Powered by Deep Web Technologies
Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Single Membrane Reactor Configuration for Separation of Hydrogen, Carbon Dioxide and Hydrogen Sulfide  

SciTech Connect (OSTI)

The objective of the project was to develop a novel complementary membrane reactor process that can consolidate two or more downstream unit operations of a coal gasification system into a single module for production of a pure stream of hydrogen and a pure stream of carbon dioxide. The overall goals were to achieve higher hydrogen production efficiencies, lower capital costs and a smaller overall footprint than what could be achieved by utilizing separate components for each required unit process/operation in conventional coal-to-hydrogen systems. Specifically, this project was to develop a novel membrane reactor process that combines hydrogen sulfide removal, hydrogen separation, carbon dioxide separation and water-gas shift reaction into a single membrane configuration. The carbon monoxide conversion of the water-gas-shift reaction from the coal-derived syngas stream is enhanced by the complementary use of two membranes within a single reactor to separate hydrogen and carbon dioxide. Consequently, hydrogen production efficiency is increased. The single membrane reactor configuration produces a pure H{sub 2} product and a pure CO{sub 2} permeate stream that is ready for sequestration. This project focused on developing a new class of CO{sub 2}-selective membranes for this new process concept. Several approaches to make CO{sub 2}-selective membranes for high-temperature applications have been tested. Membrane disks using the technique of powder pressing and high temperature sintering were successfully fabricated. The powders were either metal oxide or metal carbonate materials. Experiments on CO{sub 2} permeation testing were also performed in the temperature range of 790 to 940 C for the metal carbonate membrane disks. However, no CO{sub 2} permeation rate could be measured, probably due to very slow CO{sub 2} diffusion in the solid state carbonates. To improve the permeation of CO{sub 2}, one approach is to make membranes containing liquid or molten carbonates. Several different types of dual-phase membranes were fabricated and tested for their CO{sub 2} permeation in reducing conditions without the presence of oxygen. Although the flux was quite low, on the order of 0.01-0.001 cc STP/cm{sup 2}/min, the selectivity of CO{sub 2}/He was almost infinite at temperatures of about 800 C. A different type of dual-phase membrane prepared by Arizona State University (ASU) was also tested at GTI for CO{sub 2} permeation. The measured CO{sub 2} fluxes were 0.015 and 0.02 cc STP/cm{sup 2}/min at 750 and 830 C, respectively. These fluxes were higher than the previous flux obtained ({approx}0.01 cc STP/cm{sup 2}/min) using the dual-phase membranes prepared by GTI. Further development in membrane development should be conducted to improve the CO{sub 2} flux. ASU has also focused on high temperature permeation/separation experiments to confirm the carbon dioxide separation capabilities of the dual-phase membranes with La{sup 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF6482) supports infiltrated with a Li/Na/K molten carbonate mixture (42.5/32.5/25.0 mole %). The permeation experiments indicated that the addition of O{sub 2} does improve the permeance of CO{sub 2} through the membrane. A simplified membrane reactor model was developed to evaluate the performance of the process. However, the simplified model did not allow the estimation of membrane transport area, an important parameter for evaluating the feasibility of the proposed membrane reactor technology. As a result, an improved model was developed. Results of the improved membrane reactor model show that the membrane shift reaction has promise as a means to simplify the production of a clean stream of hydrogen and a clean stream of carbon dioxide. The focus of additional development work should address the large area required for the CO{sub 2} membrane as identified in the modeling calculations. Also, a more detailed process flow diagram should be developed that includes integration of cooling and preheating feed streams as well as particulate removal so that stea

Micheal Roberts; Robert Zabransky; Shain Doong; Jerry Lin

2008-05-31T23:59:59.000Z

2

Hydrogen Production from Thermocatalytic Hydrogen Sulfide Decomposition  

Science Journals Connector (OSTI)

Experimental data on hydrogen production from hydrogen sulfide decomposition over various solid catalysts at ... The possibilities given by surface modification by vacuum methods (electron beam evaporation and ma...

O. K. Alexeeva

2002-01-01T23:59:59.000Z

3

Removal of Hydrogen Sulfide from Landfill Gas Using a Solar Regenerable Adsorbent.  

E-Print Network [OSTI]

??Landfill gas is a complex mix of gases, containing methane, carbon dioxide, nitrogen and hydrogen sulfide, created by the action of microorganisms within the landfill. (more)

Kalapala, Sreevani

2014-01-01T23:59:59.000Z

4

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide (reproduced from: Hydrogen Sulphide at the Work Site, Alberta Workplace Health & Safety

Machel, Hans

5

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN  

E-Print Network [OSTI]

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A&M UNIVERSITY;PREFACE Attached is the "REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN" that will be used for ODP coring and drilling operations on legs where hydrogen sulfide is likely to be encountered. Prior

6

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

.E.L) is 10 parts per million (ppm) for 8 hours and 15 ppm as a ceiling limit. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide

Machel, Hans

7

Thiophene Hydrogenation to Tetrahydrothiophene over Tungsten Sulfide Catalysts  

Science Journals Connector (OSTI)

Independent reactions of thiophene reduction to tetrahydrothiophene and thiophene hydrogenolysis to form hydrogen sulfide...4...hydrocarbons are shown to occur over supported tungsten sulfide catalysts and unsupp...

A. V. Mashkina

2003-03-01T23:59:59.000Z

8

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

9

Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants  

SciTech Connect (OSTI)

IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

Elias Stefanakos; Burton Krakow; Jonathan Mbah

2007-07-31T23:59:59.000Z

10

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

11

Gas-Phase Thiophene Hydrogenation to Tetrahydrothiophene over Sulfide Catalysts  

Science Journals Connector (OSTI)

Thiophene hydrogenation to tetrahydrothiophene over supported transition metal sulfides is studied....T = 240C and P...= 2 MPa showed that aluminosilicate-supported PdS is one to two orders of magnitude more act...

A. V. Mashkina; L. G. Sakhaltueva

2002-01-01T23:59:59.000Z

12

A study of the reactions of arsinic and arsonic acids with hydrogen sulfide and hydrogen selenide  

E-Print Network [OSTI]

A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE by CYNTHIA ANNETTE APPLEGATE Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1986 Major Subject: Chemistry A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE A Thesis by CYNTHIA ANNETTE APPLEGATE Approved as to style and content by: Ralph A. ngaro...

Applegate, Cynthia Annette

2012-06-07T23:59:59.000Z

13

ARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas liquid interface  

E-Print Network [OSTI]

production methods in the US have led to the emergence of large- scale commeARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas­ liquid interface-film theory Hydrogen sulfide Process-based model Lagoon flux Mass transfer a b s t r a c t Hydrogen sulfide (H

Aneja, Viney P.

14

Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution  

E-Print Network [OSTI]

). This technique involves H2S mass transfer in an aqueous phase using a gas-liquid contactor. Since H2S is poorly. This scrubbing liquid is just drained when the salt accumulation due to H2S oxidation into sulfate anions becomes Hydrogen sulfide (H2S) is currently removed from gaseous effluents by chemical scrubbing using water

Paris-Sud XI, Université de

15

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy  

E-Print Network [OSTI]

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy sporadically accumulate hydrogen sulfide (H2S), which is toxic to most multicellular organisms and has been feedback loop that could fuel further sulfate reduction and potentially stabilize the sulfidic OMZ waters

Boyer, Edmond

16

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

17

The selective adsorption of hydrogen sulfide from natural gas streams  

E-Print Network [OSTI]

, and Mr. Ovid Baker of Magnolia Petroleum Company. The author also wishes to thank the Linde Company for ths Molecular Sieve type adsorbents and technical information on the same. He also wishes to thank Mr. R. D. Henley and We Magnolia Petroleum... Effect of Water Vapor on Adsorptive Capacity of Bed. 31 Table VI Abbreviated Comparison of Adsorbents. 32 INTRODUCTIOM INTRODUC TION The separation of mercaptans and hydrogen sulfide from natural gas produced from sour reservoirs is a problem which...

Fails, James Clayton

2012-06-07T23:59:59.000Z

18

The HYSULF{sup SM} process: A valuable hydrogen resource from hydrogen sulfide  

SciTech Connect (OSTI)

The increasing demand for hydrogen to reduce the sulfur content in standard refinery fuels is a very familiar problem to everyone in the industry. This problem could be partially offset by the continuous recycling of the hydrogen portion of hydrogen sulfide. In this regard, Marathon has been developing the HYSULF process. This process uses Redox chemistry under mild operating conditions to convert hydrogen sulfide into hydrogen and sulfur. The process employs two basic steps, i.e., a sulfur production and recovery step and a hydrogen production step. All chemicals and the catalyst used in the HYSULF process are either commercially available or are slight modifications of available materials. Also, the chemistry used in the HYSULF process is similar to that used in commercial desulfurization and gas sweetening processes.

Plummer, M.A. [Marathon Oil Co., Littleton, CO (United States)

1995-09-01T23:59:59.000Z

19

Atmospheric Environment 42 (2008) 33153331 Measurement and analysis of ammonia and hydrogen sulfide  

E-Print Network [OSTI]

; Hydrogen sulfide; Swine barns; CAFOs 1. Introduction Changes in livestock production methods in the USAtmospheric Environment 42 (2008) 3315­3331 Measurement and analysis of ammonia and hydrogen, where NH3­N ¼ (14 17)NH3) and hydrogen sulfide (H2S) were measured from a finishing swine confinement

Aneja, Viney P.

20

Hydrogen sulfide spatial distribution and exposure in deep-pit swine housing.  

E-Print Network [OSTI]

??The objectives of this research focus on investigating spatial distribution of hydrogen sulfide gas associated with manure removal and agitation events in deep-pit swine production (more)

Swestka, Randy John

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts  

Science Journals Connector (OSTI)

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts ... Several semiconductor nanowire systems, synthesized by different methods, have been investigated by photoelectrochemistry. ... power available from the hydrogen produced and the power supplied by an external source. ...

Lu Gao; Yingchao Cui; Jia Wang; Alessandro Cavalli; Anthony Standing; Thuy T. T. Vu; Marcel A. Verheijen; Jos E. M. Haverkort; Erik P. A. M. Bakkers; Peter H. L. Notten

2014-05-29T23:59:59.000Z

22

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana  

E-Print Network [OSTI]

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana , L. A. Wiseb , S for the poisoning kinetics of hydrogen sulfide (H2S) on composite solid polymer electrolyte Pt (SPE-Pt) electrode) fuel cells, there is much less in the literature on H2S poisoning. Uribe et al showed

Sethuraman, Vijay A.

23

Modeling of Syngas Reactions and Hydrogen Generation Over Sulfides  

SciTech Connect (OSTI)

The objective of the research is to analyze pathways of reactions of hydrogen with oxides of carbon over sulfides, and to predict which characteristics of the sulfide catalyst (nature of metal, defect structure) give rise to the lowest barriers toward oxygenated hydrocarbon product. Reversal of these pathways entails the generation of hydrogen, which is also proposed for study. In this first year of study, adsorption reactions of H atoms and H{sub 2} molecules with MoS{sub 2}, both in molecular and solid form, have been modeled using high-level density functional theory. The geometries and strengths of the adsorption sites are described and the methods used in the study are described. An exposed MO{sup IV} species modeled as a bent MoS{sub 2} molecule is capable of homopolar dissociative chemisorption of H{sub 2} into a dihydride S{sub 2}MoH{sub 2}. Among the periodic edge structures of hexagonal MoS{sub 2}, the (1{bar 2}11) edge is most stable but still capable of dissociating H{sub 2}, while the basal plane (0001) is not. A challenging task of theoretically accounting for weak bonding of MoS{sub 2} sheets across the Van der Waals gap has been addressed, resulting in a weak attraction of 0.028 eV/MoS{sub 2} unit, compared to the experimental value of 0.013 eV/MoS{sub 2} unit.

Kamil Klier; Jeffery A. Spirko; Michael L. Neiman

2002-09-17T23:59:59.000Z

24

Methods for producing hydrogen (BI) sulfide and/or removing metals  

DOE Patents [OSTI]

The present invention is a process wherein sulfide production by bacteria is efficiently turned on and off, using pH adjustment. The adjustment of pH impacts sulfide production by bacteria by altering the relative amounts of H.sub.2 S and HS-- in solution and thereby control the inhibition of the bacterial metabolism that produces sulfide. This process can be used to make a bioreactor produce sulfide "on-demand" so that the production of sulfide can be matched to its use as a metal precipitation reagent. The present invention is of significance because it enables the use of a biological reactor, a cost effective sulfide production system, by making the biological reactor produce hydrogen sulfide "on demand", and therefore responsive to production schedules, waste stream generation rate, and health and safety requirements/goals.

Truex, Michael J [Richland, WA; Peyton, Brent M [Pullman, WA; Toth, James J [Kennewick, WA

2002-05-14T23:59:59.000Z

25

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect (OSTI)

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

26

Corrosion of iron in acid solutions with hydrogen sulfide  

SciTech Connect (OSTI)

The influence of pH and the concentration of hydrogen sulfide (H{sub 2}S) on corrosion of iron in acid solutions was studied using a potentiostatic polarization method. The alternating current (AC) impedance technique also was used to characterize the active dissolution process of iron. Results showed the dissolution process was accelerated by H{sub 2}S. The anodic dissolution current (i{sub a}) increased with pH and H{sub 2}S concentration with reaction orders of about n{sub pH} = n{sub H{sub 2}s} = 0.25 when the ratio of H{sub 2}S concentration and hydrogen ion (H{sub 3}O{sup +}) concentration was <10{sup 1.5} i{sub a} reached a maximum and became independent of pH and [H{sub 2}S] when [H{sub 2}S]/H{sub 3}O{sup +} > 10{sup 1.5}. The Nyquist diagram corresponding to the active dissolution process in the Tafel range exhibited two capacitive loops in addition to the well-known, high-frequency capacitive loop. A mechanism was proposed to explain the results in which H{sub 2}S chemisorbed first on the electrode surface and then catalyzed the anodic dissolution of iron in two discharging steps.

Cheng, X.L.; Ma, H.Y.; Zhang, J.P.; Chen, X.; Chen, S.H. [Shandong Univ., Jinan (China). Dept. of Chemistry; Yang, H.Q. [Peking Univ. (China). Dept. of Chemistry

1998-05-01T23:59:59.000Z

27

Journal of Power Sources 135 (2004) 184191 A solid oxide fuel cell system fed with hydrogen sulfide  

E-Print Network [OSTI]

Journal of Power Sources 135 (2004) 184­191 A solid oxide fuel cell system fed with hydrogen for a solid oxide fuel cell (SOFC). This paper presents an examination of a simple hydrogen sulfide and natural gas-fed solid oxide fuel cell system. The possibility of utilization of hydrogen sulfide

28

Quantitative evaluation of hydrogen sulfide at 0.3 M and 1.0 M-hydrogen-ion concentration  

E-Print Network [OSTI]

. In the present study, cobalt sulfide was quantitatively re? covered from a solution whose hydrogen-ion concentration -12was calculated to be 6.95 x 10 M. As in the case of zinc sulfide, this was to be expected, since a decreased hydrogen-ion concentration... quantitatively to an electrolysis beaker with distilled water. The copper 28 was deposited on a platinum gauze cathode in 9 hours from a solution containing a 5 ml. excess of 18 M sulfuric acid in 125 ml., and a current of 0.5 ampere. 12. Copper (II) - Zinc...

Machel, Albert R.

1958-01-01T23:59:59.000Z

29

High-Temperature Nano-Derived Micro-Hydrogen Sulfide Sensors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Temperature Nano-Derived Micro- Temperature Nano-Derived Micro- Hydrogen and -Hydrogen Sulfide Sensors Background The Department of Energy (DOE) National Energy Technology Laboratory (NETL) seeks applications for the University Coal Research (UCR) Program to further develop the understanding of coal utilization. Since the program's inception in 1979, its primary objectives have been to (1) improve our understanding of the chemical and physical processes involved in the conversion and utilization of coal in an environmentally

30

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

31

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

32

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

33

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network [OSTI]

, and carbon dioxide. Introduction Carbon dioxide emissions resulting from the burning of fossil fuels 20 metric tons of carbon dioxide per capita are released annually into the atmosphere.1a,b CarbonStorage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks

Yaghi, Omar M.

34

Effect of hydrogen sulfide on chemical looping of coal-derived synthesis gas over bentonite-supported metal---oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H2S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxidesssuch as iron oxide, nickel oxide, manganese oxide, and copper oxideswas investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H2S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H2S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H2S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H2S for all four metal oxides.

Tian, H.; Simonyi, T.; Poston, J.; Siriwardane, R.

2009-01-01T23:59:59.000Z

35

Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H{sub 2}S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxides - such as iron oxide, nickel oxide, manganese oxide, and copper oxide - was investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H{sub 2}S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H{sub 2}S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H{sub 2}S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H{sub 2}S for all four metal oxides.

Tian, H.J.; Simonyi, T.; Poston, J.; Siriwardane, R. [US DOE, Morgantown, WV (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

36

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1997-01-01T23:59:59.000Z

37

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1999-01-01T23:59:59.000Z

38

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

39

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant  

E-Print Network [OSTI]

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

Gates, Kent. S.

40

HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE  

SciTech Connect (OSTI)

HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE Lucia M. Petkovic, Harry W. Rollins, Daniel M. Ginosar, and Kyle C. Burch Idaho National Laboratory P.O. Box 1625 Idaho Falls, ID 83415-2208 Introduction Anthropogenic emissions of carbon dioxide, a gas often associated with global warming, have increased considerably since the beginning of the industrial age.1 In the U.S., stationary CO2 sources, such as electricity generation plants, produce about one-third of the anthropogenic CO2 generation. Reports2 indicate that the power required to recover 90% of the CO2 from an integrated coal-fired power-plant is about 10% of the power-plant capacity. This energy requirement can be reduced to less than 1% if the recovered CO2 is applied to the production of synthetic fuels. However, the lack of efficient catalysts along with the costs of energy and hydrogen has prevented the development of technologies for direct hydrogenation of CO2.3 Although the cost of hydrogen for hydrogenating CO2 is not economically attractive at present, the future production of hydrogen by nuclear power sources could completely change this scenario.2 Still, an efficient catalyst will be essential for commercial application of those processes. The objective of the work presented here was the development of hybrid catalysts for one-step carbon dioxide hydrogenation to liquid fuels. The hybrid catalysts, which were prepared by two novel techniques, included a copper/zinc oxide catalytic function distributed within an acidic zeolitic matrix. Results of catalyst activity and selectivity studies at atmospheric pressure are presented in this contribution. Experimental Catalysts were prepared by two novel techniques and under several different conditions to produce copper/zinc oxide/zeolite materials. Once synthesized, samples were pelletized and the fraction between 40-60 mesh was utilized for the experiments. Two hundred milligrams of catalyst were loaded in a U-tube stainless steel reactor and a flow of 100 cm3/min of a 10:90 H2:Ar mixture was passed through the catalyst bed while the temperature was increased from room temperature to 513 K at 1.8 K/min and held at 513 K for 15 h. A reactant gas mixture composed by 10 cm3/min of CO2 and 30 cm3/min of H2 was then passed through the catalyst bed and the reaction products monitored by on-line gas chromatographic analyses using an SRI Multiple Gas Analyzer #2 equipped with 3 columns (MoleSieve 13X, Hayesep-D, and MXT-1) and 3 detectors (TCD, FID, and FID-methanizer). This GC system allowed for quantification of inert gases, CO, CO2, methanol, dimethylether, higher alcohols, water, and hydrocarbons up to C20. One hundred milligrams of a commercial syngas-to-methanol catalyst along with the same amount of a commercial zeolite catalyst was utilized under the same reaction conditions for comparison purposes. These catalysts were utilized either in two-layers (Com1) or mixed together (Com2). Results and Discussion Under the conditions applied in this study, the main reaction products were CO, CH3OH, CH3OCH3, and H2O. Methanol and dimethylether production rates and selectivities with respect to CO formation are presented in Figures 1 and 2, respectively. Although the activity of the synthesized catalysts did not surpass the commercial catalysts, the selectivity to oxygenates with respect to CO on most of the synthesized catalysts were better than on the commercial catalysts. For example, cat

Licia M. Petkovic; Harry W. Rollins; Daniel M. Ginosar; Kyle C. Burch

2006-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors  

SciTech Connect (OSTI)

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-10-14T23:59:59.000Z

42

Hydrogen storage and carbon dioxide capture in an iron-based...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Previous Next List Kenji Sumida,...

43

DOE Hydrogen Analysis Repository: Carbon Dioxide Compression, Transport,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Dioxide Compression, Transport, and Storage Carbon Dioxide Compression, Transport, and Storage Project Summary Full Title: Techno-Economic Models for Carbon Dioxide Compression, Transport, and Storage & Correlations for Estimating Carbon Dioxide Density and Viscosity Project ID: 195 Principal Investigator: David McCollum Brief Description: This project addresses several components of carbon capture and storage (CCS) costs, provides technical models for determining the engineering and infrastructure requirements of CCS, and describes some correlations for estimating CO2 density and viscosity. Keywords: Pipeline, transportation, greenhouse gases (GHG), costs, technoeconomic analysis Purpose Estimate costs of carbon dioxide capture, compression, transport, storage, etc., and provide some technical models for determining the engineering and

44

Effect of the metal-semiconductor phase transition on the rate of hydrogen penetration into vanadium dioxide thin films  

Science Journals Connector (OSTI)

The rates of hydrogen penetration from an aqueous solution of glycerin into ... compared. It has been found that the rate of hydrogen penetration into the metal phase of vanadium dioxide ... order of magnitude hi...

V. N. Andreev; V. A. Klimov

2010-03-01T23:59:59.000Z

45

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

46

Simulating Geologic Co-sequestration of Carbon Dioxide and Hydrogen Sulfide in a Basalt Formation  

SciTech Connect (OSTI)

Co-sequestered CO2 with H2S impurities could affect geologic storage, causing changes in pH and oxidation state that affect mineral dissolution and precipitation reactions and the mobility of metals present in the reservoir rocks. We have developed a variable component, non-isothermal simulator, STOMP-COMP (Water, Multiple Components, Salt and Energy), which simulates multiphase flow gas mixtures in deep saline reservoirs, and the resulting reactions with reservoir minerals. We use this simulator to model the co-injection of CO2 and H2S into brecciated basalt flow top. A 1000 metric ton injection of these supercritical fluids, with 99% CO2 and 1% H2S, is sequestered rapidly by solubility and mineral trapping. CO2 is trapped mainly as calcite within a few decades and H2S is trapped as pyrite within several years.

Bacon, Diana H.; Ramanathan, Ramya; Schaef, Herbert T.; McGrail, B. Peter

2014-01-15T23:59:59.000Z

47

The Path of Carbon in Photosynthesis IX. Photosynthesis, Photoreduction, and the Hydrogen-Oxygen-Carbon Dioxide Dark Reaction  

DOE R&D Accomplishments [OSTI]

A comparison of the rates of fixation of Carbon 14 dioxide in algae for the processes of photosynthesis, photoreduction and the hydrogen-oxygen-carbon dioxide dark reaction has been made. For the same series of experiments, rates of incorporation of tracer carbon into the separate soluble components using the radiogram method have been determined. The mechanism of carbon dioxide uptake has been shown to occur via two distinct paths. In all cases studied, essentially the same compounds appear radioactive. The distribution with time, however, differs markedly.

Badin, E. J.; Calvin, M.

1950-02-01T23:59:59.000Z

48

Promotive SMSI effect for hydrogenation of carbon dioxide to methanol on a Pd/CeO{sub 2} catalyst  

SciTech Connect (OSTI)

This article reports strong metal support interaction (SMSI) appearing in supported palladium catalysts which improves greatly the selectivity and lifetime of the catalysts for methanol synthesis from CO{sub 2} hydrogenation. Catalytic hydrogenation of carbon dioxide into valuable chemicals and fuels such as methanol has recently been recognized as one of the promising recycling technologies for emitted CO{sub 2}. 33 refs., 1 fig., 3 tabs.

NONE

1994-11-01T23:59:59.000Z

49

The Impact of Increased Use of Hydrogen on Petroleum Consumption and Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

SR/OIAF-CNEAF/2008-04 SR/OIAF-CNEAF/2008-04 The Impact of Increased Use of Hydrogen on Petroleum Consumption and Carbon Dioxide Emissions September 2008 Energy Information Administration Office of Integrated Analysis and Forecasting Office of Coal, Nuclear, Electric and Alternate Fuels U.S. Department of Energy Washington, DC 20585 This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. Unless referenced otherwise, the information contained herein should be attributed to the Energy Information Administration and should not be construed as advocating or reflecting any policy position of the Department of Energy or any other organization. Service Reports are prepared by the Energy Information Administration upon special

50

Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

51

Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)  

SciTech Connect (OSTI)

The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

1999-05-01T23:59:59.000Z

52

Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

2012-11-13T23:59:59.000Z

53

Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

An apparatus and a method are disclosed for converting hydrocarbon fuel or an alcohol into hydrogen gas and carbon dioxide. The apparatus includes a first vessel having a partial oxidation reaction zone and a separate steam reforming reaction zone that is distinct from the partial oxidation reaction zone. The first vessel has a first vessel inlet at the partial oxidation reaction zone and a first vessel outlet at the steam reforming zone. The reformer also includes a helical tube extending about the first vessel. The helical tube has a first end connected to an oxygen-containing source and a second end connected to the first vessel at the partial oxidation reaction zone. Oxygen gas from an oxygen-containing source can be directed through the helical tube to the first vessel. A second vessel having a second vessel inlet and second vessel outlet is annularly disposed about the first vessel. The helical tube is disposed between the first vessel and the second vessel and gases from the first vessel can be directed through second vessel.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H.J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

54

Zinc sulfide liquefaction catalyst  

DOE Patents [OSTI]

A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

Garg, Diwakar (Macungie, PA)

1984-01-01T23:59:59.000Z

55

SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS  

SciTech Connect (OSTI)

Inorganic membrane reactors offer the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. Such attractive features can be advantageously utilized in a number of potential commercial opportunities, which include dehydrogenation, hydrogenation, oxidative dehydrogenation, oxidation and catalytic decomposition reactions. However, to be cost effective, significant technological advances and improvements will be required to solve several key issues which include: (a) permselective thin solid film, (b) thermal, chemical and mechanical stability of the film at high temperatures, and (c) reactor engineering and module development in relation to the development of effective seals at high temperature and high pressure. In this project, we are working on the development and application of palladium and palladium-silver alloy thin-film composite membranes in membrane reactor-separator configuration for simultaneous production and separation of hydrogen and carbon dioxide at high temperature. From our research on Pd-composite membrane, we have demonstrated that the new membrane has significantly higher hydrogen flux with very high perm-selectivity than any of the membranes commercially available. The steam reforming of methane by equilibrium shift in Pd-composite membrane reactor is being studied to demonstrate the potential application this new development. We designed and built a membrane reactor to study the reforming reaction. A two-dimensional pseudo-homogeneous reactor model was developed to study the performance of the membrane reactor parametrically. The important results are presented in this report.

Shamsuddin Illias

2002-06-10T23:59:59.000Z

56

Investigation of charge compensation in indium-doped tin dioxide by hydrogen insertion via annealing under humid conditions  

SciTech Connect (OSTI)

The behavior of hydrogen (H) as an impurity in indium (In)-doped tin dioxide (SnO{sub 2}) was investigated by mass spectrometry analyses, with the aim of understanding the charge compensation mechanism in SnO{sub 2}. The H-concentration of the In-doped SnO{sub 2} films increased to (12)??10{sup 19}?cm{sup ?3} by annealing in a humid atmosphere (WET annealing). The electron concentration in the films also increased after WET annealing but was two orders of magnitude less than their H-concentrations. A self-compensation mechanism, based on the assumption that H sits at substitutional sites, is proposed to explain the mismatch between the electron- and H-concentrations.

Watanabe, Ken, E-mail: Watanabe.Ken@nims.go.jp [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); International Center for Young Scientists (ICYS-MANA), NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Ohsawa, Takeo; Ross, Emily M., E-mail: emross@hmc.edu; Adachi, Yutaka; Haneda, Hajime [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Sakaguchi, Isao; Takahashi, Ryosuke [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Department of Applied Science for Electronics and Materials, Kyushu University, 6-1 Kasuga-kouen Kasuga, Fukuoka 816-8580 (Japan); Bierwagen, Oliver, E-mail: bierwagen@pdi-berlin.de [Paul-Drude-Institute, Hausvogteiplatz 5-7, 10117 Berlin (Germany); Materials Department, University of California, Santa Barbara, California 93106 (United States); White, Mark E.; Tsai, Min-Ying; Speck, James S., E-mail: speck@ucsb.edu [Materials Department, University of California, Santa Barbara, California 93106 (United States); Ohashi, Naoki, E-mail: Ohashi.Naoki@nims.go.jp [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Department of Applied Science for Electronics and Materials, Kyushu University, 6-1 Kasuga-kouen Kasuga, Fukuoka 816-8580 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)

2014-03-31T23:59:59.000Z

57

Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

Solehudin, Agus, E-mail: asolehudin@upi.edu [Department of Mechanical Engineering Education, Indonesia University of Education (UPI), Bandung, West Java (Indonesia); Nurdin, Isdiriayani [Department of Chemical Engineering, Bandung Institute of Technology, Bandung, West Java (Indonesia)

2014-03-24T23:59:59.000Z

58

Quantum cascade laser spectrometer for trace-gas detection of exhaled Carbonyl Sulfide  

Science Journals Connector (OSTI)

Simultaneous concentration measurements of exhaled carbonyl sulfide and carbon dioxide were demonstrated using a pulsed quantum cascade laser based gas sensor. This sensor has...

Wysocki, Gerard; So, Stephen; McCurdy, Matt; Roller, Chad; Weidmann, Damien; Kosterev, Anatoliy a; Frantz, J Patrick; Curl, Robert F; Tittel, Frank K

59

The production of pure hydrogen with simultaneous capture of carbon dioxide  

E-Print Network [OSTI]

The need to stabilise or even reduce the production of anthropogenic CO2 makes the capture of CO2 during energy generation from carbonaceous fuels, e.g. coal or biomass, necessary for the future. For hydrogen, an environmentally-benign energy vector...

Bohn, Christopher

2010-10-12T23:59:59.000Z

60

Hydrogen and electricity from coal with carbon dioxide separation using chemical looping reactors  

SciTech Connect (OSTI)

Concern about global climate change has led to research on low CO{sub 2} emission in the process of the energy conversion of fossil fuel. One of the solutions is the conversion of fossil fuel into carbon-free energy carriers, hydrogen, and electricity with CO{sub 2} capture and storage. In this paper, the main purpose is to investigate the thermodynamics performance of converting coal to a hydrogen and electricity system with chemical-looping reactors and to explore the influences of operating parameters on the system performance. Using FeO/Fe{sub 3}O{sub 4} as an oxygen carrier, we propose a carbon-free coproduction system of hydrogen and electricity with chemical-looping reactors. The performance of the new system is simulated using ASPEN PLUS software tool. The influences of the chemical-looping reactor's temperature, steam conversion rate, and O{sub 2}/coal quality ratio on the system performance, and the exergy performance are discussed. The results show that a high-purity of H{sub 2} (99.9%) is reached and that CO{sub 2} can be separated. The system efficiency is 57.85% assuming steam reactor at 815 C and the steam conversion rate 37%. The system efficiency is affected by the steam conversion rate, rising from 53.17 to 58.33% with the increase of the steam conversion rate from 28 to 41%. The exergy efficiency is 54.25% and the losses are mainly in the process of gasification and HRSG. 14 refs., 12 figs., 3 tabs.

