National Library of Energy BETA

Sample records for development wet chemistry

  1. Categorical Exclusion 4497: Lithium Wet Chemistry Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Categorical Exclusion Detennination Form Proposed Action Tills: Lithium W@t Chemistry Project (4597) Program or Fild Oftke: Y-12 Site Office L&cationfs)...

  2. Development of a Wet Logistics System for Bulk Corn Stover

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Wet Logistics System for Bulk Corn Stover March 25, 2015 Lynn M. Wendt, William A. Smith, Austin Murphy, and Ian J. Bonner Idaho National Laboratory This presentation does not ...

  3. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Print Chemical science at the ALS encompasses a broad range of approaches and specializations, including surfaces/interfaces, catalysis, chemical dynamics (gas-phase chemistry), crystallography, and physical chemistry. By one estimate, nearly 80% of all chemical reactions in nature and in human technology take place at boundaries between phases, i.e., at surfaces or interfaces. Atomic- and molecular-scale studies are needed to develop a thorough understanding of the relationships

  4. Analysis Of Post-Wet-Chemistry Heat Treatment Effects On Nb SRF Surface Resistance

    SciTech Connect (OSTI)

    Dhakal, Pashupati; Ciovati, Gianluigi; Kneisel, Peter K.; Myneni, Ganapati Rao

    2014-02-01

    Most of the current research in superconducting radio frequency (SRF) cavities is focused on ways to reduce the construction and operating cost of SRF-based accelerators as well as on the development of new or improved cavity processing techniques. The increase in quality factors is the result of the reduction of the surface resistance of the materials. A recent test on a 1.5 GHz single cell cavity made from ingot niobium of medium purity and heat treated at 1400 deg C in a ultra-high vacuum induction furnace resulted in a residual resistance of ~ 1n{Omega} and a quality factor at 2.0 K increasing with field up to ~ 5×10{sup 10} at a peak magnetic field of 90 mT. In this contribution, we present some results on the investigation of the origin of the extended Q{sub 0}-increase, obtained by multiple HF rinses, oxypolishing and heat treatment of “all Nb” cavities.

  5. Development of a two-body wet abrasion test method with attention to the

    Office of Scientific and Technical Information (OSTI)

    effects of reused abradant (Conference) | SciTech Connect Conference: Development of a two-body wet abrasion test method with attention to the effects of reused abradant Citation Details In-Document Search Title: Development of a two-body wet abrasion test method with attention to the effects of reused abradant Abrasive wear is among the most common and costliest causes for material wastage, and it occurs in many forms. A simple method has been developed to quantify the response of metals

  6. Scalable Computational Chemistry: New Developments and Applications

    SciTech Connect (OSTI)

    Yuri Alexeev

    2002-12-31

    The computational part of the thesis is the investigation of titanium chloride (II) as a potential catalyst for the bis-silylation reaction of ethylene with hexaclorodisilane at different levels of theory. Bis-silylation is an important reaction for producing bis(silyl) compounds and new C-Si bonds, which can serve as monomers for silicon containing polymers and silicon carbides. Ab initio calculations on the steps involved in a proposed mechanism are presented. This choice of reactants allows them to study this reaction at reliable levels of theory without compromising accuracy. The calculations indicate that this is a highly exothermic barrierless reaction. The TiCl{sub 2} catalyst removes a 50 kcal/mol activation energy barrier required for the reaction without the catalyst. The first step is interaction of TiCl{sub 2} with ethylene to form an intermediate that is 60 kcal/mol below the energy of the reactants. This is the driving force for the entire reaction. Dynamic correlation plays a significant role because RHF calculations indicate that the net barrier for the catalyzed reaction is 50 kcal/mol. They conclude that divalent Ti has the potential to become an important industrial catalyst for silylation reactions. In the programming part of the thesis, parallelization of different quantum chemistry methods is presented. The parallelization of code is becoming important aspects of quantum chemistry code development. Two trends contribute to it: the overall desire to study large chemical systems and the desire to employ highly correlated methods which are usually computationally and memory expensive. In the presented distributed data algorithms computation is parallelized and the largest arrays are evenly distributed among CPUs. First, the parallelization of the Hartree-Fock self-consistent field (SCF) method is considered. SCF method is the most common starting point for more accurate calculations. The Fock build (sub step of SCF) from AO integrals is also often used to avoid MO integral computation. The presented distributed data SCF increases the size of chemical systems that can be calculated by using RHF and DFT. The important ab initio method to study bond formation and breaking as well as excited molecules is CASSCF. The presented distributed data CASSCF algorithm can significantly decrease computational time and memory requirements per node. Therefore, large CASSCF computations can be performed. The most time consuming operation to study potential energy surfaces of reactions and chemical systems is Hessian calculations. The distributed data parallelization of CPHF will alloy scientists carry out large analytic Hessian calculations.

  7. Rye Patch geothermal development, hydro-chemistry of thermal...

    Open Energy Info (EERE)

    Patch geothermal development, hydro-chemistry of thermal water applied to resource definition Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Rye Patch...

  8. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Chemistry Top Journals Journal of the American Chemical Society Angewandte Chemie & Angewandte Chemie, international edition in English Chemical Communications Chemical...

  9. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Chemical science for a dynamic world Jonathan Ward Engle, is among 49 winners, of the US Department of Energy's Early Career Research Program awards for 2016. Physicist wins early-career award for isotope work READ MORE 3D printer is ideal tool to make cones of explosive material with finely controlled internal microstructure Explosiv3Design READ MORE Isotopes for cancer and cardiac care Isotopes for cancer and cardiac care READ MORE Contact Us Division Leader David Morris

  10. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysts play a central role in processes relevant to energy, the environment, and biology. Researchers are working to develop cheaper and smarter catalysts that are fine tuned...

  11. Development of a Stiffness-Based Chemistry Load Balancing Scheme...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of a Stiffness-Based Chemistry Load Balancing Scheme, and Optimization of IO and Communication, to Enable Massively Parallel High-Fidelity Internal Combustion Engine Simulations...

  12. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect (OSTI)

    Newkirk, L.

    1997-12-01

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  13. Chemistry {ampersand} Materials Science program report, Weapons Resarch and Development and Laboratory Directed Research and Development FY96

    SciTech Connect (OSTI)

    Chase, L.

    1997-03-01

    This report is the annual progress report for the Chemistry Materials Science Program: Weapons Research and Development and Laboratory Directed Research and Development. Twenty-one projects are described separately by their principal investigators.

  14. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 1, Executive summary

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    About 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the solids for compaction in a landfill also consumes fly ash that otherwise may be marketable. This Executive Summary describes efforts to dewater the magnesium hydroxide and gypsum slurries and then process the solids into a more user friendly and higher value form. To eliminate the cost of solids disposal in its first generation Thiosorbic® system, the Dravo Lime Company developed the ThioClear® process that utilizes a magnesium based absorber liquor to remove S02 with minimal suspended solids. Magnesium enhanced lime is added to an oxidized bleed stream of thickener overflow (TOF) to produce magnesium hydroxide [Mg(OH)2] and gypsum (CaS04 • 2H20), as by-products. This process was demonstrated at the 3 to 5 MW closed loop FGD system pilot plant at the Miami Fort Station of Cinergy, near Cincinnati, Ohio with the help of OCDO Grant Agreement CDO/D-91-6. A similar process strictly for'recovery and reuse of Mg(OH)2 began operation at the Zimmer Station of Cinergy in late 1994 that can produce 900 pounds of Mg(OH)2 per hour and 2,600 pounds of gypsum per hour. This by-product plant, called the Zimmer Slipstream Magnesium Hydroxide Recovery Project Demonstration, was conducted with the help of OCDO Grant Agreement CDO/D-921-004. Full scale ThioClear® plants began operating in 1997 at the 130 MW Applied Energy Services plant, in Monaca, PA, and in year 2000 at the 1,330 MW Allegheny Energy Pleasants Station at St. Marys, WV.

  15. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

    2004-07-01

    Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

  16. Wetting of a Chemically Heterogeneous Surface

    SciTech Connect (OSTI)

    Frink, L.J.D.; Salinger, A.G.

    1998-11-20

    Theories for inhomogeneous fluids have focused in recent years on wetting, capillary conden- sation, and solvation forces for model systems where the surface(s) is(are) smooth homogeneous parallel plates, cylinders, or spherical drops. Unfortunately natural systems are more likely to be hetaogeneous both in surt%ce shape and surface chemistry. In this paper we discuss the conse- quences of chemical heterogeneity on wetting. Specifically, a 2-dimensional implementation of a nonlocal density functional theory is solved for a striped surface model. Both the strength and range of the heterogeneity are varied. Contact angles are calculated, and phase transitions (both the wetting transition and a local layering transition) are located. The wetting properties of the surface ase shown to be strongly dependent on the nature of the surface heterogeneity. In addition highly ordered nanoscopic phases are found, and the operational limits for formation of ordered or crystalline phases of nanoscopic extent are discussed.

  17. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 3, Product development of gypsum, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in Figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compunction in a landfill also consumes fly ash that otherwise may be marketable.

  18. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 2, Product development of magnesium hydroxide, Phase 1

    SciTech Connect (OSTI)

    Smith, Kevin; Beeghly, Joel H.

    2000-11-30

    In the way of background information about 30 electric utility units with a combined total of 15,000 MW utilize magnesium enhanced lime flue gas desulfurization (FGD) systems. The first generation process begun in 1973, called the Thiosorbic® Process, was a technical breakthrough that offered significantly improved operating and performance characteristics compared with competing FGD technologies. The process is described as Flow Diagram "A" in figure 1. A disadvantage of this and other inhibited or natural oxidation wet FGD systems is the capital and operating cost associated with landfill disposal of the calcium sulfite based solids. Fixation to stabilize the sludge solids for compaction in a landfill also consumes fly ash that otherwise may be marketable.

  19. Physics and Chemistry of Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Physics and Chemistry of Materials Developing new science and technologies needed for ... Fundamental and applied theoretical research on the physics and chemistry of materials The ...

  20. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide Chemistry Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise David Gallimore Actinide Analytical Chemistry Email Rebecca Chamberlin Actinide Analytical Chemistry Email Josh Smith Chemistry Communications Email Along with the lanthanides, they are often called "the f-elements" because they have valence electrons in the f shell. Actinide chemistry serves a

  1. Reactant ion chemistry for detection of TNT, RDX, and PETN using an ion mobility spectrometer

    SciTech Connect (OSTI)

    Klassen, S.E.; Rodacy, P.; Silva, R.

    1997-09-01

    This report describes the responses of three energetic materials (TNT, RDX, and PETN) to varying reactant ion chemistries and IMS cell temperatures. The following reactant ion chemistries were evaluated; air-dry; air-wet; methylene chloride-dry; methylene chloride-wet; methylene bromide-dry; nitrogen dioxide-wet; sulfur dioxide-wet. The temperature was varied between 160 - 220{degrees}C.

  2. Atmospheric Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    competencies Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced...

  3. A Component Approach to Collaborative Scientific Software Development: Tools and Techniques Utilized by the Quantum Chemistry Science Application Partnership

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kenny, Joseph P.; Janssen, Curtis L.; Gordon, Mark S.; Sosonkina, Masha; Windus, Theresa L.

    2008-01-01

    Cutting-edge scientific computing software is complex, increasingly involving the coupling of multiple packages to combine advanced algorithms or simulations at multiple physical scales. Component-based software engineering (CBSE) has been advanced as a technique for managing this complexity, and complex component applications have been created in the quantum chemistry domain, as well as several other simulation areas, using the component model advocated by the Common Component Architecture (CCA) Forum. While programming models do indeed enable sound software engineering practices, the selection of programming model is just one building block in a comprehensive approach to large-scale collaborative development which must also addressmore » interface and data standardization, and language and package interoperability. We provide an overview of the development approach utilized within the Quantum Chemistry Science Application Partnership, identifying design challenges, describing the techniques which we have adopted to address these challenges and highlighting the advantages which the CCA approach offers for collaborative development.« less

  4. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, L.C.; Simpson, M.L.

    1995-01-17

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

  5. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, Lonnie C.; Simpson, Marc L.

    1995-01-01

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

  6. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  7. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide chemistry serves a critical role in addressing global threats Project Description At Los Alamos, scientists are using actinide analytical chemistry to identify and quantify the chemical and isotopic composition of materials. Since the Manhattan Project, such work has supported the Laboratory's mission. Today, actinide analytical chemistry plays a critical role in ensuring the national security of the United States through nuclear science and technology. The scope of

  8. Does surface roughness amplify wetting?

    SciTech Connect (OSTI)

    Malijevský, Alexandr

    2014-11-14

    Any solid surface is intrinsically rough on the microscopic scale. In this paper, we study the effect of this roughness on the wetting properties of hydrophilic substrates. Macroscopic arguments, such as those leading to the well-known Wenzel's law, predict that surface roughness should amplify the wetting properties of such adsorbents. We use a fundamental measure density functional theory to demonstrate the opposite effect from roughness for microscopically corrugated surfaces, i.e., wetting is hindered. Based on three independent analyses we show that microscopic surface corrugation increases the wetting temperature or even makes the surface hydrophobic. Since for macroscopically corrugated surfaces the solid texture does indeed amplify wetting there must exist a crossover between two length-scale regimes that are distinguished by opposite response on surface roughening. This demonstrates how deceptive can be efforts to extend the thermodynamical laws beyond their macroscopic territory.

  9. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  10. Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Applications Gaussian 09 Gaussian 09 is a connected series of programs for performing semi-empirical, density functional theory and ab initio molecular orbital calculations. Read More » GAMESS GAMESS (General Atomic and Molecular Electronic Structure System) is a general ab initio quantum chemistry package. Read More » AMBER AMBER (Assisted Model Building with Energy Refinement) is the collective name for a suite of programs designed to carry out molecular dynamics

  11. Hydrothermal Processing of Wet Wastes

    Broader source: Energy.gov [DOE]

    Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

  12. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  13. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department`s moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  14. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  15. Aerosol transport and wet scavenging in deep convective clouds: a case study and model evaluation using a multiple passive tracer analysis approach

    SciTech Connect (OSTI)

    Yang, Qing; Easter, Richard C.; Campuzano-Jost, Pedro; Jimenez, Jose L.; Fast, Jerome D.; Ghan, Steven J.; Wang, Hailong; Berg, Larry K.; Barth, Mary; Liu, Ying; Shrivastava, ManishKumar B.; Singh, Balwinder; Morrison, H.; Fan, Jiwen; Ziegler, Conrad L.; Bela, Megan; Apel, Eric; Diskin, G. S.; Mikoviny, Tomas; Wisthaler, Armin

    2015-08-20

    The effect of wet scavenging on ambient aerosols in deep, continental convective clouds in the mid-latitudes is studied for a severe storm case in Oklahoma during the Deep Convective Clouds and Chemistry (DC3) field campaign. A new passive-tracer based transport analysis framework is developed to characterize the convective transport based on the vertical distribution of several slowly reacting and nearly insoluble trace gases. The passive gas concentration in the upper troposphere convective outflow results from a mixture of 47% from the lower level (0-3 km), 21% entrained from the upper troposphere, and 32% from mid-atmosphere based on observations. The transport analysis framework is applied to aerosols to estimate aerosol transport and wet-scavenging efficiency. Observations yield high overall scavenging efficiencies of 81% and 68% for aerosol mass (Dp < 1μm) and aerosol number (0.03< Dp < 2.5μm), respectively. Little chemical selectivity to wet scavenging is seen among observed submicron sulfate (84%), organic (82%), and ammonium (80%) aerosols, while nitrate has a much lower scavenging efficiency of 57% likely due to the uptake of nitric acid. Observed larger size particles (0.15 - 2.5μm) are scavenged more efficiently (84%) than smaller particles (64%; 0.03 - 0.15μm). The storm is simulated using the chemistry version of the WRF model. Compared to the observation based analysis, the standard model underestimates the wet scavenging efficiency for both mass and number concentrations with low biases of 31% and 40%, respectively. Adding a new treatment of secondary activation significantly improves simulation results, so that the bias in scavenging efficiency in mass and number concentrations is reduced to <10%. This supports the hypothesis that secondary activation is an important process for wet removal of aerosols in deep convective storms.

  16. Chemistry and materials science progress report. Weapons-supporting research and laboratory directed research and development: FY 1995

    SciTech Connect (OSTI)

    NONE

    1996-04-01

    This report covers different materials and chemistry research projects carried out a Lawrence Livermore National Laboratory during 1995 in support of nuclear weapons programs and other programs. There are 16 papers supporting weapons research and 12 papers supporting laboratory directed research.

  17. Department of Chemistry | Center for Catalytic HydrocarbonFunctionali...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    expertise in catalysis, electrochemistry, bioinorganic chemistry, materials chemistry and quantum mechanics. To enable fundamental advancements in the design and development of...

  18. Competitive Wetting in Active Brazes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chandross, Michael Evan

    2014-05-01

    We found that the wetting and spreading of molten filler materials (pure Al, pure Ag, and AgAl alloys) on a Kovar ™ (001) substrate was studied with molecular dynamics simulations. A suite of different simulations was used to understand the effects on spreading rates due to alloying as well as reactions with the substrate. Moreover, the important conclusion is that the presence of Al in the alloy enhances the spreading of Ag, while the Ag inhibits the spreading of Al.

  19. he Impact of Primary Marine Aerosol on Atmospheric Chemistry, Radiation and Climate: A CCSM Model Development Study

    SciTech Connect (OSTI)

    Keene, William C.; Long, Michael S.

    2013-05-20

    This project examined the potential large-scale influence of marine aerosol cycling on atmospheric chemistry, physics and radiative transfer. Measurements indicate that the size-dependent generation of marine aerosols by wind waves at the ocean surface and the subsequent production and cycling of halogen-radicals are important but poorly constrained processes that influence climate regionally and globally. A reliable capacity to examine the role of marine aerosol in the global-scale atmospheric system requires that the important size-resolved chemical processes be treated explicitly. But the treatment of multiphase chemistry across the breadth of chemical scenarios encountered throughout the atmosphere is sensitive to the initial conditions and the precision of the solution method. This study examined this sensitivity, constrained it using high-resolution laboratory and field measurements, and deployed it in a coupled chemical-microphysical 3-D atmosphere model. First, laboratory measurements of fresh, unreacted marine aerosol were used to formulate a sea-state based marine aerosol source parameterization that captured the initial organic, inorganic, and physical conditions of the aerosol population. Second, a multiphase chemical mechanism, solved using the Max Planck Institute for Chemistry??s MECCA (Module Efficiently Calculating the Chemistry of the Atmosphere) system, was benchmarked across a broad set of observed chemical and physical conditions in the marine atmosphere. Using these results, the mechanism was systematically reduced to maximize computational speed. Finally, the mechanism was coupled to the 3-mode modal aerosol version of the NCAR Community Atmosphere Model (CAM v3.6.33). Decadal-scale simulations with CAM v.3.6.33, were run both with and without reactive-halogen chemistry and with and without explicit treatment of particulate organic carbon in the marine aerosol source function. Simulated results were interpreted (1) to evaluate influences of marine aerosol production on the microphysical properties of aerosol populations and clouds over the ocean and the corresponding direct and indirect effects on radiative transfer; (2) atmospheric burdens of reactive halogen species and their impacts on O3, NOx, OH, DMS, and particulate non-sea-salt SO42-; and (3) the global production and influences of marine-derived particulate organic carbon. The model reproduced major characteristics of the marine aerosol system and demonstrated the potential sensitivity of global, decadal-scale climate metrics to multiphase marine-derived components of Earth??s troposphere. Due to the combined computational burden of the coupled system, the currently available computational resources were the limiting factor preventing the adequate statistical analysis of the overall impact that multiphase chemistry might have on climate-scale radiative transfer and climate.

  20. Chemistry-nuclear chemistry division. Progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1981-05-01

    This report presents the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, element migration and fixation, inorganic chemistry, isotope separation and analysis, atomic and molecular collisions, molecular spectroscopy, muonic x rays, nuclear cosmochemistry, nuclear structure and reactions, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  1. Flame Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  2. Materials Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  3. Combustion Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  4. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  5. Analytical Chemistry Laboratory Progress Report for FY 1994

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1994-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1994 (October 1993 through September 1994). This annual report is the eleventh for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has a research program in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. The ACL has four technical groups -- Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis -- which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL. The Chemical Analysis Group uses wet- chemical and instrumental methods for elemental, compositional, and isotopic determinations in solid, liquid, and gaseous samples and provides specialized analytical services. Major instruments in this group include an ion chromatograph (IC), an inductively coupled plasma/atomic emission spectrometer (ICP/AES), spectrophotometers, mass spectrometers (including gas-analysis and thermal-ionization mass spectrometers), emission spectrographs, autotitrators, sulfur and carbon determinators, and a kinetic phosphorescence uranium analyzer.

  6. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Office of Scientific and Technical Information (OSTI)

    George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information * Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations

  7. Carbon nanotube fiber spun from wetted ribbon

    DOE Patents [OSTI]

    Zhu, Yuntian T; Arendt, Paul; Zhang, Xiefei; Li, Qingwen; Fu, Lei; Zheng, Lianxi

    2014-04-29

    A fiber of carbon nanotubes was prepared by a wet-spinning method involving drawing carbon nanotubes away from a substantially aligned, supported array of carbon nanotubes to form a ribbon, wetting the ribbon with a liquid, and spinning a fiber from the wetted ribbon. The liquid can be a polymer solution and after forming the fiber, the polymer can be cured. The resulting fiber has a higher tensile strength and higher conductivity compared to dry-spun fibers and to wet-spun fibers prepared by other methods.

  8. ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    , . - - ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1 DE89 009559 W. D. Shults Analytical Chemistry Division Oak Ridge National Laboratory* Oak Ridge, Tennessee 37831-6129 ABSTRACT Over the past forty years, analytical scientists within the DOE complex have had a tremendous impact on the field of analytical chemistry. This paper suggests six "high impact" research/development areas that either originated within or wcce

  9. Predictive modeling of reactive wetting and metal joining.

    SciTech Connect (OSTI)

    van Swol, Frank B.

    2013-09-01

    The performance, reproducibility and reliability of metal joints are complex functions of the detailed history of physical processes involved in their creation. Prediction and control of these processes constitutes an intrinsically challenging multi-physics problem involving heating and melting a metal alloy and reactive wetting. Understanding this process requires coupling strong molecularscale chemistry at the interface with microscopic (diffusion) and macroscopic mass transport (flow) inside the liquid followed by subsequent cooling and solidification of the new metal mixture. The final joint displays compositional heterogeneity and its resulting microstructure largely determines the success or failure of the entire component. At present there exists no computational tool at Sandia that can predict the formation and success of a braze joint, as current capabilities lack the ability to capture surface/interface reactions and their effect on interface properties. This situation precludes us from implementing a proactive strategy to deal with joining problems. Here, we describe what is needed to arrive at a predictive modeling and simulation capability for multicomponent metals with complicated phase diagrams for melting and solidification, incorporating dissolutive and composition-dependent wetting.

  10. National Ignition Facility wet weather construction plan

    SciTech Connect (OSTI)

    Kugler, A N

    1998-01-01

    This report presents a wet weather construction plan for the National Ignition Facility (NIF) construction project. Construction of the NIF commenced in mid- 1997, and excavation of the site was completed in the fall. Preparations for placing concrete foundations began in the fall, and above normal rainfall is expected over the tinter. Heavy rainfall in late November impacted foundation construction, and a wet weather construction plan was determined to be needed. This wet weather constiction plan recommends a strategy, techniques and management practices to prepare and protect the site corn wet weather effects and allow construction work to proceed. It is intended that information in this plan be incorporated in the Stormwater Pollution Prevention Plan (SWPPP) as warranted.

  11. Reducing the atmospheric impact of wet slaking

    SciTech Connect (OSTI)

    B.D. Zubitskii; G.V. Ushakov; B.G. Tryasunov; A.G.Ushakov

    2009-05-15

    Means of reducing the atmospheric emissions due to the wet slaking of coke are considered. One option, investigated here, is to remove residual active silt and organic compounds from the biologically purified wastewater sent for slaking, by coagulation and flocculation.

  12. Wet/dry cooling tower and method

    DOE Patents [OSTI]

    Glicksman, Leon R.; Rohsenow, Warren R.

    1981-01-01

    A wet/dry cooling tower wherein a liquid to-be-cooled is flowed along channels of a corrugated open surface or the like, which surface is swept by cooling air. The amount of the surface covered by the liquid is kept small compared to the dry part thereof so that said dry part acts as a fin for the wet part for heat dissipation.

