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1

On deformation twinning in a 17.5%Mn-TWIP steel: A physically...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological model. On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological...

2

Public Meeting: Draft Renewable Energy and Efficient Energy Projects Loan Guarantee Solicitation- Twin Cities, MN  

Broader source: Energy.gov [DOE]

University of Minnesota, Twin Cities, Institute on the Environment, Learning & Environmental Sciences, R-380

3

Sustaining development in Detroit  

E-Print Network [OSTI]

The intent of this thesis is to propose a strategy for stabilizing and increasing the disparate pieces of development that form the traces of the once great industrial city of Detroit. It focuses primarily on Fordism as a ...

Resnick, Noah Samuel, 1977-

2004-01-01T23:59:59.000Z

4

DOE - Office of Legacy Management -- Twin Cities Ammunition - MN 0-01  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site - MOTracerlab Inc -Twin Cities

5

TEXT-ALTERNATIVE VERSION: DETROIT WORKSHOP HIGHLIGHTS  

Broader source: Energy.gov [DOE]

Mayor Mike Duggan, City of Detroit: The DOE has just been an outstanding partner, and I'm really glad to be welcoming you here at this time. So welcome to Detroit.

6

Detroit Commuter Hydrogen Project  

SciTech Connect (OSTI)

This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with luggage. By collecting fuel use data for the two H2ICE buses, with both written driver logs and onboard telemetry devices, and for two conventional propane-gasoline powered buses in the same service, comparisons of operating efficiency and maintenance requirements were completed. Public opinion about the concept of hydrogen fuel was sampled with a rider survey throughout the demonstration. The demonstration was very effective in adding to the understanding of the application of hydrogen as a transportation fuel. The two 9 passenger H2ICE buses accumulated nearly 50,000 miles and carried 14,285 passengers. Data indicated the H2ICE bus fuel economy to be 9.4 miles/ gallon of gasoline equivalent (m/GGE) compared to the 10 passenger propane-gasoline bus average of 9.8 m/GGE over 32,400 miles. The 23- passenger bus averaged 7.4 m/GGE over 40,700 miles. Rider feedback from 1050 on-board survey cards was overwhelmingly positive with 99.6% indicating they would ride again on a hydrogen powered vehicle. Minimal maintenance was required for theses buses during the demonstration project, but a longer duration demonstration would be required to more adequately assess this aspect of the concept.

Brooks, Jerry; Prebo, Brendan

2010-07-31T23:59:59.000Z

7

Detroit's Urban Regime: Composition and Consequence  

E-Print Network [OSTI]

employ 6,000 United Auto Workers. !~: when it opened. Second, securing the project for Detroit was symbolically important. The new plant would mean investment by GM in Detroit: not just t.: jobs but an economic linchpin for the city. With an air... is defined as "the informal arrangements by which public bodies and private interests function together in order to be able to make and carry out governing decisions" (Stone, 1989:6). This informal partnership and the way it operates constitute the city...

Hall, Leda Mclntyre; Hall, Melvin F.

1993-04-01T23:59:59.000Z

8

A thermo-mechanical correlation with driving forces for hcp martensite and twin formations in the Fe-Mn-C system exhibiting multicomposition sets  

SciTech Connect (OSTI)

Thermodynamic properties of the Fe-Mn-C system were investigated by using an analytical model constructed by a CALPHAD approach. Stacking fault energy (SFE) of the fcc structure with respect to the hcp phase was always constant at T{sub 0}, independent of composition and temperature when the other related parameters were assumed to be constant. Experimental limits for the thermal hcp formation and the mechanical (deformation-induced) hcp formation were separated by the SFE at T{sub 0}. The driving force for the fcc to hcp transition, defined as a dimensionless value –dG{sub m}/(RT), was determined in the presence of Fe-rich and Mn-rich composition sets in each phase. Carbon tended to partition to the Mn-rich phase rather than to the Fe-rich phase for the studied compositions. The obtained results revealed a thermo-mechanical correlation with empirical yield strength, maximum true stress and maximum true strain. The proportionality between thermodynamics and mechanical properties is discussed.

Nakano, Jinichiro

2013-02-01T23:59:59.000Z

9

,"Detroit, MI Natural Gas Pipeline Imports From Canada (MMcf...  

U.S. Energy Information Administration (EIA) Indexed Site

Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Detroit, MI...

10

Detroit Public Lighting Department- Commercial and Industrial Energy Wise Program  

Broader source: Energy.gov [DOE]

The Detroit Public Lighting Department (PLD) offers commercial and industrial customers rebates for energy efficient equipment. Specific rebate amounts, equipment requirements, and applications are...

11

Detroit Public Lighting Department- Residential Energy Wise Program  

Broader source: Energy.gov [DOE]

The Detroit Public Lighting Department (PLD) offers residential customers rebates for energy efficient lights. In addition, low-income residential customers may qualify for free compact fluorescent...

12

In his recently published book Driving Detroit: The Quest  

E-Print Network [OSTI]

changed by three forces: an unplanned, speculation-driven housing development system; dependency. Throughout Driving Detroit, Detroiters tell their stories in songs, poems and oral histories, offering and management,describes his WSU playing field with the precision of an engineer:"More than 120 buildings,12

Baskaran, Mark

13

Detroit Edison Co | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump to:52c8ff988c1Dering Harbor, New York: EnergyEnergygua BonitaDetroit Edison

14

Detroit Edison Co | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump to:52c8ff988c1Dering Harbor, New York: EnergyEnergygua BonitaDetroit

15

Detroit Edison Co | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision has beenFinancialSilverUsing ThermalDetroit

16

Detroit, Michigan: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision has beenFinancialSilverUsingDetroit is a city in

17

SUSTAINABLE COMMUNITY REDEVELOPMENT: A Plan for Detroit's Lower Eastside  

E-Print Network [OSTI]

SUSTAINABLE COMMUNITY REDEVELOPMENT: A Plan for Detroit's Lower of Science/Master of Landscape Architecture (Natural Resources and Environment of the neighborhood. To aid JEBA in their strategic planning process, we developed a replicable model of sustainable

Edwards, Paul N.

18

Health-hazard evaluation report HETA 84-484-1754, Detroit Fire Fighters, Detroit, Michigan  

SciTech Connect (OSTI)

In response to a request from the International Association of Fire Fighters on behalf of the Detroit Fire Fighters Association, Detroit, Michigan, a health hazard evaluation was made of respiratory symptoms and skin irritation in fire fighters involved in a large fire and explosion at a warehouse. Over 200 fire fighters from fire-fighting organizations in three communities were involved in the incident. Site runoff water contained chlordane and malathion in low parts per million; other samples were negative. Nose and throat irritation, cough, and shortness of breath were experienced by a large proportion of fire fighters following the fire, and in 14, 15, and 17 percent, respectively, symptoms persisted over 2 months. Symptoms were significantly associated with time spent at the scene and time spent in heavy smoke. Pulmonary function tests were abnormal in 14 cases, ten due to obstructive lung disease, three to restrictive lung disease, and one to a combination. The authors conclude that better protective equipment is needed for fire fighters at chemical fires. Recommendations include development of a hazardous-materials response team, and implementation of a routine medical surveillance program.

Anderson, K.E.; Melius, J.M.

1986-12-01T23:59:59.000Z

19

Revving up the Motor City : targeted neighborhood redevelopment in Detroit  

E-Print Network [OSTI]

This thesis is an analysis of an ambitious redevelopment plan for a two square mile area in the city of Detroit, Michigan. This area is dominated by city-owned vacant lots, which make up half of the neighborhood. The plan, ...

Pauls, Edward, 1977-

2004-01-01T23:59:59.000Z

20

Transverse acoustic actuation of Ni-Mn-Ga single crystals  

E-Print Network [OSTI]

Two methods for the transverse acoustic actuation of {110}-cut Ni-Mn-Ga single crystals are discussed. In this actuation mode, crystals are used that have the {110}- type twinning planes parallel to the base of the crystal. ...

Simon, Jesse Matthew

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

WWJ-TV CBS Detroit/CW50 Detroit Internship Job Descriptions Community Affairs/Programming Internship: This internship provides students  

E-Print Network [OSTI]

WWJ-TV CBS Detroit/CW50 Detroit Internship Job Descriptions Community Affairs/Programming Internship: This internship provides students interns the opportunity to gain experience in Community Affairs internships offered for the winter, summer, and fall terms. Interns generally work either a Monday

Cinabro, David

22

A Look Inside the Detroit Auto Show | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3 Beryllium-Associated Worker2014Department ofDepartmentA Look Inside the Detroit

23

The struggle for vibrancy : a study of local government intervention in Detroit's inner suburbs  

E-Print Network [OSTI]

Today, many communities located on the periphery of central cities confront traditionally "urban" problems. Detroit's inner suburbs struggle with aging infrastructure, limited governmental capacity, commercial disinvestment, ...

Kohn, Amy J. (Amy Jennifer)

2005-01-01T23:59:59.000Z

24

Detroit Edison Advanced Implementation of Energy Storage Technologies  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy CooperationRequirements Matrix U.S. Department of|ALDeterminations andDetroit Edison

25

Tweed, Twins, and Holes  

E-Print Network [OSTI]

distribution is that of collapsing porous minerals under stress, where the main focus of research is the identification of precursor effects as warning signs for larger events such as the collapse of mines, boreholes or even regional earth quakes... science in which the functionality of a device material is no longer expected to be present in the bulk of the material but located in its nanoscopically small regions such as twin boundaries. This approach is summarized as ‘domain boundary engineering...

Salje, Ekhard K.H.

2014-07-08T23:59:59.000Z

26

Urban agriculture as a tool for neighborhood fabric repair in post-industrial Detroit  

E-Print Network [OSTI]

This thesis focuses on Detroit as a post-industrial city that suffers from abandonment, vacancy, and food security issues. I address this problem through the lens of agriculture, asking how urban farming can be used to ...

Fairbank, Sandra Trubow

2011-01-01T23:59:59.000Z

27

Anticipating Detroit : a collection of instruments as a catalyst for recovery  

E-Print Network [OSTI]

The social, political and economic history of Detroit has been inextricably linked to the development of its most dominant industry: automotive manufacturing. This thesis suggests a strategy to overcome the disadvantages ...

Bouwman, Laura Marcella, 1976-

2003-01-01T23:59:59.000Z

28

Detroit Edison's Fermi 1 - Preparation for Reactor Removal  

SciTech Connect (OSTI)

This paper is intended to provide information about the ongoing decommissioning tasks at Detroit Edison's Fermi 1 plant, and in particular, the work being performed to prepare the reactor for removal and disposal. In 1972 Fermi 1 was shutdown and the fuel returned to the Atomic Energy Commission. By the end of 1975, a retirement plan was prepared, the bulk sodium removed, and the plant placed in a safe store condition. The plant systems were left isolated with the sodium containing systems inert with carbon dioxide in an attempt to form a carbonate layer, thus passivating the underlying reactive sodium. In 1996, Detroit Edison determined to evaluate the condition of the plant and to make recommendations in relation to the Fermi 1 future plans. At the end of 1997 approval was obtained to remove the bulk asbestos and residual alkali-metals (i.e., sodium and sodium potassium (NaK)). In 2000, full nuclear decommissioning of the plant was approved. To date, the bulk asbestos insulation has been removed, and the only NaK remaining is located in six capillary instrument tubes. The remaining sodium is contained within the reactor, two of the three primary loops, and miscellaneous removed pipes and equipment to be processed. The preferred method for removing or reacting sodium at Fermi 1 is by injecting superheated steam into a heated, nitrogen inert system. The byproducts of this reaction are caustic sodium hydroxide, hydrogen gas, and heat. The decision was made to separate the three primary loops from the reactor for better control prior to processing each loop and the reactor separately. The first loop has already been processed. The main focus is now to process the reactor to allow removal and disposal of the Class C waste prior to the anticipated June 2008 closure of the Barnwell radioactive waste disposal facility located in South Carolina. Lessons learnt are summarized and concern: the realistic schedule and adherence to the schedule, time estimates, personnel accountability, back up or fill in work, work packages, condensation control, radiological contamination control, and organization of the waste stream.

Swindle, Danny [Sargent and Lundy Engineers, LLC, 55 E. Monroe Street, Chicago, IL 60603 (United States)

2008-01-15T23:59:59.000Z

29

INTERNSHIP OPPORTUNITY GRAPHIC DESIGN After 5 Detroit is looking for a Web Design Intern for Fall 2011. The internship runs  

E-Print Network [OSTI]

INTERNSHIP OPPORTUNITY ­ GRAPHIC DESIGN After 5 Detroit is looking for a Web Design Intern for Fall 2011. The internship runs from the beginning of May through the end of August. It is an unpaid internship but our past interns have generally earned college credits for their work. After 5 Detroit LLC

Cinabro, David

30

SAE 1983 Transactions, Paper No. 830200, pp. 1.810-1.816 International Congress & Exposition, Detroit, Mi., Feb. 28-March 4, 1983  

E-Print Network [OSTI]

, Detroit, Mi., Feb. 28- March 4, 1983 #12;SAE 1983 Transactions, Paper No. 830200, pp. 1.810-1.816 International Congress & Exposition, Detroit, Mi., Feb. 28- March 4, 1983 #12;SAE 1983 Transactions, Paper No. 830200, pp. 1.810-1.816 International Congress & Exposition, Detroit, Mi., Feb. 28- March 4, 1983 Fig. 2

Radcliffe, Clark J.

31

Detroit Area Guide This brief overview of the more popular areas to live while attending WSU-SOM is intended to  

E-Print Network [OSTI]

Midtown: A region of the City of Detroit located just south of WSU's campus. A few minutes' drive://www.metroairport.com/transportation/ #12;SMART Bus Website The SMART Bus system is Detroit's major form of public transportation. Check out their website for routes, schedules, and fares. http://www.smartbus.org/smart/home Detroit Taxi Directory Gives

Finley Jr., Russell L.

32

Potential benefits of a resource-recovery facility coupled with district heating in Detroit, Michigan  

SciTech Connect (OSTI)

The City of Detroit, Michigan, announced plans for a 2.7-Gg/d (3000-ton/d) Resource Recovery Facility to be located in the central part of the city. The facility will process and burn waste collected by the municipal forces. Steam generated in the facility's boilers will be used to produce electricity; the surplus electricity will be sold to the Detroit Edison Company. When needed by the Central Heating System (CHS), large portions of the steam can be extracted from the turbine and sold to the Detroit Edison Company. The facility will meet its primary purpose of greatly relieving Detroit's solid waste disposal problem. A second very important benefit is that it will be a source of reasonably priced steam for the CHS, which serves the downtown area. Detroit is now in a local depression, and the downtown areas have suffered urban decay. The city is focusing on the redevelopment of these areas, and a viable, cost-effective district heating system would be a major asset. Currently, the CHS is losing money, although it charges relatively high rates for steam, because it uses primarily natural gas to generate steam. The economic feasibility of converting the CHS's relatively oil boiler units to burn coal, a much cheaper fuel, is doubtful. The Resource Recovery Facility can provide CHS with a major part of its steam needs at competitive prices in the near future. This would do much to relieve the CHS's financial problems and help it to become a viable system. This, in turn, would assist the city in the redevelopment of the downtown areas. An overall strategy for district heating in Detroit is being developed. It is suggested that a comprehensive study of a regional district heating system in the city be made.

McLain, H.A.; Brinker, M.J.; Gatton, D.W.

1982-09-01T23:59:59.000Z

33

Michigan State University Community Music School -Detroit GIFT IN KIND VALUATION AND INTENT FORM  

E-Print Network [OSTI]

Michigan State University Community Music School -Detroit GIFT IN KIND VALUATION AND INTENT FORM University through the Michigan State University Foundation. This gift of: (Please include model & serial to Michigan State University for the specific purpose/use for: The value of my gift to MSU/MSU Foundation is

Liu, Taosheng

34

Plastic strain due to twinning in austenitic TWIP steels  

E-Print Network [OSTI]

Plastic strain due to twinning in austenitic TWIP steels B. Qin and H. K. D. H. Bhadeshia* Twinning induced plasticity steels are austenitic alloys in which mechanical twinning is a prominent deformation, Twinning, Twinning induced plasticity, Automobiles Introduction Mechanical twinning is a plastic

Cambridge, University of

35

Refinement in cases of Twinning Lothar Esser  

E-Print Network [OSTI]

Refinement in cases of Twinning Lothar Esser National Cancer Institute Despite working in crystallography for a number of years, it was only recently that I was asked to refine a structure against twinned was twinned using a model of > 99% sequence identity. As the refinement did not progress as it should

36

Advanced Communication and Control of Distributed Energy Resources at Detroit Edison  

SciTech Connect (OSTI)

The project objective was to create the communication and control system, the process and the economic procedures that will allow owners (e.g., residential, commercial, industrial, manufacturing, etc.) of Distributed Energy Resources (DER) connected in parallel to the electric distribution to have their resources operated in a manner that protects the electric utility distribution network and personnel that may be working on the network. The Distribution Engineering Workstation (DEW) (a power flow and short circuit modeling tool) was modified to calculate the real-time characteristics of the distribution network based on the real-time electric distribution network information and provide DER operating suggestions to the Detroit Edison system operators so that regional electric stability is maintained. Part of the suggestion algorithm takes into account the operational availability of DER’s, which is known by the Energy Aggregator, DTE Energy Technologies. The availability information will be exchanged from DTE Energy Technologies to Detroit Edison. For the calculated suggestions to be used by the Detroit Edison operators, procedures were developed to allow an operator to operate a DER by requesting operation of the DER through DTE Energy Technologies. Prior to issuing control of a DER, the safety of the distribution network and personnel needs to be taken into account. This information will be exchanged from Detroit Edison to DTE Energy Technologies. Once it is safe to control the DER, DTE Energy Technologies will issue the control signal. The real-time monitoring of the DECo system will reflect the DER control. Multi-vendor DER technologies’ representing approximately 4 MW of capacity was monitored and controlled using a web-based communication path. The DER technologies included are a photovoltaic system, energy storage, fuel cells and natural gas/diesel internal combustion engine generators. This report documents Phase I result for the Detroit Edison (Utility) led team, which also includes: DTE Energy Technology (DER provider & Aggregator), Electrical Distribution Design (Virginia Tech company supporting DEW); Systems Integration Specialists Company (real-time protocol integrator); and OSIsoft (software system for managing real-time information). This work was performed in anticipation of being selected for Phase II of the Advanced Communication and Control of Distributed Energy Resources project.

