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Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Low band gap polymers Organic Photovoltaics  

E-Print Network [OSTI]

Low band gap polymers for Organic Photovoltaics Eva Bundgaard Ph.D. Dissertation Risř National Bundgaard Title: Low band gap polymers for Organic photovoltaics Department: The polymer department Report the area of organic photovoltaics are focusing on low band gap polymers, a type of polymer which absorbs

2

Megahertz organic/polymer diodes  

DOE Patents [OSTI]

Featured is an organic/polymer diode having a first layer composed essentially of one of an organic semiconductor material or a polymeric semiconductor material and a second layer formed on the first layer and being electrically coupled to the first layer such that current flows through the layers in one direction when a voltage is applied in one direction. The second layer is essentially composed of a material whose characteristics and properties are such that when formed on the first layer, the diode is capable of high frequency rectifications on the order of megahertz rectifications such as for example rectifications at one of above 100KHz, 500KhZ, IMHz, or 10 MHz. In further embodiments, the layers are arranged so as to be exposed to atmosphere.

Katz, Howard Edan; Sun, Jia; Pal, Nath Bhola

2012-12-11T23:59:59.000Z

3

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

properties for organic photovoltaics (OPVs). Space-chargePolymers for Organic Photovoltaics By David Fredric JoelPolymers for Organic Photovoltaics by David Fredric Joel

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

4

The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells  

E-Print Network [OSTI]

of High Efficiency Polymer Photovoltaics…………………7 Futureof High Efficiency Polymer Photovoltaics Although the Tangthe Efficiency of Organic Photovoltaics……………..7 Development

Armstrong, Paul Barber

2010-01-01T23:59:59.000Z

5

Electroluminescence in ion gel gated organic polymer semiconductor transistors  

E-Print Network [OSTI]

This thesis reports the light emission in ion gel gated, thin film organic semiconductor transistors and investigates the light emission mechanism behind these devices. We report that ion gel gated organic polymer semiconductor transistors emit...

Bhat, Shrivalli

2011-07-12T23:59:59.000Z

6

The challenges of organic polymer solar cells  

E-Print Network [OSTI]

The technical and commercial prospects of polymer solar cells were evaluated. Polymer solar cells are an attractive approach to fabricate and deploy roll-to-roll processed solar cells that are reasonably efficient (total ...

Saif Addin, Burhan K. (Burhan Khalid)

2011-01-01T23:59:59.000Z

7

Inorganic Metal Oxide/Organic Polymer Nanocomposites And Method Thereof  

DOE Patents [OSTI]

A synthetic method for preparation of hybrid inorganic/organic energetic nanocomposites is disclosed herein. The method employs the use of stable metal in organic salts and organic solvents as well as an organic polymer with good solubility in the solvent system to produce novel nanocomposite energetic materials. In addition, fuel metal powders (particularly those that are oxophilic) can be incorporated into composition. This material has been characterized by thermal methods, energy-filtered transmission electron microscopy (EFTEM), N.sub.2 adsoprtion/desorption methods, and Fourier-Transform (FT-IR) spectroscopy. According to these characterization methods the organic polymer phase fills the nanopores of the material, providing superb mixing of the component phases in the energetic nanocomposite.

Gash, Alexander E. (Livermore, CA); Satcher, Joe H. (Patterson, CA); Simpson, Randy (Livermore, CA)

2004-11-16T23:59:59.000Z

8

Inorganic metal oxide/organic polymer nanocomposites and method thereof  

DOE Patents [OSTI]

A synthetic method for preparation of hybrid inorganic/organic energetic nanocomposites is disclosed herein. The method employs the use of stable metal inorganic salts and organic solvents as well as an organic polymer with good solubility in the solvent system to produce novel nanocomposite energetic materials. In addition, fuel metal powders (particularly those that are oxophillic) can be incorporated into composition. This material has been characterized by thermal methods, energy-filtered transmission electron microscopy (EFTEM), N.sub.2 adsoprtion/desorption methods, and Fourier-Transform (FT-IR) spectroscopy. According to these characterization methods the organic polymer phase fills the nanopores of the composite material, providing superb mixing of the component phases in the energetic nanocomposite.

Gash, Alexander E.; Satcher, Joe H.; Simpson, Randy

2004-03-30T23:59:59.000Z

9

The Organic Chemistry of Conducting Polymers  

SciTech Connect (OSTI)

For the last several years, we have examined the fundamental principles of conduction in one-dimensional systems, i.e., molecular “wires”. It is, of course, widely recognized that such systems, as components of electronically conductive materials, function in a two- and three-dimensional milieu. Thus interchain hopping and grain-boundary resistivity are limiting conductivity factors in highly conductive materials, and overall conductivity is a function of through-chain and boundary hopping. We have given considerable attention to the basic principles underlying charge transport (the “rules of the game”) in two-dimensional systems by using model systems which allow direct observation of such processes, including the examination of tunneling and hopping as components of charge transfer. In related work, we have spent considerable effort on the chemistry of conjugated heteropolymers, most especially polythiophens, with the aim of using these most efficient of readily available electroactive polymers in photovoltaic devices.

Tolbert, Laren Malcolm [Georgia Institute of Technology

2014-12-01T23:59:59.000Z

10

Polybiphenylmethylenes: New Polymers for Bistable Organic Switches  

E-Print Network [OSTI]

architectures that can be used to fabricate high density storage elements ­ so called organic electronically to the referenced protocol. 2,2-Bis(4- trifluoromethanesulfonyloxyphenyl)propane (2a), 7,8 2,2-bis(4

Carter, Kenneth

11

Highly dispersed carbon nanotubes in organic media for polymer:fullerene photovoltaic devices  

E-Print Network [OSTI]

Highly dispersed carbon nanotubes in organic media for polymer:fullerene photovoltaic devices Gwang photovoltaic device are fabricated using homogeneously dispersed carbon nanotubes (CNTs) in a polymer. All rights reserved. 1. Introduction Organic photovoltaic (OPV) materials promise the production

Hong, Soon Hyung

12

Oxidative chemical vapor deposition of semiconducting polymers and their use In organic photovoltaics  

E-Print Network [OSTI]

Organic photovoltaics (OPVs) have received significant interest for their potential low cost, high mechanical flexibility, and unique functionalities. OPVs employing semiconducting polymers in the photoactive layer have ...

Borrelli, David Christopher

2014-01-01T23:59:59.000Z

13

The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells  

E-Print Network [OSTI]

J. The physics of solar cells; Imperial College Press,for organic polymer solar cells investigated to date. Thebulk heterojunction organic solar cells, blends of a p-type

Armstrong, Paul Barber

2010-01-01T23:59:59.000Z

14

A dual approach to tuning the porosity of porous organic polymers: controlling the porogen size and  

E-Print Network [OSTI]

. Consequently, the majority of POPs are interpenetrating networks with rela- tively low total pore volumesA dual approach to tuning the porosity of porous organic polymers: controlling the porogen size. Weston, Omar K. Farha,* Joseph T. Hupp* and SonBinh T. Nguyen* Porous organic polymers (POPs

15

SIMULATION OF GEOMETRY AND SHADOW EFFECTS IN 3D ORGANIC POLYMER SOLAR CELLS  

E-Print Network [OSTI]

levels of Solar panels and new production capacity is driving solar PV prices lower and thereby, bringingSIMULATION OF GEOMETRY AND SHADOW EFFECTS IN 3D ORGANIC POLYMER SOLAR CELLS OF THE THESIS Simulation of Geometry and Shadow Effects in 3D Organic Polymer Solar Cells by Mihir Prakashbhai

Kassegne, Samuel Kinde

16

Chemical anchoring of organic conducting polymers to semiconducting surfaces  

DOE Patents [OSTI]

According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge-conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge-conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

Frank, Arthur J. (Lakewood, CO); Honda, Kenji (Wheatridge, CO)

1984-01-01T23:59:59.000Z

17

Chemical anchoring of organic conducting polymers to semiconducting surfaces  

DOE Patents [OSTI]

According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

Frank, A.J.; Honda, K.

1984-01-01T23:59:59.000Z

18

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

organic photovoltaics (OPVs), with reported efficiencies asseparation efficiency in organic photovoltaics. 15CI, a

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

19

Fundamental Studies on Polymer and Organic-Inorganic Hybrid Nanoparticles Reinforced Silica Aerogels.  

E-Print Network [OSTI]

??The objective of this research was to reinforce silica aerogels using functional organic-inorganic hybrid nanoparticles, silane end-capped polyurethane oligomer and chain extended polymer, and self-crosslinkable… (more)

Duan, Yannan

2012-01-01T23:59:59.000Z

20

The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells  

E-Print Network [OSTI]

of solid-state dye sensitized cells have previously beenon organic polymer and dye-sensitized cells. The detailedof a Typical Dye-Sensitized Cell……12 Design of Dyes for Dye-

Armstrong, Paul Barber

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Designing phase selective soluble polymers for applications in organic chemistry  

E-Print Network [OSTI]

. The work described in the succeeding chapters describes my efforts to synthesize new catalysts that can be attached to polymer supports, to study their catalytic activity and to study separation efficiency. Most of the work focus is on polyacrylamide...

Li, Chunmei

2004-09-30T23:59:59.000Z

22

Thiophene Based Donor/Acceptor Conjugated Polymers for Organic Photovoltaics Brian Doyle, Rutgers University, SURF Fellow 2010  

E-Print Network [OSTI]

Thiophene Based Donor/Acceptor Conjugated Polymers for Organic Photovoltaics Brian structure. These organic photovoltaics have the advantages of large scale processing groups on electrochemical properties and application to organic photovoltaics. Synthesis

Li, Mo

23

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

in low-cost thin-film photovoltaic cells. Importantly, SubNcefficient organic photovoltaic cells with power conversionSubNc films in organic photovoltaic cells was evaluated in

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

24

NOCHAR Polymers: An Aqueous and Organic Liquid Solidification Process for Cadarache LOR (Liquides Organiques Radioactifs) - 13195  

SciTech Connect (OSTI)

To handle the Very Low Level Waste (VLLW) and the Low Level Waste (LLW) in France, two options can be considered: the incineration at CENTRACO facility and the disposal facility on ANDRA sites. The waste acceptance in these radwaste routes is dependent upon the adequacy between the waste characteristics (physical chemistry and radiological) and the radwaste route specifications. If the waste characteristics are incompatible with the radwaste route specifications (presence of significant quantities of chlorine, fluorine, organic component etc or/and high activity limits), it is necessary to find an alternative solution that consists of a waste pre-treatment process. In the context of the problematic Cadarache LOR (Liquides Organiques Radioactifs) waste streams, two radioactive scintillation cocktails have to be treated. The first one is composed of organic liquids at 13.1 % (diphenyloxazol, mesitylene, TBP, xylene) and water at 86.9 %. The second one is composed of TBP at 8.6 % and water at 91.4 %. They contain chlorine, fluorine and sulphate and have got alpha/beta/gamma spectra with mass activities equal to some kBq.g{sup -1}. Therefore, tritium is present and creates the second problematic waste stream. As a consequence, in order for disposal acceptance at the ANDRA site, it is necessary to pre-treat the waste. The NOCHAR polymers as an aqueous and organic liquid solidification process seem to be an adequate solution. Indeed, these polymers constitute an important variety of products applied to the treatment of radioactive aqueous and organic liquids (solvent, oil, solvent/oil mixing etc) and sludge through a mechanical and chemical solidification process. For Cadarache LOR, N910 and N960 respectively dedicated to the organic and aqueous liquids solidification are considered. With the N910, the organic waste solidification occurs in two steps. As the organic liquid travels moves through the polymer strands, the strands swell and immobilise the liquid. Then as the polymer-organic cure, over time, the polymer continues to collapse on the organic to create a permanent bond. The N960 has the ability to absorb aqueous waste up to 100 times its own weight. It creates a strong mechanical bond which permanently traps the contamination imbedded in the aqueous liquids. As a consequence, these two polymers seem to be able to constitute a suitable solidification matrix for a final acceptance in storage on ANDRA sites. In order to validate the polymers as an acceptable aqueous and organic solidification process for Cadarache LOR, some solidification tests realized with N910 and N960, have been carried out for different Waste/Polymer ratios. The determination of the best Waste/Polymer ratio and of the optimal experimental parameters has been made through an exudation test. Indeed, the process prevents leaching and it results in the absence of residual free organic or aqueous liquid which is forbidden in storage by ANDRA specifications. With these test results, we generated scientific data which are fundamental to obtain an ANDRA agreement. As a conclusion, the aim of this study is to demonstrate that the solidification by polymers can constitute a pre-treatment solution for Cadarache LOR and more generally, for various organic and mixed organic/aqueous waste which can not be directly acceptable at CENTRACO facility or at ANDRA storage sites. This work is, therefore, a solid background to demonstrate the feasibility of the waste pre-treatment by solidification with polymers and to encourage the development of this process. (authors)

Vaudey, Claire-Emilie; Renou, Sebastien; Porco, Julien [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France)] [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France); Kelley, Dennis [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States)] [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States); Cochaud, Chantal [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France)] [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France); Serrano, Roger [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)] [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)

2013-07-01T23:59:59.000Z

25

Solvent-enhanced dye diffusion in polymer thin films for color tuning of organic light-emitting diodes  

E-Print Network [OSTI]

Solvent-enhanced dye diffusion in polymer thin films for color tuning of organic light; accepted for publication 27 February 2001 A method of solvent-enhanced dye diffusion in polymer films for organic light-emitting diode OLED application is introduced. After an initial dye transfer from a dye

26

Highly efficient carbon dioxide capture with a porous organic polymer impregnated with  

E-Print Network [OSTI]

Highly efficient carbon dioxide capture with a porous organic polymer impregnated environmental crises such as global warming and ocean acidication, efficient carbon dioxide (CO2) capture As CO2 capture mate- rials, numerous solid adsorbents such as silica5 and carbon materials,6 metal

Paik Suh, Myunghyun

27

Imprinted large-scale high density polymer nanopillars for organic solar cells  

E-Print Network [OSTI]

Imprinted large-scale high density polymer nanopillars for organic solar cells Mukti Aryal used to make bulk heterojunction solar cells by depositing PCBM on top of the pillars. Imprinting provides a way to precisely control the interdigitized heterojunction morphology, leading to improved solar

Gao, Jinming

28

authors demonstrate that the new polymer is highly soluble in common organic solvents,  

E-Print Network [OSTI]

. & Thelakkat, M. Appl.Phys.Lett. 92, 093302/1 (2008). 10. Cantatore, E. etal. IEEEJ.SolidStateCircuits 42, 84authors demonstrate that the new polymer is highly soluble in common organic solvents stabil- ity. The new material will undoubtedly inspire further work to synthesize other donor­accep- tor

Nicchitta, Chris

29

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

power conversion efficiency (PCE) of an organic solar cellpower conversion efficiency (PCE or ?) at a given incident3.9%, 3.8%, and 3.8% peak PCE respectively at AM 1.5G with

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

30

Research on the electronic and optical properties of polymer and other organic molecular thin films  

SciTech Connect (OSTI)

The main goal of the work is to find materials and methods of optimization of organic layered electroluminescent cells and to study such properties of polymers and other organic materials that can be used in various opto-electronic devices. The summary of results obtained during the first year of work is presented. They are: (1) the possibility to produce electroluminescent cells using a vacuum deposition photoresist technology for commercial photoresists has been demonstrated; (2) the idea to replace the polyaryl polymers by other polymers with weaker hole conductivity for optimization of electroluminescent cells with ITO-Al electrodes has been suggested. The goal is to obtain amorphous processable thin films of radiative recombination layers in electroluminescent devices; (3) procedures of preparation of high-quality vacuum-deposited poly (p-phenylene) (PPP) films on various substrates have been developed; (4) it was found for the first time that the fluorescence intensity of PPP films depends on the degree of polymerization; (5) the role of interfaces between organic compounds, on one side, and metals or semiconductors, on the other side, has been studied and quenching of the fluorescence caused by semiconductor layer in thin sandwiches has been observed; (6) studies of the dynamics of photoexcitations revealed the exciton self-trapping in quasi-one-dimensional aggregates; and (7) conditions for preparation of highly crystalline fullerene C{sub 60} films by vacuum deposition have been found. Composites of C{sub 60} with conjugated polymers have been prepared.

NONE

1997-02-01T23:59:59.000Z

31

New N-Type Polymers for Organic Photovoltaics: Cooperative Research and Development Final Report, CRADA Number CRD-06-177  

SciTech Connect (OSTI)

This CRADA will develop improved thin film organic solar cells using a new n-type semiconducting polymer. High efficiency photovoltaics (PVs) based on inorganic semiconductors have good efficiencies (up to 30%) but are extremely expensive to manufacture. Organic PV technology has the potential to overcome this problem through the use of high-throughput production methods like reel-to-reel printing on flexible substrates. Unfortunately, today's best organic PVs have only a few percent efficiency, a number that is insufficient for virtually all commercial applications. The limited choice of stable n-type (acceptor) organic semiconductor materials is one of the key factors that prevent the further improvement of organic PVs. TDA Research, Inc. (TDA) previously developed a new class of electron-deficient (n-type) conjugated polymers for use in organic light emitting diodes (OLEDs). During this project TDA in collaboration with the National Renewable Energy Laboratory (NREL) will incorporate these electron-deficient polymers into organic photovoltaics and investigate their performance. TDA Research, Inc. (TDA) is developing new materials and polymers to improve the performance of organic solar cells. Materials being developed at TDA include spin coated transparent conductors, charge injection layers, fullerene derivatives, electron-deficient polymers, and three-phase (fullerene/polythiophene/dye) active layer inks.

Olson, D.

2014-08-01T23:59:59.000Z

32

Toward High-Performance Organic-Inorganic Hybrid Solar Cells: Bringing Conjugated Polymers and Inorganic Nanocrystals in Close  

E-Print Network [OSTI]

to traditional silicon solar cells due to the capacity of producing high- efficiency solar energy in a cost these advantages and progress, organic-inorganic hybrid solar cells still exhibit much lower PCEs (iToward High-Performance Organic-Inorganic Hybrid Solar Cells: Bringing Conjugated Polymers

Lin, Zhiqun

33

An electrocyclic strategy to poly(triarylmethyl radical) polymers: Potential organic ferromagnets  

SciTech Connect (OSTI)

Recent interest in organic ferromagnetism has been stimulated by the idea that large poly(triarylmethyl radical) polymers in which the radical centers are connected by [open quotes]meta[close quotes]-aryl groups may possess ferromagnetic properties. However, synthesis of these polyradicals has been limited by stepwise methods that are unsuitable for the preparation of large polymers. This limitation represents a primary challenge confronting the field. The authors have developed the first polymeric strategy to poly (m-triarylmethyl radical) precursors that involves an electrocyclic formation of the [open quotes]meta[close quotes]-substituted triarylmethyl chloride repeating unit from a polypropynol precursor. Poly[(E)-6-[beta]-chloroethenyl-1,3-phenylene-1-phenylpropynol-1,3-ylene] was prepared by palladium-catalyzed coupling of a bifunctional acetylene-aryl iodide monomer. The stable polymer reacted with thionyl chloride to form an unstable polychloroallene intermediate that underwent an electrocyclic conversion to the polyradical precursor, poly(1-chloro-2,7-naphthalenechlorobenzylidene). The reduced polyradicals exhibited properties of radical-radical coupling, and preparation of a second generation polymer that would overcome this problem has been initiated. The polymeric strategy was based on model studies that showed that (E)-3-(2-[beta]-chloroethenylphenyl)-1,1-diphenylpropynol, when converted to the corresponding chloroallene with thionyl chloride, underwent an electrocyclic conversion to [beta]-(1-chlornaphthyl)diphenylmethyl chloride. The strategy expanded upon the use of triarylpropynes as precursors to triarylmethyl chlorides, and extension of both approaches to higher analogs was demonstrated with dimeric systems. The electrocyclic processes were found to occur only for the trans-vinyl chlorides; the cis-isomers were found to undergo an alternative concerted cyclization to benzofluorene products.

Morelli, J.P.

1992-01-01T23:59:59.000Z

34

The conformational evolution of elongated polymer solutions tailors the polarization of light-emission from organic nanofibers  

E-Print Network [OSTI]

Polymer fibers are currently exploited in tremendously important technologies. Their innovative properties are mainly determined by the behavior of the polymer macromolecules under the elongation induced by external mechanical or electrostatic forces, characterizing the fiber drawing process. Although enhanced physical properties were observed in polymer fibers produced under strong stretching conditions, studies of the process-induced nanoscale organization of the polymer molecules are not available, and most of fiber properties are still obtained on an empirical basis. Here we reveal the orientational properties of semiflexible polymers in electrospun nanofibers, which allow the polarization properties of active fibers to be finely controlled. Modeling and simulations of the conformational evolution of the polymer chains during electrostatic elongation of semidilute solutions demonstrate that the molecules stretch almost fully within less than 1 mm from jet start, increasing polymer axial orientation at the jet center. The nanoscale mapping of the local dichroism of individual fibers by polarized near-field optical microscopy unveils for the first time the presence of an internal spatial variation of the molecular order, namely the presence of a core with axially aligned molecules and a sheath with almost radially oriented molecules. These results allow important and specific fiber properties to be manipulated and tailored, as here demonstrated for the polarization of emitted light.

Andrea Camposeo; Israel Greenfeld; Francesco Tantussi; Maria Moffa; Francesco Fuso; Maria Allegrini; Eyal Zussman; Dario Pisignano

2014-07-30T23:59:59.000Z

35

Analytical and Numerical Study of Photocurrent Transients in Organic Polymer Solar Cells  

E-Print Network [OSTI]

This article is an attempt to provide a self consistent picture, including existence analysis and numerical solution algorithms, of the mathematical problems arising from modeling photocurrent transients in Organic-polymer Solar Cells (OSCs). The mathematical model for OSCs consists of a system of nonlinear diffusion-reaction partial differential equations (PDEs) with electrostatic convection, coupled to a kinetic ordinary differential equation (ODE). We propose a suitable reformulation of the model that allows us to prove the existence of a solution in both stationary and transient conditions and to better highlight the role of exciton dynamics in determining the device turn-on time. For the numerical treatment of the problem, we carry out a temporal semi-discretization using an implicit adaptive method, and the resulting sequence of differential subproblems is linearized using the Newton-Raphson method with inexact evaluation of the Jacobian. Then, we use exponentially fitted finite elements for the spatial...

de Falco, Carlo; Verri, Maurizio; 10.1016/j.cma.2010.01.018

2012-01-01T23:59:59.000Z

36

Analytical and Numerical Study of Photocurrent Transients in Organic Polymer Solar Cells  

E-Print Network [OSTI]

This article is an attempt to provide a self consistent picture, including existence analysis and numerical solution algorithms, of the mathematical problems arising from modeling photocurrent transients in Organic-polymer Solar Cells (OSCs). The mathematical model for OSCs consists of a system of nonlinear diffusion-reaction partial differential equations (PDEs) with electrostatic convection, coupled to a kinetic ordinary differential equation (ODE). We propose a suitable reformulation of the model that allows us to prove the existence of a solution in both stationary and transient conditions and to better highlight the role of exciton dynamics in determining the device turn-on time. For the numerical treatment of the problem, we carry out a temporal semi-discretization using an implicit adaptive method, and the resulting sequence of differential subproblems is linearized using the Newton-Raphson method with inexact evaluation of the Jacobian. Then, we use exponentially fitted finite elements for the spatial discretization, and we carry out a thorough validation of the computational model by extensively investigating the impact of the model parameters on photocurrent transient times.

Carlo de Falco; Riccardo Sacco; Maurizio Verri

2012-06-27T23:59:59.000Z

37

Self-organized Nano-lens Arrays by Intensified Dewetting of Electron Beam Modified Polymer Thin-films  

E-Print Network [OSTI]

Sub-100 nm polymeric spherical plano-convex nano-lens arrays are fabricated using short electron beam exposures to selectively modify the ultrathin (nano-lenses. The intensified self-organized dewetting under a water-organic solvent mixture overcomes the limitations on surface tension and dewetting force and thus facilitates the formation of sub-100 nm diameter polymer nanolenses of tunable curvature. By varying the extent of e-beam exposure, various configurations from isolated to connected nano-lens arrays can be fabricated.

Ankur Verma; Ashutosh Sharma

2011-09-18T23:59:59.000Z

38

OrganicInorganic Nanohybrids through the Direct Tailoring of Semiconductor Nanocrystals with Conjugated Polymers  

E-Print Network [OSTI]

in photovoltaic cells.[17­19] This indicates that an interpenetrated network of CP/NC on the scale of the exciton with Conjugated Polymers Zhiqun Lin*[a] 2008 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Chem. Eur. J. 2008, 14- gated polymers (CPs; i.e., forming the CP/NC hybrids). Hybrids of electroactive CPs with NCs inherit

Lin, Zhiqun

39

Co-assembly of Zn(SPh){sub 2} and organic linkers into helical and zig-zag polymer chains  

SciTech Connect (OSTI)

Two novel one-dimensional coordination polymers, single helicate [Zn(SPh){sub 2}(TPyTA)(EG)]{sub n} (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh){sub 2}(BPyVB)]{sub n} (2), were synthesized under solvothermal conditions at 150 Degree-Sign C or room temperature by the co-assembly of Zn(SPh){sub 2} and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2{sub 1}/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 Degree-Sign C and 210 Degree-Sign C. - Graphical abstract: Two novel one-dimensional coordination polymers, single helicate [Zn(SPh){sub 2}(TPyTA)(EG)]{sub n} (1) and zig-zag structure [Zn(SPh){sub 2}(BPyVB)]{sub n} (2), were synthesized. Solid-state UV-vis absorptions show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 Degree-Sign C and 210 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Two novel one-dimensional coordination polymers have been synthesized. Black-Right-Pointing-Pointer TPyTA results in helical structures in 1 while BPyVB leads to zig-zag chains in 2. Black-Right-Pointing-Pointer Solid-state UV-vis absorption spectra and TGA analysis of the title polymers were studied.

Liu Yi; Yu Lingmin; Loo, Say Chye Joachim [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Blair, Richard G. [Chemistry and Forensic Science, University of Central Florida, Department of Chemistry, 4000 Central Florida Blvd. P.O. Box 162366, Orlando, FL 32816-2366 (United States); Zhang Qichun, E-mail: qczhang@ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

2012-07-15T23:59:59.000Z

40

Broadband energy-efficient optical modulation by hybrid integration of silicon nanophotonics and organic electro-optic polymer  

E-Print Network [OSTI]

Silicon-organic hybrid integrated devices have emerging applications ranging from high-speed optical interconnects to photonic electromagnetic-field sensors. Silicon slot photonic crystal waveguides (PCWs) filled with electro-optic (EO) polymers combine the slow-light effect in PCWs with the high polarizability of EO polymers, which promises the realization of high-performance optical modulators. In this paper, a broadband, power-efficient, low-dispersion, and compact optical modulator based on an EO polymer filled silicon slot PCW is presented. A small voltage-length product of V{\\pi}*L=0.282Vmm is achieved, corresponding to an unprecedented record-high effective in-device EO coefficient (r33) of 1230pm/V. Assisted by a backside gate voltage, the modulation response up to 50GHz is observed, with a 3-dB bandwidth of 15GHz, and the estimated energy consumption is 94.4fJ/bit at 10Gbit/s. Furthermore, lattice-shifted PCWs are utilized to enhance the optical bandwidth by a factor of ~10X over other modulators bas...

Zhang, Xingyu; Subbaraman, Harish; Luo, Jingdong; Jen, Alex K -Y; Chung, Chi-jui; Yan, Hai; Pan, Zeyu; Nelson, Robert L; Chen, Ray T

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Miniaturized Low-power Electro-optic Modulator Based on Silicon Integrated Nanophotonics and Organic Polymers  

E-Print Network [OSTI]

We design and demonstrate a compact, low-power, low-dispersion and broadband optical modulator based on electro-optic (EO) polymer refilled silicon slot photonic crystal waveguide (PCW). The EO polymer is engineered for large EO activity and near-infrared transparency. The half-wave switching-voltage is measured to be V{\\pi}=0.97V over optical spectrum range of 8nm, corresponding to a record-high effective in-device r33 of 1190pm/V and V{\\pi} L of 0.291Vmm in a push-pull configuration. Excluding the slow-light effect, we estimate the EO polymer is poled with an ultra-high efficiency of 89pm/V in the slot. In addition, to achieve high-speed modulation, silicon PCW is selectively doped to reduce RC time delay. The 3-dB RF bandwidth of the modulator is measured to be 11GHz, and a modulation response up to 40GHz is observed.

Zhang, Xingyu; Luo, Jingdong; Jen, Alex K -Y; Chen, Ray T

2014-01-01T23:59:59.000Z

42

Reduced bleaching in organic nanofibers by bilayer polymer/oxide coating  

SciTech Connect (OSTI)

Para-hexaphenylene (p-6P) molecules exhibit a characteristic photoinduced reaction (bleaching) resulting in a decrease in luminescence intensity upon UV light exposure, which could render the technological use of the nanofibers problematic. In order to investigate the photoinduced reaction in nanofibers, optical bleaching experiments have been performed by irradiating both pristine and coated nanofibers with UV light. Oxide coating materials (SiO{sub x} and Al{sub 2}O{sub 3}) were applied onto p-6P nanofibers. These treatments caused a reduction in the bleaching reaction but in addition, the nanofiber luminescence spectrum was significantly altered. It was observed that some polymer coatings [a statistical copolymer of tetrafluoroethylene and 2,2-bis-trifluoromethyl-4,5-difluoro-1,3-dioxole, P(TFE-PDD), and poly(methyl methacrylate), PMMA] do not interfere with the luminescence spectrum from the p-6P but are not effective in stopping the bleaching. Bilayer coatings with first a polymer material, which should work as a protection layer to avoid modifications of the p-6P luminescence spectrum, and second an oxide layer used as oxygen blocker were tested and it was found that a particular bilayer polymer/oxide combination results in a significant reduction in bleaching without affecting significantly the emission spectrum from the nanofibers.

Tavares, L.; Kjelstrup-Hansen, J.; Rubahn, H.-G. [NanoSyd, Mads Clausen Institute, University of Southern Denmark, Alsion 2, DK-6400 Soenderborg (Denmark); Sturm, H. [Federal Institute for Materials Research and Testing (BAM), Unter den Eichen 87, D-12205 Berlin (Germany)

2010-05-15T23:59:59.000Z

43

Study of organic molecules and nano-particle/polymer composites for flash memory and switch applications  

E-Print Network [OSTI]

Organic materials exhibit fascinating optical and electronic properties which motivate their hybridization with traditional silicon-based electronics in order to achieve novel functionalities and address scaling challenges ...

Paydavosi, Sarah

2012-01-01T23:59:59.000Z

44

Sputtered Nickel Oxide Thin Film for Efficient Hole Transport Layer in Polymer-Fullerene Bulk-Heterojunction Organic Solar Cell  

SciTech Connect (OSTI)

Bulk-heterojunction (BHJ) organic photovoltaics (OPV) are very promising thin film renewable energy conversion technologies due to low production cost by high-throughput roll-to-roll manufacturing, an expansive list of compatible materials, and flexible device fabrication. An important aspect of OPV device efficiency is good contact engineering. The use of oxide thin films for this application offers increased design flexibility and improved chemical stability. Here we present our investigation of radio frequency magnetron sputtered nickel oxide (NiO{sub x}) deposited from oxide targets as an efficient, easily scalable hole transport layer (HTL) with variable work-function, ranging from 4.8 to 5.8 eV. Differences in HTL work-function were not found to result in statistically significant changes in open circuit voltage (V{sub oc}) for poly(3-hexylthiophene):[6,6]-phenyl-C{sub 61}-butyric acid methyl ester (P3HT:PCBM) BHJ device. Ultraviolet photoemission spectroscopy (UPS) characterization of the NiO{sub x} film and its interface with the polymer shows Fermi level alignment of the polymer with the NiO{sub x} film. UPS of the blend also demonstrates Fermi level alignment of the organic active layer with the HTL, consistent with the lack of correlation between V{sub oc} and HTL work-function. Instead, trends in j{sub sc}, V{sub oc}, and thus overall device performance are related to the surface treatment of the HTL prior to active layer deposition through changes in active layer thickness.

Widjonarko, N. E.; Ratcliff, E. L.; Perkins, C. L.; Sigdel, A. K.; Zakutayev, A.; Ndione, P. F.; Gillaspie, D. T.; Ginley, D. S.; Olson, D. C.; Berry, J. J.

2012-03-01T23:59:59.000Z

45

Polymer and carbon nanotube materials for chemical sensors and organic electronics  

E-Print Network [OSTI]

This thesis details the development of new materials for high-performance chemical sensing as well as organic electronic applications. In Chapter 2, we develop a chemiresistive material based on single-walled carbon nanotubes ...

Wang, Fei, Ph. D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

46

Polymers via chemical vapor deposition and their application to organic photovoltaics  

E-Print Network [OSTI]

There is emerging interest in the ability to fabricate organic photovoltaics (OPVs) on flexible, lightweight substrates, which could lower the cost of installation and enable new form factors for deployment. However, ...

Barr, Miles Clark

2012-01-01T23:59:59.000Z

47

Development of hybrid organic-inorganic light emitting diodes using conducting polymers deposited by oxidative chemical vapor deposition process  

E-Print Network [OSTI]

Difficulties with traditional methods of synthesis and film formation for conducting polymers, many of which are insoluble, motivate the development of CVD methods. Indeed, conjugated polymers with rigid linear backbones ...

Chelawat, Hitesh

2010-01-01T23:59:59.000Z

48

Photovoltaic properties and morphology of organic solar cells based on liquid-crystal semiconducting polymer with additive  

SciTech Connect (OSTI)

Bulk heterojunction organic solar cell based on liquid crystal semiconducting polymers of poly[9,9-dioctylfluorene-co-bithiophene] (F8T2) as p-type semiconductors and fullerenes (C{sub 60}) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as electron donor and acceptor has been fabricated and characterized for improving photovoltaic and optical properties. The photovoltaic performance including current voltage curves in the dark and illumination of the F8T2/C{sub 60} conventional and inverted bulk heterojunction solar cells were investigated. Relationship between the photovoltaic properties and morphological behavior was focused on tuning for optimization of photo-voltaic performance under annealing condition near glass transition temperature. Additive-effect of diiodooctane (DIO) and poly(3-hexylthiophene-2,5-diyl) (P3HT) on the photovoltaic performance and optical properties was investigated. Mechanism of the photovoltaic properties of the conventional and inverted solar cells will be discussed by the experimental results.