  13. ,"West Virginia Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","West Virginia Nonassociated Natural Gas, Wet After ... PM" "Back to Contents","Data 1: West Virginia Nonassociated Natural Gas, Wet After ...

  14. ,"West Virginia Natural Gas, Wet After Lease Separation Proved...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","West Virginia Natural Gas, Wet After Lease Separation ... PM" "Back to Contents","Data 1: West Virginia Natural Gas, Wet After Lease Separation ...

  15. ,"West Virginia Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","West Virginia Associated-Dissolved Natural Gas, Wet ... PM" "Back to Contents","Data 1: West Virginia Associated-Dissolved Natural Gas, Wet ...

  16. ,"Virginia Nonassociated Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Virginia Nonassociated Natural Gas, Wet After ... 12:22:14 PM" "Back to Contents","Data 1: Virginia Nonassociated Natural Gas, Wet After ...

  17. Texas State Offshore Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  18. Texas State Offshore Associated-Dissolved Natural Gas, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves...

  19. Texas State Offshore Nonassociated Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic...

  20. Texas Natural Gas, Wet After Lease Separation Proved Reserves...

    Gasoline and Diesel Fuel Update (EIA)

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas Natural Gas, ... Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 Texas Natural Gas ...

  1. Texas Associated-Dissolved Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Texas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves ... Wet After Lease Separation, as of Dec. 31 Texas Associated-Dissolved Natural Gas Proved ...

  2. Texas Nonassociated Natural Gas, Wet After Lease Separation,...

    Gasoline and Diesel Fuel Update (EIA)

    Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion ... Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 Texas ...

  3. MHK Technologies/WET NZ | Open Energy Information

    Open Energy Info (EERE)

    to the MHK database homepage WET NZ.jpg Technology Profile Primary Organization Wave Energy Technology New Zealand WET NZ Technology Resource Click here Wave Technology...

  4. Texas - RRC District 1 Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  5. Texas - RRC District 6 Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  6. Texas - RRC District 5 Natural Gas, Wet After Lease Separation...

    Gasoline and Diesel Fuel Update (EIA)

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  7. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    SciTech Connect (OSTI)

    Ryan, R.R.

    1982-05-01

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  8. DOE fundamentals handbook: Chemistry. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  9. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Mechanistic Chemistry Security at center of chemical and mechanistic chemistry research at Lab Project Description Los Alamos scientists are using synthetic and mechanistic chemistry to address energy security and other emerging challenges, including global security and core weapons missions. Synthetic chemistry includes work in ligands for catalysts, fission-products separations for isotope delivery, and labeled substrates for reaction mechanisms. Other research addresses materials

  10. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Chemistry Synthetic and mechanistic chemical sciences play an important role in Lab missions dedicated to energy security, emerging challenges, global security, and core weapons missions. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this

  11. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, Louis G.

    1982-01-01

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  12. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, L.G.

    1979-08-29

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  13. Controllable underwater anisotropic oil-wetting

    SciTech Connect (OSTI)

    Yong, Jiale; Chen, Feng Yang, Qing; Farooq, Umar; Bian, Hao; Du, Guangqing; Hou, Xun

    2014-08-18

    This Letter demonstrates a simple method to achieve underwater anisotropic oil-wetting using silicon surfaces with a microgroove array produced by femtosecond laser ablation. The oil contact angles along the direction perpendicular to the grooves are consistently larger than those parallel to the microgroove arrays in water because the oil droplet is restricted by the energy barrier that exists between the non-irradiated domain and the trapped water in the laser-ablated microgrooves. This underwater anisotropic oil-wetting is able to be controlled, and the anisotropy can be tuned from 0° to ∼20° by adjusting the period of the microgroove arrays.

  14. Coal combustion by wet oxidation. Wet oxidation of coal for energy production: test plan and partial results. Interim report

    SciTech Connect (OSTI)

    Bettinger, J.A.

    1980-07-10

    A test plan has been developed which will provide the data necessary to carry out design and economic studies of a steam generating facility, employing the wet oxidation of coal as a heat source. It is obvious, from the literature search and preliminary testing, that the higher the reaction temperature, the more complete the combustion of coal. However, operation at elevated temperatures and pressures present difficult design problems, and the necessary equipment is costly. Operation under these conditions can only be justified by the higher economic value of high pressure and temperature steam. With a reduction in temperature from 550/sup 0/F (228/sup 0/C) to 450/sup 0/F (232/sup 0/C), the operating pressure is reduced by more than half, thus holding down the overall cost of the system. For this reason, our plan is to study both the enhancement of low temperature wet oxidation of coal, and the higher operating regions. The coal selected for the first portion of this test is an Eastern Appalachian high-volatile-A Bituminous type, from the Upper Clarion seam in Pennsylvania. This coal was selected as being a typical high sulfur, eastern coal. The wet oxidation of coal to produce low pressure steam is a process suited for a high sulfur, low grade, coal. It is not intended that wet oxidation be used in all applications with all types of coals, as it does not appear to be competitive, economically, with conventional combustion, therefore the testing will focus on using high sulfur, low grade coals. In the later portion of testing all the available coals will be tested. In addition, a sample of Minnesota peat will be tested to determine if it also can be used in the process.

  15. WETTABILITY AND IMBIBITION: MICROSCOPIC DISTRIBUTION OF WETTING AND ITS CONSEQUENCES AT THE CORE AND FIELD SCALES

    SciTech Connect (OSTI)

    Jill S. Buckley; Norman R. Morrow; Chris Palmer; Purnendu K. Dasgupta

    2003-02-01

    The questions of reservoir wettability have been approached in this project from three directions. First, we have studied the properties of crude oils that contribute to wetting alteration in a reservoir. A database of more than 150 different crude oil samples has been established to facilitate examination of the relationships between crude oil chemical and physical properties and their influence on reservoir wetting. In the course of this work an improved SARA analysis technique was developed and major advances were made in understanding asphaltene stability including development of a thermodynamic Asphaltene Solubility Model (ASM) and empirical methods for predicting the onset of instability. The CO-Wet database is a resource that will be used to guide wettability research in the future. The second approach is to study crude oil/brine/rock interactions on smooth surfaces. Contact angle measurements were made under controlled conditions on mica surfaces that had been exposed to many of the oils in the CO-Wet database. With this wealth of data, statistical tests can now be used to examine the relationships between crude oil properties and the tendencies of those oils to alter wetting. Traditionally, contact angles have been used as the primary wetting assessment tool on smooth surfaces. A new technique has been developed using an atomic forces microscope that adds a new dimension to the ability to characterize oil-treated surfaces. Ultimately we aim to understand wetting in porous media, the focus of the third approach taken in this project. Using oils from the CO-Wet database, experimental advances have been made in scaling the rate of imbibition, a sensitive measure of core wetting. Application of the scaling group to mixed-wet systems has been demonstrated for a range of core conditions. Investigations of imbibition in gas/liquid systems provided the motivation for theoretical advances as well. As a result of this project we have many new tools for studying wetting at microscopic and macroscopic scales and a library of well-characterized fluids for use in studies of crude oil/brine/rock interactions.

  16. 1987 wet deposition temporal and spatial patterns in North America

    SciTech Connect (OSTI)

    Simpson, J.C.; Olsen, A.R.

    1990-03-01

    The focus of this report is on North American wet deposition temporal patterns from 1979 to 1987 and spatial patterns for 1987. The report investigates the patterns of annual precipitation-weighted average concentration and annual deposition for nine ion species: hydrogen, sulfate, nitrate, ammonium, calcium, chloride, sodium, potassium, and magnesium. Data are from the Acid Deposition System (ADS) for the statistical reporting of North American deposition data which includes the National Atmospheric Deposition Program/National Trends Network (NADP/NTN), the MAP3S precipitation chemistry network, the Utility Acid Precipitation Study Program (UAPSP), the Canadian Precipitation Monitoring Network (CAPMoN), and the daily and 4-weekly Acidic Precipitation in Ontario Study (APIOS-D and APIOS-C). Mosaic maps, based on surface estimation using kriging, display concentration and deposition spatial patterns of pH, hydrogen, sulfate, nitrate, ammonium, and calcium ion species for 1987 annual, winter, and summer periods. The temporal pattern analyses use a subset of 39 sites over a 9-year (1979--1987) period and an expanded subset of 140 sites with greater spatial coverage over a 6-year (1982--1987) period. 68 refs., 15 figs., 15 tabs.

  17. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Jurgen G. Schmidt: Synthetic chemistry and stable isotopes for biological applications ... for monitoring and detecting chemical warfare agents" Journal of Labelled Compounds and ...

  18. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Key Personnel * Jurgen G. Schmidt: Synthetic chemistry and stable isotopes for biological ... for monitoring and detecting chemical warfare agents" Journal of Labelled Compounds and ...

  19. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, andor more complex work activity than is allowed on the ALS...

  20. ,"Virginia Natural Gas, Wet After Lease Separation Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Virginia Natural Gas, Wet After Lease Separation ... 12:20:24 PM" "Back to Contents","Data 1: Virginia Natural Gas, Wet After Lease Separation ...

  1. ,"Virginia Associated-Dissolved Natural Gas, Wet After Lease...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Virginia Associated-Dissolved Natural Gas, Wet ... 12:24:05 PM" "Back to Contents","Data 1: Virginia Associated-Dissolved Natural Gas, Wet ...

  2. Indian Centre for Wind Energy Technology C WET | Open Energy...

    Open Energy Info (EERE)

    Centre for Wind Energy Technology C WET Jump to: navigation, search Name: Indian Centre for Wind Energy Technology (C-WET) Place: Chennai, India Zip: 601 302 Sector: Wind energy...

  3. Heat Transfer Characteristics of the Wet Thermal Insulator with Multi-layer

    SciTech Connect (OSTI)

    Jong-Won Kim; Goon-Cherl Park; Tae-Wan Kim; Doo-Jeong Lee

    2006-07-01

    SMART developed in KAERI is an integral type nuclear cogeneration reactor. SMART uses a nitrogen-filled gas pressurizer so that the steam partial pressure should be minimized and the pressurizer should be under low temperature condition. To sustain the low temperature condition, the wet thermal insulator and pressurizer cooler are installed in the pressurizer. Since the performance of wet thermal insulator is an important parameter to determine the size of the pressurizer cooler, it is important to evaluate the insulation performance of the wet thermal insulator. The wet thermal insulators with 20 layers are installed in SMART. In the design of SMART, the empirical correlation by Adamovich was used to estimate the thermal resistance of the wet thermal insulator. However, the experimental condition and results are not clear so that this correlation should be verified. To analyze the heat transfer characteristics of the multi-layer wet thermal insulator, natural convective heat transport through horizontal and vertical water-filled layers is investigated. Experiments and numerical analyses have been performed to evaluate the heat transfer rates through multi-layer and verify Adamovich correlation. In addition, a new multi-layer correlation was obtained. (authors)

  4. Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for

    Energy Savers [EERE]

    Tank 48H Treatment Project (TTP) | Department of Energy Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Wet Air Oxidation. PDF icon Technology Maturation Plan (TMP) Wet Air Oxidation (WAO)

  5. DOE fundamentals handbook: Chemistry. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  6. Seawater Chemistry Package

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    SeaChem Seawater Chemistry package provides routines to calculate pH, carbonate chemistry, density, and other quantities for seawater, based on the latest community standards. The chemistry is adapted from fortran routines provided by the OCMIP3/NOCES project, details of which are available at http://www.ipsl.jussieu.fr/OCMIP/. The SeaChem package can generate Fortran subroutines as well as Python wrappers for those routines. Thus the same code can be used by Python or Fortran analysis packages and Fortran ocean models alike.

  7. IN-PACKAGE CHEMISTRY ABSTRACTION

    SciTech Connect (OSTI)

    E. Thomas

    2005-07-14

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.

  8. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    To Gain Access to the ALS Chemistry Labs Complete the online course: EHS0348 Chemical Hygiene and Safety. Use the non-LDAP login and enter your badge number (if you have one) as...

  9. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A.

    1984-05-01

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  10. Selenium Speciation and Management in Wet FGD Systems

    SciTech Connect (OSTI)

    Searcy, K; Richardson, M; Blythe, G; Wallschlaeger, D; Chu, P; Dene, C

    2012-02-29

    This report discusses results from bench- and pilot-scale simulation tests conducted to determine the factors that impact selenium speciation and phase partitioning in wet FGD systems. The selenium chemistry in wet FGD systems is highly complex and not completely understood, thus extrapolation and scale-up of these results may be uncertain. Control of operating parameters and application of scrubber additives have successfully demonstrated the avoidance or decrease of selenite oxidation at the bench and pilot scale. Ongoing efforts to improve sample handling methods for selenium speciation measurements are also discussed. Bench-scale scrubber tests explored the impacts of oxidation air rate, trace metals, scrubber additives, and natural limestone on selenium speciation in synthetic and field-generated full-scale FGD liquors. The presence and concentration of redox-active chemical species as well as the oxidation air rate contribute to the oxidation-reduction potential (ORP) conditions in FGD scrubbers. Selenite oxidation to the undesirable selenate form increases with increasing ORP conditions, and decreases with decreasing ORP conditions. Solid-phase manganese [Mn(IV)] appeared to be the significant metal impacting the oxidation of selenite to selenate. Scrubber additives were tested for their ability to inhibit selenite oxidation. Although dibasic acid and other scrubber additives showed promise in early clear liquor (sodium based and without calcium solids) bench-scale tests, these additives did not show strong inhibition of selenite oxidation in tests with higher manganese concentrations and with slurries from full-scale wet FGD systems. In bench-tests with field liquors, addition of ferric chloride at a 250:1 iron-to-selenium mass ratio sorbed all incoming selenite to the solid phase, although addition of ferric salts had no impact on native selenate that already existed in the field slurry liquor sample. As ORP increases, selenite may oxidize to selenate more rapidly than it sorbs to ferric solids. Though it was not possible to demonstrate a decrease in selenium concentrations to levels below the project?¢????s target of 50 ???µg/L during pilot testing, some trends observed in bench-scale testing were evident at the pilot scale. Specifically, reducing oxidation air rate and ORP tends to either retain selenium as selenite in the liquor or shift selenium phase partitioning to the solid phase. Oxidation air flow rate control may be one option for managing selenium behavior in FGD scrubbers. Units that cycle load widely may find it more difficult to impact ORP conditions with oxidation air flow rate control alone. Because decreasing oxidation air rates to the reaction tank showed that all ?¢????new?¢??? selenium reported to the solids, the addition of ferric chloride to the pilot scrubber could not show further improvements in selenium behavior. Ferric chloride addition did shift mercury to the slurry solids, specifically to the fine particles. Several competing pathways may govern the reporting of selenium to the slurry solids: co-precipitation with gypsum into the bulk solids and sorption or co-precipitation with iron into the fine particles. Simultaneous measurement of selenium and mercury behavior suggests a holistic management strategy is best to optimize the fate of both of these elements in FGD waters. Work conducted under this project evaluated sample handling and analytical methods for selenium speciation in FGD waters. Three analytical techniques and several preservation methods were employed. Measurements of selenium speciation over time indicated that for accurate selenium speciation, it is best to conduct measurements on unpreserved, filtered samples as soon after sampling as possible. The capital and operating costs for two selenium management strategies were considered: ferric chloride addition and oxidation air flow rate control. For ferric chloride addition, as migh

  11. SC e-journals, Chemistry

    Office of Scientific and Technical Information (OSTI)

    Biogeochemistry Bioinorganic Chemistry and Applications - OAJ Biometals Biopolymers Bioresource Technology Bioscience Reports Biotechnology Advances Biotechnology ...

  12. Microbial Enhanced Oil Recovery in Fractional-Wet Systems: A Pore-Scale Investigation

    SciTech Connect (OSTI)

    Armstrong, Ryan T.; Wildenschild, Dorthe

    2012-10-24

    Microbial enhanced oil recovery (MEOR) is a technology that could potentially increase the tertiary recovery of oil from mature oil formations. However, the efficacy of this technology in fractional-wet systems is unknown, and the mechanisms involved in oil mobilization therefore need further investigation. Our MEOR strategy consists of the injection of ex situ produced metabolic byproducts produced by Bacillus mojavensis JF-2 (which lower interfacial tension (IFT) via biosurfactant production) into fractional-wet cores containing residual oil. Two different MEOR flooding solutions were tested; one solution contained both microbes and metabolic byproducts while the other contained only the metabolic byproducts. The columns were imaged with X-ray computed microtomography (CMT) after water flooding, and after MEOR, which allowed for the evaluation of the pore-scale processes taking place during MEOR. Results indicate that the larger residual oil blobs and residual oil held under relatively low capillary pressures were the main fractions recovered during MEOR. Residual oil saturation, interfacial curvatures, and oil blob sizes were measured from the CMT images and used to develop a conceptual model for MEOR in fractional-wet systems. Overall, results indicate that MEOR was effective at recovering oil from fractional-wet systems with reported additional oil recovered (AOR) values between 44 and 80%; the highest AOR values were observed in the most oil-wet system.

  13. Cavitation as a Mechanism to Enhance Wetting in a Mercury Thermal Convection Loop

    SciTech Connect (OSTI)

    Pawel, SJ

    2001-07-17

    Type 316L stainless steel was statically tested under cavitation conditions via an ultrasonic transducer externally mounted on a tube filled with ambient mercury. During the preliminary exposure (24 h, 20 kHz, 1.5 MPa), cavitation resulted in apparent wetting of the specimens by mercury as well as general surface roughening and wastage similar to erosion damage. Subsequently, a thermal convection loop identical to those used previously to study thermal gradient mass transfer was modified to include an externally-mounted donut-shaped transducer in order to similarly produce cavitation and wetting at temperatures prototypic of those expected in the SNS target. However, a series of attempts to develop cavitation and wetting on 316L specimens in the thermal convection loop was unsuccessful.

  14. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  15. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves from Greater than 200 Meters Deep (Percent) Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than...

  16. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Less than 200 Meters Deep (Billion Cubic...

  17. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production from Greater than 200 Meters Deep (Billion...

  18. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Less than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Less than 200 Meters Deep (Billion...

  19. Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Production from Greater than 200 Meters Deep (Percent) Gulf of Mexico Federal Offshore Percentage of Natural Gas, Wet After Lease Separation, Production from Greater than 200...

  20. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Greater than 200 Meters Deep (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves from Greater than 200 Meters Deep...

  1. Challenges and Opportunities for Wet-Waste Feedstocks - Resource...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications "Wet" Waste-to-Energy in the Bioenergy Technologies Office Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater ...

  2. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  3. W.E.T. Automotive Systems | Open Energy Information

    Open Energy Info (EERE)

    E.T. Automotive Systems Jump to: navigation, search Name: W.E.T. Automotive Systems Place: Odelzhausen, Germany Information About Partnership with NREL Partnership with NREL Yes...

  4. New Mexico Natural Gas Wet After Lease Separation, Reserves in...

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) New Mexico Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion...

  5. ,"New Mexico Nonassociated Natural Gas Proved Reserves, Wet After...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation",10,"Annual",201...

  6. Observation of Ordered Structures in Counterion Layers near Wet...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Observation of Ordered Structures in Counterion Layers near Wet Charged Surfaces: A Potential Mechanism for Charge Inversion ...

  7. Reaction chemistry of cerium

    SciTech Connect (OSTI)

    1997-01-01

    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  8. In-Package Chemistry Abstraction

    SciTech Connect (OSTI)

    E. Thomas

    2004-11-09

    This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been breached but the drip shield remains intact, so all of the seepage flow is diverted from the waste package. The chemistry from the vapor influx case is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion, and to determine the degradation rates for the waste forms. TSPA-LA uses the water influx case for the seismic scenario, where the waste package has been breached and the drip shield has been damaged such that seepage flow is actually directed into the waste package. The chemistry from the water influx case that is a function of the flow rate is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion and advection, and to determine the degradation rates for the CSNF and HLW glass. TSPA-LA does not use this model for the igneous scenario. Outputs from the in-package chemistry model implemented inside TSPA-LA include pH, ionic strength, and total carbonate concentration. These inputs to TSPA-LA will be linked to the following principle factors: dissolution rates of the CSNF and HLWG, dissolved concentrations of radionuclides, and colloid generation.

  9. Sandia National Laboratories: Careers: Chemistry & Chemical Engineering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry & Chemical Engineering Chemistry research photo Sandia's Combustion Research Facility pioneered the use of chemical-imaging tools, such as laser diagnostics, for combustion applications. Chemists at Sandia conduct research and development at the interface between biology, synthetic chemistry, and surface science to deliver prototype solutions in diverse applications. They provide knowledge about materials structure, properties, and performance and about the processes to produce,

  10. Chemistry and Transport - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Transport Chemistry and Transport The overall goal of the flame chemistry working group is to obtain fundamental combustion and emission properties of low and high pressure flames, to validate kinetic and transport models, and to develop accurate and computationally efficient models capable of predicting turbulent combustion of future transportation fuels. Experimental data of laminar and turbulent flame speeds, flame structures, extinction/ignition limits, and soot/NOx emissions

  11. A round robin evaluation of the corrosiveness of wet residential insulation by electrochemical measurements

    SciTech Connect (OSTI)

    Stansbury, E.E. , Knoxville, TN )

    1991-10-01

    The results of a round cabin evaluation of the use of an electrochemical method of calculating the corrosion rate of low carbon steel in environments related to cellulosic building insulations are reported. Environments included the leachate from a wet cellulosic insulation and solutions based on pure and commercial grades of borax, ammonium sulfate and aluminum sulfate. The pH values of these environments were in the range of 2.5 to 9.5. Electrochemical measurements were made using a direct reading corrosion rate instrument. The calculated corrosion rates were compared with those determined directly by weight loss measurements. Electrochemical measurements were made over a period of 48 hours and weight loss exposures were for two weeks. Poor agreement was observed for the corrosion rates determined electrochemically and the values were consistently larger than those based on weight loss. Reasons proposed for these results included the complex nature of the corrosion product deposits and the control these deposits have on oxygen diffusion to the metal interface. Both factors influence the validity of the calculation of the corrosion rate by the direct reading instrument. It was concluded that development of a viable electrochemical method of general applicability to the evaluation of the corrosiveness of wet residential building thermal insulations were doubtful. Because of the controlling influence of dissolved oxygen on the corrosion rate in the insulation leachate, an alternate evaluation method is proposed in which a thin steel specimen is partially immersed in wet insulation for three weeks. The corrosiveness of the wet insulation is evaluated in terms of the severity of attack near the metal-air-wet insulation interface. With thin metal specimens, complete penetration along the interface is proposed as a pass/fail criterion. An environment of sterile cotton wet with distilled water is proposed as a comparative standard. 9 refs., 2 figs., 3 tabs.

  12. Method for wetting a boron alloy to graphite

    DOE Patents [OSTI]

    Storms, E.K.

    1987-08-21

    A method is provided for wetting a graphite substrate and spreading a a boron alloy over the substrate. The wetted substrate may be in the form of a needle for an effective ion emission source. The method may also be used to wet a graphite substrate for subsequent joining with another graphite substrate or other metal, or to form a protective coating over a graphite substrate. A noneutectic alloy of boron is formed with a metal selected from the group consisting of nickel (Ni), palladium (Pd), and platinum (Pt) with excess boron, i.e., and atomic percentage of boron effective to precipitate boron at a wetting temperature of less than the liquid-phase boundary temperature of the alloy. The alloy is applied to the substrate and the graphite substrate is then heated to the wetting temperature and maintained at the wetting temperature for a time effective for the alloy to wet and spread over the substrate. The excess boron is evenly dispersed in the alloy and is readily available to promote the wetting and spreading action of the alloy. 1 fig.

  13. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR)...

  14. Analytical Chemistry Laboratory | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Laboratory provides a broad range of analytical chemistry support services to the scientific and engineering programs. AnalyticalChemistryLaboratoryfactsheet...

  15. SPONTANEOUS CATALYTIC WET AIR OXIDATION DURING PRE-TREATMENT OF HIGH-LEVEL RADIOACTIVE WASTE SLUDGE

    SciTech Connect (OSTI)

    Koopman, D.; Herman, C.; Pareizs, J.; Bannochie, C.; Best, D.; Bibler, N.; Fellinger, T.

