National Library of Energy BETA

Sample records for developing liquid desiccant

  1. Using liquid desiccant as a regenerable filter for capturing and deactivating contaminants

    DOE Patents [OSTI]

    Slayzak, Steven J. (Denver, CO); Anderson, Ren S. (Broomfield, CO); Judkoff, Ronald D. (Golden, CO); Blake, Daniel M. (Golden, CO); Vinzant, Todd B. (Golden, CO); Ryan, Joseph P. (Golden, CO)

    2007-12-11

    A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.

  2. Energy-efficient regenerative liquid desiccant drying process

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL); Grodzka, Philomena G. (Huntsville, AL); McCormick, Paul O. (Athens, AL)

    1980-01-01

    This invention relates to the use of desiccants in conjunction with an open oop drying cycle and a closed loop drying cycle to reclaim the energy expended in vaporizing moisture in harvested crops. In the closed loop cycle, the drying air is brought into contact with a desiccant after it exits the crop drying bin. Water vapor in the moist air is absorbed by the desiccant, thus reducing the relative humidity of the air. The air is then heated by the used desiccant and returned to the crop bin. During the open loop drying cycle the used desiccant is heated (either fossil or solar energy heat sources may be used) and regenerated at high temperature, driving water vapor from the desiccant. This water vapor is condensed and used to preheat the dilute (wet) desiccant before heat is added from the external source (fossil or solar). The latent heat of vaporization of the moisture removed from the desiccant is reclaimed in this manner. The sensible heat of the regenerated desiccant is utilized in the open loop drying cycle. Also, closed cycle operation implies that no net energy is expended in heating drying air.

  3. Low-Flow Liquid Desiccant Air-Conditioning: Demonstrated Performance and Cost Implications

    SciTech Connect (OSTI)

    Kozubal, E.; Herrmann, L.; Deru, M.; Clark, J.; Lowenstein, A.

    2014-09-01

    Cooling loads must be dramatically reduced when designing net-zero energy buildings or other highly efficient facilities. Advances in this area have focused primarily on reducing a building's sensible cooling loads by improving the envelope, integrating properly sized daylighting systems, adding exterior solar shading devices, and reducing internal heat gains. As sensible loads decrease, however, latent loads remain relatively constant, and thus become a greater fraction of the overall cooling requirement in highly efficient building designs, particularly in humid climates. This shift toward latent cooling is a challenge for heating, ventilation, and air-conditioning (HVAC) systems. Traditional systems typically dehumidify by first overcooling air below the dew-point temperature and then reheating it to an appropriate supply temperature, which requires an excessive amount of energy. Another dehumidification strategy incorporates solid desiccant rotors that remove water from air more efficiently; however, these systems are large and increase fan energy consumption due to the increased airside pressure drop of solid desiccant rotors. A third dehumidification strategy involves high flow liquid desiccant systems. These systems require a high maintenance separator to protect the air distribution system from corrosive desiccant droplet carryover and so are more commonly used in industrial applications and rarely in commercial buildings. Both solid desiccant systems and most high-flow liquid desiccant systems (if not internally cooled) add sensible energy which must later be removed to the air stream during dehumidification, through the release of sensible heat during the sorption process.

  4. Low-Flow Liquid Desiccant Air Conditioning: General Guidance and Site Considerations

    SciTech Connect (OSTI)

    Kozubal, E.; Herrmann, L.; Deru, M.; Clark, J.

    2014-09-01

    Dehumidification or latent cooling in buildings is an area of growing interest that has been identified as needing more research and improved technologies for higher performance. Heating, ventilating, and air-conditioning (HVAC) systems typically expend excessive energy by using overcool-and-reheat strategies to dehumidify buildings. These systems first overcool ventilation air to remove moisture and then reheat the air to meet comfort requirements. Another common strategy incorporates solid desiccant rotors that remove moisture from the air more efficiently; however, these systems increase fan energy consumption because of the high airside pressure drop of solid desiccant rotors and can add heat of absorption to the ventilation air. Alternatively, liquid desiccant air-conditioning (LDAC) technology provides an innovative dehumidification solution that: (1) eliminates the need for overcooling and reheating from traditional cooling systems; and (2) avoids the increased fan energy and air heating from solid desiccant rotor systems.

  5. Indirect evaporative cooler using membrane-contained, liquid desiccant for dehumidification

    DOE Patents [OSTI]

    Kozubal, Eric Joseph; Slayzak, Steven Joseph

    2014-07-08

    An indirect evaporative cooler for cooling inlet supply air from a first temperature to a second, lower temperature using a stream of liquid coolant and a stream of exhaust or purge air. The cooler includes a first flow channel for inlet supply air and a second flow channel adjacent the first for exhaust air. The first and second flow channels are defined in part by sheets of a membrane permeable to water vapor such that mass is transferred as a vapor through the membrane from the inlet supply air to a contained liquid desiccant for dehumidification and also to the exhaust air as heat is transferred from the inlet supply air to the liquid coolant. A separation wall divides the liquid desiccant and the coolant but allows heat to be transferred from the supply air to the coolant which releases water vapor to the counter or cross flowing exhaust air.

  6. Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype Eric Kozubal, Jason Woods, and Ron Judkoff Technical Report NREL/TP-5500-54755 April 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308

  7. Zero Carryover Liquid-Desiccant Air Conditioner for Solar Applications: Preprint

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Zero Carryover Liquid-Desiccant Air Conditioner for Solar Applications Preprint A. Lowenstein AIL Research, Inc. S. Slayzak and E. Kozubal National Renewable Energy Laboratory To be presented at ASME International Solar Energy Conference (ISEC2006) Denver, Colorado July 8-13, 2006 Conference Paper NREL/CP-550-39798 July 2006 NOTICE The submitted manuscript has been offered by an employee of the Midwest Research Institute (MRI), a contractor of the US Government under Contract No.

  8. Solar-Powered, Liquid-Desiccant Air Conditioner for Low-Electricity Humidity Control: Report and Summary Report

    SciTech Connect (OSTI)

    Dean, J.; Kozubal, E.; Herrmann, L.; Miller, J.; Lowenstein, A.; Barker, G.; Slayzak, S.

    2012-11-01

    The primary objective of this project was to demonstrate the capabilities of a new high-performance, liquid-desiccant dedicated outdoor air system (DOAS) to enhance cooling efficiency and comfort in humid climates while substantially reducing electric peak demand at Tyndall Air Force Base (AFB), which is 12 miles east of Panama City, Florida.

  9. Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype

    SciTech Connect (OSTI)

    Kozubal, E.; Woods, J.; Judkoff, R.

    2012-04-01

    This report documents the design of a desiccant enhanced evaporative air conditioner (DEVAP AC) prototype and the testing to prove its performance. Previous numerical modeling and building energy simulations indicate a DEVAP AC can save significant energy compared to a conventional vapor compression AC (Kozubal et al. 2011). The purposes of this research were to build DEVAP prototypes, test them to validate the numerical model, and identify potential commercialization barriers.

  10. Seminar 14 - Desiccant Enhanced Air Conditioning: Desiccant Enhanced Evaporative Air Conditioning (Presentation)

    SciTech Connect (OSTI)

    Kozubal, E.

    2013-02-01

    This presentation explains how liquid desiccant based coupled with an indirect evaporative cooler can efficiently produce cool, dry air, and how a liquid desiccant membrane air conditioner can efficiently provide cooling and dehumidification without the carryover problems of previous generations of liquid desiccant systems. It provides an overview to a liquid desiccant DX air conditioner that can efficiently provide cooling and dehumidification to high latent loads without the need for reheat, explains how liquid desiccant cooling and dehumidification systems can outperform vapor compression based air conditioning systems in hot and humid climates, explains how liquid desiccant cooling and dehumidification systems work, and describes a refrigerant free liquid desiccant based cooling system.

  11. Zero Energy Communities with Central Solar Plants using Liquid Desiccants and Local Storage: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Woods, J.; Kozubal, E.; Boranian, A.

    2012-08-01

    The zero energy community considered here consists of tens to tens-of-thousands of residences coupled to a central solar plant that produces all the community's electrical and thermal needs. A distribution network carries fluids to meet the heating and cooling loads. Large central solar systems can significantly reduce cost of energy vs. single family systems, and they enable economical seasonal heat storage. However, the thermal distribution system is costly. Conventional district heating/cooling systems use a water/glycol solution to deliver sensible energy. Piping is sized to meet the peak instantaneous load. A new district system introduced here differs in two key ways: (i) it continuously distributes a hot liquid desiccant (LD) solution to LD-based heating and cooling equipment in each home; and (ii) it uses central and local storage of both LD and heat to reduce flow rates to meet average loads. Results for piping sizes in conventional and LD thermal communities show that the LD zero energy community reduces distribution piping diameters meeting heating loads by {approx}5X and meeting cooling loads by {approx}8X for cooling, depending on climate.

  12. Advanced Development and Market Penetration of Desiccant-Based Air-Conditioning Systems

    SciTech Connect (OSTI)

    Vineyard, E A; Sand, J R; Linkous, R L; Baskin, E; Mason, D

    1998-01-01

    Desiccant Air Conditioning Systems can be used as alternatives for conventional air conditioning equipment in any commercial or residential building.

  13. Open cycle liquid desiccant dehumidifier and hybrid solar/electric absorption refrigeration system. Annual report, January 1993--December 1993. Calendar year 1993

    SciTech Connect (OSTI)

    Nimmo, B.G.; Thornbloom, M.D.

    1995-04-01

    This annual report presents work performed during calendar year 1993 by the Florida Solar Energy Center under contract to the US Department of Energy. Two distinctively different solar powered indoor climate control systems were analyzed: the open cycle liquid desiccant dehumidifier, and an improved efficiency absorption system which may be fired by flat plate solar collectors. Both tasks represent new directions relative to prior FSEC research in Solar Cooling and Dehumidification.

  14. Lab Breakthrough: Desiccant Enhanced Evaporative Air Conditioning |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Desiccant Enhanced Evaporative Air Conditioning Lab Breakthrough: Desiccant Enhanced Evaporative Air Conditioning May 29, 2012 - 5:22pm Addthis This breakthrough combines desiccant materials, which remove moisture from the air using heat, and advanced evaporative technologies to develop a cooling unit that uses 90 percent less electricity and up to 80 percent less total energy than traditional air conditioning. This solution, called the desiccant enhanced evaporative air

  15. Desiccant Enhanced Evaporative Air-Conditioning (DEVap): Evaluation of a New Concept in Ultra Efficient Air Conditioning

    SciTech Connect (OSTI)

    Kozubal, E.; Woods, J.; Burch, J.; Boranian, A.; Merrigan, T.

    2011-01-01

    NREL has developed the novel concept of a desiccant enhanced evaporative air conditioner (DEVap) with the objective of combining the benefits of liquid desiccant and evaporative cooling technologies into an innovative 'cooling core.' Liquid desiccant technologies have extraordinary dehumidification potential, but require an efficient cooling sink. DEVap's thermodynamic potential overcomes many shortcomings of standard refrigeration-based direct expansion cooling. DEVap decouples cooling and dehumidification performance, which results in independent temperature and humidity control. The energy input is largely switched away from electricity to low-grade thermal energy that can be sourced from fuels such as natural gas, waste heat, solar, or biofuels.

  16. Distributed Energy Technology Characterization (Desiccant Technologies),

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2004 | Department of Energy Characterization (Desiccant Technologies), January 2004 Distributed Energy Technology Characterization (Desiccant Technologies), January 2004 The purpose of this report is to characterize desiccant technology and applications, and to show how these technologies can be designed to utilize the available thermal energy from a combined heat and power (CHP) system. This technology characterization is intended to provide decision-makers and system developers

  17. Desiccant cooling: State-of-the-art assessment

    SciTech Connect (OSTI)

    Pesaran, A.A.; Penney, T.R.; Czanderna, A.W.

    1992-10-01

    The objectives of this document are to present an overview of the work accomplished to date on desiccant cooling to provide assessment of the state of the art of desiccant cooling technology in the field of desiccant material dehumidifier components, desiccant systems, and models. The report also discusses the factors that affect the widespread acceptance of desiccant cooling technology. This report is organized as follows. First, a basic description and historical overview of desiccant cooling technology is provided. Then, the recent research and development (R D) program history (focusing on DOE's funded efforts) is discussed. The status of the technology elements (materials, components, systems) is discussed in detail and a preliminary study on the energy impact of desiccant technology is presented. R D needs for advancing the technology in the market are identified. The National Renewable Energy Laboratory's unique desiccant test facilities and their typical outputs are described briefly. Finally, the results of a comprehensive literature search on desiccant cooling are presented in a bibliography. The bibliography contains approximately 900 citations on desiccant cooling.

  18. Desiccant cooling: State-of-the-art assessment

    SciTech Connect (OSTI)

    Pesaran, A.A.; Penney, T.R.; Czanderna, A.W.

    1992-10-01

    The objectives of this document are to present an overview of the work accomplished to date on desiccant cooling to provide assessment of the state of the art of desiccant cooling technology in the field of desiccant material dehumidifier components, desiccant systems, and models. The report also discusses the factors that affect the widespread acceptance of desiccant cooling technology. This report is organized as follows. First, a basic description and historical overview of desiccant cooling technology is provided. Then, the recent research and development (R&D) program history (focusing on DOE`s funded efforts) is discussed. The status of the technology elements (materials, components, systems) is discussed in detail and a preliminary study on the energy impact of desiccant technology is presented. R&D needs for advancing the technology in the market are identified. The National Renewable Energy Laboratory`s unique desiccant test facilities and their typical outputs are described briefly. Finally, the results of a comprehensive literature search on desiccant cooling are presented in a bibliography. The bibliography contains approximately 900 citations on desiccant cooling.

  19. Desiccant Enhanced Evaporative Air Conditioning: Parametric Analysis and Design; Preprint

    SciTech Connect (OSTI)

    Woods, J.; Kozubal, E.

    2012-10-01

    This paper presents a parametric analysis using a numerical model of a new concept in desiccant and evaporative air conditioning. The concept consists of two stages: a liquid desiccant dehumidifier and a dew-point evaporative cooler. Each stage consists of stacked air channel pairs separated by a plastic sheet. In the first stage, a liquid desiccant film removes moisture from the process (supply-side) air through a membrane. An evaporatively-cooled exhaust airstream on the other side of the plastic sheet cools the desiccant. The second-stage indirect evaporative cooler sensibly cools the dried process air. We analyze the tradeoff between device size and energy efficiency. This tradeoff depends strongly on process air channel thicknesses, the ratio of first-stage to second-stage area, and the second-stage exhaust air flow rate. A sensitivity analysis reiterates the importance of the process air boundary layers and suggests a need for increasing airside heat and mass transfer enhancements.

  20. Breakthrough Video: Desiccant Enhanced Evaporative Air Conditioning

    SciTech Connect (OSTI)

    2012-01-01

    Researchers at the National Renewable Energy Laboratory (NREL) invented a breakthrough technology that improves air conditioning in a novel way—with heat. NREL combined desiccant materials, which remove moisture from the air using heat, and advanced evaporative technologies to develop a cooling unit that uses 90% less electricity and up to 80% less total energy than traditional air conditioning (AC). This solution, called the desiccant enhanced evaporative air conditioner (DEVAP), also controls humidity more effectively to improve the comfort of people in buildings.

  1. Composite desiccant structure

    DOE Patents [OSTI]

    Fraioli, Anthony V. (Hawthorn Woods, IL); Schertz, William W. (Batavia, IL)

    1987-01-01

    A composite formed of small desiccant particles retained in a dark matrix composed of a porous binder containing a transition metal oxide with pores to provide moisture transport with respect to the particles, and metallic fibers to remove the heat of condensation during dehumidification and provide heat for the removal of moisture during regeneration. The moisture absorbing properties of the composite may be regenerated by exposure of the dark matrix to solar radiation with dehumidification occurring at night.

  2. Composite desiccant structure

    DOE Patents [OSTI]

    Fraioli, A.V.; Schertz, W.W.

    1984-06-06

    This patent discloses a composite formed of small desiccant particles retained in a dark matrix composed of a porous binder containing a transition metal oxide with pores to provide moisture transport with respect to the particles, and metallic fibers to remove the heat of condensation during dehumidification and provide heat for the removal of moisture during regeneration. The moisture absorbing properties of the composite may be regenerated by exposure of the dark matrix to solar radiation with dehumidification occurring at night.

  3. Method and apparatus for extracting water from air using a desiccant

    DOE Patents [OSTI]

    Spletzer, Barry L.; Callow, Diane Schafer

    2003-01-01

    The present invention provides a method and apparatus for extracting liquid water from moist air using minimal energy input. The method can be considered as four phases: (1) adsorbing water from air into a desiccant, (2) isolating the water-laden desiccant from the air source, (3) desorbing water as vapor from the desiccant into a chamber, and (4) isolating the desiccant from the chamber, and compressing the vapor in the chamber to form liquid condensate. The liquid condensate can be removed for use. Careful design of the dead volumes and pressure balances can minimize the energy required. The dried air can be exchanged for fresh moist air and the process repeated. An apparatus comprises a first chamber in fluid communication with a desiccant, and having ports to intake moist air and exhaust dried air. The apparatus also comprises a second chamber in fluid communication with the desiccant. The second chamber allows variable internal pressure, and has a port for removal of liquid condensate. Each chamber can be configured to be isolated or in communication with the desiccant. The first chamber can be configured to be isolated or in communication with a course of moist air. Various arrangements of valves, pistons, and chambers are described.

  4. Desiccant contamination research: Report on the desiccant contamination test facility

    SciTech Connect (OSTI)

    Pesaran, A.A.; Bingham, C.E.

    1991-07-01

    The activity in the cooling systems research involves research on high performance dehumidifiers and chillers that can operate efficiently with the variable thermal outputs and delivery temperatures associated with solar collectors. It also includes work on advanced passive cooling techniques. This report describes the work conducted to improve the durability of solid desiccant dehumidifiers by investigating the causes of degradation of desiccant materials from airborne contaminants and thermal cycling. The performance of a dehumidifier strongly depends on the physical properties and durability of the desiccant material. To make durable and reliable dehumidifiers, an understanding is needed of how and to what degree the performance of a dehumidifier is affected by desiccant degradation. This report, an account of work under Cooling Systems Research, documents the efforts to design and fabricate a test facility to investigate desiccant contamination based on industry and academia recommendations. It also discusses the experimental techniques needed for obtaining high-quality data and presents plans for next year. Researchers of the Mechanical and Industrial Technology Division performed this work at the Solar Energy Research Institute in FY 1988 for DOE's Office of Solar Heat Technologies. 7 refs., 19 figs., 1 tab.

  5. Desiccant-based dehumidification system and method

    DOE Patents [OSTI]

    Fischer, John C.

    2004-06-22

    The present invention provides an apparatus for dehumidifying air supplied to an enclosed space by an air conditioning unit. The apparatus includes a partition separating the interior of the housing into a supply portion and a regeneration portion. The supply portion has an inlet for receiving supply air from the air conditioning unit and an outlet for supplying air to the enclosed space. A regeneration fan creates the regeneration air stream. The apparatus includes an active desiccant wheel positioned such that a portion of the wheel extends into the supply portion and a portion of the wheel extends into the regeneration portion, so that the wheel can rotate through the supply air stream and the regeneration air stream to dehumidify the supply air stream. A heater warms the regeneration air stream as necessary to regenerate the desiccant wheel. The invention also comprises a hybrid system that combines air conditioning and dehumidifying components into a single integrated unit.

  6. Desiccant Cooling Poised for Entry into Mainstream Markets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Desiccant Cooling Poised for Entry into Mainstream Markets For more information contact: Kerry Masson, (303) 275-4083 Golden, Colo., March 24, 1997 -- Heating and cooling systems manufacturers and members of the emerging desiccant cooling industry recently gathered at the U.S. Department of Energy's National Renewable Energy Laboratory to assess progress in a two-year research program aimed at expanding markets for gas-fired desiccant cooling and dehumidifying systems. The new technology

  7. Development of a Very Dense Liquid Cooled Compute Platform

    SciTech Connect (OSTI)

    Hughes, Phillip N.; Lipp, Robert J.

    2013-12-10

    The objective of this project was to design and develop a prototype very energy efficient high density compute platform with 100% pumped refrigerant liquid cooling using commodity components and high volume manufacturing techniques. Testing at SLAC has indicated that we achieved a DCIE of 0.93 against our original goal of 0.85. This number includes both cooling and power supply and was achieved employing some of the highest wattage processors available.

  8. Development of characterization protocol for mixed liquid radioactive waste classification

    SciTech Connect (OSTI)

    Zakaria, Norasalwa; Wafa, Syed Asraf; Wo, Yii Mei; Mahat, Sarimah

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as ‘problematic’ waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this study is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.

  9. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Interim Post-Desiccation Monitoring Results, Fiscal Year 2014

    SciTech Connect (OSTI)

    Truex, Michael J.; Strickland, Christopher E.; Johnson, Christian D.; Johnson, Timothy C.; Clayton, Ray E.; Chronister, Glen B.

    2014-09-01

    Over decades of operation, the U.S. Department of Energy (DOE) and its predecessors have released nearly 2 trillion L (450 billion gal.) of liquid into the vadose zone at the Hanford Site. Much of this discharge of liquid waste into the vadose zone occurred in the Central Plateau, a 200 km2 (75 mi2) area that includes approximately 800 waste sites. Some of the inorganic and radionuclide contaminants in the deep vadose zone at the Hanford Site are at depths below the limit of direct exposure pathways, but may need to be remediated to protect groundwater. The Tri-Party Agencies (DOE, U.S. Environmental Protection Agency, and Washington State Department of Ecology) established Milestone M 015 50, which directed DOE to submit a treatability test plan for remediation of technetium-99 (Tc-99) and uranium in the deep vadose zone. These contaminants are mobile in the subsurface environment and have been detected at high concentrations deep in the vadose zone, and at some locations have reached groundwater. Testing technologies for remediating Tc-99 and uranium will also provide information relevant for remediating other contaminants in the vadose zone. A field test of desiccation is being conducted as an element of the DOE test plan published in March 2008 to meet Milestone M 015 50. The active desiccation portion of the test has been completed. Monitoring data have been collected at the field test site during the post-desiccation period and are reported herein. This is an interim data summary report that includes about 3 years of post-desiccation monitoring data. The DOE field test plan proscribes a total of 5 years of post-desiccation monitoring.

  10. Heavy liquid beneficiation developed for Alabama tar sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    The tar sand deposits in the State of Alabama contain about 1.8 billion barrels of measured and more than 4 billion barrels of speculative in-place bitumen. A comprehensive research program is in progress for the separation of bitumen from these deposits. In general, Alabama tar sands are oil wetted, low grade and highly viscous in nature. In view of these facts, a beneficiation strategy has been developed to recover bitumen enriched concentrate which can be used as a feed material for further processing. Heavy liquid separation tests and results are discussed. A 77% zinc bromide solution, specific gravity of 2.4, was used for the tests. 2 figures.

  11. Development of an Ionic-Liquid Absorption Heat Pump

    SciTech Connect (OSTI)

    Holcomb, Don

    2011-03-29

    Solar Fueled Products (SFP) is developing an innovative ionic-liquid absorption heat pump (ILAHP). The development of an ILAHP is extremely significant, as it could result in annual savings of more than 190 billion kW h of electrical energy and $19 billion. This absorption cooler uses about 75 percent less electricity than conventional cooling and heating units. The ILAHP also has significant environmental sustainability benefits, due to reduced CO2 emissions. Phase I established the feasibility and showed the economic viability of an ILAHP with these key accomplishments: • Used the breakthrough capabilities provided by ionic liquids which overcome the key difficulties of the common absorption coolers. • Showed that the theoretical thermodynamic performance of an ILAHP is similar to existing absorption-cooling systems. • Established that the half-effect absorption cycle reduces the peak generator temperature, improving collector efficiency and reducing collector area. • Component testing demonstrated that the most critical components, absorber and generator, operate well with conventional heat exchangers. • Showed the economic viability of an ILAHP. The significant energy savings, sustainability benefits, and economic viability are compelling reasons to continue the ILAHP development.

  12. Design, Installation, and Field Verification of Integrated Active Desiccant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid Rooftop Systems Combined with a Natural Gas Driven Cogeneration Package, 2008 | Department of Energy Design, Installation, and Field Verification of Integrated Active Desiccant Hybrid Rooftop Systems Combined with a Natural Gas Driven Cogeneration Package, 2008 Design, Installation, and Field Verification of Integrated Active Desiccant Hybrid Rooftop Systems Combined with a Natural Gas Driven Cogeneration Package, 2008 This report summarizes a research/demonstration project in which a

  13. Moving Advanced Desiccant Materials into Mainstream Non-CFC Cooling Products

    SciTech Connect (OSTI)

    Sand, J R; Grossman, G; Rice, C K; Fairchild, P D; Gross, I L

    1994-01-01

    Desiccant air-conditioning systems can be used as alternatives for conventional air-conditioning equipment in any commercial or residential building. Recent breakthroughs in desiccant materials technology and the creation of new markets by Indoor Air Quality issues make desiccant-based air-conditioning equipment practical for many space-conditioning applications.

  14. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Interim Post-Desiccation Monitoring Results

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Johnson, Timothy C.; Johnson, Christian D.; Clayton, Ray E.; Chronister, Glen B.

    2013-09-01

    A field test of desiccation is being conducted as an element of the deep vadose zone treatability test program. Desiccation technology relies on removal of water from a portion of the subsurface such that the resultant low moisture conditions inhibit downward movement of water and dissolved contaminants. Previously, a field test report (Truex et al. 2012a) was prepared describing the active desiccation portion of the test and initial post-desiccation monitoring data. Additional monitoring data have been collected at the field test site during the post-desiccation period and is reported herein along with interpretation with respect to desiccation performance. This is an interim report including about 2 years of post-desiccation monitoring data.

  15. Deep Vadose Zone Treatability Test for the Hanford Central Plateau. Interim Post-Desiccation Monitoring Results, Fiscal Year 2015

    SciTech Connect (OSTI)

    Truex, Michael J.; Strickland, Christopher E.; Oostrom, Martinus; Johnson, Christian D.; Tartakovsky, Guzel D.; Johnson, Timothy C.; Clayton, Ray E.; Chronister, Glen B.

    2015-09-01

    A field test of desiccation is being conducted as an element of the Deep Vadose Zone Treatability Test Program. The active desiccation portion of the test has been completed. Monitoring data have been collected at the field test site during the post-desiccation period and are reported herein. This is an interim data summary report that includes about 4 years of post-desiccation monitoring data. The DOE field test plan proscribes a total of 5 years of post-desiccation monitoring.

  16. Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing, April 2013

    Broader source: Energy.gov [DOE]

    Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing

  17. STANDARDS CONTROLLING AIR EMISSIONS FOR THE SOIL DESICCATION PILOT TEST

    SciTech Connect (OSTI)

    BENECKE MW

    2010-09-08

    This air emissions document supports implementation of the Treatability Test Plan for Soil Desiccation as outlined in the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DOE/RL-2007-56). Treatability testing supports evaluation of remedial technologies for technetium-99 (Tc-99) contamination in the vadose zone at sites such as the BC Cribs and Trenches. Soil desiccation has been selected as the first technology for testing because it has been recommended as a promising technology in previous Hanford Site technology evaluations and because testing of soil desiccation will provide useful information to enhance evaluation of other technologies, in particular gas-phase remediation technologies. A soil desiccation pilot test (SDPT) will evaluate the desiccation process (e.g., how the targeted interval is dried) and the long-term performance for mitigation of contaminant transport. The SDPT will dry out a moist zone contaminated by Tc-99 and nitrate that has been detected at Well 299-E13-62 (Borehole C5923). This air emissions document applies to the activities to be completed to conduct the SDPT in the 200-BC-1 operable unit located in the 200 East Area of the Hanford Site. Well 299-E13-62 is planned to be used as an injection well. This well is located between and approximately equidistant from cribs 216-B-16, 216-B-17, 216-B-18. and 216-B-19. Nitrogen gas will be pumped at approximately 300 ft{sup 3}/min into the 299-EI3-62 injection well, located approximately 12 m (39 ft) away from extraction well 299-EI3-65. The soil gas extraction rate will be approximately 150 ft{sup 3}/min. The SDPT will be conducted continuously over a period of approximately six months. The purpose of the test is to evaluate soil desiccation as a potential remedy for protecting groundwater. A conceptual depiction is provided in Figure 1. The soil desiccation process will physically dry, or evaporate, some of the water from the moist zone of interest. As such, it is expected that Tc-99 and nitrate will remain with the water residual that is not removed, or remain as a salt bound to the soil particles. In addition, the SDPT will be conducted at lower extraction velocities to preclude pore water entrainment and thus, the extracted air effluent should be free of the contaminant residual present in the targeted moist zone. However, to conservatively bound the planned activity for potential radionuclide air emissions, it is assumed, hypothetically, that the Tc-99 does not remain in the zone of interest, but that it instead travels with the evaporated moisture to the extraction well and to the test equipment at the land surface. Thus, a release potential would exist from the planned point source (powered exhaust) for Tc-99 in the extracted moist air. In this hypothetical bounding case there would also be a potential for very minor fugitive emissions to occur due to nitrogen injection into the soil. The maximum value for Tc-99, measured in the contaminated moist zone, is used in calculating the release potential described in Section 2.3. The desiccation mechanism will be evaporation. Nitrate is neither a criteria pollutant nor a toxic air pollutant. It would remain nitrate as a salt adhered to sand and silt grains or as nitrate dissolved in the pore water. Nitrogen, an inert gas, will be injected into the ground during the test. Tracer gasses will also be injected near the beginning, middle, and the end of the test. The tracer gasses are sulfur hexafluoride, trichlorofluoromethane, and difluoromethane.

  18. Method and composition for molding low density desiccant syntactic foam articles

    DOE Patents [OSTI]

    Lula, James W. (Bonner Springs, KS); Schicker, James R. (Lee's Summit, MO)

    1984-01-01

    A method and a composition are provided for molding low density desiccant syntactic foam articles. A low density molded desiccant article may be made as a syntactic foam by blending a thermosetting resin, microspheres and molecular sieve desiccant powder, molding and curing. Such articles have densities of 0.2-0.9 g/cc, moisture capacities of 1-12% by weight, and can serve as light weight structural supports.

  19. Design of a test facility for gas-fired desiccant-based air conditioning systems

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A.A.; Steele, W.G.; Hodge, B.K.

    1996-12-31

    The design of a facility for testing desiccant-based air conditioning systems is presented. The determination of the performance parameters of desiccant systems is discussed including moisture removal capacity, latent and total cooling capacities, and efficiency indexes. The appropriate procedures and key measurements for determining these parameters are identified using uncertainty analysis.

  20. Laboratory and Modeling Evaluations in Support of Field Testing for Desiccation at the Hanford Site

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Freedman, Vicky L.; Strickland, Christopher E.; Wietsma, Thomas W.; Tartakovsky, Guzel D.; Ward, Anderson L.

    2011-02-23

    The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau includes testing of the desiccation technology as a potential technology to be used in conjunction with surface infiltration control to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. Laboratory and modeling efforts were conducted to investigate technical uncertainties related to the desiccation process and its impact on contaminant transport. This information is intended to support planning, operation, and interpretation of a field test for desiccation in the Hanford Central Plateau.

  1. Development of Hydrothermal Liquefaction and Upgrading Technologies for Lipid-Extracted Algae Conversion to Liquid Fuels

    SciTech Connect (OSTI)

    Zhu, Yunhua; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Jones, Susanne B.

    2013-10-01

    Bench-scale tests were performed for lipid-extracted microalgae (LEA) conversion to liquid fuels via hydrotreating liquefaction (HTL) and upgrading processes. Process simulation and economic analysis for a large-scale LEA HTL and upgrading system were developed based on the best available test results. The system assumes an LEA feed rate of 608 dry metric ton/day and that the feedstock is converted to a crude HTL bio-oil and further upgraded via hydrotreating and hydrocracking to produce liquid hydrocarbon fuels, mainly alkanes. Performance and cost results demonstrate that HTL would be an effective option to convert LEA to liquid fuel. The liquid fuels annual yield was estimated to be 26.9 million gallon gasoline-equivalent and the overall energy efficiency at higher heating value basis was estimated to be 69.5%. The minimum fuel selling price (MFSP) was estimated to be $0.75/L with LEA feedstock price at $33.1 metric ton at dry basis and 10% internal rate of return. A sensitivity analysis indicated that the largest effects to production cost would come from the final products yields and the upgrading equipments cost. The impact of plant scale on MFSP was also investigated.

  2. Development of a low background liquid scintillation counter for a shallow underground laboratory

    SciTech Connect (OSTI)

    Erchinger, Jennifer L.; Aalseth, Craig E.; Bernacki, Bruce E.; Douglas, Matthew; Fuller, Erin S.; Keillor, Martin E.; Morley, Shannon M.; Mullen, Crystal A.; Orrell, John L.; Panisko, Mark E.; Warren, Glen A.; Williams, Russell O.; Wright, Michael E.

    2015-08-20

    Pacific Northwest National Laboratory has recently opened a shallow underground laboratory intended for measurement of lowconcentration levels of radioactive isotopes in samples collected from the environment. The development of a low-background liquid scintillation counter is currently underway to further augment the measurement capabilities within this underground laboratory. Liquid scintillation counting is especially useful for measuring charged particle (e.g., B, a) emitting isotopes with no (orvery weak) gamma-ray yields. The combination of high-efficiency detection of charged particle emission in a liquid scintillation cocktail coupled with the low-background environment of an appropriately-designed shield located in a clean underground laboratory provides the opportunity for increased-sensitivity measurements of a range of isotopes. To take advantage of the 35-meter water-equivalent overburden of the underground laboratory, a series of simulations have evaluated the instrumental shield design requirements to assess the possible background rate achievable. This report presents the design and background evaluation for a shallow underground, low background liquid scintillation counter design for sample measurements.

  3. Experimental and Numerical Investigations of Soil Desiccation for Vadose Zone Remediation: Report for Fiscal Year 2007

    SciTech Connect (OSTI)

    Ward, Andy L.; Oostrom, Mart; Bacon, Diana H.

    2008-02-04

    Apart from source excavation, the options available for the remediation of vadose zone metal and radionuclide contaminants beyond the practical excavation depth (0 to 15 m) are quite limited. Of the available technologies, very few are applicable to the deep vadose zone with the top-ranked candidate being soil desiccation. An expert panel review of the work on infiltration control and supplemental technologies identified a number of knowledge gaps that would need to be overcome before soil desiccation could be deployed. The report documents some of the research conducted in the last year to fill these knowledge gaps. This work included 1) performing intermediate-scale laboratory flow cell experiments to demonstrate the desiccation process, 2) implementing a scalable version of Subsurface Transport Over Multiple Phases–Water-Air-Energy (STOMP-WAE), and 3) performing numerical experiments to identify the factors controlling the performance of a desiccation system.

  4. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Soil Desiccation Pilot Test Results

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Johnson, Timothy C.; Freedman, Vicky L.; Johnson, Christian D.; Greenwood, William J.; Ward, Anderson L.; Clayton, Ray E.; Lindberg, Michael J.; Peterson, John E.; Hubbard, Susan; Chronister, Glen B.; Benecke, Mark W.

    2012-05-01

    This report describes results of a pilot test of soil desiccation conducted as part of the Deep Vadose Zone Treatability Test program. The report is written in CERCLA treatabilty test report format.

  5. Method and composition for molding low-density desiccant syntactic-foam articles

    DOE Patents [OSTI]

    Not Available

    1981-12-07

    These and other objects of the invention are achieved by a process for molding to size a desiccant syntactic foam article having a density of 0.2 to 0.9 g/cc and a moisture capacity of 1 to 12% by weight, comprising the steps of: charging a mold with a powdery mixture of an activated desiccant, microspheres and a thermosetting resin, the amount of the desiccant being sufficient to provide the required moisture capacity, and the amounts of the microspheres and resin being such that the microspheres/desiccant volume fraction exceeds the packing factor by an amount sufficient to substantially avoid shrinkage without causing excessively high molding pressures; covering the mold and heating the covered mold to a temperature and for an amount of time sufficient to melt the resin; and tightly closing the mold and heating the closed mold to a temperature and for an amount of time sufficient to cure the resin, and removing the resultant desiccant syntactic foam article from the mold. In a composition of matter aspect, the present invention provides desiccant syntactic foam articles, and a composition of matter for use in molding the same.

