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Sample records for di genova i-16146

  1. Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in...

    Office of Scientific and Technical Information (OSTI)

    Chimica Fisica, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy). E-mail: cfmet@chimica.unige.it Dipartimento di Chimica e Chim. Ind., Sezione di Chimica Fisica, ...

  2. Di?partment o

    Office of Legacy Management (LM)

    ,Di?partment o f E n e r g y ' ' ' : . ' ~' Washington, DC 20585 ., .* -,, : ', ," FEE 17.,1995' , :' ' , ,,- ',/ 'he Honorable Larry.Guidt ' ' : X 1455 W., 126th Street lawthorne; California 90250 1 _. _ tear.Mayor Guidi: ; ..,, _ ietretary of Energy Hazel O'Leary,has announced a new approach to openness.in :he Department .of Energy (DOE) and its communications wifh,the public: In ; - upport of thts initiative, we are ,p;T.eased to forward the enclosed,,information .,~ -elated to the

  3. Politecnico di Milano | Open Energy Information

    Open Energy Info (EERE)

    Politecnico di Milano Jump to: navigation, search Name: Politecnico di Milano Place: Milan, Italy Zip: 20133 Sector: Solar Product: Milan-based technical university. The institute...

  4. Emcore DI Semicon JV | Open Energy Information

    Open Energy Info (EERE)

    Place: Korea (Republic) Product: Emcore and DI Semicon combine forces in a South Korean joint venture to manufacture PV systems. References: Emcore & DI Semicon JV1 This...

  5. Interporto di Padova | Open Energy Information

    Open Energy Info (EERE)

    Italy Zip: 35127 Product: Based in Italy, Interporto is a center for the integrated logistics and intermodality. References: Interporto di Padova1 This article is a stub. You...

  6. DI-MGMT-81861 DOE Changes Version | Department of Energy

    Energy Savers [EERE]

    DI-MGMT-81861 DOE Changes Version DI-MGMT-81861 DOE Changes Version PDF icon DI-MGMT-81861 IPMR DOE Version 20140211 Chgs.pdf More Documents & Publications Integrated Program...

  7. Facon Electronica di Facconi Massimo C | Open Energy Information

    Open Energy Info (EERE)

    Facon Electronica di Facconi Massimo C Jump to: navigation, search Name: Facon Electronica di Facconi Massimo & C Place: Leno, Italy Zip: 25024 Product: Leno-based electrical...

  8. NREL: Energy Analysis - Nicholas DiOrio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selected publications Pratt,J., P. Axelrad, K. Larson, B. Lesage, R. Gerren, and N. DiOrio. "Satellite Clock Bias Estimation for iGPS." GPS Solutions 17 (2013): 381-89. Bershenyi, ...

  9. Exclusive e+e-, di-photon and di-jet production at the Tevatron

    SciTech Connect (OSTI)

    Terashi, Koji; /Rockefeller U.

    2007-05-01

    Results from studies on exclusive production of electron-position pair, di-photon, and dijet production at CDF in proton-antiproton collisions at the Fermilab Tevatron are presented. THe first observation and cross section measurements of exclusive e{sup +}e{sup -} and di-jet production in hadron-hadron collisions are emphasized.

  10. Batteries & Fuel Cells - Research Thrust Leader > Frank DiSalvo...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frank DiSalvo fjd3@cornell.edu Research The DiSalvo Group's research focuses on the synthesis, characterization and potential applications of new solid state materials. Current...

  11. Distributed Solar Power Ltd Di S P | Open Energy Information

    Open Energy Info (EERE)

    Solar Power Ltd Di S P Jump to: navigation, search Name: Distributed Solar Power Ltd (Di.S.P) Place: Yokneam, Israel Zip: 20692 Sector: Solar Product: Distributed Solar Power...

  12. Ponte di Archimede International S P A | Open Energy Information

    Open Energy Info (EERE)

    Ponte di Archimede International S P A Jump to: navigation, search Name: Ponte di Archimede International S P A Address: Viale Libert IS 515 Place: Messina Zip: 98121 Region: Italy...

  13. Di-hadron production at Jefferson Lab

    SciTech Connect (OSTI)

    Anefalos Pereira, Sergio; et. al.,

    2014-10-01

    Semi-inclusive deep inelastic scattering (SIDIS) has been used extensively in recent years as an important testing ground for QCD. Studies so far have concentrated on better determination of parton distribution functions, distinguishing between the quark and antiquark contributions, and understanding the fragmentation of quarks into hadrons. Hadron pair (di-hadron) SIDIS provides information on the nucleon structure and hadronization dynamics that complement single hadron SIDIS. Di-hadrons allow the study of low- and high-twist distribution functions and Dihadron Fragmentation Functions (DiFF). Together with the twist-2 PDFs ( f1, g1, h1), the Higher Twist (HT) e and hL functions are very interesting because they offer insights into the physics of the largely unexplored quark-gluon correlations, which provide access into the dynamics inside hadrons. The CLAS spectrometer, installed in Hall-B at Jefferson Lab, has collected data using the CEBAF 6 GeV longitudinally polarized electron beam on longitudinally polarized solid NH3 targets. Preliminary results on di-hadron beam-, target- and double-spin asymmetries will be presented.

  14. Di-interstitial defect in silicon revisited

    SciTech Connect (OSTI)

    Londos, C. A.; Antonaras, G.; Chroneos, A.; Department of Materials, Imperial College London, London SW7 2BP

    2013-11-21

    Infrared spectroscopy was used to study the defect spectrum of Cz-Si samples following fast neutron irradiation. We mainly focus on the band at 533 cm{sup ?1}, which disappears from the spectra at ?170 C, exhibiting similar thermal stability with the Si-P6 electron paramagnetic resonance (EPR) spectrum previously correlated with the di-interstitial defect. The suggested structural model of this defect comprises of two self-interstitial atoms located symmetrically around a lattice site Si atom. The band anneals out following a first-order kinetics with an activation energy of 0.88 0.3 eV. This value does not deviate considerably from previously quoted experimental and theoretical values for the di-interstitial defect. The present results indicate that the 533 cm{sup ?1} IR band originates from the same structure as that of the Si-P6 EPR spectrum.

  15. Basic ReseaRch DiRections

    National Nuclear Security Administration (NNSA)

    Basic ReseaRch DiRections for User Science at the National Ignition Facility Report on the National Nuclear Security Administration - Office of Science Workshop on Basic Research Directions on User Science at the National Ignition Facility BASIC RESEARCH DIRECTIONS FOR USER SCIENCE AT THE NATIONAL IGNITION FACILITY Report on the National Nuclear Security Administration (NNSA) - Office of Science (SC) Workshop on Basic Research Directions on User Science at the National Ignition Facility Chairs:

  16. ORISE: Recent Graduate Research Experiences - Nicholas DiLucia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nicholas DiLucia Computer engineer utilizes skills from NETL to update lab website Nicholas DiLucia Nicholas DiLucia returned to the National Energy and Technology Laboratory for the fourth year in a row to engage in website development. His previous internship experiences at the lab helped him succeed in courses at the Univ. of Pittsburgh, where he graduated in April 2012. When Nicholas DiLucia graduated from the Univ. of Pittsburgh in April 2012, he was excited to have a place to go to develop

  17. Kathy DiBennardi | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kathy DiBennardi Executive Secretary Argonne National Laboratory 9700 South Cass Avenue Building 240 - Wkstn. 4D11 Argonne IL, 60439 630-252-8600 dibennar

  18. TianDi Growth Capital | Open Energy Information

    Open Energy Info (EERE)

    Venture capital investor interested in projects in Wind energy, Electric vehicles, Energy-efficient lighting, Biodiesel and Clean water. References: TianDi Growth Capital1...

  19. DiTour 3.1

    Energy Science and Technology Software Center (OSTI)

    2015-06-30

    There is a need for software that allows a tour guide to present different tracks of slides and then return to the default slide show automatically upon completion. A mobile solution is needed for trade shows. DiTour is an iPad/iPhone app that pulls presentation content from a website, stores it on the device and presents it on a connected display. A tour guide can select a track to present and it will automatically return tomore » the default track after a timeout. It offers a mobile solution which is ideal for trade shows.« less

  20. Anion-controlled assembly of silver-di(aminophenyl)sulfone coordinatio...

    Office of Scientific and Technical Information (OSTI)

    Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ... Title: Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ...

  1. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Presentation given at the ...

  2. ORISE: Recent Graduate Research Experiences - Nicholas DiLucia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... grade due to the prior exposure to C, a very similar programming language to JAVA. This time around, DiLucia will not be headed back to a classroom, since he already graduated. ...

  3. Reducing the Particulate Emission Numbers in DI Gasoline Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Particulate Emission Numbers in DI Gasoline Engines Reducing the Particulate Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding air/fuel zones richer than stoichiometric and temperatures that promote particle formation deer10_klindt.pdf (866.03 KB) More Documents & Publications Bosch Powertrain Technologies Vehicle Emissions Review - 2012 Ethanol Effects on Lean-Burn and

  4. Microsoft Word - SWPF-15-DI-001_R1_Construction Turnover to C...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Construction Turnover to Testing and Commissioning Oversight SWPF-15-DI-001, Rev. 1 September, 2015 SWPF-15-DI-001 Revision 1 Page 3 of 29 REV A Internal Review by DOE Construction ...

  5. Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers...

    Office of Scientific and Technical Information (OSTI)

    Selective Cleavage of C-O Bonds in Di-aryl Ethers in Aqueous Phase Citation Details In-Document Search Title: Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers in ...

  6. Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd...

    Open Energy Info (EERE)

    Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd Jump to: navigation, search Name: Xiang Ge Li La Xian Mai Di He Hydro Power Development Co., Ltd. Place: Yunnan...

  7. ParaDiS-FEM dislocation dynamics simulation code primer (Technical...

    Office of Scientific and Technical Information (OSTI)

    ParaDiS-FEM dislocation dynamics simulation code primer Citation Details In-Document Search Title: ParaDiS-FEM dislocation dynamics simulation code primer You are accessing a ...

  8. Ryo Wakabayashi > Graduate Student - DiSalvo Group > Researchers, Postdocs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Graduates > The Energy Materials Center at Cornell Ryo Wakabayashi Graduate Student - DiSalvo Group rhw224@cornell.edu

  9. Synthesis and study of conjugated polymers containing Di- or Triphenylamine

    SciTech Connect (OSTI)

    Sukwattanasinitt, M.

    1996-06-21

    This thesis consists of two separate parts. The first part addresses the synthesis and study of conjugated polymers containing di- or triphenylamine. Two types of polymers: linear polymers and dendrimers, were synthesized. The polymers were characterized by NMR, IR, UV, GPC, TGA and DSC. Electronic and optical properties of the polymers were studied through the conductivity measurements and excitation- emission spectra. the second part of this thesis deals with a reaction of electron-rich acetylenes with TCNE. The discovery of the reaction from charge transfer complex studies and the investigation of this reaction on various electron-rich acetylenes are presented.

  10. dI UNIVERSITY OF NEV\DA SYSTEM

    Office of Legacy Management (LM)

    g3t4 6 dI UNIVERSITY OF NEV\DA SYSTEM tw ?r@ D O E / D P / O 1 2 6 3 - 2 0 L , n z l t P ' " WATER RESOURCES CENTER itf.l This report was prepared as an aecount of work sponsore$ by the United States Government. Neither the United States nor the United States Department of Energy, nor any of their employees, mal assumes any legal liability or responsib usefulness of any informationr apparatus' I that its use would not infringe privately speeifie eommereial produetr proeesst ufacturen, or

  11. Critical cleaning agents for Di-2-ethylhexyl sebacate.

    SciTech Connect (OSTI)

    Hartley, Mya; Archuleta, Kim M.

    2013-08-01

    It is required that Di-2-ethylhexyl Sebacate oil, also commonly known as Dioctyl Sebacate oil, be thoroughly removed from certain metals, in this case stainless steel parts with narrow, enclosed spaces. Dioctyl Sebacate oil is a synthetic oil with a low compressibility. As such, it is ideally used for high pressure calibrations. The current method to remove the Dioctyl Sebacate from stainless steel parts with narrow, enclosed spaces is a labor-intensive, multi-step process, including a detergent clean, a deionized (DI) water rinse, and several solvent rinses, to achieve a nonvolatile residue of0.04 mg per 50 mL rinse effluent. This study was undertaken to determine a superior detergent/solvent cleaning method for the oil to reduce cleaning time and/or the amount of detergent/solvent used. It was determined that while some detergent clean the oil off the metal better than the current procedure, using only solvents obtained the best result. In addition, it can be inferred, based on elevated temperature test results, that raising the temperature of the oil-contaminated stainless steel parts to approximately 50%C2%B0C will provide for improved cleaning efficacy.

  12. ParaDiS-FEM dislocation dynamics simulation code primer (Technical...

    Office of Scientific and Technical Information (OSTI)

    When we try to perform discrete dislocation dynamics simulations for finite systems such as thin films or cylinders, the ParaDiS code must be extended. First, dislocations need to ...

  13. Direct Visualization of Spray and Combustion Inside a DI-SI Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel, injection timing, and valve deactivation in a DI optical accessible engine with side-mounted, multi-hole injector are investigated using CFD and high-speed imaging of sprays ...

  14. Frank DiSalvo > Research Thrust Leader - Fuel Cells and Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frank DiSalvo Research Thrust Leader - Fuel Cells and Batteries John A. Newman Professor of Physical Science Chemistry and Chemical Biology Research Group Webpage fjd3@cornell.edu...

  15. Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion 2003 DEER Conference Presentation: Sandia National Laboratories 2003_deer_pickett.pdf (538.33 KB) More Documents & Publications Effects of Ambient Density and Temperature on Soot Formation under High-EGR Conditions Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines Optical-Engine and Surrogate-Fuels

  16. HD Applications of Significantly Downsized SI Engines Using Alcohol DI for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Knock Avoidance | Department of Energy Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding knock in turbocharged, high-compression ratio spark-ignited engines that could replace diesels in certain vocational applications. deer08_blumberg.pdf (163.75 KB) More Documents &

  17. Boosted di-boson from a mixed heavy stop

    SciTech Connect (OSTI)

    Ghosh, Diptimoy

    2013-12-01

    The lighter mass eigenstate ($\\widetilde{t}_1$) of the two top squarks, the scalar superpartners of the top quark, is extremely difficult to discover if it is almost degenerate with the lightest neutralino ($\\widetilde{\\chi}_1^0$), the lightest and stable supersymmetric particle in the R-parity conserving supersymmetry. The current experimental bound on $\\widetilde{t}_1$ mass in this scenario stands only around 200 GeV. For such a light $\\widetilde{t}_1$, the heavier top squark ($\\widetilde{t}_2$) can also be around the TeV scale. Moreover, the high value of the higgs ($h$) mass prefers the left and right handed top squarks to be highly mixed allowing the possibility of a considerable branching ratio for $\\widetilde{t}_2 \\to \\widetilde{t}_1 h$ and $\\widetilde{t}_2 \\to \\widetilde{t}_1 Z$. In this paper, we explore the above possibility together with the pair production of $\\widetilde{t}_2$ $\\widetilde{t}_2^*$ giving rise to the spectacular di-boson + missing transverse energy final state. For an approximately 1 TeV $\\widetilde{t}_2$ and a few hundred GeV $\\widetilde{t}_1$ the final state particles can be moderately boosted which encourages us to propose a novel search strategy employing the jet substructure technique to tag the boosted $h$ and $Z$. The reconstruction of the $h$ and $Z$ momenta also allows us to construct the stransverse mass $M_{T2}$ providing an additional efficient handle to fight the backgrounds. We show that a 4--5$\\sigma$ signal can be observed at the 14 TeV LHC for $\\sim$ 1 TeV $\\widetilde{t}_2$ with 100 fb$^{-1}$ integrated luminosity.

  18. Potentiality of small DI diesel engines under consideration of emissions and noise control

    SciTech Connect (OSTI)

    Sugihara, K.; Matusi, Y.; Saegusa, S.

    1985-01-01

    The potentiality of direct injection (DI) diesel engines for passenger cars has been examined by comparing the characteristics of fuel consumption, exhaust emissions and noise levels between a turbocharged DI diesel engine and a turbocharged IDI diesel engine with the same displacement, 4 cylinders and 2 liters. It was observed that improved fuel consumption was obtained as the engine load increased, namely, 10 - 15% in the higher load range and 5 - 10% in the partial load range. In comparison to the IDI engine, the exhaust emissions of the DI engine tended to contain two or three times higher NOx and HC, and also about 30% higher particulates. Further, the noise levels of the DI engine were approximately 2 - 4 db (a) higher than those of the IDI engine. It was suggested from these results that in those countries which have stringent emission and noise regulations several years would be required to introduce small, high speed DI diesel engines for passenger cars to meet with these regulations.

  19. Method of dissolving metal oxides with di- or polyphosphonic acid and a redundant

    DOE Patents [OSTI]

    Horwitz, Earl P.; Chiarizia, Renato

    1996-01-01

    A method of dissolving metal oxides using a mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal oxides and optionally containing corrosion inhibitors and pH adjusting agents.

  20. Dimeric c-di-GMP is required for post-translational regulation of alginate production in Pseudomonas aeruginosa

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Whitney, John C.; Robinson, Howard; Whitfield, Gregory B.; Marmont, Lindsey S.; Yip, Patrick; Neculai, A. Mirela; Lobsanov, Yuri D.; Ohman, Dennis E.; Howell, P. Lynne

    2015-05-15

    Pseudomonas aeruginosa is an opportunistic human pathogen that secretes the exopolysaccharide alginate during infection of the respiratory tract of individuals afflicted with cystic fibrosis and chronic obstructive pulmonary disease. Among the proteins required for alginate production, Alg44 has been identified as an inner membrane protein whose bis-(3',5')-cyclic dimeric guanosine monophosphate (c-di-GMP) binding activity post-translationally regulates alginate secretion. In this study, we report the 1.8 Å crystal structure of the cytoplasmic region of Alg44 in complex with dimeric self-intercalated c-di-GMP and characterize its dinucleotide-binding site using mutational analysis. The structure shows that the c-di-GMP binding region of Alg44 adopts a PilZmore » domain fold with a dimerization mode not previously observed for this family of proteins. Moreover, calorimetric binding analysis of residues in the c-di-GMP binding site demonstrate that mutation of Arg-17 and Arg-95 alters the binding stoichiometry between c-di-GMP and Alg44 from 2:1 to 1:1. Introduction of these mutant alleles on the P. aeruginosa chromosome show that the residues required for binding of dimeric c-di-GMP in vitro are also required for efficient alginate production in vivo. Our results suggest that the dimeric form of c-di-GMP represents the biologically active signaling molecule needed for the secretion of an important virulence factor produced by P. aeruginosa.« less

  1. Dimeric c-di-GMP is required for post-translational regulation of alginate production in Pseudomonas aeruginosa

    SciTech Connect (OSTI)

    Whitney, John C.; Robinson, Howard; Whitfield, Gregory B.; Marmont, Lindsey S.; Yip, Patrick; Neculai, A. Mirela; Lobsanov, Yuri D.; Ohman, Dennis E.; Howell, P. Lynne

    2015-05-15

    Pseudomonas aeruginosa is an opportunistic human pathogen that secretes the exopolysaccharide alginate during infection of the respiratory tract of individuals afflicted with cystic fibrosis and chronic obstructive pulmonary disease. Among the proteins required for alginate production, Alg44 has been identified as an inner membrane protein whose bis-(3',5')-cyclic dimeric guanosine monophosphate (c-di-GMP) binding activity post-translationally regulates alginate secretion. In this study, we report the 1.8 Å crystal structure of the cytoplasmic region of Alg44 in complex with dimeric self-intercalated c-di-GMP and characterize its dinucleotide-binding site using mutational analysis. The structure shows that the c-di-GMP binding region of Alg44 adopts a PilZ domain fold with a dimerization mode not previously observed for this family of proteins. Moreover, calorimetric binding analysis of residues in the c-di-GMP binding site demonstrate that mutation of Arg-17 and Arg-95 alters the binding stoichiometry between c-di-GMP and Alg44 from 2:1 to 1:1. Introduction of these mutant alleles on the P. aeruginosa chromosome show that the residues required for binding of dimeric c-di-GMP in vitro are also required for efficient alginate production in vivo. Our results suggest that the dimeric form of c-di-GMP represents the biologically active signaling molecule needed for the secretion of an important virulence factor produced by P. aeruginosa.

  2. Joint Statement by President Obama and Prime Minister Elio Di Rupo of

    National Nuclear Security Administration (NNSA)

    Belgium on the 2014 Nuclear Security Summit | National Nuclear Security Administration | (NNSA) Joint Statement by President Obama and Prime Minister Elio Di Rupo of Belgium on the 2014 Nuclear Security Summit March 24, 2014 See a fact sheet here. The White House Office of the Press Secretary Belgium and the United States of America are pleased to announce that they have jointly completed the removal of a significant amount of excess highly enriched uranium (HEU) and separated plutonium from

  3. Efficient Emissions Control for Multi-Mode Lean DI Engines | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace031_parks_2011_o.pdf (848.8 KB) More Documents & Publications Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines Efficient Emissions Control for Multi-Mode Lean DI Engines

  4. ULEV potential of a DI/TCI diesel passenger car engine operated on dimethyl ether

    SciTech Connect (OSTI)

    Kapus, P.E.; Cartellieri, W.P.

    1995-12-31

    This paper describes a feasibility test program on a 2 liter, 4 cylinder DI/TCI passenger car engine operated on the new alternative fuel Dimethyl Ether (DME) with the aim of demonstrating its potential of meeting ULEV (ultra low emission vehicle) emissions (0.2 g/mi NOx in the FTP 75 test cycle) when installed in a full size passenger car. Special attention is drawn to the fuel injection equipment (FIE) as well as combustion system requirements towards the reduction of NOx and combustion noise while keeping energetic fuel consumption at the level of he baseline DI/TCI diesel engine. FIE and combustion system parameters were optimized on the steady state dynamometer by variation of a number of parameters, such as rate of injection, number of nozzle holes, compression ratio, piston bowl shape and exhaust gas recirculation. The paper presents engine test results achieved with DME under various operating conditions and compares these results to those achieved with the diesel version of the same engine.The FTP 75 cycle results were projected from steady state engine maps using a vehicle simulation program taking into account vehicle data and road resistance data of a given vehicle.The cycle results are also compared to actual chassis dynamometer results achieved with the diesel version of the same engine installed in the same vehicle.the passenger car DI/TCI engine adapted for and operated on DME shows very promising results with respect to meeting ULEV NOx emissions without any soot emissions and without the need for a DENOX catalyst. DME fuel consumption on energy basis can be kept very close to the DI diesel value. An oxidation catalyst will be necessary to meet the stringent CO and HC ULEV emission limits.

  5. Azimuthal angle dependence of di-jet production in unpolarized hadron scattering

    SciTech Connect (OSTI)

    Lu Zhun; Schmidt, Ivan [Departamento de Fisica, Universidad Tecnica Federico Santa Maria, Valparaiso (Chile) and Center of Subatomic Physics, Valparaiso (Chile)

    2009-08-04

    We study the azimuthal asymmetry of back-to-back di-jet production in unpolarized hadron scattering, arising from the product of two Boer-Mulders functions, which describe the transverse spin distribution of quarks inside an unpolarized hadron. We find that there is a cos {delta}{phi} angular dependence of the di-jet, with {delta}{phi} the difference of the azimuthal angle of tow jets respectively. In the case of J{sub q}+J{sub q} production, we find that there is a color factor enhancement in the gluonic cross-section due to the multiple initial-/final-state interactions, compared with the result from the standard generalized parton model. We estimate the cos {delta}{phi} asymmetry of the total di-jet production at RHIC, showing that the color factor enhancement in the azimuthal asymmetric cross section of J{sub q}+J{sub q} production will reverse the sign of the asymmetry.

  6. Di-J/psi Studies, Level 3 Tracking and the D0 Run IIb Upgrade

    SciTech Connect (OSTI)

    Vint, Philip John; /Imperial Coll., London

    2009-10-01

    The D0 detector underwent an upgrade to its silicon vertex detector and triggering systems during the transition from Run IIa to Run IIb to maximize its ability to fully exploit Run II at the Fermilab Tevatron. This thesis describes improvements made to the tracking and vertexing algorithms used by the high level trigger in both Run IIa and Run IIb, as well as a search for resonant di-J/{psi} states using both Run IIa and Run IIb data. Improvements made to the tracking and vertexing algorithms during Run IIa included the optimization of the existing tracking software to reduce overall processing time and the certification and testing of a new software release. Upgrades made to the high level trigger for Run IIb included the development of a new tracking algorithm and the inclusion of the new Layer 0 silicon detector into the existing software. The integration of Layer 0 into the high level trigger has led to an improvement in the overall impact parameter resolution for tracks of {approx}50%. The development of a new parameterization method for finding the error associated to the impact parameter of tracks returned by the high level tracking algorithm, in association with the inclusion of Layer 0, has led to improvements in vertex resolution of {approx}4.5 {micro}m. A previous search in the di-J/{psi} channel revealed a unpredicted resonance at {approx}13.7 GeV/c{sup 2}. A confirmation analysis is presented using 2.8 fb{sup -1} of data and two different approaches to cuts. No significant excess is seen in the di-J/{psi} mass spectrum.

  7. Improved di-p-xylylene polymer and apparatus and method for making the same

    DOE Patents [OSTI]

    Jahn, R.K.; Liepins, R.

    Solid di-para-xylyene dimer is sublimed in a sublimation furnace at approximately 100 to 200/sup 0/C and subsequently conducted to a pyrolysis furnace where it is pyrolyzed to the diradical p-xylylene monomer while in the vapor state at approximately 600 degrees C. The diradical monomer is then introduced into a deposition chamber for deposition onto a suitable substrate. The deposition chamber includes electrodes for producing a low pressure plasma through which the diradical monomer passes prior to deposition. The interaction of the diradical monomer with the low pressure plasma results in the formation of poly-p-xylyene film which is exceptionally hard and thermally stable.

  8. Di-22:6-bis(monoacylglycerol)phosphate: A clinical biomarker of drug-induced phospholipidosis for drug development and safety assessment

    SciTech Connect (OSTI)

    Liu, Nanjun; Tengstrand, Elizabeth A.; Chourb, Lisa; Hsieh, Frank Y.

    2014-09-15

    The inability to routinely monitor drug-induced phospholipidosis (DIPL) presents a challenge in pharmaceutical drug development and in the clinic. Several nonclinical studies have shown di-docosahexaenoyl (22:6) bis(monoacylglycerol) phosphate (di-22:6-BMP) to be a reliable biomarker of tissue DIPL that can be monitored in the plasma/serum and urine. The aim of this study was to show the relevance of di-22:6-BMP as a DIPL biomarker for drug development and safety assessment in humans. DIPL shares many similarities with the inherited lysosomal storage disorder Niemann–Pick type C (NPC) disease. DIPL and NPC result in similar changes in lysosomal function and cholesterol status that lead to the accumulation of multi-lamellar bodies (myeloid bodies) in cells and tissues. To validate di-22:6-BMP as a biomarker of DIPL for clinical studies, NPC patients and healthy donors were classified by receiver operator curve analysis based on urinary di-22:6-BMP concentrations. By showing 96.7-specificity and 100-sensitivity to identify NPC disease, di-22:6-BMP can be used to assess DIPL in human studies. The mean concentration of di-22:6-BMP in the urine of NPC patients was 51.4-fold (p ≤ 0.05) above the healthy baseline range. Additionally, baseline levels of di-22:6-BMP were assessed in healthy non-medicated laboratory animals (rats, mice, dogs, and monkeys) and human subjects to define normal reference ranges for nonclinical/clinical studies. The baseline ranges of di-22:6-BMP in the plasma, serum, and urine of humans and laboratory animals were species dependent. The results of this study support the role of di-22:6-BMP as a biomarker of DIPL for pharmaceutical drug development and health care settings. - Highlights: • A reliable biomarker of drug-induced phospholipidosis (DIPL) is needed for humans. • Di-22:6-BMP is specific/sensitive for DIPL in animals as published in literatures. • The di-22:6-BMP biomarker can be validated for humans via NPC patients. • DIPL

  9. Di-p-xylylene polymer and method for making the same

    DOE Patents [OSTI]

    Jahn, Randy K.; Liepins, Raimond

    1985-01-01

    A method and apparatus for forming an improved poly-p-xylylene film. Solid di-para-xylylene dimer is sublimed in a sublimation furnace at approximately 100.degree. to 200.degree. C. and subsequently conducted to a pyrolysis furnace where it is pyrolyzed to the diradical p-xylylene monomer while in the vapor state at approximately 600 degrees C. The diradical monomer is then introduced into a deposition chamber for deposition onto a suitable substrate. The deposition chamber includes electrodes for producing a low pressure plasma through which the diradical monomer passes prior to deposition. The interaction of the diradical monomer with the low pressure plasma results in the formation of poly-p-xylylene film which is exceptionally hard and thermally stable.

  10. Cerreto di Spoleto (Umbria-Italy): Seismic amplification at the ENEA local array stations

    SciTech Connect (OSTI)

    Rinaldis, Dario

    2008-07-08

    The Nerina valley, where Borgo Cerreto is located, is surrounded by the Apennine mount chain at the top of which lies the historical centre of Cerreto di Spoleto. The study is part of a research project aiming at analysing natural disasters and their impact on the Italian cultural heritage. Within the framework of this research project, local seismic records were analysed for both the carbonate ridge and the bordering alluvial valley. The choice of Cerreto di Spoleto as a test site derives from the analysis of Italian seismic hazard maps, obtained in terms of peak ground velocity and taking into account regional geology. The maps highlight the considerable seismic hazard which characterises the Apennine belt and its possible increase due to the effect of alluvial deposits. To this aim, ENEA installed in the 80's an accelerometric array (CODISMA up to 2000 and, in the following years, ETNA; for more detailed description see [1]. The 14 October event, was recorded both at the roof of CSM and at BCT stations. This is important to check the features observed comparing the FAS of acceleration at CSM and BCT during the 26 September events. Unfortunately the station at CSM basement did not record the above mentioned events but several aftershocks were recorded at each array station. Velocimetric records of both ambient noise and small-magnitude earthquakes were analysed in order to identify amplification conditions. The analysis was carried out in the time domain, through directional energy evaluation, and in the frequency domain, through H/V spectral ratios and spectral ratios with respect to a reference station.

  11. Direct Visualization of Spray and Combustion Inside a DI-SI Engine and Its Implications to Flex-Fuel VVT Operations

    Broader source: Energy.gov [DOE]

    Fuel, injection timing, and valve deactivation in a DI optical accessible engine with side-mounted, multi-hole injector are investigated using CFD and high-speed imaging of sprays and combustion.

  12. Di-photon and photon + b/c production cross sections at Ecm = 1.96- TeV

    SciTech Connect (OSTI)

    Gajjar, Anant; /Liverpool U.

    2005-05-01

    Measurements of the di-photon cross section have been made in the central region and are found to be in good agreement with NLO QCD predictions. The cross section of events containing a photon and additional heavy flavor jet have also been measured, as well as the ratio of photon + b to photon + c. The statistically limited sample shows good agreement with Leading Order predictions.

  13. Comparative Study of Low-temperature PECVD of Amorphous Silicon using Mono-, Di-, Trisilane and Cyclohexasilane

    SciTech Connect (OSTI)

    Konstantin Pokhodnya; Joseph Sandstrom; Xuliang Dai; Philip Boudjouk; Douglas L. Schulz

    2009-06-08

    The hydrogenated amorphous silicon a-Si:H films were grown by plasma-enhanced chemical vapor deposition (PECVD) using liquid cyclohexasilane Si{sub 6}H{sub 12} (CHS). The growth rate of a-Si:H was studied as a function of substrate temperatures in the range of 30 C < T < 450 C using deposition conditions that were optimized for monosilane SiH{sub 4}. The same parameters were used for a-Si:H films grown using disilane (Si{sub 2}H{sub 6}) and trisilane (Si{sub 3}H{sub 8}) precursors. It was found that the a-Si:H film growth rate for CHS is lower with respect to those for mono-, di- and trisilane in an Ar plasma. Addition of {approx}10% of H{sub 2} dramatically increases the deposition rate for CHS-based films to {_}nm/min - a 700% increase. The as-deposited films were characterized by FTIR and Raman spectroscopy to probe the hydrogen content and local bonding environment. It was found that the films grown using Ar/H{sub 2} mixtures as carrier gas have a reduced hydrogen content relative to polysilane fragments indicating higher quality amorphous silicon.

  14. Di-boson production and SM SUSY Higgs searches at the Tevatron

    SciTech Connect (OSTI)

    Elvira, V.Daniel; /Fermilab

    2005-07-01

    The discovery of the Higgs boson would be a major success for the Standard Model (SM) and would provide further insights into the electroweak symmetry breaking mechanism. This report contains the latest results from the D0 and CDF Tevatron experiments on searches for the SM Higgs produced from gluon fusion with H {yields} WW, and in association with a W boson. It also includes searches for a supersymmetric Higgs in the b{bar b} and {tau}{sup +}{tau}{sup -} decay channels. The study of di-boson production at the Tevatron is important to understand backgrounds in high mass Higgs searches. It also provides a test of the SM through the measurement of the production cross section and the gauge boson self couplings. This paper includes measurements of the WW, W{gamma}, and WZ production cross sections, as well as limits on the anomalous couplings associated with the WW{gamma} and WWZ interactions. The results are based on sets of up to 320 pb{sup -1} of data collected by the D0 and CDF experiments at the {bar p}p Tevatron collider, running at a center-of-mass energy of 1.96 TeV.

  15. Kinetic and Thermodynamic Investigation of Hydrogen Release from Ethane 1,2-di-amineborane

    SciTech Connect (OSTI)

    Neiner, Doinita; Karkamkar, Abhijeet J.; Bowden, Mark; Choi, Young Joon; Luedtke, Avery T.; Holladay, Jamelyn D.; Fisher, Allison M.; Szymczak, Nathaniel; Autrey, Thomas

    2011-07-18

    The thermodynamics and kinetics of hydrogen (H2) release from ethane 1,2-di-amineborane (EDAB, BH3NH2CH2CH2NH2BH3) were measured using Calvet and differential scanning calorimetry (DSC), pressure-composition isotherms, and volumetric gas-burette experiments. The results presented here indicate that EDAB releases ~ 9 wt.% H2 at temperatures ranging from 100 C to 200 C in two moderately exothermic steps, approximately -101 kJ/mol H2 and -3.81 kJ/mol H2. Isothermal kinetic analysis shows that EDAB is more stable than ammonia borane (AB) at temperatures lower than 100C; however, the rates of hydrogen release are faster for EDAB than for AB at temperatures higher than 120C. In addition, no volatile impurities in the H2 released by EDAB were detected by mass spectrometry upon heating with 1C/min to 200C in a calorimeter.

  16. Seismic model of a progradational carbonate platform, Picco di Vallandro, the Dolomites, northern Italy

    SciTech Connect (OSTI)

    Biddle, K.T.; Bush, T.L. ); Schlager, W. ); Rudolph, K.W. )

    1992-01-01

    The authors present a seismic model of a well-exposed carbonate platform-to-basin transition from the Triassic succession at Picco di Vallandro, the Dolomites, northern Italy. The core of this model is a detailed lithologic cross section that represents 1,500 m of stratigraphic section over a distance of 3.5 km. The cross section is based on detailed measured sections, photo interpretation, and careful projection of surface mapping into the plane of section. Samples from the measured sections provide control on velocity and density distribution, and these data were used to generate an impedance model from the cross section. The impedance model was convolved with a zero-phase, 25-Hz peak-frequency wavelet to produce the seismic model. The results illustrate how the platform-to-basin transition might be imaged by conventional seismic reflection data, how the reflections relate to the distribution of lithology and through-going geological surfaces, and how constructive and destructive interference and seismic resolution combine to produce individual reflections.

  17. Functionalization/passivation of porous graphitic carbon with di-tert-amylperoxide

    SciTech Connect (OSTI)

    Jensen, David S.; Gupta, Vipul; Olsen, Rebecca E.; Miller, Alex T.; Davis, Robert C.; Ess, Daniel; Zhu, Zihua; Vail, Michael A.; Dadson, Andrew; Linford, Matthew R.

    2011-11-18

    Porous graphitic carbon (PGC) particles were functionalized/passivated in situ in packed beds at elevated temperature with neat di-tert-amylperoxide (DTAP) in a column oven. The performance of these particles for high performance liquid chromatography (HPLC) was assayed before and after this chemistry with the following analytes: benzene, toluene, ethyl benzene, n-propyl benzene, n-butyl benzene, p-xylene, phenol, 4-methylphenol, phenetole, 3,5-xylenol, and anisole. After the first functionalization/passivation, the retention factors, k, of these compounds decreased by about 5% and the number of theoretical plates (N) increased by ca. 15%. These values of k then remained roughly constant after a second functionalization/ passivation but a further increase in N was noticed. In addition, after each of the reactions, the peak asymmetries decreased by ca. 15%, for a total of ca. 30%. The columns were then subjected twice to methanol at 100 C for 5 h at 1 mL/min. After these stability tests, the values of k remained roughly constant, the number of plates increased, which is favorable, and the asymmetries rose and then declined, where they remained below the initial values for the unfunctionalized columns. Functionalized and unfunctionalized particles were characterized by scanning electron microscopy and BET measurements, which showed no difference between the functionalized and unfunctionalized materials, and X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry (ToF-SIMS), where ToF-SIMS suggested some chemical differences between the functionalized and unfunctionalized materials. In particular ToF-SIMS suggested that the expected five-carbon fragments from DTAP exist at higher concentrations on DTAP-functionalized PGC. First principle calculations on model graphitic surfaces suggest that the first addition of a DTAP radical to the surface proceeds in an approximately isothermal or slightly favorable fashion, but that subsequent DTAP

  18. Thermal chemistry of copper(I)-N,N '-di-sec-butylacetamidinate on Cu(110) single-crystal surfaces

    SciTech Connect (OSTI)

    Ma Qiang; Zaera, Francisco; Gordon, Roy G.