Haukur Asgeirsson; Richard Seguin

2004-01-31T23:59:59.000Z

37

Reversibleirreversible plasticity transition in twinned copper nanopillars  

E-Print Network [OSTI]

Reversible­irreversible plasticity transition in twinned copper nanopillars J.A. Brown, N 31 October 2009 Abstract Through computer simulations, we show that plasticity in twinned copper nanopillar under compression, plastic deformation can be totally reversed when rR is in the range 0:5 6 rR 6

Ghoniem, Nasr M.

38

INTERNSHIP OPPORTUNITY SOCIAL WEBSITE AND EVENTS After 5 Detroit is looking for a Website Intern for Fall 2011. The internship runs from  

E-Print Network [OSTI]

INTERNSHIP OPPORTUNITY ­ SOCIAL WEBSITE AND EVENTS After 5 Detroit is looking for a Website Intern for Fall 2011. The internship runs from the beginning of May through the end of August. It is an unpaid internship but our past interns have generally earned college credits for their work. After 5 Detroit LLC

Cinabro, David

39

Positron Emission Tomography-Scanner at Children`s Hospital of Michigan at Detroit, Michigan  

SciTech Connect (OSTI)

The Department of Energy has prepared an environmental assessment (EA), DOE/EA-0795, to support the DOE decision to provide a grant of $7,953,600 to be used in support of a proposed Positron Emission Tomography Scanner at Children`s Hospital of Michigan at Detroit, Michigan. Based upon the analysis in the EA, DOE has determined that the proposed action is not a major Federal action significantly affected the quality of the human environment within the meaning of the National Environmental Policy Act of 1969 (NEPA). Therefore, the preparation of an Environmental Impact Statement is not required and DOE is issuing this Finding of No Significant Impact (FONSI).

Not Available

1992-12-31T23:59:59.000Z

40

TWIN BUILDING LATTICES DO NOT HAVE ASYMPTOTIC CUT-POINTS  

E-Print Network [OSTI]

TWIN BUILDING LATTICES DO NOT HAVE ASYMPTOTIC CUT-POINTS PIERRE-EMMANUEL CAPRACE*, FRANÃ?OIS DAHMANI**, AND VINCENT GUIRARDEL** Abstract. We show that twin building lattices have linear divergence, which implies of asymptotic cones of twin building lattices. Theorem 1. The asymptotic cones of a twin building lattice do

Caprace, Pierre-Emmanuel

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Society of Automotive Engineers World Congress and Exposition, Detroit, MI, April, 2006 (draft) 1 MEASURING INDUSTRIAL ENERGY SAVINGS  

E-Print Network [OSTI]

Society of Automotive Engineers World Congress and Exposition, Detroit, MI, April, 2006 (draft) 1 MEASURING INDUSTRIAL ENERGY SAVINGS Kelly Kissock and Carl Eger Department of Mechanical and Aerospace Engineering University of Dayton 300 College Park Dayton, Ohio 45469-0238 Abstract This paper presents

Kissock, Kelly

42

Coupling of twin rectangular supersonic jets  

E-Print Network [OSTI]

Twin jet plumes on aircraft can couple, producing dynamic pressures significant enough to cause structural fatigue. For closely spaced jets with a moderate aspect ratio (e.g. 5), previous work has established that two ...

Raman, G.; Taghavi, Ray

1998-01-01T23:59:59.000Z

43

Asymmetric twins in rhombohedral boron carbide  

SciTech Connect (OSTI)

Superhard materials consisting of light elements have recently received considerable attention because of their ultrahigh specific strength for a wide range of applications as structural and functional materials. However, the failure mechanisms of these materials subjected to high stresses and dynamic loading remain to be poorly known. We report asymmetric twins in a complex compound, boron carbide (B{sub 4}C), characterized by spherical-aberration-corrected transmission electron microscopy. The atomic structure of boron-rich icosahedra at rhombohedral vertices and cross-linked carbon-rich atomic chains can be clearly visualized, which reveals unusual asymmetric twins with detectable strains along the twin interfaces. This study offers atomic insights into the structure of twins in a complex material and has important implications in understanding the planar defect-related failure of superhard materials under high stresses and shock loading.

Fujita, Takeshi, E-mail: tfujita@wpi-aimr.tohoku.ac.jp; Guan, Pengfei; Madhav Reddy, K.; Hirata, Akihiko; Guo, Junjie [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Chen, Mingwei, E-mail: mwchen@wpi-aimr.tohoku.ac.jp [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200030 (China)

2014-01-13T23:59:59.000Z

44

Evaluation of Fish Passage Conditions for Juvenile Salmonids Using Sensor Fish at Detroit Dam, Oregon  

SciTech Connect (OSTI)

Fish passage conditions through two spillways at Detroit Dam on the North Santiam River in Oregon were evaluated by Pacific Northwest National Laboratory for the U.S. Army Corps of Engineers (USACE), Portland District, using Sensor Fish devices. The objective of the study was to describe and compare passage exposure conditions through Spillbay 3 and Spillbay 6 at 1.5- and 3.5-ft gate openings, identifying potential fish injury regions of the routes. The study was performed in July 2009, concurrent with HI-Z balloon-tag studies by Normandeau Associates, Inc. Sensor Fish and live fish were deployed at elevations approximately 3 ft above structure at depths determined using a computational fluid dynamics model. Data collected were analyzed to estimate 1) exposure conditions, particularly exposure to severe collision and shear events by passage route sub-regions; 2) differences in passage conditions between passage routes; and 3) relationships to live-fish injury and mortality data estimates.

Duncan, Joanne P.

2010-01-29T23:59:59.000Z

45

Deformation twinning mechanisms in FCC and HCP metals  

SciTech Connect (OSTI)

We report the recent work on twinning and detwinning in fcc and hcp metals based on the in situ and ex situ TEM observations and molecular dynamics simulations. Three aspects are discussed in this paper. (1) Detwinning in single-phase Cu with respect to growth twins, (2) deformation twinning in Ag-Cu composites, and (3) deformation twinning mechanisms in hcp metals. The main conclusion is that atomic structures of interfaces (twin boundaries, two-phases interface, and grain boundaries) play a crucial role in nucleating and propagating of deformation twins.

Wang, Jian [Los Alamos National Laboratory; Tome, Carlos N [Los Alamos National Laboratory; Beyerlein, Irene J [Los Alamos National Laboratory; Misra, Amit [Los Alamos National Laboratory; Mara, N [Los Alamos National Laboratory

2011-01-31T23:59:59.000Z

46

Solar twins in M67  

E-Print Network [OSTI]

The discovery of true solar analogues is fundamental for a better understanding of the Sun and of the solar system. The open cluster M67 offers a unique opportunity to search for solar analogues because its chemical composition and age are very similar to those of the Sun. We analyze FLAMES spectra of a large number of M67 main sequence stars to identify solar analogues in this cluster.We first determine cluster members which are likely not binaries, by combining proper motions and radial velocity measurements. We concentrate our analysis on the determination of stellar effective temperature, using analyses of line-depth ratios and H$\\alpha$ wings, making a direct comparison with the solar spectrum obtained with the same instrument. We also compute the lithium abundance for all the stars.Ten stars have both the temperature derived by line-depth ratios and H$\\alpha$ wings within 100 K from the Sun. From these stars we derive, assuming a cluster reddening $E(B-V)=0.041$, the solar colour $(B-V)_\\odot=0.649\\pm0.016$ and a cluster distance modulus of 9.63. Five stars are most similar (within 60 K) to the Sun and candidates to be true solar twins. These stars have also a low Li content, comparable to the photospheric abundance of the Sun, likely indicating a similar mixing evolution. We find several candidates for the best solar analogues ever. These stars are amenable to further spectroscopic investigations and planet search. The solar colours are determined with rather high accuracy with an independent method, as well as the cluster distance modulus.

L. Pasquini; K. Biazzo; P. Bonifacio; S. Randich; L. Bedin

2008-07-01T23:59:59.000Z

47

Low-noise macroscopic twin beams  

E-Print Network [OSTI]

Applying a multiphoton-subtraction technique to two-color macroscopic squeezed vacuum state of light generated via high-gain parametric down conversion we conditionally prepare a new state of light: bright multi-mode low-noise twin beams. The obtained results demonstrate up to 8-fold suppression of noise in each beam while preserving and even moderately improving the nonclassical photon number correlations between the beams. The prepared low-noise macroscopic state, containing up to 2000 photons per mode, is not among the states achievable through nonlinear optical processes. The proposed technique substantially improves the usefulness of twin beams for quantum technologies.

Timur Sh. Iskhakov; Vladyslav C. Usenko; Radim Filip; Maria V. Chekhova; Gerd Leuchs

2014-08-27T23:59:59.000Z

48

ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried  

E-Print Network [OSTI]

. Physical properties . Protein . Twin-screw extruder Introduction As a consequence of changes in energyORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced

49

Introduction High-shear wet granulation by twin screw extrusion  

E-Print Network [OSTI]

and compaction16,17 . Wet granulation in a twin screw extruder is particularly useful with many investigates foam granulation in a twin screw extruder as a new continuous wet granulation technique drop or spray liquid addition in batch granulation. This work demonstrates a twin screw extruder

Thompson, Michael

50

1 INTRODUCTION In industrial mixing processes, as twin screw  

E-Print Network [OSTI]

the domain occupied by the fluid inside a portion of a twin screw extruder or a batch mixer. For a Newtonian-set/Hamilton-Jacobi method. Two flow case studies will be presented in this paper: the flow within a twin-screw extruder1 INTRODUCTION In industrial mixing processes, as twin screw compounding or batch mixing

Paris-Sud XI, Université de

51

Twinning effect on photoluminescence spectra of ZnSe nanowires  

SciTech Connect (OSTI)

Bandgap engineering in a single material along the axial length of nanowires may be realized by arranging periodic twinning, whose twin plane is vertical to the axial length of nanowires. In this paper, we report the effect of twin on photoluminescence of ZnSe nanowires, which refers to the bandgap of it. The exciton-related emission peaks of transverse twinning ZnSe nanowires manifest a 10-meV-blue-shift in comparison with those of longitudinal twinning ZnSe nanowires. The blue-shift is attributed to quantum confinement effect, which is influenced severely by the proportion of wurtzite ZnSe layers in ZnSe nanowires.

Xu, Jing; Wang, Chunrui, E-mail: crwang@dhu.edu.cn; Wu, Binhe; Xu, Xiaofeng [Department of Applied Physics and State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 2999 Renmin Rd. North, Songjiang District, Shanghai 201620 (China); Chen, Xiaoshuang [Department of Applied Physics and State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 2999 Renmin Rd. North, Songjiang District, Shanghai 201620 (China); National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Science, Shanghai 200083 (China); Oh, Hongseok; Baek, Hyeonjun; Yi, Gyu-Chul [Department of Physics and Astronomy, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151-747 (Korea, Republic of)

2014-11-07T23:59:59.000Z

52

Accelerated immunosenescence in preindustrial twin mothers  

E-Print Network [OSTI]

Accelerated immunosenescence in preindustrial twin mothers Samuli Helle* , Virpi Lummaa , and Jukka that this tradeoff is a result of reproductive costs accelerating senescence of the immune system, leading to earlier accelerated immunosenescence. immune function cost of reproduction longevity reproductive effort tuberculosis

Lummaa, Virpi

53

Twin Cities Regional Bicycle System Study  

E-Print Network [OSTI]

Twin Cities Regional Bicycle System Study Developing a Regional Bicycle Network CTS Research Corridors Analysis Results Proposed Regional Bicycle Network Critical Bicycle Links Next Steps Introduction #12;3 Improve knowledge base of regional bicycle transportation system and learn · How on

Minnesota, University of

54

The Detroit Diesel DELTA Engine for Light Trucks and SUVs - Year 2000 Update  

SciTech Connect (OSTI)

Detroit Diesel Corporation (DDC) is developing the DELTA 4.0L V6 engine, specifically for the North American light truck market. This market poses unique requirements for a diesel engine, necessitating a clean sheet engine design. DELTA was developed from a clean sheet of paper, with the first engine firing just 228 days later. The process began with a Quality Function Deployment (QFD) analysis, which prioritized the development criteria. The development process integrated a co-located, fully cross-functional team. Suppliers were fully integrated and maintained on-site representation. The first demonstration vehicle moved under its own power 12 weeks after the first engine fired. It was demonstrated to the automotive press 18 days later. DELTA has repeatedly demonstrated its ability to disprove historical North American diesel perceptions and compete directly with gasoline engines. This paper outlines the Generation 0.0 development process and briefly defines the engine. A brief indication of the Generation 0.5 development status is given.

Nabil S. Hakim; Charles E. Freese; Stanley P. Miller

2000-06-19T23:59:59.000Z

55

Determining chemical cleaning requirements for Detroit Edison Belle River Unit No. 1  

SciTech Connect (OSTI)

Detroit Edison's Belle river Power Plant is a two unit coal-fired installation. The drum type boilers are Carolina type and burn pulverized low sulfur western coal. Both units have a normal boiler operating pressure of 2700 psi, are rated at 650 MW net, with a boiler operating volume of 125,000 gallons. The boilers were pre-operationally chemically cleaned during start up in 1984 (Unit 1) and 1985 (Unit 2), to remove millscale and the preservative coatings. Following the vendor recommendation to chemically clean when the tube deposit weight reaches 25 g/ft{sup 2} (as determined by the solvent removal method). However, a review of tube deposit test results form Belle River Unit 1 indicated that the type of deposit found was markedly different in appearance and physical nature than deposits typically found in other Company boilers. This paper reports that based on this difference, and the conservatism of the published limit, a comprehensive evaluation of the need to chemically clean the Belle River boilers was undertaken.

Sonntag, D.J.; Palmer, R.E. (Technical and Engineering Services, Detroit Edison Co. (US))

1992-01-01T23:59:59.000Z

56

The Twin Higgs mechanism and Composite Higgs  

E-Print Network [OSTI]

We combine the Twin Higgs mechanism with the paradigm of Composite Higgs models. In this class of models the Higgs is a pseudo-Nambu-Goldstone boson from a strongly coupled sector near the TeV scale, and it is additionally protected by a discrete symmetry due to the twin mechanism. We discuss the model building issues associated with this setup and quantify the tuning needed to achieve the correct electroweak vacuum and the Higgs mass. In contrast to standard Composite Higgs models, the lightest resonance associated with the top sector is the uncolored mirror top, while the colored top partners can be made parameterically heavier without extra tuning. In some cases, the vector resonances are predicted to lie in the multi-TeV range. We present models where the resonances - both fermions and vectors - being heavier alleviates the pressure on naturalness coming from direct searches demonstrating that theories with low tuning may survive constraints from the Large Hadron Collider.

Low, Matthew; Wang, Lian-Tao

2015-01-01T23:59:59.000Z

57

Zebra Mussel control experiences at Detroit Edison Harbor Beach Power Plant  

SciTech Connect (OSTI)

The Detroit Edison Co. Harbor Beach Power Plant on Lake Huron in Michigan`s thumb and is comprised of one 100 MW coal-fired unit. Zebra mussels first were discovered during a routine inspection of the plant screen house in August 1991. The initial population of 5 mussels/m{sup 2} increased to 650 mussels/m{sup 2} by March 1992. During this eight-month period the plant began to experience problems with zebra mussels clogging small coolers, check valves, and miscellaneous service water connections. Although the mussels had not affected the unit`s availability, it was evident that they soon might if left uncontrolled. A treatment program was devised in 1992 to eliminate the mussels living in the screen house and inside the plant. Targeted in-plant systems included the condenser cooling supply lines, plant service water system, and plant fire fighting system. An oxygen scavenger (sodium sulfate) was used in conjunction with thermal treatment (saturated steam) to asphyxiate and heat the mussels over a several day period. Inspection dives in the screen house before and after treatment as well as subsequent in-plant equipment inspections have revealed the treatment to be successful. Complete mortality was achieved in the screen house and in-plant systems. By April, 1993, the zebra mussel colony had re-established itself in the plant screen house to a level of 400 mussels/m{sup 2}. In October 1993, the colony had grown to 2,600 mussels/m{sup 2}. A second treatment was scheduled and completed on October 18--21, 1993. Thermal treatment was used alone during this treatment episode in which 100% mortality again wax achieved. Test bags, an in-line viewport, and post treatment dive inspections confirmed that the treatment was completely successful. Population monitoring and treatments continue on a regular basis.

Harwood, D.B.; Buda, D.J. [Detroit Edison Co., Harbor Beach, MI (United States)

1994-12-31T23:59:59.000Z

58

A Mechanism-based Model for Deformation Twinning in Polycrystalline...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Polycrystalline FCC Steel. Abstract: Deformation twinning, a common and important plastic deformation mechanism, is the key contributor to the excellent combination of...

59

Phenomenology of the left-right twin Higgs model  

E-Print Network [OSTI]

Phenomenology of the Left-Right Twin Higgs Model* Hock-SengUniversity of California. Phenomenology of the Left-Rightwith rich collider phenomenology. In addition, there are

Goh, Hock-Seng

2008-01-01T23:59:59.000Z

60

Application for Presidential Permit OE Docket No. PP-366 Twin...  

Broader source: Energy.gov (indexed) [DOE]

transmission facilities at the U.S. - Canada Border. Application for Presidential Permit OE Docket No. PP-366 Twin Rivers Paper Company, Inc. More Documents & Publications...

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

E-Print Network 3.0 - andidentical twins discordant Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

twins discordant Page: << < 1 2 3 4 5 > >> 1 Discordance of prenatal and neonatal brain development in twins Niyati Mukherjee a Summary: Discordance of prenatal and neonatal...

62

Twin Falls District | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective:ToyoTurkey: EnergyGeothermal AreaBML Twin Falls

63

Clean Cities: Twin Cities Clean Cities coalition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationClean Communities of Western NewSouth Shore CleanSt.Tucson CleanTwin

64

HEAT BUMP MODELING IN HIGH HEAT-LOAD X-RAY OPTICS* E. Windisch IV, Wayne State, Detroit, MI, 48201, U.S.A.  