  6. Liquid phase methanol LaPorte process development unit: Modification, operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1991-01-02

    Liquid-entrained operations at the LaPorte Liquid Phase Methanol (LPMEOH) Process Development Unit (PDU) continued during June and July 1988 under Tasks 2.1 and 2.2 of Contract No. DE-AC22-87PC90005 for the US Department of Energy. The primary focus of this PDU operating program was to prepare for a confident move to the next scale of operation with an optimized and simplified process. Several new design options had been identified and thoroughly evaluated in a detailed process engineering study completed under the LPMEOH Part-2 contract (DE-AC22-85PC80007), which then became the basis for the current PDU modification/operating program. The focus of the Process Engineering Design was to optimize and simplifications focused on the slurry loop, which consists of the reactor, vapor/liquid separator, slurry heat exchanger, and slurry circulation pump. Two-Phase Gas Holdup tests began at LaPorte in June 1988 with nitrogen/oil and CO- rich gas/oil systems. The purpose of these tests was to study the hydrodynamics of the reactor, detect metal carbonyl catalyst poisons, and train operating personnel. Any effect of the new gas sparger and the internal heat exchanger would be revealed by comparing the hydrodynamic data with previous PDU hydrodynamic data. The Equipment Evaluation'' Run E-5 was conducted at the LaPorte LPMEOH PDU in July 1988. The objective of Run E-5 was to systematically evaluate each new piece of equipment (sparger, internal heat exchanger, V/L disengagement zone, demister, and cyclone) which had been added to the system, and attempt to run the reactor in an internal-only mode. In addition, a successful catalyst activation with a concentrated (45 wt % oxide) slurry was sought. 9 refs., 26 figs., 15 tabs.

  7. Effects of temperature on desiccant catalysis of refrigerant and lubricant decomposition. Final report

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.

    1998-06-01

    Accelerated aging at high temperatures (149 C) for short aging times (28 days) is effective in screening the compatibility of different materials in refrigeration systems. However, in actual applications temperatures are usually lower and operating times much longer. Therefore plots to allow for interpolation or extrapolation of experimental data to actual operating conditions are needed. In the current study, aging of refrigerant/lubricant/desiccant/metal systems was conducted at five different temperatures, and for each temperature at four different aging times. The data collected from this study provided plots relating refrigerant or lubricant decomposition to aging time, aging temperature, and type of desiccant, which can be used for interpolation or extrapolation.

  8. Liquid phase methanol LaPorte process development unit: Modification, operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1990-10-23

    The objectives of this program are to implement and test the process improvements identified through the engineering studies of the current program to demonstrate the capability of long-term catalyst activity maintenance, and to perform process and design engineering work that can be applied to a scaled-up Liquid Phase Methanol (LPMEOH) facility. An optional series of PDU runs is offered to extend the testing of the process improvements. A parallel research program will be performed to enhance the LPMEOH technical data base to improve the likelihood of commercialization of the LPMEOH process. Activities this quarter include: Flow sheet development for La Porte PDU modifications continues. A preliminary P ID review was completed and flow sheet modifications were identified and are being incorporated. A preliminary hazards review was completed on 22 May. Some minor flow sheet modifications resulted and a number of action items were identified. The most significant action item is to develop a materials reactivity and compatibility grid for the different alcohols, ethers, and esters which will be produced at the PDU. Heat and material balances were completed for the maximum production case of the mixed DME/MEOH synthesis campaign. An improved rate expression was developed. 1 fig.

  9. Liquid phase methanol LaPorte process development unit: Modification operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1991-01-28

    In April 1987, Air Products started the third and final contract with the US Department of Energy to develop the Liquid Phase Methanol (LPMEOH) process. One of the objectives was to identify alternative commercial catalyst(s) for the process. This objective was strategically important as we want to demonstrate that the LPMEOH process is flexible and not catalyst selection limited. Among three commercially available catalysts evaluated in the lab, the catalyst with a designation of F21/0E75-43 was the most promising candidate. The initial judging criteria included not only the intrinsic catalyst activity but also the ability to be used effectively in a slurry reactor. The catalyst was then advanced for a 40-day life test in a laboratory 300 cc autoclave. The life test result also revealed superior stability when compared with that of a standard catalyst. Consequently, the new catalyst was recommended for demonstration in the Process Development Unit (PDU) at LaPorte, Texas. This report details the methodology of testing and selecting the catalyst.

  10. Sensor and numerical simulator evaluation for porous medium desiccation and rewetting at the intermediate laboratory scale

    SciTech Connect (OSTI)

    Oostrom, Martinus; Wietsma, Thomas W.; Strickland, Christopher E.; Freedman, Vicky L.; Truex, Michael J.

    2012-02-01

    Soil desiccation, in conjunction with surface infiltration control, is considered at the Hanford Site as a potential technology to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. An intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media. The instruments include thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes. The experiment was simulated with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. All instrument types used for this experiment were able to indicate when the desiccation front passed a certain location. In most cases the changes were sharp, indicating rapid changes in moisture content, water potential, or humidity. However, a response to the changing conditions was recorded only when the drying front was very close to a sensor. Of the tested instruments, only the heat dissipation unit and humidity probes were able to detect rewetting. The numerical simulation results reasonably match the experimental data, indicating that the simulator captures the pertinent gas flow and transport processes related to desiccation and rewetting and may be useful in the design and analysis of field tests.

  11. Liquid-Liquid Separation Process: Cooperative Research and Development Final Report, CRADA Number CRD-09-362

    SciTech Connect (OSTI)

    Schell, D.

    2014-06-01

    The 3M Company, in collaboration with the National Renewable Energy Laboratory (NREL) and others, will develop the concept of the membrane solvent-extraction (MSE) technology for water removal and verify the technology at a pilot scale for bio-ethanol production to increase energy and water savings.

  12. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste

    SciTech Connect (OSTI)

    Digby D. Macdonald; Brian M. Marx; Sejin Ahn; Julio de Ruiz; Balaji Soundararaja; Morgan Smith; and Wendy Coulson

    2008-01-15

    Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprised of NaOH and NaNO{sub 3}, along with trace amounts of phosphate, sulfate, carbonate, and chloride. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair. The different tasks that are being carried out under the current program are as follows: (1) Theoretical and experimental assessment of general corrosion of iron/steel in borate buffer solutions by using electrochemical impedance spectroscopy (EIS), ellipsometry and XPS techniques; (2) Development of a damage function analysis (DFA) which would help in predicting the accumulation of damage due to pitting corrosion in an environment prototypical of DOE liquid waste systems; (3) Experimental measurement of crack growth rate, acoustic emission signals and coupling currents for fracture in carbon and low alloy steels as functions of mechanical (stress intensity), chemical (conductivity), electrochemical (corrosion potential, ECP), and microstructural (grain size, precipitate size, etc) variables in a systematic manner, with particular attention being focused on the structure of the noise in the current and its correlation with the acoustic emissions; (4) Development of fracture mechanisms for carbon and low alloy steels that are consistent with the crack growth rate, coupling current data and acoustic emissions; (5) Inserting advanced crack growth rate models for SCC into existing deterministic codes for predicting the evolution of corrosion damage in DOE liquid waste storage tanks; (6) Computer simulation of the anodic and cathodic activity on the surface of the steel samples in order to exactly predict the corrosion mechanisms; (7) Wavelet analysis of EC noise data from steel samples undergoing corrosion in an environment similar to that of the high level waste storage containers, to extract data pertaining to general, pitting and stress corrosion processes, from the overall data. The Point Defect Model (PDM) is directly applied as the theoretical assessment method for describing the passive film formed on iron/steels. The PDM is used to describe general corrosion in the passive region of iron. In addition, previous work suggests that pit formation is due to the coalescence of cation vacancies at the metal/film interface which would make it possible to use the PDM parameters to predict the onset of pitting. This previous work suggests that once the critical vacancy density is reached, the film ruptures to form a pit. Based upon the kinetic parameters derived for the general corrosion case, two parameters relating to the cation vacancy formation and annihilation can be calculated. These two parameters can then be applied to predict the transition from general to pitting corrosion for iron/mild steels. If cation vacancy coalescence is shown to lead to pitting, it can have a profound effect on the direction of future studies involving the onset of pitting corrosion. The work has yielded a number of important findings, including an unequivocal demonstration of the role of chloride ion in passivity breakdown on nickel in terms of cation vacancy generation within the passive film, the first detection and characterization of individual micro fracture events in stress corrosion cracking, and the determination of kinetic parameters for the generation and annihilation of point defects in the passive film on iron. The existence of coupling between the internal crack environment and the external cathodic environment, as predicted by the coupled environment fracture model (CEFM), has also been indisputably established for the AISI 4340/NaOH system. It is evident from the studies that analysis of coupling current noise is a very sensitive tool f

  13. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste

    SciTech Connect (OSTI)

    Digby Macdonald; Brian Marx; Balaji Soundararajan; Morgan Smith

    2005-07-28

    The different tasks that have been carried out under the current program are as follows: (1) Theoretical and experimental assessment of general corrosion of iron/steel in borate buffer solutions by using electrochemical impedance spectroscopy (EIS), ellipsometry and XPS techniques; (2) Development of a damage function analysis (DFA), which would help in predicting the accumulation of damage due to pitting corrosion in an environment prototypical of DOE liquid waste systems; (3) Experimental measurement of crack growth rate, acoustic emission signals, and coupling currents for fracture in carbon and low alloy steels as functions of mechanical (stress intensity), chemical (conductivity), electrochemical (corrosion potential, ECP), and microstructural (grain size, precipitate size, etc) variables in a systematic manner, with particular attention being focused on the structure of the noise in the current and its correlation with the acoustic emissions; (4) Development of fracture mechanisms for carbon and low alloy steels that are consistent with the crack growth rate, coupling current data and acoustic emissions; (5) Inserting advanced crack growth rate models for SCC into existing deterministic codes for predicting the evolution of corrosion damage in DOE liquid waste storage tanks; (6) Computer simulation of the anodic and cathodic activity on the surface of the steel samples in order to exactly predict the corrosion mechanisms; (7) Wavelet analysis of EC noise data from steel samples undergoing corrosion in an environment similar to that of the high level waste storage containers, to extract data pertaining to general, pitting and stress corrosion processes, from the overall data. The work has yielded a number of important findings, including an unequivocal demonstration of the role of chloride ion in passivity breakdown on nickel in terms of cation vacancy generation within the passive film, the first detection and characterization of individual micro fracture events in stress corrosion cracking, and the determination of kinetic parameters for the generation and annihilation of point defects in the passive film on iron. The existence of coupling between the internal crack environment and the external cathodic environment, as predicted by the coupled environment fracture model (CEFM), has also been indisputably established for the AISI 4340/NaOH system. It is evident from the studies that analysis of coupling current noise is a very sensitive tool for studying the crack tip processes in relation to the chemical, mechanical, electrochemical, and microstructural properties of the system. Experiments are currently being carried out to explore these crack tip processes by simultaneous measurement of the acoustic activity at the crack tip in an effort to validate the coupling current data. These latter data are now being used to deterministically predict the accumulation of general and localized corrosion damage on carbon in prototypical DOE liquid waste storage tanks. Computer simulation of the cathodic and anodic activity on the steel surfaces is also being carried out in an effort to simulate the actual corrosion process. Wavelet analysis of the coupling current data promises to be a useful tool to differentiate between the different corrosion mechanisms. Hence, wavelet analysis of the coupling current data from the DOE waste containers is also being carried out to extract data pertaining to general, pitting and stress corrosion processes, from the overall data which is bound to contain noise fluctuations due to any or all of the above mentioned processes.

  14. Liquid phase fluid dynamic (methanol) run in the LaPorte alternative fuels development unit

    SciTech Connect (OSTI)

    Bharat L. Bhatt

    1997-05-01

    A fluid dynamic study was successfully completed in a bubble column at DOE's Alternative Fuels Development Unit (AFDU) in LaPorte, Texas. Significant fluid dynamic information was gathered at pilot scale during three weeks of Liquid Phase Methanol (LPMEOJP) operations in June 1995. In addition to the usual nuclear density and temperature measurements, unique differential pressure data were collected using Sandia's high-speed data acquisition system to gain insight on flow regime characteristics and bubble size distribution. Statistical analysis of the fluctuations in the pressure data suggests that the column was being operated in the churn turbulent regime at most of the velocities considered. Dynamic gas disengagement experiments showed a different behavior than seen in low-pressure, cold-flow work. Operation with a superficial gas velocity of 1.2 ft/sec was achieved during this run, with stable fluid dynamics and catalyst performance. Improvements included for catalyst activation in the design of the Clean Coal III LPMEOH{trademark} plant at Kingsport, Tennessee, were also confirmed. In addition, an alternate catalyst was demonstrated for LPMEOH{trademark}.

  15. Development of Geothermally Assisted Process for Production of Liquid Fuels and Chemicals from Wheat Straw

    SciTech Connect (OSTI)

    Murphy, V.G.; Linden, J.C.; Moreira, A.R.; Lenz, T.G.

    1981-06-01

    Recently there has been much interest in developing processes for producing liquid fuels from renewable resources. The most logical long term approach in terms of economics derives the carbohydrate substrate for fermentation from the hydrolysis of cellulosic crop and forest residues rather than from grains or other high grade food materials (1,2). Since the presence of lignin is the main barrier to the hydrolysis of cellulose from lignocellulosic materials, delignification processes developed by the wood pulping industry have been considered as possible prehydrolysis treatments. The delignification process under study in our laboratory is envisioned as a synthesis of two recently developed pulping processes. In the first step, called autohydrolysis, hot water is used directly to solubilize hemicellulose and to depolymerize lignin (3). Then, in a second step known as organosolv pulping (4), the autohydrolyzed material is extracted with aqueous alcohol. A s shown in Figure 1, this process can separate the original lignocellulosic material into three streams--hemicellulose in water, lignin in aqueous alcohol, and a cellulose pulp. Without further mechanical milling, delignified cellulose can be enzymatically hydrolyzed at 45-50 C to greater than 80% theoretical yield of glucose using fungal cellulases (5, 6). The resulting glucose syrup can then be fermented by yeast to produce ethanol or by selected bacteria to produce acetone and butanol or acetic and propionic acids (7). One objection to such a process, however, is the large energy input that is required. In order to extend our supplies of liquid fuels and chemicals, it is important that the use of fossil fuels in any lignocellulosic conversion process be minimized. The direct use of geothermal hot water in carrying out the autohydrolysis and extraction operations, therefore, seems especially attractive. On the one hand, it facilitates the conversion of non-food biomass to fuels and chemicals without wasting fossil fuel; and on the other hand, it provides a means for ''exporting'' geothermal energy from the well site. The primary goal of the work discussed in this report was to investigate the effects of variations in autohydrolysis conditions on the production of fermentable sugars from wheat straw. In assessing the relative merits of various sets of conditions, we considered both the direct production of sugar from the autohydrolysis of hemicellulose and the subsequent yield from the enzymatic hydrolysis of cellulose. The principal parameters studied were time, temperature, and water/fiber weight ratio; however, we also investigated the effects of adding minor amounts of phenol and aluminum sulfate to the autohydrolysis charge. Phenol was selected for study because it was reported (8) to be effective in suppressing repolymerization of reactive lignin fragments. Aluminum sulfate, on the other hand, was chosen as a representative of the Lewis acids which, we hoped, would catalyze the delignification reactions.

  16. Development and Optimization of a Flocculation Procedure for Improved Solid-Liquid Separation of Digested Biomass

    SciTech Connect (OSTI)

    Patton, Caroline; Lischeske, James J.; Sievers, David A.

    2015-11-03

    One viable treatment method for conversion of lignocellulosic biomass to biofuels begins with saccharification (thermochemical pretreatment and enzymatic hydrolysis), followed by fermentation or catalytic upgrading to fuels such as ethanol, butanol, or other hydrocarbons. The post-hydrolysis slurry is typically 4-8 percent insoluble solids, predominantly consisting of lignin. Suspended solids are known to inhibit fermentation as well as poison catalysts and obstruct flow in catalyst beds. Thus a solid-liquid separation following enzymatic hydrolysis would be highly favorable for process economics, however the material is not easily separated by filtration or gravimetric methods. Use of a polyacrylamide flocculant to bind the suspended particles in a corn stover hydrolyzate slurry into larger flocs (1-2mm diameter) has been found to be extremely helpful in improving separation. Recent and ongoing research on novel pretreatment methods yields hydrolyzate material with diverse characteristics. Therefore, we need a thorough understanding of rapid and successful flocculation design in order to quickly achieve process design goals. In this study potential indicators of flocculation performance were investigated in order to develop a rapid analysis method for flocculation procedure in the context of a novel hydrolyzate material. Flocculation conditions were optimized on flocculant type and loading, pH, and mixing time. Filtration flux of the hydrolyzate slurry was improved 170-fold using a cationic polyacrylamide flocculant with a dosing of approximately 22 mg flocculant/g insoluble solids at an approximate pH of 3. With cake washing, sugar recovery exceeded 90 percent with asymptotic yield at 15 L wash water/kg insoluble solids.

  17. Liquid phase methanol LaPorte process development unit: Modification, operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1990-11-09

    As part of the liquid phase methanol process development program the present study evaluated adsorptive schemes to remove catalyst poisons from coal gas at pilot scale. In addition to a lab test with coal gas from Coolwater, two field tests were performed at Great Plains with live coal gas. In the lab with Coolwater, gas iron carbonyl, carbonyl sulfide,and hydrogen sulfide were effectively removed from the coal gas. The capacities of H-Y zeolite and BPL carbon for Fe(CO){sub 5} agreed well with the previous bench scale results at similar CO{sub 2} partial pressure. COS appeared to be chemisorbed on FCA carbon; its capacity was non-regenerable by hot nitrogen purge. A Cu/Zn catalyst, used to remove H{sub 2}S adsorptively, worked adequately. With the adsorption system on-line, a downstream methanol catalyst showed stable activity for 120 hours of operation. In the two field tests, it was demonstrated that the Great Plains (GP) syngas could be treated by adsorption for LPMEOH process. The catalyst deactivation observed in the first field test was much improved in the second field test after regular (every three days) regeneration of the adsorbents was practiced. The absorption system, which was designed for the removal of iron/nickel carbonyls, hydrogen/carbonyl sulfide and hydrochloric acid, needed to be modified to accommodate other unexpected impurities, such as acetonitrile and ethylene which were observed during both field tests. A lab test with a simulated GP gas indicated that low CO{sub 2} content (0.5%) in the GP gas does not cause catalyst deactivation. Adjusting the CO{sub 2} content of the feed to 5% by CO{sub 2} addition, increased methanol productivity by 40% in both the lab and the second field test. 6 refs., 25 figs., 14 tabs.

  18. Desiccant Enhanced Evaporative Air-Conditioning (DEVap): Evaluation of a New Concept in Ultra Efficient Air Conditioning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Desiccant Enhanced Evaporative Air-Conditioning (DEVap): Evaluation of a New Concept in Ultra Efficient Air Conditioning Eric Kozubal, Jason Woods, Jay Burch, Aaron Boranian, and Tim Merrigan NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Technical Report NREL/TP-5500-49722 January 2011 Contract No. DE-AC36-08GO28308 Desiccant Enhanced Evaporative Air-Conditioning (DEVap):

  19. DEVELOPMENT OF METHODOLOGY AND FIELD DEPLOYABLE SAMPLING TOOLS FOR SPENT NUCLEAR FUEL INTERROGATION IN LIQUID STORAGE

    SciTech Connect (OSTI)

    Berry, T.; Milliken, C.; Martinez-Rodriguez, M.; Hathcock, D.; Heitkamp, M.

    2012-06-04

    This project developed methodology and field deployable tools (test kits) to analyze the chemical and microbiological condition of the fuel storage medium and determine the oxide thickness on the spent fuel basin materials. The overall objective of this project was to determine the amount of time fuel has spent in a storage basin to determine if the operation of the reactor and storage basin is consistent with safeguard declarations or expectations. This project developed and validated forensic tools that can be used to predict the age and condition of spent nuclear fuels stored in liquid basins based on key physical, chemical and microbiological basin characteristics. Key parameters were identified based on a literature review, the parameters were used to design test cells for corrosion analyses, tools were purchased to analyze the key parameters, and these were used to characterize an active spent fuel basin, the Savannah River Site (SRS) L-Area basin. The key parameters identified in the literature review included chloride concentration, conductivity, and total organic carbon level. Focus was also placed on aluminum based cladding because of their application to weapons production. The literature review was helpful in identifying important parameters, but relationships between these parameters and corrosion rates were not available. Bench scale test systems were designed, operated, harvested, and analyzed to determine corrosion relationships between water parameters and water conditions, chemistry and microbiological conditions. The data from the bench scale system indicated that corrosion rates were dependent on total organic carbon levels and chloride concentrations. The highest corrosion rates were observed in test cells amended with sediment, a large microbial inoculum and an organic carbon source. A complete characterization test kit was field tested to characterize the SRS L-Area spent fuel basin. The sampling kit consisted of a TOC analyzer, a YSI multiprobe, and a thickness probe. The tools were field tested to determine their ease of use, reliability, and determine the quality of data that each tool could provide. Characterization was done over a two day period in June 2011, and confirmed that the L Area basin is a well operated facility with low corrosion potential.

  20. Moving Advanced Desiccant Materials into Mainstream Non-CFC Cooling Products

    SciTech Connect (OSTI)

    Sand, J. R.; Grossman, T.; Rice, C. K.; Fairchild, P. D.; Gross, I. L.

    2004-12-30

    Desiccant dehumidification technology is emerging as a technically viable alternative for comfort conditioning in many commercial and institutional buildings. Attempts to improve the indoor air quality of buildings has resulted in increasingly stringent guidelines for occupant outdoor air ventilation rates. Additionally, revised building heating, ventilating, and air-conditioning (HVAC) design criteria based on regional peak dew point data highlight the important of the latent (moisture removal) building load relative to the sensible (temperature) building load.

  1. Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing New Process Produces Ethylene More Efficiently and Reduces Coke Formation Ethylene, an important olefn, is a key building block in the production of numerous chemicals and polymers and the largest volume organic chemical produced in the United States and the world today. Ethylene also has one of the highest overall energy consumption totals compared to the production of other chemicals

  2. Effects of Porous Medium Heterogeneity on Vadose Zone Desiccation: Intermediate-scale Laboratory Experiments and Simulations

    SciTech Connect (OSTI)

    Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Dane, Jacob H.; Truex, Michael J.

    2012-11-01

    Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreements between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.

  3. Development of an Ultra-Low Background Liquid Scintillation Counter for Trace Level Analysis

    SciTech Connect (OSTI)

    Erchinger, Jennifer L.; Orrell, John L.; Aalseth, Craig E.; Bernacki, Bruce E.; Douglas, Matthew; Finn, Erin C.; Fuller, Erin S.; Keillor, Martin E.; Morley, Shannon M.; Mullen, Crystal A.; Panisko, Mark E.; Shaff, Sarah M.; Warren, Glen A.; Wright, Michael E.

    2015-09-01

    Low-level liquid scintillation counting (LSC) has been established as one of the radiation detection techniques useful in elucidating environmental processes and environmental monitoring around nuclear facilities. The Ultra-Low Background Liquid Scintillation Counter (ULB-LSC) under construction in the Shallow Underground Laboratory at Pacific Northwest National Laboratory aims to further reduce the MDAs and/or required sample processing. Through layers of passive shielding in conjunction with an active veto and 30 meters water equivalent overburden, the background reduction is expected to be 10 to 100 times below typical analytic low-background liquid scintillation systems. Simulations have shown an expected background of around 14 counts per day. A novel approach to the light collection will use a coated hollow light guide cut into the inner copper shielding. Demonstration LSC measurements will show low-energy detection, spectral deconvolution, and alpha/beta discrimination capabilities, from trials with standards of tritium, strontium-90, and actinium-227, respectively. An overview of the system design and expected demonstration measurements will emphasize the potential applications of the ULB-LSC in environmental monitoring for treaty verification, reach-back sample analysis, and facility inspections.

  4. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste

    SciTech Connect (OSTI)

    MacDonal, Digby D.; Marx, Brian M.; Ahn, Sejin; Ruiz, Julio de; Soundararajan, Balaji; Smith, Morgan; Coulson, Wendy

    2005-06-15

    Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprised of NaOH and NaNO3, along with trace amounts of phosphate, sulfate, carbonate, and chloride. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair.

  5. Development of a Liquid to Compressed Natural Gas (LCNG) Fueling Station. Final Report

    SciTech Connect (OSTI)

    Moore, J. A.

    1999-06-30

    The program objective was the development of equipment and processes to produce compressed natural gas (CNG) from liquified natural gas (LNG) for heavy duty vehicular applications. The interest for this technology is a result of the increased use of alternative fuels for the reduction of emissions and dependency of foreign energy. Technology of the type developed under this program is critical for establishing natural gas as an economical alternative fuel.

  6. Summary of the Second Workshop on Liquid Argon Time Projection Chamber Research and Development in the United States

    SciTech Connect (OSTI)

    Acciarri, R.; et al.

    2015-04-21

    The second workshop to discuss the development of liquid argon time projection chambers (LArTPCs) in the United States was held at Fermilab on July 8-9, 2014. The workshop was organized under the auspices of the Coordinating Panel for Advanced Detectors, a body that was initiated by the American Physical Society Division of Particles and Fields. All presentations at the workshop were made in six topical plenary sessions: i) Argon Purity and Cryogenics, ii) TPC and High Voltage, iii) Electronics, Data Acquisition and Triggering, iv) Scintillation Light Detection, v) Calibration and Test Beams, and vi) Software. This document summarizes the current efforts in each of these areas. It primarily focuses on the work in the US, but also highlights work done elsewhere in the world.

  7. Recent developments in the production of liquid fuels via catalytic conversion of microalgae: experiments and simulations

    SciTech Connect (OSTI)

    Shi,Fan; Wang, Pin; Duan, Yuhua; Link, Dirk; Morreale, Bryan

    2012-01-01

    Due to continuing high demand, depletion of non-renewable resources and increasing concerns about climate change, the use of fossil fuel-derived transportation fuels faces relentless challenges both from a world markets and an environmental perspective. The production of renewable transportation fuel from microalgae continues to attract much attention because of its potential for fast growth rates, high oil content, ability to grow in unconventional scenarios, and inherent carbon neutrality. Moreover, the use of microalgae would minimize ‘‘food versus fuel’’ concerns associated with several biomass strategies, as microalgae do not compete with food crops in the food chain. This paper reviews the progress of recent research on the production of transportation fuels via homogeneous and heterogeneous catalytic conversions of microalgae. This review also describes the development of tools that may allow for a more fundamental understanding of catalyst selection and conversion processes using computational modelling. The catalytic conversion reaction pathways that have been investigated are fully discussed based on both experimental and theoretical approaches. Finally, this work makes several projections for the potential of various thermocatalytic pathways to produce alternative transportation fuels from algae, and identifies key areas where the authors feel that computational modelling should be directed to elucidate key information to optimize the process.

  8. Selection for increased desiccation resistance in Drosophila melanogaster: Additive genetic control and correlated responses for other stresses

    SciTech Connect (OSTI)

    Hoffmann, A.A.; Parsons, P.A. )

    1989-08-01

    Previously we found that Drosophila melanogaster lines selected for increased desiccation resistance have lowered metabolic rate and behavioral activity levels, and show correlated responses for resistance to starvation and a toxic ethanol level. These results were consistent with a prediction that increased resistance to many environmental stresses may be genetically correlated because of a reduction in metabolic energy expenditure. Here we present experiments on the genetic basis of the selection response and extend the study of correlated responses to other stresses. The response to selection was not sex-specific and involved X-linked and autosomal genes acting additively. Activity differences contributed little to differences in desiccation resistance between selected and control lines. Selected lines had lower metabolic rates than controls in darkness when activity was inhibited. Adults from selected lines showed increased resistance to a heat shock, {sup 60}Co-gamma-radiation, and acute ethanol and acetic acid stress. The desiccation, ethanol and starvation resistance of isofemale lines set up from the F2s of a cross between one of the selected and one of the control lines were correlated. Selected and control lines did not differ in ether-extractable lipid content or in resistance to acetone, ether or a cold shock.

  9. Critical point of gas-liquid type phase transition and phase equilibrium functions in developed two-component plasma model

    SciTech Connect (OSTI)

    Butlitsky, M. A.; Zelener, B. V.

    2014-07-14

    A two-component plasma model, which we called a “shelf Coulomb” model has been developed in this work. A Monte Carlo study has been undertaken to calculate equations of state, pair distribution functions, internal energies, and other thermodynamics properties. A canonical NVT ensemble with periodic boundary conditions was used. The motivation behind the model is also discussed in this work. The “shelf Coulomb” model can be compared to classical two-component (electron-proton) model where charges with zero size interact via a classical Coulomb law. With important difference for interaction of opposite charges: electrons and protons interact via the Coulomb law for large distances between particles, while interaction potential is cut off on small distances. The cut off distance is defined by an arbitrary ? parameter, which depends on system temperature. All the thermodynamics properties of the model depend on dimensionless parameters ? and ? = ?e{sup 2}n{sup 1/3} (where ? = 1/k{sub B}T, n is the particle's density, k{sub B} is the Boltzmann constant, and T is the temperature) only. In addition, it has been shown that the virial theorem works in this model. All the calculations were carried over a wide range of dimensionless ? and ? parameters in order to find the phase transition region, critical point, spinodal, and binodal lines of a model system. The system is observed to undergo a first order gas-liquid type phase transition with the critical point being in the vicinity of ?{sub crit}?13(T{sub crit}{sup *}?0.076),?{sub crit}?1.8(v{sub crit}{sup *}?0.17),P{sub crit}{sup *}?0.39, where specific volume v* = 1/?{sup 3} and reduced temperature T{sup *} = ?{sup ?1}.

  10. LiquidMaize LLC | Open Energy Information

    Open Energy Info (EERE)

    Name: LiquidMaize, LLC Place: Denver, Colorado Zip: 80237 Product: LiquidMaize is an ethanol development and management company that builds, owns, and operates ethanol plants...

  11. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    SciTech Connect (OSTI)

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

    2014-01-07

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

  12. Imaging Liquids Using Microfluidic Cells

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

    2013-05-10

    Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

  13. Engineering scale development of the Vapor-Liquid-Solid (VLS) process for the production of silicon carbide fibrils

    SciTech Connect (OSTI)

    Hollar, W.E. Jr.; Mills, W.H.

    1993-09-01

    Vapor-liquid-solid (VLS)SiC fibrils are used as reinforcement in ceramic matrix composites (CMC). A program has been completed for determining process scaleup parameters and to produce material for evaluation in a CMC. The scaleup is necessary to lower production cost and increase material availability. Scaleup parameters were evaluated in a reactor with a vertical dimension twice that of the LANL reactor. Results indicate that the scaleup will be possible. Feasibility of recycling process gas was demonstrated and the impact of postprocessing on yields determined.

  14. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  15. Picosecond dynamics of reactions in the liquid phase: studies of iodine photodissociation and development of new laser techniques

    SciTech Connect (OSTI)

    Berg, M.A.

    1985-09-01

    Iodine photodissociation and recombination was studied as a model for processes common to chemical reaction in the liquid phase. Picosecond transient absorption measurements from 1000 to 295 nm were used to monitor the dynamics in a variety of solvents. Most of the atoms which undergo geminate recombination were found to do so in less than or equal to 15 ps, in agreement with the results of existing molecular dynamics simulations. Vibrational relaxation times vary from approx.15 ps near the middle of the ground state well to approx.150 ps for complete relaxation to v = 0. The prediction of strong resonant vibrational energy transfer to chlorinated methane solvents was not supported, but some evidence for this mechanism was found for alkane solvents. Current theory is unable to explain the large variation (65 to 2700 ps) of the excited A'-state lifetime in various solvents. The 10-Hz amplified, synchronously-pumped dye laser which was used in these studies is described and characterized. SERS (Stimulated Electronic Raman Scattering) and difference frequency mixing were used in the generation of the infrared and far-infrared, respectively. 54 refs., 38 figs., 3 tabs. (WRF)

  16. Ionic Liquids for Utilization of Geothermal Energy

    Broader source: Energy.gov [DOE]

    DOE Geothermal Program Peer Review 2010 - Presentation. Project objective: to develop ionic liquids for two geothermal energy related applications.

  17. CATALYST ACTIVITY MAINTENANCE FOR THE LIQUID PHASE SYNTHESIS GAS-TO-DIMETHYL ETHER PROCESS PART II: DEVELOPMENT OF ALUMINUM PHOSPHATE AS THE DEHYDRATION CATALYST FOR THE SINGLE-STEP LIQUID PHASE SYNGAS-TO-DME PROCESS

    SciTech Connect (OSTI)

    Xiang-Dong Peng

    2002-05-01

    At the heart of the single-step liquid phase syngas-to-DME process (LPDME{trademark}) is a catalyst system that can be active as well as stable. In the Alternative Fuels I program, a dual-catalyst system containing a Cu-based commercial methanol synthesis catalyst (BASF S3-86) and a commercial dehydration material ({gamma}-alumina) was demonstrated. It provided the productivity and selectivity expected from the LPDME process. However, the catalyst system deactivated too rapidly to warrant a viable commercial process [1]. The mechanistic investigation in the early part of the DOE's Alternative Fuels II program revealed that the accelerated catalyst deactivation under LPDME conditions is due to detrimental interaction between the methanol synthesis catalyst and methanol dehydration catalyst [2,3]. The interaction was attributed to migration of Cu- and/or Zn-containing species from the synthesis catalyst to the dehydration catalyst. Identification of a dehydration catalyst that did not lead to this detrimental interaction while retaining adequate dehydration activity was elusive. Twenty-nine different dehydration materials were tested, but none showed the desired performance [2]. The search came to a turning point when aluminum phosphate was tested. This amorphous material is prepared by precipitating a solution containing Al(NO{sub 3}){sub 3} and H{sub 3}PO{sub 4} with NH{sub 4}OH, followed by washing, drying and calcination. The aluminum phosphate catalyst has adequate dehydration activity and good stability. It can co-exist with the Cu-based methanol synthesis catalyst without negatively affecting the latter catalyst's stability. This report documents the details of the development of this catalyst. These include initial leads, efforts in improving activity and stability, investigation and development of the best preparation parameters and procedures, mechanistic understanding and resulting preparation guidelines, and the accomplishments of this work.

  18. Turning Bacteria into Biofuel: Development of an Integrated Microbial Electrocatalytic (MEC) System for Liquid Biofuel Production from CO2

    SciTech Connect (OSTI)

    2010-08-01

    Electrofuels Project: LBNL is improving the natural ability of a common soil bacteria called Ralstonia eutropha to use hydrogen and carbon dioxide for biofuel production. First, LBNL is genetically modifying the bacteria to produce biofuel at higher concentrations. Then, LBNL is using renewable electricity obtained from solar, wind, or wave power to produce high amounts of hydrogen in the presence of the bacteria—increasing the organism’s access to its energy source and improving the efficiency of the biofuel-creation process. Finally, LBNL is tethering electrocatalysts to the bacteria’s surface which will further accelerate the rate at which the organism creates biofuel. LBNL is also developing a chemical method to transform the biofuel that the bacteria produce into ready-to-use jet fuel.

  19. Engineering scale development of the vapor-liquid-solid (VLS) process for the production of silicon carbide fibrils. Phase 2

    SciTech Connect (OSTI)

    Ohnsorg, R.W.; Hollar, W.E. Jr.; Lau, S.K.; Ko, F.K.; Schatz, K.

    1995-04-01

    As reinforcements for composites, VLS SiC fibrils have attractive mechanical properties including high-strength, high modulus, and excellent creep resistance. To make use of their excellent mechanical properties in a composite, a significant volume fraction (>10%) of aligned, long fibrils (>2 mm) needs to be consolidated in the ceramic matrix. The fibrils must be processed into an assembly that will allow for composite fabrication while maintaining fibril alignment and length. With Advanced Product Development (APD) as the yam fabrication subcontractor, Carborundum investigated several approaches to achieve this goaL including traditional yam-forming processes such as carding and air-vortex spinning and nontraditional processes such as tape forming and wet casting. Carborundum additionally performed an economic analysis for producing 500 and 10,000 pounds of SiC fibrils annually using both conservative and more aggressive processing parameters. With the aggressive approach, the projected costs for SiC fibril production for 500 and 10,000 pounds per year are $1,340/pound and $340/pound, respectively.

