Sample records for dioxide emissions remain

  1. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01T23:59:59.000Z

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  2. MASTER THESIS IN AQUATIC PHOTOCHEMISTRY Sunlight-induced carbon dioxide emissions from lakes

    E-Print Network [OSTI]

    Uppsala Universitet

    MASTER THESIS IN AQUATIC PHOTOCHEMISTRY Sunlight-induced carbon dioxide emissions from lakes The emissions of carbon dioxide (CO2) from inland waters are substantial on a global scale. Yet, the fundamental question remains open which proportion of these CO2 emissions is induced by sunlight via photochemical

  3. Costs to reduce sulfur dioxide emissions

    SciTech Connect (OSTI)

    None

    1982-03-01T23:59:59.000Z

    Central to the resolution of the acid rain issue are debates about the costs and benefits of controlling man-made emissions of chemicals that may cause acid rain. In this briefing, the position of those who are calling for immediate action and implicating coal-fired powerplants as the cause of the problem is examined. The costs of controlling sulfur dioxide emissions using alternative control methods available today are presented. No attempt is made to calculate the benefits of reducing these emissions since insufficient information is available to provide even a rough estimate. Information is presented in two steps. First, costs are presented as obtained through straightforward calculations based upon simplifying but realistic assumptions. Next, the costs of sulfur dioxide control obtained through several large-scale analyses are presented, and these results are compared with those obtained through the first method.

  4. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    Year) MSA Emissions from Driving (Lbs of CO2) Electricity (CO2 per Megawatt Hrs) Carbon Dioxide Emissions Cost MSA Emissions from Driving ElectricityEmissions from Driving (Lbs of CO2) Suburb-City Difference in Electricity (

  5. Carbon Dioxide and Helium Emissions from a Reservoir of Magmatic...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Carbon Dioxide and Helium Emissions from a Reservoir of Magmatic Gas Beneath Mammoth...

  6. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    E-Print Network [OSTI]

    Hultman, Nathan E.

    PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results S.J. Smith E;PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results PNNL Research Report Joint Global Change Research Institute 8400 Baltimore Avenue College Park, Maryland 20740 #12;PNNL-14537

  7. World Energy Consumption and Carbon Dioxide Emissions: 1950 2050

    E-Print Network [OSTI]

    -U" relation with a within- sample peak between carbon dioxide emissions (and energy use) per capita and perWorld Energy Consumption and Carbon Dioxide Emissions: 1950 Ñ 2050 Richard Schmalensee, Thomas M capita income. Using the income and population growth assumptions of the Intergovernmental Panel

  8. Carbon dioxide emission during forest fires ignited by lightning

    E-Print Network [OSTI]

    Magdalena Pelc; Radoslaw Osuch

    2009-03-31T23:59:59.000Z

    In this paper we developed the model for the carbon dioxide emission from forest fire. The master equation for the spreading of the carbon dioxide to atmosphere is the hyperbolic diffusion equation. In the paper we study forest fire ignited by lightning. In that case the fores fire has the well defined front which propagates with finite velocity.

  9. GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2)

    E-Print Network [OSTI]

    Green, Donna

    GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2) from the combustion),2 China, Russia, Japan, India and Canada--accounted for more than 70 percent of energy-related CO2. Figure 1 Global Carbon Dioxide Emissions: 1850­2030 1850 1860 1870 1880 1890 1900 1910 1920 1930 1940

  10. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard

    1995-01-01T23:59:59.000Z

    Emissions of carbon dioxide form combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  11. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard.; Stoker, Thomas M.; Judson, Ruth A.

    Emissions of carbon dioxide from combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  12. Figure 3. Energy-Related Carbon Dioxide Emissions

    U.S. Energy Information Administration (EIA) Indexed Site

    3. Energy-Related Carbon Dioxide Emissions" " (million metric tons)" ,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024,2025,2026,2027,2028,...

  13. Carbon Dioxide Emissions From Vegetation-Kill Zones Around The...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Carbon Dioxide Emissions From Vegetation-Kill Zones Around The Resurgent Dome Of Long Valley...

  14. Estimated Carbon Dioxide Emissions in 2008: United States

    SciTech Connect (OSTI)

    Smith, C A; Simon, A J; Belles, R D

    2011-04-01T23:59:59.000Z

    Flow charts depicting carbon dioxide emissions in the United States have been constructed from publicly available data and estimates of state-level energy use patterns. Approximately 5,800 million metric tons of carbon dioxide were emitted throughout the United States for use in power production, residential, commercial, industrial, and transportation applications in 2008. Carbon dioxide is emitted from the use of three major energy resources: natural gas, coal, and petroleum. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states, the District of Columbia, and one national) carbon dioxide flow charts representing a comprehensive systems view of national CO{sub 2} emissions. Lawrence Livermore National Lab (LLNL) has published flow charts (also referred to as 'Sankey Diagrams') of important national commodities since the early 1970s. The most widely recognized of these charts is the U.S. energy flow chart (http://flowcharts.llnl.gov). LLNL has also published charts depicting carbon (or carbon dioxide potential) flow and water flow at the national level as well as energy, carbon, and water flows at the international, state, municipal, and organizational (i.e. United States Air Force) level. Flow charts are valuable as single-page references that contain quantitative data about resource, commodity, and byproduct flows in a graphical form that also convey structural information about the system that manages those flows. Data on carbon dioxide emissions from the energy sector are reported on a national level. Because carbon dioxide emissions are not reported for individual states, the carbon dioxide emissions are estimated using published energy use information. Data on energy use is compiled by the U.S. Department of Energy's Energy Information Administration (U.S. EIA) in the State Energy Data System (SEDS). SEDS is updated annually and reports data from 2 years prior to the year of the update. SEDS contains data on primary resource consumption, electricity generation, and energy consumption within each economic sector. Flow charts of state-level energy usage and explanations of the calculations and assumptions utilized can be found at: http://flowcharts.llnl.gov. This information is translated into carbon dioxide emissions using ratios of carbon dioxide emissions to energy use calculated from national carbon dioxide emissions and national energy use quantities for each particular sector. These statistics are reported annually in the U.S. EIA's Annual Energy Review. Data for 2008 (US. EIA, 2010) was updated in August of 2010. This is the first presentation of a comprehensive state-level package of flow charts depicting carbon dioxide emissions for the United States.

  15. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01T23:59:59.000Z

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  16. Auction design and the market for sulfur dioxide emissions

    E-Print Network [OSTI]

    Joskow, Paul L.

    1996-01-01T23:59:59.000Z

    Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

  17. Global warming and global dioxide emission: An empirical study

    SciTech Connect (OSTI)

    Linyan Sun [Xian Jiaotong Univ., Shaanxi (China); Wang, M. [Saint Mary`s Univ., Halifax, Nova Scotia (Canada)

    1996-04-01T23:59:59.000Z

    In this paper, the dynamic relationship between global surface temperature (global warming) and global carbon dioxide emission (CO{sub 2}) is modelled and analyzed by causality and spectral analysis in the time domain and frequency domain, respectively. Historical data of global CO{sub 2} emission and global surface temperature anomalies over 129 years from 1860-1988 are used in this study. The causal relationship between the two phenomena is first examined using the Sim and Granger causality test in the time domain after the data series are filtered by ARIMA models. The Granger causal relationship is further scrutinized and confirmed by cross-spectral and multichannel spectral analysis in the frequency domain. The evidence found from both analyses proves that there is a positive causal relationship between the two variables. The time domain analysis suggests that Granger causality exists between global surface temperature and global CO{sub 2} emission. Further, CO{sub 2} emission causes the change in temperature. The conclusions are further confirmed by the frequency domain analysis, which indicates that the increase in CO{sub 2} emission causes climate warming because a high coherence exists between the two variables. Furthermore, it is proved that climate changes happen after an increase in CO{sub 2} emission, which confirms that the increase in CO{sub 2} emission does cause global warming. 27 refs., 10 figs., 5 tabs.

  18. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    dioxide emissions from fossil-fuel combustion R. J. Andresdioxide emis- sions from fossil-fuel use in North America,S. : High resolution fossil fuel combustion CO 2 emission

  19. Environmental Kuznets Curve for carbon dioxide emissions: lack of robustness to heterogeneity?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Environmental Kuznets Curve for carbon dioxide emissions: lack of robustness to heterogeneity applying the iterative Bayesian shrinkage procedure. The environmental Kuznets curve (EKC) hypothesis. Keywords: Environmental Kuznets curve; Bayesian shrinkage estimator; Heterogeneity JEL classification: O13

  20. Towards constraints on fossil fuel emissions from total column carbon dioxide

    E-Print Network [OSTI]

    Keppel-Aleks, G.; Wennberg, P. O; O'Dell, C. W; Wunch, D.

    2013-01-01T23:59:59.000Z

    G. Keppel-Aleks et al. : Fossil fuel constraints from X CO 2P. P. : Assess- ment of fossil fuel carbon dioxide and otherstrong localized sources: fossil fuel power plant emissions

  1. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    dioxide impact of electricity consumption in different majorand residential electricity consumption. Car usage and homefor fuel oil and electricity consumption. We then use

  2. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01T23:59:59.000Z

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  3. Further Sensitivity Analysis of Hypothetical Policies to Limit Energy-Related Carbon Dioxide Emissions

    Reports and Publications (EIA)

    2013-01-01T23:59:59.000Z

    This analysis supplements the Annual Energy Outlook 2013 alternative cases which imposed hypothetical carbon dioxide emission fees on fossil fuel consumers. It offers further cases that examine the impacts of fees placed only on the emissions from electric power facilities, impacts of returning potential revenues to consumers, and two cap-and-trade policies.

  4. Sulfur dioxide emissions from primary nonferrous smelters in the Western United States

    SciTech Connect (OSTI)

    Mangeng, C.; Mead, R.

    1980-08-01T23:59:59.000Z

    The greatest source of sulfur dioxide emissions in the West has been the pyrometallurgical processing of copper, lead, and zinc ores. Until the early 1970s, the emissions from most nonferrous metal smelters were released without control into the environment. However, recent Federal and State legislation has mandated the need for large reductions of emissions, a task that will require the introduction of highly efficient sulfur dioxide control technology. The particular processes at each smelter, the smelter location, the capital and operating costs including the cost of energy, the resolution of currently litigated issues, and the metal market prices will be major influences on the choice of technology and on the schedule for implementation of smelter control plans. These parameters are examined, and the problems and issues associated with them are described. The future impact of smelter sulfur dioxide emissions is discussed within the framework of the relevant economic, technologial, and legal issues.

  5. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    the Path of China's CO2 Emissions Using Province LevelTransportation (Lbs of CO2) Emissions from Home Heating (LbsStandardized Household CO2 Emissions for Households Living

  6. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    with sulfuric and nitric acids formed from at- mospheric oxidations of sulfur dioxide SO2 and nitrogen oxides mobile sources comes from the combustion of sulfur compounds in fuel. The U.S. is in the process of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  7. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15T23:59:59.000Z

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  8. Producing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions

    E-Print Network [OSTI]

    effects of global warming. In this article we describe a process which producesa lowProducing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions K. Blok, C.A. Hendriks the electricity production cost by one third. The secondprovides hydrogenor a hydrogen-rich fuel gas

  9. Anthropogenic Sulfur Dioxide Emissions: 1850-2005 Supplementary Material

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    A composite time series of fossil fuels used for combustion was constructed by combining data from a number .......................................................................................................1 S.2 Composite Energy Demand .........................................................................................8 S.5 Methodological Detail: Fossil Combustion Emissions

  10. Synthetic Assessment of Historical Anthropogenic Sulfur Dioxide (SO2) Emissions

    E-Print Network [OSTI]

    activities (Smith et al., 2011) · The following 100 years emissions had rapidly increased by use of coal, and by anthropogenic sources, such as burning of coal, oil and gases. SO2 as a pollutant not only changes the climate

  11. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    fuel oil and natural gas) and electricity usage. We use databetween natural gas or petroleum usage and emissions. If wenatural gas and fuel oil) and residential electricity consumption. Car usage

  12. Short run effects of a price on carbon dioxide emissions from U.S. electric generators

    SciTech Connect (OSTI)

    Adam Newcomer; Seth A. Blumsack; Jay Apt; Lester B. Lave; M. Granger Morgan [Carnegie Mellon University, Pittsburgh, PA (United States). Carnegie Mellon Electricity Industry Center

    2008-05-01T23:59:59.000Z

    The price of delivered electricity will rise if generators have to pay for carbon dioxide emissions through an implicit or explicit mechanism. There are two main effects that a substantial price on CO{sub 2} emissions would have in the short run (before the generation fleet changes significantly). First, consumers would react to increased price by buying less, described by their price elasticity of demand. Second, a price on CO{sub 2} emissions would change the order in which existing generators are economically dispatched, depending on their carbon dioxide emissions and marginal fuel prices. Both the price increase and dispatch changes depend on the mix of generation technologies and fuels in the region available for dispatch, although the consumer response to higher prices is the dominant effect. We estimate that the instantaneous imposition of a price of $35 per metric ton on CO{sub 2} emissions would lead to a 10% reduction in CO{sub 2} emissions in PJM and MISO at a price elasticity of -0.1. Reductions in ERCOT would be about one-third as large. Thus, a price on CO{sub 2} emissions that has been shown in earlier work to stimulate investment in new generation technology also provides significant CO{sub 2} reductions before new technology is deployed at large scale. 39 refs., 4 figs., 2 tabs.

  13. Accounting for Carbon Dioxide Emissions from Biomass Energy Combustion (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01T23:59:59.000Z

    Carbon Dioxide (CO2) emissions from the combustion of biomass to produce energy are excluded from the energy-related CO2 emissions reported in Annual Energy Outlook 2010. According to current international convention, carbon released through biomass combustion is excluded from reported energy-related emissions. The release of carbon from biomass combustion is assumed to be balanced by the uptake of carbon when the feedstock is grown, resulting in zero net emissions over some period of time]. However, analysts have debated whether increased use of biomass energy may result in a decline in terrestrial carbon stocks, leading to a net positive release of carbon rather than the zero net release assumed by its exclusion from reported energy-related emissions.

  14. Development of a local carbon dioxide emissions inventory based on energy demand and waste production

    SciTech Connect (OSTI)

    Joao Gomes; Joana Nascimento; Helena Rodrigues [Instituto Superior de Engenharia de Lisboa, Lisboa (Portugal)

    2007-09-15T23:59:59.000Z

    The paper describes the study that led to the development of a carbon dioxide emissions matrix for the Oeiras municipality, one of the largest Portuguese municipalities, located in the metropolitan area of Lisbon. This matrix takes into account the greenhouse gas (GHG) emissions due to an increase of electricity demand in buildings as well as solid and liquid wastes treatment from the domestic and services sectors. Using emission factors that were calculated from the relationship between the electricity produced and amount of treated wastes, the GHC emissions in the Oeiras municipality were estimated for a time series of 6 yr (1998 - 2003). The obtained results showed that the electricity sector accounts for approximately 75% of the municipal emissions in 2003. This study was developed to obtain tools to base options and actions to be undertaken by local authorities such as energy planning and also public information. 11 refs., 12 tabs.

  15. Abstract--Historic data shows an increase in carbon dioxide (CO2) emissions at airports caused by an increase

    E-Print Network [OSTI]

    design alternatives provides reduction of CO2 emission levels such that the CO2 emissions for 2050 meet Abstract-- Historic data shows an increase in carbon dioxide (CO2) emissions at airports caused regulations at airports through reduction of CO2 for all components of flight operations. The purpose

  16. Using Vehicle Taxes to Reduce Carbon Dioxide Emissions Rates of New Passenger Vehicles: Evidence from France, Germany, and Sweden

    E-Print Network [OSTI]

    Klier, Thomas

    France, Germany, and Sweden link vehicle taxes to the carbon dioxide (CO2) emissions rates of passenger vehicles. Based on new vehicle registration data from 2005–2010, a vehicle’s tax is negatively correlated with its ...

  17. Inventory of Carbon Dioxide (CO2) Emissions at Pacific Northwest National Laboratory

    SciTech Connect (OSTI)

    Judd, Kathleen S.; Kora, Angela R.; Shankle, Steve A.; Fowler, Kimberly M.

    2009-06-29T23:59:59.000Z

    The Carbon Management Strategic Initiative (CMSI) is a lab-wide initiative to position the Pacific Northwest National Laboratory (PNNL) as a leader in science, technology and policy analysis required to understand, mitigate and adapt to global climate change as a nation. As part of an effort to walk the talk in the field of carbon management, PNNL conducted its first carbon dioxide (CO2) emissions inventory for the 2007 calendar year. The goal of this preliminary inventory is to provide PNNL staff and management with a sense for the relative impact different activities at PNNL have on the lab’s total carbon footprint.

  18. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P.

    2012-11-13T23:59:59.000Z

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  19. Carbon dioxide emission index as a mean for assessing fuel quality

    SciTech Connect (OSTI)

    Furimsky, E. [IMAF Group, Ottawa, ON (Canada)

    2008-07-01T23:59:59.000Z

    Carbon dioxide emission index, defined as the amount of CO{sub 2} released per unit of energy value, was used to rate gaseous, liquid and solid fuels. The direct utilization of natural gas is the most efficient option. The conversion of natural gas to synthesis gas for production of liquid fuels represents a significant decrease in fuel value of the former. The fuel value of liquids, such as gasoline, diesel oil, etc. is lower than that of natural gas. Blending gasoline with ethanol obtained either from bio-mass or via synthesis may decrease fuel value of the blend when CO{sub 2} emissions produced during the production of ethanol are included in total emissions. The introduction of liquid fuels produced by pyrolysis and liquefaction of biomass would result in the increase in the CO{sub 2} emissions. The CO{sub 2} emissions from the utilization of coal and petroleum coke are much higher than those from gaseous and liquid fuels. However, for petroleum coke, this is offset by the high value gaseous and liquid fuels that are simultaneously produced during coking. Conversion of low value fuels such as coal and petroleum coke to a high value chemicals via synthesis gas should be assessed as means for replacing natural gas and making it available for fuel applications.

  20. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P

    2012-09-18T23:59:59.000Z

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  1. Measuring Sulphur Dioxide (SO2) Emissions in October, 2010 Catastrophic Eruption from Merapi Volcano in Java, Indonesia

    E-Print Network [OSTI]

    Gilbes, Fernando

    Volcano in Java, Indonesia with Ozone Monitoring Instrument (OMI) José A. Morales-Collazo Geology This paper discusses sulfur dioxide (SO2) cloud emissions from Merapi Volcano in Java, Indonesia during, Indonesia. In October 26th , 2010, a catastrophic eruption was reported from Merapi causing nearly 386

  2. Estimating carbon dioxide emission factors for the California electric power sector

    SciTech Connect (OSTI)

    Marnay, Chris; Fisher, Diane; Murtishaw, Scott; Phadke, Amol; Price, Lynn; Sathaye, Jayant

    2002-08-01T23:59:59.000Z

    The California Climate Action Registry (''Registry'') was initially established in 2000 under Senate Bill 1771, and clarifying legislation (Senate Bill 527) was passed in September 2001. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) has been asked to provide technical assistance to the California Energy Commission (CEC) in establishing methods for calculating average and marginal electricity emissions factors, both historic and current, as well as statewide and for sub-regions. This study is exploratory in nature. It illustrates the use of three possible approaches and is not a rigorous estimation of actual emissions factors. While the Registry will ultimately cover emissions of all greenhouse gases (GHGs), presently it is focusing on carbon dioxide (CO2). Thus, this study only considers CO2, which is by far the largest GHG emitted in the power sector. Associating CO2 emissions with electricity consumption encounters three major complications. First, electricity can be generated from a number of different primary energy sources, many of which are large sources of CO2 emissions (e.g., coal combustion) while others result in virtually no CO{sub 2} emissions (e.g., hydro). Second, the mix of generation resources used to meet loads may vary at different times of day or in different seasons. Third, electrical energy is transported over long distances by complex transmission and distribution systems, so the generation sources related to electricity usage can be difficult to trace and may occur far from the jurisdiction in which that energy is consumed. In other words, the emissions resulting from electricity consumption vary considerably depending on when and where it is used since this affects the generation sources providing the power. There is no practical way to identify where or how all the electricity used by a certain customer was generated, but by reviewing public sources of data the total emission burden of a customer's electricity supplier can b e found and an average emissions factor (AEF) calculated. These are useful for assigning a net emission burden to a facility. In addition, marginal emissions factors (MEFs) for estimating the effect of changing levels of usage can be calculated. MEFs are needed because emission rates at the margin are likely to diverge from the average. The overall objective of this task is to develop methods for estimating AEFs and MEFs that can provide an estimate of the combined net CO2 emissions from all generating facilities that provide electricity to California electricity customers. The method covers the historic period from 1990 to the present, with 1990 and 1999 used as test years. The factors derived take into account the location and time of consumption, direct contracts for power which may have certain atypical characteristics (e.g., ''green'' electricity from renewable resources), resource mixes of electricity providers, import and export of electricity from utility owned and other sources, and electricity from cogeneration. It is assumed that the factors developed in this way will diverge considerably from simple statewide AEF estimates based on standardized inventory estimates that use conventions inconsistent with the goals of this work. A notable example concerns the treatment of imports, which despite providing a significant share of California's electricity supply picture, are excluded from inventory estimates of emissions, which are based on geographical boundaries of the state.

  3. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    independent budgeting of fossil fuel CO 2 over Europe by (CO2008), Where do fossil fuel carbon dioxide emissions from2004), Estimates of annual fossil-fuel CO 2 emitted for each

  4. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    independent budgeting of fossil fuel CO 2 over Europe by (CO2008 Where do fossil fuel carbon dioxide emissions frompatterns and mixing of fossil fuel-derived CO 2 is important

  5. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01T23:59:59.000Z

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  6. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01T23:59:59.000Z

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  7. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    7 Subsectoral CO2 Emissions at the National7 Subsectoral CO2 Emissions at the ProvincialResults Subsectoral CO2 Emissions at the National Level In

  8. ASSESSING CARBON DIOXIDE EMISSIONS FROM U.S. LARGE CITIES Risa Patarasuk1, Darragh O'Keeffe1, Yang Song1, Igor Razlivano1, Kevin R. Gurney1, and Preeti Rao2

    E-Print Network [OSTI]

    Hall, Sharon J.

    ASSESSING CARBON DIOXIDE EMISSIONS FROM U.S. LARGE CITIES Risa Patarasuk1, Darragh O'Keeffe1, Yang University, 2Jet Propulsion Laboratory Introduction Carbon dioxide (CO2) emissions, a primary greenhouse gas emissions from natural gas, coal, and petroleum sources. We use a `bottom-up' approach in which CO2

  9. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    emissions from fossil-fuel combustion R. J. Andres 1 , T. A.resolution fossil fuel combustion CO 2 emission fluxes forCO 2 emissions from fuel combustion, 2010 edition, OECD/IEA,

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    from Fuel Combustion in 2004.. 34Emissions from Fuel Combustion in California, Million MetricEmission Estimates from the Combustion of Fossil Fuels in

  11. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    U.S. EPA), 2005.. Emission Inventory Improvement Program,National Greenhouse Gas Inventories, Annex 8A.2: Reportingin the fossil CO 2 emissions inventories, and verify whether

  12. A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission

    SciTech Connect (OSTI)

    Fang, Zhigang Zak [University of Utah] [University of Utah

    2013-11-05T23:59:59.000Z

    The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO{sub 2} emission from the production of titanium dioxide (TiO{sub 2}) pigment. TiO{sub 2} is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO{sub 2} pigment is currently produced primarily by the use of the so called ?chloride process?. A key step of the chloride process relies on high temperature carbo-chlorination of TiO{sub 2} bearing raw materials, hence producing large quantities of CO{sub 2}. The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO{sub 2} from high-TiO{sub 2} slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO{sub 2} produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology. These objectives were successfully met and a new process for producing commercial quality TiO{sub 2} pigment was developed and experimentally validated. The process features a unique combination of established metallurgical processes, including alkaline roasting of titania slag followed by leaching, solvent extraction, hydrolysis, and calcination. The caustic, acidic, and organic streams in the process will also be regenerated and reused in the process, greatly reducing environmental waste. The purpose and effect of each of these steps in producing purified TiO{sub 2} is detailed in the report. The levels of impurities in our pigment meet the requirements for commercial pigment, and are nearly equivalent to those of two commercial pigments. Solvent extraction with an amine extractant proved to be extremely effective in achieving these targets. A model plant producing 100,000 tons TiO{sub 2} per year was designed that would employ the new method of pigment manufacture. A flow sheet was developed and a mass and energy balance was performed. A comparison of the new process and the chloride process indicate that implementation of the new process in the US would result in a 21% decrease in energy consumption, an annual energy savings of 42.7 million GJ. The new process would reduce CO{sub 2} emissions by 21% in comparison to the chloride process, an annual reduction of 2.70 million tons of CO{sub 2}. Since the process equipment employed in the new process is well established in other industrial processes and the raw materials for the two processes are identical we believe the capital, labor and materials cost of production of pigment grade TiO{sub 2} using the new method would be at least equivalent to that of the chloride process. Additionally, it is likely that the operating costs will be lower by using the new process because of the reduced energy consumption. Although the new process technology is logical and feasible based on its chemistry, thermodynamic principles, and experimental results, its development and refinement through more rigorous and comprehensive research at the kilogram scale is needed to establish it as a competitive industrial process. The effect of the recycling of process streams on the final product quality should also be investigated. Further development would also help determine if the energy efficiency and the environmental benefits of the new process are indeed significantly better than current commercial methods of pigment manufacture.

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    CHP) ** Uncertainties with hydrogen production are not estimated ***includes emissions from other sectors such as other industry, residential,CHP) ** Uncertainties with hydrogen production are not estimated ***ncludes emissions from other sectors such as other industry, residential,

  14. EIA - AEO2013 Early Release Energy-Related Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    Energy-Related CO2 Emissions Total U.S. energy-related CO2 emissions do not return to their 2005 level (5,997 million metric tons) by the end of the AEO2013 projection period.6...

  15. Sulfur Dioxide Regulations (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

  16. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  17. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13T23:59:59.000Z

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  18. Comparison of two U.S. power-plant carbon dioxide emissions data sets

    SciTech Connect (OSTI)

    Katherine V. Ackerman; Eric T. Sundquist [U.S. Geological Survey, Woods Hole, MA (United States)

    2008-08-15T23:59:59.000Z

    Estimates of fossil-fuel CO{sub 2} emissions are needed to address a variety of climate-change mitigation concerns over a broad range of spatial and temporal scales. We compared two data sets that report power-plant CO{sub 2} emissions in the conterminous U.S. for 2004, the most recent year reported in both data sets. The data sets were obtained from the Department of Energy's Energy Information Administration (EIA) and the Environmental Protection Agency's eGRID database. Conterminous U.S. total emissions computed from the data sets differed by 3.5% for total plant emissions (electricity plus useful thermal output) and 2.3% for electricity generation only. These differences are well within previous estimates of uncertainty in annual U.S. fossil-fuel emissions. However, the corresponding average absolute differences between estimates of emissions from individual power plants were much larger, 16.9% and 25.3%, respectively. By statistical analysis, we identified several potential sources of differences between EIA and eGRID estimates for individual plants. Estimates that are based partly or entirely on monitoring of stack gases (reported by eGRID only) differed significantly from estimates based on fuel consumption (as reported by EIA). Differences in accounting methods appear to explain differences in estimates for emissions from electricity generation from combined heat and power plants, and for total and electricity generation emissions from plants that burn nonconventional fuels (e.g., biomass). Our analysis suggests the need for care in utilizing emissions data from individual power plants, and the need for transparency in documenting the accounting and monitoring methods used to estimate emissions. 19 refs., 2 figs., 2 tabs.

  19. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    International Energy Agency (OECD/IEA): CO 2 emissions fromcombustion, 2010 edition, OECD/IEA, Paris, 2010. Kashiwagi,data are generated by the IEA and are a no- table feature of

  20. EIA - AEO2012 Early Release Energy-Related Carbon Dioxide Emissions

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    of the CSAPR, which helps shift the fuel mix away from coal toward lower carbon fuels. Energy-related CO2 emissions reflect the mix of fossil fuels consumed. Given the high...

  1. Analysis and optimization of the Graz cycle : a coal fired power generation scheme with near-zero carbon dioxide emissions

    E-Print Network [OSTI]

    Alexander, Brentan R

    2007-01-01T23:59:59.000Z

    Humans are releasing record amounts of carbon dioxide into the atmosphere through the combustion of fossil fuels in power generation plants. With mounting evidence that this carbon dioxide is a leading cause of global ...