Xiang Wenguo; Chen Yingying [Southeast University, Nanjing (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

2007-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS  

SciTech Connect (OSTI)

Inorganic membrane reactors offer the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. Such attractive features can be advantageously utilized in a number of potential commercial opportunities, which include dehydrogenation, hydrogenation, oxidative dehydrogenation, oxidation and catalytic decomposition reactions. However, to be cost effective, significant technological advances and improvements will be required to solve several key issues which include: (a) permselective thin solid film, (b) thermal, chemical and mechanical stability of the film at high temperatures, and (c) reactor engineering and module development in relation to the development of effective seals at high temperature and high pressure. In this project, we are working on the development and application of palladium and palladium-silver alloy thin-film composite membranes in membrane reactor-separator configuration for simultaneous production and separation of hydrogen and carbon dioxide at high temperature. From our research on Pd-composite membrane, we have demonstrated that the new membrane has significantly higher hydrogen flux with very high perm-selectivity than any of the membranes commercially available. The steam reforming of methane by equilibrium shift in Pd-composite membrane reactor is being studied to demonstrate the potential application of this new development. A two-dimensional, pseudo-homogeneous membrane-reactor model was developed to investigate the steam-methane reforming (SMR) reactions in a Pd-based membrane reactor. Radial diffusion was taken into consideration to account for the concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system. The equations were solved by finite difference method. The solution of the model equations is complicated by the coupled reactions. At the inlet, if there is no hydrogen, rate expressions become singular. To overcome this problem, the first element of the reactor was treated as a continuous stirred tank reactor (CSTR). Several alternative numerical schemes were implemented in the solution algorithm to get a converged, stable solution. The model was also capable of handling steam-methane reforming reactions under non-membrane condition and equilibrium reaction conversions. Some of the numerical results were presented in the previous report. To test the membrane reactor model, we fabricated Pd-stainless steel membranes in tubular configuration using electroless plating method coupled with osmotic pressure. Scanning Electron Microscopy (SEM) and Energy Dispersive Xray (EDX) were used to characterize the fabricated Pd-film composite membranes. Gas-permeation tests were performed to measure the permeability of hydrogen, nitrogen and helium using pure gas. Some of these results are discussed in this progress report.

Shamsuddin Ilias

2004-02-17T23:59:59.000Z

62

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents [OSTI]

A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-03-27T23:59:59.000Z

63

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

Clawson, Lawrence G. (7 Rocky Brook Rd., Dover, MA 02030); Mitchell, William L. (111 Oakley Rd., Belmont, MA 02178); Bentley, Jeffrey M. (20 Landmark Rd., Westford, MA 01886); Thijssen, Johannes H. J. (1 Richdale Ave.#2, Cambridge, MA 02140)

2002-01-01T23:59:59.000Z

64

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-01-01T23:59:59.000Z

65

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents [OSTI]

A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-09-26T23:59:59.000Z

66

Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report  

SciTech Connect (OSTI)

This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation CalvinBensonBassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol.

Sinskey, Anthony J. [MIT] [MIT; Worden, Robert Mark [Michigan State University MSU] [Michigan State University MSU; Brigham, Christopher [MIT] [MIT; Lu, Jingnan [MIT] [MIT; Quimby, John Westlake [MIT] [MIT; Gai, Claudia [MIT] [MIT; Speth, Daan [MIT] [MIT; Elliott, Sean [Boston University] [Boston University; Fei, John Qiang [MIT] [MIT; Bernardi, Amanda [MIT] [MIT; Li, Sophia [MIT] [MIT; Grunwald, Stephan [MIT] [MIT; Grousseau, Estelle [MIT] [MIT; Maiti, Soumen [MSU] [MSU; Liu, Chole [MSU] [MSU

2013-12-16T23:59:59.000Z

67

Chemical-Looping Gasification of Biomass for Hydrogen-Enriched Gas Production with In-Process Carbon Dioxide Capture  

Science Journals Connector (OSTI)

This may help to increase the carbon dioxide capture on one hand but, on other hand, also increases the size of the gasifier and regenerator and the heat requirement of the regenerator. ... Steam was used as the fluidizing medium. ...

Bishnu Acharya; Animesh Dutta; Prabir Basu

2009-09-03T23:59:59.000Z

68

Process for producing cadmium sulfide on a cadmium telluride surface  

DOE Patents [OSTI]

A process is described for producing a layer of cadmium sulfide on a cadmium telluride surface to be employed in a photovoltaic device. The process comprises providing a cadmium telluride surface which is exposed to a hydrogen sulfide plasma at an exposure flow rate, an exposure time and an exposure temperature sufficient to permit reaction between the hydrogen sulfide and cadmium telluride to thereby form a cadmium sulfide layer on the cadmium telluride surface and accomplish passivation. In addition to passivation, a heterojunction at the interface of the cadmium sulfide and the cadmium telluride can be formed when the layer of cadmium sulfide formed on the cadmium telluride is of sufficient thickness. 12 figs.

Levi, D.H.; Nelson, A.J.; Ahrenkiel, R.K.

1996-07-30T23:59:59.000Z

69

Hydrogen  

Science Journals Connector (OSTI)

Hydrogen energy is a clean or inexhaustible energy like renewable energy and nuclear energy. Todays energy supply has a considerable impact on the environment. Hydrogen energy is a promising alternative solut...

2009-01-01T23:59:59.000Z

70

Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Biodiesel: Cooperative Research and Development Final Report, CRADA Number: CRD-10-408  

SciTech Connect (OSTI)

OPX Biotechnologies, Inc. (OPX), the National Renewable Energy Laboratory (NREL), and Johnson Matthey will develop and optimize a novel, engineered microorganism that directly produces biodiesel from renewable hydrogen (H2) and carbon dioxide (CO2). The proposed process will fix CO2 utilizing H2 to generate an infrastructure-compatible, energy-dense fuel at costs of less than $2.50 per gallon, with water being produced as the primary byproduct. NREL will perform metabolic engineering on the bacterium Cupriavidus necator (formerly Ralstonia eutropha) and a techno-economic analysis to guide future scale-up work. H2 and CO2 uptakes rates will be genetically increased, production of free fatty acids will be enhanced and their degradation pathway blocked in order to meet the ultimate program goals.

Maness, P. C.

2014-06-01T23:59:59.000Z

71

Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation  

Science Journals Connector (OSTI)

...energy conversion with consumption of a pollutant, CO2...energy conversion with consumption of a pollutant, CO...energy conversion with consumption of a pollutant, CO2...energy by producing fuels (hydrogen, carbon...M) in the reaction vessel; the gas contained...

Jean-Marie Lehn; Raymond Ziessel

1982-01-01T23:59:59.000Z

72

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents [OSTI]

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

73

Crossed beam reaction of atomic carbon C ( 3 P j ) with hydrogen sulfide, H 2 S (X 1 A 1 ): Observation of the thioformyl radical, HCS (X 2 A?)  

Science Journals Connector (OSTI)

One of the simplest organosulfur reactions that between ground statecarbon atoms C ( 3 P j ) and hydrogen sulfide H 2 S (X 1 A 1 ) was studied at an average collision energy of 21.0 kJ? mol ?1 using the crossed molecular beams technique. The product angular distribution and time-of-flight spectra of m/e=45 ( HC 32 S ) were monitored. Forward-convolution fitting of our data yields an almost isotropic center-of-mass angular flux-distribution whereas the center-of-mass translational energy flux distribution peaks at about 50 kJ? mol ?1 indicating a tight exit transition state from the decomposing thiohydroxycarbene HCSH complex to the reaction products. The high energy cut-off of the translational energy flux distribution is consistent with the formation of the thioformyl radical HCS in its X 2 A electronic ground state. The first experimental verification of an existing thiohydroxycarbene intermediate and the rigorous assignment of the HCS radical product under single collision conditions explicitly suggest inclusion of the title reaction in chemical reaction networks of molecular clouds TMC-1 and OMC-1 the outflow of the carbon star IRC+10216 Shoemaker/Levy 9 impact-induced nonequilibrium sulfur chemistry in the Jovian atmosphere as well as combustion of sulfur containing coal.

R. I. Kaiser; W. Sun; A. G. Suits

1997-01-01T23:59:59.000Z

74

Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: A Mechanistic Investigation using High-Pressure NMR Spectroscopy  

SciTech Connect (OSTI)

The previously reported complex, cis-(PMe3)4RuCl(OAc) (1) acts as a catalyst for CO2 hydrogenation into formic acid in the presence of a base and an alcohol co-catalyst. NMR spectroscopy has revealed that 1 exists in solution in equilibrium with fac-(PMe3)3RuCl(h2-OAc) (2), [(PMe3)4Ru(h2-OAc)]Cl (3a), and free PMe3. Complex 2 has been isolated and characterized by elemental analysis, NMR spectroscopy, and X-ray crystallography. 2 has been tested as a CO2 hydrogenation catalyst, however, it performed poorly under the conditions of catalysis used for 1. Complex 3a can be prepared by adding certain alcohols, such as MeOH, EtOH, or o-C6H5OH, to a solution of 1 in CDCl3. The chloride ion of 3a has been exchanged for the non-coordinating anions BPh4 or B(ArF )4 (B(ArF)4 = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) to produce [(PMe3)4Ru(h2-OAc)]BPh4 (3b) and [(PMe3)4Ru(h2-OAc)]B(ArF)4 (3c). Both of these complexes have been isolated and characterized by elemental analysis, NMR spectroscopy, and in the case of 3b, X-ray crystallography. Complexes 3b and 3c perform just as well as 1 for CO2 hydrogenation to formic acid in the presence of an alcohol co-catalyst; however, 3b,c perform equally well without the added alcohol. High-pressure NMR has been used to investigate the mechanism of CO2 hydrogenation via 3a,b in the presence of base. Two of the intermediates involved have been identified as cis-(PMe3)4RuH2 (5) and cis-(PMe3)4Ru(H)O2CH (6), and the role of the base includes not only trapping of the formic acid product, but also initiation of the catalysis by aiding the conversion of 3b,c to 5.

Getty, April D.; Tai, Chih-Cheng; Linehan, John C.; Jessop, Philip G.; Olmstead, Marilyn M.; Rheingold, Arnold

2009-08-26T23:59:59.000Z

75

High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor  

SciTech Connect (OSTI)

Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

2011-07-31T23:59:59.000Z

76

Bisphosphine dioxides  

DOE Patents [OSTI]

A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

Moloy, K.G.

1990-02-20T23:59:59.000Z

77

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary and its influence on hard clam survival  

E-Print Network [OSTI]

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary that is grown to market size in estuarine sediments. Hydrogen sulfide, a natural metabolic poison known of hard clams used in field aquaculture areas in the Suwannee River estuary. Sulfide was found in sediment

Florida, University of

78

Solar Thermal Energy Cycle Based on Sulfur and Sulfide Oxidizing Bacteria  

Science Journals Connector (OSTI)

New solar energy technologies for the production of biomass for the purpose of synthesizing methane, hydrogen and proteins could be based on the solar generation of the inorganic energy source (Fe2+, metal sulfid...

C. C. Brtels; H. Tributsch

1991-01-01T23:59:59.000Z

79

Nitrogen Dioxide-Induced Responses in Brassica campestris Seedlings: The Role of Hydrogen Peroxide in the Modulation of Antioxidative Level and Induced Resistance  

Science Journals Connector (OSTI)

This article investigates the responses of Brassica campestris seedlings to an acute level of nitrogen dioxide (NO2) exposure in a plant growth chamber, and examines whether pretreating plants with hydrogen peroxide (H2O2) will alleviate NO2-caused injury. Twenty-eight-day-old B. campestris plants sprayed with 10 mmol L?1 H2O2 aqueous solution (corresponding to approximate 1.0 mg H2O2 per single plant) were exposed to different concentrations of NO2 (0.25, 0.5, 1.0, and 2.0 ?L L?1, respectively) for 24 h under controlled environment. To measure the plant biomass, the plants were fumigated with the same NO2 concentrations as mentioned above for 7 h per day (8.00-15.00) for 7 days. As a control, charcoal filtered air alone was applied. Data were collected on plant biomass, total chlorophyll, photosynthetic rate, stomatal conductance, nitrate and nitrate reductase (NR), antioxidative enzymes, ascorbate (ASA), and malondialdehyde (MDA), immediately after exposure. The results showed that exposure to a moderate dose of NO2 (e.g., 0.25 ?L L?1) had a favorable effect on plants, and the dry weight of the above-ground part increased, whereas the exposure to high NO2 concentrations (e.g., 0.5 ?L L?1 or higher) caused a reduction in the plant biomass and the total chlorophyll, when compared with the control. In addition, at 0.5 ?L L?1 or higher NO2 concentrations, prominent increases in the MDA level and superoxide dismutase (SOD) and NR activities were observed. Exposure to 1 ?L L?1 and higher NO2 resulted in necroses appearing on older leaves, and an increase in catalase (CAT) activity, decrease in ASA content, increased accumulation of NO3, and reduction in photosynthesis, when compared with the controls. No changes were detected in stomatal conductance under NO2 fumigation. The pretreatment with 10 mmol L?1 H2O2 alleviated significantly NO2-caused biomass decrease and photosynthetic inhibition when compared with H2O2-untreated plants. Under NO2 fumigation, further induction in SOD and CAT activities occurred in H2O2 treated plants when compared with H2O2-untreated plants. The effect of NO2 on the ASA and MDA contents was also absent in H2O2-treated plants. However, the H2O2 treatment did not alter the nitrate content and NR activity in plants under NO2 fumigation. The H2O2 treatment caused a lower rate of stomatal conductance. Taken together, these data suggest that fumigation with an acute level of NO2 causes oxidative damage to B. campestris seedlings. The H2O2 pretreatment markedly protects plants against NO2 stress and this may be associated with inducible antioxidative level. NO2 fumigation contributes, at least in part, to the enhanced levels of nitrate in B. campestris leaves.

Chun-yan MA; Xin XU; Lin HAO; Jun CAO

2007-01-01T23:59:59.000Z

80

NREL: Learning - Hydrogen Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fuel, so the carbon dioxide released in the reformation process adds to the greenhouse effect. Hydrogen has very high energy for its weight, but very low energy for its...

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Method for synthesis of titanium dioxide nanotubes using ionic liquids  

SciTech Connect (OSTI)

The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

Qu, Jun; Luo, Huimin; Dai, Sheng

2013-11-19T23:59:59.000Z

82

Oxidative Remobilization of Technetium Sequestered by Sulfide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent...

83

Purification of sulfide oxidase from rat liver  

E-Print Network [OSTI]

of sulfide oxidase, provided an initial precipitation of sulfide oxidase, and after chromatographic procedures a 21 fold purification of the enzyme was obtained....

Pu, Lixia

1994-01-01T23:59:59.000Z

84

UNCORRECTEDPROOF The effect of temperature on the adsorption rate of hydrogen  

E-Print Network [OSTI]

size, and low operating temperatures. In a ``hydrogen challenged'' economy, the fuel for the PEMFCsUNCORRECTEDPROOF DTD 5 The effect of temperature on the adsorption rate of hydrogen sulfide on Pt adsorbed at lower temperatures. A value of the activation energy of hydrogen sulfide adsorption on Pt

Van Zee, John W.

85

PRODUCTION OF HYDROGEN BY SUPERADIABATIC DECOMPOSITION OF HYDROGEN SULFIDE  

E-Print Network [OSTI]

in a cylindrical vessel packed with a porous ceramic medium with a high thermal capacity. The intensive heat internal surfaces permits the accumulation of combustion energy in the solid matrix. As a result, flame hydrocarbons via the superadiabatic partial oxidation have shown the high potential of this approach. It has

86

E-Print Network 3.0 - anaerobic hydrogen producing Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a small percentage of hydrogen sulfide, water vapor, carbon... Technology Biomethane (biogas) is an alternative and renewable energy source produced through the anaerobic... are...

87

High P/T phase and volumetric behavior of coal liquid constituents. (Quarterly technical progress report), January 1-April 1, 1984. [6 gases in hydrogen-dibenzofuran and in hydrogen-g-methylanthracene  

SciTech Connect (OSTI)

A sophisticated perturbation chromatography technique has been used to study the vapor-liquid equilibrium behavior of six light gases in two hydrogen-coal liquid model compounds systems. Infinite-dilution K values are reported for methane, ethane, propane, n-butane, carbon dioxide and hydrogen sulfide in: (1) hydrogen-dibenzofuran system at 373.2 and 398.2/sup 0/K and up to 6 MPa; and (2) hydrogen-g-methylanthracene systems at 373.2, 398.2, 423.2, 448.2 and 473.2/sup 0/K and up to 21 M Pa. Henry's constants were determined for the light gases in 9-methylanthracene. Second cross virial coefficients and vapor-phase infinite-dilution fugacity coefficients were calculated for the hydrocarbon gases in hydrogen. The results were combined with the experimental K-value measurements to obtain Henry's constants in hydrogen-9-methylanthracene mixtures of fixed liquid composition. The constants thus obtained show a significant dependence of hydrogen solubility. 1 reference.

Kobayshi, R.

1984-01-01T23:59:59.000Z

88

Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through  

E-Print Network [OSTI]

Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through Hydrogenation Xiaobo . Hydrogen adsorption was proposed to proceed through molecular H2 dissoci- ation via a hydride intermediate and subsequent migration, and studies of hydrogen adsorption on (TiO2)N clusters revealed that an initial

89

Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants  

SciTech Connect (OSTI)

Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

2001-11-06T23:59:59.000Z

90

Synthesis and Optical Properties of Sulfide Nanoparticles Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Synthesis and Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Abstract: Many...

91

Catalytic reduction of CO with hydrogen sulfide. 3. Study of adsorption of O/sub 2/, CO, and CO coadsorbed with H/sub 2/S on anatase and rutile using Auger electron spectroscopy and temperature-programmed desorption  

SciTech Connect (OSTI)

In O/sub 2/ and CO adsorption on anatase, only one weakly bound molecular desorption state was observed. For CO on rutile, there was a strongly bound and a weakly bound state. For O/sub 2/ rutile, a weakly bound state and two strongly chemisorbed states were observed. These strongly bound states are associated with the surface lattice anion vacancies produced on rutile (110). The amount of chemisorption in one of the strongly bound oxygen desorption states is correlated with the initial rate of irreversible adsorption of H/sub 2/S on rutile. Coadsorption of CO and H/sub 2/S indicates that strongly chemisorbed CO interacts with strongly chemisorbed H/sub 2/S to yield intermediates which desorb as CH/sub 3/SH and CH/sub 4/ at T approx. 800 K. At higher temperatures the surface sulfide concentration dominates the -SH concentration, explaining the dominance of COS in the product mixture. Implications of commercial hydrodesulfurization catalysts are discussed.

Beck, D.D.; White, J.M.; Ratcliffe, C.T.

1986-07-03T23:59:59.000Z

92

Carbon Dioxide Capture by Absorption with Potassium Carbonate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Dioxide Capture by Absorption Carbon Dioxide Capture by Absorption with Potassium Carbonate Background Although alkanolamine solvents, such as monoethanolamine (MEA), and solvent blends have been developed as commercially-viable options for the absorption of carbon dioxide (CO 2 ) from waste gases, natural gas, and hydrogen streams, further process improvements are required to cost-effectively capture CO 2 from power plant flue gas. The promotion of potassium carbonate (K

93

Hydrogen separation process  

DOE Patents [OSTI]

A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

2011-05-24T23:59:59.000Z

94

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS  

E-Print Network [OSTI]

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS S.W. Banovic, J.N. Du (Received January 5, 1998) (Accepted March 23, 1998) Introduction Iron-aluminum weld overlay coatings, the application of iron-aluminum alloys is currently limited due to hydrogen cracking susceptibility subsequent

DuPont, John N.

95

Stable catalyst layers for hydrogen permeable composite membranes  

DOE Patents [OSTI]

The present invention provides a hydrogen separation membrane based on nanoporous, composite metal carbide or metal sulfide coated membranes capable of high flux and permselectivity for hydrogen without platinum group metals. The present invention is capable of being operated over a broad temperature range, including at elevated temperatures, while maintaining hydrogen selectivity.

Way, J. Douglas; Wolden, Colin A

2014-01-07T23:59:59.000Z

96

C. Plennevaux et al., Electrochemistry Communications 26 (2013) 1720 Contribution of CO2 on hydrogen evolution and hydrogen permeation in low  

E-Print Network [OSTI]

Introduction The risk of hydrogen embrittlement of steels is a primary concern for material selection in oil the risk of hydrogen embrittlement. Sulfide stress cracking (SSC) is one of the main risks of steel on hydrogen evolution and hydrogen permeation in low alloy steels exposed to H2S environment C. Plennevauxa

Paris-Sud XI, Université de

97

Sulfur geochemistry of thermogenic gas hydrate and associated sediment from the Texas-Louisiana continental slope  

E-Print Network [OSTI]

total reduced sulfide (TRS), acid volatile sulfide, and citrate-dithionate and HCl extractable iron. Pore-fluid measurements included []H?S, chloride, sulfate, ammonia and total dissolved inorganic carbon. Gas hydrate hydrogen sulfide and carbon dioxide...

Gledhill, Dwight Kuehl

2001-01-01T23:59:59.000Z

98

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

99

Sulfidation of coal gasifier heat exchanger alloys  

Science Journals Connector (OSTI)

Three steels, viz., INCOLOY* 800H, Fecralloy, and AlSI 310, were exposed to a simulated low Btu coal gasifier product gas at 450 C. Sulfidation...

S. R. J. Saunders; S. Schlierer

1986-03-01T23:59:59.000Z

100

Nitrogen dioxide detection  

DOE Patents [OSTI]

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

New Texas Oil Project Will Help Keep Carbon Dioxide Underground |  

Broader source: Energy.gov (indexed) [DOE]

Texas Oil Project Will Help Keep Carbon Dioxide Underground Texas Oil Project Will Help Keep Carbon Dioxide Underground New Texas Oil Project Will Help Keep Carbon Dioxide Underground February 5, 2013 - 12:05pm Addthis The Air Products and Chemicals hydrogen production facilities in Port Arthur, Texas, is funded by the Energy Department through the 2009 Recovery Act. It is managed by the Office of Fossil Energy’s National Energy Technology Laboratory. | Photo credit Air Products and Chemicals hydrogen production facilities. The Air Products and Chemicals hydrogen production facilities in Port Arthur, Texas, is funded by the Energy Department through the 2009 Recovery Act. It is managed by the Office of Fossil Energy's National Energy Technology Laboratory. | Photo credit Air Products and Chemicals hydrogen

102

New Texas Oil Project Will Help Keep Carbon Dioxide Underground |  

Broader source: Energy.gov (indexed) [DOE]

New Texas Oil Project Will Help Keep Carbon Dioxide Underground New Texas Oil Project Will Help Keep Carbon Dioxide Underground New Texas Oil Project Will Help Keep Carbon Dioxide Underground February 5, 2013 - 12:05pm Addthis The Air Products and Chemicals hydrogen production facilities in Port Arthur, Texas, is funded by the Energy Department through the 2009 Recovery Act. It is managed by the Office of Fossil Energy’s National Energy Technology Laboratory. | Photo credit Air Products and Chemicals hydrogen production facilities. The Air Products and Chemicals hydrogen production facilities in Port Arthur, Texas, is funded by the Energy Department through the 2009 Recovery Act. It is managed by the Office of Fossil Energy's National Energy Technology Laboratory. | Photo credit Air Products and Chemicals hydrogen

103

NANOPOROUS NONOXIDIC MATERIALS FOR HYDROGEN PURIFICATION Mercouri G. Kanatzidis, Department of Chemistry, Northwestern University  

E-Print Network [OSTI]

promising alternative sources of energy is hydrogen fuel cells. However, hydrogen must be purified, or separated from other molecules, before it can be used as fuel. Current methods of refining hydrogen, hydrogen fuel technology. Separation of hydrogen and carbon dioxide occurs as hydrogen (white) passes

Shull, Kenneth R.

104

Biogenic formation of photoactive arsenic-sulfide nanotubes by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 . Biogenic formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 ....

105

High pressure/high temperature vapor liquid equilibrium study of light gases in hydrogen-coal liquid model compound systems using perturbation chromatography  

SciTech Connect (OSTI)

Perturbation chromatography or gas-liquid partition chromatography (GLPC) provides a powerful tool for making physicochemical measurements. In this investigation GLPC was applied to study the vapor-liquid equilibrium behavior of light gases in nonvolatile coal liquid model compound solvents at high temperatures and high pressures. Improvements made in existing GLPC techniques include: the use of a high pressure tandem proportioning pump to give precise control of the carrier gas flow rate and low pressure drops; a high pressure ionization chamber to detect the injection of very dilute radioactive sample gases; and the use of a microcomputer to provide instantaneous integration and very precise retention times of the chromatographic peaks. Infinite dilution K-values for methane, ethane, propane, n-butane, carbon dioxide, and hydrogen sulfide in hydrogen-dibenzofuran systems were obtained at 100 and 125 C and up to 800 psia. Infinite dilution K-values for the same light gases in hydrogen-9-methylanthracene systems were obtained at 100, 125, 150, 175, and 200 C and up to 3000 psia. Henry's constants were determined for the light gases in 9-methylanthracene. Second cross virial coefficients and vapor phase infinite dilution fugacity coefficients were calculated for methane, ethane, propane, and n-butane in hydrogen. These results were combined with the experimental K-value measurements to obtain Henry's constants in hydrogen-9-methylanthracene mixtures of fixed liquid compositions. Infinite dilution heats of solution of the solute gases in the mixtures were calculated.

Kragas, T.K.

1983-01-01T23:59:59.000Z

106

Viscosity of tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

107

Kinetics and mechanism of thiophene hydrodesulfurization over carbon-supported transition metal sulfides  

SciTech Connect (OSTI)

Results of a detailed kinetic study on the thiophene hydrodesulfurization reaction at atmospheric pressure over a set of carbon-supported transition metal sulfides, i.e., the sulfides of Co, Mo, Rh, and the mixed CoMo sulfide, are presented. It is found that (partially) hydrogenated thiophenes, i.e., 2,3-dihydrothiophene, 2,5-dihydrothiophene, and tetrahydrothiophene, are important intermediates in the reaction mechanism. The reaction orders of thiophene suggest that carbon-sulfur bond cleavage is rate limiting for most of the catalysts. The CoMo catalyst may have hydrogenative sulfur removal as the rate limiting step. This catalyst shows a strong decrease in apparent activation energy with temperature to be ascribed to a large change in steady state surface coverage by thiophene (or H{sub 2}S) as a function of temperature. This is consistent with a strong interaction between catalyst and thiophene. The Rh catalyst most probably shows a phase transition leading to different kinetic parameters. A strong interaction between the metal sulfide and thiophene is important for a high HDS activity. 38 refs., 4 figs., 5 tabs.

Hensen, E.J.M.; Vissenberg, M.J.; Beer, V.H.J. de [Eindhoven Univ. of Technology (Netherlands)] [and others] [Eindhoven Univ. of Technology (Netherlands); and others

1996-10-01T23:59:59.000Z

108

Coadsorption as a probe of mechanism: cyclic sulfides and straight chain thiols on Mo(110)  

SciTech Connect (OSTI)

The authors reported that tetrahydrothiophene and trimethylene sulfide undergo desulfurization on Mo(110) to form gaseous alkanes and alkenes in a temperature-programmed reaction experiment. In both cases, straight chain alkane evolution preceded alkene evolution. They proposed that the intermediate leading to straight chain alkanes and alkenes from these two cyclic sulfides is a surface thiolate. The thiolate undergoes competitive C/sub 1/-hydrogenation to alkane and C/sub 2/-dehydrogenation to alkene, depending on the surface hydrogenation concentration. They report here that coadsorbed cyclic sulfides C/sub n/H/sub 2n/S (n = 3, 4) and linear thiols C/sub m/H/sub 2m+1/SH(m = 2, 3, 4) react during a temperature-programmed reaction experiment to form alkanes C/sub n/H/sub 2n+2/ and C/sub m/H/sub 2m+2/ at exactly the same temperature. These experiments lend powerful support to their proposal that cyclic sulfides and straight chain thiols react on Mo(110) by way of a thiolate intermediate.

Roberts, J.T.; Friend, C.M.

1987-07-08T23:59:59.000Z

109

Abatement of Air Pollution: Control of Carbon Dioxide Emissions/Carbon  

Broader source: Energy.gov (indexed) [DOE]

Carbon Dioxide Carbon Dioxide Emissions/Carbon Dioxide Budget Trading Program (Connecticut) Abatement of Air Pollution: Control of Carbon Dioxide Emissions/Carbon Dioxide Budget Trading Program (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Connecticut

110

Turning Sun and Water Into Hydrogen Fuel | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel May 5, 2011 - 1:27pm Addthis Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D. Damsgaard, Thomas Pedersen and Ole Hansen, Technical University of Denmark Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D.

111

Turning Sun and Water Into Hydrogen Fuel | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel Turning Sun and Water Into Hydrogen Fuel May 5, 2011 - 1:27pm Addthis Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D. Damsgaard, Thomas Pedersen and Ole Hansen, Technical University of Denmark Tiny silicon pillars, used to absorb light. When dotted with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately two micrometers in diameter. | Photo courtesy of Christian D.

112

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments  

E-Print Network [OSTI]

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments and Water: Influence on Hard;ObjectivesObjectives Examine sediment sulfide levels in the SuwanneeExamine sediment sulfide levels of sulfide on hard clam survivalsurvival #12;MethodsMethods SedimentSediment porewaterporewater samples

Florida, University of

113

Carbon dioxide, the feedstock for using renewable energy  

Science Journals Connector (OSTI)

Extrapolation of world energy consumption between 1990 and 2007 to the future reveals the complete exhaustion of petroleum, natural gas, uranium and coal reserves on Earth in 2040, 2044, 2049 and 2054, respectively. We are proposing global carbon dioxide recycling to use renewable energy so that all people in the whole world can survive. The electricity will be generated by solar cell in deserts and used to produce hydrogen by seawater electrolysis at t nearby desert coasts. Hydrogen, for which no infrastructures of transportation and combustion exist, will be converted to methane at desert coasts by the reaction with carbon dioxide captured by energy consumers. Among systems in global carbon dioxide recycling, seawater electrolysis and carbon dioxide methanation have not been performed industrially. We created energy-saving cathodes for hydrogen production and anodes for oxygen evolution without chlorine formation in seawater electrolysis, and ideal catalysts for methane formation by the reaction of carbon dioxide with hydrogen. Prototype plant and industrial scale pilot plant have been built.