  20. Liquid phase methanol LaPorte process development unit: Modification operation, and support studies. Task 3.6/3.7: Alternative catalyst/life run

    SciTech Connect (OSTI)

    Not Available

    1991-01-28

    In April 1987, Air Products started the third and final contract with the US Department of Energy to develop the Liquid Phase Methanol (LPMEOH) process. One of the objectives was to identify alternative commercial catalyst(s) for the process. This objective was strategically important as we want to demonstrate that the LPMEOH process is flexible and not catalyst selection limited. Among three commercially available catalysts evaluated in the lab, the catalyst with a designation of F21/0E75-43 was the most promising candidate. The initial judging criteria included not only the intrinsic catalyst activity but also the ability to be used effectively in a slurry reactor. The catalyst was then advanced for a 40-day life test in a laboratory 300 cc autoclave. The life test result also revealed superior stability when compared with that of a standard catalyst. Consequently, the new catalyst was recommended for demonstration in the Process Development Unit (PDU) at LaPorte, Texas. This report details the methodology of testing and selecting the catalyst.

  1. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  2. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  3. Energy and economic assessment of desiccant cooling systems coupled with single glazed air and hybrid PV/thermal solar collectors for applications in hot and humid climate

    SciTech Connect (OSTI)

    Beccali, Marco; Finocchiaro, Pietro; Nocke, Bettina

    2009-10-15

    This paper presents a detailed analysis of the energy and economic performance of desiccant cooling systems (DEC) equipped with both single glazed standard air and hybrid photovoltaic/thermal (PV/t) collectors for applications in hot and humid climates. The use of 'solar cogeneration' by means of PV/t hybrid collectors enables the simultaneous production of electricity and heat, which can be directly used by desiccant air handling units, thereby making it possible to achieve very energy savings. The present work shows the results of detailed simulations conducted for a set of desiccant cooling systems operating without any heat storage. System performance was investigated through hourly simulations for different systems and load combinations. Three configurations of DEC systems were considered: standard DEC, DEC with an integrated heat pump and DEC with an enthalpy wheel. Two kinds of building occupations were considered: office and lecture room. Moreover, three configurations of solar-assisted air handling units (AHU) equipped with desiccant wheels were considered and compared with standard AHUs, focusing on achievable primary energy savings. The relationship between the solar collector's area and the specific primary energy consumption for different system configurations and building occupation patterns is described. For both occupation patterns, sensitivity analysis on system performance was performed for different solar collector areas. Also, this work presents an economic assessment of the systems. The cost of conserved energy and the payback time were calculated, with and without public incentives for solar cooling systems. It is worth noting that the use of photovoltaics, and thus the exploitation of related available incentives in many European countries, could positively influence the spread of solar air cooling technologies (SAC). An outcome of this work is that SAC systems equipped with PV/t collectors are shown to have better performance in terms of primary energy saving than conventional systems fed by vapour compression chillers and coupled with PV cells. All SAC systems present good figures for primary energy consumption. The best performances are seen in systems with integrated heat pumps and small solar collector areas. The economics of these SAC systems at current equipment costs and energy prices are acceptable. They become more interesting in the case of public incentives of up to 30% of the investment cost (Simple Payback Time from 5 to 10 years) and doubled energy prices. (author)

  4. Liquid metal thermoacoustic engine

    SciTech Connect (OSTI)

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1986-01-01

    We are studying a liquid metal thermoacoustic engine both theoretically and experimentally. This type of engine promises to produce large quantities of electrical energy from heat at modest efficiency with no moving parts. A sound wave is usually thought of as consisting of pressure oscillations, but always attendant to the pressure oscillation are temperature oscillations. The combination produces a rich variety of ''thermoacoustic'' effects. These effects are usually so small that they are never noticed in everyday life; nevertheless under the right circumstances they can be harnessed to produce powerful heat engines, heat pumps, and refrigerators. In our liquid metal thermoacoustic engine, heat flow from a high temperature source to a low temperature sink generates a high-amplitude standing acoustic wave in liquid sodium. This acoustic power is converted to electric power by a simple magnetohydrodynamic effect at the acoustic oscillation frequency. We have developed a detailed thermoacoustic theory applicable to this engine, and find that a reasonably designed liquid sodium engine operating between 700/sup 0/C and 100/sup 0/C should generate about 60 W/cm/sup 2/ of acoustic power at about 1/3 of Carnot's efficiency. Construction of a 3000 W-thermal laboratory model engine has just been completed, and we have exciting preliminary experimental results as of the time of preparation of this manuscript showing, basically, that the engine works. We have also designed and built a 1 kHz liquid sodium magnetohydrodynamic generator and have extensive measurements on it. It is now very well characterized both experimentally and theoretically. The first generator of its kind, it already converts acoustic power to electric power with 40% efficiency. 16 refs., 5 figs.

  5. Liquid phase Fischer-Tropsch (II) demonstration in the LaPorte Alternative Fuels Development Unit. Volume 1/2, Main Report. Final report

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1995-09-01

    This report presents results from a demonstration of Liquid Phase Fischer-Tropsch (LPFT) technology in DOE`s Alternative Fuels Development Unit (AFDU) at LaPorte, Texas. The run was conducted in a bubble column at the AFDU in May--June 1994. The 10-day run demonstrated a very high level of reactor productivity for LPFT, more than five times the previously demonstrated productivity. The productivity was constrained by mass transfer limitations, perhaps due to slurry thickening as a result of carbon formation on the catalyst. With a cobalt catalyst or an improved iron catalyst, if the carbon formation can be avoided, there is significant room for further improvements. The reactor was operated with 0.7 H{sub 2}/CO synthesis gas in the range of 2400--11700 sl/hr-kg Fe, 175--750 psig and 270--300C. The inlet gas velocity ranged from 0.19 to 0.36 ft/sec. The demonstration was conducted at a pilot scale of 5 T/D. Catalyst activation with CO/N{sub 2} proceeded well. Initial catalyst activity was close to the expectations from the CAER autoclave runs. CO conversion of about 85% was obtained at the baseline condition. The catalyst also showed good water-gas shift activity and a low {alpha}. At high productivity conditions, reactor productivity of 136 grams of HC/hr -- liter of slurry volume was demonstrated, which was within the target of 120--150. However, mass transfer limitations were observed at these conditions. To alleviate these limitations and prevent excessive thickening, the slurry was diluted during the run. This enabled operations under kinetic control later in the run. But, the dilution resulted in lower conversion and reactor productivity. A new reactor internal heat exchanger, installed for high productivity conditions, performed well above design,and the system never limited the performance. The control can expected, the reactor temperature control needed manual intervention. The control can be improved by realigning the utility oil system.

  6. The Use of Humidity Sensors to Develop BIPV Packaging Solutions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy The Use of Humidity Sensors to Develop BIPV Packaging Solutions The Use of Humidity Sensors to Develop BIPV Packaging Solutions Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado PDF icon pvmrw13_ps4_tata_rice.pdf More Documents & Publications Agenda for the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado Distributed Energy Technology Characterization (Desiccant Technologies), January 2004 Energy Savings

  7. Liquid Hydrogen Absorber for MICE

    SciTech Connect (OSTI)

    Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing

    2010-05-30

    Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.

  8. Documenting the Effectiveness of Cosorption of Airborne Contaminants by a Field-Installed Active Desiccant System: Final Report - Phase 2D

    SciTech Connect (OSTI)

    Fischer, J

    2003-01-23

    The final report for Phase 1 of this research effort (ORNL/SUB/94-SV004/1) concluded that a significant market opportunity would exist for active desiccant systems if it could be demonstrated that they can remove a significant proportion of common airborne contaminants while simultaneously performing the primary function of dehumidifying a stream of outdoor air or recirculated building air. If the engineering community begins to follow the intent of ASHRAE Standard 62, now part of all major building codes, the outdoor air in many major cities may need to be pre-cleaned before it is introduced into occupied spaces. Common air contaminant cosorption capability would provide a solution to three important aspects of the ASHRAE 62-89 standard that have yet to be effectively addressed by heating, ventilation, and air-conditioning (HVAC) equipment manufacturers: (1) The ASHRAE standard defines acceptable outdoor air quality. If the outdoor air contains unacceptable levels of certain common outdoor air contaminants (e.g., sulfur dioxide, ozone), then the standard requires that these contaminants be removed from the outdoor air stream to reach compliance with the acceptable outdoor air quality guidelines. (2) Some engineers prefer to apply a filtration or prescriptive approach rather than a ventilation approach to solving indoor air quality problems. The ASHRAE standard recognizes this approach provided that the filtration technology exists to remove the gaseous contaminants encountered. The performance of current gaseous filtration technologies is not well documented, and they can be costly to maintain because the life of the filter is limited and the cost is high. Moreover, it is not easy to determine when the filters need changing. In such applications, an additional advantage provided by the active desiccant system would be that the same piece of equipment could control space humidity and provide filtration, even during unoccupied periods, if the active desiccant system were operated in a recirculation mode. (3) Almost all major medical, university, and research facilities face the dilemma that the air exhausted from a building exits near the intake of another building. As a result, contaminants exhausted outdoors are pulled back into the same or an adjacent building. The removal of contaminants from outdoor air that an active desiccant system offers would be attractive to applications in such cases. The primary objective of this research project was to quantify the ability of the SEMCO composite desiccant dehumidification wheel to purify outdoor and recirculated air streams by removing gaseous contaminants commonly encountered in actual applications. This contaminant removal is provided simultaneously with dehumidification (removing the latent load) of these air streams at conditions encountered in HVAC applications. This research builds upon initial seed work completed by the Georgia Tech Research Institute (GTRI) during 1993 (Bayer and Downing 1993).

  9. Nanoscopic Manipulation and Imaging of Liquid Crystals

    SciTech Connect (OSTI)

    Rosenblatt, Charles S.

    2014-02-04

    This is the final project report. The project’s goals centered on nanoscopic imaging and control of liquid crystals and surfaces. We developed and refined techniques to control liquid crystal orientation at surfaces with resolution as small as 25 nm, we developed an optical imaging technique that we call Optical Nanotomography that allows us to obtain images inside liquid crystal films with resolution of 60 x 60 x 1 nm, and we opened new thrust areas related to chirality and to liquid crystal/colloid composites.

  10. Strings of liquid beads for gas-liquid contact operations

    SciTech Connect (OSTI)

    Hattori, Kenji; Ishikawa, Mitsukuni; Mori, Y.H. . Dept. of Mechanical Engineering)

    1994-12-01

    Energy recovery from hot gases exhausted from power plants, garbage incineration facilities, and many industrial processes has been growing due to demands for saving the primary-energy consumption. A novel device for gas-liquid contact operations is proposed to feed a liquid onto wires (or threads) hanging down in a gas stream is proposed. The liquid disintegrates into beads strung on each wire at regular intervals; if the wire is moderately wettable, a thin film forms to sheathe the wire, thereby interconnecting the beads. Since the beads fall down slowly, which possibly renews the film flowing down even more slowly, a sufficient gas-liquid contact time is available even in a contactor with considerably limited height. An approximate calculation method is developed for predicting the variation in the temperature effectiveness for the liquid (the fractional approach of the liquid exit temperature to the gas inlet temperature) with the falling distance, assuming an applicability of strings-of-beads contactors to thermal energy recovery from hot gas streams.

  11. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  12. Tokamak with liquid metal toroidal field coil

    DOE Patents [OSTI]

    Ohkawa, Tihiro (La Jolla, CA); Schaffer, Michael J. (San Diego, CA)

    1981-01-01

    Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.

  13. Design and construction of coal/biomass to liquids (CBTL) process development unit (PDU) at the University of Kentucky Center for Applied Energy Research (CAER)

    SciTech Connect (OSTI)

    Placido, Andrew; Liu, Kunlei; Challman, Don; Andrews, Rodney; Jacques, David

    2015-10-30

    This report describes a first phase of a project to design, construct and commission an integrated coal/biomass-to-liquids facility at a capacity of 1 bbl. /day at the University of Kentucky Center for Applied Energy Research (UK-CAER) – specifically for construction of the building and upstream process units for feed handling, gasification, and gas cleaning, conditioning and compression. The deliverables from the operation of this pilot plant [when fully equipped with the downstream process units] will be firstly the liquid FT products and finished fuels which are of interest to UK-CAER’s academic, government and industrial research partners. The facility will produce research quantities of FT liquids and finished fuels for subsequent Fuel Quality Testing, Performance and Acceptability. Moreover, the facility is expected to be employed for a range of research and investigations related to: Feed Preparation, Characteristics and Quality; Coal and Biomass Gasification; Gas Clean-up/ Conditioning; Gas Conversion by FT Synthesis; Product Work-up and Refining; Systems Analysis and Integration; and Scale-up and Demonstration. Environmental Considerations - particularly how to manage and reduce carbon dioxide emissions from CBTL facilities and from use of the fuels - will be a primary research objectives. Such a facility has required significant lead time for environmental review, architectural/building construction, and EPC services. UK, with DOE support, has advanced the facility in several important ways. These include: a formal EA/FONSI, and permits and approvals; construction of a building; selection of a range of technologies and vendors; and completion of the upstream process units. The results of this project are the FEED and detailed engineering studies, the alternate configurations and the as-built plant - its equipment and capabilities for future research and demonstration and its adaptability for re-purposing to meet other needs. These are described in some detail in this report, along with lessons learned.

  14. Liquid level detector

    DOE Patents [OSTI]

    Grasso, A.P.

    1984-02-21

    A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  15. Liquid level detector

    DOE Patents [OSTI]

    Grasso, Albert P.

    1986-01-01

    A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  16. SERI Desiccant Cooling Test Facility. Status report. Preliminary data on the performance of a rotary parallel-passage silica-gel dehumidifier

    SciTech Connect (OSTI)

    Schultz, K.J.

    1986-04-01

    This report describes the SERI Desiccant Cooling Test Facility. The facility can test bench-scale rotary dehumidifiers over a wide range of controlled conditions. We constructed and installed in the test loop a prototype parallel-passage rotary dehumidifier that has spirally wound polyester tape coated with silica gel. The initial tests gave satisfactory results indicating that approximately 90% of the silica gel was active and the overall Lewis number of the wheel was near unity. The facility has several minor difficulties including an inability to control humidity satisfactorily and nonuniform and highly turbulent inlet velocities. To completely validate the facility requires a range of dehumidifier designs. Several choices are available including constructing a second parallel-passage dehumidifier with the passage spacing more uniform.

  17. Liquid metal Flow Meter - Final Report

    SciTech Connect (OSTI)

    Andersen, C.; Hoogendoom, S.; Hudson, B.; Prince, J.; Teichert, K.; Wood, J.; Chase, K.

    2007-01-30

    Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

  18. Liquid-Liquid Extraction Equipment

    SciTech Connect (OSTI)

    Jack D. Law; Terry A. Todd

    2008-12-01

    Solvent extraction processing has demonstrated the ability to achieve high decontamination factors for uranium and plutonium while operating at high throughputs. Historical application of solvent extraction contacting equipment implies that for the HA cycle (primary separation of uranium and plutonium from fission products) the equipment of choice is pulse columns. This is likely due to relatively short residence times (as compared to mixer-settlers) and the ability of the columns to tolerate solids in the feed. Savannah River successfully operated the F-Canyon with centrifugal contactors in the HA cycle (which have shorter residence times than columns). All three contactors have been successfully deployed in uranium and plutonium purification cycles. Over the past 20 years, there has been significant development of centrifugal contactor designs and they have become very common for research and development applications. New reprocessing plants are being planned in Russia and China and the United States has done preliminary design studies on future reprocessing plants. The choice of contactors for all of these facilities is yet to be determined.

  19. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  20. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E. (Los Alamos, NM); Bolton, Richard D. (Los Alamos, NM)

    1999-01-01

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  1. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of why the development, by Zhu et al., of a technique allowing direct measurement and control of liquid-crystal properties is important. The NOBOW molecular structure and a...

  2. Future of Liquid Biofuels for APEC Economies

    SciTech Connect (OSTI)

    Milbrandt, A.; Overend, R. P.

    2008-05-01

    This project was initiated by APEC Energy Working Group (EWG) to maximize the energy sector's contribution to the region's economic and social well-being through activities in five areas of strategic importance including liquid biofuels production and development.

  3. Fractionation and Removal of Solutes from Ionic Liquids - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Fractionation and Removal of Solutes from Ionic Liquids Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryResearchers at the Joint BioEnergy Institute (JBEI) have developed a technology to fractionate and recover biomaterials dissolved in an ionic liquid and to purify water miscible ionic liquids. The JBEI technology utilizes specific mixtures of solvents to precipitate or extract compounds dissolved in an ionic liquid without high

  4. Biomass and Natural Gas to Liquid Transportation Fuels | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Natural Gas to Liquid Transportation Fuels Biomass and Natural Gas to Liquid Transportation Fuels Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Josephine Elia, Graduate Student, Princeton University PDF icon b13_elia_1-d.pdf More Documents & Publications Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Exploring the Optimum Role of Natural Gas in Biofuels Production GBTL Workshop Attendees

  5. Liquid level detector

    DOE Patents [OSTI]

    Tshishiku, Eugene M. (Augusta, GA)

    2011-08-09

    A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

  6. LIQUID CYCLONE CONTACTOR

    DOE Patents [OSTI]

    Whatley, M.E.; Woods, W.M.

    1962-09-01

    This invention relates to liquid-liquid extraction systems. The invention, an improved hydroclone system, comprises a series of serially connected, axially aligned hydroclones, each of which is provided with an axially aligned overflow chamber. The chambers are so arranged that rotational motion of a fluid being passed through the system is not lost in passing from chamber to chamber; consequently, this system is highly efficient in contacting and separating two immiscible liquids. (AEC)

  7. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J. (Oak Ridge, TN); Lowrie, Robert S. (Oak Ridge, TN); Sease, John D. (Knoxville, TN)

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  8. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  9. Ultrasonic liquid level detector

    DOE Patents [OSTI]

    Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

    2010-09-28

    An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

  10. HV in Noble Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

  11. Liquid Propane Injection Applications

    Broader source: Energy.gov [DOE]

    Liquid propane injection technology meets manufacturing/assembly guidelines, maintenance/repair strategy, and regulations, with same functionality, horsepower, and torque as gasoline counterpart.

  12. Dynamic density functional theory with hydrodynamic interactions: Theoretical development and application in the study of phase separation in gas-liquid systems

    SciTech Connect (OSTI)

    Kikkinides, E. S.; Monson, P. A.

    2015-03-07

    Building on recent developments in dynamic density functional theory, we have developed a version of the theory that includes hydrodynamic interactions. This is achieved by combining the continuity and momentum equations eliminating velocity fields, so the resulting model equation contains only terms related to the fluid density and its time and spatial derivatives. The new model satisfies simultaneously continuity and momentum equations under the assumptions of constant dynamic or kinematic viscosity and small velocities and/or density gradients. We present applications of the theory to spinodal decomposition of subcritical temperatures for one-dimensional and three-dimensional density perturbations for both a van der Waals fluid and for a lattice gas model in mean field theory. In the latter case, the theory provides a hydrodynamic extension to the recently studied dynamic mean field theory. We find that the theory correctly describes the transition from diffusive phase separation at short times to hydrodynamic behaviour at long times.

  13. Liquid heat capacity lasers

    DOE Patents [OSTI]

    Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

    2007-05-01

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  14. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

    2008-09-09

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  15. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

    2011-11-01

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  16. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    1985-01-29

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge. 2 figs.

  17. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

    1985-01-01

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  18. Renewable liquid reflecting zone plate

    DOE Patents [OSTI]

    Toor, Arthur; Ryutov, Dmitri D.

    2003-12-09

    A renewable liquid reflecting zone plate. Electrodes are operatively connected to a dielectric liquid in a circular or other arrangement to produce a reflecting zone plate. A system for renewing the liquid uses a penetrable substrate.

  19. Ionic liquids for rechargeable lithium batteries

    SciTech Connect (OSTI)

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz,John; Newman, John

    2005-09-29

    We have investigated possible anticipated advantages of ionic-liquid electrolytes for use in lithium-ion batteries. Thermal stabilities and phase behavior were studied by thermal gravimetric analysis and differential scanning calorimetry. The ionic liquids studied include various imidazoliumTFSI systems, pyrrolidiniumTFSI, BMIMPF{sub 6}, BMIMBF{sub 4}, and BMIMTf. Thermal stabilities were measured for neat ionic liquids and for BMIMBF{sub 4}-LiBF{sub 4}, BMIMTf-LiTf, BMIMTFSI-LiTFSI mixtures. Conductivities have been measured for various ionic-liquid lithium-salt systems. We show the development of interfacial impedance in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell and we report results from cycling experiments for a Li|BMIMBF{sub 4} + 1 mol/kg LIBF{sub 4}|C cell. The interfacial resistance increases with time and the ionic liquid reacts with the lithium electrode. As expected, imidazolium-based ionic liquids react with lithium electrodes. We seek new ionic liquids that have better chemical stabilities.

  20. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L. (Idaho Falls, ID)

    1987-01-01

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  1. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  2. Gas/liquid sampler for closed canisters in KW Basin - test report

    SciTech Connect (OSTI)

    Pitkoff, C.C.

    1995-01-23

    Test report for the gas/liquid sampler designed and developed for sampling closed canisters in the KW Basin.

  3. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  4. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  5. Liquid-level detector

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

  6. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  7. Arabidopsis AtSerpin1, Crystal Structure and in Vivo Interaction with Its Target Protease RESPONSIVE TO DESICCATION-21 (RD21)

    SciTech Connect (OSTI)

    Lampl, Nardy; Budai-Hadrian, Ofra; Davydov, Olga; Joss, Tom V.; Harrop, Stephen J.; Curmi, Paul M.G.; Roberts, Thomas H.; Fluhr, Robert

    2010-05-25

    In animals, protease inhibitors of the serpin family are associated with many physiological processes, including blood coagulation and innate immunity. Serpins feature a reactive center loop (RCL), which displays a protease target sequence as a bait. RCL cleavage results in an irreversible, covalent serpin-protease complex. AtSerpin1 is an Arabidopsis protease inhibitor that is expressed ubiquitously throughout the plant. The x-ray crystal structure of recombinant AtSerpin1 in its native stressed conformation was determined at 2.2 {angstrom}. The electrostatic surface potential below the RCL was found to be highly positive, whereas the breach region critical for RCL insertion is an unusually open structure. AtSerpin1 accumulates in plants as a full-length and a cleaved form. Fractionation of seedling extracts by nonreducing SDS-PAGE revealed the presence of an additional slower migrating complex that was absent when leaves were treated with the specific cysteine protease inhibitor l-trans-epoxysuccinyl-l-leucylamido (4-guanidino)butane. Significantly, RESPONSIVE TO DESICCATION-21 (RD21) was the major protease labeled with the l-trans-epoxysuccinyl-l-leucylamido (4-guanidino)butane derivative DCG-04 in wild type extracts but not in extracts of mutant plants constitutively overexpressing AtSerpin1, indicating competition. Fractionation by nonreducing SDS-PAGE followed by immunoblotting with RD21-specific antibody revealed that the protease accumulated both as a free enzyme and in a complex with AtSerpin1. Importantly, both RD21 and AtSerpin1 knock-out mutants lacked the serpin-protease complex. The results establish that the major Arabidopsis plant serpin interacts with RD21. This is the first report of the structure and in vivo interaction of a plant serpin with its target protease.

  8. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T. (Pleasant Hill, CA)

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  9. Tokamak with liquid metal for inducing toroidal electrical field

    DOE Patents [OSTI]

    Ohkawa, Tihiro (La Jolla, CA)

    1981-01-01

    A tokamak apparatus includes a vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within said vessel defines a toroidal space within the liner confines gas therein. Liquid metal fills the reservoir outside the liner. A magnetic field is established in the liquid metal to develop magnetic flux linking the toroidal space. The gas is ionized. The liquid metal and the toroidal space are moved relative to one another transversely of the space to generate electric current in the ionized gas in the toroidal space about its major axis and thereby heat plasma developed in the toroidal space.

  10. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-07-13

    The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

  11. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Santosh Gangwal, Director-Business Development, Energy Technologies, Southern Research Institute PDF icon gangwal_biomass_2014.pdf

  12. Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Multifunctional Ashless Additives for Engine Lubrication Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication A group of oil-miscible ionic liquids has been developed by an ORNL-GM team as candidate lubricant additives with promising physical/chemical properties and potential multiple functionalities. PDF icon deer12_qu.pdf More Documents & Publications Ionic Liquids as Multi-Functional Lubricant Additives to Enhance Engine Efficiency Vehicle

  13. Improved Lithium-Loaded Liquid Scintillators for Neutron Detection - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Improved Lithium-Loaded Liquid Scintillators for Neutron Detection Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary A liquid scintillator with a substantially increased lithium weight was developed by ORNL researchers. Scintillators are widely used for the detection of neutron radiation emitted by radioactive sources. Conventional liquid scintillators are loaded with neutron absorbers. However, these scintillators generally have

  14. Recent development in green buildings

    SciTech Connect (OSTI)

    Mei, V.C.

    1996-12-31

    Because of the environmental concerns about some materials used in buildings, particularly chlorofluorocarbon (CFC) fluids used as the blowing agent for insulation materials and as refrigerants used in the air conditioning systems have led to a search for environmentally safe alternatives. For insulation materials, new non-CFC blowing agents are still under development. However, the old insulation materials in the buildings will stay because they do not pose any further environmental damage. It is a different story for refrigerants used in air conditioning systems. This study reports that the change-over from CFC to non-CFC refrigerants in the existing and future air conditioning equipment could be a chance not only to take care of the environmental concerns, but to save energy as well. Alternative air conditioning technologies, such as the desiccant dehumidification and absorption systems, and the potential of some natural substances, such as carbon dioxide, as the future refrigerants are also discussed.

  15. Adaptive Liquid Crystal Windows

    SciTech Connect (OSTI)

    Taheri, Bahman; Bodnar, Volodymyr

    2011-12-31

    Energy consumption by private and commercial sectors in the U.S. has steadily grown over the last decade. The uncertainty in future availability of imported oil, on which the energy consumption relies strongly, resulted in a dramatic increase in the cost of energy. About 20% of this consumption are used to heat and cool houses and commercial buildings. To reduce dependence on the foreign oil and cut down emission of greenhouse gases, it is necessary to eliminate losses and reduce total energy consumption by buildings. To achieve this goal it is necessary to redefine the role of the conventional windows. At a minimum, windows should stop being a source for energy loss. Ideally, windows should become a source of energy, providing net gain to reduce energy used to heat and cool homes. It is possible to have a net energy gain from a window if its light transmission can be dynamically altered, ideally electronically without the need of operator assistance, providing optimal control of the solar gain that varies with season and climate in the U.S. In addition, the window must not require power from the building for operation. Resolution of this problem is a societal challenge and of national interest and will have a broad global impact. For this purpose, the year-round, allclimate window solution to provide an electronically variable solar heat gain coefficient (SHGC) with a wide dynamic range is needed. AlphaMicron, Inc. (AMI) developed and manufactured 1ft × 1ft prototype panels for the world’s first auto-adjusting Adaptive Liquid Crystal Windows (ALCWs) that can operate from sunlight without the need for external power source and demonstrate an electronically adjustable SHGC. This novel windows are based on AlphaMicron’s patented e-Tint® technology, a guesthost liquid crystal system implemented on flexible, optically clear plastic films. This technology is suitable both for OEM and aftermarket (retro-fitting) lamination to new and existing windows. Low level of power consumption by ALCWs allows for on-board power electronics for automatic matching of transmission through windows to varying climate conditions without drawing the power from the power grid. ALCWs are capable of transmitting more sunlight in winters to assist in heating and less sunlight in summers to minimize overheating. As such, they can change the window from being a source of energy loss to a source of energy gain. In addition, the scalable AMI’s roll-to-roll process, proved by making 1ft × 1ftALCW prototype panels, allows for cost-effective production of large-scale window panels along with capability to change easily their color and shape. In addition to architectural glazing in houses and commercial buildings, ALCWs can be used in other applications where control of sunlight is needed, such as green houses, used by commercial produce growers and botanical gardens, cars, aircrafts, etc.

  16. Accurate measure by weight of liquids in industry

    SciTech Connect (OSTI)

    Muller, M.R.

    1992-12-12

    This research's focus was to build a prototype of a computerized liquid dispensing system. This liquid metering system is based on the concept of altering the representative volume to account for temperature changes in the liquid to be dispensed. This is actualized by using a measuring tank and a temperature compensating displacement plunger. By constantly monitoring the temperature of the liquid, the plunger can be used to increase or decrease the specified volume to more accurately dispense liquid with a specified mass. In order to put the device being developed into proper engineering perspective, an extensive literature review was undertaken on all areas of industrial metering of liquids with an emphasis on gravimetric methods.

  17. Accurate measure by weight of liquids in industry. Final report

    SciTech Connect (OSTI)

    Muller, M.R.

    1992-12-12

    This research`s focus was to build a prototype of a computerized liquid dispensing system. This liquid metering system is based on the concept of altering the representative volume to account for temperature changes in the liquid to be dispensed. This is actualized by using a measuring tank and a temperature compensating displacement plunger. By constantly monitoring the temperature of the liquid, the plunger can be used to increase or decrease the specified volume to more accurately dispense liquid with a specified mass. In order to put the device being developed into proper engineering perspective, an extensive literature review was undertaken on all areas of industrial metering of liquids with an emphasis on gravimetric methods.

  18. Instabilities during liquid migration into superheated hydrothermal systems

    SciTech Connect (OSTI)

    Fitzgerald, Shaun D.; Woods, Andrew W.

    1995-01-26

    Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

  19. Properties of Liquid Plutonium

    SciTech Connect (OSTI)

    Freibert, Franz J.; Mitchell, Jeremy N.; Schwartz, Daniel S.; Saleh, Tarik A.; Migliori, Albert

    2012-08-02

    Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

  20. Liquid Fuels and Natural Gas in the Americas

    Reports and Publications (EIA)

    2014-01-01

    The Energy Information Administration's (EIA) Liquid Fuels and Natural Gas in the Americas report, published today, is a Congressionally-requested study examining the energy trends and developments in the Americas over the past decade. The report focuses on liquid fuels and natural gas—particularly reserves and resources, production, consumption, trade, and investment—given their scale and significance to the region.

  1. Liquid Fuels and Natural Gas in the Americas

    Reports and Publications (EIA)

    2014-01-01

    The Energy Information Administration's (EIA) Liquid Fuels and Natural Gas in the Americas report, published today, is a Congressionally-requested study examining the energy trends and developments in the Americas over the past decade. The report focuses on liquid fuels and natural gas—particularly reserves and resources, production, consumption, trade, and investment—given their scale and significance to the region.

  2. Performance and technical challenges of liquid argon detectors

    SciTech Connect (OSTI)

    Rebel, Brian; /Fermilab

    2011-01-01

    Liquid argon time projection chambers offer the possibility of incredible resolution of particle interactions. This review outlines the ongoing research and development towards the realization of a multi-kiloton scale detector. The ICARUS and ArgoNeuT experiments which make use of liquid argon time projection chamber technology are also described.

  3. Air Liquide- Biogas & Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

  4. Historical Liquid Discharges and Outfalls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Historical Liquid Discharges and Outfalls Historical Liquid Discharges and Outfalls During the 1940s and 1950s, untreated radioactive liquids were discharged to Pueblo and Los Alamos Canyons. August 1, 2013 Contamination from the Acid Canyon outfall has been clean up to below residential levels Contamination from the Acid Canyon outfall has been clean up to below residential levels During the 1940s and 1950s, untreated radioactive liquids were discharged to Pueblo and Los Alamos Canyons.

  5. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko; David J. (Naperville, IL)

    2007-05-08

    The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

  6. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  7. High temperature liquid level sensor

    DOE Patents [OSTI]

    Tokarz, Richard D. (West Richland, WA)

    1983-01-01

    A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

  8. ionic-liquid pretreatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionic-liquid pretreatment - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  9. RHIC The Perfect Liquid

    ScienceCinema (OSTI)

    BNL

    2009-09-01

    Evidence to date suggests that gold-gold collisions the Relativistic Heavy Ion Collider at Brookhaven are indeed creating a new state of hot, dense matter, but one quite different and even more remarkable than had been predicted. Instead of behaving like a gas of free quarks and gluons, as was expected, the matter created in RHIC's heavy ion collisions appears to be more like a "perfect" liquid.

  10. Liquid Dynamics from Neutron Spectrometry

    DOE R&D Accomplishments [OSTI]

    Brockhouse, Bertram N.; Bergsma, J.; Dasannacharya, B. A.; Pope, N. K.

    1962-10-01

    Recent experiments carried out at Chalk River on the dynamics of liquids using neutron inelastic scattering are reviewed, including one by Sakamoto et al., in which the Van Hove self-correlation functions in water at 25 and 75 deg C were determined, and another in which the correlation functions in liquid argon near its triple point were studied. The possible occurrence of short wavelength phonons in classical liquids is discussed, in analogy with their existence in the quantum liquid He4, and in connection with incomplete experiments on liquid tin. (auth)

  11. Low-Emissions Burner Technology using Biomass-Derived Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This factsheet describes a project that developed fuel-flexible, low-emissions burner technology capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as ...

  12. All-Optically Prepared and Controlled Nematic Liquid Crystal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is achieved through photo-induced anisotropy that develops in a monomolecular layer coating the inside surfaces of a liquid crystal cell.DescriptionOne of these surfaces is...

  13. Liquid class predictor for liquid handling of complex mixtures

    DOE Patents [OSTI]

    Seglke, Brent W. (San Ramon, CA); Lekin, Timothy P. (Livermore, CA)

    2008-12-09

    A method of establishing liquid classes of complex mixtures for liquid handling equipment. The mixtures are composed of components and the equipment has equipment parameters. The first step comprises preparing a response curve for the components. The next step comprises using the response curve to prepare a response indicator for the mixtures. The next step comprises deriving a model that relates the components and the mixtures to establish the liquid classes.

  14. Coal-to-Liquids Process Model

    Energy Science and Technology Software Center (OSTI)

    2006-01-01

    A comprehensive Aspen Plus model has been developed to rigorously model coal-to-liquids processes. This portion was developed under Laboratory Directed Research and Development (LDRD) funding. The model is built in a modular fashion to allow rapid reconfiguration for evaluation of process options. Aspen Plus is the framework in which the model is developed. The coal-to-liquids simulation package is an assemble of Aspen Hierarchy Blocks representing subsections of the plant. Each of these Blocks are consideredmore » individual components of the Copyright, which may be extracted and licensed as individual components, but which may be combined with one or more other components, to model general coal-conversion processes, including the following plant operations: (1) coal handling and preparation, (2) coal pyrolysis, combustion, or gasification, (3) syngas conditioning and cleanup, (4) sulfur recovery using Claus-SCOT unit operations, (5) Fischer-Tropsch liquid fuels synthesis, (6) hydrocracking of high molecular weight paraffin, (7) hydrotreating of low molecular weight paraffin and olefins, (8) gas separations, and (9) power generation representing integrated combined cycle technology.« less

  15. Portable liquid collection electrostatic precipitator

    DOE Patents [OSTI]

    Carlson, Duane C.; DeGange, John J.; Halverson, Justin E.

    2005-10-18

    A portable liquid collection electrostatic collection precipitator for analyzing air is provided which is a relatively small, self-contained device. The device has a tubular collection electrode, a reservoir for a liquid, and a pump. The pump pumps the liquid into the collection electrode such that the liquid flows down the exterior of the collection electrode and is recirculated to the reservoir. An air intake is provided such that air to be analyzed flows through an ionization section to ionize analytes in the air, and then flows near the collection electrode where ionized analytes are collected. A portable power source is connected to the air intake and the collection electrode. Ionizable constituents in the air are ionized, attracted to the collection electrode, and precipitated in the liquid. The precipitator may also have an analyzer for the liquid and may have a transceiver allowing remote operation and data collection.

  16. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

    1986-01-01

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  17. Supercooled liquid water Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2012-05-04

    The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

  18. Liquid monobenzoxazine based resin system

    DOE Patents [OSTI]

    Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

    2014-10-07

    The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

  19. Process for preparing liquid wastes

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

    1997-01-01

    A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

  20. Historical Liquid Discharges and Outfalls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    liquids were discharged to Pueblo and Los Alamos Canyons. August 1, 2013 Contamination from the Acid Canyon outfall has been clean up to below residential levels...

