waste disposal concept at Yucca Mountain using MULTIFLUX, an integrated in-drift- and mountain-scale thermal-hydrologic model. The results show that a large amount of vapor flow into the drift is expected during the period of above-boiling temperatures. This phenomenon makes the emplacement drift a water/moisture attractor during the above-boiling temperature operation. The evaporation of the percolation water into the drift gives rise to salt accumulation in the rock wall, especially in the crown of the drift for about 1500 years in the example. The deposited salts over the drift footprint, almost entirely present in the fractures, may enter the drift either by rock fall or by water drippage. During the high temperature operation mode, the barometric pressure variation creates fluctuating relative humidity in the emplacement drift with a time period of approximately 10 days. Potentially wet and dry conditions and condensation on salt-laden drift wall sections may adversely affect the storage environment. Salt accumulations during the above-boiling temperature operation must be sufficiently addressed to fully understand the waste package environment during the thermal period. Until the questions are resolved, a below-boiling repository design is favored where the Alloy-22 will be less susceptible to localized corrosion. (authors)

  2. Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated

    E-Print Network [OSTI]

    Cal, Mark P.

    Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated Activated Carbon August 25, 1995@ Water vapor adsorption on activated carbon cloth (ACCBO)which has been oxidized% Cl), and ACCBO (4% N), exhibits sigmoidal isotherms with hysteresis loops of varying magnitudes

  3. Vapor-liquid equilibria of sulfur dioxide in polar organic solvents

    SciTech Connect (OSTI)

    Demyanovich, R.J.; Lynn, S.

    1987-03-01T23:59:59.000Z

    Vapor-liquid equilibrium data for SO/sub 2/ in eight polar organic solvents and three mixtures of organic solvents were investigated over the temperature range 30-95/sup 0/C and over a concentration range of 0.02-0.16 weight fraction of SO/sub 2/. The solvents investigated were N, N-dimethylaniline (DMA); quinoline; the dimethyl ethers of diethylene glycol, triethylene glycol, and tetraethylene glycol; the monomethyl ether of diethylene glycol (DGM); tetramethylene sulfone; and tributyl phosphate. The mixed solvents investigated were various mixtures of DMA and DGM. The data were correlated by using the UNIQUAC, NRTL, Wilson, and Henry's law phase-equilibrium models.

  4. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  5. Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions

    SciTech Connect (OSTI)

    Pazmany, Andrew

    2006-11-09T23:59:59.000Z

    Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

  6. Measurements of water vapor adsorption on the Geysers rocks

    SciTech Connect (OSTI)

    Gruszkiewicz, Miroslaw S.; Horita, Juske; Simonson, John M.; Mesmer, Robert E.

    1996-01-24T23:59:59.000Z

    The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 C and at 200 C as a function of pressure in the range 0.00 ? p/p0 ? 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in estimating water retention capability of a porous material. The same laboratory also determined the densities of the samples by helium pycnometry. Their results were then compared with our own density values obtained by measuring the effect of buoyancy in compressed argon. One of the goals of this project is to determine the dependence of the water retention capacity of the rocks as a function of temperature. The results show a significant dependence of the adsorption and desorption isotherms on the grain size of the sample. The increase in the amount of water retained with temperature observed previously (Shang et al., 1994a, 1994b, 1995) between 90 and 130C for various reservoir rocks from The Geysers may be due to the contribution of slow chemical adsorption and may be dependent on the time allowed for equilibration. In contrast with the results of Shang et al. (1994a, 1994b, 1995), some closed and nearly closed hysteresis loops on the water adsorption/desorption isotherms (with closing points at p/p0 ? 0.6) were obtained in this study. In these cases the effects of activated processes were not present, and no increase in water adsorption with temperature was observed

  7. ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 24, NO. 3, 2007, 509526 Variational Assimilation of GPS Precipitable Water Vapor and

    E-Print Network [OSTI]

    Precipitable Water Vapor and Hourly Rainfall Observations for a Meso- Scale Heavy Precipitation Event During Atmospheric water vapor plays a significant role in numerical weather predictions (NWP) of heavy rain- fall of the precipitable water vapor (PWV) from delayed signals transmitted by GPS satellites, which can be assimilated

  8. Mass densification and defect restoration in chemical vapor deposition silicon dioxide film using Ar plasma excited by microwave

    SciTech Connect (OSTI)

    Kawase, Kazumasa, E-mail: Kawase.Kazumasa@ak.MitsubishiElectric.co.jp; Motoya, Tsukasa; Uehara, Yasushi [Advanced Technology R and D Center, Mitsubishi Electric Corporation, 8-1-1 Tsukaguchi-honmachi, Amagasaki, Hyogo 661-8661 (Japan); Teramoto, Akinobu; Suwa, Tomoyuki; Ohmi, Tadahiro [New Industry Creation Hatchery Center, Tohoku University, 6-6-10 Aoba Aramaki, Aoba-ku, Sendai, Miyagi 980-8579 (Japan)

    2014-09-01T23:59:59.000Z

    Silicon dioxide (SiO{sub 2}) films formed by chemical vapor deposition (CVD) have been treated with Ar plasma excited by microwave. The changes of the mass densities, carrier trap densities, and thicknesses of the CVD-SiO{sub 2} films with the Ar plasma treatments were investigated. The mass density depth profiles were estimated with X-Ray Reflectivity (XRR) analysis using synchrotron radiation. The densities of carrier trap centers due to defects of Si-O bond network were estimated with X-ray Photoelectron Spectroscopy (XPS) time-dependent measurement. The changes of the thicknesses due to the oxidation of Si substrates were estimated with the XRR and XPS. The mass densities of the CVD-SiO{sub 2} films are increased by the Ar plasma treatments. The carrier trap densities of the films are decreased by the treatments. The thicknesses of the films are not changed by the treatments. It has been clarified that the mass densification and defect restoration in the CVD-SiO{sub 2} films are caused by the Ar plasma treatments without the oxidation of the Si substrates.

  9. Thermodynamic Models for Vapor-Liquid Equilibria of Nitrogen+Oxygen+Carbon Dioxide at Low Temperatures

    E-Print Network [OSTI]

    Vrabec, J; Buchhauser, U; Meyer-Pittroff, R; Hasse, H

    2009-01-01T23:59:59.000Z

    For the design and optimization of CO2 recovery from alcoholic fermentation processes by distillation, models for vapor-liquid equilibria (VLE) are needed. Two such thermodynamic models, the Peng-Robinson equation of state (EOS) and a model based on Henry's law constants, are proposed for the ternary mixture N2+O2+CO2. Pure substance parameters of the Peng-Robinson EOS are taken from the literature, whereas the binary parameters of the Van der Waals one-fluid mixing rule are adjusted to experimental binary VLE data. The Peng-Robinson EOS describes both binary and ternary experimental data well, except at high pressures approaching the critical region. A molecular model is validated by simulation using binary and ternary experimental VLE data. On the basis of this model, the Henry's law constants of N2 and O2 in CO2 are predicted by molecular simulation. An easy-to-use thermodynamic model, based on those Henry's law constants, is developed to reliably describe the VLE in the CO2-rich region.

  10. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01T23:59:59.000Z

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  11. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

    2011-08-23T23:59:59.000Z

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  12. Temperature and water vapor pressure effects on the friction coefficient of hydrogenated diamondlike carbon films.

    SciTech Connect (OSTI)

    Dickrell, P. L.; Sawyer, W. G.; Eryilmaz, O. L.; Erdemir, A.; Energy Technology; Univ. of Florida

    2009-07-01T23:59:59.000Z

    Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H{sub 2}O and O{sub 2}. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.

  13. An Analysis of Cloud Cover and Water Vapor for the ALMA Project

    E-Print Network [OSTI]

    (Chile), Chalviri (Bolivia) and Five Sites in Argentina using Satellite Data and a Verification and water vapor at Chajnantor (Chile), Chalviri (Bolivia) and four sites in Argentina. Since time

  14. Models of the atmospheric water vapor budget for the Texas HIPLEX area: by Steven Francis Williams.

    E-Print Network [OSTI]

    Williams, Steven Francis

    1979-01-01T23:59:59.000Z

    co:erage cf. convective activ' ty, Thus, the em&unt of convection seems to be more important than the type oz pr"se. . ce of convective activi!y. An increased tran:port of water vapor near ti e surface is -hown to be an important factor... of watc-. z vapor tnrough each later, l boundary shown in Fig. 1 can be comput d by substituting Eqs. (16) ? (19), reaper tively, into Eq. (14) . Th ' net transport of water vapor 'nt the volume through la+eral oouccdaries or t?:e net horizontal tran:;port...

  15. Effect of atmospheric water vapor on modification of stable isotopes in near-surface snow on ice sheets

    E-Print Network [OSTI]

    Walden, Von P.

    temperature and the abundance of heavy isotopes of water found in water vapor and precipitation as functionsEffect of atmospheric water vapor on modification of stable isotopes in near-surface snow on ice fractionation model is developed to investigate postdepositional modification of stable isotopes of water

  16. GEOSTAR-II: A PROTOTYPE WATER VAPOR IMAGER/SOUNDER FOR THE PATH Todd Gaier1

    E-Print Network [OSTI]

    Ruf, Christopher

    GEOSTAR-II: A PROTOTYPE WATER VAPOR IMAGER/SOUNDER FOR THE PATH MISSION Todd Gaier1 , Bjorn Lambrigtsen1 , Pekka Kangaslahti1 , Boon Lim1 , Alan Tanner1 , Dennis Harding1 , Heather Owen1 , Mary Soria1 GHz water line. The preferred concept to meet this requirement is an interferometric imager

  17. Raman lidar profiling of water vapor and aerosols over the ARM SGP Site

    SciTech Connect (OSTI)

    Ferrare, R.A.

    2000-01-09T23:59:59.000Z

    The authors have developed and implemented automated algorithms to retrieve profiles of water vapor mixing ratio, aerosol backscattering, and aerosol extinction from Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) Raman Lidar data acquired during both daytime and nighttime operations. The Raman lidar sytem is unique in that it is turnkey, automated system designed for unattended, around-the-clock profiling of water vapor and aerosols. These Raman lidar profiles are important for determining the clear-sky radiative flux, as well as for validating the retrieval algorithms associated with satellite sensors. Accurate, high spatial and temporal resolution profiles of water vapor are also required for assimilation into mesoscale models to improve weather forecasts. The authors have also developed and implemented routines to simultaneously retrieve profiles of relative humidity. These routines utilize the water vapor mixing ratio profiles derived from the Raman lidar measurements together with temperature profiles derived from a physical retrieval algorithm that uses data from a collocated Atmospheric Emitted Radiance Interferometer (AERI) and the Geostationary Operational Environmental Satellite (GOES). These aerosol and water vapor profiles (Raman lidar) and temperature profiles (AERI+GOES) have been combined into a single product that takes advantage of both active and passive remote sensors to characterize the clear sky atmospheric state above the CART site.

  18. RAMAN LIDAR PROFILING OF WATER VAPOR AND AEROSOLS OVER THE ARM SGP SITE.

    SciTech Connect (OSTI)

    FERRARE,R.A.

    2000-01-09T23:59:59.000Z

    We have developed and implemented automated algorithms to retrieve profiles of water vapor mixing ratio, aerosol backscattering, and aerosol extinction from Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) Raman Lidar data acquired during both daytime and nighttime operations. This Raman lidar system is unique in that it is turnkey, automated system designed for unattended, around-the-clock profiling of water vapor and aerosols (Goldsmith et al., 1998). These Raman lidar profiles are important for determining the clear-sky radiative flux, as well as for validating the retrieval algorithms associated with satellite sensors. Accurate, high spatial and temporal resolution profiles of water vapor are also required for assimilation into mesoscale models to improve weather forecasts. We have also developed and implemented routines to simultaneously retrieve profiles of relative humidity. These routines utilize the water vapor mixing ratio profiles derived from the Raman lidar measurements together with temperature profiles derived from a physical retrieval algorithm that uses data from a collocated Atmospheric Emitted Radiance Interferometer (AERI) and the Geostationary Operational Environmental Satellite (GOES) (Feltz et al., 1998; Turner et al., 1999). These aerosol and water vapor profiles (Raman lidar) and temperature profiles (AERI+GOES) have been combined into a single product that takes advantage of both active and passive remote sensors to characterize the clear sky atmospheric state above the CART site.

  19. The Impact of Thermal Conductivity and Diffusion Rates on Water Vapor Transport through Gas Diffusion Layers

    E-Print Network [OSTI]

    Burlatsky, S F; Gummallaa, M; Condita, D; Liua, F

    2013-01-01T23:59:59.000Z

    Water management in a hydrogen polymer electrolyte membrane (PEM) fuel cell is critical for performance. The impact of thermal conductivity and water vapor diffusion coefficients in a gas diffusion layer (GDL) has been studied by a mathematical model. The fraction of product water that is removed in the vapour phase through the GDL as a function of GDL properties and operating conditions has been calculated and discussed. Furthermore, the current model enables identification of conditions when condensation occurs in each GDL component and calculation of temperature gradient across the interface between different layers, providing insight into the overall mechanism of water transport in a given cell design. Water transport mode and condensation conditions in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDL and water removal scenarios have been identified and related to experimentally-determined GDL proper...

  20. Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere

    DOE Patents [OSTI]

    Allendorf, Mark D; Robinson, Alex L

    2014-12-09T23:59:59.000Z

    We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

  1. A NORMETEX MODEL 15 M3/HR WATER VAPOR PUMPING TEST

    SciTech Connect (OSTI)

    Klein, J.; Fowley, M.; Steeper, T.

    2010-12-20T23:59:59.000Z

    Tests were performed using a Model 15 m{sup 3}/hr Normetex vacuum pump to determine if pump performance degraded after pumping a humid gas stream. An air feed stream containing 30% water vapor was introduced into the pump for 365 hours with the outlet pressure of the pump near the condensation conditions of the water. Performance of the pump was tested before and after the water vapor pumping test and indicated no loss in performance of the pump. The pump also appeared to tolerate small amounts of condensed water of short duration without increased noise, vibration, or other adverse indications. The Normetex pump was backed by a dual-head diaphragm pump which was affected by the condensation of water and produced some drift in operating conditions during the test.

  2. FIRST DETECTION OF WATER VAPOR IN A PRE-STELLAR CORE

    SciTech Connect (OSTI)

    Caselli, Paola; Douglas, Thomas [School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom); Keto, Eric [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Bergin, Edwin A. [Department of Astronomy, The University of Michigan, 500 Church Street, Ann Arbor, MI 48109-1042 (United States); Tafalla, Mario [Observatorio Astronomico Nacional (IGN), Calle Alfonso XII, 3, E-28014 Madrid (Spain); Aikawa, Yuri [Department of Earth and Planetary Sciences, Kobe University, Nada, 657-8501 Kobe (Japan); Pagani, Laurent [LERMA and UMR 8112 du CNRS, Observatoire de Paris, 61 Av. de l'Observatoire, F-75014 Paris (France); Yildiz, Umut A.; Kristensen, Lars E.; Van Dishoeck, Ewine F. [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands); Van der Tak, Floris F. S. [SRON Netherlands Institute for Space Research, P.O. Box 800, 9700 AV, Groningen (Netherlands); Walmsley, C. Malcolm; Codella, Claudio [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Nisini, Brunella, E-mail: p.caselli@leeds.ac.uk [INAF-Osservatorio Astronomico di Roma, I-00040 Monte Porzio Catone (Italy)

    2012-11-10T23:59:59.000Z

    Water is a crucial molecule in molecular astrophysics as it controls much of the gas/grain chemistry, including the formation and evolution of more complex organic molecules in ices. Pre-stellar cores provide the original reservoir of material from which future planetary systems are built, but few observational constraints exist on the formation of water and its partitioning between gas and ice in the densest cores. Thanks to the high sensitivity of the Herschel Space Observatory, we report on the first detection of water vapor at high spectral resolution toward a dense cloud on the verge of star formation, the pre-stellar core L1544. The line shows an inverse P-Cygni profile, characteristic of gravitational contraction. To reproduce the observations, water vapor has to be present in the cold and dense central few thousand AU of L1544, where species heavier than helium are expected to freeze out onto dust grains, and the ortho:para H{sub 2} ratio has to be around 1:1 or larger. The observed amount of water vapor within the core (about 1.5 Multiplication-Sign 10{sup -6} M{sub Sun }) can be maintained by far-UV photons locally produced by the impact of galactic cosmic rays with H{sub 2} molecules. Such FUV photons irradiate the icy mantles, liberating water vapor in the core center. Our Herschel data, combined with radiative transfer and chemical/dynamical models, shed light on the interplay between gas and solids in dense interstellar clouds and provide the first measurement of the water vapor abundance profile across the parent cloud of a future solar-type star and its potential planetary system.

  3. Time domain measurement of the THz refractivity of water vapor

    E-Print Network [OSTI]

    Oklahoma State University

    region," Metrologia 18(2), 49­52 (1982). 7. R. J. Hill and R. S. Lawrence, "Refractive index of water

  4. Water-in-carbon dioxide microemulsions: An environment for hydrophiles including proteins

    SciTech Connect (OSTI)

    Johnston, K.P.; Harrison, K.L. [Univ. of Texas, Austin, TX (United States); Clarke, M.J. [Univ. of Nottingham (United Kingdom)] [and others

    1996-02-02T23:59:59.000Z

    Carbon dioxide in the liquid and supercritical fluid states is useful as a replacement for toxic organic solvents. However, nonvolatile hydrophilic substances such as proteins, ions, and most catalysts are insoluble. This limitation was overcome by the formation of aqueous microemulsion droplets in a carbon dioxide-continuous phase with a nontoxic ammonium carboxylate perfluoropolyether surfactant. Several spectroscopic techniques consistently indicated that the properties of the droplets approach those of bulk water. The protein bovine serum albumin (BSA) with a molecular weight of 67,000 is soluble in this microemulsion and experiences an environment similar to that of native BSA in buffer. 23 refs., 4 figs.

  5. IUPAC critical evaluation of the rotationalvibrational spectra of water vapor. Part I--Energy levels and transition wavenumbers

    E-Print Network [OSTI]

    Chance, Kelly

    Keywords: Water vapor Transition wavenumbers Atmospheric physics Energy levels MARVEL Information systemIUPAC critical evaluation of the rotationalvibrational spectra of water vapor. Part I--Energy levels and transition wavenumbers for H2 17 O and H2 18 O Jonathan Tennyson a,, Peter F. Bernath b

  6. Orbital apocenter is not a sufficient condition for HST/STIS detection of Europa's water vapor aurora

    E-Print Network [OSTI]

    Nimmo, Francis

    aurora Lorenz Rotha,b,1 , Kurt D. Retherforda , Joachim Saurc , Darrell F. Strobeld,e , Paul D. Feldmane that the discovery of a water vapor aurora in Decem- ber 2012 by local hydrogen (H) and oxygen (O) emissions by our 2014 STIS observations. Europa | Hubble Space Telescope | aurora | water vapor plumes | Jupiter

  7. The role of water vapor and solar radiation in determining temperature changes and trends measured at Armagh, 18812000

    E-Print Network [OSTI]

    The role of water vapor and solar radiation in determining temperature changes and trends measured in atmospheric circulation, are discussed. Citation: Stanhill, G. (2011), The role of water vapor and solar radiation in determining temperature changes and trends measured at Armagh, 1881­2000, J. Geophys. Res., 116

  8. Water vapor on supergiants. The 12 micron TEXES spectra of mu Cephei

    E-Print Network [OSTI]

    N. Ryde; M. J. Richter; G. M. Harper; K. Eriksson; D. L. Lambert

    2006-03-15T23:59:59.000Z

    Several recent papers have argued for warm, semi-detached, molecular layers surrounding red giant and supergiant stars, a concept known as a MOLsphere. Spectroscopic and interferometric analyses have often corroborated this general picture. Here, we present high-resolution spectroscopic data of pure rotational lines of water vapor at 12 microns for the supergiant mu Cephei. This star has often been used to test the concept of molecular layers around supergiants. Given the prediction of an isothermal, optically thick water-vapor layer in Local Thermodynamic Equilibrium around the star (MOLsphere), we expected the 12 micron lines to be in emission or at least in absorption but filled in by emission from the molecular layer around the star. Our data, however, show the contrary; we find definite absorption. Thus, our data do not easily fit into the suggested isothermal MOLsphere scenario. The 12 micron lines, therefore, put new, strong constraints on the MOLsphere concept and on the nature of water seen in signatures across the spectra of early M supergiants. We also find that the absorption is even stronger than that calculated from a standard, spherically symmetric model photosphere without any surrounding layers. A cool model photosphere, representing cool outer layers is, however, able to reproduce the lines, but this model does not account for water vapor emission at 6 microns. Thus, a unified model for water vapor on mu Cephei appears to be lacking. It does seem necessary to model the underlying photospheres of these supergiants in their whole complexity. The strong water vapor lines clearly reveal inadequacies of classical model atmospheres.

  9. investigating the source, transport, and isotope fractionation of water vapor in the atmospheric boundary layer

    E-Print Network [OSTI]

    Minnesota, University of

    investigating the source, transport, and isotope fractionation of water vapor in the atmospheric-portable mixing ratio generator and Rayleigh distillation device, Agricultural and Forest Meteorology, 150, 1607 ratio generator. Incom- ing dry air passes through a molecular sieve and then a stainless steel frit (a

  10. Water Vapor and Mechanical Work: A Comparison of Carnot and Steam Cycles OLIVIER PAULUIS

    E-Print Network [OSTI]

    Pauluis, Olivier M.

    by the corresponding Carnot cycle. The Carnot and steam cycles can be combined into a mixed cycle that is forcedWater Vapor and Mechanical Work: A Comparison of Carnot and Steam Cycles OLIVIER PAULUIS Center in the atmosphere is discussed here by comparing two idealized heat engines: the Carnot cycle and the steam cycle

  11. Water Vapor Radiometry : Outline of Goals and Tasks for the Spring Semester 2001

    E-Print Network [OSTI]

    Backer, Don

    that can accu­ rately measure the spectrum of the water vapor emis­ sion. The current receivers follow, as in a conventional re­ ceiver, the correlation receiver splits the rf signal into two with a splitter that follows the feed horn. Both branches are mixed with a carefully controlled ther­ mal load. A 180 ffi phase shift

  12. Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor transfer

    E-Print Network [OSTI]

    Martin, Timothy

    Summary Weusedthreemethodstomeasureboundarylayer conductance to heat transfer (gbH) and water vapor of transpiration). The boundary layer conductance to heat transfer is small enough that leaf temperature can become diffusion, the boundary layer around a leaf also provides resistance to the transfer of heat between a leaf

  13. 2.1 RAMAN LIDAR PROFILING OF WATER VAPOR AND AEROSOLS OVER THE ARM SGP SITE

    E-Print Network [OSTI]

    with satellite sensors. Accurate, high spatial and temporal resolution profiles of water vapor are also required+GOES) have been combined into a single product that takes advantage of both active and passive remote sensors with the use of narrowband (~0.4 nm bandpass) filters, reduces the background skylight and, therefore

  14. IUPAC critical evaluation of the rotationalvibrational spectra of water vapor, Part III: Energy levels and transition

    E-Print Network [OSTI]

    Chance, Kelly

    rotational vibrational line positions, transition intensities, and energy levels, with associated critically. These transitions give rise to 18 486 validated energy levels, of which 10 446 and 8040 belong to o-H2 16 O and p-H2IUPAC critical evaluation of the rotationalvibrational spectra of water vapor, Part III: Energy

  15. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06T23:59:59.000Z

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  16. Forced Dispersion of Liquefied Natural Gas Vapor Clouds with Water Spray Curtain Application

    E-Print Network [OSTI]

    Rana, Morshed A.

    2011-02-22T23:59:59.000Z

    .............................................................................................................................. 211 xv LIST OF FIGURES Page Fig. 1. Densities of methane (vapor) and air at different temperatures. .......................... 2 Fig. 2. Temperature and specific gravity of methane, air and methane-air mixture at atmospheric... on methane concentration downwind of the LNG pool ..................................................................................................... 37 Fig. 10. Methane concentrations downwind of the LNG pool, with and without water spray...

  17. Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy

    E-Print Network [OSTI]

    Barrett, Alexander B.

    2010-07-14T23:59:59.000Z

    Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

  18. Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein

    DOE Patents [OSTI]

    Bamberger, Carlos E. (Oak Ridge, TN); Robinson, Paul R. (Knoxville, TN)

    1980-01-01T23:59:59.000Z

    A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cylic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

  19. Hydrogenation of Carbon Dioxide by Water: Alkali-Promoted Synthesis of Formate

    SciTech Connect (OSTI)

    Hrbek, J.; Hoffmann, F.M.; Yang, Y.; Paul, J.; White, M.G.

    2010-07-15T23:59:59.000Z

    Conversion of carbon dioxide utilizing protons from water decomposition is likely to provide a sustainable source of fuels and chemicals in the future. We present here a time-evolved infrared reflection absorption spectroscopy (IRAS) and temperature-programmed desorption (TPD) study of the reaction of CO{sub 2} + H{sub 2}O in thin potassium layers. Reaction at temperatures below 200 K results in the hydrogenation of carbon dioxide to potassium formate. Thermal stability of the formate, together with its sequential transformation to oxalate and to carbonate, is monitored and discussed. The data of this model study suggest a dual promoter mechanism of the potassium: the activation of CO{sub 2} and the dissociation of water. Reaction at temperatures above 200 K, in contrast, is characterized by the absence of formate and the direct reaction of CO{sub 2} to oxalate, due to a drastic reduction of the sticking coefficient of water at higher temperatures.

  20. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06T23:59:59.000Z

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of this contract, we participated in another ARM-sponsored experiment at the NSA during February-March 2007. This experiment is called the Radiative Heating in Underexplored Bands Campaign (RHUBC) and the GSR was operated successfully for the duration of the campaign. One of the principal goals of the experiment was to provide retrievals of water vapor during PWV amounts less than 2 mm and to compare GSR data with ARM radiometers and radiosondes. A secondary goal was to compare the radiometric response of the microwave and millimeter wavelength radiometers to water and ice clouds. In this final report, we will include the separate progress reports for each of the three years of the project and follow with a section on major accomplishments of the project.

  1. Energy and water vapor transport across a simplified cloud-clear air interface

    E-Print Network [OSTI]

    Gallana, Luca; De Santi, Francesca; Iovieno, Michele; Tordella, Daniela

    2015-01-01T23:59:59.000Z

    We consider a simplified physics of the could interface where condensation, evaporation and radiation are neglected and momentum, thermal energy and water vapor transport is represented in terms of the Boussinesq model coupled to a passive scalar transport equation for the vapor. The interface is modeled as a layer separating two isotropic turbulent regions with different kinetic energy and vapor concentration. In particular, we focus on the small scale part of the inertial range as well as on the dissipative range of scales which are important to the micro-physics of warm clouds. We have numerically investigated stably stratified interfaces by locally perturbing at an initial instant the standard temperature lapse rate at the cloud interface and then observing the temporal evolution of the system. When the buoyancy term becomes of the same order of the inertial one, we observe a spatial redistribution of the kinetic energy which produce a concomitant pit of kinetic energy within the mixing layer. In this sit...

  2. Vapor-liquid equilibria of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems

    SciTech Connect (OSTI)

    Mun, S.Y.; Lee, H.

    1999-12-01T23:59:59.000Z

    Vapor-liquid equilibrium data of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems were measured at 60, 160, 300, and 760 mmHg at temperatures ranging from 315 to 488 K. The apparatus used in this work is a modified still especially designed for the measurement of low-pressure VLE, in which both liquid and vapor are continuously recirculated. For the analysis of salt-containing solutions, a method incorporating refractometry and gravimetry was used. From the experimental measurements, the effect of lithium bromide on the VLE behavior of water + 1,3-propanediol was investigated. The experimental data of the salt-free system were successfully correlated using the Wilson, NRTL, and UNIQUAC models. In addition, the extended UNIQUAC model of Sander et al. was applied to the VLE calculation of salt-containing mixtures.

  3. Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I)

    E-Print Network [OSTI]

    Manning, Norman Willis William

    2012-06-07T23:59:59.000Z

    A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ polarization difference...

  4. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01T23:59:59.000Z

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  5. The Effects of Water Vapor and Hydrogen on the High-Temperature Oxidation of Alloys

    SciTech Connect (OSTI)

    Mu, N.; Jung, K.; Yanar, N. M.; Pettit, F. S; Holcomb, G. R.; Howard, B. H.; Meier, G. H.

    2013-06-01T23:59:59.000Z

    Essentially all alloys and coatings that are resistant to corrosion at high temperature require the formation of a protective (slowly-growing and adherent) oxide layer by a process known as selective oxidation. The fundamental understanding of this process has been developed over the years for exposure in pure oxygen or air. However, the atmospheres in most applications contain significant amounts of water vapor which can greatly modify the behavior of protective oxides. The development of oxy-fuel combustion systems in which fossil fuels are burned in a mixture of recirculated flue gas and oxygen, rather than in air, has caused renewed interest in the effects of water vapor and steam on alloy oxidation. The focus of this paper is on the ways the presence of water vapor can directly alter the selective oxidation process. The paper begins with a brief review of the fundamentals of selective oxidation followed by a description of recent experimental results regarding the effect of water vapor on the oxidation of a variety of chromia-forming alloys (Fe- and Ni-base) in the temperature range 600 to 700 C. The atmospheres include air, air-H{sub 2}O, Ar-H{sub 2}O and Ar-H{sub 2}O-O{sub 2}. Then the behavior of alumina-forming alloys in H{sub 2}O-containing atmospheres is briefly described. As hydrogen is produced during oxidation of alloys in H{sub 2}O, it can be released back into the gas phase or injected into the metal (where it can diffuse through to the other side). Experiments in which hydrogen concentrations have been measured on both sides of thin specimens during oxidation by H{sub 2}O on only one side are described. Finally, it is attempted to catalogue the various experimental observations under a few general principles.

  6. Short-range precipitation forecasts using assimilation of simulated satellite water vapor profiles and column cloud liquid water amounts

    SciTech Connect (OSTI)

    Wu, X.; Diak, G.R.; Hayden, C.M.; Young, J.A. [Univ. of Wisconsin, Madison, WI (United States)] [Univ. of Wisconsin, Madison, WI (United States)

    1995-02-01T23:59:59.000Z

    These observing system simulation experiments investigate the assimilation of satellite-observed water vapor and cloud liquid water data in the initialization of a limited-area primitive equations model with the goal of improving short-range precipitation forecasts. The assimilation procedure presented includes two aspects: specification of an initial cloud liquid water vertical distribution and diabatic initialization. The satellite data is simulated for the next generation of polar-orbiting satellite instruments, the Advanced Microwave Sounding Unit (AMSU) and the High-Resolution Infrared Sounder (HIRS), which are scheduled to be launched on the NOAA-K satellite in the mid-1990s. Based on cloud-top height and total column cloud liquid water amounts simulated for satellite data a diagnostic method is used to specify an initial cloud water vertical distribution and to modify the initial moisture distribution in cloudy areas. Using a diabatic initialization procedure, the associated latent heating profiles are directly assimilated into the numerical model. The initial heating is estimated by time averaging the latent heat release from convective and large-scale condensation during the early forecast stage after insertion of satellite-observed temperature, water vapor, and cloud water formation.