K Hashimoto; N Kumagai; K Izumiya; Z Kato

2011-01-01T23:59:59.000Z

114

Polymer system for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

115

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

1998-11-17T23:59:59.000Z

116

Hydrogen Sulfide Combustion:? Relevant Issues under Claus Furnace Conditions  

Science Journals Connector (OSTI)

Their mechanisms include the chemistry that leads to the formation of SO, SO2, SO3, and S2, as well as other chemical paths for the destruction of H2S. Another important source of chemistry and kinetics data that is more recent can be found in the University of Leeds, U.K. Sulfur Mechanism (which can be found on the Internet at www.chem.leeds.ac.uk/Combustion/Combustion.html). ... The databank contains the ideal gas heat capacity, free energy of formation, and enthalpy of formation for many species, and these values are accurate at the high temperatures that are typical of combustion for more than 59 stable and radical species. ... Clark et al.4 noted in their study of Claus chemistry that H2S combusts more quickly than the hydrocarbons that were present in the initial gas mixture. ...

Ivan A. Gargurevich

2005-08-23T23:59:59.000Z

117

Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of  

E-Print Network [OSTI]

. These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

Borguet, Eric

118

Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor  

E-Print Network [OSTI]

monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures thanSulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20­600 times greater

Tobin, Roger G.

119

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network [OSTI]

,2 operated by fuel cells. Unfortunately, the lack of infrastructure, such as a network of hydrogen refueling of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiencyPerformance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel

Azad, Abdul-Majeed

120

What's Next for Vanadium Dioxide?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

NREL: Learning - Hydrogen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production Production The simplest and most common element, hydrogen is all around us, but always as a compound with other elements. To make it usable in fuel cells or otherwise provide energy, we must expend energy or modify another energy source to extract it from the fossil fuel, biomass, water, or other compound in which it is found. Nearly all hydrogen production in the United States today is by steam reformation of natural gas. This, however, releases carbon dioxide in the process and trades one relatively clean fuel for another, with associated energy loss, so it does little to meet national energy needs. Hydrogen can also be produced by electrolysis-passing an electrical current through water to break it into hydrogen and oxygen-but electrolysis is inefficient and is only as clean

122

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

123

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

124

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

125

Hydrogen Selective Exfoliated Zeolite Membranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Selective Exfoliated Zeolite Hydrogen Selective Exfoliated Zeolite Membranes Background An important component of the Department of Energy (DOE) Carbon Sequestration Program is the development of carbon capture technologies for power systems. Capturing carbon dioxide (CO 2 ) from mixed-gas streams is a first and critical step in carbon sequestration. To be technically and economically viable, a successful separation method must be applicable to industrially relevant gas streams at realistic

126

New energy, new hazards ? The hydrogen scenario  

E-Print Network [OSTI]

"energy carrier" ? Hydrogen based economy and associated energy converters fuel cell systems are said dioxide...)1 . Besides, energy conversion yields seem to be better and finally it allows fossil fuels. Hydrogen can be used as an energy carrier for many traditional technologies such as cars (direct combustion

Paris-Sud XI, Université de

127

Hydrogen Highways  

E-Print Network [OSTI]

adequate on-board hydrogen storage is essential, and remainsjustify their costs. Hydrogen storage remains an importantto 10,000 psi, liquid hydrogen storage, and other solid and

Lipman, Timothy

2005-01-01T23:59:59.000Z

128

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents [OSTI]

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1993-03-30T23:59:59.000Z

129

Hydrogen Storage Technologies Hydrogen Delivery  

E-Print Network [OSTI]

Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This.................................................................................. 13 6. Hydrogen Storage). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission

130

Hydrogen Delivery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mark Paster Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technology Program Hydrogen Production and Delivery Team Hydrogen Delivery Goal Hydrogen Delivery Goal Liquid H 2 & Chem. Carriers Gaseous Pipeline Truck Hydrides Liquid H 2 - Truck - Rail Other Carriers Onsite reforming Develop Develop hydrogen fuel hydrogen fuel delivery delivery technologies that technologies that enable the introduction and enable the introduction and long long - - term viability of term viability of hydrogen as an energy hydrogen as an energy carrier for transportation carrier for transportation and stationary power. and stationary power. Delivery Options * End Game - Pipelines - Other as needed * Breakthrough Hydrogen Carriers * Truck: HP Gas & Liquid Hydrogen

131

Metal-Organic Frameworks as Adsorbents for Hydrogen Purification...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture Previous Next List Z. R. Herm, J. A. Swisher, B. Smit, R. Krishna, and J....

132

Supercritical Water Desulfurization of Organic Sulfides Is Consistent with Free-Radical Kinetics  

Science Journals Connector (OSTI)

Pushkaraj R. Patwardhan , Michael T. Timko , Caleb A. Class , Robin E. Bonomi , Yuko Kida , Hector H. Hernandez , Jefferson W. Tester , and William H. Green * ... In contrast to sulfides and disulfides, they observed that ionic reactions dominated mercaptan decomposition and resulted in greater conversions in aqueous medium. ... Model compounds were selected to represent the various classes of sulfur compounds present in crude oil: an alkyl sulfide (hexyl sulfide), a cyclic sulfide (tetrahydrothiophene), an alkyl aryl sulfide (isopropyl phenyl sulfide), three aromatic sulfides (dibenzyl sulfide, benzyl phenyl sulfide, and diphenyl sulfides), and two thiophenic compounds (thiophene and dibenzothiophene). ...

Pushkaraj R. Patwardhan; Michael T. Timko; Caleb A. Class; Robin E. Bonomi; Yuko Kida; Hector H. Hernandez; Jefferson W. Tester; William H. Green

2013-09-20T23:59:59.000Z

133

Florida Hydrogen Initiative  

SciTech Connect (OSTI)

The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

Block, David L

2013-06-30T23:59:59.000Z

134

Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

Air Products and Chemicals, Inc., is developing the sour pressure swing adsorption (PSA) technology which can be used to reject acid gas components (hydrogen sulfide [H{sub 2}S] and carbon dioxide [CO{sub 2}]) from sour syngas streams such as coal gasification syngas. In the current work, tests were conducted to investigate the impact of continuous exposure of real sour syngas and dilute levels of hydrochloric acid (HCl) and ammonia (NH{sub 3}) on the preferred adsorbent of that process. The results show a modest (~10%15%) decrease in CO{sub 2} adsorption capacity after sour syngas exposure, as well as deposition of metals from carbonyl decomposition. Continuous exposure to HCl and NH{sub 3} yield a higher degree of CO{sub 2} capacity degradation (up to 25%). These tests represent worst-case approaches since the exposure is continuous and the HCl and NH{sub 3} levels are relatively high compare to an industrial sour syngas stream. Long-term PSA tests are needed to unequivocally evaluate the impact of cyclic exposure to these types of streams.

Dunham, Grant

2012-03-15T23:59:59.000Z

135

Hydrogens Potential  

Science Journals Connector (OSTI)

Estimates of future demand for non-fossil produced hydrogen and of its potential are oriented toward ... to the environment as the present fossil energy economy [10.4, 10.9].

J. Nitsch; C. Voigt

1988-01-01T23:59:59.000Z

136

CARBON DIOXIDE EMISSION REDUCTION  

E-Print Network [OSTI]

.5 Primary Energy Use and Carbon Dioxide Emissions for Selected US Chemical Subsectors in 1994 ...............................................................................................................16 Table 2.7 1999 Energy Consumption and Specific Energy Consumption (SEC) in the U.S. Cement Efficiency Technologies and Measures in Cement Industry.................22 Table 2.9 Energy Consumption

Delaware, University of

137

Carbon dioxide recovery from an integrated coal gasifier, combined cycle plant using membrane separation and a CO2 gas turbine  

Science Journals Connector (OSTI)

A scheme is described for electricity production based on coal gasification with recovery of carbon dioxide. In this scheme, coal is gasified into a coal gas, consisting mainly of hydrogen and carbon monoxide. A ...

Chris Hendriks

1994-01-01T23:59:59.000Z

138

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

139

Stabilization of Lead Sulfide Nanoparticles by Polyamines in Aqueous Solutions. A Structural Study of the Dispersions  

Science Journals Connector (OSTI)

Department of Chemistry, University of Cyprus, P.O. ... (1, 42-45) Excluding some older aqueous procedures, based on sulfur sources such as hydrogen sulfide gas or thioacetamide,(23, 24) optimal size and polydispersity control is currently provided in organic solvents either at high temperatures, using variants of the TOP/TOPO method,(21) or closer to room temperature with oleylamine as a coordinating solvent. ... The pH was equal to 6 in the cases of PAH and PDDA and equal to 10 in the case of PEI, these being the natural pH values of the dispersions, obtained immediately upon mixing their components. ...

Elena Koupanou; Silvia Ahualli; Otto Glatter; Angel Delgado; Frank Krumeich; Epameinondas Leontidis

2010-10-14T23:59:59.000Z

140

NETL: Carbon Dioxide 101 FAQs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is carbon dioxide? is carbon dioxide? CO2 Dipole Carbon Dioxide Carbon dioxide (chemical name CO2) is a clear gas composed of one atom of carbon (C) and two atoms of oxygen (O). Carbon dioxide is one of many chemical forms of carbon on the Earth. It does not burn, and in standard temperature and pressure conditions it is stable, inert, and non-toxic. Carbon dioxide occurs naturally in small amounts (about 0.04%) in the Earth's atmosphere. The volume of CO2 in the atmosphere is equivalent to one individual in a crowd of 2,500. Carbon dioxide is produced naturally by processes deep within the Earth. This CO2 can be released at the surface by volcanoes or might be trapped in natural underground geologic CO2 deposits, similar to underground deposits of oil and natural gas. As a major greenhouse gas, CO2 helps create and

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Hydrogen sensor  

DOE Patents [OSTI]

A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

2010-11-23T23:59:59.000Z

142

Nuclear Hydrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Error Error Nuclear Hydrogen - RCC cannot be displayed due to a timeout error. We recommend: * Refresh Nuclear Hydrogen - RCC * Increasing your portlet timeout setting. *...

143

Organusulfur Catalysis With Reduced Molybdenum Sulfides Containing the Mo6S8 Cluster  

SciTech Connect (OSTI)

Industrial synthesis of sulfur-containing organic chemicals basically focuses on the broad categories of mercaptans (thiols), alkylsulfides (thioethers), polysulfides, and thiophenes. Of the organo-sulfur compounds produced, by far the most important in terms of quantities produced is methyl mercaptan (methanethiol or MeSH), which is produced mainly for the downstream production of methionine and methanesulfonyl chloride. Higher thiols are also used in the manufacture of rubber and plastics as polymerization regulators, chain transfer agents, or initiators. Other important organosulfur chemicals are dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), both of which are used extensively for presulfiding of industrial hydroprocessing catalysts, and substituted thiophenes which are used as intermediates for production of agrochemicals, dyes, and pharmaceuticals. Thiols are produced commercially at the rate of about 10{sup 4} ton/yr from hydrogen sulfide (H{sub 2}S) and alcohols or olefins, using homogeneous free-radical synthesis, or heterogeneous catalysts based on solid acids or supported metal oxides and/or sulfides. Despite this large production rate, and the industrial importance of the organosulfur compounds, only limited research has been devoted to the development of new catalytic materials for their synthesis. Additionally, for most organosulfur catalytic reactions, only limited information exists about reaction mechanisms, active sites, adsorbed surface species, and especially the nature of the catalysts under reaction conditions.

Thomas Jay Paskach

2002-08-27T23:59:59.000Z

144

Characterization and activity of ferric-sulfide-based catalyst in model reactions of direct coal liquefaction: Effect of preparation conditions  

SciTech Connect (OSTI)

The authors studied the activity of various ferric-sulfide-based catalysts in model hydrogenation and cracking reactions under conditions typical of direct coal liquefaction (DCL). The catalysts used were mixtures of FeS{sub 2} (pyrite, PY) and nonstoichiometric FeS{sub x} (pyrrhotite, PH) obtained by high-temperature disproportionation of ferric sulfide in a nitrogen atmosphere or a hydrogen atmosphere. The structural changes in the catalyst were also examined, both before and after the model reactions. The cracking functionality of the catalysts was studied by using cumene, and the hydrocracking functionality was studied by using diphenylmethane. Phenanthrene was used as a model compound for hydrogenation and hydrogen shuttling. Phenanthrene hydrogenation was studied in the presence of H{sub 2}(g), and hydrogen shuttling was studied when a hydrogen donor (tetralin) was present in the absence of H{sub 2}(g). All the model reactions were performed under conditions typical of DCL: 400 C and 1,000 psig for 30 min. The surface and bulk of the catalysts were characterized by Auger electron spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and atomic absorption spectroscopy. The performance of the catalysts was found to vary with the type of reaction, the initial ratio of FeS{sub x} to FeS{sub 2} (PH/PY) found in the catalyst, and the catalyst age. Catalysts freshly prepared in a nitrogen atmosphere were most active for model hydrogenation and hydrocracking runs. Catalysts freshly prepared in hydrogen were most active in shuttling. A simple model was developed to explain changes in the surface and bulk of the catalysts.

Chadha, A.; Stinespring, C.D.; Stiller, A.H.; Zondlo, J.W.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1997-02-01T23:59:59.000Z

145

NETL: News Release - DOE Advances Production of Hydrogen from Coal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 , 2006 6 , 2006 DOE Advances Production of Hydrogen from Coal Projects Selected to Address Technological Challenges of Hydrogen Production in Large-Scale Facilities WASHINGTON, DC - The Department of Energy today announced the selection of six research and development projects that will promote the production of hydrogen from coal at large-scale facilities. This central approach will combat climate change by allowing for the capture - and subsequent sequestration - of carbon dioxide generated during hydrogen production. The selections support President Bush's Hydrogen Fuel Initiative, which provides funding for research and technology development to realize a future hydrogen economy that minimizes America's dependence on foreign oil and reduces greenhouse gas emissions.

146

CARBON DIOXIDE FIXATION.  

SciTech Connect (OSTI)

Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

FUJITA,E.

2000-01-12T23:59:59.000Z

147

Analysis of Ontario's hydrogen economy demands from hydrogen fuel cell vehicles  

Science Journals Connector (OSTI)

The Hydrogen Economy is a proposed system where hydrogen is produced from carbon dioxide free energy sources and is used as an alternative fuel for transportation. The utilization of hydrogen to power fuel cell vehicles (FCVs) can significantly decrease air pollutants and greenhouse gases emission from the transportation sector. In order to build the future hydrogen economy, there must be a significant development in the hydrogen infrastructure, and huge investments will be needed for the development of hydrogen production, storage, and distribution technologies. This paper focuses on the analysis of hydrogen demand from hydrogen \\{FCVs\\} in Ontario, Canada, and the related cost of hydrogen. Three potential hydrogen demand scenarios over a long period of time were projected to estimate hydrogen \\{FCVs\\} market penetration, and the costs associated with the hydrogen production, storage and distribution were also calculated. A sensitivity analysis was implemented to investigate the uncertainties of some parameters on the design of the future hydrogen infrastructure. It was found that the cost of hydrogen is very sensitive to electricity price, but other factors such as water price, energy efficiency of electrolysis, and plant life have insignificant impact on the total cost of hydrogen produced.

Hui Liu; Ali Almansoori; Michael Fowler; Ali Elkamel

2012-01-01T23:59:59.000Z

148

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Quality Issues for Fuel Cell Vehicles Hydrogen Quality Issues for Fuel Cell Vehicles Introduction Developing and implementing fuel quality specifications for hydrogen are prerequisites to the widespread deployment of hydrogen-fueled fuel cell vehicles. Several organizations are addressing this fuel quality issue, including the International Standards Organization (ISO), the Society of Automotive Engineers (SAE), the California Fuel Cell Partnership (CaFCP), and the New Energy and Industrial Technology Development Organization (NEDO)/Japan Automobile Research Institute (JARI). All of their activities, however, have focused on the deleterious effects of specific contaminants on the automotive fuel cell or on-board hydrogen storage systems. While it is possible for the energy industry to provide extremely pure hydrogen, such hydrogen could entail excessive costs. The objective of our task is to develop a process whereby the hydrogen quality requirements may be determined based on life-cycle costs of the complete hydrogen fuel cell vehicle "system." To accomplish this objective, the influence of different contaminants and their concentrations in fuel hydrogen on the life-cycle costs of hydrogen production, purification, use in fuel cells, and hydrogen analysis and quality verification are being assessed.

149

Refractive index of tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

150

Dielectric constant of tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

151

Comparative studies of hydrodenitrogenation by mixed metal sulfide catalysts  

E-Print Network [OSTI]

. , Sanchez, K. M. , and Reibenspies, J. , "Synthesis and characterization of [Et4N][M(CO)5SR] and [Et4N]2[M2 (CO) 8 (SR) 2] complexes (M = Cr, Mo, W) . Ligand substitution... to mimic the commercial catalyst (ie. no sulfide bridges prior to activation) l a Ni/Mo sulfide catalyst which consisted of Ni and Mo atoms brought in intimate contact by sulfide bridges; Ni/Mo and Co/Mo organometallic catalysts whose central metal had...

Luchsinger, Mary Margaret

1990-01-01T23:59:59.000Z

152

EA-1846: Demonstration of Carbon Dioxide Capture and Sequestration of Steam  

Broader source: Energy.gov (indexed) [DOE]

46: Demonstration of Carbon Dioxide Capture and Sequestration 46: Demonstration of Carbon Dioxide Capture and Sequestration of Steam Methane Reforming Process Gas Used for Large-Scale Hydrogen Production, Port Arthur, Texas EA-1846: Demonstration of Carbon Dioxide Capture and Sequestration of Steam Methane Reforming Process Gas Used for Large-Scale Hydrogen Production, Port Arthur, Texas Overview DOE completed a final environmental assessment (EA) for a project under Area I of the Industrial Carbon Capture and Sequestration from Industrial Sources and Innovative Concepts for Beneficial CO2 Use . Based on the analyses in the EA DOE determined that its proposed action - awarding a grant to Air Products and Chemicals, Inc. to design and demonstrate a state-of-the-art system to concentrate carbon dioxide (CO,) from two steam

153

Decoding Titanium Dioxide | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

range from the production of clean hydrogen energy and self-cleaning auto windshields to purification of air and water. "The photocatalytic and thermo-catalytic chemistry of the...

154

A paradox resolved: Sulfide acquisition by roots of seep tubeworms sustains net chemoautotrophy  

Science Journals Connector (OSTI)

...numbers indicate consumption and negative numbers...require sulfide to fuel autotrophic carbon...In the split-vessel respiration experiments...production to consumption) when sulfide...animal biomass to vessel volume necessitated...sulfide and oxygen consumption rates...

John K. Freytag; Peter R. Girguis; Derk C. Bergquist; Jason P. Andras; James J. Childress; Charles R. Fisher

2001-01-01T23:59:59.000Z

155

E-Print Network 3.0 - antimony sulfide colloid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

156

E-Print Network 3.0 - antimony sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

157

CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

Hobbs, D; Hector Colon-Mercado, H

2007-01-31T23:59:59.000Z

158

The Viscosity of Carbon Dioxide  

Science Journals Connector (OSTI)

26 July 1912 research-article The Viscosity of Carbon Dioxide P. Phillips The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access to Proceedings...

1912-01-01T23:59:59.000Z

159

Photosynthesis and carbon dioxide fixation  

Science Journals Connector (OSTI)

Photosynthesis and carbon dioxide fixation ... Photosynthetic pigments, photosystems, the Calvin cycle, the Hatch-Slack pathway, photorespiration, and photosynthetic yield improvement. ...

Muriel B. Bishop; Carl B. Bishop

1987-01-01T23:59:59.000Z

160

Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith  

DOE Patents [OSTI]

New amorphous molybdenum/tungsten sulfides with the general formula M.sup.n+.sub.2x/n (L.sub.6 S.sub.8)S.sub.x, where L is molybdenum or tungsten and M is a ternary metal, has been developed. Characterization of these amorphous materials by chemical and spectroscopic methods (IR, Raman, PES) shows that the (M.sub.6 S.sub.8).sup.0 cluster units are present. Vacuum thermolysis of the amorphous Na.sub.2x (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH first produces poorly crystalline NaMo.sub.6 S.sub.8 by disproportionation at 800.degree. C. and well-crystallized NaMo.sub.6 S.sub.8 at .gtoreq. 900.degree. C. Ion-exchange of the sodium material in methanol with soluble M.sup.2+ and M.sup.3+ salts (M=Sn, Co, Ni, Pb, La, Ho) produces the M.sup.n+.sub.2x/n (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH compounds. Additionally, the new reduced ternary molybdenum sulfides with the general formula M.sup.n+.sub.2x/n Mo.sub.6 S.sub.8+x (MeOH).sub.y MMOS! (M=Sn, Co, Ni) is an effective hydrodesulfurization (HDS) catalyst both as-prepared and after a variety of pretreatment conditions. Under specified pretreatment conditions with flowing hydrogen gas, the SnMoS type catalyst can be stabilized, and while still amorphous, can be considered as "Chevrel phase-like" in that both contain Mo.sub.6 S.sub.8 cluster units. Furthermore, the small cation NiMoS and CoMoS type pretreated catalyst showed to be very active HDS catalysts with rates that exceeded the model unpromoted and cobalt-promoted MoS.sub.2 catalysts.

Hilsenbeck, Shane J. (Ames, IA); McCarley, Robert E. (Ames, IA); Schrader, Glenn L. (Ames, IA); Xie, Xiaobing (College Station, TX)

1999-02-16T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Process for sequestering carbon dioxide and sulfur dioxide  

DOE Patents [OSTI]

A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

2009-10-20T23:59:59.000Z

162

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

163

Carbon dioxide capture and geological storage  

Science Journals Connector (OSTI)

...Blundell and Fraser Armstrong Carbon dioxide capture and geological storage Sam...Nottingham NG12 5GG, UK Carbon dioxide capture and geological storage is a...80-90%. It involves the capture of carbon dioxide at a large industrial...

2007-01-01T23:59:59.000Z

164

Carbon dioxide and climate  

SciTech Connect (OSTI)

Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

Not Available

1990-10-01T23:59:59.000Z

165

Hydrogen Analysis  

Broader source: Energy.gov [DOE]

Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

166

Hydrogen Storage  

Broader source: Energy.gov [DOE]

On-board hydrogen storage for transportation applications continues to be one of the most technically challenging barriers to the widespread commercialization of hydrogen-fueled vehicles. The EERE...

167

Hydrogen Safety  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

168

Hydrogen Cryomagnetics  

E-Print Network [OSTI]

% cryogenics (inc. MRI) 29% pressurisation and purging 11%controlled atmospheres (inc. breathing) 6% 4 Figure 5. Simplified price-cost, supply-demand relationship that is central to the helium market model developed during the Helium Resources... of hydrogen large amounts of hydrogen must be available for liquefaction. This poses problems for the production of liquid hydrogen via intermittent wind energy and via microwave plasma reactors that are not scalable as a result of low hydrogen production...

Glowacki, B. A.; Hanely, E.; Nuttall, W. J.

2014-01-01T23:59:59.000Z

169

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

2000-01-01T23:59:59.000Z

170

Effective hydrogen generation and resource circulation based on sulfur cycle system  

SciTech Connect (OSTI)

For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, system integration to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this system integration, the sulfur cycle system for the new energy generation can be constructed.

Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

2013-12-10T23:59:59.000Z

171

Hydrogenation apparatus  

DOE Patents [OSTI]

Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

Friedman, J.; Oberg, C. L.; Russell, L. H.

1981-06-23T23:59:59.000Z

172

Toward a quantitative model for the formation of gravitational magmatic sulfide deposits  

E-Print Network [OSTI]

concentration at sulfide saturation (referred to as sulfur solubility for simplicity) decreases. As the melt of sulfide liquid from a silicate melt, and the coupled growth kinetics and settling dynamics of sulfide liquid layer at the bottom of a magma chamber are referred to as the necessary criteria for sulfide ore

Zhang, Youxue

173

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-  

E-Print Network [OSTI]

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide dioxide separation and sequestration because the lower cost of carbon dioxide separation from for injection of carbon dioxide into oil or gas-bearing formations. An advantage of sequestration involving

174

Reducing carbon dioxide to products  

DOE Patents [OSTI]

A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

2014-09-30T23:59:59.000Z

175

decommissioning of carbon dioxide (CO  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

decommissioning of carbon dioxide (CO decommissioning of carbon dioxide (CO 2 ) storage wells. The manual builds on lessons learned through NETL research; the experiences of the Regional Carbon Sequestration Partnerships' (RCSPs) carbon capture, utilization, and storage (CCUS) field tests; and the acquired knowledge of industries that have been actively drilling wells for more than 100 years. In addition, the BPM provides an overview of the well-

176

Recuperative supercritical carbon dioxide cycle  

DOE Patents [OSTI]

A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

2014-11-18T23:59:59.000Z

177

Adsorption and methanation of carbon dioxide on a nickel/silica catalyst  

SciTech Connect (OSTI)

Temperature-programed desorption and reaction studies showed that increasing amounts of CO/sub 2/ adsorbed on silica-supported 6.9% nickel with increasing temperature to a maximum adsorption at approx. 443/sup 0/K, i.e., that the adsorption was activated; that CO/sub 2/ desorbed partly as CO/sub 2/ with the peak at 543/sup 0/K, and partly as CO with several peaks; that in the presence of hydrogen, nearly all adsorbed CO/sub 2/ desorbed as methane, and a small amount as CO; and that the methane desorption peaks from adsorbed CO and CO/sub 2/ both occurred at 473/sup 0/K. These results suggested that carbon dioxide adsorbed dissociatively as a carbon monoxide and an oxygen species. An observed absence of higher hydrocarbons in the methanation products of carbon dioxide was attributed to a high hydrogen/carbon monoxide surface ratio caused by the activated carbon dioxide adsorption.

Falconer, J.L.; Zagli, A.E.

1980-04-01T23:59:59.000Z

178

Microbial Electrosynthesis: Feeding Microbes Electricity To Convert Carbon Dioxide and Water to Multicarbon Extracellular Organic Compounds  

Science Journals Connector (OSTI)

...extracellular organic compounds...directly to the cells with a graphite...dioxide to organic compounds...microbial production of multicarbon...to convert solar energy that...hydrogen production was verified...outlet, but a solar-powered...a) H-cell device for...errors of the organic acid and...

Kelly P. Nevin; Trevor L. Woodard; Ashley E. Franks; Zarath M. Summers; Derek R. Lovley

2010-06-01T23:59:59.000Z

179

Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transition Metal Sulfide Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 March 21, 2003 Objectives ¾ Investigate non-platinum electro-catalysts with CO tolerance ¾ Focus on transition metal sulfides as electro-catalysts

180

Design and fabrication of a tin-sulfide annealing furnace  

E-Print Network [OSTI]

A furnace was designed and its heat transfer properties were analyzed for use in annealing thin-film tins-ulfide solar cells. Tin sulfide has been explored as an earth abundant solar cell material, and the furnace was ...

Lewis, Raymond (Raymond A.)

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Utilization of Dimethyl Sulfide as a Sulfur Source with the Aid of Light by Marinobacterium sp. Strain DMS-S1  

Science Journals Connector (OSTI)

...sulfone, methanesulfonate, diethyl sulfide, tetrahydrothiophene, diethyl sulfone, ethanesulfonate, methionine...Methylphenyl sulfide (, TK) Diphenyl sulfide (, TK) Tetrahydrothiophene (, TK) Tetramethylene sulfoxide (, TK) Sulfolane...

Hiroyuki Fuse; Osamu Takimura; Katsuji Murakami; Yukiho Yamaoka; Toshio Omori

2000-12-01T23:59:59.000Z

182

Hierarchically Ordered Cadmium Sulfide Nanowires Dispersed in Aqueous Solution  

Science Journals Connector (OSTI)

The paper reports on the preparation, characterization, and dispersion of cadmium sulfide (CdS) nanowires using ordered mesoporous silica, SBA-15, as a template. A homogeneous and stable dispersion of hierarchically ordered CdS nanowires in water ...This work demonstrates the formation of cadmium sulfide (CdS) nanowires. These nanowires are templated by mesoporous SBA-15 and their connectivity is tuned by the number of nanoconnectors (templated by micropores). They form stable dispersions in aqueous sodium dodecyl sulfate (SDS) solutions.

Rajagopalan Thiruvengadathan; Oren Regev

2005-05-17T23:59:59.000Z

183

Process for thin film deposition of cadmium sulfide  

DOE Patents [OSTI]

The present invention teaches a process for depositing layers of cadmium sulfide. The process includes depositing a layer of cadmium oxide by spray pyrolysis of a cadmium salt in an aqueous or organic solvent. The oxide film is then converted into cadmium sulfide by thermal ion exchange of the O.sup.-2 for S.sup.-2 by annealing the oxide layer in gaseous sulfur at elevated temperatures.

Muruska, H. Paul (East Windsor, NJ); Sansregret, Joseph L. (Scotch Plains, NJ); Young, Archie R. (Montclair, NJ)

1982-01-01T23:59:59.000Z

184

CdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible Light  

E-Print Network [OSTI]

and for the conversion of carbon dioxides into methanol and hydrocarbons. Metal chalcogenides1­9 are promisingCdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible driven pathway to hydrogen. Hydrogen is not only an environmentally benign fuel for the generation

Osterloh, Frank

185

Iron sulfide catalysts for coal liquefaction prepared using a micellar technique  

SciTech Connect (OSTI)

The authors have recently synthesized nanometer-size iron sulfide catalysts using a reverse micellar system. These particles are 40--70 nm in size and were used in laboratory-scale coal-liquefaction experiments. The catalyst particles were impregnated in situ on coal particles. The catalyst loading was 1.67% with respect to coal. The liquefaction run was carried out at 400 C for 30 min, at a pressure of 1,000 psia H{sub 2}(g) measured at ambient temperature (corresponding to approximately 2,000 psia at reaction conditions), tine absence of any solvent or hydrogen donor. The total conversion, as well as the yields of asphaltene plus preasphaltene and oil plus gas, increased after the run, relative to a thermal (noncatalytic) run. The activity of the micellar catalyst is slightly less than that of a nonmicellar catalyst. However, a slightly higher selectivity to oil plus gas is observed with the micellar catalyst.

