Sample records for dibasic acid dl

  1. Capillary electrophoretic study of dibasic acids of different structures: Relation to separation of oxidative intermediates in remediation

    SciTech Connect (OSTI)

    Yu, Z.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)

    1998-09-01T23:59:59.000Z

    Dicarboxylic acids are important in environmental chemistry because they are intermediates in oxidative processes involved in natural remediation and waste management processes such as oxidative detoxification and advanced oxidation. Capillary electrophoresis (CE), a promising technique for separating and analyzing these intermediates, has been used to examine a series of dibasic acids of different structures and conformations. This series includes malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, maleic acid, fumaric acid, phthalic acid, and trans, trans-muconic acid. The CE parameters as well as structural variations (molecular structure and molecular isomers, buffer composition, pH, applied voltage, injection mode, current, temperature, and detection wavelength) that affect the separations and analytical results have been examined in this study. Those factors that affect the separation have been delineated. Among these parameters, the pH has been found to be the most important, which affects the double-layer of the capillary wall, the electro-osmotic flow and analyte mobility. The optimum pH for separating these dibasic acids, as well as the other parameters are discussed in detail and related to the development of methods for analyzing oxidation intermediates in oxidative waste management procedures.

  2. Modulation of DL-. alpha. -amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid/quisqualate receptors by phospholipase A sub 2 : A necessary step in long-term potentiation

    SciTech Connect (OSTI)

    Massicotte, G.; Baudry, M. (Univ. of Southern California, Los Angeles (United States)); Vanderklish, P.; Lynch, G. (Univ. of California, Irvine (United States))

    1991-03-01T23:59:59.000Z

    The effects of kainate (KA)-induced epileptic seizures on the binding properites of hippocampal glutamate receptors, on the modulation of DL-{alpha}-amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid (AMPA)/quisqualate receptor by phospholipase A{sub 2} (PLA{sub 2}), and on the formation of long-term potentiation (LTP) were studied in hippocampal membranes and hippocampal slices. Systemic administration of KA produced specific changes in the binding properties of the AMPA/quisqualate receptors and its regulation. Whereas the binding of various ligands to the N-methyl-D-aspartate receptors was not modified by KA treatment, there was a singificant decrease in the maximal number of binding sites for ({sup 3}H)AMPA. The loss of LTP was not due to changes in postsynaptic responses elicited by the bursts that trigger the potentiation effect, thus suggesting that KA treatment disrupts processes that follow N-methyl-D-aspartate receptor activation. Systemic administration of KA was associated with calpain activation as the amount of spectrin breakdown products was increased severalfold in hippocampus but not in cerebellum. Pretreatment of telencephalic membranes with calpain greatly reduced the PLA{sub 2}-induced increase in ({sup 3}H)AMPA binding. The results provide evidence in favor of an essential role of PLA{sub 2} in the development of LTP and suggest that the order of activation of different calcium-dependent processes is critical for producing the final changes underlying LTP.

  3. Doppler Lidar (DL) Handbook

    SciTech Connect (OSTI)

    Newsom, RK

    2012-02-13T23:59:59.000Z

    The Doppler lidar (DL) is an active remote sensing instrument that provides range- and time-resolved measurements of radial velocity and attenuated backscatter. The principle of operation is similar to radar in that pulses of energy are transmitted into the atmosphere; the energy scattered back to the transceiver is collected and measured as a time-resolved signal. From the time delay between each outgoing transmitted pulse and the backscattered signal, the distance to the scatterer is inferred. The radial or line-of-sight velocity of the scatterers is determined from the Doppler frequency shift of the backscattered radiation. The DL uses a heterodyne detection technique in which the return signal is mixed with a reference laser beam (i.e., local oscillator) of known frequency. An onboard signal processing computer then determines the Doppler frequency shift from the spectra of the heterodyne signal. The energy content of the Doppler spectra can also be used to determine attenuated backscatter.

  4. Aggregation of n-octanoyl-dl-cysteine in aqueous solvent systems

    E-Print Network [OSTI]

    Shelley, Ralph Ray

    1975-01-01T23:59:59.000Z

    ? Octanoyl-dl ? Cysteine Sample Preparation Proton Nuclear Magnetic Resonance Apparatus pH Apparatus Dye Absorption Spectrophotometry Apparatus Dye RESULTS AND DISCUSSION Proton Nuclear Magnetic Resonance Theory Chemical Shifts of NOC Critical... concentration Deoxyribonucleic acid n-Octanoyl-dl-cysteine Tetrahydrofuran Nuclear magnetic resonance Surfactant concentration Observed chemical shift of surfactant Micellar chemical shift of surfactant Monomeric chemical shift of surfactant Monomeric...

  5. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 105, NO. Dl, PAGES 1387-1415, JANUARY 20,2000 Sulfur chelllistry in the National Center for

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    Understanding the tropospheric sulfur cycle is impor- tant because of its contribution to acid rain and its effect on the Earth's radiation balance. The role of sulfuric acid in acid rain has been recognizedJOURNAL OF GEOPHYSICAL RESEARCH, VOL. 105, NO. Dl, PAGES 1387-1415, JANUARY 20,2000 Sulfur

  6. Note on Evaluation of AWG Port Utilization Probabilities dl(1, j), j = 1, D, D -1, and

    E-Print Network [OSTI]

    Reisslein, Martin

    1 Note on Evaluation of AWG Port Utilization Probabilities dl(1, j), j = 1, D, D - 1, and dl(1, 1, D - 1 In this appendix we evaluate dl(1, j) for j = 1, D, D-1, i.e., the output port j is not a direct neighbor of sender port D, and note that the dl(1, j) are the same for these AWG ports j. We

  7. Revision of DL-Lite Knowledge Bases Zhe Wang, Kewen Wang, and Rodney Topor

    E-Print Network [OSTI]

    Wang, Kewen

    for propositional logic to DLs but no specific revision operators were provided, e.g. [4, 5]. Recently, there haveRevision of DL-Lite Knowledge Bases Zhe Wang, Kewen Wang, and Rodney Topor Griffith University, Australia Abstract. We address the revision problem for knowledge bases (KBs) in De- scription Logics (DLs

  8. Beamforming for the Underlay Cognitive MISO Interference Channel via UL-DL Duality

    E-Print Network [OSTI]

    Gesbert, David

    Beamforming for the Underlay Cognitive MISO Interference Channel via UL-DL Duality Francesco Negro.negro@eurecom.fr, dirk.slock@eurecom.fr Abstract--SINR duality is shown in a multi-input single- output (MISO) downlink for the IFC. We show that SINR duality under the sum power constraint nevertheless holds in the MISO IFC

  9. MR-Trackable Intramyocardial Injection Catheter P.V. Karmarkar,1* D.L. Kraitchman,1

    E-Print Network [OSTI]

    Atalar, Ergin

    MR-Trackable Intramyocardial Injection Catheter P.V. Karmarkar,1* D.L. Kraitchman,1 I. Izbudak,1 L.V. Hofmann,1 L.C. Amado,2 D. Fritzges,1 R. Young,3 M. Pittenger,3 J.W.M. Bulte,1 and E. Atalar1 ventricular remodeling. MRI can be effectively used to differentiate in- farcted from healthy myocardium. MR

  10. Geomorphic Stream Classification "A Classification of Natural Rivers", Rosgen, D.L.

    E-Print Network [OSTI]

    and animals are constrained by natural channel physics #12;Stream Corridor Restoration: Principles, ProcessesGeomorphic Stream Classification "A Classification of Natural Rivers", Rosgen, D.L. #12;Why is Stream Classification Essential? Napeequa River · Physical stream channel evolution ·Similar stream types

  11. E-Print Network 3.0 - acid similarity matrix Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sia, and Peter S. Kim*, Summary: -terminus) of a DL tetramer, based on the AcidBase system (13, 21). While similar to helical wheel projections... :1 (unpublished results). This...

  12. Voltage Dependent Carrier Collection in CdTe Solar Cells D.L. Btzner1

    E-Print Network [OSTI]

    Romeo, Alessandro

    Voltage Dependent Carrier Collection in CdTe Solar Cells D.L. Bätzner1 , Guido Agostinelli2 , A to 1000nm, i.e. the band edge region of CdTe. Region I is further divided in a `blue' part between 300 nm III is as well subdivided in region IIIa from about 800 nm to the band gap of CdTe (~850 nm

  13. Rvision par r-ensembles de bases de connaissances en DL-LiteR S. Benferhat1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2 E. Würbel3 1 Université d'Artois - Nord de France, CRIL-CNRS UMR 8188. 2 Université d- vision" for revising DL-Lite knowledge bases. Such stra- tegy of revision is based on inconsistency

  14. Some Factors Affecting the Utilization of Phosphoric Acid in Soils by Plants in Pot Experiments.

    E-Print Network [OSTI]

    Fudge, J. F. (Joseph Franklin); Fraps, G. S. (George Stronach)

    1944-01-01T23:59:59.000Z

    TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, Director College Station, Texas BULLETIN NO. 647 APRIL, 1944 SOME FACTORS AFFECTING THE UTILIZATION OF PHOSPHORIC ACID IN SOILS BY PLANTS IN POT EXPERIMENTS G. S. FRAPS and J. F. FUDGE...] The relations between the quantities of phosphoric acid re- moved by corn and milo or kafir and the composition and other characteristics of Texas soils was ascertained from the data of 375 pot experiments. acid acid crol nhn! =---, Wit pho; tota DL...

  15. ITER BLANKET AND SHIELD STUDIES FOR HIGH ASPECT RATIO DESIGN OPTION* Y .Gohar, H. Attaya, M. Billone,C. Johnson,J. Kopasz, S.Majumdar, R. Mattas, and D.L. Smith

    E-Print Network [OSTI]

    Abdou, Mohamed

    . Billone,C. Johnson,J. Kopasz, S.Majumdar, R. Mattas, and D.L. Smith Argonne National Laboratory, 9700 S

  16. The feedback phase instability in the HBT-EP tokamak D.L. Nadle, C. Cates, H. Dahi, M.E. Mauel,

    E-Print Network [OSTI]

    Mauel, Michael E.

    The feedback phase instability in the HBT-EP tokamak D.L. Nadle, C. Cates, H. Dahi, M.E. Mauel, D of a performance limiting feedback phase instability in the HBT-EP toka- mak are reported. The phase instability instability limits feedback performance in HBT-EP by decreasing the feedback loop's phase accuracy as gain

  17. Cryogenic friction behavior of PTFE based solid lubricant composites N.L. McCook, D.L. Burris, P.L. Dickrell and W.G. Sawyer*

    E-Print Network [OSTI]

    Sawyer, Wallace

    of fluid lubricants is precluded. Such conditions are typically considered extreme, often existing lubrication 1. Introduction Solid lubricants are frequently used under opera- tional conditions where the useCryogenic friction behavior of PTFE based solid lubricant composites N.L. McCook, D.L. Burris, P

  18. DEVELOPMENT OF HIGH EFFICIENCY FLEXIBLE CdTe SOLAR CELLS A.Romeo, M. Arnold, D.L. Btzner, H. Zogg and A.N. Tiwari*

    E-Print Network [OSTI]

    Romeo, Alessandro

    to the solar panel that can be adapted to any kind of shape and is easy to deploy in space. In the last yearsDEVELOPMENT OF HIGH EFFICIENCY FLEXIBLE CdTe SOLAR CELLS A.Romeo, M. Arnold, D.L. Bätzner, H. Zogg Telephone: +44-1509-227031 E-mail: a.n.tiwari@lboro.ac.uk ABSTRACT: Polycrystalline thin film solar cells

  19. ARM - Instrument - dl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcal Documentation(AVIRIS) ProductsAirborneOctober 11,govInstrumentsccngovInstrumentscsapr

  20. Does aspartic acid racemization constrain the depth limit of the subsurface biosphere?

    SciTech Connect (OSTI)

    Onstott, T. C. [Princeton University] [Princeton University; Aubrey, A.D. [Jet Propulsion Laboratory, Pasadena, CA] [Jet Propulsion Laboratory, Pasadena, CA; Kieft, T L [New Mexico Institute of Mining and Technology] [New Mexico Institute of Mining and Technology; Silver, B J [Jet Propulsion Laboratory, Pasadena, CA] [Jet Propulsion Laboratory, Pasadena, CA; Phelps, Tommy Joe [ORNL] [ORNL; Van Heerden, E. [University of the Free State] [University of the Free State; Opperman, D. J. [University of the Free State] [University of the Free State; Bada, J L. [Geosciences Research Division, Scripps Instition of Oceanography, Univesity of California San Diego,] [Geosciences Research Division, Scripps Instition of Oceanography, Univesity of California San Diego,

    2014-01-01T23:59:59.000Z

    Previous studies of the subsurface biosphere have deduced average cellular doubling times of hundreds to thousands of years based upon geochemical models. We have directly constrained the in situ average cellular protein turnover or doubling times for metabolically active micro-organisms based on cellular amino acid abundances, D/L values of cellular aspartic acid, and the in vivo aspartic acid racemization rate. Application of this method to planktonic microbial communities collected from deep fractures in South Africa yielded maximum cellular amino acid turnover times of ~89 years for 1 km depth and 27 C and 1 2 years for 3 km depth and 54 C. The latter turnover times are much shorter than previously estimated cellular turnover times based upon geochemical arguments. The aspartic acid racemization rate at higher temperatures yields cellular protein doubling times that are consistent with the survival times of hyperthermophilic strains and predicts that at temperatures of 85 C, cells must replace proteins every couple of days to maintain enzymatic activity. Such a high maintenance requirement may be the principal limit on the abundance of living micro-organisms in the deep, hot subsurface biosphere, as well as a potential limit on their activity. The measurement of the D/L of aspartic acid in biological samples is a potentially powerful tool for deep, fractured continental and oceanic crustal settings where geochemical models of carbon turnover times are poorly constrained. Experimental observations on the racemization rates of aspartic acid in living thermophiles and hyperthermophiles could test this hypothesis. The development of corrections for cell wall peptides and spores will be required, however, to improve the accuracy of these estimates for environmental samples.

  1. DL-36361 UC-414 I

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganization FY Middle SchoolARM-TR-01468This4t c 5

  2. The effect of fasting and the dietary levels of vitamins on the concentration of free amino acids in the plasma and tissues of chicks

    E-Print Network [OSTI]

    Notani, Gursaran Wadhumal

    1957-01-01T23:59:59.000Z

    *, produced a marked depression of growth in rats. The depressed growth was corrected by the addition of either tryptophan or niacin. = Hankes, Henderson;, Elvehjem (1949) observed a de? pression in. tbs rate of; growth of rats after adding DL... of methionine. Henderson, Koeppe and Zimmerman (1953) obtained a growth depression in rats receiving diets that contained 10 percent acid hydrolyzed casein or 1.0 percent zein by ittcrreasing the threonine from 0.33 to 0.38 percent. Lysine above 0?5 percent...

  3. Plant fatty acid hydroxylases

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Lexington, KY)

    2001-01-01T23:59:59.000Z

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  4. Mann, C.P., Stix, J., Vallance, J.W., and Richer, M., 2004, Subaqueous intracaldera volcanism, Ilopango Caldera, El Salvador, Central America, in Rose, W.I., Bommer, J.J., Lpez, D.L., Carr, M.J., and Major, J.J., eds., Natural hazards in El Salvador: Boul

    E-Print Network [OSTI]

    Long, Bernard

    , Ilopango Caldera, El Salvador, Central America, in Rose, W.I., Bommer, J.J., López, D.L., Carr, M.J., and Major, J.J., eds., Natural hazards in El Salvador: Boulder, Colorado, Geological Society of America of America Special Paper 375 2004 Subaqueous intracaldera volcanism, Ilopango Caldera, El Salvador, Central

  5. Cleavage of nucleic acids

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Waunakee, WI); Lyamichev, Victor I. (Madison, WI); Brow; Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

    2010-11-09T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  6. Cleavage of nucleic acids

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor L. (Madison, WI); Brow, Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

    2007-12-11T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  7. Nucleic acid detection compositions

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor I. (Madison, WI); Brow, Mary Ann (Madison, WI); Dahlberg, James L. (Madison, WI)

    2008-08-05T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  8. Process for the preparation of lactic acid and glyceric acid

    DOE Patents [OSTI]

    Jackson, James E [Haslett, MI; Miller, Dennis J [Okemos, MI; Marincean, Simona [Dewitt, MI

    2008-12-02T23:59:59.000Z

    Hexose and pentose monosaccharides are degraded to lactic acid and glyceric acid in an aqueous solution in the presence of an excess of a strongly anionic exchange resin, such as AMBERLITE IRN78 and AMBERLITE IRA400. The glyceric acid and lactic acid can be separated from the aqueous solution. Lactic acid and glyceric acid are staple articles of commerce.

  9. STANDARD OPERATING PROCEDURE ACIDS CONTAINING PHOSPHOROUS

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    12.1 STANDARD OPERATING PROCEDURE for ACIDS CONTAINING PHOSPHOROUS Location(s): ___________________________________________________ Chemical(s): Hypophosphorous acid, methylphosphonic acid, phosphonic acid, phosphoric acid, phosphorous

  10. Microorganisms for producing organic acids

    DOE Patents [OSTI]

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-09-30T23:59:59.000Z

    Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

  11. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

  12. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31T23:59:59.000Z

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  13. EMSL - Nuclei acid structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions showed a temporary pH decrease, with a concomitant increase in formic acid during exponential growth. Fermentation experiments performed outside of the magnet...

  14. Nuclei acid structure | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions showed a temporary pH decrease, with a concomitant increase in formic acid during exponential growth. Fermentation experiments performed outside of the magnet...

  15. Controlling acid rain

    E-Print Network [OSTI]

    Fay, James A.

    1983-01-01T23:59:59.000Z

    High concentrations of sulfuric and nitric acid in raTn fn the northeastern USA are caused by the large scale combustion of fossil fuels within this region. Average precipitation acidity is pH 4.2, but spatial and temporal ...

  16. Microsoft Word - mitchell-dl.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA Trimodal SizePreliminaryTypes

  17. (Acid rain workshop)

    SciTech Connect (OSTI)

    Turner, R.S.

    1990-12-05T23:59:59.000Z

    The traveler presented a paper entitled Susceptibility of Asian Ecosystems to Soil-Mediated Acid Rain Damage'' at the Second Workshop on Acid Rain in Asia. The workshop was organized by the Asian Institute of Technology (Bangkok, Thailand), Argonne National Laboratory (Argonne, Illinois), and Resource Management Associates (Madison, Wisconsin) and was sponsored by the US Department of Energy, the United Nations Environment Program, the United Nations Economic and Social Commission for Asia and the Pacific, and the World Bank. Papers presented on the first day discussed how the experience gained with acid rain in North America and Europe might be applied to the Asian situation. Papers describing energy use projections, sulfur emissions, and effects of acid rain in several Asian countries were presented on the second day. The remaining time was allotted to discussion, planning, and writing plans for a future research program.

  18. Fatty Acid Carcass Mapping

    E-Print Network [OSTI]

    Turk, Stacey N.

    2010-01-14T23:59:59.000Z

    FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2008... Major Subject: Animal Science FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

  19. The utilization of tricarboxylic acid cycle acids and the uptake of succinic acid by Neurospora crassa

    E-Print Network [OSTI]

    Gilliland, Patti Lynn

    2012-06-07T23:59:59.000Z

    THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1978 Ma) or Subject: Microbiology THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Approved as to style and content by...

  20. Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid

    E-Print Network [OSTI]

    Wilcock, William

    Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid Hydrofluoric acid (HF characterized by weight loss, brittle bones, anemia, and general ill health. Safe use If possible, avoid working to exposures. #12;Focus Sheet | Hydrofluoric Acid Environmental Health and Safety Environmental Programs Office

  1. Optical high acidity sensor

    DOE Patents [OSTI]

    Jorgensen, Betty S. (Jemez Springs, NM); Nekimken, Howard L. (Los Alamos, NM); Carey, W. Patrick (Lynnwood, WA); O'Rourke, Patrick E. (Martinez, GA)

    1997-01-01T23:59:59.000Z

    An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and, a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber.

  2. A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid

    SciTech Connect (OSTI)

    Arceo, Elena; Ellman, Jonathan; Bergman, Robert

    2010-05-03T23:59:59.000Z

    An alternative biomass-based route to benzoic acid from the renewable starting materials quinic acid and shikimic acid is described. Benzoic acid is obtained selectively using a highly efficient, one-step formic acid-mediated deoxygenation method.

  3. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    2003-06-24T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  4. Plant fatty acid hydroxylase

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); van de Loo, Frank (Lexington, KY)

    2000-01-01T23:59:59.000Z

    The present invention relates to the identification of nucleic acid sequences and constructs, and methods related thereto, and the use of these sequences and constructs to produce genetically modified plants for the purpose of altering the composition of plant oils, waxes and related compounds.

  5. Fatty acid-producing hosts

    DOE Patents [OSTI]

    Pfleger, Brian F; Lennen, Rebecca M

    2013-12-31T23:59:59.000Z

    Described are hosts for overproducing a fatty acid product such as a fatty acid. The hosts include an exogenous nucleic acid encoding a thioesterase and, optionally, an exogenous nucleic acid encoding an acetyl-CoA carboxylase, wherein an acyl-CoA synthetase in the hosts are functionally delected. The hosts prefereably include the nucleic acid encoding the thioesterase at an intermediate copy number. The hosts are preferably recominantly stable and growth-competent at 37.degree. C. Methods of producing a fatty acid product comprising culturing such hosts at 37.degree. C. are also described.