Suzuki, Atsushi; Zushi, Masahito; Suzuki, Hisato; Ogahara, Shinichi; Akiyama, Tsuyoshi; Oku, Takeo [Department of Materials Science, The University of Shiga Prefecture, 2500 Hassaka, Hikone, Shiga 522-8533 (Japan)

2014-02-20T23:59:59.000Z

49

Controlled Self Assembly of Conjugated Polymer Containing Block Copolymers  

E-Print Network [OSTI]

Copolymers for Organic Optoelectronics. Macromolecules 2009,Copolymers for Organic Optoelectronics. Macromolecules 2009,performance of polymer optoelectronics. Table of Contents

McCulloch, Bryan

2012-01-01T23:59:59.000Z

50

Comparison of light out-coupling enhancements in single-layer blue-phosphorescent organic light emitting diodes using small-molecule or polymer hosts  

SciTech Connect (OSTI)

Single-layer blue phosphorescence organic light emitting diodes (OLEDs) with either small-molecule or polymer hosts are fabricated using solution process and the performances of devices with different hosts are investigated. The small-molecule device exhibits luminous efficiency of 14.7?cd/A and maximum power efficiency of 8.39?lm/W, which is the highest among blue phosphorescence OLEDs with single-layer solution process and small molecular hosts. Using the same solution process for all devices, comparison of light out-coupling enhancement, with brightness enhancement film (BEF), between small-molecule and polymer based OLEDs is realized. Due to different dipole orientation and anisotropic refractive index, polymer-based OLEDs would trap less light than small molecule-based OLEDs internally, about 37% better based simulation results. In spite of better electrical and spectroscopic characteristics, including ambipolar characteristics, higher carrier mobility, higher photoluminescence quantum yield, and larger triplet state energy, the overall light out-coupling efficiency of small molecule-based devices is worse than that of polymer-based devices without BEF. However, with BEF for light out-coupling enhancement, the improved ratio in luminous flux and luminous efficiency for small molecule based device is 1.64 and 1.57, respectively, which are significantly better than those of PVK (poly-9-vinylcarbazole) devices. In addition to the theoretical optical simulation, the experimental data also confirm the origins of differential light-outcoupling enhancement. The maximum luminous efficiency and power efficiency are enhanced from 14.7?cd/A and 8.39?lm/W to 23?cd/A and 13.2?lm/W, respectively, with laminated BEF, which are both the highest so far for single-layer solution-process blue phosphorescence OLEDs with small molecule hosts.

Chang, Yung-Ting [Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, Taiwan (China); Department of Electrical Engineering, Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei, Taiwan 10617, Taiwan (China); Liu, Shun-Wei [Department of Electronic Engineering, Mingchi University of Technology, New Taipei, Taiwan 24301, Taiwan (China); Yuan, Chih-Hsien; Lee, Chih-Chien [Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan 10607, Taiwan (China); Ho, Yu-Hsuan; Wei, Pei-Kuen [Research Center for Applied Science Academia Sinica, Taipei, Taiwan 11527, Taiwan (China); Chen, Kuan-Yu [Chilin Technology Co., LTD, Tainan City, Taiwan 71758, Taiwan (China); Lee, Yi-Ting; Wu, Min-Fei; Chen, Chin-Ti, E-mail: cchen@chem.sinica.edu.tw, E-mail: chihiwu@cc.ee.ntu.edu.tw [Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, Taiwan (China); Wu, Chih-I, E-mail: cchen@chem.sinica.edu.tw, E-mail: chihiwu@cc.ee.ntu.edu.tw [Department of Electrical Engineering, Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei, Taiwan 10617, Taiwan (China)

2013-11-07T23:59:59.000Z

51

Electrooptic microwave antenna using organic poled polymers Arnaud Gardeleina, Sylvain Le Tacona, Eric Tanguya, Nicolas Breuilb and Tchanguiz Razbana  

E-Print Network [OSTI]

actually electrooptical polymer properties and stability are lower than lithium niobate ones, the gap of the electrooptic antenna design is to obtain maximum microwave and optical interaction. We propose a novel approach polarizer or other means. Two electrooptic-enabled materials are under interest. The older one is lithium

Paris-Sud XI, Université de

52

Controlled Self Assembly of Conjugated Polymer Containing Block Copolymers  

E-Print Network [OSTI]

in dye/polymer blend photovoltaic cells. Advanced MaterialsA. J. , Polymer Photovoltaic Cells - Enhanced Efficiencies2-Layer Organic Photovoltaic Cell. Applied Physics Letters

McCulloch, Bryan

2012-01-01T23:59:59.000Z

53

Solid polymer electrolyte lithium batteries  

DOE Patents [OSTI]

This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

Alamgir, M.; Abraham, K.M.

1993-10-12T23:59:59.000Z

54

Solid polymer electrolyte lithium batteries  

DOE Patents [OSTI]

This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

1993-01-01T23:59:59.000Z

55

Solid polymer electrolyte compositions  

DOE Patents [OSTI]

An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

Garbe, James E. (Stillwater, MN); Atanasoski, Radoslav (Edina, MN); Hamrock, Steven J. (St. Paul, MN); Le, Dinh Ba (St. Paul, MN)

2001-01-01T23:59:59.000Z

56

Diabetes: The Growing Epidemic  

E-Print Network [OSTI]

Research Brief August 2007 Diabetes: The Growing Epidemicof people diagnosed with diabetes in California continues tohad been diagnosed with diabetes, up from 1.5 million in

Diamant, Allison L.; Babey, Susan H.; Brown, E. Richard; Hastert, Theresa A.

2007-01-01T23:59:59.000Z

57

Fabrication and Characterization of Organic Solar Cells  

E-Print Network [OSTI]

processable polymer photovoltaic cells by self?organization Photodiodes,  and  Photovoltaic  Cells.   Applied Physics F,  Heeger  AJ.   Polymer  Photovoltaic  Cells  ?  Enhanced 

Yengel, Emre

2010-01-01T23:59:59.000Z

58

Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture  

SciTech Connect (OSTI)

IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

None

2010-07-01T23:59:59.000Z

59

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

2000-01-01T23:59:59.000Z

60

Energy level alignment in polymer organic solar cells at donor-acceptor planar junction formed by electrospray vacuum deposition  

SciTech Connect (OSTI)

Using ultraviolet photoelectron spectroscopy (UPS), we have measured the energy level offset at the planar interface between poly(3-hexylthiophene) (P3HT) and C{sub 61}-butyric acid methylester (PCBM). Gradual deposition of PCBM onto spin-coated P3HT in high vacuum was made possible by using electrospray vacuum deposition (EVD). The UPS measurement of EVD-prepared planar interface resulted in the energy level offset of 0.91?eV between P3HT HOMO and PCBM LUMO, which is considered as the upper limit of V{sub oc} of the organic photovoltaic cells.

Kim, Ji-Hoon; Hong, Jong-Am; Kwon, Dae-Gyeon; Seo, Jaewon; Park, Yongsup, E-mail: parky@khu.ac.kr [Department of Physics and Research Institute for Basic Sciences, Kyung Hee University, Seoul 130-701 (Korea, Republic of)

2014-04-21T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat CornellInternships,(SC) Laboratories »OrganicOrganization

62

E-Print Network 3.0 - affect polymer matrix Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Diffusion In Polymer Films T. Graves... to pattern full color polymer Organic Light-Emitting Diode (OLED) displays is to print dye ... Source: Sturm, James C.- Department of...

63

New functional polymers for sensors, smart materials and solar cells  

E-Print Network [OSTI]

Organic polymers can be used as the active component of sensors, smart materials, chemical-delivery systems and the active layer of solar cells. The rational design and modification of the chemical structure of polymers ...

Lobez Comeras, Jose Miguel

2012-01-01T23:59:59.000Z

64

Conducting Polymer Devices for Bioelectronics  

E-Print Network [OSTI]

signals recording. Organic electrochemical transistors (OECTs) represent a step beyond conducting polymer a far superior signal-to-noise- ratio (SNR) compared to electrodes. The high SNR of the OECT recordings and contamination. The use of an organic electrochemical transistor for detection of lactate by integration

Paris-Sud XI, Université de

65

Diabetes Reunion Celebrating Sensibly with Diabetes  

E-Print Network [OSTI]

In the first lesson, we learned about planning meals using the Plate Method to balance the amounts and types1 Lesson 4: Diabetes Reunion Celebrating Sensibly with Diabetes T oday is our final lesson on Cooking Well with Diabetes. In this lesson, we will focus on four key points, reviewing the concepts

66

Dielectric Actuation of Polymers  

E-Print Network [OSTI]

S. Stanford, Interpenetrating polymer networks for high-based on interpenetrating polymer networks, Proceeding ofX. Niu, Q. Pei, Interpenetrating polymer networks based on

Niu, Xiaofan

2013-01-01T23:59:59.000Z

67

Organic Photovoltaics Philip Schulz  

E-Print Network [OSTI]

Field Effect Transistors Organic Light Emitting Diodes Organic Solar Cells .OFET, OTFT .RF-ID tag 1977 ­ Conductivity in polymers 1986 ­ First heterojunction OPV 1987 ­ First organic light emitting diode (OLED) 1993 ­ First OPV from solution processing 2001 ­ First certified organic solar cell with 2

Firestone, Jeremy

68

Anion exchange polymer electrolytes  

DOE Patents [OSTI]

Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

Kim, Yu Seung; Kim, Dae Sik

2013-09-10T23:59:59.000Z

69

Antimocrobial Polymer  

DOE Patents [OSTI]

A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from quaternary ammonium compounds, gentian violet compounds, substituted or unsubstituted phenols, biguanide compounds, iodine compounds, and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl; and the antimicrobial agent is chlorhexidine, dimethylchlorophenol, cetyl pyridinium chloride, gentian violet, triclosan, thymol, iodine, and mixtures thereof.

McDonald, William F. (Utica, OH); Huang, Zhi-Heng (Walnut Creek, CA); Wright, Stacy C. (Columbus, GA)

2005-09-06T23:59:59.000Z

70

Antimicrobial Polymer  

DOE Patents [OSTI]

A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The polymeric composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from metals, metal alloys, metal salts, metal complexes and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one example embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl; and the metallic antimicrobial agent is selected from chelated silver ions, silver metal, chelated copper ions, copper metal, chelated zinc ions, zinc metal and mixtures thereof.

McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

2004-09-28T23:59:59.000Z

71

A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties  

SciTech Connect (OSTI)

Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers, [Zn(L)(1,4-bdc){sub 0.5}] (1), [Zn{sub 1.5}(L)(2,5-pydc)] (2), [Zn(HL)(1,2,4,5-btec){sub 0.5}] (3), and [Cd(HL)(1,2,4,5-btec){sub 0.5}] (4) (1,4-bdc, 1,4-benzenedicarboxylate; 2,5-pydc, 2,5-pyridinedicarboxylate; 1,2,4,5-btec, 1,2,4,5-benzenetetracarboxylate) have been successfully synthesized and analyzed. Compound 1 features the 2D [Zn(L)]{sub n} layers built by ?{sub 3}-L bridging ligands and Zn(II) ions, which are further linked by pillared 1,4-bdc{sup 2?} ligands to form a 2-fold interpenetrating dmc framework. The 3D network of compound 2 can be simplified as a rare 2-nodal (3,6)-connected rtl (rutile) topology. Compound 3 possesses a 2D layer structure which is accomplished by connecting ladder-chains to L ligands. Compound 4 exhibits 2D [Cd(1,2,4,5-btec)] layers with infinite Cd–O–Cd rods and the adjacent 2D networks are further pillared by L with terminal bidentate coordination mode to generate the final 3D structure. The solid-state luminescent studies show that compounds 1–4 display intense fluorescent emissions. - Graphical abstract: Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers have been obtained. All compounds show good luminescence properties at room temperature. Display Omitted - Highlights: • Four Zn(II)/Cd(II)-MOCPs have been successfully prepared with the rigid bifunctional ligand 5-(4-imidazol -1-yl-phenyl) -2H-tetrazole and different aromatic carboxylates mixed ligands. • Compound 2 is a 2-nodal rtl (rutile) net and compound 4 is a binodal (5, 6)-connected net with yav topology. • Compounds 1-4 display intense fluorescent emissions at room temperature.

Sun, Jiayin [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Daojun, E-mail: zhangdj0410@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Wang, Li [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Renchun; Wang, Junjie; Zeng, Ying; Zhan, Jinling [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Xu, Jianing [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Fan, Yong, E-mail: mrfy@jlu.edu.cn [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

2013-10-15T23:59:59.000Z

72

Conductive Polymers  

SciTech Connect (OSTI)

Electroluminescent devices such as light-emitting diodes (LED) and high-energy density batteries. These new polymers offer cost savings, weight reduction, ease of processing, and inherent rugged design compared to conventional semiconductor materials. The photovoltaic industry has grown more than 30% during the past three years. Lightweight, flexible solar modules are being used by the U.S. Army and Marine Corps for field power units. LEDs historically used for indicator lights are now being investigated for general lighting to replace fluorescent and incandescent lights. These so-called solid-state lights are becoming more prevalent across the country since they produce efficient lighting with little heat generation. Conductive polymers are being sought for battery development as well. Considerable weight savings over conventional cathode materials used in secondary storage batteries make portable devices easier to carry and electric cars more efficient and nimble. Secondary battery sales represent an $8 billion industry annually. The purpose of the project was to synthesize and characterize conductive polymers. TRACE Photonics Inc. has researched critical issues which affect conductivity. Much of their work has focused on production of substituted poly(phenylenevinylene) compounds. These compounds exhibit greater solubility over the parent polyphenylenevinylene, making them easier to process. Alkoxy substituted groups evaluated during this study included: methoxy, propoxy, and heptyloxy. Synthesis routes for production of alkoxy-substituted poly phenylenevinylene were developed. Considerable emphasis was placed on final product yield and purity.

Bohnert, G.W.

2002-11-22T23:59:59.000Z

73

SEC data for polymer 1-6: UV-vis spectra for polymer 1-6  

E-Print Network [OSTI]

for organic solar cells Eva Bundgaard a,b and Frederik C. Krebs a a Polymer Solar Cell Initiative, The Danish with increase in area (3 and 10 cm2 devices). · Lifetime of less than 2 hours for non encapsulated devices of the device by a better overlap with the solar spectrum. The synthesis of low band gap polymers are however

74

DIABETES, OBESITY AND METABOLISM INSTITUTE  

E-Print Network [OSTI]

DIABETES, OBESITY AND METABOLISM INSTITUTE AT NORTHWESTERN MEDICINE THE INSTITUTES AT NORTHWESTERN MEDICINE #12;THE INSTITUTES AT NORTHWESTERN MEDICINE DIABETES, OBESITY AND METABOLISM INSTITUTE AT NORTHWESTERN MEDICINE "As we launch the Diabetes, Obesity and Metabolism Institute at Northwestern Medicine, I

Engman, David M.

75

Conductor-polymer composite electrode materials  

DOE Patents [OSTI]

A conductive composite material useful as an electrode, comprises a conductor and an organic polymer which is reversibly electrochemically dopable to change its electrical conductivity. Said polymer continuously surrounds the conductor in intimate electrical contact therewith and is prepared by electrochemical growth on said conductor or by reaction of its corresponding monomer(s) on said conductor which has been pre-impregnated or pre-coated with an activator for said polymerization. Amount of the conductor is sufficient to render the resultant composite electrically conductive even when the polymer is in an undoped insulating state.

Ginley, D.S.; Kurtz, S.R.; Smyrl, W.H.; Zeigler, J.M.

1984-06-13T23:59:59.000Z

76

Polymer system for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

77

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

1998-11-17T23:59:59.000Z

78

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

79

Polymer and small molecule based hybrid light source  

DOE Patents [OSTI]

An organic electroluminescent device, includes: a substrate; a hole-injecting electrode (anode) coated over the substrate; a hole injection layer coated over the anode; a hole transporting layer coated over the hole injection layer; a polymer based light emitting layer, coated over the hole transporting layer; a small molecule based light emitting layer, thermally evaporated over the polymer based light emitting layer; and an electron-injecting electrode (cathode) deposited over the electroluminescent polymer layer.

Choong, Vi-En (Carlsbad, CA); Choulis, Stelios (Nuremberg, DE); Krummacher, Benjamin Claus (Regensburg, DE); Mathai, Mathew (Monroeville, PA); So, Franky (Gainesville, FL)

2010-03-16T23:59:59.000Z

80

Management of Hypertriglyceridemia in the Diabetic Patient  

E-Print Network [OSTI]

Robins SJ, Collins D, et al. : Diabetes, plasma insulin, andprogression of coronary-artery disease in type 2 diabetes:the Diabetes Atherosclerosis Intervention Study, a

Jialal, Ishwarlal; Amess, William; Kaur, Manpreet

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

High Seebeck effects from conducting polymer: Poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) based thin-film device with hybrid metal/polymer/metal architecture  

SciTech Connect (OSTI)

Conductive polymers are of particular interest for thermoelectric applications due to their low thermal conductivity and relatively high electrical conductivity. In this study, commercially available conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) was used in a hybrid metal/polymer/metal thin film design in order to achieve a high Seebeck coefficient with the value of 252lV/k on a relatively low temperature scale. Polymer film thickness was varied in order to investigate its influence on the Seebeck effect. The high Seebeck coefficient indicates that the metal/polymer/metal design can develop a large entropy difference in internal energy of charge carriers between high and low-temperature metal electrodes to develop electrical potential due to charge transport in conducting polymer film through metal/polymer interface. Therefore, the metal/polymer/metal structure presents a new design to combine inorganic metals and organic polymers in thin-film form to develop Seebeck devices

Stanford, Michael G [ORNL; Wang, Hsin [ORNL; Ivanov, Ilia N [ORNL; Hu, Bin [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

82

Polymer and Composite Materials Used in Hydrogen Service  

E-Print Network [OSTI]

and standards. Previous meetings2 focused largely on either hydrogen compatibility with metals or pipeline1 Polymer and Composite Materials Used in Hydrogen Service MEETING PROCEEDINGS Polymer materials in hydrogen applications. The meeting, which was organized by the U.S. Department of Energy

83

Inorganic-Organic Hybrid Thermoelectrics  

Broader source: Energy.gov [DOE]

Large-scale synthesis of inorganic and organic nanomaterials (single-crystalline nanowires and functionalized conducting polymer thin films) together with strategies for large-scale assembly are discussed

84

Molecular design of conjugated polymers for the control of conformation, electronics and self-assembly  

E-Print Network [OSTI]

The design, synthesis and characterization of organic electronic materials, in particular luminescent conjugated polymers, with structural motifs that allow for the controlled modulation of their photophysical properties ...

Bouffard, Jean, Ph. D. Massachusetts Institute of Technology

2008-01-01T23:59:59.000Z

85

Insulating polymer concrete  

DOE Patents [OSTI]

A lightweight insulating polymer concrete formed from a lightweight closed cell aggregate and a water resistance polymeric binder.

Schorr, H. Peter (Douglaston, NY); Fontana, Jack J. (Shirley, NY); Steinberg, Meyer (Melville, NY)

1987-01-01T23:59:59.000Z

86

Nanoporous polymer electrolyte  

DOE Patents [OSTI]

A nanoporous polymer electrolyte and methods for making the polymer electrolyte are disclosed. The polymer electrolyte comprises a crosslinked self-assembly of a polymerizable salt surfactant, wherein the crosslinked self-assembly includes nanopores and wherein the crosslinked self-assembly has a conductivity of at least 1.0.times.10.sup.-6 S/cm at 25.degree. C. The method of making a polymer electrolyte comprises providing a polymerizable salt surfactant. The method further comprises crosslinking the polymerizable salt surfactant to form a nanoporous polymer electrolyte.

Elliott, Brian (Wheat Ridge, CO); Nguyen, Vinh (Wheat Ridge, CO)

2012-04-24T23:59:59.000Z

87

Harold Schnitzer Diabetes Health Center Type 1 Diabetes Support Group  

E-Print Network [OSTI]

will be for sharing and a professional from our diabetes center will present a short diabetes-related topic park your car take the elevator up to the first floor of the #12;

Chapman, Michael S.

88

Mechanics of amorphous polymers and polymer gels  

E-Print Network [OSTI]

Many applications of amorphous polymers require a thermo-mechanically coupled large-deformation elasto-viscoplasticity theory which models the strain rate and temperature dependent response of amorphous polymeric materials ...

Chester, Shawn Alexander

2011-01-01T23:59:59.000Z

89

Fabrication and life cycle assessment of organic photovoltaics.  

E-Print Network [OSTI]

??Increasing demand for renewable energy has resulted in a new interest for alternative technologies such as organic photovoltaics. With efficiencies exceeding 8% for both polymer… (more)

Anctil, Annick

2011-01-01T23:59:59.000Z

90

Polymer-assisted deposition of films  

DOE Patents [OSTI]

A polymer assisted deposition process for deposition of metal nitride films and the like is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures under a suitable atmosphere to yield metal nitride films and the like. Such films can be conformal on a variety of substrates including non-planar substrates. In some instances, the films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

McCleskey,Thomas M. (Los Alamos, NM); Burrell,Anthony K. (Los Alamos, NM); Jia,Quanxi (Los Alamos, NM); Lin,Yuan (Chandler, AZ)

2012-02-28T23:59:59.000Z

91

Radioluminescent polymer lights  

SciTech Connect (OSTI)

The preparation of radioluminescent light sources where the tritium is located on the aryl-ring in a polymer has been demonstrated with deuterium/tritium substitution. This report discusses tests, results, and future applications of radioluminescent polymers. 10 refs. (FI)

Jensen, G.A.; Nelson, D.A.; Molton, P.M.

1990-09-01T23:59:59.000Z

92

todasuvida: Las personas con diabetes son ms  

E-Print Network [OSTI]

diabetes Controlesu todasuvida: Las personas con diabetes son más propensas a padecer de enfermedades del corazón que quienes no tienen diabetes. Boletín 631 D Las personas con diabetes tienen mayor- res relacionados con la diabetes, como derrame cerebral, mala circulación en las piernas y pies e

93

Method for identifying type I diabetes mellitus in humans  

SciTech Connect (OSTI)

A method and system for classifying subject populations utilizing predictive and diagnostic biomarkers for type I diabetes mellitus. The method including determining the levels of a variety of markers within the serum or plasma of a target organism and correlating this level to general populations as a screen for predisposition or progressive monitoring of disease presence or predisposition.

Metz, Thomas O [Kennewick, WA; Qian, Weijun [Richland, WA; Jacobs, Jon M [Pasco, WA

2011-04-12T23:59:59.000Z

94

InP Nanowire/Polymer Hybrid Clint J. Novotny, Edward T. Yu, and Paul K. L. Yu*  

E-Print Network [OSTI]

in conjugated polymer hybrid solar cells as well as in nanowire- based dye-sensitized solar cells10 factor of 0.44, thus showing promise as an alternative to current polymer solar cell designs produced in the polymer will be lost to recombina- tion. Bulk organic heterojunction solar cells attempt

Yu, Edward T.

95

Semipermeable polymers and method for producing same  

DOE Patents [OSTI]

A polyamide membrane comprising reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst; and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant comprising one ring. A composite semipermeable membrane comprising the polyamide membrane on a porous support. A method of making a composite semipermeable membrane by coating a porous support with an anhydrous solution comprising an anhydrous solvent, a polyfunctional secondary amine and a pre-polymer deposition catalyst, to form an activated pre-polymer layer on the porous support and contacting the activated pre-polymer layer with an anhydrous, organic solvent solution comprising a polyfunctional amine-reactive reactant to interfacially condense the amine-reactive reactant with the polyfunctional secondary amine, thereby forming a cross-linked, interfacial polyamide layer on the porous support. A method of impregnating a composite semipermeable membrane with nanoparticles selected from heavy metals and/or oxides of heavy metals.

Buschmann, Wayne E. (Boulder, CO)

2012-04-03T23:59:59.000Z

96

Silvered polymer reflectors  

SciTech Connect (OSTI)

One of the principal objectives of the Solar Thermal Research Program is to develop silvered polymer films for constructing durable, low-cost, lightweight concentrating collectors for high temperature solar thermal systems. The mirrors are characterized for their solar-weighted (air mass 1.5) reflectance and exposed to environmental degradation. Photodegradation of polymers has also been studied using Fourier transform infrared spectroscopy supplemented with surface analysis characterization. Results are discussed for extruded films, ultraviolet effects, metallization, and the effects of polymer additives. (LEW)

Schissel, P.; Neidlinger, H.H.; Czanderna, A.W.

1985-03-01T23:59:59.000Z

97

Precursors for the polymer-assisted deposition of films  

DOE Patents [OSTI]

A polymer assisted deposition process for deposition of metal oxide films is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures to yield metal oxide films. Such films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

McCleskey, Thomas M.; Burrell, Anthony K.; Jia, Quanxi; Lin, Yuan

2013-09-10T23:59:59.000Z

98

Physical Mechanisms of Interaction of Cold Plasma with Polymer Surfaces  

E-Print Network [OSTI]

Physical mechanisms of the interaction of cold plasmas with organic surfaces are discussed. Trapping of plasma ions by the CH2 groups of polymer surfaces resulting in their electrical charging is treated. Polyethylene surfaces were exposed to the cold radiofrequency air plasma for different intervals of time. The change in the wettability of these surfaces was registered. The experimentally established characteristic time scales of the interaction of cold plasma with polymer surfaces are inversely proportional to the concentration of ions. The phenomenological kinetic model of the electrical charging of polymer surfaces by plasmas is introduced and analyzed.

Bormashenko, Edward; Multanen, Victor; Shulzinger, Evgeny; Chaniel, Gilad

2015-01-01T23:59:59.000Z

99

Chemical phenomena in solid-state voltammetry in polymer solvents  

SciTech Connect (OSTI)

This paper, aimed at delineating significant chemical effects in solid-state voltammetry, describes electrochemical oxidations and reductions of electroactive monomer solutes dissolved in and diffusing through rigid and semirigid polymer electrolyte solvents. Sorption of organic monomer vapors into poly(ethylene oxide) films yields polymer solvents whose chemistry is dominated by that of the sorbed monomer as shown by coordination and precipitation effects. The dynamics of plasticization-induced changes in transport rates are quite rapid. Physical diffusion in the polymer solvent in slow enough that electron hopping reactions measurably enhance charge transport rates; the effect was used to estimate a lower limit for the (Co(bpy)/sub 3/)/sup 2+/+/ self-exchange rate constant of 2 /times/ 10/sup 9/ M/sup /minus/1/ s/sup /minus/1/. It is possible to erect polymeric film transport barriers at the electrode/polymer solvent interface and to measure the rate of permeation of monomer complexes from the polymer solvent into the polymer transport barrier film. Polymeric films of Os and Ru polypyridine complexes can be electropolymerized from polymer solutions of the corresponding monomers. Solid-state voltammetry can be extended to other polymer solvents including sulfonated polystyrene, poly(vinyl chloride), Nafion, and poly(acrylamide) gel.

Geng, L.; Reed, R.A.; Kim, M.H.; Wooster, T.T.; Oliver, B.N.; Egekeze, J.; Kennedy, R.T.; Jorgenson, J.W.; Parcher, J.F.; Murray, R.W.

1989-03-01T23:59:59.000Z

100

Sulfonated polyphenylene polymers  

DOE Patents [OSTI]

Improved sulfonated polyphenylene compositions, improved polymer electrolyte membranes and nanocomposites formed there from for use in fuel cells are described herein. The improved compositions, membranes and nanocomposites formed there from overcome limitations of Nafion.RTM. membranes.

Cornelius, Christopher J. (Albuquerque, NM); Fujimoto, Cy H. (Albuquerque, NM); Hickner, Michael A. (Albuquerque, NM)

2007-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Heavily fluorinated electronic polymers  

E-Print Network [OSTI]

Building blocks, containing majority fluorine content by weight, for PPEs and PPVs have been synthesized. Some of the monomers were shown to give exclusively fluorous-phase soluble polymers, the syntheses of which were ...

Lim, Jeewoo

2011-01-01T23:59:59.000Z

102

Polymers in disordered environments  

E-Print Network [OSTI]

A brief review of our recent studies aiming at a better understanding of the scaling behaviour of polymers in disordered environments is given. The main emphasis is on a simple generic model where the polymers are represented by (interacting) self-avoiding walks and the disordered environment by critical percolation clusters. The scaling behaviour of the number of conformations and their average spatial extent as a function of the number of monomers and the associated critical exponents $\\gamma$ and $\

V. Blavatska; N. Fricke; W. Janke

2014-11-18T23:59:59.000Z

103

Diabetes Care. Author manuscript Hyperglycemia, type 2 diabetes, and depressive symptoms: the British  

E-Print Network [OSTI]

Diabetes Care. Author manuscript Page /1 5 Hyperglycemia, type 2 diabetes, and depressive symptoms calixte cavalier 34093 MONTPELLIER CEDEX 5,FR Steno Diabetes Center9 Steno Diabetes Center, Gentofte suggestion that impaired fasting glucose may protect against depression, whereas a diagnosis of diabetes

Paris-Sud XI, Université de

104

The Harold Schnitzer Diabetes Health Center  

E-Print Network [OSTI]

The Harold Schnitzer Diabetes Health Center Investing in the future of diabetes care and support and Arlene Schnitzer CARE Foundation, the Harold Schnitzer Diabetes Health Center is leading the way Children's Hospital together with OHSU's adult-care specialists, the Harold Schnitzer Diabetes Health Cen

Chapman, Michael S.

105

with Diabetes Dining A Program For  

E-Print Network [OSTI]

with Diabetes Dining A Program For People With Diabetes And Their Families Pre to anyone with diabetes, and their family members or caregivers. Classes will include demonstrations on how. There will be an opportunity to taste a variety of main dishes, side dishes, and desserts. The class seeks to improve diabetes

106

Polymer OLED White Light Development Program  

SciTech Connect (OSTI)

OSRAM Opto Semiconductors (OSRAM) successfully completed development, fabrication and characterization of the large area, polymer based white light OLED prototype at their OLED Research and Development (R&D) facility in San Jose, CA. The program, funded by the Department of Energy (DOE), consisted of three key objectives: (1) Develop new polymer materials and device architectures--in order to improve the performance of organic light emitters. (2) Develop processing techniques--in order to demonstrate and enable the manufacturing of large area, white light and color tunable, solid state light sources. (3) Develop new electronics and driving schemes for organic light sources, including color-tunable light sources. The key performance goals are listed. A world record efficiency of 25 lm/W was established for the solution processed white organic device from the significant improvements made during the project. However, the challenges to transfer this technology from an R&D level to a large tile format such as, the robustness of the device and the coating uniformity of large area panels, remain. In this regard, the purity and the blend nature of the materials are two factors that need to be addressed in future work. During the first year, OSRAM's Materials and Device group (M&D) worked closely with the major polymer material suppliers to develop the polymer emissive technology. M&D was successful in demonstrating a 7-8 lm/W white light source which was based on fluorescent materials. However, it became apparent that the major gains in efficiency could only be made if phosphorescent materials were utilized. Thus, in order to improve the performance of the resulting devices, the focus of the project shifted towards development of solution-processable phosphorescent light emitting diodes (PHOLEDs) and device architectures. The result is a higher efficiency than the outlined project milestone.

Homer Antoniadis; Vi-En Choong; Stelios Choulis; Brian Cumpston; Rahul Gupta; Mathew Mathai; Michael Moyer; Franky So

2005-12-19T23:59:59.000Z

107

atuais para diabetes: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology Websites Summary: with Diabetes Dining A Program For People With Diabetes And Their Families Now is the time to take charge of your diabetes. What...

108

ao diabetes aloxanico: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology Websites Summary: with Diabetes Dining A Program For People With Diabetes And Their Families Now is the time to take charge of your diabetes. What...

109

Postprandial Lipoproteins and Cardiovascular Disease Risk in Diabetes Mellitus  

E-Print Network [OSTI]

Kingdom Prospec- tive Diabetes Study. Diabetologia 1997, 40(United Kingdom Prospective Diabetes Study, fasting TG levelHerman WH: Global burden of diabetes, 1995–2025: prevalence,

Enkhmaa, Byambaa; Ozturk, Zeynep; Anuurad, Erdembileg; Berglund, Lars

2010-01-01T23:59:59.000Z

110

Translating Sweetness: Type 2 Diabetes, Race, Research, and Outreach  

E-Print Network [OSTI]

Opportunities for prevention. Diabetes Care 26 (3): 645-9.1994. Explanatory models of diabetes: Patient practitionerNarratives: Obesity, Diabetes and the “Aboriginal” Thrifty

Battle, James

2012-01-01T23:59:59.000Z

111

Electrochromic Polymers for Easily Processed Devices John R. Reynolds,* Avni A. Argun, Irina Schwendeman,  

E-Print Network [OSTI]

Electrochromic Polymers for Easily Processed Devices John R. Reynolds,* Avni A. Argun, Irina for electrochromic applications. These polymers exhibit ease of processability and useful mechanical properties (e.g. flexibility). However, the major strength of these organic-based materials is that their electrochromic

Tanner, David B.

112

STRUCTURE-MECHANICAL PROPERTY RELATIONSHIPS IN A BIOLOGICAL CERAMIC-POLYMER COMPOSITE: NACRE  

E-Print Network [OSTI]

171 STRUCTURE-MECHANICAL PROPERTY RELATIONSHIPS IN A BIOLOGICAL CERAMIC-POLYMER COMPOSITE: NACRE, a laminated ceramic- polymer biocompositefound in seashell. Four-pointbending strength and three-point bend and ultramicrotomedsections with and without the intactarago- nite platelets. We found that the organic matrix is indeed

Aksay, Ilhan A.

113

Light trapping design for low band-gap polymer solar cells  

E-Print Network [OSTI]

Light trapping design for low band-gap polymer solar cells Stephen Foster1,* and Sajeev John1,2 1 demonstrate numerically a 2-D nanostructured design for light trapping in a low band-gap polymer solar cell, "Light harvesting improvement of organic solar cells with self- enhanced active layer designs," Opt

John, Sajeev

114

A Multiscale Study of High Performance Double-Walled Nanotube Polymer  

E-Print Network [OSTI]

- tinuous CNT yarns from CVD grown CNT aerogels.1,2,34 The stretching of the low den- sity aerogels of CNTs of randomly oriented bundles of DWNTs thinly coated with polymeric organic compounds. A multiscale in situ performance of yarns and isolated DWNT bundles with and without polymer coatings. DWNT polymer yarns exhibited

Espinosa, Horacio D.

115

Antithrombogenic Polymer Coating.  

DOE Patents [OSTI]

An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.

Huang, Zhi Heng (San Ramon, CA); McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

2003-01-21T23:59:59.000Z

116

Energetic Barrier Prevents Recombination in Organic Solar Photoconversion Systems (Fact Sheet)  

SciTech Connect (OSTI)

NREL researchers unravel the factors that affect charge generation and loss in high-performance conjugated polymer-fullerene blends used in organic solar cells.

Not Available

2012-08-01T23:59:59.000Z

117

Peptides and methods against diabetes  

SciTech Connect (OSTI)

This invention relates to methods of preventing or reducing the severity of diabetes. In one embodiment, the method involves administering to the individual a peptide having substantially the sequence of a on-conserved region sequence of a T cell receptor present on the surface of T cells mediating diabetes or a fragment thereof, wherein the peptide or fragment is capable of causing an effect on the immune system to regulate the T cells. In particular, the T cell receptor has the V.beta. regional V.beta.6 or V.beta.14. In another embodiment, the method involves gene therapy. The invention also relates to methods of diagnosing diabetes by determining the presence of diabetes predominant T cell receptors.

Albertini, Richard J. (Underhill Center, VT); Falta, Michael T. (Hinesburg, VT)

2000-01-01T23:59:59.000Z

118

Oxidative chemical vapor deposition of conductive polymers for use in novel photovoltaic device architectures  

E-Print Network [OSTI]

The conductive polymer poly(3,4-ethylenedioxythiophene), (PEDOT), deposited via oxidative chemical vapor deposition (oCVD) has been investigated for use in organic electronic devices. The oCVD process as well as the ...

