National Library of Energy BETA

Sample records for diffraction-limited sample preparation

  1. Overcoming the far-field diffraction limit via absorbance modulation

    E-Print Network [OSTI]

    Tsai, Hsin-Yu Sidney

    2011-01-01

    Diffraction limits the resolution of far-field lithography and imaging to about half of the wavelength, which greatly limits the capability of optical techniques. The proposed technique with absorbance modulation aims to ...

  2. Microfluidic Tools for Biological Sample Preparation

    SciTech Connect (OSTI)

    Visuri, S R; Ness, K; Dzenitis, J; Benett, B; Bettencourt, K; Hamilton, J; Fisher, K; Krulevitch, P

    2002-04-10

    Researchers at Lawrence Livermore National Laboratory are developing means to collect and identify fluid-based biological pathogens in the forms of proteins, viruses, and bacteria. To support detection instruments, we are developing a flexible fluidic sample preparation unit. The overall goal of this Microfluidic Module is to input a fluid sample, containing background particulates and potentially target compounds, and deliver a processed sample for detection. We are developing techniques for sample purification, mixing, and filtration that would be useful to many applications including immunologic and nucleic acid assays. Sample preparation functions are accomplished with acoustic radiation pressure, dielectrophoresis, and solid phase extraction. We are integrating these technologies into packaged systems with pumps and valves to control fluid flow and investigating small-scale detection methods.

  3. Diffraction limited focusing and routing of gap plasmons by a metal-dielectric-metal lens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dennis, Brian S.; Czaplewski, David A.; Haftel, Michael I.; Lopez, Daniel; Blumberg, Girsh; Aksyuk, Vladimir

    2015-08-12

    Passive optical elements can play key roles in photonic applications such as plasmonic integrated circuits. Here we experimentally demonstrate passive gap-plasmon focusing and routing in two-dimensions. This is accomplished using a high numerical-aperture metal-dielectric-metal lens incorporated into a planar-waveguide device. Fabrication via metal sputtering, oxide deposition, electron- and focused-ion- beam lithography, and argon ion-milling is reported on in detail. Diffraction-limited focusing is optically characterized by sampling out-coupled light with a microscope. The measured focal distance and full-width-half-maximum spot size agree well with the calculated lens performance. The surface plasmon polariton propagation length is measured by sampling light from multiple out-couplermore »slits.« less

  4. Microfluidic DNA sample preparation method and device

    DOE Patents [OSTI]

    Krulevitch, Peter A. (Pleasanton, CA); Miles, Robin R. (Danville, CA); Wang, Xiao-Bo (San Diego, CA); Mariella, Raymond P. (Danville, CA); Gascoyne, Peter R. C. (Bellaire, TX); Balch, Joseph W. (Livermore, CA)

    2002-01-01

    Manipulation of DNA molecules in solution has become an essential aspect of genetic analyses used for biomedical assays, the identification of hazardous bacterial agents, and in decoding the human genome. Currently, most of the steps involved in preparing a DNA sample for analysis are performed manually and are time, labor, and equipment intensive. These steps include extraction of the DNA from spores or cells, separation of the DNA from other particles and molecules in the solution (e.g. dust, smoke, cell/spore debris, and proteins), and separation of the DNA itself into strands of specific lengths. Dielectrophoresis (DEP), a phenomenon whereby polarizable particles move in response to a gradient in electric field, can be used to manipulate and separate DNA in an automated fashion, considerably reducing the time and expense involved in DNA analyses, as well as allowing for the miniaturization of DNA analysis instruments. These applications include direct transport of DNA, trapping of DNA to allow for its separation from other particles or molecules in the solution, and the separation of DNA into strands of varying lengths.

  5. GraFix: sample preparation for single-

    E-Print Network [OSTI]

    Cai, Long

    (cryo-EM). GraFix uses a glycerol gradient centrifugation step in which the complexes are centrifuged a structurally and compositionally homogeneous sample; this in turn requires advanced tools for sample handling are dissolved during centrifugation because of the pressure acting on the molecules. Chemical fixation reagents

  6. Overcoming the Diffraction Limit Using Multiple Light Scattering in a Highly Disordered Medium

    E-Print Network [OSTI]

    Choi, Youngwoon

    We report that disordered media made of randomly distributed nanoparticles can be used to overcome the diffraction limit of a conventional imaging system. By developing a method to extract the original image information ...

  7. Spatially dependent Rabi oscillations: An approach to sub-diffraction-limited coherent anti-Stokes Raman-scattering microscopy

    SciTech Connect (OSTI)

    Beeker, Willem P.; Lee, Chris J.; Boller, Klaus-Jochen; Gross, Petra; Cleff, Carsten; Fallnich, Carsten; Offerhaus, Herman L.; Herek, Jennifer L.

    2010-01-15

    We present a theoretical investigation of coherent anti-Stokes Raman scattering (CARS) that is modulated by periodically depleting the ground-state population through Rabi oscillations driven by an additional control laser. We find that such a process generates optical sidebands in the CARS spectrum and that the frequency of the sidebands depends on the intensity of the control laser light field. We show that analyzing the sideband frequency upon scanning the beams across the sample allows one to spatially resolve emitter positions where a spatial resolution of 65 nm, which is well below the diffraction limit, can be obtained.

  8. Preparation of Samples for Light Microscopy Simple Wax Seal

    E-Print Network [OSTI]

    Fygenson, Deborah Kuchnir

    Preparation of Samples for Light Microscopy Simple Wax Seal Materials - Slide - Cover Slip - Paraffin Wax Candle - Pasteur Pipette (suggested size 5 3/4 inch) - Matches Preparation of the Slide - You may want to protect the work surface from melted wax. We use a sheet of aluminum foil taped

  9. Fluidics platform and method for sample preparation and analysis

    DOE Patents [OSTI]

    Benner, W. Henry; Dzenitis, John M.; Bennet, William J.; Baker, Brian R.

    2014-08-19

    Herein provided are fluidics platform and method for sample preparation and analysis. The fluidics platform is capable of analyzing DNA from blood samples using amplification assays such as polymerase-chain-reaction assays and loop-mediated-isothermal-amplification assays. The fluidics platform can also be used for other types of assays and analyzes. In some embodiments, a sample in a sealed tube can be inserted directly. The following isolation, detection, and analyzes can be performed without a user's intervention. The disclosed platform may also comprises a sample preparation system with a magnetic actuator, a heater, and an air-drying mechanism, and fluid manipulation processes for extraction, washing, elution, assay assembly, assay detection, and cleaning after reactions and between samples.

  10. Ion source sample preparation techniques for carbon-14 AMS measurements

    SciTech Connect (OSTI)

    Balsley, D.R.; Farwell, G.W.; Grootes, P.M.; Schmidt, F.H.

    1987-01-01

    Methods for preparing solid graphite, and other types of carbon samples possessing good geometrical characteristics and producing large beams are described. Amorphous carbon, or graphite powder, is encapsulated in tantalum, compressed to approx.14 kilobars, and heated in vacuum to approx.2500/sup 0/C. The end of the capsule is cut off, exposing a smooth and hard graphite surface which provides excellent emittance in a reflection-type sputter source. The powder is prepared from CO/sub 2/ by the hydrogen-iron powder catalyzation method. Silver-carbon mixtures with good geometrical properties can also be prepared with our press. 6 refs., 4 figs.

  11. Optical Lithography and Atom Localization beyond the Diffraction Limit via Rabi Gradient 

    E-Print Network [OSTI]

    Liao, Zeyang

    2014-07-28

    frequency is much larger than the dipole-dipole interaction and showed how to extract the spatial information of the atoms with resolution far beyond the diffraction limit. This method is entirely based on far-field techniques and it does not require point...

  12. Sample preparation and detection device for infectious agents

    DOE Patents [OSTI]

    Miles, Robin R.; Wang, Amy W.; Fuller, Christopher K.; Lemoff, Asuncion V.; Bettencourt, Kerry A.; Yu, June

    2003-06-10

    A sample preparation and analysis device which incorporates both immunoassays and PCR assays in one compact, field-portable microchip. The device provides new capabilities in fluid and particle control which allows the building of a fluidic chip with no moving parts, thus decreasing fabrication cost and increasing the robustness of the device. The device can operate in a true continuous (not batch) mode. The device incorporates magnetohydrodynamic (MHD) pumps to move the fluid through the system, acoustic mixing and fractionation, dielectropheretic (DEP) sample concentration and purification, and on-chip optical detection capabilities.

  13. Apparatus for preparing a sample for mass spectrometry

    DOE Patents [OSTI]

    Villa-Aleman, E.

    1994-05-10

    An apparatus is described for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed. 1 figures.

  14. Optical imaging beyond the diffraction limit via dark states RID A-8711-2009 

    E-Print Network [OSTI]

    Li, Hebin; Sautenkov, Vladimir A.; Kash, Michael M.; Sokolov, Alexei V.; Welch, George R.; Rostovtsev, Yuri V.; Zubairy, M. Suhail; Scully, Marlan O.

    2008-01-01

    imaging beyond the diffraction limit via dark states Hebin Li,1 Vladimir A. Sautenkov,1,2 Michael M. Kash,1,3 Alexei V. Sokolov,1 George R. Welch,1 Yuri V. Rostovtsev,1 M. Suhail Zubairy,1,4 and Marlan O. Scully1,5 1Department of Physics and Institute... for Quantum Studies, Texas A&M University, College Station, Texas 77843-4242, USA 2P.N. Levedev Physical Institute, 53 Leninsky prospect, Moscow 119991, Russia 3Department of Physics, Lake Forest College, Lake Forest, Illinois 60045, USA 4Texas A...

  15. Measurement of the separation between atoms beyond diffraction limit RID A-5077-2009 

    E-Print Network [OSTI]

    Chang, J. T.; Evers, J.; Scully, Marlan O.; Zubairy, M. Suhail

    2006-01-01

    of the separation between atoms beyond diffraction limit Jun-Tao Chang,1 J?rg Evers,1,2 Marlan O. Scully,1,3 and M. Suhail Zubairy1,* 1Institute for Quantum Studies and Department of Physics, Texas A&M University, College Station, Texas 77843-4242, USA 2Max... microscopy ?3?. Also nonclassical features, such as entanglement, quantum interferometry, or multipho- ton processes, can be used to enhance resolution ?4?6?. A particularly promising development is lensless near-field op- tics, which can achieve...

  16. Detailed optical characterization of a near diffraction limited xenon fluoride laser

    SciTech Connect (OSTI)

    Londono, C. ); Smith, M.J.; Trainor, D.W.; Itzkan, I. ); Berggren, R. ); Fulghum, S.F. )

    1988-12-01

    A 1 m gain length, electron beam pumped xenon fluoride laser (lambda = 353, 351 nm) utilizing two laser mixtures of lean and rich NF/sub 3/, with Xe and balance Ne, was operated with a confocal unstable resonator with magnification of 2.24. The resultant beam quality was diagnosed with both shearing interferometry to measure near-field phase and far-field focal spot evaluation techniques. These measurements resulted in a beam quality of <1.15 times the diffraction limit with no evidence of the wide angle energy loss. This laser device was fully characterized with regard to electron beam deposition uniformity, transient refractive index effects, and optical quality of the resonator and diagnostic components.

  17. An experimental apparatus for diffraction-limites soft x-ray nanofocusing

    SciTech Connect (OSTI)

    Merthe, Daniel; Goldberg, Kenneth; Yashchuk, Valeriy; Yuan, Sheng; McKinney, Wayne; Celestre, Richard; Mochi, Iacopo; Macdougall, James; Morrison, Gregory; Rakawa, Senajith; Anderson, Erik; Smith, Brian; Domning, Edward; Warwick, Tony; Padmore, Howard

    2011-10-21

    Realizing the experimental potential of high-brightness, next generation synchrotron and free-electron laser light sources requires the development of reflecting x-ray optics capable of wavefront preservation and high-resolution nano-focusing. At the Advanced Light Source (ALS) beamline 5.3.1, we are developing broadly applicable, high-accuracy, in situ, at-wavelength wavefront measurement techniques to surpass 100-nrad slope measurement accuracy for diffraction-limited Kirkpatrick-Baez (KB) mirrors. The at-wavelength methodology we are developing relies on a series of wavefront-sensing tests with increasing accuracy and sensitivity, including scanning-slit Hartmann tests, grating-based lateral shearing interferometry, and quantitative knife-edge testing. We describe the original experimental techniques and alignment methodology that have enabled us to optimally set a bendable KB mirror to achieve a focused, FWHM spot size of 150 nm, with 1 nm (1.24 keV) photons at 3.7 mrad numerical aperture. The predictions of wavefront measurement are confirmed by the knife-edge testing.The side-profiled elliptically bent mirror used in these one-dimensional focusing experiments was originally designed for a much different glancing angle and conjugate distances. This work demonstrates that high-accuracy, at-wavelength wavefront-slope feedback can be used to optimize the pitch, roll, and mirror-bending forces in situ, using procedures that are deterministic and repeatable.

  18. Final LDRD report : development of sample preparation methods for ChIPMA-based imaging mass spectrometry of tissue samples.

    SciTech Connect (OSTI)

    Maharrey, Sean P.; Highley, Aaron M.; Behrens, Richard, Jr.; Wiese-Smith, Deneille

    2007-12-01

    The objective of this short-term LDRD project was to acquire the tools needed to use our chemical imaging precision mass analyzer (ChIPMA) instrument to analyze tissue samples. This effort was an outgrowth of discussions with oncologists on the need to find the cellular origin of signals in mass spectra of serum samples, which provide biomarkers for ovarian cancer. The ultimate goal would be to collect chemical images of biopsy samples allowing the chemical images of diseased and nondiseased sections of a sample to be compared. The equipment needed to prepare tissue samples have been acquired and built. This equipment includes an cyro-ultramicrotome for preparing thin sections of samples and a coating unit. The coating unit uses an electrospray system to deposit small droplets of a UV-photo absorbing compound on the surface of the tissue samples. Both units are operational. The tissue sample must be coated with the organic compound to enable matrix assisted laser desorption/ionization (MALDI) and matrix enhanced secondary ion mass spectrometry (ME-SIMS) measurements with the ChIPMA instrument Initial plans to test the sample preparation using human tissue samples required development of administrative procedures beyond the scope of this LDRD. Hence, it was decided to make two types of measurements: (1) Testing the spatial resolution of ME-SIMS by preparing a substrate coated with a mixture of an organic matrix and a bio standard and etching a defined pattern in the coating using a liquid metal ion beam, and (2) preparing and imaging C. elegans worms. Difficulties arose in sectioning the C. elegans for analysis and funds and time to overcome these difficulties were not available in this project. The facilities are now available for preparing biological samples for analysis with the ChIPMA instrument. Some further investment of time and resources in sample preparation should make this a useful tool for chemical imaging applications.

  19. Amphiphilic mediated sample preparation for micro-flow cytometry

    DOE Patents [OSTI]

    Clague, David S. (Livermore, CA); Wheeler, Elizabeth K. (Livermore, CA); Lee, Abraham P. (Irvine, CA)

    2009-03-17

    A flow cytometer includes a flow cell for detecting the sample, an oil phase in the flow cell, a water phase in the flow cell, an oil-water interface between the oil phase and the water phase, a detector for detecting the sample at the oil-water interface, and a hydrophobic unit operatively connected to the sample. The hydrophobic unit is attached to the sample. The sample and the hydrophobic unit are placed in an oil and water combination. The sample is detected at the interface between the oil phase and the water phase.

  20. Amphiphilic mediated sample preparation for micro-flow cytometry

    DOE Patents [OSTI]

    Clague, David S. (Livermore, CA); Wheeler, Elizabeth K. (Livermore, CA); Lee, Abraham P. (Irvine, CA)

    2006-07-25

    A flow cytometer includes a flow cell for detecting the sample, an oil phase in the flow cell, a water phase in the flow cell, an oil-water interface between the oil phase and the water phase, a detector for detecting the sample at the oil-water interface, and a hydrophobic unit operatively connected to the sample. The hydrophobic unit is attached to the sample. The sample and the hydrophobic unit are placed in an oil and water combination. The sample is detected at the interface between the oil phase and the water phase.

  1. Preparation of Oriented, Fully Hydrated Lipid Samples for Structure Determination Using X-Ray Scattering

    E-Print Network [OSTI]

    Nagle, John F.

    "the rock and roll method," which is basically a solvent evaporation technique with controlled manual. Atomic force microscopy is used to compare samples prepared using the rock and roll method with those prepared by spin-coating, which produces well-oriented but less homogeneous lipid stacks. These samples can

  2. Preparation of Bone Sam-ples for DNA Extraction: A

    E-Print Network [OSTI]

    , such as hammering frozen bone sealed in plastic freezer bags, have proven unreliable; shards of bone tend to pierce abrasive agent was included with the bone sample (in our case, sterilized glass fragments) to en- sure even-and-bolt as- sembly for reuse with other samples. However, considering the low cost of the nuts and bolts

  3. Electronic Supplement1 Details of sample preparation and data acquisition/processing, and sensitivity2

    E-Print Network [OSTI]

    Vel, Senthil

    Electronic Supplement1 Details of sample preparation and data acquisition of those smaller regions provides the bulk elastic moduli of the studied map. In27 this supplement we test

  4. Microwave-assisted sample preparation of coal and coal fly ash for subsequent metal determination

    SciTech Connect (OSTI)

    Srogi, K.

    2007-01-15

    The aim of this paper is to review microwave-assisted digestion of coal and coal fly ash. A brief description of microwave heating principles is presented. Microwave-assisted digestion appears currently to be the most popular preparation technique, possibly due to the comparatively rapid sample preparation and the reduction of contamination, compared to the conventional hot-plate digestion methods.

  5. Sample preparation method for glass welding by ultrashort laser pulses yields higher seam strength

    SciTech Connect (OSTI)

    Cvecek, K.; Miyamoto, I.; Strauss, J.; Wolf, M.; Frick, T.; Schmidt, M.

    2011-05-01

    Glass welding by ultrashort laser pulses allows joining without the need of an absorber or a preheating and postheating process. However, cracks generated during the welding process substantially impair the joining strength of the welding seams. In this paper a sample preparation method is described that prevents the formation of cracks. The measured joining strength of samples prepared by this method is substantially higher than previously reported values.

  6. Highly simplified lateral flow-based nucleic acid sample preparation and passive fluid flow control

    DOE Patents [OSTI]

    Cary, Robert B.

    2015-12-08

    Highly simplified lateral flow chromatographic nucleic acid sample preparation methods, devices, and integrated systems are provided for the efficient concentration of trace samples and the removal of nucleic acid amplification inhibitors. Methods for capturing and reducing inhibitors of nucleic acid amplification reactions, such as humic acid, using polyvinylpyrrolidone treated elements of the lateral flow device are also provided. Further provided are passive fluid control methods and systems for use in lateral flow assays.

  7. Method and apparatus for the preparation of liquid samples for determination of boron

    DOE Patents [OSTI]

    Siemer, Darryl D. (Idaho Falls, ID)

    1986-01-01

    A method and apparatus for the preparation of a liquid sample for the quantitative determination of boron by flame photometry. The sample is combined in a vessel with sulfuric acid, and an excess of methanol is added thereto. The methanol reacts with any boron present in the sample to form trimethyl borate which is volatilized by the heat of reaction between the excess methanol and sulfuric acid. The volatilized trimethyl borate is withdrawn from the vessel by either a partial vacuum or a positive pressure and is rapidly transferred to a standard flame photometer. The method is free of interference from typical boron concomitants.

  8. Diffraction limited focusing and...

    Office of Scientific and Technical Information (OSTI)

    at 180 C. The stack deposited onto the glass wafer piece consists of a 10 nm Cr adhesion layer, a 220 nm Au layer, a 2 nm Ti adhesion layer, 220 nm of SiO2, a 2 nm Ti...

  9. EVALUATION OF ARG-1 SAMPLES PREPARED BY CESIUM CARBONATE DISSOLUTION DURING THE ISOLOK SME ACCEPTABILITY TESTING

    SciTech Connect (OSTI)

    Edwards, T.; Hera, K.; Coleman, C.

    2011-12-05

    Evaluation of Defense Waste Processing Facility (DWPF) Chemical Process Cell (CPC) cycle time identified several opportunities to improve the CPC processing time. The Mechanical Systems & Custom Equipment Development (MS&CED) Section of the Savannah River National Laboratory (SRNL) recently completed the evaluation of one of these opportunities - the possibility of using an Isolok sampling valve as an alternative to the Hydragard valve for taking DWPF process samples at the Slurry Mix Evaporator (SME). The use of an Isolok for SME sampling has the potential to improve operability, reduce maintenance time, and decrease CPC cycle time. The SME acceptability testing for the Isolok was requested in Task Technical Request (TTR) HLW-DWPF-TTR-2010-0036 and was conducted as outlined in Task Technical and Quality Assurance Plan (TTQAP) SRNLRP-2011-00145. RW-0333P QA requirements applied to the task, and the results from the investigation were documented in SRNL-STI-2011-00693. Measurement of the chemical composition of study samples was a critical component of the SME acceptability testing of the Isolok. A sampling and analytical plan supported the investigation with the analytical plan directing that the study samples be prepared by a cesium carbonate (Cs{sub 2}CO{sub 3}) fusion dissolution method and analyzed by Inductively Coupled Plasma - Optical Emission Spectroscopy (ICP-OES). The use of the cesium carbonate preparation method for the Isolok testing provided an opportunity for an additional assessment of this dissolution method, which is being investigated as a potential replacement for the two methods (i.e., sodium peroxide fusion and mixed acid dissolution) that have been used at the DWPF for the analysis of SME samples. Earlier testing of the Cs{sub 2}CO{sub 3} method yielded promising results which led to a TTR from Savannah River Remediation, LLC (SRR) to SRNL for additional support and an associated TTQAP to direct the SRNL efforts. A technical report resulting from this work was issued that recommended that the mixed acid method be replaced by the Cs{sub 2}CO{sub 3} method for the measurement of magnesium (Mg), sodium (Na), and zirconium (Zr) with additional testing of the method by DWPF Laboratory being needed before further implementation of the Cs{sub 2}CO{sub 3} method at that laboratory. While the SME acceptability testing of the Isolok does not address any of the open issues remaining after the publication of the recommendation for the replacement of the mixed acid method by the Cs{sub 2}CO{sub 3} method (since those issues are to be addressed by the DWPF Laboratory), the Cs{sub 2}CO{sub 3} testing associated with the Isolok testing does provide additional insight into the performance of the method as conducted by SRNL. The performance is to be investigated by looking to the composition measurement data generated by the samples of a standard glass, the Analytical Reference Glass - 1 (ARG-1), that were prepared by the Cs{sub 2}CO{sub 3} method and included in the SME acceptability testing of the Isolok. The measurements of these samples were presented as part of the study results, but no statistical analysis of these measurements was conducted as part of those results. It is the purpose of this report to provide that analysis, which was supported using JMP Version 7.0.2.

  10. Enhancing the science return of Mars missions via sample preparation, robotic surface exploration and in orbit fuel production

    E-Print Network [OSTI]

    Lamamy, Julien-Alexandre, 1978-

    2004-01-01

    The future of Mars exploration is challenging from multiple points of view. To enhance their science return, future surface probes will most likely be equipped with complex Sample Preparation And Transfer (SPAT) facilities. ...

  11. Mobile on-site sample collection, preparation, and analysis in Iraq. Final report, January-April 1995

    SciTech Connect (OSTI)

    Swahn, I.D.; Brzezinski, J.H.

    1996-11-01

    The U.S. Army Edgewood Research, Development and Engineering Center has developed mobile on-site sample collection, preparation, and analysis equipment to collect environmental samples in highly contaminated areas. This equipment is being used by the United Nations Special Commission at the Baghdad Monitoring and Verification Center (BMVC), which provides long-term monitoring of dual-purpose chemical sites in Iraq, especially those with potential for chemical warfare (CW) production. A mobile laboratory was set-up in the BMVC to prepare and analyze samples collected throughout Iraq. Automatic air samplers were installed at various sites to collect vapor samples on absorption tubes that were analyzed using a gas chromatographic (GC) flame photometric detector (FPD). Mobile sample collection kits were used to collect solid, liquid, air, and wipe samples during challenge inspections. These samples were prepared using a sample preparation kit, which concentrates CW agent, breakdown products, and their precursors in complex matrices down to sub part per million levels for chemical analysis by a GC mass selective detector (MSD). This report describes the problems and solutions encountered with setting up a self-sufficient mobile analytical laboratory. Details of the various components associated with the laboratory and the collection kits are included.

  12. Toward a Fieldable Atomic Mass Spectrometer for Safeguards Applications: Sample Preparation and Ionization

    SciTech Connect (OSTI)

    Barinaga, Charles J.; Hager, George J.; Hart, Garret L.; Koppenaal, David W.; Marcus, R. Kenneth; Jones, Sarah MH; Manard, Benjamin T.

    2014-10-31

    The International Atomic Energy Agency’s (IAEA’s) long-term research and development plan calls for the development of new methods to detect misuse at nuclear fuel cycle facilities such as reprocessing and enrichment plants. At enrichment plants, for example, the IAEA’s contemporary safeguards approaches are based on a combination of routine and random inspections that include collection of UF6 samples from in-process material and selected cylinders for subsequent analyses. These analyses include destructive analysis (DA) in a laboratory (typically by mass spectrometry [MS]) for isotopic characterization, and environmental sampling (ES) for subsequent laboratory elemental and isotopic analysis (also both typically by MS). One area of new method development includes moving this kind of isotope ratio analytical capability for DA and ES activities into the field. Some of the reasons for these developments include timeliness of results, avoidance of hazardous material shipments, and guidance for additional sample collecting. However, this capability does not already exist for several reasons, such as that most lab-based chemical and instrumental methods rely on laboratory infrastructure (highly trained staff, power, space, hazardous material handling, etc.) and require significant amounts of consumables (power, compressed gases, etc.). In addition, there are no currently available, fieldable instruments for atomic or isotope ratio analysis. To address these issues, Pacific Northwest National Laboratory (PNNL) and collaborator, Clemson University, are studying key areas that limit the fieldability of isotope ratio mass spectrometry for atomic ions: sample preparation and ionization, and reducing the physical size of a fieldable mass spectrometer. PNNL is seeking simple and robust techniques that could be effectively used by inspectors who may have no expertise in analytical MS. In this report, we present and describe the preliminary findings for three candidate techniques: matrix-assisted laser desorption/ionization (MALDI) MS, liquid sampling-atmospheric pressure glow discharge (LS-APGD), and laser ablation/ionization (LAI) MS at atmospheric pressure. Potential performance metrics for these techniques will be presented, including detectability, response, isotope ratio accuracy and precision, and ease of use.

  13. Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE

    SciTech Connect (OSTI)

    Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

    2013-06-01

    The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

  14. Low-mass star formation in CG1: a diffraction limited search for pre-main sequence stars next to NX Puppis

    E-Print Network [OSTI]

    Wolfgang Brandner; Jerome Bouvier; Eva K. Grebel; Eric Tessier; Dolf de Winter; Jean-Luc Beuzit

    1995-05-11

    Using adaptive optics at the ESO 3.6m telescope, we obtained diffraction limited JHK-images of the region around the Herbig AeBe star NX Pup. We clearly resolved the close companion (sep. 0.128") to NX Pup -- originally discovered by HST -- and measured its JHK magnitudes. A third object at a separation of 7.0" from NX Pup was identified as a classical T Tauri star so that NX Pup may in fact form a hierarchical triple system. We discuss the evolutionary status of these stars and derive estimates for their spectral types, luminosities, masses and ages.

  15. Low-mass star formation in CG1: a diffraction limited search for pre-main sequence stars next to NX Pup

    E-Print Network [OSTI]

    W. Brandner; J. Bouvier; E. K. Grebel; E. Tessier; D. de Winter; J. -L. Beuzit

    1995-09-08

    Using adaptive optics at the ESO 3.6m telescope, we obtained diffraction limited JHK-images of the region around the Herbig AeBe star NX Pup. We clearly resolved the close companion (sep. 0.128") to NX Pup -- originally discovered by HST -- and measured its JHK magnitudes. A third object at a separation of 7.0" from NX Pup was identified as a classical T Tauri star so that NX Pup may in fact form a hierarchical triple system. We discuss the evolutionary status of these stars and derive estimates for their spectral types, luminosities, masses and ages.

  16. Adjustable virtual pore-size filter for automated sample preparation using acoustic radiation force

    SciTech Connect (OSTI)

    Jung, B; Fisher, K; Ness, K; Rose, K; Mariella, R

    2008-05-22

    We present a rapid and robust size-based separation method for high throughput microfluidic devices using acoustic radiation force. We developed a finite element modeling tool to predict the two-dimensional acoustic radiation force field perpendicular to the flow direction in microfluidic devices. Here we compare the results from this model with experimental parametric studies including variations of the PZT driving frequencies and voltages as well as various particle sizes and compressidensities. These experimental parametric studies also provide insight into the development of an adjustable 'virtual' pore-size filter as well as optimal operating conditions for various microparticle sizes. We demonstrated the separation of Saccharomyces cerevisiae and MS2 bacteriophage using acoustic focusing. The acoustic radiation force did not affect the MS2 viruses, and their concentration profile remained unchanged. With optimized design of our microfluidic flow system we were able to achieve yields of > 90% for the MS2 with > 80% of the S. cerevisiae being removed in this continuous-flow sample preparation device.

  17. Portable sample preparation and analysis system for micron and sub-micron particle characterization using light scattering and absorption spectroscopy

    DOE Patents [OSTI]

    Stark, Peter C. (Los Alamos, NM); Zurek, Eduardo (Barranquilla, CO); Wheat, Jeffrey V. (Fort Walton Beach, FL); Dunbar, John M. (Santa Fe, NM); Olivares, Jose A. (Los Alamos, NM); Garcia-Rubio, Luis H. (Temple Terrace, FL); Ward, Michael D. (Los Alamos, NM)

    2011-07-26

    There is provided a method and device for remote sampling, preparation and optical interrogation of a sample using light scattering and light absorption methods. The portable device is a filtration-based device that removes interfering background particle material from the sample matrix by segregating or filtering the chosen analyte from the sample solution or matrix while allowing the interfering background particles to be pumped out of the device. The segregated analyte is then suspended in a diluent for analysis. The device is capable of calculating an initial concentration of the analyte, as well as diluting the analyte such that reliable optical measurements can be made. Suitable analytes include cells, microorganisms, bioparticles, pathogens and diseases. Sample matrixes include biological fluids such as blood and urine, as well as environmental samples including waste water.

  18. Flat Polishing for TEM sample preparation Things you will need to buy or borrow

    E-Print Network [OSTI]

    Devoret, Michel H.

    with sample Thickness adjustment knob #12;4 Mounting the sample 6. Crystal bond wax melts nicely at 150C, so flake of wax on it. Let the wax melt, then push your sample into it. Use just a small flake of wax. You don't want wax all over the holder. 7. Place the sample holder into the polishing puck, and retract

  19. SLUDGE BATCH 7 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB7 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Pareizs, J.; Hay, M.

    2011-02-22

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Seven (SB7) for processing in the Defense Waste Processing Facility (DWPF). The SB7 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB6. The radionuclide concentrations were measured or estimated in the Tank 51 SB7 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter qualification sample of Tank 51 sludge slurry (HTF-51-10-125) received on September 18, 2010. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. With consultation from the Liquid Waste Organization, the qualification sample was then modified by several washes and decants, which included addition of Pu from H Canyon and sodium nitrite per the Tank Farm corrosion control program. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB7 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2010-0031. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task III.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB7 will be taken and transferred to SRNL for measurement of these radionuclides. The results presented in this report are those necessary for DWPF to assess if the Tank 51 SB7 sample prepared at SRNL meets the requirements for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria evaluation, and the DWPF Solid Waste Characterization Program. Concentrations are given for thirty-four radionuclides along with total alpha and beta activity. Values for total gamma and total gamma plus beta activities are also calculated.

  20. The Sample Preparation Laboratories | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDidDevelopment TopMetathesisSediments and RelatedProjectResearch

  1. LCLS Sample Preparation Laboratory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate student Subtask22 LANSCE Topical UserLAPACKNewLCLSLCLS

  2. Universal nucleic acids sample preparation method for cells, spores and their mixture

    DOE Patents [OSTI]

    Bavykin, Sergei (Darien, IL)

    2011-01-18

    The present invention relates to a method for extracting nucleic acids from biological samples. More specifically the invention relates to a universal method for extracting nucleic acids from unidentified biological samples. An advantage of the presently invented method is its ability to effectively and efficiently extract nucleic acids from a variety of different cell types including but not limited to prokaryotic or eukaryotic cells and/or recalcitrant organisms (i.e. spores). Unlike prior art methods which are focused on extracting nucleic acids from vegetative cell or spores, the present invention effectively extracts nucleic acids from spores, multiple cell types or mixtures thereof using a single method. Important that the invented method has demonstrated an ability to extract nucleic acids from spores and vegetative bacterial cells with similar levels effectiveness. The invented method employs a multi-step protocol which erodes the cell structure of the biological sample, isolates, labels, fragments nucleic acids and purifies labeled samples from the excess of dye.

  3. SLUDGE BATCH 6 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB6 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Bannochie, C.; Bibler, N.; Diprete, D.

    2010-05-21

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Six (SB6) for processing in the Defense Waste Processing Facility (DWPF). The SB6 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB5. The radionuclide concentrations were measured or estimated in the Tank 51 SB6 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter sample of Tank 51 sludge slurry (HTF-51-09-110) taken on October 8, 2009. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. Under the direction of the Liquid Waste Organization it was then modified by eight washes, nine decants, an addition of Pu from Canyon Tank 16.3, and an addition of NaNO{sub 2}. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB6 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2009-0014. The work with this qualification sample is covered by a Task Technical and Quality Assurance Plan and an Analytical Study Plan. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task II.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB6 will be taken and transferred to SRNL for measurement of these radionuclides. The results presented in this report are those necessary for DWPF to assess if the Tank 51 SB6 sample prepared at SRNL meets the requirements for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria evaluation, and the DWPF Solid Waste Characterization Program. The sample is the same as that on which the chemical composition was reported. Concentrations are given for thirty-four radionuclides along with total alpha and beta activity. Values for total gamma and total gamma plus beta activities are also calculated. Results also indicate that 99% of the Tc-99 and at least 90% of the I-129 that could have been in this sludge batch have been removed by chemical processing steps in the SRS Canyons or Tank Farm.

  4. SLUDGE BATCH 5 ACCEPTANCE EVALUATION RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB5 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Bannochie, C; Ned Bibler, N; David Diprete, D

    2008-07-28

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Five (SB5) for processing in the Defense Waste Processing Facility (DWPF). Part of this SB5 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40 to complete the formation of SB5. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB4. The radionuclide concentrations were measured or estimated in the Tank 51 SB5 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter sample of Tank 51 sludge slurry taken on March 21, 2008. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. Under direction of the Liquid Waste Organization it was then modified by five washes, six decants, an addition of Pu/Be from Canyon Tank 16.4, and an addition of NaNO2. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Ta Determining the radionuclide concentrations in this Tank 51 SB5 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2008-0010. The work with this qualification sample is covered by a Task Technical and Quality Assurance Plan and an Analytical Study Plan. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task 2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task 5) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB5 will be taken and transferred to SRNL for measurement of these radionuclides. Data presented in this report represents the measured or estimated radionuclide concentrations obtained from several standard and special analytical methods performed by Analytical Development (AD) personnel within SRNL. The method for I-129 measurement in sludge is described in detail. Most of these methods were performed on solutions resulting from the dissolutions of the slurry samples. Concentrations are given for twenty-nine radionuclides along with total alpha and beta activity. Values for total gamma and total gamma plus beta activities are also calculated. Results also indicate that 98% of the Tc-99 and 92% of the I-129 that could have been in this sludge batch have been removed by chemical processing steps in the SRS Canyons or Tank Farm.

  5. Comparison of SW-846 method 3051 and SW-846 method 7471A for the preparation of solid waste samples for mercury determination

    SciTech Connect (OSTI)

    Giaquinto, J.M.; Essling, A.M.; Keller, J.M.

    1996-08-01

    This report describes experimental studies to evaluate the use of EPA SW-846 method 3051 for preparation and dissolution of solid samples for Hg analysis. The study showed that the method is effective in dissolution of four sample types without significant loss of Hg. Based on results of this study, method 3051 was used for analysis of high radioactive waste samples to obtain results for a number of RCRA regulated metals without the need to utilize a separate sample preparation method (EPA SW-846 method 7471A) specific only for Hg.

  6. Sample M&V Plan from the Texas Workshop: Preparing and Evaluating Measurement and Verification Plans for Energy Performance Contracts in Texas 

    E-Print Network [OSTI]

    Haberl, J. S.

    1999-01-01

    This document contains a sample M&V plan that has been prepared in accordance with the Texas Guidelines for Measurement and Verification for Energy Performance Contracts. This sample M&V plan was extracted from the March 1999 workshop, entitled...