    2012-01-15

    The surface chemistry of copper(I)-N,N'-di-sec-butylacetamidinate on Cu(110) single-crystal surfaces has been characterized under ultrahigh vacuum by temperature programmed desorption (TPD) and X-ray photoelectron spectroscopy. A series of thermal stepwise conversions were identified, starting with the partial dissociative adsorption of the copper acetamidinate dimers into a mixture of monomers and dimers on the surface. An early dissociation of a C-N bond leads to the production of N-sec-butylacetamidine, which is detected in TPD experiments in three temperature regimes, the last one centered around 480 K. Butene, and a small amount of butane, is also detected above approximately 500 K, and hydrogen production, an indication of dehydrogenation of surface fragments, is observed at 460, 550 and 670 K. In total, only about 10% of the initial copper(I)-N,N'-di-sec-butylacetamidinate adsorbed monolayer decomposes, and only about {approx}3% of carbon is left behind on the surface after heating to high temperatures. The implications of this surface chemistry to the design of chemical film growth processes using copper acetamidinates as precursors are discussed.

  19. Study of di-pion Bottomonium Transitions and Search for the h_b(1P) State

    SciTech Connect (OSTI)

    Lees, J.P.; Poireau, V.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Milanes, D.A.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Sun, L.; Brown, D.N.; Kerth, L.T.; Kolomensky, Yu.G.; Lynch, G.; Koch, H.; Schroeder, T.; Asgeirsson, D.J.; Hearty, C.; Mattison, T.S.; /British Columbia U. /Brunel U. /Novosibirsk, IYF /UC, Irvine /UC, Riverside /UC, Santa Barbara /UC, Santa Cruz /Caltech /Cincinnati U. /Colorado U. /Colorado State U. /Dortmund U. /Dresden, Tech. U. /Ecole Polytechnique /Edinburgh U. /INFN, Ferrara /INFN, Ferrara /Ferrara U. /INFN, Ferrara /Frascati /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /INFN, Genoa /Indian Inst. Tech., Guwahati /Harvard U. /Harvey Mudd Coll. /Heidelberg U. /Humboldt U., Berlin /Imperial Coll., London /Iowa State U. /Iowa State U. /Johns Hopkins U. /Paris U., VI-VII /LLNL, Livermore /Liverpool U. /Queen Mary, U. of London /Royal Holloway, U. of London /Royal Holloway, U. of London /Louisville U. /Mainz U., Inst. Kernphys. /Manchester U. /Maryland U. /Massachusetts U., Amherst /MIT /McGill U. /INFN, Milan /Milan U. /INFN, Milan /INFN, Milan /Milan U. /Mississippi U. /Montreal U. /INFN, Naples /Naples U. /NIKHEF, Amsterdam /NIKHEF, Amsterdam /Notre Dame U. /Ohio State U. /Oregon U. /INFN, Padua /Padua U. /INFN, Padua /INFN, Padua /Padua U. /Paris U., VI-VII /INFN, Perugia /Perugia U. /INFN, Pisa /Pisa U. /INFN, Pisa /Pisa, Scuola Normale Superiore /INFN, Pisa /Pisa U. /INFN, Pisa /INFN, Pisa /Pisa U. /INFN, Pisa /Princeton U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /Rostock U. /Rutherford /DAPNIA, Saclay /SLAC /South Carolina U. /Southern Methodist U. /Stanford U., Phys. Dept. /SUNY, Albany /Tel Aviv U. /Tennessee U. /Texas Nuclear Corp., Austin /Texas U., Dallas /INFN, Turin /Turin U. /INFN, Trieste /Trieste U. /Valencia U. /Victoria U. /Warwick U. /Wisconsin U., Madison

    2011-12-09

    We study inclusive di-pion decays using a sample of 108 x 10{sup 6} {Upsilon}(3S) events recorded with the BABAR detector. We search for the decay mode {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}h{sub b} (1P) and find no evidence for the bottomonium spin-singlet state h{sub b}(1P) in the invariant mass distribution recoiling against the {pi}{sup +}{pi}{sup -} system. Assuming the h{sub b}(1P) mass to be 9.900 GeV/c{sup 2}, we measure the upper limit on the branching fraction {Beta}[{Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}h{sub b}(1P)] < 1.2 x 10{sup -4}, at 90% confidence level. We also investigate the {chi}{sub bJ}(2P) {yields} {pi}{sup +}{pi}{sup -} {chi}{sub bJ}(1P), {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(2S), and {Upsilon}(2S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(1S) di-pion transitions and present an improved measurement of the branching fraction of the {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(2S) decay and of the {Upsilon}(3S) - {Upsilon}(2S) mass difference.

  20. A Search for Supersymmetric Higgs Bosons in the Di-tau Decay Mode in Proton - Anti-proton Collisions at 1.8 TeV

    SciTech Connect (OSTI)

    Connolly, Amy Lynn

    2003-09-01

    A search for directly produced Supersymmetric Higgs Bosons has been performed in the di-tau decay channel in 86.3 {+-} 3.5 pb{sup -1} of data collected by CDF during Run1b at the Tevatron. They search for events where one tau decays to an electron and the other tau decays hadronically. They perform a counting experiment and set limits on the cross section for Higgs production in the high tan {beta} region of the m{sub A}-tan {beta} plane. For a benchmark parameter space point where m{sub A} = 100 and tan {beta} = 50, they set a 95% confidence level upper limit at 891 pb compared to the theoretically predicted cross section of 122 pb. For events where the tau candidates are not back-to-back, they utilize a di-tau mass reconstruction technique for the first time on hadron collider data. Limits based on a likelihood binned in di-tau mass from non-back-to-back events alone are weaker than the limits obtained from the counting experiment using the full di-tau sample.

  1. DE-EM-0001971 WIPP M&O D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING Table of Content D-1 PACKAGING ....................................................................................................... 1 D-2 MARKING ........................................................................................................... 1 DE-EM-0001971 WIPP M&O D-1 PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING D-1 PACKAGING Preservation, packaging, and packing for shipment or mailing of all work delivered

  2. Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers in Aqueous Phase

    SciTech Connect (OSTI)

    He, Jiayue; Zhao, Chen; Mei, Donghai; Lercher, Johannes A.

    2014-01-02

    A novel route for cleaving the C-O aryl ether bonds of p-substituted H-, CH3-, and OH- diphenyl ethers has been explored over Ni/SiO2 catalysts at very mild conditions. The C-O bond of diphenyl ether is cleaved by parallel hydrogenolysis and hydrolysis (hydrogenolysis combined with HO* addition) on Ni. The rates as a function of H2 pressure from 0 to 10 MPa indicate that the rate-determining step is the C-O bond cleavage on Ni. H* atoms compete with the organic reactant for adsorption leading to a maximum in the rate with increasing H2 pressure. In contrast to diphenyl ether, hydrogenolysis is the exclusive route for cleaving an ether C-O bond of di-p-tolyl ether to form p-cresol and toluene. 4,4'-dihydroxydiphenyl ether undergoes sequential surface hydrogenolysis, first to phenol and HOC6H4O* (adsorbed), which is then cleaved to phenol (C6H5O* with added H*) and H2O (O* with two added H*) in a second step. Density function theory supports the operation of this pathway. Notably, addition of H* to HOC6H4O* is less favorable than a further hydrogenolytic C-O bond cleavage. The TOFs of three aryl ethers with Ni/SiO2 in water followed the order 4,4'-dihydroxydiphenyl ether (69 h-1) > diphenyl ether (26 h-1) > di-p-tolyl ether (1.3 h-1), in line with the increasing apparent activation energies, ranging from 93 kJ∙mol-1 (4,4'-dihydroxydiphenyl ether) < diphenyl ether (98 kJ∙mol-1) to di-p-tolyl ether (105 kJ∙mol-1). D.M. thanks the support from the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. Computing time was granted by the grand challenge of computational catalysis of the William R

  3. Synthesis, characterization and crystal structure of diaquadi(2,2`-bipyridine)di(dichloroacetato)lanthanide (III) monodichloroacetato

    SciTech Connect (OSTI)

    Lu Weimin, Cheng Yiqiang, Dong Nan

    1995-05-01

    The title complexes, Diaquadi(2,2`-bipyridine)Di(Dichloroacetato)Lanthanide (III) Monodichloroacetato [Ln(CHCI{sub 2}COO){sub 2}(2,2`-bipy){sub 2}(H{sub 2}O){sub 2}]{sup +}(CHCI{sub 2}COO){sup -}(Ln=Dy, Ho, Tm, Er, Yb) were obtained and characterized. [Er(CHCI{sub 2}COOO){sub 2}(2,2`-bipy){sub 2} (H{sub 2}O){sub 2}]+(CHCI{sub 2}COO){sup -} crystallizes in the monoclinic space group P2{sub 1}/n with Z=4. Cell dimensions are a=15.886 (9), b=13.758(2), c=16.343(4) {angstrom}, {Beta}=113.31(3){degrees}, and the structure was refined to an R of 0.049 for 3415 observed reflections. The Er(III) ion exhibits a distorted, square antiprismatic configuration. Four N atoms of 2,2`-bipy and four O atoms from two dichloroacetato and two water ligands are coordinated. One dichloroacetato group lies outside the polyhedron and is connected with water ligands by hydrogen bonds.

  4. DiMES Studies of Temperature Dependence of Carbon Erosion and Re-Deposition in the DIII-D Divertor

    SciTech Connect (OSTI)

    Rudakov, D L; Jacob, W; Krieger, K; Litnovsky, A; Philipps, V; West, W P; Wong, C C; Allen, S L; Bastasz, R J; Boedo, J A; Brooks, N H; Boivin, R L; De Temmerman, G; Fenstermacher, M E; Groth, M; Hollmann, E M; Lasnier, C J; McLean, A G; Moyer, R A; Stangeby, P C; Wampler, W R; Watkins, J G; Wienhold, P; Whaley, J

    2007-03-15

    A strong effect of a moderately elevated surface temperature on net carbon deposition and deuterium co-deposition in the DIII-D divertor was observed under detached conditions. A DiMES sample with a gap 2 mm wide and 18 mm deep was exposed to lower-single-null (LSN) L-mode plasmas first at room temperature, and then at 200 C. At the elevated temperature, deuterium co-deposition in the gap was reduced by an order of magnitude. At the plasma-facing surface of the heated sample net carbon erosion was measured at a rate of 3 nm/s, whereas without heating net deposition is normally observed under detachment. In a related experiment three sets of molybdenum mirrors recessed 2 cm below the divertor floor were exposed to identical LSN ELMy H-mode discharges. The first set of mirrors exposed at ambient temperature exhibited net carbon deposition at a rate of up to 3.7 nm/s and suffered a significant drop in reflectivity. In contrast, two other mirror sets exposed at elevated temperatures between 90 C and 175 C exhibited practically no carbon deposition.

  5. Seismic models of a carbonate foreslope-to-basin transition, Picco di Vallandro, Dolomite Alps, northern Italy

    SciTech Connect (OSTI)

    Rudolph, K.W. ); Schlager, W. ); Biddle, K.T. )

    1989-05-01

    Detailed geologic cross sections, augmented by laboratory calibration of lithology and acoustic impedance, have been used to produce synthetic reflection seismic sections of a carbonate foreslope-to-basin transition. Two areas from the Picco di Vallandro region of the Dolomite Alps were modeled: a progradational section and a retrogradational (backstepping) section. The resulting models show how these complex areas of strata interfingering might be displayed on conventional reflection seismic lines. In the area of progradation, rapid stratigraphic thinning below seismic detectibility, coupled with abrupt impedance changes, produces a reflection discontinuity between steeply dipping reflections of the foreslope and gently dipping paralle reflections of the basin section. This apparent downlap surface marks the toe-of-slope for successive clinoforms but dose not correspond to a discrete stratigraphic surface. In the backstepping example, similar stratigraphic thinning and impedance changes create an apparent onlap surface. Wavelet interference causes complications in both examples. These models indicate how stratigraphic complexity can be simplified by the seismic reflection process and suggest that caution should be exercised when using seismic data to construct general models in areas of complex depositional geometries and rapidly changing facies.

  6. Di(2-ethylhexyl) phthalate inhibits antral follicle growth, induces atresia, and inhibits steroid hormone production in cultured mouse antral follicles

    SciTech Connect (OSTI)

    Hannon, Patrick R. Brannick, Katherine E. Wang, Wei Gupta, Rupesh K. Flaws, Jodi A.

    2015-04-01

    Di(2-ethylhexyl) phthalate (DEHP) is a ubiquitous environmental toxicant found in consumer products that causes ovarian toxicity. Antral follicles are the functional ovarian units and must undergo growth, survival from atresia, and proper regulation of steroidogenesis to ovulate and produce hormones. Previous studies have determined that DEHP inhibits antral follicle growth and decreases estradiol levels in vitro; however, the mechanism by which DEHP elicits these effects is unknown. The present study tested the hypothesis that DEHP directly alters regulators of the cell cycle, apoptosis, and steroidogenesis to inhibit antral follicle functionality. Antral follicles from adult CD-1 mice were cultured with vehicle control or DEHP (1–100 μg/ml) for 24–96 h to establish the temporal effects of DEHP on the follicle. Following 24–96 h of culture, antral follicles were subjected to gene expression analysis, and media were subjected to measurements of hormone levels. DEHP increased the mRNA levels of cyclin D2, cyclin dependent kinase 4, cyclin E1, cyclin A2, and cyclin B1 and decreased the levels of cyclin-dependent kinase inhibitor 1A prior to growth inhibition. Additionally, DEHP increased the mRNA levels of BCL2-associated agonist of cell death, BCL2-associated X protein, BCL2-related ovarian killer protein, B-cell leukemia/lymphoma 2, and Bcl2-like 10, leading to an increase in atresia. Further, DEHP decreased the levels of progesterone, androstenedione, and testosterone prior to the decrease in estradiol levels, with decreased mRNA levels of side-chain cleavage, 17α-hydroxylase-17,20-desmolase, 17β-hydroxysteroid dehydrogenase, and aromatase. Collectively, DEHP directly alters antral follicle functionality by inhibiting growth, inducing atresia, and inhibiting steroidogenesis. - Highlights: • DEHP inhibits antral follicle growth by dysregulating cell cycle regulators. • DEHP induces antral follicle atresia by dysregulating apoptosis regulators. • DEHP

  7. Anomalous dynamics of aqueous solutions of di-propylene glycol methylether confined in MCM-41 by quasielastic neutron scattering

    SciTech Connect (OSTI)

    Swenson, Jan Elamin, Khalid; Chen, Guo; Lohstroh, Wiebke; Sakai, Victoria Garcia

    2014-12-07

    The molecular dynamics of solutions of di-propylene glycol methylether (2PGME) and H{sub 2}O (or D{sub 2}O) confined in 28 Å pores of MCM-41 have been studied by quasielastic neutron scattering and differential scanning calorimetry over the concentration range 0–90 wt.% water. This system is of particular interest due to its pronounced non-monotonic concentration dependent dynamics of 2PGME in the corresponding bulk system, showing the important role of hydrogen bonding for the dynamics. In this study we have elucidated how this non-monotonic concentration dependence is affected by the confined geometry. The results show that this behaviour is maintained in the confinement, but the slowest diffusive dynamics of 2PGME is now observed at a considerably higher water concentration; at 75 wt.% water in MCM-41 compared to 30 wt.% water in the corresponding bulk system. This difference can be explained by an improper mixing of the two confined liquids. The results suggest that water up to a concentration of about 20 wt.% is used to hydrate the hydrophilic hydroxyl surface groups of the silica pores, and that it is only at higher water contents the water becomes partly mixed with 2PGME. Hence, due to this partial micro-phase separation of the two liquids larger, and thereby slower relaxing, structural entities of hydrogen bonded water and 2PGME molecules can only be formed at higher water contents than in the bulk system. However, the Q-dependence is unchanged with confinement, showing that the nature of the molecular motions is preserved. Thus, there is no indication of localization of the dynamics at length scales of less than 20 Å. The dynamics of both water and 2PGME is strongly dominated by translational diffusion at a temperature of 280 K.

  8. THE USE OF DI WATER TO MITIGATE DUSTING FOR ADDITION OF DWPF FRIT TO THE SLURRY MIX EVAPORATOR

    SciTech Connect (OSTI)

    Hansen, E.

    2010-07-21

    objective of this task is to perform bench scale testing on various frits that have been used at DWPF or in test programs at SRNL to determine the quantity of de-ionized (DI) water required to mitigate dusting per mass basis of frit. The quantity of DI water required was determined visually by observing the effluent port of the mixer, and DI water addition was made to the point where no visible dust was observed leaving the effluent port. A total of eight different frits were selected for testing. Secondary objectives in this task include the following: (1) Video taping of the de-dusting procedure, (2) Particle size distribution analyses of the dry and wetted frits at the weight fraction of water required for de-dusting, (3) Plate flow tests to determine angle of flow and quantity of material remaining on plate at 90 degrees, (4) Microscopy of dry and wetted frit, and (5) Effect of excess water for selected frits on plate flow. The above analyses were performed within one hour of water addition, to minimize the effect of evaporative water losses. To better understand the size of dust particles, perform settling tests on selected frits and capture the fines. Analyze the fines for particle size distribution. Finally, it is expected that the surface area of frit is an important parameter in the quantity of water required for dust mitigation. An analysis of particle size distribution (PSD) data of as-received frit analyzed by SRNL over the past two to three years will be performed to determine the variation in the distribution of as-received frit. The following objectives were stated in the Technical Task Request4 as objectives that given adequate time would provide insight in helping DWPF in assessing equipment or processes for de-dusting and processing of dry frit. Due to time constraints, commercial methods for dedusting are provided. These results are detailed in section 3.7. Obtain design information from Hanford with respective to equipment used for dedusting. Suggestions

  9. DiTour

    SciTech Connect (OSTI)

    Pelaia, II, Thomas A.

    2014-06-05

    it is common for facilities to have a lobby with a display loop while also requiring an option for guided tours. Existing solutions have required expensive hardware and awkward software. Our solution is relative low cost as it runs on an iPad connected to an external monitor, and our software provides an intuitive touch interface. The media files are downloaded from a web server onto the device allowing a mobile option (e.g. displays at conferences). Media may include arbitrary sequences of images, movies or PDF documents. Tour guides can select different tracks of slides to display and the presentation will return to the default loop after a timeout.

  10. DiTour

    Energy Science and Technology Software Center (OSTI)

    2014-06-05

    it is common for facilities to have a lobby with a display loop while also requiring an option for guided tours. Existing solutions have required expensive hardware and awkward software. Our solution is relative low cost as it runs on an iPad connected to an external monitor, and our software provides an intuitive touch interface. The media files are downloaded from a web server onto the device allowing a mobile option (e.g. displays at conferences).more » Media may include arbitrary sequences of images, movies or PDF documents. Tour guides can select different tracks of slides to display and the presentation will return to the default loop after a timeout.« less

  11. Advances on MHD superconducting magnets design and construction in Italy

    SciTech Connect (OSTI)

    Negrini, F.; Blasio, P.; Martinelli, G.; Molfino, P.

    1993-12-31

    The paper illustrates the activities developed in the frame of the Progetto Finalizzato {open_quotes}Superconducting and Cryogenic Technologies: superconducting magnets for MHD{close_quotes}. This five years Italian national program on MHD superconducting magnets is near the completions. Many important targets have been obtained in very good agreement with the initial hypotheses. The MHD s.c. prototype is now under fabrication at the Ansaldo workshop in Genova. One of the main effort of the project is the development and production of the 8800 metres of NbTi copper stabilised cable in conduit ({open_quotes}rope in a pipe{close_quotes} type) in single lengths of 300 m average. This cable is now under production at Europa Metalli (Fornaci di Barga, Italy). In the present contribution the main problems that had to be solved after and during the production by the designer and the manufacturer, are described.

  12. Extraction of uranium(VI) by N,N-di-(2-ethylhexyl)isobutyramide (DEHIBA): from the batch experimental data to the countercurrent process

    SciTech Connect (OSTI)

    Miguirditchian, M.; Sorel, C.; Cames, B.; Bisel, I.; Baron, P.

    2008-07-01

    The selective separation of uranium(VI) in the first cycle of the GANEX process is operated by a hydrometallurgical process using a monoamide extractant DEHiBA (N,N-di-(2-ethylhexyl)isobutyramide). Distribution ratios of uranium(VI) and nitric acid in 1 M DEHiBA/HTP were determined with macro-concentrations of uranium, and the experimental data were modelled by taking into account the activity coefficients of the constituents in aqueous phases. A flowsheet was designed and tested in a countercurrent process in laboratory-scale mixer-settlers on a surrogate U(VI)/HNO 3 feed. More than 99.999% of the uranium was recovered. (authors)

  13. Gold(I) chloride adducts of 1,3-bis(di-2-pyridylphosphino)propane: synthesis, structural studies and antitumour activity

    SciTech Connect (OSTI)

    Humphreys, Anthony S.; Filipovska, Aleksandra; Berners-Price, Susan J.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.

    2008-06-30

    The novel water soluble bidentate phosphine ligand 1,3-bis(di-2-pyridylphosphino)propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} and isolation in crystalline form as the hydrochloride salt. The synthesis of the precursor Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} has been optimized by the use of triphosgene as the chlorinating agent. The 2:1 and 1:2 AuCl:d2pypp adducts have been synthesized and characterized by NMR spectroscopy and single crystal X-ray studies, and shown to be of the form (AuCl){sub 2}({mu}-d2pypp-P,P{prime}) and Au(d2pypp-P,P{prime}){sub 2}Cl(-3.75H{sub 2}O), respectively. The latter is more lipophilic than analogous 1:2 adducts of gold(I) chloride with the diphosphine ligands 1,2-bis(di-n-pyridylphosphino)ethane (dnpype) for n = 2, 3 and 4, based on measurement of the n-octanol-water partition coefficient (log P = -0.46). A single crystal structure determination of the 1:2 Au(I) complex of the 3-pyridyl ethane ligand shows it to be of the form [Au(d3pype-P,P{prime}){sub 2}]Cl {center_dot} 5H{sub 2}O. The in vitro cytotoxic activity of [Au(d2pypp){sub 2}]Cl was assessed in human normal and cancer breast cells and selective toxicity to the cancer cells found. The significance of these results to the antitumour properties of chelated 1:2 Au(I) diphosphine complexes is discussed.

  14. An in-cylinder study of the particulate/NO{sub x} trade-off in a DI Diesel Engine. Draft of final report

    SciTech Connect (OSTI)

    Litzinger, T.A.; Santavicca, D.A.; Santoro, R.J.

    1994-07-01

    The goal of the work performed during the contract period was to establish the ability to study soot and NO within the combustion chamber of a DI Diesel engine and to couple these measurements with actual exhaust emissions. This work was motivated by the need to obtain a more complete understanding of the particulate/NO{sub X} trade-off, observed in Diesel engines, to aid engine designers in meeting emissions limits. In order to achieve the desired goal, an optically accessible DI Diesel engine was designed and constructed. Also, planar imaging methods for imaging soot and NO were developed in laboratory flames and were then applied to the engine. For the study of soot, planar Mie scattering was used and a polarization ratio method was investigated to distinguish soot from fuel droplets. The Mie scattering technique proved to be well suited for the engine, and extensive results were obtained. In order to observe NO, planar laser induced fluorescence was used and it was successfully applied in the engine. In addition to these techniques, high speed combustion photography and shadowgraph photography were applied to obtain general characteristics of the combustion process. As a final diagnostic, actual engine emissions were measured. This report begins with a brief discussion of the problem under investigation and a summary of other studies of the NO{sub x}/particulate trade-off. Following these sections is a summary of the accomplishments and results from the present study. Finally, detailed results are presented through the six technical papers which were written during the contract period; these papers are appended to the report.

  15. Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes

    DOE Patents [OSTI]

    Kerr, John B.; Tian, Minmin

    2000-01-01

    A electrochemical cell is described comprising an anode, a cathode, a solid polymer electrolyte, and a redox shuttle additive to protect the cell against overcharging and a redox shuttle additive to protect the cell against overcharging selected from the group consisting of: (a) a substituted anisole having the general formula (in an uncharged state): ##STR1## where R.sub.1 is selected from the group consisting of H, OCH.sub.3, OCH.sub.2 CH.sub.3, and OCH.sub.2 phenyl, and R.sub.2 is selected from the group consisting of OCH.sub.3, OCH.sub.2 CH.sub.3, OCH.sub.2 phenyl, and O.sup.- Li.sup.+ ; and (b) a di-anisole compound having the general formula (in an uncharged state): ##STR2## where R is selected from the group consisting of -OCH.sub.3 and -CH.sub.3, m is either 1 or 0, n is either 1 or 0, and X is selected from the group consisting of -OCH.sub.3 (methoxy) or its lithium salt --O.sup.- Li.sup.+. The lithium salt of the di-anisole is the preferred form of the redox shuttle additive because the shuttle anion will then initially have a single negative charge, it loses two electrons when it is oxidized at the cathode, and then moves toward the anode as a single positively charged species where it is then reduced to a single negatively charged species by gaining back two electrons.

  16. Synthesis and characterization of d{sup 10} metal complexes with mixed 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate ligands

    SciTech Connect (OSTI)

    Chen, Zhi-Hao; Zhao, Yue; Chen, Shui-Sheng; Wang, Peng; Sun, Wei-Yin

    2013-06-15

    Seven new coordination polymers [Zn(H{sub 2}L)(mbdc)] (1), [Zn(H{sub 3}L)(btc)] (2), [Zn(H{sub 2}L)(Hbtc)] (3), [Zn(H{sub 2}L)(Hbtc)]H{sub 2}O (4), [Zn{sub 2}(H{sub 2}L)(btc)(?{sub 2}-OH)] (5), [Cd(H{sub 2}L)(mbdc)] (6) and [Cd{sub 3}(H{sub 2}L){sub 2}(btc){sub 2}(H{sub 2}O)]5H{sub 2}O (7) were synthesized by reactions of the corresponding metal salt with rigid ligand 1,3-di(1H-imidazol-4-yl)benzene (H{sub 2}L) and different carboxylic acids of 1,3-benzenedicarboxylic acid (H{sub 2}mbdc) and benzene-1,3,5-tricarboxylic acid (H{sub 3}btc), respectively. The results of X-ray crystallographic analysis indicate that complex 1 is 1D chain while 2 is a (3,3)-connected 2D network with Point (Schlfli) symbol of (4,8{sup 2}). Complexes 3 and 6 are 2D networks, 4 is a 3-fold interpenetrating 3D framework with Point (Schlfli) symbol of (6{sup 5},8) and 5 is a (3,8)-connected 2D network with Point (Schlfli) symbol of (3,4{sup 2}){sub 2}(3{sup 4},4{sup 6},5{sup 6},6{sup 8},7{sup 3},8), while 7 is a (3,10)-connected 3D net with Schlfli symbol of (3,4,5){sub 2}(3{sup 4},4{sup 8},5{sup 18},6{sup 12},7{sup 2},8). The thermal stability and photoluminescence of the complexes were investigated. Furthermore, DFT calculations were performed for 24 to discuss the temperature controlled self-assembly of the complexes. - Graphical abstract: Seven new coordination polymers with multicarboxylate and rigid ditopic 4-imidazole containing ligands have been obtained and found to show different structures and topologies. - Highlights: Metal complexes with diverse structures of 1D chain, 2D network and 3D framework. Mixed ligands of 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate. Photoluminescence property.

  17. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  18. Study of very high pressure fuel-injection for high-BMEP DI-diesel engine. Final report, 30 September 1997--28 February 1999

    SciTech Connect (OSTI)

    Rhee, K.T.

    1999-03-16

    In order to help design a high-power-density (HPD) low-heat-rejection (LHR) high-injection-fuel (HIP) direct-injection compression-ignition engine (DI-CI), two main methods were employed: (1) engine performance analysis; and (2) in-cylinder imaging. In the performance analysis, a Cummins 903 engine was used. The range of air/fuel ratio studied was from 18-1 to over 35-1, the injection pressure investigated was as high as 30,625 psi (210 Mpa) under varied intake air temperature over 150 deg C. In the in-cylinder imaging, a separate optical single-cylinder Cummins 903 engine was used. A high-speed four-color IR digital imaging system was greatly improved during this contract period. New spectrometric methods were developed to simultaneously determine the distributions of temperature, water vapor and soot concentrations. In addition, a new data analysis and presentation method has been developed. The performance analysis results are reported in two parts: a preliminary report as included in Appendix-I and an additional set of results (Appendix-III). Some of the in-cylinder imaging results, which are now being captured by the improved 515 after incorporating with new electronic packages (designed and fabricated in the laboratory), are included with discussions.

  19. Ansaldo Energia | Open Energy Information

    Open Energy Info (EERE)

    Energia Place: Genova, Italy Zip: 16152 Product: Provides plant engineering, manufacturing and service expertise for the global power industry. References: Ansaldo...

  20. Understanding the Electronic Structure of 4d Metal Complexes: From Molecular Spinors to L-Edge Spectra of a di-Ru Catalyst

    SciTech Connect (OSTI)

    Alperovich, Igor; Smolentsev, Grigory; Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Meyer, Thomas J.; Soldatov, Alexander; Pushkar, Yulia

    2015-09-17

    L{sub 2,3}-edge X-ray absorption spectroscopy (XAS) has demonstrated unique capabilities for the analysis of the electronic structure of di-Ru complexes such as the blue dimer cis,cis-[Ru{sub 2}{sup III}O(H{sub 2}O){sub 2}(bpy){sub 4}]{sup 4+} water oxidation catalyst. Spectra of the blue dimer and the monomeric [Ru(NH{sub 3}){sub 6}]{sup 3+} model complex show considerably different splitting of the Ru L{sub 2,3} absorption edge, which reflects changes in the relative energies of the Ru 4d orbitals caused by hybridization with a bridging ligand and spin-orbit coupling effects. To aid the interpretation of spectroscopic data, we developed a new approach, which computes L{sub 2,3}-edges XAS spectra as dipole transitions between molecular spinors of 4d transition metal complexes. This allows for careful inclusion of the spin-orbit coupling effects and the hybridization of the Ru 4d and ligand orbitals. The obtained theoretical Ru L{sub 2,3}-edge spectra are in close agreement with experiment. Critically, existing single-electron methods (FEFF, FDMNES) broadly used to simulate XAS could not reproduce the experimental Ru L-edge spectra for the [Ru(NH{sub 3}){sub 6}]{sup 3+} model complex nor for the blue dimer, while charge transfer multiplet (CTM) calculations were not applicable due to the complexity and low symmetry of the blue dimer water oxidation catalyst. We demonstrated that L-edge spectroscopy is informative for analysis of bridging metal complexes. The developed computational approach enhances L-edge spectroscopy as a tool for analysis of the electronic structures of complexes, materials, catalysts, and reactive intermediates with 4d transition metals.

  1. Visible Light-Induced Electron Transfer from Di-mu-oxo Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores

    SciTech Connect (OSTI)

    Frei, Heinz; Weare, Walter W.; Pushkar, Yulia; Yachandra, Vittal K.; Frei, Heinz

    2008-06-03

    The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. These findings will allow for the assembly and photochemical characterization of well defined transition metal molecular units, with the ultimate goal of performing endothermic, multi-electron transformations that are coupled to visible light electron pumps in nanostructured scaffolds.

  2. Evaluating the use of PAO (4 cSt polyalphaoelfin) oil instead of DOP (di-octyl phthalate) oil for measuring the aerosol capture of nuclear canister filters

    SciTech Connect (OSTI)

    Moore, Murray E.

    2014-07-18

    This document details the distinction between using PAO (4 cSt polyalphaoelfin) oil instead of DOP (di-octyl phthalate) oil for measuring the aerosol capture of filters. This document is developed to justify the use of PAO rather than DOP for evaluating the performance of filters in the SAVY 4000 and Hagan containers. The design criteria (Anderson et al, 2012) for purchasing SAVY 4000 containers and the Safety Analysis Report for the SAVY 4000 Container Series specified that the filter must “capture greater than 99.97% of 0.45 μm mean diameter dioctyl phthalate (DOP) aerosol at the rated flow with a DOP concentration of 65±15 micrograms per liter.”This corresponds to a leakage percent of 0.03% (3.0x10-2). The density of DOP oil is 985 kg/m3 and the density of PAO oil is 819 kg/m3. ATI Test Inc measured the mass mean diameter of aerosol distributions produced by a single Laskin type III-A nozzle operating at a 20 psig air pressure as 0.563 μm for DOP oil and 0.549 μm for PAO oil. (See Appendix A.) For both types of oil in this document, the single fiber method calculated the leakage percent to be 4.4x10-5 for DOP oil and 4.7x10-5 for PAO oil. Although the percent error between these two quantities is 7.7%, these calculated leakage percent values are more than two orders of magnitude less than the criterion specified in the SAVY canister SAR. As a point of reference, the photometer used to measure the SAVY canister filter performance cannot resolve values for the leakage percent below 1.0x10-5. Additionally, over a range of particle sizes from 0.01 μm to 3.0 μm, there was less than 4.0x10-5 error between the calculated filter efficiency for the two types of oil at any particular particle size diameter. In conclusion, the difference between using DOP and PAO for testing SAVY canister filters is of inconsequential concern.

  3. INFN - LABORATORI NAZIONALI DI FRASCATI

    Office of Scientific and Technical Information (OSTI)

    1 - FERMILAB-CONF-13-037-APC IHEP-AC-2013-001 SLAC-PUB-15370 CERN-ATS-2013-032 arXiv:1302.3318 physics.acc-ph Report of the ICFA Beam Dynamics Workshop "Accelerators for a Higgs...

  4. Separation of actinides(III) from lanthanides(III) by extraction chromatography using new n,n'-dialkyl-n,n'-diphenyl-pyridine-2,6-di-carboxy-amides

    SciTech Connect (OSTI)

    Arisaka, Makoto; Watanabe, Masayuki; Kimura, Takaumi

    2007-07-01

    Four N,N'-dialkyl-N,N'-diphenyl-pyridine-2,6- di-carboxy-amides (R-PDA; R butyl, octyl, decyl, dodecyl) were newly synthesized and were applied to extraction chromatography as extractant to attain the separation of actinides(III) from high level radioactive waste containing lanthanides(III). R-PDA was successfully impregnated into XAD-4 resin. It was found that (i) the leakage of R-PDA from XAD-4 resin was suppressed with an increase of the length of the alkyl groups in R-PDA, while the leakage for each adsorbent resin was promoted with an increase of HNO{sub 3} concentration in the aqueous phase and (ii) Oc-PDA or De-PDA/XAD-4 resin exhibits moderate separation ability of actinides(III) from lanthanides(III) at relatively high HNO{sub 3} concentration. (authors)

  5. Distinguishing tautomerism in the crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide using DFT-D calculations and {sup 13}C solid-state NMR

    SciTech Connect (OSTI)

    Li, Xiaozhou; Bond, Andrew D.; Johansson, Kristoffer E.; Van de Streek, Jacco

    2014-08-01

    The crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide contains an imine tautomer, rather than the previously reported amine tautomer. The tautomers can be distinguished using dispersion-corrected density functional theory calculations and by comparison of calculated and measured {sup 13}C solid-state NMR spectra. The crystal structure of the title compound, C{sub 11}H{sub 13}N{sub 3}O{sub 2}S{sub 2}, has been determined previously on the basis of refinement against laboratory powder X-ray diffraction (PXRD) data, supported by comparison of measured and calculated {sup 13}C solid-state NMR spectra [Hangan et al. (2010 ▶). Acta Cryst. B66, 615–621]. The mol@@ecule is tautomeric, and was reported as an amine tautomer [systematic name: N-(5-ethyl-1,3,4-thia@@diazol-2-yl)-p-toluene@@sulfonamide], rather than the correct imine tautomer. The protonation site on the mol@@ecule’s 1,3,4-thia@@diazole ring is indicated by the inter@@molecular contacts in the crystal structure: N—H⋯O hydrogen bonds are established at the correct site, while the alternative protonation site does not establish any notable inter molecular inter@@actions. The two tautomers provide essentially identical Rietveld fits to laboratory PXRD data, and therefore they cannot be directly distinguished in this way. However, the correct tautomer can be distinguished from the incorrect one by previously reported qu@@anti@@tative criteria based on the extent of structural distortion on optimization of the crystal structure using dispersion-corrected density functional theory (DFT-D) calculations. Calculation of the {sup 13}C SS-NMR spectrum based on the correct imine tautomer also provides considerably better agreement with the measured {sup 13}C SS-NMR spectrum.

