National Library of Energy BETA

Sample records for dioxide co2 sulfur

  1. ARM - Measurement - Carbon dioxide (CO2) concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Carbon dioxide (CO2) concentration The amount of carbon dioxide, a heavy, colorless...

  2. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  3. ARM - Measurement - Carbon dioxide (CO2) flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide, a heavy, colorless greenhouse gas. Categories Atmospheric Carbon, Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  4. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    1996-01-01

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  5. Copper mercaptides as sulfur dioxide indicators

    DOE Patents [OSTI]

    Eller, Phillip G.; Kubas, Gregory J.

    1979-01-01

    Organophosphine copper(I) mercaptide complexes are useful as convenient and semiquantitative visual sulfur dioxide gas indicators. The air-stable complexes form 1:1 adducts in the presence of low concentrations of sulfur dioxide gas, with an associated color change from nearly colorless to yellow-orange. The mercaptides are made by mixing stoichiometric amounts of the appropriate copper(I) mercaptide and phosphine in an inert organic solvent.

  6. Catalytic conversion of sulfur dioxide and trioxide

    SciTech Connect (OSTI)

    Solov'eva, E.L.; Shenfel'd, B.E.; Kuznetsova, S.M.; Khludenev, A.G.

    1987-11-10

    The reclamation and utilization of sulfur-containing wastes from the flue gas of fossil-fuel power plants and the subsequent reduction in sulfur emission is addressed in this paper. The authors approach this problem from the standpoint of the catalytic oxidation of sulfur dioxide on solid poison-resistant catalysts with subsequent sorption of the sulfur trioxide and its incorporation into the manufacture of sulfuric acid. The catalyst they propose is a polymetallic dust-like waste from the copper-smelting industry comprised mainly of iron and copper oxides. Experiments with this catalyst were carried out using multifactorial experiment planning.

  7. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  8. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of

  9. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, R.; Steinberg, M.

    This invention relates to high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280/sup 0/C and containing as little as 36 mo1% ethylene and about 41 to 51 mo1% sulfur dioxide, and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10 to 50/sup 0/C, and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  10. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard; Steinberg, Meyer

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  11. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  12. Process for sequestering carbon dioxide and sulfur dioxide

    DOE Patents [OSTI]

    Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

    2009-10-20

    A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

  13. Inventory of Carbon Dioxide (CO2) Emissions at Pacific Northwest National Laboratory

    SciTech Connect (OSTI)

    Judd, Kathleen S.; Kora, Angela R.; Shankle, Steve A.; Fowler, Kimberly M.

    2009-06-29

    The Carbon Management Strategic Initiative (CMSI) is a lab-wide initiative to position the Pacific Northwest National Laboratory (PNNL) as a leader in science, technology and policy analysis required to understand, mitigate and adapt to global climate change as a nation. As part of an effort to walk the talk in the field of carbon management, PNNL conducted its first carbon dioxide (CO2) emissions inventory for the 2007 calendar year. The goal of this preliminary inventory is to provide PNNL staff and management with a sense for the relative impact different activities at PNNL have on the labs total carbon footprint.

  14. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect (OSTI)

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  15. Utilizing the market to control sulfur dioxide emissions

    SciTech Connect (OSTI)

    Loeher, C.F. III

    1995-12-01

    Environmental policy in the United States is evolving; command and control approaches are being slowly replaced with market-based incentives. Market-based regulation is favorable because it provides the regulated community with flexibility in choosing between pollution control options. A recent application of a market-based approach is Title IV of the 1990 Clean Air Act Amendments. This paper evaluates the advantages of utilizing market-based incentives to control sulfur dioxide emissions. The evaluation embodies an extensive methodology, which provides an overview of the policy governing air quality, discusses pollution control philosophies and analyzes their associated advantages and limitations. Further, it describes the development and operation of a market for emissions trading, impediments to the market, and recommends strategies to improve the market. The evaluation concludes by analyzing the results of five empirical simulations demonstrating the cost-effectiveness of employing market-based incentives versus command-and-control regulation for controlling sulfur dioxide emissions. The results of the evaluation indicate that regulatory barriers and market impediments have inhibited allowance trading. However, many of these obstacles have been or are being eliminated through Federal and state regulations, and through enhancement of the market. Results also demonstrate that sulfur dioxide allowance trading can obtain identical levels of environmental protection as command-and-control approaches while realizing cost savings to government and industry.

  16. Integrated Energy System with Beneficial Carbon Dioxide (CO2) Use - Final Scientific/Technical Report

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy T

    2011-04-29

    This report presents an integrated energy system that combines the production of substitute natural gas through coal hydrogasification with an algae process for beneficial carbon dioxide (CO2) use and biofuel production (funded under Department of Energy (DOE) contract DE-FE0001099). The project planned to develop, test, operate and evaluate a 2 ton-per-day coal hydrogasification plant and 25-acre algae farm at the Arizona Public Service (APS) 1000 Megawatt (MW) Cholla coal-fired power plant in Joseph City, Arizona. Conceptual design of the integrated system was undertaken with APS partners Air Liquide (AL) and Parsons. The process engineering was separated into five major areas: flue gas preparation and CO2 delivery, algae farming, water management, hydrogasification, and biofuel production. The process flow diagrams, energy and material balances, and preliminary major equipment needs for each major area were prepared to reflect integrated process considerations and site infrastructure design basis. The total project also included research and development on a bench-scale hydrogasifier, one-dimensional (1-D) kinetic-model simulation, extensive algae stressing, oil extraction, lipid analysis and a half-acre algae farm demonstration at APS?s Redhawk testing facility. During the project, a two-acre algae testing facility with a half-acre algae cultivation area was built at the APS Redhawk 1000 MW natural gas combined cycle power plant located 55 miles west of Phoenix. The test site integrated flue gas delivery, CO2 capture and distribution, algae cultivation, algae nursery, algae harvesting, dewatering and onsite storage as well as water treatment. The site environmental, engineering, and biological parameters for the cultivators were monitored remotely. Direct biodiesel production from biomass through an acid-catalyzed transesterification reaction and a supercritical methanol transesterification reaction were evaluated. The highest oil-to-biodiesel conversion of 79

  17. Short-Term Energy Outlook Model Documentation: Carbon Dioxide (CO2) Emissions Model

    Reports and Publications (EIA)

    2009-01-01

    Description of the procedures for estimating carbon dioxide emissions in the Short-Term Energy Outlook

  18. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico 2004_deer_hammache.pdf (249.2 KB) More Documents & Publications CLEERS Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis An Improvement of Diesel PM and NOx Reduction System

  19. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  20. Sulfur dioxide emissions from primary copper smelters in the western US

    SciTech Connect (OSTI)

    Mangeng, C.A.; Mead, R.W.

    1980-01-01

    The body of information presented is directed to environmental scientists and policy makers without chemical or metallurgical engineering backgrounds. This paper addresses the problems of reducing sulfur dioxide emissions from primary copper smelters in the western United States and projects the future impact of emissions within a framework of legal, technological, and economic considerations. Methodology used to calculate historical sulfur dioxide emissions is described. Sulfur dioxide emission regulations are outlined as they apply to primary copper smelters. A discussion of available sulfur dioxide control technology and copper smelting processes summarizes the technological and economic problems of reducing copper smelter emissions. Based upon these technological and economic considerations, projections of smelter emissions indicate that compliance with existing legislative requirements will be achieved by 1990. Three smelters are projected to close by 1985.

  1. Sulfur dioxide-induced chronic bronchitis in beagle dogs

    SciTech Connect (OSTI)

    Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

    1984-01-01

    This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

  2. Letter from Commonwealth to Mirant Potomac River Concerning Serious Violations of the National Ambient Air Quality Standards for Sulfur Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE)

    Docket No. EO-05-01: Letter from Commonwealth of Virginia to Mirant Potomac River concerning Serious Violations of the National Ambient Air Quality Standards for Sulfur Dioxide.

  3. A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission

    SciTech Connect (OSTI)

    Fang, Zhigang Zak

    2013-11-05

    The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO{sub 2} emission from the production of titanium dioxide (TiO{sub 2}) pigment. TiO{sub 2} is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO{sub 2} pigment is currently produced primarily by the use of the so called �chloride process�. A key step of the chloride process relies on high temperature carbo-chlorination of TiO{sub 2} bearing raw materials, hence producing large quantities of CO{sub 2}. The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO{sub 2} from high-TiO{sub 2} slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO{sub 2} produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology. These objectives were successfully met and a new process for producing commercial quality TiO{sub 2} pigment was developed and experimentally validated. The process features a unique combination of established metallurgical processes, including alkaline roasting of titania slag followed by leaching, solvent extraction, hydrolysis, and calcination. The caustic, acidic, and organic streams in the process will also be regenerated and reused in the process, greatly reducing environmental waste. The purpose and effect of each of these steps in producing purified TiO{sub 2} is detailed in the report. The levels of impurities in our pigment meet the requirements for commercial pigment, and are nearly equivalent to those of two commercial pigments. Solvent extraction with an amine extractant

  4. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  5. Modified dry limestone process for control of sulfur dioxide emissions

    DOE Patents [OSTI]

    Shale, Correll C.; Cross, William G.

    1976-08-24

    A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

  6. Natural sulfur flux from the Gulf of Mexico: dimethyl sulfide, carbonyl sulfide, and sulfur dioxide. Technical report

    SciTech Connect (OSTI)

    Van Valin, C.C.; Luria, M.; Wellman, D.L.; Gunter, R.L.; Pueschel, R.F.

    1987-06-01

    Atmospheric measurements of natural sulfur compounds were performed over the northern Gulf of Mexico during the late summer months of 1984. Air samples were collected with an instrumented aircraft at elevations of 30-3500 m, during both day and night. Most air samples were representative of the clean maritime atmosphere, although some were from continental contaminated air during periods of offshore flow at the coastline. In all samples, carbonyl sulfide concentrations were within the range of 400-500 pptv. Conversely, the dimethyl sulfide concentrations showed significant variability: during clean atmospheric conditions the average of all measurements was 27 pptv, whereas under polluted conditions the average was 7 pptv. Measureable quantities of dimethyl sulfide (>5 pptv) were not observed above the boundary layer. The average sulfur dioxide concentration measured in the marine (clean) atmosphere was 215 pptv, which is consistent with the oxidation of dimethyl sulfide being its major source.

  7. Advection of sulfur dioxide over the western Atlantic Ocean during CITE 3

    SciTech Connect (OSTI)

    Thornton, D.C.; Bandy, A.R.; Beltz, N.; Driedger, A.R. III; Ferek, R. ||

    1993-12-01

    During the NASA Chemical Instrumentation Test and Evaluation 3 sulfur intercomparison over the western Atlantic Ocean, five techniques for the determination of sulfur dioxide were evaluated. The response times of the techniques varied from 3 to 30 min. Based on the ensemble of measurements reported, it was clear that advection of SO2 from the North American continent occurred in the boundary layer (altitude less than 1 km) with only one exception. The vertical distribution of SO2 above the boundary layer for the northern and southern Atlantic Ocean was remarkably similar duing this experiment.

  8. Bench-Scale Process for Low-Cost Carbon Dioxide (CO2) Capture Using a Phase-Changing Absorbent

    SciTech Connect (OSTI)

    Westendorf, Tiffany; Caraher, Joel; Chen, Wei; Farnum, Rachael; Perry, Robert; Spiry, Irina; Wilson, Paul; Wood, Benjamin

    2015-03-31

    The objective of this project is to design and build a bench-scale process for a novel phase-changing aminosilicone-based CO2-capture solvent. The project will establish scalability and technical and economic feasibility of using a phase-changing CO2-capture absorbent for post-combustion capture of CO2 from coal-fired power plants with 90% capture efficiency and 95% CO2 purity at a cost of $40/tonne of CO2 captured by 2025 and a cost of <$10/tonne of CO2 captured by 2035. In the first budget period of this project, the bench-scale phase-changing CO2 capture process was designed using data and operating experience generated under a previous project (ARPA-e project DE-AR0000084). Sizing and specification of all major unit operations was completed, including detailed process and instrumentation diagrams. The system was designed to operate over a wide range of operating conditions to allow for exploration of the effect of process variables on CO2 capture performance.

  9. Carbon Dioxide Transport and Sorption Behavior in Confined Coal Cores for Enhanced Coalbed Methane and CO2 Sequestration

    SciTech Connect (OSTI)

    Jikich, S.A.; McLendon, T.R.; Seshadri, K.S.; Irdi, G.A.; Smith, D.H.

    2007-11-01

    Measurements of sorption isotherms and transport properties of CO2 in coal cores are important for designing enhanced coalbed methane/CO2 sequestration field projects. Sorption isotherms measured in the lab can provide the upper limit on the amount of CO2 that might be sorbed in these projects. Because sequestration sites will most likely be in unmineable coals, many of the coals will be deep and under considerable lithostatic and hydrostatic pressures. These lithostatic pressures may significantly reduce the sorption capacities and/or transport rates. Consequently, we have studied apparent sorption and diffusion in a coal core under confining pressure. A core from the important bituminous coal Pittsburgh #8 was kept under a constant, three-dimensional external stress; the sample was scanned by X-ray computer tomography (CT) before, then while it sorbed, CO2. Increases in sample density due to sorption were calculated from the CT images. Moreover, density distributions for small volume elements inside the core were calculated and analyzed. Qualitatively, the computerized tomography showed that gas sorption advanced at different rates in different regions of the core, and that diffusion and sorption progressed slowly. The amounts of CO2 sorbed were plotted vs. position (at fixed times) and vs. time (for various locations in the sample). The resulting sorption isotherms were compared to isotherms obtained from powdered coal from the same Pittsburgh #8 extended sample. The results showed that for this single coal at specified times, the apparent sorption isotherms were dependent on position of the volume element in the core and the distance from the CO2 source. Also, the calculated isotherms showed that less CO2 was sorbed than by a powdered (and unconfined) sample of the coal. Changes in density distributions during the experiment were also observed. After desorption, the density distribution of calculated volume elements differed from the initial distribution

  10. CO2 Injection in Kansas Oilfield Could Greatly Increase Production, Permanently Store Carbon Dioxide, DOE Study Says

    Broader source: Energy.gov [DOE]

    The feasibility of using carbon dioxide injection for recovering between 250 million and 500 million additional barrels of oil from Kansas oilfields has been established in a study funded by the U.S. Department of Energy.

  11. Regional Opportunities for Carbon Dioxide Capture and Storage in China: A Comprehensive CO2 Storage Cost Curve and Analysis of the Potential for Large Scale Carbon Dioxide Capture and Storage in the People’s Republic of China

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Li, Xiaochun; Davidson, Casie L.; Wei, Ning; Dooley, James J.

    2009-12-01

    This study presents data and analysis on the potential for carbon dioxide capture and storage (CCS) technologies to deploy within China, including a survey of the CO2 source fleet and potential geologic storage capacity. The results presented here indicate that there is significant potential for CCS technologies to deploy in China at a level sufficient to deliver deep, sustained and cost-effective emissions reductions for China over the course of this century.

  12. CO2 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Our Jobs Our Jobs Working at NNSA Blog Home CO2 CO2 'Underground battery' could store renewable energy, sequester CO2 This integrated system would store carbon dioxide in an...

  13. Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

  14. EVALUATION OF PROTON-CONDUCTING MEMBRANES FOR USE IN A SULFUR-DIOXIDE DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D.; Elvington, M.; Colon-Mercado, H.

    2009-11-11

    The chemical stability, sulfur dioxide transport, ionic conductivity, and electrolyzer performance have been measured for several commercially available and experimental proton exchange membranes (PEMs) for use in a sulfur dioxide depolarized electrolyzer (SDE). The SDE's function is to produce hydrogen by using the Hybrid Sulfur (HyS) Process, a sulfur based electrochemical/thermochemical hybrid cycle. Membrane stability was evaluated using a screening process where each candidate PEM was heated at 80 C in 60 wt. % H{sub 2}SO{sub 4} for 24 hours. Following acid exposure, chemical stability for each membrane was evaluated by FTIR using the ATR sampling technique. Membrane SO{sub 2} transport was evaluated using a two-chamber permeation cell. SO{sub 2} was introduced into one chamber whereupon SO{sub 2} transported across the membrane into the other chamber and oxidized to H{sub 2}SO{sub 4} at an anode positioned immediately adjacent to the membrane. The resulting current was used to determine the SO{sub 2} flux and SO{sub 2} transport. Additionally, membrane electrode assemblies (MEAs) were prepared from candidate membranes to evaluate ionic conductivity and selectivity (ionic conductivity vs. SO{sub 2} transport) which can serve as a tool for selecting membranes. MEAs were also performance tested in a HyS electrolyzer measuring current density versus a constant cell voltage (1V, 80 C in SO{sub 2} saturated 30 wt% H2SO{sub 4}). Finally, candidate membranes were evaluated considering all measured parameters including SO{sub 2} flux, SO{sub 2} transport, ionic conductivity, HyS electrolyzer performance, and membrane stability. Candidate membranes included both PFSA and non-PFSA polymers and polymer blends of which the non-PFSA polymers, BPVE-6F and PBI, showed the best selectivity.

  15. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture...

  16. An intercomparison of aircraft instrumentation for tropospheric measurements of sulfur dioxide

    SciTech Connect (OSTI)

    Gregory, G.L.; Davis, D.D.; Beltz, N.; Bandy, A.R.; Ferek, R.J.; Thornton, D.C. [NASA, Langely Research Center, Hampton, VA (United States)]|[Georgia Institute of Technology, Atlanta, GA (United States)]|[J.W. Goethe Univ., Frankfurt (Germany)]|[Drexel Univ., Philadelphia, PA (United States)]|[Univ. of Washington, Seattle, WA (United States)

    1993-12-01

    As part of the NASA Tropospheric Chemistry Program, a series of field intercomparisons have been conducted to evaluate the state-of-the art for measuring key tropospheric species. One of the objectives of the third intercomparison campaign in this series, Chemical Instrumentation Test and Evaluation 3 (CITE 3), was to evaluate instrumentation for making reliable tropospheric aircraft measurements of sulfur dioxide, dimethyl sulfide, hydrogen sulfide, carbon disulfide, and carbonyl sulfide. This paper reports the results of the intercomparisons of five sulfur dioxide measurement methods ranging from filter techniques, in which samples collected in flight are returned to the laboratory for analyses (chemiluminescent or ion chromatographic), to near real-time, in-flight measurements via gas chromatographic, mass spectrometric, and chemiluminescent techniques. All techniques showed some tendency to track sizeable changes in ambient SO2 such as those associated with altitude changes. For SO2 mixing ratios in the range of 200 pptv to a few ppbv, agreement among the techniques varies from about 30% to several orders of magnitude, depending upon the pair of measurements intercompared. For SO2 mixing ratios less than 200 pptv, measurements from the techniques are uncorrelated. In general, observed differences in the measurement of standards do not account for the flight results. The CITE 3 results do not unambiguously identify one or more of the measurement techniques as providing valid or invalid SO2 measurements, but identify the range of `potential` uncertainty in SO2 measurements reported by currently available instrumentation and as measured under realistic aircraft environments.

  17. New analytical reagents for the determination of sulfur dioxide and carbon monoxide

    SciTech Connect (OSTI)

    Trump, E.L.

    1987-01-01

    Four solid reagent methods were developed for the determination of sulfur dioxide in air, and one method was developed to measure carbon monoxide. When applied to filter paper with acetamide as the humectant and 4-phenylcyclohexanone as a bisulfite absorbent, oxohydroxybis(8-hydroxyquinolinyl-) vanadium (V) changes from yellow to black in the presence of sulfur dioxide. The three other methods, also on a filter paper support, utilized the reduction of bromate to bromine which then changed 3-,3'-, 5-,5'-tetramethylbenzidine from yellow to blue, phenothiazine from white to green, and 4-dimethylamino-4'-,4/double prime/-dimethoxytriphenylmethanol from colorless to red-purple. Quantitative measurements were made by reflectance spectroscopy. The method for carbon monoxide involved the use of tetrakis (acetamide-) Pd(II) ditetrafluoroborate, sodium iodate, and leuco crystal violet all together on a filter paper support. Carbon monoxide reduced the Pd(II)-acetamide complex to metallic palladium. The metallic palladium then reduced iodate to hypoiodous acid, HOI, which, in turn, oxidized leuco crystal violet to crystal violet. The crystal violet color was then measured by reflectance.

  18. CO2 Utilization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Utilization CO2 Utilization Carbon dioxide (CO2) use and reuse efforts focus on the conversion of CO2 to useable products and fuels that will reduce CO2 emissions in areas where geologic storage may not be an optimal solution. These include: Enhanced Oil/Gas Recovery - Injecting CO2 into depleting oil or gas bearing fields to maximize the amount of CO2 that could be stored as well as maximize hydrocarbon production. View the latest projects selected in FY 2014. CO2 as Feedstock - Use CO2 as

  19. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  20. Airborne measurements of sulfur dioxide, dimethyl sulfide, carbon disulfide, and carbonyl sulfide by isotope dilution gas chromatography/mass spectrometry

    SciTech Connect (OSTI)

    Bandy, A.R.; Thornton, D.C.; Driedger, A.R. III [Drexel Univ., Philadelphia, PA (United States)

    1993-12-01

    A gas chromatograph/mass spectrometer is described for determining atmospheric sulfur dioxide, carbon disulfide, dimethyl sulfide, and carbonyl sulfide from aircraft and ship platforms. Isotopically labelled variants of each analyte were used as internal standards to achieve high precision. The lower limit of detection for each species for an integration time of 3 min was 1 pptv for sulfur dioxide and dimethyl sulfide and 0.2 pptv for carbon disulfide and carbonyl sulfide. All four species were simultaneously determined with a sample frequency of one sample per 6 min or greater. When only one or two species were determined, a frequency of one sample per 4 min was achieved. Because a calibration is included in each sample, no separate calibration sequence was needed. Instrument warmup was only a few minutes. The instrument was very robust in field deployments, requiring little maintenance.

  1. Large-Scale Utilization of Biomass Energy and Carbon Dioxide Capture and Storage in the Transport and Electricity Sectors under Stringent CO2 Concentration Limit Scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-08-05

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to meet atmospheric concentrations of CO2 at 400ppm and 450ppm by the end of the century. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. A key aspect of the research presented here is that the costs of processing and transporting biomass energy at much larger scales than current experience are explicitly incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced globally by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the majority source, along with growing utilization of waste-to-energy. The ability to draw on a diverse set of biomass based feedstocks helps to reduce the pressure for drastic large-scale changes in land use and the attendant environmental, ecological, and economic consequences those changes would unleash. In terms of the conversion of bioenergy feedstocks into value added energy, this paper demonstrates that biomass is and will continue to be used to generate electricity as well as liquid transportation fuels. A particular focus of this paper is to show how climate policies and technology assumptions - especially the availability of carbon dioxide capture and storage (CCS) technologies - affect the decisions made about where the biomass is used in the energy system. The potential for net-negative electric sector emissions through the use of CCS with biomass feedstocks provides an attractive part of the solution for meeting stringent

  2. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Maine

    SciTech Connect (OSTI)

    2008-10-01

    Analysis of the expected impacts of 1000 MW of wind power in Maine, including economic benefits, CO2 emissions reductions, and water conservation.

  3. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Arizona

    SciTech Connect (OSTI)

    2008-10-01

    Analysis of the expected impacts of 1000 MW of wind power in Arizona, including economic benefits, CO2 emissions reductions, and water conservation.

  4. Regional versus global? -- Will strategies for reduction of sulfur dioxide emissions from electric utilities increase carbon dioxide emissions?

    SciTech Connect (OSTI)

    Randolph, J.C.; Dolsak, N.

    1996-12-31

    Electric utilities, which are dependent on high-sulfur coal are expected to reduce their SO{sub 2} emissions. The strategies for reduction of SO{sub 2} emissions may result in increased CO{sub 2} emissions. Thereby decrease of regional pollution may cause increase of global pollution. Environmental, political, moral, and economic consequences of the two types of pollution differ significantly. Midwestern electric utilities, USA, which are dependent on high-sulfur coal, are analyzed in the paper. However, the same problem is relevant for some European coal fueled power plants. Strategies for reduction of SO{sub 2} emissions, employed by Midwestern electric utilities to comply with the clean Air Act amendments (CAAA) of 1990 and their possible affects on CO{sub 2} emissions, are presented. The paper focuses on two general strategies for reduction of SO{sub 2} emissions. First is coal-switching or blending with a low-sulfur coal. Second is construction and use of flue-gas desulfurization devices (scrubbers). A combination of both strategies is also a viable option. Switching to low-sulfur coal may result in larger CO{sub 2} emissions because that coal has different characteristics and has to be transported much greater distances. Scrubbers require significant amounts of energy for their operation which requires burning more coal. This increases the level of CO{sub 2} emissions.

  5. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  6. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  7. In Situ Study of CO2 and H2O Partitioning Between Na-Montmorillonite and Variably Wet Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Loring, John S.; Ilton, Eugene S.; Chen, Jeffrey; Thompson, Christopher J.; Martin, Paul F.; Benezeth, Pascale; Rosso, Kevin M.; Felmy, Andrew R.; Schaef, Herbert T.

    2014-06-03

    Shale formations play fundamental roles in large-scale geologic carbon sequestration (GCS) aimed primarily to mitigate climate change, and in smaller-scale GCS targeted mainly for CO2-enhanced gas recovery operations. In both technologies, CO2 is injected underground as a supercritical fluid (scCO2), where interactions with shale minerals could influence successful GCS implementation. Reactive components of shales include expandable clays, such as montmorillonites and mixed-layer illite/smectite clays. In this work, we used in situ X-ray diffraction (XRD) and in situ infrared (IR) spectroscopy to investigate the swelling/shrinkage and water/CO2 sorption of a pure montmorillonite, Na-SWy-2, when the clay is exposed to variably hydrated scCO2 at 50 °C and 90 bar. Measured interlayer spacings and sorbed water concentrations at varying levels of scCO2 hydration are similar to previously reported values measured in air at ambient pressure over a range of relative humidities. IR spectra show evidence of both water and CO2 intercalation, and variations in peak shapes and positions suggest multiple sorbed types with distinct chemical environments. Based on the intensity of the asymmetric CO stretching band of the CO2 associated with the Na-SWy-2, we observed a significant increase in sorbed CO2 as the clay expands from a 0W to a 1W state, suggesting that water props open the interlayer so that CO2 can enter. However, as the clay transitions from a 1W to a 2W state, CO2 desorbs sharply. These observations were placed in the context of two conceptual models concerning hydration mechanisms for expandable clays and were also discussed in light of recent theoretical studies on CO2-H2O-clay interactions. The swelling/shrinkage of expandable clays could affect solid volume, porosity, and permeability of shales. Consequently, the results from this work could aid predictions of shale caprock integrity in large-scale GCS, as well as methane transmissivity in enhanced gas recovery

  8. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Arizona (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Arizona. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Arizona to be $1.15 billion, annual CO2 reductions are estimated at 2.0 million tons, and annual water savings are 818 million gallons.

  9. Economic Benefits, Carbon Dioxide (CO2) Emissions Reduction, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Georgia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Georgia. We forecast the cumulative economic benefits from 1000 MW of development in Georgia to be $2.1 billion, annual CO2 reductions are estimated at 3.0 million tons, and annual water savings are 1,628 million gallons.

  10. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  11. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  12. Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration

    SciTech Connect (OSTI)

    Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

    2008-09-30

    The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have

  13. ARM - Campaign Instrument - co2air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Airborne Carbon Dioxide Analyzer System (CO2AIR) Instrument Categories...

  14. ARM - Campaign Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Flux Measurement Systems (CO2FLX) Instrument Categories...

  15. 2011 NETL CO2 Capture Technology Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Pilot Test of Novel Electrochemical Membrane System for Carbon Dioxide Capture and Power Generation (FE0026580) Hossein Ghezel-Ayagh, FuelCell Energy, Inc. 4:00 p.m. CO2 Capture ...

  16. ARM - Campaign Instrument - co2lidar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Doppler Lidar (CO2LIDAR) Instrument Categories Cloud Properties Campaigns Remote Cloud...

  17. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Maine (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Maine. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Maine to be $1.3 billion, annual CO2 reductions are estimated at 2.8 million tons, and annual water savings are 1,387 million gallons.

  18. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in North Carolina (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-03-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in North Carolina. Although construction and operation of 1000 MW of wind power is a significant effort, seven states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in North Carolina to be $1.1 billion, annual CO2 reductions are estimated at 2.9 million tons, and annual water savings are 1,558 million gallons.

  19. Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer

    SciTech Connect (OSTI)

    Ji-lu Chen

    1993-12-31

    Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

  20. Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

    SciTech Connect (OSTI)

    Smith, P.V.

    1995-12-31

    Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

  1. Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control

    SciTech Connect (OSTI)

    Li, Liyu; King, David L.

    2010-01-23

    It is known that sulfur oxides contribute significantly and deleteriously to the overall performance of lean-burn diesel engine aftertreatment systems, especially in the case of NOx traps. A Ag-based, fast regenerable SO2 absorbent has been developed and will be described. Over a temperature range of 300oC to 550oC, it absorbs almost all of the SO2 in the simulated exhaust gases during the lean cycles and can be fully regenerated by the short rich cycles at the same temperature. Its composition has been optimized as 1 wt% Pt-5wt%Ag-SiO2, and the preferred silica source for the supporting material has been identified as inert Cabosil fumed silica. The thermal instability of Ag2O under fuel-lean conditions at 230oC and above makes it possible to fast regenerate the sulfur-loaded absorbent during the following fuel-rich cycles. Pt catalyst helps reducing Ag2SO4 during rich cycles at low temperatures. And the chemically inert fumed SiO2 support gives the absorbent long term stability. This absorbent shows great potential to work under the same lean-rich cycling conditions as those imposed on the NOx traps, and thus, can protect the downstream particulate filter and the NOx trap from sulfur poisoning.