  7. Sample Preparation and Characterisation

    E-Print Network [OSTI]

    Cambridge, University of

    supplied by Corus RD&T. These were from creep tests, and comprised a screw-thread, which was used to hold.49 0.011 0.009 11.15 Mo Ni Nb V W 0.85 0.34 0.01 0.28 0.02 Table 6.2: Composition of creep-tested steel Fracture surface Screw thread Gauge Figure 6.1: Failed creep test specimen. The arrows show the position

  8. Recovery of semi-volatile organic compounds during sample preparation: Compilation for characterization of airborne particulate matter

    SciTech Connect (OSTI)

    Swartz, Erick; Stockburger, Leonard; Gundel, Lara

    2002-05-01

    Semi-volatile compounds present special analytical challenges not met by conventional methods for analysis of ambient particulate matter (PM). Accurate quantification of PM-associated organic compounds requires validation of the laboratory procedures for recovery over a wide volatility and polarity range. To meet these challenges, solutions of n-alkanes (nC{sub 12} to nC{sub 40}) and polycyclic aromatic hydrocarbons PAHs (naphthalene to benzo[ghi]perylene) were reduced in volume from a solvent mixture (equal volumes of hexane, dichloromethane and methanol), to examine recovery after reduction in volume. When the extract solution volume reached 0.5 mL the solvent was entirely methanol, and the recovery averaged 60% for n-alkanes nC{sub 12} to nC{sub 25} and PAHs from naphthalene to chrysene. Recovery of higher MW compounds decreased with MW, because of their insolubility in methanol. When the walls of the flasks were washed with 1 mL of equal parts hexane and dichloromethane (to reconstruct the original solvent composition), the recovery of nC{sub 18} and higher MW compounds increased dramatically, up to 100% for nC{sub 22}-nC{sub 32} and then slowly decreasing with MW due to insolubility. To examine recovery during extraction of the components of the High Capacity Integrated Gas and Particle Sampler, the same standards were used to spike its denuders and filters. For XAD-4 coated denuders and filters, normalized recovery was > 95% after two extractions. Recovery from spiked quartz filters matched the recovery from the coated surfaces for alkanes nC{sub 18} and larger, and for fluoranthene and larger PAHs. Lower MW compounds evaporated from the quartz filter with the spiking solvent. This careful approach allowed quantification of organics by correcting for volatility- and solubility-related sample preparation losses. This method is illustrated for an ambient sample collected with this sampler during the Texas Air Quality Study 2000.

  9. Polysialylated N-Glycans Identified in Human Serum Through Combined Developments in Sample Preparation, Separations and Electrospray ionization-mass spectrometry

    SciTech Connect (OSTI)

    Kronewitter, Scott R.; Marginean, Ioan; Cox, Jonathan T.; Zhao, Rui; Hagler, Clay D.; Shukla, Anil K.; Carlson, Timothy S.; Adkins, Joshua N.; Camp, David G.; Moore, Ronald J.; Rodland, Karin D.; Smith, Richard D.

    2014-09-02

    The N-glycan diversity of human serum glycoproteins, i.e. the human blood serum N-glycome, is complex due to the range of glycan structures potentially synthesizable by human glycosylation enzymes. The reported glycome, however, is limited by methods of sample preparation, available analytical platforms, e.g., based upon electrospray ionization-mass spectrometry (ESI-MS), and software tools for data analysis. In this report, several improvements have been implemented in sample preparation and analysis to extend ESI-MS glycan characterization and to provide an improved view of glycan diversity. Sample preparation improvements include acidified, microwave-accelerated, PNGase F N-glycan release, and sodium borohydride reduction were optimized to improve quantitative yields and conserve the number of glycoforms detected. Two-stage desalting (during solid phase extraction and on the analytical column) increased the sensitivity by reducing analyte signal division between multiple reducing-end-forms or cation adducts. On-line separations were improved by using extended length graphitized carbon columns and adding TFA as an acid modifier to a formic acid/reversed phase gradient which provides additional resolving power and significantly improved desorption of both large and heavily sialylated glycans. To improve MS sensitivity and provide gentler ionization conditions at the source-MS interface, subambient pressure ionization with nanoelectrospray (SPIN) has been utilized. When method improvements are combined together with the Glycomics Quintavariate Informed Quantification (GlyQ-IQ) recently described1 these technologies demonstrate the ability to significantly extend glycan detection sensitivity and provide expanded glycan coverage. We demonstrate application of these advances in the context of the human serum glycome, and for which our initial observations include detection of a new class of heavily sialylated N-glycans, including polysialylated N-glycans.

  10. Optical properties of (162173) 1999 JU3: in preparation for the JAXA Hayabusa 2 sample return mission

    SciTech Connect (OSTI)

    Ishiguro, Masateru [Department of Physics and Astronomy, Seoul National University, Gwanak, Seoul 151-742 (Korea, Republic of); Kuroda, Daisuke [Okayama Astrophysical Observatory, National Astronomical Observatory of Japan, Asakuchi, Okayama 719-0232 (Japan); Hasegawa, Sunao; Abe, Masanao; Yoshikawa, Makoto [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Sagamihara, Kanagawa 252-5210 (Japan); Kim, Myung-Jin [Department of Astronomy, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Choi, Young-Jun [Korea Astronomy and Space Science Institute, 776 Daedeokdae-ro, Yuseong-gu, Daejeon 305-348 (Korea, Republic of); Moskovitz, Nicholas [Lowell Observatory, 1400 W. Mars Hill Road, Flagstaff, AZ 86001 (United States); Abe, Shinsuke [Department of Aerospace Engineering, Nihon University, 7-24-1 Narashinodai Funabashi, Chiba 274-8501 (Japan); Pan, Kang-Sian [Institute of Astronomy, National Central University, 300 Jhongda Road, Jhongli, Taoyuan 32001, Taiwan (China); Takahashi, Jun; Takagi, Yuhei; Arai, Akira [Nishi-Harima Astronomical Observatory, Center for Astronomy, University of Hyogo, Sayo, Hyogo 679-5313 (Japan); Tokimasa, Noritaka [Sayo Town Office, 2611-1 Sayo, Sayo-cho, Sayo, Hyogo 679-5380 (Japan); Hsieh, Henry H. [Academia Sinica Institute of Astronomy and Astrophysics, Roosevelt Road, Taipei 10617, Taiwan (China); Thomas-Osip, Joanna E.; Osip, David J. [The Observatories of the Carnegie Institute of Washington, Las Campanas Observatory, Colina El Pino, Casilla 601, La Serena (Chile); Urakawa, Seitaro [Bisei Spaceguard Center, Japan Spaceguard Association, 1716-3 Okura, Bisei-cho, Ibara, Okayama 714-1411 (Japan); Hanayama, Hidekazu [Ishigakijima Astronomical Observatory, National Astronomical Observatory of Japan, 1024-1 Arakawa, Ishigaki, Okinawa 907-0024 (Japan); Sekiguchi, Tomohiko [Department of Teacher Training, Hokkaido University of Education, 9 Hokumon, Asahikawa 070-8621 (Japan); and others

    2014-09-01

    We investigated the magnitude-phase relation of (162173) 1999 JU3, a target asteroid for the JAXA Hayabusa 2 sample return mission. We initially employed the International Astronomical Union's H-G formalism but found that it fits less well using a single set of parameters. To improve the inadequate fit, we employed two photometric functions: the Shevchenko and Hapke functions. With the Shevchenko function, we found that the magnitude-phase relation exhibits linear behavior in a wide phase angle range (? = 5°-75°) and shows weak nonlinear opposition brightening at ? < 5°, providing a more reliable absolute magnitude of H {sub V} = 19.25 ± 0.03. The phase slope (0.039 ± 0.001 mag deg{sup –1}) and opposition effect amplitude (parameterized by the ratio of intensity at ? = 0.°3 to that at ? = 5°, I(0.°3)/I(5°) = 1.31 ± 0.05) are consistent with those of typical C-type asteroids. We also attempted to determine the parameters for the Hapke model, which are applicable for constructing the surface reflectance map with the Hayabusa 2 onboard cameras. Although we could not constrain the full set of Hapke parameters, we obtained possible values, w = 0.041, g = –0.38, B {sub 0} = 1.43, and h = 0.050, assuming a surface roughness parameter ?-bar = 20°. By combining our photometric study with a thermal model of the asteroid, we obtained a geometric albedo of p {sub v} = 0.047 ± 0.003, phase integral q = 0.32 ± 0.03, and Bond albedo A {sub B} = 0.014 ± 0.002, which are commensurate with the values for common C-type asteroids.

  11. Sample Preparation Laboratory Training - Course 204 | Sample Preparation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of

  12. Chemical Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene NetworkNuclear SecurityChattan ooga Eag le ForChemCamChemical

  13. Chemical Resources | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMayARM-0501 Marine StratusChemCamChemical Resources

  14. Geoscience Laboratory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunities NuclearlongGeneralGeorge T.

  15. Laboratory Access | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate student Subtask22BackgroundLabSanta'sNewNaturalAccess

  16. Laboratory Waste | Sample Preparation Laboratories

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScience (SC)Planning Process Combined

  17. Equipment Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesof Energy ServicesEnergy4th Quarter 2012 for

  18. Stable isotope analysis of organic carbon in small (mg C) samples and dissolved organic matter using a GasBench preparation device

    E-Print Network [OSTI]

    Gilli, Adrian

    on freeze-dried samples of DOC. The low detection limit and the ease with which it can be combined,4] Modifications to the EA system, including cryogenically trapping the CO2 resulting from sample combustion

  19. Introduction Preparation

    E-Print Network [OSTI]

    Introduction Motivation Preparation Notos' Components Results Conclusions and Future Work Building Problem Description and Motivation Preparation Notation, Passive DNS trends and Anchor Classes Notos Reputation Results Conclusions and Future Work Special thanks to: Damballa Passive DNS data, Malware and BL

  20. Diffraction limited focusing and routing of gap plasmons by a...

    Office of Scientific and Technical Information (OSTI)

    70NANB14H030; 70NANB14H259; DMR-1104884 Type: Accepted Manuscript Journal Name: Optics Express Additional Journal Information: Journal Volume: 23; Journal Issue: 17; Journal...

  1. Diffraction limited focusing and routing of gap plasmons by a

    Office of Scientific and Technical Information (OSTI)

    Nanoscale Science and Technology. 42 ENGINEERING electro-optical devices; integrated optics devices; optical microelectromechanical devices; plasmonics; nanophotonics and...

  2. Sample Preparation of Biofluids Using Microscale Vortices

    E-Print Network [OSTI]

    Mach, Albert

    2012-01-01

    microorganism identification. This process usually takes 2-3 days, and can be suboptimal in terms of pathogen

  3. Sample Preparation of Biofluids Using Microscale Vortices

    E-Print Network [OSTI]

    Mach, Albert

    2012-01-01

    Annual Review of Analytical Chemistry, vol. 3, no. 1, pp.Capture Devices,” Analytical Chemistry, vol. 84, no. 8, pp.Inertial Focusing,” Analytical Chemistry , vol. 80, no. 6,

  4. 7 SAMPLING AND PREPARATION FOR LABORATORY MEASUREMENTS

    E-Print Network [OSTI]

    . Scanning is an evaluation technique performed by moving a portable radiation detection instrument at a constant speed and distance above the surface to semi-quantitatively detect elevated areas of radiation time. Commonly used radiation detection and measuring equipment for radiological survey field

  5. Sample preparation system for microfluidic applications

    DOE Patents [OSTI]

    Mosier, Bruce P. (San Francisco, CA); Crocker, Robert W. (Fremont, CA); Patel, Kamlesh D. (Dublin, CA); Harnett, Cindy K. (Livermore, CA)

    2007-05-08

    An apparatus that couples automated injection with flow feedback to provide nanoliter accuracy in controlling microliter volumes. The apparatus comprises generally a source of hydraulic fluid pressure, a fluid isolator joined to the outlet of the hydraulic pressure source and a flow sensor to provide pressure-driven analyte metering. For operation generally and particularly in microfluidic systems the hydraulic pressure source is typically an electrokinetic (EK) pump that incorporates gasless electrodes. The apparatus is capable of metering sub-microliter volumes at flowrates of 1 100 .mu.L/min into microsystem load pressures of up to 1000 50 psi, respectively. Flowrates can be specified within 0.5 .mu.L/min and volumes as small as 80 nL can be metered.

  6. Protein Sample Preparation and Analysis Application Manual

    E-Print Network [OSTI]

    Lebendiker, Mario

    in North America, Europe, and Asia, Pall provides enabling and process enhancing technologies to industries ranging from medical/pharmaceutical, aerospace, automotive, environmental, microelectronics, and semiconductors, to municipal and industrial water treatment, fuels, chemicals, energy, and food and beverages

  7. Available for Checkout Equipment Inventory | Sample Preparation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass andAtomsVehicles and Fuels

  8. BCM 1 Equipment Inventory | Sample Preparation Laboratories

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  9. BCM 2 Equipment Inventory | Sample Preparation Laboratories

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  10. LCLS Equipment Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  11. LCLS Prep Lab Images | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  12. Laboratory Equipment & Supplies | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  13. Geoscience Equipment Inventory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LET IonizingGeorge B.Thousand CubicGeoscience

  14. Geoscience Prep Lab Slideshow | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LET IonizingGeorge B.Thousand

  15. Sample introducing apparatus and sample modules for mass spectrometer

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1993-01-01

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus.

  16. Sample introducing apparatus and sample modules for mass spectrometer

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1993-12-21

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus. 5 figures.

  17. Preparing Your

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgram Guidelines This document w1.½tankSurfaceSciTechenergyand*Prepare

  18. Core sampling system spare parts assessment

    SciTech Connect (OSTI)

    Walter, E.J.

    1995-04-04

    Soon, there will be 4 independent core sampling systems obtaining samples from the underground tanks. It is desirable that these systems be available for sampling during the next 2 years. This assessment was prepared to evaluate the adequacy of the spare parts identified for the core sampling system and to provide recommendations that may remediate overages or inadequacies of spare parts.

  19. Tank 12H residuals sample analysis report

    SciTech Connect (OSTI)

    Oji, L. N.; Shine, E. P.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.

    2015-06-11

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 12H final characterization samples to determine the residual tank inventory prior to grouting. Eleven Tank 12H floor and mound residual material samples and three cooling coil scrape samples were collected and delivered to SRNL between May and August of 2014.

  20. Sampling box

    DOE Patents [OSTI]

    Phillips, Terrance D. (617 Chestnut Ct., Aiken, SC 29803); Johnson, Craig (100 Midland Rd., Oak Ridge, TN 37831-0895)

    2000-01-01

    An air sampling box that uses a slidable filter tray and a removable filter cartridge to allow for the easy replacement of a filter which catches radioactive particles is disclosed.

  1. Use of Electrodeposition for Sample Preparation and Rejection Rate Prediction for Assay of Electroformed Ultra High Purity Copper for 232Th and 238U Prior to Inductively Coupled Plasma Mass Spectrometry (ICP/MS)

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Aalseth, Craig E.; Brodzinski, Ronald L.; Day, Anthony R.; Farmer, Orville T.; Hossbach, Todd W.; McIntyre, Justin I.; Miley, Harry S.; Mintzer, Esther E.; Seifert, Allen; Smart, John E.; Warren, Glen A.

    2008-07-01

    The search for neutrinoless double beta decay in 76Ge has driven the need for ultra-low background Ge detectors shielded by electroformed copper of ultra-high radiopurity (<0.1µBq/kg). Although electrodeposition processes are almost sophisticated enough to produce copper of this purity, to date there are no methods sensitive enough to assay it. Inductively-coupled plasma mass spectrometry (ICP/MS) can detect thorium and uranium at femtogram levels, but in the past, this assay has been hindered by high copper concentrations in the sample. Electrodeposition of copper samples removes copper from the solution while selectively concentrating thorium and uranium contaminants to be assayed by ICP/MS. Spiking 232Th and 238U into the plating bath simulates low purity copper and allows for the calculation of the electrochemical rejection rate of thorium and uranium in the electroplating system. This rejection value will help to model plating bath chemistry.

  2. Sampling apparatus

    DOE Patents [OSTI]

    Gordon, N.R.; King, L.L.; Jackson, P.O.; Zulich, A.W.

    1989-07-18

    A sampling apparatus is provided for sampling substances from solid surfaces. The apparatus includes first and second elongated tubular bodies which telescopically and sealingly join relative to one another. An absorbent pad is mounted to the end of a rod which is slidably received through a passageway in the end of one of the joined bodies. The rod is preferably slidably and rotatably received through the passageway, yet provides a selective fluid tight seal relative thereto. A recess is formed in the rod. When the recess and passageway are positioned to be coincident, fluid is permitted to flow through the passageway and around the rod. The pad is preferably laterally orientable relative to the rod and foldably retractable to within one of the bodies. A solvent is provided for wetting of the pad and solubilizing or suspending the material being sampled from a particular surface. 15 figs.

  3. Small sample feature selection 

    E-Print Network [OSTI]

    Sima, Chao

    2007-09-17

    that the correction factor is a function of the dimensionality. The estimated standard deviations for the bolstering kernels are thus given by: ?i = ˆd(yi) ?p,i , for i = 1,...,n. (2.8) Clearly, as the number of samples in the training data increases, the standard de..., the DeArray software of the National Human Genome Research Institute calculates a multi-faceted quality metric for each spot [25]. This quality problem is a result of imperfections in RNA preparation, hybridization to the arrays, scanning, and also...

  4. Quantum rejection sampling

    E-Print Network [OSTI]

    Maris Ozols; Martin Roetteler; Jérémie Roland

    2011-12-13

    Rejection sampling is a well-known method to sample from a target distribution, given the ability to sample from a given distribution. The method has been first formalized by von Neumann (1951) and has many applications in classical computing. We define a quantum analogue of rejection sampling: given a black box producing a coherent superposition of (possibly unknown) quantum states with some amplitudes, the problem is to prepare a coherent superposition of the same states, albeit with different target amplitudes. The main result of this paper is a tight characterization of the query complexity of this quantum state generation problem. We exhibit an algorithm, which we call quantum rejection sampling, and analyze its cost using semidefinite programming. Our proof of a matching lower bound is based on the automorphism principle which allows to symmetrize any algorithm over the automorphism group of the problem. Our main technical innovation is an extension of the automorphism principle to continuous groups that arise for quantum state generation problems where the oracle encodes unknown quantum states, instead of just classical data. Furthermore, we illustrate how quantum rejection sampling may be used as a primitive in designing quantum algorithms, by providing three different applications. We first show that it was implicitly used in the quantum algorithm for linear systems of equations by Harrow, Hassidim and Lloyd. Secondly, we show that it can be used to speed up the main step in the quantum Metropolis sampling algorithm by Temme et al.. Finally, we derive a new quantum algorithm for the hidden shift problem of an arbitrary Boolean function and relate its query complexity to "water-filling" of the Fourier spectrum.

  5. International perspectives on coal preparation

    SciTech Connect (OSTI)

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  6. Digital microfluidic sample preparation for biological mass spectrometry 

    E-Print Network [OSTI]

    Stokes, Adam A.

    2011-06-27

    The use of mass spectrometry in the biosciences has undergone huge growth in re- cent years due to sustained effort in the development of new ionisation techniques, more powerful mass analysers and better bioinformatic ...

  7. BCM1 Prep Lab Slideshow | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass andAtomsVehicles and FuelsjBBEE Public1

  8. BCM2 Prep Lab Slideshow | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass andAtomsVehicles and FuelsjBBEE Public1BCM2 Prep

  9. Biology Chemistry & Material Science Laboratory 1 | Sample Preparation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & InspectionsBeryllium andSamplerBiological Imaging

  10. Biology Chemistry & Material Science Laboratory 2 | Sample Preparation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & InspectionsBeryllium andSamplerBiological ImagingLaboratories

  11. Modular microfluidic system for biological sample preparation (Patent) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport)Fermentative Activity

  12. Modular microfluidic system for biological sample preparation (Patent) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport)Fermentative ActivitySciTech Connect Modular microfluidic

  13. Preparation of acetaldehyde

    DOE Patents [OSTI]

    Tustin, G.C.; Depew, L.S.

    1997-10-21

    Disclosed is a process for the preparation of acetaldehyde by the hydrogenation of ketene in the presence of a transition metal hydrogenation catalyst.

  14. Method for preparing Pb-. beta. ''-alumina ceramic

    DOE Patents [OSTI]

    Hellstrom, E.E.

    1984-08-30

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-..beta..''-alumina ceramic from Na-..beta..''-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-..beta..''-alumina ceramic that is substantially crack-free.

  15. Aerosol preparation of intact lipoproteins

    DOE Patents [OSTI]

    Benner, W. Henry (Danville, CA); Krauss, Ronald M (Berkeley, CA); Blanche, Patricia J (Berkeley, CA)

    2012-01-17

    A medical diagnostic method and instrumentation system for analyzing noncovalently bonded agglomerated biological particles is described. The method and system comprises: a method of preparation for the biological particles; an electrospray generator; an alpha particle radiation source; a differential mobility analyzer; a particle counter; and data acquisition and analysis means. The medical device is useful for the assessment of human diseases, such as cardiac disease risk and hyperlipidemia, by rapid quantitative analysis of lipoprotein fraction densities. Initially, purification procedures are described to reduce an initial blood sample to an analytical input to the instrument. The measured sizes from the analytical sample are correlated with densities, resulting in a spectrum of lipoprotein densities. The lipoprotein density distribution can then be used to characterize cardiac and other lipid-related health risks.

  16. Double patterning HSQ processes of zone plates for 10 nm diffraction limited performance

    E-Print Network [OSTI]

    Chao, Weilun

    2009-01-01

    set followed by electroplating. Our internally developedusing PMMA and gold electroplating, which were overlaid andsubstrate needed for the electroplating step. We developed a

  17. Multi-wavelength diffraction-limited imaging of the evolved carbon star IRC +10216, II

    E-Print Network [OSTI]

    P. G. Tuthill; J. D. Monnier; W. C. Danchi

    2005-03-09

    High angular resolution images of IRC +10216 taken at various bandpasses within the near-infrared h, k & l bands are presented. The maps have the highest angular resolution yet recovered, and were reconstructed from interferometric measurements obtained at the Keck 1 telescope in 1997 December and 1998 April, forming a subset of a 7-epoch monitoring program presented earlier [paper 1]. Systematic changes with observing wavelength are found and discussed in context of present geometrical models for the circumstellar envelope. With these new high-resolution, multi-wavelength data and contemporaneous photometry, we also re-visit the hypothesis that the bright compact Core of the nebula (component `A') marks the location of the central carbon star. We find that directly measured properties of the Core (angular size, flux density, color temperature) are consistent with a reddened carbon star photosphere (line-of-sight tau=5.3).

  18. An experimental apparatus for diffraction-limites soft x-ray nanofocusing

    E-Print Network [OSTI]

    Merthe, Daniel

    2012-01-01

    thermal variations and mechanical vibrations. This sectionresponse to the mechanical vibrations of the facility.mechanical actuation, position drift, vibration and the

  19. Guide to preparing SAND Reports and other communication products.

    SciTech Connect (OSTI)

    Not Available

    2009-02-01

    This guide describes the R&A process, Common Look and Feel requirements, and preparation and publishing procedures for communication products at Sandia National Laboratories. Samples of forms and examples of published communications products are provided.

  20. EXPORT CONTROLS PREPARED BY

    E-Print Network [OSTI]

    Sorin, Eric J.

    EXPORT CONTROLS MANUAL PREPARED BY: Office of General Counsel The California State University SEPTEMBER 2012 #12; Export Controls Manual Table of Contents I. INTRODUCTION ......................................................................................................... 1 II. HISTORY OF EXPORT CONTROLS

  1. Review: Preparing for Climate Change

    E-Print Network [OSTI]

    Kunnas, Jan

    2013-01-01

    Review: Preparing for Climate Change By Michael D.Stephen, Preparing for Climate Change. A Boston Review Book.alkaline paper. “Climate change is inevitable, but disaster

  2. Preparation of ethylenediamine dinitrate

    DOE Patents [OSTI]

    Lee, K.

    1984-05-17

    Method for the preparation of ethylenediamine dinitrate. Ethylenediamine dinitrate, a useful explosive, may readily be prepared by solvent extraction of nitrate ion from an acidic aqueous solution thereof using a high-molecular-weight, water-insoluble amine dissolved in an organic solvent, and reacting the resulting oraganic solution with ethylenediamine. The process of the instant invention avoids the use of concentrated nitric acid, as is currently practiced, resulting in a synthesis which is far less hazardous, especially for large quantities of the explosive, and more efficient.

  3. Preparation of ethylenediamine dinitrate

    DOE Patents [OSTI]

    Lee, Kien-yin (Los Alamos, NM)

    1985-01-01

    Method for the preparation of ethylenediamine dinitrate. Ethylenediamine dinitrate, a useful explosive, may readily be prepared by solvent extraction of nitrate ion from an acidic aqueous solution thereof using a high-molecular-weight, water-insoluble amine dissolved in an organic solvent, and reacting the resulting organic solution with ethylenediamine. The process of the instant invention avoids the use of concentrated nitric acid, as is currently practiced, resulting in a synthesis which is far less hazardous especially for large quantities of the explosive, and more efficient.

  4. Preparation of hydrophobic coatings

    DOE Patents [OSTI]

    Branson, Eric D. (Albuquerque, NM); Shah, Pratik B. (Albuquerque, NM); Singh, Seema (Rio Rancho, NM); Brinker, C. Jeffrey (Albuquerque, NM)

    2009-02-03

    A method for preparing a hydrophobic coating by preparing a precursor sol comprising a metal alkoxide, a solvent, a basic catalyst, a fluoroalkyl compound and water, depositing the precursor sol as a film onto a surface, such as a substrate or a pipe, heating, the film and exposing the film to a hydrophobic silane compound to form a hydrophobic coating with a contact angle greater than approximately 150.degree.. The contact angle of the film can be controlled by exposure to ultraviolet radiation to reduce the contact angle and subsequent exposure to a hydrophobic silane compound to increase the contact angle.

  5. ARTICULATION AGREEMENT Teacher Preparation

    E-Print Network [OSTI]

    Hammack, Richard

    ARTICULATION AGREEMENT For Teacher Preparation Between J. Sargeant Reynolds Community College of Interdisciplinary Studies degree in Liberal Studies for Early and Elementary Education (LSEE) and Master of Teaching degree in Elementary Education; · Bachelor of Arts degree in English or History and the Master

  6. Experiments: Preparation and Measurement

    E-Print Network [OSTI]

    Neumaier, Arnold

    the experimental set­up und the results of performing the experiment. Again, this is part of human cultureExperiments: Preparation and Measurement by Arnold Neumaier, Vienna March 1996 Abstract Introduction Experiments, properly arranged, provide information about a physical system by suitable

  7. Preparation of graphitic articles

    DOE Patents [OSTI]

    Phillips, Jonathan; Nemer, Martin; Weigle, John C.

    2010-05-11

    Graphitic structures have been prepared by exposing templates (metal, metal-coated ceramic, graphite, for example) to a gaseous mixture that includes hydrocarbons and oxygen. When the template is metal, subsequent acid treatment removes the metal to yield monoliths, hollow graphitic structures, and other products. The shapes of the coated and hollow graphitic structures mimic the shapes of the templates.

  8. Preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-03-24

    This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

  9. Prepared for Outlook 2020

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Northern British Columbia: A Vision for Prosperity Prepared for Outlook 2020: Shaping BC Trust #12;2 Northern British Columbia's Vision for Prosperity Outlook 2020: Shaping BC's Economic and the emerging bio-energy industry..................................... 15 2.2 Mining, oil and gas

  10. Stakeholder Interview Prepared for

    E-Print Network [OSTI]

    Interviews By GE Global Research For University of Hawaii Hawaii Natural Energy Institute 1680 East-West RoadStakeholder Interview Report Prepared for U.S. Department of Energy Office of Electricity Delivery and Energy Reliability Under Award No. DE-FC-06NT42847 Task 1. Deliverable #1 ­ Results of Stakeholder

  11. Porous electrode preparation method

    DOE Patents [OSTI]

    Arons, R.M.; Dusek, J.T.

    1983-10-18

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity. 2 figs.

  12. Porous electrode preparation method

    DOE Patents [OSTI]

    Arons, Richard M. (Wheaton, IL); Dusek, Joseph T. (Downers Grove, IL)

    1983-01-01

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  13. Preparation of fibrous palladium

    SciTech Connect (OSTI)

    Silver, G.L.; Seabaugh, P.W.; Leahy, B.T.; Werkmeister, D.W.; Martin, F.S.; Friedlander, H.N.

    1988-06-15

    Acrylic fibers (pan fibers) absorb palladium from a hot solution of palladium nitrate in nitric acid. When palladium-loaded acrylic fibers are burned, fibers consisting of palladium and palladium oxide are formed. Reduction of this mixture with hydrogen produces fibers of palladium metal. The fibers may be compressed into pellets which offer less resistance to flowing hydrogen than similar pellets prepared by compressing commercial palladium powder. 9 refs., 12 figs., 5 tabs.

  14. TORIS Data Preparation Guidelines

    SciTech Connect (OSTI)

    Guinn, H.; Remson, D.

    1999-03-11

    The objective of this manual is to present guidelines and procedures for the preparation of new data for the Tertiary Oil Recovery Information System (TORIS) data base. TORIS is an analytical system currently maintained by the Department of Energy's (DOE) Bartlesville Project Office. It uses an extensive field- and reservoir-level data base to evaluate the technical and economic recovery potential of specific crude oil reservoirs.

  15. Rapid determination of actinides in seawater samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.; Utsey, Robin C.; McAlister, Daniel R.

    2014-03-09

    A new rapid method for the determination of actinides in seawater samples has been developed at the Savannah River National Laboratory. The actinides can be measured by alpha spectrometry or inductively-coupled plasma mass spectrometry. The new method employs novel pre-concentration steps to collect the actinide isotopes quickly from 80 L or more of seawater. Actinides are co-precipitated using an iron hydroxide co-precipitation step enhanced with Ti+3 reductant, followed by lanthanum fluoride co-precipitation. Stacked TEVA Resin and TRU Resin cartridges are used to rapidly separate Pu, U, and Np isotopes from seawater samples. TEVA Resin and DGA Resin were used tomore »separate and measure Pu, Am and Cm isotopes in seawater volumes up to 80 L. This robust method is ideal for emergency seawater samples following a radiological incident. It can also be used, however, for the routine analysis of seawater samples for oceanographic studies to enhance efficiency and productivity. In contrast, many current methods to determine actinides in seawater can take 1–2 weeks and provide chemical yields of ~30–60 %. This new sample preparation method can be performed in 4–8 h with tracer yields of ~85–95 %. By employing a rapid, robust sample preparation method with high chemical yields, less seawater is needed to achieve lower or comparable detection limits for actinide isotopes with less time and effort.« less

  16. Rain sampling device

    DOE Patents [OSTI]

    Nelson, D.A.; Tomich, S.D.; Glover, D.W.; Allen, E.V.; Hales, J.M.; Dana, M.T.

    1991-05-14

    The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of the precipitation from the chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device. 11 figures.

  17. Rain sampling device

    DOE Patents [OSTI]

    Nelson, Danny A. (Richland, WA); Tomich, Stanley D. (Richland, WA); Glover, Donald W. (Prosser, WA); Allen, Errol V. (Benton City, WA); Hales, Jeremy M. (Kennewick, WA); Dana, Marshall T. (Richland, WA)

    1991-01-01

    The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of said precipitation from said chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device.

  18. forEnvironmentalManagementofMilitaryLands Guide to Sampling Soil

    E-Print Network [OSTI]

    forEnvironmentalManagementofMilitaryLands Guide to Sampling Soil Compaction Using Hand-Held Soil Fort Collins, CO 80523-1490 January 2004 #12;#12;1 Guide to Sampling Soil Compaction Using Hand-Held Soil Penetrometers1 Prepared by Dave Jones and Matt Kunze Center for Environmental Management

  19. Preparation of tungsten oxide

    DOE Patents [OSTI]

    Bulian, Christopher J. (Yankton, SD); Dye, Robert C. (Los Alamos, NM); Son, Steven F. (Los Alamos, NM); Jorgensen, Betty S. (Jemez Springs, NM); Perry, W. Lee (Jemez Springs, NM)

    2009-09-22

    Tungsten trioxide hydrate (WO.sub.3.H.sub.2O) was prepared from a precursor solution of ammonium paratungstate in concentrated aqueous hydrochloric acid. The precursor solution was rapidly added to water, resulting in the crash precipitation of a yellow white powder identified as WO.sub.3.H.sub.2O nanosized platelets by x-ray diffraction and scanning electron microscopy. Annealing of the powder at 200.degree. C. provided cubic phase WO.sub.3 nanopowder, and at 400.degree. C. provided WO.sub.3 nanopowder as a mixture of monoclinic and orthorhombic phases.

  20. Performance evaluation soil samples utilizing encapsulation technology

    DOE Patents [OSTI]

    Dahlgran, James R. (Idaho Falls, ID)

    1999-01-01

    Performance evaluation soil samples and method of their preparation using encapsulation technology to encapsulate analytes which are introduced into a soil matrix for analysis and evaluation by analytical laboratories. Target analytes are mixed in an appropriate solvent at predetermined concentrations. The mixture is emulsified in a solution of polymeric film forming material. The emulsified solution is polymerized to form microcapsules. The microcapsules are recovered, quantitated and introduced into a soil matrix in a predetermined ratio to form soil samples with the desired analyte concentration.

  1. Performance evaluation soil samples utilizing encapsulation technology

    DOE Patents [OSTI]

    Dahlgran, J.R.

    1999-08-17

    Performance evaluation soil samples and method of their preparation uses encapsulation technology to encapsulate analytes which are introduced into a soil matrix for analysis and evaluation by analytical laboratories. Target analytes are mixed in an appropriate solvent at predetermined concentrations. The mixture is emulsified in a solution of polymeric film forming material. The emulsified solution is polymerized to form microcapsules. The microcapsules are recovered, quantitated and introduced into a soil matrix in a predetermined ratio to form soil samples with the desired analyte concentration. 1 fig.

  2. Sample Proficiency Test exercise

    SciTech Connect (OSTI)

    Alcaraz, A; Gregg, H; Koester, C

    2006-02-05

    The current format of the OPCW proficiency tests has multiple sets of 2 samples sent to an analysis laboratory. In each sample set, one is identified as a sample, the other as a blank. This method of conducting proficiency tests differs from how an OPCW designated laboratory would receive authentic samples (a set of three containers, each not identified, consisting of the authentic sample, a control sample, and a blank sample). This exercise was designed to test the reporting if the proficiency tests were to be conducted. As such, this is not an official OPCW proficiency test, and the attached report is one method by which LLNL might report their analyses under a more realistic testing scheme. Therefore, the title on the report ''Report of the Umpteenth Official OPCW Proficiency Test'' is meaningless, and provides a bit of whimsy for the analyses and readers of the report.

  3. Sample Environments at Sector 30

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Designs Two standard sample holder designs are below. Copper sample holder from ARS. ARS sample holde diagram picture Aluminum sample holder - custom design Al design Al pic...

  4. ARTIFACT FORMATION DURING NEUTRALIZATION OF TANK 50 SAMPLES

    SciTech Connect (OSTI)

    Crump, S.; Young, J.

    2014-08-01

    Degradation products have been identified in the extracts of Tank 50 samples analyzed by semivolatile organic compound analysis (SVOA) using gas chromatography/mass spectrometry (GC/MS). These materials, identified as short chain alkyl alcohols, were formed by acidification during sample preparation. A number of questions were raised about the formation of these and other materials reported in Tank 50 surface samples, and this report serves to address these questions.

  5. Method to prepare Semtex

    SciTech Connect (OSTI)

    Alcaraz, A; Dougan, A

    2006-11-26

    This procedure requires the binder and uncoated RDX be prepared in separate steps, see Figure 1: (1) The binder and dye are mixed by agitation with a water-insoluble organic solvent (e.g., toluene), I; (2) The RDX/PETN is agitated thoroughly with water, II; (3) The binder solution I is added to the RDX/water mixture at II with thorough mixing to form a slurry III; (4) In the next step the solvent is distilled off at IV leaving resulting granules; (5) The next step is followed by filtration at V, which may be done by vacuum; (6) The composition is then dried at VI to a dough-like consistency.

  6. Procedures for sampling radium-contaminated soils

    SciTech Connect (OSTI)

    Fleischhauer, H.L.

    1985-10-01

    Two procedures for sampling the surface layer (0 to 15 centimeters) of radium-contaminated soil are recommended for use in remedial action projects. Both procedures adhere to the philosophy that soil samples should have constant geometry and constant volume in order to ensure uniformity. In the first procedure, a ''cookie cutter'' fashioned from pipe or steel plate, is driven to the desired depth by means of a slide hammer, and the sample extracted as a core or plug. The second procedure requires use of a template to outline the sampling area, from which the sample is obtained using a trowel or spoon. Sampling to the desired depth must then be performed incrementally. Selection of one procedure over the other is governed primarily by soil conditions, the cookie cutter being effective in nongravelly soils, and the template procedure appropriate for use in both gravelly and nongravelly soils. In any event, a minimum sample volume of 1000 cubic centimeters is recommended. The step-by-step procedures are accompanied by a description of the minimum requirements for sample documentation. Transport of the soil samples from the field is then addressed in a discussion of the federal regulations for shipping radioactive materials. Interpretation of those regulations, particularly in light of their application to remedial action soil-sampling programs, is provided in the form of guidance and suggested procedures. Due to the complex nature of the regulations, however, there is no guarantee that our interpretations of them are complete or entirely accurate. Preparation of soil samples for radium-226 analysis by means of gamma-ray spectroscopy is described.

