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Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials  

E-Print Network [OSTI]

nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

Duffy, Thomas S.

2

Double bevel construction of a diamond anvil  

DOE Patents [OSTI]

A double or multiple bevel culet geometry is used on a diamond anvil in a high pressure cell apparatus to provide increased sample pressure and stability for a given force applied to the diamond tables. Double or multiple bevel culet geometries can also be used for sapphire or other hard crystal anvils. Pressures up to and above 5 Megabars can be reached. 8 figs.

Moss, W.C.

1988-10-11T23:59:59.000Z

3

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear  

DOE Patents [OSTI]

Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

1997-01-14T23:59:59.000Z

4

X-Ray Diamond Anvil Cell Facility at NSLS: 2010 Progress Report  

E-Print Network [OSTI]

X-Ray Diamond Anvil Cell Facility at NSLS: 2010 Progress Report Zhiqiang ChenZhiqiang Chen Stony) Powder X-ray Diffraction, Total Scattering Pair-Distributiony , g Function (PDF) under high P and high, yield strength, amorphization, texturing, compressibility Hydrothermal DAC (Bassett) Angle Dispersive X-ray

Duffy, Thomas S.

5

Double bevel construction of a diamond anvil  

DOE Patents [OSTI]

Use of double or multiple bevel culet geometry on a diamond anvil to provide increased sample pressure and stability for a given force applied to the diamond tables. 7 figs.

Moss, W.C.

1987-02-06T23:59:59.000Z

6

A compact bellows-driven diamond anvil cell for high-pressure, low-temperature magnetic measurements  

SciTech Connect (OSTI)

We present the design of an efficient bellows-controlled diamond anvil cell that is optimized for use inside the bores of high-field superconducting magnets in helium-3 cryostats, dilution refrigerators, and commercial physical property measurement systems. Design of this non-magnetic pressure cell focuses on in situ pressure tuning and measurement by means of a helium-filled bellows actuator and fiber-coupled ruby fluorescence spectroscopy, respectively. We demonstrate the utility of this pressure cell with ac susceptibility measurements of superconducting, ferromagnetic, and antiferromagnetic phase transitions to pressures exceeding 8 GPa. This cell provides an opportunity to probe charge and magnetic order continuously and with high resolution in the three-dimensional Magnetic Field–Pressure–Temperature parameter space.

Feng, Yejun [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States); Silevitch, D. M.; Rosenbaum, T. F. [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)] [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)

2014-03-15T23:59:59.000Z

7

Sound speed and thermal property measurements of inert materials: laser spectroscopy and the diamond-anvil cell  

SciTech Connect (OSTI)

An indispensable companion to dynamical physics experimentation, static high-pressure diamond-anvil cell research continues to evolve, with laser diagnostic, as an accurate and versatile experimental deep planetary properties have bootstrapped each other in a process that has produced even higher pressures; consistently improved calibrations of temperature and pressure under static and dynamic conditions; and unprecedented data and understanding of materials, their elasticity, equations of state (EOS), and transport properties under extreme conditions. A collection of recent pressure and/or temperature dependent acoustic and thermal measurements and deduced mechanical properties and EOS data are summarized for a wide range of materials including H2, H2O, H2S, D2S, CO2, CH4, N2O, CH3OH,, SiO2, synthetic lubricants, PMMA, single crystal silicates, and ceramic superconductors. Room P&T sound speed measurements are presented for the first time on single crystals of beta-HMX. New high-pressure and temperature diamond cell designed and pressure calibrant materials are reviewed.

Zaug, J.M.

1997-07-01T23:59:59.000Z

8

Large volume high-pressure cell with supported moissanite anvils  

SciTech Connect (OSTI)

The recently developed moissanite anvil cell (MAC) has become a useful device for achieving both high-pressure and large sample volume in an anvil cell. We describe two improvements in the basic design of the MAC. First, the loading environment has been optimized by centering the load. Second, a variety of supported systems have been examined to provide anvil stability at high loads with large anvils. Sample volumes that are nearly three orders magnitude greater than allowed by conventional diamond anvil cells can be pressurized and characterized at {approx}50 GPa.

Xu, J.; Mao, H.-k.; Hemley, R.J.; Hines , E. (CIW/GL)

2010-11-16T23:59:59.000Z

9

Development of Designer Diamond Anvils for High Pressure-High-Temperature Experiments in Support of the Stockpile Stewardship Program  

SciTech Connect (OSTI)

The focus of this program at the University of Alabama at Birmingham (UAB) is to develop the next generation of designer diamond anvils that can perform simultaneous joule heating and temperature profile measurements in a diamond anvil cell. A series of tungsten-rhenium thermocouples will be fabricated onto to the anvil and encapsulated by a chemical vapor deposited diamond layer to allow for a complete temperature profile measurement across the anvil. The tip of the diamond anvil will be engineered to reduce the thermal conductivity so that the tungsten-heating coils can be deposited on top of this layer. Several different approaches will be investigated to engineer the tip of the diamond anvil for reduction in thermal conductivity (a) isotopic mixture of 12C and 13C in the diamond layer, (b) doping of diamond with impurities (nitrogen and/or boron), and (c) growing diamond in a higher concentration of methane in hydrogen plasma. Under this academic alliance with Lawrence Livermore National Laboratory (LLNL), PI and his graduate students will use the lithographic and diamond polishing facility at LLNL. This proposed next generation of designer diamond anvils will allow multi-tasking capability with the ability to measure electrical, magnetic, structural and thermal data on actinide materials with unparallel sensitivity in support of the stockpile stewardship program.

Yogesh K. Vohra

2005-05-12T23:59:59.000Z

10

Plasma etching of cavities into diamond anvils for experiments at high pressures and high temperatures  

SciTech Connect (OSTI)

We describe a method for precisely etching small cavities into the culets of diamond anvils for the purpose of providing thermal insulation for samples in experiments at high pressures and high temperatures. The cavities were fabricated using highly directional oxygen plasma to reactively etch into the diamond surface. The lateral extent of the etch was precisely controlled to micron accuracy by etching the diamond through a lithographically fabricated tungsten mask. The performance of the etched cavities in high-temperature experiments in which the samples were either laser heated or electrically heated is discussed.

Weir, S.T.; Cynn, H.; Falabella, S.; Evans, W.J.; Aracne-Ruddle, C.; Farber, D.; Vohra, Y.K. (LLNL); (UAB)

2012-10-23T23:59:59.000Z

11

Cell assemblies for reproducible multi-anvil experiments (the COMPRES assemblies)  

SciTech Connect (OSTI)

The multi-anvil high-pressure technique is an important tool in high-pressure mineralogy and petrology, as well as in chemical synthesis, allowing the treatment of large (millimeter-size) samples of minerals, rocks, and other materials at pressures of a few GPa to over 25 GPa and simultaneous uniform temperatures up to 2500 C and higher. A series of cell assemblies specially designed and implemented for interlaboratory use are described here. In terms of the size of the pressure medium and the anvil truncation size, the five sizes of assemblies developed here are an 8/3, 10/5, 14/8, 18/12, and 25/15 assembly. As of this writing, these assemblies are in widespread use at many laboratories. The details of design, construction, and materials developed or used for the assemblies are presented here.

Leinenweber, Kurt D.; Tyburczy, James A.; Sharp, Thomas G.; Soignard, Emmanuel; Diedrich, Tamara; Petuskey, William B.; Wang, Yanbin; Mosenfelder, Jed L. (CIT); (AZU); (UC)

2012-01-31T23:59:59.000Z

12

High efficiency diamond solar cells  

DOE Patents [OSTI]

A photovoltaic device and method of making same. A layer of p-doped microcrystalline diamond is deposited on a layer of n-doped ultrananocrystalline diamond such as by providing a substrate in a chamber, providing a first atmosphere containing about 1% by volume CH.sub.4 and about 99% by volume H.sub.2 with dopant quantities of a boron compound, subjecting the atmosphere to microwave energy to deposit a p-doped microcrystalline diamond layer on the substrate, providing a second atmosphere of about 1% by volume CH.sub.4 and about 89% by volume Ar and about 10% by volume N.sub.2, subjecting the second atmosphere to microwave energy to deposit a n-doped ultrananocrystalline diamond layer on the p-doped microcrystalline diamond layer. Electrodes and leads are added to conduct electrical energy when the layers are irradiated.

Gruen, Dieter M. (Downers Grove, IL)

2008-05-06T23:59:59.000Z

13

E-Print Network 3.0 - anvil apparatus bars Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pressure D. B. McWhan Summary: pressures above 5 GPa it is necessary to change from a piston cylinder design to an anvil apparatus. Opposed... diamond anvil high pressure...

14

sures between 0 and 10 GPa were applied with a diamond anvil cell (DAC) and were measured with  

E-Print Network [OSTI]

. Faraday Soc. 1935 (1935). 18. X. Y. Li, R. Jeanloz, Phys. Rev. B 36, 474 (1987). 19. F. P. Bundy, Proc. K, Berke- ley (1997). 30. L. D. Landau, E. Lifshitz, Statistical physics, J. B. Sykes, M. J. Kearsley, Eds

Goddard III, William A.

15

Synthesis and characterization of a nanocrystalline diamond aerogel  

SciTech Connect (OSTI)

Aerogel materials have myriad scientific and technological applications due to their large intrinsic surface areas and ultralow densities. However, creating a nanodiamond aerogel matrix has remained an outstanding and intriguing challenge. Here we report the high-pressure, high-temperature synthesis of a diamond aerogel from an amorphous carbon aerogel precursor using a laser-heated diamond anvil cell. Neon is used as a chemically inert, near-hydrostatic pressure medium that prevents collapse of the aerogel under pressure by conformally filling the aerogel's void volume. Electron and X-ray spectromicroscopy confirm the aerogel morphology and composition of the nanodiamond matrix. Time-resolved photoluminescence measurements of recovered material reveal the formation of both nitrogen- and silicon- vacancy point-defects, suggesting a broad range of applications for this nanocrystalline diamond aerogel.

Pauzauskie, Peter J.; Crowhurst, Jonathan C.; Worsley, Marcus A.; Laurence, Ted A.; Kilcoyne, A. L. David; Wang, Yinmin; Willey, Trevor M.; Visbeck, Kenneth S.; Fakra, Sirine C.; Evans, William J.; Zaug, Joseph M.; Satcher, Jr., Joe H.

2011-07-06T23:59:59.000Z

16

Synthesis of new Diamond-like B-C Phases under High Pressure and Temperatures  

SciTech Connect (OSTI)

A cubic BC3 (c-BC3) phase was synthesized by direct transformation from graphitic phases at a pressure of 39 GPa and temperature of 2200 K in a laser-heated diamond anvil cell (DAC). A combination of x-ray diffraction (XRD), electron diffraction (ED), transmission electron microscopy (TEM) imaging, and electron energy loss spectroscopy (EELS) measurements lead us to conclude that the obtained phase is hetero-nano-diamond, c-BC3. The EELS measurements show that the atoms inside the cubic structure are bonded by sp3 bonds.

Ming, L. C. [University of Hawaii] [University of Hawaii; Zinin, P. V. [University of Hawaii] [University of Hawaii; Sharma, S. K. [University of Hawaii] [University of Hawaii

2014-04-22T23:59:59.000Z

17

Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications.  

SciTech Connect (OSTI)

The original funding under this project number was awarded for a period 12/1999 until 12/2002 under the project title Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications. The project was extended until 06/2003 at which time a renewal proposal was awarded for a period 06/2003 until 06/2008 under the project title Metal/Diamond Composite Thin-Film Electrodes: New Carbon Supported Catalytic Electrodes. The work under DE-FG02-01ER15120 was initiated about the time the PI moved his research group from the Department of Chemistry at Utah State University to the Department of Chemistry at Michigan State University. This DOE-funded research was focused on (i) understanding structure-function relationships at boron-doped diamond thin-film electrodes, (ii) understanding metal phase formation on diamond thin films and developing electrochemical approaches for producing highly dispersed electrocatalyst particles (e.g., Pt) of small nominal particle size, (iii) studying the electrochemical activity of the electrocatalytic electrodes for hydrogen oxidation and oxygen reduction and (iv) conducting the initial synthesis of high surface area diamond powders and evaluating their electrical and electrochemical properties when mixed with a Teflon binder.

Swain; Greg M.

2009-04-13T23:59:59.000Z

18

Experiment Hazard Class 5.1 - High Pressures - Diamond Anvil...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- None Personal Protective Equipment - Safety glasses with side shields that meet ANSI Z87 requirements. Experiment Authorization Unless otherwise noted in the approved...

19

Diamond-Like Carbon Coatings as Encapsulants for Photovoltaic Solar Cells  

SciTech Connect (OSTI)

High-quality single-layer and bilayer diamond-like carbon (DLC) thin films are fabricated by two technologies, namely, ion-assisted plasma-enhanced deposition (IAPED) and electron cyclotron resonance (ECR) deposition. Deposition on various substrates, such as sapphires and solar cells, has been performed at low substrate temperatures (50 {approx} 80 C). The two deposition technologies allow good control over the growth conditions to produce DLC films with desired optical properties, thickness, and energy bandgap. The bilayer-structured DLC can be fabricated by using IAPED for the bottom layer followed by ECR for the top layer, or just by IAPED for both layers with different compositions. The DLC films have shown good spatial uniformity, density, microhardness, and adhesion strength. They exhibit excellent stability against attack by strong acids, prolonged damp-heat exposure at 85 C and 85% relative humidity, mechanical scratch, ultrasonication, and irradiation by ultraviolet (UV), protons, and electrons. When deposited on crystalline Si and GaAs solar cells in single-layer and/or bilayer structure, the DLC films not only serve as antireflection coating and protective encapsulant, but also improve the cell efficiencies.

Pern, F. J.; Panosyan, Zh.; Gippius, A. A.; Kontsevoy, J. A.; Touryan, K.; Voskanyan, S.; Yengibaryan, Y.

2005-02-01T23:59:59.000Z

20

Fabrication of highly transparent diamond-like carbon anti-reflecting coating for Si solar cell application  

SciTech Connect (OSTI)

ARC grade highly transparent unhydrogenated diamond-like carbon (DLC) films were produced, directly from a-C target, using RF magnetron sputtering deposition technique, for optoelectronic applications. Optical band gap, transmittance, reflectance, sp{sup 3} fraction, I{sub D}/I{sub G}, density, and refractive index of the films have been estimated with the help of optical tools like Uv-vis spectrophotometer, ellipsometer and micro-Raman. Optimum ARC-qualities have been identified in low-temperature grown DLC films at an Ar pressure of 4 mTorr in the reactor, accomplishing its key requirements for use in silicon solar cells.

Banerjee, Amit, E-mail: erdd@iacs.res.in; Das, Debajyoti, E-mail: erdd@iacs.res.in [Nano-Science Group, Energy Research Unit, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032 (India)

2014-04-24T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Development of Designer Diamond Technology for High Pressure High Temperature Experiments in Support of Stockpile Stewardship Program  

SciTech Connect (OSTI)

The role of nitrogen in the fabrication of designer diamond was systematically investigated by adding controlled amount of nitrogen in hydrogen/methane/oxygen plasma. This has led to a successful recipe for reproducible fabrication of designer diamond anvils for high-pressure high-temperature research in support of stockpile stewardship program. In the three-year support period, several designer diamonds fabricated with this new growth chemistry were utilized in high-pressure experiments at UAB and Lawrence Livermore National Laboratory. The designer diamond anvils were utilized in high-pressure studies on heavy rare earth metals, high pressure melting studies on metals, and electrical resistance measurements on iron-based layered superconductors under high pressures. The growth chemistry developed under NNSA support can be adapted for commercial production of designer diamonds.

Vohra, Yogesh, K.

2009-10-28T23:59:59.000Z

22

Diamond fiber field emitters  

DOE Patents [OSTI]

A field emission electron emitter comprising an electrode formed of at least one diamond, diamond-like carbon or glassy carbon composite fiber, said composite fiber having a non-diamond core and a diamond, diamond-like carbon or glassy carbon coating on said non-diamond core, and electronic devices employing such a field emission electron emitter.

Blanchet-Fincher, Graciela B. (Wilmington, DE); Coates, Don M. (Santa Fe, NM); Devlin, David J. (Los Alamos, NM); Eaton, David F. (Wilmington, DE); Silzars, Aris K. (Landenburg, PA); Valone, Steven M. (Santa Fe, NM)

1996-01-01T23:59:59.000Z

23

Anvil effect in spherical indentation testing on sheet metal  

E-Print Network [OSTI]

A spherical indentation test is considered to be invalid if there is presence of a visible mark on the side of the sheet metal facing the anvil and exactly below the indentation. With the available standard loads of the conventional testers...

Dhaigude, Mayuresh Mukund

2009-06-02T23:59:59.000Z

24

A diamond-window XAFS cell for studies of high-temperature, high-pressure aqueous solutions  

SciTech Connect (OSTI)

We describe a method to collect x-ray absorption fine structure (XAFS) spectra of ions in a supercritical water solvent. Supercritical water (SCW), at temperatures above water{close_quote}s critical point of 374{degree}C, is an interesting solvent for chemical reactions and hazardous waste destruction due to the high solubility of organics and the aggressive oxidizing environment. XAFS may provide a better understanding of the solvent environment in SCW. The XAFS cell used in these studies was composed of a block of high-nickel alloy, Hastelloy C-22, containing two windows for transmission of the x-ray beam and a single optical view window. All internal wetted surfaces were platinum plated. The maximum operating conditions for this design were 500{degree}C and 700 bar. The x-ray transmission windows consisted of CVD (chemical vapor deposition) diamond windows (3 mm diameter {times}0.5 mm thick) that were brazed to the tip of a standard 1/4-in. high-pressure, coned-shape fitting. Spectra are reported for strontium and rubidium ions in a supercritical water solvent. This cell design could be used for a variety of other solvent systems at high temperatures and high pressures. {copyright} {ital 1996 American Institute of Physics.}

Fulton, J.L.; Pfund, D.M. [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States)] [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States); Ma, Y. [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)] [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)

1996-09-01T23:59:59.000Z

25

E-Print Network 3.0 - anvil cirrus parameterization Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2007 Cirrus in convective Summary: detrained anvils. 1 Introduction15 Upper tropospheric ice clouds in the tropics (tropical cirrus) have... with the conclusions of Mace et al....

26

Diamond and Polycrystalline Diamond for MEMS Applications: Simulations and Experiments  

E-Print Network [OSTI]

Diamond and Polycrystalline Diamond for MEMS Applications: Simulations and Experiments Tahir C¸ a on Silicon and polycrystalline diamond show that this rapid wear is caused by a variety of factors, related processes on diamond surfaces. We studied the atomic friction of diamond (100)­surface employing an extended

Çagin, Tahir

27

Stability and breakdown of Ca{sup 13}CO{sub 3} melt associated with formation of {sup 13}C-diamond in static high pressure experiments up to 43 GPa and 3900 K  

SciTech Connect (OSTI)

Melting of calcium carbonate Ca{sup 13}CO{sub 3}, stability of the melt and its decomposition were studied in static high pressure experiments at pressures of 11-43 GPa and temperatures of 1600-3900 K using diamond anvil cell technique with laser heating. We observed formation of {sup 13}C-graphite (below 16 GPa) and {sup 13}C-diamond (between 16 and 43 GPa) on decomposition of the Ca{sup 13}CO{sub 3} melt at temperatures above 3400 K. At temperatures below 3400 K congruent melting of calcium carbonate was confirmed. The experimental results were applied to construction of the phase diagram of CaCO{sub 3} up to 43 GPa and 3900 K focusing at the melting curve of calcium carbonate and the decomposition phase boundary of CaCO{sub 3} melt. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer Phase states of CaCO{sub 3} were studied at P=11-43 GPa and T=1600-3900 K. Black-Right-Pointing-Pointer {sup 13}C-diamond easily crystallizes in carbonate-carbon (Ca{sup 13}CO{sub 3-}{sup 13}C-graphite) melt-solutions. Black-Right-Pointing-Pointer Ca-carbonate melts congruently that was observed in experiments in DAC with laser heating. Black-Right-Pointing-Pointer Decomposition of CaCO{sub 3} melt, indicated by formation of graphite and/or diamond. Black-Right-Pointing-Pointer Decomposition of CaCO{sub 3} was observed at temperatures above 3400 K in the pressure interval studied.

Spivak, A.V., E-mail: spivak@iem.ac.ru [Institute of Experimental Mineralogy of the Russian Academy of Sciences, Chernogolovka, Moscow Region (Russian Federation); Litvin, Yu.A. [Institute of Experimental Mineralogy of the Russian Academy of Sciences, Chernogolovka, Moscow Region (Russian Federation); Ovsyannikov, S.V. [Bayerishes Geoinstitut, University of Bayreuth, Bayreuth (Germany); Dubrovinskaia, N.A. [Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, Bayreuth (Germany); Dubrovinsky, L.S. [Bayerishes Geoinstitut, University of Bayreuth, Bayreuth (Germany)

2012-07-15T23:59:59.000Z

28

CURRICULUM VITAE Howard J. Diamond  

E-Print Network [OSTI]

______________________ CURRICULUM VITAE FOR Howard J. Diamond ______________________ NOAA.diamond@noaa.gov or hjdiamond45@gmail.com #12;Curriculum Vitae Mr. Howard Jeffrey Diamond NOAA/National Climatic Data Center

29

Electrically conductive polycrystalline diamond and particulate metal based electrodes  

DOE Patents [OSTI]

An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

Swain, Greg M.; Wang, Jian

2005-04-26T23:59:59.000Z

30

Diamond films: Historical perspective  

SciTech Connect (OSTI)

This section is a compilation of notes and published international articles about the development of methods of depositing diamond films. Vapor deposition articles are included from American, Russian, and Japanese publications. The international competition to develop new deposition methodologies is stressed. The current status of chemical vapor deposition of diamond is assessed.

Messier, R. [Pennsylvania State Univ., University Park (United States)

1993-01-01T23:59:59.000Z

31

Diamond nucleation using polyethene  

DOE Patents [OSTI]

The invention presents a simple, non-destructive and non-abrasive method of diamond nucleation using polyethene. It particularly describes the nucleation of diamond on an electrically viable substrate surface using polyethene via chemical vapor deposition (CVD) technique in a gaseous environment.

Morell, Gerardo; Makarov, Vladimir; Varshney, Deepak; Weiner, Brad

2013-07-23T23:59:59.000Z

32

JOURNAL DE PHYSIQUE Colloque C8, supplement au n l l , Tome 45, novembre 1984 page C8-141  

E-Print Network [OSTI]

and promethium were i n v e s t i - gated to 40 GPa and above in a gasketed diamond anvil cell by energy

Paris-Sud XI, Université de

33

Diamond nanobeam waveguide optomechanics  

E-Print Network [OSTI]

Optomechanical devices sensitively transduce and actuate motion of nanomechanical structures using light, and are central to many recent fundamental studies and technological advances. Single--crystal diamond promises to improve the performance of optomechanical devices, while also providing opportunities to interface nanomechanics with diamond color center spins and related quantum technologies. Here we demonstrate measurement of diamond nanobeam resonators with a sensitivity of 9.5 fm/Hz^0.5 and bandwidth >120 nm through dissipative waveguide--optomechanical coupling. Nanobeams are fabricated from bulk single--crystal diamond using a scalable quasi--isotropic oxygen plasma undercut etching process, and support mechanical resonances with quality factor of 2.5 x 10^5 at room temperature, and 7.2 x 10^5 in cryogenic conditions (5K). Mechanical self--oscillations, resulting from interplay between optomechanical coupling and the photothermal response of nanobeams in a buckled state, are observed with amplitude e...

Khanaliloo, Behzad; Hryciw, Aaron C; Lake, David P; Kaviani, Hamidreza; Barclay, Paul E

2015-01-01T23:59:59.000Z

34

Ultratough, Thermally Stable Polycrystalline Diamond/Silicon...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide Nanocomposites for Drill Bits Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide...

35

Examinations of ice formation processes in Florida cumuli using ice nuclei measurements of anvil ice crystal particle residues  

E-Print Network [OSTI]

importance of different ice formation processes in cumuli and the cirrus anvils they produce. Cirrus playExaminations of ice formation processes in Florida cumuli using ice nuclei measurements of anvil ice crystal particle residues Anthony J. Prenni,1 Paul J. DeMott,1 Cynthia Twohy,2 Michael R. Poellot

36

Diamond-graphite field emitters  

DOE Patents [OSTI]

A field emission electron emitter comprising an electrode of diamond and a conductive carbon, e.g., graphite, is provided.

Valone, Steven M. (Santa Fe, NM)

1997-01-01T23:59:59.000Z

37

CVD diamond - fundamental phenomena  

SciTech Connect (OSTI)

This compilation of figures and diagrams addresses the basic physical processes involved in the chemical vapor deposition of diamond. Different methods of deposition are illustrated. For each method, observations are made of the prominent advantages and disadvantages of the technique. Chemical mechanisms of nucleation are introduced.

Yarbrough, W.A. [Pennsylvania State Univ., University Park (United States)

1993-01-01T23:59:59.000Z

38

Diamond nanobeam waveguide optomechanics  

E-Print Network [OSTI]

Optomechanical devices sensitively transduce and actuate motion of nanomechanical structures using light, and are central to many recent fundamental studies and technological advances. Single--crystal diamond promises to improve the performance of optomechanical devices, while also providing opportunities to interface nanomechanics with diamond color center spins and related quantum technologies. Here we demonstrate measurement of diamond nanobeam resonators with a sensitivity of 9.5 fm/Hz^0.5 and bandwidth >120 nm through dissipative waveguide--optomechanical coupling. Nanobeams are fabricated from bulk single--crystal diamond using a scalable quasi--isotropic oxygen plasma undercut etching process, and support mechanical resonances with quality factor of 2.5 x 10^5 at room temperature, and 7.2 x 10^5 in cryogenic conditions (5K). Mechanical self--oscillations, resulting from interplay between optomechanical coupling and the photothermal response of nanobeams in a buckled state, are observed with amplitude exceeding 200 nm, and are accompanied by nonlinear mechanical softening.

Behzad Khanaliloo; Harishankar Jayakumar; Aaron C. Hryciw; David P. Lake; Hamidreza Kaviani; Paul E. Barclay

2015-02-06T23:59:59.000Z

39

Lower pressure synthesis of diamond material  

DOE Patents [OSTI]

Methods of synthesizing a diamond material, particularly nanocrystalline diamond, diamond-like carbon and bucky diamond are provided. In particular embodiments, a composition including a carbon source, such as coal, is subjected to addition of energy, such as high energy reactive milling, producing a milling product enriched in hydrogenated tetrahedral amorphous diamond-like carbon compared to the coal. A milling product is treated with heat, acid and/or base to produce nanocrystalline diamond and/or crystalline diamond-like carbon. Energy is added to produced crystalline diamond-like carbon in particular embodiments to produce bucky diamonds.

Lueking, Angela (State College, PA); Gutierrez, Humberto (State College, PA); Narayanan, Deepa (Redmond, WA); Burgess Clifford, Caroline E. (State College, PA); Jain, Puja (King Of Prussia, PA)

2010-07-13T23:59:59.000Z

40

Anvil characteristics as seen by C-POL during the Tropical Warm Pool International Cloud Experiment (TWP-ICE)  

E-Print Network [OSTI]

The Tropical Pacific Warm Pool International Cloud Experiment (TWP-ICE) took place in Darwin, Australia in early 2006. C-band radar data from this experiment were used to characterize tropical anvil areal coverage, height, and thickness during...

Frederick, Kaycee Loretta

2007-04-25T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Integrated-fin gasket for palm cubic-anvil high pressure apparatus  

SciTech Connect (OSTI)

We described an integrated-fin gasket technique for the palm cubic-anvil apparatus specialized for the high-pressure and low-temperature measurements. By using such a gasket made from the semi-sintered MgO ceramics and the tungsten-carbide anvils of 2.5 mm square top, we successfully generate pressures over 16 GPa at both room and cryogenic temperatures down to 0.5 K. We observed a pressure self-increment for this specific configuration and further characterized the thermally induced pressure variation by monitoring the antiferromagnetic transition temperature of chromium up to 12 GPa. In addition to enlarge the pressure capacity, such a modified gasket also improves greatly the surviving rate of electrical leads hanging the sample inside a Teflon capsule filled with the liquid pressure-transmitting medium. These improvements should be attributed to the reduced extrusion of gasket materials during the initial compression.

Cheng, J.-G. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Matsubayashi, K.; Nagasaki, S.; Hisada, A.; Hirayama, T.; Uwatoko, Y. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Hedo, M. [Faculty of Science, University of Ryukyus, Senbaru, Nishihara, Okinawa 903-0213 (Japan); Kagi, H. [Graduate School of Science, University of Tokyo, 7-3-1, Hongo Bunkyo-Ku, Tokyo 113-0033 (Japan)

2014-09-15T23:59:59.000Z

42

Structure and properties of diamond and diamond-like films  

SciTech Connect (OSTI)

This section is broken into four parts: (1) introduction, (2) natural IIa diamond, (3) importance of structure and composition, and (4) control of structure and properties. Conclusions of this discussion are that properties of chemical vapor deposited diamond films can compare favorably with natural diamond, that properties are anisotropic and are a strong function of structure and crystal perfection, that crystal perfection and morphology are functions of growth conditions and can be controlled, and that the manipulation of texture and thereby surface morphology and internal crystal perfection is an important step in optimizing chemically deposited diamond films for applications.

Clausing, R.E. [Oak Ridge National Lab., TN (United States)

1993-01-01T23:59:59.000Z

43

A Climatology of Tropical Anvil and Its Relationship to the Large-Scale Circulation  

E-Print Network [OSTI]

This research was sponsored by the ARM-DOE Grant DE-FG02-06ER64174. viii TABLE OF CONTENTS Page ABSTRACT??????.???????????????????..??? iii DEDICATION... the climate feedback obtained from doubled CO 2 experiments with different parameterizations of large-scale clouds and moist convection by using the Goddard Institute for Space Studies (GISS) GCM. They showed that the presence of optically thick anvil...

Li, Wei

2011-02-22T23:59:59.000Z

44

Diamond turning of glass  

SciTech Connect (OSTI)

A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

Blackley, W.S.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

45

Diamond films treated with alkali-halides  

DOE Patents [OSTI]

A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

Anderson, D.F.; Kwan, S.W.

1997-04-08T23:59:59.000Z

46

Electronic Structure of Diamond Surfaces Functionalized by Ru(tpy)2 Ioannis Zegkinoglou,,  

E-Print Network [OSTI]

by reducing the output voltage by almost a factor of 2.4 For all solar energy conversion processes of the frontier orbitals of the dye relative to the band edges of diamond are inferred from the spectroscopic data. The implications of using diamond films as inert electron donors in photocatalysis and dye-sensitized solar cells

Himpsel, Franz J.

47

Raman and conductivity studies of boron-doped microcrystalline diamond, facetted nanocrystalline diamond and cauliflower diamond films  

E-Print Network [OSTI]

-like conductivity. A complication is that polycrystalline boron-doped CVD diamond films possess grain boundariesRaman and conductivity studies of boron-doped microcrystalline diamond, facetted nanocrystalline diamond and cauliflower diamond films P.W. May a,, W.J. Ludlow a , M. Hannaway a , P.J. Heard b , J

Bristol, University of

48

UV photoemission efficiency of polycrystalline CVD diamond films  

E-Print Network [OSTI]

efficiency of a polycrystalline diamond planar reflectivequantum efficiency of polycrystalline diamond films grown onallowed the growth of polycrystalline diamond thin films on

Tremsin, A S; Siegmund, OHW

2005-01-01T23:59:59.000Z

49

A subpicotesla diamond magnetometer  

E-Print Network [OSTI]

Diamond defect centers are promising solid state magnetometers. Single centers allow for high spatial resolution field imaging but are limited in their magnetic field sensitivity to around 10 nT/Hz^(1/2) at room-temperature. Using defect center ensembles sensitivity can be scaled as N^(1/2) when N is the number of defects. In the present work we use an ensemble of 1e11 defect centers for sensing. By carefully eliminating all noise sources like laser intensity fluctuations, microwave amplitude and phase noise we achieve a photon shot noise limited field sensitivity of 0.9 pT/Hz^(1/2) at room-temperature with an effective sensor volume of 8.5e-4 mm^3. The smallest field we measured with our device is 100 fT. While this denotes the best diamond magnetometer sensitivity so far, further improvements using decoupling sequences and material optimization could lead to fT/Hz^(1/2) sensitivity.

Thomas Wolf; Philipp Neumann; Kazuo Nakamura; Hitoshi Sumiya; Junichi Isoya; Jörg Wrachtrup

2014-12-19T23:59:59.000Z

50

Amorphous-diamond electron emitter  

DOE Patents [OSTI]

An electron emitter comprising a textured silicon wafer overcoated with a thin (200 .ANG.) layer of nitrogen-doped, amorphous-diamond (a:D-N), which lowers the field below 20 volts/micrometer have been demonstrated using this emitter compared to uncoated or diamond coated emitters wherein the emission is at fields of nearly 60 volts/micrometer. The silicon/nitrogen-doped, amorphous-diamond (Si/a:D-N) emitter may be produced by overcoating a textured silicon wafer with amorphous-diamond (a:D) in a nitrogen atmosphere using a filtered cathodic-arc system. The enhanced performance of the Si/a:D-N emitter lowers the voltages required to the point where field-emission displays are practical. Thus, this emitter can be used, for example, in flat-panel emission displays (FEDs), and cold-cathode vacuum electronics.

Falabella, Steven (Livermore, CA)

2001-01-01T23:59:59.000Z

51

Method of Dehalogenation using Diamonds  

SciTech Connect (OSTI)

A method for preparing olefins and halogenated olefins is provided comprising contacting halogenated compounds with diamonds for a sufficient time and at a sufficient temperature to convert the halogenated compounds to olefins and halogenated olefins via elimination reactions.

Farcasiu, Malvina; Kaufman, Phillip B.; Ladner, Edward P.; Anderson, Richard R.

1999-02-26T23:59:59.000Z

52

DIAMOND CHEMICAL VAPOR DEPOSITION Nucleation and Early Growth Stages  

E-Print Network [OSTI]

a reality. Epi- taxial diamond has been grown on diamond and cubic-BN. Polycrystalline diamond films haveDIAMOND CHEMICAL VAPOR DEPOSITION Nucleation and Early Growth Stages by Huimin Liu David S. Dandy of high-quality diamond coatings on preshaped parts and synthesis of free-standing shapes of diamond

Dandy, David

53

Raman and conductivity studies of boron doped microcrystalline diamond, facetted nanocrystalline diamond  

E-Print Network [OSTI]

superconductivity at temperatures polycrystalline boron-doped CVD diamond filmsRaman and conductivity studies of boron doped microcrystalline diamond, facetted nanocrystalline diamond and cauliflower diamond films P.W. May a,*, W.J. Ludlow a , M. Hannaway a , P.J. Heard b , J

Bristol, University of

54

Explosive fragmentation of oil shale: Results from Colony and Anvil Points Mines, Colorado  

SciTech Connect (OSTI)

From 1978 through 1983, numerous oil shale fragmentation tests were conducted at the Colony and Anvil Points Mines, Colorado. These experiments were part of an investigation to determine factors required for the adequate fragmentation of oil shale and to evaluate the feasibility of using the vertical modified in situ retort (VMIS) method for recovery of kerogen from oil shale. The objective of this research was to support the design of a large volume (10{sup 4} m{sup 3}) rubble bed for in situ processing. In addition, this rubble bed was to be formed in a large single-blast event which included decked charges, time delays, and multiple boreholes. Results are described.

Dick, R.D.; Fourney, W.L. [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering] [Maryland Univ., College Park, MD (United States). Dept. of Mechanical Engineering; Young, C. III [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)] [Sunburst Recovery, Inc., Steamboat Springs, CO (United States)

1992-12-31T23:59:59.000Z

55

Method of Forming Diamonds from Carbonaceous Material  

SciTech Connect (OSTI)

A method for producing diamonds is provided comprising exposing carbonaceous material to ion irradiation at ambient temperature and pressure.

Daulton, Tyrone; Lewis, Roy; Rehn, Lynn; Kirk, Marquis

1999-11-30T23:59:59.000Z

56

Diamond Thin Films Handbook David S. Dandy  

E-Print Network [OSTI]

..................................................................................10 A. Calculation of diamond surface structures and energetics .................................................................................................36 2. Reactor pressure ...........................................................................................48 VI. Reactor scale modeling

Dandy, David

57

Diamond and diamond-like films for transportation applications  

SciTech Connect (OSTI)

This section is a compilation of transparency templates which describe the goals of the Office of Transportation Materials (OTM) Tribology Program. The positions of personnel on the OTM are listed. The role and mission of the OTM is reviewed. The purpose of the Tribology Program is stated to be `to obtain industry input on program(s) in tribology/advanced lubricants areas of interest`. The objective addressed here is to identify opportunities for cost effective application of diamond and diamond-like carbon in transportation systems.

Perez, J.M.

1993-01-01T23:59:59.000Z

58

Recent Results on Diamond Radiation Tolerance  

E-Print Network [OSTI]

-crystal (sc) and polycrystalline (poly) diamond exposed to 5 beam conditions. Figure of merit: Mean Free PathRecent Results on Diamond Radiation Tolerance Sally Seidel University of New Mexico Representing 1 #12;§ Overview of diamond and radiation damage issues § Investigation of the application

Seidel, Sally

59

Diamond-silicon carbide composite  

DOE Patents [OSTI]

Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5–8 GPa, T=1400K–2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa.dot.m1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.

Qian, Jiang; Zhao, Yusheng

2006-06-13T23:59:59.000Z

60

Method for machining steel with diamond tools  

DOE Patents [OSTI]

The present invention is directed to a method for machine optical quality finishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

Casstevens, J.M.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Method for machining steel with diamond tools  

DOE Patents [OSTI]

The present invention is directed to a method for machining optical quality inishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

Casstevens, John M. (Greenville, TX)

1986-01-01T23:59:59.000Z

62

Gas-loading apparatus for large-volume high-pressure cell   

E-Print Network [OSTI]

The Paris-Edinburgh cell (PEC) is a widely used opposed-anvil device for neutron scattering. Since its development, it has been used to study a number of samples loaded as solids or liquids. However, studying gases at ...

Bocian, Artur

2012-06-25T23:59:59.000Z

63

Magnetic properties of aggregate polycrystalline diamond: implications for carbonado history  

E-Print Network [OSTI]

Magnetic properties of aggregate polycrystalline diamond: implications for carbonado history Gu form 20 June 2000; accepted 25 June 2000 Abstract Carbonados are aggregate polycrystalline diamonds features; magnetic hysteresis 1. Introduction Carbonados are sintered polycrystalline micro- diamond

Kletetschka, Gunther

64

Chemical vapor deposited diamond-on-diamond powder composites (LDRD final report)  

SciTech Connect (OSTI)

Densifying non-mined diamond powder precursors with diamond produced by chemical vapor infiltration (CVI) is an attractive approach for forming thick diamond deposits that avoids many potential manufacturability problems associated with predominantly chemical vapor deposition (CVD) processes. The authors developed techniques for forming diamond powder precursors and densified these precursors in a hot filament-assisted reactor and a microwave plasma-assisted reactor. Densification conditions were varied following a fractional factorial statistical design. A number of conclusions can be drawn as a result of this study. High density diamond powder green bodies that contain a mixture of particle sizes solidify more readily than more porous diamond powder green bodies with narrow distributions of particle sizes. No composite was completely densified although all of the deposits were densified to some degree. The hot filament-assisted reactor deposited more material below the exterior surface, in the interior of the powder deposits; in contrast, the microwave-assisted reactor tended to deposit a CVD diamond skin over the top of the powder precursors which inhibited vapor phase diamond growth in the interior of the powder deposits. There were subtle variations in diamond quality as a function of the CVI process parameters. Diamond and glassy carbon tended to form at the exterior surface of the composites directly exposed to either the hot filament or the microwave plasma. However, in the interior, e.g. the powder/substrate interface, diamond plus diamond-like-carbon formed. All of the diamond composites produced were grey and relatively opaque because they contained flawed diamond, diamond-like-carbon and glassy carbon. A large amount of flawed and non-diamond material could be removed by post-CVI oxygen heat treatments. Heat treatments in oxygen changed the color of the composites to white.

Panitz, J.K.; Hsu, W.L.; Tallant, D.R.; McMaster, M.; Fox, C.; Staley, D.

1995-12-01T23:59:59.000Z

65

Corrigendum to Zircon solubility and zirconium complexation in H2O+Na2O+SiO2±Al2O3 fluids at high pressure and temperature [Earth Planet. Sci. Lett. 349-350 (2012) 15-25  

E-Print Network [OSTI]

A confocal set-up for micro-XRF and XAFS experiments usingsynchrotron radiation micro-XRF. Earth Planet. Sci. Lett.diamond-anvil cell and SR-XRF: solubility of AgCl in water.

2013-01-01T23:59:59.000Z

66

Single-crystal elasticity of grossular-and almandine-rich garnets to 11 GPa by Brillouin  

E-Print Network [OSTI]

to 11 GPa in a diamond anvil cell. The experiments were carried out using a 16:3:1 methanol is the dissolution of pyroxene into the garnet structure producing Al-deficient garnets (majorite) that are stable

Duffy, Thomas S.

67

Final Scientific Report  

SciTech Connect (OSTI)

Viscosities of water, nitrogen and carbon dioxide have been measured at elevated pressures and temperatures in the diamond-anvil cell. A strong correlation between viscosity and entropy has been confirmed.

Evan Abramson

2009-06-26T23:59:59.000Z

68

Diamond-silicon carbide composite and method  

DOE Patents [OSTI]

Uniformly dense, diamond-silicon carbide composites having high hardness, high fracture toughness, and high thermal stability are prepared by consolidating a powder mixture of diamond and amorphous silicon. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPam.sup.1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness.

Zhao, Yusheng (Los Alamos, NM)

2011-06-14T23:59:59.000Z

69

Diamond turning machine controller implementation  

SciTech Connect (OSTI)

The standard controller for a Pnuemo ASG 2500 Diamond Turning Machine, an Allen Bradley 8200, has been replaced with a custom high-performance design. This controller consists of four major components. Axis position feedback information is provided by a Zygo Axiom 2/20 laser interferometer with 0.1 micro-inch resolution. Hardware interface logic couples the computers digital and analog I/O channels to the diamond turning machine`s analog motor controllers, the laser interferometer, and other machine status and control information. It also provides front panel switches for operator override of the computer controller and implement the emergency stop sequence. The remaining two components, the control computer hardware and software, are discussed in detail below.

Garrard, K.P.; Taylor, L.W.; Knight, B.F.; Fornaro, R.J.

1988-12-01T23:59:59.000Z

70

Diamond turning of thermoplastic polymers  

SciTech Connect (OSTI)

Single point diamond turning studies were made using a series of thermoplastic polymers with different glass transition temperatures. Variations in surface morphology and surface roughness were observed as a function of cutting speed. Lower glass transition temperatures facilitate smoother surface cuts and better surface finish. This can be attributed to the frictional heating that occurs during machining. Because of the very low glass transition temperatures in polymeric compared to inorganic glasses, the precision machining response can be very speed sensitive.

Smith, E.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

71

All diamond self-aligned thin film transistor  

DOE Patents [OSTI]

A substantially all diamond transistor with an electrically insulating substrate, an electrically conductive diamond layer on the substrate, and a source and a drain contact on the electrically conductive diamond layer. An electrically insulating diamond layer is in contact with the electrically conductive diamond layer, and a gate contact is on the electrically insulating diamond layer. The diamond layers may be homoepitaxial, polycrystalline, nanocrystalline or ultrananocrystalline in various combinations.A method of making a substantially all diamond self-aligned gate transistor is disclosed in which seeding and patterning can be avoided or minimized, if desired.

Gerbi, Jennifer (Champaign, IL)

2008-07-01T23:59:59.000Z

72

EA-1795: Diamond Green Diesel Facility in Norco, LA | Department...  

Broader source: Energy.gov (indexed) [DOE]

April 1, 2011 EA-1795: Final Environmental Assessment Loan Guarantee to Diamond Green Diesel, LLC for Construction of the Diamond Green Diesel Facility in Norco, Louisiana April...

73

Energy Harvesting Diamond Channel with Energy Cooperation  

E-Print Network [OSTI]

Energy Harvesting Diamond Channel with Energy Cooperation Berk Gurakan Sennur Ulukus Department@umd.edu Abstract--We consider the energy harvesting diamond channel, where the source and two relays harvest energy the option of wirelessly transferring some of its energy to the relays via energy cooperation. We find

Ulukus, Sennur

74

Fracture of synthetic diamond M. D. Droty  

E-Print Network [OSTI]

Fracture of synthetic diamond M. D. Droty Ctystallume, 3506 Bassett Street, Santa Clara, California 1995) The fracture behavior of synthetic diamond has been investigated using indentation methods and by the tensile testing of pre-notched fracture-mechanics type samples. Specifically, the fracture toughness

Ritchie, Robert

75

Fluorinated diamond bonded in fluorocarbon resin  

DOE Patents [OSTI]

By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

Taylor, Gene W. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

76

Diamond as an inert substrate of graphene  

SciTech Connect (OSTI)

Interaction between graphene and semiconducting diamond substrate has been examined with large-scale density functional theory calculations. Clean and hydrogenated diamond (100) and (111) surfaces have been studied. It turns out that weak van der Waals interactions dominate for graphene on all these surfaces. High carrier mobility of graphene is almost not affected, except for a negligible energy gap opening at the Dirac point. No charge transfer between graphene and diamond (100) surfaces is detected, while different charge-transfer complexes are formed between graphene and diamond (111) surfaces, inducing either p-type or n-type doping on graphene. Therefore, diamond can be used as an excellent substrate of graphene, which almost keeps its electronic structures at the same time providing the flexibility of charge doping.