  2. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  3. Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01T23:59:59.000Z

    sulfur dioxide smelting reduction smelting reduction iron three-dimensional tonne top-gas recycling blast furnace tonnes per day ultra-low-

  4. Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01T23:59:59.000Z

    clean CO 2 for storage and a hydrogen stream to be recycledand storage ? Flexibility to make CO 2 -free hydrogen forand storage computational fluid dynamics carbon monoxide carbon dioxide direct reduced iron electric arc furnace gram gigajoules hour diatomic hydrogen

  5. CARBON DIOXIDE EMISSION REDUCTION

    E-Print Network [OSTI]

    Delaware, University of

    ........................................................................................... 3 2.3 Energy Efficiency Technologies and Measures with gas turbine at Cascades Inc. ............................................... 34 3.5 Boiler blowdown Efficiency Technologies and Measures in Steel Industry .......................5 Table 2.3 Energy Efficiency

  6. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    Over the past decade increasing concern over the potential environmental impact associated with the emissions of both gaseous and particulate pollutants has resulted in the promulgation of strict regulatory standards governing such emissions...

  7. Contraction & Convergence: UK carbon emissions and the

    E-Print Network [OSTI]

    Watson, Andrew

    the EU's emissions trading scheme will do little to mitigate carbon emissions 4) Aviation growth must emissions. Keywords Contraction & Convergence; aviation; emissions trading; passengers; carbon dioxide #12

  8. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton [National Council of the Paper Industry for Air and Stream Improvement Inc., Research Triangle Park, NC (United States). Air Quality Program

    2007-08-15T23:59:59.000Z

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  9. Effects of ozone exposure on 'Golden' papaya fruit by photoacoustic phase-resolved method: Physiological changes associated with carbon dioxide and ethylene emission rates during ripening

    SciTech Connect (OSTI)

    Correa, Savio Figueira; Brito Paiva, Luisa; Mota do Couto, Flavio; Gomes da Silva, Marcelo; Silva Sthel, Marcelo; Vargas, Helion [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Mota, Leonardo [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Fraunhofer Institut fuer Bauphysik, Nobelstrasse 12, Vaihingen 70569, Stuttgart, Baden Wuerttemberg (Germany); Goncalves de Oliveira, Jurandi [Laboratorio de Melhoramento Genetico Vegetal, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Miklos, Andras [Fraunhofer Institut fuer Bauphysik, Nobelstrasse 12, Vaihingen 70569, Stuttgart, Baden Wuerttemberg (Germany)

    2011-06-01T23:59:59.000Z

    This work addresses the effects of ozone activity on the physiology of 'Golden' papaya fruit. Depth profile analysis of double-layer biological samples was accomplished using the phase-resolved photoacoustic spectroscopy. The feasibility of the method was demonstrated by singling out the spectra of the cuticle and the pigment layers of papaya fruit. The same approach was used to monitor changes occurring on the fruit during ripening when exposed to ozone. In addition, one has performed real time studies of fluorescence parameters and the emission rates of carbon dioxide and ethylene. Finally, the amount of pigments and the changes in waxy cuticle have been monitored. Results indicate that a fruit deliberately subjected to ozone at a level of 6 ppmv underwent ripening sooner (at least 24-48 h) than a fruit stored at ambient conditions. Moreover, ozone caused a reduction in the maximum quantum yield of photosynthetic apparatus located within the skin of papaya fruit.

  10. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, K.G.

    1990-02-20T23:59:59.000Z

    A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  11. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, Kenneth G. (Charleston, WV)

    1990-01-01T23:59:59.000Z

    A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  12. New methodology for estimating biofuel consumption for cooking: Atmospheric emissions of black carbon and sulfur dioxide from India

    E-Print Network [OSTI]

    Dickerson, Russell R.

    New methodology for estimating biofuel consumption for cooking: Atmospheric emissions of black; accepted 8 June 2004; published 30 July 2004. [1] The dominance of biofuel combustion emissions in the Indian region, and the inherently large uncertainty in biofuel use estimates based on cooking energy

  13. Non-linear response of carbon dioxide and methane emissions to oxygen availability in a drained histosol

    E-Print Network [OSTI]

    McNicol, Gavin; Silver, Whendee L

    2015-01-01T23:59:59.000Z

    emissions to oxygen availability in a drained HistosolIncreased O 2 availability from wetland drainage and climateunder greater O 2 availability. We varied gas-phase O 2

  14. The evolution of carbon dioxide emissions from energy use in industrialized countries: an end-use analysis

    SciTech Connect (OSTI)

    Schipper, L.; Ting, M.; Khrushch, M.; Unander, F.; Monahan, P.; Golove, W.

    1996-08-01T23:59:59.000Z

    There has been much attention drawn to plans for reductions or restraint in future C02 emissions, yet little analysis of the recent history of those emissions by end use or economic activity. Understanding the components of C02 emissions, particularly those related to combustion of fossil fuels, is important for judging the likely success of plans for dealing with future emissions. Knowing how fuel switching, changes in economic activity and its structure, or changes in energy-use efficiency affected emissions in the past, we can better judge both the realism of national proposals to restrain future emissions and the outcome as well. This study presents a first step in that analysis. The organization of this paper is as follows. We present a brief background and summarize previous work analyzing changes in energy use using the factorial method. We then describe our data sources and method. We then present a series of summary results, including a comparison of C02 emissions in 1991 by end use or sector. We show both aggregate change and change broken down by factor, highlighting briefly the main components of change. We then present detailed results, sector by sector. Next we highlight recent trends. Finally, we integrate our results, discussing -the most important factors driving change - evolution in economic structure, changes in energy intensities, and shifts in the fuel mix. We discuss briefly some of the likely causes of these changes - long- term technological changes, effects of rising incomes, the impact of overall changes in energy prices, as well as changes in the relative prices of energy forms.

  15. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet [Carnegie Institution for Science, Stanford, CA; Michalak, Anna M. [Carnegie Institution for Science, Stanford, CA; van Bloemen Waanders, Bart Gustaaf [Sandia National Laboratories, Albuquerque, NM; McKenna, Sean Andrew [IBM Research, Mulhuddart, Dublin 15, Ireland

    2013-04-01T23:59:59.000Z

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  16. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18T23:59:59.000Z

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  17. Personal revised version of: Howitt et al. (2011), Carbon dioxide emissions from international air freight. Paper to appear in

    E-Print Network [OSTI]

    Otago, University of

    2011-01-01T23:59:59.000Z

    presents a methodology to calculate the amount of fuel burnt and the resulting CO2 emissions from New calculated. The total amount of fuel consumed for the international air transport of New Zealand's imports to other nations and/or regions. Using data on fuel uplift, air freight and air craft movements

  18. PHYSICAL REVIEW E 87, 012814 (2013) Carbon-dioxide emissions trading and hierarchical structure in worldwide finance

    E-Print Network [OSTI]

    Stanley, H. Eugene

    2013-01-01T23:59:59.000Z

    , the nature of relationships between financial entities is becoming an increasingly important area of study of the stock market indicators and those of the EU CO2 emission allowance (EUA) and crude oil futures (WTI and of crude oil in the near future. DOI: 10.1103/PhysRevE.87.012814 PACS number(s): 89.65.Gh, 05.45.Tp, 89

  19. become more important as countries agree to emission reduction targets

    E-Print Network [OSTI]

    Constable, Steve

    : immediate stabilization of carbon dioxide emissions, regulation of air pollution that balances removal

  20. Estimated monthly emissions of sulfur dioxide, oxides of nitrogen, and volatile organic compounds for the 48 contiguous states, 1985-1986: Volume 2, Sectoral emissions by month for states

    SciTech Connect (OSTI)

    Kohout, E.J.; Knudson, D.A.; Saricks, C.L.; Miller, D.J.

    1987-11-01T23:59:59.000Z

    A listing by source of sulfur dioxide, nitrogen oxides and volatile organic compounds emitted in 48 states of the US is provided. (CBS)

  1. Emissions Trading, Electricity Industry Restructuring, and Investment in Pollution Abatement

    E-Print Network [OSTI]

    Fowlie, Meredith

    2005-01-01T23:59:59.000Z

    Foss, B . "Carbon Emissions Trading is New Weapon to BattleBehavior and the Emission Trading Market, Resources andof Sulfur Dioxide Emissions Trading." The Journal of

  2. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127byForms What'sAnnual2 EIA372.

  3. Associations of health, physical activity and weight status with motorised travel and transport carbon dioxide emissions: a cross-sectional, observational study

    E-Print Network [OSTI]

    Goodman, Anna; Brand, Christian; Ogilvie, David; on behalf of the iConnect consortium

    2012-08-03T23:59:59.000Z

    (petrol ICE, diesel ICE, LPG ICE, petrol HEV), engine size (2 litres) and vehicle age. The ‘most used vehicle’ reported by the participants was taken as the reference vehicle for the emissions analysis. Where one or more... fleet average of petrol and diesel car emissions factors. Multiplying total distance travelled by these speed-emissions factors gave us an estimate of the total ‘hot’ emissions for each vehicle when the engine was warmed up. As a final adjustment...

  4. Decoding Titanium Dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Decoding Titanium Dioxide Decoding Titanium Dioxide Released: December 03, 2010 Scientists advance understanding of remarkable catalyst STM images of 1-, 2-, 3-, and 4-octoxy...

  5. Motivating carbon dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Motivating carbon dioxide Motivating carbon dioxide Released: April 17, 2013 Scientists show what it takes to get the potential fuel feedstock to a reactive spot on a model...

  6. The use of onboard diagnostics to reduce emissions in automobiles

    E-Print Network [OSTI]

    Perez, Alberto, Jr

    2009-01-01T23:59:59.000Z

    The emissions from automobiles are very harmful and include gases such as Carbon Dioxide, Nitrous Oxide, and Sulfur Dioxide. One of the main reasons OBD was created was to control emissions however it currently only monitors ...

  7. The Net Environmental Effects of Carbon Dioxide Reduction Policies

    E-Print Network [OSTI]

    of policy measures have been proposed to reduce the emissions of carbon dioxide (CO2). However, policies which reduce CO2 emissions will also decrease the emissions of greenhouse-relevant gases methane are overlooked the net effect of CO2 reduction policies on global warming is understated. Thus, emissions of all

  8. Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions

    E-Print Network [OSTI]

    Millstein, Dev

    2009-01-01T23:59:59.000Z

    2005). Particulate emissions from construction activities.M. S. , (2000b). In-use emissions from heavy- duty dieseland nitrogen dioxide emissions from gasoline- and diesel-

  9. Evaluating the Effects of Organic Amendment Applications on Nitrous Oxide Emissions From Salt-Affected Soils

    E-Print Network [OSTI]

    Pulla Reddy Gari, Namratha

    2013-01-01T23:59:59.000Z

    Effect of Soil Properties on Carbon Dioxide and Nitrous110 Effect of Soil Properties on Carbon Dioxide and Nitrousproperties have been well studied, their effects on greenhouse gas emissions such as carbon dioxide (

  10. Nitrogen dioxide detection

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

    1993-01-01T23:59:59.000Z

    Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

  11. Scaling up carbon dioxide capture and storage: From megatons to gigatons Howard J. Herzog

    E-Print Network [OSTI]

    Global warming Carbon mitigation Low carbon energy technologies Carbon dioxide capture and storage (CCS) Carbon dioxide (CO2) capture and storage (CCS) is the only technology that can reduce CO2 emissionsScaling up carbon dioxide capture and storage: From megatons to gigatons Howard J. Herzog MIT

  12. Scaling up carbon dioxide capture and storage: From megatons to gigatons Howard J. Herzog

    E-Print Network [OSTI]

    warming Carbon mitigation Low carbon energy technologies Carbon dioxide capture and storage (CCS) CarbonScaling up carbon dioxide capture and storage: From megatons to gigatons Howard J. Herzog MIT dioxide (CO2) capture and storage (CCS) is the only technology that can reduce CO2 emissions substantially

  13. Carbon dioxide dissolution in structural and stratigraphic traps

    E-Print Network [OSTI]

    Hesse, M. A.

    The geologic sequestration of carbon dioxide (CO[subscript 2]) in structural and stratigraphic traps is a viable option to reduce anthropogenic emissions. While dissolution of the CO[subscript 2] stored in these traps ...

  14. NMR studies of carbon dioxide sequestration in porous media

    E-Print Network [OSTI]

    Hussain, Rehan

    2015-06-09T23:59:59.000Z

    Carbon dioxide (CO2) sequestration in the sub-surface is a potential mitigation technique for global climate change caused by greenhouse gas emissions. In order to evaluate the feasibility of this technique, understanding the behaviour of CO2 stored...

  15. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in West Virginia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in West Virginia. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in West Virginia to be $1.0 billion, annual CO2 reductions are estimated at 3.3 million tons, and annual water savings are 1,763 million gallons.

  16. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Pennsylvania (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Pennsylvania. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Pennsylvania to be $1.2 billion, annual CO2 reductions are estimated at 3.4 million tons, and annual water savings are 1,837 million gallons.

  17. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    SciTech Connect (OSTI)

    Riley, W.J.; Hsueh, D.Y.; Randerson, J.T.; Fischer, M.L.; Hatch, J.G.; Pataki, D.E.; Wang, W.; Goulden, M.L.

    2008-05-01T23:59:59.000Z

    Characterizing flow patterns and mixing of fossil fuel-derived CO{sub 2} is important for effectively using atmospheric measurements to constrain emissions inventories. Here we used measurements and a model of atmospheric radiocarbon ({sup 14}C) to investigate the distribution and fluxes of atmospheric fossil fuel CO{sub 2} across the state of California. We sampled {sup 14}C in annual C{sub 3} grasses at 128 sites and used these measurements to test a regional model that simulated anthropogenic and ecosystem CO{sub 2} fluxes, transport in the atmosphere, and the resulting {sup 14}C of annual grasses ({Delta}{sub g}). Average measured {Delta}{sub g} in Los Angeles, San Francisco, the Central Valley, and the North Coast were 27.7 {+-} 20.0, 44.0 {+-} 10.9, 48.7 {+-} 1.9, and 59.9 {+-} 2.5{per_thousand}, respectively, during the 2004-2005 growing season. Model predictions reproduced regional patterns reasonably well, with estimates of 27.6 {+-} 2.4, 39.4 {+-} 3.9, 46.8 {+-} 3.0, and 59.3 {+-} 0.2{per_thousand} for these same regions and corresponding to fossil fuel CO{sub 2} mixing ratios (Cf) of 13.7, 6.1, 4.8, and 0.3 ppm. {Delta}{sub g} spatial heterogeneity in Los Angeles and San Francisco was higher in the measurements than in the predictions, probably from insufficient spatial resolution in the fossil fuel inventories (e.g., freeways are not explicitly included) and transport (e.g., within valleys). We used the model to predict monthly and annual transport patterns of fossil fuel-derived CO{sub 2} within and out of California. Fossil fuel CO{sub 2} emitted in Los Angeles and San Francisco was predicted to move into the Central Valley, raising Cf above that expected from local emissions alone. Annually, about 21, 39, 35, and 5% of fossil fuel emissions leave the California airspace to the north, east, south, and west, respectively, with large seasonal variations in the proportions. Positive correlations between westward fluxes and Santa Ana wind conditions were observed. The southward fluxes over the Pacific Ocean were maintained in a relatively coherent flow within the marine boundary layer, while the eastward fluxes were more vertically dispersed. Our results indicate that state and continental scale atmospheric inversions need to consider areas where concentration measurements are sparse (e.g., over the ocean to the south and west of California), transport within and across the marine boundary layer, and terrestrial boundary layer dynamics. Measurements of {Delta}{sub g} can be very useful in constraining these estimates.

  18. Geochemistry of silicate-rich rocks can curtail spreading of carbon dioxide in subsurface aquifers

    E-Print Network [OSTI]

    Cardoso, S. S. S.; Andres, J. T. H.

    2014-12-11T23:59:59.000Z

    of carbon sequestration and dissolution rates in the subsurface, suggesting that pooled carbon dioxide may remain in the shallower regions of the formation for hundreds to thousands of years. The deeper regions of the reservoir can remain virtually carbon... interests. References 1. Marini, L. Geochemical Sequestration of Carbon Dioxide. (Elsevier 2007). 2. IPCC Special Report on Carbon Dioxide Capture and Storage, edited by Metz B. et al. (Cambridge University Press, UK and New York, USA, 2005). 3. Falkowski...

  19. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    dioxide (CO2) emissions from fossil fuel combustion, as wellCO2 emissions (including cement process and fossil fuel combustion

  20. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Agency (IEA), 2004c. CO2 emissions from fuel combustion,of Carbon Dioxide Emissions on GNP Growth: Interpretation ofD. , 2000. Special Report on Emissions Scenarios: Report of

  1. II. Greenhouse gas markets, carbon dioxide credits and biofuels17

    E-Print Network [OSTI]

    15 II. Greenhouse gas markets, carbon dioxide credits and biofuels17 The previous chapter analysed biofuels production. GHG policies18 that create a carbon price either through an emissions trading system or directly by taxing GHG emissions also generate increased demand for biofuels. They do so by raising

  2. Sandia National Laboratories: reducing carbon dioxide emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurements of Thermal Stratification in a Homogenous Charge Compression Ignition Engine On February 27, 2013, in CRF, Energy, Facilities, News, News & Events, Partnership,...

  3. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18T23:59:59.000Z

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  4. Armament remains from His Majesty's sloop Boscawen

    E-Print Network [OSTI]

    Carter, Brinnen Stiles

    1995-01-01T23:59:59.000Z

    His Majesty's Sloop Boscawen was built on Lake Champlain by British forces in 1759 as part of their successful campaign to drive the French Army from the Champlain Valley. This thesis describes and analyzes the armament remains found in and around...

  5. Coal remains a hot commodity for Australia

    SciTech Connect (OSTI)

    Bram, L.

    2006-02-15T23:59:59.000Z

    Based largely on analyses by the Australian Bureau of Agricultural and Resource Economics in late 2005 and early 2006, the article looks at the recent and near future export market for Australian coal. Demand in Asia is growing; European demand remains steady. Developments existing and new mines in Queensland are summarised in the article. 3 tabs.

  6. Emissions Benefits of Distributed Generation in the Texas Market

    SciTech Connect (OSTI)

    Hadley, SW

    2005-06-16T23:59:59.000Z

    One potential benefit of distributed generation (DG) is a net reduction in air emissions. While DG will produce emissions, most notably carbon dioxide and nitrogen oxides, the power it displaces might have produced more. This study used a system dispatch model developed at Oak Ridge National Laboratory to simulate the 2012 Texas power market with and without DG. This study compares the reduction in system emissions to the emissions from the DG to determine the net savings. Some of the major findings are that 85% of the electricity displaced by DG during peak hours will be simple cycle natural gas, either steam or combustion turbine. Even with DG running as baseload, 57% of electricity displaced will be simple cycle natural gas. Despite the retirement of some gas-fired steam units and the construction of many new gas turbine and combined cycle units, the marginal emissions from the system remain quite high (1.4 lb NO{sub x}/MWh on peak and 1.1 lb NO{sub x}/MWh baseload) compared to projected DG emissions. Consequently, additions of DG capacity will reduce emissions in Texas from power generation in 2012. Using the DG exhaust heat for combined heat and power provides an even greater benefit, since it eliminates further boiler emissions while adding none over what would be produced while generating electricity. Further studies are warranted concerning the robustness of the result with changes in fuel prices, demands, and mixes of power generating technology.

  7. 1 Spreading and convective dissolution of carbon dioxide in vertically 2 confined, horizontal aquifers

    E-Print Network [OSTI]

    Neufeld, Jerome A.

    1 Spreading and convective dissolution of carbon dioxide in vertically 2 confined, horizontal] Injection of carbon dioxide (CO2) into saline aquifers is a promising tool for reducing 6 anthropogenic CO2 emissions. At reservoir conditions, the injected CO2 is buoyant relative 7 to the ambient groundwater

  8. Spreading and convective dissolution of carbon dioxide in vertically confined, horizontal aquifers

    E-Print Network [OSTI]

    Huppert, Herbert

    Spreading and convective dissolution of carbon dioxide in vertically confined, horizontal aquifers of carbon dioxide (CO2) into saline aquifers is a promising tool for reducing anthropogenic CO2 emissions. At reservoir conditions, the injected CO2 is buoyant relative to the ambient groundwater. The buoyant plume

  9. Economic Evaluation of Leading Technology Options for Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    1 Economic Evaluation of Leading Technology Options for Sequestration of Carbon Dioxide by Jérémy, which releases nearly six billion tons of carbon per year into the atmosphere. These fuels will continue development. Since power plants are the largest point sources of CO2 emissions, capturing the carbon dioxide

  10. Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao

    E-Print Network [OSTI]

    Barthelat, Francois

    Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao promising carbon uptake results and is a viable option for carbonation curing. Carbon sequestration increase in Carbon dioxide (CO2) emissions over the past five decades, specific ways to reduce

  11. Project Profile: Direct Supercritical Carbon Dioxide Receiver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Supercritical Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The...

  12. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide:...

  13. Explaining low sulfur dioxide allowance prices : the effect of expectation errors and irreversibility

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    1998-01-01T23:59:59.000Z

    The low price of allowances has been a frequently noted featured of the implementation of the sulfur dioxide emissions market of the U.S. Acid Rain Program. This paper presents theoretical and numerical analyses that explain ...

  14. Solar-thermal hybridization of Advanced Zero Emissions Power Plants

    E-Print Network [OSTI]

    El Khaja, Ragheb Mohamad Fawaz

    2012-01-01T23:59:59.000Z

    Carbon Dioxide emissions from power production are believed to have significant contributions to the greenhouse effect and global warming. Alternative energy resources, such as solar radiation, may help abate emissions but ...

  15. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  16. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01T23:59:59.000Z

    carbon dioxide (NEU-CO2) emissions, represent a signi?cantSimply described, NEU-CO2 emissions are generated via twoData permitting, NEU-CO2 emissions arising from energy

  17. The temporal efficiency of SO? emissions trading

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2002-01-01T23:59:59.000Z

    This paper provides an empirical evaluation of the temporal efficiency of the U.S. Acid Rain Program, which implemented a nationwide market for trading and banking sulfur dioxide (SO2) emission allowances. We first develop ...

  18. Apparatus and method for removing solvent from carbon dioxide in resin recycling system

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06T23:59:59.000Z

    A two-step resin recycling system and method solvent that produces essentially contaminant-free synthetic resin material. The system and method includes one or more solvent wash vessels to expose resin particles to a solvent, the solvent contacting the resin particles in the one or more solvent wash vessels to substantially remove contaminants on the resin particles. A separator is provided to separate the solvent from the resin particles after removal from the one or more solvent wash vessels. The resin particles are next exposed to carbon dioxide in a closed loop carbon dioxide system. The closed loop system includes a carbon dioxide vessel where the carbon dioxide is exposed to the resin, substantially removing any residual solvent remaining on the resin particles after separation. A separation vessel is also provided to separate the solvent from the solvent laden carbon dioxide. Both the carbon dioxide and the solvent are reused after separation in the separation vessel.

  19. CARBON DIOXIDE FIXATION.

    SciTech Connect (OSTI)

    FUJITA,E.

    2000-01-12T23:59:59.000Z

    Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

  20. Capture of carbon dioxide by hybrid sorption

    SciTech Connect (OSTI)

    Srinivasachar, Srivats

    2014-09-23T23:59:59.000Z

    A composition, process and system for capturing carbon dioxide from a combustion gas stream. The composition has a particulate porous support medium that has a high volume of pores, an alkaline component distributed within the pores and on the surface of the support medium, and water adsorbed on the alkaline component, wherein the proportion of water in the composition is between about 5% and about 35% by weight of the composition. The process and system contemplates contacting the sorbent and the flowing gas stream together at a temperature and for a time such that some water remains adsorbed in the alkaline component when the contact of the sorbent with the flowing gas ceases.

  1. What's Next for Vanadium Dioxide?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory (ORNL) has made an important advancement in understanding a classic transition-metal oxide, vanadium dioxide, by quantifying the thermodynamic forces driving...

  2. Carbon Dioxide Reduction Through Urban Forestry

    E-Print Network [OSTI]

    Standiford, Richard B.

    . Retrieval Terms: urban forestry, carbon dioxide, sequestration, avoided energy The Authors E. Gregory McCarbon Dioxide Reduction Through Urban Forestry: Guidelines for Professional and Volunteer Tree; Simpson, James R. 1999. Carbon dioxide reduction through urban forestry

  3. Process for sequestering carbon dioxide and sulfur dioxide

    DOE Patents [OSTI]

    Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

    2009-10-20T23:59:59.000Z

    A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

  4. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  5. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one...

  6. Modeling of shippingModeling of shipping NONOxx emissions in globalemissions in global GeertGeert VinkenVinken11,, FolkertFolkert BoersmaBoersma22, and Daniel J. Jacob, and Daniel J. Jacob33

    E-Print Network [OSTI]

    Haak, Hein

    ) emissions 5-7% of global sulfur dioxide (SO2) emissions 3-4% of global carbon dioxide (CO2) emissions ShipModeling of shippingModeling of shipping NONOxx emissions in globalemissions in global CTMs 70% of the ship emissions occur within 400 km of land Only industrial sector not regulated under

  7. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  8. Comparison of Two U.S. Power-Plant Carbon Dioxide

    E-Print Network [OSTI]

    Comparison of Two U.S. Power-Plant Carbon Dioxide Emissions Data Sets K A T H E R I N E V . A C K E to more localized carbon budgets, uncertainties in emissions from local sources such as power plants-change mitigation concerns over a broad range of spatial and temporal scales. We compared two data sets that report

  9. Uncertainty analysis of capacity estimates and leakage potential for geologic storage of carbon dioxide in saline aquifers

    E-Print Network [OSTI]

    Raza, Yamama

    2009-01-01T23:59:59.000Z

    The need to address climate change has gained political momentum, and Carbon Capture and Storage (CCS) is a technology that is seen as being feasible for the mitigation of carbon dioxide emissions. However, there is ...

  10. Worldwide, accelerating glacier loss provides independent and startling evidence that global warming is occurring1 It is now clear that the Earth is warming rapidly due to man-made emissions of carbon dioxide and other heat-trap-

    E-Print Network [OSTI]

    Combes, Stacey A.

    such as coal, oil and natural gas are burned for trans- portation, heating, or the production of electricity, in order to avoid exceeding this 2°C threshold. The majority of CO2 pollution is released when fossil fuels. Coal is particularly damaging, as it produces 70% more CO2 emissions than natural gas for the same

  11. Current Understanding and Remaining Challenges in Modeling Long...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses. Current Understanding and Remaining Challenges in Modeling...

  12. Uranium dioxide electrolysis

    DOE Patents [OSTI]

    Willit, James L. (Batavia, IL); Ackerman, John P. (Prescott, AZ); Williamson, Mark A. (Naperville, IL)

    2009-12-29T23:59:59.000Z

    This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

  13. CARBON DIOXIDE AND OUR OCEAN LEGACY

    E-Print Network [OSTI]

    is a biologist at the California State Univer- sity San Marcos, with expertise in the effects of carbon dioxideCARBON DIOXIDE AND OUR OCEAN LEGACY G Carbon Dioxide: Our Role The United States is the single. Every day the average American adds about 118 pounds of carbon dioxide to the atmos- phere, due largely

  14. Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-

    E-Print Network [OSTI]

    Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide dioxide separation and sequestration because the lower cost of carbon dioxide separation from for injection of carbon dioxide into oil or gas-bearing formations. An advantage of sequestration involving

  15. Carbon Dioxide: Threat or Opportunity?

    E-Print Network [OSTI]

    McKinney, A. R.

    1982-01-01T23:59:59.000Z

    catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar...

  16. Reducing carbon dioxide to products

    DOE Patents [OSTI]

    Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

    2014-09-30T23:59:59.000Z

    A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

  17. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18T23:59:59.000Z

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  18. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfn; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2004-12-31T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. Continuous carbon dioxide injection began on December 2, 2003. By the end of December 2004, 11.39 MM lb of carbon dioxide were injected into the pilot area. Carbon dioxide injection rates averaged about 242 MCFD. Vent losses were excessive during June as ambient temperatures increased. Installation of smaller plungers in the carbon dioxide injection pump reduced the recycle and vent loss substantially. Carbon dioxide was detected in one production well near the end of May and in the second production well in August. No channeling of carbon dioxide was observed. The GOR has remained within the range of 3000-4000 for most the last six months. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February, increasing to an average of about 2.35 B/D for the six month period between July 1 and December 31. Cumulative oil production was 814 bbls. Neither well has experienced increased oil production rates expected from the arrival of the oil bank generated by carbon dioxide injection.

  19. Climate Change and Air Quality People's emission of carbon

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    carbon dioxide out of the air using existing "air capture" technologies could cost about the same or lessClimate Change and Air Quality · People's emission of carbon dioxide will affect Earth's sea level to the North Slope of Alaska in the summer of 2009, to study the carbon content in permafrost. Policy · Pulling

  20. argon carbon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide levels in the atmosphere. Additional measurements by scientists working 10 Carbon Dioxide Sequestration and Utilization CiteSeer Summary: ? Carbon dioxide (CO2) in...

  1. applied carbon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide levels in the atmosphere. Additional measurements by scientists working 8 Carbon Dioxide Sequestration and Utilization CiteSeer Summary: ? Carbon dioxide (CO2) in...