  6. Acidizing of Sandstone Reservoirs Using HF and Organic Acids

    E-Print Network [OSTI]

    Yang, Fei

    2012-10-19T23:59:59.000Z

    Mud acid, which is composed of HCl and HF, is commonly used to remove the formation damage in sandstone reservoirs. However, many problems are associated with HCl, especially at high temperatures. Formic-HF acids have served as an alternative...

  7. acid docosahexaenoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 38 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  8. acid aspartic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 20 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  9. acid caffeic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 11 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  10. acid succinic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulated the laser heating of the succinic acid (this data is still simulation is that infrared heating generates about 10-15 more succinic acid molecules bound to the analyte...

  11. acid benzoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 24 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  12. acid propanoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 9 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  13. acid oleic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 31 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  14. Acid Placement in Acid Jetting Treatments in Long Horizontal Wells

    E-Print Network [OSTI]

    Sasongko, Hari

    2012-07-16T23:59:59.000Z

    In the Middle East, extended reach horizontal wells (on the order of 25,000 feet of horizontal displacement) are commonly acid stimulated by jetting acid out of drill pipe. The acid is jetted onto the face of the openhole wellbore as the drill pipe...

  15. Acid placement and coverage in the acid jetting process

    E-Print Network [OSTI]

    Mikhailov, Miroslav I.

    2009-05-15T23:59:59.000Z

    Many open-hole acid treatments are being conducted by pumping acid through jetting ports placed at the end of coiled tubing or drill pipe. The filter-cake on the bore-hole is broken by the jet; the acid-soluble material is dissolved, creating...

  16. Investigating acid rain

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    A report is given of an address by Kathleen Bennett, Assistant Administrator of Air, Noise and Radiation, Environmental Protection Agency which was presented to the US Senate Committee on the Environment and Public Works. Bennet explained that in view of the many unknowns about acid rain, and the possible substantial cost burden of additional controls, EPA is proceeding with its program to investigate this environmental malady over a 10-year period. The three major areas of the research program are (1) transport, transformation, and deposition processes, (2) effects of acid deposition, and (3) assessments and policy studies. Other issues discussed were global transboundary air pollution and Senate amendments addressing long-range transport. (JMT)

  17. Pantothenic acid biosynthesis in zymomonas

    DOE Patents [OSTI]

    Tao, Luan; Tomb, Jean-Francois; Viitanen, Paul V.

    2014-07-01T23:59:59.000Z

    Zymomonas is unable to synthesize pantothenic acid and requires this essential vitamin in growth medium. Zymomonas strains transformed with an operon for expression of 2-dehydropantoate reductase and aspartate 1-decarboxylase were able to grow in medium lacking pantothenic acid. These strains may be used for ethanol production without pantothenic acid supplementation in seed culture and fermentation media.

  18. acid acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the...

  19. Acidic gas capture by diamines

    DOE Patents [OSTI]

    Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

    2011-05-10T23:59:59.000Z

    Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

  20. Carbonic Acid Pretreatment of Biomass

    SciTech Connect (OSTI)

    G. Peter van Walsum; Kemantha Jayawardhana; Damon Yourchisin; Robert McWilliams; Vanessa Castleberry

    2003-05-31T23:59:59.000Z

    This project sought to address six objectives, outlined below. The objectives were met through the completion of ten tasks. 1) Solidify the theoretical understanding of the binary CO2/H2O system at reaction temperatures and pressures. The thermodynamics of pH prediction have been improved to include a more rigorous treatment of non-ideal gas phases. However it was found that experimental attempts to confirm theoretical pH predictions were still off by a factor of about 1.8 pH units. Arrhenius experiments were carried out and the activation energy for carbonic acid appears to be substantially similar to sulfuric acid. Titration experiments have not yet confirmed or quantified the buffering or acid suppression effects of carbonic acid on biomass. 2) Modify the carbonic acid pretreatment severity function to include the effect of endogenous acid formation and carbonate buffering, if necessary. It was found that the existing severity functions serve adequately to account for endogenous acid production and carbonate effects. 3) Quantify the production of soluble carbohydrates at different reaction conditions and severity. Results show that carbonic acid has little effect on increasing soluble carbohydrate concentrations for pretreated aspen wood, compared to pretreatment with water alone. This appears to be connected to the release of endogenous acids by the substrate. A less acidic substrate such as corn stover would derive benefit from the use of carbonic acid. 4) Quantify the production of microbial inhibitors at selected reaction conditions and severity. It was found that the release of inhibitors was correlated to reaction severity and that carbonic acid did not appear to increase or decrease inhibition compared to pretreatment with water alone. 5) Assess the reactivity to enzymatic hydrolysis of material pretreated at selected reaction conditions and severity. Enzymatic hydrolysis rates increased with severity, but no advantage was detected for the use of carbonic acid compared to water alone. 6) Determine optimal conditions for carbonic acid pretreatment of aspen wood. Optimal severities appeared to be in the mid range tested. ASPEN-Plus modeling and economic analysis of the process indicate that the process could be cost competitive with sulfuric acid if the concentration of solids in the pretreatment is maintained very high (~50%). Lower solids concentrations result in larger reactors that become expensive to construct for high pressure applications.

  1. Metabolism of Thioctic Acid in Algae

    E-Print Network [OSTI]

    Grisebach, Hans; Fuller, R.C.; Calvin, M.

    1956-01-01T23:59:59.000Z

    METABOLISM OF THlOCTlC ACID IN ALGAE TWO-WEEK LOAN COPY ThisMETABOLISM OF THIOCTIC ACID IN ALGAE Hans Grisebach, R. , C.METABOLISM OF THIOCTIC ACID IN ALGAE Hans Grisebach, R. C.

  2. Solvent extraction of inorganic acids

    E-Print Network [OSTI]

    Ysrael, Miguel Curie

    1965-01-01T23:59:59.000Z

    the solution by a sim?. le process that is economically =ttrsctlve is of con- sider. ble interest~ Dilute "olution; of hydrochloric, nitric and sul- furic acid d; occur in many processes either alone or toga- th: r . 'he use of li. , uid-li~uid extraction...~~ram for hexyl c~rbitol- water-nitric acid 17 ~ Distribution die, r m for hoxl'' ca:-bitol- watcr-sulfur'c acid Table 1. . 'xperimental d ta of amyl alcohol-water-!!Cl Pa, e 33 2. Experimental data of isoamyl alcohol-water- HC1 34 3 ~ Cxperimental data...

  3. Naphthenic acid corrosion literature survey

    SciTech Connect (OSTI)

    Babaian-Kibala, E. [Nalco/Exxon Energy Chemicals, Sugar Land, TX (United States); Nugent, M.J. [Tosco Refining Co., Linden, NJ (United States)

    1999-11-01T23:59:59.000Z

    Naphthenic acid corrosion is a growing concern for refineries processing crudes containing high levels of naphthenic acid. Due to this concern initiatives in place to better understand the mechanism of corrosion for mitigating the corrosion. During the 1996 Fall Corrosion Group, organized existing literature relevant to the literature search. Committee Week, NACE International many refineries have and evaluate methods T-8 Refining Industry a task group, T-8-22, to perform a review and compilation of naphthenic acid corrosion. This paper provides a summary of the literature research.

  4. acetic acid solutions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  5. arachidonic acid activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  6. acid inertness studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  7. acid activated montmorillonite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  8. acid amide hydrolase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been studied....

  9. acid chelation phototherapeutic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  10. acid phosphatase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  11. acetic acid solution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  12. acetic acid operational: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  13. acid phosphatase activities: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  14. acid sphingomyelinase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  15. acids decreases fibrinolysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  16. arachidonic acid activates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  17. acid decarboxylase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  18. acid activates nrf2: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  19. acid processing activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  20. ascorbic acid enhances: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  1. acid cupric chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  2. In vivo incorporation of unnatural amino acids

    DOE Patents [OSTI]

    Schultz, Peter G. (La Jolla, CA); Wang, Lei (San Diego, CA); Anderson, John Christopher (San Diego, CA); Chin, Jason W. (Cambridge, GB); Liu, David R. (Lexington, MA); Magliery, Thomas J. (North Haven, CT); Meggers, Eric L. (Philadelphia, PA); Mehl, Ryan Aaron (Lancaster, PA); Pastrnak, Miro (San Diego, CA); Santoro, Stephen William (Cambridge, MA); Zhang, Zhiwen (San Diego, CA)

    2012-05-08T23:59:59.000Z

    The invention provides methods and compositions for in vivo incorporation of unnatural amino acids. Also provided are compositions including proteins with unnatural amino acids.

  3. Carbonic Acid Shows Promise in Geology, Biology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprising Secrets of Carbonic Acid Probing the Surprising Secrets of Carbonic Acid Berkeley Lab Study Holds Implications for Geological and Biological Processes October 23,...

  4. Mineralogical transformations controlling acid mine drainage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mineralogical transformations controlling acid mine drainage chemistry. Mineralogical transformations controlling acid mine drainage chemistry. Abstract: The role of Fe(III)...

  5. Seasonalepisodic control of acid deposition

    E-Print Network [OSTI]

    Fay, James A.

    1988-01-01T23:59:59.000Z

    This report contains the climatological, technical and economic factors for episodic and seasonal control of emissions in existing power plants. Analyzing a large data set of acid deposition for the years 1982-85, we find ...

  6. Asphaltene damage in matrix acidizing

    E-Print Network [OSTI]

    Hinojosa, Roberto Antonio

    2012-06-07T23:59:59.000Z

    This work addresses the problem of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the components these asphaltenes are more...

  7. Controlling acid rain : policy issues

    E-Print Network [OSTI]

    Fay, James A.

    1983-01-01T23:59:59.000Z

    The policy and regulatory ramifications of U.S. acid rain control programs are examined; particularly, the alternative of a receptor-oriented strategy as constrasted to emission-oriented proposals (e.g., the Mitchell bill) ...

  8. Nitrate and Prussic Acid Poisoning

    E-Print Network [OSTI]

    Stichler, Charles; Reagor, John C.

    2001-09-05T23:59:59.000Z

    Nitrate and prussic acid poisoning in cattle are noninfectious conditions that can kill livestock. This publication explains the causes and symptoms of these conditions as well as preventive measures and sampling and testing steps....

  9. Factors controlling naphthenic acid corrosion

    SciTech Connect (OSTI)

    Turnbull, A. [National Physical Lab., Teddington (United Kingdom); Slavcheva, E. [Bulgarian Academy of Sciences, Sofia (Bulgaria); Shone, B. [Ty Isa, Nr Mold (United Kingdom)

    1998-11-01T23:59:59.000Z

    A laboratory study was conducted to elucidate the influence of chemical and physical parameters on corrosion of type 1018 carbon steel (CS, UNS G10180) and 5% Cr-0.5% Mo steel in oils containing naphthenic acids (NAs) for application to crude oil refinery systems. Effects of test duration, temperature, and acid concentration were assessed for a range of single acids of varying carbon numbers and for NA mixtures in mineral oil (MO) and in heavy vacuum gas oil (HGVO). In addition, a limited study of the effect of hydrogen sulfide (H{sub 2}S) addition to the acid-oil mixture was conducted. Use of the total acid number (TAN) as a measure of corrosiveness of a crude oil was discredited further. For the same TAN value, molecular size and structure of the acid were shown to have an important influence. Tests conducted in HGVO showed lower corrosion rates than in MO, suggesting inhibition caused by S species in the oil or the steric hindrance of naphtheno-aromatic acids. In oil containing the mixture of NAs, the corrosion rate of type 1018 CS was lower than that for 5% Cr-0.5% Mo steel. The 0.1% H{sub 2}S that passed through the acid-oil mixtures had an inhibiting effect on corrosion. Predicting corrosiveness of a crude oil from the measurement of TAN, distribution of NA composition, and S content and form was particularly challenging. The simple tests used were informative, but further work will be required to establish a standard test method that can provide an adequate ranking of crudes.

  10. Acid sorption regeneration process using carbon dioxide

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); Husson, Scott M. (Anderson, SC)

    2001-01-01T23:59:59.000Z

    Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

  11. Succinic acid production by Anaerobiospirillum succiniciproducens

    E-Print Network [OSTI]

    , succinic acid has been produced commercially by chemical processes. Recently, however, fermentative of bacteria produce succinic acid as a fermentation end product,4 7 few species can produce it as the major 10 Previous studies showed that A. succiniciproducens produces succinic acid and acetic acid

  12. Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants

    DOE Patents [OSTI]

    Ohlrogge, John B. (Okemos, MI); Cahoon, Edgar B. (Lansing, MI); Shanklin, John (Upton, NY); Somerville, Christopher R. (Okemos, MI)

    1995-01-01T23:59:59.000Z

    The present invention relates to a process for producing lipids containing the fatty acid petroselinic acid in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a .omega.12 desaturase from another species which does normally accumulate petroselinic acid.

  13. Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants

    DOE Patents [OSTI]

    Ohlrogge, J.B.; Cahoon, E.B.; Shanklin, J.; Somerville, C.R.

    1995-07-04T23:59:59.000Z

    The present invention relates to a process for producing lipids containing the fatty acid, petroselinic acid, in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a {omega}12 desaturase from another species which does normally accumulate petroselinic acid. 19 figs.

  14. New syntheses of aminoalkylphosphonic acids

    E-Print Network [OSTI]

    DeBardeleben, John Frederick

    2012-06-07T23:59:59.000Z

    NEW SYNTHESES OF AMINOALKYLPHOSPHON1C ACIDS A Thesis by John Frederick DeBardeleben, Jr. Su'bmitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 196$ Major Subject: Chemistry NEW SYNTHESES OF AMINOALKYLPHOSPHONIC ACIDS A Thesis BY John Frederick DeBardeleben, Jr. Approved as to style and content hy: (Chairman of Committee) iJ C wc+'. A-c-~-' & (Head of Department...

  15. Conductive polymeric compositions for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles A. (Mesa, AZ); Xu, Wu (Tempe, AZ)

    2009-03-17T23:59:59.000Z

    Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

  16. Acid Catalysis in Modern Organic

    E-Print Network [OSTI]

    Snyder, Scott A.

    catalyst for organic synthesis". That is the starting sentence of this book by Yamamoto and Ishihara, which follows their earlier book "Lewis Acids in Organic Synthesis (2000)", and covers the new developments book that should be available in every well-equipped chemistry library. It will certainly be helpful

  17. HYDROFLUORIC ACID FIRST AID INSTRUCTIONS

    E-Print Network [OSTI]

    Jalali. Bahram

    with large amounts of cool running water. Immediately washing off the acid is of primary importance. 2.Remove Immediately flush eyes for at least 15 minutes with copious cool flowing water. 2 If only one eye is affected by a glass of milk or milk of magnesia. 3 Call 911 for immediate medical assistance. REMEMBER, ALL PERSONNEL

  18. E-Print Network 3.0 - acid acetylsalicylic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  19. E-Print Network 3.0 - acid methoxyacetic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  20. E-Print Network 3.0 - acidic alpha-amino acids Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  1. E-Print Network 3.0 - acid sorbic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  2. E-Print Network 3.0 - acid dichloroacetic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  3. E-Print Network 3.0 - acid n-glycolylneuraminic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acids are kept in storage cabinets under the fume hood... in the plastic box. 3. Place filters in hood, add 50% (approximate concentration) HCl acid (Fisher, certified ACS......

  4. E-Print Network 3.0 - acids organic acids Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the decomposition of organic material, is the primary source of acidity in unpolluted rainwater. NOTE: Parts per... A ACID RAIN Audrey Gibson ATOC 3500 Thursday, April ......

  5. E-Print Network 3.0 - acid propionic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Explorit Topic List Advanced Search Sample search results for: acid propionic acid Page: << < 1 2 3 4 5 > >> 1 Biodegradation 9: 463473, 1998. 1998 Kluwer Academic...

  6. E-Print Network 3.0 - acid linoleic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FAs (linolenic, linoleic) - - monounsaturated FAs (oleic acid) - olive, canola - hydrogenation... Biol 458 Lecture 6 & 7 Fatty Acids 1 A. Introduction to acyl lipids...

  7. Modeling of Acid Fracturing in Carbonate Reservoirs

    E-Print Network [OSTI]

    Al Jawad, Murtada s

    2014-06-05T23:59:59.000Z

    The acid fracturing process is a thermal, hydraulic, mechanical, and geochemical (THMG)-coupled phenomena in which the behavior of these variables are interrelated. To model the flow behavior of an acid into a fracture, mass and momentum balance...

  8. acidization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  9. Fuel cell electrolyte membrane with acidic polymer

    DOE Patents [OSTI]

    Hamrock, Steven J. (Stillwater, MN); Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

    2009-04-14T23:59:59.000Z

    An electrolyte membrane is formed by an acidic polymer and a low-volatility acid that is fluorinated, substantially free of basic groups, and is either oligomeric or non-polymeric.

  10. Recovery of mercury from acid waste residues

    DOE Patents [OSTI]

    Greenhalgh, W.O.

    1987-02-27T23:59:59.000Z

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

  11. Recovery of mercury from acid waste residues

    DOE Patents [OSTI]

    Greenhalgh, Wilbur O. (Richland, WA)

    1989-01-01T23:59:59.000Z

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

  12. amino acid intake: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    protein intake (PDI) and net portal appearance rate of amino acids by continuous infusion of para-aminohippuric acid via the mesenteric catheter. The amino-acid appearance...

  13. Reactions Between Water Soluble Organic Acids and Nitrates in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactions Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Reactions Between Water Soluble Organic Acids and...

  14. acid synthase impacts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid utilization and glucose oxidation. Glucose... Adhikari, Sean 2006-10-30 246 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  15. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

    2014-08-26T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  16. Organic Acid Production by Filamentous Fungi

    E-Print Network [OSTI]

    -being. Indeed, organic acid fermentations are often not even identified as fungal bioprocesses, having been Aspergillus niger in aerated stirred-tank-reactors can convert glucose to citric acid with greater than 80 lipolytica, and related yeast species, may be in use commercially to produce citric acid (Lopez-Garcia, 2002

  17. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander (La Jolla, CA); Cropp, T. Ashton (Bethesda, MD); Chin, Jason W. (Cambridge, GB); Anderson, J. Christopher (San Francisco, CA); Schultz, Peter G. (La Jolla, CA)

    2011-08-09T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNAsyn-thetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  18. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, Ashton T; Chin, Jason W; Anderson, Christopher J; Schultz, Peter G

    2013-05-21T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  19. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, L.

    1999-05-25T23:59:59.000Z

    A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  20. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    1999-01-01T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinic acid comprising: dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures thereof to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing said alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  1. ARM - Lesson Plans: Acid Rain

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearch Related InformationAcid Rain Outreach Home Room News

  2. Thermal Stability Of Formohydroxamic Acid

    SciTech Connect (OSTI)

    Fondeur, F. F.; Rudisill, T. S.

    2011-10-21T23:59:59.000Z

    The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

  3. CHAPTER 13. ACID RAIN Acid rain was discovered in the 19th century by Robert Angus

    E-Print Network [OSTI]

    Jacob, Daniel J.

    247 CHAPTER 13. ACID RAIN Acid rain was discovered in the 19th century by Robert Angus Smith, a pharmacist from Manchester (England), who measured high levels of acidity in rain falling over industrial decline of fish populations in the lakes of southern Norway and traced the problem to acid rain. Similar

  4. Fate of Acids in Clouds 1. Combination with bases dissolved in clouds: acids neutralized

    E-Print Network [OSTI]

    Schofield, Jeremy

    problems. E#11;ects of Acid Rain 1. Vegetation: SO 2 is toxic to plants #15; Leaves damaged below pH 3 rain { Athens and Rome cathedrals and statues: pollution leads to acid rain #15; SteelFate of Acids in Clouds 1. Combination with bases dissolved in clouds: acids neutralized NH 3 (g

  5. Radioiodinated fatty acid analogs for myocardial imaging

    SciTech Connect (OSTI)

    Ruyan, M.K.

    1993-01-01T23:59:59.000Z

    Fatty acids are the preferred substrate for the normoxic heart. About sixty percent of the energy required by the myocardium is provided by fatty acid [beta]-oxidation. Many scientists have focused on the alterations in fatty acid metabolism in the ischemic heart for the development of radiolabelled fatty acids for functional imaging of the heart. Three main categories of compounds were synthesized: tetrazoles (1 and 2), glycidic and [alpha]-methylene acids (3-5), and analogs of oleic acid (6,7 and 7A). The tetrazole group has a similar pKa and size to that of a carboxyl group; however, such fatty acid analogs cannot undergo normal fatty acid metabolism. Glycidic and [alpha]-methylene analogs are potential irreversible inhibitors of fatty acid metabolism. Oleic acid analogs were investigated to assess the affect of stereochemical consequences on biodistribution. The key intermediates in the synthesis of the target compounds were [omega]-nitrophenyl alkylcarboxylic acids and alcohols, which were made using a variety of cross-coupling reactions. The Wittig reaction, which was used in the synthesis of tetrazole 1 and glycidic acid 3, gave low yields of the cross-coupled products. The remaining target compounds were synthesized by condensation of appropriate RCu (CN) ZnI and substituted benzyl bromides or by Pd[sup II] catalyzed cross-coupling of substituted arylhalides with suitable alkynes. The latter two reactions produced much higher yields of the desired products. All of the target compounds were radiolabeled with [sup 125]I by various Cu(I) catalyzed radioiodine exchange procedures and were then subjected to tissue biodistribution (TD) studies in rats. Except for the 15-(4-iodophenyl)-2-methylene-pentadecanoic acid (5), all of the fatty acid analogs failed to surpass clinically-used 15-(4-iodophenyl)pentadecanoic acid (IPPA) in their ability to be taken up and retained by the rat myocardium.