Hu Wei; Li Zhenyu; Yang Jinlong [Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2013-02-07T23:59:59.000Z

77

Multi-length Scale Modeling of CVD of Diamond Films  

E-Print Network [OSTI]

) of single-- crystalline and polycrystalline diamond films in acrystalline and polycrystalline diamond filmsMulti-length Scale Modeling of CVD of Diamond Films M. Grujicic and S. G. LaiM. Grujicic and S. G-scale Modeling of CVD Deposition of Diamond Films RotatingRotating--disk Hotdisk Hot--filament CVD

Grujicic, Mica

78

Appendix A SIMS profiles of hydrogen and deuterium in diamond  

E-Print Network [OSTI]

.5 due to the polycrystalline diamond coating on the quartz sample holder. The resulting layered127 Appendix A SIMS profiles of hydrogen and deuterium in diamond A.1 Introduction A diamond sample ion­beam doping. Impurity levels were profiled as a function of depth from the diamond surface using

Goddard III, William A.

79

Nanofocusing optics for synchrotron radiation made from polycrystalline diamond  

E-Print Network [OSTI]

Nanofocusing optics for synchrotron radiation made from polycrystalline diamond O. J. L. Fox,1,2,* L. Alianelli,1 A. M. Malik,3,4 I. Pape,1,5 P. W. May,2 and K. J. S. Sawhney1 1 Diamond Light Source of Engineering, University of Nottingham, NG7 2RD, UK * oliver.fox@diamond.ac.uk Abstract: Diamond possesses many

Bristol, University of

80

JOURNAL OF MATERIALS SCIENCE 31 (1996) 2801 2805 Laser ablation of diamond fibres and a diamond fibre  

E-Print Network [OSTI]

.been embedded in Ti-6A1-4V alloy to produce a diamond fibre-reinforced composite. Both the fibres and a diamond fibre-reinforced titanium alloy composite. 2. Experimental procedure Fibres have been made of a diamond-coated fibre after localized ablations is shown tn Fig. 1. The areas of the diamond surface

Bristol, University of

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Carbon sp2-on-sp3 Technology: Graphene-on-Diamond Devices and Interconnects  

E-Print Network [OSTI]

Table 2.2 lists the properties of polycrystalline diamond.Table 2.2 Polycrystalline diamond properties* Film Type MCD24 2.2 Polycrystalline diamond

Yu, Jie

2012-01-01T23:59:59.000Z

82

Chemical Analysis of Impurity Boron Atoms in Diamond Using Soft X-ray Emission Spectroscopy  

E-Print Network [OSTI]

from the spectral profiles of HTP-B-diamond, h-BN, and c-BN.diamond differ from those of HTP-B-diamond and the reference

Muramatsu, Yasuji

2009-01-01T23:59:59.000Z

83

Self-composite comprised of nanocrystalline diamond and a non-diamond component useful for thermoelectric applications  

DOE Patents [OSTI]

One provides nanocrystalline diamond material that comprises a plurality of substantially ordered diamond crystallites that are sized no larger than about 10 nanometers. One then disposes a non-diamond component within the nanocrystalline diamond material. By one approach this non-diamond component comprises an electrical conductor that is formed at the grain boundaries that separate the diamond crystallites from one another. The resultant nanowire is then able to exhibit a desired increase with respect to its ability to conduct electricity while also preserving the thermal conductivity behavior of the nanocrystalline diamond material.

Gruen, Dieter M.

2012-09-04T23:59:59.000Z

84

Self-composite comprised of nanocrystalline diamond and a non-diamond component useful for thermoelectric applications  

DOE Patents [OSTI]

One provides nanocrystalline diamond material that comprises a plurality of substantially ordered diamond crystallites that are sized no larger than about 10 nanometers. One then disposes a non-diamond component within the nanocrystalline diamond material. By one approach this non-diamond component comprises an electrical conductor that is formed at the grain boundaries that separate the diamond crystallites from one another. The resultant nanowire is then able to exhibit a desired increase with respect to its ability to conduct electricity while also preserving the thermal conductivity behavior of the nanocrystalline diamond material.

Gruen, Dieter M. (Downers Grove, IL)

2009-08-11T23:59:59.000Z

85

First principles study of Fe in diamond: A diamond-based half metallic dilute magnetic semiconductor  

SciTech Connect (OSTI)

Half-metallic ferromagnetic ordering in semiconductors, essential in the emerging field of spintronics for injection and transport of highly spin polarised currents, has up to now been considered mainly in III–V and II–VI materials. However, low Curie temperatures have limited implementation in room temperature device applications. We report ab initio Density Functional Theory calculations on the properties of Fe in diamond, considering the effects of lattice site, charge state, and Fermi level position. We show that the lattice sites and induced magnetic moments of Fe in diamond depend strongly on the Fermi level position and type of diamond co-doping, with Fe being energetically most favorable at the substitutional site in p-type and intrinsic diamond, while it is most stable at a divacancy site in n-type diamond. Fe induces spin polarized bands in the band gap, with strong hybridization between Fe-3d and C-2s,2p bands. We further consider Fe-Fe spin interactions in diamond and show that substitutional Fe{sup +1} in p-type diamond exhibits a half-metallic character, with a magnetic moment of 1.0??{sub B} per Fe atom and a large ferromagnetic stabilization energy of 33?meV, an order of magnitude larger than in other semiconductors, with correspondingly high Curie temperatures. These results, combined with diamond's unique properties, demonstrate that Fe doped p-type diamond is likely to be a highly suitable candidate material for spintronics applications.

Benecha, E. M. [Department of Physics, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa); Lombardi, E. B., E-mail: lombaeb@unisa.ac.za [College of Graduate Studies, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa)

2013-12-14T23:59:59.000Z

86

Amorphous Diamond MEMS and Sensors  

SciTech Connect (OSTI)

This report describes a new microsystems technology for the creation of microsensors and microelectromechanical systems (MEMS) using stress-free amorphous diamond (aD) films. Stress-free aD is a new material that has mechanical properties close to that of crystalline diamond, and the material is particularly promising for the development of high sensitivity microsensors and rugged and reliable MEMS. Some of the unique properties of aD include the ability to easily tailor film stress from compressive to slightly tensile, hardness and stiffness 80-90% that of crystalline diamond, very high wear resistance, a hydrophobic surface, extreme chemical inertness, chemical compatibility with silicon, controllable electrical conductivity from insulating to conducting, and biocompatibility. A variety of MEMS structures were fabricated from this material and evaluated. These structures included electrostatically-actuated comb drives, micro-tensile test structures, singly- and doubly-clamped beams, and friction and wear test structures. It was found that surface micromachined MEMS could be fabricated in this material easily and that the hydrophobic surface of the film enabled the release of structures without the need for special drying procedures or the use of applied hydrophobic coatings. Measurements using these structures revealed that aD has a Young's modulus of {approx}650 GPa, a tensile fracture strength of 8 GPa, and a fracture toughness of 8 MPa{center_dot}m {sup 1/2}. These results suggest that this material may be suitable in applications where stiction or wear is an issue. Flexural plate wave (FPW) microsensors were also fabricated from aD. These devices use membranes of aD as thin as {approx}100 nm. The performance of the aD FPW sensors was evaluated for the detection of volatile organic compounds using ethyl cellulose as the sensor coating. For comparable membrane thicknesses, the aD sensors showed better performance than silicon nitride based sensors. Greater than one order of magnitude increase in chemical sensitivity is expected through the use of ultra-thin aD membranes in the FPW sensor. The discoveries and development of the aD microsystems technology that were made in this project have led to new research projects in the areas of aD bioMEMS and aD radio frequency MEMS.

SULLIVAN, JOHN P.; FRIEDMANN, THOMAS A.; ASHBY, CAROL I.; DE BOER, MAARTEN P.; SCHUBERT, W. KENT; SHUL, RANDY J.; HOHLFELDER, ROBERT J.; LAVAN, D.A.

2002-06-01T23:59:59.000Z

87

Method and apparatus for making diamond-like carbon films  

DOE Patents [OSTI]

Ion-assisted plasma enhanced deposition of diamond-like carbon (DLC) films on the surface of photovoltaic solar cells is accomplished with a method and apparatus for controlling ion energy. The quality of DLC layers is fine-tuned by a properly biased system of special electrodes and by exact control of the feed gas mixture compositions. Uniform (with degree of non-uniformity of optical parameters less than 5%) large area (more than 110 cm.sup.2) DLC films with optical parameters varied within the given range and with stability against harmful effects of the environment are achieved.

Pern, Fu-Jann (Golden, CO); Touryan, Kenell J. (Indian Hills, CO); Panosyan, Zhozef Retevos (Yerevan, AM); Gippius, Aleksey Alekseyevich (Moscow, RU)

2008-12-02T23:59:59.000Z

88

Electronic Impact of Inclusions in Diamond  

SciTech Connect (OSTI)

X-ray topography data are compared with photodiode responsivity maps to identify potential candidates for electron trapping in high purity, single crystal diamond. X-ray topography data reveal the defects that exist in the diamond material, which are dominated by non-electrically active linear dislocations. However, many diamonds also contain defects configurations (groups of threading dislocations originating from a secondary phase region or inclusion) in the bulk of the wafer which map well to regions of photoconductive gain, indicating that these inclusions are a source of electron trapping which affect the performance of diamond X-ray detectors. It was determined that photoconductive gain is only possible with the combination of an injecting contact and charge trapping in the near surface region. Typical photoconductive gain regions are 0.2 mm across; away from these near-surface inclusions the device yields the expected diode responsivity.

Muller, E.M.; Smedley, J.; Raghothamachar, B.; Gaowei, M.; Keister, J.W.; Ben-Zvi, I.; Dudley, M.; Wu, Q.

2010-04-07T23:59:59.000Z

89

Effective placement of detectors at diamond interchanges  

E-Print Network [OSTI]

Most signalized interchanges in Texas are tight urban diamond interchanges of freeways having one-way frontage roads. At these interchanges, traffic actuated control with improper location of detectors may result in inefficient traffic operations...

Prabhakar, Dayakar

1994-01-01T23:59:59.000Z

90

Geometry and temperature dependent thermal conductivity of diamond nanowires: A non-equilibrium molecular dynamics study  

E-Print Network [OSTI]

plasma etching of polycrystalline diamond films [7], microwave plasma assisted chemical vapor deposition. For theoretical calculations of proper- ties of nanosized diamond materials, polycrystalline diamond thin filmsGeometry and temperature dependent thermal conductivity of diamond nanowires: A non

Melnik, Roderick

91

Diamond film growth argon-carbon plasmas  

DOE Patents [OSTI]

A method and system are disclosed for manufacturing diamond film. The method involves forming a carbonaceous vapor, providing a gas stream of argon, hydrogen and hydrocarbon and combining the gas with the carbonaceous vapor, passing the combined carbonaceous vapor and gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the carbonaceous and deposition of a diamond film on a substrate. 29 figs.

Gruen, D.M.; Krauss, A.R.; Liu, S.Z.; Pan, X.Z.; Zuiker, C.D.

1998-12-15T23:59:59.000Z

92

Diamond film growth from fullerene precursors  

DOE Patents [OSTI]

A method and system are disclosed for manufacturing diamond film. The method involves forming a fullerene vapor, providing a noble gas stream and combining the gas with the fullerene vapor, passing the combined fullerene vapor and noble gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the fullerene and deposition of a diamond film on a substrate. 10 figs.

Gruen, D.M.; Liu, S.; Krauss, A.R.; Pan, X.

1997-04-15T23:59:59.000Z

93

Diamond and Related Materials 8 (1999) 13881392 www.elsevier.com/locate/diamond  

E-Print Network [OSTI]

of the hot-filament diamond CVD gas-phase environment: direct comparison with experimental measurements R diamond reactor. These simulations have been compared to data measured using an in-situ molecular beam atoms, was found to be very important since it controlled the whole gas-phase chemistry. Comparison

Bristol, University of

94

Plasma spraying method for forming diamond and diamond-like coatings  

DOE Patents [OSTI]

A method and composition is disclosed for the deposition of a thick layer of diamond or diamond-like material. The method includes high temperature processing wherein a selected composition including at least glassy carbon is heated in a direct current plasma arc device to a selected temperature above the softening point, in an inert atmosphere, and is propelled to quickly quenched on a selected substrate. The softened or molten composition crystallizes on the substrate to form a thick deposition layer comprising at least a diamond or diamond-like material. The selected composition includes at least glassy carbon as a primary constituent and may include at least one secondary constituent. Preferably, the secondary constituents are selected from the group consisting of at least diamond powder, boron carbide (B{sub 4}C) powder and mixtures thereof. 9 figs.

Holcombe, C.E.; Seals, R.D.; Price, R.E.

1997-06-03T23:59:59.000Z

95

Plasma spraying method for forming diamond and diamond-like coatings  

DOE Patents [OSTI]

A method and composition for the deposition of a thick layer (10) of diamond or diamond-like material. The method includes high temperature processing wherein a selected composition (12) including at least glassy carbon is heated in a direct current plasma arc device to a selected temperature above the softening point, in an inert atmosphere, and is propelled to quickly quenched on a selected substrate (20). The softened or molten composition (18) crystallizes on the substrate (20) to form a thick deposition layer (10) comprising at least a diamond or diamond-like material. The selected composition (12) includes at least glassy carbon as a primary constituent (14) and may include at least one secondary constituent (16). Preferably, the secondary constituents (16) are selected from the group consisting of at least diamond powder, boron carbide (B.sub.4 C) powder and mixtures thereof.

Holcombe, Cressie E. (Farragut, TN); Seals, Roland D. (Oak Ridge, TN); Price, R. Eugene (Knoxville, TN)

1997-01-01T23:59:59.000Z

96

n-Type diamond and method for producing same  

DOE Patents [OSTI]

A new n-type semiconducting diamond is disclosed, which is doped with n-type dopant atoms. Such diamond is advantageously formed by chemical vapor deposition from a source gas mixture comprising a carbon source compound for the diamond, and a volatile hot wire filament for the n-type impurity species, so that the n-type impurity atoms are doped in the diamond during its formation. A corresponding chemical vapor deposition method of forming the n-type semiconducting diamond is disclosed. The n-type semiconducting diamond of the invention may be usefully employed in the formation of diamond-based transistor devices comprising pn diamond junctions, and in other microelectronic device applications.

Anderson, Richard J. (Oakland, CA)

2002-01-01T23:59:59.000Z

97

Sparkling Diamonds – Reducing High Energy in the Frozen North  

E-Print Network [OSTI]

De Beers, the undisputed world leader in diamond mining, in a typically proactive approach, completed an energy review at the Snap Lake Diamond Mine in the Northwest Territories. What makes the approach unique is that the mine is still under...

Feldman, J.

2007-01-01T23:59:59.000Z

98

Study of Electron Transport and Amplification in Diamond  

SciTech Connect (OSTI)

As a successful completion of this award, my group has demonstrated world-leading electron gain from diamond for use in a diamond-amplified photocathode. Also, using high-resolution photoemission measurements we were able to uncover exciting new physics of the electron emission mechanisms from hydrogen terminated diamond. Our work, through the continued support of HEP, has resulted in a greater understanding of the diamond material science, including current limits, charge transport modeling, and spatial uniformity.

Muller, Erik M.; Ben-Zvi, Ilan

2013-03-31T23:59:59.000Z

99

Comparative evaluation of CVD diamond technologies  

SciTech Connect (OSTI)

Chemical vapor deposition (CVD) of diamonds occurs from hydrogen-hydrocarbon gas mixtures in the presence of atomic hydrogen at subatmospheric pressures. Most CVD methods are based on different means of generating and transporting atomic hydrogen in a particular system. Evaluation of these different techniques involves their capital costs, material costs, energy costs, labor costs and the type and quality of diamond that they produce. Currently, there is no universal agreement on which is the best technique and technique selection has been largely driven by the professional background of the user as well as the particular application of interest. This article discusses the criteria for evaluating a process for low-pressure deposition of diamond. Next, a brief history of low-pressure diamond synthesis is reviewed. Several specific processes are addressed, including the hot filament process, hot filament electron-assisted chemical vapor deposition, and plasma generation of atomic hydrogen by glow discharge, microwave discharge, low pressure radio frequency discharge, high pressure DC discharge, high pressure microwave discharge jets, high pressure RF discharge, and high and low pressure flames. Other types of diamond deposition methods are also evaluated. 101 refs., 15 figs.

Anthony, T.R. [General Electric Corporate Research & Development Center, Schenectady, NY (United States)

1993-01-01T23:59:59.000Z

100

Etching of polycrystalline diamond films by electron beam assisted plasma  

E-Print Network [OSTI]

Etching of polycrystalline diamond films by electron beam assisted plasma Koji Kobashi, Shigeaki) Polycrystalline diamond films were processed in a direct current plasma produced by a self-focused electron beam that the etching apparatus used was capable of forming at least a 5-mm wide pattern of polycrystalline diamond film

Rocca, Jorge J.

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Physica B 308310 (2001) 612615 Irradiation effects in semiconducting diamonds  

E-Print Network [OSTI]

Physica B 308­310 (2001) 612­615 Irradiation effects in semiconducting diamonds N. Kristianpoller irradiation on semiconducting diamonds (type IIb) were studied and compared with those induced at the same conditions in natural (type Ia) and in synthetic diamonds. Methods of optical absorption, of X-ray and light

Chen, Reuven

102

Fuel Cells Get New BFF | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells Get New BFF Fuel Cells Get New BFF Artificial diamonds may lead to affordable, efficient fuel cells Oxygen (red spheres) migrates from one vacancy to another inside the...

103

Materials science Nanotubes get hard  

E-Print Network [OSTI]

Materials science Nanotubes get hard under pressure Proc. Natl Acad. Sci. USA doi:10.1073/pnas.0405877101 (2004) When Zhongwu Wang et al. squeezed carbon nanotubes in a diamond anvil cell, they made nanotubes into diamond itself: the carbon material formed under compression at room temperature seems

Downs, Robert T.

104

Wear of diamond and diamondlike carbon films.  

SciTech Connect (OSTI)

Detailed tribological studies on diamond and diamond-like carbon (DLC) films have confirmed that these films are inherently self-lubricating and resistant to abrasive, adhesive and corrosive wear. Because of their high chemical inertness, they are also resistant to corrosion and oxidation (even at elevated temperatures). The combination of such exceptional qualities in these films makes them ideal for a wide range of demanding tribological applications (such as microelectromechanical systems, cutting tools, mechanical seals, magnetic hard disks, etc.). These films, available for more than three decades, have been used extensively for tooling and magnetic hard disk applications. Their potential in other application areas is currently being explored around the world. With the development of new and more robust deposition methods in recent years, it is envisioned that the production of high quality diamond and DLC films will become very cost effective and highly reliable for large-scale applications in the transportation and manufacturing sectors. In this paper, sliding wear mechanisms of diamond and DLC films will be presented. Specifically, it will be shown that, in general the wear of these films is extremely low (mainly because of their exceptional hardness and low friction characteristics). Specific test conditions established during each sliding test, however, may dramatically affect the wear performance of certain diamond and DLC films. One of the dominant wear mechanismsrelates to a phase transformation that is primarily the result of very high mechanical and thermal loadings of sliding contact interfaces. The transformation products (such as disordered graphite) trapped at the sliding interface may transfer to themating surface and significantly affect friction and wear. This paper describes, in terms of structural and fundamental tribological knowledge, the ideal film microstructures and chemistry, as well as operational conditions under which diamond and DLC films perform the best and provide superlow friction and wear properties in sliding tribological applications.

Erdemir, A.; Energy Technology

2002-01-01T23:59:59.000Z

105

Accepted to Diamond and Related Materials A kinetic model of diamond nucleation and silicon carbide interlayer formation during  

E-Print Network [OSTI]

Accepted to Diamond and Related Materials A kinetic model of diamond nucleation and silicon carbide Engineering, Colorado State University, Fort Collins, CO, USA Abstract The presence of thin silicon carbide diffusion of carbon atoms into the silicon carbide layer, and the morphology and orientation of the diamond

Dandy, David

106

Hydrogen-doped cubic diamond and the crystal structure of n-diamond Bin Wen a,b,  

E-Print Network [OSTI]

Hydrogen-doped cubic diamond and the crystal structure of n-diamond Bin Wen a,b, , Roderick Melnik. In particular, hydrogen concen- tration dependent elastic constants and lattice parameters for the H-doped diamond have been analyzed. Our results indicate that when the hydrogen concentration is less than 19 at

Melnik, Roderick

107

Method of improving field emission characteristics of diamond thin films  

DOE Patents [OSTI]

A method of preparing diamond thin films with improved field emission properties. The method includes preparing a diamond thin film on a substrate, such as Mo, W, Si and Ni. An atmosphere of hydrogen (molecular or atomic) can be provided above the already deposited film to form absorbed hydrogen to reduce the work function and enhance field emission properties of the diamond film. In addition, hydrogen can be absorbed on intergranular surfaces to enhance electrical conductivity of the diamond film. The treated diamond film can be part of a microtip array in a flat panel display.

Krauss, Alan R. (Naperville, IL); Gruen, Dieter M. (Downer Grove, IL)

1999-01-01T23:59:59.000Z

108

Method of improving field emission characteristics of diamond thin films  

DOE Patents [OSTI]

A method of preparing diamond thin films with improved field emission properties is disclosed. The method includes preparing a diamond thin film on a substrate, such as Mo, W, Si and Ni. An atmosphere of hydrogen (molecular or atomic) can be provided above the already deposited film to form absorbed hydrogen to reduce the work function and enhance field emission properties of the diamond film. In addition, hydrogen can be absorbed on intergranular surfaces to enhance electrical conductivity of the diamond film. The treated diamond film can be part of a microtip array in a flat panel display. 3 figs.

Krauss, A.R.; Gruen, D.M.

1999-05-11T23:59:59.000Z

109

EIS-0070: Mining, Construction and Operation for a Full-size Module at the Anvil Points Oil Shale Facility, Rifle, Garfield County, Colorado  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy prepared this environmental impact statement to assess the environmental and socioeconomic implications of its proposal to mine 11 million tons of oil shale from the Naval Oil Shale Reserves (NOSR) at Anvil Points, Colorado; to construct an experimental full-size shale retort module on a 365-acre lease tract having a 4700 bbl/day production capacity; and to consider extension, modification or new leasing of the facility.

110

Diamond and diamond-like carbon films for advanced electronic applications  

SciTech Connect (OSTI)

Aim of this laboratory-directed research and development (LDRD) project was to develop diamond and/or diamond-like carbon (DLC) films for electronic applications. Quality of diamond and DLC films grown by chemical vapor deposition (CVD) is not adequate for electronic applications. Nucleation of diamond grains during growth typically results in coarse films that must be very thick in order to be physically continuous. DLC films grown by CVD are heavily hydrogenated and are stable to temperatures {le} 400{degrees}C. However, diamond and DLC`s exceptional electronic properties make them candidates for integration into a variety of microelectronic structures. This work studied new techniques for the growth of both materials. Template layers have been developed for the growth of CVD diamond films resulting in a significantly higher nucleation density on unscratched or unprepared Si surfaces. Hydrogen-free DLC with temperature stability {le} 800{degrees}C has been developed using energetic growth methods such as high-energy pulsed-laser deposition. Applications with the largest system impact include electron-emitting materials for flat-panel displays, dielectrics for interconnects, diffusion barriers, encapsulants, and nonvolatile memories, and tribological coatings that reduce wear and friction in integrated micro-electro-mechanical devices.

Siegal, M.P.; Friedmann, T.A.; Sullivan, J.P. [and others

1996-03-01T23:59:59.000Z

111

Ultrasensitive Magnetometry and Imaging with NV Diamond  

E-Print Network [OSTI]

-size wire structure to sit directly on the surface of millimeter-scale diamond plate. In contrast to conventional magnetic resonance imaging pulsed ESR was used to measure the Rabi oscillations. From the beating of Rabi oscillations from a "double NV...

Kim, Changdong

2011-08-08T23:59:59.000Z

112

Workshop on diamond and diamond-like-carbon films for the transportation industry  

SciTech Connect (OSTI)

Applications exist in advanced transportation systems as well as in manufacturing processes that would benefit from superior tribological properties of diamond, diamond-like-carbon and cubic boron nitride coatings. Their superior hardness make them ideal candidates as protective coatings to reduce adhesive, abrasive and erosive wear in advanced diesel engines, gas turbines and spark-ignited engines and in machining and manufacturing tools as well. The high thermal conductivity of diamond also makes it desirable for thermal management not only in tribological applications but also in high-power electronic devices and possibly large braking systems. A workshop has been recently held at Argonne National Laboratory entitled ``Diamond and Diamond-Like-Carbon Films for Transportation Applications`` which was attended by 85 scientists and engineers including top people involved in the basic technology of these films and also representatives from many US industrial companies. A working group on applications endorsed 18 different applications for these films in the transportation area alone. Separate abstracts have been prepared.

Nichols, F.A.; Moores, D.K. [eds.

1993-01-01T23:59:59.000Z

113

Very low friction for diamond sliding on diamond in water Plasma Processing Laboratory, Auburn University, 200 Broun Hall, Auburn, Alabama 36849  

E-Print Network [OSTI]

on a polished polycrystalline chemically vapor deposited diamond film in water at a speed of 0.05 mm/s underVery low friction for diamond sliding on diamond in water Y. Tzeng Plasma Processing Laboratory for publication 17 September 1993) This letter reports the lowest coefficient of friction measured for diamond

Tzeng, Yonhua

114

Method to fabricate micro and nano diamond devices  

DOE Patents [OSTI]

A method including forming a diamond material on the surface of a substrate; forming a first contact and a separate second contact; and patterning the diamond material to form a nanowire between the first contact and the second contact. An apparatus including a first contact and a separate second contact on a substrate; and a nanowire including a single crystalline or polycrystalline diamond material on the substrate and connected to each of the first contact and the second contact.

Morales, Alfredo M; Anderson, Richard J; Yang, Nancy Y. C.; Skinner, Jack L; Rye, Michael J

2014-10-07T23:59:59.000Z

115

Effectiveness of guidelines for retiming signalized diamond interchanges  

E-Print Network [OSTI]

OF SCIENCE May 1991 Major Subject: Civil Engineering EFFECTIVENESS OF GUIDELINES FOR RETIMING SIGNALIZED DIAMOND INTERCHANGES A Thesis by YVONNE DENISE IRVINE Approved as to style and content by: Daniel B. Fambro (Chair of Committee) Thomas Urbanik.... For the diamond interchange test, the participants were randomly assigned to two groups: the control group with no guidelines as reference or the second group, with the guidelines. The average scores on the diamond interchange test were compared using analysis...

Irvine, Yvonne Denise

1991-01-01T23:59:59.000Z

116

Measurement of tool forces in diamond turning  

SciTech Connect (OSTI)

A dynamometer has been designed and built to measure forces in diamond turning. The design includes a 3-component, piezoelectric transducer. Initial experiments with this dynamometer system included verification of its predicted dynamic characteristics as well as a detailed study of cutting parameters. Many cutting experiments have been conducted on OFHC Copper and 6061-T6 Aluminum. Tests have involved investigation of velocity effects, and the effects of depth and feedrate on tool forces. Velocity has been determined to have negligible effects between 4 and 21 m/s. Forces generally increase with increasing depth of cut. Increasing feedrate does not necessarily lead to higher forces. Results suggest that a simple model may not be sufficient to describe the forces produced in the diamond turning process.

Drescher, J.; Dow, T.A.

1988-12-01T23:59:59.000Z

117

Precision diamond grinding of ceramics and glass  

SciTech Connect (OSTI)

A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

Smith, S.; Paul, H.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

118

amorphous diamond films: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

simulations of the nanometer-scale indentation of amorphous-carbon thin films Materials Science Websites Summary: , and lattice constants of both solid-state diamond and...

119

Electroless nickel: an important coating for diamond turning applications  

SciTech Connect (OSTI)

Diamond turning is the use of a single-point diamond tool on a precision lathe under very precisely controlled machine and environmental conditions to fabricate finished components. With a machine presently available at LLNL a part accuracy between 0.05 and 1.0 ..mu..m (2 and 40 millionths of an inch) is obtainable. Coatings offer significant advantages for diamond turning applications inasmuch as they can be applied to lightweight substrates such as aluminum or beryllium. One of the most used coatings for diamond turning applications is electroless nickel. Purpose of this paper is to document case histories of such applications and suggest areas for future work.

Dini, J.W.

1980-09-24T23:59:59.000Z

120

Robust Diamond-Based RF Switch Yields Enhanced Communication...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Robust Diamond-Based RF Switch Yields Enhanced Communication Capabilities Technology available for licesning: A radio frequency (RF) microelectromechanical system (MEMS) switch...

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Microsoft Word - DiamondB_Easement_CX.doc  

Broader source: Energy.gov (indexed) [DOE]

Cecilia Brown Project Manager - KEWM-4 Proposed Action: Provision of funds to Montana Fish, Wildlife & Parks to purchase the Diamond B conservation easement. Fish and Wildlife...

122

Synthesis and characterization of a nanocrystalline diamond aerogel  

E-Print Network [OSTI]

nanocrystalline diamond aerogel Peter J. Pauzauskie a,1,2 ,Laboratory, Berkeley, CA 94720 Aerogel materials have myriadcreating a nanodiamond aerogel matrix has remained an

Pauzauskie, Peter J.

2012-01-01T23:59:59.000Z

123

Luminescence Dating `I also brought it [a diamond] to some  

E-Print Network [OSTI]

Includes ­ Thermoluminescence (TL), Optically stimulated luminescence (OSL), infrared stimulatedLuminescence Dating `I also brought it [a diamond] to some kind of glimmering light by taking

Sengun, Mehmet Haluk

124

Yield Optimization of Nitrogen Vacancy Centers in Diamond  

E-Print Network [OSTI]

Atomic Force Microscopy APD Avalanche Photodiode CCD Charge Coupled Device CVD Chemical Vapor Deposition DC Direct Current ESR... CHAPTER I INTRODUCTION ................................................................................ …. .1 II THEORY .................................................................................................... .3 A. Diamond...

Chen, Jeson

2012-10-19T23:59:59.000Z

125

amorphous diamond flat: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

32 Synthesis and characterization of single-wall carbon nanotubeamorphous diamond thin-film composites Materials Science Websites Summary: . Ultrahard, transparent,...

126

Diamonds are an Electronic Device's Best Friend | Department...  

Broader source: Energy.gov (indexed) [DOE]

way to combine diamond films with two other materials important for advanced devices, graphene and gallium nitride. Graphene is a rising star of the materials science world, with...

127

amorphous diamond-like carbon: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 Atmospheric plasma deposition of diamond-like carbon coatings Angela M. Ladwig a,b, Materials Science Websites Summary: Atmospheric plasma deposition of diamond-like carbon...

128

adherent diamond-like carbon: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 Atmospheric plasma deposition of diamond-like carbon coatings Angela M. Ladwig a,b, Materials Science Websites Summary: Atmospheric plasma deposition of diamond-like carbon...

129

Panel 2 - properties of diamond and diamond-like-carbon films  

SciTech Connect (OSTI)

This panel attempted to identify and prioritize research and development needs in determining the physical, mechanical and chemical properties of diamond and diamond-like-carbon films (D/DLCF). Three specific goals were established. They were: (1) To identify problem areas which produce concern and require a better knowledge of D/DLCF properties. (2) To identify and prioritize key properties of D/DLCF to promote transportation applications. (3) To identify needs for improvement in properties-measurement methods. Each of these goals is addressed subsequently.

Blau, P.J.; Clausing, R.E. [Oak Ridge National Lab., TN (United States); Ajayi, O.O.; Liu, Y.Y.; Purohit, A. [Argonne National Lab., IL (United States); Bartelt, P.F. [Deere & Co., Moline, IL (United States); Baughman, R.H. [Allied Signal, Morristown, NJ (United States); Bhushan, B. [Ohio State Univ., Columbus (United States); Cooper, C.V. [United Technologies Research Center, East Hartford, CT (United States); Dugger, M.T. [Sandia National Laboratories, Albuquerque, NM (United States); Freedman, A. [Aerodyne Research, Inc., Billerica, MA (United States); Larsen-Basse, J. [National Science Foundation, Washington, DC (United States); McGuire, N.R. [Caterpillar, Peoria, IL (United States); Messier, R.F. [Pennsylvania State Univ., University Park (United States); Noble, G.L.; Ostrowki, M.H. [John Crane, Inc., Morton Grove, IL (United States); Sartwell, B.D. [Naval Research Lab., Washington, DC (United States); Wei, R. [Colorado State Univ., Fort Collins (United States)

1993-01-01T23:59:59.000Z

130

Patterning of nanocrystalline diamond films for diamond microstructures useful in MEMS and other devices  

DOE Patents [OSTI]

MEMS structure and a method of fabricating them from ultrananocrystalline diamond films having average grain sizes of less than about 10 nm and feature resolution of less than about one micron . The MEMS structures are made by contacting carbon dimer species with an oxide substrate forming a carbide layer on the surface onto which ultrananocrystalline diamond having average grain sizes of less than about 10 nm is deposited. Thereafter, microfabrication process are used to form a structure of predetermined shape having a feature resolution of less than about one micron.

Gruen, Dieter M. (Downers Grove, IL); Busmann, Hans-Gerd (Bremen, DE); Meyer, Eva-Maria (Bremen, DE); Auciello, Orlando (Bolingbrook, IL); Krauss, Alan R. (late of Naperville, IL); Krauss, Julie R. (Naperville, IL)

2004-11-02T23:59:59.000Z

131

NEW HIGH STRENGTH AND FASTER DRILLING TSP DIAMOND CUTTERS  

SciTech Connect (OSTI)

The manufacture of thermally stable diamond (TSP) cutters for drill bits used in petroleum drilling requires the brazing of two dissimilar materials--TSP diamond and tungsten carbide. The ENDURUS{trademark} thermally stable diamond cutter developed by Technology International, Inc. exhibits (1) high attachment (shear) strength, exceeding 345 MPa (50,000 psi), (2) TSP diamond impact strength increased by 36%, (3) prevents TSP fracture when drilling hard rock, and (4) maintains a sharp edge when drilling hard and abrasive rock. A novel microwave brazing (MWB) method for joining dissimilar materials has been developed. A conventional braze filler metal is combined with microwave heating which minimizes thermal residual stress between materials with dissimilar coefficients of thermal expansion. The process results in preferential heating of the lower thermal expansion diamond material, thus providing the ability to match the thermal expansion of the dissimilar material pair. Methods for brazing with both conventional and exothermic braze filler metals have been developed. Finite element modeling (FEM) assisted in the fabrication of TSP cutters controllable thermal residual stress and high shear attachment strength. Further, a unique cutter design for absorbing shock, the densification of otherwise porous TSP diamond for increased mechanical strength, and diamond ion implantation for increased diamond fracture resistance resulted in successful drill bit tests.

Robert Radtke

2006-01-31T23:59:59.000Z

132

Method and apparatus for diamond wire cutting of metal structures  

DOE Patents [OSTI]

A method and apparatus for diamond wire cutting of metal structures, such as nuclear reactor vessels, is provided. A diamond wire saw having a plurality of diamond beads with beveled or chamfered edges is provided for sawing into the walls of the metal structure. The diamond wire is guided by a plurality of support structures allowing for a multitude of different cuts. The diamond wire is cleaned and cooled by CO.sub.2 during the cutting process to prevent breakage of the wire and provide efficient cutting. Concrete can be provided within the metal structure to enhance cutting efficiency and reduce airborne contaminants. The invention can be remotely controlled to reduce exposure of workers to radioactivity and other hazards.

Parsells, Robert; Gettelfinger, Geoff; Perry, Erik; Rule, Keith

2005-04-19T23:59:59.000Z

133

Secondary-electron emission from hydrogen-terminated diamond  

SciTech Connect (OSTI)

Diamond amplifiers demonstrably are an electron source with the potential to support high-brightness, high-average-current emission into a vacuum. We recently developed a reliable hydrogenation procedure for the diamond amplifier. The systematic study of hydrogenation resulted in the reproducible fabrication of high gain diamond amplifier. Furthermore, we measured the emission probability of diamond amplifier as a function of the external field and modelled the process with resulting changes in the vacuum level due to the Schottky effect. We demonstrated that the decrease in the secondary electrons average emission gain was a function of the pulse width and related this to the trapping of electrons by the effective NEA surface. The findings from the model agree well with our experimental measurements. As an application of the model, the energy spread of secondary electrons inside the diamond was estimated from the measured emission.

Wang E.; Ben-Zvi, I.; Rao, T.; Wu, Q.; Dimitrov, D.A.; T. Xin, T.

2012-05-20T23:59:59.000Z

134

Black Diamond Power Co | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:form ViewBlack Diamond Power Co Jump to: navigation,

135

Diamond Based TE Materials | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent CompanyaUSAMPRelated Path DependenceDiamond Based TE

136

Bruce Diamond | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofofOxford SiteToledoSampling atSFO |Alternate|BenefitsDiamond |

137

Nanocrystalline diamond synthesized from C60 Natalia Dubrovinskaia*, Leonid Dubrovinsky, Falko Langenhorst,  

E-Print Network [OSTI]

, the synthesis of nanocrystalline films of diamond-like carbon (DLC) and polycrystalline cubic diamond have display excellent properties as surface coating for metals [9]. Polycrystalline cubic diamond synthesisedNanocrystalline diamond synthesized from C60 Natalia Dubrovinskaia*, Leonid Dubrovinsky, Falko

Jacobsen, Steven D.

138

The electrical and optical properties of thin lm diamond implanted with silicon  

E-Print Network [OSTI]

:Si alloys were formed by the implantation of Si into polycrystalline diamond ®lms grown by che- mical vaporThe electrical and optical properties of thin ®lm diamond implanted with silicon K.J. Roea,* , J of diamond make it an attractive material for use in extreme conditions. Diamond devices have been fabricated

Kolodzey, James

139

Integrated High-Quality Factor Optical Resonators in Diamond B. J. M. Hausmann,,  

E-Print Network [OSTI]

-performance devices places stringent requirements on the diamond film quality. For example, polycrystalline diamond associated with polycrystalline and ion-sliced single crystal diamond films. For example, low-loss opticalIntegrated High-Quality Factor Optical Resonators in Diamond B. J. M. Hausmann,, I. B. Bulu,, P. B

Loncar, Marko

140

Reduced thermal resistance of the silicon-synthetic diamond composite substrates at elevated temperatures  

E-Print Network [OSTI]

/Si sub- strates, depends on the polycrystalline-diamond grain size, diamond layer thicknessReduced thermal resistance of the silicon-synthetic diamond composite substrates at elevated of synthetic diamond-silicon composite substrates. Although composite substrates are more thermally resistive

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Mantle-related carbonados? Geochemical insights from diamonds from the Dachine komatiite (French Guiana)  

E-Print Network [OSTI]

Carbonado is a unique type of polycrystalline diamond characterised, among others, by 13 C-depleted isotope carbonado diamonds are polycrystalline, but the reciprocal is not true, i.e. a polycrystalline diamond is not necessarily a carbonado. Most classifications for polycrystalline diamonds are established according

Cartigny, Pierre

142

THE ELECTRICAL AND OPTICAL PROPERTIES OF THIN FILM DIAMOND IMPLANTED WITH SILICON  

E-Print Network [OSTI]

devices. The C:Si alloys were formed by the implantation of Si into polycrystalline diamond films grownTHE ELECTRICAL AND OPTICAL PROPERTIES OF THIN FILM DIAMOND IMPLANTED WITH SILICON K. J. Roe and J and electrical properties of diamond make it an attractive material for use in extreme conditions. Diamond

Kolodzey, James

143

Field emission properties of phosphorus doped microwave plasma chemical vapor deposition diamond films by ion implantation  

E-Print Network [OSTI]

2002; published 5 February 2003 Phosphorus doped polycrystalline diamond films were grown using ion the electrical char- acteristics of diamond FEAs to lower the operating voltage. Polycrystalline diamond hasField emission properties of phosphorus doped microwave plasma chemical vapor deposition diamond

Lee, Jong Duk

144

Boron Doping of Microcrystalline and Nanocrystalline Diamond Films: Where is the Boron Paul William May1  

E-Print Network [OSTI]

is that polycrystalline boron-doped CVD diamond films possess grain boundaries containing a small-volume fraction of non-diamondBoron Doping of Microcrystalline and Nanocrystalline Diamond Films: Where is the Boron Going? Paul `cauliflower'-type nanocrystalline (c-NCD) CVD diamond films vary as a function of B content. The conductivity

Bristol, University of

145

Estimation of parameters in thermal-field emission from diamond D.G. Walkera  

E-Print Network [OSTI]

: Thermal field emission; Diamond film 1. Introduction Polycrystalline diamond films can exhibit outstanding polycrystalline diamond films at elevated temperatures. Thermal effects are included in the models and provide. Wang et al. [10] observed emission from the region between grains in polycrystalline diamond films

Walker, D. Greg

146

Atomistic simulations of structures and mechanical properties of S011diamond  

E-Print Network [OSTI]

Polycrystalline diamond films obtained by chemical vapor deposition CVD have numerous applications due and their triple junctions in diamond O. A. Shenderova and Donald W. Brenner Department of Materials Science triple junctions TJ's in diamond as well as a multiply twinned diamond particle have been calculated

Brenner, Donald W.

147

Nano-diamonds in the Universe A.C. Andersen,1  

E-Print Network [OSTI]

Nano-diamonds in the Universe A.C. Andersen,1 H. Mutschke,2 L. Binette3 , S. Höfner4 1 NORDITA, SE-75120 Uppsala Sweden The first direct evidence for nano-diamonds in space came from meteorites. Laboratory analyses on fine-grained diamond residues from primitive meteorites have shown that nano- diamonds

Andersen, Anja C.

148

Coupling of nitrogen-vacancy centers in diamond to a GaP waveguide  

E-Print Network [OSTI]

The optical coupling of guided modes in a GaP waveguide to nitrogen-vacancy (NV) centers in diamond is demonstrated. The electric field penetration into diamond and the loss of the guided mode are measured. The results indicate that the GaP-diamond system could be useful for realizing coupled microcavity-NV devices for quantum information processing in diamond.

K. -M. C. Fu; C. Santori; P. E. Barclay; I. Aharonovich; S. Prawer; N. Meyer; A. M. Holm; R. G. Beausoleil

2008-11-03T23:59:59.000Z

149

Performance evaluation of bound diamond ring tools  

SciTech Connect (OSTI)

LLNL is collaborating with the Center for Optics Manufacturing (COM) and the American Precision Optics Manufacturers Association (APOMA) to optimize bound diamond ring tools for the spherical generation of high quality optical surfaces. An important element of this work is establishing an experimentally-verified link between tooling properties and workpiece quality indicators such as roughness, subsurface damage and removal rate. In this paper, we report on a standardized methodology for assessing ring tool performance and its preliminary application to a set of commercially-available wheels. Our goals are to (1) assist optics manufacturers (users of the ring tools) in evaluating tools and in assessing their applicability for a given operation, and (2) provide performance feedback to wheel manufacturers to help optimize tooling for the optics industry. Our paper includes measurements of wheel performance for three 2-4 micron diamond bronze-bond wheels that were supplied by different manufacturers to nominally- identical specifications. Preliminary data suggests that the difference in performance levels among the wheels were small.

Piscotty, M.A.; Taylor, J.S.; Blaedel, K.L.

1995-07-14T23:59:59.000Z

150

Diamond Magnetometry of Superconducting Thin Films  

E-Print Network [OSTI]

In recent years diamond magnetometers based on the nitrogen-vacancy (NV) center have been of considerable interest for magnetometry applications at the nanoscale. An interesting application which is well suited for NV centers is the study of nanoscale magnetic phenomena in superconducting materials. We employ the magnetic sensitivity of NV centers in diamond to interrogate the magnetic properties of a thin-layer yttrium barium copper oxide (YBCO) superconductor. Using fluorescence-microscopy methods and samples integrated with an NV sensor on a microchip, we measure the temperature of phase transition in the layer to be 70.0(2) K, and the penetration field of vortices to be 46(4) G. We observe the pinning of the vortices in the layer at 65 K, and estimate their density after cooling the sample in a ~ 10 G field to be 0.45(1) \\mu m^{-2}. These measurements are done with a 10 nm thick NV layer, so that high spatial resolution may be enabled in the future. Based on these results, we anticipate that this magnetometer could be useful for imaging the structure and dynamics of vortices. As an outlook, we present a fabrication method for a superconductor chip designed for this purpose.

A. Waxman; H. Schlussel; D. Groswasser; V. M. Acosta; L. -S. Bouchard; D. Budker; R. Folman

2014-02-05T23:59:59.000Z

151

Well drilling tool with diamond radial/thrust bearings  

SciTech Connect (OSTI)

A turbodrill is disclosed for connection to a drill string and has a rotating shaft for turning a drill bit. The turbodrill has rotor and stator blades operated by drilling mud flowing therethrough to rotate the shaft. The shaft is provided with radial/thrust bearing consisting of a pair of annular plates, each of which has conical surfaces supporting a plurality of friction bearing members of polycrystalline diamond. The radial and thrust loads are carried by the wear-resistant diamond bearing surfaces. The bearing members are preferably cylindrical studs having flat faces with flat disc-shaped diamond bearing members supported thereon around the adjacent surfaces of the supporting plates. The faces of the diamond bearings will wear into smoothly mating conical bearing surfaces with use. There are two or more pairs of diamond radial/thrust bearings to handle longitudinal as well as radial loads. The use of the diamond radial/thrust bearings makes it possible to eliminate the lubricant-flooded construction of prior art turbodrills and allow the bearings to be cooled and lubricated be drilling fluid flowing therethrough. The diamond radial/thrust bearings may be used with lubricant-flooded turbodrills and with other types of downhole motor driven drills such as drills driven by positive displacement motors.