  2. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture Previous Next List Jihan Kim, Li-Chiang Lin, Joseph A. Swisher, Maciej Haranczyk, and...

  3. Commercial CO2 Electric HPWH | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    PROJECT OBJECTIVE Residential heat pump water heaters (HPWH) that use carbon dioxide (CO2) ... Information flow schematic for an integrated heat pump design model and wrapped tank ...

  4. Microsoft Word - CO2 Supplement.doc

    Gasoline and Diesel Fuel Update (EIA)

    Understanding the Decline in Carbon Dioxide Emissions in 2009 1 EIA projects carbon dioxide (CO2) emissions from fossil fuels in 2009 to be 5.9 percent below the 2008 level in the Short-Term Energy Outlook, October 2009 (STEO) (Table 1). Projected coal CO2 emissions fall by 10.1 percent in 2009, primarily because of lower consumption for electricity generation. Coal accounts for 63 percent of the total decline in CO2 emissions from fossil fuels this year. Forecast lower natural gas and petroleum

  5. The last decade of global anthropogenic sulfur dioxide: 2000-2011 emissions

    SciTech Connect (OSTI)

    Klimont, Z.; Smith, Steven J.; Cofala, Janusz

    2013-01-09

    Evolution of global and regional anthropogenic SO2 emissions in the last decade has been estimated through a bottom-up calculation for recent years. After a strong increase in emissions that peaked about 2006, we estimate a declining trend continuing until 2011. However, there is a strong spatial variability with North America and Europe continuing to reduce emissions with an increasing role of Asia and international shipping. China remains a key contributor but the introduction of stricter emission limits followed by an ambitious program of installing flue gas desulfurization on power plants resulted in significant decline in emissions from energy sector and stabilization of Chinese SO2 emissions. Comparable mitigation strategies are not yet present in several other Asian countries and industrial sectors in general, while emissions from international shipping are expected to start declining soon following agreed reduction of sulfur content of fuel oil. Estimated trends in global SO2 emissions are within the range of RCP projections and uncertainty calculated for the year 2005.

  6. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  7. CO2 Injection Begins in Illinois | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Injection Begins in Illinois CO2 Injection Begins in Illinois November 17, 2011 - 12:00pm Addthis Washington, DC - The Midwest Geological Sequestration Consortium (MGSC), one of seven regional partnerships created by the U.S. Department of Energy (DOE) to advance carbon storage technologies nationwide, has begun injecting carbon dioxide (CO2) for their large-scale CO2 injection test in Decatur, Illinois. The test is part of the development phase of the Regional Carbon Sequestration

  8. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H.

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  9. Quantum Alloys Offer Prospects for CO2 Management Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with sulfur and gold atoms in a "shell" to form the Au2525 catalyst for CO2 remediation. ... When common household metals, such as copper, gold, or silver, are reduced in size to ...

  10. Final Report - "CO2 Sequestration in Cell Biomass of Chlorobium Thiosulfatophilum"

    SciTech Connect (OSTI)

    James L. Gaddy, PhD; Ching-Whan Ko, PhD

    2009-05-04

    World carbon dioxide emissions from the combustion of fossil fuels have increased at a rate of about 3 percent per year during the last 40 years to over 24 billion tons today. While a number of methods have been proposed and are under study for dealing with the carbon dioxide problem, all have advantages as well as disadvantages which limit their application. The anaerobic bacterium Chlorobium thiosulfatophilum uses hydrogen sulfide and carbon dioxide to produce elemental sulfur and cell biomass. The overall objective of this project is to develop a commercial process for the biological sequestration of carbon dioxide and simultaneous conversion of hydrogen sulfide to elemental sulfur. The Phase I study successfully demonstrated the technical feasibility of utilizing this bacterium for carbon dioxide sequestration and hydrogen sulfide conversion to elemental sulfur by utilizing the bacterium in continuous reactor studies. Phase II studies involved an advanced research and development to develop the engineering and scale-up parameters for commercialization of the technology. Tasks include culture isolation and optimization studies, further continuous reactor studies, light delivery systems, high pressure studies, process scale-up, a market analysis and economic projections. A number of anaerobic and aerobic microorgansims, both non-photosynthetic and photosynthetic, were examined to find those with the fastest rates for detailed study to continuous culture experiments. C. thiosulfatophilum was selected for study to anaerobically produce sulfur and Thiomicrospira crunogena waws selected for study to produce sulfate non-photosynthetically. Optimal conditions for growth, H2S and CO2 comparison, supplying light and separating sulfur were defined. The design and economic projections show that light supply for photosynthetic reactions is far too expensive, even when solar systems are considered. However, the aerobic non-photosynthetic reaction to produce sulfate with T

  11. CO2 on the Integrity of Well Cement | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Utilization CO2 Utilization Carbon dioxide (CO2) use and reuse efforts focus on the conversion of CO2 to useable products and fuels that will reduce CO2 emissions in areas where geologic storage may not be an optimal solution. These include: Enhanced Oil/Gas Recovery - Injecting CO2 into depleting oil or gas bearing fields to maximize the amount of CO2 that could be stored as well as maximize hydrocarbon production. View the latest projects selected in FY 2014. CO2 as Feedstock - Use CO2 as

  12. Novel CO2-Thickeners for Improved Mobility Control

    SciTech Connect (OSTI)

    Enick, Dr. Robert M.; Beckman, Dr. Eric J.; Hamilton, Dr. Andrew

    2002-01-15

    The objective of this contract was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO2.

  13. Researchers Uncover Copper's Potential for Reducing CO2 Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    When used as a part of a promising coal combustion technology known as chemical looping, copper can help economically remove carbon dioxide (CO2) from fossil fuel emissions. In ...

  14. Bees, Balloons, Pollen Used as Novel CO2 Monitoring Approach

    Broader source: Energy.gov [DOE]

    Researchers at the Office of Fossil Energy's National Energy Technology Laboratory have discovered an innovative way to use bees, pollen, and helium-filled balloons to verify that no carbon dioxide (CO2) leaks from carbon sequestration sites.

  15. DOE Manual Studies 11 Major CO2 Geologic Storage Formations

    Broader source: Energy.gov [DOE]

    A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

  16. CO2 Capture and Storage Project, Education and Training Center...

    Broader source: Energy.gov (indexed) [DOE]

    It's the process of capturing and storing or re-using carbon dioxide (CO2) from coal-fired ... from Archer Daniels Midland's ethanol plant in Decatur, transported via a mile-long ...

  17. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is ...

  18. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    This carbon dioxide (CO2) has been injected in the United States as part of DOEs Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the...

  19. 12,877,644 Metric Tons of CO2 Injected as of July 1, 2016

    Broader source: Energy.gov [DOE]

    This carbon dioxide (CO2) has been injected in the United States as part of DOE’s Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the...

  20. 'Underground battery' could store renewable energy, sequester CO2 |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) 'Underground battery' could store renewable energy, sequester CO2 Wednesday, January 6, 2016 - 2:40pm NNSA Blog This integrated system would store carbon dioxide in an underground reservoir, with concentric rings of horizontal wells confining the pressurized CO2 beneath the caprock. Stored CO2 displaces brine that flows up wells to the surface where it is heated by thermal plants (e.g., solar farms) and reinjected into the reservoir to store

  1. Communication: Theoretical prediction of the importance of the {sup 3}B{sub 2} state in the dynamics of sulfur dioxide

    SciTech Connect (OSTI)

    Lvque, Camille; CNRS, LCPMR, UMR 7614, Paris Cedex 05; Theoretische Chemie, Physikalisch-Chemisches Institut, Universitt Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg ; Taeb, Richard; CNRS, LCPMR, UMR 7614, Paris Cedex 05 ; Kppel, Horst

    2014-03-07

    Even though the sulfur dioxide molecule has been extensively studied over the last decades, its photo-excitation dynamics is still unclear, due to its complexity, combining conical intersections, and spin-orbit coupling between a manifold of states. We present a comprehensive ab initio study of the intersystem crossing of the molecule in the low energy domain, based on a wave-packet propagation on the manifold of the lowest singlet and triplet states. Furthermore, spin-orbit couplings are evaluated on a geometry-dependent grid, and diabatized along with the different conical intersections. Our results show for the first time the primordial role of the triplet {sup 3}B{sub 2} state and furthermore predict novel interference patterns due to the different intersystem crossing channels induced by the spin-orbit couplings and the shapes of the different potential energy surfaces. These give new insight into the coupled singlet-triplet dynamics of SO{sub 2}.

  2. Capturing and Converting CO2 in a Single Step | U.S. DOE Office...

    Office of Science (SC) Website

    Capturing and Converting CO2 in a Single Step Researchers computationally design a cheap, ... carbon dioxide should provide design strategies for efficient, less expensive catalysts. ...

  3. Supercritical CO2 Tech Team

    Broader source: Energy.gov [DOE]

    Supercritical CO2 is a highly technical team focused on different heat source applications of the sCO2 Brayton Cycle.

  4. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  5. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    Open Energy Info (EERE)

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  6. Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides

    DOE Patents [OSTI]

    Ramkumar, Shwetha; Fan, Liang-Shih

    2015-11-04

    A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

  7. Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides

    DOE Patents [OSTI]

    Ramkumar, Shwetha; Fan, Liang-Shih

    2013-07-30

    A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

  8. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluating a new approach to CO2 capture and storage Evaluating a new approach to CO2 capture and storage In a perspective paper published in Greenhouse Gases: Science and Technology, researchers examined a new approach that could potentially overcome many barriers to deployment and jumpstart this process on a commercial scale. September 13, 2015 Map of the contiguous United States shows the location of facilities that produce high-value chemicals/products and the amount of carbon dioxide

  9. Industrial CO2 Removal: CO2 Capture from Ambient Air and Geological Sequestration

    SciTech Connect (OSTI)

    Dooley, James J.

    2011-06-08

    This abstract and its accompanying presentation will provide an overview of two distinct industrial processes for removing carbon dioxide (CO2) from the atmosphere as a means of addressing anthropogenic climate change. The first of these is carbon dioxide capture and storage (CCS) coupled with large scale biomass production (hereafter referred to as bioCCS). The second is CO2 capture from ambient air via industrial systems (hereafter referred to as direct air capture (DAC)). In both systems, the captured CO2 would be injected into deep geologic formations so as to isolate it from the atmosphere. The technical literature is clear that both of these technologies are technically feasible as of today (IPCC, 2005; Keith, 2009; Lackner, 2009; Luckow et al., 2010; Ranjan and Herzog, 2011). What is uncertain is the relative cost of these industrial ambient-air CO2 removal systems when compared to other emissions mitigation measures, the ultimate timing and scale of their deployment, and the resolution of potential site specific constraints that would impact their ultimate commercial deployment.

  10. Geothermal Startup Will Put Carbon Dioxide to Good Use

    Broader source: Energy.gov [DOE]

    Geothermal power holds enormous opportunities to provide affordable, clean energy that avoids greenhouse gases like carbon dioxide (CO2).

  11. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  12. High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor

    SciTech Connect (OSTI)

    Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

    2011-07-31

    Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

  13. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium

  15. Project Profile: Lifetime Model Development for Supercritical CO2 CSP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems (SuNLaMP) | Department of Energy Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Funding Program: SuNLaMP SunShot Subprogram: CSP Location: Oak Ridge National Laboratory, Oak Ridge, TN SunShot Award Amount: $2,175,000 This project seeks to develop a predictive lifetime model for materials in supercritical carbon dioxide (sCO2) conditions similar to

  16. Chapter 9 - Energy-related CO2 emission

    Gasoline and Diesel Fuel Update (EIA)

    9 U.S. Energy Information Administration | International Energy Outlook 2016 Chapter 9 Energy-related CO2 emissions Overview Because anthropogenic emissions of carbon dioxide (CO2) result primarily from the combustion of fossil fuels, energy consumption is at the center of the climate change debate. In the International Energy Outlook 2016 (IEO2016) Reference case, world energy- related CO2 emissions 331 increase from 32.3 billion metric tons in 2012 to 35.6 billion metric tons in 2020 and to

  17. 10 MW Supercritical CO2 Turbine Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 MW Supercritical CO2 Turbine Project 10 MW Supercritical CO2 Turbine Project This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042313_turchi.pdf (1.86 MB) More Documents & Publications 10-Megawatt Supercritical Carbon Dioxide Turbine - FY13 Q2 10-MW Supercritical-CO2 Turbine Degradation Mechanisms and Development of Protective Coatings for TES and HTF Containment Materials

  18. Electron Transfer Dynamics in Photocatalytic CO2 Conversion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Transfer Dynamics in Photocatalytic CO2 Conversion Electron Transfer Dynamics in Photocatalytic CO2 Conversion Coal is the workhorse of our power industry, responsible for approximately half of the electricity consumed by Americans. Managing carbon dioxide (CO2) emissions from coal utilization is one of the most challenging issues facing the fossil energy industry today. To cost-effectively capture and manage CO2, new and flexible photocatalytic technologies are being developed that can

  19. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the suitability of geologic formations for secure storage of carbon dioxide (CO2). The minerals may affect the reservoir storage capacity as well as the integrity of its natural seals such as caprock formations. CO2 interaction with swelling clays such as smectites is a complex process involving physisorption in micropores and

  20. 10 MW Supercritical CO2 Turbine Test (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    10 MW Supercritical CO2 Turbine Test Citation Details In-Document Search Title: 10 MW Supercritical CO2 Turbine Test The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved

  1. CO2 Sequestration short course

    SciTech Connect (OSTI)

    DePaolo, Donald J.; Cole, David R; Navrotsky, Alexandra; Bourg, Ian C

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  2. Trinity CO2 LLC | Open Energy Information

    Open Energy Info (EERE)

    CO2 LLC Jump to: navigation, search Name: Trinity CO2 LLC Place: Texas Product: String representation "Trinity CO2 LLC ... smission lines." is too long. References: Trinity CO2...

  3. Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16S_2005 (11 January - 24 February, 2005)

    SciTech Connect (OSTI)

    Kozyr, Alex

    2006-08-30

    This report presents methods, and analytical and quality control procedures for salinity, oxygen, nutrient, inorganic carbon, organic carbon, chlorofluorocarbon (CFC), and bomb 14C system parameters performed during the A16S_2005 cruise, which took place from January 11 to February 24, 2005, aboard research vessel (R/V) Ronald H. Brown under the auspices of the National Oceanic and Atmospheric Administration (NOAA). The R/V Ronald H. Brown departed Punta Arenas, Chile, on January 11, 2005, and ended its cruise in Fortaleza, Brazil, on February 24, 2005. The research conducted was one of a series of repeat hydrography sections jointly funded by NOAA and the National Science Foundation as part of the CLIVAR/CO2/repeat hydrography/tracer program. Samples were taken from 36 depths at 121 stations. The data presented in this report include the analyses of water samples for total inorganic carbon (TCO2), fugacity of CO2 (fCO2), total alkalinity (TALK), pH, dissolved organic carbon (DOC), CFC, 14C, hydrographic, and other chemical measurements. The R/V Ronald H. Brown A16S_2005 data set is available free of charge as a numeric data package (NDP) from the Carbon Dioxide Information Analysis Center (CDIAC). The NDP consists of the oceanographic data files and this printed documentation, which describes the procedures and methods used to obtain the data.

  4. Watch Our CO2 Drop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Watch Our CO2 Drop Watch Our CO2 Drop

  5. ARM - Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsco2flx Documentation CO2FLX : Handbook ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  6. Method of detecting sulfur dioxide

    DOE Patents [OSTI]

    Spicer, Leonard D.; Bennett, Dennis W.; Davis, Jon F.

    1985-01-01

    (CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.

  7. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  8. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  9. Does elevated CO2 alter silica uptake in trees?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fulweiler, Robinson W.; Maguire, Timothy J.; Carey, Joanna C.; Finzi, Adrien C.

    2015-01-13

    Human activities have greatly altered global carbon (C) and Nitrogen (N) cycling. In fact, atmospheric concentrations of carbon dioxide (CO2) have increased 40% over the last century and the amount of N cycling in the biosphere has more than doubled. In an effort to understand how plants will respond to continued global CO2 fertilization, longterm free-air CO2 enrichment experiments have been conducted at sites around the globe. Here we examine how atmospheric CO2 enrichment and N fertilization affects the uptake of silicon (Si) in the Duke Forest, North Carolina, a stand dominated by Pinus taeda (loblolly pine), and five hardwoodmore » species. Specifically, we measured foliar biogenic silica concentrations in five deciduous and one coniferous species across three treatments: CO2 enrichment, N enrichment, and N and CO2 enrichment. We found no consistent trends in foliar Si concentration under elevated CO2, N fertilization, or combined elevated CO2 and N fertilization. However, two-thirds of the tree species studied here have Si foliar concentrations greater than well-known Si accumulators, such as grasses. Based on net primary production values and aboveground Si concentrations in these trees, we calculated forest Si uptake rates under control and elevated CO2 concentrations. Due largely to increased primary production, elevated CO2 enhanced the magnitude of Si uptake between 20 and 26%, likely intensifying the terrestrial silica pump. This uptake of Si by forests has important implications for Si export from terrestrial systems, with the potential to impact C sequestration and higher trophic levels in downstream ecosystems.« less

  10. Supercritical CO2-Brayton Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercritical CO2-Brayton Cycle - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs

  11. DOE Research Projects to Examine Promising Geologic Formations for CO2 Storage

    Broader source: Energy.gov [DOE]

    The Department of Energy today announced 11 projects valued at $75.5 million aimed at increasing scientific understanding about the potential of promising geologic formations to safely and permanently store carbon dioxide (CO2).

  12. Department of Energy, Shell Canada to Collaborate on CO2 Storage Project

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) and Shell Canada announced today they intend to collaborate in field tests to validate advanced monitoring, verification, and accounting (MVA) technologies for underground storage of carbon dioxide (CO2).

  13. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  15. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  16. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  17. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  18. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  19. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  20. First U.S. Large-Scale CO2 Storage Project Advances

    Broader source: Energy.gov [DOE]

    Drilling nears completion for the first large-scale carbon dioxide injection well in the United States for CO2 sequestration. This project will be used to demonstrate that CO2 emitted from industrial sources - such as coal-fired power plants - can be stored in deep geologic formations to mitigate large quantities of greenhouse gas emissions.

  1. DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site

    Broader source: Energy.gov [DOE]

    A project that uses lasers to monitor carbon dioxide (CO2) is being analyzed as part of the U.S. Department of Energy’s (DOE) drive to improve greenhouse gas-monitoring abilities at CO2 storage sites. The project is managed by the DOE Office of Fossil Energy’s National Energy Technology Laboratory (NETL).

  2. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  3. FY 2014 Research Projects on CO2 Storage in Enhanced Oil Recovery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Research Projects on CO2 Storage in Enhanced Oil Recovery FY 2014 Research Projects on CO2 Storage in Enhanced Oil Recovery In FY 2014, the U.S. Department of Energy selected five projects focused on advancing the state of knowledge and developing and validating technologies that would allow for more effective storage of carbon dioxide (CO2) in enhanced oil recovery (EOR) operations while also promoting additional oil recovery. Valued at more than $14 million, these

  4. Secretary Chu Announces Six Projects to Convert Captured CO2 Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Sources into Useful Products | Department of Energy Six Projects to Convert Captured CO2 Emissions from Industrial Sources into Useful Products Secretary Chu Announces Six Projects to Convert Captured CO2 Emissions from Industrial Sources into Useful Products July 22, 2010 - 12:00am Addthis Washington, D.C. - U.S. Energy Secretary Steven Chu announced today the selections of six projects that aim to find ways of converting captured carbon dioxide (CO2) emissions from industrial

  5. In-Situ MVA of CO2 Sequestration Using Smart Field Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In-Situ MVA of CO 2 Sequestration Using Smart Field Technology Background Through its core research and development program administered by the National Energy Technology Laboratory (NETL), the U.S. Department of Energy (DOE) emphasizes monitoring, verification, and accounting (MVA), as well as computer simulation and risk assessment, of possible carbon dioxide (CO 2 ) leakage at CO 2 geologic storage sites. MVA efforts focus on the development and deployment of technologies that can provide an

  6. solvents-co2-capture-pitt | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvents for CO2 Capture Project No.: R&D 048 The most attractive physical solvents for carbon dioxide (CO2) capture are those having such properties as high thermal stability, extremely low vapor pressures, nonflammability, and nontoxicity. Such materials not only have the potential to capture CO2 with minimal solvent loss in the gas stream but are expected to be environmentally benign. NETL's Office of Research and Development is conducting a study involving one general type of

  7. DOE-Sponsored Drilling Projects Demonstrate Significant CO2 Storage at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Three Sites | Department of Energy Drilling Projects Demonstrate Significant CO2 Storage at Three Sites DOE-Sponsored Drilling Projects Demonstrate Significant CO2 Storage at Three Sites May 3, 2012 - 1:00pm Addthis Washington, DC - Evaluation-related test drilling at geologic sites in three states that could store a combined 64 million metric tons of carbon dioxide (CO2) emissions - an important component of carbon capture, utilization and storage (CCUS) technology development - has been

  8. Carbon Storage Partner Completes First Year of CO2 Injection Operations in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Illinois | Department of Energy Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois November 19, 2012 - 12:00pm Addthis Washington, DC - A project important to demonstrating the commercial viability of carbon capture, utilization and storage (CCUS) technology has completed the first year of injecting carbon dioxide (CO2) from an industrial plant at a large-scale test site in

  9. HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION

    SciTech Connect (OSTI)

    Stoots, C.M.

    2006-11-01

    Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. The syngas can then be used for synthetic fuel production. This program is a combination of experimental and computational activities. Since the solid oxide electrolyte material is a conductor of oxygen ions, CO can be produced by electrolyzing CO2 sequestered from some greenhouse gas-emitting process. Under certain conditions, however, CO can further electrolyze to produce carbon, which can then deposit on cell surfaces and reduce cell performance. The understanding of the co-electrolysis of steam and CO2 is also complicated by the competing water-gas shift reaction. Results of experiments and calculations to date of CO2 and CO2/H2O electrolysis will be presented and discussed. These will include

  10. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wan -Hui; Himeda, Yuichiro; Muckerman, James T.; Manbeck, Gerald F.; Fujita, Etsuko

    2015-09-03

    In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in severalmore » ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.« less

  11. On sorption and swelling of CO2 in clays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Busch, A.; Bertier, P.; Gensterblum, Y.; Rother, G.; Spiers, C. J.; Zhang, M.; Wentinck, H. M.

    2016-03-23

    One well-studied technology is the geological storage of carbon dioxide (CO2), and a number of demonstration projects around the world have proven its feasibility and challenges. Storage conformance and seal integrity are among the most important aspects, as they determine risk of leakage as well as limits for storage capacity and injectivity. By providing evidence for safe storage is critical for improving public acceptance. Most caprocks are composed of clays as dominant mineral type which can typically be illite, kaolinite, chlorite or smectite. A number of recent studies addressed the interaction between CO2 and these different clays and it wasmore » shown that clay minerals adsorb considerable quantities of CO2. For smectite this uptake can lead to volumetric expansion followed by the generation of swelling pressures. On the one hand CO2 adsorption traps CO2, on the other hand swelling pressures can potentially change local stress regimes and in unfavourable situations shear-type failure is assumed to occur. Moreover, for storage in a reservoir having high clay contents the CO2 uptake can add to storage capacity which is widely underestimated so far. Smectite-rich seals in direct contact with a dry CO2 plume at the interface to the reservoir might dehydrate leading to dehydration cracks. Such dehydration cracks can provide pathways for CO2 ingress and further accelerate dewatering and penetration of the seal by supercritical CO2. At the same time, swelling may also lead to the closure of fractures or the reduction of fracture apertures, thereby improving seal integrity. Finally, the goal of this communication is to theoretically evaluate and discuss these scenarios in greater detail in terms of phenomenological mechanisms, but also in terms of potential risks or benefits for carbon storage.« less

  12. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  13. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  14. Factor CO2 | Open Energy Information

    Open Energy Info (EERE)

    Factor CO2 Jump to: navigation, search Name: Factor CO2 Place: Bilbao, Spain Zip: 48008 Product: Spain-based consultancy specializing in climate change projects. References: Factor...

  15. Co2balance | Open Energy Information

    Open Energy Info (EERE)

    balance Jump to: navigation, search Name: Co2balance Place: United Kingdom Sector: Carbon Product: Carbon offset provider based in Somerset, UK. References: Co2balance1 This...

  16. co2-use-reuse | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Use and Reuse Carbon dioxide is thermodynamically stable, but it is still reactive under certain conditions that do not necessarily require intensive energy input. Using CO2 as a feedstock for a variety of products is a promising research area, particularly in conjunction with energy generated from renewable energy sources. The Carbon Use and Reuse Technology Area seeks to support the development of technologies identified as having the greatest potential to help boost the commodity

  17. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2

    Reports and Publications (EIA)

    2001-01-01

    This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

  18. DOE Regional Partner Initiates CO2 Injection Study in Virginia | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Partner Initiates CO2 Injection Study in Virginia DOE Regional Partner Initiates CO2 Injection Study in Virginia February 11, 2009 - 12:00pm Addthis Washington, D.C. -- A U.S. Department of Energy (DOE) team of regional partners has begun injecting carbon dioxide (CO2) into coal seams in the Central Appalachian Basin to determine the feasibility of CO2 storage in unmineable coal seams and the potential for enhanced coalbed methane recovery. The results of the study will be vital in

  19. Microsoft Word - Updated Air Dispersion Modeling Table _sulfur...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DIVINE STRAKE AIR DISPERSION MODELING RESULTS for SULFUR DIOXIDE The attached table is ... within the Nevada Ambient Air Quality Standards at the boundary of the Nevada Test Site. ...

  20. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  1. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  2. CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts

    SciTech Connect (OSTI)

    Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

    2005-09-01

    An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

  3. Surface Ocean CO2 Atlas (SOCAT) gridded data products

    SciTech Connect (OSTI)

    Sabine, Christopher; Hankin, S.; Koyuk, H; Bakker, D C E; Pfeil, B; Olsen, A; Metzl, N; Fassbender, A; Manke, A; Malczyk, J; Akl, J; Alin, S R; Bellerby, R G J; Borges, A; Boutin, J; Cai, W-J; Chavez, F P; Chen, A; Cosa, C; Feely, R A; Gonzalez-Davila, M; Goyet, C; Hardman-Mountford, N; Heinze, C; Hoppema, M; Hunt, C W; Hydes, D; Ishii, M; Johannessen, T; Key, R M; Kortzinger, A; Landschutzer, P; Lauvset, S K; Lefevre, N; Lourantou, A; Mintrop, L; Miyazaki, C; Murata, A; Nakadate, A; Nakano, Y; Nakaoka, S; Nojiri, Y; et al.

    2013-01-01

    A well documented, publicly available, global data set for surface ocean carbon dioxide (CO2) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC). SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968 2007). The SOCAT gridded data is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust regularly spaced fCO2 product with minimal spatial and temporal interpolation which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet, but also contains biases and limitations that the user needs to recognize and address.

  4. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  5. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Brayton Energy's supercritical carbon dioxide (s-CO 2 ) solar receiver has the potential to significantly improve reliability, increase efficiency, and reduce costs of CSP systems. ...

  6. A Field Study on Simulation of CO 2 Injection and ECBM Production and Prediction of CO 2 Storage Capacity in Unmineable Coal Seam

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Qin; Mohaghegh, Shahab D.; Gholami, Vida

    2013-01-01

    CO 2 sequestration into a coal seam project was studied and a numerical model was developed in this paper to simulate the primary and secondary coal bed methane production (CBM/ECBM) and carbon dioxide (CO 2 ) injection. The key geological and reservoir parameters, which are germane to driving enhanced coal bed methane (ECBM) and CO 2 sequestration processes, including cleat permeability, cleat porosity, CH 4 adsorption time, CO 2 adsorption time, CH 4 Langmuir isotherm, CO 2 Langmuir isotherm, and Palmer and Mansoori parameters, have been analyzed within a reasonable range. The model simulation results showed good matches formore » both CBM/ECBM production and CO 2 injection compared with the field data. The history-matched model was used to estimate the total CO 2 sequestration capacity in the field. The model forecast showed that the total CO 2 injection capacity in the coal seam could be 22,817 tons, which is in agreement with the initial estimations based on the Langmuir isotherm experiment. Total CO 2 injected in the first three years was 2,600 tons, which according to the model has increased methane recovery (due to ECBM) by 6,700 scf/d.« less

  7. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  8. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon dioxide instead of steam allows higher...

  9. 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the annual greenhouse gas emissions from 210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program and the

  10. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  11. Dry-deposition measurements of sulfur dioxide to a spruce-fir forest in the Black Forest: a data report. Technical memo

    SciTech Connect (OSTI)

    McMillen, R.T.; Matt, D.R.; Hicks, B.B.; Womack, J.D.

    1987-02-01

    Measurements of dry deposition of SO/sub 2/ are reported for a forested site in the Black Forest of West Germany. The measurements were made using the eddy-correlation method about 10 meters above the top of a spruce forest that was already affected by Waldsterben. These measurements were conducted as one component of TULLA, a large sulfur mass-balance experiment. The dry-deposition measurements were successful during times when SO/sub 2/ concentrations were greater than 5 micro grams/cu m.

  12. Is CO2 an Indoor Pollutant? Higher Levels of CO2 May Diminish...

    Office of Scientific and Technical Information (OSTI)

    Decision Making Performance Citation Details In-Document Search Title: Is CO2 an Indoor Pollutant? Higher Levels of CO2 May Diminish Decision Making Performance You are ...