E-Print Network [OSTI]

HEAT BUMP MODELING IN HIGH HEAT-LOAD X-RAY OPTICS* E. Windisch IV, Wayne State, Detroit, MI, 48201, U.S.A. Abstract Thermal deformation in high heat load X-Ray optics limits coherence and reduces flux-equipped MATLAB program designed to calculate three dimensional energy depostion in a solid. It uses an executable

Cinabro, David

65

Education in anesthesia for nurses entered a new era in Michigan in September 1963. Nine registered nurses entered the program in anesthesia offered by Detroit Receiving  

E-Print Network [OSTI]

History Education in anesthesia for nurses entered a new era in Michigan in September 1963. Nine registered nurses entered the program in anesthesia offered by Detroit Receiving Hospital in collaborationD., the Wayne State University Nurse Anesthesia Program (WSUNAP), became the first in the country to offer

Berdichevsky, Victor

66

INTERNSHIP OPPORTUNITY PHOTOGRAPHY & EVENTS After 5 Detroit is looking for a Photo and Event Intern for Fall 2011. The internship runs  

E-Print Network [OSTI]

INTERNSHIP OPPORTUNITY ­ PHOTOGRAPHY & EVENTS After 5 Detroit is looking for a Photo and Event Intern for Fall 2011. The internship runs from the beginning of May until the end of August. It is an unpaid internship but our past interns have generally earned college credits for their work. After 5

Cinabro, David

67

Lynne Ellyn is the senior vice president and chief information officer at DTE Energy (NYSE: DTE), a Detroit-based diversified energy company involved in the development and  

E-Print Network [OSTI]

Health System Foundation, the Henry Ford Health System Quality Committee, and the DTE Energy Charitable: DTE), a Detroit-based diversified energy company involved in the development and management of energy of Management in Information Technology Advisory Board. She serves on the board of trustees of the Henry Ford

68

Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems  

E-Print Network [OSTI]

Advance View Proofs Thermodynamic Description of the Mg-Mn, Al-Mn and Mg-Al-Mn Systems Using-consistent thermodynamic model of the Mg-Mn, Al-Mn and Mg-Al-Mn systems has been developed. The major difference between work on the Al-Mn system that uses the same model for the liquid phase reveals that better agreement

Medraj, Mamoun

69

On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002 WholesaleEnergy's 1000 acres of landJune 2013 The

70

Hydroacoustic Evaluation of Juvenile Salmonid Passage and Distribution at Detroit Dam, 2011  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory evaluated juvenile salmonid passage and distribution at Detroit Dam (DET) on the North Santiam River, Oregon for the U.S. Army Corps of Engineers (USACE) to provide data to support decisions on long-term measures to enhance downstream passage at DET and others dams in USACE’s Willamette Valley Project. This study was conducted in response to regulatory requirements necessitated by the listing of Upper Willamette River Spring Chinook salmon (Oncorhynchus tshawytscha) and Upper Willamette River steelhead (O. mykiss) as threatened under the Endangered Species Act. The goal of the study was to provide information of juvenile salmonid passage and distribution at DET from February 2011 through February 2012. The results of the hydroacoustic study provide new and, in some cases, first-ever data on passage estimates, run timing, distributions, and relationships between fish passage and environmental variables at the dam. This information will inform management decisions on the design and development of surface passage and collection devices to help restore Chinook salmon populations in the North Santiam River watershed above DET. During the entire study period, an estimated total of 182,526 smolt-size fish (±4,660 fish, 95% CI) passed through turbine penstock intakes. Run timing peaked in winter and early spring months. Passage rates were highest during late fall, winter and early spring months and low during summer. Horizontal distribution for hours when both turbine units were operated simultaneously indicated Unit 2 passed almost twice as much fish as Unit 1. Diel distribution for smolt-size fish during the study period was fairly uniform, indicating fish were passing the turbines at all times of the day. A total of 5,083 smolt-size fish (± 312 fish, 95% CI) were estimated passed via the spillway when it was open between June 23 and September 27, 2011. Daily passage was low at the spillway during the June-August period, and increased somewhat in September 2011. When the spillway was operated simultaneously with the turbines, spillway efficiency (efficiency is estimated as spillway passage divided by total project passage) was 0.72 and effectiveness (fish:flow ratio—proportion fish passage at a route (e.g., spillway) divided by proportion water through that route out of the total project) was 2.69. That is, when the spillway was open, 72% of the fish passing the dam used the spillway and 28% passed into the turbine penstocks. Diel distribution for smolt-size fish at the spillway shows a distinct peak in passage between mid-morning and mid-afternoon and low passage at night. We estimated that 23,339 smolt-size fish (± 572 fish, 95% CI) passed via the Regulating Outlet (RO) when it was open from October 29 through November 12, 2011, January 2-6, and January 20 through February 3, 2012. During the October–November period, RO passage peaked at 1,086 fish on November 5, with a second peak on November 7 (1,075 fish). When the RO was operated simultaneously with the turbines, RO efficiency was 0.33 and effectiveness was 0.89. In multiple regression analyses, a relatively parsimonious model was selected that predicted the observed fish passage data well. The best model included forebay temperature at depth, forebay elevation, total discharge, hours of daylight, and the operation period. The vertical distribution of fish in the forebay near the face of the dam where the transducers sampled showed fish were generally distributed throughout the water column during all four operational periods. During the refill and full pool periods, vertical distribution was bi-modal with surface-layer and mid-water modes. Patterns for day and night distributions were variable. Fish were distributed above and below the thermocline when it was present (full pool and drawdown periods).

Khan, Fenton; Royer, Ida M.; Johnson, Gary E.; Ham, Kenneth D.

2012-11-15T23:59:59.000Z

71

Two wide-angle imaging neutral-atom spectrometers (TWINS)  

SciTech Connect (OSTI)

Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) is a revolutionary new mission designed to stereoscopically image the magnetosphere in charge exchange neutral atoms for the first time. The authors propose to fly two identical TWINS instruments as a mission of opportunity on two widely-spaced high-altitude, high-inclination US Government spacecraft. Because the spacecraft are funded independently, TWINS can provide a vast quantity of high priority science observations (as identified in an ongoing new missions concept study and the Sun-Earth Connections Roadmap) at a small fraction of the cost of a dedicated mission. Because stereo observations of the near-Earth space environs will provide a particularly graphic means for visualizing the magnetosphere in action, and because of the dedication and commitment of the investigator team to the principles of carrying space science to the broader audience, TWINS will also be an outstanding tool for public education and outreach.

McComas, D.J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Blake, B. [Aerospace Corp., CA (United States)] [Aerospace Corp., CA (United States); Burch, J. [Southwest Research Inst., San Antonio, TX (United States)] [and others] [Southwest Research Inst., San Antonio, TX (United States); and others

1998-11-01T23:59:59.000Z

72

Wet-gas compression in twin-screw multiphase pumps  

E-Print Network [OSTI]

encountered when operating under conditions with high gas volume fractions (GVF). Twin-screw multiphase pumps experience a severe decrease in efficiency when operating under wet-gas conditions, GVF over 95%. Field operations have revealed severe vibration...

Chan, Evan

2009-05-15T23:59:59.000Z

73

Influence of shockwave obliquity on deformation twin formation in Ta  

SciTech Connect (OSTI)

Energetic loading subjects a material to a 'Taylor wave' (triangular wave) loading profile that experiences an evolving balance of hydrostatic (spherical) and deviatoric stresses. While much has been learned over the past five decades concerning the propensity of deformation twinning in samples shockloaded using 'square-topped' profiles as a function of peak stress, achieved most commonly via flyer plate loading, less is known concerning twinning propensity during non-I-dimensional sweeping detonation wave loading. Systematic small-scale energetically-driven shock loading experiments were conducted on Ta samples shock loaded with PEFN that was edge detonated. Deformation twinning was quantified in post-mortem samples as a function of detonation geometry and radial position. In the edge detonated loading geometry examined in this paper, the average volume fraction of deformation twins was observed to drastically increase with increasing shock obliquity. The results of this study are discussed in light of the formation mechanisms of deformation twins, previous literature studies of twinning in shocked materials, and modeling of the effects of shock obliquity on the evolution of the stress tensor during shock loading.

Gray, George T., III [Los Alamos National Laboratory; Livescu, V [Los Alamos National Laboratory; Cerreta, E K [Los Alamos National Laboratory; Mason, T A [Los Alamos National Laboratory; Maudlin, P J [RETIRED; Bingert, J F [Los Alamos National Laboratory

2009-02-18T23:59:59.000Z

74

Determining the Appropriate Package and Transportation Methodology for the Detroit Edison, Fermi II Msrs and Associated Components  

SciTech Connect (OSTI)

During the spring of 2005, Detroit Edison, Enrico Fermi II Nuclear Power Station (Fermi) decided to disposition two MSRs and associated components scheduled for replacement in the spring of 2006 during the MSR Replacement Outage. Of concern to Fermi was the proper packaging and transportation methodology when dis-positioning a component measuring approximately 110' in length and 13' in diameter and weighing over 300 tons. Upon removal from the Turbine Deck the retired MSRs and associated components were turned over to the Rad Waste Group for packaging and final disposition. Fermi requested quotations from vendors to package, transport, and disposition the MSRs and associated components. However, multiple Vendors informed Fermi that the size and weight of the MSRs were questionable in passing permitting requirements and would require segmentation and volume reduction on site or at a waste processor. Fermi contracted with MHF Logistical Solutions (MHF-LS) based on their ability to receive clearances for shipping the MSRs in one piece via two heavy haul rail conveyances acting as a bolstered load with professionally engineered blocking and bracing configured to support the retired MSRs. (authors)

Weber, B. [Detroit Edison Company/Enrico Fermi II Nuclear Power Station, Newport, MI (United States); Dempsey, S. [MHF Logistical Solutions, Oak Ridge, TN (United States)

2007-07-01T23:59:59.000Z

75

Application to Export Electric Energy OE Docket No. EA-358 Twin...  

Broader source: Energy.gov (indexed) [DOE]

Twin Cities Energy, LLC to export electric energy to Canada Application to Export Electric Energy OE Docket No, EA-358 Twin Cities Energy, LLC More Documents & Publications EA-358...

76

September 7, 2009 Thank you for your recent critique of our Twin Lakes Enhancement Proposal (#2008-  

E-Print Network [OSTI]

recycling. Summertime "habitat squeeze" was clearly identified as the primary limitation for salmonids in Twin Lakes. These studies led to the construction of the oxygenation system in North Twin in 2008 which

77

On existence of infinite primes and infinite twin primes  

E-Print Network [OSTI]

The twin primes conjecture is a very old problem. Tacitly it is supposed that the primes it deals with are finite. In the present paper we consider three problems that are not related to finite primes but deal with infinite integers. The main tool of our investigation is a numeral system proposed recently that allows one to express various infinities and infinitesimals easily and by a finite number of symbols. The problems under consideration are the following and for all of them we give affermative answers: (i) do infinite primes exist? (ii) do infinite twin primes exist? (ii) is the set of infinite twin primes infinite? Examples of these three kinds of objects are given.

Maurice Margenstern; Yaroslav D. Sergeyev

2015-01-08T23:59:59.000Z

78

Final Project Report - ARM CLASIC CIRPAS Twin Otter Aerosol  

SciTech Connect (OSTI)

The NOAA/ESRL/GMD aerosol group made three types of contributions related to airborne measurements of aerosol light scattering and absorption for the Cloud and Land Surface Interaction Campaign (CLASIC) in June 2007 on the Twin Otter research airplane operated by the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS). GMD scientists served as the instrument mentor for the integrating nephelometer and particle soot absorption photometer (PSAP) on the Twin Otter during CLASIC, and were responsible for (1) instrument checks/comparisons; (2) instrument trouble shooting/repair; and (3) data quality control (QC) and submittal to the archive.

John A. Ogren

2010-04-05T23:59:59.000Z

79

Phenomenology of The Left-Right Twin Higgs Model  

E-Print Network [OSTI]

The twin Higgs mechanism has recently been proposed to solve the little hierarchy problem. We study the implementation of the twin Higgs mechanism in left-right models. At TeV scale, heavy quark and gauge bosons appear, with rich collider phenomenology. In addition, there are extra Higgses, some of which couple to both the Standard Model fermion sector and the gauge sector, while others couple to the gauge bosons only. We present the particle spectrum, and study the general features of the collider phenomenology of this class of model at the Large Hadron Collider.

Hock-Seng Goh; Shufang Su

2007-04-30T23:59:59.000Z

80

On the role of twinning in solid-state reactions  

SciTech Connect (OSTI)

A new concept of the role of twinning in processes of plastic deformation is proposed which suggests mechanical twinning to be the main mechanism of solid-state reactions under the deformation mixing of components, in particular, the grinding of aluminum oxide (Al{sub 2}O{sub 3}) and yttrium oxide (Y{sub 2}O{sub 3}) powders, as a result of which yttrium-aluminum garnet (Y{sub 3}Al{sub 5}O{sub 12}) particles are formed.

Akchurin, M. Sh., E-mail: akchurin@ns.crys.ras.ru; Zakalyukin, R. M. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

2013-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Twin Falls, Idaho: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective:ToyoTurkey: EnergyGeothermal AreaBML TwinTwin

82

Examining the mechanics of granulation with a hot melt binder in a twin-screw extruder  

E-Print Network [OSTI]

Examining the mechanics of granulation with a hot melt binder in a twin-screw extruder B. Mu, M processing Melt agglomeration Twin screw extruder a b s t r a c t Hot melt granulation involves particle-rotating intermeshing twin screw extruder for operating temperatures between 80 1C and 120 1C. Three different screw

Thompson, Michael

83

American Recovery and Reinvestment Act ( ARRA) FEMP Technical Assistance, U.S. General Services Administration - Project 194 U.S. Custom Cargo Inspection Facility, Detroit, MI  

SciTech Connect (OSTI)

This report documents the findings of an on-site audit of the U.S. Customs Cargo Inspection Facility (CIF) in Detroit, Michigan. The federal landlord for this building is the General Services Administration (GSA). The focus of the audit was to identify various no-cost or low-cost energy-efficiency opportunities that, once implemented, would reduce electrical and gas consumption and increase the operational efficiency of the building. This audit also provided an opportunity to identify potential capital cost projects that should be considered in the future to acquire additional energy (electric and gas) and water savings to further increase the operational efficiency of the building.

Arends, J.; Sandusky, William F.

2010-05-31T23:59:59.000Z

84

Comparative study of nonclassicality, entanglement, and dimensionality of multimode noisy twin beams  

E-Print Network [OSTI]

Nonclassicality, entanglement, as well as dimensionality of a noisy twin beam are determined using characteristic function of the beam written in the Fock basis. One-to-one correspondence between the negativity quantifying entanglement and the nonclassicality depth is revealed. Twin beams, which are either entangled or nonclassical (independent of their entanglement), are observed only for the limited degrees of noise that degrades their quantumness. Dimensionality of the twin beam quantified by the participation ratio is compared with the dimensionality of entanglement determined from the negativity. The partition of the degrees of freedom of the twin beam into those related to entanglement and to noise is suggested. Both single-mode and multimode twin beams are analyzed. Weak nonclassicality based on integrated-intensity quasidistributions of multimode twin beams is studied. Relation of the model to the experimental twin beams is discussed.

I. I. Arkhipov; J. Perina Jr.; J. Perina; A. Miranowicz

2015-01-21T23:59:59.000Z

85

Structure and magnetic properties of rf thermally plasma synthesized Mn and MnZn ferrite nanoparticles  

E-Print Network [OSTI]

Structure and magnetic properties of rf thermally plasma synthesized Mn and Mn­Zn ferrite has previously been shown to be a viable route to producing nanocrystalline magnetite and Ni ferrite nanoparticles. In this work nanocrystalline powders of Mn and Mn­Zn ferrites have been synthesized using a 50 k

McHenry, Michael E.

86

Temperature-induced martensite in magnetic shape memory Fe{sub 2}MnGa observed by photoemission electron microscopy  

SciTech Connect (OSTI)

The magnetic domain structure in single crystals of a Heusler shape memory compound near the composition Fe{sub 2}MnGa was observed during phase transition by photoelectron emission microscopy at Beamline 11.0.1.1 of the Advanced Light Source. The behavior is comparable with recent observations of an adaptive martensite phase in prototype Ni{sub 2}MnGa, although the pinning in the recent work is an epitaxial interface and in this work the e#11;ective pinning plane is a boundary between martensitic variants that transform in a self-accommodating way from the single crystal austenite phase present at high temperatures. Temperature dependent observations of the twinning structure give information as to the coupling behavior between the magnetism and the structural evolution.

Jenkins, Catherine; Scholl, Andreas; Kainuma, R.; Elmers, Hans-Joachim; Omori, Toshihiro

2012-01-18T23:59:59.000Z

87

Characterization of Fish Passage Conditions through a Francis Turbine, Spillway, and Regulating Outlet at Detroit Dam, Oregon, Using Sensor Fish, 2009  

SciTech Connect (OSTI)

Fish passage conditions through two spillways, a Francis turbine, and a regulating outlet (RO) at Detroit Dam on the North Santiam River in Oregon were evaluated by Pacific Northwest National Laboratory for the U.S. Army Corps of Engineers (USACE), Portland District, using Sensor Fish devices. The objective of the study was to describe and compare passage exposure conditions, identifying potential fish injury regions within the routes. The study was performed in July, October, and December 2009 concurrent with HI-Z balloon-tag studies by Normandeau Associates, Inc. Sensor Fish data were analyzed to estimate 1) exposure conditions, particularly exposure to severe strike, collision, and shear events by passage route sub-regions; 2) differences in passage conditions between passage routes; and 3) relationships to live-fish injury and mortality data estimates. Comparison of the three passage routes evaluated at Detroit Dam indicates that the RO passage route through the 5-ft gate opening was relatively the safest route for fish passage under the operating conditions tested; turbine passage was the most deleterious. These observations were supported also by the survival and malady estimates obtained from live-fish testing. Injury rates were highest for turbine and spillway passage. However, none of the passage routes tested is safe for juvenile salmonid passage.

Duncan, Joanne P.; Carlson, Thomas J.

2011-05-06T23:59:59.000Z

88

Lake Survey DETROIT, MICH.  

E-Print Network [OSTI]

. DEPARTMENT OF' COMMERCE National Ouanic and Atmospheric Admlnl,trltion National OeUII SUI"II, Great Lakes Ice ................. .... ............. . $l'.iUllary ice charts ..............·.......·................. Area ice charts - winter 1971-72 ......... . ,, Table Tabl e l.--Ice 2.--Key to ice chart sy

89

E-Print Network 3.0 - adolescent twin pairs Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sample search results for: adolescent twin pairs Page: << < 1 2 3 4 5 > >> 1 Genes, Brain and Behavior (2009) 8: 107113 2009 The Authors Journal compilation 2009 Blackwell...

