National Library of Energy BETA

Sample records for development wet chemistry

  1. Categorical Exclusion 4497: Lithium Wet Chemistry Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Categorical Exclusion Detennination Form Proposed Action Tills: Lithium W@t Chemistry Project (4597) Program or Fild Oftke: Y-12 Site Office L&cationfs)...

  2. Y-12 to Resume Wet Chemistry Operations | National Nuclear Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Administration | (NNSA) to Install New Fence to Reduce Trespassing March 28, 2013 The National Nuclear Security Administration today announced plans to extend the boundary fence at the Y-12 National Security Complex along Scarboro Road. The new fence is expected to be in place by April 4. File 2013-03-28 NPO.docx Administration | (NNSA)

    to Resume Wet Chemistry Operations March 14, 2003 PDF icon 3-14-03.pdf

  3. Development studies of a novel wet oxidation process

    SciTech Connect (OSTI)

    Rogers, T.W.; Dhooge, P.M.

    1995-10-01

    Many DOE waste streams and remediates contain complex and variable mixtures of organic compounds, toxic metals, and radionuclides. These materials are often dispersed in organic or inorganic matrices, such as personal protective equipment, various sludges, soils, and water. Incineration and similar combustive processes do not appear to be viable options for treatment of these waste streams due to various considerations. The objective of this project is to develop a novel catalytic wet oxidation process for the treatment of multi-component wastes. The DETOX process uses a unique combination of metal catalysts to increase the rate of oxidation of organic materials.

  4. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Print Chemical science at the ALS encompasses a broad range of approaches and specializations, including surfaces/interfaces, catalysis, chemical dynamics (gas-phase chemistry), crystallography, and physical chemistry. By one estimate, nearly 80% of all chemical reactions in nature and in human technology take place at boundaries between phases, i.e., at surfaces or interfaces. Atomic- and molecular-scale studies are needed to develop a thorough understanding of the

  5. Development of a Wet Logistics System for Bulk Corn Stover

    Broader source: Energy.gov (indexed) [DOE]

    a Wet Logistics System for Bulk Corn Stover March 25, 2015 Lynn M. Wendt, William A. Smith, Austin Murphy, and Ian J. Bonner Idaho National Laboratory This presentation does not ...

  6. Analysis Of Post-Wet-Chemistry Heat Treatment Effects On Nb SRF Surface Resistance

    SciTech Connect (OSTI)

    Dhakal, Pashupati; Ciovati, Gianluigi; Kneisel, Peter K.; Myneni, Ganapati Rao

    2014-02-01

    Most of the current research in superconducting radio frequency (SRF) cavities is focused on ways to reduce the construction and operating cost of SRF-based accelerators as well as on the development of new or improved cavity processing techniques. The increase in quality factors is the result of the reduction of the surface resistance of the materials. A recent test on a 1.5 GHz single cell cavity made from ingot niobium of medium purity and heat treated at 1400 deg C in a ultra-high vacuum induction furnace resulted in a residual resistance of ~ 1n{Omega} and a quality factor at 2.0 K increasing with field up to ~ 5×10{sup 10} at a peak magnetic field of 90 mT. In this contribution, we present some results on the investigation of the origin of the extended Q{sub 0}-increase, obtained by multiple HF rinses, oxypolishing and heat treatment of “all Nb” cavities.

  7. Scalable Computational Chemistry: New Developments and Applications

    SciTech Connect (OSTI)

    Yuri Alexeev

    2002-12-31

    The computational part of the thesis is the investigation of titanium chloride (II) as a potential catalyst for the bis-silylation reaction of ethylene with hexaclorodisilane at different levels of theory. Bis-silylation is an important reaction for producing bis(silyl) compounds and new C-Si bonds, which can serve as monomers for silicon containing polymers and silicon carbides. Ab initio calculations on the steps involved in a proposed mechanism are presented. This choice of reactants allows them to study this reaction at reliable levels of theory without compromising accuracy. The calculations indicate that this is a highly exothermic barrierless reaction. The TiCl{sub 2} catalyst removes a 50 kcal/mol activation energy barrier required for the reaction without the catalyst. The first step is interaction of TiCl{sub 2} with ethylene to form an intermediate that is 60 kcal/mol below the energy of the reactants. This is the driving force for the entire reaction. Dynamic correlation plays a significant role because RHF calculations indicate that the net barrier for the catalyzed reaction is 50 kcal/mol. They conclude that divalent Ti has the potential to become an important industrial catalyst for silylation reactions. In the programming part of the thesis, parallelization of different quantum chemistry methods is presented. The parallelization of code is becoming important aspects of quantum chemistry code development. Two trends contribute to it: the overall desire to study large chemical systems and the desire to employ highly correlated methods which are usually computationally and memory expensive. In the presented distributed data algorithms computation is parallelized and the largest arrays are evenly distributed among CPUs. First, the parallelization of the Hartree-Fock self-consistent field (SCF) method is considered. SCF method is the most common starting point for more accurate calculations. The Fock build (sub step of SCF) from AO integrals is also

  8. Rye Patch geothermal development, hydro-chemistry of thermal...

    Open Energy Info (EERE)

    Patch geothermal development, hydro-chemistry of thermal water applied to resource definition Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Rye Patch...

  9. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Chemical science for a dynamic world 3D printer is ideal tool to make cones of explosive material with finely controlled internal microstructure Explosiv3Design READ MORE Isotopes for cancer and cardiac care Isotopes for cancer and cardiac care READ MORE Contact Us Division Leader David Morris Deputy Division Leader Mark McCleskey Division Office (505) 667-4457 Email Chemical science in support of Los Alamos mission The Chemistry Division serves the Laboratory's mission with

  10. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Chemistry Top Journals Journal of the American Chemical Society Angewandte Chemie & Angewandte Chemie, international edition in English Chemical Communications Chemical...

  11. Development of a Stiffness-Based Chemistry Load Balancing Scheme...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of a Stiffness-Based Chemistry Load Balancing Scheme, and Optimization of IO and Communication, to Enable Massively Parallel High-Fidelity Internal Combustion Engine Simulations...

  12. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect (OSTI)

    Newkirk, L.

    1997-12-01

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  13. Chemistry {ampersand} Materials Science program report, Weapons Resarch and Development and Laboratory Directed Research and Development FY96

    SciTech Connect (OSTI)

    Chase, L.

    1997-03-01

    This report is the annual progress report for the Chemistry Materials Science Program: Weapons Research and Development and Laboratory Directed Research and Development. Twenty-one projects are described separately by their principal investigators.

  14. FULL-SCALE TESTING OF ENHANCED MERCURY CONTROL TECHNOLOGIES FOR WET FGD SYSTEMS

    SciTech Connect (OSTI)

    D.K. McDonald; G.T. Amrhein; G.A. Kudlac; D. Madden Yurchison

    2003-05-07

    Wet flue gas desulfurization (wet FGD) systems are currently installed on about 25% of the coal-fired utility generating capacity in the U.S., representing about 15% of the number of coal-fired units. Depending on the effect of operating parameters such as mercury content of the coal, form of mercury (elemental or oxidized) in the flue gas, scrubber spray tower configuration, liquid-to-gas ratio, and slurry chemistry, FGD systems can provide cost-effective, near-term mercury emissions control options with a proven history of commercial operation. For boilers already equipped with FGD systems, the incremental cost of any vapor phase mercury removal achieved is minimal. To be widely accepted and implemented, technical approaches that improve mercury removal performance for wet FGD systems should also have low incremental costs and have little or no impact on operation and SO{sub 2} removal performance. The ultimate goal of the Full-scale Testing of Enhanced Mercury Control for Wet FGD Systems Program was to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The program was funded by the U.S. Department of Energy's National Energy Technology Laboratory, the Ohio Coal Development Office within the Ohio Department of Development, and Babcock & Wilcox. Host sites and associated support were provided by Michigan South Central Power Agency (MSCPA) and Cinergy. Field-testing was completed at two commercial coal-fired utilities with wet FGD systems: (1) MSCPA's 55 MW{sub e} Endicott Station and (2) Cinergy's 1300 MW{sub e} Zimmer Station. Testing was conducted at these two locations because of the large differences in size and wet scrubber chemistry. Endicott employs a limestone, forced oxidation (LSFO) wet FGD system, whereas Zimmer uses Thiosorbic{reg_sign} Lime (magnesium enhanced lime) and ex situ oxidation. Both locations burn Ohio bituminous coal.

  15. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 1, Executive summary

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    About 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the solids for compaction in a landfill also consumes fly ash that otherwise may be marketable. This Executive Summary describes efforts to dewater the magnesium hydroxide and gypsum slurries and then process the solids into a more user friendly and higher value form. To eliminate the cost of solids disposal in its first generation Thiosorbic® system, the Dravo Lime Company developed the ThioClear® process that utilizes a magnesium based absorber liquor to remove S02 with minimal suspended solids. Magnesium enhanced lime is added to an oxidized bleed stream of thickener overflow (TOF) to produce magnesium hydroxide [Mg(OH)2] and gypsum (CaS04 • 2H20), as by-products. This process was demonstrated at the 3 to 5 MW closed loop FGD system pilot plant at the Miami Fort Station of Cinergy, near Cincinnati, Ohio with the help of OCDO Grant Agreement CDO/D-91-6. A similar process strictly for'recovery and reuse of Mg(OH)2 began operation at the Zimmer Station of Cinergy in late 1994 that can produce 900 pounds of Mg(OH)2 per hour and 2,600 pounds of gypsum per hour. This by-product plant, called the Zimmer Slipstream Magnesium Hydroxide Recovery Project Demonstration, was conducted with the help of OCDO Grant Agreement CDO/D-921-004. Full scale ThioClear® plants began operating in 1997 at the 130 MW Applied Energy Services plant, in Monaca, PA, and in year 2000 at the 1,330 MW Allegheny Energy Pleasants Station at St. Marys, WV.

  16. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

    2004-07-01

    Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

  17. Wetting of a Chemically Heterogeneous Surface

    SciTech Connect (OSTI)

    Frink, L.J.D.; Salinger, A.G.

    1998-11-20

    Theories for inhomogeneous fluids have focused in recent years on wetting, capillary conden- sation, and solvation forces for model systems where the surface(s) is(are) smooth homogeneous parallel plates, cylinders, or spherical drops. Unfortunately natural systems are more likely to be hetaogeneous both in surt%ce shape and surface chemistry. In this paper we discuss the conse- quences of chemical heterogeneity on wetting. Specifically, a 2-dimensional implementation of a nonlocal density functional theory is solved for a striped surface model. Both the strength and range of the heterogeneity are varied. Contact angles are calculated, and phase transitions (both the wetting transition and a local layering transition) are located. The wetting properties of the surface ase shown to be strongly dependent on the nature of the surface heterogeneity. In addition highly ordered nanoscopic phases are found, and the operational limits for formation of ordered or crystalline phases of nanoscopic extent are discussed.

  18. Atmospheric Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistry Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced by ...

  19. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide chemistry serves a critical role in addressing global threats Project Description At Los Alamos, scientists are using actinide analytical chemistry to ...

  20. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 3, Product development of gypsum, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in Figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compunction in a landfill also consumes fly ash that otherwise may be marketable.

  1. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 2, Product development of magnesium hydroxide, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compaction in a landfill also consumes fly ash that otherwise may be marketable.

  2. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide Chemistry Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise David Gallimore Actinide Analytical Chemistry Email Rebecca Chamberlin Actinide Analytical Chemistry Email Josh Smith Chemistry Communications Email Along with the lanthanides, they are often called "the f-elements" because they have valence electrons in the f shell. Actinide chemistry serves a

  3. Reactant ion chemistry for detection of TNT, RDX, and PETN using an ion mobility spectrometer

    SciTech Connect (OSTI)

    Klassen, S.E.; Rodacy, P.; Silva, R.

    1997-09-01

    This report describes the responses of three energetic materials (TNT, RDX, and PETN) to varying reactant ion chemistries and IMS cell temperatures. The following reactant ion chemistries were evaluated; air-dry; air-wet; methylene chloride-dry; methylene chloride-wet; methylene bromide-dry; nitrogen dioxide-wet; sulfur dioxide-wet. The temperature was varied between 160 - 220{degrees}C.

  4. A Component Approach to Collaborative Scientific Software Development: Tools and Techniques Utilized by the Quantum Chemistry Science Application Partnership

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kenny, Joseph P.; Janssen, Curtis L.; Gordon, Mark S.; Sosonkina, Masha; Windus, Theresa L.

    2008-01-01

    Cutting-edge scientific computing software is complex, increasingly involving the coupling of multiple packages to combine advanced algorithms or simulations at multiple physical scales. Component-based software engineering (CBSE) has been advanced as a technique for managing this complexity, and complex component applications have been created in the quantum chemistry domain, as well as several other simulation areas, using the component model advocated by the Common Component Architecture (CCA) Forum. While programming models do indeed enable sound software engineering practices, the selection of programming model is just one building block in a comprehensive approach to large-scale collaborative development which must also addressmore » interface and data standardization, and language and package interoperability. We provide an overview of the development approach utilized within the Quantum Chemistry Science Application Partnership, identifying design challenges, describing the techniques which we have adopted to address these challenges and highlighting the advantages which the CCA approach offers for collaborative development.« less

  5. WET SOLIDS FLOW ENHANCEMENT

    SciTech Connect (OSTI)

    Unknown

    2001-03-25

    The yield locus, tensile strength and fracture mechanisms of wet granular materials were studied. The yield locus of a wet material was shifted to the left of that of the dry specimen by a constant value equal to the compressive isostatic stress due to pendular bridges. for materials with straight yield loci, the shift was computed from the uniaxial tensile strength, either measured in a tensile strength tester or calculated from the correlation, and the angle of internal friction of the material. The predicted shift in the yield loci due to different moisture contents compare well with the measured shift in the yield loci of glass beads, crushed limestone, super D catalyst and Leslie coal. Measurement of the void fraction during the shear testing was critical to obtain the correct tensile strength theoretically or experimentally.

  6. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  7. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, L.C.; Simpson, M.L.

    1995-01-17

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

  8. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, Lonnie C.; Simpson, Marc L.

    1995-01-01

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

  9. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  10. Chemical structures of low-pressure premixed methylcyclohexane flames as benchmarks for the development of a predictive combustion chemistry model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skeen, Scott A.; Yang, Bin; Jasper, Ahren W.; Pitz, William J.; Hansen, Nils

    2011-11-14

    The chemical compositions of three low-pressure premixed flames of methylcyclohexane (MCH) are investigated with the emphasis on the chemistry of MCH decomposition and the formation of aromatic species, including benzene and toluene. The flames are stabilized on a flat-flame (McKenna type) burner at equivalence ratios of φ = 1.0, 1.75, and 1.9 and at low pressures between 15 Torr (= 20 mbar) and 30 Torr (= 40 mbar). The complex chemistry of MCH consumption is illustrated in the experimental identification of several C7H12, C7H10, C6H12, and C6H10 isomers sampled from the flames as a function of distance from the burner.more » Three initiation steps for MCH consumption are discussed: ring-opening to heptenes and methyl-hexenes (isomerization), methyl radical loss yielding the cyclohexyl radical (dissociation), and H abstraction from MCH. Mole fraction profiles as a function of distance from the burner for the C7 species supplemented by theoretical calculations are presented, indicating that flame structures resulting in steeper temperature gradients and/or greater peak temperatures can lead to a relative increase in MCH consumption through the dissociation and isomerization channels. Trends observed among the stable C6 species as well as 1,3-pentadiene and isoprene also support this conclusion. Relatively large amounts of toluene and benzene are observed in the experiments, illustrating the importance of sequential H-abstraction steps from MCH to toluene and from cyclohexyl to benzene. Furthermore, modeled results using the detailed chemical model of Pitz et al. (Proc. Combust. Inst.2007, 31, 267–275) are also provided to illustrate the use of these data as a benchmark for the improvement or future development of a MCH mechanism.« less

  11. Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Applications Gaussian 09 Gaussian 09 is a connected series of programs for performing semi-empirical, density functional theory and ab initio molecular orbital calculations. Read More » GAMESS GAMESS (General Atomic and Molecular Electronic Structure System) is a general ab initio quantum chemistry package. Read More » AMBER AMBER (Assisted Model Building with Energy Refinement) is the collective name for a suite of programs designed to carry out molecular dynamics

  12. Does surface roughness amplify wetting?

    SciTech Connect (OSTI)

    Malijevský, Alexandr

    2014-11-14

    Any solid surface is intrinsically rough on the microscopic scale. In this paper, we study the effect of this roughness on the wetting properties of hydrophilic substrates. Macroscopic arguments, such as those leading to the well-known Wenzel's law, predict that surface roughness should amplify the wetting properties of such adsorbents. We use a fundamental measure density functional theory to demonstrate the opposite effect from roughness for microscopically corrugated surfaces, i.e., wetting is hindered. Based on three independent analyses we show that microscopic surface corrugation increases the wetting temperature or even makes the surface hydrophobic. Since for macroscopically corrugated surfaces the solid texture does indeed amplify wetting there must exist a crossover between two length-scale regimes that are distinguished by opposite response on surface roughening. This demonstrates how deceptive can be efforts to extend the thermodynamical laws beyond their macroscopic territory.

  13. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  14. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department`s moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  15. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  16. Hydrothermal Processing of Wet Wastes

    Broader source: Energy.gov [DOE]

    Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

  17. Aerosol transport and wet scavenging in deep convective clouds: a case study and model evaluation using a multiple passive tracer analysis approach

    SciTech Connect (OSTI)

    Yang, Qing; Easter, Richard C.; Campuzano-Jost, Pedro; Jimenez, Jose L.; Fast, Jerome D.; Ghan, Steven J.; Wang, Hailong; Berg, Larry K.; Barth, Mary; Liu, Ying; Shrivastava, ManishKumar B.; Singh, Balwinder; Morrison, H.; Fan, Jiwen; Ziegler, Conrad L.; Bela, Megan; Apel, Eric; Diskin, G. S.; Mikoviny, Tomas; Wisthaler, Armin

    2015-08-20

    The effect of wet scavenging on ambient aerosols in deep, continental convective clouds in the mid-latitudes is studied for a severe storm case in Oklahoma during the Deep Convective Clouds and Chemistry (DC3) field campaign. A new passive-tracer based transport analysis framework is developed to characterize the convective transport based on the vertical distribution of several slowly reacting and nearly insoluble trace gases. The passive gas concentration in the upper troposphere convective outflow results from a mixture of 47% from the lower level (0-3 km), 21% entrained from the upper troposphere, and 32% from mid-atmosphere based on observations. The transport analysis framework is applied to aerosols to estimate aerosol transport and wet-scavenging efficiency. Observations yield high overall scavenging efficiencies of 81% and 68% for aerosol mass (Dp < 1μm) and aerosol number (0.03< Dp < 2.5μm), respectively. Little chemical selectivity to wet scavenging is seen among observed submicron sulfate (84%), organic (82%), and ammonium (80%) aerosols, while nitrate has a much lower scavenging efficiency of 57% likely due to the uptake of nitric acid. Observed larger size particles (0.15 - 2.5μm) are scavenged more efficiently (84%) than smaller particles (64%; 0.03 - 0.15μm). The storm is simulated using the chemistry version of the WRF model. Compared to the observation based analysis, the standard model underestimates the wet scavenging efficiency for both mass and number concentrations with low biases of 31% and 40%, respectively. Adding a new treatment of secondary activation significantly improves simulation results, so that the bias in scavenging efficiency in mass and number concentrations is reduced to <10%. This supports the hypothesis that secondary activation is an important process for wet removal of aerosols in deep convective storms.

  18. Chemistry and materials science progress report. Weapons-supporting research and laboratory directed research and development: FY 1995

    SciTech Connect (OSTI)

    NONE

    1996-04-01

    This report covers different materials and chemistry research projects carried out a Lawrence Livermore National Laboratory during 1995 in support of nuclear weapons programs and other programs. There are 16 papers supporting weapons research and 12 papers supporting laboratory directed research.

  19. he Impact of Primary Marine Aerosol on Atmospheric Chemistry, Radiation and Climate: A CCSM Model Development Study

    SciTech Connect (OSTI)

    Keene, William C.; Long, Michael S.

    2013-05-20

    This project examined the potential large-scale influence of marine aerosol cycling on atmospheric chemistry, physics and radiative transfer. Measurements indicate that the size-dependent generation of marine aerosols by wind waves at the ocean surface and the subsequent production and cycling of halogen-radicals are important but poorly constrained processes that influence climate regionally and globally. A reliable capacity to examine the role of marine aerosol in the global-scale atmospheric system requires that the important size-resolved chemical processes be treated explicitly. But the treatment of multiphase chemistry across the breadth of chemical scenarios encountered throughout the atmosphere is sensitive to the initial conditions and the precision of the solution method. This study examined this sensitivity, constrained it using high-resolution laboratory and field measurements, and deployed it in a coupled chemical-microphysical 3-D atmosphere model. First, laboratory measurements of fresh, unreacted marine aerosol were used to formulate a sea-state based marine aerosol source parameterization that captured the initial organic, inorganic, and physical conditions of the aerosol population. Second, a multiphase chemical mechanism, solved using the Max Planck Institute for Chemistry's MECCA (Module Efficiently Calculating the Chemistry of the Atmosphere) system, was benchmarked across a broad set of observed chemical and physical conditions in the marine atmosphere. Using these results, the mechanism was systematically reduced to maximize computational speed. Finally, the mechanism was coupled to the 3-mode modal aerosol version of the NCAR Community Atmosphere Model (CAM v3.6.33). Decadal-scale simulations with CAM v.3.6.33, were run both with and without reactive-halogen chemistry and with and without explicit treatment of particulate organic carbon in the marine aerosol source function. Simulated results were interpreted (1) to evaluate influences of

  20. Hydrothermal Processing of Wet Wastes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing of Wet Wastes James Oyler July 2014 Slide 1 Slide 2 Q: What is possible with Waste-to-Energy (WTE)? A: Up to 25% of US Liquid Fuel Supply. 25% Sounds High-Is That Possible? * Available technology and wet wastes can start toward this goal now * 285,000 barrels of oil per day by 2025 - 3.3 million bbl/d by 2045 (17% of US demand); also produces more than 6 million MCF/d of methane - Continue growing to 25% of US demand by adding more feedstocks (chart shown later) * Using wastes solves

  1. Flame Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  2. Materials Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  3. Chemistry-nuclear chemistry division. Progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1981-05-01

    This report presents the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, element migration and fixation, inorganic chemistry, isotope separation and analysis, atomic and molecular collisions, molecular spectroscopy, muonic x rays, nuclear cosmochemistry, nuclear structure and reactions, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  4. Competitive Wetting in Active Brazes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chandross, Michael Evan

    2014-05-01

    We found that the wetting and spreading of molten filler materials (pure Al, pure Ag, and AgAl alloys) on a Kovar ™ (001) substrate was studied with molecular dynamics simulations. A suite of different simulations was used to understand the effects on spreading rates due to alloying as well as reactions with the substrate. Moreover, the important conclusion is that the presence of Al in the alloy enhances the spreading of Ag, while the Ag inhibits the spreading of Al.

  5. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information * Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations

  6. Analytical Chemistry Laboratory Progress Report for FY 1994

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1994-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1994 (October 1993 through September 1994). This annual report is the eleventh for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has a research program in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. The ACL has four technical groups -- Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis -- which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL. The Chemical Analysis Group uses wet- chemical and instrumental methods for elemental, compositional, and isotopic determinations in solid, liquid, and gaseous samples and provides specialized analytical services. Major instruments in this group include an ion chromatograph (IC), an inductively coupled plasma/atomic emission spectrometer (ICP/AES), spectrophotometers, mass spectrometers (including gas-analysis and thermal-ionization mass spectrometers), emission spectrographs, autotitrators, sulfur and carbon determinators, and a kinetic phosphorescence uranium analyzer.

  7. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  8. Episodic response project: Wet deposition at watersheds in three regions of the eastern United States

    SciTech Connect (OSTI)

    Barchet, W.R.