Nagel, D.D.; Aparicio, T. Jr.

1983-10-18T23:59:59.000Z

152

Implantation conditions for diamond nanocrystal formation in amorphous silica  

SciTech Connect (OSTI)

We present a study of carbon ion implantation in amorphous silica, which, followed by annealing in a hydrogen-rich environment, leads to preferential formation of carbon nanocrystals with cubic diamond (c-diamond), face-centered cubic (n-diamond), or simple cubic (i-carbon) carbon crystal lattices. Two different annealing treatments were used: furnace annealing for 1 h and rapid thermal annealing for a brief period, which enables monitoring of early nucleation events. The influence of implanted dose and annealing type on carbon and hydrogen concentrations, clustering, and bonding were investigated. Rutherford backscattering, elastic recoil detection analysis, infrared spectroscopy, transmission electron microscopy, selected area electron diffraction, ultraviolet-visible absorption measurements, and Raman spectroscopy were used to study these carbon formations. These results, combined with the results of previous investigations on similar systems, show that preferential formation of different carbon phases (diamond, n-diamond, or i-carbon) depends on implantation energy, implantation dose, and annealing conditions. Diamond nanocrystals formed at a relatively low carbon volume density are achieved by deeper implantation and/or lower implanted dose. Higher volume densities led to n-diamond and finally to i-carbon crystal formation. This observed behavior is related to damage sites induced by implantation. The optical properties of different carbon nanocrystal phases were significantly different.

Buljan, Maja; Radovic, Iva Bogdanovic; Desnica, Uros V.; Ivanda, Mile; Jaksic, Milko [Ruder Boskovic Institute, P.O. Box 180, 10002 Zagreb (Croatia); Saguy, Cecile; Kalish, Rafi [Physics Department and Solid State Institute, Technion, Haifa 32000 (Israel); Djerdj, Igor [Department of Materials, Swiss Federal Institute of Technology (ETH) Zuerich, Wolfgang-Pauli-Str. 10, CH-8093 Zuerich (Switzerland); Tonejc, Andelka [Faculty of Science, Department of Physics, University of Zagreb, 10000 Zagreb (Croatia); Gamulin, Ozren [School of Medicine, Zagreb University, 10000 Zagreb (Croatia)

2008-08-01T23:59:59.000Z

153

Printable, flexible and stretchable diamond for thermal management  

DOE Patents [OSTI]

Various heat-sinked components and methods of making heat-sinked components are disclosed where diamond in thermal contact with one or more heat-generating components are capable of dissipating heat, thereby providing thermally-regulated components. Thermally conductive diamond is provided in patterns capable of providing efficient and maximum heat transfer away from components that may be susceptible to damage by elevated temperatures. The devices and methods are used to cool flexible electronics, integrated circuits and other complex electronics that tend to generate significant heat. Also provided are methods of making printable diamond patterns that can be used in a range of devices and device components.

Rogers, John A; Kim, Tae Ho; Choi, Won Mook; Kim, Dae Hyeong; Meitl, Matthew; Menard, Etienne; Carlisle, John

2013-06-25T23:59:59.000Z

154

Software optimization for electrical conductivity imaging in polycrystalline diamond cutters  

SciTech Connect (OSTI)

We previously reported on an electrical conductivity imaging instrument developed for measurements on polycrystalline diamond cutters. These cylindrical cutters for oil and gas drilling feature a thick polycrystalline diamond layer on a tungsten carbide substrate. The instrument uses electrical impedance tomography to profile the conductivity in the diamond table. Conductivity images must be acquired quickly, on the order of 5 sec per cutter, to be useful in the manufacturing process. This paper reports on successful efforts to optimize the conductivity reconstruction routine, porting major portions of it to NVIDIA GPUs, including a custom CUDA kernel for Jacobian computation.

Bogdanov, G.; Ludwig, R. [Department of Electrical and Computer Engineering, Worcester Polytechnic Institute, 100 Institute Rd, Worcester, MA 01609 (United States); Wiggins, J.; Bertagnolli, K. [US Synthetic, 1260 South 1600 West, Orem, UT 84058 (United States)

2014-02-18T23:59:59.000Z

155

Observation of diamond turned OFHC copper using Scanning Tunneling Microscopy  

SciTech Connect (OSTI)

Diamond turned OFHC copper samples have been observed within the past few months using the Scanning Tunneling Microscope. Initial results have shown evidence of artifacts which may be used to better understand the diamond turning process. The STM`s high resolution capability and three dimensional data representation allows observation and study of surface features unobtainable with conventional profilometry systems. Also, the STM offers a better quantitative means by which to analyze surface structures than the SEM. This paper discusses findings on several diamond turned OFHC copper samples having different cutting conditions. Each sample has been cross referenced using STM and SEM.

Grigg, D.A.; Russell, P.E.; Dow, T.A.

1988-12-01T23:59:59.000Z

156

Electrodeposited coatings for diamond turning applications  

SciTech Connect (OSTI)

Electrodeposited coatings are attractive for precision machining operations because thick coatings can be economically applied, with good adhesion, to a variety of substrates. Approximately 20 pure metals and a large number of alloys can be deposited from aqueous solutions. Fused salt and organic solvent electrolytes can be used to lengthen the list of metals that can be electrodeposited. However, both the choice of the metallic coating and the control of the plating process are critical for success in precision finishing of electrodeposited coatings. Some preliminary results at the National Institute of Standards and Technology and at the Lawrence Livermore National Laboratory suggest that electrodeposited nickel-phosphorus alloys are excellent coatings for single point diamond turning from the standpoint of material properties and low tool wear. Electrodeposited aluminum and aluminum alloy coatings also merit consideration for precision finishing where weight is an important factor. 10 refs., 6 figs.

Mayer, A.; Bramlett, R.D.; Day, R.D. (Los Alamos National Lab., NM (USA)); Evans, C.J.; Polvani, R.S. (National Inst. of Standards and Technology, Gaithersburg, MD (USA))

1991-01-01T23:59:59.000Z

157

From Ultrananocrystalline Diamond to Single Crystal Diamond Growth in Hot Filament and Microwave Plasma-Enhanced CVD Reactors: a Unified Model for Growth Rates and  

E-Print Network [OSTI]

From Ultrananocrystalline Diamond to Single Crystal Diamond Growth in Hot Filament and Microwave, Moscow State UniVersity, 119991 Moscow, Russia ReceiVed: April 29, 2008 CVD Diamond can now be deposited either in the form of single crystal homoepitaxial layers, or as polycrystalline films with crystal sizes

Bristol, University of

158

Diamond graphs and super-reflexivity William B. Johnson  

E-Print Network [OSTI]

Diamond graphs and super-reflexivity William B. Johnson and Gideon Schechtman Abstract The main results is that dimension reduction a-la Johnson­Lindenstrauss fails in any non super reflexive space

Johnson, William B.

159

Electrochemical hydrogen termination of boron-doped diamond  

SciTech Connect (OSTI)

Boron-doped diamond is a promising transducer material for numerous devices which are designed for contact with electrolytes. For optimized electron transfer the surface of diamond needs to be hydrogen terminated. Up to now H-termination of diamond is done by plasma chemical vapor deposition techniques. In this paper, we show that boron-doped diamond can be H-terminated electrochemically by applying negative voltages in acidic solutions. Electrochemical H-termination generates a clean surface with virtually no carbon-oxygen bonds (x-ray photoelectron spectroscopy), a reduced electron affinity (scanning electron microscopy), a highly hydrophobic surface (water contact angle), and a fast electron exchange with Fe(CN){sub 6}{sup -3/-4} (cyclic voltammetry).

Hoffmann, Rene; Kriele, Armin; Obloh, Harald; Hees, Jakob; Wolfer, Marco; Smirnov, Waldemar; Yang Nianjun; Nebel, Christoph E. [Fraunhofer Institute for Applied Solid State Physics (IAF), Tullastrasse 72, Freiburg 79108 (Germany)

2010-08-02T23:59:59.000Z

160

Spin properties of very shallow nitrogen vacancy defects in diamond  

E-Print Network [OSTI]

We investigate spin and optical properties of individual nitrogen vacancy centers located within 1–10 nm from the diamond surface. We observe stable defects with a characteristic optically detected magnetic-resonance ...

Ofori-Okai, Benjamin Kwasi

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Thin diamond films provide new material for micro-machines |...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thin diamond films provide new material for micro-machines By Jared Sagoff * July 31, 2014 Tweet EmailPrint ARGONNE, Ill. - Airbags, inkjet printers and video projectors may not...

162

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents [OSTI]

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

163

Large piezoresistive effect in surface conductive nanocrystalline diamond  

SciTech Connect (OSTI)

Surface conductivity in hydrogen-terminated single crystal diamond is an intriguing phenomenon for fundamental reasons as well as for application driven research. Surface conductivity is also observed in hydrogen-terminated nanocrystalline diamond although the electronic transport mechanisms remain unclear. In this work, the piezoresistive properties of intrinsic surface conductive nanocrystalline diamond are investigated. A gauge factor of 35 is calculated from bulging a diamond membrane of 350?nm thick, with a diameter of 656??m and a sheet resistance of 1.45 M?/sq. The large piezoresistive effect is reasoned to originate directly from strain-induced changes in the resistivity of the grain boundaries. Additionally, we ascribe a small time-dependent fraction of the piezoresistive effect to charge trapping of charge carriers at grain boundaries. In conclusion, time-dependent piezoresistive effect measurements act as a tool for deeper understanding the complex electronic transport mechanisms induced by grain boundaries in a polycrystalline material or nanocomposite.

Janssens, S. D., E-mail: stoffel.d.janssens@gmail.com; Haenen, K., E-mail: ken.haenen@uhasselt.be [Institute for Materials Research (IMO), Hasselt University, Wetenschapspark 1, B-3590 Diepenbeek (Belgium); IMOMEC, IMEC vzw, Wetenschapspark 1, B-3590 Diepenbeek (Belgium); Drijkoningen, S. [Institute for Materials Research (IMO), Hasselt University, Wetenschapspark 1, B-3590 Diepenbeek (Belgium)

2014-09-08T23:59:59.000Z

164

Strategic level expert system design for diamond interchange control  

E-Print Network [OSTI]

The selection of control for a diamond interchange is based upon many factors, including the geometry of the interchange, the current traffic patterns, and expected traffic patterns. Each possible control plan for an interchange is more applicable...

Patrone, David Michael

1999-01-01T23:59:59.000Z

165

Mixing Water and Oil Under Static High Pressure H.K. Ploeg1, M.D. McCluskey2,3, G.J. Hanna2,3  

E-Print Network [OSTI]

University of Michigan, Ann Arbor, MI 2 Institute for Shock Physics, Washington State University, Pullman, WA 3Dept. of Physics and Astronomy, Washington State University, Pullman, WA The diamond anvil cell a phase change is observed at about 9.8kbar. ·The phase diagram (left) confirms that the cell contains ice

Collins, Gary S.

166

Analysis of the influence of tool dynamics in diamond turning  

SciTech Connect (OSTI)

This report describes the progress in defining the role of machine and interface dynamics on the surface finish in diamond turning. It contains a review of literature from conventional and diamond machining processes relating tool dynamics, material interactions and tool wear to surface finish. Data from experimental measurements of tool/work piece interface dynamics are presented as well as machine dynamics for the DTM at the Center.

Fawcett, S.C.; Luttrell, D.E.; Keltie, R.F.

1988-12-01T23:59:59.000Z

167

Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix  

DOE Patents [OSTI]

A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al/sub 2/O/sub 3/ yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

Taylor, G.W.; Roybal, H.E.

1983-11-14T23:59:59.000Z

168

Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix  

DOE Patents [OSTI]

A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al.sub.2 O.sub.3 yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

Taylor, Gene W. (Los Alamos, NM); Roybal, Herman E. (Santa Fe, NM)

1985-01-01T23:59:59.000Z

169

Boron Doped diamond films as electron donors in photovoltaics: An X-ray absorption and hard X-ray photoemission study  

SciTech Connect (OSTI)

Highly boron-doped diamond films are investigated for their potential as transparent electron donors in solar cells. Specifically, the valence band offset between a diamond film (as electron donor) and Cu(In,Ga)Se{sub 2} (CIGS) as light absorber is determined by a combination of soft X-ray absorption spectroscopy and hard X-ray photoelectron spectroscopy, which is more depth-penetrating than standard soft X-ray photoelectron spectroscopy. In addition, a theoretical analysis of the valence band is performed, based on GW quasiparticle band calculations. The valence band offset is found to be small: VBO?=?VBM{sub CIGS} – VBM{sub diamond}?=?0.3?eV?±?0.1?eV at the CIGS/Diamond interface and 0.0?eV?±?0.1?eV from CIGS to bulk diamond. These results provide a promising starting point for optimizing the band offset by choosing absorber materials with a slightly lower valence band maximum.

Kapilashrami, M.; Zegkinoglou, I. [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Physics, University of Wisconsin Madison, Madison, Wisconsin 53706 (United States); Conti, G.; Nemšák, S.; Conlon, C. S.; Fadley, C. S. [Department of Physics, University of California, Davis, California 95616 (United States); Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Törndahl, T.; Fjällström, V. [Ångström Solar Center, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden); Lischner, J. [Department of Physics, University of California, Berkeley, California 94720 (United States); Louie, Steven G. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Physics, University of California, Berkeley, California 94720 (United States); Hamers, R. J.; Zhang, L. [Department of Chemistry, University of Wisconsin Madison, Madison, Wisconsin 53706 (United States); Guo, J.-H. [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Himpsel, F. J., E-mail: fhimpsel@wisc.edu [Department of Physics, University of Wisconsin Madison, Madison, Wisconsin 53706 (United States)

2014-10-14T23:59:59.000Z

170

Diagnostic of fusion neutrons on JET tokamak using diamond detector  

SciTech Connect (OSTI)

In 2011-2012, an experimental campaign with a significant yield of fusion neutrons was carried out on the JET tokamak. During this campaign the facility was equipped with two diamond detectors based on natural and artificial CVD diamond. These detectors were designed and manufactured in State Research Center of Russian Federation TRINITI. The detectors measure the flux of fast neutrons with energies above 0.2 MeV. They have been installed in the torus hall and the distance from the center of plasma was about 3 m. For some of the JET pulses in this experiment, the neutron flux density corresponded to the operational conditions in collimator channels of ITER Vertical Neutron Camera. The main objective of diamond monitors was the measurement of total fast neutron flux at the detector location and the estimation of the JET total neutron yield. The detectors operate as threshold counters. Additionally a spectrometric measurement channel has been configured that allowed us to distinguish various energy components of the neutron spectrum. In this paper we describe the neutron signal measuring and calibration procedure of the diamond detector. Fluxes of DD and DT neutrons at the detector location were measured. It is shown that the signals of total neutron yield measured by the diamond detector correlate with signals measured by the main JET neutron diagnostic based on fission chambers with high accuracy. This experiment can be considered as a successful test of diamond detectors in ITER-like conditions.

Nemtsev, G.; Amosov, V.; Marchenko, N.; Meshchaninov, S.; Rodionov, R. [Institution Project center ITER, Moscow (Russian Federation); Popovichev, S. [EURATOM-CCFE Fusion Association, Culham Science Centre, Abingdon, OXON, OX14 3DB (United Kingdom); Collaboration: JET EFDA Conbributors

2014-08-21T23:59:59.000Z

171

The influence of surface preparation on the electrochemistry of boron doped diamond: A study of the reduction of  

E-Print Network [OSTI]

; Surface modification 1. Introduction Electrodes based on polycrystalline diamond are presently generating significant interest. Polycrystalline diamond possesses physical properties that suggest that electrodesThe influence of surface preparation on the electrochemistry of boron doped diamond: A study

Bristol, University of

172

Elasticity, strength, and toughness of single crystal silicon carbide, ultrananocrystalline diamond, and hydrogen-free tetrahedral amorphous  

E-Print Network [OSTI]

Elasticity, strength, and toughness of single crystal silicon carbide, ultrananocrystalline diamond carbide 3C-SiC , ultrananocrystalline diamond, and hydrogen-free tetrahedral amorphous carbon

Espinosa, Horacio D.

173

E-Print Network 3.0 - adherent cvd diamond Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: adherent cvd diamond Page: << < 1 2 3 4 5 > >> 1 Thin Film Diamond by Chemical Vapour Deposition Methods M. N. R. Ashfold, P. W. May, and C. A....

174

Proceedings of the Seventh Applied Diamond Conference/Third Frontier Carbon  

E-Print Network [OSTI]

Proceedings of the Seventh Applied Diamond Conference/Third Frontier Carbon Technology Joint of the Seventh Applied Diamond Conference/Third Frontier Carbon Technology Joint Conference (ADC/FCT 2003) NASA

Tzeng, Yonhua

175

Progress in the Advanced Synthetic-Diamond Drill Bit Program  

SciTech Connect (OSTI)

Cooperative research is currently underway among five drill bit companies and Sandia National Laboratories to improve synthetic-diamond drill bits for hard-rock applications. This work, sponsored by the US Department of Energy and individual bit companies, is aimed at improving performance and bit life in harder rock than has previously been possible to drill effectively with synthetic-diamond drill bits. The goal is to extend to harder rocks the economic advantages seen in using synthetic-diamond drill bits in soft and medium rock formations. Four projects are being conducted under this research program. Each project is investigating a different area of synthetic diamond bit technology that builds on the current technology base and market interests of the individual companies involved. These projects include: optimization of the PDC claw cutter; optimization of the Track-Set PDC bit; advanced TSP bit development; and optimization of impregnated-diamond drill bits. This paper describes the progress made in each of these projects to date.

Glowka, D.A. [Sandia National Labs., Albuquerque, NM (United States); Dennis, T. [Dennis Tool Co., Houston, TX (United States); Le, Phi [Security DBS, Houston, TX (United States); Cohen, J. [Maurer Engineering, Inc., Houston, TX (United States); Chow, J. [Hughes Christensen Co., Salt Lake City, UT (United States)

1995-11-01T23:59:59.000Z

176

Stress state of diamond and gold under nonhydrostatic compression Jianghua Wang,1  

E-Print Network [OSTI]

for the polycrystalline gold under the highest load. Polycrystalline diamond can support a microscopic deviatoric stress of polycrystalline diamond and gold in the DAC under nonhydrostatic compression to above 300 GPa. The influenceStress state of diamond and gold under nonhydrostatic compression to 360 GPa Jianghua Wang,1

Duffy, Thomas S.

177

Effects of phosphorus implantation and subsequent growth on diamond Euo Sik Choa,*, Cheon An Leea  

E-Print Network [OSTI]

]. Espe- cially, polycrystalline diamond films grown by microwave plasma chemical vapor deposition (MPCVD, and their fabrication is easy and economical. Polycrystalline diamond film has a rough surface and a lot of defectsEffects of phosphorus implantation and subsequent growth on diamond Euo Sik Choa,*, Cheon An Leea

Lee, Jong Duk

178

Thermal conductivity of nitrogenated ultrananocrystalline diamond films M. Shamsa,1,a  

E-Print Network [OSTI]

, polycrystalline diamond PCD , diamondlike carbon DLC , carbon nanotubes, and single-layer graphene, have recentlyThermal conductivity of nitrogenated ultrananocrystalline diamond films on silicon M. Shamsa,1,a S of nitrogenated ultrananocrystalline diamond UNCD films on silicon. For better accuracy, the thermal conductivity

179

Grafting odorant binding proteins on diamond bio-MEMS R. Manai a,  

E-Print Network [OSTI]

. Beside, cantilevers based on polycrystalline diamond surfaces are very promising as chemical transducers. Here two methods were investigated for chemically grafting porcine OBPs onto polycrystalline diamond1 Grafting odorant binding proteins on diamond bio-MEMS R. Manai a, *, E. Scorsone a , L. Rousseau

Boyer, Edmond

180

A Study of the Grain Boundaries and Hydrogen in HF-CVD Diamond Films  

E-Print Network [OSTI]

composition of grain boundaries in polycrystalline diamond lms by transmission electron microscopy and highA Study of the Grain Boundaries and Hydrogen in HF-CVD Diamond Films Israel Yoel Koenka #12;A Study of the Grain Boundaries and Hydrogen in HF-CVD Diamond Films Research Thesis In partial fulllment

Adler, Joan

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Raman spectroscopy study of the influence of processing conditions on the structure of polycrystalline diamond films  

E-Print Network [OSTI]

of polycrystalline diamond films R. Ramamurti, V. Shanov, and R. N. Singha Department of Chemical and Materials is obvious, especially when polycrystalline diamond PCD is considered for optical and electronic applications-0030 Received 17 May 2005; accepted 14 November 2005; published 8 February 2006 Diamond films are prepared

Boolchand, Punit

182

Simulations of polycrystalline CVD diamond film growth using a simplified Monte Carlo model  

E-Print Network [OSTI]

Simulations of polycrystalline CVD diamond film growth using a simplified Monte Carlo model P online 6 November 2009 Keywords: CVD diamond growth Modelling Nucleation Nanodiamond A simple 1) of a diamond (100) surface. The model considers adsorption, etching/desorption, lattice incorporation

Bristol, University of

183

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent  

E-Print Network [OSTI]

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent being marketed [83,84]. The first paper on the electrochemistry of boron doped polycrystalline diamond The electrochemistry of boron doped diamond is currently an active field of research. In the majority of studies

Bristol, University of

184

Moleculardynamics simulation of thermal stress at the (100) diamond/substrate interface: effect of film continuity  

E-Print Network [OSTI]

with the development of advanced CVD techniques 2 producing polycrystalline diamond of quality approachingMolecular­dynamics simulation of thermal stress at the (100) diamond/substrate interface: effect at the (100) diamond/substrate interface. The stress­induced binding energy reduction obtained

Adler, Joan

185

Transitions in morphology observed in nitrogenmethanehydrogen depositions of polycrystalline diamond films  

E-Print Network [OSTI]

% and 1% methane­hydrogen depositions of polycrystalline diamond films. Five results are reported. 1.1063/1.1362406 I. INTRODUCTION Controlled, textured growth of polycrystalline diamond films would be desirable of polycrystalline diamond films: 2% CH4 /H2 and 1% CH4 /H2 . Five results are reported and discussed. II

Ayres, Virginia

186

Charge Collection in the MERIT Diamond Detectors Kirk T. McDonald  

E-Print Network [OSTI]

, Princeton University, Princeton, NJ 08544 (February 18, 2010) The polycrystalline diamond detectors usedCharge Collection in the MERIT Diamond Detectors Kirk T. McDonald Joseph Henry Laboratories detectors used a bias field of 1 V/m, i.e., 500 V.1 The capacitance of the diamond detector itself was about

McDonald, Kirk

187

Studies of n-type doping and surface modification of CVD diamond for use  

E-Print Network [OSTI]

strategy in chemical vapour deposition (CVD) of polycrystalline diamond films. Lithium nitride (Li3NStudies of n-type doping and surface modification of CVD diamond for use in thermionic applications-type dopants in diamond, the work has examined the use of Li-N codoping as a possible alternative doping

Bristol, University of

188

Microcrystalline diamond micromechanical resonators with quality factor limited by thermoelastic damping  

E-Print Network [OSTI]

using polycrystalline films. However, polycrystalline diamond films may not retain the desirable, while j approaching 2000 W mÀ1 KÀ1 has been demonstrated in thick (250­500 lm) polycrystalline diamondMicrocrystalline diamond micromechanical resonators with quality factor limited by thermoelastic

Lin, Liwei

189

Spatially-Correlated Microstructure and Superconductivity in Polycrystalline Boron-Doped Diamond  

E-Print Network [OSTI]

Spatially-Correlated Microstructure and Superconductivity in Polycrystalline Boron-Doped Diamond F tunneling spectroscopies are performed below 100 mK on nano-crystalline boron-doped diamond films been discovered in heavily doped group IV covalent semicon- ductors [1], in particular diamond [2

190

The Influence of Doping Levels and Surface Termination on the Electrochemistry of Polycrystalline Diamond  

E-Print Network [OSTI]

of Polycrystalline Diamond Matthew N. Latto, Gustavo Pastor-Moreno, D. Jason Riley* School of Chemistry, University on the redox chemistry of Fe(CN)3À=4À 6 at CVD polycrystalline diamond electrodes is considered diamond metallic electrochemical behavior is always observed, even at boron doping densities as low as 7 Â

Bristol, University of

191

Elastic properties of transparent nano-polycrystalline diamond measured by GHz-ultrasonic interferometry and resonant  

E-Print Network [OSTI]

Elastic properties of transparent nano-polycrystalline diamond measured by GHz-ultrasonic interferometry Sphere resonance Nano-polycrystalline diamond NPD Elastic properties Superhard materials a b s t r a c t The sound velocities and elastic moduli of transparent nano-polycrystalline diamond (NPD) have

Jacobsen, Steven D.

192

Atomistic simulations of structures and mechanical properties of polycrystalline diamond: Symmetrical S001< tilt grain boundaries  

E-Print Network [OSTI]

Atomistic simulations of structures and mechanical properties of polycrystalline diamond for diamond to deposit as a polycrystalline film with a high density of grain boundaries and related defects structures and energies of symmetrical 001 tilt grain boundaries GB's in diamond have been calculated over

Brenner, Donald W.

193

Alumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed reactor  

E-Print Network [OSTI]

/high-temperature (HP/HT) synthesis methods [4­7] led to the discovery of polycrystalline diamond grit and the manufacture of polycrystalline diamond compact (PDC) materials [8]. PDC cutters are well known and widely usedAlumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed

George, Steven M.

194

Direct engraving of quantum point contacts in heterostructures with a diamond tip  

E-Print Network [OSTI]

of polycrystalline diamond onto a pre-patterned silicon substrate [7]. The results of the engraving procedure usingDirect engraving of quantum point contacts in heterostructures with a diamond tip J. Regul, U. F-Universit¨at Bochum, 44780 Bochum, Germany Abstract. We use the all-diamond tip of an atomic force microscope

Hohls, Frank

195

Fabrication of adherent porous diamond films on sintered WC-13 wt.%Co  

E-Print Network [OSTI]

and lower threshold voltages for field emission [10]. Conductive polycrystalline diamond films are alsoFabrication of adherent porous diamond films on sintered WC-13 wt.%Co substrates by bias enhanced 2011, accepted 3 May 2011 Published online 10 August 2011 Keywords diamond films, HFCVD, porous, WC

Bristol, University of

196

Electrical and optical properties of diamond-like carbon films deposited by pulsed laser ablation  

E-Print Network [OSTI]

films, which make them more useful than polycrystalline diamond films for many applications. For exampleElectrical and optical properties of diamond-like carbon films deposited by pulsed laser ablation K e i n f o Available online 11 March 2010 Keyword: Pulsed laser ablation Diamond-like carbon films

Bristol, University of

197

Spatially-correlated microstructure and superconductivity in polycrystalline Boron-doped diamond  

E-Print Network [OSTI]

Spatially-correlated microstructure and superconductivity in polycrystalline Boron-doped diamond F are performed below 100 mK on polycrystalline Boron-doped diamond films characterized by Transmission Electron and the superconducting proximity effect.8,9 Neverthe- less, recent studies of polycrystalline diamond films10,11 did

Paris-Sud XI, Université de

198

Atomistic modeling of the fracture of polycrystalline diamond O. A. Shenderova and D. W. Brenner  

E-Print Network [OSTI]

Atomistic modeling of the fracture of polycrystalline diamond O. A. Shenderova and D. W. Brenner characteristic of GB toughness. Crack propagation in polycrystalline diamond samples under an applied load of several 001 and 011 symmetrical tilt grain boundaries GB's in diamond. Cohesive energies, the work

Brenner, Donald W.

199

FIELD EMISSION FROM BORON-DOPING POLYCRYSTALLINE DIAMOND FILMS ON SILICON  

E-Print Network [OSTI]

FIELD EMISSION FROM BORON-DOPING POLYCRYSTALLINE DIAMOND FILMS ON SILICON J. A. N. Gonçalves, G. M material fail. The field emission current from boron-doped polycrystalline diamond films grown by hot Campos, SP, Brazi Abstract This work deals with the study and development of the boron-doped diamond

200

Raman and Photoluminescence Spectroscopy of Nanocrystalline Diamond Films grown by Hot Filament CVD  

E-Print Network [OSTI]

H4 flow-rate ratio of standard polycrystalline diamond deposition parameters on formationRaman and Photoluminescence Spectroscopy of Nanocrystalline Diamond Films grown by Hot Filament CVD of Physics, University of Malaya, 50603 Kuala Lumpur, Malaysia b,c Diamond Research Laboratory, School

Bristol, University of

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Unravelling aspects of the gas phase chemistry involved in diamond chemical vapour deposition  

E-Print Network [OSTI]

of thin Ðlms of polycrystalline diamond by chemi- cal vapour deposition (CVD) methods,2h4 since which timeUnravelling aspects of the gas phase chemistry involved in diamond chemical vapour deposition been used to unravel details of the gas phase chemistry involved in diamond chemical vapour deposition

Bristol, University of

202

EXPERIMENTAL DEMONSTRATION OF WAKEFIELD EFFECTS IN A 250 GHZ PLANAR DIAMOND ACCELERATING STRUCTURE*  

E-Print Network [OSTI]

of a rectangular waveguide loaded with polycrystalline CVD diamond plates as an accelerating structure. It should polycrystalline diamond plates loaded in a 6 cm long waveguide (Fig. 2). The beam gap was 200 microns (Fig. TM11EXPERIMENTAL DEMONSTRATION OF WAKEFIELD EFFECTS IN A 250 GHZ PLANAR DIAMOND ACCELERATING STRUCTURE

Brookhaven National Laboratory

203

Characterization of B-doped polycrystalline diamond films using thermally stimulated luminescence  

E-Print Network [OSTI]

1 Characterization of B-doped polycrystalline diamond films using thermally stimulated luminescence, boron level in polycrystalline diamond films was identified by TL by an intense glow peak at 226 K polycrystalline diamond films grown by Chemical Vapor Deposition (CVD) have a wide array of potential applications

Paris-Sud XI, Université de

204

Electrical characterisation of defects in polycrystalline B-doped diamond films  

E-Print Network [OSTI]

applied to B-doped thin polycrystalline diamond films deposited on p+ -silicon by hot filament chemical]. Recently valuable information about defects in monocrystalline [3] and polycrystalline [7] diamond filmsElectrical characterisation of defects in polycrystalline B-doped diamond films O. S. Elsherif 1, a

Bristol, University of

205

In Situ Tribo-Electrochemical Characterization of Diamond-Containing Materials  

E-Print Network [OSTI]

diamond carbon (sp^(3)) to amorphous carbon (sp^(2)) is confirmed by Raman spectroscopy in the diamond composite. The surface roughness of the diamond grits was found to be greatly reduced due to wear. A tribo-electrochemical method is developed to in situ...

Xiao, Huaping

2014-07-31T23:59:59.000Z

206

RESEARCH HIGHLIGHTS Dark matter lost and found  

E-Print Network [OSTI]

-component condensate.They considered the limited access inherent to samples confined in a diamond anvil cell the gas disks of two spiral galaxies merge. As spirals have dark-matter haloes, their elliptical offspring­Einstein condensate within a ring- shaped magnetic trap (Phys. Rev. Lett. (in the press); preprint at http

Loss, Daniel

207

Spin crossover equation of state and sound velocities of (Mg0.65Fe0.35)O ferropericlase to 140 GPa  

E-Print Network [OSTI]

Spin crossover equation of state and sound velocities of (Mg0.65Fe0.35)O ferropericlase to 140 GPa August 2012. [1] We have determined the elastic and vibrational properties of periclase-structured (Mg0 in diamond-anvil cells at 300 K. Combining with in situ XRD measurements, the Debye sound velocity of FP35

Jackson, Jennifer M.

208

Life in Solid Ice on Earth and Other Planetary Bodies P. Buford Price  

E-Print Network [OSTI]

to spores. 1. Liquid veins in polycrystalline ice as a microbial habitat In phase equilibrium at temperatures below the liquidus and above the eutectic, polycrystalline ice comprises a two-phase system. coli and Shewanella oneidensis (a piezophile) in a diamond anvil cell. At pressures 1.2 to 1.6 Gpa

Price, P. Buford

209

A quenchable superhard carbon phase synthesized by cold compression of carbon nanotubes  

E-Print Network [OSTI]

A quenchable superhard carbon phase synthesized by cold compression of carbon nanotubes Zhongwu) A quenchable superhard high-pressure carbon phase was synthe- sized by cold compression of carbon nanotubes. Carbon nanotubes were placed in a diamond anvil cell, and x-ray diffraction measure- ments were conducted

Downs, Robert T.

210

Science and technology review, March 1996  

SciTech Connect (OSTI)

This publication contains two feature articles and one research highlight. The first feature article is on the safe disposal of nuclear wastes. The second article is about using the Lab`s diamond anvil cell to probe the behavior of nuclear weapons related materials. The research highlight is on using hydrogen fuel for hybrid vehicles.

Failor, B.; Wheatcraft, D. [eds.

1996-03-01T23:59:59.000Z

211

Research papers Polymerization of aqueous silica in H2OK2O solutions at 25200 C and 1 bar  

E-Print Network [OSTI]

Research papers Polymerization of aqueous silica in H2O­K2O solutions at 25­200 °C and 1 bar to 20 Aqueous silica polymerization Diamond anvil cell Alkaline uids Ab initio calculation Understanding the polymerization of aqueous silica is important for modeling uid­rock interactions at high pressure and temperature

Manning, Craig

212

Aluminum speciation in aqueous fluids at deep crustal pressure and temperature  

E-Print Network [OSTI]

Aluminum speciation in aqueous fluids at deep crustal pressure and temperature Mainak Mookherjee a Abstract We investigated aluminum speciation in aqueous fluids in equilibrium with corundum using in situ Raman spectroscopy in hydrothermal diamond anvil cells to 20 kbar and 1000 °C. We have studied aluminum

Manning, Craig

213

Capacitively coupled RF diamond-like-carbon reactor  

DOE Patents [OSTI]

A process of coating a non-conductive fiber with diamond-like carbon, including passing a non-conductive fiber between a pair of parallel metal grids within a reaction chamber, introducing a hydrocarbon gas into the reaction chamber, forming a plasma within the reaction chamber for a sufficient period of time whereby diamond-like carbon is formed upon the non-conductive fiber, is provided together with a reactor chamber for deposition of diamond-like carbon upon a non-conductive fiber, including a vacuum chamber, a cathode assembly including a pair of electrically isolated opposingly parallel metal grids spaced apart at a distance of less than about 1 centimeter, an anode, a means of introducing a hydrocarbon gas into said vacuum chamber, and a means of generating a plasma within said vacuum chamber.

Devlin, David James (Los Alamos, NM); Coates, Don Mayo (Santa Fe, NM); Archuleta, Thomas Arthur (Espanola, NM); Barbero, Robert Steven (Santa Cruz, NM)

2000-01-01T23:59:59.000Z

214

Diamond tool wear of electrodeposited nickel-phosphorus alloy  

SciTech Connect (OSTI)

Nickel-Phosphorus alloys are attractive materials for diamond turning applications such as fabrication of large optics and other high precision parts. Although the mechanism is not understood, diamond tool wear is minimized when the phosphorus content of the deposit is greater than 11% (wgt). In recent years, increased attention has been directed at electrodeposition as an alternate to electroless deposition for producing Ni-P alloys. One principal advantage of the electrodeposition process is that alloys with 14--15% P can be obtained; another is that an order of magnitude greater deposition thickness can be provided if necessary. This paper compares diamond turning results for electrodeposited and electroless Ni-P alloys and shows that the electrodeposited coatings provide promising results. 28 refs., 7 figs., 1 tab.

Dini, J.W.; Donaldson, R.R.; Syn, C.K. (Lawrence Livermore National Lab., CA (USA)); Sugg, D.J. (Techmetals, Inc., Dayton, OH (USA))

1990-02-01T23:59:59.000Z

215

Diamond-Silicon Carbide Composite And Method For Preparation Thereof  

DOE Patents [OSTI]

Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5-8 GPa, T=1400K-2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa.multidot.m.sup.1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.

Qian, Jiang (Los Alamos, NM); Zhao, Yusheng (Los Alamos, NM)

2005-09-06T23:59:59.000Z

216

Mapping the location and configuration of nitrogen in diamond nanoparticles.  

SciTech Connect (OSTI)

Understanding how impurities such as nitrogen are included in diamond nanoparticles is expected to be important for use in future nanodevices, such as qubits for quantum computing. Most commercial diamond nanoparticles contain approximately 2-3% nitrogen, but it is difficult to determine experimentally whether it is located within the core or at the surface of the nanoparticles. Presented here are density functional tight-binding simulations examining the configuration and potential energy surface of substitutional nitrogen in diamond nanoparticles, directly comparing results of different sizes, shapes and surface chemistry. The results predict that nitrogen is metastable within the core of both hydrogenated and dehydrogenated particles, but that the binding energy, coordination and preferred location is dependent upon the structure of the nanoparticle as a whole.

Barnard, A. S.; Sternberg, M.; Center for Nanoscale Materials; Univ. of Oxford

2007-01-17T23:59:59.000Z

217

Subtractive 3D Printing of Optically Active Diamond Structures  

E-Print Network [OSTI]

Diamond has recently attracted considerable attention as a promising platform for quantum technologies, photonics and high resolution sensing applications. Here we demonstrate a chemical approach that enables the fabrication of functional diamond structures using gas-mediated electron induced etching. The method achieves chemical etching at room temperature through the dissociation of surface-adsorbed H2O molecules by electron irradiation in a water vapor environment. High throughput, parallel processing is possible by electron flood exposure and the use of an etch mask, while single step, mask-free three dimensional fabrication and iterative editing are achieved using a variable pressure scanning electron microscope. The electron induced chemical etching paves the way to a transformative technology for nanofabrication of diamond and other wide band-gap semiconductors.

Martin, Aiden A; Aharonovich, Igor

2014-01-01T23:59:59.000Z

218

Photonic nano-structures on (111)-oriented diamond  

SciTech Connect (OSTI)

We demonstrate the fabrication of single-crystalline diamond nanopillars on a (111)-oriented chemical vapor deposited diamond substrate. This crystal orientation offers optimal coupling of nitrogen-vacancy (NV) center emission to the nanopillar mode and is thus advantageous over previous approaches. We characterize single native NV centers in these nanopillars and find one of the highest reported saturated fluorescence count rates in single crystalline diamond in excess of 10{sup 6} counts per second. We show that our nano-fabrication procedure conserves the preferential alignment as well as the spin coherence of the NVs in our structures. Our results will enable a new generation of highly sensitive probes for NV magnetometry and pave the way toward photonic crystals with optimal orientation of the NV center's emission dipole.

Neu, Elke; Appel, Patrick; Ganzhorn, Marc; Miguel-Sánchez, Javier; Maletinsky, Patrick, E-mail: patrick.maletinsky@unibas.ch [Department of Physics, University of Basel, Klingelbergstrasse 82, CH-4056 Basel (Switzerland); Lesik, Margarita; Jacques, Vincent [Laboratoire Aimé Cotton, CNRS, Université Paris-Sud and Ecole Normale Supérieure de Cachan, F-91405 Orsay (France); Mille, Vianney; Tallaire, Alexandre; Achard, Jocelyn [Université Paris 13, Sorbonne Paris Cité, Laboratoire des Sciences des Procédés et des Matériaux (CNRS UPR 3407), F-93430 Villetaneuse (France)

2014-04-14T23:59:59.000Z

219

Diamond turning of Si and Ge single crystals  

SciTech Connect (OSTI)

Single-point diamond turning studies have been completed on Si and Ge crystals. A new process model was developed for diamond turning which is based on a critical depth of cut for plastic flow-to-brittle fracture transitions. This concept, when combined with the actual machining geometry for single-point turning, predicts that {open_quotes}ductile{close_quotes} machining is a combined action of plasticity and fracture. Interrupted cutting experiments also provide a meant to directly measure the critical depth parameter for given machining conditions.

Blake, P.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

220

Smooth diamond films as low friction, long wear surfaces  

DOE Patents [OSTI]

An article and method of manufacture of a nanocrystalline diamond film. The nanocrystalline film is prepared by forming a carbonaceous vapor, providing an inert gas containing gas stream and combining the gas stream with the carbonaceous containing vapor. A plasma of the combined vapor and gas stream is formed in a chamber and fragmented carbon species are deposited onto a substrate to form the nanocrystalline diamond film having a root mean square flatness of about 50 nm deviation from flatness in the as deposited state.

Gruen, Dieter M. (Downers Grove, IL); Krauss, Alan R. (Naperville, IL); Erdemir, Ali (Naperville, IL); Bindal, Cuma (Woodridge, IL); Zuiker, Christopher D. (LaGrange, IL)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Boron-doped superlattices and Bragg mirrors in diamond  

SciTech Connect (OSTI)

A periodic modulation of the boron doping level of single crystal diamond multilayers over more than three orders of magnitude during epitaxial growth by microwave plasma-enhanced chemical vapor deposition is shown to yield Bragg mirrors in the visible. The thicknesses and doping level of the individual layers were controlled by in situ spectroscopic ellipsometry, enabling to tune the reflectance peak to the wavelength range of diamond color centers, such as NV{sup 0} or NV{sup ?}. The crystalline quality, periodicity, and sharpness of the doping transitions in these doping superlattices over tens of periods were confirmed by high resolution X-ray diffraction.

Fiori, A. [University of Grenoble Alpes, Inst. NEEL, 38042 Grenoble (France); CNRS, Inst. NEEL, 25 rue des Martyrs, 38042 Grenoble (France); National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Bousquet, J.; Eon, D.; Omnès, F.; Bustarret, E., E-mail: Etienne.bustarret@neel.cnrs.fr [University of Grenoble Alpes, Inst. NEEL, 38042 Grenoble (France); CNRS, Inst. NEEL, 25 rue des Martyrs, 38042 Grenoble (France); Bellet-Amalric, E. [University of Grenoble Alpes, Inst. NEEL, 38042 Grenoble (France); CEA-Grenoble, INAC/SP2M, 17 rue des Martyrs, 38054 Grenoble (France)

2014-08-25T23:59:59.000Z

222

Polycrystal diamond growth in a microwave plasma torch  

SciTech Connect (OSTI)

Diamond films of different structures were deposited on quartz, WC-Co, and molybdenum substrates in a microwave plasma torch discharge in an argon-hydrogen-methane gas mixture in a sealed chamber at pressures close to atmospheric by using the chemical vapor deposition technique. Images of diamond polycrystal films and separate crystals, as well as results of Raman spectroscopy, are presented. The spectra of optical plasma radiation recorded during film deposition demonstrate the presence of intense H{sub {alpha}} hydrogen and C{sub 2} radical bands known as Swan bands.

Sergeichev, K. F.; Lukina, N. A.; Bolshakov, A. P.; Ralchenko, V. G.; Arutyunyan, N. R.; Vlasov, I. I. [Russian Academy of Sciences, Prokhorov Institute of General Physics (Russian Federation)

2010-12-15T23:59:59.000Z

223

The role of inert gas in MW-enhanced plasmas for the deposition of nanocrystalline diamond thin films  

E-Print Network [OSTI]

in polycrystalline diamond film CVD [3,4]. While the mechanical, thermal and acoustic properties of MCD films haveThe role of inert gas in MW-enhanced plasmas for the deposition of nanocrystalline diamond thin diamond Nanocrystalline Inert gas Growth Nanocrystalline diamond thin films have been deposited using

Bristol, University of

224

Laser-processed three dimensional graphitic electrodes for diamond radiation detectors  

SciTech Connect (OSTI)

We have used an original approach for diamond detectors where three dimensional buried graphitic electrodes are processed in the bulk of a diamond substrate via laser-induced graphitization. Prototype made of polycrystalline chemical vapor deposition diamond was fabricated using a nanosecond UV laser. Its charge collection efficiency was evaluated using ?-particles emitted by a 241-Americium source. An improved charge collection efficiency was measured proving that laser micro-machining of diamond is a valid option for the future fabrication of three dimensional diamond detectors.

Caylar, Beno?-carett; Pomorski, Michal; Bergonzo, Philippe [CEA-LIST, Diamond Sensors Laboratory, Gif-sur-Yvette F-91191 (France)] [CEA-LIST, Diamond Sensors Laboratory, Gif-sur-Yvette F-91191 (France)

2013-07-22T23:59:59.000Z

225

Controlled incorporation of mid-to-high Z transition metals in CVD diamond  

SciTech Connect (OSTI)

We report on a general method to fabricate transition metal related defects in diamond. Controlled incorporation of Mo and W in synthetic CVD diamond was achieved by adding volatile metal precursors to the diamond chemical vapor deposition (CVD) growth process. Effects of deposition temperature, grain structure and precursor exposure on the doping level were systematically studied, and doping levels of up to 0.25 at.% have been achieved. The metal atoms are uniformly distributed throughout the diamond grains without any indication of inclusion formation. These results are discussed in context of the kinetically controlled growth process of CVD diamond.