    2009-10-01

    Savannah River Remediation, LLC (SRR) operates the Defense Waste Processing Facility for the U.S. Department of Energy at the Savannah River Site. This facility immobilizes high-level radioactive waste through vitrification following chemical pretreatment. Catalytic destruction of formate and oxalate ions to carbon dioxide has been observed during qualification testing of non-radioactive analog systems. Carbon dioxide production greatly exceeded hydrogen production, indicating the occurrence of a process other than the catalytic decomposition of formic acid. Statistical modeling was used to relate the new reaction chemistry to partial catalytic wet air oxidation of both formate and oxalate ions driven by the low concentrations of palladium, rhodium, and/or ruthenium in the waste. Variations in process conditions led to increases or decreases in the total oxidative destruction, as well as partially shifting the preferred species undergoing destruction from oxalate ion to formate ion.

  16. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beltrami, Denis; Cote, Gérard; Mokhtari, Hamid; Courtaud, Bruno; Moyer, Bruce A; Chagnes, Alexandre

    2014-01-01

    Between 1951 and 1991, about 17 processes were developed to recover uranium from wet phosphoric acid (WPA), but the viability of these processes was subject to the variation of the uranium price market. Nowadays, uranium from WPA appears to be attractive due to the increase of the global uranium demand resulting from the emergence of developing countries. The increasing demand provides impetus for a new look at the applicable technology with a view to improvements as well as altogether new approaches. This paper gives an overview on extraction processes developed in the past to recover uranium from wet phosphoric acidmore » (WPA) as well as the physicochemistry involved in these processes. Recent advances concerning the development of new extraction systems are also reported and discussed.« less

  17. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

    SciTech Connect (OSTI)

    Beltrami, Denis; Cote, Grard; Mokhtari, Hamid; Courtaud, Bruno; Moyer, Bruce A; Chagnes, Alexandre

    2014-01-01

    Between 1951 and 1991, about 17 processes were developed to recover uranium from wet phosphoric acid (WPA), but the viability of these processes was subject to the variation of the uranium price market. Nowadays, uranium from WPA appears to be attractive due to the increase of the global uranium demand resulting from the emergence of developing countries. The increasing demand provides impetus for a new look at the applicable technology with a view to improvements as well as altogether new approaches. This paper gives an overview on extraction processes developed in the past to recover uranium from wet phosphoric acid (WPA) as well as the physicochemistry involved in these processes. Recent advances concerning the development of new extraction systems are also reported and discussed.

  18. Exhaust Phosphorous Chemistry | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon deer_2003_bunting2.pdf More Documents & Publications Exhaust Phosphorous Chemistry and Catalyst Poisoning The Development of Rapid Aging and Poisoning Protocols for Diesel Aftertreatment Devices Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report

  19. RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL

    Office of Scientific and Technical Information (OSTI)

    The early days Richards, P. 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL ASPECTS; TECHNETIUM 99; COLLOIDS; MOLYBDENUM...

  20. Enhanced NO{sub x} removal in wet scrubbers using metal chelates. Final report, Volume 1

    SciTech Connect (OSTI)

    Smith, K.; Lani, B.; Berisko, D.; Schultz, C.; Carlson, W.; Benson, L.B.

    1992-12-01

    Successful pilot plant tests of simultaneous removal of S0{sub 2} and NO{sub x} in a wet lime flue gas desulfurization system were concluded in December. The tests, at up to 1.5 MW(e) capacity, were conducted by the Cincinnati Gas and Electric Company and Dravo Lime Company for the US Department of Energy at a pilot facility at the Miami Fort station of CG&E near Cincinnati, Ohio. The pilot plant scrubbed a slipstream of flue gas from Unit 7, a 530 MW coal-fired electric generating unit. Tests were conducted in three phases between April and December. The technology tested was wet scrubbing with Thiosorbic{reg_sign} magnesium-enhanced lime for S0{sub 2} removal and simultaneous NO scrubbing with ferrous EDTA, a metal chelate. Magnesium-enhanced lime-based wet scrubbing is used at 20 full-scale high-sulfur coal-fired electric generating units with a combined capacity of 8500 NW. Ferrous EDTA reacts with nitric oxide, NO, which comprises about 95% of NO{sub x} from coal-fired boilers. In this report, although not precise, NO and NO{sub x} are used interchangably. A major objective of the tests was to combine NO{sub x} removal using ferrous EDTA, a developing technology, with SO{sub 2} removal using wet lime FGD, already in wide commercial use. If successful, this could allow wide application of this NO{sub x} removal technology.

  1. High Pressure Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  2. High Temperature Aqueous Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accurate knowledge of aqueous chemistry at high temperatures and pressures is important in many applications including nuclear waste disposal and energy extraction. Sandia's Defense Waste Management Programs is equipped with a state-of-the-art hydrothermal experimental system that allows us to obtain high quality kinetic and equilibrium data at temperatures and pressures of interest up to 600 o C and 1,000 bars (100 MPa). This state-of-the-art hydrothermal experimental system includes the

  3. Chemistry of Autoignition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Autoignition - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  4. Extensible Computational Chemistry Environment

    Energy Science and Technology Software Center (OSTI)

    2012-08-09

    ECCE provides a sophisticated graphical user interface, scientific visualization tools, and the underlying data management framework enabling scientists to efficiently set up calculations and store, retrieve, and analyze the rapidly growing volumes of data produced by computational chemistry studies. ECCE was conceived as part of the Environmental Molecular Sciences Laboratory construction to solve the problem of researchers being able to effectively utilize complex computational chemistry codes and massively parallel high performance compute resources. Bringing themore » power of these codes and resources to the desktops of researcher and thus enabling world class research without users needing a detailed understanding of the inner workings of either the theoretical codes or the supercomputers needed to run them was a grand challenge problem in the original version of the EMSL. ECCE allows collaboration among researchers using a web-based data repository where the inputs and results for all calculations done within ECCE are organized. ECCE is a first of kind end-to-end problem solving environment for all phases of computational chemistry research: setting up calculations with sophisticated GUI and direct manipulation visualization tools, submitting and monitoring calculations on remote high performance supercomputers without having to be familiar with the details of using these compute resources, and performing results visualization and analysis including creating publication quality images. ECCE is a suite of tightly integrated applications that are employed as the user moves through the modeling process.« less

  5. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  6. Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    (Billion Cubic Feet) Gulf of Mexico Federal Offshore Natural Gas, Wet After Lease Separation, Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  7. MHK Technologies/WET EnGen | Open Energy Information

    Open Energy Info (EERE)

    Test of Wave Energy Technologies Moored Floating WET EnGen: Regular and Irregular Waves. TR-2009-13, Fraser Winsor and Emile Baddour, June 2009. Date Submitted 1082010 << Return...

  8. Texas - RRC District 8 Natural Gas, Wet After Lease Separation...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas - RRC District 8 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 ...

  9. Nebraska Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Associated-Dissolved Natural Gas Proved Reserves, Wet After Lease Separation, as of Dec. 31 Nebraska Associated-Dissolved Natural

  10. Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Nebraska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) No Data Available For This Series - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Nonassociated Natural Gas Proved Reserves,

  11. Observation of Ordered Structures in Counterion Layers near Wet Charged

    Office of Scientific and Technical Information (OSTI)

    Surfaces: A Potential Mechanism for Charge Inversion (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Observation of Ordered Structures in Counterion Layers near Wet Charged Surfaces: A Potential Mechanism for Charge Inversion Citation Details In-Document Search Title: Observation of Ordered Structures in Counterion Layers near Wet Charged Surfaces: A Potential Mechanism for Charge Inversion Authors: Miller, Mitchell ; Chu, Miaoqi ; Lin, Binhua ; Meron,

  12. U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet After...

    Gasoline and Diesel Fuel Update (EIA)

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) U.S. Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves...

  13. U.S. Federal Offshore Nonassociated Natural Gas, Wet After Lease...

    Gasoline and Diesel Fuel Update (EIA)

    Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) U.S. Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic...

  14. Texas - RRC District 2 Onshore Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)...

  15. Texas - RRC District 7B Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  16. Texas - RRC District 4 Onshore Natural Gas, Wet After Lease Separation...

    Gasoline and Diesel Fuel Update (EIA)

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)...

  17. Texas - RRC District 3 Onshore Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)...

  18. Texas - RRC District 7C Natural Gas, Wet After Lease Separation...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 7C Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade...

  19. Wet Chemical Compositional and Near IR Spectra Data Sets for Biomass -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Wet Chemical Compositional and Near IR Spectra Data Sets for Biomass National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing SummaryNREL has developed the following laboratory analytical procedures (LAPs) for standard biomass analysis. The American Society for Testing and Materials (ASTM) and the Technical Association of the Pulp and Paper Industry

  20. Henry Taube and Coordination Chemistry

    Office of Scientific and Technical Information (OSTI)

    Henry Taube and Coordination Chemistry Resources with Additional Information Henry Taube Chuck Painter/Stanford News Service Henry Taube, a Marguerite Blake Wilbur Professor of Chemistry, Emeritus, at Stanford University, received the 1983 Nobel Prize in Chemistry "for his work on the mechanisms of electron transfer reactions, especially in metal complexes" Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I

  1. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry » Synthetic and Mechanistic Synthetic and Mechanistic publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this century.

  2. Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Applications Chemistry and Material Sciences Applications June 26, 2012 Jack Zhengji NERSC Training Event 09:00 - 12:00 PST June 26, 2012 Concurrently presented on the web and at NERSC's Oakland Scientific Facility Attendance: 45 Chemistry and Material Sciences Applications Zhengji Zhao, NERSC User Services Group Jack Deslippe, NERSC User Services Group The first hour of the training is targeted at beginners. We will show you how to get started running material

  3. Surveillance of LWR spent fuel in wet storage. Final report, October 1984

    SciTech Connect (OSTI)

    Bailey, W.J.; Johnson, A.B. Jr.

    1984-10-01

    Battelle, Pacific Northwest Laboratories established a surveillance program for EPRI that documents the integrity of spent light-water reactor fuel and structural materials (spent fuel storage pool liners, racks, piping, etc.) during wet storage. The program involves providing an update on the overall performance of spent fuel in wet storage, monitoring Licensee Event Reports (LERs) for pertinent significant occurrences, identifying lead spent fuel assemblies that are of particular interest to EPRI, monitoring developments in fuel design and performance and assessing their influence on spent fuel storage characteristics, and identifying specific actions or programs that may be needed to maintain the viability of wet storage of spent fuel for extended periods. Experience to date indicates that wet storage is a well-developed technology with no associated major technological problems. Spent fuel storage pools are operated without substantial risk to the public or the plant personnel. A list of lead spent fuel assemblies is presented. Pertinent occurrences from LERs are listed. Very few fuel assemblies have suffered major mechanical damage as a result of handling operations at spent fuel storage pools. Experience to date with handling operations at spent fuel storage pools indicates that failed fuel rods and inadvertent fracturing of fuel rods can be accommodated. Minor problems have occurred with spent fuel storage pool components such as liners, racks, and piping. Surveillance continues to be needed on: (1) possible effects on handling and storage of spent fuel from extended burnup, hydrogen injection at boiling water reactors, and rod consolidation operations; (2) extended pool exposure of neutron-absorbing materials; (3) cracking of spent fuel storage pool piping at pressurized water reactors; and (4) control of impurities in spent fuel pool waters. 120 references, 13 figures, 10 tables.

  4. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

    2010-12-31

    This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed-structure mercury sorbent upstream. This final report presents and discusses detailed results from all of these efforts, and makes a number of conclusions about what was learned through these efforts.

  5. New York Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New York Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 211 1980's 208 262 226 295 387 367 457 410 351 364 1990's 354 331 329 264 240 195 229 223 217 212 2000's 320 311 315 365 324 346 361 365 360 196 2010's 271 245 178 138 138 - = No Data

  6. North Dakota Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) North Dakota Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 485 1980's 594 654 696 673 643 650 610 578 593 625 1990's 650 533 567 585 568 518 512 531 501 475 2000's 487 495 524 497 465 508 539 572 603 1,213 2010's 1,869 2,652 3,974 6,081 6,787 - = No Data Reported; -- = Not Applicable; NA =

  7. North Dakota Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) North Dakota Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 284 1980's 355 401 448 416 376 319 317 302 327 312 1990's 316 290 301 311 293 255 257 274 240 225 2000's 223 225 209 181 145 165 182 155 119 143 2010's 152 141 105 91 45 - = No Data

  8. Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Ohio Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 432 1980's 282 165 158 396 364 395 522 477 749 686 1990's 844 805 780 763 780 699 715 594 548 777 2000's 717 631 772 823 767 714 801 926 886 799 2010's 742 684 1,012 2,887 6,985 - = No Data Reported; --

  9. Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 9 1980's 11 14 14 21 78 67 22 21 8 19 1990's 23 20 10 8 9 36 47 92 79 96 2000's 157 168 137 164 125 134 151 130 127 133 2010's 144 134 125 269 299 - = No Data

  10. Louisiana - North Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - North Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 765 1980's 916 1,040 832 775 690 632 567 488 249 237 1990's 241 192 160 120 134 133 255 287 183 260 2000's 186 168 159 139 107 98 90 73 78 53

  11. Louisiana State Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,269 1,351 1,478 1,209 1,273 1990's 1,019 1,082 845 946 988 862 783 743 571 661 2000's 721 772 512 527 394 433 442 392 934 728 2010's 386 519 519 420 341 - = No Data Reported; -- = Not Applicable; NA =

  12. Louisiana State Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,820 1,100 1,218 1,002 1,042 1990's 812 875 691 789 820 714 626 613 473 541 2000's 592 627 428 448 333 370 386 327 248 215 2010's 279 468 391 332 273 - =

  13. Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 733 1980's 883 758 719 824 774 689 577 569 491 432 1990's 408 437 352 328 357 326 347 281 228 227 2000's 214 159 214 269 193 153 192 179 148 77 2010's 72 77 94 125 108

  14. Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14 1980's 34 12 27 31 14 25 41 13 28 39 1990's 22 14 11 9 11 32 28 31 17 54 2000's 19 19 20 14 12 14 19 15 9 78 2010's 10 104 7 19 18 - = No

  15. Miscellaneous States Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Miscellaneous States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 156 1980's 180 193 74 81 77 77 136 66 84 87 1990's 72 76 93 96 67 69 68 44 39 67 2000's 42 83 100 134 110 132 139 241 272 349 2010's 363 393 233 188 185 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  16. Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 142 1980's 146 181 47 50 63 52 95 53 56 48 1990's 50 62 82 87 56 37 40 13 22 13 2000's 23 64 80 120 98 118 120 226 263 271 2010's 353 270 219 169 167 - = No Data

  17. Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 67 1980's 73 66 74 80 114 105 66 61 71 105 1990's 126 108 85 53 43 27 47 51 47 31 2000's 35 26 33 27 20 20 21 30 45 38 2010's 36 62 62 43 58 - = No Data Reported; --

  18. Montana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 51 1980's 122 89 81 108 77 91 98 97 101 68 1990's 86 66 61 53 55 53 51 42 52 67 2000's 70 85 94 112 130 161 195 219 197 312 2010's 302 270 289 304 325 - = No Data

  19. Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Montana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 786 1980's 1,186 1,247 789 813 748 793 725 704 733 821 1990's 834 782 814 631 672 739 755 727 737 784 2000's 822 822 820 956 872 837 874 848 817 681 2010's 657 522 327 286 361 - = No Data

  20. Electro-osmotic transport in wet processing of textiles

    DOE Patents [OSTI]

    Cooper, John F.

    1998-01-01

    Electro-osmotic (or electrokinetic) transport is used to efficiently force a solution (or water) through the interior of the fibers or yarns of textile materials for wet processing of textiles. The textile material is passed between electrodes that apply an electric field across the fabric. Used alone or in parallel with conventional hydraulic washing (forced convection), electro-osmotic transport greatly reduces the amount of water used in wet processing. The amount of water required to achieve a fixed level of rinsing of tint can be reduced, for example, to 1-5 lbs water per pound of fabric from an industry benchmark of 20 lbs water/lb fabric.

  1. Electro-osmotic transport in wet processing of textiles

    DOE Patents [OSTI]

    Cooper, J.F.

    1998-09-22

    Electro-osmotic (or electrokinetic) transport is used to efficiently force a solution (or water) through the interior of the fibers or yarns of textile materials for wet processing of textiles. The textile material is passed between electrodes that apply an electric field across the fabric. Used alone or in parallel with conventional hydraulic washing (forced convection), electro-osmotic transport greatly reduces the amount of water used in wet processing. The amount of water required to achieve a fixed level of rinsing of tint can be reduced, for example, to 1--5 lbs water per pound of fabric from an industry benchmark of 20 lbs water/lb fabric. 5 figs.

  2. Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 13 1980's 23 25 1990's 25 23 30 46 56 44 38 30 28 27 2000's 29 26 31 32 32 29 18 20 19 29 2010's 38 48 100 46 141 - = No Data Reported; -- = Not Applicable; NA = Not

  3. Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 166 1980's 194 184 174 194 189 157 150 145 157 145 1990's 67 136 133 93 85 104 89 56 38 41 2000's 39 30 38 37 40 46 44 37 12 20 2010's 29 46 82 135 189 - = No Data

  4. California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 307 1980's 265 265 325 344 256 254 261 243 220 233 1990's 228 220 196 135 145 109 120 129 116 233 2000's 244 185 197

  5. California - Coastal Region Onshore Natural Gas, Wet After Lease Separation

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 395 1980's 330 325 384 405 284 277 275 255 232 238 1990's 232 231 215 201 205 163 168 176 118 233 2000's 244 185 197 174 196 277 214 212 151 169 2010's 180 173 305 284 277 - = No Data

  6. California - Coastal Region Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Coastal Region Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 88 1980's 65 60 59 61 28 23 14 12 12 5 1990's 4 11 19 66 60 54 48 47 2 0 2000's 0 0 0 1 8 8 6 1 1 1 2010's 2 1 2 2 8 - = No Data

  7. California - Los Angeles Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 176 1980's 207 163 104 115 163 188 149 155 158 141 1990's 110 120 103 108 108 115 112 146 154 174 2000's 204 195 218 196 184 186 161 154 81 91 2010's 92 102 98 90 84 - =

  8. California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - Los Angeles Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1 1980's 0 1 1 1 1 3 0 0 0 0 1990's 0 0 3 0 0 0 0 3 1 0 2000's 1 1 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not

  9. California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,784 1980's 1,721 1,566 1,593 1,556 1,538 1,642 1,398 1,196 1,086 972 1990's 901 885 773 749 744 679 560 518 445 336 2000's 748 836

  10. California Federal Offshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 249 1980's 307 1,110 1,249 1,312 1,252 1990's 1,229 995 987 976 1,077 1,195 1,151 498 437 488 2000's 500 490 459 456 412 776 756

  11. California Federal Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 73 1980's 107 227 217 258 267 1990's 240 179 149 147 110 94 115 58 52 48 2000's 76 50 56 55 47 49 55 53 3 9 2010's 3 0 0 0 0 - = No Data Reported; -- =

  12. California Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,881 1980's 1,792 1,424 1,230 1,120 1,006 1990's 911 901 799 817 808 736 610 570 453 355 2000's 754 842 796 759 767 799 780 686 621 612 2010's 503 510 272 247 273 - = No Data Reported;

  13. California State Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California State Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 234 1980's 166 256 254 243 235 1990's 194 60 63 65 63 59 49 56 44 77 2000's 91 85 91 83 87 90 90 83 57 57 2010's 66 82 66 75 76 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  14. California State Offshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8 1980's 6 12 22 22 29 1990's 6 5 4 2 4 3 2 2 5 19 2000's 5 5 6 7 2 1 5 4 3 4 2010's 3 3 1 0 0 - = No Data Reported; -- = Not Applicable; NA = Not

  15. Florida Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 30 2 0 1 0 - = No Data Reported; -- =

  16. Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 108 1980's 122 99 86 64 90 81 69 62 69 57 1990's 53 45 55 59 117 110 119 112 106 100 2000's 93 96 102 92 88 87 50 110 1 7 2010's 56 6 16 15 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  17. Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Florida Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 26 4 16 14 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  18. Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2 1980's 11 14 12 19 17 13 17 19 19 22 1990's 8 10 8 6 47 27 24 26 20 29 2000's 27 25 25 25 19 30 36 34 34 32 2010's 111 98 93 44 49 - = No Data Reported; -- = Not

  19. Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 633 1980's 502 796 965 845 786 753 761 717 686 617 1990's 703 674 613 636 715 730 749 785 665 1,180 2000's 1,645 2,428 3,070 3,514 4,445 4,608 6,660 7,846

  20. Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,038 1980's 1,374 1,228 1,060 959 867 710 691 691 616 581 1990's 573 572 624 502 611 879 824 850 794 713 2000's 652 488 561 450 362 384 347 365 223 362 2010's 334 318

  1. Design of the national trends network for monitoring the chemistry of atmospheric precipitation

    SciTech Connect (OSTI)

    Robertson, J.K.; Wilson, J.W.

    1985-01-01

    Long-term monitoring (10 years minimum) of the chemistry of wet deposition will be conducted at National Trends Network (NTN) sites across the United States. Precipitation samples will be collected at sites that represent broad regional characteristics. Design of the NTN considered four basic elements during construction of a model to distribute 50, 75, 100, 125 or 150 sites. The modeling oriented design was supplemented with guidance developed during the course of the site selection process. Ultimately, a network of 151 sites was proposed. The basic elements of the design are: assurance that all areas of the country are represented in the network on the basis of regional ecological properties (96 sites); placement of additional sites east of the Rocky Mountains to better define high deposition gradients (27 sites); placement of sites to assure that potentially sensitive regions are represented (15 sites); and placement of sites to allow for other considerations such as urban area effects (5 sites), intercomparison with Canada (3 sites), and apparent disparities in regional coverage (5 sites). Site selection stressed areas away from urban centers, large point sources, or ocean influences. Local factors, such as stable land ownership, nearby small emission sources (about 10 km), and close-by roads and fireplaces (about 0.5 km) were also considered. All proposed sites will be visited as part of the second phase of the study. 29 refs., 18 figs.

  2. Chemistry for Measurement and Detection Science publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science » Chemistry for Measurement and Detection Science publications Chemistry for Measurement and Detection Science publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of

  3. Molecular dynamics of wetting layer formation and forced water invasion in angular nanopores with mixed wettability

    SciTech Connect (OSTI)

    Sedghi, Mohammad Piri, Mohammad; Goual, Lamia

    2014-11-21

    The depletion of conventional hydrocarbon reservoirs has prompted the oil and gas industry to search for unconventional resources such as shale gas/oil reservoirs. In shale rocks, considerable amounts of hydrocarbon reside in nanoscale pore spaces. As a result, understanding the multiphase flow of wetting and non-wetting phases in nanopores is important to improve oil and gas recovery from these formations. This study was designed to investigate the threshold capillary pressure of oil and water displacements in a capillary dominated regime inside nanoscale pores using nonequilibrium molecular dynamics (NEMD) simulations. The pores have the same cross-sectional area and volume but different cross-sectional shapes. Oil and water particles were represented with a coarse grained model and the NEMD simulations were conducted by assigning external pressure on an impermeable piston. Threshold capillary pressures were determined for the drainage process (water replaced by oil) in different pores. The molecular dynamics results are in close agreements with calculations using the Mayer-Stowe-Princen (MS-P) method which has been developed on the premise of energy balance in thermodynamic equilibrium. After the drainage simulations, a change in wall particles’ wettability from water-wet to oil-wet was implemented based on the final configuration of oil and water inside the pore. Waterflooding simulations were then carried out at the threshold capillary pressure. The results show that the oil layer formed between water in the corner and in the center of the pore is not stable and collapses as the simulation continues. This is in line with the predictions from the MS-P method.

  4. Cetane Performance and Chemistry Comparing Conventional Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels Derived from Heavy Crude Sources Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels ...

  5. Chemistry and Material Sciences Codes at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Codes Chemistry and Material Sciences Codes at NERSC April 6, 2011 Last edited: 2016-04-29 11:35:1

  6. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home News & Publications NERSC News Center News Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda...

  7. Modeling the Explicit Chemistry of Anthropogenic and Biogenic Organic Aerosols

    SciTech Connect (OSTI)

    Madronich, Sasha

    2015-12-09

    The atmospheric burden of Secondary Organic Aerosols (SOA) remains one of the most important yet uncertain aspects of the radiative forcing of climate. This grant focused on improving our quantitative understanding of SOA formation and evolution, by developing, applying, and improving a highly detailed model of atmospheric organic chemistry, the Generation of Explicit Chemistry and Kinetics of Organics in the Atmosphere (GECKO-A) model. Eleven (11) publications have resulted from this grant.