  7. Response of water vapor to interannual variations of SST: Results from NCAR Community Climate Model (CCM2)

    SciTech Connect (OSTI)

    Sun, De-Zheng [National Center For Atmospheric Research, Boulder, CO (United States)

    1997-11-01T23:59:59.000Z

    This paper very briefly documents the response of water vapor to interannual changes in sea surface temperature (SST) in two of the most frequently used climate models: the National Center for Atmospheric Research (NCAR) community climate model (CCM2) and the GFDL spectral model (R30). The corresponding results from radiosonde data are also presented for reference. A simple linear regression model is used to quantify the response of water vapor to changes in SST in the two simulations. Except for the negative response of water vapor over Australia, CCM2 simulates the major characteristics in the horizontal structure of the water vapor response shown in the radiosonde data. The negative response of water over Australia is also not well simulated by GFDL R30. In addition, GFDL R30 significantly underestimates the positive response over the Indian Ocean. The horizontal contrasts between the negative response over the western Pacific and the positive response over the central and eastern Pacific in the model simulations are larger than in the radiosonde data. The negative response in the subtropical region in CCM2 is more pronounced than in R30. Averaged over the tropics, CCM2 has a larger water vapor response in both the boundary layer and the upper troposphere than R30. The correlations between variations of water vapor in the upper troposphere and those at the surface level are also stronger in CCM2 than in R30. 2 refs., 5 figs.

  8. Orographic Precipitation and Water Vapor Fractionation over the Southern Andes RONALD B. SMITH AND JASON P. EVANS

    E-Print Network [OSTI]

    Evans, Jason

    Orographic Precipitation and Water Vapor Fractionation over the Southern Andes RONALD B. SMITH (Smith and Barstad 2004) to predict the patterns of orographic pre- Corresponding author address: Ronald B. Smith, Depa

  9. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    Bulavin, L A; Makhlaichuk, V N

    2015-01-01T23:59:59.000Z

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherlan...

  10. Effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water

    SciTech Connect (OSTI)

    Polka, H.M.; Gmehling, J. (Univ. of Oldenburg (Germany). Chair of Industrial Chemistry)

    1994-07-01T23:59:59.000Z

    The effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water was studied using a Swietoslawski ebulliometer. The measurements were performed for two constant salt molalities (1 and 2 mol[center dot]kg[sup [minus]1]) under isobaric conditions at 50.66 kPa. Strong salting-out of the alcohol was observed in all cases, leading to a complete elimination of the azeotropic point at relatively low salt concentrations. The results were correlated using an extension of the NRTL equation for mixed solvent electrolyte systems proposed by Mock, Evans, and Chen.

  11. E-Print Network 3.0 - ammonia-water-carbon dioxide mixtures Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: . The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet... . Carbon dioxide gas is the principal greenhouse...

  12. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01T23:59:59.000Z

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  13. Near-infrared diode laser absorption diagnostic for temperature and water vapor in a scramjet combustor

    SciTech Connect (OSTI)

    Liu, Jonathan T.C.; Rieker, Gregory B.; Jeffries, Jay B.; Gruber, Mark R.; Carter, Campbell D.; Mathur, Tarun; Hanson, Ronald K

    2005-11-01T23:59:59.000Z

    Tunable diode laser absorption measurements of gas temperature and water concentration were made at the exit of a model scramjet combustor fueled on JP-7. Multiplexed, fiber-coupled, near-infrared distributed feedback lasers were used to probe three water vapor absorption features in the 1.34-1.47 {mu}m spectral region (2v1and v1+ v3overtone bands). Ratio thermometry was performed using direct-absorption wavelength scans of isolated features at a 4-kHz repetition rate, as well as 2f wavelength modulation scans at a 2-kHz scan rate. Large signal-to-noise ratios demonstrate the ability of the optimally engineered optical hardware to reject beam steering and vibration noise. Successful measurements were made at full combustion conditions for a variety of fuel/air equivalence ratios and at eight vertical positions in the duct to investigate spatial uniformity. The use of three water vapor absorption features allowed for preliminary estimates of temperature distributions along the line of sight. The improved signal quality afforded by 2f measurements, in the case of weak absorption, demonstrates the utility of a scanned wavelength modulation strategy in such situations.

  14. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  15. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01T23:59:59.000Z

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  16. In-reactor oxidation of zircaloy-4 under low water vapor pressures

    SciTech Connect (OSTI)

    Walter G. Luscher; David J. Senor; Keven K. Clayton; Glen R. Longhurst

    2015-01-01T23:59:59.000Z

    Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 C). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

  17. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu (Rijswijk, NL)

    2010-03-16T23:59:59.000Z

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  18. Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

    SciTech Connect (OSTI)

    Hosni, Mohammad H.

    2014-03-30T23:59:59.000Z

    Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerants pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

  19. Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)

    SciTech Connect (OSTI)

    Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

    1999-05-01T23:59:59.000Z

    The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

  20. Electrical, optical, and material characterizations of blue InGaN light emitting diodes submitted to reverse-bias stress in water vapor condition

    SciTech Connect (OSTI)

    Chen, Hsiang, E-mail: hchen@ncnu.edu.tw; Chu, Yu-Cheng; Chen, Yun-Ti; Chen, Chian-You [Department of Applied Materials and Optoelectronic Engineering, National Chi Nan University, No. 1, University Road, Puli, Nantou County 54561, Taiwan (China); Shei, Shih-Chang [Department of Electrical Engineering, National University of Tainan, No.33, Sec. 2, Shulin St., West Central Dist., Tainan City 70005, Taiwan (China)

    2014-09-07T23:59:59.000Z

    In this paper, we investigate degradation of InGaN/GaN light emitting diodes (LEDs) under reverse-bias operations in water vapor and dry air. To examine failure origins, electrical characterizations including current-voltage, breakdown current profiles, optical measurement, and multiple material analyses were performed. Our findings indicate that the diffusion of indium atoms in water vapor can expedite degradation. Investigation of reverse-bias stress can help provide insight into the effects of water vapor on LEDs.

  1. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01T23:59:59.000Z

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  2. Comparison of Atmospheric Water Vapor in Observational and Model Data Sets

    SciTech Connect (OSTI)

    Boyle, J.S.

    2000-03-01T23:59:59.000Z

    The global water vapor distribution for five observational based data sets and three GCM integrations are compared. The variables considered are the mean and standard deviation values of the precipitable water for the entire atmospheric column and the 500 to 300 hPa layer for January and July. The observationally based sets are the radiosonde data of Ross and Elliott, the ERA and NCEP reanalyses, and the NVAP blend of sonde and satellite data. The three GCM simulations all use the NCAR CCM3 as the atmospheric model. They include: a AMIP type simulation using observed SSTs for the period 1979 to 1993, the NCAR CSM 300 year coupled ocean--atmosphere integration, and a CSM integration with a 1% CO2 increase per year. The observational data exhibit some serious inconsistencies. There are geographical patterns of differences related to interannual variations and national instrument biases. It is clear that the proper characterization of water vapor is somewhat uncertain. Some conclusions about these data appear to be robust even given the discrepancies. The ERA data are too dry especially in the upper levels. The observational data evince much better agreement in the data rich Northern Hemisphere compared to the Southern. Distinct biases are quite pronounced over the Southern Ocean. The mean values and particularly the standard deviations of the three reanalyses are very dependent upon the GCM used as the assimilation vehicle for the analyses. This is made clear by the much enhanced tropical variability in the NCEP/DOE/ AMIP reanalyses compared the initial NCEP/NCAR Reanalysis. The NCAR CCM3 shows consistent evidence of a dry bias. The 1% CO2 experiment shows a very similar pattern of disagreement with the sonde data as the other integrations, once account is taken of the warming trend. No new modes of difference are evident in the 1% CO2 experiment. All the CCM3 runs indicated too much Tropical variability especially in the western Tropical Pacific and Southeast Asia. A EOF analysis of the interannual variations of the zonally averaged precipitable water and the 500 to 300 hPa layer reveals fundamental differences in the structure of the variations. The impact of ENSO and variations of the ITCZ have only a low level of correspondence between the observed data, much less the simulations. It is apparent that an adequate characterization of the climatology of the global water vapor distribution is not yet at hand.

  3. PERFORMANCE IMPROVEMENTS IN COMMERCIAL HEAT PUMP WATER HEATERS USING CARBON DIOXIDE

    SciTech Connect (OSTI)

    BOWERS C.D.; ELBEL S.; PETERSEN M.; HRNJAK P.S.

    2011-07-01T23:59:59.000Z

    Although heat pump water heaters are today widely accepted in Japan, where energy costs are high and government incentives for their use exist, acceptance of such a product in the U.S. has been slow. This trend is slowly changing with the introduction of heat pump water heaters into the residential market, but remains in the commercial sector. Barriers to heat pump water heater acceptance in the commercial market have historically been performance, reliability and first/operating costs. The use of carbon dioxide (R744) as the refrigerant in such a system can improve performance for relatively small increase in initial cost and make this technology more appealing. What makes R744 an excellent candidate for use in heat pump water heaters is not only the wide range of ambient temperatures within which it can operate, but also the excellent ability to match water to refrigerant temperatures on the high side, resulting in very high exit water temperatures of up to 82?ºC (180?ºF), as required by sanitary codes in the U.S.(Food Code, 2005), in a single pass, temperatures that are much more difficult to reach with other refrigerants. This can be especially attractive in applications where this water is used for the purpose of sanitation. While reliability has also been of concern historically, dramatic improvements have been made over the last several years through research done in the automotive industry and commercialization of R744 technology in residential water heating mainly in Japan. This paper presents the performance results from the development of an R744 commercial heat pump water heater of approximately 35kW and a comparison to a baseline R134a unit of the same capacity and footprint. In addition, recommendations are made for further improvements of the R744 system which could result in possible energy savings of up to 20%.

  4. A model of vapor-liquid equilibria for acid gas-alkanolamine-water systems

    SciTech Connect (OSTI)

    Austgen, D.M. Jr.

    1989-01-01T23:59:59.000Z

    A physico-chemical model was developed for representing liquid phase chemical equilibria and vapor-liquid (phase) equilibria of H{sub 2}SCO{sub 2}-alkanolamine-water systems. The equilibrium composition of the liquid phase is determined by minimization of the Gibbs free energy. Activity coefficients are represented with the Electrolyte-NRTL equation treating both long-range electrostatic interactions and short-range binary interactions between liquid phase species. Vapor phase fugacity coefficients are calculated using the Redlich-Kwong-Soave Equation of State. Adjustable parameters of the model, binary interaction parameters and carbamate stability constants, were fitted on published binary system alkanolamine-water and ternary system (H{sub 2}S-alkanolamine-water, CO{sub 2}-alkanolamine-water) VLE data. The Data Regression System of ASPEN PLUS, based upon the Maximum Likelihood Principle, was used to estimate adjustable parameters. Ternary system measurements used in parameter estimation ranged in temperature from 25 to 120{degree}C in alkanolamine concentration from 1 to 5 M, in acid gas loading from 0 to 1.5 moles per mole alkanolamine, and in acid gas partial pressure from 0.1 to 1,000 kPa. Maximum likelihood estimates of ternary system H{sub 2} or CO{sub 2} equilibrium partial pressures and liquid phase concentrations were found to be in good agreement with measurements for aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA), diglycolamine (DGA), and methyldiethanolamine (MDEA) indicating that the model successfully represents ternary system data. The model was extended to represent CO{sub 2} solubility in aqueous mixtures of MDEA with MEA or DEA. The solubility was measured at 40 and 80{degree}C over a wide range of CO{sub 2} partial pressures. These measurements were used to estimate additional binary parameters of the mixed solvent systems.

  5. Moisture effects in low-slope roofs: Drying rates after water addition with various vapor retarders

    SciTech Connect (OSTI)

    Pedersen, C.R. [Technical Univ. of Denmark, Lyngby (Denmark); Petrie, T.W. [Marquette Univ., Milwaukee, WI (United States). Dept. of Mechanical Engineering; Courville, G.E.; Desjarlais, A.O.; Childs, P.W.; Wilkes, K.E. [Oak Ridge National Lab., TN (United States)

    1992-10-01T23:59:59.000Z

    Tests have been conducted in the Large Scale Climate Simulator (LSCS) of the US. Building Envelope Research Center at the Oak Ridge National Laboratory (ORNL) to investigate downward drying rates of various unvented, low-slope roof systems. A secondary objective was to study heat flow patterns so as to understand how to control latent heat effects on impermeable heat flux transducers. Nine test sections were tested simultaneously. The sections had a p deck above fibrous-glass insulation and were examples of cold-deck systems. These five sections had various vapor retarder systems on a gypsum board ceiling below the insulation. The other four sections had a lightweight insulating concrete deck below expanded polystyrene insulation and the same vapor retarder systems, and were examples of warm-deck systems. The cold-deck systems had materials that were relatively permeable to water vapor, while the materials in the warm-deck systems were less permeable. All test sections were topped by an impermeable roofing membrane. The test sections were instrumented with thermocouples between all layers and with small heat flux transducers at the bottom and top of the fibrous-glass insulation and in the middle of the expanded polystyrene insulation. Two different kinds of moisture probes were used to qualitatively monitor the movement of the moisture. The heat flux measurements showed that heat conduction dominates the system using impermeable insulation materials, with only a slight increase due to increased thermal conductivity of wet expanded polystyrene. There was significant transfer of latent heat in the test sections with permeable insulation, causing the peak heat fluxes to increase by as much as a factor of two. With temperatures imposed that are typical of summer days, latent heat transfer associated with condensation and evaporation of moisture in the test sections was measured to be as important as the heat transfer by conduction.

  6. Effect of surfactants on the interfacial tension and emulsion formation between water and carbon dioxide

    SciTech Connect (OSTI)

    Rocha, S.R.P. da; Harrison, K.L.; Johnston, K.P. [Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering] [Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering

    1999-01-19T23:59:59.000Z

    The lowering of the interfacial tension ({gamma}) between water and carbon dioxide by various classes of surfactants is reported and used to interpret complementary measurements of the capacity, stability, and average drop size of water-in-CO{sub 2} emulsions. {gamma} is lowered from {approximately}20 to {approximately}2 mN/m for the best poly(propylene oxide)-b-poly(ethylene oxide)-b-poly(propylene oxide) (PPO-b-PEO-b-PPO) and PeO-b-PPO-b-PEO Pluronic triblock copolymers, 1.4 mN/m for a poly(butylene oxide)-b-PEO copolymer, 0.8 mN/m for a perfluoropolyether (PEPE) ammonium carboxylate and 0.2 mN/m for PDMS{sub 24}-g-EO{sub 22}. The hydrophilic-CO{sub 2}-philic balance (HCB) of the triblock Pluronic and PDMS-g-PEO-PPO surfactants is characterized by the CO{sub 2}-to-water distribution coefficient and V-shaped plots of log {gamma} vs wt % EO. A minimum in {gamma} is observed for the optimum HCB. As the CO{sub 2}-philicity of the surfactant tail is increased, the molecular weight of the hydrophilic segment increases for an optimum HCB. The stronger interactions on both sides of the interface lead to a lower {gamma}. Consequently, more water was emulsified for the PDMS-based copolymers than either the PPO- or PBO-based copolymers.

  7. A comparison of water vapor quantities from model short-range forecasts and ARM observations

    SciTech Connect (OSTI)

    Hnilo, J J

    2006-03-17T23:59:59.000Z

    Model evolution and improvement is complicated by the lack of high quality observational data. To address a major limitation of these measurements the Atmospheric Radiation Measurement (ARM) program was formed. For the second quarter ARM metric we will make use of new water vapor data that has become available, and called the 'Merged-sounding' value added product (referred to as OBS, within the text) at three sites: the North Slope of Alaska (NSA), Darwin Australia (DAR) and the Southern Great Plains (SGP) and compare these observations to model forecast data. Two time periods will be analyzed March 2000 for the SGP and October 2004 for both DAR and NSA. The merged-sounding data have been interpolated to 37 pressure levels (e.g., from 1000hPa to 100hPa at 25hPa increments) and time averaged to 3 hourly data for direct comparison to our model output.

  8. The Effect of Water Vapor on Cr Depletion in Advanced Recuperator Alloys

    SciTech Connect (OSTI)

    Pint, Bruce A [ORNL

    2005-01-01T23:59:59.000Z

    Durable alloy foils are needed for gas turbine recuperators operating at 650--700 C. It has been established that water vapor in the exhaust gas causes more rapid consumption of Cr in austenitic stainless steels leading to a reduction in operating lifetime of these thin-walled components. Laboratory testing at 650--800 C of commercial and model alloys is being used to develop a better understanding of the long-term rate of Cr consumption in these environments. Results are presented for commercial alloys 709, 120 and 625. After 10,000h exposures at 650 C and 700 C in humid air, grain boundary Cr depletion was observed near the surface of all these materials. In the Fe-base alloys, 709 and 120, this depletion led to localized Fe-rich nodule formation. This information then can be used to develop low-cost alternatives to currently available candidate materials.

  9. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31T23:59:59.000Z

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during air sparging. To this end, we conducted batch and column laboratory SMZ and VPB experiments with synthetic and actual produced waters. Based on the results of the laboratory testing, a pilot scale study was designed and conducted to evaluate the combined SMZ/VPB process. An economic and regulatory feasibility analysis was also completed as part of the current study to assess the viability of the process for various water re-use options.

  10. Ten Years of Measurements of Tropical Upper-Tropospheric Water Vapor by MOZAIC. Part I: Climatology, Variability, Transport, and Relation to

    E-Print Network [OSTI]

    Lombardi, John R.

    the International Satellite Cloud Climatology Project (ISCCP). 1. Introduction Water vapor is the key atmosphericTen Years of Measurements of Tropical Upper-Tropospheric Water Vapor by MOZAIC. Part I: Climatology, Variability, Transport, and Relation to Deep Convection ZHENGZHAO LUO, DIETER KLEY,* AND RICHARD H. JOHNSON

  11. Storing carbon dioxide in saline formations : analyzing extracted water treatment and use for power plant cooling.

    SciTech Connect (OSTI)

    Dwyer, Brian P.; Heath, Jason E.; Borns, David James; Dewers, Thomas A.; Kobos, Peter Holmes; Roach, Jesse D.; McNemar, Andrea; Krumhansl, James Lee; Klise, Geoffrey T.

    2010-10-01T23:59:59.000Z

    In an effort to address the potential to scale up of carbon dioxide (CO{sub 2}) capture and sequestration in the United States saline formations, an assessment model is being developed using a national database and modeling tool. This tool builds upon the existing NatCarb database as well as supplemental geological information to address scale up potential for carbon dioxide storage within these formations. The focus of the assessment model is to specifically address the question, 'Where are opportunities to couple CO{sub 2} storage and extracted water use for existing and expanding power plants, and what are the economic impacts of these systems relative to traditional power systems?' Initial findings indicate that approximately less than 20% of all the existing complete saline formation well data points meet the working criteria for combined CO{sub 2} storage and extracted water treatment systems. The initial results of the analysis indicate that less than 20% of all the existing complete saline formation well data may meet the working depth, salinity and formation intersecting criteria. These results were taken from examining updated NatCarb data. This finding, while just an initial result, suggests that the combined use of saline formations for CO{sub 2} storage and extracted water use may be limited by the selection criteria chosen. A second preliminary finding of the analysis suggests that some of the necessary data required for this analysis is not present in all of the NatCarb records. This type of analysis represents the beginning of the larger, in depth study for all existing coal and natural gas power plants and saline formations in the U.S. for the purpose of potential CO{sub 2} storage and water reuse for supplemental cooling. Additionally, this allows for potential policy insight when understanding the difficult nature of combined potential institutional (regulatory) and physical (engineered geological sequestration and extracted water system) constraints across the United States. Finally, a representative scenario for a 1,800 MW subcritical coal fired power plant (amongst other types including supercritical coal, integrated gasification combined cycle, natural gas turbine and natural gas combined cycle) can look to existing and new carbon capture, transportation, compression and sequestration technologies along with a suite of extracting and treating technologies for water to assess the system's overall physical and economic viability. Thus, this particular plant, with 90% capture, will reduce the net emissions of CO{sub 2} (original less the amount of energy and hence CO{sub 2} emissions required to power the carbon capture water treatment systems) less than 90%, and its water demands will increase by approximately 50%. These systems may increase the plant's LCOE by approximately 50% or more. This representative example suggests that scaling up these CO{sub 2} capture and sequestration technologies to many plants throughout the country could increase the water demands substantially at the regional, and possibly national level. These scenarios for all power plants and saline formations throughout U.S. can incorporate new information as it becomes available for potential new plant build out planning.

  12. The influence of midlatitude and tropical overturning circulation on the isotopic composition of atmospheric water vapor and

    E-Print Network [OSTI]

    Noone, David

    coordinates. In this depiction, poleward transport of air and water vapor is non-diffusive, in a way for an open distillation. Model experiments that simulate a wide range of circulation strengths show to the polar region exceeds the rate at which surface sources replenish the poleward moving air stream. Across

  13. Isothermal vapor-liquid equilibria for water + 2-aminoethanol + dimethyl sulfoxide and its constituent three binary systems

    SciTech Connect (OSTI)

    Tochigi, Katsumi; Akimoto, Kentarou; Ochi, Kenji [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Liu, Fangyhi; Kawase, Yasuhito [Nippon Refine Co., Ltd., Tokyo (Japan)] [Nippon Refine Co., Ltd., Tokyo (Japan)

    1999-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system water + 2-aminoethanol + dimethyl sulfoxide and its three constituent binary mixtures at 363.15 K. The apparatus used was a modified Rogalski-Malanoski equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  14. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01T23:59:59.000Z

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

  15. Designer organisms for photosynthetic production of ethanol from carbon dioxide and water

    DOE Patents [OSTI]

    Lee, James Weifu (Knoxville, TN)

    2011-07-05T23:59:59.000Z

    The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

  16. DESIGN OF HYBRID POWER GENERATION CYCLES EMPLOYING AMMONIA-WATER-CARBON DIOXIDE MIXTURES

    SciTech Connect (OSTI)

    Ashish Gupta

    2002-06-01T23:59:59.000Z

    A power cycle generates electricity from the heat of combustion of fossil fuels. Its efficiency is governed by the cycle configuration, the operating parameters, and the working fluid. Typical. designs use pure water as the fluid. in the last two decades, hybrid cycles based on ammonia-water, and carbon-dioxide mixtures as the working fluid have been proposed. These cycles may improve the power generation efficiency of Rankine cycles by 15%. Improved efficiency is important for two reasons: it lowers the cost of electricity being produced, and by reducing the consumption of fossil fuels per unit power, it reduces the generation of environmental pollutants. The goal of this project is to develop a computational optimization-based method for the design and analysis of hybrid bottoming power cycles to minimize the usage of fossil fuels. The development of this methodology has been achieved by formulating this task as that of selecting the least cost power cycle design from all possible configurations. They employ a detailed thermodynamic property prediction package they have developed under a DOE-FETC grant to model working fluid mixtures. Preliminary results from this work suggest that a pure NH{sub 3} cycle outperforms steam or the expensive Kalina cycle.

  17. A three-beam water vapor sensor system for combustion diagnostics using a 1390 nm tunable diode laser

    SciTech Connect (OSTI)

    Wang, L.G. [Coll. of William and Mary, Williamsburg, VA (United States). Dept. of Physics; Vay, S. [National Aeronautics and Space Administration, Hampton, VA (United States). Langley Research Center

    1995-12-31T23:59:59.000Z

    H{sub 2}O(v) is an important species in combustion and hypersonic flow measurements because it is a primary combustion product. Measurements of water vapor can be used to determine performance parameters, such as extent and efficiency of combustion in propulsion and aerodynamics facilities. Water vapor concentration measurement in these high-temperature hypervelocity combustion conditions requires very high sensitivity and fast time response. A three-beam diode laser H{sub 2}O(v) measurement system for nonintrusive combustion diagnostics has been developed at NASA Langley Research Center and successfully tested and installed at GASL NASA HYPULSE facility for routine operation. The system was built using both direct laser absorption spectroscopy and frequency modulation laser spectroscopy. The output beam from a distributed feedback (DFB) InGaAsP diode laser (emitting around 1.39 {micro}m) is split into three equal-powered equal-distanced parallel beams with separation of 9 mm. With three beams, the authors are able to obtain water vapor number densities at three locations. Frequency modulation spectroscopy technique is used to achieve high detection sensitivity. The diode laser is modulated at radio frequency (RF), while the wavelength of the diode laser is tuned to scan over a strong water vapor absorption line. The detected RF signal is then demodulated at the fundamental frequency of the modulation (one-F demodulation). A working model and a computer software code have been developed for data process and data analysis. Water vapor number density measurements are achieved with consideration of temperature dependence. Experimental results and data analysis will be presented.

  18. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria, E-mail: Valeria.Molinero@utah.edu [Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

    2014-11-14T23:59:59.000Z

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  19. Two Stage Vapor Compression Heat Pump with Solution Circuits: Catering to Simultaneous Chilling and Water Heating Needs

    E-Print Network [OSTI]

    Rane, M. V.; Radermacher, R.

    results indicate that the two stage VCHSC can achiev~ cooling coefficient of performances as high as 1.04 while pumping heat through a lift of 194?F (10S0C). Comparison is made with a system consisting of a vapor compressor chiller and a gas fired... conditioning and hot water for various uses will be assessed. comparison is made with a system consisting of a vapor compressor chiller and a gas fired furnace (option 2). The basis for comparison being: a) the total primary energy usage, b) the cost...

  20. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

    2014-05-14T23:59:59.000Z

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  1. Laboratory Investigations in Support of Carbon Dioxide-in-Water Emulsions Stabilized by Fine Particles for Ocean and Geologic Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Dan Golomb; David Ryan; Eugene Barry

    2007-01-08T23:59:59.000Z

    Since the submission of our last Semi-annual Report, dated September 2006, the research objectives of this Co-operative Agreement shifted toward geologic sequestration of carbon dioxide. In the period September 2006-February 2007, experiments were conducted in a High-Pressure Batch Reactor (HPBR) for creating emulsions of liquid carbon dioxide (/CO{sub 2})-in-water stabilized by fine particles for geologic sequestration of CO{sub 2}. Also, emulsions were created in water of a binary mixture of liquid carbon dioxide and liquid hydrogen sulfide (/H{sub 2}S), called Acid Gas (AG). This leads to the possibility of safe disposal of AG in deep geologic formations, such as saline aquifers. The stabilizing particles included pulverized limestone (CaCO{sub 3}), unprocessed flyash, collected by an electrostatic precipitator at a local coal-fired power plant, and pulverized siderite (FeCO{sub 3}). Particle size ranged from submicron to a few micrometers. The first important finding is that /CO{sub 2} and /H{sub 2}S freely mix as a binary liquid without phase separation. The next finding is that the mixture of /CO{sub 2} and /H{sub 2}S can be emulsified in water using fine particles as emulsifying agents. Such emulsions are stable over prolonged periods, so it should not be a problem to inject an emulsion into subterranean formations. The advantage of injecting an emulsion into subterranean formations is that it is denser than the pure liquid, therefore it is likely to disperse in the bottom of the geologic formation, rather than buoying upward (called fingering). In such a fashion, the risk of the liquids escaping from the formation, and possibly re-emerging into the atmosphere, is minimized. This is especially important for H{sub 2}S, because it is a highly toxic gas. Furthermore, the emulsion may interact with the surrounding minerals, causing mineral trapping. This may lead to longer sequestration periods than injecting the pure liquids alone.

  2. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01T23:59:59.000Z

    Renewable Energy, Office of Geothermal Technologies, of theTransport in Fractured Geothermal Reservoirs, Geothermics,Depletion of Vapor-Dominated Geothermal Reservoirs, Lawrence

  3. Raman spectroscopy of solutions and interfaces containing nitrogen dioxide, water, and 1,4 dioxane: Evidence for repulsion of surface water by NO{sub 2} gas

    SciTech Connect (OSTI)

    Murdachaew, Garold [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel)] [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel); Varner, Mychel E.; Veer, Wytze E. van der [Department of Chemistry, University of California, Irvine, California 92697 (United States)] [Department of Chemistry, University of California, Irvine, California 92697 (United States); Gerber, R. Benny [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel) [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel); Department of Chemistry, University of California, Irvine, California 92697 (United States); Phillips, Leon F., E-mail: leon.phillips@canterbury.ac.nz [Department of Chemistry, University of California, Irvine, California 92697 (United States); Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch (New Zealand)

    2014-05-14T23:59:59.000Z

    The interaction of water, 1,4 dioxane, and gaseous nitrogen dioxide, has been studied as a function of distance measured through the liquid-vapour interface by Raman spectroscopy with a narrow (<0.1 mm) laser beam directed parallel to the interface. The Raman spectra show that water is present at the surface of a dioxane-water mixture when gaseous NO{sub 2} is absent, but is virtually absent from the surface of a dioxane-water mixture when gaseous NO{sub 2} is present. This is consistent with recent theoretical calculations that show NO{sub 2} to be mildly hydrophobic.

  4. Corrosion of aluminum-uranium alloys in water vapor at 200 C

    SciTech Connect (OSTI)

    Lam, P.S.; Sindelar, R.L.; Barrett, K.Y.

    1999-07-01T23:59:59.000Z

    Specimens of aluminum-uranium alloys at 10 and 18 wt.% uranium were exposed to a saturated water vapor condition at 200 C up to about 12 weeks and compared to previous results for aluminum 1100. The aluminum-uranium materials exhibited a range of initial corrosion rates and approached similar rates with the formation of a passive film of boehmite (Al{sub 2}O{sub 3}{center{underscore}dot}H{sub 2}O). The initial corrosion rates of the aluminum-uranium materials were one to four times higher than that for aluminum 1100. It is postulated that a micro-galvanic coupling between the large UAl{sub 4} particles and the aluminum matrix has caused this difference. Sectioning the exposed specimens shows different characteristics of the oxide layers. In the oxide on the aluminum-10% uranium alloy (Al-10%U), small uranium aluminide particles can be seen in a boehmite matrix and do not seem to be corroded. The oxide film on the aluminum-18% uranium alloy (Al-18%U) appears to have two distinct oxide layers. The outer layer has mass aggregates in a boehmite matrix, while the inner layer contains UAl{sub 4} particles as in the case of Al-10%U.

  5. Corrosion of Aluminum-Uranium Alloys in Water Vapor at 200\\260C

    SciTech Connect (OSTI)

    Lam, P.S.

    1998-11-25T23:59:59.000Z

    Coupons of aluminum-uranium alloys at 10 and 18 weight percent were exposed to a saturated water vapor condition at 200 degrees C up to about 1500 hours and compared to previous results for aluminum 1100. The aluminum-uranium materials exhibited a range of initial corrosion rates and approached similar rates with the formation of a passive film of boehmite (Al2O3oH2O). The cast and extruded 10 percent uranium, having a primary aluminum-eutectic microstructure, was more corrosion resistant than the 18% cast and extruded. The initial corrosion rates of the aluminum-uranium materials were one to four times higher than that for aluminum 1100. It is postulated that a micro-galvanic coupling between the large UAl4 particles and the aluminum matrix has caused the variation. Sectioning the exposed specimens shows different characteristics of the oxide layers. In the case of the cast and extruded Al-10 percent U alloy, small uranium aluminide particles can be seen in the boehmite matrix and do not seem to be corroded. The oxide film of the Al-18 percent U alloy appears to have two distinct oxide layers. The outer layer has mass aggregates formed in the aluminum oxide matrix, while the inner layer contains UAl4 particles as in the case of Al-10 percent U

  6. 3708 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 47, NO. 11, NOVEMBER 2009 Retrieval of Atmospheric Water Vapor Density With

    E-Print Network [OSTI]

    Reising, Steven C.