  13. NETL Patented CO2-Removal Sorbents Promise Power and Cost Savings |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Patented CO2-Removal Sorbents Promise Power and Cost Savings NETL Patented CO2-Removal Sorbents Promise Power and Cost Savings May 30, 2012 - 1:00pm Addthis Washington, DC - Carbon dioxide removal sorbents developed by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) could result in power and cost savings for users of some heating, ventilation and air conditioning (HVAC) systems under a recently signed license agreement. NETL, the

  14. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M

    2009-07-21

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  15. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  16. Department of Energy Announces 15 Projects Aimed at Secure CO2 Underground

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage | Department of Energy 5 Projects Aimed at Secure CO2 Underground Storage Department of Energy Announces 15 Projects Aimed at Secure CO2 Underground Storage August 11, 2010 - 12:00am Addthis Washington, D.C. - U.S. Energy Secretary Steven Chu announced today the selection of 15 projects to develop technologies aimed at safely and economically storing carbon dioxide in geologic formations. Funded with $21.3 million over three years, today's selections will complement existing DOE

  17. Composition and Method for Rapid and Equimolar CO2 Capture - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Composition and Method for Rapid and Equimolar CO2 Capture Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication 11-G00233_ID2434.pdf (627 KB) Technology Marketing SummaryThe emission of carbon dioxide (CO2) from burning of fossil fuels has received worldwide attention because of its implication in

  18. Forest succession at elevated CO2

    SciTech Connect (OSTI)

    Clark, James S.; Schlesinger, William H.

    2002-02-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response.

  19. International Energy Outlook 2016-Energy-related CO2 emissions - Energy

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration 9. Energy-related CO2 emissions print version Overview Because anthropogenic emissions of carbon dioxide (CO2) result primarily from the combustion of fossil fuels, energy consumption is at the center of the climate change debate. In the International Energy Outlook 2016 (IEO2016) Reference case, world energy-related CO2 emissions [331] increase from 32.3 billion metric tons in 2012 to 35.6 billion metric tons in 2020 and to 43.2 billion metric tons in 2040. The

  20. DOE Selects Projects to Monitor and Evaluate Geologic CO2 Storage |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Selects Projects to Monitor and Evaluate Geologic CO2 Storage DOE Selects Projects to Monitor and Evaluate Geologic CO2 Storage August 24, 2009 - 1:00pm Addthis Washington, D.C. -- The U.S. Department of Energy (DOE) today announced the selection of 19 projects to enhance the capability to simulate, track, and evaluate the potential risks of carbon dioxide (CO2) storage in geologic formations. The projects' total value is approximately $35.8 million over four years, with

  1. Project Profile: High-Temperature Particle Heat Exchanger for sCO2 Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cycles (SuNLaMP) | Department of Energy High-Temperature Particle Heat Exchanger for sCO2 Power Cycles (SuNLaMP) Project Profile: High-Temperature Particle Heat Exchanger for sCO2 Power Cycles (SuNLaMP) Funding Program: SuNLaMP SunShot Subprogram: CSP Location: Sandia National Laboratory, Albuquerque, NM SunShot Award Amount: $4,586,967 This project is designing, developing, and testing a supercritical carbon dioxide (sCO2) heat exchanger that operates at temperatures higher than 720°C and

  2. DOE Establishes National Carbon Capture Center to Speed Deployment of CO2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capture Processes | Department of Energy DOE Establishes National Carbon Capture Center to Speed Deployment of CO2 Capture Processes DOE Establishes National Carbon Capture Center to Speed Deployment of CO2 Capture Processes May 27, 2009 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy has announced the creation of a new National Carbon Capture Center (NCCC) to develop and test technologies to capture carbon dioxide (CO2) from coal-based power plants. Managed and operated by

  3. DOE Best Practices Manual Focuses on Site Selection for CO2 Storage |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Best Practices Manual Focuses on Site Selection for CO2 Storage DOE Best Practices Manual Focuses on Site Selection for CO2 Storage January 5, 2011 - 12:00pm Addthis Washington, DC - The most promising methods for assessing potential carbon dioxide (CO2) geologic storage sites - a crucial component of Carbon Capture and Storage (CCS) technology - is the focus of the latest in a series of U.S. Department of Energy (DOE) CCS "best practices" manuals. Developed by

  4. DOE Selects Eight Projects to Receive Funding for Reducing the Cost of CO2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capture and Compression | Department of Energy Eight Projects to Receive Funding for Reducing the Cost of CO2 Capture and Compression DOE Selects Eight Projects to Receive Funding for Reducing the Cost of CO2 Capture and Compression September 1, 2015 - 10:03am Addthis The U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) has selected eight projects to receive funding to construct small- and large-scale pilots for reducing the cost of carbon dioxide (CO2) capture

  5. H. R. 4177: A Bill to amend the Internal Revenue Code of 1986 to impose an excise tax on sulfur dioxide and nitrogen oxide emissions from utility plants. Introduced in the House of Representatives, One Hundredth First Congress, Second Session, March 5, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The tax imposed would begin in 1991 in the amount of 15 cents per pound of sulfur dioxide released and 10 cents per pound nitrogen oxide, and would increase so that the tax in 1997 and thereafter would be 45 cents per pound of sulfur dioxide and 30 cents per pound of nitrogen oxide released. An inflation adjustment is provided for years after 1997. The tax is imposed on emissions which exceed the exemption level for each pollutant, and these levels are specified herein as pounds exempted per million Btu's of fuel burned. No tax is imposed on units less than 75 megawatts, or units providing less than one-third of the electricity produced to a utility power distribution system for sale.

  6. Biofuels from Bacteria, Electricity, and CO2: Biofuels from CO2 Using Ammonia or Iron-Oxidizing Bacteria in Reverse Microbial Fuel Cells

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: Electrofuels Project: Columbia University is using carbon dioxide (CO2) from ambient air, ammoniaan abundant and affordable chemical, and a bacteria called N. europaea to produce liquid fuel. The Columbia University team is feeding the ammonia and CO2 into an engineered tank where the bacteria live. The bacteria capture the energy from ammonia and then use that energy to convert CO2 into a liquid fuel. When the bacteria use up all the ammonia, renewable electricity can regenerate it and pump it back into the systemcreating a continuous fuel-creation cycle. In addition, Columbia University is also working with the bacteria A. ferrooxidans to capture and use energy from ferrous iron to produce liquid fuels from CO2.

  7. CO2-driven Enhanced Oil Recovery as a Stepping Stone to What?

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2010-07-14

    This paper draws heavily on the authors’ previously published research to explore the extent to which near term carbon dioxide-driven enhanced oil recovery (CO2-EOR) can be “a stepping stone to a long term sequestration program of a scale to be material in climate change risk mitigation.” The paper examines the historical evolution of CO2-EOR in the United States and concludes that estimates of the cost of CO2-EOR production or the extent of CO2 pipeline networks based upon this energy security-driven promotion of CO2-EOR do not provide a robust platform for spurring the commercial deployment of carbon dioxide capture and storage technologies (CCS) as a means of reducing greenhouse gas emissions. The paper notes that the evolving regulatory framework for CCS makes a clear distinction between CO2-EOR and CCS and the authors examine arguments in the technical literature about the ability for CO2-EOR to generate offsetting revenue to accelerate the commercial deployment of CCS systems in the electric power and industrial sectors of the economy. The authors conclude that the past 35 years of CO2-EOR in the U.S. have been important for boosting domestic oil production and delivering proven system components for future CCS systems. However, though there is no reason to suggest that CO2-EOR will cease to deliver these benefits, there is also little to suggest that CO2-EOR is a necessary or significantly beneficial step towards the commercial deployment of CCS as a means of addressing climate change.

  8. TIME-LAPSE SEISMIC MODELING & INVERSION OF CO2 SATURATION FOR SEQUESTRATION AND ENHANCED OIL RECOVERY

    SciTech Connect (OSTI)

    Mark A. Meadows

    2006-03-31

    Injection of carbon dioxide (CO2) into subsurface aquifers for geologic storage/sequestration, and into subsurface hydrocarbon reservoirs for enhanced oil recovery, has become an important topic to the nation because of growing concerns related to global warming and energy security. In this project we developed new ways to predict and quantify the effects of CO2 on seismic data recorded over porous reservoir/aquifer rock systems. This effort involved the research and development of new technology to: (1) Quantitatively model the rock physics effects of CO2 injection in porous saline and oil/brine reservoirs (both miscible and immiscible). (2) Quantitatively model the seismic response to CO2 injection (both miscible and immiscible) from well logs (1D). (3) Perform quantitative inversions of time-lapse 4D seismic data to estimate injected CO2 distributions within subsurface reservoirs and aquifers. This work has resulted in an improved ability to remotely monitor the injected CO2 for safe storage and enhanced hydrocarbon recovery, predict the effects of CO2 on time-lapse seismic data, and estimate injected CO2 saturation distributions in subsurface aquifers/reservoirs. We applied our inversion methodology to a 3D time-lapse seismic dataset from the Sleipner CO2 sequestration project, Norwegian North Sea. We measured changes in the seismic amplitude and traveltime at the top of the Sleipner sandstone reservoir and used these time-lapse seismic attributes in the inversion. Maps of CO2 thickness and its standard deviation were generated for the topmost layer. From this information, we estimated that 7.4% of the total CO2 injected over a five-year period had reached the top of the reservoir. This inversion approach could also be applied to the remaining levels within the anomalous zone to obtain an estimate of the total CO2 injected.

  9. A Review of the CO2 Pipeline Infrastructure in the U.S.

    Broader source: Energy.gov [DOE]

    This paper provides summary descriptions of the U.S. carbon dioxide (CO2) pipeline system and future scenarios for expansion. Spanning across more than a dozen U.S. states and into Canada, a safe and regionally extensive network of pipelines has been constructed over the past four decades. These pipelines represent an essential building block for linking the capture of CO2 from electric power plants and other industrial sources with its productive use in oilfields and its safe storage in saline formations. The vast majority of the CO2 pipeline system is dedicated to CO2- Enhanced Oil Recovery (EOR), connecting natural and industrial sources of CO2 with EOR projects in oil fields. Roughly 80 percent of CO2 traveling through U.S. pipelines is from natural (geologic) sources; however, if currently planned industrial CO2 capture facilities and new pipelines are built, by 2020 the portion of CO2 from industrial sources could nearly match the portion from natural sources. A national carbon policy could significantly increase the scale of CO2 infrastructure by creating incentives for electric power plants and other industrial facilities to reduce CO2 emissions through carbon capture technologies and improving the economics for oil production through EOR. Low-carbon cases modeled for this report project that construction through 2030 could more than triple the size of current U.S. CO2 pipeline infrastructure. The development of an expanded national CO2 pipeline network capable of meeting U.S. GHG emission goals may require regulatory changes, incentives and a more concerted federal policy, involving closer cooperation among federal, state, and local governments.

  10. CO2 Europipe | Open Energy Information

    Open Energy Info (EERE)

    www.co2europipe.eu Equivalent URI: cleanenergysolutions.orgcontentco2-europipe Language: English Policies: "Deployment Programs,Regulations,Financial Incentives" is not in...

  11. CO2 Tech | Open Energy Information

    Open Energy Info (EERE)

    produces and installs equipment for controlling and measuring atmospheric emissions and greenhouse gases for a wide variety of industries. References: CO2 Tech1 This article is...

  12. R&D100: CO2 Memzyme

    SciTech Connect (OSTI)

    Rempe, Susan; Brinker, Jeff; Jiang, Ying-Bing; Vanegas, Juan

    2015-11-19

    By combining a water droplet loaded with CO2 enzymes in an ultrathin nanopore on a flexible substrate, researchers at Sandia National Laboratories realized the first technology that meets and exceeds DOE targets for cost-effective CO2 capture. When compared with the nearest membrane competitor, this technology delivers a three times permeation rate, twenty times higher selectivity, and ten time lower fabrication cost. The CO2 Memzyme has the potential to remove 90% of CO2 emissions and is forecasted to save the U.S. coal industry $90 billion a year compared to conventional technology.

  13. CO2 Heat Pump Water Heater

    Broader source: Energy.gov (indexed) [DOE]

    CO 2 Heat Pump Water Heater 2014 Building Technologies Office Peer Review Evaporator Kyle ... MarketAudience: Residential electric water heating Key Partners: GE Appliances CRADA ...

  14. CO2 Conference Presentation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Conference Presentation More Documents & Publications POWER-GEN Conference Presentation U.S. Energy Association Presentation EEI Environment Meetings Presentation...

  15. Recycling Carbon Dioxide to Make Plastics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recycling Carbon Dioxide to Make Plastics Recycling Carbon Dioxide to Make Plastics May 20, 2013 - 1:31pm Addthis Novomer’s thermoplastic pellets incorporate waste CO2 into a variety of consumer products. Novomer's thermoplastic pellets incorporate waste CO2 into a variety of consumer products. Why is this important? By using CO2 that would otherwise be emitted to the atmosphere, the process has the potential to cut greenhouse gas emissions while simultaneously reducing petroleum

  16. DOE Targets Rural Indiana Geologic Formation for CO2 Storage Field Test

    Broader source: Energy.gov [DOE]

    A U.S. Department of Energy team of regional partners has begun injecting 8,000 tons of carbon dioxide (CO2) to evaluate the carbon storage potential and test the enhanced oil recovery (EOR) potential of the Mississippian-aged Clore Formation in Posey County, Ind.

  17. DOE Partnership Completes Successful CO2 Injection Test in the Mount Simon Sandstone

    Broader source: Energy.gov [DOE]

    The Midwest Regional Carbon Sequestration Partnership, one of seven partnerships in the U.S. Department of Energy's Regional Carbon Sequestration Partnerships program, has successfully injected 1,000 metric tons of carbon dioxide (CO2) into the Mount Simon Sandstone, a deep saline formation that is widespread across much of the Midwest.

  18. Energy Department Selects Projects to Demonstrate Feasibility of Producing Usable Water from CO2 Storage Sites

    Broader source: Energy.gov [DOE]

    Today, the Department of Energy (DOE) announced the selection of two projects that will test emerging enhanced water recovery (EWR) technologies for their potential to produce useable water from carbon dioxide (CO2) storage sites. The two projects were competitively selected from the five Brine Extraction Storage Test (BEST) projects awarded in September 2015.

  19. Researchers Uncover Copper’s Potential for Reducing CO2 Emissions in Chemical Looping

    Broader source: Energy.gov [DOE]

    Researchers at the Department of Energy’s National Energy Technology Laboratory (NETL) believe copper may play an important role in combatting climate change. When used as a part of a promising coal combustion technology known as chemical looping, copper can help economically remove carbon dioxide (CO2) from fossil fuel emissions.

  20. DOE Partner Begins Injecting 50,000 Tons of CO2 in Michigan Basin

    Broader source: Energy.gov [DOE]

    Building on an initial injection project of 10,000 metric tons of carbon dioxide into a Michigan geologic formation, a U.S. Department of Energy team of regional partners has begun injecting 50,000 additional tons into the formation, which is believed capable of storing hundreds of years worth of CO2, a greenhouse gas that contributes to climate change.

  1. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  2. Particle-scale CO2 adsorption kinetics modeling considering three reaction mechanisms

    SciTech Connect (OSTI)

    Suh, Dong-Myung; Sun, Xin

    2013-09-01

    In the presence of water (H2O), dry and wet adsorptions of carbon dioxide (CO2) and physical adsorption of H2O happen concurrently in a sorbent particle. The three reactions depend on each other and have a complicated, but important, effect on CO2 capturing via a solid sorbent. In this study, transport phenomena in the sorbent were modeled, including the tree reactions, and a numerical solving procedure for the model also was explained. The reaction variable distribution in the sorbent and their average values were calculated, and simulation results were compared with experimental data to validate the proposed model. Some differences, caused by thermodynamic parameters, were observed between them. However, the developed model reasonably simulated the adsorption behaviors of a sorbent. The weight gained by each adsorbed species, CO2 and H2O, is difficult to determine experimentally. It is known that more CO2 can be captured in the presence of water. Still, it is not yet known quantitatively how much more CO2 the sorbent can capture, nor is it known how much dry and wet adsorptions separately account for CO2 capture. This study addresses those questions by modeling CO2 adsorption in a particle and simulating the adsorption process using the model. As adsorption temperature changed into several values, the adsorbed amount of each species was calculated. The captured CO2 in the sorbent particle was compared quantitatively between dry and wet conditions. As the adsorption temperature decreased, wet adsorption increased. However, dry adsorption was reduced.

  3. Final Progress Report: Direct Experiments on the Ocean Disposal of Fossil Fuel CO2.

    SciTech Connect (OSTI)

    James P. Barry; Peter G. Brewer

    2004-05-25

    OAK-B135 This report summarizes activities and results of investigations of the potential environmental consequences of direct injection of carbon dioxide into the deep-sea as a carbon sequestration method. Results of field experiments using small scale in situ releases of liquid CO2 are described in detail. The major conclusions of these experiments are that mortality rates of deep sea biota will vary depending on the concentrations of CO2 in deep ocean waters that result from a carbon sequestration project. Large changes in seawater acidity and carbon dioxide content near CO2 release sites will likely cause significant harm to deep-sea marine life. Smaller changes in seawater chemistry at greater distances from release sites will be less harmful, but may result in significant ecosystem changes.

  4. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock

  5. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one year of operating experience with a transcritical carbon dioxide (TC CO2) booster refrigeration system at Delhaize America's Hannaford supermarket location in Turner, Maine. This supermarket, which began operation in June 2013, is the first supermarket installation in the U.S. of a TC CO2 booster

  6. Residential CO2 Heat Pump Water Heater | Department of Energy

    Energy Savers [EERE]

    Residential CO2 Heat Pump Water Heater Residential CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater Prototype
    Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater ...

  7. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    SciTech Connect (OSTI)

    Malhotra, Vivak

    2014-06-30

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (≤ 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale

  8. Ancient Lava Flows Trap CO2 for Long-Term Storage in Big Sky Injection

    Broader source: Energy.gov [DOE]

    How can a prehistoric volcanic eruption help us reduce the amount of CO2 released into the atmosphere today? The answer is found in the basalt formations created by the lava – formations that can be used as sites for injecting carbon dioxide (CO2) captured from industrial sources in a process called carbon capture and storage. The Big Sky Carbon Sequestration Partnership recently injected 1,000 metric tons of CO2 into the Grande Ronde Basalt Formation in eastern Washington. This first-of-its kind injection is part of research meant to determine if basalt formations could provide a long-term solution for storing CO2, a potent greenhouse gas.

  9. CENIT CO2 | Open Energy Information

    Open Energy Info (EERE)

    and develop new solutions to reducing CO2 emissions from fossil fuel combustion during electricity generation. References: CENIT-CO21 This article is a stub. You can help...

  10. CO2 | OpenEI Community

    Open Energy Info (EERE)

    cities CO2 emissions OpenEI suburbs US New research from the University of California-Berkeley shows that those who live in cities in the United States have significantly smaller...

  11. Using hyperspectral plant signatures for CO2 leak detection during the 2008 ZERT CO2 sequestration field experiment in Bozeman, Montana

    SciTech Connect (OSTI)

    Male, E.J.; Pickles, W.L.; Silver, E.A.; Hoffmann, G.D.; Lewicki, J.; Apple, M.; Repasky, K.; Burton, E.A.

    2009-11-01

    Hyperspectral plant signatures can be used as a short-term, as well as long-term (100-yr timescale) monitoring technique to verify that CO2 sequestration fields have not been compromised. An influx of CO2 gas into the soil can stress vegetation, which causes changes in the visible to nearinfrared reflectance spectral signature of the vegetation. For 29 days, beginning on July 9th, 2008, pure carbon dioxide gas was released through a 100-meter long horizontal injection well, at a flow rate of 300 kg/day. Spectral signatures were recorded almost daily from an unmown patch of plants over the injection with a ''FieldSpec Pro'' spectrometer by Analytical Spectral Devices, Inc. Measurements were taken both inside and outside of the CO2 leak zone to normalize observations for other environmental factors affecting the plants.

  12. CO2-Based Glue - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search CO2-Based Glue An environmentally friendly epoxy that utilizes CO2 as a starting material National Energy Technology Laboratory Contact NETL About This Technology Weights suspended by plates that are held together with the adhesive Weights suspended by plates that are held together with the adhesive Plates held together by adhesive. Weights were suspended from the

  13. Insights into the structure of mixed CO2/CH4 in gas hydrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Everett, S. Michelle; Rawn, Claudia J.; Chakoumakos, Bryan C.; Keffer, David J.; Huq, Ashfia; Phelps, Tommy J.

    2015-05-12

    The exchange of carbon dioxide for methane in natural gas hydrates is an attractive approach to harvesting CH4 for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x·5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. In this paper, high-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules thatmore » form the surrounding cages, and resulted in a reduction in the unit-cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. Finally, these results provide important insights on the impact and mechanisms for the structure of mixed CH4/CO2 gas hydrate.« less

  14. A Review of Hazardous Chemical Species Associated with CO2 Capturefrom Coal-Fired Power Plants and Their Potential Fate in CO2 GeologicStorage

    SciTech Connect (OSTI)

    Apps, J.A.

    2006-02-23

    Conventional coal-burning power plants are major contributors of excess CO2 to the atmospheric inventory. Because such plants are stationary, they are particularly amenable to CO2 capture and disposal by deep injection into confined geologic formations. However, the energy penalty for CO2 separation and compression is steep, and could lead to a 30-40 percent reduction in useable power output. Integrated gas combined cycle (IGCC) plants are thermodynamically more efficient, i.e.,produce less CO2 for a given power output, and are more suitable for CO2 capture. Therefore, if CO2 capture and deep subsurface disposal were to be considered seriously, the preferred approach would be to build replacement IGCC plants with integrated CO2 capture, rather than retrofit existing conventional plants. Coal contains minor quantities of sulfur and nitrogen compounds, which are of concern, as their release into the atmosphere leads to the formation of urban ozone and acid rain, the destruction of stratospheric ozone, and global warming. Coal also contains many trace elements that are potentially hazardous to human health and the environment. During CO2 separation and capture, these constituents could inadvertently contaminate the separated CO2 and be co-injected. The concentrations and speciation of the co-injected contaminants would differ markedly, depending on whether CO2 is captured during the operation of a conventional or an IGCC plant, and the specific nature of the plant design and CO2 separation technology. However, regardless of plant design or separation procedures, most of the hazardous constituents effectively partition into the solid waste residue. This would lead to an approximately two order of magnitude reduction in contaminant concentration compared with that present in the coal. Potential exceptions are Hg in conventional plants, and Hg and possibly Cd, Mo and Pb in IGCC plants. CO2 capture and injection disposal could afford an opportunity to deliberately capture

  15. Synthesis of Scrub-Oak Ecosystem Responses to Elevated CO2

    SciTech Connect (OSTI)

    Hungate, Bruce

    2014-11-07

    This report summarizes a synthesis project of a long-term global change experiment conducted at the Kennedy Space Center, Florida, investigating how increasing concentrations of atmospheric carbon dioxide (CO2) influences the functioning of a fire-dominated scrub-oak ecosystem. The experiment began in 1996 and ended in 2007. Results presented here summarize the effects of elevated CO2 on plant growth, soil processes, carbon and nutrient cycling, and other responses. Products include archived data from the experiment, as well as six publications in the peer-reviewed literature.

  16. Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II

    SciTech Connect (OSTI)

    Czirr, K.L.; Gaddis, M.P.; Moshell, M.K.

    2002-02-21

    The principle objective of this project is to demonstrate the economic viability and widespread applicability of an innovative reservoir management and carbon dioxide (CO2) flood project development approach for improving CO2 flood project economics in shallow shelf carbonate (SSC) reservoirs.

  17. Surface CO2 leakage during the first shallow subsurface CO2release experiment

    SciTech Connect (OSTI)

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2007-09-15

    A new field facility was used to study CO2 migrationprocesses and test techniques to detect and quantify potential CO2leakage from geologic storage sites. For 10 days starting 9 July 2007,and for seven days starting 5 August 2007, 0.1 and 0.3 t CO2 d-1,respectively, were released from a ~;100-m long, sub-water table (~;2.5-mdepth) horizontal well. The spatio-temporal evolution of leakage wasmapped through repeated grid measurements of soil CO2 flux (FCO2). Thesurface leakage onset, approach to steady state, and post-release declinematched model predictions closely. Modeling suggested that minimal CO2was taken up by groundwater through dissolution, and CO2 spread out ontop of the water table. FCO2 spatial patterns were related to well designand soil physical properties. Estimates of total CO2 discharge along withsoil respiration and leakage discharge highlight the influence ofbackground CO2 flux variations on detection of CO2 leakagesignals.

  18. Early opportunities of CO2 geological storage deployment in coal chemical industry in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, Robert T.; Davidson, Casie L.

    2014-11-12

    Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sources together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  19. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect (OSTI)

    K. K. Bloomfield; J. N. Moore

    1999-10-01

    Emission of �greenhouse gases� into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize �green power.� Geothermal power is classed as �green power� and has lower emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  20. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect (OSTI)

    Bloomfield, Kevin Kit; Moore, J. N.

    1999-10-01

    Emission of “greenhouse gases” into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize “green power.” Geothermal power is classed as “green power” and has power emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  1. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  2. Thermo Scientific Sulfur Dioxide Analyzer Instrument Handbook...

    Office of Scientific and Technical Information (OSTI)

    in National Instruments LabView that both controls the Model 43i-TLE Analyzer AND queries the unit for all measurement and housekeeping data. The LabView vi (the software program ...

  3. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  4. Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach

    SciTech Connect (OSTI)

    Schoonen, Martin A.

    2014-12-22

    The reactivity of sandstones was studied under conditions relevant to the injection of supercritical carbon dioxide in the context of carbon geosequestration. The emphasis of the study was on the reactivity of iron-bearing minerals when exposed to supercritical CO2 (scCO2) and scCO2 with commingled aqueous solutions containing H2S and/or SO2. Flow through and batch experiments were conducted. Results indicate that sandstones, irrespective of their mineralogy, are not reactive when exposed to pure scCO2 or scCO2 with commingled aqueous solutions containing H2S and/or SO2 under conditions simulating the environment near the injection point (flow through experiments). However, sandstones are reactive under conditions simulating the edge of the injected CO2 plume or ahead of the plume (batch experiments). Sandstones containing hematite (red sandstone) are particularly reactive. The composition of the reaction products is strongly dependent on the composition of the aqueous phase. The presence of dissolved sulfide leads to the conversion of hematite into pyrite and siderite. The relative amount of the pyrite and siderite is influenced by the ionic strength of the solution. Little reactivity is observed when sulfite is present in the aqueous phase. Sandstones without hematite (grey sandstones) show little reactivity regardless of the solution composition.

  5. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  6. Scientists Can Recycle CO2 Using Gold | Department of Energy

    Office of Environmental Management (EM)

    Can Recycle CO2 Using Gold Scientists Can Recycle CO2 Using Gold May 27, 2016 - 9:57am Addthis A new chemical process has the potential to reduce atmospheric CO2 emissions by ...

  7. Uncertainty analyses of CO2 plume expansion subsequent to wellbore...

    Office of Scientific and Technical Information (OSTI)

    in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. ... The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the ...

  8. Feasibility of CO2 Capture from Mobile Sources | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Capture from Mobile Sources Feasibility of CO2 Capture from Mobile Sources Presents integrated system for post-combustion CO2 capture from mobile sources PDF icon ...

  9. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR Sites Citation Details In-Document Search Title: An Integrated Framework for CO2 Accounting and Risk ...

  10. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2008-02-29

    There is growing interest regarding the potential size of a future U.S. dedicated CO2 pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale. In trying to understand the potential scale of a future national CO2 pipeline network, comparisons are often made to the existing pipeline networks used to deliver natural gas and liquid hydrocarbons to markets within the U.S. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The data presented here suggest that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a significant obstacle for the commercial deployment of CCS technologies.

  11. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energys National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  12. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  13. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  14. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the ...

  15. Ganglion dynamics of Supercritical CO2 in heterogeneous media...

    Office of Scientific and Technical Information (OSTI)

    Ganglion dynamics of Supercritical CO2 in heterogeneous media. Citation Details In-Document Search Title: Ganglion dynamics of Supercritical CO2 in heterogeneous media. Abstract ...

  16. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow ... Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated ...

  17. Grangemouth Advanced CO2 Capture Project GRACE | Open Energy...

    Open Energy Info (EERE)

    Grangemouth Advanced CO2 Capture Project GRACE Jump to: navigation, search Name: Grangemouth Advanced CO2 Capture Project (GRACE) Place: United Kingdom Sector: Carbon Product:...

  18. CO2 Global Solutions International | Open Energy Information

    Open Energy Info (EERE)

    Global Solutions International Jump to: navigation, search Name: CO2 Global Solutions International Place: Madrid, Spain Zip: 28001 Sector: Carbon Product: CO2 Global Solutions is...

  19. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  20. Texas CO2 Capture Demonstration Project Hits Three Million Metric...

    Office of Environmental Management (EM)

    Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone June 30, 2016 - ...

  1. Meeting the CO2 Challenge DEER 2002 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the CO2 Challenge DEER 2002 Meeting the CO2 Challenge DEER 2002 2002 DEER Conference Presentation: Ricardo PDF icon 2002deergraham.pdf More Documents & Publications Application ...

  2. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    CO2 Capture by Absorption with Potassium Carbonate Citation Details In-Document Search Title: CO2 Capture by Absorption with Potassium Carbonate You are accessing a document ...

  3. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: CO2 Capture by Absorption with Potassium Carbonate Citation Details In-Document Search Title: CO2 Capture by Absorption with Potassium Carbonate You are ...

  4. Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone

    Broader source: Energy.gov [DOE]

    On June 30, Allentown, PA-based Air Products and Chemicals, Inc. successfully captured and transported, via pipeline, its 3 millionth metric ton of carbon dioxide (CO2) to be used for enhanced oil recovery. This achievement highlights the ongoing success of a carbon capture and storage (CCS) project sponsored by the U.S. Department of Energy (DOE) and managed by the National Energy Technology Laboratory (NETL).