  6. DL)TTCS^^r^i^ Ris Re Probabilistic Assessment

    E-Print Network [OSTI]

    the evaluation of irradiation experiments, design comparisons, and analyse of minor accidents. INIS Descriptors

  7. Distinguished Lecture Series Professor Deborah D.L. Chung

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    102D, Engineering Bldg. 1, UH Abstract Polymer-matrix composites containing a high proportion. The energy conversion allows the structure to be self-powered. The heat dissipation is important due to the increasing thermal load of aircraft. The monitoring is needed for structural health monitoring, load

  8. DL-940 1/08 Animal Health Diagnostic Center

    E-Print Network [OSTI]

    Keinan, Alon

    These are instructions for collecting specimens for Campylobacter fetus culture fluorescent antibody and Tritrichomonas with protective sheath 5. Sterile rubber bulb (return to lab for credit to your account) Needed but not supplied by the AHDC 6. Syringe (3cc) and needle Procedures 1. Attach rubber bulb to collection catheter 2

  9. (continued) DL-943 8/12 Animal Health Diagnostic Center

    E-Print Network [OSTI]

    Keinan, Alon

    herds. The cost is $18 for out-of-state herds. Samples must be submitted through a licensed veterinarian. How will results be reported? Results will be reported through the normal channel to the veterinarian://diagcenter.vet.cornell.edu/dlaccess/login.asp What is the lag time? Results will normally be available 7-10 business days after the AHDC receives

  10. SSC-DL Version 1.0 SIRTF Science Center

    E-Print Network [OSTI]

    Masci, Frank

    -SED 6741 Code walk-through fixes/updates to "LoadIrsaPtgMetaData" perl subroutine. 6735 New module-masked pixels are NaN'd in final mips24 BCD products.. 6710 Update GenSBPHFsForCampaign.pl following comments from code walk-thru.. 6679 Update w_po

  11. 18 Modeling high-performance HBTs D.L. Pulfrey

    E-Print Network [OSTI]

    Pulfrey, David L.

    an acceptable base resistance. A short base width leads directly to an improved cut-off frequency, fT , which, when coupled with the lower base resistance, leads to an improved oscillation frequency, fmax. These consideration is also given to the incorporation of the compact model for JC into a large-signal equivalent

  12. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-12-21T23:59:59.000Z

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  13. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-08-17T23:59:59.000Z

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  14. acid bacteria isolates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acids are solids not liquids. They sublime under vacuum to compare the strengths of solid acids with liquid acids therefore led us to obtain a measure of acidity in dilute...

  15. acid bacteria isolated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acids are solids not liquids. They sublime under vacuum to compare the strengths of solid acids with liquid acids therefore led us to obtain a measure of acidity in dilute...

  16. Double stranded nucleic acid biochips

    DOE Patents [OSTI]

    Chernov, Boris; Golova, Julia

    2006-05-23T23:59:59.000Z

    This invention describes a new method of constructing double-stranded DNA (dsDNA) microarrays based on the use of pre-synthesized or natural DNA duplexes without a stem-loop structure. The complementary oligonucleotide chains are bonded together by a novel connector that includes a linker for immobilization on a matrix. A non-enzymatic method for synthesizing double-stranded nucleic acids with this novel connector enables the construction of inexpensive and robust dsDNA/dsRNA microarrays. DNA-DNA and DNA-protein interactions are investigated using the microarrays.

  17. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, C.R.; Niemeyer, C.M.; Smith, C.L.; Sano, Takeshi; Hnatowich, D.J.; Rusckowski, M.

    1996-10-01T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products. 5 figs.

  18. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

    1999-10-12T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

  19. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

    1996-01-01T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

  20. Testing of organic acids in engine coolants

    SciTech Connect (OSTI)

    Weir, T.W. [ARCO Chemical Co., Newtown Square, PA (United States)

    1999-08-01T23:59:59.000Z

    The effectiveness of 30 organic acids as inhibitors in engine coolants is reported. Tests include glassware corrosion of coupled and uncoupled metals. FORD galvanostatic and cyclic polarization electrochemistry for aluminum pitting, and reserve alkalinity (RA) measurements. Details of each test are discussed as well as some general conclusions. For example, benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In general, the organic acids provide little RA when titrated to a pH of 5.5, titration to a pH of 4.5 can result in precipitation of the acid. Trends with respect to acid chain length are reported also.

  1. Carboxylic acid accelerated formation of diesters

    DOE Patents [OSTI]

    Tustin, G.C.; Dickson, T.J.

    1998-04-28T23:59:59.000Z

    This invention pertains to accelerating the rate of formation of 1,1-dicarboxylic esters from the reaction of an aldehyde with a carboxylic acid anhydride or a ketene in the presence of a non-iodide containing a strong Bronsted acid catalyst by the addition of a carboxylic acid at about one bar pressure and between about 0 and 80 C in the substantial absence of a hydrogenation or carbonylation catalyst.

  2. Organic Phosphoric Acid of the Soil.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1911-01-01T23:59:59.000Z

    TEXAS AGRICULTURAL EXPERIMENT STATIONS BULLETIN NO. +6CT /36 CHEMICAL SECTION, FEBRUARY, 191 1 I TECHNICAL BULLETIN Organic Phosphoric Acid of the Soil BY G. S. FRAPS, Chemist POSTOFFICE College Station, Brazos County, 'Texas. ,\\ustin... . ................................................ introduction 5 .............................. hmmonia-Soluble Phosphoric Acid 5 ................ Solubility of Phosphates in Ammonia 6 I Fixation of Phosphoric Acid from Ammonia .......... 7 Effect of Ratio of Soil to Solvent in Extraction of Phos- I I...

  3. Acid rain information book. Draft final report

    SciTech Connect (OSTI)

    None

    1980-12-01T23:59:59.000Z

    Acid rain is one of the most widely publicized environmental issues of the day. The potential consequences of increasingly widespread acid rain demand that this phenomenon be carefully evaluated. Reveiw of the literature shows a rapidly growing body of knowledge, but also reveals major gaps in understanding that need to be narrowed. This document discusses major aspects of the acid rain phenomenon, points out areas of uncertainty, and summarizes current and projected research by responsible government agencies and other concerned organizations.

  4. Carboxylic acid accelerated formation of diesters

    DOE Patents [OSTI]

    Tustin, Gerald Charles (Kingsport, TN); Dickson, Todd Jay (Kingsport, TN)

    1998-01-01T23:59:59.000Z

    This invention pertains to accelerating the rate of formation of 1,1-dicarboxylic esters from the reaction of an aldehyde with a carboxylic acid anhydride or a ketene in the presence of a non-iodide containing a strong Bronsted acid catalyst by the addition of a carboxylic acid at about one bar pressure and between about 0.degree. and 80.degree. C. in the substantial absence of a hydrogenation or carbonylation catalyst.

  5. Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part I. Regeneration of Amine-Carboxylic Acid Extracts

    E-Print Network [OSTI]

    Poole, L.J.

    2008-01-01T23:59:59.000Z

    production of citric acid by fermentation, recovery of theof Citric Acid from Aqueous Fermentation Solutions byof citric acid was 1.1.1 Lactic Acid Currently, fermentation

  6. Acid Doped Membranes for High Temperature PEMFC

    Broader source: Energy.gov [DOE]

    Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  7. Organic acid-tolerant microorganisms and uses thereof for producing organic acids

    DOE Patents [OSTI]

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-05-06T23:59:59.000Z

    Organic acid-tolerant microorganisms and methods of using same. The organic acid-tolerant microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid (3HP), acrylic acid, and propionic acid. Further modifications to the microorganisms such as increasing expression of malonyl-CoA reductase and/or acetyl-CoA carboxylase provide or increase the ability of the microorganisms to produce 3HP. Methods of generating an organic acid with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers include replacing acsA or homologs thereof in cells with genes of interest and selecting for the cells comprising the genes of interest with amounts of organic acids effective to inhibit growth of cells harboring acsA or the homologs.

  8. E-Print Network 3.0 - acid eicosapentaenoic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sample search results for: acid eicosapentaenoic acid Page: << < 1 2 3 4 5 > >> 1 Fish or Fish Oil in the Diet and Heart Attacks MAURICE E. STANSBY Summary: . Further...

  9. E-Print Network 3.0 - acids eicosapentaenoic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sample search results for: acids eicosapentaenoic acid Page: << < 1 2 3 4 5 > >> 1 Fish or Fish Oil in the Diet and Heart Attacks MAURICE E. STANSBY Summary: . Further...

  10. 2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with...

    Broader source: Energy.gov (indexed) [DOE]

    2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with Frozen-in Free Volume for use in High Temperature Fuel Cells 2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic...

  11. 2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with...

    Broader source: Energy.gov (indexed) [DOE]

    Poly(p-phenylene Sulfonic Acid)s with Frozen-in Free Volume for use in High Temperature Fuel Cells Morton Litt and Peter Pintauro Case Western Reserve University Cleveland, Ohio...

  12. acid-dependent ribonucleic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 40 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  13. Decomposition Studies of Triphenylboron, Diphenylborinic Acid and Phenylboric Acid in Aqueous Alkaline Solutions Containing Copper

    SciTech Connect (OSTI)

    Crawford, C.L. [Westinghouse Savannah River Company, AIKEN, SC (United States); Peterson, R. A.

    1997-02-11T23:59:59.000Z

    This report documents the copper-catalyzed chemical kinetics of triphenylboron, diphenylborinic acid and phenylboric acid (3PB, 2PB and PBA) in aqueous alkaline solution contained in carbon-steel vessels between 40 and 70 degrees C.

  14. BNL Citric Acid Technology: Pilot Scale Demonstration

    SciTech Connect (OSTI)

    FRANCIS, A J; DODGE,; J, C; GILLOW, J B; FORRESTER, K E

    1999-09-24T23:59:59.000Z

    The objective of this project is to remove toxic metals such as lead and cadmium from incinerator ash using the Citric Acid Process developed at Brookhaven National Laboratory. In this process toxic metals in bottom ash from the incineration of municipal solid waste were first extracted with citric acid followed by biodegradation of the citric acid-metal extract by the bacterium Pseudomonas fluorescens for metals recovery. The ash contained the following metals: Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Se, Sr, Ti, and Zn. Optimization of the Citric Acid Process parameters which included citric acid molarity, contact time, the impact of mixing aggressiveness during extraction and pretreatment showed lead and cadmium removal from incinerator ash of >90%. Seeding the treated ash with P. fluorescens resulted in the removal of residual citric acid and biostabilization of any leachable lead, thus allowing it to pass EPA?s Toxicity Characteristic Leaching Procedure. Biodegradation of the citric acid extract removed >99% of the lead from the extract as well as other metals such as Al, Ca, Cu, Fe, Mg, Mn, Ti, and Zn. Speciation of the bioprecipitated lead by Extended X-ray Absorption Fine Structure at the National Synchrotron Light Source showed that the lead is predominantly associated with the phosphate and carboxyl functional groups in a stable form. Citric acid was completely recovered (>99%) from the extract by sulfide precipitation technique and the extraction efficiency of recovered citric acid is similar to that of the fresh citric acid. Recycling of the citric acid should result in considerable savings in the overall treatment cost. We have shown the potential application of this technology to remove and recover the metal contaminants from incinerator ash as well as from other heavy metal bearing wastes (i.e., electric arc furnace dust from steel industry) or soils. Information developed from this project is being applied to demonstrate the remediation of lead paint contaminated soils on Long Island.

  15. Further Investigation of Fluoboric Acid in Sandstone Acidizing Using ^(11)B and ^(19)F NMR

    E-Print Network [OSTI]

    Pituckchon, Arpajit

    2014-05-01T23:59:59.000Z

    Although fluoboric acid (HBF_(4)) has long been known as one of the low-damaging acid treatments for clayey sandstone formations, little is known of its chemistry which could explain the mixed results of fluoboric acid in actual field application. A...

  16. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-10-29T23:59:59.000Z

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  17. Electrostatic precipitation of condensed acid mist

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    This project addresses the acid mist that is formed by condensation of sulfuric acid vapor in flue gas from coal-fired utility boilers. An acid mist can be formed whenever the flue gas temperature approaches the prevailing acid dew point. This commonly occurs when the gas is subjected to rapid adiabatic cooling in a wet scrubber system for flue gas desulfurization. Acid mists can also sometimes result from unexpected temperature excursions caused by air inleakage, load cycling, and start-up operations. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attach glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. Therefore, this program has been structured around the use of a compact, wet ESP to control acid mist emissions. Progress to date is discussed. 7 refs., 1 fig.

  18. Electrostatic precipitation of condensed acid mist

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    This project addresses the acid mist that is formed by condensation of sulfuric acid vapor in flue gas from coal-fired utility boilers. An acid mist can be formed whenever the flue gas temperature approaches the prevailing acid dew point. This commonly occurs when the gas is subjected to rapid adiabatic cooling in a wet scrubber system for flue gas desulfurization. Acid mists can also sometimes result from unexpected temperature excursions caused by air inleakage, load cycling, and start-up operations. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attack glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. Therefore, this program has been structured around the use of a compact, wet ESP to control acid mist emissions. 7 refs.

  19. Nanoparticles modified with multiple organic acids

    DOE Patents [OSTI]

    Cook, Ronald Lee (Lakewood, CO); Luebben, Silvia DeVito (Golden, CO); Myers, Andrew William (Arvada, CO); Smith, Bryan Matthew (Boulder, CO); Elliott, Brian John (Superior, CO); Kreutzer, Cory (Brighton, CO); Wilson, Carolina (Arvada, CO); Meiser, Manfred (Aurora, CO)

    2007-07-17T23:59:59.000Z

    Surface-modified nanoparticles of boehmite, and methods for preparing the same. Aluminum oxyhydroxide nanoparticles are surface modified by reaction with selected amounts of organic acids. In particular, the nanoparticle surface is modified by reactions with two or more different carboxylic acids, at least one of which is an organic carboxylic acid. The product is a surface modified boehmite nanoparticle that has an inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core and a surface-bonded organic shell. Organic carboxylic acids of this invention contain at least one carboxylic acid group and one carbon-hydrogen bond. One embodiment of this invention provides boehmite nanoparticles that have been surface modified with two or more acids one of which additional carries at least one reactive functional group. Another embodiment of this invention provides boehmite nanoparticles that have been surface modified with multiple acids one of which has molecular weight or average molecular weight greater than or equal to 500 Daltons. Yet, another embodiment of this invention provides boehmite nanoparticles that are surface modified with two or more acids one of which is hydrophobic in nature and has solubility in water of less than 15 by weight. The products of the methods of this invention have specific useful properties when used in mixture with liquids, as filler in solids, or as stand-alone entities.

  20. Nitrates and Prussic Acid in Forages

    E-Print Network [OSTI]

    Provin, Tony; Pitt, John L.

    2003-01-06T23:59:59.000Z

    When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

  1. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, M.M.; Shoup, T.

    1998-10-06T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

  2. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, M.M.; Shoup, T.

    1998-09-15T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

  3. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

    1998-09-15T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is .sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

  4. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

    1998-10-06T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is .sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

  5. Naphthenic acid corrosion by Venezuelan crudes

    SciTech Connect (OSTI)

    Hopkinson, B.E.; Penuela, L.E. [Lagoven, S.A., Judibana (Venezuela). Amuay Refinery

    1997-09-01T23:59:59.000Z

    Venezuelan crudes can contain levels of naphthenic acids that cause corrosion in distillation units designed for sweet crudes. This naphthenic acid corrosion can be mitigated in several ways, the most common of which is selective alloying. This paper will provide information from field experience on how various refineries worldwide have upgraded materials to run Venezuelan crudes in a cost effective way.

  6. Naphthenic acid corrosion in crude distillation units

    SciTech Connect (OSTI)

    Piehl, R.L.

    1988-01-01T23:59:59.000Z

    This paper summarizes corrosion experience in crude distillation units processing highly naphthenic California crude oils. Correlations have been developed relating corrosion rates to temperature and total acid number. There is a threshold acid number in the range of 1.5 to 2 mg KOH/g below which corrosion is minimal. High concentrations of hydrogen sulfide may raise this threshold value.

  7. Metabolic Flux Analysis for Succinic Acid Production by Recombinant Escherichia

    E-Print Network [OSTI]

    ; Samuelov et al., 1991). Escherichia coli produces several metabolic products by fermentation: acetic acid the final succinic acid concentration obtained was 9.5 g/L and the ratio of succinic acid to acetic acid being expended on the production of succinic acid by microbial fermentation using renewable feedstocks

  8. Surfactant Screening to Alter the Wettability and Aid in Acidizing Carbonate Formations

    E-Print Network [OSTI]

    Yadhalli Shivaprasad, Arun Kumar

    2013-02-26T23:59:59.000Z

    , known as high temperature organic acids (HTO acids), have been found to be useful in acidizing subterranean formations at temperatures up to 400oF. Some of these acids are oxalic acid, malonic acid, pimelic acid, succinic acid, glutaric acid, adipic... acid and their mixtures. In addition to creating wormholes in carbonate formations, HTO acids can remove carbonate scale at high temperatures and cause very low corrosion to the tubing and casing. 6 1.2 Role of Surfactants in Acidizing 1...

  9. Difunctional carboxylic acid anions in oilfield waters

    SciTech Connect (OSTI)

    MacGowan, D.B.; Surdam, R.C.

    1988-01-01T23:59:59.000Z

    Recent models of porosity enhancement during sandstone diagenesis have called upon the metal complexing ability of difunctional carboxylic acid anions in subsurface waters to explain aluminosilicate dissolution. Although carboxylic acid anions have been known to exist in oilfield waters since the turn of the century, until now the existence of significant concentrations of difunctional carboxylic acid anions has not been documented. Data from this study show that difunctional carboxylic acid anions can exist in concentrations up to 2640 ppm, and can account for nearly 100% of the organic acid anions in some oilfield waters. Formation water samples with exceptionally high concentrations of difunctional carboxylic acid anions are found in reservoirs which are at maximum levels of thermal exposure, and which are presently in the 80-100/sup 0/C thermal window. Plagioclase dissolution experiments performed with natural oilfield waters and artificial solutions indicate that waters with high difunctional acid anion concentrations are capable, by organo-metallic complexation, of being apparently oversaturated with respect to total aluminum concentrations compared to the inorganic solubility of kaolinite by several orders of magnitude. Dissolution experiments simulating a specific geologic environment (Stevens Sandstone, southern San Joaquin Basin, California; using natural oilfield waters and Stevens Sandstone core samples), produced plagioclase and calcite dissolution textures similar to those noted in well cores from the Stevens Sandstone, as well as raising total aluminum concentrations in these experimental solutions several orders of magnitude over the solubility of kaolinite.

  10. Experimental Study of Acid Fracture Conductivity of Austin Chalk Formation

    E-Print Network [OSTI]

    Nino Penaloza, Andrea

    2013-05-01T23:59:59.000Z

    Acid fracture conductivity and the effect of key variables in the etching process during acid fracturing can be assessed at the laboratory scale. This is accomplished by using an experimental apparatus that simulates acid injection fluxes comparable...

  11. Experimental High Velocity Acid Jetting in Limestone Carbonates

    E-Print Network [OSTI]

    Holland, Christopher

    2014-04-30T23:59:59.000Z

    Acid jetting is a well stimulation technique that is used in carbonate reservoirs. It typically involves injecting acid down hole at high flow rates through small orifices which cause high velocities of acid to strike the borehole wall...

  12. acid-base imbalance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid generates a material (PE-C02H Deutch, John 59 Acid-Based Synthesis of Monodisperse Rare-Earth-Doped Colloidal SiO2 Spheres Materials Science Websites Summary: Acid-Based...

  13. aqueous tartaric acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with limited success.2,3 During the last decade, attention to sulfuric acid anodizing and boric-sulfuric acid Paris-Sud XI, Universit de 255 Si isotope systematics of acidic...

  14. Production of Succinic Acid for Lignocellulosic Hydrolysates

    SciTech Connect (OSTI)

    Davison, B.H.; Nghiem, J.