  6. Improving the efficiency of copper indium gallium (Di-)selenide (CIGS) solar cells through integration of a moth-eye textured resist with a refractive index similar to aluminum doped zinc oxide

    SciTech Connect (OSTI)

    Burghoorn, M.; Kniknie, B.; Deelen, J. van; Ee, R. van; Xu, M.; Vroon, Z.; Belt, R. van de; Buskens, P. E-mail: buskens@dwi.rwth-aachen.de

    2014-12-15

    Textured transparent conductors are widely used in thin-film silicon solar cells. They lower the reflectivity at interfaces between different layers in the cell and/or cause an increase in the path length of photons in the Si absorber layer, which both result in an increase in the number of absorbed photons and, consequently, an increase in short-circuit current density (J{sub sc}) and cell efficiency. Through optical simulations, we recently obtained strong indications that texturing of the transparent conductor in copper indium gallium (di-)selenide (CIGS) solar cells is also optically advantageous. Here, we experimentally demonstrate that the J{sub sc} and efficiency of CIGS solar cells with an absorber layer thickness (d{sub CIGS}) of 0.85 μm, 1.00 μm and 2.00 μm increase through application of a moth-eye textured resist with a refractive index that is sufficiently similar to AZO (n{sub resist} = 1.792 vs. n{sub AZO} = 1.913 at 633 nm) to avoid large optical losses at the resist-AZO interface. On average, J{sub sc} increases by 7.2%, which matches the average reduction in reflection of 7.0%. The average relative increase in efficiency is slightly lower (6.0%). No trend towards a larger relative increase in J{sub sc} with decreasing d{sub CIGS} was observed. Ergo, the increase in J{sub sc} can be fully explained by the reduction in reflection, and we did not observe any increase in J{sub sc} based on an increased photon path length.

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Ferretti, M. SPIN-CNR, C.so Perrone 24, 16152 Genova (Italy) (1) Ritter, C. Institute Laue-Langevin, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France) (1) Save Results Save ...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Yapaskurt, V.O. (2) Yuan, Fang (2) Aliakbarian, B. (1) Bernini, C. (1) CNR-SPIN, Corso ... Corso Perrone 24, 16156 Genova ; Bernini, C. ; Perego, P. ; Ferretti, M. ; ...

  9. Effect of Cu{sup 2+} and Ni{sup 2+} substitution at the Mn site...

    Office of Scientific and Technical Information (OSTI)

    Via Dodecaneso 31, 16146 Genova 2 ; Castellano, C. 3 ; Cimberle, M.R. 4 ; Ritter, ... PEAKS Word Cloud More Like This Full Text Journal Articles DOI: 10.1016J.JSSC.2013.01.048

  10. Kinetics of di(2-ethylhexyl) phthalate (DEHP) and mono(2-ethylhexyl) phthalate in blood and of DEHP metabolites in urine of male volunteers after single ingestion of ring-deuterated DEHP

    SciTech Connect (OSTI)

    Kessler, Winfried; Numtip, Wanwiwa; Vlkel, Wolfgang; Seckin, Elcim; Csandy, Gyrgy A.; Institut fr Toxikologie und Umwelthygiene, Technische Universitt Mnchen, Mnchen ; Ptz, Christian; and others

    2012-10-15

    The plasticizer di(2-ethylhexyl) phthalate (DEHP) is suspected to induce antiandrogenic effects in men via its metabolite mono(2-ethylhexyl) phthalate (MEHP). However, there is only little information on the kinetic behavior of DEHP and its metabolites in humans. The toxikokinetics of DEHP was investigated in four male volunteers (2861 y) who ingested a single dose (645 20 ?g/kg body weight) of ring-deuterated DEHP (DEHP-D{sub 4}). Concentrations of DEHP-D{sub 4}, of free ring-deuterated MEHP (MEHP-D{sub 4}), and the sum of free and glucuronidated MEHP-D{sub 4} were measured in blood for up to 24 h; amounts of the monoesters MEHP-D{sub 4}, ring-deuterated mono(2-ethyl-5-hydroxyhexyl) phthalate and ring-deuterated mono(2-ethyl-5-oxohexyl) phthalate were determined in urine for up to 46 h after ingestion. The bioavailability of DEHP-D{sub 4} was surprisingly high with an area under the concentration-time curve until 24 h (AUC) amounting to 50% of that of free MEHP-D{sub 4}. The AUC of free MEHP-D{sub 4} normalized to DEHP-D{sub 4} dose and body weight (AUC/D) was 2.1 and 8.1 times, that of DEHP-D{sub 4} even 50 and 100 times higher than the corresponding AUC/D values obtained earlier in rat and marmoset, respectively. Time courses of the compounds in blood and urine of the volunteers oscillated widely. Terminal elimination half-lives were short (4.36.6 h). Total amounts of metabolites in 22-h urine are correlated linearly with the AUC of free MEHP-D{sub 4} in blood, the parameter regarded as relevant for risk assessment. -- Highlights: ? After DEHP intake, DEHP and MEHP in blood show oscillating time courses. ? Dose-related blood levels of DEHP are 50 times higher in humans than in rats. ? Dose-related blood levels of free MEHP are 2 times higher in humans than in rats. ? Elimination of DEHP and its metabolites is short with half-lives of 4.3-6.6 h.

  11. Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol

    SciTech Connect (OSTI)

    Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K.

    1996-11-01

    Ideal-gas enthalpies of formation of butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo-[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol are reported. Enthalpies of fusion were determined for bicyclo[2.2.1]hept-2-ene and trans-azobenzene. Two-phase (solid + vapor) or (liquid + vapor) heat capacities were determined from 300 K to the critical region or earlier decomposition temperature for each compound studied. Liquid-phase densities along the saturation line were measured for bicyclo[2.2.1]hept-2-ene. For butyl vinyl ether and 1,2-dimethoxyethane, critical temperatures and critical densities were determined from the dsc results and corresponding critical pressures derived from the fitting procedures. Fitting procedures were used to derive critical temperatures, critical pressures, and critical densities for bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, and di-tert-butyl ether. Group-additivity parameters or ring-correction terms useful in the application of the Benson group-contribution correlations were derived.

  12. DI-MMAP V.1.0

    Energy Science and Technology Software Center (OSTI)

    002804WKSTN00 Data-Intensive Memory-Map simulator and runtime https://computation.llnl.gov/casc/dcca-pub/dcca/downloads.ht

  13. Di-Jia Liu | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & high-performance computing Systems architecture & design Physics ... electrode for proton exchange membrane (PEM) fuel cell application; low-cost electrode ...

  14. Basic ReseaRch DiRections

    National Nuclear Security Administration (NNSA)

    ... of nuclear energy to the use of nuclear isotopes for medical diagnostics and treatment. ... probes such as heavy ion accelerators, neutron sources, and rare isotope facilities. ...

  15. DI Semicon Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Seoul, Korea (Republic) Sector: Solar Product: Korean company that offers testing and packaging of Display Drive ID; as of December 2007, entered into a secondary business in solar...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  17. Instituto Torcuato Di Tella (ITDT) | Open Energy Information

    Open Energy Info (EERE)

    In the beginning, ITDT categorized activities through research centers specializing in different subjects, mainly economics, social sciences, urban planning, and the arts....

  18. Women @ Energy: Pascale Di Nicola | Department of Energy

    Office of Environmental Management (EM)

    I have always loved science in general; mathematics, physics, and chemistry were my ... I wanted to study organic chemistry to become a fragrance designer, so I followed the ...

  19. Di- and tri-benzotriazole substituted tri-hydroxybenzenes

    DOE Patents [OSTI]

    Vogl, O.; Li, S.

    1983-10-06

    Ultraviolet light stabilizing compounds of the formula (phenyl) R/sub 1/, R/sub 2/(OH)/sub 3/R/sub 3/, are described, wherein R/sub 1/, R/sub 2/, and R/sub 3/ are hydrogen or 2H-benzotriazole-2-yl groups and wherein no more than one of R/sub 1/, R/sub 2/, and R/sub 3/ is hydrogen, and organic compositions susceptible to ultraviolet light degradation containing these compounds, and method for selectively producing the compounds.

  20. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  1. AquaLite Wuhan Di Yuan Optoelectronic | Open Energy Information

    Open Energy Info (EERE)

    Place: Wuhan, Hubei Province, China Zip: 430074 Product: High-power and high-brightness LED manufacturer. Coordinates: 30.572399, 114.279121 Show Map Loading map......

  2. Efficient Emissions Control for Multi-Mode Lean DI Engines

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  3. Process for selective production of di- and tri-alkylamines

    DOE Patents [OSTI]

    Klier, Kamil; Herman, Richard G.; Vedage, Gamini A.

    1984-01-01

    A primary alkyl amine and an alcohol of up to 12 carbon atoms are reacted at low temperature (50.degree.-250.degree. C.) over specific catalysts (alkali-treated catalysts generally or binary Cu/ZnO and Pd/SiO.sub.2 systems, with or without alkali treatment) to produce, with good selectivity, secondary and tertiary alkylamines of the general formula, R.sub.1 N(R.sub.2).sub.2, wherein R.sub.1 is a lower alkyl or an aryl group, and R.sub.2 is hydrogen or another lower alkyl or aryl group, with at least one of R.sub.2 's being an alkyl or aryl group.

  4. DI-MGMT-81861 DOE Changes Version | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earned Value Management System Interpretation Handbook (EVMSIH) Enhancing Earned Value (EV) Analysis Using Project Assessment & Reporting System (PARS II) - Road Show Presentation...

  5. Overview of Sonex Combustion Systems (SCS) for DI Engines

    Broader source: Energy.gov [DOE]

    The SCS system has undergone computational and experimental verification and allows for controlled auto-ignition of low-cetane fuels.

  6. DI-MGMT-81861 DOE Changes Version -- Integrated Program Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Program Management Report (IPMR) Data Item Description (DID) Earned Value Management System Interpretation Handbook (EVMSIH) Enhancing Earned Value (EV) Analysis Using ...

  7. Institute for Advanced Study Christine Di Bella Institute for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    driven research in the sciences and humanities. Diverse schol- ars including Albert Einstein, Erwin Panofsky, John von Neu- mann, J. Robert Oppenheimer, Freeman Dyson,...

  8. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Surface Di-directional Reflectance Properties Over the ARM SGP...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Introduction Surface albedo is an important parameter in atmospheric...

  11. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  12. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  13. Crystal structure of cerium (IV)-di-potassium trisulfate monohydrate

    SciTech Connect (OSTI)

    Kuznetsov, V.Ya.; Dikareva, L.M.; Rogachev, D.L.; Porai-Koshits, M.A.

    1986-07-01

    The compound K2Ce(SO4)3 x H2O (I) was obtained in a study of the system Ce(SO4)2-K2SO4-H2O4-HO2 at 50-150C (1). The refined unit-cell parameters are: a = 20.600(3), b = 7.0744 (6), c = 18.583(3) A, US = 126.083(8), V = 2189(1) AT, Z = 8, rho/sub calc/ = 3.202(2) g/cmT, space group C2. The previously given unit-cell parameters are related to those given here by the matrices 100/010/0.5 0 1 and 100/010/-1 0-1. The intensities of 3416 independent reflections (3363 with I greater than or equal to 2sigma) and the unit cell parameters were measured on a Syntex P21 four-circle automatic diffractometer (lambdaMoK , theta/2 theta scanning at variable rate from 4 to 29.3 deg/min to theta = 60). The structural calculations were done on a Nova 1200 minicomputer by means of the Syntex XTL programs and on an ES 1022 computer by means of the Struktura programs. They used the heavy atom method; the final refinement over 3240 reflections (R = 0.071) was made allowing for the anisotropy of the thermal vibrations of the atoms.

  14. Apparatus to study crystal channeling and volume reflection phenomena...

    Office of Scientific and Technical Information (OSTI)

    De Salvador, Davide 3 ; Dipartimento di Fisica, Universita di Padova, Via Marzolo 8, ... INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara, Via Saragat 1, ...

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... De Francesco, A. (1) Devetta, M. CIMAINA and Dipartimento di Fisica, Universit di ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  16. Volume Reflection Dependence of 400 GeV/c Protons on the Bent...

    Office of Scientific and Technical Information (OSTI)

    INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara Via Saragat 1, ... 06123 Perugia (Italy) Dipartimento di Fisica, Universita degli Studi di Perugia via ...

  17. High-Efficiency Deflection of High-Energy Protons through Axial...

    Office of Scientific and Technical Information (OSTI)

    INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara, Via Saragat 1, ... degli Studi di Perugia, Dipartimento di Fisica, Via Pascoli, 06123 Perugia (Italy) INFN ...

  18. Synthesis, characterization, and structure of a uranyl complex with a disulfide ligand, Bis(di-n-propylammonium) Disulfidobis(di-n-propylthiocarbamato)dioxouranate(VI)

    SciTech Connect (OSTI)

    Perry, D.L.; Zalkin, A.; Ruben, H.; Templeton, D.H.

    1982-01-01

    Olive green crystals of the title compound, ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2//sup +/)/sub 2/(UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/, are orthorhombic, space group Pcan, with a = 15.326 (6) A, b = 17.474 (6) A, c = 14.728 (6) A, and Z = 4 (d/sub x/ = 1.45 g/cm/sup 3/). For 1833 data, I > sigma/sub I/, R = 0.052, and R/sub w/ = 0.069. The structure was revealed by single-crystal x-ray diffraction studies to consist of ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2/)/sup +/ cations and (UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/ anions with the uranium atom at the center of an irregular hexagonal bipyramid. The uranyl oxygen atoms occupy the axial positions. The equatorial coordiantion plane contains the disulfide (S/sub 2//sup 2 -/) group bonded in a side-on fashion and two oxygen and two sulfur donor atoms from the monothiocarbamate ligands. Interatomic distances are S-S = 2.05 (1) A and U-S = 2.711 (3) A (disulfide), U-S = 2.873 (3) A and U-O = 2.48 (1) A (thiocarbamate), and U-0 = 1.82 (1) A (uranyl). The nitrogen atom in the dipropylammonium cation is hydrogen bonded to the uranyl oxygen atoms.

  19. SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF A URANYL COMPLEX WITH A DISULFIDE LIGAND, BIS(DI-n-PROPYLAMMONIUM) DISULFIDOBIS (DI-n-PROPYLMONOTHIOCARBAMATO) DIOXOURANATE(VI)

    SciTech Connect (OSTI)

    Perry, Dale L.; Zalkin, Allan; Ruben, Helena; Templeton, David H.

    1981-05-01

    Olive-green crystals of the title compound, [({underline n}-C{sub 3}H{sub 7}){sub 2}NH{sub 2}{sup +}]{sub 2} [UO(({underline n}-C{sub 3}H{sub 7}){sub 2}NCOS){sub 2}(S{sub 2}){sup -2}, are orthorhombic, space group Pcan, with {underline a}= 15.326(6) {Angstrom}, {underline b} = 17.474(6) {Angstrom}, {underline C} = 14.728(6) {Angstrom}, and Z = 4, (d{sub X} = 1.45 g/cm{sup 3}). For 1833 data, I >{sigma}, R = 0.052, and R{sub w} = 0.069. The structure was revealed by single-crystal x-ray diffraction studies to consist of [(n-C{sub 3}H{sub 7}){sub 2}NH{sub 2}]+ cations and [UO{sub 2}(({underline n|-C{sub 3}H{sub 7}){sub 2}NCOS){sub 2}(S{sub 2}){sup -2} anions with the uranium atom at the center of an irregular hexagonal bipyramid. The uranyl oxygen atoms occupy the axial positions. The equatorial coordination plane contains the disulfide (S{sub 2}{sup -2}) group bonded in a "side-on" fashion, and two oxygen and two sulfur donor atoms from the monothiocarbamate ligands. Interatomic distances are S-S = 2.05(1) {Angstrom}, U-S= 2.714(3) {Angstrom} (disulfide); U-S= 2.871(3) {Angstrom} and U-O = 2.46(1) {Angstrom} (thiocarbamate); U-O = 1.81(1) {Angstrom} (uranyl), The nitrogen atom in the dipropylammonium cation is hydrogen bonded to the uranyl oxgyen atoms,

  20. Chromatographic extraction with di(2-ethylhexyl)orthophosphoric acid for production and purification of promethium-147

    DOE Patents [OSTI]

    Boll, Rose A [Knoxville, TN

    2008-10-14

    A method of producing and purifying promethium-147 including the steps of: irradiating a target material including neodymium-146 with neutrons to produce promethium-147 within the irradiated target material; dissolving the irradiated target material to form an acidic solution; loading the acidic solution onto a chromatographic separation apparatus containing HDEHP; and eluting the apparatus to chromatographically separate the promethium-147 from the neodymium-146.

  1. DEPARTMENT OF FNERGY EERE PROJECT MANAGEMENT CENTER NFPA DI!TERJ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEPARTMENT OF FNERGY EERE PROJECT MANAGEMENT CENTER NFPA DITERJ.fiNATION ... publication. and distribution; and classroom training and informational programs), ...

  2. Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel...

    Broader source: Energy.gov (indexed) [DOE]

    Effects of Ambient Density and Temperature on Soot Formation under High-EGR Conditions Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines Optical-Engine ...

  3. A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer...

    Broader source: Energy.gov (indexed) [DOE]

    Mixture Formation: Preliminary Results Diesel HCCI with External Mixture Preparation A Micro-Variable Circular Orifice (MVCO) Fuel Injector for Zoned Low Temperature Combustion

  4. A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application

    SciTech Connect (OSTI)

    Fang, Howard L.; Huang, Shyan C.; Yu, Robert C.; Wan, C. Z.; Howden, Ken

    2002-10-01

    Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

  5. Helicity amplitudes of di-photons production at the LHC with scalar unparticles intermediate states

    SciTech Connect (OSTI)

    Aliane, I.; Mebarki, N.; Haouchine, M.

    2012-06-27

    The helecity amplitudes of the subprocess gg{yields}{gamma}{gamma} via scalar unparticles intermediate states are calculated. The differential cross section is compared to that of the standard model. Phenomenological implications are also discussed.

  6. Cylinder-averaged histories of nitrogen oxide in a D.I. diesel with simulated turbocharging

    SciTech Connect (OSTI)

    Donahue, R.J.; Borman, G.L.; Bower, G.R.

    1994-10-20

    An experimental study was conducted using the dumping technique (total cylinder sampling) to produce cylinder mass-averaged nitric oxide histories. Data were taken using a four stroke diesel research engine employing a quiescent chamber, high pressure direct ijection fuel system, and simulated turbocharging. Two fuels were used to determine fuel cetane number effects. Two loads were run, one at an equivalence ratio of 0.5 and the other at a ratio of 0.3. The engine speed was held constant at 1500 rpm. Under the turbocharged and retarded timing conditions of this study, nitric oxide was produced up to the point of about 85% mass burned. Two different models were used to simulate the engine mn conditions: the phenomenological Hiroyasu spray-combustion model, and the three dimensional, U.W.-ERO modified KIVA-lI computational fluid dynamic code. Both of the models predicted the correct nitric oxide trend. Although the modified KIVA-lI combustion model using Zeldovich kinetics correctly predicted the shapes of the nitric oxide histories, it did not predict the exhaust concentrations without arbitrary adjustment based on experimental values.

  7. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  8. Effect of pilot injection on combustion in a turbocharged D.I. diesel engine

    SciTech Connect (OSTI)

    Ishida, Masahiro; Chen, Z.L.; Luo, G.F.; Ueki, Hironobu

    1994-09-01

    For reducing the exhaust emissions and improving the ignition characteristics, the effect of pilot injection was investigated experimentally in a turbocharged direct injection diesel engine. The pilot injection quantity was varied by changing the seat diameter of the Doge plunger installed in the newly developed pilot injector while the separation period between the beginning of pilot injection and that of main injection was fixed at a short interval in the present experiment. The pilot injection effect on combustion was compared with the case of normal injection in two fuel oils with the cetane indexes of 53 and 40-respectively. The pilot injection showed some significant effects on improving the ignition characteristics and fuel consumption as follows: (1) The pilot ignition delay and the main ignition delay were about half of the ignition delay of the normal injection respectively. (2) The lower fuel consumption and NOx could be attained by the pilot injection at the retarded injection timing, especially under the lower load condition. (3) The trade-off relationship between the specific fuel consumption and NOx was significantly improved by the pilot injection. (4) In the present short pilot-main interval, a small amount of pilot quantity was recommended to reduce NOx and fuel consumption without deteriorating smoke density. 12 refs., 16 figs., 1 tab.

  9. Table A26. Components of Total Electricity Demand by Census Region, Census Di

    U.S. Energy Information Administration (EIA) Indexed Site

    Components of Total Electricity Demand by Census Region, Census Division, and" " Economic Characteristics of the Establishment, 1994" " (Estimates in Million Kilowatthours)" " "," "," "," ","Sales/"," ","RSE" " "," ","Transfers","Onsite","Transfers"," ","Row" "Economic

  10. Doubly Heavy Baryons, Heavy Quark-DiQuark Symmetry and NRQCD...

    Office of Scientific and Technical Information (OSTI)

    Date: 2005-09-27 OSTI Identifier: 850526 Report Number(s): JLAB-THY-05-415; DOEER40150-3612; hep-ph0509313 DOE Contract Number: AC05-84ER40150 Resource Type: Journal...

  11. Microsoft Word - SWPF-15-DI-001_R1_Construction Turnover to C&T Oversight

    Office of Environmental Management (EM)

    April 6, 2015 1 SAFETY SYSTEM OVERSIGHT ANNUAL AWARD PROGRAM OBJECTIVE The Safety System Oversight (SSO) Annual Award is a special award designed to recognize superior or exemplary service by an employee who has performed SSO functions. This special award program has been established in accordance with the requirements of Department of Energy (DOE) Order 331.1C, Employee Performance Management and Recognition Program. SAFETY SYSTEM OVERSIGHT ANNUAL AWARD The SSO Annual Award recipient is

  12. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain

    Broader source: Energy.gov [DOE]

    Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  13. Resonance-continuum interference in the di-photon Higgs signal at the LHC

    SciTech Connect (OSTI)

    Dixon, Lance

    2003-02-25

    A low mass Standard Model Higgs boson should be visible at the Large Hadron Collider through its production via gluon-gluon fusion and its decay to two photons. We compute the interference of this resonant process, gg {yields} H {yields} {gamma}{gamma}, with the continuum QCD background, gg {yields} {gamma}{gamma} induced by quark loops. Helicity selection rules suppress the effect, which is dominantly due to the imaginary part of the two-loop gg {yields} {gamma}{gamma} scattering amplitude. The interference is destructive, but only of order 5% in the Standard Model, which is still below the 10-20% present accuracy of the total cross section prediction. We comment on the potential size of such effects in other Higgs models.

  14. DI-MGMT-81861 DOE Changes Version-- Integrated Program Management Report

    Office of Energy Efficiency and Renewable Energy (EERE)

    Integrated Program Management Report (IPMR) combines the Contractor Performance Report (CPR) and Integrated Master Schedule (IMS) reporting requirements on contracts requiring Earned Value Management (EVM) reporting of project/contract performance.

  15. Idling Emissions Reduction Technology with Low Temperature Combustion of DI Biodiesel and PFI n-Butanol

    Broader source: Energy.gov [DOE]

    Results from an idling strategy using PCCI coupled with LTC indicate that, when used with n-butanol, it can be very promising for extended idling including the LTC regimes.

  16. The Role of The fedeRal PRojecT diRecToR

    Office of Environmental Management (EM)

    Subcommittee on Energy and Power Committee on Energy and Commerce U.S. House of Representatives February 11, 2015 Chairman Upton, Ranking Member Pallone, Chairman Whitfield, Ranking Member Rush, and Members of the Subcommittee, thank you for the opportunity to appear before you today to discuss the Department of Energy's (DOE) Budget Request for fiscal year (FY) 2016. I appreciate the opportunity to discuss how the Budget Request advances the Department of Energy's missions. Advancing Nuclear

  17. Doubly Heavy Baryons, Heavy Quark-DiQuark Symmetry and NRQCD...

    Office of Scientific and Technical Information (OSTI)

    This method is used to rederive Lagrangians for the Qbar Q and QQ sectors of pNRQCD and give a correct derivation of the O(1mQ) prediction for the hyperfine splitting of doubly ...

  18. Vehicle Technologies Office Merit Review 2014: Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratories at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced lean...

  19. MHK Projects/Colorado River Indian Tribes IRR DI | Open Energy...

    Open Energy Info (EERE)

    Organization Marine Power Water Inc Project Licensing FERC License Docket Number P-13350 Environmental Monitoring and Mitigation Efforts See Tethys << Return to the MHK database...

  20. A Conceptual Model of DI Diesel Combustion Based on Laser-Sheet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Table 2 summarizes the specifications of the fuel injector. The injector is instru- mented with a Hall-effect needle lift sensor, and injection pressure is determined from strain ...

  1. Vehicle Technologies Office Merit Review 2015: Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about advanced lean-burn...

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... di Chimica, Biologia e Biotecnologie, Universit degli Studi di Perugia, 06123 Perugia (Italy) (1) Roncaratti, Luiz F. Dipartimento di Chimica, Biologia e Biotecnologie, ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Francesco, E-mail: francesco.tarantelli@unipg.it ; Dipartimento di Chimica, Biologia e Biotecnologie, Universit degli Studi di Perugia, via Elce di Sotto 8, I-06123 ...

  4. Catching the role of anisotropic electronic distribution and...

    Office of Scientific and Technical Information (OSTI)

    ... del CNR, Perugia 06123 5 + Show Author Affiliations Dipartimento di Chimica, Biologia e Biotecnologie, Universit di Perugia, Perugia 06123 (Italy) Istituto di Scienze e ...

  5. Browse by Discipline -- E-print Network Subject Pathways: Biotechnolog...

    Office of Scientific and Technical Information (OSTI)

    ... Romu (Romu Romero) - Departament de Fsica, Universitat de les Illes Balears Romps, ... Universit di - Dipartimento di Fisica, Laboratorio di Fisica Terrestre Royal ...

  6. Stress effects on the elastic properties of amorphous polymeric...

    Office of Scientific and Technical Information (OSTI)

    Istituto Officina dei Materiali del CNR (CNR-IOM) - Unit di Perugia, co Dipartimento di Fisica e Geologia, Perugia I-06100 (Italy) Dipartimento di Fisica e Geologia, Universit ...

  7. Evidence of Luttinger-liquid behavior in one-dimensional dipolar...

    Office of Scientific and Technical Information (OSTI)

    Dipartimento di Fisica E. R. Caianiello and CNISM, Universita degli Studi di Salerno, ... DEMOCRITOS INFM-CNR and Dipartimento di Fisica Teorica, Universita Trieste, Trieste ...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Paciaroni, A., E-mail: alessandro.paciaroni@fisica.unipg.it (1) Petrillo, C. (1) ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  9. Hydration-dependent dynamics of human telomeric oligonucleotides...

    Office of Scientific and Technical Information (OSTI)

    Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ... A., E-mail: alessandro.paciaroni@fisica.unipg.it 1 ; De Francesco, A. 3 ; ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ; INFN Sezione di Ferrara, via Saragat 1, 44100 Ferrara, Italy, ; and Dipartimento di Fisica, Universita di Ferrara, via Saragat 1, 44100 Ferrara A new mechanism of adjustment of...

  11. Microsoft Word - Mazzocco_abs_11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marco Mazzocco Dipartimento di Fisica and INFN - Sezione di Padova, Padova, Italy The ... (RIB's) is now fully operational at the Laboratori Nazionali di Legnaro (LNL, Italy). ...

  12. Angle-resolved spin wave band diagrams of square antidot lattices...

    Office of Scientific and Technical Information (OSTI)

    (IOM-CNR), Sede di Perugia, co Dipartimento di Fisica e Geologia, Via A. Pascoli, I-06123 Perugia (Italy) Dipartimento di Fisica e Scienze della Terra, Universit di Ferrara, ...

  13. Lanthanide(III) di- and tetra-nuclear complexes supported by a chelating tripodal tris(amidate) ligand

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Jessie L.; Jones, Matthew B.; Gaunt, Andrew J.; Scott, Brian L.; MacBeth, Cora E.; Gordon, John C.

    2015-04-06

    Syntheses, structural, and spectroscopic characterization of multinuclear tris(amidate) lanthanide complexes is described. Addition of K3[N(o-PhNC(O)tBu)3] to LnX3 (LnX3 = LaBr3, CeI3, and NdCl3) in N,N-dimethylformamide (DMF) results in the generation of dinuclear complexes, [Ln(N(o-PhNC(O)tBu)3)(DMF)]2(μ-DMF) (Ln = La (1), Ce (2), Nd(3)), in good yields. Syntheses of tetranuclear complexes, [Ln(N(o-PhNC(O)tBu)3)]4 (Ln = Ce (4), Nd(5)), resulted from protonolysis of Ln[N(SiMe3)2]3 (Ln = Ce, Nd) with N(o-PhNCH(O)tBu)3. As a result, in the solid-state, complexes 1–5 exhibit coordination modes of the tripodal tris(amidate) ligand that are unique to the 4f elements and have not been previously observed in transition metal systems.

  14. STUDY OF THE RECURRING DIMMING REGION DETECTED AT AR 11305 USING THE CORONAL DIMMING TRACKER (CoDiT)

    SciTech Connect (OSTI)

    Krista, Larisza D.; Reinard, Alysha

    2013-01-10

    We present a new approach to coronal dimming detection using the COronal DImming Tracker tool (CODIT), which was found to be successful in locating and tracking multiple dimming regions. This tool, an extension of a previously developed coronal hole tracking software, allows us to study the properties and the spatial evolution of dimming regions at high temporal and spatial cadence from the time of their appearance to their disappearance. We use Solar Dynamics Observatory/Atmospheric Imaging Assembly 193 A wavelength observations and Helioseismic and Magnetic Imager magnetograms to study dimmings. As a demonstration of the detection technique we analyzed six recurrences of a dimming observed near AR 11305 between 2011 September 29 and October 2. The dimming repeatedly appeared and formed in a similar way, first expanding then shrinking and occasionally stabilizing in the same location until the next eruption. The dimming areas were studied in conjunction with the corresponding flare magnitudes and coronal mass ejection (CME) masses. These properties were found to follow a similar trend during the observation period, which is consistent with the idea that the magnitude of the eruption and the CME mass affect the relative sizes of the consecutive dimmings. We also present a hypothesis to explain the evolution of the recurrent single dimming through interchange reconnection. This process would accommodate the relocation of quasi-open magnetic field lines and hence allow the CME flux rope footpoint (the dimming) to expand into quiet-Sun regions. By relating the properties of dimmings, flares, and CMEs we improve our understanding of the magnetic field reconfiguration caused by reconnection.

  15. A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine

    Broader source: Energy.gov [DOE]

    A single-cylinder engine was used to study how selected oxygenated fuels affect combustion and emissions in a modern diesel engine during conventional combustion and low-temperature combustion (LTC).

  16. DE-EM-0001971 WIPP M&O D-i PART I - THE SCHEDULE SECTION D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Identifies the contract number under which the item is being delivered; and * Identifies the contract requirement or other instruction which requires the delivered item(s)....

  17. Microsoft Word - 2014_01_10 D&I At a Glance_v4_dda.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 4 Strategic Projects Table 4: Strategic Projects Strategic Project Description (25 words or less) Objectives FY funded 1. Workforce Pipeline Engage and develop current employees and ...

  18. HCCI and Stratified-Charge CI Engine Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... CNL, DI-60 CNL, PFS CNL, PM RI, DI-60 RI, PFS RI, PM CA50 Sweeps at Constant Fueling P in 2.4 bar, PM, std. PFS, & Early -DI Adapted Matlab code for combustion noise level ...

  19. Compact

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compact soft x-ray multichord camera: Design and initial operation P. Franz Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy and Istituto Nazionale di Fisica della Materia, Unita ` di Ricerca di Padova, Italy G. Gadani Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy R. Pasqualotto Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy and Istituto Nazionale di Fisica della Materia, Unita ` di Ricerca di Padova, Italy L. Marrelli Consorzio RFX-Associazione EURATOM

  20. Role of the antiferromagnetic pinning layer on spin wave properties...

    Office of Scientific and Technical Information (OSTI)

    Authors: Gubbiotti, G., E-mail: gubbiotti@fisica.unipg.it ; Tacchi, S. 1 ; Del Bianco, ... 4 ; Tamisari, M. 4 ; Dipartimento di Fisica e Geologia, Universit di Perugia, ...

  1. Ion implantation for manufacturing bent and periodically bent...

    Office of Scientific and Technical Information (OSTI)

    Galilei, University of Padova, Via Marzolo 8, 35131 Padova (Italy) Dipertimento di Economia e Tecnologia, Universit degli Studi della Repubblica di San Marino, Salita alla ...

  2. The Hubble space telescope UV legacy survey of galactic globular...

    Office of Scientific and Technical Information (OSTI)

    a.cunial@studenti.unipd.it 1 ; and others + Show Author Affiliations Dipartimento di Fisica e Astronomia "Galileo Galilei," Universit di Padova, Vicolo dell'Osservatorio 3,...

  3. Chirality of weakly bound complexes: The potential energy surfaces...

    Office of Scientific and Technical Information (OSTI)

    Instituto de Fsica, Universidade de Braslia, 70910 Braslia (Brazil) Dipartimento di Chimica, Biologia e Biotecnologie, Universit di Perugia, 06123 Perugia (Italy) (Brazil) ...

  4. Browse by Discipline -- E-print Network Subject Pathways: Energy...

    Office of Scientific and Technical Information (OSTI)

    ... Andrea (Andrea Marini) - Dipartimento di Fisica, Universit di Roma Tor Vergata ... Marko) - Departments of Biochemistry, Molecular Biology, and Cell Biology & Physics and ...

  5. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Zabaras, Nicholas J. (Nicholas J. Zabaras) - School of Engineering, University of Warwick Zaccarelli, Emanuela (Emanuela Zaccarelli) - Dipartimento di Fisica, Universit di Roma ...

  6. Center for Nanophase Materials Sciences (CNMS) - CNMS User Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    di Fisica "A. Volta", Universita degli Studi di Pavia, via Bassi 6, 27100 Pavia, Italy Department of Physics and Institute for Optical Sciences, University of Toronto, 60 St. ...

  7. Center for Nanophase Materials Sciences (CNMS) - CNMS Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    di Fisica "A. Volta", Universita degli Studi di Pavia, via Bassi 6, 27100 Pavia, Italy Department of Physics and Institute for Optical Sciences, University of Toronto, 60 St. ...

  8. Micro-focused Brillouin light scattering study of the magnetization...

    Office of Scientific and Technical Information (OSTI)

    Authors: Madami, M., E-mail: marco.madami@fisica.unipg.it ; Carlotti, G. 1 ; Gubbiotti, ... Show Author Affiliations Dipartimento di Fisica e Geologia, Universit di Perugia, ...

  9. Disorder effects in the {ital t}-{ital J} model (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Authors: Caprara, S. 1 ; Dipartimento di Fisica, Universita Tor Vergata, Via della ... Dipartimento di Fisica, Universita La Sapienza, Piazzale Aldo Moro, 00185 Roma (Italy) ...

  10. High-resolution Soft-RIXS: Scientific Goals and Technical Challenges...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SSRL Conference Room 137-322 Giacomo Ghiringhelli, CNRSPIN and Dipartimento di Fisica, Politecnico di Milano, Italy Visiting scholar at SIMES-Department of physics, Stanford ...

  11. Efficiency evaluation of the DISC (direct-injection stratified charge), DHC (dilute homogeneous charge), and DI Diesel engines (direct-injection diesel)

    SciTech Connect (OSTI)

    Hane, G.J.

    1983-09-01

    The thermodynamic laws governing the Otto and diesel cycle engines and the possible approaches that might be taken to increase the delivered efficiency of the reciprocating piston engine are discussed. The generic aspects of current research are discussed and typical links between research and the technical barriers to the engines' development are shown. The advanced engines are discussed individually. After a brief description of each engine and its advantages, the major technical barriers to their development are discussed. Also included for each engine is a discussion of examples of the linkages between these barriers and current combustion and thermodynamic research. For each engine a list of questions is presented that have yet to be resolved and could not be resolved within the scope of this study. These questions partially indicate the limit to the state of knowledge regarding efficiency characteristics of the advanced engine concepts. The major technical barriers to each of the engines and their ranges of efficiency improvement are summarized.

  12. The effect of TDC temperature and density on the liquid-phase fuel penetration in a D.I. Diesel engine

    SciTech Connect (OSTI)

    Espey, C.; Dec, J.E.

    1995-12-01

    A parametric study of the liquid-phase fuel penetration of evaporating Diesel fuel jets has been conducted in a directinjection Diesel engine using laser elastic-scatter imaging. The experiments were conducted in an optically accessible Diesel engine of the ``heavy-duty`` size class at a representative medium speed (1200 rpm) operating condition. The density and temperature at TDC were varied systematically by adjusting the intake temperature and pressure. At all operating conditions the measurements show that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum length. Then, the liquid-fuel penetration length remains fairly constant although fuel injection continues. At a TDC density of 16.6 kg/m{sup 3} and a temperature of about 1000 K the maximum penetration length is approximately 23 mm. However, it varies significantly as TDC conditions are changed, with the liquid-length being less at higher temperatures and at higher densities. The corresponding apparent heat release rate plots are presented and the results of the liquid-phase fuel penetration are discussed with respect to the ignition delay and premixed bum fraction.

  13. Development of a process for the extraction of {sup 137}Cs from acidic HLLW based on crown-calix extractant use of di-alkylamide modifier

    SciTech Connect (OSTI)

    Alexova, J.; Sirova, M.; Rais, J.; Suzuki, S.; Hirata, M.; Kimura, T.; Tachimori, S.