Howden, Rachel M. (Rachel Mary)

2013-01-01T23:59:59.000Z

119

POLYMER ELECTROLYTE FUEL CELLS  

E-Print Network [OSTI]

POLYMER ELECTROLYTE FUEL CELLS: The Gas Diffusion Layer Johannah Itescu Princeton University PRISM REU #12;PEM FUEL CELLS: A little background information I. What do fuel cells do? Generate electricity through chemical reaction #12;PEM FUEL CELLS: A little background information -+ + eHH 442 2 0244 22 He

Petta, Jason

120

Sedimentation of Knotted Polymers  

E-Print Network [OSTI]

We investigate the sedimentation of knotted polymers by means of stochastic rotation dynamics, a molecular dynamics algorithm that takes hydrodynamics fully into account. We show that the sedimentation coefficient s, related to the terminal velocity of the knotted polymers, increases linearly with the average crossing number n_c of the corresponding ideal knot. To the best of our knowledge, this provides the first direct computational confirmation of this relation, postulated on the basis of experiments in "The effect of ionic conditions on the conformations of supercoiled DNA. I. sedimentation analysis" by Rybenkov et al., for the case of sedimentation. Such a relation was previously shown to hold with simulations for knot electrophoresis. We also show that there is an accurate linear dependence of s on the inverse of the radius of gyration R_g^-1, more specifically with the inverse of the R_g component that is perpendicular to the direction along which the polymer sediments. When the polymer sediments in a slab, the walls affect the results appreciably. However, R_g^-1 remains to a good precision linearly dependent on n_c. Therefore, R_g^-1 is a good measure of a knot's complexity.

Joonas Piili; Davide Marenduzzo; Kimmo Kaski; Riku Linna

2012-12-20T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Durable metallized polymer mirror  

DOE Patents [OSTI]

A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

1994-01-01T23:59:59.000Z

122

Durable metallized polymer mirror  

DOE Patents [OSTI]

A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

1994-11-01T23:59:59.000Z

123

High temperature polymer concrete  

DOE Patents [OSTI]

This invention is concerned with a polymer concrete composition, which is a two-component composition useful with many bases including metal. Component A, the aggregate composition, is broadly composed of silica, silica flour, portland cement, and acrylamide, whereas Component B, which is primarily vinyl and acrylyl reactive monomers, is a liquid system.

Fontana, J.J.; Reams, W.

1984-05-29T23:59:59.000Z

124

Gel polymer electrolytes for batteries  

DOE Patents [OSTI]

Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains--one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1.times.10.sup.-4 S cm.sup.-1 at 25.degree. C.

Balsara, Nitash Pervez; Eitouni, Hany Basam; Gur, Ilan; Singh, Mohit; Hudson, William

2014-11-18T23:59:59.000Z

125

Acid Diversion in Carbonate Reservoirs Using Polymer-Based In-Situ Gelled Acids  

E-Print Network [OSTI]

to be white viscous liquids composed of an organic solvent, water, surfactants, and a polymer emulsified in an oil 3 external emulsion. Oil external emulsions, although dependent on the ratios of organic solvent to water, are inherently high in viscosity...??????????????????????.? vii LIST OF FIGURES????????????????????????.? x LIST OF TABLES?????????????????????????? xviii 1. INTRODUCTION???????????????????????. 1 1.1 History of Polymer???????????????????... 2 1.2 Mechanism of Viscosity Build-Up?????????????... 3 1...

Gomaa, Ahmed Mohamed Mohamed

2012-07-16T23:59:59.000Z

126

Semipermeable polymers and method for producing the same  

DOE Patents [OSTI]

A polyamide membrane including reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst, and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant having one ring. A composite semipermeable membrane including the polyamide membrane on a porous support.

Buschmann, Wayne E

2014-04-01T23:59:59.000Z

127

Lightweight polymer concrete composites  

SciTech Connect (OSTI)

Lightweight polymer concrete composites have been developed with excellent insulating properties. The composites consist of lightweight aggregates such as expanded perlites, multicellular glass nodules, or hollow alumina silicate microspheres bound together with unsaturated polyester or epoxy resins. These composites, known as Insulating Polymer Concrete (IPC), have thermal conductivites from 0.09 to 0.19 Btu/h-ft-/sup 0/F. Compressive strengths, dependent upon the aggregates used, range from 1000 to 6000 psi. These materials can be precast or cast-in-place on concrete substrates. Recently, it has been demonstrated that these materials can also be sprayed onto concrete and other substrates. An overlay application of IPC is currently under way as dike insulation at an LNG storage tank facility. The composites have numerous potentials in the construction industry such as insulating building blocks or prefabricated insulating wall panels.

Fontana, J.J.; Steinberg, M.; Reams, W.

1985-08-01T23:59:59.000Z

128

Solid polymer electrolytes  

DOE Patents [OSTI]

This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA); Choe, Hyoun S. (Waltham, MA)

1995-01-01T23:59:59.000Z

129

Solid polymer electrolytes  

DOE Patents [OSTI]

This invention relates to Li ion (Li{sup +}) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF{sub 3}SO{sub 2}){sub 2}, LiAsF{sub 6}, and LiClO{sub 4}. 2 figs.

Abraham, K.M.; Alamgir, M.; Choe, H.S.

1995-12-12T23:59:59.000Z

130

Role of the Na{sup +}/H{sup +} exchanger on the development of diabetes mellitus and its chronic complications  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer NHE protect against intracellular hydrogen overload. Black-Right-Pointing-Pointer NHE protect {beta}-cells against strong acidification. Black-Right-Pointing-Pointer NHE inhibitors improve myocardial ischemia and reperfusion. -- Abstract: Micro- and macrovascular complications are the main cause of morbidity and mortality in diabetes mellitus. The Na{sup +}/H{sup +} exchanger (NHE) is a family of proteins which exchange Na{sup +} for H{sup +} according to their concentration gradients in an electroneutral manner. The exchanger also plays a key role in several other cellular functions including proliferation, differentiation, apoptosis, migration, and cytoskeletal organization. Since not much is known on the relationship between NHE and diabetes mellitus, this review outlines the contribution of NHE to chronic complications of diabetes mellitus, such as diabetic nephropathy; diabetic cardiomyopathy.

Sun, Yan-Ming [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Su, Ying [Department of Endocrinology, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Endocrinology, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Li, Jia; Tian, Ye [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Wang, Lan-Feng, E-mail: wlfccu@126.com [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)

2012-10-19T23:59:59.000Z

131

Polymer Thermodynamics and Chain Structure Polymers display some similarities and some differences with nano-aggregates.  

E-Print Network [OSTI]

for aggregates and by the late Paul Flory of Stanford for polymer coils. Since the spring constant of a polymer of a polymer coil is largely determined by entropy, an individual polymer coil displays an increasing spring an aggregate in nanomaterials and a polymer coil in Polymer Science. The mass-fractal or minimum dimension

Beaucage, Gregory

132

Superconductivity in Metal-mixed Ion-Implanted Polymer Films  

E-Print Network [OSTI]

Ion-implantation of normally insulating polymers offers an alternative to depositing conjugated organics onto plastic films to make electronic circuits. We used a 50 keV nitrogen ion beam to mix a thin 10 nm Sn/Sb alloy film into the sub-surface of polyetheretherketone (PEEK) and report the low temperature properties of this material. We observed metallic behavior, and the onset of superconductivity below 3 K. There are strong indications that the superconductivity does not result from a residual thin-film of alloy, but instead from a network of alloy grains coupled via a weakly conducting, ion-beam carbonized polymer matrix.

A. P. Micolich; E. Tavenner; B. J. Powell; A. R. Hamilton; M. T. Curry; R. E. Giedd; P. Meredith

2006-03-15T23:59:59.000Z

133

Stretched Polymers in Random Environment  

E-Print Network [OSTI]

We survey recent results and open questions on the ballistic phase of stretched polymers in both annealed and quenched random environments.

Dmitry Ioffe; Yvan Velenik

2011-03-01T23:59:59.000Z

134

Photochemical Crosslinking Reactions in Polymers.  

E-Print Network [OSTI]

??The post-synthesis modification of polymer properties has very broad applications in industry. It is employed to produce products that are impossible to directly synthesize, modify… (more)

Carbone, Nicholas

2012-01-01T23:59:59.000Z

135

Photopatterned conjugated polymer electrochromic nanofibers Arvind Kumara  

E-Print Network [OSTI]

Photopatterned conjugated polymer electrochromic nanofibers on paper Arvind Kumara , Chris Asemotaa. Electrochromic nanofibers of conducting polymer (terthiophene) have been deposited over a conventional paper in electrochromic characters. SEM images of the conducting polymer nanofibers together with the cellulose fibers

Otero, Toribio Fernández

136

The application of a new polymer mud to horizontal drilling in the Dagang Oilfield  

SciTech Connect (OSTI)

A new kind of polymer muds, which is generally referred to as the amphionic polymer mud, has been applied to the two horizontal well drilling for the first time in the Dagang Oilfield, located in east China. In this mud system, two amphionic polymers are usually used as the main additives, the one with high molecular weight is an inhibitive encapsuler and filtration control agent, and the other one with low molecular weight is a deflocculant. The amphionic polymer, just as its name, is defined as the polymer that both organic cations and anions simultaneously exist in their molecular chains. The design criteria, formulations and properties of this mud system are discussed. As a case history, the field performance of this new polymer mud in the different sections of the second well (by name Guan H-1, a medium-radius horizontal well) is also given. It was shown from the laboratory and field tests that the amphionic polymer mud not only has all the advantages of the polymer muds commonly used, but is able to overcome the disadvantages of those muds, indicated by its highly inhibitive character while maintaining excellent mud performances. For this reason, the major drilling problems for horizontal wells in the Dagang Oilfield, such as hole cleaning, wellbore stability, lubricity, lost circulation and formation damage, which were hardly solved by the use of other water-based muds, could be solved successfully by the use of the amphionic polymer mud at much lower cost than the oil-based mud.

Yan, J.; Jiang, G.; Zong, R.

1995-10-01T23:59:59.000Z

137

Method for separating water soluble organics from a process stream by aqueous biphasic extraction  

DOE Patents [OSTI]

A method for separating water-miscible organic species from a process stream by aqueous biphasic extraction is provided. An aqueous biphase system is generated by contacting a process stream comprised of water, salt, and organic species with an aqueous polymer solution. The organic species transfer from the salt-rich phase to the polymer-rich phase, and the phases are separated. Next, the polymer is recovered from the loaded polymer phase by selectively extracting the polymer into an organic phase at an elevated temperature, while the organic species remain in a substantially salt-free aqueous solution. Alternatively, the polymer is recovered from the loaded polymer by a temperature induced phase separation (cloud point extraction), whereby the polymer and the organic species separate into two distinct solutions. The method for separating water-miscible organic species is applicable to the treatment of industrial wastewater streams, including the extraction and recovery of complexed metal ions from salt solutions, organic contaminants from mineral processing streams, and colorants from spent dye baths.

Chaiko, David J. (Naperville, IL); Mego, William A. (Naperville, IL)

1999-01-01T23:59:59.000Z

138

Singular Limits in Polymer Stabilized Liquid Crystals  

E-Print Network [OSTI]

We investigate equilibrium configurations for a polymer stabilized liquid crys- tal material ... eling the cross section of the liquid crystal-polymer fiber composite.

1910-31-00T23:59:59.000Z

139

Partially fluorinated cyclic ionic polymers and membranes  

DOE Patents [OSTI]

Ionic polymers are made from selected partially fluorinated dienes, in which the repeat units are cycloaliphatic. The polymers are formed into membranes.

Yang, Zhen-Yu

2013-04-09T23:59:59.000Z

140

Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods and the related working mechanism  

E-Print Network [OSTI]

Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods-to-electrical conversion performances in polymer photovoltaic cells. Totally different improvement factors in short AIP Publishing LLC. [http://dx.doi.org/10.1063/1.4880575] Organic photovoltaic (OPV) cells

Xiong, Qihua

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

DOI: 10.1002/ejic.201000555 Flexible and Redox-Active Coordination Polymer: Control of the Network  

E-Print Network [OSTI]

*[a] Keywords: Coordination polymers / Flexible networks / Macrocyles / Palladium / Nickel The coordination[3a] as well as in the fourfold interpenetrating dia- mondoid network[11] by the reaction of organicFULL PAPER DOI: 10.1002/ejic.201000555 Flexible and Redox-Active Coordination Polymer: Control

Paik Suh, Myunghyun

142

Photovoltaic devices with low band gap polymers Eva Bundgaarda, Sean Shaheenb, David S. Ginleyb, Frederik C. Krebsa  

E-Print Network [OSTI]

Photovoltaic devices with low band gap polymers Eva Bundgaarda, Sean Shaheenb, David S. Ginleyb, Colorado, USA Abstract Progress in organic photovoltaic devices has recently resulted in reported temperature, active area of the device and molecular weight of the polymer, on the photovoltaic response

143

Polymers in a Vacuum  

SciTech Connect (OSTI)

In a variety of situations, isolated polymer molecules are found in a vacuum, and here we examine their properties. Angular momentum conservation is shown to significantly alter the average size of a chain and its conservation is only broken slowly by thermal radiation. For an ideal chain, the time autocorrelation for monomer position oscillates with a period proportional to chain length. The oscillations and damping are analyzed in detail. Short-range repulsive interactions suppress oscillations and speed up relaxation, but stretched chains still show damped oscillatory correlations.

Deutsch, J. M. [Department of Physics, University of California, Santa Cruz, California 95064 (United States)

2007-12-07T23:59:59.000Z

144

Protect Your Heart Against Diabetes  

E-Print Network [OSTI]

Protect Your Heart Against Diabetes Healthy Hearts, Healthy Homes #12;Read other booklets in the Healthy Hearts, Healthy Homes series: Are You at Risk for Heart Disease? Do You Need To Lose Weight? Do Free Web site: www.nhlbi.nih.gov/health/public/heart/other/sp_package.htm For More Information

Bandettini, Peter A.

145

Vacuum flash evaporated polymer composites  

DOE Patents [OSTI]

A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

Affinito, J.D.; Gross, M.E.

1997-10-28T23:59:59.000Z

146

Accelerated Characterization of Polymer Properties  

SciTech Connect (OSTI)

This report describes the efforts to develop a suite of microanalysis techniques that can rapidly measure a variety of polymer properties of industrial importance, including thermal, photo-oxidative, and color stability; as well as ductility, viscosity, and mechanical and antistatic properties. Additional goals of the project were to direct the development of these techniques toward simultaneous measurements of multiple polymer samples of small size in real time using non-destructive and/or parallel or rapid sequential measurements, to develop microcompounding techniques for preparing polymers with additives, and to demonstrate that samples prepared in the microcompounder could be analyzed directly or used in rapid off-line measurements. These enabling technologies are the crucial precursors to the development of high-throughput screening (HTS) methodologies for the polymer additives industry whereby the rate of development of new additives and polymer formulations can be greatly accelerated.

R. Wroczynski; l. Brewer; D. Buckley; M. Burrell; R. Potyrailo

2003-07-30T23:59:59.000Z

147

Oilfield flooding polymer  

DOE Patents [OSTI]

A monomer, polymers containing the monomer, and the use of the polymer in oilfield flooding is disclosed. The subject monomer is represented by the general formula: ##STR1## wherein: n is an integer from 0 to about 4; m is an integer from 0 to about 6; a is an integer equal to at least 1 except where m is equal to 0, a must equal 0 and where m is equal to 1, a must equal 0 or 1; p is an integer from 2 to about 10; b is an integer equal to at least 1 and is of sufficient magnitude that the ratio b/p is at least 0.2; and q is an integer from 0 to 2. The number of hydroxy groups in the monomer is believed to be critical, and therefore the sum of (a+b) divided by the sum (m+p) should be at least 0.2. The moieties linked to the acrylic nitrogen can be joined to provide a ringed structure.

Martin, Fred D. (Socorro, NM); Hatch, Melvin J. (Socorro, NM); Shepitka, Joel S. (Socorro, NM); Donaruma, Lorraine G. (Syosset, NY)

1986-01-01T23:59:59.000Z

148

Beta amyloid and hyperphosphorylated tau deposits in the pancreas in type 2 diabetes  

SciTech Connect (OSTI)

Strong epidemiologic evidence suggests an association between Alzheimer disease (AD) and type 2 diabetes. To determine if amyloid beta (A{beta}) and hyperphosphorylated tau occurs in type 2 diabetes, pancreas tissues from 21 autopsy cases (10 type 2 diabetes and 11 controls) were analyzed. APP and tau mRNAs were identified in human pancreas and in cultured insulinoma beta cells (INS-1) by RT-PCR. Prominent APP and tau bands were detected by Western blotting in pancreatic extracts. Aggregated A{beta}, hyperphosphorylated tau, ubiquitin, apolipoprotein E, apolipoprotein(a), IB1/JIP-1 and JNK1 were detected in Langerhans islets in type 2 diabetic patients. A{beta} was co-localized with amylin in islet amyloid deposits. In situ beta sheet formation of islet amyloid deposits was shown by infrared microspectroscopy (SIRMS). LPS increased APP in non-neuronal cells as well. We conclude that A{beta} deposits and hyperphosphorylated tau are also associated with type 2 diabetes, highlighting common pathogenetic features in neurodegenerative disorders, including AD and type 2 diabetes and suggesting that A{beta} deposits and hyperphosphorylated tau may also occur in other organs than the brain.

Miklossy, J.; Miller, L.; Qing, H.; Radenovic, A.; Kis, A.; Vileno, B.; Laszlo, F.; Martins, R.N.; Waeber, G.; Mooser, V.; Bosman, F.; Khalili, K.; Darbinian, N.; McGeer, P.L.

2008-08-25T23:59:59.000Z

149

Soluble polyacetylenic and polyaromatic polymers and method of mking the same  

DOE Patents [OSTI]

A soluble polyene polymer and a method of making the same are disclosed. The polymer is of the class suitable for doping to produce an electrically conductive polymer. The method is generally applicable to acetylenic and aromatic monomers, proven examples of which include acetylene, benzene, anthracene and napthalene. In accordance with the method, the monomer is dissolved in arsenic trifluoride. Arsenic pentafluoride is then introduced into the solution to induce polymerization by what is speculated to be an ionic polymerization reaction. The resulting polymer differs from other polyene polymers in that it is soluble in common organic solvents, and further in that it can be melted without undergoing decomposition, thereby rendering it particularly suitable for processing to form various polymeric articles.

Aldissi, M.; Liepins, R.

1983-12-16T23:59:59.000Z

150

Free Carrier Generation in Fullerene Acceptors and Its Effect on Polymer Photovoltaics  

E-Print Network [OSTI]

Free Carrier Generation in Fullerene Acceptors and Its Effect on Polymer Photovoltaics George F is this also true for many of the soluble fullerene derivatives commonly used in organic photovoltaics generated by numerous field- dependent techniques. INTRODUCTION In the organic photovoltaic (OPV) community

McGehee, Michael

151

Carbon nanotube-polymer composite actuators  

DOE Patents [OSTI]

The present invention discloses a carbon nanotube (SWNT)-polymer composite actuator and method to make such actuator. A series of uniform composites was prepared by dispersing purified single wall nanotubes with varying weight percents into a polymer matrix, followed by solution casting. The resulting nanotube-polymer composite was then successfully used to form a nanotube polymer actuator.

Gennett, Thomas (Denver, CO); Raffaelle, Ryne P. (Honeoye Falls, NY); Landi, Brian J. (Rochester, NY); Heben, Michael J. (Denver, CO)

2008-04-22T23:59:59.000Z

152

The workshop on conductive polymers: Final report  

SciTech Connect (OSTI)

Reports are made by groups on: polyacetylene, polyphenylene, polyaniline, and related systems; molecular, crystallographic, and defect structures in conducting polymers; heterocyclic polymers; synthesis of new and improved conducting polymers; future applications possibilities for conducting polymers; and challenges for improved understanding of properties. (DLC)

Not Available

1985-01-01T23:59:59.000Z

153

Thermodynamics of tubelike flexible polymers  

E-Print Network [OSTI]

In this work we present the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling methods to simulate small bead-stick polymer models with Lennard-Jones interaction among non-bonded monomers. We analyze energetic fluctuations and structural quantities to classify conformational pseudophases. We find that the tube thickness influences the thermodynamic behavior of simple tubelike polymers significantly, i.e., for given temperature, the formation of secondary structures strongly depends on the tube thickness.

Thomas Vogel; Thomas Neuhaus; Michael Bachmann; Wolfhard Janke

2009-07-17T23:59:59.000Z

154

RESTORING A DAMAGED 16-YEAR -OLD INSULATING POLYMER CONCRETE DIKE OVERLAY: REPAIR MATERIALS AND TECHNOLOGIES.  

SciTech Connect (OSTI)

The objective of this program was to design and formulate organic polymer-based material systems suitable for repairing and restoring the overlay panels of insulating lightweight polymer concrete (ILPC) from the concrete floor and slope wall of a dike at KeySpan liquefied natural gas (LNG) facility in Greenpoint, Brooklyn, NY, just over sixteen years ago. It also included undertaking a small-scale field demonstration to ensure that the commercial repairing technologies were applicable to the designed and formulated materials.

SUGAMA,T.

2007-01-01T23:59:59.000Z

155

Diabetes and breast cancer : the women's healthy eating & living study  

E-Print Network [OSTI]

and their effects on diabetes risk, randomized controlledQiao Q, Zethelius B, et al: Diabetes, prediabetes and cancerS, Lopez A, et al: Diabetes, obesity and survival in a large

Erickson, Kirsten Diann

2011-01-01T23:59:59.000Z

156

Polymer-cement geothermal-well-completion materials. Final report  

SciTech Connect (OSTI)

A program to develop high-temperature polymer cements was performed. Several formulations based on organic and semi-inorganic binders were evaluated on the basis of mechanical and thermal stability, and thickening time. Two optimized systems exhibited properties exceeding those required for use in geothermal wells. Both systems were selected for continued evaluation at the National Bureau of Standards and contingent upon the results, for field testing in geothermal wells.

Zeldin, A.N.; Kukacka, L.E.

1980-07-01T23:59:59.000Z

157

Characterization of macro-length conducting polymers and the development of a conducting polymer rotary motor  

E-Print Network [OSTI]

Conducting polymers are a subset of materials within the electroactive polymer class that exhibit active mechanical deformations. These deformations induce stresses and strains that allow for conducting polymers to be used ...

Schmid, Bryan D. (Bryan David), 1981-

2005-01-01T23:59:59.000Z

158

High elastic modulus polymer electrolytes  

DOE Patents [OSTI]

A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1.times.10.sup.7 Pa and an ionic conductivity of at least 1.times.10.sup.-5 Scm.sup.-1. The electrolyte is made under dry conditions to achieve the noted characteristics.

Balsara, Nitash Pervez; Singh, Mohit; Eitouni, Hany Basam; Gomez, Enrique Daniel

2013-10-22T23:59:59.000Z

159

Polymer electronic devices and materials.  

SciTech Connect (OSTI)

Polymer electronic devices and materials have vast potential for future microsystems and could have many advantages over conventional inorganic semiconductor based systems, including ease of manufacturing, cost, weight, flexibility, and the ability to integrate a wide variety of functions on a single platform. Starting materials and substrates are relatively inexpensive and amenable to mass manufacturing methods. This project attempted to plant the seeds for a new core competency in polymer electronics at Sandia National Laboratories. As part of this effort a wide variety of polymer components and devices, ranging from simple resistors to infrared sensitive devices, were fabricated and characterized. Ink jet printing capabilities were established. In addition to promising results on prototype devices the project highlighted the directions where future investments must be made to establish a viable polymer electronics competency.

Schubert, William Kent; Baca, Paul Martin; Dirk, Shawn M.; Anderson, G. Ronald; Wheeler, David Roger

2006-01-01T23:59:59.000Z

160

Continuous production of conducting polymer  

E-Print Network [OSTI]

A device to continuously produce polypyrrole was designed, manufactured, and tested. Polypyrrole is a conducting polymer which has potential artificial muscle applications. The objective of continuous production was to ...

Gaige, Terry A. (Terry Alden), 1981-

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Layered plasma polymer composite membranes  

DOE Patents [OSTI]

Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is [>=]2 and is the number of selective layers. 2 figs.

Babcock, W.C.

1994-10-11T23:59:59.000Z

162

Polymer Bose--Einstein Condensates  

E-Print Network [OSTI]

In this work we analyze a non--interacting one dimensional polymer Bose--Einstein condensate in an harmonic trap within the semiclassical approximation. We use an effective Hamiltonian coming from the polymer quantization that arises in loop quantum gravity. We calculate the number of particles in order to obtain the critical temperature. The Bose--Einstein functions are replaced by series, whose high order terms are related to powers of the polymer length. It is shown that the condensation temperature presents a shift respect to the standard case, for small values of the polymer scale. In typical experimental conditions, it is possible to establish a bound for $\\lambda^{2}$ up to $ \\lesssim 10 ^{-16}$m$^2$. To improve this bound we should decrease the frequency of the trap and also decrease the number of particles.

E. Castellanos; G. Chacon-Acosta

2013-01-22T23:59:59.000Z

163

Conducting polymer actuators : temperature effects  

E-Print Network [OSTI]

In order to utilize conducting polymer actuators as a viable engineering solution, it is necessary to produce usable levels of force with a reasonable bandwidth. Polypyrrole actuated at temperatures as high as 100 °C ...

Del Zio, Michael R. (Michael Robert), 1982-

2006-01-01T23:59:59.000Z

164

Do Well, Be Well with Diabetes 2014 1 Wrap-Up Form for People with Diabetes Wrap-Up Form for People with Diabetes 2014  

E-Print Network [OSTI]

Do Well, Be Well with Diabetes ­ 2014 1 Wrap-Up Form for People with Diabetes Wrap-Up Form for People with Diabetes ­ 2014 Please complete this form ONLY IF YOU HAVE DIABETES. Thank you. A. The month of my telephone number are __ __ __ __. C. Circle how many Do Well, Be Well Classes you attended? 1 2 3

165

ASSISTANT/ASSOCIATE/FULL PROFESSOR Diabetes, Obesity, Metabolic Disease  

E-Print Network [OSTI]

ASSISTANT/ASSOCIATE/FULL PROFESSOR Diabetes, Obesity, Metabolic Disease Department strengths in diabetes, obesity and metabolic disease. Outstanding candidates with expertise

Cinabro, David

166

High cation transport polymer electrolyte  

DOE Patents [OSTI]

A solid state ion conducting electrolyte and a battery incorporating same. The electrolyte includes a polymer matrix with an alkali metal salt dissolved therein, the salt having an anion with a long or branched chain having not less than 5 carbon or silicon atoms therein. The polymer is preferably a polyether and the salt anion is preferably an alkyl or silyl moiety of from 5 to about 150 carbon/silicon atoms.

Gerald, II, Rex E. (Brookfield, IL); Rathke, Jerome W. (Homer Glen, IL); Klingler, Robert J. (Westmont, IL)

2007-06-05T23:59:59.000Z

167

Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Abstract: Super-absorbent polymers (SAPs) have...

168

High Temperature Polymer Membrane Development at Argonne National...  

Broader source: Energy.gov (indexed) [DOE]

Polymer Membrane Development at Argonne National Laboratory High Temperature Polymer Membrane Development at Argonne National Laboratory Summary of ANL's high temperature polymer...

169

Organic materials and devices for detecting ionizing radiation  

DOE Patents [OSTI]

A .pi.-conjugated organic material for detecting ionizing radiation, and particularly for detecting low energy fission neutrons. The .pi.-conjugated materials comprise a class of organic materials whose members are intrinsic semiconducting materials. Included in this class are .pi.-conjugated polymers, polyaromatic hydrocarbon molecules, and quinolates. Because of their high resistivities (.gtoreq.10.sup.9 ohmcm), these .pi.-conjugated organic materials exhibit very low leakage currents. A device for detecting and measuring ionizing radiation can be made by applying an electric field to a layer of the .pi.-conjugated polymer material to measure electron/hole pair formation. A layer of the .pi.-conjugated polymer material can be made by conventional polymer fabrication methods and can be cast into sheets capable of covering large areas. These sheets of polymer radiation detector material can be deposited between flexible electrodes and rolled up to form a radiation detector occupying a small volume but having a large surface area. The semiconducting polymer material can be easily fabricated in layers about 10 .mu.m to 100 .mu.m thick. These thin polymer layers and their associated electrodes can be stacked to form unique multi-layer detector arrangements that occupy small volume.

Doty, F. Patrick (Livermore, CA); Chinn, Douglas A. (Livermore, CA)

2007-03-06T23:59:59.000Z

170

2 Highly efficient inverted rapid-drying blade-coated organic solar cells 3 Jung-Hao Chang a  

E-Print Network [OSTI]

-coated were demonstrated. Optimized self-organization interpenetration networks 26and donor/acceptor domain organic solar cells (OSCs) based 39 on mixture of conjugated polymers and fullerene deriva- 40 tives have

171

Methods and systems for chemoautotrophic production of organic compounds  

DOE Patents [OSTI]

The present disclosure identifies pathways, mechanisms, systems and methods to confer chemoautotrophic production of carbon-based products of interest, such as sugars, alcohols, chemicals, amino acids, polymers, fatty acids and their derivatives, hydrocarbons, isoprenoids, and intermediates thereof, in organisms such that these organisms efficiently convert inorganic carbon to organic carbon-based products of interest using inorganic energy, such as formate, and in particular the use of organisms for the commercial production of various carbon-based products of interest.

Fischer, Curt R.; Che, Austin J.; Shetty, Reshma P.; Kelly, Jason R.

2013-01-08T23:59:59.000Z

172

Nanostructured polymer membranes for proton conduction  

DOE Patents [OSTI]

Polymers having an improved ability to entrain water are characterized, in some embodiments, by unusual humidity-induced phase transitions. The described polymers (e.g., hydrophilically functionalized block copolymers) have a disordered state and one or more ordered states (e.g., a lamellar state, a gyroid state, etc.). In one aspect, the polymers are capable of undergoing a disorder-to-order transition while the polymer is exposed to an increasing temperature at a constant relative humidity. In some aspects the polymer includes a plurality of portions, wherein a first portion forms proton-conductive channels within the membrane and wherein the channels have a width of less than about 6 nm. The described polymers are capable of entraining and preserving water at high temperature and low humidity. Surprisingly, in some embodiments, the polymers are capable of entraining greater amounts of water with the increase of temperature. The polymers can be used in Polymer Electrolyte Membranes in fuel cells.

Balsara, Nitash Pervez; Park, Moon Jeong

2013-06-18T23:59:59.000Z

173

SUPER HARD SURFACED POLYMERS  

SciTech Connect (OSTI)

High energy ion beam surface treatments were applied to a selected group of polymers. Of the six materials in the present study, four were thermoplastics (polycarbonate, polyethylene, polyethylene terephthalate, and polystyrene) and two were thermosets (epoxy and polyimide). The particular epoxy evaluated in this work is one of the resins used in formulating fiber reinforced composites for military helicopter blades. Measures of mechanical properties of the near surface regions were obtained by nanoindentation hardness and pin on disk wear. Attempts were also made to measure erosion resistance by particle impact. All materials were hardness tested. Pristine materials were very soft, having values in the range of approximately 0.1 to 0.5 GPa. Ion beam treatment increased hardness by up to 50 times compared to untreated materials. For reference, all materials were hardened to values higher than those typical of stainless steels. Wear tests were carried out on three of the materials, PET, PI and epoxy. On the ion beam treated epoxy no wear could be detected, whereas the untreated material showed significant wear.

Mansur, Louis K [ORNL] [ORNL; Bhattacharya, R [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Blau, Peter Julian [ORNL] [ORNL; Clemons, Art [ORNL] [ORNL; Eberle, Cliff [ORNL] [ORNL; Evans, H B [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Janke, Christopher James [ORNL] [ORNL; Jolly, Brian C [ORNL] [ORNL; Lee, E H [Consultant, Milpitas, CA] [Consultant, Milpitas, CA; Leonard, Keith J [ORNL] [ORNL; Trejo, Rosa M [ORNL] [ORNL; Rivard, John D [ORNL] [ORNL

2010-01-01T23:59:59.000Z

174

Propagation of polymer slugs through porous media  

SciTech Connect (OSTI)

This paper describes an experimental and theoretical study of the mechanisms governing polymer slug propagation through porous media. An analytical model taking into account the macromolecule exclusion from pore walls is proposed to predict rodlike polymer velocity in porous media and thus the spreading out of polydispersed polymer slugs. Under conditions where this wall exclusion is maximum, i.e. at low shear rates and polymer concentrations, the experiments show that xanthan propagation is effectively predicted by this model. At higher flow rates and polymer concentrations, the effects of hydrodynamic dispersion and viscous fingering are analyzed. A new fractionation method for determining molecular weight distribution of polymers used in EOR is proposed.

Lecourtier, J.; Chauveteau, G.

1984-09-01T23:59:59.000Z

175

Impact of diabetic serum on endothelial cells: An in-vitro-analysis of endothelial dysfunction in diabetes mellitus type 2  

SciTech Connect (OSTI)

Diabetic endothelial dysfunction was characterized by altered levels of adhesion molecules and cytokines. Aim of our study was to evaluate the effects of diabetic serum on cell-growth and proinflammatory markers in human saphenous vein endothelial cells (HSVEC) from diabetic and non-diabetic patients. Diabetic serum showed (1) complementary proliferative activity for non-diabetic and diabetic HSVEC, (2) unchanged surface expression of adhesion molecules, and (3) elevated levels of sICAM-1 in HSVEC of all donors. The concentration of sVCAM-1 was increased only in diabetic cells. The proinflammatory state of diabetic HSVEC characterized by increased levels of cytokines was compensated. We concluded that even under normoglycemic conditions the serum itself contains critical factors leading to abnormal regulation of inflammation in diabetics. We introduced an in vitro model of diabetes representing the endothelial situation at the beginning of diabetes (non-diabetic cells/diabetic serum) as well as the diabetic chronic state (diabetic cells/diabetic serum)

Muenzel, Daniela [Department of Cardiothoracic Surgery, University Hospital Regensburg, D-93042 Regensburg (Germany); Lehle, Karla [Department of Cardiothoracic Surgery, University Hospital Regensburg, D-93042 Regensburg (Germany)], E-mail: Karla.Lehle@klinik.uni-regensburg.de; Haubner, Frank; Schmid, Christof; Birnbaum, Dietrich E.; Preuner, Juergen G. [Department of Cardiothoracic Surgery, University Hospital Regensburg, D-93042 Regensburg (Germany)

2007-10-19T23:59:59.000Z

176

Enzyme-polymer composites with high biocatalytic activity and stability  

SciTech Connect (OSTI)

We have applied vacuum-spraying and electrospinning to incorporate an enzyme into a polymer matrix, creating a novel and highly active biocatalytic composite. As a unique technical approach, enzymes were co-dissolved in toluene with polymers, and the solvent was then rapidly removed by injecting the mixture into a vacuum chamber or by electrospinning. Subsequent crosslinking of the enzyme with glutaraldehyde resulted in stable entrapped enzyme within the polymeric matrices. For example, an amorphous composite of alpha-chymotrypsin and polyethylene showed no significant loss of enzymatic activity in aqueous buffer for one month. Nanofibers of alpha-chymotrypsin and polystyrene also showed no decrease in activity for more than two weeks. The normalized activity of amorphous composite in organic solvents was 3-13 times higher than that of native alpha-chymotrypsin. The activity of nanofibers was 5-7 times higher than that of amorphous composite in aqueous buffer solution. The composites of alpha-chymotrypsin and polymers demonstrate the feasibility of obtaining a wide variety of active and stable biocatalytic materials with many combinations of enzymes and polymers.