  5. Fuel from Bacteria, CO2, Water, and Solar Energy: Engineering a Bacterial Reverse Fuel Cell

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: Harvard is engineering a self-contained, scalable Electrofuels production system that can directly generate liquid fuels from bacteria, carbon dioxide (CO2), water, and sunlight. Harvard is genetically engineering bacteria called Shewanella, so the bacteria can sit directly on electrical conductors and absorb electrical current. This current, which is powered by solar panels, gives the bacteria the energy they need to process CO2 into liquid fuels. The Harvard team pumps this CO2 into the system, in addition to water and other nutrients needed to grow the bacteria. Harvard is also engineering the bacteria to produce fuel molecules that have properties similar to gasoline or diesel fuelmaking them easier to incorporate into the existing fuel infrastructure. These molecules are designed to spontaneously separate from the water-based culture that the bacteria live in and to be used directly as fuel without further chemical processing once theyre pumped out of the tank.

  6. A Comparative Study on the Environmental Impact of CO2 Supermarket Refrigeration Systems

    SciTech Connect (OSTI)

    Beshr, Mohamed; Aute, Vikrant; Sharma, Vishaldeep; Abdelaziz, Omar; Fricke, Brian A; Radermacher, Reinhard

    2014-01-01

    Supermarket refrigeration systems have high environmental impact due to their large refrigerant charge and high leak rates. Accordingly, the interest in using natural refrigerants, such as carbon dioxide (CO2), and new refrigerant blends with low GWP in such systems is increasing. In this paper, an open-source Life Cycle Climate Performance (LCCP) framework is presented and used to compare the environmental impact of three supermarket refrigeration systems. These systems include a transcritical CO2 booster system, a cascade CO2/N-40 system, and a baseline R-404A multiplex direct expansion system. The study is performed for cities representing different climates within the USA using EnergyPlus to simulate the systems' hourly performance. Finally, a parametric analysis is performed to study the impact of annual leak rate on the systems' LCCP.

  7. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  8. Impacts of Elevated Atmospheric CO2and O3on Paper Birch (Betula papyrifera): Reproductive Fitness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Darbah, Joseph N. T.; Kubiske, Mark E.; Nelson, Neil; Oksanen, Elina; Vaapavuori, Elina; Karnosky, David F.

    2007-01-01

    Atmospheric CO2and tropospheric O3are rising in many regions of the world. Little is known about how these two commonly co-occurring gases will affect reproductive fitness of important forest tree species. Here, we report on the long-term effects of CO3and O3for paper birch seedlings exposed for nearly their entire life history at the Aspen FACE (Free Air Carbon Dioxide Enrichment) site in Rhinelander, WI. Elevated CO2increased both male and female flower production, while elevated O3increased female flower production compared to trees in control rings. Interestingly, very little flowering has yet occurred in combined treatment. Elevated CO2had significant positive effect on birchmorecatkin size, weight, and germination success rate (elevated CO2increased germination rate of birch by 110% compared to ambient CO2concentrations, decreased seedling mortality by 73%, increased seed weight by 17%, increased root length by 59%, and root-to-shoot ratio was significantly decreased, all at 3 weeks after germination), while the opposite was true of elevated O3(elevated O3decreased the germination rate of birch by 62%, decreased seed weight by 25%, and increased root length by 15%). Under elevated CO2, plant dry mass increased by 9 and 78% at the end of 3 and 14 weeks, respectively. Also, the root and shoot lengths, as well as the biomass of the seedlings, were increased for seeds produced under elevated CO2, while the reverse was true for seedlings from seeds produced under the elevated O3. Similar trends in treatment differences were observed in seed characteristics, germination, and seedling development for seeds collected in both 2004 and 2005. Our results suggest that elevated CO2and O3can dramatically affect flowering, seed production, and seed quality of paper birch, affecting reproductive fitness of this species.less

  9. Impacts of Elevated Atmospheric CO 2 and O 3 on Paper Birch ( Betula papyrifera ): Reproductive Fitness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Darbah, Joseph N. T.; Kubiske, Mark E.; Nelson, Neil; Oksanen, Elina; Vaapavuori, Elina; Karnosky, David F.

    2007-01-01

    Atmospheric CO 2 and tropospheric O 3 are rising in many regions of the world. Little is known about how these two commonly co-occurring gases will affect reproductive fitness of important forest tree species. Here, we report on the long-term effects of CO 3 and O 3 for paper birch seedlings exposed for nearly their entire life history at the Aspen FACE (Free Air Carbon Dioxide Enrichment) site in Rhinelander, WI. Elevated CO 2 increased both male and female flower production, while elevated O 3 increased female flower production compared to trees in control rings. Interestingly, very little floweringmore » has yet occurred in combined treatment. Elevated CO 2 had significant positive effect on birch catkin size, weight, and germination success rate (elevated CO 2 increased germination rate of birch by 110% compared to ambient CO 2 concentrations, decreased seedling mortality by 73%, increased seed weight by 17%, increased root length by 59%, and root-to-shoot ratio was significantly decreased, all at 3 weeks after germination), while the opposite was true of elevated O 3 (elevated O 3 decreased the germination rate of birch by 62%, decreased seed weight by 25%, and increased root length by 15%). Under elevated CO 2 , plant dry mass increased by 9 and 78% at the end of 3 and 14 weeks, respectively. Also, the root and shoot lengths, as well as the biomass of the seedlings, were increased for seeds produced under elevated CO 2 , while the reverse was true for seedlings from seeds produced under the elevated O 3 . Similar trends in treatment differences were observed in seed characteristics, germination, and seedling development for seeds collected in both 2004 and 2005. Our results suggest that elevated CO 2 and O 3 can dramatically affect flowering, seed production, and seed quality of paper birch, affecting reproductive fitness of this species.« less

  10. Recent advances in carbon dioxide capture with metal-organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recent advances in carbon dioxide capture with metal-organic frameworks Previous Next List ... Great progress in MOF materials for CO2 capture has been made in the past and reviewed ...

  11. DOE to Provide $36 Million to Advance Carbon Dioxide Capture...

    Broader source: Energy.gov (indexed) [DOE]

    of carbon dioxide (CO2) from the existing fleet of coal-fired power plants. "Currently, the ... and laboratory methods to identify and ... an additive for reducing the stripping ...

  12. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, K.G.

    1990-02-20

    A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  13. Bisphosphine dioxides

    DOE Patents [OSTI]

    Moloy, Kenneth G.

    1990-01-01

    A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  14. Visualizing the Surface Infrastructure Used to Move 2 MtCO2/year from the Dakota Gasification Company to the Weyburn CO2 Enhanced Oil Recovery Project: Version of July 1, 2009

    SciTech Connect (OSTI)

    Dooley, James J.

    2009-07-09

    Google Earth Pro has been employed to create an interactive flyover of the world’s largest operational carbon dioxide capture and storage project. The visualization focuses on the transport and storage of 2 MtCO2/year which is captured from the Dakota Gasification Facility (Beula, North Dakota) and transported 205 miles and injected into the Weyburn oil field in Southeastern Saskatchewan.

  15. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print Friday, 19 February 2016 13:11 The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric

  16. NETL CO2 Storage Frequently Asked Questions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Storage Frequently Asked Questions faq-header-big.jpg A combined portfolio of carbon management options for fossil fuel use can be implemented to manage current emission levels of greenhouse gases (GHGs) while enhancing energy security and building the technologies and knowledge base for export to other countries faced with reducing emissions. The U.S. portfolio includes Use of fuels with reduced carbon intensity: renewables, nuclear, and natural gas. Adoption of more efficient technologies

  17. Continuous CO2 extractor and methods

    SciTech Connect (OSTI)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  18. DOE-Funded Research Yields U.S. Patent for Use of CO2 in Concrete Curing

    Broader source: Energy.gov [DOE]

    The United States Patent and Trademark Office has issued a patent to Solidia Technologies Inc. (Piscataway, NJ) for a process that uses carbon dioxide (CO2) rather than water to cure pre-cast concrete. Development of the process was funded in part by the U.S. Department of Energy’s National Energy Technology Laboratory (NETL).

  19. NETL’s 2015 Carbon Storage Atlas Shows Increase in U.S. CO2 Storage Potential

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) today released the fifth edition of the Carbon Storage Atlas (Atlas V), which shows prospective carbon dioxide (CO2) storage resources of at least 2,600 billion metric tons – an increase over the findings of the 2012 Atlas.

  20. Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    do this, we first identified a suitable force field for describing CO2, N2, and CH4 adsorption in ZIFs. On the basis of the validated force field, adsorption selectivities of the...

  1. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur ...

  2. Agricultural green revolution as a driver of increasing atmospheric CO2 seasonal amplitude

    SciTech Connect (OSTI)

    Zeng, Ning; Zhao, Fang; Collatz, George; Kalnay, Eugenia; Salawitch, Ross J.; West, Tristram O.; Guanter, Luis

    2014-11-20

    The atmospheric carbon dioxide (CO2) record displays a prominent seasonal cycle that arises mainly from changes in vegetation growth and the corresponding CO2 uptake during the boreal spring and summer growing seasons and CO2 release during the autumn and winter seasons. The CO2 seasonal amplitude has increased over the past five decades, suggesting an increase in Northern Hemisphere biospheric activity. It has been proposed that vegetation growth may have been stimulated by higher concentrations of CO2 as well as by warming in recent decades, but such mechanisms have been unable to explain the full range and magnitude of the observed increase in CO2 seasonal amplitude. Here we suggest that the intensification of agriculture (the Green Revolution, in which much greater crop yield per unit area was achieved by hybridization, irrigation and fertilization) during the past five decades is a driver of changes in the seasonal characteristics of the global carbon cycle. Our analysis of CO2 data and atmospheric inversions shows a robust 15 per cent long-term increase in CO2 seasonal amplitude from 1961 to 2010, punctuated by large decadal and interannual variations. Using a terrestrial carbon cycle model that takes into account high-yield cultivars, fertilizer use and irrigation, we find that the long-term increase in CO2 seasonal amplitude arises from two major regions: the mid-latitude cropland between 256N and 606N and the high-latitude natural vegetation between 506N and 706 N. The long-term trend of seasonal amplitude increase is 0.311 ± 0.027 percent per year, of which sensitivity experiments attribute 45, 29 and 26 per cent to land-use change, climate variability and change, and increased productivity due to CO2 fertilization, respectively. Vegetation growth was earlier by one to two weeks, as measured by the mid-point of vegetation carbon uptake, and took up 0.5 petagrams more carbon in July, the height of the growing season, during 2001–2010 than in 1961–1970

  3. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-04-20

    There is growing interest regarding the potential size of a future U.S. dedicated carbon dioxide (CO2) pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale within the United States. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies (so called WRE450 and WRE550 stabilization scenarios) and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The analysis reveals that between 11,000 and 23,000 additional miles of dedicated CO2 pipeline might be needed in the U.S. before 2050 across these two cases. While that is a significant increase over the 3,900 miles that comprise the existing national CO2 pipeline infrastructure, it is critically important to realize that the demand for additional CO2 pipeline capacity will unfold relatively slowly and in a geographically dispersed manner as new dedicated CCS-enabled power plants and industrial facilities are brought online. During the period 2010-2030, the growth in the CO2 pipeline system is on the order of a few hundred to less than a thousand miles per year. In comparison during the period 1950-2000, the U.S. natural gas pipeline distribution system grew at rates that far exceed these projections in growth in a future dedicated CO2 pipeline system. This analysis indicates that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a major obstacle for the commercial deployment of CCS technologies in the U.S. Nevertheless, there will undoubtedly be some associated regulatory and siting issues to work through but these issues should not be unmanageable based on the size of infrastructure requirements alone.

  4. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  5. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  6. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  7. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  8. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  9. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  10. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  11. Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Porous Framework Electrocatalysts Are Key to Carbon Dioxide Conversion Print The burning of fossil fuels and the consequent rising levels of atmospheric CO-2 has led to a number of negative environmental consequences, including global warming and ocean acidification. Converting CO2 to fuels or chemical feedstock, ideally through the use of renewable energy, can simultaneously reduce atmospheric CO2 and decrease fossil fuel consumption. The principal difficulty in this process is that

  12. RPCSIM-SCO2 (Reactor Power and Control SIMulator for Supercritical CO2)

    SciTech Connect (OSTI)

    Wright, Steven A.

    2012-09-12

    The RPCSIM-SCO2 code performs a dynamic simulation of a supercritical CO2 (carbon dioxide) Brayton cycle loop. The code is based on the MathLabTM program SimulinkTM from Mathworks. The Supercritical CO2 (S-CO2) model uses direct calls to the National Institute of Standards Refprop 9.0 Fortran library for the Equation-of-State (EOS) model for the CO2 working fluid (Lemmon, 2010). The calls to Refprop are made in the form of Simulink s-Functions that use a C interface to directly call the compiled Refprop fortran program library functions. Minor changes to the code can be made to use other working fluids. The code is intended to be used to perform many different types of dynamic cycle analysis for supercritical CO2 power producing systems. The code will calculate the transient temperature and pressure and all other thermodynamic properties at the inlet and outlet of each component given user supplied inputs such as rotor shaft speed, and heater power.

  13. In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO2

    SciTech Connect (OSTI)

    Loring, John S.; Thompson, Christopher J.; Wang, Zheming; Joly, Alan G.; Sklarew, Deborah S.; Schaef, Herbert T.; Ilton, Eugene S.; Rosso, Kevin M.; Felmy, Andrew R.

    2011-07-19

    Carbonation reactions are central to the prospect of CO2 trapping by mineralization in geologic reservoirs. In contrast to the relevant aqueous-mediated reactions, little is known about the propensity for carbonation in the long-term partner fluid: water-containing supercritical carbon dioxide (wet scCO2). We employed in situ mid-infrared spectroscopy to follow the reaction of a model silicate mineral (forsterite, Mg2SiO4) for 24 hr with wet scCO2 at 50C and 180 atm, using water concentrations corresponding to 0%, 55%, 95%, and 136% saturation. Results show a dramatic dependence of reactivity on water concentration and the presence of liquid water on the forsterite particles. Exposure to neat scCO2 showed no detectable carbonation reaction. At 55% and 95% water saturation, a liquid-like thin water film was detected on the forsterite particles; less than 1% of the forsterite transformed, mostly within the first 3 hours of exposure to the fluid. At 136% saturation, where an (excess) liquid water film approximately several nanometers thick was intentionally condensed on the forsterite, the carbonation reaction proceeded continuously for 24 hr with 10% to 15% transformation. Our collective results suggest constitutive links between water concentration, water film formation, reaction rate and extent, and reaction products in wet scCO2.

  14. RPCSIM-SCO2 (Reactor Power and Control SIMulator for Supercritical CO2)

    Energy Science and Technology Software Center (OSTI)

    2012-09-12

    The RPCSIM-SCO2 code performs a dynamic simulation of a supercritical CO2 (carbon dioxide) Brayton cycle loop. The code is based on the MathLabTM program SimulinkTM from Mathworks. The Supercritical CO2 (S-CO2) model uses direct calls to the National Institute of Standards Refprop 9.0 Fortran library for the Equation-of-State (EOS) model for the CO2 working fluid (Lemmon, 2010). The calls to Refprop are made in the form of Simulink s-Functions that use a C interface tomore » directly call the compiled Refprop fortran program library functions. Minor changes to the code can be made to use other working fluids. The code is intended to be used to perform many different types of dynamic cycle analysis for supercritical CO2 power producing systems. The code will calculate the transient temperature and pressure and all other thermodynamic properties at the inlet and outlet of each component given user supplied inputs such as rotor shaft speed, and heater power.« less

  15. China's transportation energy consumption and CO2 emissions from a global perspective

    SciTech Connect (OSTI)

    Yin, Xiang; Chen, Wenying; Eom, Jiyong; Clarke, Leon E.; Kim, Son H.; Patel, Pralit L.; Yu, Sha; Kyle, G. Page

    2015-07-01

    ABSTRACT Rapidly growing energy demand from China's transportation sector in the last two decades have raised concerns over national energy security, local air pollution, and carbon dioxide (CO2) emissions, and there is broad consensus that China's transportation sector will continue to grow in the coming decades. This paper explores the future development of China's transportation sector in terms of service demands, final energy consumption, and CO2 emissions, and their interactions with global climate policy. This study develops a detailed China transportation energy model that is nested in an integrated assessment model—Global Change Assessment Model (GCAM)—to evaluate the long-term energy consumption and CO2 emissions of China's transportation sector from a global perspective. The analysis suggests that, without major policy intervention, future transportation energy consumption and CO2 emissions will continue to rapidly increase and the transportation sector will remain heavily reliant on fossil fuels. Although carbon price policies may significantly reduce the sector's energy consumption and CO2 emissions, the associated changes in service demands and modal split will be modest, particularly in the passenger transport sector. The analysis also suggests that it is more difficult to decarbonize the transportation sector than other sectors of the economy, primarily owing to its heavy reliance on petroleum products.

  16. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  17. International Symposium on Site Characterization for CO2Geological Storage

    SciTech Connect (OSTI)

    Tsang, Chin-Fu

    2006-02-23

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  18. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  19. CO2 Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO 2 Heat Pump Water Heater 2016 Building Technologies Office Peer Review Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Evaporator 2 Project Summary Timeline: Start date: Oct 1, 2009 Planned end date: Sep 30, 2016 Key Milestones 1. Go/No-Go: Price premium <$750 compared to baseline HFC HPWH; FY15Q2 (MET) 2. Go/No-Go: EF>2.0 and FHR>50 gallon to meet ENERGY STAR qualification criteria; FY14Q4 (MET) Budget: Total DOE to Date: $2,367k Total Project: $2,435k Key

  20. Free Air CO2 Enrichment (FACE) Data from the Duke Forest FACE Facility

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    DOE has conducted trace gas enrichment experiments since the mid 1990s. The FACE Data Management System is a central repository and archive for Free-Air Carbon Dioxide Enrichment (FACE) data, as well as for the related open-top chamber (OTC) experiments. FACE Data Management System is located at DOEs Carbon Dioxide Information Analysis Center (CDIAC). While the data from the various FACE sites, each one a unique user facility, are centralized at CDIAC, each of the FACE sites presents its own view of its activities and information. For that reason, DOE Data Explorer users are advised to see both the central repository at http://public.ornl.gov/face/index.shtml and the individual home pages of each site. The Duke University FACE website actually presents information on several FACE experiments. The Forest-Atmosphere Carbon Transfer and Storage (FACTS-I) facility is located in the Blackwood Division of the Duke Forest. It consists of four free-air CO2 enrichment (FACE) plots that provide elevated atmospheric CO2 concentration and four plots that provide ambient CO2 control. The system has been in operation since June, 1994 in the prototype plot, and since August, 1996 in the three additional plots. The prototype plot and its reference were halved with a barrier inserted in the soil in 1998 to conduct, together with five additional plot pairs, CO2 X soil nutrient enrichment experiments. The rest of the plots were partitioned in early 2005 and incorporated into the CO2 X nutrient experiment. To increase statistical power, four additional ambient plots were established in January, 2005, halved, and one half of each fertilized. [copied from http://face.env.duke.edu/description.cfm] The Duke FACE home page makes information available from both completed and ongoing projects, provides a searchable database of publications and presentations, and data, images, and links to related websites.

  1. Free Air CO2 Enrichment (FACE) Data from the Duke Forest FACE Facility

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    DOE has conducted trace gas enrichment experiments since the mid 1990s. The FACE Data Management System is a central repository and archive for Free-Air Carbon Dioxide Enrichment (FACE) data, as well as for the related open-top chamber (OTC) experiments. FACE Data Management System is located at DOEÆs Carbon Dioxide Information Analysis Center (CDIAC). While the data from the various FACE sites, each one a unique user facility, are centralized at CDIAC, each of the FACE sites presents its own view of its activities and information. For that reason, DOE Data Explorer users are advised to see both the central repository at http://public.ornl.gov/face/index.shtml and the individual home pages of each site. The Duke University FACE website actually presents information on several FACE experiments. The Forest-Atmosphere Carbon Transfer and Storage (FACTS-I) facility is located in the Blackwood Division of the Duke Forest. It consists of four free-air CO2 enrichment (FACE) plots that provide elevated atmospheric CO2 concentration and four plots that provide ambient CO2 control. The system has been in operation since June, 1994 in the prototype plot, and since August, 1996 in the three additional plots. The prototype plot and its reference were halved with a barrier inserted in the soil in 1998 to conduct, together with five additional plot pairs, CO2 X soil nutrient enrichment experiments. The rest of the plots were partitioned in early 2005 and incorporated into the CO2 X nutrient experiment. To increase statistical power, four additional ambient plots were established in January, 2005, halved, and one half of each fertilized. [copied from http://face.env.duke.edu/description.cfm] The Duke FACE home page makes information available from both completed and ongoing projects, provides a searchable database of publications and presentations, and data, images, and links to related websites.

  2. Spatial Disaggregation of CO2 Emissions for the State of California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

    2008-06-11

    This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel

  3. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  4. EIS-0473: W.A. Parish Post-Combustion CO2 Capture and Sequestration Project (PCCS), Fort Bend County, TX

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a proposal to provide financial assistance for a project proposed by NRG Energy, Inc (NRG). DOE selected NRG’s proposed W.A. Parish Post-Combustion CO2 Capture and Sequestration Project for a financial assistance award through a competitive process under the Clean Coal Power Initiative Program. NRG would design, construct and operate a commercial-scale carbon dioxide (CO2) capture facility at its existing W.A. Parish Generating Station in Fort Bend County, Texas; deliver the CO2 via a new pipeline to the existing West Ranch oil field in Jackson County, Texas, for use in enhanced oil recovery operations; and demonstrate monitoring techniques to verify the permanence of geologic CO2 storage.

  5. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  6. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  7. Sulfur dioxide gas detection with Na/sub 2/SO/sub 4/-Li/sub 2/SO/sub 4/-Y/sub 2/(SO/sub 4/)/sub 3/-SiO/sub 2/ solid electrolyte by a solid reference electrode method

    SciTech Connect (OSTI)

    Imanaka, N.; Yamaguchi, Y.; Adachi, G.; Shiokawa, J.

    1987-03-01

    The electromotive force (EMF) measurement for a Na/sub 2/SO/sub 4/Li/sub 2/SO/sub 4/-Y/sub 2/(SO/sub 4/)/sub 3/-SiO/sub 2/ solid electrolyte was performed both with NiSO/sub 4/-NiO and CoSO/sub 4/-Co/sub 3/O/sub 4/ solid reference SO/sub 2/ electrodes. The measured EMF coincided well with the calculated EMF for a sulfur dioxide gas concentration from 30 ppm to 1% at 973 K. Good agreement between the measured and calculated EMF was also obtained for the SO/sub 2/ gas content from 100 ppm to 1%, at 923 K with the NiSO/sub 4/-NiO electrode.

  8. [NiIII(OMe)]-mediated reductive activation of CO2 affording a Ni(κ1-OCO) complex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chiou, Tzung -Wen; Tseng, Yen -Ming; Lu, Tsai -Te; Weng, Tsu -Chien; Sokaras, Dimosthenes; Ho, Wei -Chieh; Kuo, Ting -Shen; Jang, Ling -Yun; Lee, Jyh -Fu; Liaw, Wen -Feng

    2016-02-24

    Here, carbon dioxide is expected to be employed as an inexpensive and potential feedstock of C1 sources for the mass production of valuable chemicals and fuel. Versatile chemical transformations of CO2, i.e. insertion of CO2 producing bicarbonate/acetate/formate, cleavage of CO2 yielding μ-CO/μ-oxo transition-metal complexes, and electrocatalytic reduction of CO2 affording CO/HCOOH/CH3OH/CH4/C2H4/oxalate were well documented. Herein, we report a novel pathway for the reductive activation of CO2 by the [NiIII(OMe)(P(C6H3-3-SiMe3-2-S)3)]– complex, yielding the [NiIII(κ1-OCO˙–)(P(C6H3-3-SiMe3-2-S)3)]– complex. The formation of this unusual NiIII(κ1-OCO˙–) complex was characterized by single-crystal X-ray diffraction, EPR, IR, SQUID, Ni/S K-edge X-ray absorption spectroscopy, and Ni valence-to-core X-ray emissionmore » spectroscopy. The inertness of the analogous complexes [NiIII(SPh)], [NiII(CO)], and [NiII(N2H4)] toward CO2, in contrast, demonstrates that the ionic [NiIII(OMe)] core attracts the binding of weak σ-donor CO2 and triggers the subsequent reduction of CO2 by the nucleophilic [OMe]– in the immediate vicinity. This metal–ligand cooperative activation of CO2 may open a novel pathway promoting the subsequent incorporation of CO2 in the buildup of functionalized products.« less

  9. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon

  10. Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cycles | Department of Energy Receivers for Supercritical Carbon Dioxide Cycles Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles Brayton logo --This project is inactive -- Brayton Energy, under the 2012 SunShot Concentrating Solar Power (CSP) R&D FOA, is building and testing a new solar receiver that uses supercritical carbon dioxide (s-CO2) as the heat-transfer fluid. The research team is designing the receiver to withstand higher operating temperatures

  11. Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exchangers | Department of Energy Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers SWRI Logo The Southwest Research Institute (SWRI) and its partners, under the 2012 Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are developing a supercritical carbon dioxide (s-CO2) power cycle that combines high efficiencies and low costs for modular CSP applications.

  12. Shell Future Fuels and CO2 | Open Energy Information

    Open Energy Info (EERE)

    Shell Future Fuels and CO2 Jump to: navigation, search Name: Shell Future Fuels and CO2 Place: Glasgow, Scotland, United Kingdom Zip: G1 9BG Sector: Hydro, Hydrogen Product:...

  13. CO2ReMoVe | Open Energy Information

    Open Energy Info (EERE)

    of industrial, research and service organizations with experience in CO2 geological storage. References: CO2ReMoVe1 This article is a stub. You can help OpenEI by expanding...

  14. CantorCO2e | Open Energy Information

    Open Energy Info (EERE)

    CantorCO2e Jump to: navigation, search Name: CantorCO2e Place: London, Greater London, United Kingdom Zip: E14 5RD Product: London-headquartered emissions broker and fund manager...

  15. CO2 Capture Poject CCP | Open Energy Information

    Open Energy Info (EERE)

    CO2 Capture Poject CCP Jump to: navigation, search Name: CO2 Capture Poject (CCP) Place: United Kingdom Sector: Carbon Product: CCP is a partnership of energy companies and...

  16. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    a synthesis of net land-atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990-2009. Only CO2 is considered, not methane or...

  17. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  18. Supercritical CO2 Tech Team | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    offered by the sCO2 Brayton Cycle technology (compared to the widely-used steam turbine Rankin Cycle.) Benefits of the sCO2 Brayton Cycle for energy production Economic ...

  19. Enhanced Geothermal Systems: Comparing Water and CO2 as Heat...

    Office of Scientific and Technical Information (OSTI)

    ENHANCED GEOTHERMAL SYSTEMS (EGS): COMPARING WATER AND CO 2 AS HEAT TRANSMISSION FLUIDS ... with supercritical CO 2 instead of water as heat transmission fluid (D.W. Brown, 2000). ...

  20. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    An integrated framework for CO2 accounting and risk analysis of CO2-EOR Authors: Dai, Zhenxue 1 ; Viswanathan, Hari S. 1 ; Middleton, Richard Stephen 1 ; Fessenden-Rahn, ...

  1. Overview of the CO2 Geological Sequestration System

    Office of Scientific and Technical Information (OSTI)

    CO 2 is a so-called "greenhouse gas" that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO 2 will make the arctic ...

  2. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    up with a net reduction in the CO2 emitted. Thus, effective catalysts that can lower the energy requirements for CO2 chemical reactions are an important part of the equation....

  3. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    CO2 storage site, the Rangely Oil Field, where CO2-EOR has been underway since the 1980s. ... as well as methane and trace gases) of conventional and unconventional oil and gas. ...

  4. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World

  5. Pressure data from Cranfield CO2 Thermosiphon test

    SciTech Connect (OSTI)

    Barry Freifeld

    2015-01-21

    Pressure data acquired in well F2 and F3 during the CO2 geothermal thermosiphoning test, Cranfield MS.

  6. SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

    SciTech Connect (OSTI)

    Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

    2014-12-31

    Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this report’s real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transport–storage projects: Sleipner, Snøhvit, In Salah, Weyburn, and Illinois Basin–Decatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The

  7. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result

  8. Conductivity measurements on H2O-bearing CO2-rich fluids

    SciTech Connect (OSTI)

    Capobianco, Ryan [Virginia Polytechnic Institute and State University; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Bodnar, Robert [Virginia Polytechnic Institute and State University; Rimstidt, J. Donald [Virginia Polytechnic Institute and State University

    2015-01-01

    Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H2O to CO2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H2O concentrations up to ~1600 ppmw (xH2O 3.9 10-3), corresponding to the H2O solubility limit in liquid CO2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. This observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.