Chadha, A.; Sharma, R.K.; Stinespring, C.D.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1996-09-01T23:59:59.000Z

186

EIS-0431: Hydrogen Energy California's Integrated Gasification Combined  

Broader source: Energy.gov (indexed) [DOE]

1: Hydrogen Energy California's Integrated Gasification 1: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California EIS-0431: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California Summary This EIS evaluates the potential environmental impacts of a proposal to provide financial assistance for the construction and operation of Hydrogen Energy California LLC (HECA's) project, which would produce and sell electricity, carbon dioxide and fertilizer. DOE selected this project for an award of financial assistance through a competitive process under the Clean Coal Power Initiative program. Public Comment Opportunities None available at this time. Documents Available for Download September 5, 2013

187

Carbon Dioxide Hydrate Process for Gas Separation from a Shifted Synthesis Gas Stream  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sequestration and Sequestration and Gasification Technologies Carbon DioxiDe HyDrate ProCess for Gas seParation from a sHifteD syntHesis Gas stream Background One approach to de-carbonizing coal is to gasify it to form fuel gas consisting predominately of carbon monoxide and hydrogen. This fuel gas is sent to a shift conversion reactor where carbon monoxide reacts with steam to produce carbon dioxide (CO 2 ) and hydrogen. After scrubbing the CO 2 from the fuel, a stream of almost pure hydrogen stream remains, which can be burned in a gas turbine or used to power a fuel cell with essentially zero emissions. However, for this approach to be practical, it will require an economical means of separating CO 2 from mixed gas streams. Since viable options for sequestration or reuse of CO

188

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage Systems Modeling and Analysis Hydrogen Storage Systems Modeling and Analysis Several different approaches are being pursued to develop on-board hydrogen storage systems for light-duty vehicle applications. The different approaches have different characteristics, such as: the thermal energy and temperature of charge and discharge kinetics of the physical and chemical process steps involved requirements for the materials and energy interfaces between the storage system and the fuel supply system on one hand, and the fuel user on the other Other storage system design and operating parameters influence the projected system costs as well. Argonne researchers are developing thermodynamic, kinetic, and engineering models of the various hydrogen storage systems to understand the characteristics of storage systems based on these approaches and to evaluate their potential to meet the DOE targets for on-board applications. The DOE targets for 2015 include a system gravimetric capacity of 1.8 kWh/kg (5.5 wt%) and a system volumetric capacity of 1.3 kWh/L (40 g/L). We then use these models to identify significant component and performance issues, and evaluate alternative system configurations and design and operating parameters.

189

Weyburn Carbon Dioxide Sequestration Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Weyburn Carbon DioxiDe SequeStration Weyburn Carbon DioxiDe SequeStration ProjeCt Background Since September 2000, carbon dioxide (CO 2 ) has been transported from the Dakota Gasification Plant in North Dakota through a 320-km pipeline and injected into the Weyburn oilfield in Saskatchewan, Canada. The CO 2 has given the Weyburn field, discovered 50 years ago, a new life: 155 million gross barrels of incremental oil are slated to be recovered by 2035 and the field is projected to be able to store 30 million tonnes of CO 2 over 30 years. CO 2 injection began in October of 2005 at the adjacent Midale oilfield, and an additional 45-60 million barrels of oil are expected to be recovered during 30 years of continued operation. A significant monitoring project associated with the Weyburn and Midale commercial

190

Life cycle assessment of various hydrogen production methods  

Science Journals Connector (OSTI)

A comprehensive life cycle assessment (LCA) is reported for five methods of hydrogen production, namely steam reforming of natural gas, coal gasification, water electrolysis via wind and solar electrolysis, and thermochemical water splitting with a CuCl cycle. Carbon dioxide equivalent emissions and energy equivalents of each method are quantified and compared. A case study is presented for a hydrogen fueling station in Toronto, Canada, and nearby hydrogen resources close to the fueling station. In terms of carbon dioxide equivalent emissions, thermochemical water splitting with the CuCl cycle is found to be advantageous over the other methods, followed by wind and solar electrolysis. In terms of hydrogen production capacities, natural gas steam reforming, coal gasification and thermochemical water splitting with the CuCl cycle methods are found to be advantageous over the renewable energy methods.

E. Cetinkaya; I. Dincer; G.F. Naterer

2012-01-01T23:59:59.000Z

191

Carbon Dioxide: Threat or Opportunity?  

E-Print Network [OSTI]

tion will be by direct combustion for the generation of power, but an increasing proportion will be con verted to syngas for chemical and fuel uses. Coal gasification is projected to become a major industry in the next decade. For every ton of coal... entering the gasification process, 1.88 lons of carbon dio xide are produced. This carbon dioxide is removed in virtually pure form by existing technology. This same technology can be applied to remove carbon dioxide from stack gases produced by power...

McKinney, A. R.

1982-01-01T23:59:59.000Z

192

Capture of carbon dioxide from ambient air  

Science Journals Connector (OSTI)

Carbon dioxide capture from ambient air could compensate for all carbon dioxide emissions to the atmosphere. Such capture would, for example, make it possible to use liquid, carbon-based fuels in cars or airplane...

K.S. Lackner

2009-09-01T23:59:59.000Z

193

Carbon Dioxide and Methane Emissions from Estuaries  

Science Journals Connector (OSTI)

Carbon dioxide and methane emissions from estuaries are reviewed in relation with biogeochemical processes and carbon cycling. In estuaries, carbon dioxide and methane emissions show a large spatial and temporal ...

Gwenal Abril; Alberto Vieira Borges

2005-01-01T23:59:59.000Z

194

Hydrogen Liquefaction  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Liquid Hydrogen is 0.2% Ortho, 99.8% Para 3 Liquid Supply North America 250+ TPD Capacity Diverse Feedstocks Chlor-Alkali SMR Petro-chem Market...

195

Hydrogen Storage  

Science Journals Connector (OSTI)

Hydrogen is an important energy carrier, and when used as a fuel, can be considered as an alternate to the major fossil fuels, coal, crude oil, and natural gas, and their derivatives. It has the potential to b...

Prof. Dr. Robert A. Huggins

2010-01-01T23:59:59.000Z

196

Hydrogen energy  

Science Journals Connector (OSTI)

...use of hydrogen as an energy carrier will depend significantly...its utilization and conversion to electricity/heat...becomes an alternative energy carrier. However, various...effectively with conventional energy conversion technologies. The...

2007-01-01T23:59:59.000Z

197

Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

198

Carbon dioxide storage professor Martin Blunt  

E-Print Network [OSTI]

Carbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS) referS to the Set of technologies developed to capture carbon dioxide (Co2) gas from the exhausts of technologies developed to capture carbon dioxide (Co2) gas from the exhausts of power stations and from other

199

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research  

Science Journals Connector (OSTI)

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research ...

John D. Spengler; Benjamin G. Ferris Jr.; Douglas W. Dockery; Frank E. Speizer

1979-10-01T23:59:59.000Z

200

Coregulated Genes Link Sulfide:Quinone Oxidoreductase and Arsenic Metabolism in Synechocystis sp. Strain PCC6803  

Science Journals Connector (OSTI)

...salt-tolerant chemolithoautotrophic sulfide oxidizers found in hot spring biofilms at Mono...using enrichment cultures of sulfide oxidizers closely related to some Thioalkalivibrio...Reyes (Andalusian Molecular Biology and Regenerative Medicine Centre). There is no conflict...

Csaba I. Nagy; Imre Vass; Gbor Rkhely; Istvn Zoltn Vass; Andrs Tth; gnes Duzs; Loredana Peca; Jerzy Kruk; Pter B. Ks

2014-07-14T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Hydrogen program overview  

SciTech Connect (OSTI)

This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

1997-12-31T23:59:59.000Z

202

Active Hydrogen  

Science Journals Connector (OSTI)

Dry hydrogen can be activated in an electric discharge if the pressure and voltage are carefully regulated. Active hydrogen reduces metallic sulphides whose heat of formation is 22 000 cal. or less. The active gas is decomposed by 3 cm of well packed glass wool. A quantitative method is given for the determination of active hydrogen. Less of the active gas is formed in a tube coated with stearic acid or phosphoric acid than when no coating is employed. The decay reaction was found to follow the expression for a unimolecular reaction. The rate of decay appears to be independent of the wall surface. The period of half?life at room temperature and 40 mm pressure is 0.2 sec. approximately. The energy of formation of active hydrogen is approximately 18 000 cal. The energy of activation for the decay of the active constituent is approximately 17 800 cal. The properties of active hydrogen are considered in relation to the properties predicted for H3.

A. C. Grubb; A. B. Van Cleave

1935-01-01T23:59:59.000Z

203

Radical cations of sulfides and disulfides: An ESR study  

SciTech Connect (OSTI)

Exposure of dilute solutions of dimethylsulfide, methanethiol, tetrahydrothiophene, terbutyl and diterbutyl-sulfides, dimethyl-disulfide, and diterbutyldisulfide, in freon at 77 K to /sup 60/Co ..gamma.. rays gave the corresponding cations. From the reported ESR spectra, g tensors were obtained. It was found that both sulfide and disulfide cations exhibit the same g tensor: (g/sub max/ = 2.034 +- 0.002, g/sub int/ = 2.017 +- 0.001, g/sub min/ = 2.001 +- 0.005). From this result it has been shown that the disulfide cation is planar. This finding was supported by fully optimized geometry ab initio calculations.

Bonazzola, L.; Michaut, J.P.; Roncin, J.

1985-09-15T23:59:59.000Z

204

Hydrogen Generation Via Fuel Reforming  

Science Journals Connector (OSTI)

Reforming is the conversion of a hydrocarbon based fuel to a gas mixture that contains hydrogen. The H2 that is produced by reforming can then be used to produce electricity via fuel cells. The realization of H2?based power generation via reforming is facilitated by the existence of the liquid fuel and natural gas distribution infrastructures. Coupling these same infrastructures with more portable reforming technology facilitates the realization of fuel cell powered vehicles. The reformer is the first component in a fuel processor. Contaminants in the H2?enriched product stream such as carbon monoxide (CO) and hydrogen sulfide (H2S) can significantly degrade the performance of current polymer electrolyte membrane fuel cells (PEMFCs). Removal of such contaminants requires extensive processing of the H2?rich product stream prior to utilization by the fuel cell to generate electricity. The remaining components of the fuel processor remove the contaminants in the H2 product stream. For transportation applications the entire fuel processing system must be as small and lightweight as possible to achieve desirable performance requirements. Current efforts at Argonne National Laboratory are focused on catalyst development and reactor engineering of the autothermal processing train for transportation applications.

John F. Krebs

2003-01-01T23:59:59.000Z

205

Ionically Conducting Membranes for Hydrogen Production and Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IONICALLY CONDUCTING MEMBRANES IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND SEPARATION Presented by Tony Sammells Eltron Research Inc. Boulder, Colorado www.eltronresearch.com Presented at DOE Hydrogen Separations Workshop Arlington, Virginia September 8, 2004 ELTRON RESEARCH INC. TO BE DISCUSSED * Membranes for Hydrogen Production - Compositions - Feedstocks - Performance - Key Technical Hurdles * Membranes for Hydrogen Separation - Compositions - Ex Situ vs. In Situ WGS - Performance - Key Technical Hurdles ELTRON RESEARCH INC. OVERALL SCHEME FOR CONVERTING FEEDSTOCK TO HYDROGEN WITH SIMULTANEOUS CARBON DIOXIDE SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H 2 WGS H 2 O CO 2 /H 2 1618afs.dsf H 2 CO 2 ELTRON RESEARCH INC. INCENTIVES FOR OXYGEN TRANSPORT MEMBRANES FOR

206

Hydrogen Analysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A A H2A: Hydrogen Analysis Margaret K. Mann DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. H2A Charter * H2A mission: Improve the transparency and consistency of approach to analysis, improve the understanding of the differences among analyses, and seek better validation from industry. * H2A was supported by the HFCIT Program H2A History * First H2A meeting February 2003 * Primary goal: bring consistency & transparency to hydrogen analysis * Current effort is not designed to pick winners - R&D portfolio analysis - Tool for providing R&D direction * Current stage: production & delivery analysis - consistent cost methodology & critical cost analyses * Possible subsequent stages: transition analysis, end-point

207

Hydrogen Technologies Group  

SciTech Connect (OSTI)

The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

Not Available

2008-03-01T23:59:59.000Z

208

Hydrogen | Open Energy Information  

Open Energy Info (EERE)

Sector List of Hydrogen Incentives Hydrogen Energy Data Book Retrieved from "http:en.openei.orgwindex.php?titleHydrogen&oldid271963...

209

The Hype About Hydrogen  

E-Print Network [OSTI]

economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

Mirza, Umar Karim

2006-01-01T23:59:59.000Z

210

Hydrogen and Hydrogen-Storage Materials  

Science Journals Connector (OSTI)

Currently, neutron applications in the field of hydrogen and hydrogen-storage materials represent a large and promising research ... relevant topics from this subject area, including hydrogen bulk properties (con...

Milva Celli; Daniele Colognesi; Marco Zoppi

2009-01-01T23:59:59.000Z

211

Capturing Carbon Dioxide From Air  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capturing Carbon Dioxide From Air Capturing Carbon Dioxide From Air Klaus S. Lackner (kl2010@columbia.edu; 212-854-0304) Columbia University 500 West 120th Street New York, NY 10027 Patrick Grimes (pgrimes@worldnet.att.net; 908-232-1134) Grimes Associates Scotch Plains, NJ 07076 Hans-J. Ziock (ziock@lanl.gov; 505-667-7265) Los Alamos National Laboratory P.O.Box 1663 Los Alamos, NM 87544 Abstract The goal of carbon sequestration is to take CO 2 that would otherwise accumulate in the atmosphere and put it in safe and permanent storage. Most proposed methods would capture CO 2 from concentrated sources like power plants. Indeed, on-site capture is the most sensible approach for large sources and initially offers the most cost-effective avenue to sequestration. For distributed, mobile sources like cars, on-board capture at affordable cost would not be

212

Reductive Sequestration of Carbon Dioxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reductive Sequestration of Carbon Dioxide Reductive Sequestration of Carbon Dioxide T. Mill (ted.mill@sri.com; 650-859-3605) SRI, PS273 333 Ravenswood Menlo Park, CA 94025 D. Ross (dsross3@yahoo.com; 650-327-3842) U.S. Geological Survey, Bldg 15 MS 999 345 Middlefield Rd. Menlo Park, CA 94025 Introduction The United States currently meets 80% of its energy needs by burning fossil fuels to form CO 2 . The combustion-based production of CO 2 has evolved into a major environmental challenge that extends beyond national borders and the issue has become as politically charged as it is technologically demanding. Whereas CO 2 levels in the atmosphere had remained stable over the 10,000 years preceeding the industrial revolution, that event initiated rapid growth in CO 2 levels over the past 150 years (Stevens, 2000). The resulting accelerating accumulation of

213

IEP - Carbon Dioxide: Regulatory Drivers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Carbon Dioxide (CO2) Regulatory Drivers In July 7, 2009 testimony before the U.S. Senate Committee on Environment and Public Works, Secretary of Energy Steven Chu made the following statements:1 "...Overwhelming scientific evidence shows that carbon dioxide from human activity has increased the atmospheric level of CO2 by roughly 40 percent, a level one- third higher than any time in the last 800,000 years. There is also a consensus that CO2 and other greenhouse gas emissions have caused our planet to change. Already, we have seen the loss of about half of the summer arctic polar ice cap since the 1950s, a dramatically accelerating rise in sea level, and the loss of over two thousand cubic miles of glacial ice, not on geological time scales but over a mere hundred years.

214

Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sequestering Carbon Dioxide and Sulfur Dioxide Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,922,792 entitled "Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams." Disclosed in this patent is the invention of a neutralization/sequestration method that concomitantly treats bauxite residues from aluminum production processes, as well as brine wastewater from oil and gas production processes. The method uses an integrated approach that coincidentally treats multiple industrial waste by-product streams. The end results include neutralizing caustic

215

APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS PRE-COMBUSTION SORBENTS PRE-COMBUSTION MEMBRANES POST-COMBUSTION SOLVENTS POST-COMBUSTION SORBENTS POST-COMBUSTION MEMBRANES OXY-COMBUSTION OXYGEN PRODUCTION CHEMICAL LOOPING ADVANCED COMPRESSION R&D COLLABORATIONS B-1 APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS NATIONAL ENERGY TECHNOLOGY LABORATORY PRE-COMBUSTION SOLVENTS B-6 SRI International - CO 2 Capture Using AC-ABC Processt B-7 PRE-COMBUSTION SORBENTS B-14 TDA Research - CO 2 Capture for Low-Rank Coal IGCC Systems B-15 URS Group - Sorbent Development for WGS B-18 Air Products and Chemicals - Advanced Acid Gas Separation B-24 Ohio State University-Department of Chemical Engineering - Calcium Looping for Hydrogen Production B-33

216

NETL: Pre-Combustion Carbon Dioxide Capture by a New Dual-Phase Ceramic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pre-Combustion Carbon Dioxide Capture by a New Dual-Phase Ceramic Carbonate Membrane Reactor Pre-Combustion Carbon Dioxide Capture by a New Dual-Phase Ceramic Carbonate Membrane Reactor Project No.: DE-FE0000470 Arizona State University is developing a dual-phase, membrane-based separation device which will separate carbon dioxide (CO2) from typical water gas shift (WGS) mixture feeds and produce hydrogen, which can be introduced into the combustion turbines of integrated gasification combined cycle (IGCC) plants. The objectives of the project are experimental studies of the synthesis of a high-temperature, chemically and thermally stable and CO2 perm-selective dual-phase membrane and its use as a membrane reactor for WGS reaction to produce H2 and CO2 rich streams. Concept of ceramic-carbonate dual phase membranes for CO2 separation. Concept of ceramic-carbonate dual phase membranes for CO2 separation.

217

Adsorption of carbonyl sulfide on nickel and tungsten films  

SciTech Connect (OSTI)

The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

Saleh, J.M.; Nasser, F.A.K.

1985-07-18T23:59:59.000Z

218

A supramolecular ladder-like network from trimesic acid and pyrazine N,N'-dioxide  

Science Journals Connector (OSTI)

Cocrystallized trimesic acid (TMA) and pyrazine N,N'-dioxide (PNO) molecules form strong O-HO hydrogen bonds, but also important weak C-HO and dipole-dipole intermolecular interactions, to generate a densely packed three-dimensional network.

Yadav, V.N.

2013-12-07T23:59:59.000Z

219

Dielectric constant of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) pyridine  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

220

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) ethylbenzene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Dielectric constant of the mixture (1) water; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

222

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 1,4-dimethylbenzene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

223

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) toluene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

224

Refractive index of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 1-methylnapthalene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

225

Viscosity of the mixture (1) 1,3-dioxolane; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

226

Viscosity of the mixture (1) water; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

227

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 1,3-dimethylbenzene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

228

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) benzene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

229

Viscosity of the mixture (1) tetrahydrofuran; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

230

Viscosity of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 1,2-dimethylbenzene  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2009-01-01T23:59:59.000Z

231

Hydrogen Energy System and Hydrogen Production Methods  

Science Journals Connector (OSTI)

Hydrogen is being considered as a synthetic fuel ... . This paper contains an overview of the hydrogen production methods, those being commercially available today as well...

F. Barbir; T. N. Veziro?lu

1992-01-01T23:59:59.000Z

232

Why Hydrogen? Hydrogen from Diverse Domestic Resources  

Broader source: Energy.gov [DOE]

Overview of the U.S. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program, including technical targets and research and development needs for hydrogen storage and delivery.

233

Turning carbon dioxide into fuel  

Science Journals Connector (OSTI)

...i.e. less negative) Gibbs free energy, e.g. H2 or CH4. These hydrogen-bearing energy carriers give up their intrinsic chemical energy to promote the conversion of CO2. Thus, the heats of reaction...

2010-01-01T23:59:59.000Z

234

NETL: Hydrogen Selective Exfoliated Zeolite Membranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Selective Exfoliated Zeolite Membranes Hydrogen Selective Exfoliated Zeolite Membranes Project No.: DE-FE0001322 The University of Minnesota is developing a technically and economically viable membrane for carbon dioxide (CO2) separation from typical water-gas-shift (WGS) mixture feeds. The goal of this project is to further develop recently developed membrane technology based on exfoliated zeolite coatings as components for carbon capture in integrated gasification combined cycle plants. These membranes have the potential to contribute to carbon capture by high-temperature separation of hydrogen from CO2 and other gases present in shifted synthesis gas. Molecular sieve membrane for the pre-combustion capture of CO2. Molecular sieve membrane for the pre-combustion capture of CO2. Related Papers and Publications:

235

Hydrogen Analysis Group  

SciTech Connect (OSTI)

NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

Not Available

2008-03-01T23:59:59.000Z

236

The Hype About Hydrogen  

E-Print Network [OSTI]

another promising solution for hydrogen storage. However,storage and delivery, and there are safety issues as well with hydrogen

Mirza, Umar Karim

2006-01-01T23:59:59.000Z

237

Hydrogen Technology Validation  

Fuel Cell Technologies Publication and Product Library (EERE)

This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

238

An analysis of the impact of having uranium dioxide mixed in with plutonium dioxide  

SciTech Connect (OSTI)

An assessment was performed to show the impact on airborne release fraction, respirable fraction, dose conversion factor and dose consequences of postulated accidents at the Plutonium Finishing Plant involving uranium dioxide rather than plutonium dioxide.

MARUSICH, R.M.

1998-10-21T23:59:59.000Z

239

Hydrogen Delivery Technologies and Systems - Pipeline Transmission...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen Hydrogen Delivery...

240

Putting the pressure on carbon dioxide | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Putting the pressure on carbon dioxide Improving the chances for fuel recovery and carbon sequestration Artwork from this research graces the cover of Environmental Science...

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Sandia National Laboratories: reducing carbon dioxide emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon dioxide emissions Measurements of Thermal Stratification in a Homogenous Charge Compression Ignition Engine On February 27, 2013, in CRF, Energy, Facilities, News, News &...

242

Club Convergence in Carbon Dioxide Emissions  

Science Journals Connector (OSTI)

We examine convergence in carbon dioxide emissions among 128 countries for the period 1960...2 emissions among all the countries under scrutiny in...

Ekaterini Panopoulou; Theologos Pantelidis

2009-09-01T23:59:59.000Z

243

Enzymatic conversion of carbon dioxide to methanol: Enhanced methanol production in silica sol-gel matrices  

SciTech Connect (OSTI)

Strategies for effective conversion of atmospheric CO{sub 2} to methanol offer promising new technologies not only for recycling of the greenhouse gas but also for an efficient production of fuel alternatives. Partial hydrogenation of carbon dioxide has been accomplished by means of heterogeneous catalysis, electrocatalysis, and photocatalysis. Oxide-based catalysts are predominantly used for industrial fixation of carbon dioxide. A unique approach in this direction involves the use of enzymes as catalysts for conversion of carbon dioxide to methanol. The use of enzymes is particularly appealing since it provides a facile low-temperature route for generation of methanol directly from gaseous carbon dioxide. The authors report an enzymatically coupled sequential reduction of carbon dioxide to methanol by using a series of reactions catalyzed by three different dehydrogenases. Overall, the process involves an initial reduction of CO{sub 2} to formate catalyzed by formate dehydrogenase (F{sub ate}DH), followed by reduction of formate to formaldehyde by formaldehyde dehydrogenase (F{sub ald}DH), and finally formaldehyde is reduced to methanol by alcohol dehydrogenase (ADH). In this process, reduced nicotinamide adenine dinucleotide (NADH) acts as a terminal electron donor for each dehydrogenase-catalyzed reduction.

Obert, R.; Dave, B.C.

1999-12-29T23:59:59.000Z

244

Nuclear Hydrogen Initiative  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Nuclear Research Advanced Nuclear Research Office of Nuclear Energy, Science and Technology FY 2003 Programmatic Overview Nuclear Hydrogen Initiative Nuclear Hydrogen Initiative Office of Nuclear Energy, Science and Technology Henderson/2003 Hydrogen Initiative.ppt 2 Nuclear Hydrogen Initiative Nuclear Hydrogen Initiative Program Goal * Demonstrate the economic commercial-scale production of hydrogen using nuclear energy by 2015 Need for Nuclear Hydrogen * Hydrogen offers significant promise for reduced environmental impact of energy use, specifically in the transportation sector * The use of domestic energy sources to produce hydrogen reduces U.S. dependence on foreign oil and enhances national security * Existing hydrogen production methods are either inefficient or produce

245

A Basic, and Slightly Acidic, Solution to Hydrogen Storage | Department of  

Broader source: Energy.gov (indexed) [DOE]

A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage March 23, 2012 - 2:17pm Addthis Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab. Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab.

246

Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...  

Broader source: Energy.gov (indexed) [DOE]

Pipeline Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31...

247

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

248

Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

249

The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides  

SciTech Connect (OSTI)

Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

Kelty,S.; Berhault, G.; Chianelli, R.

2007-01-01T23:59:59.000Z

250

Chapter 4 - Hydrogen and Fuel Cell Systems  

Science Journals Connector (OSTI)

Abstract In this chapter, hydrogen and fuel cell systems are introduced. Hydrogen is closely related to fuel cells because fuel cells are very efficient devices for power generation which when supplied with hydrogen generate non-polluting effluents, mainly water or steam. A hydrogen economy is necessary in the context of continuous growth of population and per-capita energy consumption. In this context, renewable energy solutionsespecially solarbecome more important and their harvesting requires hydrogen as energy carrier. Therefore the role of hydrogen and fuel cell systems in power generation becomes very important. As detailed in the chapter, these systems are useful for converting the fluctuating and intermittent energy of renewable sources and providing power on demand. Hydrogen and fuel cell systems can work either as grid-connected or as independent power generators. Connection to the grid allows for better load leveling and major savings as well as for reduction of pollution associated with power generation. Hydrogen can also be used to power residences and to cogenerate heat or other commodities. In addition, hydrogen and fuel cell technologies are much required for the transportation sector, where they can contribute to pollution and cost reduction and increased efficiency. Hydrogen production methods are reviewed in this chapter with a focus on electrolysis and thermochemical cycles. These systems appear to be leading technologies for the future. Other revised hydrogen production methods are gasification and reforming, which are very relevant for biomass conversion into hydrogen. Photochemical and photo-biochemical hydrogen production methods are also discussed. All types of fuel cells are introduced; these include alkaline, proton-exchange-membrane, phosphoric acid, molten carbonate, solid oxide, direct methanol, and direct ammonia fuel cells. Construction and specific application for power generation are presented for each type. The modeling and optimization aspects of fuel cells and their systems are explained. Several power generation systems with fuel cells are discussed, in which each type of fuel cells has specific system requirements. The overall system must include various types of separators, pumps, and compressors depending on the case. In aqueous systems water must be recycled, e.g., in the case of proton-exchange membrane fuel cells water must be actually fed in excess so that the membrane is wetted. Also for a direct methanol fuel cell water must be recovered and recycled. In molten carbonate fuel cell systems carbon dioxide must be recovered and recycled. In solid oxide fuel cell systems, the fuel must be supplied in excess and is not completely consumed; therefore it is important to couple these systems with gas turbines.

Ibrahim Dincer; Calin Zamfirescu

2014-01-01T23:59:59.000Z

251

Adsorption Kinetics of Hydrogen Sulfide and Thiols on GaAs (001) Surfaces in a Vacuum  

Science Journals Connector (OSTI)

For instance, a p(2 2) LEED structure, achieved upon repeated exposure to thiol and annealing to 750 K,9 implies that the surface concentration of chemisorbed sulfur could reach 0.25 monolayers. ... Funding for this research was provided by the Canadian Institutes for Health Research and the Canada Research Chair Program. ...

Oleksandr Voznyy; Jan J. Dubowski

2008-02-20T23:59:59.000Z

252

Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water  

E-Print Network [OSTI]

the use of strong acids and bases, thus reducing their environmental impact and increasing Generation from Water Yujie Sun,,,, Chong Liu,, David C. Grauer,, Junko Yano, Jeffrey R. Long,*,, Peidong, and long-term aqueous stability, offer promising features for potential use in solar energy applications

253

PERGAMON Carbon 38 (2000) 17571765 High temperature hydrogen sulfide adsorption on activated  

E-Print Network [OSTI]

directly, as in a traditional H , 23.1% CO, 5.8% CO , 6.6% H O, 0.5% H S, and2 2 2 2 coal-fired power plant types of activated carbon sorbents were evaluated for their ability to remove H S from a simulated coal temperature was examined as a2 function of carbon surface chemistry (oxidation, thermal desorption, and metal

Cal, Mark P.

254

Crossed beam reaction of atomic carbon C(3 Pj) with hydrogen sulfide,  

E-Print Network [OSTI]

impact-induced nonequilibrium sulfur chemistry in the Jovian atmosphere, as well as combustion of sulfur of the thioformyl radical, HCS(X2 A ) R. I. Kaiser, W. Sun, and A. G. Suits Department of Chemistry, University containing coal. © 1997 American Institute of Physics. S0021-9606 97 03412-0 I. INTRODUCTION The sulfur

Kaiser, Ralf I.

255

Sulfur incorporation into copper indium diselenide single crystals through annealing in hydrogen sulfide  

SciTech Connect (OSTI)

CuInSe{sub 2} crystals were sulfurized in a H{sub 2}S-Ar gas mixture at 575 deg. C. The focus was on the resulting mass transport, in particular, on the interdiffusion of Se and S. Experiments were done for various sulfurization times, and the resulting S distribution was measured by Auger electron spectroscopy sputter depth profiling and analyzed with the Boltzmann-Matano method. A one-dimensional diffusion process had shaped the S distribution in these crystals. The respective diffusion coefficient was on the order of 10{sup -16} cm{sup 2}/s, and it varied only slightly with the S content in CuIn(Se,S){sub 2}.

Titus, Jochen; Birkmire, Robert W.; Hack, Christina; Mueller, Georg; McKeown, Patrick [Institute of Energy Conversion, University of Delaware, Newark, Delaware 19716 (United States); Crystal Growth Laboratory, Department of Materials Science, University of Erlangen-Nuernberg (Germany); Evans East, Princeton, New Jersey 08520 (United States)

2006-02-15T23:59:59.000Z

256

Hydrogen Sulfide Exposure among Oil Refinery Workers at Marathon Petroleum Company in Canton, Ohio.  

E-Print Network [OSTI]

??Air monitoring surveys were conducted during loading operations at three locations inside of Marathon Petroleum Companys Canton, Ohio oil refinery. These three locationsthe sulfur truck (more)

Beil, Christine A

2012-01-01T23:59:59.000Z

257

Effect of Hydrogen Sulfide in Landfill Gas on Anode Poisoning of Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The world is facing an energy crisis and there is an immediate need to find a sustainable source of energy. Landfill gas has the potential (more)

Khan, Feroze

2012-01-01T23:59:59.000Z

258

The effect of hydrogen sulfide on straight-run gasoline during storage  

E-Print Network [OSTI]

AORICULTURAL AND MECHANICAL COLLEOE OF TEXAS COLLEGE STATION. TEXAS DEPARTMENT CP CHEMISTRY ANC CHEMICAL ENOINEERINO k+ fg QLU, er XSS4 l 5, . f ~ t ~ II%& '~ NF14eSC %%Sf, Oa 1S CL+koS4 . '45 gg%444440 %Et ~fv@8&l !a . s Thc~ for ". 4...~ ~y holptvL ~~hices 6mLag %ho e&eaduet of t: ha e~~g, ae6 4a &'~tet &i G~ '~ he &to 'a~lssbis ce%4teieae ts the yesyara@na of this eae~iy4~ X448741NA XOA o ~ o ~ e e o ~ ~ e ~ ~ e ~ ~ ~ o o ~ ~ ~ o ~ o X e %44Clem'4 o e ~ e e ~ e ~ ~ o e e...

Miller, Alvin Junius

2012-06-07T23:59:59.000Z

259

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network [OSTI]

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

260

Carbon Dioxide Capture from Coal-Fired  

E-Print Network [OSTI]

Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005 are valued using the "real options" valuation methodology in an uncertain carbon dioxide (CO2) price (baseline IGCC), and IGCC with pre-investments that make future retrofit for CO2 capture less expensive (pre

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Optimize carbon dioxide sequestration, enhance oil recovery  

E-Print Network [OSTI]

- 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

262

Predicting Future Atmospheric Carbon Dioxide Levels  

Science Journals Connector (OSTI)

...Predicting future atmospheric carbon dioxide levels...1978012175 air atmosphere biosphere carbon...Predicting future atmospheric carbon dioxide levels...re-quired 5-Mhz bandwidth, which...synchronization rate of 16 khz and the picture...the interstellar plasma. For UHF frequencies...