90

Low-Cost Magnesium Sheet Production using the Twin Roll Casting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

using the Twin Roll Casting Process and Asymmetric Rolling 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

91

Sedimentology and Holocene stratigraphy of a carbonate mangrove buildup, Twin Cays, Belize, Central America  

E-Print Network [OSTI]

surface sediment sample Clusters 1 and 2. . Twin Cays surface sediment sample Clusters 3 and 4. . Twin Cays surface sediment sample Clusters 5 and 6. . Twin Cays surface sediment sample Clusters 7 and 8. . Twin Cays surface sediment sample Cluster 9...: 1A, 18, 1C, 3, 5, 6, 8, 9, 10, 11, 15, and 17. . . . . . . . . . . . . . 58 LIST OF FIGURES (continued) FIGURE PAGE 16 East to west cross section drawn based upon description of the sediment contained in the cores: 2, 4, 7, 8, 9, 12, 13 and 14. 60...

Bond, Gregor Benton

1988-01-01T23:59:59.000Z

92

Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes  

SciTech Connect (OSTI)

Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

2009-05-28T23:59:59.000Z

93

EA-344-A Twin Cities Power | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: TopEnergy DOEDealingVehicle1 Closing American Electric0-A S.A.C.94-A Twin

94

EA-358 Twin Cities Energy, LLC | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: TopEnergy DOEDealingVehicle1 Closing American Electric0-A S.A.C.94-A-B18 Twin

95

PP-366 Twin Rivers Paper Company, Inc. | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15, 2010Energy6 Frontera Generation Limited15 Trico Electric26 Twin

96

Twin Falls, Idaho: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective:ToyoTurkey: EnergyGeothermal AreaBML Twin

97

Twin Groves II (08) Wind Farm | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective:ToyoTurkey: EnergyGeothermal AreaBMLII (07)Twin

98

Fermilab Today | University of Minnesota - Twin Cities Profile  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibility ofSmall Works:Oklahomaat Chicago May 16,Maryland- Twin

99

Twin Valley Electric Coop Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectric Coop, IncTipmontInformationKentucky)Bank,Turkmenistan:Pwr AssnTwin

100

Ramp meters on trial: Evidence from the Twin Cities metering holiday  

E-Print Network [OSTI]

Ramp meters on trial: Evidence from the Twin Cities metering holiday David Levinson a,*, Lei Zhang; accepted 15 December 2004 Abstract Ramp meters in the Twin Cities have been the subject of a recent test metering for several representative freeways during the afternoon peak period. Seven performance measures

Levinson, David M.

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

EVALUATING EFFECTIVENESS OF RAMP Evidence from the twin cities ramp meter shut-off  

E-Print Network [OSTI]

Chapter 9 EVALUATING EFFECTIVENESS OF RAMP METERS Evidence from the twin cities ramp meter shut-625-6354 Abstract: Ramp meters in the Twin Cities have been turned off for eight weeks in Fall 2000 in an experiment representative freeways during the afternoon peak period. Several performance measures for ramp metering

Levinson, David M.

102

Discordance of Prenatal and Neonatal Brain Development in Twins Niyati Mukherjee1  

E-Print Network [OSTI]

neonatal discordance of head and brain size, and the role that zygosity and chorionicity play in discordances of early brain development in twins. Aims: To compare prenatal and neonatal discordances of headDiscordance of Prenatal and Neonatal Brain Development in Twins Niyati Mukherjee1 , Chaeryon Kang1

Utah, University of

103

Discordance of prenatal and neonatal brain development in twins Niyati Mukherjee a  

E-Print Network [OSTI]

about prenatal and early neonatal discordance of head and brain size, and the role that zygosityDiscordance of prenatal and neonatal brain development in twins Niyati Mukherjee a , Chaeryon Kang and chorionicity play in discordances of early brain development in twins. Aims: To compare prenatal and neonatal

Utah, University of

104

Understanding wet granulation in the kneading block of twin screw extruders  

E-Print Network [OSTI]

Understanding wet granulation in the kneading block of twin screw extruders H. Li a,1 , M done in a 27 mm twin screw extruder with different powder formulations consisting of lactose H I G H L I G H T S In situ examination of granule development inside extruder. Granule based

Thompson, Michael

105

STATISTICS OF MIXING DISTRIBUTIONS IN FILLED ELASTOMERS PROCESSED BY TWIN SCREW EXTRUSION  

E-Print Network [OSTI]

screw extruder under controlled extruder geometry, order of ingredient addition and die pressurizationC. This formulation was twin screw extruded using an annular die with a star-shaped mandrel (see Fig.1). Three controlSTATISTICS OF MIXING DISTRIBUTIONS IN FILLED ELASTOMERS PROCESSED BY TWIN SCREW EXTRUSION Elvan

106

Wet Granulation in a Twin-Screw Extruder: Implications of Screw Design  

E-Print Network [OSTI]

Wet Granulation in a Twin-Screw Extruder: Implications of Screw Design M.R. THOMPSON, J. SUN MMRI of auxiliary units like feeders and pumps. In comparison, single-screw variants of an extruder have received granulation in twin-screw extrusion machinery is an attractive tech- nology for the continuous processing

Thompson, Michael

107

Acoustic attenuation due to transformation twins in CaCl2: Analogue behaviour for stishovite  

E-Print Network [OSTI]

Acoustic attenuation due to transformation twins in CaCl2: Analogue behaviour for stishovite: Pseudoproper ferroelastic phase transition Ferroelastic twin walls Stishovite CaCl2 Acoustic attenuation a b s t r a c t CaCl2 undergoes a tetragonal (P42/mnm) to orthorhombic (Pnnm) transition as a function

Cambridge, University of

108

Developing a Model for Car Sharing Potential in Twin Cities Neighborhoods James Andrew  

E-Print Network [OSTI]

Developing a Model for Car Sharing Potential in Twin Cities Neighborhoods James Andrew Masters neighborhoods in the Twin Cities of Minneapolis and St. Paul, Minnesota for their amenability to car sharing, a study of the market and use of car sharing programs in the United States was conducted through

Levinson, David M.

109

First-principles calculations of twin-boundary and stacking-fault energies in magnesium  

E-Print Network [OSTI]

First-principles calculations of twin-boundary and stacking-fault energies in magnesium Y. Wang and stacking faults in metal magnesium have been calculated using first-principles supercell approach. Four. Keywords: Magnesium; Interfaces; Twinning; First-principles calculation Magnesium alloys are increasingly

Chen, Long-Qing

110

Structure and motion of junctions between coherent and incoherent twin boundaries in copper  

E-Print Network [OSTI]

Structure and motion of junctions between coherent and incoherent twin boundaries in copper J online 4 July 2009 Abstract The atomic mechanisms of twin boundary migration in copper under externally. Ã? 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. Keywords: Copper

Ghoniem, Nasr M.

111

THE ECONOMIC IMPACT OF A TERRORIST ATTACK ON THE TWIN PORTS OF LOS  

E-Print Network [OSTI]

THE ECONOMIC IMPACT OF A TERRORIST ATTACK ON THE TWIN PORTS OF LOS ANGELES-LONG BEACH Gordon, P.usc.edu/create Report #05-012DRAFT #12;THE ECONOMIC IMPACT OF A TERRORIST ATTACK ON THE TWIN PORTS OF LOS ANGELES International Airport (LAX), downtown high-rises, its theme parks, its freeways, and its ports, among many

Wang, Hai

112

Mesh immersion technique for 3D moving domain calculation and applications to twin-screw extrusion and mixing  

E-Print Network [OSTI]

in a complex system such as a twin screw extruder or a batch mixer, including moving free surfaces. 1 Fluid, the domain occupied by the fluid inside a portion of a twin screw extruder. The velocity- pressure (u to a twin screw extrud

Paris-Sud XI, Université de

113

Dynamic modeling of the reactive twin-screw co-rotating extrusion process: experimental validation by using inlet  

E-Print Network [OSTI]

and modification.1 The co-rotating twin-screw extruder is of particular interest due to its modular geometry or removing chemical species.3,4 Furthermore, the co-rotating twin-screw extruder can handle high viscosityDynamic modeling of the reactive twin-screw co-rotating extrusion process: experimental validation

Paris-Sud XI, Université de

114

Effect of Mn doping on the structural, morphological, optical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mn doping on the structural, morphological, optical and magnetic properties of indium tin oxide films. Effect of Mn doping on the structural, morphological, optical and magnetic...

115

Twin-screw tanker designed for high efficiency  

SciTech Connect (OSTI)

In late 1994, the Ching Fu shipyard in Taiwan delivered a chemical tanker to Fram Shipping, for operations around Northern Europe for Norsk Hydro. The 13000 dwt tanker design is optimized to have the lowest possible operational cost for the given dead-weight capacity. Waertsilae Propulsion has from an early stage contributed to the development of the propulsion system. The company proposed the Waertsilae Propac concept, including the hydrodynamic design and the supply of the main components. The propeller was designed using in-house computer programs, and the results confirmed by model tests, both at Danish Maritime Institute (DMI) in Copenhagen, and at SSPA Maritime Consulting in Gothenburg. The hull form for the tanker was optimized by a special bulb design to reduce the wave resistance. The vessel is also designed with a special twin skeg arrangement in the stern. This solution allows for two large and efficient propellers to be installed.

NONE

1995-11-01T23:59:59.000Z

116

Heterologous protein production using the twin arginine translocation pathway  

DOE Patents [OSTI]

Provided are means for evaluating and identifying putative substrates of the twin arginine translocation (Tat) secretory pathway in Streptomyces and other bacterial species. Also provided, therefore, are simple ways to express, secrete and purify correctly folded heterologous proteins on a large scale using host microorganisms, such as, Streptomyces and the Tat pathway therein. Many of the thus-produced proteins are of significant therapeutic value in the pharmaceutical and biochemical industries, particularly when they can be secreted from the host in fully-folded active form. Accordingly, there are further provided the heterologous proteins produced by the Tat secretion pathway using the foregoing methods, and the computer algorithm used to identify the Tat signal sequence and putative substrates.

Pohlschroder, Mechtild (Philadelphia, PA); Kissinger, Jessica C (Athens, GA); Rose, R. Wesley (Glenside, PA); Brueser, Thomas (Halle, DE); Dilks, Kieran (Collingswood, NJ)

2008-11-04T23:59:59.000Z

117

IMPROVEMENT OF CdMnTe DETECTOR PERFORMANCE BY MnTe PURIFICATION  

SciTech Connect (OSTI)

Residual impurities in manganese (Mn) are a big obstacle to obtaining high-performance CdMnTe (CMT) X-ray and gamma-ray detectors. Generally, the zone-refining method is an effective way to improve the material's purity. In this work, we purified the MnTe compounds combining the zone-refining method with molten Te, which has a very high solubility for most impurities. We confirmed the improved purity of the material by glow-discharge mass spectrometry (GDMS). We also found that CMT crystals from a multiply-refined MnTe source, grown by the vertical Bridgman method, yielded better performing detectors.

Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Tappero, R.; Hossain, A.; Cui, Y.; Yang, G.; Gul, R.; and James, R.B.

2011-04-25T23:59:59.000Z

118

Mn/DOT County Road Safety Plans  

E-Print Network [OSTI]

Roads Program !! Minnesota Central Safety Funds !! Foster safety culture among county stakeholders 41 Mn/DOT County Road Safety Plans CTS Annual Research Conference April 27 & 28, 2010 Howard Preston & Objectives !! Project Overview !! Schedule, Participating Counties, Approach !! Safety Emphasis Areas

Minnesota, University of

119

Genome, Epigenome and RNA sequences of Monozygotic Twins Discordant for Multiple Sclerosis  

SciTech Connect (OSTI)

Neil Miller, Deputy Director of Software Engineering at the National Center for Genome Resources, discusses a monozygotic twin study on June 2, 2010 at the "Sequencing, Finishing, Analysis in the Future" meeting in Santa Fe, NM

Miller, Neil [National Center for Genome Resources

2010-06-02T23:59:59.000Z

120

Modeling of wet gas compression in twin-screw multiphase pump  

E-Print Network [OSTI]

Twin-screw multiphase pumps experience a severe decrease in efficiency, even the breakdown of pumping function, when operating under wet gas conditions. Additionally, field operations have revealed significant vibration and thermal issues which can...

Xu, Jian

2009-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Nanostructured Ni-Co Alloys with Tailorable Grain Size and Twin Density  

E-Print Network [OSTI]

grain sizes and twin densities in the Ni-Co binary system. Using electrodeposition with various applied nanocrystalline nickel. I. INTRODUCTION BULK nanocrystalline materials are characterized by a large volume

Ferreira, Paulo J.

122

In 2011, the University of Minnesota's Twin Cities Sustainability Committee developed a campus climate  

E-Print Network [OSTI]

Benefits In 2011, the University of Minnesota's Twin Cities Sustainability Committee developed' Climate Commitment and to implement University of Minnesota sustainability goals. The CAP identifies neutrality by 2050. The Sustainability Committee, a standing body charged by the president

Webb, Peter

123

Design and Construction of a High Pressure System for Evaluating Multiphase Twin-Screw Pumps  

E-Print Network [OSTI]

Twin-screw pumps are currently sold by manufacturers without adequate data predicting the pump behavior when pumping multiphase mixtures. In light of the fact that pump behavior is known to change significantly under these conditions, a new closed...

Hatch, Theodore Isaac

2013-08-26T23:59:59.000Z

124

Performance Evaluation and CFD Simulation of Multiphase Twin-Screw Pumps  

E-Print Network [OSTI]

Twin-screw pumps are economical alternatives to the conventional multiphase system and are increasingly used in the oil and gas industry due to their versatility in transferring the multiphase mixture with varying Gas Void Fraction (GVF). Present...

Patil, Abhay

2013-05-16T23:59:59.000Z

125

Off-design performance characteristics of a twin shaft gas turbine engine with regeneration  

E-Print Network [OSTI]

OFF-DESIGN PERFORMANCE CHARACTERISTICS OF A TWIN SHAFT GAS TURBINE ENGINE WITH RECTION A 'Ihesis TODD STEWART LECKIE Submitted to the Graduate College Texas ABM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1984 Major Subject: Mechanical Engineering OFF-DESIGN PERFORMANCE CHARACTERISTICS OF A TWIN SHAFT GAS TURBINE ENGINE WITH REGENERATION A Thesis by Approved as to style and content by: er E. J 'ns rrman of Corrmittee) Je- 'n Han...

Leckie, Todd Stewart

1984-01-01T23:59:59.000Z

126

Instrumentation of a light twin aircraft for flow energizer flight tests  

E-Print Network [OSTI]

INSTRUMDITATION OF A LIGHT TWIN AIRCRAFT FOR FLOW ENERGIZER FLIGHT TESTS A Thesis by ROBERT SUSUMU BINFORD Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of HASTER... OF SCIENCE August 1986 MaJor SubJect: Aerospace Engineering INSTRUMENTATION OF A LIGHT TWIN AIRCRAFT FOR FLOW ENERGIZER FLIGHT TESTS A Thesis by ROBERT SUSUMU BINFORD Approved as to style and content by: Donald T. Ward (Chairman of Committee) Cyrus...

Binford, Robert Susumu

1986-01-01T23:59:59.000Z

127

THE FUTURE OF THE SUN: AN EVOLVED SOLAR TWIN REVEALED BY CoRoT  

SciTech Connect (OSTI)

The question of whether the Sun is peculiar within the class of solar-type stars has been the subject of active investigation over the past three decades. Although several solar twins have been found with stellar parameters similar to those of the Sun (albeit in a range of Li abundances and with somewhat different compositions), their rotation periods are unknown, except for 18 Sco, which is younger than the Sun and with a rotation period shorter than solar. It is difficult to obtain rotation periods for stars of solar age from ground-based observations, as a low-activity level implies a shallow rotational modulation of their light curves. CoRoT has provided space-based long time series from which the rotation periods of solar twins as old as the Sun could be estimated. Based on high-signal-to-noise, high-resolution spectroscopic observations gathered at the Subaru Telescope, we show that the star CoRoT ID 102684698 is a somewhat evolved solar twin with a low Li abundance. Its rotation period is 29 {+-} 5 days, compatible with its age (6.7 Gyr) and low lithium content, A{sub Li} {approx}< 0.85 dex. Interestingly, our CoRoT solar twin seems to have enhanced abundances of the refractory elements with respect to the Sun, a typical characteristic of most nearby twins. With a magnitude V {approx_equal} 14.1, ID 102684698 is the first solar twin revealed by CoRoT, the farthest field solar twin so far known, and the only solar twin older than the Sun for which a rotation period has been determined.

Do Nascimento, J.-D. Jr.; Da Costa, J. S.; Castro, M. [Departamento de Fisica Teorica e Experimental (DFTE), Universidade Federal do Rio Grande do Norte (UFRN), CP 1641, 59072-970 Natal, RN (Brazil); Takeda, Y. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Melendez, J. [Departamento de Astronomia do IAG/USP, Universidade de Sao Paulo, Rua do Matao 1226, 05508-900 Sao Paulo, SP (Brazil); Porto de Mello, G. F., E-mail: dias@dfte.ufrn.br [Observatrio do Valongo, UFRJ, Ladeira do Pedro Antonio 43, 20080-090 Rio de Janeiro, RJ (Brazil)

2013-07-10T23:59:59.000Z

128

High Mn austenitic stainless steel  

DOE Patents [OSTI]

An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

2010-07-13T23:59:59.000Z

129

Creating a single twin boundary between two CdTe (111) wafers with controlled rotation angle by wafer bonding  

SciTech Connect (OSTI)

The single twin boundary with crystallographic orientation relationship (1{sup ¯}1{sup ¯}1{sup ¯})//(111) [01{sup ¯}1]//[011{sup ¯}] was created by wafer bonding. Electron diffraction patterns and high-resolution transmission electron microscopy images demonstrated the well control of the rotation angle between the bonded pair. At the twin boundary, one unit of wurtzite structure was found between two zinc-blende matrices. High-angle annular dark-field scanning transmission electron microscopy images showed Cd- and Te-terminated for the two bonded portions, respectively. The I-V curve across the twin boundary showed increasingly nonlinear behavior, indicating a potential barrier at the bonded twin boundary.