Biener, M M; Biener, J; Kucheyev, S O; Wang, Y M; El-Dasher, B; Teslich, N E; Hamza, A V; Obloh, H; Mueller-Sebert, W; Wolfer, M; Fuchs, T; Grimm, M; Kriele, A; Wild, C

2010-01-08T23:59:59.000Z

226

The chemistry of halogens on diamond: effects on growth and electron emission  

SciTech Connect (OSTI)

Diamond growth using halogenated precursors was studied in several diamond growth reactors. In a conventionao plasma reactor, diamond growth using the following gas mixtures was studied: CF{sub 4}/H{sub 2}, CH{sub 4}/H{sub 2}, CH{sub 3}F/H{sub 2}, and CH{sub 3}CL/H{sub 2}. Both the diamond growth measurements demonstrated ineffective transport of halogen radicals to the diamond surface during the growth process. In order to transport radical halogen species to the diamond surface during growth, a flow-tube reactor was constructed which minimized gas phase reactions. Also, the flow-tube reactor enabled pulsed gs transport to the diamond surface by fast-acting valves. Molecular beam mass spectroscopy was used to find condition which resulted in atomic hydrogen and/or atomic fluorine transport to the growing diamond surface. Although such conditions were found, they required very low pressures (0.5 Torr and below); these low pressures produce radical fluxes which are too low to sustain a reasonable diamond growth rate. The sequential reactor at Stanford was modified to add a halogen-growth step to the conventinoal atomic hydrogen/atomic carbon diamond growth cycle. Since the atomic fluorine, hydrogen and carbon environments are independent in the sequential reactor, the effect of fluorine on diamond growth could be studied independently of gas phase reactions. Although the diamond growth rate was increased by the use of fluorine, the film quality was seen to deteriorate as well as the substrate surface. Moreover, materials incompatibilities with fluorine significantly limited the use of fluorine in this reactor. A diamond growth model incorporating both gas phase and surface reactions was developed for the halocarbon system concurrent with the film growth efforts. In this report, we review the results of the growth experiments, the modeling, and additional experiments done to understand fluorine with diamond surfaces.

Hsu, W.L.; Pan, L.S.; Brown, L.A. [Sandia National Labs., Livermore, CA (United States)] [and others

1997-02-01T23:59:59.000Z

227

Diamond Lattice Model of Semicrystalline Polyethylene in the Amorphous Region  

E-Print Network [OSTI]

Diamond Lattice Model of Semicrystalline Polyethylene in the Amorphous Region Zhong­Hui Duan Abstract The statistics of polyethylene chains in the amorphous region between two crystallites have been as models of the chain molecules in the amorphous region of semicrystalline polyethylene, both

Aluffi, Paolo

228

New route to the fabrication of nanocrystalline diamond films  

SciTech Connect (OSTI)

Nanocrystalline diamond (NCD) thin films offer applications in various fields, but the existing synthetic approaches are cumbersome and destructive. A major breakthrough has been achieved by our group in the direction of a non-destructive, scalable, and economic process of NCD thin-film fabrication. Here, we report a cheap precursor for the growth of nanocrystalline diamond in the form of paraffin wax. We show that NCD thin films can be fabricated on a copper support by using simple, commonplace paraffin wax under reaction conditions of Hot Filament Chemical Vapor Deposition (HFCVD). Surprisingly, even the presence of any catalyst or seeding that has been conventionally used in the state-of-the-art is not required. The structure of the obtained films was analyzed by scanning electron microscopy and transmission electron microscopy. Raman spectroscopy and electron energy-loss spectroscopy recorded at the carbon K-edge region confirm the presence of nanocrystalline diamond. The process is a significant step towards cost-effective and non-cumbersome fabrication of nanocrystalline diamond thin films for commercial production.

Varshney, Deepak, E-mail: deepvar20@gmail.com; Morell, Gerardo [Institute of Functional Nanomaterials, University of Puerto Rico, San Juan, Puerto Rico 00931, Puerto Rico (United States); Department of Physics, University of Puerto Rico, San Juan, PO Box 70377, Puerto Rico 00936, Puerto Rico (United States); Palomino, Javier; Resto, Oscar [Department of Physics, University of Puerto Rico, San Juan, PO Box 70377, Puerto Rico 00936, Puerto Rico (United States); Gil, Jennifer [Department of Chemistry, University of Puerto Rico, San Juan, Puerto Rico 00936, Puerto Rico (United States); Weiner, Brad R. [Institute of Functional Nanomaterials, University of Puerto Rico, San Juan, Puerto Rico 00931, Puerto Rico (United States); Department of Chemistry, University of Puerto Rico, San Juan, Puerto Rico 00936, Puerto Rico (United States)

2014-02-07T23:59:59.000Z

229

Quantum optics with nitrogen-vacancy centers in diamond  

E-Print Network [OSTI]

We review the electronic level structure of the nitrogen-vacancy in diamond and some common experimental techniques to study its optical properties at low temperatures. We then summarize several recent experiments and advances in using nitrogen-vacancy centers for quantum optics.

Yiwen Chu; Mikhail D. Lukin

2015-04-22T23:59:59.000Z

230

Diamond Wire Saw for Precision Machining of Laser Target Components  

SciTech Connect (OSTI)

The fabrication of precision laser targets requires a wide variety of specialized mesoscale manufacturing techniques. The diamond wire saw developed in this study provides the capability to precisely section meso-scale workpieces mounted on the assembly stations used by the Target Fabrication Group. This new capability greatly simplifies the fabrication of many types of targets and reduces the time and cost required to build the targets. A variety of materials are used to fabricate targets, including metals, plastics with custom designed chemical formulas, and aerogels of various densities. The materials are usually provided in the form of small pieces or cast rods that must be machined to the required shape. Many of these materials, such as metals and some plastics, can be trimmed using a parting tool on a diamond turning machine. However, other materials, such as aerogels and brittle materials, cannot be adequately cut with a parting tool. In addition, the geometry of the parts often requires that the workpieces be held in a special assembly station, which excludes the use of a parting tool. In the past, these materials were sectioned using a small, handheld coping saw that used a diamond-impregnated wire as a blade. This miniature coping saw was effective, but it required several hours to cut through certain materials. Furthermore, the saw was guided by hand and often caused significant damage to fragile aerogels. To solve these problems, the diamond wire saw shown in Figure 1 was developed. The diamond wire saw is designed to machine through materials that are mounted in the Target Fabrication Group's benchtop assembly stations. These assembly stations are the primary means of aligning and assembling target components, and there is often a need to machine materials while they are mounted in the assembly stations. Unfortunately, commercially available saws are designed for very different applications and are far too large to be used with the assembly stations. Therefore, a custom diamond wire saw was designed and constructed. The diamond wire saw cuts through workpieces using a continuous loop of diamond-impregnated wire of length 840 mm. The wire loop runs around several idler pulleys and is driven by a simple geared DC motor that rotates at 17 rpm. The linear speed of the wire is 107 inches/minute. The saw is oriented at an angle of 20{sup o} from horizontal, so the operator can view the wire through the cutout at the front end of the saw. When looking through a microscope or camera with a horizontal line of sight, the operator can clearly see the wire as it cuts through the workpiece, as shown in the right side of Figure 1. The saw is mounted on a two-axis stage that allows the operator to align the wire with the workpiece. To cut through the workpiece, the operator drives the wire through the workpiece by turning the feed micrometer. An image of the interior of the diamond wire saw appears in Figure 2. This picture was taken after removing the protective cover plate from the saw.

Bono, M J; Bennett, D W

2005-08-08T23:59:59.000Z

231

Diamond neutral particle spectrometer for fusion reactor ITER  

SciTech Connect (OSTI)

A compact diamond neutral particle spectrometer with digital signal processing has been developed for fast charge-exchange atoms and neutrons measurements at ITER fusion reactor conditions. This spectrometer will play supplementary role for Neutral Particle Analyzer providing 10 ms time and 30 keV energy resolutions for fast particle spectra in non-tritium ITER phase. These data will also be implemented for independent studies of fast ions distribution function evolution in various plasma scenarios with the formation of a single fraction of high-energy ions. In tritium ITER phase the DNPS will measure 14 MeV neutrons spectra. The spectrometer with digital signal processing can operate at peak counting rates reaching a value of 10{sup 6} cps. Diamond neutral particle spectrometer is applicable to future fusion reactors due to its high radiation hardness, fast response and high energy resolution.

Krasilnikov, V.; Amosov, V.; Kaschuck, Yu.; Skopintsev, D. [Institution PROJECT CENTER ITER, 1, Akademik Kurchatov Sq., Moscow (Russian Federation)

2014-08-21T23:59:59.000Z

232

Strategies for improving traffic operations at oversaturated signalized diamond interchanges  

E-Print Network [OSTI]

street improvement goals should include improved traffic flow along with reductions in congestion, air pollution, and energy use, without major new construction. Super-street arterials, which are multi-lane arterials with limited access and a limited...STRATEGIES FOR IMPROVING TRAFFIC OPERATIONS AT OVERSATURATED SIGNALIZED DIAMOND INTERCHANGES A Thesis by GEORGE CURTIS HERRICK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

Herrick, George Curtis

1992-01-01T23:59:59.000Z

233

Method of forming fluorine-bearing diamond layer on substrates, including tool substrates  

DOE Patents [OSTI]

A method of forming a fluorine-bearing diamond layer on non-diamond substrates, especially on tool substrates comprising a metal matrix and hard particles, such as tungsten carbide particles, in the metal matrix. The substrate and a fluorine-bearing plasma or other gas are then contacted under temperature and pressure conditions effective to nucleate fluorine-bearing diamond on the substrate. A tool insert substrate is treated prior to the diamond nucleation and growth operation by etching both the metal matrix and the hard particles using suitable etchants.

Chang, R. P. H. (Glenview, IL); Grannen, Kevin J. (Evanston, IL)

2002-01-01T23:59:59.000Z

234

New Superhard Form of Carbon Dents Diamond | U.S. DOE Office...  

Office of Science (SC) Website

exists in many different structures, each having different properties (e.g. graphite, graphene, and diamond). This research demonstrated yet another structure that is superhard,...

235

E-Print Network 3.0 - advanced diamond product Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses... , and will position Canada with Botswana and Russia as...

236

Perfect preferential orientation of nitrogen-vacancy defects in a synthetic diamond sample  

SciTech Connect (OSTI)

We show that the orientation of nitrogen-vacancy (NV) defects in diamond can be efficiently controlled through chemical vapor deposition growth on a (111)-oriented diamond substrate. More precisely, we demonstrate that spontaneously generated NV defects are oriented with a ?97% probability along the [111] axis, corresponding to the most appealing orientation among the four possible crystallographic axes. Such a nearly perfect preferential orientation is explained by analyzing the diamond growth mechanism on a (111)-oriented substrate and could be extended to other types of defects. This work is a significant step towards the design of optimized diamond samples for quantum information and sensing applications.

Lesik, M.; Roch, J.-F. [Laboratoire Aimé Cotton, CNRS, Université Paris-Sud and Ecole Normale Supérieure de Cachan, 91405 Orsay (France); Tetienne, J.-P.; Jacques, V., E-mail: vjacques@ens-cachan.fr [Laboratoire Aimé Cotton, CNRS, Université Paris-Sud and Ecole Normale Supérieure de Cachan, 91405 Orsay (France); Laboratoire de Photonique Quantique et Moléculaire, Ecole Normale Supérieure de Cachan and CNRS UMR 8537, 94235 Cachan (France); Tallaire, A., E-mail: alexandre.tallaire@lspm.cnrs.fr; Achard, J.; Mille, V.; Gicquel, A. [Laboratoire des Sciences des Procédés et des Matériaux, CNRS and Université Paris 13, 93340 Villetaneuse (France)

2014-03-17T23:59:59.000Z

237

Use of diamond-turned mirrors for synchrotron radiation (SR)  

SciTech Connect (OSTI)

The diamond turning technique has great interest for users of synchrotron radiation because of its ability to produce surfaces of arbitrary shape. It also has the advantage of being well adapted to producing metal optics. These are of interest because they lend themselves to water cooling and hence represent one approach to the problem of high synchrotron radiation power loadings on optical surfaces. The optical figure produced by diamond turning is generally adequate for synchrotron radiation applications. The main difficulty centers around the question of smoothness. Diamond turned surfaces must receive a final polish after machining before they are sufficiently smooth for use with ultra-violet or x-ray radiation. The manufacturing stages can be carried out by various groups in the optics industry and the National Synchrotron Light Source has procured a considerable number of mirrors and is having them polished for use on the vuv storage ring. At the time of writing one mirror has been completed and evaluated and we give the results for this and discuss the indications for the future. The important measurement of the r.m.s. height of the surface roughness has given a value of 3 +- 0.9A using total integrated scatter of visible light at normal incidence.

Howells, M.R.; Takacs, P.Z.

1981-01-01T23:59:59.000Z

238

Deposition of CVD diamond onto GaN P.W. May a,*, H.Y. Tsai b  

E-Print Network [OSTI]

of the polycrystalline diamond surface would prevent light from leaking out of the GaN layer and channel it to the endsDeposition of CVD diamond onto GaN P.W. May a,*, H.Y. Tsai b , W.N. Wang c , J.A. Smith a a School performed to deposit continuous layers of CVD diamond onto epitaxial GaN films. Such diamond coatings would

Bristol, University of

239

Evidence for a mantle component shown by rare gases, C and N isotopes in polycrystalline diamonds from Orapa (Botswana)  

E-Print Network [OSTI]

Evidence for a mantle component shown by rare gases, C and N isotopes in polycrystalline diamonds. Farley Abstract In an attempt to constrain the origin of polycrystalline diamond, combined analyses in the source of the polycrystalline diamonds from Orapa. The y13 C and y15 N isotopic values of À1.04 to À9.79x

Cartigny, Pierre

240

785 nm Raman Spectroscopy of CVD Diamond Films Paul William May, James A Smith, and Keith N Rosser  

E-Print Network [OSTI]

. Here, we report that when using 785 nm excitation, the Raman spectra from thin polycrystalline diamond785 nm Raman Spectroscopy of CVD Diamond Films Paul William May, James A Smith, and Keith N Rosser Raman spectroscopy is a powerful technique often used to study CVD diamond films, however, very little

Bristol, University of

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Fabrication of diamond nanowires for quantum information processing applications Birgit J.M. Hausmann a,b,  

E-Print Network [OSTI]

and polycrystalline diamond. Numerical modeling was used to study coupling between a Nitrogen Vacancy (NV) color crystal diamond. The heights and diameters of the polycrystalline nanowires presented in this paper are 1Fabrication of diamond nanowires for quantum information processing applications Birgit J

Loncar, Marko

242

High-temperature electron emission from diamond films Department of Mechanical Engineering, Vanderbilt University, Nashville, Tennessee 37235  

E-Print Network [OSTI]

This work examines electron field-emission characteristics of polycrystalline diamond films at elevated in applications where high temperatures exist. Nitrogen-doped polycrystalline diamond films were grown by plasmaHigh-temperature electron emission from diamond films S. H. Shin Department of Mechanical

Walker, D. Greg

243

Diamond growth on WC-Co substrates by hot filament chemical vapor deposition: Effect of filamentsubstrate separation  

E-Print Network [OSTI]

Polycrystalline diamond films have been grown by hot filament (HF) chemical vapor deposition on WC-Co bar is an established technique for growing hard, wear- resistant polycrystalline diamond films on a range of substratesDiamond growth on WC-Co substrates by hot filament chemical vapor deposition: Effect of filament

Bristol, University of

244

Field emission properties of the polycrystalline diamond film prepared by microwave-assisted plasma chemical vapor deposition  

E-Print Network [OSTI]

Field emission properties of the polycrystalline diamond film prepared by microwave-assisted plasma Field emission characteristics for the diamond films grown using a gas mixture of different methane V 3.0 V/ m and 9 V 5.5 V/ m , respectively, for the diamond emitter of a little poor quality grown

Lee, Jong Duk

245

Evidence of universality in the dynamical response of nanomechanical ultra-nanocrystalline diamond resonators at millikelvin temperatures  

E-Print Network [OSTI]

independent theory. In particular, polycrystalline diamond is an exciting material for nanomechanical devicesEvidence of universality in the dynamical response of nanomechanical ultra-nanocrystalline diamond fabricated from ultra-nanocrystalline diamond. Frequency shift f/f0 and dissipa- tion Q-1 demonstrate

246

Direct observation of electron emission from the grain boundaries of chemical vapour deposition diamond films by tunneling atomic force microscopy  

E-Print Network [OSTI]

.1063/1.3475506 Direct observation of electron emission site on boron-doped polycrystalline diamond thin films using or energy harvesting devices. Electron emission studies usually use doped polycrystalline diamond films observation of the emission sites over a large area of polycrystalline diamond using tunneling atomic force

Bristol, University of

247

785 nm Raman spectroscopy of CVD diamond films P.W. May , J.A. Smith, K.N. Rosser  

E-Print Network [OSTI]

using 785 nm excitation with 1 µm spot size, the Raman spectra from thin polycrystalline diamond films785 nm Raman spectroscopy of CVD diamond films P.W. May , J.A. Smith, K.N. Rosser School is a powerful technique often used to study CVD diamond films, however, very little work has been reported

Bristol, University of

248

Strength of Materials, Vol. 46, No. 2, March, 2014 ANALYSIS OF FRACTURE BEHAVIOR OF THIN POLYCRYSTALLINE DIAMOND FILMS  

E-Print Network [OSTI]

POLYCRYSTALLINE DIAMOND FILMS D. S. Li,a,c,1 D. W. Zuo,a,b UDC 539.4 and Q. H. Qinc The effect of the substrate temperature and CH4 concentrations on the fracture behavior of thin polycrystalline diamond films that the fracture behavior of thin polycrystalline diamond films synthesized by direct current plasma jet chemical

Qin, Qinghua

249

Fabrication of quantum point contacts by engraving GaAsAlGaAs heterostructures with a diamond tip  

E-Print Network [OSTI]

by hot-filament chemical vapor deposition of polycrystalline diamond onto a prepat- terned siliconFabrication of quantum point contacts by engraving GaAsÕAlGaAs heterostructures with a diamond tip for publication 17 July 2002 We use the all-diamond tip of an atomic force microscope for the direct engraving

Hohls, Frank

250

Optical properties of polycrystalline diamond films in the far-infrared A. J. Gatesman, R. H. Giles, J. Waldman  

E-Print Network [OSTI]

Optical properties of polycrystalline diamond films in the far-infrared A. J. Gatesman, R. H. Giles for the complex refractive index (n - ik) of polycrystalline diamond films grown by microwave plasma enhanced a CO2 optically pumped submillimeter laser. Due to their polycrystalline nature, the diamond films

Massachusetts at Lowell, University of

251

MetalBosonic InsulatorSuperconductor Transition in Boron-Doped Granular Diamond Gufei Zhang,1,* Monika Zeleznik,2  

E-Print Network [OSTI]

. Second, the giant RðTÞ peak is observed in heavily boron-doped polycrystalline diamond thick filmsMetal­Bosonic Insulator­Superconductor Transition in Boron-Doped Granular Diamond Gufei Zhang,1 the onset of superconductivity in heavily boron-doped diamond. This anomalous RðTÞ peak in a 3D system

Bristol, University of

252

Method of bonding diamonds in a matrix and articles thus produced  

DOE Patents [OSTI]

By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

Taylor, G.W.

1981-01-27T23:59:59.000Z

253

A kinetic model of diamond nucleation and silicon carbide interlayer formation during chemical vapor deposition  

E-Print Network [OSTI]

A kinetic model of diamond nucleation and silicon carbide interlayer formation during chemical February 2005 Available online 7 April 2005 Abstract The presence of thin silicon carbide intermediate of carbon atoms into the silicon carbide layer and the morphology and orientation of the diamond film

Dandy, David

254

OSL RADIATION DOSIMETRY USING BORON DOPED CVD DIAMOND FILMS J. A. N. Gonalves1  

E-Print Network [OSTI]

de la Universidad de Sonora, Apdo. Postal 130, Hermosillo, Sonora, 83000 México The optically irradiated diamond filmsTL glow curves of beta irradiated diamond films de B/C de 4000de B/C de 4000 ppm beta irradiation and photostimulated with blue light.toa beta irradiation and photostimulated with blue

255

On the optimization of a dc arcjet diamond chemical vapor deposition reactor  

E-Print Network [OSTI]

On the optimization of a dc arcjet diamond chemical vapor deposition reactor S. W. Reevea) and W. A precursor in our dc arcjet reactor.1 Based on conclusions drawn from that work, an optimization strategy diamond film growth in a dc arcjet chemical vapor deposition reactor has been developed. Introducing

Dandy, David

256

High-dynamic-range magnetometry with a single nuclear spin in diamond  

E-Print Network [OSTI]

High-dynamic-range magnetometry with a single nuclear spin in diamond G. Waldherr1 *, J. Beck1 , P, we implement a quantum phase estimation algorithm6­8 on a single nuclear spin in diamond to combineT). If this priorinformation aboutthemagnetic fieldisnotavailable, estimation of B cannot be performed. To summarize, shorter

Pfeifer, Holger

257

Graphite-to-diamond transformation induced by ultrasound cavitation A.Kh. Khachatryan a,c  

E-Print Network [OSTI]

Graphite-to-diamond transformation induced by ultrasound cavitation A.Kh. Khachatryan a,c , S microcrystals have been synthesized using ultrasonic cavitation of a suspension of hexagonal graphite in various. © 2008 Elsevier B.V. All rights reserved. Keywords: Ultrasound cavitation; Microcrystalline diamond 1

Bristol, University of

258

A robust scanning diamond sensor for nanoscale imaging with single nitrogen-vacancy centres  

E-Print Network [OSTI]

A robust scanning diamond sensor for nanoscale imaging with single nitrogen-vacancy centres P and A. Yacoby1 * The nitrogen-vacancy defect centre in diamond1­4 has potential applications processing9 and bioimaging10 . These applications rely on the ability to pos- ition a single nitrogen-vacancy

Walsworth, Ronald L.

259

Growth of diamond films using an enclosed methyl-acetylene and propadiene combustion flame  

E-Print Network [OSTI]

1 Growth of diamond films using an enclosed methyl-acetylene and propadiene combustion flame K Abstract Diamond growth in low pressure combustion flames was studied using a safer, more economical and chemical kinetic time scales in the combustion reactor. 1 Present Address: 3M Corporation, Bldg. 60-1N-01

Dandy, David

260

Thermal conductivity changes upon neutron transmutation of {sup 10}B doped diamond  

SciTech Connect (OSTI)

{sup 10}B doped p-type diamond samples were subjected to neutron transmutation reaction using thermal neutron flux of 0.9 × 10{sup 13} cm{sup ?2} s{sup ?1} and fast neutron flux of 0.09 × 10{sup 13} cm{sup ?2} s{sup ?1}. Another sample of epilayer grown on type IIa (110) single crystal diamond substrate was subjected to equal thermal and fast neutron flux of 10{sup 14}?cm{sup ?2} s{sup ?1}. The defects in the diamond samples were previously characterized by different methods. In the present work, thermal conductivity of these diamond samples was determined at room temperature by transient thermoreflectance method. The thermal conductivity change in the samples as a function of neutron fluence is explained by the phonon scattering from the point defects and disordered regions. The thermal conductivity of the diamond samples decreased more rapidly initially and less rapidly for larger neutron fluence. In addition, the thermal conductivity in type IIb diamond decreased less rapidly with thermal neutron fluence compared to the decrease in type IIa diamond subjected to fast neutron fluence. It is concluded that the rate of production of defects during transmutation reaction is slower when thermal neutrons are used. The thermal conductivity of epilayer of diamond subjected to high thermal and fast neutron fluence is associated with the covalent carbon network in the composite structure consisting of disordered carbon and sp{sup 2} bonded nanocrystalline regions.

Jagannadham, K., E-mail: jag-kasichainula@ncsu.edu [Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Verghese, K. [Nuclear Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Butler, J. E. [Code 6174, Naval research Laboratory, Washington, District of Columbia 20375 (United States)

2014-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Vacuum encapsulated hermetically sealed diamond amplified cathode capsule and method for making same  

DOE Patents [OSTI]

A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first cold-weld ring disposed between the cathode element and the annular insulating spacer and a second cold-weld ring disposed between the annular insulating spacer and the diamond window element. The cathode capsule is formed by a vacuum cold-weld process such that the first cold-weld ring forms a hermetical seal between the cathode element and the annular insulating spacer and the second cold-weld ring forms a hermetical seal between the annular spacer and the diamond window element whereby a vacuum encapsulated chamber is formed within the capsule.

Rao, Triveni; Walsh, John; Gangone, Elizabeth

2014-12-30T23:59:59.000Z

262

Structure and superconductivity of isotope-enriched boron-doped diamond  

SciTech Connect (OSTI)

Superconducting boron-doped diamond samples were synthesized with isotopes of {sup 10}B, {sup 11}B, {sup 13}C and {sup 12}C. We claim the presence of a carbon isotope effect on the superconducting transition temperature, which supports the 'diamond-carbon'-related nature of superconductivity and the importance of the electron-phonon interaction as the mechanism of superconductivity in diamond. Isotope substitution permits us to relate almost all bands in the Raman spectra of heavily boron-doped diamond to the vibrations of carbon atoms. The 500 cm{sup 01} Raman band shifts with either carbon or boron isotope substitution and may be associated with vibrations of paired or clustered boron. The absence of a superconducting transition (down to 1.6 K) in diamonds synthesized in the Co-C-B system at 1900 K correlates with the small boron concentration deduced from lattice parameters.

Thompson, Joe D [Los Alamos National Laboratory; Ekimov, E A [INSTIT OF HIGH PRESSURE; Sidorov, V A [INSTIT OF HIGH PRESSURE; Zoteev, A [MOSCOW SU; Lebed, Y [INST FOR NUCI RES; Stishov, S M [INST FOR HIGH PRESSURE

2008-01-01T23:59:59.000Z

263

Enhancement of the nucleation of smooth and dense nanocrystalline diamond films by using molybdenum seed layers  

SciTech Connect (OSTI)

A method for the nucleation enhancement of nanocrystalline diamond (NCD) films on silicon substrates at low temperature is discussed. A sputter deposition of a Mo seed layer with thickness 50 nm on Si substrates was applied followed by an ultrasonic seeding step with nanosized detonation diamond powders. Hot-filament chemical vapor deposition (HF-CVD) was used to nucleate and grow NCD films on substrates heated up at 550 deg. C. The nucleation of diamond and the early stages of NCD film formation were investigated at different methane percentages in methane/hydrogen gas mixtures by atomic force microscopy, micro-Raman spectroscopy, scanning electron microscopy, and grazing incidence x-ray analyses in order to gain specific insight in the nucleation process of NCD films. The nucleation kinetics of diamond on the Mo-coated Si substrates was found to be up to ten times higher than on blank Si substrates. The enhancement of the nucleation of diamond on thin Mo interlayers results from two effects, namely, (a) the nanometer rough Mo surface shows an improved embedding of ultrasonically introduced nanosized diamond seeds that act as starting points for the diamond nucleation during HF-CVD and (b) the rapid carbonization of the Mo surface causes the formation of Mo{sub 2}C onto which diamond easily nucleates. The diamond nucleation density progressively increases at increasing methane percentages and is about 5x10{sup 10} cm{sup -2} at 4.0% methane. The improved nucleation kinetics of diamond on Mo interlayers facilitates the rapid formation of NCD films possessing a very low surface roughness down to {approx}6 nm, and allows a submicron thickness control.

Buijnsters, J. G. [Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, Kasteelpark Arenberg 44, B-3001 Leuven (Belgium); Institute for Molecules and Materials, Radboud University Nijmegen, Heijendaalseweg 135, 6525 AJ Nijmegen (Netherlands); Vazquez, L. [Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Cantoblanco, C/Sor Juana Ines de la Cruz 3, 28049 Madrid (Spain); Dreumel, G. W. G. van; Meulen, J. J. ter; Enckevort, W. J. P. van [Institute for Molecules and Materials, Radboud University Nijmegen, Heijendaalseweg 135, 6525 AJ Nijmegen (Netherlands); Celis, J. P. [Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, Kasteelpark Arenberg 44, B-3001 Leuven (Belgium)

2010-11-15T23:59:59.000Z

264

PDC (polycrystalline diamond compact) bit research at Sandia National Laboratories  

SciTech Connect (OSTI)

From the beginning of the geothermal development program, Sandia has performed and supported research into polycrystalline diamond compact (PDC) bits. These bits are attractive because they are intrinsically efficient in their cutting action (shearing, rather than crushing) and they have no moving parts (eliminating the problems of high-temperature lubricants, bearings, and seals.) This report is a summary description of the analytical and experimental work done by Sandia and our contractors. It describes analysis and laboratory tests of individual cutters and complete bits, as well as full-scale field tests of prototype and commercial bits. The report includes a bibliography of documents giving more detailed information on these topics. 26 refs.

Finger, J.T.; Glowka, D.A.

1989-06-01T23:59:59.000Z

265

Nanoscale fluorescence lifetime imaging with a single diamond NV center  

E-Print Network [OSTI]

Solid-state quantum emitters, such as artificially engineered quantum dots or naturally occurring defects in solids, are being investigated for applications ranging from quantum information science and optoelectronics to biomedical imaging. Recently, these same systems have also been studied from the perspective of nanoscale metrology. In this letter we study the near-field optical properties of a diamond nanocrystal hosting a single nitrogen vacancy center. We find that the nitrogen vacancy center is a sensitive probe of the surrounding electromagnetic mode structure. We exploit this sensitivity to demonstrate nanoscale fluorescence lifetime imaging microscopy (FLIM) with a single nitrogen vacancy center by imaging the local density of states of an optical antenna.

Ryan Beams; Dallas Smith; Timothy W. Johnson; Sang-Hyun Oh; Lukas Novotny; Nick Vamivakas

2013-03-05T23:59:59.000Z

266

The reflection of very cold neutrons from diamond powder nanoparticles  

E-Print Network [OSTI]

We study possibility of efficient reflection of very cold neutrons (VCN) from powders of nanoparticles. In particular, we measured the scattering of VCN at a powder of diamond nanoparticles as a function of powder sample thickness, neutron velocity and scattering angle. We observed extremely intense scattering of VCN even off thin powder samples. This agrees qualitatively with the model of independent nanoparticles at rest. We show that this intense scattering would allow us to use nanoparticle powders very efficiently as the very first reflectors for neutrons with energies within a complete VCN range up to $10^{-4}$ eV.

V. V. Nesvizhevsky; E. V. Lychagin; A. Yu. Muzychka; A. V. Strelkov; G. Pignol; K. V. Protasov

2008-05-17T23:59:59.000Z

267

Refractory two-dimensional hole gas on hydrogenated diamond surface  

SciTech Connect (OSTI)

Use of two-dimensional hole gas (2DHG), induced on a hydrogenated diamond surface, is a solution to overcoming one of demerits of diamond, i.e., deep energy levels of impurities. This 2DHG is affected by its environment and accordingly needs a passivation film to get a stable device operation especially at high temperature. In response to this requirement, we achieved the high-reliability passivation forming an Al{sub 2}O{sub 3} film on the diamond surface using an atomic-layer-deposition (ALD) method with an H{sub 2}O oxidant at 450 Degree-Sign C. The 2DHG thus protected survived air annealing at 550 Degree-Sign C for an hour, establishing a stable high-temperature operation of 2DHG devices in air. In part, this achievement is based on high stability of C-H bonds up to 870 Degree-Sign C in vacuum and above 450 Degree-Sign C in an H{sub 2}O-containing environment as in the ALD. Chemically, this stability is supported by the fact that both the thermal decomposition of C-H bonds and reaction between C-H bonds and H{sub 2}O are endothermic processes. It makes a stark contrast to the instability of Si-H bonds, which decompose even at room temperature being exposed to atomic hydrogen. In this respect, the diamond 2DHG devices are also promising as power devices expectedly being free from many instability phenomena, such as hot carrier effect and negative-bias temperature instability, associated with Si devices. As to adsorbate, which is the other prerequisite for 2DHG, it desorbed in vacuum below 250 Degree-Sign C, and accordingly some new adsorbates should have adsorbed during the ALD at 450 Degree-Sign C. As a clue to this question, we certainly confirmed that some adsorbates, other than those at room temperature, adsorbed in air above 100 Degree-Sign C and remained at least up to 290 Degree-Sign C. The identification of these adsorbates is open for further investigation.

Hiraiwa, Atsushi [Institute for Nanoscience and Nanotechnology, Waseda University, 513 Waseda-tsurumaki, Shinjuku, Tokyo 162-0041 (Japan); Daicho, Akira; Kurihara, Shinichiro; Yokoyama, Yuki; Kawarada, Hiroshi [Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo 169-8555 (Japan)

2012-12-15T23:59:59.000Z

268

Black Diamond, Washington: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:form ViewBlack Diamond Power Co Jump to:

269

Long coherence time of spin qubits in $^{12}$C enriched polycrystalline CVD diamond  

E-Print Network [OSTI]

Single defects in diamond and especially negatively charged nitrogen vacancy (NV) centers are very promising quantum systems with wide applications in physics and biology. It was shown that their coherence properties can be strongly improved by growing ultrapure diamond with low concentration of parasitic spins associated with nitrogen electron spins and nuclear spins related to $^{13}$C carbon isotope. Here we report a high quality $^{12}$C-enriched polycrystalline CVD diamond material with properties comparable with single crystals. We find single NVs in the grains of this material, which show extremely long electron spin coherence time $T_2 > 2\\,ms$.

K. D. Jahnke; B. Naydenov; T. Teraji; S. Koizumi; T. Umeda; J. Isoya; F. Jelezko

2012-06-19T23:59:59.000Z

270

Increasing the creation yield of shallow single defects in diamond by surface plasma treatment  

SciTech Connect (OSTI)

Single Nitrogen-Vacancy (NV) centers in diamond close to the crystal surface are very promising magnetic field sensors with very high sensitivity. Here, we report the enhanced creation of very shallow (less than 3 nm below the diamond surface) NV centers by using fluorine and oxygen plasma treatment. We observe a four fold increase—from 0.11% to about 0.45% in the production yield when the sample surface is terminated with fluorine or oxygen atoms. This effect is explained by the stabilization of the NV's negative charge state which is influenced by the various defects present on the diamond surface.

Osterkamp, Christian; Scharpf, Jochen; Naydenov, Boris; Jelezko, Fedor [Institut für Quantenoptik, Ulm University, Albert Einstein Allee 11, Ulm 89081 (Germany)] [Institut für Quantenoptik, Ulm University, Albert Einstein Allee 11, Ulm 89081 (Germany); Pezzagna, Sebastien; Meijer, Jan [Institut für Experimentelle Physik II, Abteilung Nukleare Festkörperphysik, Universität Leipzig, Linnestraße 5, Leipzig 04103 (Germany)] [Institut für Experimentelle Physik II, Abteilung Nukleare Festkörperphysik, Universität Leipzig, Linnestraße 5, Leipzig 04103 (Germany); Diemant, Thomas; Jürgen Behm, Rolf [Institut für Oberflächenchemie und Katalyse, Ulm University, Albert-Einstein-Allee 47, Ulm 89081 (Germany)] [Institut für Oberflächenchemie und Katalyse, Ulm University, Albert-Einstein-Allee 47, Ulm 89081 (Germany)

2013-11-04T23:59:59.000Z

271

HFCVD of diamond at low substrate and low filament temperatures  

SciTech Connect (OSTI)

It has been discovered that the addition of a small amount of oxygen to the CH{sub 4} and H{sub 2} feed gas permits HFCVD of diamond at significantly lower filament and substrate temperatures. The effective O/C ratio here is much lower than that used in most studies of the oxygen effect. Careful control of the O/C and C/H ratios were found to be crucial to success. The effects of substrate and filament temperatures on growth rate and film quality were studied. Optimum conditions were found that gave reasonable growth rates ( {approximately}0.5 {mu}m/h ) with high film quality at filament temperatures below 1750{degrees}C and substrate temperatures below 600C. As a result, low temperature deposition has been realized. Power consumption can be reduced 50%, and the filament lifetime is extended indefinitely.

Tolt, Z.L.; Heatherly, L.; Clausing, R.E.; Shaw, R.W. [Oak Ridge National Lab., TN (United States); Feigerle, C.S. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

1995-12-31T23:59:59.000Z

272

The Discrete Geometry of a Small Causal Diamond  

E-Print Network [OSTI]

We study the discrete causal set geometry of a small causal diamond in a curved spacetime using the average abundance of k-element chains or total orders in the underlying causal set C. We begin by obtaining the first order curvature corrections to the flat spacetime expression for the abundance using Riemann normal coordinates. For fixed spacetime dimension this allows us to find a new expression for the discrete scalar curvature of C as well as the time-time component of its Ricci tensor in terms of the abundances of k-chains. We also find a new dimension estimator for C which replaces the flat spacetime Myrheim-Meyer estimator in generic curved spacetimes.

Mriganko Roy; Debdeep Sinha; Sumati Surya

2012-12-04T23:59:59.000Z

273

Study of narrowband single photon emitters in polycrystalline diamond films  

SciTech Connect (OSTI)

Quantum information processing and integrated nanophotonics require robust generation of single photon emitters on demand. In this work, we demonstrate that diamond films grown on a silicon substrate by microwave plasma chemical vapor deposition can host bright, narrowband single photon emitters in the visible—near infra-red spectral range. The emitters possess fast lifetime (?several ns), absolute photostability, and exhibit full polarization at excitation and emission. Pulsed and continuous laser excitations confirm their quantum behaviour at room temperature, while low temperature spectroscopy is performed to investigate inhomogeneous broadening. Our results advance the knowledge of solid state single photon sources and open pathways for their practical implementation in quantum communication and quantum information processing.

Sandstrom, Russell G.; Shimoni, Olga; Martin, Aiden A.; Aharonovich, Igor, E-mail: igor.aharonovich@uts.edu.au [School of Physics and Advanced Materials, University of Technology, Sydney, P.O. Box 123, Broadway, New South Wales 2007 (Australia)

2014-11-03T23:59:59.000Z

274

Evaluation of traffic operations at diamond interchanges using advanced actuated control  

E-Print Network [OSTI]

This thesis documents an operational analysis of ographics. advanced actuated traffic control at signalized diamond interchanges. The study attempts to determine the benefits a "flexible'' phasing strategy provides to the interchange. Flexible...

Koonce, Peter John Vincent

1998-01-01T23:59:59.000Z

275

Reactive ion etching: Optimized diamond membrane fabrication for transmission electron microscopy  

E-Print Network [OSTI]

Commonly used preparation method for thin diamond membranes by focused ion beam (FIB) techniques results in surface damage. Here, the authors introduce an alternative method based on reactive ion etching (RIE). To compare ...

Li, Luozhou

276

Examination of the Material Removal Rate in Lapping Polycrystalline Diamond Compacts  

E-Print Network [OSTI]

This study examines the lapping machining process used during the manufacturing of polycrystalline diamond compacts (PDCs). More specifically, it is aimed at improving the productivity of the process by developing a better understanding...

Sowers, Jason Michael

2012-10-19T23:59:59.000Z

277

Development and analysis of a flexible signal phasing strategy for diamond interchange control  

E-Print Network [OSTI]

There are many signal timing strategies for diamond interchanges. Due to the different geometric and traffic conditions, however, none of the available strategies is always optimal. The two most widely used strategies, three-phase, and four...

Krueger, Gregory David

1995-01-01T23:59:59.000Z

278

Core-Shell Diamond as a Support for Solid-Phase Extraction and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a Support for Solid-Phase Extraction and High-Performance Liquid Chromatography. Core-Shell Diamond as a Support for Solid-Phase Extraction and High-Performance Liquid...

279

The effects of diamond injector angles on flow structures at various Mach numbers  

E-Print Network [OSTI]

THE EFFECTS OF DIAMOND INJECTOR ANGLES ON FLOW STRUCTURES AT VARIOUS MACH NUMBERS A Thesis by JUSTIN WALTER MCLELLAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 2005 Major Subject: Aerospace Engineering THE EFFECTS OF DIAMOND INJECTOR ANGLES ON FLOW STRUCTURES AT VARIOUS MACH NUMBERS A Thesis by JUSTIN WALTER...

McLellan, Justin Walter

2006-10-30T23:59:59.000Z

280

Optical properties of inhomogeneous metallic hydrogen plasmas  

E-Print Network [OSTI]

We investigate the optical properties of hydrogen as it undergoes a transition from the insulating molecular to the metallic atomic phase, when heated by a pulsed laser at megabar pressures in a diamond anvil cell. Most current experiments attempt to observe this transition by detecting a change in the optical reflectance and/or transmittance. Theoretical models for this change are based on the dielectric function calculated for bulk, homogeneous slabs of material. Experimentally, one expects a hydrogen plasma density that varies on a length scale not substantially smaller than the wave length of the probing light. We show that taking this inhomogeneity into account can lead to significant corrections in the reflectance and transmittance. We present a technique to calculate the optical properties of systems with a smoothly varying density of charge carriers, determine the optical response for metallic hydrogen in the diamond anvil cell experiment and contrast this with the standard results. Analyzing recent e...

Broeck, N Van den; Tempere, J; Silvera, I F

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Equation of state of rhenium and application for ultra high pressure calibration  

SciTech Connect (OSTI)

The isothermal equation of state of rhenium has been measured by powder X-ray diffraction experiments up to 144?GPa at room temperature in a diamond anvil cell. A helium pressure transmitting medium was used to minimize the non-hydrostatic stress on the sample. The fit of pressure-volume data yields a bulk modulus K{sub 0}?=?352.6?GPa and a pressure derivative of the bulk modulus K?{sub 0}=4.56. This equation of state differs significantly from a recent determination [Dubrovinsky et al., Nat. Commun. 3, 1163 (2012)], giving here a lower pressure at a given volume. The possibility of using rhenium gasket X-ray diffraction signal, with the present equation of state, to evaluate multi-Mbar pressures in the chamber of diamond anvil cells is discussed.

Anzellini, Simone; Dewaele, Agnès; Occelli, Florent; Loubeyre, Paul [CEA, DAM, DIF, F-91297 Arpajon (France); Mezouar, Mohamed [European Synchrotron Radiation Facility, BP220, 38043 Grenoble Cedex (France)

2014-01-28T23:59:59.000Z

282

Development of Single Crystal Chemical Vapor Deposition Diamonds for Detector Applications  

SciTech Connect (OSTI)

With the LHC upgrades in 2013, and further LHC upgrades scheduled in 2018, most LHC experiments are planning for detector upgrades which require more radiation hard technologies than presently available. At present all LHC experiments now have some form of diamond detector. As a result Chemical Vapor Deposition (CVD) diamond has now been used extensively in beam conditions monitors as the innermost detectors in the highest radiation areas of all LHC experiments. Moreover CVD diamond is now being discussed as an alternative sensor material for tracking very close to the interaction region of the HL-LHC where the most extreme radiation conditions will exist. Our work addressed the further development of the new material, single-crystal Chemical Vapor Deposition diamond, towards reliable industrial production of large pieces and new geometries needed for detector applications. Our accomplishments include: • Developed a two U.S.companies to produce electronic grade diamond, • Worked with companies and acquired large area diamond pieces, • Performed radiation hardness tests using various proton energies: 70 MeV (Cyric, Japan), 800 MeV (Los Alamos), and 24 GeV (CERN).

Kagan, Harris; Kass, Richard; Gan, K.K.

2014-01-23T23:59:59.000Z

283

hal-00761492,version1-5Dec2012 Author manuscript, published in "Diamond and Related Materials 17 (2008) 1324" DOI : 10.1016/j.diamond.2008.01.090  

E-Print Network [OSTI]

the n-type phosphorus-doped polycrystalline diamond films PN04 (grain size: 1m), PN11 (grain size: 3m-00761492,version1-5Dec2012 Author manuscript, published in "Diamond and Related Materials 17 (2008) 1324" DOI : 10.1016/j.diamond.2008.01.090 #12;1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

Paris-Sud XI, Université de

2008-01-01T23:59:59.000Z

284

X-Ray Diffraction Study of Elemental Erbium to 65 GPa  

SciTech Connect (OSTI)

We have investigated phase transitions in elemental erbium in a diamond anvil cell up to 65 GPa using x-ray powder diffraction methods. We present preliminary evidence of a series of phase transitions that appear to follow the expected hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc sequence. In particular, we believe that we have evidence for the predicted dhcp {yields} distorted fcc transition between 43 GPa and 65 GPa.

Pravica, M.G.; Lipinska-Kalita, K.; Quine, Z.; Romano, E.; Nicol, M.F. (UNLV)

2006-02-02T23:59:59.000Z

285

Diamond detector for high rate monitors of fast neutrons beams  

SciTech Connect (OSTI)

A fast neutron detection system suitable for high rate measurements is presented. The detector is based on a commercial high purity single crystal diamond (SDD) coupled to a fast digital data acquisition system. The detector was tested at the ISIS pulsed spallation neutron source. The SDD event signal was digitized at 1 GHz to reconstruct the deposited energy (pulse amplitude) and neutron arrival time; the event time of flight (ToF) was obtained relative to the recorded proton beam signal t{sub 0}. Fast acquisition is needed since the peak count rate is very high ({approx}800 kHz) due to the pulsed structure of the neutron beam. Measurements at ISIS indicate that three characteristics regions exist in the biparametric spectrum: i) background gamma events of low pulse amplitudes; ii) low pulse amplitude neutron events in the energy range E{sub dep}= 1.5-7 MeV ascribed to neutron elastic scattering on {sup 12}C; iii) large pulse amplitude neutron events with E{sub n} < 7 MeV ascribed to {sup 12}C(n,{alpha}){sup 9}Be and 12C(n,n')3{alpha}.