  2. aqueous carbon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide levels in the atmosphere. Additional measurements by scientists working 12 Carbon Dioxide Sequestration and Utilization CiteSeer Summary: ? Carbon dioxide (CO2) in...

  3. Reduced Turbine Emissions Using Hydrogen-Enriched Fuels

    E-Print Network [OSTI]

    ·Aids in the attainment of energy independence from foreign sources ­ Low-heating and medium emissions Source: Analysis of Strategies for Reducing Multiple Emissions from Power Plants: Sulfur Dioxide Systems At ultra lean conditions a tradeoff exists between NOx and CO emissions · Lean Premixed Combustion

  4. MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1

    E-Print Network [OSTI]

    Boyer, Edmond

    2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

  5. Transportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation

    E-Print Network [OSTI]

    .S. CO2 emissions sources. U.S. CO2 transportation emissions sources by mode. #12;Center% of the carbon dioxide we produce. As such it is a leading candidate for greenhouse gas ((GHG) (CO2, NH4, HFCsTransportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation Oak Ridge

  6. Market-Based Emissions Regulation and Industry Dynamics

    E-Print Network [OSTI]

    Fowlie, Meredith

    We assess the long-run dynamic implications of market-based regulation of carbon dioxide emissions in the US Portland cement industry. We consider several alternative policy designs, including mechanisms that use production ...

  7. Biochar amendment and greenhouse gas emissions from agricultural soils 

    E-Print Network [OSTI]

    Case, Sean Daniel Charles

    2013-11-28T23:59:59.000Z

    The aim of this study was to investigate the effects of biochar amendment on soil greenhouse gas (GHG) emissions and to elucidate the mechanisms behind these effects. I investigated the suppression of soil carbon dioxide ...

  8. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  9. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07T23:59:59.000Z

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  10. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    ) and their binary mixtures (between 348 and 393 K). The properties of supercritical carbon dioxide were determinedVAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE the vapor-liquid equilibrium of water (between 323 and 573 K), carbon dioxide (between 230 and 290 K

  11. SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW

    E-Print Network [OSTI]

    Santos, Juan

    SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW J. E. Santos1, G. B. Savioli2, J. M. Carcione3, D´e, Argentina SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. I Storage of CO2). SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. II CO2 is separated from natural

  12. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2007-03-07T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. By December 31, 2006, 79,072 bbls of water were injected into CO2 I-1 and 3,923 bbl of oil were produced from the pilot. Water injection rates into CO2 I-1, CO2 No.10 and CO2 No.18 were stabilized during this period. Oil production rates increased from 4.7 B/D to 5.5 to 6 B/D confirming the arrival of an oil bank at CO2 No.12. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver No.7, Colliver No.3 and possibly Graham A4 located on an adjacent property. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Our management plan is to continue water injection maintaining oil displacement by displacing the carbon dioxide remaining in the C zone,. If the decline rate of production from the Colliver Lease remains as estimated and the oil rate from the pilot region remains constant, we estimate that the oil production attributed to carbon dioxide injection will be about 12,000 bbl by December 31, 2007. Oil recovery would be equivalent to 12 MCF/bbl, which is consistent with field experience in established West Texas carbon dioxide floods. The project is not economic.

  13. Spatial Disaggregation of CO2 Emissions for the State of California

    E-Print Network [OSTI]

    consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported fromSpatial Disaggregation of CO2 Emissions for the State of California Stephane de la Rue du Can, Tom dioxide (CO2) emissions from fuel combustion1 to the 58 counties in the state. The total emissions

  14. Spatial Disaggregation of CO2 Emissions for the State of California

    E-Print Network [OSTI]

    consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported fromSpatial Disaggregation of CO2 Emissions for the State of California Stephane de la Rue du Can, Tom carbon dioxide (CO2) emissions from fuel combustion1 to the 58 counties in the state. The total emissions

  15. RESULTS FROM THE U.S. DOE 2006 SAVE ENERGY NOW ASSESSMENT INITIATIVE: DOE's Partnership with U.S. Industry to Reduce Energy Consumption, Energy Costs, and Carbon Dioxide Emissions

    SciTech Connect (OSTI)

    Wright, Anthony L [ORNL; Martin, Michaela A [ORNL; Gemmer, Bob [U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy; Scheihing, Paul [U.S. Department of Energy, Industrial Technologies Program; Quinn, James [U.S. Department of Energy

    2007-09-01T23:59:59.000Z

    In the wake of Hurricane Katrina and other severe storms in 2005, natural gas supplies were restricted, prices rose, and industry sought ways to reduce its natural gas use and costs. In October 2005, U.S. Department of Energy (DOE) Energy Secretary Bodman launched his Easy Ways to Save Energy campaign with a promise to provide energy assessments to 200 of the largest U.S. manufacturing plants. A major thrust of the campaign was to ensure that the nation's natural gas supplies would be adequate for all Americans, especially during home heating seasons. In a presentation to the National Press Club on October 3, 2005, Secretary Bodman said: 'America's businesses, factories, and manufacturing facilities use massive amounts of energy. To help them during this period of tightening supply and rising costs, our Department is sending teams of qualified efficiency experts to 200 of the nation's most energy-intensive factories. Our Energy Saving Teams will work with on-site managers on ways to conserve energy and use it more efficiently.' DOE's Industrial Technologies Program (ITP) responded to the Secretary's campaign with its Save Energy Now initiative, featuring a new and highly cost-effective form of energy assessments. The approach for these assessments drew heavily on the existing resources of ITP's Technology Delivery component. Over the years, ITP-Technology Delivery had worked with industry partners to assemble a suite of respected software decision tools, proven assessment protocols, training curricula, certified experts, and strong partnerships for deployment. Because of the program's earlier activities and the resources that had been developed, ITP was prepared to respond swiftly and effectively to the sudden need to promote improved industrial energy efficiency. Because of anticipated supply issues in the natural gas sector, the Save Energy Now initiative strategically focused on natural gas savings and targeted the nation's largest manufacturing plants--those that consume a total of 1 trillion British thermal units (Btu) or more annually. The approximately 6800 U.S. facilities that fall into this category collectively account for about 53% of all energy consumed by industry in the United States. The 2006 Save Energy Now energy assessments departed from earlier DOE plant assessments by concentrating solely on steam and process heating systems, which are estimated to account for approximately 74% of all natural gas use for manufacturing. The assessments also integrated a strong training component designed to teach industrial plant personnel how to use DOE's steam or process heating opportunity assessment software tools. This approach had the advantages of promoting strong buy-in of plant personnel for the assessment and its outcomes and preparing them better to independently replicate the assessment process at the company's other facilities. The Save Energy Now initiative also included provisions to help plants that applied for but did not qualify for assessments (based on the 1 trillion Btu criterion). Services offered to these plants included (1) an assessment by one of DOE's 26 university-based Industrial Assessment Centers (IACs), (2) a telephone consultation with a systems expert at the DOE's Energy Efficiency and Renewable Energy Information Center, or (3) other technical materials and services available through ITP (e.g., the Save Energy Now CD). By the end of 2006, DOE had completed all 200 of the promised assessments, identifying potential natural gas savings of more than 50 trillion Btu and energy cost savings of about $500 million. These savings, if fully implemented, could reduce CO2 emissions by 4.04 million metric tons annually. These results, along with the fact that a large percentage of U.S. energy is used by a relatively small number of very large plants, clearly suggest that assessments are an expedient and cost-effective way to significantly affect large amounts of energy use. Building on the success of the 2006 initiative, ITP has expanded the effort in 2007 with the goal of conducting 250 more asse

  16. Tuning Chirality of Single-Wall Carbon Nanotubes by Selective Etching with Carbon Dioxide

    E-Print Network [OSTI]

    Kim, Bongsoo

    Tuning Chirality of Single-Wall Carbon Nanotubes by Selective Etching with Carbon Dioxide Kwanyong properties that are determined by the chirality1 and diameter of carbon nanotubes. One way to overcome@skku.ac.kr Application of carbon nanotubes (CNTs) to various electronic devices such as field emission displays, gas

  17. Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily

    SciTech Connect (OSTI)

    Helene Hilger; James Oliver; Jean Bogner; David Jones

    2009-03-31T23:59:59.000Z

    Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

  18. A National Forum on Demand Response: Results on What Remains...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forum on Demand Response: Results on What Remains to Be Done to Achieve Its Potential - Cost-Effectiveness Working Group A National Forum on Demand Response: Results on What...

  19. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)

    E-Print Network [OSTI]

    180 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by two firms with operations in Nevada and Oregon% of the titanium metal used was in aerospace applications. The remaining 40% was used in the armor, chemical

  20. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    172 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada and Utah. Ingot was produced. In 2011, an estimated 66% of the titanium metal was used in aerospace applications. The remaining 34

  1. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)

    E-Print Network [OSTI]

    182 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by two firms with operations in Nevada and Oregon% of the titanium metal used was in aerospace applications. The remaining 35% was used in the chemical process

  2. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by two firms with operations in Nevada and Oregon% of the titanium metal used was in aerospace applications. The remaining 40% was used in armor, chemical processing

  3. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada, Oregon, and Utah. Ingot and castings. In 2006, an estimated 72% of the titanium metal was used in aerospace applications. The remaining

  4. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    172 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada and Utah. Ingot was produced. In 2012, an estimated 72% of the titanium metal was used in aerospace applications. The remaining 28

  5. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    170 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada and Utah. Titanium ingot and castings. In 2013, an estimated 73% of the titanium metal was used in aerospace applications. The remaining

  6. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    180 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada, Oregon, and Utah. Ingot and castings. In 2007, an estimated 76% of the titanium metal was used in aerospace applications. The remaining

  7. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    172 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by four operations in Nevada, Oregon, and Utah. Ingot and castings. In 2010, an estimated 75% of the titanium metal was used in aerospace applications. The remaining

  8. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada, Oregon, and Utah. Ingot and castings. In 2008, an estimated 79% of the titanium metal was used in aerospace applications. The remaining

  9. TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)

    E-Print Network [OSTI]

    174 TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted) Domestic Production and Use: Titanium sponge metal was produced by three operations in Nevada, Oregon, and Utah. A fourth, an estimated 76% of the titanium metal was used in aerospace applications. The remaining 24% was used in armor

  10. Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Murtishaw, Scott; Worrell, Ernst

    2003-06-01T23:59:59.000Z

    Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes

  11. Abatement of Air Pollution: Control of Carbon Dioxide Emissions/Carbon Dioxide Budget Trading Program (Connecticut)

    Broader source: Energy.gov [DOE]

    Any source that serves an electricity generator with a nameplate capacity equal to or greater than 25 MWe is considered a CO2 budget source for the purpose of these regulations. This section lists...

  12. An analysis of the impact of having uranium dioxide mixed in with plutonium dioxide

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    1998-10-21T23:59:59.000Z

    An assessment was performed to show the impact on airborne release fraction, respirable fraction, dose conversion factor and dose consequences of postulated accidents at the Plutonium Finishing Plant involving uranium dioxide rather than plutonium dioxide.

  13. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01T23:59:59.000Z

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  14. Abatement of Air Pollution: Control of Sulfur Dioxide Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    apply to fossil-fuel fired stationary sources which serve a generator with a nameplate capacity of 15 MW or more, or fossil-fuel fired boilers or indirect heat exchangers with a...

  15. Abatement of Air Pollution: Control of Carbon Dioxide Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Savings Category Fuel Cells Photovoltaics Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection Any...

  16. Carbon Dioxide Emissions Associated with Bioenergy and Other...

    Open Energy Info (EERE)

    Protection Agency Sector: Energy, Climate Focus Area: Biomass, - Biomass Combustion, - Biomass Gasification, - Biomass Pyrolysis, - Biofuels, - Landfill Gas, - Waste to...

  17. The Projected Impacts of Carbon Dioxide Emissions Reduction Legislation on

    E-Print Network [OSTI]

    of wind and natural gas generation, retirement of older coal- fired units that have not been retrofitted by 2025. Due to the state's heavy reliance on coal as a fuel source for electricity generation, Indiana allowances and offsets, shifting production technology from coal-fired baseload resources to a combination

  18. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    html includes actual household energy consumption data.We use this energy consumption data to estimate nationaldo not have data on energy consumption from public transit

  19. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    City~K Charlotte-Gas~C Tulsa, OK Akron, OH Raleigh-Durha~CCity~K Memphis, TN/A~S Tulsa, OK Albany-Schene~Y MO~L St.Greenville-Sp~ OK Atlanta, GA Tulsa, Dayton-Spring~H City, ~

  20. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    natural gas and fuel oil consumption for a household with anfor fuel oil and electricity consumption. We then usefuel oil) and residential electricity consumption. Car usage

  1. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    public transit, home heating, and household electricitypublic transportation, home heating (fuel oil and naturalCar usage and home heating involves a relatively simple

  2. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01T23:59:59.000Z

    public transportation, residential heating (natural gas andtransportation, home heating (fuel oil and natural gas) and

  3. U.S. Energy-Related Carbon Dioxide Emissions, 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production andOrigin219:

  4. Estimates of State Energy-Related Carbon Dioxide Emissions

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity Use as an IndicatorNatural GasRevenueMay

  5. Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpen EnergyCallawayCapara Energia S ACarbon Clear JumpSources |

  6. An Analysis of the Effectiveness and Impact of Mandatory Company Greenhouse Gas Emission Reporting Under The Companies Act 2006 (Strategic Report and Directors’ Report) Regulations 2013 

    E-Print Network [OSTI]

    Plaza, Celina

    2014-11-22T23:59:59.000Z

    The intent of this research is to examine the effectiveness and impact of the UK’s mandatory reporting of company greenhouse gas emissions, otherwise known as carbon dioxide equivalent (CO2e) emissions, in accordance to ...

  7. Trends in emissions of acidifying species in Asia, 1985-1997.

    SciTech Connect (OSTI)

    Streets, D. G.; Tsai, N. Y.; Akimoto, H.; Oka, K.

    2000-05-31T23:59:59.000Z

    Acid deposition is a serious problem throughout much of Asia. Emissions of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) have been increasing steadily, as nations strive to increase their levels of economic development. Coal and fuel oil have been the main choices for powering industrial development; and, until recently, only a few countries (notably Japan and Taiwan) had taken significant steps to avert the atmospheric emissions that accompany fuel combustion. This paper discusses trends in emissions of SO{sub 2} and NO{sub x} that have occurred in Asian countries in the period 1985--1997, using results from the RAINS-ASIA computer model and energy-use trends from the IEA Energy Statistics and Balances database. Emissions of SO{sub 2} in Asia grew from 26.6 Tg in 1985 to 33.7 Tg in 1990 and to 39.2 Tg in 1997. Though SO{sub 2} emissions used to grow as fast as fossil-fuel use, recent limitations on the sulfur content of coal and oil have slowed the growth. The annual-average emissions growth between 1990 and 1997 was only 1.1%, considerably less than the economic growth rate. Emissions of NO{sub x}, on the other hand, continue to grow rapidly, from 14.1 Tg in 1985 to 18.7 Tg in 1990 and 28.5 Tg in 1997, with no signs of abating. Thus, though SO{sub 2} remains the major contributor to acidifying emissions in Asia, the role of NO{sub x}, will become more and more important in the future.

  8. GHG Emissions from Hydropower Reservoirs The role of hydropower reservoirs in contributing to greenhouse gas (GHG) emissions is poorly

    E-Print Network [OSTI]

    GHG Emissions from Hydropower Reservoirs The role of hydropower reservoirs in contributing from tropical and boreal reservoirs are significant. In light of hydropower's potential role as a green to characterize carbon dioxide (CO2) and methane (CH4) emissions from hydropower reservoirs in the US Southeast

  9. SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW

    E-Print Network [OSTI]

    santos

    SEISMIC MONITORING OF. CARBON DIOXIDE FLUID FLOW. J. E. Santos. 1. , G. B. Savioli. 2. , J. M. Carcione. 3. , D. Gei. 3. 1. CONICET, IGPUBA, Fac.

  10. Putting the pressure on carbon dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on carbon dioxide Released: March 26, 2014 Improving the chances for fuel recovery and carbon sequestration Artwork from this research graces the cover of Environmental Science...

  11. SIMULATION OF CARBON DIOXIDE STORAGE APPLYING ...

    E-Print Network [OSTI]

    Capture and storage of Carbon dioxide in aquifers and reservoirs is one of the solutions to mitigate the greenhouse effect. Geophysical methods can be used to

  12. Accomplishments and Remaining Challenges: THREDDS Data Server and

    E-Print Network [OSTI]

    Accomplishments and Remaining Challenges: THREDDS Data Server and Common Data Model Ethan Davis Unidata Policy Committee Meeting 23-24 May 2011 #12;THREDDS Data Server (TDS) · Web server for scientific;THREDDS Data Server (TDS) · ... · Data access services: ­ OPeNDAP ­ OGC WMS and WCS ­ NCSS · Data

  13. Reply to Davies: Hydraulic fracturing remains a possible mechanism for

    E-Print Network [OSTI]

    Jackson, Robert B.

    LETTER Reply to Davies: Hydraulic fracturing remains a possible mechanism for observed methane in aquifers overlying the Marcellus formation but asserts that we prematurely ascribed its cause to hydraulic mechanisms were leaky gas well casings and the possibility that hydraulic fracturing might generate new

  14. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

  15. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01T23:59:59.000Z

    Coal-Fired Electricity Generation Technology Shares and Efficiencies, 2005- Figure 54 China CIS Total and Power Sector Carbon Dioxide Emissions,coal capacity 100-200 MW power sector carbon dioxide emissionsemissions. Table 41 Comparison of CCS Assumptions in Different Studies % of Coal Power

  16. absorbing sulfur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known 158 Interglacials, Milankovitch Cycles, and Carbon Dioxide CERN...

  17. amorphous titanium dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known 177 Interglacials, Milankovitch Cycles, and Carbon Dioxide CERN...

  18. acute sulphur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known 82 Interglacials, Milankovitch Cycles, and Carbon Dioxide CERN...

  19. addressing chlorine dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known 103 Interglacials, Milankovitch Cycles, and Carbon Dioxide CERN...

  20. Water and Carbon Dioxide Adsorption at Olivine Surfaces. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Carbon Dioxide Adsorption at Olivine Surfaces. Water and Carbon Dioxide Adsorption at Olivine Surfaces. Abstract: Plane-wave density functional theory (DFT) calculations were...

  1. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers This fact sheet describes a supercritical carbon...

  2. Haverford Researchers Create Carbon Dioxide-Separating Polymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy...

  3. Project Profile: Supercritical Carbon Dioxide Turbo-Expander...

    Energy Savers [EERE]

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers SWRI Logo The Southwest Research...

  4. Carbon dioxide-assisted fabrication of highly uniform submicron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide-assisted fabrication of highly uniform submicron-sized colloidal carbon spheres via hydrothermal carbonization Carbon dioxide-assisted fabrication of highly uniform...

  5. atmospheric sulphur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide CERN Preprints Summary: The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause...

  6. atmospheric sulfur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide CERN Preprints Summary: The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause...

  7. Greenhouse gas emissions and the surface transport of freight in Canada

    E-Print Network [OSTI]

    Greenhouse gas emissions and the surface transport of freight in Canada Paul Steenhof a,*, Clarence committed to reducing its greenhouse gas (GHG) emissions to 6% below 1990 levels between 2008 and 2012's emissions of 740 million metric tonnes of carbon dioxide (mmTCO2e), and 41% of the CO2e emitted from

  8. Julian Cleary, Nigel T. Roulet and Tim R. Moore Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Roulet, Nigel T.

    ) emissions from land use, fossil fuel combustion, and peat decomposition, contributes to Canada's net the rate of in situ decomposition through greater diffusion of oxygen, increasing CO2 emissions, manufacturing, use, and disposition (12, 13). GHG emissions, comprising carbon dioxide (CO2), methane (CH4

  9. SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased

    E-Print Network [OSTI]

    Martin, Randall

    SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, spacebased 18 March 2011. [1] Topdown constraints on global sulfur dioxide (SO2) emissions are inferred through of GEOSChem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS

  10. On-Road Remote Sensing of Automobile Emissions in west Los Angeles: Year 4,

    E-Print Network [OSTI]

    Denver, University of

    emission inventory.1 For a description of the internal combustion engine and causes of pollutants excess oxygen not involved in combustion. Mass emissions per mass or volume of fuel can also (or completely) converting engine-out CO, HC and NO emissions to carbon dioxide (CO2), water

  11. Carbon Dioxide for pH Control

    SciTech Connect (OSTI)

    Wagonner, R.C.

    2001-08-16T23:59:59.000Z

    Cardox, the major supplier of carbon dioxide, has developed a diffuser to introduce carbon dioxide into a water volume as small bubbles to minimize reagent loss to the atmosphere. This unit is integral to several configurations suggested for treatment to control alkalinity in water streams.

  12. Optimize carbon dioxide sequestration, enhance oil recovery

    E-Print Network [OSTI]

    - 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

  13. Carbon dioxide storage professor Martin Blunt

    E-Print Network [OSTI]

    Carbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS) referS to the Set of technologies developed to capture carbon dioxide (Co2) gas from the exhausts raises new issues of liability and risk. the focus of this briefing paper is on the storage of carbon

  14. Electricity generation and emissions reduction decisions under uncertainty : a general equilibrium analysis

    E-Print Network [OSTI]

    Morris, Jennifer F. (Jennifer Faye)

    2013-01-01T23:59:59.000Z

    The electric power sector, which accounts for approximately 40% of U.S. carbon dioxide emissions, will be a critical component of any policy the U.S. government pursues to confront climate change. In the context of uncertainty ...

  15. 1996 update on compliance and emissions trading under the U.S. acid rain program

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1998-01-01T23:59:59.000Z

    November 1997This paper reports on the second year of compliance with the sulfur dioxide (SO2) emissions-reduction and -trading provisions of the Title IV of the 1990 Clean Air Act Amendments (CAAA). The material is intended ...

  16. Electricity Generation and Emissions Reduction Decisions under Policy Uncertainty: A General Equilibrium Analysis

    E-Print Network [OSTI]

    Morris, J.

    The electric power sector, which accounts for approximately 40% of U.S. carbon dioxide emissions, will be a critical component of any policy the U.S. government pursues to confront climate change. In the context of uncertainty ...

  17. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01T23:59:59.000Z

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  18. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Richard Pancake; JyunSyung Tsau; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2010-03-07T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide was injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide was injected to displace the oil bank to the production wells by water injection. By March 7,2010, 8,736 bbl of oil were produced from the pilot. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver A7, Colliver A3, Colliver A14 and Graham A4 located on adjacent leases. About 19,166 bbl of incremental oil were estimated to have been produced from these wells as of March 7, 2010. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Estimated oil recovery attributed to the CO2 flood is 27,902 bbl which is equivalent to a gross CO2 utilization of 4.8 MCF/bbl. The pilot project is not economic.

  19. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    SciTech Connect (OSTI)

    K.A.M. Gasem; R.L. Robinson, Jr.; L.R. Radovic

    2001-06-15T23:59:59.000Z

    The authors' long term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure and adsorbent types. The major objectives of the project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coal being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals, to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. The specific accomplishments of this project during this reporting period are summarized below in three broad categories outlining experimentation, model development, and coal characterization. (1) Experimental Work: Our adsorption apparatus was reassembled, and all instruments were tested and calibrated. Having confirmed the viability of the experimental apparatus and procedures used, adsorption isotherms for pure methane, carbon dioxide and nitrogen on wet Fruitland coal were measured at 319.3 K (115 F) and pressures to 12.4 MPa (1800 psia). These measurements showed good agreement with our previous data and yielded an expected uncertainty of about 2%. Preparations are underway to measure adsorption isotherms for pure methane, carbon dioxide and nitrogen on two other coals. (2) Model Development: The experimental data were used to evaluate the predictive capabilities of various adsorption models, including the Langmuir/loading ratio correlation, two-dimensional cubic equations of state, and the local density model. In general, all models performed well for Type I adsorption exhibited by methane, nitrogen, and carbon dioxide up to 8.3 MPa (average deviations within 2%). However, for pressures higher than 8.3 MPa (1200 psia), carbon dioxide produced multilayer adsorption behavior similar to Type IV adsorption. Our results to date indicate that the SLD model may be a suitable choice for modeling multilayer coalbed gas adsorption. However, model improvements are required to (a) account for coal heterogeneity and structure complexity, and (b) provide for more accurate density predictions. (3) Coal Characterization: We have identified several well-characterized coals for use in our adsorption studies. The criteria for coal selection has been guided by the need for coals that (a) span the spectrum of properties encountered in coalbed methane production (such as variation in rank), and (b) originate from coalbed methane recovery sites (e.g., San Juan Basin, Black Warrior Basin, etc.). At Pennsylvania State University, we have completed calibrating our instruments using a well-characterized activated carbon. In addition, we have conducted CO{sub 2} and methane uptakes on four samples, including (a) a widely used commercial activated carbon, BPL from Calgon Carbon Corp.; (b) an Illinois No.6 bituminous coal from the Argonne Premium Coal sample bank; (c) a Fruitland Intermediate coal sample; (d) a dry Fruitland sample. The results are as expected, except for a greater sensitivity to the outgassing temperature. ''Standard'' outgassing conditions (e.g., 383.2 K, overnight), which are often used, may not be appropriate for gas storage in coalbeds. Conditions that are more representative of in-situ coal (approximately 313.2 K) may be much more appropriate. In addition, our results highlight the importance of assessing the degree of approach to adsorption equilibrium.

  20. CARBON DIOXIDE HYDRATES CRYSTALLISATION IN EMULSION Aurlie Galfr, Amara Fezoua, Yamina Ouabbas, Ana Cameirao, Jean Michel Herri

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    identified as major sources responsible for global warming. To reduce carbon dioxide emissions, capture (several cubic meters per second of CO2), the capture technology needs to run at severe conditions and to minimize the cost of the process Innovative technology capture by gas hydrates crystallization can

  1. Effects of Various Membrane Electrode Assemblies on the Electrochemical Reduction of Carbon Dioxide in the Gas Phase

    E-Print Network [OSTI]

    Petta, Jason

    for global warming. Human activities have contributed to the rise in sea level, change in wind patterns to decrease net carbon dioxide emissions and mitigate the effects of global warming, it is necessary to find, and increase in temperatures. If this trend in CO2 levels continues to rise it can lead to the loss of portions

  2. Methane-assisted combustion synthesis of nanocomposite tin dioxide materials

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Methane-assisted combustion synthesis of nanocomposite tin dioxide materials S.D. Bakrania *, C., Ann Arbor, MI 48109-2125, USA Abstract Combustion synthesis of tin dioxide (SnO2) was studied using: Combustion synthesis; Nanoparticles; Tin dioxide; Metals 1. Introduction Tin dioxide (SnO2) is the most

  3. Displacement of crude oil by carbon dioxide

    E-Print Network [OSTI]

    Omole, Olusegun

    1980-01-01T23:59:59.000Z

    by Carbon Dioxide (December 1980) Olusegun Omole, B. S. , University of Ibadan, Nigeria Chairman of Advisory Committee: Dr. J. S. Osoba It has long been recognized that carbon dioxide could be used as an oil recovery agent. Both laboratory and field...- tion. Crude oil from the Foster Field in West Texas, of 7 cp and 34 API, 0 was used as the oil in place. Oil displacements were conducted at pres- sures between 750 psig and 1800 ps1g, and at a temperature of 110 F. 0 Carbon dioxide was injected...

  4. Apparatus for determining past-service conditions and remaining life of thermal barrier coatings and components having such coatings

    DOE Patents [OSTI]

    Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Rexford, NY)

    2004-05-04T23:59:59.000Z

    An apparatus for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises a radiation source that provides the exciting radiation to the TBC to excite a photoluminescent ("PL") material contained therein, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of an emission spectrum of the PL material to the amount of a crystalline phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component or the TBC.

  5. Regulating carbon dioxide capture and storage

    E-Print Network [OSTI]

    De Figueiredo, Mark A.

    2007-01-01T23:59:59.000Z

    This essay examines several legal, regulatory and organizational issues that need to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal, regulatory, and organizational ...

  6. Thorium dioxide: properties and nuclear applications

    SciTech Connect (OSTI)

    Belle, J.; Berman, R.M. (eds.)

    1984-01-01T23:59:59.000Z

    This is the sixth book on reactor materials published under sponsorship of the Naval Reactors Office of the United States Department of Energy, formerly the United States Atomic Energy Commission. This book presents a comprehensive compilation of the most significant properties of thorium dioxide, much like the book Uranium Dioxide: Properties and Nuclear Applications presented information on the fuel material used in the Shippingport Pressurized Water Reactor core.