    2008-07-01

    Within the framework of the ARTIST project of total fuel retreatment with ecological mixtures of solvents and extractants containing only C, H, O, and N atoms, a process segment of extraction of {sup 137}Cs from acidic stream was developed. The process with 25,27-Bis(1-octyloxy)calix[4]arene-crown- 6, DOC[4]C6, dissolved at its 0.01 M concentration in a mixture of 90 vol % 1-octanol and 10% dihexyl octanamide, DHOA was proposed as a viable variant due to its good multicycle performance, even with irradiated solvent, and due to the good chemical stability of the chosen combination of solvent mixture. (authors)

  14. Measurement of Transverse Single-Spin Asymmetries for Di-JetProduction in Proton-Proton Collisions at sqrt s = 200 GeV

    SciTech Connect (OSTI)

    Abelev, B.I.; Adams, J.; Aggarwal, M.M.; Ahammed, Z.; Amonett,J.; Anderson, B.D.; Anderson, M.; Arkhipkin, D.; Averichev, G.S.; Bai,Y.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellingeri-Laurikainen, A.; Bellwied, R.; Benedosso, F.; Bhardwaj, S.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L.C.; Blyth, S.-L.; Bonner, B.E.; Botje, M.; Bouchet, J.; Brandin, A.V.; Bravar, A.; Bystersky, M.; Cadman, R.V.; Cai,X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Castillo, J.; Catu,O.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen,H.F.; Chen, J.H.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cosentino, M.R.; Cramer, J.G.; Crawford,H.J.; Das, D.; Das, S.; Daugherity, M.; de Moura, M.M.; Dedovich, T.G.; DePhillips, M.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Djawotho,P.; Dogra, S.M.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dunin, V.B.; Dunlop, J.C.; Dutta Mazumdar, M.R.; Eckardt, V.; Edwards, W.R.; Efimov,L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch,E.; Fine, V.; Fisyak, Y.; Fu, J.; Gagliardi, C.A.; Gaillard, L.; Ganti,M.S.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.S.; Gorbunov, Y.G.; Gos,H.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Guimaraes, K.S.F.F.; Guo,Y.; Gupta, N.; Gutierrez, T.D.; Haag, B.; Hallman, T.J.; Hamed, A.; Harris, J.W.; He, W.; Heinz, M.; Henry, T.W.; Hepplemann, S.; Hippolyte,B.; Hirsch, A.; Hjort, E.; Hoffman, A.M.; Hoffmann, G.W.; Horner, M.J.; Huang, H.Z.; Huang, S.L.; Hughes, E.W.; Humanic, T.J.; Igo, G.; Jacobs,P.; Jacobs, W.W.; Jakl, P.; Jia, F.; Jiang, H.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kang, K.; Kapitan, J.; Kaplan, M.; Keane, D.; Kechechyan, A.; Khodyrev, V.Yu.; Kim, B.C.; Kiryluk, J.; Kisiel, A.; Kislov, E.M.; Klein,S.R.; Kocoloski, A.; Koetke, D.D.; et al.

    2007-10-02

    We report the first measurement of the opening angledistribution between pairs of jets produced in high-energy collisions oftransversely polarized protons. The measurement probes (Sivers)correlations between the transverse spin orientation of a proton and thetransverse momentum directions of its partons. With both beams polarized,the wide pseudorapidity (-1 leq eta leq +2) coverage for jets permitsseparation of Sivers functions for the valence and sea regions. Theresulting asymmetries are all consistent with zero and considerablysmaller than Sivers effects observed in semi-inclusive deep inelasticscattering (SIDIS). We discuss theoretical attempts to reconcile the newresults with the sizable transverse spin effects seen in SIDIS andforward hadron production in pp collisions.

  15. Calcium-Dependent Conformation of a Heme and Fingerprint Peptide of the Di-Heme Cytochrome c Peroxidase from Paracoccus Pantotrophus

    SciTech Connect (OSTI)

    PAULETA,SOFIA R.; LU,YI; GOODHEW,CELIA F.; MOURA,ISABEL; PETTIGREW,GRAHAM W.; SHELNUTT,JOHN A.

    2000-12-18

    The structural changes in the heme macrocycle and substituents caused by binding of Ca{sup 2+} to the diheme cytochrome c peroxidase from Paracoccuspantotrophus were clarified by resonance Raman spectroscopy of the inactive filly oxidized form of the enzyme. The changes in the macrocycle vibrational modes are consistent with a Ca{sup 2+}-dependent increase in the out-of-plane distortion of the low-potential heme, the proposed peroxidatic heme. Most of the increase in out-of-plane distortion occurs when the high affinity site I is occupied, but a small further increase in distortion occurs when site II is also occupied by Ca{sup 2+}or Mg{sup 2+}. This increase in the heme distortion also explains the red shift in the Soret absorption band that occurs upon Ca{sup 2+} binding. Changes also occur in the low frequency substituent modes of the heme, indicating that a structural change in the covalently attached fingerprint pentapeptide of the LP heme occurs upon CM{sup 2+} binding to site I. These structural changes, possibly enhanced in the semi-reduced form of the enzyme, may lead to loss of the sixth ligand at the peroxidatic heme and activation of the enzyme.

  16. di Synthesis and Characterization of the Platinum-Substituted Keggin Anion alpha-H2SiPtW11O404-

    SciTech Connect (OSTI)

    Klonowski, P; Goloboy, JC; Uribe-Romo, FJ; Sun, FR; Zhu, LY; Gandara, F; Wills, C; Errington, RJ; Yaghi, OM; Klemperer, WG

    2014-12-15

    Acidification of an aqueous solution of K8SiW11O39 and K2Pt(OH)(6) to pH 4 followed by addition of excess tetramethylammonium (TMA) chloride yielded a solid mixture of TMA salts of H2SiPtW11O404- (1) and SiW12O404- (2). The former was separated from the latter by extraction into an aqueous solution and converted into tetra-n-butylammonium (TBA) and potassium salts TBA-1 and K-1. The a-H2SiPtW11O404- was identified as a monosubstituted Keggin anion using elemental analysis, IR spectroscopy, X-ray crystallography, electrospray ionization mass spectrometry, Pt-195 NMR spectroscopy, (183)W NMR spectroscopy, and W-183-W-183 2D INADEQUATE NMR spectroscopy. Both TBA-1 and K-1 readily cocrystallized with their unsubstituted Keggin anion salts, TBA-2 and K-2, respectively, providing an explanation for the historical difficulty of isolating certain platinum-substituted heteropolyanions in pure form.

  17. nersc-brownbag-docker-jacobsen-canon.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jacobsen & Shane Canon Contain This, Unleashing Docker for HPC --- 1 --- Repeat o f Cray U ser G roup 2 015 A pril 2 9, 2 015 at NERSC B rownbag/Training M ay 1 5, 2 015 Acknowledgements * Larry Pezzaglia ( Former N ERSC, U DI C OE, C HOS) * ScoN B urrow ( NERSC, Jesup/MyDock) * Shreyas C holia ( NERSC, M yDock) * Dani C onner ( Cray, U DI C OE) * Martha Dumler ( Cray, U DI C OE) * Dave H enseler ( Cray, U DI C OE) * Dean R oe ( Cray, U DI C OE) * Kitrick S heets ( Cray, U DI C OE) * Michael

  18. High

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    resolution soft x-ray tomography in the Madison Symmetric Torus P. Franz a) Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Padova, Italy and Istituto Nazionale di Fisica della Materia, Unità di Ricerca di Padova, Italy F. Bonomo, G. Gadani, and L. Marrelli Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Padova, Italy P. Martin and P. Piovesan Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Padova, Italy and Istituto Nazionale di Fisica della Materia, Unità di Ricerca di

  19. The Ho-Ni-Ge system: Isothermal section and new rare-earth nickel...

    Office of Scientific and Technical Information (OSTI)

    ... Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4M1 (Canada) Institute SPIN-CNR and Dipartimento di Chimica e Chimica Industriale, Universit di ...

  20. Quasi real time in vivo dosimetry for VMAT (Journal Article)...

    Office of Scientific and Technical Information (OSTI)

    Authors: Fidanzio, A. ; Azario, L. 1 ; U.O.C di Fisica Sanitaria, Universit Cattolica del Sacro Cuore, Rome 00168 2 ; Istituto Nazionale di Fisica Nucleare 3 ; Porcelli, A. ...

  1. Idling Emissions Reduction Technology with Low Temperature Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion of DI Biodiesel and PFI n-Butanol Idling Emissions Reduction Technology with Low Temperature Combustion of DI Biodiesel and PFI n-Butanol Results from an ...

  2. Jefferson Lab Human Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Links Diversity Home Diversity Council Integrated D&I Management JLab Diversity Policies D&I Quick Links Links on Diversity Coordinating the Council on Women and Girls APS ...

  3. Structural Inventory of Great Basin Geothermal Systems and Definition of Favorable Structural Settings

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Faulds, James E.

    2013-12-31

    - A fault intersection is generally more complex, as it generally contains both multiple fault strands and can include discrete di...

  4. Registration List - WCI-III

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WCI-III Registration List Sandro Barlini, INFN - Laboratori Nazionali di Legnaro Wolfgang Bauer, Michigan State Aldo Bonasera, Laboratorio Nazionale del Sud, INFN Alexander Botvina, Institute for Nuclear Research RAS, Moscow Kyrill Bugaev, Lawrence Berkeley National Laboratory Xavier Campi, LPTMS Abdou Chbihi, GANIL Philippe Chomaz, GANIL Marco Cinausero, INFN Laboratori Nazionali di Legnaro Gianluca Colo', Dipartimento di Fisica Romualdo deSouza, Indiana University/IUCF Massimo Di Toro,

  5. Structural Inventory of Great Basin Geothermal Systems and Definition of Favorable Structural Settings

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Faulds, James E.

    - A fault intersection is generally more complex, as it generally contains both multiple fault strands and can include discrete di...

  6. CoverSheet

    Office of Scientific and Technical Information (OSTI)

    in superconducting () * Types of superconductors *Type I > *Type II < H c 0 () Ginzburg -Landau Theory: Nobel 2003, 1962 Universit di...

  7. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-1-dopa

    DOE Patents [OSTI]

    Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.; Bida, G.T.

    1996-04-23

    A process is revealed for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb{sub 3}; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to {<=}7. 1 fig.

  8. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6-(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6- .sup.18 F!fluoro-1-dopa

    DOE Patents [OSTI]

    Satyamurthy, Nagichettiar; Barrio, Jorge R.; Bishop, Allyson J.; Namavari, Mohammad; Bida, Gerald T.

    1996-01-01

    A process for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb.sub.3 ; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to .ltoreq.7.

  9. Testing decisions of the TSCA Interagency Testing Committee for chemicals on the Canadian Environmental Protection Act Domestic Substances List and Priority Substances List: Di-tert-butylphenol, ethyl benzene, brominated flame retardants, phthalate esters, chloroparaffins, chlorinated benzenes, and anilines

    SciTech Connect (OSTI)

    Walker, J.D.

    1996-12-31

    In 1976, under section 4(e) of the Toxic Substances Control Act (TSCA), the US Congress created the TSCA Interagency Testing Committee (ITC) to decide which chemicals should be recommended to the Administrator of the US Environmental Protection Agency for testing. In 1988, under the Canadian Environmental Protection Act (CEPA), the Government of Canada created the Domestic Substances List and Priority Substances List. This paper briefly describes the ITC, the different ITC testing decisions and a few of the ITC`s 11,150 testing decisions for the 21,413 chemicals on the CEPA Domestic Substances List and some of the 24 testing decisions for the 44 chemicals and chemical groups on the CEPA.

  10. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-L-dopa

    DOE Patents [OSTI]

    Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.

    1995-02-28

    A protected 6-trimethylstannyl dopa derivative has been synthesized for the as a precursor for the preparation of 6-[{sup 18}F]fluoro-L-dopa. The tin derivative readily reacts with electrophilic radiofluorinating agents such as [{sup 18}F]F{sub 2}, [{sup 18}F]OF{sub 2} and [{sup 18}F]AcOF. The [{sup 18}F]fluoro intermediate was easily hydrolyzed with HBr and the product 6-[{sup 18}F]fluoro-L-dopa was isolated after HPLC purification in a maximum radiochemical yield of 23%, ready for human use. 1 fig.

  11. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6-(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[.sup.18 F]fluoro-L-dopa

    DOE Patents [OSTI]

    Satyamurthy, Nagichettiar; Barrio, Jorge R.; Bishop, Allyson J.; Namavari, Mohammad

    1995-01-01

    A protected 6-trimethylstannyl dopa derivative has been synthesized for the as a precursor for the preparation of 6-[.sup.18 F]fluoro-L-dopa. The tin derivative readily reacts with electrophilic radiofluorinating agents such as [.sup.18 F]F.sub.2, [.sup.18 F]OF.sub.2 and [.sup.18 F]AcOF. The [.sup.18 F]fluoro intermediate was easily hydrolyzed with HBr and the product 6-[.sup.18 F]fluoro-L-dopa was isolated after HPLC purification in a maximum radiochemical yield of 23%, ready for human use.

  12. Mesure de la section efficace de production de paires de quarks top dans l'etat final di-electron avec les donnees collectees par l'experience D0 au RunIIa

    SciTech Connect (OSTI)

    Martin Dit Latour, Bertrand; /LPSC, Grenoble

    2008-09-01

    The top quark has been discovered in 1995 by CDF and D0 collaborations in proton-antiproton collisions at the Tevatron. The amount of data recorded by both experiments makes it possible to accurately measure the properties of this very massive quark. This thesis is devoted to the measurement of the top pair production cross-section via the strong interaction, in a final state composed of two electrons, two particle jets and missing transverse energy. It is based on a 1 fb{sup -1} data set collected by the D0 experiment between 2002 and 2006. The reconstruction and identification of electrons and jets is of major importance in this analysis, and have been studied in events where a Z boson is produced together with one or more jets. The Z+jets process is indeed the dominant physics background to top pair production in the dielectron final state. The primary goal of this cross-section measurement is to verify Standard Model predictions. In this document, this result is also interpreted to indirectly extract the top quark mass. Moreover, the cross-section measurement is sensitive to new physics such as the existence of a charged Higgs boson. The selection established for the cross-section analysis has been used to search for a H{sup +} boson lighter than the top quark, where the latter can decay into a W{sup +} or H{sup +} boson and a b quark. The model that has been studied makes the assumption that the H{sup +} boson can only decay into a tau lepton and a neutrino.

  13. A Meaurement of the W+- production cross section in p anti-p collisions at sqroot(s)=1.96 TeV in the DiLepton channel and limits on anomalous WWZ/gamma couplings

    SciTech Connect (OSTI)

    McGivern, Dustin; /University Coll. London

    2005-12-01

    Measurements of the production cross section of W{sup +}W{sup -} pairs in p{bar p} collisions at 1.96 TeV and limits on trilinear gauge boson coupling (TGC) parameters are presented. The data were recorded with the CDF experiment at Tevatron during the 2001 and 2002 data taking periods in which a total integrated luminosity of 184 pb{sup -1} was collected. The data sample was filtered for events with two leptonic w boson decays where the charged leptons can be either electrons or muons. 17 events are observed against an expected background of 5.0{sub -0.8}{sup +2.2} events. The resulting cross-section is found to be {sigma}(p{bar p} {yields} W{sup +}W{sup -}) = 14.5{sub -5.1}{sup +5.8}(stat){sub -3.0}{sup +1.8}(syst) {+-} 0.9(lum) pb and agrees well with the Standard Model expectation. Limits on the TGC parameters {Delta}{kappa} and {lambda} are set under both the equal coupling scheme, that assumes the W boson couples identically to the Z and {gamma}, and the HISZ coupling scheme, that requires the couplings to respect SU(2){sub L} x &(1){sub Y} gauge symmetry. In both cases this is achieved by using a likelihood fit to the lepton-P{sub T} distribution of the 17 candidate events. The resulting limits are found to be: -0.4 < {Delta}{kappa} < +0.6({lambda} = 0); -0.3 < {lambda} < +0.4 ({Delta}{kappa} = 0) for the EQUAL couplings and -0.7 < {Delta}{kappa} < +0.9 ({lambda} = 0); -0.4 < {lambda} < +0.4 ({Delta}{kappa} = 0) for the HISZ couplings.

  14. Mu2e transport solenoid prototype design and manufacturing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fabbricatore, P.; Ambrosio, G.; Cheban, S.; Evbota, D.; Farinon, S.; Lamm, M.; Lopes, M.; Musenich, R.; Wands, R.; Masullo, G.

    2016-02-08

    The Mu2e Transport Solenoid consists of 52 coils arranged in 27 coil modules that form the S-shaped cold mass. Each coil is wound from Al-stabilized NbTi superconductor. The coils are supported by an external structural aluminum shell machined from a forged billet. Most of the coil modules house two coils, with the axis of each coil oriented at an angle of approximately 5° with respect to each other. The coils are indirectly cooled with LHe circulating in tubes welded on the shell. In order to enhance the cooling capacity, pure aluminum sheets connect the inner bore of the coils tomore » the cooling tubes. The coils are placed inside the shell by the means of a shrink-fit procedure. A full-size prototype, with all the features of the full assembly, was successfully manufactured in a collaboration between INFN Genova and Fermilab. In order to ensure an optimal mechanical prestress at the coil-shell interface, the coils are inserted into the shell through a shrink-fitting process. We present the details of the prototype with the design choices as validated by the structural analysis. In conclusion, the fabrication steps are described as well.« less

  15. Polycyclic aromatic hydrocarbons in surface waters of Alessandria District, South Eastern Piedmont (Italy)

    SciTech Connect (OSTI)

    Trova, C.; Cossa, G.; Gandolfo, G.

    1992-10-01

    Polynuclear aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants. Because of the high toxicity of some polycyclic compounds, such as benzopyrenes, the determination of their levels in air, water, soil and aquatic organisms was the object of several papers. Anthropogenic pyrolitic and combustion processes, related to industrial plants, domestic heating, automobile traffic, are the major sources of these compounds; from these sources they enter atmospheric environment where their concentration is reduced by scavenging during precipitation events: rain, snow and fog in urban areas usually show high contents of PAHs. Dry and wet atmospheric polluted depositions effluents transport appreciable amounts of PAHs to aquatic environment, where they are rapidly taken up and accumulated by both fish and shellfish. Alessandria District, in South-Eastern Piedmont (Italy), lies in the middle of Torino-Milano-Genova industrial area: in addition to local sources, a relatively long range transport of polluted air masses may conduct to this region atmospheric contaminants, such as polynuclear compounds, that can enter fluvial environments through meteoric precipitation. The object of this work was to evaluate PAH content in surface waters flowing across the described territory. Samplings were carried on during winter season, when the concentration of these pollutants usually reaches the highest levels. 8 refs., 4 figs., 2 tabs.

  16. Further reduction of efficiency droop effect by adding a lower-index dielectric interlayer in a surface plasmon coupled blue light-emitting diode with surface metal nanoparticles

    SciTech Connect (OSTI)

    Lin, Chun-Han; Su, Chia-Ying; Chen, Chung-Hui; Yao, Yu-Feng; Shih, Pei-Ying; Chen, Horng-Shyang; Hsieh, Chieh; Kiang, Yean-Woei Yang, C. C.; Kuo, Yang

    2014-09-08

    Further reduction of the efficiency droop effect and further enhancements of internal quantum efficiency (IQE) and output intensity of a surface plasmon coupled, blue-emitting light-emitting diode (LED) by inserting a dielectric interlayer (DI) of a lower refractive index between p-GaN and surface Ag nanoparticles are demonstrated. The insertion of a DI leads to a blue shift of the localized surface plasmon (LSP) resonance spectrum and increases the LSP coupling strength at the quantum well emitting wavelength in the blue range. With SiO{sub 2} as the DI, a thinner DI leads to a stronger LSP coupling effect, when compared with the case of a thicker DI. By using GaZnO, which is a dielectric in the optical range and a good conductor under direct-current operation, as the DI, the LSP coupling results in the highest IQE, highest LED output intensity, and weakest droop effect.

  17. Process for separation of the rare earths by solvent extraction

    DOE Patents [OSTI]

    Mason, George W.; Lewey, Sonia

    1977-04-05

    Production rates for solvent extraction separation of the rare earths and yttrium from each other can be improved by the substitution of di(2-ethylhexyl) mono-thiophosphoric acid for di(2-ethylhexyl) phosphoric acid. The di(2-ethylhexyl) mono-thiophosphoric acid does not form an insoluble polymer at approximately 50% saturation as does the former extractant, permitting higher feed solution concentration and thus greater throughput.

  18. An Adaptive Multi-Grid Chemistry (AMC) Model for Efficient Simulation of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI and DI Engine Combustion | Department of Energy An Adaptive Multi-Grid Chemistry (AMC) Model for Efficient Simulation of HCCI and DI Engine Combustion An Adaptive Multi-Grid Chemistry (AMC) Model for Efficient Simulation of HCCI and DI Engine Combustion An adaptive multi-grid technique was used to group thermodynamically similar cells in order to reduce the calling frequency to the chemistry solver. deer08_shi.pdf (189.13 KB) More Documents & Publications Homogeneous Charge

  19. Assessment of Combustion and Turbulence Models for the Simulation of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Processes in a DI Diesel Engine | Department of Energy Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Assessment of Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Various applied combustion and turbulence models were investigated along with chemical kinetic mechanisms simulating a biodiesel-fueled engine deer09_ren.pdf (497.22 KB) More Documents & Publications Low Temperature

  20. Soft-x-ray

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soft-x-ray emission, plasma equilibrium, and fluctuation studies on Madison Symmetric Torus C. Xiao Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin and Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, Canada P. Franz Consorzio RFX-Associazione EURATOM ENEA Sulla Fusione, Italy and Istituto Nazionale di Fisica della Materia, Unita' di Ricerca di Padova, Italy B. E. Chapman and D. Craig Department of Physics, University of

  1. Search for: All records | SciTech Connect

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    ... Thermodynamics of metal-organic frameworks Wu, Di ; Navrotsky, Alexandra, E-mail: ... Thus strong thermodynamic instability does not seem to limit framework formation. ...

  2. Mid-Term Model Development - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    PDF Icon White papers Vincent DiVita, Jacobs Consultancy PDF Icon Terrence Higgins, Hart Downstream Energy Services PDF Icon David Hirshfeld, Mathpro Inc. PDF Icon Frederic...

  3. Research Highlight

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    The Importance of Thermodynamic Profiling in the Boundary Layer Submitter: Turner, D. D., ... Journal Reference: Wulfmeyer V, RM Hardesty, DD Turner, A Behrendt, MP Cadeddu, P Di ...

  4. Search for: All records | SciTech Connect

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    ... Rutherford Appleton Laboratory, Chilton, Didcot, OXON OX11 0QX ; Dipartimento di Fisica E. Amaldi, Universita degli Studi Roma Tre, Via della Vasca Navale 84, 00146 Rome ...

  5. The Use of Benchmarks for High-Reliability Systems (Conference...

    Office of Scientific and Technical Information (OSTI)

    Los Alamos National Laboratory Vanderbilt Univ UFRGS Stellenbosch Univ Univ. de Sevilla Politecnico di Torino Universidad Carlos III de Madrid JPL Northeastern Univ BYU Publication ...

  6. Pharmacologic Profile of the Adnectin BMS-962476, a Small Protein...

    Office of Scientific and Technical Information (OSTI)

    Daniel ; Low, Simon ; Russo, Katie ; DiBella, Rose ; Denhez, Fabienne ; Gao, Mian ; Myers, Joseph ; Duke, Gerald ; Witmer, Mark ; Miao, Bowman ; Ho, Siew P. ; Khan, Javed ; ...

  7. A. M. Szelc, Neutrino 2014, Boston

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    Kreslo Michele Weber Christoph Rudolf von Rohr Thomas Strauss Istituto Nazionale di Fisica Nucleare, Italy Flavio Cavanna Ornella Palamara Virginia Tech Mindy Jen Leonidas...

  8. Silfab Spa | Open Energy Information

    Open Energy Info (EERE)

    Spa Place: Carmignano di Brenta, Italy Zip: 35010 Product: A silicon feedstock manufacturing company to be set up by the founder of Helios Technology. References: Silfab...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... in the interaction of water with a metal-organic framework Wu, Di ; Guo, Xiaofeng ; Sun, Hui ; Navrotsky, Alexandra Here, the enthalpy of water adsorption (h) on the ...

  10. Recent Results on T and CP Violation at BABAR (Conference) |...

    Office of Scientific and Technical Information (OSTI)

    We also report on other CPV measurements recently performed on the B-meson system Authors: Perez Perez, Alejandro 1 + Show Author Affiliations Istituto Nazionale di Fisica ...

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Pacific Decadal Variability and Central Pacific Warming El Nio in a Changing Climat Schneider, Niklas ; Di Lorenzo, E. ; Cobb, K. ; Anderson, B. T. ; Vimont, D. J. Final report ...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Google trace based cloud simulator with virtual machines: GloudSim: Google trace based cloud simulator with virtual machines Di, Sheng ; Cappello, Franck December 2014 , Wiley

  13. Fermilab Today

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IL Violinist Paolo Castellani and guitarist Francesco Di Giandomenico play the colorful music from Argentina, Spain and Puerto Rico. They will present their latest album,...

  14. Implementation and Re nement of a Comprehensive Model for Dense...

    Office of Scientific and Technical Information (OSTI)

    Model for Dense Granular Flows Dense granular ows are ubiquitous in both natural and industrial processes. They manifest three di erent ow regimes, each exhibiting its own...

  15. Search for: All records | SciTech Connect

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    ... (IE) (United States) USDOE Office of Intelligence and Counterintelligence (IN) (United ... one-dimensional optical lattices with artificial gauge fields Chien, Chih-Chun ; Di ...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... In general, we expected to probe typical van der Waals interactions, consisting of a ... ; Dipartimento di Chimica, Biologia e Biotecnologie, Universit degli Studi ...

  17. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Roncaratti, Luiz F. Dipartimento di Chimica, Biologia e Biotecnologie, Universit degli ... In general, we expected to probe typical van der Waals interactions, consisting of a ...

  18. Microsoft Word - 2010Aser_Appx_D

    Office of Legacy Management (LM)

    0 Site Environmental Report May 2011 Doc. No. S07409 Page D-i Contents Abbreviations ................................................................................................................................. iii Measurement Abbreviations .......................................................................................................... iv References

  19. Microsoft Word - Appendix-D

    Office of Legacy Management (LM)

    1 Site Environmental Report May 2012 Doc. No. S08629 Page D-i Contents Abbreviations ................................................................................................................................. iii Measurement Abbreviations .......................................................................................................... iv References

  20. Final Technical report-4-30-13

    Office of Scientific and Technical Information (OSTI)

    ... of Shewanella oneidensis MR-1. FEMS Microbiology Letters, 259:282-287. Dale, J., R. ... Department of Microbiology, Cornell University, Ithaca, NY, 407. DiChristina T. 2007. ...

  1. Recent Results on T and CP Violation at BABAR (Conference) |...

    Office of Scientific and Technical Information (OSTI)

    Authors: Perez Perez, Alejandro 1 + Show Author Affiliations Istituto Nazionale di Fisica Nucleare (INFN), Pisa (Italy). Publication Date: 2015-02-06 OSTI Identifier: 1169461 ...

  2. Hydrocarbon fouling of SCR during Premixed Charge Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Efficient Emissions Control for Multi-Mode Lean DI Engines Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  3. Kickoff Meeting for New Fuel Cell Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Jason Marcinkoski PNNL - Topic 5 Susan Stenkamp Tim Armstrong ANL - Topic 5 Di-Jia Liu Tim Armstrong LANL - Topic 6 Fernando Garzon John Garbak Award Requirements * ...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    "INFN Sezione di Perugia, via Pascoli, 06123 Perugia" Sort by Relevance Sort by Date (newest first) Sort by Date (oldest first) Sort by Relevance Prev Next ...

  5. Vehicle Technologies Office Issues Notice of Intent for Multi...

    Office of Environmental Management (EM)

    of 2007 (EISA) Section 131. 2) Direct Injection Propane Engine - research, develop, and demonstrate a direct injection (DI) propane engine for on-road vehicles approved for highway ...

  6. Tet3 CXXC Domain and Dioxygenase Activity Cooperatively Regulate...

    Office of Scientific and Technical Information (OSTI)

    Authors: Xu, Yufei ; Xu, Chao ; Kato, Akiko ; Tempel, Wolfram ; Abreu, Jose Garcia ; Bian, Chuanbing ; Hu, Yeguang ; Hu, Di ; Zhao, Bin ; Cerovina, Tanja ; Diao, Jianbo ; Wu, ...

  7. Trace Water Catalyzes Lithium Peroxide Electrochemistry - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 19, 2014, Research Highlights Trace Water Catalyzes Lithium Peroxide Electrochemistry Reaction cycle for reduction of di-oxygen by lithium and water to lithium peroxide on ...

  8. Browse by Discipline -- E-print Network Subject Pathways: Energy...

    Office of Scientific and Technical Information (OSTI)

    di Roma "La Sapienza" Zadkov, Victor (Victor Zadkov) - International Laser Center and Faculty of Physics, M.V.Lomonosov Moscow State University Zaggia, Simone (Simone Zaggia) - ...

  9. Integrated Program Management Report (IPMR) Data Item Description...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DI-MGMT-81861 DOE Changes Version -- Integrated Program Management Report Earned Value Management System Interpretation Handbook (EVMSIH) EVMS and Project Analysis Standard ...

  10. Kerself SPA | Open Energy Information

    Open Energy Info (EERE)

    Name: Kerself SPA Place: Prato di Correggio, Italy Zip: 42015 Sector: Solar Product: Italian manufacturer of electric motors and pumps; installs and produces PV and solar passive...

  11. Comprehensive Mapping and Characteristic Regimes of Aerosol Effects...

    Office of Scientific and Technical Information (OSTI)

    Authors: Chang, Di ; Cheng, Yafang ; Reutter, Philipp ; Trentmann, Jrg ; Burrows, Susannah M. ; Spichtinger, Peter ; Nordmann, Stephan ; Andreae, M. O. ; Poschl, U. ; Su, Hang ...

  12. Totem results (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    di Pisa (Italy) Publication Date: 2015-04-10 OSTI Identifier: 22391348 Resource Type: Journal Article Resource Relation: Journal Name: AIP Conference Proceedings; Journal Volume:...

  13. Tunable quantum temperature oscillations in graphene nanostructures...

    Office of Scientific and Technical Information (OSTI)

    nanostructures Authors: Bergfield, Justin P. ; Ratner, Mark A. ; Stafford, Charles A. ; Di Ventra, Massimiliano Publication Date: 2015-03-05 OSTI Identifier: 1181399 Grant...

  14. dcheng | The Ames Laboratory

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    dcheng Ames Laboratory Profile Di Cheng Student Associate Division of Materials Science & Engineering A311 Zaffarano Phone Number: 515-294-5373 Email Address: dcheng@iastate.edu...

  15. Gruppo Ascopiave | Open Energy Information

    Open Energy Info (EERE)

    Gruppo Ascopiave Jump to: navigation, search Name: Gruppo Ascopiave Place: Pieve di Soligo, Italy Zip: 31053 Sector: Renewable Energy Product: Italy-based energy utility. The...

  16. 6He

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    deduced log ft, Gamow-Teller transition strength, level width, di-neutron, neutron halo roles. 1993BO24: 6He(-); measured -delayed deuteron spectrum; deduced branching...

  17. Microwave and Millimeter Wave Forward Modeling Results from the...

    Office of Scientific and Technical Information (OSTI)

    9 to April 9, 2004. The goals of the experiment were: to study the microwave and ... ColoradoNOAA-Environmental Technology Laboratory, Boulder, Colorado (US); Universiti di ...

  18. Integral Relations for Three-Body Continuum States with the Adiabatic...

    Office of Scientific and Technical Information (OSTI)

    de la Materia, CSIC, Serrano 123, E-28006 Madrid (Spain) Istituto Nazionale di Fisica Nucleare, Largo Pontecorvo 3, 56100 Pisa (Italy) Publication Date: 2009-08-28 OSTI ...

  19. Variational description of continuum states in terms of integral...

    Office of Scientific and Technical Information (OSTI)

    CSIC, Serrano 123, E-28006 Madrid 3 + Show Author Affiliations Istituto Nazionale di Fisica Nucleare, Largo Pontecorvo 3, I-56100 Pisa (Italy) (United Kingdom) (Spain) ...

  20. General integral relations for the description of scattering...

    Office of Scientific and Technical Information (OSTI)

    University College London, Gower Street, London WC1E 6BT 2 ; Istituto Nazionale di Fisica Nucleare, Largo Pontecorvo 3, 56100 Pisa 3 + Show Author Affiliations Instituto de ...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Electromagnetic structure of few-nucleon ground states Marcucci, Laura E. ; Istituto Nazionale di Fisica Nucleare ; Gross, Franz L. ; Thomas Jefferson National Accelerator Facility ...

  2. Helios Technology Srl | Open Energy Information

    Open Energy Info (EERE)

    Solar Product: Carmignano di Brenta-based manufacturer of solar cells, modules and photovoltaic systems. References: Helios Technology Srl1 This article is a stub. You can help...

  3. STUDENTS WHO RECEIVED GRADUATE DEGREES FROM THESIS WORK CONDUCTED...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 - March 31, 2003 Name Year Thesis Title Advisor First Position Present Position Tiegang Di 2002 Charm Meson Interactions with Hadrons Che-Ming Ko Graduate Research Assistant...

  4. Ground-based Microwave Cloud Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Courtesy of Bernhard Mayer Cloud structure important to radiation - Cumulus (Benner & Evans 2001, Pincus et al. 2005), deep convection (DiGiuseppe & Tompkins 2003) - Horizontal...

  5. The 2004 North Slope of Alaska Arctic Winter Radiometric Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CETEMPS Universita' dell'Aquila L'Aquila, Italy V. Mattioli Dipartimento di Ingegneria Elettronica e dell'Informazione Perugia, Italy B. L. Weber and S. Dowlatshahi Science ...

  6. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "New data will soon allow us to distinguish between our explanation for the accelerated expansion of the universe and the dark energy solution." INFN (Istituto Nazionale di...

  7. Real-Time US-CT/MRI Image Fusion for Guidance of Thermal Ablation of Liver Tumors Undetectable with US: Results in 295 Cases

    SciTech Connect (OSTI)

    Mauri, Giovanni Cova, Luca; Beni, Stefano De; Ierace, Tiziana Tondolo, Tania Cerri, Anna; Goldberg, S. Nahum; Solbiati, Luigi

    2015-02-15

    PurposeThis study was designed to assess feasibility of US-CT/MRI fusion-guided ablation in liver tumors undetectable with US.MethodsFrom 2002 to 2012, 295 tumors (162 HCCs and 133 metastases; mean diameter 1.3 ± 0.6 cm, range 0.5–2.5 cm) detectable on contrast-enhanced CT/MRI, but completely undetectable with unenhanced US and either totally undetectable or incompletely conspicuous with contrast-enhanced US (CEUS), were treated in 215 sessions using either internally cooled radiofrequency or microwave with standard ablation protocols, guided by an image fusion system (Virtual Navigation System, Esaote S.p.A., Genova, Italy) that combines US with CT/ MRI images. Correct targeting and successful ablation of tumor were verified after 24 hours with CT or MRI.ResultsA total of 282 of 295 (95.6 %) tumors were correctly targeted with successful ablation achieved in 266 of 295 (90.2 %). Sixteen of 295 (5.4 %) tumors were correctly targeted, but unsuccessfully ablated, and 13 of 295 (4.4 %) tumors were unsuccessfully ablated due to inaccurate targeting. There were no perioperative deaths. Major complications were observed in 2 of the 215 treatments sessions (0.9 %).ConclusionsReal-time virtual navigation system with US-CT/MRI fusion imaging is precise for targeting and achieving successful ablation of target tumors undetectable with US alone. Therefore, a larger population could benefit from ultrasound guided ablation procedures.

  8. Ultraviolet light absorbers having two different chromophors in the same molecule

    DOE Patents [OSTI]

    Vogl, Otto; Li, Shanjun

    1988-05-17

    Ultraviolet light absorbing compounds having two different chromophors in the same molecule, particularly the benzotriazole chromophor and either the dihydroxybenzophenone or dihydroxyacetophenone chromophor; specifically, the two compounds 3,5-[di(2H-benzotriazole-2-yl)]-2,4-dihydroxyacetophenone and 3,5-[di(2H-benzotriazole-2-yl)]2,4-dihydroxybenzophenone.

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Similarly, di-n-propyl- or di-n-butylether gives Cp'2Ce(O-n-Pr) and propane or Cp'2Ce(O-n-Bu) and butane, respectively. Using Cp'2CeD, the propane and butane contain deuterium ...

  10. Microsoft Word - lblsubethers.doc

    Office of Scientific and Technical Information (OSTI)

    Similarly, di-n-propyl- or di-n-butylether gives Cp' 2 Ce(O-n- Pr) and propane or Cp' 2 Ce(O-n-Bu) and butane, respectively. Using Cp' 2 CeD, the propane and butane contain ...

  11. Splitting a C-O bond in dialkylethers withbis(1,2,4-tri-t-butylcyclop...

    Office of Scientific and Technical Information (OSTI)

    Similarly, di-n-propyl- or di-n-butylether gives Cp'2Ce(O-n-Pr) and propane or Cp'2Ce(O-n-Bu) and butane, respectively. Using Cp'2CeD, the propane and butane contain deuterium ...