    3708 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 47, NO. 11, NOVEMBER 2009 Retrieval, remote sensing, water vapor. Manuscript received November 1, 2008; revised May 2, 2009 and August 8, 2009 the latent heat of vaporization is a principal mechanism for the transport of energy from the equatorial

  7. Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO)

    1995-01-01T23:59:59.000Z

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

  8. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20T23:59:59.000Z

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  9. Glass softening, crystallization, and vaporization of nano-aggregates of Amorphous Solid Water: Fast Scanning Calorimetry studies

    E-Print Network [OSTI]

    Deepanjan Bhattacharya; Liam OReilly; Vlad Sadtchenko

    2014-10-31T23:59:59.000Z

    Fast scanning calorimetry (FSC) was employed to investigate glass softening dynamics in amorphous solid water (ASW) nano-aggregates with thicknesses ranging from 2 to 20 nm. ASW nano-aggregates were prepared by vapor-deposition on the surface of a tungsten filament near 141 K and then heated at a rate of 100 kK/s. The resulting thermogram complex endo- and exothermal features were analyzed using a simple model. The results of the analysis show that glass softening of ASW nano-aggregates takes place at 160 K and vaporization of ASW nano-aggregates can take place at temperatures as low as 185 K. The results of these studies are discussed in conjunction with results of past studies of glass softening dynamics in water in various confining geometries.

  10. Isobaric vapor-liquid equilibria of the water + 1-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-09-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.

  11. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01T23:59:59.000Z

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This experiment relied heavily on our experiences of the 1999 experiment. Particular attention was paid to issues of radiometric calibration and radiosonde intercomparisons. Our theoretical and experimental work also supplements efforts by industry (F. Solheim, Private Communication) to develop sub-millimeter radiometers for ARM deployment. In addition to quantitative improvement of water vapor measurements at cold temperature, the impact of adding millimeter-wave window channels to improve the sensitivity to arctic clouds was studied. We also deployed an Infrared Cloud Imager (ICI) during this experiment, both for measuring continuous day-night statistics of the study of cloud coverage and identifying conditions suitable for tipcal analysis. This system provided the first capability of determining spatial cloud statistics continuously in both day and night at the NSA site and has been used to demonstrate that biases exist in inferring cloud statistics from either zenith-pointing active sensors (lidars or radars) or sky imagers that rely on scattered sunlight in daytime and star maps at night [6].

  12. Plasma Kinetics in Electrical Discharge in Mixture of Air, Water and Ethanol Vapors for Hydrogen Enriched Syngas Production

    E-Print Network [OSTI]

    Shchedrin, A I; Ryabtsev, A V; Chernyak, V Ya; Yukhymenko, V V; Olszewski, S V; Naumov, V V; Prysiazhnevych, I V; Solomenko, E V; Demchina, V P; Kudryavtsev, V S

    2008-01-01T23:59:59.000Z

    The complex theoretical and experimental investigation of plasma kinetics of the electric discharge in the mixture of air and ethanol-water vapors is carried out. The discharge was burning in the cavity, formed by air jets pumping between electrodes, placed in aqueous ethanol solution. It is found out that the hydrogen yield from the discharge is maximal in the case when ethanol and water in the solution are in equal amounts. It is shown that the hydrogen production increases with the discharge power and reaches the saturation at high value. The concentrations of the main stable gas-phase components, measured experimentally and calculated numerically, agree well in the most cases.

  13. Water injection as a means for reducing non-condensible andcorrosive gases in steam produced from vapor-dominated reservoirs

    SciTech Connect (OSTI)

    Pruess, Karsten; Spycher, Nicolas; Kneafsey, Timothy J.

    2007-01-08T23:59:59.000Z

    Large-scale water injection at The Geysers, California, hasgenerated substantial benefits in terms of sustaining reservoir pressuresand production rates, as well as improving steam composition by reducingthe content of non-condensible gases (NCGs). Two effects have beenrecognized and discussed in the literature as contributing to improvedsteam composition, (1) boiling of injectate provides a source of "clean"steam to production wells, and (2) pressurization effects induced byboiling of injected water reduce upflow of native steam with large NCGconcentrations from depth. In this paper we focus on a possibleadditional effect that could reduce NCGs in produced steam by dissolutionin a condensed aqueous phase.Boiling of injectate causes pressurizationeffects that will fairly rapidly migrate outward, away from the injectionpoint. Pressure increases will cause an increase in the saturation ofcondensed phase due to vapor adsorption on mineral surfaces, andcapillary condensation in small pores. NCGs will dissolve in theadditional condensed phase which, depending upon their solubility, mayreduce NCG concentrations in residual steam.We have analyzed thepartitioning of HCl between vapor and aqueous phases, and have performednumerical simulations of injection into superheated vapor zones. Oursimulations provide evidence that dissolution in the condensed phase canindeed reduce NCG concentrations in produced steam.

  14. A logical extension of the ASTM Standard E96 to determine the dependence of water vapor transmission on relative humidity

    SciTech Connect (OSTI)

    Lackey, J.C.; Marchand, R.G.; Kumaran, M.K. [National Research Council of Canada, Ottawa, Ontario (Canada). Inst. for Research in Construction

    1997-11-01T23:59:59.000Z

    It is well known that the water vapor transmission properties of hygroscopic building materials depend on the local relative humidities(rh). Traditionally, the ASTM Standard E96 specifies only two conditions of rh. The dry cup method in the standard corresponds to a mean rh of 25% and the wet cup to 75%. This information is not enough to describe the behavior of the material through the entire range of rh. European Standards have already proposed an extension of the existing standard to address this issue. ASTM standard should follow this change. A logical extension of the E96 standard to include the effect of rh on water vapor transmission properties has been proposed and is being discussed by one of the C16 Committee Task Groups. This paper presents the application of the proposed extension to several common building materials. The details include the operating principles of a constant temperature-rh chamber and the effects on the test results, of the vapor resistance offered by still air inside the cup, the surface resistances and buoyancy. The experimental data were used to critically assess the above effects. The data as well as the analyses of the data are expected to provide guidance to refine the existing ASTM Standard.

  15. Numerical Simulation of Hydrodynamics of a Heavy Liquid Drop Covered by Vapor Film in a Water Pool

    SciTech Connect (OSTI)

    Ma, W.M.; Yang, Z.L.; Giri, A.; Sehgal, B.R. [Royal Institute of Technology (KTH), Drottning Kristinas vaeg 33 A, 100 44, Stockholm (Sweden)

    2002-07-01T23:59:59.000Z

    A numerical study on the hydrodynamics of a droplet covered by vapor film in water pool is carried out. Two level set functions are used as to implicitly capture the interfaces among three immiscible fluids (melt-drop, vapor and coolant). This approach leaves only one set of conservation equations for the three phases. A high-order Navier-Stokes solver, called Cubic-Interpolated Pseudo-Particle (CIP) algorithm, is employed in combination with level set approach, which allows large density ratios (up to 1000), surface tension and jump in viscosity. By this calculation, the hydrodynamic behavior of a melt droplet falling into a volatile coolant is simulated, which is of great significance to reveal the mechanism of steam explosion during a hypothetical severe reactor accident. (authors)

  16. Isobaric vapor-liquid equilibria of the water + 2-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica] [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica

    1996-05-01T23:59:59.000Z

    Distillation is perhaps the separation process most widely used in the chemical processing industry. The correct design of distillation columns requires the availability of accurate and, if possible, thermodynamically consistent vapor-liquid equilibria (VLE) data. The present work is part of a project studying the effect of pressure on the behavior of the azeotropic point in mixtures in which at least one component is an alcohol. Isobaric vapor-liquid equilibria were obtained for the water + 2-propanol system at 30, 60, and 100 kPa. The activity coefficients were found to be thermodynamically consistent by the methods of Van Ness-Byer-Gibbs, Kojima, and Wisniak. The data were correlated with five liquid phase activity coefficient models (Margules, Van Laar, Wilson, NRTL, and UNIQUAC).

  17. Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water. Version 2

    SciTech Connect (OSTI)

    Dickson, A.G.; Goyet, C. [eds.] [eds.

    1994-09-01T23:59:59.000Z

    The collection of extensive, reliable, oceanic carbon data is a key component of the Joint Global Ocean Flux Study (JGOFS). A portion of the US JGOFS oceanic carbon dioxide measurements will be made during the World Ocean Circulation Experiment Hydrographic Program. A science team has been formed to plan and coordinate the various activities needed to produce high quality oceanic carbon dioxide measurements under this program. This handbook was prepared at the request of, and with the active participation of, that science team. The procedures have been agreed on by the members of the science team and describe well tested methods. They are intended to provide standard operating procedures, together with an appropriate quality control plan, for measurements made as part of this survey. These are not the only measurement techniques in use for the parameters of the oceanic carbon system; however, they do represent the current state-of-the-art for ship-board measurements. In the end, the editors hope that this handbook can serve widely as a clear and unambiguous guide to other investigators who are setting up to analyze the various parameters of the carbon dioxide system in sea water.

  18. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  19. In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Loring, John S.; Thompson, Christopher J.; Zhang, Changyong; Wang, Zheming; Schaef, Herbert T.; Rosso, Kevin M.

    2012-04-25T23:59:59.000Z

    In geologic carbon sequestration, while part of the injected carbon dioxide will dissolve into host brine, some will remain as neat to water saturated super critical CO2 (scCO2) near the well bore and at the caprock, especially in the short-term life cycle of the sequestration site. Little is known about the reactivity of minerals with scCO2 containing variable concentrations of water. In this study, we used high-pressure infrared spectroscopy to examine the carbonation of brucite (Mg(OH)2) in situ over a 24 hr reaction period with scCO2 containing water concentrations between 0% and 100% saturation, at temperatures of 35, 50, and 70 C, and at a pressure of 100 bar. Little or no detectable carbonation was observed when brucite was reacted with neat scCO2. Higher water concentrations and higher temperatures led to greater brucite carbonation rates and larger extents of conversion to magnesium carbonate products. The only observed carbonation product at 35 C was nesquehonite (MgCO3 3H2O). Mixtures of nesquehonite and magnesite (MgCO3) were detected at 50 C, but magnesite was more prevalent with increasing water concentration. Both an amorphous hydrated magnesium carbonate solid and magnesite were detected at 70 C, but magnesite predominated with increasing water concentration. The identity of the magnesium carbonate products appears strongly linked to magnesium water exchange kinetics through temperature and water availability effects.

  20. A Fixed Point Charge Model for Water Optimized to the Vapor-Liquid Coexistence Properties

    E-Print Network [OSTI]

    the temperature range of the liquid. Results were compared to the SPC, SPC/E, and MSPC/E models, vapor pressures, critical parameters, and the second virial coefficient. It is inferior to the SPC interactions. Models of this type include the Bernal-Fowler1 , ST22 , TIPS23 , TIP4P4 , SPC5 , SPC/E6

  1. Carbon dioxide and energy flux partitioning between the understorey and the overstorey of a maritime pine forest during a year with reduced soil water availability

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    during an atypical year with long-lasting reduced soil water availibility. Energy balance closure1 Carbon dioxide and energy flux partitioning between the understorey and the overstorey of a maritime pine forest during a year with reduced soil water availability Nathalie Jarosz* , Yves Brunet

  2. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)

    SciTech Connect (OSTI)

    Gaustad, KL; Turner, DD; McFarlane, SA

    2011-07-25T23:59:59.000Z

    This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

  3. Collaborative Research: The Influence of Cloud Microphysics and Radiation on the Response of Water Vapor and Clouds to Climate Change

    SciTech Connect (OSTI)

    Dr. Kerry Emanuel; Michael J. Iacono

    2011-06-28T23:59:59.000Z

    Uncertainties in representing the atmospheric water cycle are major obstacles to an accurate prediction of future climate. This project focused on addressing some of these uncertainties by implementing new physics for convection and radiation into the NCAR climate model. To better understand and eventually better represent these processes, we modified CAM3.5 to use the convection and cloud schemes developed by the Massachusetts Institute of Technology (MIT) and the RRTMG rapid radiation code for global models developed by Atmospheric and Environmental Research, Inc. (AER). The impact of the new physics on the CAM3.5 simulation of convection on diurnal and intra-seasonal scales, intra-seasonal oscillations and the distribution of water vapor has been investigated. The effect of the MIT and AER physics also has been tested in the Weather Research and Forecasting (WRF) regional forecast model. It has been found that the application of the AER radiation and MIT convection produces significant improvements in the modeled diurnal cycle of convection, especially over land, in the NCAR climate model. However, both the standard CAM3.5 (hereinafter STD) and the modified CAM3.5 with the new physics (hereinafter MOD) are still unable to capture the proper spectrum and propagating characteristics of the intra-seasonal oscillations (ISOs). The new physics methods modify, but do not substantially improve, the distribution of upper tropospheric water vapor relative to satellite measurements.

  4. Water vapor and temperature inversions near the 0 deg C level over the tropical western Pacific. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.A.

    1994-01-01T23:59:59.000Z

    During the Intensive Observation Period (IOP), several periods of water vapor and temperature inversions near the 0 deg C level were observed. Satellite and radiosonde data from TOGA COARE are used to document the large-scale conditions and thermodynamic and kinematic structures present during three extended periods in which moisture and temperature inversions near the freezing level were very pronounced. Observations from each case are synthesized into schematics which represent typical structures of the inversion phenomena. Frequency distributions of the inversion phenomena along with climatological humidity and temperature profiles are calculated for the four-month IOP.

  5. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31T23:59:59.000Z

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  6. New demands, new supplies : a national look at the water balance of carbon dioxide capture and sequestration.

    SciTech Connect (OSTI)

    Krumhansl, James Lee; McNemar, Andrea (National Energy Technology Laboratory (NETL), Morgantown, WV); Kobos, Peter Holmes; Roach, Jesse Dillon; Klise, Geoffrey Taylor

    2010-12-01T23:59:59.000Z

    Concerns over rising concentrations of greenhouse gases in the atmosphere have resulted in serious consideration of policies aimed at reduction of anthropogenic carbon dioxide (CO2) emissions. If large scale abatement efforts are undertaken, one critical tool will be geologic sequestration of CO2 captured from large point sources, specifically coal and natural gas fired power plants. Current CO2 capture technologies exact a substantial energy penalty on the source power plant, which must be offset with make-up power. Water demands increase at the source plant due to added cooling loads. In addition, new water demand is created by water requirements associated with generation of the make-up power. At the sequestration site however, saline water may be extracted to manage CO2 plum migration and pressure build up in the geologic formation. Thus, while CO2 capture creates new water demands, CO2 sequestration has the potential to create new supplies. Some or all of the added demand may be offset by treatment and use of the saline waters extracted from geologic formations during CO2 sequestration. Sandia National Laboratories, with guidance and support from the National Energy Technology Laboratory, is creating a model to evaluate the potential for a combined approach to saline formations, as a sink for CO2 and a source for saline waters that can be treated and beneficially reused to serve power plant water demands. This presentation will focus on the magnitude of added U.S. power plant water demand under different CO2 emissions reduction scenarios, and the portion of added demand that might be offset by saline waters extracted during the CO2 sequestration process.

  7. The Influence of Cloud Microphysics and Radiation on the Response of Water Vapor and Clouds to Climate Change

    SciTech Connect (OSTI)

    Emanuel, Kerry; Iacono, Michael J.

    2010-11-11T23:59:59.000Z

    Uncertainties in representing the atmospheric water cycle are major obstacles to the accurate prediction of future climate. This project focused on addressing some of these uncertainties by implementing new physics for convection and radiation into the NCAR Community Atmosphere Model (CAM). To better understand and eventually better represent these processes in this major national climate model, we modified CAM3.5 to use the convection and cloud schemes developed by the Massachusetts Institute of Technology (MIT) and the RRTMG rapid radiation code for global climate models developed by Atmospheric and Environmental Research, Inc. (AER). The impact of the new physics on the CAM3.5 simulation of convection on diurnal and intra-seasonal scales, on intra-seasonal oscillations and on the distribution of water vapor has been investigated. In addition, the MIT and AER physics packages have been incorporated and tested in combination within the Weather Research and Forecasting (WRF) regional forecast model for the purpose of evaluating and improving convective and radiative processes on time scales appropriate to weather simulations. It has been found that the application of the AER radiation and MIT convection produces significant improvements in the modeled diurnal cycle of convection, especially over land, in the NCAR climate model. However, both the standard CAM3.5 and the modified CAM3.5 with the new physics are unable to capture the proper spectrum and propagating characteristics of dynamical intra-seasonal oscillations such as the Madden-Julian Oscillation. In addition, it has been shown that the new physics methods modify, but do not substantially improve, the distribution of upper tropospheric water vapor in CAM as established through the comparison of modeled and observed satellite radiances. This suggests that continuing regional discrepancies in water vapor amounts in the climate model may not be solely related to convective or radiative processes. The major results of this project have been described in more detail in a journal article titled ??The Impacts of AER Radiation and MIT Convection on the Water Cycle Simulated by CAM3.5? that will be submitted for publication during Fall 2010.

  8. Oxidation of Slurry Aluminide Coatings on Cast Stainless Steel Alloy CF8C-Plus at 800oC in Water Vapor

    SciTech Connect (OSTI)

    Haynes, James A [ORNL; Armstrong, Beth L [ORNL; Dryepondt, Sebastien N [ORNL; Kumar, Deepak [ORNL; Zhang, Ying [Tennessee Technological University

    2013-01-01T23:59:59.000Z

    A new, cast austenitic stainless steel, CF8C-Plus, has been developed for a wide range of high temperature applications, including diesel exhaust components, turbine casings and turbocharger housings. CF8C-Plus offers significant improvements in creep rupture life and creep rupture strength over standard CF8C steel. However, at higher temperatures and in more aggressive environments, such as those containing significant water vapor, an oxidation-resistant protective coating will be necessary. The oxidation behavior of alloys CF8C and CF8C-Plus with various aluminide coatings were compared at 800oC in air plus 10 vol% water vapor. Due to their affordability, slurry aluminides were the primary coating system of interest, although chemical vapor deposition (CVD) and pack cementation coatings were also compared. Additionally, a preliminary study of the low cycle fatigue behavior of aluminized CF8C-Plus was conducted at 800oC. Each type of coating provided substantial improvements in oxidation behavior, with simple slurry aluminides showing very good oxidation resistance after 4,000 h testing in water vapor. Preliminary low cycle fatigue results indicated that thicker aluminide coatings degraded high temperature fatigue properties of CF8C-Plus, whereas thinner coatings did not. Results suggest that appropriately designed slurry aluminide coatings are a viable option for economical, long-term oxidation protection of austenitic stainless steels in water vapor.

  9. DOE/SC-ARM/TR-122 G-Band Vapor Radiometer Precipitable Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganizationElectronic Reading2Q)38232 Revision2 G-Band Vapor

  10. DOE/SC-ARM/TR-128 Tower Water-Vapor Mixing Ratio Value-Added

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganizationElectronic Reading2Q)38232 Revision2 G-Band Vapor48

  11. Analysis and forecast improvements from simulated satellite water vapor profiles and rainfall using a global data assimilation system

    SciTech Connect (OSTI)

    Nehrkorn, T.; Hoffman, R.N.; Louis, J.F.; Isaacs, R.G.; Moncet, J.L. (Atmospheric and Environmental Research, Inc., Cambridge, MA (United States))

    1993-10-01T23:59:59.000Z

    The potential improvements of analyses and forecasts from the use of satellite-observed rainfall and water vapor measurements from the Defense Meteorological Satellite Program Sensor Microwave (SSM) T-1 and T-2 instruments are investigated in a series of observing system simulation experiments using the Air Force Phillips Laboratory (formerly Air Force Geophysics Laboratory) data assimilation system. Simulated SSM radiances are used directly in a radiance retrieval step following the conventional optimum interpolation analysis. Simulated rainfall rates in the tropics are used in a moist initialization procedure to improve the initial specification of divergence, moisture, and temperature. Results show improved analyses and forecasts of relative humidity and winds compared to the control experiment in the tropics and the Southern Hemisphere. Forecast improvements are generally restricted to the first 1-3 days of the forecast. 27 refs., 11 figs.

  12. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 102, NO. D24, PAGES 29,737-29,745, DECEMBER 26, 1997 Atmospheric aerosol and water vapor characteristics over north

    E-Print Network [OSTI]

    Atmospheric aerosol and water vapor characteristics over north central Canada during BOREAS B. L. Markham, J typically0.09 and 0.34 cm, respectively.Size distributionsderivedfrom solar almucantarmeasurementsshowtheHughesSTXCorporation,Greenbelt,Maryland. 2Formerlyat HSTX/GSFC-NASA,Greenbelt,Maryland. Copyright1997by the American

  13. Interaction of wide-band-gap single crystals with 248-nm excimer laser radiation. XI. The effect of water vapor and temperature on laser desorption

    E-Print Network [OSTI]

    Dickinson, J. Thomas

    . Significantly, introducing water vapor lowers the particle velocities and thus the effective surface temperature systems, simultaneous electronic excitation and exposure to aggressive chemicals can acceler- ate etching-induced neutral particle desorption and surface erosion on single- crystal sodium chloride in the presence of low

  14. Multimodel Predictive System for Carbon Dioxide Solubility in Saline Formation Waters

    SciTech Connect (OSTI)

    Wang, Zan; Small, Mitchell J.; Karamalidis, Athanasios K.

    2013-02-05T23:59:59.000Z

    The prediction of carbon dioxide solubility in brine at conditions relevant to carbon sequestration (i.e., high temperature, pressure, and salt concentration (T-P-X)) is crucial when this technology is applied. Eleven mathematical models for predicting CO{sub 2} solubility in brine are compared and considered for inclusion in a multimodel predictive system. Model goodness of fit is evaluated over the temperature range 304433 K, pressure range 74500 bar, and salt concentration range 07 m (NaCl equivalent), using 173 published CO{sub 2} solubility measurements, particularly selected for those conditions. The performance of each model is assessed using various statistical methods, including the Akaike Information Criterion (AIC) and the Bayesian Information Criterion (BIC). Different models emerge as best fits for different subranges of the input conditions. A classification tree is generated using machine learning methods to predict the best-performing model under different T-P-X subranges, allowing development of a multimodel predictive system (MMoPS) that selects and applies the model expected to yield the most accurate CO{sub 2} solubility prediction. Statistical analysis of the MMoPS predictions, including a stratified 5-fold cross validation, shows that MMoPS outperforms each individual model and increases the overall accuracy of CO{sub 2} solubility prediction across the range of T-P-X conditions likely to be encountered in carbon sequestration applications.

  15. Ocean Water Vapor and Cloud Burden Trends Derived from the Topex Microwave Radiometer

    E-Print Network [OSTI]

    Ruf, Christopher

    algorithm is a log-linear regression algorithm with coefficients that are stratified by wind speed and water. TMR OBSERVATIONS The TMR flew in a 10-day non-sun-synchronous exact repeat orbit with an inclination

  16. Green chemistry : dense carbon dioxide and water as environmentally benign reaction media

    E-Print Network [OSTI]

    Allen, Andrew J. (Andrew John), 1978-

    2004-01-01T23:59:59.000Z

    (cont.) was investigated in scCO?, and the cycloaddition between cyclopentadiene and methyl vinyl ketone (MVK) was studied in an scCO?/liquid water environment. Nitrogen chemistry, specifically the synthesis of nitrogen ...

  17. Isobaric vapor-liquid equilibria for binary and ternary systems composed of water, 1-propanol, and 2-propanol at 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-11-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria data were obtained for the 2-propanol + 1-propanol binary system and the water + 1-propanol + 2-propanol ternary system at 100 kPa. The data were found to be thermodynamically consistent according to the Van Ness-Byer-Gibbs method for the binary system and according to the McDermott-Ellis method for the ternary one. The binary system is well represented by assuming ideal behavior. The binary interaction parameters obtained from this and previous work are used to predict the vapor-liquid equilibrium for the ternary system using the UNIQUAC, NRTL, and Wilson models. The ternary system is well predicted from binary data.

  18. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, Kenneth G. (Charleston, WV)

    1990-01-01T23:59:59.000Z

    A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  19. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, K.G.

    1990-02-20T23:59:59.000Z

    A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  20. Intraparticle heat and mass transfer characteristics of silica-gel/water vapor adsorption

    SciTech Connect (OSTI)

    Yamamoto, Eri; Watanabe, Fujio; Hasatani, Masanobu

    1999-07-01T23:59:59.000Z

    Recently, highly efficient energy utilization systems which extensively employ adsorption phenomena such as pressure swing adsorption, heat storage, adsorption heat pump, etc. are being regarded as one of the countermeasures for environmental issues such as green house effect and ozone layer destruction. An Adsorption Heat Pump (AHP) has been investigated as one of the important techniques via which cold heat energy is obtained from waste thermal energy below 373K without using electricity and CFCs. An AHP normally consists of an adsorber and an evaporator/condenser and cold heat energy is generated by latent heat of evaporation during adsorption process. For realizing the AHP technology, it has been pointed out that the development of an adsorber with optimum heat and mass transfer characteristics is essentially important. In this study, experimental studies were carried out which was based on the data of temperature inside the adsorbent particle and adsorptivity profiles at the adsorption/desorption process by volumetric method. To clarify adsorption mechanism relatively large silica-gel particle (7 mm f) was used. Temperature distribution in the particle is determined at the center, at one half radius in the radial direction and at the surface by using very thin (30 mm f) thermocouples. The temperatures at these points simultaneously increase/decrease as soon as the adsorption/desorption started, reached their respective maximum/minimum values and then return to initial temperature. The temperature profiles for the adsorption process show that the temperature at the surface is initially slightly higher than the other two points. All three points reached their respective maximum temperature at the same time with the temperature at the center point the highest and at the surface the lowest. The temperature profiles during the desorptive process are almost exactly the opposite to that of the adsorption process. This shows that the adsorption phenomena can take place not only at the surface but inside the adsorbent particle, implying that intraparticle vapor diffusion has a great influence on adsorptivity.

  1. Extremely Luminous Water Vapor Emission from a Type 2 Quasar at Redshift z = 0.66

    E-Print Network [OSTI]

    Richard Barvainis; Robert Antonucci

    2005-06-10T23:59:59.000Z

    A search for water masers in 47 Sloan Digital Sky Survey Type 2 quasars using the Green Bank Telescope has yielded a detection at a redshift of z = 0.660. This maser is more than an order of magnitude higher in redshift than any previously known and, with a total isotropic luminosity of 23,000 L_sun, also the most powerful. The presence and detectability of water masers in quasars at z ~ 0.3-0.8 may provide a better understanding of quasar molecular tori and disks, as well as fundamental quasar and galaxy properties such as black hole masses. Water masers at cosmologically interesting distances may also eventually provide, via direct distance determinations, a new cosmological observable for testing the reality and properties of dark energy, currently inferred primarily through Type 1a supernova measurements.

  2. Hydrogen Ingress in Steels During High-Temperature Oxidation in Water Vapor

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Fayek, Mostafa [ORNL; Keiser, James R [ORNL; Meyer III, Harry M [ORNL; More, Karren Leslie [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL

    2011-01-01T23:59:59.000Z

    It is well established that hydrogen derived from water vapour can penetrate oxidizing alloys with detrimental effect. However, the complexities of tracking hydrogen in these materials have prevented the direct profiling of hydrogen ingress needed to understand these phenomena. Here we report hydrogen profiles in industrially-relevant alumina- and chromia- forming steels correlated with the local oxide-metal nano/microstructure by use of SIMS D2O tracer studies and experimental protocols to optimize D retention. The D profiles unexpectedly varied markedly among the alloys examined, which indicates mechanistic complexity but also the potential to mitigate detrimental water vapour effects by manipulation of alloy chemistry.

  3. Wavelength-modulation laser hygrometer for ultrasensitive detection of water vapor in

    E-Print Network [OSTI]

    - bines wavelength-modulation absorption spectros- copy WMS 12­16 that uses near-infrared InGaAsP diode is measured by use of a near-infrared diode laser and wavelength-modulation absorption spectroscopy. Humidity in the spectral regions of strongest water absorption. Sensitive single-mode cavity ring-down techniques based

  4. Microemulsions of water in supercritical carbon dioxide : an in-situ NMR investigation of micelle formation and structure.

    SciTech Connect (OSTI)

    Fremgen, D. E.; Smotkin, E. S.; Gerald, R. E.; Klingler, R. J.; Rathke, J. W.; Chemical Engineering; IIT

    2001-04-01T23:59:59.000Z

    High-pressure NMR spectroscopy was used for the first time to investigate microemulsions of water in supercritical carbon dioxide. The emulsions were formed using a family of anionic perfluoropolyether ammonium carboxylate surfactants. This system holds promise as a reaction medium for conducting homogeneous catalytic reactions within the aqueous micellular cores while, at the same time, exploiting the facile mass transfer properties of the supercritical fluid. Ammonium hexafluorophosphate was used as a water-soluble ionic guest to investigate micelle formation and structure. Under micelle-forming conditions, the PF{sub 6}{sup -} guest, surfactant, and water were uniformly dispersed throughout the CO{sub 2} phase, as demonstrated by in situ NMR imaging. In addition, the micelles were observed to form even in the absence of mechanical stirring. This spontaneous formation of micelles demonstrates that the NMR spectral properties were obtained under conditions that result in the production of thermodynamically stable microemulsions. The nuclear overhauser effect (NOE) was used to probe the micellular structure through dipole-dipole interactions between the PF{sub 6}{sup -} anion and the fluorinated backbone of the surfactant. A strong negative homonuclear NoE was observed between the PF{sub 6}{sup -} guest and the fluorine moiety that is located directly adjacent to the surfactant's carboxylate head group. This highly specific negative NOE indicates an ordered arrangement, where the PF{sub 6}{sup -} anion and carboxylate ion are located in close proximity to one another. This close association of two negatively charged ionic groups in an aqueous environment is unusual and suggests that the PF{sub 6}{sup -} guest is concentrated within the electric double layer that forms at the micellular interface.

  5. Development of High Efficiency Carbon Dioxide Commercial Heat Pump Water Heater

    SciTech Connect (OSTI)

    Michael PETERSEN; Chad D. BOWERS; Stefan ELBEL; Pega HRNJAK

    2012-07-01T23:59:59.000Z

    Although heat pump water heaters are today widely accepted in both Japan and Europe, where energy costs are high and government incentives for their use exist, acceptance of such products in the US has been limited. While this trend is slowly changing with the introduction of heat pump water heaters into the residential market, but acceptance remains low in the commercial sector. The objective of the presented work is the development of a high efficiency R744 heat pump water heater for commercial applications with effective utilization of the cooling capability for air conditioning and/or refrigeration. The ultimate goal is to achieve total system COP of up to 8. This unit will be targeted at commercial use where some cooling load is typically needed year round, such as restaurants, hotels, nursing homes, and hospitals. This paper presents the performance results from the development of four R744 commercial heat pump water heater packages of approximately 35 kW and comparison to a commercially available baseline R134a unit of the same capacity and footprint. In addition, the influences of an internal heat exchanger and an enhanced evaporator on the system performance are described and recommendations are made for further improvements of the R744 system.