Kim, Jungbae; Kosto, Timothy J.; Manimala, Joseph C.; Nauman, E B.; Dordick, Jonathan S.

2004-08-22T23:59:59.000Z

177

Polymer Grafted Janus Multi-Walled Carbon Nanotubes  

SciTech Connect (OSTI)

We describe a novel and facile strategy to modify the surface of carbon nanotubes (CNTs) with two chemically different polymer brushes utilizing the grafting from technique. A [4 + 2] Diels Alder cycloaddition reaction was used to functionalize multi-walled carbon nanotubes (MWNTs) with two different precursor initiators, one for ring opening polymerization (ROP) and one for atom transfer radical polymerization (ATRP). The binary functionalized MWNTs were used for the simultaneous surface initiated polymerizations of different monomers resulting in polymer grafted MWNTs that can form Janus type structures under appropriate conditions. 1H NMR, FTIR and Raman spectra showed that the precursor initiators were successfully synthesized and covalently attached on the CNT surface. Thermogravimetric analysis (TGA) revealed that the grafted polymer content varies when different monomer ratios and polymerization times are used. The presence of an organic layer around the CNTs was observed through transmission electron microscopy (TEM). Differential scanning calorimetry (DSC) proved that the glass transition (Tg) and melting (Tm) temperatures of the grafted polymers are affected by the presence of the CNTs, while circular dichroism (CD) spectra indicated that the PLLA ahelix conformation remains intact.

Priftis, Dimitrios [ORNL; Sakellariou, Georgios [ORNL; Baskaran, Durairaj [University of Tennessee, Knoxville (UTK); Mays, Jimmy [ORNL; Hadjichristidis, Nikos [University of Athens, Athens, Greece

2009-01-01T23:59:59.000Z

178

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

power conversion efficiency (PCE = ?) of the solar cell ischarge extraction and PCE. For a zero order approximation,seen success in OPVs with PCE between 5-7.4%. 5,22,23 Figure

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

179

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

Photovoltaic Cell .the materials, all photovoltaic cells operate on the basicEquation 1.2) For photovoltaic cells of all kinds and from

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

180

Functional Polymer Architectures for Solution Processed Organic Light Emitting Diodes  

E-Print Network [OSTI]

through formation of the tetrazole from 4-bromobenzonitrile13 5-(4-Bromophenyl)tetrazole, 7 2-(4-tert- Butylphenyl)-5-(

Poulsen, Daniel Andrew

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Stability and flocculation of nanosilica by conventional organic polymer  

E-Print Network [OSTI]

, solar panels, sports equipment, cleaning products and dietary supplements. It is by far the most vastly concentrations of different coagulants and flocculants used were determined by electrophoresis and turbidity potential route to treat other types of NPs. The treatment proposed to reach a ratio of average diameters d

Paris-Sud XI, Université de

182

Special Topics in Organic Chemistry Biorenewable Polymers 8833  

E-Print Network [OSTI]

, conformation, synthesis/ derivatization, reaction mechanisms and application of biomass to: a. Integrated Biorefinery b. Pretreatment Chemistry Lignocellulosics c. SSF/CBP Conversion of Biomass to BioEthanol d. Third

Sherrill, David

183

aligned organic polymer: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

significant signal for nonrandom angles on any scale leq 100h-1Mpc. However, refining the null hypothesis with the Wilcoxon rank-sum test, we found a high confidence...

184

Materials from Renewable Resources Most synthetic organic materials and polymers  

E-Print Network [OSTI]

initiative of the faculties of chemistry and pharmacy, physics, biology, didactics and the Straubing Center complete the activities o To support the resear didactics and the Straubing Center of Science

Schubart, Christoph

185

Ammonia Capture in Porous Organic Polymers Densely Functionalized with  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch HighlightsTools Printable Version Share thisToolsatturbines

186

Organic Polymers Show Sunny Potential | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics Group (X-ray ScienceMicroflows.coal4.00ReclamationA

187

Multi-Walled Carbon Nanotubes-Modified Polymer Organic Photovoltaics.  

E-Print Network [OSTI]

??Since the carbon nanotubes were first discovered by Iijima in 1991, CNTs have been the focus of intense research by many groups. Nearly 7000 papers… (more)

Chen, Tzu-Fan

2009-01-01T23:59:59.000Z

188

Gain properties of dye-doped polymer thin films  

E-Print Network [OSTI]

The demonstration of an electrically pumped organic laser remains a major issue of organic optoelectronics for several decades. Nowadays, hybrid pumping seems a promising compromise where the organic material is optically pumped by an electrically pumped inorganic device on chip. This technical solution requires therefore an optimization of the organic gain medium under optical pumping. Here, we report a detailed study of gain features of dye-doped polymer thin films, in particular we introduce the gain efficiency $K$, in order to facilitate comparison between material and experimental conditions. First, we measure the bulk gain by the means of a pump-probe setup, and then present in details several factors which modify the actual gain of the layer, namely the confinement factor, the pump polarization, the molecular anisotropy, and the re-absorption. The usual model to evaluate the gain leads to an overestimation by more than one order of magnitude, which stresses the importance to design the devices accordin...

Gozhyk, I; Rabbani, H; Djellali, N; Forget, S; Chenais, S; Ulysse, C; Brosseau, A; Gauvin, S; Zyss, J; Lebental, M

2014-01-01T23:59:59.000Z

189

Polymer Welding: Strength Through Entanglements  

E-Print Network [OSTI]

Large-scale simulations of thermal welding of polymers are performed to investigate the rise of mechanical strength at the polymer-polymer interface with the welding time. The welding process is in the core of integrating polymeric elements into devices as well as in thermal induced healing of polymers; processes that require development of interfacial strength equal to that of the bulk. Our simulations show that the interfacial strength saturates at the bulk shear strength much before polymers diffuse by their radius of gyration. Along with the strength increase, the dominant failure mode changes from chain pullout at the interface to chain scission as in the bulk. Formation of sufficient entanglements across the interface, which we track using a Primitive Path Analysis is required to arrest catastrophic chain pullout at the interface. The bulk response is not fully recovered until the density of entanglements at the interface reaches the bulk value. Moreover, the increase of interfacial strength before saturation is proportional to the number of interfacial entanglements between chains from opposite sides.

Ting Ge; Flint Pierce; Dvora Perahia; Gary S. Grest; Mark O. Robbins

2012-11-29T23:59:59.000Z

190

Gamification to Improve Adherence to Diabeteic Treatment in Saudi Arabia  

E-Print Network [OSTI]

Gamification to Improve Adherence to Diabeteic Treatment in Saudi Arabia Alaa Abdullah Al, proposes the first Arabic system for managing diabetes using gamification. Keywords-component; Diabetes; Gamification; Self-Care; e- Healthcare I. INTRODUCTION Diabetes mellitus is one of the most common illnesses

191

Solvent-enhanced Dye Diffusion in Polymer This-Films for OLED Application F. Pschenitzka, K. Long, and J. C. Sturm  

E-Print Network [OSTI]

Solvent-enhanced Dye Diffusion in Polymer This-Films for OLED Application F. Pschenitzka, K. Long (POEM), Princeton University, Princeton, NJ 08544 ABSTRACT A method of solvent-enhanced dye diffusion in polymer films for organic light-emitting diode (OLED) application is introduced. After an initial dye

192

Process to produce lithium-polymer batteries  

DOE Patents [OSTI]

A polymer bonded sheet product is described suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance. 1 fig.

MacFadden, K.O.

1998-06-30T23:59:59.000Z

193

Transports of Polymer Nanomedicine in the Environment  

E-Print Network [OSTI]

With increasing production and commercial use of polymer nanomedicine and a lack of regulation to govern their disposal, polymer nanomedicine may enter into soils and ultimately into ground water system. In this dissertation, adsorption of polymeric...

Zhang, Ming

2013-11-14T23:59:59.000Z

194

Modeling and Optimization of Interpenetrating Polymer  

E-Print Network [OSTI]

Modeling and Optimization of Interpenetrating Polymer Network Process Weijie Lin, Lorenz T. Biegler. Crosslinking Features Complex diffusion; single component reaction Complex composite networking reaction · Initiator feeding rate · Initial polymer · Monomer concentration · Initiator concentration · Holding

Grossmann, Ignacio E.

195

Process to produce lithium-polymer batteries  

DOE Patents [OSTI]

A polymer bonded sheet product suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance.

MacFadden, Kenneth Orville (Highland, MD)

1998-01-01T23:59:59.000Z

196

Solvent-enhanced dye diffusion in polymer thin films for polymer light-emitting diode application  

E-Print Network [OSTI]

Solvent-enhanced dye diffusion in polymer thin films for polymer light-emitting diode application 2004; accepted 24 August 2004) The method of solvent-enhanced dye diffusion for patterning full dry transfer of dye onto a device polymer film, the dye remains on the surface of the polymer layer

197

Unwinding relaxation dynamics of polymers  

E-Print Network [OSTI]

The relaxation dynamics of a polymer wound around a fixed obstacle constitutes a fundamental instance of polymer with twist and torque and it is of relevance also for DNA denaturation dynamics. We investigate it by simulations and Langevin equation analysis. The latter predicts a relaxation time scaling as a power of the polymer length times a logarithmic correction related to the equilibrium fluctuations of the winding angle. The numerical data support this result and show that at short times the winding angle decreases as a power-law. This is also in agreement with the Langevin equation provided a winding-dependent friction is used, suggesting that such reduced description of the system captures the basic features of the problem.

Jean-Charles Walter; Marco Baiesi; Gerard Barkema; Enrico Carlon

2013-01-13T23:59:59.000Z

198

Post polymerization cure shape memory polymers  

DOE Patents [OSTI]

This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

Wilson, Thomas S; Hearon, Michael Keith; Bearinger, Jane P

2014-11-11T23:59:59.000Z

199

Anion exchange polymer electrolytes  

DOE Patents [OSTI]

Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: ##STR00001## wherein: i) A is a spacer having the structure O, S, SO.sub.2, --NH--, --N(CH.sub.2).sub.n, wherein n=1-10, --(CH.sub.2).sub.n--CH.sub.3--, wherein n=1-10, SO.sub.2-Ph, CO-Ph, ##STR00002## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are independently --H, --NH.sub.2, F, Cl, Br, CN, or a C.sub.1-C.sub.6 alkyl group, or any combination of thereof; ii) R.sub.9, R.sub.10, R.sub.11, R.sub.12, or R.sub.13 each independently are --H, --CH.sub.3, --NH.sub.2, --NO, --CH.sub.nCH.sub.3 where n=1-6, HC.dbd.O--, NH.sub.2C.dbd.O--, --CH.sub.nCOOH where n=1-6, --(CH.sub.2).sub.n--C(NH.sub.2)--COOH where n=1-6, --CH--(COOH)--CH.sub.2--COOH, --CH.sub.2--CH(O--CH.sub.2CH.sub.3).sub.2, --(C.dbd.S)--NH.sub.2, --(C.dbd.NH)--N--(CH.sub.2).sub.nCH.sub.3, where n=0-6, --NH--(C.dbd.S)--SH, --CH.sub.2--(C.dbd.O)--O--C(CH.sub.3).sub.3, --O--(CH.sub.2).sub.n--CH--(NH.sub.2)--COOH, where n=1-6, --(CH.sub.2).sub.n--CH.dbd.CH wherein n=1-6, --(CH.sub.2).sub.n--CH--CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.

Kim, Yu Seung; Kim, Dae Sik; Lee, Kwan-Soo

2013-07-23T23:59:59.000Z

200

Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes  

DOE Patents [OSTI]

A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

2003-06-03T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Novel polyoxazolines polymer drug delivery platform  

E-Print Network [OSTI]

performed with 4 different polymers in multi- drug resistant (MCF7/ADR) human adenocarcinoma cells, non-resistant (MCF7) human adenocarcinoma cells and Madin-Darby canine kidney (MDCK) cells. All polymers were found lines. 2. To investigate the effect of the addition of drugs to the polymers on cell toxicity, micelles

202

Organosiloxane-grafted natural polymer coatings  

DOE Patents [OSTI]

A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.

Sugama, Toshifumi (Wading River, NY)

1998-01-01T23:59:59.000Z

203

Modeling and Optimization for Interpenetrating polymer  

E-Print Network [OSTI]

Modeling and Optimization for Interpenetrating polymer network process 1 Weijie Lin, Lorenz T #12;Project Overview · IPN Interpenetrating polymer network ­ A combination of two polymers in a network form Fig. 2 An IPN process example · Typical Sequential Type of Process Fig. 1 IPN network

Grossmann, Ignacio E.

204

Transport characteristics across drum filter vents and polymer bags  

SciTech Connect (OSTI)

The rate at which hydrogen (H {sub 2}) or a volatile organic compound (VOC) exits a layer of confinement in a vented waste drum is proportional to the concentration difference across the layer. The proportionality constant is the gas transport characteristic. A series of transport experiments were conducted to determine H{sub 2} and VOC transport characteristics across different drum filter vents and polymer bags. This report reviews the methods and results of past investigators in defining transport characteristics across filter vents and polymer bags, describes the apparatus and procedures used in these experiments, compares the reported and estimated transport characteristics with earlier results, and discusses the impact of changing the transport characteristic values used in model calculations.

Liekhus, K.J.

1994-08-01T23:59:59.000Z

205

Water-soluble conductive polymers  

DOE Patents [OSTI]

Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

Aldissi, M.

1988-02-12T23:59:59.000Z

206

Water-soluble conductive polymers  

DOE Patents [OSTI]

Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

Aldissi, Mahmoud (Sante Fe, NM)

1989-01-01T23:59:59.000Z

207

Water-soluble conductive polymers  

DOE Patents [OSTI]

Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

Aldissi, Mahmoud (Sante Fe, NM)

1990-01-01T23:59:59.000Z

208

Friction between Ring Polymer Brushes  

E-Print Network [OSTI]

Friction between ring-polymer brushes at melt densities sliding past each other are studied using extensive course-grained molecular dynamics simulations and scaling arguments, and the results are compared to the friction between linear-polymer brushes. We show that for a velocity range spanning over three decades, the frictional forces measured for ring-polymer brushes are half the corresponding friction in case of linear brushes. In the linear-force regime, the weak inter-digitation of two ring brushes compared to linear brushes also leads to a lower number of binary collisions between the monomers of opposing brushes. At high velocities, where the thickness of the inter-digitation layer between two opposing brushes is on the order monomer size regardless of brush topology, stretched segments of ring polymers take a double-stranded conformation. As a result, monomers of the double-stranded segments collide less with the monomers of the opposing ring brush even though a similar number of monomers occupies the inter-digitation layer for ring and linear-brush bilayers. The numerical data obtained from our simulations is consistent with the proposed scaling analysis. Conformation-dependent frictional reduction observed in ring brushes can have important consequences in non-equilibrium bulk systems.

A. Erbas; J. Paturej

2015-01-07T23:59:59.000Z

209

Enhanced photophysics of conjugated polymers  

DOE Patents [OSTI]

A particulate fluorescent conjugated polymer surfactant complex and method of making and using same. The particles are between about 15 and about 50 nm and when formed from a lipsome surfactant have a charge density similar to DNA and are strongly absorbed by cancer cells.

Chen, Liaohai (Darien, IL)

2007-06-12T23:59:59.000Z

210

Stretching of polymers in a turbulent environment  

E-Print Network [OSTI]

The interaction of polymers with small-scale velocity gradients can trigger a coil-stretch transition in the polymers. We analyze this transition within a direct numerical simulation of shear turbulence with an Oldroyd-B model for the polymer. In the coiled state the lengths of polymers are distributed algebraically with an exponent alpha=2 gamma-1/De, where gamma is a characteristic stretching rate of the flow and De the Deborah number. In the stretched state we demonstrate that the length distribution of the polymers is limited by the feedback to the flow.

Bruno Eckhardt; Jochen Kronjaeger; Joerg Schumacher

2002-01-20T23:59:59.000Z

211

Method of forming a foamed thermoplastic polymer  

DOE Patents [OSTI]

A solid thermoplastic polymer is immersed in an immersant solution comprising a compatible carrier solvent and an infusant solution containing an incompatible liquid blowing agent for a time sufficient for the immersant solution to infuse into the polymer. The carrier solvent is then selectively extracted, preferably by a solvent exchange process in which the immersant solution is gradually diluted with and replaced by the infusant solution, so as to selectively leave behind the infustant solution permanently entrapped in the polymer. The polymer is then heated to volatilize the blowing agent and expand the polymer into a foamed state.

Duchane, D.V.; Cash, D.L.

1984-11-21T23:59:59.000Z

212

Arginine metabolism in enterocytes of diabetic rats  

E-Print Network [OSTI]

Diabetic rats and patients exhibit decreased plasma arginine concentrations. Arginine is important in numerous cellular pathways, including the synthesis of nitric oxide and the release of insulin from pancreatic ? cells. At present, little...

Morrow, Natalie Anne

2002-01-01T23:59:59.000Z

213

Ghrelin reverses experimental diabetic neuropathy in mice  

SciTech Connect (OSTI)

Ghrelin, an acylated peptide produced in the stomach, increases food intake and growth hormone secretion, suppresses inflammation and oxidative stress, and promotes cell survival and proliferation. We investigated the pharmacological potential of ghrelin in the treatment of polyneuropathy in uncontrolled streptozotocin (STZ)-induced diabetes in mice. Ghrelin or desacyl-ghrelin was administered daily for 4 weeks after STZ-induced diabetic polyneuropathy had developed. Ghrelin administration did not alter food intake, body weight gain, blood glucose levels, or plasma insulin levels when compared with mice given saline or desacyl-ghrelin administration. Ghrelin administration ameliorated reductions in motor and sensory nerve conduction velocities in diabetic mice and normalized their temperature sensation and plasma concentrations of 8-isoprostaglandin {alpha}, an oxidative stress marker. Desacyl-ghrelin failed to have any effect. Ghrelin administration in a mouse model of diabetes ameliorated polyneuropathy. Thus, ghrelin's effects represent a novel therapeutic paradigm for the treatment of this otherwise intractable disorder.

Kyoraku, Itaru; Shiomi, Kazutaka [Division of Neurology, Respirology, Endocrinology and Metabolism, Department of Internal Medicine, Faculty of Medicine, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan)] [Division of Neurology, Respirology, Endocrinology and Metabolism, Department of Internal Medicine, Faculty of Medicine, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan); Kangawa, Kenji [Department of Biochemistry, National Cardiovascular Center Research Institute, Osaka 565-8565 (Japan)] [Department of Biochemistry, National Cardiovascular Center Research Institute, Osaka 565-8565 (Japan); Nakazato, Masamitsu, E-mail: nakazato@med.miyazaki-u.ac.jp [Division of Neurology, Respirology, Endocrinology and Metabolism, Department of Internal Medicine, Faculty of Medicine, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan)] [Division of Neurology, Respirology, Endocrinology and Metabolism, Department of Internal Medicine, Faculty of Medicine, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan)

2009-11-20T23:59:59.000Z

214

Polymer compositions, polymer films and methods and precursors for forming same  

DOE Patents [OSTI]

Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 .mu.m and about 30 .mu.m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.

Klaehn, John R; Peterson, Eric S; Orme, Christopher J

2013-09-24T23:59:59.000Z

215

Oxidative and initiated chemical vapor deposition for application to organic electronics  

E-Print Network [OSTI]

Since the first discovery of polymeric conductors in 1977, the research area of "organic electronics" has grown dramatically. However, methods for forming thin films comprised solely of conductive polymers are limited by ...

Im, Sung Gap

2009-01-01T23:59:59.000Z

216

Laboratory Thin-Film Encapsulation of Air-Sensitive Organic Semiconductor Devices  

E-Print Network [OSTI]

We present an approach, which is compatible with both glass and polymer substrates, to in-laboratory handling and intra-laboratory shipping of air-sensitive organic semiconductors. Encapsulation approaches are presented ...

Subbarao, Samuel P.

217

Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties  

SciTech Connect (OSTI)

Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li, E-mail: wangxiuli@bhu.edu.cn

2013-09-15T23:59:59.000Z

218

Internal dissipation of a polymer  

SciTech Connect (OSTI)

The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics of a single chain in the absence of solvent to characterize the nature of this internal friction. We model the chains as freely hinged but with localized bond angles and threefold symmetric dihedral angles. We show that the damping is close but not identical to Kelvin damping, which depends on the first temporal and second spatial derivative of monomer position. With no internal potential between monomers, the magnitude of the damping is small for long wavelengths and weakly damped oscillatory time dependent behavior is seen for a large range of spatial modes. When the size of the internal potential is increased, such oscillations persist, but the damping becomes larger. However underdamped motion is present even with quite strong dihedral barriers for long enough wavelengths.

Deutsch, J. M. [Department of Physics, University of California, Santa Cruz, California 95064 (United States)

2010-06-15T23:59:59.000Z

219

Water-thinnable polymers for durable coatings for different materials  

SciTech Connect (OSTI)

The methods of obtaining water-thinnable polymers - water-thinnable unsaturated polyester resins (WTUPR) - by polycondensation were elaborate and optimized. As hydrophilic monomers different types of sulfonate monomers were used. The monomers, with sulfonate groups and other reactive groups, were obtained by sulfonation of organic compounds with satisfactory yield. All products were analyzed by {sup 1}H NMR and {sup 13}C NMR spectra. WTUPR were used as polymeric binders for coatings applications. Coatings with relatively high pendulum hardness, good properties and durability, useful for practical applications, were obtained. Typical existing equipment for the production of unsaturated polyester resins can be applied for the industrial preparation of WTUPR.

Jankowski, Piotr, E-mail: piotr.jankowski@ichp.pl; Kijowska, Dorota, E-mail: piotr.jankowski@ichp.pl [Industrial Chemistry Research Institute, Department of Polyesters, Epoxides and Polyurethanes, 8 Rydygiera Str., 01-793 Warszawa (Poland)

2014-05-15T23:59:59.000Z

220

Diamond turning of thermoplastic polymers  

SciTech Connect (OSTI)

Single point diamond turning studies were made using a series of thermoplastic polymers with different glass transition temperatures. Variations in surface morphology and surface roughness were observed as a function of cutting speed. Lower glass transition temperatures facilitate smoother surface cuts and better surface finish. This can be attributed to the frictional heating that occurs during machining. Because of the very low glass transition temperatures in polymeric compared to inorganic glasses, the precision machining response can be very speed sensitive.

Smith, E.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

Fontana, J.J.; Elling, D.; Reams, W.

1988-05-26T23:59:59.000Z

222

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

1990-01-01T23:59:59.000Z

223

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, J.J.; Elling, D.; Reams, W.

1990-03-13T23:59:59.000Z

224

Model-based experimental analysis for inter-polymer process  

E-Print Network [OSTI]

) + Polyethylene (PE) ARCEL TOUGH FLEXIBLE Advanced packaging material Interpenetrating polymer network productModel-based experimental analysis for inter-polymer process CMU: Weijie Lin, Lorenz T. Biegler processed in a sequential way Polymer A Polymer B Project overview Inter-polymer process #12;Project

Grossmann, Ignacio E.

225

Organic geochemistry and organic petrography  

SciTech Connect (OSTI)

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

226

NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

Fondeur, F.; Peters, T.; Fink, S.

2011-09-29T23:59:59.000Z

227

Tritium containing polymers having a polymer backbone substantially void of tritium  

DOE Patents [OSTI]

A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium.

Jensen, George A. (Richland, WA); Nelson, David A. (Richland, WA); Molton, Peter M. (Richland, WA)

1992-01-01T23:59:59.000Z

228

Tritium containing polymers having a polymer backbone substantially void of tritium  

DOE Patents [OSTI]

A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium. 2 figs.

Jensen, G.A.; Nelson, D.A.; Molton, P.M.

1992-03-31T23:59:59.000Z

229

Asphaltenes-based polymer nano-composites  

DOE Patents [OSTI]

Inventive composite materials are provided. The composite is preferably a nano-composite, and comprises an asphaltene, or a mixture of asphaltenes, blended with a polymer. The polymer can be any polymer in need of altered properties, including those selected from the group consisting of epoxies, acrylics, urethanes, silicones, cyanoacrylates, vulcanized rubber, phenol-formaldehyde, melamine-formaldehyde, urea-formaldehyde, imides, esters, cyanate esters, allyl resins.

Bowen, III, Daniel E

2013-12-17T23:59:59.000Z

230

Organosiloxane-grafted natural polymer coatings  

DOE Patents [OSTI]

A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation. 17 figs.

Sugama, Toshifumi

1998-12-01T23:59:59.000Z

231

Organic Superconductors  

SciTech Connect (OSTI)

Intense magnetic fields are an essential tool for understanding layered superconductors. Fundamental electronic properties of organic superconductors are revealed in intense (60 tesla) magnetic fields. Properties such as the topology of the Fermi surface and the nature of the superconducting order parameter are revealed. With modest maximum critical temperatures~13K the charge transfer salt organic superconductors prove to be incredibly valuable materials as their electronically clean nature and layered (highly anisotropic) structures yield insights to the high temperature superconductors. Observation of de Haas-van Alphen and Shubnikov-de Haas quantum oscillatory phenomena, magnetic field induced superconductivity and re-entrant superconductivity are some of the physical phenomena observed in the charge transfer organic superconductors. In this talk, I will discuss the nature of organic superconductors and give an overview of the generation of intense magnetic fields; from the 60 tesla millisecond duration to the extreme 1000 tesla microsecond pulsed magnetic fields.

Charles Mielke

2009-02-27T23:59:59.000Z

232

Cadmium, diabetes and chronic kidney disease  

SciTech Connect (OSTI)

Recent epidemiological studies suggest a positive association between exposure to the environmental pollutant cadmium (Cd) and the incidence and severity of diabetes. In this review, we examine the literature suggesting a relationship between Cd exposure, elevated blood glucose levels, and the development of diabetes. In addition we review human and animal studies indicating that Cd potentiates or exacerbates diabetic nephropathy. We also review the various possible cellular mechanisms by which Cd may alter blood glucose levels. In addition, we present some novel findings from our own laboratories showing that Cd elevates fasting blood glucose levels in an animal model of subchronic Cd exposure before overt signs of renal dysfunction are evident. These studies also show that Cd reduces insulin levels and has direct cytotoxic effects on the pancreas. Together, these findings indicate that Cd may be a factor in the development of some types of diabetes and they raise the possibility that Cd and diabetes-related hyperglycemia may act synergistically to damage the kidney.

Edwards, Joshua R. [Department of Pharmacology, Midwestern University, Downers Grove, IL 60515 (United States)], E-mail: jedwar@midwestern.edu; Prozialeck, Walter C. [Department of Pharmacology, Midwestern University, Downers Grove, IL 60515 (United States)

2009-08-01T23:59:59.000Z

233

Conducting polymer actuator enhancement through microstructuring  

E-Print Network [OSTI]

Electroactive conducting polymers, such as polypyrrole, polyaniline, and polythiophenes are currently studied as novel biologically inspired actuators. The actuation mechanisms in these materials are based on the diffusion ...

Pillai, Priam Vasudevan

2007-01-01T23:59:59.000Z

234

Fabrication and characterization of conducting polymer microwires  

E-Print Network [OSTI]

Flexible microwires fabricated from conducting polymers have a wide range of potential applications, including smart textiles that incorporate sensing, actuation, and data processing. The development of garments that ...

Saez, Miguel Angel

2009-01-01T23:59:59.000Z

235

Imaging Hydrated Microbial Extracellular Polymers: Comparative...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dehydration-based sample preparation that resulted in the collapse of hydrated gel-like EPS into filamentous structures. Dehydration-induced polymer collapse can lead to...

236

Conformational properties of polymers in anisotropic environments  

E-Print Network [OSTI]

We analyze the conformational properties of polymer macromolecules in solutions in presence of extended structural obstacles of (fractal) dimension $\\varepsilon_d$ causing the anisotropy of environment. Applying the pruned-enriched Rosenbluth method (PERM), we obtain numerical estimates for scaling exponents and universal shape parameters of polymers in such environments for a wide range $0<\\varepsilon_d<2$ in space dimension $d=3$. An analytical description of the model is developed within the des Cloizeaux direct polymer renormalization scheme. Both numerical and analytical studies qualitatively confirm the existence of two characteristic length scales of polymer chain in directions parallel and perpendicular to the extended defects.

K. Haydukivska; V. Blavatska

2014-07-11T23:59:59.000Z

237

Polymer escape from a confining potential  

E-Print Network [OSTI]

The rate of escape of polymers from a two-dimensionally confining potential well has been evaluated using self-avoiding as well as ideal chain representations of varying length, up to 80 beads. Long timescale Langevin trajectories were calculated using the path integral hyperdynamics method to evaluate the escape rate. A minimum is found in the rate for self-avoiding polymers of intermediate length while the escape rate decreases monotonically with polymer length for ideal polymers. The increase in the rate for long, self-avoiding polymers is ascribed to crowding in the potential well which reduces the free energy escape barrier. An effective potential curve obtained using the centroid as an independent variable was evaluated by thermodynamic averaging and Kramers rate theory then applied to estimate the escape rate. While the qualitative features are well reproduced by this approach, it significantly overestimates the rate, especially for the longer polymers. The reason for this is illustrated by constructing a two-dimensional effective energy surface using the radius of gyration as well as the centroid as controlled variables. This shows that the description of a transition state dividing surface using only the centroid fails to confine the system to the region corresponding to the free energy barrier and this problem becomes more pronounced the longer the polymer is. A proper definition of a transition state for polymer escape needs to take into account the shape as well as the location of the polymer.

Harri Mökkönen; Timo Ikonen; Tapio Ala-Nissila; Hannes Jónsson

2015-03-26T23:59:59.000Z

238

Localized domain patterns in complex polymers  

E-Print Network [OSTI]

Localized domain patterns in complex polymers abstract. Block copolymers are macromolecules that can form variety of microstructures as a result of incomplete

239

ELECTROSPUN POLYMER-FIBER SOLAR CELL.  

E-Print Network [OSTI]

??A study of fabricating the first electrospun polymer-fiber solar cell with MEHPPV is presented. Motivation for the work and a brief history of solar cell… (more)

Nagata, Shinobu

2011-01-01T23:59:59.000Z

240

EFFECTS OF TRITIUM GAS EXPOSURE ON POLYMERS  

SciTech Connect (OSTI)

Effects of tritium gas exposure on various polymers have been studied over the last several years. Despite the deleterious effects of beta exposure on many material properties, structural polymers continued to be used in tritium systems. Improved understanding of the tritium effects will allow more resistant materials to be selected. Currently polymers find use mainly in tritium gas sealing applications (eg. valve stem tips, O-rings). Future uses being evaluated including polymeric based cracking of tritiated water, and polymer-based sensors of tritium.

Clark, E.; Fox, E.; Kane, M.; Staack, G.

2011-01-07T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Conjugated Amplifying Polymers for Optical Sensing Applications  

E-Print Network [OSTI]

Thanks to their unique optical and electrochemical properties, conjugated polymers have attracted considerable attention over the last two decades and resulted in numerous technological innovations. In particular, their ...

Rochat, Sebastien

242

Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene are common  

E-Print Network [OSTI]

Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene are common commercial materials used for consumer products. Polyethylene is the most widely used polymer due and processing conditions. Equistar, in Cincinnati, is the largest producer of polyethylene in the US and P

Beaucage, Gregory

243

Laser Processing of Metals and Polymers  

SciTech Connect (OSTI)

A laser offers a unique set of opportunities for precise delivery of high quality coherent energy. This energy can be tailored to alter the properties of material allowing a very flexible adjustment of the interaction that can lead to melting, vaporization, or just surface modification. Nowadays laser systems can be found in nearly all branches of research and industry for numerous applications. Sufficient evidence exists in the literature to suggest that further advancements in the field of laser material processing will rely significantly on the development of new process schemes. As a result they can be applied in various applications starting from fundamental research on systems, materials and processes performed on a scientific and technical basis for the industrial needs. The interaction of intense laser radiation with solid surfaces has extensively been studied for many years, in part, for development of possible applications. In this thesis, I present several applications of laser processing of metals and polymers including polishing niobium surface, producing a superconducting phase niobium nitride and depositing thin films of niobium nitride and organic material (cyclic olefin copolymer). The treated materials were examined by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), atomic force microscopy (AFM), high resolution optical microscopy, surface profilometry, Fourier transform infrared spectroscopy (FTIR) and x-ray diffraction (XRD). Power spectral density (PSD) spectra computed from AFM data gives further insight into the effect of laser melting on the topography of the treated niobium.

Senthilraja Singaravelu

2012-05-31T23:59:59.000Z

244

Heat Transfer Study of Polymer Solutions with Different Rigidities  

E-Print Network [OSTI]

rigidities. A mathematic method was introduced to model the rigidity of polymer chain's effect on the dynamic viscosity of dilute polymer solution. Results were also obtained for the dilute polymer solutions under both hydro-dynamically developing and hydro...

Huang, Yao

2014-05-08T23:59:59.000Z

245

New Polymer Architectures for Imidazole Solvating groups, Anion...  

Broader source: Energy.gov (indexed) [DOE]

Polymer - Li Metalpolymer & Fuel Cells -High Temp PEM (150 0 C) Gel Polymer - Li Ion and Fuel Cell Li + Li + Li + X - X - X - Network Backbone may be polymer or inorganic. Free...

246

Modeling Cold Start in a Polymer-Electrolyte Fuel Cell  

E-Print Network [OSTI]

conditions used for fuel—cell simulations. 3.12 Values usedin Polymer Electrolyte Fuel Cells — II. Parametric Study,”of Polymer Electrolyte Fuel Cells,” Electrochimica Acta, 53,

Balliet, Ryan

2010-01-01T23:59:59.000Z

247

New Polymer Architectures for Imidazole Solvating groups, Anion...  

Broader source: Energy.gov (indexed) [DOE]

New Polymer Architectures for Imidazole Solvating groups, Anion Mobility and Flexibility New Polymer Architectures for Imidazole Solvating groups, Anion Mobility and Flexibility...

248

Development of a Low Cost Ultra Specular Advanced Polymer Film...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Development of a Low Cost Ultra Specular Advanced Polymer Film Solar Reflector Development of a Low Cost Ultra Specular Advanced Polymer Film Solar Reflector This presentation was...

249

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2012 DOE Hydrogen and Fuel Cells Program and...

250

Fabrication and performance of polymer-nanocomposite anti-reflective...  

Office of Scientific and Technical Information (OSTI)

News, VA (United States) Design of polymer anti-reflective (AR) optical coatings for plastic substrates is challenging because polymers exhibit a relatively narrow range of...

251

Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal Sepsis by Multidrug-Resistant Pathogens. Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal Sepsis by...

252

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...  

Broader source: Energy.gov (indexed) [DOE]

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2013 DOE Hydrogen and Fuel Cells Program and...

253

Development of Polymer Electrolytes for Advanced Lithium Batteries...  

Broader source: Energy.gov (indexed) [DOE]

Development of Polymer Electrolytes for Advanced Lithium Batteries Development of Polymer Electrolytes for Advanced Lithium Batteries 2013 DOE Hydrogen and Fuel Cells Program and...