    2002-06-01T23:59:59.000Z

    The purpose of this Cooperative Research and Development Agreement (CRADA) is to add and test new metabolic activities to existing microbial catalysts for the production of succinic acid from renewables. In particular, they seek to add to the existing organism the ability to utilize xylose efficiently and simultaneously with glucose in mixtures of sugars or to add succinic acid production to another strain and to test the value of this new capability for production of succinic acid from industrial lignocellulosic hydrolyasates. The Contractors and Participant are hereinafter jointly referred to as the 'Parties'. Research to date in succinic acid fermentation, separation and genetic engineering has resulted in a potentially economical process based on the use of an Escherichia coli strain AFP111 with suitable characteristics for the production of succinic acid from glucose. Economic analysis has shown that higher value commodity chemicals can be economically produced from succinic acid based on repliminary laboratory findings and predicted catalytic parameters. The initial target markets include succinic acid itself, succinate salts, esters and other derivatives for use as deicers, solvents and acidulants. The other commodity products from the succinic acid platform include 1,4-butanediol, {gamma}-butyrolactone, 2-pyrrolidinone and N-methyl pyrrolidinone. Current economic analyses indicate that this platform is competitive with existing petrochemical routes, especially for the succinic acid and derivatives. The report presents the planned CRADA objectives followed by the results. The results section has a combined biocatalysis and fermentation section and a commercialization section. This is a nonproprietary report; additional proprietary information may be made available subject to acceptance of the appropriate proprietary information agreements.

  15. Naphthenic acid corrosion in refinery settings

    SciTech Connect (OSTI)

    Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States)); Craig, H.L. Jr. (Mobil Research and Development Corp., Paulsboro, NJ (United States)); Rusk, G.L. (Mobil Oil Co., Torrance, CA (United States)); Blanchard, K.V.; Rose, T.J.; Uehlein, B.L. (Nalco Chemical Co., Paulsboro, NJ (United States)); Quinter, R.C. (Sun Co., Newtown Square, PA (United States)); Summers, M.A. (Sun Co., Marcus Hook, PA (United States))

    1993-04-01T23:59:59.000Z

    Naphthenic acid corrosion has been a problem in the refining industry for many years. Recently interest in this problem has grown because crudes that contain naphthenic acid are being recovered from areas which were not known to produce this type of crude, such as china, India, and Africa. New techniques for identifying naphthenic acid corrosion and chemical treatments for preventing this attack are presented. Refinery case studies include stream analysis, failure analysis, and inhibitor use. Laboratory tests to show the effect of hydrogen sulfide and phosphorus-based inhibitors are discussed.

  16. E-Print Network 3.0 - acid rain compliance Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produces salt and water. 2. Acid rain... is rain that is slightly acidic due to pollution in the air. Acid rain greatly affects the ecosystems... is acid ... Source:...

  17. E-Print Network 3.0 - acidic potassium permanganate Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State University General Guidelines Summary: acid Aminoalkanoic acids with 6 or fewer carbon atoms and the ammonium, sodium and potassium salts... of these acids. Amino acids...

  18. Experimental Investigation for the Effects of the Core Geometry on the Optimum Acid Flux in Carbonate Acidizing

    E-Print Network [OSTI]

    Jin, Xiao

    2013-11-21T23:59:59.000Z

    Previous matrix acidizing experimental research showed that there exists an optimum acid interstitial velocity (Vi-opt) that results in the minimum volume of acid used while providing the best stimulation results. There are already several...

  19. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

  20. Characterizing Surface Acidic Sites in Mesoporous-Silica-Supported...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Acidic Sites in Mesoporous-Silica-Supported Tungsten Oxide Catalysts Using Solid State NMR and Quantum Characterizing Surface Acidic Sites in Mesoporous-Silica-Supported...

  1. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

  2. amino acid pattern: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  3. amino acid selective: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  4. amino acid selection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  5. amino acid mutations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  6. amino acid recognition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  7. amino acid insertion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their distribution in known structures with experimental data such as amino acid transfer free energy scales (water to membrane center and water Senes, Alessandro 2 Amino Acid...

  8. Selective Removal of Lanthanides from Natural Waters, Acidic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Selective Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Abstract: The...

  9. adenylic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    preservation A Rauramaa A Tommila J Ltd, Espoo Reseach Centre, PO Box 44, 02271 Espoo, Finland Formic acid is known to improve silage hygienic quality. Formic acid based...

  10. acid rain program: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    preservation A Rauramaa A Tommila J Ltd, Espoo Reseach Centre, PO Box 44, 02271 Espoo, Finland Formic acid is known to improve silage hygienic quality. Formic acid based...

  11. Formation of iron complexs from trifluoroacetic acid based liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

  12. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

  13. Membrane Stresses Induced by Overproduction of Free Fatty Acids...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Membrane Stresses Induced by Overproduction of Free Fatty Acids in Escherichia coli. Membrane Stresses Induced by Overproduction of Free Fatty Acids in Escherichia coli. Abstract:...

  14. Electrodeposition From Acidic Solutions of Nickel Bis(benzenedithiolat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni-S Film on Glassy Carbon Electrodeposition From Acidic Solutions of Nickel...

  15. acid bacteria inducing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  16. acid bacteria enhance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de 4 The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Environmental Sciences and Ecology Websites Summary: The Fate of Amino Acid in...

  17. acid biosynthesis revealed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  18. acid biosynthesis inhibitors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  19. abscisic acid biosynthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  20. aspartic acid racemization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rate of racemization for amino acids preserved in planktonic foraminifera climate change. Keywords: amino acid racemization, Quaternary geochronology, Arctic Ocean, planktonic...

  1. acid neutralization capacity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID...

  2. acid neutralizing capacity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID...

  3. acid levels metabolic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  4. acid function biosynthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  5. acid biosynthesis leads: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  6. acid biosynthesis synthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  7. acid biosynthesis genes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  8. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion...

  9. Effects of Continuous Triiodothyronine Infusion on Citric Acid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Continuous Triiodothyronine Infusion on Citric Acid Cycle in the Normal Immature Swine Heart under Extracorporeal Effects of Continuous Triiodothyronine Infusion on Citric Acid...

  10. Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid Hydrolysis. Abstract: Cotton linters were partially hydrolyzed in dilute acid and the morphology of remaining...

  11. acid adenine dinucleotide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theoretical Determination of One-Electron Oxidation Potentials for Nucleic Acid Bases Brian T potentials for N-methyl substituted nucleic acid bases guanine, adenine, cytosine,...

  12. acid increases expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that are especially sensitive to increasing nutrient Gotelli, Nicholas J. 378 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  13. acid isopropyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 192 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  14. acid vinyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 280 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  15. acid inhibits production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Animals excrete three main nitrogen products, ammonia, urea and uric acid (Fig. 1), as well as some and amino acids. The term ammonia...

  16. acid monoethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  17. acid copolymeric hydrogels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 278 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  18. acid hydrolysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 213 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  19. acid synthase type: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 328 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  20. acid ester prodrugs: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 194 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  1. acid allyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 239 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  2. acid phenylethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  3. acrylic acid esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 242 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  4. acid dimethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 227 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  5. acid decarboxylase expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the expressions. Anna Sthl; Petra Sundstrm; Kristina Hk 2005-01-01 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  6. acid phosphatase 5a: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 193 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  7. acid based hydrogels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mix of multiple different monomers. These silicone are themselves a complex mix of water, boric acid, hyaluronic acid and other constituents including surfactants suitable surface...

  8. acid propyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 191 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  9. acid phenethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 178 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  10. acid synthase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    use Rippe, Karsten 53 Z .Comparative Biochemistry and Physiology Part B 128 2001 445 450 Purification and characterization of the fatty acid Chemistry Websites Summary: fatty acid...

  11. Systems Virology Identifies a Mitochondrial Fatty Acid Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fatty Acid Oxidation Enyzme, Dodecenoyl Coenzyme A Delta Isomerase, Required for Systems Virology Identifies a Mitochondrial Fatty Acid Oxidation Enyzme, Dodecenoyl Coenzyme...

  12. Lactic acid fermentation of crude sorghum extract

    SciTech Connect (OSTI)

    Samuel, W.A.; Lee, Y.Y.; Anthony, W.B.

    1980-04-01T23:59:59.000Z

    Crude extract from sweet sorghum supplemented with vetch juice was utilized as the carbohydrate source for fermentative production of lactic acid. Fermentation of media containing 7% (w/v) total sugar was completed in 60-80 hours by Lactobacillus plantarum, product yield averaging 85%. Maximum acid production rates were dependent on pH, initial substrate distribution, and concentration, the rates varying from 2 to 5 g/liter per hour. Under limited medium supplementation the lactic acid yield was lowered to 67%. The fermented ammoniated product contained over eight times as much equivalent crude protein (N x 6.25) as the original medium. Unstructured kinetic models were developed for cell growth, lactic acid formation, and substrate consumption in batch fermentation. With the provision of experimentally determined kinetic parameters, the proposed models accurately described the fermentation process. 15 references.

  13. A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    R.G.B and J.A.E. ). Keywords: biomass carboxylic acids 10.1002/cssc.201000111 A Direct, Biomass-Based Synthesis ofaro- matic compounds from biomass resources could provide a

  14. Electrostatic control of acid mist emissions

    SciTech Connect (OSTI)

    Dahlin, R S [Southern Research Inst., Birmingham, AL (United States)] [Southern Research Inst., Birmingham, AL (United States); Brown, T D [USDOE Pittsburgh Energy Technology Center, PA (United States)] [USDOE Pittsburgh Energy Technology Center, PA (United States)

    1991-01-01T23:59:59.000Z

    This paper describes a two-phased study of the control of acid mist emissions using a compact, wet electrostatic precipitator (WESP). The goal of the study was to determine the degree of acid mist control that could be achieved when a compact WESP is used to replace or augment the mist eliminators in a flue gas desulfurization (FGD) system. Phase I of the study examined the electrical operation of a lab-scale WESP collecting an acid mist from a coal combustion pilot plant equipped with a spray chamber. The results of this study were used to develop and validate a computer model of the WESP. In Phase II, measurements were made at two utility scrubber installations to determine the loadings of acid mist, fly ash, and scrubber carryover. These measurements were used as input to the model to project the performance of a retrofitted WESP.

  15. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1994-01-25T23:59:59.000Z

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 9 figures.

  16. 3D characterization of acidized fracture surfaces

    E-Print Network [OSTI]

    Malagon Nieto, Camilo

    2007-09-17T23:59:59.000Z

    generated by the profilometer identified hydrodynamic channels that could not be identified by the naked eye in acidized surfaces. The plots clarified the existence of rock heterogeneities and revealed how the processes of dissolution function in chalk rock...

  17. NH Acid Rain Control Act (New Hampshire)

    Broader source: Energy.gov [DOE]

    The Act is implemented under New Hampshire's acid deposition control program established under the Rules to Control Air Pollution in Chapter Env-A 400. The goal of the Act is to reduce emissions...

  18. Methods for analyzing nucleic acid sequences

    SciTech Connect (OSTI)

    Korlach, Jonas (Ithaca, NY); Webb, Watt W. (Ithaca, NY); Levene, Michael (Ithaca, NY); Turner, Stephen (Ithaca, NY); Craighead, Harold G. (Ithaca, NY); Foquet, Mathieu (Ithaca, NY)

    2011-05-17T23:59:59.000Z

    The present invention is directed to a method of sequencing a target nucleic acid. The method provides a complex comprising a polymerase enzyme, a target nucleic acid molecule, and a primer, wherein the complex is immobilized on a support Fluorescent label is attached to a terminal phosphate group of the nucleotide or nucleotide analog. The growing nucleic acid strand is extended by using the polymerase to add a nucleotide analog to the nucleic acid strand. The nucleotide analog added to the oligonucleotide primer as a result of the polymerizing step is identified. The time duration of the signal from labeled nucleotides or nucleotide analogs that become incorporated is distinguished from freely diffusing labels by a longer retention in the observation volume for the nucleotides or nucleotide analogs that become incorporated than for the freely diffusing labels.

  19. Long range transport of acid rain precursors

    E-Print Network [OSTI]

    Fay, James A.

    1983-01-01T23:59:59.000Z

    A model of the long range transport of primary and secondary pollutants derived by Fay and Rosenzweig (1) is applied to the problem of the transport of acid rain precursors. The model describes the long term average (annual ...

  20. Heterogeneous Reactions of Epoxides in Acidic Media

    E-Print Network [OSTI]

    Lal, Vinita

    2012-02-14T23:59:59.000Z

    Epoxides have been recently identified as one of the intermediate species in the gas phase oxidation of alkenes. This study investigates the reaction of isoprene oxide and alpha-pinene oxide with sulfuric acid to identify the potential of epoxides...

  1. Plant response to leonardite and humic acid

    E-Print Network [OSTI]

    Duval, John Robert

    1996-01-01T23:59:59.000Z

    Leonardite and humic acid have been reported to improve plant growth by many investigators in very controlled settings. The objectives of this study were twofold. First, to determine if the use of leonardite as a fertilizer supplement improved crop...

  2. NO reduction using sublimation of cyanuric acid

    DOE Patents [OSTI]

    Perry, R.A.

    1996-05-21T23:59:59.000Z

    A method of reducing the NO content of a gas stream comprises contacting the gas stream with an amount of HNCO at a temperature effective for heat-induced decomposition of cyanuric acid, said amount and temperature being effective for the resultant lowering of the NO content of the gas stream, said cyanuric acid being particulate and having a particle size of less than 90 {micro}m. 1 fig.

  3. Amplification of trace amounts of nucleic acids

    DOE Patents [OSTI]

    Church, George M. (Brookline, MA); Zhang, Kun (Brighton, MA)

    2008-06-17T23:59:59.000Z

    Methods of reducing background during amplification of small amounts of nucleic acids employ careful analysis of sources of low level contamination. Ultraviolet light can be used to reduce nucleic acid contaminants in reagents and equipment. "Primer-dimer" background can be reduced by judicious design of primers. We have shown clean signal-to-noise with as little as starting material as one single human cell (.about.6 picogram), E. coli cell (.about.5 femtogram) or Prochlorococcus cell (.about.3 femtogram).

  4. Relative reactivities of solid benzoic acids

    E-Print Network [OSTI]

    Warwas, Edwin James

    2012-06-07T23:59:59.000Z

    RELATIVE REACTIVITIES OF SOLID BENZOIC ACIDS A Thesis By EDWIN J, WARWAS Submitted to the Graduate College of the Texas A8rM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1967' Major... Subject: Chemistry RELATIVE REACTIVITIES OF SOLID BENZOIC ACIDS A Thesis By EDWIN J. WARWAS Submitted to the Graduate College of the Texas ASSAM University in partial fulfillment of the requirements for the degree of MAST ER OF S CIENCE January...

  5. Primer on lead-acid storage batteries

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    This handbook was developed to help DOE facility contractors prevent accidents caused during operation and maintenance of lead-acid storage batteries. Major types of lead-acid storage batteries are discussed as well as their operation, application, selection, maintenance, and disposal (storage, transportation, as well). Safety hazards and precautions are discussed in the section on battery maintenance. References to industry standards are included for selection, maintenance, and disposal.

  6. Elastic electron scattering from formic acid

    SciTech Connect (OSTI)

    Trevisan, Cynthia S.; Orel, Ann E.; Rescigno, Thomas N.

    2006-07-31T23:59:59.000Z

    Following our earlier study on the dynamics of low energy electron attachment to formic acid, we report the results of elastic low-energy electron collisions with formic acid. Momentum transfer and angular differential cross sections were obtained by performing fixed-nuclei calculations employing the complex Kohn variational method. We make a brief description of the technique used to account for the polar nature of this polyatomic target and compare our results with available experimental data.

  7. PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS

    E-Print Network [OSTI]

    Tan, Xuehao

    2010-01-16T23:59:59.000Z

    PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS A Thesis by XUEHAO TAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 2009 Major Subject: Petroleum Engineering PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS A Thesis by XUEHAO TAN Submitted to the Office of Graduate Studies of Texas A&M University...

  8. Biologically produced acid precipitable polymeric lignin

    DOE Patents [OSTI]

    Crawford, Don L. (Moscow, ID); Pometto, III, Anthony L. (Moscow, ID)

    1984-01-01T23:59:59.000Z

    A water soluble, acid precipitable polymeric degraded lignin (APPL), having a molecular weight of at least 12,000 daltons, and comprising, by percentage of total weight, at least three times the number of phenolic hydroxyl groups and carboxylic acid groups present in native lignin. The APPL may be modified by chemical oxidation and reduction to increase its phenolic hydroxyl content and reduce the number of its antioxidant inhibitory side chains, thereby improving antioxidant properties.

  9. Electrostatic precipitation of condensed acid mist

    SciTech Connect (OSTI)

    Dahlin, R.S.

    1989-11-01T23:59:59.000Z

    Southern Research Institute is developing a compact, wet electrostatic precipitator (WESP) to control acid mist missions from high-sulfur coal combustion. The WESP is being developed as a retrofit technology for existing coal-fired power plants, particularly those equipped with wet flue gas desulfurization (FGD) scrubbers. Acid mist emissions can be a significant problem at these facilities because the sulfuric acid vapor in the flue gas is converted to a very fine mist that is not collected in the scrubber system. Conventional mist eliminators are not adequate in this application due to the very fine size of the mist droplets. The potential for corrosion also makes it difficult to use a fabric filter or a conventional, dry ESP in this application. Therefore, this research project has been structured around the development of a compact WESP that could be retrofit on top of an existing scrubber or within an existing flue gas duct. This paper describes the development and testing of a prototype WESP for the utility acid mist application. Testing was conducted with combustion of sulfur-doped gas to simulate the acid mist alone, and with a combination of coal and sulfur-doped gas to simulate the mixture of acid mist and fly ash downstream from a scrubber. The performance of the WESP test unit was modeled using two different cylindrical-geometry computer models: a current-seeking'' model and a current-specific'' model. 8 refs., 15 figs., 7 tabs.

  10. E-Print Network 3.0 - acids amino acids Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State University Collection: Biology and Medicine 77 CHE 427627 THE ORGANIC CHEMISTRY OF BIOLOGICAL MOLECULES Summary: macromolecules: carbohydrates, amino acids, nucleic...

  11. E-Print Network 3.0 - acid amino acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State University Collection: Biology and Medicine 77 CHE 427627 THE ORGANIC CHEMISTRY OF BIOLOGICAL MOLECULES Summary: macromolecules: carbohydrates, amino acids, nucleic...

  12. The inability of rats to synthesize linoleic acid from cis-2-octenoic acid

    E-Print Network [OSTI]

    Anderson, Robert Eugene

    2012-06-07T23:59:59.000Z

    THE INABILITY OF RATS TO SYNTHESI2E LINOLEIC ACID FROM CIS-2-OCTENOIC ACID A Thesis Robert Eugene Anderson Submitted to the Graduate College of the Texas A g: M University in partia1 fulfillment of the requirerents for the degree of MASTER... OF SCIENCE January 1965 Major Subjeot: Bioohemistry THE INABILITY OF RATS TQ SYNTHESIEE LINOLEIC ACID FROM CIS-2E)CTENOIC ACID A Thesis Robert, Eugene Anderson Approved as to style and content by: Chair n of Committee)~ (Head of Depart~ant, Member...

  13. Effects of Acid Additives on Spent Acid Flowback through Carbonate Cores

    E-Print Network [OSTI]

    Nasir, Ehsaan Ahmad

    2012-07-16T23:59:59.000Z

    Limestone and the non-emulsifying agent M-NEA the worst for Texas Cream Chalk for spent acid recovery after gas flowback....

  14. E-Print Network 3.0 - acid-amino acid conjugates Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    amino acids is reported with the incorporation of one example into a ... Source: Beal, Peter A. - Department of Chemistry, University of Utah Collection: Chemistry 13 An...

  15. Electrostatic precipitation of condensed acid mist

    SciTech Connect (OSTI)

    Dahlin, R.S.

    1991-04-01T23:59:59.000Z

    This report deals with the second part (Phase 2) of a two-phased study of the control of acid mist emissions using a compact, wet electrostatic precipitator (WESP). The goal of the study was to determine the degree of acid mist control that could be achieved when a compact WESP was used to replace or augment the mist eliminators in a flue gas desulfurization (FGD) system. Phase 1 of the study examined the electrical operation of a lab-scale WESP collecting an acid mist from a coal combustion pilot plant equipped with a spray chamber. The results of this study were used to develop and validate a computer model of the WESP. In Phase 2, measurements were made at two utility scrubber installations to determine the loadings of acid mist, fly ash, and scrubber carryover. These measurements were used as input to the computer model to project the performance of retrofitted WESPs at both of the utility test sites. Phase 1 results showed that excellent electrical operating conditions could be achieved, but very high loadings of acid mist or the fine fly ash tended to degrade electrical operation because of space charge suppression of the corona current. Measurements made at the utility sites under Phase 2 showed that acid mist accounted for 40 to 57% of the total particulate mass, while fly ash and scrubber solids accounted for 40 to 55% and 1.0 to 3.4%. Impactor samples from both test sites showed an increase in acid content with decreasing particle size. 9 refs., 14 figs., 13 tabs.

  16. Energy densification of biomass-derived organic acids

    DOE Patents [OSTI]

    Wheeler, M. Clayton; van Walsum, G. Peter; Schwartz, Thomas J.; van Heiningen, Adriaan

    2013-01-29T23:59:59.000Z

    A process for upgrading an organic acid includes neutralizing the organic acid to form a salt and thermally decomposing the resulting salt to form an energy densified product. In certain embodiments, the organic acid is levulinic acid. The process may further include upgrading the energy densified product by conversion to alcohol and subsequent dehydration.