Sun, Ce; Lu, Ning; Wang, Jinguo; Lee, Jihyung; Peng, Xin; Kim, Moon J., E-mail: moonkim@utdallas.edu [Department of Materials Science and Engineering, The University of Texas at Dallas, Richardson, Texas 75080 (United States); Klie, Robert F. [Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607 (United States)] [Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607 (United States)

2013-12-16T23:59:59.000Z

130

Energy absorption in Ni-Mn-Ga/ polymer composites  

E-Print Network [OSTI]

In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

Feuchtwanger, Jorge

2006-01-01T23:59:59.000Z

131

Mechanistic Selection and Growth of Twinned Bicrystalline Primary Si in Near Eutectic Al-Si Alloys  

SciTech Connect (OSTI)

Morphological evolution and selection of angular primary silicon is investigated in near-eutectic Al-Si alloys. Angular silicon arrays are grown directionally in a Bridgman furnace at velocities in the regime of 10{sup -3} m/sec and with a temperature gradient of 7.5 x 10{sup 3} K/m. Under these conditions, the primary Si phase grows as an array of twinned bicrystalline dendrites, where the twinning gives rise to a characteristic 8-pointed star-shaped primary morphology. While this primary Si remains largely faceted at the growth front, a complex structure of coherent symmetric twin boundaries enables various adjustment mechanisms which operate to optimize the characteristic spacings within the primary array. In the work presented here, this primary silicon growth morphology is examined in detail. In particular, this thesis describes the investigation of: (1) morphological selection of the twinned bicrystalline primary starshape morphology; (2) primary array behavior, including the lateral propagation of the starshape grains and the associated evolution of a strong <100> texture; (3) the detailed structure of the 8-pointed star-shaped primary morphology, including the twin boundary configuration within the central core; (4) the mechanisms of lateral propagation and spacing adjustment during array evolution; and (5) the thermosolutal conditions (i.e. operating state) at the primary growth front, including composition and phase fraction in the vicinity of the primary tip.

Choonho Jung

2006-12-12T23:59:59.000Z

132

Theory of weak localization in ferromagnetic (Ga,Mn)As  

E-Print Network [OSTI]

We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

2009-01-01T23:59:59.000Z

133

Modelling Al and Mn in the open ocean  

E-Print Network [OSTI]

Modelling Al and Mn in the open ocean Marco van Hulten*, Alessandro Tagliabue, Jean-Claude Dutay van Hulten: Modelling Al and Mn in the open ocean 1 #12;Outline Introduction Model of aluminium Constraining dust flux Model of manganese Conclusions Marco van Hulten: Modelling Al and Mn in the open ocean 2

Haak, Hein

134

MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM  

E-Print Network [OSTI]

MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM OPERATIONAL TEST & EVALUATION METHODOLOGIES LTC Thom support assessing a weapon systems true cost and performance characteristics? S1: Can/should cost, operational effectiveness and suitability be assessed independent of one another? S2: Do current test

135

"MBUF Demo" "Mn Road Fee Test"  

E-Print Network [OSTI]

(40 mpg) Electric Vehicle (non-gas powered) State Tax * Federal Tax ** State Tax * Federal Tax"MBUF Demo" "Mn Road Fee Test" "IntelliDrive Connected Vehicles for Safety, Mobility and User Fee Overview Six Months In-Vehicle Data Collection Participant Recruited Equipment Deployed First Odometer

Minnesota, University of

136

Mn/DOT's Project Peer Review  

E-Print Network [OSTI]

and sustain this culture #12;Project Management #12;Recent National Work in Transportation Project ManagementMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research a Peer Review? Why Project Management? ·Improve project delivery performance ­ on time, on budget (an

Minnesota, University of

137

Traffic Equilibration: The Case of the Twin Cities Ramp Meter Shut Off David Levinson1and Atif Sheikh2  

E-Print Network [OSTI]

Traffic Equilibration: The Case of the Twin Cities Ramp Meter Shut Off David Levinson1and Atif Sheikh2 Abstract In Fall 2000, more than 430 ramp meters in the Twin Cities metropolitan area were shut down in order to evaluate the effectiveness of the metering system. This shutdown disturbed normal

Levinson, David M.

138

Direct extraction of oil from sunflower seeds by twin-screw extruder according to an aqueous extraction process: Feasibility  

E-Print Network [OSTI]

Direct extraction of oil from sunflower seeds by twin-screw extruder according to an aqueous the feasibility of an aqueous process to extract sunflower seed oil using a co-rotating twin-screw extruder. Aqueous extraction was carried out using whole seeds and the influence of the operating conditions on oil

Paris-Sud XI, Université de

139

Quantum Key Ditribution Based on Quantum Intensity Correlation of Twin Beams  

E-Print Network [OSTI]

A new and simple quantum key distribution scheme based on the quantum intensity correlation of optical twin beams and the directly local measurements of intensity noise of single optical beam is presented and experimentally demonstrated. Using the twin beams with the quantum intensity correlation of 5dB the effective bit rate of $2\\times 10^7bits/s$ is completed. The noncloning of quantum systems and the sensitivity of the existing correlations to losses provide the physical mechamism for the security against eavesdropping. In the presented scheme the signal modulation and homodyne detection are not needed.

Xiaojun Jia; Xiaolong Su; Qing Pan; Kunchi Peng; Changde Xie

2005-04-08T23:59:59.000Z

140

Broadband squeezing of quantum noise in a Michelson interferometer with Twin-Signal-Recycling  

E-Print Network [OSTI]

Twin-Signal-Recycling (TSR) builds on the resonance doublet of two optically coupled cavities and efficiently enhances the sensitivity of an interferometer at a dedicated signal frequency. We report on the first experimental realization of a Twin-Signal-Recycling Michelson interferometer and also its broadband enhancement by squeezed light injection. The complete setup was stably locked and a broadband quantum noise reduction of the interferometers shot noise by a factor of up to 4\\,dB was demonstrated. The system was characterized by measuring its quantum noise spectra for several tunings of the TSR cavities. We found good agreement between the experimental results and numerical simulations.

André Thüring; Christian Gräf; Henning Vahlbruch; Moritz Mehmet; Karsten Danzmann; Roman Schnabel

2010-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Concentration profiles across twin boundaries in YBa{sub 2}Cu{sub 3}O{sub 6+{delta}}  

SciTech Connect (OSTI)

Twin boundaries in polycrystalline YBa{sub 2}Cu{sub 3}O{sub 6+{delta}} have been studied by atom-probe field-ion microscopy. Oxygen depletion at a twin boundary in a {delta}=0.6 material was observed. The width of the depleted region was 6{endash}7 nm. It agrees well with the width of oxygen depletion calculated from the oxygen-depleted twin boundary model by Jou and Washburn. However, a twin boundary in a {delta}=0.9 material did not show any oxygen depletion. This study provides direct evidence of oxygen depletion at twin boundaries in polycrystalline YBa{sub 2}Cu{sub 3}O{sub 6+{delta}} ceramics. {copyright} {ital 1997} {ital The American Physical Society}

Hu, Q.; Stiller, K.; Olsson, E.; Andren, H. [Department of Physics, Chalmers University of Technology and University of Goeteborg, S-412 96 Goeteborg (Sweden)] [Department of Physics, Chalmers University of Technology and University of Goeteborg, S-412 96 Goeteborg (Sweden); Berastegui, P.; Johansson, L. [Department of Inorganic Chemistry, Chalmers University of Technology and University of Goeteborg, S-412 96 Goeteborg (Sweden)] [Department of Inorganic Chemistry, Chalmers University of Technology and University of Goeteborg, S-412 96 Goeteborg (Sweden)

1997-11-01T23:59:59.000Z

142

The Development of a CFD Program to Model the Pressure Distribution of a Nanocomposite Melt Flow through a Twin-Screw Extruder  

E-Print Network [OSTI]

through a Twin-Screw Extruder Craig Lewandowski University of Minnesota Latin Honors Thesis Academic Year. The manifold analyzed is attached to the twin-screw extruder associated with the NASA Oriented Nanocomposite project with the University of Maryland (College Park). A Werner & Pfleiderer 28mm twin-screw extruder

Dumitrica,Traian

143

Nutrition & Food Science, 3009 Science Hall, Wayne State University, Detroit, MI 48202Telephone: (313) 577-2500 Fax: (313) 577-8616 Email: ab8207@wayne.edu World Wide Web: www.clas.wayne.edu/nfs (revised brochure Sep 2012)  

E-Print Network [OSTI]

.A.) are offered. The MA degree can have an emphasis in Food Service Management or be done in conjunction to be in non-laboratory aspects of nutrition or food service. Required Component of Courses: (13 credit hours & Food Science, 3009 Science Hall, Wayne State University, Detroit, MI 48202Telephone: (313) 577-2500 Fax

Berdichevsky, Victor

144

City of Detroit- SmartBuildings Detroit Grant Program  

Broader source: Energy.gov [DOE]

'''''Note: This program is no longer accepting applications. Check the program web site for information regarding future solicitations.'''''...

145

City of Detroit- SmartBuildings Detroit Green Fund Loan  

Broader source: Energy.gov [DOE]

'''''Note: This program is no longer accepting applications. Check the program web site for information regarding future solicitations.'''''...

146

On the theory of type-I superconductor surface tension and twinning-plane-superconductivity  

E-Print Network [OSTI]

447 On the theory of type-I superconductor surface tension and twinning-plane-superconductivity T du paramètre de Landau-Ginsburg 03BA est trouvée pour la tension de surface des supraconducteurs de. Abstract. 2014 A correction is found to the surface tension in type-I superconductors which is proportional

Boyer, Edmond

147

Twin Screw Extrusion Processing of Energetic Materials AIChE Annual Meeting  

E-Print Network [OSTI]

Twin Screw Extrusion Processing of Energetic Materials AIChE Annual Meeting San Francisco, CA, and the mathematical modeling of the thermo-mechanical history of the energetic formulations in the extruder and bulk distortions of extrudates, the formation of hot spots, the important role played

148

Prediction of Channel Thermal Noise in Twin Silicon Nanowire MOSFET (TSNWFET)  

E-Print Network [OSTI]

proportional to the drain driving current. 3. Derivation of channel thermal noise For analyzing channel thermal effects, the power spectral density equation of channel thermal noise suitable for short channelPrediction of Channel Thermal Noise in Twin Silicon Nanowire MOSFET (TSNWFET) Jaehong Lee, Jongwook

Lee, Jong Duk

149

Preparation of high-strength nanometer scale twinned coating and foil  

DOE Patents [OSTI]

Very high strength single phase stainless steel coating has been prepared by magnetron sputtering onto a substrate. The coating has a unique microstructure of nanometer spaced twins that are parallel to each other and to the substrate surface. For cases where the coating and substrate do not bind strongly, the coating can be peeled off to provide foil.

Zhang, Xinghang (Los Alamos, NM); Misra, Amit (Los Alamos, NM); Nastasi, Michael A. (Santa Fe, NM); Hoagland, Richard G. (Santa Fe, NM)

2006-07-18T23:59:59.000Z

150

Car Sharing for the Twin Cities ! HOURCAR helps make it possible to live car-  

E-Print Network [OSTI]

Car Sharing for the Twin Cities ! HOURCAR helps make it possible to live car- free or car-lite by filling in the "gaps" ! Car sharing reduces car ownership and saves its members thousands of dollars per year ! Car sharing "right-sizes" and makes transparent the costs of car usage #12;HOURCAR ! Transit

Minnesota, University of

151

Giant Narrowband Twin-Beam Generation along the Pump Energy Propagation  

E-Print Network [OSTI]

Walk-off effects, originating from the difference between the group and phase velocities, limit the efficiency of nonlinear optical interactions. While transverse walk-off can be eliminated by proper medium engineering, longitudinal walk-off is harder to avoid. In particular, ultrafast twin- beam generation via pulsed parametric down-conversion (PDC) and four-wave mixing (FWM) is only possible in short crystals or fibres or in double-path schemes. Here we show that in high-gain PDC, one can overcome the destructive role of both effects and even turn them into useful tools for shaping the emission. In our experiment, one of the twin beams is emitted along the pump Poynting vector or its group velocity matches that of the pump. The result is dramatically enhanced generation of both twin beams, with the simultaneous narrowing of angular and frequency spectrum. The effect will enable efficient generation of ultrafast twin photons and beams in cavities, waveguides, and whispering-gallery mode resonators.

Angela M. Perez; Kirill Yu. Spasibko; Polina R. Sharapova; Olga V. Tikhonova; Gerd Leuchs; Maria V. Chekhova

2014-12-16T23:59:59.000Z

152

Surface and grain boundary scattering in nanometric Cu thin films: A quantitative analysis including twin boundaries  

SciTech Connect (OSTI)

The relative contributions of various defects to the measured resistivity in nanocrystalline Cu were investigated, including a quantitative account of twin-boundary scattering. It has been difficult to quantitatively assess the impact twin boundary scattering has on the classical size effect of electrical resistivity, due to limitations in characterizing twin boundaries in nanocrystalline Cu. In this study, crystal orientation maps of nanocrystalline Cu films were obtained via precession-assisted electron diffraction in the transmission electron microscope. These orientation images were used to characterize grain boundaries and to measure the average grain size of a microstructure, with and without considering twin boundaries. The results of these studies indicate that the contribution from grain-boundary scattering is the dominant factor (as compared to surface scattering) leading to enhanced resistivity. The resistivity data can be well-described by the combined Fuchs–Sondheimer surface scattering model and Mayadas–Shatzkes grain-boundary scattering model using Matthiessen's rule with a surface specularity coefficient of p?=?0.48 and a grain-boundary reflection coefficient of R?=?0.26.

Barmak, Katayun [Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027 and Department of Materials Science and Engineering and Materials Research Science and Engineering Center, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Darbal, Amith [Department of Materials Science and Engineering and Materials Research Science and Engineering Center, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Ganesh, Kameswaran J.; Ferreira, Paulo J. [Materials Science and Engineering, The University of Texas at Austin, 1 University Station, Austin, Texas 78712 (United States); Rickman, Jeffrey M. [Department of Materials Science and Engineering and Department of Physics, Lehigh University, Bethlehem, Pennsylvania 18015 (United States); Sun, Tik; Yao, Bo; Warren, Andrew P.; Coffey, Kevin R., E-mail: kb2612@columbia.edu [Department of Materials Science and Engineering, University of Central Florida, 4000 Central Florida Boulevard, Orlando, Florida 32816 (United States)

2014-11-01T23:59:59.000Z

153

The concrete theory of numbers : Problem of simplicity of Fermat number-twins  

E-Print Network [OSTI]

The problem of simplicity of Fermat number-twins $f_{n}^{\\pm}=2^{2^n}\\pm3$ is studied. The question for what $n$ numbers $f_{n}^{\\pm}$ are composite is investigated. The factor-identities for numbers of a kind $x^2 \\pm k $ are found.

Boris V. Tarasov

2007-07-06T23:59:59.000Z

154

MASS-ANGULAR-MOMENTUM RELATIONS IMPLIED BY MODELS OF TWIN PEAK QUASI-PERIODIC OSCILLATIONS  

SciTech Connect (OSTI)

Twin peak quasi-periodic oscillations (QPOs) appear in the X-ray power-density spectra of several accreting low-mass neutron star (NS) binaries. Observations of the peculiar Z-source Circinus X-1 display unusually low QPO frequencies. Using these observations, we have previously considered the relativistic precession (RP) twin peak QPO model to estimate the mass of the central NS in Circinus X-1. We have shown that such an estimate results in a specific mass-angular-momentum (M - j) relation rather than a single preferred combination of M and j. Here we confront our previous results with another binary, the atoll source 4U 1636-53 that displays the twin peak QPOs at very high frequencies, and extend the consideration to various twin peak QPO models. In analogy to the RP model, we find that these imply their own specific M - j relations. We explore these relations for both sources and note differences in the {chi}{sup 2} behavior that represent a dichotomy between high- and low-frequency sources. Based on the RP model, we demonstrate that this dichotomy is related to a strong variability of the model predictive power across the frequency plane. This variability naturally comes from the radial dependence of characteristic frequencies of orbital motion. As a consequence, the restrictions on the models resulting from observations of low-frequency sources are weaker than those in the case of high-frequency sources. Finally we also discuss the need for a correction to the RP model and consider the removing of M - j degeneracies, based on the twin peak QPO-independent angular momentum estimates.

Toeroek, Gabriel; Bakala, Pavel; Sramkova, Eva; Stuchlik, Zdenek; Urbanec, Martin; Goluchova, Katerina, E-mail: pavel.bakala@fpf.slu.cz, E-mail: martin.urbanec@fpf.slu.cz, E-mail: zdenek.stuchlik@fpf.slu.cz, E-mail: terek@volny.cz, E-mail: sram_eva@centrum.cz [Institute of Physics, Faculty of Philosophy and Science, Silesian University in Opava, Bezrucovo nam. 13, CZ-746 01 Opava (Czech Republic)

2012-12-01T23:59:59.000Z

155

,"International Falls, MN Natural Gas Pipeline Imports From Canada...  

U.S. Energy Information Administration (EIA) Indexed Site

International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of...

156

,"Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Noyes, MN...

157

,"Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf...  

U.S. Energy Information Administration (EIA) Indexed Site

Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN...

158

Direct measurement and reconstruction of nonclassical features of twin beams generated in spontaneous parametric down-conversion  

E-Print Network [OSTI]

Correlations in twin beams composed of many photon pairs are studied using an intensified CCD camera. Joint signal-idler photon-number distribution and quantum phase-space quasi-distributions determined from experimental data have nonclassical features.

Ondrej Haderka; Jan Perina Jr; Martin Hamar; Jan Perina

2004-05-20T23:59:59.000Z

159

Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof  

E-Print Network [OSTI]

This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

Seo, Dongmin

2009-05-15T23:59:59.000Z

160

Longitudinal Dynamics of Twin Electron Bunches in a High-energy Linac  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The recent development of two-color x-ray free-electron lasers, as well as the successful demonstration of high-gradient witness bunch acceleration in a plasma, have generated strong interest in electron bunch trains, where two or more electron bunches are generated, accelerated and compressed in the same accelerating bucket. In this paper we give a detailed analysis of a twin-bunch technique in a high-energy linac. This method allows the generation of two electron bunches with high peak current and independent control of time delay and energy separation. We #12;find that the wake#12;fields in the accelerator structures play an important role in the twin-bunch compression, and through analysis show that they can be used to extend the available time delay range. Based on the theoretical model and simulations we propose several methods to achieve larger time delay.