  7. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  8. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2006-06-30T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and two production wells on about 10 acre spacing. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February 2004, increasing to an average of about 3.78 B/D for the six month period between January 1 and June 30, 2005 before declining. By June 30, 2006, 41,566 bbls of water were injected into CO2I-1 and 2,726 bbl of oil were produced from the pilot. Injection rates into CO2I-1 declined with time, dropping to an unacceptable level for the project. The injection pressure was increased to reach a stable water injection rate of 100 B/D. However, the injection rate continued to decline with time, suggesting that water was being injected into a region with limited leakoff and production. Oil production rates remained in the range of 3-3.5 B/D following conversion to water injection. Oil rates increased from about 3.3 B/D for the period from January through March to about 4.7 B/D for the period from April through June. If the oil rate is sustained, this may be the first indication of the arrival of the oil bank mobilized by carbon dioxide injection. A sustained fluid withdrawal rate of about 200 B/D from CO2 No.12 and CO2 No.13 appears to be necessary to obtain higher oil rates. There is no evidence that the oil bank generated by injection of carbon dioxide has reached either production well. Water injection will continue to displace oil mobilized by carbon dioxide to the production wells and to maintain the pressure in the PPV region at a level that supports continued miscible displacement as the carbon dioxide is displaced by the injected water.

  9. Coal: Long-term prospects remain very good

    SciTech Connect (OSTI)

    Doerell, P.E. [ed.

    1996-03-01T23:59:59.000Z

    Worldwide, it is the most economic and widespread fossil fuel available. The importance of coal will continue to grow to generate enough electricity to meet a rapidly increasing demand for energy. The first sign of a rising standard of living is access to a reliable and plentiful supply of electricity-and that means power generation from coal. The World Energy Conference in Tokyo last October called upon governments to {open_quotes}recognize that fossil fuels are likely to remain cost-competitive against alternatives over the next few decades and are set to play a greater and longer role than is widely thought.{close_quotes} Since coal, of all fossil fuels, has by far the most abundant reserves, this applies especially to coal. The International Energy Agency in Paris predicts a constant increase in the international hard-coal trade. While in 1973 (at the beginning of the first oil price crisis) only 8% of world hard coal produced was traded worldwide, this contribution increased to 11% by 1992 and may even grow to 16% between 1992 and 2010. Regarding volume, this would mean that the international hard-coal trade would more than double in the 18 years to 2010, i.e., from 403M to 852 M mt/yr. The 1995 update of the {open_quotes}Review of World Coal Trade,{close_quotes} published by the U.N. Economic Commission for Europe in Geneva, Switzerland, gives lower but still very considerable growth rate estimates: requirements from 3.508B (1990) to 3.982B mt (2010), production from 3.549B to 3994B mt, imports from 396M to 566M mt, and exports from 395M to 578M mt.

  10. Remaining-life estimation of boiler pressure parts

    SciTech Connect (OSTI)

    Borden, M.P.; Ellis, F.V. (ABB Combustion Engineering Systems, Chattanooga, TN (USA)); Miller, D.A.; Gladwin, D. (National Power, Leatherhead (UK))

    1991-02-01T23:59:59.000Z

    One of the objectives of this project was to determine the effect of prior creep damage on the remaining life of base material and HAZ material subjected to pure fatigue and creep fatigue loading. Life assessment techniques for cyclic loading conditions are required due to the need to two shifts (two shifts on, one shift off) or load-follow for conventional fossil power plant as new nuclear units become available. Described herein are the results of work undertaken at ABB Combustion Engineering Systems in the US and South Western Regional Scientific Services Department and Central Electricity Research Laboratories of the Central Electricity Generating Board in the UK. An interrupted creep testing program was conducted on a single heat of 1Cr--1/2Mo steel to produce creep damaged or pre-crept material for the pure fatigue and creep-fatigue test programs. Metallographic examination of the pre-crept material revealed the primary creep damage mechanism was thermal softening for the base material and creep cavitation for the HAZ material. Creep rupture properties were measured for the virgin, aged, and pre-crept materials at the creep-fatigue test temperature of 535{degree}C to aid in interpretation of the effect of prior creep on creep-fatigue life. Creep-fatigue life prediction was performed using the linear life fraction rule, stress based and strain-based life fraction approaches. The remanent creep-fatigue of the HAZ material can be predicted by conducting a linear summation of creep life fraction and creep-fatigue life fraction. This approach is not applicable for base material. The life fraction method of predicting the as-received creep-fatigue endurance data based on a ductility exhaustion approach gave better prediction than a stress based approach. The implications of the current project results are discussed in terms of developing an assessment procedure for determining the creep-fatigue life of elevated temperature components. 21 refs., 54 figs., 15 tabs.

  11. Ionic Liquid Membranes for Carbon Dioxide Separation

    SciTech Connect (OSTI)

    Myers, C.R.; Ilconich, J.B.; Luebke, D.R.; Pennline, H.W.

    2008-07-12T23:59:59.000Z

    Recent scientific studies are rapidly advancing novel technological improvements and engineering developments that demonstrate the ability to minimize, eliminate, or facilitate the removal of various contaminants and green house gas emissions in power generation. The Integrated Gasification Combined Cycle (IGCC) shows promise for carbon dioxide mitigation not only because of its higher efficiency as compared to conventional coal firing plants, but also due to a higher driving force in the form of high partial pressure. One of the novel technological concepts currently being developed and investigated is membranes for carbon dioxide (CO2) separation, due to simplicity and ease of scaling. A challenge in using membranes for CO2 capture in IGCC is the possibility of failure at elevated temperatures or pressures. Our earlier research studies examined the use of ionic liquids on various supports for CO2 separation over the temperature range, 37°C-300°C. The ionic liquid, 1-hexyl-3methylimidazolium Bis(trifluoromethylsulfonyl)imide, ([hmim][Tf2N]), was chosen for our initial studies with the following supports: polysulfone (PSF), poly(ether sulfone) (PES), and cross-linked nylon. The PSF and PES supports had similar performance at room temperature, but increasing temperature caused the supported membranes to fail. The ionic liquid with the PES support greatly affected the glass transition temperature, while with the PSF, the glass transition temperature was only slightly depressed. The cross-linked nylon support maintained performance without degradation over the temperature range 37-300°C with respect to its permeability and selectivity. However, while the cross-linked nylon support was able to withstand temperatures, the permeability continued to increase and the selectivity decreased with increasing temperature. Our studies indicated that further testing should examine the use of other ionic liquids, including those that form chemical complexes with CO2 based on amine interactions. The hypothesis is that the performance at the elevated temperatures could be improved by allowing a facilitated transport mechanism to become dominant. Several amine-based ionic liquids were tested on the cross-linked nylon support. It was found that using the amine-based ionic liquid did improve selectivity and permeability at higher temperature. The hypothesis was confirmed, and it was determined that the type of amine used also played a role in facilitated transport. Given the appropriate aminated ionic liquid with the cross-linked nylon support, it is possible to have a membrane capable of separating CO2 at IGCC conditions. With this being the case, the research has expanded to include separation of other constituents besides CO2 (CO, H2S, etc.) and if they play a role in membrane poisoning or degradation. This communication will discuss the operation of the recently fabricated ionic liquid membranes and the impact of gaseous components other than CO2 on their performance and stability.

  12. The Fabrication of Titanium Dioxide Based Anode Material Using Aerosol Method

    E-Print Network [OSTI]

    Zhao, Lin

    2013-01-01T23:59:59.000Z

    synthesis of graphene-based titanium dioxide nanocompositesLos Angeles The Fabrication of Titanium Dioxide Based AnodeTHE THESIS The Fabrication of Titanium Dioxide Based Anode

  13. Pressure buildup during supercritical carbon dioxide injection from a partially penetrating borehole into gas reservoirs

    E-Print Network [OSTI]

    Mukhopadhyay, S.

    2013-01-01T23:59:59.000Z

    the physical properties of carbon dioxide, compare thei.e. , Physical Properties of Carbon Dioxide Z ? PV ? 1 ?Thermophysical Properties of Carbon Dioxide, Publishing

  14. Semiconductor-metal phase transition of vanadium dioxide nanostructures on silicon substrate: Applications for thermal control of spacecraft

    SciTech Connect (OSTI)

    Leahu, G. L., E-mail: roberto.livoti@uniroma1.it; Li Voti, R., E-mail: roberto.livoti@uniroma1.it; Larciprete, M. C., E-mail: roberto.livoti@uniroma1.it; Belardini, A., E-mail: roberto.livoti@uniroma1.it; Mura, F., E-mail: roberto.livoti@uniroma1.it; Sibilia, C.; Bertolotti, M. [Dipartimento di Scienze di Base ed Applicate per l'Ingegneria, Sapienza Università di Roma, Via A. Scarpa 16 00161 Roma (Italy); Fratoddi, I. [Dipartimento di Chimica, Sapienza Università di Roma, Piazzale A. Moro, Roma (Italy)

    2014-06-19T23:59:59.000Z

    We present a detailed infrared study of the semiconductor-to-metal transition (SMT) in a vanadium dioxide (VO2) film deposited on silicon wafer. The VO2 phase transition is studied in the mid-infrared (MIR) region by analyzing the transmittance and the reflectance measurements, and the calculated emissivity. The temperature behaviour of the emissivity during the SMT put into evidence the phenomenon of the anomalous absorption in VO2 which has been explained by applying the Maxwell Garnett effective medium approximation theory, together with a strong hysteresis phenomenon, both useful to design tunable thermal devices to be applied for the thermal control of spacecraft. We have also applied the photothermal radiometry in order to study the changes in the modulated emissivity induced by laser. Experimental results show how the use of these techniques represent a good tool for a quantitative measurement of the optothermal properties of vanadium dioxide based structures.

  15. Supermarket with Ground Coupled Carbon Dioxide Refrigeration Plant

    E-Print Network [OSTI]

    Rehault, N.

    2012-01-01T23:59:59.000Z

    are massive energy consumers [4] EnOB [5] Kauffeld 2009 ? Fraunhofer ISE 4 Global emissions of fluorinated greenhouse gases Source: UBA ? 12.2010 1,1% 7,9% F-gas contribution to greenhouse effect 1. Backgrounds ? Fraunhofer ISE 5 Energy breakdown... refrigeration remains the last big subsector and the strongest emission source of the fluorinated hydrocarbons (HFC) in Germany? - Kauffeld [4] About 65 % of the cooling needs in Germany for frozen and refrigerated food products ? over 50.000 GWh...

  16. Investigation of the carbon dioxide sorption capacity and structural deformation of coal

    SciTech Connect (OSTI)

    Hur, Tae-Bong; Fazio, James; Romanov, Vyacheslav; Harbert, William

    2010-01-01T23:59:59.000Z

    Due to increasing atmospheric CO2 concentrations causing the global energy and environmental crises, geological sequestration of carbon dioxide is now being actively considered as an attractive option to mitigate greenhouse gas emissions. One of the important strategies is to use deep unminable coal seams, for those generally contain significant quantities of coal bed methane that can be recovered by CO2 injection through enhanced coal bed natural gas production, as a method to safely store CO2. It has been well known that the adsorbing CO2 molecules introduce structural deformation, such as distortion, shrinkage, or swelling, of the adsorbent of coal organic matrix. The accurate investigations of CO2 sorption capacity as well as of adsorption behavior need to be performed under the conditions that coals deform. The U.S. Department of Energy-National Energy Technology Laboratory and Regional University Alliance are conducting carbon dioxide sorption isotherm experiments by using manometric analysis method for estimation of CO2 sorption capacity of various coal samples and are constructing a gravimetric apparatus which has a visual window cell. The gravimetric apparatus improves the accuracy of carbon dioxide sorption capacity and provides feasibility for the observation of structural deformation of coal sample while carbon dioxide molecules interact with coal organic matrix. The CO2 sorption isotherm measurements have been conducted for moist and dried samples of the Central Appalachian Basin (Russell County, VA) coal seam, received from the SECARB partnership, at the temperature of 55 C.

  17. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.] [eds.

    1991-09-01T23:59:59.000Z

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  18. Carbon dioxide capture process with regenerable sorbents

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

    2002-05-14T23:59:59.000Z

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  19. FIELD DEMONSTRATION OF CARBON DIOXIDE MISCIBLE FLOODING IN THE LANSING-KANSAS CITY FORMATION, CENTRAL KANSAS

    SciTech Connect (OSTI)

    Alan Byrnes; G. Paul Willhite; Don Green; Martin Dubois; Richard Pancake; Timothy Carr; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2005-12-31T23:59:59.000Z

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and two production wells on about 10 acre spacing. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide were injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide has been injected to displace the oil bank to the production wells by water injection. Wells in the pilot area produced 100% water at the beginning of the flood. Oil production began in February 2004, increasing to an average of about 3.78 B/D for the six month period between January 1 and June 30, 2005 before declining. By the end of December 2005, 14,115 bbls of water were injected into CO2I-1 and 2,091 bbl of oil were produced from the pilot. Injection rates into CO2I-1 declined with time, dropping to an unacceptable level for the project. The injection pressure was increased to reach a stable water injection rate of 100 B/D. However, the injection rate continued to decline with time, suggesting that water was being injected into a region with limited leakoff and production. Oil production rates remained in the range of 3-3.5 B/D following conversion to water injection. There is no evidence that the oil bank generated by injection of carbon dioxide has reached either production well. Continued injection of water is planned to displace oil mobilized by carbon dioxide to the production wells and to maintain the pressure in the PPV region at a level that supports continued miscible displacement as the carbon dioxide is displaced by the injected water.

  20. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    SciTech Connect (OSTI)

    K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

    2003-04-30T23:59:59.000Z

    The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also provided direct synergism with the original goals of our work. Specific accomplishments of this project are summarized below in three broad categories: experimentation, model development, and coal characterization.

  1. A methodology for forecasting carbon dioxide flooding performance

    E-Print Network [OSTI]

    Marroquin Cabrera, Juan Carlos

    1998-01-01T23:59:59.000Z

    A methodology was developed for forecasting carbon dioxide (CO2) flooding performance quickly and reliably. The feasibility of carbon dioxide flooding in the Dollarhide Clearfork "AB" Unit was evaluated using the methodology. This technique is very...

  2. Dry process fluorination of uranium dioxide using ammonium bifluoride

    E-Print Network [OSTI]

    Yeamans, Charles Burnett, 1978-

    2003-01-01T23:59:59.000Z

    An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ...

  3. Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas)

    Broader source: Energy.gov [DOE]

    Carbon Dioxide Capture/Sequestration Tax Deduction allows a taxpayer a deduction to adjusted gross income with respect to the amortization of the amortizable costs of carbon dioxide capture,...

  4. Louisiana Geologic Sequestration of Carbon Dioxide Act (Louisiana)

    Broader source: Energy.gov [DOE]

    This law establishes that carbon dioxide and sequestration is a valuable commodity to the citizens of the state. Geologic storage of carbon dioxide may allow for the orderly withdrawal as...

  5. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Receivers for Supercritical Carbon Dioxide Cycles - FY12 Q4 High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles - FY12 Q4 This document summarizes the progress of...

  6. Designed amyloid fibers as materials for selective carbon dioxide capture

    E-Print Network [OSTI]

    Designed amyloid fibers as materials for selective carbon dioxide capture Dan Lia,b,c,1 , Hiroyasu demonstrate that amyloids, self-assembling protein fibers, are effective for selective carbon dioxide capture formation rate is fast enough to capture carbon dioxide by dynamic separation, undiminished by the presence

  7. Glutamate Surface Speciation on Amorphous Titanium Dioxide and

    E-Print Network [OSTI]

    Sverjensky, Dimitri A.

    Glutamate Surface Speciation on Amorphous Titanium Dioxide and Hydrous Ferric Oxide D I M I T R I (HFO) and titanium dioxide exhibit similar strong attachment of many adsorbates including biomolecules on amorphous titanium dioxide. The results indicate that glutamate adsorbs on HFO as a deprotonated divalent

  8. Nanostructured Tin Dioxide Materials for Gas Sensor Applications

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    CHAPTER 30 Nanostructured Tin Dioxide Materials for Gas Sensor Applications T. A. Miller, S. D) levels for some species. Tin dioxide (also called stannic oxide or tin oxide) semi- conductor gas sensors undergone extensive research and development. Tin dioxide (SnO2) is the most important material for use

  9. Thermal Properties of Supercritical Carbon Dioxide by Monte Carlo Simulations

    E-Print Network [OSTI]

    Lisal, Martin

    Thermal Properties of Supercritical Carbon Dioxide by Monte Carlo Simulations C.M. COLINAa,b, *, C and speed of sound for carbon dioxide (CO2) in the supercritical region, using the fluctuation method based: Fluctuations; Carbon dioxide; 2CLJQ; Joule­Thomson coefficient; Speed of sound INTRODUCTION Simulation methods

  10. Array of titanium dioxide nanostructures for solar energy utilization

    DOE Patents [OSTI]

    Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

    2014-12-30T23:59:59.000Z

    An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

  11. Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

  12. Influence of Shrinkage and Swelling Properties of Coal on Geologic Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Siriwardane, H.J.; Gondle, R.; Smith, D.H.

    2007-05-01T23:59:59.000Z

    The potential for enhanced methane production and geologic sequestration of carbon dioxide in coalbeds needs to be evaluated before large-scale sequestration projects are undertaken. Geologic sequestration of carbon dioxide in deep unmineable coal seams with the potential for enhanced coalbed methane production has become a viable option to reduce greenhouse gas emissions. The coal matrix is believed to shrink during methane production and swell during the injection of carbon dioxide, causing changes in tlie cleat porosity and permeability of the coal seam. However, the influence of swelling and shrinkage, and the geomechanical response during the process of carbon dioxide injection and methane recovery, are not well understood. A three-dimensional swelling and shrinkage model based on constitutive equations that account for the coupled fluid pressure-deformation behavior of a porous medium was developed and implemented in an existing reservoir model. Several reservoir simulations were performed at a field site located in the San Juan basin to investigate the influence of swelling and shrinkage, as well as other geomechanical parameters, using a modified compositional coalbed methane reservoir simulator (modified PSU-COALCOMP). The paper presents numerical results for interpretation of reservoir performance during injection of carbon dioxide at this site. Available measured data at the field site were compared with computed values. Results show that coal swelling and shrinkage during the process of enhanced coalbed methane recovery can have a significant influence on the reservoir performance. Results also show an increase in the gas production rate with an increase in the elastic modulus of the reservoir material and increase in cleat porosity. Further laboratory and field tests of the model are needed to furnish better estimates of petrophysical parameters, test the applicability of thee model, and determine the need for further refinements to the mathematical model.

  13. Development of Diesel Exhaust Aftertreatment System for Tier II Emissions

    SciTech Connect (OSTI)

    Yu, R. C.; Cole, A. S., Stroia, B. J.; Huang, S. C. (Cummins, Inc.); Howden, Kenneth C.; Chalk, Steven (U.S. Dept. of Energy)

    2002-06-01T23:59:59.000Z

    Due to their excellent fuel efficiency, reliability, and durability, compression ignition direct injection (CIDI) engines have been used extensively to power almost all highway trucks, urban buses, off-road vehicles, marine carriers, and industrial equipment. CIDI engines burn 35 to 50% less fuel than gasoline engines of comparable size, and they emit far less greenhouse gases (Carbon Dioxides), which have been implicated in global warming. Although the emissions of CIDI engines have been reduced significantly over the last decade, there remains concern with the Nitrogen Oxides (NOX) and Particulate Matter (PM) emission levels. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulations. Meeting the Tier II standards requires NOX and PM emissions to be reduced dramatically. Achieving such low emissions while minimizing fuel economy penalty cannot be done through engine development and fuel reformulation alone, and requires application of NOX and PM aftertreatment control devices. A joint effort was made between Cummins Inc. and the Department of Energy to develop the generic aftertreatment subsystem technologies applicable for Light-Duty Vehicle (LDV) and Light-Duty Truck (LDT) engines. This paper provides an update on the progress of this joint development program. Three NOX reduction technologies including plasmaassisted catalytic NOX reduction (PACR), active lean NOX catalyst (LNC), and adsorber catalyst (AC) technology using intermittent rich conditions for NOX reduction were investigated in parallel in an attempt to select the best NOX control approach for light-duty aftertreatment subsystem integration and development. Investigations included system design and analysis, critical lab/engine experiments, and ranking then selection of NOX control technologies against reliability, up-front cost, fuel economy, service interval/serviceability, and size/weight. The results of the investigations indicate that the best NOX control approach for LDV and LDT applications is a NOX adsorber system. A greater than 83% NOX reduction efficiency is required to achieve 0.07g/mile NOX Tier II vehicle-out emissions. Both active lean NOX and PACR technology are currently not capable of achieving the high conversion efficiency required for Tier II, Bin 5 emissions standards. In this paper, the NOX technology assessment and selection is first reviewed and discussed. Development of the selected NOX technology (NOX adsorber) and PM control are then discussed in more detail. Discussion includes exhaust sulfur management, further adsorber formulation development, reductant screening, diesel particulate filter development & active regeneration, and preliminary test results on the selected integrated SOX trap, NOX adsorber, and diesel particulate filter system over an FTP-75 emissions cycle, and its impact on fuel economy. Finally, the direction of future work for continued advanced aftertreatment technology development is discussed. (SAE Paper SAE-2002-01-1867 © 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.)

  14. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  15. Carbon Dioxide Corrosion: Modelling and Experimental Work

    E-Print Network [OSTI]

    Carbon Dioxide Corrosion: Modelling and Experimental Work Applied to Natural Gas Pipelines Philip in the corrosion related research institutions at IFE and the Ohio University or any other scientific research;#12;Introduction - v - Summary CO2 corrosion is a general problem in the industry and it is expensive. The focus

  16. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Scherer, Norbert F.

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  17. Carbon Dioxide Corrosion and Inhibition Studies

    E-Print Network [OSTI]

    Petta, Jason

    · Corrosion inhibition very important in the oil industry · Film forming inhibitors containing nitrogenCarbon Dioxide Corrosion and Inhibition Studies Kristin Gilida #12;Outline · Background = Zreal + Zim Rp 1/Corr Rate #12;Tafel · Measures corrosion rate directly · Measures iCORR from A and C

  18. Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

    SciTech Connect (OSTI)

    Garcia, Julio Enrique

    2003-12-18T23:59:59.000Z

    Injection of carbon dioxide (CO{sub 2}) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO{sub 2} will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO{sub 2} and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO{sub 2}-H{sub 2}O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO{sub 2}. The basic problem of CO{sub 2} injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO{sub 2} injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO{sub 2} injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO{sub 2}. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO{sub 2} into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO{sub 2}) the viscosity of carbon dioxide can be less than the viscosity of the aqueous phase by a factor of 15. Because of the lower viscosity, the CO{sub 2} displacement front will have a tendency towards instability. Preliminary simulation results show good agreement between classical instability solutions and numerical predictions of finger growth and spacing obtained using different gas/liquid viscosity ratios, relative permeability and capillary pressure models. Further studies are recommended to validate these results over a broader range of conditions.

  19. The TRANSIMS Approach to Emission Estimation

    SciTech Connect (OSTI)

    Barth, M.J.; Smith, L.; Thayer, G.R.; Williams, M.D.

    1999-02-01T23:59:59.000Z

    Transportation systems play a significant role in urban air quality, energy consumption and carbon-dioxide emissions. Recently, it has been found that current systems for estimating emissions of pollutants from transportation devices lead to significant inaccuracies. Most of the existing emission modules use very aggregate representations of traveler behavior and attempt to estimate emissions on typical driving cycles. However, recent data suggests that typical driving cycles produce relatively low emissions with most emissions coming from off-cycle driving, cold-starts, malfunctioning vehicles, and evaporative emissions. TRANSIMS is a simulation system for the analysis of transportation options in metropolitan areas. It's major functional components are: (1) a population disaggregation module, (2) a travel planning module, (3) a regional microsimulation module, and (4) an environmental module. In addition to the major functional components, it includes a strong underpining of simulation science and an analyst's tool box. The purpose of the environmental module is to translate traveler behavior into consequent air quality. The environmental module uses information from the TRANSIMS planner and the microsimulation and it supports the analyst's toolbox. The TRANSIMS system holds the promise of a more complete description of the role of heterogeneity in transportation in emission estimation.

  20. A STUDY OF EXTRACTIVE AND REMOTE-SENSING SAMPLING AND MEASUREMENT OF EMISSIONS FROM MILITARY AIRCRAFT ENGINES

    SciTech Connect (OSTI)

    Cheng, Mengdawn [ORNL; Corporan, E. [Air Force Research Laboratory, Wright-Patterson AFB, OH

    2010-01-01T23:59:59.000Z

    Aircraft emissions contribute to the increased atmospheric burden of particulate matter (e.g., black carbon and secondary organic compounds) that plays a role in air quality, contrail formation and climate change. Sampling and measurement of modern aircraft emissions at the engine exhaust plane (EEP) for to engine and fuel certification remains a daunting task, no agency-certified method is available for the task. In this paper we summarize the results of a recent study that was devoted to investigate both extractive and optical remote-sensing (ORS) technologies in sampling and measurement of gaseous and particulate matter (PM) emitted by a number of military aircraft engines operated with JP-8 and a Fischer-Tropsch (FT) fuel at various engine conditions. These engines include cargo, bomber, and helicopter types of military aircraft that consumes 70-80% of the military aviation fuel each year. The emission indices of selected pollutants are discussed as these data may be of interest for atmospheric modeling and for design of air quality control strategies around the airports and military bases. It was found that non-volatile particles in the engine emissions were all in the ultrafine range. The mean diameter of particles increased as the engine power increased; the mode diameters were in the 20nm range for the low power condition of a new helicopter engine to 80nm for the high power condition of a newly maintained bomber engine. Elemental analysis indicated little metals were present on particles in the exhaust, while most of the materials on the exhaust particles were based on carbon and sulfate. Carbon monoxide, carbon dioxide, nitrogen oxide, sulfur dioxide, formaldehyde, ethylene, acetylene, propylene, and alkanes were detected using both technologies. The last five species (in the air toxics category) were most noticeable only under the low engine power. The emission indices calculated based on the ORS data were however observed to differ significantly (up to 90%) from (typically lower than) those based on the extractive techniques. However, the ORS techniques were useful in providing non-intrusive real-time measurements of gaseous species in the exhaust plume, which warrants further development. The results obtained in this program validate sampling methodology and measurement techniques used for non-volatile PM aircraft emissions as described in the SAE AIR-6037.

  1. Impacts of High Resolution Extreme Events on U.S. Energy Demand and CO{sub 2} Emissions in the 21st Century

    SciTech Connect (OSTI)

    Diffenbaugh, Noah [Stanford University

    2013-06-21T23:59:59.000Z

    Progress is reported in these areas: Validation of temperature and precipitation extremes; Time of emergence of severe heat stress in the United States; Quantifying the effects of temperature extremes on energy demand and carbon dioxide emissions.

  2. Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production

    E-Print Network [OSTI]

    Liu, Zhongzhe

    2013-01-01T23:59:59.000Z

    with carbon capture and storage (BECCS) technology [6,7] .carbon dioxide emissions by major fuel, 2009…………….2 Fig.1.4 Schematic of CO 2 capture systems and technologies……………………………..carbon footprint. One unique technique is using in-situ CO 2 capture technology,

  3. Regional Opportunities for Carbon Dioxide Capture and Storage in China: A Comprehensive CO2 Storage Cost Curve and Analysis of the Potential for Large Scale Carbon Dioxide Capture and Storage in the People’s Republic of China

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Li, Xiaochun; Davidson, Casie L.; Wei, Ning; Dooley, James J.

    2009-12-01T23:59:59.000Z

    This study presents data and analysis on the potential for carbon dioxide capture and storage (CCS) technologies to deploy within China, including a survey of the CO2 source fleet and potential geologic storage capacity. The results presented here indicate that there is significant potential for CCS technologies to deploy in China at a level sufficient to deliver deep, sustained and cost-effective emissions reductions for China over the course of this century.

  4. Low Cost Open-Path Instrument for Monitoring Surface Carbon Dioxide at Sequestration Sites Phase I SBIR Final Report

    SciTech Connect (OSTI)

    Sheng Wu

    2012-10-02T23:59:59.000Z

    Public confidence in safety is a prerequisite to the success of carbon dioxide (CO2) capture and storage for any program that intends to mitigate greenhouse gas emissions. In that regard, this project addresses the security of CO2 containment by undertaking development of what is called �¢����an open path device�¢��� to measure CO2 concentrations near the ground above a CO2 storage area.

  5. Capture of Carbon Dioxide Archived Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Services, Inc. Electric Power Research Institute Westinghouse Electric Corporation, Power Generation Business Unit 9141990 Advanced Emissions Control Development Program...