254

acid polymers highly: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Highly Porous Catalytic Layers for Polymer Electrolyte Fuel Cell Based on Carbon Aerogels Physics Websites Summary: Synthesis of Highly Porous Catalytic Layers for Polymer...

255

azo dye polymer: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alignment 10 Solvent-enhanced dye diffusion in polymer thin films for polymer light-emitting diode application Engineering Websites Summary: Solvent-enhanced dye diffusion in...

256

Self-Assembly of Polymer Nano-Elements on Sapphire  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Assembly of Polymer Nano-Elements on Sapphire Print Self-assembly of polymers promises to vastly improve the properties and manufacturing processes of nanostructured...

257

High temperature polymer concrete compositions  

DOE Patents [OSTI]

This invention is concerned with a polymer concrete composition, which is a two-component composition useful with many bases including metal. Component A, the aggregate composition, is broadly composed of silica, silica flour, portland cement, and acrylamide, whereas Component B, which is primarily vinyl and acrylyl reactive monomers, is a liquid system. A preferred formulation emphasizing the major necessary components is as follows: ______________________________________ Component A: Silica sand 60-77 wt. % Silica flour 5-10 wt. % Portland cement 15-25 wt. % Acrylamide 1-5 wt. % Component B: Styrene 50-60 wt. % Trimethylolpropane 35-40 wt. % trimethacrylate ______________________________________ and necessary initiators, accelerators, and surfactants.

Fontana, Jack J. (Shirley, NY); Reams, Walter (Shirley, NY)

1985-01-01T23:59:59.000Z

258

Miscibility Evaluation Of The Next Generation Solvent With Polymers Currently Used At DWPF, MCU, And Saltstone  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, funded the development of an enhanced Caustic-Side Solvent Extraction (CSSX) solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. This effort lead to the development of the Next Generation Solvent (NGS) with Tris (3,7-dimethyl octyl) guanidine (TiDG). The first deployment target for the NGS solvent is within the Modular CSSX Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the new chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the affected facility. This report provides the calculated data from exposing these polymers to the Next Generation Solvent. An assessment of the dimensional stability of polymers known to be used or present in the MCU, Defense Waste Processing Facility (DWPF), and Saltstone facilities that will be exposed to the NGS showed that TiDG could selectively affect the elastomers and some thermoplastics to varying extents, but the typical use of these polymers in a confined geometry will likely prevent the NGS from impacting component performance. The polymers identified as of primary concern include Grafoil® (flexible graphite), Tefzel®, Isolast®, ethylene-propylene-diene monomer (EPDM) rubber, nitrile-butadiene rubber (NBR), styrene-butadiene rubber (SBR), ultra high molecular weight polyethylene (UHMWPE), and fluorocarbon rubber (FKM). Certain polymers like NBR and EPDM were found to interact mildly with NGS but their calculated swelling and the confined geometry will impede interaction with NGS. In addition, it was found that Vellumoid (cellulose fibers-reinforced glycerin and protein) may leach protein and Polyvinyl Chloride (PVC) may leach plasticizer (such as Bis-Ethylhexyl-Phthalates) into the NGS solvent. Either case will not impact decontamination or immobilization operations at Savannah River Site (SRS). Some applications have zero tolerance for dimensional changes such as the operation of valves while other applications a finite dimensional change improves the function of the application such as seals and gaskets. Additional considerations are required before using the conclusions from this work to judge outcomes in field applications. Decane, a component of Isopar?L that is most likely to interact with the polymers, mildly interacted with the elastomers and the propylene based polymers but their degree of swelling is at most 10% and the confined geometry that they are typically placed in indicate this is not significant. In addition, it was found that Vellumoid may leach protein into the NGS solvent. Since Vellumoid is used at the mixer in Saltstone where it sees minimum quantities of solvent, this leaching has no effect on the extraction process at MCU or the immobilization process at saltstone. No significant interaction is expected between MaxCalix and the polymers and elastomers used at MCU, DWPF, and Saltstone. Overall, minimal and insignificant interactions are expected on extraction and immobilization operations when MCU switches from CSSX to NGS solvent. It is expected that contacting NGS will not accelerate the aging rate of polymers and elastomers under radiation and heat. This is due to the minimal interaction between NGS and the polymers and the confined geometries for these polymers. SRNL recommends the use of the HSP method (for screening) and some testing to evaluate the impact of other organic such as alcohols, glycolate, and their byproducts on the polymers used throughout the site.

Fondeur, F. F.

2013-04-17T23:59:59.000Z

259

Diorganosilacetylene-alt-diorganosilvinylene polymers and a process densifying porous silicon-carbide bodies  

DOE Patents [OSTI]

The present invention provides linear organosilicon polymers including acetylene and vinylene moieties, and a process for their preparation. These diorganosilacetylene-alt-diorganosilvinylene linear polymers can be represented by the formula: --[--(R.sup.1)(R.sup.2)Si--C.tbd.C--(R.sup.3)(R.sup.4)Si--CH=CH--].sub.n-- , wherein n.gtoreq.2; and each R.sup.1, R.sup.2, R.sup.3, and R.sup.4 is independently selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, aryl, and aralkyl radicals. The polymers are soluble in organic solvents, air stable, and can be pulled into fibers or cast into films. They can be thermally converted into silicon carbide ceramic materials.

Barton, Thomas J. (Ames, IA); Ijadi-Maghsoodi, Sina (Ames, IA); Pang, Yi (Ames, IA)

1994-05-17T23:59:59.000Z

260

Fuel cell electrolyte membrane with basic polymer  

DOE Patents [OSTI]

The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

2012-12-04T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Fuel cell electrolyte membrane with basic polymer  

DOE Patents [OSTI]

The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Hamrock, Steven J. (Stillwater, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

2010-11-23T23:59:59.000Z

262

Application of conducting polymers to electroanalysis  

SciTech Connect (OSTI)

Conducting polymers can be used as sensitive layers in chemical microsensors leading to new applications of theses devices. They offer the potential for developing material properties that are critical to the sensor sensitivity, selectivity and fabrication. The advantages and limitations of the use of thin polymer layers in electrochemical sensors are discussed.

Josowicz, M.A.

1994-04-01T23:59:59.000Z

263

Multicolored Electrochromism in Polymers: Structures and Devices  

E-Print Network [OSTI]

Multicolored Electrochromism in Polymers: Structures and Devices Avni A. Argun, Pierre-Henri Aubert May 12, 2004 A review of electrochromic (EC) polymers and their applications in absorption/transmission, reflective, and patterned electrochromic devices (ECDs) is presented. Fundamental properties of EC materials

Tanner, David B.

264

Computationally-guided Design of Polymer Electrolytes  

E-Print Network [OSTI]

of Polymer Electrolytes Global Significance While progress of sustainable energy- harvesting techniques is promising, tandem advancements in energy storage are required to maintain a stable energy supply be a valuable contribution to the emerging sustainable energy landscape. This project applies polymer physics

265

Polymer surface treatment with particle beams  

DOE Patents [OSTI]

A polymer surface and near surface treatment process produced by irradiation with high energy particle beams. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications.

Stinnett, Regan W. (1033 Tramway La. NE., Albuquerque, NM 87122); VanDevender, J. Pace (7604 Lamplighter NE., Albuquerque, NM 87109)

1999-01-01T23:59:59.000Z

266

Polymer surface treatment with particle beams  

DOE Patents [OSTI]

A polymer surface and near surface treatment process produced by irradiation with high energy particle beams is disclosed. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications. 16 figs.

Stinnett, R.W.; VanDevender, J.P.

1999-05-04T23:59:59.000Z

267

Diffraction in Time of Polymer Particles  

E-Print Network [OSTI]

We study the quantum dynamics of a suddenly released beam of particles using a background independent (polymer) quantization scheme. We show that, in the first order of approximation, the low-energy polymer distribution converges to the standard quantum-mechanical result in a clear fashion, but also arises an additional small polymer correction term. We find that the high-energy polymer behaviour becomes predominant at short distances and short times. Numerical results are also presented. We find that particles whose wave functions satisfy the polymer wave equation do not exhibit the diffraction in time phenomena. The implementation of a lower bound to the possible resolution of times into the time-energy Heisenberg uncertainty relation is briefly discussed.

A. Martín-Ruiz

2014-06-13T23:59:59.000Z

268

MMMaaattteeerrriiiaaalllsss SSSeeemmmiiinnnaaarrr There have been great interests in recent years in exploring the use of organic-inorganic hybrid electronic  

E-Print Network [OSTI]

Early Career Development (CAREER) Award from the National Science Foundation and a Solar Energy energy applications including photovoltaics and light-emitting devices (LEDs). Organic electronic materials such as conjugated polymers have advantages in low material cost, tunability in material

269

Advances in inherently conducting polymers  

SciTech Connect (OSTI)

The discovery of polyacetylene as the prototype material led to extensive research on its synythesis and characterization. The techniques that emerged as the most important and promising ones are those that dealt with molecular orientation and that resulted in conductivities almost as high as that of copper. The study of dozens of other materials followed. Interest in conducting polymers stems from their nonclassical optical and electronic properties as well as their potential technological applications. However, some of the factors currently limiting their use are the lack of long-term stability and the need to develop conventional low-cost techniques for easy processing. Therefore, research was extended toward solving these problems, and progress has been recently made in that direction. The synthesis of new materials such as stable and easily processable alkylthiophenes, water-soluble polymers, and multicomponent systems, including copolymers and composites, constitutes an important step forward in the area of synthetic metals. However, a full understanding of materials chemistry and properties requires more work in the years to come. Although, few small-scale applications have proven to be successful, long-term stability and applicability tests are needed before their commercial use becomes reality.

Aldissi, M.

1987-09-01T23:59:59.000Z

270

Imprinted Polymers in Wastewater Treatment  

SciTech Connect (OSTI)

In wastewater treatment, a method that specifically recognizes a variety of impurities in a flexible manner would be useful for treatment facilities with varying needs. Current purification techniques (i.e. bacteria, oxidation, reduction, precipitation and filtration) are nonspecific and difficult to control in complex mixtures. Heavy metal removal is particularly important in improving the efficiency of wastewater treatment, as they inhibit or even destroy the bacteria used for filtration. Imprinting polymerization is a technique that allows for the efficient removal of specific compounds and has been used in purification of enantiomers. It has potential to be applied in wastewater systems with the impurities acting as the template for the imprinting polymerization. The polymer with the bound impurities intact can then be removed via precipitation. After removal of the impurity the polymer can be reused. Data for the imprinting polymerization of polyacrylates and polyacrylamides for several metal complexes will be presented. Imprinting polymerization in combination with emulsion polymerization to improve the removal of hydrophobic contaminants will be described. Removal efficiencies will be presented and compared with conventional wastewater treatment methods.

Eastman, Christopher; Goodrich, Scott; Gartner, Isabelle; Mueller, Anja

2004-03-31T23:59:59.000Z

271

Protective Effect of Nrf2 and Catalase in Maternal Diabetes-Induced Perinatal Hypertension and Kidney Disease  

E-Print Network [OSTI]

prevents maternal diabetes– induced perinatal programmingInt 2005;68:1670–1683 DIABETES, VOL. 61, OCTOBER 2012 12.I, et al. Maternal diabetes modulates renal morphogenesis in

Vaziri, Nosratola D.

2012-01-01T23:59:59.000Z

272

2010 POLYMER PHYSICS - JUNE 27 - JULY 2, 2010  

SciTech Connect (OSTI)

The 2010 Gordon Research Conference on Polymer Physics will provide outstanding lectures and discussions in this critical field that impacts every industrial sector from electronics to transportation to medicine to textiles to energy generation and storage. Fundamental topics range from mechanical properties of soft gels to new understanding in polymer crystallization to energy conversion and transmission to simulating polymer dynamics at the nanoscale. This international conference will feature 22 invited lectures, wherein the opening 10 minutes are specifically designed for a general polymer physics audience. In addition, poster sessions and informal activities provide ample opportunity to discuss the latest advances in polymer physics. The technical content of the meeting will include new twists on traditional polymer physics topics, recent advances in previously underrepresented topics, and emerging technologies enabled by polymer physics. Here is a partially listing of targeted topics: (1) electrically-active and light-responsive polymers and polymer-based materials used in energy conversion and storage; (2) polymers with hierarchical structures including supramolecular assemblies, ion-containing polymers, and self-assembled block polymers; (3) mechanical and rheological properties of soft materials, such as hydrogels, and of heterogeneous materials, particularly microphase separated polymers and polymer nanocomposites; and (4) crystallization of polymers in dilute solutions, polymer melts, and miscible polymer blends.

Karen Winey

2010-07-02T23:59:59.000Z

273

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer.

Weaver, Paul F. (Golden, CO); Maness, Pin-Ching (Golden, CO)

1993-01-01T23:59:59.000Z

274

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer. 3 figures.

Weaver, P.F.; Pinching Maness.

1993-10-05T23:59:59.000Z

275

Serum markers for type II diabetes mellitus  

DOE Patents [OSTI]

A method for identifying persons with increased risk of developing type 2 diabetes mellitus utilizing selected biomarkers described hereafter either alone or in combination. The present invention allows for broad based, reliable, screening of large population bases and provides other advantages, including the formulation of effective strategies for characterizing, archiving, and contrasting data from multiple sample types under varying conditions.

Metz, Thomas O; Qian, Wei-Jun; Jacobs, Jon M; Polpitiya, Ashoka D; Camp, II, David G; Smith, Richard D

2014-03-18T23:59:59.000Z

276

The effect of polyacrylamide polymers and formaldehyde on selected strains of oilfield related bacteria  

SciTech Connect (OSTI)

A preliminary study of the effect of two polyacrylamide polymers and formaldehyde on certain strains of oil field related bacteria was performed. Since at this stage of the development of planning the proposed North Sea polymer flood field samples of native bacteria populations and fluid samples were not available, the preliminary study was made using pure strains of bacteria associated with the oilfield environment. The tests were run using ideal growth conditions of temperature and culture media. The purpose of the study was to determine the effect of proposed polyacrylamide polymer flooding materials on the growth of selected strains of bacteria belonging to families common to the oilfield environment. The effect of 100 ppm of formaldehyde on these organisms also was investigated. The results of the tests showed that these bacteria responded differently to exposure to formaldehyde, polyacrylamide polymers and mixtures of both. These results indicate another possible mechanism for the occurrence of high bacteria related corrosion rates reported to occur on the producing side of polymer floods.

Farquhar, G.B. [Texaco E.P.T.D., Houston, TX (United States)

1996-08-01T23:59:59.000Z

277

Covalent modification of mushroom tyrosinase with different amphiphic polymers for pharmaceutical and biocatalysis applications  

SciTech Connect (OSTI)

Two different poly(ethylene glycol) derivatives (linear, mol wt 5000 and a branched form, mol wt 10000) and a new polymer (poly-[acryloylmorfoline], mol wt 5500) were covalently bound to the enzyme tyrosinase. The polymer-protein conjugates were studied with a view to their potential pharmaceutical application and to their use for the bioconversion of phenolic substrates in organic solvents. V{sub max} and K{sub m} for the dopa-dopaquinone conversion, thermostability, stability toward inactivation by dopa oxidation products, half-life in blood circulation, and behavior in organic solvents for the different adducts were investigated. Arrhenius plots for the dopa-dopaquinone conversion were also obtained in order to study the effects of temperature on the different enzyme forms. Covalent attachment of the polymers increased enzyme stability in aqueous solution and the solubility in organic solvents. However, organic solvent solubilization brought about loss of enzyme conformation as assessed by CD measurements, which is accompanied by a nonreversible loss of catalytic activity. 30 refs., 4 figs., 4 tabs.

Morpurgo, M.; Schiavon, O.; Caliceti, P. [Univ. of Padova (Italy)] [and others

1996-01-01T23:59:59.000Z

278

Molecular Design of Doped Polymers for Thermoelectric Systems-Final Technical Report  

SciTech Connect (OSTI)

The self-assembly of organic semiconducting molecules and polymers is critical for their electrical properties. This project addressed the design of organic semiconductors with novel synthetic building blocks for proton-dopable conducting materials and the molecular order and microstructure of high performance semiconducting polymers blended with charge transfer dopants. Novel azulene donor-acceptor materials were designed and synthesized with unique electronic effects upon protonation to generate charged species in solution. The microstructure and optical properties of these derivatives were examined to develop structure-property relationships. Studies of the microstructure of blends of charge transfer doped semiconducting polymers revealed highly ordered conductive phases in blends. The molecular packing of one blend was studied in detail using a combination of solid-state NMR and x-ray scattering revealing that dopant incorporation is unlikely to be random as assumed in transport models. Studies of the electrical properties of these highly ordered blends revealed a universal trend between the thermopower and electrical conductivity of semiconducting polymers that is independent of the doping mechanism.

Chabinyc, Michael L. [University of California, Santa Barbara; Hawker, Craig J. [University of California, Santa Barbara

2013-10-09T23:59:59.000Z

279

Conductive inks for metalization in integrated polymer microsystems  

DOE Patents [OSTI]

A system of metalization in an integrated polymer microsystem. A flexible polymer substrate is provided and conductive ink is applied to the substrate. In one embodiment the flexible polymer substrate is silicone. In another embodiment the flexible polymer substrate comprises poly(dimethylsiloxane).

Davidson, James Courtney (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA); Maghribi, Mariam N. (Livermore, CA); Benett, William J. (Livermore, CA); Hamilton, Julie K. (Tracy, CA); Tovar, Armando R. (San Antonio, TX)

2006-02-28T23:59:59.000Z

280

Polymer nanocomposites based on transition metal ion modified organoclays  

E-Print Network [OSTI]

from both academic and industrial laboratories in the past several years [1,2]. Polymer nanocom in modulus, toughness, and barrier properties may be obtained. Typically, the improved properties can.polymer.2006.12.005 Polymer 48 (2007) 827e840 www.elsevier.com/locate/polymer #12;formation of silica

Frenkel, Anatoly

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Glass/polymer composites and methods of making  

DOE Patents [OSTI]

The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

1995-01-01T23:59:59.000Z

282

Open Questions about Polymer Friction JANET S. WONG,1  

E-Print Network [OSTI]

perfluoropolyethers are more effective than competing polymers. In the regulation of the viscosity of engine oils

Granick, Steve

283

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents [OSTI]

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

284

MODEL AND OPTIMIZATION OF ORGANIC PHOTOVOLTAIC CELLS Amelia McNamara  

E-Print Network [OSTI]

advantages. In contrast to the typical silicon-based solar cells, organic cells can be formed from extremely the organic photovoltaic cell, an important topic in the energy industry which has not been well studied. We are especially interested in the optimization of the two active layers in the solar cell, the PEOPT polymer

285

Electrical condition monitoring method for polymers  

DOE Patents [OSTI]

An electrical condition monitoring method utilizes measurement of electrical resistivity of a conductive composite degradation sensor to monitor environmentally induced degradation of a polymeric product such as insulated wire and cable. The degradation sensor comprises a polymeric matrix and conductive filler. The polymeric matrix may be a polymer used in the product, or it may be a polymer with degradation properties similar to that of a polymer used in the product. The method comprises a means for communicating the resistivity to a measuring instrument and a means to correlate resistivity of the degradation sensor with environmentally induced degradation of the product.

Watkins, Jr. Kenneth S. (Dahlonega, GA); Morris, Shelby J. (Hampton, VA); Masakowski, Daniel D. (Worcester, MA); Wong, Ching Ping (Duluth, GA); Luo, Shijian (Boise, ID)

2010-02-16T23:59:59.000Z

286

Redox polymer electrodes for advanced batteries  

DOE Patents [OSTI]

Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

Gregg, Brian A. (Golden, CO); Taylor, A. Michael (Golden, CO)

1998-01-01T23:59:59.000Z

287

Randomly charged polymers in porous environment  

E-Print Network [OSTI]

We study the conformational properties of charged polymers in a solvent in the presence of structural obstacles correlated according to a power law $\\sim x^{-a}$. We work within the continuous representation of a model of linear chain considered as a random sequence of charges $q_i=\\pm q_0$. Such a model captures the properties of polyampholytes -- heteropolymers comprising both positively and negatively charged monomers. We apply the direct polymer renormalization scheme and analyze the scaling behavior of charged polymers up to the first order of an $\\epsilon=6-d$, $\\delta=4-a$-expansion.

V. Blavatska; C. von Ferber

2013-11-22T23:59:59.000Z

288

Exploring novel silicon-containing polymers---From preceramic polymers to conducting polymers with nonlinear optical properties  

SciTech Connect (OSTI)

Several new types of silicon-containing preceramic polymers, i.e., poly(diorganosilacetylene) and poly(diorganosilvinylene) have been synthesized with molecular weights from 10,000 to 120,000. These polymers could be thermally converted to SiC with a moderate to high char yields. Ready solubility and good processability made these types of polymers attractive in their applications to ceramics. The thermal polymerization of diethynyldiphenyl-silane, which was reported in 1968 to afford poly(diphenylsilyldiacetylene) via dehydrogenation, was reinvestigated. Spectroscopic studies showed that the polymer had a structure of polyacetylene type not diacetylene. Diphenyldiethynylgermane and a series of diorganodiethynylsilances were synthesized. These could be polymerized in the presence of MoCl{sub 5} or WCl{sub 6} to afford a soluble, violet material with Mw as high as 108,000. 100 refs., 56 figs., 16 tabs.

Pang, Yi.

1991-10-07T23:59:59.000Z

289

Position: Polymer Chemist Company: ExxonMobil Research and Engineering Company, a wholly owned subsidiary of Exxon Mobil  

E-Print Network [OSTI]

candidate will apply his or her knowledge to improve existing olefin-based products and develop new ones productive collaborations internally and with outside research organizations, and grow new science areas. JobPosition: Polymer Chemist Company: ExxonMobil Research and Engineering Company, a wholly owned

Alpay, S. Pamir

290

Study of polymer molecules and conformations with a nanopore  

DOE Patents [OSTI]

The invention features methods for evaluating the conformation of a polymer, for example, for determining the conformational distribution of a plurality of polymers and to detect binding or denaturation events. The methods employ a nanopore which the polymer, e.g., a nucleic acid, traverses. As the polymer traverses the nanopore, measurements of transport properties of the nanopore yield data on the conformation of the polymer.

Golovchenko, Jene A. (Lexington, MA); Li, Jiali (Fayetteville, AR); Stein, Derek (Delft, NL); Gershow, Marc H. (Cambridge, MA)

2010-12-07T23:59:59.000Z

291

Study of polymer molecules and conformations with a nanopore  

DOE Patents [OSTI]

The invention features methods for evaluating the conformation of a polymer, for example, for determining the conformational distribution of a plurality of polymers and to detect binding or denaturation events. The methods employ a nanopore which the polymer, e.g., a nucleic acid, traverses. As the polymer traverses the nanopore, measurements of transport properties of the nanopore yield data on the conformation of the polymer.

Golovchenko, Jene A.; Li, Jiali; Stein, Derek; Gershow, Marc H.

2013-03-12T23:59:59.000Z

292

Polymer graphite composite anodes for Li-ion batteries  

E-Print Network [OSTI]

­ Polarization resistance C2 ­ Double layer capacitance #12;Equivalent circuit parameters for polymer composite%polymer 6%Polymer 7.8%Polymer 8.4%Polymer #12;Equivalent circuit used to fit the experimental data R R1 R2 C2C1 DPE1 DPE2 R ­ ohmic resistance R1 ­ SEI layer resistance C1 ­ SEI layer capacitance R2

Popov, Branko N.

293

Polymer Matrix Composites: A Perspective for a Special Issue of Polymer Reviews  

SciTech Connect (OSTI)

Polymer matrix composites, with their high specific strength and stiffness, are used in a wide range of applications from large wind turbine blades to microelectronics. This perspective article provides a brief primer on polymer matrix composites, discusses some of their advantages and limitations, and describes a number of emerging trends in the field. In addition, it introduces four review articles on the topics of recent developments in carbon fibers, natural fiber reinforced composites, evaluation of the interface between the fiber reinforcement and polymer matrix, and carbon nanotube reinforced polymers.

Kessler, Michael R.

2012-09-04T23:59:59.000Z

294

Relationship among religious coping, psychosocial factors, and quality of life in individuals with type 2 diabetes  

E-Print Network [OSTI]

The purpose of this study was to examine the relationship among religious coping, acceptance of diabetes, social support, diabetes management, and quality of life among individuals with type 2 diabetes (T2DM). Religious coping, acceptance...

Lager, Julia M.

2009-06-02T23:59:59.000Z

295

Large displacement fast conducting polymer actuators  

E-Print Network [OSTI]

Conducting polymers are a promising class of electroactive materials that undergo volumetric changes under applied potentials, which make them particularly useful for many actuation applications. Polypyrrole , is one of ...

Chen, Angela Y. (Angela Ying-Ju), 1982-

2006-01-01T23:59:59.000Z

296

Electrical conductivity of segregated network polymer nanocomposites  

E-Print Network [OSTI]

in both electrical and mechanical properties with low carbon black loading, while the solution-based composite achieves its maximum enhancement at higher carbon black loading (~25wt%). The effect of the particle size ratio between the polymer particle...

Kim, Yeon Seok

2009-06-02T23:59:59.000Z

297

Polymer-based electrocaloric cooling devices  

DOE Patents [OSTI]

Cooling devices (i.e., refrigerators or heat pumps) based on polymers which exhibit a temperature change upon application or removal of an electrical field or voltage, (e.g., fluoropolymers or crosslinked fluoropolymers that exhibit electrocaloric effect).

Zhang, Qiming; Lu, Sheng-Guo; Li, Xinyu; Gorny, Lee; Cheng, Jiping; Neese, Bret P; Chu, Baojin

2014-10-28T23:59:59.000Z

298

Semiconductor-nanocrystal/conjugated polymer thin films  

DOE Patents [OSTI]

The invention described herein provides for thin films and methods of making comprising inorganic semiconductor-nanocrystals dispersed in semiconducting-polymers in high loading amounts. The invention also describes photovoltaic devices incorporating the thin films.

Alivisatos, A. Paul (Oakland, CA); Dittmer, Janke J. (Munich, DE); Huynh, Wendy U. (Munich, DE); Milliron, Delia (Berkeley, CA)

2010-08-17T23:59:59.000Z

299

California: Conducting Polymer Binder Boosts Storage Capacity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- 10:17am Addthis Working with Nextval, Inc., Lawrence Berkeley National Laboratory (LBNL) developed a Conducting Polymer Binder for high-capacity lithium-ion batteries. With a...

300

Chemical vapor deposition of functionalized isobenzofuran polymers  

E-Print Network [OSTI]

This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

Olsson, Ylva Kristina

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Synthesis and characterization of conducting polymer actuators  

E-Print Network [OSTI]

Conducting polymers are known to mechanically respond to electrochemical stimuli and have been utilized as linear actuators. To date, the most successful mechanism for actuation is ionic ingress and egress, though mechanisms ...

Vandesteeg, Nathan A. (Nathan Alan)

2007-01-01T23:59:59.000Z

302

Dynamic Fracture Toughness of Polymer Composites  

E-Print Network [OSTI]

that of defense or transport. In this project, the focus is on determining dynamic fracture toughness property of fiber reinforced polymer composites by using a combined numerical- experimental methodology. Impact tests are conducted on Split-Hopkinson pressure...

Harmeet Kaur

2012-02-14T23:59:59.000Z

303

Carbon nanotube polymer composition and devices  

DOE Patents [OSTI]

A thin film device and compound having an anode, a cathode, and at least one light emitting layer between the anode and cathode, the at least one light emitting layer having at least one carbon nanotube and a conductive polymer.

Liu, Gao (Oakland, CA); Johnson, Stephen (Richmond, CA); Kerr, John B. (Oakland, CA); Minor, Andrew M. (El Cerrito, CA); Mao, Samuel S. (Castro Valley, CA)

2011-06-14T23:59:59.000Z

304

Counting primary loops in polymer gels  

E-Print Network [OSTI]

Much of our fundamental knowledge related to polymer networks is built on an assumption of ideal end-linked network structure. Real networks invariably possess topological imperfections that negatively affect mechanical ...

Zhou, Huaxing

305

Structural retrofitting using fiber reinforced polymers  

E-Print Network [OSTI]

Over the past decades, fiber reinforced polymers (FRP) have been widely used in the aeronautical and naval industries. Being more costly than conventional Civil Engineering materials such as steel or concrete, they have ...

Dumas, Pierre, M. Eng. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

306

Chemical vapor deposition of antimicrobial polymer coatings  

E-Print Network [OSTI]

There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...

Martin, Tyler Philip, 1977-

2007-01-01T23:59:59.000Z

307

Novel molecular architectures from iptycene polymers  

E-Print Network [OSTI]

This thesis explored the incorporation of iptycenes into polymers as a means to enhance the mechanical properties. Iptycene structures were targeted because they possess a unique structural property called internal molecular ...

Tsui, Nicholas T. (Nicholas Tang)

2007-01-01T23:59:59.000Z

308

Fuel cell electrolyte membrane with acidic polymer  

DOE Patents [OSTI]

An electrolyte membrane is formed by an acidic polymer and a low-volatility acid that is fluorinated, substantially free of basic groups, and is either oligomeric or non-polymeric.

Hamrock, Steven J. (Stillwater, MN); Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

2009-04-14T23:59:59.000Z

309

Injectable polymer for in vivo oxygen sensing  

E-Print Network [OSTI]

This thesis documents the synthesis and characterization of an elastomeric polymer that is oxygen sensitive and can be interrogated using Magnetic Resonance Imaging (MRI) or Magnetic Resonance (MR) technology to report the ...

Imaad, Syed M. (Syed Muhammad)

2013-01-01T23:59:59.000Z

310

Development and characterization of conducting polymer actuators  

E-Print Network [OSTI]

Conducting polymers such as polypyrrole, polythiophene and polyaniline are currently studied as novel biologically inspired actuators. The actuation mechanism of these materials depends upon the motion of ions in and out ...

Pillai, Priam Vasudevan

2011-01-01T23:59:59.000Z

311

Nanocomposite polymer electrolyte for rechargeable magnesium batteries  

SciTech Connect (OSTI)

Nanocomposite polymer electrolytes present new opportunities for rechargeable magnesium batteries. However, few polymer electrolytes have demonstrated reversible Mg deposition/dissolution and those that have still contain volatile liquids such as tetrahydrofuran (THF). In this work, we report a nanocomposite polymer electrolyte based on poly(ethylene oxide) (PEO), Mg(BH4)2 and MgO nanoparticles for rechargeable Mg batteries. Cells with this electrolyte have a high coulombic efficiency of 98% for Mg plating/stripping and a high cycling stability. Through combined experiment-modeling investigations, a correlation between improved solvation of the salt and solvent chain length, chelation and oxygen denticity is established. Following the same trend, the nanocomposite polymer electrolyte is inferred to enhance the dissociation of the salt Mg(BH4)2 and thus improve the electrochemical performance. The insights and design metrics thus obtained may be used in nanocomposite electrolytes for other multivalent systems.

Shao, Yuyan; Rajput, Nav Nidhi; Hu, Jian Z.; Hu, Mary Y.; Liu, Tianbiao L.; Wei, Zhehao; Gu, Meng; Deng, Xuchu; Xu, Suochang; Han, Kee Sung; Wang, Jiulin; Nie, Zimin; Li, Guosheng; Zavadil, K.; Xiao, Jie; Wang, Chong M.; Henderson, Wesley A.; Zhang, Jiguang; Wang, Yong; Mueller, Karl T.; Persson, Kristin A.; Liu, Jun

2014-12-28T23:59:59.000Z

312

Polymers for Chemical Sensors Using Hydrosilylation Chemistry  

SciTech Connect (OSTI)

Sorbent and functionalized polymers play a key role in a diverse set of fields, including chemical sensors, separation membranes, solid phase extraction techniques, and chromatography. Sorbent polymers are critical to a number of sensor array or "electronic nose" systems. The responses of the sensors in the array give rise to patterns that can be used to distinguish one compound from another, provided that a sufficiently diverse set of sensing materials is present in the array. Figure 1 illustrates the concept of several sensors, each with a different sensor coating, giving rise to variable responses to an analyte that appear as a pattern in bar graph format. Using hydrosilylation as the bond-forming reaction, we have developed a versatile and efficient approach to developing sorbent polymers with diverse interactive properties for sensor applications. Both the chemical and physical properties of these polymers are predictable and tunable by design.

Grate, Jay W.; Kaganove, Steven N.; Nelson, David A.

2001-06-28T23:59:59.000Z

313

Fracture of Thermosetting Polymers: Experiments and Modeling  

E-Print Network [OSTI]

for the designation as UNDERGRADUATE RESEARCH SCHOLAR A Senior Scholars Thesis by BRAD EVIN BURGESS FRACTURE OF THERMOSETTING POLYMERS: EXPERIMENTS AND MODELING Approved by: Research Advisor: Amine Benzerga Associate Dean for Undergraduate... Scholars Thesis by BRAD EVIN BURGESS iii ABSTRACT Fracture of Thermosetting Polymers: Experiments and Modeling. (April 2009) Brad Evin Burgess Department of Aerospace Engineering Texas A&M University Research Advisor: Dr. Amine Benzerga...

Benzerga, Amine; Burgess, Brad

2011-08-04T23:59:59.000Z

314

Poisson Bracket Formulation of Nematic Polymer Dynamics  

E-Print Network [OSTI]

We formulate the dynamical theory of nematic polymers, starting from a microscopic Poisson bracket approach. We find that the Poisson bracket between the nematic director and momentum depends on the (Maier-Saupe) order parameter of the nematic phase. We use this to derive reactive couplings of the nematic director to the strain rates. Additionally, we find that local dynamics breaks down as the polymers begin to overlap. We offer a physical picture for both results.

Randall D. Kamien

1999-06-22T23:59:59.000Z

315

Multidimensional Random Polymers : A Renewal Approach  

E-Print Network [OSTI]

In these lecture notes, which are based on the mini-course given at 2013 Prague School on Mathematical Statistical Physics, we discuss ballistic phase of quenched and annealed stretched polymers in random environment on ${\\mathbb Z}^d$ with an emphasis on the natural renormalized renewal structures which appear in such models. In the ballistic regime an irreducible decomposition of typical polymers leads to an effectiverandom walk reinterpretation of the latter. In the annealed casethe Ornstein-Zernike theory based on this approach paves the way to an essentially complete control on the level of local limit results and invariance principles. In the quenched case, the renewal structure maps the model of stretched polymers into an effective model of directed polymers. As a result one is able to use techniques and ideas developed in the context of directed polymers in order to address issues like strong disorder in low dimensions and weak disorder in higher dimensions. Among the topics addressed: Thermodynamics of quenched and annealed models, multi-dimensional renewal theory (under Cramer's condition), renormalization and effective random walk structure of annealed polymers, very weak disorder in dimensions $d\\geq 4$ and strong disorder in dimensions $d=1,2$.

Dmitry Ioffe

2014-11-30T23:59:59.000Z

316

SURFACTANT - POLYMER INTERACTION FOR IMPROVED OIL RECOVERY  

SciTech Connect (OSTI)

The goal of this research is to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, adsorption and mobility control. Surfactant--polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation high adsorption and viscous/heterogeneity fingering. A mixture comprising a ''pseudo oil'' with appropriate surfactant and polymer has been selected to study micellar-polymer chemical flooding. The physical properties and phase behavior of this system have been determined. A surfactant-polymer slug has been designed to achieve high efficiency recovery by improving phase behavior and mobility control. Recovery experiments have been performed on linear cores and a quarter 5-spot. The same recovery experiments have been simulated using a commercially available simulator (UTCHEM). Good agreement between experimental data and simulation results has been achieved.