    1991-11-01

    During the period from August 1988 to June 1990, wet-only sampling of precipitation was carried out at three Episodic Response Project sites and at one supplemental site. The three watershed sites are Moss Lake, Biscuit Brook, and Linn Run. The supplemental site was the MAP3S site at Pennsylvania State University that characterizes the central group of northern Appalachian streams. The site operators adhered by varying degrees to the sample collection protocol based on the daily sampling protocol of the MAP3S Precipitation Chemistry Network. Sulfate and nitrate ion together accounted for more than 80% of total anions (in {mu}Eq/L) in the precipitation at all sites. Wet deposition of sulfate at Moss Lake, Biscuit Brook, Penn State, and Linn Run averaged 223, 230, 253, and 402 mg/m{sup 2}/month, respectively, whereas nitrate wet deposition averaged 197, 195, 160, and 233 mg/m{sup 2}/month, respectively. Sulfate deposition was a factor of 2 to 4 higher in summer than in winter. The seasonal pattern for nitrate deposition was weak; the seasonal contrast was less than a factor of 2.5 at all sites. The association between the wet deposition and precipitation chemistry at the MAP3S monitoring site and the average for the study watersheds was dependent on the distance between the site and watershed and the intervening terrain. Precipitation chemistry at the monitoring site is representative of that at the ERP study watersheds in the Adirondack and Catskill regions and in the south-western group of watersheds in the Appalachian region. High spatial variability in precipitation amounts makes this assumption weaker for wet deposition. Chemical input to watersheds from dry deposition has not been determined at any site but could range from a factor of 0.3 to 1.0 of the wet deposition. 7 refs., 38 figs., 12 tabs.

  9. Flame Chemistry and Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flame Conditions Flame Chemistry Insights (n-butanol flame) Experiment vs. ... Molecular beam sampling "freezes" chemistry Time-of-flight mass spectrometry ...

  10. Exhaust Phosphorous Chemistry | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Exhaust Phosphorous Chemistry and Catalyst Poisoning The Development of Rapid Aging and Poisoning Protocols for Diesel Aftertreatment Devices Vehicle ...

  11. Final Report: Wetted Cathodes for Low-Temperature Aluminum Smelting

    SciTech Connect (OSTI)

    Brown, Craig W

    2002-09-30

    A low-temperature aluminum smelting process being developed differs from the Hall-Heroult process in several significant ways. The low-temperature process employs a more acidic electrolyte than cryolite, an alumina slurry, oxygen-generating metal anodes, and vertically suspended electrodes. Wetted and drained vertical cathodes are crucial to the new process. Such cathodes represent a significant portion of the capital costs projected for the new technology. Although studies exist of wetted cathode technology with Hall-Heoult cells, the differences make such a study desirable with the new process.

  12. Carbon nanotube fiber spun from wetted ribbon

    DOE Patents [OSTI]

    Zhu, Yuntian T; Arendt, Paul; Zhang, Xiefei; Li, Qingwen; Fu, Lei; Zheng, Lianxi

    2014-04-29

    A fiber of carbon nanotubes was prepared by a wet-spinning method involving drawing carbon nanotubes away from a substantially aligned, supported array of carbon nanotubes to form a ribbon, wetting the ribbon with a liquid, and spinning a fiber from the wetted ribbon. The liquid can be a polymer solution and after forming the fiber, the polymer can be cured. The resulting fiber has a higher tensile strength and higher conductivity compared to dry-spun fibers and to wet-spun fibers prepared by other methods.

  13. ITP Industrial Distributed Energy: A Guide to Developing Air...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    .........21 6.2 CHEMISTRY APPROACHES ......Developers have used several approaches, including chemistry changes to inhibit ...

  14. Predictive modeling of reactive wetting and metal joining.

    SciTech Connect (OSTI)

    van Swol, Frank B.

    2013-09-01

    The performance, reproducibility and reliability of metal joints are complex functions of the detailed history of physical processes involved in their creation. Prediction and control of these processes constitutes an intrinsically challenging multi-physics problem involving heating and melting a metal alloy and reactive wetting. Understanding this process requires coupling strong molecularscale chemistry at the interface with microscopic (diffusion) and macroscopic mass transport (flow) inside the liquid followed by subsequent cooling and solidification of the new metal mixture. The final joint displays compositional heterogeneity and its resulting microstructure largely determines the success or failure of the entire component. At present there exists no computational tool at Sandia that can predict the formation and success of a braze joint, as current capabilities lack the ability to capture surface/interface reactions and their effect on interface properties. This situation precludes us from implementing a proactive strategy to deal with joining problems. Here, we describe what is needed to arrive at a predictive modeling and simulation capability for multicomponent metals with complicated phase diagrams for melting and solidification, incorporating dissolutive and composition-dependent wetting.

  15. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    SciTech Connect (OSTI)

    Ryan, R.R.

    1982-05-01

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  16. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Synthetic and Mechanistic ... Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry ...

  17. Actinide Analytical Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AAC Actinide Analytical Chemistry We do analyses that range from assay of the major and ... Group Office (505) 667-4087 The Actinide Analytical Chemistry (C-AAC) Group at Los Alamos ...

  18. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Mechanistic Chemistry Security at center of chemical and mechanistic chemistry research at Lab Project Description Los Alamos scientists are using synthetic and mechanistic chemistry to address energy security and other emerging challenges, including global security and core weapons missions. Synthetic chemistry includes work in ligands for catalysts, fission-products separations for isotope delivery, and labeled substrates for reaction mechanisms. Other research addresses materials

  19. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Chemistry Synthetic and mechanistic chemical sciences play an important role in Lab missions dedicated to energy security, emerging challenges, global security, and core weapons missions. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this

  20. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE

  1. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE

  2. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE controls

  3. DOE fundamentals handbook: Chemistry. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  4. National Ignition Facility wet weather construction plan

    SciTech Connect (OSTI)

    Kugler, A N

    1998-01-01

    This report presents a wet weather construction plan for the National Ignition Facility (NIF) construction project. Construction of the NIF commenced in mid- 1997, and excavation of the site was completed in the fall. Preparations for placing concrete foundations began in the fall, and above normal rainfall is expected over the tinter. Heavy rainfall in late November impacted foundation construction, and a wet weather construction plan was determined to be needed. This wet weather constiction plan recommends a strategy, techniques and management practices to prepare and protect the site corn wet weather effects and allow construction work to proceed. It is intended that information in this plan be incorporated in the Stormwater Pollution Prevention Plan (SWPPP) as warranted.

  5. Reducing the atmospheric impact of wet slaking

    SciTech Connect (OSTI)

    B.D. Zubitskii; G.V. Ushakov; B.G. Tryasunov; A.G.Ushakov

    2009-05-15

    Means of reducing the atmospheric emissions due to the wet slaking of coke are considered. One option, investigated here, is to remove residual active silt and organic compounds from the biologically purified wastewater sent for slaking, by coagulation and flocculation.

  6. ARM: AOS Wet Nephelometer 1 Minute Averages (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: AOS Wet Nephelometer 1 Minute Averages AOS Wet Nephelometer 1 Minute Averages Authors: Scott Smith ; Cynthia Salwen ; Janek Uin ; Gunnar Senum ; Stephen Springston ; ...

  7. MHK Technologies/WET NZ | Open Energy Information

    Open Energy Info (EERE)

    to the MHK database homepage WET NZ.jpg Technology Profile Primary Organization Wave Energy Technology New Zealand WET NZ Technology Resource Click here Wave Technology...

  8. New Mexico Associated-Dissolved Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    New Mexico Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 New Mexico Associated-Dissolved Natural Gas ...

  9. New Mexico Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) New Mexico Nonassociated Natural Gas, Wet After ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New ...

  10. New Mexico Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico Natural ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New Mexico Natural ...

  11. New York Nonassociated Natural Gas, Wet After Lease Separation...

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves (Billion Cubic Feet) New York Nonassociated Natural Gas, Wet After ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New ...

  12. ,"West Virginia Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","West Virginia Associated-Dissolved Natural Gas, Wet ... PM" "Back to Contents","Data 1: West Virginia Associated-Dissolved Natural Gas, Wet ...

  13. ,"Louisiana State Offshore Nonassociated Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana State Offshore Nonassociated Natural Gas, Wet After ... to Contents","Data 1: Louisiana State Offshore Nonassociated Natural Gas, Wet After ...

  14. Louisiana State Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Louisiana State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 LA, State Offshore ...

  15. ,"Texas State Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas State Offshore Natural Gas, Wet After Lease Separation ... "Back to Contents","Data 1: Texas State Offshore Natural Gas, Wet After Lease Separation ...

  16. Texas State Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 TX, State Offshore ...

  17. ,"Louisiana State Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana State Offshore Natural Gas, Wet After Lease Separation ... to Contents","Data 1: Louisiana State Offshore Natural Gas, Wet After Lease Separation ...

  18. ,"Texas State Offshore Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas State Offshore Nonassociated Natural Gas, Wet After ... "Back to Contents","Data 1: Texas State Offshore Nonassociated Natural Gas, Wet After ...

  19. ,"Texas State Offshore Associated-Dissolved Natural Gas, Wet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas State Offshore Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: Texas State Offshore Associated-Dissolved Natural Gas, Wet ...

  20. ,"West Virginia Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  1. ,"Montana Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  2. ,"Oklahoma Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  3. ,"Kentucky Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  4. ,"Louisiana Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  5. ,"Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  6. ,"Ohio Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  7. ,"Mississippi Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  8. ,"Mississippi Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  9. ,"Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  10. ,"Michigan Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  11. ,"Lower 48 States Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 48 States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  12. ,"Virginia Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  13. ,"Wyoming Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  14. ,"Kansas Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  15. ,"Pennsylvania Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  16. ,"Montana Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  17. ,"Mississippi Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  18. ,"Texas Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  19. ,"Kansas Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  20. ,"Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  1. ,"Michigan Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  2. ,"Miscellaneous States Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  3. ,"Ohio Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  4. ,"Utah Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  5. ,"Kentucky Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  6. ,"Montana Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  7. ,"Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  8. ,"Utah Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Utah Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  9. ,"Virginia Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  10. ,"Louisiana - South Onshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click ... Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  11. ,"Kentucky Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  12. ,"Virginia Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  13. ,"Miscellaneous States Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  14. ,"Wyoming Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  15. ,"Michigan Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  16. ,"Louisiana Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  17. ,"Oklahoma Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  18. ,"Utah Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  19. ,"West Virginia Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  20. ,"Texas Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  1. ,"Texas Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  2. ,"Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  3. ,"Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  4. ,"Louisiana Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  5. ,"U.S. Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic ...

  6. New Mexico - East Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - East Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade ...

  7. New Mexico - West Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    West Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - West Associated-Dissolved Natural Gas, Wet After Lease ...

  8. New Mexico - East Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation, Proved ...

  9. New Mexico - East Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Associated-Dissolved Natural Gas, Wet After Lease Separation, ...

  10. New Mexico - West Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - West Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade ...

  11. Louisiana - North Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation, Proved ...

  12. ,"North Dakota Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Nonassociated Natural Gas, Wet ... 9:32:06 AM" "Back to Contents","Data 1: North Dakota Nonassociated Natural Gas, Wet ...

  13. Louisiana - North Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Louisiana - North Associated-Dissolved Natural Gas, Wet ... Wet After Lease Separation, as of Dec. 31 North Louisiana Associated-Dissolved Natural Gas ...

  14. ,"Louisiana - North Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Nonassociated Natural Gas, Wet After Lease ... "Back to Contents","Data 1: Louisiana - North Nonassociated Natural Gas, Wet After Lease ...

  15. North Dakota Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Dakota Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North ...

  16. ,"Louisiana - North Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Natural Gas, Wet After Lease Separation ... "Back to Contents","Data 1: Louisiana - North Natural Gas, Wet After Lease Separation ...

  17. North Dakota Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) North Dakota Natural ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North Dakota ...

  18. ,"Louisiana - North Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana - North Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: Louisiana - North Associated-Dissolved Natural Gas, Wet ...

  19. North Dakota Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Dakota Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 North Dakota Associated-Dissolved Natural Gas ...

  20. Louisiana - North Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Louisiana - North Natural Gas, Wet After Lease Separation ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 North Louisiana ...

  1. Wet/dry cooling tower and method

    DOE Patents [OSTI]

    Glicksman, Leon R.; Rohsenow, Warren R.

    1981-01-01

    A wet/dry cooling tower wherein a liquid to-be-cooled is flowed along channels of a corrugated open surface or the like, which surface is swept by cooling air. The amount of the surface covered by the liquid is kept small compared to the dry part thereof so that said dry part acts as a fin for the wet part for heat dissipation.

  2. Chemistry, Reservoir, and Integrated Models | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry, Reservoir, and Integrated Models Chemistry, Reservoir, and Integrated Models Below are the project presentations and respective peer review results for Chemistry, Reservoir and Integrated Models. Development and Validation of an Advanced Stimulation Prediction Model for Enhanced Geothermal Systems (EGS), Marte Gutierrez and Masami Nakagawa, Colorado School of Mines Development of Advanced Thermal-Hydrological-Mechanical-Chemical (THMC) Modeling Capabilities for Enhanced Geothermal

  3. Wetting state on hydrophilic and hydrophobic micro-textured surfaces: Thermodynamic analysis and X-ray visualization

    SciTech Connect (OSTI)

    Yu, Dong In; Kwak, Ho Jae; Doh, Seung Woo; Park, Hyun Sun Kiyofumi, Moriyama; Kang, Hie Chan; Ahn, Ho Seon; Kim, Moo Hwan

    2015-04-27

    In this study, the wetting state on hydrophobic and hydrophilic micro-textured surfaces was investigated. High spatial resolution synchrotron X-ray radiography was used to overcome the limitations in visualization in previous research and clearly visualize the wetting state for each droplet under quantified surface conditions. Based on thermodynamic characteristics, a theoretical model for wetting state depending on the chemical composition (intrinsic contact angle) and geometrical morphology (roughness ratio) of the surfaces was developed.

  4. Challenges and Opportunities for Wet-Waste Feedstocks - Resource

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment | Department of Energy Challenges and Opportunities for Wet-Waste Feedstocks - Resource Assessment Challenges and Opportunities for Wet-Waste Feedstocks - Resource Assessment Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste Feedstocks Challenges and Opportunities for Wet-Waste Feedstocks - Resource Assessment Corinne Drennan, Energy & Environment Directorate, Pacific Northwest National Laboratory

  5. Wetted foam liquid fuel ICF target experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Olson, R. E.; Leeper, R. J.; Yi, S. A.; Kline, J. L.; Zylstra, A. B.; Peterson, R. R.; Shah, R.; Braun, T.; Biener, J.; Kozioziemski, B. J.; et al

    2016-05-01

    Here, we are developing a new NIF experimental platform that employs wetted foam liquid fuel layer ICF capsules. We will use the liquid fuel layer capsules in a NIF sub-scale experimental campaign to explore the relationship between hot spot convergence ratio (CR) and the predictability of hot spot formation. DT liquid layer ICF capsules allow for flexibility in hot spot CR via the adjustment of the initial cryogenic capsule temperature and, hence, DT vapor density. Our hypothesis is that the predictive capability of hot spot formation is robust and 1D-like for a relatively low CR hot spot (CR~15), but willmore » become less reliable as hot spot CR is increased to CR>20. Simulations indicate that backing off on hot spot CR is an excellent way to reduce capsule instability growth and to improve robustness to low-mode x-ray flux asymmetries. In the initial experiments, we will test our hypothesis by measuring hot spot size, neutron yield, ion temperature, and burn width to infer hot spot pressure and compare to predictions for implosions with hot spot CR's in the range of 12 to 25. Larger scale experiments are also being designed, and we will advance from sub-scale to full-scale NIF experiments to determine if 1D-like behavior at low CR is retained as the scale-size is increased. The long-term objective is to develop a liquid fuel layer ICF capsule platform with robust thermonuclear burn, modest CR, and significant α-heating with burn propagation.« less

  6. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, L.G.

    1979-08-29

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  7. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, Louis G.

    1982-01-01

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  8. Chemistry of Materials

    Office of Scientific and Technical Information (OSTI)

    Engineering and Materials Science, Dept. of Chemistry, The Smalley Institute for Nanoscale ... University, R.E. Smalley Institute for Nanoscale Science and Tech., Ajayan, Pulickel; ...

  9. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performing weapons chemistry of targets for cross-section measurements, energetic ligands, and composites. Conducting separations for (1) medical isotope purification and (2) ...

  10. Controllable underwater anisotropic oil-wetting

    SciTech Connect (OSTI)

    Yong, Jiale; Chen, Feng Yang, Qing; Farooq, Umar; Bian, Hao; Du, Guangqing; Hou, Xun

    2014-08-18

    This Letter demonstrates a simple method to achieve underwater anisotropic oil-wetting using silicon surfaces with a microgroove array produced by femtosecond laser ablation. The oil contact angles along the direction perpendicular to the grooves are consistently larger than those parallel to the microgroove arrays in water because the oil droplet is restricted by the energy barrier that exists between the non-irradiated domain and the trapped water in the laser-ablated microgrooves. This underwater anisotropic oil-wetting is able to be controlled, and the anisotropy can be tuned from 0° to ∼20° by adjusting the period of the microgroove arrays.

  11. Coal combustion by wet oxidation. Wet oxidation of coal for energy production: test plan and partial results. Interim report

    SciTech Connect (OSTI)

    Bettinger, J.A.

    1980-07-10

    A test plan has been developed which will provide the data necessary to carry out design and economic studies of a steam generating facility, employing the wet oxidation of coal as a heat source. It is obvious, from the literature search and preliminary testing, that the higher the reaction temperature, the more complete the combustion of coal. However, operation at elevated temperatures and pressures present difficult design problems, and the necessary equipment is costly. Operation under these conditions can only be justified by the higher economic value of high pressure and temperature steam. With a reduction in temperature from 550/sup 0/F (228/sup 0/C) to 450/sup 0/F (232/sup 0/C), the operating pressure is reduced by more than half, thus holding down the overall cost of the system. For this reason, our plan is to study both the enhancement of low temperature wet oxidation of coal, and the higher operating regions. The coal selected for the first portion of this test is an Eastern Appalachian high-volatile-A Bituminous type, from the Upper Clarion seam in Pennsylvania. This coal was selected as being a typical high sulfur, eastern coal. The wet oxidation of coal to produce low pressure steam is a process suited for a high sulfur, low grade, coal. It is not intended that wet oxidation be used in all applications with all types of coals, as it does not appear to be competitive, economically, with conventional combustion, therefore the testing will focus on using high sulfur, low grade coals. In the later portion of testing all the available coals will be tested. In addition, a sample of Minnesota peat will be tested to determine if it also can be used in the process.

  12. WETTABILITY AND IMBIBITION: MICROSCOPIC DISTRIBUTION OF WETTING AND ITS CONSEQUENCES AT THE CORE AND FIELD SCALES

    SciTech Connect (OSTI)

    Jill S. Buckley; Norman R. Morrow; Chris Palmer; Purnendu K. Dasgupta

    2003-02-01

    The questions of reservoir wettability have been approached in this project from three directions. First, we have studied the properties of crude oils that contribute to wetting alteration in a reservoir. A database of more than 150 different crude oil samples has been established to facilitate examination of the relationships between crude oil chemical and physical properties and their influence on reservoir wetting. In the course of this work an improved SARA analysis technique was developed and major advances were made in understanding asphaltene stability including development of a thermodynamic Asphaltene Solubility Model (ASM) and empirical methods for predicting the onset of instability. The CO-Wet database is a resource that will be used to guide wettability research in the future. The second approach is to study crude oil/brine/rock interactions on smooth surfaces. Contact angle measurements were made under controlled conditions on mica surfaces that had been exposed to many of the oils in the CO-Wet database. With this wealth of data, statistical tests can now be used to examine the relationships between crude oil properties and the tendencies of those oils to alter wetting. Traditionally, contact angles have been used as the primary wetting assessment tool on smooth surfaces. A new technique has been developed using an atomic forces microscope that adds a new dimension to the ability to characterize oil-treated surfaces. Ultimately we aim to understand wetting in porous media, the focus of the third approach taken in this project. Using oils from the CO-Wet database, experimental advances have been made in scaling the rate of imbibition, a sensitive measure of core wetting. Application of the scaling group to mixed-wet systems has been demonstrated for a range of core conditions. Investigations of imbibition in gas/liquid systems provided the motivation for theoretical advances as well. As a result of this project we have many new tools for studying

  13. (Chemistry of the global atmosphere)

    SciTech Connect (OSTI)

    Marland, G.

    1990-09-27

    The traveler attended the conference The Chemistry of the Global Atmosphere,'' and presented a paper on the anthropogenic emission of carbon dioxide (CO{sub 2}) to the atmosphere. The conference included meetings of the International Global Atmospheric Chemistry (IGAC) programme, a core project of the International Geosphere/Biosphere Programme (IGBP) and the traveler participated in meetings on the IGAC project Development of Global Emissions Inventories'' and agreed to coordinate the working group on CO{sub 2}. Papers presented at the conference focused on the latest developments in analytical methods, modeling and understanding of atmospheric CO{sub 2}, CO, CH{sub 4}, N{sub 2}O, SO{sub 2}, NO{sub x}, NMHCs, CFCs, and aerosols.

  14. Physics and Chemistry of Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Physics and Chemistry of Materials Developing new science and technologies needed for the national security of the United States by understanding how basic forces operating at the atomic level manifest themselves in the properties of matter at the macroscopic level. Molecular docking simulations The influence of small organic molecules on the operation and mechanism of electron transfer in enzymatic anodes. Molecular docking simulations The influence of small organic molecules on the operation

  15. DOE fundamentals handbook: Chemistry. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  16. 1987 wet deposition temporal and spatial patterns in North America

    SciTech Connect (OSTI)

    Simpson, J.C.; Olsen, A.R.

    1990-03-01

    The focus of this report is on North American wet deposition temporal patterns from 1979 to 1987 and spatial patterns for 1987. The report investigates the patterns of annual precipitation-weighted average concentration and annual deposition for nine ion species: hydrogen, sulfate, nitrate, ammonium, calcium, chloride, sodium, potassium, and magnesium. Data are from the Acid Deposition System (ADS) for the statistical reporting of North American deposition data which includes the National Atmospheric Deposition Program/National Trends Network (NADP/NTN), the MAP3S precipitation chemistry network, the Utility Acid Precipitation Study Program (UAPSP), the Canadian Precipitation Monitoring Network (CAPMoN), and the daily and 4-weekly Acidic Precipitation in Ontario Study (APIOS-D and APIOS-C). Mosaic maps, based on surface estimation using kriging, display concentration and deposition spatial patterns of pH, hydrogen, sulfate, nitrate, ammonium, and calcium ion species for 1987 annual, winter, and summer periods. The temporal pattern analyses use a subset of 39 sites over a 9-year (1979--1987) period and an expanded subset of 140 sites with greater spatial coverage over a 6-year (1982--1987) period. 68 refs., 15 figs., 15 tabs.

  17. Detecting bioterrorism: Is chemistry enough?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detecting bioterrorism: Is chemistry enough? Detecting bioterrorism: Is chemistry enough? In an online webinar, Kristin Omberg will offer discussion on the possibilities and ...

  18. SC e-journals, Chemistry

    Office of Scientific and Technical Information (OSTI)

    ... Acta Glass and Ceramics Global Biogeochemical Cycles Green Chemistry Helvetica Chimica Acta High Energy Chemistry High Temperature Hyle: International Journal for ...

  19. Seawater Chemistry Package

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    SeaChem Seawater Chemistry package provides routines to calculate pH, carbonate chemistry, density, and other quantities for seawater, based on the latest community standards. The chemistry is adapted from fortran routines provided by the OCMIP3/NOCES project, details of which are available at http://www.ipsl.jussieu.fr/OCMIP/. The SeaChem package can generate Fortran subroutines as well as Python wrappers for those routines. Thus the same code can be used by Python or Fortran analysis packages and Fortran ocean models alike.

  20. ,"New Mexico - West Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - West Natural Gas, Wet After Lease ... 8:56:27 AM" "Back to Contents","Data 1: New Mexico - West Natural Gas, Wet After Lease ...

  1. New York Natural Gas, Wet After Lease Separation Proved Reserves...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New York Natural Gas, ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 New York Natural ...

  2. ,"New Mexico Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico Nonassociated Natural Gas, Wet After ... 8:57:57 AM" "Back to Contents","Data 1: New Mexico Nonassociated Natural Gas, Wet After ...