  17. Correlation between Fibroin Amino Acid Sequence and Physical Silk Properties*

    E-Print Network [OSTI]

    ?urovec, Michal

    moth (Ephe- stia kuehniella), and Indian meal moth (Plodia inter- punctella). The amino acid repeats

  18. Transcription factor-based biosensors for detecting dicarboxylic acids

    DOE Patents [OSTI]

    Dietrich, Jeffrey; Keasling, Jay

    2014-02-18T23:59:59.000Z

    The invention provides methods and compositions for detecting dicarboxylic acids using a transcription factor biosensor.

  19. Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols

    E-Print Network [OSTI]

    Robock, Alan

    aerosols can potentially result in an increase in acid deposition. [4] Acid rain has been studiedSulfuric acid deposition from stratospheric geoengineering with sulfate aerosols Ben Kravitz,1 Alan limit of hydration of all sulfate aerosols into sulfuric acid. For annual injection of 5 Tg of SO2

  20. System for agitating the acid in a lead-acid battery

    DOE Patents [OSTI]

    Weintraub, Alvin (Schenectady, NY); MacCormack, Robert S. (Glenville, NY)

    1987-01-01T23:59:59.000Z

    A system and method for agitating the acid in a large lead-sulfuric acid storage battery of the calcium type. An air-lift is utilized to provide the agitation. The air fed to the air-lift is humidified prior to being delivered to the air-lift.

  1. Evaluation of acid fracturing based on the "acid fracture number" concept

    E-Print Network [OSTI]

    Alghamdi, Abdulwahab

    2006-08-16T23:59:59.000Z

    Acid fracturing is one of the preferred methods to stimulate wells in carbonate reservoirs. It consists of injecting an acid solution at high enough pressure to break down the formation and to propagate a two-wing crack away from the wellbore...

  2. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20T23:59:59.000Z

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  3. Asthmatic responses to airborne acid aerosols

    SciTech Connect (OSTI)

    Ostro, B.D.; Lipsett, M.J.; Wiener, M.B.; Selner, J.C. (California Department of Health Services, Berkeley (USA))

    1991-06-01T23:59:59.000Z

    Controlled exposure studies suggest that asthmatics may be more sensitive to the respiratory effects of acidic aerosols than individuals without asthma. This study investigates whether acidic aerosols and other air pollutants are associated with respiratory symptoms in free-living asthmatics. Daily concentrations of hydrogen ion (H+), nitric acid, fine particulates, sulfates and nitrates were obtained during an intensive air monitoring effort in Denver, Colorado, in the winter of 1987-88. A panel of 207 asthmatics recorded respiratory symptoms, frequency of medication use, and related information in daily diaries. We used a multiple regression time-series model to analyze which air pollutants, if any, were associated with health outcomes reported by study participants. Airborne H+ was found to be significantly associated with several indicators of asthma status, including moderate or severe cough and shortness of breath. Cough was also associated with fine particulates, and shortness of breath with sulfates. Incorporating the participants' time spent outside and exercise intensity into the daily measure of exposure strengthened the association between these pollutants and asthmatic symptoms. Nitric acid and nitrates were not significantly associated with any respiratory symptom analyzed. In this population of asthmatics, several outdoor air pollutants, particularly airborne acidity, were associated with daily respiratory symptoms.

  4. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

    2009-05-05T23:59:59.000Z

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  5. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Xu, Wu (Tempe, AZ)

    2008-01-01T23:59:59.000Z

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  6. E-Print Network 3.0 - acid analysis including Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    predict the relative acid strength of a set... section. Findings Our analysis led to the identification of four distinct mental models of acid and acid... models of acid and acid...

  7. Water and UV degradable lactic acid polymers

    DOE Patents [OSTI]

    Bonsignore, P.V.; Coleman, R.D.

    1994-11-01T23:59:59.000Z

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer were selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide where the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures to an agricultural site is also disclosed.

  8. Water and UV degradable lactic acid polymers

    DOE Patents [OSTI]

    Bonsignore, Patrick V. (Joliet, IL); Coleman, Robert D. (Wheaton, IL)

    1994-01-01T23:59:59.000Z

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  9. Water and UV degradable lactic acid polymers

    DOE Patents [OSTI]

    Bonsignore, P.V.; Coleman, R.D.

    1996-10-08T23:59:59.000Z

    A water and UV light degradable copolymer is described made from monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  10. Water and UV degradable lactic acid polymers

    DOE Patents [OSTI]

    Bonsignore, Patrick V. (Joliet, IL); Coleman, Robert D. (Wheaton, IL)

    1996-01-01T23:59:59.000Z

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  11. IMPROVED PROCESSES TO REMOVE NAPHTHENIC ACIDS

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; William A. Goddard; Yongchun Tang

    2004-04-28T23:59:59.000Z

    In the first year of this project, we have established our experimental and theoretical methodologies for studies of the catalytic decarboxylation process. We have developed both glass and stainless steel micro batch type reactors for the fast screening of various catalysts with reaction substrates of model carboxylic acid compounds and crude oil samples. We also developed novel product analysis methods such as GC analyses for organic acids and gaseous products; and TAN measurements for crude oil. Our research revealed the effectiveness of several solid catalysts such as NA-Cat-1 and NA-Cat-2 for the catalytic decarboxylation of model compounds; and NA-Cat-5{approx}NA-Cat-9 for the acid removal from crude oil. Our theoretical calculations propose a three-step concerted oxidative decarboxylation mechanism for the NA-Cat-1 catalyst.

  12. Photoenhanced anaerobic digestion of organic acids

    DOE Patents [OSTI]

    Weaver, Paul F. (Golden, CO)

    1990-01-01T23:59:59.000Z

    A process is described for rapid conversion of organic acids and alcohols anaerobic digesters into hydrogen and carbon dioxide, the optimal precursor substrates for production of methane. The process includes addition of photosynthetic bacteria to the digester and exposure of the bacteria to radiant energy (e.g., solar energy). The process also increases the pH stability of the digester to prevent failure of the digester. Preferred substrates for photosynthetic bacteria are the organic acid and alcohol waste products of fermentative bacteria. In mixed culture with methanogenic bacteria or in defined co-culture with non-aceticlastic methanogenic bacteria, photosynthetic bacteria are capable of facilitating the conversion or organic acids and alcohols into methane with low levels of light energy input.

  13. Formic acid fuel cells and catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Larsen, Robert; Ha, Su Yun

    2010-06-22T23:59:59.000Z

    An exemplary fuel cell of the invention includes a formic acid fuel solution in communication with an anode (12, 134), an oxidizer in communication with a cathode (16, 135) electrically linked to the anode, and an anode catalyst that includes Pd. An exemplary formic acid fuel cell membrane electrode assembly (130) includes a proton-conducting membrane (131) having opposing first (132) and second surfaces (133), a cathode catalyst on the second membrane surface, and an anode catalyst including Pd on the first surface.

  14. Acid mine water aeration and treatment system

    DOE Patents [OSTI]

    Ackman, Terry E. (Finleyville, PA); Place, John M. (Bethel Park, PA)

    1987-01-01T23:59:59.000Z

    An in-line system is provided for treating acid mine drainage which basically comprises the combination of a jet pump (or pumps) and a static mixer. The jet pump entrains air into the acid waste water using a Venturi effect so as to provide aeration of the waste water while further aeration is provided by the helical vanes of the static mixer. A neutralizing agent is injected into the suction chamber of the jet pump and the static mixer is formed by plural sections offset by 90 degrees.

  15. Effect of Conjugated Linoleic Acid or Oleic Acid Addition on Fatty Acid Composition Profiles of Poultry Meat

    E-Print Network [OSTI]

    Shin, Dae Keun

    2011-08-08T23:59:59.000Z

    on the omega-6 fatty acid accumulation in broiler chicken breast and thigh meat. Eight broilers from each treatment were processed at 4 and 6 weeks of age, respectively. Regarding the diets containing five different fat sources, broiler chickens fed CLA...

  16. A method to attenuate U(VI) mobility in acidic waste plumes using humic acids

    SciTech Connect (OSTI)

    Wan, J.; Dong, W.; Tokunaga, T.K.

    2011-02-01T23:59:59.000Z

    Acidic uranium (U) contaminated plumes have resulted from acid-extraction of plutonium during the Cold War and from U mining and milling operations. A sustainable method for in-situ immobilization of U under acidic conditions is not yet available. Here, we propose to use humic acids (HAs) for in-situ U immobilization in acidic waste plumes. Our laboratory batch experiments show that HA can adsorb onto aquifer sediments rapidly, strongly and practically irreversibly. Adding HA greatly enhanced U adsorption capacity to sediments at pH below 5.0. Our column experiments using historically contaminated sediments from the Savannah River Site under slow flow rates (120 and 12 m/y) show that desorption of U and HA were non-detectable over 100 pore-volumes of leaching with simulated acidic groundwaters. Upon HA-treatment, 99% of the contaminant [U] was immobilized at pH < 4.5, compared to 5% and 58% immobilized in the control columns at pH 3.5 and 4.5, respectively. These results demonstrated that HA-treatment is a promising in-situ remediation method for acidic U waste plumes. As a remediation reagent, HAs are resistant to biodegradation, cost effective, nontoxic, and easily introducible to the subsurface.

  17. Development of a polylactic acid (PLA) polymer with an acid-sensitive N-ethoxybenzylimidazole (NEBI) crosslinker as a drug delivery system

    E-Print Network [OSTI]

    Hang, Leibniz Fangtinq

    2012-01-01T23:59:59.000Z

    of a Polylactic Acid (PLA) Polymer with an Acid-Sensitive N-of Poly-lactic Acid (PLA) and N- ethoxybenzylimidazoles (2 Poly-lactic Acid (PLA) and Functionalized Derivatives of

  18. Myristic acid participation in cholesterol metabolism

    E-Print Network [OSTI]

    Sidelman, Zvi

    1967-01-01T23:59:59.000Z

    . 5 3170 7217 10382 , 43 1. 4 1456 4147 5603 . 35 1360 1914 3274 . 70 868 790 1658 1. 0 2103 3060 5163 . 68 1137 4045 5182 . 28 29 Table D. Liver cholesterol radioactivity as effected by the addition of myristic and linoleic acids to a 2g...

  19. Corrosion free phosphoric acid fuel cell

    DOE Patents [OSTI]

    Wright, Maynard K. (Bethel Park, PA)

    1990-01-01T23:59:59.000Z

    A phosphoric acid fuel cell with an electrolyte fuel system which supplies electrolyte via a wick disposed adjacent a cathode to an absorbent matrix which transports the electrolyte to portions of the cathode and an anode which overlaps the cathode on all sides to prevent corrosion within the cell.

  20. Heterogeneous organic acid uptake on soot surfaces

    E-Print Network [OSTI]

    Levitt, Nicholas Paul

    2009-05-15T23:59:59.000Z

    observed the interaction between a number of carboxylic acids and soot from different fuel sources and formation mechanisms. A low pressure fast flow reactor was used to control the contact between the solid phase soot and gas phase organics, while chemical...

  1. The thermodynamic properties of some aminophosphonic acids

    E-Print Network [OSTI]

    Austin, James Richard

    1967-01-01T23:59:59.000Z

    constant differ by at least three pK units. 1 1. Samuel Glasstone, An Introduction to Electrochemistry, D. Van Nostrand Co. , Inc. , New York, Chapter 9, $25, (1954-). Each amino acid investigated satisfied the afore- said condition in that there were...

  2. Improved Processes to Remove Naphthenic Acids

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; Kangshi Wang; Yongchun Tang; William A. Goddard

    2005-12-09T23:59:59.000Z

    In the past three years, we followed the work plan as we suggested in the proposal and made every efforts to fulfill the project objectives. Based on our large amount of creative and productive work, including both of experimental and theoretic aspects, we received important technical breakthrough on naphthenic acid removal process and obtained deep insight on catalytic decarboxylation chemistry. In detail, we established an integrated methodology to serve for all of the experimental and theoretical work. Our experimental investigation results in discovery of four type effective catalysts to the reaction of decarboxylation of model carboxylic acid compounds. The adsorption experiment revealed the effectiveness of several solid materials to naphthenic acid adsorption and acidity reduction of crude oil, which can be either natural minerals or synthesized materials. The test with crude oil also received promising results, which can be potentially developed into a practical process for oil industry. The theoretical work predicted several possible catalytic decarboxylation mechanisms that would govern the decarboxylation pathways depending on the type of catalysts being used. The calculation for reaction activation energy was in good agreement with our experimental measurements.

  3. Preparation of Some Substituted Terephthalic Acids

    E-Print Network [OSTI]

    Benin, Vladimir

    , with the dilithiation of 2,5-dibromotoluene with t-BuLi at ­78 8C, followed by reaction with dry ice and subsequent acid (3) is esterified,[9] then side-chain brominated with NBS, to produce dimethyl 2

  4. Producing a trimethylpentanoic acid using hybrid polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2014-10-07T23:59:59.000Z

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing trimethylpentanoic acid. The present invention also provides for a host cell comprising the PKS and when cultured produces the trimethylpentanoic acid. The present invention also provides for a method of producing the trimethylpentanoic acid, comprising: providing a host cell of the present invention, and culturing said host cell in a suitable culture medium such that the trimethylpentanoic acid is produced, optionally isolating the trimethylpentanoic acid, and optionally, reducing the isolated trimethylpentanoic acid into a trimethylpentanol or an iso-octane.

  5. Effect of fulvic acid on the kinetics of aluminum fluoride complexation in acidic waters

    SciTech Connect (OSTI)

    Plankey, B.J.; Patterson, H.H.

    1988-12-01T23:59:59.000Z

    Both fluoride ion and fulvic acid are important aluminum binding ligands present in soil and surface waters. As such they play a role in the speciation and toxicity of natural waters that have increased aluminum concentration due to acid precipitation. We report here a kinetic study of aluminum complexation in the presence of both of these naturally occurring ligands. An overall mechanism has been identified and rate constants have been obtained for several of the reactions involved. We find that an a priori model of the two ligands in competition for aluminum is incorrect. In fact, the rate of fluoride ion consumption is increased by the presence of fulvic acid. Evidence is presented that this effect is due to several equilibria, some of which involve mixed-ligand species. The important equilibria in this three-component system are identified and discussed, as are aluminum speciation and toxicity in acidic waters.

  6. Investigating the Effect of Oil Saturation on Acid Propagation during Matrix Acidization of Carbonate Rocks

    E-Print Network [OSTI]

    Kumar, Rahul Pradeep

    2014-01-02T23:59:59.000Z

    The existence of an optimum injection rate for wormhole propagation, and face dissolution at low injection rates during matrix acidizing are well established. However, little has been documented that describes how the presence of residual oil...

  7. Modeling Acid Transport and Non-Uniform Etching in a Stochastic Domain in Acid Fracturing

    E-Print Network [OSTI]

    Mou, Jianye

    2010-10-12T23:59:59.000Z

    Success of acid fracturing depends on uneven etching along the fracture surfaces caused by heterogeneities such as variations in local mineralogy and variations in leakoff behavior. The heterogeneities tend to create channeling characteristics...

  8. Acidizing Dolomite Reservoirs Using HCL Acid Prepared with Seawater: Problems and Solutions

    E-Print Network [OSTI]

    Arensman, Dennis G

    2014-04-28T23:59:59.000Z

    with seawater and no scale inhibitors. Scale inhibitors were also tested for effectiveness in reducing calcium sulfate scale during acidizing. Static jar tests of three phosphonate-based, two sulphonated polymer-based, and one polyacrylic-based scale...

  9. A study of the distribution of fatty acids in the system: cottonseed oil-oleic acid-isopropanol-water

    E-Print Network [OSTI]

    Lamb, Frank E

    1948-01-01T23:59:59.000Z

    STUDY OF THE DISTHIBUTION OF FATTY ACIDS IN THE SYSTEM: COTTONSEED OIL - OLEIC ACID - ISOFHOPANOL - WATER A Thesis By Frank E. Lamb January 1948 A STUDY QF TNE DISTRIBUTION OF FATTY ACIDS IN TRE SYSTEM: COTTONSEED OII, - OIEIC ACID - ISOPROPANOL...A STDDY OF THI' DISTBIRliTION OF FATTY ACIDS IN THE SYSTEM: COTTONSFED OIL - OLEIC ACID - ISOPBOPANOL - YlATEB A Thesis Frank E. Lomb January 1948 Approval as to style and content recommended: Head ' t Te epartm nt of hem cal Engineer ng A...

  10. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...

    Broader source: Energy.gov (indexed) [DOE]

    Fuel Cell (Phosphoric Acid) Manufacturing R&D High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop...

  11. acid methyl esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  12. acidic antigenic fractions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  13. acid methyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  14. An antibacterial hydroxy fusidic acid analogue from Acremonium crotocinigenum

    E-Print Network [OSTI]

    Griffith, Gareth

    against a panel of multidrug-resistant (MDR) and methicillin-resistant Staphylococcus aureus (MRSA reserved. Keywords: Acremonium crotocinigenum; Fusidane triterpene; Fusidic acid; Antibacterial; MRSA; MDR, fusidic acid, a widely used therapeutic for methicillin-resistant Staphylococcus aureus (MRSA) infections

  15. TRL Acid and Solvent Wet Processing Rules and Guidelines

    E-Print Network [OSTI]

    Reif, Rafael

    : General rules and guidelines for wet chemical processing in TRL. Author: KFlo hood and when transporting or handling chemicals. An acid-proof apron, sleeveTRL Acid and Solvent Wet Processing Rules and Guidelines Purpose

  16. Nucleic acid based fluorescent sensor for copper detection

    DOE Patents [OSTI]

    Lu, Yi; Liu, Juewen

    2013-04-02T23:59:59.000Z

    A nucleic acid enzyme responsive to copper, comprising an oligonucleotide comprising a nucleotide sequence of SEQ ID NO:1, wherein the nucleic acid enzyme is not self-cleaving.

  17. Study of Acid Response of Qatar Carbonate Rocks

    E-Print Network [OSTI]

    Wang, Zhaohong

    2012-02-14T23:59:59.000Z

    reservoirs. Recently papers published from industry discussed the techniques, planning, and optimization of acid stimulation for Qatar carbonate. To the best of authors knowledge, no study has focused on the acid reaction to Qatar carbonates. The lack...

  18. Development and testing of an advanced acid fracture conductivity apparatus

    E-Print Network [OSTI]

    Zou, ChunLei

    2006-08-16T23:59:59.000Z

    wells. Acid fracturing is a standard practice to increase the production rate and to improve ultimate recovery in carbonate reservoirs. There have been successful cases in most carbonate reservoirs around the world. However acid fracture performance...

  19. acid binding proteins: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The adipocyte fatty acid-binding protein aP2 regulates systemic glucose (more) Shum, Bennett Oh Vic 2007-01-01 2 Fatty acid-binding protein in bovine skeletal muscle Texas A&M...

  20. acid dopac binds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The adipocyte fatty acid-binding protein aP2 regulates systemic glucose (more) Shum, Bennett Oh Vic 2007-01-01 2 Fatty acid-binding protein in bovine skeletal muscle Texas A&M...

  1. Determination of Total Lipids as Fatty Acid Methyl Esters (FAME...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    will be replaced by an ester bond between the fatty acid and a methyl group, producing methyl esters of the fatty acids (FAME) and free glycerol. 1.4 The FAME are then...

  2. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, A.

    1995-07-11T23:59:59.000Z

    Lubricating compositions are disclosed including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  3. acid mononucleotide adenylyltransferase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 14 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  4. aminoadipic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  5. aminocaproic acid eaca: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  6. acid hydrazone dpktch: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 11 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  7. aminolevulinic acid dehydratase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 18 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  8. aminobutyric acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 36 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  9. acid controls expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  10. aminolevulinic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 12 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  11. acid riboside salvage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 30 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  12. anf 4-hydroxyhomocitric acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 15 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  13. acid dioxygenase hpd: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 37 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  14. acid ascorbyl palmitate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 27 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  15. acid dehydratase alad: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 15 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  16. acetoacetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 8 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  17. acid lna taqman: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 46 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  18. amygdalic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 8 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  19. acid phosphoribosyltransferase 1-deficient: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 19 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  20. adipic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 11 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  1. acid dmsa renography: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 8 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  2. anthranilic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 10 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  3. aminocaproic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  4. acid glycosaminoglycan mucopolysaccharide: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 34 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  5. acidic oligosaccharides paos: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 40 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  6. aminobutyric acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 36 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  7. asparaginic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 17 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  8. arsonic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 10 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  9. anthraquinonic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 12 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  10. aristolochic acid nephropathy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 28 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  11. acetylsalicylic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 11 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  12. acid decarboxylase hgad65: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 32 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  13. acid catabolism evidence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Index 21 Allowance trading activity and state regulatory rulings : evidence from the U.S. Acid Rain Program MIT - DSpace Summary: The U.S. Acid Rain Program is one of the first,...

  14. The Effect of Heterogeneity on Matrix Acidizing of Carbonate Rocks

    E-Print Network [OSTI]

    Keys, Ryan S.

    2010-07-14T23:59:59.000Z

    In matrix acidizing, the goal is to dissolve minerals in the rock to increase well productivity. This is accomplished by injecting an application-specific solution of acid into the formation at a pressure between the pore pressure and fracture...