Unknown

1998-10-01T23:59:59.000Z

317

TFB:TPDSi2 interfacial layer usable in organic photovoltaic cells  

DOE Patents [OSTI]

The present invention, in one aspect, relates to a solar cell. In one embodiment, the solar cell includes an anode; an active organic layer comprising an electron-donating organic material and an electron-accepting organic material; and an interfacial layer formed between the anode and active organic layer, where the interfacial layer comprises a hole-transporting polymer characterized with a hole-mobility higher than that of the electron-donating organic material in the active organic layer, and a small molecule that has a high hole-mobility and is capable of crosslinking on contact with air.

Marks, Iobin J. (Evanston, IL); Hains, Alexander W. (Evanston, IL)

2011-02-15T23:59:59.000Z

318

autoimmune diabetic nod: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

insulitis but rather acute pathology and disease. Additionally, these results lead us to question the feasibility of Th2-based therapy in type I diabetes, especially in...

319

american diabetes association: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and without diabetes in 2002 by sex, age, raceethnicity, type of medical condition, and health care setting. Health care use and total health care expenditures attributable to...

320

E-Print Network 3.0 - age-related diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

E-Print Network 3.0 - asymptomatic diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

322

E-Print Network 3.0 - arsenic-induced diabetes mellitus Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

323

E-Print Network 3.0 - adult-onset diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

324

E-Print Network 3.0 - ao diabetes mellitus Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

325

Serum magnesium level and magnesium supplementation on Type 2 Diabetes Mellitus: systematic review.  

E-Print Network [OSTI]

??Objective: To assess the association between serum magnesium levels and risk of type 2 diabetes and to evaluate the effect of magnesium supplementation on diabetes… (more)

Sefealem, Assefa Belay

2011-01-01T23:59:59.000Z

326

Plastic flow modeling in glassy polymers  

SciTech Connect (OSTI)

Glassy amorphous and semi-crystalline polymers exhibit strong rate, temperature, and pressure dependent polymeric yield. As a rule of thumb, in uniaxial compression experiments the yield stress increases with the loading rate and applied pressure, and decreases as the temperature increases. Moreover, by varying the loading state itself complex yield behavior can be observed. One example that illustrates this complexity is that most polymers in their glassy regimes (i.e., when the temperature is below their characteristic glass transition temperature) exhibit very pronounced yield in their uniaxial stress stress-strain response but very nebulous yield in their uniaxial strain response. In uniaxial compression, a prototypical glassy-polymer stress-strain curve has a stress plateau, often followed by softening, and upon further straining, a hardening response. Uniaxial compression experiments of this type are typically done from rates of 10{sup -5} s{sup -1} up to about 1 s{sup -1}. At still higher rates, say at several thousands per second as determined from Split Hopkinson Pressure Bar experiments, the yield can again be measured and is consistent with the above rule of thumb. One might expect that that these two sets of experiments should allow for a successful extrapolation to yet higher rates. A standard means to probe high rates (on the order of 105-107 S-I) is to use a uniaxial strain plate impact experiment. It is well known that in plate impact experiments on metals that the yield stress is manifested in a well-defined Hugoniot Elastic Limit (HEL). In contrast however, when plate impact experiments are done on glassy polymers, the HEL is arguably not observed, let alone observed at the stress estimated by extrapolating from the lower strain rate experiments. One might argue that polymer yield is still active but somehow masked by the experiment. After reviewing relevant experiments, we attempt to address this issue. We begin by first presenting our recently developed glassy polymer model. While polymers are well known for their non-equilibrium deviatoric behavior we have found the need for incorporating both equilibrium and non-equilibrium volumetric behavior into our theory. Experimental evidence supporting the notion of non-equilibrium volumetric behavior will be summarized. Our polymer yield model accurately captures the stress plateau, softening and hardening and its yield stress predictions agree well with measured values for several glassy polymers including PMMA, PC, and an epoxy resin. We then apply our theory to plate impact experiments in an attempt to address the questions associated with high rate polymer yield in uniaxial strain configurations.

Clements, Brad [Los Alamos National Laboratory

2010-12-13T23:59:59.000Z

327

Shital Dodhia et al. Effect Of Blood Pressure On Diabetic Nephropathy RESEARCH ARTICLE EFFECT OF BLOOD PRESSURE ON DIABETIC NEPHROPATHY  

E-Print Network [OSTI]

Background: Hypertension is known to be risk factor for the development of proteinuria in patients with uncontrolled diabetes mellitus type2, leads to progression of end stage renal disease Aims & Objective: To study the effect of hypertension on diabetic nephropathy in type 2 diabetic patients. Material and Methods: We investigated, progression of diabetic nephropathy by measuring arterial blood pressure, serum creatinine and glomerular filtration rate(GFR) level in 60 (35 men and 25 women) type 2 uncontrolled diabetes mellitus patients on antihypertensive treatment. Results: The survey was done for 6 months during which 30 (group 1)-uncontrolled diabetes mellitus patients with normal blood pressure were compared with 30 (group 2)-Uncontrolled diabetes mellitus patients with hypertension who had mean systolic blood pressure (SBP) was 148.86 ± 5.12 mmHg. In group 2 the mean level of serum creatinine (1.71 ± 0.46 mg/dl) was significantly higher and mean GFR (54.57 ± 35.26 ml/min) was significantly lower than group 1 (P < 0.05). Conclusion: Uncontrolled hypertension leads to progression of diabetic nephropathy with decline in GFR earlier than normotensive uncontrolled diabetic patients.

Dr. Shital Dodhia; Mahesh Bhabhor; Kalpesh Vidja; Rajesh Kathrotia; Chinmay Shah; Dr. Varsha Joshi

328

Polymer micromold and fabrication process  

DOE Patents [OSTI]

A mold assembly is disclosed with micro-sized features in which the hollow portion thereof is fabricated from a sacrificial mandrel which is surface treated and then coated to form an outer shell. The sacrificial mandrel is then selectively etched away leaving the outer shell as the final product. The sacrificial mandrel is fabricated by a precision lathe, for example, so that when removed by etching the inner or hollow area has diameters as small as 10`s of micros ({micro}m). Varying the inside diameter contours of the mold can be accomplished with specified ramping slopes formed on the outer surface of the sacrificial mandrel, with the inside or hollow section being, for example, 275 {micro}m in length up to 150 {micro}m in diameter within a 6 mm outside diameter (o.d.) mold assembly. The mold assembly itself can serve as a micronozzle or microneedle, and plastic parts, such as microballoons for angioplasty, polymer microparts, and microactuators, etc., may be formed within the mold assembly. 6 figs.

Lee, A.P.; Northrup, M.A.; Ahre, P.E.; Dupuy, P.C.

1997-08-19T23:59:59.000Z

329

Friction in (im-)miscible polymer brush systems and the role of transverse polymer-tilting  

E-Print Network [OSTI]

Friction in (im-)miscible polymer brush systems and the role of transverse polymer-tilting Sissi de preferred solvent, leading to low friction and low wear rates. Here, we demonstrate, using molecular systems also show smaller friction than miscible systems, although the friction reduction is less than

Mueser, Martin

330

Interfacial thermal conductance in spun-cast polymer films and polymer brushes  

E-Print Network [OSTI]

represents the length of a material of thermal conduc- tivity providing an equivalent thermal resistance inorganic materials and anharmonic polymers have potentially intriguing thermal transport behavior. The low. This requirement proves challenging for low thermal conductivity materials like amorphous polymers. The effective

Braun, Paul

331

Organization Chart - Home  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LSD Logo About Us People & Organization Research News & Events Safety Internal Resources Organization Chart Departments Scientific Staff Directory Committees Organization Chart...

332

Combinatorial synthesis and screening of non-biological polymers  

DOE Patents [OSTI]

Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

Schultz, Peter G.; Xiang, Xiao-Dong; Goldwasser, Isy; Briceno, Gabriel; Sun, Xiao-Dong; Wang, Kai-An

2006-04-25T23:59:59.000Z

333

Polymer arrays from the combinatorial synthesis of novel materials  

DOE Patents [OSTI]

Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

Schultz, Peter G.; Xiang, Xiao-Dong; Goldwasser, Isy; Briceno, Gabriel; Sun, Xiao-Dong

2004-09-21T23:59:59.000Z

334

Method of making metal-polymer composite catalysts  

DOE Patents [OSTI]

A metal-polymer-carbon composite catalyst for use as a cathode electrocatalyst in fuel cells. The catalyst includes a heteroatomic polymer; a transition metal linked to the heteroatomic polymer by one of nitrogen, sulfur, and phosphorus, and a recast ionomer dispersed throughout the heteroatomic polymer-carbon composite. The method includes forming a heteroatomic polymer-carbon composite and loading the transition metal onto the composite. The invention also provides a method of making a membrane electrode assembly for a fuel cell that includes the metal-polymer-carbon composite catalyst.

Zelena, Piotr (Los Alamos, NM); Bashyam, Rajesh (Los Alamos, NM)

2009-06-23T23:59:59.000Z

335

Submitting Organization Sandia National ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in a polymer coating. It functions by integrating a lithium-ion based solid-state battery with a thin photovoltaic (PV) collector. The battery is a solid-state system...

336

Who Gets Diabetes? Good health is your most valuable asset  

E-Print Network [OSTI]

Who Gets Diabetes? Good health is your most valuable asset ­ make the most of it. Millions, blindness and many other health problems if it is not controlled. By managing this condition with the right care, treatment and lifestyle changes, a patient diagnosed with diabetes can continue to live a happy

337

Peptide and protein biomarkers for type 1 diabetes mellitus  

SciTech Connect (OSTI)

A method for identifying persons with increased risk of developing type 1 diabetes mellitus, or having type I diabetes mellitus, utilizing selected biomarkers described herein either alone or in combination. The present disclosure allows for broad based, reliable, screening of large population bases. Also provided are arrays and kits that can be used to perform such methods.

Zhang, Qibin; Metz, Thomas O.

2014-06-10T23:59:59.000Z

338

Polymer quenched prealloyed metal powder  

DOE Patents [OSTI]

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

2001-01-01T23:59:59.000Z

339

Cylindrical confinement of semiflexible polymers  

E-Print Network [OSTI]

Equilibrium states of a closed semiflexible polymer binding to a cylinder are described. This may be either by confinement or by constriction. Closed completely bound states are labeled by two integers, the number of oscillations, $n$, and the number of times it winds the cylinder, $p$, the latter a topological invariant. We examine the behavior of these states as the length of the loop is increased by evaluating the energy, the conserved axial torque and the contact force. The ground state for a given $p$ is the state with $n=1$; a short loop with $p=1$ is an elliptic deformation of a parallel circle; as its length increases it elongates along the cylinder axis, with two hairpin ends. Excited states with $n \\geq 2$ and $p=1$ posses $n$-fold axial symmetry. Short (long) loops possess energies $\\approx p E_0$ ($n E_0$), with $E_0$ the energy of a circular loop with same radius as the cylinder; in long loops the axial torque vanishes. Confined bound excited states are initially unstable; however, above a critical length they becomes stable: the folded hairpin cannot be unfolded. The ground state for each $p$ is also initially unstable with respect to deformations rotating the loop off the surface into the interior. A closed planar elastic curve aligned along the cylinder axis making contact with the cylinder on its two sides is identified as the ground state of a confined loop. Exterior bound states behave very differently, if free to unbind, as signaled by the reversal in the sign of the contact force. If $p=1$, all such states are unstable. If $p\\ge 2$, however, a topological obstruction to complete unbinding exists. If the loop is short, the bound state with $p=2$ and $n=1$ provides a stable constriction of the cylinder, partially unbinding as the length is increased. This motif could be relevant to an understanding of the process of membrane fission mediated by dynamin rings.

Pablo Vázquez-Montejo; Zachary McDargh; Markus Deserno; Jemal Guven

2015-03-03T23:59:59.000Z

340

Ring polymers in crowded environment: conformational properties  

E-Print Network [OSTI]

We analyze the universal size characteristics of flexible ring polymers in solutions in presence of structural obstacles (impurities) in d dimensions. One encounters such situations when considering polymers in gels, colloidal solutions, intra- and extracellular environments. A special case of extended impurities correlated on large distances r according to a power law \\sim r^{-a} is considered. Applying the direct polymer renormalization scheme, we evaluate the estimates for averaged gyration radius $\\langle R_{g\\,{\\rm ring}} \\rangle$ and spanning radius $\\langle R_{1/2\\,{\\rm ring}} \\rangle$ of typical ring polymer conformation up to the first order of double \\varepsilon=4-d, \\delta=4-a expansion. Our results quantitatively reveal an extent of the effective size and anisotropy of closed ring macromolecules in disordered environment. In particular, the size ratio of ring and open (linear) polymers of the same molecular weight grows when increasing the strength of disorder according to $\\langle R^2_{g\\,{\\rm ring}} \\rangle / \\langle R^2_{g\\,{\\rm chain}} \\rangle =\\frac{1}{2} \\left(1+\\frac{13}{48}\\delta \\right)$.

K. Haydukivska; V. Blavatska

2014-08-20T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Arsenic and diabetes and hypertension in human populations: A review  

SciTech Connect (OSTI)

Long-term exposure to ingested arsenic from drinking water has been well documented to be associated with an increased risk of diabetes mellitus and hypertension in a dose-response relationship among residents of arseniasis-endemic areas in southwestern Taiwan and Bangladesh. An increased risk of self-reported hypertension but not diabetes was reported in a community-based study of residents who consumed drinking water with a low level of arsenic. Increased glycosylated hemoglobin level and systolic blood pressure were observed in workers occupationally exposed to arsenic. Inconsistent findings of arsenic and diabetes in occupational studies may result from the healthy worker effect and the variation in exposure measurement, age composition, number of patients, accuracy in diagnosis and classification of underlying causes of death, competing causes of death, and method to detect diabetes. The dose-response relationship and toxicological mechanisms of arsenic-induced diabetes and hypertension need further elucidation.

Chen, C.-J. [Genomics Research Center, Academia Sinica, 128 Academia Road Section 2, Nankang, Taipei 11529, Taiwan (China); Division of Environmental Health and Occupational Medicine, National Health Research Institutes, Miaoli, Taiwan Institute of Statistical Science, Academia Sinica, Taipei, Taiwan (China); Department of Internal Medicine, National Taiwan University, Taipei, Taiwan (China); School of Public Health, Taipei Medical University, Taipei, Taiwan (China); Department of Public Health, Tzu-Chi University, Hualien, Taiwan (China); Graduate Institute of Preventive Medicine, National Taiwan University, Taipei, Taiwan (China)], E-mail: cjchen@ha.mc.ntu.edu.tw; Wang, S.-L.; Chiou, J.-M.; Tseng, C.-H.; Chiou, H.-Y.; Hsueh, Y.-M.; Chen, S.-Y.; Wu, M.-M.; Lai, M.-S. [Genomics Research Center, Academia Sinica, 128 Academia Road Section 2, Nankang, Taipei 11529, Taiwan (China); Division of Environmental Health and Occupational Medicine, National Health Research Institutes, Miaoli, Taiwan Institute of Statistical Science, Academia Sinica, Taipei, Taiwan (China); Department of Internal Medicine, National Taiwan University, Taipei, Taiwan (China); School of Public Health, Taipei Medical University, Taipei, Taiwan (China); Department of Public Health, Tzu-Chi University, Hualien, Taiwan (China); Graduate Institute of Preventive Medicine, National Taiwan University, Taipei, Taiwan (China)

2007-08-01T23:59:59.000Z

342

Kinetic Modeling for a Semi-Interpenetrating Polymer Network (SIPN) Process  

E-Print Network [OSTI]

Kinetic Modeling for a Semi-Interpenetrating Polymer Network (SIPN) Process Advisor: Lorenz T A ·Networking component Polymer A chain Linear Polymer B Grafted Polymer B Grafting/ Crosslinking site Fig 3 B ·Grafted chain ·Homo- polymer Part 2: Component A ·Networking component Polymer A chain Linear

Grossmann, Ignacio E.

343

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, T.

1984-09-28T23:59:59.000Z

344

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1986-01-01T23:59:59.000Z

345

Tailoring the Thermoelectric Behavior of Electrically Conductive Polymer Composites  

E-Print Network [OSTI]

fabrication temperatures. These concerns have led research efforts into electrically conductive polymer composites prepared in ambient conditions from aqueous solutions. By combining polymer latex with carbon nanotubes (CNT), electrical conductivity can...

Moriarty, Gregory P.

2013-05-21T23:59:59.000Z

346

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

347

Switchable window based on electrochromic polymers Chunye Xu,a)  

E-Print Network [OSTI]

Switchable window based on electrochromic polymers Chunye Xu,a) Lu Liu, Susan E. Legenski, Dai Ning March 2004) A large contrast ratio (> 60%) and rapid switching (0.3­1 s) electrochromic (EC) polymer

Taya, Minoru

348

An overview of molten polymer drawing instabilities Yves Demay1  

E-Print Network [OSTI]

dissipation in a screw/barrel device and then forced in a spinning pack consisting of a metal plaque of processes for polymer film production: · In the cast-film process, the polymer is melted in an extruder

Paris-Sud XI, Université de

349

Synthesis and Characterization of Polymer Nanocomposites for Energy Applications  

E-Print Network [OSTI]

Polymer nanocomposites are used in a variety of applications due to their good mechanical properties. Specifically, better performance of lithium ion batteries and thermal interface material can be obtained by using conductive materials and polymer...

Park, Wonchang

2011-10-21T23:59:59.000Z

350

Phase selectively soluble polymer supports to facilitate homogeneous catalysis  

E-Print Network [OSTI]

Soluble polymers that have phase selective solubility are useful in synthesis because they simplify purification and separation. Such selectively soluble polymers simplify catalyst, reagent, and product recovery and enable the use of Green chemistry...

Ortiz-Acosta, Denisse

2009-05-15T23:59:59.000Z

351

Multiobjective Design and Optimization of Polymer Flood Performance  

E-Print Network [OSTI]

The multiobjective genetic algorithm can be used to optimize two conflicting objectives, oil production and polymer utility factor in polymer flood design. This approach provides a set of optimal solutions which can be considered as trade-off curve...

Ekkawong, Peerapong

2013-07-22T23:59:59.000Z

352

Polymer-coated iron oxide nanoparticles for medical imaging  

E-Print Network [OSTI]

One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

Chen, Suelin, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

353

Modeling Cold Start in a Polymer-Electrolyte Fuel Cell  

E-Print Network [OSTI]

Boundary conditions used for fuel—cell simulations. 3.12to the Problem of Cold Start 1.1 Polymer—Electrolyte Fuelin Polymer Electrolyte Fuel Cells — II. Parametric Study,”

Balliet, Ryan

2010-01-01T23:59:59.000Z

354

Processing and thermal properties of molecularly oriented polymers  

E-Print Network [OSTI]

High molecular weight polymers that are linear in molecular construction can be oriented such that some of their physical properties in the oriented direction are enhanced. For over 50 years polymer orientation and processing ...

Skow, Erik (Erik Dean)

2007-01-01T23:59:59.000Z

355

Stretchable polymer-based electronic device  

DOE Patents [OSTI]

A stretchable electronic circuit or electronic device and a polymer-based process to produce a circuit or electronic device containing a stretchable conducting circuit. The stretchable electronic apparatus has a central longitudinal axis and the apparatus is stretchable in a longitudinal direction generally aligned with the central longitudinal axis. The apparatus comprises a stretchable polymer body and at least one circuit line operatively connected to the stretchable polymer body. The circuit line extends in the longitudinal direction and has a longitudinal component that extends in the longitudinal direction and has an offset component that is at an angle to the longitudinal direction. The longitudinal component and the offset component allow the apparatus to stretch in the longitudinal direction while maintaining the integrity of the circuit line.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA); Davidson, James Courtney (Livermore, CA); Wilson, Thomas S. (Castro Valley, CA); Hamilton, Julie K. (Tracy, CA); Benett, William J. (Livermore, CA); Tovar, Armando R. (San Antonio, TX)

2008-02-26T23:59:59.000Z

356

Study of Hydrophobic and Ionizable Hydrophilic Copolymers at Polymer/Solid and Polymer/Liquid Interfaces  

SciTech Connect (OSTI)

Joint experimental-computational efforts were set to characterize the interfacial effects on the structure and dynamics of polymers consisting of highly rigid hydrophilic-ionizable and hydrophobic sub-units within one polymeric chain casted into thin films of several molecular dimensions. Focusing on the ultra thin film region we separate out the interfacial effects from bulk characteristics. Specifically, the study sought to: identify the parameters that control the formation of a stable polymer-solid interface. The study consists of two components, experimental investigations and computational efforts. The experimental component was designed to derive empirical trends that can be used to correlate the set of coupled polymer molecular parameters with the interfacial characteristics of these polymers, and their response to presence of solvents. The computational study was designed to provide molecular insight into the ensemble averages provided by the experimental efforts on multiple length scales from molecular dimensions, to the nanometer lengths to a macroscopic understanding of solvent interactions with structured polymers. With the ultimate goal of correlating molecular parameters to structure, dynamics and properties of ionic polymers, the first stage of the research began with the study of two systems, one which allowed tailoring the flexibility of the backbone without the presence of ionic groups, but with a potential to sulfonate groups at a later stage, and a polymer whose backbone is rigid and the density of the ionic group can be varied. The combined experimental and computational studies significantly extended the understanding of polymers at interfaces from model systems to polydispersed copolymers with blocks of varying nature and complexity. This new insight directly affects the design of polymers for sustainable energy applications from batteries and fuel cells to solar energy.

Perahia, Dvora

2011-11-01T23:59:59.000Z

357

Solid polymer electrolyte from phosphorylated chitosan  

SciTech Connect (OSTI)

Recently, the need of secondary battery application continues to increase. The secondary battery which using a liquid electrolyte was indicated had some weakness. A solid polymer electrolyte is an alternative electrolytes membrane which developed in order to replace the liquid electrolyte type. In the present study, the effect of phosphorylation on to polymer electrolyte membrane which synthesized from chitosan and lithium perchlorate salts was investigated. The effect of the component’s composition respectively on the properties of polymer electrolyte, was carried out by analyzed of it’s characterization such as functional groups, ion conductivity, and thermal properties. The mechanical properties i.e tensile resistance and the morphology structure of membrane surface were determined. The phosphorylation processing of polymer electrolyte membrane of chitosan and lithium perchlorate was conducted by immersing with phosphoric acid for 2 hours, and then irradiated on a microwave for 60 seconds. The degree of deacetylation of chitosan derived from shrimp shells was obtained around 75.4%. Relative molecular mass of chitosan was obtained by viscometry method is 796,792 g/mol. The ionic conductivity of chitosan membrane was increase from 6.33 × 10{sup ?6} S/cm up to 6.01 × 10{sup ?4} S/cm after adding by 15 % solution of lithium perchlorate. After phosphorylation, the ionic conductivity of phosphorylated lithium chitosan membrane was observed 1.37 × 10{sup ?3} S/cm, while the tensile resistance of 40.2 MPa with a better thermal resistance. On the strength of electrolyte membrane properties, this polymer electrolyte membrane was suggested had one potential used for polymer electrolyte in field of lithium battery applications.

Fauzi, Iqbal, E-mail: arcana@chem.itb.ac.id; Arcana, I Made, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Groups, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2014-03-24T23:59:59.000Z

358

Novel Ceramic-Polymer Composite Membranes for the Separation of Hazardous Liquid Waste  

SciTech Connect (OSTI)

The present project was conceived to address the need for robust yet selective membranes suitable for operating in harsh ph, solvent, and temperature environments. An important goal of the project was to develop a membrane chemical modification technology that would allow one to tailor-design membranes for targeted separation tasks. The method developed in the present study is based on the process of surface graft polymerization. Using essentially the same base technology of surface modification the research was aimed at demonstrating that improved membranes can be designed for both pervaporation separation and ultrafiltration. In the case of pervaporation, the present study was the first to demonstrate that pervaporation can be achieved with ceramic support membranes modified with an essentially molecular layer of terminally anchored polymer chains. The main advantage of the above approach, relative to other proposed membranes, is that the separating polymer layer is covalently attached to the ceramic support. Therefore, such membranes have a potential use in organic-organic separations where the polymer can swell significantly yet membrane robustness is maintained due to the chemical linkage of the chains to be inorganic support. The above membrane technology was also useful in developing fouling resistant ultrafiltration membranes. The prototype membrane developed in the project was evaluated for the treatment of oil-in-water microemulsions, demonstrating lack of irreversible fouling common with commercial membranes.

Yoram Cohen

2001-12-01T23:59:59.000Z

359

Evaluation of Rexene polymers in hot mixed asphalt concrete  

E-Print Network [OSTI]

Committee: Dr. Dallas N. Little The objective of this research was to provide a comprehensive characterization of asphalt binders and paving mixtures modified with four polymers produced by the Rexene Products Company (Odessa, Texas). The four polymers... on control asphalt cements and polymer modified asphalt cements to quantify the effects of the Rexene polymers. Most importantly, the binder study was designed to determine the temperature susceptibility of the binders. Asphalt cements from three...

Rodriguez, Mary Anne Reese

1991-01-01T23:59:59.000Z

360

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents [OSTI]

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

2007 Status of Manufacturing: Polymer Electrolyte Membrane (PEM) Fuel Cells  

SciTech Connect (OSTI)

In this document we assess the North American industry's current ability to manufacture polymer electrolyte membrane (PEM) fuel cells.

Wheeler, D.; Sverdrup, G.

2008-03-01T23:59:59.000Z

362

Polymer-electrolyte membrane, electrochemical fuel cell, and related method  

DOE Patents [OSTI]

A polymer-electrolyte membrane is presented. The polymer-electrolyte membrane comprises an acid-functional polymer, and an additive incorporated in at least a portion of the membrane. The additive comprises a fluorinated cycloaliphatic additive, a hydrophobic cycloaliphatic additive, or combinations thereof, wherein the additive has a boiling point greater than about 120.degree. C. An electrochemical fuel cell including the polymer-electrolyte membrane, and a related method, are also presented.

Krishnan, Lakshmi; Yeager, Gary William; Soloveichik, Grigorii Lev

2014-12-09T23:59:59.000Z

363

SS-166-99-R06 Diabetes and the Older Adult  

E-Print Network [OSTI]

SS-166-99-R06 Diabetes and the Older Adult Approximately 18 million people (over 6% of the population) in the United States have diabetes. Another 16 million people have pre-diabetes, mean- ing that their blood glucose levels are higher than normal. It is estimated that 1 in 10 people will develop diabetes

364

Development and modeling of conducting polymer actuators and the fabrication of a conducting polymer based feedback loop  

E-Print Network [OSTI]

Conducting polymers as a class of materials can be used to build a diverse range of devices. Conducting polymer based actuators (muscles), transistors (neurons), strain gages (muscle spindles), force sensors (Golgi tendon ...

Madden, Peter Geoffrey Alexander, 1971-

2003-01-01T23:59:59.000Z

365

Superdiffusivity for a Brownian polymer in a continuous Gaussian environment  

E-Print Network [OSTI]

environment (random medium) which can be briefly described as follows: the polymer itself, in the absenceSuperdiffusivity for a Brownian polymer in a continuous Gaussian environment S´ergio Bezerra Samy the asymptotic behavior of a one-dimen- sional Brownian polymer in random medium represented by a Gaussian field

Tindel, Samy - Institut de Mathématiques �lie Cartan, Université Henri Poincaré

366

Sliding Friction with Polymer Brushes Rafael Tadmor,* Joanna Janik,  

E-Print Network [OSTI]

across the polymer layers decays logarithmically with time, consistent with the relaxation of a network on the sliding velocity, an effect attributed to a velocity-dependent interpenetration of the opposing polymerSliding Friction with Polymer Brushes Rafael Tadmor,* Joanna Janik, and Jacob Klein Department

Klein, Jacob

367

Review Article Polymers and Gels as Molecular Recognition Agents  

E-Print Network [OSTI]

-responsive hydrogels (10). These hydro- gels are semi-interpenetrating polymer networks with complementary antibodyReview Article Polymers and Gels as Molecular Recognition Agents Nicholas A. Peppas1,2,3 and Yanbin Huang1 Received December 7, 2001; accepted February 6, 2002 Synthetic polymers and gels capable

Peppas, Nicholas A.

368

CASIMIR EFFECT IN CROSSLINKED POLYMER BLENDS M. Benhamou  

E-Print Network [OSTI]

-potential. I. INTRODUCTION Interpenetrated polymer networks (IPNs) or crosslinked polymer blends constitute new interpenetrating networks used as electronic device encapsulants [3]. For certain practical realizations, the IPNsCASIMIR EFFECT IN CROSSLINKED POLYMER BLENDS M. Benhamou , M. Boughou, H. Ka¨idi M. El Yaznasni, H

Boyer, Edmond

369

Response of Lithium Polymer Batteries to Mechanical Loading  

E-Print Network [OSTI]

Response of Lithium Polymer Batteries to Mechanical Loading Karl Suabedissen1, Christina Peabody2 · Lithium polymer batteries are everywhere. · Efforts to create flexible batteries. · Restrictive battery performance. #12;Lithium Polymer Battery Structure · Al cathode coated with LiCoO2. · Cu anode coated

Petta, Jason

370

Effects of g Radiation on Fiber-Reinforced Polymer Concrete  

E-Print Network [OSTI]

Effects of g Radiation on Fiber-Reinforced Polymer Concrete Gonzalo Marti´nez-Barrera,1,2 Luis F% of nylon fibers. The fiber-containing polymer concretes (PCs) were subjected to 5, 10, 50, and 100 k Engineers INTRODUCTION AND SCOPE It is well known that polymer concrete (PC) is three to five times stronger

North Texas, University of

371

Polymers containing borane or carborane cage compounds and related applications  

DOE Patents [OSTI]

Polymers comprising residues of borane and/or carborane cage compound monomers having at least one polyalkoxy silyl substituent. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Methods of making and applications for using such polymers are also disclosed.

Bowen, III, Daniel E. (Olathe, KS); Eastwood, Eric A. (Raymore, MO)

2012-06-05T23:59:59.000Z

372

Mechanically flexible organic electroluminescent device with directional light emission  

DOE Patents [OSTI]

A mechanically flexible and environmentally stable organic electroluminescent ("EL") device with directional light emission comprises an organic EL member disposed on a flexible substrate, a surface of which is coated with a multilayer barrier coating which includes at least one sublayer of a substantially transparent organic polymer and at least one sublayer of a substantially transparent inorganic material. The device includes a reflective metal layer disposed on the organic EL member opposite to the substrate. The reflective metal layer provides an increased external quantum efficiency of the device. The reflective metal layer and the multilayer barrier coating form a seal around the organic EL member to reduce the degradation of the device due to environmental elements.

Duggal, Anil Raj; Shiang, Joseph John; Schaepkens, Marc

2005-05-10T23:59:59.000Z

373

Method of making organic light emitting devices  

DOE Patents [OSTI]

The present invention provides a method for the preparation of organic light-emitting devices comprising a bilayer structure made by forming a first film layer comprising an electroactive material and an INP precursor material, and exposing the first film layer to a radiation source under an inert atmosphere to generate an interpenetrating network polymer composition comprising the electroactive material. At least one additional layer is disposed on the reacted first film layer to complete the bilayer structure. The bilayer structure is comprised within an organic light-emitting device comprising standard features such as electrodes and optionally one or more additional layers serving as a bipolar emission layer, a hole injection layer, an electron injection layer, an electron transport layer, a hole transport layer, exciton-hole transporting layer, exciton-electron transporting layer, a hole transporting emission layer, or an electron transporting emission layer.

Shiang, Joseph John (Niskayuna, NY); Janora, Kevin Henry (Schenectady, NY); Parthasarathy, Gautam (Saratoga Springs, NY); Cella, James Anthony (Clifton Park, NY); Chichak, Kelly Scott (Clifton Park, NY)

2011-03-22T23:59:59.000Z

374

Spontaneous helicity of a polymer with side-loops confined to a cylinder  

E-Print Network [OSTI]

Inspired by recent experiments on the spatial organization of bacterial chromosomes, we consider a type of "bottle brush" polymer consisting of a flexible backbone chain, to which flexible side loops are connected. We show that such a model with an open linear backbone spontaneously adopts a helical structure with a well-defined pitch when confined to small cylindrical volume. This helicity persists over a range of sizes and aspect-ratios of the cylinder, provided the packing fraction of the chain is suitably large. We analyze this results in terms of the interplay between the effective stiffness and actual intra-chain packing effects caused by the side-loops in response to the confinement. For the case of a circular backbone, mimicking e.g. the E. coli chromosome, the polymer adopts a linearized configuration of two parallel helices connected at the cylinder poles.

Chaudhuri, Debasish

2011-01-01T23:59:59.000Z

375

Do the Defects Make It Work? Defect Engineering in Pi-Conjugated Polymers and Their Solar Cells: Preprint  

SciTech Connect (OSTI)

The charged defect density in common pi-conjugated polymers such as poly(3-hexylthiophene), P3HT, is around 1018 cm-3. Despite, or perhaps because of, this huge defect density, bulk heterojunction solar cells made from these polymers and a C60 derivative such as PCBM exhibit some of the highest efficiencies (~5%) yet obtained in solid state organic photovoltaic cells. We discuss defects in molecular organic semiconductors and in pi-conjugated polymers. These defects can be grouped in two categories, covalent and noncovalent. Somewhat analogous to treating amorphous silicon with hydrogen, we introduce chemical methods to modify the density and charge of the covalent defects in P3HT by treating it with electrophiles such as dimethyl sulfate and nucleophiles such as sodium methoxide. The effects of these treatments on the electrical and photovoltaic properties and stability of organic PV cells is discussed in terms of the change in the number and chemical properties of the defects. Finally, we address the question of whether the efficiency of OPV cells requires the presence of these defects which function as adventitious p-type dopants. Their presence relieves the resistance limitations usually encountered in cleaner organic semiconductors and can create built-in electric fields at junctions.

Wang, D.; Reese, M.; Kopidakis N.; Gregg, B. A.

2008-05-01T23:59:59.000Z

376

Characterization of the Polymer Energy Landscape in Polymer:Fullerene Bulk Heterojunctions with Pure and Mixed Phases  

E-Print Network [OSTI]

Characterization of the Polymer Energy Landscape in Polymer:Fullerene Bulk Heterojunctions with Pure and Mixed Phases Sean Sweetnam, Kenneth R. Graham,, Guy O. Ngongang Ndjawa, Thomas Heumuller offsets between the charge transport energy levels in different morphological phases of polymer

McGehee, Michael

377

Mechanics of amorphous polymers and polymer nanocomposites during high rate deformation  

E-Print Network [OSTI]

It has been suggested that a polymer's macroscopic mechanical response to a general loading case is governed by its ability to access various primary and secondary molecular mobilities. Specifically, under conditions of ...

Mulliken, Adam Dustin, 1979-

2006-01-01T23:59:59.000Z

378

Extensional rheology of polymers and optical properties of blown polymer films  

E-Print Network [OSTI]

of blown polymer films, the product of a major process with biaxial flows, are related to the mechanical properties of the alms and a novel lubricated squeezing rheometer for generating pure biaxial elongation is constructed and tested in constant strain...