  6. Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture preservation of the IRMOF structure. Carbon dioxide capture from combustion sources such as flue gas in power this carbon capture challenge. The preferred method for measuring the efficiency of a given material

  7. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01T23:59:59.000Z

    liquid/vapor interface of SPC/E water. J. Phys. Chem. 100,dioxide mixtures described by the SPC/E and EPM2 models. (and water oxygen is denoted by O SPC/E and O TIP for SPC/E (

  8. Improved Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348 270 300 219 255Retrievals of Temperature and Water

  9. Turn-key Raman lidar for profiling atmospheric water vapor, clouds, and aerosols at the US Southern Great Plains Climate Study Site

    SciTech Connect (OSTI)

    Goldsmith, J.E.M.; Blair, F.H.; Bisson, S.E.

    1997-12-31T23:59:59.000Z

    There are clearly identified scientific requirements for continuous profiling of atmospheric water vapor at the Department of Energy, Atmospheric Radiation Measurement program, Southern Great Plains CART (Cloud and Radiation Testbed) site in northern Oklahoma. Research conducted at several laboratories has demonstrated the suitability of Raman lidar for providing measurements that are an excellent match to those requirements. We have developed and installed a ruggedized Raman lidar system that resides permanently at the CART site, and that is computer automated to eliminate the requirements for operator interaction. In addition to the design goal of profiling water vapor through most of the troposphere during nighttime and through the boundary layer during daytime, the lidar provides quantitative characterizations of aerosols and clouds, including depolarization measurements for particle phase studies.

  10. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Tortorelli, Peter F [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  11. Measurements of heat and mass transfer coefficients during absorption of water vapor by lithium bromide and (Li,K,Na)NO sub 3 mixtures

    SciTech Connect (OSTI)

    Zaltash, A.; Ally, M.R.; Linkous, R.L.; Klatt, L.N.

    1991-01-01T23:59:59.000Z

    A knowledge of heat and mass transfer coefficients in heat pump fluids, plays an important role in the design of absorption machines. Heat and mass transfer coefficients as well as subcooling are measured for absorption of water vapor in (Li, K, Na)No{sub 3} and Lithium Bromide (LiBr) mixtures.The rate of absorption of water vapor is obtained from the difference in concentration of mixtures between inlet and outlet streams across the absorber. In situ concentrations of aqueous salt mixtures over temperature ranges between 80 to 135 {degrees}C were calculated from density measurements. This technique of measurement is a reliable and convenient but not a very accurate ({plus minus}0.8 wt% salt) method of measuring the in situ salt concentration. Results show that the subcooling at the absorber exit is not only a property of the fluid, but depends strongly on the process conditions. The subcooling in LiBr mixtures without additive is shown to vary between 2.2 and 24.3 {degrees}C and the film heat transfer coefficient between 1365.2 and 801.1 W/m{sup 2}.K respectively, depending upon process conditions. These empirical results will prove to be of value to heat pump manufacturers because they have a strong bearing on costs and performance. Heat and mass transfer coefficients in aqueous salt solutions ate presented as a function of dimensionless numbers. 12 refs., 3 figs., 4 tabs.

  12. Reaction of titanium polonides with carbon dioxide

    SciTech Connect (OSTI)

    Abakumov, A.S.; Malyshev, M.L.; Reznikova, N.F.

    1987-05-01T23:59:59.000Z

    It has been ascertained that heating titanium and tantalum in carbon dioxide to temperatures of 500 or 800/sup 0/C alters the composition of the gas phase, causing the advent of carbon monoxide and lowering the oxygen content. Investigation of the thermal stability of titanium polonides in a carbon dioxide medium has shown that titanium mono- and hemipolonides are decomposed at temperatures below 350/sup 0/C. The temperature dependence of the vapor pressure of polonium produced in the decomposition of these polonides in a carbon dioxide medium have been determined by a radiotensimetric method. The enthalpy of the process, calculated from this relationship, is close to the enthalpy of vaporization of elementary polonium in vacuo.

  13. Field Study of Exhaust Fans for Mitigating Indoor Air Quality Problems: Final Report to Bonneville Power Administration

    E-Print Network [OSTI]

    Grimsrud, David T.

    2009-01-01T23:59:59.000Z

    Nitrogen dioxide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .in each house. Nitrogen dioxide concentrations in each housesampler Formaldehyde, nitrogen dioxide and water vapor

  14. Advanced Proliferation Resistant, Lower Cost, Uranium-Thorium Dioxide Fuels for Light Water Reactors (Progress report for work through June 2002, 12th quarterly report)

    SciTech Connect (OSTI)

    Mac Donald, Philip Elsworth

    2002-09-01T23:59:59.000Z

    The overall objective of this NERI project is to evaluate the potential advantages and disadvantages of an optimized thorium-uranium dioxide (ThO2/UO2) fuel design for light water reactors (LWRs). The project is led by the Idaho National Engineering and Environmental Laboratory (INEEL), with the collaboration of three universities, the University of Florida, Massachusetts Institute of Technology (MIT), and Purdue University; Argonne National Laboratory; and all of the Pressurized Water Reactor (PWR) fuel vendors in the United States (Framatome, Siemens, and Westinghouse). In addition, a number of researchers at the Korean Atomic Energy Research Institute and Professor Kwangheon Park at Kyunghee University are active collaborators with Korean Ministry of Science and Technology funding. The project has been organized into five tasks: Task 1 consists of fuel cycle neutronics and economics analysis to determine the economic viability of various ThO2/UO2 fuel designs in PWRs, Task 2 will determine whether or not ThO2/UO2 fuel can be manufactured economically, Task 3 will evaluate the behavior of ThO2/UO2 fuel during normal, off-normal, and accident conditions and compare the results with the results of previous UO2 fuel evaluations and U.S. Nuclear Regulatory Commission (NRC) licensing standards, Task 4 will determine the long-term stability of ThO2/UO2 high-level waste, and Task 5 consists of the Korean work on core design, fuel performance analysis, and xenon diffusivity measurements.

  15. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    P. C. Myint; Y. Hao; A. Firoozabadi

    2015-04-20T23:59:59.000Z

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun's model yields accurate results for the partial molar enthalpy of CO$_2$. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H$_2$O-CO$_2$-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  16. Effect of paraffinic, naphthenic and aromatic distribution in the hydrocarbon mixture and water on the phase equilibria of carbon dioxide-hydrocarbon systems over the temperature range from 333 K to 366 K

    SciTech Connect (OSTI)

    Ezekwe, J.N.

    1982-01-01T23:59:59.000Z

    Carbon dioxide flooding has been suggested as an efficient and effective means of achieving additional oil recoveries from depleted and/or water flooded reservoirs. The numerical simulation of a carbon dioxide flood requires a phase equilibria predictor that will provide the compositional distribution of the reservoir fluids as the displacement propagates through the reservoir. The objective of this work was to provide a phase equilibria predictor that utilizes the Soave-Redlich-Kwong (SRK) equation of state. A new PUT apparatus was constructed. This apparatus was used to measure the isothermal P-x data of the systems: CO/sub 2/-toluene, CO/sub 2/-ethylbenzene, CO/sub 2/-propylbenzene, CO/sub 2/-cyclopentane, CO/sub 2/-cyclohexane and CO/sub 2/-methylcyclohexane at 333.15 K, 349.82 K and 366.48 K. Interaction parameters were regressed from literature data for CO/sub 2/-paraffin systems and from the experimental data of this work for CO/sub 2/-aromatic and CO/sub 2/-naphthenic systems. Recommended interaction parameters for these systems are provided. Experimental results indicated that the dominant effect of water on CO/sub 2/-hydrocarbon systems was the solubilization of carbon dioxide by water into the aqueous phase. This concept was simulated with the SRK equation of state and a correlation of literature data on the solubility of carbon dioxide in water. The predicted results agreed well with the experimental results. The presence of dissolved salts in water mitigates the effect of water on CO/sub 2/-hydrocarbon systems. The presence on n-butylbenzene or n-butylcylcohexane in the heavy ends with n-decane improved the maximum miscibility composition of the system. Pressure has a substantial effect on maximum miscibility compositions.

  17. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23T23:59:59.000Z

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  18. E-Print Network 3.0 - acute sulphur dioxide Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acetone Concentrated nitric and sulphuric acid mixtures Alkali and alkaline Water, carbon tetrachloride... & other chlorinated earth metals hydrocarbons, carbon dioxide,...

  19. A study of the effect of added carbon dioxide and water on the recovery of oil by in situ combustion

    E-Print Network [OSTI]

    Zahiruddin, Mohammed

    2012-06-07T23:59:59.000Z

    3 4 5 6 7 8 9 10 11 12 Time, Hours FIGURE 7. PRODUCED GAS RATE FOR RUN 3 0 1 2 3 4 5 6 7 8 9 10 11 12 Time, Hours FIGURE 8. PRODUCED GAS RATE FOR RUN 4 C N3 6 0 0 '~2 M I I I I I I I I I I Start of[ Water I Inj ection~, 1. 85... DISTRIBUTIONS DURING RUN 1 4&Xi 10 M ~17 r~n6 15 7 2. 38 8o o 4N (d 2 14 0 4 8 12 16 20 24 28 32 36 Distance, Inches FIGURE 15, PRESSURE AND TEMPERATURE DISTRIBUTIONS DURING RUN 2 2. 200 190 ~180 7. 64 hrs. 3. 71 hrs. 3. 71 hrs. 7. 64 hrs...

  20. Rapid Migration of Radionuclides Leaked from High-Level Water Tanks; A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport

    SciTech Connect (OSTI)

    Anderson l. Ward; Glendon W. Gee; John S. Selker; Clay Cooper

    2002-04-24T23:59:59.000Z

    The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts atypical of low ionic strength infiltration. In the field, this mechanism could for ce flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contract angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tens ion of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of this waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediments. Th e released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

  1. Rapid Migration of Radionuclides Leaked from High-Level Water Tanks: A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport

    SciTech Connect (OSTI)

    Anderson L. Ward; Glendon W. Gee; John S. Selker; Caly Cooper

    2002-04-24T23:59:59.000Z

    The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts a typical of low ionic strength infiltration. In the field, this mechanism could force flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contact angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tension of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests of showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of the waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediment s. The released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

  2. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-10-01T23:59:59.000Z

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport reactor systems is planned to demonstrate the feasibility of this process in large scale operations to separate carbon dioxide from flue gas.

  3. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26T23:59:59.000Z

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  4. DOUBLE SHELL TANK (DST) HYDROXIDE DEPLETION MODEL FOR CARBON DIOXIDE ABSORPTION

    SciTech Connect (OSTI)

    OGDEN DM; KIRCH NW

    2007-10-31T23:59:59.000Z

    This document generates a supernatant hydroxide ion depletion model based on mechanistic principles. The carbon dioxide absorption mechanistic model is developed in this report. The report also benchmarks the model against historical tank supernatant hydroxide data and vapor space carbon dioxide data. A comparison of the newly generated mechanistic model with previously applied empirical hydroxide depletion equations is also performed.

  5. On the Diurnal Cycle of Deep Convection, High-Level Cloud, and Upper Troposphere Water Vapor in the Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Yunyan; Klein, Stephen A.; Liu, Chuntao; Tian, Baijun; Marchand, Roger T.; Haynes, J. M.; McCoy, Renata; Zhang, Yuying; Ackerman, Thomas P.

    2008-08-22T23:59:59.000Z

    The Multiscale Modeling Framework (MMF), also called superparameterization, embeds a cloud-resolving model (CRM) at each grid column of a general circulation model to replace traditional parameterizations of moist convection and large-scale condensation. This study evaluates the diurnal cycle of deep convection, high-level clouds, and upper troposphere water vapor by applying an infrared (IR) brightness temperature (Tb) and a precipitation radar (PR) simulator to the CRM column data. Simulator results are then compared with IR radiances from geostationary satellites and PR reflectivities from the Tropical Rainfall Measuring Mission (TRMM). While the actual surface precipitation rate in the MMF has a reasonable diurnal phase and amplitude when compared with TRMM observations, the IR simulator results indicate an inconsistency in the diurnal anomalies of high-level clouds between the model and the geostationary satellite data. Primarily because of its excessive high-level clouds, the MMF overestimates the simulated precipitation index (PI) and fails to reproduce the observed diurnal cycle phase relationships among PI, high-level clouds, and upper troposphere relative humidity. The PR simulator results show that over the tropical oceans, the occurrence fraction of reflectivity in excess of 20 dBZ is almost 1 order of magnitude larger than the TRMM data especially at altitudes above 6 km. Both results suggest that the MMF oceanic convection is overactive and possible reasons for this bias are discussed. However, the joint distribution of simulated IR Tb and PR reflectivity indicates that the most intense deep convection is found more often over tropical land than ocean, in agreement with previous observational studies.

  6. Nitrogen dioxide detection

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

    1993-01-01T23:59:59.000Z

    Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

  7. Uranium dioxide electrolysis

    DOE Patents [OSTI]

    Willit, James L. (Batavia, IL); Ackerman, John P. (Prescott, AZ); Williamson, Mark A. (Naperville, IL)

    2009-12-29T23:59:59.000Z

    This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

  8. Thorium dioxide: properties and nuclear applications

    SciTech Connect (OSTI)

    Belle, J.; Berman, R.M. (eds.)

    1984-01-01T23:59:59.000Z

    This is the sixth book on reactor materials published under sponsorship of the Naval Reactors Office of the United States Department of Energy, formerly the United States Atomic Energy Commission. This book presents a comprehensive compilation of the most significant properties of thorium dioxide, much like the book Uranium Dioxide: Properties and Nuclear Applications presented information on the fuel material used in the Shippingport Pressurized Water Reactor core.

  9. Warm water vapor envelope in the supergiants alf Ori and alf Her and its effects on the apparent size from the near-infrared to the mid-infrared

    E-Print Network [OSTI]

    Keiichi Ohnaka

    2004-06-02T23:59:59.000Z

    We present a possible interpretation for the increase of the angular diameter of the supergiants alf Ori (M1-2 Ia-Ibe) and alf Her (M5 Ib-II) from the K band to the 11 micron region and the high-resolution 11 micron spectra without any salient spectral features revealed by Weiner et al. (2003). The angular diameters as well as the high-resolution spectra of alf Ori and alf Her obtained in the 11 micron region can be reproduced by a warm water vapor envelope, whose presence in alf Ori was revealed by Tsuji (2000) based on the reanalysis of the near-infrared data obtained with the Stratoscope II. While prominent absorption due to H2O can be expected from such a dense, warm water vapor envelope, the absorption lines can be filled in by emission from the extended part of the envelope. This effect leads to a significant weakening of the H2O lines in the 11 micron region, and makes the observed spectra appear to be rather featureless and continuum-like. However, the emission due to H2O lines from the extended envelope leads to an increase of the apparent size in this spectral region. The observed angular diameter and the high resolution spectra of alf Ori and alf Her in the 11 micron region can be best interpreted by the water vapor envelope extending to 1.4--1.5 Rstar, with a temperature of about 2000 K and a column density of H2O of the order of 10^20 cm^-2.

  10. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

    2010-11-09T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  11. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2014-08-19T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  12. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    and MSF, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas...

  13. What's Next for Vanadium Dioxide?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

  14. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30T23:59:59.000Z

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  15. Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen in the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen the mole fraction of CO2 in the carbon dioxide + nitrogen + cyclopentane mixed hydrate phase, both defined;2 {water +carbon dioxide + nitrogen}, the equilibrium pressure of the mixed hydrate is reduced by 0.95 up

  16. E-Print Network 3.0 - acid vapor pressures Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 22 3b. Thermodynamics of moist air Water phase, water latent heat of vaporization Lv Summary: 3b. Thermodynamics of moist air Water phase, water latent...

  17. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  18. E-Print Network 3.0 - absorbing sulfur dioxide Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

  19. E-Print Network 3.0 - ambient sulfur dioxide Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

  20. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  1. Sulfur Dioxide Regulations (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

  2. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18T23:59:59.000Z

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  3. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

    1992-01-01T23:59:59.000Z

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

  4. Basic Engineering Research for D and D of R Reactor Storage Pond Sludge: Electrokinetics, Carbon Dioxide Extraction, and Supercritical Water Oxidation

    SciTech Connect (OSTI)

    Michael A. Matthews; David A. Bruce,; Thomas A. Davis; Mark C. Thies; John W. Weidner; Ralph E. White

    2002-04-01T23:59:59.000Z

    Large quantities of mixed low level waste (MLLW) that fall under the Toxic Substances Control Act (TSCA) exist and will continue to be generated during D and D operations at DOE sites across the country. The standard process for destruction of MLLW is incineration, which has an uncertain future. The extraction and destruction of PCBs from MLLW was the subject of this research Supercritical Fluid Extraction (SFE) with carbon dioxide with 5% ethanol as cosolvent and Supercritical Waster Oxidation (SCWO) were the processes studied in depth. The solid matrix for experimental extraction studies was Toxi-dry, a commonly used absorbent made from plant material. PCB surrogates were 1.2,4-trichlorobenzene (TCB) and 2-chlorobiphenyl (2CBP). Extraction pressures of 2,000 and 4,000 psi and temperatures of 40 and 80 C were studied. Higher extraction efficiencies were observed with cosolvent and at high temperature, but pressure little effect. SCWO treatment of the treatment of the PCB surrogates resulted in their destruction below detection limits.

  5. Project Profile: Direct Supercritical Carbon Dioxide Receiver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The National...

  6. Gasoline vapor recovery

    SciTech Connect (OSTI)

    Lievens, G.; Tiberi, T.P.

    1993-06-22T23:59:59.000Z

    In a gasoline distribution network wherein gasoline is drawn from a gasoline storage tank and pumped into individual vehicles and wherein the gasoline storage tank is refilled periodically from a gasoline tanker truck, a method of recovering liquid gasoline from gasoline vapor that collects in the headspace of the gasoline storage tank as the liquid gasoline is drawn therefrom, said method comprising the steps of: (a) providing a source of inert gas; (b) introducing inert gas into the gasoline storage tank as liquid gasoline is drawn therefrom so that liquid gasoline drawn from the tank is displaced by inert gas and gasoline vapor mixes with the inert gas in the headspace of the tank; (c) collecting the inert gas/gasoline vapor mixture from the headspace of the gasoline storage tank as the tank is refilled from a gasoline tanker truck; (d) cooling the inert gas/gasoline vapor mixture to a temperature sufficient to condense the gasoline vapor in the mixture to liquid gasoline but not sufficient to liquify the inert gas in the mixture; (e) separating the condensed liquid gasoline from the inert gas; and delivering the condensed liquid gasoline to a remote location for subsequent use.

  7. Capture of carbon dioxide by hybrid sorption

    DOE Patents [OSTI]

    Srinivasachar, Srivats

    2014-09-23T23:59:59.000Z

    A composition, process and system for capturing carbon dioxide from a combustion gas stream. The composition has a particulate porous support medium that has a high volume of pores, an alkaline component distributed within the pores and on the surface of the support medium, and water adsorbed on the alkaline component, wherein the proportion of water in the composition is between about 5% and about 35% by weight of the composition. The process and system contemplates contacting the sorbent and the flowing gas stream together at a temperature and for a time such that some water remains adsorbed in the alkaline component when the contact of the sorbent with the flowing gas ceases.

  8. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Arkansas (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01T23:59:59.000Z

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Arkansas. We forecast the cumulative economic benefits from 1000 MW of development in Arkansas to be $1.15 billion, annual CO2 reductions are estimated at 2.7 million tons, and annual water savings are 1,507 million gallons.

  9. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08T23:59:59.000Z

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  10. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

    1983-01-01T23:59:59.000Z

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

  11. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  12. CARBON DIOXIDE EMISSION REDUCTION

    E-Print Network [OSTI]

    Delaware, University of

    .5 Primary Energy Use and Carbon Dioxide Emissions for Selected US Chemical Subsectors in 1994 ...............................................................................................................16 Table 2.7 1999 Energy Consumption and Specific Energy Consumption (SEC) in the U.S. Cement Efficiency Technologies and Measures in Cement Industry.................22 Table 2.9 Energy Consumption

  13. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  14. Water-vapor effect on the electrical conductivity of a single-walled carbon nanotube mat A. Zahab,* L. Spina, and P. Poncharal

    E-Print Network [OSTI]

    Demouchy, Sylvie

    of physico-chemical adsorption of gases in nanotubes have been reported.11­14 One of the most excit- ing was then carefully out- gassed by heating the sample up to 220 °C at a constant rate of about 3 °C/mn. The sample lower than 0.1 °C during water injection and pumping cycle was negli- gible when compared

  15. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in West Virginia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in West Virginia. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in West Virginia to be $1.0 billion, annual CO2 reductions are estimated at 3.3 million tons, and annual water savings are 1,763 million gallons.

  16. Temperature dependent vapor pressures of chlorinated catechols, syringols, and syringaldehydes

    SciTech Connect (OSTI)

    Lei, Y.D.; Shiu, W.Y.; Boocock, D.G.B. [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry] [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry; Wania, F. [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)] [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)

    1999-03-01T23:59:59.000Z

    The vapor pressures of nine chlorinated catechols, syringols, and syringaldehydes were determined as a function of temperature with a gas chromatographic retention time technique. The vapor pressures at 298.15 K were in the range of 0.02--1 Pa, and the enthalpies of vaporization, between 68 and 82 kJ/mol. The validity of the technique was established by a calibration involving four chlorinated phenols with well-known vapor pressures. Using these data and previously reported solubility data, Henry`s law constants for these substances and some chlorinated guaiacols and veratrols were estimated. The vapor pressure of these substances tends to decrease with increasing polarity and an increasing number of chlorine atoms. Henry`s law constants decrease sharply with increasing polarity, suggesting that methylation can result in a significant increase in a chemical`s potential for volatilization from water.

  17. Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource ProgramModification andinterface of water.OrganicNov 4 5

  18. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23T23:59:59.000Z

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  19. Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects

    E-Print Network [OSTI]

    Chickos, James S.

    * Department of Chemistry and Biochemistry, University of MissourisSt. Louis, St. Louis, Missouri 63121 Liquid vapor pressure isotope effects have generally been observed, pD > pH.12 Vapor pressure and sublimation

  20. Vapor space characterization of waste Tank 241-BY-108: Results from samples collected on 10/27/94

    SciTech Connect (OSTI)

    McVeety, B.D.; Clauss, T.W.; Ligotke, M.W. [and others

    1995-10-01T23:59:59.000Z

    This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-BY-108 (referred to as Tank BY-108). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), and water vapor (H{sub 2}O). Trends in NH{sub 3} and H{sub 2}O samples indicated a possible sampling problem. Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO{sub x}) was not requested. In addition, the authors looked for the 40 TO-14 compounds plus an additional 15 analytes. Of these, 17 were observed above the 5-ppbv reporting cutoff. Also, eighty-one organic tentatively identified compounds (TICs) were observed above the reporting cutoff (ca.) 10 ppbv, and are reported with concentrations that are semiquantitative estimates based on internal standard response factors. The nine organic analytes with the highest estimated concentrations are listed in Summary Table 1 and account for approximately 48% of the total organic components in the headspace of Tank BY-108. Three permanent gases, hydrogen (H{sub 2}), carbon dioxide (CO{sub 2}), and nitrous oxide (N{sub 2}O) were also detected. Tank BY-108 is on the Ferrocyanide Watch List.

  1. Vapor space characterization of waste Tank 241-TY-101: Results from samples collected on 4/6/95

    SciTech Connect (OSTI)

    Klinger, G.S.; Clauss, T.W.; Ligotke, M.W.; Pool, K.H.; McVeety, B.D.; Olsen, K.B.; Bredt, O.P.; Fruchter, J.S.; Goheen, S.C.

    1995-11-01T23:59:59.000Z

    This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-TY-101 (referred to as Tank TY-101). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), and water vapor (H{sub 2}O). Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO{sub x}) was not requested. In addition, quantitative results were obtained for the 39 TO-14 compounds plus an additional 14 analytes. Off these, 5 were observed above the 5-ppbv reporting cutoff. One tentatively identified compound (TIC) was observed above the reporting cutoff of (ca.) 10 ppbv and are reported with concentrations that are semiquantitative estimates based on internal-standard response factors. The six organic analyses identified are listed in Table 1 and account for approximately 100% of the total organic components in Tank TY-101. Two permanent gases, carbon dioxide (CO{sub 2}) and nitrous oxide (N{sub 2}O), were also detected. Tank TY-101 is on the Ferrocyanide Watch List.

  2. Vapor space characterization of waste Tank 241-C-107: Results from samples collected on 9/29/94

    SciTech Connect (OSTI)

    Pool, K.H.; Clauss, T.W.; Ligotke, M.W. [and others

    1995-11-01T23:59:59.000Z

    This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-C-107 (referred to as Tank C-107). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), and water vapor (H{sub 2}O). Sampling for sulfur oxides (SO{sub x}) was not requested. Organic compounds were also quantitatively determined. Twenty organic tentatively identified compounds (TICs) were observed above the detection limit of (ca.) 10 ppbv, but standards for most of these were not available at the time of analysis, and the reported concentrations are semiquantitative estimates. In addition, the authors looked for the 55 TO-14 extended analytes. Of these, 3 were observed above the 5-ppbv detection limit. The 10 organic analytes with the highest estimated concentrations are listed in Summary Table 1 and account for approximately 96% of the total organic components in Tank C-107. Two permanent gases, carbon dioxide and nitrous oxide, were also detected.

  3. Vapor-phase heat-transport system

    SciTech Connect (OSTI)

    Hedstrom, J.C.

    1983-01-01T23:59:59.000Z

    A vapor-phase heat-transport system is being tested in one of the passive test cells at Los Alamos. The system consists of one selective-surface collector and a condenser inside a water storage tank. The refrigerant, R-11, can be returned to the collector by gravity or with a pump. Results from several operating configurations are presented, together with a comparison with other passive systems. A new self-pumping concept is presented.

  4. CARBON DIOXIDE FIXATION.

    SciTech Connect (OSTI)

    FUJITA,E.

    2000-01-12T23:59:59.000Z

    Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

  5. Estimated Carbon Dioxide Emissions in 2008: United States

    SciTech Connect (OSTI)

    Smith, C A; Simon, A J; Belles, R D

    2011-04-01T23:59:59.000Z

    Flow charts depicting carbon dioxide emissions in the United States have been constructed from publicly available data and estimates of state-level energy use patterns. Approximately 5,800 million metric tons of carbon dioxide were emitted throughout the United States for use in power production, residential, commercial, industrial, and transportation applications in 2008. Carbon dioxide is emitted from the use of three major energy resources: natural gas, coal, and petroleum. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states, the District of Columbia, and one national) carbon dioxide flow charts representing a comprehensive systems view of national CO{sub 2} emissions. Lawrence Livermore National Lab (LLNL) has published flow charts (also referred to as 'Sankey Diagrams') of important national commodities since the early 1970s. The most widely recognized of these charts is the U.S. energy flow chart (http://flowcharts.llnl.gov). LLNL has also published charts depicting carbon (or carbon dioxide potential) flow and water flow at the national level as well as energy, carbon, and water flows at the international, state, municipal, and organizational (i.e. United States Air Force) level. Flow charts are valuable as single-page references that contain quantitative data about resource, commodity, and byproduct flows in a graphical form that also convey structural information about the system that manages those flows. Data on carbon dioxide emissions from the energy sector are reported on a national level. Because carbon dioxide emissions are not reported for individual states, the carbon dioxide emissions are estimated using published energy use information. Data on energy use is compiled by the U.S. Department of Energy's Energy Information Administration (U.S. EIA) in the State Energy Data System (SEDS). SEDS is updated annually and reports data from 2 years prior to the year of the update. SEDS contains data on primary resource consumption, electricity generation, and energy consumption within each economic sector. Flow charts of state-level energy usage and explanations of the calculations and assumptions utilized can be found at: http://flowcharts.llnl.gov. This information is translated into carbon dioxide emissions using ratios of carbon dioxide emissions to energy use calculated from national carbon dioxide emissions and national energy use quantities for each particular sector. These statistics are reported annually in the U.S. EIA's Annual Energy Review. Data for 2008 (US. EIA, 2010) was updated in August of 2010. This is the first presentation of a comprehensive state-level package of flow charts depicting carbon dioxide emissions for the United States.

  6. Vapor-liquid equilibrium of water-acetone-air at ambient temperatures and pressures. An analysis of different VLE-fitting methods

    SciTech Connect (OSTI)

    Lichtenbelt, J.H.; Schram, B.J.

    1985-04-01T23:59:59.000Z

    The availability of accurate equilibrium data is of high importance in chemical engineering practice both for design and research purposes. It appeared that for the gas absorption system water-acetone-air in the range of special interest for absorption and desorption operations, neither literature data nor calculations following UNIFAC gave a sufficient accuracy. An experimental program was set up to determine equilibrium data with an accuracy within 2% for low acetone concentrations (up to 7 wt % gas phase) at ambient temperature (16-30/sup 0/C) and atmospheric pressure (740-860 mmHg). From experiments the activity coefficient at infinite dilution of acetone ..gamma.. is found to be 6.79 (0.01) at 20/sup 0/C and 7.28 (0.01) at 25/sup 0/C, while the total error in ..gamma.. is 1.5%. The equilibrium constant can be calculated from ..gamma.. and shows the same error. The experimental data-fitting with procedures of Margules (two parameters) and Van Laar were successful, but NRTL, Wilson, and UNIQUAC failed, probably because of the small concentration range used.

  7. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

    2008-05-20T23:59:59.000Z

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  8. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01T23:59:59.000Z

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  9. Application of chlorine dioxide as an oilfield facilities treatment fluid

    SciTech Connect (OSTI)

    Romaine, J.; Strawser, T.G.; Knippers, M.L.

    1995-11-01T23:59:59.000Z

    Both mechanical and chemical treatments are used to clean water flood injection distribution systems whose efficiency has been reduced as a result of plugging material such as iron sulfide sludge. Most mechanical treatments rely on uniform line diameter to be effective, while chemical treatments require good contact with the plugging material for efficient removal. This paper describes the design and operation of a new innovative application using chlorine dioxide for the removal of iron sulfide sludge from water flood injection distribution systems. This technology has evolved from the use of chlorine dioxide in well stimulation applications. The use of chlorine dioxide for continuous treatment of injection brines will also be discussed. Exxon USA`s Hartzog Draw facility in Gillette, Wyoming was the site for the application described. 4,500 barrels of chlorine dioxide was pumped in three phases to clean sixty-six miles of the water flood distribution system. Results indicate that chlorine dioxide was effective in cleaning the well guard screens, the injection lines, frac tanks used to collect the treatment fluids and the injection wells.

  10. Process for sequestering carbon dioxide and sulfur dioxide

    DOE Patents [OSTI]

    Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

    2009-10-20T23:59:59.000Z

    A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

  11. Carbon Dioxide Reduction Through Urban Forestry

    E-Print Network [OSTI]

    Standiford, Richard B.