Zhang, Zhen; Ding, Yuantao; Marinelli, Agostino; Huang, Zhirong

2015-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Minnesota Guidestar www.dot.state.mn.us/guidestar  

E-Print Network [OSTI]

.dot.state.mn.us/guidestar What is ITS? · Application of technology to improve the safety and efficiency of the transportation system. #12;Minnesota Guidestar www.dot.state.mn.us/guidestar What is ITS? · Traffic Management ­ Signal Systems ­ Ramp Meters · Emergency Response ­ Mobile Data Terminals ­ 911 Dispatch ­ RF Data Networks

Minnesota, University of

162

Thermal Stability of MnBi Magnetic Materials  

SciTech Connect (OSTI)

MnBi attracts great attention in recent years for its great potential as permanent magnet materials. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase for exchange coupling nanocomposite magnet. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn is easy to react with oxygen. MnO formation is irreversible and causes degradation to the magnetic properties. In this paper, we report our effort on developing MnBi permanent magnet. High purity MnBi (>90%) can be routinely produced in large quantity. The obtained powder exhibit 74 emu/g saturation magnetization at room temperature with 9 T applied field. After alignment, the powder exhibits 11.6 MGOe, and the sintered bulk magnet exhibit 7.8 MGOe at room temperature. Thermal stability study shows that the MnBi is stable up to 473 K in air.

Cui, Jun; Choi, Jung-Pyung; Li, Guosheng; Polikarpov, Evgueni; Darsell, Jens T.; Overman, Nicole R.; Olszta, Matthew J.; Schreiber, Daniel K.; Bowden, Mark E.; Droubay, Timothy C.; Kramer, Matthew J.; Zarkevich, Nikolai; Wang, L. L.; Johnson, Duane D.; Marinescu, Melania; Takeuchi, Ichiro; Huang, Qingzhen; Wu, Hui; Reeve, Hayden; Vuong, Nguyen V.; Liu, J.Ping

2014-01-01T23:59:59.000Z

163

Thermal stability of MnBi magnetic materials  

SciTech Connect (OSTI)

MnBi has attracted much attention in recent years due to its potential as a rare-earth-free permanent magnet material. It is unique because its coercivity increases with increasing temperature, which makes it a good hard phase material for exchange coupling nanocomposite magnets. MnBi phase is difficult to obtain, partly because the reaction between Mn and Bi is peritectic, and partly because Mn reacts readily with oxygen. MnO formation is irreversible and harmful to magnet performance. In this paper, we report our efforts toward developing MnBi permanent magnets. To date, high purity MnBi (>90%) can be routinely produced in large quantities. The produced powder exhibits 74:6 emu g1 saturation magnetization at room temperature with 9 T applied field. After proper alignment, the maximum energy product (BH) max of the powder reached 11.9 MGOe, and that of the sintered bulk magnet reached 7.8 MGOe at room temperature. A comprehensive study of thermal stability shows that MnBi powder is stable up to 473 K in air.

Cui, Jinfang [Pacific Northwest National Laboratory; Choi, J. P. [Pacific Northwest National Laboratory; Li, G. [Pacific Northwest National Laboratory; Polikarpov, E. [Pacific Northwest National Laboratory; Darsell, J. [Pacific Northwest National Laboratory; Overman, N. [Pacific Northwest National Laboratory; Olszta, M. [Pacific Northwest National Laboratory; Schreiber, D. [Pacific Northwest National Laboratory; Bowden, M. [Environmental Molecular Sciences Laboratory; Droubay, T. [Pacific Northwest National Laboratory; Kramer, Matthew J. [Ames Laboratory; Zarkevich, Nikolay A. [Ames Laboratory; Wang, L L. [Ames Laboratory; Johnson, Duane D. [Ames Laboratory; Marinescu, M. [Electron Energy Corporation; Takeuchi, I. [University of Maryland; Huang, Q. Z. [National Institute of Standards and Technology; Wu, H. [University of Maryland; Reeve, H. [United Technologies Research Center; Vuong, N. V. [University of Texas; Liu, J P. [University of Texas

2014-01-27T23:59:59.000Z

164

The Sun-like activity of the solar twin 18 Scorpii  

E-Print Network [OSTI]

We present the results of 10 yr of complementary spectroscopic and photometric observations of the solar twin 18 Scorpii. We show that over the course of its ~7 year chromospheric activity cycle, 18 Sco's brightness varies in the same manner as the Sun's and with a likely brightness variation of 0.09%, similar to the 0.1% decadal variation in the total solar irradiance.

Jeffrey C. Hall; Gregory W. Henry; G. Wesley Lockwood

2007-03-16T23:59:59.000Z

165

Length sensing and control of a Michelson interferometer with Power Recycling and Twin Signal Recycling cavities  

E-Print Network [OSTI]

The techniques of power recycling and signal recycling have proven as key concepts to increase the sensitivity of large-scale gravitational wave detectors by independent resonant enhancement of light power and signal sidebands within the interferometer. Developing the latter concept further, twin signal recycling was proposed as an alternative to conventional detuned signal recycling. Twin signal recycling features the narrow-band sensitivity gain of conventional detuned signal recycling but furthermore facilitates the injection of squeezed states of light, increases the detector sensitivity over a wide frequency band and requires a less complex detection scheme for optimal signal readout. These benefits come at the expense of an additional recycling mirror, thus increasing the number of degrees of freedom in the interferometer which need to be controlled. In this article we describe the development of a length sensing and control scheme and its successful application to a tabletop-scale power recycled Michelson interferometer with twin signal recycling. We were able to lock the interferometer in all relevant longitudinal degrees of freedom, enabling the long-term stable operation of the experiment. We thus laid the foundation for further investigations of this interferometer topology to evaluate its viability for the application in gravitational wave detectors.

Christian Gräf; André Thüring; Henning Vahlbruch; Karsten Danzmann; Roman Schnabel

2012-11-29T23:59:59.000Z

166

Spectroscopy of Mn atoms isolated in solid {sup 4}He  

SciTech Connect (OSTI)

We present an experimental study of the laser-induced luminescence spectra of Mn atoms in solid helium matrices. We observe transitions of the valence electron and of inner-shell electrons. We find that the Mn-He interaction perturbs the inner-shell transitions to a lesser extent than the valence-electron transitions. The observed lineshapes of the inner-shell transitions of Mn are similar to those of an inner-shell transition in Ba studied earlier. At the same time, they are more strongly perturbed than the corresponding transitions in Au and Cu under the same conditions. We suggest a qualitative explanation of these observations based on the atomic bubble model. Our results also suggest that the inner-shell transitions of Mn in solid He are more strongly perturbed than the same lines of Mn isolated in solid Ar or Kr matrices.

Moroshkin, P., E-mail: petr.moroshkin@riken.jp; Lebedev, V.; Weis, A. [Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg (Switzerland)

2014-06-07T23:59:59.000Z

167

Magnetic Moment Enhancement for Mn7 Cluster on Graphene  

SciTech Connect (OSTI)

Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

2014-08-21T23:59:59.000Z

168

The helium abundances in HgMn and normal stars  

E-Print Network [OSTI]

The parameter-free model of diffusion in the atmospheres of HgMn stars (Michaud 1986; Michaud et al 1979) predicts that helium should sink below the He II ionization zone in order that diffusion of other elements may take place, and that all HgMn stars should have deficits of helium in their photospheres, with a minimum deficit of 0.3 dex. In this study, the Smith & Dworetsky (1993) sample of HgMn stars and normal comparison stars is examined, and the helium abundances determined by spectrum synthesis using echelle spectra taken at Lick Observatory and the AAT. The prediction is confirmed; all HgMn stars are deficient in He by as much as 1.5 dex. Also, two HgMn stars, HR7361 and HR7664, show clear evidence of helium stratification.

M. M. Dworetsky

2004-07-26T23:59:59.000Z

169

Formation of MnSb during the growth of MnSi layers in the presence of an Sb flux  

E-Print Network [OSTI]

, Kawasaki 210-0855, Japan Y. Yan National Renewable Energy Laboratory, Golden, Colorado 80401 S. J a magnetic transition at TC 29.1 K from a paramag- netic state to a helicoidal order.3 An itinerant metamagnetic transition in MnSi has been observed,4,5 and magnetic prop- erties of MnSi under high pressure

Pennycook, Steve

170

Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO{sub 2}  

SciTech Connect (OSTI)

In this study, Mn silicate (MnSiO{sub 3}) barrier layers were formed on thermally grown SiO{sub 2} using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in determining the extent of the interaction between the deposited Mn and the SiO{sub 2} substrate. Using x-ray photoelectron spectroscopy, it has been shown that a metallic Mn film with an approximate thickness of 1 nm cannot be fully converted to Mn silicate following vacuum annealing to 500 deg. C. Transmission electron microscopy (TEM) analysis suggests the maximum MnSiO{sub 3} layer thickness obtainable using metallic Mn is {approx}1.7 nm. In contrast, a {approx}1 nm partially oxidized Mn film can be fully converted to Mn silicate following thermal annealing to 400 deg. C, forming a MnSiO{sub 3} layer with a measured thickness of 2.6 nm. TEM analysis also clearly shows that MnSiO{sub 3} growth results in a corresponding reduction in the SiO{sub 2} layer thickness. It has also been shown that a fully oxidized Mn oxide thin film can be converted to Mn silicate, in the absence of metallic Mn. Based on these results it is suggested that the presence of Mn oxide species at the Mn/SiO{sub 2} interface facilitates the conversion of SiO{sub 2} to MnSiO{sub 3}, in agreement with previously published studies.

Casey, P.; Bogan, J.; Hughes, G. [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland); Lozano, J. G.; Nellist, P. D. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

2011-09-01T23:59:59.000Z

171

Evaluation of three-way vs. single-cross hybrids of grain sorghum produced with twin-seeded and single-seeded parents  

E-Print Network [OSTI]

-sterile (A) lines; 2 homozygous single-seeded (tsts) and 1 homozygous twin-seeded (~sTs), their 3 non-restorer (B-line) counterparts, and 4 fertility restoring (R-lines); 2 homozygous single-seeded (tats) and 2 homozygous twin-seeded (TsTs) . These 30...-way hybrids when single- vs. twin-seeded and twin- vs ~ single-seeded, as groups, were contrasted ~ DFDICATICN Con Amor a Ko ty Pochito vii ACKNOWLEDGMEBTS I thank my major professor, Dr. Frederick R. Miller, for his advice and criticism during...

Perez, German Jose

1980-01-01T23:59:59.000Z

172

Unusual Structure and Magnetism in MnO Nanoclusters  

E-Print Network [OSTI]

We report an unusual evolution of structure and magnetism in stoichiometric MnO clusters based on an extensive and unbiased search through the potential energy surface within density functional theory. The smaller clusters, containing up to five MnO units, adopt two-dimensional structures; and regardless of the size of the cluster, magnetic coupling is found to be antiferromagnetic in contrast to previous theoretical findings. Predicted structure and magnetism are strikingly different from the magnetic core of Mn-based molecular magnets, whereas they were previously argued to be similar. Both of these features are explained through the inherent electronic structures of the clusters.

Ganguly, Shreemoyee; Sanyal, Biplab; Mookerjee, Abhijit; 10.1103/PhysRevB.83.020411

2011-01-01T23:59:59.000Z

173

Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide  

E-Print Network [OSTI]

Parallel Polarization EPR Characterization of the Mn(III) Center of Oxidized Manganese Superoxide polarization CW-EPR to investigate the paramagnetic Mn3+ ion of the MnSOD enzyme from Escherichia coli with a positive axial zero-field splitting value, D, are arranged as shown in Figure 1. An EPR signal from the Mn

Miller, Anne-Frances

174

Muon decays in the Earth's atmosphere, differential aging and the paradox of the twins  

E-Print Network [OSTI]

Observation of the decay of muons produced in the Earth's atmosphere by cosmic ray interactions provides a graphic illustration of the counter-intuitive space-time predictions of special relativity theory. Muons at rest in the atmosphere, decaying simultaneously, are subject to a universal time-dilatation effect when viewed from a moving frame and so are also observed to decay simultaneously in all such frames. The analysis of this example reveals the underlying physics of the differential aging effect in Langevin's travelling-twin thought experiment.

J. H. Field

2009-02-05T23:59:59.000Z

175

Conditional transfer of quantum correlation in the intensity of twin beams  

E-Print Network [OSTI]

A conditional protocol of transferring quantum-correlation in continuous variable regime was experimentally demonstrated. The quantum-correlation in two pairs of twin beams, each characterized by intensity-difference squeezing of 7.0 dB, was transferred to two initially independent idler beams. The quantum-correlation transfer resulted in intensity-difference squeezing of 4.0 dB between two idler beams. The dependence of preparation probability and transfer fidellity on the selection bandwidth was also studied.

Yun Zhang; Kazuhiro Hayasaka; Katsuyuki Kasai

2005-04-06T23:59:59.000Z

176

Plastification of polymers in twin-screw-extruders: New visualization technic using high-speed imaging  

SciTech Connect (OSTI)

The initial melting of the first granules through plastic energy dissipation (PED) at the beginning of the melting zone, in the co-rotating twin-screw extruder is visualized in this work. The visualization was created through the use of a high speed camera in the cross section of the melting zone. The parameters screw speed, granule-temperature, temperature-profile, type of polymer and back pressure were examined. It was shown that the screw speed and the temperature-profile have significant influence on the rate of initial melting.

Knieper, A., E-mail: Alexander.Knieper@lbf.fraunhofer.de, E-mail: Christian.Beinert@lbf.fraunhofer.de; Beinert, C., E-mail: Alexander.Knieper@lbf.fraunhofer.de, E-mail: Christian.Beinert@lbf.fraunhofer.de [Group Polymer Processing, Division Plastics, Fraunhofer-Institute LBF (Germany)

2014-05-15T23:59:59.000Z

177

EA-344 Twin Cities Power-Canada, LLC | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct,Final9: DraftPlant, Amarillo, Texas |2:12-C7-B Emera44 Twin

178

PPS27, 2011, 27th World Congress of the Polymer Processing Society, May 1014, Marrakech, Morocco 1 Influence of Twin-Screw Processing Conditions  

E-Print Network [OSTI]

montmorillonite with respective mass fraction of 85/10/5 were prepared with a co-rotating twin-screw extruder Influence of Twin-Screw Processing Conditions on Structure and Properties of Polypropylene - Organoclay such as screw speed, feed rate and barrel temperature on the nanocomposite structure and its consequences

Paris-Sud XI, Université de

179

Ambi-site substitution of Mn in lanthanum germanate apatites  

SciTech Connect (OSTI)

A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

2009-08-05T23:59:59.000Z

180

High strain in polycrystalline Ni{sub 48.8}Mn{sub 31.4}Ga{sub 19.8} Heusler alloys under overlapped static and oscillating magnetic fields  

SciTech Connect (OSTI)

Martensitic polycrystalline Ni{sub 48.8}Mn{sub 31.4}Ga{sub 19.8} Heusler alloys, with a stacking period of 14 atomic planes at room temperature, were innovatively processed by combining high-energy ball milling and powder metallurgy. Bulk samples were mechanically coupled to a piezoelectric material in a parallel configuration, and the mechanical deformation of the studied system due to the twin's variant motion was investigated under overlapped static and oscillating magnetic fields. A reversible and high mechanical deformation is observed when the frequency of the oscillating magnetic field is tuned with the natural vibration frequency of this system. In this condition, a linear deformation as a function of the static magnetic field amplitude occurs in the ±4 kOe range, and a mechanical deformation of 2% at 10 kOe is observed.

Montanher, D. Z.; Pereira, J. R. D.; Cótica, L. F.; Santos, I. A. [Department of Physics, State University of Maringá, Av. Colombo 5790, Maringá - PR 87020-900 (Brazil); Gotardo, R. A. M. [Technological Federal University of Paraná, Av. Alberto Carazzai 1640, Cornélio Procópio - PR 86300-000 (Brazil); Viana, D. S. F.; Garcia, D.; Eiras, J. A. [Department of Physics, Federal University of São Carlos, Rod. Washington Luiz, Km 235, São Carlos - SP 13565-905 (Brazil)

2014-09-21T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Magnetoluminescence of CdTe/MnTe/CdMgTe heterostructures with ultrathin MnTe layers  

SciTech Connect (OSTI)

CdTe/MnTe/CdMgTe quantum-well structures with one or two monolayers of MnTe inserted at CdTe/CdMgTe interfaces were fabricated. The spectra of the excitonic luminescence from CdTe quantum wells and their variation with temperature indicate that introduction of ultrathin MnTe layers improves the interface quality. The effect of a magnetic field in the Faraday configuration on the spectral position of the exciton-emission peaks indicates that frustration of magnetic moments in one-monolayer MnTe insertions is weaker than in two-monolayer insertions. The effect of a magnetic field on the exciton localization can be explained in terms of the exciton wave-function shrinkage and obstruction of the photoexcited charge-carrier motion in the quantum well.

Agekyan, V. F., E-mail: vfag@rambler.ru [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Holz, P. O. [Polish Academy of Sciences, Institute of Physics (Poland); Karczewski, G. [Linkoeping University (Sweden); Katz, V. N. [St. Petersburg State University, Fock Institute of Physics (Russian Federation); Moskalenko, E. S. [Russian Academy of Sciences, Ioffe Physical Technical Institute (Russian Federation); Serov, A. Yu.; Filosofov, N. G. [St. Petersburg State University, Fock Institute of Physics (Russian Federation)

2011-10-15T23:59:59.000Z

182

Diversity of Mn oxides produced by Mn(II)-oxidizing fungi. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesDataTranslocationDiurnal Cycle of Convection atDiversity of Mn

183

Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility  

E-Print Network [OSTI]

Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility Coordination Process incorporates Processes There are projects where the full process is not necessary. The Mn/DOT Utilities Manual provides

Minnesota, University of

184

Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II  

SciTech Connect (OSTI)

Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

Mishra, A.; Yano, J.; Pushkar, Y.; Abboud, K.A.; Yachandra, V.K.; Christou, G.

2009-06-03T23:59:59.000Z

185

Hydrothermal synthesis and catalytic properties of {alpha}- and {beta}-MnO{sub 2} nanorods  

SciTech Connect (OSTI)

One-dimensional {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} single-crystalline nanostructures were prepared by hydrothermal process. The products were characterized in detail by multiform techniques: X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Experimental results indicate that the temperature plays important roles in determining produce {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods. In addition, the as-prepared {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods showed excellent catalytic performance in the Fenton-like reaction.