  6. Transportable Heavy Duty Emissions Testing Laboratory and Research Program

    SciTech Connect (OSTI)

    David Lyons

    2008-03-31T23:59:59.000Z

    The objective of this program was to quantify the emissions from heavy-duty vehicles operating on alternative fuels or advanced fuel blends, often with novel engine technology or aftertreatment. In the first year of the program West Virginia University (WVU) researchers determined that a transportable chassis dynamometer emissions measurement approach was required so that fleets of trucks and buses did not need to be ferried across the nation to a fixed facility. A Transportable Heavy-Duty Vehicle Emissions Testing Laboratory (Translab) was designed, constructed and verified. This laboratory consisted of a chassis dynamometer semi-trailer and an analytic trailer housing a full scale exhaust dilution tunnel and sampling system which mimicked closely the system described in the Code of Federal Regulations for engine certification. The Translab was first used to quantify emissions from natural gas and methanol fueled transit buses, and a second Translab unit was constructed to satisfy research demand. Subsequent emissions measurement was performed on trucks and buses using ethanol, Fischer-Tropsch fuel, and biodiesel. A medium-duty chassis dynamometer was also designed and constructed to facilitate research on delivery vehicles in the 10,000 to 20,000lb range. The Translab participated in major programs to evaluate low-sulfur diesel in conjunction with passively regenerating exhaust particulate filtration technology, and substantial reductions in particulate matter were recorded. The researchers also participated in programs to evaluate emissions from advanced natural gas engines with closed loop feedback control. These natural gas engines showed substantially reduced levels of oxides of nitrogen. For all of the trucks and buses characterized, the levels of carbon monoxide, oxides of nitrogen, hydrocarbons, carbon dioxide and particulate matter were quantified, and in many cases non-regulated species such as aldehydes were also sampled. Particle size was also quantified during selected studies. A laboratory was established at WVU to provide for studies which supported and augmented the Translab research, and to provide for development of superior emissions measurement systems. This laboratory research focused on engine control and fuel sulfur issues. In recent years, as engine and aftertreatment technologies advanced, emissions levels were reduced such that they were at or below the Translab detectable limits, and in the same time frame the US Environmental Protection Agency required improved measurement methodologies for engine emissions certification. To remain current and relevant, the researchers designed a new Translab analytic system, housed in a container which can be transported on a semi-trailer. The new system's dilution tunnel flow was designed to use a subsonic venturi with closed loop control of blower speed, and the secondary dilution and particulate matter filter capture were designed to follow new EPA engine certification procedures. A further contribution of the program has been the development of techniques for creating heavy-duty vehicle test schedules, and the creation of schedules to mimic a variety of truck and bus vocations.

  7. Comparative assessment of status and opportunities for carbon Dioxide Capture and storage and Radioactive Waste Disposal In North America

    SciTech Connect (OSTI)

    Oldenburg, C.; Birkholzer, J.T.

    2011-07-22T23:59:59.000Z

    Aside from the target storage regions being underground, geologic carbon sequestration (GCS) and radioactive waste disposal (RWD) share little in common in North America. The large volume of carbon dioxide (CO{sub 2}) needed to be sequestered along with its relatively benign health effects present a sharp contrast to the limited volumes and hazardous nature of high-level radioactive waste (RW). There is well-documented capacity in North America for 100 years or more of sequestration of CO{sub 2} from coal-fired power plants. Aside from economics, the challenges of GCS include lack of fully established legal and regulatory framework for ownership of injected CO{sub 2}, the need for an expanded pipeline infrastructure, and public acceptance of the technology. As for RW, the USA had proposed the unsaturated tuffs of Yucca Mountain, Nevada, as the region's first high-level RWD site before removing it from consideration in early 2009. The Canadian RW program is currently evolving with options that range from geologic disposal to both decentralized and centralized permanent storage in surface facilities. Both the USA and Canada have established legal and regulatory frameworks for RWD. The most challenging technical issue for RWD is the need to predict repository performance on extremely long time scales (10{sup 4}-10{sup 6} years). While attitudes toward nuclear power are rapidly changing as fossil-fuel costs soar and changes in climate occur, public perception remains the most serious challenge to opening RW repositories. Because of the many significant differences between RWD and GCS, there is little that can be shared between them from regulatory, legal, transportation, or economic perspectives. As for public perception, there is currently an opportunity to engage the public on the benefits and risks of both GCS and RWD as they learn more about the urgent energy-climate crisis created by greenhouse gas emissions from current fossil-fuel combustion practices.

  8. Carbon emissions and sequestration in forests: Case studies from seven developing countries. Volume 2, Greenhouse gas emissions from deforestration in the Brazilian Amazon

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J. [eds.] [Lawrence Berkeley Lab., CA (United States); Fearnside, P.M. [Instituto Nacional de Pesquisas da Amazonia (INPA), Manaus, AM (Brazil). Departmento de Ecologia

    1992-08-01T23:59:59.000Z

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as ``committed carbon,`` or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil`s use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  9. New Materials for Capturing Carbon Dioxide from Combustion Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed New Materials for Capturing Carbon Dioxide from Combustion Gases April 9, 2014 Bookmark and Share The SIFSIX materials in order of increasing...

  10. Carbon Dioxide Transport and Storage Costs in NETL Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Office of Program Performance and Benefits 2 Carbon Dioxide Transport and Storage Costs in NETL Studies Quality Guidelines for Energy System Studies May 2014...

  11. Carbon Dioxide Capture and Storage Demonstration in Developing...

    Open Energy Info (EERE)

    Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key Policy Issues and Barriers Jump to: navigation, search Tool Summary LAUNCH TOOL Name:...

  12. american carbon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of relative proximity of those Paris-Sud XI, Universit de 11 The Fluid Mechanics of Carbon Dioxide Sequestration Geosciences Websites Summary: The Fluid Mechanics of Carbon...

  13. anthropogenic carbon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dissolution in structural and stratigraphic traps MIT - DSpace Summary: The geologic sequestration of carbon dioxide (COsubscript 2) in structural and stratigraphic traps is...

  14. Gel and process for preventing carbon dioxide break through

    SciTech Connect (OSTI)

    Sandiford, B.B.; Zillmer, R.C.

    1987-06-16T23:59:59.000Z

    A process is described for retarding the flow of carbon dioxide in carbon dioxide break-through fingers in a subterranean formation, the process comprising: (a) introducing a gas selected from the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers; (b) after the carbon dioxide break-through fingers have sorbed a predetermined amount of the gas, stopping the flow of the gas into the subterranean formation, (c) after stopping the flow of the gas into the subterranean formation, introducing an effective amount of a gel-forming composition into the subterranean formation and into the carbon dioxide break-through fingers, the gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing the brine which has absorbed substantial amounts of carbon dioxide to form a gel in the fingers which is operable for retarding the flow of the gas in the finger. The gel-forming composition comprises: i. an aqueous solution comprising a first substance selected from the group consisting of polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, and ii. an amount of a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof.

  15. acute nitrogen dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas,...

  16. Elevated carbon dioxide flux at the Dixie Valley geothermal field...

    Open Energy Info (EERE)

    Elevated carbon dioxide flux at the Dixie Valley geothermal field, Nevada- relations between surface phenomena and the geothermal reservoir Jump to: navigation, search OpenEI...

  17. assisted silicon dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide substrates is described. The approach consists of solid such as displays and thin-film polycrystalline solar cells. Particularly important for low- cost thin-film solar...

  18. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Palo, Daniel; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-01T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, an Environmental Health and Safety (EH&S) Assessment was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment addressed air and particulate emissions as well as solid and liquid waste streams. The magnitude of the emissions and waste streams was estimated for evaluation purposes. EH&S characteristics of materials used in the system are also described. This document contains data based on the mass balances from both the 40 kJ/mol CO2 and 80 kJ/mol CO2 desorption energy cases evaluated in the Final Technical and Economic Feasibility study also conducted by Barr Engineering.

  19. Final Technical Report HFC Concrete: A Low-�������­���¢�������Energy, Carbon-�������­Dioxide-�������­Negative Solution for reducing Industrial Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dr. Larry McCandlish, Principal Investigator; Dr. Richard Riman, Co-Principal Investigator

    2012-05-14T23:59:59.000Z

    Solidia/CCSM received funding for further research and development of its Low Temperature Solidification Process (LTS), which is used to create hydrate-free concrete (HFC). LTS/HFC is a technology/materials platform that offers wide applicability in the built infrastructure. Most importantly, it provides a means of making concrete without Portland cement. Cement and concrete production is a major consumer of energy and source of industrial greenhouse gas (GHG) emissions. The primary goal of this project was to develop and commercialize a novel material, HFC, which by replacing traditional concrete and cement, reduces both energy use and GHG emissions in the built infrastructure. Traditional concrete uses Portland Cement (PC) as a binder. PC production involves calcination of limestone at {approx}1450 C, which releases significant amounts of CO{sub 2} gas to the atmosphere and consumes a large amount of energy due to the high temperature required. In contrast, HFC is a carbonate-based hydrate-free concrete (HFC) that consumes CO{sub 2} gas in its production. HFC is made by reaction of silicate minerals with CO{sub 2} at temperatures below 100 C, more than an order-of-magnitude below the temperature required to make PC. Because of this significant difference in temperature, it is estimated that we will be able to reduce energy use in the cement and concrete industry by up to 30 trillion Btu by 2020. Because of the insulating properties of HFC, we believe we will also be able to significantly reduce energy use in the Building sector, though the extent of this saving is not yet quantified. It is estimated that production of a tonne of PC-based concrete requires about 6.2 million Btu of energy and produces over 1 tonne of CO{sub 2} emissions (Choate, 2003). These can be reduced to 1.9 million Btu and 0.025 tonnes of CO{sub 2} emissions per tonne of HFC (with overall CO{sub 2}-negativity possible by increasing carbonation yield). In this way, by replacing PC-based concrete with HFC in infrastructure we can reduce energy use in concrete production by 70%, and reduce CO{sub 2} emissions by 98%; thus the potential to reduce the impact of building materials on global warming and climate change is highly significant. Low Temperature Solidification (LTS) is a breakthrough technology that enables the densification of inorganic materials via a hydrothermal process. The resulting product exhibits excellent control of chemistry and microstructure, to provide durability and mechanical performance that exceeds that of concrete or natural stone. The technology can be used in a wide range of applications including facade panels, interior tiles, roof tiles, countertops, and pre-cast concrete. Replacing traditional building materials and concrete in these applications will result in significant reduction in both energy consumption and CO{sub 2} emissions.

  20. Modeling Infinite Dilution and Fickian Diffusion Coefficients of Carbon Dioxide in Water

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Modeling Infinite Dilution and Fickian Diffusion Coefficients of Carbon Dioxide in Water J. Wambui infinite dilution diffusion coefficients for carbon dioxide and water mixtures. The model takes, carbon dioxide, classical thermodynamics Introduction The increase in atmospheric concentrations of CO2

  1. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  2. Carbon emissions and sequestration in forests: Case studies from seven developing countries

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J. (eds.) (Lawrence Berkeley Lab., CA (United States)); Fearnside, P.M. (Instituto Nacional de Pesquisas da Amazonia (INPA), Manaus, AM (Brazil). Departmento de Ecologia)

    1992-08-01T23:59:59.000Z

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as committed carbon,'' or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil's use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  3. Apparatus for extracting and sequestering carbon dioxide

    DOE Patents [OSTI]

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2010-02-02T23:59:59.000Z

    An apparatus and method associated therewith to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said apparatus hydrates CO.sub.2 and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  4. Method for extracting and sequestering carbon dioxide

    DOE Patents [OSTI]

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2005-05-10T23:59:59.000Z

    A method and apparatus to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said method and apparatus hydrates CO.sub.2, and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  5. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeeding access toTest andOptimize carbon dioxide sequestration, enhance oil

  6. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  7. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    lower greenhouse gas emissions from electricity productionAssessment of Greenhouse Gas Emissions from Plug-in Hybridof national greenhouse gas emissions. Both motor vehicle

  8. Carbon Dioxide Capture and Transportation Options in the Illinois Basin

    SciTech Connect (OSTI)

    M. Rostam-Abadi; S. S. Chen; Y. Lu

    2004-09-30T23:59:59.000Z

    This report describes carbon dioxide (CO{sub 2}) capture options from large stationary emission sources in the Illinois Basin, primarily focusing on coal-fired utility power plants. The CO{sub 2} emissions data were collected for utility power plants and industrial facilities over most of Illinois, southwestern Indiana, and western Kentucky. Coal-fired power plants are by far the largest CO{sub 2} emission sources in the Illinois Basin. The data revealed that sources within the Illinois Basin emit about 276 million tonnes of CO2 annually from 122 utility power plants and industrial facilities. Industrial facilities include 48 emission sources and contribute about 10% of total emissions. A process analysis study was conducted to review the suitability of various CO{sub 2} capture technologies for large stationary sources. The advantages and disadvantages of each class of technology were investigated. Based on these analyses, a suitable CO{sub 2} capture technology was assigned to each type of emission source in the Illinois Basin. Techno-economic studies were then conducted to evaluate the energy and economic performances of three coal-based power generation plants with CO{sub 2} capture facilities. The three plants considered were (1) pulverized coal (PC) + post combustion chemical absorption (monoethanolamine, or MEA), (2) integrated gasification combined cycle (IGCC) + pre-combustion physical absorption (Selexol), and (3) oxygen-enriched coal combustion plants. A conventional PC power plant without CO2 capture was also investigated as a baseline plant for comparison. Gross capacities of 266, 533, and 1,054 MW were investigated at each power plant. The economic study considered the burning of both Illinois No. 6 coal and Powder River Basin (PRB) coal. The cost estimation included the cost for compressing the CO{sub 2} stream to pipeline pressure. A process simulation software, CHEMCAD, was employed to perform steady-state simulations of power generation systems and CO{sub 2} capture processes. Financial models were developed to estimate the capital cost, operations and maintenance cost, cost of electricity, and CO{sub 2} avoidance cost. Results showed that, depending on the plant size and the type of coal burned, CO{sub 2} avoidance cost is between $47/t to $67/t for a PC +MEA plant, between $22.03/t to $32.05/t for an oxygen combustion plant, and between $13.58/t to $26.78/t for an IGCC + Selexol plant. A sensitivity analysis was conducted to evaluate the impact on the CO2 avoidance cost of the heat of absorption of solvent in an MEA plant and energy consumption of the ASU in an oxy-coal combustion plant. An economic analysis of CO{sub 2} capture from an ethanol plant was also conducted. The cost of CO{sub 2} capture from an ethanol plant with a production capacity of 100 million gallons/year was estimated to be about $13.92/t.

  9. ammonia-water-carbon dioxide mixtures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and n-pentane - n-octane - carbon dioxide... Wirawan, Januar Fitri Santo 2012-06-07 4 Carbon dioxide sequestration in concrete in different curing environments Engineering...

  10. NUMERICAL INVESTIGATION OF TEMPERATURE EFFECTS DURING THE INJECTION OF CARBON DIOXIDE INTO BRINE

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    reservoir scenario. 1. INTRODUCTION Recent investigations of underground carbon dioxide storage for the simulation of carbon dioxide injection into geological formations is currently an intensive field of research

  11. actinide-zirconium dioxide solid-solutions: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Exergy analysis of transcritical carbon dioxide refrigeration cycle with an expander Jun Lan Yang is performed for the transcritical carbon dioxide refrigeration...

  12. Development of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle

    E-Print Network [OSTI]

    Zimmer, Uwe

    stage to prevent potential danger to workforce and material, and carbon capture and sequestration (CCSDevelopment of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle Florian Poppa and Uwe the development of a carbon dioxide (CO2) sensing rotorcraft unmanned aerial vehicle (RUAV) and the experiences

  13. Method for synthesis of titanium dioxide nanotubes using ionic liquids

    DOE Patents [OSTI]

    Qu, Jun; Luo, Huimin; Dai, Sheng

    2013-11-19T23:59:59.000Z

    The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

  14. Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    i Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Topical Report Prepared Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Ross Edward Dugas, M capture using monoethanolamine (MEA). MEA is an appropriate choice for a baseline study since

  15. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

  16. Carbon Dioxide Capture DOI: 10.1002/anie.200902836

    E-Print Network [OSTI]

    Paik Suh, Myunghyun

    Carbon Dioxide Capture DOI: 10.1002/anie.200902836 Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks** Hye-Sun Choi and Myunghyun Paik Suh* Carbon dioxide capture has been warming, and the development of efficient methods for capturing CO2 from industrial flue gas has become

  17. Carbon Dioxide Capture DOI: 10.1002/anie.201000431

    E-Print Network [OSTI]

    ] Carbon capture and storage (CCS) schemes embody a group of technologies for the capture of CO2 from powerCarbon Dioxide Capture DOI: 10.1002/anie.201000431 Carbon Dioxide Capture: Prospects for New- and gas-fired power plants.[3­5] Such conven- tional technologies for large-scale capture have been com

  18. Carbon dioxide sequestration in concrete in different curing environments

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Carbon dioxide sequestration in concrete in different curing environments Y.-m. Chun, T.R. Naik, USA ABSTRACT: This paper summarizes the results of an investigation on carbon dioxide (CO2) sequestration in concrete. Concrete mixtures were not air entrained. Concrete mixtures were made containing

  19. ORNL/CDIAC-34 Carbon Dioxide Information Analysis Center and

    E-Print Network [OSTI]

    Research U.S. Department of Energy Budget Activity Number KP 12 04 01 0 Prepared by the Carbon Dioxide. Burtis Carbon Dioxide Information Analysis Center Environmental Sciences Division Publication No. 4777's (DOE) Environmental Sciences Division, Office of Biological and Environmental Research (OBER

  20. RESEARCH ARTICLE Open Access Intratracheally administered titanium dioxide or

    E-Print Network [OSTI]

    Boyer, Edmond

    RESEARCH ARTICLE Open Access Intratracheally administered titanium dioxide or carbon black,2,5,6* Abstract Background: Titanium dioxide (TiO2) and carbon black (CB) nanoparticles (NPs) have biological a particle's size to the nanometric dimension can greatly modify its properties for applications

  1. The Subsurface Fluid Mechanics of Geologic Carbon Dioxide Storage

    E-Print Network [OSTI]

    The Subsurface Fluid Mechanics of Geologic Carbon Dioxide Storage by Michael Lawrence Szulczewski S Mechanics of Geologic Carbon Dioxide Storage by Michael Lawrence Szulczewski Submitted to the Department capture and storage (CCS), CO2 is captured at power plants and then injected into deep geologic reservoirs

  2. Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear"

    E-Print Network [OSTI]

    Rust, Bert W.

    Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear" Bert W. Rust Mathematical- tioned the connection between global warming and increasing atmospheric carbon dioxide by pointing out of these plots to global warming have spilled over to the real world, inviting both praise [4, 17] and scorn [15

  3. Hyperparameter estimation for uncertainty quantification in mesoscale carbon dioxide inversions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hyperparameter estimation for uncertainty quantification in mesoscale carbon dioxide inversions-validation (GCV) and x2 test are compared for the first time under a realistic setting in a mesoscale CO2 estimation, uncertainty quantification, mesoscale carbon dioxide inversions 1. Introduction The atmosphere

  4. Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall loading. The absorption rate did not follow pseudo first-order beha®ior except at ®ery low loading. All

  5. Updated State Air Emissions Regulations (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01T23:59:59.000Z

    The Regional Greenhouse Gas Initiative (RGGI) is a program that includes 10 Northeast states that have agreed to curtail and reverse growth in their carbon dioxide (CO2) emissions. The RGGI program includes all electricity generating units with a capacity of at least 25 megawatts and requires an allowance for each ton of CO2 emitted. The first year of mandatory compliance was in 2009.

  6. acromegaly remains under-recognized: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bees 144 Voices from the Small Cinemas: Beyond the Remaining Countries University of Kansas - KU ScholarWorks Summary: This introduction to a special volume dedicated to...

  7. Decontamination and Management of Human Remains Following Incidents of Hazardous Chemical Release

    SciTech Connect (OSTI)

    Hauschild, Veronique [U.S. Army Public Health Command; Watson, Annetta Paule [ORNL; Bock, Robert Eldon [ORNL

    2012-01-01T23:59:59.000Z

    Abstract Objective: To provide specific procedural guidance and resources for identification, assessment, control, and mitigation of compounds that may contaminate human remains resulting from chemical attack or release. Design: A detailed technical, policy, and regulatory review is summarized. Setting: Guidance is suitable for civilian or military settings where human remains potentially contaminated with hazardous chemicals may be present. Settings would include sites of transportation accidents, natural disasters, terrorist or military operations, mortuary affairs or medical examiner processing and decontamination points, and similar. Patients, Participants: While recommended procedures have not been validated with actual human remains, guidance has been developed from data characterizing controlled experiments with fabrics, materiel, and laboratory animals. Main Outcome Measure(s): Presentation of logic and specific procedures for remains management, protection and decontamination of mortuary affairs personnel, as well as decision criteria for determining when remains are sufficiently decontaminated so as to pose no chemical health hazard. Results: Established procedures and existing equipment/materiel available for decontamination and verification provide appropriate and reasonable means to mitigate chemical hazards from remains. Extensive characterization of issues related to remains decontamination indicates that supra-lethal concentrations of liquid chemical warfare agent VX may prove difficult to decontaminate and verify in a timely fashion. Specialized personnel can and should be called upon to assist with monitoring necessary to clear decontaminated remains for transport and processing. Conclusions: Once appropriate decontamination and verification have been accomplished, normal procedures for remains processing and transport to the decedent s family and the continental United States can be followed.

  8. Carbon dioxide absorbent and method of using the same

    DOE Patents [OSTI]

    Perry, Robert James (Niskayuna, NY); Lewis, Larry Neil (Scotia, NY); O'Brien, Michael Joseph (Clifton Park, NY); Soloveichik, Grigorii Lev (Latham, NY); Kniajanski, Sergei (Clifton Park, NY); Lam, Tunchiao Hubert (Clifton Park, NY); Lee, Julia Lam (Niskayuna, NY); Rubinsztajn, Malgorzata Iwona (Ballston Spa, NY)

    2011-10-04T23:59:59.000Z

    In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

  9. Assessing the Effect of Timing of Availability for Carbon Dioxide Storage in the Largest Oil and Gas Pools in the Alberta Basin: Description of Data and Methodology

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Bachu, Stefan

    2007-03-05T23:59:59.000Z

    Carbon dioxide capture from large stationary sources and storage in geological media is a technologically-feasible mitigation measure for the reduction of anthropogenic emissions of CO2 to the atmosphere in response to climate change. Carbon dioxide (CO2) can be sequestered underground in oil and gas reservoirs, in deep saline aquifers, in uneconomic coal beds and in salt caverns. The Alberta Basin provides a very large capacity for CO2 storage in oil and gas reservoirs, along with significant capacity in deep saline formations and possible unmineable coal beds. Regional assessments of potential geological CO2 storage capacity have largely focused so far on estimating the total capacity that might be available within each type of reservoir. While deep saline formations are effectively able to accept CO2 immediately, the storage potential of other classes of candidate storage reservoirs, primarily oil and gas fields, is not fully available at present time. Capacity estimates to date have largely overlooked rates of depletion in these types of storage reservoirs and typically report the total estimated storage capacity that will be available upon depletion. However, CO2 storage will not (and cannot economically) begin until the recoverable oil and gas have been produced via traditional means. This report describes a reevaluation of the CO2 storage capacity and an assessment of the timing of availability of the oil and gas pools in the Alberta Basin with very large storage capacity (>5 MtCO2 each) that are being looked at as likely targets for early implementation of CO2 storage in the region. Over 36,000 non-commingled (i.e., single) oil and gas pools were examined with effective CO2 storage capacities being individually estimated. For each pool, the life expectancy was estimated based on a combination of production decline analysis constrained by the remaining recoverable reserves and an assessment of economic viability, yielding an estimated depletion date, or year that it will be available for CO2 storage. The modeling framework and assumptions used to assess the impact of the timing of CO2 storage resource availability on the region’s deployment of CCS technologies is also described. The purpose of this report is to describe the data and methodology for examining the carbon dioxide (CO2) storage capacity resource of a major hydrocarbon province incorporating estimated depletion dates for its oil and gas fields with the largest CO2 storage capacity. This allows the development of a projected timeline for CO2 storage availability across the basin and enables a more realistic examination of potential oil and gas field CO2 storage utilization by the region’s large CO2 point sources. The Alberta Basin of western Canada was selected for this initial examination as a representative mature basin, and the development of capacity and depletion date estimates for the 227 largest oil and gas pools (with a total storage capacity of 4.7 GtCO2) is described, along with the impact on source-reservoir pairing and resulting CO2 transport and storage economics. The analysis indicates that timing of storage resource availability has a significant impact on the mix of storage reservoirs selected for utilization at a given time, and further confirms the value that all available reservoir types offer, providing important insights regarding CO2 storage implementation to this and other major oil and gas basins throughout North America and the rest of the world. For CCS technologies to deploy successfully and offer a meaningful contribution to climate change mitigation, CO2 storage reservoirs must be available not only where needed (preferably co-located with or near large concentrations of CO2 sources or emissions centers) but also when needed. The timing of CO2 storage resource availability is therefore an important factor to consider when assessing the real opportunities for CCS deployment in a given region.

  10. The Implications of a Gasoline Price Floor for the California Budget and Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Borenstein, Severin

    2008-01-01T23:59:59.000Z

    Emissions Surcharge Revenues Oil Price Price elas= -0.1 elasEmissions Surcharge Revenues Oil Price Price elas= -0.1 elasotherwise result if oil prices remain at current levels. . o

  11. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    COMPACT EMISSIONS HEV PHEV marginal power plant is a coalpower uses relatively little coal, but in other cases emissions

  12. An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries

    E-Print Network [OSTI]

    Pedram, Massoud

    An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng cycle-life tends to shrink significantly. The capacities of commercial lithium-ion batteries fade by 10 prediction model to estimate the remaining capacity of a Lithium-Ion battery. The proposed analytical model

  13. PREDICTION OF REMAINING LIFE OF POWER TRANSFORMERS BASED ON LEFT TRUNCATED AND RIGHT

    E-Print Network [OSTI]

    PREDICTION OF REMAINING LIFE OF POWER TRANSFORMERS BASED ON LEFT TRUNCATED AND RIGHT CENSORED of the remaining life of high-voltage power transform- ers is an important issue for energy companies because of the need for planning maintenance and capital expenditures. Lifetime data for such transformers

  14. Fish remains (Elasmobranchii, Actinopterygii) from the Late Cretaceous of1 the Benue Trough, Nigeria2

    E-Print Network [OSTI]

    Fish remains (Elasmobranchii, Actinopterygii) from the Late Cretaceous of1 the Benue Trough address: romain.vullo@univ-rennes1.fr9 10 Abstract11 Selachian and ray-finned fish remains from various Cenomanian­early Turonian and25 Maastrichtian) created opportunities for the dispersal of many marine fish

  15. 14 April 2001 tmospheric carbon dioxide

    E-Print Network [OSTI]

    Teskey, Robert O.

    emissions is through increased carbon sequestration into forests. In a large-scale assessment, Birdsey- ing carbon sequestration in southern forests. Carbon sequestration via southern pine forests may policy commitments. Keywords: carbon sequestration; southern pine forests ABSTRACT MEETING GLOBAL POLICY

  16. Geothermal carbon dioxide for use in greenhouses

    SciTech Connect (OSTI)

    Dunstall, M.G. [Univ. of Auckland (New Zealand); Graeber, G. [Univ. of Stuttgart (Germany)

    1997-01-01T23:59:59.000Z

    Geothermal fluids often contain carbon dioxide, which is a very effective growth stimulant for plants in greenhouses. Studies have shown that as CO{sub 2} concentration is increased from a normal level of 300 ppm (mmol/kmol) to levels of approximately 1000 ppm crop yields may increase by up to 15% (Ullmann`s Encyclopedia of Industrial Chemistry, 1989). It is suggested that geothermal greenhouse heating offers a further opportunity for utilization of the carbon dioxide present in the fluid. The main difficulty is that plants react adversely to hydrogen sulphide which is invariably mixed, at some concentration, with the CO{sub 2} from geothermal fluids. Even very low H{sub 2}S concentrations of 0.03 mg/kg can have negative effects on the growth of plants (National Research Council, 1979). Therefore, an appropriate purification process for the CO{sub 2} must be used to avoid elevated H{sub 2}S levels in the greenhouses. The use of adsorption and absorption processes is proposed. Two purification processes have been modelled using the ASOEN PLUS software package, using the Geothermal Greenhouses Ltd. Operation Kawerau New Zealand and an example. A greenhouse area of 8,000 m{sup 2}, which would create a demand for approximately 20 kg CO{sub 2} per hour, was chosen based on a proposed expansion at Kawerau. The Kawerau operation currently takes geothermal steam (and gas) from a high temperature 2-phase well to heat an area of 1650 m{sup 2}. Bottled carbon dioxide is utilized at a rate of about 50 kg per day, to provide CO{sub 2} levels of 800 mg/kg when the greenhouse is closed and 300 to 350 mg/kg whilst venting. In England and the Netherlands, CO{sub 2} levels of 1000 mg/kg are often used (Ullmann`s Encyclopedia of Industrial Chemistry, 1989) and similar concentrations are desired at Kawerau, but current costs of 0.60 NZ$/kg for bottled CO{sub 2} are too high (Foster, 1995).

