Powered by Deep Web Technologies
Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Low band gap polymers Organic Photovoltaics  

E-Print Network [OSTI]

Low band gap polymers for Organic Photovoltaics Eva Bundgaard Ph.D. Dissertation Risø National Bundgaard Title: Low band gap polymers for Organic photovoltaics Department: The polymer department Report the area of organic photovoltaics are focusing on low band gap polymers, a type of polymer which absorbs

2

Decohesion Kinetics in Polymer Organic Solar Cells  

Science Journals Connector (OSTI)

Decohesion Kinetics in Polymer Organic Solar Cells ... We investigate the role of molecular weight (MW) of the photoactive polymer poly(3-hexylthiophene) (P3HT) on the temperature-dependent decohesion kinetics of bulk heterojunction (BHJ) organic solar cells (OSCs). ... fullerenes; solar cells; thin films; fracture; polymer ...

Christopher Bruner; Fernando Novoa; Stephanie Dupont; Reinhold Dauskardt

2014-11-04T23:59:59.000Z

3

Megahertz organic/polymer diodes  

DOE Patents [OSTI]

Featured is an organic/polymer diode having a first layer composed essentially of one of an organic semiconductor material or a polymeric semiconductor material and a second layer formed on the first layer and being electrically coupled to the first layer such that current flows through the layers in one direction when a voltage is applied in one direction. The second layer is essentially composed of a material whose characteristics and properties are such that when formed on the first layer, the diode is capable of high frequency rectifications on the order of megahertz rectifications such as for example rectifications at one of above 100KHz, 500KhZ, IMHz, or 10 MHz. In further embodiments, the layers are arranged so as to be exposed to atmosphere.

Katz, Howard Edan; Sun, Jia; Pal, Nath Bhola

2012-12-11T23:59:59.000Z

4

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

properties for organic photovoltaics (OPVs). Space-chargePolymers for Organic Photovoltaics By David Fredric JoelPolymers for Organic Photovoltaics by David Fredric Joel

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

5

Ammonia Capture in Porous Organic Polymers Densely Functionalized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brnsted Acid Groups Previous Next List Jeffrey F. Van Humbeck, Thomas M. McDonald, Xiaofei Jing, Brian M....

6

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

fundamental physics behind how conjugated organic molecules the optical and electronicFundamental investigations of how synthetic molecular manipulation alters the electronicfundamental operating mechanism of organic photovoltaic devices. New conjugated polymers were characterized and their optical and electronic

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

7

Metallic Nanoantennae and their Use in Organic-Polymer Photovoltaics  

Science Journals Connector (OSTI)

Organic photovoltaics, particularly bulk heterojunction devices, have shown...1, 2]. One of the main limitations of these designs is the low charge carrier mobility of the polymer blend. This leads to losses due ...

Eric Peterson; Patrick N. Sisco; Catherine J. Murphy…

2011-03-01T23:59:59.000Z

8

E-Print Network 3.0 - aligned organic polymer Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of fullerenes in polymers is of practical interest because of its role in organic solar cell... miscibility of the fullerene with one of the polymers leading to better...

9

The Organic Chemistry of Conducting Polymers  

SciTech Connect (OSTI)

For the last several years, we have examined the fundamental principles of conduction in one-dimensional systems, i.e., molecular “wires”. It is, of course, widely recognized that such systems, as components of electronically conductive materials, function in a two- and three-dimensional milieu. Thus interchain hopping and grain-boundary resistivity are limiting conductivity factors in highly conductive materials, and overall conductivity is a function of through-chain and boundary hopping. We have given considerable attention to the basic principles underlying charge transport (the “rules of the game”) in two-dimensional systems by using model systems which allow direct observation of such processes, including the examination of tunneling and hopping as components of charge transfer. In related work, we have spent considerable effort on the chemistry of conjugated heteropolymers, most especially polythiophens, with the aim of using these most efficient of readily available electroactive polymers in photovoltaic devices.

Tolbert, Laren Malcolm [Georgia Institute of Technology

2014-12-01T23:59:59.000Z

10

Organic Solar Cells as Polymer Waveguide Integrated Photodetectors  

Science Journals Connector (OSTI)

Abstract We report on the integration of an organic photodetector into a polymer waveguide. The photodetector is based on thin film organic solar cells using Zinc phtalocyanine and Fulleren C60 (ZnPc:C60) as photoactive material. This approach comprises the potential for an ease of production of active electro optical components on passive optical elements. By using organic materials low cost production of integrated devices on uneven surfaces becomes possible. In first experiments we show the potential of ZnPc:C60 solar cells as photodetectors at a wavelength of 635 nm. We perform simulations of this detectors put on the top surface of a polymer multi-mode waveguide. The simulation shows how light, which is guided through the waveguide can be efficiently absorbed by the photodetector without complex coupling structures.

Torsten Otto; Torsten Rabe; Sebastian Döring; Wolfgang Kowalsky

2014-01-01T23:59:59.000Z

11

Organic Polymers Show Sunny Potential | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A New Family of Quasicrystals A New Family of Quasicrystals Cool Muscles: Storing Elastic Energy for Flight A Further Understanding of Superconductivity New Family of Tiny Crystals Glow Bright in LED Lights How Serotonin Receptors Can Shape Drug Effects, from LSD to Migraine Medication Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Organic Polymers Show Sunny Potential JUNE 25, 2013 Bookmark and Share Researchers at Rice and Pennsylvania State universities have created solar cells based on block copolymers, self-assembling organic materials that arrange themselves into distinct layers. Image courtesy of the Gomez Laboratory A new version of solar cells created by laboratories at the Rice and

12

Oxidative chemical vapor deposition of semiconducting polymers and their use In organic photovoltaics  

E-Print Network [OSTI]

Organic photovoltaics (OPVs) have received significant interest for their potential low cost, high mechanical flexibility, and unique functionalities. OPVs employing semiconducting polymers in the photoactive layer have ...

Borrelli, David Christopher

2014-01-01T23:59:59.000Z

13

SIMULATION OF GEOMETRY AND SHADOW EFFECTS IN 3D ORGANIC POLYMER SOLAR CELLS  

E-Print Network [OSTI]

levels of Solar panels and new production capacity is driving solar PV prices lower and thereby, bringingSIMULATION OF GEOMETRY AND SHADOW EFFECTS IN 3D ORGANIC POLYMER SOLAR CELLS OF THE THESIS Simulation of Geometry and Shadow Effects in 3D Organic Polymer Solar Cells by Mihir Prakashbhai

Kassegne, Samuel Kinde

14

Chemical anchoring of organic conducting polymers to semiconducting surfaces  

DOE Patents [OSTI]

According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge-conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge-conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

Frank, Arthur J. (Lakewood, CO); Honda, Kenji (Wheatridge, CO)

1984-01-01T23:59:59.000Z

15

Chemical anchoring of organic conducting polymers to semiconducting surfaces  

DOE Patents [OSTI]

According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

Frank, A.J.; Honda, K.

1984-01-01T23:59:59.000Z

16

The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells  

E-Print Network [OSTI]

J. The physics of solar cells; Imperial College Press,for organic polymer solar cells investigated to date. TheHarvesting in Dye-Sensitized Solar Cells Through the Use of

Armstrong, Paul Barber

2010-01-01T23:59:59.000Z

17

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

mechanism by which organic solar cells operate, and then tomechanism of an organic solar cell. (1) Absorption ofthe improvement of organic solar cells. The photophysics of

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

18

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

conversion efficiencies in organic solar cells is reported.operation of an organic solar cell and the correspondingcarrier mobility for organic solar cells for minimizing

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

19

Thiophene Based Donor/Acceptor Conjugated Polymers for Organic Photovoltaics Brian Doyle, Rutgers University, SURF Fellow 2010  

E-Print Network [OSTI]

Thiophene Based Donor/Acceptor Conjugated Polymers for Organic Photovoltaics Brian structure. These organic photovoltaics have the advantages of large scale processing groups on electrochemical properties and application to organic photovoltaics. Synthesis

Li, Mo

20

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

in low-cost thin-film photovoltaic cells. Importantly, SubNcefficient organic photovoltaic cells with power conversionSubNc films in organic photovoltaic cells was evaluated in

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Dry formation of polymer hole injection layer for top emitting organic light emitting diodes  

Science Journals Connector (OSTI)

Dry formation of polymer hole injection layer is introduced as an effective method for improving the performance of top emitting organic light emitting diodes (TOLEDs). This method involves transferring a metal/polymer bilayer to the surface of organic layers of the device by pressing. An added advantage of this method is the ability to pattern the anode in the transfer process. Fabrication of the inverted TOLED by this method results in a drastic reduction of the turn-on voltage from 14.5 to 6.5 V when compared with a reference.

Soon-min Seo; Jong H. Kim; Hong H. Lee

2006-01-01T23:59:59.000Z

22

Electroluminescence in ion gel gated organic polymer semiconductor transistors  

E-Print Network [OSTI]

Harsha (N. Shastri), without whom I wouldn’t call myself complete, and am filled with gratitude to the cause that has brought us together, be it the god or that nature of probability function or the free will. Abstract This thesis reports the light... . The presence of a positive or negative charge causes a local structural relaxation of the polymer chain around the charge due to electron-phonon coupling similar to that of an exciton. This quasi-particle (spin = 1/2) of a charge and a lattice distortion...

Bhat, Shrivalli

2011-07-12T23:59:59.000Z

23

Highly efficient carbon dioxide capture with a porous organic polymer impregnated with  

E-Print Network [OSTI]

Highly efficient carbon dioxide capture with a porous organic polymer impregnated environmental crises such as global warming and ocean acidication, efficient carbon dioxide (CO2) capture As CO2 capture mate- rials, numerous solid adsorbents such as silica5 and carbon materials,6 metal

Paik Suh, Myunghyun

24

Self-Organization in Catalyst Layers of Polymer Electrolyte Fuel Cells  

Science Journals Connector (OSTI)

Self-Organization in Catalyst Layers of Polymer Electrolyte Fuel Cells ... These insights are highly valuable for the structural design of catalyst layers with optimized performance and stability. ... The foremost objective in optimizing the composition and structure of CLs is to provide the most uniform distributions of reactants and reaction rates possible and, thus, attain the highest catalyst utilizations and voltage efficiencies. ...

Kourosh Malek; Michael Eikerling; Qianpu Wang; Titichai Navessin; Zhongsheng Liu

2007-08-17T23:59:59.000Z

25

Self-organized stiffness in regular fractal polymer structures  

Science Journals Connector (OSTI)

We investigated membrane-like polymer structures of fractal connectivity such as Sierpinski gaskets and Sierpinski carpets applying the bond fluctuation model in three dimensions. Without excluded volume (phantom), both polymeric fractals obey Gaussian elasticity on larger scales determined by their spectral dimension. On the other hand, the swelling effect due to excluded volume is rather distinct between the two polymeric fractals: Self-avoiding Sierpinski gaskets can be described using a Flory-type mean-field argument. Sierpinski carpets having a spectral dimension closer to perfect membranes are significantly more strongly swollen than predicted. Based on our simulation results it cannot be excluded that Sierpinski carpets in athermal solvent show a flat phase on larger scales. We tested the self-consistency of Flory predictions using a virial expansion to higher orders. From this we conclude that the third virial coefficient contributes marginally to Sierpinski gaskets, but higher order virial coefficients are relevant for Sierpinski carpets.

Marco Werner and Jens-Uwe Sommer

2011-05-16T23:59:59.000Z

26

Conjugated Polymer Design and Engineering for Organic Electronics  

E-Print Network [OSTI]

power conversion efficiency (PCE) of an organic solar cellpower conversion efficiency (PCE or ?) at a given incident3.9%, 3.8%, and 3.8% peak PCE respectively at AM 1.5G with

Woo, Claire Hoi Kar

2011-01-01T23:59:59.000Z

27

Research on the electronic and optical properties of polymer and other organic molecular thin films  

SciTech Connect (OSTI)

The main goal of the work is to find materials and methods of optimization of organic layered electroluminescent cells and to study such properties of polymers and other organic materials that can be used in various opto-electronic devices. The summary of results obtained during the first year of work is presented. They are: (1) the possibility to produce electroluminescent cells using a vacuum deposition photoresist technology for commercial photoresists has been demonstrated; (2) the idea to replace the polyaryl polymers by other polymers with weaker hole conductivity for optimization of electroluminescent cells with ITO-Al electrodes has been suggested. The goal is to obtain amorphous processable thin films of radiative recombination layers in electroluminescent devices; (3) procedures of preparation of high-quality vacuum-deposited poly (p-phenylene) (PPP) films on various substrates have been developed; (4) it was found for the first time that the fluorescence intensity of PPP films depends on the degree of polymerization; (5) the role of interfaces between organic compounds, on one side, and metals or semiconductors, on the other side, has been studied and quenching of the fluorescence caused by semiconductor layer in thin sandwiches has been observed; (6) studies of the dynamics of photoexcitations revealed the exciton self-trapping in quasi-one-dimensional aggregates; and (7) conditions for preparation of highly crystalline fullerene C{sub 60} films by vacuum deposition have been found. Composites of C{sub 60} with conjugated polymers have been prepared.

NONE

1997-02-01T23:59:59.000Z

28

New N-Type Polymers for Organic Photovoltaics: Cooperative Research and Development Final Report, CRADA Number CRD-06-177  

SciTech Connect (OSTI)

This CRADA will develop improved thin film organic solar cells using a new n-type semiconducting polymer. High efficiency photovoltaics (PVs) based on inorganic semiconductors have good efficiencies (up to 30%) but are extremely expensive to manufacture. Organic PV technology has the potential to overcome this problem through the use of high-throughput production methods like reel-to-reel printing on flexible substrates. Unfortunately, today's best organic PVs have only a few percent efficiency, a number that is insufficient for virtually all commercial applications. The limited choice of stable n-type (acceptor) organic semiconductor materials is one of the key factors that prevent the further improvement of organic PVs. TDA Research, Inc. (TDA) previously developed a new class of electron-deficient (n-type) conjugated polymers for use in organic light emitting diodes (OLEDs). During this project TDA in collaboration with the National Renewable Energy Laboratory (NREL) will incorporate these electron-deficient polymers into organic photovoltaics and investigate their performance. TDA Research, Inc. (TDA) is developing new materials and polymers to improve the performance of organic solar cells. Materials being developed at TDA include spin coated transparent conductors, charge injection layers, fullerene derivatives, electron-deficient polymers, and three-phase (fullerene/polythiophene/dye) active layer inks.

Olson, D.

2014-08-01T23:59:59.000Z

29

Photo-induced charge transfer across the interface between organic molecular crystals and polymers  

E-Print Network [OSTI]

Photo-induced charge transfer of positive and negative charges across the interface between an ordered organic semiconductor and a polymeric insulator is observed in the field-effect experiments. Immobilization of the transferred charge in the polymer results in a shift of the field-effect threshold of polaronic conduction along the interface in the semiconductor, which allows for direct measurements of the charge transfer rate. The transfer occurs when the photon energy exceeds the absorption edge of the semiconductor. The direction of the transverse electric field at the interface determines the sign of the transferred charge; the transfer rate is controlled by the field magnitude and light intensity.

V. Podzorov; M. E. Gershenson

2004-11-23T23:59:59.000Z

30

Toward High-Performance Organic-Inorganic Hybrid Solar Cells: Bringing Conjugated Polymers and Inorganic Nanocrystals in Close  

E-Print Network [OSTI]

to traditional silicon solar cells due to the capacity of producing high- efficiency solar energy in a cost these advantages and progress, organic-inorganic hybrid solar cells still exhibit much lower PCEs (iToward High-Performance Organic-Inorganic Hybrid Solar Cells: Bringing Conjugated Polymers

Lin, Zhiqun

31

An electrocyclic strategy to poly(triarylmethyl radical) polymers: Potential organic ferromagnets  

SciTech Connect (OSTI)

Recent interest in organic ferromagnetism has been stimulated by the idea that large poly(triarylmethyl radical) polymers in which the radical centers are connected by [open quotes]meta[close quotes]-aryl groups may possess ferromagnetic properties. However, synthesis of these polyradicals has been limited by stepwise methods that are unsuitable for the preparation of large polymers. This limitation represents a primary challenge confronting the field. The authors have developed the first polymeric strategy to poly (m-triarylmethyl radical) precursors that involves an electrocyclic formation of the [open quotes]meta[close quotes]-substituted triarylmethyl chloride repeating unit from a polypropynol precursor. Poly[(E)-6-[beta]-chloroethenyl-1,3-phenylene-1-phenylpropynol-1,3-ylene] was prepared by palladium-catalyzed coupling of a bifunctional acetylene-aryl iodide monomer. The stable polymer reacted with thionyl chloride to form an unstable polychloroallene intermediate that underwent an electrocyclic conversion to the polyradical precursor, poly(1-chloro-2,7-naphthalenechlorobenzylidene). The reduced polyradicals exhibited properties of radical-radical coupling, and preparation of a second generation polymer that would overcome this problem has been initiated. The polymeric strategy was based on model studies that showed that (E)-3-(2-[beta]-chloroethenylphenyl)-1,1-diphenylpropynol, when converted to the corresponding chloroallene with thionyl chloride, underwent an electrocyclic conversion to [beta]-(1-chlornaphthyl)diphenylmethyl chloride. The strategy expanded upon the use of triarylpropynes as precursors to triarylmethyl chlorides, and extension of both approaches to higher analogs was demonstrated with dimeric systems. The electrocyclic processes were found to occur only for the trans-vinyl chlorides; the cis-isomers were found to undergo an alternative concerted cyclization to benzofluorene products.

Morelli, J.P.

1992-01-01T23:59:59.000Z

32

The conformational evolution of elongated polymer solutions tailors the polarization of light-emission from organic nanofibers  

E-Print Network [OSTI]

Polymer fibers are currently exploited in tremendously important technologies. Their innovative properties are mainly determined by the behavior of the polymer macromolecules under the elongation induced by external mechanical or electrostatic forces, characterizing the fiber drawing process. Although enhanced physical properties were observed in polymer fibers produced under strong stretching conditions, studies of the process-induced nanoscale organization of the polymer molecules are not available, and most of fiber properties are still obtained on an empirical basis. Here we reveal the orientational properties of semiflexible polymers in electrospun nanofibers, which allow the polarization properties of active fibers to be finely controlled. Modeling and simulations of the conformational evolution of the polymer chains during electrostatic elongation of semidilute solutions demonstrate that the molecules stretch almost fully within less than 1 mm from jet start, increasing polymer axial orientation at the jet center. The nanoscale mapping of the local dichroism of individual fibers by polarized near-field optical microscopy unveils for the first time the presence of an internal spatial variation of the molecular order, namely the presence of a core with axially aligned molecules and a sheath with almost radially oriented molecules. These results allow important and specific fiber properties to be manipulated and tailored, as here demonstrated for the polarization of emitted light.

Andrea Camposeo; Israel Greenfeld; Francesco Tantussi; Maria Moffa; Francesco Fuso; Maria Allegrini; Eyal Zussman; Dario Pisignano

2014-07-30T23:59:59.000Z

33

Preparation of dielectrics HR mirrors from colloidal oxide suspensions containing organic polymer binders  

SciTech Connect (OSTI)

Colloidal suspensions of oxides have been used to prepare dielectric HR (high reflective) mirrors, specifically for high power fusion case applications, on substrates up to 38 cm square using a meniscus coater. These coatings consist of porous quarterwave layers of alternating high and low refractive index oxides. Silica was used as the low index oxide and AlOOH, ZrO{sub 2}, or HfO{sub 2} as the high index material. Coatings were weak because of low particle-to-particle adhesion. Use of organic polymer binders in the high index component was found to increase strength, thereby improving the laser damage threshold and also reducing the number of layers required for 99% reflection due to increased refractive index.

Thomas, I.M.

1994-07-19T23:59:59.000Z

34

Analytical and Numerical Study of Photocurrent Transients in Organic Polymer Solar Cells  

E-Print Network [OSTI]

This article is an attempt to provide a self consistent picture, including existence analysis and numerical solution algorithms, of the mathematical problems arising from modeling photocurrent transients in Organic-polymer Solar Cells (OSCs). The mathematical model for OSCs consists of a system of nonlinear diffusion-reaction partial differential equations (PDEs) with electrostatic convection, coupled to a kinetic ordinary differential equation (ODE). We propose a suitable reformulation of the model that allows us to prove the existence of a solution in both stationary and transient conditions and to better highlight the role of exciton dynamics in determining the device turn-on time. For the numerical treatment of the problem, we carry out a temporal semi-discretization using an implicit adaptive method, and the resulting sequence of differential subproblems is linearized using the Newton-Raphson method with inexact evaluation of the Jacobian. Then, we use exponentially fitted finite elements for the spatial...

de Falco, Carlo; Verri, Maurizio; 10.1016/j.cma.2010.01.018

2012-01-01T23:59:59.000Z

35

Solution processable organic polymers and small molecules for bulk?heterojunction solar cells: A review  

Science Journals Connector (OSTI)

Solution processed bulk heterojunction (BHJ) organic solar cells (OSCs) have gained wide interest in past few years and are established as one of the leading next generation photovoltaic technologies for low cost power production. Power conversion efficiencies up to 6% and 6.5% have been reported in the literature for single layer and tandem solar cells respectively using conjugated polymers. A recent record efficiency about 8.13% with active area of 1.13 cm 2 has been reported. However Solution processable small molecules have been widely applied for photovoltaic (PV) devices in recent years because they show strong absorption properties and they can be easily purified and deposited onto flexible substrates at low cost. Introducing different donor and acceptor groups to construct donor—acceptor (D—A) structure small molecules has proved to be an efficient way to improve the properties of organic solar cells (OSCs). The power conversion efficiency about 4.4 % has been reported for OSCs based on the small molecules. This review deals with the recent progress of solution processable D—A structure small molecules and discusses the key factors affecting the properties of OSCs based on D—A structure small molecules: sunlight absorption charge transport and the energy level of the molecules.

G. D. Sharma

2011-01-01T23:59:59.000Z

36

Polymer and organic solar cells viewed as thin film technologies: What it will take for them to become a success outside academia  

Science Journals Connector (OSTI)

Abstract The polymer and organic solar cell technology is critically presented in the context of other thin film technologies with a specific focus on what it will take to make them a commercial success. The academic success of polymer and organic solar cells far outweigh any other solar cell technology when judging by the number of scientific publications whereas the application of polymer and organic solar cells in real products is completely lacking. This aspect is viewed as a sign of the polymer and organic solar cell field as being more complex and less mature and it raises the question of whether an organic analog to a successful inorganic technology is forcibly needed and indeed whether it is at all worth exploring beyond academia.

Frederik C. Krebs; Mikkel Jørgensen

2013-01-01T23:59:59.000Z

37

Self-organized Nano-lens Arrays by Intensified Dewetting of Electron Beam Modified Polymer Thin-films  

E-Print Network [OSTI]

Sub-100 nm polymeric spherical plano-convex nano-lens arrays are fabricated using short electron beam exposures to selectively modify the ultrathin (nano-lenses. The intensified self-organized dewetting under a water-organic solvent mixture overcomes the limitations on surface tension and dewetting force and thus facilitates the formation of sub-100 nm diameter polymer nanolenses of tunable curvature. By varying the extent of e-beam exposure, various configurations from isolated to connected nano-lens arrays can be fabricated.

Ankur Verma; Ashutosh Sharma

2011-09-18T23:59:59.000Z

38

The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells  

E-Print Network [OSTI]

bulk heterojunction organic solar cells, blends of a p-typecells, including organic solar cells and dye-sensitizedin a bilayer organic solar cell. At top is a cross section

Armstrong, Paul Barber

2010-01-01T23:59:59.000Z

39

Miniaturized Low-power Electro-optic Modulator Based on Silicon Integrated Nanophotonics and Organic Polymers  

E-Print Network [OSTI]

We design and demonstrate a compact, low-power, low-dispersion and broadband optical modulator based on electro-optic (EO) polymer refilled silicon slot photonic crystal waveguide (PCW). The EO polymer is engineered for large EO activity and near-infrared transparency. The half-wave switching-voltage is measured to be V{\\pi}=0.97V over optical spectrum range of 8nm, corresponding to a record-high effective in-device r33 of 1190pm/V and V{\\pi} L of 0.291Vmm in a push-pull configuration. Excluding the slow-light effect, we estimate the EO polymer is poled with an ultra-high efficiency of 89pm/V in the slot. In addition, to achieve high-speed modulation, silicon PCW is selectively doped to reduce RC time delay. The 3-dB RF bandwidth of the modulator is measured to be 11GHz, and a modulation response up to 40GHz is observed.

Zhang, Xingyu; Luo, Jingdong; Jen, Alex K -Y; Chen, Ray T

2014-01-01T23:59:59.000Z

40

Photo-Curable Polymer Blend Dielectrics for Advancing Organic Field-Effect Transistor Applications  

SciTech Connect (OSTI)

A solution method of photo-curable and -patternable polymer gate dielectrics was introduced by using blend solutions of poly(4-dimethylsilyl styrene) (PDMSS) and poly(melamine-co-formaldehyde) acrylate (PMFA). The fabrication was optimized to produce a smooth hydrophobic gate dielectric with good insulating and solvent-resistant properties. On the optimized PDMSS/PMFA blend gate dielectric, pentacene could grow into highly ordered structure, showing high electric performances for the resulting OFETs, as well as PTCDI-C13 and TES-ADT.

S Kim; K Hong; M Jang; J Jang; J Anthony; H Yang; C Park

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Study of organic molecules and nano-particle/polymer composites for flash memory and switch applications  

E-Print Network [OSTI]

Organic materials exhibit fascinating optical and electronic properties which motivate their hybridization with traditional silicon-based electronics in order to achieve novel functionalities and address scaling challenges ...

Paydavosi, Sarah

2012-01-01T23:59:59.000Z

42

Sputtered Nickel Oxide Thin Film for Efficient Hole Transport Layer in Polymer-Fullerene Bulk-Heterojunction Organic Solar Cell  

SciTech Connect (OSTI)

Bulk-heterojunction (BHJ) organic photovoltaics (OPV) are very promising thin film renewable energy conversion technologies due to low production cost by high-throughput roll-to-roll manufacturing, an expansive list of compatible materials, and flexible device fabrication. An important aspect of OPV device efficiency is good contact engineering. The use of oxide thin films for this application offers increased design flexibility and improved chemical stability. Here we present our investigation of radio frequency magnetron sputtered nickel oxide (NiO{sub x}) deposited from oxide targets as an efficient, easily scalable hole transport layer (HTL) with variable work-function, ranging from 4.8 to 5.8 eV. Differences in HTL work-function were not found to result in statistically significant changes in open circuit voltage (V{sub oc}) for poly(3-hexylthiophene):[6,6]-phenyl-C{sub 61}-butyric acid methyl ester (P3HT:PCBM) BHJ device. Ultraviolet photoemission spectroscopy (UPS) characterization of the NiO{sub x} film and its interface with the polymer shows Fermi level alignment of the polymer with the NiO{sub x} film. UPS of the blend also demonstrates Fermi level alignment of the organic active layer with the HTL, consistent with the lack of correlation between V{sub oc} and HTL work-function. Instead, trends in j{sub sc}, V{sub oc}, and thus overall device performance are related to the surface treatment of the HTL prior to active layer deposition through changes in active layer thickness.

Widjonarko, N. E.; Ratcliff, E. L.; Perkins, C. L.; Sigdel, A. K.; Zakutayev, A.; Ndione, P. F.; Gillaspie, D. T.; Ginley, D. S.; Olson, D. C.; Berry, J. J.

2012-03-01T23:59:59.000Z

43

Sulfides organic polymer: Novel cathode active material for rechargeable lithium batteries  

Science Journals Connector (OSTI)

Two novel sulfide polymers, poly(2-phenyl-1,3-dithiolane) and poly[1,4-di(1,3-dithiolan-2-yl)benzene], were prepared via facile oxidative-coupling polymerization under ambient conditions, characterized by FT-IR, XRD, TGA and elemental analysis, and were tested as cathode materials in rechargeable lithium battery. The charge–discharge tests showed that the specific capacity of poly[1,4-di(1,3-dithiolan-2-yl)benzene)] was 378 mAh g?1 at the third cycle, and retained at 300 mAh g?1 after 20 cycles. The specific capacity of poly(2-phenyl-1,3-dithiolane) was 117 mAh g?1 at the second cycle, and retained at 100 mAh g?1 after 20 cycles. The results indicated that thiolane group could be used as cathode active function group for lithium secondary batteries and the novel electrode reaction is proposed tentatively.

Jing Yu Zhang; Ling Bo Kong; Li Zhi Zhan; Jing Tang; Hui Zhan; Yun Hong Zhou; Cai Mao Zhan

2007-01-01T23:59:59.000Z

44

Polymer and carbon nanotube materials for chemical sensors and organic electronics  

E-Print Network [OSTI]

This thesis details the development of new materials for high-performance chemical sensing as well as organic electronic applications. In Chapter 2, we develop a chemiresistive material based on single-walled carbon nanotubes ...

Wang, Fei, Ph. D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

45

Organic solar cells based on conjugated polymers : History and recent advances  

Science Journals Connector (OSTI)

Organic solar cells have attracted huge attention because of their ... potential in the low-cost manufacturing of plastic solar modules featuring flexible, lightweight, ultrathin, rollable ... bendable shapes. Th...

Hwajeong Kim; Sungho Nam; Jaehoon Jeong…

2014-07-01T23:59:59.000Z

46

Nonphotochemical hole burning of organic dyes and rare earth ions in polymers and glasses: a probe of the amorphous state  

SciTech Connect (OSTI)

New and in depth studies of amorphous materials (e.g., glasses and polymers) probed via the low temperature optical technique of nonphotochemical hole burning (NPHB) are presented. An extensive review of the phenomena itself, along with selected topics involving the use of persistent hole burning techniques, is given. In addition, a semi-complete tabulation of essentially all hole burning systems to date is included. The deuteration dependence in an amorphous host is examined for the system of tetracene in an ethanol/methanol mixture. The results illustrate the importance of hydrogen bonding in the hole burning process. The discovery of a highly efficient (or facile) class of hole burning systems, i.e., ionic dyes in hydroxylated polymers (i.e., poly(vinyl alcohol) (PVOH) and poly(acrylic acid) (PAA)), is presented and discussed. Ultrafast relaxation processes (i.e., dephasing) are studied for the system of cresyl violet perchlorate (CV) in PVOH. Further, for the first time, NPHB of rare earth ions, specifically Pr/sup +3/ and Nd/sup +3/, in a soft organic glass (i.e., PVOH) is discussed briefly. Detailed experimental results of two related phenomena, spontaneous hole filling (SPHF) and laser induced hole filling (LIHF), are presented and discussed for several systems: rhodamine 560 perchlorate (R560), rhodamine 640 perchlorate (R640), CV, Pr/sup +3/ and Nd..mu../sup 3/ in either PVOH or PAA. A theoretical model is developed for SPHF. The model invokes a correlated feedback mechanism from the anti-hole, which is able to account for the fact that no line broadening is observed. A tentative model is also presented for the phenomenon of LIHF.

Fearey, B.L.

1986-01-01T23:59:59.000Z

47

Self-organizing molecular photonic structures based on functionalized synthetic nucleic acid (DNA) polymers  

Science Journals Connector (OSTI)

Work has been carried out with the objective of imparting the electronic/photonic property of extended Forster energy transfer into organized structures formed by the programmed self-assembly of synthetic nucleic acid units (fluorescent oligonucleotides and polynucleotides). Forster energy transfer is a non-radiative process by which a fluorescent donor molecule excited at one wavelength is able to transfer its absorbed photonic energy efficiently to a fluorescent acceptor molecule, in close proximity, which then re-emits it at a second wavelength. An extended energy transfer system, with multiple donor molecules, could be considered a molecular photonic antenna or amplifier structure. Relatively efficient extended Forster energy transfer was observed in initial experiments involving multiple fluorescent donor and acceptor oligonucleotides. These results provide a clear demonstration of totally synthetic molecules, with highly specific programmable self-assembling properties, organizing into molecular structures with useful electronic/photonic properties.

M J Heller; R H Tullis

1991-01-01T23:59:59.000Z

48

Ag(I) Ion Functionalized Porous Organic Polymers As a New Platform for Highly Selective Adsorption of Ethylene over Ethane  

SciTech Connect (OSTI)

We report herein a strategy of incorporating air stable Ag(I) ions into water stable, high surface area porous organic polymer (POP) affording significant increase in ethylene uptake capacity and extremely high Qst for ethylene (over 100 kJ/mol at low ethylene load-ing) as illustrated in the context of Ag(I) ion functionalized PAF-1, PAF-1-SO3Ag. IAST calculations using single-component-isotherm data and equimolar ethylene/ethane ratio at 296 K reveal PAF-1-SO3Ag shows exceptionally high ethylene/ethane adsorption selectivi-ty (Sads: 27 to 125), far surpassing benchmark zeolite and any other MOF reported in literature. This alongside excellent water/air stability, high ethylene uptake capacity, and mild regeneration requirements make PAF-1-SO3Ag hold promise for adsorption-based eth-ylene/ethane separations, paving a way to develop Ag(I) ion function-alized POPs as a new platform for highly selective adsorption of eth-ylene over ethane.

LI, Baiyan [University of South Florida, Tampa; Zhang, Yiming [University of South Florida, Tampa; Ma, Dingxuan [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University; Wu, Zili [ORNL; Ma, Shengqian [University of South Florida, Tampa

2014-01-01T23:59:59.000Z

49

Effect of the organic groups of difunctional silanes on the preparation of coated clays for olefin polymer modification  

Science Journals Connector (OSTI)

...phase behavior of polymer-clay composites. Macromolecules , 31 , 6676-6680...of high density polyethylene composites based on poly(diphenyl-siloxanes...Fracture studies of polypropylene/nanoclay composite. Part I: Effect of loading...