  3. ,"New York Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Nonassociated Natural Gas, Wet After ... 8:57:57 AM" "Back to Contents","Data 1: New York Nonassociated Natural Gas, Wet After ...

  4. ,"New York Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Natural Gas, Wet After Lease ... 8:56:32 AM" "Back to Contents","Data 1: New York Natural Gas, Wet After Lease ...

  5. ,"New York Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New York Associated-Dissolved Natural Gas, Wet ... 8:59:18 AM" "Back to Contents","Data 1: New York Associated-Dissolved Natural Gas, Wet ...

  6. ,"New Mexico Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas, Wet After Lease ... 8:56:31 AM" "Back to Contents","Data 1: New Mexico Natural Gas, Wet After Lease ...

  7. ,"New Mexico - East Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...","Frequency","Latest Data for" ,"Data 1","New Mexico - East Natural Gas, Wet After Lease ... 8:56:26 AM" "Back to Contents","Data 1: New Mexico - East Natural Gas, Wet After Lease ...

  8. ,"U.S. Federal Offshore Nonassociated Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Nonassociated Natural Gas, Wet After ... "Back to Contents","Data 1: U.S. Federal Offshore Nonassociated Natural Gas, Wet After ...

  9. Wet Chemical Compositional and Near IR Spectra Data Sets for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Wet Chemical Compositional and Near IR Spectra Data ... Wet chemical compositional data and NIR spectra exist for the following types of biomass ...

  10. ,"Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ... AM" "Back to Contents","Data 1: Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ...

  11. ,"North Dakota Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Natural Gas, Wet After Lease ... 9:30:28 AM" "Back to Contents","Data 1: North Dakota Natural Gas, Wet After Lease ...

  12. Indian Centre for Wind Energy Technology C WET | Open Energy...

    Open Energy Info (EERE)

    Centre for Wind Energy Technology C WET Jump to: navigation, search Name: Indian Centre for Wind Energy Technology (C-WET) Place: Chennai, India Zip: 601 302 Sector: Wind energy...

  13. ,"Texas - RRC District 6 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 6 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 6 Natural Gas, Wet After ...

  14. ,"Texas - RRC District 5 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 5 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 5 Natural Gas, Wet After ...

  15. ,"Texas - RRC District 2 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 2 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 2 Onshore Natural Gas, Wet ...

  16. ,"Texas - RRC District 10 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 10 Natural Gas, Wet After ... 7:19:08 AM" "Back to Contents","Data 1: Texas - RRC District 10 Natural Gas, Wet After ...

  17. ,"Texas - RRC District 4 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 4 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 4 Onshore Natural Gas, Wet ...

  18. ,"Texas - RRC District 8 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 8 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 8 Natural Gas, Wet After ...

  19. ,"Texas - RRC District 9 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 9 Natural Gas, Wet After ... 7:19:08 AM" "Back to Contents","Data 1: Texas - RRC District 9 Natural Gas, Wet After ...

  20. ,"Texas - RRC District 1 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 1 Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 1 Natural Gas, Wet After ...

  1. ,"Texas - RRC District 3 Onshore Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 3 Onshore Natural Gas, Wet ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 3 Onshore Natural Gas, Wet ...

  2. Heat Transfer Characteristics of the Wet Thermal Insulator with Multi-layer

    SciTech Connect (OSTI)

    Jong-Won Kim; Goon-Cherl Park; Tae-Wan Kim; Doo-Jeong Lee

    2006-07-01

    SMART developed in KAERI is an integral type nuclear cogeneration reactor. SMART uses a nitrogen-filled gas pressurizer so that the steam partial pressure should be minimized and the pressurizer should be under low temperature condition. To sustain the low temperature condition, the wet thermal insulator and pressurizer cooler are installed in the pressurizer. Since the performance of wet thermal insulator is an important parameter to determine the size of the pressurizer cooler, it is important to evaluate the insulation performance of the wet thermal insulator. The wet thermal insulators with 20 layers are installed in SMART. In the design of SMART, the empirical correlation by Adamovich was used to estimate the thermal resistance of the wet thermal insulator. However, the experimental condition and results are not clear so that this correlation should be verified. To analyze the heat transfer characteristics of the multi-layer wet thermal insulator, natural convective heat transport through horizontal and vertical water-filled layers is investigated. Experiments and numerical analyses have been performed to evaluate the heat transfer rates through multi-layer and verify Adamovich correlation. In addition, a new multi-layer correlation was obtained. (authors)

  3. Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tank 48H Treatment Project (TTP) | Department of Energy Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Wet Air Oxidation. Technology Maturation Plan (TMP) Wet Air Oxidation (WAO)

  4. Controlling wet abrasion in power plants

    SciTech Connect (OSTI)

    Schumacher, W.J.

    1997-09-01

    Maintenance departments in many industries are continually battling the daily fires that run costs up and productivity down. Many plants have equipment that must operate under wet sliding conditions which can lead to accelerated wear of the equipment. Electric power generating plants, for example, have ongoing maintenance concerns for piping, chutes, hoppers, heat exchangers, and valves. Pulp and paper plants have heavy maintenance on: plate screens, conical bottoms of blow tanks, chutes, and augers. Coal handling equipment is often subjected to wet sliding conditions. Utility and coal prep plants can have serious flow problems if an improper structural or wear material is selected. Vibrating screens, chutes, surge bin feeders, conical distributors, screw conveyors, and cyclones are some of the components that must resist the ravages of corrosion and wear. This paper will address many of the issues that affect the life of plant components under wet sliding conditions. Environmental effects and material effects will be examined. Since the material of construction is most times the easier to change, the paper will concentrate on this subject. Such factors as: hardness, surface roughness, corrodent, and material of construction will be explored. Both controlled laboratory studies and real world service evaluations will be presented.

  5. Wetting properties of molecularly rough surfaces

    SciTech Connect (OSTI)

    Svoboda, Martin; Lísal, Martin; Malijevský, Alexandr

    2015-09-14

    We employ molecular dynamics simulations to study the wettability of nanoscale rough surfaces in systems governed by Lennard-Jones (LJ) interactions. We consider both smooth and molecularly rough planar surfaces. Solid substrates are modeled as a static collection of LJ particles arranged in a face-centered cubic lattice with the (100) surface exposed to the LJ fluid. Molecularly rough solid surfaces are prepared by removing several strips of LJ atoms from the external layers of the substrate, i.e., forming parallel nanogrooves on the surface. We vary the solid-fluid interactions to investigate strongly and weakly wettable surfaces. We determine the wetting properties by measuring the equilibrium droplet profiles that are in turn used to evaluate the contact angles. Macroscopic arguments, such as those leading to Wenzel’s law, suggest that surface roughness always amplifies the wetting properties of a lyophilic surface. However, our results indicate the opposite effect from roughness for microscopically corrugated surfaces, i.e., surface roughness deteriorates the substrate wettability. Adding the roughness to a strongly wettable surface shrinks the surface area wet with the liquid, and it either increases or only marginally affects the contact angle, depending on the degree of liquid adsorption into the nanogrooves. For a weakly wettable surface, the roughness changes the surface character from lyophilic to lyophobic due to a weakening of the solid-fluid interactions by the presence of the nanogrooves and the weaker adsorption of the liquid into the nanogrooves.

  6. IN-PACKAGE CHEMISTRY ABSTRACTION

    SciTech Connect (OSTI)

    E. Thomas

    2005-07-14

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.

  7. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A.

    1984-05-01

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  8. Analysis Of Post-Wet-Chemistry Heat Treatment Effects On Nb SRF...

    Office of Scientific and Technical Information (OSTI)

    The increase in quality factors is the result of the reduction of the surface resistance of the materials. A recent test on a 1.5 GHz single cell cavity made from ingot niobium of ...

  9. Lipid recovery from wet oleaginous microbial biomass for biofuel production: A critical review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dong, Tao; Knoshaug, Eric P.; Pienkos, Philip T.; Laurens, Lieve M. L.

    2016-06-15

    Biological lipids derived from oleaginous microorganisms are promising precursors for renewable biofuel productions. Direct lipid extraction from wet cell-biomass is favored because it eliminates the need for costly dehydration. However, the development of a practical and scalable process for extracting lipids from wet cell-biomass is far from ready to be commercialized, instead, requiring intensive research and development to understand the lipid accessibility, mechanisms in mass transfer and establish robust lipid extraction approaches that are practical for industrial applications. Furthermore, this paper aims to present a critical review on lipid recovery in the context of biofuel productions with special attention tomore » cell disruption and lipid mass transfer to support extraction from wet biomass.« less

  10. Reaction chemistry of cerium

    SciTech Connect (OSTI)

    1997-01-01

    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  11. In-Package Chemistry Abstraction

    SciTech Connect (OSTI)

    E. Thomas

    2004-11-09

    This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been

  12. Power generation characteristics of tubular type SOFC by wet process

    SciTech Connect (OSTI)

    Tajiri, H.; Nakayama, T.; Kuroishi, M.

    1996-12-31

    The development of a practical solid oxide fuel cell requires improvement of a cell performance and a cell manufacturing technology suitable for the mass production. In particular tubular type SOFC is thought to be superior in its reliability because its configuration can avoid the high temperature sealing and reduce the thermal stress resulting from the contact between cells. The authors have fabricated a tubular cell with an air electrode support by a wet processing technique, which is suitable for mass production in improving a power density. To enhance the power output of the module, the Integrated Tubular-Type (ITT) cell has been developed. This paper reports the performance of the single cells with various active anode areas and the bundle with series-connected 9-ITT cells with an active anode area of 840 cm{sup 2}.

  13. Performance of dehumidifying heat exchangers with and without wetting coatings

    SciTech Connect (OSTI)

    Hong, K.; Webb, R.L.

    1999-11-01

    Limited previous work has shown that use of special hydrophilic coatings will provide lower air pressure drop in finned tube heat exchangers operated under dehumidifying conditions. However, no detailed work has been reported on the effect of different coating types, or different fin surface geometries on the wet pressure drop. In this study, wind tunnel tests were performed on three different fin geometries (wavy, lanced, and louver) under wet and dry conditions. All dehumidification tests were done for fully wet surface conditions. For each geometry, the tests were performed on uncoated and coated heat exchangers. For all three fin geometries, the wet-to-dry pressure drop ratio was 1.2 at 2.5 m/s frontal air velocity. The coatings have no influence on the wet or dry heat transfer coefficient. However, the wet surface heat transfer coefficient was 10 to 30% less than the dry heat transfer coefficient, depending on the particular fin geometry. The effect of the fin press oil on wet pressure drop was also studied. If the oil contains a surfactant, good temporary wetting can be obtained on an uncoated surface; however, this effect is quickly degraded as the oil is washed from the surface during wet operation. This work also provides a critical assessment of data reduction methods for wet surface operation, including calculation of the fin efficiency.

  14. Sandia National Laboratories: Careers: Chemistry & Chemical Engineering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry & Chemical Engineering Chemistry research photo Sandia's Combustion Research Facility pioneered the use of chemical-imaging tools, such as laser diagnostics, for combustion applications. Chemists at Sandia conduct research and development at the interface between biology, synthetic chemistry, and surface science to deliver prototype solutions in diverse applications. They provide knowledge about materials structure, properties, and performance and about the processes to produce,

  15. Chemistry and Transport - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Transport Chemistry and Transport The overall goal of the flame chemistry working group is to obtain fundamental combustion and emission properties of low and high pressure flames, to validate kinetic and transport models, and to develop accurate and computationally efficient models capable of predicting turbulent combustion of future transportation fuels. Experimental data of laminar and turbulent flame speeds, flame structures, extinction/ignition limits, and soot/NOx emissions

  16. Microbial Enhanced Oil Recovery in Fractional-Wet Systems: A Pore-Scale Investigation

    SciTech Connect (OSTI)

    Armstrong, Ryan T.; Wildenschild, Dorthe

    2012-10-24

    Microbial enhanced oil recovery (MEOR) is a technology that could potentially increase the tertiary recovery of oil from mature oil formations. However, the efficacy of this technology in fractional-wet systems is unknown, and the mechanisms involved in oil mobilization therefore need further investigation. Our MEOR strategy consists of the injection of ex situ produced metabolic byproducts produced by Bacillus mojavensis JF-2 (which lower interfacial tension (IFT) via biosurfactant production) into fractional-wet cores containing residual oil. Two different MEOR flooding solutions were tested; one solution contained both microbes and metabolic byproducts while the other contained only the metabolic byproducts. The columns were imaged with X-ray computed microtomography (CMT) after water flooding, and after MEOR, which allowed for the evaluation of the pore-scale processes taking place during MEOR. Results indicate that the larger residual oil blobs and residual oil held under relatively low capillary pressures were the main fractions recovered during MEOR. Residual oil saturation, interfacial curvatures, and oil blob sizes were measured from the CMT images and used to develop a conceptual model for MEOR in fractional-wet systems. Overall, results indicate that MEOR was effective at recovering oil from fractional-wet systems with reported additional oil recovered (AOR) values between 44 and 80%; the highest AOR values were observed in the most oil-wet system.

  17. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) ...

  18. Analytical Chemistry Laboratory | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Laboratory provides a broad range of analytical chemistry support services to the scientific and engineering programs. AnalyticalChemistryLaboratoryfactsheet...

  19. Cavitation as a Mechanism to Enhance Wetting in a Mercury Thermal Convection Loop

    SciTech Connect (OSTI)

    Pawel, SJ

    2001-07-17

    Type 316L stainless steel was statically tested under cavitation conditions via an ultrasonic transducer externally mounted on a tube filled with ambient mercury. During the preliminary exposure (24 h, 20 kHz, 1.5 MPa), cavitation resulted in apparent wetting of the specimens by mercury as well as general surface roughening and wastage similar to erosion damage. Subsequently, a thermal convection loop identical to those used previously to study thermal gradient mass transfer was modified to include an externally-mounted donut-shaped transducer in order to similarly produce cavitation and wetting at temperatures prototypic of those expected in the SNS target. However, a series of attempts to develop cavitation and wetting on 316L specimens in the thermal convection loop was unsuccessful.

  20. LA-2271 CHEMISTRY-GENERAL

    Office of Scientific and Technical Information (OSTI)

    2271 CHEMISTRY-GENERAL TID-4500, 14th Ed. LOS ALAMOS SCIENTIFIC LABORATORY OF THE ... U in Vol. n of A Treatise on Physical Chemistry, edited by H. S. Taylor and S. ...

  1. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  2. BERYLLIUM MEASUREMENT IN COMMERCIALLY AVAILABLE WET WIPES

    SciTech Connect (OSTI)

    Youmans-Mcdonald, L.

    2011-02-18

    Analysis for beryllium by fluorescence is now an established method which is used in many government-run laboratories and commercial facilities. This study investigates the use of this technique using commercially available wet wipes. The fluorescence method is widely documented and has been approved as a standard test method by ASTM International and the National Institute for Occupational Safety and Health (NIOSH). The procedure involves dissolution of samples in aqueous ammonium bifluoride solution and then adding a small aliquot to a basic hydroxybenzoquinoline sulfonate fluorescent dye (Berylliant{trademark} Inc. Detection Solution Part No. CH-2) , and measuring the fluorescence. This method is specific to beryllium. This work explores the use of three different commercial wipes spiked with beryllium, as beryllium acetate or as beryllium oxide and subsequent analysis by optical fluorescence. The effect of possible interfering metals such as Fe, Ti and Pu in the wipe medium is also examined.

  3. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  4. W.E.T. Automotive Systems | Open Energy Information

    Open Energy Info (EERE)

    E.T. Automotive Systems Jump to: navigation, search Name: W.E.T. Automotive Systems Place: Odelzhausen, Germany Information About Partnership with NREL Partnership with NREL Yes...

  5. Challenges and Opportunities for Wet-Waste Feedstocks - Resource...

    Office of Environmental Management (EM)

    and Opportunities for Advanced Biofuels from Wet-Waste Feedstocks Challenges and ... Thermochemical Conversion, Nutrient Recycling, and Wastewater Pathways for Algal Biofuels

  6. New Mexico Natural Gas Wet After Lease Separation, Reserves in...

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) New Mexico Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion...

  7. ,"New Mexico Nonassociated Natural Gas Proved Reserves, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation",10,"Annual",201...

  8. Texas State Offshore Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved ... Separation, as of Dec. 31 TX, State Offshore Nonassociated Natural Gas Proved ...

  9. Texas State Offshore Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved ... Separation, as of Dec. 31 TX, State Offshore Associated-Dissolved Natural Gas Proved ...

  10. Louisiana State Offshore Nonassociated Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Louisiana State Offshore Nonassociated Natural Gas, Wet After ... Separation, as of Dec. 31 LA, State Offshore Nonassociated Natural Gas Proved ...

  11. Louisiana State Offshore Associated-Dissolved Natural Gas, Wet...

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Louisiana State Offshore Associated-Dissolved Natural Gas, Wet ... Separation, as of Dec. 31 LA, State Offshore Associated-Dissolved Natural Gas Proved ...

  12. Observation of Ordered Structures in Counterion Layers near Wet...

    Office of Scientific and Technical Information (OSTI)

    Title: Observation of Ordered Structures in Counterion Layers near Wet Charged Surfaces: A Potential Mechanism for Charge Inversion Authors: Miller, Mitchell ; Chu, Miaoqi ; Lin, ...

  13. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves from Greater than 200 Meters Deep (Percent) Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than...

  14. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Less than 200 Meters Deep (Billion Cubic...

  15. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Greater than 200 Meters Deep (Billion...

  16. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Less than 200 Meters Deep (Billion...

  17. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Production from Greater than 200 Meters Deep (Percent) Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet After Lease Separation, Production from Greater than 200...

  18. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than 200 Meters Deep...

  19. High Pressure Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  20. Chemistry of Autoignition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Autoignition - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  1. RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL

    Office of Scientific and Technical Information (OSTI)

    The early days Richards, P. 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL ASPECTS; TECHNETIUM 99; COLLOIDS; MOLYBDENUM...

  2. Extensible Computational Chemistry Environment

    Energy Science and Technology Software Center (OSTI)

    2012-08-09

    ECCE provides a sophisticated graphical user interface, scientific visualization tools, and the underlying data management framework enabling scientists to efficiently set up calculations and store, retrieve, and analyze the rapidly growing volumes of data produced by computational chemistry studies. ECCE was conceived as part of the Environmental Molecular Sciences Laboratory construction to solve the problem of researchers being able to effectively utilize complex computational chemistry codes and massively parallel high performance compute resources. Bringing themore » power of these codes and resources to the desktops of researcher and thus enabling world class research without users needing a detailed understanding of the inner workings of either the theoretical codes or the supercomputers needed to run them was a grand challenge problem in the original version of the EMSL. ECCE allows collaboration among researchers using a web-based data repository where the inputs and results for all calculations done within ECCE are organized. ECCE is a first of kind end-to-end problem solving environment for all phases of computational chemistry research: setting up calculations with sophisticated GUI and direct manipulation visualization tools, submitting and monitoring calculations on remote high performance supercomputers without having to be familiar with the details of using these compute resources, and performing results visualization and analysis including creating publication quality images. ECCE is a suite of tightly integrated applications that are employed as the user moves through the modeling process.« less

  3. Selenium Speciation and Management in Wet FGD Systems

    SciTech Connect (OSTI)

    Searcy, K; Richardson, M; Blythe, G; Wallschlaeger, D; Chu, P; Dene, C

    2012-02-29

    This report discusses results from bench- and pilot-scale simulation tests conducted to determine the factors that impact selenium speciation and phase partitioning in wet FGD systems. The selenium chemistry in wet FGD systems is highly complex and not completely understood, thus extrapolation and scale-up of these results may be uncertain. Control of operating parameters and application of scrubber additives have successfully demonstrated the avoidance or decrease of selenite oxidation at the bench and pilot scale. Ongoing efforts to improve sample handling methods for selenium speciation measurements are also discussed. Bench-scale scrubber tests explored the impacts of oxidation air rate, trace metals, scrubber additives, and natural limestone on selenium speciation in synthetic and field-generated full-scale FGD liquors. The presence and concentration of redox-active chemical species as well as the oxidation air rate contribute to the oxidation-reduction potential (ORP) conditions in FGD scrubbers. Selenite oxidation to the undesirable selenate form increases with increasing ORP conditions, and decreases with decreasing ORP conditions. Solid-phase manganese [Mn(IV)] appeared to be the significant metal impacting the oxidation of selenite to selenate. Scrubber additives were tested for their ability to inhibit selenite oxidation. Although dibasic acid and other scrubber additives showed promise in early clear liquor (sodium based and without calcium solids) bench-scale tests, these additives did not show strong inhibition of selenite oxidation in tests with higher manganese concentrations and with slurries from full-scale wet FGD systems. In bench-tests with field liquors, addition of ferric chloride at a 250:1 iron-to-selenium mass ratio sorbed all incoming selenite to the solid phase, although addition of ferric salts had no impact on native selenate that already existed in the field slurry liquor sample. As ORP increases, selenite may oxidize to selenate more

  4. A round robin evaluation of the corrosiveness of wet residential insulation by electrochemical measurements

    SciTech Connect (OSTI)

    Stansbury, E.E. , Knoxville, TN )

    1991-10-01

    The results of a round cabin evaluation of the use of an electrochemical method of calculating the corrosion rate of low carbon steel in environments related to cellulosic building insulations are reported. Environments included the leachate from a wet cellulosic insulation and solutions based on pure and commercial grades of borax, ammonium sulfate and aluminum sulfate. The pH values of these environments were in the range of 2.5 to 9.5. Electrochemical measurements were made using a direct reading corrosion rate instrument. The calculated corrosion rates were compared with those determined directly by weight loss measurements. Electrochemical measurements were made over a period of 48 hours and weight loss exposures were for two weeks. Poor agreement was observed for the corrosion rates determined electrochemically and the values were consistently larger than those based on weight loss. Reasons proposed for these results included the complex nature of the corrosion product deposits and the control these deposits have on oxygen diffusion to the metal interface. Both factors influence the validity of the calculation of the corrosion rate by the direct reading instrument. It was concluded that development of a viable electrochemical method of general applicability to the evaluation of the corrosiveness of wet residential building thermal insulations were doubtful. Because of the controlling influence of dissolved oxygen on the corrosion rate in the insulation leachate, an alternate evaluation method is proposed in which a thin steel specimen is partially immersed in wet insulation for three weeks. The corrosiveness of the wet insulation is evaluated in terms of the severity of attack near the metal-air-wet insulation interface. With thin metal specimens, complete penetration along the interface is proposed as a pass/fail criterion. An environment of sterile cotton wet with distilled water is proposed as a comparative standard. 9 refs., 2 figs., 3 tabs.

  5. Method for wetting a boron alloy to graphite

    DOE Patents [OSTI]

    Storms, E.K.

    1987-08-21

    A method is provided for wetting a graphite substrate and spreading a a boron alloy over the substrate. The wetted substrate may be in the form of a needle for an effective ion emission source. The method may also be used to wet a graphite substrate for subsequent joining with another graphite substrate or other metal, or to form a protective coating over a graphite substrate. A noneutectic alloy of boron is formed with a metal selected from the group consisting of nickel (Ni), palladium (Pd), and platinum (Pt) with excess boron, i.e., and atomic percentage of boron effective to precipitate boron at a wetting temperature of less than the liquid-phase boundary temperature of the alloy. The alloy is applied to the substrate and the graphite substrate is then heated to the wetting temperature and maintained at the wetting temperature for a time effective for the alloy to wet and spread over the substrate. The excess boron is evenly dispersed in the alloy and is readily available to promote the wetting and spreading action of the alloy. 1 fig.

  6. SPONTANEOUS CATALYTIC WET AIR OXIDATION DURING PRE-TREATMENT OF HIGH-LEVEL RADIOACTIVE WASTE SLUDGE

    SciTech Connect (OSTI)

    Koopman, D.; Herman, C.; Pareizs, J.; Bannochie, C.; Best, D.; Bibler, N.; Fellinger, T.