  17. PUBLISHED ONLINE: 31 JULY 2011 | DOI: 10.1038/NGEO1211 Carbon emission from hydroelectric reservoirs

    E-Print Network [OSTI]

    LETTERS PUBLISHED ONLINE: 31 JULY 2011 | DOI: 10.1038/NGEO1211 Carbon emission from hydroelectric * Hydroelectric reservoirs cover an area of 3.4 Ã? 105 km2 and comprise about 20% of all reservoirs. In addition dioxide and methane from hydroelectric reservoirs, on the basis of data from 85 globally distributed

  18. CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING

    E-Print Network [OSTI]

    CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING in strategies for climate protection. 1. Introduction Carbon sequestration has been highlighted recently concentration of carbon dioxide (CO2) in the atmo- sphere include sequestering carbon (C) in soils

  19. e are hearing a lot these days about carbon emissions and

    E-Print Network [OSTI]

    Sherwood, Steven

    that solar energy into a rela- tively small volume can raise its temper- ature quite a bit, even on a cold of climate change or global warming. The basic problem, we are told, is the carbon dioxide that is released carbon emissions is overblown? To answer that we need to understand what are called climate forcings

  20. U.S. EPA State Carbon Emissions Goals Georgia Fact Sheet

    E-Print Network [OSTI]

    Das, Suman

    reducing power generation from existing coal power plants. This is proposed as an existing power plant carbon dioxide emission 2030 state goals for electric power plants. These goals vary widely from state power plant efficiencies by 6%; 2. More fully utilizing existing natural gas power plants and thereby

  1. Economic Potential of Greenhouse Gas Emission Reductions: Comparative Role for Soil Sequestration in Agriculture and Forestry

    E-Print Network [OSTI]

    McCarl, Bruce A.

    for presentation at DOE First National Conference on Carbon Sequestration, May 14-17, 2001, Washington D.C. #12 sequestration generally refers to the absorption of carbon dioxide from the atmosphere through photosyntheticEconomic Potential of Greenhouse Gas Emission Reductions: Comparative Role for Soil Sequestration

  2. Science Highlight March 2010 Schematic drawing of the setup for x-ray emission spectroscopy

    E-Print Network [OSTI]

    Wechsler, Risa H.

    foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizingScience Highlight ­ March 2010 Schematic drawing of the setup for x-ray emission spectroscopy of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contrib- utes

  3. Gaseous and particulate emissions from a DC arc melter

    SciTech Connect (OSTI)

    Overcamp, T.J.; Speer, M.P.; Griner, S.J.; Cash, D.M. [Clemson Univ., Anderson, SC (United States)

    1997-12-31T23:59:59.000Z

    This paper presents the results of the gaseous and particulate emissions from eight experimental tests of a DC arc melter to treat simulated Savannah River soils contaminated with metals, surrogates for radionuclides, and organic debris. The gaseous analyses reported on the concentrations of oxygen, hydrogen, carbon monoxide, carbon dioxide, hydrogen, methane, nitric oxide, and nitrogen dioxide. The carbon dioxide concentration was high for all runs. For the runs with an air purge, the carbon monoxide concentration ranged up to 10% in the runs with the debris and 2% in the runs without debris. Hydrogen ranged up to 5% by with debris and up to 1% without debris. The methane concentration ranged up to 7,000 ppm{sub v} for the runs with debris and 2,000 ppm for the runs without debris. With a nitrogen purge, oxygen concentrations were less than 1%. The carbon dioxide concentrations ranged from 3 to 15%. Much of this carbon dioxide was probably due the carbonates added to the feed material. The carbon monoxide concentration ranged up to 20% with the debris and 7% without debris. Hydrogen was above 6% in with debris and up to 6% without debris. The methane concentration ranged up to 10,000 ppm{sub v} with debris and 4,000 ppm{sub v} without debris. The particulate concentrations exiting ranged from 32 to 145 g/m{sup 3}. From the chemical analyses, the primary elements were silicon and calcium. The CHN analyses indicated that carbon, probably as carbonates, are an additional component in the particulate matter. The estimated emissions were at a level of 3% or less for cerium, up to 7% for nickel, and 11 to 30% for cesium.

  4. Speaker to Address Impact of Natural Gas Production on Greenhouse Gas Emissions When used for power generation, Marcellus Shale natural gas can significantly reduce carbon

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    generation, Marcellus Shale natural gas can significantly reduce carbon dioxide emissions, but questions have been raised whether development of shale gas resources results in an overall lower greenhouse gas, "Life Cycle Greenhouse Gas Emissions of Marcellus Shale Gas," appeared in Environmental Research Letters

  5. Ebullitive methane emissions from oxygenated wetland J O H N T . C R A W F O R D 1 , 2

    E-Print Network [OSTI]

    Stanley, Emily

    , University of Minnesota, St. Paul, MN 55108, USA Abstract Stream and river carbon dioxide emissions are an important component of the global carbon cycle. Methane emis- sions from streams could also contribute methane emissions. Furthermore, the available data do not typically include the ebullitive (bubble

  6. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01T23:59:59.000Z

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  7. Molten uranium dioxide structure and dynamics

    SciTech Connect (OSTI)

    Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

    2014-11-20T23:59:59.000Z

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

  8. Molten uranium dioxide structure and dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

    2014-11-20T23:59:59.000Z

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

  9. Layered solid sorbents for carbon dioxide capture

    SciTech Connect (OSTI)

    Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

    2014-11-18T23:59:59.000Z

    A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

  10. Helium Migration Mechanisms in Polycrystalline Uranium Dioxide

    SciTech Connect (OSTI)

    Martin, Guillaume; Desgardin, Pierre; Sauvage, Thierry; Barthe, Marie-France [CERI, CNRS, 3 A rue de la Ferollerie, ORLEANS, 45071 (France); Garcia, Philippe; Carlot, Gaelle [DEN/DEC/SESC/LLCC, CEA Cadarache, Saint Paul Lez Durance, 13108 (France)

    2007-07-01T23:59:59.000Z

    This study aims at identifying the release mechanisms of helium in uranium dioxide. Two sets of polycrystalline UO{sub 2} sintered samples presenting different microstructures were implanted with {sup 3}He ions at concentrations in the region of 0.1 at.%. Changes in helium concentrations were monitored using two Nuclear Reaction Analysis (NRA) techniques based on the {sup 3}He(d,{alpha}){sup 1}H reaction. {sup 3}He release is measured in-situ during sample annealing at temperatures ranging between 700 deg. C and 1000 deg. C. Accurate helium depth profiles are generated after each annealing stage. Results that provide data for further understanding helium release mechanisms are discussed. It is found that helium diffusion appears to be enhanced above 900 deg. C in the vicinity of grain boundaries possibly as a result of the presence of defects. (authors)

  11. Carbon Dioxide Sequestration in Geologic Coal Formations

    SciTech Connect (OSTI)

    None

    2001-09-30T23:59:59.000Z

    BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

  12. Molten uranium dioxide structure and dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skinner, L. B.; Parise, J. B.; Benmore, C. J.; Weber, J. K.R.; Williamson, M. A.; Tamalonis, A.; Hebden, A.; Wiencek, T.; Alderman, O. L.G.; Guthrie, M.; et al

    2014-11-20T23:59:59.000Z

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. Onmore »melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.« less

  13. Coiled tubing drilling with supercritical carbon dioxide

    DOE Patents [OSTI]

    Kolle , Jack J. (Seattle, WA)

    2002-01-01T23:59:59.000Z

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  14. Electrochemical Membrane for Carbon Dioxide Separation and Power Generation

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Hunt, Jennifer; Patel, Dilip; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

    2012-12-28T23:59:59.000Z

    uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric power while capturing CO2 from flue gas, such as from an existing pulverized coal (PC) plant. Laboratory scale testing of the ECM has verified the feasibility of the technology for CO2 separation from simulated flue gases of PC plants as well as combined cycle power plants and other industrial facilities. Recently, FCE was awarded a contract (DE-FE0007634) from the U.S. Department of Energy to evaluate the use of ECM to efficiently and cost effectively separate CO2 from the emissions of existing coal fired power plants. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of an existing PC plant with no more than 35% increase in the cost of electricity (COE) produced by the plant. The specific objectives and related activities planned for the project include: 1) conduct bench scale tests of a planar membrane assembly consisting of ten or more cells of about 0.8 m2 area each, 2) develop the detailed design for an ECM-based CO2 capture system applied to an existing PC plant, and 3) evaluate the effects of impurities (pollutants such as SO2, NOx, Hg) present in the coal plant flue gas by conducting laboratory scale performance tests of the membrane. The results of this project are anticipated to demonstrate that the ECM is an advanced technology, fabricated from inexpensive materials, based on proven operational track records, modular, scalable to large sizes, and a viable candidate for >90% carbon capture from existing PC plants. In this paper, the fundamentals of ECM technology including: material of construction, principal mechanisms of operation, carbon capture test results and the benefits of applications to PC plants will be presented.

  15. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

    1981-01-01T23:59:59.000Z

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  16. Evaluating greenhouse gas emissions from hydropower complexes on large rivers in Eastern Washington

    SciTech Connect (OSTI)

    Arntzen, Evan V.; Miller, Benjamin L.; O'Toole, Amanda C.; Niehus, Sara E.; Richmond, Marshall C.

    2013-03-15T23:59:59.000Z

    Water bodies, such as freshwater lakes, are known to be net emitters of carbon dioxide (CO2), and methane (CH4). In recent years, significant greenhouse gas (GHG) emissions from tropical, boreal, and mid-latitude reservoirs have been reported. At a time when hydropower is increasing worldwide, better understanding of seasonal and regional variation in GHG emissions is needed in order to develop a predictive understanding of such fluxes within man-made impoundments. We examined power-producing dam complexes within xeric temperate locations in the northwestern United States. Sampling environments on the Snake (Lower Monumental Dam Complex) and Columbia Rivers (Priest Rapids Dam Complex) included tributary, mainstem, embayment, forebay, and tailrace areas during winter and summer 2012. At each sampling location, GHG measurement pathways included surface gas flux, degassing as water passed through dams during power generation, ebullition within littoral embayments, and direct sampling of hyporheic pore-water. Measurements were also carried out in a free-flowing reach of the Columbia River to estimate unaltered conditions. Surface flux resulted in very low emissions, with reservoirs acting as a sink for CO2 (up to –262 mg m-2 d-1, which is within the range previously reported for similarly located reservoirs). Surface flux of methane remained below 1 mg CH4 m-2d-1, a value well below fluxes reported previously for temperate reservoirs. Water passing through hydroelectric projects acted as a sink for CO2 during winter and a small source during summer, with mean degassing fluxes of –117 and 4.5 t CO2 d-1, respectively. Degassing of CH4 was minimal, with mean fluxes of 3.1 × 10-6 and –5.6 × 10-4 t CH4 d-1 during winter and summer, respectively. Gas flux due to ebullition was greater in coves located within reservoirs than in coves within the free flowing Hanford Reach–and CH4 flux exceeded that of CO2. Methane emissions varied widely across sampling locations, ranging from 10.5 to 1039 mg CH4 m-2 d-1, with mean fluxes of 324 mg CH4 m-2 d-1in Lower Monumental Dam reservoir and 482 mg CH4 m-2d-1 in the Priest Rapids Dam reservoir. The magnitude of methane flux due to ebullition was unexpectedly high, and falls within the range recently reported for other temperate reservoirs around the world, further suggesting that this methane source should be considered in estimates of global greenhouse gas emissions. Methane flux from sediment pore-water within littoral embayments averaged 4.2 mg m-2 d-1 during winter and 8.1 mg m-2 d-1 during summer, with a peak flux of 19.8 mg m-2d-1 (at the same location where CH4 ebullition was also the greatest). Carbon dioxide flux from sediment pore-water averaged approximately 80 mg m-2d-1 with little difference between winter and summer. Similar to emissions from ebullition, flux from sediment pore-water was higher in reservoirs than in the free flowing reach.

  17. Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.; Viani, Brian

    2013-01-29T23:59:59.000Z

    A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

  18. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    NONE

    1995-09-25T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  19. Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry

    Broader source: Energy.gov [DOE]

    "This report contains information on Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry, prepared for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Weatherization and Intergovernmental Program."

  20. Comparative analysis of remaining oil saturation in waterflood patterns based on analytical modeling and simulation 

    E-Print Network [OSTI]

    Azimov, Anar Etibar

    2006-08-16T23:59:59.000Z

    In assessing the economic viability of a waterflood project, a key parameter is the remaining oil saturation (ROS) within each pattern unit. This information helps in identifying the areas with the highest ROS and thus ...

  1. Taphonomy of the faunal remains of a rural roman farmsite, San Giovanni di Ruoti, Italy

    E-Print Network [OSTI]

    Hunter, Cristi Assad

    1986-01-01T23:59:59.000Z

    Hunter, B. A. , California State University at Sacramento Chairman of Advisory Committee: Dr. D. Gentry Steele The faunal remains from a rural Roman farmsite, San Giovanni di Ruoti, Italy, were used to perform a taphonomic analysis. The goal... remains. The taphonomic analysis included examination of the pig skeletal element representation, identification of the specific agents that modify bone, identification of the butchering techniques used at the site, and documentation of possible...

  2. ambient sulfur dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17...

  3. Sulfur Dioxide Treatment from Flue Gases Using a Biotrickling

    E-Print Network [OSTI]

    ), and several episodes in London (1). All fuels used by humans such as coal, oil, natural gas, peat, wood of absorbing sulfur dioxide either in water or in aqueous slurries

  4. Mechanisms for mechanical trapping of geologically sequestered carbon dioxide

    E-Print Network [OSTI]

    Cohen, Yossi

    Carbon dioxide (CO[subscript 2]) sequestration in subsurface reservoirs is important for limiting atmospheric CO[subscript 2] concentrations. However, a complete physical picture able to predict the structure developing ...

  5. Control strategies for supercritical carbon dioxide power conversion systems

    E-Print Network [OSTI]

    Carstens, Nathan, 1978-

    2007-01-01T23:59:59.000Z

    The supercritical carbon dioxide (S-C02) recompression cycle is a promising advanced power conversion cycle which couples well to numerous advanced nuclear reactor designs. This thesis investigates the dynamic simulation ...

  6. aqueous chlorine dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    28 Standard test methods for analysis of sintered gadolinium oxide-uranium dioxide pellets CERN Preprints Summary: 1.1 These test methods cover procedures for the analysis of...

  7. Electrochemically-mediated amine regeneration for carbon dioxide separations

    E-Print Network [OSTI]

    Stern, Michael C. (Michael Craig)

    2014-01-01T23:59:59.000Z

    This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

  8. Ownership of Carbon Dioxide Captured by Clean Coal Project (Texas)

    Broader source: Energy.gov [DOE]

    This legislation stipulates that the Railroad Commission of Texas automatically acquires the title to any carbon dioxide captured by a clean coal project in the state. The Bureau of Economic...

  9. Comment on "An optimized potential for carbon dioxide"

    E-Print Network [OSTI]

    Merker, T; Hasse, H

    2009-01-01T23:59:59.000Z

    A molecular model for carbon dioxide is assessed regarding vapor-liquid equilibrium properties. Large deviations, being above 15 %, are found for vapor pressure and saturated vapor density in the entire temperature range.

  10. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

    1991-09-03T23:59:59.000Z

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  11. Optical properties of nanostructured silicon-rich silicon dioxide

    E-Print Network [OSTI]

    Stolfi, Michael Anthony

    2006-01-01T23:59:59.000Z

    We have conducted a study of the optical properties of sputtered silicon-rich silicon dioxide (SRO) thin films with specific application for the fabrication of erbium-doped waveguide amplifiers and lasers, polarization ...

  12. Radiocarbon Dioxide detection based on Cavity Ring-Down Spectroscopy and a Quantum Cascade Laser

    E-Print Network [OSTI]

    Genoud, Guillaume; Phillips, Hilary; Dean, Julian; Merimaa, Mikko

    2015-01-01T23:59:59.000Z

    Monitoring of radiocarbon ($^{14}$C) in carbon dioxide is demonstrated using mid-infrared spectroscopy and a quantum cascade laser. The measurement is based on cavity ring-down spectroscopy, and a high sensitivity is achieved with a simple setup. The instrument was tested using a standardised sample containing elevated levels of radiocarbon. Radiocarbon dioxide could be detected from samples with an isotopic ratio $^{14}$C/C as low as 50 parts-per-trillion, corresponding to an activity of 5 kBq/m$^3$ in pure CO$_2$, or 2 Bq/m$^3$ in air after extraction of the CO$_2$ from an air sample. The instrument is simple, compact and robust, making it the ideal tool for on-site measurements. It is aimed for monitoring of radioactive gaseous emissions in nuclear power environment, during the operation and decommissioning of nuclear power plants. Its high sensitivity also makes it the ideal tool for the detection of leaks in radioactive waste repositories.

  13. Tethered catalysts for the hydration of carbon dioxide

    DOE Patents [OSTI]

    Valdez, Carlos A; Satcher, Jr., Joe H; Aines, Roger D; Wong, Sergio E; Baker, Sarah E; Lightstone, Felice C; Stolaroff, Joshuah K

    2014-11-04T23:59:59.000Z

    A system is provided that substantially increases the efficiency of CO.sub.2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.

  14. Making appropriate comparisons of estimated and actual costs of reducing SO{sub 2} emissions under Title IV

    SciTech Connect (OSTI)

    Smith, A.E. [DFI/Aeronomics Inc., Washington, DC (United States)

    1998-12-31T23:59:59.000Z

    A current sentiment within some parts of the environmental policy community is that market-based regulatory approaches such as emissions trading have proven so effective that actual costs will be only a small fraction of what ex ante cost estimation procedures would project. With this line of reasoning, some have dismissed available cost estimates for major proposed new regulations, such as the new PM and ozone NAAQS, as not meaningful for policy decisions. The most commonly used evidence in support of this position is the experience with SO{sub 2} reductions under Title IV of the 1990 Clean Air Act Amendments. In Title IV, a market for emissions allowances has been used to achieve reductions in sulfur dioxides (SO{sub 2}) to ameliorate acid rain. It is commonly asserted today that the cost of achieving the SO{sub 2} emissions reductions has been only one-tenth or less of what Title IV was originally expected to cost. This paper demonstrates that, to the contrary, actual costs for SO{sub 2} reductions remain roughly in line with original estimates associated with Title IV. Erroneous conclusions about Title IV`s costs are due to inappropriate comparisons of a variety of different measures that appear to be comparable only because they are all stated in dollars per ton. Program cost estimates include the total costs of a fully-implemented regulatory program. The very low costs of Title IV that are commonly cited today are neither directly reflective of a fully implemented Title IV, (which is still many years away) nor reflective of all the costs already incurred. Further, a careful review of history finds that the initial cost estimates that many cite were never associated with Title IV. Technically speaking, people are comparing the estimated control costs for the most-costly power plant associated with earlier acid rain regulatory proposals with prices from a market that do not directly reflect total costs.

  15. Membranes for separation of carbon dioxide

    DOE Patents [OSTI]

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY); Willson, Patrick Daniel (Latham, NY); Gao, Yan (Niskayuna, NY)

    2011-03-01T23:59:59.000Z

    Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

  16. Integrated Energy System with Beneficial Carbon Dioxide (CO{sub 2}) Use

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30T23:59:59.000Z

    To address the public concerns regarding the consequences of climate change from anthropogenic carbon dioxide (CO{sub 2}) emissions, the U.S. Department of Energy National Energy Technology Laboratory (DOE-NETL) is actively funding a CO{sub 2} management program to develop technologies capable of reducing the CO{sub 2} emissions from fossil fuel power plants and other industrial facilities. Over the past decade, this program has focused on reducing the costs of carbon capture and storage technologies. Recently, DOE-NETL launched an alternative CO{sub 2} mitigation program focusing on beneficial CO{sub 2} reuse and supporting the development of technologies that mitigate emissions by converting CO{sub 2} to solid mineral form that can be utilized for enhanced oil recovery, in the manufacturing of concrete or as a benign landfill, in the production of valuable chemicals and/or fuels. This project was selected as a CO{sub 2} reuse activity which would conduct research and development (R&D) at the pilot scale via a cost-shared Cooperative Agreement number DE-FE0001099 with DOE-NETL and would utilize funds setaside by the American Recovery and Reinvestment Act (ARRA) of 2009 for Industrial Carbon Capture and Sequestration R&D,

  17. Driving Down Diesel Emissions

    E-Print Network [OSTI]

    Harley, Robert

    2013-01-01T23:59:59.000Z

    Turnover on Drayage Truck Emissions at the Port of Oakland,”actions to clean up port truck emissions in Oakland serve asTurnover on Drayage Truck Emissions at the Port of Oakland,”

  18. Nitrogen dioxide and respiratory illnesses in infants

    SciTech Connect (OSTI)

    Samet, J.M.; Lambert, W.E.; Skipper, B.J.; Cushing, A.H.; Hunt, W.C.; Young, S.A.; McLaren, L.C.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

    1993-11-01T23:59:59.000Z

    Nitrogen dioxide is an oxidant gas that contaminates outdoor air and indoor air in homes with unvented gas appliances. A prospective cohort study was carried out to test the hypothesis that residential exposure to NO2 increases incidence and severity of respiratory illnesses during the first 18 months of life. A cohort of 1,205 healthy infants from homes without smokers was enrolled. The daily occurrence of respiratory symptoms and illnesses was reported by the mothers every 2 wk. Illnesses with wheezing or wet cough were classified as lower respiratory tract. Indoor NO2 concentrations were serially measured with passive samplers place in the subjects' bedrooms. In stratified analyses, illness incidence rates did not consistently increase with exposure to NO2 or stove type. In multivariate analyses that adjusted for potential confounding factors, odds ratios were not significantly elevated for current or lagged NO2 exposures, or stove type. Illness duration, a measure of illness severity, was not associated with NO2 exposure. The findings can be extended to homes with gas stoves in regions of the United States where the outdoor air is not heavily polluted by NO2.

  19. Motor Vehicle Fleet Emissions by K I M B E R L Y S . B R A D L E Y ,

    E-Print Network [OSTI]

    Denver, University of

    Motor Vehicle Fleet Emissions by OP-FTIR K I M B E R L Y S . B R A D L E Y , K E V I N B . B R O O concentrations of carbon monoxide (CO), carbon dioxide (CO2), and nitrous oxide (N2O) caused by emissions from to average emissions results obtained from on-road exhaust analysis using individual vehicle remote sensing

  20. Material Aging and Degradation Detection and Remaining Life Assessment for Plant Life Management

    SciTech Connect (OSTI)

    Ramuhalli, Pradeep; Henager, Charles H.; Griffin, Jeffrey W.; Meyer, Ryan M.; Coble, Jamie B.; Pitman, Stan G.; Bond, Leonard J.

    2012-12-31T23:59:59.000Z

    One of the major factors that may impact long term operations is structural material degradation, Detecting materials degradation, estimating the remaining useful life (RUL) of the component, and determining approaches to mitigating the degradation are important from the perspective of long term operations. In this study, multiple nondestructive measurement and monitoring methods were evaluated for their ability to assess the material degradation state. Metrics quantifying the level of damage from these measurements were defined, and evaluated for their ability to provide estimates of remaining life of the component. An example of estimating the RUL from nondestructive measurements of material degradation condition is provided.

  1. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30T23:59:59.000Z

    This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

  2. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05T23:59:59.000Z

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  3. Power Outage 1. Remain Calm; provide assistance to others if necessary.

    E-Print Network [OSTI]

    Hickman, Mark

    Power Outage 1. Remain Calm; provide assistance to others if necessary. 2. Report the outage, call. Campus-wide telephone communications will continue to operate during a power outage on standard phones. If emergency assistance is required, call UC Security on Extn 6111 and state "POWEr OUTAgE" or mobile 0800 823

  4. Prostate cancer remains the most common cancer in men in the United States, with an

    E-Print Network [OSTI]

    Cai, Long

    Prostate cancer remains the most common cancer in men in the United States, with an estimated of death from cancer in men, with 33,720 estimated deaths (11% of all estimated deaths) in 2011 (REF. 1-year relative survival rate is essentially 100% based on 2001­2007 statistics2 . However, for patients

  5. A Bayesian Prognostic Algorithm for Assessing Remaining Useful Life of Nuclear Power Components

    SciTech Connect (OSTI)

    Ramuhalli, Pradeep; Bond, Leonard J.; Griffin, Jeffrey W.; Dixit, Mukul; Henager, Charles H.

    2010-12-01T23:59:59.000Z

    A central issue in life extension for the current fleet of light water nuclear power reactors is the early detection and monitoring of significant materials degradation. To meet this need nondestructive measurement methods that are suitable for on-line, continuous, in-plant monitoring over extended time periods (months to years) are needed. A related issue is then, based on a condition assessment or degradation trend, to have the ability to estimate the remaining useful life based of components, structures and systems based on the available materials degradation information. Such measurement and modeling methods form the basis for a new range of advanced diagnostic and prognostic approaches. Prognostic methods that predict remaining life based on large crack growth, and phenomena that can be described by linear elastic fracture mechanics, have been reported by several researchers. The challenge of predicting remaining life for earlier phases of degradation is largely unsolved. Monitoring for early detection of materials degradation requires novel and enhanced sensors and data integration techniques. A recent review has considered the stages of degradation and sensing methods that can potentially be employed to detect and monitor early degradation for nuclear power plant applications. An experimental assessment of selected diagnostic techniques was also reported recently. However, the estimation of remaining useful life (RUL) determined from nondestructive diagnostic measurements for early degradation is still an unsolved problem. This present paper will discuss the application of Bayesian prognostic algorithms applied to the early degradation- life problem.

  6. `TVLSI-00029-2003.R1 An Analytical Model for Predicting the Remaining Battery

    E-Print Network [OSTI]

    Pedram, Massoud

    . Reference [7] studied the battery discharge efficiency under different loading conditions and approximated`TVLSI-00029-2003.R1 1 An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng Rong, Student Member, IEEE and Massoud Pedram, Fellow, IEEE Abstract -- Predicting

  7. Grantee Performance Required to Release the Hold on Remaining 50% of Obligated Recovery Act Funds

    Broader source: Energy.gov [DOE]

    U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Weatherization Assistance Program Notice 10-05 deals with performance requirements for program grantees?states and U.S. territories?to receive the remaining 50% of obligated funds under the 2009 American Reinvestment and Recovery Act.

  8. Environmental control technology for atmospheric carbon dioxide

    SciTech Connect (OSTI)

    Steinberg, M; Albanese, A S

    1980-01-01T23:59:59.000Z

    The impact of fossil fuel use in the United States on worldwide CO/sub 2/ emissions and the impact of increased coal utilization on CO/sub 2/ emission rates are assessed. The aspects of CO/sub 2/ control are discussed as well as the available CO/sub 2/ control points (CO/sub 2/ removal sites). Two control scenarios are evaluated, one based on the absorption of CO/sub 2/ contained in power plant flue gas by seawater; the other, based on absorption of CO/sub 2/ by MEA (Mono Ethanol Amine). Captured CO/sub 2/ is injected into the deep ocean in both cases. The analyses indicate that capture and disposal by seawater is energetically not feasible, whereas capture and disposal using MEA is a possibility. However, the economic penalities of CO/sub 2/ control are significant. The use of non-fossil energy sources, such as hydroelectric, nuclear or solar energy is considered as an alternative for limiting and controlling CO/sub 2/ emissions resulting from fossil energy usage.

  9. Carbon-dioxide-controlled ventilation study

    SciTech Connect (OSTI)

    McMordie, K.L.; Carroll, D.M.

    1994-05-01T23:59:59.000Z

    The In-House Energy Management (IHEM) Program has been established by the U.S. Department of Energy to provide funds to federal laboratories to conduct research on energy-efficient technology. The Energy Sciences Department of Pacific Northwest Laboratory (PNL) was tasked by IHEM to research the energy savings potential associated with reducing outdoor-air ventilation of buildings. By monitoring carbon dioxide (CO{sub 2}) levels in a building, outdoor air provided by the heating, ventilating, and air-conditioning (HVAC) system can be reduced to the percentage required to maintain satisfactory CO{sub 2} levels rather than ventilating with a higher outdoor-air percentage based on an arbitrary minimum outdoor-air setting. During summer months, warm outdoor air brought into a building for ventilation must be cooled to meet the appropriate cooling supply-air temperature, and during winter months, cold outdoor air must be heated. By minimizing the amount of hot or cold outdoor air brought into the HVAC system, the supply air requires less cooling or heating, saving energy and money. Additionally, the CO{sub 2} levels in a building can be monitored to ensure that adequate outdoor air is supplied to a building to maintain air quality levels. The two main considerations prior to implementing CO{sub 2}-based ventilation control are its impact on energy consumption and the adequacy of indoor air quality (IAQ) and occupant comfort. To address these considerations, six portable CO{sub 2} monitors were placed in several Hanford Site buildings to estimate the adequacy of office/workspace ventilation. The monitors assessed the potential for reducing the flow of outdoor-air to the buildings. A candidate building was also identified to monitor various ventilation control strategies for use in developing a plan for implementing and assessing energy savings.