  9. Conductivity measurements on H2O-bearing CO2-rich fluids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Capobianco, Ryan M.; Miroslaw S. Gruszkiewicz; Bodnar, Robert J.; Rimstidt, J. Donald

    2014-09-10

    Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H2O to CO2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H2O concentrations up to ~1600 ppmwmore » (xH2O ≈ 3.9 x 10-3), corresponding to the H2O solubility limit in liquid CO2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. Furthermore, this observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.« less

  10. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, R.M.; Lu, Peng; Allen, D.E.; Soong, Yee; Hedges, S.W.; Fu, J.K.; Dobbs, C.L.; DeGalbo, A.D.; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 °C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  11. Process for CO2 Capture Using Ionic Liquid That Exhibits Phase Change

    SciTech Connect (OSTI)

    Eisinger, RS; Keller, GE

    2014-11-01

    A novel process for capturing carbon dioxide from the flue gas of a coal-fired power plant has been shown to reduce parasitic power consumption substantially. The process employs an ionic liquid created at the University of Notre Dame that has a high capacity for absorbing CO2 by chemical reaction. A distinguishing property of this ionic liquid is that it changes phase from solid to liquid upon reaction with CO2. The process uses heat generated by this phase transition to lower parasitic power consumption. The driving force for CO2 separation is a combination of temperature and pressure differences; the process could even work without the addition of heat. A realistic process was created to capture CO2 efficiently. Computer simulation of the process enabled calculation of viable process conditions and power usage. The main concepts of the process were shown to work using a lab-scale apparatus. Parasitic power consumes 23% of net power generation, 55% lower than that of the monoethanolamine (MEA) process. However, capital cost is higher. The cost of electricity (COE) is 28% lower than that of the MEA process.

  12. Progress Towards Commercialization of Electrochemical Membrane Technology for CO2 Capture and Power Generation

    SciTech Connect (OSTI)

    Ghezel-Ayagh, Hossein; Jolly, Stephen; DiNitto, M.; Hunt, Jennifer; Patel, Dilip; Steen, William A.; Richardson, C. F.; Marina, Olga A.; Pederson, Larry R.

    2014-03-01

    To address the concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept, as a novel solution for greenhouse gas emission reduction. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s well established Direct FuelCell® products. The system concept works as two devices in one: it separates the CO2 from the exhaust of other plants and simultaneously, using a supplementary fuel, produces electric power at high efficiency. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of coal fired power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of a PC plant with no more than 35% increase in the cost of electricity. The specific objectives and related activities presently ongoing for the project include: 1) conduct bench scale tests of ECM and 2) evaluate the effects of impurities present in the coal plant flue gas by laboratory scale performance tests of the membrane.

  13. Liquid Fuel From Microbial Communities: Electroalcoholgenesis: Bioelectrochemical Reduction of CO2 to Butanol

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: MUSC is developing an engineered system to create liquid fuels from communities of interdependent microorganisms. MUSC is first pumping carbon dioxide (CO2) and renewable sources of electricity into a battery-like cell. A community of microorganisms uses the electricity to convert the CO2 into hydrogen. That hydrogen is then consumed by another community of microorganisms living in the same system. These new microorganisms convert the hydrogen into acetate, which in turn feed yet another community of microorganisms. This last community of microorganisms uses the acetate to produce a liquid biofuel called butanol. Similar interdependent microbial communities can be found in some natural environments, but they’ve never been coupled together in an engineered cell to produce liquid fuels. MUSC is working to triple the amount of butanol that can be produced in its system and to reduce the overall cost of the process.

  14. Efficient CO2 Fixation Pathways: Energy Plant: High Efficiency Photosynthetic Organisms

    SciTech Connect (OSTI)

    2012-01-01

    PETRO Project: UCLA is redesigning the carbon fixation pathways of plants to make them more efficient at capturing the energy in sunlight. Carbon fixation is the key process that plants use to convert carbon dioxide (CO2) from the atmosphere into higher energy molecules (such as sugars) using energy from the sun. UCLA is addressing the inefficiency of the process through an alternative biochemical pathway that uses 50% less energy than the pathway used by all land plants. In addition, instead of producing sugars, UCLA’s designer pathway will produce pyruvate, the precursor of choice for a wide variety of liquid fuels. Theoretically, the new biochemical pathway will allow a plant to capture 200% as much CO2 using the same amount of light. The pathways will first be tested on model photosynthetic organisms and later incorporated into other plants, thus dramatically improving the productivity of both food and fuel crops.

  15. NREL's Cyanobacteria Engineering Shortens Biofuel Production Process, Captures CO2 (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The flexibility of cyanobacterial metabolism supports direct conversion of carbon dioxide (CO 2 ) to ethylene. Photosynthesis fuels growth in plants and algae, two of the primary components of biomass. Biomass, in turn, can be converted into various fuels and chemicals. NREL researchers have shortened this process by engineering one photosynthetic organism, cyanobacterium, so that it converts CO 2 directly into the target chemical ethylene, bypassing the biomass produc- tion and processing

  16. Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II

    SciTech Connect (OSTI)

    Wier, Don R. Chimanhusky, John S.; Czirr, Kirk L.; Hallenbeck, Larry; Gerard, Matthew G.; Dollens, Kim B.; Owen, Rex; Gaddis, Maurice; Moshell, M.K.

    2002-11-18

    The purpose of this project was to economically design an optimum carbon dioxide (CO2) flood for a mature waterflood nearing its economic abandonment. The original project utilized advanced reservoir characterization and CO2 horizontal injection wells as the primary methods to redevelop the South Cowden Unit (SCU). The development plans; project implementation and reservoir management techniques were to be transferred to the public domain to assist in preventing premature abandonment of similar fields.

  17. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATK’s design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  18. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy

    SciTech Connect (OSTI)

    Arey, Bruce W.; Kovarik, Libor; Wang, Zheming; Felmy, Andrew R.

    2011-10-10

    The capture and storage of carbon dioxide and other greenhouse gases in deep geologic formations represents one of the most promising options for mitigating the impacts of greenhouse gases on global warming. In this regard, mineral-fluid interactions are of prime importance since such reactions can result in the long term sequestration of CO2 by trapping in mineral phases. Recently it has been recognized that interactions with neat to water-saturated non-aqueous fluids are of prime importance in understanding mineralization reactions since the introduced CO2 is likely to contain water initially or soon after injection and the supercritical CO2 (scCO2) is less dense than the aqueous phase which can result in a buoyant scCO2 plume contacting the isolating caprock. As a result, unraveling the molecular/microscopic mechanisms of mineral transformation in neat to water saturated scCO2 has taken on an added important. In this study, we are examining the interfacial reactions of the olivine mineral forsterite (Mg2SiO4) over a range of water contents up to and including complete water saturation in scCO2. The surface precipitates that form on the reacted forsterite grains are extremely fragile and difficult to experimentally characterize. In order to address this issue we have developed experimental protocols for preparing and imaging electron-transparent samples from fragile structures. These electron-transparent samples are then examined using a combination of STEM/EDX, FIB-TEM, and helium ion microscope (HIM) imaging (Figures 1-3). This combination of capabilities has provided unique insight into the geochemical processes that occur on scCO2 reacted mineral surfaces. The experimental procedures and protocols that have been developed also have useful applications for examining fragile structures on a wide variety of materials. This research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and

  19. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2

  20. Novel Concepts Research in Geologic Storage of CO2

    SciTech Connect (OSTI)

    Neeraj Gupta

    2006-09-30

    As part of the Department of Energy's (DOE) initiative on developing new technologies for the storage of carbon dioxide (CO{sub 2}) in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs of the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the July-September 2006 period of the project. As discussed in the following report, the main accomplishments were reservoir modeling for the Copper Ridge ''B-zone'' and design and feasibility support tasks. Work continued on the development of injection well design options, engineering assessment of CO2 capture systems, permitting, and assessment of monitoring technologies as they apply to the project site. In addition, an integrated risk analysis of the proposed system was completed. Finally, slipstream capture construction issues were evaluated with AEP to move the project toward an integrated carbon capture and storage system at the Mountaineer site. Overall, the current design feasibility phase project is proceeding according to plans.

  1. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  2. Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species

    SciTech Connect (OSTI)

    Nassar, Ray; Jones, DBA; Suntharalingam, P; Chen, j.; Andres, Robert Joseph; Wecht, K. J.; Yantosca, R. M.; Kulawik, SS; Bowman, K; Worden, JR; Machida, T; Matsueda, H

    2010-01-01

    The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure

  3. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  4. METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY

    SciTech Connect (OSTI)

    Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

    2009-06-22

    HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

  5. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and

  6. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore » control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  7. Sulfur tolerant highly durable CO.sub.2 sorbents (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Sulfur tolerant highly durable CO.sub.2 sorbents A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent ...

  8. Efficient Theoretical Screening of Solid Sorbents for CO2 Capture

    Office of Scientific and Technical Information (OSTI)

    Applications* (Journal Article) | SciTech Connect Journal Article: Efficient Theoretical Screening of Solid Sorbents for CO2 Capture Applications* Citation Details In-Document Search Title: Efficient Theoretical Screening of Solid Sorbents for CO2 Capture Applications* By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates

  9. Supercritical CO2 Power Cycles: Design Considerations for Concentrating

    Office of Scientific and Technical Information (OSTI)

    Solar Power (Conference) | SciTech Connect Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power Citation Details In-Document Search Title: Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power A comparison of three supercritical CO2 Brayton cycles: the simple cycle, recompression cycle and partial-cooling cycle indicates the partial-cooling cycle is favored for use in concentrating solar power (CSP) systems. Although it displays

  10. Innovative Concepts for Beneficial Reuse of Carbon Dioxide | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Innovative Concepts for Beneficial Reuse of Carbon Dioxide Innovative Concepts for Beneficial Reuse of Carbon Dioxide Funding for 12 projects to test innovative concepts for the beneficial use of carbon dioxide (CO2) was announced by the U.S. Department of Energy. The awards are part of $1.4 billion in funding from the American Recovery and Reinvestment Act (ARRA) for projects that will capture carbon dioxide from industrial sources. These 12 projects will engage in a first phase

  11. CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE (Technical...

    Office of Scientific and Technical Information (OSTI)

    Subject: 54 ENVIRONMENTAL SCIENCES; CARBON DIOXIDE; ABSORPTION; SORPTIVE PROPERTIES; POTASSIUM CARBONATES; THERMODYNAMIC MODEL; VAPOR PRESSURE; AIR POLLUTION CONTROL Word Cloud ...

  12. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54 ENVIRONMENTAL SCIENCES; CARBON DIOXIDE; ABSORPTION; POTASSIUM CARBONATES; SORPTIVE PROPERTIES; AMINES; MATERIALS RECOVERY; AIR POLLUTION CONTROL; MATHEMATICAL MODELS ...

  13. CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE (Technical...

    Office of Scientific and Technical Information (OSTI)

    Subject: 54 ENVIRONMENTAL SCIENCES; ABSORPTION; HEAT EXCHANGERS; PILOT PLANTS; POTASSIUM CARBONATES; THERMODYNAMICS; VAPOR PRESSURE; CARBON DIOXIDE; AIR POLLUTION CONTROL; SORPTIVE ...

  14. Reversible Alteration of CO2 Adsorption upon Photochemical or...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal Treatment in a Metal-Organic Framework Previous Next List Jinhee Park , Daqiang Yuan , Khanh T. Pham , ...

  15. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2013 NETL CO2 Capture Technology Meeting July 8-11, 2013 Previous Proceedings 2012: NETL CO2 Capture Technology Meeting Proceedings of the 2013 NETL CO2 Capture Technology Meeting Table of Contents Presentations Monday, July 8 Opening/Overview Post-Combustion Sorbent-Based Capture Tuesday, July 9 Post-Combustion Solvent-Based Capture CO2 Compression Wednesday, July 10 Post-Combustion Membrane-Based Capture Pre-Combustion Capture Projects Thursday, July 11 ARPA-E Capture Projects System Studies

  16. CO2 Heat Pump Water Heater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    other refrigerants), CO2 also has greater potential for use in residentialcommercial demand response units, as well as for high-temperature commercial water heating applications. ...

  17. CO2 interaction with geomaterials. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    to investigate the effect of CO2 pressure on the thermoplastic properties of coal. ... Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to ...

  18. Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring...

    Open Energy Info (EERE)

    Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring Jump to: navigation, search OpenEI Reference LibraryAdd to library Book: Hyperspectral Geobotanical Remote...

  19. Photosynthetic Conversion of CO2 to Fuels and Chemicals using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthetic Conversion of CO 2 to Fuels and Chemicals using Cyanobacteria Accelerating Innovation Webinar August 8, 2012 Jianping Yu, Ph.D., Senior Scientist * Many eukaryotic ...

  20. Game-Changing Process Mitigates CO2 Emissions Using Renewable...

    Broader source: Energy.gov (indexed) [DOE]

    Game-Changing Process Mitigates CO2 Emissions Using Renewable Energy Gold nanoparticles ... Researchers developed a special form of gold nanoparticle that contains exactly 25 gold ...

  1. CO2 Emissions from Fuel Combustion | Open Energy Information

    Open Energy Info (EERE)

    from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References "CO2 Emissions from Fuel Combustion" Retrieved from "http:...

  2. Enhanced Geothermal Systems (EGS) comparing water with CO2 as...

    Office of Scientific and Technical Information (OSTI)

    Enhanced Geothermal Systems (EGS) comparing water with CO2 as heattransmission fluids Citation Details In-Document Search Title: Enhanced Geothermal Systems (EGS) comparing water ...

  3. Tool for calculation of CO2 emissions from organisations | Open...

    Open Energy Info (EERE)

    lt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":"" Hide Map Language: English Tool for calculation of CO2 emissions from organisations Screenshot...

  4. Efficient electrochemical CO2 conversion powered by renewable energy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R.; Zeng, Chenjie; Jin, Rongchao

    2015-06-29

    Here, the catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspondmore » to conversion rates approaching 0.8–1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 106 mol CO2 molcatalyst–1 during a multiday (36 hours total hours) CO2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 106 and 4 × 106 molCO2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies

  5. Sulfonate-Grafted Porous Polymer Networks for Preferential CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure Previous Next List Weigang Lu, Daqiang Yuan, Julian Sculley, Dan Zhao, Rajamani Krishna,...

  6. Chemical Impact of Elevated CO2on Geothermal Energy Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based ...

  7. Kinetic performance of CO2 absorption into a potassium carbonate...

    Office of Scientific and Technical Information (OSTI)

    Title: Kinetic performance of CO2 absorption into a potassium carbonate solution ... Type: Publisher's Accepted Manuscript Journal Name: Chemical Engineering Journal (Print) ...

  8. High Co2 Emissions Through Porous Media- Transport Mechanisms...

    Open Energy Info (EERE)

    Co2 Emissions Through Porous Media- Transport Mechanisms And Implications For Flux Measurement And Fractionation Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  9. Literature Review of Mobility Control Methods for CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... year for 50 years), reducing oil imports by ... CO 2 captured from coal- fired power plants and other industrial ... and applying advanced methods for monitoring flood ...

  10. Secure and sustainable energy infrastructure: The case of CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Report: Secure and sustainable energy infrastructure: The case of CO2 capture, utilization, and storage Citation Details In-Document Search Title: Secure and sustainable ...

  11. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia...

    Energy Savers [EERE]

    of an NETL-sponsored CO2 storage research project ... teamed with the National Energy Technology Laboratory ... A supervisory control and data acquisition (SCADA) system ...

  12. Misrepresentation of the IPCC CO2 emission scenarios (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Misrepresentation of the IPCC CO2 emission scenarios Citation Details In-Document Search Title: ... with the IPCC SRES (Special Report on Emission Scenarios) ...

  13. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tech/NETL Research | Department of Energy Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research October 20, 2015 - 8:14am Addthis Researchers from Virginia Tech are injecting CO2 into coal seams in three locations in Buchanan County, Va., as part of an NETL-sponsored CO2 storage research project associated with enhanced gas recovery. Researchers from Virginia Tech are

  14. ESTIMATING MAXIMUM SUSTAINABLE PRESSURE DURING CO2 INJECTION...

    Office of Scientific and Technical Information (OSTI)

    ... Presented at the Ground Water Protection Council 2008 Annual ... related to upwelling of deep CO2-rich fluids during the ... Engineers (SPE) Reservoir Evaluation & Engineering. ...

  15. Low Cost Open-Path Instrument for Monitoring Surface Carbon Dioxide at Sequestration Sites Phase I SBIR Final Report

    SciTech Connect (OSTI)

    Sheng Wu

    2012-10-02

    Public confidence in safety is a prerequisite to the success of carbon dioxide (CO2) capture and storage for any program that intends to mitigate greenhouse gas emissions. In that regard, this project addresses the security of CO2 containment by undertaking development of what is called ?¢????an open path device?¢??? to measure CO2 concentrations near the ground above a CO2 storage area.

  16. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  17. Commerical-Scale CO2 Capture and Sequestration for the Cement Industry

    SciTech Connect (OSTI)

    Adolfo Garza

    2010-07-28

    On June 8, 2009, DOE issued Funding Opportunity Announcement (FOA) Number DE-FOA-000015 seeking proposals to capture and sequester carbon dioxide from industrial sources. This FOA called for what was essentially a two-tier selection process. A number of projects would receive awards to conduct front-end engineering and design (FEED) studies as Phase I. Those project sponsors selected would be required to apply for Phase II, which would be the full design, construction, and operation of their proposed technology. Over forty proposals were received, and ten were awarded Phase I Cooperative Agreements. One of those proposers was CEMEX. CEMEX proposed to capture and sequester carbon dioxide (CO2) from one of their existing cement plants and either sequester the CO2 in a geologic formation or use it for enhanced oil recovery. The project consisted of evaluating their plants to identify the plant best suited for the demonstration, identify the best available capture technology, and prepare a design basis. The project also included evaluation of the storage or sequestration options in the vicinity of the selected plant.

  18. CHEMICAL FIXATION OF CO2 IN COAL COMBUSTION PRODUCTS AND RECYCLING THROUGH BIOSYSTEMS

    SciTech Connect (OSTI)

    C. Henry Copeland; Paul Pier; Samantha Whitehead; Paul Enlow; Richard Strickland; David Behel

    2003-12-15

    This Annual Technical Progress Report presents the principle results in enhanced growth of algae using coal combustion products as a catalyst to increase bicarbonate levels in solution. A co-current reactor is present that increases the gas phase to bicarbonate transfer rate by a factor of five to nine. The bicarbonate concentration at a given pH is approximately double that obtained using a control column of similar construction. Algae growth experiments were performed under laboratory conditions to obtain baseline production rates and to perfect experimental methods. The final product of this initial phase in algae production is presented. Algal growth can be limited by several factors, including the level of bicarbonate available for photosynthesis, the pH of the growth solution, nutrient levels, and the size of the cell population, which determines the available space for additional growth. In order to supply additional CO2 to increase photosynthesis and algal biomass production, fly ash reactor has been demonstrated to increase the available CO2 in solution above the limits that are achievable with dissolved gas alone. The amount of dissolved CO2 can be used to control pH for optimum growth. Periodic harvesting of algae can be used to maintain algae in the exponential, rapid growth phase. An 800 liter scale up demonstrated that larger scale production is possible. The larger experiment demonstrated that indirect addition of CO2 is feasible and produces significantly less stress on the algal system. With better harvesting methods, nutrient management, and carbon dioxide management, an annual biomass harvest of about 9,000 metric tons per square kilometer (36 MT per acre) appears to be feasible. To sequester carbon, the algal biomass needs to be placed in a permanent location. If drying is undesirable, the biomass will eventually begin to aerobically decompose. It was demonstrated that algal biomass is a suitable feed to an anaerobic digester to produce methane

  19. Fundamental Understanding of Methane-Carbon Dioxide-Water (CH4...

    Office of Scientific and Technical Information (OSTI)

    Fundamental Understanding of Methane-Carbon Dioxide-Water (CH4-CO2-H2O) Interactions in Shale Nanopores under Reservoir Conditions. Citation Details In-Document Search Title:...

  20. Fundamental Understanding of Methane-Carbon Dioxide-Water (CH4...

    Office of Scientific and Technical Information (OSTI)

    Fundamental Understanding of Methane-Carbon Dioxide-Water (CH4-CO2- H20) Interactions in Shale Nanopores under ReservoirSAND2o 1T-20" if4pe Yifeng Wang, Yongliang Xiong & Louise ...

  1. Fundamental Understanding of Methane-Carbon Dioxide-Water (CH4...

    Office of Scientific and Technical Information (OSTI)

    ...Water (CH4-CO2-H2O) Interactions in Shale Nanopores under Reservoir Conditions. Citation Details In-Document Search Title: Fundamental Understanding of Methane-Carbon Dioxide-Water ...

  2. Method for carbon dioxide sequestration

    DOE Patents [OSTI]

    Wang, Yifeng; Bryan, Charles R.; Dewers, Thomas; Heath, Jason E.

    2015-09-22

    A method for geo-sequestration of a carbon dioxide includes selection of a target water-laden geological formation with low-permeability interbeds, providing an injection well into the formation and injecting supercritical carbon dioxide (SC--CO.sub.2) into the injection well under conditions of temperature, pressure and density selected to cause the fluid to enter the formation and splinter and/or form immobilized ganglia within the formation. This process allows for the immobilization of the injected SC--CO.sub.2 for very long times. The dispersal of scCO2 into small ganglia is accomplished by alternating injection of SC--CO.sub.2 and water. The injection rate is required to be high enough to ensure the SC--CO.sub.2 at the advancing front to be broken into pieces and small enough for immobilization through viscous instability.

  3. Positron Annihilation Spectroscopy of High Performance Polymer Films under CO2 Pressure

    SciTech Connect (OSTI)

    C.A. Quarles; John R. Klaehn; Eric S. Peterson; Jagoda M. Urban-Klaehn

    2010-08-01

    Positron annihilation Lifetime and Doppler broadening measurements are reported for six polymer films as a function of carbon dioxide absolute pressure ranging from 0 to 45 psi. Since the polymer films were thin and did not absorb all positrons, corrections were made in the lifetime analysis for the absorption of positrons in the positron source and sample holder using the Monte Carlo transport code MCNP. Different polymers are found to behave differently. Some polymers studied form positronium and some, such as the polyimide structures, do not. For those samples that form positronium an interpretation in terms of free volume is possible; for those that don’t form positronium, further work is needed to determine how best to describe the behavior in terms of the bulk positron annihilation parameters. Some polymers exhibit changes in positron lifetime and intensity under CO2 pressure which may be described by the Henry or Langmuir sorption models, while the positron response of other polymers is rather insensitive to the CO2 pressure. The results demonstrate the usefulness of positron annihilation spectroscopy in investigating the sorption of CO2 into various polymers at pressures up to about 3 atm.

  4. Sequestration of Carbon Dioxide with Enhanced Gas Recovery-CaseStudy Altmark, North German Basin

    SciTech Connect (OSTI)

    Rebscher, Dorothee; Oldenburg, Curtis M.

    2005-10-12

    Geologic carbon dioxide storage is one strategy for reducingCO2 emissions into the atmosphere. Depleted natural gas reservoirs are anobvious target for CO2 storage due to their proven record of gascontainment. Germany has both large industrial sources of CO2 anddepleting gas reservoirs. The purpose of this report is to describe theanalysis and modeling performed to investigate the feasibility ofinjecting CO2 into nearly depleted gas reservoirs in the Altmark area inNorth Germany for geologic CO2 storage with enhanced gasrecovery.

  5. Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents

    DOE Patents [OSTI]

    Ayala, Raul E.; Gal, Eli

    1995-01-01

    A process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal-sulfur compound. Spent metal-sulfur compound is regenerated to re-usable metal oxide by moving a bed of spent metal-sulfur compound progressively through a single regeneration vessel having a first and second regeneration stage and a third cooling and purging stage. The regeneration is carried out and elemental sulfur is generated in the first stage by introducing a first gas of sulfur dioxide which contains oxygen at a concentration less than the stoichiometric amount required for complete oxidation of the spent metal-sulfur compound. A second gas containing sulfur dioxide and excess oxygen at a concentration sufficient for complete oxidation of the partially spent metal-sulfur compound, is introduced into the second regeneration stage. Gaseous sulfur formed in the first regeneration stage is removed prior to introducing the second gas into the second regeneration stage. An oxygen-containing gas is introduced into the third cooling and purging stage. Except for the gaseous sulfur removed from the first stage, the combined gases derived from the regeneration stages which are generally rich in sulfur dioxide and lean in oxygen, are removed from the regenerator as an off-gas and recycled as the first and second gas into the regenerator. Oxygen concentration is controlled by adding air, oxygen-enriched air or pure oxygen to the recycled off-gas.

  6. Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I

    SciTech Connect (OSTI)

    Bou-Mikael, Sami

    2002-02-05

    This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field.

  7. Matrix Shrinkage and Swelling Effects on Economics of Enhanced Coalbed Methane Production and CO2 Sequestration in Coal

    SciTech Connect (OSTI)

    Gorucu, F.B.; Jikich, S.A.; Bromhal, G.S.; Sams, W.N.; Ertekin, T.; Smith, D.H.

    2005-09-01

    Increases in CO2 levels in the atmosphere and their contributions to global climate change have been a major concern. It has been shown that CO2 injection can enhance the methane recovery from coal. Accordingly, sequestration costs can be partially offset by the value added product. Indeed, coal seam sequestration may be profitable, particularly with the introduction of incentives for CO2 sequestration. Hence, carbon dioxide sequestration in unmineable coals is a very attractive option, not only for environmental reasons, but also for possible economic benefits. Darcy flow through cleats is an important transport mechanism in coal. Cleat compression and permeability changes due to gas sorption desorption, changes of effective stress, and matrix swelling and shrinkage introduce a high level of complexity into the feasibility of a coal sequestration project. The economic effects of carbon dioxide-induced swelling on permeabilities and injectivities has received little (if any) detailed attention. Carbon dioxide and methane have different swelling effects on coal. In this work, the Palmer-Mansoori model for coal shrinkage and permeability increases during primary methane production was re-written to also account for coal swelling caused by carbon dioxide sorption. The generalized model was added to PSU-COALCOMP, a dual porosity reservoir simulator for primary and enhanced coalbed methane production. A standard five-spot of vertical wells and representative coal properties for Appalachian coals were used.[1] Simulations and sensitivity analyses were performed with the modified simulator for nine different parameters, including coal seam and operational parameters and economic criteria. The coal properties and operating parameters that were varied included Youngs modulus, Poissons ratio, the cleat porosity, and the injection pressure. The economic variables included CH4 price, CO2 cost, CO2 credit, water disposal cost, and interest rate. Net present value analyses of

  8. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  9. Development and Validation of Multidimensional Models of Supercritical CO2 Energy Conversion Systems for Nuclear Power Reactors

    SciTech Connect (OSTI)

    Podowski, Michael Z.

    2015-01-22

    A general objective of this project was to develop, verify and validate mechanistic multidimensional models of local flow and heat transfer in supercritical carbon dioxide (S-CO2) devices and systems, and to demonstrate the application of the new models to selected components of S-CO2 nuclear energy transport systems. Both steady-state and time-dependent operating conditions have been investigated. The overall workscope consisted of the following three major parts: Development, testing and validation of a mechanistic model of forced-convection heat transfer in heated channels cooled using S-CO2 at slightly supercritical pressures; Development, testing and verification/validation of a new model of the dynamics of closed- loop S-CO2 heat transport systems; and, Formulation, testing and verification of a mechanistic model for the analysis of flow and pressure distribution in S-CO2 compressors. The results of the work performed for the project have been documented in several publications.

  10. The Influence of deep-sea bed CO2 sequestration on small metazoan (meiofaunal) community structure and function

    SciTech Connect (OSTI)

    Carman, Kevin R; Fleeger, John W; Thistle, David

    2013-02-17

    We conducted a series of experiments in Monterey Submarine Canyon to examine potential ecological impacts of deep-ocean CO2 sequestration. Our focus was on responses of meiofaunal invertebrates (< 1 mm body length) living within the sediment at depths ranging between 3000-3600 m. Our particular emphasis was on harpacticoid copepods and nematodes. In the first phase of our DOE funding, we reported findings that suggest substantial (~80%) mortality to harpacticoid copepods. In the second phase of our funding we published additional findings from phase one and conducted follow-up experiments in the Monterey Canyon and in the laboratory. In one experiment we looked for evidence that meiofauna seek to escape areas where CO2 concentrations are elevated. â??Emergence trapsâ? near the source of the CO2-rich seawater caught significantly more harpacticoids than those far from it. The harpacticoids apparently attempted to escape from the advancing front of carbon dioxide-rich seawater and therefore presumably found exposure to it to be stressful. Although most were adversely affected, species differed significantly in the degree of their susceptibility. Unexpectedly, six species showed no effect and may be resistant. The hypothesis that harpacticoids could escape the effects of carbon dioxide-rich seawater by moving deeper into the seabed was not supported. Exposure to carbon dioxide-rich seawater created partially defaunated areas, but we found no evidence that disturbance-exploiting harpacticoid species invaded during the recovery of the affected area. Based on a detailed analysis of nematode biovolumes, we postulated that the nematode community in Monterey Canyon throughout the upper 3 cm suffered a high rate of mortality after exposure to CO2, and that nematodes were larger because postmortem expansions in body length and width occurred. Decomposition rates were probably low and corpses did not disintegrate in 30 days. The observable effects of a reduction in p

  11. Vegetation Response to Carbon Dioxide and Climate: Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Information related to vegetation response to carbon dioxide and climate includes: • Area and Carbon Content of Sphagnum Since Last Glacial Maximum (2002) (Trends Online) • TDE Model Intercomparison Project Data Archive • Presentations and abstracts from the recent DOE Terrestrial Science Team Meeting (Argonne National Laboratory, October 29-31, 2001) • FACE (Free-Air CO2 Enrichment) • Walker Branch Throughfall Displacement Experiment Data Report: Site Characterization, System Performance, Weather, Species Composition, and Growth (2001) • Bibliography on CO2 Effects on Vegetation and Ecosystems: 1990-1999 Literature (2000) • Direct effects of atmospheric CO2 enrichment on plants and ecosystems: An updated bibliographic data base (1994) • A Database of Herbaceous Vegetation Responses to Elevated Atmospheric CO2 (1999) • A Database of Woody Vegetation Responses to Elevated Atmospheric CO2 (1999) • Forest Responses to Anthropogenic Stress (FORAST) Database (1995) • Effects of CO2 and Nitrogen Fertilization on Growth and Nutrient Content of Juvenile Ponderosa Pine (1998) • Carbon Dioxide Enrichment: Data on the Response of Cotton to Varying CO2Irrigation, and Nitrogen (1992) • Growth and Chemical Responses to CO2 Enrichment Virginia Pine Pinus Virginiana Mill.(1985)

  12. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles This fact sheet describes a project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by Brayton Energy, aims to develop and demonstrate a low-cost, high-efficiency solar receiver that is compatible with s-CO2 cycles and modern thermal storage subsystems. Supercritical CO2 Brayton-cycle

  13. CO2 exposure at pressure impacts metabolism and stress responses in the model sulfate-reducing bacterium Desulfovibrio vulgaris strain Hildenborough

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Hoyt, David W.; Marshall, Matthew J.; Alderson, Paul A.; Plymale, Andrew E.; Markillie, Lye Meng; Tucker, Abigail E.; Walter, Eric D.; Linggi, Bryan E.; Dohnalkova, Alice; Taylor, Ronald C.