Maxey, Jason E

1998-01-01T23:59:59.000Z

379

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty  

E-Print Network [OSTI]

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty perform research in molecular machines, exotic CHEMISTRY FACULTY RESEARCH INTERESTS Anne M. Andrews, Professor-in-Residence: Understanding how areas of interest include cross- coupling reactions, green chemistry, heterocycle synthesis, and natural

Levine, Alex J.

380

Adaptive changes in renal mitochondrial redox status in diabetic nephropathy  

SciTech Connect (OSTI)

Nephropathy is a serious and common complication of diabetes. In the streptozotocin (STZ)-treated rat model of diabetes, nephropathy does not typically develop until 30 to 45 days post-injection, although hyperglycemia occurs within 24 h. We tested the hypothesis that chronic hyperglycemia results in a modest degree of oxidative stress that is accompanied by compensatory changes in certain antioxidants and mitochondrial redox status. We propose that as kidneys progress to a state of diabetic nephropathy, further adaptations occur in mitochondrial redox status. Basic parameters of renal function in vivo and several parameters of mitochondrial function and glutathione (GSH) and redox status in isolated renal cortical mitochondria from STZ-treated and age-matched control rats were examined at 30 days and 90 days post-injection. While there was no effect of diabetes on blood urea nitrogen, measurement of other, more sensitive parameters, such as urinary albumin and protein, and histopathology showed significant and progressive worsening in diabetic rats. Thus, renal function is compromised even prior to the onset of frank nephropathy. Changes in mitochondrial respiration and enzyme activities indicated existence of a hypermetabolic state. Higher mitochondrial GSH content and rates of GSH transport into mitochondria in kidneys from diabetic rats were only partially due to changes in expression of mitochondrial GSH carriers and were mostly due to higher substrate supply. Although there are few clear indicators of oxidative stress, there are several redox changes that occur early and change further as nephropathy progresses, highlighting the complexity of the disease. Highlights: ?Adaptive changes in renal mitochondrial and redox status in diabetic rats. ?Modest renal dysfunction even prior to onset of nephropathy. ?Elevated concentrations of mitochondrial GSH in diabetic kidneys. ?Change in GSH due partly to increased protein expression of transporter. ?Oxidatively modified proteins in renal mitochondria from diabetic rats.

Putt, David A.; Zhong, Qing; Lash, Lawrence H., E-mail: l.h.lash@wayne.edu

2012-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Diabetes and mitochondrial function: Role of hyperglycemia and oxidative stress  

SciTech Connect (OSTI)

Hyperglycemia resulting from uncontrolled glucose regulation is widely recognized as the causal link between diabetes and diabetic complications. Four major molecular mechanisms have been implicated in hyperglycemia-induced tissue damage: activation of protein kinase C (PKC) isoforms via de novo synthesis of the lipid second messenger diacylglycerol (DAG), increased hexosamine pathway flux, increased advanced glycation end product (AGE) formation, and increased polyol pathway flux. Hyperglycemia-induced overproduction of superoxide is the causal link between high glucose and the pathways responsible for hyperglycemic damage. In fact, diabetes is typically accompanied by increased production of free radicals and/or impaired antioxidant defense capabilities, indicating a central contribution for reactive oxygen species (ROS) in the onset, progression, and pathological consequences of diabetes. Besides oxidative stress, a growing body of evidence has demonstrated a link between various disturbances in mitochondrial functioning and type 2 diabetes. Mutations in mitochondrial DNA (mtDNA) and decreases in mtDNA copy number have been linked to the pathogenesis of type 2 diabetes. The study of the relationship of mtDNA to type 2 diabetes has revealed the influence of the mitochondria on nuclear-encoded glucose transporters, glucose-stimulated insulin secretion, and nuclear-encoded uncoupling proteins (UCPs) in {beta}-cell glucose toxicity. This review focuses on a range of mitochondrial factors important in the pathogenesis of diabetes. We review the published literature regarding the direct effects of hyperglycemia on mitochondrial function and suggest the possibility of regulation of mitochondrial function at a transcriptional level in response to hyperglycemia. The main goal of this review is to include a fresh consideration of pathways involved in hyperglycemia-induced diabetic complications.

Rolo, Anabela P. [Center for Neurosciences and Cell Biology of Coimbra, Department of Zoology, University of Coimbra, 3004-517 Coimbra (Portugal); Palmeira, Carlos M. [Center for Neurosciences and Cell Biology of Coimbra, Department of Zoology, University of Coimbra, 3004-517 Coimbra (Portugal)]. E-mail: palmeira@ci.uc.pt

2006-04-15T23:59:59.000Z

382

Thermoset epoxy polymers from renewable resources  

DOE Patents [OSTI]

Novel thermoset epoxy polymers using the bisglycidyl ethers of anhydrosugars, such as isosorbide, isomannide, and isoidide, are disclosed. The bisglycidyl ethers are useful as substitutes for bisphenol A in the manufacture of thermoset epoxy ethers. The anhydrosugars are derived from renewable sources and the bisglycidyl ethers are not xenoestrogenic and the thermoset curing agents are likewise derived form renewable resources.

East, Anthony (Madison, NJ); Jaffe, Michael (Maplewood, NJ); Zhang, Yi (Harrison, NJ); Catalani, Luiz H (Carapicuiba, BR)

2009-11-17T23:59:59.000Z

383

Water-soluble polymers and compositions thereof  

DOE Patents [OSTI]

Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.

Smith, B.F.; Robison, T.W.; Gohdes, J.W.

1999-04-06T23:59:59.000Z

384

Preparation and characterization of gradient polymer films  

SciTech Connect (OSTI)

Gradient polymers are multicomponent polymers whose chemical constitution varies with depth in the sample. Although these polymers may possess unique mechanical, optical, and barrier properties they remain relatively unexplored. This work is a study of the preparation of gradient polymers by sequential exposure of films to a diffusing monomer followed by electron beam irradiation. Initial experiments involved immersion of poly(vinyl chloride) (PVC) films in styrene or n-butyl methacrylate (BMA) for various time periods followed by irradiation with 1 or 10 megarads of accelerated electrons. A significant amount of poly(n-butyl methacrylate) (PBMA) formed in PVC/BMA systems, but little polystyrene could be found in the PVC/styrene films. A second set of experiments involved immersion of PVC and polyethylene (PE) films in BMA for 20, 40, 60, and 720 minutes followed by irradiation with 10 megarads of electrons. These films were then characterized using optical microscopy, quantitative transmission Fourier transform infrared spectroscopy (FTIR), and a depth profiling procedure based on quantitative attenuated total reflection (ATR) FTIR. It was concluded that the mechanism of PBMA formation in the polyethylene films was a result of events immediately following irradiation. Atmospheric oxygen diffusing into irradiated films trapped free radicals at the film surfaces. This was followed by storage in an evacuated desiccator where unintentional exposure to BMA vapor took place. This BMA reacted with free radicals that remained within the film cores, polymerizing to PBMA.

Smith, S.C.

1987-01-01T23:59:59.000Z

385

Phase behavior of polymers and monomers  

E-Print Network [OSTI]

valid and reliable model, research costs would decrease and estimates for a polymer system's cloud-point could be quickly available to prevent unit shutdowns, equipment damage and possible loss of life. Hasch and McHugh (1992) used the Sanchez-Lacombe...

Purifoy, Jonathan Patrick

1998-01-01T23:59:59.000Z

386

Polymer microcantilevers fabricated via multiphoton absorption polymerization  

E-Print Network [OSTI]

Polymer microcantilevers fabricated via multiphoton absorption polymerization Z. Bayindir, Y. Sun February 2005 We have used multiphoton absorption polymerization to fabricate a series of microscale.1063/1.1863414 Multiphoton absorption polymerization MAP 1­4 offers the unparalleled ability to create arbitrarily complex 3D

Teich, Malvin C.

387

SURFACTANT - POLYMER INTERACTION FOR IMPROVED OIL RECOVERY  

SciTech Connect (OSTI)

The goal of this research is to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, adsorption and mobility control. Surfactant--polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation, high adsorption and viscous/heterogeneity fingering. This report contains data concerning selection of appropriate fluids for use in laboratory experiments and numerical simulations. A mixture comprising a ''pseudo oil'' with appropriate surfactant and polymer is proposed. The properties of this system has been determined. The experimental set-up has been conditioned for use and experiments involving the aforementioned system have already started. A commercial simulator has been acquired for use in reproducing the experiments. A graduate student has been trained in its use. Linear stability analysis equations have been developed and phase maps for one and two-dimensions are currently computed.

Unknown

1997-09-01T23:59:59.000Z

388

Polymer Expansions for Cycle LDPC Codes  

E-Print Network [OSTI]

We prove that the Bethe expression for the conditional input-output entropy of cycle LDPC codes on binary symmetric channels above the MAP threshold is exact in the large block length limit. The analysis relies on methods from statistical physics. The finite size corrections to the Bethe expression are expressed through a polymer expansion which is controlled thanks to expander and counting arguments.

Nicolas Macris; Marc Vuffray

2012-02-13T23:59:59.000Z

389

Ultrafast Large Area Micropattern Generation in Non-absorbing Polymer Thin-Films by Pulsed Laser Diffraction  

E-Print Network [OSTI]

We report an ultrafast, parallel and beyond-the-master micro-patterning technique for ultrathin (30 nm-400 nm) non-absorbing polymer films by diffraction of a laser light through a two dimensional periodic aperture. The redistribution of laser energy absorbed by the substrate causes self-organization of polymer thin-film in the form of wrinkle like surface relief structures caused by localized melting and freezing of the thin-film. Unlike the conventional laser ablation and laser writing processes, low laser fluence is employed to only passively swell the polymer as a pre-ablative process without the loss of material, and without absorption/reaction with the incident radiation. Self-organization in the thin polymer film aided by the diffraction pattern produces micro-structures made up of thin raised lines. These regular microstructures have far more complex morphologies than the mask geometry and very narrow line widths that can be an order of magnitude smaller than the openings in the mask. The microstructure morphology is easily modulated by changing the film thickness, aperture size and geometry and by changing the diffraction pattern, e.g., by changing the aperture-substrate distance.

Ankur Verma; Ashutosh Sharma; Giridhar U. Kulkarni

2011-01-27T23:59:59.000Z

390

Methods of making composite optical devices employing polymer liquid crystal  

DOE Patents [OSTI]

Composite optical devices are disclosed using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T[sub g]) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device. 7 figures.

Jacobs, S.D.; Marshall, K.L.; Cerqua, K.A.

1991-10-08T23:59:59.000Z

391

Methods of making composite optical devices employing polymer liquid crystal  

DOE Patents [OSTI]

Composite optical devices using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T.sub.g) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device.

Jacobs, Stephen D. (Pittsford, NY); Marshall, Kenneth L. (Henrietta, NY); Cerqua, Kathleen A. (Fairport, NY)

1991-01-01T23:59:59.000Z

392

Durable polymer-aerogel based superhydrophobic coatings, a composite material  

DOE Patents [OSTI]

Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140.degree. and a contact angle hysteresis of less than about 1.degree.. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

Kissel, David J; Brinker, Charles Jeffrey

2014-03-04T23:59:59.000Z

393

Supercritical extraction of organic mixtures from soil-water slurries  

E-Print Network [OSTI]

of sand, silt, and clay tractions. Of the organic portion, roughly 1-5N is lipids, 10-2(P/o is polysaccharides, and the rest of the organic matter is composed of humic and fulvic acids which are "ill-characterized hydrophilic polymers containing..., methoxy and other ether groups, and amides and other carbonyls" (Dooley et al. , 1990), The molecular weights of humic acids can be as high as 10' and those of fulvic acids range from 500 to 1000. Humicacids are soluble in only strong bases, whereas...

Green, Lynda Ann

1994-01-01T23:59:59.000Z

394

australian diabetes obesity: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Martin Conference Center at Harvard Medical School, Boston, Massachusetts October 1-2, 2014 Novo Nordisk, a world leader in diabetes are offered under a new scheme called the Novo...

395

Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings  

SciTech Connect (OSTI)

The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

Rajendra Bordia

2009-07-31T23:59:59.000Z

396

Inorganic arsenic exposure and type 2 diabetes mellitus in Mexico  

SciTech Connect (OSTI)

Inorganic arsenic exposure in drinking water has been recently related to diabetes mellitus. To evaluate this relationship the authors conducted in 2003, a case-control study in an arseniasis-endemic region from Coahuila, a northern state of Mexico with a high incidence of diabetes. The present analysis includes 200 cases and 200 controls. Cases were obtained from a previous cross-sectional study conducted in that region. Diagnosis of diabetes was established following the American Diabetes Association criteria, with two fasting glucose values {>=}126 mg/100 ml ({>=}7.0 mmol/l) or a history of diabetes treated with insulin or oral hypoglycemic agents. The next subject studied, subsequent to the identification of a case in the cross-sectional study was taken as control. Inorganic arsenic exposure was measured through total arsenic concentrations in urine, measured by hydride-generation atomic absorption spectrophotometry. Subjects with intermediate total arsenic concentration in urine (63.5-104 {mu}g/g creatinine) had two-fold higher risk of having diabetes (odds ratio=2.16; 95% confidence interval: 1.23, 3.79), but the risk was almost three times greater in subjects with higher concentrations of total arsenic in urine (odds ratio=2.84; 95% confidence interval: 1.64, 4.92). This data provides additional evidence that inorganic arsenic exposure may be diabetogenic.

Coronado-Gonzalez, Jose Antonio [Clinical Epidemiologic Research Unit, General Regional Hospital 1 'Gabriel Mancera', Mexican Institute of the Social Security, Mexico, D.F. (Mexico); Razo, Luz Maria del [Toxicology Departament, Cinvestav, Mexico D.F. (Mexico); Garcia-Vargas, Gonzalo [School of Medicine, Durango State Juarez University, Gomez Palacio, Durango (Mexico); Biomedical Research Center, Coahuila, Autonomous University, Torreon, Coahuila (Mexico); Sanmiguel-Salazar, Francisca [Biomedical Research Center, Coahuila, Autonomous University, Torreon, Coahuila (Mexico); Escobedo-de la Pena, Jorge [Clinical Epidemiologic Research Unit, General Regional Hospital 1 'Gabriel Mancera', Mexican Institute of the Social Security, Mexico, D.F. (Mexico)]. E-mail: jorgeep@servidor.unam.mx

2007-07-15T23:59:59.000Z

397

Alterations in skeletal muscle arteriolar vasoreactivity during the progression of type 2 diabetes in the Zucker Diabetic Fatty rat  

E-Print Network [OSTI]

Altered vasoreactivity and mechanical properties of skeletal muscle arterioles could impact peripheral insulin resistance and hypertension observed in type 2 diabetes. The purpose was to determine if increased vasoconstrictor reactivity, decreased...

Lesniewski, Lisa AnnMarie

2004-09-30T23:59:59.000Z

398

Development of New Absorber Materials to Achieve Organic Photovoltaic Commercial Modules with 15% Efficiency and 20 Years Lifetime: Cooperative Research and Development Final Report, CRADA Number CRD-12-498  

SciTech Connect (OSTI)

Under this CRADA the parties will develop intermediates or materials that can be employed as the active layer in dye sensitized solar cells printed polymer systems, or small molecule organic photovoltaics.

Olson, D.

2014-08-01T23:59:59.000Z

399

Ernesto Joselevich Research Summary -May 2008 Molecular Wires: From Self-Organization to Functional Nanosystems  

E-Print Network [OSTI]

-dimensional nanostructures, such as carbon nanotubes, inorganic nanowires and polymers, their integration into functional the development of epitaxial approaches to carbon nanotube organization, namely, the directed growth of carbon highly straight, kinked, wavy, crossed8 , serpentine9 and looped. A second contribution has been

Martin, Jan M.L.

400

Local tuning of organic light-emitting diode color by dye droplet application  

E-Print Network [OSTI]

Local tuning of organic light-emitting diode color by dye droplet application T. R. Hebner and J. C 1998 We have demonstrated that fluorescent dyes may be introduced into previously fabricated polymer thin films by local application of a dye-containing droplet. The UV fluorescence spectra of the films

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Organic sponges for cost-effective CVOC abatement. Final report, September 1992--April 1994  

SciTech Connect (OSTI)

Air contaminated with CVOCs (chlorinated volatile organic compounds) arise from air stripping of ground water or from soil and dual phase vapor extraction. A research program was undertaken to develop sorbents better than activated carbon for remediation. Two such sorbents were found: Dow`s XUS polymer and Rohm and Haas` Ambersorb 563 (carbonaceous). Opportunities exist to further develop sorption and biodegradation technologies.

Flanagan, W.P.; Grade, M.M.; Horney, D.P.; Mackenzie, P.D.; Salvo, J.J.; Sivavec, T.M.; Stephens, M.L.

1994-07-01T23:59:59.000Z

402

Towards an understanding of light activation processes in titanium oxide based inverted organic solar cells  

E-Print Network [OSTI]

solar cells S. Chambon, E. Destouesse, B. Pavageau, L. Hirsch, and G. Wantz Citation: J. Appl. Phys. 112. Related Articles Power losses in bilayer inverted small molecule organic solar cells Appl. Phys. Lett. 101, 233903 (2012) Thin-film encapsulation of inverted indium-tin-oxide-free polymer solar cells by atomic

Paris-Sud XI, Université de

403

Metal-doped organic foam  

DOE Patents [OSTI]

Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1982-01-01T23:59:59.000Z

404

Departmental Organization and Management  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Effective immediately, the Departmental organization structure reflected in the chart at Attachment 1 has been approved.

1993-06-10T23:59:59.000Z

405

USE OF POLYMERS TO RECOVER VISCOUS OIL FROM UNCONVENTIONAL RESERVOIRS  

SciTech Connect (OSTI)

This final technical progress report summarizes work performed the project, 'Use of Polymers to Recover Viscous Oil from Unconventional Reservoirs.' The objective of this three-year research project was to develop methods using water soluble polymers to recover viscous oil from unconventional reservoirs (i.e., on Alaska's North Slope). The project had three technical tasks. First, limits were re-examined and redefined for where polymer flooding technology can be applied with respect to unfavorable displacements. Second, we tested existing and new polymers for effective polymer flooding of viscous oil, and we tested newly proposed mechanisms for oil displacement by polymer solutions. Third, we examined novel methods of using polymer gels to improve sweep efficiency during recovery of unconventional viscous oil. This report details work performed during the project. First, using fractional flow calculations, we examined the potential of polymer flooding for recovering viscous oils when the polymer is able to reduce the residual oil saturation to a value less than that of a waterflood. Second, we extensively investigated the rheology in porous media for a new hydrophobic associative polymer. Third, using simulation and analytical studies, we compared oil recovery efficiency for polymer flooding versus in-depth profile modification (i.e., 'Bright Water') as a function of (1) permeability contrast, (2) relative zone thickness, (3) oil viscosity, (4) polymer solution viscosity, (5) polymer or blocking-agent bank size, and (6) relative costs for polymer versus blocking agent. Fourth, we experimentally established how much polymer flooding can reduce the residual oil saturation in an oil-wet core that is saturated with viscous North Slope crude. Finally, an experimental study compared mechanical degradation of an associative polymer with that of a partially hydrolyzed polyacrylamide. Detailed results from the first two years of the project may be found in our first and second annual reports. Our latest research results, along with detailed documentation of our past work, can be found on our web site at http://baervan.nmt.edu/randy/. As an overall summary of important findings for the project, polymer flooding has tremendous potential for enhanced recovery of viscous oil. Fear of substantial injectivity reduction was a primary hurdle that limited application of polymer flooding. However, that concern is largely mitigated by (1) use of horizontal wells and (2) judicious injection above the formation parting pressure. Field cases now exist where 200-300-cp polymer solutions are injected without significant reductions in injectivity. Concern about costs associated with injection of viscous polymer solutions was a second major hurdle. However, that concern is reduced substantially by realization that polymer viscosity increases approximately with the square of polymer concentration. Viscosity can be doubled with only a 40% increase in polymer concentration. Up to a readily definable point, increases in viscosity of the injected polymer solution are directly related to increases in sweep efficiency and oil recovery. Previously published simulation results - suggesting that shear-thinning polymer solutions were detrimental to sweep efficiency - were shown to be unfounded (both theoretically and experimentally).

Randall Seright

2011-09-30T23:59:59.000Z

406

Germanium films by polymer-assisted deposition  

DOE Patents [OSTI]

Highly ordered Ge films are prepared directly on single crystal Si substrates by applying an aqueous coating solution having Ge-bound polymer onto the substrate and then heating in a hydrogen-containing atmosphere. A coating solution was prepared by mixing water, a germanium compound, ethylenediaminetetraacetic acid, and polyethyleneimine to form a first aqueous solution and then subjecting the first aqueous solution to ultrafiltration.

Jia, Quanxi; Burrell, Anthony K.; Bauer, Eve; Ronning, Filip; McCleskey, Thomas Mark; Zou, Guifu

2013-01-15T23:59:59.000Z

407

Electrical condition monitoring method for polymers  

DOE Patents [OSTI]

An electrical condition monitoring method utilizes measurement of electrical resistivity of an age sensor made of a conductive matrix or composite disposed in a polymeric structure such as an electrical cable. The conductive matrix comprises a base polymer and conductive filler. The method includes communicating the resistivity to a measuring instrument and correlating resistivity of the conductive matrix of the polymeric structure with resistivity of an accelerated-aged conductive composite.

Watkins, Jr., Kenneth S. (Dahlonega, GA); Morris, Shelby J. (Hampton, VA); Masakowski, Daniel D. (Worcester, MA); Wong, Ching Ping (Duluth, GA); Luo, Shijian (Boise, ID)

2008-08-19T23:59:59.000Z

408

Polymer translocation into laterally unbounded confined environments  

E-Print Network [OSTI]

Using Langevin dynamics simulations in three dimensions (3D), we investigate the dynamics of polymer translocation into the regions between two parallel plane walls with separation $R$ under a driving force $F$, respectively. Compared with an unconfined environment, the translocation dynamics is greatly changed due to the crowding effect of the partially translocated monomers. Translocation time $\\tau$ initially decreases rapidly with increasing $R$ and then saturates for larger $R$, and the confined environment leads to a nonuniversal dependence of $\\tau$ on $F$.

Kaifu Luo; Ralf Metzler

2010-04-12T23:59:59.000Z

409

Lattice polymers with two competing collapse interactions  

E-Print Network [OSTI]

There have been separate studies of the polymer collapse transition, where the collapse was induced by two different types of attraction. In each case, the configurations of the polymer were given by the same subset of random walks being self-avoiding trails on the square lattice. Numerical evidence shows that when interacting via nearest-neighbour contacts, this transition is different from the collapse transition in square-lattice trails interacting via multiply visited sites. While both transitions are second-order, when interacting via nearest-neighbour contacts, the transition is relatively weak with a convergent specific heat, while when interacting via multiply visited sites, the specific heat diverges strongly. Moreover, an estimation of the crossover exponent for the nearest-neighbour contact interaction provides a value close to that of the canonical polymer collapse model of interacting self-avoiding walks, which also interact via nearest-neighbour contacts. From computer simulations using the flatPERM algorithm, we extend these studies by considering a model of self-avoiding trails on the square lattice containing both types of interaction, and which therefore contains all three of the models discussed above as special cases. We find that the strong multiply-visited site collapse is a singular point in the phase diagram and corresponds to a higher order multi-critical point separating a line of weak second-order transitions from a line of first-order transitions.

Andrea Bedini; Aleksander L Owczarek; Thomas Prellberg

2013-11-05T23:59:59.000Z

410

Free Energy of Twisted Semiflexible Polymers  

E-Print Network [OSTI]

We investigate the role of fluctuations in single molecule measurements of torque-link ($t-lk$) curves. For semiflexible polymers of finite persistence length (i.e. polymers with contour length $L$ comparable to the persistence length $L_P$), the torque versus link curve in the constant torque (isotorque) ensemble is distinct from the one in the constant link (isolink) ensemble. Thus, one encounters the conceptually interesting issue of a ``free energy of transition'' in switching ensembles while making torque-link measurements. We predict the dependence on the semiflexibility parameter $\\beta = L/L_P$ of this extra contribution to the free energy which shows up as an area in the torque-link plane. This can be tested against future torque-link experiments with single biopolymers. We bring out the inequivalence of torque-link curves for a stiff polymer and present explicit analytical expressions for the {\\it distinct} torque-link relations in the two ensembles and the free energy difference in switching ensembles in this context. The predictions of our work can be tested against single molecule experiments on torsionally constrained biopolymers.

Supurna Sinha

2008-05-16T23:59:59.000Z

411

Self-extinguishing Polymer/Organoclay Nanocomposites  

SciTech Connect (OSTI)

We demonstrated that self-extinguishing polymer nanocomposites, which can pass the stringent UL 94 V0 standard, can be successfully prepared by combining modified organoclays with traditional flame retardant (FR) agents. Using secondary ion mass spectrometry (SIMS) and transmission electron microscopy (TEM), we determined that the addition of modified clays, which can intercalate or exfoliate in the matrix, also improved the dispersion of the FR agents. Dynamic mechanical analysis (DMA) indicated that the clays increased the modulus of the polymer above T{sub g}, which prevented dripping during burning. Cone calorimetry test showed that the nanocomposites with both FR and organoclay, had a lower peak heat release rate (PHRR) and average mass loss rate (MLR) than those with only clay or the FR agents. Extended X-ray absorption fine structure (EXAFS) data confirmed that no FR/clay interactions occurred in the solid phase, and that the synergistic effects were due to gas phase reactions. Since this mechanism is not specific, it opens the possibility of formulating self-extinguishing materials from a large class of polymers.

Si,M.; Zaitsev, V.; Goldman, M.; Frenkel, A.; Peiffer, D.; Weil, E.; Sokolov, J.; Rafailovich, M.

2006-01-01T23:59:59.000Z

412

"Smart" Multifunctional Polymers for Enhanced Oil Recovery  

SciTech Connect (OSTI)

Recent recommendations made by the Department of Energy, in conjunction with ongoing research at the University of Southern Mississippi, have signified a need for the development of 'smart' multi-functional polymers (SMFPs) for Enhanced Oil Recovery (EOR) processes. Herein we summarize research from the period of September 2003 through March 2007 focusing on both Type I and Type II SMFPs. We have demonstrated the synthesis and behavior of materials that can respond in situ to stimuli (ionic strength, pH, temperature, and shear stress). In particular, Type I SMFPs reversibly form micelles in water and have the potential to be utilized in applications that serve to lower interfacial tension at the oil/water interface, resulting in emulsification of oil. Type II SMFPs, which consist of high molecular weight polymers, have been synthesized and have prospective applications related to the modification of fluid viscosity during the recovery process. Through the utilization of these advanced 'smart' polymers, the ability to recover more of the original oil in place and a larger portion of that by-passed or deemed 'unrecoverable' by conventional chemical flooding should be possible.

Charles McCormick; Andrew Lowe

2007-03-20T23:59:59.000Z

413

Entropic pressure in lattice models for polymers  

E-Print Network [OSTI]

In lattice models local pressure on a surface is derived from the change in the free energy of the system due to the exclusion of a certain boundary site, while the total force on the surface can be obtained by a similar exclusion of all surface sites. In these definitions, while the total force on the surface of a lattice system matches the force measured in a continuous system, the local pressure does not. Moreover, in a lattice system, the sum of the local pressures is not equal to the total force as is required in a continuous system. The difference is caused by correlation between occupations of surface sites as well as finite displacement of surface elements used in the definition of the pressures and the force. This problem is particularly acute in the studies of entropic pressure of polymers represented by random or self-avoiding walks on a lattice. We propose a modified expression for the local pressure which satisfies the proper relation between the pressure and the total force, and show that for ideal polymers in the presence of scale-invariant boundaries it produces quantitatively correct values for continuous systems. The required correction to the pressure is non-local, i.e., it depends on long range correlations between contact points of the polymer and the surface.

Yosi Hammer; Yacov Kantor

2014-11-20T23:59:59.000Z

414

Solid polymer electrolyte composite membrane comprising laser micromachined porous support  

DOE Patents [OSTI]

A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a rigid, non-electrically-conducting support, the support preferably being a sheet of polyimide having a thickness of about 7.5 to 15 microns. The support has a plurality of cylindrical pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores, which preferably have a diameter of about 5 microns, are made by laser micromachining and preferably are arranged in a defined pattern, for example, with fewer pores located in areas of high membrane stress and more pores located in areas of low membrane stress. The pores are filled with a first solid polymer electrolyte, such as a perfluorosulfonic acid (PFSA) polymer. A second solid polymer electrolyte, which may be the same as or different than the first solid polymer electrolyte, may be deposited over the top and/or bottom of the first solid polymer electrolyte.

Liu, Han (Waltham, MA); LaConti, Anthony B. (Lynnfield, MA); Mittelsteadt, Cortney K. (Natick, MA); McCallum, Thomas J. (Ashland, MA)

2011-01-11T23:59:59.000Z

415

Solid electrolyte material manufacturable by polymer processing methods  

DOE Patents [OSTI]

The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1.times.10.sup.6 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1.times.10.sup.-5 Scm-1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.

Singh, Mohit; Gur, Ilan; Eitouni, Hany Basam; Balsara, Nitash Pervez

2012-09-18T23:59:59.000Z

416

Mobile monolithic polymer elements for flow control in microfluidic devices  

DOE Patents [OSTI]

A cast-in-place and lithographically shaped mobile, monolithic polymer element for fluid flow control in microfluidic devices and method of manufacture. Microfluid flow control devices, or microvalves that provide for control of fluid or ionic current flow can be made incorporating a cast-in-place, mobile monolithic polymer element, disposed within a microchannel, and driven by fluid pressure (either liquid or gas) against a retaining or sealing surface. The polymer elements are made by the application of lithographic methods to monomer mixtures formulated in such a way that the polymer will not bond to microchannel walls. The polymer elements can seal against pressures greater than 5000 psi, and have a response time on the order of milliseconds. By the use of energetic radiation it is possible to depolymerize selected regions of the polymer element to form shapes that cannot be produced by conventional lithographic patterning and would be impossible to machine.

Hasselbrink, Jr., Ernest F. (Saline, MI); Rehm, Jason E. (Alameda, CA); Shepodd, Timothy J. (Livermore, CA); Kirby, Brian J. (San Francisco, CA)

2005-11-11T23:59:59.000Z

417

Mobile Monolith Polymer Elements For Flow Control In Microfluidic Systems  

DOE Patents [OSTI]

A cast-in-place and lithographically shaped mobile, monolithic polymer element for fluid flow control in microfluidic devices and method of manufacture. Microfluid flow control devices, or microvalves that provide for control of fluid or ionic current flow can be made incorporating a cast-in-place, mobile monolithic polymer element, disposed within a microchannel, and driven by fluid pressure (either liquid or gas) against a retaining or sealing surface. The polymer elements are made by the application of lithographic methods to monomer mixtures formulated in such a way that the polymer will not bond to microchannel walls. The polymer elements can seal against pressures greater than 5000 psi, and have a response time on the order of milliseconds. By the use of energetic radiation it is possible to depolymerize selected regions of the polymer element to form shapes that cannot be produced by conventional lithographic patterning and would be impossible to machine.

Hasselbrink, Jr., Ernest F. (Saline, MI); Rehm, Jason E. (Alameda, CA); Shepodd, Timothy J. (Livermore, CA); Kirby, Brian J. (San Francisco, CA)

2006-01-24T23:59:59.000Z

418

Electric-field-driven polymer entry into asymmetric nanoscale channels  

E-Print Network [OSTI]

The electric-field-driven entry process of flexible charged polymers such as single stranded DNA (ssDNA) into asymmetric nanoscale channels such as alpha-hemolysin protein channel is studied theoretically and using molecular dynamics simulations. Dependence of the height of the free-energy barrier on the polymer length, the strength of the applied electric field and the channel entrance geometry is investigated. It is shown that the squeezing effect of the driving field on the polymer and the lateral confinement of the polymer before its entry to the channel crucially affect the barrier height and its dependence on the system parameters. The attempt frequency of the polymer for passing the channel is also discussed. Our theoretical and simulation results support each other and describe related data sets of polymer translocation experiments through the alpha-hemolysin protein channel reasonably well.

Narges Nikoofard; Hossein Fazli

2012-02-25T23:59:59.000Z

419

Monitoring polymer properties in production wells of Chateaurenard oilfield  

SciTech Connect (OSTI)

A polymer flooding test was conducted in the Chateaurenard field (France) from 1985 to 1989. The test was run on a ten-acre inverted five-spot. A total of 240,000 m{sup 3} of partially hydrolyzed polyacrylamide at a concentration of 1000 ppm was injected followed by an equal volume of solution but at a tapered concentration. A strong response in oil recovery for three of the four producers was observed. This paper reports on an original methodology that was designed for sampling and analyzing the polymer in the effluents of the producing wells. Concentrations and main characteristics of produced polyacrylamide were determined versus injected volume. No degradation of the polymer was detected. A molecular weight fractionation during polymer slug propagation into the reservoir due to adsorption/retention chromatography was observed. The low-polymer concentration of the effluents could be explained by a strong retention of the polymer in the low permeability zones of the reservoir.

Putz, A.G. (Elf Aquitaine, Avenue Larribau, Pau (FR)); Lecourtier, J. (Inst. Francais du Petrole, Avenue Bois-Preau, 92500 Rueil-Malmaison (FR))

1991-01-01T23:59:59.000Z

420

Localization and diffusion in polymer quantum field theory  

E-Print Network [OSTI]

Polymer quantization is a non-standard approach to quantizing a classical system inspired by background independent approaches to quantum gravity such as loop quantum gravity. When applied to field theory it introduces a characteristic polymer scale at the level of the fields classical configuration space. Compared with models with space-time discreteness or non-commutativity this is an alternative way in which a characteristic scale can be introduced in a field theoretic context. Motivated by this comparison we study here localization and diffusion properties associated with polymer field observables and dispersion relation in order to shed some light on the novel physical features introduced by polymer quantization. While localization processes seems to be only mildly affected by polymer effects, we find that polymer diffusion differs significantly from the "dimensional reduction" picture emerging in other Planck-scale models beyond local quantum field theory.

Michele Arzano; Marco Letizia

2014-08-13T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Role of Polymer Segment?Particle Surface Interactions in Controlling Nanoparticle Dispersions in Concentrated Polymer Solutions  

SciTech Connect (OSTI)

The microstructure of particles suspended in concentrated polymer solutions is examined with small-angle X-ray scattering and small-angle neutron scattering. Of interest are changes to long wavelength particle density fluctuations in ternary mixtures of silica nanoparticles suspended in concentrated solutions of poly(ethylene glycol). The results are understood in terms of application of the pseudo-two-component polymer reference interaction site model (PRISM) theory modified to account for solvent addition via effective contact strength of interfacial attraction, {var_epsilon}{sub pc}, in an implicit manner. The combined experimental-theoretical study emphasizes the complex interactions between solvent, polymer, and particle surface that control particle miscibility but also demonstrate that these factors can all be understood in terms of variations of {var_epsilon}{sub pc}.