  10. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions into the atmosphere2

    E-Print Network [OSTI]

    Boyer, Edmond

    dioxide sequestration process. The overall carbonation reaction includes the following steps: (1)23 CaCarbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions change.20 This study investigates experimentally the aqueous carbonation mechanisms of an alkaline paper

  11. Carbon Dioxide Separation with Supported Ionic Liquid Membranes

    SciTech Connect (OSTI)

    Luebke, D.R.; Ilconich, J.B.; Pennline, H.W.; Myers, C.R.

    2007-05-01T23:59:59.000Z

    A practical form of CO2 capture at water-gas shift conditions in the IGCC process could serve the dual function of producing a pure CO2 stream for sequestration and forcing the equilibrium-limited shift reaction to completion enriching the stream in H2. The shift temperatures, ranging from the low temperature shift condition of 260°C to the gasification condition of 900°C, limit capture options by diminishing associative interactions which favor removal of CO2 from the gas stream. Certain sorption interactions, such as carbonate formation, remain available but generally involve exceptionally high sorbent regeneration energies that contribute heavily to parasitic power losses. Carbon dioxide selective membranes need only establish an equilibrium between the gas phase and sorption states in order to transport CO2, giving them a potential energetic advantage over other technologies. Supported liquid membranes take advantage of high, liquid phase diffusivities and a solution diffusion mechanism similar to that observed in polymeric membranes to achieve superior permeabilities and selectivites. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which possess high CO2 solubility relative to light gases such as H2, are excellent candidates for this type of membrane since they have negligible vapor pressure and are not susceptible to evaporation. A study has been conducted evaluating the use of ionic liquids including 1-hexyl-3-methyl-imidazolium bis(trifuoromethylsulfonyl)imide in supported ionic liquid membranes for the capture of CO2 from streams containing H2. In a joint project, researchers at the University of Notre Dame synthesized and characterized ionic liquids, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance. Improvements to the ionic liquid and support have allowed testing of these supported ionic liquid membranes at temperatures up to 300°C without loss of support mechanical stability or degradation of the ionic liquid. Substantial improvements in selectivity have also been observed at elevated temperature with the best membrane currently achieving optimum performance at 75°C.

  12. Multiwavelength Thermal Emission

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Multiwavelength Astronomy NASA #12;Thermal Emission #12;Thermal Emission Non-thermal p-p collisions Optical IR Radio/ Microwave sources of emission massive stars, WHIM, Ly many dust, cool objects-ray ~GeV Gamma-ray ~TeV sources of emission AGN, clusters, SNR, binaries, stars AGN (obscured), shocks

  13. Application of chlorine dioxide as an oilfield facilities treatment fluid

    SciTech Connect (OSTI)

    Romaine, J.; Strawser, T.G.; Knippers, M.L.

    1995-11-01T23:59:59.000Z

    Both mechanical and chemical treatments are used to clean water flood injection distribution systems whose efficiency has been reduced as a result of plugging material such as iron sulfide sludge. Most mechanical treatments rely on uniform line diameter to be effective, while chemical treatments require good contact with the plugging material for efficient removal. This paper describes the design and operation of a new innovative application using chlorine dioxide for the removal of iron sulfide sludge from water flood injection distribution systems. This technology has evolved from the use of chlorine dioxide in well stimulation applications. The use of chlorine dioxide for continuous treatment of injection brines will also be discussed. Exxon USA`s Hartzog Draw facility in Gillette, Wyoming was the site for the application described. 4,500 barrels of chlorine dioxide was pumped in three phases to clean sixty-six miles of the water flood distribution system. Results indicate that chlorine dioxide was effective in cleaning the well guard screens, the injection lines, frac tanks used to collect the treatment fluids and the injection wells.

  14. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Nils Johnson; Joan Ogden

    2010-12-31T23:59:59.000Z

    In this final report, we describe research results from Phase 2 of a technical/economic study of fossil hydrogen energy systems with carbon dioxide (CO{sub 2}) capture and storage (CCS). CO{sub 2} capture and storage, or alternatively, CO{sub 2} capture and sequestration, involves capturing CO{sub 2} from large point sources and then injecting it into deep underground reservoirs for long-term storage. By preventing CO{sub 2} emissions into the atmosphere, this technology has significant potential to reduce greenhouse gas (GHG) emissions from fossil-based facilities in the power and industrial sectors. Furthermore, the application of CCS to power plants and hydrogen production facilities can reduce CO{sub 2} emissions associated with electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) and, thus, can also improve GHG emissions in the transportation sector. This research specifically examines strategies for transitioning to large-scale coal-derived energy systems with CCS for both hydrogen fuel production and electricity generation. A particular emphasis is on the development of spatially-explicit modeling tools for examining how these energy systems might develop in real geographic regions. We employ an integrated modeling approach that addresses all infrastructure components involved in the transition to these energy systems. The overall objective is to better understand the system design issues and economics associated with the widespread deployment of hydrogen and CCS infrastructure in real regions. Specific objectives of this research are to: Develop improved techno-economic models for all components required for the deployment of both hydrogen and CCS infrastructure, Develop novel modeling methods that combine detailed spatial data with optimization tools to explore spatially-explicit transition strategies, Conduct regional case studies to explore how these energy systems might develop in different regions of the United States, and Examine how the design and cost of coal-based H{sub 2} and CCS infrastructure depend on geography and location.

  15. Characterizing the marginal basis source energy and emissions associated with comfort cooling systems

    SciTech Connect (OSTI)

    Reindl, D.T.; Knebel, D.E.; Gansler, R.A. [Univ. of Wisconsin, Madison, WI (United States)

    1995-08-01T23:59:59.000Z

    A ten-story commercial office building located in Fort Worth, Texas, was used as a prototype to investigate the environmental impact associated with applying various electric and gas technologies for providing ventilation and comfort conditioning. The instantaneous (hourly) electrical and gas requirements demanded by the building were ``traced`` back to their source, the point where fuel is extracted from the ground The total energy consumed and emissions produced are quantified for both electric and gas technologies. On an annual basis, electric technologies had carbon dioxide emissions that were 20% to 26% lower when compared with the gas cooling technology. The gas cooling technology had lower total carbon monoxide emissions; however, after accounting for environmental oxidation of the carbon monoxide emissions, the gas cooling technology had an overall 24% to 35% greater oxide of carbon emission impact. The gas technology had a 19% to 25% lower oxide of nitrogen emission rate when compared with the electric technologies. The gas technology had a 3% to 15% lower annual total emission of sulfur dioxide compared to electric technologies. The primary reason for this is the absence of sulfur in the ``clean`` fuel assumed to be used by the gas technology (natural gas). The gas cooling technologies required 20% to 30% more energy to be extracted from the earth to provide the equivalent space conditioning for the prototypical office building when compared with the worst-and best-case electric technologies, respectively.

  16. Method and apparatus to predict the remaining service life of an operating system

    DOE Patents [OSTI]

    Greitzer, Frank L. (Richland, WA); Kangas, Lars J. (West Richland, WA); Terrones, Kristine M. (Los Alamos, NM); Maynard, Melody A. (Richland, WA); Pawlowski, Ronald A. (West Richland, WA), Ferryman; Thomas A. (Richland, WA); Skorpik, James R. (Kennewick, WA); Wilson, Bary W. (Coconut Creek, FL)

    2008-11-25T23:59:59.000Z

    A method and computer-based apparatus for monitoring the degradation of, predicting the remaining service life of, and/or planning maintenance for, an operating system are disclosed. Diagnostic information on degradation of the operating system is obtained through measurement of one or more performance characteristics by one or more sensors onboard and/or proximate the operating system. Though not required, it is preferred that the sensor data are validated to improve the accuracy and reliability of the service life predictions. The condition or degree of degradation of the operating system is presented to a user by way of one or more calculated, numeric degradation figures of merit that are trended against one or more independent variables using one or more mathematical techniques. Furthermore, more than one trendline and uncertainty interval may be generated for a given degradation figure of merit/independent variable data set. The trendline(s) and uncertainty interval(s) are subsequently compared to one or more degradation figure of merit thresholds to predict the remaining service life of the operating system. The present invention enables multiple mathematical approaches in determining which trendline(s) to use to provide the best estimate of the remaining service life.

  17. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01T23:59:59.000Z

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  18. Estimating carbon dioxide emissions factors for the California electric power sector

    E-Print Network [OSTI]

    Marnay, Chris; Fisher, Diane; Murtishaw, Scott; Phadke, Amol; Price, Lynn; Sathaye, Jayant

    2002-01-01T23:59:59.000Z

    that, in California, combined heat and power plants (CHP orout-of-state power plants serving California in 1990. Thesethat California utilities take power from these plants

  19. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    fuel combustion are attributable to natural gas consumption.Combustion in 2004 (million metric tonne (Mt) of CO 2 ) Fuel Motor Gasoline Natural Gascombustion in 2004. California relies heavily on imported natural gas.

  20. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30T23:59:59.000Z

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  1. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    by electricity generation/CHP facilities by distillate fuelFossil Fuel Consumption for Electricity and Heat GenerationFossil Fuel Consumption for Electricity and Heat Generation

  2. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    kW LBNL LPG Mcf MECS MMBtu Mt MTBE MVSTAFF MW Average Annualof ethanol, as opposed to MTBE, as a blending component of

  3. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    their counterpart in the U.S. EIA database, accounting forreported in the U.S. EIA database; it is not clear why theForm EIA-906 and EIA-920 Databases. Washington, DC: EIA.

  4. Energy use and carbon dioxide emissions in the steel sector in key developing countries

    E-Print Network [OSTI]

    Price, Lynn; Phylipsen, Dian; Worrell, Ernst

    2001-01-01T23:59:59.000Z

    Town, South Africa: Energy Research Institute, University ofCape Town: ERI. Energy Research Institute (China), 1999.INEDIS Database. Beijing: Energy Research Institute, State

  5. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    sector. The electricity sector is disaggregated into fivefuel is used in the electricity sector, the industry sector,Electricity and CHP Sector ..

  6. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    from the combustion of residual fuel oil and distillate fuelfrom oil and gas systems except from fuel combustion (IPCC,SEDS from combustion of residual fuel oil from international

  7. Estimating carbon dioxide emissions factors for the California electric power sector

    E-Print Network [OSTI]

    Marnay, Chris; Fisher, Diane; Murtishaw, Scott; Phadke, Amol; Price, Lynn; Sathaye, Jayant

    2002-01-01T23:59:59.000Z

    for LDC Method______________________________________________load duration curve (LDC). Table EX-1 compares thesefrom import totals. c The LDC approach could be modified to

  8. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Administration (U.S. EIA), 2005a. Energy Information2003. Annual Coal Report 2004. Washington, DC: EIA. U.S.Administration (U.S. EIA), 2005b. Energy Information

  9. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    International Energy Agency (IEA), 2003a. Energy Balancesof OECD Countries. Paris: IEA.International Energy Agency (IEA) , 2003b. Energy Balances

  10. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    of a lack of energy-consumption data, most of the data atsets including sectoral energy consumption data, power plantrelated to energy consumption, but data collection and

  11. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    resources for national energy consumption data in China aredoes have energy consumption data for each subsector;production data. Energy consumption data are only reported

  12. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Hydrogen and the Oil Refining Industries”, poster presentedgas Refining** Oil/gas extraction Industry feedstocksgas Refining** Oil/gas extraction Industry feedstocks

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    EI-81, Energy Information Administration, U.S.Department ofTable_ID=293 U.S. Energy Information Administration (U.S.EIA), 2005a. Energy Information Administration, 2003. Annual

  14. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    product consumption Nat Gas NGL Additives Crude Tot Pet.Pet Coke Lubricants Asphalt Waxes Special Naphtha Petrochem feedstocks Other Petro Prods Coal Net reconciliation error Total Consumption

  15. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Survey of Domestic Oil and Gas Reserves (Field Version)Survey of Domestic Oil and Gas Reserves (Summary Version)

  16. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    activities and not in the petrochemical manufacture sector.Storage Factors LPG Petrochemical feedstocks • Carbondata for LPG and petrochemical feedstock consumption by end-

  17. EIA - AEO2011 Early Release Energy-Related Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    and socioeconomic factors, including appliance and building efficiency standards, higher energy prices, shifts in housing growth, and the continued transition to a more...

  18. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    2006. “California Crude Oil Production and Imports” AprilProduction Report (Quarterly) EIA-856 Monthly Foreign Crude OilProduction Annual Report of Natural and Supplemental Gas Supply and Disposition Domestic Crude Oil

  19. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Gas, Crude Oil and Distillates NGLs consumption in CALEBConsumption Weekly Refinery and Fractionator Report Weekly Bulk Terminal Report Weekly Product Pipeline Report Weekly Crude OilCrude Oil Butane Isobutane Other Hydrocarbons, Hydrogen and Oxygenates 10,718 Unfinished Oils Source: CEC 2006a The energy sector shows the consumption

  20. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    Coal Washed Coal Coke Coke Oven Gas Other Gas Other CokingTJ) Coal Coke Coke Oven Gas Other Gas Other Coking Products

  1. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    data from the Journal of Oil & Gas, but were refrained bydata obtained from the Journal of Oil & Gas to estimate theusing data from the Journal of Oil & Gas will be assessed 4

  2. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    Recovery TF Total fuel used TWh Terra-watt hours UNFCCC United Nations Framework Convention on Climate Repair BTS Bureau of Transportation Statistics Btu British thermal unit CalCARS California Conventional IPP Independent Power Producer Kbbl Thousand barrels kLBS Thousand pounds of Steam kst Thousand

  3. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    for Global Atmospheric Research, EDGAR version 4.2, http://Ganzeveld, L. N. : The EDGAR 3.2 Fast track 2000 dataset (at: http://www.mnp.nl/edgar/model/ v32ft2000edgar, 2005.

  4. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    CALEB CalTrans CARB CEC CEM CHP CO 2 DMV EEA U.S. EIA EMFAC2 2.1 Electricity and CHPemissions CO 2 (Mt) Electricity/CHP* coal petroleum products

  5. Energy use and carbon dioxide emissions in energy-intensive industries in key developing countries

    E-Print Network [OSTI]

    Price, Lynn; Worrell, Ernst; Phylipsen, Dian

    1999-01-01T23:59:59.000Z

    Steel Industry in India,” Ironmaking and Steelmaking, 23(4):and Future Trends,” Ironmaking and Steelmaking World Energymanufacturing industries. Ironmaking. During the ironmaking

  6. Energy use and carbon dioxide emissions in the steel sector in key developing countries

    E-Print Network [OSTI]

    Price, Lynn; Phylipsen, Dian; Worrell, Ernst

    2001-01-01T23:59:59.000Z

    1996. COREX, Revolution in Ironmaking, Linz, Austria:VAI.Steel Industry in India,” Ironmaking and Steelmaking, 23(4):Proc. 2nd European Ironmaking Congress, Glasgow, UK, 15-18

  7. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    updates. In CALEB, the energy use for electricity production in CHP is shown under the electricity sub-sector

  8. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2009

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Press Releases Presentations Congressional Testimony Radio Spots Enter Search Term(s): Search eia.gov A-Z Index A-Z Index A B C D E F G H I J K L M N O P Q R S T U...

  9. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Prepared by Booz-Allen & Hamilton. January. California AirRail Fuel In 1991 Booz-Allen & Hamilton developed a 1987

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Appendix 1- List of U.S. EIA Energy Survey Form Form NumberEnergy Consumption Survey EIA-851A Domestic Uranium858 Uranium Marketing Annual Survey EIA-860 Annual Electric

  11. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    EIA) conducts the Manufacturing Energy Consumption Survey (survey conducted in 2011. The 2006 MECS surveyed industrial establishments, and allowed EIA

  12. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    the case of oil and extraction, consumption of natural gasGas, Crude Oil and Distillates NGLs consumption in CALEBOil and Gas Extraction (Mcf) Re-pressuring Lease Fuel Consumption

  13. Energy use and carbon dioxide emissions in the steel sector in key developing countries

    E-Print Network [OSTI]

    Price, Lynn; Phylipsen, Dian; Worrell, Ernst

    2001-01-01T23:59:59.000Z

    1983-1993, Paris: OECD. PEMEX, 1985. Consumo de Energía enno. 2, Mexico City: PEMEX, Coordinación de EstudiosMetal Bulletin Books, 1994; PEMEX, 1985. E. South Africa

  14. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Thermal Unit Thermally Enhanced Oil Recovery Total fuel useduse of thermally enhanced oil recovery process (TEOR). TEOR

  15. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Sales 2006. Office of Oil and Gas, DOE/EIA-0535(06).6 2.3 Oil and Gas Extraction9 Table 6. Oil and Gas Extraction Energy Use as Estimated in

  16. Energy-Related Carbon Dioxide Emissions in U.S. Manufacturing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity Use as an IndicatorNatural Gas MonthlyUse

  17. Carbon Dioxide Emissions From Vegetation-Kill Zones Around The Resurgent

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomassSustainableCSL GasPermits ManualCanisteo,Verde:ConnectionsUtah:FeedbackDome

  18. Table 21. Total Energy Related Carbon Dioxide Emissions, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14Total Delivered Residentialtight oil plays:Total Energy

  19. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2011 - Energy

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights 2008DeutscheState Energy

  20. State-Level Energy-Related Carbon Dioxide Emissions, 2000…2011

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights 2008DeutscheState EnergyState-Level

  1. Table 1. State energy-related carbon dioxide emissions by year (2000…2011)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights1,943,742 1,947,078342 301,097

  2. Table 3. 2011 State energy-related carbon dioxide emissions by sector

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights1,943,742Coalbed20112011 State

  3. Table 5. Per capita energy-related carbon dioxide emissions by State (2000…2011)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO)U.S. Coal Stocks at Manufacturing Plants byPer

  4. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2009

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:Deployment Activities Printable80

  5. Table 1. State energy-related carbon dioxide emissions by year (2000-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energy Energy Information3 OutlookSurveyState

  6. Table 2. 2011 State energy-related carbon dioxide emissions by fuel

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energy Energy Information32. Average Price2011 State

  7. Table 3. 2011 State energy-related carbon dioxide emissions by sector

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energy Energy Information32. Average

  8. Table 4. 2011 State energy-related carbon dioxide emission shares by sector

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energy Energy Information32. Average2011 State2011

  9. Table 5. Per capita energy-related carbon dioxide emissions by State (2000-201

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energy Energy Information32. Average2011 State2011Per

  10. CarBen Version 3: Multisector Carbon Dioxide Emissions Accounting Tool |

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpen EnergyCallawayCapara Energia S A JumpOpen Energy

  11. Carbon Dioxide Emissions From Vegetation-Kill Zones Around The Resurgent

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LPInformation 8thCalwind IICaney RiverSiemens)CarbonDome Of

  12. Carbon Dioxide and Helium Emissions from a Reservoir of Magmatic Gas

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LPInformation 8thCalwind IICaney RiverSiemens)CarbonDome

  13. "1. Carbon Dioxide Emission Factors for Stationary Combustion1"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit:1996.......... 2.4Origin andFuel ExpendituresFuel

  14. "Table 21. Total Energy Related Carbon Dioxide Emissions, Projected vs. Actual"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1 U.S. Department of Energygasoline4 Space Heating8TotalTotal Energy

  15. Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium

    E-Print Network [OSTI]

    Marcalo, Joaquim

    2011-01-01T23:59:59.000Z

    D. Chemical Thermodynamics of Thorium. OECD Nuclear Energyand dioxides from thorium to curium Joaquim Marçalo a,* andmonoxides and dioxides of thorium, protactinium, uranium,

  16. Climate Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Constraints

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Climate Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Constraints by Marcus. The third case examines the benefits of increased policy coordination between air pollution constraints

  17. Ti(III) Doped Titanium Dioxide: an Effective Strategy to Improve the Visible Light Photocatalytic Activity

    E-Print Network [OSTI]

    Zuo, Fan

    2012-01-01T23:59:59.000Z

    types of surface titanium and oxygen atoms present. PageRIVERSIDE Ti(III) Doped Titanium Dioxide: an EffectiveDISSERTATION Ti(III) Doped Titanium Dioxide: an Effective

  18. Dye Sensitization of Nanocrystalline Titanium Dioxide with Osmium and Ruthenium Polypyridyl Complexes

    E-Print Network [OSTI]

    Sauvé, Geneviève

    Dye Sensitization of Nanocrystalline Titanium Dioxide with Osmium and Ruthenium Polypyridyl synthesized and used to sensitize nanoporous titanium dioxide electrodes to solar illumination. The spectral optimization in operating photoelectrochemical cells for solar energy conversion applications. Of the materials

  19. Dynamic shape factors for hydox-generated plutonium dioxide-type non-sperical objects

    E-Print Network [OSTI]

    Lohaus, James Harold

    1999-01-01T23:59:59.000Z

    to determining settling velocities of HYDOX-generated plutonium dioxide aerosols. The change of particle size distribution over time and space can be derived, leading ultimately to an assessment of the dose from an unplanned release of plutonium dioxide....

  20. Solubility of anthracene and anthraquinone in cyclohexanone + carbon dioxide

    SciTech Connect (OSTI)

    Chang, C.J. (National Chung-Hsing Univ., Taichung (Taiwan, Province of China). Dept. of Chemical Engineering)

    1994-10-01T23:59:59.000Z

    In the processing of an anthracene oil fraction from coal tar, a mixture of anthracene and anthraquinone is required to be separated to obtain products of high purity. The solubilities of anthracene and anthraquinone were measured in cyclohexanone + carbon dioxide as a function of the temperature and pressure of carbon dioxide at 291, 300, and 313 K and from 1.8--12.4 MPa. Average equilibrium solubilities and recoveries of both solids increased with increasing normalized concentration and pressure. The average separation factor of anthracene to anthraquinone, due to the effect of the mixed solvent, was 2.88 [+-] 1.91.

  1. Limiting diffusion coefficients of heavy molecular weight organic contaminants in supercritical carbon dioxide 

    E-Print Network [OSTI]

    Orejuela, Mauricio

    1994-01-01T23:59:59.000Z

    Carbon Dioxide. 5. Measured Diffusion Coefficients of Hexachlorobenzene in Supercritical Carbon Dioxide. 6. Measured Diffusion Coefficients of Pentachlorophenol in Supercritical Carbon Dioxide. 7. Carbon Dioxide Parameters as Determined by Empirical..., and for polyatomic solute and solvent molecules, A?was set to 0. 70. Erkey (1989) determined the translational-rotational coupling parameters for binary n-Alkane systems from measured diffusivity data at a wide range of densities. It was shown...

  2. Regulating Carbon Dioxide Capture and Storage 07-003 April 2007

    E-Print Network [OSTI]

    Regulating Carbon Dioxide Capture and Storage by 07-003 April 2007 M.A. de Figueiredo, H.J. Herzog, P.L. Joskow, K.A. Oye, and D.M. Reiner #12;#12;Regulating Carbon Dioxide Capture and Storage M.A. de to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal

  3. An idealized assessment of the economics of air capture of carbon dioxide in mitigation policy

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    a c t This paper discusses the technology of direct capture of carbon dioxide from the atmo- sphereAn idealized assessment of the economics of air capture of carbon dioxide in mitigation policy- ture,'' which refers to the direct removal of carbon dioxide from the ambient air. Air capture has

  4. Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks, and carbon dioxide isotherm measurements were performed at 1-85 bar and 77-298 K on the evacuated forms for COF-5, 65 mg g-1 for COF-6, 87 mg g-1 for COF-8, and 80 mg g-1 for COF-10; carbon dioxide at 298 K

  5. Solar Power To Help Convert Carbon Dioxide Into Fuel : Renewable Energy News

    E-Print Network [OSTI]

    Lovley, Derek

    Solar Power To Help Convert Carbon Dioxide Into Fuel : Renewable Energy News TUESDAY 25 MAY, 2010 | | Solar Power To Help Convert Carbon Dioxide Into Fuel by Energy Matters Microbiologist Derek Lovley dioxide into transportation fuels, with the help of special micro-organisms and solar power. The team

  6. The Implied Cost of Carbon Dioxide under the Cash for Clunkers Christopher R. Knittel

    E-Print Network [OSTI]

    Rothman, Daniel

    The Implied Cost of Carbon Dioxide under the Cash for Clunkers Program Christopher R. Knittel of the implied cost of carbon dioxide reductions under the Cash for Clunker program. The estimates suggest pollutants. Conservative estimates of the implied carbon dioxide cost exceed $365 per ton; best case scenario

  7. High surface area crystalline titanium dioxide: potential and limits in electrochemical energy storage and catalysis

    E-Print Network [OSTI]

    Pfeifer, Holger

    High surface area crystalline titanium dioxide: potential and limits in electrochemical energy-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128 Mainz, Germany Abstract Titanium dioxide is one, as support in catalysis etc. Common synthesis methods of titanium dioxide typically require a high

  8. CMOS-compatible Titanium Dioxide Deposition for Athermalization of Silicon Photonic Waveguides

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    CMOS-compatible Titanium Dioxide Deposition for Athermalization of Silicon Photonic Waveguides@ucdavis.edu , sbyoo@ucdavis.edu Abstract: We discuss titanium dioxide material development for CMOS compatible fabrication and integration of athermal silicon photonic components. Titanium dioxide overclad ring modulators

  9. CMOS-compatible, athermal silicon ring modulators clad with titanium dioxide

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    CMOS-compatible, athermal silicon ring modulators clad with titanium dioxide Stevan S. Djordjevic,1-optic contribution with that from the amorphous titanium dioxide (a-TiO2) overcladding with a negative thermo-compatible Titanium Dioxide Deposition for Athermalization of Silicon Waveguides," accepted for publication

  10. Surface runoff features on Mars: Testing the carbon dioxide formation hypothesis

    E-Print Network [OSTI]

    Nimmo, Francis

    materials and properties; KEYWORDS: Mars, gullies, seepage, runoff, carbon dioxide, water Citation: StewartSurface runoff features on Mars: Testing the carbon dioxide formation hypothesis Sarah T. Stewart1, S. T., and F. Nimmo, Surface runoff features on Mars: Testing the carbon dioxide formation

  11. Carbon Dioxide Footprint of the Northwest Power System Comments submitted by Grant County Public Utility District

    E-Print Network [OSTI]

    Carbon Dioxide Footprint of the Northwest Power System Comments submitted by Grant County Public paper: Carbon Dioxide Footprint of the Northwest Power System, dated September 13, 2007. The Grant done a very thorough job of assessing the current and future carbon dioxide footprints of the Northwest

  12. of carbon dioxide containing 12 but the low concentration of 14

    E-Print Network [OSTI]

    Zare, Richard N.

    of carbon dioxide containing 12 C and 13 C, but the low concentration of 14 C has made its measurement in carbon dioxide extremely difficult. Using an ultrasensitive technique called saturated carbon at values well below radiocarbon's natural abundance in carbon dioxide. In their technique

  13. Carbon Dioxide-Induced Anesthesia Results in a Rapid Increase in Plasma Levels of Vasopressin

    E-Print Network [OSTI]

    Chait, Brian T.

    Carbon Dioxide-Induced Anesthesia Results in a Rapid Increase in Plasma Levels of Vasopressin Brian of carbon dioxide, prior to decapitation is considered a more humane alternative for the euthanasia with carbon dioxide until recumbent (20­25 sec), immediately killed via decapitation, and trunk blood

  14. A correlation of optimal heat rejection pressures in transcritical carbon dioxide cycles

    E-Print Network [OSTI]

    Zhao, Tianshou

    ®cance for the design and control of the transcritical carbon dioxide air- conditioning and heat pump systems 7 2000A correlation of optimal heat rejection pressures in transcritical carbon dioxide cycles S.M. Liaoa) of transcritical carbon dioxide air-conditioning cycles. The analysis shows that the COP of the transcritical

  15. Globular clusters with the extended horizontal-branch as remaining cores of galaxy building blocks

    E-Print Network [OSTI]

    Young-Wook Lee; Hansung B. Gim; Chul Chung

    2007-07-11T23:59:59.000Z

    The relics of building blocks that made stellar halo and bulge are yet to be discovered unless they were completely disrupted throughout the history of the Galaxy. Here we suggest that about 25% of the Milky Way globular clusters have characteristics of the remaining cores of these early building blocks rather than genuine star clusters. They are clearly distinct from other normal globular clusters in the presence of extended horizontal-branch and multiple stellar populations, in mass (brightness), and most importantly in orbital kinematics. Based on this result, a three-stage formation picture of the Milky Way is suggested, which includes early mergers, collapse, and later accretion.