  15. Choline for neutralizing naphthenic acid in fuel and lubricating oils

    SciTech Connect (OSTI)

    Ries, D.G.; Roof, G.L.

    1986-07-15T23:59:59.000Z

    A method is described of neutralizing at least a portion of the naphthenic acids present in fuel and lubricating oils which contain naphthenic acids which comprises treating these oils with a neutralizing amount of choline.

  16. acid ethyl esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 241 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  17. acid ethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 241 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  18. ascorbic acid treatment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Both the free F. Dickens; H. E. H. Jonest; H. B. Waynforth 1968-01-01 173 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  19. acid hydrolysis monosaccharide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 221 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  20. acid increases iodide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on this diet when compared to the fat... Kelly, Peter B. 2013-10-04 183 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  1. acidic sulfate solutions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (3-5). Despite the clear importance of the ion atmosphere Das, Rhiju 80 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  2. acids increase haptoglobin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on this diet when compared to the fat... Kelly, Peter B. 2013-10-04 153 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  3. arachidonic acid increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on this diet when compared to the fat... Kelly, Peter B. 2013-10-04 209 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  4. acetic acid increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on this diet when compared to the fat... Kelly, Peter B. 2013-10-04 296 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  5. acid dehydrogenase complexes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ternary terbium p-aminobenzoic acid complexes Gao, Song 23 The distribution of boron and boric acid complexes in the sea Texas A&M University - TxSpace Summary: LIBRARY A a m...

  6. acid dehydrogenase complex: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ternary terbium p-aminobenzoic acid complexes Gao, Song 23 The distribution of boron and boric acid complexes in the sea Texas A&M University - TxSpace Summary: LIBRARY A a m...

  7. acid dibutyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 181 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  8. acid synthase expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 321 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  9. Method for removing fluoride contamination from nitric acid

    SciTech Connect (OSTI)

    Howerton, W.B.; Pruett, D.J.

    1982-07-13T23:59:59.000Z

    Fluoride ions are removed from nitric acid solution by contacting the vaporized solution with alumina or zirconium.

  10. Production of hydroxylated fatty acids in genetically modified plants

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Weston, AU); Boddupalli, Sekhar S. (Manchester, MI)

    2011-08-23T23:59:59.000Z

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  11. acid transporter hpat1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  12. acid transporters eaat-1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  13. acid transporters ntcp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  14. acid transporter lat1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  15. E-Print Network 3.0 - aminohippuric acids Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration) HCl acid (Fisher, certified ACS... the box (50% acid, etc). 5. Allow filters to soak in 50% HCl acid ... Source: Paytan, Adina - Department of Earth Sciences,...

  16. E-Print Network 3.0 - aminosuccinic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration) HCl acid (Fisher, certified ACS... the box (50% acid, etc). 5. Allow filters to soak in 50% HCl acid ... Source: Paytan, Adina - Department of Earth Sciences,...

  17. E-Print Network 3.0 - alkylphosphonic acid ehehpa-pc Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration) HCl acid (Fisher, certified ACS... the box (50% acid, etc). 5. Allow filters to soak in 50% HCl acid ... Source: Paytan, Adina - Department of Earth Sciences,...

  18. E-Print Network 3.0 - acid hiryusan hasseigata Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration) HCl acid (Fisher, certified ACS... the box (50% acid, etc). 5. Allow filters to soak in 50% HCl acid ... Source: Paytan, Adina - Department of Earth Sciences,...

  19. E-Print Network 3.0 - acids Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration) HCl acid (Fisher, certified ACS... the box (50% acid, etc). 5. Allow filters to soak in 50% HCl acid ... Source: Paytan, Adina - Department of Earth Sciences,...

  20. E-Print Network 3.0 - acid synthesis crystal Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Zeikus, 1980). To date, succinic acid has been... for succinic acid involves desalting electrodialysis, water- splitting electrodialysis, and crystallization... Succinic Acid...

  1. Synthesis and Metabolism of Carbonyl-C14 Pyruvic and Hydroxypyruvic Acids in Algae

    E-Print Network [OSTI]

    Milhaud, Gerhard; Benson, Andrew A.; Calvin, M.

    1955-01-01T23:59:59.000Z

    AND HYDROXYPYRUVIC ACIDS IN ALGAE Cerhard Milhaud, Andrew A.HYDROXYPYRUYIC ACIDS IN ALGAE Gerhard Milhaud, * - Andrew A.AND HYDROXYPYRUVIC ACIDS IN ALGAE Gerhard Milhaud, Andrew A.

  2. E-Print Network 3.0 - acid operational experiences Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acetic acid, propionic acid, butyric acid, valeric ... Source: Manning, Sturt - Cornell Tree-Ring Laboratory, Cornell University Collection: Environmental Sciences and Ecology 34...

  3. Investigating fatty acid biosynthesis within the algal chloroplast using Chlamydomonas reinhardtii as a model

    E-Print Network [OSTI]

    Blatti, Jillian L.

    2012-01-01T23:59:59.000Z

    acid biosynthesis in microalgae for sustainable biodiesel. (acid biosynthesis in microalgae for biofuel through protein-acid biosynthesis in microalgae through protein-protein

  4. E-Print Network 3.0 - ammonia acetic acid Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fluminic acid, or hydrogen. NITRIC ACID with: acetic... with: water, carbon dioxide, carbon tetrachloride, and other chlorinated hydrocarbons. ACETIC ACID with......

  5. E-Print Network 3.0 - acid alkyl esters Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitric Acid 34. Sulfuric acid... .5 will not be accepted through this program. Heavy metal, toxic, acidic (without solvents) and basic wastes should... . Mercaptans 4. ......

  6. E-Print Network 3.0 - acid conjugates synthesis Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (conjugated caffeic acid) (most plants, coffee iii) sinapine (sinapoyl choline) in canola (and... phenolic acids - structure: benzoic acid derivatives (C6 + COOH) i) salicylic...

  7. E-Print Network 3.0 - autochthonous lactic acid Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to make lactic acid... , itaconic, and lactic acids are manufactured via large-scale bio- processes. Oxalic, fumaric, and malic... source of lactic acid at the time of...

  8. E-Print Network 3.0 - acids rate studies Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Concepts... : Hydrophobic Interactions Oleic Acid is a fatty acid found in vegetable oils, ... Source: Thirumalai, Devarajan - Institute for Physical Science and Technology,...

  9. Removal of fluoride from aqueous nitric acid

    SciTech Connect (OSTI)

    Pruett, D.J.; Howerton, W.B.; Mailen, J.C.

    1981-06-01T23:59:59.000Z

    Several methods for removing fluoride from aqueous nitric acid were investigated and compared with the frequently used aluminum nitrate-calcium nitrate (Ca/sup 2 +/-Al/sup 3 +/) chemical trap-distillation system. Zirconium oxynitrate solutions were found to be superior in preventing volatilization of fluoride during distillation of the nitric acid, producing decontamination factors (DFs) on the order of 2 x 10/sup 3/ (vs approx. 500 for the Ca/sup 2 +/-Al/sup 3 +/ system). Several other metal nitrate systems were tested, but they were less effective. Alumina and zirconia columns proved highly effective in removing HF from HF-HNO/sub 3/ vapors distilled through the columns; fluoride DFs on the order of 10/sup 6/ and 10/sup 4/, respectively, were obtained. A silica gel column was very effective in adsorbing HF from HF-HNO/sub 3/ solutions, producing a fluoride DF of approx. 10/sup 4/.

  10. Lightweight, durable lead-acid batteries

    DOE Patents [OSTI]

    Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

    2011-09-13T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  11. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  12. Nucleic acids, compositions and uses thereof

    DOE Patents [OSTI]

    Preston, III, James F. (Micanopy, FL); Chow, Virginia (Gainesville, FL); Nong, Guang (Gainesville, FL); Rice, John D. (Gainesville, FL); St. John, Franz J. (Baltimore, MD)

    2012-02-21T23:59:59.000Z

    The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

  13. Nucleic acid compositions and the encoding proteins

    SciTech Connect (OSTI)

    Preston, III, James F.; Chow, Virginia; Nong, Guang; Rice, John D.; St. John, Franz J.

    2014-09-02T23:59:59.000Z

    The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

  14. Polymerization of Formic Acid under High Pressure

    SciTech Connect (OSTI)

    Goncharov, A F; Manaa, M R; Zaug, J M; Fried, L E; Montgomery, W B

    2004-08-23T23:59:59.000Z

    We report combined Raman, infrared (IR) and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid under pressure up to 50 GPa. Contrary to the report of Allan and Clark (PRL 82, 3464 (1999)), we find an infinite chain low-temperature Pna2{sub 1} structure consisting of trans molecules to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intra-chain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of the long-range order at pressures above 40 GPa with a large hysteresis at decompression. We attribute this behavior to a three-dimensional polymerization of formic acid.

  15. IMPROVED PROCESSES TO REMOVE NAPHTHENIC ACIDS

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; Kangshi Wang, William A. Goddard, Yongchun Tang

    2005-05-05T23:59:59.000Z

    In the second year of this project, we continued our effort to develop low temperature decarboxylation catalysts and investigate the behavior of these catalysts at different reaction conditions. We conducted a large number of dynamic measurements with crude oil and model compounds to obtain the information at different reaction stages, which was scheduled as the Task2 in our work plan. We developed a novel adsorption method to remove naphthenic acid from crude oil using naturally occurring materials such as clays. Our results show promise as an industrial application. The theoretical modeling proposed several possible reaction pathways and predicted the reactivity depending on the catalysts employed. From all of these studies, we obtained more comprehensive understanding about catalytic decarboxylation and oil upgrading based on the naphthenic acid removal concept.

  16. Acid treatment removes zinc sulfide scale restriction

    SciTech Connect (OSTI)

    Biggs, K. (Kerr McGee Corp., Lafayette, LA (US)); Allison, D. (Otis Engineering Corp., Lafayette, LA (US)); Ford, W.G.F. (Halliburton Co., Duncan, OK (United States))

    1992-08-31T23:59:59.000Z

    This paper reports that removal of zinc sulfide (ZnS) scale with acid restored an offshore Louisiana well's production to original rates. The zinc sulfide scale was determined to be in the near well bore area. The selected acid had been proven to control iron sulfide (FeS) scales in sour wells without causing harm to surface production equipment, tubing, and other downhole hardware. The successful removal of the blockage re-established previous production rates with a 105% increase in flowing tubing pressure. On production for a number of months, a high rate, high-pressure offshore well was experiencing unusually rapid pressure and rate declines. A small sample of the restrictive material was obtained during the wire line operations. The well was subsequently shut in while a laboratory analysis determined that zinc sulfide was the major component of the obstruction.

  17. Sulfate and acid resistant concrete and mortar

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1998-06-30T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance. 6 figs.

  18. Sulfate and acid resistant concrete and mortar

    DOE Patents [OSTI]

    Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

    1998-01-01T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance.

  19. Critical review of naphthenic acid corrosion

    SciTech Connect (OSTI)

    Tebbal, S. [SET Labs., Inc., Stafford, TX (United States)

    1999-11-01T23:59:59.000Z

    Naphthenic acid corrosion continues to be a reliability issue in refinery distillation units. A review of the subject is presented herein with special focus on field and laboratory data and on areas where research is needed. The review shows that several parameters are known to affect the corrosion process and their individual effect on crude corrosivity are somewhat understood. However, their combined effect is still subject to much controversy. The determination of a critical factor--naphthenic acid content--is still not standardized. It is shown herein that, by arranging the literature findings into three groups (1) furnace tubes and transfer lines, (2) vacuum column and (3) side cut piping, a better agreement of the literature data is achieved.

  20. EGVII endoglucanase and nucleic acids encoding the same

    DOE Patents [OSTI]

    Dunn-Coleman, Nigel; Goedegebuur, Frits; Ward, Michael; Yao, Jian

    2014-02-25T23:59:59.000Z

    The present invention provides a novel endoglucanase nucleic acid sequence, designated egl7, and the corresponding EGVII amino acid sequence. The invention also provides expression vectors and host cells comprising a nucleic acid sequence encoding EGVII, recombinant EGVII proteins and methods for producing the same.

  1. Process for the extraction of strontium from acidic solutions

    DOE Patents [OSTI]

    Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

    1994-01-01T23:59:59.000Z

    The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

  2. Process for the extraction of strontium from acidic solutions

    DOE Patents [OSTI]

    Horwitz, E.P.; Dietz, M.L.

    1993-01-01T23:59:59.000Z

    The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

  3. Production of carboxylic acid and salt co-products

    DOE Patents [OSTI]

    Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

    2014-09-09T23:59:59.000Z

    This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

  4. Method for nucleic acid isolation using supercritical fluids

    DOE Patents [OSTI]

    Nivens, David E. (11912 Kingsgate Rd., Knoxville, TN 37911); Applegate, Bruce M. (3700 Sutherland Ave. #Q2, Knoxville, TN 37911)

    1999-01-01T23:59:59.000Z

    A method for detecting the presence of a microorganism in an environmental sample involves contacting the sample with a supercritical fluid to isolate nucleic acid from the microorganism, then detecting the presence of a particular sequence within the isolated nucleic acid. The nucleic acid may optionally be subjected to further purification.

  5. EGVII endoglucanase and nucleic acids encoding the same

    DOE Patents [OSTI]

    Dunn-Coleman, Nigel (Los Gatos, CA); Goedegebuur, Frits (Vlaardingen, NL); Ward, Michael (San Francisco, CA); Yao, Jian (Sunnyvale, CA)

    2008-11-11T23:59:59.000Z

    The present invention provides a novel endoglucanase nucleic acid sequence, designated egl7, and the corresponding EGVII amino acid sequence. The invention also provides expression vectors and host cells comprising a nucleic acid sequence encoding EGVII, recombinant EGVII proteins and methods for producing the same.

  6. Process for the extraction of strontium from acidic solutions

    DOE Patents [OSTI]

    Horwitz, E.P.; Dietz, M.L.

    1994-09-06T23:59:59.000Z

    The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid. 4 figs.

  7. The Fixation of Phosphoric Acid by the Soil

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1922-01-01T23:59:59.000Z

    KAS AtiRICULTURAL EXPERIMENT STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BII BULLETIN NO. 304 eddent CEMBER, 1922 'ION OF PHOSPI ACID BY THE SOIL B. YOUNGBLOOD, DIRECTOR, COLLEGE STATION, BRAZOS COUNTY, TEXA STATION STAFF... ............................................... '7 ............................................... ;t of Acid 7' ........................................... of Ignition 8 ........................................ on by Minerals 10 ...................... on of Phosphoric Acid of Fertilizers 11...

  8. THE INFLUENCE OF INTRARUMINAL AND INTRADUODENAL INFUSION OF PICOLINIC ACID

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    THE INFLUENCE OF INTRARUMINAL AND INTRADUODENAL INFUSION OF PICOLINIC ACID ON METABOLISM OF 65Zn. The three treatments were : (1) intra- duodenal infusion of deionized water (control), (2) intraduodenal infusion of picoli- nic acid (IDPA) and (3) intraruminal infusion of picolinic acid (IRPA). Each

  9. Original article Effect of simulated acid rain on mycorrhizae

    E-Print Network [OSTI]

    Boyer, Edmond

    Original article Effect of simulated acid rain on mycorrhizae of Aleppo pine (Pinus halepensis in the three experiments. In substrata of neutro-basic pH, short-term exposures to acid rain positively affected ectomycorrhizal fungi, in parti- cular, Suillus species. acid rain / mycorrhizae / pH / Pinus

  10. MASTERS REPORT ANALYSIS AND MODELING OF ACID NEUTRALIZING CAPACITY

    E-Print Network [OSTI]

    itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID NEUTRALIZING CAPACITY IN THE MID-ATLANTIC HIGHLANDS UNIVERSITY #12;ABSTRACT Acid Neutralizing Capacity (ANC) is a measure of a solution's ability to buffer

  11. International negotiations on acid rains in Northern Europe

    E-Print Network [OSTI]

    Toint, Philippe

    International negotiations on acid rains in Northern Europe: a discrete time iterative process by M on acid rains in Northern Europe: a discrete time iterative process \\Lambda Marc Germain y Philippe L is provided by Kaitala et al. (1995) in the context of the ``acid rain game'' in Northern Europe, that is

  12. How is ferulic acid transported into the Golgi apparatus? Lignin

    E-Print Network [OSTI]

    How is ferulic acid transported into the Golgi apparatus? Lignin polymerization is also influenced]. These ferulic acid residues are thought to initiate lignin polymerization. It is not known how ferulic acid in the cell wall field, but also creates novel opportunities for the manipulation of lignin in crop plants

  13. Alkaline earth cation extraction from acid solution

    DOE Patents [OSTI]

    Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

    2003-01-01T23:59:59.000Z

    An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

  14. Acid/Base Recovery From Sodium Sulfate

    E-Print Network [OSTI]

    Niksa, M. J.

    escalating In price due to the Imbalance In market demand. Chlorine and caustic are produced together by the electrolysis 01 sodium chloride brine solutions. Every ECU (electrochemical unit) 01 chlorine resu~s In the production 01 one ECU 01 caustic soda... cell also produces an acid product that is contaminated with unreacted sullate. The voltage 01 a three compartment is higher, however, and the process system Is more complex. Process System Current density and efficiency determines the amount 01...

  15. Perfluorooctanoic acid rigidifies a model lipid membrane

    E-Print Network [OSTI]

    Beate-Annette Bruening; Bela Farago

    2014-05-05T23:59:59.000Z

    We report a combined dynamic light scattering and neutron spin-echo (NSE) study on vesicles composed of the phospholipid 1,2-dimyristoyl-sn-glycero-3-phosphatidylcholine under the influence of varying amounts of perfluorooctanoic acid. We study local lipid bilayer undulations using NSE on time scales up to 200 ns. Similar to the effect evoked by cholesterol, we attribute the observed lipid bilayer stiffening to a condensing effect of the perfluorinated compound on the membrane.

  16. Naphthenic acid corrosion in the refinery

    SciTech Connect (OSTI)

    Craig, H.L. Jr. [Mobil Research and Development Corp., Paulsboro, NJ (United States)

    1995-11-01T23:59:59.000Z

    Field tests and laboratory studies of refinery process streams are presented. The effects of temperature, velocity and physical state were studied with respect to alloy selection for corrosion resistant service. The amount of molybdenum in the austenitic stainless steel alloys is the dominant factor in conferring corrosion resistance. The Naphthenic Acid Corrosion Index (NACI) is useful in assessing the severity of corrosion under a variety of circumstances.

  17. Reaction of Calcite and Dolomite with In-Situ Gelled Acids, Organic Acids, and Environmentally Friendly Chelating Agent (GLDA)

    E-Print Network [OSTI]

    Rabie, Ahmed 1978-

    2012-11-16T23:59:59.000Z

    Well stimulation is the treatment remedy when oil/gas productivity decreases to unacceptable economical limits. Well stimulation can be carried out through either "Matrix Acidizing" or fracturing with both "Hydraulic Fracturing" and "Acid Fracturing...

  18. The Effects of Initial Condition of Fracture Surfaces, Acid Spending, and Type on Conductivity of Acid Fracture

    E-Print Network [OSTI]

    Almomen, Ali Mansour

    2013-07-24T23:59:59.000Z

    . Another area of interest is the variation of conductivity along the fracture due to acid spending. We also investigated the contact time, acid system type, and treatment temperature effects on conductivity using San Andres dolomite cores. The results...

  19. Naphthenic acid corrosion in synthetic fuels production

    SciTech Connect (OSTI)

    Bruyn, H.I. de [Mossgas Ltd., Mossel Bay (South Africa)

    1998-12-31T23:59:59.000Z

    Serious corrosion damage to carbon steel piping in a fractionation unit associated with synthetic fuels production has been ascribed to the presence of naphthenic acids. Investigation of the problem revealed total acids numbers (TAN) ranging from 8--12mg KOH/g in the feed to the unit. Damage typically occurred in the temperature range 180--240 C and manifested as localized pitting, preferential weld corrosion, general wall thinning and end-grain attack. Filming amine corrosion inhibitors designed for refinery overhead systems have been proven ineffective and high temperature phosphate-based inhibitors could not be used due to potential catalyst poisoning in downstream refinery units. Coupon exposures indicated corrosion rates in the order of 2 mm/y on carbon steel in a reboiler line as well as pitting to austenitic stainless steel type UNS S30403. Line replacement in austenitic stainless steel UNS S31603 has been proven effective. The performance of this alloy is mainly ascribed to its molybdenum content. The absence of sulfur in the feed to the unit is also contributing to the alloy performance despite the extremely high total acid numbers.