  7. Environmental Programs Procedure Preparation, Revision, Review...

    Energy Savers [EERE]

    Environmental Programs Procedure Preparation, Revision, Review, Approval, and Use Environmental Programs Procedure Preparation, Revision, Review, Approval, and Use The documents...

  8. Sampling system and method

    DOE Patents [OSTI]

    Decker, David L.; Lyles, Brad F.; Purcell, Richard G.; Hershey, Ronald Lee

    2013-04-16

    The present disclosure provides an apparatus and method for coupling conduit segments together. A first pump obtains a sample and transmits it through a first conduit to a reservoir accessible by a second pump. The second pump further conducts the sample from the reservoir through a second conduit.

  9. IDENTIFICATION Your Sample Box

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    to Virginia Tech Soil Testing Lab, 145 Smyth Hall (MC 0465), 185 Ag Quad Ln, Blacksburg VA 24061, in sturdy, K, Ca, Mg, Zn, Mn, Cu, Fe, B, and soluble salts) NoCharge $16.00 Organic Matter $4.00 $6.00 Fax with soil sample and form; make check or money order payable to "Treasurer, Virginia Tech." COST PER SAMPLE

  10. Free Standing Soil Sample

    E-Print Network [OSTI]

    Stuart, Steven J.

    Free Standing Soil Sample Kiosks Clemson University Cooperative Extension Service Reportto of Richland County, Jackie Kopack Jordan has partnered with local garden centers to provide free standing soil sample collections sites. The free standing kiosks are located at three local garden centers. Woodley

  11. Process for preparing liquid wastes

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

    1997-01-01

    A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

  12. CITIZENSHIP NOW! EXAM PREPARATION HANDBOOK

    E-Print Network [OSTI]

    Qiu, Weigang

    CITIZENSHIP NOW! EXAM PREPARATION HANDBOOK #12;washington oregon nevada idaho montananorthdakota to offer targeted programs--Si Se Puede!, a joint education initiative between CUNY and the Consulate NOW! EXAM PREPARATION HANDBOOK #12;T he City University of New York is the nation's largest urban

  13. Water Sample Concentrator

    ScienceCinema (OSTI)

    Idaho National Laboratory

    2010-01-08

    Automated portable device that concentrates and packages a sample of suspected contaminated water for safe, efficient transport to a qualified analytical laboratory. This technology will help safeguard against pathogen contamination or chemical and biolog

  14. Liquid scintillator sampling calorimetry 

    E-Print Network [OSTI]

    Dudgeon, R. Greg

    1994-01-01

    This research was supported by the Department of Energy to investigate a new sampling calorimeter technology for the high intensity regions of the Superconducting Supercollider. The technology involved using liquid scintillator filled glass tubes...

  15. Sample Changes and Issues

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    EIA-914 Survey and HPDI. Figure 2 shows how this could change apparent production. The blue line shows the reported sample production as it would normally be reported under the...

  16. Dissolution actuated sample container

    DOE Patents [OSTI]

    Nance, Thomas A.; McCoy, Frank T.

    2013-03-26

    A sample collection vial and process of using a vial is provided. The sample collection vial has an opening secured by a dissolvable plug. When dissolved, liquids may enter into the interior of the collection vial passing along one or more edges of a dissolvable blocking member. As the blocking member is dissolved, a spring actuated closure is directed towards the opening of the vial which, when engaged, secures the vial contents against loss or contamination.

  17. SAMPLING AND ANALYSIS PROTOCOLS

    SciTech Connect (OSTI)

    Jannik, T; P Fledderman, P

    2007-02-09

    Radiological sampling and analyses are performed to collect data for a variety of specific reasons covering a wide range of projects. These activities include: Effluent monitoring; Environmental surveillance; Emergency response; Routine ambient monitoring; Background assessments; Nuclear license termination; Remediation; Deactivation and decommissioning (D&D); and Waste management. In this chapter, effluent monitoring and environmental surveillance programs at nuclear operating facilities and radiological sampling and analysis plans for remediation and D&D activities will be discussed.

  18. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  19. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L. (Idaho Falls, ID)

    1987-01-01

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  20. Fluid sampling system

    DOE Patents [OSTI]

    Houck, Edward D. (Idaho Falls, ID)

    1994-01-01

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank.

  1. Fluid sampling system

    DOE Patents [OSTI]

    Houck, E.D.

    1994-10-11

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to be decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank. 4 figs.

  2. Photoactive Thermoplastic Elastomers of Azobenzene-Containing Triblock Copolymers Prepared through Atom Transfer Radical

    E-Print Network [OSTI]

    Zhao, Yue

    Photoactive Thermoplastic Elastomers of Azobenzene-Containing Triblock Copolymers Prepared through to prepare a new series of ABA triblock copolymers that are photoactive thermoplastic elastomers. The samples interesting features to this type of thermoplastic elastomers. When the solution-cast film is stretched

  3. Viscous sludge sample collector

    DOE Patents [OSTI]

    Beitel, George A [Richland, WA

    1983-01-01

    A vertical core sample collection system for viscous sludge. A sample tube's upper end has a flange and is attached to a piston. The tube and piston are located in the upper end of a bore in a housing. The bore's lower end leads outside the housing and has an inwardly extending rim. Compressed gas, from a storage cylinder, is quickly introduced into the bore's upper end to rapidly accelerate the piston and tube down the bore. The lower end of the tube has a high sludge entering velocity to obtain a full-length sludge sample without disturbing strata detail. The tube's downward motion is stopped when its upper end flange impacts against the bore's lower end inwardly extending rim.

  4. Ammonia Results Review for Retained Gas Sampling

    SciTech Connect (OSTI)

    Mahoney, Lenna A.

    2000-09-20

    This report was prepared as part of a task supporting the deployment of the retained gas sampler (RGS) system in Flammable Gas Watch List Tanks. The emphasis of this report is on presenting supplemental information about the ammonia measurements resulting from retained gas sampling of Tanks 241-AW-101, A-101, AN-105, AN-104, AN-103, U-103, S-106, BY-101, BY-109, SX-106, AX-101, S-102, S-111, U-109, and SY-101. This information provides a better understanding of the accuracy of past RGS ammonia measurements, which will assist in determining flammable and toxicological hazards.

  5. Preparing for Transfer Biological Engineering

    E-Print Network [OSTI]

    Walter, M.Todd

    Preparing for Transfer Majors: Biological Engineering Chemical Engineering Civil Engineering Computer Science Electrical & Computer Engineering Engineering Physics Environmental Engineering Information Science, Systems, & Technology Materials Science & Engineering Mechanical Engineering Operations

  6. Preparing for Transfer Biological Engineering

    E-Print Network [OSTI]

    Walter, M.Todd

    Preparing for Transfer Majors: Biological Engineering Biomedical Engineering* Chemical Engineering Civil Engineering Computer Science Electrical & Computer Engineering Engineering Physics Environmental Engineering Information Science, Systems, & Technology Materials Science & Engineering Mechanical Engineering

  7. Method for preparation of polysilanes

    DOE Patents [OSTI]

    Zeigler, John M. (2208 Lester Dr., NE, Albuquerque, NM 87112)

    1991-01-01

    High molecular weight polysilanes are prepared using highly non-chain-transferring solvents. Certain alloys of sodium can also be used to advantage with such solvents. The high molecular weights are achievable even in the commercially preferred "normal" addition procedure.

  8. ASTM sampling methods and analytical validation for lead in paint, dust, soil, and air

    SciTech Connect (OSTI)

    Ashley, K.; Schlecht, P.C.; Song, R.; Feng, A.; DeWalt, G.; McKnight, M.E.

    1996-12-31

    ASTM Subcommittee E06.23 on Abatement/Mitigation of Lead Hazards has developed a number of standards that are concerned with the sampling of leas in environmental media, namely paint, dust, soil and airborne particulate. An ASTM practice for the collection of airborne particulate lead in the workplace has been published. New ASTM standards for the collection of dry paint film samples, surface soil samples, and surface dust wipe samples for subsequent lead analysis have also been promulgated. Other draft standards pertinent to lead sampling are under development. The ASTM standards concerned with lead sample collection are accompanied by separate sample preparation standard practices and a standard analysis method. Sample preparation and analytical methods have been evaluated by interlaboratory testing; such analyses may be used to assess the efficacy of sampling protocols.

  9. REVIEW OF DIESEL PARTICULATE MATTER SAMPLING FINAL REPORT

    E-Print Network [OSTI]

    Minnesota, University of

    REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS FINAL REPORT Prepared by David B. Kittelson of Mechanical Engineering Center for Diesel Research Minneapolis, MN January 14, 1999 #12;01/14/99 Page 2 TABLE ................................................................................................................5 DIESEL ENGINE TECHNOLOGY AND EMISSION REGULATIONS .............................7 PHYSICAL

  10. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01

    P. , "Investigations on hydraulic cement from spent oilCO, April 16-18, 1980 HYDRAULIC CEMENT PREPARATION FROMUniversity of California. HYDRAULIC CEMENT PREPARATION FROM

  11. Sampling Report for May-June, 2014 WIPP Samples

    Office of Environmental Management (EM)

    1 L L N L - X X X X - X X X X X Sampling Report for May- June, 2014 WIPP Samples UNCLASSIFIED Forensic Science Center January 8, 2015 Sampling Report for May-June, 2014 WIPP...

  12. Results of Hg speciation testing on tanks 30, 32, and 37 surface samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-11

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.

  13. Decoupled Sampling for Graphics Pipelines

    E-Print Network [OSTI]

    Ragan-Kelley, Jonathan Millar

    We propose a generalized approach to decoupling shading from visibility sampling in graphics pipelines, which we call decoupled sampling. Decoupled sampling enables stochastic supersampling of motion and defocus blur at ...

  14. Sample Environments at Sector 30

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sample holder designs are below. Aluminum sample holder - custom design Al design Al pic click drawing for .pdf-file Aluminum sample holder - custom design Al design Al pic...

  15. Fluid sampling apparatus and method

    DOE Patents [OSTI]

    Yeamans, D.R.

    1998-02-03

    Incorporation of a bellows in a sampling syringe eliminates ingress of contaminants, permits replication of amounts and compression of multiple sample injections, and enables remote sampling for off-site analysis. 3 figs.

  16. Soil sampling kit and a method of sampling therewith

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN)

    1991-01-01

    A soil sampling device and a sample containment device for containing a soil sample is disclosed. In addition, a method for taking a soil sample using the soil sampling device and soil sample containment device to minimize the loss of any volatile organic compounds contained in the soil sample prior to analysis is disclosed. The soil sampling device comprises two close fitting, longitudinal tubular members of suitable length, the inner tube having the outward end closed. With the inner closed tube withdrawn a selected distance, the outer tube can be inserted into the ground or other similar soft material to withdraw a sample of material for examination. The inner closed end tube controls the volume of the sample taken and also serves to eject the sample. The soil sample containment device has a sealing member which is adapted to attach to an analytical apparatus which analyzes the volatile organic compounds contained in the sample. The soil sampling device in combination with the soil sample containment device allow an operator to obtain a soil sample containing volatile organic compounds and minimizing the loss of the volatile organic compounds prior to analysis of the soil sample for the volatile organic compounds.

  17. Soil sampling kit and a method of sampling therewith

    DOE Patents [OSTI]

    Thompson, C.V.

    1991-02-05

    A soil sampling device and a sample containment device for containing a soil sample is disclosed. In addition, a method for taking a soil sample using the soil sampling device and soil sample containment device to minimize the loss of any volatile organic compounds contained in the soil sample prior to analysis is disclosed. The soil sampling device comprises two close fitting, longitudinal tubular members of suitable length, the inner tube having the outward end closed. With the inner closed tube withdrawn a selected distance, the outer tube can be inserted into the ground or other similar soft material to withdraw a sample of material for examination. The inner closed end tube controls the volume of the sample taken and also serves to eject the sample. The soil sample containment device has a sealing member which is adapted to attach to an analytical apparatus which analyzes the volatile organic compounds contained in the sample. The soil sampling device in combination with the soil sample containment device allows an operator to obtain a soil sample containing volatile organic compounds and minimizing the loss of the volatile organic compounds prior to analysis of the soil sample for the volatile organic compounds. 11 figures.

  18. Hanford Sampling Quality Management Plan (HSQMP)

    SciTech Connect (OSTI)

    Hyatt, J.E.

    1995-04-28

    This document provides a management tool for evaluating and designing the appropriate elements of a field sampling program. This document provides discussion of the elements of a program and is to be used as a guidance document during the preparation of project and/or function specific documentation. This document does not specify how a sampling program shall be organized. The HSQMP is to be used as a companion document to the Hanford Analytical Services Quality Assurance Plan (HASQAP) DOE/RL-94-55. The generation of this document was enhanced by conducting baseline evaluations of current sampling organizations. Valuable input was received from members of field and Quality Assurance organizations. The HSQMP is expected to be a living document. Revisions will be made as regulations and or Hanford Site conditions warrant changes in the best management practices. Appendices included are: summary of the sampling and analysis work flow process, a user`s guide to the Data Quality Objective process, and a self-assessment checklist.

  19. OVERVIEW OF BERYLLIUM SAMPLING AND ANALYSIS

    SciTech Connect (OSTI)

    Brisson, M

    2009-04-01

    Because of its unique properties as a lightweight metal with high tensile strength, beryllium is widely used in applications including cell phones, golf clubs, aerospace, and nuclear weapons. Beryllium is also encountered in industries such as aluminium manufacturing, and in environmental remediation projects. Workplace exposure to beryllium particulates is a growing concern, as exposure to minute quantities of anthropogenic forms of beryllium may lead to sensitization and to chronic beryllium disease, which can be fatal and for which no cure is currently known. Furthermore, there is no known exposure-response relationship with which to establish a 'safe' maximum level of beryllium exposure. As a result, the current trend is toward ever lower occupational exposure limits, which in turn make exposure assessment, both in terms of sampling and analysis, more challenging. The problems are exacerbated by difficulties in sample preparation for refractory forms of beryllium, such as beryllium oxide, and by indications that some beryllium forms may be more toxic than others. This chapter provides an overview of sources and uses of beryllium, health risks, and occupational exposure limits. It also provides a general overview of sampling, analysis, and data evaluation issues that will be explored in greater depth in the remaining chapters. The goal of this book is to provide a comprehensive resource to aid personnel in a wide variety of disciplines in selecting sampling and analysis methods that will facilitate informed decision-making in workplace and environmental settings.

  20. NID Copper Sample Analysis

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Zhu, Zihua

    2011-09-12

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0???). This experiment requires the use of germanium isotopically enriched in 76Ge. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology, possibly one under development at Nonlinear Ion Dynamics (NID), will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL in January 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are reported here. A second sample of isotopically separated copper was provided by NID to PNNL in August 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are also reported here.

  1. Germanium-76 Sample Analysis

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Engelhard, Mark H.; Zhu, Zihua

    2011-04-01

    The MAJORANA DEMONSTRATOR is a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0???). The DEMONSTRATOR will utilize 76Ge from Russia, and the first one gram sample was received from the supplier for analysis on April 24, 2011. The Environmental Molecular Sciences facility, a DOE user facility at PNNL, was used to make the required isotopic and chemical purity measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR. The results of this first analysis are reported here.

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700 GJO-2003-411-TACe: SUBJIHX:ontineSampling at

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700 GJO-2003-411-TACe: SUBJIHX:ontineSampling

  4. 2003 CBECS Sample Design

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade Year-0Cubic MonthlyTechnical Information > Sample

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling at the

  6. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling at

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling at4

  8. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling at4and

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling Rifle,

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 theGroundwater Sampling4

  13. Entanglement sampling and applications

    E-Print Network [OSTI]

    Frédéric Dupuis; Omar Fawzi; Stephanie Wehner

    2015-06-15

    A natural measure for the amount of quantum information that a physical system E holds about another system A = A_1,...,A_n is given by the min-entropy Hmin(A|E). Specifically, the min-entropy measures the amount of entanglement between E and A, and is the relevant measure when analyzing a wide variety of problems ranging from randomness extraction in quantum cryptography, decoupling used in channel coding, to physical processes such as thermalization or the thermodynamic work cost (or gain) of erasing a quantum system. As such, it is a central question to determine the behaviour of the min-entropy after some process M is applied to the system A. Here we introduce a new generic tool relating the resulting min-entropy to the original one, and apply it to several settings of interest, including sampling of subsystems and measuring in a randomly chosen basis. The sampling results lead to new upper bounds on quantum random access codes, and imply the existence of "local decouplers". The results on random measurements yield new high-order entropic uncertainty relations with which we prove the optimality of cryptographic schemes in the bounded quantum storage model.

  14. NID Copper Sample Analysis

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Zhu, Zihua

    2011-02-01

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0???). This experiment requires the use of germanium isotopically enriched in 76Ge. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology under development at Nonlinear Ion Dynamics (NID) will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making these isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL for isotopic analysis as a test of the NID technology. The results of that analysis are reported here.

  15. Sample holder with optical features

    DOE Patents [OSTI]

    Milas, Mirko; Zhu, Yimei; Rameau, Jonathan David

    2013-07-30

    A sample holder for holding a sample to be observed for research purposes, particularly in a transmission electron microscope (TEM), generally includes an external alignment part for directing a light beam in a predetermined beam direction, a sample holder body in optical communication with the external alignment part and a sample support member disposed at a distal end of the sample holder body opposite the external alignment part for holding a sample to be analyzed. The sample holder body defines an internal conduit for the light beam and the sample support member includes a light beam positioner for directing the light beam between the sample holder body and the sample held by the sample support member.

  16. Preparation and characterization of aryl-substituted polysilsesquioxanes

    SciTech Connect (OSTI)

    Schneider, D.A.; Loy, D.A.; Baugher, B.M.; Wheeler, D.R.; Assink, R.A.; Alam, T.M.; Saunders, R.

    1998-09-01

    Polymerizations of aryltrialkoxysilanes generally afford soluble oligomeric or polymeric aryl-substituted silsesquioxanes. This is in spite of being based on trifunctional precursors capable of forming highly crosslinked and insoluble network polymers. In this study, soluble phenyl, benzyl, and phenethyl-substituted silsesquioxane oligomers and polymers were prepared by hydrolyzing their respective triethoxysilyl precursor with water or aqueous acid. Additional samples of the polymers were prepared by heating the materials at 100 C or 200 C under vacuum in order to drive the condensation chemistry. One sample of polybenzylsilsesquioxane was heated at 200 C with catalytic NaOH. The resulting materials were characterized using solution {sup 1}H, {sup 13}C, and {sup 29}Si NMR spectroscopy, gel permeation chromatography, and differential scanning calorimetry. Of particular interest was the effect of the aryl substituent, and processing conditions on the molecular weight and glass transition temperatures of the polysilsesquioxanes.

  17. Recovery of coal fines from preparation plant effluents

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1990-01-01

    The objectives of this project are to test and demonstrate the feasibility of recovering the coal fines which are currently disposed of with plant effluent streams in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of carbonaceous material from the effluent streams will be effected by means of Michigan Technological University's static tube flotation process in conjunction with pyrite depressants. This process has been successfully demonstrated on a number of coals to reject 85% of the pyritic sulfur and recover 90% of the Btu value. The process parameters will be modified to accept preparation plant effluents in order to produce a low-ash, low-sulfur clean coal product that at a minimum is compatible with the quality requirements of the plant clean coal. This report covers the first quarter of the project. The main activities during this period were the drafting of a project work plan and the collection of four coal preparation plant effluent samples for testing. Effluent slurry samples were collected from four operating preparation plants in Illinois and shipped to Michigan Technological University for experimental work.

  18. Elimination of ``memory`` from sample handling and inlet system of a mass spectrometer

    DOE Patents [OSTI]

    Chastgner, P.

    1991-05-08

    This paper describes a method for preparing the sample handling and inlet system of a mass spectrometer for analysis of a subsequent sample following analysis of a previous sample comprising the flushing of the system interior with supercritical CO{sub 2} and venting the interior. The method eliminates the effect of system ``memory`` on the subsequent analysis, especially following persistent samples such as xenon and krypton.

  19. Method and apparatus for automated processing and aliquoting of whole blood samples for analysis in a centrifugal fast analyzer

    DOE Patents [OSTI]

    Burtis, Carl A. (Oak Ridge, TN); Johnson, Wayne F. (Loudon, TN); Walker, William A. (Knoxville, TN)

    1988-01-01

    A rotor and disc assembly for use in a centrifugal fast analyzer. The assembly is designed to process multiple samples of whole blood followed by aliquoting of the resultant serum into precisely measured samples for subsequent chemical analysis. The assembly requires minimal operator involvement with no mechanical pipetting. The system comprises (1) a whole blood sample disc, (2) a serum sample disc, (3) a sample preparation rotor, and (4) an analytical rotor. The blood sample disc and serum sample disc are designed with a plurality of precision bore capillary tubes arranged in a spoked array. Samples of blood are loaded into the blood sample disc in capillary tubes filled by capillary action and centrifugally discharged into cavities of the sample preparation rotor where separation of serum and solids is accomplished. The serum is loaded into the capillaries of the serum sample disc by capillary action and subsequently centrifugally expelled into cuvettes of the analytical rotor for analysis by conventional methods.

  20. Method and apparatus for automated processing and aliquoting of whole blood samples for analysis in a centrifugal fast analyzer

    DOE Patents [OSTI]

    Burtis, C.A.; Johnson, W.F.; Walker, W.A.

    1985-08-05

    A rotor and disc assembly for use in a centrifugal fast analyzer. The assembly is designed to process multiple samples of whole blood followed by aliquoting of the resultant serum into precisely measured samples for subsequent chemical analysis. The assembly requires minimal operator involvement with no mechanical pipetting. The system comprises: (1) a whole blood sample disc; (2) a serum sample disc; (3) a sample preparation rotor; and (4) an analytical rotor. The blood sample disc and serum sample disc are designed with a plurality of precision bore capillary tubes arranged in a spoked array. Samples of blood are loaded into the blood sample disc by capillary action and centrifugally discharged into cavities of the sample preparation rotor where separation of serum and solids is accomplished. The serum is loaded into the capillaries of the serum sample disc by capillary action and subsequently centrifugally expelled into cuvettes of the analyticaly rotor for conventional methods. 5 figs.

  1. Preparation of RCRA contingency plans

    SciTech Connect (OSTI)

    Not Available

    1992-07-01

    The purpose of this guidance is to assist Department of Energy (DOE) field personnel in the preparation of Resource Conservation and Recovery Act (RCRA) contingency plans as set forth in 40 CFR 264/265 Subpart D and 270.42. The guidance will assist personnel in evaluating and ensuring facility compliance with the contingency plan requirements.

  2. Preparation of gas selective membranes

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Gas separation membranes which possess improved characteristics as exemplified by selectivity and flux may be prepared by coating a porous organic polymer support with a solution or emulsion of a plasticizer and an organic polymer, said coating being effected at subatmospheric pressures in order to increase the penetration depth of the coating material.

  3. JOURNAL AUTHORS SURVEY Prepared by

    E-Print Network [OSTI]

    Stevenson, Paul

    JISC/OSI JOURNAL AUTHORS SURVEY Report Prepared by Key Perspectives Ltd 48 Old Coach Road, Playing behind its development 4 2.2 Models and definitions of open access 8 2.2.1 Open access journals 8 2 4.1 Respondent profiles 18 4.2 Awareness of open access journals 18 4.2.1 Extent and longevity

  4. Photochemical preparation of plutonium pentafluoride

    DOE Patents [OSTI]

    Rabideau, Sherman W. (Los Alamos, NM); Campbell, George M. (Los Alamos, NM)

    1987-01-01

    The novel compound plutonium pentafluoride may be prepared by the photodissociation of gaseous plutonium hexafluoride. It is a white solid of low vapor pressure, which consists predominantly of a face-centered cubic structure with a.sub.o =4.2709.+-.0.0005 .ANG..

  5. Preparation of asymmetric porous materials

    DOE Patents [OSTI]

    Coker, Eric N. (Albuquerque, NM)

    2012-08-07

    A method for preparing an asymmetric porous material by depositing a porous material film on a flexible substrate, and applying an anisotropic stress to the porous media on the flexible substrate, where the anisotropic stress results from a stress such as an applied mechanical force, a thermal gradient, and an applied voltage, to form an asymmetric porous material.

  6. Arduino Sustainability Project Prepared for

    E-Print Network [OSTI]

    Kachroo, Pushkin

    Arduino Sustainability Project Prepared for: Dr. Pushkin Kachroo EE 290 UNLV Christian Calvo 2009 by the Arduino microcontroller to satisfy the theme of sustainability. The device I decided to construct is determined by the LDR. The LDR output signal is fed into an analog input of the Arduino. The value is read

  7. Guide to Petrography Specimen Preparation

    E-Print Network [OSTI]

    Henderson, Gideon

    I Microscopic Examination I Image Analysis & Capture #12;In 1849 when Henry Sorby, the father of pet's technologies help deliver the fullest product offering for all applications. Together with our technical in the case of preparing thin sections) · Expose the surface of interest Historically, the sectioning process

  8. Fluid sampling tool

    DOE Patents [OSTI]

    Johnston, Roger G. (Los Alamos, NM); Garcia, Anthony R. E. (Espanola, NM); Martinez, Ronald K. (Santa Cruz, NM)

    2001-09-25

    The invention includes a rotatable tool for collecting fluid through the wall of a container. The tool includes a fluid collection section with a cylindrical shank having an end portion for drilling a hole in the container wall when the tool is rotated, and a threaded portion for tapping the hole in the container wall. A passageway in the shank in communication with at least one radial inlet hole in the drilling end and an opening at the end of the shank is adapted to receive fluid from the container. The tool also includes a cylindrical chamber affixed to the end of the shank opposite to the drilling portion thereof for receiving and storing fluid passing through the passageway. The tool also includes a flexible, deformable gasket that provides a fluid-tight chamber to confine kerf generated during the drilling and tapping of the hole. The invention also includes a fluid extractor section for extracting fluid samples from the fluid collecting section.

  9. Prepared

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M1 the RFSOGorPLEASE RETURN

  10. Specified assurance level sampling procedure

    SciTech Connect (OSTI)

    Willner, O.

    1980-11-01

    In the nuclear industry design specifications for certain quality characteristics require that the final product be inspected by a sampling plan which can demonstrate product conformance to stated assurance levels. The Specified Assurance Level (SAL) Sampling Procedure has been developed to permit the direct selection of attribute sampling plans which can meet commonly used assurance levels. The SAL procedure contains sampling plans which yield the minimum sample size at stated assurance levels. The SAL procedure also provides sampling plans with acceptance numbers ranging from 0 to 10, thus, making available to the user a wide choice of plans all designed to comply with a stated assurance level.

  11. Porous-electrode preparation method

    DOE Patents [OSTI]

    Arons, R.M.; Dusek, J.T.

    1981-09-17

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  12. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, Raghunath (Littleton, CO)

    1998-01-01

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products.

  13. Preparation of energy storage materials

    DOE Patents [OSTI]

    Li, Lin Song (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2003-01-01

    A process is provided for the preparation of a metallic oxide composite including mixing an aqueous solution of a water-soluble metal compound and colloidal silica, depositing the mixture upon a substrate, heating the mixture-coated substrates at temperatures from about 150.degree. C. to about 300.degree. C. for time sufficient to form a metallic oxide film, and, removing the silica from the metallic oxide film whereby a porous metal oxide structure is formed.

  14. Preparation Of Energy Storage Materials

    DOE Patents [OSTI]

    Li, Lin Song (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2003-12-02

    A process is provided for the preparation of a metallic oxide composite including mixing an aqueous solution of a water-soluble metal compound and colloidal silica, depositing the mixture upon a substrate, heating the mixture-coated substrates at temperatures from about 150.degree. C. to about 300.degree. C. for time sufficient to form a metallic oxide film, and, removing the silica from the metallic oxide film whereby a porous metal oxide structure is formed.

  15. Method for preparing ceramic composite

    DOE Patents [OSTI]

    Alexander, Kathleen B. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN); Becher, Paul F. (Oak Ridge, TN); Waters, Shirley B. (Knoxville, TN)

    1996-01-01

    A process for preparing ceramic composite comprising blending TiC particulates, Al.sub.2 O.sub.3 particulates and nickle aluminide and consolidating the mixture at a temperature and pressure sufficient to produce a densified ceramic composite having fracture toughness equal to or greater than 7 MPa m.sup.1/2, a hardness equal to or greater than 18 GPa.

  16. Method for preparing ceramic composite

    DOE Patents [OSTI]

    Alexander, K.B.; Tiegs, T.N.; Becher, P.F.; Waters, S.B.

    1996-01-09

    A process is disclosed for preparing ceramic composite comprising blending TiC particulates, Al{sub 2}O{sub 3} particulates and nickel aluminide and consolidating the mixture at a temperature and pressure sufficient to produce a densified ceramic composite having fracture toughness equal to or greater than 7 MPa m{sup 1/2}, a hardness equal to or greater than 18 GPa. 5 figs.

  17. Northern Marshall Islands radiological survey: sampling and analysis summary

    SciTech Connect (OSTI)

    Robison, W.L.; Conrado, C.L.; Eagle, R.J.; Stuart, M.L.

    1981-07-23

    A radiological survey was conducted in the Northern Marshall Islands to document reamining external gamma exposures from nuclear tests conducted at Enewetak and Bikini Atolls. An additional program was later included to obtain terrestrial and marine samples for radiological dose assessment for current or potential atoll inhabitants. This report is the first of a series summarizing the results from the terrestrial and marine surveys. The sample collection and processing procedures and the general survey methodology are discussed; a summary of the collected samples and radionuclide analyses is presented. Over 5400 samples were collected from the 12 atolls and 2 islands and prepared for analysis including 3093 soil, 961 vegetation, 153 animal, 965 fish composite samples (average of 30 fish per sample), 101 clam, 50 lagoon water, 15 cistern water, 17 groundwater, and 85 lagoon sediment samples. A complete breakdown by sample type, atoll, and island is given here. The total number of analyses by radionuclide are 8840 for /sup 241/Am, 6569 for /sup 137/Cs, 4535 for /sup 239 +240/Pu, 4431 for /sup 90/Sr, 1146 for /sup 238/Pu, 269 for /sup 241/Pu, and 114 each for /sup 239/Pu and /sup 240/Pu. A complete breakdown by sample category, atoll or island, and radionuclide is also included.

  18. 3 - DJ : sampling as design

    E-Print Network [OSTI]

    Patel, Sayjel Vijay

    2015-01-01

    3D Sampling is introduced as a new spatial craft that can be applied to architectural design, akin to how sampling is applied in the field of electronic music. Through the development of 3-DJ, a prototype design software, ...

  19. Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830

    E-Print Network [OSTI]

    PNNL-22900 Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Solar Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Pacific Northwest National for radioactive material is required as stipulated in the PNNL Site radioactive air license. Sampling ambient air

  20. Method of surface preparation of niobium

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni (Shoreham, NY); Schill, John F. (Ridge, NY)

    2003-01-01

    The present invention is for a method of preparing a surface of niobium. The preparation method includes polishing, cleaning, baking and irradiating the niobium surface whereby the resulting niobium surface has a high quantum efficiency.

  1. Preparation for Warmer Temperatures | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preparation for Warmer Temperatures Preparation for Warmer Temperatures April 2, 2014 - 11:05am Addthis Ceiling fans are a great way to efficiently cool your house in the summer. |...

  2. Automated LEPS (low-energy photon spectrometry) system using a robotic sample changer

    SciTech Connect (OSTI)

    Delmastro, J.R.; Wade, M.A.; Dykes, F.W. (Westinghouse Idaho Nuclear Company, Idaho Falls (USA)); Lewis, A.L. (ARAMCO, Dhahran (Saudi Arabia))

    1989-11-01

    At the Idaho Chemical Processing Plant, effluent waste streams are regularly monitored for {sup 129}I. After sample preparation, a filter paper containing the separated radioiodine is mounted on an aluminum backing card for ease in handling. The card is loaded onto a low-energy photon detector and counted for {approximately}2 h with a Nuclear Data ND6700 spectrometer. After the counting is complete, the ND6700 system analyzes the spectrum to determine the quantity of {sup 129}I in the sample. The {sup 129}I in a typical waste stream sample is determined by counting four separate samples, i.e., duplicates of the waste stream sample, a blank, and an unknown quality control sample. The need arose to process large numbers of these samples. To improve sample throughput and permit unattended counting of these samples, a totally automated low-energy photon spectrometry (LEPS) system was developed to perform all the sample handling and analysis operations.

  3. Forensic Applications of Light-Element Stable Isotope Ratios of Ricinus communis Seeds and Ricin Preparations

    SciTech Connect (OSTI)

    Kreuzer, Helen W.; West, Jason B.; Ehleringer, James

    2013-01-01

    Seeds of the castor plant Ricinus communis, also known as castor beans, are of forensic interest because they are the source of the poison ricin. We have tested whether stable isotope ratios of castor seeds and ricin prepared by various methods can be used as a forensic signature. We collected over 300 castor seed samples from locations around the world and measured the C, N, O, and H stable isotope ratios of the whole seeds, oil, and three types of ricin preparations. Our results demonstrate that N isotope ratios can be used to correlate ricin prepared by any of these methods to source seeds. Further, stable isotope ratios distinguished >99% of crude and purified ricin protein samples in pair-wise comparison tests. Stable isotope ratios therefore constitute a valuable forensic signature for ricin preparations.

  4. Stormwater Pollution Prevention Plan Prepared by

    E-Print Network [OSTI]

    Eisen, Michael

    Stormwater Pollution Prevention Plan Prepared by: Environment, Health, Safety, and Security .....................................................16 3.0 Potential Sources of Pollution

  5. Preparing for the Arrival of Electric Vehicle

    Broader source: Energy.gov [DOE]

    This webinar covers how to prepare for electric vehicles and elements of developing an EV infrastructure plan.

  6. Versatile, automated sample preparation and detection of contaminants and biological materials

    E-Print Network [OSTI]

    Hoehl, Melanie Margarete

    2013-01-01

    Contamination of food, water, medicine and ingestible household products is a public health hazard that episodically causes outbreaks worldwide. Existing laboratory methods are often expensive, require a laboratory environment ...

  7. Introduction Sample preparation is an essential step for all three main

    E-Print Network [OSTI]

    Lebendiker, Mario

    -PAGE analysis of proteins extracted from Escherichia coli cells. BL21 DE3 pLysS cells were harvested-B Reagent diluted 1:5 in water. Likewise, the whole bacterial protein extracts were diluted 1:5 in water of efficiently extracting proteins from cells is essen- tial. The use of mild detergents to disrupt cells

  8. Indexing and TEM Sample Preparation of Isolated CdTe/CdS Nano-Islands.

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers(JournalatBaBar (Thesis/Dissertation) | SciTech6(Conference) |

  9. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, Raghunath (Littleton, CO); Blaugher, Richard D. (Evergreen, CO)

    1995-01-01

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals, such as nitrate salts of thallium, barium, calcium, and copper, which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of thallium in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products.

  10. Preparation of hydrophobic organic aeorgels

    DOE Patents [OSTI]

    Baumann, Theodore F. (Tracy, CA); Satcher, Jr., Joe H. (Patterson, CA); Gash, Alexander E. (Livermore, CA)

    2007-11-06

    Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

  11. Preparation of hydrophobic organic aeorgels

    DOE Patents [OSTI]

    Baumann, Theodore F.; Satcher, Jr., Joe H.; Gash, Alexander E.

    2004-10-19

    Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.

  12. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, R.

    1998-08-04

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products. 7 figs.

  13. National Coal Council Presentation/Prepared Remarks | Department...

    Broader source: Energy.gov (indexed) [DOE]

    National Coal Council PresentationPrepared Remarks More Documents & Publications MESQUITE REFF West PresentationPrepared Remarks RETECH PresentationPrepared Remarks...

  14. A perspective on the status of coal research from shipments of samples

    SciTech Connect (OSTI)

    Vorres, K.S. [Argonne National Lab., IL (United States); Kruse, C.W. [Illinois State Geological Survey, Champaign, IL (United States); Nater, K.A. [deGrote Vos, Zeeweg 37, 1753 BB St. Martenzee, NL (Netherlands); Glick, D.C.; Davis, A. [Pennsylvania State Univ., University Park, PA (United States). Coal and Organic Petrology Labs.

    1993-12-31

    Research on all aspects of coal research, at least for more small scale work, involves the use of samples at the beginning of experimental work. Most research workers for smaller scale work do not collect their own coal samples, but rather order them from a group of sample suppliers. The number of suppliers meeting the major needs in the US, as well as for the world, is not very large. An examination of the shipments of samples from each of these suppliers will give an interesting insight into the general trends in volume of work in the field. The suppliers involved in this study include the Argonne Premium Coal Sample Program, the Illinois Basin Coal Sample Program, the SBN and the several groups of samples from the Pennsylvania State University Coal Sample Bank. Each of these supplies a different number of samples in varying quantities. The quantities and variety of samples is important to the individual worker in selecting a supplier. The type of work to be done frequently affects the quantities and choice of sample, which in turn affects the choice of supplier. In general these data indicate that researchers realize the advantages of acquiring samples from centralized sample banks. These advantages include a lower cost than would be incurred from individual sampling and preparation; availability of analyzed samples; preservation of samples and the possibility of comparing results with others who have worked on the same samples.