  12. Preparation of carbon nanoparticles and carbon nitride from high nitrogen compound

    DOE Patents [OSTI]

    Huynh, My Hang V.; Hiskey, Michael A.

    2009-09-01

    The high-nitrogen compound 3,6-di(azido)-1,2,4,5-tetrazine (DiAT) was synthesized by a relatively simple method and used as a precursor for the preparation of carbon nanospheres and nanopolygons, and nitrogen-rich carbon nitrides.

  13. Composition and method for encapsulating photovoltaic devices

    DOE Patents [OSTI]

    Pern, Fu-Jann

    2000-01-01

    A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.

  14. Top quark mass measurement in the dilepton channel during the D0 experiment at the Tevatron. Mesure de la masse du quark top dans les canaux di-leptoniques auprès de l’expérience DØ au Tevatron

    SciTech Connect (OSTI)

    Croc, Aurelien

    2011-01-01

    The top quark is the heaviest standard model quark. Discovered in 1995 by the two Tevatron experiments it has atypical properties. In particular its time life is so short that it decays before hadronizing, so the top quark mass could be measured with a high precision. Data collected by the DØ experiment between 2002 and 2009, which represent an integrated luminosity of 5.4 fb⁻¹, are used to measure the top quark mass by using the matrix element method in the three dilepton channels: dielectron, electron--muon and dimuon. The measured mass, 174.0 ± 1.8 (stat.) ± 2.4 (syst.) GeV, is in a good agreement with other measurements and limited by the systematic uncertainties for the first time in these channels. In this thesis different approaches have been studied to improve the accuracy of this measurement: the use of b-quark jet identification in order to optimize the selection of top--anti-top events and a better determination of the main systematic uncertainties. A special attention has been paid to the Monte-Carlo simulation of muons in DØ: the improved smearing procedure for the simulated muons, discussed in this thesis, will be used to increase the accuracy of the top properties measurements as well as the precision of many other DØ measurements.

  15. DEVELOPMENT OF A NATURAL GAS SYSTEMS ANALYSIS MODEL (GSAM) VOLUME I - SUMMARY REPORT VOLUME II - USER'S GUIDE VOLUME IIIA - RP PROGRAMMER'S GUIDE VOLUME IIIB - SRPM PROGRAMMER'S GUIDE VOLUME IIIC - E&P PROGRAMMER'S GUIDE VOLUME IIID - D&I PROGRAMMER'S GUIDE

    SciTech Connect (OSTI)

    Unknown

    2001-02-01

    This report summarizes work completed on DOE Contract DE-AC21-92MC28138, Development of a Natural Gas Systems Analysis Model (GSAM). The products developed under this project directly support the National Energy Technology Laboratory (NETL) in carrying out its natural gas R&D mission. The objective of this research effort has been to create a comprehensive, non-proprietary, microcomputer model of the North American natural gas market. GSAM has been developed to explicitly evaluate components of the natural gas system, including the entire in-place gas resource base, exploration and development technologies, extraction technology and performance parameters, transportation and storage factors, and end-use demand issues. The system has been fully tested and calibrated and has been used for multiple natural gas metrics analyses at NETL in which metric associated with NETL natural gas upstream R&D technologies and strategies under the direction of NETL has been evaluated. NETL's Natural Gas Strategic Plan requires that R&D activities be evaluated for their ability to provide adequate supplies of reasonably priced natural gas. GSAM provides the capability to assess potential and on-going R&D projects using a full fuel cycle, cost-benefit approach. This method yields realistic, market-based assessments of benefits and costs of alternative or related technology advances. GSAM is capable of estimating both technical and commercial successes, quantifying the potential benefits to the market, as well as to other related research. GSAM, therefore, represents an integration of research activities and a method for planning and prioritizing efforts to maximize benefits and minimize costs. Without an analytical tool like GSAM, NETL natural gas upstream R&D activities cannot be appropriately ranked or focused on the most important aspects of natural gas extraction efforts or utilization considerations.

  16. Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds

    DOE Patents [OSTI]

    Peterman,Dean R.; Meikrantz,David H.; Law,Jack D.; Riddle,Catherine L.; Todd,Terry A.; Greenhalgh,Mitchell R.; Tillotson,Richard D.; Bartsch,Richard A.; Moyer,Bruce A.; Delmau,Laetitia H.; Bonnesen,Peter V.

    2012-04-17

    A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4',4',(5')-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

  17. Characterization of glycidol-hemoglobin adducts as biomarkers of exposure and in vivo dose

    SciTech Connect (OSTI)

    Honda, Hiroshi; Törnqvist, Margareta; Nishiyama, Naohiro; Kasamatsu, Toshio

    2014-03-15

    Hemoglobin adducts have been used as biomarkers of exposure to reactive chemicals. Glycidol, an animal carcinogen, has been reported to form N-(2,3-dihydroxy-propyl)valine adducts to hemoglobin (diHOPrVal). To support the use of these adducts as markers of glycidol exposure, we investigated the kinetics of diHOPrVal formation and its elimination in vitro and in vivo. Five groups of rats were orally administered a single dose of glycidol ranging from 0 to 75 mg/kg bw, and diHOPrVal levels were measured 24 h after administration. A dose-dependent increase in diHOPrVal levels was observed with high linearity (R{sup 2} = 0.943). Blood sampling at different time points (1, 10, 20, or 40 days) from four groups administered glycidol at 12 mg/kg bw suggested a linear decrease in diHOPrVal levels compatible with the normal turnover of rat erythrocytes (life span, 61 days), with the calculated first-order elimination rate constant (k{sub el}) indicating that the diHOPrVal adduct was chemically stable. Then, we measured the second-order rate constant (k{sub val}) for the reaction of glycidol with N-terminal valine in rat and human hemoglobin in in vitro experiments with whole blood. The k{sub val} was 6.7 ± 1.1 and 5.6 ± 1.3 (pmol/g globin per μMh) in rat and human blood, respectively, indicating no species differences. In vivo doses estimated from k{sub val} and diHOPrVal levels were in agreement with the area under the (concentration–time) curve values determined in our earlier toxicokinetic study in rats. Our results indicate that diHOPrVal is a useful biomarker for quantification of glycidol exposure and for risk assessment. - Highlight: • Glycidol-hemoglobin adduct (diHOPrVal) was characterized for exposure evaluation. • We studied the kinetics of diHOPrVal formation and elimination in vitro and in vivo. • Dose dependent formation and chemical stability were confirmed in the rat study. • In vivo dose (AUC) of glycidol could be estimated from diHOPrVal levels

  18. Microsoft Word - FINAL CR 2013-01 Soil Disturbance Review Plan...

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    ... the geoprobe unit in sampling of the Solar Ponds Plume Treatment System media and ... Scott Surovchak, U.S. Department of Energy (DOE); Rick DiSalvo, S.M. Stoller ...

  19. 2009 > Publications > Research > The Energy Materials Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sols Morgan Stefik, Surbhi Mahajan, Hiroaki Sai, Thomas H. Epps III, Frank S. Bates, Sol M. Gruner, Francis J. DiSalvo and Ulrich Wiesner Chemistry of Materials Vol.21, p....

  20. CX-013593: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Use of DI Water Filtration System CX(s) Applied: B3.6Date: 03/23/2015Location(s): South CarolinaOffices(s): Savannah River Operations Office

  1. Microsoft PowerPoint - NEGTN02-#212413-v3-SMR_BRIEF_FOR_FULL...

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    Modular Licensing Technical Support Program Update Program Update for Nuclear Energy Advisory Committee Nuclear Energy Advisory Committee Rebecca Smith-Kevern Di t f Li ht W t R t ...

  2. Tau and Charm Meson Decays at BaBar (Conference) | SciTech Connect

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    Resource Relation: Journal Name: Nuovo Cim.B123:827-829,2008; Conference: Prepared for IFAE 2008 (Incontri di Fisica delle Alte Energie 2008), Bologna, Italy, 26-28 Mar 2008 ...

  3. A Comparison of Combustion and Emissions of Diesel Fuels and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated ...

  4. BPA-2012-01869-FOIA Request

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    OFF WE THIS DATE: oj DUE DATE: Ib)q Ji;i LOG 2O- Di1P Description of Request: Hello, I would like to know how many GS9 or above archaeologists (0193) work for you agency....

  5. Microsoft PowerPoint - C-Mod_BPM_2010_21.ppt [Compatibility Mode...

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    di Torino U. Tokyo U T U. Texas IFS U. Toronto Coordination: FFCC, USBPO, TTF, ITPA, IEA C-Mod International Collaborations* Selected Highlights (FY0910) and Plans (FY10-12) *...

  6. Cours-II/Clavin2015.key

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    2-2. Continuity 2-3. Fick's law. Di usion equation 2-4. Conservation of momentum 2-5. Conservation of total energy Thermal equation Inviscid flows in reactive gases...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... The creation and evolution of mono-vacancy, di-vacancy, Stone-Wales (SW) and grain boundaries (GBs) under irradiation in graphene are investigated using density functional theory ...

  8. safety newsletter may.AI

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    Contact: Gyuhae Park gpark@lanl.gov Francesco Lanza di Scalea flanza@ucsd.edu Actuator Sensor Sensor Sensor Multi-Scale Sensing Multi-Scale Sensing Multi-Scale Sensing Active...

  9. BPA-2016-00103-FOIA Response

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    IN FORMATION ACT PROGRAM In reply refer to: FOIA BPA-2016-00103-F Andrew Zorn DiGioia Gray & Associates 570 Beatty Road Monroeville, P A 15229 Mr. Zorn: We have received your...

  10. Final Report-4-30-13

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    ... to respire all anaerobic electron acceptors (under review). DiChristina, T., C. Moore and C. Haller. 2002. Dissimilatory Fe(III) and Mn(IV) reduction by Shewanella putrefaciens ...

  11. The Honorable,,Richard,M. ,121 N. LaSalle St,reet

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    Alexander W illiams 301-427-1719 of my ,staff. ,, ', .&mes'W. Wagoner 11: I, I, Di.r,ector ..Off-SiteSavannah River 'Program Division, Office of Eastern Area ,Programs , " Office ...

  12. Microsoft Word - TWG Mtg 11-14-11- FINAL

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    ... between DOE and the TWG. Frank Di Sanza noted that if there is an interest, the TWG Contact List will be provided in order for members to share comments among each other. The ...

  13. EC Publications

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    O shore wind power production is an attractive clean energy option, but the di&14;culty of access can lead to expensive and rare opportunities for maintenance. As part of the ...

  14. 2012 > Publications > Research > The Energy Materials Center...

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    ... 10.1021nl301642g Interconversion of Inverse Opals of Electrically Conducting Doped Titanium Oxides and Nitrides CV Subban, IC Smith, FJ DiSalvo Small, 8(18), pp 2824-2832, 2012 ...

  15. Comparing English, Mandarin, and Russian Hydrographic and Terrain Categories

    SciTech Connect (OSTI)

    Feng, Chen-Chieh; Sorokine, Alexandre

    2013-01-01

    The paper compares hydrographic and terrain categories in the geospatial data standards of the US, Taiwan, and Russian Federation where the dominant languages used are from di erent language families. It aims to identify structural and semantic di erences between similar categories across three geospatial data standards. By formalizing the data standard structures and identifying the properties that di erentiate sibling categories in each geospatial data standard using well-known formal relations and quality universals, we develop a common basis on which hydrographic and terrain categories in the three data standards can be compared. The result suggests that all three data standards structure categories with a mixture of relations with di erent meaning even though most of them are well-known relations in top-level ontologies. Similar categories can be found across all three standards but exact match between similar categories are rare.

  16. TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID...

    Open Energy Info (EERE)

    the Devil's Kitchen fumarole area and from Coso production wells. Authors Lutz, S.J.; Moore, J.N.; Adams, M.C.; Norman and D.I. Published PROCEEDINGS, Twenty-fourth Workshop on...

  17. Conceptual Model At Coso Geothermal Area (2006) | Open Energy...

    Open Energy Info (EERE)

    created using cross-sections and fence diagrams. References Dilley, L.M.; Norman, D.I.; Moore, J.; McCullouch, J. (1 January 2006) FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL...

  18. Fluid Inclusion Analysis At Coso Geothermal Area (1999) | Open...

    Open Energy Info (EERE)

    Devil's Kitchen fumarole area and from Coso production wells. References Lutz, S.J.; Moore, J.N.; Adams, M.C.; Norman, D.I. (1 January 1999) TRACING FLUID SOURCES IN THE COSO...

  19. Fluid Inclusion Analysis At Coso Geothermal Area (2005-2006)...

    Open Energy Info (EERE)

    Interpretation of New Wells in the Coso Geothermal Field Dilley, L. M.; Norman, D.I.; Moore, J.; McCulloch, J. (1 January 2006) Fluid Stratigraphy and Permeable Zones of the Coso...

  20. Chinmayee Subban > Postdoc - Universit de Picardie Jules Verne...

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    a graduate student with the DiSalvo Group, she earned her PhD in August 2012. She is now a postdoc with Professor Jean-Marie Tarascon at the Universit de Picardie Jules Verne...

  1. Cours-I/Clavin2015.key

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    velocity flame thickness Overall reaction rate. Arrhenius law I 3) 8 P.Clavin I Maxwell 1867 Einstein 1905 Back to the kinetic theory of gases Molecular di usion Random Walk <...

  2. Process for the production of 5'-deoxy-5-(/sup 18/F)fluorouridine

    DOE Patents [OSTI]

    Shiue, C.Y.; Wolf, A.P.; Friedkin, M.

    1983-08-10

    Process for the production of 5'-deoxy-5-fluorouridine and the corresponding /sup 18/F compound by the reaction of fluorine or acetyl hypofluorite with 2', 3'-di-O-acetyl-5'-deoxyuridine followed by hydrolysis.

  3. DOE-LM/XXXX-2006

    Office of Legacy Management (LM)

    3 Site Environmental Report May 2014 Doc. No. S11109 Page D-i Contents Abbreviations ............................................................................................................................. D-iv Measurement Abbreviations ...................................................................................................... D-iv D.1.0 Ecological Restoration Monitoring ................................................................................. D-1 D.2.0 Prairie Functional

  4. DOE-LM/XXXX-2006

    Office of Legacy Management (LM)

    4 Site Environmental Report May 2015 Doc. No. S12455 Page D-i Contents Abbreviations ............................................................................................................................. D-iv Measurement Abbreviations ...................................................................................................... D-iv D.1.0 Ecological Restoration Monitoring ................................................................................. D-1 D.2.0 Forest Functional

  5. Raymond Burns > Product Research Technologist - Exxon Mobile > Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alumni > The Energy Materials Center at Cornell Raymond Burns Product Research Technologist - Exxon Mobile raymond.burns@gmail.com Formerly a member of the DiSalvo Group, Ray earned his PhD in August 2013

  6. Membrane-Associated Methane Monooygenase from Type X and Type I Methanotrophs

    SciTech Connect (OSTI)

    Antholine, William E.; DiSpirito, Alan A.

    2009-11-30

    Membrane-Associated Methane Monooxygenases from Type X and Type I Methanotrophs A.A. DiSirito and W.E. Antholine Project Number: DE-FG02-00ER15446 Final project report.

  7. 26094_ESNet_BER_Cover_052213

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... (e.g., self-organizing maps of di-, tri-, ... The largest change to the Pan-omics pipeline would be the ... Science Program CDIAC Carbon Dioxide Information Analysis ...

  8. Microsoft Word - Appendix-D.docx

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    blank U.S. Department of Energy Fernald Preserve 2012 Site Environmental Report May 2013 Doc. No. S09665 Page D-i Contents Abbreviations ............................................................................................................................ D-iii Measurement Abbreviations ..................................................................................................... D-iv References

  9. ARM - Publications: Science Team Meeting Documents

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    Establishing the True Nature of Cloud Overlap with ARM Data Di Girolamo, L.(a), Astin, I.(b), and McFarquhar, G.M.(a), University of Illinois at Urbana-Champaign (a), University of...

  10. Mah Presentation

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    Surrow (Temple University) using NLO perturbative QCD calculations showed that di- jets located at forward rapidity (2.8 < < 3.7) with transverse momenta of 5 and 8 GeV...

  11. DOE DIRECTIVES, DELEGATIONS, AND OTHER REQUIREMENTS PORTAL What...

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    Those assotiated with a directive(s) can 111.50 be found in d uded wi t h the di rective In the "Retated Content" section. Prin t this "" RSQ""c Oi rect i Y T"'" Referces ...

  12. ORNL/RASA-85/

    Office of Legacy Management (LM)

    ... R"..di"l A"tioo so-", aad ccrtificetior Actlvitics (xAtcA) prorran, o.-E-.-n"Eili Laboratoty, OIILITI-8600 (Septcrbcr 19&l). T. E. lfyrlcl, B. rL Bcrvca, ead F. F. Eayvood, ...

  13. Microsoft PowerPoint - WhitneyRehab12

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    T L B hi Terry L. Bachim Chief, Maintenance Section Fort Worth District O ti Di i i Operations Division 13June 2012 US Army Corps of Engineers BUILDING STRONG FORT WORTH...

  14. Microsoft Word - 2005 Smooth Brome 032206 FINAL.doc

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    n i c a D ra w So uth Int erc ep tor Di tch W o m a n C re ek Smooth Brome Treatment Location Smooth Brome Weed Control Locations Figure 2 DATA SOURCE BASE FEATURES: Buildings,...

  15. Fluid Inclusion Analysis At Coso Geothermal Area (2004-2005)...

    Open Energy Info (EERE)

    and much fine scale detail when the logs are analyzed in detail. References Dilley, L. M.; Norman, D.I.; Berard, B. (1 January 2004) FLUID INCLUSION STRATIGRAPHY: NEW METHOD...

  16. Internship for Italian Students at Fermilab

    Broader source: Energy.gov [DOE]

    Each year the Italian Istituto Nazionale di Fisica Nucleare (INFN), the U.S. Department of Energy, and the Italian Scientists And Scholars in North America Foundation (ISSNAF) offer a number of...

  17. Measurement of the production cross section for Z gamma to nu...

    Office of Scientific and Technical Information (OSTI)

    ... Di Marco41, M. Dobson, M. Dordevic, B. Dorney, T. du Pree, D. Duggan, M. Diinser, N. Dupont, A. Elliott-Peisert, G. Franzoni, J. Fulcher, W. Funk, D. Gigi, K. Gill, D. Giordano, ...

  18. Search for supersymmetry in electroweak production with photons...

    Office of Scientific and Technical Information (OSTI)

    ... Di Marco43, M. Dobson, M. Dordevic, B. Dorney, T. du Pree, D. Duggan, M. Diinser, N. Dupont, A. Elliott-Peisert, G. Franzoni, J. Fulcher, W. Funk, D. Gigi, K. Gill, D. Giordano, ...

  19. Search for heavy resonances decaying to two Higgs bosons in final...

    Office of Scientific and Technical Information (OSTI)

    ... Di Marco42, M. Dobson, M. Dordevic, B. Dorney, T. du Pree, D. Duggan, M. Diinser, N. Dupont, A. Elliott-Peisert, G. Franzoni, J. Fulcher, W. Funk, D. Gigi, K. Gill, D. Giordano, ...

  20. Investigating the Validity of the Knudsen Prescription for Diffusiviti...

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    values. The ratio i(0)Di,Kn is found to correlate with the isosteric heat of adsorption, which, in turn, is a reflection of the binding energy for adsorption on the pore...

  1. Nuvosun Inc | Open Energy Information

    Open Energy Info (EERE)

    Nuvosun Inc Place: Palo Alto, California Zip: 94303-4601 Product: California-based copper indium gallium (di)selenide (CIGS) thin film PV maker. References: Nuvosun Inc1 This...

  2. ARM - Publications: Science Team Meeting Documents

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    and the amount of condensed water are di- agnosed from the distribution and the cell-mean thermo- dynamic properties. Sources and sinks of the distribution moments are tied...

  3. X Group Spa | Open Energy Information

    Open Energy Info (EERE)

    Name: X-Group Spa Place: Vanzo di San Pietro Viminario, Italy Zip: 35020 Product: An Italian PV cell and module producer. References: X-Group Spa1 This article is a stub. You...

  4. Fluid Stratigraphy and Permeable Zones of the Coso Geothermal...

    Open Energy Info (EERE)

    zones can be targeted in the future Authors Dilley, L. M.; Norman, D.I.; Moore, J.; McCulloch and J. Published Geothermal Resource Council Transactions 2006, 112006 DOI...

  5. FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL RESERVOIR | Open Energy...

    Open Energy Info (EERE)

    cross-sections developed using this method. Authors Dilley, L.M.; Norman, D.I.; Moore, J.; McCullouch and J. Published PROCEEDINGS, Thirty-First Workshop on Geothermal Reservoir...

  6. 8He

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    following -decay; deduced log ft, Gamow-Teller transition strength, level width, di-neutron, neutron halo roles. 1991LUZZ: 8He; measured T12. 1993BO24: 8He(-); measured...

  7. Town of Selma, North Carolina (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    Place: North Carolina Phone Number: (919) 965-9841 Website: www.selma-nc.comelectrical-di Outage Hotline: (919) 965-9841 References: EIA Form EIA-861 Final Data File for 2010 -...

  8. 9Li

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    deduced log ft, Gamow-Teller transition strength, level width, di-neutron, neutron halo roles. 1991LUZZ: 9Li(-); measured T12. 1992LI24: 9Li(-); measured NMR...

  9. Browse by Discipline -- E-print Network Subject Pathways: Environmenta...

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    Q R S T U V W X Y Z Pola, Giordano (Giordano Pola) - Dipartimento di Ingegneria Elettrica, Universit dell'Aquila Go back to Individual Researchers Collections: A B C D E F G H I ...

  10. 3D Tracking at the Nanoscale | The Ames Laboratory

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    Super-Localization and Tracking of Single Gold Nanoparticles in Cells Author(s): Y. Gu, X. Di, W. Sun, G. Wang and N. Fang Article Link: http:dx.doi.org10.1021ac300249d...

  11. An alkyne metathesis-based route toortho-dehydrobenzannulenes

    SciTech Connect (OSTI)

    Miljanic, Ognjen S.; Vollhardt, Peter C.; Whitener, Glenn D.

    2002-11-07

    An application of alkyne metathesis to 1,2-di(prop-1-ynyl)arenes, producing dehydrobenzannulenes, is described. An efficient method for selective Sonogashira couplings of bromoiodoarenes under conditions of microwave irradiation is also reported.

  12. Spin wave eigenmodes in single and coupled sub-150 nm rectangular...

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    ...anni.carlotti@fisica.unipg.it ; Madami, M. 1 ; Tacchi, S. 2 ; Gubbiotti, G. ; Dey, H. ; Csaba, G. ; Porod, W. 3 + Show Author Affiliations Dipartimento di Fisica e Geologia, ...

  13. Economic Analysis Case Studies of Battery Energy Storage with...

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    Economic Analysis Case Studies of Battery Energy Storage with SAM Nicholas DiOrio, Aron Dobos, ... to use the storage system to increase the system value and mitigate demand charges. ...

  14. ANALYSIS OF A STATE CHANGING SUPERSOFT X-RAY SOURCE IN M31 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Future observations of this and other state changers can provide the information needed to determine the nature(s) of these intriguing new sources. Authors: Patel, B. 1 ; Di ...

  15. SITE NAME: CITY:

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    ... F. CRLLISHRN F. TRENT NORTON CONTRACT AT140-II-2174 SECURITY INFORMTION PROPERT DI3POSZTION OF CLASSIFIED DOCUIIENTB MD DECLRSSIFICIIlION OF DOCUKENTS ON PROCUREKENT OF Hk3KEgIUl ...

  16. Cours-IX/Clavin2015.key

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    (Nonlinear stochastic equation) 4 P.Clavin IX IX-2) Turbulent diffusion Einstein 1905 G.I Taylor 1922 Taylor's di usion coecient x 2 (t) 2 t 0 dt t 0 d v(t )v(t ) integration...

  17. Fast transit portal dosimetry using density-scaled layer modeling...

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    ... Authors: Jung, Jae Won ; Kim, Jong Oh ; Yeo, Inhwan Jason ; Cho, Young-Bin ; Kim, Sun Mo ; DiBiase, Steven 1 ; Department of Radiation Oncology, University of Pittsburgh Cancer ...

  18. Search for: All records | SciTech Connect

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    ... Giroletti, M. INAF Istituto di Radioastronomia, via Gobetti 101, I-40129 Bologna (Italy) (4) Chavushyan, V. (3) Fragos, T. (3) Gasparrini, D. (3) Kim, D.-W. (3) Landoni, M. (3) ...

  19. Search for: All records | SciTech Connect

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    Taillefert, Martial (4) Beazley, Melanie J. (1) Belli, Keaton M. (1) DiChristina, Thomas J. (1) Martinez, Robert J. (1) Sobecky, Patricia A (1) Sobecky, Patricia A. (1) Van ...

  20. Microsoft Word - RL14788-Section_D.doc

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    D Contract No. DE-AC06-08RL14788 D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING TABLE OF CONTENTS D.1 PACKAGING......

  1. Microsoft Word - cimini_d.doc

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    di Metodologie per l'Analisi Ambientale - National Research Council Tito Scalo (PZ), Italy E.R. Westwater, A.J. Gasiewski, M. Klein, and V. Leuski National Oceanic and ...

  2. Nonlinear

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    R. Gatto Universit di Roma "Tor Vergata", 00133 Rome, Italy P. W. Terry and D. A. Baver University of Wisconsin-Madison, Madison, Wisconsin 53706 Received 25 July 2005; ...

  3. Women @ Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    part to addressing them." Pascale Di Nicola works at the National Ignition Facility (NIF) and is in charge of a working group for pointing performance and is a core member of...

  4. From: Sent: To: Subject: FOIA-Central@hq.doe.gov Wednesday,

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    hi.Joan From: Sent: To: Subject: FOIA-Central@hq.doe.gov Wednesday, January 13,20105:09 PM FOIA-Central DOE Headquarters FOIA Request JAN. 1. 4 ':- , ( ...,i(JI DI Name: Mel...

  5. 2014 Publications Resulting from the Use of NERSC Resources

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    ... Applications VII -- Methods and Theoretical Apsects, ... Di Vittorio, A.V. and N.L.Miller (2014), Reducing the impact ... analogues, SO2, OS2, and S3: Correlation ...

  6. Visiting Speaker Program - July 16, 2008 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    16, 2008 Visiting Speaker Program - July 16, 2008 The Visiting Speaker Program event with presentations on the effectiveness of collaboration within the federal government and current and future challenges facing agencies and the entire country. Assistant Secretary James Rispoli introduced Mr. Frank DiGiammarino and Mr. Jonathan Breul and made opening remarks at the program. Mr. DiGiammarino, NAPA Vice President of Strategic Initiatives, presented the topic of collaboration and its impacts on

  7. Ultraviolet light absorbers having two different chromophors in the same molecule

    DOE Patents [OSTI]

    Vogl, O.; Li, S.

    1983-10-06

    This invention relates to novel ultraviolet light absorbers having two chromophors in the same molecule, and more particularly to benzotriazole substituted dihydroxybenzophenones and acetophenones. More particularly, this invention relates to 3,5-(di(2H-benzotriazole-2-yl))-2,4-dihydroxybenzophenone and 3,5-(di(2H-benzotriazole-2-yl))-2,4-dihydroxyacetophenone which are particularly useful as an ultraviolet light absorbers.

  8. Insensitive explosive composition and method of fracturing rock using an extrudable form of the composition

    DOE Patents [OSTI]

    Davis, Lloyd L

    2013-11-05

    Insensitive explosive compositions were prepared by reacting di-isocyanate and/or poly-isocyanate monomers with an explosive diamine monomer. Prior to a final cure, the compositions are extrudable. The di-isocyanate monomers tend to produce tough, rubbery materials while polyfunctional monomers (i.e. having more than two isocyanate groups) tend to form rigid products. The extrudable form of the composition may be used in a variety of applications including rock fracturing.

  9. High-resolution Soft-RIXS: Scientific Goals and Technical Challenges |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource High-resolution Soft-RIXS: Scientific Goals and Technical Challenges Tuesday, November 22, 2011 - 3:30pm SSRL Conference Room 137-322 Giacomo Ghiringhelli, CNR/SPIN and Dipartimento di Fisica, Politecnico di Milano, Italy Visiting scholar at SIMES-Department of physics, Stanford University The interest in resonant inelastic soft x-ray scattering has been recently boosted mainly by results on high Tc superconductors and other cuprates, where orbital

  10. Microsoft PowerPoint - Columbia_River_Corridor_Rev_2_v2.ppt [Compatibility Mode]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Columbia River Corridor The Columbia River Corridor projects selected for Recovery A t f di i l d d li hi f iliti di ti Act funding include demolishing facilities, remediating waste sites, and containing and treating contamination in groundwater. The projects support completing cleanup along the Columbia River and shrinking the active area of cleanup to the center of the Hanford Site (the Central Plateau) by 2015 1 of the Hanford Site (the Central Plateau) by 2015. May 2009 Shrinking the

  11. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Radiosonde and Precipitable Water Vapor Data from the 2004 North Slope of Alaska Arctic Winter Radiometeric Experiment V. Mattioli Dipartimento di Ingegneria Elettronica e dell'Informazione Universitά di Perugia Perugia, Italy E.R. Westwater and D. Cimini Cooperative Institute for Research in Environmental Sciences University of Colorado NOAA-Environmental Technology Laboratory Boulder, Colorado J.S. Liljegren and B.M. Lesht Department of Energy/Argonne National Laboratory Argonne,

  12. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microwave and Millimeter Wave Forward Modeling Results from the 2004 North Slope of Alaska Arctic Winter Radiometric Experiment E.R. Westwater, D. Cimini, M. Klein, and V. Leuski Cooperative Institute for Research in Environmental Sciences University of Colorado/NOAA-Environmental Technology Laboratory Boulder, Colorado V. Mattioli Dipartimento di Ingegneria Elettronica e dell'Informazione Universitά di Perugia Perugia, Italy A.J. Gasiewski NOAA-Environmental Technology Laboratory Boulder,

  13. Radio frequency (RF) microwave components and subsystems using loaded ridge waveguide

    DOE Patents [OSTI]

    Kang, Yoon W.

    2013-08-20

    A waveguide having a non-conductive material with a high permeability (.mu., .mu..sub.r for relative permeability) and/or a high permittivity (.di-elect cons., .di-elect cons..sub.r for relative permittivity) positioned within a housing. When compared to a hollow waveguide, the waveguide of this invention, reduces waveguide dimensions by .varies..mu. ##EQU00001## The waveguide of this invention further includes ridges which further reduce the size and increases the usable frequency bandwidth.

  14. Insensitive explosive composition and method of fracturing rock using an extrudable form of the composition

    SciTech Connect (OSTI)

    Davis, Lloyd L.

    2015-07-28

    Insensitive explosive compositions were prepared by reacting di-isocyanate and/or poly-isocyanate monomers with an explosive diamine monomer. Prior to a final cure, the compositions are extrudable. The di-isocyanate monomers tend to produce tough, rubbery materials while polyfunctional monomers (i.e. having more than two isocyanate groups) tend to form rigid products. The extrudable form of the composition may be used in a variety of applications including rock fracturing.

  15. University of Massachusetts Lowell: Technical Design Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. DEPARTMENT OF ENERGY (DOE) COLLEGIATE WIND COMPETITION UNIVERSITY OF MASSACHUSETTS LOWELL Wind Turbine Team Dean Kennedy Mechanical Engineering Dean_Kennedy@student.uml.edu Christopher Daly Plastics Engineering Christopher_Daly@student.uml.edu Donna DiBattista Plastics Engineering Donna_DiBattista@student.uml.edu Michael Dube Mechanical Engineering Michael_Dube@student.uml.edu Michael Schaefer Plastics Engineering Michael_Schaefer@student.uml.edu Erika Sjöberg Mechanical Engineering

  16. Acyl-chain remodeling of dioctanoyl-phosphatidylcholine in Saccharomyces cerevisiae mutant defective in de novo and salvage phosphatidylcholine synthesis

    SciTech Connect (OSTI)

    Kishino, Hideyuki; Eguchi, Hiroki; Takagi, Keiko; Horiuchi, Hiroyuki; Fukuda, Ryouichi; Ohta, Akinori

    2014-03-07

    Highlights: Dioctanoyl-PC (diC8PC) supported growth of a yeast mutant defective in PC synthesis. diC8PC was converted to PC species containing longer acyl residues in the mutant. Both acyl residues of diC8PC were replaced by longer fatty acids in vitro. This system will contribute to the elucidation of the acyl chain remodeling of PC. - Abstract: A yeast strain, in which endogenous phosphatidylcholine (PC) synthesis is controllable, was constructed by the replacement of the promoter of PCT1, encoding CTP:phosphocholine cytidylyltransferase, with GAL1 promoter in a double deletion mutant of PEM1 and PEM2, encoding phosphatidylethanolamine methyltransferase and phospholipid methyltransferase, respectively. This mutant did not grow in the glucose-containing medium, but the addition of dioctanoyl-phosphatidylcholine (diC8PC) supported its growth. Analyses of the metabolism of {sup 13}C-labeled diC8PC ((methyl-{sup 13}C){sub 3}-diC8PC) in this strain using electrospray ionization tandem mass spectrometry revealed that it was converted to PC species containing acyl residues of 16 or 18 carbons at both sn-1 and sn-2 positions. In addition, both acyl residues of (methyl-{sup 13}C){sub 3}-diC8PC were replaced with 16:1 acyl chains in the in vitro reaction using the yeast cell extract in the presence of palmitoleoyl-CoA. These results indicate that PC containing short acyl residues was remodeled to those with acyl chains of physiological length in yeast.

  17. Environmental implications of alternative-fueled automobiles: Air quality and greenhouse gas tradeoffs

    SciTech Connect (OSTI)

    MaClean, H.L.; Lave, L.B.

    2000-01-15

    The authors analyze alternative fuel-powerstrain options for internal combustion engine automobiles. Fuel/engine efficiency, energy use, pollutant discharges, and greenhouse gas emissions are estimated for spark and compression ignited, direct injected (DI), and indirect injected (II) engines fueled by conventional and reformulated gasoline, reformulated diesel, compressed natural gas (CNG), and alcohols. Since comparisons of fuels and technologies in dissimilar vehicles are misleading, the authors hold emissions level, range, vehicle size class, and style constant. At present, CNG vehicles have the best exhaust emissions performance while DI diesels have the worst. Compared to a conventional gasoline fueled II automobile, greenhouse gases could be reduced by 40% by a DI CNG automobile and by 25% by a DI diesel. Gasoline- and diesel-fueled automobiles are able to attain long ranges with little weight or fuel economy penalty. CNG vehicles have the highest penalty for increasing range, due to their heavy fuel storage systems, but are the most attractive for a 160-km range. DI engines, particularly diesels, may not be able to meet strict emissions standards, at least not without lowering efficiency.

  18. METHOD FOR PREPARING NORMORPHINE

    DOE Patents [OSTI]

    Rapoport, H.; Look, M.

    1959-06-01

    An improved method is presented for producing normorphine from morphine. Morphine as the starting material is acetylated by treatment with acetylating agents to produce di-acetyl morphine (heroin). The acetylated compound is reacted with cyanating agents to produce di-acetyl-cyanonormorphine (cyanonorheroin). The di-acetyl-cyanonormorphine compound is then treated in accordance with the improved hydrolysis reactions of the present invention in which concentrated hydrochloric acid is employed for a limited time period to hydrolyze the acetyl group therefrom forming cyanonormorphine. Subsequently, the reaction mixture is diluted and hydrolysis of the cyano groups from the cyanonormorphine is effected with a longer contact time with dilute hydrochloric acid thereby producing normorphine. A high over-all conversion and production of a high purity product which may be radioactlvely labeled, if desired, is obtained by operation of the process.

  19. Effects of Nanoparticle Morphology and Acyl Chain Length on Spontaneous Lipid Transfer Rates

    SciTech Connect (OSTI)

    Xia, Yan; Li, Ming; Charubin, Kamil; Liu, Ying; Heberle, Frederick A.; Katsaras, John; Jing, Benxin; Zhu, Yingxi; Nieh, Mu-Ping

    2015-11-05

    In this paper, we report on studies of lipid transfer rates between different morphology nanoparticles and lipids with different length acyl chains. The lipid transfer rate of dimyristoylphosphatidylcholine (di-C14, DMPC) in discoidal “bicelles” (0.156 h–1) is 2 orders of magnitude greater than that of DMPC vesicles (ULVs) (1.1 × 10–3 h–1). For both bicellar and ULV morphologies, increasing the acyl chain length by two carbons [going from di-C14 DMPC to di-C16, dipalmitoylphosphatidylcholine (DPPC)] causes lipid transfer rates to decrease by more than 2 orders of magnitude. Results from small angle neutron scattering (SANS), differential scanning calorimetry (DSC), and fluorescence correlation spectroscopy (FCS) are in good agreement. Finally, the present studies highlight the importance of lipid dynamic processes taking place in different morphology biomimetic membranes.