F. E. Monasterio; M. L. Dias; V. J. R. R. Pita; E. Erdmann; H. A. Destéfanis

50

A Key Target for Diabetes Drugs | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molten Metal Solidifies into a New Kind of Glass Molten Metal Solidifies into a New Kind of Glass Organic Polymers Show Sunny Potential A New Family of Quasicrystals Cool Muscles: Storing Elastic Energy for Flight A Further Understanding of Superconductivity Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A Key Target for Diabetes Drugs JULY 26, 2013 Bookmark and Share The structure of the human glucagon receptor, which could help scientists design new drugs for type 2 diabetes. (Image courtesy of Katya Kadyshevskaya, The Scripps Research Institute) The three-dimensional (3-D) atomic structure of the human glucagon receptor has been identified by an international team of researchers carrying out

51

Controlled Self Assembly of Conjugated Polymer Containing Block Copolymers  

E-Print Network [OSTI]

Copolymers for Organic Optoelectronics. Macromolecules 2009,Copolymers for Organic Optoelectronics. Macromolecules 2009,performance of polymer optoelectronics. Table of Contents

McCulloch, Bryan

2012-01-01T23:59:59.000Z

52

Comparison of light out-coupling enhancements in single-layer blue-phosphorescent organic light emitting diodes using small-molecule or polymer hosts  

SciTech Connect (OSTI)

Single-layer blue phosphorescence organic light emitting diodes (OLEDs) with either small-molecule or polymer hosts are fabricated using solution process and the performances of devices with different hosts are investigated. The small-molecule device exhibits luminous efficiency of 14.7?cd/A and maximum power efficiency of 8.39?lm/W, which is the highest among blue phosphorescence OLEDs with single-layer solution process and small molecular hosts. Using the same solution process for all devices, comparison of light out-coupling enhancement, with brightness enhancement film (BEF), between small-molecule and polymer based OLEDs is realized. Due to different dipole orientation and anisotropic refractive index, polymer-based OLEDs would trap less light than small molecule-based OLEDs internally, about 37% better based simulation results. In spite of better electrical and spectroscopic characteristics, including ambipolar characteristics, higher carrier mobility, higher photoluminescence quantum yield, and larger triplet state energy, the overall light out-coupling efficiency of small molecule-based devices is worse than that of polymer-based devices without BEF. However, with BEF for light out-coupling enhancement, the improved ratio in luminous flux and luminous efficiency for small molecule based device is 1.64 and 1.57, respectively, which are significantly better than those of PVK (poly-9-vinylcarbazole) devices. In addition to the theoretical optical simulation, the experimental data also confirm the origins of differential light-outcoupling enhancement. The maximum luminous efficiency and power efficiency are enhanced from 14.7?cd/A and 8.39?lm/W to 23?cd/A and 13.2?lm/W, respectively, with laminated BEF, which are both the highest so far for single-layer solution-process blue phosphorescence OLEDs with small molecule hosts.

Chang, Yung-Ting [Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, Taiwan (China); Department of Electrical Engineering, Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei, Taiwan 10617, Taiwan (China); Liu, Shun-Wei [Department of Electronic Engineering, Mingchi University of Technology, New Taipei, Taiwan 24301, Taiwan (China); Yuan, Chih-Hsien; Lee, Chih-Chien [Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan 10607, Taiwan (China); Ho, Yu-Hsuan; Wei, Pei-Kuen [Research Center for Applied Science Academia Sinica, Taipei, Taiwan 11527, Taiwan (China); Chen, Kuan-Yu [Chilin Technology Co., LTD, Tainan City, Taiwan 71758, Taiwan (China); Lee, Yi-Ting; Wu, Min-Fei; Chen, Chin-Ti, E-mail: cchen@chem.sinica.edu.tw, E-mail: chihiwu@cc.ee.ntu.edu.tw [Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, Taiwan (China); Wu, Chih-I, E-mail: cchen@chem.sinica.edu.tw, E-mail: chihiwu@cc.ee.ntu.edu.tw [Department of Electrical Engineering, Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei, Taiwan 10617, Taiwan (China)

2013-11-07T23:59:59.000Z

53

Controlled Self Assembly of Conjugated Polymer Containing Block Copolymers  

E-Print Network [OSTI]

in dye/polymer blend photovoltaic cells. Advanced MaterialsA. J. , Polymer Photovoltaic Cells - Enhanced Efficiencies2-Layer Organic Photovoltaic Cell. Applied Physics Letters

McCulloch, Bryan

2012-01-01T23:59:59.000Z

54

Design and Synthesis of Chemically and Electronically Tunable Nanoporous Organic Polymers for Use in Hydrogen Storage Applications - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 6 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Hani M. El-Kaderi (Primary Contact), Mohammad G. Rabbani, Thomas E. Reich, Karl T. Jackson, Refaie M. Kassab Virginia Commonwealth University Department of Chemistry 1001 West Main St Richmond, VA 23284-2006 Phone: (804) 828-7505 Email: helkaderi@vcu.edu DOE Program Officer: Michael Sennett Phone: (301) 903-6051 Email: Michael.Sennett@science.doe.go Objectives Design and synthesis of new classes of low density * nanoporous organic polymers that are linked by strong covalent bonds and composed of chemically and electronically tunable building blocks. Use gas sorption experiments to investigate porosity and * determine hydrogen storage at variable temperature and

55

Polymer Electrolyte and Polymer Battery  

Science Journals Connector (OSTI)

Generally the polymer electrolyte of the polymer battery is classified into two kinds of the electrolyte: One is a dry-type electrolyte composed of a polymer matrix and...21.1. Fig....

Toshiyuki Osawa; Michiyuki Kono

2009-01-01T23:59:59.000Z

56

Fabrication and Characterization of Organic Solar Cells  

E-Print Network [OSTI]

processable polymer photovoltaic cells by self?organization Photodiodes,  and  Photovoltaic  Cells.   Applied Physics F,  Heeger  AJ.   Polymer  Photovoltaic  Cells  ?  Enhanced 

Yengel, Emre

2010-01-01T23:59:59.000Z

57

Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture  

SciTech Connect (OSTI)

IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

None

2010-07-01T23:59:59.000Z

58

Energy level alignment in polymer organic solar cells at donor-acceptor planar junction formed by electrospray vacuum deposition  

SciTech Connect (OSTI)

Using ultraviolet photoelectron spectroscopy (UPS), we have measured the energy level offset at the planar interface between poly(3-hexylthiophene) (P3HT) and C{sub 61}-butyric acid methylester (PCBM). Gradual deposition of PCBM onto spin-coated P3HT in high vacuum was made possible by using electrospray vacuum deposition (EVD). The UPS measurement of EVD-prepared planar interface resulted in the energy level offset of 0.91?eV between P3HT HOMO and PCBM LUMO, which is considered as the upper limit of V{sub oc} of the organic photovoltaic cells.

Kim, Ji-Hoon; Hong, Jong-Am; Kwon, Dae-Gyeon; Seo, Jaewon; Park, Yongsup, E-mail: parky@khu.ac.kr [Department of Physics and Research Institute for Basic Sciences, Kyung Hee University, Seoul 130-701 (Korea, Republic of)

2014-04-21T23:59:59.000Z

59

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

2000-01-01T23:59:59.000Z

60

Model systems for single molecule polymer Folarin Latinwoa  

E-Print Network [OSTI]

, including synthetic organic polymers. Recently, we developed single stranded DNA (ssDNA) as a new model, the local phys- ical and chemical properties of dsDNA are distinct from common synthetic organic polymer DNA (ssDNA).15 ssDNA is a flexible polymer with local physical properties similar to synthetic organic

Schroeder, Charles

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organization Print Organization Print 2012-12 org chart A complete ALS organization chart (June 2013) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Steve Kevan, Deputy Division Director, Science Michael J. Banda, Deputy Division Director, Operations Robert W. Schoenlein, Senior Staff Scientist, Next Generation Light Source Initiative Janos Kirz, Scientific Advisor Paul Adams, Division Deputy for Biosciences ALS Scientific, Technical, and User Support Groups Accelerator Physics

62

Achieving High Performance Polymer Tandem Solar Cells via Novel Materials Design  

E-Print Network [OSTI]

polymers for organic solar cell applications. Chem. Rev.Hummelen, J. C. , Plastic solar cells. Adv. Funct. Mater.Efficient inverted polymer solar cells. Appl. Phys. Lett.

Dou, Letian

2014-01-01T23:59:59.000Z

63

Electrochemistry in Diabetes Management  

Science Journals Connector (OSTI)

Electrochemistry in Diabetes Management ... The 5.8 × 10?6 cm2 s?1 apparent electron diffusion coefficient in the hydrogel formed of the cross-linked polymer approaches the diffusion coefficient of ions, like Cl?, in water. ... Ben and two E. Heller & Co., TheraSense, and Abbott colleagues were present: TheraSense founder Ephraim Heller, who identified the need for and defined the blood volume required for the painless monitoring of glucose and made it the objective of TheraSense, and Tim Goodnow, Vice President R&D of TheraSense and now Divisional Vice President, Technical Operations of ADC, who managed the complex development and engineering of the continuous glucose monitor, involving chemistry, chemical engineering, materials science and engineering, electrical engineering, microelectronics, software engineering, mechanical engineering, process engineering, and endocrinology. ...

Adam Heller; Ben Feldman

2010-04-12T23:59:59.000Z

64

Achieving High Performance Polymer Tandem Solar Cells via Novel Materials Design  

E-Print Network [OSTI]

of conjugated polymers for organic solar cell applications.characterization of organic solar cells. Adv. Funct. Mater.techniques for the organic solar cell are employed to

Dou, Letian

2014-01-01T23:59:59.000Z

65

EMSL - polymers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

polymers en Structures and Stabilities of (MgO)n Nanoclusters. http:www.emsl.pnl.govemslwebpublicationsstructures-and-stabilities-mgon-nanoclusters

66

SEC data for polymer 1-6: UV-vis spectra for polymer 1-6  

E-Print Network [OSTI]

for organic solar cells Eva Bundgaard a,b and Frederik C. Krebs a a Polymer Solar Cell Initiative, The Danish for these devices is summarized in the table below. IV-curve for the polymer 5 and PCBM: The photovoltaic studies of the device by a better overlap with the solar spectrum. The synthesis of low band gap polymers are however

67

New functional polymers for sensors, smart materials and solar cells  

E-Print Network [OSTI]

Organic polymers can be used as the active component of sensors, smart materials, chemical-delivery systems and the active layer of solar cells. The rational design and modification of the chemical structure of polymers ...

Lobez Comeras, Jose Miguel

2012-01-01T23:59:59.000Z

68

Conducting Polymer Devices for Bioelectronics  

E-Print Network [OSTI]

signals recording. Organic electrochemical transistors (OECTs) represent a step beyond conducting polymer a far superior signal-to-noise- ratio (SNR) compared to electrodes. The high SNR of the OECT recordings and contamination. The use of an organic electrochemical transistor for detection of lactate by integration

Paris-Sud XI, Université de

69

Muon Studies in Organic Conductors [and Discussion  

Science Journals Connector (OSTI)

15 February 1995 research-article Muon Studies in Organic Conductors [and Discussion...Stoneham This paper contains a brief review of muon studies of organic conductors with emphasis...polymers. The species created by implanted muons in both semiconducting polymers and polymers...

1995-01-01T23:59:59.000Z

70

Polymer Brushes  

Science Journals Connector (OSTI)

...DOLAN, A.K., EFFECT OF EXCLUDED VOLUME ON POLYMER DISPERSANT ACTION, PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES...prop-erties of a tagged subset of chain units. One example is the nuclear magnetic resonance (NMR) studies by Blum and co-workers...

S. T. MILNER

1991-02-22T23:59:59.000Z

71

A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties  

SciTech Connect (OSTI)

Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers, [Zn(L)(1,4-bdc){sub 0.5}] (1), [Zn{sub 1.5}(L)(2,5-pydc)] (2), [Zn(HL)(1,2,4,5-btec){sub 0.5}] (3), and [Cd(HL)(1,2,4,5-btec){sub 0.5}] (4) (1,4-bdc, 1,4-benzenedicarboxylate; 2,5-pydc, 2,5-pyridinedicarboxylate; 1,2,4,5-btec, 1,2,4,5-benzenetetracarboxylate) have been successfully synthesized and analyzed. Compound 1 features the 2D [Zn(L)]{sub n} layers built by ?{sub 3}-L bridging ligands and Zn(II) ions, which are further linked by pillared 1,4-bdc{sup 2?} ligands to form a 2-fold interpenetrating dmc framework. The 3D network of compound 2 can be simplified as a rare 2-nodal (3,6)-connected rtl (rutile) topology. Compound 3 possesses a 2D layer structure which is accomplished by connecting ladder-chains to L ligands. Compound 4 exhibits 2D [Cd(1,2,4,5-btec)] layers with infinite Cd–O–Cd rods and the adjacent 2D networks are further pillared by L with terminal bidentate coordination mode to generate the final 3D structure. The solid-state luminescent studies show that compounds 1–4 display intense fluorescent emissions. - Graphical abstract: Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers have been obtained. All compounds show good luminescence properties at room temperature. Display Omitted - Highlights: • Four Zn(II)/Cd(II)-MOCPs have been successfully prepared with the rigid bifunctional ligand 5-(4-imidazol -1-yl-phenyl) -2H-tetrazole and different aromatic carboxylates mixed ligands. • Compound 2 is a 2-nodal rtl (rutile) net and compound 4 is a binodal (5, 6)-connected net with yav topology. • Compounds 1-4 display intense fluorescent emissions at room temperature.

Sun, Jiayin [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Daojun, E-mail: zhangdj0410@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Wang, Li [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Renchun; Wang, Junjie; Zeng, Ying; Zhan, Jinling [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Xu, Jianing [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Fan, Yong, E-mail: mrfy@jlu.edu.cn [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

2013-10-15T23:59:59.000Z

72

Conductive Polymers  

SciTech Connect (OSTI)

Electroluminescent devices such as light-emitting diodes (LED) and high-energy density batteries. These new polymers offer cost savings, weight reduction, ease of processing, and inherent rugged design compared to conventional semiconductor materials. The photovoltaic industry has grown more than 30% during the past three years. Lightweight, flexible solar modules are being used by the U.S. Army and Marine Corps for field power units. LEDs historically used for indicator lights are now being investigated for general lighting to replace fluorescent and incandescent lights. These so-called solid-state lights are becoming more prevalent across the country since they produce efficient lighting with little heat generation. Conductive polymers are being sought for battery development as well. Considerable weight savings over conventional cathode materials used in secondary storage batteries make portable devices easier to carry and electric cars more efficient and nimble. Secondary battery sales represent an $8 billion industry annually. The purpose of the project was to synthesize and characterize conductive polymers. TRACE Photonics Inc. has researched critical issues which affect conductivity. Much of their work has focused on production of substituted poly(phenylenevinylene) compounds. These compounds exhibit greater solubility over the parent polyphenylenevinylene, making them easier to process. Alkoxy substituted groups evaluated during this study included: methoxy, propoxy, and heptyloxy. Synthesis routes for production of alkoxy-substituted poly phenylenevinylene were developed. Considerable emphasis was placed on final product yield and purity.

Bohnert, G.W.

2002-11-22T23:59:59.000Z

73

Viscosity of polymer solutions  

Science Journals Connector (OSTI)

Viscosity of polymer solutions ... Abstracts for Volume 5A, Number 2. This program contains three components: "Density of Liquids", "Viscosity of Liquids", and "Viscosity of Polymer Solutions". ...

Gary L. Bertrand

1992-01-01T23:59:59.000Z

74

Diagnosis of Diabetes  

Science Journals Connector (OSTI)

...sensitivity (with an acceptable drop in specificity) for persons with an increased diabetes risk. Longitudinal investigations have shown that persons categorized as being "impaired" by any of these definitions have approximately a 5 to 10% annualized risk of diabetes, a risk that is greater by a factor... This article reviews recommendations for diabetes screening, which vary with respect to whether and how to screen. The American Diabetes Association recommends screening persons 45 of age or older or with other risk factors by means of fasting glucose or glycated hemoglobin testing.

Inzucchi S.E.

2012-08-09T23:59:59.000Z

75

Paths to Diabetes  

E-Print Network [OSTI]

Apr 29, 2004 ... This is known as insulin resistance and occurs in type 2 diabetics. Another facet of the condition is the blood glucose concentration.

76

Polymer system for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

77

Polymer formulations for gettering hydrogen  

DOE Patents [OSTI]

A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

1998-11-17T23:59:59.000Z

78

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

79

Polymer and small molecule based hybrid light source  

DOE Patents [OSTI]

An organic electroluminescent device, includes: a substrate; a hole-injecting electrode (anode) coated over the substrate; a hole injection layer coated over the anode; a hole transporting layer coated over the hole injection layer; a polymer based light emitting layer, coated over the hole transporting layer; a small molecule based light emitting layer, thermally evaporated over the polymer based light emitting layer; and an electron-injecting electrode (cathode) deposited over the electroluminescent polymer layer.

Choong, Vi-En (Carlsbad, CA); Choulis, Stelios (Nuremberg, DE); Krummacher, Benjamin Claus (Regensburg, DE); Mathai, Mathew (Monroeville, PA); So, Franky (Gainesville, FL)

2010-03-16T23:59:59.000Z

80

High Seebeck effects from conducting polymer: Poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) based thin-film device with hybrid metal/polymer/metal architecture  

SciTech Connect (OSTI)

Conductive polymers are of particular interest for thermoelectric applications due to their low thermal conductivity and relatively high electrical conductivity. In this study, commercially available conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) was used in a hybrid metal/polymer/metal thin film design in order to achieve a high Seebeck coefficient with the value of 252lV/k on a relatively low temperature scale. Polymer film thickness was varied in order to investigate its influence on the Seebeck effect. The high Seebeck coefficient indicates that the metal/polymer/metal design can develop a large entropy difference in internal energy of charge carriers between high and low-temperature metal electrodes to develop electrical potential due to charge transport in conducting polymer film through metal/polymer interface. Therefore, the metal/polymer/metal structure presents a new design to combine inorganic metals and organic polymers in thin-film form to develop Seebeck devices

Stanford, Michael G [ORNL; Wang, Hsin [ORNL; Ivanov, Ilia N [ORNL; Hu, Bin [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Inorganic-Organic Hybrid Thermoelectrics  

Broader source: Energy.gov [DOE]

Large-scale synthesis of inorganic and organic nanomaterials (single-crystalline nanowires and functionalized conducting polymer thin films) together with strategies for large-scale assembly are discussed

82

Chitosan-based therapeutic nanoparticles for combination gene therapy and gene silencing of in vitro cell lines relevant to type 2 diabetes  

E-Print Network [OSTI]

Chitosan-based therapeutic nanoparticles for combination gene therapy and gene silencing 2011 Keywords: Type 2 diabetes Glucagon like peptide 1 Dipeptydil-peptidase IV siRNA Chitosan Gene-IV) endoprotease. In this study, the glucosamine-based polymer chitosan was used as a cationic polymer

Buschmann, Michael

83

Vacuum-Deposited Planar Heterojunction Polymer Solar Cells  

Science Journals Connector (OSTI)

Vacuum-Deposited Planar Heterojunction Polymer Solar Cells ... Bilayer heterojunction solar cells were fabricated by sequential deposition of P3HT and C60 and the photovoltaic response measured. ... organic solar cells; conjugated polymers; poly(3-hexylthiophene); vacuum thermal deposition; thin films ...

Peter Kovacik; Giuseppe Sforazzini; Andrew G. Cook; Shawn M. Willis; Patrick S. Grant; Hazel E. Assender; Andrew A. R. Watt

2010-12-14T23:59:59.000Z

84

Molecular design of conjugated polymers for the control of conformation, electronics and self-assembly  

E-Print Network [OSTI]

The design, synthesis and characterization of organic electronic materials, in particular luminescent conjugated polymers, with structural motifs that allow for the controlled modulation of their photophysical properties ...

Bouffard, Jean, Ph. D. Massachusetts Institute of Technology

2008-01-01T23:59:59.000Z

85

Nanoporous polymer electrolyte  

DOE Patents [OSTI]

A nanoporous polymer electrolyte and methods for making the polymer electrolyte are disclosed. The polymer electrolyte comprises a crosslinked self-assembly of a polymerizable salt surfactant, wherein the crosslinked self-assembly includes nanopores and wherein the crosslinked self-assembly has a conductivity of at least 1.0.times.10.sup.-6 S/cm at 25.degree. C. The method of making a polymer electrolyte comprises providing a polymerizable salt surfactant. The method further comprises crosslinking the polymerizable salt surfactant to form a nanoporous polymer electrolyte.

Elliott, Brian (Wheat Ridge, CO); Nguyen, Vinh (Wheat Ridge, CO)

2012-04-24T23:59:59.000Z

86

Innovative approaches to improve bulk heterojuction organic photovoltaic device performance.  

E-Print Network [OSTI]

??In this thesis we studied the electrical properties of bulk heterojunction organic photovoltaic (OPV) devices fabricated using a variety of conjugated polymers, including regioregular P3HT,… (more)

Zhang, Ye

2010-01-01T23:59:59.000Z

87

Fabrication and life cycle assessment of organic photovoltaics.  

E-Print Network [OSTI]

??Increasing demand for renewable energy has resulted in a new interest for alternative technologies such as organic photovoltaics. With efficiencies exceeding 8% for both polymer… (more)

Anctil, Annick

2011-01-01T23:59:59.000Z

88

Polymer-assisted deposition of films  

DOE Patents [OSTI]

A polymer assisted deposition process for deposition of metal nitride films and the like is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures under a suitable atmosphere to yield metal nitride films and the like. Such films can be conformal on a variety of substrates including non-planar substrates. In some instances, the films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.

McCleskey,Thomas M. (Los Alamos, NM); Burrell,Anthony K. (Los Alamos, NM); Jia,Quanxi (Los Alamos, NM); Lin,Yuan (Chandler, AZ)

2012-02-28T23:59:59.000Z

89

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Structure of All-Polymer Solar Cells Impedes Efficiency Structure of All-Polymer Solar Cells Impedes Efficiency Print Wednesday, 27 October 2010 00:00 Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

90

Bulk Heterojunction Polymer Solar Cells  

Science Journals Connector (OSTI)

Recent developments on bulk-heterojunction polymer photovoltaic diodes will be presented, focusing on the mechanism of charge generation, low bandgap polymers for increased photon...

Janssen, René

91

Radioluminescent polymer lights  

SciTech Connect (OSTI)

The preparation of radioluminescent light sources where the tritium is located on the aryl-ring in a polymer has been demonstrated with deuterium/tritium substitution. This report discusses tests, results, and future applications of radioluminescent polymers. 10 refs. (FI)

Jensen, G.A.; Nelson, D.A.; Molton, P.M.

1990-09-01T23:59:59.000Z

92

Method of making soluble polyacetylenic and polyaromatic polymers  

DOE Patents [OSTI]

A soluble polyene polymer and a method of making the same are disclosed. The polymer is of the class suitable for doping to produce an electrically conductive polymer. The method is generally applicable to acetylenic and aromatic monomers, proven examples of which include acetylene, benzene, anthracene and napthalene. In accordance with the method, the monomer is dissolved in arsenic trifluoride. Arsenic pentafluoride is then introduced into the solution to induce polymerization by what is speculated to be an ionic polymerization reaction. The resulting polymer differs from other polyene polymers in that it is soluble in common organic solvents, and further in that it can be melted without undergoing decomposition, thereby rendering it particularly suitable for processing to form various polymeric articles.

Aldissi, Mahmoud (Los Alamos, NM); Liepins, Raimond (Los Alamos, NM)

1985-01-01T23:59:59.000Z

93

GLASSY STATES OF ADSORBED FLEXIBLE POLYMERS AND SPREAD POLYMER "MONOLAYERS"  

E-Print Network [OSTI]

1269 GLASSY STATES OF ADSORBED FLEXIBLE POLYMERS AND SPREAD POLYMER "MONOLAYERS" K. KREMER* Exxon mechanism for the dynamics of irreversibly adsorbed polymers. We argue that glass-like states can exist near of polymer adsorbed ' ' and the thickness of the adsorbed layer 2-7. While the results of the different

Paris-Sud XI, Université de

94

Conducting polymer and hydrogenated amorphous silicon hybrid solar cells  

E-Print Network [OSTI]

November 2005 An organic-inorganic hybrid solar cell with a p-i-n stack structure has been investigated for their potential in electronic devices such as organic light emitting diodes OLEDs , solar cells, photode- tectorsConducting polymer and hydrogenated amorphous silicon hybrid solar cells Evan L. Williams

Schiff, Eric A.

95

Semipermeable polymers and method for producing same  

DOE Patents [OSTI]

A polyamide membrane comprising reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst; and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant comprising one ring. A composite semipermeable membrane comprising the polyamide membrane on a porous support. A method of making a composite semipermeable membrane by coating a porous support with an anhydrous solution comprising an anhydrous solvent, a polyfunctional secondary amine and a pre-polymer deposition catalyst, to form an activated pre-polymer layer on the porous support and contacting the activated pre-polymer layer with an anhydrous, organic solvent solution comprising a polyfunctional amine-reactive reactant to interfacially condense the amine-reactive reactant with the polyfunctional secondary amine, thereby forming a cross-linked, interfacial polyamide layer on the porous support. A method of impregnating a composite semipermeable membrane with nanoparticles selected from heavy metals and/or oxides of heavy metals.

Buschmann, Wayne E. (Boulder, CO)

2012-04-03T23:59:59.000Z

96

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Cells Impedes Efficiency Print Structure of All-Polymer Solar Cells Impedes Efficiency Print Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

97

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Cells Impedes Efficiency Print Structure of All-Polymer Solar Cells Impedes Efficiency Print Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

98

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Cells Impedes Efficiency Print Structure of All-Polymer Solar Cells Impedes Efficiency Print Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

99

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Cells Impedes Efficiency Print Structure of All-Polymer Solar Cells Impedes Efficiency Print Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

100

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of All-Polymer Solar Cells Impedes Efficiency Print Structure of All-Polymer Solar Cells Impedes Efficiency Print Organic solar cells are made of thin layers of interpenetrating structures from two different conducting organic materials and are increasingly popular because they are both potentially cheaper to make than those currently in use and can be "painted" or printed onto a variety of surfaces, including flexible films made from the same material as most soda bottles. A large community is exploring a number of promising material combinations (polymer/fullerene, polymer/inorganic, all-polymer, and dye-sensitized cells), seeking a deeper understanding of their fundamental structure, operation, and limitations. A team of researchers from North Carolina State University and the UK has now found, through microscopy and resonant scattering and reflectivity studies at ALS Beamlines 6.3.2 and 5.3.2, that the low rate of energy conversion in model all-polymer solar cells is caused by domains that are too large and interfaces that are not sharp enough. This insight will lead to new approaches to all-polymer device technology that will help realize the intrinsic potential of these materials.

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Chemical phenomena in solid-state voltammetry in polymer solvents  

SciTech Connect (OSTI)

This paper, aimed at delineating significant chemical effects in solid-state voltammetry, describes electrochemical oxidations and reductions of electroactive monomer solutes dissolved in and diffusing through rigid and semirigid polymer electrolyte solvents. Sorption of organic monomer vapors into poly(ethylene oxide) films yields polymer solvents whose chemistry is dominated by that of the sorbed monomer as shown by coordination and precipitation effects. The dynamics of plasticization-induced changes in transport rates are quite rapid. Physical diffusion in the polymer solvent in slow enough that electron hopping reactions measurably enhance charge transport rates; the effect was used to estimate a lower limit for the (Co(bpy)/sub 3/)/sup 2+/+/ self-exchange rate constant of 2 /times/ 10/sup 9/ M/sup /minus/1/ s/sup /minus/1/. It is possible to erect polymeric film transport barriers at the electrode/polymer solvent interface and to measure the rate of permeation of monomer complexes from the polymer solvent into the polymer transport barrier film. Polymeric films of Os and Ru polypyridine complexes can be electropolymerized from polymer solutions of the corresponding monomers. Solid-state voltammetry can be extended to other polymer solvents including sulfonated polystyrene, poly(vinyl chloride), Nafion, and poly(acrylamide) gel.

Geng, L.; Reed, R.A.; Kim, M.H.; Wooster, T.T.; Oliver, B.N.; Egekeze, J.; Kennedy, R.T.; Jorgenson, J.W.; Parcher, J.F.; Murray, R.W.

1989-03-01T23:59:59.000Z

102

Sulfonated polyphenylene polymers  

DOE Patents [OSTI]

Improved sulfonated polyphenylene compositions, improved polymer electrolyte membranes and nanocomposites formed there from for use in fuel cells are described herein. The improved compositions, membranes and nanocomposites formed there from overcome limitations of Nafion.RTM. membranes.

Cornelius, Christopher J. (Albuquerque, NM); Fujimoto, Cy H. (Albuquerque, NM); Hickner, Michael A. (Albuquerque, NM)

2007-11-27T23:59:59.000Z

103

Modeling and Optimization of Polymer based Bulk Heterojunction (BH) Solar cell * Biswajit Ray, Pradeep R. Nair, R. Edwin Garca1  

E-Print Network [OSTI]

of the morphology can double the efficiency of BH cells. 1. Introduction Polymer based organic solar cell remains/devices of organic cells to achievable efficiency. The cartoon of a BH solar cell in Fig. 1a illustrates four keyModeling and Optimization of Polymer based Bulk Heterojunction (BH) Solar cell * Biswajit Ray

Alam, Muhammad A.

104

Solvent effects on gravure-printed organic layers of nanoscale thickness for organic solar cells  

Science Journals Connector (OSTI)

The effects of different solvents on the fabrication of organic photovoltaic cells by gravure printing are reported. Polymer bulk heterojunction solar cells were fabricated with ITO/PEDOT: PSS/P3HT ... of solvent...

Jiyeon Lee; Aran Kim; Sung Min Cho; Heeyeop Chae

2012-03-01T23:59:59.000Z

105

Robust Polymer Composite Membranes for Hydrogen Separation |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Robust Polymer Composite Membranes for Hydrogen Separation Robust Polymer Composite Membranes for Hydrogen Separation polymercompositemembranes.pdf More Documents & Publications...

106

Solubility properties of siloxane polymers for chemical sensors  

SciTech Connect (OSTI)

This paper discusses the factors governing the sorption of vapors by organic polymers. The principles have been applied in the past for designing and selecting polymers for acoustic wave sensors; however they apply equally well to sorption of vapors by polymers used on optical chemical sensors. A set of solvation parameters (a table is presented for various organic vapors) have been developed that describe the particular solubility properties of individual solute molecules; they are used in linear solvation energy relationships (LSER) that model the sorption process. LSER coefficients are tabulated for five polysiloxanes; so are individual interaction terms for each of the 5 polymers. Dispersion interactions play a major role in determining overall partition coefficients; the log L{sup 16} (gas-liquid partition coefficient of solute on hexadecane) value of vapors are important in determining overall sorption. For the detection of basic vapors such as organophosphates, a hydrogen-bond acidic polymers will be most effective at sorbing them. Currently, fiber optic sensors are being developed where the cladding serves as a sorbent layer to collect and concentrate analyte vapors, which will be detected and identified spectroscopically. These solubility models will be used to design the polymers for the cladding for particular vapors.

Grate, J.W. [Pacific Northwest Lab., Richland, WA (United States); Abraham, M.H. [University College, London (United Kingdom)

1995-05-01T23:59:59.000Z

107

Electrochromic Polymers for Easily Processed Devices John R. Reynolds,* Avni A. Argun, Irina Schwendeman,  

E-Print Network [OSTI]

Electrochromic Polymers for Easily Processed Devices John R. Reynolds,* Avni A. Argun, Irina for electrochromic applications. These polymers exhibit ease of processability and useful mechanical properties (e.g. flexibility). However, the major strength of these organic-based materials is that their electrochromic

Tanner, David B.

108

Light trapping design for low band-gap polymer solar cells  

E-Print Network [OSTI]

Light trapping design for low band-gap polymer solar cells Stephen Foster1,* and Sajeev John1,2 1 demonstrate numerically a 2-D nanostructured design for light trapping in a low band-gap polymer solar cell, "Light harvesting improvement of organic solar cells with self- enhanced active layer designs," Opt

John, Sajeev

109

High-performance organic solar cells based on a low-bandgap poly-thienothiophene-benzodithiophene polymer and fullerene composite prepared by using the airbrush spray-coating technique  

Science Journals Connector (OSTI)

In the present work, we have demonstrated high-performance organic solar cells with spray coated active layers. The influence ... butyric acid (PC71BM) methyl ester bulk heterojunction solar cells is presented. A...

Palanisamy Kumar; Santhakumar Kannappan…

2013-04-01T23:59:59.000Z

110

Pitch of a polymer cholesteric  

Science Journals Connector (OSTI)

Pitch of a polymer cholesteric ... We report measurements of the cholesteric pitch and twist elastic constant (K22) in monodisperse suspensions of the rodlike virus filamentous bacteriophage fd. ... Cholesteric Pitch of Lyotropic Polymer Liquid Crystals ...