    2009-10-01

    Savannah River Remediation, LLC (SRR) operates the Defense Waste Processing Facility for the U.S. Department of Energy at the Savannah River Site. This facility immobilizes high-level radioactive waste through vitrification following chemical pretreatment. Catalytic destruction of formate and oxalate ions to carbon dioxide has been observed during qualification testing of non-radioactive analog systems. Carbon dioxide production greatly exceeded hydrogen production, indicating the occurrence of a process other than the catalytic decomposition of formic acid. Statistical modeling was used to relate the new reaction chemistry to partial catalytic wet air oxidation of both formate and oxalate ions driven by the low concentrations of palladium, rhodium, and/or ruthenium in the waste. Variations in process conditions led to increases or decreases in the total oxidative destruction, as well as partially shifting the preferred species undergoing destruction from oxalate ion to formate ion.

  7. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

    SciTech Connect (OSTI)

    Beltrami, Denis; Cote, Grard; Mokhtari, Hamid; Courtaud, Bruno; Moyer, Bruce A; Chagnes, Alexandre

    2014-01-01

    Between 1951 and 1991, about 17 processes were developed to recover uranium from wet phosphoric acid (WPA), but the viability of these processes was subject to the variation of the uranium price market. Nowadays, uranium from WPA appears to be attractive due to the increase of the global uranium demand resulting from the emergence of developing countries. The increasing demand provides impetus for a new look at the applicable technology with a view to improvements as well as altogether new approaches. This paper gives an overview on extraction processes developed in the past to recover uranium from wet phosphoric acid (WPA) as well as the physicochemistry involved in these processes. Recent advances concerning the development of new extraction systems are also reported and discussed.

  8. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

    SciTech Connect (OSTI)

    Beltrami, Denis; Cote, Gérard; Mokhtari, Hamid; Courtaud, Bruno; Moyer, Bruce A.; Chagnes, Alexandre

    2014-11-17

    Between 1951 and 1991, we developed about 17 processes to recover uranium from wet phosphoric acid (WPA), but the viability of these processes was subject to the variation of the uranium price market. Nowadays, uranium from WPA appears to be attractive due to the increase of the global uranium demand resulting from the emergence of developing countries. Moreover, the increasing demand provides impetus for a new look at the applicable technology with a view to improvements as well as altogether new approaches. This paper gives an overview on extraction processes developed in the past to recover uranium from wet phosphoric acid (WPA) as well as the physicochemistry involved in these processes. Recent advances concerning the development of new extraction systems are also reported and discussed.

  9. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beltrami, Denis; Cote, Gérard; Mokhtari, Hamid; Courtaud, Bruno; Moyer, Bruce A.; Chagnes, Alexandre

    2014-11-17

    Between 1951 and 1991, we developed about 17 processes to recover uranium from wet phosphoric acid (WPA), but the viability of these processes was subject to the variation of the uranium price market. Nowadays, uranium from WPA appears to be attractive due to the increase of the global uranium demand resulting from the emergence of developing countries. Moreover, the increasing demand provides impetus for a new look at the applicable technology with a view to improvements as well as altogether new approaches. This paper gives an overview on extraction processes developed in the past to recover uranium from wet phosphoricmore » acid (WPA) as well as the physicochemistry involved in these processes. Recent advances concerning the development of new extraction systems are also reported and discussed.« less

  10. Challenges of tomorrow. chemistry

    SciTech Connect (OSTI)

    Steindler, M.J. )

    1989-11-01

    According to the author, nuclear materials are going to play an increasing role in concerns regarding proliferation and international affair, with an increased demand for clean electric power, and in environmental and health and safety issues. Challenges range from detecting a single species in a sea of others at molar ratios of 10-{sup 12}, or smaller, to a knowledge of the fundamental physical chemistry (e.g., thermodynamics, activity coefficients, etc., of a two phase system, containing about 40 materials, at 500{sup 0}C) for the lanthanide and actinide elements produced during reactor operation. Other concerns are identified and discussed.

  11. Henry Taube and Coordination Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Henry Taube and Coordination Chemistry Resources with Additional Information Henry Taube Chuck Painter/Stanford News Service Henry Taube, a Marguerite Blake Wilbur Professor of Chemistry, Emeritus, at Stanford University, received the 1983 Nobel Prize in Chemistry "for his work on the mechanisms of electron transfer reactions, especially in metal complexes" Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I

  12. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry » Synthetic and Mechanistic Synthetic and Mechanistic publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this century.

  13. Heat removal (wetting, heat transfer, T/H, secondary circuit, code validation etc.)

    SciTech Connect (OSTI)

    Dury, T.; Siman-Tov, M.

    1996-06-01

    This working group provided a comprehensive list of feasibility and uncertainty issues. Most of the issues seem to fall into the `needed but can be worked out` category. They feel these can be worked out as the project develops. A few issues can be considered critical or feasibility issues (that must be proven to be feasible). Those include: (1) Thermal shock and its mitigation (>1 MW); how to inject the He bubbles (if used) - back pressure into He lines - mercury traces in He lines; how to maintain proper bubble distribution and size (static and dynamic; if used); vibrations and fatigue (dynamic); possibility of cavitation from thermal shock. (2) Wetting and/or non-wetting of mercury on containment walls with or without gases and its effect on heat transfer (and materials). (3) Prediction capabilities in the CFD code; bubbles behavior in mercury (if used) - cross stream turbulence (ESS only) - wetting/non-wetting effects. (4) Cooling of beam `windows`; concentration of local heat deposition at center, especially if beam is of parabolic profile.

  14. Enhanced NO{sub x} removal in wet scrubbers using metal chelates. Final report, Volume 1

    SciTech Connect (OSTI)

    Smith, K.; Lani, B.; Berisko, D.; Schultz, C.; Carlson, W.; Benson, L.B.

    1992-12-01

    Successful pilot plant tests of simultaneous removal of S0{sub 2} and NO{sub x} in a wet lime flue gas desulfurization system were concluded in December. The tests, at up to 1.5 MW(e) capacity, were conducted by the Cincinnati Gas and Electric Company and Dravo Lime Company for the US Department of Energy at a pilot facility at the Miami Fort station of CG&E near Cincinnati, Ohio. The pilot plant scrubbed a slipstream of flue gas from Unit 7, a 530 MW coal-fired electric generating unit. Tests were conducted in three phases between April and December. The technology tested was wet scrubbing with Thiosorbic{reg_sign} magnesium-enhanced lime for S0{sub 2} removal and simultaneous NO scrubbing with ferrous EDTA, a metal chelate. Magnesium-enhanced lime-based wet scrubbing is used at 20 full-scale high-sulfur coal-fired electric generating units with a combined capacity of 8500 NW. Ferrous EDTA reacts with nitric oxide, NO, which comprises about 95% of NO{sub x} from coal-fired boilers. In this report, although not precise, NO and NO{sub x} are used interchangably. A major objective of the tests was to combine NO{sub x} removal using ferrous EDTA, a developing technology, with SO{sub 2} removal using wet lime FGD, already in wide commercial use. If successful, this could allow wide application of this NO{sub x} removal technology.

  15. Update On Aquatic Toxicity/Whole Effluent Toxicity (WET) Issues, 2005

    SciTech Connect (OSTI)

    Specht, Winona L

    2005-07-01

    This paper summarizes recent changes in the field of aquatic toxicity/Whole Effluent Toxicity (WET) testing. There are been numerous legal challenges to the validity of WET testing, both at the federal and state levels, but to date, the regulators have prevailed and WET testing is used as a regulatory tool to ensure that the biota of receiving streams are protected. The most recent ruling at the federal level was on December 10, 2004, when a federal appeals court in the District of Columbia upheld the validity of WET testing. At the state level, at the urging of the South Carolina Manufacturers Alliance, the state legislature passed a law (the South Carolina Aquatic Life Protection Act) in 2004 that requires the South Carolina Department of Health and Environmental Control (DHEC) to evaluate the accuracy and precision of the WET test. As a result, SCDHEC removed WET test limits from several NPDES permits. EPA took issue with the impact of the legislation and SCDHEC's actions, and as a result, EPA has taken over several NPDES permits from SCDHEC and threatened to revoke the state's delegated NPDES permit program. A new Act was signed into law in March 2005, which does not exclude the use of chronic toxicity testing for regulatory compliance. As a result, EPA has turned over the issuance of NPDES permits back to SCDHEC. In December 2004, the U.S. EPA issued the Draft National WET Implementation Guidance document for review and comment. The guidance contains recommendations on the determination of ''reasonable potential'' for toxicity. The EPA's ECOTOX database is a valuable resource of toxicity data for many chemicals. For those cases in which there are no toxicity data or very limited data available, the EPA has developed two models, the Interspecies Correlation Estimation (ICE) and the Acute to Chronic Estimation (ACE), for predicting toxicity. Active areas of research include assessing the uptake of heavy metals via multiple routes of exposure, the development of

  16. MHK Technologies/WET EnGen | Open Energy Information

    Open Energy Info (EERE)

    Test of Wave Energy Technologies Moored Floating WET EnGen: Regular and Irregular Waves. TR-2009-13, Fraser Winsor and Emile Baddour, June 2009. Date Submitted 1082010 << Return...

  17. ,"Crude Oil and Lease Condensate","Wet Natural Gas"

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. proved reserves, and reserves changes, 2013-2014" ,"Crude Oil and Lease Condensate","Wet Natural Gas" ,"billion barrels","trillion cubic feet" "U.S. proved reserves at...

  18. Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet ... as of Dec. 31 Federal Offshore, Gulf of Mexico, Texas Natural Gas Reserves Summary as of ...

  19. New Mexico - West Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 ...

  20. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  1. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  2. New York Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    New York Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 New York Associated-Dissolved Natural Gas ...

  3. ,"U.S. Nonassociated Natural Gas Proved Reserves, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Proved Reserves, Wet After Lease Separation" ,"Click worksheet name or tab at bottom ... Gas Proved Reserves, Wet After Lease Separation",10,"Annual",2014,"06301979" ...

  4. ,"U.S. Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet ... 1","U.S. Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic ...

  5. ,"U.S. Natural Gas Proved Reserves, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves, Wet After Lease Separation" ,"Click worksheet name or tab at bottom for ... Gas Proved Reserves, Wet After Lease Separation",10,"Annual",2014,"06301979" ...

  6. Department of Chemistry | Center for Catalytic HydrocarbonFunctionali...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars ... electrochemistry, bioinorganic chemistry, materials chemistry and quantum mechanics. ...

  7. Nebraska Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Associated-Dissolved Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 Nebraska Associated-Dissolved Natural

  8. Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Nonassociated Natural Gas Proved Reserves,

  9. Analytical Chemistry and Measurement Science: (What Has DOE Done for Analytical Chemistry?)

    DOE R&D Accomplishments [OSTI]

    Shults, W. D.

    1989-04-01

    Over the past forty years, analytical scientists within the DOE complex have had a tremendous impact on the field of analytical chemistry. This paper suggests six "high impact" research/development areas that either originated within or were brought to maturity within the DOE laboratories. "High impact" means they lead to new subdisciplines or to new ways of doing business.

  10. Analytical chemistry and measurement science; (What DOE has done for analytical chemistry)

    SciTech Connect (OSTI)

    Shults, W.D. . Analytical Chemistry Div.)

    1989-11-01

    Over the past forty years, analytical scientists within the Department of Energy (DOE) complex have had impact on the field of analytical chemistry. This paper suggests six research/development areas that either originated within or were brought to maturity with the DOE laboratories. These areas have lead to new subdisciplines or to new ways of doing business.

  11. Challenges and Opportunities for Wet-Waste Feedstocks…Resource Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Opportunities for Wet-Waste Feedstocks - Resource Assessment CORINNE DRENNAN July 15, 2015 PNNL- 1 Energy and Environment Directorate corinne.drennan@pnnl.gov Bioenergy 2015 24 June 2015 BETO Waste-to-Energy Efforts There is a significant near-term market entry opportunity to develop WTE technologies in the U.S., specifically with regard to anaerobic digestion at landfills to recycle organic waste biomass into renewable energy, thereby enabling a national network of distributed power and

  12. Chemistry for Measurement and Detection Science publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science » Chemistry for Measurement and Detection Science publications Chemistry for Measurement and Detection Science publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of

  13. Exhaust Phosphorous Chemistry and Catalyst Poisoning | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry and Catalyst Poisoning Exhaust Phosphorous Chemistry and Catalyst Poisoning 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Oak Ridge National ...

  14. NREL: Transportation Research - Fuel Chemistry Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Research Photo of a hand holding a beaker containing a clear yellow liquid. NREL ... Photo by Dennis Schroeder, NREL NREL's fuel chemistry research explores how biofuels, ...

  15. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home News & Publications News Center News Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, ...

  16. Computational Actinide Chemistry: Reliable Predictions and New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Actinide Chemistry: Reliable Predictions and New Concepts PI Name: David ... 100 Million Year: 2014 Research Domain: Chemistry The project will obtain some of the ...

  17. Redox Chemistry of Anthraquinone Derivatives Via Simulations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 27, 2014, Research Highlights Redox Chemistry of Anthraquinone Derivatives Via ... S. Assary, Investigation of the Redox Chemistry of Anthraquinone Derivatives Using ...

  18. Understanding and Manipulating Solution Chemistry of Polysulfides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding and Manipulating Solution Chemistry of Polysulfides for Lithium Sulfur Batteries (Top)Fundamental details regarding the solution chemistry of polysulfides in organic ...

  19. Chemistry and Material Sciences Codes at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Codes Chemistry and Material Sciences Codes at NERSC April 6, 2011 Last edited: 2016-04-29 11:35:1

  20. Design of the national trends network for monitoring the chemistry of atmospheric precipitation

    SciTech Connect (OSTI)

    Robertson, J.K.; Wilson, J.W.

    1985-01-01

    Long-term monitoring (10 years minimum) of the chemistry of wet deposition will be conducted at National Trends Network (NTN) sites across the United States. Precipitation samples will be collected at sites that represent broad regional characteristics. Design of the NTN considered four basic elements during construction of a model to distribute 50, 75, 100, 125 or 150 sites. The modeling oriented design was supplemented with guidance developed during the course of the site selection process. Ultimately, a network of 151 sites was proposed. The basic elements of the design are: assurance that all areas of the country are represented in the network on the basis of regional ecological properties (96 sites); placement of additional sites east of the Rocky Mountains to better define high deposition gradients (27 sites); placement of sites to assure that potentially sensitive regions are represented (15 sites); and placement of sites to allow for other considerations such as urban area effects (5 sites), intercomparison with Canada (3 sites), and apparent disparities in regional coverage (5 sites). Site selection stressed areas away from urban centers, large point sources, or ocean influences. Local factors, such as stable land ownership, nearby small emission sources (about 10 km), and close-by roads and fireplaces (about 0.5 km) were also considered. All proposed sites will be visited as part of the second phase of the study. 29 refs., 18 figs.

  1. Analytical Chemistry Laboratory progress report for FY 1991

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Graczyk, D.G.; Lindahl, P.C.; Boparai, A.S.

    1991-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year 1991 (October 1990 through September 1991). This is the eighth annual report for the ACL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. In addition, the ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques.

  2. Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Chemistry during LNT Regeneration for a Lean Gasoline Engine Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. p-09_parks.pdf (507.29 KB) More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Emissions Control for Lean

  3. Modeling the Explicit Chemistry of Anthropogenic and Biogenic Organic Aerosols

    SciTech Connect (OSTI)

    Madronich, Sasha

    2015-12-09

    The atmospheric burden of Secondary Organic Aerosols (SOA) remains one of the most important yet uncertain aspects of the radiative forcing of climate. This grant focused on improving our quantitative understanding of SOA formation and evolution, by developing, applying, and improving a highly detailed model of atmospheric organic chemistry, the Generation of Explicit Chemistry and Kinetics of Organics in the Atmosphere (GECKO-A) model. Eleven (11) publications have resulted from this grant.

  4. Surveillance of LWR spent fuel in wet storage. Final report, October 1984

    SciTech Connect (OSTI)

    Bailey, W.J.; Johnson, A.B. Jr.

    1984-10-01

    Battelle, Pacific Northwest Laboratories established a surveillance program for EPRI that documents the integrity of spent light-water reactor fuel and structural materials (spent fuel storage pool liners, racks, piping, etc.) during wet storage. The program involves providing an update on the overall performance of spent fuel in wet storage, monitoring Licensee Event Reports (LERs) for pertinent significant occurrences, identifying lead spent fuel assemblies that are of particular interest to EPRI, monitoring developments in fuel design and performance and assessing their influence on spent fuel storage characteristics, and identifying specific actions or programs that may be needed to maintain the viability of wet storage of spent fuel for extended periods. Experience to date indicates that wet storage is a well-developed technology with no associated major technological problems. Spent fuel storage pools are operated without substantial risk to the public or the plant personnel. A list of lead spent fuel assemblies is presented. Pertinent occurrences from LERs are listed. Very few fuel assemblies have suffered major mechanical damage as a result of handling operations at spent fuel storage pools. Experience to date with handling operations at spent fuel storage pools indicates that failed fuel rods and inadvertent fracturing of fuel rods can be accommodated. Minor problems have occurred with spent fuel storage pool components such as liners, racks, and piping. Surveillance continues to be needed on: (1) possible effects on handling and storage of spent fuel from extended burnup, hydrogen injection at boiling water reactors, and rod consolidation operations; (2) extended pool exposure of neutron-absorbing materials; (3) cracking of spent fuel storage pool piping at pressurized water reactors; and (4) control of impurities in spent fuel pool waters. 120 references, 13 figures, 10 tables.

  5. National Nuclear Chemistry Summer School

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding is provided by the US Department of Energy.

  6. National Nuclear Chemistry Summer School

    Office of Energy Efficiency and Renewable Energy (EERE)

    he Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding...

  7. Hot atom chemistry and radiopharmaceuticals

    SciTech Connect (OSTI)

    Krohn, Kenneth A.; Moerlein, Stephen M.; Link, Jeanne M.; Welch, Michael J.

    2012-12-19

    The chemical products made in a cyclotron target are a combined result of the chemical effects of the nuclear transformation that made the radioactive atom and the bulk radiolysis in the target. This review uses some well-known examples to understand how hot atom chemistry explains the primary products from a nuclear reaction and then how radiation chemistry is exploited to set up the optimal product for radiosynthesis. It also addresses the chemical effects of nuclear decay. There are important principles that are common to hot atom chemistry and radiopharmaceutical chemistry. Both emphasize short-lived radionuclides and manipulation of high specific activity nuclides. Furthermore, they both rely on radiochromatographic separation for identification of no-carrieradded products.

  8. Henry Taube and Coordination Chemistry

    Office of Scientific and Technical Information (OSTI)

    Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I became deeply interested in chemistry soon after I came ...

  9. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

    2010-12-31

    This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed

  10. Nuclear Science/Nuclear Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nuclear science nuclear chemistry Nuclear Science/Nuclear Chemistry Nuclear Physics The 10-MV tandem accelerator at CAMS provides a platform for conducting nuclear physics experiment both for basic science and lab mission-related programs. For example, we performed a new cross section measurement of the astrophysically important reaction 40Ca(a,g)44Ti in which high purity CaO targets were irradiated with helium ions at several different discrete energies. The reaction rate was measured on-line

  11. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADCLES Chemistry, Life, and Earth Sciences The CLES Directorate is home to world class capabilities in chemistry, bioscience, and earth and environmental sciences. Structural protein research Structural protein research A wide range of protein folding research Field Instrument Deployments and Operations (FIDO) Field Instrument Deployments and Operations (FIDO) Atmospheric science research Quantum Dots Quantum Dots Quantum dot research for energy and light Contact Us Associate Director Nan Sauer

  12. Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 13 1980's 23 25 1990's 25 23 30 46 56 44 38 30 28 27 2000's 29 26 31 32 32 29 18 20 19 29 2010's 38 48 100 46 141 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Electro-osmotic transport in wet processing of textiles

    DOE Patents [OSTI]

    Cooper, John F.

    1998-01-01

    Electro-osmotic (or electrokinetic) transport is used to efficiently force a solution (or water) through the interior of the fibers or yarns of textile materials for wet processing of textiles. The textile material is passed between electrodes that apply an electric field across the fabric. Used alone or in parallel with conventional hydraulic washing (forced convection), electro-osmotic transport greatly reduces the amount of water used in wet processing. The amount of water required to achieve a fixed level of rinsing of tint can be reduced, for example, to 1-5 lbs water per pound of fabric from an industry benchmark of 20 lbs water/lb fabric.

  14. Electro-osmotic transport in wet processing of textiles

    DOE Patents [OSTI]

    Cooper, J.F.

    1998-09-22

    Electro-osmotic (or electrokinetic) transport is used to efficiently force a solution (or water) through the interior of the fibers or yarns of textile materials for wet processing of textiles. The textile material is passed between electrodes that apply an electric field across the fabric. Used alone or in parallel with conventional hydraulic washing (forced convection), electro-osmotic transport greatly reduces the amount of water used in wet processing. The amount of water required to achieve a fixed level of rinsing of tint can be reduced, for example, to 1--5 lbs water per pound of fabric from an industry benchmark of 20 lbs water/lb fabric. 5 figs.

  15. Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 166 1980's 194 184 174 194 189 157 150 145 157 145 1990's 67 136 133 93 85 104 89 56 38 41 2000's 39 30 38 37 40 46 44 37 12 20 2010's 29 46 82 135 189 - = No Data

  16. California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 307 1980's 265 265 325 344 256 254 261 243 220 233 1990's 228 220 196 135 145 109 120 129 116 233 2000's 244 185 197

  17. California - Coastal Region Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 395 1980's 330 325 384 405 284 277 275 255 232 238 1990's 232 231 215 201 205 163 168 176 118 233 2000's 244 185 197 174 196 277 214 212 151 169 2010's 180 173 305 284 277 - = No Data

  18. California - Coastal Region Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 88 1980's 65 60 59 61 28 23 14 12 12 5 1990's 4 11 19 66 60 54 48 47 2 0 2000's 0 0 0 1 8 8 6 1 1 1 2010's 2 1 2 2 8 - = No Data

  19. California - Los Angeles Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 176 1980's 207 163 104 115 163 188 149 155 158 141 1990's 110 120 103 108 108 115 112 146 154 174 2000's 204 195 218 196 184 186 161 154 81 91 2010's 92 102 98 90 84 - =

  20. California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1 1980's 0 1 1 1 1 3 0 0 0 0 1990's 0 0 3 0 0 0 0 3 1 0 2000's 1 1 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not

  1. California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,784 1980's 1,721 1,566 1,593 1,556 1,538 1,642 1,398 1,196 1,086 972 1990's 901 885 773 749 744 679 560 518 445 336 2000's 748 836

  2. California Federal Offshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 249 1980's 307 1,110 1,249 1,312 1,252 1990's 1,229 995 987 976 1,077 1,195 1,151 498 437 488 2000's 500 490 459 456 412 776 756

  3. California Federal Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 73 1980's 107 227 217 258 267 1990's 240 179 149 147 110 94 115 58 52 48 2000's 76 50 56 55 47 49 55 53 3 9 2010's 3 0 0 0 0 - = No Data Reported; -- =

  4. California Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,881 1980's 1,792 1,424 1,230 1,120 1,006 1990's 911 901 799 817 808 736 610 570 453 355 2000's 754 842 796 759 767 799 780 686 621 612 2010's 503 510 272 247 273 - = No Data Reported;

  5. California State Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 234 1980's 166 256 254 243 235 1990's 194 60 63 65 63 59 49 56 44 77 2000's 91 85 91 83 87 90 90 83 57 57 2010's 66 82 66 75 76 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  6. California State Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8 1980's 6 12 22 22 29 1990's 6 5 4 2 4 3 2 2 5 19 2000's 5 5 6 7 2 1 5 4 3 4 2010's 3 3 1 0 0 - = No Data Reported; -- = Not Applicable; NA = Not

  7. Florida Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 30 2 0 1 0 - = No Data Reported; -- =

  8. Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 56 6 16 15 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  9. Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 26 4 16 14 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  10. Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2 1980's 11 14 12 19 17 13 17 19 19 22 1990's 8 10 8 6 47 27 24 26 20 29 2000's 27 25 25 25 19 30 36 34 34 32 2010's 111 98 93 44 49 - = No Data Reported; -- = Not

  11. Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 633 1980's 502 796 965 845 786 753 761 717 686 617 1990's 703 674 613 636 715 730 749 785 665 1,180 2000's 1,645 2,428 3,070 3,514 4,445 4,608 6,660 7,846

  12. Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,038 1980's 1,374 1,228 1,060 959 867 710 691 691 616 581 1990's 573 572 624 502 611 879 824 850 794 713 2000's 652 488 561 450 362 384 347 365 223 362 2010's 334 318

  13. Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 733 1980's 883 758 719 824 774 689 577 569 491 432 1990's 408 437 352 328 357 326 347 281 228 227 2000's 214 159 214 269 193 153 192 179 148 77 2010's 72 77 94 125 108

  14. Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14 1980's 34 12 27 31 14 25 41 13 28 39 1990's 22 14 11 9 11 32 28 31 17 54 2000's 19 19 20 14 12 14 19 15 9 78 2010's 10 104 7 19 18 - = No

  15. Miscellaneous States Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Miscellaneous States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 156 1980's 180 193 74 81 77 77 136 66 84 87 1990's 72 76 93 96 67 69 68 44 39 67 2000's 42 83 100 134 110 132 139 241 272 349 2010's 363 393 233 188 185 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  16. Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 142 1980's 146 181 47 50 63 52 95 53 56 48 1990's 50 62 82 87 56 37 40 13 22 13 2000's 23 64 80 120 98 118 120 226 263 271 2010's 353 270 219 169 167 - = No Data

  17. Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 67 1980's 73 66 74 80 114 105 66 61 71 105 1990's 126 108 85 53 43 27 47 51 47 31 2000's 35 26 33 27 20 20 21 30 45 38 2010's 36 62 62 43 58 - = No Data Reported; --

  18. Montana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 51 1980's 122 89 81 108 77 91 98 97 101 68 1990's 86 66 61 53 55 53 51 42 52 67 2000's 70 85 94 112 130 161 195 219 197 312 2010's 302 270 289 304 325 - = No Data

  19. Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 786 1980's 1,186 1,247 789 813 748 793 725 704 733 821 1990's 834 782 814 631 672 739 755 727 737 784 2000's 822 822 820 956 872 837 874 848 817 681 2010's 657 522 327 286 361 - = No Data

  20. Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 432 1980's 282 165 158 396 364 395 522 477 749 686 1990's 844 805 780 763 780 699 715 594 548 777 2000's 717 631 772 823 767 714 801 926 886 799 2010's 742 684 1,012 2,887 6,985 - = No Data Reported; --

  1. Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 9 1980's 11 14 14 21 78 67 22 21 8 19 1990's 23 20 10 8 9 36 47 92 79 96 2000's 157 168 137 164 125 134 151 130 127 133 2010's 144 134 125 269 299 - = No Data

  2. Manufacture of SOFC electrodes by wet powder spraying

    SciTech Connect (OSTI)

    Wilkenhoener, R.; Mallener, W.; Buchkremer, H.P.