  8. Subcritical water extraction of lipids from wet algal biomass

    DOE Patents [OSTI]

    Deng, Shuguang; Reddy, Harvind K.; Schaub, Tanner; Holguin, Francisco Omar

    2016-05-03

    Methods of lipid extraction from biomass, in particular wet algae, through conventionally heated subcritical water, and microwave-assisted subcritical water. In one embodiment, fatty acid methyl esters from solids in a polar phase are further extracted to increase biofuel production.

  9. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    The Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding is provided by the US Department of Energy.

  10. Hot atom chemistry and radiopharmaceuticals

    SciTech Connect (OSTI)

    Krohn, Kenneth A.; Moerlein, Stephen M.; Link, Jeanne M.; Welch, Michael J.

    2012-12-19

    The chemical products made in a cyclotron target are a combined result of the chemical effects of the nuclear transformation that made the radioactive atom and the bulk radiolysis in the target. This review uses some well-known examples to understand how hot atom chemistry explains the primary products from a nuclear reaction and then how radiation chemistry is exploited to set up the optimal product for radiosynthesis. It also addresses the chemical effects of nuclear decay. There are important principles that are common to hot atom chemistry and radiopharmaceutical chemistry. Both emphasize short-lived radionuclides and manipulation of high specific activity nuclides. Furthermore, they both rely on radiochromatographic separation for identification of no-carrieradded products.

  11. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    he Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding...

  12. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADCLES Chemistry, Life, and Earth Sciences The CLES Directorate is home to world class capabilities in chemistry, bioscience, and earth and environmental sciences. Structural protein research Structural protein research A wide range of protein folding research Field Instrument Deployments and Operations (FIDO) Field Instrument Deployments and Operations (FIDO) Atmospheric science research Quantum Dots Quantum Dots Quantum dot research for energy and light Contact Us Associate Director Nan Sauer

  13. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science Chemistry for Measurement and Detection Science Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of two FBI "hub" laboratories for analyzing bulk special nuclear

  14. Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,246 1980's 2,252 2,441 2,426 2,269 2,244 2,149 2,191 2,017 1,894 1,785 1990's 1,820 1,406 1,483 1,550 1,342 1,228 1,023 1,015 1,196 1,238 2000's 1,113 1,109 1,177

  15. Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,545 1980's 13,908 15,507 17,140 17,261 17,102 17,078 17,779 17,703 17,450 16,733 1990's 16,967 15,518 14,732 14,099 14,323 14,295 13,952 14,311 14,517 13,490 2000's 14,543 14,366 15,753 16,231 17,200 18,146 18,535 20,184 22,113 24,207 2010's

  16. Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Oklahoma Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,299 1980's 11,656 13,066 14,714 14,992 14,858 14,929 15,588 15,686 15,556 14,948 1990's 15,147 14,112 13,249 12,549 12,981 13,067 12,929 13,296 13,321 12,252 2000's 13,430 13,256 14,576

  17. Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,516 1980's 951 1,265 1,430 1,882 1,576 1,618 1,562 1,650 2,074 1,644 1990's 1,722 1,631 1,533 1,722 1,806 1,488 1,702 1,861 1,848 1,780 2000's 1,740 1,782 2,225 2,497 2,371 2,793 3,064 3,377 3,594 7,018 2010's 14,068 26,719 36,543

  18. Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Pennsylvania Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,507 1980's 940 1,251 1,416 1,861 1,498 1,551 1,540 1,629 2,066 1,625 1990's 1,699 1,611 1,523 1,714 1,797 1,452 1,655 1,769 1,769 1,684 2000's 1,583 1,614 2,088 2,333 2,246 2,659

  19. Louisiana - North Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana - North Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,869 1980's 3,160 3,358 2,988 3,008 2,546 2,650 2,567 2,350 2,442 2,705 1990's 2,640 2,435 2,363 2,376 2,599 2,863 3,189 3,156 2,943 3,127 2000's 3,344 3,927 4,283 5,137 5,841 6,768 6,795 6,437 7,966 17,273 2010's

  20. Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,104 1980's 2,244 2,318 2,156 2,233 1,856 2,018 2,000 1,862 2,193 2,468 1990's 2,399 2,243 2,203 2,256 2,465 2,730 2,934 2,869 2,760 2,867 2000's 3,158 3,759 4,124

  1. Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,580 1980's 13,407 13,049 12,153 11,553 10,650 10,120 9,416 9,024 8,969 8,934 1990's 8,492 7,846 7,019 6,219 6,558 6,166 6,105 6,137 5,966 5,858 2000's 5,447 5,341 4,395 3,874 3,557 3,478 3,473 3,463

  2. Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,276 1980's 11,273 11,178 10,364 9,971 9,162 8,328 7,843 7,644 7,631 7,661 1990's 7,386 6,851 6,166 5,570 5,880 5,446 5,478 5,538 5,336 5,259 2000's

  3. Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,360 2,391 2,128 1,794 1,741 1990's 1,554 1,394 1,167 926 980 1,001 1,039 1,016 911 979 2000's 807 796 670 586 557 588 561 641 1,235 1,072 2010's 679 639 773 870 908

  4. Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 19,676 13,334 12,852 12,620 12,912 1990's 12,151 11,363 10,227 9,541 10,145 9,891 10,077 10,036 9,480 9,646 2000's 9,512 10,040 9,190 9,538 9,792 10,679 10,710 10,292 11,816 20,970 2010's 29,517 30,545 22,135 20,389 23,258 - = No Data Reported;

  5. Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 16,316 10,943 10,724 10,826 11,171 1990's 10,597 9,969 9,060 8,615 9,165 8,890 9,038 9,020 8,569 8,667 2000's 8,704 9,245 8,520 8,952 9,235 10,091 10,149 9,651 10,581 19,898 2010's 28,838

  6. Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Lower 48 States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 143,852 1980's 139,421 143,515 142,984 143,469 141,226 138,464 139,070 135,256 141,211 139,798 1990's 141,941 140,584 138,883 136,953 138,213 139,369 141,136 140,382 139,015

  7. Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Michigan Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 601 1980's 668 494 481 529 419 375 665 1,002 943 1,011 1990's 922 967 938 890 1,022 1,018 1,778 1,975 2,158 2,086 2000's 2,558 2,873 3,097 3,219 2,961 2,808 2,925 3,512 3,105 2,728 2010's

  8. Mississippi Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Mississippi Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,511 1980's 1,776 2,042 1,803 1,603 1,496 1,364 1,304 1,223 1,146 1,108 1990's 1,129 1,061 873 800 653 667 634 583 662 681 2000's 620 663 746 748 692 758 816 958 1,035 922 2010's 858 868 612 600 563 - = No Data Reported; -- = Not

  9. Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Mississippi Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,444 1980's 1,703 1,976 1,729 1,523 1,382 1,259 1,238 1,162 1,075 1,003 1990's 1,003 953 788 747 610 640 587 532 615 650 2000's 585 637 713 721 672 738 795 928 990 884 2010's 822 806

  10. Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 837 1980's 1,308 1,336 870 921 825 884 823 801 834 889 1990's 920 848 875 684 727 792 806 769 789 851 2000's 892 907 914 1,068 1,002 998 1,069 1,067 1,014 993 2010's 959 792 616 590 686 - = No Data Reported; -- = Not Applicable; NA = Not

  11. New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,634 1980's 2,266 2,377 2,331 2,214 2,117 2,001 1,750 1,901 2,030 2,131 1990's 2,290 2,073 1,948 1,860 1,791 1,648 1,612 1,694 1,694 1,880 2000's 2,526 2,571 2,632

  12. New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 9,934 1980's 10,001 10,536 9,231 8,654 8,341 7,947 9,344 9,275 15,000 13,088 1990's 14,804 16,131 16,854 16,494 15,156 15,421 14,620 13,586 13,122 13,292 2000's

  13. New Mexico Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 12,568 1980's 12,267 12,913 11,562 10,868 10,458 9,948 11,094 11,176 17,030 15,219 1990's 17,094 18,204 18,802 18,354 16,947 17,069 16,232 15,280 14,816 15,172 2000's 16,922 17,112 16,971

  14. Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 693 1980's 682 683 1990's 4,184 5,460 5,870 5,212 4,898 4,930 5,100 5,013 4,643 4,365 2000's 4,269 3,958 3,922 4,345 4,159 4,006 3,963 4,036 3,379 2,948 2010's 2,724 2,570 2,304 1,670 2,121 - = No Data Reported; -- = Not Applicable; NA = Not

  15. Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alabama Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 680 1980's 659 658 1990's 4,159 5,437 5,840 5,166 4,842 4,886 5,062 4,983 4,615 4,338 2000's 4,241 3,931 3,891 4,313 4,127 3,977 3,945 4,016 3,360 2,919 2010's 2,686 2,522 2,204 1,624 1,980

  16. Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 32,275 1980's 33,395 33,049 35,002 34,291 34,476 34,223 33,355 33,715 9,179 9,019 1990's 9,393 9,653 9,725 9,986 9,813 9,575 9,296 10,673 10,043 9,855 2000's 9,331 8,901 8,533 8,348 8,473 8,237 10,333 12,022 7,766 9,183 2010's 8,917 9,511 9,667

  17. Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alaska Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 5,058 1980's 4,828 4,373 4,188 3,883 4,120 3,131 2,462 2,983 2,910 2,821 1990's 2,466 2,924 3,002 3,492 3,326 3,310 3,216 2,957 2,768 2,646 2000's 2,564 2,309 2,157 2,081 2,004 1,875 1,447

  18. Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,725 1980's 1,796 1,821 1,974 2,081 2,240 2,032 2,011 2,018 2,000 1,782 1990's 1,739 1,672 1,752 1,555 1,610 1,566 1,472 1,479 1,332 1,546 2000's 1,584 1,619 1,654 1,666 1,837 1,967 2,271 3,306 5,628 10,872 2010's 14,181 16,374 11,039 13,524

  19. Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Arkansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,559 1980's 1,602 1,637 1,800 1,887 2,051 1,875 1,861 1,873 1,843 1,637 1990's 1,672 1,536 1,619 1,462 1,525 1,462 1,383 1,423 1,294 1,505 2000's 1,545 1,589 1,616 1,629 1,797 1,921 2,227

  20. California - San Joaquin Basin Onshore Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California - San Joaquin Basin Onshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,037 1980's 4,434 4,230 4,058 3,964 3,808 3,716 3,404 3,229 3,033 2,899 1990's 2,775 2,703 2,511 2,425 2,130 2,018 1,864 2,012 2,016 2,021 2000's 2,413 2,298 2,190 2,116

  1. California Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,961 1980's 3,345 2,660 2,663 2,546 2,507 1990's 2,400 2,213 2,093 1,982 1,698 1,619 1,583 1,820 1,879 2,150 2000's 2,198 1,922 1,900 1,810 2,006 2,585 2,155 2,193

  2. California Federal Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Federal Offshore Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 322 1980's 414 1,337 1,466 1,570 1,519 1990's 1,469 1,174 1,136 1,123 1,187 1,289 1,266 556 489 536 2000's 576 540 515 511 459 825 811 805 705 740 2010's 725 711 652 264 243 - = No Data Reported; -- =

  3. California Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,842 1980's 5,137 4,084 3,893 3,666 3,513 1990's 3,311 3,114 2,892 2,799 2,506 2,355 2,193 2,390 2,332 2,505 2000's 2,952 2,763 2,696 2,569 2,773 3,384 2,935 2,879 2,538 2,926 2010's 2,785 3,042 2,119 2,023 2,260 - = No Data Reported; -- =

  4. Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 181 1980's 200 259 206 173 208 167 190 219 177 236 1990's 510 682 762 1,162 1,088 1,072 1,055 533 772 781 2000's 960 1,025 1,097 1,186 1,293 1,326 1,541 1,838 2,010

  5. Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,838 1980's 3,170 3,228 3,551 3,373 3,140 3,095 3,198 3,131 3,749 4,526 1990's 4,759 6,011 6,463 6,979 7,036 7,592 8,064 7,160 8,208 9,372 2000's 10,837 12,949 14,348 15,893 15,249 17,122 17,682 22,480 24,169 24,081 2010's 25,372 26,151 21,674

  6. Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Colorado Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,657 1980's 2,970 2,969 3,345 3,200 2,932 2,928 3,008 2,912 3,572 4,290 1990's 4,249 5,329 5,701 5,817 5,948 6,520 7,009 6,627 7,436 8,591 2000's 9,877 11,924 13,251 14,707 13,956 15,796

  7. Gulf of Mexico Federal Offshore - Texas Nonassociated Natural Gas, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Gulf of Mexico Federal Offshore - Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6,411 6,191 6,956 6,739 6,745 6,504 1990's 6,884 6,305 6,353 6,138 5,739 5,674 5,240 4,799 4,452 4,507 2000's 5,030 5,404 4,967

  8. Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,824 1980's 10,065 10,443 10,128 10,183 9,981 9,844 11,093 11,089 10,530 10,509 1990's 10,004 9,946 10,302 9,872 9,705 9,093 8,145 7,328 6,862 6,248 2000's 5,682 5,460 5,329 5,143 5,003 4,598 4,197 4,248 3,795 3,500 2010's 3,937 3,747 3,557

  9. Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,657 1980's 9,880 10,304 10,016 10,051 9,871 9,729 10,961 10,974 10,427 10,408 1990's 9,890 9,831 10,208 9,779 9,630 9,026 8,063 7,277 6,802 6,196 2000's 5,641 5,355 5,263 5,058 4,923 4,515

  10. Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 504 1980's 536 561 592 600 647 806 883 940 957 1,015 1990's 1,047 1,187 1,126 1,036 1,025 1,102 1,046 1,429 1,295 1,530 2000's 1,837 1,950 1,999 1,971 1,982 2,240 2,369 2,588 2,846 2,919 2010's 2,785 2,128 1,515 1,794 1,753 - = No Data Reported;

  11. Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kentucky Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 502 1980's 525 547 580 581 630 793 866 921 938 993 1990's 1,039 1,177 1,118 1,030 978 1,075 1,022 1,403 1,275 1,501 2000's 1,810 1,925 1,974 1,946 1,963 2,210 2,333 2,554 2,812 2,887 2010's

  12. Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 732 1980's 683 870 708 960 714 754 716 639 1,002 1,037 1990's 744 660 606 540 586 498 523 950 1,101 1,165 2000's 1,037 1,024 1,047 1,047 1,184 1,148 1,048

  13. Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,805 1980's 6,381 6,264 6,242 5,948 5,443 5,484 5,320 5,030 4,876 4,849 1990's 4,608 4,763 4,463 4,214 4,405 4,656 4,592 4,386 4,510 4,447 2000's 4,143

  14. Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,127 1980's 1,117 1,265 1,322 1,477 1,911 2,100 2,169 2,106 1,989 1,789 1990's 1,835 1,841 1,692 1,790 1,926 1,876 2,088 1,681 1,906 2,301 2000's 3,089

  15. Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,710 1980's 3,622 3,653 3,749 4,279 4,087 4,274 4,324 4,151 4,506 5,201 1990's 5,345 4,856 4,987 5,170 5,131 5,425 5,690 5,616 5,691 5,562 2000's 5,901

  16. Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 8,073 1980's 7,216 6,620 6,084 6,064 5,362 5,246 5,254 4,973 4,738 4,403 1990's 4,323 4,023 3,792 3,569 3,267 3,218 3,069 2,886 2,727 2,947 2000's 3,345

  17. Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Utah Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 650 1980's 870 1,722 1,928 2,112 1,984 1,897 1,795 1,870 1,509 1,498 1990's 1,432 1,532 1,709 1,909 1,631 1,424 1,446 1,695 2,293 3,050 2000's 4,125 4,450 3,915 3,318 3,661 4,051 4,894 6,095 6,393 6,810

  18. Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 2,446 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579 2,373 2,800 - = No Data Reported; -- = Not Applicable; NA =

  19. Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 122 175 216 235 253 248 230 217 1990's 138 225 904 1,322 1,833 1,836 1,930 1,923 1,973 2,017 2000's 1,704 1,752 1,673 1,717 1,742 2,018 2,302 2,529 2,378 3,091 2010's 3,215 2,832 2,579

  20. West Virginia Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) West Virginia Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,669 1980's 2,559 1,944 2,252 2,324 2,246 2,177 2,272 2,360 2,440 2,342 1990's 2,329 2,672 2,491 2,598 2,702 2,588 2,793 2,946 2,968 3,040 2000's 3,062 2,825 3,498 3,399 3,509 4,572 4,654 4,881 5,266 6,090 2010's 7,163 10,532

  1. West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) West Virginia Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,593 1980's 2,437 1,881 2,169 2,238 2,173 2,104 2,207 2,210 2,299 2,244 1990's 2,243 2,513 2,293 2,408 2,569 2,514 2,722 2,887 2,925 2,952 2000's 2,929 2,777 3,477 3,376 3,489 4,553

  2. Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,834 1980's 9,413 9,659 10,155 10,728 11,014 11,229 10,393 10,572 10,903 11,276 1990's 10,433 10,433 11,305 11,387 11,351 12,712 13,084 14,321 14,371 14,809 2000's 17,211 19,399 21,531 22,716 23,640 24,722 24,463 30,896 32,399 36,748 2010's

  3. Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Wyoming Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 6,796 1980's 8,039 8,431 9,095 9,769 10,147 10,519 9,702 9,881 10,287 10,695 1990's 9,860 9,861 10,681 10,885 10,740 11,833 12,260 13,471 13,577 14,096 2000's 16,559 18,911 20,970 22,266

  4. Wetting and free surface flow modeling for potting and encapsulation.

    SciTech Connect (OSTI)

    Brooks, Carlton, F.; Brooks, Michael J.; Graham, Alan Lyman; Noble, David F. ); Notz, Patrick K.; Hopkins, Matthew Morgan; Castaneda, Jaime N.; Mahoney, Leo James; Baer, Thomas A.; Berchtold, Kathryn; Adolf, Douglas Brian; Wilkes, Edward Dean; Rao, Rekha Ranjana; Givler, Richard C.; Sun, Amy Cha-Tien; Cote, Raymond O.; Mondy, Lisa Ann; Grillet, Anne Mary; Kraynik, Andrew Michael

    2007-06-01

    As part of an effort to reduce costs and improve quality control in encapsulation and potting processes the Technology Initiative Project ''Defect Free Manufacturing and Assembly'' has completed a computational modeling study of flows representative of those seen in these processes. Flow solutions are obtained using a coupled, finite-element-based, numerical method based on the GOMA/ARIA suite of Sandia flow solvers. The evolution of the free surface is solved with an advanced level set algorithm. This approach incorporates novel methods for representing surface tension and wetting forces that affect the evolution of the free surface. In addition, two commercially available codes, ProCAST and MOLDFLOW, are also used on geometries representing encapsulation processes at the Kansas City Plant. Visual observations of the flow in several geometries are recorded in the laboratory and compared to the models. Wetting properties for the materials in these experiments are measured using a unique flowthrough goniometer.

  5. Challenges and Opportunities for Wet-Waste Feedstocks – Resource Assessment

    Broader source: Energy.gov [DOE]

    Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste FeedstocksChallenges and Opportunities for Wet-Waste Feedstocks – Resource...

  6. Wet-steam erosion of steam turbine disks and shafts

    SciTech Connect (OSTI)

    Averkina, N. V.; Zheleznyak, I. V.; Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G.; Shishkin, V. I.

    2011-01-15

    A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

  7. Role of nanocrystallinity on the chemical ordering of CoxPt100-x nanocrystals synthesized by wet chemistry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cordeiro, Marco; Kameche, Farid; Ngo, Anh -Tu; Salzemann, Caroline; Sutter, Eli; Petit, Christophe

    2015-03-17

    CoxPt100–x nanoalloys have been synthesized by two different chemical processes either at high or at low temperature. Their physical properties and the order/disorder phase transition induced by annealing have been investigated depending on the route of synthesis. It is demonstrated that the chemical synthesis at high temperature allows stabilization of the fcc structure of the native nanoalloys while the soft chemical approach yields mainly poly or non crystalline structure. As a result the approach of the order/disorder phase transition is strongly modified as observed by high-resolution transmission electron microscopy (HR-TEM) studies performed during in situ annealing of the different nanoalloys.more » The control of the nanocrystallinity leads to significant decrease in the chemical ordering temperature as the ordered structure is observed at temperatures as low as 420 °C. Furthermore, this in turn preserves the individual nanocrystals and prevents their coalescence usually observed during the annealing necessary for the transition to an ordered phase.« less

  8. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H.

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  9. Hydrologic Behavior of Two Engineered Barriers Following Extreme Wetting

    SciTech Connect (OSTI)

    Porro, I.

    2000-09-30

    Many engineered barriers are expected to function for hundreds of years or longer. Over the course of time, it is likely that some barriers will experience infiltration to the point of breakthrough. This study compares the recovery from breakthrough of two storage- evapotranspiration type engineered barriers. Replicates of test plots comprising thick soil and capillary/biobarrier covers were wetted to breakthrough in 1997. Test plots were kept cleared of vegetation to maximize hydrologic stress during recovery. Following cessation of drainage resulting from the wetting irrigations, water storage levels in all plots were at elevated levels compared to pre-irrigation levels. As a result, infiltration of melting snow during the subsequent spring overloaded the storage capacity and produced drainage in all plots. Relatively rapid melting of accumulated snowfall produced the most significant infiltration events each year during the study. Capillary barriers yielded less total drainage than thick soil barriers. By limiting drainage, capillary barriers increased water storage in the upper portions of the test plots, which led to increased evaporation from the capillary barrier plots compared to thick soil plots. Increased evaporation in the capillary barrier plots allowed more water to infiltrate in the second season following the wetting tests without triggering drainage. All thick soil plots again yielded drainage in the second season. Within two years of intentionally induced breakthrough, evaporation alone (without transpiration) restored the capability of the capillary barrier covers to function as intended, although water storage in these covers remained at elevated levels.

  10. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T.

    2001-01-01

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  11. Analytical Chemistry Laboratory. Progress report for FY 1996

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1996-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1996. This annual report is the thirteenth for the ACL. It describes effort on continuing and new projects and contributions of the ACL staff to various programs at ANL. The ACL operates in the ANL system as a full-cost-recovery service center, but has a mission that includes a complementary research and development component: The Analytical Chemistry Laboratory will provide high-quality, cost-effective chemical analysis and related technical support to solve research problems of our clients -- Argonne National Laboratory, the Department of Energy, and others -- and will conduct world-class research and development in analytical chemistry and its applications. Because of the diversity of research and development work at ANL, the ACL handles a wide range of analytical chemistry problems. Some routine or standard analyses are done, but the ACL usually works with commercial laboratories if our clients require high-volume, production-type analyses. It is common for ANL programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. Thus, much of the support work done by the ACL is very similar to our applied analytical chemistry research.

  12. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  13. Wetting kinetics of water nano-droplet containing non-surfactant nanoparticles: A molecular dynamics study

    SciTech Connect (OSTI)

    Lu, Gui; Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, Pennsylvania 19104 ; Hu, Han; Sun, Ying E-mail: ysun@coe.drexel.edu; Duan, Yuanyuan E-mail: ysun@coe.drexel.edu

    2013-12-16

    In this Letter, dynamic wetting of water nano-droplets containing non-surfactant gold nanoparticles on a gold substrate is examined via molecular dynamics simulations. The results show that the addition of non-surfactant nanoparticles hinders the nano-second droplet wetting process, attributed to the increases in both surface tension of the nanofluid and friction between nanofluid and substrate. The droplet wetting kinetics decreases with increasing nanoparticle loading and water-particle interaction energy. The observed wetting suppression and the absence of nanoparticle ordering near the contact line of nano-sized droplets differ from the wetting behaviors reported from nanofluid droplets of micron size or larger.

  14. Cooperative Research in C1 Chemistry

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2000-10-27

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

  15. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues ...