Cao, Guangsheng, E-mail: daqingcgs@163.com [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China); Su, Ling; Zhang, Xiaojuan; Li, Hui [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)

2010-04-15T23:59:59.000Z

186

Spin dependent transport properties of Mn-Ga/MgO/Mn-Ga magnetic tunnel junctions with metal(Mg, Co, Cr) insertion layer  

SciTech Connect (OSTI)

We report a first principles theoretical investigation of spin polarized quantum transport in Mn{sub 2}Ga/MgO/Mn{sub 2}Ga and Mn{sub 3}Ga/MgO/Mn{sub 3}Ga magnetic tunneling junctions (MTJs) with the consideration of metal(Mg, Co, Cr) insertion layer effect. By changing the concentration of Mn, our calculation shows a considerable disparity in transport properties: A tunneling magnetoresistance (TMR) ratio of 852% was obtained for Mn{sub 2}Ga-based MTJs, however, only a 5% TMR ratio for Mn{sub 3}Ga-based MTJs. In addition, the influence of insertion layer has been considered in our calculation. We found the Co insertion layer can increase the TMR of Mn{sub 2}Ga-based MTJ to 904%; however, the Cr insertion layer can decrease the TMR by 668%; A negative TMR ratio can be obtained with Mg insertion layer. Our work gives a comprehensive understanding of the influence of different insertion layer in Mn-Ga based MTJs. It is proved that, due to the transmission can be modulated by the interfacial electronic structure of insertion, the magnetoresistance ratio of Mn{sub 2}Ga/MgO/Mn{sub 2}Ga MTJ can be improved by inserting Co layer.

Liang, S. H.; Tao, L. L.; Liu, D. P., E-mail: dpliu@iphy.ac.cn; Han, X. F., E-mail: xfhan@iphy.ac.cn [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Lu, Y. [Institut Jean Lamour, UMR 7198, CNRS-Nancy Université, BP 239, 54506 Vandoeuvre (France)

2014-04-07T23:59:59.000Z

187

A comparative study of magnetic behaviors in TbNi{sub 2}, TbMn{sub 2} and TbNi{sub 2}Mn  

SciTech Connect (OSTI)

All TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn compounds exhibit the cubic Laves phase with AB{sub 2}-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi{sub 2}Mn is 1:3. Rietveld refinement indicates that in TbNi{sub 2}Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a?=?14.348?Å (space group F-43?m), 7.618?Å, and 7.158?Å (space group Fd-3?m) for TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn, respectively. The magnetic transition temperatures T{sub C} were found to be T{sub C}?=?38?K and T{sub C}?=?148?K for TbNi{sub 2} and TbNi{sub 2}Mn, respectively, while two magnetic phase transitions are detected for TbMn{sub 2} at T{sub 1}?=?20?K and T{sub 2}?=?49?K. Clear magnetic history effects in a low magnetic field are observed in TbMn{sub 2} and TbNi{sub 2}Mn. The magnetic entropy changes have been obtained.

Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Md Din, M. F.; Hong, F.; Cheng, Z. X.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Kennedy, S. J.; Studer, A. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China)

2014-05-07T23:59:59.000Z

188

Submitted to Composites A: Applied Science and Manufacturing Graded Polymer Composites Using Twin Screw Extrusion: A Combinatorial  

E-Print Network [OSTI]

Twin Screw Extrusion: A Combinatorial Approach to Developing New Energetic Materials Frederick M The development of new energetic materials is a time-consuming, laborious, and sometimes dangerous process. Batch for developing new energetic materials. Graded composite energetic materials with 79 to 87% solids loading

Maryland at College Park, University of

189

Mn-Fe base and Mn-Cr-Fe base austenitic alloys  

DOE Patents [OSTI]

Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

1987-01-01T23:59:59.000Z

190

Chains of quasiclassical information for bipartite correlations and the role of twin observables  

SciTech Connect (OSTI)

Having the quantum correlations in a general mixed or pure bipartite state in mind, the part of information accessible by simultaneous measurement on both subsystems is shown never to exceed the part accessible by measurement on one subsystem, which, in turn is proved not to exceed the von Neumann mutual information. A particular pair of (opposite-subsystem) observables is shown to be responsible both for the amount of quasiclassical correlations and for that of the purely quantum entanglement in the pure-state case: the former via simultaneous subsystem measurements, and the latter through the entropy of coherence or of incompatibility, which is defined for the general case. The observables at issue are so-called twin observables. A general definition of the latter is given in terms of their detailed properties.

Herbut, Fedor [Faculty of Physics, University of Belgrade, P.O. Box 368, Belgrade 11001, Serbia (Serbia and Montenegro); Serbian Academy of Sciences and Arts, Knez Mihajlova 35, 11000 Belgrade (Serbia and Montenegro)

2002-11-01T23:59:59.000Z

191

The development of uranium foil farication technology utilizing twin roll method for Mo-99 irradiation target  

E-Print Network [OSTI]

MDS Nordion in Canada, occupying about 75% of global supply of Mo-99 isotope, has provided the irradiation target of Mo-99 using the rod-type UAl sub x alloys with HEU(High Enrichment Uranium). ANL (Argonne National Laboratory) through co-operation with BATAN in Indonesia, leading RERTR (Reduced Enrichment for Research and Test Reactors) program substantially for nuclear non-proliferation, has designed and fabricated the annular cylinder of uranium targets, and successfully performed irradiation test, in order to develop the fabrication technology of fission Mo-99 using LEU(Low Enrichment Uranium). As the uranium foils could be fabricated in laboratory scale, not in commercialized scale by hot rolling method due to significant problems in foil quality, productivity and economic efficiency, attention has shifted to the development of new technology. Under these circumstances, the invention of uranium foil fabrication technology utilizing twin-roll casting method in KAERI is found to be able to fabricate LEU or...

Kim, C K; Park, H D

2002-01-01T23:59:59.000Z

192

Employing Twin Crabbing Cavities to Address Variable Transverse Coupling of Beams in the MEIC  

SciTech Connect (OSTI)

The design strategy of the Medium Energy Electron-Ion Collider (MEIC) at Jefferson Lab contemplates both matching of the emittance aspect ratios and a 50 mrad crossing angle along with crab crossing scheme for both electron and ion beams over the energy range (?s=20-70 GeV) to achieve high luminosities at the interaction points (IPs). However, the desired locations for placing the crabbing cavities may include regions where the transverse degrees of freedom of the beams are coupled with variable coupling strength that depends on the collider rings’ magnetic elements (solenoids and skew quadrupoles). In this work we explore the feasibility of employing twin rf dipoles that produce a variable direction crabbing kick to account for a range of transverse coupling of both beams.

Castilla, Alejandro [ODU; Delayen, Jean R. [ODU, JLAB; Morozov, Vasiliy [JLAB; Satogata, Todd [JLAB

2014-07-01T23:59:59.000Z

193

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

194

Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures  

E-Print Network [OSTI]

Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

Ruan, Shiyun

195

Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge  

E-Print Network [OSTI]

Li, A. P. et al. Magnetism in Mn x Ge 1-x semiconductorsElectronic Structure and Magnetism for Mn in Amorphous Sistructure that determines magnetism. Figure 3 shows XAS data

Zeng, Li

2010-01-01T23:59:59.000Z

196

Mn12-acetate thin film patterns and their interaction with superconductors  

E-Print Network [OSTI]

Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

Kim, Kyongwan

2009-05-15T23:59:59.000Z

197

Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance  

SciTech Connect (OSTI)

In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

Dai, Qilin; Wang, Wenyong, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu; Tang, Jinke, E-mail: wwang5@uwyo.edu, E-mail: jtang2@uwyo.edu [Department of Physics and Astronomy, University of Wyoming, Laramie, Wyoming 82071 (United States); Sabio, Erwin M. [Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071 (United States)

2014-05-05T23:59:59.000Z

198

Engineering the magnetic properties of the Mn13 cluster by doping  

E-Print Network [OSTI]

With a goal to produce a giant magnetic moment in a Mn13 cluster that will be useful for practical applications, we have considered the structure and magnetic properties of a pure Mn13 cluster and substitutionally doped ...

Datta, Soumendu

199

X-ray absorption study of the electronic structure of Mn-doped amorphous Si  

E-Print Network [OSTI]

X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

Zeng, Li

2008-01-01T23:59:59.000Z

200

E-Print Network 3.0 - al fe mn Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

National Cheng Kung University Collection: Physics 4 Valence states of transition-metal ions in cubic perovskites SrMn1-xFexO3 H. J. Lee,a Summary: the Mn 3d resonance and...

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Effect of Composition and Heat Treatment on MnBi Magnetic Materials...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract: The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high...

202

Application of the method of effective potentials to a model for twinning in elastic materials  

SciTech Connect (OSTI)

We extend the method of effective potentials to systems with next-nearest-neighbor interactions, and apply it to a one-dimensional discrete model for twins in elastic materials. The energy of the system is given by H = +(..gamma../2) (u/sub n//sub +1/-2u/sub n/+u/sub n-1/)/sup 2/ -cosu/sub n/, where the first two terms model the elastic strain-dependent energy which we take to be in the form of a double well in the strains and the third term gives its dependence on the discretized strain gradients. The periodic potential in the last term is introduced to allow for additional interactions with a background such as a parent phase, grain boundaries, or another array of twins. We obtain the phase diagram and show that it consists of various modulated commensurate as well as incommensurate ground-state configurations. We find continuous phonon-driven transitions between the homogeneous and any modulated phase, an incomplete devil's staircase in a narrow region close to the homogeneous phase and first-order soliton-driven transitions between commensurate phases. The first-order transition lines end at triple points where three commensurate phases coexist. In contrast to other nonconvex models we do not find here any superdegenerate points. We give general arguments which exclude the existence of such points in the present model. Preliminary results obtained by driving the system are discussed. These consist of various metastable configurations exhibiting strong hysteretic variation with the driving force.

Marianer, S.; Floria, L.M.

1988-12-01T23:59:59.000Z

203

Transitions of Dislocation Glide to Twinning and Shear Transformation in Shock-Deformed Tantalum  

SciTech Connect (OSTI)

Recent TEM studies of deformation substructures developed in tantalum and tantalum-tungsten alloys shock-deformed at a peak pressure {approx}45 GPa have revealed the occurrence of shock-induced phase transformation [i.e., {alpha} (bcc) {yields} {omega} (hexagonal) transition] in addition to shock-induced deformation twinning. The volume fraction of twin and {omega} domains increases with increasing content of tungsten. A controversy arises since tantalum exhibits no clear equilibrium solid-state phase transformation under hydrostatic pressures up to 174 GPa. It is known that phase stability of a material system under different temperatures and pressures is determined by system free energy. That is, a structural phase that has the lowest free energy will be stable. For pressure-induced phase transformation under hydrostatic-pressure conditions, tantalum may undergo phase transition when the free energy of a competing phase {omega} becomes smaller than that of the parent phase {alpha} above a critical pressure (P{sub eq}), i.e., the equilibrium {alpha} {yields} {omega} transition occurs when the pressure increases above P{sub eq}. However, it is also known that material shocked under dynamic pressure can lead to a considerable increase in temperature, and the higher the applied pressure the higher the overheat temperature. This means a higher pressure is required to achieve an equivalent volume (or density) in dynamic-pressure conditions than in hydrostatic-pressure conditions. Accordingly, P{sub eq} for {alpha} {yields} {omega} transition is anticipated to increase under dynamic-pressure conditions as a result of the temperature effect. Although no clear equilibrium transition pressure under hydrostatic-pressure conditions is reported for tantalum, it is reasonable to assume that Peq under dynamic-pressure conditions will be considerably higher than that under hydrostatic-pressure conditions if there is a pressure-induced {alpha} {yields} {omega} transition in tantalum. The observation of {alpha} {yields} {omega} transition in shock-compressed tantalum and tantalum-tungsten alloys at {approx}45 GPa in fact reveals the occurrence of a non-equilibrium phase transformation at such a low pressure. We therefore postulated that the equation of state (EOS) based on static thermodynamics, which asserts that the system free energy (G) is a function of volume (V), pressure (P), and temperature (T), i.e., G = F(V, P, T) is insufficient to rationalize the system free energy under dynamic-pressure conditions. Since shear deformation was found to play a crucial role in shock-induced deformation twins and {omega} phase, the density and arrangement of dislocations, which can alter and increase the system free energy, should also be taken into account to rationalize the non-equilibrium phase transformation in shocked tantalum. Typical arrangements of high-density dislocations formed in pure tantalum shocked at {approx}45 GPa are shown in Figs. 1a and 1b. Figure 1a reveals a cellular dislocation structure but no twins or {omega} phase-domains were observed in this region. The formation of low-energy type cellular dislocation structures indicates the occurrence of dynamic-recovery reactions to reduce dislocation density in this region. Figure 1b shows an evenly distributed dislocation structure with a local dislocation density ({rho}) as high as {approx}5 x 10{sup 12} cm{sup -2} according to {rho} {approx} 1/l{sup 2}, where l ({approx}4.5 nm) is the spacing between two dislocations. Here shock-induced twin plates and {omega} phase-domains can be readily seen. These observations provide us a clue that dislocation arrangement and density population, which can alter system free energy through the changes of dislocation self-energy (E{sub s}) and dislocation interaction energy (E{sub ij}), are relevant to the occurrence of shock-induced twinning and phase transformation in tantalum. The objective of this paper is to report new results obtained from pure tantalum and tantalum tungsten alloys shocked at {approx}30 GPa in order to clarify the corr

Hsiung, L L; Campbell, G H; McNaney, J M

2009-10-19T23:59:59.000Z

204

Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa  

SciTech Connect (OSTI)

Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

2011-05-03T23:59:59.000Z

205

Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands{  

E-Print Network [OSTI]

Novel frustrated magnetic lattice based on triangular [Mn3(m3-F)] clusters with tetrazole ligands701840a Unprecedented [MnII 3(m3-F)(m-N­N)3] triangular clusters with tetrazole ligands are linked by Mn the tetrazolate ligands, which possess additional N-donor sites for network formation. To our knowledge, [M3(m3-X

Gao, Song

206

On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite  

SciTech Connect (OSTI)

Photoreductive dissolution of layer type Mn(IV) oxides (birnessite) under sunlight illumination to form soluble Mn(II) has been observed in both field and laboratory settings, leading to a consensus that this process is a key driver of the biogeochemical cycling of Mn in the euphotic zones of marine and freshwater ecosystems. However, the underlying mechanisms for the process remain unknown, although they have been linked to the semiconducting characteristics of hexagonal birnessite, the ubiquitous Mn(IV) oxide produced mainly by bacterial oxidation of soluble Mn(II). One of the universal properties of this biogenic mineral is the presence of Mn(IV) vacancies, long-identified as strong adsorption sites for metal cations. In this paper, the possible role of Mn vacancies in photoreductive dissolution is investigated theoretically using quantum mechanical calculations based on spin-polarized density functional theory (DFT). Our DFT study demonstrates unequivocally that Mn vacancies significantly reduce the band-gap energy for hexagonal birnessite relative to a hypothetical vacancy-free MnO{sub 2} and thus would increase the concentration of photo-induced electrons available for Mn(IV) reduction upon illumination of the mineral by sunlight. Calculations of the charge distribution in the presence of vacancies, although not fully conclusive, show a clear separation of photo-induced electrons and holes, implying a slow recombination of these charge-carriers that facilitates the two-electron reduction of Mn(IV) to Mn(II).

Kwon, K.D.; Refson, K.; Sposito, G.

2009-06-01T23:59:59.000Z

207

Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}  

SciTech Connect (OSTI)

We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

López, C.A., E-mail: calopez@unsl.edu.ar [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Saleta, M.E. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Pedregosa, J.C. [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Sánchez, R.D. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain); and others

2014-02-15T23:59:59.000Z

208

Growing the renewable chemicals and advanced biofuels cluster in MN  

E-Print Network [OSTI]

Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

Levinson, David M.

209

Electronic interactions between gold films and mn12-acetate  

E-Print Network [OSTI]

the presence of a surface layer of Mn12–acetate, have been performed using a dilution refrigerator. Quantitative fits to the data using the predictions of weak localization theory were performed using a least-squares fit method in order to determine...

Means, Joel Lewis

2009-05-15T23:59:59.000Z

210

Mn/DOT's Ombudsman Program Collaboration and Process  

E-Print Network [OSTI]

Mn/DOT's Ombudsman Program Collaboration and Process #12;Overview Ombudsman exists to rebuild trust on the environmental and municipal consent processes can be critical #12;A Large Organization #12;Tragedy;Ombudsman Does Not... ·! Advocate for one party or point of view ·! Own any formal process or policy

Minnesota, University of

211

Study of progesterone for the prevention of preterm birth in twins (STOPPIT): findings from a trial-based cost-effectiveness analysis   

E-Print Network [OSTI]

OBJECTIVES: Preterm birth contributes to a range of healthcare problems amongst infants surmounting to sizeable healthcare costs. Twin pregnancies are at particular risk of preterm birth. The objective of this study was ...

Eddama, O.; Petrou, S.; Regier, D.; Norrie, J.; MacLennan, G.; Mackenzie, F.; Norman, J. E.

212

which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Dicephalus parapagus conjoined twins discordant for anencephaly: a case report  

E-Print Network [OSTI]

This Provisional PDF corresponds to the article as it appeared upon acceptance. Fully formatted PDF and full text (HTML) versions will be made available soon. Dicephalus parapagus conjoined twins discordant for anencephaly: a case report

Usang E Usang; Babatunde J Olasode; Ayi E Archibong; Jacob J Udo; Usang E Usang; Babatunde J Olasode; Ayi E Archibong; Jacob J Udo; U Eduwem

2009-01-01T23:59:59.000Z

213

Chain-oxygen ordering in twin-free YBa2Cu3O7-single crystals driven by 20-keV electron irradiation  

E-Print Network [OSTI]

Chain-oxygen ordering in twin-free YBa2Cu3O7- single crystals driven by 20-keV electron irradiation 2005 We have examined the effects of 20-keV electron irradiation on the -Cu 1 -O 1 - n chain-oxygen arrange- ments in oxygen-deficient but otherwise twin-free YBa2Cu3O7- single crystals. Comparison

Johansen, Tom Henning

214

0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core  

E-Print Network [OSTI]

1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

Gilli, Adrian

215

Effect of geometrical constraint condition on the formation of nanoscale twins in the Ni-based metallic glass composite  

SciTech Connect (OSTI)

We investigated the effect of geometrically constrained stress-strain conditions on the formation of nanotwins in alpha-brass phase reinforced Ni59Zr20Ti16Si2Sn3 metallic glass (MG) matrix deformed under macroscopic uniaxial compression. The specific geometrically constrained conditions in the samples lead to a deviation from a simple uniaxial state to a multi-axial stress state, for which nanocrystallization in the MG matrix together with nanoscale twinning of the brass reinforcement is observed in localized regions during plastic flow. The nanocrystals in the MG matrix and the appearance of the twinned structure in the reinforcements indicate that the strain energy is highly confined and the local stress reaches a very high level upon yielding. Both the effective distribution of reinforcements on the strain enhancement of composite and the effects of the complicated stress states on the development of nanotwins in the second-phase brass particles are discussed.