U. Siegenthaler; H. Oeschger

1978-01-27T23:59:59.000Z

263

Hydrogen from Coal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U.S. Department of Energy DOE Workshop on Hydrogen Separations and Purification Technologies September 8, 2004 Presentation Outline ƒ Hydrogen Initiatives ƒ Hydrogen from Coal Central Production Goal ƒ Why Coal ƒ Why Hydrogen Separation Membranes ƒ Coal-based Synthesis Gas Characteristics ƒ Technical Barriers ƒ Targets ƒ Future Plans 2 3 Hydrogen from Coal Program Hydrogen from Coal Program FutureGen FutureGen Hydrogen Fuel Initiative Hydrogen Fuel Initiative Gasification Fuel Cells Turbines Gasification Fuel Cells Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Supports the Hydrogen Fuel Initiative and FutureGen * The Hydrogen Fuel Initiative is a $1.2 billion RD&D program to develop hydrogen

264

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy...

265

Table 2. 2011 State energy-related carbon dioxide emisssions...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

2011 State energy-related carbon dioxide emissions by fuel million metric tons of carbon dioxide shares State Coal Petroleum Natural Gas Total Coal Petroleum Natural Gas Alabama...

266

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes &  

E-Print Network [OSTI]

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure)DescriptionMilestone #12;Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes & Standards #12;Hydrogen Codes & Standards: Goal & Objectives Goal

267

carbon dioxide emissions | OpenEI  

Open Energy Info (EERE)

dioxide emissions dioxide emissions Dataset Summary Description Total annual carbon dioxide emissions by country, 2005 to 2009 (million metric tons). Compiled by Energy Information Administration (EIA). Source EIA Date Released Unknown Date Updated Unknown Keywords carbon dioxide emissions EIA world Data text/csv icon total_carbon_dioxide_emissions_from_the_consumption_of_energy_2005_2009million_metric_tons.csv (csv, 12.3 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Time Period 2005 - 2009 License License Other or unspecified, see optional comment below Comment Rate this dataset Usefulness of the metadata Average vote Your vote Usefulness of the dataset Average vote Your vote Ease of access Average vote Your vote Overall rating

268

EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

2. Carbon Dioxide Emissions 2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors contributing to the decrease in carbon dioxide emissions in 2009 included an economy in recession with a decrease in gross domestic product of 2.6 percent, a decrease in the energy intensity of the economy of 2.2 percent, and a decrease in the carbon intensity of energy supply of

269

HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM  

E-Print Network [OSTI]

to serve as "go-to" organization to catalyze PA Hydrogen and Fuel Cell Economy development #12;FundingHYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA Melissa Klingenberg, PhDMelissa Klingenberg, PhD #12;Hydrogen ProgramHydrogen Program Air Products

270

Ring size and strain as a control of reaction selectivity: ethylene sulfide on Mo(110)  

SciTech Connect (OSTI)

The adsorption and reaction of sulfur-containing organic on single-crystal transition-metal surfaces form a subject of current to the authors and others. The primary focus of their work is an investigation of how thermodynamic properties of adsorbate molecules affect the mechanism(s) by which they react. To this end, they have studied the reactions of two saturated cyclic sulfides-trimethylene sulfide (c-C/sub 3/H/sub 6/S) and tetrahydrothiophene (c-C/sub 4/H/sub 8/S)--on Mo(110). On the basis of these studies they proposed that ring strain in the cyclic sulfide controls reaction selectivity on Mo(110). This work concerns the reactions of a third cyclic sulfide, ethylene sulfide (c-C/sub 2/H/sub 4/S), on Mo(110). The results presented here demonstrate that ring size as well as ring strain determines the reaction selectivity of cyclic sulfides on Mo(110).

Roberts, J.T.; Friend, C.M.

1987-12-09T23:59:59.000Z

271

Combined Heat and Power (CHP): Is It Right For Your Facility...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

per kW 0.010 to 0.015 per kWh In Partnership with the US DOE Landfill Gas andor Biogas Cleanup - Consider Moisture, Siloxanes, Hydrogen Sulfide, Carbon Dioxide - Can add up...

272

Prediction of gas-hydrate formation conditions in production and surface facilities  

E-Print Network [OSTI]

such as methane, ethane, propane, carbon dioxide and hydrogen sulfide to binary, ternary, and natural gas mixtures. I used the Statistical Analysis Software (SAS) to find the best correlations among variables such as specific gravity and pseudoreduced pressure...

Ameripour, Sharareh

2006-10-30T23:59:59.000Z

273

Solar-Powered Electrochemical Oxidation of Organic Compounds Coupled with the Cathodic Production of Molecular Hydrogen  

Science Journals Connector (OSTI)

Solar-Powered Electrochemical Oxidation of Organic Compounds Coupled with the Cathodic Production of Molecular Hydrogen ... The volume percent of the headspace was calculated assuming that it was directly proportional to the ion current measured by the mass spectrometer and that the transfer of all gases through the membrane and their 70 eV electron ionization cross-sections were approximately equivalent. ... In addition, even if hydrogen is mixed with carbon dioxide, CO2 can be readily removed just by chemical absorption process (e.g., flowing carbon dioxide gas through amine solution), which is a typical CO2 separation process in gas turbine power plants. ...

Hyunwoong Park; Chad D. Vecitis; Michael R. Hoffmann

2008-07-26T23:59:59.000Z

274

Chapter 6 - The fusion - hydrogen energy system  

Science Journals Connector (OSTI)

Publisher Summary This chapter shows that the combination of fusion generation combined with hydrogen distribution will provide a system capable of virtually eliminating the negative impact on the environment from the use of energy by humanity. It addition, implementation of the energy system will provide techniques and tools that can ameliorate environmental problems unrelated to energy use. The nations that implement the FusionHydrogen energy system will experience a powerful surge of growth as companies, new and old, compete to product the supporting equipment. The Fusionhydrogen energy system will provide the means for dramatically reducing all forms of soil, water, and air pollution resulting from the extraction and use of fossil fuels. Hydrogen fuel use will stop the addition of carbon dioxide to the atmosphere and the attendant warming of the earth. It will stop atmospheric pollution by materials responsible for acid rain. It will also provide a reliable energy source with an inconsequential potential for generation of new types of pollution. The hydrogen energy carrier can be easily transported throughout the world without damage to the environment. It provides a safe and highly reliable energy distribution system for use by all the sectors of the economy.

Laurence O. Williams

2002-01-01T23:59:59.000Z

275

E-Print Network 3.0 - antimony sulfide thin Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The strata-bound, sulfide- and ... Source: USGS Western Region Coastal and Marine Geology Collection: Geosciences 77 Experimental partitioning of uranium between liquid...

276

Hydrogen Dissociation on Pd4S Surfaces  

SciTech Connect (OSTI)

Exposure of Pd-based hydrogen purification membranes to H,S. a common contaminant in coal gasification streams, can cause membrane performance to deteriorate, either by deactivating surface sites required for dissociative H, adsorption or by forming a low-permeability sulfide scale. In this work. the composition, structure, and catalytic activity of Pd4S, a surface scale commonly observed in Pd-membrane separation of hydrogen from sulfur-containing gas streams, were examined using a combination of experimental characterization and density functional theory (DFT) calculations. A Pd,S sample was prepared by exposing a 100 f1m Pd foil to H2S at 908 K. Both X-ray photoemission depth profiling and low energy ion scattering spectroscopic (LEISS) analysis reveal slight sulfur-enrichment of the top surface of the sample. This view is consistent with the predictions of DFT atomistic thermodynamic calculations. which identified S-terminated Pd,S surfaces as energetically favored over corresponding Pd-terminated surfaces. Activation barriers for H2 dissociation on the Pd,S surfaces were calculated. Although barriers are higher than on Pd(lll). transition state theory analysis identified reaction pathways on the S-terminated surfaces for which hydrogen dissociation rates are high enough to sustain the separation process at conditions relevant to gasification applications.

Miller, J.B.; Alfonso, D.R.; Howard, B.H.; O'Brien, C.P.; Morreale, B.D.

2009-01-01T23:59:59.000Z

277

Adsorption and methanation of carbon dioxide on a nickel/silica catalyst  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a nickel/silica catalyst were studied using temperature-programmed desorption and temperature-programmed reaction. Carbon dioxide adsorption on nickel was found to be activated; almost no adsorption occurred at room temperature, but large coverages were obtained between 383 and 473 K. The data indicate CO/sub 2/ dissociates upon adsorption at elevated temperatures to yield carbon monoxide and oxygen atoms. These oxygen atoms react with hydrogen at room temperature, so the methane and water observed during programmed heating in flowing hydrogen are identical for adsorbed CO and adsorbed CO/sub 2/. Single CH/sub 4/ and H/sub 2/O peaks, each with a peak temperature at 473 K, were observed. This peak temperature did not change with initial coverage, indicating methanation is first order in CO surface coverage. The activated adsorption of CO/sub 2/ allowed these coverage variation experiments to be carried out. Thus, following adsorption, CO and CO/sub 2/ methanation proceed by the same mechanism. However, the activated adsorption of CO/sub 2/ may create a higher H/sub 2/:CO surface ratio during steady-state hydrogenation, causing CO/sub 2/ hydrogenation to favor methane over higher hydrocarbons. 5 figures.

Falconer, J.L.; Zagli, A.E.

1980-04-01T23:59:59.000Z

278

FCT Hydrogen Production: Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Hydrogen Production: Basics on Facebook Tweet about FCT Hydrogen Production: Basics on Twitter Bookmark FCT Hydrogen Production: Basics on Google Bookmark FCT Hydrogen Production: Basics on Delicious Rank FCT Hydrogen Production: Basics on Digg Find More places to share FCT Hydrogen Production: Basics on AddThis.com... Home Basics Central Versus Distributed Production Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of hydrogen production in photobioreactor Hydrogen, chemical symbol "H", is the simplest element on earth. An atom of hydrogen has only one proton and one electron. Hydrogen gas is a diatomic

279

The Transition to Hydrogen  

E-Print Network [OSTI]

above, not all hydrogen production methods are equal inrealize hydrogens bene- ?ts fully, production methods thathydrogen vary depending on which primary source produces it and which production method

Ogden, Joan M

2005-01-01T23:59:59.000Z

280

The Hydrogen Economy  

Science Journals Connector (OSTI)

The hydrogen economy is a vision for a future in which hydrogen replaces fossil fuels. There are a variety ... of methods for generating, storing and delivering hydrogen since no single method has yet proven supe...

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Hydrogen storage methods  

Science Journals Connector (OSTI)

Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of todays ...

Andreas Zttel

2004-04-01T23:59:59.000Z

282

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September byet al. , 1988,1989 HYDROGEN FUEL-CELL VEHICLES: TECHNICALIn the FCEV, the hydrogen fuel cell could supply the "net"

Delucchi, Mark

1992-01-01T23:59:59.000Z

283

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

for the hydrogen refueling station. Compressor cost: inputcost) Compressor power requirement: input data 288.80 Initial temperature of hydrogen (Compressor cost per unit of output ($/hp/million standard ft [SCF] of hydrogen/

Delucchi, Mark

1992-01-01T23:59:59.000Z

284

NETL: Carbon Dioxide 101 FAQs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is the greenhouse effect? is the greenhouse effect? Greenhouse Effect Greenhouse Effect The greenhouse effect is used to describe the phenomenon whereby the Earth's atmosphere traps solar radiation, caused by the presence of gases, such as carbon dioxide (CO2), methane (CH4), and water vapor (H2O), in the atmosphere that allow incoming sunlight to pass through but absorb heat radiated back from the Earth's surface, resulting in higher temperatures. The greenhouse effect gets its name from what actually happens in a greenhouse. In a greenhouse, short wavelength visible sunlight shines through the glass panes and warms the air and the plants inside. The radiation emitted from the heated objects is of longer wavelength and is unable to pass through the glass barrier, maintaining a warm temperature

285

An investigation of convergence pressure methods  

E-Print Network [OSTI]

of carbon dioxide, hydrogen sulfide, nitrogen, hydrocarbons having molecular weights from methane through hexane, and the remainder of the hydrocarbons are lumped into a single pseudocomponent G7+. Butane and pentane are further split into iso and normal... of Mixtures Versus Saturation Pressure Number of Mixtures Versus Temperature 55 56 10 Number of Mixtures Versus Mole Fraction of Carbon Dioxide 57 Number of Mixtures Versus Mole Fraction of Hydrogen Sulfide 12 Number of Mixtures Versus Mole Fraction...

Wattenbarger, Robert Chick

1986-01-01T23:59:59.000Z

286

Hydrogen Permeation Barrier Coatings  

SciTech Connect (OSTI)

Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

Henager, Charles H.

2008-01-01T23:59:59.000Z

287

Technology: Hydrogen and hydrates  

Science Journals Connector (OSTI)

... . 22492258 (2004). US Department of Energy Hydrogen Posture Plan http://www.eere.energy.gov/hydrogenandfuelcells/pdfs/hydrogen_posture_plan.pdf Kuhs, W. F. , Genov, ...

Ferdi Schth

2005-04-06T23:59:59.000Z

288

Hydrogen Pipeline Working Group  

Broader source: Energy.gov [DOE]

The Hydrogen Pipeline Working Group of research and industry experts focuses on issues related to the cost, safety, and reliability of hydrogen pipelines. Participants represent organizations...

289

Hydrogen and fuel taxation.  

E-Print Network [OSTI]

??The competitiveness of hydrogen depends on how it is integrated in the energy tax system in Europe. This paper addresses the competitiveness of hydrogen and (more)

Hansen, Anders Chr.

2007-01-01T23:59:59.000Z

290

CAN HYDROGEN WIN?: EXPLORING SCENARIOS FOR HYDROGEN  

E-Print Network [OSTI]

such as biofuel plug-in hybrids, but did well when biofuels were removed or priced excessively. Hydrogen fuel cells failed unless costs were assumed to descend independent of demand. However, hydrogen vehicles were; Hydrogen as fuel -- Economic aspects; Technological innovations -- Environmental aspects; Climatic changes

291

Summary of research on hydrogen production from fossil fuels conducted at NETL  

SciTech Connect (OSTI)

In this presentation we will summarize the work performed at NETL on the production of hydrogen via partial oxidation/dry reforming of methane and catalytic decomposition of hydrogen sulfide. We have determined that high pressure resulted in greater carbon formation on the reforming catalysts, lower methane and CO2 conversions, as well as a H2/CO ratio. The results also showed that Rh/alumina catalyst is the most resistant toward carbon deposition both at lower and at higher pressures. We studied the catalytic partial oxidation of methane over Ni-MgO solid solutions supported on metal foams and the results showed that the foam-supported catalysts reach near-equilibrium conversions of methane and H2/CO selectivities. The rates of carbon deposition differ greatly among the catalysts, varying from 0.24 mg C/g cat h for the dipped foams to 7.0 mg C/g cat h for the powder-coated foams, suggesting that the exposed Cr on all of the foam samples may interact with the Ni-MgO catalyst to kinetically limit carbon formation. Effects of sulfur poisoning on reforming catalysts were studies and pulse sulfidation of catalyst appeared to be reversible for some of the catalysts but not for all. Under pulse sulfidation conditions, the 0.5%Rh/alumina and NiMg2Ox-1100C (solid solution) catalysts were fully regenerated after reduction with hydrogen. Rh catalyst showed the best overall activity, less carbon deposition, both fresh and when it was exposed to pulses of H2S. Sulfidation under steady state conditions significantly reduced catalyst activity. Decomposition of hydrogen sulfide into hydrogen and sulfur was studied over several supported metal oxides and metal oxide catalysts at a temperature range of 650-850C. H2S conversions and effective activation energies were estimated using Arrhenius plots. The results of these studies will further our understanding of catalytic reactions and may help in developing better and robust catalysts for the production of hydrogen from fossil fuels

Shamsi, Abolghasem

2008-03-30T23:59:59.000Z

292

Hydrogen Pipeline Discussion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

praxair.com praxair.com Copyright © 2003, Praxair Technology, Inc. All rights reserved. Hydrogen Pipeline Discussion BY Robert Zawierucha, Kang Xu and Gary Koeppel PRAXAIR TECHNOLOGY CENTER TONAWANDA, NEW YORK DOE Hydrogen Pipeline Workshop Augusta, GA August 2005 2 Introduction Regulatory and technical groups that impact hydrogen and hydrogen systems ASME, DOE, DOT etc, Compressed Gas Association activities ASTM TG G1.06.08 Hydrogen pipelines and CGA-5.6 Selected experience and guidance Summary and recommendations 3 CGA Publications Pertinent to Hydrogen G-5: Hydrogen G-5.3: Commodity Specification for Hydrogen G-5.4: Standard for Hydrogen Piping at Consumer Locations G-5.5: Hydrogen Vent Systems G-5.6: Hydrogen Pipeline Systems (IGC Doc 121/04/E) G-5.7: Carbon Monoxide and Syngas

293

Hydrogen | Open Energy Information  

Open Energy Info (EERE)

<-- Back to Hydrogen Gateway <-- Back to Hydrogen Gateway Technical Reference for Hydrogen Compatibility of Materials KIA FCEV SUNRISE MG 7955 6 7.jpg Guidance on materials selection for hydrogen service is needed to support the deployment of hydrogen as a fuel as well as the development of codes and standards for stationary hydrogen use, hydrogen vehicles, refueling stations, and hydrogen transportation. Materials property measurement is needed on deformation, fracture and fatigue of metals in environments relevant to this hydrogen economy infrastructure. The identification of hydrogen-affected material properties such as strength, fracture resistance and fatigue resistance are high priorities to ensure the safe design of load-bearing structures. To support the needs of the hydrogen community, Sandia National

294

Solar-Powered Production of Molecular Hydrogen from Water  

Science Journals Connector (OSTI)

At the present time, the majority of industrial-scale hydrogen is produced by steam?methane reformation (SMR), even though the high-temperature conversion of methane to hydrogen results in the concomitant production of carbon monoxide and carbon dioxide. ... 7-9 The PV arrays are used to convert solar light to electricity in order to power alkaline (e.g., 27% KOH at pH 14.7) electrolyzers for producing hydrogen gas. ... Narayanan et al. describe a DC-powered hybrid system that drives a methanol fuel cell in reverse,10 while Soler et al. report on a solar-powered photo-Fenton process that produces hydrogen noncatalytically under severe conditions with a limited number of organic substrates. ...

Hyunwoong Park; Chad D. Vecitis; Wonyong Choi; Oleh Weres; Michael R. Hoffmann

2008-01-04T23:59:59.000Z

295

Hydrogen Energy Technology Geoff Dutton  

E-Print Network [OSTI]

Integrated gasification combined cycle (IGCC) Pyrolysis Water electrolysis Reversible fuel cell Hydrogen Hydrogen-fuelled internal combustion engines Hydrogen-fuelled turbines Fuel cells Hydrogen systems Overall expensive. Intermediate paths, employing hydrogen derived from fossil fuel sources, are already used

Watson, Andrew

296

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

297

Hydrogen production during processing of radioactive sludge containing noble metals  

SciTech Connect (OSTI)

Hydrogen was produced when radioactive sludge from Savannah River Site radioactive waste containing noble metals was reacted with formic acid. This will occur in a process tank in the Defense Waste Facility at SRS when waste is vitrified. Radioactive sludges from four tanks were tested in a lab-scale apparatus. Maximum hydrogen generation rates varied from 5 {times}10{sup {minus}7} g H{sub 2}/hr/g of sludge from the least reactive sludge (from Waste Tank 51) to 2 {times}10{sup {minus}4} g H{sub 2}/hr/g of sludge from the most reactive sludge (from Waste Tank 11). The time required for the hydrogen generation to reach a maximum varied from 4.1 to 25 hours. In addition to hydrogen, carbon dioxide and nitrous oxide were produced and the pH of the reaction slurry increased. In all cases, the carbon dioxide and nitrous oxide were generated before the hydrogen. The results are in agreement with large-scale studies using simulated sludges.

Ha, B.C.; Ferrara, D.M.; Bibler, N.E.

1992-09-01T23:59:59.000Z

298

Hydrogen production during processing of radioactive sludge containing noble metals  

SciTech Connect (OSTI)

Hydrogen was produced when radioactive sludge from Savannah River Site radioactive waste containing noble metals was reacted with formic acid. This will occur in a process tank in the Defense Waste Facility at SRS when waste is vitrified. Radioactive sludges from four tanks were tested in a lab-scale apparatus. Maximum hydrogen generation rates varied from 5 {times}10{sup {minus}7} g H{sub 2}/hr/g of sludge from the least reactive sludge (from Waste Tank 51) to 2 {times}10{sup {minus}4} g H{sub 2}/hr/g of sludge from the most reactive sludge (from Waste Tank 11). The time required for the hydrogen generation to reach a maximum varied from 4.1 to 25 hours. In addition to hydrogen, carbon dioxide and nitrous oxide were produced and the pH of the reaction slurry increased. In all cases, the carbon dioxide and nitrous oxide were generated before the hydrogen. The results are in agreement with large-scale studies using simulated sludges.

Ha, B.C.; Ferrara, D.M.; Bibler, N.E.

1992-01-01T23:59:59.000Z

299

DOE Permitting Hydrogen Facilities: Hydrogen Fueling Stations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stations Stations Public-use hydrogen fueling stations are very much like gasoline ones. In fact, sometimes, hydrogen and gasoline cars can be fueled at the same station. These stations offer self-service pumps, convenience stores, and other services in high-traffic locations. Photo of a Shell fueling station showing the site convenience store and hydrogen and gasoline fuel pumps. This fueling station in Washington, D.C., provides drivers with both hydrogen and gasoline fuels Many future hydrogen fueling stations will be expansions of existing fueling stations. These facilities will offer hydrogen pumps in addition to gasoline or natural gas pumps. Other hydrogen fueling stations will be "standalone" operations. These stations will be designed and constructed to

300

Carbon Dioxide Information Analysis Center (CDIAC)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Latest Estimates Latest Estimates Atmos CO2 Level 397.31 ppm Fossil CO2 Emissions 9,167 MMT Carbon Global Temp Anomaly +0.56°C / +1.01°F Global Sea Level Rise +2.9 ± 0.4 mm/y Carbon Dioxide Information Analysis Center The Carbon Dioxide Information Analysis Center (CDIAC) is the primary climate-change data and information analysis center of the U.S. Department of Energy (DOE). CDIAC is located at DOE's Oak Ridge National Laboratory (ORNL) and includes the World Data Center for Atmospheric Trace Gases. CDIAC's data holdings include estimates of carbon dioxide emissions from fossil-fuel consumption and land-use changes; records of atmospheric concentrations of carbon dioxide and other radiatively active trace gases; carbon cycle and terrestrial carbon management datasets and analyses; and

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Carbon Dioxide Emission Factors for Coal  

Reports and Publications (EIA)

The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

1994-01-01T23:59:59.000Z

302

Storage of Carbon Dioxide in Offshore Sediments  

Science Journals Connector (OSTI)

...Carbon Dioxide in Offshore Sediments 10...efforts to increase energy efficiency; efforts...sources, including renewable and nuclear energy; and investment...repositories. Offshore geological repositories...between Scotland and Norway and far out of...

Daniel P. Schrag

2009-09-25T23:59:59.000Z

303

Hydrogen & Our Energy Future  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Program Hydrogen Program www.hydrogen.energy.gov Hydrogen & Our Energy Future  | HydrOgEn & Our EnErgy FuturE U.S. Department of Energy Hydrogen Program www.hydrogen.energy.gov u.S. department of Energy |  www.hydrogen.energy.gov Hydrogen & Our Energy Future Contents Introduction ................................................... p.1 Hydrogen - An Overview ................................... p.3 Production ..................................................... p.5 Delivery ....................................................... p.15 Storage ........................................................ p.19 Application and Use ........................................ p.25 Safety, Codes and Standards ............................... p.33

304

Sulfur isotope and trace element data from ore sulfides in the Noranda district (Abitibi, Canada): implications for volcanogenic massive sulfide deposit genesis  

Science Journals Connector (OSTI)

We examine models for volcanogenic massive sulfide (VMS) mineralization in the ~2.7-Ga Noranda camp, Abitibi subprovince, Superior Province, Canada, using a combination of multiple sulfur isotope and trace ele...

Elizabeth R. Sharman; Bruce E. Taylor; William G. Minarik

2014-10-01T23:59:59.000Z

305

Displacement of crude oil by carbon dioxide  

E-Print Network [OSTI]

DISPLACEMENT OF CRUDE OIL BY CARBON DIOXIDE A Thesis by OLUSEGUN OMOLE Submitted to the Graduate College of Texas ASM University in part';al fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1980 Major Subject...: Petroleum Engineering DISPLACEMENT OF CRUDE OIL BY CARBON DIOXIDE A Thesis by OLUSEGUN OMOLE Approved as to style and content by: hairman of Committee / (Member (Member (Member (Hea o Depart ent December 1980 ABSTRACT Displacement of Crude Oil...

Omole, Olusegun

1980-01-01T23:59:59.000Z

306

Hydrogen Compatibility of Materials  

Broader source: Energy.gov [DOE]

Presentation slides from the Energy Department webinar, Hydrogen Compatibility of Materials, held August 13, 2013.

307

Hydrogen Delivery Liquefaction & Compression  

E-Print Network [OSTI]

Hydrogen Delivery Liquefaction & Compression Raymond Drnevich Praxair - Tonawanda, NY Strategic Initiatives for Hydrogen Delivery Workshop - May 7, 2003 #12;2 Agenda Introduction to Praxair Hydrogen Liquefaction Hydrogen Compression #12;3 Praxair at a Glance The largest industrial gas company in North

308

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

309

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

310

Process Balances of Vegetable Oil Hydrogenation and Coprocessing Investigations with Middle-Distillates  

Science Journals Connector (OSTI)

The hydrogenation of vegetable oil is a promising technology for the production of highly valuable diesel components. ... Finding a sustainable energy supplement as well as the need for carbon dioxide reduction leads to the necessity to integrate more and more renewable energy sources into the transportation fuel markets. ... A possibility for introduction of hydrogenated vegetable oils on the market is the coprocessing in conventional hydrotreater and hydrocracker units in a refinery. ...

Matthias Endisch; Thomas Kuchling; Jan Roscher

2013-03-19T23:59:59.000Z

311

Composition for absorbing hydrogen  

DOE Patents [OSTI]

A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

Heung, L.K.; Wicks, G.G.; Enz, G.L.

1995-05-02T23:59:59.000Z

312

Hydrogen Storage - Current Technology | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Current on-board hydrogen storage approaches involve compressed hydrogen gas tanks, liquid hydrogen tanks, cryogenic compressed hydrogen, metal hydrides,...

313

Gaseous Hydrogen Delivery Breakout - Strategic Directions for...  

Broader source: Energy.gov (indexed) [DOE]

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

314

Dielectric constant of the mixture (1) ethane-1,2-diol; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

315

Refractive index of the mixture (1) ethane-1,2-diol; (2) tetrahydrothiophene-1,1-dioxide  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

316

Dielectric constant of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 2-(2-hydroxyethoxy)-ethanol  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

317

Refractive index of the mixture (1) tetrahydrothiophene-1,1-dioxide; (2) 2-(2-hydroxyethoxy)-ethanol  

Science Journals Connector (OSTI)

Substance name(s): tetrahydrothiophene-1,1-dioxide; tetrahydrothiophene-S,S-dioxide; tetrahydro-thiophene-1,1 ... ,1-dioxide; thiacyclopentane dioxide; tetramethylene sulfone; tetrahydrothiophene 1...

Ch. Wohlfarth

2008-01-01T23:59:59.000Z

318

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

319

Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents  

E-Print Network [OSTI]

Articles Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic for finding carbon-free synthesis methods for metal sulfides. The decomposition of organosulfur, such as manganese sulfide (MnS). Here we report a hydrothermal synthesis method for the formation of MnS in which

320

FCT Hydrogen Storage: Hydrogen Storage R&D Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage R&D Activities Hydrogen Storage R&D Activities to someone by E-mail Share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Facebook Tweet about FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Twitter Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Google Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Delicious Rank FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Digg Find More places to share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on AddThis.com... Home Basics Current Technology DOE R&D Activities National Hydrogen Storage Compressed/Liquid Hydrogen Tanks Testing and Analysis Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions  

DOE Patents [OSTI]

A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

Huffman, Gerald P

2012-09-18T23:59:59.000Z

322

DOE Hydrogen Analysis Repository: Hydrogen Modeling Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Modeling Projects Modeling Projects Below are models grouped by topic. These models are used to analyze hydrogen technology, infrastructure, and other areas related to the development and use of hydrogen. Cross-Cutting Distributed Energy Resources Customer Adoption Model (DER_CAM) Hydrogen Deployment System (HyDS) Model and Analysis Hydrogen Technology Assessment and Selection Model (HyTASM) Renewable Energy Power System Modular Simulator (RPM-Sim) Stranded Biogas Decision Tool for Fuel Cell Co-Production Energy Infrastructure All Modular Industry Growth Assessment (AMIGA) Model Building Energy Optimization (BEopt) Distributed Energy Resources Customer Adoption Model (DER_CAM) Hydrogen Deployment System (HyDS) Model and Analysis Hydrogen Technology Assessment and Selection Model (HyTASM)

323

Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4: April 9, 2007 4: April 9, 2007 Carbon Dioxide Emissions to someone by E-mail Share Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on Facebook Tweet about Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on Twitter Bookmark Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on Google Bookmark Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on Delicious Rank Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on Digg Find More places to share Vehicle Technologies Office: Fact #464: April 9, 2007 Carbon Dioxide Emissions on AddThis.com... Fact #464: April 9, 2007 Carbon Dioxide Emissions Carbon dioxide (CO2) emissions from the transportation sector began to

324

DOE Hydrogen and Fuel Cells Program: Hydrogen Analysis Resource Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Analysis Repository H2A Analysis Hydrogen Analysis Resource Center Scenario Analysis Well-to-Wheels Analysis Systems Integration U.S. Department of Energy Search help Home > Systems Analysis > Hydrogen Analysis Resource Center Printable Version Hydrogen Analysis Resource Center The Hydrogen Analysis Resource Center provides consistent and transparent data that can serve as the basis for hydrogen-related calculations, modeling, and other analytical activities. This new site features the Hydrogen Data Book with data pertinent to hydrogen infrastructure analysis; links to external databases related to

325

Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...  

Broader source: Energy.gov (indexed) [DOE]

of hydrogen permeation behavior and its impact on hydrogen embrittlement of pipeline steels under high gaseous pressures relevant to hydrogen gas transmission pipeline...

326

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...  

Broader source: Energy.gov (indexed) [DOE]

Bulk Hydrogen Storage Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session - Bulk Hydrogen Storage Main ThemesCaveats Bulk...

327

Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...  

Broader source: Energy.gov (indexed) [DOE]

Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22,...

328

NREL: Hydrogen and Fuel Cells Research - Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

L. Simpson. (2010) Contact: Thomas Gennett 303-384-6628 Printable Version Hydrogen & Fuel Cells Research Home Projects Fuel Cells Hydrogen Production & Delivery Hydrogen Storage...