Giacomelli, L.; Rebai, M.; Cippo, E. Perelli; Tardocchi, M.; Fazzi, A.; Andreani, C.; Pietropaolo, A.; Frost, C. D.; Rhodes, N.; Schooneveld, E.; Gorini, G. [Dipartimento di Fisica, Universita degli Studi di Milano-Bicocca, and Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, Milano (Italy); Energy Department, Politecnico di Milano, Milano (Italy); Dipartimento di Fisica, Centro NAST, Universita degli Studi di Roma Tor Vergata, Roma (Italy); STFC, ISIS facility, Rutherford Appleton Laboratory, Chilton Didcot Oxfordshire (United Kingdom); Dipartimento di Fisica, Universita degli Studi di Milano-Bicocca, and Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, Milano (Italy)

2012-06-19T23:59:59.000Z

286

Diamond tool wear vs cutting distance on electroless nickel mirrors  

SciTech Connect (OSTI)

Wear data are presented for diamond tools cutting electroless nickel (eNi) for cut lengths up to 70,000 ft (13 miles). Two tools having different infrared absorption characteristics were used to cut an eNi preparation that had yielded minimum values for surface roughness and tool wear rate in a previous study. The data include Talystep measurement of the rms amplitude of the feed-marks versus cumulative cutting distance, representative examples of shape changes for the feed-mark profiles, SEM and optical micrographs of the tool rake and flank face wear zones, and measurements of the cutting edge profile and edge recession distance by a tool-nose replication technique. Feed-mark roughness values were found to increase from 5 to 90 A rms over the duration of the test, with an associated edge recession of about 1000 A and the development of a periodic tool edge grooving indicative of burnishing of the part surface. The ir absorption data successfully predicted the order of the two tools in terms of wear rate and fracture toughness.

Syn, C.K.; Taylor, J.S.; Donaldson, R.R.

1986-10-14T23:59:59.000Z

287

High-power TSP bits. [Thermally Stable Polycrystalline diamond  

SciTech Connect (OSTI)

This paper reviews a three-year R D project to develop advanced thermally stable polycrystalline diamond (TSP) bits that can operate at power levels 5 to 10 times greater than those typically delivered by rotary rigs. These bits are designed to operate on advanced drilling motors that drill 3 to 6 times faster than rotary rigs. TSP bit design parameters that were varied during these tests include cutter size, shape, density, and orientation. Drilling tests conducted in limestone, sandstone, marble, and granite blocks showed that these optimized bits drilled many of these rocks at 500 to 1,000 ft/hr (150 to 300 m/h), compared to 50 to 100 ft/hr (15 to 30 m/h) for roller bits. These tests demonstrated that TSP bits are capable of operating at the high speeds and high torques delivered by advanced drilling motors now being developed. These advanced bits and motors are designed for use in slim-hole and horizontal drilling applications.

Cohen, J.H.; Maurer, W.C. (Maurer Engineering Inc., Houston, TX (United States)); Westcott, P.A. (Gas Research Inst., Chicago, IL (United States))

1994-03-01T23:59:59.000Z

288

Kinetically Inhibited Order in a Diamond-Lattice Antiferromagnet  

SciTech Connect (OSTI)

Frustrated magnetic systems exhibit highly degenerate ground states and strong fluctuations, often leading to new physics. An intriguing example of current interest is the antiferromagnet on a diamond lattice, realized physically in the A-site spinel materials. This is a prototypical system in three dimensions where frustration arises from competing interactions rather than purely geometric constraints, and theory suggests the possibility of novel order at low temperature. Here we present a comprehensive single crystal neutron scattering study CoAl2O4, a highly frustrated A-site spinel. We observe strong diffuse scattering that peaks at wavevectors associated with Neel ordering. Below the temperature T*=6.5K, there is a dramatic change in elastic scattering lineshape accompanied by the emergence of well-defined spin-wave excitations. T* had previously been associated with the onset of glassy behavior. Our new results suggest instead that in fact T* signifies a first-order phase transition, but with true long-range order inhibited by the kinetic freezing of domain walls. This scenario might be expected to occur widely in frustrated systems containing first-order phase transitions and is a natural explanation for existing reports of anomalous glassy behavior in other materials.

MacDougall, Gregory J [ORNL; Gout, Delphine J [ORNL; Zarestky, Jerel L [ORNL; Ehlers, Georg [ORNL; Podlesnyak, Andrey A [ORNL; McGuire, Michael A [ORNL; Mandrus, David [ORNL; Nagler, Stephen E [ORNL

2011-01-01T23:59:59.000Z

289

Ferromagnetic ordering of Cr and Fe doped p-type diamond: An ab initio study  

SciTech Connect (OSTI)

Ferromagnetic ordering of transition metal dopants in semiconductors holds the prospect of combining the capabilities of semiconductors and magnetic systems in single hybrid devices for spintronic applications. Various semiconductors have so far been considered for spintronic applications, but low Curie temperatures have hindered room temperature applications. We report ab initio DFT calculations on the stability and magnetic properties of Fe and Cr impurities in diamond, and show that their ground state magnetic ordering and stabilization energies depend strongly on the charge state and type of co-doping. We predict that divacancy Cr{sup +2} and substitutional Fe{sup +1} order ferromagnetically in p-type diamond, with magnetic stabilization energies (and magnetic moment per impurity ion) of 16.9 meV (2.5 ?{sub B}) and 33.3 meV (1.0 ?{sub B}), respectively. These magnetic stabilization energies are much larger than what has been achieved in other semiconductors at comparable impurity concentrations, including the archetypal dilute magnetic semiconductor GaAs:Mn. In addition, substitutional Fe{sup +1} exhibits a strong half-metallic character, with the Fermi level crossing bands in only the spin down channel. These results, combined with diamond’s extreme properties, demonstrate that Cr or Fe dopedp-type diamond may successfully be considered in the search for room temperature spintronic materials.

Benecha, E. M. [Department of Physics, University of South Africa, P.O Box 392, UNISA 0003, Pretoria (South Africa); Lombardi, E. B. [College of Graduate Studies, University of South Africa, P.O Box 392, UNISA 0003, Pretoria (South Africa)

2014-02-21T23:59:59.000Z

290

Electron microscopic evidence for a tribologically induced phase transformation as the origin of wear in diamond  

SciTech Connect (OSTI)

Tribological testing of a coarse-grained diamond layer, deposited by plasma-enhanced chemical vapor deposition, was performed on a ring-on-ring tribometer with a diamond counterpart. The origin of the wear of diamond and of the low friction coefficient of 0.15 was studied by analyzing the microstructure of worn and unworn regions by transmission and scanning electron microscopy. In the worn regions, the formation of an amorphous carbon layer with a thickness below 100?nm is observed. Electron energy loss spectroscopy of the C-K ionization edge reveals the transition from sp{sup 3}-hybridized C-atoms in crystalline diamond to a high fraction of sp{sup 2}-hybridized C-atoms in the tribo-induced amorphous C-layer within a transition region of less than 5?nm thickness. The mechanically induced phase transformation from diamond to the amorphous phase is found to be highly anisotropic which is clearly seen at a grain boundary, where the thickness of the amorphous layer above the two differently oriented grains abruptly changes.

Zhang, Xinyi; Schneider, Reinhard; Müller, Erich; Gerthsen, Dagmar [Laboratory for Electron Microscopy, Karlsruhe Institute of Technology (KIT), Engesserstr. 7, D-76131 Karlsruhe (Germany); Mee, Manuel; Meier, Sven [Fraunhofer Institute for Mechanics of Materials IWM, Wöhlerstr. 11, D-79108 Freiburg (Germany); Gumbsch, Peter [Fraunhofer Institute for Mechanics of Materials IWM, Wöhlerstr. 11, D-79108 Freiburg (Germany); Institute for Applied Materials IAM, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, D-76131 Karlsruhe (Germany)

2014-02-14T23:59:59.000Z

291

Creation of deep blue light emitting nitrogen-vacancy center in nanosized diamond  

SciTech Connect (OSTI)

This paper reports on the formation of complex defect centers related to the N3 center in nanosized diamond by employing plasma immersion and focused ion beam implantation methods. He{sup +} ion implantation into nanosized diamond “layer” was performed with the aim of creating carbon atom vacancies in the diamond structure, followed by the introduction of molecular N{sub 2}{sup +} ion and heat treatment in vacuum at 750?°C to initiate vacancy diffusion. To decrease the sp{sup 2} carbon content of nanosized diamond formed during the implantation processes, a further heat treatment at 450?°C in flowing air atmosphere was used. The modification of the bonding properties after each step of defect creation was monitored by Raman scattering measurements. The fluorescence measurements of implanted and annealed nanosized diamond showed the appearance of an intensive and narrow emission band with fine structures at 2.98?eV, 2.83?eV, and 2.71?eV photon energies.

Himics, L., E-mail: himics.laszlo@wigner.mta.hu; Tóth, S.; Veres, M.; Koós, M. [Institute for Solid State Physics and Optics, Wigner Research Center for Physics, Hungarian Academy of Sciences, H-1525 Budapest, P.O. Box 49 (Hungary); Balogh, Z. [Uzhhorod National University, 88000 Uzhhorod (Ukraine)

2014-03-03T23:59:59.000Z

292

Rome 2007 2nd International Industrial Diamond Conference Proceedings, Rome April 19-Development of a Procedure for Fatigue Crack Growth in PCD  

E-Print Network [OSTI]

and the crack morphology. #12;1. Background Polycrystalline diamond cutters are known to fail during drilling polycrystalline diamond material inevitably leads to premature degradation of the cutter's ability to drill rockRome 2007 2nd International Industrial Diamond Conference Proceedings, Rome April 19- 20, 2007

293

FAR-INFRARED SPECTROSCOPIC STUDY OF DIAMOND FILMS A. J. Gatesman*, R. H. Giles*, G. C. Phillips*, J. Waldman*, L. P. Bourget** and R. Post**  

E-Print Network [OSTI]

**Applied Science and Technology, Inc., Woburn, MA 01801 High quality polycrystalline diamond films grownFAR-INFRARED SPECTROSCOPIC STUDY OF DIAMOND FILMS A. J. Gatesman*, R. H. Giles*, G. C. Phillips*, J in this frequency regime. INTRODUCTION Recent interest in the growth, production and application of diamond thin

Massachusetts at Lowell, University of

294

singapore_composites5.doc submitted to World Scientific 22/10/2003 -14:46 1/1 DIAMOND-FIBRE REINFORCED PLASTIC COMPOSITES  

E-Print Network [OSTI]

thin films of polycrystalline diamond on different substrates has enabled scientists and engineerssingapore_composites5.doc submitted to World Scientific 22/10/2003 - 14:46 1/1 DIAMOND of Bristol, Bristol BS8 1TR, UK Email: David.Smith@bris.ac.uk Diamond fibre reinforced poly

Bristol, University of

295

Validating optical emission spectroscopy as a diagnostic of microwave activated CH4/Ar/H2 plasmas used for diamond chemical vapor deposition  

E-Print Network [OSTI]

chemical vapor deposition of polycrystalline diamond. Several tracer species are monitored in order to gain used for diamond chemical vapor deposition Jie Ma,1 Michael N. R. Ashfold,1,a and Yuri A. Mankelevich2 spectroscopic methods used to diagnose microwave MW plasmas used for diamond chemical vapor deposition CVD . Zhu

Bristol, University of

296

Effects of thickness and cycle parameters on fretting wear behavior of CVD diamond coatings on steel substrates  

E-Print Network [OSTI]

of low friction, high hardness, high wear resistance, as well as promising corrosion resistance. © 2010 of thermal expansion between diamond and steel may induce high stress within the deposited diamond films c a School of Materials Science and Engineering, Central South University, Changsha, 410083, PR

Bristol, University of

297

Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon wafers  

E-Print Network [OSTI]

microscopy, profilometer and wafer bow measurements. Plasma-activated direct bonding of DOI wafers to thermalPlasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon (CMP) on the diamond surface makes a poor bonding to silicon wafers with thermal oxide. Our results

Akin, Tayfun

298

Phlogopite and Quartz Lamellae in Diamond-bearing Diopside from Marbles of the Kokchetav Massif Kazakhstan: Exsolution or Replacement Reaction  

SciTech Connect (OSTI)

Exsolution lamellae of pyroxene in garnet (grt), coesite in titanite and omphacite from UHPM terranes are widely accepted as products of decompression. However, interpretation of oriented lamellae of phyllosilicates, framework silicates and oxides as a product of decompression of pyroxene is very often under debate. Results are presented here of FIB-TEM, FEG-EMP and synchrotron-assisted infrared (IR) spectroscopy studies of phlogopite (Phlog) and phlogopite + quartz (Qtz) lamellae in diamond-bearing clinopyroxene (Cpx) from ultra-high pressure (UHP) marble. These techniques allowed collection of three-dimensional information from the grain boundaries of both the single (phlogopite), two-phase lamellae (phlogopite + quartz), and fluid inclusions inside of diamond included in K-rich Cpx and understanding their relationships and mechanisms of formation. The Cpx grains contain in their cores lamellae-I, which are represented by topotactically oriented extremely thin lamellae of phlogopite (that generally are two units cell wide but locally can be seen to be somewhat broader) and microdiamond. The core composition is: (Ca{sub 0.94}K{sub 0.04}Na{sub 0.02})(Al{sub 0.06}Fe{sub 0.08}Mg{sub 0.88})(Si{sub 1.98}Al{sub 0.02})O{sub 6.00}. Fluid inclusions rich in K and Si are recognized in the core of the Cpx, having no visible connections to the lamellae-I. Lamellar-II inclusions consist of micron-size single laths of phlogopite and lens-like quartz or slightly elongated phlogopite + quartz intergrowths; all are situated in the rim zone of the Cpx. The composition of the rim is (Ca{sub 0.95}Fe{sub 0.03}Na{sub 0.02})(Al{sub 0.05}Fe{sub 0.05}Mg{sub 0.90})Si{sub 2}O{sub 6}, and the rim contains more Ca, Mg than the core, with no K there. Such chemical tests support our microstructural observations and conclusion that the phlogopite lamellae-I are exsolved from the K-rich Cpx-precursor during decompression. It is assumed that Cpx-precursor was also enriched in H{sub 2}O, because diamond included in the core of this Cpx contains fluid inclusions. The synchrotron IR spectra of such diamond record the presence of OH{sup -} stretching and H{sub 2}O bending motion regions. Lamellar-II inclusions are interpreted as forming partly because of modification of the lamellae-i in the presence of fluid enriched in K, Fe and Si during deformation of the host diopside; the latter is probably related to the shallower stage of exhumation of the UHP marble. This study emphasizes that in each case to understand the mechanism of lamellar inclusion formation more detailed studies are needed combining both compositional, structural and three-dimensional textural features of lamellar inclusions and their host.

L Dobrzhinetskaya; R Wirth; D Rhede; Z Liu; H Green

2011-12-31T23:59:59.000Z

299

Ultraviolet photosensitivity of sulfur-doped micro- and nano-crystalline diamond  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The room-temperature photosensitivity of sulfur-doped micro- (MCD), submicro- (SMCD) and nano- (NCD) crystalline diamond films synthesized by hot-filament chemical vapor deposition was studied. The structure and composition of these diamond materials were characterized by Raman spectroscopy, scanning electron microscopy and X-ray diffraction. The UV sensitivity and response time were studied for the three types of diamond materials using a steady state broad UV excitation source and two pulsed UV laser radiations. It was found that they have high sensitivity in the UV region, as high as 109 sec-1mV-1 range, linear response in a broad spectral range below 320 nm, photocurrents around ~10-5 A, and short response time better than 100 ns, which is independent of fluency intensity. A phenomenological model was applied to help understand the role of defects and dopant concentration on the materials’ photosensitivity.

Mendoza, Frank; Makarov, Vladimir; Hidalgo, Arturo; Weiner, Brad; Morell, Gerardo

2011-06-06T23:59:59.000Z

300

Efficient readout of a single spin state in diamond via spin-to-charge conversion  

E-Print Network [OSTI]

Efficient readout of individual electronic spins associated with atom-like impurities in the solid state is essential for applications in quantum information processing and quantum metrology. We demonstrate a new method for efficient spin readout of nitrogen-vacancy (NV) centers in diamond. The method is based on conversion of the electronic spin state of the NV to a charge state distribution, followed by single-shot readout of the charge state. Conversion is achieved through a spin-dependent photoionization process in diamond at room temperature. Using NVs in nanofabricated diamond beams, we demonstrate that the resulting spin readout noise is within a factor of three of the spin projection noise level. Applications of this technique for nanoscale magnetic sensing are discussed.

B. J. Shields; Q. P. Unterreithmeier; N. P. de Leon; H. Park; M. D. Lukin

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Nano-fabricated solid immersion lenses registered to single emitters in diamond  

E-Print Network [OSTI]

We describe a technique for fabricating micro- and nano-structures incorporating fluorescent defects in diamond with a positional accuracy in the hundreds of nanometers. Using confocal fluorescence microscopy and focused ion beam (FIB) etching we first locate a suitable defect with respect to registration marks on the diamond surface and then etch a structure using these coordinates. We demonstrate the technique here by etching an 8 micron diameter hemisphere positioned such that a single negatively charged nitrogen-vacancy defect lies at its origin. This type of structure increases the photon collection efficiency by removing refraction and aberration losses at the diamond-air interface. We make a direct comparison of the fluorescence photon count rate before and after fabrication and observe an 8-fold increase due to the presence of the hemisphere.

L. Marseglia; J. P. Hadden; A. C. Stanley-Clarke; J. P. Harrison; B. Patton; Y. -L. D. Ho; B. Naydenov; F. Jelezko; J. Meijer; P. R. Dolan; J. M. Smith; J. G. Rarity; J. L. O'Brien

2011-02-22T23:59:59.000Z

302

The Development of Open Water-lubricated Polycrystalline Diamond (PCD) Thrust Bearings for Use in Marine Hydrokinetic (MHK) Energy Machines  

SciTech Connect (OSTI)

Polycrstalline diamond (PCD) bearings were designed, fabricated and tested for marine-hydro-kinetic (MHK) application. Bearing efficiency and life were evaluated using the US Synthetic bearing test facility. Three iterations of design, build and test were conducted to arrive at the best bearing design. In addition life testing that simulated the starting and stopping and the loading of real MHK applications were performed. Results showed polycrystalline diamond bearings are well suited for MHK applications and that diamond bearing technology is TRL4 ready. Based on life tests results bearing life is estimated to be at least 11.5 years. A calculation method for evaluating the performance of diamond bearings of round geometry was also investigated and developed. Finally, as part of this effort test bearings were supplied free of charge to the University of Alaska for further evaluation. The University of Alaska test program will subject the diamond bearings to sediment laden lubricating fluid.

Cooley, Craig, H.; Khonsari, Michael,, M; Lingwall, Brent

2012-11-28T23:59:59.000Z

303

Design of flexible ultrahigh-Q microcavities in diamond-based photonic crystal slabs  

E-Print Network [OSTI]

We design extremely flexible ultrahigh-Q diamond-based double-heterostructure photonic crystal slab cavities by modifying the refractive index of the diamond. The refractive index changes needed for ultrahigh-Q cavities with $Q ~ 10^7$, are well within what can be achieved ($\\Delta n \\sim 0.02$). The cavity modes have relatively small volumes $Vdesign is flexible because the range of parameters, cavity length and the index changes, that enables an ultrahigh-Q is quite broad. Furthermore as the index modification is post-processed, an efficient technique to generate cavities around defect centres is achievable, improving prospects for defect-tolerant quantum architectures.

Snjezana Tomljenovic-Hanic; Andrew D. Greentree; C. Martijn de Sterke; Steven Prawer

2008-12-10T23:59:59.000Z

304

Photo-stimulated low electron temperature high current diamond film field emission cathode  

DOE Patents [OSTI]

An electron source includes a back contact surface having a means for attaching a power source to the back contact surface. The electron source also includes a layer comprising platinum in direct contact with the back contact surface, a composite layer of single-walled carbon nanotubes embedded in platinum in direct contact with the layer comprising platinum. The electron source also includes a nanocrystalline diamond layer in direct contact with the composite layer. The nanocrystalline diamond layer is doped with boron. A portion of the back contact surface is removed to reveal the underlying platinum. The electron source is contained in an evacuable container.

Shurter; Roger Philips (Los Alamos, NM), Devlin; David James (Santa Fe, NM), Moody; Nathan Andrew (Los Alamos, NM), Taccetti; Jose Martin (Santa Fe, NM), Russell; Steven John (Los Alamos, NM)

2012-07-24T23:59:59.000Z

305

4e-condensation in a fully frustrated Josephson junction diamond chain  

SciTech Connect (OSTI)

Fully frustrated one-dimensional diamond Josephson chains have been shown [B. Doucot and J. Vidal, Phys. Rev. Lett. 88, 227005 (2002)] to possess a remarkable property: The superfluid phase occurs through the condensation of pairs of Cooper pairs. By means of Monte Carlo simulations we analyze quantitatively the insulator to 4e-superfluid transition. We determine the location of the critical point and discuss the behavior of the phase-phase correlators. For comparison, we also present the case of a diamond chain at zero and 1/3 frustration where the standard 2e-condensation is observed.

Rizzi, Matteo [NEST CNR-INFM and Scuola Normale Superiore, Piazza dei Cavalieri 7, 56126 Pisa (Italy); Cataudella, Vittorio [COHERENTIA CNR-INFM and Dipartimento di Fisica, Universit Federico II, 80126 Napoli (Italy); Fazio, Rosario [NEST CNR-INFM and Scuola Normale Superiore, Piazza dei Cavalieri 7, 56126 Pisa (Italy); International School for Advanced Studies (SISSA), via Beirut 2-4, I-34014, Trieste (Italy)

2006-03-01T23:59:59.000Z

306

Isotope engineering of silicon and diamond for quantum computing and sensing applications  

E-Print Network [OSTI]

Some of the stable isotopes of silicon and carbon have zero nuclear spin, whereas many of the other elements that constitute semiconductors consist entirely of stable isotopes that have nuclear spins. Silicon and diamond crystals composed of nuclear-spin-free stable isotopes (Si-28, Si-30, or C-12) are considered to be ideal host matrixes to place spin quantum bits (qubits) for quntum computing and sensing applications because their coherent properties are not disrupted thanks to the absence of host nuclear spins. The present article describes the state-of-the-art and future perspective of silicon and diamond isotope engineering for development of quantum information processing devices.

Kohei M. Itoh; Hideyuki Watanabe

2014-10-15T23:59:59.000Z

307

Coherent interference effects in a nano-assembled diamond NV center  

E-Print Network [OSTI]

-Packard Laboratories, 1501 Page Mill Rd, Palo Alto, CA 94304, USA Presently with Hewlett-Packard Laboratories, 1501 Page Mill Rd, Palo Alto, CA 94304, USA paul.barclay@hp.com Abstract: Diamond nanocrystals containing NV, P. Olivero, A. D. Greentree, S. Prawer, F. Jelezko, and P. Hemmer, "Coherent Population Trapping

Painter, Oskar

308

Advances in PSII Deposited Diamond-Like Carbon Coatings for Use as a Corrosion Barrier  

E-Print Network [OSTI]

Advances in PSII Deposited Diamond-Like Carbon Coatings for Use as a Corrosion Barrier R. S to improve corrosion resistance, however, the necessary organometallics needed to implant these materials to produce an adherent, hard, wear and, corrosion-resistant coating plays a vital role. These applications

309

AIR FLOW DISTRIBUTION IN A HIGH-RISE RESIDENTIAL Helmut E. Feustel and Richard C. Diamond  

E-Print Network [OSTI]

AIR FLOW DISTRIBUTION IN A HIGH-RISE RESIDENTIAL BUILDING Helmut E. Feustel and Richard C. Diamond Lawrence Berkeley National Laboratory, Berkeley, USA ABSTRACT The provision of ventilation air for high-rise multifamily housing has plagued retrofit practitioners and researchers alike. We have been studying the air

Diamond, Richard

310

Porous Boron-Doped Diamond/Carbon Nanotube Electrodes H. Zanin,*,  

E-Print Network [OSTI]

with BDD (large potential window, chemical inertness, low background levels), but also they have application in electronics and sensors, such B-doped diamond (BDD) films are increasingly being used and a very low background current, in addition to chemical and physical stability.7 Planar BDD electrodes

Bristol, University of

311

Slide diamond burnishing of tool steels with adhesive coatings and diffusion layers  

E-Print Network [OSTI]

Slide diamond burnishing of tool steels with adhesive coatings and diffusion layers W. Brostow*1 with a scratch tester. A combination of both approaches, slide burnishing with hard chrome coating and/or slide in manufacturing tools and structural elements in automotive and aerospace industries. Keywords: Tool steels, Slide

North Texas, University of

312

Automated Testing of HVAC Systems for Commissioning Tim Salsbury and Rick Diamond  

E-Print Network [OSTI]

Automated Testing of HVAC Systems for Commissioning Tim Salsbury and Rick Diamond Lawrence Berkeley of the commissioning of HVAC systems. The approach is based on software that generates a sequence of test signals for new and retrofit projects. Introduction The performance of many HVAC systems is limited more by poor

Diamond, Richard

313

High quality factor nanocrystalline diamond micromechanical resonators limited by thermoelastic damping  

SciTech Connect (OSTI)

We demonstrate high quality factor thin-film nanocrystalline diamond micromechanical resonators with quality factors limited by thermoelastic damping. Cantilevers, single-anchored and double-anchored double-ended tuning forks, were fabricated from 2.5??m thick in-situ boron doped nanocrystalline diamond films deposited using hot filament chemical vapor deposition. Thermal conductivity measured by time-domain thermoreflectance resulted in 24?±?3?W m{sup ?1} K{sup ?1} for heat transport through the thickness of the diamond film. The resonant frequencies of the fabricated resonators were 46?kHz–8?MHz and showed a maximum measured Q???86?000 at f{sub n}?=?46.849?kHz. The measured Q-factors are shown to be in good agreement with the limit imposed by thermoelastic dissipation calculated using the measured thermal conductivity. The mechanical properties extracted from resonant frequency measurements indicate a Young's elastic modulus of ?788?GPa, close to that of microcrystalline diamond.

Najar, Hadi, E-mail: hnajar@ucdavis.edu [Department of Electrical and Computer Engineering, University of California, Davis, California 95616 (United States); Chan, Mei-Lin [Department of Mechanical and Aerospace Engineering, University of California, Davis, California 95616 (United States); Yang, Hsueh-An; Lin, Liwei [Department of Mechanical Engineering, University of California, Berkeley, California 94720 (United States); Cahill, David G. [Department of Materials Science and Engineering, Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801 (United States); Horsley, David A. [Department of Electrical and Computer Engineering, University of California, Davis, California 95616 (United States); Department of Mechanical and Aerospace Engineering, University of California, Davis, California 95616 (United States)

2014-04-14T23:59:59.000Z

314

Diamond Amplified Photocathode Ilan Ben-Zvi, Andrew Burrill, Xiangyun Chang, Peter D.  

E-Print Network [OSTI]

the diamond sample This heat load can be handled by LN cooling #12;Experimental Program I · Measure SEY and temporal broadening · Determine High Current Performance (Heat load, electron temperature) · Establish temperature is calculated to be ~ 0.35eV. Electron temperature for transport mode #12;Transit time: Drift

315

Method to grow pure nanocrystalline diamond films at low temperatures and high deposition rates  

DOE Patents [OSTI]

A method of depositing nanocrystalline diamond film on a substrate at a rate of not less than about 0.2 microns/hour at a substrate temperature less than about 500.degree. C. The method includes seeding the substrate surface with nanocrystalline diamond powder to an areal density of not less than about 10.sup.10sites/cm.sup.2, and contacting the seeded substrate surface with a gas of about 99% by volume of an inert gas other than helium and about 1% by volume of methane or hydrogen and one or more of acetylene, fullerene and anthracene in the presence of a microwave induced plasma while maintaining the substrate temperature less than about 500.degree. C. to deposit nanocrystalline diamond on the seeded substrate surface at a rate not less than about 0.2 microns/hour. Coatings of nanocrystalline diamond with average particle diameters of less than about 20 nanometers can be deposited with thermal budgets of 500.degree. C.-4 hours or less onto a variety of substrates such as MEMS devices.

Carlisle, John A. (Plainfield, IL); Gruen, Dieter M. (Downers Grove, IL); Auciello, Orlando (Bolingbrook, IL); Xiao, Xingcheng (Woodridge, IL)

2009-07-07T23:59:59.000Z

316

Standards Panel: 1. Stephen Diamond, General Manager, Industry Standards Office and Global Standards Officer, EMC  

E-Print Network [OSTI]

Standards Officer, EMC Corporation, Office of the CTO Steve Diamond has 30 years of management, marketing was President of the IEEE Computer Society. Steve is General Manager of the Industry Standards Office at EMC Corporation, and Global Standards Officer in the Office of the CTO. Before EMC, he was responsible for cloud

317

PHYSICAL REVIEW B 83, 193410 (2011) Denser than diamond: Ab initio search for superdense carbon allotropes  

E-Print Network [OSTI]

. At ambient conditions, the hP3 phase is a semiconductor with the GW band gap of 3.0 eV, tI12 is an insulator semimetallic (graphite, an excel- lent lubricant) and even superconducting (doped diamond and fullerenes).1 two-dimensional (2D) mate- rial is graphene. Such extremely high density, with uniquely high valence

Oganov, Artem R.

318

Thermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee  

E-Print Network [OSTI]

are concerned with the exchange of thermal energy across an interface between two materials. This topic-nonmetal interface, a two-temperature model predicts a thermal resistance of Rep = 1/ gL in series with the phononThermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee Department

Cahill, David G.

319

Graphene-on-Diamond Devices with Increased Current-Carrying Capacity: Carbon sp2  

E-Print Network [OSTI]

Graphene-on-Diamond Devices with Increased Current-Carrying Capacity: Carbon sp2 -on-sp3 Technology Laboratory, Illinois 60439, United States *S Supporting Information ABSTRACT: Graphene demonstrated potential for practical applications owing to its excellent electronic and thermal properties. Typical graphene field

320

Diamonds as timing detectors for MIP: The HADES proton-beam monitor and start detectors  

E-Print Network [OSTI]

This paper gives an overview of a recent development of measuring time of flight of minimum-ionizing particles (MIP) with mono-crystalline diamond detectors. The application in the HADES spectrometer as well as test results obtained with proton beams are discussed.

J. Pietraszko; L. Fabbietti; W. Koenig

2009-11-02T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Diamonds as timing detectors for MIP: The HADES proton-beam monitor and start detectors  

E-Print Network [OSTI]

This paper gives an overview of a recent development of measuring time of flight of minimum-ionizing particles (MIP) with mono-crystalline diamond detectors. The application in the HADES spectrometer as well as test results obtained with proton beams are discussed.

,

2009-01-01T23:59:59.000Z

322

Ultrananocrystalline diamond thin films for MEMS and moving mechanical assembly devices.  

SciTech Connect (OSTI)

MEMS devices are currently fabricated primarily in silicon because of the available surface machining technology. A major problem with the Si-based MEMS technology is that Si has poor mechanical and tribological properties [J.J. Sniegowski, in: B. Bushan (Ed.), Tribology Issues and Opportunities in MEMS, Kluwer Academic Publisher, The Netherlands, 1998, p. 325; A.P. Lee, A.P. Pisano, M.G. Lim, Mater. Res. Soc. Symp. Proc. 276 (1992) 67.], and practical MEMS devices are currently limited primarily to applications involving only bending and flexural motion, such as cantilever accelerometers and vibration sensors. However, because of the poor flexural strength and fracture toughness of Si, and the tendency of Si to adhere to hydrophilic surfaces, even these simple devices have limited dynamic range. Future MEMS applications that involve significant rolling or sliding contact will require the use of new materials with significantly improved mechanical and tribological properties, and the ability to perform well in harsh environments, Diamond is a superhard material of high mechanical strength, exceptional chemical inertness, and outstanding thermal stability. The brittle fracture strength is 23 times that of Si, and the projected wear life of diamond MEMS moving mechanical assemblies (MEMS MMAs) is 10 000 times greater than that of Si MMAs. However, as the hardest known material, diamond is notoriously difficult to fabricate. Conventional CVD thin film deposition methods offer an approach to the fabrication of ultra-small diamond structures, but the films have large grain size, high internal stress, poor intergranular adhesion, and very rough surfaces, and are consequently ill-suited for MEMS MMA applications. Diamond-like films are also being investigated for application to MEMS devices. However, they involve mainly physical vapor deposition methods that are not suitable for good conformal deposition on high aspect ratio features, and generally they do not exhibit the outstanding mechanical properties of diamond. We demonstrate here the application of a novel microwave plasma technique using a unique C{sub 60}/Ar or CH{sub 4}/Ar chemistry that produces phase-pure ultrananocrystalline diamond (UNCD) coatings with morphological and mechanical properties that are ideally suited for MEMS applications in general, and MMA use in particular. We have developed lithographic techniques for the fabrication of UNCD-MEMS components, including cantilevers and multi-level devices, acting as precursors to microbearings and gears, making UNCD a promising material for the development of high performance MEMS devices.

Krauss, A. R.; Gruen, D. M.; Jayatissa, A.; Sumant, A.; Tucek, J.; Auciello, O.; Mancini, D.; Moldovan, N.; Erdemir, A.; Ersoy, D.; Gardos, M. N.; Busmann, H. G.; Meyer, E. M.; Ding, M. Q.; Univ. of Illinois at Chicago; Raytheon Electronic Systems Comp.; Fraunhofer Inst. for Applied Materials Science; Univ. of Bremen; Beijing Inst. of Electronics

2001-11-01T23:59:59.000Z

323

Design of diamond turned holograms by the nonlinear conjugate gradients method Colin Dankwart, Claas Falldorf and Jurgen Jahns  

E-Print Network [OSTI]

Design of diamond turned holograms by the nonlinear conjugate gradients method Colin Dankwart investigate a different optimization approach, the nonlinear conjugate gradients (NCG) method. The NGC method design algorithm, based on the generalized projections method (GPM) [?] was established, taking

Jahns, Jürgen

324

Systematic studies of the nucleation and growth of ultrananocrystalline diamond films on silicon substrates coated with a tungsten layer  

SciTech Connect (OSTI)

We report on effects of a tungsten layer deposited on silicon surface on the effectiveness for diamond nanoparticles to be seeded for the deposition of ultrananocrystalline diamond (UNCD). Rough tungsten surface and electrostatic forces between nanodiamond seeds and the tungsten surface layer help to improve the adhesion of nanodiamond seeds on the tungsten surface. The seeding density on tungsten coated silicon thus increases. Tungsten carbide is formed by reactions of the tungsten layer with carbon containing plasma species. It provides favorable (001) crystal planes for the nucleation of (111) crystal planes by Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) in argon diluted methane plasma and further improves the density of diamond seeds/nuclei. UNCD films grown at different gas pressures on tungsten coated silicon which is pre-seeded by nanodiamond along with heteroepitaxially nucleated diamond nuclei were characterized by Raman scattering, field emission-scanning electron microscopy, and high resolution-transmission electron microscopy.

Chu, Yueh-Chieh; Jiang, Gerald [Institute of Microelectronics, No.1, University Road, Tainan 701, Taiwan (China); Tu, Chia-Hao [Institute of Nanotechnology and Microsystems Engineering, No.1, University Road, Tainan 701, Taiwan (China); Department of Materials Science and Engineering, National Cheng Kung University, No.1, University Road, Tainan 701, Taiwan (China); Chang Chi [Institute of Nanotechnology and Microsystems Engineering, No.1, University Road, Tainan 701, Taiwan (China); Liu, Chuan-pu; Ting, Jyh-Ming [Department of Materials Science and Engineering, National Cheng Kung University, No.1, University Road, Tainan 701, Taiwan (China); Lee, Hsin-Li [Industrial Technology Research Institute - South, Tainan 701, Taiwan (China); Tzeng, Yonhua [Institute of Microelectronics, No.1, University Road, Tainan 701, Taiwan (China); Advanced Optoelectronics Technology Center, No.1, University Road, Tainan 701, Taiwan (China); Auciello, Orlando [Argonne National Laboratory, Materials Science Division, 9700 S. Cass Avenue, Argonne, Illinois 60439 (United States)

2012-06-15T23:59:59.000Z

325

Tests in Time: A Review of Natural Experiments of History, edited by Jared Diamond and James A. Robinson  

E-Print Network [OSTI]

on the island of Hispaniola (discussed in more detailCaribbean island of Hispaniola. Diamond wants to understandhave played a key role in Hispaniola’s history it is unclear

Currie, Thomas E

2010-01-01T23:59:59.000Z

326

The contact heat conductance at diamond-OFHC copper interface with GaIn eutectic as a heat transfer medium  

SciTech Connect (OSTI)

Results of an experimental study of the contact heat conductance across a single diamond crystal interface with OFHC copper (Cu) are reported. Gallium-indium (GaIn) eutectic was used as an interstitial material. Contact conductance data are important in the design and the prediction of the performance of x-ray diamond monochromators under high-heat-load conditions. Two sets of experiments were carried out. In one, the copper surface in contact with diamond was polished and then electroless plated with 1 {mu}m of nickel, while in the other, the copper contact surface was left as machined. Measured average interface heat conductances are 44.7 {plus_minus}8 W/cm{sup 2}{minus}K for nonplated copper and 23.0 {plus_minus}3 W/cm{sup 2}{minus}K for nickel-plated copper. For reference, the thermal contact conductances at a copper-copper interface (without diamond) were also measured, and the results are reported. A typical diamond monochromator, 0.2 mm thick, will absorb about 44 W under a standard undulator beam at the Advanced Photon Source. The measured conductance for nickel-plated copper suggests that the temperature drop across the interface of diamond and nickel-plated copper, with a 20 mm{sup 2} contact area, will be about 10{degree}C. Therefore temperature rises are rather modest, and the accuracy of the measured contact conductances presented here are sufficient for design purposes.

Assoufid, L.; Khounsary, A.M.

1996-01-01T23:59:59.000Z

327

Hybrid optics for the visible produced by bulk casting of sol-gel glass using diamond-turned molds  

SciTech Connect (OSTI)

Recent combinations of diffractive and refractive functions in the same optical component allow designers additional opportunities to make systems more compact and enhance performance. This paper describes a research program for fabricating hybrid refractive/diffractive components from diamond-turned molds using the bulk casting of sol-gel silica glass. The authors use the complementary dispersive nature of refractive and diffractive optics to render two-color correction in a single hybrid optical element. Since diamond turning has matured as a deterministic manufacturing technology, techniques previously suitable only in the infrared are now being applied to components used at visible wavelengths. Thus, the marriage of diamond turning and sol-gel processes offers a cost-effective method for producing highly customized and specialized optical components in high quality silica glass. With the sol-gel casting method of replication, diamond-turned mold costs can be shared over many pieces. Diamond turning takes advantage of all of the available degrees of freedom in a single hybrid optical element: aspheric surface to eliminate spherical aberration, kinoform surface for control of primary chromatic aberration, and the flexibility to place the kinoform on non-planar surfaces for maximum design flexibility. The authors discuss the critical issues involved in designing the hybrid element, single point diamond-turning the mold, and fabrication in glass using the sol-gel process.

Bernacki, B.E.; Miller, A.C.; Maxey, L.C.; Cunningham, J.P. [Oak Ridge National Lab., TN (United States); Moreshead, W.V.; Nogues, J.L.R. [Geltech Inc., Alachua, FL (United States)

1995-07-01T23:59:59.000Z

328

Diamond X-ray photodiode for white and monochromatic SR beams  

SciTech Connect (OSTI)

High-purity, single-crystal CVD diamond plates are screened for quality and instrumented into a sensor assembly for quantitative characterization of flux and position sensitivity. Initial investigations have yielded encouraging results and have led to further development. Several limiting complications are observed and discussed, as well as mitigations thereof. For example, diamond quality requirements for X-ray diodes include low nitrogen impurity and crystallographic defectivity. Thin electrode windows and electronic readout performance are ultimately also critical to device performance. Promising features observed so far from prototype devices include calculable responsivity, flux linearity, position sensitivity and timing performance. Recent results from testing in high-flux and high-speed applications are described.

Keister, J.W.; Heroux, A.; Smedley, J.; Muller, E. M.; Bohon, J.

2011-09-01T23:59:59.000Z

329

Heteroepitaxial ZnO films on diamond: Optoelectronic properties and the role of interface polarity  

SciTech Connect (OSTI)

We demonstrate the growth of heteroepitaxial ZnO films on (110) diamond substrates by molecular beam epitaxy and report on a major advance in structural quality, as confirmed by XRD and high-resolution TEM measurements. The growth direction is found to be along the polar c-axis with Zn-polarity, deduced from annular bright-field scanning transmission electron microscopy imaging. This is important information, as simulations of the electronic band structure reveal the ZnO polarity to dominate the electronic structure of the interface: the formation of a two-dimensional electron gas on the ZnO side or a two-dimensional hole gas on the diamond side are predicted for Zn- and O-polarity, respectively. In addition, photoluminescence and absorption studies exhibit good optical properties and reveal stimulated emission for optical excitation above a threshold of 30?kW/cm{sup 2}.

Schuster, Fabian, E-mail: Fabian.Schuster@wsi.tum.de; Hetzl, Martin; Garrido, Jose A.; Stutzmann, Martin [Walter Schottky Institut, Technische Universität München, Am Coulombwall 4, 85748 Garching (Germany); Magén, Cesar [Laboratorio de Microscopías Avanzadas (LMA) - Instituto de Nanociencia de Aragon (INA) and Departamento de Física de la Materia Condensada, Universidad de Zaragoza, 50018 Zaragoza (Spain); Fundación ARAID, 50018 Zaragoza (Spain); Arbiol, Jordi [Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, 08193 Bellaterra, CAT (Spain); Institució Catalana de Recerca i Estudis Avançats (ICREA), 08010 Barcelona, CAT (Spain)

2014-06-07T23:59:59.000Z

330

Electroless vs electrodeposited Ni-P alloys for diamond turning applications  

SciTech Connect (OSTI)

Electrolytes nickel deposits with greater than 10% phosphorous have been widely used for diamond turning applications such as fabrications of large optics and other high precision parts. Although the coatings have worked well, they are not without their drawbacks. Porosity and nodule formation have been problems as well as the difficulty of obtaining deposits greater than about 75 {mu}m. In recent years much effort has been directed at the investigating electrodeposition of Ni-P alloys in an attempt to avoid these problems. The purpose of this paper is to compare diamond turning results for both electroless and electrodeposited alloys and speculate about the future uses of electrodeposited Ni-P for precision finishing applications. 16 refs., 7 figs.

Dini, J.W.

1991-07-01T23:59:59.000Z

331

Performance of a beam-multiplexing diamond crystal monochromator at the Linac Coherent Light Source  

SciTech Connect (OSTI)

A double-crystal diamond monochromator was recently implemented at the Linac Coherent Light Source. It enables splitting pulses generated by the free electron laser in the hard x-ray regime and thus allows the simultaneous operations of two instruments. Both monochromator crystals are High-Pressure High-Temperature grown type-IIa diamond crystal plates with the (111) orientation. The first crystal has a thickness of ?100 ?m to allow high reflectivity within the Bragg bandwidth and good transmission for the other wavelengths for downstream use. The second crystal is about 300 ?m thick and makes the exit beam of the monochromator parallel to the incoming beam with an offset of 600 mm. Here we present details on the monochromator design and its performance.

Zhu, Diling, E-mail: dlzhu@slac.stanford.edu; Feng, Yiping; Lemke, Henrik T.; Fritz, David M.; Chollet, Matthieu; Glownia, J. M.; Alonso-Mori, Roberto; Sikorski, Marcin; Song, Sanghoon; Williams, Garth J.; Messerschmidt, Marc; Boutet, Sébastien; Robert, Aymeric [Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Stoupin, Stanislav; Shvyd'ko, Yuri V. [Advanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439 (United States); Terentyev, Sergey A.; Blank, Vladimir D. [Technological Institute of Superhard and Novel Carbon Materials, Tsentralnaya str. 7a, Troitsk, Moscow 142190 (Russian Federation); Driel, Tim B. van [Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Center for Molecular Movies, Department of Physics, Technical University of Denmark, DK-2800 Lyngby (Denmark)

2014-06-15T23:59:59.000Z

332

Spectrally dependent photovoltages in Schottky photodiode based on (100) B-doped diamond  

SciTech Connect (OSTI)

Spectrally and spatially resolved photovoltages were measured by Kelvin probe force microscopy (KPFM) on a Schottky photo-diode made of a 4?nm thin tungsten-carbide (WC) layer on a 500?nm oxygen-terminated boron-doped diamond epitaxial layer (O-BDD) that was grown on a Ib (100) diamond substrate. The diode was grounded by the sideways ohmic contact (Ti/WC), and the semitransparent Schottky contact was let unconnected. The electrical potentials across the device were measured in dark (only 650?nm LED of KPFM being on), under broad-band white light (halogen lamp), UV (365?nm diode), and deep ultraviolet (deuterium lamp) illumination. Illumination induced shift of the electrical potential remains within 210?mV. We propose that the photovoltage actually corresponds to a shift of Fermi level inside the BDD channel and thereby explains orders of magnitude changes in photocurrent.