  15. Homeowner Soil Sample Information Form 

    E-Print Network [OSTI]

    Provin, Tony

    2007-04-11

    THE TEXAS A&M UNIVERSITY SYSTEM Soil, Water and Forage Testing Laboratory Urban and Homeowner Soil Sample Information Form See sampling procedures and mailing instructions on the back of this form. (PLEASE DO NOT SEND CASH) SU07 E-444... (7-07) Results will be mailed to this address ONLY Address City Phone County where sampled Name Laboratory # (For Lab Use Only) State Zip Payment (DO NOT SEND CASH). Amount Paid $ SUBMITTED BY: Check Money Order Make Checks Payable to: Soil...

  16. Acceptance sampling using judgmental and randomly selected samples

    SciTech Connect (OSTI)

    Sego, Landon H.; Shulman, Stanley A.; Anderson, Kevin K.; Wilson, John E.; Pulsipher, Brent A.; Sieber, W. Karl

    2010-09-01

    We present a Bayesian model for acceptance sampling where the population consists of two groups, each with different levels of risk of containing unacceptable items. Expert opinion, or judgment, may be required to distinguish between the high and low-risk groups. Hence, high-risk items are likely to be identifed (and sampled) using expert judgment, while the remaining low-risk items are sampled randomly. We focus on the situation where all observed samples must be acceptable. Consequently, the objective of the statistical inference is to quantify the probability that a large percentage of the unsampled items in the population are also acceptable. We demonstrate that traditional (frequentist) acceptance sampling and simpler Bayesian formulations of the problem are essentially special cases of the proposed model. We explore the properties of the model in detail, and discuss the conditions necessary to ensure that required samples sizes are non-decreasing function of the population size. The method is applicable to a variety of acceptance sampling problems, and, in particular, to environmental sampling where the objective is to demonstrate the safety of reoccupying a remediated facility that has been contaminated with a lethal agent.

  17. (Recovery of coal fines from preparation plant effluents)

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1991-01-01

    The objectives of this project are to test and demonstrate the feasibility of recovering coal fines which are currently disposed of with plant effluent streams, in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of coal from the effluent stream samples will be effected by means of Michigan Technological University's static tube flotation process. This process has been successfully demonstrated on a number of raw coals to reject 85% of the pyritic sulfur and recover 90% of the combustible matter. The process parameters will be modified so that this technology can be applied to preparation plant effluents in order to recover a low-ash, low-sulfur clean coal that is, at a minimum, compatible with the quality of the clean coal currently produced from the preparation plant. The main activities during this period were setting up the static tube test unit to conduct the experimental work as outlined in the project work plan. The first of four effluent slurry samples collected from four operating Illinois preparation plants was tested at Michigan Technological University. The first batch of tests resulted in a clean coal containing 7.5% ash at 94.5% combustible matter recovery. Another test aimed at lowering the ash further analyzed at 3.0% ash and 0.92% total sulfur. In addition, analyses of particle size distribution and sink-float testing of the +200 mesh material were undertaken as a part of the effluent characterization work. 5 tabs.

  18. Sample Residential Program Term Sheet

    Broader source: Energy.gov [DOE]

    A sample for defining and elaborating on the specifics of a clean energy loan program. Author: U.S. Department of Energy

  19. Adaptive Sampling for Environmental Robotics

    E-Print Network [OSTI]

    Mohammad Rahimi; Richard Pon; Deborah Estrin; William J. Kaiser; Mani Srivastava; Gaurav S. Sukhatme

    2003-01-01

    186, 2003. S. Thrun, “Robotics Mapping: A survey”, Exploringtechnique to environmental robotics applications includingSampling for Environmental Robotics Mohammad Rahimi †,‡‡ ,

  20. Corrosion behavior of magnetic ferrite coating prepared by plasma spraying

    SciTech Connect (OSTI)

    Liu, Yi; Wei, Shicheng Tong, Hui; Tian, Haoliang; Liu, Ming; Xu, Binshi

    2014-12-15

    Graphical abstract: The saturation magnetization (M{sub s}) of the ferrite coating is 34.417 emu/g while the M{sub s} value of the ferrite powder is 71.916 emu/g. It can be seen that plasma spray process causes deterioration of the room temperature soft magnetic properties. - Highlights: • Spinel ferrite coatings have been prepared by plasma spraying. • The coating consists of nanocrystalline grains. • The saturation magnetization of the ferrite coating is 34.417 emu/g. • Corrosion behavior of the ferrite coating was examined in NaCl solution. - Abstract: In this study, spray dried spinel ferrite powders were deposited on the surface of mild steel substrate through plasma spraying. The structure and morphological studies on the ferrite coatings were carried out using X-ray diffraction, scanning electron microscope and Raman spectroscopy. It was showed that spray dried process was an effective method to prepare thermal spraying powders. The coating showed spinel structure with a second phase of LaFeO{sub 3}. The magnetic property of the ferrite samples were measured by vibrating sample magnetometer. The saturation magnetization (M{sub s}) of the ferrite coating was 34.417 emu/g. The corrosion behavior of coating samples was examined by electrochemical impedance spectroscopy. EIS diagrams showed three corrosion processes as the coating immersed in 3.5 wt.% NaCl solution. The results suggested that plasma spraying was a promising technology for the production of magnetic ferrite coatings.

  1. Defining And Characterizing Sample Representativeness For DWPF Melter Feed Samples

    SciTech Connect (OSTI)

    Shine, E. P.; Poirier, M. R.

    2013-10-29

    Representative sampling is important throughout the Defense Waste Processing Facility (DWPF) process, and the demonstrated success of the DWPF process to achieve glass product quality over the past two decades is a direct result of the quality of information obtained from the process. The objective of this report was to present sampling methods that the Savannah River Site (SRS) used to qualify waste being dispositioned at the DWPF. The goal was to emphasize the methodology, not a list of outcomes from those studies. This methodology includes proven methods for taking representative samples, the use of controlled analytical methods, and data interpretation and reporting that considers the uncertainty of all error sources. Numerous sampling studies were conducted during the development of the DWPF process and still continue to be performed in order to evaluate options for process improvement. Study designs were based on use of statistical tools applicable to the determination of uncertainties associated with the data needs. Successful designs are apt to be repeated, so this report chose only to include prototypic case studies that typify the characteristics of frequently used designs. Case studies have been presented for studying in-tank homogeneity, evaluating the suitability of sampler systems, determining factors that affect mixing and sampling, comparing the final waste glass product chemical composition and durability to that of the glass pour stream sample and other samples from process vessels, and assessing the uniformity of the chemical composition in the waste glass product. Many of these studies efficiently addressed more than one of these areas of concern associated with demonstrating sample representativeness and provide examples of statistical tools in use for DWPF. The time when many of these designs were implemented was in an age when the sampling ideas of Pierre Gy were not as widespread as they are today. Nonetheless, the engineers and statisticians used carefully thought out designs that systematically and economically provided plans for data collection from the DWPF process. Key shared features of the sampling designs used at DWPF and the Gy sampling methodology were the specification of a standard for sample representativeness, an investigation that produced data from the process to study the sampling function, and a decision framework used to assess whether the specification was met based on the data. Without going into detail with regard to the seven errors identified by Pierre Gy, as excellent summaries are readily available such as Pitard [1989] and Smith [2001], SRS engineers understood, for example, that samplers can be biased (Gy?s extraction error), and developed plans to mitigate those biases. Experiments that compared installed samplers with more representative samples obtained directly from the tank may not have resulted in systematically partitioning sampling errors into the now well-known error categories of Gy, but did provide overall information on the suitability of sampling systems. Most of the designs in this report are related to the DWPF vessels, not the large SRS Tank Farm tanks. Samples from the DWPF Slurry Mix Evaporator (SME), which contains the feed to the DWPF melter, are characterized using standardized analytical methods with known uncertainty. The analytical error is combined with the established error from sampling and processing in DWPF to determine the melter feed composition. This composition is used with the known uncertainty of the models in the Product Composition Control System (PCCS) to ensure that the wasteform that is produced is comfortably within the acceptable processing and product performance region. Having the advantage of many years of processing that meets the waste glass product acceptance criteria, the DWPF process has provided a considerable amount of data about itself in addition to the data from many special studies. Demonstrating representative sampling directly from the large Tank Farm tanks is a difficult, if not unsolvable enterprise due to li

  2. Environmental surveillance master sampling schedule

    SciTech Connect (OSTI)

    Bisping, L.E.

    1995-02-01

    Environmental surveillance of the Hanford Site and surrounding areas is conducted by the Pacific Northwest Laboratory (PNL) for the U.S. Department of Energy (DOE). This document contains the planned 1994 schedules for routine collection of samples for the Surface Environmental Surveillance Project (SESP), Drinking Water Project, and Ground-Water Surveillance Project. Samples are routinely collected for the SESP and analyzed to determine the quality of air, surface water, soil, sediment, wildlife, vegetation, foodstuffs, and farm products at Hanford Site and surrounding communities. The responsibility for monitoring onsite drinking water falls outside the scope of the SESP. PNL conducts the drinking water monitoring project concurrent with the SESP to promote efficiency and consistency, utilize expertise developed over the years, and reduce costs associated with management, procedure development, data management, quality control, and reporting. The ground-water sampling schedule identifies ground-water sampling .events used by PNL for environmental surveillance of the Hanford Site. Sampling is indicated as annual, semi-annual, quarterly, or monthly in the sampling schedule. Some samples are collected and analyzed as part of ground-water monitoring and characterization programs at Hanford (e.g. Resources Conservation and Recovery Act (RCRA), Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), or Operational). The number of samples planned by other programs are identified in the sampling schedule by a number in the analysis column and a project designation in the Cosample column. Well sampling events may be merged to avoid redundancy in cases where sampling is planned by both-environmental surveillance and another program.

  3. Rapid determination of 226Ra in emergency urine samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.; Utsey, Robin C.; McAlister, Daniel R.

    2014-02-27

    A new method has been developed at the Savannah River National Laboratory (SRNL) that can be used for the rapid determination of 226Ra in emergency urine samples following a radiological incident. If a radiological dispersive device event or a nuclear accident occurs, there will be an urgent need for rapid analyses of radionuclides in urine samples to ensure the safety of the public. Large numbers of urine samples will have to be analyzed very quickly. This new SRNL method was applied to 100 mL urine aliquots, however this method can be applied to smaller or larger sample aliquots as needed.more »The method was optimized for rapid turnaround times; urine samples may be prepared for counting in 226Ra from the urine sample matrix, followed by removal of calcium by cation exchange separation. A stacked elution method using DGA Resin was used to purify the 226Ra during the cation exchange elution step. This approach combines the cation resin elution step with the simultaneous purification of 226Ra with DGA Resin, saving time. 133Ba was used instead of 225Ra as tracer to allow immediate counting; however, 225Ra can still be used as an option. The rapid purification of 226Ra to remove interferences using DGA Resin was compared with a slightly longer Ln Resin approach. A final barium sulfate micro-precipitation step was used with isopropanol present to reduce solubility; producing alpha spectrometry sources with peaks typically 90 %), and removes interferences effectively. The sample preparation method can also be adapted to ICP-MS measurement of 226Ra, with rapid removal of isobaric interferences.« less

  4. SST Sample Characterization Analysis of Archive Samples 102-C, 105-C, and 106-C

    SciTech Connect (OSTI)

    Hara, F. T.; Kaye, J. H.; Steele, R. T.; Stromatt, R. W.; Thomas, D. L.; Urie, M. W.

    1990-04-01

    A substantial effort is planned to be initiated at the Hanford Site regarding the characterization of 149 single-shell tanks (SSTs) containing the byproducts of reprocessing during the 1950s and 1960s. Sampling and analysis, in distinct phases, are planned to involve laboratory investigations to determine both chemical and radionuclide inventories, so that waste disposal decisions can be developed. During 1989, trial analyses were performed on four archived samples from SSTs at the Pacific Northwest Laboratory using established U.S. Environmental Protection Agency (EPA) protocols and radiochemical procedures. The analysis of the archived SST waste material provides three important types of data for use in planning Phase I-A and Phase 1-B sample analysis. The types of data served as input to I) fi na 1 i zing the waste samp 1 e analysis procedures and methods and identify where procedure developmen~ may be needed, 2) evaluating the impact of normal paraffin hydrocarbon (NPH) lubricant {used in field sampling) on extracting inorganics or radionuclides from the SST sample, and 3) identifying trends in amounts of occupational radiation exposure expected from performing the various analysis procedures. Overall, the results are qualitative in nature, and the conclusions given are to be used with appropriate respect for the limitations of small amounts of data from four samples used in development processes. The results of the Phase I-A and I-B sample analysis will provide essential data for method performance for use in finalizing Phase I-C planning and methods development scope. Section 2.0, Inorganic Analysis, encompasses sample preparation, sample analysis, identification of methods performance limitations, and possible alternatives. Performance of the inorganic analytical methods was evaluated and changes were made to some of the procedures. In some cases, inductively coupled plasma-atomic emission spectroscopy (referred to in this report as ICP) did not provide the levels of accuracy and precision usually required for EPA work due to interference by other elements. In these cases, other methods are suggested as appropriate for trial as alternatives. In all cases, duplicates, spikes, and blanks were used to establish performance of the methods for the specific waste matrix. Results focused on problems in using the methods tested on the samples, the suitability of the ICP method of determining EP Toxicity metal ions and 22 EPA pollutant metal ions, and the suitability of cold vapor atomic absorption (CVAA) for mercury determinations. Problems areas identified are ICP spectral corrections, poor reproducibility from water leach and EP Toxicity methods, and adjustments needed for mercury analysis by CVAA. Section 3.0, Organics Analysis, details two screening procedures [total organic carbon (TOC) and gas chromatography (GC)], extraction procedures and related problems, surrogate spiking to test extraction efficiencies and matrix effects, and semivolatile organics via GC/mass spectroscopy (MS). The results show that the GC/MS is vulnerable to fouling and overload and that a combination of dilution and perhaps acidification are required to provide acceptable results. NPH and silicone-based lubricants from the sampling process impact the semivolatile analysis; however, with some modification the semivolatile method based on EPA SOW 288 can be used. Section 4.0, Radionuclide Analysis, evaluates procedures used to measure the radionuclides that might be found in the SST tank waste samples and establishes the level of accuracy and precision that can be expected. These data reveal that additional procedure development is needed in order to measure all of the radionuclides listed in Table 4-14 of the Waste Characterization Plan. In addition, the archive samples analyzed may not be representative of the tank population and considerable adaptation of the radiochemical procedures may be necessary to perform the desired measurements. NPH tests were conducted to determine whether the NPH from the field sampling process extracted significan

  5. Sampling for Beryllium Surface Contamination using Wet, Dry and Alcohol Wipe Sampling

    SciTech Connect (OSTI)

    Kerr, Kent

    2004-12-17

    This research project was conducted at the National Nuclear Security Administration's Kansas City Plant, operated by Honeywell Federal Manufacturing and Technologies, in conjunction with the Safety Sciences Department of Central Missouri State University, to compare relative removal efficiencies of three wipe sampling techniques currently used at Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling with dry Whatman 42 filter paper, with water-moistened (Ghost Wipe) materials, and by methanol-moistened wipes. Test plates were prepared using 100 mm X 15 mm Pyrex Petri dishes with interior surfaces spray painted with a bond coat primer. To achieve uniform deposition over the test plate surface, 10 ml aliquots of solution containing 1 beryllium and 0.1 ml of metal working fluid were transferred to the test plates and subsequently evaporated. Metal working fluid was added to simulate the slight oiliness common on surfaces in metal working shops where fugitive oil mist accumulates over time. Sixteen test plates for each wipe method (dry, water, and methanol) were processed and sampled using a modification of wiping patterns recommended by OSHA Method 125G. Laboratory and statistical analysis showed that methanol-moistened wipe sampling removed significantly more (about twice as much) beryllium/oil-film surface contamination as water-moistened wipes (p< 0.001), which removed significantly more (about twice as much) residue as dry wipes (p <0.001). Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced residue removal efficiency.

  6. Characterization Of Sample HTF-13-13-128

    SciTech Connect (OSTI)

    Pareizs, J. M.

    2013-09-25

    Savannah River Remediation (SRR) has requested that Savannah River National Laboratory (SRNL) characterize a sample of Tank 13 in preparation for Sludge Batch 9 (SB9). A 200 mL sample of Tank 13 was received by SRNL on July 22, 2013 (Tank Farm sample ID HTF-13-13-128). Characterization of the sample to meet the requirements of the request is complete. Results include: visual observations; slurry and supernatant density; weight percent total and insoluble solids; supernatant characterization; total alpha, total beta, and several radionuclide analyses; and elemental analyses of the dried solids. The sample was very fluid. After settling overnight, there was a small layer of solids on the bottom of the sample container (a 250 mL HDPE bottle) with the remainder being clear supernatant. To better show the sludge solids relative to the overall sample, 25 mL of slurry was placed in a graduated cylinder and allowed to settle over a weekend (approximately 90 hours). The sludge layer was at the approximately 4 mL. The small visually observed quantity of insoluble solids was confirmed with a low weight percent insoluble solids of 0.94%.

  7. Hazard Sampling Dialog General Layout

    E-Print Network [OSTI]

    Zhang, Tao

    1 Hazard Sampling Dialog General Layout The dialog's purpose is to display information about the hazardous material being sampled by the UGV so either the system or the UV specialist can identify the risk level of the hazard. The dialog is associated with the hazmat reading icons (Table 1). Components

  8. Database Sampling with Functional Dependencies

    E-Print Network [OSTI]

    Riera, Jesús Bisbal

    Database Sampling with Functional Dependencies Jes´us Bisbal, Jane Grimson Department of Computer there is a need to prototype the database which the applications will use when in operation. A prototype database can be built by sampling data from an existing database. Including relevant semantic information when

  9. 200 area TEDF sample schedule

    SciTech Connect (OSTI)

    Brown, M.J.

    1995-03-22

    This document summarizes the sampling criteria associated with the 200 Area Treatment Effluent Facility (TEDF) that are needed to comply with the requirements of the Washington State Discharge Permit No. WA ST 4502 and good engineering practices at the generator streams that feed into TEDF. In addition, this document Identifies the responsible parties for both sampling and data transference.

  10. Sample push-out fixture

    DOE Patents [OSTI]

    Biernat, John L. (Scotia, NY)

    2002-11-05

    This invention generally relates to the remote removal of pelletized samples from cylindrical containment capsules. V-blocks are used to receive the samples and provide guidance to push out rods. Stainless steel liners fit into the v-channels on the v-blocks which permits them to be remotely removed and replaced or cleaned to prevent cross contamination between capsules and samples. A capsule holder securely holds the capsule while allowing manual up/down and in/out movement to align each sample hole with the v-blocks. Both end sections contain identical v-blocks; one that guides the drive out screw and rods or manual push out rods and the other to receive the samples as they are driven out of the capsule.

  11. Adiabatic state preparation study of methylene

    SciTech Connect (OSTI)

    Veis, Libor, E-mail: libor.veis@jh-inst.cas.cz; Pittner, Ji?í, E-mail: jiri.pittner@jh-inst.cas.cz [J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 3, 18223 Prague 8 (Czech Republic)

    2014-06-07

    Quantum computers attract much attention as they promise to outperform their classical counterparts in solving certain type of problems. One of them with practical applications in quantum chemistry is simulation of complex quantum systems. An essential ingredient of efficient quantum simulation algorithms are initial guesses of the exact wave functions with high enough fidelity. As was proposed in Aspuru-Guzik et al. [Science 309, 1704 (2005)], the exact ground states can in principle be prepared by the adiabatic state preparation method. Here, we apply this approach to preparation of the lowest lying multireference singlet electronic state of methylene and numerically investigate preparation of this state at different molecular geometries. We then propose modifications that lead to speeding up the preparation process. Finally, we decompose the minimal adiabatic state preparation employing the direct mapping in terms of two-qubit interactions.

  12. The application of Graphene as a sample support in Transmission Electron Microscopy

    E-Print Network [OSTI]

    Pantelic, R S; Kaiser, U; Stahlberg, H

    2012-01-01

    Transmission electron microscopy has witnessed rampant development and surging point resolution over the past few years. The improved imaging performance of modern electron microscopes shifts the bottleneck for image contrast and resolution to sample preparation. Hence, it is increasingly being realized that the full potential of electron microscopy will only be realized with the optimization of current sample preparation techniques. Perhaps the most recognized issues are background signal and noise contributed by sample supports, sample charging and instability. Graphene provides supports of single atom thickness, extreme physical stability, periodic structure, and ballistic electrical conductivity. As an increasing number of applications adapting graphene to their benefit emerge, we discuss the unique capabilities afforded by the use of graphene as a sample support for electron microscopy.

  13. Sampling Report for August 15, 2014 WIPP Samples

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and pulley system was constructed to move a camera for documentation and close-up pictures. The sampling device is located at the end of the boom. (Note, this picture is from...

  14. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01

    Investigations on hydraulic cement from spent oil shale,"April 16-18, 1980 HYDRAULIC CEMENT PREPARATION FROM LURGIpressi ve b strength, MPa this cement in moist environments.

  15. Preparing A Vita Ready Reference E-13

    E-Print Network [OSTI]

    Preparing A Vita Ready Reference E-13 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office

  16. Thesis/Dissertation Guide Instructions for Preparation

    E-Print Network [OSTI]

    Frantz, Kyle J.

    Thesis/Dissertation Guide Instructions for Preparation ........................................................................................ 3 1.5 Obtaining Bound Copies of your Thesis or Dissertation .......................................................................................... 8 3 ORGANIZATION OF THE THESIS

  17. Preparing for Project Implementation Assigning Accountability...

    Office of Environmental Management (EM)

    Assigning Accountability for Each Project, April 14, 2010 Preparing for Project Implementation Assigning Accountability for Each Project, April 14, 2010 Assigning Accountability...

  18. Methods for preparation of cyclopentadienyliron (II) arenes

    DOE Patents [OSTI]

    Keipert, S.J.

    1991-10-22

    Two improved methods for preparation of compounds with the structure shown in the equation, [(Cp)--Fe--(Ar)][sup +][sub b]X[sup b[minus

  19. RAPID DETERMINATION OF {sup 210} PO IN WATER SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2013-05-22

    A new rapid method for the determination of {sup 210}Po in water samples has been developed at the Savannah River National Laboratory (SRNL) that can be used for emergency response or routine water analyses. If a radiological dispersive device (RDD) event or a radiological attack associated with drinking water supplies occurs, there will be an urgent need for rapid analyses of water samples, including drinking water, ground water and other water effluents. Current analytical methods for the assay of {sup 210}Po in water samples have typically involved spontaneous auto-deposition of {sup 210}Po onto silver or other metal disks followed by counting by alpha spectrometry. The auto-deposition times range from 90 minutes to 24 hours or more, at times with yields that may be less than desirable. If sample interferences are present, decreased yields and degraded alpha spectrums can occur due to unpredictable thickening in the deposited layer. Separation methods have focused on the use of Sr Resin?, often in combination with 210Pb analysis. A new rapid method for {sup 210}Po in water samples has been developed at the Savannah River National Laboratory (SRNL) that utilizes a rapid calcium phosphate co-precipitation method, separation using DGA Resin? (N,N,N?,N? tetraoctyldiglycolamide extractant-coated resin, Eichrom Technologies or Triskem-International), followed by rapid microprecipitation of {sup 210}Po using bismuth phosphate for counting by alpha spectrometry. This new method can be performed quickly with excellent removal of interferences, high chemical yields and very good alpha peak resolution, eliminating any potential problems with the alpha source preparation for emergency or routine samples. A rapid sequential separation method to separate {sup 210} Po and actinide isotopes was also developed. This new approach, rapid separation with DGA Resin plus microprecipitation for alpha source preparation, is a significant advance in radiochemistry for the rapid determination of {sup 210}Po.

  20. Preparation and characterization of boro-tellurite glasses

    SciTech Connect (OSTI)

    Kaur, Nirmal, E-mail: akphysics@yahoo.com; Khanna, Atul, E-mail: akphysics@yahoo.com [Glass Physics and Sensors Laboratory, Department of Physics, Guru Nanak Dev University, Amritsar-143005, Punjab (India); Krishna, P. S. R. [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai-400085, Maharashtra (India)

    2014-04-24

    Glass samples of the system: xB{sub 2}O{sub 3}?(100?x) TeO{sub 2}; x= 15, 20, 25 and 30 mol% were prepared by melt quenching and characterized by X-ray diffraction, density measurements, Differential Scanning Calorimetry and FTIR spectroscopy. XRD confirmed the amorphous structure of all samples. Density of glasses decreased with increase in B{sub 2}O{sub 3} concentration due to the replacement of heavier TeO{sub 2} with lighter B{sub 2}O{sub 3} whereas the glass transition temperature increased from 339°C to 366°C; the later effect was due to increase in the concentration of stronger B-O bonds in the glass network. FTIR studies found that BO{sub 4} units convert into BO{sub 3} with the addition of B{sub 2}O{sub 3}.

  1. Platinum adlayered ruthenium nanoparticles, method for preparing, and uses thereof

    DOE Patents [OSTI]

    Tong, YuYe; Du, Bingchen

    2015-08-11

    A superior, industrially scalable one-pot ethylene glycol-based wet chemistry method to prepare platinum-adlayered ruthenium nanoparticles has been developed that offers an exquisite control of the platinum packing density of the adlayers and effectively prevents sintering of the nanoparticles during the deposition process. The wet chemistry based method for the controlled deposition of submonolayer platinum is advantageous in terms of processing and maximizing the use of platinum and can, in principle, be scaled up straightforwardly to an industrial level. The reactivity of the Pt(31)-Ru sample was about 150% higher than that of the industrial benchmark PtRu (1:1) alloy sample but with 3.5 times less platinum loading. Using the Pt(31)-Ru nanoparticles would lower the electrode material cost compared to using the industrial benchmark alloy nanoparticles for direct methanol fuel cell applications.

  2. Process for preparing energetic materials

    DOE Patents [OSTI]

    Simpson, Randall L. (Livermore, CA); Lee, Ronald S. (Livermore, CA); Tillotson, Thomas M. (Tracy, CA; , Hrubesh, Lawrence W. (Pleasanton, CA); Swansiger, Rosalind W. (Livermore, CA); Fox, Glenn A. (Livermore, CA)

    2011-12-13

    Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

  3. Depth-discrete sampling port

    DOE Patents [OSTI]

    Pemberton, Bradley E. (Aiken, SC); May, Christopher P. (Columbia, MD); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA); Nichols, Ralph L. (North Augusta, SC)

    1998-07-07

    A sampling port is provided which has threaded ends for incorporating the port into a length of subsurface pipe. The port defines an internal receptacle which is in communication with subsurface fluids through a series of fine filtering slits. The receptacle is in further communication through a bore with a fitting carrying a length of tubing there which samples are transported to the surface. Each port further defines an additional bore through which tubing, cables, or similar components of adjacent ports may pass.

  4. Ninth annual coal preparation, utilization, and environmental control contractors conference: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    Papers are grouped under the following sessions: compliance technology; high-efficiency preparation; characterization; advanced technologies; alternative fuels; coal utilization; industrial/commercial combustor development; combustion; superclean emission systems; carbon dioxide recovery and reuse; air toxics and fine particulates; air toxics sampling and analysis workshop; and combined poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  5. ANALYSIS OF THE TANK 6F FINAL CHARACTERIZATION SAMPLES-2012

    SciTech Connect (OSTI)

    Oji, L.; Diprete, D.; Coleman, C.; Hay, M.; Shine, G.

    2012-06-28

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 6F final characterization samples to determine the residual tank inventory prior to grouting. Fourteen residual Tank 6F solid samples from three areas on the floor of the tank were collected and delivered to SRNL between May and August 2011. These Tank 6F samples were homogenized and combined into three composite samples based on a proportion compositing scheme and the resulting composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 6F composite samples include bulk density and water leaching of the solids to account for water soluble components. The composite Tank 6F samples were analyzed and the data reported in triplicate. Sufficient quality assurance standards and blanks were utilized to demonstrate adequate characterization of the Tank 6F samples. The main evaluation criteria were target detection limits specified in the technical task request document. While many of the target detection limits were met for the species characterized for Tank 6F some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The isotopes whose detection limits were not met in all cases included Sn-126, Sb-126, Sb-126m, Eu-152, Cm-243 and Cf-249. SRNL, in conjunction with the customer, reviewed all of these cases and determined that the impacts of not meeting the target detection limits were acceptable. Based on the analyses of variance (ANOVA) for the inorganic constituents of Tank 6F, all the inorganic constituents displayed heterogeneity. The inorganic results demonstrated consistent differences across the composite samples: lowest concentrations for Composite Sample 1, intermediate-valued concentrations for Composite Sample 2, and highest concentrations for Composite Sample 3. The Hg and Mo results suggest possible measurement outliers. However, the magnitudes of the differences between the Hg 95% upper confidence limit (UCL95) results with and without the outlier and the magnitudes of the differences between the Mo UCL95 results with and without the outlier do not appear to have practical significance. It is recommended to remove the potential measurement outliers. Doing so is conservative in the sense of producing a higher UCL95 for Hg and Mo than if the potential outliers were included in the calculations. In contrast to the inorganic results, most of the radionuclides did not demonstrate heterogeneity among the three Tank 6F composite sample characterization results.

  6. Analysis Of The Tank 6F Final Characterization Samples-2012

    SciTech Connect (OSTI)

    Oji, L. N.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.; Shine, E. P.

    2012-09-27

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 6F final characterization samples to determine the residual tank inventory prior to grouting. Fourteen residual Tank 6F solid samples from three areas on the floor of the tank were collected and delivered to SRNL between May and August 2011. These Tank 6F samples were homogenized and combined into three composite samples based on a proportion compositing scheme and the resulting composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 6F composite samples include bulk density and water leaching of the solids to account for water soluble components. The composite Tank 6F samples were analyzed and the data reported in triplicate. Sufficient quality assurance standards and blanks were utilized to demonstrate adequate characterization of the Tank 6F samples. The main evaluation criteria were target detection limits specified in the technical task request document. While many of the target detection limits were met for the species characterized for Tank 6F some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The isotopes whose detection limits were not met in all cases included Sn-126, Sb-126, Sb-126m, Eu-152, Cm-243 and Cf-249. SRNL, in conjunction with the customer, reviewed all of these cases and determined that the impacts of not meeting the target detection limits were acceptable. Based on the analyses of variance (ANOVA) for the inorganic constituents of Tank 6F, all the inorganic constituents displayed heterogeneity. The inorganic results demonstrated consistent differences across the composite samples: lowest concentrations for Composite Sample 1, intermediate-valued concentrations for Composite Sample 2, and highest concentrations for Composite Sample 3. The Hg and Mo results suggest possible measurement outliers. However, the magnitudes of the differences between the Hg 95% upper confidence limit (UCL95) results with and without the outlier and the magnitudes of the differences between the Mo UCL95 results with and without the outlier do not appear to have practical significance. It is recommended to remove the potential measurement outliers. Doing so is conservative in the sense of producing a higher UCL95 for Hg and Mo than if the potential outliers were included in the calculations. In contrast to the inorganic results, most of the radionuclides did not demonstrate heterogeneity among the three Tank 6F composite sample characterization results.

  7. Analysis of the Tank 6F Final Characterization Samples-2012

    SciTech Connect (OSTI)

    Oji, L. N.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.; Shine, E. P.

    2013-01-31

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 6F final characterization samples to determine the residual tank inventory prior to grouting. Fourteen residual Tank 6F solid samples from three areas on the floor of the tank were collected and delivered to SRNL between May and August 2011. These Tank 6F samples were homogenized and combined into three composite samples based on a proportion compositing scheme and the resulting composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 6F composite samples include bulk density and water leaching of the solids to account for water soluble components. The composite Tank 6F samples were analyzed and the data reported in triplicate. Sufficient quality assurance standards and blanks were utilized to demonstrate adequate characterization of the Tank 6F samples. The main evaluation criteria were target detection limits specified in the technical task request document. While many of the target detection limits were met for the species characterized for Tank 6F some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The isotopes whose detection limits were not met in all cases included Sn-126, Sb-126, Sb-126m, Eu-152, Cm- 243 and Cf-249. SRNL, in conjunction with the customer, reviewed all of these cases and determined that the impacts of not meeting the target detection limits were acceptable. Based on the analyses of variance (ANOVA) for the inorganic constituents of Tank 6F, all the inorganic constituents displayed heterogeneity. The inorganic results demonstrated consistent differences across the composite samples: lowest concentrations for Composite Sample 1, intermediate-valued concentrations for Composite Sample 2, and highest concentrations for Composite Sample 3. The Hg and Mo results suggest possible measurement outliers. However, the magnitudes of the differences between the Hg 95% upper confidence limit (UCL95) results with and without the outlier and the magnitudes of the differences between the Mo UCL95 results with and without the outlier do not appear to have practical significance. It is recommended to remove the potential measurement outliers. Doing so is conservative in the sense of producing a higher UCL95 for Hg and Mo than if the potential outliers were included in the calculations. In contrast to the inorganic results, most of the radionuclides did not demonstrate heterogeneity among the three Tank 6F composite sample characterization results.

  8. SLUDGE BATCH 7 PREPARATION TANK 4 AND 12 CHARACTERIZATION

    SciTech Connect (OSTI)

    Bannochie, C.; Click, D.; Pareizs, J.

    2010-05-21

    Samples of PUREX sludge from Tank 4 and HM sludge from Tank 12 were characterized in preparation for Sludge Batch 7 (SB7) formulation in Tank 51. SRNL analyses on Tank 4 and Tank 12 were requested in separate Technical Assistance Requests (TAR). The Tank 4 samples were pulled on January 19, 2010 following slurry operations by F-Tank Farm. The Tank 12 samples were pulled on February 9, 2010 following slurry operations by H-Tank Farm. At the Savannah River National Laboratory (SRNL), two 200 mL dip samples of Tank 4 and two 200 mL dip samples of Tank 12 were received in the SRNL Shielded Cells. Each tank's samples were composited into clean 500 mL polyethylene storage bottles and weighed. The composited Tank 4 sample was 428.27 g and the composited Tank 12 sample was 502.15 g. As expected there are distinct compositional differences between Tank 4 and Tank 12 sludges. The Tank 12 slurry is much higher in Al, Hg, Mn, and Th, and much lower in Fe, Ni, S, and U than the Tank 4 slurry. The Tank 4 sludge definitely makes the more significant contribution of S to any sludge batch blend. This S, like that observed during SB6 washing, is best monitored by looking at the total S measured by digesting the sample and analyzing by inductively coupled plasma - atomic emission spectroscopy (ICPAES). Alternatively, one can measure the soluble S by ICP-AES and adjust the value upward by approximately 15% to have a pretty good estimate of the total S in the slurry. Soluble sulfate measurements by ion chromatography (IC) will be biased considerably lower than the actual total S, the difference being due to the non-sulfate soluble S and the undissolved S. Tank 12 sludge is enriched in U-235, and hence samples transferred into SRNL from the Tank Farm will need to be placed on the reportable special nuclear material inventory and tracked for total U per SRNL procedure requirements.

  9. Sample Results from Routine Salt Batch 7 Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-05-13

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the “microbatches” of Integrated Salt Disposition Project (ISDP) Salt Batch (“Macrobatch”) 7B have been analyzed for 238Pu, 90Sr, 137Cs, Inductively Coupled Plasma Emission Spectroscopy (ICPES), and Ion Chromatography Anions (IC-A). The results from the current microbatch samples are similar to those from earlier samples from this and previous macrobatches. The Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU) continue to show more than adequate Pu and Sr removal, and there is a distinct positive trend in Cs removal, due to the use of the Next Generation Solvent (NGS). The Savannah River National Laboratory (SRNL) notes that historically, most measured Concentration Factor (CF) values during salt processing have been in the 12-14 range. However, recent processing gives CF values closer to 11. This observation does not indicate that the solvent performance is suffering, as the Decontamination Factor (DF) has still maintained consistently high values. Nevertheless, SRNL will continue to monitor for indications of process upsets. The bulk chemistry of the DSSHT and SEHT samples do not show any signs of unusual behavior.

  10. Analysis Of The Tank 5F Final Characterization Samples-2011

    SciTech Connect (OSTI)

    Oji, L. N.; Diprete, D.; Coleman, C. J.; Hay, M. S.

    2012-09-27

    The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection limits and provide data for the extensive suite of components. While many of the target detection limits were met for the species characterized for Tank 5F, as specified in the technical task request, some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The Technical Task Request allows that while the analyses of these isotopes is needed, meeting the detection limits for these isotopes is a lower priority than meeting detection limits for the other specified isotopes. The isotopes whose detection limits were not met in all cases included the following: Al-26, Sn-126, Sb-126, Sb-126m, Eu-152 and Cf-249. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

  11. ANALYSIS OF THE TANK 5F FINAL CHARATERIZATION SAMPLES-2011

    SciTech Connect (OSTI)

    Oji, L.; Diprete, D.; Coleman, C.; Hay, M.