  16. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2014-05-26

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOC) in the gas-phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the regional chemistry transport model WRF-Chem, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48% and 63% respectively over the continental US Dry deposition of gas-phasemore » SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40% vs. −8% for anthropogenics, −52% vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas-phase (61% for anthropogenics, 76% for biogenics). A number of sensitivity studies shows that this is a robust feature of the modeling system. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 25% / 10% compared to our best estimate. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations.« less

  17. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2015-01-06

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOCs) in the gas phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the WRF-Chem regional chemistry transport model, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48 and 63% respectively over the continental US. Dry deposition ofmore » gas-phase SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40 vs. −8% for anthropogenics, and −52 vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas phase (61% for anthropogenics and 76% for biogenics). Results are sensitive to assumptions made in the dry deposition scheme, but gas-phase deposition of SVOCs remains crucial even under conservative estimates. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = H* (CH3COOH); H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 35%/25%/10% compared to our best estimate.« less

  18. Development of Novel Front Contract Pastes for Crystalline Silicon Solar Cells

    SciTech Connect (OSTI)

    Duty, C.; Jellison, D. G.E. P.; Joshi, P.

    2012-04-05

    In order to improve the efficiencies of silicon solar cells, paste to silicon contact formation mechanisms must be more thoroughly understood as a function of paste chemistry, wafer properties and firing conditions. Ferro Corporation has been involved in paste development for over 30 years and has extensive expertise in glass and paste formulations. This project has focused on the characterization of the interface between the top contact material (silver paste) and the underlying silicon wafer. It is believed that the interface between the front contact silver and the silicon wafer plays a dominant role in the electrical performance of the solar cell. Development of an improved front contact microstructure depends on the paste chemistry, paste interaction with the SiNx, and silicon (Si) substrate, silicon sheet resistivity, and the firing profile. Typical front contact ink contains silver metal powders and flakes, glass powder and other inorganic additives suspended in an organic medium of resin and solvent. During fast firing cycles glass melts, wets, corrodes the SiNx layer, and then interacts with underlying Si. Glass chemistry is also a critical factor in the development of an optimum front contact microstructure. Over the course of this project, several fundamental characteristics of the Ag/Si interface were documented, including a higher-than-expected distribution of voids along the interface, which could significantly impact electrical conductivity. Several techniques were also investigated for the interfacial analysis, including STEM, EDS, FIB, EBSD, and ellipsometry.

  19. Appendix C Analytical Chemistry Data

    Office of Legacy Management (LM)

    Analytical Chemistry Data This page intentionally left blank Contents Section Analytical Data for Deleted Contaminants of Concern ............................................................. C1.O Mol~tezuma Creek Hardness Dat Surface Water Copper Data Summa ................ CI-9 Surface Water Radium-228 Dat Surface Water Radon-222 Data Summary ....................... ....................................... . . . . . . . . . . . C l - I 2 Alluvial Ground Water Aln~noniuu~ as Nitrogen Data

  20. Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016

  1. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are...

  2. Interfacial Chemistry and Engineering Annual Report 2000

    SciTech Connect (OSTI)

    Grate, Jay W.

    2001-08-01

    This annual report describes the research and staff accomplishments in 2000 for the EMSL Interfacial Chemistry and Engineering Directorate.

  3. Eleventh international symposium on radiopharmaceutical chemistry

    SciTech Connect (OSTI)

    1995-12-31

    This document contains abstracts of papers which were presented at the Eleventh International Symposium on Radiopharmaceutical Chemistry. Sessions included: radiopharmaceuticals for the dopaminergic system, strategies for the production and use of labelled reactive small molecules, radiopharmaceuticals for measuring metabolism, radiopharmaceuticals for the serotonin and sigma receptor systems, labelled probes for molecular biology applications, radiopharmaceuticals for receptor systems, radiopharmaceuticals utilizing coordination chemistry, radiolabelled antibodies, radiolabelling methods for small molecules, analytical techniques in radiopharmaceutical chemistry, and analytical techniques in radiopharmaceutical chemistry.

  4. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) building supports research and experimental activities for plutonium and uranium analytical chemistry and metallurgy. CMR capabilities support a number of national security programs, such as non-proliferation and nuclear safeguards. The CMR Facility In 1952, the first LANL CMR facility was completed. At that time, the

  5. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home » News & Publications » NERSC News » Center News » Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov Karplus605v1.jpg Martin Karplus On Wednesday, the Nobel Prize in Chemistry was awarded to three scientists for pioneering methods in computational chemistry that have brought a deeper understanding of complex chemical structure and reactions in biochemical systems. These methods

  6. HARNESSING THE CHEMISTRY OF CO2

    SciTech Connect (OSTI)

    Louie, Janis

    2010-05-11

    Our research program is broadly focused on activating CO{sub 2} through the use of organic and organometallic based catalysts. Some of our methods have centered on annulation reactions of unsaturated hydrocarbons (and carbonyl substrates) to provide a diverse array of carbocycles and heterocycles. We use a combination of catalyst discovery and optimization in conjunction with classical physical organic chemistry to elucidate the key mechanistic features of the cycloaddition reactions such that the next big advances in catalyst development can be made. Key to all of our cycloaddition reactions is the use of a sterically hindered, electron donating N heterocyclic carbene (NHC) ligand, namely IPr (or SIPr), in conjunction with a low valent nickel pre-catalyst. The efficacy of this ligand is two-fold: (1) the high {delta}-donating ability of the NHC increases the nucleophilicity of the metal center which thereby facilitates interaction with the electrophilic carbonyl and (2) the steric hindrance prevents an otherwise competitive side reaction involving only the alkyne substrate. Such a system has allowed for the facile cycloaddition to prepare highly functionalized pyrones, pyridones, pyrans, as well as novel carbocycles. Importantly, all reactions proceed under extremely mild conditions (room temperature, atmospheric pressures, and short reaction times), require only catalytic amounts of Ni/NHC and readily available starting materials, and afford annulated products in excellent yields. Our current focus revolves around understanding the fundamental processes that govern these cycloadditions such that the next big advance in the cyclization chemistry of CO{sub 2} can be made. Concurrent to our annulation chemistry is our investigation of the potential for imidazolylidenes to function as thermally-actuated CO{sub 2} sequestering and delivery agents.

  7. High performance computing in chemistry and massively parallel computers: A simple transition?

    SciTech Connect (OSTI)

    Kendall, R.A.

    1993-03-01

    A review of the various problems facing any software developer targeting massively parallel processing (MPP) systems is presented. Issues specific to computational chemistry application software will be also outlined. Computational chemistry software ported to and designed for the Intel Touchstone Delta Supercomputer will be discussed. Recommendations for future directions will also be made.

  8. Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,334 1980's 1,551 1,252 1,200 1,353 1,193 1,064 1,242 1,571 1,434 1,443 1990's 1,330 1,404 1,290 1,218 1,379 1,344 2,125 2,256 2,386 2,313 2000's 2,772 3,032 3,311 3,488 3,154 2,961 3,117 3,691 3,253 2,805 2010's 2,975 2,549 1,781 1,839 1,873 -

  9. 1986 wet deposition temporal and spatial patterns in North America

    SciTech Connect (OSTI)

    Olsen, A.R.

    1989-07-01

    The focus of this report is on North American wet deposition temporal patterns from 1979 to 1986 and spatial patterns for 1986. The report provides statistical distribution summaries of annual precipitation-weighted average concentration and annual deposition for nine ion species: hydrogen, sulfate, nitrate, ammonium, calcium, chloride, sodium, potassium, and magnesium. The data in the report are from the Acid Depositing System (ADS) for the statistical reporting of North American deposition data. Isopleth maps, based on surface estimation using kriging, display concentration and deposition spatial patterns of pH, hydrogen, sulfate, nitrate, ammonium, and calcium ion species for 1986 annual, winter, and summer periods. The temporal pattern analyses use a subset of 30 sites over an 8-year (1979-1986) period and an expanded subset of 137 sites with greater spatial coverage over a 5-year (1982-1986) period. The 8-year period represents the longest period with wet deposition monitoring data unavailable that has a sufficient number of sites with data of known quality to allow a descriptive summary of annual temporal patterns. 19 refs., 105 figs., 29 tabs.

  10. A preliminary assessment of beryllium dust oxidation during a wet bypass accident in a fusion reactor

    SciTech Connect (OSTI)

    Brad J. Merrill; Richard L. Moore; J. Phillip Sharp

    2008-09-01

    A beryllium dust oxidation model has been developed at the Idaho National Laboratory (INL) by the Fusion Safety Program (FSP) for the MELCOR safety computer code. The purpose of this model is to investigate hydrogen production from beryllium dust layers on hot surfaces inside a fusion reactor vacuum vessel (VV) during in-vessel loss-of-cooling accidents (LOCAs). This beryllium dust oxidation model accounts for the diffusion of steam into a beryllium dust layer, the oxidation of the dust particles inside this layer based on the beryllium-steam oxidation equations developed at the INL, and the effective thermal conductivity of this beryllium dust layer. This paper details this oxidation model and presents the results of the application of this model to a wet bypass accident scenario in the ITER device.

  11. HARNESSING THE CHEMISTRY OF CO{sub 2}

    SciTech Connect (OSTI)

    Louie, Janis

    2012-11-30

    Our research presents several strategies for addressing the challenges of activating CO2. In addition, our cycloaddition chemistry addresses several fundamental issues pertaining to catalysis as it applies to energy conservation. Topics addressed include: DEVELOPMENT OF A CYCLOADDITION CATALYST; INCREASING THE UTILITY OF THE NI CYCLOADDITION CATALYST; UNDERSTANDING THE MECHANISM OF NI-CATALYZED CYCLOADDITION; and METAL-FREE CO{sub 2} ACTIVATION.

  12. Final Report: Ionization chemistry of high temperature molecular...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACCURACY; CHEMICAL EXPLOSIVES; CHEMISTRY; EXPLOSIONS; ...

  13. Physical Chemistry and Applied Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PCS Physical Chemistry and Applied Spectroscopy We perform basic and applied research in support of the Laboratory's national security mission and serve a wide range of customers. Contact Us Group Leader Kirk Rector Deputy Group Leader Jeff Pietryga Group Office (505) 667-7121 Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in the Los Alamos National Laboratory optical laboratory. Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in

  14. Journal of Physical Chemistry A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physical Chemistry A - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  15. GAT-280 CHEMISTRY-GENERAL

    Office of Scientific and Technical Information (OSTI)

    GAT-280 CHEMISTRY-GENERAL 1 URANIUM HEXAFLUORIDE: A SURVEY O F THE PHYSICO-CHEMICAL PROPERTIES R. DeWitt Information and Records Subdivision August 1 2 , 1960 GOODYEAR ATOMIC CORPORATION Portsmouth, Ohio DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for

  16. UCRL-11359 UC-4 Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1359 UC-4 Chemistry TID-45 (27th Ed ) UNIVERSITY OF CALIFORNIA Lawrence Radiation Laboratory Berkeley, California AEC Contract No. W-7405-eng-48 PROPOSED MOLECULAR BEAM DETERMINATION OF ENERGY PARTITION IN THE PHOTO DISSOCIATION OF POLYATOMIC MOLECULES Richard N. Zare and Dudley R. Herschba.ch January 29, 1.964 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of

  17. Experimental evaluation of dry/wet air-cooled heat exchangers. Progress report

    SciTech Connect (OSTI)

    Hauser, S.G.; Gruel, R.L.; Huenefeld, J.C.; Eschbach, E.J.; Johnson, B.M.; Kreid, D.K.

    1982-08-01

    The ultimate goal of this project was to contribute to the development of improved cooling facilities for power plants. Specifically, the objective during FY-81 was to experimentally determine the thermal performance and operating characteristics of an air-cooled heat exchanger surface manufactured by the Unifin Company. The performance of the spiral-wound finned tube surface (Unifin) was compared with two inherently different platefin surfaces (one developed by the Trane Co. and the other developed by the HOETERV Institute) which were previously tested as a part of the same continuing program. Under dry operation the heat transfer per unit frontal area per unit inlet temperature difference (ITD) of the Unifin surface was 10% to 20% below that of the other two surfaces at low fan power levels. At high fan power levels, the performances of the Unifin and Trane surfaces were essentially the same, and 25% higher than the HOETERV surface. The design of the Unifin surface caused a significantly larger air-side pressure drop through the heat exchanger both in dry and deluge operation. Generally higher overall heat transfer coefficients were calculated for the Unifin surface under deluged operation. They ranged from 2.0 to 3.5 Btu/hr-ft/sup 2/-/sup 0/F as compared to less than 2.0 Btu hr-ft/sup 2/-/sup 0/F for the Trane and HOETERV surfaces under similar conditions. The heat transfer enhancement due to the evaporative cooling effect was also measureably higher with the Unifin surface as compared to the Trane surface. This can be primarily attributed to the better wetting characteristics of the Unifin surface. If the thermal performance of the surfaces are compared at equal face velocities, the Unifin surface is as much as 35% better. This method of comparison accounts for the wetting characteristics while neglecting the effect of pressure drop. Alternatively the surfaces when compared at equal pressure drop essentially the same thermal performance.

  18. Patterned functional arrays by selective de-wetting

    SciTech Connect (OSTI)

    FAN,HONGYOU; DOSHI,DHAVAL; LU,YUNFENG; BRINKER,C. JEFFREY

    2000-05-11

    Using a micro-Contact Printing ({mu}-CP) technique, substrates are prepared with patterns of hydrophilic, hydroxyl-terminated SAMS and hydrophobic methyl-terminated SAMS. Beginning with a homogeneous solution of silica, surfactant, ethanol, water, and functional silane, preferential ethanol evaporation during dip-coating, causes water enrichment and selective de-wetting of the hydrophobic SAMS. Correspondingly, film deposition occurs exclusively on the patterned hydrophilic SAMS. In addition, by co-condensation of tetrafunctional silanes (Si(OR){sub 4}) with tri-functional organosilanes ((RO){sub 3}Si(CH{sub 2}){sub 3}NH{sub 2}), the authors have selectively derived the silica framework with functional amine NH{sub 2} groups. A pH sensitive, micro-fluidic system was formed by further conjugation reactions with pH sensitive dye molecules.

  19. Wet chemical thinning of molybdenum disulfide down to its monolayer

    SciTech Connect (OSTI)

    Amara, Kiran Kumar; Chu, Leiqiang; Kumar, Rajeev; Toh, Minglin; Eda, Goki

    2014-09-01

    We report on the preparation of mono- and bi-layer molybdenum disulfide (MoS{sub 2}) from a bulk crystal by facile wet chemical etching. We show that concentrated nitric acid (HNO{sub 3}) effectively etches thin MoS{sub 2} crystals from their edges via formation of MoO{sub 3}. Interestingly, etching of thin crystals on a substrate leaves behind unreacted mono- and bilayer sheets. The flakes obtained by chemical etching exhibit electronic quality comparable to that of mechanically exfoliated counterparts. Our findings indicate that the self-limiting chemical etching is a promising top-down route to preparing atomically thin crystals from bulk layer compounds.

  20. Crude Oil and Lease Condensate Wet Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. proved reserves, and reserves changes, 2013-2014 Crude Oil and Lease Condensate Wet Natural Gas billion barrels trillion cubic feet U.S. proved reserves at December 31, 2013 36.5 354.0 Total discoveries 5.4 50.5 Net revisions 0.4 1.0 Net Adjustments, Sales, Acquisitions 0.8 11.5 Production -3.2 -28.1 Net additions to U.S. proved reserves 3.4 34.8 U.S. proved reserves at December 31, 2014 39.9 388.8 Percent change in U.S. proved reserves 9.3% 9.8% Percent change calculated from unrounded

  1. Wet oxidation of high-concentration reactive dyes

    SciTech Connect (OSTI)

    Chen, G.; Lei, L.; Yue, P.L.

    1999-05-01

    Advanced oxidation methods were used to degrade reactive dyes at high concentrations in aqueous solutions. Wet peroxide oxidation (WPO) was found to be the best method in terms of the removal of color and total organic carbon (TOC). Reactive blue (Basilen Brilliant Blue P-3R) was chosen as a model dye for determining the suitable reaction conditions. The variables studied include reaction temperature, H{sub 2}O{sub 2} dosage, solution pH, dye concentration, and catalyst usage. The removal of TOC and color by wet oxidation is very sensitive to the reaction temperature. At 150 C, the removal of 77% TOC and 90% color was obtained in less than 30 min. The initial TOC removal rate is proportional to the H{sub 2}O{sub 2} dosage. The TOC removal is insignificant even when 50% of the stoichiometric amount of H{sub 2}O{sub 2} is used. No color change is observed until the dosage of H{sub 2}O{sub 2} is 100% of the stoichiometric amount. The color removal is closely related to TOC removal. When the pH of the solution is adjusted to 3.5, the dye degradation rate increases significantly. The rates of TOC and color removal are enhanced by using a Cu{sup 2+} catalyst. Another four reactive dyes, Procion Red PX-4B, Cibacron Yellow P-6GS, Cibacron Brown P-6R, and Procion Black PX-2R, were treated at 150 C using WPO. More than 80% TOC was removed from the solution in less than 15 min. The process can remove the colors of al these dyes except Procion Black PX-2R.

  2. WPN 97-6: Approval of Wet-Spray Cellulose Insulation as an Allowable Weatherization Material

    Broader source: Energy.gov [DOE]

    To provide states with information about the approved use of wet-spray cellulose for use in the low-income Weatherization Assistance Program.

  3. MHK Projects/US Navy Wave Energy Technology WET Program at Marine...

    Open Energy Info (EERE)

    US Navy Wave Energy Technology WET Program at Marine Corps Base Hawaii MCBH < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map......

  4. Nuclear Science/Nuclear Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Science/Nuclear Chemistry Nuclear Physics The 10-MV tandem accelerator at CAMS provides a platform for conducting nuclear physics experiment both for basic science and lab mission-related programs. For example, we performed a new cross section measurement of the astrophysically important reaction 40Ca(a,g)44Ti in which high purity CaO targets were irradiated with helium ions at several different discrete energies. The reaction rate was measured on-line via prompt gamma ray spectroscopy

  5. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  6. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  7. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  8. Appendix SOTERM: Actinide Chemistry Source Term

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SOTERM-2014 Actinide Chemistry Source Term United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix SOTERM-2014 Actinide Chemistry Source Term Table of Contents SOTERM-1.0 Introduction SOTERM-2.0 Expected WIPP Repository Conditions, Chemistry, and Processes SOTERM-2.1 Ambient Geochemical Conditions SOTERM-2.2 Repository Conditions SOTERM-2.2.1 Repository Pressure SOTERM-2.2.2 Repository

  9. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Screening of Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrodes Vehicle Technologies Office Merit Review 2015: Materials Benchmarking Activities for ...

  10. Nanostructure, Chemistry and Crystallography of Iron Nitride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy and Related Methods Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related ...

  11. 2005 American Conference on Theoretical Chemistry

    SciTech Connect (OSTI)

    Carter, Emily A

    2006-11-19

    The materials uploaded are meant to serve as final report on the funds provided by DOE-BES to help sponsor the 2005 American Conference on Theoretical Chemistry.

  12. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 Last edited: 2016-04-29 11:34:4

  13. Symposium on high temperature and materials chemistry

    SciTech Connect (OSTI)

    Not Available

    1989-10-01

    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  14. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 L ast edited: 2015-12-11 16:11:02...

  15. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce...

  16. understanding the low-temperature combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-temperature combustion chemistry - Sandia Energy Energy Search Icon Sandia Home ... EnergyWater History Water Monitoring & Treatment Technology Decision Models for ...

  17. Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment

    SciTech Connect (OSTI)

    Neu, M.P.

    1993-11-01

    The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

  18. Chemistry and Processing of Nanostructured Materials

    SciTech Connect (OSTI)

    Fox, G A; Baumann, T F; Hope-Weeks, L J; Vance, A L

    2002-01-18

    Nanostructured materials can be formed through the sol-gel polymerization of inorganic or organic monomer systems. For example, a two step polymerization of tetramethoxysilane (TMOS) was developed such that silica aerogels with densities as low as 3 kg/m{sup 3} ({approx} two times the density of air) could be achieved. Organic aerogels based upon resorcinol-formaldehyde and melamine-formaldehyde can also be prepared using the sol-gel process. Materials of this type have received significant attention at LLNL due to their ultrafine cell sizes, continuous porosity, high surface area and low mass density. For both types of aerogels, sol-gel polymerization depends upon the transformation of these monomers into nanometer-sized clusters followed by cross-linking into a 3-dimensional gel network. While sol-gel chemistry provides the opportunity to synthesize new material compositions, it suffers from the inability to separate the process of cluster formation from gelation. This limitation results in structural deficiencies in the gel that impact the physical properties of the aerogel, xerogel or nanocomposite. In order to control the properties of the resultant gel, one should be able to regulate the formation of the clusters and their subsequent cross-linking. Towards this goal, we are utilizing dendrimer chemistry to separate the cluster formation from the gelation so that new nanostructured materials can be produced. Dendrimers are three-dimensional, highly branched macromolecules that are prepared in such a way that their size, shape and surface functionality are readily controlled. The dendrimers will be used as pre-formed clusters of known size that can be cross-linked to form an ordered gel network.

  19. Chemistry: Theory - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theory Chemistry: Theory Presentations from 2010 CEFRC First Annual Conference MultireferenceCorrelated WavefunctionCalculations and Reaction Flux Analyses of Methyl Ester Combustion Emily A. Carter, Princeton University Constructing Accurate Combustion Chemistry Models William H. Green, MIT Theoretical Gas Phase Chemical Kinetics Stephen J. Klippenstein, Argonne National Laboratory Theoretical Chemical Kinetics and Combustion Modeling James A. Miller, Argonne National Laboratory Computation of

  20. Radiation chemistry in solvent extraction: FY2010 Research

    SciTech Connect (OSTI)

    Bruce J. Mincher; Leigh R. Martin; Stephen P. Mezyk

    2010-09-01

    This report summarizes work accomplished under the Fuel Cycle Research and Development (FCR&D) program in the area of radiation chemistry during FY 2010. The tasks assigned during FY 2010 included: Development of techniques to measure free radical reaction kinetics in the organic phase. Initiation of an alpha-radiolysis program Initiation of an effort to understand dose rate effects in radiation chemistry Continued work to characterize TALSPEAK radiation chemistry Progress made on each of these tasks is reported here. Briefly, a method was developed and used to measure the kinetics of the reactions of the NO3 radical with solvent extraction ligands in organic solution, and the method to measure OH radical reactions under the same conditions has been designed. Rate constants for the CMPO and DMDOHEMA reaction with NO3 radical in organic solution are reported. Alpha-radiolysis was initiated on samples of DMDOHEMA in alkane solution using He ion beam irradiation and 211At isotope irradiation. The samples are currently being analyzed for comparison to DMDOHEMA ?-irradiations using a custom-developed mass spectrometric method. Results are also reported for the radiolytic generation of nitrous acid, in ?-irradiated nitric acid. It is shown that the yield of nitrous acid is unaffected by an order-of-magnitude change in dose rate. Finally, recent results for TALSPEAK radiolysis are reported, summarizing the effects on solvent extraction efficiency due to HDEHP irradiation, and the stable products of lactic acid and DTPA irradiation. In addition, results representing increased scope are presented for the radiation chemistry program. These include an investigation of the effect of metal complexation on radical reaction kinetics using DTPA as an example, and the production of a manuscript reporting the mechanism of Cs-7SB radiolysis. The Cs-7SB work takes advantage of recent results from a current LDRD program to understand the fundamental chemistry of nitration under radiolysis conditions. Finally, work toward understanding the chemistry of irradiated formic acid is presented. This is important because all organic compounds eventually produce formic acid under long-term irradiation.

  1. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, J.A.

    1997-08-26

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for (1) cleaning, developing or etching, (2) rinsing, and (3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material. 5 figs.

  2. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, Jerald A. (Oakley, CA)

    1997-01-01

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for 1) cleaning, developing or etching, 2) rinsing, and 3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material.

  3. Archaeopteryx Feathers and Bone Chemistry Fully Revealed via Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Archaeopteryx Feathers and Bone Chemistry Fully Revealed via Synchrotron Imaging Archaeopteryx specimens are important but extremely rare fossils. Due to their possession of both reptilian (jaws with teeth, long bony tail) and avian (feathered wings) characters, Archaeopteryx has been crucial in the development of Darwinian evolution. Despite their importance, no Archaeopteryx specimen has ever been chemically analyzed. This in large part may be explained by the analytical obstacles

  4. Pentavalent Uranium Chemistry - Synthetic Pursuit Of A Rare Oxidation State

    SciTech Connect (OSTI)

    Graves, Christopher R; Kiplinger, Jaqueline L

    2009-01-01

    This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.