    1996-12-31

    The reproducible and commercial manufacturing of electrodes with enhanced electrochemical performance is of central importance for a successful technical realization of Solid Oxide Fuel Cell (SOFC) systems. The route of electrode fabrication for the SOFC by Wet Powder Spraying (WPS) is presented. Stabilized suspensions of the powder materials for the electrodes were sprayed onto a substrate by employing a spray gun. After drying of the layers, binder removal and sintering are performed in one step. The major advantage of this process is its applicability for a large variety of materials and its flexibility with regard to layer shape and thickness. Above all, flat or curved substrates of any size can be coated, thus opening up the possibility of {open_quotes}up-scaling{close_quotes} SOFC technology. Electrodes with an enhanced electrochemical performance were developed by gradually optimizing the different process steps. For example an optimized SOFC cathode of the composition La{sub 0.65}Sr{sub 0.3}MnO{sub 3} with 40% 8YSZ showed a mean overpotential of about -50 mV at a current density of -0.8 A/cm{sup 2}, with a standard deviation amounting to 16 mV (950{degrees}C, air). Such optimized electrodes can be manufactured with a high degree of reproducibility, as a result of employing a computer-controlled X-Y system for moving the spray gun. Several hundred sintered composites, comprising the substrate anode and the electrolyte, of 100x 100 mm{sup 2} were coated with the cathode by WPS and used for stack integration. The largest manufactured electrodes were 240x240 mm{sup 2}, and data concerning their thickness homogeneity and electrochemical performance are given.

  3. Molecular dynamics of wetting layer formation and forced water invasion in angular nanopores with mixed wettability

    SciTech Connect (OSTI)

    Sedghi, Mohammad Piri, Mohammad; Goual, Lamia

    2014-11-21

    The depletion of conventional hydrocarbon reservoirs has prompted the oil and gas industry to search for unconventional resources such as shale gas/oil reservoirs. In shale rocks, considerable amounts of hydrocarbon reside in nanoscale pore spaces. As a result, understanding the multiphase flow of wetting and non-wetting phases in nanopores is important to improve oil and gas recovery from these formations. This study was designed to investigate the threshold capillary pressure of oil and water displacements in a capillary dominated regime inside nanoscale pores using nonequilibrium molecular dynamics (NEMD) simulations. The pores have the same cross-sectional area and volume but different cross-sectional shapes. Oil and water particles were represented with a coarse grained model and the NEMD simulations were conducted by assigning external pressure on an impermeable piston. Threshold capillary pressures were determined for the drainage process (water replaced by oil) in different pores. The molecular dynamics results are in close agreements with calculations using the Mayer-Stowe-Princen (MS-P) method which has been developed on the premise of energy balance in thermodynamic equilibrium. After the drainage simulations, a change in wall particles’ wettability from water-wet to oil-wet was implemented based on the final configuration of oil and water inside the pore. Waterflooding simulations were then carried out at the threshold capillary pressure. The results show that the oil layer formed between water in the corner and in the center of the pore is not stable and collapses as the simulation continues. This is in line with the predictions from the MS-P method.

  4. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science Chemistry for Measurement and Detection Science Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of two FBI "hub" laboratories for analyzing bulk special nuclear

  5. Subcritical water extraction of lipids from wet algal biomass

    DOE Patents [OSTI]

    Deng, Shuguang; Reddy, Harvind K.; Schaub, Tanner; Holguin, Francisco Omar

    2016-05-03

    Methods of lipid extraction from biomass, in particular wet algae, through conventionally heated subcritical water, and microwave-assisted subcritical water. In one embodiment, fatty acid methyl esters from solids in a polar phase are further extracted to increase biofuel production.

  6. Analytical Chemistry Laboratory. Progress report for FY 1996

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1996-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1996. This annual report is the thirteenth for the ACL. It describes effort on continuing and new projects and contributions of the ACL staff to various programs at ANL. The ACL operates in the ANL system as a full-cost-recovery service center, but has a mission that includes a complementary research and development component: The Analytical Chemistry Laboratory will provide high-quality, cost-effective chemical analysis and related technical support to solve research problems of our clients -- Argonne National Laboratory, the Department of Energy, and others -- and will conduct world-class research and development in analytical chemistry and its applications. Because of the diversity of research and development work at ANL, the ACL handles a wide range of analytical chemistry problems. Some routine or standard analyses are done, but the ACL usually works with commercial laboratories if our clients require high-volume, production-type analyses. It is common for ANL programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. Thus, much of the support work done by the ACL is very similar to our applied analytical chemistry research.

  7. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H.

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  8. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  9. Family Chemistry | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Family Chemistry Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Family Chemistry Family gathers at the dinner table and, sometimes, the conference table or the science lab. Paul and Mark Buckley both work at the Global Research Center in Niskayuna, New York and, collectively, have more than 45 years of experience

  10. Role of nanocrystallinity on the chemical ordering of CoxPt100-x nanocrystals synthesized by wet chemistry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cordeiro, Marco; Kameche, Farid; Ngo, Anh -Tu; Salzemann, Caroline; Sutter, Eli; Petit, Christophe

    2015-03-17

    CoxPt100–x nanoalloys have been synthesized by two different chemical processes either at high or at low temperature. Their physical properties and the order/disorder phase transition induced by annealing have been investigated depending on the route of synthesis. It is demonstrated that the chemical synthesis at high temperature allows stabilization of the fcc structure of the native nanoalloys while the soft chemical approach yields mainly poly or non crystalline structure. As a result the approach of the order/disorder phase transition is strongly modified as observed by high-resolution transmission electron microscopy (HR-TEM) studies performed during in situ annealing of the different nanoalloys.more » The control of the nanocrystallinity leads to significant decrease in the chemical ordering temperature as the ordered structure is observed at temperatures as low as 420 °C. Furthermore, this in turn preserves the individual nanocrystals and prevents their coalescence usually observed during the annealing necessary for the transition to an ordered phase.« less

  11. Computational and Theoretical Chemistry | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational and Theoretical Chemistry Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Computational and Theoretical Chemistry Print Text Size: A A A FeedbackShare Page Research in Computational and Theoretical Chemistry emphasizes integration and development of new and existing

  12. Cooperative Research in C1 Chemistry

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2000-10-27

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F

  13. Mathematical challenges from theoretical/computational chemistry

    SciTech Connect (OSTI)

    1995-12-31

    The committee believes that this report has relevance and potentially valuable suggestions for a wide range of readers. Target audiences include: graduate departments in the mathematical and chemical sciences; federal and private agencies that fund research in the mathematical and chemical sciences; selected industrial and government research and development laboratories; developers of software and hardware for computational chemistry; and selected individual researchers. Chapter 2 of this report covers some history of computational chemistry for the nonspecialist, while Chapter 3 illustrates the fruits of some past successful cross-fertilization between mathematical scientists and computational/theoretical chemists. In Chapter 4 the committee has assembled a representative, but not exhaustive, survey of research opportunities. Most of these are descriptions of important open problems in computational/theoretical chemistry that could gain much from the efforts of innovative mathematical scientists, written so as to be accessible introductions to the nonspecialist. Chapter 5 is an assessment, necessarily subjective, of cultural differences that must be overcome if collaborative work is to be encouraged between the mathematical and the chemical communities. Finally, the report ends with a brief list of conclusions and recommendations that, if followed, could promote accelerated progress at this interface. Recognizing that bothersome language issues can inhibit prospects for collaborative research at the interface between distinctive disciplines, the committee has attempted throughout to maintain an accessible style, in part by using illustrative boxes, and has included at the end of the report a glossary of technical terms that may be familiar to only a subset of the target audiences listed above.

  14. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues ...

  15. ,"U.S. Federal Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Natural Gas, Wet After Lease Separation ... "Back to Contents","Data 1: U.S. Federal Offshore Natural Gas, Wet After Lease Separation ...

  16. ,"U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet ... "Back to Contents","Data 1: U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet ...

  17. ,"Texas - RRC District 7B Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 7B Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 7B Natural Gas, Wet After ...

  18. ,"Texas - RRC District 7C Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 7C Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 7C Natural Gas, Wet After ...

  19. ,"Texas - RRC District 8A Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas - RRC District 8A Natural Gas, Wet After ... 7:19:07 AM" "Back to Contents","Data 1: Texas - RRC District 8A Natural Gas, Wet After ...

  20. Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 693 1980's 682 683 1990's 4,184 5,460 5,870 5,212 4,898 4,930 5,100 5,013 4,643 4,365 2000's 4,269 3,958 3,922 4,345 4,159 4,006 3,963 4,036 3,379 2,948 2010's 2,724 2,570 2,304 1,670 2,121 - = No Data Reported; -- = Not Applicable; NA = Not

  1. Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 680 1980's 659 658 1990's 4,159 5,437 5,840 5,166 4,842 4,886 5,062 4,983 4,615 4,338 2000's 4,241 3,931 3,891 4,313 4,127 3,977 3,945 4,016 3,360 2,919 2010's 2,686 2,522 2,204 1,624 1,980

  2. Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 32,275 1980's 33,395 33,049 35,002 34,291 34,476 34,223 33,355 33,715 9,179 9,019 1990's 9,393 9,653 9,725 9,986 9,813 9,575 9,296 10,673 10,043 9,855 2000's 9,331 8,901 8,533 8,348 8,473 8,237 10,333 12,022 7,766 9,183 2010's 8,917 9,511 9,667

  3. Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 5,058 1980's 4,828 4,373 4,188 3,883 4,120 3,131 2,462 2,983 2,910 2,821 1990's 2,466 2,924 3,002 3,492 3,326 3,310 3,216 2,957 2,768 2,646 2000's 2,564 2,309 2,157 2,081 2,004 1,875 1,447

  4. Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,725 1980's 1,796 1,821 1,974 2,081 2,240 2,032 2,011 2,018 2,000 1,782 1990's 1,739 1,672 1,752 1,555 1,610 1,566 1,472 1,479 1,332 1,546 2000's 1,584 1,619 1,654 1,666 1,837 1,967 2,271 3,306 5,628 10,872 2010's 14,181 16,374 11,039 13,524

  5. Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,559 1980's 1,602 1,637 1,800 1,887 2,051 1,875 1,861 1,873 1,843 1,637 1990's 1,672 1,536 1,619 1,462 1,525 1,462 1,383 1,423 1,294 1,505 2000's 1,545 1,589 1,616 1,629 1,797 1,921 2,227

  6. California - San Joaquin Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,037 1980's 4,434 4,230 4,058 3,964 3,808 3,716 3,404 3,229 3,033 2,899 1990's 2,775 2,703 2,511 2,425 2,130 2,018 1,864 2,012 2,016 2,021 2000's 2,413 2,298 2,190 2,116

  7. California Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,961 1980's 3,345 2,660 2,663 2,546 2,507 1990's 2,400 2,213 2,093 1,982 1,698 1,619 1,583 1,820 1,879 2,150 2000's 2,198 1,922 1,900 1,810 2,006 2,585 2,155 2,193

  8. California Federal Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 322 1980's 414 1,337 1,466 1,570 1,519 1990's 1,469 1,174 1,136 1,123 1,187 1,289 1,266 556 489 536 2000's 576 540 515 511 459 825 811 805 705 740 2010's 725 711 652 264 243 - = No Data Reported; -- =

  9. California Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,842 1980's 5,137 4,084 3,893 3,666 3,513 1990's 3,311 3,114 2,892 2,799 2,506 2,355 2,193 2,390 2,332 2,505 2000's 2,952 2,763 2,696 2,569 2,773 3,384 2,935 2,879 2,538 2,926 2010's 2,785 3,042 2,119 2,023 2,260 - = No Data Reported; -- =

  10. Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 181 1980's 200 259 206 173 208 167 190 219 177 236 1990's 510 682 762 1,162 1,088 1,072 1,055 533 772 781 2000's 960 1,025 1,097 1,186 1,293 1,326 1,541 1,838 2,010

  11. Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,838 1980's 3,170 3,228 3,551 3,373 3,140 3,095 3,198 3,131 3,749 4,526 1990's 4,759 6,011 6,463 6,979 7,036 7,592 8,064 7,160 8,208 9,372 2000's 10,837 12,949 14,348 15,893 15,249 17,122 17,682 22,480 24,169 24,081 2010's 25,372 26,151 21,674

  12. Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,657 1980's 2,970 2,969 3,345 3,200 2,932 2,928 3,008 2,912 3,572 4,290 1990's 4,249 5,329 5,701 5,817 5,948 6,520 7,009 6,627 7,436 8,591 2000's 9,877 11,924 13,251 14,707 13,956 15,796

  13. Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,824 1980's 10,065 10,443 10,128 10,183 9,981 9,844 11,093 11,089 10,530 10,509 1990's 10,004 9,946 10,302 9,872 9,705 9,093 8,145 7,328 6,862 6,248 2000's 5,682 5,460 5,329 5,143 5,003 4,598 4,197 4,248 3,795 3,500 2010's 3,937 3,747 3,557

  14. Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,657 1980's 9,880 10,304 10,016 10,051 9,871 9,729 10,961 10,974 10,427 10,408 1990's 9,890 9,831 10,208 9,779 9,630 9,026 8,063 7,277 6,802 6,196 2000's 5,641 5,355 5,263 5,058 4,923 4,515

  15. Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 504 1980's 536 561 592 600 647 806 883 940 957 1,015 1990's 1,047 1,187 1,126 1,036 1,025 1,102 1,046 1,429 1,295 1,530 2000's 1,837 1,950 1,999 1,971 1,982 2,240 2,369 2,588 2,846 2,919 2010's 2,785 2,128 1,515 1,794 1,753 - = No Data Reported;

  16. Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 502 1980's 525 547 580 581 630 793 866 921 938 993 1990's 1,039 1,177 1,118 1,030 978 1,075 1,022 1,403 1,275 1,501 2000's 1,810 1,925 1,974 1,946 1,963 2,210 2,333 2,554 2,812 2,887 2010's

  17. Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 732 1980's 683 870 708 960 714 754 716 639 1,002 1,037 1990's 744 660 606 540 586 498 523 950 1,101 1,165 2000's 1,037 1,024 1,047 1,047 1,184 1,148 1,048

  18. Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,805 1980's 6,381 6,264 6,242 5,948 5,443 5,484 5,320 5,030 4,876 4,849 1990's 4,608 4,763 4,463 4,214 4,405 4,656 4,592 4,386 4,510 4,447 2000's 4,143

  19. Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,127 1980's 1,117 1,265 1,322 1,477 1,911 2,100 2,169 2,106 1,989 1,789 1990's 1,835 1,841 1,692 1,790 1,926 1,876 2,088 1,681 1,906 2,301 2000's 3,089

  20. Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,710 1980's 3,622 3,653 3,749 4,279 4,087 4,274 4,324 4,151 4,506 5,201 1990's 5,345 4,856 4,987 5,170 5,131 5,425 5,690 5,616 5,691 5,562 2000's 5,901

  1. Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8,073 1980's 7,216 6,620 6,084 6,064 5,362 5,246 5,254 4,973 4,738 4,403 1990's 4,323 4,023 3,792 3,569 3,267 3,218 3,069 2,886 2,727 2,947 2000's 3,345

  2. Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 46,803 46,620 44,319 42,192 41,404 41,554 1990's 41,411 39,288 38,141 37,847 39,020 39,736 41,592 41,108 40,793 43,350 2000's 45,419 46,462 47,491 48,717 53,275 60,178 65,805 76,357 81,843 85,034 2010's 94,287 104,454 93,475 97,921 105,955 - = No

  3. Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 35,971 35,867 34,584 32,852 32,309 32,349 1990's 32,412 30,729 29,474 29,967 31,071 31,949 33,432 33,322 33,429 35,470 2000's 38,585 40,376 41,104 42,280 46,728 53,175 58,736 68,827 74,284

  4. Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 650 1980's 870 1,722 1,928 2,112 1,984 1,897 1,795 1,870 1,509 1,498 1990's 1,432 1,532 1,709 1,909 1,631 1,424 1,446 1,695 2,293 3,050 2000's 4,125 4,450 3,915 3,318 3,661 4,051 4,894 6,095 6,393 6,810

  5. Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 2,446 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579 2,373 2,800 - = No Data Reported; -- = Not Applicable; NA =

  6. Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 1,923 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579

  7. West Virginia Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) West Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,669 1980's 2,559 1,944 2,252 2,324 2,246 2,177 2,272 2,360 2,440 2,342 1990's 2,329 2,672 2,491 2,598 2,702 2,588 2,793 2,946 2,968 3,040 2000's 3,062 2,825 3,498 3,399 3,509 4,572 4,654 4,881 5,266 6,090 2010's 7,163 10,532

  8. West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,593 1980's 2,437 1,881 2,169 2,238 2,173 2,104 2,207 2,210 2,299 2,244 1990's 2,243 2,513 2,293 2,408 2,569 2,514 2,722 2,887 2,925 2,952 2000's 2,929 2,777 3,477 3,376 3,489 4,553

  9. Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,834 1980's 9,413 9,659 10,155 10,728 11,014 11,229 10,393 10,572 10,903 11,276 1990's 10,433 10,433 11,305 11,387 11,351 12,712 13,084 14,321 14,371 14,809 2000's 17,211 19,399 21,531 22,716 23,640 24,722 24,463 30,896 32,399 36,748 2010's

  10. Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,796 1980's 8,039 8,431 9,095 9,769 10,147 10,519 9,702 9,881 10,287 10,695 1990's 9,860 9,861 10,681 10,885 10,740 11,833 12,260 13,471 13,577 14,096 2000's 16,559 18,911 20,970 22,266

  11. Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,580 1980's 13,407 13,049 12,153 11,553 10,650 10,120 9,416 9,024 8,969 8,934 1990's 8,492 7,846 7,019 6,219 6,558 6,166 6,105 6,137 5,966 5,858 2000's 5,447 5,341 4,395 3,874 3,557 3,478 3,473 3,463

  12. Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,276 1980's 11,273 11,178 10,364 9,971 9,162 8,328 7,843 7,644 7,631 7,661 1990's 7,386 6,851 6,166 5,570 5,880 5,446 5,478 5,538 5,336 5,259 2000's

  13. Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,360 2,391 2,128 1,794 1,741 1990's 1,554 1,394 1,167 926 980 1,001 1,039 1,016 911 979 2000's 807 796 670 586 557 588 561 641 1,235 1,072 2010's 679 639 773 870 908

  14. Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 19,676 13,334 12,852 12,620 12,912 1990's 12,151 11,363 10,227 9,541 10,145 9,891 10,077 10,036 9,480 9,646 2000's 9,512 10,040 9,190 9,538 9,792 10,679 10,710 10,292 11,816 20,970 2010's 29,517 30,545 22,135 20,389 23,258 - = No Data Reported;

  15. Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 16,316 10,943 10,724 10,826 11,171 1990's 10,597 9,969 9,060 8,615 9,165 8,890 9,038 9,020 8,569 8,667 2000's 8,704 9,245 8,520 8,952 9,235 10,091 10,149 9,651 10,581 19,898 2010's 28,838

  16. Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 143,852 1980's 139,421 143,515 142,984 143,469 141,226 138,464 139,070 135,256 141,211 139,798 1990's 141,941 140,584 138,883 136,953 138,213 139,369 141,136 140,382 139,015

  17. Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 601 1980's 668 494 481 529 419 375 665 1,002 943 1,011 1990's 922 967 938 890 1,022 1,018 1,778 1,975 2,158 2,086 2000's 2,558 2,873 3,097 3,219 2,961 2,808 2,925 3,512 3,105 2,728 2010's

  18. Mississippi Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Mississippi Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,511 1980's 1,776 2,042 1,803 1,603 1,496 1,364 1,304 1,223 1,146 1,108 1990's 1,129 1,061 873 800 653 667 634 583 662 681 2000's 620 663 746 748 692 758 816 958 1,035 922 2010's 858 868 612 600 563 - = No Data Reported; -- = Not

  19. Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,444 1980's 1,703 1,976 1,729 1,523 1,382 1,259 1,238 1,162 1,075 1,003 1990's 1,003 953 788 747 610 640 587 532 615 650 2000's 585 637 713 721 672 738 795 928 990 884 2010's 822 806

  20. Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 837 1980's 1,308 1,336 870 921 825 884 823 801 834 889 1990's 920 848 875 684 727 792 806 769 789 851 2000's 892 907 914 1,068 1,002 998 1,069 1,067 1,014 993 2010's 959 792 616 590 686 - = No Data Reported; -- = Not Applicable; NA = Not

  1. Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,246 1980's 2,252 2,441 2,426 2,269 2,244 2,149 2,191 2,017 1,894 1,785 1990's 1,820 1,406 1,483 1,550 1,342 1,228 1,023 1,015 1,196 1,238 2000's 1,113 1,109 1,177

  2. Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,545 1980's 13,908 15,507 17,140 17,261 17,102 17,078 17,779 17,703 17,450 16,733 1990's 16,967 15,518 14,732 14,099 14,323 14,295 13,952 14,311 14,517 13,490 2000's 14,543 14,366 15,753 16,231 17,200 18,146 18,535 20,184 22,113 24,207 2010's

  3. Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,299 1980's 11,656 13,066 14,714 14,992 14,858 14,929 15,588 15,686 15,556 14,948 1990's 15,147 14,112 13,249 12,549 12,981 13,067 12,929 13,296 13,321 12,252 2000's 13,430 13,256 14,576

  4. Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,516 1980's 951 1,265 1,430 1,882 1,576 1,618 1,562 1,650 2,074 1,644 1990's 1,722 1,631 1,533 1,722 1,806 1,488 1,702 1,861 1,848 1,780 2000's 1,740 1,782 2,225 2,497 2,371 2,793 3,064 3,377 3,594 7,018 2010's 14,068 26,719 36,543

  5. Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,507 1980's 940 1,251 1,416 1,861 1,498 1,551 1,540 1,629 2,066 1,625 1990's 1,699 1,611 1,523 1,714 1,797 1,452 1,655 1,769 1,769 1,684 2000's 1,583 1,614 2,088 2,333 2,246 2,659

  6. Wetting and free surface flow modeling for potting and encapsulation.

    SciTech Connect (OSTI)

    Brooks, Carlton, F.; Brooks, Michael J.; Graham, Alan Lyman; Noble, David F. ); Notz, Patrick K.; Hopkins, Matthew Morgan; Castaneda, Jaime N.; Mahoney, Leo James; Baer, Thomas A.; Berchtold, Kathryn; Adolf, Douglas Brian; Wilkes, Edward Dean; Rao, Rekha Ranjana; Givler, Richard C.; Sun, Amy Cha-Tien; Cote, Raymond O.; Mondy, Lisa Ann; Grillet, Anne Mary; Kraynik, Andrew Michael

    2007-06-01

    As part of an effort to reduce costs and improve quality control in encapsulation and potting processes the Technology Initiative Project ''Defect Free Manufacturing and Assembly'' has completed a computational modeling study of flows representative of those seen in these processes. Flow solutions are obtained using a coupled, finite-element-based, numerical method based on the GOMA/ARIA suite of Sandia flow solvers. The evolution of the free surface is solved with an advanced level set algorithm. This approach incorporates novel methods for representing surface tension and wetting forces that affect the evolution of the free surface. In addition, two commercially available codes, ProCAST and MOLDFLOW, are also used on geometries representing encapsulation processes at the Kansas City Plant. Visual observations of the flow in several geometries are recorded in the laboratory and compared to the models. Wetting properties for the materials in these experiments are measured using a unique flowthrough goniometer.