  16. Crack closure effects on fatigue crack growth thresholds and remaining life in an HSLA steel

    SciTech Connect (OSTI)

    Todd, J.A.; Mostovoy, S. [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Mechanical, Materials and Aerospace Engineering; Chen, L. [Texas Instruments, Attleboro, MA (United States); Yankov, E.Y. [A. Finkl and Sons, Chicago, IL (United States)

    1997-02-01T23:59:59.000Z

    The effects of crack closure on the near-threshold corrosion fatigue crack growth behavior of Mil S-24645 HSLA steel and its weld metal have been investigated in air, ASTM seawater at the free corrosion potential, and ASTM seawater at {minus}0.8V and {minus}1.0V (SCE) using frequencies of 10, 2, and 0.2 Hz, and a stress ratio, R = 0.1. Remaining life, in the presence and absence of crack closure, has been estimated as a function of applied stress range for a structure containing a 3-mm-deep surface semi-elliptical flaw.

  17. A little rain doesn't fix it: Farmers and ranchers remain cautious as drought continues

    E-Print Network [OSTI]

    Kalisek, Danielle

    2012-01-01T23:59:59.000Z

    A little rain doesn?t fix it Farmers and ranchers remain cautious as drought continues Summer 2012 tx H2O 11 ] Story by Danielle Kalisek Rains in the Brazos Valley early in 2012 helped this grass green up, but more rains are needed now... to help warm-season grasses. Photo by Danielle Kalisek. This might sound like a broken record, but it still rings true: Last year?s drought was historic the worst one-year drought in Texas? history. #31;ough recent rains in some parts of the state...

  18. MCA 22-3-801 - Human Skeletal Remains and Burial Site Protection Act | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to:LandownersLuther, Oklahoma: EnergyMAREC Jump to: navigation,Remains |

  19. appearance of the remaining chapters. This Flash transmits the first installment

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2, 2015Visiting Strong,Women @JoinEnergyappearance of the remaining

  20. Silicon dioxide and hafnium dioxide evaporation characteristics from a high-frequency sweep e-beam system

    SciTech Connect (OSTI)

    Chow, R. [Lawrence Livermore National Laboratory, Livermore, California 94551-0808 (United States); Tsujimoto, N. [MDC Vacuum Products Corporation, Hayward, California 94545 (United States)

    1996-09-01T23:59:59.000Z

    Reactive oxygen evaporation characteristics were determined as a function of the front-panel control parameters provided by a programmable, high-frequency sweep e-beam system. An experimental design strategy used deposition rate, beam speed, pattern, azimuthal rotation speed, and dwell time as the variables. The optimal settings for obtaining a broad thickness distribution, efficient silicon dioxide boule consumption, and minimal hafnium dioxide defect density were generated. The experimental design analysis showed the compromises involved with evaporating these oxides. {copyright} {ital 1996 Optical Society of America.}

  1. Emissions mitigation of blended coals through systems optimization

    SciTech Connect (OSTI)

    Don Labbe [IOM Invensys Operations Management (United States)

    2009-10-15T23:59:59.000Z

    For coal fired power stations, such as those located in the US, that have installed NOx and SOx emissions abatement equipment substantial carbon dioxide reduction could be achieved by shifting from pure PRB coal to blended coals with local bituminous coal. Don Labbe explains how. The article is based on a presentation at Power-Gen Asia 2009, which takes place 7-9 October in Bangkok, Thailand and an ISA POWID 2009 paper (19th Annual Joint ISA POWID/EPRI Controlls and Instrumentation Conference, Chicago, Illinois, May 2009). 4 refs., 3 figs.

  2. BP's Perspective on Emissions Purdue Emissions Trading Workshop

    E-Print Network [OSTI]

    BP's Perspective on Emissions Trading Purdue Emissions Trading Workshop April 30, 2010 Mark - Government policies can create a carbon price via three primary mechanisms: - Emissions trading (BP's strong

  3. Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Ryan, Joseph V. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Gin, Stephane [CEA Marcoule, DTCD SECM, Bagnols-sur-Ceze (France); Inagaki, Yaohiro [Dept. of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoda (Japan)

    2013-12-01T23:59:59.000Z

    Chemical durability is not a single material property that can be uniquely measured. Instead it is the response to a host of coupled material and environmental processes whose rates are estimated by a combination of theory, experiment, and modeling. High-level nuclear waste (HLW) glass is perhaps the most studied of any material yet there remain significant technical gaps regarding their chemical durability. The phenomena affecting the long-term performance of HLW glasses in their disposal environment include surface reactions, transport properties to and from the reacting glass surface, and ion exchange between the solid glass and the surrounding solution and alteration products. The rates of these processes are strongly influenced and are coupled through the solution chemistry, which is in turn influenced by the reacting glass and also by reaction with the near-field materials and precipitation of alteration products. Therefore, those processes must be understood sufficiently well to estimate or bound the performance of HLW glass in its disposal environment over geologic time-scales. This article summarizes the current state of understanding of surface reactions, transport properties, and ion exchange along with the near-field materials and alteration products influences on solution chemistry and glass reaction rates. Also summarized are the remaining technical gaps along with recommended approaches to fill those technical gaps.

  4. Lubrication Oil Condition Monitoring and Remaining Useful Life Prediction with Particle Filtering

    E-Print Network [OSTI]

    Junda Zhu; Jae M. Yoon; David He; Yongzhi Qu; Eric Bechhoefer

    In order to reduce the costs of wind energy, it is necessary to improve the wind turbine availability and reduce the operational and maintenance costs. The reliability and availability of a functioning wind turbine depend largely on the protective properties of the lubrication oil for its drive train subassemblies such as the gearbox and means for lubrication oil condition monitoring and degradation detection. The wind industry currently uses lubrication oil analysis for detecting gearbox and bearing wear but cannot detect the functional failures of the lubrication oils. The main purpose of lubrication oil condition monitoring and degradation detection is to determine whether the oils have deteriorated to such a degree that they no longer fulfill their functions. This paper describes a research on developing online lubrication oil condition monitoring and remaining useful life prediction using particle filtering technique and commercially available online sensors. It first introduces the lubrication oil condition monitoring and degradation detection for wind turbines. Viscosity and dielectric constant are selected as the performance parameters to model the degradation of lubricants. In particular, the lubricant performance evaluation and remaining useful life prediction of degraded lubrication oil with viscosity and dielectric constant data using particle filtering are presented. A simulation study based on lab verified models is provided to demonstrate the effectiveness of the developed technique. 1.

  5. A Novel System for Carbon Dioxide Capture Utilizing Electrochemical Membrane Technology

    SciTech Connect (OSTI)

    Ghezel-Ayagh, Hossein; Jolly, Stephen; Patel, Dilip; Hunt, Jennifer; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

    2013-06-03T23:59:59.000Z

    FuelCell Energy, Inc. (FCE), in collaboration with Pacific Northwest National Laboratory (PNNL) and URS Corporation, is developing a novel Combined Electric Power and Carbon-Dioxide Separation (CEPACS) system, under a contract from the U.S. Department of Energy (DE-FE0007634), to efficiently and cost effectively separate carbon dioxide from the emissions of existing coal fired power plants. The CEPACS system is based on FCE’s electrochemical membrane (ECM) technology utilizing the Company’s internal reforming carbonate fuel cell products carrying the trade name of Direct FuelCell® (DFC®). The unique chemistry of carbonate fuel cells offers an innovative approach for separation of CO2 from existing fossil-fuel power plant exhaust streams (flue gases). The ECM-based CEPACS system has the potential to become a transformational CO2-separation technology by working as two devices in one: it separates the CO2 from the exhaust of other plants such as an existing coal-fired plant and simultaneously produces clean and environmentally benign (green) electric power at high efficiency using a supplementary fuel. The overall objective of this project is to successfully demonstrate the ability of FCE’s electrochemical membrane-based CEPACS system technology to separate ? 90% of the CO2 from a simulated Pulverized Coal (PC) power plant flue-gas stream and to compress the captured CO2 to a state that can be easily transported for sequestration or beneficial use. Also, a key project objective is to show, through a Technical and Economic Feasibility Study and bench scale testing (11.7 m2 area ECM), that the electrochemical membrane-based CEPACS system is an economical alternative for CO2 capture in PC power plants, and that it meets DOE objectives for the incremental cost of electricity (COE) for post-combustion CO2 capture.

  6. INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES

    E-Print Network [OSTI]

    Suni, Ian Ivar

    INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES H. Lin, A. A. Busnaina, and I. I. Suni T he removal of ionic contaminants from silicon surfaces surface contamination level canM Communications L td. INTRODUCTION with increasing frequency and power, and decreases Contamination removal is one

  7. The surface science of titanium dioxide Ulrike Diebold*

    E-Print Network [OSTI]

    Diebold, Ulrike

    relaxation and reconstruction; Surface structure; Morphology; Roughness; Topography Contents 1. IntroductionThe surface science of titanium dioxide Ulrike Diebold* Department of Physics, Tulane University is the most investigated single-crystalline system in the surface science of metal oxides, and the literature

  8. Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through

    E-Print Network [OSTI]

    hydrogen atom could easily bond to a terminal oxygen site13 . The observed hydrogen diffusion into the TiO2Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through Hydrogenation Xiaobo, on the other hand, can undergo fast diffusion and exchange. The enhanced hydrogen mobility may be explained

  9. Corrosion of various engineering alloys in supercritical carbon dioxide

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    2010-01-01T23:59:59.000Z

    The corrosion resistance of ten engineering alloys were tested in a supercritical carbon dioxide (S-CO 2) environment for up to 3000 hours at 610°C and 20MPa. The purpose of this work was to evaluate each alloy as a potential ...

  10. Molybdenum Dioxide As A Solid Oxide Fuel Cell Anodic Catalyst

    E-Print Network [OSTI]

    Collins, Gary S.

    Molybdenum Dioxide As A Solid Oxide Fuel Cell Anodic Catalyst Jay Thunstrom, Su Ha, Oscar Flores are being developed. One of the most auspicious and the topic presented here is the solid oxide fuel cell hydrocarbons and have great resistance to poisoning. Solid Oxide Fuel Cell Operation Three stages exist

  11. One-Dimensional Titanium Dioxide Nanomaterials: Nanowires, Nanorods, and Nanobelts

    E-Print Network [OSTI]

    Wang, Xudong

    One-Dimensional Titanium Dioxide Nanomaterials: Nanowires, Nanorods, and Nanobelts Xudong Wang Methods P 4.4. Top-down Fabrication Techniques Q 4.4.1. Direct Oxidation of Titanium Sheets Q 4 Nanostructures for Energy Storage AD 5.3.1. Lithium Ion Batteries AD 5.3.2. Supercapacitors AE 5

  12. Hollow hemispherical titanium dioxide aggregates fabricated by coaxial

    E-Print Network [OSTI]

    Cao, Guozhong

    hemispherical titanium dioxide aggregates fabricated by coaxial electrospray for dye-sensitized solar cell nanocrystallites were prepared by a coaxial electrospray method and applied to dye- sensitized solar cells (DSCs-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.JNP.6.063519] Keywords dye-sensitized solar cells; hollow

  13. Carbon dioxide flash-freezing applied to ice cream production

    E-Print Network [OSTI]

    Peters, Teresa Baker, 1981-

    2006-01-01T23:59:59.000Z

    (cont.) Carbon dioxide is recompressed from 1.97 x 106 Pa (285 psi) to 3.96 x 106 Pa (575 psi). The process is scaled by increasing the number of nozzles to accommodate the desired flow rate. Only 165 nozzles are required ...

  14. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

  15. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30T23:59:59.000Z

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  16. www.sciam.com SCIENTIFIC AMERICAN 49 Pumping carbon dioxide

    E-Print Network [OSTI]

    O'Donnell, Tom

    for capture and storage already exists and that the obstacles hindering implementa- tion seem to the gallon and go 10,000 miles next year, you will need to buy 330 gallons-- about a ton--of gasoline. Burning that much gasoline sends around three tons of carbon dioxide out the tailpipe. Al- though CO2

  17. Remote estimation of carbon dioxide uptake by a Mediterranean forest

    E-Print Network [OSTI]

    Garbulsky, Martín

    to assessing the global carbon budget in a context of climate change (Ciais et al., 2005; Boisvenue & RunningRemote estimation of carbon dioxide uptake by a Mediterranean forest M A R T I´ N F. G A R B U L of the ecology of global change. Current remote sensing methodologies for estimating gross primary productivity

  18. Phase relation between global temperature and atmospheric carbon dioxide

    E-Print Network [OSTI]

    Stallinga, Peter

    2013-01-01T23:59:59.000Z

    The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause for temperature variations. In this paper we discuss this assumption and analyze it on basis of bi-centenary measurements and using a relaxation model which causes phase shifts and delays.

  19. Degassing of metamorphic carbon dioxide from the Nepal Himalaya

    E-Print Network [OSTI]

    Derry, Louis A.

    Degassing of metamorphic carbon dioxide from the Nepal Himalaya Matthew J. Evans Chemistry at the foot of the Higher Himalaya near the Main Central Thrust (MCT), Nepal Himalaya. We have sampled hot the Nepal Himalaya, Geochem. Geophys. Geosyst., 9, Q04021, doi:10.1029/2007GC001796. 1. Introduction [2

  20. High Temperature Electrolysis of Steam and Carbon Dioxide

    E-Print Network [OSTI]

    High Temperature Electrolysis of Steam and Carbon Dioxide Søren Højgaard Jensen+,#, Jens V. T. Høgh + O2 #12;Electrolysis of steam at high temperature Interesting because · Improved thermodynamic of electrolysis of steam Picture taken from E. Erdle, J. Gross, V. Meyringer, "Solar thermal central receiver

  1. Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite C H E N H . S H E N A N D G by absorption in sulfite solution in existing scrubbers for desulfurization. Rates of NO2 absorption and sulfite absorption initiates sulfite oxidation in the presence of oxygen, and this study quantified the effect

  2. Excess Emissions (New Mexico)

    Broader source: Energy.gov [DOE]

    This regulation establishes requirements for a source whose operation results in an excess emission and to establish criteria for a source whose operation results in an excess emission to claim an...

  3. Effects of Canola Biodiesel on a DI Diesel Engine Performance and Emissions

    E-Print Network [OSTI]

    Murari Mohon Roy; Majed Alawi; Wilson Wang

    Abstract- A direct injection (DI) diesel engine is tested with different biodiesel-diesel blends, such as B0 (neat diesel), B5 (i.e., 5 vol. % biodiesel and 95 vol. % diesel), B10 (10 vol. % biodiesel), B20 (20 vol. % biodiesel), B50 (50 vol. % biodiesel), and B100 (neat biodiesel) for performance and emissions under different load conditions. Engine performance is examined by measuring brake specific fuel consumption (bsfc) and fuel conversion efficiency (? f). The emission of carbon monoxide (CO), hydrocarbon (HC), nitric oxide (NO), nitrogen dioxide (NO 2), nitrogen oxides (NOx), carbon dioxide (CO 2) and others are measured. Biodiesel shows a significant CO and HC reduction compared to diesel under low load operation; under high load operation, however, CO with biodiesel is increased a little and HC emissions are very similar to that with diesel. On the other hand, under low load operation, NOx emission with biodiesel is significantly increased than diesel; however, under high load operation, there is almost no change in NOx emissions with biodiesel and diesel. Index Term- Canola biodiesel, diesel engine, engine performance, exhaust emissions.

  4. Emissions Trading and Social Justice

    E-Print Network [OSTI]

    Farber, Daniel A

    2011-01-01T23:59:59.000Z

    David  M.  Driesen,  Does  Emissions  Trading  Encourage  Jason  Coburn,  Emissions  Trading   and   Environmental  Szambelan,  U.S.  Emissions  Trading  Markets  for  SO 2  

  5. Why does Low-Luminosity AGN Fueling Remain an Unsolved Problem?

    E-Print Network [OSTI]

    Paul Martini

    2004-04-21T23:59:59.000Z

    Despite many years of effort, observational studies have not found a strong correlation between the presence of any proposed fueling mechanism and low-luminosity AGN. After a discussion of the mass requirements for fueling, I summarize this observational work and provide a number of hypotheses for why the nature of AGN fueling has remained unresolved. In particular, I stress the potential importance of the increasing number of candidate fueling mechanisms with decreasing mass accretion rate, the relevant spatial scales for different fueling mechanisms, and the lifetime of an individual episode of nuclear accretion. The episodic AGN lifetime is a particularly relevant complication if it is comparable to or shorter than the time that the responsible fueling mechanisms are observationally detectable. I conclude with a number of relatively accessible areas for future investigation.

  6. Radiative heat transfer in porous uranium dioxide

    SciTech Connect (OSTI)

    Hayes, S.L. [Texas A and M Univ., College Station, TX (United States)] [Texas A and M Univ., College Station, TX (United States)

    1992-12-01T23:59:59.000Z

    Due to low thermal conductivity and high emissivity of UO{sub 2}, it has been suggested that radiative heat transfer may play a significant role in heat transfer through pores of UO{sub 2} fuel. This possibility was computationally investigated and contribution of radiative heat transfer within pores to overall heat transport in porous UO{sub 2} quantified. A repeating unit cell was developed to model approximately a porous UO{sub 2} fuel system, and the heat transfer through unit cells representing a wide variety of fuel conditions was calculated using a finite element computer program. Conduction through solid fuel matrix as wekk as pore gas, and radiative exchange at pore surface was incorporated. A variety of pore compositions were investigated: porosity, pore size, shape and orientation, temperature, and temperature gradient. Calculations were made in which pore surface radiation was both modeled and neglected. The difference between yielding the integral contribution of radiative heat transfer mechanism to overall heat transport. Results indicate that radiative component of heat transfer within pores is small for conditions representative of light water reactor fuel, typically less than 1% of total heat transport. It is much larger, however, for conditions present in liquid metal fast breeder reactor fuel; during restructuring of this fuel type early in life, the radiative heat transfer mode was shown to contribute as much as 10-20% of total heat transport in hottest regions of fuel.

  7. Regulation of GHG emissions from transportation fuels: Emission quota versus emission intensity standard

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2010-01-01T23:59:59.000Z

    Derivation of average cost of emission reduction by blending?) and ? respectively. GHG emissions per unit of blend is, ?+ ?? i Reduction in GHG emissions with respect to unblended

  8. Thermal Property Evaluation of Cerium Dioxide and Cerium Dioxide Magnesium Oxide Powders for Testing Plutonium

    SciTech Connect (OSTI)

    HOYT, R C

    2002-06-01T23:59:59.000Z

    Ceric oxide (CeO{sub 2}) and mixtures of CeO{sub 2} -magnesium oxide (MgO) have been utilized at the Plutonium Finishing Plant (PFP) as surrogate materials to represent plutonium dioxide (PuO{sub 2}) and impure PuO{sub 2} containing impurities such as MgO during verification tests on PFP's stabilization furnaces. Magnesium oxide was selected during furnace testing as the impurity of interest since much of the impure PuO{sub 2} to be stabilized and packaged at the PFP contains significant amounts of MgO from solution stabilization work. The issue being addressed in this study is whether or not heating the surrogate materials to 950 C adequately simulates heating PuO{sub 2} powders to 950 C. This paper evaluates some of the thermal properties of these oxides, as related to the heating of powders of these materials where heat transfer within the powders is governed primarily by conduction. Detailed heat transfer modeling was outside the scope of this paper.

  9. Supercritical carbon dioxide cycle control analysis.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J. (Nuclear Engineering Division)

    2011-04-11T23:59:59.000Z

    This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO{sub 2} cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO{sub 2} Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO{sub 2} pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO{sub 2} Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO{sub 2} heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO{sub 2} cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined. In particular, the peak heat removal capacity of the shutdown heat removal loop may be specified to be 1.1 % of the nominal reactor power. An investigation of the oscillating cycle behavior calculated by the ANL Plant Dynamics Code under specific conditions has been carried out. It has been found that the calculation of unstable operation of the cycle during power reduction to 0 % may be attributed to the modeling of main compressor operation. The most probable reason for such instabilities is the limit of applicability of the currently used one-dimensional compressor performance subroutines which are based on empirical loss coefficients. A development of more detailed compressor design and performance models is required and is recommended for future work in order to better investigate and possibly eliminate the calculated instabilities. Also, as part of such model development, more reliable surge criteria should be developed for compressor operation close to the critical point. It is expected that more detailed compressor models will be developed as a part of validation of the Plant Dynamics Code through model comparison with the experiment data generated in the small S-CO{sub 2} loops being constructed at Barber-Nichols Inc. and Sandia National Laboratories (SNL). Although such a comparison activity had been planned to be initiated in FY 2008, data from the SNL compression loop currently in operation at Barber Nichols Inc. has not yet become available by the due date of this report. To enable the transient S-CO{sub 2} cycle investigations to be carried out, the ANL Plant Dynamics Code for the S-CO{sub 2} Brayton cycle was further developed and improved. The improvements include further optimization and tuning of the control mechanisms as well as an adaptation of the code for reactor systems other than the Lead-Cooled Fast Reactor (LFR). Since the focus of the ANL work on S-CO{sub 2} cycle development for the majority of the current year has been on the applicability of the cycle to SFRs, work has started on modification of the ANL Plant Dynamics Code to allow

  10. Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale in a Mediterranean climate

    E-Print Network [OSTI]

    van Kessel, Chris

    Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale, N2O emissions from soil management activities accounted for 29.7% of the combined emissions of CO2 estimates across fields remain uncertain. Here, we quantified CO2, N2O, and NO emissions from an irrigated

  11. Carbon dioxide capture by chemical absorption : a solvent comparison study

    E-Print Network [OSTI]

    Kothandaraman, Anusha

    2010-01-01T23:59:59.000Z

    In the light of increasing fears about climate change, greenhouse gas mitigation technologies have assumed growing importance. In the United States, energy related CO? emissions accounted for 98% of the total emissions in ...

  12. Timelines for mitigating methane emissions from energy technologies

    E-Print Network [OSTI]

    Roy, Mandira; Trancik, Jessika E

    2015-01-01T23:59:59.000Z

    Energy technologies emitting differing proportions of methane and carbon dioxide vary in their relative climate impacts over time, due to the different atmospheric lifetimes of the two gases. Standard technology comparisons using the global warming potential (GWP) emissions equivalency metric do not reveal these dynamic impacts, and may not provide the information needed to assess technologies and emissions mitigation opportunities in the context of broader climate policy goals. Here we formulate a portfolio optimization model that incorporates changes in technology impacts as a radiative forcing (RF) stabilization target is approached. An optimal portfolio, maximizing allowed energy consumption while meeting the RF target, is obtained by year-wise minimization of the marginal RF impact in an intended stabilization year. The optimal portfolio calls for using certain higher methane-emitting technologies prior to an optimal switching year, followed by methane-light technologies as the stabilization year approac...

  13. Light duty vehicle full fuel cycle emissions analysis. Topical report, April 1993-April 1994

    SciTech Connect (OSTI)

    Darrow, K.G.

    1994-04-01T23:59:59.000Z

    The report provides a methodology for analyzing full fuel cycle emissions of alternative fuels for vehicles. Included in this analysis is an assessment of the following fuel cycles relevant to vehicle use: gasoline, reformulated gasoline, natural gas, liquefied petroleum gas, electric power (with onboard battery storage), ethanol, and methanol fuels. The analysis focuses on basic criteria pollutants (reactive organic gases, nitrous oxides, carbon monoxide, sulfurous oxides, and particulates less than 10 microns (PM10)). Emissions of greenhouse gases (carbon dioxide, methane, and nitrous oxide) are also defined. The analysis was conducted for two cases, United States and the State of California and two time frames, current and year 2000.

  14. An Assessment of Uncertainty in Remaining Life Estimation for Nuclear Structural Materials

    SciTech Connect (OSTI)

    Ramuhalli, Pradeep; Griffin, Jeffrey W.; Fricke, Jacob M.; Bond, Leonard J.

    2012-12-01T23:59:59.000Z

    In recent years, several operating US light-water nuclear power reactors (LWRs) have moved to extended-life operations (from 40 years to 60 years), and there is interest in the feasibility of extending plant life to 80 years. Operating experience suggests that material degradation of structural components in LWRs (such as the reactor pressure vessel) is expected to be the limiting factor for safe operation during extended life. Therefore, a need exists for assessing the condition of LWR structural components and determining its remaining useful life (RUL). The ability to estimate RUL of degraded structural components provides a basis for determining safety margins (i.e., whether safe operation over some pre-determined time horizon is possible), and scheduling degradation management activities (such as potentially modifying operating conditions to limit further degradation growth). A key issue in RUL estimation is calculation of uncertainty bounds, which are dependent on current material state, as well as past and future stressor levels (such as time-at-temperature, pressure, and irradiation). This paper presents a preliminary empirical investigation into the uncertainty of RUL estimates for nuclear structural materials.

  15. Neutron measurements of the fuel remaining in the TMI II once-through steam generators (OTSG'S)

    SciTech Connect (OSTI)

    Geelhood, B.D.; Abel, K.H.

    1989-02-01T23:59:59.000Z

    Polypropylene tubes containing a string of 18 copper rods were inserted into the lower head region and each J-leg of the two once-through steam generators (OTSG) of the unit two reactor at Three Mile Island. The object was to measure the neutron flux present in those regions and estimate the amount of residual fuel remaining in each OTSG. The neutron flux from any residual fuel induces a radioisotope, /sup 64/Cu, in the copper coupons. The /sup 64/Cu activity is detected by coincidence counting the two 511-keV gamma rays produced by the annihilation of the positron emitted in the decay of /sup 64/Cu. The copper coupons were placed between two 6-inch diameter, 6-inch long NaI(Tl) crystals and the electronics produced a coincidence count whenever the two gamma rays were uniquely detected. The net coincidence count is proportional to the amount of /sup 64/Cu activity in the coupon. This document discusses calculation methods, statistical methods, and results of this research. 3 figs., 30 tabs.

  16. Long-Term, Autonomous Measurement of Atmospheric Carbon Dioxide Using an Ormosil Nanocomposite-Based Optical Sensor

    SciTech Connect (OSTI)

    Kisholoy Goswami

    2005-10-11T23:59:59.000Z

    The goal of this project is to construct a prototype carbon dioxide sensor that can be commercialized to offer a low-cost, autonomous instrument for long-term, unattended measurements. Currently, a cost-effective CO2 sensor system is not available that can perform cross-platform measurements (ground-based or airborne platforms such as balloon and unmanned aerial vehicle (UAV)) for understanding the carbon sequestration phenomenon. The CO2 sensor would support the research objectives of DOE-sponsored programs such as AmeriFlux and the North American Carbon Program (NACP). Global energy consumption is projected to rise 60% over the next 20 years and use of oil is projected to increase by approximately 40%. The combustion of coal, oil, and natural gas has increased carbon emissions globally from 1.6 billion tons in 1950 to 6.3 billion tons in 2000. This figure is expected to reach 10 billon tons by 2020. It is important to understand the fate of this excess CO2 in the global carbon cycle. The overall goal of the project is to develop an accurate and reliable optical sensor for monitoring carbon dioxide autonomously at least for one year at a point remote from the actual CO2 release site. In Phase I of this project, InnoSense LLC (ISL) demonstrated the feasibility of an ormosil-monolith based Autonomous Sensor for Atmospheric CO2 (ASAC) device. All of the Phase I objectives were successfully met.

  17. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

    2001-05-01T23:59:59.000Z

    Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

  18. Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications

    DOE Patents [OSTI]

    Gay, McMahan; Choi, Sunho; Jones, Christopher W

    2014-09-16T23:59:59.000Z

    A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.

  19. Standard specification for sintered (Uranium-Plutonium) dioxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2001-01-01T23:59:59.000Z

    1.1 This specification covers finished sintered and ground (uranium-plutonium) dioxide pellets for use in thermal reactors. It applies to uranium-plutonium dioxide pellets containing plutonium additions up to 15 % weight. This specification may not completely cover the requirements for pellets fabricated from weapons-derived plutonium. 1.2 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aware of and conform to all applicable international, federal, state, and local regulations pertaining to possessing, processing, shipping, or using source or special nuclear material. Examples of U.S. government documents are Code of Federal Regulations Title 10, Part 50Domestic Licensing of Production and Utilization Facilities; Code of Federal Regulations Title 10, Part 71Packaging and Transportation of Radioactive Material; and Code of Federal Regulations Tit...

  20. Application of optical processing for growth of silicon dioxide

    DOE Patents [OSTI]

    Sopori, B.L.

    1997-06-17T23:59:59.000Z

    A process for producing a silicon dioxide film on a surface of a silicon substrate is disclosed. The process comprises illuminating a silicon substrate in a substantially pure oxygen atmosphere with a broad spectrum of visible and infrared light at an optical power density of from about 3 watts/cm{sup 2} to about 6 watts/cm{sup 2} for a time period sufficient to produce a silicon dioxide film on the surface of the silicon substrate. An optimum optical power density is about 4 watts/cm{sup 2} for growth of a 100{angstrom}-300{angstrom} film at a resultant temperature of about 400 C. Deep level transient spectroscopy analysis detects no measurable impurities introduced into the silicon substrate during silicon oxide production and shows the interface state density at the SiO{sub 2}/Si interface to be very low. 1 fig.