  1. Liquid-liquid interfacial nanoparticle assemblies

    DOE Patents [OSTI]

    Emrick, Todd S. (South Deerfield, MA); Russell, Thomas P. (Amherst, MA); Dinsmore, Anthony (Amherst, MA); Skaff, Habib (Amherst, MA); Lin, Yao (Amherst, MA)

    2008-12-30

    Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.

  2. SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS...

    Office of Scientific and Technical Information (OSTI)

    that the liquid fuels production from the FT catalyst was ... and Development for Fossil Energy-Related Resources ... funding was provided by the Illinois Clean Coal Institute. ...

  3. Liquid crystal polyester thermosets

    DOE Patents [OSTI]

    Benicewicz, Brian C.; Hoyt, Andrea E.

    1992-01-01

    The present invention provides (1) curable liquid crystalline polyester monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted naimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro lower alkyl, e.g., methyl, ethyl, or propyl, alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--O-- and --O--C(O)--, (2) thermoset liquid crystalline polyester compositions comprised of heat-cured segments derived from monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 as described above, (3) curable blends of at least two of the polyester monomers and (4) processes of preparing the curable liquid crystalline polyester monomers.

  4. Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

    DOE Patents [OSTI]

    Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

    2015-12-08

    An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.

  5. Phase-Changing Ionic Liquids: CO2 Capture with Ionic Liquids Involving Phase Change

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Notre Dame is developing a new CO2 capture process that uses special ionic liquids (ILs) to remove CO2 from the gas exhaust of coal-fired power plants. ILs are salts that are normally liquid at room temperature, but Notre Dame has discovered a new class of ILs that are solid at room temperature and change to liquid when they bind to CO2. Upon heating, the CO2 is released for storage, and the ILs re-solidify and donate some of the heat generated in the process to facilitate further CO2 release. These new ILs can reduce the energy required to capture CO2 from the exhaust stream of a coal-fired power plant when compared to state-ofthe- art technology.

  6. Liquid-permeable electrode

    DOE Patents [OSTI]

    Folser, George R. (Lower Burrell, PA)

    1980-01-01

    Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

  7. Lithium-loaded liquid scintillators

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Kesanli, Banu (Mersin, TR); Neal, John S. (Knoxville, TN)

    2012-05-15

    The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.

  8. Taylor Instability of Incompressible Liquids

    DOE R&D Accomplishments [OSTI]

    Fermi, E.; von Neumann, J.

    1955-11-01

    A discussion is presented in simplified form of the problem of the growth of an initial ripple on the surface of an incompressible liquid in the presence of an acceleration, g, directed from the outside into the liquid. The model is that of a heavy liquid occupying at t = 0 the half space above the plane z = 0, and a rectangular wave profile is assumed. The theory is found to represent correctly one feature of experimental results, namely the fact that the half wave of the heavy liquid into the vacuum becomes rapidly narrower while the half wave pushing into the heavy liquid becomes more and more blunt. The theory fails to account for the experimental results according to which the front of the wave pushing into the heavy liquid moves with constant velocity. The case of instability at the boundary of 2 fluids of different densities is also explored. Similar results are obtained except that the acceleration of the heavy liquid into the light liquid is reduced.

  9. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

    1995-12-26

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

  10. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, Kattesh V. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Singh, Prahlad (Columbia, MO); Ketring, Alan R. (Columbia, MO)

    1995-01-01

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

  11. Magnetically focused liquid drop radiator

    DOE Patents [OSTI]

    Botts, Thomas E. (Fairfax, VA); Powell, James R. (Shoreham, NY); Lenard, Roger (Redondo Beach, CA)

    1986-01-01

    A magnetically focused liquid drop radiator for application in rejecting rgy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

  12. Magnetically focused liquid drop radiator

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.; Lenard, R.

    1984-12-10

    A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

  13. Active Radiatiive Liquid Lithium (metal) Divertor | Princeton Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Lab Active Radiatiive Liquid Lithium (metal) Divertor Developing a reactor-compatible divertor has been identified as a particularly challenging technology problem for magnetic confinement fusions. Application of Lithium (Li) in NSTX resulted in improved H-mode confinement, H-mode power threshold reduction, and other plasma performance benefits. The liquid lithium coating of the divertor surfaces can also provide a "sacrificial" protective layer to protect the substrate

  14. Electrically Integrated Graphene on Silicon Nitride Liquid Flow Cells for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Resolution TEM - Energy Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Electrically Integrated Graphene on Silicon Nitride Liquid Flow Cells for High Resolution TEM Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary A Berkeley Lab research team led by Paul Alivisatos and Alex Zettl has developed liquid flow cells providing unprecedented resolution and contrast in

  15. Liquid-Phase Deposition of Silicon Nanocrystal Films - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Liquid-Phase Deposition of Silicon Nanocrystal Films University of Minnesota DOE Grant Recipients Contact GRANT About This Technology Technology Marketing Summary Silicon Nanocrystal Deposition A method to deposit colloidal silicon nanocrystal thin films using a liquid-phase process has been developed. The method lowers costs because the films are deposited unfunctionalized (no insulating ligand termination). The process allows for precise control of the size of the crystals; giving

  16. EERE Success Story-Ionic Liquids Used as Wear Reduction, Wins R&D 100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award | Department of Energy Ionic Liquids Used as Wear Reduction, Wins R&D 100 Award EERE Success Story-Ionic Liquids Used as Wear Reduction, Wins R&D 100 Award October 16, 2014 - 11:19am Addthis Partnered with Shell Global Solutions, the Oak Ridge National Laboratory (ORNL) has developed ionic liquids (salts in a liquid state at ambient temperatures) that can be used as friction and wear reduction additives for lubricating oils. The ionic liquids create nanostructured protective

  17. Ionic Liquids Used as Wear Reduction, Wins R&D 100 Award | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Liquids Used as Wear Reduction, Wins R&D 100 Award Ionic Liquids Used as Wear Reduction, Wins R&D 100 Award October 16, 2014 - 11:19am Addthis Partnered with Shell Global Solutions, the Oak Ridge National Laboratory (ORNL) has developed ionic liquids (salts in a liquid state at ambient temperatures) that can be used as friction and wear reduction additives for lubricating oils. The ionic liquids create nanostructured protective films on lubricated metal surfaces, reducing

  18. Preparation and purification of ionic liquids and precursors

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Agrawal, Anoop (Tucson, AZ)

    2010-07-27

    Substantially pure ionic liquids and ionic liquid precursors were prepared. The substantially pure ionic liquid precursors were used to prepare substantially pure ionic liquids.

  19. Method of measuring a liquid pool volume

    DOE Patents [OSTI]

    Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

    1991-01-01

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

  20. Liquid sodium dip seal maintenance system

    DOE Patents [OSTI]

    Briggs, Richard L. (Hempfield Township, Westmoreland County, PA); Meacham, Sterling A. (Hempfield Township, Westmoreland County, PA)

    1980-01-01

    A system for spraying liquid sodium onto impurities associated with liquid dip seals of nuclear reactors. The liquid sodium mixing with the impurities dissolves the impurities in the liquid sodium. The liquid sodium having dissolved and diluted the impurities carries the impurities away from the site thereby cleaning the liquid dip seal and surrounding area. The system also allows wetting of the metallic surfaces of the dip seal thereby reducing migration of radioactive particles across the wetted boundary.

  1. X-rays at Solid-Liquid Surfaces

    SciTech Connect (OSTI)

    Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

    2007-05-02

    Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

  2. Hydrophobic ionic liquids

    DOE Patents [OSTI]

    Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

    1998-10-27

    Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

  3. Hydrophobic ionic liquids

    DOE Patents [OSTI]

    Koch, Victor R.; Nanjundiah, Chenniah; Carlin, Richard T.

    1998-01-01

    Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

  4. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting...

  5. Dielectric liquid pulsed-power switch

    DOE Patents [OSTI]

    Christophorou, Loucas G. (Oak Ridge, TN); Faidas, Homer (Knoxville, TN)

    1990-01-01

    This disclosure identifies dielectric liquids for use as opening and closing switching media in pulsed power technology, and describes a dielectric-liquid-pulsed-power switch empolying flashlamps.

  6. Air Liquide Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Jump to: navigation, search Logo: Air Liquide Hydrogen Energy Name: Air Liquide Hydrogen Energy Address: 6, Rue Cognacq-Jay Place: Paris, France Zip: 75321 Sector:...

  7. Controlled release liquid dosage formulation

    DOE Patents [OSTI]

    Benton, Ben F. (Centerburg, OH); Gardner, David L. (Bellville, OH)

    1989-01-01

    A liquid dual coated dosage formulation sustained release pharmaceutic having substantial shelf life prior to ingestion is disclosed. A dual coating is applied over controlled release cores to form dosage forms and the coatings comprise fats melting at less than approximately 101.degree. F. overcoated with cellulose acetate phthalate or zein. The dual coated dosage forms are dispersed in a sugar based acidic liquid carrier such as high fructose corn syrup and display a shelf life of up to approximately at least 45 days while still retaining their release profiles following ingestion. Cellulose acetate phthalate coated dosage form cores can in addition be dispersed in aqueous liquids of pH <5.

  8. Shock compression of liquid hydrazine

    SciTech Connect (OSTI)

    Garcia, B.O.; Chavez, D.J.

    1995-01-01

    Liquid hydrazine (N{sub 2}H{sub 4}) is a propellant used by the Air Force and NASA for aerospace propulsion and power systems. Because the propellant modules that contain the hydrazine can be subject to debris impacts during their use, the shock states that can occur in the hydrazine need to be characterized to safely predict its response. Several shock compression experiments have been conducted in an attempt to investigate the detonability of liquid hydrazine; however, the experiments results disagree. Therefore, in this study, we reproduced each experiment numerically to evaluate in detail the shock wave profiles generated in the liquid hydrazine. This paper presents the results of each numerical simulation and compares the results to those obtained in experiment. We also present the methodology of our approach, which includes chemical kinetic experiments, chemical equilibrium calculations, and characterization of the equation of state of liquid hydrazine.

  9. Coal and Biomass to Liquids

    Broader source: Energy.gov [DOE]

    Over the last several decades, the Office of Fossil Energy performed RD&D activities that made significant advancements in the areas of coal conversion to liquid fuels and chemicals. Technology...

  10. Fluorescent optical liquid level sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    2001-01-01

    A liquid level sensor comprising a transparent waveguide containing fluorescent material that is excited by light of a first wavelength and emits at a second, longer wavelength. The upper end of the waveguide is connected to a light source at the first wavelength through a beveled portion of the waveguide such that the input light is totally internally reflected within the waveguide above an air/liquid interface in a tank but is transmitted into the liquid below this interface. Light is emitted from the fluorescent material only in those portions of the waveguide that are above the air/liquid interface, to be collected at the upper end of the waveguide by a detector that is sensitive only to the second wavelength. As the interface moves down in the tank, the signal strength from the detector will increase.

  11. ARM - Measurement - Liquid water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water content The concentration (mass/vol) of liquid water droplets in a cloud. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded

  12. Atomizer with liquid spray quenching

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Osborne, Matthew G. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    1998-04-14

    Method and apparatus for making metallic powder particles wherein a metallic melt is atomized by a rotating disk or other atomizer at an atomizing location in a manner to form molten droplets moving in a direction away from said atomizing location. The atomized droplets pass through a series of thin liquid quenching sheets disposed in succession about the atomizing location with each successive quenching sheet being at an increasing distance from the atomizing location. The atomized droplets are incrementally cooled and optionally passivated as they pass through the series of liquid quenching sheets without distorting the atomized droplets from their generally spherical shape. The atomized, cooled droplets can be received in a chamber having a collection wall disposed outwardly of the series of liquid quenching sheets. A liquid quenchant can be flowed proximate the chamber wall to carry the cooled atomized droplets to a collection chamber where atomized powder particles and the liquid quenchant are separated such that the liquid quenchant can be recycled.

  13. Atomizer with liquid spray quenching

    DOE Patents [OSTI]

    Anderson, I.E.; Osborne, M.G.; Terpstra, R.L.

    1998-04-14

    Method and apparatus are disclosed for making metallic powder particles wherein a metallic melt is atomized by a rotating disk or other atomizer at an atomizing location in a manner to form molten droplets moving in a direction away from said atomizing location. The atomized droplets pass through a series of thin liquid quenching sheets disposed in succession about the atomizing location with each successive quenching sheet being at an increasing distance from the atomizing location. The atomized droplets are incrementally cooled and optionally passivated as they pass through the series of liquid quenching sheets without distorting the atomized droplets from their generally spherical shape. The atomized, cooled droplets can be received in a chamber having a collection wall disposed outwardly of the series of liquid quenching sheets. A liquid quenchant can be flowed proximate the chamber wall to carry the cooled atomized droplets to a collection chamber where atomized powder particles and the liquid quenchant are separated such that the liquid quenchant can be recycled. 6 figs.

  14. Corrosion by liquid lead and lead-bismuth: experimental results review and analysis

    SciTech Connect (OSTI)

    Zhang, Jinsuo

    2008-01-01

    Liquid metal technologies for liquid lead and lead-bismuth alloy are under wide investigation and development for advanced nuclear energy systems and waste transmutation systems. Material corrosion is one of the main issues studied a lot recently in the development of the liquid metal technology. This study reviews corrosion by liquid lead and lead bismuth, including the corrosion mechanisms, corrosion inhibitor and the formation of the protective oxide layer. The available experimental data are analyzed by using a corrosion model in which the oxidation and scale removal are coupled. Based on the model, long-term behaviors of steels in liquid lead and lead-bismuth are predictable. This report provides information for the selection of structural materials for typical nuclear reactor coolant systems when selecting liquid lead or lead bismuth as heat transfer media.

  15. SEAPORT LIQUID NATURAL GAS STUDY

    SciTech Connect (OSTI)

    COOK,Z.

    1999-02-01

    The Seaport Liquid Natural Gas Study has attempted to evaluate the potential for using LNG in a variety of heavy-duty vehicle and equipment applications at the Ports of Los Angeles and Oakland. Specifically, this analysis has focused on the handling and transport of containerized cargo to, from and within these two facilities. In terms of containerized cargo throughput, Los Angeles and Oakland are the second and sixth busiest ports in the US, respectively, and together handle nearly 4.5 million TEUs per year. At present, the landside handling and transportation of containerized cargo is heavily dependent on diesel-powered, heavy-duty vehicles and equipment, the utilization of which contributes significantly to the overall emissions impact of port-related activities. Emissions from diesel units have been the subject of increasing scrutiny and regulatory action, particularly in California. In the past two years alone, particulate matter from diesel exhaust has been listed as a toxic air contaminant by CAM, and major lawsuits have been filed against several of California's largest supermarket chains, alleging violation of Proposition 65 statutes in connection with diesel emissions from their distribution facilities. CARE3 has also indicated that it may take further regulatory action relating to the TAC listing. In spite of these developments and the very large diesel emissions associated with port operations, there has been little AFV penetration in these applications. Nearly all port operators interviewed by CALSTART expressed an awareness of the issues surrounding diesel use; however, none appeared to be taking proactive steps to address them. Furthermore, while a less controversial issue than emissions, the dominance of diesel fuel use in heavy-duty vehicles contributes to a continued reliance on imported fuels. The increasing concern regarding diesel use, and the concurrent lack of alternative fuel use and vigorous emissions reduction activity at the Ports provide both the backdrop and the impetus for this study.

  16. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  17. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  18. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Watching a Liquid-Crystal Helix Unwind Print Wednesday, 09 December 2015 00:00 Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can

  19. Nanophosphor composite scintillator with a liquid matrix

    DOE Patents [OSTI]

    McKigney, Edward Allen; Burrell, Anthony Keiran; Bennett, Bryan L.; Cooke, David Wayne; Ott, Kevin Curtis; Bacrania, Minesh Kantilal; Del Sesto, Rico Emilio; Gilbertson, Robert David; Muenchausen, Ross Edward; McCleskey, Thomas Mark

    2010-03-16

    An improved nanophosphor scintillator liquid comprises nanophosphor particles in a liquid matrix. The nanophosphor particles are optionally surface modified with an organic ligand. The surface modified nanophosphor particle is essentially surface charge neutral, thereby preventing agglomeration of the nanophosphor particles during dispersion in a liquid scintillator matrix. The improved nanophosphor scintillator liquid may be used in any conventional liquid scintillator application, including in a radiation detector.

  20. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  1. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  2. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  3. Liquid Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery » Liquid Hydrogen Delivery Liquid Hydrogen Delivery Hydrogen is most commonly transported and delivered as a liquid when high-volume transport is needed in the absence of pipelines. To liquefy hydrogen it must be cooled to cryogenic temperatures through a liquefaction process. Trucks transporting liquid hydrogen are referred to as liquid tankers. Liquefaction Gaseous hydrogen is liquefied by cooling it to below -253°C (-423°F). Once hydrogen is liquefied it can be stored at

  4. A Liquid Layer Solution for the Grid | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Liquid Layer Solution for the Grid A Liquid Layer Solution for the Grid September 15, 2011 - 2:47pm Addthis The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for any solid separator. The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for

  5. Photoluminescence analysis of self induced planer alignment in azo dye dispersed nematic liquid crystal complex

    SciTech Connect (OSTI)

    Kumar, Rishi Sood, Srishti Raina, K. K.

    2014-04-24

    We have developed azo dye doped nematic liquid crystal complex for advanced photonic liquid crystal display technology aspects. Disperse orange azo dye self introduced planer alignment in the nematic liquid crystal without any surface anchoring treatment. Planer alignment was characterized by optical polarizing microscopy. The electro-optical switching response of dye disperse planer aligned nematic cell was investigated as a function of applied voltage with the help of photoluminescence spectrophotometer for the tuning of photoluminescence contrast.

  6. Liquid-phase chromatography detector

    DOE Patents [OSTI]

    Voigtman, Edward G. (Gainesville, FL); Winefordner, James D. (Gainesville, FL); Jurgensen, Arthur R. (Gainesville, FL)

    1983-01-01

    A liquid-phase chromatography detector comprising a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focussing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof.

  7. Liquid-phase chromatography detector

    DOE Patents [OSTI]

    Voigtman, E.G.; Winefordner, J.D.; Jurgensen, A.R.

    1983-11-08

    A liquid-phase chromatography detector comprises a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focusing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof. 5 figs.

  8. Vertical tube liquid pollutant separators

    SciTech Connect (OSTI)

    Lynch, W.M.

    1982-06-08

    A plurality of elongated hollow, circular, foraminous substantially vertical tubes contiguously stacked transversely to the direction flowing liquid such as waste water containing foreign matter, I.E., settable solids and free oil, in a coalescer-separator apparatus provide a filter body providing for significant surface area contact by the liquid on both inside and outside surfaces of the tubes to entrap the foreign matter but defining substantially vertical passages permitting the entrapped foreign matter to be gravity separated with the lighter matter coalescing and floating upwardly and the heavier matter settling downwardly so that substantially clarified effluent flows from the apparatus. The stacked tube filter body is contained within an insulated closed container of a sufficient capacity, and the arrays of holes in the tube walls are coordinated with respect to the intended volumetric capacity of the apparatus, so that turbulence in the liquid flowing through the filter body is minimized.

  9. Ventura_E_liquids.pdf

    Gasoline and Diesel Fuel Update (EIA)

    Liquids Reserve Class No 2004 Proved Liquids Reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl > 10,000 Mbbl Study Area Outline 0 4 8 2 6 Miles ± The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by

  10. ARM - Measurement - Liquid water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water path A measure of the weight of the liquid water droplets in the atmosphere above a unit surface area on the earth, given in units of kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument

  11. Method of measuring a liquid pool volume

    DOE Patents [OSTI]

    Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

    1991-03-19

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

  12. Ultra-high-resolution time projection chambers with liquid crystal backplanes

    SciTech Connect (OSTI)

    Monreal, Benjamin

    2014-10-15

    We investigated the possibility of incorporating a liquid-crystal device into a gas ionization detector. After extensive R&D on several candidate liquid-crystal technologies, we developed some novel materials allowing twisted nematic liquid-crystal layers to be coupled directly to gas ionization counters. However, the resulting structures were unsuitable for large-scale or practical use. We tested several technologies known to result in mechanically-robust liquid crystal electrooptic layers, but found poor behavior in the detector context.

  13. Liquid-film electron stripper

    DOE Patents [OSTI]

    Gavin, Basil F. (Albion, CA)

    1986-01-01

    An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one said of the disc's periphery and with a highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90.degree. angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

  14. Fracturing And Liquid CONvection

    Energy Science and Technology Software Center (OSTI)

    2012-02-29

    FALCON has been developed to enable simulation of the tightly coupled fluid-rock behavior in hydrothermal and engineered geothermal system (EGS) reservoirs, targeting the dynamics of fracture stimulation, fluid flow, rock deformation, and heat transport in a single integrated code, with the ultimate goal of providing a tool that can be used to test the viability of EGS in the United States and worldwide. Reliable reservoir performance predictions of EGS systems require accurate and robust modelingmore » for the coupled thermal-hydrological-mechanical processes. Conventionally, these types of problems are solved using operator-splitting methods, usually by coupling a subsurface flow and heat transport simulator with a solid mechanics simulator via input files. FALCON eliminates the need for using operator-splitting methods to simulate these systems, and the scalability of the underlying MOOSE architecture allows for simulating these tightly coupled processes at the reservoir scale, allowing for examination of the system as a whole (something the operator-splitting methodologies generally cannot do).« less

  15. Ultrastable Superbase-Derived Protic Ionic Liquids - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    protic ionic liquids (PILs). Protic ionic liquids can be used in protonexchange membrane fuel cells for the transformation of chemical energy to electrical energy. These liquids...

  16. New York Natural Gas Liquids Proved Reserves (Million Barrels...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Date: 12312016 Referring Pages: Natural Gas Liquids Proved Reserves as of Dec. 31 New York Natural Gas Liquids Proved Reserves Natural Gas Liquids Proved Reserves as of...

  17. An improved model for the transit entropy of monatomic liquids

    SciTech Connect (OSTI)

    Wallace, Duane C; Chisolm, Eric D; Bock, Nicolas

    2009-01-01

    In the original formulation of V-T theory for monatomic liquid dynamics, the transit contribution to entropy was taken to be a universal constant, calibrated to the constant-volume entropy of melting. This model suffers two deficiencies: (a) it does not account for experimental entropy differences of {+-}2% among elemental liquids, and (b) it implies a value of zero for the transit contribution to internal energy. The purpose of this paper is to correct these deficiencies. To this end, the V-T equation for entropy is fitted to an overall accuracy of {+-}0.1% to the available experimental high temperature entropy data for elemental liquids. The theory contains two nuclear motion contributions: (a) the dominant vibrational contribution S{sub vib}(T/{theta}{sub 0}), where T is temperature and {theta}{sub 0} is the vibrational characteristic temperature, and (b) the transit contribution S{sub tr}(T/{theta}{sub tr}), where {theta}{sub tr} is a scaling temperature for each liquid. The appearance of a common functional form of S{sub tr} for all the liquids studied is a property of the experimental data, when analyzed via the V-T formula. The resulting S{sub tr} implies the correct transit contribution to internal energy. The theoretical entropy of melting is derived, in a single formula applying to normal and anomalous melting alike. An ab initio calculation of {theta}{sub 0}, based on density functional theory, is reported for liquid Na and Cu. Comparison of these calculations with the above analysis of experimental entropy data provides verification of V-T theory. In view of the present results, techniques currently being applied in ab initio simulations of liquid properties can be employed to advantage in the further testing and development of V-T theory.

  18. Waste Treatment Plant Liquid Effluent Treatability Evaluation

    SciTech Connect (OSTI)

    LUECK, K.J.

    2001-06-07

    Bechtel National, Inc. (BNI) provided a forecast of the radioactive, dangerous liquid effluents expected to be generated by the Waste Treatment Plant (WTP). The forecast represents the liquid effluents generated from the processing of 25 distinct batches of tank waste through the WTP. The WTP liquid effluents will be stored, treated, and disposed of in the Liquid Effluent Retention Facility (LERF) and the Effluent Treatment Facility (ETF). Fluor Hanford, Inc. (FH) evaluated the treatability of the WTP liquid effluents in the LERFIETF. The evaluation was conducted by comparing the forecast to the LERFIETF treatability envelope, which provides information on the items that determine if a liquid effluent is acceptable for receipt and treatment at the LERFIETF. The WTP liquid effluent forecast is outside the current LERFlETF treatability envelope. There are several concerns that must be addressed before the WTP liquid effluents can be accepted at the LERFIETF.

  19. Alternative Liquid Fuels (ALF) | Open Energy Information

    Open Energy Info (EERE)

    Liquid Fuels (ALF) Jump to: navigation, search Name: Alternative Liquid Fuels (ALF) Address: P.O. Box 76 Place: McArthur, Ohio Zip: 45651 Sector: Biofuels, Renewable Energy,...

  20. Nanoparticle enhanced ionic liquid heat transfer fluids

    DOE Patents [OSTI]

    Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

    2014-08-12

    A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

  1. Method for enhanced atomization of liquids

    DOE Patents [OSTI]

    Thompson, Richard E. (27121 Puerta del Oro, Mission Viejo, CA 92691); White, Jerome R. (44755 Wyandotte, Hemet, CA 92544)

    1993-01-01

    In a process for atomizing a slurry or liquid process stream in which a slurry or liquid is passed through a nozzle to provide a primary atomized process stream, an improvement which comprises subjecting the liquid or slurry process stream to microwave energy as the liquid or slurry process stream exits the nozzle, wherein sufficient microwave heating is provided to flash vaporize the primary atomized process stream.

  2. Interaction between Supersonic Disintegrating Liquid Jets and Their Shock Waves

    SciTech Connect (OSTI)

    Im, Kyoung-Su; Cheong, Seong-Kyun; Liu, X.; Wang Jin; Lai, M.-C.; Tate, Mark W.; Ercan, Alper; Renzi, Matthew J.; Schuette, Daniel R.; Gruner, Sol M.

    2009-02-20

    We used ultrafast x radiography and developed a novel multiphase numerical simulation to reveal the origin and the unique dynamics of the liquid-jet-generated shock waves and their interactions with the jets. Liquid-jet-generated shock waves are transiently correlated to the structural evolution of the disintegrating jets. The multiphase simulation revealed that the aerodynamic interaction between the liquid jet and the shock waves results in an intriguing ambient gas distribution in the vicinity of the shock front, as validated by the ultrafast x-radiography measurements. The excellent agreement between the data and the simulation suggests the combined experimental and computational approach should find broader applications in predicting and understanding dynamics of highly transient multiphase flows.

  3. Liquid cooled counter flow turbine bucket

    DOE Patents [OSTI]

    Dakin, James T. (Schenectady, NY)

    1982-09-21

    Means and a method are provided whereby liquid coolant flows radially outward through coolant passages in a liquid cooled turbine bucket under the influence of centrifugal force while in contact with countercurrently flowing coolant vapor such that liquid is entrained in the flow of vapor resulting in an increase in the wetted cooling area of the individual passages.

  4. Apparatus and method for spraying liquid materials

    DOE Patents [OSTI]

    Alvarez, J.L.; Watson, L.D.

    1988-01-21

    A method for spraying liquids involving a flow of gas which shears the liquid. A flow of gas is introduced in a converging-diverging nozzle where it meets and shears the liquid into small particles which are of a size and uniformity which can be controlled through adjustment of pressures and gas velocity. 5 figs.

  5. Apparatus and method for spraying liquid materials

    DOE Patents [OSTI]

    Alvarez, Joseph L.; Watson, Lloyd D.

    1990-01-01

    A method for spraying liquids involving a flow of gas which shears the liquid. A flow of gas is introduced in a converging-diverging nozzle where it meets and shears the liquid into small particles which are of a size and uniformity which can be controlled through adjustment of pressures and gas velocity.

  6. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D. [Benham Companies LLC (USA)

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  7. Producing liquid fuels from coal: prospects and policy issues

    SciTech Connect (OSTI)

    James T. Bartis; Frank Camm; David S. Ortiz

    2008-07-01

    The increase in world oil prices since 2003 has prompted renewed interest in producing and using liquid fuels from unconventional resources, such as biomass, oil shale, and coal. This book focuses on issues and options associated with establishing a commercial coal-to-liquids (CTL) industry within the United States. It describes the technical status, costs, and performance of methods that are available for producing liquids from coal; the key energy and environmental policy issues associated with CTL development; the impediments to early commercial experience; and the efficacy of alternative federal incentives in promoting early commercial experience. Because coal is not the only near-term option for meeting liquid-fuel needs, this book also briefly reviews the benefits and limitations of other approaches, including the development of oil shale resources, the further development of biomass resources, and increasing dependence on imported petroleum. A companion document provides a detailed description of incentive packages that the federal government could offer to encourage private-sector investors to pursue early CTL production experience while reducing the probability of bad outcomes and limiting the costs that might be required to motivate those investors. (See Rand Technical Report TR586, Camm, Bartis, and Bushman, 2008.) 114 refs., 2 figs., 16 tabs., 3 apps.

  8. Catalyst for hydrotreating carbonaceous liquids

    DOE Patents [OSTI]

    Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

    1982-01-01

    A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

  9. High pressure liquid level monitor

    DOE Patents [OSTI]

    Bean, Vern E. (Frederick, MD); Long, Frederick G. (Ijamsville, MD)

    1984-01-01

    A liquid level monitor for tracking the level of a coal slurry in a high-pressure vessel including a toroidal-shaped float with magnetically permeable bands thereon disposed within the vessel, two pairs of magnetic field generators and detectors disposed outside the vessel adjacent the top and bottom thereof and magnetically coupled to the magnetically permeable bands on the float, and signal processing circuitry for combining signals from the top and bottom detectors for generating a monotonically increasing analog control signal which is a function of liquid level. The control signal may be utilized to operate high-pressure control valves associated with processes in which the high-pressure vessel is used.

  10. Bent core liquid crystal elastomers

    SciTech Connect (OSTI)

    Verduzco, R.; DiMasi, E.; Luchette, P.; Ho Hong, S.; Harden, J.; Palffy-Muhoray, P.; Kilbey II, S.M.; Sprunt, S.; Gleeson, G.T. Jakli, A.

    2010-07-28

    Liquid crystal (LC) elastomers with bent-core side-groups incorporate the properties of bent-core liquid crystals in a flexible and self-supporting polymer network. Bent-core liquid crystal elastomers (BCEs) with uniform alignment were prepared by attaching a reactive bent-core LC to poly(hydrogenmethylsiloxane) and crosslinking with a divinyl crosslinker. Phase behavior studies indicate a nematic phase over a wide temperature range that approaches room temperature, and thermoelastic measurements show that these BCEs can reversibly change their length by more than a factor of two upon heating and cooling. Small-angle X-ray scattering studies reveal multiple, broad low-angle peaks consistent with short-range smectic C order of the bent-core side groups. A comparison of these patterns with predictions of a Landau model for short-range smectic C order shows that the length scale for smectic ordering in BCEs is similar to that seen in pure bent-core LCs. The combination of rubber elasticity and smectic ordering of the bent-core side groups suggests that BCEs may be promising materials for sensing, actuating, and other advanced applications.

  11. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  12. Mobile interfaces: Liquids as a perfect structural material for multifunctional, antifouling surfaces

    SciTech Connect (OSTI)

    Grinthal, Alison; Aizenberg, Joanna

    2013-10-14

    Life creates some of its most robust, extreme surface materials not from solids but from liquids: a purely liquid interface, stabilized by underlying nanotexture, makes carnivorous plant leaves ultraslippery, the eye optically perfect and dirt-resistant, our knees lubricated and pressure-tolerant, and insect feet reversibly adhesive and shape-adaptive. Novel liquid surfaces based on this idea have recently been shown to display unprecedented omniphobic, self-healing, anti-ice, antifouling, optical, and adaptive properties. In this Perspective, we present a framework and a path forward for developing and designing such liquid surfaces into sophisticated, versatile multifunctional materials. Drawing on concepts from solid materials design and fluid dynamics, we outline how the continuous dynamics, responsiveness, and multiscale patternability of a liquid surface layer can be harnessed to create a wide range of unique, active interfacial functions-able to operate in harsh, changing environments-not achievable with static solids. We discuss how, in partnership with the underlying substrate, the liquid surface can be programmed to adaptively and reversibly reconfigure from a defect-free, molecularly smooth, transparent interface through a range of finely tuned liquid topographies in response to environmental stimuli. In conclusion, with nearly unlimited design possibilities and unmatched interfacial properties, liquid materials-as long-term stable interfaces yet in their fully liquid state-may potentially transform surface design everywhere from medicine to architecture to energy infrastructure.

  13. Mobile interfaces: Liquids as a perfect structural material for multifunctional, antifouling surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Grinthal, Alison; Aizenberg, Joanna

    2013-10-14

    Life creates some of its most robust, extreme surface materials not from solids but from liquids: a purely liquid interface, stabilized by underlying nanotexture, makes carnivorous plant leaves ultraslippery, the eye optically perfect and dirt-resistant, our knees lubricated and pressure-tolerant, and insect feet reversibly adhesive and shape-adaptive. Novel liquid surfaces based on this idea have recently been shown to display unprecedented omniphobic, self-healing, anti-ice, antifouling, optical, and adaptive properties. In this Perspective, we present a framework and a path forward for developing and designing such liquid surfaces into sophisticated, versatile multifunctional materials. Drawing on concepts from solid materials design andmore » fluid dynamics, we outline how the continuous dynamics, responsiveness, and multiscale patternability of a liquid surface layer can be harnessed to create a wide range of unique, active interfacial functions-able to operate in harsh, changing environments-not achievable with static solids. We discuss how, in partnership with the underlying substrate, the liquid surface can be programmed to adaptively and reversibly reconfigure from a defect-free, molecularly smooth, transparent interface through a range of finely tuned liquid topographies in response to environmental stimuli. In conclusion, with nearly unlimited design possibilities and unmatched interfacial properties, liquid materials-as long-term stable interfaces yet in their fully liquid state-may potentially transform surface design everywhere from medicine to architecture to energy infrastructure.« less

  14. Process for vaporizing a liquid hydrocarbon fuel

    DOE Patents [OSTI]

    Szydlowski, Donald F. (East Hartford, CT); Kuzminskas, Vaidotas (Glastonbury, CT); Bittner, Joseph E. (East Hartford, CT)

    1981-01-01

    The object of the invention is to provide a process for vaporizing liquid hydrocarbon fuels efficiently and without the formation of carbon residue on the apparatus used. The process includes simultaneously passing the liquid fuel and an inert hot gas downwardly through a plurality of vertically spaed apart regions of high surface area packing material. The liquid thinly coats the packing surface, and the sensible heat of the hot gas vaporizes this coating of liquid. Unvaporized liquid passing through one region of packing is uniformly redistributed over the top surface of the next region until all fuel has been vaporized using only the sensible heat of the hot gas stream.

  15. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection ...

  16. Testing of Liquid Lithium Limiters in CDX-U

    SciTech Connect (OSTI)

    R. Majeski; R. Kaita; M. Boaz; P. Efthimion; T. Gray; B. Jones; D. Hoffman; H. Kugel; J. Menard; T. Munsat; A. Post-Zwicker; V. Soukhanovskii; J. Spaleta; G. Taylor; J. Timberlake; R. Woolley; L. Zakharov; M. Finkenthal; D. Stutman; G. Antar; R. Doerner; S. Luckhardt; R. Seraydarian; R. Maingi; M. Maiorano; S. Smith; D. Rodgers

    2004-07-30

    Part of the development of liquid metals as a first wall or divertor for reactor applications must involve the investigation of plasma-liquid metal interactions in a functioning tokamak. Most of the interest in liquid-metal walls has focused on lithium. Experiments with lithium limiters have now been conducted in the Current Drive Experiment-Upgrade (CDX-U) device at the Princeton Plasma Physics Laboratory. Initial experiments used a liquid-lithium rail limiter (L3) built by the University of California at San Diego. Spectroscopic measurements showed some reduction of impurities in CDX-U plasmas with the L3, compared to discharges with a boron carbide limiter. While no reduction in recycling was observed with the L3, which had a plasma-wet area of approximately 40 cm2, subsequent experiments with a larger area fully toroidal lithium limiter demonstrated significant reductions in both recycling and in impurity levels. Two series of experiments with the toroidal limiter have now be en performed. In each series, the area of exposed, clean lithium was increased, until in the latest experiments the liquid-lithium plasma-facing area was increased to 2000 cm2. Under these conditions, the reduction in recycling required a factor of eight increase in gas fueling in order to maintain the plasma density. The loop voltage required to sustain the plasma current was reduced from 2 V to 0.5 V. This paper summarizes the technical preparations for lithium experiments and the conditioning required to prepare the lithium surface for plasma operations. The mechanical response of the liquid metal to induced currents, especially through contact with the plasma, is discussed. The effect of the lithium-filled toroidal limiter on plasma performance is also briefly described.