329

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

330

Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

331

EIS-0431: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California  

Broader source: Energy.gov [DOE]

This EIS evaluates the potential environmental impacts of a proposal to provide financial assistance for the construction and operation of Hydrogen Energy California's LLC project, which would produce and sell electricity, carbon dioxide and fertilizer. DOE selected this project for an award of financial assistance through a competitive process under the Clean Coal Power Initiative program.

332

International Journal of Hydrogen Energy 31 (2006) 7792 www.elsevier.com/locate/ijhydene  

E-Print Network [OSTI]

for fueling automotives to reduce car- bon dioxide emissions, limit dependence on imported petroleum-grade crude oils into transport fuels. World oil refineries and chemical plants' demand for hydrogen-free tech- nologies, including either battery- or fuel-cell--operated vehicles. However, the H2 fuel

Yildiz, Bilge

333

Storage and Proper Segregation of Chemical Classes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Proper Segregation of Chemical Classes Proper Segregation of Chemical Classes Partial List of Incompatible chemicals (Toxic Hazards) Substances in the left hand column should be stored and handled so that they cannot possibly accidentally contact corresponding substances in the center column, because toxic materials (right hand column) would be produced. Arsenical Materials Any Reducing Agent Arsine Azides Acids Hydrogen Azide Cyanides Acids Hydrogen Cyanide Hypochlorites Acids Chlorine or Hypochlorous Acid Nitrates Sulfuric Acid Nitrogen Dioxide Nitric acid Copper, Brass, Heavy Metals Nitrogen Dioxide Nitrites Acids Nitrous Fumes Phosphorus Caustic Alkalies/ Reducers Phosphine Selenides Reducers Hydrogen Selenide Sulfides Acids Hydrogen Sulfide Tellurides Reducers Hydrogen Telluride

334

Why Hydrogen? Hydrogen from Diverse Domestic Resources  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

produce hydrogen in a centralized coal based operation for .79kg at the plant gate with carbon sequestration. Develop advanced OTM, HTM, technology, advanced reforming and shift...

335

Resource Assessment for Hydrogen Production: Hydrogen Production...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Administration ERR Estimated Recoverable Reserves FCEV fuel cell electric vehicle GHG greenhouse gas GW gigawatt GWh gigawatt-hour GWdt gigawatt-days thermal H2A Hydrogen...

336

The Copper Sulfide Coating on Polyacrylonitrile with Chelating Agents by an Electroless Deposition Method and its EMI Shielding Effectiveness  

SciTech Connect (OSTI)

In this study, a variety of concentrations of chelating agents were added to obtain the anchoring effect and chelating effect in the electroless plating bath. The mechanism of the Cu{sub x(x=1,2)}S growth and the electromagnetic interference shielding effectiveness (EMI SE) of the composite were studied. It was found that the vinyl acetate residued in PAN substrate would be purged due to the swelling effect by chelating agents solution. And then, the anchoring effect occurred due to the hydrogen bonding between the pits of PAN substrate and the chelating agent. Consequently, the copper sulfide layer deposited by the electroless plating reaction with EDTA and TEA. The swelling degree (S{sub d}) was proposed and evaluated from the FT-IR spectra. The relationship between swelling degree of the PAN films and EDTA (C) is expressed as: S{sub d} = 0.13+0.90xe and (-15.15C). And TEA series is expressed as: S{sub d} = 0.07+1.00xe and (-15.15C). On the other hand, the FESEM micrograph showed that the average thickness of copper sulfide increased from 76 nm to 383 nm when the concentration of EDTA increased from 0.00M to 0.20M. Consequently, the EMI SE of the composites increased from 10{approx}12 dB to 25{approx}27 dB. The GIA-XRD analyze indicated that the deposited layer consisted of CuS and Cu{sub 2}S.

Roan, M.-L. [Department of Electro-optical Engineering, Lan-Yan Institute of Technology, Taiwan (China); Chen, Y.-H.; Huang, C.-Y. [Department of Materials Engineering, Tatung University, Taiwan (China)

2008-08-28T23:59:59.000Z

337

Photoelectrochemical Hydrogen Production  

SciTech Connect (OSTI)

The objectives of this project, covering two phases and an additional extension phase, were the development of thin film-based hybrid photovoltaic (PV)/photoelectrochemical (PEC) devices for solar-powered water splitting. The hybrid device, comprising a low-cost photoactive material integrated with amorphous silicon (a-Si:H or a-Si in short)-based solar cells as a driver, should be able to produce hydrogen with a 5% solar-to-hydrogen conversion efficiency (STH) and be durable for at least 500 hours. Three thin film material classes were studied and developed under this program: silicon-based compounds, copper chalcopyrite-based compounds, and metal oxides. With the silicon-based compounds, more specifically the amorphous silicon carbide (a-SiC), we achieved a STH efficiency of 3.7% when the photoelectrode was coupled to an a-Si tandem solar cell, and a STH efficiency of 6.1% when using a crystalline Si PV driver. The hybrid PV/a-SiC device tested under a current bias of -3~4 mA/cm{sup 2}, exhibited a durability of up to ~800 hours in 0.25 M H{sub 2}SO{sub 4} electrolyte. Other than the PV driver, the most critical element affecting the photocurrent (and hence the STH efficiency) of the hybrid PV/a-SiC device was the surface energetics at the a-SiC/electrolyte interface. Without surface modification, the photocurrent of the hybrid PEC device was ~1 mA/cm{sup 2} or lower due to a surface barrier that limits the extraction of photogenerated carriers. We conducted an extensive search for suitable surface modification techniques/materials, of which the deposition of low work function metal nanoparticles was the most successful. Metal nanoparticles of ruthenium (Ru), tungsten (W) or titanium (Ti) led to an anodic shift in the onset potential. We have also been able to develop hybrid devices of various configurations in a monolithic fashion and optimized the current matching via altering the energy bandgap and thickness of each constituent cell. As a result, the short-circuit photocurrent density of the hybrid device (measured in a 2-electrode configuration) increased significantly without assistance of any external bias, i.e. from ?1 mA/cm{sup 2} to ~5 mA/cm{sup 2}. With the copper chalcopyrite compounds, we have achieved a STH efficiency of 3.7% in a coplanar configuration with 3 a-Si solar cells and one CuGaSe{sub 2} photocathode. This material class exhibited good durability at a photocurrent density level of -4 mA/cm{sup 2} (5% STH equivalent) at a fixed potential (-0.45 VRHE). A poor band-edge alignment with the hydrogen evolution reaction (HER) potential was identified as the main limitation for high STH efficiency. Three new pathways have been identified to solve this issue. First, PV driver with bandgap lower than that of amorphous silicon were investigated. Crystalline silicon was identified as possible bottom cell. Mechanical stacks made with one Si solar cell and one CuGaSe{sub 2} photocathode were built. A 400 mV anodic shift was observed with the Si cell, leading to photocurrent density of -5 mA/cm{sup 2} at 0VRHE (compared to 0 mA/cm{sup 2} at the same potential without PV driver). We also investigated the use of p-n junctions to shift CuGaSe{sub 2} flatband potential anodically. Reactively sputtered zinc oxy-sulfide thin films was evaluated as n-type buffer and deposited on CuGaSe{sub 2}. Ruthenium nanoparticles were then added as HER catalyst. A 250 mV anodic shift was observed with the p-n junction, leading to photocurrent density at 0VRHE of -1.5 mA/cm{sup 2}. Combining this device with a Si solar cell in a mechanical stack configuration shifted the onset potential further (+400 mV anodically), leading to photocurrent density of -7 mA/cm{sup 2} at 0VRHE. Finally, we developed wide bandgap copper chalcopyrite thin film materials. We demonstrated that Se can be substituted with S using a simple annealing step. Photocurrent densities in the 5-6 mA/cm{sub 2} range were obtained with red 2.0eV CuInGaS{sub 2} photocathodes. With the metal oxide compounds, we have demonstrated that a WO{sub 3}-based hybrid p

Hu, Jian

2013-12-23T23:59:59.000Z

338

Carbon dioxide removal and capture for landfill gas up-grading  

Science Journals Connector (OSTI)

Within the frame of an EC financially supported project - LIFE05 ENV/IT/000874 GHERL (Greenhouse Effect Reduction from Landfill)a pilot plant was set up in order to demonstrate the feasibility of applying chemical absorption to remove carbon dioxide from landfill gas. After proper upgrading - basically removal of carbon dioxide, hydrogen sulphide, ammonia and other trace gas compoundthe gas might be fed into the distribution grid for natural gas or used as vehicle fuel, replacing a fossil fuel thus saving natural resources and carbon dioxide emissions. Several experiences in Europe have been carried out concerning the landfill gas - and biogas from anaerobic digestion - quality up-grading through CO2 removal, but in all of them carbon dioxide was vented to the atmosphere after separation, without any direct benefit in terms of greenhouse gases reduction. With respect to those previous experiences, in this work the attention was focused on CO2 removal from landfill gas with an effective capture process, capable of removing carbon dioxide from atmosphere, through a globally carbon negative process. In particular, processes capable of producing final solid products were investigated, with the aim of obtaining as output solid compounds which can be either used in the chemical industry or disposed off. The adopted absorption process is based on using aqueous solutions of potassium hydroxide, with the final aim of producing potassium carbonate. Potassium carbonate is a product which has several applications in the chemical industry if obtained with adequate quality. It can be sold as a pulverised solid, or in aqueous solution. Several tests were carried out at the pilot plant, which was located at a landfill site, in order to feed it with a fraction of the on-site collected landfill gas. The results of the experimental campaign are reported, explained and commented in the paper. Also a discussion on economic issues is presented.

Lidia Lombardia; Andrea Corti; Ennio Carnevale; Renato Baciocchi; Daniela Zingaretti

2011-01-01T23:59:59.000Z

339

Hydrogen storage gets new hope  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen storage gets new hope Hydrogen storage gets new hope A new method for "recycling" hydrogen-containing fuel materials could open the door to economically viable...

340

The Bumpy Road to Hydrogen  

E-Print Network [OSTI]

will trump hydrogen and fuel cell vehicles. Advocates ofbenefits sooner than hydrogen and fuel cells ever could.emissions from a hydrogen fuel cell vehicle will be about

Sperling, Dan; Ogden, Joan M

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Theoretical Studies on Heavy Metal Sulfides in Solution  

SciTech Connect (OSTI)

'Calculating the stabilities, Raman and UV spectra and acidities of As sulfides in aqueous solution', J. A. Tossell, M. D. Zimmermann and G. R. Helz. Some of the Raman spectra obtained by reacting aqueous As(OH)3 with aqueous bisulfide are shown, taken from Wood, et al. (2002). To interpret these spectra we have carried out an extensive series of calculations, detailed for the case of AsS(SH){sub 2}{sup -} in Table 1 below. By employing state of the art quantum chemical techniques to determine gas-phase harmonic and anharmonic frequencies and solution phase corrections we can accurately match features in the experimental spectrum shown in the top figure. The AsS(SH){sub 2}{sup -}...22 H{sub 2}O nanocluster employed is shown in the lower figure. For this species we have calculated the equilibrium structure and the harmonic vibrational spectrum at the CBSB7 B3LYP level. For the free solute species AsS(SH){sub 2}{sup -} we have carried out a whole series of calculations, evaluating harmonic and anharmonic vibrational frequencies at a number of different quantum mechanical levels. In the spectra below, Fig. 3 and Fig. 5 from Wood, et al. (2002), the features around 700-800 cm{sup -1} are attributed to As-O stretches and those around 350-450 cm{sup -1} to As-S stretches. In the nanocluster an isolated vibrational feature is observed at 425 cm{sup -1}, an As=S stretch, close to the value (415 cm{sup -1}) determined by Wood, et al. (2002). Analysis of the calculated frequencies for AsS(SH){sub 2}{sup -} within a polarizable continuum model yields a similar result. Taking the highest level harmonic results, obtained from a CCSD calculation, and adding anharmonic and PCM corrections at the B3LYP level (designated (3) + (5) - (1) in Table 1) gives a frequency for the intense high frequency As=S stretch within 15 cm{sup -1} of experiment. Although there is still interesting work to be done on the stabilities and the Raman and UV spectra of As sulfides, most of the basic concepts have been worked out and we are therefore proposing to move to a new area, that of humic acids (while continuing our studies complexes formed by As oxides and sulfides, now applied to functional groups present in humic acids).

Tossell, John A.

2007-10-31T23:59:59.000Z

342

Support and crystallite effects in CO hydrogenation on nickel  

SciTech Connect (OSTI)

The adsorption and reaction of carbon monoxide and hydrogen were studied on seven alumina-supported catalysts containing 0.5-23% nickel, four silica-supported catalysts containing 2.7-15% nickel, and 2.8 and 15% nickel on titanium oxide. On the silica and alumina-supported catalysts, hydrogen adsorption, per cent reduction of metal, carbon monoxide/hydrogen adsorption ratio, and methane yield increased with increasing metal dispersion, the methane turnover number decreased with increasing metal dispersion, and the carbon monoxide turnover number was not affected by dispersion. Hydrogen adsorption was suppressed by the titanium dioxide support. The suppression of hydrogen adsorption and the activity for carbon monoxide hydrogenation decreased as a function of support in the order TiO/sub 2/ > Al/sub 2/O/sub 3/ > SiO/sub 2/ and apparently depended on the strength of the electronic interaction of support and metal. The selectivity shifted to higher hydrocarbons as the metal dispersion increased and as the carbon monoxide/hydrogen adsorption ratio increased. Effects of preparation method are also reported.

Bartholomew, C.H.; Pannell, R.B.; Butler, J.L.

1980-10-01T23:59:59.000Z

343

Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

344

FCT Hydrogen Production: Hydrogen Production R&D Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production R&D Hydrogen Production R&D Activities to someone by E-mail Share FCT Hydrogen Production: Hydrogen Production R&D Activities on Facebook Tweet about FCT Hydrogen Production: Hydrogen Production R&D Activities on Twitter Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Google Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Delicious Rank FCT Hydrogen Production: Hydrogen Production R&D Activities on Digg Find More places to share FCT Hydrogen Production: Hydrogen Production R&D Activities on AddThis.com... Home Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts

345

Lithium sulfide compositions for battery electrolyte and battery electrode coatings  

SciTech Connect (OSTI)

Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2014-10-28T23:59:59.000Z

346

Changes in Dimethyl Sulfide Oceanic Distribution due to Climate Change  

SciTech Connect (OSTI)

Dimethyl sulfide (DMS) is one of the major precursors for aerosols and cloud condensation nuclei in the marine boundary layer over much of the remote ocean. Here they report on coupled climate simulations with a state-of-the-art global ocean biogeochemical model for DMS distribution and fluxes using present-day and future atmospheric CO{sub 2} concentrations. They find changes in zonal averaged DMS flux to the atmosphere of over 150% in the Southern Ocean. This is due to concurrent sea ice changes and ocean ecosystem composition shifts caused by changes in temperature, mixing, nutrient, and light regimes. The largest changes occur in a region already sensitive to climate change, so any resultant local CLAW/Gaia feedback of DMS on clouds, and thus radiative forcing, will be particularly important. A comparison of these results to prior studies shows that increasing model complexity is associted with reduced DMS emissions at the equator and increased emissions at high latitudes.

Cameron-Smith, P; Elliott, S; Maltrud, M; Erickson, D; Wingenter, O

2011-02-16T23:59:59.000Z

347

Catalyzed Hydrogen Spillover for Hydrogen Storage  

Science Journals Connector (OSTI)

Catalyzed Hydrogen Spillover for Hydrogen Storage ... Storing sufficient H on-board a wide range of vehicle platforms, while meeting all consumer requirements (driving range, cost, safety, performance, etc.), without compromising passenger or cargo space, is a tremendous tech. ... The authors show that for the 1st time significant amts. of H can be stored in MOF-5 and IRMOF-8 at ambient temp. ...

Ralph T. Yang; Yuhe Wang

2009-02-27T23:59:59.000Z

348

Hydrogen Permeability and Integrity of Hydrogen  

E-Print Network [OSTI]

· To develop suitable welding technology for H2 pipeline construction and repair · To develop technical basisHydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Z. Feng*, L.M. Anovitz*, J pressure permeation test · Edison Welding Institute - Pipeline materials · Lincoln Electric Company

349

SEQUESTERING CARBON DIOXIDE IN COALBEDS  

SciTech Connect (OSTI)

The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also provided direct synergism with the original goals of our work. Specific accomplishments of this project are summarized below in three broad categories: experimentation, model development, and coal characterization.

K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

2003-04-30T23:59:59.000Z

350

The hydrogen economy: Its history  

Science Journals Connector (OSTI)

The concept leading to a hydrogen economy lay in the work of a Nazi engineer, Lawaceck, 1968. I heard his suggestion of cheaper transfer of energy in hydrogen through pipes at a dinner in that year. A paper was published with Appleby in 1972 which was the first published document concerning that title and involving the title of A Hydrogen Economy. The first meeting was in Cornell University in 1973. In 1974 T. Nejat Veziroglu organized the first big meeting on hydrogen (900 attendees). At this meeting I presented privately to Veziroglu the possibilities of a world development and he told me that he was ready to put his organizing ability to use in spreading the ideas worldwide. However, he not only proceeded to do this but he, also a professor at the University of Miami, contributed several papers of notes, particularly the one with Awad of 1974 about the cost of pollution. Gregory worked at the Gas Research Institute from 1971 and confirmed the expectations put down by Lawaceck. Veziroglu founded the International Journal of Hydrogen Energy in 1974. Research in hydrogen was relatively low cost and therefore was taken up most eagerly by those from the newer countries. The National Science Foundation awarded Texas A&M University in 1982 a five year support for hydrogen as a fuel with the condition that half the costs be borne by at least five industrial companies. I was appointed director of the research under the grant and chose to concentrate upon the decomposition of water by solar light via an electrochemical photo fuel cell. We were able to obtain considerable increases in efficiency of decomposition of water by solar light, and at the time the work was interrupted we had 9.6 percent efficiency for decomposition. S.U.M. Khan and R. Kainthla were the principal contributors to the theory of using light via electrochemical cells for this purpose. The Texas A&M University work on hydrogen was interrupted in 1989 by the arrival of claims that one of my former students had carried out electrolysis of deuterium oxide saying that an extra unexplained heat had been observed and he suggested this heat was nuclear in origin. Later, seeking to reduce the cost of hydrogen as a fuel I involved Sol Zaromb in discussions and we came across the idea that if one included a carbon dioxide molecule obtained by removing it from the atmosphere in the structure of methanolAT, no increase in global warming would occur from the use of methanol with that condition, (published in 2008). By this condition methanol took on the largest advantage of gaseous hydrogen: That it did not cause global warming. The estimated cost of the new (anti-global warming) fuel, methanolAT was less than $30/GJ. This estimated cost could be compared with the $48/GJ which is now being supported by a French Canadian group who published an attractive book with six pages of calculations of costs. The difference between the cost estimated by this group and the costs which have been assumed by hydrogen enthusiasts in earlier times was that they took into account the auxiliary expenses which would come with the use of hydrogen, in particular the storage at high pressure. The characteristics of the new methanol to cause no global warming put that aspect of it on an equal footing to the gaseous hydrogen. The CO2 which was an essential part of the structure of methanolAT was necessary to be created in a stream, rather than directly from the atmosphere, but it was easily shown that this could be done by the use of biomass and by carbonaceous wastes. A German team under Weiderman and Grob appeared in 2008 and proceeded to suggest some extensions of the ideas which had been undergoing publication for some time. The aim of the German work was to reduce costs of a compound which they called Methasyn. The present situation is that the claim of methanolAT as a world fuel to be used without any concerns of exhaustion or pollution depends on the commercial point of view of the costs being less than that of obtaining oil from the tar sands.

John O'.M. Bockris

2013-01-01T23:59:59.000Z

351

sulfur dioxide emissions | OpenEI  

Open Energy Info (EERE)

sulfur dioxide emissions sulfur dioxide emissions Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides

352

A Vortex Contactor for Carbon Dioxide Separations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vortex Contactor for Carbon Dioxide Separations Vortex Contactor for Carbon Dioxide Separations Kevin T. Raterman (ratekt@inel.gov; 208-526-5444) Michael McKellar (mgq@inel.gov; 208-526-1346) Anna Podgorney (poloak@inel.gov; 208-526-0064) Douglas Stacey (stacde@inel.gov; 208-526-3938) Terry Turner (tdt@inel.gov; 208-526-8623) Idaho National Engineering and Environmental Laboratory P.O. Box 1625 Idaho Falls, Idaho 83415-2110 Brian Stokes (bxs9@pge.com; 415-972-5591) John Vranicar (jjv2@pge.com; 415-972-5591) Pacific Gas & Electric Company 123 Mission Street San Francisco, CA 94105 Introduction Many analysts 1,2,3 identify carbon dioxide (CO 2 ) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA)

353

Reaction of titanium polonides with carbon dioxide  

SciTech Connect (OSTI)

It has been ascertained that heating titanium and tantalum in carbon dioxide to temperatures of 500 or 800/sup 0/C alters the composition of the gas phase, causing the advent of carbon monoxide and lowering the oxygen content. Investigation of the thermal stability of titanium polonides in a carbon dioxide medium has shown that titanium mono- and hemipolonides are decomposed at temperatures below 350/sup 0/C. The temperature dependence of the vapor pressure of polonium produced in the decomposition of these polonides in a carbon dioxide medium have been determined by a radiotensimetric method. The enthalpy of the process, calculated from this relationship, is close to the enthalpy of vaporization of elementary polonium in vacuo.

Abakumov, A.S.; Malyshev, M.L.; Reznikova, N.F.

1987-05-01T23:59:59.000Z

354

Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop  

Broader source: Energy.gov [DOE]

Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

355

BP and Hydrogen Pipelines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BP and Hydrogen Pipelines BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Gary P. Yoho, P.E. i l i * Green corporate philosophy and senior management commitment * Reduced greenhouse gas emissions nine years ahead of target * Alternatives to oil are a big part of BP' including natural gas, LNG, solar and hydrogen * Hydrogen Bus Project won Australia' prestigious environmental award * UK partnership opened the first hydrogen demonstration refueling station * Two hydrogen pipelines in Houston area BP Env ronmenta Comm tment s portfolio, s most BP' * li l " li i i * i l pl i i * Li l li l * " i i l i 2 i i ll i i l pl ifi i * 8" ly idl i i l s Hydrogen Pipelines Two nes, on y a brand new 12 ne s act ve Connect Houston area chem ca ant w th a ref nery nes come off a p

356

Hydrogen Production- Current Technology  

Broader source: Energy.gov [DOE]

The development of clean, sustainable, and cost-competitive hydrogen production processesis key to a viable future clean energy economy. Hydrogen production technologies fall into three general...

357

A Hydrogen Economy  

Science Journals Connector (OSTI)

The history of the hydrogen economy may be broken down into three parts ... is the history of the founding of the Hydrogen Energy Society which took place in Miami,...

J. OM. Bockris

1981-01-01T23:59:59.000Z

358

Solar Hydrogen Production  

Science Journals Connector (OSTI)

The common methods of hydrogen production impose many concerns regarding the decline in...2...emission, and ecological impacts. Subsequently, all the downstream industries that consume hydrogen involve the aforem...

Ibrahim Dincer; Anand S. Joshi

2013-01-01T23:59:59.000Z

359

Hydrogen Fuel Quality (Presentation)  

SciTech Connect (OSTI)

Jim Ohi of NREL's presentation on Hydrogen Fuel Quality at the 2007 DOE Hydrogen Program Annual Merit Review and Peer Evaluation on May 15-18, 2007 in Arlington, Virginia.

Ohi, J.

2007-05-17T23:59:59.000Z

360

Webinar: Hydrogen Refueling Protocols  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled, Hydrogen Refueling Protocols, originally presented on February 22, 2013.

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The Hydrogen Economy  

Science Journals Connector (OSTI)

Before describing the characteristics of an economy in which hydrogen is the medium of energy, let us...

J. OM. Bockris; Z. Nagy

1974-01-01T23:59:59.000Z

362

Hydrogen Technologies Safety Guide  

SciTech Connect (OSTI)

The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

Rivkin, C.; Burgess, R.; Buttner, W.

2015-01-01T23:59:59.000Z

363

National Hydrogen Energy Roadmap  

Broader source: Energy.gov [DOE]

This roadmap provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development.

364

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage  

Science Journals Connector (OSTI)

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage ... Use of hydrogen for transportation applications requires materials that not only store hydrogen at high density but that can operate reversibly at temperatures and pressures below approximately 100 C and 10 bar, respectively. ... This composition is based on assuming the following complete hydrogenation reaction:which stores 2.6 wt % hydrogen. ...

Wen Li; John J. Vajo; Robert W. Cumberland; Ping Liu; Son-Jong Hwang; Chul Kim; Robert C. Bowman, Jr.

2009-11-06T23:59:59.000Z

365

EIA - International Energy Outlook 2007 - Energy-Related Carbon Dioxide  

Gasoline and Diesel Fuel Update (EIA)

Energy-Relaated Carbon Dioxide Emissions Energy-Relaated Carbon Dioxide Emissions International Energy Outlook 2007 Chapter 7 - Energy-Related Carbon Dioxide Emissions In 2004, non-OECD emissions of carbon dioxide were greater than OECD emissions for the first time. In 2030, carbon dioxide emissions from the non-OECD countries are projected to exceed those from the OECD countries by 57 percent. Figure 77. World Energy-Related Carbon Dioxide Emissions by Region, 2003-2030 (Billion Metric Tons). Need help, contact the National Energy Information Center on 202-585-8800. Figure Data Figure 78. World energy-Related Carbon Dioxide Emissions by Fuel Type, 1990-2030 (Billion Metric Tons). Need help, contact the National Energy at 202-586-8800. Figure Data Carbon dioxide is the most abundant anthropogenic (human-caused) greenhouse

366

EIA - International Energy Outlook 2008-Energy-Related Carbon Dioxide  

Gasoline and Diesel Fuel Update (EIA)

Energy-Related Carbon Dioxide Emissions Energy-Related Carbon Dioxide Emissions International Energy Outlook 2008 Chapter 7 - Energy-Related Carbon Dioxide Emissions In 2005, non-OECD emissions of carbon dioxide exceeded OECD emissions by 7 percent. In 2030, carbon dioxide emissions from the non-OECD countries are projected to exceed those from the OECD countries by 72 percent. Figure 75. World Energy-Related Carbon Dioxide Emissions, 2005-2030 (Billion Metric Tons). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 76. World Energy-Related Carbon Dioxide Emissions by Fuel Type, 1990-2030 (Billion Metric Tons). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 77. Average Annual Growth in Energy-Related Carbon Dioxide Emissions in the OECD Economies, 2005-2030 (Percent per Year). Need help, contact the National Energy Information Center at 202-586-8800.

367

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

368

A methodology for forecasting carbon dioxide flooding performance  

E-Print Network [OSTI]

A methodology was developed for forecasting carbon dioxide (CO2) flooding performance quickly and reliably. The feasibility of carbon dioxide flooding in the Dollarhide Clearfork "AB" Unit was evaluated using the methodology. This technique is very...

Marroquin Cabrera, Juan Carlos

2012-06-07T23:59:59.000Z

369

Graph Model for Carbon Dioxide Emissions from Metallurgical Plants  

Science Journals Connector (OSTI)

Mathematical models are presented for estimating carbon dioxide emissions from metallurgical processes. The article also presents ... in graph form to calculate transit and net emissions of carbon dioxide based o...

Yu. N. Chesnokov; V. G. Lisienko; A. V. Lapteva

2013-03-01T23:59:59.000Z

370

Gaseous Hydrogen Delivery Breakout  

E-Print Network [OSTI]

or reduce the likelihood of hydrogen embrittlement Test existing high strength steel alloys for use in largeGaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 compression. Safety, integrity, reliability: Metal embrittlement, no H2 odorant, low ignition energy

371

E-Print Network 3.0 - arterial carbon dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactivity. inserm-00495071... , manufactured nanoparticles, especially carbon or titanium dioxide nanoparticles, could be relevant surrogate... of carbon or titanium dioxide...

372

DOE Hydrogen Analysis Repository: Life Cycle Analysis of Vehicles for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Life Cycle Analysis of Vehicles for Canada Life Cycle Analysis of Vehicles for Canada Project Summary Full Title: Life Cycle Analysis of Vehicles Powered by a Fuel Cell and by Internal Combustion Engine for Canada Project ID: 117 Principal Investigator: Xianguo Li Purpose In this study, a full life cycle analysis of an internal combustion engine vehicle (ICEV) and a fuel cell vehicle (FCV) has been carried out. The impact of the material and fuel used in the vehicle on energy consumption and carbon dioxide emissions is analyzed for Canada. Four different methods of obtaining hydrogen were analyzed; using coal and nuclear power to produce electricity and extraction of hydrogen through electrolysis and via steam reforming of natural gas in a natural gas plant and in a hydrogen refueling station.

373

Hydrogen Delivery Liquefaction and Compression  

Broader source: Energy.gov [DOE]

Hydrogen Delivery Liquefaction and Compression - Overview of commercial hydrogen liquefaction and compression and opportunities to improve efficiencies and reduce cost.

374

New Materials for Hydrogen Pipelines  

Broader source: Energy.gov [DOE]

Barriers to Hydrogen Delivery: Existing steel pipelines are subject to hydrogen embrittlement and are inadequate for widespread H2 distribution.

375

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

carbon dioxide emissions per 1,000 cubic feet of natural gas. In this case, there is much less energy

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

376

Anti-Hydrogen Jonny Martinez  

E-Print Network [OSTI]

Anti-Hydrogen Jonny Martinez University of California, Berkeley #12;OUTLINE WHAT IS ANTI-HYDROGEN? HISTORY IMPORTANCE THEORY HOW TO MAKE ANTI-HYDROGEN OTHER ANTI-MATTER EXPERIMENTS CONCLUSION #12;WHAT IS ANTI-HYDROGEN? Anti-hydrogen is composed of a Positron(anti-electron) and anti-Proton. Anti-Hydrogen

Budker, Dmitry

377

Designed amyloid fibers as materials for selective carbon dioxide capture  

E-Print Network [OSTI]

Designed amyloid fibers as materials for selective carbon dioxide capture Dan Lia,b,c,1 , Hiroyasu demonstrate that amyloids, self-assembling protein fibers, are effective for selective carbon dioxide capture formation rate is fast enough to capture carbon dioxide by dynamic separation, undiminished by the presence

378

Array of titanium dioxide nanostructures for solar energy utilization  

DOE Patents [OSTI]

An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

2014-12-30T23:59:59.000Z

379

Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere  

E-Print Network [OSTI]

dioxide Water vapor #12;Atmospheric composition (parts per million by volume) · Nitrogen (N2) 780Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere Bill Satzer 3M Company #12;Outline,840 · Oxygen (O2) 209,460 · Argon (Ar) 9340 · Carbon dioxide (CO2) 394 · Methane (CH4) 1.79 · Ozone (O3) 0

Olver, Peter

380

World Energy Consumption and Carbon Dioxide Emissions: 1950 2050  

E-Print Network [OSTI]

-U" relation with a within- sample peak between carbon dioxide emissions (and energy use) per capita and perWorld Energy Consumption and Carbon Dioxide Emissions: 1950 ? 2050 Richard Schmalensee, Thomas M. Stoker, andRuth A. Judson* Emissions of carbon dioxide from combustion of fossil fuels, which may

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Glutamate Surface Speciation on Amorphous Titanium Dioxide and  

E-Print Network [OSTI]

Glutamate Surface Speciation on Amorphous Titanium Dioxide and Hydrous Ferric Oxide D I M I T R I (HFO) and titanium dioxide exhibit similar strong attachment of many adsorbates including biomolecules on amorphous titanium dioxide. The results indicate that glutamate adsorbs on HFO as a deprotonated divalent

Sverjensky, Dimitri A.