    . Retrieval Terms: urban forestry, carbon dioxide, sequestration, avoided energy The Authors E. Gregory McCarbon Dioxide Reduction Through Urban Forestry: Guidelines for Professional and Volunteer Tree; Simpson, James R. 1999. Carbon dioxide reduction through urban forestry

  12. MASTER THESIS IN AQUATIC PHOTOCHEMISTRY Sunlight-induced carbon dioxide emissions from lakes

    E-Print Network [OSTI]

    Uppsala Universitet

    MASTER THESIS IN AQUATIC PHOTOCHEMISTRY Sunlight-induced carbon dioxide emissions from lakes The emissions of carbon dioxide (CO2) from inland waters are substantial on a global scale. Yet, the fundamental question remains open which proportion of these CO2 emissions is induced by sunlight via photochemical

  13. To estimate vapor pressure easily

    SciTech Connect (OSTI)

    Yaws, C.L.; Yang, H.C. (Lamar Univ., Beaumont, TX (USA))

    1989-10-01T23:59:59.000Z

    Vapor pressures as functions of temperature for approximately 700 major organic chemical compounds are given. The tabulation also gives the temperature range for which the data are applicable. Minimum and maximum temperatures are denoted by TMIN and TMAX. The Antoine equation that correlates vapor pressure as a function of temperature is described. A representative comparison of calculated and actual data values for vapor pressure is shown for ethyl alcohol. The coefficient tabulation is based on both literature (experimental data) and estimated values.

  14. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one...

  15. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  16. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields...

  17. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  18. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2004-06-30T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2004, 6.26 MM lb of carbon dioxide were injected into the pilot area. Carbon dioxide injection rates averaged about 250 MCFD. Carbon dioxide was detected in one production well near the end of May. The amount of carbon dioxide produced was small during this period. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February, increasing to an average of about 2.5 B/D in May and June. Operational problems encountered during the initial stages of the flood were identified and resolved.

  19. Sulfur dioxide removal by enhanced electrostatics

    SciTech Connect (OSTI)

    Larkin, K.; Tseng, C.; Keener, T.C.; Khang, S.J. [Univ. of Cincinnati, OH (United States)

    1997-12-31T23:59:59.000Z

    The economic removal of sulfur dioxide (SO{sub 2}) still represents a significant technical challenge which could determine the use of certain types of fossil fuels for energy production. This paper will present the preliminary results of an innovative research project utilizing a low-cost wet electrostatic precipitator to remove sulfur dioxide. There are many aspects for gas removal in an electrostatic precipitator which are not currently being used. This project utilizes electron attachment of free electrons onto gas molecules and ozone generation to remove sulfur dioxide which is a typical flue gas pollutant. This research was conducted on a bench-scale, wet electrostatic precipitator. A direct-current negative discharge corona is used to generate the ozone in-situ. This ozone will be used to oxidize SO{sub 2} to form sulfuric acid, which is very soluble in water. However, it is believed that the primary removal mechanism is electron attachment of the free electrons from the corona which force the SO{sub 2} to go to equilibrium with the water and be removed from the gas stream. Forcing the equilibrium has been shown to achieve removal efficiencies of up to 70%. The bench scale unit has been designed to operate wet or dry, positive and negative for comparison purposes. The applied dc voltage is variable from 0 to 100 kV, the flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. Tests are conducted on a simulated flue gas stream with SO{sub 2} ranging from 0 to 4,000 ppmv. This paper presents the results of tests conducted to determine the effect of operating conditions on removal efficiency. The removal efficiency was found to vary with gas residence time, water flow rate, inlet concentration, applied power, and the use of corona pulsing.

  20. ARM - Field Campaign - Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD) by Microtops Atmospheric OpticalExperiment (VORTEX) govCampaignsVerification

  1. Apparatus for extracting and sequestering carbon dioxide

    DOE Patents [OSTI]

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2010-02-02T23:59:59.000Z

    An apparatus and method associated therewith to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said apparatus hydrates CO.sub.2 and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  2. Method for extracting and sequestering carbon dioxide

    DOE Patents [OSTI]

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2005-05-10T23:59:59.000Z

    A method and apparatus to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said method and apparatus hydrates CO.sub.2, and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  3. Fuel vapor control device

    SciTech Connect (OSTI)

    Ota, I.; Nishimura, Y.; Nishio, S.; Yogo, K.

    1987-10-20T23:59:59.000Z

    A fuel vapor control device is described having a valve opening and closing a passage connecting a carburetor and a charcoal canister according to a predetermined temperature. A first coil spring formed by a ''shape memory effect'' alloy is provided to urge the valve to open the passage when the temperature is high. A second coil spring urges the valve to close the passage. A solenoid is provided to urge an armature against the valve to close the passage against the force of the first coil spring when the engine is running. The solenoid heats the first coil spring to generate a spring force therein when the engine is running. When the engine is turned off, the solenoid is deactivated, and the force of the first spring overcomes the force of the second spring to open the passage until such time as the temperature of the first spring drops below the predetermined temperature.

  4. CARBON DIOXIDE AND OUR OCEAN LEGACY

    E-Print Network [OSTI]

    is a biologist at the California State Univer- sity San Marcos, with expertise in the effects of carbon dioxideCARBON DIOXIDE AND OUR OCEAN LEGACY G Carbon Dioxide: Our Role The United States is the single. Every day the average American adds about 118 pounds of carbon dioxide to the atmos- phere, due largely

  5. Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-

    E-Print Network [OSTI]

    Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide dioxide separation and sequestration because the lower cost of carbon dioxide separation from for injection of carbon dioxide into oil or gas-bearing formations. An advantage of sequestration involving

  6. Isochoric measurements of an equimolar mixture of carbon dioxide and ethane

    E-Print Network [OSTI]

    Kidd, Michael William

    1992-01-01T23:59:59.000Z

    ) . ~-~YC K. N. Marsh (Member) R. C. Wilhoit (Member) R. W. Flumerfelt (Head of Department) May 1992 ABSTRACT Isochoric Measurements of an Equimolar Mixture of Carbon Dioxide-Ethane. (May 1992} Michael William Kidd B. S. , Clemson University... obtained from Burnett and pycnometer measurements to provide experimental information about PVT behavior, vapor pressures and the phase boundaries of the mixture. The PVT measurements are used to calculate residual energies and entropies at five...

  7. Carbon Dioxide: Threat or Opportunity?

    E-Print Network [OSTI]

    McKinney, A. R.

    1982-01-01T23:59:59.000Z

    catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar...

  8. Reducing carbon dioxide to products

    DOE Patents [OSTI]

    Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

    2014-09-30T23:59:59.000Z

    A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

  9. Passive vapor extraction feasibility study

    SciTech Connect (OSTI)

    Rohay, V.J.

    1994-06-30T23:59:59.000Z

    Demonstration of a passive vapor extraction remediation system is planned for sites in the 200 West Area used in the past for the disposal of waste liquids containing carbon tetrachloride. The passive vapor extraction units will consist of a 4-in.-diameter pipe, a check valve, a canister filled with granular activated carbon, and a wind turbine. The check valve will prevent inflow of air that otherwise would dilute the soil gas and make its subsequent extraction less efficient. The granular activated carbon is used to adsorb the carbon tetrachloride from the air. The wind turbine enhances extraction rates on windy days. Passive vapor extraction units will be designed and operated to meet all applicable or relevant and appropriate requirements. Based on a cost analysis, passive vapor extraction was found to be a cost-effective method for remediation of soils containing lower concentrations of volatile contaminants. Passive vapor extraction used on wells that average 10-stdft{sup 3}/min air flow rates was found to be more cost effective than active vapor extraction for concentrations below 500 parts per million by volume (ppm) of carbon tetrachloride. For wells that average 5-stdft{sup 3}/min air flow rates, passive vapor extraction is more cost effective below 100 ppm.

  10. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18T23:59:59.000Z

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  11. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2007-06-12T23:59:59.000Z

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  12. Effect of paraffinic, naphthenic and aromatic distribution in the hydrocarbon mixture and water on the phase equilibria of carbon dioxide-hydrocarbon systems over the temperature range from 333 k to 366 k

    SciTech Connect (OSTI)

    Ezekwe, J.N.

    1983-04-01T23:59:59.000Z

    Carbon dioxide flooding has been suggested as an efficient and effective means of achieving additional oil recoveries from depleted and/or waterflooded reservoirs. The numeric simulation of a CO/sub 2/ flood requires a phase equilibria predictor that will provide the compositional distribution of the reservoir fluids as the displacement propagates through the reservoir. The objective of this work is to provide a phase equilibria predictor that utilizes the Soave-Redlich-Kwong equation of state.

  13. Vapor deposition of hardened niobium

    DOE Patents [OSTI]

    Blocher, Jr., John M. (Columbus, OH); Veigel, Neil D. (Columbus, OH); Landrigan, Richard B. (Columbus, OH)

    1983-04-19T23:59:59.000Z

    A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

  14. Optimization of multi-pressure himidification-dehumidification desalination using thermal vapor compression and hybridization

    E-Print Network [OSTI]

    Mistry, Karan Hemant

    Humidification-dehumidification (HD or HDH) desalination, and specifically HD driven by a thermal vapor compressor (TVC), is a thermal desalination method that has the potential to produce potable water efficiently in order ...

  15. Application of Computational Fluid Dynamics in the Forced Dispersion Modeling of LNG Vapor Clouds

    E-Print Network [OSTI]

    Kim, Byung-Kyu

    2013-05-31T23:59:59.000Z

    The safety and security of liquefied natural gas (LNG) facilities has prompted the need for continued study of LNG mitigation systems. Water spray systems are widely recognized as an effective measure for dispersing LNG vapor clouds. Currently...

  16. Laboratory Investigations in Support of Dioxide-Limestone Sequestration in the Ocean

    SciTech Connect (OSTI)

    Dan Golomb; Eugene Barry; David Ryan; Stephen Pennell; Carl Lawton; Peter Swett; Devinder Arora; John Hannon; Michael Woods; Huishan Duan; Tom Lawlor

    2008-09-30T23:59:59.000Z

    Research under this Project has proven that liquid carbon dioxide can be emulsified in water by using very fine particles as emulsion stabilizers. Hydrophilic particles stabilize a CO{sub 2}-in-H{sub 2}O (C/W) emulsion; hydrophobic particles stabilize a H{sub 2}O-in-CO{sub 2} (W/C) emulsion. The C/W emulsion consists of tiny CO{sub 2} droplets coated with hydrophilic particles dispersed in water. The W/C emulsion consists of tiny H{sub 2}O droplets coated with hydrophobic particles dispersed in liquid carbon dioxide. The coated droplets are called globules. The emulsions could be used for deep ocean sequestration of CO{sub 2}. Liquid CO{sub 2} is sparsely soluble in water, and is less dense than seawater. If neat, liquid CO{sub 2} were injected in the deep ocean, it is likely that the dispersed CO{sub 2} droplets would buoy upward and flash into vapor before the droplets dissolve in seawater. The resulting vapor bubbles would re-emerge into the atmosphere. On the other hand, the emulsion is denser than seawater, hence the emulsion plume would sink toward greater depth from the injection point. For ocean sequestration a C/W emulsion appears to be most practical using limestone (CaCO{sub 3}) particles of a few to ten ?m diameter as stabilizing agents. A mix of one volume of liquid CO{sub 2} with two volumes of H{sub 2}O, plus 0.5 weight of pulverized limestone per weight of liquid CO{sub 2} forms a stable emulsion with density 1087 kg m{sup -3}. Ambient seawater at 500 m depth has a density of approximately 1026 kg m{sup -3}, so the emulsion plume would sink by gravity while entraining ambient seawater till density equilibrium is reached. Limestone is abundant world-wide, and is relatively cheap. Furthermore, upon disintegration of the emulsion the CaCO{sub 3} particles would partially buffer the carbonic acid that forms when CO{sub 2} dissolves in seawater, alleviating some of the concerns of discharging CO{sub 2} in the deep ocean. Laboratory experiments showed that the CaCO{sub 3} emulsion is slightly alkaline, not acidic. We tested the release of the CO{sub 2}-in-H{sub 2}O emulsion stabilized by pulverized limestone in the DOE National Energy Technology Laboratory High Pressure Water Tunnel Facility (HPWTF). Digital photographs showed the sinking globules in the HPWTF, confirming the concept of releasing the emulsion in the deep ocean. We modeled the release of an emulsion from the CO{sub 2} output of a 1000 MW coal-fired power plant at 500 m depth. The emulsion would typically sink several hundred meters before density equilibration with ambient seawater. The CO{sub 2} globules would rain out from the equilibrated plume toward the ocean bottom where they would disintegrate due to wave action and bottom friction. Conceptual release systems are described both for an open ocean release and a sloping seabed release of the emulsion.

  17. STUDIES ON THE USE OF CARBON DIOXIDE DISSOLVED IN REFRIGERATED BRINE FOR THE PRESERVATION OF WHOLE FISH

    E-Print Network [OSTI]

    of water by species of low oil content, such as sole and cod, and an increase in total salt. Con- trolling, NO. Z, 1971. Use of carbon dioxide gas dissolved in re- frigerated seawater seemed promising as an in experiments on holding fish in tanks, carbon dioxide decreased the rate at which their quality was degraded

  18. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOE Patents [OSTI]

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02T23:59:59.000Z

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  19. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfn; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2004-12-31T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. Continuous carbon dioxide injection began on December 2, 2003. By the end of December 2004, 11.39 MM lb of carbon dioxide were injected into the pilot area. Carbon dioxide injection rates averaged about 242 MCFD. Vent losses were excessive during June as ambient temperatures increased. Installation of smaller plungers in the carbon dioxide injection pump reduced the recycle and vent loss substantially. Carbon dioxide was detected in one production well near the end of May and in the second production well in August. No channeling of carbon dioxide was observed. The GOR has remained within the range of 3000-4000 for most the last six months. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February, increasing to an average of about 2.35 B/D for the six month period between July 1 and December 31. Cumulative oil production was 814 bbls. Neither well has experienced increased oil production rates expected from the arrival of the oil bank generated by carbon dioxide injection.

  20. Carbon dioxide adsorption and methanation on ruthenium

    SciTech Connect (OSTI)

    Zagli, E.; Falconer, J.L.

    1981-05-01T23:59:59.000Z

    The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

  1. The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas

    E-Print Network [OSTI]

    Chickos, James S.

    by Correlation Gas Chromatography Chase Gobble, Nigam Rath, and James Chickos* Department of Chemistry Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals and boiling temperatures when available. Sublimation enthalpies and vapor pressures are also evaluated for 1

  2. Evaluation and prevention of explosions in soil vapor extraction systems

    SciTech Connect (OSTI)

    Hower, J.W. [Radian Corp., El Segundo, CA (United States)

    1995-12-31T23:59:59.000Z

    Due to the widespread and long term use of petroleum derived fuels and solvents, many areas have subsurface soils contaminated with petroleum derivatives. This contamination can migrate to groundwater, which is frequently used to supply drinking water needs. A common method of cleaning up that contamination is soil vapor extraction (SVE). SVE is a technique where several extraction wells are installed in the contaminated area, with screens in the appropriate vertical locations. The soil vapors re extracted form the wells using a positive displacement blower. To prevent this subsurface contamination from becoming air pollution, the extracted vapors are then sent to some hydrocarbon removal device, such as a carbon adsorption system or a thermal oxidizer. The data used in this investigation were collected as part of a Radian Corporation project for a client. The site is a former petroleum refinery, and the hydrocarbons are primarily gasoline and diesel.

  3. A study of new mixture combining rules for prediction of vapor-liquid equilibria

    E-Print Network [OSTI]

    Shyu, Guor-Shiarn

    1993-01-01T23:59:59.000Z

    geometric mean of Eq. 63 for methane and n- o ))an butane. 29 b. Propane (1) and Carbon Dioxide (2) In this system, experimental data for B12 are used as taken from Dymond and Smith(1980). Figure 7 is the fitting diagram of Bin for this system. The y... Dioxide (2). c. Carbon Dioxide (I) and Methanol (2). . d. Ethanol (I) and Benzene (2). . e. Propane (I) and Methanol (2). . f. Methanol (1) and Benzene (2). . g. Ethanol (1) and Water (2)? 15 15 17 20 20 29 29 30 30 38 57 V. DISCUSSIONS...

  4. SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW

    E-Print Network [OSTI]

    Santos, Juan

    SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW J. E. Santos1, G. B. Savioli2, J. M. Carcione3, D´e, Argentina SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. I Storage of CO2). SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. II CO2 is separated from natural

  5. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

    2001-05-01T23:59:59.000Z

    Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

  6. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  7. VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA

    E-Print Network [OSTI]

    Rudnyi, Evgenii B.

    .B. Department of Chemistry, Moscow State University, Moscow, 119899, Russia Bonnell D.W., Hastie J.W. National temperature chemistry situations, vapor pressures are typically less than 100 kPa. The molar volume is p = 101325 Pa). The subscript trs denotes that the changeisfor a transition, typically sublimation

  8. Coiled tubing drilling with supercritical carbon dioxide

    DOE Patents [OSTI]

    Kolle , Jack J. (Seattle, WA)

    2002-01-01T23:59:59.000Z

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  9. Water Management in A PEMFC: Water Transport Mechanism and Material

    E-Print Network [OSTI]

    Kandlikar, Satish

    Water Management in A PEMFC: Water Transport Mechanism and Material Degradation in Gas Diffusion on the water management of the PEMFC, namely the transport of product water (both liquid and vapor its water management performance and func- tion as indicators of the degradation of GDL material

  10. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2006-06-30T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and two production wells on about 10 acre spacing. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February 2004, increasing to an average of about 3.78 B/D for the six month period between January 1 and June 30, 2005 before declining. By June 30, 2006, 41,566 bbls of water were injected into CO2I-1 and 2,726 bbl of oil were produced from the pilot. Injection rates into CO2I-1 declined with time, dropping to an unacceptable level for the project. The injection pressure was increased to reach a stable water injection rate of 100 B/D. However, the injection rate continued to decline with time, suggesting that water was being injected into a region with limited leakoff and production. Oil production rates remained in the range of 3-3.5 B/D following conversion to water injection. Oil rates increased from about 3.3 B/D for the period from January through March to about 4.7 B/D for the period from April through June. If the oil rate is sustained, this may be the first indication of the arrival of the oil bank mobilized by carbon dioxide injection. A sustained fluid withdrawal rate of about 200 B/D from CO2 No.12 and CO2 No.13 appears to be necessary to obtain higher oil rates. There is no evidence that the oil bank generated by injection of carbon dioxide has reached either production well. Water injection will continue to displace oil mobilized by carbon dioxide to the production wells and to maintain the pressure in the PPV region at a level that supports continued miscible displacement as the carbon dioxide is displaced by the injected water.

  11. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  12. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2007-03-07T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. By December 31, 2006, 79,072 bbls of water were injected into CO2 I-1 and 3,923 bbl of oil were produced from the pilot. Water injection rates into CO2 I-1, CO2 No.10 and CO2 No.18 were stabilized during this period. Oil production rates increased from 4.7 B/D to 5.5 to 6 B/D confirming the arrival of an oil bank at CO2 No.12. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver No.7, Colliver No.3 and possibly Graham A4 located on an adjacent property. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Our management plan is to continue water injection maintaining oil displacement by displacing the carbon dioxide remaining in the C zone,. If the decline rate of production from the Colliver Lease remains as estimated and the oil rate from the pilot region remains constant, we estimate that the oil production attributed to carbon dioxide injection will be about 12,000 bbl by December 31, 2007. Oil recovery would be equivalent to 12 MCF/bbl, which is consistent with field experience in established West Texas carbon dioxide floods. The project is not economic.

  13. Vapor canister heater for evaporative emissions systems

    SciTech Connect (OSTI)

    Bishop, R.P.; Berg, P.G.

    1987-01-01T23:59:59.000Z

    Automotive evaporative emissions systems use a charcoal canister to store evaporative hydrocarobn emissions. These stored vapors are later purged and burned during engine operation. Under certain conditions the engine cannot completely purge the canister of the stored fuel vapors, which results in a decreased vapor storage capacity in the canister. A self-regulating PTC (Positive Temperature Coefficient) heater has been developed to warm the purge air as it enters the canister, in order to provide thermal energy for increased release of the vapors from charcoal sites. This paper describes the construction and operation of the vapor canister heater as it relates to improved evaporative emission system performance.

  14. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, L.D.; Cerni, T.A.

    1989-10-17T23:59:59.000Z

    Apparatus and method are disclosed which determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavelength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to an equation given in the patent where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4) + K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation. 11 figs.

  15. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, Loren D. (Morrison, CO); Cerni, Todd A. (Littleton, CO)

    1989-01-01T23:59:59.000Z

    Apparatus and method determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavlength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to: ##EQU1## where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4)+K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation.

  16. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30T23:59:59.000Z

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  17. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2005-12-31T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and two production wells on about 10 acre spacing. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February 2004, increasing to an average of about 3.78 B/D for the six month period between January 1 and June 30, 2005 before declining. By the end of December 2005, 14,115 bbls of water were injected into CO2I-1 and 2,091 bbl of oil were produced from the pilot. Injection rates into CO2I-1 declined with time, dropping to an unacceptable level for the project. The injection pressure was increased to reach a stable water injection rate of 100 B/D. However, the injection rate continued to decline with time, suggesting that water was being injected into a region with limited leakoff and production. Oil production rates remained in the range of 3-3.5 B/D following conversion to water injection. There is no evidence that the oil bank generated by injection of carbon dioxide has reached either production well. Continued injection of water is planned to displace oil mobilized by carbon dioxide to the production wells and to maintain the pressure in the PPV region at a level that supports continued miscible displacement as the carbon dioxide is displaced by the injected water.

  18. An analysis of the impact of having uranium dioxide mixed in with plutonium dioxide

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    1998-10-21T23:59:59.000Z

    An assessment was performed to show the impact on airborne release fraction, respirable fraction, dose conversion factor and dose consequences of postulated accidents at the Plutonium Finishing Plant involving uranium dioxide rather than plutonium dioxide.

  19. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01T23:59:59.000Z

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  20. SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW

    E-Print Network [OSTI]

    santos

    SEISMIC MONITORING OF. CARBON DIOXIDE FLUID FLOW. J. E. Santos. 1. , G. B. Savioli. 2. , J. M. Carcione. 3. , D. Gei. 3. 1. CONICET, IGPUBA, Fac.

  1. Vapor explosion in the RIA-ST-4 experiment. [BWR

    SciTech Connect (OSTI)

    El-Genk, M.S.

    1980-01-01T23:59:59.000Z

    A concern in assuring the safety of commercial light water reactors (LWRs) is whether core overheating, during which molten fuel is produced, can lead to massive vaporization of the coolant and shock pressurization of the system due to an energetic molten fuel-coolant interaction (MFCI). The RIA-ST-4 experiment was one of four scoping tests in the Reactivity Initiated Accident (RIA) Test Series which is being conducted in the Power Burst Facility (PBF) to define an energy deposition failure threshold and to determine modes and consequences of fuel rod failure during a postulated boiling water reactor (BWR) control rod drop accident.

  2. Sustaining dry surfaces under water

    E-Print Network [OSTI]

    Paul R. Jones; Xiuqing Hao; Eduardo R. Cruz-Chu; Konrad Rykaczewski; Krishanu Nandy; Thomas M. Schutzius; Kripa K. Varanasi; Constantine M. Megaridis; Jens H. Walther; Petros Koumoutsakos; Horacio D. Espinosa; Neelesh A. Patankar

    2014-09-29T23:59:59.000Z

    Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have not been investigated, and are critically important to maintain surfaces dry under water. In this work, we identify the critical roughness scale below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys - thus keeping the immersed surface dry. Theoretical predictions are consistent with molecular dynamics simulations and experiments.

  3. Assessment of radionuclide vapor-phase transport in unsaturated tuff

    SciTech Connect (OSTI)

    Smith, D.M.; Updegraff, C.D.; Bonano, E.J.; Randall, J.D.

    1986-11-01T23:59:59.000Z

    This report describes bounding calculations performed to investigate the possibility of radionuclide migration in a vapor phase associated with the emplacement of high-level waste canister in unsaturated tuff formations. Two potential radionuclide transport mechanisms in the vapor phase were examined: aerosol migration and convection/diffusion of volatile species. The former may have significant impact on the release of radionuclides to the accessible environment as the concentration in the aerosols will be equal to that in the ground water. A conservative analysis of air diffusion in a stagnant liquid film indicated that for all expected repository conditions, aerosol formation is not possible. The migration of volatile species was examined both in the vicinity of a waste canister and outside the thermally disturbed zone. Two-dimensional (radial) and three-dimensional (radial-vertical) coupled heat transfer-gas flow-liquid flow simulations were performed using the TOUGH computer code. The gas flow rate relative to the liquid flow rate predicted from the simulations allowed calculations of mobility ratios due to convection which led to the conclusion that, except for the immediate region near the canister, transport in the liquid phase will be dominant for radionuclides heavier than radon. Near the waste canister, iodine transport may also be important in the vapor phase. Bounding calculations for vertical mobility ratios were carried out as a function of saturation. These calculations are conservative and agree well with the two-dimensional simulations. Based on this analysis, it is clear that vapor-phase transport will not be important for radionuclides such as cesium and heavier species. Vapor transport for iodine may play a role in the overall release scenario depending on the particular repository conditions.

  4. Control of flow through a vapor generator

    DOE Patents [OSTI]

    Radcliff, Thomas D.

    2005-11-08T23:59:59.000Z

    In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

  5. THE KINETICS OF LASER PULSE VAPORIZATION OF URANIUM DIOXIDE BY MASS SPECTROMETRY

    E-Print Network [OSTI]

    Tsai, Chuen-horng

    2012-01-01T23:59:59.000Z

    B. Nicholson, "VENUS-II: An LMFBR Disassembly Program," ANL-metal fast breeder reactor (LMFBR) safety analysis. Most

  6. Anisotropic Vapor HF etching of silicon dioxide for Si microstructure release

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and actuators presented in the literature [7] [8] use polysilicon as structural material with phosphosilicate glass (also called as phosphorous doped glass, PSG) as sacrificial. More recently, poly

  7. Wave lengths of some new absorption bands of sulfur dioxide vapor

    E-Print Network [OSTI]

    Landrum, Bobby Lee

    2012-06-07T23:59:59.000Z

    000 020 R 010 100 L 010 020 f 011 120 031 210 R 000 010 L 020 020 f 101 200 002 120 L 100 100 040 110 300 210 Wave number from ) Russell's Formula 24110, 9 A24224, 4 24624. 6 24740 ' 5 24746. 6 24985. 4 25107. 5 25096, 1 25105 F 1...

  8. Overview of chemical vapor infiltration

    SciTech Connect (OSTI)

    Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

    1993-06-01T23:59:59.000Z

    Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

  9. atmospheric sulphur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide CERN Preprints Summary: The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause...

  10. Carbon dioxide-assisted fabrication of highly uniform submicron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide-assisted fabrication of highly uniform submicron-sized colloidal carbon spheres via hydrothermal carbonization Carbon dioxide-assisted fabrication of highly uniform...

  11. Optimize carbon dioxide sequestration, enhance oil recovery

    E-Print Network [OSTI]

    - 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

  12. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  13. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  14. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17T23:59:59.000Z

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  15. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems

    SciTech Connect (OSTI)

    Factorovich, Matas H.; Scherlis, Damin A. [Departamento de Qumica Inorgnica, Analtica y Qumica Fsica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires C1428EHA (Argentina)] [Departamento de Qumica Inorgnica, Analtica y Qumica Fsica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires C1428EHA (Argentina); Molinero, Valeria [Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)] [Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

    2014-02-14T23:59:59.000Z

    In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

  16. Standard specification for sintered gadolinium oxide-uranium dioxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    1.1 This specification is for finished sintered gadolinium oxide-uranium dioxide pellets for use in light-water reactors. It applies to gadolinium oxide-uranium dioxide pellets containing uranium of any 235U concentration and any concentration of gadolinium oxide. 1.2 This specification recognizes the presence of reprocessed uranium in the fuel cycle and consequently defines isotopic limits for gadolinium oxide-uranium dioxide pellets made from commercial grade UO2. Such commercial grade UO2 is defined so that, regarding fuel design and manufacture, the product is essentially equivalent to that made from unirradiated uranium. UO2 falling outside these limits cannot necessarily be regarded as equivalent and may thus need special provisions at the fuel fabrication plant or in the fuel design. 1.3 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aw...

  17. Near real time vapor detection and enhancement using aerosol adsorption

    SciTech Connect (OSTI)

    Novick, Vincent J.; Johnson, Stanley A.

    1997-12-01T23:59:59.000Z

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  18. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03T23:59:59.000Z

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  19. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

    1999-01-01T23:59:59.000Z

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  20. Carbon dioxide sequestration by aqueous mineral carbonation of magnesium silicate minerals

    SciTech Connect (OSTI)

    Gerdemann, Stephen J.; Dahlin, David C.; O'Connor, William K.; Penner, Larry R.

    2003-01-01T23:59:59.000Z

    The dramatic increase in atmospheric carbon dioxide since the Industrial Revolution has caused concerns about global warming. Fossil-fuel-fired power plants contribute approximately one third of the total human-caused emissions of carbon dioxide. Increased efficiency of these power plants will have a large impact on carbon dioxide emissions, but additional measures will be needed to slow or stop the projected increase in the concentration of atmospheric carbon dioxide. By accelerating the naturally occurring carbonation of magnesium silicate minerals it is possible to sequester carbon dioxide in the geologically stable mineral magnesite (MgCO3). The carbonation of two classes of magnesium silicate minerals, olivine (Mg2SiO4) and serpentine (Mg3Si2O5(OH)4), was investigated in an aqueous process. The slow natural geologic process that converts both of these minerals to magnesite can be accelerated by increasing the surface area, increasing the activity of carbon dioxide in the solution, introducing imperfections into the crystal lattice by high-energy attrition grinding, and in the case of serpentine, by thermally activating the mineral by removing the chemically bound water. The effect of temperature is complex because it affects both the solubility of carbon dioxide and the rate of mineral dissolution in opposing fashions. Thus an optimum temperature for carbonation of olivine is approximately 185 degrees C and 155 degrees C for serpentine. This paper will elucidate the interaction of these variables and use kinetic studies to propose a process for the sequestration of the carbon dioxide.

  1. Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water

    SciTech Connect (OSTI)

    Sperling, Brent A., E-mail: brent.sperling@nist.gov; Hoang, John; Kimes, William A.; Maslar, James E. [Chemical Sciences Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8320, Gaithersburg, Maryland 20899-8320 (United States); Steffens, Kristen L. [Biomolecular Measurement Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8362, Gaithersburg, Maryland 20899-8362 (United States); Nguyen, Nhan V. [Semiconductor and Dimensional Metrology Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8120, Gaithersburg, Maryland 20899-8120 (United States)

    2014-05-15T23:59:59.000Z

    Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120?ms. At 190?C and 240?C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110?C) and with long purge times (30?s)

  2. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Richard Pancake; JyunSyung Tsau; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2010-03-07T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide was injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide was injected to displace the oil bank to the production wells by water injection. By March 7,2010, 8,736 bbl of oil were produced from the pilot. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver A7, Colliver A3, Colliver A14 and Graham A4 located on adjacent leases. About 19,166 bbl of incremental oil were estimated to have been produced from these wells as of March 7, 2010. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Estimated oil recovery attributed to the CO2 flood is 27,902 bbl which is equivalent to a gross CO2 utilization of 4.8 MCF/bbl. The pilot project is not economic.