  17. Radiation Chemistry and Photochemistry of Ionic Liquids

    SciTech Connect (OSTI)

    Wishart, J.F.; Takahaski, K.

    2010-12-01

    As our understanding of ionic liquids and their tunable properties has grown, it is possible to see many opportunities for ionic liquids to contribute to the sustainable use of energy. The potential safety and environmental benefits of ionic liquids, as compared to conventional solvents, have attracted interest in their use as processing media for the nuclear fuel cycle. Therefore, an understanding of the interactions of ionizing radiation and photons with ionic liquids is strongly needed. However, the radiation chemistry of ionic liquids is still a relatively unexplored topic although there has been a significant increase in the number of researchers in the field recently. This article provides a brief introduction to ionic liquids and their interesting properties, and recent advances in the radiation chemistry and photochemistry of ionic liquids. In this article, we will mainly focus on excess electron dynamics and radical reaction dynamics. Because solvation dynamics processes in ionic liquids are much slower than in molecular solvents, one of the distinguishing characteristics is that pre-solvated electrons play an important role in ionic liquid radiolysis. It will be also shown that the reaction dynamics of radical ions is significantly different from that observed in molecular solvents because of the Coulombic screening effects and electrostatic interactions in ionic liquids.

  18. Bearing for liquid metal pump

    DOE Patents [OSTI]

    Dickinson, Robert J. (Shaler Township, Allegheny County, PA); Wasko, John (Plum Borough, PA); Pennell, William E. (Unity Township, Allegheny County, PA)

    1984-01-01

    A liquid metal pump bearing support comprises a series of tangentially oriented spokes that connect the bearing cylinder to the pump internals structure. The spokes may be arranged in a plurality of planes extending from the bearing cylinder to the pump internals with the spokes in one plane being arranged alternately with those in the next plane. The bearing support structure provides the pump with sufficient lateral support for the bearing structure together with the capability of accommodating differential thermal expansion without adversely affecting pump performance.

  19. Liquid-sodium thermoacoustic engine

    SciTech Connect (OSTI)

    Migliori, A.; Swift, G.W.

    1988-08-01

    We have constructed a thermoacoustic engine that uses liquid sodium as its working substance. The engine generates acoustic power using heat flowing from a high-temperature source to a low-temperature sink. The measured performance of this engine disagrees significantly with numerical calculations based on our theory of thermoacoustic engines. The efficiency of the engine is a substantial fraction of Carnot's efficiency, and its power density is comparable to that of the conventional heat engines in widespread use. Thus we expect this type of engine to be of practical, economic importance.

  20. Natural Gas Plant Liquids Production

    Gasoline and Diesel Fuel Update (EIA)

    Liquids Production (Million Barrels) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012 2013 2014 View History U.S. 714 745 784 865 931 1,124 1979-2014 Alabama 5 6 6 5 6 5 1979-2014 Alaska 13 11 11 11 11 17 1979-2014 Arkansas 0 0 0 0 0 0 1979-2014 California 11 10 10 10 11 10 1979-2014 Coastal Region Onshore 1 1 1 1 1 1 1979-2014 Los Angeles Basin Onshore 0 0 0 0 0 0 1979-2014 San Joaquin Basin

  1. Liquid Silane Routes to Electronic Materials

    SciTech Connect (OSTI)

    Douglas L. Schulz; Xuliang Dai; Kendric J. Nelson; Konstantin Pokhodnya; Justin M. Hoey; Iskander S. Akhatov; Orven F. Swenson; Jeremiah Smith; John Lovaasen; Matt Robinson; Scott Payne; Philip R. Boudjouk

    2008-12-04

    New chemistries based upon liquid cyclohexasilane (Si{sub 6}H{sub 12} or CHS) have been used as precursors to silicon-containing electronic materials. Spin-coating of CHS-based inks with subsequent UV light and/or thermal treatment yielded amorphous silicon (a-Si:H) films. While initial ink chemistries gave a-Si:H with high resistivity (i.e., > 10{sup 6} {Omega}.cm), several doping strategies are under development to address this limitation. In this contribution, the current status of solution processed rectifying diodes and field effect transistors fabricated from CHS-based inks will be presented. Additionally, a new printing approach termed collimated aerosol beam direct write (CAB-DW{sup TM}) was developed that allows the deposition of printed Ag lines 5 {mu}m in width. A status update will be given where CHS-based inks have been used to CAB-DW silicon-based features with linewidths <10 {mu}m. Assuming silicon thin film materials with good electrical properties will be developed, there may be significant cost advantages associated with the ability to controllably deposit the semiconductor in a metered fashion.

  2. Stationary Liquid Fuel Fast Reactor

    SciTech Connect (OSTI)

    Yang, Won Sik; Grandy, Andrew; Boroski, Andrew; Krajtl, Lubomir; Johnson, Terry

    2015-09-30

    For effective burning of hazardous transuranic (TRU) elements of used nuclear fuel, a transformational advanced reactor concept named SLFFR (Stationary Liquid Fuel Fast Reactor) was proposed based on stationary molten metallic fuel. The fuel enters the reactor vessel in a solid form, and then it is heated to molten temperature in a small melting heater. The fuel is contained within a closed, thick container with penetrating coolant channels, and thus it is not mixed with coolant nor flow through the primary heat transfer circuit. The makeup fuel is semi- continuously added to the system, and thus a very small excess reactivity is required. Gaseous fission products are also removed continuously, and a fraction of the fuel is periodically drawn off from the fuel container to a processing facility where non-gaseous mixed fission products and other impurities are removed and then the cleaned fuel is recycled into the fuel container. A reference core design and a preliminary plant system design of a 1000 MWt TRU- burning SLFFR concept were developed using TRU-Ce-Co fuel, Ta-10W fuel container, and sodium coolant. Conservative design approaches were adopted to stay within the current material performance database. Detailed neutronics and thermal-fluidic analyses were performed to develop a reference core design. Region-dependent 33-group cross sections were generated based on the ENDF/B-VII.0 data using the MC2-3 code. Core and fuel cycle analyses were performed in theta-r-z geometries using the DIF3D and REBUS-3 codes. Reactivity coefficients and kinetics parameters were calculated using the VARI3D perturbation theory code. Thermo-fluidic analyses were performed using the ANSYS FLUENT computational fluid dynamics (CFD) code. Figure 0.1 shows a schematic radial layout of the reference 1000 MWt SLFFR core, and Table 0.1 summarizes the main design parameters of SLFFR-1000 loop plant. The fuel container is a 2.5 cm thick cylinder with an inner radius of 87.5 cm. The fuel container is penetrated by twelve hexagonal control assembly (CA) guide tubes, each of which has 3.0 mm thickness and 69.4 mm flat-to-flat outer distance. The distance between two neighboring CA guide tube is selected to be 26 cm to provide an adequate space for CA driving systems. The fuel container has 18181 penetrating coolant tubes of 6.0 mm inner diameter and 2.0 mm thickness. The coolant tubes are arranged in a triangular lattice with a lattice pitch of 1.21 cm. The fuel, structure, and coolant volume fractions inside the fuel container are 0.386, 0.383, and 0.231, respectively. Separate steel reflectors and B4C shields are used outside of the fuel container. Six gas expansion modules (GEMs) of 5.0 cm thickness are introduced in the radial reflector region. Between the radial reflector and the fuel container is a 2.5 cm sodium gap. The TRU inventory at the beginning of equilibrium cycle (BOEC) is 5081 kg, whereas the TRU inventory at the beginning of life (BOL) was 3541 kg. This is because the equilibrium cycle fuel contains a significantly smaller fissile fraction than the LWR TRU feed. The fuel inventory at BOEC is composed of 34.0 a/o TRU, 41.4 a/o Ce, 23.6 a/o Co, and 1.03 a/o solid fission products. Since uranium-free fuel is used, a theoretical maximum TRU consumption rate of 1.011 kg/day is achieved. The semi-continuous fuel cycle based on the 300-batch, 1- day cycle approximation yields a burnup reactivity loss of 26 pcm/day, and requires a daily reprocessing of 32.5 kg of SLFFR fuel. This yields a daily TRU charge rate of 17.45 kg, including a makeup TRU feed of 1.011 kg recovered from the LWR used fuel. The charged TRU-Ce-Co fuel is composed of 34.4 a/o TRU, 40.6 a/o Ce, and 25.0 a/o Co.

  3. Method of fabrication of supported liquid membranes

    DOE Patents [OSTI]

    Luebke, David R.; Hong, Lei; Myers, Christina R.

    2015-11-17

    Method for the fabrication of a supported liquid membrane having a dense layer in contact with a porous layer, and a membrane liquid layer within the interconnected pores of the porous layer. The dense layer is comprised of a solidified material having an average pore size less than or equal to about 0.1 nanometer, while the porous layer is comprised of a plurality of interconnected pores and has an average pore size greater than 10 nanometers. The supported liquid membrane is fabricated through the preparation of a casting solution of a membrane liquid and a volatile solvent. A pressure difference is established across the dense layer and porous layer, the casting solution is applied to the porous layer, and the low viscosity casting solution is drawn toward the dense layer. The volatile solvent is evaporated and the membrane liquid precipitates, generating a membrane liquid layer in close proximity to the dense layer.

  4. Engineering Development of Slurry Bubble Column Reactor (SBCR) Technology

    SciTech Connect (OSTI)

    Puneet Gupta

    2002-07-31

    This report summarizes the procedures used and results obtained in determining radial gas holdup profiles, via gamma ray scanning, and in assessing liquid and gas mixing parameters, via radioactive liquid and gas tracers, during Fischer Tropsch synthesis. The objectives of the study were (i) to develop a procedure for detection of gas holdup radial profiles in operating reactors and (ii) to test the ability of the developed, previously described, engineering models to predict the observed liquid and gas mixing patterns. It was shown that the current scanning procedures were not precise enough to obtain an accurate estimate of the gas radial holdup profile and an improved protocol for future use was developed. The previously developed physically based model for liquid mixing was adapted to account for liquid withdrawal from the mid section of the column. The ability of our engineering mixing models for liquid and gas phase to predict both liquid and gas phase tracer response was established and illustrated.

  5. Development of National Liquid Propane (Autogas) Refueling Network...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon arravt059tiday2012o...

  6. Development of National Liquid Propane (Autogas) Refueling Network...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt059tiday2011...

  7. Development of National Liquid Propane (Autogas) Refueling Network...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon tiarravt059day2010...

  8. Development of National Liquid Propane (Autogas) Refueling Network, Clean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    School Bus/Vehicle Incentive & Green Jobs Outreach Program | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon arravt059_ti_day_2012_o

  9. Development of National Liquid Propane (Autogas) Refueling Network, Clean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    School Bus/Vehicle Incentive & Green Jobs Outreach Program | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt059_ti_day_2011

  10. Development of National Liquid Propane (Autogas) Refueling Network, Clean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    School Bus/Vehicle Incentive & Green Jobs Outreach Program | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon tiarravt059_day_2010

  11. A New Model for Liquid Water Absorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model for Liquid Water Absorption For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Liquid water path (LWP) is a critical measurement for a wide range of atmospheric studies, as the amount of liquid in a cloud is critical to understanding many cloud processes. For example, the radiative impact of the cloud (in both the longwave and shortwave portions of the spectrum) depends heavily on the LWP. Thus, the Atmospheric

  12. Liquid metal cooled nuclear reactor plant system

    DOE Patents [OSTI]

    Hunsbedt, Anstein (Los Gatos, CA); Boardman, Charles E. (Saratoga, CA)

    1993-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

  13. Reimagining liquid transportation fuels : sunshine to petrol.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Hogan, Roy E., Jr.; McDaniel, Anthony H.; Siegel, Nathan Phillip; Dedrick, Daniel E.; Stechel, Ellen Beth; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D.; Ambrosini, Andrea; Coker, Eric Nicholas; Staiger, Chad Lynn; Chen, Ken Shuang; Ermanoski, Ivan; Kellog, Gary L.

    2012-01-01

    Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO{sub 2} + (x+1)H{sub 2}O {yields} C{sub x}H{sub 2x+2}(liquid fuel) + (1.5x+.5)O{sub 2} Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO{sub 2} and H{sub 2}O to CO and H{sub 2}, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO{sub 2} to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

  14. Liquid Resources LLC | Open Energy Information

    Open Energy Info (EERE)

    search Name: Liquid Resources LLC Place: Medina, Ohio Zip: 44258 Product: Produces bioethanol from waste. Coordinates: 43.174659, -89.082003 Show Map Loading map......

  15. Liquid phase sintering of silicon carbide

    DOE Patents [OSTI]

    Cutler, R.A.; Virkar, A.V.; Hurford, A.C.

    1989-05-09

    Liquid phase sintering is used to densify silicon carbide based ceramics using a compound comprising a rare earth oxide and aluminum oxide to form liquids at temperatures in excess of 1,600 C. The resulting sintered ceramic body has a density greater than 95% of its theoretical density and hardness in excess of 23 GPa. Boron and carbon are not needed to promote densification and silicon carbide powder with an average particle size of greater than one micron can be densified via the liquid phase process. The sintered ceramic bodies made by the present invention are fine grained and have secondary phases resulting from the liquid phase. 4 figs.

  16. Closed-field capacitive liquid level sensor

    DOE Patents [OSTI]

    Kronberg, J.W.

    1998-03-03

    A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units. 12 figs.

  17. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may...

  18. Hydrogen Production: Biomass-Derived Liquid Reforming

    Broader source: Energy.gov [DOE]

    Liquids derived from biomass resources—including ethanol and bio-oils—can be reformed to produce hydrogen in a process similar to natural gas reforming.

  19. Air Liquide Group | Open Energy Information

    Open Energy Info (EERE)

    search Name: Air Liquide Group Place: Paris, France Zip: 75321 Sector: Hydro, Hydrogen Product: Paris-based manufacturer of industrial and medical gases. The company is...

  20. ,"Natural Gas Plant Liquids Proved Reserves"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2013,"06301979" ,"Release...

  1. Membrane separation of ionic liquid solutions

    DOE Patents [OSTI]

    Campos, Daniel; Feiring, Andrew Edward; Majumdar, Sudipto; Nemser, Stuart

    2015-09-01

    A membrane separation process using a highly fluorinated polymer membrane that selectively permeates water of an aqueous ionic liquid solution to provide dry ionic liquid. Preferably the polymer is a polymer that includes polymerized perfluoro-2,2-dimethyl-1,3-dioxole (PDD). The process is also capable of removing small molecular compounds such as organic solvents that can be present in the solution. This membrane separation process is suitable for drying the aqueous ionic liquid byproduct from precipitating solutions of biomass dissolved in ionic liquid, and is thus instrumental to providing usable lignocellulosic products for energy consumption and other industrial uses in an environmentally benign manner.

  2. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report You are accessing a document from the Department of Energy's (DOE)...

  3. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report In this Quarter, the research was focused continually on the...

  4. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 The research was...

  5. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 You are accessing a...

  6. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 You are accessing...

  7. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 In this Quarter, the...

  8. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report In this Quarter, the research was focused continually on the two...

  9. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report You are accessing a document from the Department of...

  10. Communication: Quantum molecular dynamics simulation of liquid...

    Office of Scientific and Technical Information (OSTI)

    Communication: Quantum molecular dynamics simulation of liquid para-hydrogen by nuclear and electron wave packet approach Citation Details In-Document Search Title: Communication:...

  11. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Coal-Biomass to Liquids Turning coal into liquid fuels like gasoline, diesel and jet fuel, with biomass to reduce carbon dioxide emissions, is the main goal of the Coal and Coal-Biomass to Liquids program. The program also aims to reduce the cost of these low-emission fuels, and will take advantage of carbon capture and sequestration technologies to further reduce greenhouse gas emissions. Other Coal and Coal-Biomass to Liquids (C&CBTL) Program Activities: The C&CBTL Program

  12. Closed-field capacitive liquid level sensor

    DOE Patents [OSTI]

    Kronberg, J.W.

    1995-01-01

    A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

  13. Anomalous liquid scintillation counting of chromium-51

    SciTech Connect (OSTI)

    Charig, A.; Blake-Haskins, J.; Eigen, E.

    1985-12-01

    Unusual behavior of chromium-51 in liquid scintillation cocktail is described. Rapidly declining count rate is attributed to first-order binding of chromate to glass vials.

  14. Synthesis of Ionic Liquids - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionic liquids are compatible with extraction processes and reaction schemes common to organic chemistry. They are water stable and immiscible with water, and are useful...

  15. Binding Organic Liquids - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    More Like This Return to Search Binding Organic Liquids Pacific Northwest National Laboratory Contact PNNL About This Technology Technology Marketing Summary Researchers at...

  16. Liquid metal ion source and alloy

    DOE Patents [OSTI]

    Clark, Jr., William M. (Thousand Oaks, CA); Utlaut, Mark W. (Saugus, CA); Behrens, Robert G. (Los Alamos, NM); Szklarz, Eugene G. (Los Alamos, NM); Storms, Edmund K. (Los Alamos, NM); Santandrea, Robert P. (Santa Fe, NM); Swanson, Lynwood W. (McMinnville, OR)

    1988-10-04

    A liquid metal ion source and alloy, wherein the species to be emitted from the ion source is contained in a congruently vaporizing alloy. In one embodiment, the liquid metal ion source acts as a source of arsenic, and in a source alloy the arsenic is combined with palladium, preferably in a liquid alloy having a range of compositions from about 24 to about 33 atomic percent arsenic. Such an alloy may be readily prepared by a combustion synthesis technique. Liquid metal ion sources thus prepared produce arsenic ions for implantation, have long lifetimes, and are highly stable in operation.

  17. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the...

  18. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  19. Distributed Energy Technology Characterization (Desiccant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    applications, and to show how these technologies can be designed to utilize the available thermal energy from a combined heat and power (CHP) system. This technology...

  20. Carbon Films Produced from Ionic Liquid Precursors - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Carbon Films Produced from Ionic Liquid Precursors Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryResearchers at ORNL have invented a more effective method of preparing thin carbons films, a material that has become increasing important to the development of energy-saving storage batteries. Using this new method, it is possible to produce a very resilient, thermally stable porous carbon film characterized by a highly ordered arrangement of

  1. Liquid Effluent Retention Facility/Effluent Treatment Facility Hazards Assessment

    SciTech Connect (OSTI)

    Simiele, G.A.

    1994-09-29

    This document establishes the technical basis in support of Emergency Planning activities for the Liquid Effluent Retention Facility and Effluent Treatment Facility the Hanford Site. The document represents an acceptable interpretation of the implementing guidance document for DOE ORDER 5500.3A. Through this document, the technical basis for the development of facility specific Emergency Action Levels and the Emergency Planning Zone is demonstrated.

  2. Liquid Metal Heat Exchanger for Geologic Deposits - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Liquid Metal Heat Exchanger for Geologic Deposits Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryResearchers at ORNL developed a down-well heating apparatus that efficiently heats subterranean geological deposits, such as oil shale, to extract hydrocarbons for energy needs. The apparatus provides more efficient heat transfer than existing technologies for hydrocarbon extraction. It also holds promise for in situ remediation of contaminated

  3. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compensation Committee Report Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Santosh Gangwal Biomass 2014: Growing the Future Bioeconomy Agenda Washington, DC July 29-30, 2014 * Established in 1941 as an independent, not-for-profit (501-c-3) center for scientific research and development * Headquartered in Birmingham, Alabama; 8 locations in Southeastern US; 500 employees * Serves both Government and private industry clients * Revenue ~$80 million from contract

  4. Synthesis of Poly(ionic liquid)s by Atom Transfer Radical Polymerization

    Office of Scientific and Technical Information (OSTI)

    with ppm of Cu Catalyst (Journal Article) | SciTech Connect Journal Article: Synthesis of Poly(ionic liquid)s by Atom Transfer Radical Polymerization with ppm of Cu Catalyst Citation Details In-Document Search Title: Synthesis of Poly(ionic liquid)s by Atom Transfer Radical Polymerization with ppm of Cu Catalyst Authors: He, Hongkun ; Luebke, David ; Nulwala, Hunaid ; Matyjaszewski, Krzysztof Publication Date: 2014-10-14 OSTI Identifier: 1185116 DOE Contract Number: ER-45998; DMR-0969301;

  5. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  6. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  7. Viscosity of liquid {sup 4}He and quantum of circulation: Are they related?

    SciTech Connect (OSTI)

    L’vov, Victor S. E-mail: skrbek@fzu.cz; Skrbek, Ladislav E-mail: skrbek@fzu.cz; Sreenivasan, Katepalli R. E-mail: skrbek@fzu.cz

    2014-04-15

    In the vicinity of the superfluid transition in liquid {sup 4}He, we explore the relation between two apparently unrelated physical quantities—the kinematic viscosity, ?, in the normal state and the quantum of circulation, ?, in the superfluid state. The model developed here leads to the simple relationship ? ? ?/6, and links the classical and quantum flow properties of liquid {sup 4}He. We critically examine available data relevant to this relation and find that the prediction holds well at the saturated vapor pressure. Additionally, we predict the kinematic viscosity for liquid {sup 4}He along the ?-line at negative pressures.

  8. ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water and Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vapor ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file level. Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : MWR Retrievals of Cloud Liquid Water and Water Vapor A new algorithm is being developed for the ARM Program to derive liquid water path (LWP) and precipitable water vapor (PWV) from the

  9. Engineered microorganisms having resistance to ionic liquids

    DOE Patents [OSTI]

    Ruegg, Thomas Lawrence; Thelen, Michael P.

    2016-03-22

    The present invention provides for a method of genetically modifying microorganisms to enhance resistance to ionic liquids, host cells genetically modified in accordance with the methods, and methods of using the host cells in a reaction comprising biomass that has been pretreated with ionic liquids.

  10. Fiber-optic liquid level sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    1991-01-01

    A fiber-optic liquid level sensor measures the height of a column of liquid through the hydrostatic pressure it produces. The sensor employs a fiber-optic displacement sensor to detect the pressure-induced displacement of the center of a corrugated diaphragm.

  11. Liquid crystal-templated conducting organic polymers

    DOE Patents [OSTI]

    Stupp, Samuel I.; Hulvat, James F.

    2004-01-20

    A method of preparing a conductive polymeric film, includes providing a liquid crystal phase comprising a plurality of hydrophobic cores, the phase on a substrate, introducing a hydrophobic component to the phase, the component a conductive polymer precursor, and applying an electric potential across the liquid crystal phase, the potential sufficient to polymerize the said precursor.

  12. Ionic Liquid Pretreatment Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ionic Liquid Pretreatment Technologies Ionic Liquid Pretreatment Technologies These slides were used as a presentation by Dr. Blake Simmons on June 24, 2013, for the bimonthly BETO webinar. PDF icon june2013_snl_webinar.pdf More Documents & Publications 2015 Peer Review Presentations-Biochemical Conversion Innovative Topics for Advanced Biofuels Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals

  13. Nozzle development

    SciTech Connect (OSTI)

    Dodge, F.T.; Dodge, L.G.; Johnson, J.E.

    1989-06-01

    The objective of this program has been the development of experimental techniques and data processing procedures to allow for the characterization of multi-phase fuel nozzles using laboratory tests. Test results were to be used to produce a single value coefficient-of-performance that would predict the performance of the fuel nozzles independent of system application. Several different types of fuel nozzles capable of handling multi-phase fuels have been characterized for: (a) fuel flow rate versus delivery pressure, (b) fuel-air ratio throughout the fuel spray or plume and the effective cone angle of the injector, and (c) fuel drop- or particle-size distribution as a function of fluid properties. Fuel nozzles which have been characterized on both single-phase liquids and multi-phase liquid-solid slurries include a variable-film-thickness nozzle, a commercial coal-water slurry (CWS) nozzle, and four diesel injectors of different geometries (tested on single-phase fluids only). Multi-phase mixtures includes CWS with various coal loadings, surfactant concentrations, and stabilizer concentrations, as well as glass-bead water slurries with stabilizing additives. Single-phase fluids included glycerol-water mixtures to vary the viscosity over a range of 1 to 1500 cP, and alcohol-water mixtures to vary the surface tension from about 22 to 73 dyne/cm. In addition, tests were performed to characterize straight-tube gas-solid nozzles using two differences size distributions of glass beads in air. Standardized procedures have been developed for processing measurements of spray drop-size characteristics and the overall cross-section average drop or particle size. 43 refs., 60 figs., 7 tabs.

  14. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, D.D.

    A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  15. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, Don D.

    1985-01-01

    A chromatographic system that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a non-transparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extremely low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  16. Liquid crystal device and method thereof

    DOE Patents [OSTI]

    Shiyanovskii, Sergij V; Gu, Mingxia; Lavrentovich, Oleg D

    2012-10-23

    The invention provides a liquid crystal device and method thereof. Subsequent to applying a first electrical voltage on a liquid crystal to induce a reorientation of the liquid crystal, a second electrical voltage with proper polarity is applied on the liquid crystal to assist the relaxation of the reorientation that was induced by the first electrical voltage. The "switch-off" phase of the liquid crystal can therefore be accelerated or temporally shortened, and the device can exhibit better performance such as fast response to on/off signals. The invention can be widely used LCD, LC shutter, LC lens, spatial light modulator, telecommunication device, tunable filter, beam steering device, and electrically driven LC device, among others.

  17. Sewage sludge dewatering using flowing liquid metals

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1986-01-01

    A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

  18. EIS-0085-S: Liquid-Metal Fast Breeder Reactor Program, Supplemental

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this supplemental statement to examine the reduced scope of the Liquid Metal Fast Breeder Reactor (LMFBR) program and the environmental impacts associated therewith, including a re-examination of the purpose, need and timing of the program, the present program structure, including reasonable program alternatives, and alternative electricity production technologies anticipated to be available within the same timeframe as the LMFBR technology option. This statement supplements ERDA-1535, Liquid Metal Fast Breeder Reactor Program.

  19. NREL to Help Convert Methane to Liquid Diesel - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Help Convert Methane to Liquid Diesel Advanced research project could lead to lower greenhouse emissions, new life for spent gas and oil wells January 3, 2013 The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) will help develop microbes that convert methane found in natural gas into liquid diesel fuel, a novel approach that if successful could reduce greenhouse gas emissions and lower dependence on foreign oil. The amount of natural gas simply flared or vented

  20. Iraq liquid radioactive waste tanks maintenance and monitoring program plan.

    SciTech Connect (OSTI)

    Dennis, Matthew L.; Cochran, John Russell; Sol Shamsaldin, Emad

    2011-10-01

    The purpose of this report is to develop a project management plan for maintaining and monitoring liquid radioactive waste tanks at Iraq's Al-Tuwaitha Nuclear Research Center. Based on information from several sources, the Al-Tuwaitha site has approximately 30 waste tanks that contain varying amounts of liquid or sludge radioactive waste. All of the tanks have been non-operational for over 20 years and most have limited characterization. The program plan embodied in this document provides guidance on conducting radiological surveys, posting radiation control areas and controlling access, performing tank hazard assessments to remove debris and gain access, and conducting routine tank inspections. This program plan provides general advice on how to sample and characterize tank contents, and how to prioritize tanks for soil sampling and borehole monitoring.

  1. Large area liquid argon detectors for interrogation systems

    SciTech Connect (OSTI)

    Gary, Charles; Kane, Steve; Firestone, Murray I.; Smith, Gregory [Adelphi Technology LLC, Purdue Technology Center, 5225 Exploration Drive, Indianapolis, IN 46241 (United States); Gozani, Tsahi; Brown, Craig; Kwong, John; King, Michael J. [Rapiscan Laboratories, 520 Almanor Avenue, Sunnyvale, CA 94085 (United States); Nikkel, James A.; McKinsey, Dan [Physics Department, Yale University, New Haven, CT 06520 (United States)

    2013-04-19

    Measurements of the efficiency, pulse shape, and energy and time resolution of liquid argon (LAr) detectors are presented. Liquefied noble gas-based (LNbG) detectors have been developed for the detection of dark matter and neutrinoless double-beta decay. However, the same qualities that make LNbG detectors ideal for these applications, namely their size, cost, efficiency, pulse shape discrimination and resolution, make them promising for portal screening and the detection of Special Nuclear Materials (SNM). Two 18-liter prototype detectors were designed, fabricated, and tested, one with pure LAr and the other doped with liquid Xe (LArXe). The LArXe detector presented the better time and energy resolution of 3.3 ns and 20% at 662 KeV, respectively. The total efficiency of the detector was measured to be 35% with 4.5% of the total photons detected in the photopeak.

  2. Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns

    SciTech Connect (OSTI)

    Wishart,J.F.

    2008-09-29

    Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs are generally nonvolatile, noncombustible, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of chemical reactions and product distributions. Successful use of ionic liquids in radiation-filled environments, where their safety advantages could be significant, requires an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of IL radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material. An understanding of ionic liquid radiation chemistry will also facilitate pulse radiolysis studies of general chemical reactivity in ILs, which will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increases the importance of pre-solvated electron reactivity and consequently alters product distributions. Parallel studies of IL solvation phenomena using coumarin-153 dynamic Stokes shifts and polarization anisotropy decay rates are done to compare with electron solvation studies and to evaluate the influence of ILs on charge transport processes. Picosecond pulse radiolysis studies at BNL's Laser-Electron Accelerator Facility (LEAF) are used to identify reactive species in ionic liquids and measure their solvation and reaction rates. We and our collaborators (R. Engel (Queens College, CUNY) and S. Lall-Ramnarine, (Queensborough CC, CUNY)) develop and characterize new ionic liquids specifically designed for our radiolysis and solvation dynamics studies. IL solvation and rotational dynamics are measured by TCSPC and fluorescence upconversion measurements in the laboratory of E. W. Castner at Rutgers Univ. Investigations of radical species in irradiated ILs are carried out at ANL by I. Shkrob and S. Chemerisov using EPR spectroscopy. Diffusion rates are obtained by PGSE NMR in S. Greenbaum's lab at Hunter College, CUNY and S. Chung's lab at William Patterson U. Professor Mark Kobrak of CUNY Brooklyn College performs molecular dynamics simulations of solvation processes. A collaboration with M. Dietz at U. Wisc. Milwaukee is centered around the properties and radiolytic behavior of ionic liquids for nuclear separations. Collaborations with C. Reed (UC Riverside), D. Gabel (U. Bremen) and J. Davis (U. South Alabama) are aimed at characterizing the radiolytic and other properties of borated ionic liquids, which could be used to make fissile material separations processes inherently safe from criticality accidents.

  3. Cost Analysis of Bio-Derived Liquids Reforming (Presentation) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Bio-Derived Liquids Reforming (Presentation) Cost Analysis of Bio-Derived Liquids Reforming (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 03_dti_cost_analysis_bio-derived_liquids_reforming.pdf More Documents & Publications BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Bio-Derived Liquids to Hydrogen Distributed Reforming Working

  4. Mixing liquid holding tanks for uniform concentration

    SciTech Connect (OSTI)

    Sprouse, K.M.

    1988-01-01

    Achieving uniform concentration within liquid holding tanks can often times be a difficult task for the nuclear chemical process industry. This is due to the fact that nuclear criticality concerns require these tanks to be designed with high internal aspect ratios such that the free movement of fluid is greatly inhibited. To determine the mixing times required to achieve uniform concentrations within these tanks, an experimental program was conducted utilizing pencil tanks, double-pencil tanks, and annular tanks of varying geometries filled with salt-water solutions (simulant for nitric acid actinide solutions). Mixing was accomplished by air sparging and/or pump recirculation. Detailed fluid mechanic mixing models were developed --from first principles--to analyze and interpret the test results. These nondimensional models show the functionality of the concentration inhomogeneity (defined as the relative standard deviation of the true concentration within the tank) in relationship to the characteristic mixing time--among other variables. The results can be readily used to scale tank geometries to sizes other than those studied here.

  5. Infrared curing simulations of liquid composites molding

    SciTech Connect (OSTI)

    Nakouzi, S.; Pancrace, J.; Schmidt, F. M.; Le Maoult, Y.; Berthet, F. [Universite de Toulouse (France); INSA, UPS, Mines Albi, ISAE, ICA - Institut Clement Ader, Campus Jarlard, F-81013 Albi cedex 09 (France); Ecole des Mines Albi, Campus Jarlard, F-81013 Albi (France)

    2011-05-04

    Infrared radiation is an effective energy source to cure thermosetting polymers. Its usage is expected to reduce curing time in comparison with thermal heating and mold thermally regulated. In addition, because of the polymerization mechanism and instant on-off control of this power, an improvement in the final properties of the material is also expected. In this paper, we studied the infrared interaction with carbon (or glass) fibers reinforced epoxy matrix, where Liquid resin infusion (LRI) is used to manufacture the composite. Temperature of the composite is a key parameter that affects its mechanical properties and is controlled by the infrared emitters and the exothermic heat released from the polymerization. Radiative heat flux is computed using the in-lab developed software RAYHEAT. Then, the heat flux (or absorbed energy for glass fibers) is exported to the finite element based program COMSOLMULTIPHYSICS where heat balance equation is solved. This equation is coupled with the exothermic heat released during the curing process in order to predict the composite temperature versus time and degree of cure. Numerical simulations will be performed on planar parts (sheet shape) as well as curvilinear shapes. Experimental validations of the infrared curing carbon (glass)-epoxy composite system are presented in this paper Sheet surface temperature distribution are measured thanks to infrared camera. Kinetic parameters were estimated from differential scanning calorimeter (DSC) experimental data.

  6. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of liquid carbon at near-solid densities that can then be compared with results from molecular dynamics simulations. Extreme Carbon: Liquid Diamond or Molten Graphite?...

  7. Louisiana Offshore Natural Gas Plant Liquids Production Extracted...

    Gasoline and Diesel Fuel Update (EIA)

    Plant Liquids Production Extracted in Louisiana (Million Cubic Feet) Louisiana Offshore Natural Gas Plant Liquids Production Extracted in Louisiana (Million Cubic Feet) Decade...

  8. High intensity x-ray source using liquid gallium target

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL); Knapp, Gordon S. (Cupertino, CA); Westbrook, Edwin M. (Chicago, IL); Forster, George A. (Westmont, IL)

    1990-01-01

    A high intensity x-ray source that uses a flowing stream of liquid gallium as a target with the electron beam impinging directly on the liquid metal.

  9. Mobile interfaces: Liquids as a perfect structural material for...

    Office of Scientific and Technical Information (OSTI)

    Mobile interfaces: Liquids as a perfect structural material for multifunctional, antifouling surfaces Prev Next Title: Mobile interfaces: Liquids as a perfect structural ...

  10. Ionic Liquids as Multifunctional Ashless Additives for Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multifunctional Ashless Additives for Engine Lubrication Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication A group of oil-miscible ionic liquids has been ...

  11. High Operating Temperature Liquid Metal Heat Transfer Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Operating Temperature Liquid Metal Heat Transfer Fluids High Operating Temperature Liquid Metal Heat Transfer Fluids This fact sheet describes a UCLA-led solar project to ...

  12. Project Profile: High Operating Temperature Liquid Metal Heat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Operating Temperature Liquid Metal Heat Transfer Fluids Project Profile: High Operating Temperature Liquid Metal Heat Transfer Fluids Logos for The University of California, ...

  13. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Technical Team Research Review Cost Analysis of Bio-Derived Liquids Reforming (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids

  14. Technical Assessment of Organic Liquid Carrier Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive...

  15. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  16. Molecular catalytic coal liquid conversion (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Conference: Molecular catalytic coal liquid conversion Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion This research, which is relevant to the...

  17. Molecular catalytic coal liquid conversion (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Conference: Molecular catalytic coal liquid conversion Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion You are accessing a document from...

  18. Energetic Materials for EGS Well Stimulation (solids, liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well ...

  19. Copper ionic liquids: Tunable ligand and anion chemistries to...

    Office of Scientific and Technical Information (OSTI)

    Copper ionic liquids: Tunable ligand and anion chemistries to control electrochemistry and deposition morphology. Citation Details In-Document Search Title: Copper ionic liquids: ...

  20. Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help...