  7. Wet-steam erosion of steam turbine disks and shafts

    SciTech Connect (OSTI)

    Averkina, N. V.; Zheleznyak, I. V.; Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G.; Shishkin, V. I.

    2011-01-15

    A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

  8. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are ...

  9. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T.

    2001-01-01

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  10. Hydrologic Behavior of Two Engineered Barriers Following Extreme Wetting

    SciTech Connect (OSTI)

    Porro, I.

    2000-09-30

    Many engineered barriers are expected to function for hundreds of years or longer. Over the course of time, it is likely that some barriers will experience infiltration to the point of breakthrough. This study compares the recovery from breakthrough of two storage- evapotranspiration type engineered barriers. Replicates of test plots comprising thick soil and capillary/biobarrier covers were wetted to breakthrough in 1997. Test plots were kept cleared of vegetation to maximize hydrologic stress during recovery. Following cessation of drainage resulting from the wetting irrigations, water storage levels in all plots were at elevated levels compared to pre-irrigation levels. As a result, infiltration of melting snow during the subsequent spring overloaded the storage capacity and produced drainage in all plots. Relatively rapid melting of accumulated snowfall produced the most significant infiltration events each year during the study. Capillary barriers yielded less total drainage than thick soil barriers. By limiting drainage, capillary barriers increased water storage in the upper portions of the test plots, which led to increased evaporation from the capillary barrier plots compared to thick soil plots. Increased evaporation in the capillary barrier plots allowed more water to infiltrate in the second season following the wetting tests without triggering drainage. All thick soil plots again yielded drainage in the second season. Within two years of intentionally induced breakthrough, evaporation alone (without transpiration) restored the capability of the capillary barrier covers to function as intended, although water storage in these covers remained at elevated levels.

  11. Eleventh international symposium on radiopharmaceutical chemistry

    SciTech Connect (OSTI)

    1995-12-31

    This document contains abstracts of papers which were presented at the Eleventh International Symposium on Radiopharmaceutical Chemistry. Sessions included: radiopharmaceuticals for the dopaminergic system, strategies for the production and use of labelled reactive small molecules, radiopharmaceuticals for measuring metabolism, radiopharmaceuticals for the serotonin and sigma receptor systems, labelled probes for molecular biology applications, radiopharmaceuticals for receptor systems, radiopharmaceuticals utilizing coordination chemistry, radiolabelled antibodies, radiolabelling methods for small molecules, analytical techniques in radiopharmaceutical chemistry, and analytical techniques in radiopharmaceutical chemistry.

  12. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) building supports research and experimental activities for plutonium and uranium analytical chemistry and metallurgy. CMR capabilities support a number of national security programs, such as non-proliferation and nuclear safeguards. The CMR Facility In 1952, the first LANL CMR facility was completed. At that time, the

  13. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home » News & Publications » News » Center News » Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov Karplus605v1.jpg Martin Karplus On Wednesday, the Nobel Prize in Chemistry was awarded to three scientists for pioneering methods in computational chemistry that have brought a deeper understanding of complex chemical structure and reactions in biochemical systems. These methods can

  14. Interfacial Chemistry and Engineering Annual Report 2000

    SciTech Connect (OSTI)

    Grate, Jay W.

    2001-08-01

    This annual report describes the research and staff accomplishments in 2000 for the EMSL Interfacial Chemistry and Engineering Directorate.

  15. HARNESSING THE CHEMISTRY OF CO2

    SciTech Connect (OSTI)

    Louie, Janis

    2010-05-11

    Our research program is broadly focused on activating CO{sub 2} through the use of organic and organometallic based catalysts. Some of our methods have centered on annulation reactions of unsaturated hydrocarbons (and carbonyl substrates) to provide a diverse array of carbocycles and heterocycles. We use a combination of catalyst discovery and optimization in conjunction with classical physical organic chemistry to elucidate the key mechanistic features of the cycloaddition reactions such that the next big advances in catalyst development can be made. Key to all of our cycloaddition reactions is the use of a sterically hindered, electron donating N heterocyclic carbene (NHC) ligand, namely IPr (or SIPr), in conjunction with a low valent nickel pre-catalyst. The efficacy of this ligand is two-fold: (1) the high {delta}-donating ability of the NHC increases the nucleophilicity of the metal center which thereby facilitates interaction with the electrophilic carbonyl and (2) the steric hindrance prevents an otherwise competitive side reaction involving only the alkyne substrate. Such a system has allowed for the facile cycloaddition to prepare highly functionalized pyrones, pyridones, pyrans, as well as novel carbocycles. Importantly, all reactions proceed under extremely mild conditions (room temperature, atmospheric pressures, and short reaction times), require only catalytic amounts of Ni/NHC and readily available starting materials, and afford annulated products in excellent yields. Our current focus revolves around understanding the fundamental processes that govern these cycloadditions such that the next big advance in the cyclization chemistry of CO{sub 2} can be made. Concurrent to our annulation chemistry is our investigation of the potential for imidazolylidenes to function as thermally-actuated CO{sub 2} sequestering and delivery agents.

  16. High performance computing in chemistry and massively parallel computers: A simple transition?

    SciTech Connect (OSTI)

    Kendall, R.A.

    1993-03-01

    A review of the various problems facing any software developer targeting massively parallel processing (MPP) systems is presented. Issues specific to computational chemistry application software will be also outlined. Computational chemistry software ported to and designed for the Intel Touchstone Delta Supercomputer will be discussed. Recommendations for future directions will also be made.

  17. Development of Novel Front Contract Pastes for Crystalline Silicon Solar Cells

    SciTech Connect (OSTI)

    Duty, C.; Jellison, D. G.E. P.; Joshi, P.

    2012-04-05

    In order to improve the efficiencies of silicon solar cells, paste to silicon contact formation mechanisms must be more thoroughly understood as a function of paste chemistry, wafer properties and firing conditions. Ferro Corporation has been involved in paste development for over 30 years and has extensive expertise in glass and paste formulations. This project has focused on the characterization of the interface between the top contact material (silver paste) and the underlying silicon wafer. It is believed that the interface between the front contact silver and the silicon wafer plays a dominant role in the electrical performance of the solar cell. Development of an improved front contact microstructure depends on the paste chemistry, paste interaction with the SiNx, and silicon (“Si”) substrate, silicon sheet resistivity, and the firing profile. Typical front contact ink contains silver metal powders and flakes, glass powder and other inorganic additives suspended in an organic medium of resin and solvent. During fast firing cycles glass melts, wets, corrodes the SiNx layer, and then interacts with underlying Si. Glass chemistry is also a critical factor in the development of an optimum front contact microstructure. Over the course of this project, several fundamental characteristics of the Ag/Si interface were documented, including a higher-than-expected distribution of voids along the interface, which could significantly impact electrical conductivity. Several techniques were also investigated for the interfacial analysis, including STEM, EDS, FIB, EBSD, and ellipsometry.

  18. Physical Chemistry and Applied Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PCS Physical Chemistry and Applied Spectroscopy We perform basic and applied research in support of the Laboratory's national security mission and serve a wide range of customers. Contact Us Group Leader Kirk Rector Deputy Group Leader Jeff Pietryga Group Office (505) 667-7121 Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in the Los Alamos National Laboratory optical laboratory. Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in

  19. Wetting kinetics of water nano-droplet containing non-surfactant nanoparticles: A molecular dynamics study

    SciTech Connect (OSTI)

    Lu, Gui; Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, Pennsylvania 19104 ; Hu, Han; Sun, Ying E-mail: ysun@coe.drexel.edu; Duan, Yuanyuan E-mail: ysun@coe.drexel.edu

    2013-12-16

    In this Letter, dynamic wetting of water nano-droplets containing non-surfactant gold nanoparticles on a gold substrate is examined via molecular dynamics simulations. The results show that the addition of non-surfactant nanoparticles hinders the nano-second droplet wetting process, attributed to the increases in both surface tension of the nanofluid and friction between nanofluid and substrate. The droplet wetting kinetics decreases with increasing nanoparticle loading and water-particle interaction energy. The observed wetting suppression and the absence of nanoparticle ordering near the contact line of nano-sized droplets differ from the wetting behaviors reported from nanofluid droplets of micron size or larger.

  20. HARNESSING THE CHEMISTRY OF CO{sub 2}

    SciTech Connect (OSTI)

    Louie, Janis

    2012-11-30

    Our research presents several strategies for addressing the challenges of activating CO2. In addition, our cycloaddition chemistry addresses several fundamental issues pertaining to catalysis as it applies to energy conservation. Topics addressed include: DEVELOPMENT OF A CYCLOADDITION CATALYST; INCREASING THE UTILITY OF THE NI CYCLOADDITION CATALYST; UNDERSTANDING THE MECHANISM OF NI-CATALYZED CYCLOADDITION; and METAL-FREE CO{sub 2} ACTIVATION.

  1. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2015-01-06

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOCs) in the gas phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the WRF-Chem regional chemistry transport model, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48 and 63% respectively over the continental US. Dry deposition ofmore » gas-phase SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40 vs. −8% for anthropogenics, and −52 vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas phase (61% for anthropogenics and 76% for biogenics). Results are sensitive to assumptions made in the dry deposition scheme, but gas-phase deposition of SVOCs remains crucial even under conservative estimates. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility

  2. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2014-05-26

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOC) in the gas-phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the regional chemistry transport model WRF-Chem, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48% and 63% respectively over the continental US Dry deposition of gas-phasemore » SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40% vs. −8% for anthropogenics, −52% vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas-phase (61% for anthropogenics, 76% for biogenics). A number of sensitivity studies shows that this is a robust feature of the modeling system. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 25% / 10% compared to our best estimate. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We

  3. Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016

  4. Advanced emissions control development project. Phase I final report appendices, November 1, 1993--February 29, 1996

    SciTech Connect (OSTI)

    Farthing, G.A.

    1996-06-01

    Appendices are presented on the Advanced Emissions Control Development Project on the following: wet scrubber sampling and analysis; DBA/lime chemical analysis; limestone forced oxidation chemical analysis; benchmarking on baghouse conditions, electrostatic precipitators, and wet scrubber conditions.

  5. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The ALS provides the intense x-ray radiation necessary for studies of crystals that, ... understanding-at the molecular, atomic, and electronic level-of how chemical ...

  6. Numerical solution of 2D wet steam flow with non-equilibrium condensation and real thermodynamics

    SciTech Connect (OSTI)

    Hric, V.; Halama, J.

    2015-03-10

    An approach to modeling of wet steam flow with non-equilibrium condensation phenomenon is presented. The first part of our flow model is homogeneous Euler system of transport equations for mass, momentum and total energy of wet steam (mixture). The additional second part describes liquid phase via non-homogeneous system of transport equations for moments of droplets number distribution function and relies on corrected classical nucleation theory. Moment equations are closed by linearization of droplet growth rate model. All necessary relations for thermodynamic properties of steam are provided by IAPWS set of equations. However, properties of condensate are simply modeled by liquid saturation data. Two real equations of state are implemented. Recently developed CFD formulation for entropy (does not require iteration process) and so-called IAPWS special gas equation for Helmholtz energy (one iteration loop is necessary). Flow model is validated on converging-diverging supersonic nozzle with Barschdorff geometry. Simulations were performed by in-house CFD code based on finite volume method and stiff character of equations was solved by symmetrical time operator splitting. Achieved results satisfactorily agreed with experimental data.

  7. 1986 wet deposition temporal and spatial patterns in North America

    SciTech Connect (OSTI)

    Olsen, A.R.

    1989-07-01

    The focus of this report is on North American wet deposition temporal patterns from 1979 to 1986 and spatial patterns for 1986. The report provides statistical distribution summaries of annual precipitation-weighted average concentration and annual deposition for nine ion species: hydrogen, sulfate, nitrate, ammonium, calcium, chloride, sodium, potassium, and magnesium. The data in the report are from the Acid Depositing System (ADS) for the statistical reporting of North American deposition data. Isopleth maps, based on surface estimation using kriging, display concentration and deposition spatial patterns of pH, hydrogen, sulfate, nitrate, ammonium, and calcium ion species for 1986 annual, winter, and summer periods. The temporal pattern analyses use a subset of 30 sites over an 8-year (1979-1986) period and an expanded subset of 137 sites with greater spatial coverage over a 5-year (1982-1986) period. The 8-year period represents the longest period with wet deposition monitoring data unavailable that has a sufficient number of sites with data of known quality to allow a descriptive summary of annual temporal patterns. 19 refs., 105 figs., 29 tabs.

  8. Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,334 1980's 1,551 1,252 1,200 1,353 1,193 1,064 1,242 1,571 1,434 1,443 1990's 1,330 1,404 1,290 1,218 1,379 1,344 2,125 2,256 2,386 2,313 2000's 2,772 3,032 3,311 3,488 3,154 2,961 3,117 3,691 3,253 2,805 2010's 2,975 2,549 1,781 1,839 1,873 -

  9. Combined wet and dry cleaning of SiGe(001)

    SciTech Connect (OSTI)

    Park, Sang Wook; Kaufman-Osborn, Tobin; Kim, Hyonwoong; Siddiqui, Shariq; Sahu, Bhagawan; Yoshida, Naomi; Brandt, Adam; Kummel, Andrew C.

    2015-07-15

    Combined wet and dry cleaning via hydrofluoric acid (HF) and atomic hydrogen on Si{sub 0.6}Ge{sub 0.4}(001) surface was studied at the atomic level using ultrahigh vacuum scanning tunneling microscopy (STM), scanning tunneling spectroscopy (STS), and x-ray photoelectron spectroscopy to understand the chemical transformations of the surface. Aqueous HF removes native oxide, but residual carbon and oxygen are still observed on Si{sub 0.6}Ge{sub 0.4}(001) due to hydrocarbon contamination from post HF exposure to ambient. The oxygen contamination can be eliminated by shielding the sample from ambient via covering the sample in the HF cleaning solution until the sample is introduced to the vacuum chamber or by transferring the sample in an inert environment; however, both processes still leave carbon contaminant. Dry in-situ atomic hydrogen cleaning above 330 °C removes the carbon contamination on the surface consistent with a thermally activated atomic hydrogen reaction with surface hydrocarbon. A postdeposition anneal at 550 °C induces formation of an atomically flat and ordered SiGe surface observed by STM. STS verifies that the wet and dry cleaned surface has an unpinned Fermi level with no states between the conduction and valence band edge comparable to sputter cleaned SiGe surfaces.

  10. A preliminary assessment of beryllium dust oxidation during a wet bypass accident in a fusion reactor

    SciTech Connect (OSTI)

    Brad J. Merrill; Richard L. Moore; J. Phillip Sharp

    2008-09-01

    A beryllium dust oxidation model has been developed at the Idaho National Laboratory (INL) by the Fusion Safety Program (FSP) for the MELCOR safety computer code. The purpose of this model is to investigate hydrogen production from beryllium dust layers on hot surfaces inside a fusion reactor vacuum vessel (VV) during in-vessel loss-of-cooling accidents (LOCAs). This beryllium dust oxidation model accounts for the diffusion of steam into a beryllium dust layer, the oxidation of the dust particles inside this layer based on the beryllium-steam oxidation equations developed at the INL, and the effective thermal conductivity of this beryllium dust layer. This paper details this oxidation model and presents the results of the application of this model to a wet bypass accident scenario in the ITER device.

  11. Discovering chemistry with an ab initio nanoreactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Lee-Ping; Titov, Alexey; McGibbon, Robert; Liu, Fang; Pande, Vijay S.; Martínez, Todd J.

    2014-11-02

    Chemical understanding is driven by the experimental discovery of new compounds and reactivity, and is supported by theory and computation that provides detailed physical insight. While theoretical and computational studies have generally focused on specific processes or mechanistic hypotheses, recent methodological and computational advances harken the advent of their principal role in discovery. Here we report the development and application of the ab initio nanoreactor – a highly accelerated, first-principles molecular dynamics simulation of chemical reactions that discovers new molecules and mechanisms without preordained reaction coordinates or elementary steps. Using the nanoreactor we show new pathways for glycine synthesis frommore » primitive compounds proposed to exist on the early Earth, providing new insight into the classic Urey-Miller experiment. Ultimately, these results highlight the emergence of theoretical and computational chemistry as a tool for discovery in addition to its traditional role of interpreting experimental findings.« less

  12. Analytical Chemistry Laboratory, progress report for FY 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1993 (October 1992 through September 1993). This annual report is the tenth for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has research programs in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require development or modification of methods and adaption of techniques to obtain useful analytical data. The ACL is administratively within the Chemical Technology Division (CMT), its principal ANL client, but provides technical support for many of the technical divisions and programs at ANL. The ACL has four technical groups--Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis--which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL.

  13. Appendix SOTERM: Actinide Chemistry Source Term

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SOTERM-2014 Actinide Chemistry Source Term United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix SOTERM-2014 Actinide Chemistry Source Term Table of Contents SOTERM-1.0 Introduction SOTERM-2.0 Expected WIPP Repository Conditions, Chemistry, and Processes SOTERM-2.1 Ambient Geochemical Conditions SOTERM-2.2 Repository Conditions SOTERM-2.2.1 Repository Pressure SOTERM-2.2.2 Repository

  14. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  15. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  16. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  17. Chemistry Controls Material's Nanostructure | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Controls Material's Nanostructure Tweaking the chemicals used to form nanorods can be used to control their shape.Controlling a nanorod's shape is a key to controlling ...

  18. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 Last edited: 2016-04-29 11:34:4

  19. 2005 American Conference on Theoretical Chemistry

    SciTech Connect (OSTI)

    Carter, Emily A

    2006-11-19

    The materials uploaded are meant to serve as final report on the funds provided by DOE-BES to help sponsor the 2005 American Conference on Theoretical Chemistry.

  20. Coordination Chemistry in Magnesium Battery Electrolytes: How...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 3, 2014, Research Highlights Coordination Chemistry in Magnesium Battery Electrolytes: How Ligands Affect Their Performance (Top) Schematic illustration of the solution ...

  1. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Office of Scientific and Technical Information (OSTI)

    are excellent combustion fuels and feedstocks for ethylene and propylene production. ... Technical Report, 1980 Superacid Catalyzed Coal Conversion Chemistry. 1st and 2nd ...

  2. understanding the low-temperature combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-temperature combustion chemistry - Sandia Energy Energy Search Icon Sandia Home ... EnergyWater History Water Monitoring & Treatment Technology Decision Models for ...

  3. Symposium on high temperature and materials chemistry

    SciTech Connect (OSTI)

    Not Available

    1989-10-01

    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  4. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 Last edited: 2016-04-29 11:34:4

  5. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Office of Scientific and Technical Information (OSTI)

    George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information * Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah ...

  6. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Screening of Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrodes Vehicle Technologies Office Merit Review 2015: Materials Benchmarking Activities for ...

  7. new chemistry to break down cell walls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    new chemistry to break down cell walls - Sandia Energy Energy Search Icon Sandia Home ... Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power ...

  8. Experimental evaluation of dry/wet air-cooled heat exchangers. Progress report

    SciTech Connect (OSTI)

    Hauser, S.G.; Gruel, R.L.; Huenefeld, J.C.; Eschbach, E.J.; Johnson, B.M.; Kreid, D.K.

    1982-08-01

    The ultimate goal of this project was to contribute to the development of improved cooling facilities for power plants. Specifically, the objective during FY-81 was to experimentally determine the thermal performance and operating characteristics of an air-cooled heat exchanger surface manufactured by the Unifin Company. The performance of the spiral-wound finned tube surface (Unifin) was compared with two inherently different platefin surfaces (one developed by the Trane Co. and the other developed by the HOETERV Institute) which were previously tested as a part of the same continuing program. Under dry operation the heat transfer per unit frontal area per unit inlet temperature difference (ITD) of the Unifin surface was 10% to 20% below that of the other two surfaces at low fan power levels. At high fan power levels, the performances of the Unifin and Trane surfaces were essentially the same, and 25% higher than the HOETERV surface. The design of the Unifin surface caused a significantly larger air-side pressure drop through the heat exchanger both in dry and deluge operation. Generally higher overall heat transfer coefficients were calculated for the Unifin surface under deluged operation. They ranged from 2.0 to 3.5 Btu/hr-ft/sup 2/-/sup 0/F as compared to less than 2.0 Btu hr-ft/sup 2/-/sup 0/F for the Trane and HOETERV surfaces under similar conditions. The heat transfer enhancement due to the evaporative cooling effect was also measureably higher with the Unifin surface as compared to the Trane surface. This can be primarily attributed to the better wetting characteristics of the Unifin surface. If the thermal performance of the surfaces are compared at equal face velocities, the Unifin surface is as much as 35% better. This method of comparison accounts for the wetting characteristics while neglecting the effect of pressure drop. Alternatively the surfaces when compared at equal pressure drop essentially the same thermal performance.

  9. Patterned functional arrays by selective de-wetting

    SciTech Connect (OSTI)

    FAN,HONGYOU; DOSHI,DHAVAL; LU,YUNFENG; BRINKER,C. JEFFREY

    2000-05-11

    Using a micro-Contact Printing ({mu}-CP) technique, substrates are prepared with patterns of hydrophilic, hydroxyl-terminated SAMS and hydrophobic methyl-terminated SAMS. Beginning with a homogeneous solution of silica, surfactant, ethanol, water, and functional silane, preferential ethanol evaporation during dip-coating, causes water enrichment and selective de-wetting of the hydrophobic SAMS. Correspondingly, film deposition occurs exclusively on the patterned hydrophilic SAMS. In addition, by co-condensation of tetrafunctional silanes (Si(OR){sub 4}) with tri-functional organosilanes ((RO){sub 3}Si(CH{sub 2}){sub 3}NH{sub 2}), the authors have selectively derived the silica framework with functional amine NH{sub 2} groups. A pH sensitive, micro-fluidic system was formed by further conjugation reactions with pH sensitive dye molecules.