Theo. Odijk

1987-01-01T23:59:59.000Z

111

polymers | OpenEI  

Open Energy Info (EERE)

polymers polymers Dataset Summary Description These data files contain volume, mass, and hardness changes of elastomers and plastics representative exposed to gasoline containing various levels of ethanol. These materials are representative of those used in gasoline fuel storage and dispensing hardware. All values are compared to the original untreated condition. The data sets include results from specimens exposed directly to the fuel liquid and also a set of specimens exposed only to the fuel vapors. Source Mike Kass, Oak Ridge National Laboratory Date Released August 16th, 2012 (2 years ago) Date Updated August 16th, 2012 (2 years ago) Keywords compatibility elastomers ethanol gasoline plastics polymers Data application/vnd.openxmlformats-officedocument.spreadsheetml.sheet icon plastics_dma_results_san.xlsx (xlsx, 4.9 MiB)

112

MHK Technologies/Electroactive Polymer Artificial Muscle EPAM | Open Energy  

Open Energy Info (EERE)

Electroactive Polymer Artificial Muscle EPAM Electroactive Polymer Artificial Muscle EPAM < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Electroactive Polymer Artificial Muscle EPAM.jpg Technology Profile Primary Organization SRI International Technology Resource Click here Wave Technology Type Click here Point Absorber - Floating Technology Description This wave powered generator is unique in that it uses SRI s Electroactive Polymer Artificial Muscle EPAM technology a rubbery material that can generate electricity by simply being stretched and allowed to return to its original shape This artificial muscle technology can generate electricity directly from the motion of waves without the need for complicated and costly hydraulic transmissions that are typically found in other wave power generators

113

DSM INVESTS IN MEDICAL POLYMERS  

Science Journals Connector (OSTI)

DSM INVESTS IN MEDICAL POLYMERS ... AS PART OF ITS SHIFT toward the specialty materials business, DSM will acquire Polymer Technology Group (PTG), a privately held maker of biomedical polymers. ... DSM isn’t disclosing the purchase price other than to say it is about 10 times PTG’s annual earnings. ...

MELODY VOITH

2008-05-05T23:59:59.000Z

114

Electromagnetic field optimization for enhancing photovoltaic efficiency of organic solar cells  

Science Journals Connector (OSTI)

The electromagnetic field distribution inside multilayer organic solar cells composed of interpenetrated networks of conjugated polymers is calculated. By enhancing the...

Simon, Jean-Jacques; Torchio, Philippe; Escoubas, Ludovic; Cathelinaud, Michel; Alem, Salima; Nunzi, Jean-Michel

115

Design of light-trapping microscale-textured surfaces for efficient organic solar cells  

Science Journals Connector (OSTI)

Organic photovoltaic (OPV) cells suffer from low charge carrier mobilities of polymers, which renders it important to achieve complete optical absorption in active layers thinner...

Nalwa, Kanwar S; Chaudhary, Sumit

2010-01-01T23:59:59.000Z

116

Oxidative chemical vapor deposition of conductive polymers for use in novel photovoltaic device architectures  

E-Print Network [OSTI]

The conductive polymer poly(3,4-ethylenedioxythiophene), (PEDOT), deposited via oxidative chemical vapor deposition (oCVD) has been investigated for use in organic electronic devices. The oCVD process as well as the ...

Howden, Rachel M. (Rachel Mary)

2013-01-01T23:59:59.000Z

117

Sedimentation of Knotted Polymers  

E-Print Network [OSTI]

We investigate the sedimentation of knotted polymers by means of stochastic rotation dynamics, a molecular dynamics algorithm that takes hydrodynamics fully into account. We show that the sedimentation coefficient s, related to the terminal velocity of the knotted polymers, increases linearly with the average crossing number n_c of the corresponding ideal knot. To the best of our knowledge, this provides the first direct computational confirmation of this relation, postulated on the basis of experiments in "The effect of ionic conditions on the conformations of supercoiled DNA. I. sedimentation analysis" by Rybenkov et al., for the case of sedimentation. Such a relation was previously shown to hold with simulations for knot electrophoresis. We also show that there is an accurate linear dependence of s on the inverse of the radius of gyration R_g^-1, more specifically with the inverse of the R_g component that is perpendicular to the direction along which the polymer sediments. When the polymer sediments in a slab, the walls affect the results appreciably. However, R_g^-1 remains to a good precision linearly dependent on n_c. Therefore, R_g^-1 is a good measure of a knot's complexity.

Joonas Piili; Davide Marenduzzo; Kimmo Kaski; Riku Linna

2012-12-20T23:59:59.000Z

118

Gel polymer electrolytes for batteries  

DOE Patents [OSTI]

Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains--one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1.times.10.sup.-4 S cm.sup.-1 at 25.degree. C.

Balsara, Nitash Pervez; Eitouni, Hany Basam; Gur, Ilan; Singh, Mohit; Hudson, William

2014-11-18T23:59:59.000Z

119

Peptides and methods against diabetes  

DOE Patents [OSTI]

This invention relates to methods of preventing or reducing the severity of diabetes. In one embodiment, the method involves administering to the individual a peptide having substantially the sequence of a on-conserved region sequence of a T cell receptor present on the surface of T cells mediating diabetes or a fragment thereof, wherein the peptide or fragment is capable of causing an effect on the immune system to regulate the T cells. In particular, the T cell receptor has the V.beta. regional V.beta.6 or V.beta.14. In another embodiment, the method involves gene therapy. The invention also relates to methods of diagnosing diabetes by determining the presence of diabetes predominant T cell receptors.

Albertini, Richard J. (Underhill Center, VT); Falta, Michael T. (Hinesburg, VT)

2000-01-01T23:59:59.000Z

120

Semipermeable polymers and method for producing the same  

DOE Patents [OSTI]

A polyamide membrane including reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst, and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant having one ring. A composite semipermeable membrane including the polyamide membrane on a porous support.

Buschmann, Wayne E

2014-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A Random Loop Model for Long Polymers Manfred Bohn  

E-Print Network [OSTI]

the disorder of loops (i.e., bead-bead interactions) is equivalent to the average over an adequate ensemble organisms, as they are permanently altered by enzymes and protein complexes. We present a new polymer model a general expression for the thermal ensemble average of the squared physical distance between two arbitrary

Heermann, Dieter W.

122

Lightweight polymer concrete composites  

SciTech Connect (OSTI)

Lightweight polymer concrete composites have been developed with excellent insulating properties. The composites consist of lightweight aggregates such as expanded perlites, multicellular glass nodules, or hollow alumina silicate microspheres bound together with unsaturated polyester or epoxy resins. These composites, known as Insulating Polymer Concrete (IPC), have thermal conductivites from 0.09 to 0.19 Btu/h-ft-/sup 0/F. Compressive strengths, dependent upon the aggregates used, range from 1000 to 6000 psi. These materials can be precast or cast-in-place on concrete substrates. Recently, it has been demonstrated that these materials can also be sprayed onto concrete and other substrates. An overlay application of IPC is currently under way as dike insulation at an LNG storage tank facility. The composites have numerous potentials in the construction industry such as insulating building blocks or prefabricated insulating wall panels.

Fontana, J.J.; Steinberg, M.; Reams, W.

1985-08-01T23:59:59.000Z

123

Elegant Way of Strengthening Polymer?Polymer Interface Using Nanoclay  

Science Journals Connector (OSTI)

Elegant Way of Strengthening Polymer?Polymer Interface Using Nanoclay ... In this group, montmorillonite (MMT) nanoclay has been employed in numerous polymer nanocomposite systems because it is environmentally friendly, readily available in large quantities, and its intercalation chemistry has been well studied in comparison with other nanoclays (18-20). ... The detection of this interesting behavior of nanoclays in BIMS rubber has prompted us to initiate a detailed investigation into the tackification mechanism of nanoclay in other general purpose elastomers also. ...

Ganesh C. Basak; K. Dinesh Kumar; Abhijit Bandyopadhyay; Anil K. Bhowmick

2010-10-12T23:59:59.000Z

124

Polymer Crowding and Shape Distributions in Polymer-Nanoparticle Mixtures  

E-Print Network [OSTI]

Macromolecular crowding can influence polymer shapes, which is important for understanding the thermodynamic stability of polymer solutions and the structure and function of biopolymers (proteins, RNA, DNA) under confinement. We explore the influence of nanoparticle crowding on polymer shapes via Monte Carlo simulations and free-volume theory of a coarse-grained model of polymer-nanoparticle mixtures. Exploiting the geometry of random walks, we model polymer coils as effective penetrable ellipsoids, whose shapes fluctuate according to the probability distributions of the eigenvalues of the gyration tensor. Accounting for the entropic cost of a nanoparticle penetrating a larger polymer coil, we compute the crowding-induced shift in the shape distributions, radius of gyration, and asphericity of ideal polymers in a theta solvent. With increased nanoparticle crowding, we find that polymers become more compact (smaller, more spherical), in agreement with predictions of free-volume theory. Our approach can be easily extended to nonideal polymers in good solvents and used to model conformations of biopolymers in crowded environments.

Wei Kang Lim; Alan R. Denton

2014-10-24T23:59:59.000Z

125

Metal-Polymer Interactions in a Polymer/Metal Nanocomposite  

Science Journals Connector (OSTI)

A poly(t-butyl acrylate)/gold nanocomposite sandwich was annealed to induce diffusion of the gold particles, which was monitored using Rutherford backscattering spectrometry. Marker motion experiments were also performed to probe particle and polymer mobilities independently. The experiments revealed that particle mobility was decreased by 2 to 3 orders of magnitude compared with the predictions by Stokes-Einstein theory. Diffusion of polymer molecules through a gold particle layer is decreased by a much smaller extent. These results are attributed to bridging between particles arising from slow exchange kinetics of polymer segments at the polymer/metal interface.

Douglas H. Cole; Kenneth R. Shull; L. E. Rehn; P. Baldo

1997-06-30T23:59:59.000Z

126

Polymer Thermodynamics and Chain Structure Polymers display some similarities and some differences with nano-aggregates.  

E-Print Network [OSTI]

for aggregates and by the late Paul Flory of Stanford for polymer coils. Since the spring constant of a polymer of a polymer coil is largely determined by entropy, an individual polymer coil displays an increasing spring an aggregate in nanomaterials and a polymer coil in Polymer Science. The mass-fractal or minimum dimension

Beaucage, Gregory

127

MST: Organizations: Organic Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adhesive Bonding Adhesive Bonding Composites Encapsulation Materials Characterization Mechanical Testing Molding, Thermoforming, & Compounding Organizations Organic Materials Composite-to-metal adhesive bond Experimental/analytical study of composit-to-metal adhesive bond. The Organic Materials department in the Advanced Manufacturing and Processing Laboratory provides innovative prototype fabrication, full service small lot production, materials technology, processing expertise, and a broad range of organic material characterization and mechanical testing techniques. We encapsulate, we join and bond, we foam, we analyze and image, we build composite structures. We strive to make you, our customers, successful! We partner with you to find the right combination of materials, processing, and fixturing that will result in the highest value

128

Organic Vegetable Organic Vegetable  

E-Print Network [OSTI]

marketed separately from conventionally grown produce in order to be profitably sold. Because of the amount of organic material include compost, Purdue University · Cooperative Extension Service · Knowledge to Go

129

Role of the Na{sup +}/H{sup +} exchanger on the development of diabetes mellitus and its chronic complications  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer NHE protect against intracellular hydrogen overload. Black-Right-Pointing-Pointer NHE protect {beta}-cells against strong acidification. Black-Right-Pointing-Pointer NHE inhibitors improve myocardial ischemia and reperfusion. -- Abstract: Micro- and macrovascular complications are the main cause of morbidity and mortality in diabetes mellitus. The Na{sup +}/H{sup +} exchanger (NHE) is a family of proteins which exchange Na{sup +} for H{sup +} according to their concentration gradients in an electroneutral manner. The exchanger also plays a key role in several other cellular functions including proliferation, differentiation, apoptosis, migration, and cytoskeletal organization. Since not much is known on the relationship between NHE and diabetes mellitus, this review outlines the contribution of NHE to chronic complications of diabetes mellitus, such as diabetic nephropathy; diabetic cardiomyopathy.

Sun, Yan-Ming [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Su, Ying [Department of Endocrinology, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Endocrinology, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Li, Jia; Tian, Ye [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China); Wang, Lan-Feng, E-mail: wlfccu@126.com [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)] [Department of Cardiac Care Unit, The First Affiliated Hospital of Harbin Medical University, Harbin 150001 (China)

2012-10-19T23:59:59.000Z

130

Photochemical Crosslinking Reactions in Polymers.  

E-Print Network [OSTI]

??The post-synthesis modification of polymer properties has very broad applications in industry. It is employed to produce products that are impossible to directly synthesize, modify… (more)

Carbone, Nicholas

2012-01-01T23:59:59.000Z

131

Acoustic emission during polymer crystallization  

Science Journals Connector (OSTI)

... .G.; part support to L.K.) Acoustic Emission, Special Technical Publication 505, ASTM, Philadelphia, 1971; Grabec, I. & Peterlin, A. J. Polymer Sci. ...

A. Galeski; L. Koenczoel; E. Piorkowska; E. Baer

1987-01-01T23:59:59.000Z

132

Photopatterned conjugated polymer electrochromic nanofibers Arvind Kumara  

E-Print Network [OSTI]

Photopatterned conjugated polymer electrochromic nanofibers on paper Arvind Kumara , Chris Asemotaa. Electrochromic nanofibers of conducting polymer (terthiophene) have been deposited over a conventional paper in electrochromic characters. SEM images of the conducting polymer nanofibers together with the cellulose fibers

Otero, Toribio Fernández

133

Organic Solar Cells with Inverted and Tandem Structures  

Science Journals Connector (OSTI)

During the past decade, organic solar cells have attracted great attention due to their ... Although the technologies of small molecule and polymer solar cells have advanced significantly, the efficiency and stab...

De Wei Zhao; Aung Ko Ko Kyaw; Xiao Wei Sun

2011-01-01T23:59:59.000Z

134

Method for separating water soluble organics from a process stream by aqueous biphasic extraction  

DOE Patents [OSTI]

A method for separating water-miscible organic species from a process stream by aqueous biphasic extraction is provided. An aqueous biphase system is generated by contacting a process stream comprised of water, salt, and organic species with an aqueous polymer solution. The organic species transfer from the salt-rich phase to the polymer-rich phase, and the phases are separated. Next, the polymer is recovered from the loaded polymer phase by selectively extracting the polymer into an organic phase at an elevated temperature, while the organic species remain in a substantially salt-free aqueous solution. Alternatively, the polymer is recovered from the loaded polymer by a temperature induced phase separation (cloud point extraction), whereby the polymer and the organic species separate into two distinct solutions. The method for separating water-miscible organic species is applicable to the treatment of industrial wastewater streams, including the extraction and recovery of complexed metal ions from salt solutions, organic contaminants from mineral processing streams, and colorants from spent dye baths.

Chaiko, David J. (Naperville, IL); Mego, William A. (Naperville, IL)

1999-01-01T23:59:59.000Z

135

Hybrid Silicon Nanocone–Polymer Solar Cells  

Science Journals Connector (OSTI)

Hybrid Silicon Nanocone–Polymer Solar Cells ... In this study, we demonstrate a hybrid solar cell composed of Si nanocones and conductive polymer. ...

Sangmoo Jeong; Erik C. Garnett; Shuang Wang; Zongfu Yu; Shanhui Fan; Mark L. Brongersma; Michael D. McGehee; Yi Cui

2012-04-30T23:59:59.000Z

136

Webinar: Hydrogen Production by Polymer Electrolyte Membrane...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton Webinar: Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotligh...

137

Polymers in a Vacuum  

SciTech Connect (OSTI)

In a variety of situations, isolated polymer molecules are found in a vacuum, and here we examine their properties. Angular momentum conservation is shown to significantly alter the average size of a chain and its conservation is only broken slowly by thermal radiation. For an ideal chain, the time autocorrelation for monomer position oscillates with a period proportional to chain length. The oscillations and damping are analyzed in detail. Short-range repulsive interactions suppress oscillations and speed up relaxation, but stretched chains still show damped oscillatory correlations.

Deutsch, J. M. [Department of Physics, University of California, Santa Cruz, California 95064 (United States)

2007-12-07T23:59:59.000Z

138

Vacuum flash evaporated polymer composites  

DOE Patents [OSTI]

A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

Affinito, J.D.; Gross, M.E.

1997-10-28T23:59:59.000Z

139

Materials - Recycling - Polymer Matrix Composites  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Recycling of Polymer Matrix Composites Recycling of Polymer Matrix Composites Polymer matrix composites Carbon fibers recovered from a epoxy-based polymer matrix composite. Carbon fiber reinforced polymer matrix composites (PMCs) are materials with superior strength-to-weight ratios. Finding increased applications in the aerospace industry, PMCs are now being evaluated for possible use in automobile construction. The materialÂ’s high cost, however, along with concerns about whether the PMCs will be recyclable when the vehicles reach the end of their useful lives, are barriers to its widespread use. With funding provided by the U.S. Department of EnergyÂ’s Vehicle Technologies Program (formerly called the Office of Advanced Transportation Technologies), Argonne is developing an efficient and cost-effective

140

Accelerated Characterization of Polymer Properties  

SciTech Connect (OSTI)

This report describes the efforts to develop a suite of microanalysis techniques that can rapidly measure a variety of polymer properties of industrial importance, including thermal, photo-oxidative, and color stability; as well as ductility, viscosity, and mechanical and antistatic properties. Additional goals of the project were to direct the development of these techniques toward simultaneous measurements of multiple polymer samples of small size in real time using non-destructive and/or parallel or rapid sequential measurements, to develop microcompounding techniques for preparing polymers with additives, and to demonstrate that samples prepared in the microcompounder could be analyzed directly or used in rapid off-line measurements. These enabling technologies are the crucial precursors to the development of high-throughput screening (HTS) methodologies for the polymer additives industry whereby the rate of development of new additives and polymer formulations can be greatly accelerated.

R. Wroczynski; l. Brewer; D. Buckley; M. Burrell; R. Potyrailo

2003-07-30T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Fundamental studies of polymer filtration  

SciTech Connect (OSTI)

This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objectives of this project were (1) to develop an enhanced fundamental understanding of the coordination chemistry of hazardous-metal-ion complexation with water-soluble metal-binding polymers, and (2) to exploit this knowledge to develop improved separations for analytical methods, metals processing, and waste treatment. We investigated features of water-soluble metal-binding polymers that affect their binding constants and selectivity for selected transition metal ions. We evaluated backbone polymers using light scattering and ultrafiltration techniques to determine the effect of pH and ionic strength on the molecular volume of the polymers. The backbone polymers were incrementally functionalized with a metal-binding ligand. A procedure and analytical method to determine the absolute level of functionalization was developed and the results correlated with the elemental analysis, viscosity, and molecular size.

Smith, B.F.; Lu, M.T.; Robison, T.W.; Rogers, Y.C.; Wilson, K.V.

1998-12-31T23:59:59.000Z

142

Contracting Polymer with Current  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Contracting Polymer with Current Contracting Polymer with Current Name: Ian Status: student Grade: 9-12 Location: PA Country: USA Date: Summer 2011 Question: Hello and thank you in advance. I have previously read of a material ( a kind of "rubber") that contracts when an electric current is applied. My question is what is this material, how does it work/what is it made of? Thank you very much. Replies: Hi Ian, I believe the material you are referring to is a kind of piezoelectric rubber. Piezoelectric materials (usually they are special types of ceramics or crystals) produce an electrical voltage when compressed of otherwise subjected to stress. They also do the opposite... they slightly expand or contract when a voltage is applied. But the amount they expand or contract is very small indeed. For example, one square meter of the recently discovered piezoelectric rubber materials typically contracts a mere 100 picometers for ever applied volt. Translated into everyday measurements, this means that if you apply a voltage of 1 Volt to a one foot long piece of this rubber, it will only contract less than half a billionth of an inch! Applying 100 volts will cause it to contract just under 50 billionths of an inch!

143

Protect Your Heart Against Diabetes  

E-Print Network [OSTI]

Protect Your Heart Against Diabetes Healthy Hearts, Healthy Homes #12;Read other booklets in the Healthy Hearts, Healthy Homes series: Are You at Risk for Heart Disease? Do You Need To Lose Weight? Do Free Web site: www.nhlbi.nih.gov/health/public/heart/other/sp_package.htm For More Information

Bandettini, Peter A.

144

Soluble polyacetylenic and polyaromatic polymers and method of mking the same  

DOE Patents [OSTI]

A soluble polyene polymer and a method of making the same are disclosed. The polymer is of the class suitable for doping to produce an electrically conductive polymer. The method is generally applicable to acetylenic and aromatic monomers, proven examples of which include acetylene, benzene, anthracene and napthalene. In accordance with the method, the monomer is dissolved in arsenic trifluoride. Arsenic pentafluoride is then introduced into the solution to induce polymerization by what is speculated to be an ionic polymerization reaction. The resulting polymer differs from other polyene polymers in that it is soluble in common organic solvents, and further in that it can be melted without undergoing decomposition, thereby rendering it particularly suitable for processing to form various polymeric articles.

Aldissi, M.; Liepins, R.

1983-12-16T23:59:59.000Z

145

Exciton splitting and carrier transport across the amorphous-silicon/ polymer solar cell interface  

E-Print Network [OSTI]

of bilayer hybrid solar cells to better understand the physics controlling organic-inorganic device of Physics. DOI: 10.1063/1.2408641 Hybrid organic-inorganic solar cells combine the pro- cessabilityExciton splitting and carrier transport across the amorphous-silicon/ polymer solar cell interface

McGehee, Michael

146

Conjugated polymer electroluminescence: technical aspects from basic devices to commercial products  

Science Journals Connector (OSTI)

...in the design of the active semi- conductors...bility of the organic materials in an LEP device, are...morphological effects in the active organic layers are par...matrix placed under the cathode can dramatically increase...the polymer layers, materials requirements are very...

1997-01-01T23:59:59.000Z

147

Carbon nanotube-polymer composite actuators  

DOE Patents [OSTI]

The present invention discloses a carbon nanotube (SWNT)-polymer composite actuator and method to make such actuator. A series of uniform composites was prepared by dispersing purified single wall nanotubes with varying weight percents into a polymer matrix, followed by solution casting. The resulting nanotube-polymer composite was then successfully used to form a nanotube polymer actuator.

Gennett, Thomas (Denver, CO); Raffaelle, Ryne P. (Honeoye Falls, NY); Landi, Brian J. (Rochester, NY); Heben, Michael J. (Denver, CO)

2008-04-22T23:59:59.000Z

148

The workshop on conductive polymers: Final report  

SciTech Connect (OSTI)

Reports are made by groups on: polyacetylene, polyphenylene, polyaniline, and related systems; molecular, crystallographic, and defect structures in conducting polymers; heterocyclic polymers; synthesis of new and improved conducting polymers; future applications possibilities for conducting polymers; and challenges for improved understanding of properties. (DLC)

Not Available

1985-01-01T23:59:59.000Z

149

Science Organizations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organizations Science Organizations National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place...

150

Thermodynamics of tubelike flexible polymers  

E-Print Network [OSTI]

In this work we present the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling methods to simulate small bead-stick polymer models with Lennard-Jones interaction among non-bonded monomers. We analyze energetic fluctuations and structural quantities to classify conformational pseudophases. We find that the tube thickness influences the thermodynamic behavior of simple tubelike polymers significantly, i.e., for given temperature, the formation of secondary structures strongly depends on the tube thickness.

Thomas Vogel; Thomas Neuhaus; Michael Bachmann; Wolfhard Janke

2009-07-17T23:59:59.000Z

151

Thermodynamics of tubelike flexible polymers  

Science Journals Connector (OSTI)

In this work, we discuss the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling methods to simulate small bead-stick polymer models with Lennard-Jones interaction among nonbonded monomers. We analyze energetic fluctuations and structural quantities to classify conformational pseudophases. We find that the tube thickness influences the thermodynamic behavior of simple tubelike polymers significantly, i.e., for a given temperature, the formation of secondary structures strongly depends on the tube thickness.

Thomas Vogel; Thomas Neuhaus; Michael Bachmann; Wolfhard Janke

2009-07-16T23:59:59.000Z

152

Self-Assembling Efficient Organic Electronics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Assembling Efficient Organic Electronics Self-Assembling Efficient Organic Electronics Speaker(s): Rachel Segalman Date: April 26, 2005 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Venkat Srinivasan In the last decade, the use of self-assembling block copolymers to nanopattern substrates and template synthesis has made incredible gains as a primary step towards the fabrication of nanodevices. Many studies have demonstrated a sophisticated level of control over the self-assembling, coil-type polymer systems to produce long range order. The knowledge now exists to begin to pattern polymers with a much higher degree of complexity and inherent functionality. It is apparent, for instance, that the mesostructure of conductive polymers impacts their luminescence and photovoltaic efficiency. For instance, block copolymers made from

153

Metal catalyzed synthesis of hyperbranched ethylene and/or .alpha.-olefin polymers  

DOE Patents [OSTI]

Oily hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin, and a method for their synthesis, are disclosed. The polymers have non-regular microstructures and are characterized by a ratio ({character pullout})of methyl hydrogens centered around 0.85 ppm on the 1H-NMR spectra of the polymers relative to total aliphatic hydrogens of from about 0.40 to about 0.65 for polymers derived from ethylene or butene, and a ratio ({character pullout})of from greater than 0.50 to about 0.65 for polymers derived from propylene. A method for grafting hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin onto aromatic rings in organic molecules and polymers, and the resulting grafted materials, are also disclosed. The hyperbranched polymers and grafted materials are useful, for example, as lubricants and lubricant additives.

Sen, Ayusman (State College, PA); Kim, Jang Sub (State College, PA); Pawlow, James H. (Gainesville, FL); Murtuza, Shahid (State College, PA); Kacker, Smita (Annandale, NJ); Wojcinski, III, Louis M. (State College, PA)

2001-01-01T23:59:59.000Z

154

Polymer-cement geothermal-well-completion materials. Final report  

SciTech Connect (OSTI)

A program to develop high-temperature polymer cements was performed. Several formulations based on organic and semi-inorganic binders were evaluated on the basis of mechanical and thermal stability, and thickening time. Two optimized systems exhibited properties exceeding those required for use in geothermal wells. Both systems were selected for continued evaluation at the National Bureau of Standards and contingent upon the results, for field testing in geothermal wells.

Zeldin, A.N.; Kukacka, L.E.

1980-07-01T23:59:59.000Z

155

Study of surface enhanced resonant Raman spectroscopy of chromophores on unaggregated plasmonically active nanoparticles / Surface-enhanced Raman study of the interaction of the PEDOT:PSS and P3HT/PCBM components of organic polymer solar cells with plasmonically active nanoparticles  

E-Print Network [OSTI]

Light Collection in Organic Solar Cells. Appl. Phys. Lett.Performance of Organic Solar Cells using Electrodeposited AgHybrid Plasmonic Organic Solar Cells with Ag Nanoparticles.

Stavytska-Barba, Marina Valeriyivna

2012-01-01T23:59:59.000Z

156

A conjugated polymer plastic gel  

E-Print Network [OSTI]

We present a gel route to process highly oriented conjugated polymer films and fibers. The incorporation of hexafluoroisopropanol, a strong and stable dipolar group, to the polythiophene backbone enhances the solubility ...

Alcazar Jorba, Daniel

2008-01-01T23:59:59.000Z

157

Polymers For Advanced Lithium Batteries  

Broader source: Energy.gov (indexed) [DOE]

Accomplishments 1 m SEM of cathode LiFePO 4 +Binder (5050) Nothing else, no optimization Li metal (anode) Al current collector Polymer electrolyte membrane (S-EO-S)...

158

Polymers, Fractals, and Ceramic Materials  

Science Journals Connector (OSTI)

...application primarily as optical coatings and aerogels. Aerogels (1...4) Gelation //Polymer x Coating_rn Film Monomer Aggregation...Sintering.......... Aerogel Monolith Fig. 1. Ceramic...desired for index-matched coatings, then base-catalyzed materials...

DALE W. SCHAEFER

1989-02-24T23:59:59.000Z

159

Layered plasma polymer composite membranes  

DOE Patents [OSTI]

Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is [>=]2 and is the number of selective layers. 2 figs.

Babcock, W.C.

1994-10-11T23:59:59.000Z

160

Characterization of macro-length conducting polymers and the development of a conducting polymer rotary motor  

E-Print Network [OSTI]

Conducting polymers are a subset of materials within the electroactive polymer class that exhibit active mechanical deformations. These deformations induce stresses and strains that allow for conducting polymers to be used ...

Schmid, Bryan D. (Bryan David), 1981-

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Thermal stability of organic solar cells: the decay in photocurrent linked with changes in active layer morphology  

Science Journals Connector (OSTI)

Nowadays bulk heterojunction polymer:fullerene (PCBM) solar cells reach efficiencies of 5% through the ... . One of the general bottlenecks of organic solar cells is their poor stability. Organic solar cells have...

S. Bertho; I. Haeldermans; A. Swinnen…

2008-01-01T23:59:59.000Z

162

Modulation of Nociception in Painful Diabetic Neuropathy  

E-Print Network [OSTI]

xiv List of Figures Chapter 1 Introduction Figure 1 Fiber types involved in conveying sensory information from the periphery to the central nervous system 16 Figure 2 Overview of purinergic signaling 25 Figure 3 Signaling downstream... glucose levels and/or hemoglobin A1c levels [2], placing them at increased risk for developing diabetes. Direct and indirect medical costs related to the care and treatment of diabetes exceed $174 billion annually [2]. Diabetes is a complex metabolic...

Katz, Natalie

2014-05-31T23:59:59.000Z

163

Viscosity of Ring Polymer Melts  

Science Journals Connector (OSTI)

Viscosity of Ring Polymer Melts ... The ratio of the zero-shear viscosities of linear polymer melts ?0,linear to their ring counterparts ?0,ring at isofrictional conditions is discussed as a function of the number of entanglements Z. ... For this reason we have determined the viscosities by fitting the complex viscosity curves with different methods to obtain reliable estimates and error bars (see Supporting Information). ...

Rossana Pasquino; Thodoris C. Vasilakopoulos; Youn Cheol Jeong; Hyojoon Lee; Simon Rogers; George Sakellariou; Jürgen Allgaier; Atsushi Takano; Ana R. Brás; Taihyun Chang; Sebastian Gooßen; Wim Pyckhout-Hintzen; Andreas Wischnewski; Nikos Hadjichristidis; Dieter Richter; Michael Rubinstein; Dimitris Vlassopoulos

2013-09-17T23:59:59.000Z

164

High cation transport polymer electrolyte  

DOE Patents [OSTI]

A solid state ion conducting electrolyte and a battery incorporating same. The electrolyte includes a polymer matrix with an alkali metal salt dissolved therein, the salt having an anion with a long or branched chain having not less than 5 carbon or silicon atoms therein. The polymer is preferably a polyether and the salt anion is preferably an alkyl or silyl moiety of from 5 to about 150 carbon/silicon atoms.

Gerald, II, Rex E. (Brookfield, IL); Rathke, Jerome W. (Homer Glen, IL); Klingler, Robert J. (Westmont, IL)

2007-06-05T23:59:59.000Z

165

Organization | Department of Energy  

Energy Savers [EERE]

About Us Organization Organization Organization Printable PDF News & Blog CIO Leadership Organization Contact Us...

166

Organization | Department of Energy  

Office of Environmental Management (EM)

About Us Organization Organization Organization News Leadership Organization History Careers Contact Us...

167

High Temperature Polymer Membrane Development at Argonne National...  

Broader source: Energy.gov (indexed) [DOE]

Polymer Membrane Development at Argonne National Laboratory High Temperature Polymer Membrane Development at Argonne National Laboratory Summary of ANL's high temperature polymer...

168

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

169

Methods and systems for chemoautotrophic production of organic compounds  

DOE Patents [OSTI]

The present disclosure identifies pathways, mechanisms, systems and methods to confer chemoautotrophic production of carbon-based products of interest, such as sugars, alcohols, chemicals, amino acids, polymers, fatty acids and their derivatives, hydrocarbons, isoprenoids, and intermediates thereof, in organisms such that these organisms efficiently convert inorganic carbon to organic carbon-based products of interest using inorganic energy, such as formate, and in particular the use of organisms for the commercial production of various carbon-based products of interest.

Fischer, Curt R.; Che, Austin J.; Shetty, Reshma P.; Kelly, Jason R.

2013-01-08T23:59:59.000Z

170

Remission and regression of diabetic nephropathy  

Science Journals Connector (OSTI)

Diabetic kidney disease is considered to be an irreversible and inexorable progressive disease. Therefore, prevention of development of ESRD is extremely important. Animal studies have demonstrated that regres...

Peter Hovind MD; Lise Tarnow MD; DMSc…

2004-01-01T23:59:59.000Z

171

Folded reflective tandem polymer solar cell doubles efficiency  

Science Journals Connector (OSTI)

Conjugated polymers are promising materials for the production of inexpensive and flexible photovoltaic cells. Organic materials display tunable optical absorption within a large spectral range. This enables the construction of organic tandem photovoltaic cells. The authors here demonstrate a reflective tandem cell where single cells are reflecting the nonabsorbed light upon another adjacent cell. By folding two planar but spectrally different cells toward each other spectral broadening and light trapping are combined to give an enhancement of power conversion efficiency of a factor of 1.8 ± 0.3 .