  1. Method and apparatus for transporting liquid slurries

    DOE Patents [OSTI]

    Berry, Gregory F. (Naperville, IL); Lyczkowski, Robert W. (Darien, IL); Wang, Chi-Sheng (Woodridge, IL)

    1993-01-01

    An improved method and device to prevent erosion of slurry transport devices is disclosed which uses liquid injection to prevent contact by the slurry composition with the inner surface of the walls of the transport system. A non-abrasive liquid is injected into the slurry transport system and maintains intimate contact with the entire inner surface of the transport system, thereby creating a fluid barrier between the non-abrasive liquid and the inner surface of the transport system which thereby prevents erosion.

  2. Liquid-hydrogen-fueled passenger aircraft

    SciTech Connect (OSTI)

    Not Available

    1986-03-11

    This Chinese translation discusses the idea that passenger aircraft will eventually use liquid-hydrogen fuel. There is a large reserve of hydrogen and hydrogen poses no danger to the environment. Hydrogen has high calorific value, high specific heat, low density, and low temperature. Aircraft will have to have liquid fuel tanks to carry the hydrogen and will have to be partially redesigned. Lockheed and NASA have considered such designs. A problem remains in the planning--the high cost of large extraction of liquid hydrogen.

  3. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  4. Method and apparatus for transporting liquid slurries

    DOE Patents [OSTI]

    Berry, G.F.; Lyczkowski, R.W.; Chisheng Wang.

    1993-03-16

    An improved method and device to prevent erosion of slurry transport devices is disclosed which uses liquid injection to prevent contact by the slurry composition with the inner surface of the walls of the transport system. A non-abrasive liquid is injected into the slurry transport system and maintains intimate contact with the entire inner surface of the transport system, thereby creating a fluid barrier between the non-abrasive liquid and the inner surface of the transport system which thereby prevents erosion.

  5. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    SciTech Connect (OSTI)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

  6. Modeling, system identification, and control for slosh-free motion of an open container of liquid

    SciTech Connect (OSTI)

    Feddema, J.; Baty, R.; Dykhuizen, R.; Dohrmann, C.; Parker, G.; Robinett, R.; Romero, V.; Schmitt, D.

    1996-04-01

    This report discusses work performed under a Cooperative Research And Development Agreement (CRADA) with Corning, Inc., to analyze and test various techniques for controlling the motion of a high speed robotic arm carrying an open container of viscous liquid, in this case, molten glass. A computer model was generated to estimate the modes of oscillation of the liquid based on the shape of the container and the viscosity of the liquid. This fluid model was experimentally verified and tuned based on experimental data from a capacitive sensor on the side of the container. A model of the robot dynamics was also developed and verified through experimental tests on a Fanuc S-800 robot arm. These two models were used to estimate the overall modes of oscillation of an open container of liquid being carried by a robot arm. Using the estimated modes, inverse dynamic control techniques were used to determine a motion profile which would eliminate waves on the liquid`s surface. Experimental tests showed that residual surface waves in an open container of water at the end of motion were reduced by over 95% and that in-motion surface waves were reduced by over 75%.

  7. US crude oil, natural gas, and natural gas liquids reserves, 1992 annual report

    SciTech Connect (OSTI)

    Not Available

    1993-10-18

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1992, as well as production volumes for the United States, and selected States and State subdivisions for the year 1992. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), its two major components (nonassociated and associated-dissolved gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, two components of natural gas liquids, lease condensate and natural gas plant liquids, have their reserves and production data presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1992 is provided.

  8. U.S. crude oil, natural gas, and natural gas liquids reserves 1997 annual report

    SciTech Connect (OSTI)

    Wood, John H.; Grape, Steven G.; Green, Rhonda S.

    1998-12-01

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1997, as well as production volumes for the US and selected States and State subdivisions for the year 1997. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), nonassociated gas and associated-dissolved gas (which are the two major types of wet natural gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, reserve estimates for two types of natural gas liquids, lease condensate and natural gas plant liquids, are presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1997 is provided. 21 figs., 16 tabs.

  9. THERMAL OSCILLATIONS IN LIQUID HELIUM TARGETS.

    SciTech Connect (OSTI)

    WANG,L.; JIA,L.X.

    2001-07-16

    A liquid helium target for the high-energy physics was built and installed in the proton beam line at the Alternate Gradient Synchrotron of Brookhaven National Laboratory in 2001. The target flask has a liquid volume of 8.25 liters and is made of thin Mylar film. A G-M/J-T cryocooler of five-watts at 4.2K was used to produce liquid helium and refrigerate the target. A thermosyphon circuit for the target was connected to the J-T circuit by a liquid/gas separator. Because of the large heat load to the target and its long transfer lines, thermal oscillations were observed during the system tests. To eliminate the oscillation, a series of tests and analyses were carried out. This paper describes the phenomena and provides the understanding of the thermal oscillations in the target system.

  10. Removal of arsenic compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, Richard H.

    1985-01-01

    Described is a process for removing arsenic from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic bound to it from contacting petroliferous liquid as described above and involves: a. treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10 and, b. separating the solids and liquids from each other. Preferably the regeneration treatment is in two steps wherein step (a) is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, steps (a) and (b) are repeated using a bicarbonate.

  11. Phosphonium-based ionic liquids and uses

    DOE Patents [OSTI]

    Del Sesto, Rico E; Koppisch, Andrew T; Lovejoy, Katherine S; Purdy, Geraldine M

    2014-12-30

    Phosphonium-based room temperature ionic liquids ("RTILs") were prepared. They were used as matrices for Matrix-Assisted Laser Desorption Ionization (MALDI) mass spectrometry and also for preparing samples of dyes for analysis.

  12. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In a chiral liquid crystal, stacked molecular layers form a twist-a useful property in LCD technology. NOBOW transforms from the B4 (helical) phase to the B2 (flat) phase at 142...

  13. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an...

  14. Liquid metal cooled divertor for ARIES

    SciTech Connect (OSTI)

    Muraviev, E. [Gosudarstvennyj Komitet po Ispol`zovaniyu Atomnoj Ehnergii SSSR, Moscow (Russian Federation). Inst. Atomnoj Ehnergii

    1995-01-01

    A liquid metal, Ga-cooled divertor design was completed for the double null ARIES-II divertor design. The design analysis indicated a surface heat flux removal capability of up to 15 MW/m{sup 2}, and its relative easy maintenance. Design issues of configuration, thermal hydraulics, thermal stresses, liquid metal loop and safety effects were evaluated. For coolant flow control, it was found that it is necessary to use some part of the blanket cooling ducts for the draining of liquid metal from the top divertor. In order to minimize the inventory of Ga, it was recommended that the liquid metal loop equipment should be located as close to the torus as possible. More detailed analysis of transient conditions especially under accident conditions was identified as an issue that will need to be addressed.

  15. Liquid Fuels Market Module - NEMS Documentation

    Reports and Publications (EIA)

    2014-01-01

    Defines the objectives of the Liquid Fuels Market Model (LFMM), describes its basic approach, and provides detail on how it works. This report is intended as a reference document for model analysts, users, and the public.

  16. SRS Liquid Waste Program Partnering Agreement

    Broader source: Energy.gov [DOE]

    We the members of the  SRS Liquid Waste Partnering Team do hereby mutually agree to work in a collaborative and cooperative manner through open communication and coordination with team members, and...

  17. LFCM (liquid-fed ceramic melter) vitrification technology: Quarterly progress report, October-December 1986

    SciTech Connect (OSTI)

    Brouns, R.A.; Allen, C.R.; Powell, J.A.

    1987-09-01

    This report describes the progress in developing, testing, applying, and documenting liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1987 is discussed. Topics include melting process chemistry and glass development, feed preparation and transfer systems, melter systems, off-gas systems, canister filling and handling systems, and process/product modeling.

  18. Photosensitive dopants for liquid noble gases

    DOE Patents [OSTI]

    Anderson, David F. (Wheaton, IL)

    1988-01-01

    In an ionization type detector for high energy radiation wherein the energy of incident radiation is absorbed through the ionization of a liquid noble gas and resulting free charge is collected to form a signal indicative of the energy of the incident radiation, an improvement comprising doping the liquid noble gas with photosensitive molecules to convert scintillation light due to recombination of ions, to additional free charge.

  19. Superbase-derived protic ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Baker, Gary A.

    2013-09-03

    Protic ionic liquids having a composition of formula (A.sup.-)(BH.sup.+) wherein A.sup.- is a conjugate base of an acid HA, and BH.sup.+ is a conjugate acid of a superbase B. In particular embodiments, BH.sup.+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: ##STR00001## The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.

  20. Flash evaporation of liquid monomer particle mixture

    DOE Patents [OSTI]

    Affinito, J.D.; Darab, J.G.; Gross, M.E.

    1999-05-11

    The present invention is a method of making a first solid composite polymer layer. The method has the steps of (a) mixing a liquid monomer with particles substantially insoluble in the liquid monomer forming a monomer particle mixture; (b) flash evaporating the particle mixture and forming a composite vapor; and (c) continuously cryocondensing said composite vapor on a cool substrate and cross-linking the cryocondensed film thereby forming the polymer layer. 3 figs.

  1. Process for preparing a liquid fuel composition

    DOE Patents [OSTI]

    Singerman, Gary M. (Monroeville, PA)

    1982-03-16

    A process for preparing a liquid fuel composition which comprises liquefying coal, separating a mixture of phenols from said liquefied coal, converting said phenols to the corresponding mixture of anisoles, subjecting at least a portion of the remainder of said liquefied coal to hydrotreatment, subjecting at least a portion of said hydrotreated liquefied coal to reforming to obtain reformate and then combining at least a portion of said anisoles and at least a portion of said reformate to obtain said liquid fuel composition.

  2. Liquid Fuels Market Model (LFMM) Unveiling LFMM

    Gasoline and Diesel Fuel Update (EIA)

    Implementation of the Renewable Fuel Standard (RFS) in the Liquid Fuels Market Module (LFMM) of NEMS Michael H. Cole, PhD, PE michael.cole@eia.gov August 1, 2012 | Washington, DC LFMM / NEMS overview 2 M. Cole, EIA Advanced Biofuels Workshop August 1, 2012 | Washington, DC * LFMM is a mathematical representation of the U.S. liquid fuels market (motor gasoline, diesel, biofuels, etc.). EIA analysts use LFMM to project motor fuel prices and production approaches through 2040. * LFMM is a

  3. Flash evaporation of liquid monomer particle mixture

    DOE Patents [OSTI]

    Affinito, John D. (Kennewick, WA); Darab, John G. (Richland, WA); Gross, Mark E. (Pasco, WA)

    1999-01-01

    The present invention is a method of making a first solid composite polymer layer. The method has the steps of (a) mixing a liquid monomer with particles substantially insoluble in the liquid monomer forming a monomer particle mixture; (b) flash evaporating the particle mixture and forming a composite vapor; and (c) continuously cryocondensing said composite vapor on a cool substrate and cross-linking the cryocondensed film thereby forming the polymer layer.

  4. Nonconventional Liquid Fuels (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    Higher prices for crude oil and refined petroleum products are opening the door for nonconventional liquids to displace petroleum in the traditional fuel supply mix. Growing world demand for diesel fuel is helping to jump-start the trend toward increasing production of nonconventional liquids, and technological advances are making the nonconventional alternatives more viable commercially. Those trends are reflected in the Annual Energy Outlook 2006 projections.

  5. Process for stabilization of coal liquid fractions

    DOE Patents [OSTI]

    Davies, Geoffrey (Boston, MA); El-Toukhy, Ahmed (Alexandria, EG)

    1987-01-01

    Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

  6. IONIC LIQUIDS: RADIATION CHEMISTRY, SOLVATION DYNAMICS AND REACTIVITY PATTERNS.

    SciTech Connect (OSTI)

    WISHART,J.F.

    2007-10-01

    energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs are generally nonvolatile, noncombustible, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of chemical reactions and product distributions. Successful use of ionic liquids in radiation-filled environments, where their safety advantages could be significant, requires an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of IL radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material. An understanding of ionic liquid radiation chemistry will also facilitate pulse radiolysis studies of general chemical reactivity in ILs, which will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increases the importance of pre-solvated electron reactivity and consequently alters product distributions. Parallel studies of IL solvation phenomena using coumarin-153 dynamic Stokes shifts and polarization anisotropy decay rates are done to compare with electron solvation studies and to evaluate the influence of ILs on charge transport processes. Methods. Picosecond pulse radiolysis studies at BNL's Laser-Electron Accelerator Facility (LEAF) are used to identify reactive species in ionic liquids and measure their solvation and reaction rates. We and our collaborators (R. Engel (Queens College, CUNY) and S. Lall-Ramnarine, (Queensborough CC, CUNY)) develop and characterize new ionic liquids specifically designed for our radiolysis and solvation dynamics studies. IL solvation and rotational dynamics are measured by TCSPC and fluorescence upconversion measurements in the laboratory of E. W. Castner at Rutgers Univ. Investigations of radical species in irradiated ILs are carried out at ANL by I. Shkrob and S. Chemerisov using EPR spectroscopy. Diffusion rates are obtained by PGSE NMR in S. Greenbaum's lab at Hunter College, CUNY and S. Chung's lab at William Patterson U. Professor Mark Kobrak of CUNY Brooklyn College performs molecular dynamics simulations of solvation processes. A collaboration with M. Dietz and coworkers at ANL is centered around the properties and radiolytic behavior of ionic liquids for nuclear separations. Collaborations with C. Reed (UC Riverside), D. Gabel (U. Bremen) and J. Davis (U. South Alabama) are aimed at characterizing the radiolytic and other properties of borated ionic liquids, which could be used to make fissile material separations processes inherently safe from criticality accidents.

  7. Elimination of liquid discharge to the environment from the TA-50 Radioactive Liquid Waste Treatment Facility

    SciTech Connect (OSTI)

    Moss, D.; Williams, N.; Hall, D.; Hargis, K.; Saladen, M.; Sanders, M.; Voit, S.; Worland, P.; Yarbro, S.

    1998-06-01

    Alternatives were evaluated for management of treated radioactive liquid waste from the radioactive liquid waste treatment facility (RLWTF) at Los Alamos National Laboratory. The alternatives included continued discharge into Mortandad Canyon, diversion to the sanitary wastewater treatment facility and discharge of its effluent to Sandia Canyon or Canada del Buey, and zero liquid discharge. Implementation of a zero liquid discharge system is recommended in addition to two phases of upgrades currently under way. Three additional phases of upgrades to the present radioactive liquid waste system are proposed to accomplish zero liquid discharge. The first phase involves minimization of liquid waste generation, along with improved characterization and monitoring of the remaining liquid waste. The second phase removes dissolved salts from the reverse osmosis concentrate stream to yield a higher effluent quality. In the final phase, the high-quality effluent is reused for industrial purposes within the Laboratory or evaporated. Completion of these three phases will result in zero discharge of treated radioactive liquid wastewater from the RLWTF.

  8. Compressed/Liquid Hydrogen Tanks

    Broader source: Energy.gov [DOE]

    Currently, DOE's physical hydrogen storage R&D focuses on the development of high-pressure (10,000 psi) composite tanks, cryo-compressed tanks, conformable tanks, and other advanced concepts...

  9. Method for the removal of carbonyl sulfide from liquid propane

    SciTech Connect (OSTI)

    McClure, G.

    1980-06-17

    A method for the removal of carbonyl sulfide from liquid propane under liquid-liquid contact conditions by mixing liquid propane containing carbonyl sulfide as an impurity with 2-(2-aminoethoxy) ethanol as the principal agent for the carbonyl sulfide removal. The 2(2-aminoethoxy) ethanol is reclaimed and reused for further carbonyl sulfide removal. 5 claims.

  10. Collection of liquid from below-ground location

    DOE Patents [OSTI]

    Phillips, Steven J. (Kennewick, WA); Alexander, Robert G. (Kennewick, WA)

    1995-01-01

    A method of retrieving liquid from a below-ground collection area by permitting gravity flow of the liquid from the collection area to a first closed container; monitoring the level of the liquid in the closed container; and after the liquid reaches a given level in the first closed container, transferring the liquid to a second closed container disposed at a location above the first closed container, via a conduit, by introducing into the first closed container a gas which is substantially chemically inert with respect to the liquid, the gas being at a pressure sufficient to propel the liquid from the first closed container to the second closed container.

  11. Liquid over-feeding air conditioning system and method

    DOE Patents [OSTI]

    Mei, V.C.; Chen, F.C.

    1993-09-21

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

  12. Liquid over-feeding air conditioning system and method

    DOE Patents [OSTI]

    Mei, Viung C. (Oak Ridge, TN); Chen, Fang C. (Knoxville, TN)

    1993-01-01

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

  13. Liquid Scintillator Production for the NOvA Experiment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mufson, S.; Baugh, B.; Bower, C.; Coan, T.; Cooper, J.; Corwin, L.; Karty, J.; Mason, P.; Messier, M. D.; Pla-Dalmau, A.; et al

    2015-04-15

    The NOvA collaboration blended and delivered 8.8 kt (2.72M gal) of liquid scintillator as the active detector medium to its near and far detectors. The composition of this scintillator was specifically developed to satisfy NOvA's performance requirements. A rigorous set of quality control procedures was put in place to verify that the incoming components and the blended scintillator met these requirements. The scintillator was blended commercially in Hammond, IN. The scintillator was shipped to the NOvA detectors using dedicated stainless steel tanker trailers cleaned to food grade.

  14. Impedance e-tongue instrument for rapid liquid assessment

    SciTech Connect (OSTI)

    Cabral, Flavio P. A.; Bergamo, Bruno B.; Dantas, Cleber A. R.; Giacometti, Jose A.; Riul, A. Jr

    2009-02-15

    We present a compact and easy to handle instrument developed to perform rapid analysis of liquids utilizing an 'electronic tongue' system. Briefly, the e-tongue used here is based on impedance measurements of an array of sensing units fabricated with ultrathin films of different materials deposited onto gold interdigitated electrodes. The instrument has the capability of measuring up to eight different sensor sets, each comprising an array of eight sensing units, and can perform a series of measurements in less than half of an hour. Additionally, there is a user-friendly software interface for instrument control, allowing the statistical correlation of samples using principal component analysis.

  15. HTL Model Development

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1.3.4.100 HTL Model Development MARCH 24, 2015 ALGAE Sue Jones Yunhua Zhu, Lesley Snowden-Swan, Dan Anderson, Rich Hallen, Karl Albrecht, Doug Elliott, Andy Schmidt Pacific Northwest National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement for HTL Model 2 GOAL: Enable R&D to produce sustainable, economic liquid fuels through targeted research coupled with techno-economic analysis (TEA) leading to optimized algal

  16. Gas-liquid separator and method of operation

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev (Latham, NY); Whitt, David Brandon (Albany, NY)

    2009-07-14

    A system for gas-liquid separation in electrolysis processes is provided. The system includes a first compartment having a liquid carrier including a first gas therein and a second compartment having the liquid carrier including a second gas therein. The system also includes a gas-liquid separator fluidically coupled to the first and second compartments for separating the liquid carrier from the first and second gases.

  17. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, W.F.; Burtis, C.A.; Walker, W.A.

    1987-07-17

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described. 5 figs.

  18. Hydrogen from Bio-Derived Liquids (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Bio-Derived Liquids (Presentation) Hydrogen from Bio-Derived Liquids (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 09_pnnl_h2_from_bio-derived_liquids.pdf More Documents & Publications Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Renewable

  19. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, Wayne F. (Loudon, TN); Burtis, Carl A. (Oak Ridge, TN); Walker, William A. (Knoxville, TN)

    1989-01-01

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described.

  20. Rotor for processing liquids using movable capillary tubes

    DOE Patents [OSTI]

    Johnson, Wayne F. (Loudon, TN); Burtis, Carl A. (Oak Ridge, TN); Walker, William A. (Knoxville, TN)

    1989-05-30

    A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described.

  1. Ionic Liquid Sorbents for Carbon Capture - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Ionic Liquid Sorbents for Carbon Capture Ionic liquids for carbon capture and gas separation National Energy Technology Laboratory Contact NETL About This Technology Ionic liquids Ionic liquids Technology Marketing Summary Research is active on technologies for application of ionic liquids to carbon capture or other separation processes in energy systems. The technologies consist of materials and methods that promise to

  2. Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help scientists predict how carbon is stored underground August 22, 2013 Dan Krotz 510-486-4019 dakrotz@lbl.gov red2.jpg Artistic rendition of liquid-liquid separation in a supersaturated calcium carbonate solution. New research suggests that a dense liquid phase (shown in red in the background and in full atomistic detail

  3. Removal of arsenic compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1984-04-06

    The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

  4. Process for the production of liquid hydrocarbons

    DOE Patents [OSTI]

    Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria Gerardus

    2006-06-27

    The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

  5. Double-duct liquid metal magnetohydrodynamic engine

    DOE Patents [OSTI]

    Haaland, Carsten M. (Oak Ridge, TN)

    1997-01-01

    An internal combustion, liquid metal (LM) magnetohydrodynamic (MHD) engine and an alternating current (AC) magnetohydrodynamic generator, are used in combination to provide useful AC electric energy output. The engine design has four pistons and a double duct configuration, with each duct containing sodium potassium liquid metal confined between free pistons located at either end of the duct. The liquid metal is forced to flow back and forth in the duct by the movement of the pistons, which are alternatively driven by an internal combustion process. In the MHD generator, the two LM-MHD ducts pass in close proximity through a Hartmann duct with output transformer. AC power is produced by operating the engine with the liquid metal in the two generator ducts always flowing in counter directions. The amount of liquid metal maintained in the ducts may be varied. This provides a variable stroke length for the pistons. The engine/generator provides variable AC power at variable frequencies that correspond to the power demands of the vehicular propulsion. Also the engine should maintain nearly constant efficiency throughout the range of power usage. Automobiles and trucks could be powered by the invention, with no transmission or power converter devices being required.

  6. Double-duct liquid metal magnetohydrodynamic engine

    DOE Patents [OSTI]

    Haaland, Carsten M. (Oak Ridge, TN)

    1995-01-01

    An internal combustion, liquid metal (LM) magnetohydrodynamic (MHD) engine and an alternating current (AC) magnetohydrodynamic generator, are used in combination to provide useful AC electric energy output. The engine design has-four pistons and a double duct configuration, with each duct containing sodium potassium liquid metal confined between free pistons located at either end of the duct. The liquid metal is forced to flow back and forth in the duct by the movement of the pistons, which are alternatively driven by an internal combustion process. In the MHD generator, the two LM-MHD ducts pass in close proximity through a Hartmann duct with output transformer. AC power is produced by operating the engine with the liquid metal in the two generator ducts always flowing in counter directions. The amount of liquid metal maintained in the ducts may be varied. This provides a variable stroke length for the pistons. The engine/generator provides variable AC power at variable frequencies that correspond to the power demands of the vehicular propulsion. Also the engine should maintain nearly constant efficiency throughout the range of power usage. Automobiles and trucks could be powered by the invention, with no transmission or power converter devices being required.

  7. Liquid-absorption preconcentrator sampling instrument

    DOE Patents [OSTI]

    Zaromb, S.

    1990-12-11

    A system is described for detecting trace concentrations of an analyte in air and includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container in which is disposed a wettable material extending substantially the entire length of the container. One end of the wettable material is continuously wetted with an analyte-sorbing liquid, which flows to the other end of the container. Sample air is flowed through the container in contact with the wetted material for trapping and preconcentrating the traces of analyte in the sorbing liquid, which is then collected at the other end of the container and discharged to the detector. The wetted material may be a wick comprising a bundle of fibers, one end of which is immersed in a reservoir of the analyte-sorbing liquid, or may be a liner disposed on the inner surface of the container, with the sorbing liquid being centrifugally dispersed onto the liner at one end thereof. The container is preferably vertically oriented so that gravity effects the liquid flow. 4 figs.

  8. Liquid-absorption preconcentrator sampling instrument

    DOE Patents [OSTI]

    Zaromb, Solomon (Hinsdale, IL)

    1990-01-01

    A system for detecting trace concentrations of an analyte in air and includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container in which is disposed a wettable material extending substantially the entire length of the container. One end of the wettable material is continuously wetted with an analyte-sorbing liquid, which flows to the other end of the container. Sample air is flowed through the container in contact with the wetted material for trapping and preconcentrating the traces of analyte in the sorbing liquid, which is then collected at the other end of the container and discharged to the detector. The wetted material may be a wick comprising a bundle of fibers, one end of which is immersed in a reservoir of the analyte-sorbing liquid, or may be a liner disposed on the inner surface of the container, with the sorbing liquid being centrifugally dispersed onto the liner at one end thereof. The container is preferably vertically oriented so that gravity effects the liquid flow.

  9. NGNP Process Heat Utilization: Liquid Metal Phase Change Heat Exchanger

    SciTech Connect (OSTI)

    Piyush Sabharwall; Mike Patterson; Vivek Utgikar; Fred Gunnerson

    2008-09-01

    One key long-standing issue that must be overcome to fully realize the successful growth of nuclear power is to determine other benefits of nuclear energy apart from meeting the electricity demands. The Next Generation Nuclear Plant (NGNP) will most likely be producing electricity and heat for the production of hydrogen and/or oil retrieval from oil sands and oil shale to help in our national pursuit of energy independence. For nuclear process heat to be utilized, intermediate heat exchange is required to transfer heat from the NGNP to the hydrogen plant or oil recovery field in the most efficient way possible. Development of nuclear reactor - process heat technology has intensified the interest in liquid metals as heat transfer media because of their ideal transport properties. Liquid metal heat exchangers are not new in practical applications. An important rational for considering liquid metals is the potential convective heat transfer is among the highest known. Thus explains the interest in liquid metals as coolant for intermediate heat exchange from NGNP. For process heat it is desired that, intermediate heat exchangers (IHX) transfer heat from the NGNP in the most efficient way possible. The production of electric power at higher efficiency via the Brayton Cycle, and hydrogen production, requires both heat at higher temperatures and high effectiveness compact heat exchangers to transfer heat to either the power or process cycle. Compact heat exchangers maximize the heat transfer surface area per volume of heat exchanger; this has the benefit of reducing heat exchanger size and heat losses. High temperature IHX design requirements are governed in part by the allowable temperature drop between the outlet and inlet of the NGNP. In order to improve the characteristics of heat transfer, liquid metal phase change heat exchangers may be more effective and efficient. This paper explores the overall heat transfer characteristics and pressure drop of the phase change heat exchanger with Na as the heat exchanger coolant. In order to design a very efficient and effective heat exchanger one must optimize the design such that we have a high heat transfer and a lower pressure drop, but there is always a trade-off between them. Based on NGNP operational parameters, a heat exchanger analysis with the sodium phase change will be presented to show that the heat exchanger has the potential for highly effective heat transfer, within a small volume at reasonable cost.

  10. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Watkins, Arthur D. (Idaho Falls, ID)

    1999-01-01

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube.

  11. High throughput liquid absorption preconcentrator sampling instrument

    DOE Patents [OSTI]

    Zaromb, S.; Bozen, R.M.

    1992-12-22

    A system for detecting trace concentrations of an analyte in air includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container comprising a wettable material. The wettable material is continuously wetted with an analyte-sorbing liquid which flows from one part of the container to a lower end. Sampled air flows through the container in contact with the wetted material with a swirling motion which results in efficient transfer of analyte vapors or aerosol particles to the sorbing liquid and preconcentration of traces of analyte in the liquid. The preconcentrated traces of analyte may be either detected within the container or removed therefrom for injection into a separate detection means or for subsequent analysis. 12 figs.

  12. The CAPTAIN liquid argon neutrino experiment

    SciTech Connect (OSTI)

    Liu, Qiuguang [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-01-01

    The CAPTAIN liquid argon experiment is designed to make measurements of scientific importance to long-baseline neutrino physics and physics topics that will be explored by large underground detectors. The experiment employs two detectors – a primary detector with approximately 10-ton of liquid argon that will be deployed at different facilities for physics measurements and a prototype detector with 2-ton of liquid argon for configuration testing. The physics programs for CAPTAIN include measuring neutron interactions at Los Alamos Neutron Science Center, measuring neutrino interactions in medium energy regime (1.5–5 GeV) at Fermilab's NuMI beam, and measuring neutrino interactions in low energy regime (< 50 MeV) at stopped pion sources for supernova neutrino studies.

  13. High throughput liquid absorption preconcentrator sampling instrument

    DOE Patents [OSTI]

    Zaromb, Solomon (Hinsdale, IL); Bozen, Ralph M. (Hattiesburg, MS)

    1992-01-01

    A system for detecting trace concentrations of an analyte in air includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container comprising a wettable material. The wettable material is continuously wetted with an analyte-sorbing liquid which flows from one part of the container to a lower end. Sampled air flows through the container in contact with the wetted material with a swirling motion which results in efficient transfer of analyte vapors or aerosol particles to the sorbing liquid and preconcentration of traces of analyte in the liquid. The preconcentrated traces of analyte may be either detected within the container or removed therefrom for injection into a separate detection means or for subsequent analysis.

  14. The CAPTAIN liquid argon neutrino experiment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Qiuguang

    2015-01-01

    The CAPTAIN liquid argon experiment is designed to make measurements of scientific importance to long-baseline neutrino physics and physics topics that will be explored by large underground detectors. The experiment employs two detectors – a primary detector with approximately 10-ton of liquid argon that will be deployed at different facilities for physics measurements and a prototype detector with 2-ton of liquid argon for configuration testing. The physics programs for CAPTAIN include measuring neutron interactions at Los Alamos Neutron Science Center, measuring neutrino interactions in medium energy regime (1.5–5 GeV) at Fermilab's NuMI beam, and measuring neutrino interactions in low energymore » regime (< 50 MeV) at stopped pion sources for supernova neutrino studies.« less

  15. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, P.C.; Watkins, A.D.

    1999-05-25

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube. 8 figs.

  16. DOE studies on coal-to-liquids

    SciTech Connect (OSTI)

    2007-07-01

    The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

  17. Liquid chromatography detection unit, system, and method

    DOE Patents [OSTI]

    Derenzo, Stephen E; Moses, William W

    2015-11-06

    An embodiment of a liquid chromatography detection unit includes a fluid channel and a radiation detector. The radiation detector is operable to image a distribution of a radiolabeled compound as the distribution travels along the fluid channel. An embodiment of a liquid chromatography system includes an injector, a separation column, and a radiation detector. The injector is operable to inject a sample that includes a radiolabeled compound into a solvent stream. The position sensitive radiation detector is operable to image a distribution of the radiolabeled compound as the distribution travels along a fluid channel. An embodiment of a method of liquid chromatography includes injecting a sample that comprises radiolabeled compounds into a solvent. The radiolabeled compounds are then separated. A position sensitive radiation detector is employed to image distributions of the radiolabeled compounds as the radiolabeled compounds travel along a fluid channel.

  18. Liquid chromatography detection unit, system, and method

    DOE Patents [OSTI]

    Derenzo, Stephen E.; Moses, William W.

    2015-10-27

    An embodiment of a liquid chromatography detection unit includes a fluid channel and a radiation detector. The radiation detector is operable to image a distribution of a radiolabeled compound as the distribution travels along the fluid channel. An embodiment of a liquid chromatography system includes an injector, a separation column, and a radiation detector. The injector is operable to inject a sample that includes a radiolabeled compound into a solvent stream. The position sensitive radiation detector is operable to image a distribution of the radiolabeled compound as the distribution travels along a fluid channel. An embodiment of a method of liquid chromatography includes injecting a sample that comprises radiolabeled compounds into a solvent. The radiolabeled compounds are then separated. A position sensitive radiation detector is employed to image distributions of the radiolabeled compounds as the radiolabeled compounds travel along a fluid channel.

  19. Direct Liquid Cooling for Electronic Equipment

    SciTech Connect (OSTI)

    Coles, Henry; Greenberg, Steve

    2014-03-01

    This report documents a demonstration of an electronic--equipment cooling system in the engineering prototype development stage that can be applied in data centers. The technology provides cooling by bringing a water--based cooling fluid into direct contact with high--heat--generating electronic components. This direct cooling system improves overall data center energy efficiency in three ways: High--heat--generating electronic components are more efficiently cooled directly using water, capturing a large portion of the total electronic equipment heat generated. This captured heat reduces the load on the less--efficient air--based data center room cooling systems. The combination contributes to the overall savings. The power consumption of the electronic equipment internal fans is significantly reduced when equipped with this cooling system. The temperature of the cooling water supplied to the direct cooling system can be much higher than that commonly provided by facility chilled water loops, and therefore can be produced with lower cooling infrastructure energy consumption and possibly compressor-free cooling. Providing opportunities for heat reuse is an additional benefit of this technology. The cooling system can be controlled to produce high return water temperatures while providing adequate component cooling. The demonstration was conducted in a data center located at Lawrence Berkeley National Laboratory in Berkeley, California. Thirty--eight servers equipped with the liquid cooling system and instrumented for energy measurements were placed in a single rack. Two unmodified servers of the same configuration, located in an adjacent rack, were used to provide a baseline. The demonstration characterized the fraction of heat removed by the direct cooling technology, quantified the energy savings for a number of cooling infrastructure scenarios, and provided information that could be used to investigate heat reuse opportunities. Thermal measurement data were used with data center energy use modeling software to estimate overall site energy use. These estimates show that an overall data center energy savings of approximately 20 percent can be expected if a center is retrofitted as specified in the models used. Increasing the portion of heat captured by this technology is an area suggested for further development.

  20. Liquid metal pump for nuclear reactors

    DOE Patents [OSTI]

    Allen, H.G.; Maloney, J.R.

    1975-10-01

    A pump for use in pumping high temperature liquids at high pressures, particularly liquid metals used to cool nuclear reactors is described. It is of the type in which the rotor is submerged in a sump but is fed by an inlet duct which bypasses the sump. A chamber, kept full of fluid, surrounds the pump casing into which fluid is bled from the pump discharge and from which fluid is fed to the rotor bearings and hence to the sump. This equalizes pressure inside and outside the pump casing and reduces or eliminates the thermal shock to the bearings and sump tank.

  1. Separation of metals by supported liquid membrane

    DOE Patents [OSTI]

    Takigawa, Doreen Y. (Los Alamos, NM)

    1992-01-01

    A supported liquid membrane system for the separation of a preselected chemical species within a feedstream, preferably an aqueous feedstream, includes a feed compartment containing a feed solution having at least one preselected chemical species therein, a stripping compartment containing a stripping solution therein, and a microporous polybenzimidazole membrane situated between the compartments, the microporous polybenzimidazole membrane containing an extractant mixture selective for the preselected chemical species within the membrane pores is disclosed along with a method of separating preselected chemical species from a feedstream with such a system, and a supported liquid membrane for use in such a system.

  2. Shear viscosity coefficient of liquid lanthanides

    SciTech Connect (OSTI)

    Patel, H. P. Thakor, P. B. Prajapati, A. V.; Sonvane, Y. A.

    2015-05-15

    Present paper deals with the computation of shear viscosity coefficient (?) of liquid lanthanides. The effective pair potential v(r) is calculated through our newly constructed model potential. The Pair distribution function g(r) is calculated from PYHS reference system. To see the influence of local field correction function, Hartree (H), Tailor (T) and Sarkar et al (S) local field correction function are used. Present results are compared with available experimental as well as theoretical data. Lastly, we found that our newly constructed model potential successfully explains the shear viscosity coefficient (?) of liquid lanthanides.

  3. Cellulosic Liquid Fuels Commercial Production Today

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cellulosic Liquid Fuels Commercial Production Today DOE Conference Washington DC, Aug 1, 2013 Our Business 2  We produce a renewable liquid fuel from wood and other non-food biomass  Our key product is Renewable Fuel Oil(tm) (RFO(tm))  RFO is a flexible petroleum-replacement with multiple uses including heating and for production of drop-in transportation fuels Commercial Status  Commercial production for over 20 years  Over 35 million gallons produced to date  Five commercial

  4. Coal to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in

  5. Kolorsafe Liquid Acid Neutralizer Safety Data Sheet

    Office of Environmental Management (EM)

    Kolorsafe Liquid Acid Neutralizer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: 03/07/2014 Date of issue: 03/07/2014 Version: 1.0 03/07/2014 EN (English US) 1/8 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY Product Identifier Product Form: Mixture Product Name: Kolorsafe Liquid Acid Neutralizer Product Code: 4100 series Intended Use of the Product Spill cleanup/ neutralize acids. For

  6. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Hyatt, David E.; Bustard, Cynthia Jean; Sjostrom, Sharon

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  7. LIQUID PHASE FISCHER-TROPSCH (III & IV) DEMONSTRATION IN THE LAPORTE ALTERNATIVE FUELS DEVELOPMENT UNIT. Final Topical Report. Volume I/II: Main Report. Task 1: Engineering Modifications (Fischer-Tropsch III & IV Demonstration) and Task 2: AFDU Shakedown, Operations, Deactivation (Shut-Down) and Disposal (Fischer-Tropsch III & IV Demonstration).