  5. Radiation chemistry in solvent etxraction: FY2011 research

    SciTech Connect (OSTI)

    Bruce J. Mincher; Stephen P. Mezyk; Leigh R. Martin

    2011-09-01

    This report summarizes work accomplished under the Fuel Cycle Research and Development (FCR&D) program in the area of radiation chemistry during FY 2011. The tasks assigned during FY 2011 included: (1) Continue measurements free radical reaction kinetics in the organic phase; (2) Continue development of an alpha-radiolysis program and compare alpha and gamma radiolysis for CMPO; (3) Initiate an effort to understand dose rate effects in radiation chemistry; and (4) Continued work to characterize TALSPEAK radiation chemistry, including the examination of metal complexed ligand kinetics. Progress made on each of these tasks is reported here. Briefly, the method developed to measure the kinetics of the reactions of the NO3 radical with solvent extraction ligands in organic solution during FY10 was extended here to a number of compounds to better understand the differences between radical reactions in the organic versus aqueous phases. The alpha-radiolysis program in FY11 included irradiations of CMPO solutions with 244Cm, 211At and the He ion beam, for comparison to gamma irradiations, and a comparison of the gamma irradiation results for CMPO at three different gamma dose rates. Finally, recent results for TALSPEAK radiolysis are reported, summarizing the latest in an effort to understand how metal complexation to ligands affects their reaction kinetics with free radicals.

  6. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal-Derived Liquids to Enable HCCI Technology Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing ...

  7. Plastic Bags to Batteries: A Green Chemistry Solution | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastic Bags to Batteries: A Green Chemistry Solution Share Description Plastic bags are the scourge of roadsides, parking lots and landfills. But chemistry comes to the rescue At...

  8. Low-Temperature Combustion Chemistry of Biofuels: Pathways in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Low-Temperature Combustion Chemistry of Biofuels: Pathways in the Initial Low-Temperature (550 K - 750 K) Oxidation Chemistry of Isopentanol. Citation Details ...

  9. Impact of small changes in particle surface chemistry for unentangled...

    Office of Scientific and Technical Information (OSTI)

    particle surface chemistry for unentangled polymer nanocomposites Citation Details In-Document Search Title: Impact of small changes in particle surface chemistry for unentangled ...

  10. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED...

    Office of Scientific and Technical Information (OSTI)

    AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE ... Title: AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND ...

  11. July 2013 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    July 2013 Most Viewed Documents for Chemistry Science Subject Feed Lithium literature ... Grandy, J. (1997) 35 > Background chemistry for chemical warfare agents and ...

  12. March 2014 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    4 Most Viewed Documents for Chemistry Science Subject Feed Flammability characteristics of ... Richards, P. (1989) 19 > Background chemistry for chemical warfare agents and ...

  13. Electrophilic Metal Alkyl Chemistry in New Ligand Environments...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Electrophilic Metal Alkyl Chemistry in New Ligand Environments Citation Details In-Document Search Title: Electrophilic Metal Alkyl Chemistry in New Ligand ...

  14. Most Viewed Documents - Chemistry | OSTI, US Dept of Energy,...

    Office of Scientific and Technical Information (OSTI)

    - Chemistry Flammability characteristics of combustible gases and vapors. 249 refs ... Electrophoresis Wenjun Xi (2008) Chemistry of americium Schulz, W.W. (1976) ...

  15. Private Company Uses EERE-Supported Chemistry Model to Substantially...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Private Company Uses EERE-Supported Chemistry Model to Substantially Improve Combustion Engine Simulation Software Private Company Uses EERE-Supported Chemistry Model to ...

  16. Bridging the Gap between Fundamental Physics and Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI ...

  17. Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control...

    Office of Scientific and Technical Information (OSTI)

    Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, ... guide to allow anyone to learn the fundamentals of chemistry, engineering, and safety ...

  18. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry published a special Forum issue on the ... fuel enrichment); the "service period" when the fuel ...

  19. Final Report: Ionization chemistry of high temperature molecular...

    Office of Scientific and Technical Information (OSTI)

    Final Report: Ionization chemistry of high temperature molecular fluids Citation Details In-Document Search Title: Final Report: Ionization chemistry of high temperature molecular ...

  20. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    State University Alavi, Ali (Ali Alavi) - Department of Chemistry, University of Cambridge Allen, Heather C.(Heather C.Allen).- Department of Chemistry, Ohio State University ...

  1. NERSC training events: Data Transfer and Archiving; Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences...

  2. Chemistry, phase formation, and catalytic activity of thinpalladium...

    Office of Scientific and Technical Information (OSTI)

    Title: Chemistry, phase formation, and catalytic activity of thin palladium-containing oxide films synthesized by plasma-assisted physical vapor deposition The chemistry, ...

  3. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    ... E.Smalley).- Departments of Chemistry & Physics, Rice University Smith III, Milton R (Milton R Smith III) - Department of Chemistry, Michigan State University Smith, Arthur ...

  4. New Chemistries Found for Liquid Batteries: Grid-scale approach...

    Office of Environmental Management (EM)

    New Chemistries Found for Liquid Batteries: Grid-scale approach to rechargeable power storage gets new arsenal of possible materials New Chemistries Found for Liquid Batteries: ...

  5. Coagulation chemistries for silica removal from cooling tower...

    Office of Scientific and Technical Information (OSTI)

    Coagulation chemistries for silica removal from cooling tower water. Citation Details In-Document Search Title: Coagulation chemistries for silica removal from cooling tower water. ...

  6. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces New Technique Gives a Deeper Look into the Chemistry of Interfaces Print Monday, 23 February 2015 10:48 A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with

  7. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO

    Office of Scientific and Technical Information (OSTI)

    PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT (Conference) | SciTech Connect AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT Citation Details In-Document Search Title: AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT One factor limiting the development of

  8. Reaction chemistry of nitrogen species in hydrothermal systems: Simple reactions, waste simulants, and actual wastes

    SciTech Connect (OSTI)

    Dell`Orco, P.; Luan, L.; Proesmans, P.; Wilmanns, E.

    1995-02-01

    Results are presented from hydrothermal reaction systems containing organic components, nitrogen components, and an oxidant. Reaction chemistry observed in simple systems and in simple waste simulants is used to develop a model which presents global nitrogen chemistry in these reactive systems. The global reaction path suggested is then compared with results obtained for the treatment of an actual waste stream containing only C-N-0-H species.

  9. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1990-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  10. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1989-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  11. Plasma chemistry in wire chambers

    SciTech Connect (OSTI)

    Wise, J.

    1990-05-01

    The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to remove trace water and oxygen contaminants from the gas resulted in an increase in the average molecular weight of the products, consistent with results from low-pressure rf-discharge plasmas. It is suggested that because water and oxygen inhibit polymer growth in the gas phase that they may also reduce polymer deposition in proportional tubes and therefore retard wire aging processes. Mechanistic implications of the plasma reactions of hydrocarbons with oxygen are suggested. Unresolved issues in this work and proposals for further study are discussed.

  12. CRYSTAL CHEMISTRY OF HYDROUS MINERALS

    SciTech Connect (OSTI)

    Y. ZHAO; ET AL

    2001-02-01

    Hydrogen has long been appreciated for its role in geological processes of the Earth's crust. However, its role in Earth's deep interior has been neglected in most geophysical thinking. Yet it is now believed that most of our planet's hydrogen may be locked up in high pressure phases of hydrous silicate minerals within the Earth's mantle. This rocky interior (approximately 7/8 of Earth's volume) is conjectured to contain 1-2 orders of magnitude more water than the more obvious oceans (the ''hydrosphere'') and atmosphere. This project is aimed at using the capability of neutron scattering from hydrogen to study the crystal chemistry and stability of hydrogen-bearing minerals at high pressures and temperatures. At the most basic level this is a study of the atomic position and hydrogen bond itself. We have conducted experimental runs on hydrous minerals under high pressure and high temperature conditions. The crystallographic structure of hydrous minerals at extreme conditions and its structural stability, and hydrogen bond at high P-T conditions are the fundamental questions to be addressed. The behavior of the hydrous minerals in the deep interior of the Earth has been discussed.

  13. COOPERATIVE RESEARCH IN C1 CHEMISTRY

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2001-04-30

    Faculty and students from five universities (Kentucky, West Virginia, Utah, Pittsburgh and Auburn) are collaborating on a basic research program to develop novel C1 chemistry processes for the production of clean, high quality transportation fuel. An Industrial Advisory Board (IAB) with members from Chevron, Eastman Chemical, Energy International, Teir Associates, and the Department of Defense has been formed to provide practical guidance to the program. The program has two principal objectives. (1) Develop technology for conversion of C1 source materials (natural gas, synthesis gas, carbon dioxide and monoxide, and methanol) into clean, high efficiency transportation fuel. (2) Develop novel processes for producing hydrogen from natural gas and other hydrocarbons. Some of the principal accomplishments of the program in its first two years are: (1) The addition of acetylenic compounds in Fischer-Tropsch synthesis is found to produce significant amounts of oxygenated products in FT diesel fuels. Such oxygenated products should decrease particulate matter (PM) emissions. (2) Nanoscale, binary, Fe-based catalysts supported on alumina have been shown to have significant activity for the decomposition of methane into pure hydrogen and potentially valuable multi-walled carbon nanotubes. (3) Catalytic synthesis processes have been developed for synthesis of diethyl carbonate, higher ethers, and higher alcohols from C1 source materials. Testing of the effect of adding these oxygenates to diesel fuel on PM emissions has begun using a well-equipped small diesel engine test facility. (4) Supercritical fluid (SCF) FT synthesis has been conducted under SCF hexane using both Fe and Co catalysts. There is a marked effect on the hydrocarbon product distribution, with a shift to higher carbon number products. These and other results are summarized.

  14. Modification of heterogeneous chemistry by complex substrate morphology

    SciTech Connect (OSTI)

    Henson, B.F.; Buelow, S.J.; Robinson, J.M.

    1998-12-31

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Chemistry in many environmental systems is determined at some stage by heterogeneous reaction with a surface. Typically the surface exists as a dispersion or matrix of particulate matter or pores, and a determination of the heterogeneous chemistry of the system must address the extent to which the complexity of the environmental surface affects the reaction rates. Reactions that are of current interest are the series of chlorine nitrate reactions important in polar ozone depletion. The authors have applied surface spectroscopic techniques developed at LANL to address the chemistry of chlorine nitrate reactions on porous nitric and sulfuric acid ice surfaces as a model study of the measurement of complex, heterogeneous reaction rates. The result of the study is an experimental determination of the surface coverage of one adsorbed reagent and a mechanism of reactivity based on the dependence of this coverage on temperature and vapor pressure. The resulting mechanism allows the first comprehensive modeling of chlorine nitrate reaction probability data from several laboratories.

  15. A filtered tabulated chemistry model for LES of premixed combustion

    SciTech Connect (OSTI)

    Fiorina, B.; Auzillon, P.; Darabiha, N.; Gicquel, O.; Veynante, D. [EM2C - CNRS, Ecole Centrale Paris, 92295 Chatenay Malabry (France); Vicquelin, R. [EM2C - CNRS, Ecole Centrale Paris, 92295 Chatenay Malabry (France); GDF SUEZ, Pole CHENE, Centre de Recherche et d'Innovation Gaz et Energies Nouvelles, 93211 Saint-Denis la Plaine (France)

    2010-03-15

    A new modeling strategy called F-TACLES (Filtered Tabulated Chemistry for Large Eddy Simulation) is developed to introduce tabulated chemistry methods in Large Eddy Simulation (LES) of turbulent premixed combustion. The objective is to recover the correct laminar flame propagation speed of the filtered flame front when subgrid scale turbulence vanishes as LES should tend toward Direct Numerical Simulation (DNS). The filtered flame structure is mapped using 1-D filtered laminar premixed flames. Closure of the filtered progress variable and the energy balance equations are carefully addressed in a fully compressible formulation. The methodology is first applied to 1-D filtered laminar flames, showing the ability of the model to recover the laminar flame speed and the correct chemical structure when the flame wrinkling is completely resolved. The model is then extended to turbulent combustion regimes by including subgrid scale wrinkling effects in the flame front propagation. Finally, preliminary tests of LES in a 3-D turbulent premixed flame are performed. (author)

  16. Analytical Chemistry Laboratory progress report for FY 1984

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Jensen, K.J.; Stetter, J.R.

    1985-03-01

    Technical and administrative activities of the Analytical Chemistry Laboratory (ACL) are reported for fiscal year 1984. The ACL is a full-cost-recovery service center, with the primary mission of providing a broad range of technical support services to the scientific and engineering programs at ANL. In addition, ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL is administratively within the Chemical Technology Division, the principal user, but provides technical support for all of the technical divisions and programs at ANL. The ACL has three technical groups - Chemical Analysis, Instrumental Analysis, and Organic Analysis. Under technical activities 26 projects are briefly described. Under professional activities, a list is presented for publications and reports, oral presentations, awards and meetings attended. 6 figs., 2 tabs.

  17. Safety Aspects of Wet Storage of Spent Nuclear Fuel, OAS-L-13-11

    Energy Savers [EERE]

    Safety Aspects of Wet Storage of Spent Nuclear Fuel OAS-L-13-11 July 2013 Department of Energy Washington, DC 20585 July 10, 2013 MEMORANDUM FOR THE SENIOR ADVISOR FOR ENVIRONMENTAL MANAGEMENT FROM: Daniel M. Weeber Assistant Inspector General for Audits and Administration Office of Inspector General SUBJECT: INFORMATION: Audit Report on "Safety Aspects of Wet Storage of Spent Nuclear Fuel" BACKGROUND The Department of Energy (Department) is responsible for managing and storing spent

  18. ChemCam follows the 'Yellowknife Road' to Martian wet area

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Yellowknife Road' to martian wet area ChemCam follows the 'Yellowknife Road' to martian wet area Researchers have tracked a trail of minerals that point to the prior presence of water at the Curiosity rover site on Mars. January 15, 2013 The Mars Science Laboratory's Curiosity Rover recently took this photo of the Martian landscape looking toward Mount Sharp while on its way toward Yellowknife Bay-an area where researchers have found minerals indicating the past presence of water. (NASA Photo)

  19. Perspective: Water cluster mediated atmospheric chemistry

    SciTech Connect (OSTI)

    Vaida, Veronica

    2011-07-14

    The importance of water in atmospheric and environmental chemistry initiated recent studies with results documenting catalysis, suppression and anti-catalysis of thermal and photochemical reactions due to hydrogen bonding of reagents with water. Water, even one water molecule in binary complexes, has been shown by quantum chemistry to stabilize the transition state and lower its energy. However, new results underscore the need to evaluate the relative competing rates between reaction and dissipation to elucidate the role of water in chemistry. Water clusters have been used successfully as models for reactions in gas-phase, in aqueous condensed phases and at aqueous surfaces. Opportunities for experimental and theoretical chemical physics to make fundamental new discoveries abound. Work in this field is timely given the importance of water in atmospheric and environmental chemistry.

  20. NREL: Transportation Research - Fuel Chemistry Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photo by Dennis Schroeder, NREL NREL's fuel chemistry research explores how biofuels, advanced petroleum-based fuels, fuel blends, and natural gas perform in vehicles as well as in ...

  1. Chemistry Division annual progress report for period ending January 31, 1984

    SciTech Connect (OSTI)

    Not Available

    1984-05-01

    Progress is reported in the following fields: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, high-temperature chemistry and thermodynamics of structural materials, chemistry of transuranium elements and compounds, separations chemistry, elecrochemistry, catalysis, chemical physics, theoretical chemistry, nuclear waste chemistry, chemistry of hazardous chemicals, and thermal energy storage.

  2. Hiking the valleys of quatum chemistry

    SciTech Connect (OSTI)

    Aikens, Christine Marie

    2005-08-01

    This thesis is concerned with both the application and the extension of quantum chemical methods. Each chapter of the thesis represents a paper that has been published in or will be submitted to a scientific journal. The first three chapters of this thesis describe contributions made to chemistry through the use of quantum chemical methods, while the final two chapters illustrate the development of new methods. Chapter 2 and Chapter 3 characterize a study of the electronic structure and magnetic properties of homodinuclear titanium(III) complexes, in order to determine trends related to their potential use as molecular magnets. Chapter 2 focuses on hydride and halide bridging and terminal ligands, while Chapter 3 explores bridging ligands from other groups in the periodic table. Chapter 4 portrays a study of the solvation of glycine. Microsolvation and continuum solvation approaches are investigated in order to study the structures of small glycine-water clusters and determine the energy difference between the zwitterionic and nonionized forms of glycine, the simplest amino acid. Chapters 5 and 6 describe the implementation of analytic gradients, which are required for efficient molecular geometry optimizations, for two open-shell second-order perturbation theory methods. Chapter 5 discusses gradients for unrestricted Moeller-Plesset perturbation theory, and Chapter 6 describes gradients for Z-averaged perturbation theory.

  3. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of

  4. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J.

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  5. Chemistry Impacts in Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P; Bunting, Bruce G

    2006-09-01

    The use of homogeneous charge compression ignition (HCCI) combustion in internal combustion engines is of interest because it has the potential to produce low oxides of nitrogen (NOx) and particulate matter (PM) emissions while providing diesel-like efficiency. In HCCI combustion, a premixed charge of fuel and air auto-ignites at multiple points in the cylinder near top dead center (TDC), resulting in rapid combustion with very little flame propagation. In order to prevent excessive knocking during HCCI combustion, it must take place in a dilute environment, resulting from either operating fuel lean or providing high levels of either internal or external exhaust gas recirculation (EGR). Operating the engine in a dilute environment can substantially reduce the pumping losses, thus providing the main efficiency advantage compared to spark-ignition (SI) engines. Low NOx and PM emissions have been reported by virtually all researchers for operation under HCCI conditions. The precise emissions can vary depending on how well mixed the intake charge is, the fuel used, and the phasing of the HCCI combustion event; but it is common for there to be no measurable PM emissions and NOx emissions <10 ppm. Much of the early HCCI work was done on 2-stroke engines, and in these studies the CO and hydrocarbon emissions were reported to decrease [1]. However, in modern 4-stroke engines, the CO and hydrocarbon emissions from HCCI usually represent a marked increase compared with conventional SI combustion. This literature review does not report on HCCI emissions because the trends mentioned above are well established in the literature. The main focus of this literature review is the auto-ignition performance of gasoline-type fuels. It follows that this discussion relies heavily on the extensive information available about gasoline auto-ignition from studying knock in SI engines. Section 2 discusses hydrocarbon auto-ignition, the octane number scale, the chemistry behind it, its shortcomings, and its relevance to HCCI. Section 3 discusses the effects of fuel volatility on fuel and air mixing and the consequences it has on HCCI. The effects of alcohol fuels on HCCI performance, and specifically the effects that they have on the operable speed/load range, are reviewed in Section 4. Finally, conclusions are drawn in Section 5.

  6. Development of a two-body wet abrasion test method with attention...

    Office of Scientific and Technical Information (OSTI)

    SiC grinding papers were used under fixed load and speed to rank the abrasive wear of seven alloy steels, some of which are candidates for drill cones for geothermal drilling. ...

  7. User's guide for the BNW-III optimization code for modular dry/wet-cooled power plants

    SciTech Connect (OSTI)

    Braun, D.J.; Faletti, D.W.

    1984-09-01

    This user's guide describes BNW-III, a computer code developed by the Pacific Northwest Laboratory (PNL) as part of the Dry Cooling Enhancement Program sponsored by the US Department of Energy (DOE). The BNW-III code models a modular dry/wet cooling system for a nuclear or fossil fuel power plant. The purpose of this guide is to give the code user a brief description of what the BNW-III code is and how to use it. It describes the cooling system being modeled and the various models used. A detailed description of code input and code output is also included. The BNW-III code was developed to analyze a specific cooling system layout. However, there is a large degree of freedom in the type of cooling modules that can be selected and in the performance of those modules. The costs of the modules are input to the code, giving the user a great deal of flexibility.

  8. Advanced fuel chemistry for advanced engines.

    SciTech Connect (OSTI)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  9. Structure, chemistry, and properties of mineral nanoparticles

    SciTech Connect (OSTI)

    Waychunas, G.A.; Zhang, H.; Gilbert, B.

    2008-12-02

    Nanoparticle properties can depart markedly from their bulk analog materials, including large differences in chemical reactivity, molecular and electronic structure, and mechanical behavior. The greatest changes are expected at the smallest sizes, e.g. 10 nm and below, where surface effects are expected to dominate bonding, shape and energy considerations. The precise chemistry at nanoparticle interfaces can have a profound effect on structure, phase transformations, strain, and reactivity. Certain phases may exist only as nanoparticles, requiring transformations in chemistry, stoichiometry and structure with evolution to larger sizes. In general, mineralogical nanoparticles have been little studied.

  10. New York Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New York Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 211 1980's 208 264 229 295 389 369 457 410 351 368 1990's 354 331 329 264 242 197 232 224 218 221 2000's 322 318 315 365 324 349 363 375 389 196 2010's 281 253 184 144 143 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  11. North Dakota Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) North Dakota Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 201 1980's 239 253 248 257 267 331 293 276 266 313 1990's 334 243 266 274 275 263 255 257 261 250 2000's 264 270 315 316 320 343 357 417 484 1,070 2010's 1,717

  12. Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Ohio Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,047 1980's 1,417 800 984 1,635 1,178 938 898 594 480 589 1990's 371 376 381 343 315 355 399 391 342 402 2000's 469 340 346 304 208 184 174 101 99 97 2010's 90 74 223 314 208 - =

  13. Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana - South Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,304 1980's 2,134 1,871 1,789 1,582 1,488 1,792 1,573 1,380 1,338 1,273 1990's 1,106 995 853 649 678 720 627 599 630 599

  14. Louisiana State Offshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Louisiana State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 449 251 260 207 231 1990's 207 207 154 157 168 148 157 130 98 120 2000's 129 145 84 79 61 63 56 65 686 513 2010's 107 51 128 88 68 - = No

  15. New Mexico - West Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) West Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - West Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 151 1980's 156 150 146 180 194 181 214 213 259 178 1990's 184 156 127 107 97 119 108 106 98 92 2000's 115 99 103 89 90 98 82 87 86 82 2010's

  16. New York Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New York Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 0 1980's 0 2 3 0 2 2 0 0 0 4 1990's 0 0 0 0 2 2 3 1 1 9 2000's 2 7 0 0 0 3 2 10 29 0 2010's 10 8 6 6 5 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  17. California State Offshore Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) California State Offshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 226 1980's 160 244 232 221 206 1990's 188 55 59 63 59 56 47 54 39 58 2000's 86 80 85 76 85 89 85 79 54 53 2010's 63 79 65 75 76 - = No Data

  18. Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Kansas Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 167 1980's 185 139 112 132 110 115 132 115 103 101 1990's 114 115 94 93 75 67 82 51 60 52 2000's 40 105 66 85 80 83 82 83 85 83 2010's 79 127 326 433 657 - = No Data Reported;

  19. ,"Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Michigan Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  20. ,"Mississippi Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Mississippi Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  1. ,"Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Montana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  2. ,"Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  3. ,"Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  4. ,"Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  5. ,"Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  6. ,"U.S. Natural Gas Proved Reserves, Wet After Lease Separation"

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves, Wet After Lease Separation" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Natural Gas Proved Reserves, Wet After Lease Separation",10,"Annual",2014,"6/30/1979" ,"Release Date:","11/19/2015" ,"Next Release Date:","12/31/2016" ,"Excel File

  7. ,"Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  8. Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 1 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 209 1980's 172 180 216 175 170 260 241 205 204 251 1990's 333 401 361 191 151 248 446 68 51 67 2000's 69 43 47 48 45 57 61 72 60 67 2010's 267

  9. Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 0 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 484 1980's 546 456 489 537 617 560 537 482 424 364 1990's 311 298 396 264 264 254 253 227 234 241 2000's 289 255 271 252 249 253 316 436

  10. Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 955 1980's 921 806 780 747 661 570 517 512 428 430 1990's 407 352 308 288 299 245 252 235 204 202 2000's 115 65 70 81

  11. Texas - RRC District 4 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 4 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,416 1980's 1,292 1,005 890 765 702 684 596 451 393 371 1990's 301 243 228 215 191 209 246 368 394 182 2000's 176 140

  12. Texas - RRC District 5 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 5 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 5 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 62 1980's 75 44 47 52 44 40 69 118 101 136 1990's 116 89 126 141 148 47 53 68 89 49 2000's 128 83 65 62 58 51 57 50 40 21 2010's 8 40 53 177

  13. Texas - RRC District 6 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 6 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 6 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 868 1980's 954 869 881 943 938 874 822 811 728 695 1990's 668 638 606 607 547 611 562 578 580 545 2000's 464 412 400 387 402 344 276 247 412

  14. Texas - RRC District 7B Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 7B Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 234 1980's 332 292 214 338 292 276 244 282 264 196 1990's 214 157 170 187 181 276 232 260 204 190 2000's 114 88 57 69 76 73 74 62 68 102

  15. Texas - RRC District 7B Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) B Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7B Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 608 1980's 530 655 733 872 645 574 589 546 576 364 1990's 413 379 380 393 332 263 378 299 306 275 2000's 242 203 237 314 288 859 1,589 2,350 2,682 2,322

  16. Texas - RRC District 8A Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 8A Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 71 1980's 69 59 37 44 43 39 34 30 24 16 1990's 21 21 13 12 15 15 18 41 18 44 2000's 69 82 101 100 95 85 82 88 63 43 2010's 58 31 20 23 24 - = No Data

  17. Texas - RRC District 9 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 9 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 175 1980's 249 274 299 255 274 290 263 267 241 212 1990's 214 200 184 178 148 138 121 147 199 180 2000's 209 124 140 125 110 126 105 139 158

  18. Utah Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Utah Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 367 1980's 414 335 325 360 341 391 410 471 475 442 1990's 455 469 309 289 286 277 301 310 209 321 2000's 348 303 359 299 290 308 317 368 321 601 2010's 631 909 1,001 895 872 - =

  19. West Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) West Virginia Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 76 1980's 122 63 83 86 73 73 65 150 141 98 1990's 86 159 198 190 133 74 71 59 43 88 2000's 98 48 21 23 20 19 16 16 23 24 2010's 29 52 21 70 32 - = No Data

  20. ,"Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  1. ,"Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  2. ,"Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  3. ,"California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  4. ,"Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  5. ,"Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  6. ,"Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Kansas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  7. ,"Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Kentucky Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  8. ,"Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release Date:","11/19/2015" ,"Next Release

  9. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect (OSTI)

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  10. Inorganic, Isotope, and Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Innovative, Lower Cost Sensors and Controls Yield Better Energy Efficiency Innovative, Lower Cost Sensors and Controls Yield Better Energy Efficiency March 23, 2015 - 1:05pm Addthis ORNL researchers are experimenting with additive roll-to-roll manufacturing techniques to develop low-cost wireless sensors. ORNL’s Pooran Joshi shows how the process enables electronics components to be printed on flexible plastic substrates. Credit: Oak Ridge National Lab ORNL

  11. ITP Chemicals: Technology Roadmap for Computational Chemistry | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Chemistry ITP Chemicals: Technology Roadmap for Computational Chemistry PDF icon compchemistry_roadmap.pdf More Documents & Publications Summary Report from Theory Focus Session on Hydrogen Storage Materials Volume 4 FY 2014 LDRD Report

  12. John Marohn > ProfessorChemistry and Chemical Biology > Faculty...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marohn Professor Chemistry and Chemical Biology Research Group Webpage jam99@cornell.edu John Marohn earned a B.S. in Chemistry and a B.A. in Physics from the University of...