?ermák, Jan, E-mail: cermakj@fzu.cz; Rezek, Bohuslav [Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnická 10, 16200 Prague 6 (Czech Republic); Koide, Yasuo [Sensor Materials Center, National Institute for Material Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Takeuchi, Daisuke [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba 305-8568 (Japan)

2014-02-07T23:59:59.000Z

333

Fluorinated diamond thin films for tribological applications. Final report, April-October 1989  

SciTech Connect (OSTI)

Diamond (100) substrates have been fluorinated with both atomic and molecular fluorine under ultrahigh vacuum conditions using molecular beams. X-ray photoelectron spectra of the resulting samples indicate that atomic fluorine, F, reacts with an initial accommodation coefficient of 0.25 (+ or - 0.1) at 298 K; a saturation coverage of about three quarters of a monolayer is obtained. The carbon fluoride adlayer is thermally stable to 700 K, but slowly desorbs at temperatures above this. In contrast, molecular fluorine, F2, reacts quite slowly; a saturation coverage of less than one fifth of a monolayer after several hundred monolayers exposure to F2 at temperatures from 300 K to 700 K is achieved. In addition, diamond substrates saturated with fluorine atoms showed no loss of fluorine after exposure to beams of H2 and O2 at temperatures between 300 K and 700 K.

Freedman, A.; Stinespring, C.

1990-01-04T23:59:59.000Z

334

Diamond pixel detector for beam profile monitoring in COMET experiment at J-PARC  

E-Print Network [OSTI]

We present the design and initial prototype results of a pixellized proton beam profile monitor for the COMET experiment at J-PARC. The goal of COMET is to look for charged lepton flavor violation by direct muon to electron conversion at a sensitivity of $0^{-19}$. An 8 GeV proton beam pulsed at 100 ns with $10^{10}$ protons/s will be used to create muons through pion production and decay. In the final experiment, the proton flux will be raised to $10^{14}$ protons/sec to increase the sensitivity. These requirements of harsh radiation tolerance and fast readout make diamond a good choice for constructing a beam profile monitor in COMET. We present first results of the characterization of single crystal diamond (scCVD) sourced from a new company, 2a systems Singapore. Our measurements indicate excellent charge collection efficiency and high carrier mobility down to cryogenic temperatures.

M. Cerv; P. Sarin; H. Pernegger; P. Vageesvaran; E. Griesmayer

2014-11-15T23:59:59.000Z

335

US Synthetic Corp (TRL 4 Component)- The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines  

Broader source: Energy.gov [DOE]

US Synthetic Corp (TRL 4 Component) - The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines

336

Effect of Decreasing of Cobalt Content in Properties for Diamond/Cemented Carbide Tools  

SciTech Connect (OSTI)

Powder metallurgy plays a role in manufacturing such as automotive and cutting tool applications. Diamond/cemented carbide tools are also made from this technique. Diamond particle and other matrix materials were employed in this study. The purpose is to investigate the physical and mechanical properties of different Cobalt (Co) content samples by using Taguchi's method. The materials used in the experiments were mixed by using a ball-mill machine. The mixed powders were pressed by conventional method. Then the green samples were sintered in a vacuum furnace. After reaching 500 deg. C, the samples were sintered with Argon (Ar) gas. The sintered samples were investigated density by immersion method, porosity by water saturation method, and hardness by Vicker hardness tester. It was found that with 59.5% Co content, plain diamond type, sintering temperature of 950 deg. C, sintering time of 40 minutes, and pressure of 625 MPa, density, porosity, and hardness got the best result in this study. From the Taguchi's analysis, the significant factors effected the performance were composition, sintering temperature, and sintering time.

Waratta, A.; Hamdi, M. [Department of Design and Manufacture, Faculty of Engineering, University of Malaya (Malaysia); Ariga, T. [Department of Materials Science, School of Engineering, Tokai University (Japan)

2010-03-11T23:59:59.000Z

337

Signal transduction and conversion with color centers in diamond and piezo-elements  

E-Print Network [OSTI]

The ability to measure weak signals such as pressure, force, electric field, and temperature with nanoscale devices and high spatial resolution offers a wide range of applications in fundamental and applied sciences. Here we present a proposal for a hybrid device composed of thin film layers of diamond with color centers implanted and piezo-active elements for the transduction and measurement of a wide variety of physical signals. The magnetic response of a piezomagnetic layer to an external stress or a stress induced by the change of electric field and temperature is shown to affect significantly the spin properties of nitrogen-vacancy centers in diamond. Under ambient conditions, realistic environmental noise and material imperfections, our detailed numerical studies show that this hybrid device can achieve significant improvements in sensitivity over the pure diamond based approach in combination with nanometer scale spatial resolution. Beyond its applications in quantum sensing the proposed hybrid architecture offers novel possibilities for engineering strong coherent couplings between nanomechanical oscillator and solid state spin qubits.

Jianming Cai; Fedor Jelezko; Martin B. Plenio

2014-04-25T23:59:59.000Z

338

Local and bulk 13C hyperpolarization in NV-centered diamonds at variable fields and orientations  

E-Print Network [OSTI]

Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches targeting diamonds with nitrogen-vacancy (NV) centers could alleviate this need, but hitherto proposed strategies lack generality as they demand stringent conditions on the strength and/or alignment of the magnetic field. We report here an approach for achieving efficient electron->13C spin alignment transfers, compatible with a broad range of magnetic field strengths and field orientations with respect to the diamond crystal. This versatility results from combining coherent microwave- and incoherent laser-induced transitions between selected energy states of the coupled electron-nuclear spin manifold. 13C-detected Nuclear Magnetic Resonance (NMR) experiments demonstrate that this hyperpolarization can be transferred via first-shell or via distant 13Cs, throughout the nuclear bulk ensemble. This method opens new perspectives for applications of diamond NV centers in NMR, and in quantum information processing.

Gonzalo A. Alvarez; Christian O. Bretschneider; Ran Fischer; Paz London; Hisao Kanda; Shinobu Onoda; Junichi Isoya; David Gershoni; Lucio Frydman

2014-12-30T23:59:59.000Z

339

Compressive response of a sandwich plate containing a cracked diamond-celled lattice  

E-Print Network [OSTI]

and diesel particulate filters for automobiles, medical prosthetic implants, absorbers for solar energy is the lightest topology for combined load bearing and active cooling application. There has been significant

Fleck, Norman A.

340

Contact heat conductance at a diamond-OFHC copper interface with GaIn eutectic as a heat transfer medium  

SciTech Connect (OSTI)

The results of an experimental study of the contact heat conductance across a single diamond crystal interface with OFHC copper (Cu) are reported. Gallium-indium (GaIn) eutectic was used as an interstitial material. Contact conductance data are important in the design and the prediction of the performance of x-ray optics under high-heat-load conditions. Two sets of experiments were carried out. In one, the copper surface in contact with diamond was polished and then electroless plated with 1 {mu}m of nickel, while in the other, the copper contact surface was left as machined. The measured average interface heat conductances are 44.7{plus_minus}8 W/cm{sup 2}-K for nonplated copper and 23.0{plus_minus}8 W/cm{sup 2}-K for nickel-plated copper. For reference, the thermal contact conductances at a copper-copper interface (without diamond) were also measured, and the results are reported. A typical diamond monochromator, 0.2 mm thick, will absorb about 44 W under a standard undulator beam at the Advanced Photon Source. The measured conductance for nickel-plated copper suggests that the temperature drop across the interface of diamond and nickel-plated copper, with a 20 mm {sup 2}contact area, will be about 10{degree}C. Therefore temperature rises are rather modest, and the accuracy of the measured contact conductances presented here are sufficient for design purposes. {copyright} {ital 1996 American Institute of Physics.}

Assoufid, L.; Khounsary, A. [Experimental Facilities Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Experimental Facilities Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

1996-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Ab initio investigation of lithium on the diamond C(100) surface K. M. O'Donnell,1,2,* T. L. Martin,2,3 N. A. Fox,3 and D. Cherns3  

E-Print Network [OSTI]

for diamond thermionic converters currently of interest for solar power generation and heat recycling. INTRODUCTION Diamond is a promising photocathode, field emitter, and thermionic emitter due to its chemical of approximately 400 °C, too low for thermionic applications.3 As such, research into diamond thermionics has

Bristol, University of

342

W. N. WANGet al.: Laser Raman Studies of Polycrystalline and A-Diamond Films 255 phys. stat. sol. (a) 154,255 (1996)  

E-Print Network [OSTI]

W. N. WANGet al.: Laser Raman Studies of Polycrystalline and A-Diamond Films 255 phys. stat. sol, Transducer Systems Division, Wotton-under-Edge4)(d) Laser Raman Studies of Polycrystalline and Amorphic Diamond Films W. N. WANG(a), N. A. FOX(a), P. W. MAY(b), M. P. KNAPPER(b), G. MEADEN(c), P. G. PARTRIDGE

Bristol, University of

1996-01-01T23:59:59.000Z

343

CVD POLYCRYSTALLINE DIAMOND HIGH-Q MICROMECHANICAL RESONATORS Jing Wang, James E. Butler*, D. S. Y. Hsu*, and Clark T.-C. Nguyen  

E-Print Network [OSTI]

CVD POLYCRYSTALLINE DIAMOND HIGH-Q MICROMECHANICAL RESONATORS Jing Wang, James E. Butler*, D. S. Y one variant of approach (3), in which CVD polycrystalline diamond material, with an acoustic velocity@engin.umich.edu ABSTRACT Chemical Vapor Deposited (CVD) polycrystalline dia- mond material, with an acoustic velocity

Nguyen, Clark T.-C.

344

Mechanical Spin Control of Nitrogen-Vacancy Centers in Diamond E. R. MacQuarrie, T. A. Gosavi, N. R. Jungwirth, S. A. Bhave, and G. D. Fuchs*  

E-Print Network [OSTI]

Mechanical Spin Control of Nitrogen-Vacancy Centers in Diamond E. R. MacQuarrie, T. A. Gosavi, N. R 2013; published 27 November 2013) We demonstrate direct coupling between phonons and diamond nitrogen-vacancy fundamental interest as a potential mediator of spin-spin interactions [1,2]. Nitrogen-vacancy (NV) center

Afshari, Ehsan

345

Solar-induced chemical vapor deposition of diamond-type carbon films  

DOE Patents [OSTI]

An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

1994-09-13T23:59:59.000Z

346

All-optical high-resolution magnetic resonance using a nitrogen-vacancy spin in diamond  

E-Print Network [OSTI]

We propose an all-optical scheme to prolong the quantum coherence of a negatively charged nitrogen-vacancy (NV) center in diamond. Optical control of the NV spin suppresses energy fluctuations of the $^{3}\\text{A}_{2}$ ground states and forms an energy gap protected subspace. By optical control, the spectral linewidth of magnetic resonance is much narrower and the measurement of the frequencies of magnetic field sources has higher resolution. The optical control also improves the sensitivity of the magnetic field detection and can provide measurement of the directions of signal sources.

Zhen-Yu Wang; Jian-Ming Cai; Alex Retzker; Martin B. Plenio

2014-04-04T23:59:59.000Z

347

Solar-induced chemical vapor deposition of diamond-type carbon films  

DOE Patents [OSTI]

An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

Pitts, J. Roland (Lakewood, CO); Tracy, C. Edwin (Golden, CO); King, David E. (Lakewood, CO); Stanley, James T. (Beaverton, OR)

1994-01-01T23:59:59.000Z

348

First Evidence of Near-Infrared Photonic Bandgap in Polymeric Rod-Connected Diamond Structure  

E-Print Network [OSTI]

We present the simulation, fabrication, and optical characterization of low-index polymeric rod-connected diamond (RCD) structures. Such complex three-dimensional photonic crystal structures are created via direct laser writing by two-photon polymerization. To our knowledge, this is the first measurement at near-infrared wavelengths, showing partial photonic bandgaps. We characterize structures in transmission and reflection using angular resolved Fourier image spectroscopy to visualize the band structure. Comparison of the numerical simulations of such structures with the experimentally measured data show good agreement for both P- and S-polarizations.

Chen, Lifeng; Zheng, Xu; Lin, Jia-De; Oulton, Ruth; Lopez-Garcia, Martin; Ho, Ying-Lung D; Rarity, John G

2015-01-01T23:59:59.000Z

349

Surface finish measurements of diamond-turned electroless-nickel-plated mirrors  

SciTech Connect (OSTI)

Surface roughness data are presented for a matrix of diamond-turned electroless nickel samples having a combination of six phosphorus contents and four heat treatments. Roughness measurements were conducted with commercial optical and stylus profilers (WYKO and Talystep). The results are discussed in terms of the material composition and heat treatment, plus other factors having an observed influence on the surface roughness. For the optimum material properties, full-length (665..mu..m) 20x WYKO scans yielded values of better than 10 A rms after correction for instrument roll-off.

Taylor, J.S.; Syn, C.K.; Saito, T.T.; Donaldson, R.R.

1986-09-01T23:59:59.000Z

350

Surface finish measurements of diamond-turned electroless-nickel-plated mirrors  

SciTech Connect (OSTI)

Surface roughness data are presented for a matrix of diamond-turned electroless-nickel samples having a combination of six phosphorous contents and four heat treatments. Roughness measurements were conducted with commercial optical and stylus profilometers (Wyko and Talystep). The results are discussed in terms of the material composition and heat treatment, plus other factors having an observed influence on the surface roughness. For the optimum material properties, full-length (665 ..mu..m) restored 20X Wyko scans yielded values of better than 10A rms.

Taylor, J.S.; Syn, C.K.; Saito, T.T.; Donaldson, R.R.

1985-08-16T23:59:59.000Z

351

Direct-write milling of diamond by a focused oxygen ion beam  

E-Print Network [OSTI]

Recent advances in focused ion beam technology have enabled high-resolution, direct-write nanofabrication using light ions. Studies with light ions to date have, however, focused on milling of materials where sub-surface ion beam damage does not inhibit device performance. Here we report on direct-write milling of single crystal diamond using a focused beam of oxygen ions. Material quality is assessed by Raman and luminescence analysis, and reveals that the damage layer generated by oxygen ions can be removed by nonintrusive post-processing methods such as localised electron beam induced chemical etching.

Martin, Aiden A; Botman, Aurelien; Toth, Milos; Aharonovich, Igor

2015-01-01T23:59:59.000Z

352

Effect of Temperature and Charged Particle Fluence on the Resistivity of Polycrystalline CVD Diamond Sensors  

E-Print Network [OSTI]

The resistivity of polycrystalline chemical vapor deposition diamond sensors is studied in samples exposed to fluences relevant to the environment of the High Luminosity Large Hadron Collider. We measure the leakage current for a range of bias voltages on samples irradiated with 800 MeV protons up to 1.6\\times 10^{16} p/cm^2. The proton beam at LANSCE, Los Alamos National Laboratory, was applied to irradiate the samples. The devices' resistivity is extracted for temperatures in the -10^\\circC to +20^\\circC range.

Rui Wang; Martin Hoeferkamp; Sally Seidel

2013-10-09T23:59:59.000Z

353

Effect of Temperature and Charged Particle Fluence on the Resistivity of Polycrystalline CVD Diamond Sensors  

E-Print Network [OSTI]

The resistivity of polycrystalline chemical vapor deposition diamond sensors is studied in samples exposed to fluences relevant to the environment of the High Luminosity Large Hadron Collider. We measure the leakage current for a range of bias voltages on samples irradiated with 800 MeV protons up to 1.6\\times 10^{16} p/cm^2. The proton beam at LANSCE, Los Alamos National Laboratory, was applied to irradiate the samples. The devices' resistivity is extracted for temperatures in the -10^\\circC to +20^\\circC range.

Wang, Rui; Seidel, Sally

2013-01-01T23:59:59.000Z

354

Evaluation of TexSIM for modeling traffic behavior at diamond interchanges  

E-Print Network [OSTI]

VITA 81 LIST OF FIGURES Figure Page 1 Typical Diamond Interchange Configurations and Movements 2 Three-Phase Control Strategies 3 TTI Four-Phase Sequence 4 Approach Numbering Scheme for TexSIM Coding 5 Pretimed 1 Interchange Layout and Phasing... Stopped Delay 26 Model Versus Pretimed 2 (7am - 9am) Field Data Stopped Delay 51 53 53 54 54 55 27 Model Versus Field Data Interior Left Turn Stopped Delay 56 28 EfFect of Loop Detector Size on Cycle Length 60 LIST OF TABLES Table 1 Study Sites...

Meadors, Allison Christine Cherry

2012-06-07T23:59:59.000Z

355

Pretreatment process for forming a smooth surface diamond film on a carbon-coated substrate  

DOE Patents [OSTI]

A process is disclosed for the pretreatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate. The process comprises exposing the carbon-coated substrate, in a microwave plasma enhanced chemical vapor deposition system, to a mixture of hydrogen-methane gases, having a methane gas concentration of at least about 4% (as measured by partial pressure), while maintaining the substrate at a pressure of about 10 to about 30 Torr during the pretreatment.

Feng, Zhu (Albany, CA); Brewer, Marilee (Goleta, CA); Brown, Ian (Berkeley, CA); Komvopoulos, Kyriakos (Orinda, CA)

1994-01-01T23:59:59.000Z

356

Pretreatment process for forming a smooth surface diamond film on a carbon-coated substrate  

DOE Patents [OSTI]

A process is disclosed for the pretreatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate. The process comprises exposing the carbon-coated substrate, in a microwave plasma enhanced chemical vapor deposition system, to a mixture of hydrogen-methane gases, having a methane gas concentration of at least about 4% (as measured by partial pressure), while maintaining the substrate at a pressure of about 10 to about 30 Torr during the pretreatment. 6 figures.

Feng, Z.; Brewer, M.; Brown, I.; Komvopoulos, K.

1994-05-03T23:59:59.000Z

357

Radiation-assisted Frenkel-Poole transport in single-crystal diamond  

SciTech Connect (OSTI)

The measurement of the density of occupied states as a function of the applied electric field, performed on single-crystal chemical vapour deposition diamond by x-ray modulated photocurrent technique, is reported. Two regimes of non-linear charge transport were observed: a classical Frenkel-Poole (FP) process at high electric fields (>6800 V/cm), and a radiation-assisted transport mechanism at intermediate electric fields (2000 to 6800 V/cm), consisting of a double-step process in which the direct re-emission into the extended band occurs following multiple photo-induced FP-like hopping transitions.

Girolami, M.; Bellucci, A.; Calvani, P.; Flammini, R.; Trucchi, D. M. [CNR-IMIP, Institute of Inorganic Methodologies and Plasmas, National Research Council, Via Salaria km 29.300, 00015 Monterotondo Stazione, Rome (Italy)] [CNR-IMIP, Institute of Inorganic Methodologies and Plasmas, National Research Council, Via Salaria km 29.300, 00015 Monterotondo Stazione, Rome (Italy)

2013-08-19T23:59:59.000Z

358

An ultra-thin diamond membrane as a transmission particle detector and vacuum window for external microbeams  

SciTech Connect (OSTI)

Several applications of external microbeam techniques demand a very accurate and controlled dose delivery. To satisfy these requirements when post-sample ion detection is not feasible, we constructed a transmission single-ion detector based on an ultra-thin diamond membrane. The negligible intrinsic noise provides an excellent signal-to-noise ratio and enables a hit-detection efficiency of close to 100%, even for energetic protons, while the small thickness of the membrane limits beam spreading. Moreover, because of the superb mechanical stiffness of diamond, this membrane can simultaneously serve as a vacuum window and allow the extraction of an ion microbeam into the atmosphere.

Grilj, V.; Skukan, N.; Jakši?, M. [Division of Experimental Physics, Ru?er Boškovi? Institute, 10000 Zagreb (Croatia)] [Division of Experimental Physics, Ru?er Boškovi? Institute, 10000 Zagreb (Croatia); Pomorski, M. [CEA-LIST, Diamond Sensors Laboratory, Gif-sur-Yvette F-91191 (France)] [CEA-LIST, Diamond Sensors Laboratory, Gif-sur-Yvette F-91191 (France); Kada, W. [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu, Gunma 376-8515 (Japan)] [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu, Gunma 376-8515 (Japan); Iwamoto, N.; Kamiya, T.; Ohshima, T. [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency (JAEA), Takasaki, Gunma 370-1292 (Japan)] [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency (JAEA), Takasaki, Gunma 370-1292 (Japan)

2013-12-09T23:59:59.000Z

359

Circularly polarized microwaves for magnetic resonance study in the GHz range: application to nitrogen-vacancy in diamonds  

E-Print Network [OSTI]

The ability to create time-dependent magnetic fields of controlled polarization is essential for many experiments with magnetic resonance. We describe a microstrip circuit that allows us to generate strong magnetic field at microwave frequencies with arbitrary adjusted polarization. The circuit performance is demonstrated by applying it to an optically detected magnetic resonance and Rabi nutation experiments in nitrogen-vacancy color centers in diamond. Thanks to high efficiency of the proposed microstrip circuit and degree of circular polarization of 85% it is possible to address the specific spin states of a diamond sample using a low power microwave generator.

Mrozek, Mariusz; Rudnicki, Daniel S; Gawlik, Wojciech

2015-01-01T23:59:59.000Z

360

Stokes--anti-Stokes Correlations in Raman Scattering from Diamond Membranes  

E-Print Network [OSTI]

We investigate the arrival statistics of Stokes (S) and anti-Stokes (aS) Raman photons generated in diamond membranes. Strong quantum correlations between the S and aS signals are observed, which implies that the two processes share the same phonon, that is, the phonon excited by the S process is consumed in the aS process. We show that the intensity cross-correlation $g_{\\rm S,aS}^{(2)}(0)$, which describes the simultaneous detection of Stokes and anti-Stokes photons, decreases steadily with laser power as $1/{\\rm P_L}$. Contrary to many other material systems, diamond exhibits a maximum $g_{\\rm S,aS}^{(2)}(0)$ at very low pump powers, implying that the Stokes-induced aS photons outnumber the thermally generated aS photons. On the other hand, the coincidence rate shows a quadratic plus cubic power dependence, which indicates a departure from the Stokes-induced anti-Stokes process.

Kasperczyk, Mark; Neu, Elke; Maletinsky, Patrick; Novotny, Lukas

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

A diamond based neutron spectrometer for diagnostics of deuterium-tritium fusion plasmas  

SciTech Connect (OSTI)

Single crystal Diamond Detectors (SDD) are being increasingly exploited for neutron diagnostics in high power fusion devices, given their significant radiation hardness and high energy resolution capabilities. The geometrical efficiency of SDDs is limited by the size of commercially available crystals, which is often smaller than the dimension of neutron beams along collimated lines of sight in tokamak devices. In this work, we present the design and fabrication of a 14 MeV neutron spectrometer consisting of 12 diamond pixels arranged in a matrix, so to achieve an improved geometrical efficiency. Each pixel is equipped with an independent high voltage supply and read-out electronics optimized to combine high energy resolution and fast signals (<30 ns), which are essential to enable high counting rate (>1 MHz) spectroscopy. The response function of a prototype SDD to 14 MeV neutrons has been measured at the Frascati Neutron Generator by observation of the 8.3 MeV peak from the {sup 12}C(n, ?){sup 9}Be reaction occurring between neutrons and {sup 12}C nuclei in the detector. The measured energy resolution (2.5% FWHM) meets the requirements for neutron spectroscopy applications in deuterium-tritium plasmas.

Cazzaniga, C., E-mail: carlo.cazzaniga@mib.infn.it; Nocente, M.; Gorini, G. [University of Milano Bicocca, Piazza della Scienza 3, Milano (Italy); Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, via Roberto Cozzi 53, Milano (Italy); Rebai, M.; Giacomelli, L. [University of Milano Bicocca, Piazza della Scienza 3, Milano (Italy); Tardocchi, M.; Croci, G.; Grosso, G. [Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, via Roberto Cozzi 53, Milano (Italy); Calvani, P.; Girolami, M.; Trucchi, D. M. [CNR-ISM, Research Area Roma 1, Via Salaria km 29.300, 00015-Monterotondo Scalo (Rm) (Italy); Griesmayer, E. [Atominstitut, Vienna University of Technology, Vienna (Austria); Pillon, M. [Associazione EURATOM-ENEA sulla Fusione ENEA C.R. Frascati, Via E. Fermi, 45, 00044 Frascati (Roma) (Italy)

2014-11-15T23:59:59.000Z

362

Electronic and physico-chemical properties of nanometric boron delta-doped diamond structures  

SciTech Connect (OSTI)

Heavily boron doped diamond epilayers with thicknesses ranging from 40 to less than 2?nm and buried between nominally undoped thicker layers have been grown in two different reactors. Two types of [100]-oriented single crystal diamond substrates were used after being characterized by X-ray white beam topography. The chemical composition and thickness of these so-called delta-doped structures have been studied by secondary ion mass spectrometry, transmission electron microscopy, and spectroscopic ellipsometry. Temperature-dependent Hall effect and four probe resistivity measurements have been performed on mesa-patterned Hall bars. The temperature dependence of the hole sheet carrier density and mobility has been investigated over a broad temperature range (6?K?

Chicot, G., E-mail: gauthier.chicot@neel.cnrs.fr; Fiori, A.; Tran Thi, T. N.; Bousquet, J.; Delahaye, J.; Grenet, T.; Eon, D.; Omnès, F.; Bustarret, E. [Université Grenoble Alpes, Institut NEEL, 38042 Grenoble (France); CNRS, Institut NEEL, 38042 Grenoble (France); Volpe, P. N.; Tranchant, N.; Mer-Calfati, C.; Arnault, J. C. [CEA, LIST, Diamond Sensors Laboratory, 91191 Gif-sur-Yvette (France); Gerbedoen, J. C.; Soltani, A.; De Jaeger, J. C. [IEMN, UMR-CNRS 8520, Avenue Poincaré, Université de Lille 1, 59652 Villeneuve d'Ascq (France); Alegre, M. P.; Piñero, J. C.; Araújo, D. [Dpto Ciencia de los Materiales, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real (Cádiz) (Spain); Jomard, F. [Groupe d'Étude de la Matière Condensée (GEMaC), UMR 8635 du CNRS, UVSQ, 45 Avenue des États-Unis, 78035 Versailles Cedex (France); and others

2014-08-28T23:59:59.000Z

363

Diamond logic inverter with enhancement-mode metal-insulator-semiconductor field effect transistor  

SciTech Connect (OSTI)

A diamond logic inverter is demonstrated using an enhancement-mode hydrogenated-diamond metal-insulator-semiconductor field effect transistor (MISFET) coupled with a load resistor. The gate insulator has a bilayer structure of a sputtering-deposited LaAlO{sub 3} layer and a thin atomic-layer-deposited Al{sub 2}O{sub 3} buffer layer. The source-drain current maximum, extrinsic transconductance, and threshold voltage of the MISFET are measured to be ?40.7?mA·mm{sup ?1}, 13.2?±?0.1?mS·mm{sup ?1}, and ?3.1?±?0.1?V, respectively. The logic inverters show distinct inversion (NOT-gate) characteristics for input voltages ranging from 4.0 to ?10.0?V. With increasing the load resistance, the gain of the logic inverter increases from 5.6 to as large as 19.4. The pulse response against the high and low input voltages shows the inversion response with the low and high output voltages.

Liu, J. W., E-mail: liu.jiangwei@nims.go.jp [International Center for Young Scientists (ICYS), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Liao, M. Y.; Imura, M. [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Watanabe, E.; Oosato, H. [Nanofabrication Platform, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Koide, Y., E-mail: koide.yasuo@nims.go.jp [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Nanofabrication Platform, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Center of Materials Research for Low Carbon Emission, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2014-08-25T23:59:59.000Z

364

Renewable Energy 33 (2008) 226231 The effect of annealing on the properties of diamond-like carbon  

E-Print Network [OSTI]

Renewable Energy 33 (2008) 226­231 The effect of annealing on the properties of diamond-like carbon (XPS) and high-resolution transmission electron microscopy (HRTEM). The reflectance of DLC thin film was investigated by UV­vis spectrometry and its electrical properties were investigated using a four point probe

Hong, Byungyou

365

Salsbury and Diamond: Automated Testing of HVAC Systems for Commissioning -1 -Automated Testing of HVAC Systems for Commissioning  

E-Print Network [OSTI]

and Diamond: Automated Testing of HVAC Systems for Commissioning - 1 - Automated Testing of HVAC Systems This paper describes an approach to the automation of the commissioning of HVAC systems. The approach of many HVAC systems is limited more by poor installation, commissioning, and maintenance than by poor

366

Evidence for ice VI as an inclusion in cuboid diamonds from high P-T near infrared spectroscopy  

E-Print Network [OSTI]

Evidence for ice VI as an inclusion in cuboid diamonds from high P-T near infrared spectroscopy H.W., Washington, D.C. 20015-1305, USA ABSTRACT Near infrared absorption (NIR) spectra of natural morphologically on heating to 1208C. The combination band of H2O at high pressure and temperature was measured using

Hemley, Russell J.

367

Quantum Monte Carlo Study of the Optical and Diffusive Properties of theVacancy Defect in Diamond  

E-Print Network [OSTI]

associated with radiation damage. It is also very interesting scientifically, with a wide variety of physicalQuantum Monte Carlo Study of the Optical and Diffusive Properties of theVacancy Defect in Diamond]. The best-known optical transition, GR1 at 1.673 eV [5], long associated with the neutral vacancy, cannot

Kent, Paul

368

THERMAL DISTRIBUTION SYSTEMS IN COMMERCIAL BUILDINGS Rick Diamond, Craig Wray, Darryl Dickerhoff, Nance Matson, and Duo Wang  

E-Print Network [OSTI]

1 THERMAL DISTRIBUTION SYSTEMS IN COMMERCIAL BUILDINGS Rick Diamond, Craig Wray, Darryl Dickerhoff SYSTEMS IN COMMERCIAL BUILDINGS 2 Acknowledgements Our largest debt of gratitude is to our Energy assistance guiding us through the EMCS system of the large commercial test building. The building management

369

Development and evaluation of operational strategies for providing an integrated diamond interchange ramp-metering control system  

E-Print Network [OSTI]

. Therefore, there is a lack of both analysis tools and operational strategies for considering them as an integrated system. One drawback of operating the ramp-metering system and the diamond interchange system in isolation is that traffic from the ramp...

Tian, Zongzhong

2004-09-30T23:59:59.000Z

370

Magnetic susceptibility measurement of solid oxygen at pressures up to 3.3?GPa  

SciTech Connect (OSTI)

The magnetic susceptibility of solid oxygen had long been observed only in the restricted pressure region below 0.8?GPa. We succeeded in extending the pressure region up to 3.3?GPa by clamping condensed oxygen in the sample chamber of a miniature diamond anvil cell and measuring the dc magnetic susceptibility using a superconducting quantum interference device magnetometer. In this experiment, the well-known ?–? and ?–? transitions are observed in the phase diagram, suggesting consistency with the previous results of X-ray and Raman studies. In addition, a new magnetic anomaly is observed in the ? phase.

Mito, M., E-mail: mitoh@tobata.isc.kyutech.ac.jp; Yamaguchi, S.; Tsuruda, H.; Deguchi, H. [Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550 (Japan); Ishizuka, M. [Renovation Center of Instruments for Science Education and Technology, Osaka University, Toyonaka 560-8531 (Japan)

2014-01-07T23:59:59.000Z

371

Mineralogy under extreme conditions  

SciTech Connect (OSTI)

We have performed measurements of minerals based on the synchrotron source for single crystal and powder X-ray diffraction, inelastic scattering, spectroscopy and radiography by using diamond anvil cells. We investigated the properties of iron (Fe), iron-magnesium oxides (Fe, Mg)O, silica(SiO{sub 2}), iron-magnesium silicates (Fe, Mg)SiO{sub 3} under simulated high pressure-high temperature extreme conditions of the Earth's crust, upper mantle, low mantle, core-mantle boundary, outer core, and inner core. The results provide a new window on the investigation of the mineral properties at Earth's conditions.

Shu, Jinfu (CIW)

2012-02-07T23:59:59.000Z

372

Behavior of the Diamond Difference and Low-Order Nodal Numerical Transport Methods in the Thick Diffusion Limit for Slab Geometry  

SciTech Connect (OSTI)

The objective of this work is to investigate the thick diffusion limit of various spatial discretizations of the one-dimensional, steady-state, monoenergetic, discrete ordinates neutron transport equation. This work specifically addresses the two lowest order nodal methods, AHOT-N0 and AHOT-N1, as well as reconsiders the asymptotic limit of the Diamond Difference method. The asymptotic analyses of the AHOT-N0 and AHOT-N1 nodal methods show that AHOT-N0 does not possess the thick diffusion limit for cell edge or cell average fluxes except under very limiting conditions, which is to be expected considering the AHOT-N0 method limits to the Step method in the thick diffusion limit. The AHOT-N1 method, which uses a linear in-cell representation of the flux, was shown to possess the thick diffusion limit for both cell average and cell edge fluxes. The thick diffusion limit of the DD method, including the boundary conditions, was derived entirely in terms of cell average scalar fluxes. It was shown that, for vacuum boundaries, only when {sigma}{sub t}, h, and Q are constant and {sigma}{sub a} = 0 is the asymptotic limit of the DD method close to the finite-differenced diffusion equation in the system interior, and that the boundary conditions between the systems will only agree in the absence of an external source. For a homogeneous medium an effective diffusion coefficient was shown to be present, which was responsible for causing numeric diffusion in certain cases. A technique was presented to correct the numeric diffusion in the interior by altering certain problem parameters. Numerical errors introduced by the boundary conditions and material interfaces were also explored for a two-region problem using the Diamond Difference method. A discrete diffusion solution which exactly solves the one-dimensional diffusion equation in a homogeneous region with constant cross sections and a uniform external source was also developed and shown to be equal to the finite-differenced diffusion discretization for c = 1 in the system interior, where again the boundary conditions again only agree in the absence of an external source. It was also shown that for c < 1 the exact discrete diffusion solution is written in terms of hyperbolic functions, with expressions which limit to the exact solution for the c = 1 case as c {yields} 1. Finally, a transport discretization is developed which reproduces the exact S2 solution for the case of a purely scattering homogeneous region with vacuum boundary conditions, and an extension to the discretization for the case of c < 1 is found by considering a Taylor series expansion of the exact answer centered at c = 0.

Gill DF

2007-04-17T23:59:59.000Z

373

Kernel polynomial method for a nonorthogonal electronic-structure calculation of amorphous diamond  

SciTech Connect (OSTI)

The Kernel polynomial method (KPM) has been successfully applied to tight-binding electronic-structure calculations as an O(N) method. Here we extend this method to nonorthogonal basis sets with a sparse overlap matrix {bold S} and a sparse Hamiltonian {bold H}. Since the KPM method utilizes matrix vector multiplications it is necessary to apply {bold S}{sup {minus}1}{bold H} onto a vector. The multiplication of {bold S}{sup {minus}1} is performed using a preconditioned conjugate-gradient method and does not involve the explicit inversion of {bold S}. Hence the method scales the same way as the original KPM method, i.e., O(N), although there is an overhead due to the additional conjugate-gradient part. We apply this method to a large scale electronic-structure calculation of amorphous diamond. {copyright} {ital 1997} {ital The American Physical Society}

Roeder, H.; Silver, R.N. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Drabold, D.A.; Dong, J.J. [Department of Physics and Astronomy, Condensed Matter and Surface Science Program, Ohio University, Athens, Ohio 45701 (United States)

1997-06-01T23:59:59.000Z

374

Proceedings of the conference on electrochemistry of carbon allotropes: Graphite, fullerenes and diamond  

SciTech Connect (OSTI)

This conference provided an opportunity for electrochemists, physicists, materials scientists and engineers to meet and exchange information on different carbon allotropes. The presentations and discussion among the participants provided a forum to develop recommendations on research and development which are relevant to the electrochemistry of carbon allotropes. The following topics which are relevant to the electrochemistry of carbon allotropes were addressed: Graphitized and disordered carbons, as Li-ion intercalation anodes for high-energy-density, high-power-density Li-based secondary batteries; Carbons as substrate materials for catalysis and electrocatalysis; Boron-doped diamond film electrodes; and Electrochemical characterization and electrosynthesis of fullerenes and fullerene-type materials. Abstracts of the presentations are presented.

Kinoshita, K. [ed.] [Lawrence Berkeley National Lab., CA (United States); Scherson, D. [ed.] [Case Western Reserve Univ., Cleveland, OH (United States)

1998-02-01T23:59:59.000Z

375

Wear mechanisms for polycrystalline-diamond compacts as utilized for drilling in geothermal environments. Final report  

SciTech Connect (OSTI)

The work, which was performed in the period from 12/6/79 to 9/30/81 included: (1) rock cutting experiments with single point polycrystalline sintered diamond compact (PDC) cutters to quantitatively determine cutter wear rates and identify wear modes, (2) PDC rock cutting experiments to measure temperatures developed and examine the effects of tool wear, cutting parameters and coolant flow rates on temperature generation, (3) assisting in performing full scale laboratory drilling experiments with PDC bits, using preheated air to simulate geothermal drilling conditions, and in analyzing and reporting the experimental results, and (4) acting in a consulting role with the purpose of establishing design specifications for geothermal hard matrix PDC bits to be procured by Sandia Laboratories for test purposes.

Hibbs, L.E. Jr.; Sogoian, G.C.

1983-05-01T23:59:59.000Z

376

Channeling Effect in Polycrystalline Deuterium-Saturated CVD Diamond Target Bombarded by Deuterium Ion Beam  

E-Print Network [OSTI]

At the ion accelerator HELIS at the LPI, the neutron yield is investigated in DD reactions within a polycrystalline deuterium-saturated CVD diamond, during an irradiation of its surface by a deuterium ion beam with the energy less than 30 keV. The measurements of the neutron flux in the beam direction are performed in dependence on the target angle, \\b{eta}, with respect to the beam axis. These measurements are performed using a multichannel detector based on He3 counters. A significant anisotropy in neutron yield is observed, it was higher by a factor of 3 at \\b{eta}=0 compared to that at \\b{eta} = +-45{\\deg}. The possible reasons for the anisotropy, including ion channeling, are discussed.

Bagulya, A V; Negodaev, M A; Rusetskii, A S; Chubenko, A P; Ralchenko, V G; Bolshakov, A P

2014-01-01T23:59:59.000Z

377

Channeling Effect in Polycrystalline Deuterium-Saturated CVD Diamond Target Bombarded by Deuterium Ion Beam  

E-Print Network [OSTI]

At the ion accelerator HELIS at the LPI, the neutron yield is investigated in DD reactions within a polycrystalline deuterium-saturated CVD diamond, during an irradiation of its surface by a deuterium ion beam with the energy less than 30 keV. The measurements of the neutron flux in the beam direction are performed in dependence on the target angle, \\b{eta}, with respect to the beam axis. These measurements are performed using a multichannel detector based on He3 counters. A significant anisotropy in neutron yield is observed, it was higher by a factor of 3 at \\b{eta}=0 compared to that at \\b{eta} = +-45{\\deg}. The possible reasons for the anisotropy, including ion channeling, are discussed.

A. V. Bagulya; O. D. Dalkarov; M. A. Negodaev; A. S. Rusetskii; A. P. Chubenko; V. G. Ralchenko; A. P. Bolshakov

2014-09-08T23:59:59.000Z

378

Polarization dependent asymmetric magneto-resistance features in nanocrystalline diamond films  

SciTech Connect (OSTI)

Polar angle-dependence of magneto-resistance (AMR) in heavily nitrogen-incorporated ultra-nanocrystalline diamond (UNCD) films is recorded by applying high magnetic fields, which shows strong anisotropic features at low temperatures. The temperature-dependence of MR and AMR can reveal transport in the weak-localization regime, which is explained by using a superlattice model for arbitrary values of disorder and angles. While a propagative Fermi surface model explains the negative MR features for low degree of disorder the azimuthal angle-dependent MR shows field dependent anisotropy due to the aligned conducting channels on the layers normal to film growth direction. The analysis of MR and AMR can extract the temperature dependence of dephasing time with respect to the elastic scattering time which not only establishes quasi-two dimensional features in this system but also suggests a potential application in monitoring the performance of UNCD based quantum devices.

Bhattacharyya, Somnath, E-mail: Somnath.Bhattacharyya@wits.ac.za [Nano-Scale Transport Physics Laboratory, School of Physics, University of the Witwatersrand, Private Bag 3, WITS 2050, Johannesburg (South Africa); DST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, WITS 2050, Johannesburg, South Africa and Department of Physics and Astronomy, University of Leeds, Leeds LS2 9JT (United Kingdom); Churochkin, Dmitry [Nano-Scale Transport Physics Laboratory, School of Physics, University of the Witwatersrand, Private Bag 3, WITS 2050, Johannesburg (South Africa)

2014-08-18T23:59:59.000Z

379

A superconducting cavity bus for single Nitrogen Vacancy defect centres in diamond  

E-Print Network [OSTI]

Circuit-QED has demonstrated very strong coupling between individual microwave photons trapped in a superconducting coplanar resonator and nearby superconducting qubits. In this work we show how, by designing a novel interconnect, one can strongly connect the superconducting resonator, via a magnetic interaction, to a small number (perhaps single), of electronic spins. By choosing the electronic spin to be within a Nitrogen Vacancy centre in diamond one can perform optical readout, polarization and control of this electron spin using microwave and radio frequency irradiation. More importantly, by utilising Nitrogen Vacancy centres with nearby 13C nuclei, using this interconnect, one has the potential build a quantum device where the nuclear spin qubits are connected over centimeter distances via the Nitrogen Vacancy electronic spins interacting through the superconducting bus.

J. Twamley; S. D. Barrett

2009-12-18T23:59:59.000Z

380

Broadband, noise-free optical quantum memory with neutral nitrogen-vacancy centers in diamond  

E-Print Network [OSTI]

It is proposed that the ground-state manifold of the neutral nitrogen-vacancy center in diamond could be used as a quantum two-level system in a solid-state-based implementation of a broadband, noise-free quantum optical memory. The proposal is based on the same-spin $\\Lambda$-type three level system created between the two E orbital ground states and the A$_1$ orbital excited state of the center, and the cross-linear polarization selection rules obtained with the application of transverse electric field or uniaxial stress. Possible decay and decoherence mechanisms of this system are discussed, and it is shown that high efficiency, noise-free storage of photons with a bandwidth of a few tens of GHz for a few tens of nanoseconds would be possible at low temperature.

E. Poem; C. Weinzetl; J. Klatzow; K. T. Kaczmarek; J. H. D. Munns; T. F. M. Champion; D. J. Saunders; J. Nunn; I. A. Walmsley

2015-01-11T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Resolving single molecule structures with nitrogen-vacancy centers in diamond  

E-Print Network [OSTI]

We present two-dimensional nuclear magnetic resonance spectroscopy protocols based on nitrogen-vacancy (NV) centers in diamond as efficient quantum sensors of protein structure. Continuous microwave driving fields are used to achieve Hartmann-Hahn resonances between NV spin sensor and proximate nuclei for selective control of nuclear spins and measurement of their polarization. Our protocols take advantage of the strong coupling between the NV sensor and the nuclei, thus facilitating coherence control of nuclear spins and relax the requirement of nuclear spin polarization. We dramatically reduce the experimental effort by employing a singular value thresholding matrix completion algorithm from signal processing to regain the resolution of protein structure based on sub-sampled data from NV based single molecule nuclear magnetic resonance spectroscopy. As an illustration, we demonstrate the power of this approach by identifying the nitrogen-Hydrogen interaction peak in an Alanine spectrum based on merely 5% of the sample data.

Matthias Kost; Jianming Cai; Martin B. Plenio

2014-07-23T23:59:59.000Z

382

Calibration of the nonlinear ring model at the Diamond Light Source  

E-Print Network [OSTI]

Nonlinear beam dynamics plays a crucial role in defining the performance of a storage ring. The beam lifetime, the injection efficiency, and the dynamic and momentum apertures available to the beam are optimized during the design phase by a proper optimization of the linear lattice and of the distribution of sextupole families. The correct implementation of the design model, especially the nonlinear part, is a nontrivial accelerator physics task. Several parameters of the nonlinear dynamics can be used to compare the real machine with the model and eventually to correct the accelerator. Most of these parameters are extracted from the analysis of turn-by-turn data after the excitation of betatron oscillations of the particles in the ring. We present the experimental results of the campaign of measurements carried out at the Diamond storage ring to characterize the nonlinear beam dynamics. A combination of frequency map analysis with the detuning with momentum measurements has allowed for a precise calibration ...

Bartolini, R; Rehm, G; Martin, I P S

2011-01-01T23:59:59.000Z

383

Broadband Magnetometry and Temperature Sensing with a Light Trapping Diamond Waveguide  

E-Print Network [OSTI]

Solid-state quantum sensors are attracting wide interest because of their exceptional sensitivity at room temperature. In particular, the spin properties of individual nitrogen vacancy (NV) color centers in diamond make it an outstanding nanoscale sensor of magnetic fields, electric fields, and temperature, under ambient conditions. Recent work on ensemble NV-based magnetometers, inertial sensors, and clocks have employed $N$ unentangled color centers to realize a factor of up to $\\sqrt{N}$ improvement in sensitivity. However, to realize fully this signal enhancement, new techniques are required to excite efficiently and to collect fluorescence from large NV ensembles. Here, we introduce a light-trapping diamond waveguide (LTDW) geometry that enables both high fluorescence collection ($\\sim20\\%$) and efficient pump absorption achieving an effective path length exceeding $1$ meter in a millimeter-sized device. The LTDW enables in excess of $2\\%$ conversion efficiency of pump photons into optically detected magnetic resonance (ODMR) fluorescence, a \\textit{three orders of magnitude} improvement over previous single-pass geometries. This dramatic enhancement of ODMR signal enables broadband measurements of magnetic field and temperature at less than $1$ Hz, a frequency range inaccessible by dynamical decoupling techniques. We demonstrate $\\sim 1~\\mbox{nT}/\\sqrt{\\mbox{Hz}}$ magnetic field sensitivity for $0.1$ Hz to $10$ Hz and a thermal sensitivity of $\\sim 400 ~\\mu\\mbox{K}/\\sqrt{\\mbox{Hz}}$ and estimate a spin projection limit at $\\sim 0.36$ fT/$\\sqrt{\\mbox{Hz}}$ and $\\sim 139~\\mbox{pK}/\\sqrt{\\mbox{Hz}}$, respectively.