382

E-Print Network 3.0 - anaerobic sulfide oxidation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

marsh microbial mat geochemistry Summary: 1, p. 114-160. KAMP A., STIEF P. & SCHULZ-VOGT H.N. (2006).- Anaerobic sulfide oxidation... to facultative anaerobic spirochetes may...

383

Three-dimensional defect characterization : focused ion beam tomography applied to tin sulfide thin films  

E-Print Network [OSTI]

Porosity is postulated to be one of the reasons for the low efficiency of tin sulfide-based devices. This work is a preliminary investigation of the effects of two film growth parameters deposition rate and substrate ...

Youssef, Amanda

2014-01-01T23:59:59.000Z

384

Elemental and isotopic compositions of the hydrothermal sulfide on the East Pacific Rise near 13N  

Science Journals Connector (OSTI)

The mineralogical, elemental, and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (1242.30?N, 10354.48?W, water depth 2655 m) on the East Pacific Rise near 13N were analyze...

ZhiGang Zeng; DaiGeng Chen; XueBo Yin; XiaoYuan Wang

2010-02-01T23:59:59.000Z

385

Sodium sulfide leaching of low-grade jamesonite concentrate in production of sodium pyroantimoniate  

Science Journals Connector (OSTI)

Sodium sulfide leaching of a low-grade jamesonite concentrate in the production of sodium pyroantimoniate through the air oxidation process and the influencing factors on the leaching rate of antimony were...

Tian-zu Yang PhD; Ming-xi Jiang

2005-06-01T23:59:59.000Z

386

E-Print Network 3.0 - arsenic sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

387

E-Print Network 3.0 - americium sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

388

E-Print Network 3.0 - activated zinc sulfide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

389

Biosynthesis and urinary excretion of methyl sulfonium derivatives of the sulfur mustard analog, 2-chloroethyl ethyl sulfide, and other thioethers  

SciTech Connect (OSTI)

Thioether methyltransferase was previously shown to catalyze the S-adenosylmethionine-dependent methylation of diemthyl selenide, dimethyl telluride, and various thioethers to produce the corresponding methyl onium ions. In this paper we show that the following thioethers are also substrates for this enzyme in vitro: 2-hydroxyethyl ethyl sulfide, 2-chloroethyl ethyl sulfide, thiodiglycol, t-butyl sulfide, and isopropyl sulfide. To demonstrate thioether methylation in vivo, mice were injected with (methyl-{sup 3}H)methionine plus different thioethers, and extracts of lungs, livers, kidneys, and urine were analyzed by high-performance liquid chromatography for the presence of ({sup 3}H)methyl sulfonium ions. The following thioethers were tested, and all were found to be methylated in vivo: dimethyl sulfide, diethyl sulfide, methyl n-propyl sulfide, tetrahydrothiophene, 2-(methylthio)ethylamine, 2-hydroxyethyl ethyl sulfide, and 2-chloroethyl ethyl sulfide. This supports our hypothesis that the physiological role of thioether methyltransferase is to methylate seleno-, telluro-, and thioethers to more water-soluble onium ions suitable for urinary excretion. Conversion of the mustard gas analog, 2-chloroethyl ethyl sulfide, to the methyl sulfonium derivative represents a newly discovered mechanism for biochemical detoxification of sulfur mustards, as this conversion blocks formation of the reactive episulfonium ion that is the ultimate alkylating agent for this class of compounds.

Mozier, N.M.; Hoffman, J.L. (Univ. of Louisville, KY (USA))

1990-12-01T23:59:59.000Z

390

Metal sulfide and rare-earth phosphate nanostructures and methods of making same  

DOE Patents [OSTI]

The present invention provides a method of producing a crystalline metal sulfide nanostructure. The metal is a transitional metal or a Group IV metal. In the method, a porous membrane is placed between a metal precursor solution and a sulfur precursor solution. The metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure.

Wong, Stanislaus; Zhang, Fen

2014-05-13T23:59:59.000Z

391

Recovery Act: Carbon Dioxide-Water Emulsion for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Dioxide-Water Carbon Dioxide-Water Emulsion for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide Background The U.S. Department of Energy (DOE) distributed a portion of American Recovery and Reinvestment Act (ARRA) funds to advance technologies for chemical conversion of carbon dioxide (CO 2 ) captured from industrial sources. The focus of the research projects is permanent sequestration of CO 2 through mineralization or development

392

Hydrogen peroxide safety issues  

SciTech Connect (OSTI)

A literature survey was conducted to review the safety issues involved in handling hydrogen peroxide solutions. Most of the information found in the literature is not directly applicable to conditions at the Rocky Flats Plant, but one report describes experimental work conducted previously at Rocky Flats to determine decomposition reaction-rate constants for hydrogen peroxide solutions. Data from this report were used to calculate decomposition half-life times for hydrogen peroxide in solutions containing several decomposition catalysts. The information developed from this survey indicates that hydrogen peroxide will undergo both homogeneous and heterogeneous decomposition. The rate of decomposition is affected by temperature and the presence of catalytic agents. Decomposition of hydrogen peroxide is catalyzed by alkalies, strong acids, platinum group and transition metals, and dissolved salts of transition metals. Depending upon conditions, the consequence of a hydrogen peroxide decomposition can range from slow evolution of oxygen gas to a vapor, phase detonation of hydrogen peroxide vapors.

Conner, W.V.

1993-04-14T23:59:59.000Z

393

Hydrogen Use and Safety  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

USE AND SAFETY USE AND SAFETY The lightest and most common element in the universe, hydrogen has been safely used for decades in industrial applications. Currently, over 9 million tons of hydrogen are produced in the U.S. each year and 3.2 trillion cubic feet are used to make many common products. They include glass, margarine, soap, vitamins, peanut butter, toothpaste and almost all metal products. Hydrogen has been used as a fuel since the 1950s by the National Aeronautics & Space Administration (NASA) in the U.S. space program. Hydrogen - A Safe, Clean Fuel for Vehicles Hydrogen has another use - one that can help our nation reduce its consumption of fossil fuels. Hydrogen can be used to power fuel cell vehicles. When combined with oxygen in a fuel cell, hydrogen generates electricity used

394

CARBON DIOXIDE AND OUR OCEAN LEGACY  

E-Print Network [OSTI]

to energy-consuming activities that burn fossil fuels. On a yearly basis, the average Ameri- can produces 22 of carbon dioxide from the atmosphere, or nearly half of the fossil fuel carbon emissions over this period sea life that depend on the health and avail- ability of these shelled organisms. At present, ocean

395

Predicting Future Atmospheric Carbon Dioxide Levels  

Science Journals Connector (OSTI)

...re-quired 5-Mhz bandwidth...interstellar plasma. For UHF frequencies of 500 Mhz, this amounts...chang-ing the atmospheric carbon dioxide...in the polar areas. Although...The shaded area indicates the...per-missible atmospheric CO2 level might...emission rates are largest between 2000...

U. Siegenthaler; H. Oeschger

1978-01-27T23:59:59.000Z

396

Synthetic fuels, carbon dioxide and climate  

Science Journals Connector (OSTI)

The observed increase in atmospheric carbon dioxide (CO2) has been attributed to the use of fossil fuels. There is concern that the generation and use of synthetic fuels derived from oil shale and coal will accelerate the increase of CO2.

Alex R. Sapre; John R. Hummel; Ruth A. Reck

1982-01-01T23:59:59.000Z

397

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network [OSTI]

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

398

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network [OSTI]

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

399

DOE Hydrogen Analysis Repository: Hydrogen Production by  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production by Photovoltaic-powered Electrolysis Production by Photovoltaic-powered Electrolysis Project Summary Full Title: Production of Hydrogen by Photovoltaic-powered Electrolysis Project ID: 91 Principal Investigator: D.L. Block Keywords: Hydrogen production; electrolysis; photovoltaic (PV) Purpose To evaluate hydrogen production from photovoltaic (PV)-powered electrolysis. Performer Principal Investigator: D.L. Block Organization: Florida Solar Energy Center Address: 1679 Clearlake Road Cocoa, FL 32922 Telephone: 321-638-1001 Email: block@fsec.ucf.edu Sponsor(s) Name: Michael Ashworth Organization: Florida Energy Office Name: Neil Rossmeissl Organization: DOE/Advanced Utilities Concepts Division Name: H.T. Everett Organization: NASA/Kennedy Space Center Project Description Type of Project: Analysis Category: Hydrogen Fuel Pathways

400

Hydrogen Material Compatibility for Hydrogen ICE | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. pm04smith.pdf More Documents & Publications Hydrogen Materials Compatibility for the H-ICE...

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

INDUSTRIAL EFFLUENT TREATMENT USING IONIZING RADIATION COMBINED TO TITANIUM DIOXIDE  

SciTech Connect (OSTI)

The Advanced Oxidation Process (AOP) with OH radicals are the most efficient to mineralize organic compounds, and there are various methods to generate OH radicals as the use of ozone, hydrogen peroxide and ultra-violet radiation and ionizing radiation. The irradiation of aqueous solutions with high-energy electrons results in the excitation and ionizing of the molecules and rapid (10{sup -14} - 10{sup -9} s) formation of reactive intermediates. These reactive species will react with organic compounds present in industrial effluent inducing their decomposition. Titanium dioxide (TiO{sub 2}) catalyzed photoreaction is used to remove a wide range of pollutants in air and water media, combined to UV/VIS light, FeO{sub 2}, and H{sub 2}O{sub 2}, but as far as known there is no report on the combination with ionizing radiation. In some recent studies, the removal of organic pollutants in industrial effluent, such as Benzene, Toluene, and Xylene from petroleum production using ionizing radiation was investigated. It has been ob served that none of the methods can be used individually in wastewater treatment applications with good economics and high degree of energy efficiency. In the present work, the efficiency of ionizing radiation in presence of TiO{sub 2} to treat industrial effluent was evaluated. The main aim to combine these technologies is to improve the efficiency for very hard effluents and to reduce the processing cost for future implementation to large-scale design.

Duarte, C.L.; Oikawa, H.; Mori, M.N.; Sampa, M.H.O.

2004-10-04T23:59:59.000Z

402

Study of hydrogen production system by using PV solar energy and PEM electrolyser in Algeria  

Science Journals Connector (OSTI)

Hydrogen fuel can be produced by using solar electric energy from photovoltaic (PV) modules for the electrolysis of water without emitting carbon dioxide or requiring fossil fuels. In this paper, an assessment of the technical potential for producing hydrogen from the PV/proton exchange membrane (PEM) electrolyser system is investigated. The present study estimates the amount of hydrogen produced by this system in six locations using hourly global solar irradiations on horizontal plane and ambient temperature. The system studied in this work is composed of 60W PV module connected with a commercial 50W PEM electrolyser via DC/DC converter equipped with a maximum power point tracking. The primary objective is to develop a mathematical model of hydrogen production system, including PV module and PEM electrolyser to analyze the system performance. The secondary aim is to compare the system performance in terms of hydrogen production at seven locations situated in different regions of Algeria. The amount of hydrogen produced is estimated at seven locations situated in different regions. In terms of hydrogen production, the results show that the southern region of Algeria (Adrar, Ghardaia, Bechar and Tamanrasset) is found to have the relatively highest hydrogen production. The total annual production of hydrogen is estimated to be around 2029m3 at these sites. The hydrogen production at various sites has been found to vary according to the solar radiation.

Djamila Ghribi; Abdellah Khelifa; Said Diaf; Maouf Belhamel

2013-01-01T23:59:59.000Z

403

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

EnhancEd hydrogEn Production EnhancEd hydrogEn Production intEgratEd with co 2 SEParation in a SinglE-StagE rEactor Description One alternative for the United States to establish independence from foreign energy sources is to utilize the nation's abundant domestic reserves of coal. Gasification provides a route to produce liquid fuels, chemical feedstocks, and hydrogen from coal. Coal continues to be viewed as the fuel source for the 21st century. Products from coal gasification, however, contain other gases, particularly carbon dioxide, as well as other contaminants that must be removed to produce the pure stream of hydrogen needed to operate fuel cells and other devices. This project seeks to demonstrate a technology to efficiently produce a pure hydrogen stream from

404

Extended Operations of the Pratt & Whitney Rocketdyne Pilot-Scale Compact Reformer Year 6 - Activity 3.2 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

U.S. and global demand for hydrogen is large and growing for use in the production of chemicals, materials, foods, pharmaceuticals, and fuels (including some low-carbon biofuels). Conventional hydrogen production technologies are expensive, have sizeable space requirements, and are large carbon dioxide emitters. A novel sorbent-based hydrogen production technology is being developed and advanced toward field demonstration that promises smaller size, greater efficiency, lower costs, and reduced to no net carbon dioxide emissions compared to conventional hydrogen production technology. Development efforts at the pilot scale have addressed materials compatibility, hot-gas filtration, and high-temperature solids transport and metering, among other issues, and have provided the basis for a preliminary process design with associated economics. The process was able to achieve a 93% hydrogen purity on a purge gasfree basis directly out of the pilot unit prior to downstream purification.

Almlie, Jay

2011-10-01T23:59:59.000Z

405

The effect of phosphorus on the formation of tungsten dioxide: A novel morphology  

SciTech Connect (OSTI)

The industrial production of tungsten is based on the hydrogen reduction of tungsten oxides, ammonium paratungstate (APT) or ammonium tungsten oxide bronze (ATOB). Hydrogen reduction is applied when high purity tungsten is required and when the addition of other elements or compounds (dopants) is desired for modification of the properties of the metal powder. The first stage of the reduction is finished when WO{sub 2} is formed and it seems that the efficient incorporation of the additives starts mainly at this reduction step. The study reported here was undertaken to investigate the effect of phosphorus dope on the morphology of the intermediate tungsten dioxide and analyze its influence on the grain size of the final tungsten metal powder. The authors observed star shaped morphology of WO{sub 2}, a structure which has not been describe in the literature. Contrary to the well-known cauliflower shaped tungsten dioxide, these starlets are not pseudomorphic to the initial ATOB particles; they grow separately and have a great influence on the grain size of the final metal powder.

Hegedus, E.; Neugebauer, J. [Hungarian Academy of Sciences, Budapest (Hungary). Research Inst. for Technical Physics and Materials Science] [Hungarian Academy of Sciences, Budapest (Hungary). Research Inst. for Technical Physics and Materials Science

1999-02-19T23:59:59.000Z

406

Ultrafine hydrogen storage powders  

DOE Patents [OSTI]

A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

2000-06-13T23:59:59.000Z

407

SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10-Megawatt Supercritical Carbon 10-Megawatt Supercritical Carbon Dioxide Turbine to someone by E-mail Share SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on Facebook Tweet about SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on Twitter Bookmark SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on Google Bookmark SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on Delicious Rank SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on Digg Find More places to share SunShot Initiative: 10-Megawatt Supercritical Carbon Dioxide Turbine on AddThis.com... Concentrating Solar Power Systems Components Competitive Awards CSP Research & Development Thermal Storage CSP Recovery Act Baseload CSP SunShot Multidisciplinary University Research Initiative

408

International Energy Outlook 2006 - Energy-Related Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

Eneregy-Related Carbon Dioxide Emissions Eneregy-Related Carbon Dioxide Emissions International Energy Outlook 2006 Chapter 7: Energy-Related Carbon Dioxide Emissions In the coming decades, actions to limit greenhouse gas emissions could affect patterns of energy use around the world and alter the level and composition of energy-related carbon dioxide emissions by energy source. Figure 65. World Carbon Dioxide Emissions by Region, 1990-2030 (Billion Metric Tons). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 66. World Carbon Dioxide Emissions by Fuel Type, 1980-2030 (Billion Metric Tons). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Carbon dioxide is one of the most prevalent greenhouse gases in the

409

EIA - 2010 International Energy Outlook - Energy-Related Carbon Dioxide  

Gasoline and Diesel Fuel Update (EIA)

Energy-Related Carbon Dioxide Emissions Energy-Related Carbon Dioxide Emissions International Energy Outlook 2010 Energy-Related Carbon Dioxide Emissions In 2007, non-OECD energy-related emissions of carbon dioxide exceeded OECD emissions by 17 percent. In the IEO2010 Reference case, energy-related carbon dioxide emissions from non-OECD countries in 2035 are about double those from OECD countries. Overview Because anthropogenic emissions of carbon dioxide result primarily from the combustion of fossil fuels, world energy use continues to be at the center of the climate change debate. In the IEO2010 Reference case, world energy-related carbon dioxide emissions29 grow from 29.7 billion metric tons in 2007 to 33.8 billion metric tons in 2020 and 42.4 billion metric tons in 2035 (Table 18).30

410

Synthesis and characterization of reduced tungsten sulfide cluster complexes  

SciTech Connect (OSTI)

Reduction of tungsten(IV) chloride with metals was studied in order to find a high-yield and convenient preparation of {alpha}-tungsten (II) chloride. The reduction of tungsten(IV) chloride with iron metal proved to be the most convenient and reliable synthesis, with a good yield of 60%. The reactions between {alpha}-tungsten(II) chloride and sodium hydrosulfide were investigated. Complete substitution of sulfide for chloride in W{sub 6}Cl{sub 8}{sup 4+} was achieved in the presence of sodium n-butoxide in pyridine solution. Single crystals were grown at elevated temperature (200{degrees}C) in pyridine, and the structure of W{sub 6}S{sub 8}(py){sub 6} was determined by single crystal x-ray techniques. The triethylphosphine (PEt{sub 3}) and tetrahydrothiophene (THT) complexes of W{sub 6}S{sub 8} were established by ligand displacement of pyridine in W{sub 6}S{sub 8}(py){sub 6}. Structures for both W{sub 6}S{sub 8}(PEt{sub 3}){sub 6}. 1.44CH{sub 2}Cl{sub 2} and W{sub 6}S{sub 8}(THT){sub 6} were determined by single crystal x-ray diffraction. These molecular complexes of the W{sub 6}S{sub 8} cluster were also characterized by infrared spectroscopy. 86 refs., 19 figs., 22 tabs.

Zhang, Xiang.

1991-06-27T23:59:59.000Z

411

The oceanic cycle and global atmospheric budget of carbonyl sulfide  

SciTech Connect (OSTI)

A significant portion of stratospheric air chemistry is influenced by the existence of carbonyl sulfide (COS). This ubiquitous sulfur gas represents a major source of sulfur to the stratosphere where it is converted to sulfuric acid aerosol particles. Stratospheric aerosols are climatically important because they scatter incoming solar radiation back to space and are able to increase the catalytic destruction of ozone through gas phase reactions on particle surfaces. COS is primarily formed at the surface of the earth, in both marine and terrestrial environments, and is strongly linked to natural biological processes. However, many gaps in the understanding of the global COS cycle still exist, which has led to a global atmospheric budget that is out of balance by a factor of two or more, and a lack of understanding of how human activity has affected the cycling of this gas. The goal of this study was to focus on COS in the marine environment by investigating production/destruction mechanisms and recalculating the ocean-atmosphere flux.

Weiss, P.S.

1994-12-31T23:59:59.000Z

412

Hydrogen Codes and Standards  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Codes and Standards Codes and Standards James Ohi National Renewable Energy Laboratory 1617 Cole Blvd. Golden, CO 80401 Background The development and promulgation of codes and standards are essential if hydrogen is to become a significant energy carrier and fuel because codes and standards are critical to establishing a market-receptive environment for commercializing hydrogen-based products and systems. The Hydrogen, Fuel Cells, and Infrastructure Technologies Program of the U.S. Department of Energy (DOE) and the National Renewable Energy Laboratory (NREL), with the help of the National Hydrogen Association (NHA) and other key stakeholders, are coordinating a collaborative national effort by government and industry to prepare, review, and promulgate hydrogen codes and standards needed to expedite hydrogen infrastructure development. The

413

President's Hydrogen Fuel Initiative  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Fuel Initiative Hydrogen Fuel Initiative Workshop on Manufacturing R&D for the Hydrogen Economy Washington, DC July 13, 2005 JoAnn Milliken DOE Hydrogen Program Planning U.S. Energy Dependence is Driven By Transportation * The U.S. imports 55% of its oil; expected to grow to 68% by 2025 under the status quo. * Transportation accounts for 2/3 of the 20 million barrels of oil our nation uses each day. * Gasoline hybrid electric vehicles will help in the near -mid term; a replacement for petroleum is needed for the long-term. 0 2 4 6 8 10 12 14 16 18 20 22 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020 2025 Million barrels per day Marine Rail Actual Projection Cars Air Light Trucks Heavy Vehicles U.S. Production Off-Road Projection Hydrogen Provides a Solution Producing hydrogen from domestic resources, including renewable, nuclear, and coal

414

Hydrogen Based Bacteria  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Based Bacteria Hydrogen Based Bacteria Name: Ellen Location: N/A Country: N/A Date: N/A Question: i was in my Biology class and a very respectable someone mentioned something about the discovery of a hydrogen based bacteria. my teacher wasnt aware of this study, and assigned me to find out about it. so i thought i would Email you and see if you people knew anything about it. Awaiting your repsonse Replies: I'm not quite sure what you mean by hydrogen based bacteria but I will take a stab that you mean bacteria that use hydrogen for energy. Some bacteria are chemolithotrophs which mean that they are autrophs but don't use the sun as their energy source; they get their energy from chemical sources. There are bacteria that use hydrogen as their energy source. They are diverse as a group and are all facultative. The overall chemical reaction looks like this:

415

Hydrogenation of carbonaceous materials  

DOE Patents [OSTI]

A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

1980-01-01T23:59:59.000Z

416

Hydrogen permeability and Integrity of hydrogen transfer pipelines  

E-Print Network [OSTI]

Natural Gas Pipelines Hydrogen embrittlement What is the relevance to hydrogen pipelines? ORNL researchHydrogen permeability and Integrity of hydrogen transfer pipelines Team: Sudarsanam Suresh Babu, Z Pressure Permeation Testing) Hydrogen Pipeline R&D, Project Review Meeting Oak Ridge National Laboratory

417

Hydrogen Delivery Technologies and Pipeline Transmission of Hydrogen  

E-Print Network [OSTI]

Issues for H2 Service Materials of Construction Hydrogen Embrittlement Presence of atomic hydrogen susceptible to Hydrogen Embrittlement. #12;Pipeline Transmission of Hydrogen --- 7 Copyright: H2 Induced, characteristic of hydrogen embrittlement. Photo Courtesy of NASA/Kennedy Space Center Materials Lab #12;Pipeline

418

BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop  

E-Print Network [OSTI]

BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Gary P · UK partnership opened the first hydrogen demonstration refueling station · Two hydrogen pipelines l · " i i l i 2 i i ll i i l pl ifi i · 8" ly idl i i l s Hydrogen Pipelines Two nes, on y a brand

419

Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*  

E-Print Network [OSTI]

Hydrogen Storage - Overview George Thomas, Hydrogen Consultant to SNL* and Jay Keller, Hydrogen volumetric density of gaseous fuels requires a storage method which compacts the fuel. Hence, hydrogen and cost-effective hydrogen storage? #12;4/14/03 3 Sandia National Laboratories From George Thomas, BES

420

Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide  

SciTech Connect (OSTI)

In this final report, we describe research results from Phase 2 of a technical/economic study of fossil hydrogen energy systems with carbon dioxide (CO{sub 2}) capture and storage (CCS). CO{sub 2} capture and storage, or alternatively, CO{sub 2} capture and sequestration, involves capturing CO{sub 2} from large point sources and then injecting it into deep underground reservoirs for long-term storage. By preventing CO{sub 2} emissions into the atmosphere, this technology has significant potential to reduce greenhouse gas (GHG) emissions from fossil-based facilities in the power and industrial sectors. Furthermore, the application of CCS to power plants and hydrogen production facilities can reduce CO{sub 2} emissions associated with electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) and, thus, can also improve GHG emissions in the transportation sector. This research specifically examines strategies for transitioning to large-scale coal-derived energy systems with CCS for both hydrogen fuel production and electricity generation. A particular emphasis is on the development of spatially-explicit modeling tools for examining how these energy systems might develop in real geographic regions. We employ an integrated modeling approach that addresses all infrastructure components involved in the transition to these energy systems. The overall objective is to better understand the system design issues and economics associated with the widespread deployment of hydrogen and CCS infrastructure in real regions. Specific objectives of this research are to: Develop improved techno-economic models for all components required for the deployment of both hydrogen and CCS infrastructure, Develop novel modeling methods that combine detailed spatial data with optimization tools to explore spatially-explicit transition strategies, Conduct regional case studies to explore how these energy systems might develop in different regions of the United States, and Examine how the design and cost of coal-based H{sub 2} and CCS infrastructure depend on geography and location.

Nils Johnson; Joan Ogden

2010-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Hydrogen powered bus  

ScienceCinema (OSTI)

Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

None

2013-11-22T23:59:59.000Z

422

ORIGIN OF THE AURIFEROUS BARITE-BASE METAL AND GOETHITE STAGES OF THE SUMMITVILLE HIGH SULFIDATION GOLD DEPOSIT, COLORADO, USA.  

E-Print Network [OSTI]

??The Summitville high-sulfidation gold deposit is hosted by a volcanic dome consisting of the South Mountain Quartz Latite that was erupted 23 Ma ago during (more)

Russin, Teresa Z.

2009-01-01T23:59:59.000Z

423

Hydrogen Compatibility of Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Compatibility of Materials Compatibility of Materials August 13, 2013 DOE EERE Fuel Cell Technologies Office Webinar Chris San Marchi Sandia National Laboratories Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000 SAND2013-6278P 2 Webinar Objectives * Provide context for hydrogen embrittlement and hydrogen compatibility of materials - Distinguish embrittlement, compatibility and suitability - Examples of hydrogen embrittlement * Historical perspective - Previous work on hydrogen compatibility - Motivation of "Materials Guide" * Identify the landscape of materials compatibility documents

424

Hydrogen Generation by Electrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Better Engineered Solutions. Better Engineered Solutions. What Listening Generates. Better Engineered Solutions. What Listening Generates. Hydrogen Generation by Electrolysis September 2004 Steve Cohen Hydrogen Generation by Electrolysis September 2004 Steve Cohen NREL H 2 Electrolysis - Utility Integration Workshop NREL H 2 Electrolysis - Utility Integration Workshop 2 Hydrogen Generation by Electrolysis Hydrogen Generation by Electrolysis  Intro to Teledyne Energy Systems  H 2 Generator Basics & Major Subsystems  H 2 Generating & Storage System Overview  Electrolysis System Efficiency & Economics  Focus for Attaining DOE H 2 Production Cost Goals 3 Teledyne Energy Systems Locations - ISO 9001 Teledyne Energy Systems Locations - ISO 9001 Hunt Valley, Maryland  State-of-the-art thermoelectric,

425

Hydrogen permeation resistant barrier  

DOE Patents [OSTI]

A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

McGuire, Joseph C. (Richland, WA); Brehm, William F. (Richland, WA)

1982-01-01T23:59:59.000Z

426

Hydrogen Generator Appliance  

Broader source: Energy.gov (indexed) [DOE]

lAbOrAtOry NG Workshop summary report - appeNDIX J slide presentation: hydrogen Generator appliance Gus Block, Nuvera Fuel Cells...

427

Module 2: Hydrogen Use  

Broader source: Energy.gov [DOE]

This course covers the processes by which hydrogen is extracted, how it is stored and transported, and the inherent advantages and disadvantages of each method

428

Hydrogen | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

electric cooperatives* to offer net metering to customers who generate electricity using solar energy, wind energy, hydropower, hydrogen, biomass, landfill gas, geothermal energy,...

429

Hydrogen Production & Delivery  

Energy Savers [EERE]

* Address key materials needs for P&D: Membranes, Catalysts, PEC Devices, Reactors, and Tanks Hydrogen from Coal * Complete laboratory-scale development of separation and...

430

Renewable Hydrogen (Presentation)  

SciTech Connect (OSTI)

Presentation about the United State's dependence on oil, how energy solutions are challenging, and why hydrogen should be considered as a long-term alternative for transportation fuel.

Remick, R. J.

2009-11-16T23:59:59.000Z

431

Hydrogen Production & Delivery  

Broader source: Energy.gov [DOE]

"2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation H2 and Fuel Cells Plenary "

432

Hydrogen Release Behavior  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

433

Hydrogen permeation resistant barrier  

DOE Patents [OSTI]

A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

McGuire, J.C.; Brehm, W.F.

1980-02-08T23:59:59.000Z

434

President's Hydrogen Fuel Initiative  

Broader source: Energy.gov [DOE]

Hydrogen Infrastructure and Fuel Cell Technologies put on an Accelerated Schedule. President Bush commits a total $1.7 billion over first 5 years

435

Hydrogen Safety Knowledge Tools  

SciTech Connect (OSTI)

With hydrogen gaining acceptance as an energy carrier for fuel cell vehicles and stationary fuel cell applications, a new community of hydrogen users is emerging and continues to grow. With this growth has come the need to spread the word about safe practices for handling, storing, and using hydrogen. Like all energy forms, hydrogen can be used safely through proper procedures and engineering techniques. However, hydrogen involves a degree of risk that must be respected, and the importance of avoiding complacency or haste in the safe conduct and performance of projects involving hydrogen cannot be overstated. To encourage and promote the safe use of hydrogen, Pacific Northwest National Laboratory (PNNL) has developed and continues to enhance two software tools in support of the U.S. Department of Energy's Fuel Cell Technologies Program: the Hydrogen Safety Best Practices online manual (www.H2BestPractices.org) and the Hydrogen Incident Reporting and Lessons Learned database (www.H2Incidents.org).

Fassbender, Linda L.

2011-01-31T23:59:59.000Z

436

Hydrogen ion microlithography  

DOE Patents [OSTI]

Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing. 6 figs.

Tsuo, Y.S.; Deb, S.K.

1990-10-02T23:59:59.000Z

437

Detroit Commuter Hydrogen Project  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

438

Hydrogen Fuel Cells  

Fuel Cell Technologies Publication and Product Library (EERE)

The fuel cell an energy conversion device that can efficiently capture and use the power of hydrogen is the key to making it happen.

439

Department of Energy - Hydrogen  

Broader source: Energy.gov (indexed) [DOE]

Goes to.... Lighting Up Operations with Hydrogen and Fuel Cell Technology http:energy.goveerearticlesand-oscar-sustainable-mobile-lighting-goes-lighting-operations-hydro...

440

Thin film hydrogen sensor  

DOE Patents [OSTI]

A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed.