    SciTech Connect (OSTI)

    Bharat L. Bhatt

    1999-06-01

    Slurry phase Fischer-Tropsch technology was successfully demonstrated in DOE's Alternative Fuels Development Unit (AFDU) at LaPorte, Texas. Earlier work at LaPorte, with iron catalysts in 1992 and 1994, had established proof-of-concept status for the slurry phase process. The third campaign (Fischer-Tropsch III), in 1996, aimed at aggressively extending the operability of the slurry reactor using a proprietary cobalt catalyst. Due to an irreversible plugging of catalyst-wax separation filters as a result of unexpected catalyst fines generation, the operations had to be terminated after seven days on-stream. Following an extensive post-run investigation by the participants, the campaign was successfully completed in March-April 1998, with an improved proprietary cobalt catalyst. These runs were sponsored by the U. S. Department of Energy (DOE), Air Products & Chemicals, Inc., and Shell Synthetic Fuels, Inc. (SSFI). A productivity of approximately 140 grams (gm) of hydrocarbons (HC)/ hour (hr)-liter (lit) of expanded slurry volume was achieved at reasonable system stability during the second trial (Fischer-Tropsch IV). The productivity ranged from 110-140 at various conditions during the 18 days of operations. The catalyst/wax filters performed well throughout the demonstration, producing a clean wax product. For the most part, only one of the four filter housings was needed for catalyst/wax filtration. The filter flux appeared to exceed the design flux. A combination of use of a stronger catalyst and some innovative filtration techniques were responsible for this success. There was no sign of catalyst particle attrition and very little erosion of the slurry pump was observed, in contrast to the Fischer-Tropsch III operations. The reactor operated hydrodynamically stable with uniform temperature profile and gas hold-ups. Nuclear density and differential pressure measurements indicated somewhat higher than expected gas hold-up (45 - 50 vol%) during Fischer-Tropsch IV operations. The high gas hold-up was confirmed by a dynamic gas disengagement test conducted at the end of the run. Heat transfer in the reactor was better than expected. Heat, mass and elemental balance calculations indicated excellent closure. After the initial learning curve with system dynamics, the plant was restarted very quickly (24 hours and 17 hours) following two plant trips. This demonstrates the ease and flexibility of the slurry technology. In-situ reduction of catalyst pre-cursor was completed successfully during F-T IV operations. Water measurements proved to be inaccurate due to wax/oil contamination of the analytical system. However, the reduction appeared to proceed well as close to expected syngas conversion was obtained at the beginning of the run. The selectivity to wax was lower than expected, with higher methane selectivity. Returning to the baseline condition indicated a productivity decline from 135-140 to 125-130 gm HC/hr-lit. of reactor volume in two weeks of operation. This may be a result of some catalyst loss from the reactor as well as initial catalyst deactivation. Significant quantities of product and samples were collected for further processing and analysis by the participants. Gas, liquid and solid phase mixing were studied as planned at two operating conditions using radioactive materials. A large amount of data were collected by ICI Tracerco using 43 detectors around the reactor. The data are being analyzed by Washington University as part of the Hydrodynamic Program with DOE.

  8. Systems and methods for analyzing liquids under vacuum

    DOE Patents [OSTI]

    Yu, Xiao-Ying; Yang, Li; Cowin, James P.; Iedema, Martin J.; Zhu, Zihua

    2013-10-15

    Systems and methods for supporting a liquid against a vacuum pressure in a chamber can enable analysis of the liquid surface using vacuum-based chemical analysis instruments. No electrical or fluid connections are required to pass through the chamber walls. The systems can include a reservoir, a pump, and a liquid flow path. The reservoir contains a liquid-phase sample. The pump drives flow of the sample from the reservoir, through the liquid flow path, and back to the reservoir. The flow of the sample is not substantially driven by a differential between pressures inside and outside of the liquid flow path. An aperture in the liquid flow path exposes a stable portion of the liquid-phase sample to the vacuum pressure within the chamber. The radius, or size, of the aperture is less than or equal to a critical value required to support a meniscus of the liquid-phase sample by surface tension.

  9. US crude oil, natural gas, and natural gas liquids reserves 1996 annual report

    SciTech Connect (OSTI)

    1997-12-01

    The EIA annual reserves report series is the only source of comprehensive domestic proved reserves estimates. This publication is used by the Congress, Federal and State agencies, industry, and other interested parties to obtain accurate estimates of the Nation`s proved reserves of crude oil, natural gas, and natural gas liquids. These data are essential to the development, implementation, and evaluation of energy policy and legislation. This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1996, as well as production volumes for the US and selected States and State subdivisions for the year 1996. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), nonassociated gas and associated-dissolved gas (which are the two major types of wet natural gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, reserve estimates for two types of natural gas liquids, lease condensate and natural gas plant liquids, are presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1996 is provided. 21 figs., 16 tabs.

  10. U.S. crude oil, natural gas, and natural gas liquids reserves 1995 annual report

    SciTech Connect (OSTI)

    1996-11-01

    The EIA annual reserves report series is the only source of comprehensive domestic proved reserves estimates. This publication is used by the Congress, Federal and State agencies, industry, and other interested parties to obtain accurate estimates of the Nation`s proved reserves of crude oil, natural gas, and natural gas liquids. These data are essential to the development, implementation, and evaluation of energy policy and legislation. This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1995, as well as production volumes for the US and selected States and State subdivisions for the year 1995. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), nonassociated gas and associated-dissolved gas (which are the two major types of wet natural gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, reserve estimates for two types of natural gas liquids, lease condensate and natural gas plant liquids, are presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1995 is provided. 21 figs., 16 tabs.

  11. VOC and HAP recovery using ionic liquids

    SciTech Connect (OSTI)

    Michael R. Milota : Kaichang Li

    2007-05-29

    During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200°C (almost 400°F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120°C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy(trihexyl)phosphonium dicyanamide as the RTIL. It was determined that it has good absorption properties for methanol and ?-pinene, is thermally stable, and is relatively easy to synthesize. It has a density of 0.89 g/mL at 20°C and a molecular weight of 549.9 g/mol. Trials were conducted with a small absorption system and a larger absorption system. Methanol, formaldehyde, and other HAPs were absorbed well, nearly 100%. Acetaldehyde was difficult to capture. Total VOC capture, while satisfactory on methanol and ?-pinene in a lab system, was less than expected in the field, 60-80%. The inability to capture the broad spectrum of total organics is likely due to difficulties in cleaning them from the ionic liquid rather than the ability of the ionic liquid to absorb. It’s likely that a commercial system could be constructed to remove 90 to 100% of the gas contaminates. Selecting the correct ionic liquid would be key to this. Absorption may not be the main selection criterion, but rather how easily the ionic liquid can be cleaned is very important. The ionic liquid absorption system might work very well in a system with a limited spectrum of pollutants, such as a paint spray line, where there are not very high molecular weight, non volatile, compounds in the exhaust.

  12. Utilizing Metalized Fabrics for Liquid and Rip Detection and Localization

    SciTech Connect (OSTI)

    Holland, Stephen; Mahan, Cody; Kuhn, Michael J; Rowe, Nathan C

    2013-01-01

    This paper proposes a novel technique for utilizing conductive textiles as a distributed sensor for detecting and localizing liquids (e.g., blood), rips (e.g., bullet holes), and potentially biosignals. The proposed technique is verified through both simulation and experimental measurements. Circuit theory is utilized to depict conductive fabric as a bounded, near-infinite grid of resistors. Solutions to the well-known infinite resistance grid problem are used to confirm the accuracy and validity of this modeling approach. Simulations allow for discontinuities to be placed within the resistor matrix to illustrate the effects of bullet holes within the fabric. A real-time experimental system was developed that uses a multiplexed Wheatstone bridge approach to reconstruct the resistor grid across the conductive fabric and detect liquids and rips. The resistor grid model is validated through a comparison of simulated and experimental results. Results suggest accuracy proportional to the electrode spacing in determining the presence and location of discontinuities in conductive fabric samples. Future work is focused on refining the experimental system to provide more accuracy in detecting and localizing events as well as developing a complete prototype that can be deployed for field testing. Potential applications include intelligent clothing, flexible, lightweight sensing systems, and combat wound detection.

  13. A method of measuring a molten metal liquid pool volume

    DOE Patents [OSTI]

    Garcia, G.V.; Carlson, N.M., Donaldson, A.D.

    1990-12-12

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figs.

  14. Liquid Fuels from Lignins: Annual Report

    SciTech Connect (OSTI)

    Chum, H. L.; Johnson, D. K.

    1986-01-01

    This task was initiated to assess the conversion of lignins into liquid fuels, primarily of lignins relevant to biomass-to-ethanol conversion processes. The task was composed of a literature review of this area and an experimental part to obtain pertinent data on the conversion of lignins germane to biomass-to-ethanol conversion processes.

  15. Separations by supported liquid membrane cascades

    DOE Patents [OSTI]

    Danesi, Pier R.

    1986-01-01

    The invention describes a new separation technique which leads to multi-stage operations by the use of a series (a cascade) of alternated carrier-containing supported-liquid membranes. The membranes contain alternatively a liquid cation exchanger extractant and a liquid anion exchanger extractant (or a neutral extractant) as carrier. The membranes are spaced between alternated aqueous electrolytic solutions of different composition which alternatively provide positively charged extractable species and negatively charged (or zero charged) extractable species, of the chemical species to be separated. The alternated aqueous electrolytic solutions in addition to providing the driving force to the process, simultaneously function as a stripping solution from one type of membrane and as an extraction-promoting solution for the other type of membrane. The aqueous electrolytic solutions and the supported liquid membranes are arranged in such a way to provide a continuous process which leads to the continuous enrichment of the species which show the highest permeability coefficients. By virtue of the very high number of stages which can be arranged, even chemical species having very similar chemical behavior (and consequently very similar permeability coefficients) can be completely separated. The invention also provide a way to concentrate the separated species.

  16. Conversion of cellulosic wastes to liquid fuels

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-09-01

    The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

  17. Improved liquid-film electron stripper

    DOE Patents [OSTI]

    Gavin, B.F.

    1984-11-01

    An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one side of the disc's periphery and with highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90/sup 0/ angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

  18. Liquid uranium alloy-helium fission reactor

    DOE Patents [OSTI]

    Minkov, Vladimir (Skokie, IL)

    1986-01-01

    This invention teaches a nuclear fission reactor having a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200.degree.-1800.degree. C. range, and even higher to 2500.degree. C., limited only by the thermal effectiveness of the structural materials, increasing the efficiency of power generation from the normal 30-35% with 300.degree.-500.degree. C. upper limit temperature to 50-65%. Irradiation of the circulating liquid fuel, as contrasted to only localized irradiation of a solid fuel, provides improved fuel utilization.

  19. Combined plasma/liquid cleaning of substrates

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM); Henins, Ivars (Los Alamos, NM)

    2003-04-15

    Apparatus and method for cleaning substrates. A substrate is held and rotated by a chuck and an atmospheric pressure plasma jet places a plasma onto predetermined areas of the substrate. Subsequently liquid rinse is sprayed onto the predetermined areas. In one embodiment, a nozzle sprays a gas onto the predetermined areas to assist in drying the predetermined areas when needed.

  20. 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunaid; Tang, Chau

    2014-12-09

    The present invention relates to compositions of matter that are ionic liquids, the compositions comprising substituted 1,2,3-triazolium cations combined with any anion. Compositions of the invention should be useful in the separation of gases and, perhaps, as catalysts for many reactions.

  1. Engineering-Scale Liquid Cadmium Cathode Experiments

    SciTech Connect (OSTI)

    D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

    2006-08-01

    Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

  2. Dataset used to improve liquid water absorption models in the microwave

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Turner, David

    2015-12-14

    Two datasets, one a compilation of laboratory data and one a compilation from three field sites, are provided here. These datasets provide measurements of the real and imaginary refractive indices and absorption as a function of cloud temperature. These datasets were used in the development of the new liquid water absorption model that was published in Turner et al. 2015.

  3. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  4. Methods to control phase inversions and enhance mass transfer in liquid-liquid dispersions

    DOE Patents [OSTI]

    Tsouris, Constantinos (Oak Ridge, TN); Dong, Junhang (Oak Ridge, TN)

    2002-01-01

    The present invention is directed to the effects of applied electric fields on liquid-liquid dispersions. In general, the present invention is directed to the control of phase inversions in liquid-liquid dispersions. Because of polarization and deformation effects, coalescence of aqueous drops is facilitated by the application of electric fields. As a result, with an increase in the applied voltage, the ambivalence region is narrowed and shifted toward higher volume fractions of the dispersed phase. This permits the invention to be used to ensure that the aqueous phase remains continuous, even at a high volume fraction of the organic phase. Additionally, the volume fraction of the organic phase may be increased without causing phase inversion, and may be used to correct a phase inversion which has already occurred. Finally, the invention may be used to enhance mass transfer rates from one phase to another through the use of phase inversions.

  5. 13.0 LIQUID EFFLUENT TREATMENT AND DISPOSAL 13.1 LIQUID EFFLUENT...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are the result, in part, of EPA's and Ecology's reviews of the Liquid Effluent Study (LES) that was submitted by DOE in August 1990. The LES included information on the 33 Phase...

  6. Laser capillary spectrophotometric acquisition of bivariate drop size and concentration data for liquid-liquid dispersion

    DOE Patents [OSTI]

    Tavlarides, Lawrence L. (Fayetteville, NY); Bae, Jae-Heum (Daejeon, KR)

    1991-01-01

    A laser capillary spectrophotometric technique measures real time or near real time bivariate drop size and concentration distribution for a reactive liquid-liquid dispersion system. The dispersion is drawn into a precision-bore glass capillary and an appropriate light source is used to distinguish the aqueous phase from slugs of the organic phase at two points along the capillary whose separation is precisely known. The suction velocity is measured, as is the length of each slug from which the drop free diameter is calculated. For each drop, the absorptivity at a given wavelength is related to the molar concentration of a solute of interest, and the concentration of given drops of the organic phase is derived from pulse heights of the detected light. This technique permits on-line monitoring and control of liquid-liquid dispersion processes.

  7. Dependence of solid-liquid interface free energy on liquid structure

    SciTech Connect (OSTI)

    Wilson, S R; Mendelev, M I

    2014-09-01

    The Turnbull relation is widely believed to enable prediction of solid–liquid interface (SLI) free energies from measurements of the latent heat and the solid density. Ewing proposed an additional contribution to the SLI free energy to account for variations in liquid structure near the interface. In the present study, molecular dynamics (MD) simulations were performed to investigate whether SLI free energy depends on liquid structure. Analysis of the MD simulation data for 11 fcc metals demonstrated that the Turnbull relation is only a rough approximation for highly ordered liquids, whereas much better agreement is observed with Ewing’s theory. A modification to Ewing’s relation is proposed in this study that was found to provide excellent agreement with MD simulation data.

  8. Laser capillary spectrophotometric acquisition of bivariate drop size and concentration data for liquid-liquid dispersion

    DOE Patents [OSTI]

    Tavlarides, L.L.; Bae, J.H.

    1991-12-24

    A laser capillary spectrophotometric technique measures real time or near real time bivariate drop size and concentration distribution for a reactive liquid-liquid dispersion system. The dispersion is drawn into a precision-bore glass capillary and an appropriate light source is used to distinguish the aqueous phase from slugs of the organic phase at two points along the capillary whose separation is precisely known. The suction velocity is measured, as is the length of each slug from which the drop free diameter is calculated. For each drop, the absorptivity at a given wavelength is related to the molar concentration of a solute of interest, and the concentration of given drops of the organic phase is derived from pulse heights of the detected light. This technique permits on-line monitoring and control of liquid-liquid dispersion processes. 17 figures.

  9. Idaho Nuclear Technology and Engineering Center Newly Generated Liquid Waste Demonstration Project Feasibility Study

    SciTech Connect (OSTI)

    Herbst, A.K.

    2000-02-01

    A research, development, and demonstration project for the grouting of newly generated liquid waste (NGLW) at the Idaho Nuclear Technology and Engineering Center is considered feasible. NGLW is expected from process equipment waste, decontamination waste, analytical laboratory waste, fuel storage basin waste water, and high-level liquid waste evaporator condensate. The potential grouted waste would be classed as mixed low-level waste, stabilized and immobilized to meet RCRA LDR disposal in a grouting process in the CPP-604 facility, and then transported to the state.

  10. Savannah River Site Liquid-Waste Contractor Installs New Cost...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Liquid-Waste Contractor Installs New Cost-Saving Pump Design Savannah River Site Liquid-Waste Contractor Installs New Cost-Saving Pump Design October 29, 2015 - 12:05pm Addthis New...

  11. Process to upgrade coal liquids by extraction prior to hydrodenitrogenation

    DOE Patents [OSTI]

    Schneider, Abraham (Overbrook Hills, PA); Hollstein, Elmer J. (Wilmington, DE); Janoski, Edward J. (Havertown, PA); Scheibel, Edward G. (Media, PA)

    1982-01-01

    Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

  12. Systems and methods for monitoring a solid-liquid interface

    DOE Patents [OSTI]

    Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

    2013-06-11

    Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

  13. System for removing liquid waste from a tank

    DOE Patents [OSTI]

    Meneely, Timothy K. (Penn Hills, PA); Sherbine, Catherine A. (N. Versailles Township, Allegheny County, PA)

    1994-01-01

    A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid therethrough. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank.

  14. Hybrid Rotor Compression for Multiphase and Liquids-Rich Wellhead

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but also allows for compression of wet gas, or gas that contains liquid content. At many natural gas wellheads, liquids-typically heavier hydrocarbons and water-are present in the...

  15. Removal of carbonyl sulfide from liquid hydrocarbon streams

    SciTech Connect (OSTI)

    Damron, E.; Mick, M.B.; Woodall, R.M.

    1981-09-22

    Carbonyl sulfide is removed from propane and other similar liquefied petroleum gas products by mixing liquid methanol with the untreated liquefied gas and then contacting the liquid mixture with solid potassium hydroxide.

  16. System for removing liquid waste from a tank

    DOE Patents [OSTI]

    Meneely, T.K.; Sherbine, C.A.

    1994-04-26

    A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid there through. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank. 2 figures.

  17. Technology available for license: Charging of liquid energy storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    license: Charging of liquid energy storage media through radiolysis (ANL-IN-14-036) January 23, 2015 Tweet EmailPrint This technology utilizes radiolysis to charge liquid energy...

  18. Texas Natural Gas Plant Liquids Production (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Production (Million Cubic Feet) Texas Natural Gas Plant Liquids Production (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...

  19. Texas Natural Gas Plant Liquids, Proved Reserves (Million Barrels...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Liquids, Proved Reserves (Million Barrels) Texas Natural Gas Plant Liquids, Proved Reserves (Million Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

  20. Performance Characteristics of Coal-to-Liquids (CTL) Diesel in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State Emissions Compliant Passenger Car Performance Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State Emissions ...

  1. Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries

    SciTech Connect (OSTI)

    Kushner, Mark Jay

    2014-07-10

    In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

  2. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  3. Sensor for detection of liquid spills on surfaces

    DOE Patents [OSTI]

    Davis, Brent C. (Oak Ridge, TN); Gayle, Tom M. (Oak Ridge, TN)

    1989-01-01

    A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

  4. EIAs Proposed Definitions for Natural Gas Liquids

    Gasoline and Diesel Fuel Update (EIA)

    Definitions for Natural Gas Liquids 1 June 14, 2013 EIA's Proposed Definitions for Natural Gas Liquids Term Current Definition Proposed Definition Note Lease condensate Condensate (lease condensate): A natural gas liquid recovered from associated and non associated gas wells from lease separators or field facilities, reported in barrels of 42 U.S. gallons at atmospheric pressure and 60 degrees Fahrenheit. Lease condensate: Light liquid hydrocarbons recovered from lease separators or field

  5. Liquid Propane Injection Technology Conductive to Today's North American

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Specification | Department of Energy Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection technology can offer the same power, torque, and environmental vehicle performance while reducing imports of foreign oil PDF icon deer09_arnold.pdf More Documents & Publications Liquid Propane Injection Applications Liquid Propane Injection Applications Transportation Fuels: The

  6. Testing for Uranium Deuteride Initiation in Liquid Deuterium

    SciTech Connect (OSTI)

    Siekhaus, W. J.; Teslich, N. E.; Kucheyev, S. O.; Go, J.

    2015-10-29

    This report offers a description of the testing related to Uranium foil and its interaction with liquid deuterium.

  7. Radioactive Liquid Waste Treatment Facility Discharges in 2014

    SciTech Connect (OSTI)

    Del Signore, John C.

    2015-07-14

    This report documents radioactive discharges from the TA50 Radioactive Liquid Waste Treatment Facilities (RLWTF) during calendar 2014.

  8. Metal-air low temperature ionic liquid cell

    DOE Patents [OSTI]

    Friesen, Cody A; Buttry, Daniel A

    2014-11-25

    The present application relates to an electrochemical metal-air cell in which a low temperature ionic liquid is used.

  9. New Structure found at Ionic Liquid Surface | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Structure found at Ionic Liquid Surface

  10. Energetic Materials for EGS Well Stimulation (solids, liquids, gases) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon energetics_peer2013.pdf More Documents & Publications Controlled Rapid Pressurization Using Liquid Propellants for EGS Well Stimulation track 4: enhanced geothermal systems

  11. MagViz Bottled Liquid Scanner at Albuquerque International Sunport

    ScienceCinema (OSTI)

    Surko, Stephen; Dennis, Steve; Espy, Michelle

    2014-08-12

    The next-generation bottled liquid scanner, MagViz BLS, is demonstrated at the Albuquerque International Sunport, New Mexico

  12. Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan

    SciTech Connect (OSTI)

    Van Hoesen, S.D.

    2003-09-09

    Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

  13. Dynamic and spectroscopic characteristics of atmospheric gliding arc in gas-liquid two-phase flow

    SciTech Connect (OSTI)

    Tu, X.; Yu, L.; Yan, J. H.; Cen, K. F.; Cheron, B. G.

    2009-11-15

    In this study, an atmospheric alternating-current gliding arc device in gas-liquid two-phase flow has been developed for the purpose of waste water degradation. The dynamic behavior of the gas-liquid gliding arc is investigated through the oscillations of electrical signals, while the spatial evolution of the arc column is analyzed by high speed photography. Different arc breakdown regimes are reported, and the restrike mode is identified as the typical fluctuation characteristic of the hybrid gliding arc in air-water mixture. Optical emission spectroscopy is employed to investigate the active species generated in the gas-liquid plasma. The axial evolution of the OH (309 nm) intensity is determined, while the rotational and vibrational temperatures of the OH are obtained by a comparison between the experimental and simulated spectra. The significant discrepancy between the rotational and translational temperatures has also been discussed.

  14. Liquid Fuel From Microbial Communities: Electroalcoholgenesis: Bioelectrochemical Reduction of CO2 to Butanol

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: MUSC is developing an engineered system to create liquid fuels from communities of interdependent microorganisms. MUSC is first pumping carbon dioxide (CO2) and renewable sources of electricity into a battery-like cell. A community of microorganisms uses the electricity to convert the CO2 into hydrogen. That hydrogen is then consumed by another community of microorganisms living in the same system. These new microorganisms convert the hydrogen into acetate, which in turn feed yet another community of microorganisms. This last community of microorganisms uses the acetate to produce a liquid biofuel called butanol. Similar interdependent microbial communities can be found in some natural environments, but they’ve never been coupled together in an engineered cell to produce liquid fuels. MUSC is working to triple the amount of butanol that can be produced in its system and to reduce the overall cost of the process.

  15. High air volume to low liquid volume aerosol collector

    DOE Patents [OSTI]

    Masquelier, Donald A. (Tracy, CA); Milanovich, Fred P. (Lafayette, CA); Willeke, Klaus (Cincinnati, OH)

    2003-01-01

    A high air volume to low liquid volume aerosol collector. A high volume flow of aerosol particles is drawn into an annular, centripetal slot in a collector which directs the aerosol flow into a small volume of liquid pool contained is a lower center section of the collector. The annular jet of air impinges into the liquid, imbedding initially airborne particles in the liquid. The liquid in the pool continuously circulates in the lower section of the collector by moving to the center line, then upwardly, and through assistance by a rotating deflector plate passes back into the liquid at the outer area adjacent the impinging air jet which passes upwardly through the liquid pool and through a hollow center of the collector, and is discharged via a side outlet opening. Any liquid droplets escaping with the effluent air are captured by a rotating mist eliminator and moved back toward the liquid pool. The collector includes a sensor assembly for determining, controlling, and maintaining the level of the liquid pool, and includes a lower centrally located valve assembly connected to a liquid reservoir and to an analyzer for analyzing the particles which are impinged into the liquid pool.

  16. Electrohydrodynamically driven large-area liquid ion sources

    DOE Patents [OSTI]

    Pregenzer, Arian L. (Corrales, NM)

    1988-01-01

    A large-area liquid ion source comprises means for generating, over a large area of the surface of a liquid, an electric field of a strength sufficient to induce emission of ions from a large area of said liquid. Large areas in this context are those distinct from emitting areas in unidimensional emitters.

  17. Synthesis of electroactive ionic liquids for flow battery applications

    DOE Patents [OSTI]

    Anderson, Travis Mark; Ingersoll, David; Staiger, Chad; Pratt, Harry

    2015-09-01

    The present disclosure is directed to synthesizing metal ionic liquids with transition metal coordination cations, where such metal ionic liquids can be used in a flow battery. A cation of a metal ionic liquid includes a transition metal and a ligand coordinated to the transition metal.

  18. RF cavity using liquid dielectric for tuning and cooling

    DOE Patents [OSTI]

    Popovic, Milorad (Warrenville, IL); Johnson, Rolland P. (Newport News, VA)

    2012-04-17

    A system for accelerating particles includes an RF cavity that contains a ferrite core and a liquid dielectric. Characteristics of the ferrite core and the liquid dielectric, among other factors, determine the resonant frequency of the RF cavity. The liquid dielectric is circulated to cool the ferrite core during the operation of the system.

  19. Optical Design Considerations for Efficient Light Collection from Liquid Scintillation Counters

    SciTech Connect (OSTI)

    Bernacki, Bruce E.; Douglas, Matthew; Erchinger, Jennifer L.; Fuller, Erin S.; Keillor, Martin E.; Morley, Shannon M.; Mullen, Crystal A.; Orrell, John L.; Panisko, Mark E.; Warren, Glen A.; Wright, Michael E.

    2015-01-01

    Liquid scintillation counters measure charged particle-emitting radioactive isotopes and are used for environmental studies, nuclear chemistry, and life science. Alpha and beta emissions arising from the material under study interact with the scintillation cocktail to produce light. The prototypical liquid scintillation counter employs low-level photon-counting detectors to measure the arrival of the scintillation light produced as a result of the dissolved material under study interacting with the scintillation cocktail. For reliable operation the counting instrument must convey the scintillation light to the detectors efficiently and predictably. Current best practices employ the use of two or more detectors for coincidence processing to discriminate true scintillation events from background events due to instrumental effects such as photomultiplier tube dark rates, tube flashing, or other light emission not generated in the scintillation cocktail vial. In low background liquid scintillation counters additional attention is paid to shielding the scintillation cocktail from naturally occurring radioactive material (NORM) present in the laboratory and within the instruments construction materials. Low background design is generally at odds with optimal light collection. This study presents the evolution of a light collection design for liquid scintillation counting in a low background shield. The basic approach to achieve both good light collection and a low background measurement is described. The baseline signals arising from the scintillation vial are modeled and methods to efficiently collect scintillation light are presented as part of the development of a customized low-background, high sensitivity liquid scintillation counting system.

  20. Studies of ionic liquids in lithium-ion battery test systems

    SciTech Connect (OSTI)

    Salminen, Justin; Prausnitz, John M.; Newman, John

    2006-06-01

    In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.

  1. Liquid CO{sub 2}/Coal Slurry for Feeding Low Rank Coal to Gasifiers

    SciTech Connect (OSTI)

    Marasigan, Jose; Goldstein, Harvey; Dooher, John

    2013-09-30

    This study investigates the practicality of using a liquid CO{sub 2}/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO{sub 2} has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO{sub 2} is much lower than water. This means it should take less energy to pump liquid CO{sub 2} through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO{sub 2} is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO{sub 2} is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO{sub 2} slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO{sub 2} has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO{sub 2} over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO{sub 2}/coal slurry properties. This low-rank coal study extends the existing knowledge base to evaluate the liquid CO{sub 2}/coal slurry concept on an E-Gas™-based IGCC plant with full 90% CO{sub 2} capture. The overall objective is to determine if this technology could be used to reduce the cost and improve the efficiency of IGCC plants. The study goes beyond the systems-level analyses and initial lab work that formed the bases of previous studies and includes the following tasks: performing laboratory tests to quantify slurry properties; developing an engineering design of a liquid CO{sub 2} slurry preparation and feed system; conducting a full IGCC plant techno-economic analysis for Powder River Basin (PRB) coal and North Dakota lignite in both water and liquid CO{sub 2} slurries; and identifying a technology development plan to continue the due diligence to conduct a comprehensive evaluation of this technology. The initial task included rheology tests and slurry data analyses that would increase the knowledge and understanding of maximum solids loading capability for both PRB and lignite. Higher coal concentrations have been verified in liquid CO{sub 2} over water slurries, and a coal concentration of 75% by weight in liquid CO{sub 2} has been estimated to be achievable in a commercial application. In addition, lower slurry viscosities have been verified in liquid CO{sub 2} at the same solids loading, where the liquid CO{sub 2}/coal slurry viscosity has been measured to be about a factor of 10 lower than the comparable water slurry and estimated to be less than 100 centipoise in a commercial application. In the following task, an engineering design of a liquid CO{sub 2}/coal slurry preparation and mixing system has been developed for both a batch and continuous system. The capital cost of the design has also been estimated so that it could be used in the economic analysis. An industry search and survey has been conducted to determine if essential components required to construct the feed system are available from commercial sources or if targeted R&D efforts are required. The search and survey concluded that commercial sources are available for selected components that comprise both the batch and continuous type systems. During normal operation, the fuel exits the bottom of the coal silo and is fed to a rod mill for grinding to the desired particle size. From the rod mill, the coal is transported in a dense phase pneumatic transport system to the top of a solids heat exchanger, wherein the ground coal is chilled to a low temperature (in the range of -23.3°C (-10°F)) prior to mixing with liquid CO{sub 2}. This temperature was selected based on evaluating trade-offs between refrigeration work and the cost of the system pressure boundary at various combinations of pressure and temperature that correspond to the gas/liquid phase boundary for CO{sub 2}. Electrical loads to drive the equipment comprising the liquid CO{sub 2} feed system are significantly greater than those for a water slurry system, and this effect has been captured in the technical performance analysis. In the next task, a plant-wide techno-economic analysis has been conducted for PRB coal and lignite in both liquid CO{sub 2} and water slurry feed. The IGCC cases using a liquid CO{sub 2} slurry system show reduced plant output and higher heat rate for PRB coal and for ND lignite at 90% CO{sub 2} capture. Some of these performance differences can be attributed to the higher requirement for steam for the liquid CO{sub 2} slurry cases to drive the water-gas shift reaction, thereby reducing steam turbine power generation. Other factors contributing to the calculated performance differences are the increase in parasitic loads attributable to refrigeration to produce liquid CO{sub 2} and chilled coal and the reduction in enthalpy of the inlet streams to the gasifier associated with the low temperature liquid CO{sub 2} slurry feed. The capital costs for the complete plant are slightly higher for the liquid CO{sub 2} slurry cases for PRB coal but somewhat reduced for ND lignite relative to the corresponding water slurry cases. Differences in dollar/kWe costs are higher for both coals due to the reduction in net output. The cost of electricity computed for the liquid CO{sub 2}/coal slurry cases is greater for both PRB and ND Lignite coals. It does not appear that there is any benefit to using liquid CO{sub 2}/coal slurries for feeding low rank coals to the E-Gas™ gasifier. Any incidental benefits in improved cold gas efficiency are more than compensated for in higher overall plant costs, increased complexity, and reduced power output and efficiency. The results of the study are compared with previous published analyses, and the differences in model assumptions, approach and basis are summarized. It has been concluded that the use of liquid CO{sub 2} may still prove to have a significant advantage in a different type of gasifier, i.e., single-stage entrained flow with radiant quench section, but some key questions remain unanswered that can validate the potential improvement of gasifier performance using liquid CO{sub 2} slurries. In order to provide a path to answering these questions, a technology development roadmap has been developed to resolve fundamental issues and to better define the operation aspects of using liquid CO{sub 2}/coal slurries. The fundamental issues could be resolved by conducting additional laboratory analyses consisting of: • A rheological test program to quantitatively evaluate slurry preparation and handling for liquid CO{sub 2} including experiments to evaluate preparation systems. • An experimental program on CO{sub 2}-assisted gasification in order to obtain the most relevant experimental data from drop tube furnace studies to aid in verifying the potential advantages of direct feed of liquid CO{sub 2}/coal as gasifier feedstocks. Quantifying the operational aspects of liquid CO{sub 2} slurries can best be achieved with: • An experimental program using a flow test loop to evaluate equipment performance and handling properties of liquid CO{sub 2}/coal slurries for gasifier feedstocks on a scale sufficient to predict full scale operating parameters. • Spray atomization studies necessary to evaluate the effect of atomization properties of liquid CO{sub 2}/coal slurries that could be significantly different than those of water/coal slurries.

  2. Thermally triggered phononic gaps in liquids at THz scale

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bolmatov, Dima; Zhernenkov, Mikhail; Zavyalov, Dmitry; Stoupin, Stanislav; Cunsolo, Alessandro; Cai, Yong Q.

    2016-01-14

    In this study we present inelastic X-ray scattering experiments in a diamond anvil cell and molecular dynamic simulations to investigate the behavior of phononic excitations in liquid Ar. The spectra calculated using molecular dynamics were found to be in a good agreement with the experimental data. Furthermore, we observe that, upon temperature increases, a low-frequency transverse phononic gap emerges while high-frequency propagating modes become evanescent at the THz scale. The effect of strong localization of a longitudinal phononic mode in the supercritical phase is observed for the first time. The evidence for the high-frequency transverse phononic gap due to themore » transition from an oscillatory to a ballistic dynamic regimes of motion is presented and supported by molecular dynamics simulations. This transition takes place across the Frenkel line thermodynamic limit which demarcates compressed liquid and non-compressed fluid domains on the phase diagram and is supported by calculations within the Green-Kubo phenomenological formalism. These results are crucial to advance the development of novel terahertz thermal devices, phononic lenses, mirrors, and other THz metamaterials.« less

  3. Advanced Liquid Natural Gas Onboard Storage System

    SciTech Connect (OSTI)

    Greg Harper; Charles Powars

    2003-10-31

    Cummins Westport Incorporated (CWI) has designed and developed a liquefied natural gas (LNG) vehicle fuel system that includes a reciprocating pump with the cold end submerged in LNG contained in a vacuum-jacketed tank. This system was tested and analyzed under the U.S. Department of Energy (DOE) Advanced LNG Onboard Storage System (ALOSS) program. The pumped LNG fuel system developed by CWI and tested under the ALOSS program is a high-pressure system designed for application on Class 8 trucks powered by CWI's ISX G engine, which employs high-pressure direct injection (HPDI) technology. A general ALOSS program objective was to demonstrate the feasibility and advantages of a pumped LNG fuel system relative to on-vehicle fuel systems that require the LNG to be ''conditioned'' to saturation pressures that exceeds the engine fuel pressure requirements. These advantages include the capability to store more fuel mass in given-size vehicle and station tanks, and simpler lower-cost LNG refueling stations that do not require conditioning equipment. Pumped LNG vehicle fuel systems are an alternative to conditioned LNG systems for spark-ignition natural gas and port-injection dual-fuel engines (which typically require about 100 psi), and they are required for HPDI engines (which require over 3,000 psi). The ALOSS program demonstrated the feasibility of a pumped LNG vehicle fuel system and the advantages of this design relative to systems that require conditioning the LNG to a saturation pressure exceeding the engine fuel pressure requirement. LNG tanks mounted on test carts and the CWI engineering truck were repeatedly filled with LNG saturated at 20 to 30 psig. More fuel mass was stored in the vehicle tanks as well as the station tank, and no conditioning equipment was required at the fueling station. The ALOSS program also demonstrated the general viability and specific performance of the CWI pumped LNG fuel system design. The system tested as part of this program is designed to be used on Class 8 trucks with CWI ISX G HPDI engines. Extensive test cart and engineering truck tests of the pump demonstrated good durability and the high-pressure performance needed for HPDI application. The LNG tanks manufactured by Taylor-Wharton passed SAE J2343 Recommended Practice drop tests and accelerated road-load vibration tests. NER and hold-time tests produced highly consistent results. Additional tests confirmed the design adequacy of the liquid level sensor, vaporizer, ullage volume, and other fuel system components. While the testing work performed under this program focused on a high-pressure pumped LNG fuel system design, the results also validate the feasibility of a low-pressure pumped fuel system. A low-pressure pumped fuel system could incorporate various design refinements including a simpler and lighter-weight pump, which would decrease costs somewhat relative to a high-pressure system.