Kristofer Tvingstedt; Viktor Andersson; Fengling Zhang; Olle Inganäs

2007-01-01T23:59:59.000Z

172

Interfacial Widths of Conjugated Polymer Bilayers  

SciTech Connect (OSTI)

The interfaces of conjugated polyelectrolyte (CPE)/poly[2-methoxy-5-(2{prime}-ethylhexyloxy)-p-phenylene vinylene] (MEH-PPV) bilayers cast from differential solvents are shown by resonant soft X-ray reflectivity (RSoXR) to be very smooth and sharp. The chemical interdiffusion due to casting is limited to less than 0.6 nm, and the interface created is thus nearly 'molecularly' sharp. These results demonstrate for the first time and with high precision that the nonpolar MEH-PPV layer is not much disturbed by casting the CPE layer from a polar solvent. A baseline is established for understanding the role of interfacial structure in determining the performance of CPE-based polymer light-emitting diodes. More broadly, we anticipate further applications of RSoXR as an important tool in achieving a deeper understanding of other multilayer organic optoelectronic devices, including multilayer photovoltaic devices.

NCSU; UC Berkeley; UCSB; Advanced Light Source; Garcia, Andres; Yan, Hongping; Sohn, Karen E.; Hexemer, Alexander; Nguyen, Thuc-Quyen; Bazan, Guillermo C.; Kramer, Edward J.; Ade, Harald

2009-08-13T23:59:59.000Z

173

SUPER HARD SURFACED POLYMERS  

SciTech Connect (OSTI)

High energy ion beam surface treatments were applied to a selected group of polymers. Of the six materials in the present study, four were thermoplastics (polycarbonate, polyethylene, polyethylene terephthalate, and polystyrene) and two were thermosets (epoxy and polyimide). The particular epoxy evaluated in this work is one of the resins used in formulating fiber reinforced composites for military helicopter blades. Measures of mechanical properties of the near surface regions were obtained by nanoindentation hardness and pin on disk wear. Attempts were also made to measure erosion resistance by particle impact. All materials were hardness tested. Pristine materials were very soft, having values in the range of approximately 0.1 to 0.5 GPa. Ion beam treatment increased hardness by up to 50 times compared to untreated materials. For reference, all materials were hardened to values higher than those typical of stainless steels. Wear tests were carried out on three of the materials, PET, PI and epoxy. On the ion beam treated epoxy no wear could be detected, whereas the untreated material showed significant wear.

Mansur, Louis K [ORNL] [ORNL; Bhattacharya, R [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Blau, Peter Julian [ORNL] [ORNL; Clemons, Art [ORNL] [ORNL; Eberle, Cliff [ORNL] [ORNL; Evans, H B [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Janke, Christopher James [ORNL] [ORNL; Jolly, Brian C [ORNL] [ORNL; Lee, E H [Consultant, Milpitas, CA] [Consultant, Milpitas, CA; Leonard, Keith J [ORNL] [ORNL; Trejo, Rosa M [ORNL] [ORNL; Rivard, John D [ORNL] [ORNL

2010-01-01T23:59:59.000Z

174

Materials from Renewable Resources Most synthetic organic materials and polymers  

E-Print Network [OSTI]

.sukumaran@che Conceptualize ecofriendly chemicals, solvents, surfactants, and liquid solutions for chemical and industrial processeschemical and industrial processes Play a pivotal role in benign ways of producing chemicals and solvents research partners Create a sustainable economy using green chemistry Impressum Herausgeber: Universität

Schubart, Christoph

175

Functional Polymer Architectures for Solution Processed Organic Light Emitting Diodes  

E-Print Network [OSTI]

through formation of the tetrazole from 4-bromobenzonitrile13 5-(4-Bromophenyl)tetrazole, 7 2-(4-tert- Butylphenyl)-5-(

Poulsen, Daniel Andrew

2010-01-01T23:59:59.000Z

176

New N-Type Polymers for Organic Photovoltaics: Cooperative Research...  

Office of Scientific and Technical Information (OSTI)

by Pat Corkery, NREL 16560, photo by Dennis Schroeder, NREL 17613, photo by Dean Armstrong, NREL 17436, photo by Pat Corkery, NREL 17721. NREL prints on paper that contains...

177

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

power conversion efficiency (PCE = ?) of the solar cell ischarge extraction and PCE. For a zero order approximation,seen success in OPVs with PCE between 5-7.4%. 5,22,23 Figure

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

178

Structure-Function Relationships in Semiconducting Polymers for Organic Photovoltaics  

E-Print Network [OSTI]

Photovoltaic Cell .the materials, all photovoltaic cells operate on the basicEquation 1.2) For photovoltaic cells of all kinds and from

Kavulak, David Fredric Joel

2010-01-01T23:59:59.000Z

179

Functional Polymer Architectures for Solution Processed Organic Light Emitting Diodes  

E-Print Network [OSTI]

for high energy blue phosphorescent materials. Therefore,this high triplet energy block copolymer as host material, afind materials with sufficiently high triplet energy to be

Poulsen, Daniel Andrew

2010-01-01T23:59:59.000Z

180

Multi-Walled Carbon Nanotubes-Modified Polymer Organic Photovoltaics.  

E-Print Network [OSTI]

??Since the carbon nanotubes were first discovered by Iijima in 1991, CNTs have been the focus of intense research by many groups. Nearly 7000 papers… (more)

Chen, Tzu-Fan

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Gain properties of dye-doped polymer thin films  

E-Print Network [OSTI]

The demonstration of an electrically pumped organic laser remains a major issue of organic optoelectronics for several decades. Nowadays, hybrid pumping seems a promising compromise where the organic material is optically pumped by an electrically pumped inorganic device on chip. This technical solution requires therefore an optimization of the organic gain medium under optical pumping. Here, we report a detailed study of gain features of dye-doped polymer thin films, in particular we introduce the gain efficiency $K$, in order to facilitate comparison between material and experimental conditions. First, we measure the bulk gain by the means of a pump-probe setup, and then present in details several factors which modify the actual gain of the layer, namely the confinement factor, the pump polarization, the molecular anisotropy, and the re-absorption. The usual model to evaluate the gain leads to an overestimation by more than one order of magnitude, which stresses the importance to design the devices accordin...

Gozhyk, I; Rabbani, H; Djellali, N; Forget, S; Chenais, S; Ulysse, C; Brosseau, A; Gauvin, S; Zyss, J; Lebental, M

2014-01-01T23:59:59.000Z

182

Selective separation of Eu{sup 3+} using polymer-enhanced ultrafiltration  

SciTech Connect (OSTI)

A process to selectively remove {sup 241}Am from liquid radioactive waste was investigated as an actinide separation method applicable to Hanford and other waste sites. The experimental procedures involved removal of Eu, a nonradioactive surrogate for Am, from aqueous solutions at pH 5 using organic polymers in conjunction with ultrafiltration. Commercially available polyacrylic acid (60,000 MW) and Pacific Northwest Laboratory`s (PNL) synthesized E3 copolymer ({approximately}10,000 MW) were tested. Test solutions containing 10 {mu}g/mL of Eu were dosed vath each polymer at various concentrations in order to bind Eu (i.e., by complexation and/or cation exchange) for subsequent rejection by an ultrafiltration coupon. Test solutions were filtered with and without polymer to determine if enhanced Eu separation could be achieved from polymer treatment. Both polymers significantly increased Eu removal. Optimum concentrations were 20 {mu}g/mL of polyacrylic acid and 100 {mu}g/mL of E3 for 100% Eu rejection by the Amicon PM10 membrane at 55 psi. In addition to enhancement of removal, the polymers selectively bound Eu over Na, suggesting that selective separation of Eu was possible. This suggests that polymer-enhanced ultrafiltration is a potential process for separation of {sup 241}Am from Hanford tank waste, further investigation of binding agents and membranes effective under very alkaline and high ionic strength is warranted. This process also has potential applications for selective separation of toxic metals from industrial process streams.

Norton, M.V.

1994-03-01T23:59:59.000Z

183

Process for hardening the surface of polymers  

DOE Patents [OSTI]

Hard surfaced polymers and the method for making them is generally described. Polymers are subjected to simultaneous multiple ion beam bombardment, that results in a hardening of the surface and improved wear resistance. 1 figure.

Mansur, L.K.; Lee, E.H.

1992-07-14T23:59:59.000Z

184

Mechanics of Polymer?Clay Nanocomposites  

Science Journals Connector (OSTI)

The mechanics of nanocomposites is critical in the design of nanomaterials with desirable properties. In this paper, the mechanics of polymer?clay nanocomposites is studied using a designed polymer and solution nanocomposite synthesis. A copolymer latex, ...

YuanQiao Rao; John M. Pochan

2006-12-16T23:59:59.000Z

185

Process to produce lithium-polymer batteries  

DOE Patents [OSTI]

A polymer bonded sheet product is described suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance. 1 fig.

MacFadden, K.O.

1998-06-30T23:59:59.000Z

186

Transports of Polymer Nanomedicine in the Environment  

E-Print Network [OSTI]

With increasing production and commercial use of polymer nanomedicine and a lack of regulation to govern their disposal, polymer nanomedicine may enter into soils and ultimately into ground water system. In this dissertation, adsorption of polymeric...

Zhang, Ming

2013-11-14T23:59:59.000Z

187

Unwinding relaxation dynamics of polymers  

E-Print Network [OSTI]

The relaxation dynamics of a polymer wound around a fixed obstacle constitutes a fundamental instance of polymer with twist and torque and it is of relevance also for DNA denaturation dynamics. We investigate it by simulations and Langevin equation analysis. The latter predicts a relaxation time scaling as a power of the polymer length times a logarithmic correction related to the equilibrium fluctuations of the winding angle. The numerical data support this result and show that at short times the winding angle decreases as a power-law. This is also in agreement with the Langevin equation provided a winding-dependent friction is used, suggesting that such reduced description of the system captures the basic features of the problem.

Jean-Charles Walter; Marco Baiesi; Gerard Barkema; Enrico Carlon

2013-01-13T23:59:59.000Z

188

Nanoparticle Diffusion in Polymer Nanocomposites  

Science Journals Connector (OSTI)

Large-scale molecular dynamics simulations show that nanoparticle (NP) diffusivity in weakly interacting mixtures of NPs and polymer melts has two very different classes of behavior depending on their size. NP relaxation times and their diffusivities are completely described by the local, Rouse dynamics of the polymer chains for NPs smaller than the polymer entanglement mesh size. The motion of larger NPs, which are comparable to the entanglement mesh size, is significantly slowed by chain entanglements, and is not describable by the Stokes-Einstein relationship. Our results are in essentially quantitative agreement with a force-level generalized Langevin equation theory for all the NP sizes and chain lengths explored, and imply that for these lightly entangled systems, activated NP hopping is not important.

Jagannathan T. Kalathi; Umi Yamamoto; Kenneth S. Schweizer; Gary S. Grest; Sanat K. Kumar

2014-03-12T23:59:59.000Z

189

Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes  

DOE Patents [OSTI]

A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

2003-06-03T23:59:59.000Z

190

MHK Technologies/WaveBlanket PolymerMembrane | Open Energy Information  

Open Energy Info (EERE)

WaveBlanket PolymerMembrane WaveBlanket PolymerMembrane < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage WaveBlanket PolymerMembrane.jpg Technology Profile Primary Organization Wind Waves and Sun Technology Resource Click here Wave Technology Type Click here Oscillating Wave Surge Converter Technology Readiness Level Click here TRL 1 3 Discovery Concept Def Early Stage Dev Design Engineering Technology Description WaveBlanket could be called the accordion of the sea Poetically speaking It is simply a bellows played upon by the swells of the ocean WaveBlanket is a flexible polymer membrane which uses air pressure rather than steel to achieve its lateral strength and as a result produces about 1000 times more energy per unit of mass than rigid green energy designs

191

Gamification to Improve Adherence to Diabeteic Treatment in Saudi Arabia  

E-Print Network [OSTI]

Gamification to Improve Adherence to Diabeteic Treatment in Saudi Arabia Alaa Abdullah Al, proposes the first Arabic system for managing diabetes using gamification. Keywords-component; Diabetes; Gamification; Self-Care; e- Healthcare I. INTRODUCTION Diabetes mellitus is one of the most common illnesses

192

“Coffee-ring” patterns of polymer droplets  

Science Journals Connector (OSTI)

Dried droplets of polymer solutions carries the self-assembly behavior of polymer molecules by forming various patterns. Pattern formation is a consequence of deposition of molecules depending on motion of the contact line during the drying process. The contact line motion depends on initial polymer concentrations and hence entanglement. Thus depending on entanglement the patterns represent the ‘particle’ like or ‘collective’ behavior of polymer molecules.

Nupur Biswas; Alokmay Datta

2013-01-01T23:59:59.000Z

193

Post polymerization cure shape memory polymers  

DOE Patents [OSTI]

This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

Wilson, Thomas S; Hearon, Michael Keith; Bearinger, Jane P

2014-11-11T23:59:59.000Z

194

Polymer combustion: effects of flame emissivity  

Science Journals Connector (OSTI)

...gas phase. Polymer combustion chemistry is modelled...investigating polymer combustion it has proven advantageous...properties and treat the heat flux from the ignition...luminous flames from hydrocarbon fuels, it is common...A (1999) Polymer combustion: effects of flame emissivity...

1999-01-01T23:59:59.000Z

195

Organosiloxane-grafted natural polymer coatings  

DOE Patents [OSTI]

A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.

Sugama, Toshifumi (Wading River, NY)

1998-01-01T23:59:59.000Z

196

Transport characteristics across drum filter vents and polymer bags  

SciTech Connect (OSTI)

The rate at which hydrogen (H {sub 2}) or a volatile organic compound (VOC) exits a layer of confinement in a vented waste drum is proportional to the concentration difference across the layer. The proportionality constant is the gas transport characteristic. A series of transport experiments were conducted to determine H{sub 2} and VOC transport characteristics across different drum filter vents and polymer bags. This report reviews the methods and results of past investigators in defining transport characteristics across filter vents and polymer bags, describes the apparatus and procedures used in these experiments, compares the reported and estimated transport characteristics with earlier results, and discusses the impact of changing the transport characteristic values used in model calculations.

Liekhus, K.J.

1994-08-01T23:59:59.000Z

197

Bimolecular Crystals of Fullerenes in Conjugated Polymers and the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimolecular Crystals of Fullerenes in Conjugated Polymers and the Bimolecular Crystals of Fullerenes in Conjugated Polymers and the Implications of Molecular Mixing for Solar Cells figure 1 Figure 1: Diffraction data for pBTTT:PC[71]BM blends of varying weight ratio that have been annealed at 185 °C for 10 minutes. The annealing took place at the glass transition temperature of pBTTT in order to increase the molecular order. (a) 2D GIXS of pure pBTTT. (b) 2D GIXS of 1:1 pBTTT:PC[71]BM blend. (c) High resolution specular x-ray diffraction for a series of pBTTT:PC[71]BM blends. This confirms the expansion perpendicular to the substrate. Organic photovoltaics have recently attracted tremendous attention in industry and academia since they offer the potential to significantly change energy production by drastically reducing the manufacturing cost for

198

Author's personal copy Pyroelectric energy converter using co-polymer P(VDF-TrFE) and Olsen cycle  

E-Print Network [OSTI]

into electricity by means of an electrical generator or dynamo. Alternatively, organic Rankine cycles use organicAuthor's personal copy Pyroelectric energy converter using co-polymer P(VDF-TrFE) and Olsen cycle heat harvesting Ferroelectric Olsen cycle a b s t r a c t This study was concerned with designing

Pilon, Laurent

199

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Print Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However, even though this class of devices is finding a growing number of applications, electronic processes in organic materials are still not well understood. A group of researchers from the University of California and the ALS has succeeded in probing the intrinsic electronic properties of the charge carriers in organic FETs using infrared spectromicroscopy. The results of their study could help in the future development of sensors, large-area displays, and other plastic electronic components.

200

5th International Conference on Polymer Batteries and Fuel Cells - PBFC-5 -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home Home Conference Goals Organizers Sponsors Speakers Program Posters Registration Hotels Breakfast/Dinner Options Maps and Transportation to Argonne Bus Schedule Contact Us Chicago skyline Battery research Argonne APS 5th INTERNATIONAL CONFERENCE ON POLYMER BATTERIES AND FUEL CELLS (PBFC-5) PBFC 2011 August 1 - 5, 2011 Advanced Photon Source, Argonne National Laboratory Argonne, Illinois USA About the Conference It is a great pleasure for the organizing committee of the 5th International Conference on Polymer Batteries and Fuel Cells (PBFC-5, PBFC-2011) to invite all who are interested in materials for and systems based on lithium polymer, lithium-ion, metal-air, and flow batteries, and proton-exchange membrane and alkaline-exchange membrane fuel cells to attend PBFC-5. Read more.

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Selective sorption of PCBs by low-cost polymers and application to soil washing processes  

SciTech Connect (OSTI)

Surfactant-assisted soil washing and soil flushing processes have shown to be a promising soil decontamination method. In these and other remediation technologies that employ surfactants to mobilize organic contaminants, large volumes of contaminated aqueous solutions are generated. An efficient process to selectively concentrate the organic contaminant from the aqueous surfactant solution, thereby allowing the recycle of the surfactant, is considered essential for cost-effective application of these remediation methods. To this end, a process was developed wherein commercial, low-cost polymers are used to selectively sorb PCBs and petroleum oils from aqueous surfactant solutions. Sorption isotherms and sorption rates were determined for a large number of polymer sorbents and several significant structure-property relationships were observed. Two classes of polymers, polyester elastomers and carbon-filled elastomer rubbers (e.g., recycled rubber tire), were found to perform superiorly in this application and a successful pilot-scale demonstration of the process was conducted.

Sivavec, T.M.; Webb, J.L.; Gascoyne, D.G. [GE Corporate Research and Development, Schenectady, NY (United States)

1996-10-01T23:59:59.000Z

202

Enhanced photophysics of conjugated polymers  

DOE Patents [OSTI]

A particulate fluorescent conjugated polymer surfactant complex and method of making and using same. The particles are between about 15 and about 50 nm and when formed from a lipsome surfactant have a charge density similar to DNA and are strongly absorbed by cancer cells.

Chen, Liaohai (Darien, IL)

2007-06-12T23:59:59.000Z

203

POLYMER FEEDSTOCK MADE FROM BIOMASS  

Science Journals Connector (OSTI)

Method effectively converts fructose to 5-hydroxymethylfurfural ... Researchers at the University of Wisconsin, Madison, have developed a selective method for converting fructose to 5-hydroxymethylfurfural (HMF), a compound that could serve as a key intermediate for manufacturing polymers, pharmaceuticals, and other valuable products ( Science 2006, 312 , 1933). ...

2006-07-03T23:59:59.000Z

204

Friction between Ring Polymer Brushes  

E-Print Network [OSTI]

Friction between ring-polymer brushes at melt densities sliding past each other are studied using extensive course-grained molecular dynamics simulations and scaling arguments, and the results are compared to the friction between linear-polymer brushes. We show that for a velocity range spanning over three decades, the frictional forces measured for ring-polymer brushes are half the corresponding friction in case of linear brushes. In the linear-force regime, the weak inter-digitation of two ring brushes compared to linear brushes also leads to a lower number of binary collisions between the monomers of opposing brushes. At high velocities, where the thickness of the inter-digitation layer between two opposing brushes is on the order monomer size regardless of brush topology, stretched segments of ring polymers take a double-stranded conformation. As a result, monomers of the double-stranded segments collide less with the monomers of the opposing ring brush even though a similar number of monomers occupies the inter-digitation layer for ring and linear-brush bilayers. The numerical data obtained from our simulations is consistent with the proposed scaling analysis. Conformation-dependent frictional reduction observed in ring brushes can have important consequences in non-equilibrium bulk systems.

A. Erbas; J. Paturej

2015-01-07T23:59:59.000Z

205

Organic Photovoltaics  

Science Journals Connector (OSTI)

Satisfying the world's growing demand for energy is an urgent societal challenge. Organic photovoltaics holds promise as a cost-efficient and environmentally friendly solution.

Kippelen, Bernard

2007-01-01T23:59:59.000Z

206

17 - Organic solar cells (OSCs)  

Science Journals Connector (OSTI)

Abstract The organic solar cell (OSC) is the only solar cell technology that fully addresses the challenges of manufacturing on a scale corresponding to an energy production capacity of 1 \\{GWpeak\\} per day based solely on abundant elements. This ability arises through the use of printing techniques and photoactive layers comprising carbon-based conjugated polymer materials. The technology is briefly reviewed in this chapter by describing the common device structures and materials. The second half of the chapter gives an overview on suitable roll-to-roll (R2R) processing techniques for the fabrication of OSCs. Finally some demonstration projects and future trends are illustrated.

M. Hösel; D. Angmo; F.C. Krebs

2013-01-01T23:59:59.000Z

207

Oxidative and initiated chemical vapor deposition for application to organic electronics  

E-Print Network [OSTI]

Since the first discovery of polymeric conductors in 1977, the research area of "organic electronics" has grown dramatically. However, methods for forming thin films comprised solely of conductive polymers are limited by ...

Im, Sung Gap

2009-01-01T23:59:59.000Z

208

Analytical theory of polymer-network-mediated interaction between colloidal particles  

Science Journals Connector (OSTI)

...organic-inorganic hybrid solar cells. Further...for renewable energy production. For...unclear, a major obstacle to its understanding...materials and energy (e.g., super-rigid...rubbers, composite solar cells, etc...applications, and energy-related materials. 1 Heinrich...nanorod-polymer solar cells . Science...

Lorenzo Di Michele; Alessio Zaccone; Erika Eiser

2012-01-01T23:59:59.000Z

209

Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties  

SciTech Connect (OSTI)

Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li, E-mail: wangxiuli@bhu.edu.cn

2013-09-15T23:59:59.000Z

210

Arginine metabolism in enterocytes of diabetic rats  

E-Print Network [OSTI]

Diabetic rats and patients exhibit decreased plasma arginine concentrations. Arginine is important in numerous cellular pathways, including the synthesis of nitric oxide and the release of insulin from pancreatic ? cells. At present, little...

Morrow, Natalie Anne

2012-06-07T23:59:59.000Z

211

Understanding Why Some Women with a History of Gestational Diabetes Do Not Get Tested for Diabetes  

Science Journals Connector (OSTI)

AbstractBackground The proportion of women with previous gestational diabetes mellitus (GDM) receiving postpartum diabetes testing is far less than desired. Even in health care systems with high testing rates, some women remain untested. We explored what helps and what hinders women to obtain recommended testing. Methods In this mixed methods study, we recruited 139 patients with a history of GDM in their most recent pregnancy (6 months to 4.5 years before study enrollment) from a delivery system that had instituted a quality improvement program to increase postpartum diabetes testing rates. We determined whether they had received a postpartum diabetes test according to American Diabetes Association guidelines. Using survey data, we ran logistic regression models to assess correlates of testing status, and we conducted in-depth interviews with 22 women to provide greater context to their survey responses. Results Of the 139 women, 21 women (15%) did not complete recommended diabetes testing. From the survey data, women who visited a primary care provider had 72% (95% CI, 0.09–0.83) lesser odds of not having been tested. From the qualitative interviews, difficulty fitting testing around work and caregiver demands were the most common reasons for not testing. Untested women interpreted providers' reassurances that diabetes would resolve after delivery and lack of reminders to reschedule missed appointments and to complete diabetes testing as indicators that their physicians were not concerned about their diabetes risk. Conclusions Among hard-to-reach women, multiple demands on their time were common explanations for not receiving a postpartum diabetes test. Consistent messages regarding long-term diabetes risk during pregnancy, access to postpartum primary care and convenient lab appointments, and systematic reminders to providers and patients are approaches that, in combination, may influence more resistant women to test.

Kathryn A. Paez; Emma M. Eggleston; Susan J. Griffey; Brandy Farrar; Jacquelyn Smith; Jennifer Thompson; Matthew W. Gillman

2014-01-01T23:59:59.000Z

212

Organic geochemistry and organic petrography  

SciTech Connect (OSTI)

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

213

Internal dissipation of a polymer  

SciTech Connect (OSTI)

The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics of a single chain in the absence of solvent to characterize the nature of this internal friction. We model the chains as freely hinged but with localized bond angles and threefold symmetric dihedral angles. We show that the damping is close but not identical to Kelvin damping, which depends on the first temporal and second spatial derivative of monomer position. With no internal potential between monomers, the magnitude of the damping is small for long wavelengths and weakly damped oscillatory time dependent behavior is seen for a large range of spatial modes. When the size of the internal potential is increased, such oscillations persist, but the damping becomes larger. However underdamped motion is present even with quite strong dihedral barriers for long enough wavelengths.

Deutsch, J. M. [Department of Physics, University of California, Santa Cruz, California 95064 (United States)

2010-06-15T23:59:59.000Z

214

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

Fontana, J.J.; Elling, D.; Reams, W.

1988-05-26T23:59:59.000Z

215

Diamond turning of thermoplastic polymers  

SciTech Connect (OSTI)

Single point diamond turning studies were made using a series of thermoplastic polymers with different glass transition temperatures. Variations in surface morphology and surface roughness were observed as a function of cutting speed. Lower glass transition temperatures facilitate smoother surface cuts and better surface finish. This can be attributed to the frictional heating that occurs during machining. Because of the very low glass transition temperatures in polymeric compared to inorganic glasses, the precision machining response can be very speed sensitive.

Smith, E.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

216

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

1990-01-01T23:59:59.000Z

217

Chaperonin Polymers in Archaea: The Cytoskeleton of Prokaryotes?  

DOE R&D Accomplishments [OSTI]

Chaperonins are protein complexes that play a critical role in folding nascent polypeptides under normal conditions and refolding damaged proteins under stress conditions. In all organisms these complexes are composed of evolutionarily conserved 60-kDa proteins arranged in double-ring structures with between 7 and 9 protein subunits per ring. These double ring structures are assumed to be the functional units in vivo, although they have never been observed inside cells. Here the authors show that the purified chaperonin from the hyperthermophilic archaeon Sulfolobus shibatae, which is closely related to chaperonins in eukaryotes, has a double ring structure at low concentrations (0.1 mg/ml), but at more physiological concentrations, the rings stack end to end to form polymers. The polymers are stable at physiological temperatures (75 C) and closely resemble structures observed inside unfixed S. shibatae cells. The authors suggest that in vivo chaperonin activity may be regulated by polymerization and that chaperonin polymers may act as a cytoskeleton-like structure in archaea and bacteria.

Trent, J. D.; Kagawa, H. K.; Zaluzec, N. J.

1997-07-00T23:59:59.000Z

218

NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

Fondeur, F.; Peters, T.; Fink, S.

2011-09-29T23:59:59.000Z

219

Electrochemical properties of Li ion polymer battery with gel polymer electrolyte based on polyurethane  

Science Journals Connector (OSTI)

Gel polymer electrolyte (GPE) was prepared using polyurethane acrylate as polymer host and its performance was evaluated. LiCoO2/GPE/graphite cells were prepared and their electrochemical performance as a functio...

H-S. Kim; G-Y. Choi; S-I. Moon; S-P. Kim

2003-06-01T23:59:59.000Z

220

Displacement Mechanism of Polymer Flooding by Molecular  

Science Journals Connector (OSTI)

Whether polymer flooding can enhance displacement efficiency or not is still a problem under debate. Laboratory experiment, numerical simulation and core data analysis are the commonly used means to study polymer flooding displacement efficiency. We discuss the limitations of these methods and employ molecular tribology to study the problem. The black–white ball action principle, i.e. the atom action model for describing the friction principle, is used to analyse the microscopic mechanism of oil displacement and describe the molecular interactions and displacement power during polymer flooding. Both tribology theory and dynamic rheological test show that molecular interactions during polymer flooding are bigger than that during water flooding. It is concluded that displacement efficiency of water flooding may be higher than that of polymer flooding at particular area; while polymer flooding can weaken the heterogeneity significantly, decrease ineffective injection and enhance the total displacement efficiency.

Yang Er-Long; Song Kao-Ping

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Tritium containing polymers having a polymer backbone substantially void of tritium  

DOE Patents [OSTI]

A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium. 2 figs.

Jensen, G.A.; Nelson, D.A.; Molton, P.M.

1992-03-31T23:59:59.000Z

222

Structural Arrangements of Polymers Adsorbed at Nanostrings  

E-Print Network [OSTI]

We study ground states of a hybrid system consisting of a polymer and an attractive nanowire by means of computer simulations. Depending on structural and energetic properties of the substrate, we find different adsorbed polymer conformations, amongst which are spherical droplets attached to the wire and monolayer tubes surrounding it. We construct the complete conformational phase diagram and analyze in more detail particularly interesting polymer-tube conformations.

Thomas Vogel; Michael Bachmann

2011-03-09T23:59:59.000Z

223

Nanoscale molecularly imprinted polymers and method thereof  

DOE Patents [OSTI]

Nanoscale molecularly imprinted polymers (MIP) having polymer features wherein the size, shape and position are predetermined can be fabricated using an xy piezo stage mounted on an inverted microscope and a laser. Using an AMF controller, a solution containing polymer precursors and a photo initiator are positioned on the xy piezo and hit with a laser beam. The thickness of the polymeric features can be varied from a few nanometers to over a micron.

Hart, Bradley R. (Brentwood, CA); Talley, Chad E. (Brentwood, CA)

2008-06-10T23:59:59.000Z

224

Organosiloxane-grafted natural polymer coatings  

DOE Patents [OSTI]

A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation. 17 figs.

Sugama, Toshifumi

1998-12-01T23:59:59.000Z

225

Structure, Dynamics, and Power Conversion Efficiency Correlations in a New Low Bandgap Polymer: PCBM Solar Cell  

Science Journals Connector (OSTI)

Since their discovery about 15 years ago, bulk heterojunction (BHJ) organic photovoltaic (OPV) devices made from semiconducting polymers have shown promise for future commercialization due to their low cost, ease of fabrication, and small environmental impact relative to silicon and heavy metal based semiconductor solar cells. ... (1-3) To achieve a high power conversion efficiency (PCE) in solar cells based on BHJ OPV materials, the semiconducting polymer composites must be efficient in light harvesting, exciton splitting, charge carrier generation, and transport. ... The white light continuum probe pulses were generated by focusing a few microjoules of the Ti:sapphire amplifier output onto a sapphire disk. ...

Jianchang Guo; Yongye Liang; Jodi Szarko; Byeongdu Lee; Hae Jung Son; Brian S. Rolczynski; Luping Yu; Lin X. Chen

2009-12-28T23:59:59.000Z

226

Polymer Electrolytes for Advanced Lithium Batteries | Department...  

Broader source: Energy.gov (indexed) [DOE]

Advanced Lithium Batteries Polymer Electrolytes for Advanced Lithium Batteries 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

227

ELECTROSPUN POLYMER-FIBER SOLAR CELL.  

E-Print Network [OSTI]

??A study of fabricating the first electrospun polymer-fiber solar cell with MEHPPV is presented. Motivation for the work and a brief history of solar cell… (more)

Nagata, Shinobu

2011-01-01T23:59:59.000Z

228

Graphene-based polymer waveguide polarizer  

Science Journals Connector (OSTI)

Planar-lightwave-circuit (PLC)-type graphene polarizers are fabricated by using a low loss optical polymer waveguide. The optical characteristics are investigated at a wavelength of...

Kim, Jin Tae; Choi, Choon-Gi

2012-01-01T23:59:59.000Z

229

Dynamics in Polymer | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neutron scattering characterizes dynamics in polymer family Agatha Bardoel - December 01, 2012 Interior of BASIS. Research Contact: Christine Gerstl Understanding the interplay...

230

Imaging Hydrated Microbial Extracellular Polymers: Comparative...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dehydration-based sample preparation that resulted in the collapse of hydrated gel-like EPS into filamentous structures. Dehydration-induced polymer collapse can lead to...

231

Heat insulation layer of polymer composite material  

Science Journals Connector (OSTI)

A new heat insulation layer polymer composite material is developed, within whose composition there is foam polyurethane and basaltoplastic. Results are provided for...

G. P. Ponomareva; A. A. Artemenko; O. M. Sladkov…

2010-05-01T23:59:59.000Z

232

Efficient Polymer Solar Cells - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laboratory researchers have developed a process for producing more efficient polymer solar cells by increasing light absorption through a thin and uniform light-absorbing...

233

Plasma immersion ion implantation on polymers.  

E-Print Network [OSTI]

??The focus of this thesis is to achieve plasma based surface modification of polymers. Highly ionized carbon plasma was generated from a filtered cathodic arc… (more)

Sze, Jia Yin.

2010-01-01T23:59:59.000Z

234

Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene are common  

E-Print Network [OSTI]

Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene are common commercial materials used for consumer products. Polyethylene is the most widely used polymer due and processing conditions. Equistar, in Cincinnati, is the largest producer of polyethylene in the US and P

Beaucage, Gregory

235

Detection of neovascularization for screening of proliferative diabetic retinopathy  

Science Journals Connector (OSTI)

Diabetic retinopathy is one of the leading cause of blindness caused due to increase of insulin in blood. It is a progressive disease and needs an early detection and treatment. Proliferative diabetic retinopathy is an advance stage and causes severe ...

M. Usman Akram; Anam Tariq; Shoab A. Khan

2012-06-01T23:59:59.000Z

236

Production of structures for microfluidics using polymer imprint techniques  

Science Journals Connector (OSTI)

We present a technology for the fabrication of three dimensional microfluidic channels in optically transparent substrates consisting of polymers with different properties. The microstructures are fabricated using polymer replication techniques with ... Keywords: Hot embossing, Micromechanisation, Micromoldin, Nanoimprint lithography, Polymers

C. A. Mills; E. Martinez; F. Bessueille; G. Villanueva; J. Bausells; J. Samitier; A. Errachid

2005-03-01T23:59:59.000Z

237

Systematic development of coarse-grained polymer models  

E-Print Network [OSTI]

The coupling between polymer models and experiments has improved our understanding of polymer behavior both in terms of rheology and dynamics of single molecules. Developing these polymer models is challenging because of ...