Hannah Clevenson; Matthew E. Trusheim; Tim Schroder; Carson Teale; Danielle Braje; Dirk Englund

2014-06-19T23:59:59.000Z

384

Band offsets of Al{sub 2}O{sub 3} and HfO{sub 2} oxides deposited by atomic layer deposition technique on hydrogenated diamond  

SciTech Connect (OSTI)

High-k oxide insulators (Al{sub 2}O{sub 3} and HfO{sub 2}) have been deposited on a single crystalline hydrogenated diamond (H-diamond) epilayer by an atomic layer deposition technique at temperature as low as 120 Degree-Sign C. Interfacial electronic band structures are characterized by X-ray photoelectron spectroscopy. Based on core-level binding energies and valence band maximum values, valence band offsets are found to be 2.9 {+-} 0.2 and 2.6 {+-} 0.2 eV for Al{sub 2}O{sub 3}/H-diamond and HfO{sub 2}/H-diamond heterojunctions, respectively. Band gaps of the Al{sub 2}O{sub 3} and HfO{sub 2} have been determined to be 7.2 {+-} 0.2 and 5.4 {+-} 0.2 eV by measuring O 1s energy loss spectra, respectively. Both the Al{sub 2}O{sub 3}/H-diamond and HfO{sub 2}/H-diamond heterojunctions are concluded to be type-II staggered band configurations with conduction band offsets of 1.2 {+-} 0.2 and 2.7 {+-} 0.2 eV, respectively.

Liu, J. W.; Liao, M. Y.; Imura, M. [Optical and Electronic Materials Unit, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Koide, Y. [Optical and Electronic Materials Unit, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Nanofabrication Platform, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Center of Materials Research for Low Carbon Emission, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2012-12-17T23:59:59.000Z

385

Direct first-principles simulation of a high-performance electron emitter: Lithium-oxide-coated diamond surface  

SciTech Connect (OSTI)

We examined the field emission properties of lithium(Li)/oxygen(O)-co-terminated diamond (001) surface [C(001)-LiO] through real-time electron dynamics simulation under an applied field. The current emitted from this surface was found to be more than four-fold that emitted by an H-terminated (001) surface, the latter being a typical negative electron affinity system. This high performance is attributed to the Li layer, which bends the potential wall of O-induced electron pockets down in the direction of vacuum, thus facilitating electron emission. Detailed analysis of the emitted electrons and the profile of the self-consistent potential elucidated that the role of O atoms changes from an electron barrier on OH-terminated diamond surfaces to an outlet for electron emission on C(001)-LiO.

Miyamoto, Yoshiyuki, E-mail: yoshi-miyamoto@aist.go.jp; Miyazaki, Takehide [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Takeuchi, Daisuke; Yamasaki, Satoshi [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); JST, ALCA, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)

2014-09-28T23:59:59.000Z

386

Levitation and collection of diamond fine particles in the rf plasma chamber equipped with a hot filament  

SciTech Connect (OSTI)

We demonstrate the levitation of diamond fine particles in a H{sub 2} rf plasma chamber equipped with a hot filament and heated electrodes. The levitation conditions should be carefully chosen to compensate the strong thermophoretic forces caused by the filament and the electrodes. This levitation technique with the existence of a hot filament can be applied, e.g., for the efficient growth of diamond layers on seed particles injected and levitated in an rf plasma with reactive gases, e.g., CH{sub 4}/H{sub 2}. Additionally, the method for direct capture of levitated particles on a planar substrate was established, which is useful if it is necessary to analyze the particles after the levitation.

Shimizu, S.; Shimizu, T.; Thomas, H. M.; Morfill, G. E. [Max-Planck-Institut fuer extraterrestrische Physik, Giessenbachstrasse, D-85748 Garching (Germany); Jacob, W. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, Boltzmannstrasse 2, D-85748 Garching (Germany)

2011-11-15T23:59:59.000Z

387

Optimisation of NSLS-II Blade X-ray Beam Position Monitors: from Photoemission type to Diamond Detector  

SciTech Connect (OSTI)

Optimisation of blade type x-ray beam position monitors (XBPM) was performed for NSLS-II undulator IVU20. Blade material, con and #64257;guration and operation principle was analysed in order to improve XBPM performance. Optimisation is based on calculation of the XBPM signal spatial distribution. Along with standard photoemission type XBPM a Diamond Detector Blades (DDB) were analysed as blades for XBPMs. DDB XBPMs can help to overcome drawbacks of the photoemission blade XBPMs.

ILINSKI P.

2012-07-10T23:59:59.000Z

388

Frictional heating and convective cooling of polycrystalline diamond drag tools during rock cutting  

SciTech Connect (OSTI)

A numerical-analytical model is developed to predict temperatures in stud-mounted polycrystalline diamond compact (PDC) drag tools during rock cutting. Experimental measurements of the convective heat transfer coefficient for PDC cutters are used in the model to predict temperatures under typical drilling conditions with fluid flow. The analysis compares favorably with measurements of frictional temperatures in controlled cutting tests on Tennessee marble. It is shown that mean cutter wearflat temperatures can be maintained below the critical value of 750{sup 0}C only under conditions of low friction at the cutter/rock interface. This is true, regardless of the level of convective cooling. In fact, a cooling limit is established above which increases in convective cooling do not further reduce cutter temperatures. The ability of liquid drilling fluids to reduce interface friction is thus shown to be far more important in preventing excessive temperatures than their ability to provide cutter cooling. Due to the relatively high interface friction developed under typical air drilling conditions, it is doubtful that temperatures can be kept subcritical at high rotary speeds in some formations when air is employed as the drilling fluid, regardless of the level of cooling achieved.

Ortega, A.; Glowka, D.A.

1982-01-01T23:59:59.000Z

389

The potential application of ultra-nanocrystalline diamond films for heavy ion irradiation detection  

SciTech Connect (OSTI)

The potential of utilizing the ultra-nanocrystalline (UNCD) films for detecting the Au-ion irradiation was investigated. When the fluence for Au-ion irradiation is lower than the critical value (f{sub c}= 5.0 Multiplication-Sign 10{sup 12} ions/cm{sup 2}) the turn-on field for electron field emission (EFE) process of the UNCD films decreased systematically with the increase in fluence that is correlated with the increase in sp{sup 2}-bonded phase ({pi}{sup *}-band in EELS) due to the Au-ion irradiation. The EFE properties changed irregularly, when the fluence for Au-ion irradiation exceeds this critical value. The transmission electron microscopic microstructural examinations, in conjunction with EELS spectroscopic studies, reveal that the structural change preferentially occurred in the diamond-to-Si interface for the samples experienced over critical fluence of Au-ion irradiation, viz. the crystalline SiC phase was induced in the interfacial region and the thickness of the interface decreased. These observations implied that the UNCD films could be used as irradiation detectors when the fluence for Au-ion irradiation does not exceed such a critical value.

Chen, Huang-Chin [Department of Physics, Tamkang University, Tamsui, New-Taipei, Taiwan 251 (China); Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan, 300 (China); Chen, Shih-Show [Department of Physics, Tamkang University, Tamsui, New-Taipei, Taiwan 251 (China); Department of Information Technology and Mobile Communication, Taipei College of Maritime Technology, Tamsui, New-Taipei, Taiwan 251 (China); Wang, Wei-Cheng; Lin, I-Nan; Chang, Ching-Lin [Department of Physics, Tamkang University, Tamsui, New-Taipei, Taiwan 251 (China); Lee, Chi-Young [Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan, 300 (China); Guo, Jinghua [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

2013-06-15T23:59:59.000Z

390

Characterization of Monoenergetic Neutron Reference Fields with a High Resolution Diamond Detector  

E-Print Network [OSTI]

A novel radiation detector based on an artificial single crystal diamond was used to characterize in detail the energy distribution of neutron reference fields at the Physikalisch-Technische Bundesanstalt (PTB) and their contamination with charged particles. The monoenergetic reference fields at PTB in the neutron energy range from 1.5 MeV up to 19 MeV are generated by proton and deuteron beams impinging on solid and gas targets of tritium and deuterium. The energy of the incoming particles and the variation of the angle under which the measurement is performed produce monoenergetic reference fields with different mean energies and line shapes. In this paper we present high resolution neutron spectrometry measurements of different monoenergetic reference fields. The results are compared with calculated spectra taking into account the actual target parameters. Line structures in the order of 80 keV for a neutron energy of 9 MeV were resolved. The shift of the mean energy and the increasing of the width of the ...

Zimbal, A; Nolte, R; Schuhmacher, H

2009-01-01T23:59:59.000Z

391

Failure mechanisms of polycrystalline diamond compact drill bits in geothermal environments  

SciTech Connect (OSTI)

Over the past few years the interest in polycrystalline diamond compact (PDC) drill bits has grown proportionately with their successful use in drilling oil and gas wells in the North Sea and the United States. This keen interest led to a research program at Sandia to develop PDC drill bits suitable for the severe drilling conditions encountered in geothermal fields. Recently, three different PDC drill bits were tested using either air or mud drilling fluids: one in the laboratory with hot air, one in the Geysers field with air, and one in the Geysers field with mud. All three tests were unsuccessful due to failure of the braze joint used to attach the PDC drill blanks to the tungsten carbide studs. A post-mortem failure analysis of the defective cutters identified three major failure mechanisms: peripheral nonbonding caused by braze oxidation during the brazing step, nonbonding between PDC drill blanks and the braze due to contamination prior to brazing, and hot shortness. No evidence was found to suggest that the braze failures in the Geysers field tests were caused by frictional heating. In addition, inspection of the PDC/stud cutter assemblies using ultrasonic techniques was found to be ineffective for detecting the presence of hot shortness in the braze joint.

Hoover, E.R.; Pope, L.E.

1981-09-01T23:59:59.000Z

392

Atomic-scale nuclear spin imaging using quantum-assisted sensors in diamond  

E-Print Network [OSTI]

Nuclear spin imaging at the atomic level is essential for the understanding of fundamental biological phenomena and for applications such as drug discovery. The advent of novel nano-scale sensors has given hope of achieving the long-standing goal of single-protein, high spatial-resolution structure determination in their natural environment and ambient conditions. In particular, quantum sensors based on the spin-dependent photoluminescence of Nitrogen Vacancy (NV) centers in diamond have recently been used to detect nanoscale ensembles of external nuclear spins. While NV sensitivity is approaching single-spin levels, extracting relevant information from a very complex structure is a further challenge, since it requires not only the ability to sense the magnetic field of an isolated nuclear spin, but also to achieve atomic-scale spatial resolution. Here we propose a method that, by exploiting the coupling of the NV center to an intrinsic quantum memory associated with the Nitrogen nuclear spin, can reach a tenfold improvement in spatial resolution, down to atomic scales. The spatial resolution enhancement is achieved through coherent control of the sensor spin, which creates a dynamic frequency filter selecting only a few nuclear spins at a time. We propose and analyze a protocol that would allow not only sensing individual spins in a complex biomolecule, but also unraveling couplings among them, thus elucidating local characteristics of the molecule structure.

Ashok Ajoy; Ulf Bissbort; Mikhail D. Lukin; Ronald L. Walsworth; Paola Cappellaro

2014-07-11T23:59:59.000Z

393

Characterization of diamond-like nanocomposite thin films grown by plasma enhanced chemical vapor deposition  

SciTech Connect (OSTI)

Diamond-like nanocomposite (DLN) thin films, comprising the networks of a-C:H and a-Si:O were deposited on pyrex glass or silicon substrate using gas precursors (e.g., hexamethyldisilane, hexamethyldisiloxane, hexamethyldisilazane, or their different combinations) mixed with argon gas, by plasma enhanced chemical vapor deposition technique. Surface morphology of DLN films was analyzed by atomic force microscopy. High-resolution transmission electron microscopic result shows that the films contain nanoparticles within the amorphous structure. Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and x-ray photoelectron spectroscopy (XPS) were used to determine the structural change within the DLN films. The hardness and friction coefficient of the films were measured by nanoindentation and scratch test techniques, respectively. FTIR and XPS studies show the presence of C-C, C-H, Si-C, and Si-H bonds in the a-C:H and a-Si:O networks. Using Raman spectroscopy, we also found that the hardness of the DLN films varies with the intensity ratio I{sub D}/I{sub G}. Finally, we observed that the DLN films has a better performance compared to DLC, when it comes to properties like high hardness, high modulus of elasticity, low surface roughness and low friction coefficient. These characteristics are the critical components in microelectromechanical systems (MEMS) and emerging nanoelectromechanical systems (NEMS).

Santra, T. S.; Liu, C. H. [Institute of Nanoengineering and Microsystems (NEMS), National Tsing Hua University, Hsinchu, Taiwan 30043 (China); Bhattacharyya, T. K. [Department of Electronics and Electrical Communication Engineering, Indian Institute of Technology, Kharagpur 721302, West Bengal (India); Patel, P. [Department of Electrical and Computer Engineering, University of Illinois at Urbana Champaign, Urbana, Illinois 61801 (United States); Barik, T. K. [School of Applied Sciences, Haldia Institute of Technology, Haldia 721657, Purba Medinipur, West Bengal (India)

2010-06-15T23:59:59.000Z

394

Theory of Linear Optical Absorption in Diamond Shaped Graphene Quantum Dots  

E-Print Network [OSTI]

In this paper, optical and electronic properties of diamond shaped graphene quantum dots (DQDs) have been studied by employing large-scale electron-correlated calculations. The computations have been performed using the $\\pi$-electron Pariser-Parr-Pople model Hamiltonian, which incorporates long-range Coulomb interactions. The influence of electron-correlation effects on the ground and excited states has been included by means of the configuration-interaction approach, used at various levels. Our calculations have revealed that the absorption spectra are red-shifted with the increasing sizes of quantum dots. It has been observed that the first peak of the linear optical absorption, which represents the optical gap, is not the most intense peak. This result is in excellent agreement with the experimental data, but in stark contrast to the predictions of the tight-binding model, according to which the first peak is the most intense peak, pointing to the importance of electron-correlation effects. Furthermore, a...

Basak, Tista; Shukla, Alok

2015-01-01T23:59:59.000Z

395

Effect of doping on electronic states in B-doped polycrystalline CVD diamond films This article has been downloaded from IOPscience. Please scroll down to see the full text article.  

E-Print Network [OSTI]

Effect of doping on electronic states in B-doped polycrystalline CVD diamond films This article has-doped polycrystalline CVD diamond films O S Elsherif1,4, K D Vernon-Parry1, J H Evans-Freeman2 and P W May3 1 Materials the effect of boron (B) concentration on the electronic states in polycrystalline chemical vapour deposition

Bristol, University of

396

Method to grow carbon thin films consisting entirely of diamond grains 3-5 nm in size and high-energy grain boundaries  

DOE Patents [OSTI]

An ultrananocrystalline diamond (UNCD) having an average grain size between 3 and 5 nanometers (nm) with not more than about 8% by volume diamond having an average grain size larger than 10 nm. A method of manufacturing UNCD film is also disclosed in which a vapor of acetylene and hydrogen in an inert gas other than He wherein the volume ratio of acetylene to hydrogen is greater than 0.35 and less than 0.85, with the balance being an inert gas, is subjected to a suitable amount of energy to fragment at least some of the acetylene to form a UNCD film having an average grain size of 3 to 5 nm with not more than about 8% by volume diamond having an average grain size larger than 10 nm.

Carlisle, John A.; Auciello, Orlando; Birrell, James

2006-10-31T23:59:59.000Z

397

Studies of the frictional heating of polycrystalline diamond compact drag tools during rock cutting  

SciTech Connect (OSTI)

A numerical-analytical model is developed to analyze temperatures in polycrystalline diamond compact (PDC) drag tools subject to localized frictional heating at a worn flat area and convective cooling at exposed lateral surfaces. Experimental measurements of convective heat transfer coefficients of PDC cutters in a uniform crossflow are presented and used in the model to predict temperatures under typical drilling conditions with fluid flow. The analysis compares favorably with measurements of frictional temperatures in controlled cutting tests on Tennessee marble. It is found that average temperatures at the wearflat contact zone vary directly with frictional force per unit area and are proportional to the one-half power of the cutting speed at the velocities investigated. Temperatures are found to be much more sensitive to decreases in the dynamic friction by lubrication than to increases in convective cooling rates beyond currently achievable levels with water or drilling fluids. It is shown that use of weighted drilling fluids may actually decrease cooling rates compared to those achieved with pure water. It is doubtful that tool temperatures can be kept below critical levels (750/sup 0/C) if air is employed as the drilling fluid. The degree of tool wear is found to have a major influence on the thermal response of the friction contact zone, so that for equal heating per contact area, a worn tool will run much hotter than a sharp tool. It is concluded that tool temperatures may be kept below critical levels with conventional water or mud cooling as long as the fluid provides good cutter-rock lubrication.

Ortega, A.; Glowka, D.A.

1982-06-01T23:59:59.000Z

398

Relationship between the structure and electrical characteristics of diamond-like carbon films  

SciTech Connect (OSTI)

To elucidate the relationship between the structure and the electrical characteristics of diamond-like carbon (DLC) films, DLC films were synthesized in a well-controlled glow discharge with the aid of photoelectrons in an argon/methane atmosphere. The dielectric constant and breakdown strength of the films exhibited opposite behaviors, depending on the total pressure during the synthesis. The product of these two values decreased monotonically as the pressure increased. The Raman spectra were analyzed with a Voigt-type formula. Based on the results, the authors propose the “sp{sup 2} cluster model” for the DLC structure. This model consists of conductive clusters of sp{sup 2} carbons surrounded by a dielectric matrix sea of sp{sup 2} carbon, sp{sup 3} carbon, and hydrogen, and indicates that the dielectric constant of the whole DLC film is determined by the balance between the dielectric constant of the matrix and the total size of the clusters, while the breakdown strength is determined by the reciprocal of the cluster size. The model suggests that a high-? DLC film can be synthesized at a middle pressure and consists of well-grown sp{sup 2} clusters and a dense matrix. A low-? DLC film can be synthesized both at low and high pressures. The sp{sup 2} cluster model explains that a low-? DLC film synthesized at low pressure consists of a dense matrix and a low density of sp{sup 2} clusters, and exhibits a high breakdown strength. On the other hand, a low-? film synthesized at high pressure consists of a coarse matrix and a high density of clusters and exhibits a low breakdown strength.

Takabayashi, Susumu, E-mail: stak@riec.tohoku.ac.jp; Otsuji, Taiichi [Research Institute of Electrical Communication, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yang, Meng; Ogawa, Shuichi; Hayashi, Hiroyuki; Ješko, Radek; Takakuwa, Yuji [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2014-09-07T23:59:59.000Z

399

Energy levels and decoherence properties of single electron and nuclear spins in a defect center in diamond  

E-Print Network [OSTI]

The coherent behavior of the single electron and single nuclear spins of a defect center in diamond and a 13C nucleus in its vicinity, respectively, are investigated. The energy levels associated with the hyperfine coupling of the electron spin of the defect center to the 13C nuclear spin are analyzed. Methods of magnetic resonance together with optical readout of single defect centers have been applied in order to observe the coherent dynamics of the electron and nuclear spins. Long coherence times, in the order of microseconds for electron spins and tens of microseconds for nuclear spins, recommend the studied system as a good experimental approach for implementing a 2-qubit gate.

I. Popa; T. Gaebel; M. Domhan; C. Wittmann; F. Jelezko; J. Wrachtrup

2004-09-12T23:59:59.000Z

400

Enhancement in electron field emission in ultrananocrystalline and microcrystalline diamond films upon 100 MeV silver ion irradiation  

SciTech Connect (OSTI)

Enhanced electron field emission (EFE) behavior was observed in ultrananocrystalline diamond (UNCD) and microcrystalline diamond (MCD) films upon irradiation with 100 MeV Ag{sup 9+}-ions in a fluence of 5x10{sup 11} ions/cm{sup 2}. Transmission electron microscopy indicated that while the overall crystallinity of these films remained essentially unaffected, the local microstructure of the materials was tremendously altered due to heavy ion irradiation, which implied that the melting and recrystallization process have occurred along the trajectory of the heavy ions. Such a process induced the formation of interconnected nanocluster networks, facilitating the electron conduction and enhancing the EFE properties for the materials. The enhancement in the EFE is more prominent for MCD films than that for UNCD films, reaching a low turn-on field of E{sub 0}=3.2 V/mum and large EFE current density of J{sub e}=3.04 mA/cm{sup 2} for 5x10{sup 11} ions/cm{sup 2} heavy ion irradiated samples.

Chen, H.-C.; Palnitkar, Umesh; Pong, W.-F.; Lin, I-N. [Department of Physics, Tamkang University, Tamsui, Taiwan 251 (China); Singh, Abhinav Pratap; Kumar, Ravi [Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi 110007 (India)

2009-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

C-H surface diamond field effect transistors for high temperature (400?°C) and high voltage (500?V) operation  

SciTech Connect (OSTI)

By forming a highly stable Al{sub 2}O{sub 3} gate oxide on a C-H bonded channel of diamond, high-temperature, and high-voltage metal-oxide-semiconductor field-effect transistor (MOSFET) has been realized. From room temperature to 400?°C (673?K), the variation of maximum drain-current is within 30% at a given gate bias. The maximum breakdown voltage (V{sub B}) of the MOSFET without a field plate is 600?V at a gate-drain distance (L{sub GD}) of 7 ?m. We fabricated some MOSFETs for which V{sub B}/L{sub GD}?>?100?V/?m. These values are comparable to those of lateral SiC or GaN FETs. The Al{sub 2}O{sub 3} was deposited on the C-H surface by atomic layer deposition (ALD) at 450?°C using H{sub 2}O as an oxidant. The ALD at relatively high temperature results in stable p-type conduction and FET operation at 400?°C in vacuum. The drain current density and transconductance normalized by the gate width are almost constant from room temperature to 400?°C in vacuum and are about 10 times higher than those of boron-doped diamond FETs.

Kawarada, H., E-mail: kawarada@waseda.jp [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Kagami Memorial Laboratory for Material Science and Technology, Waseda University, Shinjuku, Tokyo 169-0051 (Japan); Tsuboi, H.; Naruo, T.; Yamada, T.; Xu, D.; Daicho, A.; Saito, T. [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Hiraiwa, A. [Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

2014-07-07T23:59:59.000Z

402

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling  

SciTech Connect (OSTI)

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill 'faster and deeper' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energy and loads. The significance of the 'ultra-high rotary speed drilling system' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm - usually well below 5,000 rpm. This document provides the progress through two phases of the program entitled 'Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling' for the period starting 30 June 2003 and concluding 31 March 2009. The accomplishments of Phases 1 and 2 are summarized as follows: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance (see Black and Judzis); (2) TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more consistent product with consistent performance. A test matrix for the final core bit testing program was completed; (3) TerraTek concluded small-scale cutting performance tests; (4) Analysis of Phase 1 data indicated that there is decreased specific energy as the rotational speed increases; (5) Technology transfer, as part of Phase 1, was accomplished with technical presentations to the industry (see Judzis, Boucher, McCammon, and Black); (6) TerraTek prepared a design concept for the high speed drilling test stand, which was planned around the proposed high speed mud motor concept. Alternative drives for the test stand were explored; a high speed hydraulic motor concept was finally used; (7) The high speed system was modified to accommodate larger drill bits than originally planned; (8) Prototype mud turbine motors and the high speed test stand were used to drive the drill bits at high speed; (9) Three different rock types were used during the testing: Sierra White granite, Crab Orchard sandstone, and Colton sandstone. The drill bits used included diamond impregnated bits, a polycrystalline diamond compact (PDC) bit, a thermally stable PDC (TSP) bit, and a hybrid TSP and natural diamond bit; and (10) The drill bits were run at rotary speeds up to 5500 rpm and weight on bit (WOB) to 8000 lbf. During Phase 2, the ROP as measured in depth of cut per bit revolution generally increased with increased WOB. The performance was mixed with increased rotary speed, with the depth cut with the impregnated drill bit generally increasing and the TSP and hybrid TSP drill bits generally decreasing. The ROP in ft/hr generally increased with all bits with increased WOB and rotary speed. The mechanical specific energy generally improved (decreased) with increased WOB and was mixed with increased rotary speed.

TerraTek, A Schlumberger Company

2008-12-31T23:59:59.000Z

403

Journal of Electronic Materials, Vol. 26, No. 3, 1997 SpecialIssuePaper Electrical Properties of MetaI-Diamond-Like-Nanocomposite  

E-Print Network [OSTI]

. VENKATRAMAN* *Schoolof Electrical and Computer Engineering and the Engineering Research Center voltage and high temperature applications. Basic SiC processing technology has been rapidly evolving and silicon net- works terminated by oxygen. Carbon to carbon bonds are predomi- nately sp3or diamond

Woodall, Jerry M.

404

Mean carrier transport properties and charge collection dynamics of single-crystal, natural type IIa diamonds from ion-induced conductivity measurements  

SciTech Connect (OSTI)

Ion-induced conductivity has been used to investigate the detector characteristics of diamond detectors. Both integrated-charge, and time-resolved current measurements were performed to examine the mean carrier transport properties of diamond and the dynamics of charge collection under highly-localized and high-density excitation conditions. The integrated-charge measurements were conducted with a standard pulse-counting system with {sup 241}Am radioactivity as the excitation source for the detectors. The time-resolved current measurements were performed using a 70 GHz random sampling oscilloscope with the detectors incorporated into high-speed microstrip transmission lines and the excitation source for these measurements was an ion beam of either 5-MeV He{sup +} or 10-MeV Si{sup 3+}. The detectors used in both experiments can be described as metal-semiconductor-metal (MSM) devices where a volume of the detector material is sandwiched between two metal plates. A charge collection model was developed to interpret the integrated-charge measurements which enabled estimation of the energy required to produce an electron-hole pair ({epsilon}{sub di}) and the mean carrier transport properties in diamond, such as carrier mobility and lifetime, and the behavior of the electrical contacts to diamond.

Han, S.S.

1993-09-01T23:59:59.000Z

405

Native and induced triplet nitrogen-vacancy centers in nano- and micro-diamonds: Half-field electron paramagnetic resonance fingerprint  

SciTech Connect (OSTI)

Multiple frequency electron paramagnetic resonance (EPR) study of small (4–25?nm) nanodiamonds obtained by various dynamic synthesis techniques reveals systematic presence in the half-field (HF) region a distinctive doublet fingerprint consisting of resolved g{sub HF1}?=?4.26 and g{sub HF2}?=?4.00 signals. This feature is attributed to “forbidden” ?M{sub S}?=?2 transitions in EPR spectra of two native paramagnetic centers of triplet (S?=?1) origin designated as TR1 and TR2, characterized by zero field splitting values D{sub 1}?=?0.0950?±?0.002?cm{sup ?1} and D{sub 2}?=?0.030?±?0.005?cm{sup ?1}. Nanodiamonds of ?50?nm particle size, obtained by crushing of Ib type nitrogen rich synthetic diamonds, show only HF TR2 signal whereas the same sample undergone high energy (20 MeV) electron irradiation and thermal annealing demonstrates rise of HF TR1 signal. The same HF TR1 signals appear in the process of fabrication of fluorescent nanodiamonds from micron-size synthetic diamond precursors. Results obtained allow unambiguous attribution of the half-field TR1 EPR signals with g{sub HF1}?=?4.26, observed in nano- and micron-diamond powders, to triplet negatively charged nitrogen-vacancy centers. These signals are proposed as reliable and convenient fingerprints in both qualitative and quantitative study of fluorescent nano- and micron-diamonds.

Shames, A. I., E-mail: sham@bgu.ac.il [Department of Physics, Ben-Gurion University of the Negev, Be'er-Sheva 84105 (Israel); Osipov, V. Yu.; Vul’, A. Ya. [Ioffe Physical-Technical Institute, Polytechnicheskaya 26, 194021 St. Petersburg (Russian Federation); Bardeleben, H.-J. von [Institut des Nano Sciences de Paris-INSP, Université Pierre et Marie Curie/UMR 7588 au CNRS, 7500 Paris (France); Boudou, J.-P.; Treussart, F. [Laboratoire Aimé Cotton, CNRS, Université Paris-Sud and ENS Cachan, 91405 Orsay (France)

2014-02-10T23:59:59.000Z

406

anvil points research facility: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for future use in the MITR-II. The information obtained includes reactivity effects, core flux ... Meagher, Paul Christopher 1976-01-01 123 Development of a Next-Generation...

407

ARM - Publications: Science Team Meeting Documents: The evolution of anvil  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD) by Microtops AtmosphericApplication andAnthe Infrared Land Surfacethe ARMmicrophysics observed

408

Tropical anvil cirrus evolution from observations and numerical simulations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2TopoPortalBRDF EffectsPacific: A Year in

409

Rectification properties of n-type nanocrystalline diamond heterojunctions to p-type silicon carbide at high temperatures  

SciTech Connect (OSTI)

Highly rectifying heterojunctions of n-type nanocrystalline diamond (NCD) films to p-type 4H-SiC substrates are fabricated to develop p-n junction diodes operable at high temperatures. In reverse bias condition, a potential barrier for holes at the interface prevents the injection of reverse leakage current from the NCD into the SiC and achieves the high rectification ratios of the order of 10{sup 7} at room temperature and 10{sup 4} even at 570?K. The mechanism of the forward current injection is described with the upward shift of the defect energy levels in the NCD to the conduction band of the SiC by forward biasing. The forward current shows different behavior from typical SiC Schottky diodes at high temperatures.

Goto, Masaki; Amano, Ryo; Shimoda, Naotaka [Graduate School of Automotive Science, Kyushu University, Nishiku, Fukuoka 819-0395 (Japan); Kato, Yoshimine, E-mail: yoshimine.kato@zaiko.kyushu-u.ac.jp [Department of Materials Science and Engineering, Kyushu University, Nishiku, Fukuoka 819-0395 (Japan); Teii, Kungen [Department of Applied Science for Electronics and Materials, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan)

2014-04-14T23:59:59.000Z

410

A diamond-based scanning probe spin sensor operating at low temperature in ultra-high vacuum  

SciTech Connect (OSTI)

We present the design and performance of an ultra-high vacuum (UHV) low temperature scanning probe microscope employing the nitrogen-vacancy color center in diamond as an ultrasensitive magnetic field sensor. Using this center as an atomic-size scanning probe has enabled imaging of nanoscale magnetic fields and single spins under ambient conditions. In this article we describe an experimental setup to operate this sensor in a cryogenic UHV environment. This will extend the applicability to a variety of molecular systems due to the enhanced target spin lifetimes at low temperature and the controlled sample preparation under UHV conditions. The instrument combines a tuning-fork based atomic force microscope (AFM) with a high numeric aperture confocal microscope and the facilities for application of radio-frequency (RF) fields for spin manipulation. We verify a sample temperature of <50 K even for strong laser and RF excitation and demonstrate magnetic resonance imaging with a magnetic AFM tip.

Schaefer-Nolte, E.; Wrachtrup, J. [Max-Planck Institute for Solid State Research, 70569 Stuttgart (Germany) [Max-Planck Institute for Solid State Research, 70569 Stuttgart (Germany); 3rd Institute of Physics and Research Center SCoPE, University Stuttgart, 70569 Stuttgart (Germany); Reinhard, F. [3rd Institute of Physics and Research Center SCoPE, University Stuttgart, 70569 Stuttgart (Germany)] [3rd Institute of Physics and Research Center SCoPE, University Stuttgart, 70569 Stuttgart (Germany); Ternes, M., E-mail: m.ternes@fkf.mpg.de [Max-Planck Institute for Solid State Research, 70569 Stuttgart (Germany); Kern, K. [Max-Planck Institute for Solid State Research, 70569 Stuttgart (Germany) [Max-Planck Institute for Solid State Research, 70569 Stuttgart (Germany); Institut de Physique de la Matière Condenseé, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland)

2014-01-15T23:59:59.000Z

411

Van der Waals density-functional theory study for bulk solids with BCC, FCC, and diamond structures  

E-Print Network [OSTI]

Proper inclusion of van der Waals (vdW) interactions in theoretical simulations based on standard density functional theory (DFT) is crucial to describe the physics and chemistry of systems such as organic and layered materials. Many encouraging approaches have been proposed to combine vdW interactions with standard approximate DFT calculations. Despite many vdW studies, there is no consensus on the reliability of vdW methods. To help further development of vdW methods, we have assessed various vdW functionals through the calculation of structural prop- erties at equilibrium, such as lattice constants, bulk moduli, and cohesive energies, for bulk solids, including alkali, alkali-earth, and transition metals, with BCC, FCC, and diamond structures as the ground state structure. These results provide important information for the vdW-related materials research, which is essential for designing and optimizing materials systems for desired physical and chemical properties.

Park, Jinwoo; Hong, Suklyun

2015-01-01T23:59:59.000Z

412

The Geometry of Large Causal Diamonds and the No Hair Property of Asymptotically de-Sitter Spacetimes  

E-Print Network [OSTI]

In a previous paper we obtained formulae for the volume of a causal diamond or Alexandrov open set $I^+(p) \\cap I^-(q)$ whose duration $\\tau(p,q) $ is short compared with the curvature scale. In the present paper we obtain asymptotic formulae valid when the point $q$ recedes to the future boundary ${\\cal I}^+$ of an asymptotically de-Sitter spacetime. The volume (at fixed $\\tau$) remains finite in this limit and is given by the universal formula $V(\\tau) = {4\\over 3}\\pi (2\\ln \\cosh{\\tau\\over 2}-\\tanh^2{\\tau\\over 2})$ plus corrections (given by a series in $e^{-t_q}$) which begin at order $e^{-4t_q}$. The coefficents of the corrections depend on the geometry of ${\\cal I}^+$. This behaviour is shown to be consistent with the no-hair property of cosmological event horizons and with calculations of de-Sitter quasinormal modes in the literature.

G. W. Gibbons; S. N. Solodukhin

2007-06-12T23:59:59.000Z

413

The structure and electrochemical behavior of nitrogen-containing nanocrystalline diamond films deposited from CH4/N2/Ar mixtures.  

SciTech Connect (OSTI)

Electrically conductive nanocrystalline diamond films (approximately 750 to 1000 nm thick) were deposited on conducting Si and W substrates from CH{sub 4}/N{sub 2}/Ar gas mixtures using plasma-enhanced chemical vapor deposition. Such films are continuous over the surface and nanometer smooth. The grain size is 3 to 10 nm, and the grain boundaries are 0.2 to 0.5 nm wide (two carbon atoms). Nitrogen appears to substitutionally insert into the grain boundaries and the film concentration ({approx}10{sup 20} atom/cm{sup 3}) scales with the N{sub 2} added to the source gas mixture up to about the 5% level. The nitrogen-incorporated films are void of pinholes and cracks, and electrically conducting due in part to the high concentration of nitrogen impurities and or the nitrogen-related defects (sp{sup 2} bonding). The films possess semimetallic electronic properties over a potential range from at least -1.5 to 1.0 V vs. SCE. The electrodes, like boron-doped microcrystalline diamond, exhibit a wide working potential window, a low background current, and high degree of electrochemical activity for redox systems such as Fe(CN)6{sup -3/-4}, Ru(NH{sub 3}6{sup +3/+2}), IrCl6{sup -2/-3}, and methyl viologen (MV{sup +2/+}). More sluggish electrode kinetics are observed for 4-methylcatechol, presumably due to weak adsorption on the surface. Apparent heterogeneous electron transfer rate constants of 10{sup -2} to 10{sup -1} cm/s are observed for Fe(CN)6{sup -3/-4}, Ru(NH{sub 3})6{sup +3/+2}, IrCl6{sup -2/-3}, and MV {sup +2/+} at films without any pretreatment.

Chen, Q.; Gruen, D. M.; Krauss, A. R.; Corrigan, T. D.; Swain, G. M.; Utah State Univ.; Northwestern Univ.

2001-01-01T23:59:59.000Z

414

Click Chemistry in Generation of Mammalian Acetylome to Study Shwachman-Diamond Syndrome  

E-Print Network [OSTI]

Address: c/o Dr. Paul de Figueiredo Department of Plant Pathology & Microbiology MS 2123 Texas A&M University College Station, TX 77843 Email Address: carsonsib@gmail.com Education: B.S., Biology Texas A&M University, May 2012 Honors... to the cell pellet, followed by co- incubating with 0.7 ?L of benzonase nuclease (Sigma, St. Louis, MO) for 20 min. The cell suspensions were then lysed by adding 150 ?L of lysis buffer (1% SDS, 150 mM NaCl, 50 mM tris-base, pH 7.8) with subsequent...

Sibley, Robert

2011-08-08T23:59:59.000Z

415

Superhard nanophase cutter materials for rock drilling applications  

SciTech Connect (OSTI)

The Low Pressure-High Temperature (LPHT) System has been developed for sintering of nanophase cutter and anvil materials. Microstructured and nanostructured cutters were sintered and studied for rock drilling applications. The WC/Co anvils were sintered and used for development of High Pressure-High Temperature (HPHT) Systems. Binderless diamond and superhard nanophase cutter materials were manufactured with help of HPHT Systems. The diamond materials were studied for rock machining and drilling applications. Binderless Polycrystalline Diamonds (BPCD) have high thermal stability and can be used in geothermal drilling of hard rock formations. Nanophase Polycrystalline Diamonds (NPCD) are under study in precision machining of optical lenses. Triphasic Diamond/Carbide/Metal Composites (TDCC) will be commercialized in drilling and machining applications.

Voronov, O.; Tompa, G.; Sadangi, R.; Kear, B.; Wilson, C.; Yan, P.

2000-06-23T23:59:59.000Z

416

Method and article of manufacture corresponding to a composite comprised of ultra nonacrystalline diamond, metal, and other nanocarbons useful for thermoelectric and other applications  

DOE Patents [OSTI]

One provides (101) disperse ultra-nanocrystalline diamond powder material that comprises a plurality of substantially ordered crystallites that are each sized no larger than about 10 nanometers. One then reacts (102) these crystallites with a metallic component. The resultant nanowire is then able to exhibit a desired increase with respect to its ability to conduct electricity while also substantially preserving the thermal conductivity behavior of the disperse ultra-nanocrystalline diamond powder material. The reaction process can comprise combining (201) the crystallites with one or more metal salts in an aqueous solution and then heating (203) that aqueous solution to remove the water. This heating can occur in a reducing atmosphere (comprising, for example, hydrogen and/or methane) to also reduce the salt to metal.

Gruen, Dieter M.

2010-05-18T23:59:59.000Z

417

Predicting spatial distribution of critical pore types and their influence on reservoir quality, Canyon (Pennsylvanian) Reef reservoir, Diamond M field, Texas  

E-Print Network [OSTI]

Subject: Geology iii ABSTRACT Predicting Spatial Distribution of Critical Pore Types and Their Influence on Reservoir Quality, Canyon (Pennsylvanian) Reef Reservoir, Diamond M Field, Texas... scale. Ultimately slice maps of reservoir quality at a 10 ft interval for a 150 ft section of the Canyon Reef reservoir were developed. These iv reservoir quality maps will provide a useful tool for the design and implementation of accurate...

Fisher, Aaron Jay

2007-04-25T23:59:59.000Z

418

Fabrication and testing of diamond-machined gratings in ZnSe, GaP, and bismuth germanate for the near infrared and visible  

SciTech Connect (OSTI)

High quality immersion gratings for infrared applications have been demonstrated in silicon and germanium. To extend this technology to shorter wavelengths other materials must be investigated. We selected three materials, zinc selenide, gallium phosphide and bismuth germanate (Bi{sub 4}Ge{sub 3}O{sub 12}), based on high refractive index, good visible transmission and commercial availability in useful sizes. Crystal samples were diamond turned on an ultra-precision lathe to identify preferred cutting directions. Using this information we diamond-flycut test gratings over a range of feed rates to determine the optimal cutting conditions. For both ZnSe and GaP good surface quality was achieved at feed rates up to 1.0 cm/minute using a special compound angle diamond tool with negative rake angles on both cutting surfaces. The surface roughness of the groove facets was about 4 nm. A Zygo interferometer measured grating wavefront errors in reflection. For the ZnSe the RMS error was < {lambda}/20 at 633nm. More extensive testing was performed with a HeNe laser source and a cooled CCD camera. These measurements demonstrated high relative diffraction efficiency (> 80%), low random groove error (2.0 nm rms), and Rowland ghost intensities at < 0.1%. Preliminary tests on bismuth germanate show high tool wear.

Kuzmenko, P J; Little, S L; Ikeda, Y; Kobayashi, N

2008-06-22T23:59:59.000Z

419

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING  

SciTech Connect (OSTI)

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rock cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING'' for the period starting June 23, 2003 through September 30, 2004. (1) TerraTek has reviewed applicable literature and documentation and has convened a project kick-off meeting with Industry Advisors in attendance. (2) TerraTek has designed and planned Phase I bench scale experiments. Some difficulties in obtaining ultra-high speed motors for this feasibility work were encountered though they were sourced mid 2004. (3) TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. Some improvements over early NASA experiments have been identified.

Alan Black; Arnis Judzis

2004-10-01T23:59:59.000Z

420

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING  

SciTech Connect (OSTI)

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rock cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING'' for the period starting June 23, 2003 through September 30, 2004. TerraTek has reviewed applicable literature and documentation and has convened a project kick-off meeting with Industry Advisors in attendance. TerraTek has designed and planned Phase I bench scale experiments. Some difficulties in obtaining ultra-high speed motors for this feasibility work were encountered though they were sourced mid 2004. TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. Some improvements over early NASA experiments have been identified.

Alan Black; Arnis Judzis

2004-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Novel Catalyst Support Materials for PEM Fuel Cells: Current Status and Future Prospects  

SciTech Connect (OSTI)

The catalyst supports exhibit great influence on the cost, performance, and durability of polymer electrolyte membrane (PEM) fuel cells. This review paper is to summarize several important kinds of novel support materials for PEM fuel cells (including direct methanol fuel cell, DMFC): nanostructured carbon materials (carbon nanotubes/carbon nanofibers, mesoporous carbon), conductive doped diamonds and nanodiamonds, conductive oxides (tin oxide/indium tin oxide, titanium oxide, tungsten oxide) and carbides (tungsten carbides). The advantages and disadvantages, the acting mechanism to promote electrocatalysis, and the strategies to improve present catalyst support materials and to search for new ones are discussed. This is expected to throw light on future development of catalyst support for PEM fuel cells.

Shao, Yuyan; Liu, Jun; Wang, Yong; Lin, Yuehe

2008-12-15T23:59:59.000Z

422

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling  

SciTech Connect (OSTI)

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energy and loads. The significance of the ultra-high rotary speed drilling system is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 October 2004 through 30 September 2005. Additionally, research activity from 1 October 2005 through 28 February 2006 is included in this report: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance. (2) TerraTek designed and planned Phase I bench scale experiments. Some difficulties continue in obtaining ultra-high speed motors. Improvements have been made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs have been provided to vendors for production. A more consistent product is required to minimize the differences in bit performance. A test matrix for the final core bit testing program has been completed. (3) TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. (4) Significant testing has been performed on nine different rocks. (5) Bit balling has been observed on some rock and seems to be more pronounces at higher rotational speeds. (6) Preliminary analysis of data has been completed and indicates that decreased specific energy is required as the rotational speed increases (Task 4). This data analysis has been used to direct the efforts of the final testing for Phase I (Task 5). (7) Technology transfer (Task 6) has begun with technical presentations to the industry (see Judzis).

Arnis Judzis; Alan Black; Homer Robertson

2006-03-01T23:59:59.000Z

423

Room-Temperature in situ Nuclear Spin Hyperpolarization from Optically-Pumped Nitrogen Vacancy Centers in Diamond  

E-Print Network [OSTI]

We report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field nuclear magnetic resonance (NMR). The hyperpolarization is achieved by optical pumping (OP) of nitrogen vacancy defect centers in diamond accompanied by dynamic nuclear polarization (DNP). The technique harnesses the large optically-induced spin polarization of NV- centers at room temperature, which is many orders of magnitude greater than thermal equilibrium polarization and typically achievable only at sub-Kelvin temperatures. Transfer of the spin polarization to the 13C nuclear spins is accomplished via a combination of OP and microwave irradiation. The OP/DNP is performed at 420 mT, where inductive detection of NMR is feasible, in contrast to the typically exploited level anticrossing regimes at 100 mT and 50 mT. Here, we report a bulk nuclear spin polarization of 6%. This polarization was generated in situ and detected with a standard, inductive NMR probe without the need for sample shuttling or precise crystal orientation. Hyperpolarization via OP/DNP should operate at arbitrary magnetic fields, enabling orders of magnitude sensitivity enhancement for NMR of solids and liquids at ambient conditions.