    2014-09-01

    Geologic carbon dioxide (CO2) sequestration drives physical and geochemical changes in deep subsurface environments that impact indigenous microbial activities. The combined effects of pressurized CO2 on a model sulfate-reducing microorganism, Desulfovibrio vulgaris, have been assessed using a suite of genomic and kinetic measurements. Novel high-pressure NMR time-series measurements using 13C-lactate were used to track D. vulgaris metabolism. We identified cessation of respiration at CO2 pressures of 10 bar, 25 bar, 50 bar, and 80 bar. Concurrent experiments using N2 as the pressurizing phase had no negative effect on microbial respiration, as inferred from reduction of sulfate to sulfide. Complementary pressurized batch incubations and fluorescence microscopy measurements supported NMR observations, and indicated that non-respiring cells were mostly viable at 50 bar CO2 for at least four hours, and at 80 bar CO2 for two hours. The fraction of dead cells increased rapidly after four hours at 80 bar CO2. Transcriptomic (RNA-Seq) measurements on mRNA transcripts from CO2-incubated biomass indicated that cells up-regulated the production of certain amino acids (leucine, isoleucine) following CO2 exposure at elevated pressures, likely as part of a general stress response. Evidence for other poorly understood stress responses were also identified within RNA-Seq data, suggesting that while pressurized CO2 severely limits the growth and respiration of D. vulgaris cells, biomass retains intact cell membranes at pressures up to 80 bar CO2. Together, these data show that geologic sequestration of CO2 may have significant impacts on rates of sulfate reduction in many deep subsurface environments where this metabolism is a key respiratory process.

  14. Carbon Dioxide (CO2) Capture Project Phase 2 (CCP2) - Storage...

    Open Energy Info (EERE)

    Clean Fossil Energy Topics: System & Application Design Website: www.sciencedirect.comscience?obMiamiImageURL&cid277910&user10& Equivalent URI: cleanenergysolutions.org...

  15. Comparative Reactivity Study of Forsterite and Antigorite in Wet Supercritical CO2 by In Situ Infrared Spectroscopy

    SciTech Connect (OSTI)

    Thompson, Christopher J.; Loring, John S.; Rosso, Kevin M.; Wang, Zheming

    2013-10-01

    The carbonation reactions of forsterite (Mg2SiO4) and antigorite [Mg3Si2O5(OH)4], representatives of olivine and serpentine minerals, in dry and wet supercritical carbon dioxide (scCO2) at conditions relevant to geologic carbon sequestration (35 C and 100 bar) were studied by in-situ Fourier transform infrared (FT-IR) spectroscopy. Our results confirm that water plays a critical role in the reactions between metal silicate minerals and scCO2. For neat scCO2, no reaction was observed in 24 hr for either mineral. When water was added to the scCO2, a thin water film formed on the minerals surfaces, and the reaction rates and extents increased as the water saturation level was raised from 54% to 116% (excess water). For the first time, the presence of bicarbonate, a key reaction intermediate for metal silicate reactions with scCO2, was observed in a heterogeneous system where mineral solids, an adsorbed water film, and bulk scCO2 co-exist. In excess-water experiments, approximately 4% of forsterite and less than 2% of antigorite transformed into hydrated Mg-carbonates. A precipitate similar to nesquehonite (MgCO33H2O) was observed for forsterite within 6 hr of reaction time, but no such precipitate was formed from antigorite until after water was removed from the scCO2 following a 24-hr reaction period. The reduced reactivity and carbonate-precipitation behavior of antigorite was attributed to slower, incongruent dissolution of the mineral and lower concentrations of Mg2+ and HCO3- in the water film. The in situ measurements employed in this work make it possible to quantify metal carbonate precipitates and key reaction intermediates such as bicarbonate for the investigation of carbonation reaction mechanisms relevant to geologic carbon sequestration.

  16. Large CO2 effluxes at night and during synoptic weather events significantly contribute to CO2 emissions from a reservoir

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Heping; Zhang, Qianyu; Katul, Gabriel G.; Cole, Jonathan J.; Chapin, III, F. Stuart; MacIntyre, Sally

    2016-05-24

    CO2 emissions from inland waters are commonly determined by indirect methods that are based on the product of a gas transfer coefficient and the concentration gradient at the air water interface (e.g., wind-based gas transfer models). The measurements of concentration gradient are typically collected during the day in fair weather throughout the course of a year. Direct measurements of eddy covariance CO2 fluxes from a large inland water body (Ross Barnett reservoir, Mississippi, USA) show that CO2 effluxes at night are approximately 70% greater than those during the day. At longer time scales, frequent synoptic weather events associated with extratropicalmore » cyclones induce CO2 flux pulses, resulting in further increase in annual CO2 effluxes by 16%. Therefore, CO2 emission rates from this reservoir, if these diel and synoptic processes are under-sampled, are likely to be underestimated by approximately 40%. Our results also indicate that the CO2 emission rates from global inland waters reported in the literature, when based on indirect methods, are likely underestimated. Field samplings and indirect modeling frameworks that estimate CO2 emissions should account for both daytime-nighttime efflux difference and enhanced emissions during synoptic weather events. Furthermore, the analysis here can guide carbon emission sampling to improve regional carbon estimates.« less

  17. CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents

    SciTech Connect (OSTI)

    2010-10-01

    IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.

  18. Combustion-Assisted CO2 Capture Using MECC Membranes

    SciTech Connect (OSTI)

    Sherman, Steven R; Gray, Dr. Joshua R.; Brinkman, Dr. Kyle S.; Huang, Dr. Kevin

    2012-01-01

    Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

  19. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  20. Geologic Carbon Dioxide Storage Field Projects Supported by DOE's

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sequestration Program | Department of Energy Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program Background: The U.S. DOE's Sequestration Program began with a small appropriation of $1M in 1997 and has grown to be the largest most comprehensive CCS R&D program in the world. The U.S. DOE's sequestration program has supported a number of projects implementing CO2

  1. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2012 NETL CO2 Capture Technology Meeting July 9 - 12, 2012 Proceedings of the 2012 NETL CO2 Capture Technology Meeting Table of Contents Presentations Monday, July 9 Opening/Overview Post-Combustion Membrane-Based Capture Post-Combustion Sorbent-Based Capture Tuesday, July 10 Post-Combustion Solvent-Based Capture Wednesday, July 11 Oxy-Combustion and Oxygen Production Chemical Looping Process CO2 Compression ARPA-e Capture Projects System Studies and Modeling Thursday, July 12 FutureGen 2.0,

  2. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  3. Potential effects of global atmospheric CO2 enrichment on the growth and competitiveness of C3 and C4 weed and crop plants

    SciTech Connect (OSTI)

    Patterson, D.T.; Flint, E.P.

    1980-01-01

    Research report: Mathematical growth analysis techniques were used to determine the effects of carbon dioxide on the growth and biomass partitioning in corn (zea mays), itchgrass (Rottbiellia exalata concentrations of 350 ppM, 600 ppM, and 1000 ppM were considered. Dry matter production in soybean and velvetleaf was increased significantly by raising the CO2 concentration above 350 ppM. Dry matter production in itchgrass was greatest at 600 ppM; CO2 levels did not affect dry matter production in corn. Weed growth with each plant at the various CO2 concentrations was also measured. CO2 enrichment increased weed growth in weeds planted with soybean and velvetleaf; weeds planted with corn and itchgrass did not experience any significant increase in growth. (18 references, 4 tables)

  4. ASPEN Plus Simulation of CO2 Recovery Process (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    GENERATION; PURIFICATION; SCRUBBING; COMPUTERIZED SIMULATION; A CODES; CARBON DIOXIDE; AIR POLLUTION CONTROL; MATERIALS RECOVERY Word Cloud More Like This Full Text preview...

  5. ASPEN Plus Simulation of CO2 Recovery Process (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    PURIFICATION; SCRUBBING; COMPUTERIZED SIMULATION; A CODES; CARBON DIOXIDE; AIR POLLUTION CONTROL; MATERIALS RECOVERY Word Cloud More Like This Full Text preview image File ...

  6. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 20 FOSSIL-FUELED POWER PLANTS; 54 ENVIRONMENTAL SCIENCES; POTASSIUM CARBONATES; CARBON DIOXIDE; MATERIALS RECOVERY; AMINES; SOLVENTS; MATERIALS TESTING; ...

  7. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    ... Language: English Subject: 20 FOSSIL-FUELED POWER PLANTS; 54 ENVIRONMENTAL SCIENCES; POTASSIUM CARBONATES; CARBON DIOXIDE; MATERIALS RECOVERY; AMINES; SOLVENTS; MATERIALS TESTING; ...

  8. CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE (Technical...

    Office of Scientific and Technical Information (OSTI)

    Subject: 54 ENVIRONMENTAL SCIENCES; CARBON DIOXIDE; ABSORPTION; ACID NEUTRALIZING CAPACITY; DESORPTION; POTASSIUM CARBONATES; AMINES; AIR POLLUTION CONTROL; FLUE GAS Word Cloud ...

  9. CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE (Technical...

    Office of Scientific and Technical Information (OSTI)

    Subject: 54 ENVIRONMENTAL SCIENCES; ABSORPTION; PERFORMANCE; POTASSIUM CARBONATES; CHEMICAL REACTION KINETICS; CARBON DIOXIDE; AIR POLLUTION CONTROL; AMINES Word Cloud More Like ...

  10. TECHNOLOGY IN AN INTEGRATED ASSESSMENT MODEL: THE POTENTIAL REGIONAL DEPLOYMENT OF CARBON CAPTURE AND STORAGE IN THE CONTEXT OF GLOBAL CO2 STABILIZATION

    SciTech Connect (OSTI)

    Edmonds, James A.; Dooley, James J.; Kim, Son H.; Friedman, S. Julio; Wise, Marshall A.

    2007-11-19

    Technology is a critically important determinant of the cost of meeting any environmental objective. In this paper we examine the role of a particular technology, carbon dioxide capture and storage (CCS), in the stabilization of the concentration of atmospheric carbon dioxide (CO2). While CCS is not presently deployed at scale, it has the potential to deploy extensively during the course of the 21st century if concentrations of atmospheric CO2 are to be stabilized. The existing research literature has focused largely on the cost of capturing CO2, with the implicit assumption that storage options would be relatively cheap, plentiful and located in close proximity to future CO2 point sources. However, CO2 capture and storage will take place at the local and regional scale and will compete with other mitigation options that also exhibit local or regional differences. This paper provides an initial examination of the implications of regionally disaggregated demand for and supply of CO2 storage reservoirs within the context of a globally disaggregated, long-term analysis of both the geology and economics of CCS. This analysis suggests that some regions will see their ability to deploy CCS systems constrained by a lack of quality target reservoirs relative to the demand for storage placed upon these candidate geologic storage reservoirs by large stationary CO2 point sources within the region. Other regions appear to have sufficient storage capacity to easily carry them into the 22nd century. We examined the regional and global economic implications of the distribution of these sources and sinks in meeting various potential limits to atmospheric CO2 concentrations. This analysis confirms that CCS is an important potential response to climate change throughout the 21st century and a technology that can play a key role in controlling the cost of addressing climate change.

  11. Electronic Structure, Phonon Dynamical Properties, and CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electronic Structure, Phonon Dynamical Properties, and CO2 Capture Capability of Na2-xMxZrO3 ( MLi ,K): Density-Functional Calculations and Experimental...

  12. Investigations of supercritical CO2 Rankine cycles for geothermal...

    Office of Scientific and Technical Information (OSTI)

    brayton cycle while lower efficiencies can be attained with the transcritical CO2 Rankine cycle. Authors: Sabau, Adrian S 1 ; Yin, Hebi 1 ; Qualls, A L 1 ; McFarlane,...

  13. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from...

    Office of Scientific and Technical Information (OSTI)

    on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. ... without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent ...

  14. Formation and Behavior of Composite CO2 Hydrate Particles in...

    Office of Scientific and Technical Information (OSTI)

    a High-Pressure Water Tunnel Facility Citation Details In-Document Search Title: Formation and Behavior of Composite CO2 Hydrate Particles in a High-Pressure Water Tunnel Facility ...

  15. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from mixtures of H2 and CO (or sometimes CO2) at elevated pressures (50 to 100 atm) and temperatures (450 to 600 K) using catalysts containing copper and zinc oxide. The...

  16. Co2 Deep Store Ltd | Open Energy Information

    Open Energy Info (EERE)

    Deep Store Ltd Jump to: navigation, search Name: Co2 Deep Store Ltd Place: Scotland, United Kingdom Zip: AB11 7LH Sector: Carbon Product: UK based organization focused on the...

  17. Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Svec, Robert K.

    2003-03-10

    The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

  18. CO2e Capital Limited | Open Energy Information

    Open Energy Info (EERE)

    e Capital Limited Jump to: navigation, search Name: CO2e Capital Limited Place: New York City, New York Zip: 10022 Product: New York based merchant bank focused on reducing global...

  19. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implementing CO2 capture in coal-fired power plants could result in almost a doubling of electricity prices for consumers. The researchers examined near-term market-viable ...

  20. Direct s-CO2 Reciever Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation was delivered at the SunShot Concentrating Solar Power ... High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 ...

  1. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (ceria) in contact with copper will form metal-oxide interfaces that allow the adsorption and activation of CO2, opening a new reaction pathway for the synthesis of methanol....

  2. NETL - World CO2 Emissions - Projected Trends Tool | Open Energy...

    Open Energy Info (EERE)

    to look at both total and power sector CO2 emissions from the use of coal, oil, or natural gas, over the period 1990 to 2030. One can use the tool to compare five of the larger...

  3. Plains CO2 Reduction Partnership PCOR | Open Energy Information

    Open Energy Info (EERE)

    Grand Forks, North Dakota Zip: 58202-9018 Product: North Dakota-based consortium researching CO2 storage options. PCOR is busy with the ECBM in the Unminable Lignite Research...

  4. Post-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing of LindeBASF Post-Combustion CO2 Capture Technology at the Abbott Coal-Fired Power Plant University of Illinois FE0026588 Phase 1 - Large pilot-scale (25 MWe) Large ...

  5. 2015 CO2 Capture Technology Meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Wednesday, June 24, 2015 POST-COMBUSTION SOLVENT-BASED CAPTURE An Advanced Catalytic Solvent for Lower Cost Post-Combustion CO2 Capture in a Coal Fired Power Plant Cameron Lippert, ...

  6. Secretary Chu Announces Six Projects to Convert Captured CO2...

    Energy Savers [EERE]

    ... CO2 from an industrial coal-fired source to produce biofuel and other high value co-products. ... Aggregates, Ltd. cement manufacturing plant in San Antonio, Texas. (DOE Share: ...

  7. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  8. Free Air CO2 Enrichment (FACE) Research Data from the Nevada Desert FACE Facility (NDFF)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    DOE has conducted trace gas enrichment experiments since the mid 1990s. The FACE Data Management System is a central repository and archive for Free-Air Carbon Dioxide Enrichment (FACE) data, as well as for the related open-top chamber (OTC) experiments. FACE Data Management System is located at the Carbon Dioxide Information Analysis Center (CDIAC). While the data from the various FACE sites, each one a unique user facility, are centralized at CDIAC, each of the FACE sites presents its own view of its activities and information. For that reason, DOE Data Explorer users are advised to see both the central repository at http://public.ornl.gov/face/index.shtml and the individual home pages of each site. NDFF whole-ecosystem manipulation is a flagship experiment of the Terrestrial Carbon Process (TCP) research program of the US Dept. of Energy. It is also a core project of the International Geosphere-Biosphere Program (IGBP) and a contribution to the US Global Change Research Program. The NDFF was developed in conjunction with the National Science Foundation (NSF) and DOE-EPSCoR programs. FACE (Free-Air-Carbon dioxide-Enrichment) technology allows researchers to elevate the carbon dioxide level in large study plots while minimizing ecosystem disturbance. At the NDFF the concentration of CO2 was elevated by 50 percent above the present atmospheric levels in three plots in the Mojave Desert ecosystem, while six other plots remained at the current level. This experimental design provided a large area in which integrated teams of scientists could describe and quantify processes regulating carbon, nutrient, and water balances in desert ecosystems.

  9. R & D Supercritiacl CO2/ Rock Chemicals Interactions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution / precipitation with spatial and temporal flow variations in CO 2 /brine/rock systems Principal Investigator: Martin Saar Department of Earth Sciences University of Minnesota Track Name: Resource Characterization, Modeling, Supercritical CO 2 / Rock Chemical Interactions Total Project Funding: $1,937,523 ($1,550,018 from DOE-GTP) This presentation does not

  10. CO2 Removal using a Synthetic Analogue of Carbonic Anhydrase

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-09-14

    Project attempts to develop a synthetic analogue for carbonic anhydrase and incorporate it in a membrane for separation of CO2 from coal power plant flue gas. Conference poster presents result of first 9 months of project progress including concept, basic system architecture and membrane properties target, results of molecular modeling for analogue - CO2 interaction, and next steps of testing analogue resistance to flue gas contaminants.

  11. Regenerable Sorbent Technique for Capturing CO2 Using Immobilized Amine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorbents - Energy Innovation Portal Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Regenerable Sorbent Technique for Capturing CO2 Using Immobilized Amine Sorbents The BIAS (Basic Immobilized Amine Sorbent) Process National Energy Technology Laboratory Contact NETL About This Technology Technology Marketing Summary This technology allows for optimal CO2 removal capacity for a given absorption and regeneration reactor

  12. Reversible Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Yonker, Clement R.; Rainbolt, James E.; Zheng, Feng

    2010-08-31

    Acid gas scrubbing technology is predominantly aqueous alkanolamine based. Of the acid gases, CO2, H2S and SO2 have been shown to be reversible, however there are serious disadvantages with corrosion and high regeneration costs. The primary scrubbing system composed of monoethanolamine is limited to 30% by weight because of the highly corrosive solution. This gravimetric limitation limits the CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the system. Furthermore the scrubbing system has a large energy penalty from pumping and heating the excess water required to dissolve the MEA bicarbonate salt. Considering the high specific heat of water (4 j/g-1K-1), low capacities and the high corrosion we set out to design a fully organic solvent that can chemically bind all acid gases i.e. CO2 as reversible alkylcarbonate ionic liquids or analogues thereof. Having a liquid acid gas carrier improves process economics because there is no need for excess solvent to pump and to heat. We have demonstrated illustrated in Figure 1, that CO2-binding organic liquids (CO2BOLs) have a high CO2 solubility paired with a much lower specific heat (<1.5 J/g-1K-1) than aqueous systems. CO2BOLs are a subsection of a larger class of materials known as Binding Organic Liquids (BOLs). Our BOLs have been shown to reversibly bind and release COS, CS2, and SO2, which we denote COSBOLS, CS2BOLs and SO2BOLs. Our BOLs are highly tunable and can be designed for post or pre-combustion gas capture. The design and testing of the next generation zwitterionic CO2BOLs and SO2BOLs are presented.

  13. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  14. SULPHUR DIOXIDE LEACHING OF URANIUM CONTAINING MATERIAL

    DOE Patents [OSTI]

    Thunaes, A.; Rabbits, F.T.; Hester, K.D.; Smith, H.W.

    1958-12-01

    A process is described for extracting uranlum from uranium containing material, such as a low grade pitchblende ore, or mill taillngs, where at least part of the uraniunn is in the +4 oxidation state. After comminuting and magnetically removing any entrained lron particles the general material is made up as an aqueous slurry containing added ferric and manganese salts and treated with sulfur dioxide and aeration to an extent sufficient to form a proportion of oxysulfur acids to give a pH of about 1 to 2 but insufficient to cause excessive removal of the sulfur dioxide gas. After separating from the solids, the leach solution is adjusted to a pH of about 1.25, then treated with metallic iron in the presence of a precipitant such as a soluble phosphate, arsonate, or fluoride.

  15. Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture

    SciTech Connect (OSTI)

    Vahdat, Nader

    2013-09-30

    The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project team’s approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

  16. SANS Investigations of CO2 Adsorption in Microporous Carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bahadur, Jitendra; Melnichenko, Yuri B.; He, Lilin; Contescu, Cristian I.; Gallego, Nidia C.; Carmichael, Justin R.

    2015-08-07

    The high pressure adsorption behavior of CO2 at T = 296 K in microporous carbon was investigated by small-angle neutron scattering (SANS) technique. A strong densification of CO2 in micropores accompanied by non-monotonic adsorption-induced pore deformation was observed. The density of confined CO2 increases rapidly with pressure and reaches the liquid –like density at 20 bar, which corresponds to the relative pressure of P/Psat ~0.3. At P > 20 bar density of confined CO2 increases slowly approaching a plateau at higher pressure. The size of micropores first increases with pressure, reaches a maximum at 20 bar,more » and then decreases with pressure. A complementary SANS experiment conducted on the same microporous carbon saturated with neutron-transparent and non-adsorbing inert gas argon shows no deformation of micropores at pressures up to ~200 bars. This result demonstrates that the observed deformation of micropores in CO2 is an adsorption-induced phenomenon, caused by the solvation pressure - induced strain and strong densification of confined CO2 .« less

  17. Evaluating Impacts of CO2 and CH4 Gas Intrusion into an Unconsolidated Aquifer: Fate of As and Cd

    SciTech Connect (OSTI)

    Lawter, Amanda R.; Qafoku, Nikolla; Shao, Hongbo; Bacon, Diana H.; Brown, Christopher F.

    2015-07-10

    Abstract The sequestration of carbon dioxide (CO2) in deep underground reservoirs has been identified as an important strategy to decrease atmospheric CO2 levels and mitigate global warming, but potential risks on overlying aquifers currently lack a complete evaluation. In addition to CO2, other gases such as methane (CH4) may be present in storage reservoirs. This paper explores for the first time the combined effect of leaking CO2 and CH4 gasses on the fate of major, minor and trace elements in an aquifer overlying a potential sequestration site. Emphasis is placed on the fate of arsenic (As) and cadmium (Cd) released from the sediments or present as soluble constituents in the leaking brine. Results from macroscopic batch and column experiments show that the presence of CH4 (at a concentration of 1 % in the mixture CO2/CH4) does not have a significant effect on solution pH or the concentrations of most major elements (such as Ca, Ba, and Mg). However, the concentrations of Mn, Mo, Si and Na are inconsistently affected by the presence of CH4 (i.e., in at least one sediment tested in this study). Cd is not released from the sediments and spiked Cd is mostly removed from the aqueous phase most likely via adsorption. The fate of sediment associated As [mainly sorbed arsenite or As(III) in minerals] and spiked As [i.e., As5+] is complex. Possible mechanisms that control the As behavior in this system are discussed in this paper. Results are significant for CO2 sequestration risk evaluation and site selection and demonstrate the importance of evaluating reservoir brine and gas stream composition during site selection to ensure the safest site is being chosen.

  18. Assessment of model estimates of land-atmosphere CO2 exchange across Northern Eurasia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rawlins, M. A.; McGuire, A. D.; Kimball, J. S.; Dass, P.; Lawrence, D.; Burke, E.; Chen, X.; Delire, C.; Koven, C.; MacDougall, A.; et al

    2015-07-28

    A warming climate is altering land-atmosphere exchanges of carbon, with a potential for increased vegetation productivity as well as the mobilization of permafrost soil carbon stores. Here we investigate land-atmosphere carbon dioxide (CO2) cycling through analysis of net ecosystem productivity (NEP) and its component fluxes of gross primary productivity (GPP) and ecosystem respiration (ER) and soil carbon residence time, simulated by a set of land surface models (LSMs) over a region spanning the drainage basin of Northern Eurasia. The retrospective simulations cover the period 1960–2009 at 0.5° resolution, which is a scale common among many global carbon and climate modelmore » simulations. Model performance benchmarks were drawn from comparisons against both observed CO2 fluxes derived from site-based eddy covariance measurements as well as regional-scale GPP estimates based on satellite remote-sensing data. The site-based comparisons depict a tendency for overestimates in GPP and ER for several of the models, particularly at the two sites to the south. For several models the spatial pattern in GPP explains less than half the variance in the MODIS MOD17 GPP product. Across the models NEP increases by as little as 0.01 to as much as 0.79 g C m⁻² yr⁻², equivalent to 3 to 340 % of the respective model means, over the analysis period. For the multimodel average the increase is 135 % of the mean from the first to last 10 years of record (1960–1969 vs. 2000–2009), with a weakening CO2 sink over the latter decades. Vegetation net primary productivity increased by 8 to 30 % from the first to last 10 years, contributing to soil carbon storage gains. The range in regional mean NEP among the group is twice the multimodel mean, indicative of the uncertainty in CO2 sink strength. The models simulate that inputs to the soil carbon pool exceeded losses, resulting in a net soil carbon gain amid a decrease in residence time. Our analysis points to improvements in

  19. Subtask 2.6 - Assessment of Alternative Fuels on CO2 Production

    SciTech Connect (OSTI)

    Debra Pflughoeft-Hassett; Darren Naasz

    2009-06-16

    Many coal-based electric generating units use alternative fuels, and this effort assessed the impact of alternative fuels on CO{sub 2} production and other emissions and also assessed the potential impact of changes in emission regulations under the Clean Air Act (CAA) for facilities utilizing alternative fuels that may be categorized as wastes. Information was assembled from publicly available U.S. Department of Energy Energy Information Administration databases that included alternative fuel use for 2004 and 2005. Alternative fuel types were categorized along with information on usage by coal-based electric, number of facilities utilizing each fuel type, and the heating value of solid, liquid, and gaseous alternative fuels. The sulfur dioxide, nitrogen oxide, and carbon dioxide emissions associated with alternative fuels and primary fuels were also evaluated. Carbon dioxide emissions are also associated with the transport of all fuels. A calculation of carbon dioxide emissions associated with the transport of biomass-based fuels that are typically accessed on a regional basis was made. A review of CAA emission regulations for coal-based electric generating facilities from Section 112 (1) and Section 129 (2) for solid waste incinerators was performed with consideration for a potential regulatory change from Section 112 (1) regulation to Section 129 (2). Increased emission controls would be expected to be required if coal-based electric generating facilities using alternative fuels would be recategorized under CAA Section 129 (2) for solid waste incinerators, and if this change were made, it is anticipated that coal-fired electric generating facilities might reduce the use of alternative fuels. Conclusions included information on the use profile for alternative fuels and the impacts to emissions as well as the impact of potential application of emission regulations for solid waste incinerators to electric generating facilities using alternative fuels.

  20. Investigation of the carbon dioxide sorption capacity and structural deformation of coal

    SciTech Connect (OSTI)

    Hur, Tae-Bong; Fazio, James; Romanov, Vyacheslav; Harbert, William

    2010-01-01

    Due to increasing atmospheric CO2 concentrations causing the global energy and environmental crises, geological sequestration of carbon dioxide is now being actively considered as an attractive option to mitigate greenhouse gas emissions. One of the important strategies is to use deep unminable coal seams, for those generally contain significant quantities of coal bed methane that can be recovered by CO2 injection through enhanced coal bed natural gas production, as a method to safely store CO2. It has been well known that the adsorbing CO2 molecules introduce structural deformation, such as distortion, shrinkage, or swelling, of the adsorbent of coal organic matrix. The accurate investigations of CO2 sorption capacity as well as of adsorption behavior need to be performed under the conditions that coals deform. The U.S. Department of Energy-National Energy Technology Laboratory and Regional University Alliance are conducting carbon dioxide sorption isotherm experiments by using manometric analysis method for estimation of CO2 sorption capacity of various coal samples and are constructing a gravimetric apparatus which has a visual window cell. The gravimetric apparatus improves the accuracy of carbon dioxide sorption capacity and provides feasibility for the observation of structural deformation of coal sample while carbon dioxide molecules interact with coal organic matrix. The CO2 sorption isotherm measurements have been conducted for moist and dried samples of the Central Appalachian Basin (Russell County, VA) coal seam, received from the SECARB partnership, at the temperature of 55 C.

  1. Synthetic fuel concept to steal CO2 from air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concept, called Green Freedom(tm), for large-scale production of carbon-neutral, sulfur-free fuels and organic chemicals from air and water. February 12, 2008 Los Alamos National...

  2. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect (OSTI)

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  3. Evaluating the impact of aquifer layer properties on geomechanical response during CO2 geological sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Lin, Guang; Fang, Yilin

    2013-04-01

    Numerical models play an essential role in understanding the facts of carbon dioxide (CO2) geological sequestration in the life cycle of a storage reservoir. We present a series of test cases that reflect a broad and realistic range of aquifer reservoir properties to systematically evaluate and compare the impacts on the geomechanical response to CO2 injection. In this study, a coupled hydro-mechanical model was introduced to simulate the sequestration process, and a quasi-Monte Carlo sampling method was introduced to efficiently sample the value of aquifer properties and geometry parameters. Aquifer permeability was found to be of significant importance to the geomechanical response to the injection. To study the influence of uncertainty of the permeability distribution in the aquifer, an additional series of tests is presented, based on a default permeability distribution site sample with various distribution deviations generated by the Monte Carlo sampling method. The results of the test series show that different permeability distributions significantly affect the displacement and possible failure zone.