  20. Effects of Nanoparticle Morphology and Acyl Chain Length on Spontaneous Lipid Transfer Rates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xia, Yan; Li, Ming; Charubin, Kamil; Liu, Ying; Heberle, Frederick A.; Katsaras, John; Jing, Benxin; Zhu, Yingxi; Nieh, Mu-Ping

    2015-11-05

    In this paper, we report on studies of lipid transfer rates between different morphology nanoparticles and lipids with different length acyl chains. The lipid transfer rate of dimyristoylphosphatidylcholine (di-C14, DMPC) in discoidal “bicelles” (0.156 h–1) is 2 orders of magnitude greater than that of DMPC vesicles (ULVs) (1.1 × 10–3 h–1). For both bicellar and ULV morphologies, increasing the acyl chain length by two carbons [going from di-C14 DMPC to di-C16, dipalmitoylphosphatidylcholine (DPPC)] causes lipid transfer rates to decrease by more than 2 orders of magnitude. Results from small angle neutron scattering (SANS), differential scanning calorimetry (DSC), and fluorescence correlationmore » spectroscopy (FCS) are in good agreement. Finally, the present studies highlight the importance of lipid dynamic processes taking place in different morphology biomimetic membranes.« less

  1. Structure and Dynamics of Dinucleosomes Assessed by Atomic Force Microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Filenko, Nina A.; Palets, Dmytro B.; Lyubchenko, Yuri L.

    2012-01-01

    Dynamics of nucleosomes and their interactions are important for understanding the mechanism of chromatin assembly. Internucleosomal interaction is required for the formation of higher-order chromatin structures. Although H1 histone is critically involved in the process of chromatin assembly, direct internucleosomal interactions contribute to this process as well. To characterize the interactions of nucleosomes within the nucleosome array, we designed a dinucleosome and performed direct AFM imaging. The analysis of the AFM data showed dinucleosomes are very dynamic systems, enabling the nucleosomes to move in a broad range along the DNA template. Di-nucleosomes in close proximity were observed, but their populationmore » was low. The use of the zwitterionic detergent, CHAPS, increased the dynamic range of the di-nucleosome, facilitating the formation of tight di-nucleosomes. The role of CHAPS and similar natural products in chromatin structure and dynamics is also discussed.« less

  2. Magnetic and structural properties of yellow europium oxide compound and Eu(OH){sub 3}

    SciTech Connect (OSTI)

    Lee, Dongwook; Seo, Jiwon; Valladares, Luis de los Santos; Avalos Quispe, O.; Barnes, Crispin H.W.

    2015-08-15

    A new material based on a yellow europium oxide compound was prepared from europium oxide in a high vacuum environment. The structural and magnetic properties of the material were investigated. Owing to the absence of a crystal structure, the material exhibited a disordered magnetic behavior. In a reaction with deionized (DI) water without applied heat, the compound assumed a white color as soon as the DI water reached the powder, and the structure became polycrystalline Eu(OH){sub 3}. The magnetic properties, such as the thermal hysteresis, disappeared after the reaction with DI water, and the magnetic susceptibility of the yellow oxide compound weakened. The magnetic properties of Eu(OH){sub 3} were also examined. Although Eu{sup 3+} is present in Eu(OH){sub 3}, a high magnetic moment due to the crystal field effect was observed. - Graphical abstract: (top left) Optical image of the yellow europium oxide compound. (top right) Optical image of the product of DI water and yellow europium oxide. (bottom) Magnetization curves as a function of temperature measured in various magnetic field. - Highlights: • We prepared a new material based on a yellow europium oxide compound from europium oxide. • We characterized the magnetic properties of the material which exhibits a disordered magnetic behavior such as thermal hysteresis. • The compound turned white (Eu(OH){sub 3}) as soon as the DI water reached the powder. • The thermal hysteresis disappeared after the reaction with DI water and the magnetic susceptibility of the yellow oxide compound weakened.

  3. SU-E-T-413: Experience-Based VMAT Plan Quality Database

    SciTech Connect (OSTI)

    Bernstein, K; Kalach, N; Wolthuis, B; Tai, C; Kravchuk, A; Bernstein, E

    2014-06-01

    Purpose: To quantify VMAT plan quality using a retrospective study of over 200 clinical treated VMAT plans created using the Eclipse Treatment Planning System to create benchmarks of plan quality for a few categories of treatment sites. Methods: Using a controlled phantom geometry, various dosimetric indices were investigated to quantify dosimetric plan quality as a function of isocenter displacement from center of mass, average path length, number of arcs and PTV proximity to critical structures. Beginning with published dosimetry indices from SRS and SBRT evaluations, UDI (Unified Dosimetry Index) and modified UDI were tested before creating a new factor VMAT-DI. VMAT-DI was developed within boundaries of this project and it includes renormalized factors of conformity index, coverage index, modified gradient index and homogeneity index as well as indices based on routine clinical practice such as absolute dose max index. The plans were then evaluated using the VMAT-DI such that benchmarks for planning could be created. Results: The majority of the plans evaluated could be assigned VMAT-DI values within a range for each treatment site. However, the outliers were results of difficult planning parameters such as very irregular targets, inhomogeneities or difficult to achieve critical structure constraints. To effectively use VMAT-DI for guidance, especially for prediction of the plan quality for body sites new to the practice, VMATDI database needs to be subdivided by target complexity and by body site index/average path length factor. Conclusion: An experienced-based VMAT-DI database can be used to help analyze plans before evaluation by the physician to show that it adheres to the clinical standards of previously treated VMAT plans which will make a guideline for concluding the optimization. The introduction of institution-wide clinical planning protocols, standardizing OAR naming and constraints will make it possible to incorporate a cumulative critical structure

  4. Synthesis and structural characterization of [eta superscript 3]-allyl([alpha]-diimine)nickel(II) complexes bearing trimethylsilyl groups

    SciTech Connect (OSTI)

    Ionkin, Alex S.; Marshall, William J.

    2012-02-10

    A set of isomeric para- and meta-trimethylsilylphenyl ortho-substituted N,N-phenyl {alpha}-diimine ligands [(Ar-N C(Me)-(Me)C N-Ar) Ar=2,6-di(4-trimethylsilylphenyl)phenyl (16); Ar=2,6-di(3-trimethylsilylphenyl)phenyl (17)] have been synthesized through a two-step procedure. The palladium-catalyzed cross-coupling reaction between 2,6-dibromophenylamine (7) and 4-trimethylsilylphenylboronic acid (8), 3-trimethylsilylphenylboronic acid (9) was used to prepare 4,4-bis(trimethylsilyl)-[1,1;3,1]terphenyl-2-ylamine (10) and 3,3-bis(trimethylsilyl)-[1,1;3,1]terphenyl-2-ylamine (11). The di-1-adamantylphosphine oxide Ad{sub 2}P(O)H (13) and di-tert-butyl-trimethylsilylanylmethylphosphine tert-Bu{sub 2}P-CH{sub 2}-SiMe{sub 3} (14) were used for the first time as ligands for the Suzuki coupling. The condensation of 2,2,3,3-tetramethoxybutane (15) with anilines 10 and 11 afforded {alpha}-diimines 16 and 17. The reaction of {pi}-allylnickel chloride dimer (18), {alpha}-diimines (16), (17) and sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BAF) (19) or silver hexafluoroantimonate (20) led to two sets of isomeric complexes [{eta}{sup 3}-allyl(Ar-N C(Me)-(Me)C N-Ar)Ni]{sup +} X{sup -}, [Ar=2,6-di(4-trimethylsilylphenyl)phenyl, X=BAF (3), X=SbF6 (4); Ar=2,6-di(3-trimethylsilylphenyl)phenyl, X=BAF (5), X=SbF6 (6)]. The steric repulsion of closely positioned trimethylsilyl groups in 4 caused the distortion of the nickel square planar coordination by 17.6{sup o} according to X-ray analysis.

  5. Process for fullerene functionalization

    DOE Patents [OSTI]

    Cahill, P.A.; Henderson, C.C.

    1995-12-12

    Di-addended and tetra-addended Buckminster fullerenes are synthesized through the use of novel organoborane intermediates. The C{sub 60}, C{sub 70}, or higher fullerene is reacted with a borane such as BH{sub 3} in a solvent such as toluene to form an organoborane intermediate. Reaction of the organoborane such as hydrolysis with water or alcohol results in the product di-addended and tetra-addended fullerene in up to 30% yields. Dihydrofullerenes and tetrahydrofullerenes are produced by the process of the invention. 7 figs.

  6. d:\

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (2001) 919-927 www.iop.org/Journals/pp PII: S0741-3335(01)21911-3 Magnetic fluctuations and energy transport in RFX G Serianni 1 , A Murari 1 , G Fiksel 2 , V Antoni 1,3 , M Bagatin 1,3 , D Desideri 1,3 , E Martines 1 and L Tramontin 1 1 Consorzio RFX-Corso Stati Uniti, 4-35127 Padova, Italy 2 Department of Physics, University of Wisconsin-Madison, Madison, WI 53706, USA 3 Istituto Nazionale di Fisica della Materia, Unit` a di Padova, Italy Received 14 February 2001, in final form 8 May 2001

  7. Microsoft PowerPoint - Low Dose Update Metting 6 Dec 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Dose DOE's Low Dose R di ti R h R di ti R h Radiation Research Radiation Research Program Program g g NF Metting, Sc.D., Program Manager Nuclear Energy Advisory Committee Meeting Nuclear Energy Advisory Committee Meeting L'Enfant Plaza Hotel L'Enfant Plaza Hotel 6 December 2012 Office of Science Office of Biological and Environmental Research DOE's Low Dose Program: DOE s Low Dose Program: Is unique within the U.S. government in focusing on low dose biological research aimed at informing

  8. Microsoft PowerPoint - Managing Uncertainty and Demonstrating Compliance

    Office of Environmental Management (EM)

    Low Dose DOE's Low Dose R di ti R h R di ti R h Radiation Research Radiation Research Program Program g g NF Metting, Sc.D., Program Manager Nuclear Energy Advisory Committee Meeting Nuclear Energy Advisory Committee Meeting L'Enfant Plaza Hotel L'Enfant Plaza Hotel 6 December 2012 Office of Science Office of Biological and Environmental Research DOE's Low Dose Program: DOE s Low Dose Program: Is unique within the U.S. government in focusing on low dose biological research aimed at informing

  9. Method for cleaning solution used in nuclear fuel reprocessing

    DOE Patents [OSTI]

    Tallent, Othar K. (Oak Ridge, TN); Dodson, Karen E. (Knoxville, TN); Mailen, James C. (Oak Ridge, TN)

    1983-01-01

    A nuclear fuel processing solution containing (1) hydrocarbon diluent, (2) tri-n-butyl phosphate or tri-2-ethylhexyl phosphate, and (3) monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, di-2-ethylhexyl phosphate, or a complex formed by plutonium, uranium, or a fission product thereof with monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, or di-2-ethylhexyl phosphate is contacted with silica gel having alkali ions absorbed thereon to remove any one of the degradation products named in section (3) above from said solution.

  10. 1009-0630_17_2_04

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An AMR Capable Finite Element DiÆusion Solver for ALE Hydrocodes A. C. FISHER 1 , D. S. BAILEY 1 , T. B. KAISER 1 , D. C. EDER 1 , B. T. N. GUNNEY 1 , N. D. MASTERS 1 , A. E. KONIGES 2 , R. W. ANDERSON 1 1 Lawrence Livermore National Laboratory, P. O. Box 808, Livermore, CA 94551, USA 2 Lawrence Berkeley National Laboratory, 1 Cyclotron Rd. Berkeley, CA 94720, USA Abstract We present a novel method for the solution of the diÆusion equation on a composite AMR mesh. This approach is suitable for

  11. rptserver.asp

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Department of Energy FY 2014 Congressional Budget Request State Tables P li i Preliminary April 2013 Office of Chief Financial Officer DOE/CF-0092 Department of Energy FY 2014 Congressional Budget Request State Tables P li i Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. Th fi i l d b th th di ti d d t f di i th b d t Th d t id The figures include both the discretionary and mandatory funding in the budget. They do

  12. rqxb180.tmp

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Department of Energy FY 2014 Congressional Budget Request State Tables P li i Preliminary April 2013 Office of Chief Financial Officer DOE/CF-0092 Department of Energy FY 2014 Congressional Budget Request State Tables P li i Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. Th fi i l d b th th di ti d d t f di i th b d t Th d t id The figures include both the discretionary and mandatory funding in the budget. They do

  13. Process for fullerene functionalization

    DOE Patents [OSTI]

    Cahill, Paul A.; Henderson, Craig C.

    1995-01-01

    Di-addended and tetra-addended Buckminster fullerenes are synthesized through the use of novel organoborane intermediates. The C.sub.60, C.sub.70, or higher fullerene is reacted with a borane such as BH.sub.3 in a solvent such as toluene to form an organoborane intermediate. Reaction of the organoborane such as hydrolysis with water or alcohol results in the product di-addended and tetra-addended fullerene in up to 30% yields. Dihydrofullerenes and tetrahydrofullerenes are produced by the process of the invention.

  14. Structure of adenovirus bound to cellular receptor car

    DOE Patents [OSTI]

    Freimuth, Paul I.

    2007-01-02

    Disclosed is a mutant CAR-DI-binding adenovirus which has a genome comprising one or more mutations in sequences which encode the fiber protein knob domain wherein the mutation causes the encoded viral particle to have a significantly weakened binding affinity for CAR-DI relative to wild-type adenovirus. Such mutations may be in sequences which encode either the AB loop, or the HI loop of the fiber protein knob domain. Specific residues and mutations are described. Also disclosed is a method for generating a mutant adenovirus which is characterized by a receptor binding affinity or specificity which differs substantially from wild type.

  15. Biodiversity | Savannah River National Environmental Park

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    El biodiésel es un combustible renovable producido a nivel nacional que puede elaborarse a partir de aceites vegetales nuevos y usados, grasas animales y grasa reciclada proveniente de restaurantes. Las propiedades físicas del biodiésel son similares a las del diésel de petróleo, pero la primera es una alternativa renovable de combustión más limpia. Utilizar biodiésel en lugar de diésel de petróleo reduce signifcativamente las emisiones de carbono durante su vida útil. Las

  16. 2010 > Publications > Research > The Energy Materials Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CV Subban, Q Zhou, A Hu, TE Moylan, FT Wagner and FJ DiSalvo Journal of the American Chemical Society, 132(49), pp 17531-17536, 2010 DOI: 10.1021ja1074163 Pt-Decorated PdCo@PdC...

  17. A Porous Metal-Organic Framework with Helical Chain Building Units Exhibiting Facile Transition from Micro- to Meso-porosity

    SciTech Connect (OSTI)

    Park, Jinhee; Li, Jian-Rong; Carolina Sañudo, E.; Yuan, Daqiang; Zhou, Hong-Cai

    2012-01-01

    A metal–organic framework (MOF) with helical channels has been constructed by bridging helical chain secondary building units with 2,6-di-p-carboxyphenyl-4,4'-bipyridine ligands. The activated MOF shows permanent porosity and gas adsorption selectivity. Remarkably, the MOF exhibits a facile transition from micro- to meso-porosity.

  18. Parallel Dislocation Simulator

    Energy Science and Technology Software Center (OSTI)

    2006-10-30

    ParaDiS is software capable of simulating the motion, evolution, and interaction of dislocation networks in single crystals using massively parallel computer architectures. The software is capable of outputting the stress-strain response of a single crystal whose plastic deformation is controlled by the dislocation processes.

  19. Formulations for iron oxides dissolution

    DOE Patents [OSTI]

    Horwitz, Earl P.; Chiarizia, Renato

    1992-01-01

    A mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal oxides and optionally containing corrosion inhibitors and pH adjusting agents.

  20. BPA-2012-00009-C FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Request Form Date: Friday, August 26, 2011 1:56:54 PM RECE)VIj) BY R.PA First Name: t Richard FOIA OFFICE "1lIS Last Name: van Dijk Email: DI. E: f).. I F:: Company: Another...

  1. 1-/sup 11/C-2-deoxy-D-glucose and process for the preparation thereof

    DOE Patents [OSTI]

    MacGregor, R.R.; Wolf, A.P.; Shiue, C.Y.; Wan, C.N.

    1980-02-08

    The novel labelled compound 1-/sup 11/C-2-deoxy-D-glucose, and a process for its preparation from 2,3:4,5-di-O-isopropylidene-D-arabinitol derivatives of relatively high reactivity are disclosed. 1-/sup 11/C-2-deoxy-D-glucose is useful for measuring regional brain glucose metabolism in vivo.

  2. PART I - THE SCHEDULE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D Contract No. DE-AC06-09RL14728 D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING TABLE OF CONTENTS D.1 PACKAGING ................................................................................................................ D-1 D.2 MARKING .................................................................................................................... D-1 D.3 SECURITY REQUIREMENTS ...................................................................................... D-1 Mission

  3. PART I - THE SCHEDULE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D Contract No. DE-AC27-08RV14800 D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING TABLE OF CONTENTS D.1 PACKAGING ................................................................................................................ D-1 D.2 MARKING .................................................................................................................... D-1 D.3 SECURITY REQUIREMENTS ...................................................................................... D-1 Tank

  4. Zhiming Cui > Research Fellow - UT Austin > Center Alumni > The Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Center at Cornell Zhiming Cui Research Fellow - UT Austin cuizm26@gmail.com Formerly a postdoc with the DiSalvo Group, he is now working at the University of Texas - Austin. He joined the Department of Mechanical Engineering in the Summer of 2014

  5. A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    48 55 22 41 52 28 50 02 63 66 64 74 00 62 58 59 11 P a j a r i t o R o a d Los Alamos Airport Di am o nd D r iv e W e st J e m e z R oad 00 Technical Areas TA-00 TA-02 TA-03 TA-05...

  6. The BRAG and GM2003 Models for Glass Dissolution

    SciTech Connect (OSTI)

    Aertsens, Marc

    2007-07-01

    The GM2003 model extends the r(t) glass dissolution model with water diffusion through the diffusion layer. Boron and alkali diffusion through the diffusion layer is described by introducing a retention factor K{sub d,i} between boron/alkali and water in the diffusion layer. Introducing a boron/alkali diffusion coefficient, the BRAG model describes boron/alkali diffusion in the diffusion layer as well. It is shown that both models are consistent with each other and an expression is derived for the boron/alkali diffusion coefficient (BRAG) as a function of both parameters of GM2003: the retention factor K{sub d,i} and the water diffusion coefficient D{sub H{sub 2}}{sub O} in the diffusion layer. From dissolution data only, it is possible to fit the value for the boron/alkali diffusion coefficient in the diffusion layer but due to correlations the individual values of both parameters K{sub d,i} and DH{sub 2}O of GM2003 cannot be determined. From theoretical considerations follows that the K{sub d,i} value for boron/alkali should be slightly larger than 0.1 kg/liter. A user friendly code for the BRAG model allows automatic fits of glass dissolution data in water. (authors)

  7. Augmented Reality for Close Quarters Combat

    ScienceCinema (OSTI)

    None

    2014-06-23

    Sandia National Laboratories has developed a state-of-the-art augmented reality training system for close-quarters combat (CQB). This system uses a wearable augmented reality system to place the user in a real environment while engaging enemy combatants in virtual space (Boston Dynamics DI-Guy). Umbra modeling and simulation environment is used to integrate and control the AR system.

  8. CD-1: Intracratonic Basin | Open Energy Information

    Open Energy Info (EERE)

    A.S. Batchelor, D.D. Blackwell, R. DiPippo, E.M. Drake, J. Garnish, B. Livesay, M.C. Moore, K. Nichols, S. Petty, M. Nafi Toksoz, R.W. Veatch, R. Baria, C. Augustine, E. Murphy,...

  9. Microsoft PowerPoint - ARM2008_poster_mbc_raf [Compatibility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 NASA L l R h C t 2 U i it f Wi i M di 3 S i S t d A li ti I 4 P ifi N th t N ti l L b t1 NASA Langley Research Center 2 University of Wisconsin-Madison 3 Science Systems and ...

  10. Transition metal-free olefin polymerization catalyst

    DOE Patents [OSTI]

    Sen, Ayusman; Wojcinski, II, Louis M.; Liu, Shengsheng

    2001-01-01

    Ethylene and/or propylene are polymerized to form high molecular weight, linear polymers by contacting ethylene and/or propylene monomer, in the presence of an inert reaction medium, with a catalyst system which consists essentially of (1) an aluminum alkyl component, such as trimethylaluminum, triethylaluminum, triisobutylaluminum, tri-n-octylaluminum and diethylaluminum hydride and (2) a Lewis acid or Lewis acid derivative component, such as B (C.sub.6 F.sub.5).sub.3, [(CH.sub.3).sub.2 N (H) (C.sub.6 H.sub.5)].sup.+ [B (C.sub.6 F.sub.5)4].sup.-, [(C.sub.2 H.sub.5).sub.3 NH].sup.+ [B C.sub.6 F.sub.5).sub.4 ],.sup.-, [C(C.sub.6 F.sub.5).sub.3 ].sup.+ [B(C.sub.6 F.sub.5).sub.4 ].sup.-, (C.sub.2 H.sub.5).sub.2 Al(OCH.sub.3), (C.sub.2 H.sub.5).sub.2 Al(2,6-di-t-butyl-4-methylphenoxide), (C.sub.2 H.sub.5)Al(2,6 -di-t-butylphenoxide).sub.2, (C.sub.2 H.sub.5).sub.2 Al(2,6-di-t-butylphonoxide) , 2,6 -di-t-butylphenol.multidot.methylaluminoxane or an alkylaluminoxane, and which may be completely free any transition metal component(s).

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... We find weak evidence that both the deuteron and the di-neutron are bound at this pion mass, with binding energies of Bsub d 11(05)(12) MeV and Bsub nn 7.1(5.2)(7.3) MeV, ...

  12. Fernald Preserve 2015 Site Environmental Report Appendix D Environmental Restoration

    Office of Legacy Management (LM)

    Restoration This page intentionally left blank U.S. Department of Energy Fernald Preserve 2015 Site Environmental Report May 2016 Doc. No. S13591 Page D-i Contents Abbreviations ............................................................................................................................. D-iii Measurement Abbreviations ...................................................................................................... D-iii D.1.0 Ecological Restoration Monitoring

  13. Search for Gauge Mediated Supersymmetry in the gamma gamma missing ET Channel

    SciTech Connect (OSTI)

    Kesisoglou, Stilianos Isaak

    2004-12-01

    We present results on a search for Gauge Mediated Supersymmetry in the di-photon final state using Run II data collected by the D0 Experiment at the Fermilab Tevatron Collider. We discuss event selection, Standard Model backgrounds, and the lower limits on the lightest neutralino and chargino masses resulted from this analysis.

  14. Latest Results on Orbitally Excited Strange Bottom Mesons with the CDF II Detector

    SciTech Connect (OSTI)

    Gorelov, Igor V.; /New Mexico U.

    2006-10-01

    The authors present the latest results on the spectroscopy of orbitally excited strange bottom mesons from {approx} 1 fb{sup -1} of CDF data. The measurements are performed with fully reconstructed B decays collected by the CDF II detector at {radical}s = 1.96 TeV in both the di-muon and the fully hadronic trigger paths.

  15. Path to High Efficiency Gasoline Engine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Path to High Efficiency Gasoline Engine Path to High Efficiency Gasoline Engine Path to High Efficiency Gasoline Engine deer10_johansson.pdf (4.97 MB) More Documents & Publications Partially Premixed Combustion High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control Advanced Lean-Burn DI Spark Ignition Fuels Research

  16. To1 Col. A. 8. Pry., Jr. Prom L. c. Furney

    Office of Legacy Management (LM)

    . ' .... 200 lb6 B+ 2.0 lbe UjoB the A. C. Spark Plxq Company'aartified on IebmAr'y 4, 1947 that .they have reoelrad II-05 the UaabatknEaginoer Di&riCt 909.5 lb6 Of FWO, 33 lbs ...

  17. 14655 Section D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D Contract No. DE-AC06-05RL14655 A000 PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING TABLE OF CONTENTS D.1 PACKAGING......................................................................................................................................1 D.2 MARKING ..........................................................................................................................................1 D-i River Corridor Closure Contract Section D Contract No. DE-AC06-05RL14655 A000 PART I

  18. University of Massachusetts Amherst | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Massachusetts Amherst University of Massachusetts Amherst Team roster: Evan Benoit, Mechanical Engineering; Robert Bonetti, Management; Kristina Bosnic, Mechanical Engineering; Justin Calderara, Mechanical Engineering; Murphy Davidson, Mechanical Engineering; Marina Di Cocco, Industrial Engineering; Stephen Draghi, Accounting; Eric Dupuis, Mechanical Engineering; Gregory Forbes, Mechanical Engineering; Pavel Grigorash, Mechanical Engineering; Stephen Hicks, Mechanical Engineering; John Hoar,

  19. Hydrogen transfer from alcohols to carbonyl compounds catalyzed by aluminum porphyrins. Stereochemical aspects

    SciTech Connect (OSTI)

    Konishi, Katsuaki; Aida, Takuzo; Inoue, Shohei (Univ. of Tokyo (Japan))

    1990-02-02

    There is interest in synthesizing molecules containing di- or tri-sulfide linkages together with sulfinate functions because of their potential as antiradiation agents. In the process of synthesizing such compounds, formation of monothioquinone S,S-dioxides presented a mechanistic problem which had to be overcome. This paper focuses on the formation of these dioxides and routes around them.

  20. The hemicellulases from the ethanologenic thermophile, Thermoanaerobacter ethanolicus and similar anaerobic thermophiles. Annual technical progress report

    SciTech Connect (OSTI)

    Wiegel, J.

    1995-07-01

    A Xylanase was fractionated from Thermoanaerobacter ethanolicus, an ethanologenic thermophile, and the preparation so obtained was used to determined enzymatic parameters such as pH profile of enzyme activity. The ability of various mono- and di-saccharides as well as temperature variations to induce this enzyme activity were studied.

  1. VI-12 STUDENTS WHO RECEIVED GRADUATE DEGREES FROM THESIS WORK...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GeV Au+Au Collision with STAR S. Mioduszewski N.A. James Lucus Drachenberg 2012 Forward Di-Hadron Asymmetries from p + p at sqrt(s)200GeV at STAR C. A. Gagliardi N.A. Matthew C....

  2. Multiply Methyl-Branched Fatty Acids and Diacids in the Polar Lipids of a Microaerophilic Subsurface Microbial Community

    SciTech Connect (OSTI)

    Hedrick, David B.; Peacock, Aaron D.; Long, Philip E.; White, David C.

    2008-09-01

    A previously unreported series of di- and trimethylated fatty acids, as well as saturated and monounsaturated diacids were identified in polar lipids isolated from environmental subsurface sediment samples. Mechanisms are proposed for their formation, but their origin and role in cell membranes remains unknown.

  3. THE AEROSPACE CORPORATION

    Office of Legacy Management (LM)

    ... Gf cl:c' ;F:;: ty.3 rccidj.:itl c::. ----nsAio?, loft irl ti9 lT' .ill f%ftCZ' +5:' lOrk3 :Z: baDI: Z' ,323 5% FlpL::' k 0 LGilTJ-G- i' ,x 1 -.Dns?j-;i? ' A .. t' :iC.? ...

  4. Augmented Reality for Close Quarters Combat

    SciTech Connect (OSTI)

    2013-09-20

    Sandia National Laboratories has developed a state-of-the-art augmented reality training system for close-quarters combat (CQB). This system uses a wearable augmented reality system to place the user in a real environment while engaging enemy combatants in virtual space (Boston Dynamics DI-Guy). Umbra modeling and simulation environment is used to integrate and control the AR system.

  5. RIFLE TO SAN JUAN

    Office of Environmental Management (EM)

    Di r ec to r Wes t e r n A r e a - E l ec tric Ru r al E l ec t rifica tio n Adminis t r a tio n 14 th & Inde p e nde nce Ave., S.W. Washi n g ton, D.C. 20250 Tele pho n e:...

  6. 40th Anniversary of the First Proton-Proton Collisions in the CERN Intersecting Storage Rings (ISR)

    ScienceCinema (OSTI)

    None

    2011-10-06

    Welcome, Luigi di Lella and Rolf HeuerDesign and Construction of the ISR, Kurt HubnerPhysics at small angles, Ugo Amaldi (TERA Foundation)The Impact of the ISR on Accelerator Physics and Technology, Philip J. BryantPhysics at high transverse momentum, Pierre Darriulat (VATLY-Hanoi)Concluding remarks, Rolf Heuer

  7. Health hazard evaluation report No. HETA 80-186-1149, TLB Plastics Corporation, Marion, Indiana

    SciTech Connect (OSTI)

    Gorman, R.W.; Schleomer, J.R.

    1982-07-01

    Laboratory analysis of the cellulose acetate propionate heated to the extrusion temperature revealed that emission products included propionic acid, acetic acid, and plasticizers (suspected but not confirmed to be di(2-ethylbutyl)azelate). Recommendations are provided in the body of the full report to further minimize solvent exposure, eliminate exposure to extrusion emissions, and increase worker comfort.

  8. Acetals and ketals of reduced sugars as fuel system icing inhibitor additives

    SciTech Connect (OSTI)

    Mushrush, G.W.; Stalick, W.M.; Basu, S.

    1996-10-01

    Currently the fuel system icing inhibitor additives ethylene glycol monomethyl ether (EGME) and diethylene glycol monomethyl ether (DiEGME) are mandatory in all military aircraft fuels. These additives are optional for use in all worldwide commercial aviation fuels depending on routes, flight lengths, and season. These deicing compounds are toxic at the concentrations that are required for effective deicing. The additives are leached out of the fuel and into tank water bottoms; glycols exert high oxygen demand. In addition, water drained from fuel system pumps, filters and storage tanks contain EGME/DiEGME and creates a personnel hazard. Acetals and ketals of reduced sugars represent viable alternatives to glycol based additives. They are inexpensive, fuel stable for at least one year and show the similar icing inhibitor characteristics. The synthesis and fuel studies for these compounds will be presented.

  9. Physical properties of bio-diesel & Implications for use of bio-diesel in diesel engines

    SciTech Connect (OSTI)

    Chakravarthy, Veerathu K; McFarlane, Joanna; Daw, C Stuart; Ra, Youngchul; Griffin, Jelani K

    2008-01-01

    In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both regular diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study. Future studies of diesel combustion sensitivity to both physical and chemical properties of biodiesel are suggested.

  10. Biomarkers to monitor drug-induced phospholipidosis

    SciTech Connect (OSTI)

    Baronas, Elizabeth Tengstrand; Lee, Ju-Whei; Alden, Carl; Hsieh, Frank Y. . E-mail: frank.hsieh@nextcea.com

    2007-01-01

    Di-docosahexaenoyl (C22:6)-bis(monoacylglycerol) phosphate (BMP) was identified as a promising phospholipidosis (PL) biomarker in rats treated with either amiodarone, gentamicin, or azithromycin. Sprague-Dawley rats received either amiodarone (150 mg/kg), gentamicin (100 mg/kg) or azithromycin (30 mg/kg) once daily for ten consecutive days. Histopathological examination of tissues by transmission electron microscopy (TEM) indicated different degrees of accumulation of phospholipidosis in liver, lung, mesenteric lymph node, and kidney of drug-treated rats but not controls. Liquid chromatography coupled to mass spectrometry (LC/MS) was used to identify levels of endogenous biochemical profiles in rat urine. Urinary levels of di-docosahexaenoyl (C22:6)-bis(monoacylglycerol) phosphate (BMP) correlated with induction of phospholipidosis for amiodarone, gentamicin and azithromycin. Rats treated with gentamicin also had increased urinary levels of several phosphatidylinositol (PI), phosphatidylcholine (PC), and phosphatidylethanolamine (PE) species.

  11. Z' boson detection in the minimal quiver standard model

    SciTech Connect (OSTI)

    Berenstein, D.; Martinez, R.; Ochoa, F.; Pinansky, S.

    2009-05-01

    We undertake a phenomenological study of the extra neutral Z' boson in the minimal quiver standard model and discuss limits on the model's parameters from previous precision electroweak experiments, as well as detection prospects at the Large Hadron Collider at CERN. We find that masses lower than around 700 GeV are excluded by the Z-pole data from the CERN LEP collider, and below 620 GeV by experimental data from di-electron events at the Fermilab Tevatron collider. We also find that at a mass of 1 TeV the LHC cross section would show a small peak in the di-lepton and top pair channel.

  12. A=10B (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9AJ01) (See Energy Level Diagrams for 10B) GENERAL: See also (1974AJ01) and Table 10.5 [Table of Energy Levels] (in PDF or PS). Shell and deformed models: (1973BO1C, 1974BO29, 1974BO54, 1974BO1P, 1975DI04, 1977JA14). Cluster and α-particle models: (1976GA34, 1977NA20, 1977OK1C). Special levels: (1974BO29, 1974BO1P, 1974IR04, 1974NI1A, 1975DI04, 1976GA34, 1976IR1B, 1977BI1D, 1977JA14, 1977NA20). Electromagnetic transitions: (1974BO29, 1974BO54, 1974BO1P, 1974HA1C, 1974MU13, 1977BO1V, 1977DO06,

  13. A=11C (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    80AJ01) (See Energy Level Diagrams for 11C) GENERAL: See also (1975AJ02) and Table 11.19 [Table of Energy Levels] (in PDF or PS). Special levels: (1976IR1B). Astrophysical questions: (1976VI1A, 1977SC1D, 1977SI1D, 1978BU1B). Special reactions: (1975HU14, 1976BE1K, 1976BU16, 1976DI01, 1976HE1H, 1976LE1F, 1976SM07, 1977AR06, 1977AS03, 1977SC1G, 1978DI1A, 1978GE1C, 1978HE1C, 1979KA07, 1979VI05). Muon and neutrino capture and reactions: (1975DO1F, 1976DO1G). Pion capture and reactions (See also

  14. A=14O (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    81AJ01) (See Energy Level Diagrams for 14O) GENERAL: See also (1976AJ04) and Table 14.21 [Table of Energy Levels] (in PDF or PS). Special reactions involving 14O: (1976AB04, 1978AB08). Astrophysical questions: (1977JO1D, 1977SI1D). Applied topics: (1978HI1D). Reactions involving pions: (1976DI10, 1976DI11, 1977HO1B, 1978SH12, 1979LI1H, 1980DE10, 1980SI07). Other topics: (1976IR1B, 1976ST13, 1976VO1C, 1979KA13). Mass of 14O: The recent 14N(p, n)14O threshold measurement by (1977WH01) leads to an

  15. Light-emitting block copolymers composition, process and use

    DOE Patents [OSTI]

    Ferraris, John P.; Gutierrez, Jose J.

    2006-11-14

    Generally, and in one form, the present invention is a composition of light-emitting block copolymer. In another form, the present invention is a process producing a light-emitting block copolymers that intends polymerizing a first di(halo-methyl) aromatic monomer compound in the presence of an anionic initiator and a base to form a polymer and contacting a second di(halo-methyl) aromatic monomer compound with the polymer to form a homopolymer or block copolymer wherein the block copolymer is a diblock, triblock, or star polymer. In yet another form, the present invention is an electroluminescent device comprising a light-emitting block copolymer, wherein the electroluminescent device is to be used in the manufacturing of optical and electrical devices.

  16. CARB/SQAQMD cooperative methanol vehicle development program: Phase 1. Final report

    SciTech Connect (OSTI)

    1996-04-01

    This project was structured as a jointly-funded effort by the California Air Resources Board and the South Coast Air Quality Management District. The purpose of the Phase I work effort was to develop and evaluate an electronic alcohol injection system for DI passenger car engines. The deliverable was the evaluation, design and fabrication of a methanol compatible, electronically controlled fuel injection system, including modification/ adaptation of the engine control unit, and the ensuing functional engine testing. The technology that has been developed under this contract represents a near-production level injection system featuring electronic control of both the injection timing and quantity, closed loop EGR, and glow plug power. This development represents a significant technical progression in terms of the potential for passenger car vehicles to meet future emissions standards with methanol fueled DI engines.

  17. Evaluating ligands for use in polymer ligand film (PLF) for plutonium and uranium extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rim, Jung H.; Peterson, Dominic S.; Armenta, Claudine E.; Gonzales, Edward R.; Ünlü, Kenan

    2015-05-08

    We describe a new analyte extraction technique using Polymer Ligand Film (PLF). PLFs were synthesized to perform direct sorption of analytes onto its surface for direct counting using alpha spectroscopy. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through a radiometric technique. 4'(5')-di-t-butylcyclohexano 18-crown-6 (DtBuCH18C6) and 2-ethylhexylphosphonic acid (HEH[EHP]) were examined for plutonium extraction. Di(2-ethyl hexyl) phosphoric acid (HDEHP) were examined for plutonium and uranium extraction. DtBuCH18C6 and HEH[EHP] were not effective in plutonium extraction. HDEHP PLFs were effective for plutonium but not for uranium.

  18. Evaluating ligands for use in polymer ligand film (PLF) for plutonium and uranium extraction

    SciTech Connect (OSTI)

    Rim, Jung H.; Peterson, Dominic S.; Armenta, Claudine E.; Gonzales, Edward R.; Ünlü, Kenan

    2015-05-08

    We describe a new analyte extraction technique using Polymer Ligand Film (PLF). PLFs were synthesized to perform direct sorption of analytes onto its surface for direct counting using alpha spectroscopy. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through a radiometric technique. 4'(5')-di-t-butylcyclohexano 18-crown-6 (DtBuCH18C6) and 2-ethylhexylphosphonic acid (HEH[EHP]) were examined for plutonium extraction. Di(2-ethyl hexyl) phosphoric acid (HDEHP) were examined for plutonium and uranium extraction. DtBuCH18C6 and HEH[EHP] were not effective in plutonium extraction. HDEHP PLFs were effective for plutonium but not for uranium.