Underhill, Patrick Theodore

2006-01-01T23:59:59.000Z

238

Computer-aided diagnosis of diabetic retinopathy: A review  

Science Journals Connector (OSTI)

Diabetes mellitus may cause alterations in the retinal microvasculature leading to diabetic retinopathy. Unchecked, advanced diabetic retinopathy may lead to blindness. It can be tedious and time consuming to decipher subtle morphological changes in ... Keywords: Computer-aided diagnosis, Fundus imaging, Image processing, Pattern classification, Retina, Retinopathy

Muthu Rama Krishnan Mookiah; U. Rajendra Acharya; Chua Kuang Chua; Choo Min Lim; E. Y. K. Ng; Augustinus Laude

2013-12-01T23:59:59.000Z

239

Iron acetylacetonate complex anchored on silica xerogel polymer  

Science Journals Connector (OSTI)

Iron(III) acetylacetonate complex immobilized on silica surface was obtained by the following three steps synthesis: (i) synthesis of organic precursor (acacsil) containing the acetylacetonate (acac) group; (ii) simultaneous polycondensation of the acacsil with the tetraethylorthosilicate (TEOS) by the sol–gel method resulting in the acac/silica xerogel; and (iii) complexation of the Fe(III) on the acac sites of the xerogel surface forming a Fe-acac/silica xerogel. The xerogels, acac/silica and Fe-acac/silica, are hybrid polymers that present a covalent organic/inorganic interface between the acac groups and silica. Xerogels were characterized by using scanning electron microscopy, energy dispersive spectroscopy, infrared spectroscopy, N2 adsorption desorption isotherms (pore size distribution and surface area) and elemental analysis. The Fe-acac/silica xerogel was tested as heterogeneous catalyst for the cis-cyclooctene epoxidation, employing the same conditions of the homogeneous Mukaiyama system.

Marcia C. Brasil; Edilson V. Benvenutti; José R. Gregório; Annelise E. Gerbase

2005-01-01T23:59:59.000Z

240

Polymers For Advanced Lithium Batteries | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Polymers For Advanced Lithium Batteries Polymers For Advanced Lithium Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and...

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...  

Broader source: Energy.gov (indexed) [DOE]

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2013 DOE Hydrogen and Fuel Cells Program and...

242

Polymers For Advanced Lithium Batteries | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Polymers For Advanced Lithium Batteries Polymers For Advanced Lithium Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and...

243

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2012 DOE Hydrogen and Fuel Cells Program and...

244

Development of Polymer Electrolytes for Advanced Lithium Batteries...  

Broader source: Energy.gov (indexed) [DOE]

Development of Polymer Electrolytes for Advanced Lithium Batteries Development of Polymer Electrolytes for Advanced Lithium Batteries 2013 DOE Hydrogen and Fuel Cells Program and...

245

Fabrication and performance of polymer-nanocomposite anti-reflective...  

Office of Scientific and Technical Information (OSTI)

News, VA (United States) Design of polymer anti-reflective (AR) optical coatings for plastic substrates is challenging because polymers exhibit a relatively narrow range of...

246

Fiber-Reinforced Polymer Composites: Pursuing the Promise | Department...  

Energy Savers [EERE]

Fiber-Reinforced Polymer Composites: Pursuing the Promise Fiber-Reinforced Polymer Composites: Pursuing the Promise High-strength, lightweight advanced composites will deliver a...

247

Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal Sepsis by Multidrug-Resistant Pathogens. Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal Sepsis by...

248

Title: Pore formation in Polymer Electrolytes Abstract: Much of our ...  

E-Print Network [OSTI]

The efficient conversion of energy from one form to another, particularly solar, ... The polymer electrolytes in Polymer Electrolyte Membrane (PEM) fuel cells ...

249

azo dye polymer: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alignment 10 Solvent-enhanced dye diffusion in polymer thin films for polymer light-emitting diode application Engineering Websites Summary: Solvent-enhanced dye diffusion in...

250

Self-Assembly of Polymer Nano-Elements on Sapphire  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Assembly of Polymer Nano-Elements on Sapphire Print Self-assembly of polymers promises to vastly improve the properties and manufacturing processes of nanostructured...

251

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy...

252

Tandem Polymer Solar Cells Featuring a Spectrally Matched Low-Bandgap Polymer  

SciTech Connect (OSTI)

Tandem solar cells provide an effective way to harvest a broader spectrum of solar radiation by combining two or more solar cells with different absorption bands. However, for polymer solar cells, the performance of tandem devices lags behind single-layer solar cells mainly due to the lack of a suitable low-bandgap polymer. Here, we demonstrate highly efficient single and tandem polymer solar cells featuring a low-bandgap conjugated polymer (PBDTT-DPP: bandgap, {approx}1.44 eV). A single-layer device based on the polymer provides a power conversion efficiency of {approx}6%. When the polymer is applied to tandem solar cells, a power conversion efficiency of 8.62% is achieved, which is, to the best of our knowledge, the highest certified efficiency for a polymer solar cell to date.

Dou, L.; You, J.; Yang, J.; Chen, C. C.; He, Y.; Murase, S.; Moriarty, T.; Emery, K.; Li, G.; Yang, Y.

2012-03-01T23:59:59.000Z

253

Knot localization in adsorbing polymer rings  

E-Print Network [OSTI]

We study by Monte Carlo simulations a model of knotted polymer ring adsorbing onto an impenetrable, attractive wall. The polymer is described by a self-avoiding polygon (SAP) on the cubic lattice. We find that the adsorption transition temperature, the crossover exponent $\\phi$ and the metric exponent $\

B. Marcone; E. Orlandini; A. L. Stella

2007-09-10T23:59:59.000Z

254

Computationally-guided Design of Polymer Electrolytes  

E-Print Network [OSTI]

of Polymer Electrolytes Global Significance While progress of sustainable energy- harvesting techniques is promising, tandem advancements in energy storage are required to maintain a stable energy supply be a valuable contribution to the emerging sustainable energy landscape. This project applies polymer physics

255

Multicolored Electrochromism in Polymers: Structures and Devices  

E-Print Network [OSTI]

Multicolored Electrochromism in Polymers: Structures and Devices Avni A. Argun, Pierre-Henri Aubert May 12, 2004 A review of electrochromic (EC) polymers and their applications in absorption/transmission, reflective, and patterned electrochromic devices (ECDs) is presented. Fundamental properties of EC materials

Tanner, David B.

256

Cholesteric Pitch of Lyotropic Polymer Liquid Crystals  

Science Journals Connector (OSTI)

Cholesteric Pitch of Lyotropic Polymer Liquid Crystals ... The cholesteric pitch P of semiflexible helical polymer solutions was formulated using a threaded equivalent freely jointed chain model. ... The structure of cholesteric liquid crystals is characterized by the cholesteric pitch P or the cholesteric wavenumber qc (?2?/P). ...

Takahiro Sato; Jun Nakamura; Akio Teramoto; Mark M. Green

1998-02-03T23:59:59.000Z

257

Fuel cell electrolyte membrane with basic polymer  

DOE Patents [OSTI]

The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

2012-12-04T23:59:59.000Z

258

Polymer surface treatment with particle beams  

DOE Patents [OSTI]

A polymer surface and near surface treatment process produced by irradiation with high energy particle beams. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications.

Stinnett, Regan W. (1033 Tramway La. NE., Albuquerque, NM 87122); VanDevender, J. Pace (7604 Lamplighter NE., Albuquerque, NM 87109)

1999-01-01T23:59:59.000Z

259

Polymer surface treatment with particle beams  

DOE Patents [OSTI]

A polymer surface and near surface treatment process produced by irradiation with high energy particle beams is disclosed. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications. 16 figs.

Stinnett, R.W.; VanDevender, J.P.

1999-05-04T23:59:59.000Z

260

Shape memory polymer actuator and catheter  

DOE Patents [OSTI]

An actuator system is provided for acting upon a material in a vessel. The system includes an optical fiber and a shape memory polymer material operatively connected to the optical fiber. The shape memory polymer material is adapted to move from a first shape for moving through said vessel to a second shape where it can act upon said material.

Maitland, Duncan J. (Pleasant Hill, CA); Lee, Abraham P. (Walnut Creek, CA); Schumann, Daniel L. (Concord, CA); Matthews, Dennis L. (Moss Beach, CA); Decker, Derek E. (Byron, CA); Jungreis, Charles A. (Pittsburgh, PA)

2007-11-06T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Drug Therapy: Treatment of Diabetic Retinopathy  

Science Journals Connector (OSTI)

...macular edema. Fluorescein angiography can be used to identify patients with excessive vascular permeability, but leakage of fluorescein into the retina does not necessarily indicate macular edema. Macular edema is defined as retinal thickening resulting from the accumulation of fluid and can best be seen... Diabetic retinopathy has been and probably remains one of the four major causes of blindness in the United States.1,2 The risk of retinopathy is directly related to the degree and duration of hyperglycemia.3 After diabetes mellitus has been present for 20 ...

Ferris F.L.Davis M.D.Aiello L.M.

1999-08-26T23:59:59.000Z

262

Examining the effect of additives and thicknesses of hole transport layer for efficient organic solar cell devices  

Science Journals Connector (OSTI)

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), a conducting polymer, has been receiving a great deal of attention for next generation optoelectronic organic devices. In this report, we discu...

Shizuyasu Ochiai; Palanisamy Kumar; Kannappan Santhakumar…

2013-07-01T23:59:59.000Z

263

MMMaaattteeerrriiiaaalllsss SSSeeemmmiiinnnaaarrr There have been great interests in recent years in exploring the use of organic-inorganic hybrid electronic  

E-Print Network [OSTI]

Early Career Development (CAREER) Award from the National Science Foundation and a Solar Energy energy applications including photovoltaics and light-emitting devices (LEDs). Organic electronic materials such as conjugated polymers have advantages in low material cost, tunability in material

264

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer. 3 figures.

Weaver, P.F.; Pinching Maness.

1993-10-05T23:59:59.000Z

265

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer.

Weaver, Paul F. (Golden, CO); Maness, Pin-Ching (Golden, CO)

1993-01-01T23:59:59.000Z

266

Experimental test for geminate recombination applied to organic solar cells  

Science Journals Connector (OSTI)

We show that a clear experimental test can distinguish between geminate and nongeminate recombination in low mobility semiconductors. For the particular case of the organic solar cell, the relative contribution of geminate recombination can be determined by measuring transient photoconductivity versus applied voltage. Measurements carried out at room temperature and 200 K on bulk heterojunction organic solar cells fabricated with two different semiconducting polymers show that neither exhibits significant geminate recombination.

R. A. Street; Sarah Cowan; A. J. Heeger

2010-09-01T23:59:59.000Z

267

Functionalized Polymers For Binding To Solutes In Aqueous Solutions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalized Polymers For Binding To Solutes In Aqueous Solutions Functionalized Polymers For Binding To Solutes In Aqueous Solutions Functionalized Polymers For Binding To Solutes In Aqueous Solutions A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. Available for thumbnail of Feynman Center (505) 665-9090 Email Functionalized Polymers For Binding To Solutes In Aqueous Solutions A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. The polymer has a backbone polymer to which one or more functional groups are covalently linked. The backbone polymer can be such polymers as polyethylenimine, polyvinylamine, polyallylamine, and polypropylamine. These polymers are generally water-soluble, but can be insoluble when cross-linked. The functional group can be for example diol

268

POLYMERS IN STRUCTURAL DESIGN APPLICATIONS  

E-Print Network [OSTI]

FEP resin applications include wire and cable insulation for computer and electronic systems, telephone and alarm systems, and business-machine interconnects, FEP resin is also supplied as extruded sheet and film for release surfaces, roll covers, linings for chemical-processing tanks, and piping. A concentrate is available for Freon-blown-foam wire coating. PFA resins are used for hightemperature wire and cable insulation, heat-shrinkable tubing and roll covers, chemical-resistant linings for process-equipment components, and in semiconductor processing equipment. Materials do not adhere readily to the slippery surface of FEP, PFA, and PTFE parts. Surfaces can be chemically etched, however, to permit bonding with adhesives. Thus, low-friction surfaces of fluorocarbon tape or film can be bonded to steel, aluminum, rubber, or other materials. FEP and PFA parts can be heat sealed to themselves, to PTFE parts, or to metals at low pressure and temperatures above 310 °C. CTFE: Sensitivity to processing conditions is greater in CTFE resins than in most polymers.Molding and extruding operations require accurate temperature control, flow channel streamlining, and high pressure because of the high melt viscosity of these materials. With too little heat, the plastic is unworkable; too much heat degrades the polymer. Degradation begins at about 274 °C. Because of

Nedžad Rep?i?

269

CNF-reinforced polymer aerogels: Influence of the synthesis variables and economic evaluation  

Science Journals Connector (OSTI)

Abstract The synthesis of organic polymer aerogels reinforced with carbon nanofibers (CNF-reinforced polymer aerogels) using polyvinyl alcohol (PVA) as the polymeric matrix, by means of the freeze-drying method has been carried out. The influence of the CNF content in the polymer aerogel and the use of different solvents on the physical, morphological and mechanical properties of the final aerogel composites have been evaluated. The thermal conductivity and the porosity of CNF-reinforced polymer aerogels increased with the content of CNF. However, the density of the synthesized aerogels decreased when the CNF content was increased up to a value of 87.5 g/L. According to a dynamic mechanical analysis, the incorporation of CNF into the PVA matrix enhanced the mechanical characteristics and the glass transition temperature of the resulting CNF-reinforced polymer aerogels. On the other hand, aerogels synthesized using water as the solvent presented higher densities than those synthesized using acetone, butanol, ethanol or tert-butanol. However, their thermal conductivity values were very similar. Finally, an economic evaluation of the production of these materials using the freeze-drying technique was carried out. It was demonstrated the economic feasibility of the manufacturing process of aerogels proposed. Furthermore, no toxic pollutants were released at temperatures below 180 °C.

Sandra Víctor-Román; Carolina Simón-Herrero; Amaya Romero; Ignacio Gracia; José Luis Valverde; Luz Sánchez-Silva

2015-01-01T23:59:59.000Z

270

Serum markers for type II diabetes mellitus  

DOE Patents [OSTI]

A method for identifying persons with increased risk of developing type 2 diabetes mellitus utilizing selected biomarkers described hereafter either alone or in combination. The present invention allows for broad based, reliable, screening of large population bases and provides other advantages, including the formulation of effective strategies for characterizing, archiving, and contrasting data from multiple sample types under varying conditions.

Metz, Thomas O; Qian, Wei-Jun; Jacobs, Jon M; Polpitiya, Ashoka D; Camp, II, David G; Smith, Richard D

2014-03-18T23:59:59.000Z

271

Molecular Design of Doped Polymers for Thermoelectric Systems-Final Technical Report  

SciTech Connect (OSTI)

The self-assembly of organic semiconducting molecules and polymers is critical for their electrical properties. This project addressed the design of organic semiconductors with novel synthetic building blocks for proton-dopable conducting materials and the molecular order and microstructure of high performance semiconducting polymers blended with charge transfer dopants. Novel azulene donor-acceptor materials were designed and synthesized with unique electronic effects upon protonation to generate charged species in solution. The microstructure and optical properties of these derivatives were examined to develop structure-property relationships. Studies of the microstructure of blends of charge transfer doped semiconducting polymers revealed highly ordered conductive phases in blends. The molecular packing of one blend was studied in detail using a combination of solid-state NMR and x-ray scattering revealing that dopant incorporation is unlikely to be random as assumed in transport models. Studies of the electrical properties of these highly ordered blends revealed a universal trend between the thermopower and electrical conductivity of semiconducting polymers that is independent of the doping mechanism.

Chabinyc, Michael L. [University of California, Santa Barbara; Hawker, Craig J. [University of California, Santa Barbara

2013-10-09T23:59:59.000Z

272

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents [OSTI]

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

273

MODEL AND OPTIMIZATION OF ORGANIC PHOTOVOLTAIC CELLS Amelia McNamara  

E-Print Network [OSTI]

advantages. In contrast to the typical silicon-based solar cells, organic cells can be formed from extremely the organic photovoltaic cell, an important topic in the energy industry which has not been well studied. We are especially interested in the optimization of the two active layers in the solar cell, the PEOPT polymer

274

Syntheses and studies of acetylenic polymers  

SciTech Connect (OSTI)

Based on new diiodo aryl compounds a series of novel soluble polymers, poly(2,5-dialkoxy-1,4-phenyleneethynylene)s (PPE polymers) were synthesized using palladium-catalysis. The molecular weights (MW) range from 8,000 to 40,000. Properties such as absorption, fluorescence, and conductivity were studied. A PPE polymer with butoxy side chain exhibits a weak electrical conductivity ({sigma} = 10{sup {minus}3} S/cm) after doping with AsF{sub 5}. Absorption spectra in THF solution at room temperature (RT) show a maximum at 440 nm. However, absorption spectra of PPE polymers in the film state at (RT) show a maximum at 480 nm. PPE polymer-based light emitting diode (LED) devices have been prepared; greenish light from these LED devices can be observed. Poly(ethynylene-p-arylene-ethynylene-silylene)s were synthesized through the same palladium-catalyzed polymerization; MWs are between 6,000 and 82,000. Absorption and fluorescence were studied. Some of these polymers exhibit thermotropic liquid crystalline properties. In addition, nonlinear optical properties were briefly examined. Poly(silylene-ethynylene) homopolymers as well as alternating copolymers were synthesized through a novel palladium-catalyzed polymerization; MWs range from 56 {times} 10{sup 3} to 5.3 {times} 10{sup 3}. Thermal stability of these was also investigated; char yields range from 56 to 83%. One of these polymers exhibits thermotropic liquid crystalline properties.

Yiwei, Ding

1994-03-03T23:59:59.000Z

275

Open Questions about Polymer Friction JANET S. WONG,1  

E-Print Network [OSTI]

perfluoropolyethers are more effective than competing polymers. In the regulation of the viscosity of engine oils

Granick, Steve

276

Conductive inks for metalization in integrated polymer microsystems  

DOE Patents [OSTI]

A system of metalization in an integrated polymer microsystem. A flexible polymer substrate is provided and conductive ink is applied to the substrate. In one embodiment the flexible polymer substrate is silicone. In another embodiment the flexible polymer substrate comprises poly(dimethylsiloxane).

Davidson, James Courtney (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA); Maghribi, Mariam N. (Livermore, CA); Benett, William J. (Livermore, CA); Hamilton, Julie K. (Tracy, CA); Tovar, Armando R. (San Antonio, TX)

2006-02-28T23:59:59.000Z

277

Polymer nanocomposites based on transition metal ion modified organoclays  

E-Print Network [OSTI]

from both academic and industrial laboratories in the past several years [1,2]. Polymer nanocom in modulus, toughness, and barrier properties may be obtained. Typically, the improved properties can.polymer.2006.12.005 Polymer 48 (2007) 827e840 www.elsevier.com/locate/polymer #12;formation of silica

Frenkel, Anatoly

278

Glass/polymer composites and methods of making  

DOE Patents [OSTI]

The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

1995-01-01T23:59:59.000Z

279

An approach to the risk analysis of diabetes mellitus type 2 in a health care provider entity of Colombia using business intelligence  

Science Journals Connector (OSTI)

Business intelligence provides organizations with the ability to maintain a competitive advantage in the market. This property can be used in wide fields such as health care where lower costs and early prevention of patients are the main goals. This ... Keywords: association rules, business intelligence, data mining, diabetes mellitus type 2, risk analysis

Angela María Franco Pérez; Elizabeth León Guzmán

2012-05-01T23:59:59.000Z

280

The viscosity of polymer melts  

Science Journals Connector (OSTI)

A simple theoretical argument is presented that gives the scaling behavior of the relaxation time in a polymer melt as a function of molecular weight M. The framework for this theory is based on the reptation model of de Gennes but also incorporates the effects of excluded volume. It is argued that the effects of excluded volume change the relaxation time from M 3 to M 3 exp(const×M 2/3). This argument agrees qualitatively with a direct simulation of the reptation model that incorporates many?chain excluded volume interactions. This simulation fits experimental data quite well giving an effective power law relationship between viscosity ? and molecular weight namely ??M 3.4±.1.

J. M. Deutsch

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Polymer brush under strong shear  

Science Journals Connector (OSTI)

End-grafted polymer brush exposed to strong shear solvent flow is studied. Under strong enough shear flow, the shear force is nonlinear with the blob size depending on the shear force and not on the monomer volume fraction ?. We derive the crossover force scale separating the weak and strong shear regime. The velocity profile of the flow, v(z), inside and above the brush is calculated analytically by treating the flow as in a porous medium and solving the Brinkman equation. The solution of the velocity profile is then combined with nonequilibrium Monte Carlo simulation data, which allow a self-consistent determination of the chain end-to-end length and the incline angle of the chain. We derive the scaling form for the chain positions x(n) for the nth monomer and verified by our simulation data. We further obtain analytical expression for x(n) in terms of the effective viscosity of the model.

Pik-Yin Lai and Chee-Yuen Lai

1996-12-01T23:59:59.000Z

282

Image enhancement with polymer grid triode arrays  

SciTech Connect (OSTI)

An array of polymer grid triodes connected by a common grid functions as a {open_quotes}plastic retina,{close_quotes} providing local contrast gain control for image enhancement. This simple device, made from layers of conducting polymers, functions as an active resistive network that performs center-surround filtering. The polymer grid triode array with common grid is a continuous analog of the discrete approach of Mead, with a variety of fabrication advantages and significant savings in area within the unit cell of each pixel. 6 refs., 4 figs.

Heeger, A.J.; Heeger, D.J.; Langan, J. [UNIAX Corporation, Santa Barbara, CA (United States)] [and others

1995-12-08T23:59:59.000Z

283

Exploring novel silicon-containing polymers---From preceramic polymers to conducting polymers with nonlinear optical properties  

SciTech Connect (OSTI)

Several new types of silicon-containing preceramic polymers, i.e., poly(diorganosilacetylene) and poly(diorganosilvinylene) have been synthesized with molecular weights from 10,000 to 120,000. These polymers could be thermally converted to SiC with a moderate to high char yields. Ready solubility and good processability made these types of polymers attractive in their applications to ceramics. The thermal polymerization of diethynyldiphenyl-silane, which was reported in 1968 to afford poly(diphenylsilyldiacetylene) via dehydrogenation, was reinvestigated. Spectroscopic studies showed that the polymer had a structure of polyacetylene type not diacetylene. Diphenyldiethynylgermane and a series of diorganodiethynylsilances were synthesized. These could be polymerized in the presence of MoCl{sub 5} or WCl{sub 6} to afford a soluble, violet material with Mw as high as 108,000. 100 refs., 56 figs., 16 tabs.

Pang, Yi.

1991-10-07T23:59:59.000Z

284

High Resolution Additive Patterning of Nanoparticles and Polymers Enabled by Vapor Permeable Polymer Templates.  

E-Print Network [OSTI]

??The structure and chemistry of nanoparticles and polymers are interesting for applications in electronics and sensors. However, because they are outside of the standard material… (more)

Demko, Michael Thomas

2012-01-01T23:59:59.000Z

285

Polymer/Elastomer and Composite Material Science  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

/ Elastomer and / Elastomer and Composite Material Science KEVIN L. SIMMONS Pacific Northwest National Laboratory, Richland, WA DOE Headquarters, Forrestal Bldg. October 17-18, 2012 January 17, 2013 Kevin.simmons@pnnl.gov 1 Outline Hydrogen production, transmission, distribution, delivery system Common themes in the hydrogen system Automotive vs infrastructure Hydrogen use conditions Polymer/elastomer and composites compatibility? Common materials in BOP components, hoses, and liners Common materials in composite tank and piping Material issues Polymers/Elastomers Composites Questions 2 Main Points to Remember 1) Polymers are extensively used in hydrogen and fuel cell applications 2) Hydrogen impact on polymers is not well understood 3) Next steps 3 4 Hydrogen Production Systems

286

Neutron scattering from adsorbed polymer layers  

Science Journals Connector (OSTI)

Neutron scattering from adsorbed polymer layers ... Small-Angle Neutron Scattering Study of Cyclic Poly(ethylene glycol) Adsorption on Colloidal Particles ... Small-Angle Neutron Scattering Study of Cyclic Poly(ethylene glycol) Adsorption on Colloidal Particles ...

Terence Cosgrove; Timothy G. Heath; Keith Ryan; Trevor L. Crowley

1987-11-01T23:59:59.000Z

287

Polymer/Elastomer and Composite Material Science  

Broader source: Energy.gov [DOE]

Presentation by Kevin Simmons, Pacific Northwest National Laboratory, at the U.S. Department of Energy's Polymer and Composite Materials Meeting, held October 17-18, 2012, in Washington, D.C.

288

Chemical vapor deposition of functionalized isobenzofuran polymers  

E-Print Network [OSTI]

This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

Olsson, Ylva Kristina

2007-01-01T23:59:59.000Z

289

Electrical conductivity of segregated network polymer nanocomposites  

E-Print Network [OSTI]

in both electrical and mechanical properties with low carbon black loading, while the solution-based composite achieves its maximum enhancement at higher carbon black loading (~25wt%). The effect of the particle size ratio between the polymer particle...

Kim, Yeon Seok

2009-06-02T23:59:59.000Z

290

Catalyst supports for polymer electrolyte fuel cells  

Science Journals Connector (OSTI)

...Bruce, Richard Catlow and Peter Edwards Catalyst supports for polymer electrolyte fuel...durability in fuel cells is to discover catalyst supports that do not corrode, or corrode...black support. fuel cells|oxides|catalyst supports|nanoparticles|conductivity...

2010-01-01T23:59:59.000Z

291

Polymer-based electrocaloric cooling devices  

DOE Patents [OSTI]

Cooling devices (i.e., refrigerators or heat pumps) based on polymers which exhibit a temperature change upon application or removal of an electrical field or voltage, (e.g., fluoropolymers or crosslinked fluoropolymers that exhibit electrocaloric effect).

Zhang, Qiming; Lu, Sheng-Guo; Li, Xinyu; Gorny, Lee; Cheng, Jiping; Neese, Bret P; Chu, Baojin

2014-10-28T23:59:59.000Z

292

Numerical Simulation of Surfactant-Polymer Flooding  

Science Journals Connector (OSTI)

We propose a mathematical model (numerical simulation) of surfactant-polymer flooding for a three-phase six-component system. ... model takes into account various phenomena inherent to flooding, the effect of sur...

Baoguang Jin; Hanqiao Jiang; Xiansong Zhang…

2014-03-01T23:59:59.000Z

293

Synthesis and characterization of conducting polymer actuators  

E-Print Network [OSTI]

Conducting polymers are known to mechanically respond to electrochemical stimuli and have been utilized as linear actuators. To date, the most successful mechanism for actuation is ionic ingress and egress, though mechanisms ...

Vandesteeg, Nathan A. (Nathan Alan)

2007-01-01T23:59:59.000Z

294

Large displacement fast conducting polymer actuators  

E-Print Network [OSTI]

Conducting polymers are a promising class of electroactive materials that undergo volumetric changes under applied potentials, which make them particularly useful for many actuation applications. Polypyrrole , is one of ...

Chen, Angela Y. (Angela Ying-Ju), 1982-

2006-01-01T23:59:59.000Z

295

Dynamic Fracture Toughness of Polymer Composites  

E-Print Network [OSTI]

that of defense or transport. In this project, the focus is on determining dynamic fracture toughness property of fiber reinforced polymer composites by using a combined numerical- experimental methodology. Impact tests are conducted on Split-Hopkinson pressure...

Harmeet Kaur

2012-02-14T23:59:59.000Z

296

Carbon nanotube polymer composition and devices  

DOE Patents [OSTI]

A thin film device and compound having an anode, a cathode, and at least one light emitting layer between the anode and cathode, the at least one light emitting layer having at least one carbon nanotube and a conductive polymer.

Liu, Gao (Oakland, CA); Johnson, Stephen (Richmond, CA); Kerr, John B. (Oakland, CA); Minor, Andrew M. (El Cerrito, CA); Mao, Samuel S. (Castro Valley, CA)

2011-06-14T23:59:59.000Z

297

Counting primary loops in polymer gels  

E-Print Network [OSTI]

Much of our fundamental knowledge related to polymer networks is built on an assumption of ideal end-linked network structure. Real networks invariably possess topological imperfections that negatively affect mechanical ...

Zhou, Huaxing

298

Electronic Structure Calculations on Helical Conducting Polymers  

Science Journals Connector (OSTI)

Electronic Structure Calculations on Helical Conducting Polymers ... Therefore, we select the B3LYP/6-31G* methodology to calculate the oligomers. ... Table 3 shows several calculated parameters. ...

Juan D. Ripoll; Andrei Serna; Doris Guerra; Albeiro Restrepo

2010-09-28T23:59:59.000Z

299

Application of Conducting Polymers in Chemical Analysis  

Science Journals Connector (OSTI)

This paper presents recent achievements in the field of analytical application of conducting polymers, most of which were published in the last five years. Based on 171 references mainly to original papers in...

Marek Trojanowicz

2003-12-01T23:59:59.000Z

300

Color optimization of conjugated-polymer/InGaN Hybrid white light emitting diodes by incomplete energy transfer  

Science Journals Connector (OSTI)

Abstract By using the wavelength conversion method, white light emitting diodes (WLEDs) were produced by applying mixtures of polysiloxane and fluorescent polymers on InGaN based light emitting diodes. UV curable organic–inorganic hybrid materials with high refractive index (1.561), compromised optical, thermal and mechanical properties was used as encapsulants. Red light emitting fluorescent FABD polymer (with 9,9-dioctylfluorene (F), anthracene (A) and 2,1,3-benzothiadiazole (B), and 4,7-bis(2-thienyl)-2,1,3-benzothiadiazole (D) repeating units) and green light emitting fluorescent FAB polymer were used as wavelength converters. The encapsulant/fluorescent polymer mixture and InGaN produce the white light by incomplete energy transfer mechanism. \\{WLEDs\\} with high color rendering index (CRI, about 93), and tunable correlated color temperature (CCT) properties can be produced by controlling the composition and chemical structures of encapsulating polymer and fluorescent polymer in hybrid materials, offering cool-white and neutral-white LEDs.

Chi-Jung Chang; Chun-Feng Lai; P. Madhusudhana Reddy; Yung-Lin Chen; Wei-Yung Chiou; Shinn-Jen Chang

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Tuning the Morphology and Performance of Low Bandgap Polymer: Fullerene Heterojunctions via Solvent Annealing in Selective Solvents  

SciTech Connect (OSTI)

Low bandgap polymer (LBG):fullerene mixtures are some of the most promising organic photovoltaic active layers. Unfortunately, there are no post-deposition treatments available to rationally improve the morphology and performance of as-cast LBG:fullerene OPV active layers, where thermal annealing usually fails. Therefore, there is a glaring need to develop postdeposition methods to guide the morphology of LBG:fullerene bulk heterojunctions towards targeted structures and performance. In this paper, the structural evolution of PCPDTBT:PCBM mixtures with solvent annealing (SA) is examined, focusing on the effect of solvent quality of the fullerene and polymer in the annealing vapor on morphological evolution and device performance. The results indicate that exposure of this active layer to the solvent vapor controls the ordering of PCPDTBT and PCBM phase separation very effectively, presumably by inducing component mobility as the solvent plasticizes the mixture. These results also unexpectedly indicate that solvent annealing in a selective solvent provides a method to invert the morphology of the LBG:fullerene mixture from a polymer aggregate dispersed in a polymer:fullerene matrix to fullerene aggregates dispersed in a polymer:fullerene matrix. The judicious choice of solvent vapor, therefore, provides a unique method to exquisitely control and optimize the morphology of LBG conjugated polymer/fullerene mixtures.

Chen, Huipeng [ORNL; Hsiao, Yu-Che [ORNL; Hu, Bin [ORNL; Dadmun, Mark D [ORNL

2014-01-01T23:59:59.000Z

302

Organic bulk heterojunction solar cells using poly,,2,5-bis,,3-tetradecyllthiophen-2-yl...thieno3,2,-bthiophene...  

E-Print Network [OSTI]

. While the cost per watt of solar cell technology has steadily decreased in the past decade, an estimatedOrganic bulk heterojunction solar cells using poly,,2,5-bis,,3-tetradecyllthiophen-2-yl...thieno3 By transitioning to semicrystalline polymers, the performance of polymer-based solar cells has recently increased

McGehee, Michael

303

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However, even though this class of devices is finding a growing number of applications, electronic processes in organic materials are still not well understood. A group of researchers from the University of California and the ALS has succeeded in probing the intrinsic electronic properties of the charge carriers in organic FETs using infrared spectromicroscopy. The results of their study could help in the future development of sensors, large-area displays, and other plastic electronic components.

304

Poisson Bracket Formulation of Nematic Polymer Dynamics  

E-Print Network [OSTI]

We formulate the dynamical theory of nematic polymers, starting from a microscopic Poisson bracket approach. We find that the Poisson bracket between the nematic director and momentum depends on the (Maier-Saupe) order parameter of the nematic phase. We use this to derive reactive couplings of the nematic director to the strain rates. Additionally, we find that local dynamics breaks down as the polymers begin to overlap. We offer a physical picture for both results.