  4. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  5. High Fidelity Computational Analysis of CO2 Trapping at Pore Scales

    SciTech Connect (OSTI)

    Kumar, Vinod

    2013-07-13

    With an alarming rise in carbon dioxide (CO2) emission from anthropogenic sources, CO2 sequestration has become an attractive choice to mitigate the emission. Some popular storage media for CO{sub 2} are oil reservoirs, deep coal-bed, and deep oceanic-beds. These have been used for the long term CO{sub 2} storage. Due to special lowering viscosity and surface tension property of CO{sub 2}, it has been widely used for enhanced oil recovery. The sites for CO{sub 2} sequestration or enhanced oil recovery mostly consist of porous rocks. Lack of knowledge of molecular mobility under confinement and molecule-surface interactions between CO2 and natural porous media results in generally governed by unpredictable absorption kinetics and total absorption capacity for injected fluids, and therefore, constitutes barriers to the deployment of this technology. Therefore, it is important to understand the flow dynamics of CO{sub 2} through the porous microstructures at the finest scale (pore-scale) to accurately predict the storage potential and long-term dynamics of the sequestered CO{sub 2}. This report discusses about pore-network flow modeling approach using variational method and analyzes simulated results this method simulations at pore-scales for idealized network and using Berea Sandstone CT scanned images. Variational method provides a promising way to study the kinetic behavior and storage potential at the pore scale in the presence of other phases. The current study validates variational solutions for single and two-phase Newtonian and single phase non-Newtonian flow through angular pores for special geometries whose analytical and/or empirical solutions are known. The hydraulic conductance for single phase flow through a triangular duct was also validated against empirical results derived from lubricant theory.

  6. Identification of Fragile Microscopic Structures during Mineral Transformations in Wet Supercritical CO2

    SciTech Connect (OSTI)

    Arey, Bruce W.; Kovarik, Libor; Qafoku, Odeta; Wang, Zheming; Hess, Nancy J.; Felmy, Andrew R.

    2013-04-01

    In this study we examine the nature of highly fragile reaction products that form in low water content super critical carbon dioxide (scCO2) using a combination of scanning electron microscopy/focus ion beam (SEM/FIB), confocal Raman spectroscopy, helium ion microscopy (HeIM), and transmission electron microscopy (TEM). HeIM images show these precipitates to be fragile rosettes that can readily decompose even under slight heating from an electron beam. Using the TEM revealed details on the interfacial structure between the newly formed surface precipitates and the underlying initial solid phases. The detailed microscopic analysis revealed that the growth of the precipitates either followed a tip growth mechanism with precipitates forming directly on the forsterite surface if the initial solid was non-porous (natural forsterite) or growth from the surface of the precipitates where fluid was conducted through the porous (nanoforsterite) agglomerates to the growth center. The mechanism of formation of the hydrated/hydroxylated magnesium carbonate compound (HHMC) phases offers insight into the possible mechanisms of carbonate mineral formation from scCO2 solutions which has recently received a great deal of attention as the result of the potential for CO2 to act as an atmospheric greenhouse gas and impact overall global warming. The techniques used here to examine these fragile structures an also be used to examine a wide range of fragile material surfaces. SEM and FIB technologies have now been brought together in a single instrument, which represents a powerful combination for the studies in biological, geological and materials science.

  7. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect (OSTI)

    Davis, K.J.; Richardson, S.J.; Miles, N.L.

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are

  8. Final Report- High-Efficiency Low-Cost Solar Receiver for use in a Supercritical CO2 Recompression Cycle

    Office of Energy Efficiency and Renewable Energy (EERE)

    This project has performed solar receiver designs for two supercritical carbon dioxide (sCO2) power cycles. The first half of the program focused on a nominally 2 MWe power cycle, with a receiver designed for test at the Sandia Solar Thermal Test Facility. This led to an economical cavity-type receiver. The second half of the program focused on a 10 MWe power cycle, incorporating a surround open receiver. Rigorous component life and performance testing was performed in support of both receiver designs. The receiver performance objectives are set to conform to the US DOE goals of 6¢/kWh by 2020.

  9. Recovery and Sequestration of CO2 from Stationary Combustion Systems by Photosynthesis of Microalgae

    SciTech Connect (OSTI)

    T. Nakamura; C.L. Senior

    2005-04-01

    Most of the anthropogenic emissions of carbon dioxide result from the combustion of fossil fuels for energy production. Photosynthesis has long been recognized as a means, at least in theory, to sequester anthropogenic carbon dioxide. Aquatic microalgae have been identified as fast growing species whose carbon fixing rates are higher than those of land-based plants by one order of magnitude. Physical Sciences Inc. (PSI), Aquasearch, and the Hawaii Natural Energy Institute at the University of Hawaii are jointly developing technologies for recovery and sequestration of CO{sub 2} from stationary combustion systems by photosynthesis of microalgae. The research is aimed primarily at demonstrating the ability of selected species of microalgae to effectively fix carbon from typical power plant exhaust gases. This report covers the reporting period 1 October 2000 to 31 March 2005 in which PSI, Aquasearch and University of Hawaii conducted their tasks. This report discusses results of the work pertaining to five tasks: Task 1--Supply of CO2 from Power Plant Flue Gas to Photobioreactor; Task 2--Selection of Microalgae; Task 3--Optimization and Demonstration of Industrial Scale Photobioreactor; Task 4--Carbon Sequestration System Design; and Task 5--Economic Analysis. Based on the work conducted in each task summary conclusion is presented.

  10. Illinois CO2 Injection Project Moves Another Step Forward

    Broader source: Energy.gov [DOE]

    The recent completion of a three-dimensional (3-D) seismic survey at a large Illinois carbon dioxide injection test site is an important step forward for the carbon capture and storage project's planned early 2011 startup.

  11. 43029CO2Prod | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Background Carbon dioxide-enhanced oil recovery is a well-established method for increasing oil recovery from the Permian Basin oilfields of Texas and New Mexico and from the ...

  12. ARM - Field Campaign - Boundary Layer CO2 Using CW Lidar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBoundary Layer CO2 Using CW Lidar Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Boundary Layer CO2 Using CW Lidar 2005.05.21 - 2005.05.24 Lead Scientist : Michael Dobbs Abstract Overflights Underway at ACRF Southern Great Plains Site (M.Dobbs/J.Liljegren) Science collaborators at ITT Industries and the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) conducted flights over the Central

  13. Watch Our CO2 Drop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Our CO2 Drop Watch Our CO2 Drop January 14, 2016 - 4:55pm Addthis Daniel Wood Daniel Wood Data Visualization and Cartographic Specialist, Office of Public Affairs Learn More About Climate Change If you want to learn more about the importance of reducing our carbon pollution, read our recent report about how climate change threatens our energy infrastructure. Curious about the total amount of carbon we emit into the atmosphere? Compare countries from around the globe using this tool. On Tuesday,

  14. Near-Infrared Spectroscopic Investigation of Water in Supercritical CO2 and the Effect of CaCl2

    SciTech Connect (OSTI)

    Wang, Zheming; Felmy, Andrew R.; Thompson, Christopher J.; Loring, John S.; Joly, Alan G.; Rosso, Kevin M.; Schaef, Herbert T.; Dixon, David A.

    2013-01-25

    Near-infrared (NIR) spectroscopy was applied to investigate the dissolution and chemical interaction of water dissolved into supercritical carbon dioxide (scCO2) and the influence of CaCl2 in the co-existing aqueous phase at fo empe e : 40 50 75 nd 100 C at 90 atm. Consistent with the trend of the vapor pressure of water, the solubility of pure water in scCO2 inc e ed f om 40 ?C (0.32 mole%) o 100 ?C (1.61 mole%). The presence of CaCl2 negatively affects the solubility of water in scCO2: at a given temperature and pressure the solubility of water decreased as the concentration of CaCl2 in the aqueous phase increased, following the trend of the activity of water. A 40 ?C, the water concentration in scCO2 in contact with saturated CaCl2 aqueous solution was only 0.16 mole%, a drop of more than 50% as compared to pure water while that a 100 ?C was 1.12 mole%, a drop of over 30% as compared to pure water, under otherwise the same conditions. Analysis of the spectral profiles suggested that water dissolved into scCO2 exists in the monomeric form under the evaluated temperature and pressure conditions, for both neat water and CaCl2 solutions. However, its rotational degrees of freedom decrease at lower temperatures due to higher fluid densities, leading to formation of weak H2O:CO2 Lewis acid-base complexes. Similarly, the nearly invariant spectral profiles of dissolved water in the presence and absence of saturated CaCl2 under the same experimental conditions was taken as evidence that CaCl2 dissolution in scCO2 was limited as the dissolved Ca2+/CaCl2 would likely be highly hydrated and would alter the overall spectra of waters in the scCO2 phase.

  15. Single-well Low Temperature CO2- based Engineered Geothemal System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based ...

  16. Six-Week Time Series Of Eddy Covariance CO2 Flux At Mammoth Mountain...

    Open Energy Info (EERE)

    high, spatially heterogeneous CO2 emission rates. EC CO2 fluxes ranged from 218 to 3500 g m- 2 d- 1 (mean 1346 g m- 2 d- 1). Using footprint modeling, EC CO2 fluxes were...

  17. Inexpensive CO2 Thickening Agents for Improved Mobility Control of CO2 Floods

    SciTech Connect (OSTI)

    Robert Enick; Eric Beckman; Andrew Hamilton

    2005-08-31

    The objective of this research was the design, synthesis and evaluation of inexpensive, non-fluorous carbon dioxide thickening agents. We followed the same strategy employed in the design of fluorinated CO{sub 2} polymeric thickeners. First, a highly CO{sub 2}-philic, hydrocarbon-based monomer was to be identified. Polymers or oligomers of this monomer were then synthesized. The second step was to design a CO{sub 2}-thickener based on these CO{sub 2}-philic polymers. Two types of thickeners were considered. The first was a copolymer in which the CO{sub 2}-philic monomer was combined with a small proportion of CO{sub 2}-phobic associating groups that could cause viscosity-enhancing intermolecular interactions to occur. The second was a small hydrogen-bonding compound with urea groups in the core to promote intermolecular interactions that would cause the molecules to 'stack' in solution while the arms were composed of the CO{sub 2}-philic oligomers. Although we were not able to develop a viable thickener that exhibited high enough CO{sub 2} solubility at EOR MMP conditions to induce a viscosity increase, we made significant progress in our understanding of CO{sub 2}-soluble compounds that can be used in subsequent studies to design CO{sub 2}-soluble thickeners or CO{sub 2}-soluble surfactant-based foaming agents. These findings are detailed in this final report. In summary, we assessed many polymers and verified that the most CO{sub 2}-soluble oxygenated hydrocarbon polymer is poly(vinyl acetate), PVAc. This is primarily due to the presence of both ether and carbonyl oxygens associated with acetate-rich compounds. In addition to polymers, we also made small acetate-rich molecules that were also capable of associating in solution via the inclusion of hydrogen-bonding groups in hopes of forming viscosity-enhancing macromolecules. Despite the presence of multiple acetate groups in these compounds, which can impart incredible CO{sub 2}-solubility to many compounds, our

  18. Modeling and Evaluation of Geophysical Methods for Monitoring and Tracking CO2 Migration

    SciTech Connect (OSTI)

    Daniels, Jeff

    2012-11-30

    Geological sequestration has been proposed as a viable option for mitigating the vast amount of CO{sub 2} being released into the atmosphere daily. Test sites for CO{sub 2} injection have been appearing across the world to ascertain the feasibility of capturing and sequestering carbon dioxide. A major concern with full scale implementation is monitoring and verifying the permanence of injected CO{sub 2}. Geophysical methods, an exploration industry standard, are non-invasive imaging techniques that can be implemented to address that concern. Geophysical methods, seismic and electromagnetic, play a crucial role in monitoring the subsurface pre- and post-injection. Seismic techniques have been the most popular but electromagnetic methods are gaining interest. The primary goal of this project was to develop a new geophysical tool, a software program called GphyzCO2, to investigate the implementation of geophysical monitoring for detecting injected CO{sub 2} at test sites. The GphyzCO2 software consists of interconnected programs that encompass well logging, seismic, and electromagnetic methods. The software enables users to design and execute 3D surface-to-surface (conventional surface seismic) and borehole-to-borehole (cross-hole seismic and electromagnetic methods) numerical modeling surveys. The generalized flow of the program begins with building a complex 3D subsurface geological model, assigning properties to the models that mimic a potential CO{sub 2} injection site, numerically forward model a geophysical survey, and analyze the results. A test site located in Warren County, Ohio was selected as the test site for the full implementation of GphyzCO2. Specific interest was placed on a potential reservoir target, the Mount Simon Sandstone, and cap rock, the Eau Claire Formation. Analysis of the test site included well log data, physical property measurements (porosity), core sample resistivity measurements, calculating electrical permittivity values, seismic data

  19. Bacterial Sulfur Storage Globules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for...

  20. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  1. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    E.; Wang, Yifeng; Matteo, Edward N.; Meserole, Stephen P.; Tallant, David Robert In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration,...

  2. Impact of mesophyll diffusion on estimated global land CO2 fertilizati...

    Office of Scientific and Technical Information (OSTI)

    Impact of mesophyll diffusion on estimated global land CO2 fertilization Citation Details In-Document Search Title: Impact of mesophyll diffusion on estimated global land CO2 ...

  3. Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate CO2 ... Sponsoring Org: USDOE Office of Science (SC) Country of Publication: United States ...

  4. Near-Surface Co2 Monitoring And Analysis To Detect Hidden Geothermal...

    Open Energy Info (EERE)

    at dispersing CO2 seepage. In natural ecological systems in the absence of geothermal gas emissions, near-surface CO2 fluxes and concentrations are predominantly controlled by...

  5. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration, ... Experimental and theoretical studies have shown that water films will form on mineral ...

  6. CO2-selective, Hybrid Membranes by Silation of Alumina

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.

    2007-09-01

    Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of γ-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of “CO2-phillic” groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated γ-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin “polymer-like” surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

  7. Two-phase convective CO2 dissolution in saline aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlyingmore » two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.« less

  8. Natural CO2 accumulations in the western Williston Basin: A mineralogical analog for CO2 injection at the Weyburn site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryerson, F. J.; Lake, John; Whittaker, Steven; Johnson, James W.

    2013-01-17

    The Devonian carbonates of the Duperow Formation on the western flank of the Williston Basin in southwest Saskatchewan contain natural accumulations of CO2, and may have done so for as long as 50 million years. These carbonate sediments are characterized by a succession of carbonate cycles capped by anhydrite-rich evaporites that are thought to act as seals to fluid migration. The Weyburn CO2 injection site lies 400 km to the east in a series of Mississippian carbonates that were deposited in a similar depositional environment. That long-term isolation of natural CO2 can be accomplished within carbonate strata has motivated themore » investigation of the Duperow rocks as a potential natural analog for storage of anthropogenic CO2 in carbonate lithologies. For the Duperow strata to represent a legitimate analog for Midale injection and storage, the similarity in lithofacies, whole rock compositions, mineral compositions and porosity with the Midale Beds must be established. Here we compare lithofacies, whole rock compositions, mineralogy and mineral compositions from both locales. The major mineral phases at both locales are calcite, dolomite and anhydrite. In addition, accessory pyrite, fluorite, quartz and celestine (strontium sulfate) are also observed. Dawsonite, a potential CO2-trapping mineral, is not observed within the CO2-bearing horizons of the Duperow Formation, however. The distribution of porosity in the Midale Vuggy units is similar to that of the Duperow Formation, but the Marly units of the Midale have significantly higher porosity. The Duperow Formation is topped by the Dinesmore evaporite that is rich in anhydrite, and often contains authigenic K-feldspar. The chemistry of dolomite and calcite from the two localities also overlaps. Silicate minerals are in low abundance (<3%) within the analyzed Duperow samples, with quartz and K-feldspar the only silicates observed petrographically or in X-ray diffraction patterns. The Midale Beds contain

  9. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Liu, Wei

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  10. FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

    2008-09-01

    This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced

  11. Device and method for detecting sulfur dioxide at high temperatures

    DOE Patents [OSTI]

    West, David L.; Montgomery, Frederick C.; Armstrong, Timothy R.

    2011-11-01

    The present invention relates to a method for selectively detecting and/or measuring gaseous SO.sub.2 at a temperature of at least 500.degree. C., the method involving: (i) providing a SO.sub.2-detecting device including an oxygen ion-conducting substrate having on its surface at least three electrodes comprising a first, second, and third electrode; (ii) driving a starting current of specified magnitude and temporal variation between the first and second electrodes; (iii) contacting the SO.sub.2-detecting device with the SO.sub.2-containing sample while maintaining the magnitude and any temporal variation of the starting current, wherein said SO.sub.2-containing sample causes a change in the electrical conductance of said device; and (iv) detecting the change in electrical conductance of the device based on measuring an electrical property related to or indicative of the conductance of the device between the first and third electrodes, or between the second and third electrodes, and detecting SO.sub.2 in the SO.sub.2-containing sample based on the measured change in electrical conductance.

  12. CO2-fluxing collapses metal mobility in magmatic vapour

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van Hinsberg, V. J.; Berlo, K.; Migdisov, A. A.; Williams-Jones, A. E.

    2016-05-18

    Magmatic systems host many types of ore deposits, including world-class deposits of copper and gold. Magmas are commonly an important source of metals and ore-forming fluids in these systems. In many magmatic-hydrothermal systems, low-density aqueous fluids, or vapours, are significant metal carriers. Such vapours are water-dominated shallowly, but fluxing of CO2-rich vapour exsolved from deeper magma is now recognised as ubiquitous during open-system magma degassing. Furthermore, we show that such CO2-fluxing leads to a sharp drop in element solubility, up to a factor of 10,000 for Cu, and thereby provides a highly efficient, but as yet unrecognised mechanism for metalmore » deposition.« less

  13. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    SciTech Connect (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The software can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.

  14. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    Energy Science and Technology Software Center (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The softwaremore » can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.« less

  15. Sodium-sulfur thermal battery

    SciTech Connect (OSTI)

    Ludwig, F.A.

    1990-12-11

    This paper discusses a sodium-sulfur thermal battery for generating electrical energy at temperatures above the melting point of sodium metal and sulfur. It comprises a sodium electrode comprising sodium metal; a sulfur electrode comprising sulfur; and a separator located between the sodium and sulfur electrodes. The separator having sufficient porosity to allow preliminary migration of fluid sodium metal and fluid sulfur and fluid sodium polysulfides therethrough during operation of the thermal battery to form a mixed polysulfides electrolyte gradient within the separator.

  16. Biomass Energy for Transport and Electricity: Large scale utilization under low CO2 concentration scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-01-25

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to stabilize atmospheric concentrations of CO2 at 400ppm and 450ppm. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. The costs of processing and transporting biomass energy at much larger scales than current experience are also incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the dominant source. A key finding of this paper is the role that carbon dioxide capture and storage (CCS) technologies coupled with commercial biomass energy can play in meeting stringent emissions targets. Despite the higher technology costs of CCS, the resulting negative emissions used in combination with biomass are a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels and shows that both technologies are important contributors to liquid fuels production, with unique costs and emissions characteristics. Through application of the GCAM integrated assessment model, it becomes clear that, given CCS availability, bioenergy will be used both in electricity and transportation.

  17. An Evaluation of the Feasibility of Combining Carbon Dioxide Flooding Technologies with Microbial Enhanced Oil Recovery Technologies in Order To Sequester Carbon Dioxide

    SciTech Connect (OSTI)

    Todd French; Lew Brown; Rafael Hernandez; Magan Green; Lynn Prewitt; Terry Coggins

    2009-08-19

    The need for more energy as our population grows results in an increase in the amount of CO2 introduced into the atmosphere. The effect of this introduction is currently debated intensely as to the severity of the effect of this. The bjective of this investigation was to determine if the production of more energy (i.e. petroleum) and the sequestration of CO2 could be coupled into one process. Carbon dioxide flooding is a well-established technique that introduces Compressed CO2 into a subsurface oil-bearing formation to aide in liquefying harder to extract petroleum and enhancing its mobility towards the production wells.

  18. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  19. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers

    Broader source: Energy.gov [DOE]

    This fact sheet describes a supercritical carbon dioxide turbo-expander and heat exchangers project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Southwest Research Institute, is working to develop a megawatt-scale s-CO2 hot-gas turbo-expander optimized for the highly transient solar power plant profile. The team is also working to optimize novel printed circuit heat exchangers for s-CO2 applications to drastically reduce their manufacturing costs.

  20. A Review of Major Non-Power-Related Carbon Dioxide Stream Compositions

    SciTech Connect (OSTI)

    Last, George V.; Schmick, Mary T.

    2015-07-01

    A critical component in the assessment of long-term risk from geologic sequestration of carbon dioxide (CO2) is the ability to predict mineralogical and geochemical changes within storage reservoirs as a result of rock-brine-CO2 reactions. Impurities and/or other constituents in CO2 source streams selected for sequestration can affect both the chemical and physical (e.g., density, viscosity, interfacial tension) properties of CO2 in the deep subsurface. The nature and concentrations of these impurities are a function of both the industrial source(s) of CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for subsurface injection and geologic sequestration. This article reviews the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy-related industrial sources of CO2. Assuming that carbon capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, the authors then summarize the relative proportions of the remaining impurities assumed to be present in CO2 source streams that could be targeted for geologic sequestration. The summary is presented relative to five potential sources of CO2: 1) Flue Gas with Flue Gas Desulfurization, 2) Combustion Stack from Coke Production, 3) Portland Cement Kilns, 4) Natural Gas Combustion, and 5) Lime Production.

  1. A preliminary sub-basin scale evaluation framework of site suitability for onshore aquifer-based CO2 storage in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Wang, Ying; Dahowski, Robert T.; Davidson, Casie L.; Bromhal, Grant

    2013-01-30

    Development of a reliable, broadly applicable framework for the identification and suitability evaluation of potential CO2 storage sites is essential before large scale deployment of carbon dioxide capture and geological storage (CCS) can commence. In this study, a sub-basin scale evaluation framework was developed to assess the suitability of potential onshore deep saline aquifers for CO2 storage in China. The methodology, developed in consultation with experts from the academia and the petroleum industry in China, is based on a multi-criteria analysis (MCA) framework that considers four objectives: (1) storage optimization, in terms of storage capacity and injectivity; (2) risk minimization and storage security; (3) environmental restrictions regarding surface and subsurface use; and (4) economic considerations. The framework is designed to provide insights into both the suitability of potential aquifer storage sites as well as the priority for early deployment of CCS with existing CO2 sources. Preliminary application of the framework, conducted using GIS-based evaluation tools revealed that 18% of onshore aquifer sites with a combined CO2 storage capacity of 746 gigatons are considered to exhibit very high suitability, and 11% of onshore aquifer sites with a total capacity of 290 gigatons exhibit very high priority opportunities for implementation. These onshore aquifer sites may provide promising opportunities for early large-scale CCS deployment and contribute to CO2 mitigation in China for many decades.

  2. Nitrogen dioxide detection

    DOE Patents [OSTI]

    Sinha, Dipen N.; Agnew, Stephen F.; Christensen, William H.

    1993-01-01

    Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

  3. Deployment of CCS Technologies across the Load Curve for a Competitive Electricity Market as a Function of CO2 Emissions Permit Prices

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.

    2011-04-18

    Consistent with other published studies, the modelling presented here reveals that baseload power plants are the first aspects of the electricity sector to decarbonize and are essentially decarbonized once CO2 permit prices exceed a certain threshold ($90/ton CO2 in this study). The decarbonization of baseload electricity is met by significant expansions of nuclear power and renewable energy generation technologies as well as the application of carbon dioxide capture and storage (CCS) technologies applied to both coal and natural gas fired power plants. Relatively little attention has been paid thus far to whether intermediate and peaking units would respond the same way to a climate policy given the very different operational and economic context that these kinds of electricity generation units operate under. In this paper, the authors discuss key aspects of the load segmentation methodology used to imbed a varying electricity demand within the GCAM (a state-of-the-art Integrated Assessment Model) energy and economic modelling framework and present key results on the role CCS technologies could play in decarbonizng subpeak and peak generation (encompassing only the top 10% of the load) and under what conditions. To do this, the authors have modelled two hypothetical climate policies that require 50% and 80% reductions in US emissions from business as usual by the middle of this century. Intermediate electricity generation is virtually decarbonized once carbon prices exceed approximately $150/tonCO2. When CO2 permit prices exceed $160/tonCO2, natural gas power plants with CCS have roughly the same marketshare as conventional gas plants in serving subpeak loads. The penetration of CCS into peak load (upper 6% here) is minimal under the scenarios modeled here suggesting that CO2 emissions from this aspect of the U.S. electricity sector would persist well into the future even with stringent CO2 emission control policies in place.

  4. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  5. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P.

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  6. SULFUR POLYMER ENCAPSULATION.

    SciTech Connect (OSTI)

    KALB, P.

    2001-08-22

    Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not

  7. Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases

    DOE Patents [OSTI]

    Clay, David T.; Lynn, Scott

    1976-10-19

    A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

  8. NREL's Cyanobacteria Engineering Shortens Biofuel Production Process, Captures CO2

    SciTech Connect (OSTI)

    2015-09-01

    This highlight describes NREL's work to systematically analyze the flow of energy in a photosynthetic microbe and show how the organism adjusts its metabolism to meet the increased energy demand for making ethylene. This work successfully demonstrates that the organism could cooperate by stimulating photosynthesis. The results encourage further genetic engineering for the conversion of CO2 to biofuels and chemicals. This highlight is being developed for the September 2015 Alliance S&T Board meeting. biofuels and chemicals. This highlight is being developed for the September 2015 Alliance S&T Board meeting.

  9. Effects of long-term elevated CO2 treatment on the inner and outer bark chemistry of sweetgum (Liquidambar styraciflua L.) trees

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eberhardt, Thomas L.; Labbé, Nicole; So, Chi-Leung; Kim, Keonhee; Reed, Karen G.; Leduc, Daniel J.; Warren, Jeffrey M.

    2015-07-23

    Long-term exposure of sweetgum trees to elevated atmospheric CO2 concentrations significantly shifted inner bark (phloem) and outer bark (rhytidome) chemical compositions, having implications for both defense and nutrient cycling. Changes in plant tissue chemistry due to increasing atmospheric carbon dioxide (CO2) concentrations have direct implications for tissue resistance to abiotic and biotic stress while living, and soil nutrient cycling when senesced as litter. Although the effects of elevated CO2 concentrations on tree foliar chemistry are well documented, the effects on tree bark chemistry are largely unknown. The objective of our study was to determine the effects of a long-term elevatedmore » CO2 treatment on the contents of individual elements, extractives, ash, lignin, and polysaccharide sugars of sweetgum (Liquidambar styraciflua L.) bark. Trees were harvested from sweetgum plots equipped with the Free-Air CO2 Enrichment (FACE) apparatus, receiving either elevated or ambient CO2 treatments over a 12-year period. Whole bark sections were partitioned into inner bark (phloem) and outer bark (rhytidome) samples before analysis. Moreover, principal component analysis, coupled with either Fourier transform infrared spectroscopy or pyrolysis-gas chromatography-mass spectrometry data, was also used to screen for differences. Elevated CO2 reduced the N content (0.42 vs. 0.35 %) and increased the C:N ratio (109 vs. 136 %) of the outer bark. For the inner bark, elevated CO2 increased the Mn content (470 vs. 815 mg kg-1), total extractives (13.0 vs. 15.6 %), and residual ash content (8.1 vs. 10.8 %) as compared to ambient CO2; differences were also observed for some hemicellulosic sugars, but not lignin. Shifts in bark chemistry can affect the success of herbivores and pathogens in living trees, and as litter, bark can affect the biogeochemical cycling of nutrients within the forest floor. Our results demonstrate that increasing atmospheric CO2 concentrations

  10. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  11. Consumption, Not CO2 emissions: Reframing Perspectives on Climate Change and Sustainability

    SciTech Connect (OSTI)

    Harriss, Robert; Shui, Bin

    2010-12-01

    A stunning documentary film titled Mardi Gras: Made in China provides an insightful and engaging perspective on the globalization of desire for material consumption. Tracing the life cycle of Mardi Gras beads from a small factory in Fuzhou, China to the streets of the Mardi Gras celebration in New Orleans the viewer grasps the near universal human desire to strive for an affluent lifestyle. David Redmon, an independent film maker, follows the beads' genealogy back to the industrial town of Fuzhou, China, to the factory that is the world's largest producer of Mardi Gras beads and related party trinkets. He explores how these frivolous and toxic products affect the people who make them and those who consume them. Redmon captures the daily reality of a Chinese manufacturing facility. Its workforce of approximately 500 teenage girls, and a handful of boys, live like prisoners in a fenced-in compound. These young people, often working 16-hour days, are constantly exposed to styrene, a chemical known to cause cancer all for about 10 cents an hour. In addition to indoor pollution, the decrepit coal-fired manufacturing facilities are symbolic of Chinas fast rise to the worlds top producer of carbon dioxide (CO2) emissions.1 The process of industrialization and modernization in China is happening at an unprecedented rate and scale.

  12. Two-Phase Flow Within Porous Media Analogies: Application Towards CO2 Sequestration

    SciTech Connect (OSTI)

    Crandall, D.M. Clarkson University, Potsdam, NY); Ahmadi, G.; Smith, D.H.