Lauf, Robert J. (Oak Ridge, TN); Hoffheins, Barbara S. (Knoxville, TN); Fleming, Pamela H. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Alternative Fuels Data Center: Hydrogen  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen to someone by E-mail Share Alternative Fuels Data Center: Hydrogen on Facebook Tweet about Alternative Fuels Data Center: Hydrogen on Twitter Bookmark Alternative Fuels Data Center: Hydrogen on Google Bookmark Alternative Fuels Data Center: Hydrogen on Delicious Rank Alternative Fuels Data Center: Hydrogen on Digg Find More places to share Alternative Fuels Data Center: Hydrogen on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations Vehicles Laws & Incentives Hydrogen Hydrogen is a potentially emissions-free alternative fuel that can be produced from diverse domestic energy sources. Research is under way to make hydrogen vehicles practical for widespread use.

442

FCT Hydrogen Production: Current Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Current Technology to Current Technology to someone by E-mail Share FCT Hydrogen Production: Current Technology on Facebook Tweet about FCT Hydrogen Production: Current Technology on Twitter Bookmark FCT Hydrogen Production: Current Technology on Google Bookmark FCT Hydrogen Production: Current Technology on Delicious Rank FCT Hydrogen Production: Current Technology on Digg Find More places to share FCT Hydrogen Production: Current Technology on AddThis.com... Home Basics Current Technology Thermal Processes Electrolytic Processes Photolytic Processes R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology The development of clean, sustainable, and cost-competitive hydrogen

443

Carbon Dioxide Capture Process with Regenerable Sorbents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dioxide Capture Process with Regenerable Sorbents Dioxide Capture Process with Regenerable Sorbents sorbent material. Additionally, the design of the system incorporates a cross- flow moving-bed reactor where the gas flows horizontally through a "panel" of solid sorbent that is slowly moving down-wards under gravity flow. With the expanded use of fossil fuels expected throughout the world, the increase in CO 2 emissions may prove to contribute even more significantly to global climate change. To address this problem, carbon sequestration scientists and engineers have proposed a number of methods to remove CO 2 from gas streams, such as chemical absorption with a solvent, membrane separation, and cryogenic fractionation. However, all of these methods are expensive and possibly cost-prohibitive for a specific application.

444

Atmospheric Carbon Dioxide Record from Mauna Loa  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SIO Air Sampling Network » Mauna Loa SIO Air Sampling Network » Mauna Loa Atmospheric Carbon Dioxide Record from Mauna Loa DOI: 10.3334/CDIAC/atg.035 graphics Graphics data Data Investigators R.F. Keeling, S.C. Piper, A.F. Bollenbacher and J.S. Walker Carbon Dioxide Research Group Scripps Institution of Oceanography University of California La Jolla, California 92093-0444, U.S.A. Period of Record 1958-2008 Methods Air samples at Mauna Loa are collected continuously from air intakes at the top of four 7-m towers and one 27-m tower. Four air samples are collected each hour for the purpose of determining the CO2 concentration. Determinations of CO2 are made by using a Siemens Ultramat 3 nondispersive infrared gas analyzer with a water vapor freeze trap. This analyzer registers the concentration of CO2 in a stream of air flowing at ~0.5

445

Carbon dioxide utilization and seaweed production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dioxide utilization and seaweed production dioxide utilization and seaweed production V.R.P.Sinha World Bank Project Bangladesh Fisheries Research Institute, Mymensingh, Bangladesh e-mails; vrpsinha@ mymensingh.net, vidyut_s@hotmail.com Lowell Fraley L.D. Fraley & Associates, LLC, P.O. Box 1525, Sugarland, TX 77487, USA, e-mail idf@hia.net BS Chowdhry ISS Consultants, Inc. 13111 Westheimer, Suite 303, Houston, Texas 77077, USA, e-mail bsc@issci.com Abstract: Stronger growth in many plants stimulated by increased CO 2 concentration should lead to greater biological productivity with an expected increase in the photosynthetic storage of carbon. Thus, the biosphere will serve as a sink for CO 2 , though it will also act as a source too, because of respiration. Normally net photosynthesis dominates in summer and

446

Coal Bed Sequestration of Carbon Dioxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

COAL BED SEQUESTRATION OF CARBON DIOXIDE COAL BED SEQUESTRATION OF CARBON DIOXIDE R. Stanton (rstanton@usgs.gov; 703-648-6462) U.S. Geological Survey MS 956 National Center Reston, VA 20192 R. Flores (rflores@usgs.gov; 303-236-7774) U.S. Geological Survey MS 939, Denver Federal Center Denver, CO 80225 P.D. Warwick (pwarwick@usgs.gov; 703-648-6469) H. Gluskoter (halg@usgs.gov; 703-648-6429) U.S. Geological Survey MS 956 National Center Reston, VA 20192 G.D. Stricker (303-236-7763) U.S. Geological Survey MS 939, Denver Federal Center Denver, CO 80225 Introduction Geologic sequestration of CO 2 generated from fossil fuel combustion may be an environmentally attractive method to reduce the amount of greenhouse gas emissions. Of the geologic options, sequestering CO

447

The urgent need for carbon dioxide sequestration  

SciTech Connect (OSTI)

The danger of global warming has put in question the use of fossil fuels which constitute the most abundant and most reliable energy resource. Meeting the ever growing world demand for cheap energy, while simultaneously achieving the required drastic reduction in CO{sub 2} emissions can only be accomplished by actively preventing carbon dioxide generated in the combustion of fuels from accumulating in the atmosphere, i.e. by sequestration. Sequestration is possible and economically viable and is currently the only realistic solution to the dilemma of CO{sub 2} emissions. The authors have developed a very promising approach that disposes of carbon dioxide by chemically combining it in an exothermic reaction with readily available minerals to form carbonates. The resulting carbonates are stable solids that are known to be environmentally benign and to be stable on geological time scales. This stands in contrast to most other methods that do not appear to fully solve the long term problem.

Lackner, K.S.; Butt, D.P.; Jensen, R.; Ziock, H.

1998-09-01T23:59:59.000Z

448

Carbon Dioxide Emissions from Industrialized Countries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 6 Carbon Dioxide Emissions from Industrialized Countries Extended discussion here Carbon emissions per capita 1973 vs. 1991 by major end use. (Denmark comparison is 1972 and 1991) With the third Conference of the Parties (COP-3) in Kyoto approaching, there is a great deal of excitement over policies designed to reduce future carbon dioxide (CO2) emissions from fossil fuels. At COP-3, more than 130 nations will meet to create legally binding targets for CO2 reductions. Accordingly, we have analyzed the patterns of emissions arising from the end uses of energy (and electricity production) in ten industrialized countries, with surprising and, in some cases, worrisome results. The surprise is that emissions in many countries in the early 1990s were lower than in the 1970s in an absolute sense and on a per capita basis; the worry

449

Hydrogen Threshold Cost Calculation | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Threshold Cost Calculation Hydrogen Threshold Cost Calculation DOE Hydrogen Program Record number11007, Hydrogen Threshold Cost Calculation, documents the methodology and...

450

Hydrogen Refueling Station Costs in Shanghai  

E-Print Network [OSTI]

high-pressure stationary hydrogen storage tanks. The storagehigh-pressure gaseous hydrogen storage containers, and atrailer Compressed hydrogen storage High-pressure hydrogen

Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

2006-01-01T23:59:59.000Z

451

Hydrogen Delivery - Basics | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Delivery Hydrogen Delivery - Basics Hydrogen Delivery - Basics Photo of light-duty vehicle at hydrogen refueling station. Infrastructure is required to move hydrogen from the...

452

NREL: Hydrogen and Fuel Cells Research - Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen and Fuel Cell Basics Photo of vehicle filling up at renewable hydrogen fueling station. NREL's hydrogen fueling station dispenses hydrogen produced via renewable...

453

Combination moisture and hydrogen getter  

DOE Patents [OSTI]

A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (1) a solid acetylenic compound and (2) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

Harrah, L.A.; Mead, K.E.; Smith, H.M.

1983-09-20T23:59:59.000Z

454

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

455

6, 16191636, 2006 OCS variations by  

E-Print Network [OSTI]

significant sulfur trace gases such as carbon disulfide (CS2), hydrogen sulphide (H2S), dimethyl sulfide (DMS ­ (CH3)2S) and sulfur dioxide5 (SO2) (Brimblecombe, 1996). This lifetime, combined with an abundance, in the form of sulfur dioxide (SO2), directly to the stratosphere (Crutzen, 1976; Ko et al., 2003). However

Boyer, Edmond

456

Electrochemical hydrogen Storage Systems  

SciTech Connect (OSTI)

As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

Dr. Digby Macdonald

2010-08-09T23:59:59.000Z

457

DOE Hydrogen and Fuel Cells Program: Hydrogen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Systems Integration U.S. Department of Energy Search help Home > Hydrogen Production Printable Version Hydrogen Production Hydrogen can be produced from diverse domestic feedstocks using a variety of process technologies. Hydrogen-containing compounds such as fossil fuels, biomass or even water can be a source of hydrogen. Thermochemical processes can be used to produce hydrogen from biomass and from fossil fuels such as coal, natural gas and petroleum. Power generated from sunlight, wind and nuclear sources can be used to produce hydrogen electrolytically. Sunlight alone can also drive photolytic production of

458

Ovonic Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC |  

Open Energy Info (EERE)

Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC Jump to: navigation, search Name Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC) Place Rochester Hills, Michigan Zip 48309 Sector Hydro, Hydrogen, Vehicles Product It commercializes hydrogen storage technology based on metal-hydrides for portable and stationary power systems as well as fuel-cell vehicles. References Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC) is a company located in Rochester Hills, Michigan . References

459

Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines  

Broader source: Energy.gov [DOE]

Project Objectives: To gain basic understanding of hydrogen permeation behavior and its impact on hydrogen embrittlement of pipeline steels under high gaseous pressures relevant to hydrogen gas transmission pipeline

460

Carbon dioxide in Arctic and subarctic regions  

SciTech Connect (OSTI)

A three year research project was presented that would define the role of the Arctic ocean, sea ice, tundra, taiga, high latitude ponds and lakes and polar anthropogenic activity on the carbon dioxide content of the atmosphere. Due to the large physical and geographical differences between the two polar regions, a comparison of CO/sub 2/ source and sink strengths of the two areas was proposed. Research opportunities during the first year, particularly those aboard the Swedish icebreaker, YMER, provided additional confirmatory data about the natural source and sink strengths for carbon dioxide in the Arctic regions. As a result, the hypothesis that these natural sources and sinks are strong enough to significantly affect global atmospheric carbon dioxide levels is considerably strengthened. Based on the available data we calculate that the whole Arctic region is a net annual sink for about 1.1 x 10/sup 15/ g of CO/sub 2/, or the equivalent of about 5% of the annual anthropogenic input into the atmosphere. For the second year of this research effort, research on the seasonal sources and sinks of CO/sub 2/ in the Arctic will be continued. Particular attention will be paid to the seasonal sea ice zones during the freeze and thaw periods, and the tundra-taiga regions, also during the freeze and thaw periods.

Gosink, T. A.; Kelley, J. J.

1981-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy  

E-Print Network [OSTI]

A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

Medina, David Salvador

2011-01-01T23:59:59.000Z

462

Effect of hydrogen addition on criteria and greenhouse gas emissions for a marine diesel engine  

Science Journals Connector (OSTI)

Abstract Hydrogen remains an attractive alternative fuel to petroleum and a number of investigators claim that adding hydrogen to the air intake manifold of a diesel engine will reduce criteria emissions and diesel fuel consumption. Such claims are appealing when trying to simultaneously reduce petroleum consumption, greenhouse gases and criteria pollutants. The goal of this research was to measure the change in criteria emissions (CO, NOx, and PM2.5) and greenhouse gases such as carbon dioxide (CO2), using standard test methods for a wide range of hydrogen addition rates. A two-stroke Detroit Diesel Corporation 12V-71TI marine diesel engine was mounted on an engine dynamometer and tested at three out of the four loads specified in the ISO 8178-4 E3 emission test cycle and at idle. The engine operated on CARB ultra-low sulfur #2 diesel with hydrogen added at flow rates of 0, 22 and 220 SLPM. As compared with the base case without hydrogen, measurements showed that hydrogen injection at 22 and 220 SLPM had negligible influence on the overall carbon dioxide specific emission, EF CO 2 . However, in examining data at each load the data revealed that at idle EF CO 2 was reduced by 21% at 22 SLPM (6.9% of the added fuel energy was from hydrogen) and 37.3% at 220 SLPM (103.1% of the added fuel energy was from hydrogen). At all other loads, the influence of added hydrogen was insignificant. Specific emissions for nitrogen oxides, EF NO x , and fine particulate matters, EF PM 2.5 , showed a trade-off relationship at idle. At idle, EF NO x was reduced by 28% and 41% with increasing hydrogen flow rates, whilst EF PM 2.5 increased by 41% and 86% respectively. For other engine loads, EF NO x and EF PM 2.5 did not change significantly with varying hydrogen flow rates. One of the main reasons for the greater impact of hydrogen at idle is that the contribution of hydrogen to the total fuel energy is much higher at idle as compared to the other loads. The final examination in this paper was the system energy balance when hydrogen is produced by an on-board electrolysis unit. An analysis at 75% engine load showed that hydrogen production increased the overall equivalent fuel consumption by 2.6% at 22 SLPM and 17.7% at 220 SLPM.

Hansheng Pan; Sam Pournazeri; Marko Princevac; J. Wayne Miller; Shankar Mahalingam; M. Yusuf Khan; Varalakshmi Jayaram; William A. Welch

2014-01-01T23:59:59.000Z

463

DOE Hydrogen Analysis Repository: Transition to Hydrogen Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transition to Hydrogen Transportation Fuel Transition to Hydrogen Transportation Fuel Project Summary Full Title: A Smooth Transition to Hydrogen Transportation Fuel Project ID: 87 Principal Investigator: Gene Berry Brief Description: This project contrasts the options of decentralized production using the existing energy distribution network, and centralized production of hydrogen with a large-scale infrastructure. Keywords: Infrastructure; costs; hydrogen production Purpose The case for hydrogen-powered transportation requires an assessment of present and prospective methods for producing, storing, and delivering hydrogen. This project examines one potential pathway: on-site production of hydrogen to fuel light-duty vehicles. Performer Principal Investigator: Gene Berry Organization: Lawrence Livermore National Laboratory (LLNL)

464

Plasma post-hydrogenation of hydrogenated amorphous silicon and germanium  

SciTech Connect (OSTI)

Incorporation and kinetics of hydrogen during plasma post-hydrogenation and thermal treatment are discussed for a-Si:H and a-Ge:H films. For material of low hydrogen content, the hydrogen surface concentration reached by plasma treatment equals the hydrogen concentration obtained by deposition at the same temperature and under similar plasma conditions. Enhancements of the hydrogen diffusion coefficient and of hydrogen solubility observed for plasma treatment at temperatures {le}400 C and {le}300 C for a-Si:H and a-Ge:H, respectively, are attributed to a plasma induced rise of the surface hydrogen chemical potential.

Beyer, W.; Zastrow, U. [Forschungszentrum Juelich (Germany). Inst. fuer Schicht- und Ionentechnik

1996-12-31T23:59:59.000Z

465

Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines  

Broader source: Energy.gov [DOE]

Code for Hydrogen Piping and Pipelines. B31 Hydrogen Section Committee to develop a new code for H2 piping and pipelines.

466

NREL: Hydrogen and Fuel Cells Research - Hydrogen System Component...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

other hydrogen system components. Reliable components are needed to ensure the success of hydrogen fueling stations and support the commercial deployment of fuel cell electric...

467

NREL: Hydrogen and Fuel Cells Research - Hydrogen Production...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Cost adjusted to 2007 dollars, accurate to two significant figures. Printable Version Hydrogen & Fuel Cells Research Home Projects Fuel Cells Hydrogen Production & Delivery...

468

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen and Fuel Cells Program Record Record : 5037 Date: May 22, 2006 Title: Hydrogen Storage Materials - 2004 vs 2006 Originator: Sunita Satyapal Approved by: JoAnn Milliken...

469

NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Production and Delivery Hydrogen Production and Delivery Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen Dinh, focus on the following topics: Biological Water Splitting Fermentation Conversion of Biomass and Wastes Photoelectrochemical Water Splitting Solar Thermal Water Splitting Renewable Electrolysis Hydrogen Dispenser Hose Reliability Hydrogen Production and Delivery Pathway Analysis. Biological Water Splitting Certain photosynthetic microbes use light energy to produce hydrogen from

470

The Hydrogen Backlash  

Science Journals Connector (OSTI)

...from outside: the infrastructure they need to...existing electricity grid or natural gas...massive new hydrogen infrastructure to deliver the...development of hybrid cars, critics...out on page 974 , hybrid electric vehicles...separate hydrogen infrastructure. Near-term help...

Robert F. Service

2004-08-13T23:59:59.000Z

471

The Hydrogen Backlash  

Science Journals Connector (OSTI)

...paces, 200 fuel cells under...Switching from fossil fuels to hydrogen...reduce urban air pollution, lower dependence...cleaner air, lower greenhouse...cost of the fuel drops to $1.50...hydrogen from fossil fuels, DOE...none of these solutions is up to...

Robert F. Service

2004-08-13T23:59:59.000Z

472

Hydrogen Delivery- Current Technology  

Broader source: Energy.gov [DOE]

Hydrogen is transported from the point of production to the point of use via pipeline, over the road in cryogenic liquid trucks or gaseous tube trailers, or by rail or barge. Read on to learn more about current hydrogen delivery and storage technologies.

473

Hydrogen, Fuel Infrastructure  

E-Print Network [OSTI]

results of using hydrogen power, of course, will be energy independence for this nation... think about between hydrogen and oxygen generates energy, which can be used to power a car producing only water to taking these cars from laboratory to showroom so that the first car driven by a child born today could

474

Thick film hydrogen sensor  

DOE Patents [OSTI]

A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors. 8 figs.

Hoffheins, B.S.; Lauf, R.J.

1995-09-19T23:59:59.000Z

475

FCT Hydrogen Storage: Current Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Current Technology to someone Current Technology to someone by E-mail Share FCT Hydrogen Storage: Current Technology on Facebook Tweet about FCT Hydrogen Storage: Current Technology on Twitter Bookmark FCT Hydrogen Storage: Current Technology on Google Bookmark FCT Hydrogen Storage: Current Technology on Delicious Rank FCT Hydrogen Storage: Current Technology on Digg Find More places to share FCT Hydrogen Storage: Current Technology on AddThis.com... Home Basics Current Technology Gaseous and Liquid Hydrogen Storage Materials-Based Hydrogen Storage Hydrogen Storage Challenges Status of Hydrogen Storage Technologies DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology

476

Renewable Resources for Hydrogen (Presentation)  

SciTech Connect (OSTI)

This presentation provides an overview of renewable resources for hydrogen. It was presented at the National Hydrogen Association Hydrogen Conference & Expo in Long Beach, CA, May 3-6, 2010.

Jalalzadeh-Azar, A. A.

2010-05-03T23:59:59.000Z

477

Gaseous and Liquid Hydrogen Storage  

Broader source: Energy.gov [DOE]

Today's state of the art for hydrogen storage includes 5,000- and 10,000-psi compressed gas tanks and cryogenic liquid hydrogen tanks for on-board hydrogen storage.

478

The Bumpy Road to Hydrogen  

E-Print Network [OSTI]

in the cost of hydrogen production, distribution, and use.accelerate R&D of zero-emission hydrogen production methods.Renewable hydrogen production is a key area for focused

Sperling, Dan; Ogden, Joan M

2006-01-01T23:59:59.000Z

479

Hydrogen in semiconductors and insulators  

E-Print Network [OSTI]

type can be applied to hydrogen storage materials. Keywords:can be applied to hydrogen storage materials. Manuscript O-of the formalism to hydrogen storage materials. A partial

Van de Walle, Chris G.

2007-01-01T23:59:59.000Z

480

Thin Film Hydrogen Storage System  

Science Journals Connector (OSTI)

In the last one decade the use of hydrogen as an energy carrier has attracted world ... on the technology involved for the production, storage and use of hydrogen. In this paper we discuss storage aspect of hydrogen

I. P. Jain; Y. K. Vijay

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "dioxide hydrogen sulfide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Hydrogen Delivery | Department of Energy  

Energy Savers [EERE]

truck at hydrogen production facility. A viable hydrogen infrastructure requires that hydrogen be able to be delivered from where it's produced to the point of end-use, such as...

482

Hydrogen from Coal Edward Schmetz  

E-Print Network [OSTI]

Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Cells, Turbines, and Carbon Capture & Sequestration #12;Production Goal for Hydrogen from Coal Central Separation System PSA Membrane Membrane Carbon Sequestration Yes (87%) Yes (100%) Yes (100%) Hydrogen

483

Hydrogen Storage- Overview  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- - Overview George Thomas, Hydrogen Consultant to SNL * and Jay Keller, Hydrogen Program Manager Sandia National Laboratories H 2 Delivery and Infrastructure Workshop May 7-8, 2003 * Most of this presentation has been extracted from George Thomas' invited BES Hydrogen Workshop presentation (May 13-14, 2003) Sandia National Laboratories 4/14/03 2 Sandia National Laboratories From George Thomas, BES workshop 5/13/03 H 2 storage is a critical enabling technology for H 2 use as an energy carrier The low volumetric density of gaseous fuels requires a storage method which compacts the fuel. Hence, hydrogen storage systems are inherently more complex than liquid fuels. Storage technologies are needed in all aspects of hydrogen utilization. production distribution utilization

484

Electrochemical Hydrogen Compression (EHC)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrochemical Hydrogen Compression (EHC) Pinakin Patel and Ludwig Lipp Presentation at DOE Hydrogen Compression, Storage and Dispensing Workshop at ANL Argonne, IL March 20, 2013 2 * Experience with all fuel cells - MCFC, SOFC, PEM, PAFC, etc. * Excellent progress in commercialization of MCFC technology (>300 MW installed + backlog, >50 MW per year production rate, 11 MW single site unit in Korea, >1.5 billion kWh produced) * Unique internal reforming technology for high efficiency fuel cells FCE Overview $- $2,000 $4,000 $6,000 $8,000 $10,000 2003 2007 2011 mid-term Product cost per kW 3 H 2 Peak and Back- up Power Fuel Cell Cars DFC ® Power Plant (Electricity + Hydrogen) Solid State Hydrogen Separator (EHS) Solid State Hydrogen

485

NREL: Learning - Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Storage Hydrogen Storage On the one hand, hydrogen's great asset as a renewable energy carrier is that it is storable and transportable. On the other hand, its very low natural density requires storage volumes that are impractical for vehicles and many other uses. Current practice is to compress the gas in pressurized tanks, but this still provides only limited driving range for vehicles and is bulkier than desirable for other uses as well. Liquefying the hydrogen more than doubles the fuel density, but uses up substantial amounts of energy to lower the temperature sufficiently (-253°C at atmospheric pressure), requires expensive insulated tanks to maintain that temperature, and still falls short of desired driving range. One possible way to store hydrogen at higher density is in the spaces within the crystalline

486

Hydrogen Threshold Cost Calculation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Program Record (Offices of Fuel Cell Technologies) Program Record (Offices of Fuel Cell Technologies) Record #: 11007 Date: March 25, 2011 Title: Hydrogen Threshold Cost Calculation Originator: Mark Ruth & Fred Joseck Approved by: Sunita Satyapal Date: March 24, 2011 Description: The hydrogen threshold cost is defined as the hydrogen cost in the range of $2.00-$4.00/gge (2007$) which represents the cost at which hydrogen fuel cell electric vehicles (FCEVs) are projected to become competitive on a cost per mile basis with the competing vehicles [gasoline in hybrid-electric vehicles (HEVs)] in 2020. This record documents the methodology and assumptions used to calculate that threshold cost. Principles: The cost threshold analysis is a "top-down" analysis of the cost at which hydrogen would be

487

Hydrogen Fuel Quality  

SciTech Connect (OSTI)

For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

Rockward, Tommy [Los Alamos National Laboratory

2012-07-16T23:59:59.000Z

488

Hydrogen Purity Standard  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Compressed Gas Association Compressed Gas Association Roger A. Smith Technical Director April 26, 2004 Hydrogen Purity Standard Compressed Gas Association 2 Compressed Gas Association ‹ 150 Members „ Industrial Gas Companies „ Equipment Manufacturers „ Other Gas Industry Associations „ Other SDOs ‹ Manufacturers, Fillers, Distributors, and Transporters of Industrial and Medical Gases Compressed Gas Association 3 Hydrogen Activities ‹ Committees „ Hydrogen Fuel Technology „ Bulk Distribution Equipment „ Hazardous Materials Codes „ Gas Specifications „ Cylinders, Valves & PRD's ‹ International „ Europe (EIGA) „ Japan (JIGA) „ Asia (AIGA) „ United Nations Compressed Gas Association 4 Hydrogen Purity Standard ‹ Draft hydrogen purity standard for stationary fuel cells and ICE's in 10 months

489

EA-1336: Ocean Sequestration of Carbon Dioxide Field Experiment,  

Broader source: Energy.gov (indexed) [DOE]

336: Ocean Sequestration of Carbon Dioxide Field Experiment, 336: Ocean Sequestration of Carbon Dioxide Field Experiment, Pittsburgh, Pennsylvania EA-1336: Ocean Sequestration of Carbon Dioxide Field Experiment, Pittsburgh, Pennsylvania SUMMARY This EA evaluates the environmental impacts for the U.S. Department of Energy National Energy Technology Laboratory's proposal to participate with a group of international organizations in an experiment to evaluate the dispersion and diffusion of liquid carbon dioxide droplets in ocean waters. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD May 4, 2001 EA-1336: Finding of No Significant Impact Ocean Sequestration of Carbon Dioxide Field Experiment May 4, 2001 EA-1336: Final Environmental Assessment Ocean Sequestration of Carbon Dioxide Field Experiment

490

Improving Repository Performance by Using DU Dioxide Fill  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DU Dioxide Fill DU Dioxide Fill Improving Repository Performance by Using DU Dioxide Fill Fills may improve repository performance by acting as sacrificial materials, which delay the degradation of SNF uranium dioxide. Because fill and SNF have the same chemical form of uranium (uranium dioxide), the DU dioxide in a repository is the only fill which has the same behavior as that of the SNF. In the natural environment, some uranium ore deposits have remained intact for very long periods of time. The outer parts of the ore deposit degrade while the inner parts of the deposit are protected. The same approach is proposed herein for protecting SNF. The application could use half or more of the DU inventory in the United States. Behavior of Uranium and Potential Behavior of a Waste Package with SNF and Fill

491

Building Technologies Office: Nano-Enabled Titanium Dioxide Ultraviolet  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nano-Enabled Titanium Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project to someone by E-mail Share Building Technologies Office: Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project on Facebook Tweet about Building Technologies Office: Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project on Twitter Bookmark Building Technologies Office: Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project on Google Bookmark Building Technologies Office: Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project on Delicious Rank Building Technologies Office: Nano-Enabled Titanium Dioxide

492

DOE Hydrogen Analysis Repository: CO2 Reduction Benefits Analysis for Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 Reduction Benefits Analysis for Fuel Cell Applications CO2 Reduction Benefits Analysis for Fuel Cell Applications Project Summary Full Title: CO2 Reduction Benefits Analysis for Fuel Cell Applications Project ID: 263 Principal Investigator: Chip Friley Brief Description: This analysis used the 10-region U.S. MARKAL model to quantify the impact of changes in production, distribution and vehicle costs and carbon prices on fuel cell vehicle penetration and overall carbon dioxide emissions. Keywords: Carbon dioxide (CO2); Hydrogen; Fuel cells Purpose Perform analysis of topics of interest to the DOE Fuel Cell Technologies program related to projected carbon dioxide reduction benefits of fuel cell applications. Performer Principal Investigator: Chip Friley Organization: Brookhaven National Laboratory (BNL) Address: Mail Stop 475C

493

Hydrogen Data Book from the Hydrogen Analysis Resource Center  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). Its made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

494

NETL: Hydrogen Selective Exfoliated Zeolite Membranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Designing and Validating Ternay Pd Alloys for Optimum Sulfur/Carbon Resistance Designing and Validating Ternay Pd Alloys for Optimum Sulfur/Carbon Resistance Project No.: DE-FE0001181 Gas Permeation Cell and Test Stand Pall Corporation is developing an economically-viable hydrogen/carbon dioxide (H2/CO2) separation membrane system that would allow efficient capture of CO2 at high temperature and pressure from gasified coal in the presence of typical contaminants. Goals for the project include creating an advanced palladium alloy for optimum hydrogen separation performance using combinatorial material methods for high-throughput screening, testing, and characterization and demonstrating durability by long term testing of a pilot membrane module at a commercial coal gasification facility. The advantages of this technology are reduction of CO2 compression costs, lack of need for both upstream and downstream heat exchange and complex heat integration, and the potential for integration with water gas shift in a single compact membrane reactor system.

495

Reduced graphene oxide based silver sulfide hybrid films formed at a liquid/liquid interface  

SciTech Connect (OSTI)

Free-standing, ultra-thin films of silver sulfide and reduced graphene oxide (RGO) based silver sulfide hybrids are prepared at a liquid/liquid interface employing in situ chemical reaction strategy. Ag{sub 2}S and RGO?Ag{sub 2}S hybrid films are characterized by various techniques such as UV-visible and photo luminescence spectroscopy, X-ray diffraction and scanning electron microscopy. The morphology of hybrid films consists of Ag{sub 2}S nanocrystals on RGO surface while Ag{sub 2}S films contains branched network of dendritic structures. RGO?Ag{sub 2}S exhibit interesting optical and electrical properties. The hybrid films absorb in the region 500650 nm and show emission in the red region. A higher conductance is observed for the hybrid films arising from the RGO component. This simple low cost method can be extended to prepare other RGO based metal sulfides.

Bramhaiah, K., E-mail: jsneena@csmr.res.in; John, Neena S., E-mail: jsneena@csmr.res.in [Centre for Soft Matter Research, P.B. No.1329, Jalahalli, Bangalore-560013 (India)

2014-04-24T23:59:59.000Z

496

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas Previous Next List Weigang Lu, Julian P. Sculley, Daqiang Yuan, Rajamani Krishna, Zhangwen Wei,...

497

Carbon Dioxide Capture and Storage Demonstration in Developing...  

Open Energy Info (EERE)

Key Policy Issues and Barriers Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key...

498

Synthesis, Structure, and Carbon Dioxide Capture Properties of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks Previous Next List Anh Phan, Christian J. Doonan, Fernando J. Uribe-Romo, Carolyn B....

499

Dissociation of carbon dioxide in atmospheric pressure microchannel plasma devices.  

E-Print Network [OSTI]

??Plasma discharge of carbon dioxide at atmospheric pressure was successfully demonstrated in microchannel plasma devices at breakdown voltages lower than 1 kVRMS. Optical emissions of (more)

Oh, Taegon

2013-01-01T23:59:59.000Z

500

Carbon dioxide sequestration underground laser based detection system.  

E-Print Network [OSTI]

??Carbon dioxide (CO 2) is a known greenhouse gas. Due to the burning of fossil fuels by industrial and power plants the atmospheric concentration of (more)

Barr, Jamie Lynn.

2009-01-01T23:59:59.000Z