Randall D. Kamien

1999-06-22T23:59:59.000Z

305

Multidimensional Random Polymers : A Renewal Approach  

E-Print Network [OSTI]

In these lecture notes, which are based on the mini-course given at 2013 Prague School on Mathematical Statistical Physics, we discuss ballistic phase of quenched and annealed stretched polymers in random environment on ${\\mathbb Z}^d$ with an emphasis on the natural renormalized renewal structures which appear in such models. In the ballistic regime an irreducible decomposition of typical polymers leads to an effectiverandom walk reinterpretation of the latter. In the annealed casethe Ornstein-Zernike theory based on this approach paves the way to an essentially complete control on the level of local limit results and invariance principles. In the quenched case, the renewal structure maps the model of stretched polymers into an effective model of directed polymers. As a result one is able to use techniques and ideas developed in the context of directed polymers in order to address issues like strong disorder in low dimensions and weak disorder in higher dimensions. Among the topics addressed: Thermodynamics of quenched and annealed models, multi-dimensional renewal theory (under Cramer's condition), renormalization and effective random walk structure of annealed polymers, very weak disorder in dimensions $d\\geq 4$ and strong disorder in dimensions $d=1,2$.

Dmitry Ioffe

2014-11-30T23:59:59.000Z

306

Relationship among religious coping, psychosocial factors, and quality of life in individuals with type 2 diabetes  

E-Print Network [OSTI]

The purpose of this study was to examine the relationship among religious coping, acceptance of diabetes, social support, diabetes management, and quality of life among individuals with type 2 diabetes (T2DM). Religious coping, acceptance...

Lager, Julia M.

2009-06-02T23:59:59.000Z

307

Polymer-Nanoparticle Complexes : from Dilute Solution to Solid State  

E-Print Network [OSTI]

We report on the formation and the structural properties of supermicellar aggregates also called electrostatic complexes, made from mineral nanoparticles and polyelectrolyte-neutral block copolymers in aqueous solutions. The mineral particles put under scrutiny are ultra-fine and positively charged yttrium hydroxyacetate nanoparticles. Combining light, neutron and x-ray scattering experiments, we have characterized the sizes and the aggregation numbers of the organic-inorganic complexes. We have found that the hybrid aggregates have typical sizes in the range 100 nm and exhibit a remarkable colloidal stability with respect to ionic strength and concentration variations. Solid films with thicknesses up to several hundreds of micrometers were cast from solutions, resulting in a bulk polymer matrix in which nanoparticle clusters are dispersed and immobilized. It was found in addition that the structure of the complexes remains practically unchanged during film casting.

Jean-Francois Berret; Kazuhiko Yokota; Mikel Morvan; Ralf Schweins

2006-07-07T23:59:59.000Z

308

american diabetes association: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and without diabetes in 2002 by sex, age, raceethnicity, type of medical condition, and health care setting. Health care use and total health care expenditures attributable to...

309

Identificación del pie en riesgo de las personas con diabetes.  

E-Print Network [OSTI]

??La Diabetes Mellitus constituye una problemática sanitaria con una importante repercusión tanto en lo social como en lo económico. Se ha estimado la prevalencia de… (more)

Collar, Valeria

2009-01-01T23:59:59.000Z

310

Polymer micromold and fabrication process  

DOE Patents [OSTI]

A mold assembly is disclosed with micro-sized features in which the hollow portion thereof is fabricated from a sacrificial mandrel which is surface treated and then coated to form an outer shell. The sacrificial mandrel is then selectively etched away leaving the outer shell as the final product. The sacrificial mandrel is fabricated by a precision lathe, for example, so that when removed by etching the inner or hollow area has diameters as small as 10`s of micros ({micro}m). Varying the inside diameter contours of the mold can be accomplished with specified ramping slopes formed on the outer surface of the sacrificial mandrel, with the inside or hollow section being, for example, 275 {micro}m in length up to 150 {micro}m in diameter within a 6 mm outside diameter (o.d.) mold assembly. The mold assembly itself can serve as a micronozzle or microneedle, and plastic parts, such as microballoons for angioplasty, polymer microparts, and microactuators, etc., may be formed within the mold assembly. 6 figs.

Lee, A.P.; Northrup, M.A.; Ahre, P.E.; Dupuy, P.C.

1997-08-19T23:59:59.000Z

311

Interfacial thermal conductance in spun-cast polymer films and polymer brushes  

E-Print Network [OSTI]

represents the length of a material of thermal conduc- tivity providing an equivalent thermal resistance inorganic materials and anharmonic polymers have potentially intriguing thermal transport behavior. The low. This requirement proves challenging for low thermal conductivity materials like amorphous polymers. The effective

Braun, Paul

312

Friction in (im-)miscible polymer brush systems and the role of transverse polymer-tilting  

E-Print Network [OSTI]

Friction in (im-)miscible polymer brush systems and the role of transverse polymer-tilting Sissi de preferred solvent, leading to low friction and low wear rates. Here, we demonstrate, using molecular systems also show smaller friction than miscible systems, although the friction reduction is less than

Mueser, Martin

313

E-Print Network 3.0 - age-related diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

314

E-Print Network 3.0 - asymptomatic diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

315

E-Print Network 3.0 - arsenic-induced diabetes mellitus Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

316

E-Print Network 3.0 - adult-onset diabetes mellitus Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

317

E-Print Network 3.0 - ao diabetes mellitus Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

), a medicine approved to treat diabetes mellitus, will prevent a second stroke or heart attack by reversing... of diabetes mellitus; and you are willing to commit to a...

318

Serum magnesium level and magnesium supplementation on Type 2 Diabetes Mellitus: systematic review.  

E-Print Network [OSTI]

??Objective: To assess the association between serum magnesium levels and risk of type 2 diabetes and to evaluate the effect of magnesium supplementation on diabetes… (more)

Sefealem, Assefa Belay

2011-01-01T23:59:59.000Z

319

E-Print Network 3.0 - alloxan induced diabetic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dietary methyl- dimethyl-aminobenzene (26). Conversely, diabetes induced by alloxan... in Rats Subjected to Alloxan Diabetes and Food Restriction" Cancer Res 32, 226-232, 1972. 28....

320

Interaction of Nano-Sized Materials With Polymer Chains in Polymer-Nanocomposite Thin Films-An AFM Perspective  

SciTech Connect (OSTI)

Nanocomposite thin films were prepared with polyurethane as a matrix and organically modified clay as a filler. The interfacial interaction between the exfoliated clay nanoplatelets and the polymeric chains has been investigated by using Atomic Force Microscopy (AFM). The nanoclay platelets show a preferential association with the hard domains of polyurethane matrix on the surface of the thin films. The pendant hydroxyl group on the nanoplatelets attract the isocyanate of the polyisocyanate and a urethane group is formed. This leads to the 'clouding' and 'entwining' of the nanoplatelets by the hard segmental chains. This is the first visual evidence of nanomaterial filler and polymer matrix interaction and it could open up a spectrum of novel property achievements in nanocomposite thin films. Also the understanding of this interaction can lead to more controlled architecture of nanocomposites.

Verma, Gaurav; Kaushik, Anupama [University Institute of Chemical Engineering and Technology, Sector 14, Panjab University Chandigarh-160014, India and (Department of Chemical Engineering and Technology) (India); Ghosh, Anup K. [Centre for Polymer Science and Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi-110016 (India)

2011-12-12T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Method of making metal-polymer composite catalysts  

DOE Patents [OSTI]

A metal-polymer-carbon composite catalyst for use as a cathode electrocatalyst in fuel cells. The catalyst includes a heteroatomic polymer; a transition metal linked to the heteroatomic polymer by one of nitrogen, sulfur, and phosphorus, and a recast ionomer dispersed throughout the heteroatomic polymer-carbon composite. The method includes forming a heteroatomic polymer-carbon composite and loading the transition metal onto the composite. The invention also provides a method of making a membrane electrode assembly for a fuel cell that includes the metal-polymer-carbon composite catalyst.

Zelena, Piotr (Los Alamos, NM); Bashyam, Rajesh (Los Alamos, NM)

2009-06-23T23:59:59.000Z

322

Polymer quenched prealloyed metal powder  

DOE Patents [OSTI]

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

2001-01-01T23:59:59.000Z

323

Achieving High Performance Polymer Tandem Solar Cells via Novel Materials Design  

E-Print Network [OSTI]

polymer solar cell could be a viable technology for spacetechnology must utilize the uniqueness of polymer solar cells.

Dou, Letian

2014-01-01T23:59:59.000Z

324

Who Gets Diabetes? Good health is your most valuable asset  

E-Print Network [OSTI]

Who Gets Diabetes? Good health is your most valuable asset ­ make the most of it. Millions, blindness and many other health problems if it is not controlled. By managing this condition with the right care, treatment and lifestyle changes, a patient diagnosed with diabetes can continue to live a happy

325

Modeling Cold Start in a Polymer-Electrolyte Fuel Cell  

E-Print Network [OSTI]

Boundary conditions used for fuel—cell simulations. 3.12to the Problem of Cold Start 1.1 Polymer—Electrolyte Fuelin Polymer Electrolyte Fuel Cells — II. Parametric Study,”

Balliet, Ryan

2010-01-01T23:59:59.000Z

326

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

327

Phase selectively soluble polymer supports to facilitate homogeneous catalysis  

E-Print Network [OSTI]

Soluble polymers that have phase selective solubility are useful in synthesis because they simplify purification and separation. Such selectively soluble polymers simplify catalyst, reagent, and product recovery and enable the use of Green chemistry...

Ortiz-Acosta, Denisse

2009-05-15T23:59:59.000Z

328

Synthesis and Characterization of Polymer Nanocomposites for Energy Applications  

E-Print Network [OSTI]

Polymer nanocomposites are used in a variety of applications due to their good mechanical properties. Specifically, better performance of lithium ion batteries and thermal interface material can be obtained by using conductive materials and polymer...

Park, Wonchang

2011-10-21T23:59:59.000Z

329

Polymer-coated iron oxide nanoparticles for medical imaging  

E-Print Network [OSTI]

One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

Chen, Suelin, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

330

Tailoring the Thermoelectric Behavior of Electrically Conductive Polymer Composites  

E-Print Network [OSTI]

fabrication temperatures. These concerns have led research efforts into electrically conductive polymer composites prepared in ambient conditions from aqueous solutions. By combining polymer latex with carbon nanotubes (CNT), electrical conductivity can...

Moriarty, Gregory P.

2013-05-21T23:59:59.000Z

331

Processing and thermal properties of molecularly oriented polymers  

E-Print Network [OSTI]

High molecular weight polymers that are linear in molecular construction can be oriented such that some of their physical properties in the oriented direction are enhanced. For over 50 years polymer orientation and processing ...

Skow, Erik (Erik Dean)

2007-01-01T23:59:59.000Z

332

Switchable window based on electrochromic polymers Chunye Xu,a)  

E-Print Network [OSTI]

Switchable window based on electrochromic polymers Chunye Xu,a) Lu Liu, Susan E. Legenski, Dai Ning March 2004) A large contrast ratio (> 60%) and rapid switching (0.3­1 s) electrochromic (EC) polymer

Taya, Minoru

333

An overview of molten polymer drawing instabilities Yves Demay1  

E-Print Network [OSTI]

dissipation in a screw/barrel device and then forced in a spinning pack consisting of a metal plaque of processes for polymer film production: · In the cast-film process, the polymer is melted in an extruder

Paris-Sud XI, Université de

334

Biology and polymer physics at the single–molecule level  

Science Journals Connector (OSTI)

...Olmsted Biology and polymer physics at the single-molecule level Steven Chu Department of Physics...be hidden from view can be clearly seen in single-molecule experiments. single-molecule biology|polymer dynamics|biological physics...

2003-01-01T23:59:59.000Z

335

Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable  

Science Journals Connector (OSTI)

Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable ... Yet, such polymers are “challenged” with respect to sustainability. ... The Earth harbors finite carbon-based feedstocks that are being rapidly depleted by our increasing energy demand. ...

Marc A. Hillmyer; William B. Tolman

2014-05-22T23:59:59.000Z

336

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, T.

1984-09-28T23:59:59.000Z

337

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1986-01-01T23:59:59.000Z

338

Polymer Technology Corp | Open Energy Information  

Open Energy Info (EERE)

Polymer Technology Corp Polymer Technology Corp Jump to: navigation, search Name Polymer Technology Corp Place Menomonie, Wisconsin Zip 54751 Sector Services Product A provider of contract engineering services Coordinates 44.8805°, -91.929559° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":44.8805,"lon":-91.929559,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

339

NETL: Novel Inorganic/Polymer Composite Membranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Novel Inorganic/Polymer Composite Membranes Novel Inorganic/Polymer Composite Membranes Project No.: DE-FE0007632 Ohio State University is developing a cost-effective design and manufacturing process for new membrane modules that capture carbon dioxide (CO2) from flue gas. The membranes consist of a thin, selective inorganic layer, embedded in a polymer structure so that it can be made in a continuous manufacturing process. They will be incorporated in spiral-wound modules for bench-scale tests using coal-fired flue gas. Preliminary cost calculations show that a single-stage membrane process is economically unfavorable, primarily because of the low concentration of CO2 (~14 percent) in the flue gas stream. A two-stage process is more economical, but requires plant operation with a CO2-enriched recycle stream.

340

Adjustable flow rate controller for polymer solutions  

DOE Patents [OSTI]

An adjustable device for controlling the flow rate of polymer solutions which results in only little shearing of the polymer molecules, said device comprising an inlet manifold, an outlet manifold, a plurality of tubes capable of providing communication between said inlet and outlet manifolds, said tubes each having an internal diameter that is smaller than that of the inlet manifold and large enough to insure that viscosity of the polymer solution passing through each said tube will not be reduced more than about 25 percent, and a valve associated with each tube, said valve being capable of opening or closing communication in that tube between the inlet and outlet manifolds, each said valve when fully open having a diameter that is substantially at least as great as that of the tube with which it is associated.

Jackson, Kenneth M. (Bartlesville, OK)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Two Dimensional Polymer That Generates Nitric Oxide.  

DOE Patents [OSTI]

A polymeric composition that generates nitric oxide and a process for rendering the surface of a substrate nonthrombogenic by applying a coating of the polymeric composition to the substrate are disclosed. The composition comprises: (1) a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, and (ii) a crosslinking agent containing functional groups capable of reacting with the amino groups; and (2) a plurality of nitric oxide generating functional groups associated with the crosslinked chemical combination. Once exposed to a physiological environment, the coating generates nitric oxide thereby inhibiting platelet aggregation. In one embodiment, the nitric oxide generating functional groups are provided by a nitrated compound (e.g., nitrocellulose) imbedded in the polymeric composition. In another embodiment, the nitric oxide generating functional groups comprise N2O2- groups covalently bonded to amino groups on the polymer.

McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI)

2005-10-04T23:59:59.000Z

342

Stretchable polymer-based electronic device  

DOE Patents [OSTI]

A stretchable electronic circuit or electronic device and a polymer-based process to produce a circuit or electronic device containing a stretchable conducting circuit. The stretchable electronic apparatus has a central longitudinal axis and the apparatus is stretchable in a longitudinal direction generally aligned with the central longitudinal axis. The apparatus comprises a stretchable polymer body and at least one circuit line operatively connected to the stretchable polymer body. The circuit line extends in the longitudinal direction and has a longitudinal component that extends in the longitudinal direction and has an offset component that is at an angle to the longitudinal direction. The longitudinal component and the offset component allow the apparatus to stretch in the longitudinal direction while maintaining the integrity of the circuit line.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA); Davidson, James Courtney (Livermore, CA); Wilson, Thomas S. (Castro Valley, CA); Hamilton, Julie K. (Tracy, CA); Benett, William J. (Livermore, CA); Tovar, Armando R. (San Antonio, TX)

2008-02-26T23:59:59.000Z

343

Thermal diffusivity measurement system applied to polymers  

Science Journals Connector (OSTI)

In the search for cleaner energy sources the improvement of the efficiency of the actual ones appears as a primary objective. In this way thermoelectric materials which are able to convert wasted heat into electricity are reveal as an interesting way to improve efficiency of car engines for example. Cost-effective energy harvesting from thermoelectric devices requires materials with high electrical conductivities and Seebeck coefficient but low thermal conductivity. Conductive polymers can fulfil these conditions if they are doped appropriately. One of the most promising polymers is Polyaniline. In this work the thermal conductivity of the polyaniline and mixtures of polyaniline with nanoclays has been studied using a new experimental set-up developed in the lab. The novel system is based on the steady-state method and it is used to obtain the thermal diffusivity of the polymers and the nanocomposites.

2012-01-01T23:59:59.000Z

344

New Breathalyzer Offers Hope of Pain-Free Diabetes Monitoring  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8, 2013 8, 2013 New Breathalyzer Offers Hope of Pain-Free Diabetes Monitoring Diabetes Carbon nanotube armchair povray Researchers at the Department of Energy's National Energy Technology Laboratory (NETL) have teamed up with their Regional University Alliance (NETL-RUA) colleagues to develop a new hybrid nanostructure that could make it easier to monitor blood sugar. When used as a sensing tool in a breath analyzer, the new material could offer a way for millions of diabetics to avoid the pain and hassle of finger sticks. How will it work? By detecting acetone. Everyone produces a certain level of acetone through normal, daily metabolic processes. But diabetics produce it in larger amounts and also exhale it at a higher rate than non-diabetics, which is what produces the "fruity" aroma present when

345

Novel Ceramic-Polymer Composite Membranes for the Separation of Hazardous Liquid Waste  

SciTech Connect (OSTI)

The present project was conceived to address the need for robust yet selective membranes suitable for operating in harsh ph, solvent, and temperature environments. An important goal of the project was to develop a membrane chemical modification technology that would allow one to tailor-design membranes for targeted separation tasks. The method developed in the present study is based on the process of surface graft polymerization. Using essentially the same base technology of surface modification the research was aimed at demonstrating that improved membranes can be designed for both pervaporation separation and ultrafiltration. In the case of pervaporation, the present study was the first to demonstrate that pervaporation can be achieved with ceramic support membranes modified with an essentially molecular layer of terminally anchored polymer chains. The main advantage of the above approach, relative to other proposed membranes, is that the separating polymer layer is covalently attached to the ceramic support. Therefore, such membranes have a potential use in organic-organic separations where the polymer can swell significantly yet membrane robustness is maintained due to the chemical linkage of the chains to be inorganic support. The above membrane technology was also useful in developing fouling resistant ultrafiltration membranes. The prototype membrane developed in the project was evaluated for the treatment of oil-in-water microemulsions, demonstrating lack of irreversible fouling common with commercial membranes.

Yoram Cohen

2001-12-01T23:59:59.000Z

346

Solid polymer electrolyte from phosphorylated chitosan  

SciTech Connect (OSTI)

Recently, the need of secondary battery application continues to increase. The secondary battery which using a liquid electrolyte was indicated had some weakness. A solid polymer electrolyte is an alternative electrolytes membrane which developed in order to replace the liquid electrolyte type. In the present study, the effect of phosphorylation on to polymer electrolyte membrane which synthesized from chitosan and lithium perchlorate salts was investigated. The effect of the component’s composition respectively on the properties of polymer electrolyte, was carried out by analyzed of it’s characterization such as functional groups, ion conductivity, and thermal properties. The mechanical properties i.e tensile resistance and the morphology structure of membrane surface were determined. The phosphorylation processing of polymer electrolyte membrane of chitosan and lithium perchlorate was conducted by immersing with phosphoric acid for 2 hours, and then irradiated on a microwave for 60 seconds. The degree of deacetylation of chitosan derived from shrimp shells was obtained around 75.4%. Relative molecular mass of chitosan was obtained by viscometry method is 796,792 g/mol. The ionic conductivity of chitosan membrane was increase from 6.33 × 10{sup ?6} S/cm up to 6.01 × 10{sup ?4} S/cm after adding by 15 % solution of lithium perchlorate. After phosphorylation, the ionic conductivity of phosphorylated lithium chitosan membrane was observed 1.37 × 10{sup ?3} S/cm, while the tensile resistance of 40.2 MPa with a better thermal resistance. On the strength of electrolyte membrane properties, this polymer electrolyte membrane was suggested had one potential used for polymer electrolyte in field of lithium battery applications.

Fauzi, Iqbal, E-mail: arcana@chem.itb.ac.id; Arcana, I Made, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Groups, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2014-03-24T23:59:59.000Z

347

Polymer-electrolyte membrane, electrochemical fuel cell, and related method  

DOE Patents [OSTI]

A polymer-electrolyte membrane is presented. The polymer-electrolyte membrane comprises an acid-functional polymer, and an additive incorporated in at least a portion of the membrane. The additive comprises a fluorinated cycloaliphatic additive, a hydrophobic cycloaliphatic additive, or combinations thereof, wherein the additive has a boiling point greater than about 120.degree. C. An electrochemical fuel cell including the polymer-electrolyte membrane, and a related method, are also presented.

Krishnan, Lakshmi; Yeager, Gary William; Soloveichik, Grigorii Lev

2014-12-09T23:59:59.000Z

348

Evaluation of Rexene polymers in hot mixed asphalt concrete  

E-Print Network [OSTI]

Committee: Dr. Dallas N. Little The objective of this research was to provide a comprehensive characterization of asphalt binders and paving mixtures modified with four polymers produced by the Rexene Products Company (Odessa, Texas). The four polymers... on control asphalt cements and polymer modified asphalt cements to quantify the effects of the Rexene polymers. Most importantly, the binder study was designed to determine the temperature susceptibility of the binders. Asphalt cements from three...

Rodriguez, Mary Anne Reese

1991-01-01T23:59:59.000Z

349

Organic thin film prehistory: looking towards solution phase aggregation |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organic thin film prehistory: looking towards solution phase aggregation Organic thin film prehistory: looking towards solution phase aggregation Wednesday, November 6, 2013 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Christopher Tassone, SSRL Polymer bulk heterojunction (BHJ) solar cells have attracted significant attention in industry and academia because of their potential for achieving large-area, light-weight, and flexible photovoltaic devices through cost-effective solution deposition techniques. These devices consist of a blend of an absorbing polymer and an electron accepting fullerene, the molecular packing and phase segregation of which heavily influence power conversion efficiency by effecting important processes such as exciton splitting, charge transport, and recombination. Understanding and utilization of molecular interactions to predicatively control the

350

Microfluidic devices and methods including porous polymer monoliths  

DOE Patents [OSTI]

Microfluidic devices and methods including porous polymer monoliths are described. Polymerization techniques may be used to generate porous polymer monoliths having pores defined by a liquid component of a fluid mixture. The fluid mixture may contain iniferters and the resulting porous polymer monolith may include surfaces terminated with iniferter species. Capture molecules may then be grafted to the monolith pores.

Hatch, Anson V; Sommer, Gregory J; Singh, Anup K; Wang, Ying-Chih; Abhyankar, Vinay V

2014-04-22T23:59:59.000Z

351

Polymers Promoting Quality by Jung-Il Jin  

E-Print Network [OSTI]

of polymer science. The Polymer Education and International Cooperation sessions provided an opportunity and the total number of presentations, including posters, was slightly more than 1 300 (35 percent Brazilian) for his brilliant effort in bridging polymer science with biological problems. Mr. Hong-Shik Ko, president

Tew, Gregory N.

352

Method of making organic light emitting devices  

DOE Patents [OSTI]

The present invention provides a method for the preparation of organic light-emitting devices comprising a bilayer structure made by forming a first film layer comprising an electroactive material and an INP precursor material, and exposing the first film layer to a radiation source under an inert atmosphere to generate an interpenetrating network polymer composition comprising the electroactive material. At least one additional layer is disposed on the reacted first film layer to complete the bilayer structure. The bilayer structure is comprised within an organic light-emitting device comprising standard features such as electrodes and optionally one or more additional layers serving as a bipolar emission layer, a hole injection layer, an electron injection layer, an electron transport layer, a hole transport layer, exciton-hole transporting layer, exciton-electron transporting layer, a hole transporting emission layer, or an electron transporting emission layer.

Shiang, Joseph John (Niskayuna, NY); Janora, Kevin Henry (Schenectady, NY); Parthasarathy, Gautam (Saratoga Springs, NY); Cella, James Anthony (Clifton Park, NY); Chichak, Kelly Scott (Clifton Park, NY)

2011-03-22T23:59:59.000Z

353

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty  

E-Print Network [OSTI]

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty perform research in molecular machines, exotic CHEMISTRY FACULTY RESEARCH INTERESTS Anne M. Andrews, Professor-in-Residence: Understanding how areas of interest include cross- coupling reactions, green chemistry, heterocycle synthesis, and natural

Levine, Alex J.

354

Polymer, Vol. 46, no. 2, pp. 553-562 (2005) Modeling of the Mechanical Properties of Nanoparticle/Polymer Composites  

E-Print Network [OSTI]

and particles in the polymer. Several efforts have focused on the modeling of mechanical properties of nanoclay

Odegard, Gregory M.

355

8 - High-Performance Polyimides and Related Thermoset Polymers: Past and Present Development, and Future Research Directions  

Science Journals Connector (OSTI)

Publisher Summary Polyimides, prepared from a variety of dianhydride and diamine monomers, are characterized by repeating imide structural units (I) in the polymer backbone. This structure contributes to the exceptional thermal and oxidative stability of polyimides. It is necessary to have the imide structure along with the aromatic moieties because wholly aromatic polymers such as polyphenylenes are not as thermo-oxidatively resistant as polyimides. The combination of the aromatic structure and the imide structure results in a polymer with a high glass transition temperature (Tg) and high thermo-oxidative stability. These aromatic polyimides can be processed either as thermosetting or thermoplastic resins, depending on the processing characteristics of the polymer resin or the process required to transform the prepolymer resin into the final form or shape. These polymers are broken down conveniently into three categories, depending on their processing characteristics. One of these categories includes thermoplastic polyimides. The polyimides in this first category are processed via precursors that undergo condensation reactions to form the final product. The precursors are usually the amic acid or the amic ester intermediate. They are tractable, soluble in common organic solvents, and generally applied as lacquers.

Abraham L. Landis; Kreisler S.Y. Lau

1999-01-01T23:59:59.000Z

356

Polymer defect states modulate open-circuit voltage in bulk-heterojunction solar cells  

SciTech Connect (OSTI)

Defect states influence the operation of organic solar cells altering transport, recombination, and energetic mechanisms. This work investigates how processing conditions induce morphology-related, electrically active defects in the donor polymer of bulk-heterojunction solar cells. Structural order is inferred from absorption and X-ray diffraction data, while defect density is determined from capacitance methods. A correlation is observed between the polymer nanocrystallite size, the defect concentration, and the output voltage. For the case of poly(3-hexylthiophene), processing that promote crystallinity is beneficial for the device performance as it decreases the defect density (energy disorder) that finally enlarges the maximum achievable open-circuit voltage. Defect states within the effective bandgap modulate the downshift of the hole Fermi level upon illumination that in turn establishes the achievable open-circuit voltage.

Ripolles, Teresa S.; Guerrero, Antonio; Garcia-Belmonte, Germà, E-mail: garciag@uji.es [Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló (Spain)] [Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló (Spain)

2013-12-09T23:59:59.000Z

357

Extensional rheology of polymers and optical properties of blown polymer films  

E-Print Network [OSTI]

Extensional Rheo logy of Polymers and Optical Properties of Blown Polymer Films. (August 1998) Jason E. Maxey, B. S. , Texas A&M University Chair of Advisory Committee: Dr. Lynden Archer Biaxial extensional flows are a commonly encountered and yet poorly.... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Molecular Orientation by Bireiringence . Crystallinity by Raman Spectroscopy. Results and Discussion Film Bireiringence Raman Analysis of Crystallinity . . . . . . . 5 . . . . . 7 . . . . . 7 11 . 13 . . . 13 . . . 18 LUBRICATED SQUEEZING...

Maxey, Jason E

2012-06-07T23:59:59.000Z

358

Brine tolerant polymer for oil recovery applications  

SciTech Connect (OSTI)

This patent describes a beta-alanine-type branched partially hydrolyzed polyacrylamide, which is added to an aqueous injection fluid to increase the viscosity of the fluid. The polymer resists plugging of the wellbore face and/or matrix pores and is brine tolerant when injected into a subterranean hydrocarbon-bearing formation.

Tackett, J.E.

1987-11-24T23:59:59.000Z

359

Water-soluble polymers and compositions thereof  

DOE Patents [OSTI]

Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.

Smith, B.F.; Robison, T.W.; Gohdes, J.W.

1999-04-06T23:59:59.000Z

360

Laminar-turbulent transition in polymer solutions  

Science Journals Connector (OSTI)

... as shown in Fig. Ic. A similar appearance to Fig. Ic was obtained by roughening the surface of the ogive in pure water flow (although we were careful to ... the surface of the ogive in pure water flow (although we were careful to avoid roughening the ogive surface when using polymer solution). Thus, we conclude that the presence ...

J. W. HOYT

1977-12-08T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Preparation and characterization of gradient polymer films  

SciTech Connect (OSTI)

Gradient polymers are multicomponent polymers whose chemical constitution varies with depth in the sample. Although these polymers may possess unique mechanical, optical, and barrier properties they remain relatively unexplored. This work is a study of the preparation of gradient polymers by sequential exposure of films to a diffusing monomer followed by electron beam irradiation. Initial experiments involved immersion of poly(vinyl chloride) (PVC) films in styrene or n-butyl methacrylate (BMA) for various time periods followed by irradiation with 1 or 10 megarads of accelerated electrons. A significant amount of poly(n-butyl methacrylate) (PBMA) formed in PVC/BMA systems, but little polystyrene could be found in the PVC/styrene films. A second set of experiments involved immersion of PVC and polyethylene (PE) films in BMA for 20, 40, 60, and 720 minutes followed by irradiation with 10 megarads of electrons. These films were then characterized using optical microscopy, quantitative transmission Fourier transform infrared spectroscopy (FTIR), and a depth profiling procedure based on quantitative attenuated total reflection (ATR) FTIR. It was concluded that the mechanism of PBMA formation in the polyethylene films was a result of events immediately following irradiation. Atmospheric oxygen diffusing into irradiated films trapped free radicals at the film surfaces. This was followed by storage in an evacuated desiccator where unintentional exposure to BMA vapor took place. This BMA reacted with free radicals that remained within the film cores, polymerizing to PBMA.

Smith, S.C.

1987-01-01T23:59:59.000Z

362

Methods of making composite optical devices employing polymer liquid crystal  

DOE Patents [OSTI]

Composite optical devices are disclosed using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T[sub g]) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device. 7 figures.

Jacobs, S.D.; Marshall, K.L.; Cerqua, K.A.

1991-10-08T23:59:59.000Z

363

Methods of making composite optical devices employing polymer liquid crystal  

DOE Patents [OSTI]

Composite optical devices using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T.sub.g) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device.

Jacobs, Stephen D. (Pittsford, NY); Marshall, Kenneth L. (Henrietta, NY); Cerqua, Kathleen A. (Fairport, NY)

1991-01-01T23:59:59.000Z

364

The Organic Rankine Cycle  

Science Journals Connector (OSTI)

Chap. 3 is dedicated to Rankine cycles with organic fluids: the so-called organic Rankine cycles (ORC), which in recent years have ... of the use of...

Costante Mario Invernizzi

2013-01-01T23:59:59.000Z

365

Organization | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Organization Organization The Office of Economic Impact and Diversity is comprised of: The Office of the Director- contact us Office of Minority Business and Economic Development -...

366

Dynamics of Conformational Transition in Thermo-Sensitive Polymers and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atomistic simulations elucidating the coil-to-globule conformational changes in thermosensitive polymers. Atomistic simulations elucidating the coil-to-globule conformational changes in thermosensitive polymers. Atomistic simulations elucidating the coil-to-globule conformational changes in thermosensitive polymers. Dynamics of Conformational Transition in Thermo-Sensitive Polymers and Hydrogels PI Name: Subramanian Sankaranarayanan PI Email: skrssank@anl.gov Institution: Argonne National Laboratory Allocation Program: ALCC Allocation Hours at ALCF: 50 Million Year: 2012 Research Domain: Materials Science Subramanian Sankaranarayanan with Argonne's Center for Nanoscale Materials was awarded 50 million hours to study conformational transformations in thermo-sensitive oligomers and their macroscopic architectures such as polymer brushers and polymer gels. Understanding the conformational transformations of isolated linear polymer

367

Polymers with Tailored Electronic Structure for High Capacity Lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polymers with Tailored Electronic Structure for High Capacity Lithium Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes Title Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes Publication Type Journal Article Year of Publication 2011 Authors Liu, Gao, Shidi Xun, Nenad Vukmirovic, Xiangyun Song, Paul Olalde-Velasco, Honghe Zheng, Vince S. Battaglia, Linwang Wang, and Wanli Yang Journal Advanced Materials Volume 23 Start Page 4679 Issue 40 Pagination 4679 - 4683 Date Published 10/2011 Keywords binders, conducting polymers, density funcational theory, lithium batteries, X-ray spectroscopy Abstract A conductive polymer is developed for solving the long-standing volume change issue in lithium battery electrodes. A combination of synthesis, spectroscopy and simulation techniques tailors the electronic structure of the polymer to enable in situ lithium doping. Composite anodes based on this polymer and commercial Si particles exhibit 2100 mAh g-1 in Si after 650 cycles without any conductive additive.

368

Durable polymer-aerogel based superhydrophobic coatings, a composite material  

DOE Patents [OSTI]

Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140.degree. and a contact angle hysteresis of less than about 1.degree.. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

Kissel, David J; Brinker, Charles Jeffrey

2014-03-04T23:59:59.000Z

369

Insulin-Pump Therapy for Type 1 Diabetes Mellitus  

Science Journals Connector (OSTI)

...established that the serious microvascular complications of diabetes are linked to the duration and severity of hyperglycemia; there have therefore been renewed efforts to help patients achieve near-normal blood glucose levels. The mainstay of current management of type 1 diabetes is "physiological insulin... A 39-year-old man with type 1 diabetes mellitus is referred for consideration of insulin-pump therapy because of poor glycemic control and episodes of severe hypoglycemia. Insulin-pump therapy can improve blood glucose control but requires a willing and motivated patient.