  3. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    SciTech Connect (OSTI)

    Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

    2011-02-15T23:59:59.000Z

    Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

  4. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

    1998-01-01T23:59:59.000Z

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  5. Thermophilic Biotrickling Filtration of Ethanol Vapors

    E-Print Network [OSTI]

    Thermophilic Biotrickling Filtration of Ethanol Vapors H U U B H . J . C O X , T H O M A S S E X of ethanol vapors in biotrickling filters for air pollution control was investigated. Two reactors were adaptation phase, the removal of ethanol was similar in both reactors. At a bed contact time of 57 s

  6. VAPOR PRESSURE ISOTOPE EFFECTS IN THE MEASUREMENT OF ENVIRONMENTAL TRITIUM SAMPLES.

    SciTech Connect (OSTI)

    Kuhne, W.

    2012-12-03T23:59:59.000Z

    Standard procedures for the measurement of tritium in water samples often require distillation of an appropriate sample aliquot. This distillation process may result in a fractionation of tritiated water and regular light water due to the vapor pressure isotope effect, introducing either a bias or an additional contribution to the total tritium measurement uncertainty. The magnitude of the vapor pressure isotope effect is characterized as functions of the amount of water distilled from the sample aliquot and the heat settings for the distillation process. The tritium concentration in the distillate is higher than the tritium concentration in the sample early in the distillation process, it then sharply decreases due to the vapor pressure isotope effect and becomes lower than the tritium concentration in the sample, until the high tritium concentration retained in the boiling flask is evaporated at the end of the process. At that time, the tritium concentration in the distillate again overestimates the sample tritium concentration. The vapor pressure isotope effect is more pronounced the slower the evaporation and distillation process is conducted; a lower heat setting during the evaporation of the sample results in a larger bias in the tritium measurement. The experimental setup used and the fact that the current study allowed for an investigation of the relative change in vapor pressure isotope effect in the course of the distillation process distinguish it from and extend previously published measurements. The separation factor as a quantitative measure of the vapor pressure isotope effect is found to assume values of 1.034 {+-} 0.033, 1.052 {+-} 0.025, and 1.066 {+-} 0.037, depending on the vigor of the boiling process during distillation of the sample. A lower heat setting in the experimental setup, and therefore a less vigorous boiling process, results in a larger value for the separation factor. For a tritium measurement in water samples, this implies that the tritium concentration could be underestimated by 3 - 6%.

  7. HANFORD CHEMICAL VAPORS WORKER CONCERNS & EXPOSURE EVALUATION

    SciTech Connect (OSTI)

    ANDERSON, T.J.

    2006-12-20T23:59:59.000Z

    Chemical vapor emissions from underground hazardous waste storage tanks on the Hanford site in eastern Washington State are a potential concern because workers enter the tank farms on a regular basis for waste retrievals, equipment maintenance, and surveillance. Tank farm contractors are in the process of retrieving all remaining waste from aging single-shell tanks, some of which date to World War II, and transferring it to newer double-shell tanks. During the waste retrieval process, tank farm workers are potentially exposed to fugitive chemical vapors that can escape from tank headspaces and other emission points. The tanks are known to hold more than 1,500 different species of chemicals, in addition to radionuclides. Exposure assessments have fully characterized the hazards from chemical vapors in half of the tank farms. Extensive sampling and analysis has been done to characterize the chemical properties of hazardous waste and to evaluate potential health hazards of vapors at the ground surface, where workers perform maintenance and waste transfer activities. Worker concerns. risk communication, and exposure assessment are discussed, including evaluation of the potential hazards of complex mixtures of chemical vapors. Concentrations of vapors above occupational exposure limits-(OEL) were detected only at exhaust stacks and passive breather filter outlets. Beyond five feet from the sources, vapors disperse rapidly. No vapors have been measured above 50% of their OELs more than five feet from the source. Vapor controls are focused on limited hazard zones around sources. Further evaluations of vapors include analysis of routes of exposure and thorough analysis of nuisance odors.

  8. Displacement of crude oil by carbon dioxide

    E-Print Network [OSTI]

    Omole, Olusegun

    1980-01-01T23:59:59.000Z

    by Carbon Dioxide (December 1980) Olusegun Omole, B. S. , University of Ibadan, Nigeria Chairman of Advisory Committee: Dr. J. S. Osoba It has long been recognized that carbon dioxide could be used as an oil recovery agent. Both laboratory and field...- tion. Crude oil from the Foster Field in West Texas, of 7 cp and 34 API, 0 was used as the oil in place. Oil displacements were conducted at pres- sures between 750 psig and 1800 ps1g, and at a temperature of 110 F. 0 Carbon dioxide was injected...

  9. Identifying and Developing New, Carbon Dioxide Consuming Processes , Sudheer Indalaa

    E-Print Network [OSTI]

    Pike, Ralph W.

    of propane, styrene from ethyl benzene and carbon dioxide, and methanol from hydrogenation of carbon dioxide408b Identifying and Developing New, Carbon Dioxide Consuming Processes Aimin Xua , Sudheer Indalaa@hal.lamar.edu, yawscl@hal.lamar.edu Key words; Carbon Dioxide Processes, Greenhouse Gases, Chemical Complex, Sustainable

  10. Quantitative Infrared Intensity Studies of Vapor-PhaseGlyoxal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal, and 2,3-Butanedione (Diacetyl) with Quantitative Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal,...

  11. Absolute integrated intensities of vapor-phase hydrogen peroxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absolute integrated intensities of vapor-phase hydrogen peroxide (H202) in the mid-infrared at atmospheric pressure. Absolute integrated intensities of vapor-phase hydrogen...

  12. Oil recovery by carbon dioxide injection into consolidated and unconsolidated sandstone

    E-Print Network [OSTI]

    Lin, Fwu-Jin Frank

    1975-01-01T23:59:59.000Z

    and field in the past decade. The analysis of these tests indicated that additional oil beyond that obtained by normal water flooding could be recovered with carbon d1oxide. The c1tations on the following pages follow the style of the Journal.... Yon Gonten The use of carbon dioxide as an oil recovery agent in petro- leum reservoirs has been investigated for many years. Both la- boratory and field studies have established that carbon dioxide can be an efficient oil displacing agent...

  13. Regulating carbon dioxide capture and storage

    E-Print Network [OSTI]

    De Figueiredo, Mark A.

    2007-01-01T23:59:59.000Z

    This essay examines several legal, regulatory and organizational issues that need to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal, regulatory, and organizational ...

  14. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01T23:59:59.000Z

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  15. E-Print Network 3.0 - acid water environments Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

  16. E-Print Network 3.0 - atmospheric water demand Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and this in turn reduces carbon dioxide emissions and water use. CO2... emissions Coal Dam Demand ... Source: Crimmins, Michael A. - School of Earth and Environmental...

  17. Analysis of a duo-selecting membrane reactor for the water-gas shift

    E-Print Network [OSTI]

    Hardy, AliciA Jillian Jackson, 1978-

    2004-01-01T23:59:59.000Z

    The water-gas shift reaction is an exothermic and reversible catalytic process that converts carbon monoxide and water (steam) to hydrogen and carbon dioxide. In regard to energy-related issues, the water-gas shift is part ...

  18. T2Well/ECO2N Version 1.0: Multiphase and Non-Isothermal Model for Coupled Wellbore-Reservoir Flow of Carbon Dioxide and Variable Salinity Water

    SciTech Connect (OSTI)

    Pan, L.; Oldenburg, C.M.; Wu, Y.-S.; Pruess, K.

    2011-02-14T23:59:59.000Z

    At its most basic level, the injection of CO{sub 2} into geologic CO{sub 2} storage sites involves a system comprising the wellbore and the target reservoir. The wellbore is the only conduit available to emplace CO{sub 2} into reservoirs for long-term storage. At the same time, wellbores in general have been identified as the most likely conduit for CO{sub 2} and brine leakage from geologic carbon sequestration (GCS) sites, especially those in sedimentary basins with historical hydrocarbon production. We have developed a coupled wellbore and reservoir model for simulating the dynamics of CO{sub 2} injection and leakage through wellbores. The model describes the following processes: (1) upward or downward wellbore flow of CO{sub 2} and variable salinity water with transition from supercritical to gaseous CO{sub 2} including Joule-Thomson cooling, (2) exsolution of CO{sub 2} from the aqueous phase as pressure drops, and (3) cross flow into or interaction with layers of surrounding rock (reservoirs). We use the Drift-Flux Model and related conservation equations for describing transient two-phase non-isothermal wellbore flow of CO{sub 2}-water mixtures under different flow regimes and interacting with surrounding rock. The mass and thermal energy balance equations are solved numerically by a finite difference scheme with wellbore heat transmission to the surrounding rock handled either semi-analytically or numerically. The momentum balance equation for the flow in the wellbore is solved numerically with a semi-explicit scheme. This manual provides instructions for compilation and use of the new model, and presents some example problems to demonstrate its use.

  19. Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.

    SciTech Connect (OSTI)

    Moore, Robert Charles; Conboy, Thomas M.

    2012-02-01T23:59:59.000Z

    A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

  20. Carbon dioxide for the recovery of crude oil. Annual report, November 1978-November 1979

    SciTech Connect (OSTI)

    Doscher, T.M.

    1980-08-01T23:59:59.000Z

    The displacement of residual oil to waterflooding by miscible fluid injection has been studied using scaled physical models of line-drive systems. The effects of flow rate, mobility ratio, and density ratio, were investigated. This work was a first step in an overall program of studying miscible displacement in particular by carbon dioxide, of residual oil as a process for recovering additional crude oil from reservoirs which had been waterflooded. The ratios of gravitational and viscous forces which exist in tertiary recovery operations, using carbon dioxide as a recovery reagent, were approximated in a scaled physical model at ambient pressure and temperature. The viscosity ratio was now very unfavorable and displacement of moveable water was inefficient. Consequently, the displacement of the residual oil by the solvent, which was simulating the role of carbon dioxide, was also poor. The recovery efficiency could not be improved by reasonable increases in the fluid velocity because the unfavorable mobility-caused viscous fingering was so dominant. Insomuch as carbon dioxide flooding, an imperfectly miscible recovery process, cannot be expected to perform as well as a perfectly miscible recovery process, these experiments point to the need for imposing a strong measure of mobility control if the injection of carbon dioxide is to achieve widespread usage for the recovery of residual oil.

  1. Cobalt Ultrathin Film Catalyzed Ethanol Chemical Vapor Deposition of Single-Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Hone, James

    Cobalt Ultrathin Film Catalyzed Ethanol Chemical Vapor Deposition of Single-Walled Carbon Nanotubes (SWNTs) using a cobalt ultrathin film (1 nm) as the catalyst and ethanol as carbon feedstock flow during the growth. The trace amount of self-contained water (0.2-5 wt %) in ethanol may act

  2. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01T23:59:59.000Z

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  3. Chemical vapor deposition of antimicrobial polymer coatings

    E-Print Network [OSTI]

    Martin, Tyler Philip, 1977-

    2007-01-01T23:59:59.000Z

    There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...

  4. Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect on forest

    E-Print Network [OSTI]

    Gray, Matthew

    ecosystem's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy, sustain life10/13/2010 1 Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect

  5. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30T23:59:59.000Z

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  6. Carbon dioxide capture process with regenerable sorbents

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

    2002-05-14T23:59:59.000Z

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  7. Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A. Wilson and James S. Chickos* Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121, United States *S Supporting Information ABSTRACT: Sublimation enthalpies

  8. Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Chromatography Chase Gobble and James Chickos* Department of Chemistry and Biochemistry University of Missouri-St. Louis, St. Louis Missouri 63121, United States Sergey P. Verevkin Department of Physical Chemistry: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl

  9. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    SciTech Connect (OSTI)

    K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

    2003-04-30T23:59:59.000Z

    The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also provided direct synergism with the original goals of our work. Specific accomplishments of this project are summarized below in three broad categories: experimentation, model development, and coal characterization.

  10. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Andreas Weber; Raghubir P. Gupta

    2006-01-01T23:59:59.000Z

    This report describes research conducted between October 1, 2005, and December 31, 2005, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from flue gas from coal combustion. A field test was conducted to examine the extent to which RTI's supported sorbent can be regenerated in a heated, hollow screw conveyor. This field test was conducted at the facilities of a screw conveyor manufacturer. The sorbent was essentially completely regenerated during this test, as confirmed by thermal desorption and mass spectroscopy analysis of the regenerated sorbent. Little or no sorbent attrition was observed during 24 passes through the heated screw conveyor system. Three downflow contactor absorption tests were conducted using calcined sodium bicarbonate as the absorbent. Maximum carbon dioxide removals of 57 and 91% from simulated flue gas were observed at near ambient temperatures with water-saturated gas. These tests demonstrated that calcined sodium carbonate is not as effective at removing CO{sub 2} as are supported sorbents containing 10 to 15% sodium carbonate. Delivery of the hollow screw conveyor for the laboratory-scale sorbent regeneration system was delayed; however, construction of other components of this system continued during the quarter.

  11. Treatment of produced water by simultaneous removal of heavy metals and dissolved polycyclic aromatic hydrocarbons in a photoelectrochemical cell.

    E-Print Network [OSTI]

    Igunnu, Ebenezer Temitope

    2014-01-01T23:59:59.000Z

    ??Early produced water treatment technologies were developed before carbon dioxide emissions and hazardous waste discharge were recognised as operational priority. These technologies are deficient in (more)

  12. A methodology for forecasting carbon dioxide flooding performance

    E-Print Network [OSTI]

    Marroquin Cabrera, Juan Carlos

    1998-01-01T23:59:59.000Z

    A methodology was developed for forecasting carbon dioxide (CO2) flooding performance quickly and reliably. The feasibility of carbon dioxide flooding in the Dollarhide Clearfork "AB" Unit was evaluated using the methodology. This technique is very...

  13. Dry process fluorination of uranium dioxide using ammonium bifluoride

    E-Print Network [OSTI]

    Yeamans, Charles Burnett, 1978-

    2003-01-01T23:59:59.000Z

    An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ...

  14. Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas)

    Broader source: Energy.gov [DOE]

    Carbon Dioxide Capture/Sequestration Tax Deduction allows a taxpayer a deduction to adjusted gross income with respect to the amortization of the amortizable costs of carbon dioxide capture,...

  15. Louisiana Geologic Sequestration of Carbon Dioxide Act (Louisiana)

    Broader source: Energy.gov [DOE]

    This law establishes that carbon dioxide and sequestration is a valuable commodity to the citizens of the state. Geologic storage of carbon dioxide may allow for the orderly withdrawal as...

  16. Water Formation in the Early Universe

    E-Print Network [OSTI]

    Bialy, Shmuel; Loeb, Abraham

    2015-01-01T23:59:59.000Z

    We demonstrate that high abundances of water vapor could have existed in extremely low metallicity ($10^{-3}$ solar) partially shielded gas, during the epoch of first metal enrichment of the interstellar medium of galaxies at high redshifts.

  17. Vapor Barriers or Vapor Diffusion Retarders | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehiclesTankless or Demand-Type WaterTravel TravelUpcomingUsefulAbout

  18. Master index for the carbon dioxide research state-of-the-art report series

    SciTech Connect (OSTI)

    Farrell, M P [ed.

    1987-03-01T23:59:59.000Z

    Four State of the Art (SOA) reports, ''Atmospheric Carbon Dioxide and the Global Carbon Cycle,'' ''Direct Effects of Increasing Carbon Dioxide on Vegetation,'' ''Detecting the Climatic Effects of Increasing Carbon Dioxide,'' and ''Projecting the Climatic Effects of Increasing Carbon Dioxide,'' and two companion reports, ''Characterization of Information Requirements for Studies of CO/sub 2/ Effects: Water Resources, Agriculture, Fisheries, Forests and Human Health'' and ''Glaciers, Ice Sheets, and Sea Level: Effect of a CO/sub 2/-Induced Climatic Change,'' were published by the US Department of Energy's Carbon Dioxide Research Division. Considerable information on atmospheric carbon dioxide and its possible effects on world climate is summarized in these six volumes. Each volume has its own index, but to make the information that is distributed throughout the six volumes more accessible and usable, comprehensive citation and subject indexes have been compiled. The subject indexes of the individual volumes have been edited to provide a uniformity from volume to volume and also to draw distinctions not needed in the separate volumes' indexes. Also, the comprehensive subject index has been formatted in a matrix arrangement to graphically show the distribution of subject treatment from volume to volume. Other aids include cross references between the scientific and common names of the animals and plants referred to, a glossary of special terms used, tables of data and conversion factors related to the data, and explanations of the acronyms and initialisms used in the texts of the six volumes. The executive summaries of the six volumes are collected and reproduced to allow the readers interested in the contents of one volume to rapidly gain information on the contents of the other volumes.

  19. Vapor scavenging by atmospheric aerosol particles

    SciTech Connect (OSTI)

    Andrews, E.

    1996-05-01T23:59:59.000Z

    Particle growth due to vapor scavenging was studied using both experimental and computational techniques. Vapor scavenging by particles is an important physical process in the atmosphere because it can result in changes to particle properties (e.g., size, shape, composition, and activity) and, thus, influence atmospheric phenomena in which particles play a role, such as cloud formation and long range transport. The influence of organic vapor on the evolution of a particle mass size distribution was investigated using a modified version of MAEROS (a multicomponent aerosol dynamics code). The modeling study attempted to identify the sources of organic aerosol observed by Novakov and Penner (1993) in a field study in Puerto Rico. Experimentally, vapor scavenging and particle growth were investigated using two techniques. The influence of the presence of organic vapor on the particle`s hydroscopicity was investigated using an electrodynamic balance. The charge on a particle was investigated theoretically and experimentally. A prototype apparatus--the refractive index thermal diffusion chamber (RITDC)--was developed to study multiple particles in the same environment at the same time.

  20. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    carbon dioxide emissions per 1,000 cubic feet of natural gas. In this case, there is much less energy

  1. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1981-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  2. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1982-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  3. Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern

    E-Print Network [OSTI]

    Denver, University of

    Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern Diesel Vehicles G.A. Bishop and D negative implications for local photochemical ozone production. Keywords: Nitrogen dioxide, automobile strategies, Lemaire [1] suggests that nitrogen dioxide (NO2) was forgotten as a separate component of the NOx

  4. Nanostructured Tin Dioxide Materials for Gas Sensor Applications

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    CHAPTER 30 Nanostructured Tin Dioxide Materials for Gas Sensor Applications T. A. Miller, S. D) levels for some species. Tin dioxide (also called stannic oxide or tin oxide) semi- conductor gas sensors undergone extensive research and development. Tin dioxide (SnO2) is the most important material for use

  5. Designed amyloid fibers as materials for selective carbon dioxide capture

    E-Print Network [OSTI]

    Designed amyloid fibers as materials for selective carbon dioxide capture Dan Lia,b,c,1 , Hiroyasu demonstrate that amyloids, self-assembling protein fibers, are effective for selective carbon dioxide capture. Solid-state NMR proves that amyloid fibers containing alkylamine groups reversibly bind carbon dioxide

  6. Array of titanium dioxide nanostructures for solar energy utilization

    DOE Patents [OSTI]

    Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

    2014-12-30T23:59:59.000Z

    An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

  7. Glutamate Surface Speciation on Amorphous Titanium Dioxide and

    E-Print Network [OSTI]

    Sverjensky, Dimitri A.

    Glutamate Surface Speciation on Amorphous Titanium Dioxide and Hydrous Ferric Oxide D I M I T R I (HFO) and titanium dioxide exhibit similar strong attachment of many adsorbates including biomolecules on amorphous titanium dioxide. The results indicate that glutamate adsorbs on HFO as a deprotonated divalent

  8. Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

  9. Water Vapor Turbulence Statistics in the Convective Boundary...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This study presented the first long-term data set of variance and skewness turbulent statistic profiles in the CBL, spanning a range of seasons and environmental conditions. These...

  10. EXAMINING THE SPECTROSCOPY OF WATER VAPOR IN THE ATMOSPHERE

    E-Print Network [OSTI]

    Petta, Jason

    Compare to relative humidity probe Describes VCSEL accuracy #12;FLOW DILUTION SYSTEM Critical Orifice

  11. Validation of TES Temperature and Water Vapor Retrievals with ARM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II FieldVacancy-InducedCloud PropertiesObservations

  12. Desalination of water by vapor transport through hydrophobic nanopores

    E-Print Network [OSTI]

    Lee, Jongho, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Although Reverse osmosis (RO) is the state-of-the-art desalination technology, it still suffers from persistent drawbacks including low permeate flux, low selectivity for non-ionic species, and lack of resistance to chlorine. ...

  13. ARM - Field Campaign - ARM-FIRE Water Vapor Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01)3, 2010September 30,JuneMayIIIgovCampaignsARM West

  14. ARM - Field Campaign - Arctic Winter Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01)3, 2010SeptemberInfraredgovCampaignsAircraft

  15. ARM - Field Campaign - Fall 1997 Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01)3,Cloud ODgovCampaignsFIRE-ArcticShortwave IOP ARM DataUAV

  16. ARM - Field Campaign - Single Frequency GPS Water Vapor Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD) by Microtops Atmospheric Optical Depth (AOD)govCampaignsReplicatorgovCampaignsSingle Column

  17. Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics GroupPlanning Workshop Overview ofOverview of the

  18. Vapor characterization of Tank 241-C-103

    SciTech Connect (OSTI)

    Huckaby, J.L. [Westinghouse Hanford Co., Richland, WA (United States); Story, M.S. [Northwest Instrument Systems, Inc. Richland, WA (United States)

    1994-06-01T23:59:59.000Z

    The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program.

  19. Method and Apparatus for Concentrating Vapors for Analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2008-10-07T23:59:59.000Z

    An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

  20. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15T23:59:59.000Z

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  1. Introduction Air Quality and Nitrogen Dioxide

    E-Print Network [OSTI]

    - Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

  2. Carbon Dioxide Corrosion: Modelling and Experimental Work

    E-Print Network [OSTI]

    Carbon Dioxide Corrosion: Modelling and Experimental Work Applied to Natural Gas Pipelines Philip in the corrosion related research institutions at IFE and the Ohio University or any other scientific research;#12;Introduction - v - Summary CO2 corrosion is a general problem in the industry and it is expensive. The focus

  3. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Scherer, Norbert F.

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  4. Hydroelectric Reservoirs -the Carbon Dioxide and Methane

    E-Print Network [OSTI]

    Fischlin, Andreas

    Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

  5. Acid sorption regeneration process using carbon dioxide

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); Husson, Scott M. (Anderson, SC)

    2001-01-01T23:59:59.000Z

    Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

  6. Carbon dioxide storage professor Martin Blunt

    E-Print Network [OSTI]

    of CCS storage there are over a hundred sites worldwide where Co2 is injected under- ground as partCarbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS and those for injection and storage in deep geological formations. all the individual elements operate today

  7. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    . LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologiesCarbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005 environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  8. Carbon Dioxide Corrosion and Inhibition Studies

    E-Print Network [OSTI]

    Petta, Jason

    · Corrosion inhibition very important in the oil industry · Film forming inhibitors containing nitrogenCarbon Dioxide Corrosion and Inhibition Studies Kristin Gilida #12;Outline · Background = Zreal + Zim Rp 1/Corr Rate #12;Tafel · Measures corrosion rate directly · Measures iCORR from A and C

  9. Method of physical vapor deposition of metal oxides on semiconductors

    DOE Patents [OSTI]

    Norton, David P. (Knoxville, TN)

    2001-01-01T23:59:59.000Z

    A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

  10. CORQUENCH: A model for gas sparging-enhanced, melt-water, film-boiling heat transfer

    SciTech Connect (OSTI)

    Farmer, M.T.; Sienicki, J.J.; Spencer, B.W.

    1990-01-01T23:59:59.000Z

    In evaluation of severe-accident sequences for water-cooled nuclear reactors, molten core materials may be postulated to be released into the containment and accumulate on concrete. The heatup and decomposition of concrete is accompanied by the release of water vapor and carbon dioxide gases. Gases flowing through the melt upper surface can influence the rates of heat transfer to water overlying the melt. In particular, the gas flow through the interface can be envisioned to enhance the heat removal from the melt. A mechanistic model (CORQUENCH) has been developed to describe film-boiling heat transfer between a molten pool and an overlying coolant layer in the presence of sparging gas. The model favorably predicts the lead-Feron 11 data of Greene and Greene et al. for which the calculations indicate that area enhancement in the conduction heat transfer across the film is the predominant mechanism leading to augmentation in the heat flux as the gas velocity increases. Predictions for oxidic corium indicate a rapid increase in film-boiling heat flux as the gas velocity rises. The predominant mode of heat transfer for this case is radiation, and the increase in heat flux with gas velocity is primarily a result of interfacial area enhancement of the radiation component of the overall heat transfer coefficient. The CORQUENCH model has been incorporated into the MELTSPREAD-1 computer code{sup 6} for the analysis of transient spreading in containments.

  11. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  12. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared Land SurfaceVirus-Infected Macaques

  13. Vapor intrusion modeling : limitations, improvements, and value of information analyses

    E-Print Network [OSTI]

    Friscia, Jessica M. (Jessica Marie)

    2014-01-01T23:59:59.000Z

    Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

  14. Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01T23:59:59.000Z

    In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

  15. Final report on the project entitled "The Effects of Disturbance & Climate on Carbon Storage & the Exchanges of CO2 Water Vapor & Energy Exchange of Evergreen Coniferous Forests in the Pacific Northwest: Integration of Eddy Flux, Plant and Soil Measurements at a Cluster of Supersites"

    SciTech Connect (OSTI)

    Beverly E. Law (PI), Christoph K. Thomas (CoI)

    2011-09-20T23:59:59.000Z

    This is the final technical report containing a summary of all findings with regard to the following objectives of the project: (1) To quantify and understand the effects of wildfire on carbon storage and the exchanges of energy, CO2, and water vapor in a chronosequence of ponderosa pine (disturbance gradient); (2) To investigate the effects of seasonal and interannual variation in climate on carbon storage and the exchanges of energy, CO2, and water vapor in mature conifer forests in two climate zones: mesic 40-yr old Douglas-fir and semi-arid 60-yr old ponderosa pine (climate gradient); (3) To reduce uncertainty in estimates of CO2 feedbacks to the atmosphere by providing an improved model formulation for existing biosphere-atmosphere models; and (4) To provide high quality data for AmeriFlux and the NACP on micrometeorology, meteorology, and biology of these systems. Objective (1): A study integrating satellite remote sensing, AmeriFlux data, and field surveys in a simulation modeling framework estimated that the pyrogenic carbon emissions, tree mortality, and net carbon exchange associated with four large wildfires that burned ~50,000 hectares in 2002-2003 were equivalent to 2.4% of Oregon statewide anthropogenic carbon emissions over the same two-year period. Most emissions were from the combustion of the forest floor and understory vegetation, and only about 1% of live tree mass was combusted on average. Objective (2): A study of multi-year flux records across a chronosequence of ponderosa pine forests yielded that the net carbon uptake is over three times greater at a mature pine forest compared with young pine. The larger leaf area and wetter and cooler soils of the mature forest mainly caused this effect. A study analyzing seven years of carbon and water dynamics showed that interannual and seasonal variability of net carbon exchange was primarily related to variability in growing season length, which was a linear function of plant-available soil moisture in spring and early summer. A multi-year drought (2001-2003) led to a significant reduction of net ecosystem exchange due to carry-over effects in soil moisture and carbohydrate reserves in plant-tissue. In the same forest, the interannual variability in the rate carbon is lost from the soil and forest floor is considerable and related to the variability in tree growth as much as it is to variability in soil climatic conditions. Objective (3): Flux data from the mature ponderosa pine site support a physical basis for filtering nighttime data with friction velocity above the canopy. An analysis of wind fields and heat transport in the subcanopy at the mesic 40-year old Douglas site yielded that the non-linear structure and behavior of spatial temperature gradients and the flow field require enhanced sensor networks to estimate advective fluxes in the subcanopy of forest to close the surface energy balance in forests. Reliable estimates for flux uncertainties are needed to improve model validation and data assimilation in process-based carbon models, inverse modeling studies and model-data synthesis, where the uncertainties may be as important as the fluxes themselves. An analysis of the time scale dependence of the random and flux sampling error yielded that the additional flux obtained by increasing the perturbation timescale beyond about 10 minutes is dominated by random sampling error, and therefore little confidence can be placed in its value. Artificial correlation between gross ecosystem productivity (GEP) and ecosystem respiration (Re) is a consequence of flux partitioning of eddy covariance flux data when GEP is computed as the difference between NEE and computed daytime Re (e.g. using nighttime Re extrapolated into daytime using soil or air temperatures). Tower-data must be adequately spatially averaged before comparison to gridded model output as the time variability of both is inherently different. The eddy-covariance data collected at the mature ponderosa pine site and the mesic Douglas fir site were used to develop and evaluate a new method to extra

  16. Reductive Dehalogenation of Trichloroethene Vapors in an

    E-Print Network [OSTI]

    to treat trichloroethene (TCE) from waste gases generated by soil vapor extraction or dual-phase extraction through the recirculating liquid as a source of hydrogen, the electron donor for Dehalococcoides strains (DPE) (4). However, these techniques result in a waste gas stream that needs further treatment. Several

  17. Advancing Explosives Detection Capabilities: Vapor Detection

    ScienceCinema (OSTI)

    Atkinson, David

    2014-07-24T23:59:59.000Z

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  18. Vaporization of synthetic fuels. Final report. [Thesis

    SciTech Connect (OSTI)

    Sirignano, W.A.; Yao, S.C.; Tong, A.Y.; Talley, D.

    1983-01-01T23:59:59.000Z

    The problem of transient droplet vaporization in a hot convective environment is examined. The main objective of the present study is to develop an algorithm for the droplet vaporization which is simple enough to be feasibly incorporated into a complete spray combustion analysis and yet will also account for the important physics such as liquid-phase internal circulation, unsteady droplet heating and axisymmetric gas-phase convection. A simplified liquid-phase model has been obtained based on the assumption of the existence of a Hill's spherical vortex inside the droplet together with some approximations made in the governing diffusion equation. The use of the simplified model in a spray situation has also been examined. It has been found that droplet heating and vaporization are essentially unsteady and droplet temperature is nonuniform for a significant portion of its lifetime. It has also been found that the droplet vaporization characteristic can be quite sensitive to the particular liquid-phase and gas-phase models. The results of the various models are compared with the existing experimental data. Due to large scattering in the experimental measurements, particularly the droplet diameter, no definite conclusion can be drawn based on the experimental data. Finally, certain research problems which are related to the present study are suggested for future studies.

  19. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01T23:59:59.000Z

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  20. E-Print Network 3.0 - atmospheric water vapour Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas, and carbon dioxide (CO2) is the second... water vapour in the air that the greenhouse effect is very large, add- ing a small additional amount... of CO2 or water vapour has...

  1. ASHRAE Transactions: Research 3 A steady-state simulation model for a water-to-water

    E-Print Network [OSTI]

    ASHRAE Transactions: Research 3 ABSTRACT A steady-state simulation model for a water Reciprocating vapor compression heat pumps and chill- ers have been the target of a number of simulation models

  2. Subsurface capture of carbon dioxide

    DOE Patents [OSTI]

    Blount, Gerald; Siddal, Alvin A.; Falta, Ronald W.