  4. Refining and end use of coal liquids. Quarterly report, January--March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-01

    A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An intregral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop, an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with the Process Industry Modeling System (PICS) software. The objectives of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major efforts conducted during the first quarter of 1994 were in the areas of: subcontract preparation and negotiation; and linear programming modeling.

  5. Cracking in liquid petroleum gas Horton spheres

    SciTech Connect (OSTI)

    Trivedi, D.K. Gupta, S.C.

    1997-07-01

    A gas processing plant on the western coast of India produces sweet gas after processing sour natural gas. Liquid petroleum gas (LPG) is recovered from the sweet gas. The LPG, containing a H{sub 2}S concentration of 10 ppm to 20 ppm, is stored in Horton spheres, each 17 m in diameter with a capacity of {minus}27 C to 55 C. Horton spheres for containing liquid petroleum gas (LPG) were fabricated on-site using prestressed plates of high-strength carbon steel (CS) SA 537 Class-1 with post-weld heat treatment. High-residual tensile stresses and hydrogen absorption from H{sub 2}S present in LPG could be the cause of cracking at weld and heat-affected zone interfaces at high hardness locations. Recommendations are given for inspection and use of lower-strength CS and improved welding procedures.

  6. Kinetics of complex plasma with liquid droplets

    SciTech Connect (OSTI)

    Misra, Shikha; Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India); Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)] [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)

    2013-12-15

    This paper provides a theoretical basis for the reduction of electron density by spray of water (or other liquids) in hot plasma. This phenomenon has been observed in a hypersonic flight experiment for relief of radio black out, caused by high ionization in the plasma sheath of a hypersonic vehicle, re-entering the atmosphere. The analysis incorporates a rather little known phenomenon for de-charging of the droplets, viz., evaporation of ions from the surface and includes the charge balance on the droplets and number cum energy balance of electrons, ions, and neutral molecules; the energy balance of the evaporating droplets has also been taken into account. The analysis has been applied to a realistic situation and the transient variations of the charge and radius of water droplets, and other plasma parameters have been obtained and discussed. The analysis through made in the context of water droplets is applicable to all liquids.

  7. Ultrasonic characterization of single drops of liquids

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    1998-01-01

    Ultrasonic characterization of single drops of liquids. The present invention includes the use of two closely spaced transducers, or one transducer and a closely spaced reflector plate, to form an interferometer suitable for ultrasonic characterization of droplet-size and smaller samples without the need for a container. The droplet is held between the interferometer elements, whose distance apart may be adjusted, by surface tension. The surfaces of the interferometer elements may be readily cleansed by a stream of solvent followed by purified air when it is desired to change samples. A single drop of liquid is sufficient for high-quality measurement. Examples of samples which may be investigated using the apparatus and method of the present invention include biological specimens (tear drops; blood and other body fluid samples; samples from tumors, tissues, and organs; secretions from tissues and organs; snake and bee venom, etc.) for diagnostic evaluation, samples in forensic investigations, and detection of drugs in small quantities.

  8. Micro-column plasma emission liquid chromatograph

    DOE Patents [OSTI]

    Gay, Don D. (Aiken, SC)

    1984-01-01

    In a direct current plasma emission spectrometer for use in combination with a micro-column liquid chromatograph, an improved plasma source unit. The plasma source unit includes a quartz capillary tube having an inlet means, outlet off gas means and a pair of spaced electrodes defining a plasma region in the tube. The inlet means is connected to and adapted to receive eluant of the liquid chromatograph along with a stream of plasma-forming gas. There is an opening through the wall of the capillary tube penetrating into the plasma region. A soft glass capillary light pipe is disposed at the opening, is connected to the spectrometer, and is adapted to transmit light passing from the plasma region to the spectrometer. There is also a source of electromotive force connected to the electrodes sufficient to initiate and sustain a plasma in the plasma region of the tube.

  9. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1999-01-05

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  10. System and method for liquid silicon containment

    SciTech Connect (OSTI)

    Cliber, James A; Clark, Roger F; Stoddard, Nathan G; Von Dollen, Paul

    2014-06-03

    This invention relates to a system and a method for liquid silicon containment, such as during the casting of high purity silicon used in solar cells or solar modules. The containment apparatus includes a shielding ember adapted to prevent breaching molten silicon from contacting structural elements or cooling elements of a casting device, and a volume adapted to hold a quantity of breaching molten silicon with the volume formed by a bottom and one or more sides.

  11. imidazolium-based ionic liquid pretreatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    imidazolium-based ionic liquid pretreatment - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  12. understanding the chemistries of ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistries of ionic liquids - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  13. Ionic Liquids Create More Sustainable Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ionic Liquids Create More Sustainable Processes - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  14. System and method for liquid silicon containment

    DOE Patents [OSTI]

    Cliber, James A; Clark, Roger F; Stoddard, Nathan G; Von Dollen, Paul

    2013-05-28

    This invention relates to a system and a method for liquid silicon containment, such as during the casting of high purity silicon used in solar cells or solar modules. The containment apparatus includes a shielding member adapted to prevent breaching molten silicon from contacting structural elements or cooling elements of a casting device, and a volume adapted to hold a quantity of breaching molten silicon with the volume formed by a bottom and one or more sides.

  15. Air Emission, Liquid Effluent Inventory and Reporting

    Energy Science and Technology Software Center (OSTI)

    1998-08-18

    The IES maintains an inventory of radiological air and liquid effluents released to the atmosphere. The IES utilizes the official stack numbers. Data may be entered by generators for any monitoring time period. Waste volumes released as well as their radiological constituents are tracked. The IES provides data to produce a report for NESHAPS as well as several administrative action/anomaly reports. These reports flag unusual occurences (releases) that are above normal range releases.

  16. Ternary liquid scintillator for optical fiber applications

    DOE Patents [OSTI]

    Franks, Larry A. (Santa Barbara, CA); Lutz, Stephen S. (Santa Barbara, CA)

    1982-01-01

    A multicomponent liquid scintillator solution for use as a radiation-to-light converter in conjunction with a fiber optic transmission system. The scintillator includes a quantity of 5-amino-9-diethylaminobenz (a) phenoxazonium nitrate (Nile Blue Nitrate) as a solute in a fluor solvent such as benzyl alcohol. The use of PPD as an additional solute is also disclosed. The system is controllable by addition of a suitable quenching agent, such as phenol.

  17. Liquid scintillators for optical fiber applications

    DOE Patents [OSTI]

    Franks, Larry A. (Santa Barbara, CA); Lutz, Stephen S. (Santa Barbara, CA)

    1982-01-01

    A multicomponent liquid scintillator solution for use as a radiation-to-light converter in conjunction with a fiber optic transmission system. The scintillator includes a quantity of 1, 2, 4, 5, 3H, 6H, 1 OH, tetrahydro-8-trifluoromethyl (1) benzopyrano (9, 9a, 1-gh) quinolizin-10-one (Coumarin) as a solute in a fluor solvent such as benzyl alcohol or pseudo-cumene. The use of BIBUQ as an additional or primary solute is also disclosed.

  18. Liquid uranium alloy-helium fission reactor

    DOE Patents [OSTI]

    Minkov, V.

    1984-06-13

    This invention describes a nuclear fission reactor which has a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200 to 1800/sup 0/C range, and even higher to 2500/sup 0/C.

  19. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, Terrence L. (Lenior City, TN); Wilson, James H. (Oak Ridge, TN)

    1993-01-01

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

  20. Use of ionic liquids as coordination ligands for organometallic catalysts

    DOE Patents [OSTI]

    Li, Zaiwei (Moreno Valley, CA); Tang, Yongchun (Walnut, CA); Cheng; Jihong (Arcadia, CA)

    2009-11-10

    Aspects of the present invention relate to compositions and methods for the use of ionic liquids with dissolved metal compounds as catalysts for a variety of chemical reactions. Ionic liquids are salts that generally are liquids at room temperature, and are capable of dissolving a many types of compounds that are relatively insoluble in aqueous or organic solvent systems. Specifically, ionic liquids may dissolve metal compounds to produce homogeneous and heterogeneous organometallic catalysts. One industrially-important chemical reaction that may be catalyzed by metal-containing ionic liquid catalysts is the conversion of methane to methanol.

  1. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  2. Methods and systems for monitoring a solid-liquid interface

    DOE Patents [OSTI]

    Stoddard, Nathan G. (Gettysburg, PA); Clark, Roger F. (Frederick, MD); Kary, Tim (Union Bridge, MD)

    2010-07-20

    Methods and systems are provided for monitoring a solid-liquid interface, including providing a vessel configured to contain an at least partially melted material; detecting radiation reflected from a surface of a liquid portion of the at least partially melted material that is parallel with the liquid surface; measuring a disturbance on the surface; calculating at least one frequency associated with the disturbance; and determining a thickness of the liquid portion based on the at least one frequency, wherein the thickness is calculated based on.times. ##EQU00001## where g is the gravitational constant, w is the horizontal width of the liquid, and f is the at least one frequency.

  3. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, T.L.; Wilson, J.H.

    1993-09-21

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

  4. Collection of liquid from below-ground location

    DOE Patents [OSTI]

    Phillips, S.J.; Alexander, R.G.

    1995-05-30

    A method is described for retrieving liquid from a below-ground collection area by permitting gravity flow of the liquid from the collection area to a first closed container; monitoring the level of the liquid in the closed container; and after the liquid reaches a given level in the first closed container, transferring the liquid to a second closed container disposed at a location above the first closed container, via a conduit, by introducing into the first closed container a gas which is substantially chemically inert with respect to the liquid, the gas being at a pressure sufficient to propel the liquid from the first closed container to the second closed container. 3 figs.

  5. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % andmore » 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.« less

  6. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    SciTech Connect (OSTI)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % and 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.

  7. Combining innovative technology demonstrations with dense nonaqueous phase liquids cleanup

    SciTech Connect (OSTI)

    Hagood, M.C.; Koegler, K.J.; Rohay, V.J.; Trent, S.J.; Stein, S.L.; Brouns, T.M.; McCabe, G.H.; Tomich, S.

    1993-05-01

    Radioactively contaminated acidic aqueous wastes and organic liquids were discharged to the soil column at three disposal sites within the 200 West Area of the Hanford Site, Washington. As a result, a portion of the underlying groundwater is contaminated with carbon tetrachloride several orders of magnitude above the maximum contaminant level accepted for a drinking water supply. Treatability testing and cleanup actions have been initiated to remove the contamination from both the unsaturated soils to minimize further groundwater contamination and the groundwater itself. To expedite cleanup, innovative technologies for (1) drilling, (2) site characterization, (3) monitoring, (4) well field development, and (5) contaminant treatment are being demonstrated and subsequently used where possible to improve the rates and cost savings associated with the removal of carbon tetrachloride from the soils and groundwater.

  8. NREL Research on Converting Biomass to Liquid Fuels

    ScienceCinema (OSTI)

    None

    2013-05-29

    Unlike other renewable energy sources, biomass can be converted directly into liquid fuels, called "biofuels," to help meet transportation fuel needs. The two most common types of biofuels are ethanol and biodiesel. Today, ethanol is made from starches and sugars, but at the National Renewable Energy Laboratory (NREL) scientists are developing technology to allow it to be made from cellulose and hemicellulose, the fibrous material that makes up the bulk of most plant matter. Biodiesel is made by combining alcohol (usually methanol) with vegetable oil, animal fat, or recycled cooking grease. It can be used as an additive (typically 20%) to reduce vehicle emissions or in its pure form as a renewable alternative fuel for diesel engines. For a text version of this video visit http://www.nrel.gov/learning/re_biofuels.html

  9. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  10. Towards Chip Scale Liquid Chromatography and High Throughput Immunosensing

    SciTech Connect (OSTI)

    Ni, J.

    2000-09-21

    This work describes several research projects aimed towards developing new instruments and novel methods for high throughput chemical and biological analysis. Approaches are taken in two directions. The first direction takes advantage of well-established semiconductor fabrication techniques and applies them to miniaturize instruments that are workhorses in analytical laboratories. Specifically, the first part of this work focused on the development of micropumps and microvalves for controlled fluid delivery. The mechanism of these micropumps and microvalves relies on the electrochemically-induced surface tension change at a mercury/electrolyte interface. A miniaturized flow injection analysis device was integrated and flow injection analyses were demonstrated. In the second part of this work, microfluidic chips were also designed, fabricated, and tested. Separations of two fluorescent dyes were demonstrated in microfabricated channels, based on an open-tubular liquid chromatography (OT LC) or an electrochemically-modulated liquid chromatography (EMLC) format. A reduction in instrument size can potentially increase analysis speed, and allow exceedingly small amounts of sample to be analyzed under diverse separation conditions. The second direction explores the surface enhanced Raman spectroscopy (SERS) as a signal transduction method for immunoassay analysis. It takes advantage of the improved detection sensitivity as a result of surface enhancement on colloidal gold, the narrow width of Raman band, and the stability of Raman scattering signals to distinguish several different species simultaneously without exploiting spatially-separated addresses on a biochip. By labeling gold nanoparticles with different Raman reporters in conjunction with different detection antibodies, a simultaneous detection of a dual-analyte immunoassay was demonstrated. Using this scheme for quantitative analysis was also studied and preliminary dose-response curves from an immunoassay of a mo del antigen were obtained. Simultaneous detection of several analytes at the same address can potentially increase the analysis speed, and can further expand the analysis capability of a microarray chip.

  11. AFM fluid delivery/liquid extraction surface sampling/electrostatic spray cantilever probe

    DOE Patents [OSTI]

    Van Berkel, Gary J.

    2015-06-23

    An electrospray system comprises a liquid extraction surface sampling probe. The probe comprises a probe body having a liquid inlet and a liquid outlet, and having a liquid extraction tip. A solvent delivery conduit is provided for receiving solvent liquid from the liquid inlet and delivering the solvent liquid to the liquid extraction tip. An open liquid extraction channel extends across an exterior surface of the probe body from the liquid extraction tip to the liquid outlet. An electrospray emitter tip is in liquid communication with the liquid outlet of the liquid extraction surface sampling probe. A system for analyzing samples, a liquid junction surface sampling system, and a method of analyzing samples are also disclosed.

  12. Electromagnetic induction pump for pumping liquid metals and other conductive liquids

    DOE Patents [OSTI]

    Smither, R.K.

    1993-05-11

    An electromagnetic induction pump is described in which an electrically conductive liquid is made to flow by means of a force created by interaction of a permanent magnetic field and a DC current. The pump achieves high efficiency through combination of: powerful permanent magnet materials which provide a high strength field that is uniform and constant; steel tubing formed into a coil which is constructed to carry conducting liquids with minimal electrical resistance and heat; and application of a voltage to induce a DC current which continuously produces a force in the direction of the desired flow.

  13. Electromagnetic induction pump for pumping liquid metals and other conductive liquids

    DOE Patents [OSTI]

    Smither, Robert K.

    1993-01-01

    An electromagnetic induction pump in which an electrically conductive liquid is made to flow by means of a force created by interaction of a permanent magnetic field and a DC current. The pump achieves high efficiency through combination of: powerful permanent magnet materials which provide a high strength field that is uniform and constant; steel tubing formed into a coil which is constructed to carry conducting liquids with minimal electrical resistance and heat; and application of a voltage to induce a DC current which continuously produces a force in the direction of the desired flow.

  14. Liquid-liquid extraction of short-chain organic acids from anaerobic digesters

    SciTech Connect (OSTI)

    Wene, E.G.; Antonopoulos, A.A.

    1989-01-01

    Anaerobic digesters with glucose or municipal solid waste (MSW) feed were operated to maximize production of short-chain organic acids. Digester effluent was extracted by liquid-liquid extraction with trioctylphosphine oxide (TOPO) or trioctylamine (TOA) in heptane or 2-heptanone as the water immiscible phase. Digester effluent was recycled to digesters after extraction. Both TOPO and TOA in organic solvents effectively extract organic acids from anaerobic digester fluid. Longer chain acids have a higher distribution coefficient than shorter-chain acids. Long term extraction of digester fluid with recycle was not toxic to the anaerobic production of short-chain acids.

  15. Non-Aqueous Phase Liquid Calculator

    Energy Science and Technology Software Center (OSTI)

    2004-02-19

    Non-Aqueous Phase Liquid or "NPAL" is a term that most environmental professionals are familiar with because NAPL has been recognized in the literature as a significant source of groundwater contamination. There are two types of NAPL: DNAPL and LNAPL. DNAPL is a ‘dense’ non-aqueous phase liquid. In this context, dense means having a density greater than water (1.0 kg/L). Trichloroethylene (TCE) and tetrachioroethylene (PCE) are examples of DNAPL compounds. A compound that is heaver thanmore » water means this type of NAPL will sink in an aquifer. Conversely, LNAPL is a ‘light’ non-aqueous phase liquid with a density less than water, and will float on top of the aquifer. Examples of LNAPL’s are benzene and toluene. LNAPL or DNAPL often manifest as a complex, multi-component mixture of organic compounds that can occur in environmental media. Complex multi-component mixtures distributed in soil pore-air, pore-water, soil particles and in free phase complicate residual saturation of single and multi component NAPL compounds in soil samples. The model output also includes estimates of the NAPL mass and volume and other physical and chemical properties that may be useful for characterization, modeling, and remedial system design and operation. The discovery of NAPL in the aquifer usually leads to a focused characterization for possible sources of NAPL in the vadose zone using a variety of innovative technologies and characterization methods. Often, the analytical data will indicated the presence of NAPL, yet, the NAPL will go unrecognized. Failure to recognize the NAPL can be attributed to the complicated processes of inter-media transfer or a general lack of knowledge about the physical characteristics of complex organic mixtures in environmental samples.« less

  16. Chiral Isotropic Liquids from Achiral Molecules

    SciTech Connect (OSTI)

    L Hough; M Spannuth; M Nakata; D Coleman; C Jones; G Dantlgraber; C Tschierske; J Watanabe; N Clark; et al.

    2011-12-31

    A variety of simple bent-core molecules exhibit smectic liquid crystal phases of planar fluid layers that are spontaneously both polar and chiral in the absence of crystalline order. We found that because of intralayer structural mismatch, such layers are also only marginally stable against spontaneous saddle splay deformation, which is incompatible with long-range order. This results in macroscopically isotropic fluids that possess only short-range orientational and positional order, in which the only macroscopically broken symmetry is chirality - even though the phases are formed from achiral molecules. Their conglomerate domains exhibit optical rotatory powers comparable to the highest ever found for isotropic fluids of chiral molecules.

  17. High-pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, C.G.; Sakaji, R.H.

    1982-09-08

    A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

  18. High pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, Christian G.; Sakaji, Richard H.

    1985-01-01

    A gradient mixer which effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum "band-broadening".

  19. Reusable crucible for containing corrosive liquids

    DOE Patents [OSTI]

    de Pruneda, Jean A. H. (Livermore, CA)

    1995-01-01

    A reusable, non-wetting, corrosion-resistant material suitable for containment of corrosive liquids is formed of a tantalum or tantalum alloy substrate that is permeated with carbon atoms. The substrate is carburized to form surface layers of TaC and Ta.sub.2 C, and then is heated at high temperature under vacuum until the carbon atoms in the carbide layers diffuse throughout the substrate to form a solid solution of carbon atoms randomly interspersed in the tantalum or tantalum alloy lattice.

  20. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  1. Liquid Effluent Retention Facility - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Effluent Retention Facility About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration Disposal

  2. Natural Gas Plant Liquids Proved Reserves

    Gasoline and Diesel Fuel Update (EIA)

    Natural Gas Plant Liquids contained in Total Natural Gas Proved Reserves (Million Barrels) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012 2013 2014 View History U.S. 8,557 9,809 10,825 10,777 11,943 15,029 1979-2014 Alabama 55 68 68 55 51 59 1979-2014 Alaska 299 288 288 288 288 241 1979-2014 Arkansas 2 2 3 3 4 5 1979-2014 California 129 114 94 99 102 112 1979-2014 Coastal Region Onshore 10 11 12

  3. Liquid-Filled Piping System Analysis

    Energy Science and Technology Software Center (OSTI)

    1993-07-07

    WHAM6 is used to calculate pressure and velocity transients in liquid-filled piping networks. It can be applied to multiloop complex piping networks consisting of dead ends, elbows, orifices, multiple-branch tees, changes of flow passage cross section, check valves, pumps, pressurizers or tanks, and exit valves or breaks. Hydraulic losses are considered. Transients can be initiated either by closure or opening of one or more exit valves (equivalent to system ruptures) or by a prescribed gasmore » pressure history in a pressurizer tank.« less

  4. Cryocompressed Hydrogen Storage and Liquid Delivery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cryocompressed Hydrogen Storage & Liquid Delivery Jacob Leachman, Ph.D. Assistant Professor DOE H 2 Transmission & Delivery Workshop 2/26/2014 H Y P E R H drogen roperties for nergy esearch This presentation does not contain any proprietary, confidential, or otherwise restricted information. Jacob Leachman * DOE H 2 Transmission & Distribution Workshop * 2/25/2014 H Y P E R Why Cryogenic Hydrogen? * LH 2 tanker trucks delivered 80-90 % of total small merchant H 2 in 2010. 1 * Cryo-H

  5. Reusable crucible for containing corrosive liquids

    DOE Patents [OSTI]

    Pruneda, J.A.H. de.

    1995-01-24

    A reusable, non-wetting, corrosion-resistant material suitable for containment of corrosive liquids is formed of a tantalum or tantalum alloy substrate that is permeated with carbon atoms. The substrate is carburized to form surface layers of TaC and Ta[sub 2]C, and then is heated at high temperature under vacuum until the carbon atoms in the carbide layers diffuse throughout the substrate to form a solid solution of carbon atoms randomly interspersed in the tantalum or tantalum alloy lattice. 10 figures.

  6. Ultrasonic characterization of solid liquid suspensions

    DOE Patents [OSTI]

    Panetta, Paul D.

    2010-06-22

    Using an ultrasonic field, properties of a solid liquid suspension such as through-transmission attenuation, backscattering, and diffuse field are measured. These properties are converted to quantities indicating the strength of different loss mechanisms (such as absorption, single scattering and multiple scattering) among particles in the suspension. Such separation of the loss mechanisms can allow for direct comparison of the attenuating effects of the mechanisms. These comparisons can also indicate a model most likely to accurately characterize the suspension and can aid in determination of properties such as particle size, concentration, and density of the suspension.

  7. Durable electrooptic devices comprising ionic liquids

    DOE Patents [OSTI]

    Agrawal, Anoop (Tucson, AZ); Cronin, John P. (Tucson, AZ); Tonazzi, Juan C. L. (Tucson, AZ); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Burrell, Anthony K. (Los Alamos, NM)

    2005-11-01

    Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3-), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N-), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N-) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

  8. Experimental and Theoretical Studies of Liquid-Solid and Liquid-Vapor Interfaces of Metals and Alloys, Grant DE-FG02-06ER46321

    SciTech Connect (OSTI)

    Rice, Stuart

    2012-09-27

    The research supported by ER46321 was designed to understand in microscopic detail the structures of the interfaces between liquid metals and alloys and solid media. The system chosen for study, because of detailed knowledge of the structure of the corresponding liquid alloy-vapor interface, was the interface between a Si crystal and a dilute alloy of Pb in Ga. Experimental study of the Si:PbGa interface was anticipated to be very difficult; it requires preparation of an interface between a liquid metal and a solid surface that is flat to better than a nanometer on the scale length of the x-ray coherence, alignment of the x-ray beam and the surface in the sub-micro radian regime, and the use of high energy x-rays to penetrate the window and reach the interface without disastrous loss of intensity. The experimental design was subject to compromises forced by the limit to the highest x-ray energy available at the ChemMatCARS beam-line, namely 30 keV, which reduced the scattered signal relative to what can be obtained with higher x-ray energy. Although considerable progress was achieved during the support period and its no-cost extension, the difficulties encountered prevented completion of the studies and the data collected are incomplete. These data hint at the existence of unexpected structural features of the interface, in particular that Pb dimers play an important role in the interfacial structure. These data provide a different picture of the interface from the pentagonal structure inferred to be present in the interface between pure Pb and Si 001 (Nature 408, 839 (2000)), but much like the Ga dimers in the interface between liquid Ga and the 100 face of diamond (Nature 390, 379 (1997), J. Chem. Phys. 123, 104703 (2005)). However, during the latter part of the support period significant progress was made in the theoretical description of the liquid metal-crystal interface. In particular, stimulated by the results of an experimental study of the interface between liquid Hg and the reconstructed (0001) face of sapphire, we developed an extension of the self-consistent quantum Monte Carlo scheme previously used to study the structure of the liquid metal-vapor interface. The calculated density distribution is in very good agreement with that inferred from the experimental data. We conclude, contrary to the original interpretation offered by Tamam et al (J. Phys. Chem. Lett. 2010, I, 1041-1045), thast to account for the difference in structure between the liquid Hg-vapor and liquid Hg-reconstructed (0001) Al{sub 2}O{sub 3} interfaces it is not necessary to assume there is charge transfer from the Hg to the Al{sub 2}O{sub 3}. Rather, the available experimental data are adequately reproduced when the van der Waals interaction of the Al and O atoms with Hg atoms and the exclusion of the electron density from the Al{sub 2}O{sub 3} via repulsion of the electrons from the closed shells of the ions in the solid are accounted for. We believe this interpretation will be applicable to a wide range of liquid metal-crystal interfaces.

  9. Centrifugal contactor with liquid mixing and flow control vanes and method of mixing liquids of different phases

    DOE Patents [OSTI]

    Jubin, Robert T. (Powell, TN); Randolph, John D. (Maryville, TN)

    1991-01-01

    The invention is directed to a centrifugal contactor for solvent extraction systems. The centrifugal contactor is provided with an annular vertically oriented mixing chamber between the rotor housing and the rotor for mixing process liquids such as the aqueous and organic phases of the solvent extraction process used for nuclear fuel reprocessing. A set of stationary helically disposed vanes carried by the housing is in the lower region of the mixing chamber at a location below the process-liquid inlets for the purpose of urging the liquids in an upward direction toward the inlets and enhancing the mixing of the liquids and mass transfer between the liquids. The upper region of the mixing vessel above the inlets for the process liquids is also provided with a set helically disposed vanes carried by the housing for urging the process liquids in a downward direction when the liquid flow rates through the inlets are relatively high and the liquids contact the vane set in the upper region. The use of these opposing vane sets in the mixing zone maintains the liquid in the mixing zone at suitable levels.

  10. Gelled Ionic Liquid-Based Membranes: Achieving a 10,000 GPU Permeance for Post-Combustion Carbon Capture with Gelled Ionic Liquid-Based Membranes

    SciTech Connect (OSTI)

    None

    2011-02-02

    IMPACCT Project: Alongside Los Alamos National Laboratory and the Electric Power Research Institute, CU-Boulder is developing a membrane made of a gelled ionic liquid to capture CO2 from the exhaust of coal-fired power plants. The membranes are created by spraying the gelled ionic liquids in thin layers onto porous support structures using a specialized coating technique. The new membrane is highly efficient at pulling CO2 out of coal-derived flue gas exhaust while restricting the flow of other materials through it. The design involves few chemicals or moving parts and is more mechanically stable than current technologies. The team is now working to further optimize the gelled materials for CO2 separation and create a membrane layer that is less than 1 micrometer thick.

  11. Industrial Technology of Decontamination of Liquid Radioactive Waste in SUE MosSIA 'Radon' - 12371

    SciTech Connect (OSTI)

    Adamovich, Dmitry V.; Neveykin, Petr P.; Karlin, Yuri V.; Savkin, Alexander E. [SUE MosSIA 'Radon', 7th Rostovsky lane 2/14, Moscow 119121 (Russian Federation)

    2012-07-01

    SUE MosSIA 'RADON' - this enterprise was created more than 50 years ago, which deals with the recycling of radioactive waste and conditioning of spent sources of radiation in stationary and mobile systems in the own factory and operating organizations. Here is represented the experience SUE MosSIA 'Radon' in the field of the management with liquid radioactive waste. It's shown, that the activity of SUE MosSIA 'RADON' is developing in three directions - improvement of technical facilities for treatment of radioactive waters into SUE MosSIA 'RADON' development of mobile equipment for the decontamination of radioactive waters in other organizations, development of new technologies for decontamination of liquid radioactive wastes as part of various domestic Russian and international projects including those related to the operation of nuclear power and nuclear submarines. SUE MosSIA 'RADON' has processed more than 270 thousand m{sup 3} of radioactive water, at that more than 7000 m{sup 3} in other organizations for more than 50 years. It is shown that a number of directions, particularly, the development of mobile modular units for decontamination of liquid radioactive waste, SUE MosSIA 'RADON' is a leader in the world. (authors)

  12. Apparatus and method for excluding gas from a liquid

    DOE Patents [OSTI]

    Murphy, Jr., Robert J. (Bellaire, TX)

    1985-01-01

    The present invention is directed to an apparatus and method for preventing diffusion of a gas under high pressure into the bulk of a liquid filling a substantially closed chamber. This apparatus and method is particularly useful in connection with test devices for testing fluid characteristics under harsh conditions of extremely high pressure and high temperature. These devices typically pressurize the liquid by placing the liquid in pressure and fluid communication with a high pressure inert gas. The apparatus and method of the present invention prevent diffusion of the pressurizing gas into the bulk of the test liquid by decreasing the chamber volume at a rate sufficient to maintain the bulk of the liquid free of absorbed or dissolved gas by expelling that portion of the liquid which is contaminated by the pressurizing gas.

  13. Exploring the structure of high temperature, iron-bearing liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wilding, Martin; Benmore, Chris; Weber, Rick; Parise, John; Lazareva, Lena; Skinner, Lawrie; Alderman, Oliver; Tamalonis, Antony

    2015-06-25

    This paper describes the direct measurements of the structure of iron-bearing liquids using a combination of containerless techniques and in–situ high energy x-ray diffraction. These capabilities provide data that is important to help model and optimize processes such as smelting, steel making, and controlling slag chemistry. A successful programme of liquid studies has been undertaken and the Advanced Photon Source using these combined techniques which include the provision of gas mixing and the control of pO₂ and the changing influence of mixed valance elements. It is possible to combine rapid image acquisition with quenching of liquids to obtain the fullmore » diffraction patterns of deeply supercooled liquids and the metastable supercooled liquid regime, where the liquid structures and viscosity change most dramatically, can also be explored.« less

  14. Exploring the structure of high temperature, iron-bearing liquids

    SciTech Connect (OSTI)

    Wilding, Martin; Benmore, Chris; Weber, Rick; Parise, John; Lazareva, Lena; Skinner, Lawrie; Alderman, Oliver; Tamalonis, Antony

    2015-06-25

    This paper describes the direct measurements of the structure of iron-bearing liquids using a combination of containerless techniques and in–situ high energy x-ray diffraction. These capabilities provide data that is important to help model and optimize processes such as smelting, steel making, and controlling slag chemistry. A successful programme of liquid studies has been undertaken and the Advanced Photon Source using these combined techniques which include the provision of gas mixing and the control of pO? and the changing influence of mixed valance elements. It is possible to combine rapid image acquisition with quenching of liquids to obtain the full diffraction patterns of deeply supercooled liquids and the metastable supercooled liquid regime, where the liquid structures and viscosity change most dramatically, can also be explored.

  15. Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns

    SciTech Connect (OSTI)

    Wishart, J.F.

    2011-06-12

    Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields, which need to be quantified for the successful use under radiolytic conditions. Electron solvation dynamics in ILs are measured directly when possible and estimated using proxies (e.g. coumarin-153 dynamic emission Stokes shifts or benzophenone anion solvation) in other cases. Electron reactivity is measured using ultrafast kinetics techniques for comparison with the solvation process.

  16. Liquid methanol under a static electric field

    SciTech Connect (OSTI)

    Cassone, Giuseppe; Giaquinta, Paolo V.; Saija, Franz; Saitta, A. Marco

    2015-02-07

    We report on an ab initio molecular dynamics study of liquid methanol under the effect of a static electric field. We found that the hydrogen-bond structure of methanol is more robust and persistent for field intensities below the molecular dissociation threshold whose value (?0.31 V/Å) turns out to be moderately larger than the corresponding estimate obtained for liquid water. A sustained ionic current, with ohmic current-voltage behavior, flows in this material for field intensities above 0.36 V/Å, as is also the case of water, but the resulting ionic conductivity (?0.40 S cm{sup ?1}) is at least one order of magnitude lower than that of water, a circumstance that evidences a lower efficiency of proton transfer processes. We surmise that this study may be relevant for the understanding of the properties and functioning of technological materials which exploit ionic conduction, such as direct-methanol fuel cells and Nafion membranes.

  17. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  18. Strong liquid-crystalline polymeric compositions

    DOE Patents [OSTI]

    Dowell, Flonnie (Los Alamos, NM)

    1993-01-01

    Strong liquid-crystalline polymeric (LCP) compositions of matter. LCP backbones are combined with liquid crystalline (LC) side chains in a manner which maximizes molecular ordering through interdigitation of the side chains, thereby yielding materials which are predicted to have superior mechanical properties over existing LCPs. The theoretical design of LCPs having such characteristics includes consideration of the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and in the side chains, the degree of polymerization, the length of the side chains, the regularity of the spacing of the side chains along the backbone, the interdigitation of side chains in sub-molecular strips, the packing of the side chains on one or two sides of the backbone to which they are attached, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and the side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and the side chains for easy alignment.

  19. Converting coal to liquid fuels. [US DOE

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    Liquid fuels play a vital role in the US economy. Oil represents about 40 percent of the energy consumed each year in this country. In many cases, it fills needs for which other energy forms cannot substitute efficiently or economically - in transportation, for example. Despite a current world-wide surplus of oil, conventional petroleum is a depletable resource. It inevitably will become harder and more expensive to extract. Already in the US, most of the cheap, easily reached oil has been found and extracted. Even under optimistic projections of new discoveries, domestic oil production, particularly in the lower 48 states, will most likely continue to drop. A future alternative to conventional petroleum could be liquid fuels made from coal. The technique is called coal liquefaction. From 1 to 3 barrels of oil can be made from each ton of coal. The basic technology is known; the major obstacles in the US have been the high costs of the synthetic oil and the risks of building large, multi-billion dollar first-of-a-kind plants. Yet, as natural petroleum becomes less plentiful and more expensive, oil made from abundant coal could someday become an increasingly important energy option. To prepare for that day, the US government is working with private industries and universities to establish a sound base of technical knowledge in coal liquefaction.

  20. Strong liquid-crystalline polymeric compositions

    DOE Patents [OSTI]

    Dowell, F.

    1993-12-07

    Strong liquid-crystalline polymeric (LCP) compositions of matter are described. LCP backbones are combined with liquid crystalline (LC) side chains in a manner which maximizes molecular ordering through interdigitation of the side chains, thereby yielding materials which are predicted to have superior mechanical properties over existing LCPs. The theoretical design of LCPs having such characteristics includes consideration of the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and in the side chains, the degree of polymerization, the length of the side chains, the regularity of the spacing of the side chains along the backbone, the interdigitation of side chains in sub-molecular strips, the packing of the side chains on one or two sides of the backbone to which they are attached, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and the side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and the side chains for easy alignment. 27 figures.