    2012-01-20

    The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection limits and provide data for the extensive suite of components. While many of the target detection limits were met for the species characterized for Tank 5F, as specified in the technical task request, some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The Technical Task Request allows that while the analyses of these isotopes is needed, meeting the detection limits for these isotopes is a lower priority than meeting detection limits for the other specified isotopes. The isotopes whose detection limits were not met in all cases included the following: Al-26, Sn-126, Sb-126, Sb-126m, Eu-152 and Cf-249. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

  12. ANALYSIS OF THE TANK 5F FINAL CHARACTERIZATION SAMPLES-2011

    SciTech Connect (OSTI)

    Oji, L.; Diprete, D.; Coleman, C.; Hay, M.

    2012-08-03

    The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection limits and provide data for the extensive suite of components. While many of the target detection limits were met for the species characterized for Tank 5F, as specified in the technical task request, some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The Technical Task Request allows that while the analyses of these isotopes is needed, meeting the detection limits for these isotopes is a lower priority than meeting detection limits for the other specified isotopes. The isotopes whose detection limits were not met in all cases included the following: Al-26, Sn-126, Sb-126, Sb-126m, Eu-152 and Cf-249. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

  13. SAMPLE RESULTS FROM THE INTERIM SALT DISPOSITION PROGRAM MACROBATCH 8 TANK 21H QUALIFICATION SAMPLES

    SciTech Connect (OSTI)

    Peters, T. B.; Washington, A. L.

    2015-01-13

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 8 for the Interim Salt Disposition Program (ISDP). An Actinide Removal Process (ARP) and several Extraction-Scrub- Strip (ESS) tests were also performed. This document reports characterization data on the samples of Tank 21H as well as simulated performance of ARP and the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). No issues with the projected Salt Batch 8 strategy are identified. A demonstration of the monosodium titanate (MST) (0.2 g/L) removal of strontium and actinides provided acceptable average decontamination factors for plutonium of 2.62 (4 hour) and 2.90 (8 hour); and average strontium decontamination factors of 21.7 (4 hour) and 21.3 (8 hour). These values are consistent with results from previous salt batch ARP tests. The two ESS tests also showed acceptable performance with extraction distribution ratios (D{sub (Cs)}) values of 52.5 and 50.4 for the Next Generation Solvent (NGS) blend (from MCU) and NGS (lab prepared), respectively. These values are consistent with results from previous salt batch ESS tests. Even though the performance is acceptable, SRNL recommends that a model for predicting extraction behavior for cesium removal for the blended solvent and NGS be developed in order to improve our predictive capabilities for the ESS tests.

  14. Inertial impaction air sampling device

    DOE Patents [OSTI]

    Dewhurst, K.H.

    1987-12-10

    An inertial impactor to be used in an air sampling device for collection of respirable size particles in ambient air which may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

  15. Inertial impaction air sampling device

    DOE Patents [OSTI]

    Dewhurst, K.H.

    1990-05-22

    An inertial impactor is designed which is to be used in an air sampling device for collection of respirable size particles in ambient air. The device may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

  16. Communication Engineering Systems Sampling Theorem &

    E-Print Network [OSTI]

    Kovintavewat, Piya

    x nT nx continuous sample quantized sample binary stream x t x t 2 D 7 D 8 D ( ) 7L MIDRISE s T 3 DPCM (1-bit quantizer) 1 (unit delay) 17 1n n nv x x , 0 sgn , 0 n n n n v v v v 1n n nx v x 2 DM #12;.. DM 18 1n n nx x v nx 1 1 sgn sgn n n n i ii i x v v #12;.. 19 1 b s b R mf T #12

  17. The Ocean Sampling Day Consortium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kopf, Anna; Bicak, Mesude; Kottmann, Renzo; Schnetzer, Julia; Kostadinov, Ivaylo; Lehmann, Katja; Fernandez-Guerra, Antonio; Jeanthon, Christian; Rahav, Eyal; Ullrich, Matthias; et al

    2015-06-19

    In this study, Ocean Sampling Day was initiated by the EU-funded Micro B3 (Marine Microbial Biodiversity, Bioinformatics, Biotechnology) project to obtain a snapshot of the marine microbial biodiversity and function of the world’s oceans. It is a simultaneous global mega-sequencing campaign aiming to generate the largest standardized microbial data set in a single day. This will be achievable only through the coordinated efforts of an Ocean Sampling Day Consortium, supportive partnerships and networks between sites. This commentary outlines the establishment, function and aims of the Consortium and describes our vision for a sustainable study of marine microbial communities and theirmore »embedded functional traits.« less

  18. Characterization Results For The 2013 HTF 3H Evaporator Overhead Samples

    SciTech Connect (OSTI)

    Washington, A. L. II

    2013-12-04

    This report tabulates the radiochemical analysis of the 3H evaporator overhead sample for {sup 137}Cs, {sup 90}Sr, and {sup 129}I to meet the requirements in the Effluent Treatment Project (ETP) Waste Acceptance Criteria (WAC) (rev. 6). This report identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. All data was found to be within the ETP WAC (rev. 6) specification for the Waste Water Collection Tanks (WWCT).

  19. Method for the concentration and separation of actinides from biological and environmental samples

    DOE Patents [OSTI]

    Horwitz, E.P.; Dietz, M.L.

    1989-05-30

    A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting. 3 figs.

  20. AFRICAN AMERICAN PSYCHOLOGY Sample Syllabus

    E-Print Network [OSTI]

    Hopfinger, Joseph B.

    AFRICAN AMERICAN PSYCHOLOGY PSYC 503 Sample Syllabus Course Description and Overview: This course examines the psychology of the African American experience. We begin the course with an overview of Black/African American psychology as an evolving field of study and consider the Black/African American Psychology

  1. Design of bioaerosol sampling inlets 

    E-Print Network [OSTI]

    Nene, Rohit Ravindra

    2007-09-17

    An experimental investigation involving the design, fabrication, and testing of an ambient sampling inlet and two additional Stokes-scaled inlets is presented here. Testing of each inlet was conducted at wind speeds of 2, 8, and 24 km/h (0.55, 2...

  2. Preparation of Carbon Nanotube-Composite 

    E-Print Network [OSTI]

    Sharma, Sundeep

    2011-08-08

    properties, i.e., high tensile moduli, and strength of carbon nanotube, we chose carbon nanotube as a reinforcement fiber to enhance the mechanical properties of resulting composite. The main issue encountered while preparing composite was to fully disperse...

  3. Hometown News Scientists prepare for oil contamination

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Hometown News Scientists prepare for oil contamination Posted: 2010 Jun 25 - 00:54 By Jay Meisel organisms. If the oil contaminates reefs in the area, it will probably not totally destroy the reefs

  4. The preparation of states in quantum mechanics

    E-Print Network [OSTI]

    Juerg Froehlich; Baptiste Schubnel

    2014-09-28

    The important problem of how to prepare a quantum mechanical system, $S$, in a specific initial state of interest - e.g., for the purposes of some experiment - is addressed. Three distinct methods of state preparation are described. One of these methods has the attractive feature that it enables one to prepare $S$ in a preassigned initial state with certainty; i.e., the probability of success in preparing $S$ in a given state is unity. This method relies on coupling $S$ to an open quantum-mechanical environment, $E$, in such a way that the dynamics of $S \\vee E$ pulls the state of $S$ towards an "attractor", which is the desired initial state of $S$. This method is analyzed in detail.

  5. Numerically Efficient Parallel Algorithms Prepared for the

    E-Print Network [OSTI]

    Simulation using High Performance Computing Prepared by New Mexico Tech New Mexico Institute of Mining agency thereof. #12;Final Report for Task One Project: Application of High Performance Computing

  6. Brazil Trip, 2014 Prepared by Sukant Misra

    E-Print Network [OSTI]

    Rock, Chris

    1 Brazil Trip, 2014 Prepared by Sukant Misra 1. The Visits: Sao, National Coordinator of TTU ISD in Brazil. 3. Visits of Institutions of Higher/institutions of Brazil, and are the major players of the Brazilian Scientific Mobility Program

  7. Numerically Efficient Parallel Algorithms Prepared for the

    E-Print Network [OSTI]

    Simulation using High Performance Computing Prepared by New Mexico Tech New Mexico Institute of Mining of solutions is found by taking the randomness of wind generation and loads into consideration. A new method

  8. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-11-23

    A method for preparing organoclays for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a specific amount of polymeric hydrotrope, ranging from 0.1 to 15 weight percent relative to the weight of the clay, is adsorbed onto the clay surface. Quaternary amine exchange is also performed on the clay to modify the surface hydrophilic/lipophilic balance (HLB) of the clay.

  9. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL)

    2003-01-01

    A method for preparing organoclays from smectites for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a substantially monomolecular layer of a water soluble polymer is applied to the surfaces of the clay. A surfactant is also applied to the clay to modify the surface hydrophilic/hydrophobic balance of the clay, and the organoclay is separated out for subsequent use.

  10. Return on investment (ROI) proposal preparation guide

    SciTech Connect (OSTI)

    VALERO, O.J.

    1998-10-09

    The ROI Proposal Preparation Guide is a tool to assist Hanford waste generators in preparing ROI proposal forms for submittal to Department of Energy, Richland Operations Office (DOE/RL) for funding. The guide describes the requirements for submitting an ROI proposal and provides examples of completed ROI forms. The intent is to assist waste generators in identifying projects that meet the criteria, provide information necessary to complete the ROI forms, and submit a proposal that is eligible to receive funding.

  11. Los Alamos National Laboratory TRU waste sampling projects

    SciTech Connect (OSTI)

    Yeamans, D.; Rogers, P.; Mroz, E.

    1997-02-01

    The Los Alamos National Laboratory (LANL) has begun characterizing transuranic (TRU) waste in order to comply with New Mexico regulations, and to prepare the waste for shipment and disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. Sampling consists of removing some head space gas from each drum, removing a core from a few drums of each homogeneous waste stream, and visually characterizing a few drums from each heterogeneous waste stream. The gases are analyzed by GC/MS, and the cores are analyzed for VOC`s and SVOC`s by GC/MS and for metals by AA or AE spectroscopy. The sampling and examination projects are conducted in accordance with the ``DOE TRU Waste Quality Assurance Program Plan`` (QAPP) and the ``LANL TRU Waste Quality Assurance Project Plan,`` (QAPjP), guaranteeing that the data meet the needs of both the Carlsbad Area Office (CAO) of DOE and the ``WIPP Waste Acceptance Criteria, Rev. 5,`` (WAC).

  12. U.S. Preparations Exploring Magnetically-Confined

    E-Print Network [OSTI]

    ;Roadmap US path to participation in ITER US technical preparations for ITER US organizational preparations parties if one is added #12;Roadmap US path to participation in ITER US technical preparations for ITER US

  13. Rock Sampling | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, NewMichigan: Energy Resources JumpMtSampling Jump to:

  14. Effect Of Preparation Methods On The Performance Of Co/Al2O3 Catalysts For Dry Reforming Of Methane

    SciTech Connect (OSTI)

    Ewbank, Jessica L.; Kovarik, Libor; Kenvin, Christian C.; Sievers, Carsten

    2014-01-06

    Two methods, dry impregnation (DI) and controlled adsorption (CA), are used for the preparation of Co/ Al2O3 catalysts for methane dry reforming reactions. Point of zero charge (PZC) measurements, pH-precipitation studies, and adsorption isotherms are used to develop a synthesis procedure in which deposition of Co2+ takes place in a more controlled manner than metal deposition during drying in synthesis by dry impregnation. The possible adsorption phenomena that occur during preparation of Co/Al2O3 catalysts by controlled adsorption are discussed. H2 chemisorption and TEM show that catalysts prepared by CA have smaller average particle sizes and higher dispersions. TPR studies show that for the sample prepared by CA a higher amount of cobalt is reduced to its metallic state and that more CoAl2O4 spinel species are present relative to DI samples. The catalyst prepared by CA shows higher activity and slower deactivation for methane dry reforming than the catalyst prepared by DI. XPS and C, H, N analysis on spent catalysts confirm two types of carbonaceous deposits are formed depending on the preparation method.

  15. Final Guidance on Improving the Process for Preparing Efficient...

    Energy Savers [EERE]

    the Process for Preparing Efficient and Timely Environmental Reviews Under the National Environmental Policy Act Final Guidance on Improving the Process for Preparing Efficient...

  16. Diesel HCCI with External Mixture Preparation | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with External Mixture Preparation Diesel HCCI with External Mixture Preparation 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: The Ohio State University...

  17. Preparation of lithium-ion battery anodes using lignin (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Preparation of lithium-ion battery anodes using lignin Citation Details In-Document Search Title: Preparation of lithium-ion battery anodes using lignin Authors:...

  18. Water oxidation using a cobalt monolayer prepared by underpotential...

    Office of Scientific and Technical Information (OSTI)

    Water oxidation using a cobalt monolayer prepared by underpotential deposition Citation Details In-Document Search Title: Water oxidation using a cobalt monolayer prepared by...

  19. EIS-0380: Notice of Intent to Prepare a Supplemental Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Intent to Prepare a Supplemental Environmental Impact Statement EIS-0380: Notice of Intent to Prepare a Supplemental Environmental Impact Statement Continued Operation of Los...

  20. DOE Efforts in Preparing and Improving First Response Capabilities...

    Office of Environmental Management (EM)

    Efforts in Preparing and Improving First Response Capabilities and Performance through Drills and Exercises DOE Efforts in Preparing and Improving First Response Capabilities and...

  1. Student Design Competition Guide to Project Preparation and Submittal...

    Energy Savers [EERE]

    Design Competition Guide to Project Preparation and Submittal Student Design Competition Guide to Project Preparation and Submittal, from the U.S. Department of Energy's Zero...

  2. EIS-0437: Notice of Intent to Prepare an Environmental Impact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intent to Prepare an Environmental Impact Statement and Conduct Scoping Meetings EIS-0437: Notice of Intent to Prepare an Environmental Impact Statement and Conduct Scoping...

  3. Memorandum Guidance for the Preparation of Department of Energy...

    Energy Savers [EERE]

    Guidance for the Preparation of Department of Energy (DOE) Annual Site Environmental reports (ASERs) for Calendar Year 2014 Memorandum Guidance for the Preparation of Department...

  4. Executive Order -- Preparing the United States for the Impacts...

    Office of Environmental Management (EM)

    Executive Order -- Preparing the United States for the Impacts of Climate Change Executive Order -- Preparing the United States for the Impacts of Climate Change...

  5. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur...

  6. HYDRAULIC CONDUCTIVITY OF SALTSTONE FORMULATED USING 1Q11, 2Q11 AND 3Q11 TANK 50 SLURRY SAMPLES

    SciTech Connect (OSTI)

    Reigel, M.; Nichols, R.

    2012-06-27

    As part of the Saltstone formulation work requested by Waste Solidification Engineering (WSE), Savannah River National Laboratory (SRNL) was tasked with preparing Saltstone samples for fresh property analysis and hydraulic conductivity measurements using actual Tank 50 salt solution rather than simulated salt solution. Samples of low level waste salt solution collected from Tank 50H during the first, second, and third quarters of 2011 were used to formulate the Saltstone samples. The salt solution was mixed with premix (45 wt % slag, 45 wt % fly ash, and 10 wt % cement), in a ratio consistent with facility operating conditions during the quarter of interest. The fresh properties (gel, set, bleed) of each mix were evaluated and compared to the recommended acceptance criteria for the Saltstone Production Facility. ASTM D5084-03, Method C was used to measure the hydraulic conductivity of the Saltstone samples. The hydraulic conductivity of Saltstone samples prepared from 1Q11 and 2Q11 samples of Tank 50H is 4.2E-9 cm/sec and 2.6E-9 cm/sec, respectively. Two additional 2Q11 and one 3Q11 sample were not successfully tested due to the inability to achieve stable readings during saturation and testing. The hydraulic conductivity of the samples made from Tank 50H salt solution compare well to samples prepared with simulated salt solution and cured under similar conditions (1.4E-9 - 4.9E-8 cm/sec).

  7. Analysis of tank 39H (HTF-39-15-61, 62) surface and subsurface supernatant samples in support of corrosion control program

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-08-19

    This report provides the results of analyses on Tanks 39H surface and subsurface supernatant liquid samples in support of the Corrosion Control Program. Analyses included warm acid strike preparation followed by analysis for silicon, aluminum, and sodium and water dilution preparation followed by analysis for anions. Other reported analytical results include analyses results for uranium, Pu-241 and Pu-239.

  8. Neutron-Irradiated Samples as Test Materials for MPEX

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ellis, Ronald James; Rapp, Juergen

    2015-10-09

    Plasma Material Interaction (PMI) is a major concern in fusion reactor design and analysis. The Material-Plasma Exposure eXperiment (MPEX) will explore PMI under fusion reactor plasma conditions. Samples with accumulated displacements per atom (DPA) damage produced by fast neutron irradiations in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) will be studied in the MPEX facility. This paper presents assessments of the calculated induced radioactivity and resulting radiation dose rates of a variety of potential fusion reactor plasma-facing materials (such as tungsten). The scientific code packages MCNP and SCALE were used to simulate irradiation of themore »samples in HFIR including the generation and depletion of nuclides in the material and the subsequent composition, activity levels, gamma radiation fields, and resultant dose rates as a function of cooling time. A challenge of the MPEX project is to minimize the radioactive inventory in the preparation of the samples and the sample dose rates for inclusion in the MPEX facility.« less

  9. RAPID SEPARATION OF ACTINIDES AND RADIOSTRONTIUM IN VEGETATION SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-06-01

    A new rapid method for the determination of actinides and radiostrontium in vegetation samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations or for routine analysis. The actinides in vegetation method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Alpha emitters are prepared using rare earth microprecipitation for counting by alpha spectrometry. The purified {sup 90}Sr fractions are mounted directly on planchets and counted by gas flow proportional counting. The method showed high chemical recoveries and effective removal of interferences. The actinide and {sup 90}Sr in vegetation sample analysis can be performed in less than 8 h with excellent quality for emergency samples. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory actinide particles or vegetation residue after furnace heating is effectively digested.

  10. Anthrax Sampling and Decontamination: Technology Trade-Offs

    SciTech Connect (OSTI)

    Price, Phillip N.; Hamachi, Kristina; McWilliams, Jennifer; Sohn, Michael D.

    2008-09-12

    The goal of this project was to answer the following questions concerning response to a future anthrax release (or suspected release) in a building: 1. Based on past experience, what rules of thumb can be determined concerning: (a) the amount of sampling that may be needed to determine the extent of contamination within a given building; (b) what portions of a building should be sampled; (c) the cost per square foot to decontaminate a given type of building using a given method; (d) the time required to prepare for, and perform, decontamination; (e) the effectiveness of a given decontamination method in a given type of building? 2. Based on past experience, what resources will be spent on evaluating the extent of contamination, performing decontamination, and assessing the effectiveness of the decontamination in abuilding of a given type and size? 3. What are the trade-offs between cost, time, and effectiveness for the various sampling plans, sampling methods, and decontamination methods that have been used in the past?

  11. Neutron-Irradiated Samples as Test Materials for MPEX

    SciTech Connect (OSTI)

    Ellis, Ronald James; Rapp, Juergen

    2015-10-09

    Plasma Material Interaction (PMI) is a major concern in fusion reactor design and analysis. The Material-Plasma Exposure eXperiment (MPEX) will explore PMI under fusion reactor plasma conditions. Samples with accumulated displacements per atom (DPA) damage produced by fast neutron irradiations in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) will be studied in the MPEX facility. This paper presents assessments of the calculated induced radioactivity and resulting radiation dose rates of a variety of potential fusion reactor plasma-facing materials (such as tungsten). The scientific code packages MCNP and SCALE were used to simulate irradiation of the samples in HFIR including the generation and depletion of nuclides in the material and the subsequent composition, activity levels, gamma radiation fields, and resultant dose rates as a function of cooling time. A challenge of the MPEX project is to minimize the radioactive inventory in the preparation of the samples and the sample dose rates for inclusion in the MPEX facility.

  12. The beryllium quandary: will the lower exposure limits spur new developments in sampling and analysis?

    SciTech Connect (OSTI)

    Brisson, Michael

    2013-06-03

    At the time this article was written, new rulemakings were under consideration at OSHA and the U.S. Department of Energy (DOE) that would propose changes to occupational exposure limits for beryllium. Given these developments, it’s a good time to review the tools and methods available to IHs for assessing beryllium air and surface contamination in the workplace—what’s new and different, and what’s tried and true. The article discusses limit values and action levels for beryllium, problematic aspects of beryllium air sampling, sample preparation, sample analysis, and data evaluation.

  13. Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskeyFootprintGEXA Corp. (Delaware)GalvestonWindSampling Details

  14. Preparation and screening of crystalline inorganic materials

    DOE Patents [OSTI]

    Schultz, Peter G. (La Jolla, CA); Xiang, Xiaodong (Danville, CA); Goldwasser, Isy (Palo Alto, CA); Brice{hacek over (n)}o, Gabriel (Baldwin Park, CA); Sun, Xiao-Dong (Fremont, CA); Wang, Kai-An (Cupertino, CA)

    2008-10-28

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  15. Rapid fusion method for the determination of Pu, Np, and Am in large soil samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian; Hutchison, Jay B.; McAlister, Daniel R.

    2015-02-14

    A new rapid sodium hydroxide fusion method for the preparation of 10-20 g soil samples has been developed by the Savannah River National Laboratory (SRNL). The method enables lower detection limits for plutonium, neptunium, and americium in environmental soil samples. The method also significantly reduces sample processing time and acid fume generation compared to traditional soil digestion techniques using hydrofluoric acid. Ten gram soil aliquots can be ashed and fused using the new method in 1-2 hours, completely dissolving samples, including refractory particles. Pu, Np and Am are separated using stacked 2mL cartridges of TEVA and DGA Resin and measuredmore »using alpha spectrometry. The method can be adapted for measurement by inductively-coupled plasma mass spectrometry (ICP-MS). Two 10 g soil aliquots of fused soil may be combined prior to chromatographic separations to further improve detection limits. Total sample preparation time, including chromatographic separations and alpha spectrometry source preparation, is less than 8 hours.« less

  16. Gasoline Vehicle Exhuast Particle Sampling Study | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Exhuast Particle Sampling Study Gasoline Vehicle Exhuast Particle Sampling Study 2003 DEER Conference Presentation: University of Minnesota 2003deerkittelson.pdf More...

  17. Apparatus for sectioning demountable semiconductor samples

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Scottsdale, AZ); Wolf, Abraham (Sun City West, AZ)

    1984-01-01

    Apparatus for use during polishing and sectioning operations of a ribbon sample is described. The sample holder includes a cylinder having an axially extending sample cavity terminated in a first funnel-shaped opening and a second slot-like opening. A spring-loaded pressure plunger is located adjacent the second opening of the sample cavity for frictional engagement of the sample prior to introduction of a molding medium in the sample cavity. A heat softenable molding medium is inserted in the funnel-shaped opening, to surround the sample. After polishing, the heater is energized to allow draining of the molding medium from the sample cavity. During manual polishing, the second end of the sample holder is inserted in a support ring which provides mechanical support as well as alignment of the sample holder during polishing. A gauge block for measuring the protrusion of a sample beyond the second wall of the holder is also disclosed.

  18. Nanocrystalline Complex Oxides Prepared by Mechanochemical Reactions

    SciTech Connect (OSTI)

    Sepelak, V. [Institute of Nanotechnology, Karlsruhe Institute of Technology, Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); On leave from the Slovak Academy of Sciences, Watsonova 45, 04353 Kosice (Slovakia); Bergmann, I. [VOLKSWAGEN AG, 38436 Wolfsburg (Germany); Indris, S. [Institute of Nanotechnology, Karlsruhe Institute of Technology, Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Subrt, J. [Institute of Inorganic Chemistry, Academy of Sciences of Czech Republic, 25068 Rez (Czech Republic); Heitjans, P. [Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstrasse 3-3A, 30167 Hannover (Germany); Becker, K.-D. [Institute of Physical and Theoretical Chemistry, Braunschweig University of Technology, Hans-Sommer-Strasse 10, 38106 Braunschweig (Germany)

    2010-07-13

    The preparation of complex oxides by the conventional solid-state (ceramic) route requires a number of stages, including homogenization of the powder precursors, compaction of the reactants, and finally prolonged heat treatment at considerably elevated temperatures under controlled oxygen fugacity. One goal of modern materials research and development has been to identify simpler processing schemes that do not rely upon high-temperature treatments for inducing solid-state reactions. At present, mechanochemical methods become widely used for the preparation of nanocrystalline materials due to their relative simplicity and availability. In this work, selected examples of the preparation of nanoscale complex oxides via single-step mechanochemical routes are presented. Nuclear spectroscopic methods are employed to follow the mechanically induced formation of nanooxides and to characterize the nonequilibrium structural state of the resulting nanophases at the atomic level.

  19. Rapid fusion method for the determination of refractory thorium and uranium isotopes in soil samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Hutchison, Jay B.; McAlister, Daniel R.

    2015-02-14

    Recently, approximately 80% of participating laboratories failed to accurately determine uranium isotopes in soil samples in the U.S Department of Energy Mixed Analyte Performance Evaluation Program (MAPEP) Session 30, due to incomplete dissolution of refractory particles in the samples. Failing laboratories employed acid dissolution methods, including hydrofluoric acid, to recover uranium from the soil matrix. The failures illustrate the importance of rugged soil dissolution methods for the accurate measurement of analytes in the sample matrix. A new rapid fusion method has been developed by the Savannah River National Laboratory (SRNL) to prepare 1-2 g soil sample aliquots very quickly, withmore »total dissolution of refractory particles. Soil samples are fused with sodium hydroxide at 600 ºC in zirconium crucibles to enable complete dissolution of the sample. Uranium and thorium are separated on stacked TEVA and TRU extraction chromatographic resin cartridges, prior to isotopic measurements by alpha spectrometry on cerium fluoride microprecipitation sources. Plutonium can also be separated and measured using this method. Batches of 12 samples can be prepared for measurement in « less

  20. Characterization Data Package for Containerized Sludge Samples Collected from Engineered Container SCS-CON-210

    SciTech Connect (OSTI)

    Fountain, Matthew S.; Fiskum, Sandra K.; Baldwin, David L.; Daniel, Richard C.; Bos, Stanley J.; Burns, Carolyn A.; Carlson, Clark D.; Coffey, Deborah S.; Delegard, Calvin H.; Edwards, Matthew K.; Greenwood, Lawrence R.; Neiner, Doinita; Oliver, Brian M.; Pool, Karl N.; Schmidt, Andrew J.; Shimskey, Rick W.; Sinkov, Sergey I.; Snow, Lanee A.; Soderquist, Chuck Z.; Thompson, Christopher J.; Trang-Le, Truc LT; Urie, Michael W.

    2013-09-10

    This data package contains the K Basin sludge characterization results obtained by Pacific Northwest National Laboratory during processing and analysis of four sludge core samples collected from Engineered Container SCS-CON-210 in 2010 as requested by CH2M Hill Plateau Remediation Company. Sample processing requirements, analytes of interest, detection limits, and quality control sample requirements are defined in the KBC-33786, Rev. 2. The core processing scope included reconstitution of a sludge core sample distributed among four to six 4-L polypropylene bottles into a single container. The reconstituted core sample was then mixed and subsampled to support a variety of characterization activities. Additional core sludge subsamples were combined to prepare a container composite. The container composite was fractionated by wet sieving through a 2,000 micron mesh and a 500-micron mesh sieve. Each sieve fraction was sampled to support a suite of analyses. The core composite analysis scope included density determination, radioisotope analysis, and metals analysis, including the Waste Isolation Pilot Plant Hazardous Waste Facility Permit metals (with the exception of mercury). The container composite analysis included most of the core composite analysis scope plus particle size distribution, particle density, rheology, and crystalline phase identification. A summary of the received samples, core sample reconstitution and subsampling activities, container composite preparation and subsampling activities, physical properties, and analytical results are presented. Supporting data and documentation are provided in the appendices. There were no cases of sample or data loss and all of the available samples and data are reported as required by the Quality Assurance Project Plan/Sampling and Analysis Plan.

  1. Characterization of gels prepared from silicon ethoxide 

    E-Print Network [OSTI]

    Yun, Su-Jin

    1990-01-01

    by heating to a high temperature, with low heating rates. Tg and Tc were correlated to water gt alcohol contents in presence of HCI or HF. Aerogels were found to have high pore volume, low bulk density, large pore size, and weak mechanical strength.... Structures of dried gels 2. 3, Densification 13 14 15 19 19 CHAPTER III 3. 1. Raw materials 3. 2. Xerogel preparation 3. 3. Aerogel preparation 3. 4. Characterization of dried gels 3, 4. 1. Mercury porosimetry 3. 4. 2. BET analysis 3. 4, 3...

  2. Method of preparing meso-haloalkylporphyrins

    DOE Patents [OSTI]

    Wijesekera, Tilak (Glen Mills, PA); Lyons, James E. (Wallingford, PA); Ellis, Jr., Paul E. (Downingtown, PA); Bhinde, Manoj V. (Boothwyn, PA)

    1998-01-01

    Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solid catalyst. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solic catalyst.

  3. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  4. Sample introduction apparatus for a flow cytometer

    DOE Patents [OSTI]

    Van den Engh, Ger (Seattle, WA)

    1998-01-01

    A sample introduction system for a flow cytometer allows easy change of sample containers such as test tubes and facilitates use in high pressure environments. The sample container includes a cap having a pressure supply chamber and a sample container attachment cavity. A sample container may be automatically positioned into the attachment cavity so as to sealably engage the end of the sample container as its outer surface. This positioning may be accomplished through some sample introduction mechanism. To facilitate cleaning HPLC tubing and fittings may be used in a manner which facilitates removable of the entire tubing from both the nozzle container and other sample container cap to permit its replacement to avoid contamination. The sample container support may include horizontal stops which loosely limit the movement of the sample container and thus avoid further stresses upon it.

  5. Apparatus for sectioning demountable semiconductor samples

    DOE Patents [OSTI]

    Sopori, B.L.; Wolf, A.

    1984-01-01

    Apparatus for use during polishing and sectioning operations of a ribbon sample is described. The sample holder includes a cylinder having an axially extending sample cavity terminated in a first funnel-shaped opening and a second slot-like opening. A spring-loaded pressure plunger is located adjacent the second opening of the sample cavity for frictional engagement of the sample cavity. A heat softenable molding medium is inserted in the funnel-shaped opening, to surround the sample. After polishing, the heater is energized to allow draining of the molding medium from the sample cavity. During manual polishing, the second end of the sample holder is inserted in a support ring which provides mechanical support as well as alignment of the sample holder during polishing. A gauge block for measuring the protrusion of a sample beyond the second wall of the holder is also disclosed.

  6. PHYSICAL PROPERTY MEASUREMENTS OF LABORATORY PREPARED SALTSTONE GROUT

    SciTech Connect (OSTI)

    Hansen, E.; Cozzi, A.; Edwards, T.

    2014-05-05

    The Saltstone Production Facility (SPF) built two new Saltstone Disposal Units (SDU), SDU 3 and SDU 5, in 2013. The variable frequency drive (VFD) for the grout transfer hose pump tripped due to high current demand by the motor during the initial radioactive saltstone transfer to SDU 5B on 12/5/2013. This was not observed during clean cap processing on July 5, 2013 to SDU 3A, which is a slightly longer distance from the SPF than is SDU 5B. Saltstone Design Authority (SDA) is evaluating the grout pump performance and capabilities to transfer the grout processed in SPF to SDU 3/5. To assist in this evaluation, grout physical properties are required. At this time, there are no rheological data from the actual SPF so the properties of laboratory prepared samples using simulated salt solution or Tank 50 salt solution will be measured. The physical properties of grout prepared in the laboratory with de-ionized water (DI) and salt solutions were obtained at 0.60 and 0.59 water to premix (W/P) ratios, respectively. The yield stress of the DI grout was greater than any salt grout. The plastic viscosity of the DI grout was lower than all of the salt grouts (including salt grout with admixture). When these physical data were used to determine the pressure drop and fluid horsepower for steady state conditions, the salt grouts without admixture addition required a higher pressure drop and higher fluid horsepower to transport. When 0.00076 g Daratard 17/g premix was added, both the pressure drop and fluid horsepower were below that of the DI grout. Higher concentrations of Daratard 17 further reduced the pressure drop and fluid horsepower. The uncertainty in the single point Bingham Plastic parameters is + 4% of the reported values and is the bounding uncertainty. Two different mechanical agitator mixing protocols were followed for the simulant salt grout, one having a total mixing time of three minutes and the other having a time of 10 minutes. The Bingham Plastic parameters were essentially the same for the salt grout without admixture. When Daratard 17 was added, the Bingham Plastic yield stress increased for the 10 minute mix. The simulant salt used in this task had similar physical properties of the Tank 50 3Q13 salt grout and is recommended for future use, if the salt solution in Tank 50 does not change. The design basis physical properties used to size the pumps and mixers at SPF were obtained from DPST-85-312. The grouts characterized in this report are bounded by the design basis density and Bingham Plastic yield stress. The opposite is true for the plastic viscosity. Steady state pressure drop calculations were performed for the design basis values using the flow rate for the clean cap and salt grouts and they bound the pressure drop of the grouts characterized in this report. A comparison of the lab prepared samples to PI ProcessBook data, specifically average pressure drop, indicate that the lab prepared samples are more viscous in nature than what is processed in the facility. This difference could be due to the applied shear rates which could be lower in the lab as compared to the facility and that fact the SPF added flush water, making this comparison more difficult. A perfunctory review of the PI ProcessBook data was discussed. It may be possible that the frequency that the distributed control system alters the grout pump speed to maintain grout hopper volume can negatively affect the efficiency of the grout pump.

  7. Pi sampling: a methodical and flexible approach to initial macromolecular crystallization screening

    SciTech Connect (OSTI)

    Gorrec, Fabrice, E-mail: fgorrec@mrc-lmb.cam.ac.uk; Palmer, Colin M.; Lebon, Guillaume; Warne, Tony [MRC Laboratory of Molecular Biology, Hills Road, Cambridge CB2 0QH (United Kingdom)

    2011-05-01

    Pi sampling, derived from the incomplete factorial approach, is an effort to maximize the diversity of macromolecular crystallization conditions and to facilitate the preparation of 96-condition initial screens. The Pi sampling method is derived from the incomplete factorial approach to macromolecular crystallization screen design. The resulting ‘Pi screens’ have a modular distribution of a given set of up to 36 stock solutions. Maximally diverse conditions can be produced by taking into account the properties of the chemicals used in the formulation and the concentrations of the corresponding solutions. The Pi sampling method has been implemented in a web-based application that generates screen formulations and recipes. It is particularly adapted to screens consisting of 96 different conditions. The flexibility and efficiency of Pi sampling is demonstrated by the crystallization of soluble proteins and of an integral membrane-protein sample.

  8. Leafy Green Preparation and Cooling Study

    E-Print Network [OSTI]

    Leafy Green Preparation and Cooling Study Dominique N. Bibbins #12;Background : Leafy Greens z. #12;Background: Cooling Study z This study observes how restaurants keep their food cooled Food-borne illnesses may result when foods are improperly cooled or stored. #12;My Contribution z

  9. Preparation of III-V semiconductor nanocrystals

    DOE Patents [OSTI]

    Alivisatos, A.P.; Olshavsky, M.A.

    1996-04-09

    Nanometer-scale crystals of III-V semiconductors are disclosed. They are prepared by reacting a group III metal source with a group V anion source in a liquid phase at elevated temperature in the presence of a crystallite growth terminator such as pyridine or quinoline. 4 figs.

  10. Global Climate Dialogue Prepared by Kershney Naidoo

    E-Print Network [OSTI]

    Global Climate Dialogue Prepared by Kershney Naidoo In a historic moment of Justice for the Climate) backgrounds. It aimed to establish a set of guiding global principles for a just response to climate change. The intention of the Climate Justice Dialogue was to lend new impetus to an awareness of climate change

  11. Technical Note Graphene: Substrate preparation and introduction

    E-Print Network [OSTI]

    Technical Note Graphene: Substrate preparation and introduction Radosav S. Pantelic a , Ji Won Suk September 2010 Accepted 4 October 2010 Available online xxxx Keywords: Graphene Graphene oxide Cryo the transfer of continuous, single-layer, pristine graphene to standard Quan- tifoil TEM grids. We compare

  12. Hawaii Bioenergy Master Plan Prepared for

    E-Print Network [OSTI]

    Hawaii Bioenergy Master Plan Volume I Prepared for State of Hawaii Department of Business, Economic Development and Tourism By University of Hawaii Hawaii Natural Energy Institute School of Ocean Earth Sciences and Environmental Management, University of Hawaii Denise Antolini, Professor, William S Richardson School of Law

  13. GIS Ethics Panel Preparation Panel Session

    E-Print Network [OSTI]

    Wright, Dawn Jeannine

    GIS Ethics Panel Preparation Panel Session: 3236 Geographic Information Ethics and GIScience II State University Geney Terry - GISCI Session Description: Ethical engagements with the multitude of GIS, the variety of applications of GIS&T has led the U.S. Department of Labor to highlight "geographic technology

  14. Preparation of a semiconductor thin film

    DOE Patents [OSTI]

    Pehnt, M.; Schulz, D.L.; Curtis, C.J.; Ginley, D.S.