  10. Wet chemical thinning of molybdenum disulfide down to its monolayer

    SciTech Connect (OSTI)

    Amara, Kiran Kumar; Chu, Leiqiang; Kumar, Rajeev; Toh, Minglin; Eda, Goki

    2014-09-01

    We report on the preparation of mono- and bi-layer molybdenum disulfide (MoS{sub 2}) from a bulk crystal by facile wet chemical etching. We show that concentrated nitric acid (HNO{sub 3}) effectively etches thin MoS{sub 2} crystals from their edges via formation of MoO{sub 3}. Interestingly, etching of thin crystals on a substrate leaves behind unreacted mono- and bilayer sheets. The flakes obtained by chemical etching exhibit electronic quality comparable to that of mechanically exfoliated counterparts. Our findings indicate that the self-limiting chemical etching is a promising top-down route to preparing atomically thin crystals from bulk layer compounds.

  11. Crude Oil and Lease Condensate Wet Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. proved reserves, and reserves changes, 2013-2014 Crude Oil and Lease Condensate Wet Natural Gas billion barrels trillion cubic feet U.S. proved reserves at December 31, 2013 36.5 354.0 Total discoveries 5.4 50.5 Net revisions 0.4 1.0 Net Adjustments, Sales, Acquisitions 0.8 11.5 Production -3.2 -28.1 Net additions to U.S. proved reserves 3.4 34.8 U.S. proved reserves at December 31, 2014 39.9 388.8 Percent change in U.S. proved reserves 9.3% 9.8% Percent change calculated from unrounded

  12. U.S. Nonassociated Natural Gas, Wet After Lease Separation, New...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoir Discoveries in Old Fields (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Wet After Lease Separation, New Reservoir Discoveries in Old Fields (Billion Cubic Feet) ...

  13. U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoir Discoveries in Old Fields (Billion Cubic Feet) U.S. Associated-Dissolved Natural Gas, Wet After Lease Separation, New Reservoir Discoveries in Old Fields (Billion Cubic ...

  14. MHK Projects/US Navy Wave Energy Technology WET Program at Marine...

    Open Energy Info (EERE)

    US Navy Wave Energy Technology WET Program at Marine Corps Base Hawaii MCBH < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map......

  15. WPN 97-6: Approval of Wet-Spray Cellulose Insulation as an Allowable Weatherization Material

    Broader source: Energy.gov [DOE]

    To provide states with information about the approved use of wet-spray cellulose for use in the low-income Weatherization Assistance Program.

  16. Wet oxidation of high-concentration reactive dyes

    SciTech Connect (OSTI)

    Chen, G.; Lei, L.; Yue, P.L.

    1999-05-01

    Advanced oxidation methods were used to degrade reactive dyes at high concentrations in aqueous solutions. Wet peroxide oxidation (WPO) was found to be the best method in terms of the removal of color and total organic carbon (TOC). Reactive blue (Basilen Brilliant Blue P-3R) was chosen as a model dye for determining the suitable reaction conditions. The variables studied include reaction temperature, H{sub 2}O{sub 2} dosage, solution pH, dye concentration, and catalyst usage. The removal of TOC and color by wet oxidation is very sensitive to the reaction temperature. At 150 C, the removal of 77% TOC and 90% color was obtained in less than 30 min. The initial TOC removal rate is proportional to the H{sub 2}O{sub 2} dosage. The TOC removal is insignificant even when 50% of the stoichiometric amount of H{sub 2}O{sub 2} is used. No color change is observed until the dosage of H{sub 2}O{sub 2} is 100% of the stoichiometric amount. The color removal is closely related to TOC removal. When the pH of the solution is adjusted to 3.5, the dye degradation rate increases significantly. The rates of TOC and color removal are enhanced by using a Cu{sup 2+} catalyst. Another four reactive dyes, Procion Red PX-4B, Cibacron Yellow P-6GS, Cibacron Brown P-6R, and Procion Black PX-2R, were treated at 150 C using WPO. More than 80% TOC was removed from the solution in less than 15 min. The process can remove the colors of al these dyes except Procion Black PX-2R.

  17. Chemistry and Processing of Nanostructured Materials

    SciTech Connect (OSTI)

    Fox, G A; Baumann, T F; Hope-Weeks, L J; Vance, A L

    2002-01-18

    Nanostructured materials can be formed through the sol-gel polymerization of inorganic or organic monomer systems. For example, a two step polymerization of tetramethoxysilane (TMOS) was developed such that silica aerogels with densities as low as 3 kg/m{sup 3} ({approx} two times the density of air) could be achieved. Organic aerogels based upon resorcinol-formaldehyde and melamine-formaldehyde can also be prepared using the sol-gel process. Materials of this type have received significant attention at LLNL due to their ultrafine cell sizes, continuous porosity, high surface area and low mass density. For both types of aerogels, sol-gel polymerization depends upon the transformation of these monomers into nanometer-sized clusters followed by cross-linking into a 3-dimensional gel network. While sol-gel chemistry provides the opportunity to synthesize new material compositions, it suffers from the inability to separate the process of cluster formation from gelation. This limitation results in structural deficiencies in the gel that impact the physical properties of the aerogel, xerogel or nanocomposite. In order to control the properties of the resultant gel, one should be able to regulate the formation of the clusters and their subsequent cross-linking. Towards this goal, we are utilizing dendrimer chemistry to separate the cluster formation from the gelation so that new nanostructured materials can be produced. Dendrimers are three-dimensional, highly branched macromolecules that are prepared in such a way that their size, shape and surface functionality are readily controlled. The dendrimers will be used as pre-formed clusters of known size that can be cross-linked to form an ordered gel network.

  18. Evaluation of dry versus wet unloading of spent nuclear fuel shipping casks

    SciTech Connect (OSTI)

    Allen, Jr., G. C.; Lambert, R. W.; Larkin, D. J.

    1980-01-01

    The Transportation Technology Center at Sandia National Laboratories completed an evaluation of unloading methods for spent fuel by sponsoring technical programs at Exxon Nuclear Company, Inc., and General Electric Corporation. These programs provided a comprehensive assessment of the relative merits, capabilities, and limitations of dry and wet unloading methods. The results of this evaluation, when continued, are expected to impact the development of future spent fuel and waste transportation systems. In addition, final conclusions of the evaluation will provide input to designers of future receiving and shipping interfaces at away-from-reactor spent fuel storage facilities and geologic nuclear waste repositories in the United States. The results presented here apply to the case where uncanistered spent fuel from light water reactors is to be handled. The conclusions may be different if uncontaminated canistered waste forms are considered in the future.

  19. Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment

    SciTech Connect (OSTI)

    Neu, M.P.

    1993-11-01

    The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

  20. Chemistry: Theory - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theory Chemistry: Theory Presentations from 2010 CEFRC First Annual Conference MultireferenceCorrelated WavefunctionCalculations and Reaction Flux Analyses of Methyl Ester Combustion Emily A. Carter, Princeton University Constructing Accurate Combustion Chemistry Models William H. Green, MIT Theoretical Gas Phase Chemical Kinetics Stephen J. Klippenstein, Argonne National Laboratory Theoretical Chemical Kinetics and Combustion Modeling James A. Miller, Argonne National Laboratory Computation of

  1. Radiation chemistry in solvent extraction: FY2010 Research

    SciTech Connect (OSTI)

    Bruce J. Mincher; Leigh R. Martin; Stephen P. Mezyk

    2010-09-01

    This report summarizes work accomplished under the Fuel Cycle Research and Development (FCR&D) program in the area of radiation chemistry during FY 2010. The tasks assigned during FY 2010 included: Development of techniques to measure free radical reaction kinetics in the organic phase. Initiation of an alpha-radiolysis program Initiation of an effort to understand dose rate effects in radiation chemistry Continued work to characterize TALSPEAK radiation chemistry Progress made on each of these tasks is reported here. Briefly, a method was developed and used to measure the kinetics of the reactions of the NO3 radical with solvent extraction ligands in organic solution, and the method to measure OH radical reactions under the same conditions has been designed. Rate constants for the CMPO and DMDOHEMA reaction with NO3 radical in organic solution are reported. Alpha-radiolysis was initiated on samples of DMDOHEMA in alkane solution using He ion beam irradiation and 211At isotope irradiation. The samples are currently being analyzed for comparison to DMDOHEMA ?-irradiations using a custom-developed mass spectrometric method. Results are also reported for the radiolytic generation of nitrous acid, in ?-irradiated nitric acid. It is shown that the yield of nitrous acid is unaffected by an order-of-magnitude change in dose rate. Finally, recent results for TALSPEAK radiolysis are reported, summarizing the effects on solvent extraction efficiency due to HDEHP irradiation, and the stable products of lactic acid and DTPA irradiation. In addition, results representing increased scope are presented for the radiation chemistry program. These include an investigation of the effect of metal complexation on radical reaction kinetics using DTPA as an example, and the production of a manuscript reporting the mechanism of Cs-7SB radiolysis. The Cs-7SB work takes advantage of recent results from a current LDRD program to understand the fundamental chemistry of nitration

  2. Archaeopteryx Feathers and Bone Chemistry Fully Revealed via Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Archaeopteryx Feathers and Bone Chemistry Fully Revealed via Synchrotron Imaging Archaeopteryx specimens are important but extremely rare fossils. Due to their possession of both reptilian (jaws with teeth, long bony tail) and avian (feathered wings) characters, Archaeopteryx has been crucial in the development of Darwinian evolution. Despite their importance, no Archaeopteryx specimen has ever been chemically analyzed. This in large part may be explained by the analytical obstacles

  3. Pentavalent Uranium Chemistry - Synthetic Pursuit Of A Rare Oxidation State

    SciTech Connect (OSTI)

    Graves, Christopher R; Kiplinger, Jaqueline L

    2009-01-01

    This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.

  4. Critical-point wetting at the metastable chemical binodal in undercooled Fe-Cu alloys

    SciTech Connect (OSTI)

    Wilde, G.; Perepezko, J.H.

    1999-08-10

    Complementary results of differential thermal analysis and microstructural examination on Fe-Cu alloys provide the first evidence for critical-point wetting occurring at a completely metastable miscibility gap. The perfect wetting conditions hold for a composition range of 50--65 at.% Fe in the vicinity of the critical concentration. For samples encased with a glass slag, the Cu-rich liquid completely wets the glass upon undercooling to the metastable miscibility gap. In the perfect-wetting range, the metastable homogeneous liquid phase exhibited phase separation without undercooling below the chemical binodal. At deep undercooling, solidification of alloys with phase separated liquids results in a coarse scaled two-phase microstructure. In contrast, the homogeneous liquid phase of samples with compositions outside the perfect wetting range did undercool below the equilibrium onset of the metastable phase separation reaction. The phase separation in these samples occurred on a much finer scale. For samples without a glass encasement and thus in the presence of the Al{sub 2}O{sub 3} crucible and an iron oxide layer, perfect wetting occurred near the consolute point on both sides of the metastable miscibility gap. This demonstrates that critical-point wetting is independent of the surface environment, but the wetting phase selected is surface sensitive.

  5. Radiation chemistry in solvent etxraction: FY2011 research

    SciTech Connect (OSTI)

    Bruce J. Mincher; Stephen P. Mezyk; Leigh R. Martin

    2011-09-01

    This report summarizes work accomplished under the Fuel Cycle Research and Development (FCR&D) program in the area of radiation chemistry during FY 2011. The tasks assigned during FY 2011 included: (1) Continue measurements free radical reaction kinetics in the organic phase; (2) Continue development of an alpha-radiolysis program and compare alpha and gamma radiolysis for CMPO; (3) Initiate an effort to understand dose rate effects in radiation chemistry; and (4) Continued work to characterize TALSPEAK radiation chemistry, including the examination of metal complexed ligand kinetics. Progress made on each of these tasks is reported here. Briefly, the method developed to measure the kinetics of the reactions of the NO3 radical with solvent extraction ligands in organic solution during FY10 was extended here to a number of compounds to better understand the differences between radical reactions in the organic versus aqueous phases. The alpha-radiolysis program in FY11 included irradiations of CMPO solutions with 244Cm, 211At and the He ion beam, for comparison to gamma irradiations, and a comparison of the gamma irradiation results for CMPO at three different gamma dose rates. Finally, recent results for TALSPEAK radiolysis are reported, summarizing the latest in an effort to understand how metal complexation to ligands affects their reaction kinetics with free radicals.

  6. Solar Energy Education. Renewable energy activities for chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistry and physics Citation Details In-Document Search Title: Solar Energy Education. Renewable energy activities for chemistry and physics You are accessing a document from ...

  7. Training April 5 - Material Science and Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 5 Training April 5 - Material Science and Chemistry Applications March 9, 2011 by Francesca Verdier Training on "Using Chemistry and Material Sciences Applications" will be ...

  8. Diamond Plates Create Nanostructures through Pressure, Not Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plates Create Nanostructures through Pressure, Not Chemistry - Sandia Energy Energy Search ... Diamond Plates Create Nanostructures through Pressure, Not Chemistry HomeAdvanced ...

  9. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the ...

  10. NERSC training events: Data Transfer and Archiving; Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications ...

  11. Characteristics and Effects of Lubricant Additive Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle Fuel Economy Characteristics and Effects of Lubricant Additive Chemistry and ...

  12. PROJECT PROFILE: Defining the Defect Chemistry and Structural...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Defining the Defect Chemistry and Structural Properties Required for 24%-Efficient CdTe Devices PROJECT PROFILE: Defining the Defect Chemistry and Structural Properties Required for ...

  13. June 26 Training: Using Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 26 Training: Using Chemistry and Material Sciences Applications June 26 Training: Using Chemistry and Material Sciences Applications June 15, 2012 by Francesca Verdier NERSC ...

  14. New Chemistries Found for Liquid Batteries: Grid-scale approach...

    Broader source: Energy.gov (indexed) [DOE]

    John F. Elliott Professor of Materials Chemistry, and postdoc Takanari Ouchi, along with ... he says. "It was the most difficult chemistry" to make work but had potential benefits ...

  15. Zelenay receives professorship in chemistry from president of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zelenay receives professorship in chemistry from president of Poland Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay of Materials Synthesis and ...

  16. Nan Sauer named Associate Director for Chemistry, Life, and Earth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sauer named AD for Chemistry, Life, and Earth Sciences Nan Sauer named Associate Director for Chemistry, Life, and Earth Sciences Sauer has a distinguished track record as a ...

  17. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    ... E.Smalley).- Departments of Chemistry & Physics, Rice University Smith III, Milton R (Milton R Smith III) - Department of Chemistry, Michigan State University Smith, Arthur ...

  18. Chemistry, phase formation, and catalytic activity of thinpalladium...

    Office of Scientific and Technical Information (OSTI)

    Title: Chemistry, phase formation, and catalytic activity of thin palladium-containing oxide films synthesized by plasma-assisted physical vapor deposition The chemistry, ...

  19. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    State University Alavi, Ali (Ali Alavi) - Department of Chemistry, University of Cambridge Allen, Heather C.(Heather C.Allen).- Department of Chemistry, Ohio State University ...

  20. The Organic Chemistry of Conducting Polymers (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: The Organic Chemistry of Conducting Polymers Citation Details In-Document Search Title: The Organic Chemistry of Conducting Polymers For the last several years, ...

  1. Atomic Chemistry in Turbulent Media I: Effect of Atomic Cooling...

    Office of Scientific and Technical Information (OSTI)

    Atomic Chemistry in Turbulent Media I: Effect of Atomic Cooling Citation Details In-Document Search Title: Atomic Chemistry in Turbulent Media I: Effect of Atomic Cooling Authors: ...

  2. Final Report: Ionization chemistry of high temperature molecular...

    Office of Scientific and Technical Information (OSTI)

    Final Report: Ionization chemistry of high temperature molecular fluids Citation Details In-Document Search Title: Final Report: Ionization chemistry of high temperature molecular ...

  3. Ultrafast Shock Initiation of Exothermic Chemistry in Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Shock Initiation of Exothermic Chemistry in Hydrogen Peroxide Citation Details In-Document Search Title: Ultrafast Shock Initiation of Exothermic Chemistry in Hydrogen Peroxide ...

  4. Coagulation chemistries for silica removal from cooling tower...

    Office of Scientific and Technical Information (OSTI)

    Coagulation chemistries for silica removal from cooling tower water. Citation Details In-Document Search Title: Coagulation chemistries for silica removal from cooling tower water. ...

  5. Chemistry and Beyond : the tale of a surface chemist. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Chemistry and Beyond : the tale of a surface chemist. Citation Details In-Document Search Title: Chemistry and Beyond : the tale of a surface chemist. No abstract prepared. ...

  6. Plastic Bags to Batteries: A Green Chemistry Solution | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastic Bags to Batteries: A Green Chemistry Solution Share Description Plastic bags are the scourge of roadsides, parking lots and landfills. But chemistry comes to the rescue At...

  7. Private Company Uses EERE-Supported Chemistry Model to Substantially...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Private Company Uses EERE-Supported Chemistry Model to Substantially Improve Combustion Engine Simulation Software Private Company Uses EERE-Supported Chemistry Model to ...

  8. BETO Partners Win 20th Annual Presidential Green Chemistry Challenge...

    Broader source: Energy.gov (indexed) [DOE]

    Two of the six winners of the 20th Annual Presidential Green Chemistry Challenge ... technologies that promote environmental and economic benefits using green chemistry. ...

  9. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1989-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  10. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1990-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  11. Plasma chemistry in wire chambers

    SciTech Connect (OSTI)

    Wise, J.

    1990-05-01

    The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to remove trace water and oxygen contaminants from the gas resulted in an increase in the average molecular weight of the products, consistent with results from low-pressure rf-discharge plasmas. It is suggested that because water and oxygen inhibit polymer growth in the gas phase that they may also reduce polymer deposition in proportional tubes and therefore retard wire aging processes. Mechanistic implications of the plasma reactions of hydrocarbons with oxygen are suggested. Unresolved issues in this work and proposals for further study are discussed.

  12. CRYSTAL CHEMISTRY OF HYDROUS MINERALS

    SciTech Connect (OSTI)

    Y. ZHAO; ET AL

    2001-02-01

    Hydrogen has long been appreciated for its role in geological processes of the Earth's crust. However, its role in Earth's deep interior has been neglected in most geophysical thinking. Yet it is now believed that most of our planet's hydrogen may be locked up in high pressure phases of hydrous silicate minerals within the Earth's mantle. This rocky interior (approximately 7/8 of Earth's volume) is conjectured to contain 1-2 orders of magnitude more water than the more obvious oceans (the ''hydrosphere'') and atmosphere. This project is aimed at using the capability of neutron scattering from hydrogen to study the crystal chemistry and stability of hydrogen-bearing minerals at high pressures and temperatures. At the most basic level this is a study of the atomic position and hydrogen bond itself. We have conducted experimental runs on hydrous minerals under high pressure and high temperature conditions. The crystallographic structure of hydrous minerals at extreme conditions and its structural stability, and hydrogen bond at high P-T conditions are the fundamental questions to be addressed. The behavior of the hydrous minerals in the deep interior of the Earth has been discussed.

  13. COOPERATIVE RESEARCH IN C1 CHEMISTRY

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2001-04-30

    Faculty and students from five universities (Kentucky, West Virginia, Utah, Pittsburgh and Auburn) are collaborating on a basic research program to develop novel C1 chemistry processes for the production of clean, high quality transportation fuel. An Industrial Advisory Board (IAB) with members from Chevron, Eastman Chemical, Energy International, Teir Associates, and the Department of Defense has been formed to provide practical guidance to the program. The program has two principal objectives. (1) Develop technology for conversion of C1 source materials (natural gas, synthesis gas, carbon dioxide and monoxide, and methanol) into clean, high efficiency transportation fuel. (2) Develop novel processes for producing hydrogen from natural gas and other hydrocarbons. Some of the principal accomplishments of the program in its first two years are: (1) The addition of acetylenic compounds in Fischer-Tropsch synthesis is found to produce significant amounts of oxygenated products in FT diesel fuels. Such oxygenated products should decrease particulate matter (PM) emissions. (2) Nanoscale, binary, Fe-based catalysts supported on alumina have been shown to have significant activity for the decomposition of methane into pure hydrogen and potentially valuable multi-walled carbon nanotubes. (3) Catalytic synthesis processes have been developed for synthesis of diethyl carbonate, higher ethers, and higher alcohols from C1 source materials. Testing of the effect of adding these oxygenates to diesel fuel on PM emissions has begun using a well-equipped small diesel engine test facility. (4) Supercritical fluid (SCF) FT synthesis has been conducted under SCF hexane using both Fe and Co catalysts. There is a marked effect on the hydrocarbon product distribution, with a shift to higher carbon number products. These and other results are summarized.

  14. Reaction chemistry of nitrogen species in hydrothermal systems: Simple reactions, waste simulants, and actual wastes

    SciTech Connect (OSTI)

    Dell`Orco, P.; Luan, L.; Proesmans, P.; Wilmanns, E.

    1995-02-01

    Results are presented from hydrothermal reaction systems containing organic components, nitrogen components, and an oxidant. Reaction chemistry observed in simple systems and in simple waste simulants is used to develop a model which presents global nitrogen chemistry in these reactive systems. The global reaction path suggested is then compared with results obtained for the treatment of an actual waste stream containing only C-N-0-H species.

  15. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces New Technique Gives a Deeper Look into the Chemistry of Interfaces Print Monday, 23 February 2015 10:48 A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with

  16. Modification of heterogeneous chemistry by complex substrate morphology

    SciTech Connect (OSTI)

    Henson, B.F.; Buelow, S.J.; Robinson, J.M.

    1998-12-31

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Chemistry in many environmental systems is determined at some stage by heterogeneous reaction with a surface. Typically the surface exists as a dispersion or matrix of particulate matter or pores, and a determination of the heterogeneous chemistry of the system must address the extent to which the complexity of the environmental surface affects the reaction rates. Reactions that are of current interest are the series of chlorine nitrate reactions important in polar ozone depletion. The authors have applied surface spectroscopic techniques developed at LANL to address the chemistry of chlorine nitrate reactions on porous nitric and sulfuric acid ice surfaces as a model study of the measurement of complex, heterogeneous reaction rates. The result of the study is an experimental determination of the surface coverage of one adsorbed reagent and a mechanism of reactivity based on the dependence of this coverage on temperature and vapor pressure. The resulting mechanism allows the first comprehensive modeling of chlorine nitrate reaction probability data from several laboratories.

  17. A filtered tabulated chemistry model for LES of premixed combustion

    SciTech Connect (OSTI)

    Fiorina, B.; Auzillon, P.; Darabiha, N.; Gicquel, O.; Veynante, D.; Vicquelin, R.

    2010-03-15

    A new modeling strategy called F-TACLES (Filtered Tabulated Chemistry for Large Eddy Simulation) is developed to introduce tabulated chemistry methods in Large Eddy Simulation (LES) of turbulent premixed combustion. The objective is to recover the correct laminar flame propagation speed of the filtered flame front when subgrid scale turbulence vanishes as LES should tend toward Direct Numerical Simulation (DNS). The filtered flame structure is mapped using 1-D filtered laminar premixed flames. Closure of the filtered progress variable and the energy balance equations are carefully addressed in a fully compressible formulation. The methodology is first applied to 1-D filtered laminar flames, showing the ability of the model to recover the laminar flame speed and the correct chemical structure when the flame wrinkling is completely resolved. The model is then extended to turbulent combustion regimes by including subgrid scale wrinkling effects in the flame front propagation. Finally, preliminary tests of LES in a 3-D turbulent premixed flame are performed. (author)

  18. Analytical Chemistry Laboratory progress report for FY 1984

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Jensen, K.J.; Stetter, J.R.

    1985-03-01

    Technical and administrative activities of the Analytical Chemistry Laboratory (ACL) are reported for fiscal year 1984. The ACL is a full-cost-recovery service center, with the primary mission of providing a broad range of technical support services to the scientific and engineering programs at ANL. In addition, ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL is administratively within the Chemical Technology Division, the principal user, but provides technical support for all of the technical divisions and programs at ANL. The ACL has three technical groups - Chemical Analysis, Instrumental Analysis, and Organic Analysis. Under technical activities 26 projects are briefly described. Under professional activities, a list is presented for publications and reports, oral presentations, awards and meetings attended. 6 figs., 2 tabs.