Pickup J.C.

2012-04-26T23:59:59.000Z

370

Computer-aided diagnosis of diabetic retinopathy: A review  

Science Journals Connector (OSTI)

Abstract Diabetes mellitus may cause alterations in the retinal microvasculature leading to diabetic retinopathy. Unchecked, advanced diabetic retinopathy may lead to blindness. It can be tedious and time consuming to decipher subtle morphological changes in optic disk, microaneurysms, hemorrhage, blood vessels, macula, and exudates through manual inspection of fundus images. A computer aided diagnosis system can significantly reduce the burden on the ophthalmologists and may alleviate the inter and intra observer variability. This review discusses the available methods of various retinal feature extractions and automated analysis.

Muthu Rama Krishnan Mookiah; U. Rajendra Acharya; Chua Kuang Chua; Choo Min Lim; E.Y.K. Ng; Augustinus Laude

2013-01-01T23:59:59.000Z

371

ORGANIC CONTAMINANTS: A BIBLIOGRAPHY  

E-Print Network [OSTI]

·etention bY Por·ous PolYmer adsorbents: APPlicahc•n to for·SamPle tr·ansfer· from adsorbent into a gas chromatograPhicis collected on a dual-adsorbent traP containing Tenax GC

Lepman, S.R.

2014-01-01T23:59:59.000Z

372

Transportation Organization and Functions  

Broader source: Energy.gov [DOE]

Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

373

Metal-doped organic foam  

DOE Patents [OSTI]

Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1982-01-01T23:59:59.000Z

374

Interaction of organic additives with ceramic surfaces in colloidal slurries  

SciTech Connect (OSTI)

Three different dispersants, a low molecular weight compound (aminoalkanol), a polymer (polyelectrolyte) and a block-co-polymer (block polyethylenoxide-polyacrylic acid) were investigated with AFM and rheology in an aqueous system in order to elucidate the influence of the size and structure of the molecule on the dispersion stabilization. The AFM studies indicate that the aminoalkanol gives repulsive forces due to electrostatic repulsion only. The polyelectrolyte seems to stabilize the dispersion with both steric and electrostatic repulsive forces. A new compound that was designed for pure steric stabilization in aqueous media a block-co-polymer consisting of a polar anchor block and a stabilizing neutral chain was investigated for its behavior. The AFM measurements show that it is likely that this compound causes repulsion of silicon nitride surfaces due to steric repulsion only. Rheological measurements of aqueous powder slurries show that the adsorption of the organic additives is of great importance. Due to a more silicon dioxide like acidic surface of the investigated Si{sub 3}N{sub 4}-powder the carboxylate anions of the block-co-polymer adsorb badly. Therefore, no sterically repulsive forces can be built up. This then causes an increase in the slurry`s viscosity.

Sigmund, W.M.; Wang, L.; Sindel, J.; Rotov, M.; Aldinger, F. [Univ. of Stuttgart (Germany). Inst. fuer Nichtmetallische Anorganische Materialien

1997-08-01T23:59:59.000Z

375

Organic sponges for cost-effective CVOC abatement. Final report, September 1992--April 1994  

SciTech Connect (OSTI)

Air contaminated with CVOCs (chlorinated volatile organic compounds) arise from air stripping of ground water or from soil and dual phase vapor extraction. A research program was undertaken to develop sorbents better than activated carbon for remediation. Two such sorbents were found: Dow`s XUS polymer and Rohm and Haas` Ambersorb 563 (carbonaceous). Opportunities exist to further develop sorption and biodegradation technologies.

Flanagan, W.P.; Grade, M.M.; Horney, D.P.; Mackenzie, P.D.; Salvo, J.J.; Sivavec, T.M.; Stephens, M.L.

1994-07-01T23:59:59.000Z

376

Development of New Absorber Materials to Achieve Organic Photovoltaic Commercial Modules with 15% Efficiency and 20 Years Lifetime: Cooperative Research and Development Final Report, CRADA Number CRD-12-498  

SciTech Connect (OSTI)

Under this CRADA the parties will develop intermediates or materials that can be employed as the active layer in dye sensitized solar cells printed polymer systems, or small molecule organic photovoltaics.

Olson, D.

2014-08-01T23:59:59.000Z

377

New Diabetes Testing Technology | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

New Diabetes Testing Technology Sep 2014 Aug 2014 Jul 2014 June 2014 May 2014 Apr 2014 Mar 2014 Feb 2014 Jan 2014 Dec 2013 Nov 2013 Oct 2013 Sep 2013 Aug 2013 Jul 2013 Jun 2013 May...

378

Polymer and Composite Materials Meeting Agenda  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(all times in Eastern Time Zone) (all times in Eastern Time Zone) Start End Activity POC 08:00 08:45 Reception and badging DOE 08:45 09:00 Welcome and meeting objectives / expectations / time horizon for research activities (targets) Erika Sutherland, Sunita Satyapal 09:00 10:00 Polymer/elastomer and composite material science: key issues, knowledge gaps, R&D/testing data needs (40 min speaking, 20 min Q&A) Kevin Simmons 10:00 10:30 Codes and standards requirements - SAE J2579, SAE J2601: knowledge gaps, R&D data/testing needs Mike Veenstra 10:30 11:00 Break 11:00 11:30 Codes and standards requirements -CSA HGV 4, ASME X and B31: knowledge gaps, R&D data/testing needs Aaron Harris 11:30 12:00 Polymer/elastomer Draft R&D Work Plan ideas / Describe

379

Hot Exciton Dissociation in a Conjugated Polymer  

Science Journals Connector (OSTI)

A model has been developed to treat field-assisted ultrafast on-chain dissociation of optical excitations in a conjugated polymer. Conversion of the excess photon energy above the singlet exciton into the vibrational heat bath of a polymer segment is considered as a main source of the energy required for charges to escape from a potential well formed by a superposition of the Coulomb and external electric fields. The calculated yield of carrier photogeneration increases strongly with increasing field but is independent of the temperature in good quantitative agreement with data obtained by Barth et al. [Chem. Phys. Lett. 288, 147 (1998)] on weakly disordered conjugated ladder-type poly-phenylene.

V. I. Arkhipov; E. V. Emelianova; H. Bässler

1999-02-08T23:59:59.000Z

380

Economic assessment of the thin polymer icemaker  

SciTech Connect (OSTI)

We have constructed and tested a small device to produce ice in ice/water mixtures using a cold fluid as the heat sink. The device is a flexible heat exchanger constructed from a thin film of a suitable polymer. When filled with circulating liquid coolant the heat exchanger consists of an inflated series of parallel tubes; Ice forms on the outside in complementary half cylinders. When the circulation in cut off, gravity drains the coolant and the static head of the water bath crushes the tubes, freeing them from the ice which floats to the surface. We here report an economic assessment of this device. In its present form, we find it competitive with existing commercial ice making systems. The analysis also points out two areas where further technical progress could lead to a significant economic advantage for the polymer film ice maker.

Leigh, R.W. [Pratt Inst., Brooklyn, NY (United States)

1992-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Electrical condition monitoring method for polymers  

DOE Patents [OSTI]

An electrical condition monitoring method utilizes measurement of electrical resistivity of an age sensor made of a conductive matrix or composite disposed in a polymeric structure such as an electrical cable. The conductive matrix comprises a base polymer and conductive filler. The method includes communicating the resistivity to a measuring instrument and correlating resistivity of the conductive matrix of the polymeric structure with resistivity of an accelerated-aged conductive composite.

Watkins, Jr., Kenneth S. (Dahlonega, GA); Morris, Shelby J. (Hampton, VA); Masakowski, Daniel D. (Worcester, MA); Wong, Ching Ping (Duluth, GA); Luo, Shijian (Boise, ID)

2008-08-19T23:59:59.000Z

382

Phase behavior of polymers and monomers  

E-Print Network [OSTI]

perspective. Objective The objective of this study is to investigate the phase behavior of monomer- solvent and copolymer-solvent mixtures at elevated pressures. Supercritical ethylene will be the solvent used throughout the experiment to simulate... phase region within the reactor. The transition of the polymers from a single phase solution in the ethylene supercritical fluid solvent into two phases is referred to as the "cloud point. " Phase diagrams produced from the pressure and temperature...

Purifoy, Jonathan Patrick

1998-01-01T23:59:59.000Z

383

Effects of Bond Stretching on Polymer Statistics  

Science Journals Connector (OSTI)

Effects of Bond Stretching on Polymer Statistics ... When a system becomes strained, longer chain end-to-end separations become more probable and the assumptions that go into the Gaussian chain model are no longer valid. ... The associated probability distribution attaches too much weight to the probabilities at larger end-to-end separations, and a statistical analysis based on this distribution would unrealistically overemphasize the contributions of these longer chains. ...

Gary G. Hoffman

1999-08-10T23:59:59.000Z

384

Solitons in synthetic and biological polymers  

SciTech Connect (OSTI)

Solid state and statistical physics applications of soliton mathematics continue to expand rapidly. The present report describes connections between solid state (e.g. synthetic polymer) and biophysics, with strong nonlinearity playing the unifying role. Striking parallels examined include: analytical (as in the case of self-trapping mechanisms); numerical techniques; experimental implications, applications, and techniques. Conventional solid state probes are at last being devoted to biopolymers but their complexity is demanding new extremes and techniques.

Bishop, A.R.

1983-01-01T23:59:59.000Z

385

Comparison of amitriptyline metabolism in hepatocytes from streptozocin-induced diabetic rats and from non-diabetic rats  

Science Journals Connector (OSTI)

Biotransformation of amitriptyline (AMI) was studied at different intervals in freshly isolated hepatocytes from healthy or streptozocin-induced diabetic rats in order to investigate the influence of ... HPLC ana...

F. Coudoré; A. Besson; R. Shrivastava; A. Chevalier…

1997-02-01T23:59:59.000Z

386

Alterations in skeletal muscle arteriolar vasoreactivity during the progression of type 2 diabetes in the Zucker Diabetic Fatty rat  

E-Print Network [OSTI]

Altered vasoreactivity and mechanical properties of skeletal muscle arterioles could impact peripheral insulin resistance and hypertension observed in type 2 diabetes. The purpose was to determine if increased vasoconstrictor reactivity, decreased...

Lesniewski, Lisa AnnMarie

2004-09-30T23:59:59.000Z

387

"Smart" Multifunctional Polymers for Enhanced Oil Recovery  

SciTech Connect (OSTI)

Recent recommendations made by the Department of Energy, in conjunction with ongoing research at the University of Southern Mississippi, have signified a need for the development of 'smart' multi-functional polymers (SMFPs) for Enhanced Oil Recovery (EOR) processes. Herein we summarize research from the period of September 2003 through March 2007 focusing on both Type I and Type II SMFPs. We have demonstrated the synthesis and behavior of materials that can respond in situ to stimuli (ionic strength, pH, temperature, and shear stress). In particular, Type I SMFPs reversibly form micelles in water and have the potential to be utilized in applications that serve to lower interfacial tension at the oil/water interface, resulting in emulsification of oil. Type II SMFPs, which consist of high molecular weight polymers, have been synthesized and have prospective applications related to the modification of fluid viscosity during the recovery process. Through the utilization of these advanced 'smart' polymers, the ability to recover more of the original oil in place and a larger portion of that by-passed or deemed 'unrecoverable' by conventional chemical flooding should be possible.

Charles McCormick; Andrew Lowe

2007-03-20T23:59:59.000Z

388

Penetration of Ciprofloxacin into the Interstitial Space of Inflamed Foot Lesions in Non-Insulin-Dependent Diabetes Mellitus Patients  

Science Journals Connector (OSTI)

...frequently employed for diabetic foot infections is ciprofloxacin...concentrations in infected diabetic foot ulcers by microdialysis...who presented with a diabetic foot infection severe enough to require...patients had the statistical power to detect a 16 intraindividual...

Markus Müller; Martin Brunner; Ursula Hollenstein; Christian Joukhadar; Rainer Schmid; Erich Minar; Herbert Ehringer; Hans Georg Eichler

1999-08-01T23:59:59.000Z

389

Performance and Characterization of Lithium-Ion Type Polymer Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Performance and Characterization of Lithium-Ion Type Polymer Batteries Performance and Characterization of Lithium-Ion Type Polymer Batteries Speaker(s): Myung D. Cho Date: January 18, 2002 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Frank McLarnon A new process for the preparation of lithium-polymer batteries with crosslinked gel-polymer electrolyte will be introduced. The new process employs a thermal crosslinking method rather than cell lamination, and is termed "lithium ion type polymer battery (ITPB)". This thermal crosslinking process has many advantages over the standard lamination method, such as fusing the polymer into the electrodes and better adhesion between the electrolyte and electrodes. The new method results in improved high-temperature stability and a simpler process, as well as the improved

390

Supercomputers help unravel twists in next-generation smart polymers |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Supercomputers help unravel twists in next-generation smart polymers Supercomputers help unravel twists in next-generation smart polymers November 20, 2013 Printer-friendly version Chemists have been looking at polymers and gels for decades to see how these large chains of molecules respond to external stimuli such as heat, pH, temperature, electric fields, light and chemical influences. The scientists seek ways to control the polymers' actions and behaviors for a wide range of applications: drug delivery, medical diagnostics, tissue engineering, electrophoresis and enhanced oil recovery. Certain smart polymers, for instance, rely on heat, water and timing to execute their missions in controlled drug delivery systems. The key to employing a polymer is controlling its lower critical solution temperature (LCST). When reached, the LCST triggers a dramatic

391

Mobile monolithic polymer elements for flow control in microfluidic devices  

DOE Patents [OSTI]

A cast-in-place and lithographically shaped mobile, monolithic polymer element for fluid flow control in microfluidic devices and method of manufacture. Microfluid flow control devices, or microvalves that provide for control of fluid or ionic current flow can be made incorporating a cast-in-place, mobile monolithic polymer element, disposed within a microchannel, and driven by fluid pressure (either liquid or gas) against a retaining or sealing surface. The polymer elements are made by the application of lithographic methods to monomer mixtures formulated in such a way that the polymer will not bond to microchannel walls. The polymer elements can seal against pressures greater than 5000 psi, and have a response time on the order of milliseconds. By the use of energetic radiation it is possible to depolymerize selected regions of the polymer element to form shapes that cannot be produced by conventional lithographic patterning and would be impossible to machine.

Hasselbrink, Jr., Ernest F. (Saline, MI); Rehm, Jason E. (Alameda, CA); Shepodd, Timothy J. (Livermore, CA); Kirby, Brian J. (San Francisco, CA)

2005-11-11T23:59:59.000Z

392

Mobile Monolith Polymer Elements For Flow Control In Microfluidic Systems  

DOE Patents [OSTI]

A cast-in-place and lithographically shaped mobile, monolithic polymer element for fluid flow control in microfluidic devices and method of manufacture. Microfluid flow control devices, or microvalves that provide for control of fluid or ionic current flow can be made incorporating a cast-in-place, mobile monolithic polymer element, disposed within a microchannel, and driven by fluid pressure (either liquid or gas) against a retaining or sealing surface. The polymer elements are made by the application of lithographic methods to monomer mixtures formulated in such a way that the polymer will not bond to microchannel walls. The polymer elements can seal against pressures greater than 5000 psi, and have a response time on the order of milliseconds. By the use of energetic radiation it is possible to depolymerize selected regions of the polymer element to form shapes that cannot be produced by conventional lithographic patterning and would be impossible to machine.

Hasselbrink, Jr., Ernest F. (Saline, MI); Rehm, Jason E. (Alameda, CA); Shepodd, Timothy J. (Livermore, CA); Kirby, Brian J. (San Francisco, CA)

2006-01-24T23:59:59.000Z

393

Electric-field-driven polymer entry into asymmetric nanoscale channels  

E-Print Network [OSTI]

The electric-field-driven entry process of flexible charged polymers such as single stranded DNA (ssDNA) into asymmetric nanoscale channels such as alpha-hemolysin protein channel is studied theoretically and using molecular dynamics simulations. Dependence of the height of the free-energy barrier on the polymer length, the strength of the applied electric field and the channel entrance geometry is investigated. It is shown that the squeezing effect of the driving field on the polymer and the lateral confinement of the polymer before its entry to the channel crucially affect the barrier height and its dependence on the system parameters. The attempt frequency of the polymer for passing the channel is also discussed. Our theoretical and simulation results support each other and describe related data sets of polymer translocation experiments through the alpha-hemolysin protein channel reasonably well.

Narges Nikoofard; Hossein Fazli

2012-02-25T23:59:59.000Z

394

Polyacrylamide polymer viscosity as a function of brine composition  

SciTech Connect (OSTI)

A computer model has been developed which predicts the viscosity of polymer and oil field brine mixtures. The polymers used were Amoco- Sweepaid 103 and Dow- Pusher 500 polyacrylamide polymers. All of the experiments were conducted at 1200 ppM polymer concentration. The computer input consists of the ionic strength of the brine in the mixture and the fraction of that ionic strength due to sodium ions. The computer program makes predictions of viscosity by referencing a family of viscosity curves for various mixtures of sodium chloride and calcium chloride in 1200 ppM polymer solutions. The model has been tested using 59 mixtures of brines and polymers. The ionic strength of the brine in the mixtures varied from 0.0018 to 0.025. The fraction of the brines' total ionic strength due to sodium ions varied from 0.22 to 0.49. The brines consisted predominantly of sodium, potassium, magnesium, calcium, chloride, bicarbonate and sulfate ions.

French, T.R.; Stacy, N.; Collins, A.G.

1981-05-01T23:59:59.000Z

395

Monitoring polymer properties in production wells of Chateaurenard oilfield  

SciTech Connect (OSTI)

A polymer flooding test was conducted in the Chateaurenard field (France) from 1985 to 1989. The test was run on a ten-acre inverted five-spot. A total of 240,000 m{sup 3} of partially hydrolyzed polyacrylamide at a concentration of 1000 ppm was injected followed by an equal volume of solution but at a tapered concentration. A strong response in oil recovery for three of the four producers was observed. This paper reports on an original methodology that was designed for sampling and analyzing the polymer in the effluents of the producing wells. Concentrations and main characteristics of produced polyacrylamide were determined versus injected volume. No degradation of the polymer was detected. A molecular weight fractionation during polymer slug propagation into the reservoir due to adsorption/retention chromatography was observed. The low-polymer concentration of the effluents could be explained by a strong retention of the polymer in the low permeability zones of the reservoir.

Putz, A.G. (Elf Aquitaine, Avenue Larribau, Pau (FR)); Lecourtier, J. (Inst. Francais du Petrole, Avenue Bois-Preau, 92500 Rueil-Malmaison (FR))

1991-01-01T23:59:59.000Z

396

Role of Polymer Segment?Particle Surface Interactions in Controlling Nanoparticle Dispersions in Concentrated Polymer Solutions  

SciTech Connect (OSTI)

The microstructure of particles suspended in concentrated polymer solutions is examined with small-angle X-ray scattering and small-angle neutron scattering. Of interest are changes to long wavelength particle density fluctuations in ternary mixtures of silica nanoparticles suspended in concentrated solutions of poly(ethylene glycol). The results are understood in terms of application of the pseudo-two-component polymer reference interaction site model (PRISM) theory modified to account for solvent addition via effective contact strength of interfacial attraction, {var_epsilon}{sub pc}, in an implicit manner. The combined experimental-theoretical study emphasizes the complex interactions between solvent, polymer, and particle surface that control particle miscibility but also demonstrate that these factors can all be understood in terms of variations of {var_epsilon}{sub pc}.

Kim, So Youn; Zukoski, Charles F. (UIUC)

2014-09-24T23:59:59.000Z

397

Mixed crystal organic scintillators  

DOE Patents [OSTI]

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

398

Surfactant-Polymer Interaction for Improved Oil Recovery  

SciTech Connect (OSTI)

The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

Gabitto, Jorge; Mohanty, Kishore K.

2002-01-07T23:59:59.000Z

399

Design, synthesis, characterization and study of novel conjugated polymers  

SciTech Connect (OSTI)

After introducing the subject of conjugated polymers, the thesis has three sections each containing a literature survey, results and discussion, conclusions, and experimental methods on the following: synthesis, characterization of electroluminescent polymers containing conjugated aryl, olefinic, thiophene and acetylenic units and their studies for use in light-emitting diodes; synthesis, characterization and study of conjugated polymers containing silole unit in the main chain; and synthesis, characterization and study of silicon-bridged and butadiene-linked polythiophenes.

Chen, W.

1997-06-24T23:59:59.000Z

400

“Solar tree”: Exploring new form factors of organic solar cells  

Science Journals Connector (OSTI)

Abstract Organic solar cells have great potential as a clean and renewable solar energy conversion system, due to their low cost materials, ease of production, and lack of harmful emissions. The rapid improvement in organic solar cell performance in recent years has triggered significant interests in developing organic solar cells for commercial applications. Harnessing the unique set of characteristics of organic solar cells, here we demonstrate a new form factor for organic solar cells, a “solar tree” or an electricity-generating artificial tree with organic solar cells as leaves. We first fabricated polymer:fullerene based organic solar cells on flexible plastic substrates that show similar performance to devices on rigid glass substrates using the inverted device structure. Large-area flexible devices were fabricated and cut into palm leaf shapes with an active device area of 6.5 cm2 using a steel rule die. 12 leaf-shaped organic solar cells were then assembled to form a prototype “solar palm tree”. Two different wiring configurations among the devices provided different power delivery modes: a low-voltage, high-current “fan mode” and a high voltage, low-current “LED mode”.

Weiran Cao; Zhifeng Li; Yixing Yang; Ying Zheng; Weijie Yu; Rimza Afzal; Jiangeng Xue

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Bottle-brush polymers as an intermediate between star and cylindrical polymers  

Science Journals Connector (OSTI)

We present a theoretical study of a single bottle-brush molecule, which consists of multiarmed polymer stars grafted densely onto a stiff backbone. Mean-field approximation and a variational approach are used to calculate the dominant trajectories of the grafted chains, the shape of the molecule, and the segment density distribution around the backbone. All these properties are calculated for an arbitrary relationship between the size of the backbone and that of a grafted star. Hence cylindrical comb copolymer brushes and spherically symmetric polymer stars are considered as the limiting cases of the present problem.

N. A. Denesyuk

2003-09-18T23:59:59.000Z

402

Fire Retardant Polymer Nanocomposites: Materials Design and Thermal Degradation Modeling.  

E-Print Network [OSTI]

??Compared to conventional materials, polymer matrix composites (PMCs) have a number of attractive properties, including light weight, easiness of installation, potential to lower system-level cost,… (more)

Zhuge, Jinfeng

2012-01-01T23:59:59.000Z

403

Stable benzimidazole-incorporated porous polymer network for...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stable benzimidazole-incorporated porous polymer network for carbon capture with high efficiency and low cost Previous Next List Muwei Zhang, Zachary Perry, Jinhee Park, Hong-Cai...

404

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas Previous Next List Weigang Lu, Julian P. Sculley, Daqiang Yuan, Rajamani Krishna, Zhangwen Wei,...

405

Building multiple adsorption sites in porous polymer networks...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Building multiple adsorption sites in porous polymer networks for carbon capture applications Previous Next List Weigang Lu, Wolfgang M. Verdegaal, Jiamei Yu, Perla B Balbuena,...

406

High Temperature Polymer Membrane Development at Argonne National...  

Broader source: Energy.gov (indexed) [DOE]

Polymer Membrane Development at Argonne National Laboratory Seong-Woo Choi, Suhas Niyogi, John Kopasz, Romesh Kumar, and Debbie Myers Chemical Engineering Division Argonne National...

407

Versatile polymer film synthesis method invented > Archived News...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Archived News Stories Latest News Versatile polymer film synthesis method invented Imperfect graphene renders 'electrical highways' 'Living vicariously' has marked Gruner's...

408

Hydrogen Production by Polymer Electrolyte Membrane (PEM)Electrolysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

on Giner and Proton Presentation slides and speaker biographies from the DOE Fuel Cell Technologies Office webinar "Hydrogen Production by Polymer Electrolyte Membrane...

409

A tour-de-force in polymer crosslinked aerogels .  

E-Print Network [OSTI]

??"In the quest of building mechanically strong materials with low density and high porosity, polymer crosslinked aerogels stand as the most promising nano-engineered examples. Covalent… (more)

Mulik, Sudhir, 1979-

2008-01-01T23:59:59.000Z

410

Nanopatterns by phase separation of patterned mixed polymer monolayers  

DOE Patents [OSTI]

Micron-size and sub-micron-size patterns on a substrate can direct the self-assembly of surface-bonded mixed polymer brushes to create nanoscale patterns in the phase-separated mixed polymer brush. The larger scale features, or patterns, can be defined by a variety of lithographic techniques, as well as other physical and chemical processes including but not limited to etching, grinding, and polishing. The polymer brushes preferably comprise vinyl polymers, such as polystyrene and poly(methyl methacrylate).

Huber, Dale L; Frischknecht, Amalie

2014-02-18T23:59:59.000Z

411

New Polymer Architectures for Imidazole Solvating groups, Anion...  

Broader source: Energy.gov (indexed) [DOE]

electrode particles conducting carbon particle Gas Phase *Transport of gases and ions through crowded polymer-solid interfaces where the electrolyte mobility is restricted....

412

Polymer Composites Research in the ALM Materials Program | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

merit08warren2.pdf More Documents & Publications Polymer Composites Research in the LM Materials Program Overview Structural Automotive Components from Composite Materials...

413

Polymer injection in poorly consolidated heavy oil reservoirs:.  

E-Print Network [OSTI]

??A number of core flow experiments were conducted with different polymer concentration solutions. The effluents were analyzed to obtain the retardation factors, which was used… (more)

Kumarswamy, S.

2011-01-01T23:59:59.000Z

414

Skin-Like Prosthetic Polymer Surfaces - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mimic skin. ORNL scientists combined superhydrophobic polymer inventions with carbon nanotubes to create a self-cleaning skin-like surface material with the ability to transmit...

415

Polymer-Ceramic MEMS Bimorphs as Thermal Infrared Sensors  

E-Print Network [OSTI]

of thermal expansion between polymers and ceramics. However,of thermal expansion for selected ceramics, metals, andof thermal expansion for selected ceramics, metals, and

Warren, Clinton Gregory

2010-01-01T23:59:59.000Z

416

Crosslinked crystalline polymer and methods for cooling and heating  

DOE Patents [OSTI]

The invention relates to crystalline polyethylene pieces having optimum crosslinking for use in storage and recovery of heat, and it further relates to methods for storage and recovery of heat using crystalline polymer pieces having optimum crosslinking for these uses. Crystalline polymer pieces are described which retain at least 70% of the heat of fusion of the uncrosslinked crystalline polymer and yet are sufficiently crosslinked for the pieces not to stick together upon being cycled above and below the melting point of said polymer, preferably at least 80% of the heat of fusion with no substantial sticking together.

Salyer, Ival O. (Dayton, OH); Botham, Ruth A. (Dayton, OH); Ball, III, George L. (West Carrollton, OH)

1980-01-01T23:59:59.000Z

417

Geothermal: Sponsored by OSTI -- Polymer materials basic research...  

Office of Scientific and Technical Information (OSTI)

Polymer materials basic research needs for energy applications Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us | Admin Log On HomeBasic Search About...

418

Continuous process to produce lithium-polymer batteries  

DOE Patents [OSTI]

Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be over coated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance. 1 fig.

Chern, T.S.H.; Keller, D.G.; MacFadden, K.O.

1998-05-12T23:59:59.000Z

419

Polymer solar cell as an emerging PV technology  

Science Journals Connector (OSTI)

In the presentation, I will present progresses in polymer solar cell in recent years. Advances in material, device structure, morphology are the focus of the talk. ...

Li, Gang

420

Alejandro Briseño: Department of Polymer Science and Engineering...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with Professor Peidong Yang where he focused on inorganicorganic hybrid nanowire solar cells. In 2009, he joined the Department of Polymer Science and Engineering at the...

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Engineering Property Prediction Tools for Tailored Polymer Composite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Tailored Polymer Composite Structures Vehicle Technologies Office Merit Review 2014: Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites...

422

Charge transport in hybrid nanorod-polymer composite photovoltaic cells  

E-Print Network [OSTI]

circuit diagram for a photovoltaic cell under illumination.Polymer Composite Photovoltaic Cells Wendy U. Huynh ‡ ,devices such as photovoltaic cells and light-emitting-

Huynh, Wendy U.; Dittmer, Janke J.; Teclemariam, Nerayo; Milliron, Delia; Alivisatos, A. Paul; Barnham, Keith W.J.

2002-01-01T23:59:59.000Z

423

Understanding Molecular Interactions within Chemically Selective Layered Polymer Assemblies  

SciTech Connect (OSTI)

This work focuses on two broad issues. These are (1) the molecular origin of the chemical selectivity achieved with ultrathin polymer multilayers, and (2) how the viscoelastic properties of the polymer layers are affected by exposure to solvent and analytes. These issues are inter-related, and to understand them we need to design experiments that probe both the energetic and kinetic aspects of interfacial adsorption processes. This project focuses on controling the chemical structure, thickness, morphology and sequential ordering of polymer layers bound to interfaces using maleimide-vinyl ether and closely related alternating copolymerization chemistry and efficient covalent cross-linking reactions that allow for layer-by-layer polymer deposition. This chemistry has been developed during the funding cycle of this Grant. We have measure the equilibrium constants for interactions between specific layers within the polymer interfaces and size-controlled, surface-functionalized gold nanoparticles. The ability to control both size and functionality of gold nanoparticle model analytes allows us to evaluate the average “pore size” that characterizes our polymer films. We have measured the “bulk” viscosity and shear modulus of the ultrathin polymer films as a function of solvent overlayer identity using quartz crystal microbalance complex impedance measurements. We have measured microscopic viscosity at specific locations within the layered polymer interfaces with time-resolved fluorescence lifetime and depolarization techniques. We combine polymer, cross-linking and nanoparticle synthetic expertise with a host of characterization techniques, including QCM gravimetry and complex impedance analysis, steady state and time-resolved spectroscopies.

Gary J. Blanchard

2009-06-30T23:59:59.000Z

424

Fiber Reinforced Polymer Composite Manufacturing - RFI DE-FOA...  

Energy Savers [EERE]

Polymer Composite Manufacturing - RFI Part 2 DE-FOA-0001056: Summary of Responses Clean Energy Manufacturing Innovation Institute for Composite Materials And Structures Webinar...

425

High Temperature Polymer Membrane Development at Argonne National Laboratory  

Broader source: Energy.gov [DOE]

Summary of ANL’s high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

426

Structure of All-Polymer Solar Cells Impedes Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

thin films of semiconducting polymers as a possible alternative to silicon-based solar cells. Such devices would have the advantages of being cheap to produce,...

427

Modeling Cold Start in a Polymer-Electrolyte Fuel Cell  

E-Print Network [OSTI]

conditions used for fuel—cell simulations. 3.12 Values usedFuel Cells . . . . . . . . . . . . . . . . . . . . . . 1.1.1in Polymer Electrolyte Fuel Cells — II. Parametric Study,”

Balliet, Ryan

2010-01-01T23:59:59.000Z

428

Property Prediction Tools for Tailored Polymer Composite Structures...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08smith2.pdf More Documents & Publications Property Prediction Tools for Tailored Polymer...

429

Photoinduced Refractive Index Change of a Photochromic Diarylethene Polymer  

Science Journals Connector (OSTI)

Photoinduced Refractive Index Change of a Photochromic Diarylethene Polymer ... After completion of n-butyllithium addition, the cooling bath was removed. ... Refractive indexes of org. ...

Eunkyoung Kim; Yun-Ki Choi; Myung-Hyun Lee

1999-07-02T23:59:59.000Z

430

Coherent Aspects of Energy Transfer Dynamics in Conjugated Polymers  

Science Journals Connector (OSTI)

Electronic energy transfer is a fundamental process occurring in conjugated polymers subsequent to exciton formation. We report how structural disorder and electronic coupling among...

Scholes, Gregory; Collini, Elisabetta

431

Molecular Weight Effect on the Efficiency of Polymer Solar Cells  

Science Journals Connector (OSTI)

Molecular Weight Effect on the Efficiency of Polymer Solar Cells ... § 1-Material Inc., 2290 Chemin St-François, Dorval, Quebec, H9P 1K2, Canada ...

Chang Liu; Kai Wang; Xiaowen Hu; Yali Yang; Chih-Hao Hsu; Wei Zhang; Steven Xiao; Xiong Gong; Yong Cao

2013-11-01T23:59:59.000Z

432

Diffusion coefficients in trimethyleneoxide containing comb branch polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Diffusion coefficients in trimethyleneoxide containing comb branch polymer Diffusion coefficients in trimethyleneoxide containing comb branch polymer electrolytes Title Diffusion coefficients in trimethyleneoxide containing comb branch polymer electrolytes Publication Type Journal Article Year of Publication 2004 Authors Liu, Gao, Craig L. Reeder, Xiaoguang Sun, and John B. Kerr Journal Solid State Ionics Volume 175 Pagination 781-783 Keywords comb branch polyethers, conductivity, lithium battery, polymer electrolytes, salt diffusion coefficient, trimethylene oxide Abstract This paper reports on a new comb branch polymer based on trimethylene oxide (TMO) side chains as a polymer electrolyte for potential application in lithium metal rechargeable batteries. The trimethylene oxide (TMO) units are attached to the side chains of a polyepoxide ether to maximize the segmental motion. Lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) salt was used to formulate the polymer electrolyte with the new TMO containing polymers. The new polymer electrolytes show improved salt diffusion coefficients (Ds) and conductivity at ambient and subambient temperature compare to the ethylene oxide (EO) counterpart, whereas performance at high temperature (85 °C) remains the same or is actually worse for salt diffusivity.