  19. A=5He (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9AJ01) (See Energy Level Diagrams for 5He) GENERAL: See also (1974AJ01) and Table 5.1 [Table of Energy Levels] (in PDF or PS) here. Model calculations: (1974JA30, 1974LE22, 1975DI04). Special states: (1974GO13, 1974IR04, 1974JA30, 1974LE22, 1975DI04, 1976IR1B). Special reactions: (1973FE1A, 1974FE1A, 1975FE1A, 1976VA29, 1978ME1C). Reactions involving pions: (1973BA30, 1978FI1E). Other topics: (1974GO13, 1974IR04, 1976BI1A, 1976IR1B, 1977SH1B, 1978GO1D). Ground state of 5He: (1975BE31, 1977HI09).

  20. Low-voltage polariton electroluminescence from an ultrastrongly coupled organic light-emitting diode

    SciTech Connect (OSTI)

    Gubbin, Christopher R.; Maier, Stefan A.; Kna-Cohen, Stphane

    2014-06-09

    We demonstrate electroluminescence from Frenkel molecular excitons ultrastrongly coupled to photons of a metal-clad microcavity containing a 2,7-bis[9,9-di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl)fluorene emissive layer. Thin layers of molybdenum oxide and 4,7-diphenyl-1,10-phenanthroline are used as hole and electron injection layers, respectively. The fabricated devices exhibit an electroluminescence threshold of 3.1?V, a value that is below the bare exciton energy. This result is found to be independent of detuning and consistent with a two-step process for polariton formation. Moreover, we investigate the quantum efficiency of carrier to polariton to photon conversion and obtain an external quantum efficiency of 0.1% for the fabricated structures, an improvement of 5 orders of magnitude over previous reports.

  1. A threat-based definition of IA- and IA-enabled products.

    SciTech Connect (OSTI)

    Shakamuri, Mayuri; Schaefer, Mark A.; Campbell, Philip LaRoche

    2010-07-01

    This paper proposes a definition of 'IA and IA-enabled products' based on threat, as opposed to 'security services' (i.e., 'confidentiality, authentication, integrity, access control or non-repudiation of data'), as provided by Department of Defense (DoD) Instruction 8500.2, 'Information Assurance (IA) Implementation.' The DoDI 8500.2 definition is too broad, making it difficult to distinguish products that need higher protection from those that do not. As a consequence the products that need higher protection do not receive it, increasing risk. The threat-based definition proposed in this paper solves those problems by focusing attention on threats, thereby moving beyond compliance to risk management. (DoDI 8500.2 provides the definitions and controls that form the basis for IA across the DoD.) Familiarity with 8500.2 is assumed.

  2. A threat-based definition of IA and IA-enabled products.

    SciTech Connect (OSTI)

    Shakamuri, Mayuri; Schaefer, Mark A.; Campbell, Philip LaRoche

    2010-09-01

    This paper proposes a definition of 'IA and IA-enabled products' based on threat, as opposed to 'security services' (i.e., 'confidentiality, authentication, integrity, access control or non-repudiation of data'), as provided by Department of Defense (DoD) Instruction 8500.2, 'Information Assurance (IA) Implementation.' The DoDI 8500.2 definition is too broad, making it difficult to distinguish products that need higher protection from those that do not. As a consequence the products that need higher protection do not receive it, increasing risk. The threat-based definition proposed in this paper solves those problems by focusing attention on threats, thereby moving beyond compliance to risk management. (DoDI 8500.2 provides the definitions and controls that form the basis for IA across the DoD.) Familiarity with 8500.2 is assumed.

  3. Section 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Expansion of the CAGEX Database with a Network of Surface Radiometers and Aircraft Measurements in the ARM Enhanced Shortwave Experiment: Forthcoming Helicopter Measurements of BDRF Over the Southern Great Plains Cloud and Radiation Testbed Site T. L. Alberta, R. C. DiPasquale, F. G. Rose, W. L. Smith, Jr. Analytical Services and Materials, Inc. Hampton, Virginia T. P. Charlock, C. H. Whitlock, G. L. Schuster, P. Minnis NASA Langley Research Center Hampton, Virginia Introduction The

  4. Novel Stack Concepts: Patterned Aligned Carbon Nanotubes as Electrodes in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEAs | Department of Energy Stack Concepts: Patterned Aligned Carbon Nanotubes as Electrodes in MEAs Novel Stack Concepts: Patterned Aligned Carbon Nanotubes as Electrodes in MEAs This presentation, which focuses on novel stack concepts, was given by Di-Jia Liu of Argonne National Laboratory at a February 2007 meeting on new fuel cell projects. new_fc_liu_argonne.pdf (2.14 MB) More Documents & Publications Novel PEMFC Stack Using Patterned Aligned Carbon Nanotubes as Electrodes in MEA

  5. Data Capture Technique for High Speed Signaling

    DOE Patents [OSTI]

    Barrett, Wayne Melvin; Chen, Dong; Coteus, Paul William; Gara, Alan Gene; Jackson, Rory; Kopcsay, Gerard Vincent; Nathanson, Ben Jesse; Vranas, Paylos Michael; Takken, Todd E.

    2008-08-26

    A data capture technique for high speed signaling to allow for optimal sampling of an asynchronous data stream. This technique allows for extremely high data rates and does not require that a clock be sent with the data as is done in source synchronous systems. The present invention also provides a hardware mechanism for automatically adjusting transmission delays for optimal two-bit simultaneous bi-directional (SiBiDi) signaling.

  6. University of Massachusetts Lowell | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Massachusetts Lowell University of Massachusetts Lowell Back row: Isaac Grulon, Dean Kennedy, Erika Sjoberg, Albert Andino, Robert Leboeuf, Gregory Lennartz, Michael Dube. Middle row: David Phung, Jigar Patel, Alexandre Sampaio, Patrick Logan, Jeffrey Chung, Peter Jones. Front row: Parth Patel, Donna DiBattista, Meaghan Riley, Michael Schaefer. Not pictured: Christopher Daly, Erik Anderson. Photo by David Willis. Back row: Isaac Grulon, Dean Kennedy, Erika Sjoberg, Albert Andino, Robert Leboeuf,

  7. Microsoft Word - SAUUL_report_d

    National Nuclear Security Administration (NNSA)

    THE SCIENCE AND APPLICATIONS OF ULTRAFAST, ULTRAINTENSE LASERS: Opportunities in science and technology using the brightest light known to man A report on the SAUUL workshop held, June 17-19, 2002 THE SCIENCE AND APPLICATIONS OF ULTRAFAST, ULTRAINTENSE LASERS (SAUUL) A report on the SAUUL workshop, held in Washington DC, June 17-19, 2002 Workshop steering committee: Philip Bucksbaum (University of Michigan) Todd Ditmire (University of Texas) Louis DiMauro (Brookhaven National Laboratory) Joseph

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comparison of Ground-Based Millimeter-Wave Observations During RHUBC I Submitter: Cimini, D., CETEMPS - Dipartimento di Fisica Westwater, E. R., University of Colorado Payne, V., Jet Propulsion Laboratory/California Institute of Technology Turner, D. D., National Oceanic and Atmospheric Administration Mlawer, E. J., Atmospheric & Environmental Research, Inc. Exner, M., Radiometrics Corporation Cadeddu, M. P., Argonne National Laboratory Area of Research: Radiation Processes Working Group(s):

  9. General Observation Period 2007: Concept and first results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Orographically- induced Precipitation Study (COPS) AMF AMF Volker Wulfmeyer, Andreas Behrendt, and Hans-Stefan Bauer, University of Hohenheim Christoph Kottmeier and Ulrich Corsmeier, FZK Karlsruhe Gerhard Adrian, German Meteorological Service (DWD Alan Blyth, School of Environment, University of Leeds, UK George Craig, Ulrich Schumann, and Martin Hagen, DLR Susanne Crewell, University of Cologne Paolo Di Girolamo, Universita degli Studi della Basilicata, Potenza, Italy Cyrille Flamant,

  10. SMART Scale

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SMART Scale Small Market Advanced Retrofit Transformation Program 2014 Building Technologies Office Peer Review Colin Clark, CClark@ecoact.org ECOLOGY ACTION Project Summary Timeline:  Start date: October 1, 2013  Planned end date: September 30, 2016 Key Milestones :  June 2014: Research and develop list of measures needed to enhance Ecology !ction's DI 2.0 model to achieve an average of at least 20% energy savings  October 2014: Identification and Selection of Demonstration

  11. SMART Scale: Small Market Advanced Retrofit Transformation Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SMART Scale Small Market Advanced Retrofit Transformation Program 2015 Building Technologies Office Peer Review Colin Clark, CClark@ecoact.org ECOLOGY ACTION Project Summary Timeline:  Start date: October 1, 2013  Planned end date: September 30, 2016 Key Milestones :  June 2014: Research and develop list of measures needed to enhance Ecology !ction's DI 2.0 model to achieve an average of at least 20% energy savings  June 2015: Review of EM&V on completed projects showing an

  12. MEMORANDUM

    Office of Legacy Management (LM)

    .) ,' . .,. 3' 236 MEMORANDUM TO: FILE 22-- _____ FROM: TYPE OF OPERATION _____-------_---- x Research & Development 0 Facility Type 0 Production scale testing 0 Pilot Scale 0 Bench Scale Process 0 Theoretical Studies 0 s ample SC Analysis q ~ro%%i:;"t"' 0 Di reposal /Storage 0 Research Organization a Government Sponsored Facility q Other __I-----___--__---~~ TYPE OF CONTRACT ---------------- q Prime 0 Other information (i.e., cost 0 Subcontract& + fixed fee, unit price, _. 0

  13. FY 2012 Volume 7

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Volume 7 Department of Energy FY 2012 Congressional Budget Request Nuclear Energy D f N l W t Di l Defense Nuclear Waste Disposal Nuclear Waste Disposal February 2011 Office of Chief Financial Officer Volume 7 Printed with soy ink on recycled paper Department of Energy/ Volume 7 FY 2012 Congressional Budget Volume 7 Table of Contents Page Appropriation Account Summary ........................................................................................................... 3 Nuclear Energy

  14. Nanoparticles > Complex Oxides > Research > The Energy Materials Center at

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cornell Nanoparticles The nanoparticle synthesis efforts at EMC2 mostly take place in the Frank DiSalvo group, and focus on preparing useful fuel cell electrocatalysts in nanoparticle form. The research groups in EMC2 (formerly the Cornell Fuel Cell Institute) have discovered that bulk ordered intermetallic compounds- a class of solid materials that are made of multiple metals, but are not random alloys- show impressive resistance to poisoning as anode catalysts, and amazing activity for

  15. Research Highlights - Joint Center for Energy Storage Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights August 25, 2016, Research Highlights The Lightest Organic Radical Cation for Charge Storage in Redox Flow Batteries By systematically shedding molecular fragments of 2,5-di-tert-butyl-1,4-bis(2-methoxyethoxy)benzene that are considered important for radical cation steric stabilization, we discovered a minimalistic structure that retains long-term stability in its oxidized form and exhibits the intrinsic capacity of 161 mAh/g. Read More August 20, 2016, Research Highlights

  16. An Engine System Approach to Exhaust Waste Heat Recovery | Department of

    Broader source: Energy.gov (indexed) [DOE]

    HCCI and DI Engine Combustion | Department of Energy An adaptive multi-grid technique was used to group thermodynamically similar cells in order to reduce the calling frequency to the chemistry solver. deer08_shi.pdf (189.13 KB) More Documents & Publications Homogeneous Charge Compression Ignition (HCCI) R&D Diesel HCCI Results at Caterpillar Numerical Modeling of PCCI Combustion

    DOE Bioenergy Technologies Office 2015 Peer Review Biomass Cookstove Technology Review March 26, 2015

  17. XMCD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In optics, the term "dichroism" refers to changes in the absorption of polarized light on passing through a material in two different directions. Since materials typically absorb one color of white light preferentially, the material appears with two different colors for the two light directions - it is di- (two-) c hroic (colored). Today, the term dichroism is used more generally to reflect the dependence of photon absorption of a material on polarization. The origin of the dichroism

  18. Novel Stack Concepts: Patterned Aligned Carbon Nanotubes as Electrodes in MEAs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stack Concepts: Patterned Aligned Carbon Nanotubes as Electrodes in MEAs Di-Jia Liu Chemical Engineering Division Argonne National Laboratory Presentation at Fuel Cell Kickoff Meeting U. S. Department of Energy, Washington D. C. February 13-14, 2007 This presentation does not contain any proprietary or confidential information Objective „ To develop a novel aligned carbon nanotube (ACNT)-based membrane electrode assembly and fuel cell with: - improved efficiency - reduced Pt usage - simplified

  19. drbohlke | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Market Luciana Juvenal y Federal Reserve Bank of St. Louis Ivan Petrella z Birkbeck, University of London 26 June 2012 Abstract The run-up in oil prices since 2004 coincided with growing investment in commod- ity markets and increased price comovement among di¤erent commodities. We assess whether speculation in the oil market played a role in driving this salient empirical pattern. We identify oil shocks from a large dataset using a factor-augmented vector autoregressive (FAVAR) model. This

  20. Exploring the influence of transfer channels on fusion reactions: The case of 40 Ca + 58,64 Ni

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bourgin, D.; Courtin, S.; Haas, F.; Goasduff, A.; Stefanini, A. M.; Montagnoli, G.; Montanari, D.; Corradi, L.; Huiming, J.; Scarlassara, F.; et al

    2015-01-29

    Fusion cross sections have been measured in the 40Ca + 58Ni and 40Ca + 64Ni systems at beam energies ranging from Elab = 104.75 MeV to 153.5 MeV using the Laboratori Nazionali di Legnaro electrostatic deflector. Distributions of barriers have been extracted from the experimental data. Preliminary coupled channel calculations were performed and hints of effects of neutron transfers on the fusion below the barrier in the 40Ca + 64Ni are discussed.

  1. Working to keep us safe: Sara Brambilla, Postdoc creates threat reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tools Inspire » Working to keep us safe: Postdoc creates threat reduction tools Working to keep us safe: Sara Brambilla, Postdoc creates threat reduction tools Chemical engineer postdoc experiences a foreign culture while working on resources that respond to weapons of mass destruction and natural threats. July 18, 2012 image description Brambilla first came to Los Alamos as a visiting student during her PhD program at the Politecnico di Milano, Italy, which required an internship abroad.

  2. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NASA/GSFC Scanning Raman Lidar Participation in WVIOP2000 and AFWEX D. N. Whiteman, B. B. Demoz, and K. D. Evans, National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland P. Di Girolamo and D. O'C. Starr, Department of Environmental Engineering and Physics University of Basilicata Potenza, Italy T. Berkoff Goddard Earth Sciences and Technology Center University of Maryland Balitmore, Maryland J. E. M. Goldsmith and T. P. Tooman Sandia National Laboratories

  3. Actinide-lanthanide separation with solvents on the base of amides of heterocyclic diacids

    SciTech Connect (OSTI)

    Babain, V.A.; Alyapyshev, M.Y.; Tkachenko, L.I.

    2013-07-01

    The separation of actinides from lanthanides with a particular emphasis on Am(III) from Eu(III) with amides of heterocyclic dicarboxylic diacids was reviewed. It was shown that the di-amides of the 2,2'-dipyridyl-6,6'-dicarboxylic acid are the most promising ligands for the simultaneous selective recovery of actinides from HLLW (high level radioactive liquid waste) within the GANEX concept. (author)

  4. SEPARATION OF RARE EARTHS BY SOLVENT EXTRACTION

    DOE Patents [OSTI]

    Peppard, D.F.; Mason, G.W.

    1960-10-11

    A process is given for separating lanthanide rare earths from each other from an aqueous mineral acid solution, e.g., hydrochloric or nitric acid of a concentration of above 3 M, preferably 12 to 16 M, by extraction with a water- immiscible alkyl phosphate, such as tributyl phosphate or a mixture of mono-, di- and tributyl phosphate, and fractional back-extraction with mineral acid whereby the lanthanides are taken up by the acid in the order of increasing atomic number.

  5. Transportation Efficiency Strategies

    U.S. Energy Information Administration (EIA) Indexed Site

    Advanced Technology Vehicles: Overview and Constraints John German, ICCT EIA Energy Conference April 26, 2011 Where Does the Energy Go? http://www.fueleconomy.gov/FEG/atv.shtml Friction reduction Cylinder deactivation DI turbo Aero, tires Variable valves weight High efficient gasoline engine Clean diesel HEV expansion Base engine and vehicle improvements Efficiency/CO2 reduction EV/FCV development for future Fleet tests Research for mass production HCCI No single solution - multi-pronged

  6. Production of high molecular weight polylactic acid

    DOE Patents [OSTI]

    Bonsignore, Patrick V.

    1995-01-01

    A degradable high molecular weight poly(lactic acid). A poly(lactic acid) has a terminal end group of one of carboxyl or hydroxyl groups with low molecular weight poly(lactic acid) units coupled with linking agents of di-isocyanates, bis-epoxides, bis-oxazolines and bis-ortho esters. The resulting high molecular weight poly(lactic acid) can be used for applications taking advantage of the improved physical properties.

  7. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conceptual Model of DI Diesel Combustion Based on Laser-Sheet Imaging admin 2016-04-18T20:58:24+00:00 Popular Downloads Solar Energy Grid Integration Systems: Final Report of the Florida Solar Energy Center Team (11368 downloads) Modeling System Losses in PVsyst (9346 downloads) Numerical Manufacturing And Design Tool (NuMAD v2.0) for Wind Turbine Blades: User's Guide (7614 downloads) Solar Energy Grid Integration Systems (SEGIS) Proactive Intelligent Advances for Photovoltaic Systems (6676

  8. Production of high molecular weight polylactic acid

    DOE Patents [OSTI]

    Bonsignore, P.V.

    1995-11-28

    A degradable high molecular weight poly(lactic acid) is described. The poly(lactic acid) has a terminal end group of one of carboxyl or hydroxyl groups with low molecular weight poly(lactic acid) units coupled with linking agents of di-isocyanates, bis-epoxides, bis-oxazolines and bis-ortho esters. The resulting high molecular weight poly(lactic acid) can be used for applications taking advantage of the improved physical properties.

  9. A Lewis Acid-free and Phenolate-based Magnesium Electrolyte for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Magnesium Batteries - Joint Center for Energy Storage Research March 2, 2015, Research Highlights A Lewis Acid-free and Phenolate-based Magnesium Electrolyte for Rechargeable Magnesium Batteries X-ray single crystal isolated from the electrolyte containing the prototype [Mg2Cl3(THF)6]+ cation Scientific Achievement A novel Lewis acid-free all magnesium electrolyte containing 2,6-di-tert-butylphenoxidemagnesium chloride ((DTBP)MgCl + MgCl2) has been deliberately developed. The

  10. The confinement effect on the activity of Au NPs in polyols oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Villa, Alberto; Wang, Di; Chan-Thaw, Carine E.; Campisi, Sebastiano; Veith, Gabriel M; Vahlas, Constantin

    2016-01-01

    We demonstrate a confinement effect where gold nanoparticles trapped within N-functionalized carbon nanofibers (N-CNFs) are more active for polyol oxidation and promote selectivity towards di-acid products, whereas AuNPs trapped on the surface produce as a major by-product the one derived from C C cleavage. The behaviour of NPs confined inside the N-CNF channels can be attributed to a different, possibly multiple, coordination of glycerol on the active site

  11. Microsoft Word - Appendix G.doc

    Office of Legacy Management (LM)

    09 are included in this appendix. Appendix G, Page 1 RFLMA Contact Record 2009-01 1 of 5 ROCKY FLATS SITE REGULATORY CONTACT RECORD Purpose: Phase II and III Upgrades to Solar Ponds Plume Treatment System Contact Record Approval Date: February 17, 2009 Site Contact(s) / Affiliation(s): Scott Surovchak / DOE; Linda Kaiser / Stoller; Rick DiSalvo / Stoller; John Boylan / Stoller Regulatory Contact(s) / Affiliation(s): Carl Spreng / CDPHE Discussion: As approved in Rocky Flats Legacy Management

  12. Microsoft Word - RFOLF Yearly Report - 2013_TAC

    Office of Legacy Management (LM)

    801 Automation Way Suite 100 Fort Collins CO 80525 Tel 970.223.9600 Fax 970.223.7171 www.tetratech.com Technical Memorandum To: Mr. Rick DiSalvo From: Lance Heyer, EI Thomas A. Chapel, PE Company: S. M. Stoller Corporation Date: March 29, 2013 Re: Instrumentation and Monitoring, Rocky Flats OLF Tt Project #: 114-181750 Introduction This technical memorandum provides a summary and evaluation of data collected from inclinometer and piezometer instrumentation at the Rocky Flats Original Landfill

  13. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    Listings and Photos of Monitoring Wells and Seeps This page intentionally left blank U.S. Department of Energy Annual Assessment of the Effectiveness of Site-Wide Institutional Controls June 2011 Doc. No. S07757 Page D-i Contents 1.0 Parcel 6, 7, and 8 Remedy Wells and Seeps ..................................................................... D-1 2.0 OU-1 (Parcel 9) Wells ....................................................................................................... D-6 3.0 Phase I

  14. Microsoft PowerPoint - TFG Nov 2015.pptx

    Office of Environmental Management (EM)

    What we have seen from these Visiting Speaker Programs is an opportunity for ll b ti Th l tt di HSS Visiting Speaker Program - September 18, 2008. Washington DC collaboration. The people attending are representative of organizations investing their time and they too are struggling to solve the same issues we are ; to keep America sustainable, secure, and to foster responsible leadership. Companies have been successful preparing for and navigating this new shifting global landscape." Index

  15. Microsoft Word - TWG Mtg 8-11-11-FINAL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 11, 2011 at 2 p.m. Present: Richard Arnold, Tribal Representative Kathy Bienenstein, Nevada Site Specific Advisory Board Nohemi Brewer, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) Frank Di Sanza, NNSA/NSO Sandy Enyeart, Science Applications International Corporation Randy Fultz, City of Las Vegas Syd Gordon, National Security Technologies Cash Jaszczak, Nye County Nuclear Waste Repository Project Office Lt. Lisa Lewis, State of Nevada Highway Patrol Commercial

  16. draft41.pdf

    Gasoline and Diesel Fuel Update (EIA)

    Market Luciana Juvenal y Federal Reserve Bank of St. Louis Ivan Petrella z Birkbeck, University of London 26 June 2012 Abstract The run-up in oil prices since 2004 coincided with growing investment in commod- ity markets and increased price comovement among di¤erent commodities. We assess whether speculation in the oil market played a role in driving this salient empirical pattern. We identify oil shocks from a large dataset using a factor-augmented vector autoregressive (FAVAR) model. This

  17. Method for cleaning solution used in nuclear fuel reprocessing

    DOE Patents [OSTI]

    Tallent, O.K.; Crouse, D.J.; Mailen, J.C.

    1980-12-17

    Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

  18. WORKING GROUP PRESENTATION FOR DISCUSSION PURPOSES. DO NOT QUOTE OR CITE AS AEO2016

    U.S. Energy Information Administration (EIA) Indexed Site

    March 10, 2016 MEMORANDUM TO: John Conti Assistant Administrator for Energy Analysis Jim Diefenderfer Director, Office of Electricity, Coal, Nuclear, and Renewables Analysis FROM: Coal and Uranium Analysis Team SUBJECT: Notes from the Second AEO2016 Coal Working Group Meeting workshop held on February 9, 2016 Attendees (30) Name Affiliation Adams, Greg U.S. DOE: EIA Coleman, Leslie National Mining Association Diefenderfer, Jim U.S. DOE: EIA DiGiantommaso, Jennifer U.S. Department of Labor

  19. Microsoft PowerPoint - Horst Simon.BitstoBuidings2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficient Computing: From Bits to Energy Efficient Computing: From Bits to Buildings Horst D. Simon Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory and EECS Dept., UC Berkeley hdsimon@lbl.gov The Salishan Conference on High-Speed Computing April 29, 2009 Acknowledgements A l b f i di id l h t ib t d t A large number of individuals have contributed to energy efficiency in computing at Berkeley Lab, UC Berkeley, and to this presentation: David Bailey (CRD), Michael

  20. Joint Center for Energy Storage Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 25, 2016, Research Highlights The Lightest Organic Radical Cation for Charge Storage in Redox Flow Batteries By systematically shedding molecular fragments of 2,5-di-tert-butyl-1,4-bis(2-methoxyethoxy)benzene that are considered important for radical cation steric stabilization, we discovered a minimalistic structure that retains long-term stability in its oxidized form and exhibits the intrinsic capacity of 161 mAh/g. Read More August 24, 2016, Videos Sparingly Solvating Electrolytes

  1. INSTITUTE COLLOQUIA AND SEMINARS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-March 31, 2002 2001 April 10 Dr. Massimo Di Toro, LNS/INFN and the University of Catania, Italy Isospin Effects on Nuclear Dynamics April 12 Dr. C. Lewis, U.S. Environmental Protection Agency, Research Triangle, North Carolina Air Pollution Research Using Radiocarbon Measurements April 17 Professor Olga Kocharovskaya, Department of Physics, Texas A&M University, College Station, Texas Laser Control of Mossbauer Nuclear Transitions May 1 Dr. Bency John, Cyclotron Institute, Texas A&M

  2. hagan-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerobot-based Measurements of the Profile of Downwelling Shortwave Irradiance D. Hagan, J.-F. Blavier, and D. Crisp Jet Propulsion Laboratory California Institute of Technology Pasadena, California L. Di Girolamo University of Chicago Chicago, Illinois T. P. Ackerman The Pennsylvania State University College Park, Pennsylvania Summary Using a helium plus reversible fluid balloon system as the observing platform, multiple profiles of shortwave irradi- ance between 4 km and 10 km were recently

  3. wcicomp_012306.dvi

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deducing the nuclear matter incompressibility coefficient from data on isoscalar compression modes S. Shlomo 1 , V. M. Kolomietz 2 , and G. Col` o 3 1 Cyclotron Institute, Texas A&M University, College Station, Texas 77843, USA 2 Institut for Nuclear Research, 03680 Kiev, Ukraine 3 Dipartimento di Fisica, Universit` a degli Studi, and INFN, via Celoria 16, 20133 Milano, Italy Received: date / Revised version: date Abstract. Accurate assessment of the value of the incompressibility

  4. The Easy Way to Use Renewables: Buy Clean Electricity | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy UNIVERSITY OF MASSACHUSETTS LOWELL</strong> Back row: Isaac Grulon, Dean Kennedy, Erika Sjoberg, Albert Andino, Robert Leboeuf, Gregory Lennartz, Michael Dube. Middle row: David Phung, Jigar Patel, Alexandre Sampaio, Patrick Logan, Jeffrey Chung, Peter Jones. Front row: Parth Patel, Donna DiBattista, Meaghan Riley, Michael Schaefer. Not pictured: Christopher Daly, Erik Anderson. Credit: David Willis UNIVERSITY OF MASSACHUSETTS LOWELL Back row: Isaac Grulon, Dean

  5. University of Massachusetts Lowell 2014 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Back row: Isaac Grulon, Dean Kennedy, Erika Sjoberg, Albert Andino, Robert Leboeuf, Gregory Lennartz, Michael Dube. Middle row: David Phung, Jigar Patel, Alexandre Sampaio, Patrick Logan, Jeffrey Chung, Peter Jones. Front row: Parth Patel, Donna DiBattista, Meaghan Riley, Michael Schaefer. Not pictured: Christopher Daly, Erik Anderson. Photo by David Willis. Back row: Isaac Grulon, Dean Kennedy, Erika Sjoberg, Albert Andino, Robert Leboeuf, Gregory Lennartz, Michael Dube. Middle row: David

  6. Quality problems in waters used for drinking purposes in Italy

    SciTech Connect (OSTI)

    Funari, E.; Bastone, A.; Bottoni, P.; De Donno, D.; Donati, L. )

    1991-12-01

    With a grant from the Italian Ministry of the Environment, the National Institute of Health (Istituto Superiore di Sanita) promoted and coordinated some activities aimed at determining the extent and the intensity of contamination of waters used for human consumption by some chemical agents, and describing causes and modalities of contamination and human health implications. The chemical agents examined were herbicides, nitrates, trihalomethanes, asbestos, manganese and fluoride. In this paper a first nationwide picture of these problems is reported.

  7. Quantitative NMR Analysis of Partially Substituted Biodiesel Glycerols

    SciTech Connect (OSTI)

    Nagy, M.; Alleman, T. L.; Dyer, T.; Ragauskas, A. J.

    2009-01-01

    Phosphitylation of hydroxyl groups in biodiesel samples with 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane followed by 31P-NMR analysis provides a rapid quantitative analytical technique for the determination of substitution patterns on partially esterified glycerols. The unique 31P-NMR chemical shift data was established with a series mono and di-substituted fatty acid esters of glycerol and then utilized to characterize an industrial sample of partially processed biodiesel.

  8. Advantage, Absence of Advantage, and Disadvantage Among Scientists and Engineers

    SciTech Connect (OSTI)

    Nancy DiTomaso

    2008-09-23

    DiTomaso talks about survey data on the career experiences of 3,200 scientists and engineers from 24 major companies. Her survey findings indicate that most people who do well in their careers and make significant contributions to their organizations get assistance from others in their workplace in many forms, including offering opportunities such as good projects, providing resources that make good performance more likely, and opening up networking possibilities.

  9. Partial Acceptance for Beneficial Use (ABU) for the Type 4 In Situ Vapor Sampler (ISVS) Carts

    SciTech Connect (OSTI)

    BOGER, R.M.

    2000-05-19

    This document provides the Acceptance for Beneficial Use (ABU) for the Type 4 in-situ vapor sampler (ISVS) system. This document is generated to support the completion of equipment modifications and engineering documentation for the ISVS system that is used for sampling gaseous vapors in the Hanford single shell radioactive waste storage tanks. This ABU documents items for transferring the ISVS system to operations for field use. This document is generated following Characterization Engineering Desk Instruction DI-CE-004-001.

  10. Method for cleaning solution used in nuclear fuel reprocessing

    DOE Patents [OSTI]

    Tallent, Othar K. (Oak Ridge, TN); Crouse, David J. (Oak Ridge, TN); Mailen, James C. (Oak Ridge, TN)

    1982-01-01

    Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

  11. Development of a hybrid deterministic/stochastic method for 1D nuclear reactor kinetics

    SciTech Connect (OSTI)

    Terlizzi, Stefano; Dulla, Sandra; Ravetto, Piero; Rahnema, Farzad; Zhang, Dingkang

    2015-12-31

    A new method has been implemented for solving the time-dependent neutron transport equation efficiently and accurately. This is accomplished by coupling the hybrid stochastic-deterministic steady-state coarse-mesh radiation transport (COMET) method [1,2] with the new predictor-corrector quasi-static method (PCQM) developed at Politecnico di Torino [3]. In this paper, the coupled method is implemented and tested in 1D slab geometry.

  12. Electron impact and chemical ionization mass spectral analysis of a volatile uranyl derivative

    SciTech Connect (OSTI)

    Reutter, D.J.; Hardy, D.R.

    1981-01-01

    Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope /sup 235/U//sup 238/U abundance is demonstrated.

  13. Removal of aqueous rinsable flux residues in a batch spray dishwater

    SciTech Connect (OSTI)

    Slanina, J.T.

    1992-02-01

    An alkaline detergent solution used in an industrial dishwasher was evaluated to remove aqueous rinsable flux residues on printed wiring boards (PWBs) after hot air solder leveling and hot oil solder dip and leveling. The dishwasher, a batch cleaning process, was compared to an existing conveyorized aqueous cleaning process. The aqueous soluble flux residues from both soldering processes were removed with a solution of a mild alkaline detergent dissolved in hot deionized (DI) water.

  14. Chronic toxicity of 14 phthalate esters to Daphnia magna and rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Rhodes, J.E.; Adams, W.J.; Biddinger, G.R.; Robillard, K.A.; Gorsuch, J.W.

    1995-11-01

    Chronic toxicity studies were performed with commercial phthalate esters and Daphnia magna (14 phthalates) and rainbow trout (Oncorhynchus mykiss) (six phthalates). For the lower-molecular-weight phthalate esters--dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), and butylbenzyl phthalate (BBP)--the results of the studies indicated a general trend in which toxicity for both species increased as water solubility decreased. The geometric mean maximum acceptable toxicant concentration(GM-MATC) for D. magna ranged from 0.63 to 34.8 mg/L. For the higher-molecular-weight phthalate esters--dihexyl phthalate (DHP), butyl 2-ethylhexyl phthalate (BOP), di-(n-hexyl, n-octyl, n-decyl) phthalate (610P), di-(2-ethylhexyl) phthalate (DEHP), diisooctyl phthalate (DIOP), diisononyl phthalate (DINP), di-(heptyl, nonyl, undecyl) phthalate (711P), diisodecyl phthalate (DIDP), diundecyl phthalate (DUP), and ditridecyl phthalate (DTDP)--the GM-MATC values ranged from 0.042 to 0.15 mg/L. Survival was equally sensitive and sometimes more sensitive than reproduction. The observed toxicity to daphnids with most of the higher-molecular-weight phthalate esters appeared to be due to surface entrapment or a mode of toxicity that is not due to exposure to dissolved aqueous-phase chemical. Early life-stage toxicity studies with rainbow trout indicated that survival (DMP) and growth (DBP) were affected at 24 and 0.19 mg/L, respectively. This pattern of observed toxicity with the lower-molecular-weight phthalate esters and not the higher-molecular-weight phthalate esters is consistent with previously reported acute toxicity studies for several aquatic species.

  15. Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results 2003 DEER Conference Presentation: The Ohio State University 2003_deer_rizzoni.pdf (987.99 KB) More Documents & Publications Diesel HCCI with External Mixture Preparation Gasoline-like fuel effects on advanced combustion regimes A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer

  16. University of Massachusetts Lowell: Business Plan

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEPARTMENT O F E NERGY (DOE) COLLEGIATE WIND COMPETITION UNIVERSITY OF MASSACHUSETTS LOWELL Dean Kennedy Christopher Daly Donna DiBattista Michael Dube Michael Schaefer Erika S jöberg Erik Anderson Parth Patel Peter Jones Meaghan Riley David Phung Jeffrey Chung Patrick Logan Alexandre Sampaio Albert Andino Isaac Grullon Jigar P atel Kristin Morrissey Bobby LeBoeuf Gregory Lennartz David Willis Christopher Hansen Christopher Niezrecki Jack Wilson Stephen Johnston Yi Yang Ziyad Salameh Wind

  17. Observation of gravity decays of multiple-neutron nuclei during cold fusion

    SciTech Connect (OSTI)

    Matsumoto, T. . Dept. of Nuclear Engineering)

    1992-08-01

    The Nattoh model predicted that multiple-neutron nuclei such as quad-neutrons can be produced during cold fusion, and the gravity decays of the quad-neutrons were recorded on nuclear emulsions. Several different traces that might be produced by the gravity decays of di-neutron and multiple-neutron nuclei have been successfully observed. The mechanisms of the production of multiple-neutron nuclei are discussed in this paper.

  18. Chief, SF Eaterials

    Office of Legacy Management (LM)

    c. Yolmge, Jr., Chief, SF Eaterials January i0, 39501 Aooountability B.-oh, (Bk Ridge J. P. Morgan, Assistant Mreotor, Produotion DiViEiOn, New York Operations Office ACCOUNTABILITY AT MARXITB COMPANY SYMBOL: PMsSO ;< \.' It is Stations, the following new station be listed: Station Symbol MXC OrganiEation Addreae &farHts Co. 166 Rhverly Pl Janloe A. Cutlei .Non York 14, N.Y. ; ' :.' :., 1, ,, : ,, . . . . . . .:

  19. Current:

    Office of Legacy Management (LM)

    Qwner contacted n yes Current: ---------------------L---- if yes, date contacted Research & Development cl Facility Type 0 . Productioff 0 Di 3pcsal /Storage TYPE OF CONTRACT ---------------- q Prime q Subcontractor 0 Purchase Order 0 Other information (i.e. q cast + fixed fee, unit piice, time & material, etr) ------- ------_-----_--------------- 0 Production scale testing 0 Pilot Scale 0 Bench Scale Process a Theoretical Studies Sample & Analysis rcc t O' L~1 q Manufacturing 0

  20. I

    Office of Legacy Management (LM)

    OWNES (S) I ----L--- p=t:-~~~~-~~~~--~ Fcrva ___ current: -------------------------- Owner contacted 13 yes if yes, date contacted 0 Facility Type TYPE OF OPERATION ----------------- f-J Research & Development 0 Production scale testing 0 Pilot Scale 0 Bench Scale Process 0 Thearetical Studies 0 Sample & Analysis 0 Production 0 Di3poeal/Storage TYPE'OF CONTRACT ---------------- q Mapufacturing q University 0 Research Organization / 0 Government Sponsored Facility 0 Prime 0 Subcontractor

  1. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations p-21_ramirez.pdf (351.23 KB) More Documents & Publications HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Characterization of Dual-Fuel

  2. House II Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 MIN PRESENTATION U.s. Department of energy race to Zero 2016 stUDent Design competition philaDelphia University team emergence None of our success would have been possible without the countless hours, energy and resources the following people have contributed: John Hubert, Matt Otricelli, Shawn Connell, Vince Lombardi, Andrew Hart, Joe Andracchio, Nicholas D'Ottavio, Bob Tracy, Don DiValerio, Ron Celentano, Barbara Klinkhammer, James Dorefler, Terry Ryan, Sara Miller TEAM PROFILE

  3. Data-Intensive Memory-Map simulator and runtime

    Energy Science and Technology Software Center (OSTI)

    2012-05-01

    DI-MMAP is a simulator for modeling the performance of next generation non-volatile random access memory technologies (NVRAM) and a high-perfromance memory-map runtime for the Linux operating system. It is implemented as a device driver for the Linux operating system. It will be used by algorithm designers to unserstand the impact of future NVRAM on their algorithms and will be used by application developers for high-performance access to NVRAM storage.