    2014-07-22T23:59:59.000Z

    A process and apparatus of separating CO.sub.2 gas from industrial off-gas source in which the CO.sub.2 containing off-gas is introduced deep within an injection well. The CO.sub.2 gases are dissolved in the, liquid within the injection well while non-CO.sub.2 gases, typically being insoluble in water or brine, are returned to the surface. Once the CO.sub.2 saturated liquid is present within the injection well, the injection well may be used for long-term geologic storage of CO.sub.2 or the CO.sub.2 saturated liquid can be returned to the surface for capturing a purified CO.sub.2 gas.

  3. Process for removing sulfur dioxide from flue gases

    SciTech Connect (OSTI)

    Robinson, M.W. Jr.

    1989-08-29T23:59:59.000Z

    This patent describes an improvement in a dry process for the removal of sulfur dioxide from flue gases by the addition thereto of hydrated lime containing sugar in a coal combustion unit, wherein the flue gases result from the combustion of a coal in a combustion chamber, and the flue gases are treated in an electrostatic precipitator prior to discharge to the atmosphere the improvement comprising: passing the flue gases, after the addition of the hydrated lime is of fine particles of a specific surface of 7 to 25 square meters per gram, through a conduit towards the electrostatic precipitator; and adding an aqueous media to the flue gases in the conduit in an amount to increase the water content of the flue gases and cool the same by evaporative cooling to a temperature no lower than 20{sup 0}F. about the dew point of the gas, so as to avoid forming water droplets in the gas, so as to prevent condensation of water therefrom.

  4. Industrial Heat Pumps Using Solid/Vapor Working Fluids

    E-Print Network [OSTI]

    Rockenfeller, U.

    INDUSTRIAL HEAT PUMPS USING SOLID/VAPOR WORKING FLUIDS Uwe Rockenfeller, Desert Research Institute, Boulder City, Nevada ABSTRACT Industrial heat pumps have the potential to reduce the operating costs of chemical and heat treating processes... with vapor re-compression recovery systems. The state-of-the-art heat pump equipment employing liquid/vapor working fluids fulfills the requirements only in some applications. The employment of solid/vapor complex compounds leads to 'nore cost effective...

  5. SIGMA-ALDRICH Material Safety Data Sheet

    E-Print Network [OSTI]

    Choi, Kyu Yong

    Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific N/A Viscosity N/A Vapor Density

  6. Aluminum Nitride Micro-Channels Grown via Metal Organic Vapor Phase Epitaxy for MEMs Applications

    SciTech Connect (OSTI)

    Rodak, L.E.; Kuchibhatla, S.; Famouri, P.; Ting, L.; Korakakis, D.

    2008-01-01T23:59:59.000Z

    Aluminum nitride (AlN) is a promising material for a number of applications due to its temperature and chemical stability. Furthermore, AlN maintains its piezoelectric properties at higher temperatures than more commonly used materials, such as Lead Zirconate Titanate (PZT) [1, 2], making AlN attractive for high temperature micro and nanoelectromechanical (MEMs and NEMs) applications including, but not limited to, high temperature sensors and actuators, micro-channels for fuel cell applications, and micromechanical resonators. This work presents a novel AlN micro-channel fabrication technique using Metal Organic Vapor Phase Epitaxy (MOVPE). AlN easily nucleates on dielectric surfaces due to the large sticking coefficient and short diffusion length of the aluminum species resulting in a high quality polycrystalline growth on typical mask materials, such as silicon dioxide and silicon nitride [3,4]. The fabrication process introduced involves partially masking a substrate with a silicon dioxide striped pattern and then growing AlN via MOVPE simultaneously on the dielectric mask and exposed substrate. A buffered oxide etch is then used to remove the underlying silicon dioxide and leave a free standing AlN micro-channel. The width of the channel has been varied from 5 m to 110 m and the height of the air gap from 130 nm to 800 nm indicating the stability of the structure. Furthermore, this versatile process has been performed on (111) silicon, c-plane sapphire, and gallium nitride epilayers on sapphire substrates. Reflection High Energy Electron Diffraction (RHEED), Atomic Force Microscopy (AFM), and Raman measurements have been taken on channels grown on each substrate and indicate that the substrate is influencing the growth of the AlN micro-channels on the SiO2 sacrificial layer.

  7. Modeling engine oil vaporization and transport of the oil vapor in the piston ring pack on internal combustion engines

    E-Print Network [OSTI]

    Cho, Yeunwoo, 1973-

    2004-01-01T23:59:59.000Z

    A model was developed to study engine oil vaporization and oil vapor transport in the piston ring pack of internal combustion engines. With the assumption that the multi-grade oil can be modeled as a compound of several ...

  8. Oceanic Trace Gases Numeric Data Packages from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Most data sets or packages, many with numerous data files, are free to download from CDIAC's ftp area. CDIAC lists the following numeric data packages under the broad heading of Oceanic Trace Gases: Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16S_2005 ( 01/11/05 - 022405) Determination of Carbon Dioxide, Hydrographic, and Chemical Parameters during the R/V Nathaniel B. Palmer Cruise in the Southern Indian Ocean (WOCE Section S04I, 050396 - 070496) Inorganic Carbon, Nutrient, and Oxygen Data from the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16N_2003a (060403 081103) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Maurice Ewing Cruise in the Atlantic Ocean (WOCE Section A17, 010494 - 032194) Global Ocean Data Analysis Project GLODAP: Results and Data Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruises in the North Atlantic Ocean on WOCE Sections AR24 (1102 120596) and A24, A20, and A22 (053097 090397) Carbon Dioxide, Hydrographic and Chemical Data Obtained During the Nine R/V Knorr Cruises Comprising the Indian Ocean CO2 Survey (WOCE Sections I8SI9S, I9N, I8NI5E, I3, I5WI4, I7N, I1, I10, and I2; 120 194 012296) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Meteor Cruise 28/1 in the South Atlantic Ocean (WOCE Section A8, 032994 - 051294) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruise 138-3, -4, and -5 in the South Pacific Ocean (WOCE Sections P6E, P6C, and P6W, 050292 - 073092) Global Distribution of Total Inorganic Carbon and Total Alkalinity below the deepest winter mixed layer depths Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V John V. Vickers Cruise in the Pacific Ocean (WOCE Section P13, NOAA CGC92 Cruise, 080492 102192) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Hesperides Cruise in the Atlantic Ocean (WOCE Section A5, 071492 - 081592) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas G. Thompson Cruise in the Pacific Ocean (WOCE Section P10, 100593 111093) The International Intercomparison Exercise of Underway fCO2 Systems during the R/V Meteor Cruise 36/1 in the North Atlantic Ocean Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Meteor Cruise 22/5 in the South Atlantic Ocean (WOCE Section A10, Dec. 1992-Jan, 1993) Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the South Pacific Ocean (WOCE Sections P16A/P17A, P17E/P19S, and P19C, R/V Knorr , Oct. 1992-April 1993) Surface Water and Atmospheric Underway Carbon Data Obtained During the World Ocean Circulation Experiment Indian Ocean Survey Cruises (R/V Knorr, Dec. 1994 Jan, 1996) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Akademik Ioffe Cruise in the South Pacific Ocean (WOCE Section S4P, Feb.-April 1992) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-1 in the Equatorial Pacific Ocean (WOCE section P17C) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-3 in the Equatorial Pacific Ocean (WOCE section P16C) Carbon-14 Measurements in Surface Water CO2 from the Atlantic, Indian and Pacific Oceans, 1965-1994 Carbon Dioxide, Hydrographic, and Chemical Data Obtained During R/V Meteor Cruise 18/1 in the North Atlantic Ocean (WOCE Section A1E) Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the Central South Pacific Ocean (WOCE Sections P17S and P16S) during the TUNES-2 Expedition of the R/V Th

  9. High-Quality Epitaxy of Ruthenium Dioxide, RuO2, on Rutile Titanium Dioxide, TiO2, by Pulsed Chemical Vapor Deposition

    E-Print Network [OSTI]

    of rutile TiO2, a material with a high dielectric constant. Therefore, capacitors with high capacitance per these capacitors have low leakage current. Due to its good redox properties, RuO2 has been made into electrodes films have been made by CVD, such as wide-gap semiconductors ZnO23,25 and SnO2,26,27 super- conducting

  10. The interaction of flow, heat transfer, and free interfaces in an electron-beam vaporization system for metals

    SciTech Connect (OSTI)

    Westerberg, K.W. [Aspen Technology, Inc., Cambridge, MA (United States); McClelland, M.A. [Lawrence Livermore National Lab., CA (United States); Finlayson, B.A. [Univ. of Washington, Seattle, WA (United States)

    1994-11-01T23:59:59.000Z

    A numerical analysis is made of the liquid flow and energy transport in a system to vaporize metals. The energy from an electron beam heats metal confined in a water-cooled crucible. Metal vaporizes from a hot pool of circulating liquid which is surrounded by a shell of its own solid. Flow in the pool is strongly driven by temperature-induced buoyancy and capillary forces and is located in the transition region between laminar and turbulent flow. At high vaporization rates, the thrust of the departing vapor forms a trench at the beam impact site. A modified finite element method is used to calculate the flow and temperature fields coupled with the interface locations. The mesh is structured with spines that stretch and pivot as the interfaces move. The discretized equations are arranged in an {open_quotes}arrow{close_quotes} matrix and solved using the Newton-Raphson method. The electron-beam power and width are varied for cases involving the high-rate vaporization of aluminum. Attention is focused on the interaction of vaporization, liquid flow, and heat transport in the trench area.

  11. Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy

    E-Print Network [OSTI]

    Medina, David Salvador

    2011-01-01T23:59:59.000Z

    A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

  12. Anisotropic reactive ion etching of vanadium dioxide

    E-Print Network [OSTI]

    Radle, Byron K

    1990-01-01T23:59:59.000Z

    . Weichold Vanadium dioxide (V02) was anisotropically reactive ion etched using carbon tetrafluoride (CF4) . CF4, as an etch gas, provided the chemistry along with the control needed to achieve an anisotropic etch. This chemistry was practically inert... with vanadium quite easily. This leads to interest in using a fluorine- based chemistry. The goal of this research is to produce a selective anisotropic reactive ion etch for VO2 /photoresist using only carbon tetrafluoride (CFq) . Reactive ion etching...

  13. Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

    SciTech Connect (OSTI)

    Garcia, Julio Enrique

    2003-12-18T23:59:59.000Z

    Injection of carbon dioxide (CO{sub 2}) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO{sub 2} will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO{sub 2} and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO{sub 2}-H{sub 2}O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO{sub 2}. The basic problem of CO{sub 2} injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO{sub 2} injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO{sub 2} injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO{sub 2}. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO{sub 2} into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO{sub 2}) the viscosity of carbon dioxide can be less than the viscosity of the aqueous phase by a factor of 15. Because of the lower viscosity, the CO{sub 2} displacement front will have a tendency towards instability. Preliminary simulation results show good agreement between classical instability solutions and numerical predictions of finger growth and spacing obtained using different gas/liquid viscosity ratios, relative permeability and capillary pressure models. Further studies are recommended to validate these results over a broader range of conditions.

  14. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C. (Wilmington, DE); Rocheleau, Richard E. (Wilmington, DE)

    1987-03-31T23:59:59.000Z

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.

  15. DuPont Chemical Vapor Technical Report

    SciTech Connect (OSTI)

    MOORE, T.L.

    2003-10-03T23:59:59.000Z

    DuPont Safety Resources was tasked with reviewing the current chemical vapor control practices and providing preventive recommendations on best commercial techniques to control worker exposures. The increased focus of the tank closure project to meet the 2024 Tri-Party Agreement (TPA) milestones has surfaced concerns among some CH2MHill employees and other interested parties. CH2MHill is committed to providing a safe working environment for employees and desires to safely manage the tank farm operations using appropriate control measures. To address worker concerns, CH2MHill has chartered a ''Chemical Vapors Project'' to integrate the activities of multiple CH2MHill project teams, and solicit the expertise of external resources, including an independent Industrial Hygiene expert panel, a communications consultant, and DuPont Safety Resources. Over a three-month time period, DuPont worked with CH2MHill ESH&Q, Industrial Hygiene, Engineering, and the independent expert panel to perform the assessment. The process included overview presentations, formal interviews, informal discussions, documentation review, and literature review. DuPont Safety Resources concluded that it is highly unlikely that workers in the tank farms are exposed to chemicals above established standards. Additionally, the conventional and radiological chemistry is understood, the inherent chemical hazards are known, and the risk associated with chemical vapor exposure is properly managed. The assessment highlighted management's commitment to addressing chemical vapor hazards and controlling the associated risks. Additionally, we found the Industrial Hygiene staff to be technically competent and well motivated. The tank characterization data resides in a comprehensive database containing the tank chemical compositions and relevant airborne concentrations.

  16. Modeling of LNG Pool Spreading and Vaporization

    E-Print Network [OSTI]

    Basha, Omar 1988-

    2012-11-20T23:59:59.000Z

    ..................................................................................... 15 Figure 5: 90 mol% Methane 10mol% Ethane mixture VLE phase envelope .................. 18 Figure 6: Boiling temperature and vapor composition of 90 mol% methane 10mol% ethane mixture... process of natural gas allows a 600 fold reduction in the volume of the gas being transported at ambient pressure. The resulting liquid which is mainly composed of methane presents some hazardous properties linked to its flammable nature and its...

  17. Combined rankine and vapor compression cycles

    DOE Patents [OSTI]

    Radcliff, Thomas D.; Biederman, Bruce P.; Brasz, Joost J.

    2005-04-19T23:59:59.000Z

    An organic rankine cycle system is combined with a vapor compression cycle system with the turbine generator of the organic rankine cycle generating the power necessary to operate the motor of the refrigerant compressor. The vapor compression cycle is applied with its evaporator cooling the inlet air into a gas turbine, and the organic rankine cycle is applied to receive heat from a gas turbine exhaust to heat its boiler within one embodiment, a common condenser is used for the organic rankine cycle and the vapor compression cycle, with a common refrigerant, R-245a being circulated within both systems. In another embodiment, the turbine driven generator has a common shaft connected to the compressor to thereby eliminate the need for a separate motor to drive the compressor. In another embodiment, an organic rankine cycle system is applied to an internal combustion engine to cool the fluids thereof, and the turbo charged air is cooled first by the organic rankine cycle system and then by an air conditioner prior to passing into the intake of the engine.

  18. EBR-II Primary Tank Wash-Water Alternatives Evaluation

    SciTech Connect (OSTI)

    Demmer, R. L.; Heintzelman, J. B.; Merservey, R. H.; Squires, L. N.

    2008-05-01T23:59:59.000Z

    The EBR-II reactor at Idaho National Laboratory was a liquid sodium metal cooled reactor that operated for 30 years. It was shut down in 1994; the fuel was removed by 1996; and the bulk of sodium metal coolant was removed from the reactor by 2001. Approximately 1100 kg of residual sodium remained in the primary system after draining the bulk sodium. To stabilize the remaining sodium, both the primary and secondary systems were treated with a purge of moist carbon dioxide. Most of the residual sodium reacted with the carbon dioxide and water vapor to form a passivation layer of primarily sodium bicarbonate. The passivation treatment was stopped in 2005 and the primary system is maintained under a blanket of dry carbon dioxide. Approximately 670 kg of sodium metal remains in the primary system in locations that were inaccessible to passivation treatment or in pools of sodium that were too deep for complete penetration of the passivation treatment. The EBR-II reactor was permitted by the Idaho Department of Environmental Quality (DEQ) in 2002 under a RCRA permit that requires removal of all remaining sodium in the primary and secondary systems by 2022. The proposed baseline closure method would remove the large components from the primary tank, fill the primary system with water, react the remaining sodium with the water and dissolve the reaction products in the wash water. This method would generate a minimum of 100,000 gallons of caustic, liquid, low level radioactive, hazardous waste water that must be disposed of in a permitted facility. On February 19-20, 2008, a workshop was held in Idaho Falls, Idaho, to look at alternatives that could meet the RCRA permit clean closure requirements and minimize the quantity of hazardous waste generated by the cleanup process. The workshop convened a panel of national and international sodium cleanup specialists, subject matter experts from the INL, and the EBR-II Wash Water Project team that organized the workshop. The workshop was conducted by a trained facilitator using Value Engineering techniques to elicit the most technically sound solutions from the workshop participants. The path forward includes developing the OBA into a well engineered solution for achieving RCRA clean closure of the EBR-II Primary Reactor Tank system. Several high level tasks are also part of the path forward such as reassigning responsibility of the cleanup project to a dedicated project team that is funded by the DOE Office of Environmental Management, and making it a priority so that adequate funding is available to complete the project. Based on the experience of the sodium cleanup specialists, negotiations with the DEQ will be necessary to determine a risk-based de minimus quantity for acceptable amount of sodium that can be left in the reactor systems after cleanup has been completed.

  19. A mini review on the chemistry and catalysis of the water gas shift reaction

    E-Print Network [OSTI]

    Zhao, Zhun

    2014-01-01T23:59:59.000Z

    Water gas shift (WGS) reaction is a chemical reaction in which carbon monoxide reacts with water vapor to form carbon dioxide and hydrogen. It is an important reaction industrially used in conjunction with steam reforming of hydrocarbons for the production of high purity hydrogen. Grenoble et al examined the roles of both active metals and metal oxide support on the kinetics of the WGS reaction. They found out that the turn over numbers of various Al2O3 supported transition metals decreased in the trend of Cu, Re, Co, Ru, Ni, Pt, Os, Au, Fe, Pd, Rh, and Ir, which corresponds nicely to the observed volcano shaped correlation between catalytic activities and respective CO adsorption heat. This is a strong indication that CO gets activated on the metal surface during the reaction and different metals have different activation energies. The authors also observed that the turn over number of Pt/Al2O3 was one order of magnitude higher than that of Pt/SiO2, indicating a strong support effect, which the authors ascri...

  20. Henry's Law Constants of Methane, Nitrogen, Oxygen and Carbon Dioxide in Ethanol from 273 to 498 K: Prediction from Molecular Simulation

    E-Print Network [OSTI]

    Schnabel, T; Hasse, H

    2009-01-01T23:59:59.000Z

    noindent Henry's law constants of the solutes methane, nitrogen, oxygen and carbon dioxide in the solvent ethanol are predicted by molecular simulation. The molecular models for the solutes are taken from previous work. For the solvent ethanol, a new rigid anisotropic united atom molecular model based on Lennard-Jones and Coulombic interactions is developed. It is adjusted to experimental pure component saturated liquid density and vapor pressure data. Henry's law constants are calculated by evaluating the infinite dilution residual chemical potentials of the solutes from 273 to 498K with Widom's test particle insertion. The prediction of Henry's Law constants without the use of binary experimental data on the basis of the Lorentz-Berthelot combining rule agree well with experimental data, deviations are 20%, except for carbon dioxide for which deviations of 70% are reached. Quantitative agreement is achieved by using the modified Lorentz-Berthelot combining rule which is adjusted to one experimental mixture ...

  1. Gel and process for preventing carbon dioxide break through

    SciTech Connect (OSTI)

    Sandiford, B.B.; Zillmer, R.C.

    1987-06-16T23:59:59.000Z

    A process is described for retarding the flow of carbon dioxide in carbon dioxide break-through fingers in a subterranean formation, the process comprising: (a) introducing a gas selected from the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers; (b) after the carbon dioxide break-through fingers have sorbed a predetermined amount of the gas, stopping the flow of the gas into the subterranean formation, (c) after stopping the flow of the gas into the subterranean formation, introducing an effective amount of a gel-forming composition into the subterranean formation and into the carbon dioxide break-through fingers, the gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing the brine which has absorbed substantial amounts of carbon dioxide to form a gel in the fingers which is operable for retarding the flow of the gas in the finger. The gel-forming composition comprises: i. an aqueous solution comprising a first substance selected from the group consisting of polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, and ii. an amount of a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof.

  2. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    dioxide impact of electricity consumption in different majorand residential electricity consumption. Car usage and homefor fuel oil and electricity consumption. We then use

  3. Carbon dioxide absorbent and method of using the same

    SciTech Connect (OSTI)

    Perry, Robert James; O'Brien, Michael Joseph

    2014-06-10T23:59:59.000Z

    In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.

  4. Carbon Dioxide Capture and Storage Demonstration in Developing...

    Open Energy Info (EERE)

    Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key Policy Issues and Barriers...

  5. assisted silicon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide substrates is described. The approach consists of solid such as displays and thin-film polycrystalline solar cells. Particularly important for low- cost thin-film solar...

  6. Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report

    SciTech Connect (OSTI)

    Sinskey, Anthony J. [MIT] [MIT; Worden, Robert Mark [Michigan State University MSU] [Michigan State University MSU; Brigham, Christopher [MIT] [MIT; Lu, Jingnan [MIT] [MIT; Quimby, John Westlake [MIT] [MIT; Gai, Claudia [MIT] [MIT; Speth, Daan [MIT] [MIT; Elliott, Sean [Boston University] [Boston University; Fei, John Qiang [MIT] [MIT; Bernardi, Amanda [MIT] [MIT; Li, Sophia [MIT] [MIT; Grunwald, Stephan [MIT] [MIT; Grousseau, Estelle [MIT] [MIT; Maiti, Soumen [MSU] [MSU; Liu, Chole [MSU] [MSU

    2013-12-16T23:59:59.000Z

    This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation CalvinBensonBassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol.

  7. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    with sulfuric and nitric acids formed from at- mospheric oxidations of sulfur dioxide SO2 and nitrogen oxides mobile sources comes from the combustion of sulfur compounds in fuel. The U.S. is in the process of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  8. Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)

    E-Print Network [OSTI]

    Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

  9. 6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures

    E-Print Network [OSTI]

    Cohen, Ronald C.

    6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

  10. Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates

    E-Print Network [OSTI]

    Haak, Hein

    Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

  11. A Vortex Contactor for Carbon Dioxide Separations

    SciTech Connect (OSTI)

    Raterman, Kevin Thomas; Mc Kellar, Michael George; Turner, Terry Donald; Podgorney, Anna Kristine; Stacey, Douglas Edwin; Stokes, B.; Vranicar, J.

    2001-05-01T23:59:59.000Z

    Many analysts identify carbon dioxide (CO2) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA) Greenhouse Gas Research and Development Programme cited separation costs from $35 to $264 per tonne of CO2 avoided for a conventional coal fired power plant utilizing existing capture technologies. Because these costs equate to a greater than 40% increase in current power generation rates, it appears obvious that a significant improvement in CO2 separation technology is required if a negative impact on the world economy is to be avoided.

  12. Capture of Carbon Dioxide Archived Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route BTRICGEGR-N-Capture of Carbon Dioxide Archived

  13. Electrochemical formation of hydroxide for enhancing carbon dioxide and acid gas uptake by a solution

    DOE Patents [OSTI]

    Rau, Gregory Hudson (Castro Valley, CA)

    2012-05-15T23:59:59.000Z

    A system is described for forming metal hydroxide from a metal carbonate utilizing a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate, in particular water-insoluble calcium carbonate or magnesium carbonate, is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide. Among other uses, the metal hydroxide formed can be employed to absorb acid gases such as carbon dioxide from a gas mixture. The invention can also generate hydrogen and oxidative gases such as oxygen or chlorine.

  14. Ch.9 Water Resources ! Hydrologic cycle

    E-Print Network [OSTI]

    Pan, Feifei

    Energy Balance G Ts Td H LE Q t = Rn - LE - H - G where Q/t is the heat storage change of soil column in the liquid or solid phase at or near the land surface becomes water vapor. Water Bare soil Vegetated of the water molecules to a solid surface (e.g., soil or glass). #12;A simple soil-water-balance equation

  15. Simulation of natural corrosion by vapor hydration test: seven-year results

    SciTech Connect (OSTI)

    Luo, J.S.; Ebert, W.L.; Mazer, J.J.; Bates, J.K.

    1996-12-31T23:59:59.000Z

    We have investigated the alteration behavior of synthetic basalt and SRL 165 borosilicate waste glasses that had been reacted in water vapor at 70 {degrees}C for time periods up to seven years. The nature and extent of corrosion of glasses have been determined by characterizing the reacted glass surface with optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive x-ray spectroscopy (EDS). Alteration in 70 {degrees}C laboratory tests was compared to that which occurs at 150-200 {degrees}C and also with Hawaiian basaltic glasses of 480 to 750 year old subaerially altered in nature. Synthetic basalt and waste glasses, both containing about 50 percent wt SiO{sub 2} were found to react with water vapor to form an amorphous hydrated gel that contained small amounts of clay, nearly identical to palagonite layers formed on naturally altered basaltic glass. This result implies that the corrosion reaction in nature can be simulated with a vapor hydration test. These tests also provide a means for measuring the corrosion kinetics, which are difficult to determine by studying natural samples because alteration layers have often spelled off the samples and we have only limited knowledge of the conditions under which alteration occurred.

  16. Method and apparatus for concentrating vapors for analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2012-06-05T23:59:59.000Z

    A pre-concentration device and a method are disclosed for concentrating gaseous vapors for analysis. Vapors sorbed and concentrated within the bed of the pre-concentration device are thermally desorbed, achieving at least partial separation of the vapor mixtures. The pre-concentration device is suitable, e.g., for pre-concentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable.

  17. Chemical vapor deposition of epitaxial silicon

    DOE Patents [OSTI]

    Berkman, Samuel (Florham Park, NJ)

    1984-01-01T23:59:59.000Z

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  18. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

    1996-01-01T23:59:59.000Z

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  19. Storing images in warm atomic vapor

    E-Print Network [OSTI]

    M. Shuker; O. Firstenberg; R. Pugatch; A. Ron; N. Davidson

    2008-06-17T23:59:59.000Z

    Reversible and coherent storage of light in atomic medium is a key-stone of future quantum information applications. In this work, arbitrary two-dimensional images are slowed and stored in warm atomic vapor for up to 30 $\\mu$s, utilizing electromagnetically induced transparency. Both the intensity and the phase patterns of the optical field are maintained. The main limitation on the storage resolution and duration is found to be the diffusion of atoms. A techniqueanalogous to phase-shift lithography is employed to diminish the effect of diffusion on the visibility of the reconstructed image.

  20. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09T23:59:59.000Z

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  1. Mercury Vapor (Kooten, 1987) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(MonasterLowellisMcDonald isMelletteEnclosed andEnergySolar SystemsVapor

  2. Review of enhanced vapor diffusion in porous media

    SciTech Connect (OSTI)

    Webb, S.W.; Ho, C.K.

    1998-08-01T23:59:59.000Z

    Vapor diffusion in porous media in the presence of its own liquid has often been treated similar to gas diffusion. The gas diffusion rate in porous media is much lower than in free space due to the presence of the porous medium and any liquid present. However, enhanced vapor diffusion has also been postulated such that the diffusion rate may approach free-space values. Existing data and models for enhanced vapor diffusion, including those in TOUGH2, are reviewed in this paper.

  3. Recovery of benzene in an organic vapor monitor

    E-Print Network [OSTI]

    Krenek, Gregory Joel

    1980-01-01T23:59:59.000Z

    solid adsorbents available (silica gel, activated alumina, etc. ), activated charcoal is most frequently utilized. Activated charcoal has retentivity for sorbed vapors several times that of silica gel and it displays a selectivity for organic vapors... (diffusion rate) of the vapor molecules to the sur- face of the adsorbent. The adsorption process determine how effective the adsorbent collects and holds the contam- inant on the surface of the activated charcoal. Recovery of the contaminant from...

  4. Vaporizer design criteria for ethanol fueled internal combustion engines

    E-Print Network [OSTI]

    Ariyaratne, Arachchi Rallage

    2012-06-07T23:59:59.000Z

    . Stout (Member) L r x ge Edwa d A. Hiler (Head of Department) May 1985 ABSTRACT Vaporizer Design Criteria For Ethanol Fueled Internal Combustion Engines. (May 1985) Arachchi Rallage Ariyaratne, B. S. , University of Sri Lanka Chairman... VAPORIZATION LENGTH WITH UNIFORM HEAT FLUX 8 POLYNOMIAL FUNCTIONS FOR EVALUATING PARAMETERS C VARIATION OF HEAT FLUX AND AVERAGE SURFACE TEMPARATURE D PROGRAM FOR PREDICTING VAPORIZATION LENGTH 73 75 78 80 VITA 87 LIST OF TABLES TABLE Page 1...

  5. Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum cascade laser

    E-Print Network [OSTI]

    Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum: Faraday Rotation Spectroscopy, external-cavity quantum cascade laser, nitrogen dioxide, trace

  6. ORNL/CDIAC-143 CARBON DIOXIDE, HYDROGRAPHIC, AND CHEMICAL DATA OBTAINED DURING THE

    E-Print Network [OSTI]

    Kozyr Carbon Dioxide Information Analysis Center Oak Ridge National Laboratory Oak Ridge, Tennessee, U Prepared by the Carbon Dioxide Information Analysis Center OAK RIDGE NATIONAL LABORATORY Oak Ridge

  7. E-Print Network 3.0 - applied carbon dioxide Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 By-Products Utilization Summary: Center for By-Products Utilization DRAFT REPORT CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS... -MILWAUKEE 12;CARBON DIOXIDE...

  8. E-Print Network 3.0 - american carbon dioxide Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 By-Products Utilization Summary: Center for By-Products Utilization DRAFT REPORT CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS... -MILWAUKEE 12;CARBON DIOXIDE...

  9. E-Print Network 3.0 - air carbon dioxide Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: . The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet... . Carbon dioxide gas is the principal greenhouse...

  10. ORNL/CDIAC-34 Carbon Dioxide Information Analysis Center and

    E-Print Network [OSTI]

    Research U.S. Department of Energy Budget Activity Number KP 12 04 01 0 Prepared by the Carbon Dioxide. Burtis Carbon Dioxide Information Analysis Center Environmental Sciences Division Publication No. 4777's (DOE) Environmental Sciences Division, Office of Biological and Environmental Research (OBER

  11. World Energy Consumption and Carbon Dioxide Emissions: 1950 2050

    E-Print Network [OSTI]

    -U" relation with a within- sample peak between carbon dioxide emissions (and energy use) per capita and perWorld Energy Consumption and Carbon Dioxide Emissions: 1950 2050 Richard Schmalensee, Thomas M capita income. Using the income and population growth assumptions of the Intergovernmental Panel

  12. Method for synthesis of titanium dioxide nanotubes using ionic liquids

    SciTech Connect (OSTI)

    Qu, Jun; Luo, Huimin; Dai, Sheng

    2013-11-19T23:59:59.000Z

    The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

  13. Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    i Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Topical Report Prepared Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Ross Edward Dugas, M capture using monoethanolamine (MEA). MEA is an appropriate choice for a baseline study since

  14. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

  15. Carbon Dioxide Capture DOI: 10.1002/anie.200902836

    E-Print Network [OSTI]

    Paik Suh, Myunghyun

    Carbon Dioxide Capture DOI: 10.1002/anie.200902836 Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks** Hye-Sun Choi and Myunghyun Paik Suh* Carbon dioxide capture has been warming, and the development of efficient methods for capturing CO2 from industrial flue gas has become

  16. The surface science of titanium dioxide Ulrike Diebold*

    E-Print Network [OSTI]

    Diebold, Ulrike

    The surface science of titanium dioxide Ulrike Diebold* Department of Physics, Tulane University, New Orleans, LA 70118, USA Manuscript received in final form 7 October 2002 Abstract Titanium dioxide is reviewed on the adsorption and reaction of a wide variety of inorganic molecules (H2, O2, H2O, CO, CO2, N2

  17. Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear"

    E-Print Network [OSTI]

    Rust, Bert W.

    Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear" Bert W. Rust Mathematical- tioned the connection between global warming and increasing atmospheric carbon dioxide by pointing out of these plots to global warming have spilled over to the real world, inviting both praise [4, 17] and scorn [15

  18. Exhaust Gas Sensor Based On Tin Dioxide For Automotive Application

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Exhaust Gas Sensor Based On Tin Dioxide For Automotive Application Arthur VALLERON a,b , Christophe, Engineering Materials Department The aim of this paper is to investigate the potentialities of gas sensor based on semi-conductor for exhaust gas automotive application. The sensing element is a tin dioxide

  19. Carbon dioxide sequestration in concrete in different curing environments

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Carbon dioxide sequestration in concrete in different curing environments Y.-m. Chun, T.R. Naik, USA ABSTRACT: This paper summarizes the results of an investigation on carbon dioxide (CO2) sequestration in concrete. Concrete mixtures were not air entrained. Concrete mixtures were made containing

  20. Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall loading. The absorption rate did not follow pseudo first-order beha®ior except at ®ery low loading. All

  1. Development of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle

    E-Print Network [OSTI]

    Zimmer, Uwe

    stage to prevent potential danger to workforce and material, and carbon capture and sequestration (CCSDevelopment of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle Florian Poppa and Uwe the development of a carbon dioxide (CO2) sensing rotorcraft unmanned aerial vehicle (RUAV) and the experiences

  2. Carbon dioxide emission during forest fires ignited by lightning

    E-Print Network [OSTI]

    Magdalena Pelc; Radoslaw Osuch

    2009-03-31T23:59:59.000Z

    In this paper we developed the model for the carbon dioxide emission from forest fire. The master equation for the spreading of the carbon dioxide to atmosphere is the hyperbolic diffusion equation. In the paper we study forest fire ignited by lightning. In that case the fores fire has the well defined front which propagates with finite velocity.

  3. VOLUME 93 NUMBER 23 5 JUNE 2012

    E-Print Network [OSTI]

    and were designed to track pollutant gases such as sulfur dioxide, ozone, nitric acid, and nitrogen dioxide, rainfall, and the concentration of car- bon dioxide [New et al., 1999; Tans et al., 1996 regional networks together to measure the fluxes of carbon dioxide, water vapor, and sen- sible heat

  4. Mercury Vapor At Lassen Volcanic National Park Area (Varekamp...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lassen Volcanic National Park Area (Varekamp & Buseck, 1983) Exploration...

  5. Carbon dioxide absorbent and method of using the same

    DOE Patents [OSTI]

    Perry, Robert James (Niskayuna, NY); Lewis, Larry Neil (Scotia, NY); O'Brien, Michael Joseph (Clifton Park, NY); Soloveichik, Grigorii Lev (Latham, NY); Kniajanski, Sergei (Clifton Park, NY); Lam, Tunchiao Hubert (Clifton Park, NY); Lee, Julia Lam (Niskayuna, NY); Rubinsztajn, Malgorzata Iwona (Ballston Spa, NY)

    2011-10-04T23:59:59.000Z

    In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

  6. Global Climate Modeling of the Martian water cycle with improved microphysics and radiatively active water ice clouds

    E-Print Network [OSTI]

    Navarro, Thomas; Forget, Franois; Spiga, Aymeric; Millour, Ehouarn; Montmessin, Franck

    2013-01-01T23:59:59.000Z

    Radiative effects of water ice clouds have noteworthy consequences on the Martian atmosphere, its thermal structure and circulation. Accordingly, the inclusion of such effects in the LMD Mars Global Climate Model (GCM) greatly modifies the simulated Martian water cycle. The intent of this paper is to address the impact of radiatively active clouds on atmospheric water vapor and ice in the GCM and improve its representation. We propose a new enhanced modeling of the water cycle, consisting of detailed cloud microphysics with dynamic condensation nuclei and a better implementation of perennial surface water ice. This physical modeling is based on tunable parameters. This new version of the GCM is compared to the Thermal Emission Spectrometer observations of the water cycle. Satisfying results are reached for both vapor and cloud opacities. However, simulations yield a lack of water vapor in the tropics after Ls=180{\\deg} which is persistent in simulations compared to observations, as a consequence of aphelion c...

  7. Water, Sun, Energy | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and Materials Disposition3 Water Vapor ExperimentIrrigatingWater,

  8. The control of confined vapor phase explosions

    SciTech Connect (OSTI)

    Scilly, N.F. [Laporte plc, Widnes (United Kingdom); Owen, O.J.R. [Fine Organics, Ltd., Middlesborough (United Kingdom); Wilberforce, J.K. [Solvay SA, Brussels (Belgium)

    1995-12-31T23:59:59.000Z

    The probability of, for example, a fire or explosion occurring during a process operation is related both to the fire-related properties of the materials used, such as flash point, flammable limits etc., i.e. the material or intrinsic factors, and the nature of the operation and the equipment used, i.e. the extrinsic factors. The risk, or frequency of occurrence, of other hazards such as reaction runaway, major toxic release etc. can be determined in a similar manner. For a vapor phase explosion (and a fire) the probability of the event is the product of the probability of generating a flammable atmosphere and the probability of ignition. Firstly, materials may be coded using properties that are relevant to the hazard in question. Secondly, different operations have different degrees of risk and these risks are assigned as Low, Medium, High etc. according to criteria outlined here. Combination of these two factors will then be a measure of the overall risk of the operation with the specified material and may be used to define operating standards. Currently, the hazard/risk of a vapor phase explosions is examined by this method but in due course dust explosions, fires, condensed phase explosions, reaction runaways, physical explosions, major toxic releases and incompatibility will be included.

  9. Vapor and gas sampling of Single-Shell Tank 241-T-111 using the vapor sampling system

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-09-01T23:59:59.000Z

    This document presents sampling data resulting from the January 20, 1995, sampling of SST 241-T-111 using the vapor sampling system.

  10. Vapor and gas sampling of single-shell tank 241-BY-112 using the vapor sampling system

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-09-20T23:59:59.000Z

    This document presents sampling data from the November 18, 1994, sampling of SST 241-BY-112 using the vapor sampling system.

  11. Vapor and gas sampling of Single-Shell Tank 241-A-101 using the Vapor Sampling System

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-11-01T23:59:59.000Z

    This document presents sampling data resulting from the June 8, 1995, sampling of SST 241-A-101 using the Vapor Sampling System.

  12. Dynamic characteristics of gas-water interfacial plasma under water

    SciTech Connect (OSTI)

    Zheng, S. J.; Zhang, Y. C.; Ke, B.; Ding, F.; Tang, Z. L.; Yang, K.; Zhu, X. D. [Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2012-06-15T23:59:59.000Z

    Gas-water interfacial plasmas under water were generated in a compact space in a tube with a sandglass-like structure, where two metal wires were employed as electrodes with an applied 35 kHz ac power source. The dynamic behaviors of voltage/current were investigated for the powered electrode with/without water cover to understand the effect of the gas-water interface. It is found that the discharge exhibits periodic pulsed currents after breakdown as the powered electrode is covered with water, whereas the electrical current reveals a damped oscillation with time with a frequency about 10{sup 6} Hz as the powered electrode is in a vapor bubble. By increasing water conductivity, a discharge current waveform transition from pulse to oscillation presents in the water covering case. These suggest that the gas-water interface has a significant influence on the discharge property.

  13. Geothermal carbon dioxide for use in greenhouses

    SciTech Connect (OSTI)

    Dunstall, M.G. [Univ. of Auckland (New Zealand); Graeber, G. [Univ. of Stuttgart (Germany)

    1997-01-01T23:59:59.000Z

    Geothermal fluids often contain carbon dioxide, which is a very effective growth stimulant for plants in greenhouses. Studies have shown that as CO{sub 2} concentration is increased from a normal level of 300 ppm (mmol/kmol) to levels of approximately 1000 ppm crop yields may increase by up to 15% (Ullmann`s Encyclopedia of Industrial Chemistry, 1989). It is suggested that geothermal greenhouse heating offers a further opportunity for utilization of the carbon dioxide present in the fluid. The main difficulty is that plants react adversely to hydrogen sulphide which is invariably mixed, at some concentration, with the CO{sub 2} from geothermal fluids. Even very low H{sub 2}S concentrations of 0.03 mg/kg can have negative effects on the growth of plants (National Research Council, 1979). Therefore, an appropriate purification process for the CO{sub 2} must be used to avoid elevated H{sub 2}S levels in the greenhouses. The use of adsorption and absorption processes is proposed. Two purification processes have been modelled using the ASOEN PLUS software package, using the Geothermal Greenhouses Ltd. Operation Kawerau New Zealand and an example. A greenhouse area of 8,000 m{sup 2}, which would create a demand for approximately 20 kg CO{sub 2} per hour, was chosen based on a proposed expansion at Kawerau. The Kawerau operation currently takes geothermal steam (and gas) from a high temperature 2-phase well to heat an area of 1650 m{sup 2}. Bottled carbon dioxide is utilized at a rate of about 50 kg per day, to provide CO{sub 2} levels of 800 mg/kg when the greenhouse is closed and 300 to 350 mg/kg whilst venting. In England and the Netherlands, CO{sub 2} levels of 1000 mg/kg are often used (Ullmann`s Encyclopedia of Industrial Chemistry, 1989) and similar concentrations are desired at Kawerau, but current costs of 0.60 NZ$/kg for bottled CO{sub 2} are too high (Foster, 1995).

  14. Nitrogen dioxide and respiratory illness in children. Part II: Assessment of exposure to nitrogen dioxide

    SciTech Connect (OSTI)

    Lambert, W.E.; Samet, J.M.; Hunt, W.C.; Skipper, B.J.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

    1993-06-01T23:59:59.000Z

    Repeated measurements of nitrogen dioxide were obtained from 1988 to 1991 in the homes of 1,205 infants living in Albuquerque, NM. Passive diffusion samplers were used to obtain a series of two-week integrated measurements from the home of each infant for use in a cohort study of the relation of residential exposure to nitrogen dioxide and respiratory illnesses. Information on stove use and time spent inside the residence was collected at two-week and two-month intervals, respectively. During the winter, in the bedrooms of homes with gas cooking stoves, mean nitrogen dioxide concentrations were 21 parts per billion (ppb); mean concentrations in the living room and kitchen were 29 ppb and 34 ppb, respectively. In homes with electric cooking stoves, the mean bedroom concentration was 7 ppb during the winter. Lower indoor concentrations were observed during the summer in homes with both gas and electric stoves. On average, infants spent approximately 12.3 hours per day in their bedrooms, 7.3 hours in the living rooms, 35 minutes in the kitchens, and 3.8 hours out of their homes. (As a condition of participation, none of the infants spent more than 20 hours per week in day care outside of their homes). The mean time infants spent in the kitchen during cooking was approximately nine minutes per day. We tested whether exposures of infants living in homes with gas stoves could be reasonably estimated by measurements in the bedroom in comparison with time-weighted average concentrations based on time-activity data and simultaneous nitrogen dioxide measurements in the kitchen, living room, and bedroom. In 1,937 two-week intervals from 587 infants, 90% of time-weighted exposure (on the three-level classification used in this study) estimates were in agreement with estimates based on bedroom concentrations alone.

  15. Near-Infrared Spectroscopic Investigation of Water in Supercritical CO2 and the Effect of CaCl2

    SciTech Connect (OSTI)

    Wang, Zheming; Felmy, Andrew R.; Thompson, Christopher J.; Loring, John S.; Joly, Alan G.; Rosso, Kevin M.; Schaef, Herbert T.; Dixon, David A.

    2013-01-25T23:59:59.000Z

    Near-infrared (NIR) spectroscopy was applied to investigate the dissolution and chemical interaction of water dissolved into supercritical carbon dioxide (scCO2) and the influence of CaCl2 in the co-existing aqueous phase at fo empe e : 40 50 75 nd 100 C at 90 atm. Consistent with the trend of the vapor pressure of water, the solubility of pure water in scCO2 inc e ed f om 40 ?C (0.32 mole%) o 100 ?C (1.61 mole%). The presence of CaCl2 negatively affects the solubility of water in scCO2: at a given temperature and pressure the solubility of water decreased as the concentration of CaCl2 in the aqueous phase increased, following the trend of the activity of water. A 40 ?C, the water concentration in scCO2 in contact with saturated CaCl2 aqueous solution was only 0.16 mole%, a drop of more than 50% as compared to pure water while that a 100 ?C was 1.12 mole%, a drop of over 30% as compared to pure water, under otherwise the same conditions. Analysis of the spectral profiles suggested that water dissolved into scCO2 exists in the monomeric form under the evaluated temperature and pressure conditions, for both neat water and CaCl2 solutions. However, its rotational degrees of freedom decrease at lower temperatures due to higher fluid densities, leading to formation of weak H2O:CO2 Lewis acid-base complexes. Similarly, the nearly invariant spectral profiles of dissolved water in the presence and absence of saturated CaCl2 under the same experimental conditions was taken as evidence that CaCl2 dissolution in scCO2 was limited as the dissolved Ca2+/CaCl2 would likely be highly hydrated and would alter the overall spectra of waters in the scCO2 phase.

  16. Molten uranium dioxide structure and dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

    2014-11-20T23:59:59.000Z

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

  17. Carbon Dioxide Sequestration in Geologic Coal Formations

    SciTech Connect (OSTI)

    None

    2001-09-30T23:59:59.000Z

    BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

  18. Layered solid sorbents for carbon dioxide capture

    SciTech Connect (OSTI)

    Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

    2014-11-18T23:59:59.000Z

    A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

  19. The lifetime of excess atmospheric carbon dioxide

    SciTech Connect (OSTI)

    Moore, B. III; Braswell, B.H. (Univ. of New Hampshire, Durham, NH (United States))

    1994-03-01T23:59:59.000Z

    Since the beginning of the industrial revolution human activity has significantly altered biogeochemical cycling on a global scale. The uncertainties of future climate change rests partly on issues of physical-climate system dynamics and their representation in general circulation models. However understanding the carbon cycle is a key to comprehending the changing terrestrial biosphere and to developing a reasonable range of future concentrations of greenhouse gases. The authors look at correction of model uncertainties in the examination of the lifetime of carbon dioxide. The two difficulties analysed are as follows: (1) most model-derived estimates of the relaxation of the concentration of CO2 reveal a function which is not always well approximated by weighted sums of exponentials; (2) the function c(t) is quite sensitive to assumptions about the terrestrial biosphere and the relaxation experiment. 51 refs., 15 figs., 7 tabs.

  20. RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR

    E-Print Network [OSTI]

    Cronin, Alex D.

    RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR By SCOTT RUSSELL WAITUKAITIS A Thesis Submitted: #12;Abstract I describe a study of Faraday rotation in a hot lithium vapor. I begin by dis- cussing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.3 The Lithium Oven and Solenoid . . . . . . . . . . . . . . . . . 7 3 Theoretical Framework

  1. Chemical vapor detection with a multispectral thermal imager

    E-Print Network [OSTI]

    Chang, Chein-I

    Chemical vapor detection with a multispectral thermal imager Mark 1. G. Aithouse, MEMBER SPIE U.S. Army Chemical Research Development and Engineering Center SMCCR-DDT Aberdeen Proving Ground, Maryland algorithm 7. Conclusions 8. Acknowledgments 9. References 1. INTRODUCTION Detection of chemical vapor clouds

  2. Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-

    E-Print Network [OSTI]

    I BNL- 62834 Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-· [D VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY- A DISCUSSION OF TECHNICAL FEASIBILITY Concept MONEY --A DISCUSSION OF TECHNICAL FEASffiILITY Russell N. Dietz, Head Tracer Technology Center

  3. HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Licia M. Petkovic; Harry W. Rollins; Daniel M. Ginosar; Kyle C. Burch

    2006-09-01T23:59:59.000Z

    HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE Lucia M. Petkovic, Harry W. Rollins, Daniel M. Ginosar, and Kyle C. Burch Idaho National Laboratory P.O. Box 1625 Idaho Falls, ID 83415-2208 Introduction Anthropogenic emissions of carbon dioxide, a gas often associated with global warming, have increased considerably since the beginning of the industrial age.1 In the U.S., stationary CO2 sources, such as electricity generation plants, produce about one-third of the anthropogenic CO2 generation. Reports2 indicate that the power required to recover 90% of the CO2 from an integrated coal-fired power-plant is about 10% of the power-plant capacity. This energy requirement can be reduced to less than 1% if the recovered CO2 is applied to the production of synthetic fuels. However, the lack of efficient catalysts along with the costs of energy and hydrogen has prevented the development of technologies for direct hydrogenation of CO2.3 Although the cost of hydrogen for hydrogenating CO2 is not economically attractive at present, the future production of hydrogen by nuclear power sources could completely change this scenario.2 Still, an efficient catalyst will be essential for commercial application of those processes. The objective of the work presented here was the development of hybrid catalysts for one-step carbon dioxide hydrogenation to liquid fuels. The hybrid catalysts, which were prepared by two novel techniques, included a copper/zinc oxide catalytic function distributed within an acidic zeolitic matrix. Results of catalyst activity and selectivity studies at atmospheric pressure are presented in this contribution. Experimental Catalysts were prepared by two novel techniques and under several different conditions to produce copper/zinc oxide/zeolite materials. Once synthesized, samples were pelletized and the fraction between 40-60 mesh was utilized for the experiments. Two hundred milligrams of catalyst were loaded in a U-tube stainless steel reactor and a flow of 100 cm3/min of a 10:90 H2:Ar mixture was passed through the catalyst bed while the temperature was increased from room temperature to 513 K at 1.8 K/min and held at 513 K for 15 h. A reactant gas mixture composed by 10 cm3/min of CO2 and 30 cm3/min of H2 was then passed through the catalyst bed and the reaction products monitored by on-line gas chromatographic analyses using an SRI Multiple Gas Analyzer #2 equipped with 3 columns (MoleSieve 13X, Hayesep-D, and MXT-1) and 3 detectors (TCD, FID, and FID-methanizer). This GC system allowed for quantification of inert gases, CO, CO2, methanol, dimethylether, higher alcohols, water, and hydrocarbons up to C20. One hundred milligrams of a commercial syngas-to-methanol catalyst along with the same amount of a commercial zeolite catalyst was utilized under the same reaction conditions for comparison purposes. These catalysts were utilized either in two-layers (Com1) or mixed together (Com2). Results and Discussion Under the conditions applied in this study, the main reaction products were CO, CH3OH, CH3OCH3, and H2O. Methanol and dimethylether production rates and selectivities with respect to CO formation are presented in Figures 1 and 2, respectively. Although the activity of the synthesized catalysts did not surpass the commercial catalysts, the selectivity to oxygenates with respect to CO on most of the synthesized catalysts were better than on the commercial catalysts. For example, cat

  4. Analysis of electron-beam vaporization of refractory metals

    SciTech Connect (OSTI)

    Kheshgi, H.S.; Gresho, P.M.

    1986-09-01T23:59:59.000Z

    An electron beam is focussed onto a small area on the surface of a refractory metal to locally raise the temperature and vaporize metal. At high vaporization rates the hot area is on the surface of a churning liquid-metal pool contained in a solid-metal skull which sits in a cooled crucible. Inner workings of the process are revealed by analysis of momentum, energy, and mass transfer. At the surface high temperature causes high vaporization rate and high vapor thrust, depressing the vapor/liquid surface. In the liquid pool surface-tension gradients and thermal buoyancy drive a (typically) chaotic flow. In the solid skull thermal conductivity and contact resistance regulate the rate of heat transfer from pool to crucible. Analyses of these phenomena together reveal process performance sensitivities - e.g., to depression size or to magnitude of surface-tension gradients. 12 refs., 3 figs.

  5. Improvement of Carbon Dioxide Sweep Efficiency by Utilization of Microbial Permeability Profile Modification to Reduce the Amount of Oil Bypassed During Carbon Dioxide Flood

    SciTech Connect (OSTI)

    Darrel Schmitz; Lewis Brown F. Leo Lynch; Brenda Kirkland; Krystal Collins; William Funderburk

    2010-12-31T23:59:59.000Z

    The objective of this project was to couple microbial permeability profile modification (MPPM), with carbon dioxide flooding to improve oil recovery from the Upper Cretaceous Little Creek Oil Field situated in Lincoln and Pike counties, MS. This study determined that MPPM technology, which improves production by utilizing environmentally friendly nutrient solutions to simulate the growth of the indigenous microflora in the most permeable zones of the reservoir thus diverting production to less permeable, previously unswept zones, increased oil production without interfering with the carbon dioxide flooding operation. Laboratory tests determined that no microorganisms were produced in formation waters, but were present in cores. Perhaps the single most significant contribution of this study is the demonstration that microorganisms are active at a formation temperature of 115?C (239?F) by using a specially designed culturing device. Laboratory tests were employed to simulate the MPPM process by demonstrating that microorganisms could be activated with the resulting production of oil in coreflood tests performed in the presence of carbon dioxide at 66?C (the highest temperature that could be employed in the coreflood facility). Geological assessment determined significant heterogeneity in the Eutaw Formation, and documented relatively thin, variably-lithified, well-laminated sandstone interbedded with heavily-bioturbated, clay-rich sandstone and shale. Live core samples of the Upper Cretaceous Eutaw Formation from the Heidelberg Field, MS were quantitatively assessed using SEM, and showed that during MPPM permeability modification occurs ubiquitously within pore and throat spaces of 10-20 ?m diameter. Testing of the MPPM procedure in the Little Creek Field showed a significant increase in production occurred in two of the five production test wells; furthermore, the decline curve in each of the production wells became noticeably less steep. This project greatly extends the number of oil fields in which MPPM can be implemented.

  6. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21T23:59:59.000Z

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  7. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01T23:59:59.000Z

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  8. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15T23:59:59.000Z

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  9. Hybrid Vapor Compression Adsorption System: Thermal Storage Using Hybrid Vapor Compression Adsorption System

    SciTech Connect (OSTI)

    None

    2012-01-04T23:59:59.000Z

    HEATS Project: UTRC is developing a new climate-control system for EVs that uses a hybrid vapor compression adsorption system with thermal energy storage. The targeted, closed system will use energy during the battery-charging step to recharge the thermal storage, and it will use minimal power to provide cooling or heating to the cabin during a drive cycle. The team will use a unique approach of absorbing a refrigerant on a metal salt, which will create a lightweight, high-energy-density refrigerant. This unique working pair can operate indefinitely as a traditional vapor compression heat pump using electrical energy, if desired. The project will deliver a hot-and-cold battery that provides comfort to the passengers using minimal power, substantially extending the driving range of EVs.

  10. Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

    2003-06-03T23:59:59.000Z

    A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

  11. Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

    E-Print Network [OSTI]

    Dennis, J A

    1971-01-01T23:59:59.000Z

    Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

  12. Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy

    E-Print Network [OSTI]

    Yaghi, Omar M.

    , and carbon dioxide. Introduction Carbon dioxide emissions resulting from the burning of fossil fuels 20 metric tons of carbon dioxide per capita are released annually into the atmosphere.1a,b CarbonStorage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks

  13. M. Bahrami ENSC 461 (S 11) Vapor Power Cycles 1 Vapor Power Cycles

    E-Print Network [OSTI]

    Bahrami, Majid

    is not a suitable model for steam power cycle since: The turbine has to handle steam with low quality which steam is condensed in the condenser 4 3 1 2 s T 1 2 34 s #12;M. Bahrami ENSC 461 (S 11) Vapor Power = 0 qin = h3 ­ h2 Turbine q = 0 wturbine,out = h3 ­ h4 Condenser w = 0 qout = h4 ­ h1 The thermal

  14. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H. (Concord, MA)

    2006-02-21T23:59:59.000Z

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  15. Carbon and Greenhouse Gas Dynamics in Annual Grasslands: Effects of Management and Potential for Climate Change Mitigation

    E-Print Network [OSTI]

    Ryals, Rebecca

    2012-01-01T23:59:59.000Z

    2004. Carbon dioxide and water vapor exchange in a warmProgram. Land, Air, and Water Resources Paper 100028, Davis,effects. Journal of Soil and Water Conservation 62:77-85.

  16. Climate change will exacerbate Californias insect pest problems

    E-Print Network [OSTI]

    Trumble, John; Butler, Casey

    2009-01-01T23:59:59.000Z

    some plausible scenarios. Water Air Soil Poll 82:44554.when they breed in warmer water and must blood-feed morecarbon dioxide in also let water vapor out, and if there is

  17. E-Print Network 3.0 - aerosol-assisted chemical vapor Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Work to Prevent Chemical Warfare Agent Vapor Infiltration? John H. Sorensen Barbara M. Vogt Date... protection strategies to reduce exposure to vapors from chemical warfare...

  18. E-Print Network 3.0 - arc vapor deposition Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has been produced... al Vaporization and melting of materials in fusion devices 325 ENERGY DEPOSITED (Jcm21 Figure 3... VAPORIZATION AND MELTING OF MATERIALS IN FUSION...

  19. E-Print Network 3.0 - atomic vapor laser Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

  20. E-Print Network 3.0 - atom vapor cells Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

  1. E-Print Network 3.0 - advanced waste water Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the Swedish report "Frbrnning av avfall en Summary: in the plants, 90-95% of the dioxins in the waste are broken down into carbon dioxide, water and hydrogen... RVF - The...

  2. Multiple metrics for quantifying the intensity of water consumption of energy production

    E-Print Network [OSTI]

    Spang, E S

    Discussion of the environmental implications of worldwide energy demand is currently dominated by the effects of carbon dioxide (CO[subscript 2]) emissions on global climate. At the regional scale, however, water resource ...

  3. DESCRIPTIVE TEXT SEA WATER INORGANIC CARBON DATABASE

    E-Print Network [OSTI]

    DESCRIPTIVE TEXT SEA WATER INORGANIC CARBON DATABASE for the CARBON DIOXIDE INFORMATION OF OCEANOGRAPHY (SIO) I. GENERAL DESCRIPTION The database consists of tables presenting oceanic inorganic carbon, titration (total) alkalinity (database abbreviation: "ALK"), and the 13 C / 12 C isotopic ratio

  4. Improving the Thermal Output Availability of Reciprocating Engine Cogeneration Systems by Mechanical Vapor Compression

    E-Print Network [OSTI]

    Becker, F. E.; DiBella, F. A.; Lamphere, F.

    LOW?PRESSURE I WASTE STEAM r ... IMPROVING THE THERMAL OUTPUT AVAILABILITY OF RECIPROCATING ENGINE COGENERATION SYSTEMS BY MECHANICAL VAPOR COMPRESSION F.E. Becker and F.A. DiBella Tecogen, Inc., a Subsidiary of Thermo El~ctron Corporation...-user with electric power and process heat that is totally in the form of high-pressure steam. Current recipro cating engine systems can now provide only low pressure steam or hot water from the engine jacket, and this often is not needed or not the most appro...

  5. A study of the minimum meniscus radius as a function of vapor temperature using heat pipes

    E-Print Network [OSTI]

    Sonnier, Ronald James

    1973-01-01T23:59:59.000Z

    /sec 2 latent heat of vaporization, BTU/lb m wick permeability, ft 2 length, ft molecular weight, ibm water parameter, hf pfof/uf fgff f pressure, lbf/ft 2 desorption pressure, lbf/ft 2 saturation pressure, lbf/ft 2 heat transfer rate, BTU... into Cosgrove's equation, assuming the temperature is uni- form inside the heat pipe, replacing the sum of the section lengths by the total length of the heat pipe, and combining the fluid prop- erties into one var1able there is obtained N = hf pfof/uf...

  6. Density Profiles of Liquid/Vapor Interfaces Away from Their Critical Point

    E-Print Network [OSTI]

    Wei Bu; Doseok Kim; David Vaknin

    2014-04-28T23:59:59.000Z

    We examine the applicability of various model profiles for the liquid/vapor interface by X-ray reflectivities on water and ethanol and their mixtures at room temperature. Analysis of the X-ray reflecivities using various density profiles shows an error-function like profile is the most adequate within experimental error. Our finding, together with recent observations from simulation studies on liquid surfaces, strongly suggest that the capillary-wave dynamics shapes the interfacial density profile in terms of the error function.

  7. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

    1991-09-03T23:59:59.000Z

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  8. Haverford Researchers Create Carbon Dioxide-Separating Polymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford...

  9. Electrochemically-mediated amine regeneration for carbon dioxide separations

    E-Print Network [OSTI]

    Stern, Michael C. (Michael Craig)

    2014-01-01T23:59:59.000Z

    This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

  10. www.sciam.com SCIENTIFIC AMERICAN 49 Pumping carbon dioxide

    E-Print Network [OSTI]

    O'Donnell, Tom

    www.sciam.com SCIENTIFIC AMERICAN 49 CREDIT CanWe Bury GLOBAL WARMING? Pumping carbon dioxide is then pumped two kilometers below ground. COPYRIGHT 2005 SCIENTIFIC AMERICAN, INC. #12;adapt

  11. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01T23:59:59.000Z

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  12. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard

    1995-01-01T23:59:59.000Z

    Emissions of carbon dioxide form combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  13. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard.; Stoker, Thomas M.; Judson, Ruth A.

    Emissions of carbon dioxide from combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  14. Optical properties of nanostructured silicon-rich silicon dioxide

    E-Print Network [OSTI]

    Stolfi, Michael Anthony

    2006-01-01T23:59:59.000Z

    We have conducted a study of the optical properties of sputtered silicon-rich silicon dioxide (SRO) thin films with specific application for the fabrication of erbium-doped waveguide amplifiers and lasers, polarization ...

  15. Control strategies for supercritical carbon dioxide power conversion systems

    E-Print Network [OSTI]

    Carstens, Nathan, 1978-

    2007-01-01T23:59:59.000Z

    The supercritical carbon dioxide (S-C02) recompression cycle is a promising advanced power conversion cycle which couples well to numerous advanced nuclear reactor designs. This thesis investigates the dynamic simulation ...

  16. Mechanisms for mechanical trapping of geologically sequestered carbon dioxide

    E-Print Network [OSTI]

    Cohen, Yossi

    Carbon dioxide (CO[subscript 2]) sequestration in subsurface reservoirs is important for limiting atmospheric CO[subscript 2] concentrations. However, a complete physical picture able to predict the structure developing ...

  17. Ownership of Carbon Dioxide Captured by Clean Coal Project (Texas)

    Broader source: Energy.gov [DOE]

    This legislation stipulates that the Railroad Commission of Texas automatically acquires the title to any carbon dioxide captured by a clean coal project in the state. The Bureau of Economic...

  18. Carbon dioxide dissolution in structural and stratigraphic traps

    E-Print Network [OSTI]

    Hesse, M. A.

    The geologic sequestration of carbon dioxide (CO[subscript 2]) in structural and stratigraphic traps is a viable option to reduce anthropogenic emissions. While dissolution of the CO[subscript 2] stored in these traps ...

  19. Figure 3. Energy-Related Carbon Dioxide Emissions

    U.S. Energy Information Administration (EIA) Indexed Site

    3. Energy-Related Carbon Dioxide Emissions" " (million metric tons)" ,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024,2025,2026,2027,2028,...

  20. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD) by Microtops Atmospheric OpticalExperimentgovFieldgovDataPI Data ProductsMWR Retrievals of Cloud