  20. Oleanolic acid alters bile acid metabolism and produces cholestatic liver injury in mice

    SciTech Connect (OSTI)

    Liu, Jie, E-mail: JLiu@kumc.edu [University of Kansas Medical Center, Kansas City, KS 66160 (United States); Zunyi Medical College, Zunyi 563003 (China); Lu, Yuan-Fu [University of Kansas Medical Center, Kansas City, KS 66160 (United States); Zunyi Medical College, Zunyi 563003 (China); Zhang, Youcai; Wu, Kai Connie [University of Kansas Medical Center, Kansas City, KS 66160 (United States); Fan, Fang [Cytopathology, University of Kansas Medical Center, Kansas City, KS 66160 (United States); Klaassen, Curtis D. [University of Kansas Medical Center, Kansas City, KS 66160 (United States)

    2013-11-01T23:59:59.000Z

    Oleanolic acid (OA) is a triterpenoids that exists widely in plants. OA is effective in protecting against hepatotoxicants. Whereas a low dose of OA is hepatoprotective, higher doses and longer-term use of OA produce liver injury. This study characterized OA-induced liver injury in mice. Adult C57BL/6 mice were given OA at doses of 0, 22.5, 45, 90, and 135 mg/kg, s.c., daily for 5 days, and liver injury was observed at doses of 90 mg/kg and above, as evidenced by increases in serum activities of alanine aminotransferase and alkaline phosphatase, increases in serum total bilirubin, as well as by liver histopathology. OA-induced cholestatic liver injury was further evidenced by marked increases of both unconjugated and conjugated bile acids (BAs) in serum. Gene and protein expression analysis suggested that livers of OA-treated mice had adaptive responses to prevent BA accumulation by suppressing BA biosynthetic enzyme genes (Cyp7a1, 8b1, 27a1, and 7b1); lowering BA uptake transporters (Ntcp and Oatp1b2); and increasing a BA efflux transporter (Ost?). OA increased the expression of Nrf2 and its target gene, Nqo1, but decreased the expression of AhR, CAR and PPAR? along with their target genes, Cyp1a2, Cyp2b10 and Cyp4a10. OA had minimal effects on PXR and Cyp3a11. Taken together, the present study characterized OA-induced liver injury, which is associated with altered BA homeostasis, and alerts its toxicity potential. - Highlights: Oleanolic acid at higher doses and long-term use may produce liver injury. Oleanolic acid increased serum ALT, ALP, bilirubin and bile acid concentrations. OA produced feathery degeneration, inflammation and cell death in the liver. OA altered bile acid homeostasis, affecting bile acid synthesis and transport.

  1. The effects of solvent mixtures on the gel permeation chromatography of alkanes, fatty acids, and fatty acid esters

    E-Print Network [OSTI]

    Bolton, Patrick Lee

    1985-01-01T23:59:59.000Z

    THE EFFECTS OF SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis PATRICK LEE BOLTON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1985 Major Subject: Chemistry THE EFFECTS OP SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis by PATRICK LEE BOLTON Approved...

  2. Nucleic acid analysis using terminal-phosphate-labeled nucleotides

    DOE Patents [OSTI]

    Korlach, Jonas (Ithaca, NY); Webb, Watt W. (Ithaca, NY); Levene, Michael (Ithaca, NY); Turner, Stephen (Ithaca, NY); Craighead, Harold G. (Ithaca, NY); Foquet, Mathieu (Ithaca, NY)

    2008-04-22T23:59:59.000Z

    The present invention is directed to a method of sequencing a target nucleic acid molecule having a plurality of bases. In its principle, the temporal order of base additions during the polymerization reaction is measured on a molecule of nucleic acid, i.e. the activity of a nucleic acid polymerizing enzyme on the template nucleic acid molecule to be sequenced is followed in real time. The sequence is deduced by identifying which base is being incorporated into the growing complementary strand of the target nucleic acid by the catalytic activity of the nucleic acid polymerizing enzyme at each step in the sequence of base additions. A polymerase on the target nucleic acid molecule complex is provided in a position suitable to move along the target nucleic acid molecule and extend the oligonucleotide primer at an active site. A plurality of labelled types of nucleotide analogs are provided proximate to the active site, with each distinguishable type of nucleotide analog being complementary to a different nucleotide in the target nucleic acid sequence. The growing nucleic acid strand is extended by using the polymerase to add a nucleotide analog to the nucleic acid strand at the active site, where the nucleotide analog being added is complementary to the nucleotide of the target nucleic acid at the active site. The nucleotide analog added to the oligonucleotide primer as a result of the polymerizing step is identified. The steps of providing labelled nucleotide analogs, polymerizing the growing nucleic acid strand, and identifying the added nucleotide analog are repeated so that the nucleic acid strand is further extended and the sequence of the target nucleic acid is determined.

  3. Dosage de la lignine insoluble en milieu acide : influence du prtraitement par hydrolyse acide sur la lignine Kla-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Dosage de la lignine insoluble en milieu acide : influence du prétraitement par hydrolyse acide sur la lignine Kla- son de bois et de paille Bernard MONTIES LN.R.A., Laboratoire de Chimie biologique et la lignine insoluble dans l'acide sulfurique concentré, lignine Klason, est décrit : il comporte une

  4. Continuous-flow free acid monitoring method and system

    DOE Patents [OSTI]

    Strain, J.E.; Ross, H.H.

    1980-01-11T23:59:59.000Z

    A free acid monitoring method and apparatus is provided for continuously measuring the excess acid present in a process stream. The disclosed monitoring system and method is based on the relationship of the partial pressure ratio of water and acid in equilibrium with an acid solution at constant temperature. A portion of the process stream is pumped into and flows through the monitor under the influence of gravity and back to the process stream. A continuous flowing sample is vaporized at a constant temperature and the vapor is subsequently condensed. Conductivity measurements of the condensate produces a nonlinear response function from which the free acid molarity of the sample process stream is determined.

  5. Naphthenic acids as antiwear additives for jet fuels

    SciTech Connect (OSTI)

    Deineko, P.S.; Vasil`eva, E.N.; Popova, O.V.; Bashkatova, S.T.

    1995-05-01T23:59:59.000Z

    One of the ways in which the antiwear properties of jet fuels can be improved is the use of lubricity agents, otherwise known as antiwear additives. Among the various compounds that have antiwear properties in these fuels, naphthenic, acids merit special attention. These are alicyclic carboxylic acids, in most cases monobasic, with five- and six-membered carbon rings; they have the general formula R(CH{sub 2}){sub n}COOH, where R is a naphthene radical. Natural naphthenic acids consist mainly of acids of the cyclopentane series, beginning with the simplest, in particular cyclopentylacetic acid. The lower naphthenic acids are monocyclic; the higher acids, beginning with C{sub 13}, are bicyclic and polycyclic. Naphthenic acids of the cyclohexane series are encountered less frequently; they may be found, for example, in Baku, California, and Sakhalin crudes. The most widely used method for obtaining naphthenic acids is the treatment of light distillates, lube distillates, and diesel fuels. The standard GOST 13302-77 establishes several grades of naphthenic acids, depending on the raw material and the production technology. This work was aimed at the utilization of wastes containing naphthenic acids, with subsequent use as jet fuel additives.

  6. Detection of nucleic acids by multiple sequential invasive cleavages

    DOE Patents [OSTI]

    Hall, Jeff G; Lyamichev, Victor I; Mast, Andrea L; Brow, Mary Ann D

    2012-10-16T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof. The present invention further relates to methods and devices for the separation of nucleic acid molecules based on charge. The present invention also provides methods for the detection of non-target cleavage products via the formation of a complete and activated protein binding region. The invention further provides sensitive and specific methods for the detection of human cytomegalovirus nucleic acid in a sample.

  7. Interaction of Uranium(VI) with Phthalic Acid

    SciTech Connect (OSTI)

    Vazquez, G.; Dodge, C; Francis, A

    2008-01-01T23:59:59.000Z

    Phthalic acid, a ubiquitous organic compound found in soil, water, and in domestic and nuclear wastes can affect the mobility and bioavailability of metals and radionuclides. We examined the complexation of uranium with phthalic acid by potentiometric titration, electrospray ionization-mass spectroscopy (ESI-MS), and extended X-ray absorption fine structure (EXAFS) analysis. Potentiometric titration of a 1:1 U/phthalic acid indicated uranyl ion bonding with both carboxylate groups of phthalic acid; above pH 5 the uranyl ion underwent hydrolysis with one hydroxyl group coordinated to the inner-sphere of uranium. In the presence of excess phthalic acid, ESI-MS analysis revealed the formation of both 1:1 and 1:2 U/phthalic acid complexes. EXAFS studies confirmed the mononuclear biligand 1:2 U/phthalic acid complex as the predominant form. These results show that phthalates can form soluble stable complexes with uranium and may affect its mobility.

  8. Processes to remove acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.

    1994-09-20T23:59:59.000Z

    The present invention relates to a process for reducing the concentration of NO in a gas, which process comprises: (A) contacting a gas sample containing NO with a gaseous oxidizing agent to oxidize the NO to NO[sub 2]; (B) contacting the gas sample of step (A) comprising NO[sub 2] with an aqueous reagent of bisulfite/sulfite and a compound selected from urea, sulfamic acid, hydrazinium ion, hydrazoic acid, nitroaniline, sulfanilamide, sulfanilic acid, mercaptopropanoic acid, mercaptosuccinic acid, cysteine or combinations thereof at between about 0 and 100 C at a pH of between about 1 and 7 for between about 0.01 and 60 sec; and (C) optionally contacting the reaction product of step (A) with conventional chemical reagents to reduce the concentrations of the organic products of the reaction in step (B) to environmentally acceptable levels. Urea or sulfamic acid are preferred, especially sulfamic acid, and step (C) is not necessary or performed. 16 figs.

  9. E-Print Network 3.0 - acid-base equilibrium Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Principles of Environmental Engineering Date Topic Reading Summary: Acid-Base Chemistry 86-195 28 Acid-Base Chemistry 31 Acid Base Chemistry Sept. 2 Acid-Base Chemistry...

  10. Nucleic Acid Database: a Repository of Three-Dimensional Information about Nucleic Acids

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Berman, H.M.; Olson, W.K.; Beveridge, D.L.; Westbrook, J.; Gelbin, A.; Demeny, T.; Hsieh, S.H.; Srinivasan, A.R.; Schneider, B.

    The Nucleic Acid Database (NDB) provides 3-D structural information about nucleic acids. It is a relational database designed to facilitate the easy search for nucleic acid structures using any of the stored primary or derived structural features. Reports can then be created describing any properties of the selected structures and structures may be viewed in several different formats, including the mmCIF format, the NDB Atlas format, the NDB coordinate format, or the PDB coordinate format. Browsing structure images created directly from coordinates in the repository can also be done. More than 7000 structures have been released as of May 2014. This website also includes a number of specialized tools and interfaces. The NDB Project is funded by the National Institutes of Health and has been funded by the National Science Foundation and the Department of Energy in the past.

  11. Constructing and engineering fatty acid metabolic pathways for the production of fuels and chemicals

    E-Print Network [OSTI]

    Steen, Eric James

    2010-01-01T23:59:59.000Z

    0 fatty acids in transgenic canola by overexpression of Ch0 fatty acids in transgenic canola by overexpression of Ch

  12. Investigating fatty acid biosynthesis within the algal chloroplast using Chlamydomonas reinhardtii as a model

    E-Print Network [OSTI]

    Blatti, Jillian L.

    2012-01-01T23:59:59.000Z

    0 fatty acids in transgenic canola by overexpression of Ch0 fatty acids in transgenic canola by overexpression of Ch

  13. Effect of dietary cysteine, methionine, and sterculic acid on fatty acid distribution in rat adipose tissue

    E-Print Network [OSTI]

    Brotze, Mary Frances

    1968-01-01T23:59:59.000Z

    . Statistical Anal sis The data were treated according to the analysis of variance for data with a single criterion of classifica- tion(24). Each of the ratios for the triglyceride frac- tion were analyzed as: Source oi Variation De rees of Freedom Total... ACIDS IN ADIPOSE TISSUE OF THE RAT B. Free Fatty Acid Fraction Group No. Sterculia f~oa ao 1 Methionine level in diet Cysteine level in diet 16/16:1 18/18:1 18/18:2 18:1/18:2 III IV VI VII VIII 0. 2 0. 2 0. 2 0. 2 low low high...

  14. The greenhouse effect and acid rain

    SciTech Connect (OSTI)

    Traeger, R.K.

    1990-01-01T23:59:59.000Z

    The concentrations of carbon dioxide, methane, sulfur dioxide, nitrous oxides and chlorofluorocarbons is increasing in the earth's atmosphere. Increased concentrations of these trace gases could lead to global warming, increased acid rain and increased UV radiation on the earth's surface; however, the actual impacts are still uncertain and are also the subject of great debate. Application of clean'' energy sources such as geothermal are obviously desirable for decreasing these effects and improving our overall general environment. This paper briefly summarizes the global environment concerns, providing a backdrop for the following papers which describe the geothermal role in future environmental considerations. 5 refs., 2 figs., 1 tab.

  15. Nucleic acid amplification using modular branched primers

    DOE Patents [OSTI]

    Ulanovsky, Levy (Westmont, IL)

    2001-01-01T23:59:59.000Z

    Methods and compositions expand the options for making primers for use in amplifying nucleic acid segments. The invention eliminates the step of custom synthesis of primers for Polymerase Chain Reactions (PCR). Instead of being custom-synthesized, a primer is replaced by a combination of several oligonucleotide modules selected from a pre-synthesized library. A modular combination of just a few oligonucleotides essentially mimics the performance of a conventional, custom-made primer by matching the sequence of the priming site in the template. Each oligonucleotide module has a segment that matches one of the stretches within the priming site.

  16. Preparation of some amino phosphonic acids

    E-Print Network [OSTI]

    Chambers, James Richard

    1958-01-01T23:59:59.000Z

    TYANRYANLNOH BRAY * VIII ^Kabachnik, S.S.S.R. Inst. Orge 2,"12 ri9357T c.A., 5 M. I., and Medved, Khim. Sintezy Org. 46, 421c (195277^ T. Ya,, Akad. Nauk Soedinenii9 Sbornik9 5 The monoethyl ester (VIII) gave, on hydrolysis, amino- methylphosphonic.... ^Chavane, V. , Ann. Chim., fl23_4j 552 (1949). 6 triester were reported. The yield was not given and no evidence was disclosed as to the identity of this ester0 The hydrolysis of this triester to give the acid was not reported. 8 9 10Kabachnik...

  17. Process for producing peracids from aliphatic hydroxy carboxylic acids

    SciTech Connect (OSTI)

    Chum, H.L.; Ratcliff, M.A.; Palasz, P.D.

    1986-10-14T23:59:59.000Z

    This patent describes a wood pulp processing system of the type producing both pulp and a stream of lactic acid-containing black liquor solution, the processor for production of peracid bleaching agents from hydroxy acid contained in the black liquor solution, comprising: adjusting the pH of the black liquor solution to the range of about 8-9 by exposing the solution to CO/sub 2/ carbon dioxide to form an alkaline precipitate; separating solids from the black liquor solution to produce a residual solution containing lower aliphatic hydroxy acids selected from the group consisting of lactic acid, glycolic acid, 2-hydroxybutanoic acid, xyloisosaccharinic acid, and glucoisosaccharinic acid; decarboxylating the lower aliphatic hydroxy acids to corresponding gaseous aliphatic aldehydes by admixing a powdered semiconductor with the residual solution to form a slurry; removing the gaseous aldehydes from the residual solution by sweeping gas flow as soon as they are generated to prevent further oxidation to carboxylic acids; reacting the gaseous aldehydes with oxygen to form corresponding peracids; and applying the peracids as bleaching agents to the pulp produced in the pulp processing system.

  18. Solvent extraction of rare-earth metals by carboxylic acids

    SciTech Connect (OSTI)

    Preez, A.C. du; Preston, J.S. [Mintek, Randburg (South Africa)

    1992-04-01T23:59:59.000Z

    The solvent extraction of the trivalent lanthanides and yttrium from nitrate media by solutions of carboxylic acids in xylene has been studied. Commercially available carboxylic acids such as Versatic 10 and naphthenic acids were used, as well as model compounds of known structure, such as 2-ethylhexanoic and 3-cyclohexylpropanoic acids. In a few cases, extraction of the metals from sulphate and chloride solutions was also investigated. The dependence of the extraction properties of the carboxylic acids on the atomic number of the lanthanide shows a definite relationship to the steric bulk of the carboxylic acid molecule quantified by means of the steric parameter, E{sub s}{prime} of the substituent alkyl group. The stoichiometries of the extracted complexes for representative light (La), middle (Gd) and heavy (Lu) rare-earth metals were investigated by the slope-analysis technique for a sterically hindered acid (Versatic 10 acid; -E{prime}{sub s} = 3.83) and an acid with low steric hindrance (3-cyclohexylpropanoic acid; -E{prime}{sub s} = 0.28). 14 refs., 13 figs., 3 tabs.

  19. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23T23:59:59.000Z

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  20. in amino-acid concentration enhanced amino-acid and glucose utilization for lipogenesis, with no

    E-Print Network [OSTI]

    Boyer, Edmond

    . In contrast, insulin decreased lipid secretion measured by glycerol (-35%) and glucose incor- poration increased glycerol incorporation (+35%) into cellular lipids and consequently lipogenesis. Insulin increased more strongly amino-acid and glucose incorporation into cellular lipids, the glu- cose incorporation

  1. Evalutaion of Multi-Stage Sandstone Acidizing Uging an Organic Mud Acid and a Clay Stabalizer

    E-Print Network [OSTI]

    Sakipour, Armin

    2013-05-29T23:59:59.000Z

    and clay particles. The purpose of this study is to present and evaluate multi-stage acid injection into the Bandera sandstone cores to remove formation damage. In this study, coreflood experiments were conducted on Bandera sandstone cores (1.5 in. x 6 in...

  2. Newer method for analyzing naphthenic acids in petroleum

    SciTech Connect (OSTI)

    Fan, T.P. (Shell Development Co., Houston, TX (United States))

    1990-08-01T23:59:59.000Z

    The naphthenic acids in petroleum are considered a class of biological markers. Their potential use in source correlation and as indicator of biodegradation have been reported in the past. Their presence in waste water at refineries may also cause corrosion problems and fish toxicity. Due to their highly complicated nature, detailed characterization of the acids has been difficult and time consuming. This talk will describe a relatively simple approach in characterizing the acids based on their group types. The acids were first separated from petroleum followed by mass spectrometric determinations. Two newer methods were developed to analyze the acid components, namely Chemical Ionization with NF{sub 3} as reagent gas and negative ion Fast Atom Bombardment. The geochemical interpretation based on acid distribution will be demonstrated with a set of well understood crude oil samples.

  3. The iron powder test for naphthenic acid corrosion studies

    SciTech Connect (OSTI)

    Hau, J.L.; Yepez, O.; Specht, M.I.; Lorenzo, R. [PDVSA-Intevep, Caracas (Venezuela)

    1999-11-01T23:59:59.000Z

    In the course of an ongoing investigation into the phenomenon of naphthenic acid corrosion, a new test method has evolved and is currently being further developed to substitute the total acid number (TAN or neutralization number) as an indicator for naphthenic acid corrosion potential. It can also be used to complement conventional autoclave corrosion tests in high temperature environments, which are based on weight loss of steel coupons. In this new method an oil sample reacts with pure iron powder within an autoclave heated to the testing temperature. The result is based on the amount of dissolved iron found in the oil sample. The oil sample can dissolve an amount of iron for a given time at a given temperature, depending on the naphthenic acid corrosion, since these acids react with iron to produce oil soluble iron naphthenates. This paper describes the method, compares it with conventional crude corrosiveness testing, and proposes it as a new way of measuring naphthenic acid corrosion potential.

  4. Investigating the Effects of Core Length on Pore Volume to Breakthrough (PVBT) Behavior in Carbonate Core Samples during Matrix Acidizing with Hydrochloric Acid

    E-Print Network [OSTI]

    Nour, Mohamed

    2014-05-06T23:59:59.000Z

    Most literature contains Hydrochloric acid (HCl) carbonate acidizing experiments performed on short (2 - 6 inch) cores. These cores do not accurately represent reservoir conditions, as spent acid is not propagated for any appreciable distance along...

  5. An Improved Model for Sandstone Acidizing and Study of the Effect of Mineralogy and Temperature on Sandstone Acidizing Treatments and Simulation

    E-Print Network [OSTI]

    Agarwal, Amit Kumar

    2013-01-14T23:59:59.000Z

    Sandstone acidizing is a complex operation because the acidizing fluid reacts with a variety of minerals present in the formation that results in a wide range of reaction products. The hydrofluoric acid (HF) reaction rate differs widely from mineral...

  6. Impact of Herbicides on Winter Canola (Brassica napus L.) Production and Fatty Acid Composition in South Texas

    E-Print Network [OSTI]

    Cogdill, Todd Joseph

    2013-01-16T23:59:59.000Z

    by the herbicides evaluated. Fatty acid composition, specifically stearic acid, oleic acid, linolenic acid, and oleic to linolenic acid ratio, was affected by herbicide treatments. This research found that protoporphyrinogen oxidase (PPG oxidase) inhibitor...

  7. A high frequency titration of indium with benzenephosphinic acid

    E-Print Network [OSTI]

    Keilt, Francis Xavier

    1960-01-01T23:59:59.000Z

    with ordinary oxidizing agents as hydrogen peroxide and nitric acid. (31) Michaells and Ananoff first reported the preparation and properties of benzenepbosphinic acid in 1874 (25). Kichaells prepared the potassium, barium, calcium, and iron salts... in approximately 25 milliliters of the acid These solutions were heated on a hot plate until dry. The salt was dissolved in dis- tilled water, and diluted to one liter in a volumetric flask. These solutions were standardised volumetrically with EDTA (13...