  19. Perspective: Water cluster mediated atmospheric chemistry

    SciTech Connect (OSTI)

    Vaida, Veronica

    2011-07-14

    The importance of water in atmospheric and environmental chemistry initiated recent studies with results documenting catalysis, suppression and anti-catalysis of thermal and photochemical reactions due to hydrogen bonding of reagents with water. Water, even one water molecule in binary complexes, has been shown by quantum chemistry to stabilize the transition state and lower its energy. However, new results underscore the need to evaluate the relative competing rates between reaction and dissipation to elucidate the role of water in chemistry. Water clusters have been used successfully as models for reactions in gas-phase, in aqueous condensed phases and at aqueous surfaces. Opportunities for experimental and theoretical chemical physics to make fundamental new discoveries abound. Work in this field is timely given the importance of water in atmospheric and environmental chemistry.

  20. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, Jerald A.

    1997-01-01

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for 1) cleaning, developing or etching, 2) rinsing, and 3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material.

  1. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, J.A.

    1997-08-26

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for (1) cleaning, developing or etching, (2) rinsing, and (3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material. 5 figs.

  2. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of

  3. Hiking the valleys of quatum chemistry

    SciTech Connect (OSTI)

    Aikens, Christine Marie

    2005-08-01

    This thesis is concerned with both the application and the extension of quantum chemical methods. Each chapter of the thesis represents a paper that has been published in or will be submitted to a scientific journal. The first three chapters of this thesis describe contributions made to chemistry through the use of quantum chemical methods, while the final two chapters illustrate the development of new methods. Chapter 2 and Chapter 3 characterize a study of the electronic structure and magnetic properties of homodinuclear titanium(III) complexes, in order to determine trends related to their potential use as molecular magnets. Chapter 2 focuses on hydride and halide bridging and terminal ligands, while Chapter 3 explores bridging ligands from other groups in the periodic table. Chapter 4 portrays a study of the solvation of glycine. Microsolvation and continuum solvation approaches are investigated in order to study the structures of small glycine-water clusters and determine the energy difference between the zwitterionic and nonionized forms of glycine, the simplest amino acid. Chapters 5 and 6 describe the implementation of analytic gradients, which are required for efficient molecular geometry optimizations, for two open-shell second-order perturbation theory methods. Chapter 5 discusses gradients for unrestricted Moeller-Plesset perturbation theory, and Chapter 6 describes gradients for Z-averaged perturbation theory.

  4. Chemistry Division annual progress report for period ending January 31, 1984

    SciTech Connect (OSTI)

    Not Available

    1984-05-01

    Progress is reported in the following fields: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, high-temperature chemistry and thermodynamics of structural materials, chemistry of transuranium elements and compounds, separations chemistry, elecrochemistry, catalysis, chemical physics, theoretical chemistry, nuclear waste chemistry, chemistry of hazardous chemicals, and thermal energy storage.

  5. "Wet" Waste-to-Energy in the Bioenergy Technologies Office | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy "Wet" Waste-to-Energy in the Bioenergy Technologies Office "Wet" Waste-to-Energy in the Bioenergy Technologies Office Introductory presentation by Jonathan Male, U.S. Department of Energy Bioenergy Technologies Office Director, at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop held March 18-19, 2015. "Wet" Waste-to-Energy in the Bioenergy Technologies Office (2.4 MB) More Documents & Publications Waste-to-Energy

  6. Chemistry Impacts in Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P; Bunting, Bruce G

    2006-09-01

    The use of homogeneous charge compression ignition (HCCI) combustion in internal combustion engines is of interest because it has the potential to produce low oxides of nitrogen (NOx) and particulate matter (PM) emissions while providing diesel-like efficiency. In HCCI combustion, a premixed charge of fuel and air auto-ignites at multiple points in the cylinder near top dead center (TDC), resulting in rapid combustion with very little flame propagation. In order to prevent excessive knocking during HCCI combustion, it must take place in a dilute environment, resulting from either operating fuel lean or providing high levels of either internal or external exhaust gas recirculation (EGR). Operating the engine in a dilute environment can substantially reduce the pumping losses, thus providing the main efficiency advantage compared to spark-ignition (SI) engines. Low NOx and PM emissions have been reported by virtually all researchers for operation under HCCI conditions. The precise emissions can vary depending on how well mixed the intake charge is, the fuel used, and the phasing of the HCCI combustion event; but it is common for there to be no measurable PM emissions and NOx emissions <10 ppm. Much of the early HCCI work was done on 2-stroke engines, and in these studies the CO and hydrocarbon emissions were reported to decrease [1]. However, in modern 4-stroke engines, the CO and hydrocarbon emissions from HCCI usually represent a marked increase compared with conventional SI combustion. This literature review does not report on HCCI emissions because the trends mentioned above are well established in the literature. The main focus of this literature review is the auto-ignition performance of gasoline-type fuels. It follows that this discussion relies heavily on the extensive information available about gasoline auto-ignition from studying knock in SI engines. Section 2 discusses hydrocarbon auto-ignition, the octane number scale, the chemistry behind it, its

  7. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J.

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  8. chemistry | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    organization TechConnect for the development of prototype Hydrocarbon Membranes for Energy and Water Electrochemical Systems. Sandia's submission placed in the top 15... ...

  9. "Wet" Waste-to-Energy in the Bioenergy Technologies Office

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (BETO) "Wet" Waste-to-Energy 3/18/2015 Jonathan L. Male Director, Bioenergy Technologies Office 2 | Bioenergy Technologies Office Outline I. BETO Core Focus Areas II. Criteria for BETO Investments III. Motivation for "Wet" Waste-to-Energy IV. Relevant Existing BETO Efforts V. Context for this Workshop VI. Questions 3 | Bioenergy Technologies Office EERE Organization Chart Assistant Secretary David Danielson Office of Transportation Vehicle Technologies Office (VTO) Bioenergy

  10. ChemCam follows the 'Yellowknife Road' to Martian wet area

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Yellowknife Road' to martian wet area ChemCam follows the 'Yellowknife Road' to martian wet area Researchers have tracked a trail of minerals that point to the prior presence of water at the Curiosity rover site on Mars. January 15, 2013 The Mars Science Laboratory's Curiosity Rover recently took this photo of the Martian landscape looking toward Mount Sharp while on its way toward Yellowknife Bay-an area where researchers have found minerals indicating the past presence of water. (NASA Photo)

  11. Advanced fuel chemistry for advanced engines.

    SciTech Connect (OSTI)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  12. Structure, chemistry, and properties of mineral nanoparticles

    SciTech Connect (OSTI)

    Waychunas, G.A.; Zhang, H.; Gilbert, B.

    2008-12-02

    Nanoparticle properties can depart markedly from their bulk analog materials, including large differences in chemical reactivity, molecular and electronic structure, and mechanical behavior. The greatest changes are expected at the smallest sizes, e.g. 10 nm and below, where surface effects are expected to dominate bonding, shape and energy considerations. The precise chemistry at nanoparticle interfaces can have a profound effect on structure, phase transformations, strain, and reactivity. Certain phases may exist only as nanoparticles, requiring transformations in chemistry, stoichiometry and structure with evolution to larger sizes. In general, mineralogical nanoparticles have been little studied.

  13. Liquefaction chemistry and kinetics: Hydrogen utilization studies

    SciTech Connect (OSTI)

    Rothenberger, K.S.; Warzinski, R.P.; Cugini, A.V.

    1995-12-31

    The objectives of this project are to investigate the chemistry and kinetics that occur in the initial stages of coal liquefaction and to determine the effects of hydrogen pressure, catalyst activity, and solvent type on the quantity and quality of the products produced. The project comprises three tasks: (1) preconversion chemistry and kinetics, (2) hydrogen utilization studies, and (3) assessment of kinetic models for liquefaction. The hydrogen utilization studies work will be the main topic of this report. However, the other tasks are briefly described.

  14. Visualizing Chemistry: The Progess and Promise of Advanced Chemical Imaging

    SciTech Connect (OSTI)

    Committee on Revealing Chemistry Through Advanced Chemical Imaging

    2006-09-01

    The field of chemical imaging can provide detailed structural, functional, and applicable information about chemistry and chemical engineering phenomena that have enormous impacts on medicine, materials, and technology. In recognizing the potential for more research development in the field of chemical imaging, the National Academies was asked by the National Science Foundation, Department of Energy, U.S. Army, and National Cancer Institute to complete a study that would review the current state of molecular imaging technology, point to promising future developments and their applications, and suggest a research and educational agenda to enable breakthrough improvements in the ability to image molecular processes simultaneously in multiple physical dimensions as well as time. The study resulted in a consensus report that provides guidance for a focused research and development program in chemical imaging and identifies research needs and possible applications of imaging technologies that can provide the breakthrough knowledge in chemistry, materials science, biology, and engineering for which we should strive. Public release of this report is expected in early October.

  15. Inorganic, Isotope, and Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Innovative, Lower Cost Sensors and Controls Yield Better Energy Efficiency Innovative, Lower Cost Sensors and Controls Yield Better Energy Efficiency March 23, 2015 - 1:05pm Addthis ORNL researchers are experimenting with additive roll-to-roll manufacturing techniques to develop low-cost wireless sensors. ORNL’s Pooran Joshi shows how the process enables electronics components to be printed on flexible plastic substrates. Credit: Oak Ridge National Lab ORNL

  16. Development of a two-body wet abrasion test method with attention...

    Office of Scientific and Technical Information (OSTI)

    SiC grinding papers were used under fixed load and speed to rank the abrasive wear of seven alloy steels, some of which are candidates for drill cones for geothermal drilling. ...

  17. User's guide for the BNW-III optimization code for modular dry/wet-cooled power plants

    SciTech Connect (OSTI)

    Braun, D.J.; Faletti, D.W.

    1984-09-01

    This user's guide describes BNW-III, a computer code developed by the Pacific Northwest Laboratory (PNL) as part of the Dry Cooling Enhancement Program sponsored by the US Department of Energy (DOE). The BNW-III code models a modular dry/wet cooling system for a nuclear or fossil fuel power plant. The purpose of this guide is to give the code user a brief description of what the BNW-III code is and how to use it. It describes the cooling system being modeled and the various models used. A detailed description of code input and code output is also included. The BNW-III code was developed to analyze a specific cooling system layout. However, there is a large degree of freedom in the type of cooling modules that can be selected and in the performance of those modules. The costs of the modules are input to the code, giving the user a great deal of flexibility.

  18. The chemistry of TALSPEAK: A review of the science

    SciTech Connect (OSTI)

    Nash, Kenneth L.

    2014-11-13

    Here, the TALSPEAK Process (Trivalent Actinide Lanthanide Separation with Phosphorus-reagent Extraction from Aqueous Komplexes) was originally developed at Oak Ridge National Laboratory by B. Weaver and F.A. Kappelmann in the 1960s. It was envisioned initially as an alternative to the TRAMEX process (selective extraction of trivalent actinides by tertiary or quaternary amines over fission product lanthanides from concentrated LiCl solutions). TALSPEAK proposed the selective extraction of trivalent lanthanides away from the actinides, which are retained in the aqueous phase as aminopolycarboxylate complexes. After several decades of research and development, the conventional TALSPEAK process (based on di-(2-ethylhexyl) phosphoric acid (extractant) in 1,4-di-isopropylbenzene (diluent) and a concentrated lactate buffer containing diethylenetriamine-N,N,N',N",N"-pentaacetic acid (actinide-selective holdback reagent)) has become a widely recognized benchmark for advanced aqueous partitioning of the trivalent 4f/5f elements. TALSPEAK chemistry has also been utilized as an actinide-selective stripping agent (Reverse TALSPEAK) with some notable success. Under ideal conditions, conventional TALSPEAK separates Am3+ from Nd3+ (the usual limiting pair) with a single-stage separation factor of about 100; both lighter and heavier lanthanides are more completely separated from Am3+. Despite this apparent efficiency, TALSPEAK has not seen enthusiastic adoption for advanced partitioning of nuclear fuels at process scale for two principle reasons: 1) all adaptations of TALSPEAK chemistry to process scale applications require rigid pH control within a narrow range of pH, and 2) phase transfer kinetics are often slower than ideal. To compensate for these effects, high concentrations of the buffer (0.5-2 M H/Na lactate) are required. Acknowledgement of these complications in TALSPEAK process development has inspired significant research activities

  19. The chemistry of TALSPEAK: A review of the science

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nash, Kenneth L.

    2014-11-13

    Here, the TALSPEAK Process (Trivalent Actinide Lanthanide Separation with Phosphorus-reagent Extraction from Aqueous Komplexes) was originally developed at Oak Ridge National Laboratory by B. Weaver and F.A. Kappelmann in the 1960s. It was envisioned initially as an alternative to the TRAMEX process (selective extraction of trivalent actinides by tertiary or quaternary amines over fission product lanthanides from concentrated LiCl solutions). TALSPEAK proposed the selective extraction of trivalent lanthanides away from the actinides, which are retained in the aqueous phase as aminopolycarboxylate complexes. After several decades of research and development, the conventional TALSPEAK process (based on di-(2-ethylhexyl) phosphoric acid (extractant) inmore » 1,4-di-isopropylbenzene (diluent) and a concentrated lactate buffer containing diethylenetriamine-N,N,N',N",N"-pentaacetic acid (actinide-selective holdback reagent)) has become a widely recognized benchmark for advanced aqueous partitioning of the trivalent 4f/5f elements. TALSPEAK chemistry has also been utilized as an actinide-selective stripping agent (Reverse TALSPEAK) with some notable success. Under ideal conditions, conventional TALSPEAK separates Am3+ from Nd3+ (the usual limiting pair) with a single-stage separation factor of about 100; both lighter and heavier lanthanides are more completely separated from Am3+. Despite this apparent efficiency, TALSPEAK has not seen enthusiastic adoption for advanced partitioning of nuclear fuels at process scale for two principle reasons: 1) all adaptations of TALSPEAK chemistry to process scale applications require rigid pH control within a narrow range of pH, and 2) phase transfer kinetics are often slower than ideal. To compensate for these effects, high concentrations of the buffer (0.5-2 M H/Na lactate) are required. Acknowledgement of these complications in TALSPEAK process development has inspired significant research activities dedicated to improving

  20. TID-4500, UC-4 Chemistry Lawpenoe R

    Office of Scientific and Technical Information (OSTI)

    TID-4500, UC-4 Chemistry Lawpenoe R a d i a f i o m L&bor&fox-y U N I V E R S I T Y O F C A L I F O R N I A L I V E R M O R E UC R L - 5 04 2 2 CI ADIABATIC EXPANSION OF HIGH ...

  1. Tularosa Basin Play Fairway Analysis: Water Chemistry

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Adam Brandt

    2015-12-15

    This shapefile contains 409 well data points on Tularosa Basin Water Chemistry, each of which have a location (UTM), temperature, quartz and Potassium/Magnesium geothermometer; as well as concentrations of chemicals like Mn, Fe, Ba, Sr, Cs, Rb, As, NH4, HCO3, SO4, F, Cl, B, SiO2, Mg, Ca, K, Na, and Li.

  2. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K.

    1993-12-01

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  3. Secretary of Energy Chu Congratulates 2012 Chemistry and Physics...

    Office of Environmental Management (EM)

    2 Chemistry and Physics Nobel Laureates Secretary of Energy Chu Congratulates 2012 Chemistry and Physics Nobel Laureates October 11, 2012 - 11:08am Addthis NEWS MEDIA CONTACT (202) ...

  4. 20th Annual Green Chemistry & Engineering Conference (Portland...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    th Annual Green Chemistry & Engineering Conference (Portland, OR) 20th Annual Green Chemistry & Engineering Conference (Portland, OR) Tue, Jun 14, 2016 2:30pm 14:30 Thu, Jun 16, ...

  5. Feb. 9 Event at Jefferson Lab Features Chemistry Demonstrations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Event at Jefferson Lab Features Chemistry Demonstrations Set to Pop Music Feb. 9 Event at Jefferson Lab Features Chemistry Demonstrations Set to Pop Music NEWPORT NEWS, Va., Feb. ...

  6. PRINCETON UNIVERSITY DEPARTMENT OF CHEMISTRY PRINCETON NEW JERSEY

    Office of Legacy Management (LM)

    PRINCETON UNIVERSITY DEPARTMENT OF CHEMISTRY PRINCETON NEW JERSEY ry'ovPn'c?r 11, 1947 Yr. ... otiinr thR2 uraniw. -&7f+v+--- N. H. Furmn, ProfeeGor of Chemistry, Frlncetor;, M. 3. -

  7. March 2016 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    Chemistry LITERATURE REVIEW OF BORIC ACID SOLUBILITY DATA Crapse, K.; Kyser, E. (2011) 342 ... Yang, Shiyong; Stock, L.M. (1996) 86 Background chemistry for chemical warfare agents and ...

  8. Condensed matter physics and chemistry

    SciTech Connect (OSTI)

    Nellis, W.J.

    1995-10-01

    The proposed Los Alamos Neutron Science Center (LANSCE) upgrade is ideally suited for science-based stockpile stewardship (SBSS) because LANSCE is a highly-intensity pulsed neutron source located at a nuclear weapons design laboratory. The attributes of a high-intensity pulsed source are essential for performing experiments on Pu and other materials important for SBSS. Neutrons can accurately probe thick bulk specimens, probe thin layers both freestanding and embedded in thicker specimens, and provide time-resolution for some phenomena. Both ordered structures and disorder in solids, liquids, and amorphous materials can be characterized, as well as phase transition. Because LANSCE is at a nuclear design laboratory, specimens important for SBSS issues are available. Los Alamos National Laboratory is an appropriate place to develop the requisite hardware to accommodate SBSS specimens, such as Pu.

  9. Zelenay receives professorship in chemistry from president of Poland

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zelenay receives professorship in chemistry from president of Poland Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay of Materials Synthesis and Integrated Devices (MPA-11) received the honorary title of Professor in Chemistry from Poland's President Bronisław Komorowski during a June 23 ceremony at the Presidential Palace in Warsaw. October 8, 2015 Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay, right, shakes hands with

  10. June 26 Training: Using Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 26 Training: Using Chemistry and Material Sciences Applications June 26 Training: Using Chemistry and Material Sciences Applications June 15, 2012 by Francesca Verdier NERSC will present a three-hour training class focussed on Chemistry and Material Sciences applications on Tuesday, June 26, from 9:00 to 12:00 Pacific Time. The first hour of the training is targeted at beginners. We will show you how to get started running material science and chemistry application codes at NERSC. We will

  11. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    of Engineering and Applied Sciences, Harvard University Hammel, Chris (Chris Hammel) - ... - Departments of Chemistry & Physics, Harvard University Hellman, Frances (Frances ...

  12. Critical review of mercury chemistry in flue gas.

    SciTech Connect (OSTI)

    Mendelsohn, M. H.; Livengood, C. D.

    2006-11-27

    Mercury (Hg) and its compounds have long been recognized as potentially hazardous to human health and the environment. Many man-made sources of mercury have been reduced in recent years through process changes and control measures. However, emissions of mercury from coal-fired power plants, while exceedingly dilute by the usual pollution standards, still constitute a major source when considered in the aggregate. Concerns over those emissions and the prospect of impending emissions regulations have led to a wide range of research projects dealing with the measurement and control of mercury in flue gas. This work has made considerable progress in improving the understanding of mercury emissions and their behavior, but inconsistencies and unexpected results have also shown that a better understanding of mercury chemistry is needed. To develop a more complete understanding of where additional research on mercury chemistry is needed, the U.S. Department of Energy (DOE) asked Argonne National Laboratory (Argonne) to conduct a critical review of the available information as reported in the technical literature. The objectives were to summarize the current state of the art of chemistry knowledge, identify significant knowledge gaps, and recommend future research to resolve those gaps. An initial evaluation of potential review topics indicated that the scope of the review would need to be limited and focused on the most important topics relative to mercury control. To aid in this process, Argonne developed a brief survey that was circulated to researchers in the field who could help identify and prioritize the many aspects of the problem. The results of the survey were then used to design and guide a highly focused literature search that identified key papers for analysis. Each paper was reviewed, summarized, and evaluated for the relevance and quality of the information presented. The results of that work provided the basis for conclusions regarding the state of knowledge

  13. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    G. A. Farthing; G. T. Amrhein; G. A. Kudlac; D. A. Yurchison; D. K. McDonald; M. G. Milobowski

    2001-03-31

    The primary objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (HAPs, or air toxics) from coal-fired boilers. This objective is being met by identifying ways to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESPs), fabric filters (fabric filters), and wet flue gas desulfurization (wet FGD) systems. Development work initially concentrated on the capture of trace metals, hydrogen chloride, and hydrogen fluoride. Recent work has focused almost exclusively on the control of mercury emissions.

  14. MULTI-POLLUTANT CONTROL USING MEMBRANE--BASED UP-FLOW WET ELECTROSTATIC PRECIPITATION

    SciTech Connect (OSTI)

    James Reynolds

    2003-04-30

    This is the second quarterly report of the ''Multi-Pollutant Control Using Membrane-Based Upflow Wet Electrostatic Precipitation'' project funded by the US Department of Energy's National Energy Technology Laboratory under DOE Award No. DE-FC26-02NT41592 to Croll-Reynolds Clean Air Technologies (CRCAT). In this 18 month project, CRCAT and its team members will conduct detailed emission tests of metallic and new membrane collection material within a wet electrostatic precipitator (WESP) at First Energy's Penn Power's Bruce Mansfield (BMP) plant in Shippingport, Pa. Test results performed on the existing metallic WESP during November of 2002 showed consistent results with previous test results. Average collection efficiency of 89% on SO{sub 3} mist was achieved. Additionally, removal efficiencies of 62% were achieved at very high velocity, greater than 15 ft./sec. During the first quarter of 2003 final design and start of fabrication of the membrane wet ESP was undertaken.

  15. Vehicle exhaust treatment using electrical discharge and materials chemistry

    SciTech Connect (OSTI)

    Tonkyn, R.G.; Balmer, M.L.; Barlow, S.E.; Orlando, T.M.; Goulette, D.; Hoard, J.

    1997-12-31

    Current 3-way catalytic converters have proven quite effective at removing NO{sub x} from the exhaust of spark ignition vehicles operating near stoichiometric air-to-fuel ratios. However, diesel engines typically operate at very high air-to-fuel ratios. Under such lean burn conditions current catalytic converters are ineffective for NO{sub x} removal. As a result, considerable effort has been made to develop a viable lean NO{sub x} catalyst. Although some materials have been shown to reduce NO{sub x} under lean burn conditions, none exhibit the necessary activity and stability at the high temperatures and humidities found in typical engine exhaust,. As a result, alternative technologies are being explored in an effort to solve the so-called lean NO{sub x} problem. Packed-bed barrier discharge systems are well suited to take advantage of plasma-surface interactions due to the large number of contaminant surface collisions in the bed. The close proximity of the active surface to transient species produced by the plasma may lead to favorable chemistry at considerably lower temperatures than required by thermal catalysts. The authors present data in this paper illustrating that the identity and surface properties of the packing material can alter the discharge-driven chemistry in synthetic leanburn exhaust mixtures. Results using non-porous glass beads as the packing material suggest the limits of NO{sub x} reduction using purely gas phase discharge chemistry. By comparison, encouraging results are reported for several alternative packing materials.

  16. California State Offshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 226 1980's 160 244 232 221 206 1990's 188 55 59 63 59 56 47 54 39 58 2000's 86 80 85 76 85 89 85 79 54 53 2010's 63 79 65 75 76 - = No Data

  17. Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 167 1980's 185 139 112 132 110 115 132 115 103 101 1990's 114 115 94 93 75 67 82 51 60 52 2000's 40 105 66 85 80 83 82 83 85 83 2010's 79 127 326 433 657 - = No Data Reported;

  18. Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 209 1980's 172 180 216 175 170 260 241 205 204 251 1990's 333 401 361 191 151 248 446 68 51 67 2000's 69 43 47 48 45 57 61 72 60 67 2010's 267

  19. Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 0 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 484 1980's 546 456 489 537 617 560 537 482 424 364 1990's 311 298 396 264 264 254 253 227 234 241 2000's 289 255 271 252 249 253 316 436

  20. Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 955 1980's 921 806 780 747 661 570 517 512 428 430 1990's 407 352 308 288 299 245 252 235 204 202 2000's 115 65 70 81