Jonathan P. King; Keunhong Jeong; Christophoros C. Vassiliou; Chang S. Shin; Ralph H. Page; Claudia E. Avalos; Hai-Jing Wang; Alexander Pines

2015-01-13T23:59:59.000Z

424

Nitrogen incorporated ultrananocrystalline diamond based field emitter array for a flat-panel x-ray source  

SciTech Connect (OSTI)

A field emission based flat-panel transmission x-ray source is being developed as an alternative for medical and industrial imaging. A field emitter array (FEA) prototype based on nitrogen incorporated ultrananocrystalline diamond film has been fabricated to be used as the electron source of this flat panel x-ray source. The FEA prototype was developed using conventional microfabrication techniques. The field emission characteristics of the FEA prototype were evaluated. Results indicated that emission current densities of the order of 6?mA/cm{sup 2} could be obtained at electric fields as low as 10?V/?m to 20?V/?m. During the prototype microfabrication process, issues such as delamination of the extraction gate and poor etching of the SiO{sub 2} insulating layer located between the emitters and the extraction layer were encountered. Consequently, alternative FEA designs were investigated. Experimental and simulation data from the first FEA prototype were compared and the results were used to evaluate the performance of alternative single and double gate designs that would yield better field emission characteristics compared to the first FEA prototype. The best simulation results are obtained for the double gate FEA design, when the diameter of the collimator gate is around 2.6 times the diameter of the extraction gate.

Posada, Chrystian M.; Grant, Edwin J.; Lee, Hyoung K.; Castaño, Carlos H., E-mail: castanoc@mst.edu [Nuclear Engineering, Missouri University of Science and Technology, 220 Fulton Hall, Rolla, Missouri 65401 (United States); Divan, Ralu; Sumant, Anirudha V.; Rosenmann, Daniel; Stan, Liliana [Center for Nanoscale Materials, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2014-04-07T23:59:59.000Z

425

Using X-Rays to Test CVD Diamond Detectors for Areal Density Measurement at the National Ignition Facility  

SciTech Connect (OSTI)

At the National Ignition Facility (NIF), 192 laser beams will compress a target containing a mixture of deuterium and tritium (DT) that will release fusion neutrons, photons, and other radiation. Diagnostics are being designed to measure this emitted radiation to infer crucial parameters of an ignition shot. Chemical Vapor Deposited (CVD) diamond is one of the ignition diagnostics that will be used as a neutron time-of-flight detector for measuring primary (14.1 MeV) neutron yield, ion temperature, and plasma areal density. This last quantity is the subject of this study and is inferred from the number of downscattered neutrons arriving late in time, divided by the number of primary neutrons. We determine in this study the accuracy with which this detector can measure areal density, when the limiting factor is detector and electronics saturation. We used laser-produced x-rays to reproduce NIF signals in terms of charge carriers density, time between pulses, and amplitude contrast and found that the effect of the large pulse on the small pulse is at most 8.4%, which is less than the NIF accuracy requirement of {+-} 10%.

Dauffy, L S; Koch, J A; Tommasini, R; Izumi, N

2008-05-06T23:59:59.000Z

426

Electronic states of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface studied by synchrotron radiation photoemission and X-ray absorption spectroscopy  

SciTech Connect (OSTI)

The energy band-lineup and the electronic structure of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface have been investigated by synchrotron radiation photoemission and x-ray absorption near-edge structure (XANES) measurements. It is found that the energy band-lineup is stagger-type, so-called type-II, with its valence band discontinuity of as high as 3.9?eV and its conduction band discontinuity of 2.7?eV. The valence band maximum of the H-terminated diamond surface is positioned at Fermi level as a result of high-density hole accumulation on the diamond side. The XANES measurement has shown that the oxygen-derived interface state locates at about 1–3?eV above the Fermi level.

Takahashi, Kazutoshi; Imamura, Masaki [Synchrotron Light Application Center, Saga University, Saga 840-8502 (Japan); Hirama, Kazuyuki [NTT Basic Research Laboratories, NTT Corporation, Atsugi 243-0198 (Japan); Kasu, Makoto [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan)

2014-02-17T23:59:59.000Z

427

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect (OSTI)

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

428

The Frenkel Line: a direct experimental evidence for the new thermodynamic boundary  

E-Print Network [OSTI]

Supercritical fluids play a significant role in elucidating fundamental aspects of liquid matter under extreme conditions. They have been extensively studied at pressures and temperatures relevant to various industrial applications. However, much less is known about the structural behaviour of supercritical fluids and no structural crossovers have been observed in static compression experiments in any temperature and pressure ranges beyond the critical point. The structure of supercritical state is currently perceived to be uniform everywhere on the phase diagram, and to change only in a monotonic way while moving along any pressure and temperature path beyond the critical point and its neighborhood. Conversely, we observe structural crossovers in a deeply supercritical sample through diffraction measurements in a diamond anvil cell and discover a new thermodynamic boundary on the pressure-temperature diagram. We explain the existence of these crossovers in the framework of the phonon theory of liquids using ...

Bolmatov, Dima; Zav'yalov, D; Tkachev, S N; Cunsolo, A; Cai, Y Q

2015-01-01T23:59:59.000Z

429

Phase transition and metallization of FeO at high pressures and temperatures  

SciTech Connect (OSTI)

Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component of the core. Therefore its high pressure-temperature behavior, including its electronic structure, is essential to understanding the nature and evolution of Earth's deep interior. We performed X-ray diffraction and radiometric measurements on wuestite in a laser-heated diamond anvil cell, finding an insulator-metal transition at high pressures and temperatures. Our data show a negative slope for this apparently isostructural phase boundary, which is characterized by a volume decrease and emissivity increase. The metallic phase of FeO is stable at conditions of the lower mantle and core, which has implications for the high P-T character of Fe-O bonds, magnetic field propagation, and lower mantle conductivity.

Fischer, Rebecca A.; Campbell, Andrew J.; Lord, Oliver T.; Shofner, Gregory A.; Dera, Przemyslaw; Prakapenka, Vitali B. (Maryland); (UC); (UCL)

2012-05-10T23:59:59.000Z

430

MEASUREMENT OF THE SHOCK-HEATED MELT CURVE OF LEAD USING PYROMETRY AND REFLECTOMETRY  

SciTech Connect (OSTI)

Data on the high-pressure melting temperatures of metals is of great interest in several fields of physics including geophysics. Measuring melt curves is difficult but can be performed in static experiments (with laser-heated diamond-anvil cells for instance) or dynamically (i.e., using shock experiments). However, at the present time, both experimental and theoretical results for the melt curve of lead are at too much variance to be considered definitive. As a result, we decided to perform a series of shock experiments designed to provide a measurement of the melt curve of lead up to about 50 GPa in pressure. At the same time, we developed and fielded a new reflectivity diagnostic, using it to make measurements on tin. The results show that the melt curve of lead is somewhat higher than the one previously obtained with static compression and heating techniques.

D. Partouche-Sebban and J. L. Pelissier, Commissariat a` l'Energie Atomique,; F. G. Abeyta, Los Alamos National Laboratory; W. W. Anderson, Los Alamos National Laboratory; M. E. Byers, Los Alamos National Laboratory; D. Dennis-Koller, Los Alamos National Laboratory; J. S. Esparza, Los Alamos National Laboratory; S. D. Borror, Bechtel Nevada; C. A. Kruschwitz, Bechtel Nevada

2004-01-01T23:59:59.000Z

431

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling  

SciTech Connect (OSTI)

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energy and loads. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm-usually well below 5,000 rpm. This document details the progress at the end of Phase 1 on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 March 2006 and concluding 30 June 2006. (Note: Results from 1 September 2005 through 28 February 2006 were included in the previous report (see Judzis, Black, and Robertson)). Summarizing the accomplished during Phase 1: {lg_bullet} TerraTek reviewed applicable literature and documentation and convened a project kickoff meeting with Industry Advisors in attendance (see Black and Judzis). {lg_bullet} TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Some difficulties continued in obtaining ultra-high speed motors. Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more consistent product with consistent performance. A test matrix for the final core bit testing program was completed. {lg_bullet} TerraTek concluded Task 3 ''Small-scale cutting performance tests.'' {sm_bullet} Significant testing was performed on nine different rocks. {sm_bullet} Five rocks were used for the final testing. The final tests were based on statistical design of experiments. {sm_bullet} Two full-faced bits, a small diameter and a large diameter, were run in Berea sandstone. {lg_bullet} Analysis of data was completed and indicates that there is decreased specific energy as the rotational speed increases (Task 4). Data analysis from early trials was used to direct the efforts of the final testing for Phase I (Task 5). {lg_bullet} Technology transfer (Task 6) was accomplished with technical presentations to the industry (see Judzis, Boucher, McCammon, and Black).

Arnis Judzis; Homer Robertson; Alan Black

2006-06-22T23:59:59.000Z

432

Rabi Waves and Peculiarities of Raman Scattering in Carbon Nanotubes, Produced by High Energy Ion Beam Modification of Diamond Single Crystals  

E-Print Network [OSTI]

QED-model for multichain coupled qubit system, proposed in \\cite{Part1}, was confirmed by Raman scattering studies of carbon zigzag-shaped nanotubes, produced by high energy ion beam modification of natural diamond single crystals. New quantum optics phenomenon - Rabi waves - has been experimentally identified for the first time. Raman spectra in perfect quasi-1D carbon nanotubes are quite different in comparison with well known Raman spectra in 2D carbon nanotubes of larger diameter. They characterized by vibronic mode of Su-Schriffer-Heeger $\\sigma$-polaron lattice and its revival part in frequency representation, which is the consequence of Rabi wave packet formation.

Dmitry Yearchuck; Alla Dovlatova

2011-03-06T23:59:59.000Z

433

Origin of graphitic filaments on improving the electron field emission properties of negative bias-enhanced grown ultrananocrystalline diamond films in CH{sub 4}/Ar plasma  

SciTech Connect (OSTI)

Microstructural evolution of bias-enhanced grown (BEG) ultrananocrystalline diamond (UNCD) films has been investigated using microwave plasma enhanced chemical vapor deposition in gas mixtures of CH{sub 4} and Ar under different negative bias voltages ranging from ?50 to ?200?V. Scanning electron microscopy and Raman spectroscopy were used to characterize the morphology, growth rate, and chemical bonding of the synthesized films. Transmission electron microscopic investigation reveals that the application of bias voltage induced the formation of the nanographitic filaments in the grain boundaries of the films, in addition to the reduction of the size of diamond grains to ultra-nanosized granular structured grains. For BEG-UNCD films under ?200?V, the electron field emission (EFE) process can be turned on at a field as small as 4.08?V/?m, attaining a EFE current density as large as 3.19?mA/cm{sup 2} at an applied field of 8.64?V/?m. But the films grown without bias (0?V) have mostly amorphous carbon phases in the grain boundaries, possessing poorer EFE than those of the films grown using bias. Consequently, the induction of nanographitic filaments in grain boundaries of UNCD films grown in CH{sub 4}/Ar plasma due to large applied bias voltage of ?200?V is the prime factor, which possibly forms interconnected paths for facilitating the transport of electrons that markedly enhance the EFE properties.

Sankaran, K. J.; Tai, N. H., E-mail: inanlin@mail.tku.edu.tw, E-mail: nhtai@mse.nthu.edu.tw [Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan (China); Huang, B. R.; Saravanan, A. [Graduate Institute of Electro-Optical Engineering and Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan (China); Lin, I. N., E-mail: inanlin@mail.tku.edu.tw, E-mail: nhtai@mse.nthu.edu.tw [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China)

2014-10-28T23:59:59.000Z

434

Diamond Pixel Luminosity Telescopes  

SciTech Connect (OSTI)

In this document, Halyo summaries her key contributions to CMS at the LHC and provide an explanation of their importance and her role in each project. At the end Halyo describes her recent research interest that includes GPU/MIC Acceleration of the High Level Trigger (HLT) to Extend the Physics Research at the LHC. A descriptionof her work the recent promising results that she accomplished and the deliverable are also elaborated. These contribution were only possible thanks to DOE support of junior faculty research and their clear goal to promote research and innovations. #3;Princeton University i

Halyo, Valerie

2014-12-23T23:59:59.000Z

435

Diamond Schottky barrier diodes  

E-Print Network [OSTI]

Laboratory, to Suat for showing La Dolce vita, to Mash-hud and the right to ask questions, to Marina Antoniou and her future Romanian villa, to Zeeshan and our twin PhD-routes, to Hatice and her heinous Bukowskian nights To Alex and our Internautian nights... ....................... .. . .............. ....... ..... ......... 20 2.4.1 Introduction. . .. . .. . . . . .. . ...... ... . .. . .. . ... ..... . .. . .. . .............. 20 2.4.2 Schottky diodes...... ............ .................................... 20 2.4.3 Field effect transistors...

Brezeanu, Mihai

2008-03-11T23:59:59.000Z

436

Electron Spin Resonance Shift and Linewidth Broadening of Nitrogen-Vacancy Centers in Diamond as a Function of Electron Irradiation Dose  

E-Print Network [OSTI]

A high-nitrogen-concentration diamond sample was subject to 200-keV electron irradiation using a transmission electron microscope. The optical and spin-resonance properties of the nitrogen-vacancy (NV) color centers were investigated as a function of the irradiation dose up to 6.4\\times1021 e-/cm2. The microwave transition frequency of the NV- center was found to shift by up to 0.6% (17.1 MHz) and the linewidth broadened with increasing electron-irradiation dose. Unexpectedly, the measured magnetic sensitivity is best at the lowest irradiation dose, even though the NV concentration increases monotonically with increasing dose. This is in large part due to a sharp reduction in optically-detected spin contrast at higher doses.

Edwin Kim; Victor M. Acosta; Erik Bauch; Dmitry Budker; Philip R. Hemmer

2012-08-09T23:59:59.000Z

437

Elastic properties, sp{sup 3} fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides  

SciTech Connect (OSTI)

Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon sp{sup 2} versus sp{sup 3} content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp{sup 3} fraction, the shear modulus ? of dl-BC{sub 4}, containing 10% carbon atoms with sp{sup 3} bonds, and dl-B{sub 3}C{sub 2}, containing 38% carbon atoms with sp{sup 3} bonds, were found to be ??=?19.3?GPa and ??=?170?GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp{sup 3} bonds during the deposition processes.

Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung [Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, Hawaii 96822 (United States); Liu, Yongsheng [Science and Technology on Thermostructure Composite Materials Laboratory, Northwestern Polytechnical University, Xi'an Shanxi (China); Ciston, Jim [National Center for Electron Microscopy, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Hong, Shiming [Laboratory of High Pressure Physics, Southwest Jiaotong University, Chengdu, Sichuan (China)

2014-10-07T23:59:59.000Z

438

The influence of surface interactions on the reversibility of ferri/ferrocyanide at boron-doped diamond thin-film electrodes  

SciTech Connect (OSTI)

The electrochemistry of four redox analytes [Fe(CN){sub 6}{sup {minus}3/{minus}4}, Ru(NH{sub 3}){sub 6}{sup +2/+3}, IrCl{sub 6}{sup {minus}2/{minus}3}, and methyl viologen, MV{sup +2/+/0}] was investigated at polycrystalline, boron-doped diamond thin-film electrodes before and after anodic polarization and hydrogen plasma treatment. The as-deposited diamond surface is predominantly hydrogen treatment, and quasi-reversible cyclic voltammograms ({Delta}E{sub p} of 60--80 mV) were observed for all of these couples at 0.1 V/s. After anodic polarization in H{sub 2}SO{sub 4}, the surface atomic O/C ratio, as determined by X-ray photoelectron spectroscopy, increased from 0.02 to ca. 0.20. Concomitant with the increase in surface oxygen, the {Delta}E{sub p} for Fe(CN){sub 6}{sup {minus}3/{minus}4} increased to over 200 mV, while the {Delta}E{sub p} values for the other redox systems remained relatively unchanged. After acid washing and rehydrogenating the surface in hydrogen plasma (i.e., atomic hydrogen), the {Delta}E{sub p} for Fe(CN){sub 6}{sup {minus}3/{minus}4} returned to ca. 80 mV, while the {Delta}E{sub p} values for the other three redox analytes remained close to the original values. The results demonstrate the electron transfer for ferri/ferrocyanide is very sensitive to the presence of surface carbon-oxygen functionalities and that the electron transfer involves a site associated with the hydrogen-terminated surface. The results also unequivocally rule out the influence of adventitious nondiamond phases as the sole sites for the electron transfer.

Granger, M.C.; Swain, G.M.

1999-12-01T23:59:59.000Z

439

High-reliability passivation of hydrogen-terminated diamond surface by atomic layer deposition of Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

Although the two-dimensional hole gas (2DHG) of a hydrogen-terminated diamond surface provides a unique p-type conducting layer for high-performance transistors, the conductivity is highly sensitive to its environment. Therefore, the surface must be passivated to preserve the 2DHG, especially at high temperature. We passivated the surface at high temperature (450?°C) without the loss of C-H surface bonds by atomic layer deposition (ALD) and investigated the thermal reliability of the Al{sub 2}O{sub 3} film. As a result, C-H bonds were preserved, and the hole accumulation effect appeared after the Al{sub 2}O{sub 3} deposition by ALD with H{sub 2}O as an oxidant. The sheet resistivity and hole density were almost constant between room temperature and 500?°C by the passivation with thick Al{sub 2}O{sub 3} film thicker than 38?nm deposited by ALD at 450?°C. After the annealing at 550?°C in air The sheet resistivity and hole density were preserved. These results indicate the possibility of high-temperature application of the C-H surface diamond device in air. In the case of lower deposition temperatures, the sheet resistivity increased after air annealing, suggesting an insufficient protection capability of these films. Given the result of sheet resistivity after annealing, the increase in the sheet resistivity of these samples was not greatly significant. However, bubble like patterns were observed in the Al{sub 2}O{sub 3} films formed from 200 to 400?°C by air annealing at 550?°C for 1 h. On the other hand, the patterns were no longer observed at 450?°C deposition. Thus, this 450?°C deposition is the sole solution to enabling power device application, which requires high reliability at high temperatures.

Daicho, Akira, E-mail: notevayas-tales@ruri.waseda.jp; Saito, Tatsuya; Kurihara, Shinichiro; Kawarada, Hiroshi, E-mail: kawarada@waseda.jp [School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Hiraiwa, Atsushi [Institute for Nanoscience and Nanotechnology, Waseda University, 513 Waseda-tsurumaki, Shinjuku, Tokyo 162-0041 (Japan)

2014-06-14T23:59:59.000Z

440

Effect of H2 and O2 plasma etching treatment on the surface of diamond-like carbon thin film  

E-Print Network [OSTI]

characteristics such as extremely high hardness, low friction coefficients, chemical inertness, wear resistance-modified DLC thin films improved biocompatibility, lubricity, stability and cell adhesion [8 of approximately 100 nm and were compared with an as-deposited DLC film. We obtained the optimum condition through

Hong, Byungyou

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

Redey, L.I.; Vissers, D.R.; Prakash, J.

1994-02-01T23:59:59.000Z

442

Automated high pressure cell for pressure jump x-ray diffraction  

SciTech Connect (OSTI)

A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M. [Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Terrill, Nick J. [Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom); Rogers, Sarah E. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)

2010-06-15T23:59:59.000Z

443

Electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

Redey, L.I.; Vissers, D.R.; Prakash, J.

1994-08-23T23:59:59.000Z

444

Electrochemical cell  

DOE Patents [OSTI]

An improved secondary electrochemical cell is disclosed having a negative electrode of lithium aluminum, a positive electrode of iron sulfide, a molten electrolyte of lithium chloride and potassium chloride, and the combination that the fully charged theoretical capacity of the negative electrode is in the range of 0.5-1.0 that of the positive electrode. The cell thus is negative electrode limiting during discharge cycling. Preferably, the negative electrode contains therein, in the approximate range of 1-10 volume % of the electrode, an additive from the materials of graphitized carbon, aluminum-iron alloy, and/or magnesium oxide.

Kaun, Thomas D. (New Lenox, IL)

1984-01-01T23:59:59.000Z

445

Radiological characterization survey of the former Diamond Magnesium Company Company site, 720 Fairport-Nursery Road, Painesville, Ohio (DMP001, DMP002)  

SciTech Connect (OSTI)

At the request of the US Department of Energy (DOE), a group from Oak Ridge National Laboratory performed an investigative radiological survey at the former Diamond Magnesium Company (DMC) site at 720 Fairport-Nursery Road, Painesville, Ohio, in September 1990. The purpose of the survey was to determine if the site is contaminated with radioactive residues as a result of federal government operation in the development of nuclear energy for defense-related projects. The survey of the site, separate parcels of which are currently owned by the Uniroyal Chemical Company (DMP001) and the Lonza Chemical Company (DMP002), included a gamma scan over the ground surface, determination of gamma exposure rates at the surface and at 1 m above the surface at grid points, collection and radionuclide analysis of soil samples, and directly measured radiation levels inside three buildings used during original DMC processing. Results of the survey revealed widespread radiological contamination outdoors on the Uniroyal property and several isolated spots of elevated radiation levels on the Lonza property. The contaminants consisted of radium, uranium, and thorium in surface and subsurface soil in concentrations exceeding DOE guidelines for the release of property for unrestricted use.

Foley, R.D.; Carrier, R.F.

1991-12-01T23:59:59.000Z

446

Gold nanoparticle formation in diamond-like carbon using two different methods: Gold ion implantation and co-deposition of gold and carbon  

SciTech Connect (OSTI)

We describe work in which gold nanoparticles were formed in diamond-like carbon (DLC), thereby generating a Au-DLC nanocomposite. A high-quality, hydrogen-free DLC thin film was formed by filtered vacuum arc plasma deposition, into which gold nanoparticles were introduced using two different methods. The first method was gold ion implantation into the DLC film at a number of decreasing ion energies, distributing the gold over a controllable depth range within the DLC. The second method was co-deposition of gold and carbon, using two separate vacuum arc plasma guns with suitably interleaved repetitive pulsing. Transmission electron microscope images show that the size of the gold nanoparticles obtained by ion implantation is 3-5 nm. For the Au-DLC composite obtained by co-deposition, there were two different nanoparticle sizes, most about 2 nm with some 6-7 nm. Raman spectroscopy indicates that the implanted sample contains a smaller fraction of sp{sup 3} bonding for the DLC, demonstrating that some sp{sup 3} bonds are destroyed by the gold implantation.

Salvadori, M. C.; Teixeira, F. S.; Araujo, W. W. R.; Sgubin, L. G.; Cattani, M. [Institute of Physics, University of Sao Paulo, CP 66318, CEP 05315-970 Sao Paulo, SP (Brazil); Spirin, R. E. [Polytechnic School, University of Sao Paulo, CEP 05508-900 Sao Paulo (Brazil); Brown, I. G. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2012-10-01T23:59:59.000Z

447

Photovoltaic cell  

DOE Patents [OSTI]

In a photovoltaic cell structure containing a visibly transparent, electrically conductive first layer of metal oxide, and a light-absorbing semiconductive photovoltaic second layer, the improvement comprising a thin layer of transition metal nitride, carbide or boride interposed between said first and second layers.

Gordon, Roy G. (Cambridge, MA); Kurtz, Sarah (Somerville, MA)

1984-11-27T23:59:59.000Z

448

Nanocrystal Solar Cells  

E-Print Network [OSTI]

research on organic photovoltaic cells since small molecule10 years prior (4). Photovoltaic cells with an active layerof the associated photovoltaic cells. 2.4 Charge transport

Gur, Ilan

2006-01-01T23:59:59.000Z

449

Nanocrystal Solar Cells  

E-Print Network [OSTI]

Nov, 2005). Chapter 4 Hybrid solar cells with 3-dimensionalinorganic nanocrystal solar cells 5.1 Introduction In recentoperation of organic based solar cells and distinguish them

Gur, Ilan

2006-01-01T23:59:59.000Z

450

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Research Institute 1990 Fuel Cell Status," Proceedings ofMiller, "Introduction: Fuel-Cell-Powered Vehicle DevelopmentPrograms," presented at Fuel Cells for Transportation,

Delucchi, Mark

1992-01-01T23:59:59.000Z

451

Diagnostic Studies on Lithium Battery Cells and Cell Components...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Studies on Lithium Battery Cells and Cell Components Diagnostic Studies on Lithium Battery Cells and Cell Components 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

452

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Broader source: Energy.gov (indexed) [DOE]

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November...

453

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Presentation covers stationary fuel cells...

454

Electrochemistry Cell Model  

Broader source: Energy.gov (indexed) [DOE]

or exceeds all performance goals - Interpreting complex cell electrochemical phenomena - Identification of cell degradation mechanisms Partners (Collaborators) Daniel Abraham,...

455

Telecommunications International Cell Phone  

E-Print Network [OSTI]

Telecommunications International Cell Phone 1. Fax completed form to 979.847.1111. 2. If you do will be charged. Date Cell Phone Needed Cell Phone Pick-Up Date Cell Phone User Travel Destination(s) United States Number Destination Country Number Cell Phone Type Digital Satellite Cell Phone Return Date Notes

456

Rabi Wave Packets and Peculiarities of Raman Scattering in Carbon Nanotubes, Produced by High Energy Ion Beam Modification of Diamond Single Crystals  

E-Print Network [OSTI]

QED-model for multichain coupled qubit system, proposed in \\cite{Part1}, was confirmed by Raman scattering studies of quasi-1D carbon zigzag-shaped nanotubes (CZSNTs), produced by high energy ion beam modification of natural diamond single crystals. Multichain coupled qubit system represents itself Su-Schriffer-Heeger $\\sigma$-polaron lattice, formed in CZSNTs plus quantized external electromagnetic (EM) field. New quantum optics phenomenon - Rabi waves, predicted in \\cite{Slepyan_Yerchak} has experimentally been identified for the first time. It is shown, that Raman spectra in quasi-1D CZSNTs are quite different in comparison with well known Raman spectra in 2D those ones. They characterized by semiclassical consideration by the only one vibronic mode of Su-Schriffer-Heeger $\\sigma$-polaron lattice instead of longitudinal and transverse optical phonon $G^+$ and $G^-$modes and the out-of-plane radial breathing mode, which are observed in Raman spectra of 2D single wall nanotubes. It is consequence of 2D - 1D transition in all physical properties of nanotubes. It is shown, that strong electron-photon coupling takes place in CZSNTs by interaction with EM-field and quantum nature of EM-field has to be taken into account. It has been done for the first time in stationary spectroscopy at all. All optical spectra, in particular, Raman spectra are registered by usual stationary measurement technique in nonequilibrium conditions, which are the consequence of Rabi wave packets' formation. It leads in its turn to appearance of additional lines, corresponding to revival part of inversion dependence of joint EM-field + matter system in frequency representation.

Dmitry Yearchuck; Alla Dovlatova

2011-05-26T23:59:59.000Z

457

Near-Edge X-ray Absorption Fine Structure Imaging of Spherical and Flat Counterfaces of Ultrananocrystalline Diamond Tribological Contacts: A Correlation of Surface Chemistry and Friction  

SciTech Connect (OSTI)

A recently installed synchrotron radiation near-edge X-ray absorption fine structure (NEXAFS) full field imaging electron spectrometer was used to spatially resolve the chemical changes of both counterfaces from an ultra-nanocrystalline diamond (UNCD) tribological contact. A silicon flat and Si{sub 3}N{sub 4} sphere were both coated with UNCD, and employed to form two wear tracks on the flat in a linear reciprocating tribometer. The first wear track was produced using a new, unconditioned sphere whose surface was thus conditioned during this first experiment. This led to faster run-in and lower friction when producing a second wear track using the conditioned sphere. The large depth of field of the magnetically guided NEXAFS imaging detector enabled rapid, large area spectromicroscopic imaging of both the spherical and flat surfaces. Laterally resolved NEXAFS data from the tribological contact area revealed that both substrates had an as-grown surface layer that contained a higher fraction of sp{sup 2}-bonded carbon and oxygen which was mechanically removed. Unlike the flat, the film on the sphere showed evidence of having graphitic character, both before and after sliding. These results show that the graphitic character of the sphere is not solely responsible for low friction and short run-in. Rather, conditioning the sphere, likely by removing asperities and passivating dangling bonds, leads to lower friction with less chemical modification of the substrate in subsequent tests. The new NEXAFS imaging spectroscopy detector enabled a more complete understanding of the tribological phenomena by imaging, for the first time, the surface chemistry of the spherical counterface which had been in continual contact during wear track formation.

A Konicek; C Jaye; M Hamilton; W Sawyer; D Fischer; R Carpick

2011-12-31T23:59:59.000Z

458

Photoelectrochemical cell  

DOE Patents [OSTI]

A photoelectrochemical cell comprising a sealed container having a light-transmitting window for admitting light into the container across a light-admitting plane, an electrolyte in the container, a photoelectrode in the container having a light-absorbing surface arranged to receive light from the window and in contact with the electrolyte, the surface having a plurality of spaced portions oblique to the plane, each portion having dimensions at least an order of magnitude larger than the maximum wavelength of incident sunlight, the total surface area of the surface being larger than the area of the plane bounded by the container, and a counter electrode in the container in contact with the electrolyte.

Rauh, R. David (Newton, MA); Boudreau, Robert A. (Norton, MA)

1983-06-14T23:59:59.000Z

459

Validation of Model Simulations of Anvil Cirrus Properties During TWP-ICE: Final Report  

SciTech Connect (OSTI)

This 3-year grant, with two extensions, resulted in a successful 5-year effort, led by Ph.D. student Adam Varble, to compare cloud resolving model (CRM) simulations with the excellent database obtained during the TWP-ICE field campaign. The objective, largely achieved, is to undertake these comparisons comprehensively and quantitatively, informing the community in ways that goes beyond pointing out errors in the models, but points out ways to improve both cloud dynamics and microphysics parameterizations in future modeling efforts. Under DOE support, Adam Varble, with considerable assistance from Dr. Ann Fridlind and others, entrained scientists who ran some 10 different CRMs and 4 different limited area models (LAMs) using a variety of microphysics parameterizations, to ensure that the conclusions of the study will have considerable generality.

Zipser, Edward J. [University of Utah] [University of Utah

2013-05-20T23:59:59.000Z

460

Aircraft Microphysical Documentation from Cloud Base to Anvils of Hailstorm Feeder Clouds in Argentina  

E-Print Network [OSTI]

in Argentina DANIEL ROSENFELD The Hebrew University of Jerusalem, Jerusalem, Israel WILLIAM L. WOODLEY Woodley, Argentina, with a cloud-physics jet aircraft penetrating the major feeder clouds from cloud base to the 45°C. Introduction The province of Mendoza in western Argentina (32°S, 68°W), which is known worldwide for its wine

Daniel, Rosenfeld

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - anvil project Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

P. Akwara, "Trends in Sexual and Fertility-Related Behavior: Cameroon, Kenya, Uganda, Zambia, Summary: , Uganda, Zambia, and Thailand" (The Measure Evaluation Project,...

462

High-pressure behavior of amorphous selenium from ultrasonic measurements and Raman spectroscopy  

SciTech Connect (OSTI)

The high-pressure behavior of melt-quenched amorphous selenium (a-Se) has been investigated via ultrasonic measurements and Raman scattering at room temperature. The ultrasonic measurements were conducted on a-Se in a multi-anvil apparatus with two different sample assemblies at pressures of up to 4.5 and 4.8?GPa. We discovered that similar kinks occur in the slopes of the pressure dependence characteristics of the travel time and the sound velocity in both shear and longitudinal waves in the 2.0–2.5?GPa range. These kinks are independent of the sample assemblies, indicating an intrinsic transformation of the a-Se. Additionally, we deduced the pressure-volume relationship of a-Se from the sound velocity characteristics using the Birch–Murnaghan equation of state, and the results agreed well with those of previous reports. In situ high-pressure Raman scattering measurements of a-Se were conducted in a diamond anvil cell with an 830?nm excitation line up to a pressure of 4.3?GPa. We found that the characteristic band of a-Se at ?250?cm{sup ?1} experienced a smooth shift to a lower frequency with pressure, but a sharp slope change in the band intensity versus pressure occurred near 2.5?GPa. The results of X-ray diffraction and differential scanning calorimetry measurements indicate that the samples remain in their amorphous states after decompression. Thus, we proposed that the abnormal compression behavior of a-Se in the 2.0–2.5?GPa range can be attributed to pressure-induced local atomic reconfiguration, implying an amorphous-amorphous transition of the elementary selenium.

He, Z.; Liu, X. R.; Hong, S. M., E-mail: hpswjtu@gmail.com, E-mail: smhong@home.swjtu.edu.cn [Laboratory of High Pressure Physics, Southwest Jiaotong University, Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Chengdu 610031 (China); Wang, Z. G. [National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, Chinese Academy of Engineering Physics, Mianyang 621900 (China); Zhu, H. Y. [State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012 (China); Peng, J. P. [School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 610031 (China)

2014-07-07T23:59:59.000Z

463

Probing the Electronic Structures of [Cmu(Mu-XR(2)]**N+ Diamond Cores As a Function of the Bridging X Atom (X = N Or P) And Charge (N=0, 1, 2)  

SciTech Connect (OSTI)

A series of dicopper diamond core complexes that can be isolated in three different oxidation states ([Cu{sub 2}({mu}-XR{sub 2})]{sup n+}, where n = 0, 1, 2 and X = N or P) is described. Of particular interest is the relative degree of oxidation of the respective copper centers and the bridging XR{sub 2} units, upon successive oxidations. These dicopper complexes feature terminal phosphine and either bridging amido or phosphido donors, and as such their metal-ligand bonds are highly covalent. Cu K-edge, Cu L-edge, and P K-edge spectroscopies, in combination with solid-state X-ray structures and DFT calculations, provides a complementary electronic structure picture for the entire set of complexes that tracks the involvement of a majority of ligand-based redox chemistry. The electronic structure picture that emerges for these inorganic dicopper diamond cores shares similarities with the Cu{sub 2}({mu}-SR){sub 2} Cu{sub A} sites of cytochrome c oxidases and nitrous oxide reductases.

Harkins, S.B.; Mankad, N.P.; Miller, A.J.M.; Szilagyi, R.K.; Peters, J.C.

2009-05-18T23:59:59.000Z

464

Fuel cell arrangement  

DOE Patents [OSTI]

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber. 3 figs.

Isenberg, A.O.

1987-05-12T23:59:59.000Z

465

Fuel cell arrangement  

DOE Patents [OSTI]

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1987-05-12T23:59:59.000Z

466

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's...

467

DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 This program record from the...

468

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by...

469

Fuel cell-fuel cell hybrid system  

DOE Patents [OSTI]

A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

Geisbrecht, Rodney A.; Williams, Mark C.

2003-09-23T23:59:59.000Z

470

The nonlinear anomalous lattice elasticity associated with the high-pressure phase transition in spodumene: A high precission static compression study  

E-Print Network [OSTI]

The high-pressure behavior of the lattice elasticity of spodumene, LiAlSi2O6, was studied by static compression in a diamond-anvil cell up to 9.3 GPa. Investigations by means of single-crystal XRD and Raman spectroscopy within the hydrostatic limits of the pressure medium focus on the pressure ranges around similar to 3.2 and similar to 7.7 GPa, which have been reported previously to comprise two independent structural phase transitions. While our measurements confirm the well-established first-order C2/c-P2(1)/c transformation at 3.19 GPa (with 1.2% volume discontinuity and a hysteresis between 0.02 and 0.06 GPa), both unit-cell dimensions and the spectral changes observed in high-pressure Raman spectra give no evidence for structural changes related to a second phase transition. Monoclinic lattice parameters and unit-cell volumes at in total 59 different pressure points have been used to re-calculate the lattice-related properties of spontaneous strain, volume strain, and the bulk moduli as a function of pr...

Ullrich, A; Miletich, R; 10.1007/s00269-009-0300-8

2010-01-01T23:59:59.000Z

471

Nanocrystal Solar Cells  

E-Print Network [OSTI]

Nov, 2005). Chapter 4 Hybrid solar cells with 3-dimensional5 All-inorganic nanocrystal solar cells 5.1 Introduction Inoperation of organic based solar cells and distinguish them

Gur, Ilan

2006-01-01T23:59:59.000Z

472

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

the membrane for a PEM fuel cell would cost $5/ft (1990$) inmass-produced PEM fuel cell could cost $10/kW or less. Totalparameter for PEM fuel cells: thinner membranes cost less

Delucchi, Mark

1992-01-01T23:59:59.000Z

473

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

$ b materials cost, % a Fuel cell stack cost only. Includesof the cost of fuel-cell stacks, 1990$° Cost item GE Swan cAnnual maintenance cost of fuel cell stack and auxiliaries (

Delucchi, Mark

1992-01-01T23:59:59.000Z

474

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would becost than both. Solar-hydrogen fuel- cell vehicles would be

Delucchi, Mark

1992-01-01T23:59:59.000Z

475

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September byet al. , 1988,1989 HYDROGEN FUEL-CELL VEHICLES: TECHNICALIn the FCEV, the hydrogen fuel cell could supply the "net"

Delucchi, Mark

1992-01-01T23:59:59.000Z

476

Thermal Management of Solar Cells  

E-Print Network [OSTI]

D. Mills, "Cooling of photovoltaic cells under concentratedelectric performance of a photovoltaic cells by cooling andSolar Cell A photovoltaic cell is a semiconductor that

Saadah, Mohammed Ahmed

2013-01-01T23:59:59.000Z

477

SFTEL: Flow Cell | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flow Cell EMSL's Subsurface Flow and Transport Experimental Laboratory offers several meter-scale flow cells and columns for research in saturated and unsaturated porous media....

478

Photovoltaic Cell Structure Basics  

Broader source: Energy.gov [DOE]

The actual structural design of a photovoltaic (PV), or solar cell, depends on the limitations of the material used in the PV cell.

479

Microfluidic fuel cells.  

E-Print Network [OSTI]

??Microfluidic fuel cell architectures are presented in this thesis. This work represents the mechanical and microfluidic portion of a microfluidic biofuel cell project. While the… (more)

Kjeang, Erik

2007-01-01T23:59:59.000Z

480

POLYMER ELECTROLYTE FUEL CELLS  

E-Print Network [OSTI]

POLYMER ELECTROLYTE FUEL CELLS: The Gas Diffusion Layer Johannah Itescu Princeton University PRISM REU #12;PEM FUEL CELLS: A little background information I. What do fuel cells do? Generate electricity through chemical reaction #12;PEM FUEL CELLS: A little background information -+ + eHH 442 2 0244 22 He

Petta, Jason

Note: This page contains sample records for the topic "diamond anvil cell" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Thermal Management of Solar Cells  

E-Print Network [OSTI]

cells by cooling and concentration techniques," inheat. Different techniques of cooling solar cells have been

Saadah, Mohammed Ahmed

2013-01-01T23:59:59.000Z

482

David Jardini President, Black Diamond  

E-Print Network [OSTI]

President, Guttman Energy, Inc. Gene Harris Principal, Harris Consulting Ex Officio Marc S. Malandro, Ph.entrepreneur.pitt.edu The Institute for Entrepreneurial Excellence Advisory Board With statistics like these, it is no surprise in new funding obtained for client company growth million in increased revenue reported by client

Benos, Panayiotis "Takis"

483

Diamond-free Degree Sequences  

E-Print Network [OSTI]

Miller,A. Prosser,P. DCS Technical Report Series pp 1 to 9 Dept of Computing Science, University of Glasgow

Miller, A.

484

Recreating the Strength of Diamonds  

E-Print Network [OSTI]

· supercomputer Global Venture Challenge marks second-· year success SNS in Guinness Book of World Records· e d i endeavors of his era was accomplished under some of the most extreme conditions found on Earth. Unlike an appreciation for the extreme conditions, and because he prepared carefully. Nearly a century later

485

Diffraction studies of order?disorder at high pressures and temperatures  

SciTech Connect (OSTI)

Recent developments at synchrotron X-ray beamlines now allow collection of data suitable for structure determination and Rietveld structure refinement at high pressures and temperatures on challenging materials. These include materials, such as dolomite (CaMg(CO{sub 3}){sub 2}) that tends to calcine at high temperatures, and Fe-containing materials, such as the spinel MgFe{sub 2}O{sub 4}, which tend to undergo changes in oxidation state. Careful consideration of encapsulation along with the use of radial collimation produced powder diffraction patterns virtually free of parasitic scattering from the cell in the case of large volume high-pressure experiments. These features have been used to study a number of phase transitions, especially those where superior signal-to-noise discrimination is required to distinguish weak ordering reflections. The structures adopted by dolomite, and CaSO4, anhydrite, were determined from 298 to 1466 K at high pressures. Using laser-heated diamond-anvil cells to achieve simultaneous high pressure and temperature conditions, we have observed CaSO{sub 4} undergo phase transitions to the monazite type and at highest pressure and temperature to crystallize in the barite-type structure. On cooling, the barite structure distorts, from an orthorhombic to a monoclinic lattice, to produce the AgMnO{sub 4}-type structure.

Parise, John B.; Antao, Sytle M.; Martin, Charles D.; Crichton, Wilson (SBU); (ESRF)

2008-06-18T23:59:59.000Z

486

Micro Fuel Cells Direct Methanol Fuel Cells  

E-Print Network [OSTI]

energy density of 1.5 Wh/cc; 1.5Wh/g = X5; x10 energy density of Li ion battery * Direct & complete Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Micro Fuel Cells TM State of MTI Micro Fuel Cells Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

487

Cell Stem Cell Highly Efficient Reprogramming  

E-Print Network [OSTI]

Alexander Meissner,4,5,14 George Q. Daley,2,3,4,5,8,15,16 Andrew S. Brack,5,6 James J. Collins,11,12,15 Chad Children's Hospital Boston, Boston, MA 02115, USA 4Department of Stem Cell and Regenerative Biology 5Harvard Stem Cell Institute Harvard University, Cambridge, MA 02138, USA 6Center of Regenerative Medicine

Collins, James J.

488

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...  

Energy Savers [EERE]

Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by Sunita Satyapal at the 2010 Fuel...

489

Cell-cell and cell-medium interactions in the growth of mouse embryonic stem cells  

E-Print Network [OSTI]

Embryonic stem cells serve as powerful models for the study of development and disease and hold enormous potential for future therapeutics. Due to the potential for embryonic stem cells (ESCs) to provide a variety of tissues ...

Mittal, Nikhil, 1979-

2010-01-01T23:59:59.000Z

490

Photovoltaic Cell Performance Basics  

Broader source: Energy.gov [DOE]

Photovoltaic (PV), or solar cells use the energy in sunlight to produce electricity. However, the amount of electricity produced depends on the quality of the light available and the performance of the PV cell.

491

fuel cells | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fuel cells fuel cells Leads No leads are available at this time. The Molecular Bond: October 2014 The Molecular Bond newsletter banner October 2014 FROM THE DIRECTOR Read more...

492

NANOCOMPOSITE ENABLED SENSITIZED SOLAR CELL  

E-Print Network [OSTI]

by Dye-Sensitized Photovoltaic cells. Inorganic Chemistry,by Dye-Sensitized Photovoltaic Cells. Inorganic ChemistryThe characteristics of a photovoltaic cell. Generally,

Phuyal, Dibya

2012-01-01T23:59:59.000Z

493

Hybrid direct methanol fuel cells.  

E-Print Network [OSTI]

??A new type of fuel cell that combines the advantages of a proton exchange membrane fuel cells and anion exchange membrane fuel cells operated with… (more)

Joseph, Krishna Sathyamurthy

2012-01-01T23:59:59.000Z

494

NANOCOMPOSITE ENABLED SENSITIZED SOLAR CELL  

E-Print Network [OSTI]

efficiency in dye-sensitized solar cells based on Tio2Conversion by Dye-Sensitized Photovoltaic cells. InorganicConversion by Dye-Sensitized Photovoltaic Cells. Inorganic

Phuyal, Dibya

2012-01-01T23:59:59.000Z

495

Electroluminescence in photovoltaic cell  

E-Print Network [OSTI]

Here we propose two methods to get electroluminescence images from photovoltaic cells in a school or home lab.

Petraglia, Antonio; 10.1088/0031-9120/46/5/F01

2011-01-01T23:59:59.000Z

496

Webinar: Fuel Cell Buses  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled, Fuel Cell Buses, originally presented on September 12, 2013.

497

Biomarkers of cell senescence  

DOE Patents [OSTI]

The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, {beta}-galactosidase activity is utilized as a means by which cell senescence may be assessed either in in vitro cell cultures or in vivo. 1 fig.

Dirmi, G.P.; Campisi, J.; Peacocke, M.

1996-02-13T23:59:59.000Z

498

Biomarkers of cell senescence  

DOE Patents [OSTI]

The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, {beta}-galactosidase activity is utilized as a means by which cell senescence may be assessed either in vitro cell cultures or in vivo. 1 fig.

Dimri, G.P.; Campisi, J.; Peacocke, M.

1998-08-18T23:59:59.000Z

499

FUEL CELLS FOR TRANSPORTATION  

E-Print Network [OSTI]

................................................................................................... 34 E. Cost Analyses of Fuel Cell Stacks/Systems ­ Arthur D. Little, Inc. ......................................... 40 F. DFMA Cost Estimates of Fuel-Cell/Reformer Systems at Low/Medium/High Production Rates&D of a Novel Breadboard Device Suitable for Carbon Monoxide Remediation in an Automotive PEM Fuel Cell Power

500

Rapidly refuelable fuel cell  

DOE Patents [OSTI]

This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

Joy, Richard W. (Santa Clara, CA)

1983-01-01T23:59:59.000Z