  13. Performance evaluation of half-wetted hydrodynamic bearings with DLC coated surfaces.

    SciTech Connect (OSTI)

    Eryilmaz, O.; Erdemir, A.; Energy Systems

    2008-01-01

    In conventional liquid lubrication it is assumed that surfaces are fully wetted and no slip occurs between the fluid and the solid boundary. Under the 'no slip' condition the maximum shear gradient occurs at the fluid-surface interface. When one or both surfaces are non-wetted by the fluid, boundary slip can occur due to weak bonding between the fluid and the solid surface, which reduces shear stresses in the fluid adjacent to the non-wetted surface. A thrust bearing tribometer was used to compare the performance of 'no slip' hydrodynamic thrust bearings with bearings surfaces that were made to slip at the interface between the surface and fluid. Hydrophobic surfaces on both runner and bearing were achieved with the deposition of hydrogenated diamond like carbon (H-DLC) films, produced by plasma-enhanced CVD on titanium alloy surfaces. Hydrophilic surfaces were created through the surface modification of DLC. A mixtures of water and glycerol was used as the lubricant. The tests were conducted using different constant bearing gaps. The normal load and the torque or traction force between the rotating runner and hydrodynamic thrust bearing were measured with load cells. The experimental results confirmed that load support is still possible when surfaces are partially-wetted or nonwetted.

  14. WET-NZ Multi-Mode Wave Energy Converter Advancement Project

    SciTech Connect (OSTI)

    Klure, Justin

    2011-11-01

    Presentation from the 2011 Water Peer Review in which the principal investigator discussed the next steps to verify a multi-mode functionality of the WET-NZ device. This included overview of the approaches taken to perform wave tank testing, open ocean deployment, synthesis and analysis.

  15. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Richard Rhudy

    2006-06-30

    This final report presents and discusses results from a mercury control process development project entitled ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems''. The objective of this project was to demonstrate at pilot scale a mercury control technology that uses solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. Oxidized mercury is removed in downstream wet flue gas desulfurization (FGD) absorbers and leaves with the FGD byproducts. The goal of the project was to achieve 90% oxidation of elemental mercury in the flue gas and 90% overall mercury capture with the downstream wet FGD system. The project was co-funded by EPRI and the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) under Cooperative Agreement DE-FC26-01NT41185. Great River Energy (GRE) and City Public Service (now CPS Energy) of San Antonio were also project co-funders and provided host sites. URS Group, Inc. was the prime contractor. Longer-term pilot-scale tests were conducted at two sites to provide catalyst life data. GRE provided the first site, at their Coal Creek Station (CCS), which fires North Dakota lignite, and CPS Energy provided the second site, at their Spruce Plant, which fires Powder River Basin (PRB) coal. Mercury oxidation catalyst testing began at CCS in October 2002 and continued through the end of June 2004, representing nearly 21 months of catalyst operation. An important finding was that, even though the mercury oxidation catalyst pilot unit was installed downstream of a high-efficiency ESP, fly ash buildup began to plug flue gas flow through the horizontal catalyst cells. Sonic horns were installed in each catalyst compartment and appeared to limit fly ash buildup. A palladium-based catalyst showed initial elemental mercury oxidation percentages of 95% across the catalyst, declining to 67% after 21 months in service. A carbon-based catalyst began with almost 98% elemental mercury oxidation across the catalyst, but declined to 79% oxidation after nearly 13 months in service. The other two catalysts, an SCR-type catalyst (titanium/vanadium) and an experimental fly-ash-based catalyst, were significantly less active. The palladium-based and SCR-type catalysts were effectively regenerated at the end of the long-term test by flowing heated air through the catalyst overnight. The carbon-based catalyst was not observed to regenerate, and no regeneration tests were conducted on the fourth, fly-ash-based catalyst. Preliminary process economics were developed for the palladium and carbon-based catalysts for a scrubbed, North Dakota lignite application. As described above, the pilot-scale results showed the catalysts could not sustain 90% or greater oxidation of elemental mercury in the flue gas for a period of two years. Consequently, the economics were based on performance criteria in a later DOE NETL solicitation, which required candidate mercury control technologies to achieve at least a 55% increase in mercury capture for plants that fire lignite. These economics show that if the catalysts must be replaced every two years, the catalytic oxidation process can be 30 to 40% less costly than conventional (not chemically treated) activated carbon injection if the plant currently sells their fly ash and would lose those sales with carbon injection. If the plant does not sell their fly ash, activated carbon injection was estimated to be slightly less costly. There was little difference in the estimated cost for palladium versus the carbon-based catalysts. If the palladium-based catalyst can be regenerated to double its life to four years, catalytic oxidation process economics are greatly improved. With regeneration, the catalytic oxidation process shows over a 50% reduction in mercury control cost compared to conventional activated carbon injection for a case where the plant sells its fly ash. At Spruce Plant, mercury oxidation catalyst testing began in September 2003 and continued through the end of April 2005, interrupted only by a

  16. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K.

    1993-12-01

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  17. Redox chemistry and metal-insulator transitions intertwined | Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Redox chemistry and metal-insulator transitions intertwined

  18. Computational and Theoretical Chemistry | U.S. DOE Office of...

    Office of Science (SC) Website

    Computational and Theoretical Chemistry Chemical Sciences, Geosciences, & Biosciences ... Molecular Sciences and Gas Phase Chemical Physics programs-which together comprise ...

  19. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    of Engineering and Applied Sciences, Harvard University Hammel, Chris (Chris Hammel) - ... - Departments of Chemistry & Physics, Harvard University Hellman, Frances (Frances ...

  20. Zelenay receives professorship in chemistry from president of Poland

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zelenay receives professorship in chemistry from president of Poland Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay of Materials Synthesis and Integrated Devices (MPA-11) received the honorary title of Professor in Chemistry from Poland's President Bronisław Komorowski during a June 23 ceremony at the Presidential Palace in Warsaw. October 8, 2015 Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay, right, shakes hands with

  1. Parallel Computation Chemistry Using Constraints: Final Report, LDRD 97-0301, Case 3504140000

    SciTech Connect (OSTI)

    Todd D. Plantenga

    1998-11-01

    Computer modeling to estimate material properties, design chem/bio sensors, and evaluate protein-protein interactions all require solving force field equations for molecular structures that contain tens of thousands of covalently connected atoms. Potential energy minimization is a key step in the calculation, but stiff covalent bonding forces make optimization difficult and expensive. This two-year LDRD developed two classes of advanced minimization algorithms that were specialized for chemistry applications and distributed computing machines. The project led to two successful algorithms that were implemented in three Sandia computational chemistry codes to support various users.

  2. Chemistry Division annual progress report for period ending July 31, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Research is reported on: chemistry of coal liquefaction, aqueous chemistry at high temperatures, geosciences, high-temperature chemistry and thermodynamics of structural materials, chemistry of TRU elements and compounds, separations chemistry, electrochemistry, nuclear waste chemistry, chemical physics, theoretical chemistry, inorganic chemistry of hydrogen cycles, molten salt systems, and enhanced oil recovery. Separate abstracts were prepared for the sections dealing with coal liquefaction, TRU elements and compounds, separations, nuclear wastes, and enhanced oil recovery. (DLC)

  3. Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns

    SciTech Connect (OSTI)

    Wishart, J.F.

    2011-06-12

    Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields, which need to be quantified for the successful use under radiolytic conditions. Electron solvation dynamics in ILs are measured directly when possible and estimated using proxies (e.g. coumarin-153 dynamic emission Stokes shifts or benzophenone anion solvation) in other cases. Electron reactivity is measured using ultrafast kinetics techniques for comparison with the solvation process.

  4. Cycle chemistry related issues in fossil power plants

    SciTech Connect (OSTI)

    James, K.L.; Chhatre, R.M.

    1994-12-31

    Maximizing the availability and useful life of a fossil power plant can be achieved by the reduction of corrosion. Poorly defined chemistry limits and inadequate response to cycle chemistry excursions have cost the utility industry billions of dollars in lost revenue and repair/replacement costs of damage equipment. The Cycle Chemistry related corrosion problems can be minimized by maintaining feed water, boiler water, and steam purity. Pacific Gas and Electric Company`s approach to reduce cycle chemistry related damage, as well as their participation in the Electric Power Research Institute`s Cycle Chemistry Improvement Program demonstration are reviewed in this paper.

  5. new chemistry to break down cell walls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    new chemistry to break down cell walls - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  6. understanding the chemistries of ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistries of ionic liquids - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  7. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  8. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  9. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  10. Department of Chemistry | Center for Catalytic Hydrocarbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages

    Functionalization Department of Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars Undergraduate Studies Contact Us Faculty & Research > Research Centers & Programs > Center for Catalytic Hydrocarbon Functionalization CCHF Center for Catalytic Hydrocarbon Functionalization Catalysts are central to the efficient and clean utilization of energy resources, and they impact all aspects of the energy sector. With the University of Virginia as

  11. The Chemistry of Flammable Gas Generation

    SciTech Connect (OSTI)

    ZACH, J.J.

    2000-10-30

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  12. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  13. Chemistry Division annual progress report for period ending January 31, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-05-01

    This report has been indexed by 11 separate chapters. The subjects covered are: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, materials chemistry, chemistry of transuranium elements and compounds, separations chemistry, catalysis, electron spectroscopy, nuclear waste chemistry, heuristic modeling, and special topics. (PLG)

  14. Optimum cycle chemistry for fossil plants

    SciTech Connect (OSTI)

    Dooley, R.B.; Pate, R.

    1995-01-01

    At the time of the last International Fossil Plant Cycle Chemistry Conference in 1991, the vision for cycle chemistry indicated that the fossil plant would become a cleaner place for high purity water and steam, and that the boiler would cease to be the {open_quotes}filter{close_quotes} in the cycle. It was suggested that chemical cleans for drum boilers should be performed on a 10 year basis or greater, and that for once-through units cleans should be eliminated. Without full support of utility management and investment in carefully chosen chemistry and power cycle materials, there would be no chance of success. Three years later it is gratifying to report that the news and progress is very good. Advancements have been achieved in each area and the vision is becoming clearer and more believable by the utilities. This paper will provide the status on the major changes that have taken place and delineate the further needed activities to the end of the century and beyond. A continuing vision is also provided.

  15. Radiation chemistry of alternative fuel oxygenates -- Substituted ethers

    SciTech Connect (OSTI)

    Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

    1999-11-15

    The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

  16. Overview of actinide chemistry in the WIPP

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean - Francois; Richmann, Michael K; Reed, Donald T; Khaing, Hnin; Swanson, Juliet

    2009-01-01

    The year 2009 celebrates 10 years of safe operations at the Waste Isolation Pilot Plant (WIPP), the only nuclear waste repository designated to dispose defense-related transuranic (TRU) waste in the United States. Many elements contributed to the success of this one-of-the-kind facility. One of the most important of these is the chemistry of the actinides under WIPP repository conditions. A reliable understanding of the potential release of actinides from the site to the accessible environment is important to the WIPP performance assessment (PA). The environmental chemistry of the major actinides disposed at the WIPP continues to be investigated as part of the ongoing recertification efforts of the WIPP project. This presentation provides an overview of the actinide chemistry for the WIPP repository conditions. The WIPP is a salt-based repository; therefore, the inflow of brine into the repository is minimized, due to the natural tendency of excavated salt to re-seal. Reducing anoxic conditions are expected in WIPP because of microbial activity and metal corrosion processes that consume the oxygen initially present. Should brine be introduced through an intrusion scenario, these same processes will re-establish reducing conditions. In the case of an intrusion scenario involving brine, the solubilization of actinides in brine is considered as a potential source of release to the accessible environment. The following key factors establish the concentrations of dissolved actinides under subsurface conditions: (1) Redox chemistry - The solubility of reduced actinides (III and IV oxidation states) is known to be significantly lower than the oxidized forms (V and/or VI oxidation states). In this context, the reducing conditions in the WIPP and the strong coupling of the chemistry for reduced metals and microbiological processes with actinides are important. (2) Complexation - For the anoxic, reducing and mildly basic brine systems in the WIPP, the most important inorganic complexants are expected to be carbonate/bicarbonate and hydroxide. There are also organic complexants in TRU waste with the potential to strongly influence actinide solubility. (3) Intrinsic and pseudo-actinide colloid formation - Many actinide species in their expected oxidation states tend to form colloids or strongly associate with non actinide colloids present (e.g., microbial, humic and organic). In this context, the relative importance of actinides, based on the TRU waste inventory, with respect to the potential release of actinides from the WIPP, is greater for plutonium and americium, and to less extent for uranium and thorium. The most important oxidation states for WIPP-relevant conditions are III and IV. We will present an update of the literature on WIPP-specific data, and a summary of the ongoing research related to actinide chemistry in the WIPP performed by the Los Alamos National Laboratory (LANL) Actinide Chemistry and Repository Science (ACRSP) team located in Carlsbad, NM [Reed 2007, Lucchini 2007, and Reed 2006].

  17. U.S. Natural Gas Wet After Lease Separation, Reserves in Nonproducing

    U.S. Energy Information Administration (EIA) Indexed Site

    Reservoirs (Billion Cubic Feet) Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) U.S. Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 33,049 33,157 36,047 36,873 2000's 42,834 52,948 49,974 49,068 51,412 59,658 66,714 78,094 85,543 98,092 2010's 113,439 118,224 110,351 115,915 147,732 - = No Data Reported; -- = Not

  18. U.S. Nonassociated Natural Gas, Reserves in Nonproducing Reservoirs, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Reserves in Nonproducing Reservoirs, Wet (Billion Cubic Feet) U.S. Nonassociated Natural Gas, Reserves in Nonproducing Reservoirs, Wet (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 27,760 27,526 30,570 31,235 2000's 37,639 46,321 43,401 43,165 45,996 53,387 60,669 71,204 78,863 90,477 2010's 104,340 104,964 90,801 93,697 120,492 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  19. Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Ohio Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,479 1980's 1,699 965 1,142 2,031 1,542 1,333 1,420 1,071 1,229 1,275 1990's 1,215 1,181 1,161 1,106 1,095 1,054 1,114 985 890 1,179 2000's 1,186 971 1,118 1,127 975 898 975 1,027 985 896 2010's 832 758 1,235 3,201 7,193 - = No Data Reported; -- = Not

  20. Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Lower 48 States Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 32,208 1980's 33,443 32,870 31,268 31,286 30,282 29,515 28,684 27,457 26,609 26,611 1990's 26,242 25,088 24,701 23,551 23,913 24,532 24,715 24,666

  1. Lower 48 States Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Lower 48 States Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 176,060 1980's 172,864 176,385 174,252 174,755 171,508 167,979 167,754 162,713 167,820 166,409 1990's 168,183 165,672 163,584 160,504 162,126 163,901 165,851 165,048 162,400 166,304 2000's 177,179 182,842 187,028 188,797 192,727

  2. New Mexico - East Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico - East Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,672 1980's 1,533 1,499 1,374 1,323 1,375 1,309 1,232 1,232 1,194 1,200 1990's 1,251 1,398 1,470 1,478 1,544 1,559 1,585 1,314 1,345 1,486 2000's

  3. New Mexico - East Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - East Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,306 1980's 3,799 3,876 3,705 3,537 3,492 3,310 2,982 3,133 3,224 3,331 1990's 3,541 3,471 3,418 3,338 3,335 3,207 3,197 3,008 3,039 3,366 2000's 3,998 3,919 4,011 3,661 3,965 4,132 4,295 4,387 4,406 4,558 2010's 4,720

  4. New Mexico - West Natural Gas, Wet After Lease Separation Proved Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico - West Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 10,085 1980's 10,157 10,686 9,377 8,834 8,535 8,128 9,558 9,488 15,259 13,266 1990's 14,988 16,287 16,981 16,601 15,253 15,540 14,728 13,692 13,220 13,384 2000's 14,511 14,640 14,442 14,565 15,722 15,212 14,809 14,010

  5. New Mexico Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    Proved Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) New Mexico Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,823 1980's 1,689 1,649 1,520 1,503 1,569 1,490 1,446 1,445 1,453 1,378 1990's 1,435 1,554 1,597 1,585 1,641 1,678 1,693 1,420 1,443 1,578 2000's 1,588 1,447 1,482

  6. New Mexico Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) New Mexico Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 14,391 1980's 13,956 14,562 13,082 12,371 12,027 11,438 12,540 12,621 18,483 16,597 1990's 18,529 19,758 20,399 19,939 18,588 18,747 17,925 16,700 16,259 16,750 2000's 18,509 18,559 18,453 18,226 19,687 19,344 19,104 18,397 17,347 16,644

  7. Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Alaska Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 27,217 1980's 28,567 28,676 30,814 30,408 30,356 31,092 30,893 30,732 6,269 6,198 1990's 6,927 6,729 6,723 6,494 6,487 6,265 6,080 7,716 7,275 7,209 2000's 6,768 6,592 6,376

  8. Gulf of Mexico Federal Offshore - Louisiana and Alabama Natural Gas, Wet

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Gulf of Mexico Federal Offshore - Louisiana and Alabama Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 28,772 1990's 23,050 22,028 20,006 19,751 21,208 21,664 22,119 22,428 21,261 20,172 2000's 20,466 20,290 19,113 17,168 15,144 14,073 12,201

  9. Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation Proved Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Gulf of Mexico Federal Offshore - Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6,885 6,511 7,497 7,261 7,277 6,998 1990's 7,330 6,712 7,044 6,712 6,418 6,565 6,034 6,027 5,676 5,890 2000's 6,425 6,810 6,234 5,354 4,144 3,354 2,738 2,550 2,402 2,451

  10. Notes on the efficacy of wet versus dry screening of fly ash

    SciTech Connect (OSTI)

    Valentim, B.; Hower, J.C.; Flores, D.; Guedes, A.

    2008-08-15

    The methodology used to obtain fly ash subsamples of different sizes is generally based on wet or dry sieving methods. However, the worth of such methods is not certain if the methodology applied is not mentioned in the analytical procedure. After performing a fly ash mechanical dry, sieving, the authors compared those results with the ones obtained by laser diffraction on the same samples and found unacceptable discrepancies. A preliminary, study of a wet sieving analysis carried out on an economizer fly ash sample showed that this method was more effective than the dry sieving. The importance of standardizing the way samples are handled, pretreated and presented to the instrument of analysis are suggested and interlaboratory reproducibility trials are needed to create a common standard methodology to obtain large amounts of fly ash size fraction subsamples.

  11. AmeriFlux US-ICs Imnavait Creek Watershed Wet Sedge Tundra

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Bret-Harte, Syndonia [University of Alaska Fairbanks; Euskirchen, Eugenie [University of Alaska Fairbanks; Shaver, Gaius [Marine Biological Laboratory

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-ICs Imnavait Creek Watershed Wet Sedge Tundra. Site Description - The Imnavait Creek Watershed Wet Sedge Tundra (Fen Station) is located near Imnavait Creek in Alaska, north of the Brooks Range in the Kuparuk basin near Lake Toolik and the Toolik Field Station. The Kuparuk River has its headwaters in the Brooks Range and drains through northern Alaska into the Arctic Ocean. Within these headwaters lies the Imnavait basin at an average elevation of 930 m. Water tracks run down the hill in parallel zones with a spacing of approximately 10 m. The Fen Station was deployed at the end of Summer 2007.

  12. Texas - RRC District 10 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 10 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,289 1980's 6,927 6,720 6,731 6,485 6,060 6,044 5,857 5,512 5,300 5,213 1990's 4,919 5,061 4,859 4,478 4,669 4,910 4,845 4,613 4,744 4,688 2000's 4,433 4,263 4,299 4,510 5,383 5,430 5,950 6,932 7,601

  13. Texas - RRC District 2 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 2 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 2 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,079 1980's 1,645 1,920 1,785 1,890 1,965 1,895 1,760 1,861 1,703 1,419 1990's 1,418 1,127 1,176 1,137 1,169 1,126 1,178 1,497 1,516

  14. Texas - RRC District 3 Onshore Associated-Dissolved Natural Gas, Wet After

    U.S. Energy Information Administration (EIA) Indexed Site

    Lease Separation, Proved Reserves (Billion Cubic Feet) 3 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,513 1980's 2,429 2,080 1,881 1,784 1,756 1,537 1,405 1,296 1,226 1,148 1990's 1,056 1,123 1,206 1,159 1,063 960

  15. Texas - RRC District 3 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 3 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 3 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 4,052 1980's 3,333 3,466 3,167 3,220 3,264 2,940 2,605 2,563 2,400 2,278 1990's 2,024 1,987 1,723 2,092 2,590 3,196 3,612 3,539 3,275

  16. Texas - RRC District 4 Onshore Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 4 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 4 Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 7,143 1980's 7,074 7,251 7,802 7,847 8,094 7,825 7,964 7,317 6,891 7,009 1990's 7,473 7,096 6,813 7,136 7,679 7,812 7,877 8,115 8,430

  17. Texas - RRC District 7C Nonassociated Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 7C Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 7C Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,427 1980's 2,023 2,065 2,224 2,150 2,393 2,475 2,373 2,295 2,374 2,776 1990's 3,061 2,833 2,873 2,945 3,029 2,828 3,371 3,247 2,939 2,977 2000's 3,439

  18. Texas - RRC District 8 Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) 8 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8 Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 2,645 1980's 2,569 2,630 2,908 3,014 2,932 3,004 3,076 2,898 3,072 3,128 1990's 3,068 2,770 2,742 2,562 2,751 2,834 2,981 3,144 2,820 3,175

  19. Texas - RRC District 8A Associated-Dissolved Natural Gas, Wet After Lease

    U.S. Energy Information Administration (EIA) Indexed Site

    Separation, Proved Reserves (Billion Cubic Feet) A Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Associated-Dissolved Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,485 1980's 1,396 1,486 1,420 1,301 1,272 1,314 1,275 1,271 1,267 1,534 1990's 1,526 1,521 1,585 1,451 1,572 1,318 1,276 1,206 1,097 1,513

  20. Texas - RRC District 8A Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 8A Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 1,556 1980's 1,465 1,545 1,457 1,345 1,315 1,353 1,309 1,301 1,291 1,550 1990's 1,547 1,542 1,598 1,463 1,587 1,333 1,294 1,247 1,115 1,557 2000's 1,215 1,190 1,167 1,137 1,281 1,471 1,384 1,531 1,257

  1. Texas - RRC District 9 Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    Reserves (Billion Cubic Feet) Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Texas - RRC District 9 Natural Gas, Wet After Lease Separation Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 808 1980's 751 1,070 1,264 1,100 1,060 1,043 1,024 984 927 829 1990's 917 874 797 814 863 868 870 932 864 1,360 2000's 1,854 2,552 3,210 3,639 4,555 4,734 6,765 7,985 9,548 11,522 2010's 13,172 10,920

  2. Environmental aspects of alternative wet technologies for producing energy/fuel from peat. Final report

    SciTech Connect (OSTI)

    Smith, R.T.