433

Organic combustion fingerprints of three common home heating fuels  

SciTech Connect (OSTI)

The paper discusses the chemical structures of three common home heating fuels: wood, coal, and No. 2 fuel oil. GC and GC/MS data are then presented which demonstrate how the thermal destruction of each fuel results in the production of a characteristic group of organic 'fingerprint' compounds. For wood, where the chief structural element is lignin polymer, they are methoxy benzenes, methoxy phenols, and alkyl bezenes. For coal, where the polymer contains more fused-ring structures, the chief products are fused-ring aromatics with structures of three or more rings, benzothiophenes, and to a lesser extent methyl-substituted phenols. For oil, the chief byproducts are unburned droplets of the oil. The paper concludes with a brief discussion of how these fingerprints can be used as apportionment guides in complex airsheds.

Steiber, R.S.

1993-01-01T23:59:59.000Z

434

Semitransparent organic solar cells  

Science Journals Connector (OSTI)

The organic solar cell technology has attracted great interests due to ... low cost solution process capability. Bulk heterojunction organic solar cells offer a potentially much cheaper alternative way to harness...

Furong Zhu

2014-03-01T23:59:59.000Z

436

Stabilization of Hydrophobic Colloidal Dispersions in Water with Amphiphilic Polymers: Application to Integral  

E-Print Network [OSTI]

amphiphilic polymers ("amphipols"). These polymers, derived from poly(acrylic acid), adsorb onto the particleStabilization of Hydrophobic Colloidal Dispersions in Water with Amphiphilic Polymers: Application dispersions of highly hydrophobic colloidal particlesshere three integral membrane proteins of nanometric

437

Optimization of Polymer-based Nanocomposites for High Energy Density Applications  

E-Print Network [OSTI]

polymers are of interest owing to their high inherent electrical resistance, low dielectric loss, flexibility, light weight, and low cost; however, capacitors produced with dielectric polymers are limited to an energy density of ~1-2 J/cc. Polymer...

Barhoumi Ep Meddeb, Amira

2012-07-16T23:59:59.000Z

438

Experimental investigation on the durability of glass fiber-reinforced polymer composites containing nanocomposite  

Science Journals Connector (OSTI)

Nanoclay layers incorporated into polymer/clay nanocomposites can inhibit the harmful penetration of water and chemicals into the material, and thus the durability of glass fiber-reinforced polymer (GFRP) composites should be enhanced by using polymer/clay ...

Weiwen Li, Chunyang Ji, Honggang Zhu, Feng Xing, Jiaxin Wu, Xueli Niu

2013-01-01T23:59:59.000Z

439

Improving the dielectric and piezoelectric properties of screen-printed Low temperature PZT/polymer composite  

E-Print Network [OSTI]

materials, ceramics, polymers and composites. Ceramic piezoelectric materials (e.g. lead zirconate titanate of piezoelectric ceramic powders and a polymer matrix. The polymer used can itself be piezoelectric [3 of ceramic loadings in the composite (e.g.

440

Free Energy Fluctuations for Directed Polymers in Random Media in 1?+?1 Dimension  

E-Print Network [OSTI]

We consider two models for directed polymers in space-time independent random media (the O'Connell-Yor semidiscrete directed polymer and the continuum directed random polymer) at positive temperature and prove their KPZ ...

Borodin, Alexei

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - a-1 polymer chemistry Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

polymer chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: a-1 polymer chemistry Page: << < 1 2 3 4 5 > >> 1 Water-Soluble Polymers from...

442

Organic photosensitive devices  

DOE Patents [OSTI]

The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

Rand, Barry P; Forrest, Stephen R

2013-11-26T23:59:59.000Z

443

Topical hyperbaric oxygen and low energy laser for the treatment of diabetic foot ulcers  

Science Journals Connector (OSTI)

Fifty patients with chronic diabetic foot ulcers in whom conventional therapy had failed ... oxygen alone or in combination with a low power laser are valuable adjuvants to conventional therapy for diabetic foot

Z. Landau

1998-02-01T23:59:59.000Z

444

Development of an mHealth Open Source Platform for Diabetic Foot Ulcers Tele-consultations  

Science Journals Connector (OSTI)

Diabetes is one of the foremost causes of death in many countries and a leading cause of blindness, renal failure, and non-traumatic amputation. Therefore, diabetic foot ulceration and amputation cause extensi...

George E. Dafoulas; Stylianos Koutsias…

2012-01-01T23:59:59.000Z

445

E-Print Network 3.0 - anti-diabetic properties effect Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

number Summary: and aging bone is more susceptible to the loss due to a therapeu- tic treatment with anti-diabetic... increased fracture risk as compared to non-diabetics....

446

E-Print Network 3.0 - adult onset diabetes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

search results for: adult onset diabetes Page: << < 1 2 3 4 5 > >> 1 University of Connecticut Health Center Summary: reasons for patient referral) 1. New onset diabetes: Date of...

447

Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian Population  

E-Print Network [OSTI]

Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian) Amerind Ancestry, Socioeconomic Status and the Genetics of Type 2 Diabetes in a Colombian Population. PLo

Reich, David

448

Diabetic Nephropathy: Worldwide epidemic and effects of current treatment on natural history  

Science Journals Connector (OSTI)

Diabetic nephropathy has become a worldwide epidemic, accounting for approximately one third of all cases of end-stage renal disease. With increasing prevalence of diabetes particularly in Asia, and a global p...

Peter Rossing MD; DMSC

2006-01-01T23:59:59.000Z

449

E-Print Network 3.0 - alloxan diabetic rats Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

diabetic rats Search Powered by Explorit Topic List Advanced Search Sample search results for: alloxan diabetic rats Page: << < 1 2 3 4 5 > >> 1 Glucokinase Is the Likely Mediator...

450

Cardiac dysfunction in the diabetic rat: quantitative evaluation using high resolution magnetic resonance imaging  

E-Print Network [OSTI]

Background: Diabetes is a major risk factor for cardiovascular disease. In particular, type 1 diabetes compromises the cardiac function of individuals at a relatively early age due to the protracted course of abnormal ...

Loganathan, Rajprasad; Bilgen, Mehmet; Al-Hafez, Baraa; Alenezy, Mohammed D.; Smirnova, Irina V.

2006-04-04T23:59:59.000Z

451

e-Polymers 2009, no. 134 http://www.e-polymers.org  

E-Print Network [OSTI]

so produced are both flexible and porous; we now report their swelling efficacies as a function have been used to absorb oil spilled on water [1, 2]. Polypropylene (PP), polyethylene (PE in remediation of oil spills [3]. Among such materials, alkyl acrylate and aromatic polymers with hydrophobicity

North Texas, University of

452

e-Polymers 2008, no. 033 http://www.e-polymers.org  

E-Print Network [OSTI]

with styrene-ethylene/butylene-styrene block copolymer (SEBS) added as a compatibilizer between the two main because of lower densities, easy maintenance and inexpensive prices [1]. Among a large variety of PBMs [2 polymers. A block copolymer SEBS (styrene- ethylene/butylene-styrene) contains in each segment two styrene

North Texas, University of

453

The structure of fillers, polymers and their interfaces in polymer composites using neutron scattering methods  

SciTech Connect (OSTI)

The neutron scattering methods, small-angle neutron scattering and neutron reflectometry, provide information on the structure of polymer composite materials that is not available from other structural probes. The unique capabilities of these methods derive from three factors. First, the length scales probed correspond to polymer conformation, molecular and domain scales and to the characteristic sizes of many fillers. Second, neutrons are able to penetrate relatively thick samples, allowing bulk samples to be measured, and enabling buried interfaces to be studied. This characteristic also allows for the construction of special sample containment needed for studying materials under stress, extremes in pressure and temperature, etc. Third, neutrons readily distinguish between different light elements, and between different isotopes of the same element. The ability to distinguish between hydrogen and deuterium is particularly important in this regard. New ways of exploiting the capabilities of neutrons are opening up with the development of improved sources and instruments in the US and elsewhere. In this talk the author will discuss the basic concepts that give rise to the unique capabilities of neutron scattering, giving several examples of the uses of neutron scattering techniques in the study of polymer composites. The examples will include the morphology of fillers, polymer binders and matrices, interfaces and defect structures.

Hjelm, R.P.

1998-12-01T23:59:59.000Z

454

Organization | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Organization Organization Organization Office of Indian Energy Organizational Structure As a program office at DOE responsible for implementing energy programs, the Office of Indian Energy is structurally organized under the Office of the Under Secretary. This programmatic structure also focuses and facilitates the coordination between the Office of Indian Energy and the other companion program offices such as the Office of Fossil Energy, Office of Electricity and Energy Reliability and Office of Energy Efficiency and Renewable Energy. The Office of Indian Energy is organized around its major statutory functions, namely, policy and programs: Indian Energy Policy. The Office of Indian Energy coordinates participation in the development, refinement, training, and advice

455

Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries  

Science Journals Connector (OSTI)

Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries ... Lithium battery; cathode; polymer; graphene; nanocomposite ...

Zhiping Song; Terrence Xu; Mikhail L. Gordin; Ying-Bing Jiang; In-Tae Bae; Qiangfeng Xiao; Hui Zhan; Jun Liu; Donghai Wang

2012-03-26T23:59:59.000Z

456

E-Print Network 3.0 - active polymer gel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pathogens. The polymers exert their antimicrobial effect... the volume phase transition of polymer ... Source: Shim, Moonsub - Department of Materials Science and...

457

E-Print Network 3.0 - agents polymer modified Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the main features of polymer dissolution where a swollen layer forms... of the solvent penetration (or dissolution rate defined as the amount of polymer ... Source: Stevens...

458

E-Print Network 3.0 - amorphous glassy polymers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the main features of polymer dissolution where a swollen layer forms... of the solvent penetration (or dissolution rate defined as the amount of polymer ... Source: Stevens...

459

E-Print Network 3.0 - azlactone-containing polymers combining...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the main features of polymer dissolution where a swollen layer forms... of the solvent penetration (or dissolution rate defined as the amount of polymer ... Source: Stevens...

460

E-Print Network 3.0 - amorphous polymer field-effect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the main features of polymer dissolution where a swollen layer forms... of the solvent penetration (or dissolution rate defined as the amount of polymer ... Source: Stevens...

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - added polymer chains Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2) polymer chains molecularly dispersed into ceramic matrix. Recently, strength... in the fracture strength of the alumina that is also dependent on the amount of polymer added....

462

E-Print Network 3.0 - autoimmune diabetic nod Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and signaling in bone marrow-derived macrophages at Summary: , University of Jordan, Amman, Jordan Keywords: autoimmunity, cytokines, diabetes complications,...

463

Viscosity model for polydisperse polymer melts  

Science Journals Connector (OSTI)

A simple superposition model was used to define the relationship between molecular weight distribution and shear viscosity for linear polymeric systems. Gel permeation chromatography data for molecular weight distributions were fitted using statistical distribution functions. A simple superposition model was then employed to calculate the shear viscosity for the systems investigated. The effect of polydispersity on the shape of the flow curves was calculated. The simplicity of the model makes feasible its use in numerical simulations of complex geometries as encountered in polymer processing equipment. The present study also sheds some light on the relationship between entanglement and disentanglement phenomena in polymeric systems.

D. Nichetti; I. Manas-Zloczower

1998-01-01T23:59:59.000Z

464

Fiber Reinforced Polymer Composite Manufacturing Workshop  

Office of Energy Efficiency and Renewable Energy (EERE)

A workshop on Fiber Reinforced Polymer (FRP) Composite Manufacturing (held January 13, 2014, in Arlington, VA) brought together stakeholders from industry and academia to discuss manufacturing of composites. The workshop explored emerging FRP composite market applications in clean energy and barriers to the development and widespread commercial use of these lightweight, high-strength and high-stiffness materials. Improving the manufacturing speed and quality-and reducing their manufacturing costs-could accelerate their use in automotive, wind, compressed gas storage and other clean energy and industrial applications.

465

Mesoscopic theory of the viscoelasticity of polymers  

E-Print Network [OSTI]

We have advanced our previous static theory of polymer entanglement involving an extended Cahn-Hilliard functional, to include time-dependent dynamics. We go beyond the Gaussian approximation, to the one-loop level, to compute the frequency dependent storage and loss moduli of the system. The three parameters in our theory are obtained by fitting to available experimental data on polystyrene melts of various chain lengths. This provides a physical representation of the parameters in terms of the chain length of the system. We discuss the importance of the various terms in our energy functional with respect to their contribution to the viscoelastic response of the polymeric system.

S. M. Chitanvis

1999-01-26T23:59:59.000Z

466

The interaction of various polymers with water  

E-Print Network [OSTI]

water content. The glass transition temperature was taken as the inflection point in the heat capacity curve (Figure 3). The uncertainty in the glass points was rather high (x20'C) mainly because of the small change in heat capacities -1 (6C = . 03... water/g methylcellulose) 17 Y=. 10 Y=. 15 10 50 70 90 110 T ( c) Fig. 3. C (arbitrary units) versus temperature at two water p contents, Y, for methylcellulose. Inflection in curve is the glass transition region of the polymer-water system...

Quock, Billy

1976-01-01T23:59:59.000Z

467

Conformational properties of bottle-brush polymers  

Science Journals Connector (OSTI)

General and renormalized perturbation theories are used to study the conformational properties of a bottle-brush molecule, composed of multiarmed polymer stars grafted regularly onto a flexible backbone. The end-to-end distances of the backbone and of an arm of the middle star are calculated within the first order of perturbation theory. For the high grafting densities of stars, the calculated expressions are generalized with the help of the scaling arguments to give the equivalent power laws. According to these laws, the molecule may adopt a sequence of three different conformations (star-rod-coil) as the length of the backbone grows.

N. A. Denesyuk

2003-05-27T23:59:59.000Z

468

First-principles simulations of exciton diffusion in organic semiconductors  

Science Journals Connector (OSTI)

Exciton diffusion is crucial for the performance of organic semiconductors in photovoltaic and solid state lighting applications. We propose a first-principles approach that can predict exciton dynamics in organic semiconductors. The method is based on time-dependent density functional theory to describe the energy and many-body wave functions of excitons. Nonadiabatic ab initio molecular dynamics is used to calculate phonon-assisted transition rates between localized exciton states. Using Monte Carlo simulations, we determine the exciton diffusion length, lifetime, diffusivity, and harvesting efficiency in poly(3-hexylthiophene) polymers at different temperatures, which agree very well with the experiments. We find that exciton diffusion is primarily determined by the density of states of low-energy excitons. A widely speculated diffusion mechanism, namely an initial downhill migration followed by thermally activated migration, is confirmed and elucidated by the simulations. Some general guidelines for designing more efficient organic solar cells are obtained from the simulations.

Xu Zhang; Zi Li; Gang Lu

2011-12-22T23:59:59.000Z

469

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1984-01-01T23:59:59.000Z

470

Detection and classification of retinal lesions for grading of diabetic retinopathy  

Science Journals Connector (OSTI)

Diabetic Retinopathy (DR) is an eye abnormality in which the human retina is affected due to an increasing amount of insulin in blood. The early detection and diagnosis of DR is vital to save the vision of diabetes patients. The early signs of DR which ... Keywords: Classification, Cotton wool spots, Diabetic retinopathy, Haemorrhage, Hard exudates, Microaneurysms, NPDR, m-Mediods

M. Usman Akram; Shehzad Khalid; Anam Tariq; Shoab A. Khan; Farooque Azam

2014-02-01T23:59:59.000Z

471

Identification and classification of microaneurysms for early detection of diabetic retinopathy  

Science Journals Connector (OSTI)

Diabetic retinopathy is a progressive eye disease which may cause blindness if not detected and treated in time. The early detection and diagnosis of diabetic retinopathy is important to protect the patient's vision. The accurate detection of microaneurysms ... Keywords: Classification, Diabetic retinopathy, Medical image processing, Microaneurysms, m-Mediods

M. Usman Akram; Shehzad Khalid; Shoab A. Khan

2013-01-01T23:59:59.000Z

472

Process for removing polymer-forming impurities from naphtha fraction  

DOE Patents [OSTI]

Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment. 2 figs.

Kowalczyk, D.C.; Bricklemyer, B.A.; Svoboda, J.J.

1983-12-27T23:59:59.000Z

473

Materials comprising polydienes and hydrophilic polymers and related methods  

DOE Patents [OSTI]

Materials prepared from polydienes, such as poly(cyclohexadiene), and hydrophilic polymers, such as poly(alkylene oxide), are described. Methods of making the materials and their use in fuel cell membranes, batteries, breathable chemical-biological protective materials, and templates for sol-gel polymerization are also provided. The materials can be crosslinked and sulfonated, and can include copolymers and polymer blends.

Mays, Jimmy W. (Knoxville, TN); Deng, Suxiang (Knoxville, TN); Mauritz, Kenneth A. (Hattiesburg, MS); Hassan, Mohammad K. (Hattiesburg, MS); Gido, Samuel P. (Hadley, MA)

2011-11-22T23:59:59.000Z

474

Thermal And Thermo-Mechanical Modelling of Polymer Overmoulded Electronics  

E-Print Network [OSTI]

electronics for use in the demanding automotive environment. A two shot moulding technology will protect of electronics within polymer materials is of great interest to the automotive industry as a means to protectThermal And Thermo-Mechanical Modelling of Polymer Overmoulded Electronics F. Sarvar1 , D. C

Paris-Sud XI, Université de

475

Heats of Formation of Energetic Oxetane Monomers and Polymers  

SciTech Connect (OSTI)

Energetic oxetane polymers have shown promise as performance-enhancing ingredients in gun and missile propellants. In order to correctly predict the performance of energetic materials containing these polymers, it is important to have accurate, experimentally determined values for the polymer heats of formation ({Delta}H{sub f}). In support of a theoretical study on gun propellant performance, heats of combustion were experimentally determined for a series of oxetane polymers and monomers (see below) using combustion calorimetry, and from these, {Delta}H{sub f} values were calculated. Polymers included BAMO/AMMO, BAMO/NMMO (polyol and TPE), and BNMO/NMMO mixtures. In order to calculate the {Delta}H{sub f} of the polymers from heat of combustion data, a number of assumptions were made regarding the polymer structure and molecular weight. A comparison of the {Delta}H{sub f} values for the monomers and polymers were made, and these values were compared to heats of formation measured elsewhere.

Schmidt, R D; Manser, G E

2001-03-21T23:59:59.000Z

476

Legendre transform in the thermodynamics of flowing polymer solutions  

Science Journals Connector (OSTI)

We propose a Legendre transform linking two different choices of nonequilibrium variables (viscous pressure tensor and configuration tensor) in the thermodynamics of flowing polymer solutions. This may avoid some current confusions in the analysis of thermodynamic effects in polymer solutions under flow.

J. Casas-Vázquez; L. F. del Castillo; D. Jou; M. Criado-Sancho

2001-04-11T23:59:59.000Z

477

ADVANCED NANOIMPRINT TECHNIQUE FOR MULTILAYER STRUCTURES AND FUNCTIONAL POLYMER APPLICATIONS  

E-Print Network [OSTI]

................................................................................ 72 5.2.1 Solvent developing and reversal nanoimprint for PMMA nanowire ........................................................... 73 5.2.2 Lift-off for functional polymer nanowire ....................... 75 5.3 Summary...-demolding in nanoimprint. ...................................... 31 16 (a) Schematic of fabricating multilayer polymer structures by bonding with a thin adhesive layer; (b) Three-layer PMMA microstructure bonded by a thin SU-8 adhesive layer...

Park, Hyunsoo

2010-07-14T23:59:59.000Z

478

Photo-mechanical patterning with light activated polymers.  

SciTech Connect (OSTI)

Light activated polymers, which are capable of mechanically responding to light, promise to offer exciting, innovative, and unique material capabilities. Such materials include: photo-radical mediated cleavage and reformation of the polymer backbone in cross-linked elastomers that results in local stress relaxation; photo-switching cross-links in shape memory polymers; and photo-isomerization of azobenzene groups contained in liquid crystal elastomers. In this paper, using our recent material model that couples multiphysical processes involved in light-activated polymers, we demonstrate that a variety of patterns can be created on light activated polymer thin films when coupling mechanical deformation with light irradiation. Here, the polymer thin film is first stretched uniaxially or biaxially. Light is then irradiated on the surface of the thin film. After light irradiation, removal external load partially recovers the initial stretching of the polymer thin film and induces patterns. The variation of the geometry of the patterns can be controlled by a variety of parameters such as initial stretching, light intensity, etc. Photo-patterning with light activated polymer therefore offers a novel way to create surface patterns.

Long, Kevin N.; Qi, H. Jerry (University of Colorado, Boulder, CO); Dunn, Martin L. (University of Colorado, Boulder, CO)

2010-11-01T23:59:59.000Z

479

The Future of Material Science & Engineering A Polymer Industry Perspective  

E-Print Network [OSTI]

Polymers6 We're We've Been US Production of Synthetic Polymers (semi-log scale) DuPont, 1994 Hollywood Insulation Phenol-Formaldehyde Electrical Housings ~10y 1920s Antifreeze Polysulfide Rubber Rocket Fuel ~10y 1920s Rubber Substitute IR, SBR, NBR, etc. Tires & Rubber goods ~ 5y 1920s Coatings PMA, PMMA Glazing

Li, Mo

480

Microporous Patterned Electrodes for Color-Matched Electrochromic Polymer Displays  

E-Print Network [OSTI]

Microporous Patterned Electrodes for Color-Matched Electrochromic Polymer Displays Pierre of electroactive and conducting polymers offers new opportunities for the design of materials for electrochromic the most promising electrochromic (EC) properties. Here, we report the use of highly porous metallized

Tanner, David B.

Note: This page contains sample records for the topic "diabetes organic polymers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Appendix A: The Names of Polymers and Polymeric  

E-Print Network [OSTI]

or methylpentene polymethylpentene vinyl chloride poly(vinyl chloride) co-aminocaproic poly(co-aminocaproic acid MATERIALS For homopolymers Monomer name Polymer name X polyX XY poiy(XY) for example ethylene polyethylene acid) [nylon 6] Where the monomer name consists of two words, it should be bracketed in the polymer

Hall, Christopher

482

Hybrid Silicon Nanocone-Polymer Solar Cells Sangmoo Jeong,  

E-Print Network [OSTI]

alternative energy solution. KEYWORDS: Nanotexture, solar cell, heterojunction, conductive polymer, light solar cell.1 Conventional Si solar cells have p-n junctions inside for an efficient extraction of lightHybrid Silicon Nanocone-Polymer Solar Cells Sangmoo Jeong, Erik C. Garnett, Shuang Wang, Zongfu Yu

Cui, Yi

483

Polymer Collapse, Protein Folding, and the Percolation Threshold  

E-Print Network [OSTI]

Polymer Collapse, Protein Folding, and the Percolation Threshold HAGAI MEIROVITCH University (Macromolecules 1989, 22, 3986­3997) to study protein folding, where H and P are the hydrophobic and polar amino; computer simulation; collapse transition; protein folding Introduction The behavior of dilute polymer

Meirovitch, Hagai

484

Membrane processes relevant for the polymer electrolyte fuel cell  

E-Print Network [OSTI]

Membrane processes relevant for the polymer electrolyte fuel cell Aleksander Kolstad Chemical. The important aspects concerning the Polymer Electrolyte Membrane Fuel Cell, more commonly known as Proton Exchange Membrane Fuel Cell (PEMFC), have been studied in two separate parts. Part 1 of the thesis

Kjelstrup, Signe

485

Stability of polymer binders in Li-O2 batteries  

SciTech Connect (OSTI)

A number of polymers with various chemical structures were studied as binders for air electrodes in Li-O2 batteries. The nature of the polymer significantly affects the binding properties in the carbon electrodes thus altering the discharge performance of Li-O2 batteries. Stability of polymers to the aggressive reduced oxygen species generated during discharge was tested by ball milling them with KO2 and Li2O2, respectively. Most of the polymers decomposed under these conditions and mechanisms of the decompositions are proposed for some of the polymers. Polyethylene was found to have excellent stability and is suggested as robust binder for air electrodes in Li-O2 batteries.

Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Li, Xiaohong S.; Zhang, Jiguang

2013-06-24T23:59:59.000Z

486

Two examples of organic opto-electronic devices: Light emitting diodes and solar cells  

Science Journals Connector (OSTI)

Organic and polymeric (plastic) opto-electronic devices have been developed over the past decade and some of them have made the leap from the research laboratory to commercial use. We present a simple and inexpensive method of fabricating organic light emitting diodes and organic photovoltaic cells. The devices are fabricated by the deposition of solid films based on the fluorescent polymer MEH:PPV using the spin-coating technique. The films were sandwiched between electrodes one of which was made of Bi-Pb-Cd-Sn alloy. An overview of these two devices is also provided.

J. L. Maldonado; G. Ramos-Ortíz; M. L. Miranda; S. Vázquez-Córdova; M. A. Meneses-Nava; O. Barbosa-García; M. Ortíz-Gutiérrez

2008-01-01T23:59:59.000Z

487

NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and with the exception of CPVC, no leachate was observed in the NGS from any of the polymers studied. The testing shows no major concerns for compatibility over the short duration of these tests but does indicate that longer duration exposure studies are warranted, especially for Tefzel. However, the physical changes experienced by Tefzel in the improved solvent were comparable to the physical changes obtained when Tefzel is placed in CSSX baseline solvent. Therefore, there is no effect of the improved solvent beyond those observed in CSSX baseline solvent.

Fondeur, F.; Peters, T.; Fink, S.

2012-01-17T23:59:59.000Z

488

Nonequilibrium behavior of thin polymer films  

Science Journals Connector (OSTI)

The rheological behavior of 100-nm-thick polystyrene films cast from various solvents was examined using an electric field to weakly perturb the free surface of the polymer melt. The effective viscosity and residual stresses of the as-spun films are seen to strongly depend on the properties of the casting solvent and the solvent quality. Both effects are explained in terms of the coil dimension at the solvent-polymer composition at which the film vitrifies. The more compact chains in a near-?-solvent are less entangled and less deformed when quenched to the dry melt compared to the more swollen chains in an athermal solution. Despite chain conformations that are further from equilibrium for the ?-solvent cast chains, these films have reduced stored stresses compared to the chains cast in films from athermal solvents. A more detailed analysis of the data suggests that the formation of a surface-near region with more strongly deformed chains during spin coating. Since thermal equilibration of spin-cast high-molecular-weight films is unpractical, solvent vapor annealing was used to equilibrate films on timescale of a few hours.

Katherine R. Thomas; Alexis Chenneviere; Günter Reiter; Ullrich Steiner

2011-02-28T23:59:59.000Z

489

Solid-polymer-electrolyte fuel cells  

SciTech Connect (OSTI)

A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

Fuller, T.F.

1992-07-01T23:59:59.000Z

490

High Efficiency Organic Solar Cells: December 16, 2009 - February 2, 2011  

SciTech Connect (OSTI)

Details on the development of novel organic solar cells incorporating Trimetasphere based acceptors are presented including: baseline performance for Lu-PCBEH acceptor blended with P3HT demonstrated at 4.89% PCE exceeding the 4.5% PCE goal; an increase of over 250mV in Voc was demonstrated for Lu-PCBEH blended with low band gap polymers compared to a comparable C60-PCBM device. The actual Voc was certified at 260mV higher for a low band gap polymer device using the Lu-PCBEH acceptor; and the majority of the effort was focused on development of a device with over 7% PCE. While low current and fill factors suppressed overall device performance for the low band gap polymers tested, significant discoveries were made that point the way for future development of these novel acceptor materials.

Walker, K.; Joslin, S.

2011-05-01T23:59:59.000Z

491

Glycemic Control and Excess Mortality in Type 1 Diabetes  

Science Journals Connector (OSTI)

...status with respect to renal impairment (normoalbuminuria, microalbuminuria, macroalbuminuria, or stage 5 chronic kidney disease) to model F. All tests were two-tailed and conducted at a significance level of 0.05. Analyses of mortality according to renal disease status among patients with type 1 diabetes... In this study, patients with type 1 diabetes and a glycated hemoglobin level of 6.9% or lower (?52 mmol per mole) were found to have a risk of death from any cause or from cardiovascular causes that was twice as high as that for matched controls.

Lind M.; Svensson A.-M.; Kosiborod M.

2014-11-20T23:59:59.000Z

492

Organic Membranes for Energy Conversion and "Green" Manufacturing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organic Membranes for Energy Conversion and "Green" Manufacturing Organic Membranes for Energy Conversion and "Green" Manufacturing Speaker(s): John Kerr Date: January 17, 2002 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Cynthia Tast Organic materials are central to the operation of energy conversion devices such as lithium batteries and fuel cells. Use of organic polymer membranes has been well established in the chlor-alkali and separations industries for several decades now. New applications such as light emitting diodes for displays and area lighting, organic photovoltaics for solar conversion and electrochromics illustrate the growing importance of organic materials in energetic applications. Understanding the operation of these materials, their limitations and advantages is of major importance to the successful

493

APS Users Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

APSUO APSUO By-Laws Steering Commitee Employment Meetings Compton Award Franklin Award APS Users Organization The APSUO is responsible for advising the APS Associate Laboratory Director in the following areas: The Organization will serve as an advocacy group for the Facility and its user community. The Organization will provide advice to the ALD on matters affecting the user community. The Organization will assure good communication between the APS user community and the APS management. APSUO By-Laws The by-laws upon which the APS User Organization is based. List of Steering Committee Members Steering committee for the APS Users Organization. Employment Bulletin Board APS-related employment opportunities. APSUO Steering Committee Meetings Minutes and presentations from the APSUO meetings.

494

Cascade Organic Solar Cells  

Science Journals Connector (OSTI)

Cascade Organic Solar Cells ... Multiple factors control the efficiency of organic solar cells, making it difficult to use single donor or acceptor materials to balance the, often opposing, material properties required to optimize device performance. ... We demonstrate planar organic solar cells consisting of a series of complementary donor materials with cascading exciton energies, incorporated in the following structure: glass/indium-tin-oxide/donor cascade/C60/bathocuproine/Al. ...

Cody W. Schlenker; Vincent S. Barlier; Stephanie W. Chin; Matthew T. Whited; R. Eric McAnally; Stephen R. Forrest; Mark E. Thompson

2011-09-02T23:59:59.000Z

495

Modern Organic Chemistry  

Science Journals Connector (OSTI)

... to organic chemistry, tautomerism, glutaconic acids, the constitution of urea, the menthone chemistry, carene, hydroxymethylenecamphor, squalene, insulin, the production of acetic acid from cellulose by anaerobic fermentation ...

J. R.

1928-06-02T23:59:59.000Z

496

EMSL - soil organic matter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

soil-organic-matter en Structures and Stabilities of (MgO)n Nanoclusters. http:www.emsl.pnl.govemslwebpublicationsstructures-and-stabilities-mgon-nanoclusters

497

Organic Light Emitting Diodes: materials, device structures and light extraction  

Science Journals Connector (OSTI)

Organic Light Emitting Devices (OLEDs) are presented with particular emphasis on materials, device structures and strategies to improve light extraction. For the fabrication of efficient OLEDs, two types of electroluminescent materials are used (small molecules and polymers) with efficiencies and lifetimes which are now acceptable for small size or low content information displays. Two main approaches are described to enhance external efficiency, one is based on direct modification of the species emission and the other on modification of emitted guided modes propagation within the device. The features of the different approaches are evidenced through examples of devices reported in the literature.

B. Geffroy; L. Rocha

2009-01-01T23:59:59.000Z

498

Organic vapor jet printing system  

SciTech Connect (OSTI)

An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

Forrest, Stephen R

2012-10-23T23:59:59.000Z

499

Automation of organic elemental analysis  

Science Journals Connector (OSTI)

Automation of organic elemental analysis ... Describes the development and design of an apparatus for automated organic elemental analysis. ...

Velmer B. Fish

1969-01-01T23:59:59.000Z

500

Diabetic Healthcare Awareness in Malaysia: The Role of Poster as a Communication Medium  

Science Journals Connector (OSTI)

Abstract Poster has been a medium of communication in public healthcare since World War I and II. During then, Europe, America and Soviet used poster to channel the minds of their society towards one common insight. From this iconic scenario, the term poster propaganda has emerged. To date, posters have been used extensively in many areas especially healthcare education. Poster in healthcare as particular is the tool and medium for health-behaviour change to attain healthcare awareness. In Malaysia, numerous diabetic campaigns on diabetic healthcare awareness with the aid of posters have been held throughout the country. The use of poster by the government is meant to trigger the public on the hazardous alarm of diabetes. However, despite various efforts from government to the public through diabetes posters, Malaysian diabetes statistic still increases drastically from 1.6 million in 2011 to 2.6 million in 2012. The huge increase in statistic invites an enquiry on the role of diabetic posters as a communication medium on diabetic healthcare awareness. This study explores public opinions through observation and interview in three different regions to describe and interpret public opinion on current diabetic posters. Beneficial entries from this study would go to the Ministry of Health Malaysia, Malaysian Diabetic Society and the public towards a better understanding on the role of diabetic poster as a communication medium in diabetic healthcare awareness.

Salinatin Mohamad Saleh; Mustaffa Halabi Hj. Azahari; Adzrool Idzwan Ismail

2013-01-01T23:59:59.000Z