    1998-01-27

    A process is disclosed for the preparation of a semiconductor film. The process comprises depositing nanoparticles of a semiconductor material onto a substrate whose surface temperature during nanoparticle deposition thereon is sufficient to cause substantially simultaneous fusion of the nanoparticles to thereby coalesce with each other and effectuate film growth.

  15. Test Preparation Options Free Test Prep Websites

    E-Print Network [OSTI]

    Stowell, Michael

    Test Preparation Options Free Test Prep Websites ACT: http: http://www.collegeboard.com/student/testing/sat/prep_one/test.html http://www.number2.com://testprep.princetonreview.com/CourseSearch/Search.aspx?itemCode=17&productType=F&rid=1&zip=803 02 Test Prep Classes Front Range Community College: Classes

  16. Isolation of Yeast DNA Prepare in advance

    E-Print Network [OSTI]

    Aris, John P.

    Isolation of Yeast DNA Prepare in advance: · 2.0 ml microfuge tubes containing 0.25 g of 0.5 mm600 ~1, or 1 ml saturated YPD culture at OD600 ~10). Centrifuge for 5 minutes at 2000 rpm. Discard will thaw during centrifugation. Transfer supernatant (200-225 µl) to a fresh 1.5 ml tube. Avoid

  17. State Agency Land Leases Prepared for the

    E-Print Network [OSTI]

    and Energy Reliability Under Cooperative Agreement No. DE-FC26-06NT42847 Hawai`i Distributed Energy Resource: This material is based upon work supported by the United States Department of Energy under Cooperative AgreementState Agency Land Leases Prepared for the U.S. Department of Energy Office of Electricity Delivery

  18. LEAM Film Development Test Report Prepared by

    E-Print Network [OSTI]

    Rathbun, Julie A.

    ~~ ··········~~~ LEAM Film Development Test Report Prepared by: R. Sii'r'...ms ~1 rf\\:'3· ~ ij ATM Film Development Test Report -~~'·.· ··..· .··. . ~...=-~ ~ IWitJY~W ' ~· CONTENTS 1. PURPOSE 2. SCOPE 3. OBJECTIVES 4. EQUIPMENT DESCRIPTION 4.1 TEST ARTICLE 4.1.1 Film and Film Frame 4.1. 2 Calorimeter

  19. Energy Efficient Data Centers Prepared by

    E-Print Network [OSTI]

    Energy Efficient Data Centers Prepared by William Tschudi, Tengfang Xu, Dale Sartor, Bruce Nordman - Tengfang Xu - Bruce Nordman Data Center Case Studies · Sub-contractors - Peter Rumsey, Rumsey Engineers · Additional Investigators: - Jon Koomey - Osman Sezgen - John Steinmetz Data Center Energy Research Roadmap

  20. Process of preparing tritiated porous silicon

    DOE Patents [OSTI]

    Tam, S.W.

    1997-02-18

    A process of preparing tritiated porous silicon is described in which porous silicon is equilibrated with a gaseous vapor containing HT/T{sub 2} gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon. 1 fig.

  1. Preparation of a semiconductor thin film

    DOE Patents [OSTI]

    Pehnt, Martin (TuBingen, DE); Schulz, Douglas L. (Denver, CO); Curtis, Calvin J. (Lakewood, CO); Ginley, David S. (Evergreen, CO)

    1998-01-01

    A process for the preparation of a semiconductor film. The process comprises depositing nanoparticles of a semiconductor material onto a substrate whose surface temperature during nanoparticle deposition thereon is sufficient to cause substantially simultaneous fusion of the nanoparticles to thereby coalesce with each other and effectuate film growth.

  2. Process for the preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-02-17

    This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85 and 200 C and removing the reaction products from the contact zone.

  3. Energy Simulation Training Prepared for the

    E-Print Network [OSTI]

    Energy Simulation Training Prepared for the U.S. Department of Energy Office of Electricity Simulation Training Provided to the Hawai`i Natural Energy Institute April 1, 2013 Project funded by US ...........................................................................................................................................3 Part 1: Semester Course in Whole Building Energy Simulation .................................3

  4. Preparation and characterization of transparent PZNPLZT ceramics

    E-Print Network [OSTI]

    Cao, Wenwu

    Preparation and characterization of transparent PZN­PLZT ceramics Q.R Yin,a) A.L. Ding, X.S. Zheng, and P.S. Qiu The State Key Laboratory of High Performance Ceramics and Superfire Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Ding Xi Road, 200050, Shanghai, China M

  5. PREPARING THE VIRTUAL CLASSROOM FOR DISTANCE DELIVERY

    E-Print Network [OSTI]

    Dyer, Bill

    of humans and their companion domestic animals and livestock. Students learn that there are certain "at riskPREPARING THE VIRTUAL CLASSROOM FOR DISTANCE DELIVERY: MEDICAL-VETERINARY ENTOMOLOGY CLINICS laboratory," library materials, conventional lectures and the 43 virtual patients in the clinics

  6. Preparation and characterization of palladium particles

    SciTech Connect (OSTI)

    Silver, G.L.; Leahy, B.T.; Martin, F.S.

    1989-02-15

    Palladium particles were prepared by burning palladium loaded ion exchange resins and reducing the combustion products with hydrogen gas. The particles can be compressed into pellets. Properties of the pellets, such as resistance to the flow of hydrogen gas and rate of exchange with deuterium, have been measured. 2 refs., 16 figs., 17 tabs.

  7. Photocatalytic methods for preparation of electrocatalyst materials

    DOE Patents [OSTI]

    Nwoga, Tochi Tudor; Kawahara, Kazuo; Li, Wen; Song, Yujiang; Shelnutt, John A; Miller, James E; Medforth, Craig John; Ueno, Yukiyoshi; Kawamura, Tetsuo

    2013-12-17

    The invention relates to methods of preparing metal particles on a support material, including platinum-containing nanoparticles on a carbon support. Such materials can be used as electrocatalysts, for example as improved electrocatalysts in proton exchange membrane fuel cells (PEM-FCs).

  8. Photocatalytic methods for preparation of electrocatalyst materials

    DOE Patents [OSTI]

    Li, Wen; Kawamura, Tetsuo; Nagami, Tetsuo; Takahashi, Hiroaki; Muldoon, John; Shelnutt, John A; Song, Yujiang; Miller, James E; Hickner, Michael A; Medforth, Craig

    2013-09-24

    The invention relates to methods of preparing metal particles on a support material, including platinum-containing nanoparticles on a carbon support. Such materials can be used as electrocatalysts, for example as improved electrocatalysts in polymer electrolyte membrane fuel cells (PEM-FCs).

  9. Diffraction-limited ultrasensitive molecular nano-arrays with singular nano-cone Yunshan Wang, Ting-Chou Chang, Paul R. Stoddart, and Hsueh-Chia Chang

    E-Print Network [OSTI]

    Chang, Hsueh-Chia

    Wang, Ting-Chou Chang, Paul R. Stoddart, and Hsueh-Chia Chang Citation: Biomicrofluidics 8, 021101-arrays with singular nano-cone scattering Yunshan Wang,1 Ting-Chou Chang,1 Paul R. Stoddart,2 and Hsueh-Chia Chang1 1

  10. WIPP waste characterization program sampling and analysis guidance manual

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The Waste Isolation Pilot Plant (WIPP) Waste Characterization Program Sampling and Analysis Guidance Manual (Guidance Manual) provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Quality Assurance Program Plan (QAPP) for the WIPP Experimental-Waste Characterization Program (the Program). This Guidance Manual includes all of the sampling and testing methodologies accepted by the WIPP Project Office (DOE/WPO) for use in implementing the Program requirements specified in the QAPP. This includes methods for characterizing representative samples of transuranic (TRU) wastes at DOE generator sites with respect to the gas generation controlling variables defined in the WIPP bin-scale and alcove test plans, as well as waste container headspace gas sampling and analytical procedures to support waste characterization requirements under the WIPP test program and the Resource Conservation and Recovery Act (RCRA). The procedures in this Guidance Manual are comprehensive and detailed and are designed to provide the necessary guidance for the preparation of site specific procedures. The use of these procedures is intended to provide the necessary sensitivity, specificity, precision, and comparability of analyses and test results. The solutions to achieving specific program objectives will depend upon facility constraints, compliance with DOE Orders and DOE facilities' operating contractor requirements, and the knowledge and experience of the TRU waste handlers and analysts. With some analytical methods, such as gas chromatography/mass spectrometry, the Guidance Manual procedures may be used directly. With other methods, such as nondestructive/destructive characterization, the Guidance Manual provides guidance rather than a step-by-step procedure.

  11. Electrphoretic Sample Excitation Light Assembly.

    DOE Patents [OSTI]

    Li, Qingbo (State College, PA); Liu, Changsheng (State College, PA)

    2002-04-02

    An automated electrophoretic system is disclosed. The system employs a capillary cartridge having a plurality of capillary tubes. The cartridge has a first array of capillary ends projecting from one side of a plate. The first array of capillary ends are spaced apart in substantially the same manner as the wells of a microtitre tray of standard size. This allows one to simultaneously perform capillary electrophoresis on samples present in each of the wells of the tray. The system includes a stacked, dual carrousel arrangement to eliminate cross-contamination resulting from reuse of the same buffer tray on consecutive executions from electrophoresis. The system also has a gel delivery module containing a gel syringe/a stepper motor or a high pressure chamber with a pump to quickly and uniformly deliver gel through the capillary tubes. The system further includes a multi-wavelength beam generator to generate a laser beam which produces a beam with a wide range of wavelengths. An off-line capillary reconditioner thoroughly cleans a capillary cartridge to enable simultaneous execution of electrophoresis with another capillary cartridge. The streamlined nature of the off-line capillary reconditioner offers the advantage of increased system throughput with a minimal increase in system cost.

  12. Method and apparatus for data sampling

    DOE Patents [OSTI]

    Odell, Daniel M. C. (Aiken, SC)

    1994-01-01

    A method and apparatus for sampling radiation detector outputs and determining event data from the collected samples. The method uses high speed sampling of the detector output, the conversion of the samples to digital values, and the discrimination of the digital values so that digital values representing detected events are determined. The high speed sampling and digital conversion is performed by an A/D sampler that samples the detector output at a rate high enough to produce numerous digital samples for each detected event. The digital discrimination identifies those digital samples that are not representative of detected events. The sampling and discrimination also provides for temporary or permanent storage, either serially or in parallel, to a digital storage medium.

  13. Method and apparatus for data sampling

    DOE Patents [OSTI]

    Odell, D.M.C.

    1994-04-19

    A method and apparatus for sampling radiation detector outputs and determining event data from the collected samples is described. The method uses high speed sampling of the detector output, the conversion of the samples to digital values, and the discrimination of the digital values so that digital values representing detected events are determined. The high speed sampling and digital conversion is performed by an A/D sampler that samples the detector output at a rate high enough to produce numerous digital samples for each detected event. The digital discrimination identifies those digital samples that are not representative of detected events. The sampling and discrimination also provides for temporary or permanent storage, either serially or in parallel, to a digital storage medium. 6 figures.

  14. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, L.K.; Alper, N.I.

    1994-11-22

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump. 1 fig.

  15. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, Louis K. (Monroeville, PA); Alper, Naum I. (Monroeville, PA)

    1994-01-01

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

  16. 1 Prepared for the Education Library at Queen's University, September 2009. How to tistics: Teach with Sta

    E-Print Network [OSTI]

    Abolmaesumi, Purang

    1 Prepared for the Education Library at Queen's University, September 2009. How to tistics in contexts such as sampling and surveying and the use of statistics to analyze trends. Recognizing in advertising, opinion polls, population trends, reliability estimates, descriptions of discoveries

  17. Manuscript prepared for J. Name with version 4.2 of the LATEX class copernicus.cls.

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Manuscript prepared for J. Name with version 4.2 of the LATEX class copernicus.cls. Date: 19 July from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning Martin K, and burning capacities. If not specified differently, two samples (A and B) were taken at the same location

  18. Extraction of Proteins Glass Bead Method For preparation of protein extracts, the glass bead method is preferred. Some researchers

    E-Print Network [OSTI]

    Extraction of Proteins ­ Glass Bead Method For preparation of protein extracts, the glass bead method is preferred. Some researchers suggest more than one wash step (Step 1) to remove any residual. Protein Extraction Buffer 3. SDS-Page Sample Buffer 4. 15 mL conical tubes 5. 2 mL sardstedt tubes 6

  19. Extraction of Plutonium From Spiked INEEL Soil Samples Using the Ligand-Assisted Supercritical Fluid Extraction (LA-SFE) Technique

    SciTech Connect (OSTI)

    Fox, R.V.; Mincher, B.J.; Holmes, R.G.G.

    1999-08-01

    In order to investigate the effectiveness of ligand-assisted supercritical fluid extraction for the removal of transuranic contaminations from soils an Idaho National Engineering and Environmental Laboratory (INEEL) silty-clay soil sample was obtained from near the Radioactive Waste Management Complex area and subjected to three different chemical preparations before being spiked with plutonium. The spiked INEEL soil samples were subjected to a sequential aqueous extraction procedure to determine radionuclide portioning in each sample. Results from those extractions demonstrate that plutonium consistently partitioned into the residual fraction across all three INEEL soil preparations whereas americium partitioned 73% into the iron/manganese fraction for soil preparation A, with the balance partitioning into the residual fraction. Plutonium and americium were extracted from the INEEL soil samples using a ligand-assisted supercritical fluid extraction technique. Initial supercritical fluid extraction runs produced plutonium extraction technique. Initial supercritical fluid extraction runs produced plutonium extraction efficiencies ranging from 14% to 19%. After a second round wherein the initial extraction parameters were changed, the plutonium extraction efficiencies increased to 60% and as high as 80% with the americium level in the post-extracted soil samples dropping near to the detection limits. The third round of experiments are currently underway. These results demonstrate that the ligand-assisted supercritical fluid extraction technique can effectively extract plutonium from the spiked INEEL soil preparations.

  20. Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting

    SciTech Connect (OSTI)

    Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

    2012-04-30

    Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

  1. ALARA ASSESSMENT OF SETTLER SLUDGE SAMPLING METHODS

    SciTech Connect (OSTI)

    NELSEN LA

    2009-01-30

    The purpose of this assessment is to compare underwater and above water settler sludge sampling methods to determine if the added cost for underwater sampling for the sole purpose of worker dose reductions is justified. Initial planning for sludge sampling included container, settler and knock-out-pot (KOP) sampling. Due to the significantly higher dose consequence of KOP sludge, a decision was made to sample KOP underwater to achieve worker dose reductions. Additionally, initial plans were to utilize the underwater sampling apparatus for settler sludge. Since there are no longer plans to sample KOP sludge, the decision for underwater sampling for settler sludge needs to be revisited. The present sampling plan calls for spending an estimated $2,500,000 to design and construct a new underwater sampling system (per A21 C-PL-001 RevOE). This evaluation will compare and contrast the present method of above water sampling to the underwater method that is planned by the Sludge Treatment Project (STP) and determine if settler samples can be taken using the existing sampling cart (with potentially minor modifications) while maintaining doses to workers As Low As Reasonably Achievable (ALARA) and eliminate the need for costly redesigns, testing and personnel retraining.

  2. DWPF Sample Vial Insert Study-Statistical Analysis of DWPF Mock-Up Test Data

    SciTech Connect (OSTI)

    Harris, S.P. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1997-09-18

    This report is prepared as part of Technical/QA Task Plan WSRC-RP-97-351 which was issued in response to Technical Task Request HLW/DWPF/TTR-970132 submitted by DWPF. Presented in this report is a statistical analysis of DWPF Mock-up test data for evaluation of two new analytical methods which use insert samples from the existing HydragardTM sampler. The first is a new hydrofluoric acid based method called the Cold Chemical Method (Cold Chem) and the second is a modified fusion method.Either new DWPF analytical method could result in a two to three fold improvement in sample analysis time.Both new methods use the existing HydragardTM sampler to collect a smaller insert sample from the process sampling system. The insert testing methodology applies to the DWPF Slurry Mix Evaporator (SME) and the Melter Feed Tank (MFT) samples.The insert sample is named after the initial trials which placed the container inside the sample (peanut) vials. Samples in small 3 ml containers (Inserts) are analyzed by either the cold chemical method or a modified fusion method. The current analytical method uses a HydragardTM sample station to obtain nearly full 15 ml peanut vials. The samples are prepared by a multi-step process for Inductively Coupled Plasma (ICP) analysis by drying, vitrification, grinding and finally dissolution by either mixed acid or fusion. In contrast, the insert sample is placed directly in the dissolution vessel, thus eliminating the drying, vitrification and grinding operations for the Cold chem method. Although the modified fusion still requires drying and calcine conversion, the process is rapid due to the decreased sample size and that no vitrification step is required.A slurry feed simulant material was acquired from the TNX pilot facility from the test run designated as PX-7.The Mock-up test data were gathered on the basis of a statistical design presented in SRT-SCS-97004 (Rev. 0). Simulant PX-7 samples were taken in the DWPF Analytical Cell Mock-up Facility using 3 ml inserts and 15 ml peanut vials. A number of the insert samples were analyzed by Cold Chem and compared with full peanut vial samples analyzed by the current methods. The remaining inserts were analyzed by the modified fusion method, for comparison to the current method, and also to obtain a calcine correction factor. The simulant was within 40 - 42 wt% solids in order to provide a rheology within the DWPF design range. The rheology at 42 wt% was approximately 47 dynes/cm2 yield stress at 251/4C.

  3. Curve sampling and geometric conditional simulation

    E-Print Network [OSTI]

    Fan, Ayres C. (Ayres Chee), 1978-

    2008-01-01

    The main objective of this thesis is the development and exploitation of techniques to generate geometric samples for the purpose of image segmentation. A sampling-based approach provides a number of benefits over existing ...

  4. Principles for Sampling Airborne Radioactivity from Stacks

    SciTech Connect (OSTI)

    Glissmeyer, John A.

    2010-10-18

    This book chapter describes the special processes involved in sampling the airborne effluents from nuclear faciities. The title of the book is Radioactive Air Sampling Methods. The abstract for this chapter was cleared as PNNL-SA-45941.

  5. Adaptive Basis Sampling for Smoothing Splines 

    E-Print Network [OSTI]

    Zhang, Nan

    2015-08-03

    . However, the high computational cost of smoothing splines for large data sets has hindered their wide application. We develop a new method, named adaptive basis sampling, for efficient computation of smoothing splines in super-large samples. Generally, a...

  6. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

    1995-05-30

    Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

  7. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, Benjamin R. (Santa Fe, NM); McBranch, Duncan W. (Santa Fe, NM); Robinson, Jeanne M. (Los Alamos, NM); Koskelo, Aaron C. (Los Alamos, NM); Love, Steven P. (Los Alamos, NM)

    1995-01-01

    Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

  8. Process for preparing a liquid fuel composition

    DOE Patents [OSTI]

    Singerman, Gary M. (Monroeville, PA)

    1982-03-16

    A process for preparing a liquid fuel composition which comprises liquefying coal, separating a mixture of phenols from said liquefied coal, converting said phenols to the corresponding mixture of anisoles, subjecting at least a portion of the remainder of said liquefied coal to hydrotreatment, subjecting at least a portion of said hydrotreated liquefied coal to reforming to obtain reformate and then combining at least a portion of said anisoles and at least a portion of said reformate to obtain said liquid fuel composition.

  9. Arc Casting Intermetallic Alloy (Materials Preparation Center)

    SciTech Connect (OSTI)

    2010-01-01

    Arc casting of intermetallic (La-Ni-Sn) AB5 alloy used for metal hydride hydrogen storage. Upon solidification the Sn is partially rejected and increases in concentration in the remaining liquid. Upon completing solidification there is a great deal of internal stress in the ingot. As the ingot cools further the stress is relieved. This material was cast at the Ames Laboratorys Materials Preparation Center http://www.mpc.ameslab.gov

  10. Preparation of nitrogen-doped carbon tubes

    DOE Patents [OSTI]

    Chung, Hoon Taek; Zelenay, Piotr

    2015-12-22

    A method for synthesizing nitrogen-doped carbon tubes involves preparing a solution of cyanamide and a suitable transition metal-containing salt in a solvent, evaporating the solvent to form a solid, and pyrolyzing the solid under an inert atmosphere under conditions suitable for the production of nitrogen-doped carbon tubes from the solid. Pyrolyzing for a shorter period of time followed by rapid cooling resulted in a tubes with a narrower average diameter.

  11. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

    1980-01-21

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  12. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

    1981-01-01

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  13. Preparation of nanostructured materials having improved ductility

    DOE Patents [OSTI]

    Zhao, Yonghao; Zhu, Yuntian T.

    2010-04-20

    A method for preparing a nanostructured aluminum alloy involves heating an aluminum alloy workpiece at temperature sufficient to produce a single phase coarse grained aluminum alloy, then refining the grain size of the workpiece at a temperature at or below room temperature, and then aging the workpiece to precipitate second phase particles in the nanosized grains of the workpiece that increase the ductility without decreasing the strength of the workpiece.

  14. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  15. Program Evaluation: Preparation Activities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits theCommitteeCrystallineReserveInformation ResourcesPreparation Activities

  16. Preparing for Hurricane Season | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONAL CHAIRS MEETINGof2015 |Industry |Prepare for

  17. Preparing for Project Implementation Financing Project Implementation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONAL CHAIRS MEETINGof2015 |Industry |Prepare forJulyAugust

  18. ANALYSIS OF SAMPLES FROM TANK 5F CHEMICAL CLEANING

    SciTech Connect (OSTI)

    Poirier, M.; Fink, S.

    2011-03-07

    The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. The conclusions from this work are: (1) With the exception of iron, the dissolution of sludge components from Tank 5F agreed with results from the actual waste demonstration performed in 2007. The fraction of iron removed from Tank 5F by chemical cleaning was significantly less than the fraction removed in the SRNL demonstrations. The likely cause of this difference is the high pH following the first oxalic acid strike. (2) Most of the sludge mass remaining in the tank is iron and nickel. (3) The remaining sludge contains approximately 26 kg of barium, 37 kg of chromium, and 37 kg of mercury. (4) Most of the radioactivity remaining in the residual material is beta emitters and {sup 90}Sr. (5) The chemical cleaning removed more than {approx} 90% of the uranium isotopes and {sup 137}Cs. (6) The chemical cleaning removed {approx} 70% of the neptunium, {approx} 83% of the {sup 90}Sr, and {approx} 21% of the {sup 60}Co. (7) The chemical cleaning removed less than 10% of the plutonium, americium, and curium isotopes. (8) The chemical cleaning removed more than 90% of the aluminium, calcium, and sodium from the tank. (9) The cleaning operations removed 61% of lithium, 88% of non-radioactive strontium, and 65% of zirconium. The {sup 90}Sr and non-radioactive strontium were measured by different methods, and the differences in the fraction removed are not statistically significant. (10) Chemical cleaning removed 10-50% of the barium, chromium, iron, magnesium, manganese, and silicon. (11) Chemical cleaning removed only {approx}1% of the nickel.

  19. Fourier Sampling Coset States of Nonabelian Groups

    E-Print Network [OSTI]

    Hallgren, Sean

    55 Chapter 6 Fourier Sampling Coset States of Nonabelian Groups In this chapter we analyze the HSP problem, to the HSP over the symmetric group S n . In particular, we will analyze Fourier sampling coset states when the group is nonabelian. We show that Fourier sampling a polynomial number of coset states

  20. FNR 3410C Natural Resource Sampling FNR 3410C -NATURAL RESOURCE SAMPLING

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    of sampling. Design of cost-effective sample surveys. Sampling methodology applicable 0211 (Mechanical & Aerospace Engineering) Lab 1 Period 7-9 13:55-16:55 M BLK begins with a review of elementary statistics and continues with specific

  1. Solar Ready Vets: Preparing Our Veterans to Join the Growing...

    Office of Environmental Management (EM)

    Solar Ready Vets: Preparing Our Veterans to Join the Growing Solar Workforce Solar Ready Vets: Preparing Our Veterans to Join the Growing Solar Workforce April 6, 2015 - 2:27pm...

  2. UMBC Department of Education Early Childhood Education Personnel Preparation Program

    E-Print Network [OSTI]

    Adali, Tulay

    UMBC Department of Education Early Childhood Education Personnel Preparation Program Procedures, Early Childhood Education Department of Education UMBC 1000 Hilltop Circle Baltimore, MD 21250 #12;UMBC DEPARTMENT OF EDUCATION EARLY CHILDHOOD PERSONNEL PREPARATION PROGRAM UNDERGRADUATE APPLICATION Present Date

  3. University Planning Framework Prepared By: University Planning Committee

    E-Print Network [OSTI]

    Kavanagh, Karen L.

    University Planning Framework Prepared By: University Planning Committee Date Prepared: July 2014 Contact: Scott Penney, Director, Planning & Analysis scott_penney@sfu.ca | 778-782-7513 #12;University Planning Framework Page 1 Contents Contents

  4. Preparing the Next Generation of Bioenergy Leaders | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preparing the Next Generation of Bioenergy Leaders Preparing the Next Generation of Bioenergy Leaders March 31, 2015 - 5:12pm Addthis Dr. Valerie Sarisky-Reed Dr. Valerie...

  5. Appendix A. Notice of Inquiry: Preparation of Report to Congress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A. Notice of Inquiry: Preparation of Report to Congress on Price-Anderson Act. 62 Federal Register 68,272 (December 31, 1997) Appendix A. Notice of Inquiry: Preparation of Report...

  6. Elemental Analyses of Hanford Surface Neutron Moisture Measurement Calibration Standard Samples

    SciTech Connect (OSTI)

    Watson, W.T., Westinghouse Hanford

    1996-07-31

    Elemental analyses have been performed on twenty samples taken from the moisture standards prepared to use in performing experimental calibrations of the surface neutron moisture measurement system. These standards consisted of mixtures of sand, hydrated alumina, and boron carbide. Elemental analyses were performed primarily to discover the quantities of any strong thermal neutron absorbers that may have been present in the mixture in unknown trace quantities.

  7. Sample sizes for confidence limits for reliability.

    SciTech Connect (OSTI)

    Darby, John L.

    2010-02-01

    We recently performed an evaluation of the implications of a reduced stockpile of nuclear weapons for surveillance to support estimates of reliability. We found that one technique developed at Sandia National Laboratories (SNL) under-estimates the required sample size for systems-level testing. For a large population the discrepancy is not important, but for a small population it is important. We found that another technique used by SNL provides the correct required sample size. For systems-level testing of nuclear weapons, samples are selected without replacement, and the hypergeometric probability distribution applies. Both of the SNL techniques focus on samples without defects from sampling without replacement. We generalized the second SNL technique to cases with defects in the sample. We created a computer program in Mathematica to automate the calculation of confidence for reliability. We also evaluated sampling with replacement where the binomial probability distribution applies.

  8. Sample Preparation Methods and Pre-harvest Factors Influencing the Contents of Bioactive Compounds and Antioxidant Activity in Peppers 

    E-Print Network [OSTI]

    Bae, Hae Jin

    2012-02-14

    Peppers are a rich source of diverse bioactive compounds with potential health-promoting properties. The levels of bioactive compounds and antioxidant activity can be affected by analytical methods, pre-harvest factors, ...

  9. Characterization of Green-Emitting Translucent Zinc Oxide Ceramics Prepared Via Spark Plasma Sintering

    SciTech Connect (OSTI)

    Hong, Mei [University of California; DeVito, David M [ORNL; Howe, Jane Y [ORNL; Yang, Xiaocheng [West Virginia University; Giles, Nancy C. [Air Force Institute of Technology; Neal, John S [ORNL; Munir, Zuhair [University of California

    2011-01-01

    Translucent, green-emitting zinc oxide (ZnO) bodies, 19 mm in diameter and 0.72 mm in thickness, have been prepared via spark plasma sintering method. The consolidation of ZnO powders was investigated over the temperature range of 550-1050 C and the pressure range of 55-530 MPa. Samples sintered at temperatures >850 C and pressures of {approx}120 MPa were translucent and had densities of {approx}100%. Samples sintered at 950 C and 130 MPa showed a higher maximum transmittance than the samples sintered at higher or lower temperatures or pressures, with an excellent in-line transmission of 70% in the IR region around 2330 nm. The dense ZnO ceramics exhibited a strong green emission and a weak ultraviolet emission, and the relative intensity of the green emission increased with increasing sintering temperature.

  10. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, J.L.; Kucera, E.H.

    1991-04-16

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell. 4 figures.

  11. Improved method for preparing rare earth sesquichalcogenides

    DOE Patents [OSTI]

    Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

    1982-04-14

    An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

  12. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1991-01-01

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell.

  13. Process for preparing silicon carbide foam

    SciTech Connect (OSTI)

    Whinnery, L.L.; Nichols, M.C.; Wheeler, D.R.; Loy, D.A.

    1997-09-16

    A method of preparing near net shape, monolithic, porous SiC foams is disclosed. Organosilicon precursors are used to produce polymeric gels by thermally induced phase separation, wherein, a sufficiently concentrated solution of an organosilicon polymer is cooled below its solidification temperature to form a gel. Following solvent removal from the gel, the polymer foam is pretreated in an oxygen plasma in order to raise its glass transition temperature. The pretreated foam is then pyrolyzed in an inert atmosphere to form a SiC foam. 9 figs.

  14. Process for preparing silicon carbide foam

    SciTech Connect (OSTI)

    Whinnery, LeRoy Louis (Livermore, CA); Nichols, Monte Carl (Livermore, CA); Wheeler, David Roger (Albuquerque, NM); Loy, Douglas Anson (Albuquerque, NM)

    1997-01-01

    A method of preparing near net shape, monolithic, porous SiC foams is disclosed. Organosilicon precursors are used to produce polymeric gels by thermally induced phase separation, wherein, a sufficiently concentrated solution of an organosilicon polymer is cooled below its solidification temperature to form a gel. Following solvent removal from the gel, the polymer foam is pretreated in an oxygen plasma in order to raise its glass transition temperature. The pretreated foam is then pyrolized in an inert atmosphere to form a SiC foam.

  15. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

  16. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint. 9 figs.

  17. Absolute hydrogen determination in coal-derived heavy distillate samples

    SciTech Connect (OSTI)

    Kottenstette, R.J.; Schneider, D.A.; Loy, D.A.

    1994-06-01

    Organic elemental hydrogen analysis is routinely performed with an automated analyzer having a high temperature combustion zone that is connected to a detector which measures the response of the product water. With the advent of instrumental electronics, automated microanalysis gradually replaced the gravimetric techniques mainly because of increased analysis speed. Modern automated organic elemental analysis consists of combusting the sample in the presence of a solid oxidant and sweeping the products into a thermal conductivity of infrared detector [4,5]. An alternative technique for the detection of hydrogen is to react the product water with carbonyldiimidazole to generate a quantitative amount of carbon dioxide which is measured by a coulometric tritration [6]. The development of Proton Nuclear Magnetic Nuclear Resonance Spectroscopy has led to the description and qualitative classification of hydrogen in organic compounds. These techniques have been especially helpful in describing hydrogen as it is classified into aliphatic, aromatic and hydroaromatic groupings [1,2,3]. In addition, low resolution proton {sup 1}H-NMR has been sucessfully used to determine absolute amounts of hydrogen in a variety of petroleum fractions [7,8]. Our technique involves simple integration of high resolution {sup 1}H-NMR spectra with careful attention given to sample preparation and spectral integration.

  18. Reconstruction of Intensity From Covered Samples

    SciTech Connect (OSTI)

    Barabash, Rozaliya; Watkins, Thomas R; Meisner, Roberta Ann; Burchell, Timothy D; Rosseel, Thomas M

    2015-01-01

    The safe handling of activated samples requires containment and covering the sample to eliminate any potential for contamination. Subsequent characterization of the surface with x-rays ideally necessitates a thin film. While many films appear visually transparent, they are not necessarily x-ray transparent. Each film material has a unique beam attenuation and sometimes have amorphous peaks that can superimpose with those of the sample. To reconstruct the intensity of the underlying activated sample, the x-ray attenuation and signal due to the film needs to be removed from that of the sample. This requires the calculation of unique deconvolution parameters for the film. The development of a reconstruction procedure for a contained/covered sample is described.

  19. 100 Area Columbia River sediment sampling

    SciTech Connect (OSTI)

    Weiss, S.G. [Westinghouse Hanford Co., Richland, WA (United States)

    1993-09-08

    Forty-four sediment samples were collected from 28 locations in the Hanford Reach of the Columbia River to assess the presence of metals and man-made radionuclides in the near shore and shoreline settings of the Hanford Site. Three locations were sampled upriver of the Hanford Site plutonium production reactors. Twenty-two locations were sampled near the reactors. Three locations were sampled downstream of the reactors near the Hanford Townsite. Sediment was collected from depths of 0 to 6 in. and between 12 to 24 in. below the surface. Samples containing concentrations of metals exceeding the 95 % upper threshold limit values (DOE-RL 1993b) are considered contaminated. Contamination by arsenic, chromium, copper, lead, and zinc was found. Man-made radionuclides occur in all samples except four collected opposite the Hanford Townsite. Man-made radionuclide concentrations were generally less than 1 pCi/g.

  20. Proper Oil Sampling Intervals and Sample Collection Techniques Gasoline/Diesel/Natural Gas Engines

    E-Print Network [OSTI]

    Proper Oil Sampling Intervals and Sample Collection Techniques Gasoline/Diesel/Natural Gas Engines: · Oil samples can be collected during oil changes. Follow manufacturers recommendations on frequency (hours, mileage, etc) of oil changes. · Capture a sample from the draining oil while the oil is still hot

  1. Argonne Premium Coal Sample Bank The Argonne Premium Coal (APC) Sample Bank can supply

    E-Print Network [OSTI]

    Maranas, Costas

    Argonne Premium Coal Sample Bank Background Overview T The Argonne Premium Coal (APC) Sample Bank can supply researchers with highly uniform, well-protected coal samples unexposed to oxygen. Researchers investigating coal structure, properties, and behavior can benefit greatly from these samples

  2. Hanford Sampling Quality Management Plan (HSQMP)

    SciTech Connect (OSTI)

    Hyatt, J.E.

    1995-06-01

    HSQMP establishes quality requirements in response to DOE Order 5700. 6C and to 10 Code of Federal Regulations 830.120. HSQMP is designed to meet the needs of Richland Operations Office for controlling the quality of services provided by sampling operations. It is issued through the Analytical Services Program of the Waste Programs Division. This document describes the Environmental Sampling and Analysis Program activities considered to represent the best management activities necessary to achieve a sampling program with adequate control.

  3. Sample Withdrawal Letter Ready Reference F-11

    E-Print Network [OSTI]

    Sample Withdrawal Letter Ready Reference F-11 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  4. Sample Application Letter Ready Reference F-5

    E-Print Network [OSTI]

    Sample Application Letter Ready Reference F-5 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  5. Sample Networking Letter Ready Reference F-6

    E-Print Network [OSTI]

    Sample Networking Letter Ready Reference F-6 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  6. Sample Acceptance Letter Ready Reference F-10

    E-Print Network [OSTI]

    Sample Acceptance Letter Ready Reference F-10 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  7. Hanford analytical sample projections 1996--2001

    SciTech Connect (OSTI)

    Joyce, S.M.

    1996-06-26

    This document summarizes the biannual Hanford sample projections for fiscal years 1996 to 2001. Sample projections are based on inputs submitted to Analytical Services covering Environmental Restoration, Tank Waste Remediation Systems (TWRS), Solid Waste, Liquid Effluents, Spent Nuclear Fuels, Transition Projects, Analytical Services, Site Monitoring, and Industrial Hygiene. This information will be used by Hanford Analytical Services to assure that laboratories and resources are available and effectively utilized to meet these documented needs. Sample projections are categorized by radiation level, protocol, sample matrix and Program. Analyses requirements are also presented.