  8. Process for the recovery of strontium from acid solutions

    DOE Patents [OSTI]

    Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

    1992-01-01T23:59:59.000Z

    The invention is a process for selectively extracting strontium and technetium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant is a macrocyclic polyether in a diluent which is insoluble in water, but which will itself dissolve a small amount of water. The process will extract strontium and technetium values from nitric acid solutions which are up to 6 molar in nitric acid.

  9. Process for the recovery of strontium from acid solutions

    DOE Patents [OSTI]

    Horwitz, E.P.; Dietz, M.L.

    1992-03-31T23:59:59.000Z

    The invention is a process for selectively extracting strontium and technetium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant is a macrocyclic polyether in a diluent which is insoluble in water, but which will itself dissolve a small amount of water. The process will extract strontium and technetium values from nitric acid solutions which are up to 6 molar in nitric acid. 5 figs.

  10. The hydrogenation of dietary unsaturated fatty acids by the ruminant

    E-Print Network [OSTI]

    Reddy, H. G. Ramakrishna

    2012-06-07T23:59:59.000Z

    LIBRARY g 4 M COLLEGE Pf TEXIIG THE HYDROGENATION OF DIETARY UNSATURATED FATTY ACIDS SY THE RUMINANT A The sis H. G. RAMAKRISHNA REDDY Submitted to the Graduate School of the Agni cultural and Mechanical College of Texas in partial... EXTRACTION AND RECOVERY OF FATTY AC IDS FATTY ACID ANALYSES . RESULTS AND DISCUSSION Cottonseed oil fed goats. Linseed oil fed goats. SUMMARY AND CONCLUSIONS. LITERATURE CITED. 17 LIST OF TAIILXS Page I, Typical Component Acids (Wts. psr cent...

  11. Phosphate ester inhibitors solve naphthenic acid corrosion problems

    SciTech Connect (OSTI)

    Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States))

    1994-02-28T23:59:59.000Z

    Crude oils containing naphthenic acids can cause a variety of corrosion problems in any of several process areas. But because of the complexity of naphthenic acid corrosion, no routine technique is available for predicting corrosion from this source. Certain high-temperature corrosion inhibitors with a general phosphate ester structure have shown good mitigation of naphthenic acid corrosion in commercial applications. A description of two such cases will help refiners know what to look for to prevent similar occurrences in their plants.

  12. ascorbic acid prevents: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  13. acids prevent atrial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  14. acid nanoparticle effectively: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  15. acid prevents calcium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  16. acid oxidation held: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with docosahexaenoic acid protects low-density lipoproteins from oxidation in healthy men Materials Science Websites Summary: for cardiovascular disease prevention in a healthy...

  17. acid fluorescent nanoparticles: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Propionic-Acid-Terminated Silicon Nanoparticles: Synthesis and Optical Characterization Materials Science Websites Summary: Sato, and Mark T. Swihart*, Department of Chemical and...

  18. acid prevents lipotoxic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  19. acid prevents high: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    27 Crystallization of Highly Oriented ZnO Microrods on Carboxylic Acid-Terminated SAMs Materials Science Websites Summary: Crystallization of Highly Oriented ZnO Microrods on...

  20. acid prevents dendritic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corona effects: multi-phosphonic acid poly(ethylene glycol) copolymers for stable stealth iron oxide nanoparticles CERN Preprints Summary: When disperse in biological...

  1. Recombinant microorganisms for increased production of organic acids

    DOE Patents [OSTI]

    Yi, Jian; Kleff, Susanne; Guettler, Michael V

    2013-04-30T23:59:59.000Z

    Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

  2. Recombinant microorganisms for increased production of organic acids

    DOE Patents [OSTI]

    Yi, Jian (East Lansing, MI); Kleff, Susanne (East Lansing, MI); Guettler, Michael V. (Holt, MI)

    2012-02-21T23:59:59.000Z

    Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

  3. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    560-49072 September 2010 Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis Robert Remick National Renewable Energy Laboratory Douglas Wheeler...

  4. acid patterns early: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N and AAs in lakes, we measured Wehrli, Bernhard 25 Taxonomy of Amanita mushrooms by pattern recognition of amino acid chromatographic data CiteSeer Summary: Pattern...

  5. acid medium application: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University - TxSpace Summary: substrate and their catalytic function takes place in acid medium. This harsh environment causes an undesired reaction, which is the dissolution of...

  6. acid dissolution ensayos: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University - TxSpace Summary: substrate and their catalytic function takes place in acid medium. This harsh environment causes an undesired reaction, which is the dissolution of...

  7. acid energy percentage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their distribution in known structures with experimental data such as amino acid transfer free energy scales (water to membrane center and water Senes, Alessandro 8 Evaluation of...

  8. acid house music: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Asia MUSIC 1360 Global Popular Music MUSIC 1394 Intercultural Music MUSIC 1396 Music in Society MUSIC 1398 Women Jiang, Huiqiang 9 Using Amino Acids Composition Combined with...

  9. Amino acid treatment enhances protein recovery from sediment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment enhances protein recovery from sediment and soils for metaproteomic studies . Amino acid treatment enhances protein recovery from sediment and soils for metaproteomic...

  10. acid doped polybenzimidazole: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arayaa , Sren without the need for break in. Keywords: High temperature PEM fuel cell; Impedance spectroscopy; Break in- brane (HTPEM) fuel cells based on phosphoric acid...

  11. acid production plant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: . - ,, ,,, , -,, . 12;Volatile fatty acids (VIA), produced mainly from fermentation of carbohydrates in the ration of carbohydrates and the production of VFA have not...

  12. acids mono 2ethylhexyl: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coated with thin films of nanoporous titanium; continuous-flow photocatalytic reactor; electrodeless discharge lamp; mono-chloroacetic acid; nanoporous Cirkva, Vladimir 350...

  13. acid fast bacilli: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Fast Bacilli in a Low- Incidence Setting CiteSeer Summary: Introduction: Light emitting diode fluorescence microscopes have many practical advantages over conventional...

  14. acetal benzoic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  15. aqueous hydrochloric acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nitrate Lithium Potassium ferrocyanide Potassium hydroxide Potassium iodide Potassium nitrate Potassium oxalate Potassium Chan, Hue Sun 34 Hydrochloric Acid-Catalyzed Levulinic...

  16. acid mmaiii leads: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theses and Dissertations Summary: ??The performance of lead-acid batteries for energy storage in photovoltaicdieselbattery hybrid systems strongly depends on several...

  17. Sandia National Laboratories: Due Diligence on Lead Acid Battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the lead acid batteries are processed and recycled legally under a regularly audited New Mexico hazardous waste management permit, Pollution Prevention (P2) was prompted to...

  18. acids structures applied: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Treatment of software French, James C. 5 Parsing nucleic acid pseudoknotted secondary structure: algorithm and applications Computer Technologies and Information Sciences...

  19. acid binding protein: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Richardson, Charles C. 17 Acidic pH Changes Receptor Binding Specificity of Helicobacter pylori: a Binary Adhesion Model in which Surface Heat Shock (Stress) Proteins...

  20. amino acid conjugates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the measured distributions. Guang Wu; Shaomin Yan 71 Amino acid classes and the protein folding problem Condensed Matter (arXiv) Summary: We present and implement a...

  1. acid degradation products: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFRICAN DWARF SHEEP CiteSeer Summary: This study describes the effect of intraruminal infusion of different proportions of palmitic (saturated fatty acid) and linolenic...

  2. amino acid oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were hysterectomized... Kwon, Hyuk Jung 2005-08-29 4 Effect of Intravenous Amino Acid Infusion on Leucine Oxidation Across the Mammary Gland Biology and Medicine Websites Summary:...

  3. amino acid limitation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of energy requirements for milk production. The protein deficiency was alleviated by infusion Bequette, Brian J. 3 Enantiomeric separation of amino acids and nonprotein amino...

  4. amino acid production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of energy requirements for milk production. The protein deficiency was alleviated by infusion Bequette, Brian J. 2 METHODS TO DETERMINE AMINO ACID DIGESTIBILITY IN CiteSeer...

  5. acid aerosol exposure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nenes, Athanasios 8 Neutralization of soil aerosol and its impact on the distribution of acid rain over east Asia Geosciences Websites Summary: Neutralization of soil aerosol and...

  6. acidic conjugate cleavage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Studies on Persistent Intramolecular CHX (X O, S, Br, Cl, and F) Hydrogen Bonds Involving Benzyl Meldrums Acids. Open Access Theses and Dissertations...

  7. ascorbic acid reverses: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Containing Chimeric Amino Acids as Preferred Reverse-Turn Ye Che and Garland R. Marshall* Biology and Medicine Websites Summary: making almost a complete 180 turn in...

  8. acid reverses valproic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Containing Chimeric Amino Acids as Preferred Reverse-Turn Ye Che and Garland R. Marshall* Biology and Medicine Websites Summary: making almost a complete 180 turn in...

  9. THYROID HORMONE REVERSES AGING-INDUCED MYOCARDIAL FATTY ACID...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    occurs during aging in humans and mice and may contribute to development of heart failure. Aging also impairs myocardial fatty acid oxidation, causing increased...

  10. acids suppresses diethylnitrosamine-induced: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Suppression of rice methane emission by sulfate deposition in simulated acid rain Geosciences Websites Summary: from rice agriculture. Emissions from rice plants...

  11. acid suppression therapy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2006-01-01 2 Suppression of rice methane emission by sulfate deposition in simulated acid rain Geosciences Websites Summary: from rice agriculture. Emissions from rice plants...

  12. acid fgd additives: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of sulfur dioxide into the atmosphere. Efforts to curb damage to the environment by acid rain has necessitated the construction of flue gas desulfurization (FGD) systems...

  13. acid biosensor based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    biosensors of nucleic acids and proteins for point- of-care (POC. The merger of microfluidics and advanced biosensor technolo- gies offers new promises for POC diagnostics...

  14. AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid...

    Broader source: Energy.gov (indexed) [DOE]

    and development. The following reports describe results of testing done on a 2010 Civic hybrid electric vehicle with an advanced experimental ultra-lead acid battery, an...

  15. abscisic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the...

  16. arachidonic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the...

  17. acid hydroperoxide lyase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the...

  18. acid detergent fiber: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recent work on pretreatment techniques includes: pretreatment of cedar with peracetic acid and steam explosion to improve... AMMONIA FIBER EXPLOSION (AFEX) TREATMENT OF GRASS A...

  19. ascorbic acid oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    regulation of L Clarke, Steven 88 Co-oxidation in supercritical water : methylphosphonic acid-ethanol and ammonia-ethanol model systems MIT - DSpace Summary: Supercritical water...

  20. acid intakes decrease: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Information Sciences Websites Summary: Original article Enhancement of oleic acid and vitamin E concentrations of bovine milk using dietary supplements of whole...

  1. acid oxidation disorders: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and tau) and lipid oxidationmetabolism alterations in its pathogenesis. In (more) Smith, Simon 2011-01-01 5 Oxidation of Some ?-Amino Acids by Peroxydisulfate in an...

  2. acidic soil isolates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil pH indicates its alkalinity or acidity. This property influences soil chemistry and crop production. A low maintenance ROSS Ultra Triodeguarantees accurate measurement of...

  3. aquatic humic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XI, Universit de 5 UV Irradiation and Humic Acid Mediate Aggregation of Aqueous Environmental Management and Restoration Websites Summary: 10, 2010. Accepted September...

  4. Naphthenic acid corrosion and its control

    SciTech Connect (OSTI)

    Zetlmeisl, M.J. [Petrolite Corp., St. Louis, MO (United States)

    1996-08-01T23:59:59.000Z

    This paper first presents a brief description of naphthenic acid corrosion and the main factors which influence its onset and severity. After a brief discussion of traditional control methods, it proceeds to a discussion of chemical inhibition, which is a relatively new control technique. Chemical inhibitors can be divided into two broad classifications: phosphorus-based and non-phosphorus-based. Three types of phosphorus-based inhibitors have been reported: amine-neutralized phosphate esters, alkaline earth phosphonate phenate sulfide plus trialkyl phosphate, and thiazolines plus di and tri-alkyl phosphates. Non-phosphorus based inhibitors include: thiazolines, organic polysulfides, and sulfonated alkyl phenols. A description of each inhibitor and its effectiveness in the laboratory and field is presented.

  5. Active Phosphoric Acid and Its Relation to the Needs of the Soil for Phosphoric Acid in Pot Experiments.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1909-01-01T23:59:59.000Z

    . K/5 nitric acid, measured with a flask. Place in ter bath previously heated to 40" C. Digest five hours, shak- ?very half hour. Filter on a large'double folded filter. When cola, take 1800 c.c. for the estimation of phosphoric acid and potael... and silica. The filtrate was measured ancl its vol- ume recorded. The soil on the filter paper was washed back into the bottle with 2000 c.c. N,'5 nitric acid, and again digested. Fonr treatments in all were made with the acid, The quantity of phosphorjc...

  6. EFFECTS OF NITRIC ACID ON CRITICALITY SAFETY ANALYSIS

    SciTech Connect (OSTI)

    Williamson, B.

    2011-08-18T23:59:59.000Z

    As nitric acid molarity is increased, there are two competing phenomena affecting the reactivity of the system. First, there is interaction between each of the 10 wells in the basket-like insert. As the molarity of the nitric acid solution is increased (it moves from 100% water to 100% HNO{sub 3}), the hydrogen atom density decreases by about 80%. However, it remains a relatively efficient moderator. The moderating ratio of nitric acid is about 90% that of water. As the media between the wells is changed from 100% water to 100% nitric acid, the density of the media increases by 50%. A higher density typically leads to a better reflector. However, when the macroscopic scattering cross sections are considered, nitric acid is a much worse reflector than water. The effectiveness of nitric acid as a reflector is about 40% that of water. Since the media between the wells become a worse reflector and still remains an effective moderator, interaction between the wells increases. This phenomenon will cause reactivity to increase as nitric acid molarity increases. The seond phenomenon is due to the moderating ratio changing in the high concentration fissile-nitric acid solution in the 10 wells. Since the wells contain relatively small volumes of high concentration solutions, a small decrease in moderating power has a large effect on reactivity. This is due to the fact that neutrons are more likely to escape the high concentration fissile solution before causing another fission event. The result of this phenomenon is that as nitric acid molarity increases, reactivity decreases. Recent studies have shown that the second phenomenon is indeed the dominating force in determining reactivity changes in relation to nitric acid molarity changes. When considering the system as a whole, as nitric acid molarity increases, reactivity decreases.

  7. Human platelet aggregation and phospholipid fatty acid composition during omega-3 fatty acid enriched egg consumption: influence of nutrient intake and omega-3 fatty acid source

    E-Print Network [OSTI]

    Hatch, Sandra D

    1997-01-01T23:59:59.000Z

    The current study investigated the usefulness of omega-3 polyunsaturated fatty acid (n-3 PUFA) enriched eggs for duplicating health benefits of consuming fish, specifically decreasing platelet aggregation via changes in plasma phospholipid (PL...

  8. CHARACTERIZATION OF INVASION PLASMID ANTIGEN B AND C (IpaB AND IpaC) TRANSLOCATOR COMPLEXES AND TRANSLOCATOR/CHAPERONE COMPLEXES OF Shigella flexneri

    E-Print Network [OSTI]

    Terry, Christina Marie

    2008-08-08T23:59:59.000Z

    M Citrate Phosphate Buffer, pH 7 Solution 1(0.4 M Sodium phosphate dibasic) 56.78 g Na2HPO2, anhydrous 1.00 L diH2O Solution 2 (0.4 M Citric Acid) 76.85 g C6H8O7, anhydrous 1.00 L diH2O (90 ml Solution 1) + (10 ml of Solution 2) + (1900 ml diH2O... for disease in humans and primates. Like other organisms belonging to this family, Shigella is facultatively anaerobic, oxidase negative and possesses the abilities to reduce nitrate and ferment glucose. Differentiation among the species can...

  9. AcidBase Regulation in Fishes: Cellular and Molecular Mechanisms

    E-Print Network [OSTI]

    Claiborne, James Berkeley

    , and functional studies that have begun to define the protein transporters involved in the acid­base relevant ion gill membrane transport processes in acid­base balance. J. Exp. Zool. 293:302­319, 2002. r 2002 Wiley on recent advances in our understand- ing of membrane transport systems which are responsible for the net

  10. Selective Lability of Ruthenium(II) Arene Amino Acid Complexes

    E-Print Network [OSTI]

    Scrase, Tom G.; ONeill, Michael J.; Peel, Andrew J.; Senior, Paul W.; Matthews, Peter D.; Shi, Heyao; Boss, Sally R.; Barker, Paul D.

    2015-02-16T23:59:59.000Z

    (DAP) 1 -NH2 2 L-2,4-diamino-butanoic acid (DAB) 2 -NH2 3 L-Ornithine 3 -NH2 4 L-Lysine 4 -NH2 5 L-Histidine 2 -Imidazole 6 L-Methionine 2 -SMe 7 * L-Aspartate 2 -COO- Table 1: Summary of the tridentate amino acid complexes under investigation...

  11. Evaporative Hydrochloric Acid Recovery: Something Old, Something New...

    E-Print Network [OSTI]

    Cullivan, B.

    . If zinc is present from the pickling of galvanizing racks or stripping of parts, the zinc concentration will range from as low as zinc chloride solution remains. In the evaporative process of the Hydrochloric Acid Recovery System, the waste acid is pumped through a pre-filter into the evaporator section oftI1e recovery system. This solution is heated by means...

  12. Surface-active properties of humic and sulfochlorohumic acids

    SciTech Connect (OSTI)

    Ryabova, I.N.; Mustafina, G.A.; Akkulova, Z.G.; Satymbaeva, A.S. [Kazakh Academy of Sciences, Karaganda (Kazakhstan)

    2009-10-15T23:59:59.000Z

    The surface tension of alkaline solutions of humic acids and their sulfochloroderivatives, which are synthesized by sulfonation of chlorohumic acids isolated from coal chlorinated by the electrochemical method, is investigated. It is established that humic compounds possess weak surface activity. Basic adsorption parameters are calculated.

  13. Preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters

    DOE Patents [OSTI]

    Gogate, Makarand Ratnakar (Durham, NC); Spivey, James Jerry (Cary, NC); Zoeller, Joseph Robert (Kingsport, TN)

    1998-01-01T23:59:59.000Z

    Disclosed is a process for the preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

  14. Production of hydroxylated fatty acids in genetically modified plants

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Lexington, KY)

    2001-01-01T23:59:59.000Z

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants.

  15. Boron-containing amino carboxylic acid compounds and uses thereof

    DOE Patents [OSTI]

    Kabalka, George W. (Knoxville, TN); Srivastava, Rajiv R. (Knoxville, TN)

    2000-03-14T23:59:59.000Z

    Novel compounds which are useful for boron neutron capture therapy (BNCT) are disclosed. The compounds comprise a stable boron-containing group and an aminocycloalkane carboxylic acid group or a boronated acyclic hydrocarbon-linked amino carboxylic acid. Methods for synthesis of the compounds and for use of the compounds in BNCT are disclosed.

  16. Site specific incorporation of keto amino acids into proteins

    DOE Patents [OSTI]

    Schultz, Peter G. (La Jolla, CA); Wang, Lei (San Diego, CA)

    2009-04-28T23:59:59.000Z

    Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate keto amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with keto amino acids using these orthogonal pairs.

  17. Effects of the Biologically Produced Polymer Alginic Acid on

    E-Print Network [OSTI]

    . Using a combined atomic force microscopy (AFM)/flow- through reactor apparatus, we investigated. In alginic acid, the acute step retreat rate is nearly unchanged in comparison to water, whereas the obtuse but propagate faster in the obtuse direction. To explain these observations, we propose that alginic acid

  18. Production of amino acids using auxotrophic mutants of methylotrophic bacillus

    SciTech Connect (OSTI)

    Hanson, Richard S. (Wayzata, MN); Flickinger, Michael C. (St. Paul, MN); Schendel, Frederick J. (Falcon Heights, MN); Guettler, Michael V. (Waconia, MN)

    2001-07-17T23:59:59.000Z

    A method of producing amino acids by culturing an amino acid auxotroph of a biologically pure strain of a type I methylotrophic bacterium of the genus Bacillus which exhibits sustained growth at 50.degree. C. using methanol as a carbon and energy source and requiring vitamin B.sub.12 and biotin is provided.

  19. Propionic-Acid-Terminated Silicon Nanoparticles: Synthesis and Optical Characterization

    E-Print Network [OSTI]

    Swihart, Mark T.

    producing water-dispersible, propionic-acid-terminated particles. From transmission electron microscope (TEM oxidation of the nanocrystals. The silicon nanocrystals could be transferred into water or methanol in acrylic acid, water, and methanol and showed essentially the same optical properties in all three solvents

  20. Selective Monosaccharide Transport through Lipid Bilayers Using Boronic Acid Carriers

    E-Print Network [OSTI]

    Smith, Bradley D.

    Selective Monosaccharide Transport through Lipid Bilayers Using Boronic Acid Carriers Pamela R-one boronic acids were studied for their ability to transport saccharides in and out of liposomes. The rates transport. The order of transport selectivity was sorbitol > fructose > glucose. The disaccharides maltose