    1981-05-01

    Peat in situ contains up to 90% moisture, with about 50% of this moisture trapped as a colloidal gel. This colloidal moisture cannot be removed by conventional dewatering methods (filter presses, etc.) and must be removed by thermal drying, solvent extraction, or solar drying before the peat can be utilized as a fuel feedstock for direct combustion or gasification. To circumvent the drying problem, alternative technologies such as wet oxidation, wet carbonization, and biogasification are possible for producing energy or enhanced fuel from peat. This report describes these three alternative technologies, calculates material balances for given raw peat feed rates of 1000 tph, and evaluates the environmental consequences of all process effluent discharges. Wastewater discharges represent the most significant effluent due to the relatively large quantities of water removed during processing. Treated process water returned to the harvested bog may force in situ, acidic bog water into recieving streams, disrupting local aquatic ecosystems.

  3. Wet-chemical systems and methods for producing black silicon substrates

    DOE Patents [OSTI]

    Yost, Vernon; Yuan, Hao-Chih; Page, Matthew

    2015-05-19

    A wet-chemical method of producing a black silicon substrate. The method comprising soaking single crystalline silicon wafers in a predetermined volume of a diluted inorganic compound solution. The substrate is combined with an etchant solution that forms a uniform noble metal nanoparticle induced Black Etch of the silicon wafer, resulting in a nanoparticle that is kinetically stabilized. The method comprising combining with an etchant solution having equal volumes acetonitrile/acetic acid:hydrofluoric acid:hydrogen peroxide.

  4. Lipid Extraction from Wet-Algae for Biofuel Production - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Lipid Extraction from Wet-Algae for Biofuel Production University of Colorado Contact CU About This Technology Technology Marketing SummaryThere is a growing interest in algal biofuels; however, current methods of a thermal separation process for solvent mixtures involve concomitant issues and increased energy consumption. A research team at the University of Colorado

  5. Farm-scale production of fuel ethanol and wet grain from corn in a batch process

    SciTech Connect (OSTI)

    Westby, C.A.; Gibbons, W.R.

    1982-07-01

    The batch production of fuel grade ethanol and distillers' wet grain (wet solids) in a farm-scale process (1240-15,580 L/batch) is described. The procedure employs yeast fermentation of amylase-treated corn mash and a two-stage distillation. Primary emphasis in this study was on the cooking, fermentation and centrifugation steps. Without recycling, fermentation of the mash yielded beers with 10.0-10.5% ethanol. Recycling of stillage supernatant at full, 75, or 50% strengths produced enriched mashes that after 48-hour fermentation yielded beers with 5-14% more ethanol. Recycling twice with full-strength stillage supernatant at pH 7.0 increased the ethanol yield in the final beer 16.5%; however, the time to complete the final fermentation was extended from 48 to 72 hours and salt buildup occurred. By recycling at pH 5.4, it was possible to avoid salt buildup and obtain beers with 10.3-10.5% ethanol. Recycling resulted in increased levels of glucose, starch, crude protein, and fat in the beer and a reduced moisture content while the wet solids showed an increased starch content. Centrifugation after cooking or fermentation instead of after distillation reduced the mash volume 17-20% and this lowered the ethanol yield in the subsequently produced beer. Fermentation of a volume-restored mash supernatant gave a beer with only 9.25% ethanol. Mash wet solids varied somewhat chemically from beer and stillage solids. An economic and energy balance analysis of various modes of plant operation are provided and plant design considerations are suggested. (Refs. 31).

  6. In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO2

    SciTech Connect (OSTI)

    Loring, John S.; Thompson, Christopher J.; Wang, Zheming; Joly, Alan G.; Sklarew, Deborah S.; Schaef, Herbert T.; Ilton, Eugene S.; Rosso, Kevin M.; Felmy, Andrew R.

    2011-07-19

    Carbonation reactions are central to the prospect of CO2 trapping by mineralization in geologic reservoirs. In contrast to the relevant aqueous-mediated reactions, little is known about the propensity for carbonation in the long-term partner fluid: water-containing supercritical carbon dioxide (wet scCO2). We employed in situ mid-infrared spectroscopy to follow the reaction of a model silicate mineral (forsterite, Mg2SiO4) for 24 hr with wet scCO2 at 50C and 180 atm, using water concentrations corresponding to 0%, 55%, 95%, and 136% saturation. Results show a dramatic dependence of reactivity on water concentration and the presence of liquid water on the forsterite particles. Exposure to neat scCO2 showed no detectable carbonation reaction. At 55% and 95% water saturation, a liquid-like thin water film was detected on the forsterite particles; less than 1% of the forsterite transformed, mostly within the first 3 hours of exposure to the fluid. At 136% saturation, where an (excess) liquid water film approximately several nanometers thick was intentionally condensed on the forsterite, the carbonation reaction proceeded continuously for 24 hr with 10% to 15% transformation. Our collective results suggest constitutive links between water concentration, water film formation, reaction rate and extent, and reaction products in wet scCO2.

  7. OVERVIEW OF CRITERIA FOR INTERIM WET & DRY STORAGE OF RESEARCH REACTOR SPENT NUCLEAR FUEL

    SciTech Connect (OSTI)

    Sindelar, R.; Vinson, D.; Iyer, N.; Fisher, D.

    2010-11-03

    Following discharge from research reactors, spent nuclear fuel may be stored 'wet' in water pools or basins, or it may be stored 'dry' in various configurations including non-sealed or sealed containers until retrieved for ultimate disposition. Interim safe storage practices are based on avoiding degradation to the fuel that would impact functions related to safety. Recommended practices including environmental controls with technical bases, are outlined for wet storage and dry storage of aluminum-clad, aluminum-based research reactor fuel. For wet storage, water quality must be maintained to minimize corrosion degradation of aluminum fuel. For dry storage, vented canister storage of aluminum fuel readily provides a safe storage configuration. For sealed dry storage, drying must be performed so as to minimize water that would cause additional corrosion and hydrogen generation. Consideration must also be given to the potential for radiolytically-generated hydrogen from the bound water in the attendant oxyhydroxides on aluminum fuel from reactor operation for dry storage systems.

  8. Effect of temperature, salinity and oil composition on wetting behavior and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1996-12-31

    The effect of aging and displacement temperatures, and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea Sandstone using three distinctly different crude oils and three reservoir brines. Brine concentration was varied by changing the concentration of total dissolved solids of the synthetic brine in proportion to give brine of twice, one tenth, and one hundredth of the reservoir brine concentration. Aging and displacement temperatures were varied independently. For all crude oils, water-wetness and oil recovery increased with increase in displacement temperature. Tests on the effect of brine concentration showed that salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the reservoir brine with dilution of both the initial (connate) and invading brine or dilution of either. Removal of light components from the crude oil resulted in increased water-wetness. Addition of alkanes to the crude oil reduced the water-wetness, and increased oil recovery. Relationships between waterflood recovery and wettability are summarized.

  9. Wetting of Sodium on ??-Al2O3/YSZ Composites for Low Temperature Planar Sodium-Metal Halide Batteries

    SciTech Connect (OSTI)

    Reed, David M.; Coffey, Greg W.; Mast, Eric S.; Canfield, Nathan L.; Mansurov, Jirgal; Lu, Xiaochuan; Sprenkle, Vincent L.

    2013-04-01

    Wetting of Na on B-Al2O3/YSZ composites was investigated using the sessile drop technique. The effects of moisture and surface preparation were studied at low temperatures. Electrical conductivity of Na/B-Al2O3-YSZ/Na cells was also investigated at low temperatures and correlated to the wetting behavior. The use of planar B-Al2O3 substrates at low temperature with low cost polymeric seals is realized due to improved wetting at low temperature and conductivity values consistent with the literature.

  10. Developing an Approach for First-principles Catalyst Design:...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Developing an Approach for First-principles ... ANALYTICAL CHEMISTRY; 29 ENERGY PLANNING, POLICY AND ECONOMY; 97 MATHEMATICS, COMPUTING, ...

  11. Cornell-developed polymer has commercial debut > EMC2 News >...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lab of Geoffrey Coates, professor of chemistry and chemical biology in the College of Arts and Sciences, and further developed by the Cornell spinoff company Novomer. A...

  12. Developing an Approach for First-principles Catalyst Design:...

    Office of Scientific and Technical Information (OSTI)

    Developing an Approach for First-principles Catalyst Design: Application to Carbon Capture ... ANALYTICAL CHEMISTRY; 29 ENERGY PLANNING, POLICY AND ECONOMY; 97 MATHEMATICS, COMPUTING, ...

  13. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    KRUMHANSL,JAMES L.; LIU,JUN; NAGY,KATHRYN L.; BRADY,PATRICK V.

    1999-11-29

    We are attempting to understand the solid phase chemistry of the high level nuclear waste (HLW) stored in tanks at Hanford. Because this waste is compositionally complex, our approach is to study experimentally the aging dynamics of simplified systems whose bulk chemistry approximates that of the tank sludges. After a basic understanding of these dynamics has been attained we plan to increase the compositional complexities one component at a time, in order to assess the influence of each component. Results will allow for reliable prediction of sludge phase chemistry over a range of sludge compositions. Iron and aluminum comprise the bulk of most HLW sludges, so we chose to begin by studying the behavior of iron-aluminum systems. Fe/Al ratios were chosen to approximate those relevant to the solutions that produced the sludge. Aluminum and iron concentrations in the various process fluids are summarized and compared to our experimental starting solutions in Table 1 (process solution data from Krumhansl, personal communication, 1998). Our low aluminum experiments serve as direct analogues to both Bismuth Phosphate and low-Fe PUREX waste. Cornell and Giovanoli (1985) found that, in a pure iron system at 70 C, a 10-fold or even 50-fold increase in suspension concentration had only very slight effects on the final aged products. Since our experiments have similar Al/Fe ratios to some high Fe-PUREX process solutions our results are probably relevant to those wastes as well. However, our results may not apply to the high-Fe and high-Al PUREX wastes, as discussed below. The high Al experiments were designed specifically to simulate REDOX waste.

  14. Radiation Chemistry of Advanced TALSPEAK Flowsheet

    SciTech Connect (OSTI)

    Mincher, Bruce; Peterman, Dean; Mcdowell, Rocklan; Olson, Lonnie; Lumetta, Gregg J.

    2013-08-28

    This report summarizes the results of initial experiments designed to understand the radiation chemistry of an Advanced TALSPEAK process for separating trivalent lanthanides form the actinides. Biphasic aerated samples were irradiated and then analyzed for post-irradiation constituent concentrations and solvent extraction distribution ratios. The effects of irradiation on the TALSPEAK and Advanced TALSPEAK solvents were similar, with very little degradation of the organic phase extractant. Decomposition products were detected, with a major product in common for both solvents. This product may be responsible for the slight increase in distribution ratios for Eu and Am with absorbed dose, however; separation factors were not greatly affected.

  15. Advances in Glass Chemistry - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Projects & Facilities Waste Treatment Plant Advances in Glass Chemistry About Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration Disposal Facility F Reactor H

  16. Final Report: Ionization chemistry of high temperature molecular fluids

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Final Report: Ionization chemistry of high temperature molecular fluids Citation Details In-Document Search Title: Final Report: Ionization chemistry of high temperature molecular fluids With the advent of coupled chemical/hydrodynamic reactive flow models for high explosives, understanding detonation chemistry is of increasing importance to DNT. The accuracy of first principles detonation codes, such as CHEETAH, are dependent on an

  17. Training April 5 - Material Science and Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 5 Training April 5 - Material Science and Chemistry Applications March 9, 2011 by Francesca Verdier Training on "Using Chemistry and Material Sciences Applications" will be held April 5, presented simultaneously on the web and at NERSC. See Chemistry and Material Sciences Applications. Subscribe via RSS Subscribe Browse by Date May 2016 April 2016 January 2016 December 2015 November 2015 October 2015 September 2015 August 2015 July 2015 April 2015 March 2015 January 2015 December

  18. NERSC training events: Data Transfer and Archiving; Chemistry and Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences Applications training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications February 21, 2011 by Richard Gerber NERSC will present two training events in March: Data Transfer and Archiving March 8, 2011 10:00-12:30 Pacific Time Using Chemistry and Material Sciences Applications at NERSC March 22, 2011 10:00-12:00 Pacific Time Each event will be held

  19. Chemistry: Mechanism and Experiment - Combustion Energy Frontier Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Chemistry: Mechanism and Experiment Chemistry: Mechanism and Experiment The Mechanism and Experiment DWG uses an array of advanced experimental apparatus to probe the combustion chemistry of fuels. Primary apparatus used include shock tube (Hanson/Davidson), variable-pressure turbulent flow reactor (Dryer), rapid compression machine (Sung), low-pressure burner stabilized flame coupled with synchrotron photoionization mass spectrometry (Hansen, Dryer), atmospheric-pressure burner

  20. Symposium on the Physical Chemistry of Solar Energy Conversion,

    Office of Scientific and Technical Information (OSTI)

    Indianapolis American Chemical Society Meetings, Fall 2013 (Technical Report) | SciTech Connect Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical Society Meetings, Fall 2013 Citation Details In-Document Search Title: Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical Society Meetings, Fall 2013 The Symposium on the Physical Chemistry of Solar Energy Conversion at the Fall ACS Meeting in Indianapolis, IN

  1. Workshop on Excellence Empowered by a Diverse Academic Workforce: Achieving Racial & Ethnic Equity in Chemistry

    SciTech Connect (OSTI)

    Hassan. B. Ali

    2008-02-13

    The purpose of the Workshop 'Excellence Empowered by a Diverse Academic Workforce: Achieving Racial & Ethnic Equity in Chemistry' was to promote the development of a cadre of academic leaders who create, implement and promote programs and strategies for increasing the number of racial and ethnic minorities to equitable proportions on the faculties of departments throughout the academic chemistry community. An important objective of the workshop was to assist in creating an informed and committed community of chemistry leaders who will create, implement and promote programs and strategies to advance racial and ethnic equity in both the faculty and the student body with the goal of increasing the number of U.S. citizen underrepresented minorities (URM) participating in academic chemistry at all levels, with particular focus on the pipeline to chemistry faculty. This objective was met by (1) presentations of detailed data describing current levels of racial and ethnic minorities on the faculties of chemistry departments; (2) frank discussion of the obstacles to and benefits of racial/ethnic diversity in the chemistry professoriate; (3) summary of possible effective interventions and actions; and (4) promotion of the dissemination and adoption of initiatives designed to achieve racial/ethnic equity. Federal programs over the past thirty years have been instrumental in delivering to our universities URM students intending to major in the physical sciences such as chemistry. However, the near absence of URM faculty means that there is also an absence of URM as role models for aspiring students. For example, citing 2003 as a representative year, some statistics reveal the severity of the pipeline shrinkage for U. S. citizen URM starting from chemistry B.S. degrees awarded to the appointment to chemistry faculty. Compared to the URM population of approximately 30% for that year, 67% of the B.S. degrees in chemistry were awarded to white citizens and 17% were awarded to URM citizens. Proceeding along the pipeline, 83% of the Ph.D. degrees in chemistry were awarded to white citizens, and 6.4% were awarded to URM citizens. The number of white citizens occupying tenure faculty lines in chemistry departments at major research universities is estimated to be 86%, while the corresponding lines for URM was estimated to be only 3.7% in 2003. In raw numbers, the number of white chemistry faculty is estimated to be 1459 and the number of URM faculty was estimated to be just 62. Thus, starting with 16.6% for URM students awarded B.S. degrees in chemistry, the number decreases to 6.4% for URM students awarded Ph.D degrees in chemistry and then dwindles to only 3.6% URM faculty in major research universities, compared to a population of approximately 30% URM citizens. Similar statistics for URM representation in chemistry is found for the last two decades. Clearly there is a serious lack of URM mentors and role models among tenure faculty in our chemistry departments. The impact of this deficiency is captured in the statement that 'A university's lack of minority faculty sends a message to its students that minorities have no place in academia' thereby perpetuating a cycle of marginalization and discrimination. The lack of mentors and role models in academia deprive URM students who pass through the undergraduate programs of an education that is enriched by the intellectual and cognitive diversity that is inherent in a faculty of diverse backgrounds and cultures. Furthermore, URM are projected to constitute almost 32% of the U.S. population by 2020, so that URM will outnumber White males [who are projected to constitute 30% of the population (U.S. Census data)]. It is clearly time for this to change and proactive programs are needed immediately in order to insure that there will be an optimal inclusion of the future 'majority' of the U. S. domestic population throughout all levels of academia. The workshop was organized with the intention of triggering such a change by working with key representatives of chemistry in academia, namely the chem

  2. ,"Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Miscellaneous States Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  3. ,"New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico - East Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  4. ,"New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico - West Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  5. ,"Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  6. ,"California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Federal Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  7. ,"California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  8. ,"Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana - North Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  9. ,"Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana - South Onshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  10. ,"Louisiana State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana State Offshore Nonassociated Natural Gas, Wet After Lease Separation, Proved Reserves (Billion Cubic Feet)",1,"Annual",2014 ,"Release

  11. Physical Organic Chemistry of Reactive Intermediates | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by the photolysis of sulfur bearing precursors. Techniques and approaches involve synthesis, spectroscopy, and computational chemistry. The group also has some interest in...

  12. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Barnes, Bill (Bill Barnes) - School of Physics, University of Exeter Barrett, Christopher (Christopher Barrett) - Department of Chemistry, McGill University Barron, Annelise E. ...

  13. The Chemistry and Applications of Metal-Organic Frameworks |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Applications of Metal-Organic Frameworks Previous Next List Hiroyasu Furukawa, Kyle E. Cordova, Michael O'Keeffe, Omar M. Yaghi, Science, 341, 1230444 (2013) DOI:...

  14. Reductant Chemistry during LNT Regeneration for a Lean Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in ...

  15. Redox chemistry and metal-insulator transitions intertwined in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Redox chemistry and metal-insulator transitions intertwined in a nano-porous material Previous Next List Sergey N. Maximoff and Berend Smit, Nature Communications 5, 4032 (2014)...

  16. Solar Energy Education. Renewable energy activities for chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Citation Details In-Document Search Title: Solar Energy Education. Renewable energy activities for chemistry and physics You are accessing a document from the Department of ...

  17. Ultrafast Shock Initiation of Exothermic Chemistry in Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 71 CLASSICAL AND QUANTUMM MECHANICS, GENERAL PHYSICS; 36 MATERIALS SCIENCE; 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

  18. January 2013 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    January 2013 Most Viewed Documents for Chemistry Dialkylenecarbonate-Bridged Polysilsesquioxanes. Hybrid Organic-Inorganic Sol-Gels with a Thermally Labile Bridging Group Assink, ...

  19. Control of Slag Chemistry for the Reduction of Viscosity and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of slag viscosity and refractory wear in gasification systems. Application of this methodology to control slag chemistry will minimize refractory corrosion caused by carbon...

  20. March 2015 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    ... Dept. of Nuclear Chemistry (1995) 40 Recycling galvanized steel: Operating experience and benefits Dudek, F.J.; Daniels, E.J. Argonne National Lab., IL (United States); Morgan, ...

  1. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Qi, Limin (Limin Qi) - College of Chemistry, Peking University Qiao, Pizhong (Pizhong Qiao) - Department of Civil Engineering, University of Akron Qin, Lu-Chang (Lu-Chang Qin) - ...

  2. Symposium on the Physical Chemistry of Solar Energy Conversion...

    Office of Scientific and Technical Information (OSTI)

    Chemical Society Meetings, Fall 2013 Citation Details In-Document Search Title: Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical ...

  3. High Level Computational Chemistry Approaches to the Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energetic Properties of Chemical Hydrogen Storage Systems High Level Computational Chemistry Approaches to the Prediction of Energetic Properties of Chemical Hydrogen Storage ...

  4. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M.

    1992-11-01

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  5. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M.

    1992-01-01

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  6. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    - Division of Material Sciences, California Institute of Technology Eisenthal, Kenneth B. (Kenneth B. Eisenthal) - Department of Chemistry, Columbia University El-Naggar, Moh (Moh ...

  7. Atomic Scale Imaging of the Electronic Structure and Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Imaging of the Electronic Structure and Chemistry of Graphene and Its Precursors on Metal Surfaces Re-direct Destination: Executive Summary of Final Report for Award...

  8. Characteristics and Effects of Lubricant Additive Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Service Life and Vehicle Fuel Economy Characteristics and Effects of Lubricant Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle ...

  9. ARM - Field Campaign - MASRAD: Cloud Condensate Nuclei Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Condensate Nuclei Chemistry Measurements Campaign Links AMF Point Reyes Website ARM Data Discovery Browse Data Related Campaigns MArine Stratus Radiation Aerosol and Drizzle...

  10. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ... Materials & Cell Chemistries and Streamlining Optimization of Electrodes Validation of

  11. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit ... Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode ...

  12. Computer-Aided Construction of Combustion Chemistry Models

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constructing Accurate Combustion Chemistry Models: Butanols William H. Green & Michael Harper MIT Dept. of Chem. Eng. CEFRC Annual Meeting, Sept. 2010 The people who did this work:...

  13. Experience from the Short Course on Introduction to Nuclear Chemistry...

    Office of Environmental Management (EM)

    Short Course - Overview & Lessons Learned David Kosson, Vanderbilt & CRESP Introduction to Nuclear Chemistry and Fuel Cycle Separations December 16-18, 2008 Vanderbilt University...

  14. January 23, 2016: Science on Saturday: Using Physics and Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23, 2016 - 09:30 January 23, 2016: Science on Saturday: Using Physics and Chemistry to Understand the Genome PPPL, MBG Auditorium Speaker: Professor Mary Jo Ondrechen Northeastern...

  15. Will Dichtel > Associate ProfessorChemistry and Chemical Biology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    precise organic materials. Projects in the Dichtel Group involve organic and polymer chemistry, solution and solid-state characterization, nanofabrication, and electronic...

  16. Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry

    Broader source: Energy.gov [DOE]

    Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry presentation at the April 2013 peer review meeting held in Denver, Colorado.

  17. Interfacial Chemistry of III-V Semiconductors for Photoelectrochemical...

    Office of Scientific and Technical Information (OSTI)

    Photoelectrochemical Water Splitting Citation Details In-Document Search Title: Interfacial Chemistry of III-V Semiconductors for Photoelectrochemical Water Splitting You are ...

  18. Coagulation chemistries for silica removal from cooling tower...

    Office of Scientific and Technical Information (OSTI)

    removal from cooling tower water. Citation Details In-Document Search Title: Coagulation chemistries for silica removal from cooling tower water. You are accessing a ...

  19. Copper ionic liquids: Tunable ligand and anion chemistries to...

    Office of Scientific and Technical Information (OSTI)

    to control electrochemistry and deposition morphology. Citation Details In-Document Search Title: Copper ionic liquids: Tunable ligand and anion chemistries to control ...

  20. Time-Resolved Optical Measurements of Shock-Induced Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Title: Time-Resolved Optical Measurements of Shock-Induced Chemistry in Energetic Materials. Abstract not provided. Authors: Wixom, Ryan R. ; Knepper, Robert ; Tappan, Alexander S. ...