  8. Colloid characterization and quantification in groundwater samples

    SciTech Connect (OSTI)

    K. Stephen Kung

    2000-06-01

    This report describes the work conducted at Los Alamos National Laboratory for studying the groundwater colloids for the Yucca Mountain Project in conjunction with the Hydrologic Resources Management Program (HRMP) and the Underground Test Area (UGTA) Project. Colloidal particle size distributions and total particle concentration in groundwater samples are quantified and characterized. Colloid materials from cavity waters collected near underground nuclear explosion sites by HRMP field sampling personnel at the Nevada Test Site (NTS) were quantified. Selected colloid samples were further characterized by electron microscope to evaluate the colloid shapes, elemental compositions, and mineral phases. The authors have evaluated the colloid size and concentration in the natural groundwater sample that was collected from the ER-20-5 well and stored in a 50-gallon (about 200-liter) barrel for several months. This groundwater sample was studied because HRMP personnel have identified trace levels of radionuclides in the water sample. Colloid results show that even though the water sample had filtered through a series of Millipore filters, high-colloid concentrations were identified in all unfiltered and filtered samples. They had studied the samples that were diluted with distilled water and found that diluted samples contained more colloids than the undiluted ones. These results imply that colloids are probably not stable during the storage conditions. Furthermore, results demonstrate that undesired colloids have been introduced into the samples during the storage, filtration, and dilution processes. They have evaluated possible sources of colloid contamination associated with sample collection, filtrating, storage, and analyses of natural groundwaters. The effects of container types and sample storage time on colloid size distribution and total concentration were studied to evaluate colloid stability by using J13 groundwater. The data suggests that groundwater samples should be analyzed for colloid size and concentration shortly after they have been collected. A prolonged waiting period after sampling will affect the colloid size distribution as well as colloid concentration resulting from the changes of water chemical properties. The data also shows that sample containers, filter materials, and labware that are used for colloid analyses should be cleaned by specially treated low-colloid-containing water. Water used for sample dilution should be verified for total colloidal particle concentration. They then analyzed freshly collected groundwater from NTS wells ER-20-5{number_sign}1 and {number_sign}3. Results show that these groundwater samples have similar colloid concentrations and particle size distributions. For the particle size range between 50- and 200-nm, about ten trillion (1E10) colloidal particles per liter are present in these water samples. Most of these colloidal particles are less than 100 mm in size. For example, more than 98% of the colloids are smaller than 100 nm in size in the ER-20-5 {number_sign}1 sample. Furthermore, it was found that the smaller the sizes of colloid, the higher the colloid concentration present in the water. For another site at NTS, Cheshire, they had analyzed two zones of groundwater samples. For water samples collected from the lower water zone (near the underground detonation cavity about 3,700 feet of slanted depth from the surface), the colloid concentration was about 5E12 particles per liter. About 20 times less than the lower zone of total colloids was found in water samples collected from the upper aquifer (around 2,511 feet of slanted depth), although colloid size distributions from these two zones appear to be rather similar.

  9. Guide to preparing SAND reports and other communication products.

    SciTech Connect (OSTI)

    Not Available

    2011-09-01

    This guide describes the R&A process, Common Look and Feel requirements, and preparation and publishing procedures for communication products at Sandia National Laboratories. Samples of forms and examples of published communications products are provided. This guide takes advantage of the wealth of material now available on the Web as a resource. Therefore, it is best viewed as an electronic document. If some of the illustrations are too small to view comfortably, you can enlarge them on the screen as needed. The format of this document is considerably different than that usually expected of a SAND Report. It was selected to permit the large number of illustrations and examples to be placed closer to the text that references them. In the case of forms, covers, and other items that are included as examples, a link to the Web is provided so that you can access the items and download them for use. This guide details the processes for producing a variety of communication products at Sandia National Laboratories. Figure I-1 shows the general publication development process. Because extensive supplemental material is available from Sandia on the internal web or from external sources (Table I-1), the guide has been shortened to make it easy to find information that you need.

  10. Preparation and properties of polyvinyl alcohol microspheres

    SciTech Connect (OSTI)

    Campbell, J.H.; Grens, J.Z.; Poco, J.F.; Ives, B.H.

    1986-06-01

    Polyvinyl alcohol (PVA) microspheres, having a size range of approx.150- to 250-..mu..m diameter with 1- to 5-..mu..m wall thickness, have been fabricated using a solution droplet technique. The spheres were developed for possible use on the Lawrence Livermore National Laboratory (LLNL) Inertial Confinement Fusion (ICF) Program. PVA, a polymer chosen based on earlier survey work carried out at KMS Fusion, Inc., has good strength, low hydrogen permeability, is optically transparent, and water soluble. The latter property makes it safe and easy to use in our droplet generator system. A unique dual-orifice droplet generator was used to prepare the spheres. The droplet generator operating conditions and the column processing parameters were chosen using results from our 1-D model calculations as a guide. The polymer microsphere model is an extension of the model we developed to support the glass sphere production. After preparation, the spheres were physically characterized for surface quality, sphericity, wall thickness (and uniformity), and size. We also determined the buckling pressure for both uncoated and CH-coated spheres. Radiation stability to beta decay (from tritium) was evaluated by exposing the spheres to a 7-keV electron beam. The results from these and other physical property measurements are presented in this report.

  11. New hydroprocessing catalysts prepared from molecular complexes

    SciTech Connect (OSTI)

    Ho, T.C.

    1994-12-31

    Current commercial hydroprocessing catalysts are transition metal sulfides (TMS) based on Group 8 and 11 metals. They are prepared by dispersing MoO{sub 3} and a promoter metal oxide, either CoO or NiO, on {gamma}-Al{sub 2}O{sub 3} or SiO{sub 2}-modified Al{sub 2}O{sub 3}. This is followed by sulfiding with a sulfur-bearing stream such as H{sub 2}S at high temperatures. The thus formed MoS{sub 2} crystallites are the backbone of the working catalysts. A potentially fruitful approach to new catalysts would be to molecularly incorporate promoter metals into the structure of MoS{sub 2} edge planes. As a first step, it would seem reasonable to exploit the use of heterometallic metal sulfur complexes as hydroprocessing catalyst precursors. The authors have developed several families of new catalysts along this line. In this paper the authors restrict themselves to the metal amine thiomolybdate-derived catalysts. Specifically, they give an overview of the performance of the bulk (unsupported) FeMo sulfide prepared from MAT. This low-surface-area catalyst shows a high HDN-to-HDS volumetric activity ratio and is also active for HDA. While most of the results are taken from their previous publications, some new results are reported here.

  12. Experience in preparing fuel for combustion

    SciTech Connect (OSTI)

    Rude, J.

    1995-09-01

    The key phase seems to be that wood is the ORIGINAL FUEL. Certainly as man discovered fire, it was the most obvious as well as abundantly available fuel and it burned very well because man was smart enough to select the dry wood once he understood the basics of combustion. As the needs started to go beyond the most elementary, designs for burning ideal fuels were pretty well perfected, however, the burning of less ideal fuels still remain a challenge. To provide plant steam requirements by burning waste that must be disposed of anyway can reduce operating cost considerably. For most of us involved in producing steam, the experience we have with fuels such as bark, wood waste, sludge, and miscellaneous forms of solid combustible waste material, are a result of burning these fuels in an existing boiler supposedly designed for wood waste or possibly a combination of wood and other fuels such as coal, oil, or gas. For a supplier of fuel preparation systems, the typical application involves the sizing, cleaning, and drying of wood waste, and sludge from a pulp and/or paper mill. Other forms of combustible waste are dealt with occasionally and after proper preparation fired in the combustion system for the purpose of generating hot gas and/or steam for the plant process.

  13. Novel hard compositions and methods of preparation

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1983-08-23

    Novel very hard compositions of matter are prepared by using in all embodiments only a minor amount of a particular carbide (or materials which can form the carbide in situ when subjected to heat and pressure); and no strategic cobalt is needed. Under a particular range of conditions, densified compositions of matter of the invention are prepared having hardnesses on the Rockwell A test substantially equal to the hardness of pure tungsten carbide and to two of the hardest commercial cobalt-bonded tungsten carbides. Alternately, other compositions of the invention which have slightly lower hardnesses than those described above in one embodiment also possess the advantage of requiring no tungsten and in another embodiment possess the advantage of having a good fracture toughness value. Photomicrographs show that the shapes of the grains of the alloy mixture with which the minor amount of carbide (or carbide-formers) is mixed are radically altered from large, rounded to small, very angular by the addition of the carbide. Superiority of one of these hard compositions of matter over cobalt-bonded tungsten carbide for ultra-high pressure anvil applications was demonstrated.

  14. Ambient pressure process for preparing aerogel thin films reliquified sols useful in preparing aerogel thin films

    DOE Patents [OSTI]

    Brinker, Charles Jeffrey (Albuquerque, NM); Prakash, Sai Sivasankaran (Minneapolis, MN)

    1999-01-01

    A method for preparing aerogel thin films by an ambient-pressure, continuous process. The method of this invention obviates the use of an autoclave and is amenable to the formation of thin films by operations such as dip coating. The method is less energy intensive and less dangerous than conventional supercritical aerogel processing techniques.

  15. Preparation of certain m-aminophenols and the use thereof for preparation of laser dyes

    DOE Patents [OSTI]

    Hammond, P.R.

    1983-12-29

    Methods are provided for making certain m-aminophenols using a sulfonation/alkali fusion procedure. The aminophenols are key intermediates in the synthesis of dyes, particularly efficient, stable dyes for laser application. Preparations of some rhodamine and phenoxazone dyes from the m-aminophenols are described.

  16. Evaporator Feed Qualification Analysis Of Tank 38H And 43H Samples: January 2010 Through April 2013

    SciTech Connect (OSTI)

    Martino, C. J.; Coleman, C. J.

    2013-08-21

    This report provides the results of analyses that focused on the chemical species that pertain to the sodium aluminosilicate formation potential for archived Tank 38H and 43H subsurface samples from January 2010 through April 2013. Analyses included warm acid strike preparation followed by analysis of silicon, aluminum, and sodium and water dilution preparation followed by analysis for anions. The Tank 43H and 38H supernatant liquid silicon measurements for the January 2010 through April 2013 time period exhibit a slight increasing trend. Over this time period, the silicon concentration in the Tank 43H and Tank 38H samples averaged 179 mg/L and 235 mg/L, respectively. Comparison of Tank 43H sample results from 2005 through April 2013 to the previously developed process control models indicates that the current formation of sodium aluminosilicate in the 2H system is due to the seeded direct precipitation of cancrinite and sodalite.

  17. Stochastic Sampling for Internet Traffic Measurement

    E-Print Network [OSTI]

    Rejaie, Reza

    is to sample or aggregate information. For example, to estimate link utilization, the size of all packets Gong Department of Electrical and Computer Engineering University of Massachusetts, Amherst, MA, USA data from different sources with independent clocks and sampling rates. We present results that show

  18. EML Surface Air Sampling Program, 1989 data

    SciTech Connect (OSTI)

    Larsen, R.J.; Sanderson, C.G.

    1991-08-01

    Measurements of the concentrations of specific atmospheric radionuclides in air filter samples collected for the Environmental Measurements Laboratory`s Surface Air Sampling Program (SASP) during 1989 indicate that anthropogenic radionuclides, in both hemispheres, were at or below the lower limits of detection for the analytical and sampling techniques that were used to measure them. During 1989, the occasional detection of {sup 137}Cs in some air filter samples may have resulted from resuspension of previously deposited debris. The naturally occurring radioisotopes that we measure, {sup 7}Be and {sup 210}Pb, continue to be detected in most air filter samples. The 1989 annual mean concentrations of {sup 7}Be at many of the sites were lower than those previously reported during the last decade. Possible changes in the atmospheric production of {sup 7}Be, variations in atmospheric circulation and precipitation patterns, as well as modifications to our sampling procedure many all have contributed to this observed trend. Short-term variations in the concentrations of {sup 7}Be and {sup 210}Pb continued to be observed at many sites at which weekly air filter samples were analyzed. These short-term fluctuations probably resulted from variations in meteorological factors. The data from our quality control samples indicate that the reliability of the air filter measurements are acceptable for their intended application.

  19. EML Surface Air Sampling Program, 1989 data

    SciTech Connect (OSTI)

    Larsen, R.J.; Sanderson, C.G.

    1991-08-01

    Measurements of the concentrations of specific atmospheric radionuclides in air filter samples collected for the Environmental Measurements Laboratory's Surface Air Sampling Program (SASP) during 1989 indicate that anthropogenic radionuclides, in both hemispheres, were at or below the lower limits of detection for the analytical and sampling techniques that were used to measure them. During 1989, the occasional detection of {sup 137}Cs in some air filter samples may have resulted from resuspension of previously deposited debris. The naturally occurring radioisotopes that we measure, {sup 7}Be and {sup 210}Pb, continue to be detected in most air filter samples. The 1989 annual mean concentrations of {sup 7}Be at many of the sites were lower than those previously reported during the last decade. Possible changes in the atmospheric production of {sup 7}Be, variations in atmospheric circulation and precipitation patterns, as well as modifications to our sampling procedure many all have contributed to this observed trend. Short-term variations in the concentrations of {sup 7}Be and {sup 210}Pb continued to be observed at many sites at which weekly air filter samples were analyzed. These short-term fluctuations probably resulted from variations in meteorological factors. The data from our quality control samples indicate that the reliability of the air filter measurements are acceptable for their intended application.

  20. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, J.E.; Dinsmore, S.R.; Chandler, E.W.

    1984-08-16

    This is a patent for a disc-type, four-port sampling valve for service with erosive high temperature process streams. Inserts and liners of ..cap alpha..-silicon carbide respectively, in the faceplates and in the sampling cavities, limit erosion while providing lubricity for a smooth and precise operation. 1 fig.

  1. Accurate Direct Illumination Using Iterative Adaptive Sampling

    E-Print Network [OSTI]

    Bala, Kavita

    Accurate Direct Illumination Using Iterative Adaptive Sampling Michael Donikian, Bruce Walter with many lights and complex occlusion. Images are first divided into 8 Â 8 pixel blocks and for each point to be shaded within a block, a probability density function (PDF) is constructed over the lights and sampled

  2. Sampling Techniques for Probabilistic Roadmap Planners

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Sampling Techniques for Probabilistic Roadmap Planners Roland Geraerts Mark H. Overmars institute;Sampling Techniques for Probabilistic Roadmap Planners Roland Geraerts Mark H. Overmars Institute,markov}@cs.uu.nl. Abstract The probabilistic roadmap approach is a commonly used motion planning technique. A crucial

  3. Sampling Techniques for Probabilistic Roadmap Planners

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Sampling Techniques for Probabilistic Roadmap Planners Roland Geraerts Mark H. Overmars institute; Sampling Techniques for Probabilistic Roadmap Planners Roland Geraerts Mark H. Overmars Institute,markov}@cs.uu.nl. Abstract The probabilistic roadmap approach is a commonly used motion planning technique. A crucial

  4. SAMPLE PROGRAM (First Math Course MATH 198)

    E-Print Network [OSTI]

    Gering, Jon C.

    MATH SAMPLE PROGRAM (First Math Course MATH 198) This sample program suggests one way to navigate equivalent patterns are possible. Fall ­ Semester 1 Spring ­ Semester 2 MATH 198: Analytic Geometry with Calculus I MATH 263: Analytic Geometry with Calculus II MATH 101: Freshman Seminar CS 170: Intro

  5. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, S.A.; Glish, G.L.

    1989-07-18

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

  6. Empirical comparison of network sampling techniques

    E-Print Network [OSTI]

    Blagus, Neli; Bahec, Marko

    2015-01-01

    In the past few years, the storage and analysis of large-scale and fast evolving networks present a great challenge. Therefore, a number of different techniques have been proposed for sampling large networks. In general, network exploration techniques approximate the original networks more accurately than random node and link selection. Yet, link selection with additional subgraph induction step outperforms most other techniques. In this paper, we apply subgraph induction also to random walk and forest-fire sampling. We analyze different real-world networks and the changes of their properties introduced by sampling. We compare several sampling techniques based on the match between the original networks and their sampled variants. The results reveal that the techniques with subgraph induction underestimate the degree and clustering distribution, while overestimate average degree and density of the original networks. Techniques without subgraph induction step exhibit exactly the opposite behavior. Hence, the pe...

  7. CHARACTERIZATION OF TANK 19F SAMPLES

    SciTech Connect (OSTI)

    Oji, L.; Diprete, D.; Click, D.

    2009-12-17

    The Savannah River National Laboratory (SRNL) was asked by Liquid Waste Operations to characterize Tank 19F closure samples. Tank 19F slurry samples analyzed included the liquid and solid fractions derived from the slurry materials along with the floor scrape bottom Tank 19F wet solids. These samples were taken from Tank 19F in April 2009 and made available to SRNL in the same month. Because of limited amounts of solids observed in Tank 19F samples, the samples from the north quadrants of the tank were combined into one Tank 19F North Hemisphere sample and similarly the south quadrant samples were combined into one Tank 19F South Hemisphere sample. These samples were delivered to the SRNL shielded cell. The Tank 19F samples were analyzed for radiological, chemical and elemental components. Where analytical methods yielded additional contaminants other than those requested by the customer, these results were also reported. The target detection limits for isotopes analyzed were based on detection values of 1E-04 {micro}Ci/g for most radionuclides and customer desired detection values of 1E-05 {micro}Ci/g for I-129, Pa-231, Np-237, and Ra-226. While many of the target detection limits, as specified in the technical task request and task technical and quality assurance plans were met for the species characterized for Tank 19F, some were not met. In a number of cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

  8. CHARACTERIZATION OF THE TANK 18F SAMPLES

    SciTech Connect (OSTI)

    Oji, L.; Click, D.; Diprete, D.

    2009-12-17

    The Savannah River National Laboratory (SRNL) was asked by Liquid Waste Operations to characterize Tank 18F closure samples. Tank 18F slurry samples analyzed included the liquid and solid fractions derived from the 'as-received' slurry materials along with the floor scrape bottom Tank 18F wet solids. These samples were taken from Tank 18F in March 2009 and made available to SRNL in the same month. Because of limited amounts of solids observed in Tank 18F samples, the samples from the north quadrants of the tank were combined into one North Tank 18F Hemisphere sample and similarly the south quadrant samples were combined into one South Tank 18F Hemisphere sample. These samples were delivered to the SRNL shielded cell. The Tank 18F samples were analyzed for radiological, chemical and elemental components. Where analytical methods yielded additional contaminants other than those requested by the customer, these results were also reported. The target detection limits for isotopes analyzed were 1E-04 {micro}Ci/g for most radionuclides and customer desired detection values of 1E-05 {micro}Ci/g for I-129, Pa-231, Np-237, and Ra-226. While many of the minimum detection limits, as specified in the technical task request and task technical and quality assurance plans were met for the species characterized for Tank 18F, some were not met due to spectral interferences. In a number of cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

  9. Preparation of stable crude oil transport emulsions

    SciTech Connect (OSTI)

    Gregoli, A.A.; Hamshar, J.A.; Olah, A.M.; Riley, C.J.; Rimmer, D.P.

    1988-02-16

    A process for preparing an oil-in-water emulsion for pipeline transmission is described comprising: (a) shearing and mixing statically, without any dynamic shearing and mixing preceding or following the shearing and mixing statically, a hydrocarbon with an emulsifying composition comprising water and a minor amount of an emulsifying agent at a temperature of from about 100/sup 0/F. to about 200/sup 0/F. to form an oil-in-water emulsion having a viscosity sufficiently low for pipeline transmission, wherein the amount of water in the oil-in-water emulsion is from about 15% to about 60% by weight, and wherein the emulsifying agent is used in an amount sufficient to assist in the formation of the oil-in-water emulsion that is sufficiently stable for pipeline transmission; and wherein the emulsifying agent comprises about 50 percent by weight of an ethoxylated nonyl phenol compound.

  10. Remotely prepared entanglement: a quantum web page

    E-Print Network [OSTI]

    Todd A. Brun

    2001-07-05

    In quantum teleportation, an unknown quantum state is transmitted from one party to another using only local operations and classical communication, at the cost of shared entanglement. Is it possible similarly, using an $N$ party entangled state, to have the state retrievable by {\\it any} of the $N-1$ possible receivers? If the receivers cooperate, and share a suitable state, this can be done reliably. The $N$ party GHZ is one such state; I derive a large class of such states, and show that they are in general not equivalent to the GHZ. I also briefly discuss the problem where the parties do not cooperate, and the relationship to multipartite entanglement quantification. I define a new set of entanglement monotones, the entanglements of preparation.

  11. Method of preparing composite superconducting wire

    DOE Patents [OSTI]

    Verhoeven, John D. (Ames, IA); Gibson, Edwin D. (Ames, IA); Finnemore, Douglas K. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Schmidt, Frederick A. (Ames, IA); Owen, Charles V. (Ames, IA)

    1985-08-06

    An improved method of preparing composite multifilament superconducting wire of Nb.sub.3 Sn in a copper matrix which eliminates the necessity of coating the drawn wire with tin. A generalized cylindrical billet of an alloy of copper containing at least 15 weight percent niobium, present in the copper as discrete, randomly distributed and oriented dendritic-shaped particles, is provided with at least one longitudinal opening which is filled with tin to form a composite drawing rod. The drawing rod is then drawn to form a ductile composite multifilament wire containing a filament of tin. The ductile wire containing the tin can then be wound into magnet coils or other devices before heating to diffuse the tin through the wire to react with the niobium forming Nb.sub.3 Sn. Also described is an improved method for making large billets of the copper-niobium alloy by consumable-arc casting.

  12. Preparation of thin film high temperature superconductors

    SciTech Connect (OSTI)

    VenKatesan, X.X.T.; Li, Q.; Findikoglu, A.; Hemmick, D. . Dept. of Physics); Wu, X.D. ); Inam, A.; Chang, C.C.; Ramesh, R.; Hwang, D.M.; Ravi, T.S.; Etemad, S.; Martinez, J.A.; Wilkens, B. )

    1991-03-01

    This paper addresses fundamental issues in preparing high quality high T{sub c} YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} thin films. The techniques of inverted cylindrical magnetron sputtering and pulsed laser deposition are chosen as successful examples to illustrate how the key problems can be solved. The fabrication of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x}/PrBa{sub 2}Cu{sub 3}O{sub 7{minus}x} superlattices where superconductivity in a single unit cell layer of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} was observed demonstrates the state of the art of thin film deposition of high T{sub c} materials. Systematic variations of the deposition parameters result in changes of superconducting and structural properties of the films that correlate with their microwave and infrared characteristics.

  13. Process for preparing aqueous paint composition

    SciTech Connect (OSTI)

    Scholten, H.P.H.; Dijkstra, T.J.; Van Iperen, R.

    1990-06-12

    This patent describes a process for preparing an aqueous paint composition. It comprises: mixing a pigment power having a particle size less than about 20 micrometers, a crosslinking agent and an epoxy resin to form a liquid, solvent-free paste, reacting the liquid, solvent-free paste with an amount of an amine selected from the group consisting of secondary amines and mixtures of secondary amines and primary amines sufficient to provide at least one N {bond}H function per epoxy group of the epoxy resin to form a suspension of particles coated with an epoxy-amine adduct and the crosslinking agent; neutralizing the suspension of particles; and adjusting the concentration of the resulting dispersion to provide a solids content in the range of from about 25 to 75 solid by addition of water.

  14. Recovery of coal from preparation plant effluents using a packed column

    SciTech Connect (OSTI)

    Choudhry, V.; Khan, L.; Yang, D.; Banerjee, D.D.

    1993-12-31

    The feasibility of recovering coal from coal preparation plant waste (or effluent) streams at the pilot scale using the packed column flotation process is demonstrated. In Phase I of the project, a total of four effluent samples were tested at the bench scale with the objective of recovering low-ash, low-sulfur clean coal products that were, at a minimum, compatible with the quality of the clean coal produced by the preparation plants supplying the waste stream samples. Phase II of the project comprised demonstration of the technology at the pilot scale using a 4-in. I.D. {times} 20-ft tall column installed at the Applied Laboratory of the Illinois State Geological Survey. A large effluent sample was conducted, consisting of particle size distribution, proximate and complete analyses, and batch froth flotation testing. Ash, total and pyritic sulfur, and calorific value of the effluent sample were also determined. The effluent feed sample contained 50-55% ash and 2.2% total sulfur. Confirmatory tests were conducted at Michigan Technological University using a bench-scale packed column. A product containing 5.4% ash was obtained at 97.5% ash rejection and 71.8% combustible matter recovery. Changing the process operating parameters allowed the quality of the product to be controlled such that its ash content ranged between 6 and 10%, with combustible matter recoveries in the 71-77% range. Pilot testing was conducted using a test matrix designed to study the effects of primary variables (feed rate, percent solids, and reagent dosage) and operating variables (air rate, wash water, and pulp level) with the objective of optimizing the process performance. Feed rates of 20-108 lb/hour were tested, with very good performance being obtained at a feed rate of 32 lb/hour (374 lb/h/ft{sup 2}).

  15. ANALYSIS OF SAMPLES FROM TANK 6F CHEMICAL CLEANING

    SciTech Connect (OSTI)

    Poirier, M.; Fink, S.

    2010-02-02

    Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. In mechanical sludge removal, personnel add liquid (e.g., inhibited water or supernate salt solution) to the tank to form a slurry. They mix the liquid and sludge with pumps, and transfer the slurry to another tank for further processing. Mechanical sludge removal effectively removes the bulk of the sludge from a tank, but is not able to remove all of the sludge. In Tank 6F, SRR estimated a sludge heel of 5,984 gallons remained after mechanical sludge removal. To remove this sludge heel, SRR performed chemical cleaning. The chemical cleaning included two oxalic acid strikes, a spray wash, and a water wash. SRR conducted the first oxalic acid strike as follows. Personnel added 110,830 gallons of 8 wt % oxalic acid to Tank 6F and mixed the contents of Tank 6F with two submersible mixer pumps (SMPs) for approximately four days. Following the mixing, they transferred 115,903 gallons of Tank 6F material to Tank 7F. The SMPs were operating when the transfer started and were shut down approximately five hours after the transfer started. SRR collected a sample of the liquid from Tank 6F and submitted it to SRNL for analysis. Mapping of the tank following the transfer indicated that 2,400 gallons of solids remained in the tank. SRR conducted the second oxalic acid strike as follows. Personnel added 28,881 gallons of 8 wt % oxalic acid to Tank 6F. Following the acid addition, they visually inspected the tank and transferred 32,247 gallons of Tank 6F material to Tank 7F. SRR collected a sample of the liquid from Tank 6F and submitted it to SRNL for analysis. Mapping of the tank following the transfer indicated that 3,248 gallons of solids remained in the tank. Following the oxalic acid strikes, SRR performed Spray Washing with oxalic acid to remove waste collected on internal structures, cooling coils, tank top internals, and tank walls. The Acid Spray Wash was followed by a Water Spray Wash to remove oxalic acid from the tank internals. SRR conducted the Spray Wash as follows. Personnel added 4,802 gallons of 8 wt % oxalic acid to Tank 6F through the spray mast installed in Riser 2, added 4,875 gallons of oxalic acid through Riser 7, added 5,000 gallons of deionized water into the tank via Riser 2, and 5,000 gallons of deionized water into the tank via Riser 7. Following the Spray Wash, they visually inspected the tank and transferred 22,430 gallons of Tank 6F material to Tank 7F. SRR collected a sample of the liquid from Tank 6F and submitted it to SRNL for analysis. Following the Spray Wash and transfer, Savannah River Site (SRS) added 113,935 gallons of well water to Tank 6F. They mixed the tank contents with a single SMP and transferred 112,699 gallons from Tank 6F to Tank 7F. SRR collected a sample of the liquid from Tank 6F and submitted to SRNL for analysis. Mapping of the tank following the transfer indicated that 3,488 gallons of solids remained in the tank. Following the Water Wash, SRR personnel collected a solid sample and submitted it to SRNL for analysis to assess the effectiveness of the chemical cleaning and to provide a preliminary indication of the composition of the material remaining in the tank.

  16. Instructions for Apple Leaf Sample Collection.doc September 2013 Instructions for Apple Leaf Sample Collection Vermont

    E-Print Network [OSTI]

    Hayden, Nancy J.

    Instructions for Apple Leaf Sample Collection.doc September 2013 Instructions for Apple Leaf Sample;Instructions for Apple Leaf Sample Collection.doc September 2013 Washing Leaf Samples 1. Wash the leaf samples

  17. Results of Hg speciation testing on tanks 30, 32, and 37 depth samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-30

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The twelfth shipment of samples was designated to include 3H evaporator system Tank 30, 32, and 37 depth samples. The Tank 30 depth sample (HTF-30-15-70) was taken at 190 inches from the tank bottom and the Tank 32 depth sample (HTF-32-15-68) was taken at 89 inches from the tank bottom and both were shipped to SRNL on June 29, 2015 in an 80 mL stainless steel dip bottles. The Tank 37 surface sample (HTF-37-15-94) was taken around 253.4 inches from the tank bottom and shipped to SRNL on July 21, 2015 in an 80 mL stainless steel dip bottle. All samples were placed in the SRNL Shielded Cells and left unopened until intermediate dilutions were made on July 24, 2015 using 1.00 mL of sample diluted to 100.00 mL with deionized H2O. A 30 mL Teflon® bottle was rinsed twice with the diluted tank sample and then filled leaving as little headspace as possible. It was immediately removed from the Shielded Cells and transferred to refrigerated storage where it remained at 4 °C until final dilutions were made on October 20. A second portion of the cells diluted tank sample was poured into a shielded polyethylene bottle and transferred to Analytical Development for radiochemical analysis data needed for Hazardous Material Transportation calculations.

  18. Expediting Groundwater Sampling at Hanford and Making It Safer - 13158

    SciTech Connect (OSTI)

    Connell, Carl W. Jr.; Conley, S.F.; Carr, Jennifer S.; Schatz, Aaron L. [CH2M HILL Plateau Remediation Company, P.O. Box 1600, Richland, WA 99352 (United States)] [CH2M HILL Plateau Remediation Company, P.O. Box 1600, Richland, WA 99352 (United States); Brown, W.L. [Lockheed Martin Systems Information, P.O. Box 950, Richland, WA 99352 (United States)] [Lockheed Martin Systems Information, P.O. Box 950, Richland, WA 99352 (United States); Hildebrand, R. Douglas [Department of Energy - Richland Operations Office, 825 Jadwin Ave., Richland, WA 99352 (United States)] [Department of Energy - Richland Operations Office, 825 Jadwin Ave., Richland, WA 99352 (United States)

    2013-07-01

    The CH2M HILL Plateau Remediation Company (CHPRC) manages the groundwater monitoring programs at the Department of Energy's 586-square-mile Hanford site in southeastern Washington state. These programs are regulated by the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), and the Atomic Energy Act (AEA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. Each year, more than 1,500 wells are accessed for a variety of reasons. Historically, the monitoring activities have been very 'people intensive'. Field personnel or 'samplers' have been issued pre-printed forms showing information about the well(s) for a particular sampling evolution. This information is taken from two official electronic databases: the Hanford Well Information System (HWIS) and the Hanford Environmental Information System (HEIS). The samplers traditionally used these hardcopy forms to document the groundwater samples and well water-levels. After recording the entries in the field, the samplers turned the forms in at the end of the day and other personnel posted the collected information. In Automating Groundwater Sampling at Hanford (HNF-38542-FP Revision 0, Presented at Waste Management 2009 Conference, March 1 - March 5, 2009, Phoenix, AZ), we described the methods, tools, and techniques that would be used in automating the activities associated with measuring water levels. The Field Logging and Electronic Data Gathering (FLEDG) application/database that automates collecting the water-level measurement data has now been implemented at Hanford. In addition to eliminating the need to print out documents, the system saves three-to-four man days each month for the field personnel taking the measurements and the scientists and administrators managing the data and the documentation. After the information has received technical review, FLEDG automatically updates the database for water-level measurements and loads the document management system with the completed sampling report. Due to safety considerations, access to wells is conditional. A spreadsheet with appropriate data not only lists the wells that are cleared for work, but also the safety personnel who must be present before work can start. This spreadsheet is used in planning daily activities. Daily plans are structured to ensure that the wells to be sampled are cleared for work and the appropriate safety personnel have been assigned and are present before the work starts. Historically, the spreadsheets have been prepared manually, and as a result, are potentially subject to human error. However, a companion database application has been developed to work with FLEDG - making the entire sampling process more efficient and safer for personnel. The Well Access List - Electronic, WAL-E, is a database that contains much the same information that was previously manually loaded into the spread sheet. In addition, WAL-E contains a managed work-flow application that shows the access requirements and allows for appropriate reviews of the compiled well. Various CHPRC organizations, including Industrial Hygiene, RADCON, and Well Maintenance and Sample Administration are able to enter and review the wells added or deleted from the WAL-E database. The FLEDG system then accesses this database information to identify appropriate support personnel and provide safety requirements to field personnel. In addition, WAL-E offers the assurance that wells have appropriate locks and are correctly labeled and electrically grounded as required, before well activities begin. This feature is an extremely important aspect of the FLEDG/WAL-E system because it adds another safety check to the work evolution and reduces the pote

  19. Automated collection and processing of environmental samples

    DOE Patents [OSTI]

    Troyer, Gary L. (Richland, WA); McNeece, Susan G. (Richland, WA); Brayton, Darryl D. (Richland, WA); Panesar, Amardip K. (Kennewick, WA)

    1997-01-01

    For monitoring an environmental parameter such as the level of nuclear radiation, at distributed sites, bar coded sample collectors are deployed and their codes are read using a portable data entry unit that also records the time of deployment. The time and collector identity are cross referenced in memory in the portable unit. Similarly, when later recovering the collector for testing, the code is again read and the time of collection is stored as indexed to the sample collector, or to a further bar code, for example as provided on a container for the sample. The identity of the operator can also be encoded and stored. After deploying and/or recovering the sample collectors, the data is transmitted to a base processor. The samples are tested, preferably using a test unit coupled to the base processor, and again the time is recorded. The base processor computes the level of radiation at the site during exposure of the sample collector, using the detected radiation level of the sample, the delay between recovery and testing, the duration of exposure and the half life of the isotopes collected. In one embodiment, an identity code and a site code are optically read by an image grabber coupled to the portable data entry unit.

  20. Reference samples for water-related programs in the US Environmental Protection Agency

    SciTech Connect (OSTI)

    Winter, J.A.

    1985-06-01

    The Environmental Monitoring and Support Laboratory at Cincinnati provides quality assurance (QA) support for US Environmental Protection Agency (EPA) water-related programs. Two important segments of this support are the Quality Control Sample Program, which furnishes samples of known concentrations for use as independent checks on intralaboratory QA activities, and the EPA's Repository for Toxic and Hazardous Materials, which provides calibration standards and spiking solutions for trace organic analyses of interest to the Agency. Each series contains one or more analytes, with true or reference values. The samples and standards are prepared as stable concentrated solutions in all-glass ampuls for dilution to volume, and analyses by EPA, its contractors and grantees, and other federal, state, and local agencies. 1 reference, 6 tables.

  1. Hanford Waste Vitrification Plant full-scale feed preparation testing with water and process simulant slurries

    SciTech Connect (OSTI)

    Gaskill, J.R.; Larson, D.E.; Abrigo, G.P. [and others] [and others

    1996-03-01

    The Hanford Waste Vitrification Plant was intended to convert selected, pretreated defense high-level waste and transuranic waste from the Hanford Site into a borosilicate glass. A full-scale testing program was conducted with nonradioactive waste simulants to develop information for process and equipment design of the feed-preparation system. The equipment systems tested included the Slurry Receipt and Adjustment Tank, Slurry Mix Evaporator, and Melter-Feed Tank. The areas of data generation included heat transfer (boiling, heating, and cooling), slurry mixing, slurry pumping and transport, slurry sampling, and process chemistry. 13 refs., 129 figs., 68 tabs.

  2. The RGB Sample of Intermediate BL Lacs

    E-Print Network [OSTI]

    S. A. Laurent-Muehleisen; R. I. Kollgaard; E. D. Feigelson; W. Brinkmann; J. Siebert

    1999-05-12

    Combining newly identified and previously known BL Lacs from the RASS-Green Bank (RGB) catalog, we present a sample of 127 BL Lacs, the largest ever derived from a single uniform survey. A Complete sample of 33 objects brighter than O=18.0 mag is also presented. These samples are compared to other known BL Lac samples and are generally found to exhibit properties intermediate between those of the previously disparate classes of High and Low energy peaked BL Lacs (HBLs and LBLs, respectively). This result is most dramatic in the distribution of the X-ray to radio logarithmic flux ratios, where the RGB BL Lacs are shown to peak precisely where the sharp dichotomy between the two subclasses was previously seen. The alpha_ro vs alpha_ox diagram also shows the RGB sample smoothly bridges the gap between the previously distinct subclasses of LBLs and HBLs. We also find a weak, but statistically significant correlation between the composite X-ray spectral index alpha_xox and alpha_ro. This implies that the more LBL-like RGB BL Lacs have a secondary source of X-ray emission, possibly from an inverse Compton component. We also present both the X-ray and radio logN-logS distributions for which the competing HBL/LBL unification scenarios have differing predictions. The unknown effects of the triple flux limit inherent in the RGB Complete sample makes quantitative analysis uncertain, but the characteristics of the RGB sample compare well both with results obtained from previous samples and with general theoretical predictions based on a simple Monte Carlo simulation. Our analysis indicates that the unimodal distribution of BL Lac properties found in the RGB sample likely reliably reflect the underlying population, while the bimodal distribution found in earlier studies arose primarily from observational selection effects.

  3. Evaluating Radionuclide Air Emission Stack Sampling Systems

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.