  4. Solvent Modification in Ion-Pair Extraction: Effect on Sodium Nitrate Transport in Nitrobenzene Using a Crown Ether

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.

    2005-10-31

    A comparative quantitative analysis of the effect of solvent modifiers on an ion-pair extraction of an inorganic salt by a crown ether was conducted. Two classes of the solvent modifiers that possess electron-pair donor (EPD) or hydrogen-bond donor (HBD) groups were investigated. The equilibrium constants corresponding to the extraction of sodium nitrate into nitrobenzene (NB) employing model neutral host cis-syn-cis-dicyclohexano-18-crown-6 (1) with and without solvent modifier were determined using the SXLSQI computer model. For a series of EPD modifiers—including tri-n-butyl- and tri-phenylphosphate, tri-n-butyl- and tri-phenylphosphine oxide, N,N-di-n-butyl- and N,N-di-phenyl acetamide—the enhancement of the NaNO3 extraction by 1 was found to be dependent on the hydrogen-bond acceptance ability of the modifier quantified by the b solvatochromic parameter. Application of the solvent EPD modifier improved solvation of the sodium ion, lowering the large energy barrier of Na+ partitioning into the extraction phase. A HBD modifier 3,5-di-t-butylphenol 8 that forms strong hydrogen bonds with nitrate anion in NB, exhibited even greater enhancement of the NaNO3 extraction by 1. The determined extraction constants were correlated with the b or a solvatochromic parameters of the solvent modifiers and linear trends were observed. Hydrogen bond interaction between 3,5-di-t-butylphenol 8 and nitrate anion in the presence of the sodium-loaded crown ether in the extraction phases was studied by vibrational spectroscopy. Formation of the simple 1:1 adduct was demonstrated.

  5. On the Site-Decomposition of Magnetocrystalline Anisotropy Energy Using Ome-Electron Eigenstates

    SciTech Connect (OSTI)

    Aberg, Daniel; Sadigh, Babak; Benedict, Lorin X.

    2015-10-26

    We discuss two di erent schemes for decomposing the magnetocrystalline anisotropy energy into atomic site-speci c contributions, and show that one of these, which uses projected single-particle states, is inherently ill-de ned in practical applications. We therefore argue that the other decomposition scheme, involving ground state matrix elements of the spin-orbit operator, is preferable for the numerical prediction of one-site contributions to the anisotropy.

  6. Effect Of Preparation Methods On The Performance Of Co/Al2O3 Catalysts For Dry Reforming Of Methane

    SciTech Connect (OSTI)

    Ewbank, Jessica L.; Kovarik, Libor; Kenvin, Christian C.; Sievers, Carsten

    2014-01-06

    Two methods, dry impregnation (DI) and controlled adsorption (CA), are used for the preparation of Co/ Al2O3 catalysts for methane dry reforming reactions. Point of zero charge (PZC) measurements, pH-precipitation studies, and adsorption isotherms are used to develop a synthesis procedure in which deposition of Co2+ takes place in a more controlled manner than metal deposition during drying in synthesis by dry impregnation. The possible adsorption phenomena that occur during preparation of Co/Al2O3 catalysts by controlled adsorption are discussed. H2 chemisorption and TEM show that catalysts prepared by CA have smaller average particle sizes and higher dispersions. TPR studies show that for the sample prepared by CA a higher amount of cobalt is reduced to its metallic state and that more CoAl2O4 spinel species are present relative to DI samples. The catalyst prepared by CA shows higher activity and slower deactivation for methane dry reforming than the catalyst prepared by DI. XPS and C, H, N analysis on spent catalysts confirm two types of carbonaceous deposits are formed depending on the preparation method.

  7. Biochemical, Mechanistic, and Spectroscopic Characterization of Metallo-β-lactamase VIM-2

    SciTech Connect (OSTI)

    Aitha, Mahesh; Marts, Amy R.; Bergstrom, Alex; Møller, Abraham Jon; Moritz, Lindsay; Turner, Lucien; Nix, Jay C.; Bonomo, Robert A.; Page, Richard C.; Tierney, David L.; Crowder, Michael W.

    2014-11-25

    Our study examines metal binding to metallo-β-lactamase VIM-2, demonstrating the first successful preparation of a Co(II)-substituted VIM-2 analogue. Spectroscopic studies of the half- and fully metal loaded enzymes show that both Zn(II) and Co(II) bind cooperatively, where the major species present, regardless of stoichiometry, are apo- and di-Zn (or di-Co) enzymes. We also determined the di-Zn VIM-2 structure to a resolution of 1.55 Å, and this structure supports results from spectroscopic studies. Kinetics, both steady-state and pre-steady-state, show that VIM-2 utilizes a mechanism that proceeds through a very short-lived anionic intermediate when chromacef is used as the substrate. Comparison with other B1 enzymes shows that those that bind Zn(II) cooperatively are better poised to protonate the intermediate on its formation, compared to those that bind Zn(II) non-cooperatively, which uniformly build up substantial amounts of the intermediate.

  8. Pseudo-hydroxide extraction in the separation of sodium hydroxide from aqueous solutions using alkyl phenols

    SciTech Connect (OSTI)

    Kang, Hyun Ah; Moyer, Bruce A

    2006-01-01

    Pseudo-hydroxide extraction of sodium hydroxide from aqueous solution using four alkyl phenols of nearly identical molecular weight in 1-octanol at 25 degrees C was examined to understand the effect of alkyl substituents. The order of extraction strength among the four alkyl phenols tested was 4-tert-octylphenol. 3,5-di-tertbutylphenol. 2,4-di-tert-butylphenol. 2,6-di-tert-butyl-4-methylphenol. A good correlation with phenol pK(a) was observed, indicating that extraction strength is determined by phenol acidity, as modified by steric effects in proximity to the phenol - OH group. The effective partition ratios (P-eff) of two phenols from 1 M NaOH solution were determined, showing that the phenols remain predominantly in the 1-octanol phase even when converted to their sodium salts. However, the hydrophobicity of the tested phenols may not be sufficient for process purposes. The equilibrium constants for the governing extraction equilibria were determined by modeling the data using the program SXLSQI, supporting the cation-exchange extraction mechanism. The proposed mechanism consists of two simple sets of equilibria for a. Ion-pair extraction to give Na+OH- ion pairs and corresponding free ions in 1-octanol the phase and b. Cation exchange by monomeric phenol molecules (HAs) to form monomeric organic-phase Na(+)A(-) ion pairs and corresponding free organic-phase ions.

  9. From ZZ to ZH : How Low Can These Cross Sections Go or Everybody, Let's Cross Section Limbo!

    SciTech Connect (OSTI)

    Strauss, Emanuel Alexandre; /SUNY, Stony Brook

    2009-08-01

    We report on two searches performed at the D0 detector at the Fermi National Laboratory. The first is a search for Z di-boson production with a theoretical cross section of 1.4 pb. The search was performed on 2.6 fb{sup -1} of data and contributed to the first observation of ZZ production at a hadron collider. The second is a search for a low mass Standard Model Higgs in 4.2 fb{sup -1} of data. The Higgs boson is produced in association with a Z boson where the Higgs decays hadronically and the Z decays to two leptons. The ZZ search was performed in both the di-electron and di-muon channels. For the ZH search, we will focus on the muonic decays where we expanded the traditional coverage by considering events in which one of the two muons fails the selection requirement, and is instead reconstructed as an isolated track. We consider Higgs masses between 100 and 150 GeV, with theoretical cross sections ranging from 0.17 to 0.042 pb, and set upper limits on the ZH production cross-section at 95% confidence level.

  10. The Optimization of an Ionic Liquid-Based TALSPEAK-Like Process for Rare Earth Ions Separation

    SciTech Connect (OSTI)

    Dai, Sheng; Sun, Xiaoqi; Luo, Huimin

    2014-01-01

    Five new functionalized ionic liquids (FILs), tetraethylammonium di(2-ethylhexyl)phosphate ([N2222][DEHP]), tetraethylammonium bis(2,4,4-trimethylpentyl)phosphinite ([N2222][BTMPP]), tetraethylammonium bis(2,4,4-trimethylpentyl)dithiophosphinite ([N2222][BTMPDTP]), tetrahexylammonium di(2-ethylhexyl)phosphate ([N6666][DEHP]), and tetraoctylammonium di(2-ethylhexyl)phosphate ([N8888][DEHP]) were synthesized and characterized. These ILs along with two previously synthesized FILs ([N4444][DEHP] & [N1888][DEHP]) were used as ionic extractants and investigated for rare earth elements (REEs) separation in 1-decyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide/bis(perfluoroethanesulfonyl)imide ([C10mim][NTf2]/[BETI]). These FILs as ionic extractants were miscible with [C10mim][NTf2]/[BETI]. We herein report the applications of these FILs in an IL-based TALSPEAK-like process and the optimization of the process by adjusting the cations and anions of the FILs, concentrations of the FILs as ionic extractants in the IL phase, concentrations of diethylenetriamine pentaacetic acid (DTPA) in the aqueous phase, and acidities of the aqueous phase.

  11. hhjj production at the LHC

    SciTech Connect (OSTI)

    Dolan, Matthew J.; Englert, Christoph; Greiner, Nicolas; Nordstrom, Karl; Spannowsky, Michael

    2015-08-25

    The search for di-Higgs production at the LHC in order to set limits on the Higgs trilinear coupling and constraints on new physics is one of the main motivations for the LHC high-luminosity phase. Recent experimental analyses suggest that such analyses will only be successful if information from a range of channels is included. We therefore investigate di-Higgs production in association with two hadronic jets and give a detailed discussion of both the gluon- and the weak boson-fusion (WBF) contributions, with a particular emphasis on the phenomenology with modified Higgs trilinear and quartic gauge couplings. We perform a detailed investigation of the full hadronic final state and find that hhjj production should add sensitivity to a di-Higgs search combination at the HL-LHC with 3 ab-1. Since the WBF and GF contributions are sensitive to different sources of physics beyond the Standard Model, we devise search strategies to disentangle and isolate these production modes. In addition, while gluon fusion remains non-negligible in WBF-type selections, sizeable new physics contributions to the latter can still be constrained. As an example of the latter point we investigate the sensitivity that can be obtained for a measurement of the quartic Higgs–gauge boson couplings.

  12. hhjj production at the LHC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dolan, Matthew J.; Englert, Christoph; Greiner, Nicolas; Nordstrom, Karl; Spannowsky, Michael

    2015-08-25

    The search for di-Higgs production at the LHC in order to set limits on the Higgs trilinear coupling and constraints on new physics is one of the main motivations for the LHC high-luminosity phase. Recent experimental analyses suggest that such analyses will only be successful if information from a range of channels is included. We therefore investigate di-Higgs production in association with two hadronic jets and give a detailed discussion of both the gluon- and the weak boson-fusion (WBF) contributions, with a particular emphasis on the phenomenology with modified Higgs trilinear and quartic gauge couplings. We perform a detailed investigationmore » of the full hadronic final state and find that hhjj production should add sensitivity to a di-Higgs search combination at the HL-LHC with 3 ab-1. Since the WBF and GF contributions are sensitive to different sources of physics beyond the Standard Model, we devise search strategies to disentangle and isolate these production modes. In addition, while gluon fusion remains non-negligible in WBF-type selections, sizeable new physics contributions to the latter can still be constrained. As an example of the latter point we investigate the sensitivity that can be obtained for a measurement of the quartic Higgs–gauge boson couplings.« less

  13. SU-E-I-59: Image Quality and Dose Measurement for Partial Cone-Beam CT

    SciTech Connect (OSTI)

    Abouei, E; Ford, N

    2014-06-01

    Purpose: To characterize performance of cone beam CT (CBCT) used in dentistry investigating quantitatively the image quality and radiation dose during dental CBCT over different settings for partial rotation of the x-ray tube. Methods: Image quality and dose measurements were done on a variable field of view (FOV) dental CBCT (Carestream 9300). X-ray parameters for clinical settings were adjustable for 210 mA, 6090 kVp, and two optional voxel size values, but time was fixed for each FOV. Image quality was assessed by scanning cylindrical poly-methyl methacrylate (PMMA) image quality phantom (SEDENTEXCT IQ), and then the images were analyzed using ImageJ to calculate image quality parameters such as noise, uniformity, and contrast to noise ratio (CNR). A protocol proposed by SEDENTEXCT, dose index 1 (DI1), was applied to dose measurements obtained using a thimble ionization chamber and cylindrical PMMA dose index phantom (SEDENTEXCT DI). Dose distributions were obtained using Gafchromic film. The phantoms were positioned in the FOV to imitate a clinical positioning. Results: The image noise was 612.5% which, when normalized to the difference of mean voxel value of PMMA and air, was comparable between different FOVs. Uniformity was 93.5 99.7% across the images. CNR was 1.74.2 and 6.314.3 for LDPE and Aluminum, respectively. Dose distributions were symmetric about the rotation angle's bisector. For large and medium FOVs at 4 mA and 8090 kVp, DI1 values were in the range of 1.263.23 mGy. DI1 values were between 1.011.93 mGy for small FOV (55 cm{sup 2}) at 45 mA and 7584 kVp. Conclusion: Noise decreased by increasing kVp, and the CNR increased for each FOV. When FOV size increased, image noise increased and CNR decreased. DI1 values were increased by increasing tube current (mA), tube voltage (kVp), and/or FOV. Funding for this project from NSERC Discovery grant, UBC Faculty of Dentistry Research Equipment Grant and UBC Faculty of Dentistry S. Wah Leung

  14. Renewable source controls for grid stability.

    SciTech Connect (OSTI)

    Byrne, Raymond Harry; Elliott, Ryan Thomas; Neely, Jason C.; Silva Monroy, Cesar Augusto; Schoenwald, David Alan; Grant, Lisa

    2012-12-01

    The goal of this study was to evaluate the small signal and transient stability of the Western Electric- ity Coordinating Council (WECC) under high penetrations of renewable energy, and to identify control technologies that would improve the system performance. The WECC is the regional entity responsible for coordinating and promoting bulk electric system reliability in the Western Interconnection. Transient stability is the ability of the power system to maintain synchronism after a large disturbance while small signal stability is the ability of the power system to maintain synchronism after a small disturbance. Tran- sient stability analysis usually focuses on the relative rotor angle between synchronous machines compared to some stability margin. For this study we employed generator speed relative to system speed as a metric for assessing transient stability. In addition, we evaluated the system transient response using the system frequency nadir, which provides an assessment of the adequacy of the primary frequency control reserves. Small signal stability analysis typically identi es the eigenvalues or modes of the system in response to a disturbance. For this study we developed mode shape maps for the di erent scenarios. Prony analysis was applied to generator speed after a 1.4 GW, 0.5 second, brake insertion at various locations. Six di erent WECC base cases were analyzed, including the 2022 light spring case which meets the renewable portfolio standards. Because of the di culty in identifying the cause and e ect relationship in large power system models with di erent scenarios, several simulations were run on a 7-bus, 5-generator system to isolate the e ects of di erent con gurations. Based on the results of the study, for a large power system like the WECC, incorporating frequency droop into wind/solar systems provides a larger bene t to system transient response than replacing the lost inertia with synthetic inertia. From a small signal stability

  15. FOR STIMUL-RESPONSIVE POLYMERS WITH ENHANCED EFFICIENCY IN RESERVOIR RECOVERY PROCESSES

    SciTech Connect (OSTI)

    Charles McCormick; Roger Hester

    2004-03-26

    This report contains a series of terpolymers containing acrylic acid, methacrylamide and a twin-tailed hydrophobic monomer that were synthesized using micellar polymerization methods. These polymer systems were characterized using light scattering, viscometry, and fluorescence methods. Viscosity studies indicate that increasing the nonpolar character of the hydrophobic monomer (longer chain length or twin tailed vs. single tailed) results in enhanced viscosity in aqueous solutions. The interactions of these polymers with surfactants were investigated. These surfactants include sodium dodecyl sulfate (SDS), cetyl trimethyl ammonium bromide (CTAB), Triton X-100. Viscosity measurements of DiC{sub 6}AM and DiC{sub 8}AM mixtures indicate little interaction with SDS, gelation with CTAB, and hemimicelle formation followed by polymer hydrophobe solubilization with Triton X-100. The DiC{sub 10}Am terpolymer shows similar interaction behavior with CTAB and Triton X-100. However, the enhanced hydrophobic nature of the DiC{sub 10} polymer allows complex formation with SDS as confirmed by surface tensiometry. Fluorescence measurements performed on a dansyl labeled DiC{sub 10}Am terpolymer in the presence of increasing amounts of each of the surfactant indicate relative interaction strengths to be CTAB>Triton X-100>SDS. A modified model based on Yamakawa-Fujii and Odjik-Skolnick-Fixman theories was found to describe the contribution of electrostatic forces to the excluded volume of a polyelectrolyte in solution. The model was found to be valid for flexible polymer coils in aqueous salt solutions where intermolecular interactions are minimal. The model suggested that a dimensionless group of parameters termed the dimensionless viscosity should be proportional to the dimensionless ratio of solution screening length to polyion charge spacing. Several sets of experimental data from the literature and from our laboratory have been analyzed according to the model and the results

  16. Anthropogenic emissions of NOx over China: Reconciling the difference of inverse modeling results using GOME-2 and OMI measurements

    SciTech Connect (OSTI)

    Gu, Dasa; Wang, Yuhang; Smeltzer, Charles; Boersma, K. Folkert

    2014-06-27

    Inverse modeling using satellite observations of nitrogen dioxide (NO2) columns has been extensively used to estimate nitrogen oxides (NOx) emissions in China. Recently, the Global Ozone Monitoring Experiment-2 (GOME-2) and Ozone Monitoring Instrument (OMI) provide independent global NO2 column measurements on a nearly daily basis at around 9:30 and 13:30 local time across the equator, respectively. Anthropogenic NOx emission estimates by applying previously developed monthly inversion (MI) or daily inversion (DI) methods to these two sets of measurements show substantial differences. We improve the DI method by conducting model simulation, satellite retrieval, and inverse modeling sequentially on a daily basis. After each inversion, we update anthropogenic NOx emissions in the model simulation with the newly obtained a posteriori results. Consequently, the inversion-optimized emissions are used to compute the a priori NO2 profiles for satellite retrievals. As such, the a priori profiles used in satellite retrievals are now coupled to inverse modeling results. The improved procedure was applied to GOME-2 and OMI NO2 measurements in 2011. The new daily retrieval-inversion (DRI) method estimates an average NOx emission of 6.9 Tg N/yr over China, and the difference between using GOME-2 and OMI measurements is 0.4 Tg N/yr, which is significantly smaller than the difference of 1.3 Tg N/yr using the previous DI method. Using the more consistent DRI inversion results, we find that anthropogenic NOx emissions tend to be higher in winter and summer than spring (and possibly fall) and the weekday-to-weekend emission ratio tends to increase with NOx emission in China.

  17. Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 1

    SciTech Connect (OSTI)

    2000-03-02

    The transportation sector accounts for approximately 65% of US petroleum consumption. Consumption for light-duty vehicles has stabilized in the last 10--15 years; however, consumption in the heavy-duty sector has continued to increase. For various reasons, the US must reduce its dependence on petroleum. One significant way is to substitute alternative fuels (natural gas, propane, alcohols, and others) in place of petroleum fuels in heavy-duty applications. Most alternative fuels have the additional benefit of reduced exhaust emissions relative to petroleum fuels, thus providing a cleaner environment. The best long-term technology for heavy-duty alternative fuel engines is the 4-stroke cycle, direct injected (DI) engine using a single fuel. This DI, single fuel approach maximizes the substitution of alternative fuel for diesel and retains the thermal efficiency and power density of the diesel engine. This report summarizes the results of the first year (Phase 1) of this contract. Phase 1 focused on developing a 4-stroke cycle, DI single fuel, alternative fuel technology that will duplicate or exceed diesel power density and thermal efficiency, while having exhaust emissions equal to or less than the diesel. Although the work is currently on a 3500 Series DING engine, the work is viewed as a basic technology development that can be applied to any engine. Phase 1 concentrated on DING engine component durability, exhaust emissions, and fuel handling system durability. Task 1 focused on identifying primary areas (e.g., ignition assist and gas injector systems) for future durability testing. In Task 2, eight mode-cycle-averaged NO{sub x} emissions were reduced from 11.8 gm/hp-hr (baseline conditions) to 2.5 gm/hp-hr (modified conditions) on a 3501 DING engine. In Task 3, a state-of-the-art fuel handling system was identified.

  18. Dark Matter Annihilation at the Galactic Center

    SciTech Connect (OSTI)

    Linden, Timothy Ryan

    2013-06-01

    Observations by the WMAP and PLANCK satellites have provided extraordinarily accurate observations on the densities of baryonic matter, dark matter, and dark energy in the universe. These observations indicate that our universe is composed of approximately ve times as much dark matter as baryonic matter. However, e orts to detect a particle responsible for the energy density of dark matter have been unsuccessful. Theoretical models have indicated that a leading candidate for the dark matter is the lightest supersymmetric particle, which may be stable due to a conserved R-parity. This dark matter particle would still be capable of interacting with baryons via weak-force interactions in the early universe, a process which was found to naturally explain the observed relic abundance of dark matter today. These residual annihilations can persist, albeit at a much lower rate, in the present universe, providing a detectable signal from dark matter annihilation events which occur throughout the universe. Simulations calculating the distribution of dark matter in our galaxy almost universally predict the galactic center of the Milky Way Galaxy (GC) to provide the brightest signal from dark matter annihilation due to its relative proximity and large simulated dark matter density. Recent advances in telescope technology have allowed for the rst multiwavelength analysis of the GC, with suitable e ective exposure, angular resolution, and energy resolution in order to detect dark matter particles with properties similar to those predicted by the WIMP miracle. In this work, I describe ongoing e orts which have successfully detected an excess in -ray emission from the region immediately surrounding the GC, which is di cult to describe in terms of standard di use emission predicted in the GC region. While the jury is still out on any dark matter interpretation of this excess, I describe several related observations which may indicate a dark matter origin. Finally, I discuss the

  19. SYNTHESIS OF NOVEL CROWN ETHERS BEARING THE exo-cis-2,3-NORBORNYL GROUP AS POTENTIAL Na+ AND K+ EXTRACTANTS

    SciTech Connect (OSTI)

    Robeson, R.M.; Bonnesen, P.

    2007-01-01

    The synthesis of a series of novel dinorbornyl-16-crown-5 and dinorbornyl-18-crown-6 ethers that incorporate the exo-cis-2,3-norbornyl moiety within the macrocycle framework is described. The key starting material for the crown ethers, exo-cis-2,3-norbornanediol, was successfully prepared on a large (>30g) scale in 88% yield from norbornylene by osmium tetroxide-catalyzed hydroxylation. The syn and anti isomers of the dinorbornyl-16-crown-5 ether family were prepared using diethylene glycol with ring closure achieved using a methallyl linkage. The isomers cis-syn-cis and cis-anti-cis di-norbornano-15-methyleno-16-crown-5 (6A and 6B) could be separated using column chromatography, and a single crystal of the syn isomer 6A suitable for X-ray crystal structure analysis was obtained, thereby confi rming the syn orientation. The syn and anti isomers of the dinorbornyl-18-crown-6 ether family were successfully prepared employing a different synthetic strategy, involving the potassium–templated cyclization of two bis-hydroxyethoxy-substituted exo-cis-2,3-norbornyl groups under high dilution conditions. Attempts to fully separate cis-syn-cis di-norbornano-18-crown-6 (10A) and cis-anti-cis di-norbornano-18-crown-6 (10B) from one another using column chromatography were unsuccessful. All intermediates and products were checked for purity using either thin layer chromatography or gas chromatography, and characterized by proton and carbon NMR. Crown ethers 6AB and 10AB are to our knowledge the fi rst crown ethers to incorporate the exo-cis-2,3-norbornyl moiety into the crown ring to be successfully synthesized and characterized.

  20. Sandia National Laboratories is a multi-program laboratory managed and operated

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a Lockheed Martin Company, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2007-6815P 10/2007 S AN DI A N AT I ON AL L AB O R AT O RIES Microsystems & Engineering Sciences Applications (MES A) MESA combines silicon processing, packaging and integration, and fabrication of compound- semiconductor devices under one roof. MESA

  1. SOLVENT EXTRACTION PROCESS FOR THE RECOVERY OF METALS FROM PHOSPHORIC ACID

    DOE Patents [OSTI]

    Bailes, R.H.; Long, R.S.

    1958-11-01

    > A solvent extraction process is presented for recovering metal values including uranium, thorium, and other lanthanide and actinide elements from crude industrial phosphoric acid solutions. The process conslsts of contacting said solution with an immisclble organic solvent extractant containing a diluent and a material selected from the group consisting of mono and di alkyl phosphates, alkyl phosphonates and alkyl phosphites. The uranlum enters the extractant phase and is subsequently recovered by any of the methods known to the art. Recovery is improved if the phosphate solution is treated with a reducing agent such as iron or aluminum powder prior to the extraction step.

  2. The QCD dynamics of tetraquark production

    SciTech Connect (OSTI)

    Brodsky, Stanley J.; Lebed, Richard F.

    2015-06-18

    We use the twist dimensions of the operators underlying the dynamical behavior of exclusive production processes as a tool for determining the structure of exotic heavy-quark states such as the Z+c(4430) tetraquark. The resulting counting rules predict distinctive falloffs of the cross sections in center-of-mass energy, thus distinguishing whether the tetraquarks are segregated into di-meson molecules, diquark-antidiquark pairs, or more democratically arranged four-quark states. Additionally, we propose straightforward methods of experimentally producing additional exotic multiquark states.

  3. NELCO METALS. INC. CANAAN. CONNBC.TIC"T

    Office of Legacy Management (LM)

    NELCO METALS. INC. CANAAN. CONNBC.TIC"T -1 . 3. .' " : .: ~ .r 3. ,i . . . .:, , I November 11, 1963 i I I i] U. S. Atomic Energy CornmiSSiOn Feed Materials DiLision Oak Ridge, Tennessee Attention: Mr. W. J. Moore Administrative Officer Gentlemen: It has been requested that we make an estimate of whet: would be re- quired to recover the magnesium and uranium from prill. We muat base all our figures on the premise that all the prill to be handled will be similar in characteristics to

  4. SREL Reprint #3280

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Plutonium Immobilization and Remobilization by Soil Mineral and Organic Matter in the Far-Field of the Savannah River Site, U.S. Chen Xu1, Matthew Athon1, Yi-Fang Ho1, Hyun-Shik Chang2, Saijin Zhang1, Daniel I. Kaplan3, Kathleen A. Schwehr1, Nicole DiDonato4, Patrick G. Hatcher4, and Peter H. Santschi1 1Department of Marine Sciences, Texas A&M University, Building 3029, Galveston, TX 77553, USA 2Savannah River Ecology Laboratory, University of Georgia, P.O. Drawer E, Aiken,

  5. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mr. Espresso Visits the Molecular Foundry It could be said that a lot of the research that is done at the Molecular Foundry is fueled by coffee, and for connoisseurs, you can't do much better on the hill than the second floor's coffee club run by Nanofabrication Facility Director Stefano Cabrini. On February 16, Carlo Di Ruocco, the Founder and CEO of the coffee maker company, Mr. Espresso, visited the Foundry's coffee club to discuss the art of brewing the perfect cup of espresso. During this

  6. Summary - System Level Modeling and Simulation Tools for Hanford

    Office of Environmental Management (EM)

    The ob curren plannin Dispos yield re to mod plannin to imp (4) det actual * Th th Th co no in pl * In fo op sy as di re de co an * Th en m ha ev sc The pu techni projec Site: H roject: H Report Date: S ited States valuation in Su Why DOE bjective of the r nt Process Simu ng basis for OR sition System P easonable esti del facilities cur ng or operation rove the rate o termine if addit execution of in What th he current Syst hat are limited t hese tools curr omposition, res ot meeting was itial

  7. Bioelectrochemical Integration of Waste Heat Recovery, Waste-to-Energy

    Broader source: Energy.gov (indexed) [DOE]

    a Folleto para colorear y de actividades 1 ¿Qué es bioenergía y de dónde proviene? ? Bioenergía es un tipo de energía renovable que se deriva de la biomasa para generar calor, electricidad, productos renovables y combustibles líquidos para el transporte. 2 Biocombustibles provienen de la biomasa (plantas-árboles) y desechos Pacas Rastrojo de maíz Pastos altos Trocitos de madera D E SEC H O S Algas 2 3 BIOMASA Combustible Etanol Biodiésel Combustible de aviones Diésel Gasolina

  8. Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tappan, Bryce C.; Chavez, David E.

    2014-12-02

    This paper describes the combustion properties of the amino-substituted guanidinium 4,4’,5,5’-tetranitro-2,2’-biimidazolate (N4BIM) series, including the bis-mono, di and triaminoguanidinium salts. These salts are of interest as propellant ingredient additives, and in particular, the bis-triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4-BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.

  9. National Electric Transmission Congestion Study 2006 Executive Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EXECUTIVE SUMMARY AUGUST 2006 U.S. Department of Energy NATIONAL ELECTRIC TRANSMISSION CONGESTION STUDY EXECUTIVE SUMMARY AUGUST 2006 U.S. Department of Energy Executive Summary Section 1221(a) of the Energy Policy Act of 2005 amended the Federal Power Act (FPA) by adding a new section 216 to that Act. FPA section 216(a) di- rected the Secretary of Energy to conduct a nation- wide study of electric transmission congestion 1 by August 8, 2006. Based upon the congestion study, comments thereon,

  10. Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observations of Multiple Magnetic Islands in the Core of a Reversed Field Pinch P. Franz, 1,2 L. Marrelli, 1,2 P. Piovesan, 1,2 B. E. Chapman, 3 P. Martin, 1,2 I. Predebon, 1,2 G. Spizzo, 1 R. B. White, 4 and C. Xiao 3,5 1 Consorzio RFX, Associazione EURATOM-ENEA sulla Fusione, Corso Stati Uniti, 4 35127 Padova, Italy * 2 Istituto Nazionale di Fisica della Materia, UdR Padova, Italy 3 Department of Physics, University of Wisconsin-Madison, 1150 University Avenue, Madison, Wisconsin 53706, USA 4

  11. Catalytic activity of silanols on carbamate-functionalized surface assemblies: Monoalkoxy versus trialkoxy silanes

    SciTech Connect (OSTI)

    Blackledge, C.; McDonald, J.D.

    1999-11-09

    Aminosilanes were protected with benzyloxylcarbonyl succinimidyl ester (CBZ-SE) in solution, forming carbamates. Investigations of surface assemblies made of CBZ-protected aminosilanes were done using XPS, contact angle measurements, and an amine reactive fluorescent probe. Spontaneous loss of the protection group was observed and determined to be caused by the catalytic effect of silanols from both the surface and the assembling silanes. The use of CBZ-protected monoalkoxy, which require days to assemble, as opposed to di- and trialkoxy silanes which require only hours, mitigated the deprotection.

  12. A review of chromatographic characterization techniques for biodiesel and biodiesel blends.

    SciTech Connect (OSTI)

    Pauls, R. E.

    2011-05-01

    This review surveys chromatographic technology that has been applied to the characterization of biodiesel and its blends. Typically, biodiesel consists of fatty acid methyl esters produced by transesterification of plant or animal derived triacylglycerols. Primary attention is given to the determination of trace impurities in biodiesel, such as methanol, glycerol, mono-, di-, and triacylglycerols, and sterol glucosides. The determination of the fatty acid methyl esters, trace impurities in biodiesel, and the determination of the biodiesel content of commercial blends of biodiesel in conventional diesel are also addressed.

  13. Field experiences in on-line bacteria monitoring

    SciTech Connect (OSTI)

    Smart, J.; Pickthall, T.; Wright, T.G.

    1996-08-01

    The results of field testing for bacteria and related corrosion are presented for three crude oil and one gas pipeline. Large numbers of bacteria were usually found in the crude oil pipelines, but large bacteria populations did not result in accelerated corrosion in these lines. Crude oil pipeline corrosion was found to be most rapid in sediment deposits, which consisted of oil wet corrosion products, paraffins, and water. Both bacteria populations and corrosion rates were low in the gas pipeline studied, due to a high residual di-amine corrosion inhibitor content in the pipeline water.

  14. Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 lujAn Center reseArCh FeAtureD on Cover oF Langmuir 4 FunCtionAl oxiDes unDer extreme ConDi- tions-quest For new mAteriAls 6 heADs uP! By Diana Del Mauro ADEPS Communications Inside the Lujan Neutron Scattering Center, Victor Fanelli is busy preparing a superconducting magnet. In a series of delicate steps,

  15. 080310_NERSC_WS.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    REQUIREMENTS WORKSHOP: FES August 3-4, 2010 Rockville MD Lee. A. Berry, for Paul Bonoli and the RF SciDAC Team L.A. Berry, D.B. Batchelor, D. L. Green,, E. D`Azevedo, E. F. Jaeger C.K. Phillips, E. Valeo N. Gorelenkov, H. Qin P.T. Bonoli, J.C. Wright R.W. Harvey, A.P. Smirnov Y. Petrov M. Choi M. Brambilla R. Bilato D. Smithe T. Austin J. Carlsson D. D'Ippolito, J. Myra - Lodestar Research Politecnico di Torino R. Maggiora Participants in the Center for Simulation of Wave-Plasma Interactions

  16. Methodology to determine the technical performance and value proposition for grid-scale energy storage systems : a study for the DOE energy storage systems program.

    SciTech Connect (OSTI)

    Byrne, Raymond Harry; Loose, Verne William; Donnelly, Matthew K.; Trudnowski, Daniel J.

    2012-12-01

    As the amount of renewable generation increases, the inherent variability of wind and photovoltaic systems must be addressed in order to ensure the continued safe and reliable operation of the nation's electricity grid. Grid-scale energy storage systems are uniquely suited to address the variability of renewable generation and to provide other valuable grid services. The goal of this report is to quantify the technical performance required to provide di erent grid bene ts and to specify the proper techniques for estimating the value of grid-scale energy storage systems.

  17. Belle Physics at Wayne State

    SciTech Connect (OSTI)

    Cinabro, David

    2016-01-01

    The major goals of our work on Belle II were to complete our contributions, a 64 channel PIN diode based radiation monitor, to the precursor detector called Beast II and the electronics for the endcap K-Long/Muon (E-KLM) detector. This was done by Professor Cinabro, Technician Gutierrez, and undergraduate labor supported by US-Japan funds. Professor Bonvicini through US-Japan funds led the development and installation of a beamstrahlung monitor system in the Belle II interaction region. Graduate students Farhat and DiCarlo worked on this. We also worked on charm physics analysis.

  18. Structural and magnetic properties of transition metal substituted BaFe{sub 2}As{sub 2} compounds studied by x-ray and neutron scattering

    SciTech Connect (OSTI)

    Kim, Min Gyu

    2012-08-28

    The purpose of my dissertation is to understand the structural and magnetic properties of the newly discovered FeAs-based superconductors and the interconnection between superconductivity, antiferromagnetism, and structure. X-ray and neutron scattering techniques are powerful tools to directly observe the structure and magnetism in this system. I used both xray and neutron scattering techniques on di#11;erent transition substituted BaFe2As2 compounds in order to investigate the substitution dependence of structural and magnetic transitions and try to understand the connections between them.

  19. Modeling and Algorithmic Approaches to Constitutively-Complex, Microstructured Fluids

    SciTech Connect (OSTI)

    Miller, Gregory H.; Forest, Gregory

    2011-12-22

    We present a new multiscale model for complex uids based on three scales: microscopic, kinetic, and continuum. We choose the microscopic level as Kramers' bead-rod model for polymers, which we describe as a system of stochastic di#11;erential equations with an implicit constraint formulation. The associated Fokker-Planck equation is then derived, and adiabatic elimination removes the fast momentum coordinates. Approached in this way, the kinetic level reduces to a dispersive drift equation. The continuum level is modeled with a #12;nite volume Godunov-projection algorithm. We demonstrate computation of viscoelastic stress divergence using this multiscale approach.

  20. The behavior and importance of lactic acid complexation in Talspeak extraction systems

    SciTech Connect (OSTI)

    Grimes, Travis S.; Nilsson, Mikael; Nash, Kenneth L.

    2008-07-01

    Advanced partitioning of spent nuclear fuel in the UREX +la process relies on the TALSPEAK process for separation of fission-product lanthanides from trivalent actinides. The classic TALSPEAK utilizes an aqueous medium of both lactic acid and diethylenetriaminepentaacetic acid and the extraction reagent di(2-ethylhexyl)phosphoric acid in an aromatic diluent. In this study, the specific role of lactic acid and the complexes involved in the extraction of the trivalent actinides and lanthanides have been investigated using {sup 14}C-labeled lactic acid. Our results show that lactic acid partitions between the phases in a complex fashion. (authors)