Kim, So Youn; Zukoski, Charles F. (UIUC)

2014-09-24T23:59:59.000Z

422

Selectively patterning polymer opal films via microimprint lithography  

E-Print Network [OSTI]

functional patterning of such POFs. 2.1. Microimprinting of Polymer Opal Films The stamps used for imprinting are made by replicating a PDMS mold with epoxy resin. The initial stamp used comprises of a hexagonal array of 30 ?m high posts with diameter... the polymer opal surface to allow the microimprinting process. Microimprinting of Polymer Opal Films: The stamps used for microimprinting were made by replicating PDMS molds with epoxy resin (Sigma-Aldrich Epoxy Embedding Medium Kit). The stamps...

Ding, Tao; Zhao, Qibin; Smoukov, Stoyan; Baumberg, Jeremy J.

2014-09-01T23:59:59.000Z

423

Conducting polymers as potential active materials in electrochemical supercapacitors  

SciTech Connect (OSTI)

Electronically,conducting polymers represent an interesting class of materials for use in electrochemical capacitors because of the combination of high capacitive energy density and low materials cost. Three generalized types of electrochemical capacitors can be constructed using conducting polymers as active material, and in the third of these, which utilizes conducting polymers that can be both n- and p-doped, energy densities of up to 40 watt-hours per kilogram of active material on both electrodes have been demonstrated.

Rudge, A.; Davey, J.; Raistrick, I.; Gottesfeld, S. [Los Alamos National Lab., NM (United States); Ferraris, J.P. [Texas Univ., Richardson, TX (United States). Dept. of Chemistry

1992-12-01T23:59:59.000Z

424

Conducting polymers as potential active materials in electrochemical supercapacitors  

SciTech Connect (OSTI)

Electronically,conducting polymers represent an interesting class of materials for use in electrochemical capacitors because of the combination of high capacitive energy density and low materials cost. Three generalized types of electrochemical capacitors can be constructed using conducting polymers as active material, and in the third of these, which utilizes conducting polymers that can be both n- and p-doped, energy densities of up to 40 watt-hours per kilogram of active material on both electrodes have been demonstrated.

Rudge, A.; Davey, J.; Raistrick, I.; Gottesfeld, S. (Los Alamos National Lab., NM (United States)); Ferraris, J.P. (Texas Univ., Richardson, TX (United States). Dept. of Chemistry)

1992-01-01T23:59:59.000Z

425

Polymers containing borane or carborane cage compounds and related applications  

DOE Patents [OSTI]

Polymers comprising residues of cage compound monomers having at least one polyalkoxy silyl substituent are provided. The cage compound monomers are selected from borane cage compound monomers comprising at least 7 cage atoms and/or carborane cage compound monomers comprising 7 to 11 cage compound monomers. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Articles of manufacture comprising such polymers are also disclosed.

Bowen, III, Daniel E; Eastwood, Eric A

2013-04-23T23:59:59.000Z

426

Design, synthesis, characterization and study of novel conjugated polymers  

SciTech Connect (OSTI)

After introducing the subject of conjugated polymers, the thesis has three sections each containing a literature survey, results and discussion, conclusions, and experimental methods on the following: synthesis, characterization of electroluminescent polymers containing conjugated aryl, olefinic, thiophene and acetylenic units and their studies for use in light-emitting diodes; synthesis, characterization and study of conjugated polymers containing silole unit in the main chain; and synthesis, characterization and study of silicon-bridged and butadiene-linked polythiophenes.

Chen, W.

1997-06-24T23:59:59.000Z

427

Surfactant-Polymer Interaction for Improved Oil Recovery  

SciTech Connect (OSTI)

The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

Gabitto, Jorge; Mohanty, Kishore K.

2002-01-07T23:59:59.000Z

428

Experimental and theoretical study of polymer flow in porous media  

SciTech Connect (OSTI)

In this paper, an extensive study is presented on the single-phase flow of xanthum/tracer slugs in a consolidated sandstone. The phenomena studied include polymer/tracer dispersion, excluded/inaccessible-volume effects, polymer adsorption, and viscous fingering. In some floods, there is also evidence of nonequilibrium effects. Macroscopic flow equations are derived that include terms to model all the behaviors listed above. A microscopic approach is also developed that describes certain features of polymer flow in porous media semiquantitatively.

Sorbie, K.S.; Parker, A.; Clifford, P.J.

1987-08-01T23:59:59.000Z

429

Unraveling the Role of Morphology on Organic Solar Cell Performance  

E-Print Network [OSTI]

Polymer based organic photovoltaic (OPV) technology offers a relatively inexpensive option for solar energy conversion provided its efficiency increases beyond the current level (6-7%) along with significant improvements in operational lifetime. The critical aspect of such solar cells is the complex morphology of distributed bulk heterojunctions, which plays the central role in the conversion of photo-generated excitons to electron-hole pairs. However, the fabrication conditions that can produce the optimal morphology are still unknown due to the lack of quantitative understanding of the effects of process variables on the cell morphology. In this article, we develop a unique process-device co-simulation framework based on phase-field model for phase separation coupled with self-consistent drift-diffusion transport to quantitatively explore the effects of the process conditions (e.g., annealing temperature, mixing ratio, anneal duration) on the organic solar cell performance. Our results explain experimentally observed trends of open circuit voltage and short circuit current that would otherwise be deemed anomalous from the perspective of conventional solar cells. In addition to providing an optimization framework for OPV technology, our morphology-aware modeling approach is ideally suited for a wide class of problems involving porous materials, block co-polymers, polymer colloids, OLED devices etc.

Biswajit Ray; Pradeep R. Nair; Muhammad A. Alam

2010-11-03T23:59:59.000Z

430

Continuous process to produce lithium-polymer batteries  

DOE Patents [OSTI]

Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be over coated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance. 1 fig.

Chern, T.S.H.; Keller, D.G.; MacFadden, K.O.

1998-05-12T23:59:59.000Z

431

E-Print Network 3.0 - autohumidification polymer electrolyte...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Park Collection: Engineering ; Materials Science 18 Switchable window based on electrochromic polymers Chunye Xu,a) Summary: electrolyte, and a counterelectrode that replaces...

432

Charge transport in hybrid nanorod-polymer composite photovoltaic cells  

E-Print Network [OSTI]

circuit diagram for a photovoltaic cell under illumination.Polymer Composite Photovoltaic Cells Wendy U. Huynh ‡ ,devices such as photovoltaic cells and light-emitting-

Huynh, Wendy U.; Dittmer, Janke J.; Teclemariam, Nerayo; Milliron, Delia; Alivisatos, A. Paul; Barnham, Keith W.J.

2002-01-01T23:59:59.000Z

433

High Temperature Polymer Membrane Development at Argonne National...  

Broader source: Energy.gov (indexed) [DOE]

Polymer Membrane Development at Argonne National Laboratory Seong-Woo Choi, Suhas Niyogi, John Kopasz, Romesh Kumar, and Debbie Myers Chemical Engineering Division Argonne National...

434

Polymer-Ceramic MEMS Bimorphs as Thermal Infrared Sensors  

E-Print Network [OSTI]

of thermal expansion between polymers and ceramics. However,of thermal expansion for selected ceramics, metals, andof thermal expansion for selected ceramics, metals, and

Warren, Clinton Gregory

2010-01-01T23:59:59.000Z

435

Crosslinked crystalline polymer and methods for cooling and heating  

DOE Patents [OSTI]

The invention relates to crystalline polyethylene pieces having optimum crosslinking for use in storage and recovery of heat, and it further relates to methods for storage and recovery of heat using crystalline polymer pieces having optimum crosslinking for these uses. Crystalline polymer pieces are described which retain at least 70% of the heat of fusion of the uncrosslinked crystalline polymer and yet are sufficiently crosslinked for the pieces not to stick together upon being cycled above and below the melting point of said polymer, preferably at least 80% of the heat of fusion with no substantial sticking together.

Salyer, Ival O. (Dayton, OH); Botham, Ruth A. (Dayton, OH); Ball, III, George L. (West Carrollton, OH)

1980-01-01T23:59:59.000Z

436

acrylic acid polymers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acrylate Polymers on the Release Profile of Ambroxol Hydrochloride Controlled Release Pellets CiteSeer Summary: ABSTRACT: The effects of Ammonio Methacrylate copolymer dispersion...

437

acrylic polymers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acrylate Polymers on the Release Profile of Ambroxol Hydrochloride Controlled Release Pellets CiteSeer Summary: ABSTRACT: The effects of Ammonio Methacrylate copolymer dispersion...

438

Engineering Property Prediction Tools for Tailored Polymer Composite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting lm068nguyen2012o.pdf More Documents & Publications Engineering Property Prediction Tools for Tailored Polymer Composite Structures Property...

439

Hydrogen Production by Polymer Electrolyte Membrane (PEM)Electrolysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

on Giner and Proton Presentation slides and speaker biographies from the DOE Fuel Cell Technologies Office webinar "Hydrogen Production by Polymer Electrolyte Membrane...

440

A tour-de-force in polymer crosslinked aerogels .  

E-Print Network [OSTI]

??"In the quest of building mechanically strong materials with low density and high porosity, polymer crosslinked aerogels stand as the most promising nano-engineered examples. Covalent… (more)

Mulik, Sudhir, 1979-

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Controlled Self Assembly of Conjugated Polymer Containing Block Copolymers  

E-Print Network [OSTI]

for photovoltaics however it appears efficiencies tend to belimiting efficiencies. Typically polymer photovoltaics areefficiency Plot of current density versus voltage for photovoltaics

McCulloch, Bryan

2012-01-01T23:59:59.000Z

442

Understanding Molecular Interactions within Chemically Selective Layered Polymer Assemblies  

SciTech Connect (OSTI)

This work focuses on two broad issues. These are (1) the molecular origin of the chemical selectivity achieved with ultrathin polymer multilayers, and (2) how the viscoelastic properties of the polymer layers are affected by exposure to solvent and analytes. These issues are inter-related, and to understand them we need to design experiments that probe both the energetic and kinetic aspects of interfacial adsorption processes. This project focuses on controling the chemical structure, thickness, morphology and sequential ordering of polymer layers bound to interfaces using maleimide-vinyl ether and closely related alternating copolymerization chemistry and efficient covalent cross-linking reactions that allow for layer-by-layer polymer deposition. This chemistry has been developed during the funding cycle of this Grant. We have measure the equilibrium constants for interactions between specific layers within the polymer interfaces and size-controlled, surface-functionalized gold nanoparticles. The ability to control both size and functionality of gold nanoparticle model analytes allows us to evaluate the average “pore size” that characterizes our polymer films. We have measured the “bulk” viscosity and shear modulus of the ultrathin polymer films as a function of solvent overlayer identity using quartz crystal microbalance complex impedance measurements. We have measured microscopic viscosity at specific locations within the layered polymer interfaces with time-resolved fluorescence lifetime and depolarization techniques. We combine polymer, cross-linking and nanoparticle synthetic expertise with a host of characterization techniques, including QCM gravimetry and complex impedance analysis, steady state and time-resolved spectroscopies.

Gary J. Blanchard

2009-06-30T23:59:59.000Z

443

assembled polymer nanowires: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

functionalized nanoparticles are still challenges for (more) Bai, Litao 2009-01-01 76 Synthesis and Self-assembly of 60Fullerene Containing Sulfobetaine Polymer in Aqueous...

444

Fluorescent Multiblock ?-Conjugated Polymer Nanoparticles for In Vivo Tumor Targeting  

E-Print Network [OSTI]

Highly fluorescent multiblock conjugated polymer nanoparticles with folic acid surface ligands are highly effective for bioimaging and in vivo tumor targeting. The targeted nanoparticles were preferentially localized in ...

Ahmed, Eilaf

445

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

thin films of semiconducting polymers as a possible alternative to silicon-based solar cells. Such devices would have the advantages of being cheap to produce,...

446

PH/sub 3/ treatment for polymer stabilization  

DOE Patents [OSTI]

Polymers are stabilized against oxidative degradation by treatment with phosphine gas. The treatment can be used in situ on polymeric components already in use.

Not Available

1982-07-20T23:59:59.000Z

447

Fabrication and performance of polymer-nanocomposite anti-reflective...  

Office of Scientific and Technical Information (OSTI)

AR stack using hybrid polymer: nanoparticle materials deposited by resonant infrared matrix-assisted pulsed laser evaporation. An Er: YAG laser ablated frozen solutions...

448

Continuous process to produce lithium-polymer batteries  

DOE Patents [OSTI]

Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte-electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be overcoated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance.

Chern, Terry Song-Hsing (Midlothian, VA); Keller, David Gerard (Baltimore, MD); MacFadden, Kenneth Orville (Highland, MD)

1998-01-01T23:59:59.000Z

449

Property Prediction Tools for Tailored Polymer Composite Structures...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08smith2.pdf More Documents & Publications Property Prediction Tools for Tailored Polymer...

450

High Temperature Polymer Membrane Development at Argonne National Laboratory  

Broader source: Energy.gov [DOE]

Summary of ANL’s high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

451

Fire Retardant Polymer Nanocomposites: Materials Design and Thermal Degradation Modeling.  

E-Print Network [OSTI]

??Compared to conventional materials, polymer matrix composites (PMCs) have a number of attractive properties, including light weight, easiness of installation, potential to lower system-level cost,… (more)

Zhuge, Jinfeng

2012-01-01T23:59:59.000Z

452

Nanopatterns by phase separation of patterned mixed polymer monolayers  

DOE Patents [OSTI]

Micron-size and sub-micron-size patterns on a substrate can direct the self-assembly of surface-bonded mixed polymer brushes to create nanoscale patterns in the phase-separated mixed polymer brush. The larger scale features, or patterns, can be defined by a variety of lithographic techniques, as well as other physical and chemical processes including but not limited to etching, grinding, and polishing. The polymer brushes preferably comprise vinyl polymers, such as polystyrene and poly(methyl methacrylate).

Huber, Dale L; Frischknecht, Amalie

2014-02-18T23:59:59.000Z

453

Modeling Cold Start in a Polymer-Electrolyte Fuel Cell  

E-Print Network [OSTI]

conditions used for fuel—cell simulations. 3.12 Values usedin Polymer Electrolyte Fuel Cells — II. Parametric Study,”Fuel Cells . . . . . . . . . . . . . . . . . . . . . . 1.1.1

Balliet, Ryan

2010-01-01T23:59:59.000Z

454

Interfacial Slip in Entrained Soap Films Containing Associating Hydrosoluble Polymer  

E-Print Network [OSTI]

, polymers, and even glass beads are often added to help stabilize films against premature rupture to produce high-quality foams and emulsions. Polymeric additivescanundergoassociationwithsurfactantmicelles

Troian, Sandra M.

455

3,6-Dithiophen-2-yl-diketopyrrolo[3,2b]pyrrole (isoDPPT) as an Acceptor Building Block for Organic Opto-Electronics  

E-Print Network [OSTI]

(OTFTs),3 organic photovoltaics (OPVs)4 and organic light emitting diodes (OLEDs) and transistors (OLETs moved to more elaborated structures comprising heterofused systems enabling impressive performance.8 these reports, numerous DPPT-based polymers have been synthe- sized and utilized in both OTFT and OPV

456

Mixed crystal organic scintillators  

DOE Patents [OSTI]

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

457

Lithium Polymer (LiPo) Battery Usage Lithium polymer batteries are now being widely used in hobby and UAV applications. They work  

E-Print Network [OSTI]

Lithium Polymer (LiPo) Battery Usage 1 Lithium polymer batteries are now being widely used in hobby only LiPo Chargers with Error Detection - It is always recommended that you charge your lithium polymer batteries with a battery charger specifically designed for lithium polymer batteries. As an example, you

Langendoen, Koen

458

Optimization of Polymer-based Nanocomposites for High Energy Density Applications  

E-Print Network [OSTI]

polymers are of interest owing to their high inherent electrical resistance, low dielectric loss, flexibility, light weight, and low cost; however, capacitors produced with dielectric polymers are limited to an energy density of ~1-2 J/cc. Polymer...

Barhoumi Ep Meddeb, Amira

2012-07-16T23:59:59.000Z

459

Free Energy Fluctuations for Directed Polymers in Random Media in 1?+?1 Dimension  

E-Print Network [OSTI]

We consider two models for directed polymers in space-time independent random media (the O'Connell-Yor semidiscrete directed polymer and the continuum directed random polymer) at positive temperature and prove their KPZ ...

Borodin, Alexei

460

Keith Johnston Research Group Nanomaterials chem./Colloid Science/Interfaces/Polymers  

E-Print Network [OSTI]

nanoparticles mediated by weakly adsorbing polymer PLA-b-PEG-b-PLA Gold nanoparticle bound together by polymer Sub-5 nm gold particles Clustering of gold nanoparticles mediated by weakly adsorbing polymer PLA-b-PEG-b-PLA

Lightsey, Glenn

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - a-1 polymer chemistry Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

polymer chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: a-1 polymer chemistry Page: << < 1 2 3 4 5 > >> 1 Water-Soluble Polymers from...

462

TESTING A CONCEPTUAL FRAMEWORK FOR SELF- CARE IN PERSONS WITH DIABETES: THE EFFECT OF DEPRESSION  

E-Print Network [OSTI]

Diabetes is a major source of morbidity, mortality, and economic expense. Not only do people with diabetes have a higher risk of developing depression, the rate of depression is much higher than in the general population ...

Gharaibeh, Besher

2012-05-31T23:59:59.000Z

463

E-Print Network 3.0 - ao diabetes melito Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

estimate as a predictor of motor dysfunction in an animal model of type 1 diabetes. Am J Physiol... .2009.--Peripheral neurop- athy is a common complication of diabetes that...

464

Cardiac dysfunction in the diabetic rat: quantitative evaluation using high resolution magnetic resonance imaging  

E-Print Network [OSTI]

Background: Diabetes is a major risk factor for cardiovascular disease. In particular, type 1 diabetes compromises the cardiac function of individuals at a relatively early age due to the protracted course of abnormal ...

Loganathan, Rajprasad; Bilgen, Mehmet; Al-Hafez, Baraa; Alenezy, Mohammed D.; Smirnova, Irina V.

2006-04-04T23:59:59.000Z

465

Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian Population  

E-Print Network [OSTI]

Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian) Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian Population. PLo

Reich, David

466

HEAT SHOCK PROTEINS: NOVEL THERAPEUTIC TARGETS AGAINST INSULIN RESISTANCE AND TYPE 2 DIABETES  

E-Print Network [OSTI]

Impaired insulin action, termed insulin resistance, is characteristic of type 2 diabetes, obesity and aging. Given the rising epidemic of diabetes, efforts to understand the mechanisms of insulin resistance and discover ...

Gupte, Anisha A.

2009-03-16T23:59:59.000Z

467

PhD Studentship Department of Medicine, Division of Diabetes, Endocrinology and Metabolism  

E-Print Network [OSTI]

PhD Studentship Department of Medicine, Division of Diabetes, Endocrinology and Metabolism Payment to cure obesity and Type II diabetes. Full training will be given in all applicable techniques

468

FDA Approves Drug for Type 2 Diabetes Invented with Aid of Protein...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FDA Approves Drug for Type 2 Diabetes Invented with Aid of Protein Structure Data Taken at ALS FDA Approves Drug for Type 2 Diabetes Invented with Aid of Protein Structure Data...

469

Risk factors for cognitive decline in older people with type 2 diabetes   

E-Print Network [OSTI]

People with type 2 diabetes are at increased risk of age-related cognitive impairment. Previous literature has focused on case-control studies comparing rates of cognitive impairment in patients with and without diabetes. ...

Feinkohl, Insa

2014-07-05T23:59:59.000Z

470

Performance of steel-polymer and ceramic-polymer layered composites and concrete under high strain rate loadings  

E-Print Network [OSTI]

Performance of Steel-Polyurea Bi-layers Subjected to Impul-Performance of Steel-Polymer-Steel Sandwich Structures Sub- jected to Impulsive

Samiee, Ahsan

2010-01-01T23:59:59.000Z

471

Organic photovoltaics and concentrators  

E-Print Network [OSTI]

The separation of light harvesting and charge generation offers several advantages in the design of organic photovoltaics and organic solar concentrators for the ultimate end goal of achieving a lower cost solar electric ...

Mapel, Jonathan King

2008-01-01T23:59:59.000Z

472

e-Polymers 2009, no. 134 http://www.e-polymers.org  

E-Print Network [OSTI]

so produced are both flexible and porous; we now report their swelling efficacies as a function have been used to absorb oil spilled on water [1, 2]. Polypropylene (PP), polyethylene (PE in remediation of oil spills [3]. Among such materials, alkyl acrylate and aromatic polymers with hydrophobicity

North Texas, University of

473

Diabetologia . Author manuscript Menopausal hormone therapy and new-onset diabetes in the French Etude  

E-Print Network [OSTI]

@igr.fr > Abstract Aims/hypothesis Two US randomized trials found a lower incidence of type 2 diabetes among women Controlled Trials as Topic Author Keywords adult diabetes ; postmenopause ; menopausal hormone therapy-report or drug reimbursement record linkage, and further validated. Results 1220 new-onset diabetes cases were

Boyer, Edmond

474

1946 DIABETES, VOL. 49, NOVEMBER 2000 Genetic Obesity Unmasks Nonlinear Interactions  

E-Print Network [OSTI]

1946 DIABETES, VOL. 49, NOVEMBER 2000 Genetic Obesity Unmasks Nonlinear Interactions Between Murine Type 2 Diabetes Susceptibility Loci Jonathan P. Stoehr, Samuel T. Nadler, Kathryn L. Schueler, Mary E and genetic risk factors are thought to determine susceptibility to type 2 diabetes. We used genetic obesity

Yandell, Brian S.

475

The Factors of Chronic Kidney Disease: Diabetes, Hypertension, Smoking, Drinking, Betelnut Chewing  

E-Print Network [OSTI]

The Factors of Chronic Kidney Disease: Diabetes, Hypertension, Smoking, Drinking, Betelnut Chewing CKD 75 CKD Abstract The risk factors of Chronic Kidney Disease (CKD), including diabetes risk factors in a population-based cohort. Compared with single risk factors, diabetes (odds ratio 1

Chen, Chaur-Chin

476

CXCL5 drives obesity to diabetes, and Carine Chavey, and Lluis Fajas  

E-Print Network [OSTI]

CXCL5 drives obesity to diabetes, and further. Carine Chavey, and Lluis Fajas¶ IRCM, Institut de Key words: chemokine, adipose tissue, obesity, diabetes ¶ To whom correspondence should be addressed, and diabetes-derived pathologies, such as cardiovascular disease, retinopathy, or inflammatory bowel disease

Paris-Sud XI, Université de

477

Multi-component single-substrate conducting polymer actuation systems and fabrication techniques  

E-Print Network [OSTI]

Conducting polymer materials can be employed as actuation elements, length sensors, force sensors, energy storage devices, and electrical components. Combining the various functionalities of conducting polymers to create ...

Paster, Eli Travis

478

E-Print Network 3.0 - added polymer chains Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2) polymer chains molecularly dispersed into ceramic matrix. Recently, strength... in the fracture strength of the alumina that is also dependent on the amount of polymer added....

479

E-Print Network 3.0 - active polymer gel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

polymers whose properties are changed drastically... , copoly(AamvdMG) gel and electrochromic polymer, ProDOT-(CH3) ... Source: Taya, Minoru - Department of Mechanical...

480

Dr. Piotr Zelenay's Professional Bio Dr. Zelenay's expertise is in polymer electrolyte fuel cells, electrocatalysis, surface  

E-Print Network [OSTI]

Dr. Piotr Zelenay's Professional Bio Dr. Zelenay's expertise is in polymer electrolyte fuel cells of polymer electrolyte fuel cell science and technology, electrocatalysis, and electrode kinetics. Piotr

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

E-Print Network 3.0 - amorphous polymer field-effect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 60 Patterning-free integration of polymer light-emitting diode and polymer transistor Summary: contains a light-emitting diode LED driven by a...

482

E-Print Network 3.0 - amorphous polymer solution Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interfacial effects to polymer film... . This requirement proves challenging for low thermal conductivity materials like amorphous polymers. The effective... in thicker...

483

Changes in vigorous physical activity and incident diabetes inmale runners  

SciTech Connect (OSTI)

We examined the dose-response relationship between changes in reported vigorous exercise (running distance, {Delta}km/wk) and self-reported physician diagnosed diabetes in 25,988 men followed prospectively for (mean {+-} SD) 7.8 {+-} 1.8 years. Logistic regression analyses showed that the log odds for diabetes declined significantly in relation to men's {Delta}km/wk (coefficient {+-} SE: -0.012 {+-} 0.004, P < 0.01), which remained significant when adjusted for BMI (-0.018 {+-} 0.003, P < 0.0001). The decline in the log odds for diabetes was related to the distance run at the end of follow-up when adjusted for baseline distance, with (-0.024 {+-} 0.005, P < 0.0001) or without (-0.027 {+-} 0.005, P < 0.0001) adjustment for BMI. Baseline distance was unrelated to diabetes incidence when adjusted for the distance at the end of follow-up. Compared to men who ran <8 km/wk at the end of follow-up, incidence rates in those who ran {ge} 8 km/wk were 95% lower between 35-44 yrs old (P < 0.0001), 92% lower between 45-54 yrs old (P < 0.0001), 87% lower between 55 and 64 years old (P < 0.0001), and 46% lower between 65-75 yrs old (P = 0.30). For the subset of 6,208 men who maintained the same running distance during follow-up ({+-}5 km/wk), the log odds for diabetes declined with weekly distance run (-0.024 {+-} 0.010, P = 0.02) but not when adjusted for BMI (-0.005 {+-} 0.010, P = 0.65). Conclusion: Vigorous exercise significantly reduces diabetes incidence, due in part to the prevention of age-related weight gain and in part to other exercise effects. Physical activity decreases the risk of type 2 diabetes [1-10]. Moderate and vigorous exercise are purported to produce comparable reductions in diabetes risk if the energy expenditure is the same [3,10]. The optimal physical activity dose remains unclear, however, with some [4-7] but not all studies [1,8,9] showing continued reduction in diabetes for high versus intermediate energy expenditures. The National Runners Health Study [11-19] is unique among population cohorts in its focus on the health impact of higher doses of vigorously intense physical activity (i.e., {ge} 6-fold metabolic rate). The study was specifically designed to evaluate the dose-response relationship between vigorous physical activity and health for intensities and durations that exceed current physical activity recommendations [20-22]. One specific hypothesis is whether changes in vigorous physical activity affect the risk for becoming diabetic. Although women were surveyed and followed-up, only 23 developed diabetes so there is limited statistical power to establish their significance. Our analyses of diabetes and vigorous exercise are therefore restricted to men. This paper relates running distance at baseline and at the end of follow-up to self-reported, physician diagnosed diabetes in vigorously active men who were generally lean and ostensibly at low diabetic risk The benefits of greater doses of more vigorous exercise are relevant to the 27% of U.S. women and 34% of U.S. men meet or exceed the more general exercise recommendations for health benefits [23]. Specific issues to be addressed are: (1) whether maintenance of the same level of vigorous exercise over time reduces the risk of incident diabetes in relation to the exercise dose; (2) whether men who decrease their activity increase their risk for becoming diabetic; and (3) whether end of follow-up running distances are more predictive of diabetes than baseline distances, suggesting a causal, acute effect. Elsewhere we have shown that greater body weight is related to a lack of vigorous exercise [12-14] and increases the risk for diabetes even among generally lean vigorously active men [11]. In runners, leanness may be due to the exercise or due to initially lean men choosing to run further [17]. Therefore we also test whether body weight mediates the effects of vigorous exercise on diabetes, and whether this may be due to self-selection.

Williams, Paul T.

2007-04-30T23:59:59.000Z

484

Organic photosensitive devices  

DOE Patents [OSTI]

The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

Rand, Barry P; Forrest, Stephen R

2013-11-26T23:59:59.000Z

485

Solid-particle erosion of bismaleimide polymers  

SciTech Connect (OSTI)

Solid-particle erosion of bismaleimide (BMI) polymers of various compositions was studied and compared with measured mechanical properties. For angular aluminum oxide erodents of mean diameter 42, 63, 143 or 390 {mu}m impacting normal to the surface at 60 m s{sup {minus}1}, the erosion rate was found to be a strong function of the size of the impacting particle. Material removal occurred primarily by a process of brittle-fracture-induced damage. However, the results suggest that for the BMI specimens, degradation and plasticity occurred in addition to fracture, and that the occurrence of these phenomena reduced the erosion rates.

Brandstaedter, A.; Goretta, K.C.; Routbort, J.L. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States); Groppi, D.P.; Karasek, K.R. [Allied-Signal Inc., Des Plaines, IL (United States)] [Allied-Signal Inc., Des Plaines, IL (United States)

1991-12-31T23:59:59.000Z

486

The interaction of various polymers with water  

E-Print Network [OSTI]

water content. The glass transition temperature was taken as the inflection point in the heat capacity curve (Figure 3). The uncertainty in the glass points was rather high (x20'C) mainly because of the small change in heat capacities -1 (6C = . 03... water/g methylcellulose) 17 Y=. 10 Y=. 15 10 50 70 90 110 T ( c) Fig. 3. C (arbitrary units) versus temperature at two water p contents, Y, for methylcellulose. Inflection in curve is the glass transition region of the polymer-water system...

Quock, Billy

1976-01-01T23:59:59.000Z

487

Spatially controlled, in situ synthesis of polymers  

DOE Patents [OSTI]

An in situ polymer microstructure formation method. The monomer mixture is polymerized in a solvent/precipitant through exposure to ionizing radiation in the absence any chemical mediators. If an exposure mask is employed to block out certain regions of the radiation cross section, then a patterned microstructure is formed. The polymerization mechanism is based on the so-called free-radical retrograde-precipitation polymerization process, in which polymerization occurs while the system is phase separating above the lower critical solution temperature. This method was extended to produce a crosslinked line grid-pattern of poly (N-isopropylacrylamide), which has been known to have thermoreversible properties.

Caneba, Gerard T.; Tirumala, Vijaya Raghavan; Mancini, Derrick C.; Wang, Hsien-Hau

2005-03-22T23:59:59.000Z

488

Dynamics in Polymer | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutron scattering characterizes dynamics in polymer family Agatha Bardoel

489

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1984-01-01T23:59:59.000Z

490

Constitutive modeling of nanotubereinforced polymer composites G.M. Odegarda,  

E-Print Network [OSTI]

as compared to stan- dard structural materials. In particular, carbon nanotube/ polymer composites may provide of polymeric composite materials reinforced with typical reinforcement such as carbon or glass fibers constitutive models for polymer composite systems reinforced with single- walled carbon nanotubes (SWNT

Odegard, Gregory M.

491

Microporous Patterned Electrodes for Color-Matched Electrochromic Polymer Displays  

E-Print Network [OSTI]

Microporous Patterned Electrodes for Color-Matched Electrochromic Polymer Displays Pierre of electroactive and conducting polymers offers new opportunities for the design of materials for electrochromic the most promising electrochromic (EC) properties. Here, we report the use of highly porous metallized

Tanner, David B.

492

Universal features of polymer shapes in crowded environment  

E-Print Network [OSTI]

We study the universal characteristics of the shape of a polymer chain in an environment with correlated structural obstacles, applying the field-theoretical renormalization group approach. Our results qualitatively indicate an increase of the asymmetry of the polymer shape in crowded environment comparing with the pure solution case.

Viktoria Blavatska; Christian von Ferber; Yurij Holovatch

2010-03-09T23:59:59.000Z

493

Anomalous Phase Inversion in Polymer Blends Prepared by Cryogenic Mechanical  

E-Print Network [OSTI]

, as well as interpenetrating and bicontinu- ous networks.7,8 Phase inversion occurs when the mi- norityAnomalous Phase Inversion in Polymer Blends Prepared by Cryogenic Mechanical Alloying Archie P strategies for producing highly dis- persed multicomponent polymer blends. By their very nature

494

Biomimetic interfacial interpenetrating polymer networks control neural stem cell behavior  

E-Print Network [OSTI]

Biomimetic interfacial interpenetrating polymer networks control neural stem cell behavior Krishanu polymer network (IPN), we define a robust synthetic and highly-defined plat- form for the culture of adult precisely orchestrate signal presentation to stem cells. Using a biomimetic interfacial interpenetrating

Saha, Krishanu

495

Method for synthesizing peptides with saccharide linked enzyme polymer conjugates  

DOE Patents [OSTI]

A method is disclosed for synthesizing peptides using water soluble enzyme polymer conjugates. The method comprises catalyzing the peptide synthesis with enzyme which has been covalently bonded to a polymer through at least three linkers which linkers have three or more hydroxyl groups. The enzyme is conjugated at lysines or arginines. 19 figs.

Callstrom, M.R.; Bednarski, M.D.; Gruber, P.R.

1997-06-17T23:59:59.000Z

496

Enzyme linked immunoassay with stabilized polymer saccharide enzyme conjugates  

DOE Patents [OSTI]

An improvement in enzyme linked immunoassays is disclosed wherein the enzyme is in the form of a water soluble polymer saccharide conjugate which is stable in hostile environments. The conjugate comprises the enzyme which is linked to the polymer at multiple points through saccharide linker groups. 19 figs.

Callstrom, M.R.; Bednarski, M.D.; Gruber, P.R.

1997-11-25T23:59:59.000Z

497

The Future of Material Science & Engineering A Polymer Industry Perspective  

E-Print Network [OSTI]

&D Solvay Specialty Polymers #12;The Industry Forecasting Challenge... This "telephone" has too many William Leahy, US Atomic Bomb Project Deep Insight can Impair Foresight... #12;© 2013 Solvay Specialty Into the Future © 2013 Solvay Specialty Polymers5 Equally Dangerous Approaches... #12;© 2012 Solvay Specialty

Li, Mo

498

ADVANCED NANOIMPRINT TECHNIQUE FOR MULTILAYER STRUCTURES AND FUNCTIONAL POLYMER APPLICATIONS  

E-Print Network [OSTI]

................................................................................ 72 5.2.1 Solvent developing and reversal nanoimprint for PMMA nanowire ........................................................... 73 5.2.2 Lift-off for functional polymer nanowire ....................... 75 5.3 Summary...-demolding in nanoimprint. ...................................... 31 16 (a) Schematic of fabricating multilayer polymer structures by bonding with a thin adhesive layer; (b) Three-layer PMMA microstructure bonded by a thin SU-8 adhesive layer...

Park, Hyunsoo

2010-07-14T23:59:59.000Z

499

Materials comprising polydienes and hydrophilic polymers and related methods  

DOE Patents [OSTI]

Materials prepared from polydienes, such as poly(cyclohexadiene), and hydrophilic polymers, such as poly(alkylene oxide), are described. Methods of making the materials and their use in fuel cell membranes, batteries, breathable chemical-biological protective materials, and templates for sol-gel polymerization are also provided. The materials can be crosslinked and sulfonated, and can include copolymers and polymer blends.

Mays, Jimmy W. (Knoxville, TN); Deng, Suxiang (Knoxville, TN); Mauritz, Kenneth A. (Hattiesburg, MS); Hassan, Mohammad K. (Hattiesburg, MS); Gido, Samuel P. (Hadley, MA)

2011-11-22T23:59:59.000Z

500

Thermal And Thermo-Mechanical Modelling of Polymer Overmoulded Electronics  

E-Print Network [OSTI]

electronics for use in the demanding automotive environment. A two shot moulding technology will protect of electronics within polymer materials is of great interest to the automotive industry as a means to protectThermal And Thermo-Mechanical Modelling of Polymer Overmoulded Electronics F. Sarvar1 , D. C

Paris-Sud XI, Université de