    2007-04-20

    Geologic carbon dioxide sequestration (GCO2S) involves the capture of large quantities of CO2 from point-source emitters and pumping this greenhouse gas to subsurface reservoirs (USDOE, 2006). The mechanisms of two-phase fluid displacement in GCO2S, where a less viscous fluid displaces a more viscous fluid in a heterogeneous porous domain is similar to enhanced oil recovery activities. Direct observation of gas-liquid interface movement in geologic reservoirs is difficult due to location and opacity. Over the past decades, complex, interconnected pore-throat models have been developed and used to study multiphase flow interactions in porous media, both experimentally (Buckley, 1994) and numerically (Blunt, 2001). This work expands upon previous experimental research with the use of a new type of heterogeneous flowcell, created with stereolithography (SL). Numerical solutions using the Volume-of-Fluid (VOF) model with the same flowcell geometry, are shown to be in good agreement with the drainage experiments, where the defending fluid wets the surface. This computational model is then used to model imbibition, the case of the invading fluid preferentially wetting the surface. Low capillary flows and imbibition conditions are shown to increase the storage volume of the invading fluid in the porous medium.

  13. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Kowal, A.; Li, M; Shao, M; Sasaki, K; Vukmirovic, M; Zhang, J; Marinkovic, N; Liu, P; Frenkel, A; Adzic, R

    2009-01-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts1, 2. We synthesized a ternary PtRhSnO2/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO2, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  14. A framework for environmental assessment of CO2 capture and storage systems

    SciTech Connect (OSTI)

    Sathre, R; Chester, M; Cain, J; Masanet, E

    2012-01-01

    Carbon dioxide capture and storage (CCS) is increasingly seen as a way for society to enjoy the benefits of fossil fuel energy sources while avoiding the climate disruption associated with fossil CO2 emissions. A decision to deploy CCS technology at scale should be based on robust information on its overall costs and benefits. Life-cycle assessment (LCA) is a framework for holistic assessment of the energy and environmental footprint of a system, and can provide crucial information to policy-makers, scientists, and engineers as they develop and deploy CCS systems. We identify seven key issues that should be considered to ensure that conclusions and recommendations from CCS LCA are robust: energy penalty, functional units, scale-up challenges, non-climate environmental impacts, uncertainty management, policy-making needs, and market effects. Several recent life-cycle studies have focused on detailed assessments of individual CCS technologies and applications. While such studies provide important data and information on technology performance, such case-specific data are inadequate to fully inform the decision making process. LCA should aim to describe the system-wide environmental implications of CCS deployment at scale, rather than a narrow analysis of technological performance of individual power plants. (C) 2011 Elsevier Ltd. All rights reserved.

  15. STOMP Subsurface Transport Over Multiple Phases: STOMP-CO2 and STOMP-CO2e Guide: Version 1.0

    SciTech Connect (OSTI)

    White, Mark D.; Bacon, Diana H.; McGrail, B. Peter; Watson, David J.; White, Signe K.; Zhang, Z. F.

    2012-04-03

    This STOMP (Subsurface Transport Over Multiple Phases) guide document describes the theory, use, and application of the STOMP-CO2 and STOMP-CO2e operational modes. These operational modes of the STOMP simulator are configured to solve problems involving the sequestration of CO2 in geologic saline reservoirs. STOMP-CO2 is the isothermal version and STOMP-CO2e is the nonisothermal version. These core operational modes solve the governing conservation equations for component flow and transport through geologic media; where, the STOMP-CO2 components are water, CO2 and salt and the STOMP-CO2e operational mode also includes an energy conservation equation. Geochemistry can be included in the problem solution via the ECKEChem (Equilibrium-Conservation-Kinetic-Equation Chemistry) module, and geomechanics via the EPRMech (Elastic-Plastic-Rock Mechanics) module. This addendum is designed to provide the new user with a full guide for the core capabilities of the STOMP-CO2 and -CO2e simulators, and to provide the experienced user with a quick reference on implementing features. Several benchmark problems are provided in this addendum, which serve as starting points for developing inputs for more complex problems and as demonstrations of the simulator’s capabilities.

  16. HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT

    SciTech Connect (OSTI)

    Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

    2009-04-15

    The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and

  17. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  18. IMPLEMENTING A NOVEL CYCLIC CO2 FLOOD IN PALEOZOIC REEFS

    SciTech Connect (OSTI)

    James R. Wood; W. Quinlan; A. Wylie

    2004-07-01

    Recycled CO2 will be used in this demonstration project to produce bypassed oil from the Silurian Dover 35 pinnacle reef (Otsego County) in the Michigan Basin. We began injecting CO2 in the Dover 35 field into the Salling-Hansen 4-35A well on May 6, 2004. Subsurface characterization is being completed using well log tomography animations and 3D visualizations to map facies distributions and reservoir properties in three reefs, the Belle River Mills, Chester 18, and Dover 35 Fields. The Belle River Mills and Chester 18 fields are being used as type-fields because they have excellent log and/or core data coverage. Amplitude slicing of the log porosity, normalized gamma ray, core permeability, and core porosity curves is showing trends that indicate significant heterogeneity and compartmentalization in these reservoirs associated with the original depositional fabric of the rocks. Digital and hard copy data continues to be compiled for the Niagaran reefs in the Michigan Basin. Technology transfer took place through technical presentations regarding visualization of the heterogeneity of the Niagaran reefs. Oral presentations were given at the Petroleum Technology Transfer Council workshop, Michigan Oil and Gas Association Conference, and Michigan Basin Geological Society meeting. A technical paper was submitted to the Bulletin of the American Association of Petroleum Geologists on the characterization of the Belle River Mills Field.

  19. CO2 sequestration potential of Charqueadas coal field in Brazil

    SciTech Connect (OSTI)

    Romanov, V; Santarosa, C; Crandall, D; Haljasmaa, I; Hur, T -B; Fazio, J; Warzinski, R; Heemann, R; Ketzer, J M

    2013-02-01

    Although coal is not the primary source of energy in Brazil there is growing interest to evaluate the potential of coal from the south of the country for various activities. The I2B coal seamin the Charqueadas coal field has been considered a target for enhanced coal bed methane production and CO2 sequestration. A detailed experimental study of the samples from this seam was conducted at the NETL with assistance from the Pontif?cia Universidade Cat?lica Do Rio Grande Do Sul. Such properties as sorption capacity, internal structure of the samples, porosity and permeability were of primary interest in this characterization study. The samples used were low rank coals (high volatile bituminous and sub-bituminous) obtained from the I2B seam. It was observed that the temperature effect on adsorption capacity correlates negatively with as-received water and mineral content. Langmuir CO2 adsorption capacity of the coal samples ranged 0.61?2.09 mmol/g. The upper I2B seam appears to be overall more heterogeneous and less permeable than the lower I2B seam. The lower seam coal appears to have a large amount of micro-fractures that do not close even at 11 MPa of confining pressure.

  20. Misrepresentation of the IPCC CO2 emission scenarios

    SciTech Connect (OSTI)

    Manning, Martin; Edmonds, James A.; Emori, S.; Grubler, Arnulf; Hibbard, Kathleen A.; Joos, Fortunat; Kainuma, M.; Keeling, Ralph; Kram, Tom; Manning, Andrew; Meinhausen, Malte; Moss, Richard H.; Nakicenovic, Nebojsa; Riahi, Keywan; Rose, Steven K.; Smith, Steven J.; Swart, Robert; Van Vuuren, Detlef

    2010-06-01

    Estimates of recent fossil fuel CO2 emissions have been compared with the IPCC SRES (Special Report on Emission Scenarios) emission scenarios that had been developed for analysis of future climate change, impacts and mitigation. In some cases this comparison uses averages across subgroups of SRES scenarios and for one category of greenhouse gases (industrial sources of CO2). That approach can be misleading and cause confusion as it is inconsistent with many of the papers on future climate change projections that are based on a specific subset of closely scrutinized SRES scenarios, known as illustrative marker scenarios. Here, we show that comparison between recent estimates of fossil fuel emissions trends and the SRES illustrative marker scenarios leads to the conclusion that recent trends are not outside the SRES range. Furthermore, the recent economic downturn appears to have brought actual emission back toward the middle of the SRES illustrative marker scenarios. We also note that SRES emission scenarios are designed to reflect potential alternative long-term trends in a world without climate policy intervention and the trend in the resulting climate change is not sensitive to short-term fluctuations.

  1. IMPLEMENTING A NOVEL CYCLIC CO2 FLOOD IN PALEOZOIC REEFS

    SciTech Connect (OSTI)

    James R. Wood; W. quinlan; A. Wylie

    2006-06-01

    Recycled CO2 is being used in this demonstration project to produce bypassed oil from the Silurian Dover 35 Niagaran pinnacle reef located in Otsego County, Michigan. CO2 injection in the Dover 35 field into the Salling-Hansen 4-35A well began on May 6, 2004. A second injection well, the Salling-Hansen 1-35, commenced injection in August 2004. Oil production in the Pomerzynski 5-35 producing well increased from 9 BOPD prior to operations to an average of 165 BOPD in December, 2004 and has produced at an average rate of 61 BOPD (Jan-Dec, 2005). The Salling-Hansen 4-35A also produced during this reporting period an average of 29 BOPD. These increases have occurred as a result of CO2 injection and the production rate appears to be stabilizing. CO2 injection volume has reached approximately 2.18 BCF. The CO2 injection phase of this project has been fully operational since December 2004 and most downhole mechanical issues have been solved and surface facility modifications have been completed. It is anticipated that filling operations will run for another 6-12 months from July 1, 2005. In most other aspects, the demonstration is going well and hydrocarbon production has been stabilized at an average rate of 57 BOPD (July-Dec, 2005). Our industry partners continue to experiment with injection rates and pressures, various downhole and surface facility mechanical configurations, and the huff-n-puff technique to develop best practices for these types of enhanced recovery projects. Subsurface characterization was completed using well log tomography and 3D visualizations to map facies distributions and reservoir properties in the Belle River Mills, Chester 18, Dover 35, and Dover 36 Fields. The Belle River Mills and Chester 18 fields are being used as type-fields because they have excellent log and/or core data coverage. Amplitude slicing of the log porosity, normalized gamma ray, core permeability, and core porosity curves are showing trends that indicate significant

  2. Sandia's Supercritical Carbon-Dioxide/Brayton-Cycle Laboratory Signs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Important MOU with Industry Partners Supercritical Carbon-Dioxide/Brayton-Cycle Laboratory Signs Important MOU with Industry Partners - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power

  3. Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperatures - Energy Innovation Portal Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication S-126827 (Organoclay Sorbent).pdf (292 KB) Technology Marketing Summary By incorporating amines inside clay containing quaternary ammonium salts (organoclay) minerals, this invention has created a way to prepare sorbents that capture carbon dioxide (CO2)

  4. Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Interfaces | Department of Energy Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock Interfaces Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock Interfaces Project obectives: Utilize synchrotron X-ray measurements, to monitor all aspects of atomic to nanoscale structural changes resulting from chemical interactions of scCO2-H2O binary fluids with rocks under environments directly relevant to EGS. chemistry_you_synchrotron_studies.pdf (1.84

  5. Properties of CO2-Rich Pore Fluids and Their Effect on Porosity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks ...

  6. CO2 Induced Phase Transitions in Diamine-Appended Metal-Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Induced Phase Transitions in Diamine-Appended Metal-Organic Frameworks Previous Next List ... study the effect of CO2 adsorption in an amine functionalized metal-organic framework. ...

  7. Effect of dissolved CO2 on a shallow groundwater system: A controlled...

    Office of Scientific and Technical Information (OSTI)

    Effect of dissolved CO2 on a shallow groundwater system: A controlled release experiment Citation Details In-Document Search Title: Effect of dissolved CO2 on a shallow groundwater ...

  8. Designing small catalysts for CO2 capture (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Designing small catalysts for CO2 capture Citation Details In-Document Search Title: Designing small catalysts for CO2 capture Authors: Wong, S E ; Lau, E Y ; Satcher, J H ; Aines, ...

  9. Microsoft Word - NRAP-TRS-III-004-2013_DevelopSurrogateModelsCO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... S. Injection and storage of CO 2 in deep saline aquifers: analytical solution for CO 2 ... Jared Ciferno Director Office of Coal and Power R&D National Energy Technology Laboratory ...

  10. Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate CO2 ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  11. Advanced Development Of The Coal Fired Oxyfuel Process With CO2...

    Open Energy Info (EERE)

    Development Of The Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name: Advanced Development Of The Coal-Fired Oxyfuel Process With CO2...

  12. Understanding Trends in CO2 adsorption in Metal-Organic Frameworks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding Trends in CO2 adsorption in Metal-Organic Frameworks with Open-Metal Sites ... bond analysis, we study and explain trends in the binding between CO2 and open-metal ...

  13. NETL's 2015 Carbon Storage Atlas Shows Increase in U.S. CO2 Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NETL's 2015 Carbon Storage Atlas Shows Increase in U.S. CO2 Storage Potential NETL's 2015 Carbon Storage Atlas Shows Increase in U.S. CO2 Storage Potential September 28, 2015 - ...

  14. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy...

  15. Operation and analysis of a supercritical CO2 Brayton cycle.

    SciTech Connect (OSTI)

    Wright, Steven Alan; Radel, Ross F.; Vernon, Milton E.; Pickard, Paul S.; Rochau, Gary Eugene

    2010-09-01

    Sandia National Laboratories is investigating advanced Brayton cycles using supercritical working fluids for use with solar, nuclear or fossil heat sources. The focus of this work has been on the supercritical CO{sub 2} cycle (S-CO2) which has the potential for high efficiency in the temperature range of interest for these heat sources, and is also very compact, with the potential for lower capital costs. The first step in the development of these advanced cycles was the construction of a small scale Brayton cycle loop, funded by the Laboratory Directed Research & Development program, to study the key issue of compression near the critical point of CO{sub 2}. This document outlines the design of the small scale loop, describes the major components, presents models of system performance, including losses, leakage, windage, compressor performance, and flow map predictions, and finally describes the experimental results that have been generated.

  16. Model Selection for Monitoring CO2 Plume during Sequestration

    Energy Science and Technology Software Center (OSTI)

    2014-12-31

    The model selection method developed as part of this project mainly includes four steps: (1) assessing the connectivity/dynamic characteristics of a large prior ensemble of models, (2) model clustering using multidimensional scaling coupled with k-mean clustering, (3) model selection using the Bayes' rule in the reduced model space, (4) model expansion using iterative resampling of the posterior models. The fourth step expresses one of the advantages of the method: it provides a built-in means ofmore » quantifying the uncertainty in predictions made with the selected models. In our application to plume monitoring, by expanding the posterior space of models, the final ensemble of representations of geological model can be used to assess the uncertainty in predicting the future displacement of the CO2 plume. The software implementation of this approach is attached here.« less

  17. Data Assimilation Tools for CO2 Reservoir Model Development – A Review of Key Data Types, Analyses, and Selected Software

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Sullivan, E. C.; Murray, Christopher J.; Last, George V.; Black, Gary D.

    2009-09-30

    Pacific Northwest National Laboratory (PNNL) has embarked on an initiative to develop world-class capabilities for performing experimental and computational analyses associated with geologic sequestration of carbon dioxide. The ultimate goal of this initiative is to provide science-based solutions for helping to mitigate the adverse effects of greenhouse gas emissions. This Laboratory-Directed Research and Development (LDRD) initiative currently has two primary focus areas—advanced experimental methods and computational analysis. The experimental methods focus area involves the development of new experimental capabilities, supported in part by the U.S. Department of Energy’s (DOE) Environmental Molecular Science Laboratory (EMSL) housed at PNNL, for quantifying mineral reaction kinetics with CO2 under high temperature and pressure (supercritical) conditions. The computational analysis focus area involves numerical simulation of coupled, multi-scale processes associated with CO2 sequestration in geologic media, and the development of software to facilitate building and parameterizing conceptual and numerical models of subsurface reservoirs that represent geologic repositories for injected CO2. This report describes work in support of the computational analysis focus area. The computational analysis focus area currently consists of several collaborative research projects. These are all geared towards the development and application of conceptual and numerical models for geologic sequestration of CO2. The software being developed for this focus area is referred to as the Geologic Sequestration Software Suite or GS3. A wiki-based software framework is being developed to support GS3. This report summarizes work performed in FY09 on one of the LDRD projects in the computational analysis focus area. The title of this project is Data Assimilation Tools for CO2 Reservoir Model Development. Some key objectives of this project in FY09 were to assess the current state

  18. Carbon Dioxide Utilization Summit

    Broader source: Energy.gov [DOE]

    The 6th Carbon Dioxide Utilization Summit will be held in Newark, New Jersey, from Feb. 24–26, 2016. The conference will look at the benefits and challenges of carbon dioxide utilization. Advanced Algal Systems Program Manager Alison Goss Eng and Technology Manager Devinn Lambert will be in attendance. Dr. Goss Eng will be chairing a round table on Fuels and Chemicals during the Carbon Dioxide Utilization: From R&D to Commercialization discussion session.

  19. Chemical Impact of Elevated CO2on Geothermal Energy Production | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Impact of Elevated CO2on Geothermal Energy Production Chemical Impact of Elevated CO2on Geothermal Energy Production This is a two phase project to assess the geochemical impact of CO2on geothermal energy production by: analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based experiments to simulate production scale impacts.

  20. Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in EGS Rocks | Department of Energy Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks Project objective: Quantify key parameters critically needed for developing and validating numerical modeling of chemical interactions between EGS reservoir rocks and supercritical CO2and CO2-rich aqueous fluids. chemistry_cole_porosity_evolution.pdf (1.28 MB) More Documents &

  1. Laboratory and Field Experimental Studies of CO2 as Heat Transmission Fluid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Enhanced Geothermal Systems (EGS) | Department of Energy Laboratory and Field Experimental Studies of CO2 as Heat Transmission Fluid in Enhanced Geothermal Systems (EGS) Laboratory and Field Experimental Studies of CO2 as Heat Transmission Fluid in Enhanced Geothermal Systems (EGS) Project objectives: obtain basic information on the performance of CO2-based EGS; and enhance and calibrate modeling capabilities for such systems. reservoir_pruess_co2_transmission.pdf (634.11 KB) More

  2. Three-Dimensional Modeling of the Reactive Transport of CO2 and...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: CO2 reservoir, reactive transport, geochemistry, geomechanics, geomechanical modeling, mineral composition, homogenization, fault, hydraulic fracture, elastic modulus Word ...

  3. Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream

    DOE Patents [OSTI]

    Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

    2014-07-08

    The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

  4. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  5. Experimental study of potential wellbore cement carbonation by various phases of carbon dioxide during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong

    2013-08-16

    Hydrated Portland cement was reacted with carbon dioxide (CO2) in supercritical, gaseous, and aqueous phases to understand the potential cement alteration processes along the length of a wellbore, extending from deep CO2 storage reservoir to the shallow subsurface during geologic carbon sequestration. The 3-D X-ray microtomography (XMT) images displayed that the cement alteration was significantly more extensive by CO2-saturated synthetic groundwater than dry or wet supercritical CO2 at high P (10 MPa)-T (50C) conditions. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis also exhibited a systematic Ca depletion and C enrichment in cement matrix exposed to CO2-saturated groundwater. Integrated XMT, XRD, and SEM-EDS analyses identified the formation of extensive carbonated zone filled with CaCO3(s), as well as the porous degradation front and the outermost silica-rich zone in cement after exposure to CO2-saturated groundwater. The cement alteration by CO2-saturated groundwater for 2-8 months overall decreased the porosity from 31% to 22% and the permeability by an order of magnitude. Cement alteration by dry or wet supercritical CO2 was slow and minor compared to CO2-saturated groundwater. A thin single carbonation zone was formed in cement after exposure to wet supercritical CO2 for 8 months or dry supercritical CO2 for 15 months. Extensive calcite coating was formed on the outside surface of a cement sample after exposure to wet gaseous CO2 for 1-3 months. The chemical-physical characterization of hydrated Portland cement after exposure to various phases of carbon dioxide indicates that the extent of cement carbonation can be significantly heterogeneous depending on CO2 phase present in the wellbore environment. Both experimental and geochemical modeling results suggest that wellbore cement exposure to supercritical, gaseous, and aqueous phases of CO2 during geologic carbon sequestration is unlikely to damage the wellbore

  6. CO2 Reduction by Dry Methane Reforming Over Hexaluminates: A Promising Technology for Decreasing Global Warming in a Cost Effective Manner

    SciTech Connect (OSTI)

    Salazar-Villalpando, M.D.; Gardner, T.H.

    2008-03-01

    Efficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). Hexaaluminate catalysts prepared at NETL may represent a product that can be utilized for the conversion of CO2 to syn-gas. In this work, transition metals dispersed in barium hexaaluminate have shown to be promising new catalysts for dry methane reforming. In this investigation, a series of BaNixAl12-yO19-? catalysts with varying Ni content were prepared by co-precipitation followed by calcination at 1400C. CO2 reduction by dry methane reforming was carried out to determine catalyst performance as a function of temperature and carbon formation was also quantified after the reforming tests. Results of catalysts characterization, dispersion and surface area, were correlated to catalytic performance.

  7. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  8. Rapid, reversible, solid–gas and solution-phase insertion of CO2 into In–P bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore » 2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(μ-Cl)[μ-(i-Pr2P)2N)].« less

  9. Rapid, Reversible, SolidGas and Solution-Phase Insertion of CO 2 into InP Bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four MP bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore2 h in the solidgas reaction. The CO2 complex is stable up to at least 60 C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(?-Cl)[?-(i-Pr2P)2N)].less

  10. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  11. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  12. Lessons Learned From Gen I Carbon Dioxide Cooled Reactors

    SciTech Connect (OSTI)

    David E. Shropshire

    2004-04-01

    This paper provides a review of early gas cooled reactors including the Magnox reactors originating in the United Kingdom and the subsequent development of the Advanced Gas-cooled Reactors (AGR). These early gas cooled reactors shared a common coolant medium, namely carbon dioxide (CO2). A framework of information is provided about these early reactors and identifies unique problems/opportunities associated with use of CO2 as a coolant. Reactor designers successfully rose to these challenges. After years of successful use of the CO2 gas cooled reactors in Europe, the succeeding generation of reactors, called the High Temperature Gas Reactors (HTGR), were designed with Helium gas as the coolant. Again, in the 21st century, with the latest reactor designs under investigation in Generation IV, there is a revived interest in developing Gas Cooled Fast Reactors that use CO2 as the reactor coolant. This paper provides a historical perspective on the 52 CO2 reactors and the reactor programs that developed them. The Magnox and AGR design features and safety characteristics were reviewed, as well as the technologies associated with fuel storage, reprocessing, and disposal. Lessons-learned from these programs are noted to benefit the designs of future generations of gas cooled nuclear reactors.

  13. Carbon Dioxide Emissions from the Generation of Electric Power in the United States 1998

    Reports and Publications (EIA)

    1999-01-01

    The President issued a directive on April 15, 1999, requiring an annual report summarizing carbon dioxide (CO2) emissions produced by electricity generation in the United States, including both utilities and nonutilities. In response, this report is jointly submitted by the U.S. Department of Energy and the U.S. Environmental Protection Agency.

  14. DOE Seeks Projects to Advance Carbon Dioxide Utilization from Coal-Fired Power Plants

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) has announced approximately $6.7 million in federal funding for cost-shared projects that will develop technologies that utilize carbon dioxide (CO2) from coal-fired power plants to produce useful products.

  15. Leakage of CO2 from geologic storage: Role of secondaryaccumulation at shallow depth

    SciTech Connect (OSTI)

    Pruess, K.

    2007-05-31

    Geologic storage of CO2 can be a viable technology forreducing atmospheric emissions of greenhouse gases only if it can bedemonstrated that leakage from proposed storage reservoirs and associatedhazards are small or can be mitigated. Risk assessment must evaluatepotential leakage scenarios and develop a rational, mechanisticunderstanding of CO2 behavior during leakage. Flow of CO2 may be subjectto positive feedbacks that could amplify leakage risks and hazards,placing a premium on identifying and avoiding adverse conditions andmechanisms. A scenario that is unfavorable in terms of leakage behavioris formation of a secondary CO2 accumulation at shallow depth. This paperdevelops a detailed numerical simulation model to investigate CO2discharge from a secondary accumulation, and evaluates the role ofdifferent thermodynamic and hydrogeologic conditions. Our simulationsdemonstrate self-enhancing as well as self-limiting feedbacks.Condensation of gaseous CO2, 3-phase flow of aqueous phase -- liquid CO2-- gaseous CO2, and cooling from Joule-Thomson expansion and boiling ofliquid CO2 are found to play important roles in the behavior of a CO2leakage system. We find no evidence that a subsurface accumulation of CO2at ambient temperatures could give rise to a high-energy discharge, aso-called "pneumatic eruption."

  16. Mathematical Analysis of High-Temperature Co-electrolysis of CO2 and O2 Production in a Closed-Loop Atmosphere Revitalization System

    SciTech Connect (OSTI)

    Michael G. McKellar; Manohar S. Sohal; Lila Mulloth; Bernadette Luna; Morgan B. Abney

    2010-03-01

    NASA has been evaluating two closed-loop atmosphere revitalization architectures based on Sabatier and Bosch carbon dioxide, CO2, reduction technologies. The CO2 and steam, H2O, co-electrolysis process is another option that NASA has investigated. Utilizing recent advances in the fuel cell technology sector, the Idaho National Laboratory, INL, has developed a CO2 and H2O co-electrolysis process to produce oxygen and syngas (carbon monoxide, CO and hydrogen, H2 mixture) for terrestrial (energy production) application. The technology is a combined process that involves steam electrolysis, CO2 electrolysis, and the reverse water gas shift (RWGS) reaction. A number of process models have been developed and analyzed to determine the theoretical power required to recover oxygen, O2, in each case. These models include the current Sabatier and Bosch technologies and combinations of those processes with high-temperature co-electrolysis. The cases of constant CO2 supply and constant O2 production were evaluated. In addition, a process model of the hydrogenation process with co-electrolysis was developed and compared. Sabatier processes require the least amount of energy input per kg of oxygen produced. If co-electrolysis replaces solid polymer electrolyte (SPE) electrolysis within the Sabatier architecture, the power requirement is reduced by over 10%, but only if heat recuperation is used. Sabatier processes, however, require external water to achieve the lower power results. Under conditions of constant incoming carbon dioxide flow, the Sabatier architectures require more power than the other architectures. The Bosch, Boudouard with co-electrolysis, and the hydrogenation with co-electrolysis processes require little or no external water. The Bosch and hydrogenation processes produce water within their reactors, which aids in reducing the power requirement for electrolysis. The Boudouard with co-electrolysis process has a higher electrolysis power requirement because carbon

  17. Impact of mesophyll diffusion on estimated global land CO2 fertilization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ying; Gu, Lianhong; Dickinson, Robert E.; Norby, Richard J.; Pallardy, Stephen G.; Hoffman, Forrest M.

    2014-10-13

    In C3 plants, CO2 concentrations drop considerably along mesophyll diffusion pathways from substomatal cavities to chloroplasts where CO2 assimilation occurs. Global carbon cycle models have not explicitly represented this internal drawdown and so overestimate CO2 available for carboxylation and underestimate photosynthetic responsiveness to atmospheric CO2. An explicit consideration of mesophyll diffusion increases the modeled cumulative CO2 fertilization effect (CFE) for global gross primary production (GPP) from 915 PgC to 1057 PgC for the period of 1901 to 2010. This increase represents a 16% correction, large enough to explain the persistent overestimation of growth rates of historical atmospheric CO2 by Earthmore » System Models. Without this correction, the CFE for global GPP is underestimated by 0.05 PgC yr-1ppm-1. This finding implies that the contemporary terrestrial biosphere is more CO2-limited than previously thought.« less

  18. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T.; Jozewicz, Wojciech

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  19. Method for dissolving plutonium dioxide

    DOE Patents [OSTI]

    Tallent, Othar K.

    1976-01-01

    A method for dissolving plutonium dioxide comprises adding silver ions to a nitric acid-hydrofluoric acid solution to significantly speed up dissolution of difficultly soluble plutonium dioxide.

  20. Numerical Modeling of CO2 Sequestration in Geologic Formations -Recent Results and Open Challenges

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-03-08

    Rising atmospheric concentrations of CO2, and their role inglobal warming, have prompted efforts to reduce emissions of CO2 fromburning of fossil fuels. An attractive mitigation option underconsideration in many countries is the injection of CO2 from stationarysources, such as fossil-fueled power plants, into deep, stable geologicformations, where it would be stored and kept out of the atmosphere fortime periods of hundreds to thousands of years or more. Potentialgeologic storage reservoirs include depleted or depleting oil and gasreservoirs, unmineable coal seams, and saline formations. While oil andgas reservoirs may provide some attractive early targets for CO2 storage,estimates for geographic regions worldwide have suggested that onlysaline formations would provide sufficient storage capacity tosubstantially impact atmospheric releases. This paper will focus on CO2storage in saline formations.Injection of CO2 into a saline aquifer willgive rise to immiscible displacement of brine by the advancing CO2. Thelower viscosity of CO2 relative to aqueous fluids provides a potentialfor hydrodynamic instabilities during the displacement process. Attypical subsurface conditions of temperature and pressure, CO2 is lessdense than aqueous fluids and is subject to upward buoyancy force inenvironments where pressures are controlled by an ambient aqueous phase.Thus CO2 would tend to rise towards the top of a permeable formation andaccumulate beneath the caprock. Some CO2 will also dissolve in theaqueous phase, while the CO2-rich phase may dissolve some formationwaters, which would tend to dry out the vicinity of the injection wells.CO2 will make formation waters more acidic, and will induce chemicalrections that may precipitate and dissolve mineral phases (Xu et al.,2004). As a consequence of CO2 injection, significant pressurization offormation fluids would occur over large areas. These pressurizationeffects will change effective stresses, and may cause movement alongfaults