    2002-12-16

    The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R&D) facilities for the U.S. Department of Energy at the Hanford Site, Washington. These facilities are subject to Clean Air Act regulations that require sampling of radionuclide air emissions from some of these facilities. A revision to an American National Standards Institute (ANSI) standard on sampling radioactive air emissions has recently been incorporated into federal and state regulations and a re-evaluation of affected facilities is being performed to determine the impact. The revised standard requires a well-mixed sampling location that must be demonstrated through tests specified in the standard. It also carries a number of maintenance requirements, including inspections and cleaning of the sampling system. Evaluations were performed in 2000 – 2002 on two PNNL facilities to determine the operational and design impacts of the new requirements. The evaluation included inspection and cleaning maintenance activities plus testing to determine if the current sampling locations meet criteria in the revised standard. Results show a wide range of complexity in inspection and cleaning activities depending on accessibility of the system, ease of removal, and potential impact on building operations (need for outages). As expected, these High Efficiency Particulate Air (HEPA)-filtered systems did not show deposition significant enough to cause concerns with blocking of the nozzle or other parts of the system. The tests for sampling system location in the revised standard also varied in complexity depending on accessibility of the sample site and use of a scale model can alleviate many issues. Previous criteria to locate sampling systems at eight duct diameters downstream and two duct diameters upstream of the nearest disturbances is no guarantee of meeting criteria in the revised standard. A computational fluid dynamics model was helpful in understanding flow and contaminant mixing in an exhaust system and may be useful to identify potential sampling locations in an exhaust system that are likely to meet criteria in the revised standard.

  4. Copper- and silver-zirconia aerogels: Preparation, structural properties and catalytic behavior in methanol synthesis from carbon dioxide

    SciTech Connect (OSTI)

    Koeppel, R.A.; Stoecker, C.; Baiker, A. [Swiss Federal Inst. of Technology, Zuerich (Switzerland). Lab. of Technical Chemistry] [Swiss Federal Inst. of Technology, Zuerich (Switzerland). Lab. of Technical Chemistry

    1998-10-25

    Copper- and silver-zirconia aerogels containing 10 at% IB metal were prepared from tetra-n-butoxy zirconium(IV) and IB metal acetates using the solution sol-gel method and ensuring high-temperature (HT) and low-temperature (LT) supercritical drying, respectively. The influence of preparation parameters and calcination on the structural and catalytic properties of the aerogels for the synthesis of methanol from carbon dioxide and hydrogen was investigated. After calcination in air at 573 K, the catalysts had BET surface areas in the range of 100--143 m{sup 2}/g (Cu/ZrO{sub 2}) and 77--125 m{sup 2}/g (Ag/ZrO{sub 2}), respectively. Due to the reductive alcoholic atmosphere during high-temperature supercritical drying, metallic copper and silver existed in all raw HT-aerogels. The mean size of the copper crystallites wa/s 30 nm. The silver crystallite size for the HT-aerogel prepared with nitric acid was 10 nm, whereas for samples prepared with acetic acid it was 5--7 nm. Calcination in air at 573 K led to the formation of highly dispersed amorphous copper oxide and silver. Comparing the catalytic behavior of the calcined copper-zirconia aerogels with corresponding xerogels prepared by coprecipitation revealed highest activity for the LT-aerogel, whereas the HT-aerogels were least active. In contrast, similar catalytic behavior was observed for the differently dried silver-zirconia samples. Generally, CO{sub 2}-conversion of the copper-zirconia samples. Generally, CO{sub 2}-conversion of the copper-zirconia aerogels was markedly higher than that of the corresponding silver-zirconia aerogels, whereas methanol selectivity was similar.

  5. Visual Sample Plan (VSP) - FIELDS Integration

    SciTech Connect (OSTI)

    Pulsipher, Brent A.; Wilson, John E.; Gilbert, Richard O.; Hassig, Nancy L.; Carlson, Deborah K.; Bing-Canar, John; Cooper, Brian; Roth, Chuck

    2003-04-19

    Two software packages, VSP 2.1 and FIELDS 3.5, are being used by environmental scientists to plan the number and type of samples required to meet project objectives, display those samples on maps, query a database of past sample results, produce spatial models of the data, and analyze the data in order to arrive at defensible decisions. VSP 2.0 is an interactive tool to calculate optimal sample size and optimal sample location based on user goals, risk tolerance, and variability in the environment and in lab methods. FIELDS 3.0 is a set of tools to explore the sample results in a variety of ways to make defensible decisions with quantified levels of risk and uncertainty. However, FIELDS 3.0 has a small sample design module. VSP 2.0, on the other hand, has over 20 sampling goals, allowing the user to input site-specific assumptions such as non-normality of sample results, separate variability between field and laboratory measurements, make two-sample comparisons, perform confidence interval estimation, use sequential search sampling methods, and much more. Over 1,000 copies of VSP are in use today. FIELDS is used in nine of the ten U.S. EPA regions, by state regulatory agencies, and most recently by several international countries. Both software packages have been peer-reviewed, enjoy broad usage, and have been accepted by regulatory agencies as well as site project managers as key tools to help collect data and make environmental cleanup decisions. Recently, the two software packages were integrated, allowing the user to take advantage of the many design options of VSP, and the analysis and modeling options of FIELDS. The transition between the two is simple for the user – VSP can be called from within FIELDS, automatically passing a map to VSP and automatically retrieving sample locations and design information when the user returns to FIELDS. This paper will describe the integration, give a demonstration of the integrated package, and give users download instructions and software requirements for running the integrated package.

  6. Gas sampling system for a mass spectrometer

    DOE Patents [OSTI]

    2003-12-30

    The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

  7. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, J.E.; Dinsmore, S.R.; Chandler, E.W.

    1986-01-07

    A four-port disc valve is described for sampling erosive, high temperature process streams. A rotatable disc defining opposed first and second sampling cavities rotates between fired faceplates defining flow passageways positioned to be alternatively in axial alignment with the first and second cavities. Silicon carbide inserts and liners composed of [alpha] silicon carbide are provided in the faceplates and in the sampling cavities to limit erosion while providing lubricity for a smooth and precise operation when used under harsh process conditions. 1 fig.

  8. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  9. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

    1996-01-01

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  10. Spectroscopic diagnostics for bacteria in biologic sample

    DOE Patents [OSTI]

    El-Sayed, Mostafa A. (Atlanta, GA); El-Sayed, Ivan H. (Somerville, MA)

    2002-01-01

    A method to analyze and diagnose specific bacteria in a biologic sample using spectroscopy is disclosed. The method includes obtaining the spectra of a biologic sample of a non-infected patient for use as a reference, subtracting the reference from the spectra of an infected sample, and comparing the fingerprint regions of the resulting differential spectrum with reference spectra of bacteria in saline. Using this diagnostic technique, specific bacteria can be identified sooner and without culturing, bacteria-specific antibiotics can be prescribed sooner, resulting in decreased likelihood of antibiotic resistance and an overall reduction of medical costs.

  11. Guide to preparing SAND reports. Revised

    SciTech Connect (OSTI)

    Locke, T.K. [ed.

    1996-04-01

    This guide contains basic information needed to produce a SAND report. Its guidelines reflect DOE regulation and Sandia policy. The guide includes basic writing instructions in an annotated sample report; guidance for organization, format, and layout of reports produced by line organizations; and information about conference papers, journal articles, and brochures. The appendixes contain sections on Sandia`s preferred usage, equations, references, copyrights and permissions, and publishing terms.

  12. Sample results from the interim salt disposition program macrobatch 9 tank 21H qualification samples

    SciTech Connect (OSTI)

    Peters, T. B.

    2015-11-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 9 for the Interim Salt Disposition Program (ISDP). This document reports characterization data on the samples of Tank 21H.

  13. Structural and spectroscopic analyses of europium doped yttrium oxyfluoride powders prepared by combustion synthesis

    SciTech Connect (OSTI)

    Rakov, Nikifor; Guimarães, R. B.; Maciel, Glauco S.; Lozano B, W.

    2013-07-28

    A facile widely spread technique employed to produce low-cost high-yield oxide powders, combustion synthesis, was used to prepare yttrium oxyfluoride crystalline ceramic powders. The structure of the powders was analyzed by X-ray powder diffraction and Rietveld refinement. Samples heat treated at 700 °C had a predominance of vernier orthorhombic Y{sub 6}O{sub 5}F{sub 8} phase, while samples heat treated at 800 °C crystallized in stoichiometric rhombohedral YOF phase. The samples were doped with luminescent europium trivalent ions (Eu{sup 3+}) in different concentrations (1–15 wt.%) and Judd-Ofelt theory was used to probe the distortion from the inversion symmetry of the local crystal field and the degree of covalency between the rare-earth ion and the surrounding ligands. The luminescence lifetime was measured and the luminescence quantum efficiency (LQE) was estimated. We observed that Eu{sup 3+}:Y{sub 6}O{sub 5}F{sub 8} samples presented higher LQE in spite of the larger local crystal field anisotropy found for Eu{sup 3+}:YOF samples.

  14. Sampling and analysis plan for canister liquid and gas sampling at 105 KW fuel storage basin

    SciTech Connect (OSTI)

    Trimble, D.J.

    1996-08-09

    This Sampling and Analysis Plan describes the equipment,procedures and techniques for obtaining gas and liquid samples from sealed K West fuel canisters. The analytical procedures and quality assurance requirements for the subsequent laboratory analysis of the samples are also discussed.

  15. Department of Energy's Recommendations for the Preparation of...

    Open Energy Info (EERE)

    of Energy's Recommendations for the Preparation of Environmental Assessments and Environmental Impact Statements Abstract Department of Energy guidance on NEPA Policy and...

  16. EIS-0463: Notice of Intent to Prepare an Environmental Impact...

    Office of Environmental Management (EM)

    Public Scoping Meetings Presidential Permit Application for Northern Pass Transmission, New Hampshire Notice of Intent To Prepare an Environmental Impact Statement and Conduct...

  17. Controlled environment vitrification system for preparation of liquids

    DOE Patents [OSTI]

    Bellare, J.R.; Davis, H.T.; Scriven, L.E. II; Talmon, Y.

    1988-06-28

    A system is described for preparing specimens in a controlled environment to insure that a liquid or partially liquid specimen is maintained in its original state while it is being prepared, and once prepared the specimen is vitrified or solidified with minimal alteration of its microstructure. The controlled environment is provided within a chamber where humidity and temperature can be controlled precisely while the specimen is prepared. The specimen is mounted on a plunger and a shutter controlled opening is opened substantially simultaneously with release of the plunger so the specimen is propelled through the shutter into an adjacent cryogenic bath. 7 figs.

  18. EIS-0409: Notice of Intent to Prepare an Environmental Impact...

    Broader source: Energy.gov (indexed) [DOE]

    prepare an environmental impact statement for the proposed Kemper County Integrated Gasification Combined Cycle Project in Kemper County, Mississippi to assess the potential...

  19. Student Design Competition Guide to Project Preparation and Submittal

    Broader source: Energy.gov [DOE]

    Student Design Competition Guide to Project Preparation and Submittal, from the U.S. Department of Energy's Zero Energy Ready Home program.

  20. p-Type transparent conducting oxides and methods for preparation

    DOE Patents [OSTI]

    Shahriari, Dean Y. (Evanston, IL); Barnabe, Antoine (Toulouse, FR); Mason, Thomas O. (Evanston, IL); Poeppelmeier, Kenneth R. (Evanston, IL)

    2011-05-31

    A facile, low temperature and low pressure method for the preparation of a wide range of phase pure ABO.sub.2 compositions.

  1. EIS-0301: Notice of Intent to Prepare an Environmental Impact...

    Broader source: Energy.gov (indexed) [DOE]

    Inc.Transmission Line, Phoenix, Arizona Notice of Intent to Prepare an Environmental Impact Statement and Notice of Floodplain and Wetlands Involvement; NRG Energy, Inc. NRG...

  2. EIS-0435: Notice of Intent to Prepare an Environmental Impact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting Modification of the Groton Generation Station Interconnection Agreement, Brown County, South Dakota Notice of Intent to prepare an environmental impact statement for...

  3. The radioactive Substances (Prepared Uranium Thorium Compounds) Exemption Order 1962 

    E-Print Network [OSTI]

    Joseph, Keith

    1962-01-01

    STATUTORY INSTRUMENTS 1962 No. 2711 ATOMIC ENERGY AND RADIOACI1VE SUBSTANCES The Radioactive Substances (prepared Uranium and Thorium Compounds) Exemption Order 1962

  4. EIS-0461: Notice of Intent to Prepare an Environmental Impact...

    Broader source: Energy.gov (indexed) [DOE]

    Interconnection of the Proposed Hyde County Wind Energy Center Project, South Dakota Notice of Intent to Prepare an Environmental Impact Statement and to Conduct Scoping Meetings:...

  5. EIS-0459: Notice of Intent to Prepare a Programmatic Environmental...

    Energy Savers [EERE]

    Environmental Impact Statement Notice of Intent to Prepare a Programmatic Environmental Impact Statement for the Hawai'i Interisland Renewable Energy Program: Wind, EIS-0459...

  6. EIS-0459: Notice of Intent to Prepare a Programmatic Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    Intent to Prepare a Programmatic Environmental Impact Statement for the Hawai'i Interisland Renewable Energy Program: Wind, EIS-0459 (December 2010) (75 FR 77859) More Documents &...

  7. EIS-0462: Notice of Intent to Prepare an Environmental Impact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Statement and to Conduct Scoping Meetings Interconnection of the Proposed Crowned Ridge Wind Energy Center Project, South Dakota Intent to Prepare an Environmental Impact...

  8. Preparations of rare earth-iron alloys by thermite reduction

    DOE Patents [OSTI]

    Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA)

    1986-09-16

    An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

  9. EIS-0396: Advance Notice of Intent o Prepare an Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EIS-0396: Advance Notice of Intent o Prepare an Environmental Impact Statement Global Nuclear Energy Partnership Technology Demonstration Program Advance Notice of Intent To...

  10. EIS-0323: Notice of Intent to Prepare a Supplemental Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Prepare a Supplemental Environmental Impact Statement and Conduct Scoping Meetings Sacramento Area Voltage Support Project in California The Western Area Power Administration...

  11. Data Preparation Process for the Buildings Performance Database...

    Broader source: Energy.gov (indexed) [DOE]

    Data Preparation Process for the Buildings Performance Database, from the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy, and Lawrence Berkeley...

  12. Land Acquisition Prepared by: Ben Floyd, Economic & Engineering Services

    E-Print Network [OSTI]

    Land Acquisition Prepared by: Ben Floyd, Economic & Engineering Services May 2004 Introduction Land economy. This may also require that existing agricultural producers need to travel farther

  13. RUS Bulletin 1794-A-600: Preparing an Environmental Report for...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: RUS Bulletin 1794-A-600: Preparing an Environmental Report for Categorically...

  14. EIS-0269: Notice of Intent to Prepare a Programmatic Environmental...

    Office of Environmental Management (EM)

    EIS-0269: Notice of Intent to Prepare a Programmatic Environmental Impact Statement Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride,...

  15. EIS-0509: Supplemental Notice of Intent to Prepare Environmental...

    Energy Savers [EERE]

    Notice of Intent to Prepare Environmental Impact Statement Mississippi River LNG Project; Plaquemines Parish, Louisiana The Federal Energy Regulatory Commission (FERC)...

  16. SWNT-Filled Thermoplastic and Elastomeric Composites Prepared by

    E-Print Network [OSTI]

    Resasco, Daniel

    SWNT-Filled Thermoplastic and Elastomeric Composites Prepared by Miniemulsion Polymerization Harry nanotube (MWNT) and single wall nanotube (SWNT) filled thermoplastics such as polystyrene (PS),1 poly

  17. Advanced Post-Combustion CO2 Capture Prepared for the

    E-Print Network [OSTI]

    Advanced Post-Combustion CO2 Capture Prepared for the Clean Air Task Force under a grant from...................................................................................... 3 2. Current Status of Post-Combustion Capture

  18. ANSYS Thermoelectric Generator (TEG) Preparing the ANSYS Workbench

    E-Print Network [OSTI]

    Lee, Ho Sung

    ANSYS Thermoelectric Generator (TEG) Tutorial Preparing the ANSYS Workbench 1) Go Start Menu All) Save the project as Thermoelectric-Generator-Workbench. Specifying the Materials and Properties 1

  19. Optimized Pump Systems Save Coal Preparation Plant Money and...

    Broader source: Energy.gov (indexed) [DOE]

    case study describes how Peabody Holding Company was able to improve the performance of a coal slurry pumping system at its Randolph Coal Preparation plant. Using a systematic...

  20. DOE-L.__ PROPOSAL PREPARATION INSTRUCTIONS - COVER LETTER AND

    Office of Environmental Management (EM)

    L. PROPOSAL PREPARATION INSTRUCTIONS - COVER LETTER AND VOLUME I, OFFER AND OTHER DOCUMENTS (a) Instruction - Cover Letter. The cover letter shall include, but not be limited to,...

  1. Controlled remote state preparation via partially entangled quantum channel

    E-Print Network [OSTI]

    Chun Wang; Zhi Zeng; Xi-Han Li

    2014-12-30

    We propose two controlled remote state preparation protocols via partially entangled channels. One prepares a single-qubit state and the other prepares a two-qubit state. Different from other controlled remote state preparation schemes which also utilize partially entangled channels, neither auxiliary qubits nor two-qubit unitary transformations are required in our schemes and the success probabilities are independent of the coefficients of the quantum channel. The success probabilities are 50% and 25% for arbitrary single-qubit states and two-qubit states, respectively. We also show that the success probabilities can reach 100% for restricted classes of states.

  2. EIS-0307: Notice of Intent To Prepare an Environmental Impact...

    Broader source: Energy.gov (indexed) [DOE]

    of Sonora. The proposed transmission lines may be either alternating current (AC) or direct current (DC). Notice of Intent To Prepare an Environmental Impact Statement and To...

  3. EIS-0472: Notice of Intent to Prepare a Programmatic Environmental...

    Office of Environmental Management (EM)

    EIS-0472: Notice of Intent to Prepare a Programmatic Environmental Impact Statement Uranium Leasing Program Programmatic Environmental Impact Statement The underlying purpose...

  4. EIS-0310: Notice of Intent to Prepare a Programmatic Environmental...

    Energy Savers [EERE]

    the potential environmental impacts of alternative ways to meet the projected irradiation needs for the next 35 years. Notice of Intent to Prepare a Programmatic...

  5. EIS-0200: Notice of Intent to Prepare a Programmatic Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    Proposed Integrated Environmental Restoration and Waste Management Program, and to Conduct Public Scoping Meetings The Department of Energy announces its intent to prepare a PEIS...

  6. EIS-0447: Notice of Intent to Prepare an Environmental Impact...

    Energy Savers [EERE]

    Conduct Public Scoping Meetings Champlain Hudson Power Express Transmission Line Project, New York Notice of Intent To Prepare an Environmental Impact Statement and To Conduct...

  7. Polymer-assisted deposition of films and preparation of carbon...

    Office of Scientific and Technical Information (OSTI)

    of carbon nanotube arrays using the films Carbon nanotubes were prepared by coating a substrate with a coating solution including a suitable solvent, a soluble polymer,...

  8. EIS-0366: Notice of Intent to Prepare a Programmatic Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    Implementation of the Carbon Sequestration Program The U.S. Department of Energy (DOE) announces its intent to prepare a Programmatic Environmental Impact Statement (PEIS) to...

  9. Generalized Sampling-Based Feedback Motion Planners 

    E-Print Network [OSTI]

    Kumar, Sandip

    2012-02-14

    states. In the deterministic robotics motion planning community, sampling based algorithms like probabilistic roadmaps (PRM) and rapidly exploring random trees (RRTs) have been successful in solving very high dimensional deterministic problem. However...

  10. Interdisciplinary Mathematics/Statistics Actuarial Science Sample ...

    E-Print Network [OSTI]

    Interdisciplinary Mathematics/Statistics Actuarial Science Sample Plan 2 . 1 MA 161 (4-5) MA/S T 170 ENGL 101 Lab Science Language or 165, 173, 181, 271 ...

  11. Gibbs Sampling and Centroids for Gene Regulation

    E-Print Network [OSTI]

    Newberg, Heidi

    of bioethanol and biohydrogen production" (CEL, LAM, LAN) E #12;Lee A. Newberg 11/30/2011 Gibbs sampling ... for the understanding of cell function, differentiation, and pathology ... because the elements affect both the products

  12. Metrics for sampling-based motion planning 

    E-Print Network [OSTI]

    Morales Aguirre, Marco Antonio

    2009-05-15

    A motion planner finds a sequence of potential motions for a robot to transit from an initial to a goal state. To deal with the intractability of this problem, a class of methods known as sampling-based planners build ...

  13. LIGHT EMITTING DIODE CHARACTERISTICS (SAMPLE LAB WRITEUP)

    E-Print Network [OSTI]

    McNeill, John A.

    1 LIGHT EMITTING DIODE CHARACTERISTICS (SAMPLE LAB WRITEUP) John A. McNeill ECE Box 000 January 19, 1997 ABSTRACT This lab investigates the V-I characteristic of a light-emitting diode (LED

  14. Experimental analysis of municipal solid waste samples 

    E-Print Network [OSTI]

    Mendoza Sanchez, Itza

    2002-01-01

    In the analysis of municipal solid waste consolidation, large-scale devices are usually used to measure the compression and hydraulic conductivity parameters. The use of those devices is justified due to difficulties in probing undisturbed samples...

  15. WRAP Module 1 sampling and analysis plan

    SciTech Connect (OSTI)

    Mayancsik, B.A.

    1995-03-24

    This document provides the methodology to sample, screen, and analyze waste generated, processed, or otherwise the responsibility of the Waste Receiving and Processing Module 1 facility. This includes Low-Level Waste, Transuranic Waste, Mixed Waste, and Dangerous Waste.

  16. Surface sampling concentration and reaction probe

    DOE Patents [OSTI]

    Van Berkel, Gary J; Elnaggar, Mariam S

    2013-07-16

    A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

  17. On sampling fractions and electron shower shapes

    SciTech Connect (OSTI)

    Peryshkin, Alexander; Raja, Rajendran; /Fermilab

    2011-12-01

    We study the usage of various definitions of sampling fractions in understanding electron shower shapes in a sampling multilayer electromagnetic calorimeter. We show that the sampling fractions obtained by the conventional definition (I) of (average observed energy in layer)/(average deposited energy in layer) will not give the best energy resolution for the calorimeter. The reason for this is shown to be the presence of layer by layer correlations in an electromagnetic shower. The best resolution is obtained by minimizing the deviation from the total input energy using a least squares algorithm. The 'sampling fractions' obtained by this method (II) are shown to give the best resolution for overall energy. We further show that the method (II) sampling fractions are obtained by summing the columns of a non-local {lambda} tensor that incorporates the correlations. We establish that the sampling fractions (II) cannot be used to predict the layer by layer energies and that one needs to employ the full {lambda} tensor for this purpose. This effect is again a result of the correlations.

  18. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organicsmore »present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.« less

  19. Rapid determination of actinides in asphalt samples

    SciTech Connect (OSTI)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organics present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.

  20. Preparation of new morphological ZnO and Ce-doped ZnO

    SciTech Connect (OSTI)

    Chelouche, A.; Djouadi, D.; Aksas, A. [Laboratoire de Génie de l'Environnement, Université A. Mira de Béjaia, Route de Targua Ouzemmour Béjaia (Algeria)

    2013-12-16

    ZnO micro-tori and cerium doped hexangulars ZnO have been prepared by the sol-gel method under methanol hypercritical conditions of temperature and pressure. X-ray diffraction (XRD) measurement has revealed the high crystalline quality and the nanometric size of the samples. Scanning electron microscopy (SEM) has shown that the ZnO powder has a torus-like shape while that of ZnO:Ce has a hexangular-like shape, either standing free or inserted into the cores of ZnO tori. Transmission electron microscopy (TEM) has revealed that the ZnO particles have sizes between 25 and 30 nm while Ce-doped ZnO grains have diameters ranging from 75 nm to 100 nm. Photoluminescence spectra at room temperature of the samples have revealed that the introduction of cerium in ZnO reduces the emission intensity lines, particularly the ZnO red and green ones.

  1. Characterization of Hafnia Powder Prepared from an Oxychloride Sol Gel

    SciTech Connect (OSTI)

    McGilvery, Catriona M. [Imperial College, London; De Gendt, S [Imperial College, London; Payzant, E Andrew [ORNL; MacKenzie, M [Imperial College, London; Craven, A J [Imperial College, London; McComb, D W [Imperial College, London

    2011-01-01

    Hafnium containing compounds are of great importance to the semiconductor industry as a replacement for Si(O,N) with a high- gate dielectric. Whilst Hf is already being incorporated into working devices1, much is still to be understood about it. Here we investigate the crystallisation processes and chemistry of bulk HfO2 powders which will aid in interpretation of reactions and crystallisation events occurring in thin films used as gate dielectrics. Amorphous HfO2 powder was prepared via a sol-gel route using hafnium oxychloride (HfOCl2 xH2O) as a precursor. The powders were subjected to various heat treatments and analysed using x-ray diffraction (XRD) and thermal analysis techniques. It was found that a large change in the crystallisation pathway occurred when the sample was heated in an inert environment compared with in air. Instead of the expected monoclinic phase (m-HfO2), tetragonal HfO2 (t-HfO2) also formed under these conditions and was observed up to temperatures of ~760 C. The t-HfO2 particles, which are less than 30nm in size, eventually transform into m-HfO2 on further heating. Possible mechanisms for the crystallisation of t-HfO2 are discussed. It is proposed that within this temperature range t-HfO2 is stabilised due to the presence of oxygen vacancies in the inert environment, forming by the reduction of HfIV to HfIII. As the crystal grows in size as the temperature increases there are too few oxygen vacancies left in the structure to continue stabilising the t-HfO2 phase and so transformation to m-HfO2 occurs.

  2. Method of high purity silane preparation

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Golden, CO); Belov, Eugene P. (Moscow, RU); Gerlivanov, Vadim G. (Moscow, RU); Zadde, Vitali V. (Moscow, RU); Kleschevnikova, Solomonida I. (Moscow, RU); Korneev, Nikolai N. (Moscow, RU); Lebedev, Eugene N. (Moscow, RU); Pinov, Akhsarbek B. (Moscow, RU); Ryabenko, Eugene A. (Moscow, RU); Strebkov, Dmitry S. (Moscow, RU); Chernyshev, Eugene A. (Moscow, RU)

    2000-01-01

    A process for the preparation of high purity silane, suitable for forming thin layer silicon structures in various semiconductor devices and high purity poly- and single crystal silicon for a variety of applications, is provided. Synthesis of high-purity silane starts with a temperature assisted reaction of metallurgical silicon with alcohol in the presence of a catalyst. Alcoxysilanes formed in the silicon-alcohol reaction are separated from other products and purified. Simultaneous reduction and oxidation of alcoxysilanes produces gaseous silane and liquid secondary products, including, active part of a catalyst, tetra-alcoxysilanes, and impurity compounds having silicon-hydrogen bonds. Silane is purified by an impurity adsorption technique. Unreacted alcohol is extracted and returned to the reaction with silicon. Concentrated mixture of alcoxysilanes undergoes simultaneous oxidation and reduction in the presence of a catalyst at the temperature -20.degree. C. to +40.degree. C. during 1 to 50 hours. Tetra-alcoxysilane extracted from liquid products of simultaneous oxidation and reduction reaction is directed to a complete hydrolysis. Complete hydrolysis of tetra-alcoxysilane results in formation of industrial silica sol and alcohol. Alcohol is dehydrated by tetra-alcoxysilane and returned to the reaction with silicon.

  3. Preparation for upgrading western subbituminous coal

    SciTech Connect (OSTI)

    Grimes, R.W.; Cha, C.Y.; Sheesley, D.C.

    1990-11-01

    The objective of this project was to establish the physical and chemical characteristics of western coal and determine the best preparation technologies for upgrading this resource. Western coal was characterized as an abundant, easily mineable, clean, low-sulfur coal with low heating value, high moisture, susceptibility to spontaneous ignition, and considerable transit distances from major markets. Project support was provided by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The research was conducted by the Western Research Institute, (WRI) in Laramie, Wyoming. The project scope of work required the completion of four tasks: (1) project planning, (2) literature searches and verbal contacts with consumers and producers of western coal, (3) selection of the best technologies to upgrade western coal, and (4) identification of research needed to develop the best technologies for upgrading western coals. The results of this research suggest that thermal drying is the best technology for upgrading western coals. There is a significant need for further research in areas involving physical and chemical stabilization of the dried coal product. Excessive particle-size degradation and resulting dustiness, moisture reabsorption, and high susceptibility to spontaneous combustion are key areas requiring further research. Improved testing methods for the determination of equilibrium moisture and susceptibility to spontaneous ignition under various ambient conditions are recommended.

  4. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, Jr., Charles (Albuquerque, NM); Derzon, Dora K. (Albuquerque, NM); Nelson, Jill S. (Albuquerque, NM); Rand, Peter B. (Albuquerque, NM)

    1995-01-01

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications.

  5. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, C. Jr.; Derzon, D.K.; Nelson, J.S.; Rand, P.B.

    1995-07-11

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications. 1 fig.

  6. Methods for preparation of cyclopentadienyliron (II) arenes

    DOE Patents [OSTI]

    Keipert, Steven J. (Oakdale, MN)

    1991-01-01

    Two improved methods for preparation of compounds with the structure shown in equation X [(Cp)--Fe--(Ar)].sup.+.sub.b X.sup.b- (X) where Cp is an eta.sup.5 complexed, substituted or unsubstituted, cyclopentadienyl or indenyl anion, Ar is an eta.sup.6 complexed substituted or unsubstituted, pi-arene ligand anad X is a b-valent anion where b is an integer between 1 and 3. The two methods, which differ in the source of the cyclopentadienyl anion - Lewis acid complex, utilize a Lewis acid assisted ligand transfer reaction. The cyclopentadienyl anion ligand, assisted by a Lewis acid is transferred to ferrous ion in the presence of an arene. In the first method, the cyclopentadienyl anion is derived from ferrocene and ferrous chloride. In this reaction, the cyclopentadienyliron (II) arene product is derived partially from ferrocene and partially from the ferrous salt. In the second method, the cyclopentadienyl anion - Lewis acid complex is formed by direct reaction of the Lewis acid with an inorganic cyclopentadienide salt. The cyclopentadienyliron (II) arene product of this reaction is derived entirely from the ferrous salt. Cyclopentadienyliron (II) arene cations are of great interest due to their utility as photoactivatable catalysts for a variety of polymerization reactions.

  7. Preparation and Characterization of Graphene Oxide Paper

    SciTech Connect (OSTI)

    Dikin,D.; Stankovich, S.; Zimney, E.; Piner, R.; Dommett, G.; Evmenenko, G.; Nguyen, S.; Ruoff, R.

    2007-01-01

    Free-standing paper-like or foil-like materials are an integral part of our technological society. Their uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Inorganic 'paper-like' materials based on nanoscale components such as exfoliated vermiculite or mica platelets have been intensively studied and commercialized as protective coatings, high-temperature binders, dielectric barriers and gas-impermeable membranes. Carbon-based flexible graphite foils composed of stacked platelets of expanded graphite have long been used in packing and gasketing applications because of their chemical resistivity against most media, superior sealability over a wide temperature range, and impermeability to fluids. The discovery of carbon nanotubes brought about bucky paper, which displays excellent mechanical and electrical properties that make it potentially suitable for fuel cell and structural composite applications. Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets. This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale graphene oxide sheets.

  8. Direct analysis of samples by mass spectrometry: From elements to bio-molecules using laser ablation inductively couple plasma mass spectrometry and laser desorption/ionization mass spectrometry

    SciTech Connect (OSTI)

    Perdian, David C.

    2009-08-19

    Mass spectrometric methods that are able to analyze solid samples or biological materials with little or no sample preparation are invaluable to science as well as society. Fundamental research that has discovered experimental and instrumental parameters that inhibit fractionation effects that occur during the quantification of elemental species in solid samples by laser ablation inductively coupled plasma mass spectrometry is described. Research that determines the effectiveness of novel laser desorption/ionization mass spectrometric methods for the molecular analysis of biological tissues at atmospheric pressure and at high spatial resolution is also described. A spatial resolution is achieved that is able to analyze samples at the single cell level.

  9. Vapor and gas sampling of Single-Shell Tank 241-A-101 using the Vapor Sampling System

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-11-01

    This document presents sampling data resulting from the June 8, 1995, sampling of SST 241-A-101 using the Vapor Sampling System.

  10. Technology recommendations for pre-screening of IAEA swipe samples

    SciTech Connect (OSTI)

    Steeb, Jennifer L. [Argonne National Lab. (ANL), Argonne, IL (United States); Smith, Nicholas A. [Argonne National Lab. (ANL), Argonne, IL (United States); Lee, Denise L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Huckabay, Heath A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ticknor, Brian W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-01-01

    Argonne and Oak Ridge National Laboratories have prepared an analysis of recommended, possible, and not recommended technologies for pre-screening and prioritizing IAEA swipes. The analytical techniques listed under the recommended technology list are the most promising techniques available to date. The recommended list is divided into two sections: Argonne’s recommended techniques and Oak Ridge’s recommended techniques. This list was divided based upon the expertise of staff in each subject area and/or the instrumentation available at each laboratory. The following section, titled Possible Techniques, is a list of analytical techniques that could be used for pre-screening and prioritizing swipes if additional instrumentation and effort were provided. These techniques are not necessarily top priority, but should not be discounted for future or expanded efforts. Lastly, a list of not recommended techniques is provided to outline the analytical methods and instrumentation that were investigated by each lab but deemed not suitable for this task. In addition to the recommendation list, a short procedure is provided outlining the steps followed for destructive analysis by the Network of Analytical Laboratories (NWAL) for determination of uranium concentrations, isotopic content of sample and swipe. Swipes generated for this project will be given to ORNL’s NWAL laboratory for analysis after analysis by other techniques at both laboratories.

  11. Deliverable 3 Turbine Installation: Site Preparation and Footings

    E-Print Network [OSTI]

    Deliverable 3 Turbine Installation: Site Preparation and Footings Crissy Field Center Wind Power sufficient for industry standard analysis. Performance of the turbines on the site will be monitored programs. Deliverable 3 Turbine Installation: Site Preparation and Footings The Deliverables and Payment

  12. Our students are smart --and they're prepared.

    E-Print Network [OSTI]

    Our students are smart --and they're prepared. AnnualPlacementReport 2011­12 MichiganTechnologicalUniversity #12;2011­12Career Services 2 · Our students are smart--and they're prepared. Michigan Tech's mission Bridge team brought home two first-place awards (lightness and construction efficiency) and finished

  13. Guidelines for Preparing a Professional Report or Thesis

    E-Print Network [OSTI]

    Huang, Haiying

    Guidelines for Preparing a Professional Report or Thesis for the Master's in City and Regional a Professional Report or Thesis for the Master's in City and Regional Planning version dated September, 08 page 1 Guidelines for Preparing a Professional Report or Thesis for the Master's in City and Regional Planning

  14. Preparation and characterization of graphene oxide Dmitriy A. Dikin1

    E-Print Network [OSTI]

    LETTERS Preparation and characterization of graphene oxide paper Dmitriy A. Dikin1 , Sasha for fuel cell and structural composite applications12­15 . Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon- based membrane material made by flow

  15. Formulation and method for preparing gels comprising hydrous aluminum oxide

    SciTech Connect (OSTI)

    Collins, Jack L.

    2014-06-17

    Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

  16. Formulation and method for preparing gels comprising hydrous cerium oxide

    DOE Patents [OSTI]

    Collins, Jack L; Chi, Anthony

    2013-05-07

    Formulations useful for preparing hydrous cerium oxide gels contain a metal salt including cerium, an organic base, and a complexing agent. Methods for preparing gels containing hydrous cerium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including cerium, an organic base, and a complexing agent.

  17. Formulation and method for preparing gels comprising hydrous hafnium oxide

    DOE Patents [OSTI]

    Collins, Jack L; Hunt, Rodney D; Montgomery, Frederick C

    2013-08-06

    Formulations useful for preparing hydrous hafnium oxide gels contain a metal salt including hafnium, an acid, an organic base, and a complexing agent. Methods for preparing gels containing hydrous hafnium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including hafnium, an acid, an organic base, and a complexing agent.

  18. Augmented Vessels for Pre-operative Preparation in Endovascular Treatments

    E-Print Network [OSTI]

    Chung, Albert C. S.

    Augmented Vessels for Pre-operative Preparation in Endovascular Treatments Wilbur C.K. Wong1 to construct imaginary disease-free vessel lumens, namely augmented vessels, and demarcate the abnormalities;Augmented Vessels for Pre-operative Preparation 603 Several researchers have suggested to detach a saccular

  19. Prepared December 14, 2014, Bodenhorn SOE Alumni Performance Data

    E-Print Network [OSTI]

    Prepared December 14, 2014, Bodenhorn SOE Alumni Performance Data Education performance data can years. 100% of the 132 Educational Leadership students who took the School Leaders Licensure Assessment.org/articles/teacher-retention-a-critical-national-problem.html), we are proud of preparing teachers who are committed to their profession. 100% of our school

  20. Prepared December 14, 2014, Bodenhorn SOE Alumni Performance Data

    E-Print Network [OSTI]

    Prepared December 14, 2014, Bodenhorn SOE Alumni Performance Data Education performance data can years. 100% of the 132 Educational Leadership students who took the School Leaders Licensure Assessment of preparing teachers who are committed to their profession. 100% of our school counselor education alumni over