Lee, M.H.; Kim, B.S.; Kim, D.H.; Ott, R.T.; Sansoz, F.; Eckert, J.

2014-04-25T23:59:59.000Z

216

Bending properties of epoxy resin matrix composites filled with NiMnGa ferromagnetic shape memory alloy powders  

E-Print Network [OSTI]

Bending properties of epoxy resin matrix composites filled with Ni­Mn­Ga ferromagnetic shape memory­Mn­Ga Composite materials Mechanical properties Microstructure Two types of epoxy resin matrix composites filled­Mn­Ga epoxy resin composites were reported, yet the bending property of Ni­Mn­Ga-polymer smart composites has

Zheng, Yufeng

217

PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot  

E-Print Network [OSTI]

PHYSICAL REVIEW B 84, 205305 (2011) Spin-phonon coupling in single Mn-doped CdTe quantum dot C. L dynamics of a single Mn atom in a laser driven CdTe quantum dot is addressed theoretically. Recent of single Mn-doped CdTe dots, information about the quantum spin state of a single Mn atom is extracted from

Paris-Sud XI, Université de

218

Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals  

SciTech Connect (OSTI)

Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

KAPLAN, DANIEL

2005-09-13T23:59:59.000Z

219

Effect of Composition and Heat Treatment on MnBi Magnetic Materials  

SciTech Connect (OSTI)

The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. Several groups have demonstrated that the Hci of MnBi compound in thin film or in powder form can exceed 12 kOe and 26 kOe at 300 K and 523 K, respectively. Such steep increase in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. The reaction between Mn and Bi is peritectic, so Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, the composition of the Mn-Bi alloy with the largest amount of the desired LTP (low temperature phase) MnBi and highest saturation magnetization will be over-stoichiometric and rich in Mn. The amount of additional Mn required to compensate the Mn precipitation depends on solidification rate: the faster the quench speed, the less Mn precipitates. Here we report a systematic study of the effect of composition and heat treatments on the phase contents and magnetic properties of Mn-Bi alloys. In this study, Mn-Bi alloys with 14 compositions were prepared using conventional metallurgical methods such as arc melting and vacuum heat treatment, and the obtained alloys were analyzed for compositions, crystal structures, phase content, and magnetic properties. The results show that the composition with 55 at.% Mn exhibits the highest LTP MnBi content and the highest magnetization. The sample with this composition shows >90 wt.% LTP MnBi content. Its measured saturation magnetization is 68 emu/g with 2.3 T applied field at 300 K; its coercivity is 13 kOe and its energy product is 12 MGOe at 300 K. A bulk magnet fabricated using this powder exhibits an energy product of 8.2 MGOe.

Cui, Jun; Choi, Jung-Pyung; Polikarpov, Evgueni; Bowden, Mark E.; Xie, Wei; Li, Guosheng; Nie, Zimin; Zarkevich, Nikolai; Kramer, Matthew J.; Johnson, Duane D.

2014-08-17T23:59:59.000Z

220

Charge transport properties of CdMnTe radiation detectors  

SciTech Connect (OSTI)

Growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe)radiation detectors have been described. Alpha-particle spectroscopy measurements and time resolved current transient measurements have yielded an average charge collection efficiency approaching 100 %. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of tellurium inclusions within the detector bulk. Further, it has been shown that the role of tellurium inclusions in degrading chargecollection is reduced with increasing values of bias voltage. The electron transit time was determined from time of flight measurements. From the dependence of drift velocity on applied electric field the electron mobility was found to be n = (718 55) cm2/Vs at room temperature.

Kim K.; Rafiel, R.; Boardman, M.; Reinhard, I.; Sarbutt, A.; Watt, G.; Watt, C.; Uxa, S.; Prokopovich, D.A.; Belas, E.; Bolotnikov, A.E.; James, R.B.

2012-04-11T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster  

SciTech Connect (OSTI)

The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

2005-09-06T23:59:59.000Z

222

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439  

E-Print Network [OSTI]

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

Haskel, Daniel

223

Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys  

E-Print Network [OSTI]

The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase...

Karaca, Haluk Ersin

2009-05-15T23:59:59.000Z

224

Effect of composition and heat treatment on MnBi magnetic materials  

SciTech Connect (OSTI)

The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of Mn–Bi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

2014-10-01T23:59:59.000Z

225

DOPING AND BOND LENGTH CONTRIBUTIONS TO Mn K-EDGE SHIFT IN La1-xSrxMnO3 AND THEIR CORRELATION WITH ELECTRICAL TRANSPORT BEHAVIOUR.  

SciTech Connect (OSTI)

The experimental Mn K-edge x-ray absorption spectra of La{sub 1-x}Sr{sub x}MnO{sub 3}, x = 0 - 0.7 are compared with the band structure calculations using spin polarized density functional theory. It is explicitly shown that there is a correspondence between the inflection point on the absorption edge and the center of gravity of the unoccupied Mn 4p-band. This correspondence has been used to separate the doping and size contributions to edge shift due to variation in number of electrons in valence band and Mn-O bond lengths, respectively when Sr is doped into LaMnO{sub 3}. Such separation is helpful to find the localization behavior of charge carriers and to understand the observed transport properties and type of charge carrier participating in the conduction process in these compounds.

PANDEY,S.K.; KHALID,S.; BINDU, R.; KUMAR, A.; PIMPALE, A.V.

2006-12-04T23:59:59.000Z

226

Clean Cities: Detroit Area Clean Cities coalition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Clean Cities coalition Contact Information Sean Reed (Acting) 734-585-5720 x18 reed@cec-mi.org Coalition Website Clean Cities Coordinator Sean Reed (Acting) Sean Reed (Acting) is...

227

SmartBuildings Detroit commercial case study  

Broader source: Energy.gov [DOE]

This is a document from BetterBuilds for Michigan posted on the website of the U.S. Department of Energy's Better Buildings Neighborhood Program website.

228

State University di Detroit ed esperto  

E-Print Network [OSTI]

quali Lean Six Sigma, Design For Six Sigma, Lean Management; opera in settori diversi tra cui alimentare la presentazione dei risultati sui progetti Lean Six Sigma seguiti da Leanprove, il Forum ha visto la Leanprove ha lavorato su quasi 500 progetti di miglioramento Lean Six Sigma in di- versi settori

VandeVord, Pamela

229

Clean Cities: Detroit Area Clean Cities coalition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationClean Communities of Western New York (Buffalo)Denver Metro

230

Detroit, MI Natural Gas Exports to Canada  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 4623 42YearDelawareDetails of U.S.80

231

Detroit Auto Show 2012 | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy CooperationRequirements Matrix U.S. Department of|ALDeterminations and

232

Detroit Commuter Hydrogen Project | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Company AgreesDesiree PipkinsSuper ESPC BestDOE5

233

Ricardo Detroit Technical Center | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginia Blue Ridge AndREIIReykjanes GeothermalFalls,

234

Detroit, Michigan: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision has beenFinancialSilverUsing

235

Effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals  

SciTech Connect (OSTI)

The results of studying the effect of a high electric field on the conductivity of MnGa{sub 2}S{sub 4}, MnIn{sub 2}S{sub 4}, and MnGaInS{sub 4} single crystals are reported. The activation energy is determined in high and low electric fields. It is established that the decrease in the activation energy with increasing the external voltage is associated with decreasing the depth of the potential well, in which the electron is located.

Niftiev, N. N. [Azerbaijan State Pedagogical University (Azerbaijan); Tagiev, O. B. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-09-15T23:59:59.000Z

236

IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE  

E-Print Network [OSTI]

IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

Paris-Sud XI, Université de

237

Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

2012-08-17T23:59:59.000Z

238

Structural Changes in the Mn(4)Ca Cluster And the Mechanism of Photosynthetic Water Splitting  

SciTech Connect (OSTI)

Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn{sub 4}Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiprotein assembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn{sub 4}Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S{sub 0} through S{sub 3}, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn{sub 4}Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S{sub 2}-to-S{sub 3} and S{sub 3}-to-S{sub 0} transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S{sub 2} state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

2009-05-21T23:59:59.000Z

239

Structural Changes in the Mn4Ca Cluster and the Mechanism of Photosynthetic Water Splitting  

SciTech Connect (OSTI)

Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn4Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiproteinassembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn4Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S0 through S3, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn4Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S2-to-S3 and S3-to-S0 transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S2 state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

2007-10-25T23:59:59.000Z

240

Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4  

E-Print Network [OSTI]

correlate well with the better cycling performance of Al-doped LiMn2O4 in our Li-ion battery tests: LiAl0Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4 Yuan Yang, Chong Xie nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials

Cui, Yi

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

I - Matter, antimatter and geometry II - The twin universe model : a solution to the problem of negative energy particles III - The twin universe model plus electric charges and matter-antimatter symmetry  

E-Print Network [OSTI]

We introduce a new dynamical group whose coadjoint action on its momentum space takes account of matter-antimatter symmetry on pure geometrical grounds. According to this description the energy and the spin are unchanged under matter-antimatter symmetry. We recall that the antichron components of the Poincar\\'{e} group, ruling relativistic motions of a mass-point particle, generate negative energy particles. The model with two twin universes, inspired by Sakharov's one, solves the stability issue. Positive and negative energy particles motions hold in two distinct folds. The model is extended to charged particles. As a result, the matter-antimatter duality holds in both universes.

Frederic Henry-Couannier; Gilles D'Agostini; Jean-Pierre Petit

2005-03-09T23:59:59.000Z

242

Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors  

SciTech Connect (OSTI)

Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

Yan, Jun; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Cheng, Jie [Research Institute of Chemical Defense, Beijing 100083 (China)] [Research Institute of Chemical Defense, Beijing 100083 (China); Fan, Zhuangjun, E-mail: fanzhj666@163.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

2010-02-15T23:59:59.000Z

243

Metastable phase boundaries of quasicrystalline phases. [Al-Mn; Al-Ru  

SciTech Connect (OSTI)

The melting curve (T/sub 0/) of the metastable icosahedral phase and the liquidus of the decagonal phase of Al-Mn have been obtained for 14 to 22 at. % Mn. Icosahedral Al-Mn has a congruent melting point of 910 +- 20/sup 0/C at 20 at. % Mn, and melts approx.30/sup 0/C lower than crystalline compounds with the same composition. Icosahedral Al/sub 82/Ru/sub 18/ was determined to melt at 1260 +- 30/sup 0/C. These results were obtained by forming single-phase icosahedral alloys with ion beam mixing, and by rapid heating to accurately known temperatures with electron beams.

Follstaedt, D.M.; Knapp, J.A.

1987-01-01T23:59:59.000Z

244

Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge  

SciTech Connect (OSTI)

Transition metals such as Mn generally have large local moments in covalent semiconductors due to their partially filled d shells. However, Mn magnetization in group-IV semiconductors is more complicated than often recognized. Here we report a striking crossover from a quenched Mn moment (<0.1 {mu}{sub B}) in amorphous Si (a-Si) to a large distinct local Mn moment ({ge}3{mu}{sub B}) in amorphous Ge (a-Ge) over a wide range of Mn concentrations (0.005-0.20). Corresponding differences are observed in d-shell electronic structure and the sign of the Hall effect. Density-functional-theory calculations show distinct local structures, consistent with different atomic density measured for a-Si and a-Ge, respectively, and the Mn coordination number N{sub c} is found to be the key factor. Despite the amorphous structure, Mn in a-Si is in a relatively well-defined high coordination interstitial type site with broadened d bands, low moment, and electron (n-type) carriers, while Mn in a-Ge is in a low coordination substitutional type site with large local moment and holes (p-type) carriers. Moreover, the correlation between N{sub c} and the magnitude of the local moment is essentially independent of the matrix; the local Mn moments approach zero when N{sub c} > 7 for both a-Si and a-Ge.

Zeng, Li; Cao, J. X.; Helgren, E.; Karel, J.; Arenholz, E.; Ouyang, Lu; Smith, David J.; Wu, R. Q.; Hellman, F.

2010-06-01T23:59:59.000Z

245

Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure  

SciTech Connect (OSTI)

The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}???55 ?C/cm{sup 2} obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290?K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ?123?emu/cm{sup 3}. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

2014-09-21T23:59:59.000Z

246

Twin Oaks Landscape, Inc. is seeking additional highly-qualified green industry professionals to manage and operate our growing business; such candidates shall possess attributes of accountability, integrity, passion,  

E-Print Network [OSTI]

clients in the areas of landscape maintenance, drainage solutions and design and build projects. We winTwin Oaks Landscape, Inc. is seeking additional highly-qualified green industry professionals Experienced Snow Plow Skid and/or Truck Drivers Snow Shovelers Executive Summary Twin Oaks Landscape, Inc

Isaacs, Rufus

247

MN Office of Energy Security | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpIncMAKGalway Bay IEOWCCatcher.pngWavemill <MN Office of Energy

248

Thermal Stability of MnBi Magnetic Materials. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability of MnBi Magnetic Materials.

249

Electronic Structure and Oxidation State Changes in the Mn4Ca Cluster of Photosystem II  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn4Ca cluster) of Photosystem II cycles through five intermediate states (Si-states, i =0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn4(III2,IV2) and Mn4(III,IV3) for S1 and S2 states, while it is still controversial for the S0 and S3 states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn4Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mncomplexes. The spectral changes in the Mn 1s2p3/2 RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S0 to S1, and S1 to S2 transitions is twice as large as that during the S2 to S3 transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

Yano, Junko; Pushkar, Yulia; Messinger, Johannes; Bergmann, Uwe; Glatzel, Pieter; Yachandra, Vittal K

2007-08-03T23:59:59.000Z

250

Protective effects of ebselen (Ebs) and para-aminosalicylic acid (PAS) against manganese (Mn)-induced neurotoxicity  

SciTech Connect (OSTI)

Chronic, excessive exposure to manganese (Mn) may induce neurotoxicity and cause an irreversible brain disease, referred to as manganism. Efficacious therapies for the treatment of Mn are lacking, mandating the development of new interventions. The purpose of the present study was to investigate the efficacy of ebselen (Ebs) and para-aminosalicylic acid (PAS) in attenuating the neurotoxic effects of Mn in an in vivo rat model. Exposure biomarkers, inflammatory and oxidative stress biomarkers, as well as behavioral parameters were evaluated. Co-treatment with Mn plus Ebs or Mn plus PAS caused a significant decrease in blood and brain Mn concentrations (compared to rats treated with Mn alone), concomitant with reduced brain E{sub 2} prostaglandin (PGE{sub 2}) and enhanced brain glutathione (GSH) levels, decreased serum prolactin (PRL) levels, and increased ambulation and rearing activities. Taken together, these results establish that both PAS and Ebs are efficacious in reducing Mn body burden, neuroinflammation, oxidative stress and locomotor activity impairments in a rat model of Mn-induced toxicity. -- Highlights: ? The manuscript is unique in its approach to the neurotoxicity of Mn. ? The manuscript incorporates molecular, cellular and functional (behavioral) analyses. ? Both PAS and Ebs are effective in restoring Mn behavioral function. ? Both PAS and Ebs are effective in reducing Mn-induced oxidative stress. ? Both PAS and Ebs led to a decrease in Mn-induced neuro-inflammation.

Marreilha dos Santos, A.P., E-mail: apsantos@ff.ul.pt [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Lucas, Rui L.; Andrade, Vanda; Mateus, M. Luísa [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Milatovic, Dejan; Aschner, Michael [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Batoreu, M. Camila [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)

2012-02-01T23:59:59.000Z

251

Application of an all-solid-state, frequency-doubled Nd:YAP laser to the generation of twin beams at 1080 nm  

E-Print Network [OSTI]

A laser-diode-pumped intracavity frequency-doubled Nd:YAP/KTP laser is presented. Over 110 mw of TEM00 single-frequency output power at 540-nm wavelength was obtained. The output green laser was employed to pump a semimonolithic nondegenerate optical parametric oscillator to produce intensity quantum correlated twin beams at 1080 nm, and the maximum quantum noise squeezing of 74 %(5.9 dB) on the intensity difference fluctuation between the twin beams is observed. The threshold was reduced and the stability was increased significantly when compared with similar lamp-pumped systems.

Ruixiang Guo; Julien Laurat; Jiangrui Gao; Changde Xie; Kunchi Peng

2005-12-04T23:59:59.000Z

252

Minnesota Innovation Partnerships (MN-IP) Try and Buy MN-IP Try and Buy --for companies interested in licensing existing U of M inventions  

E-Print Network [OSTI]

is executed BUY (LICENSE) · Low, published royalty rate, with first $1 million of product sales royalty-free · Royalty rates based on industry comparables · Royalty rate discount for MN operating companies2 · Royalty

Minnesota, University of

253

Exchange interaction mediated ferroelectricity in multiferroic MnTiO{sub 3} with anisotropic orbital hybridization and hole delocalization  

SciTech Connect (OSTI)

We present the orbital structure of MnTiO{sub 3} with polarization dependent x-ray absorption and resonant x-ray emission spectra accompanied with electronic structure calculations. The results clearly indicate a strongly anisotropic O 2p-Mn 3d orbital hybridization whereas the Mn 3d hole state shows a highly delocalized characteristic ascribed to the 3d-4p mixing. The extended Mn 4p orbital could enhance the exchange interaction between Mn (3d)-O (2p)-Mn (3d) leading to an asymmetric charge distribution in Mn-O bonds. The delocalized characteristic of Mn 3d holes is indispensable to the mechanism of spin-dependent-metal-ligand hybridization to explain magnetically induced ferroelectricity.

Chen, S. W.; Fu, S. W.; Lee, J. M.; Lee, J. F.; Pao, C. W.; Ishii, H.; Tsuei, K. D.; Hiraoka, N.; Lu, K. T.; Chen, J. M., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Lin, P. A. [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Jeng, H. T., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Chen, D. P.; Dou, S. X.; Wang, X. L., E-mail: jeng@phys.nthu.edu.tw, E-mail: xiaolin@uow.edu.au, E-mail: jmchen@nsrrc.org.tw [Institute for Superconducting and Electronic Materials, Australian Institute of Innovative, Materials, University of Wollongong, North Wollongong, NSW 2500 (Australia)

2014-02-24T23:59:59.000Z

254

An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS Characterisations.  

E-Print Network [OSTI]

An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS.loyau@satie.ens-cachan.fr Abstract AC resistivity measurement results on Mn-Zn sintered ferrite were analyzed in the 0.1-500 MHz of the main limitations in frequency increase is the energy dissipations by losses in ferrites that produce

Boyer, Edmond

255

Short communication The composite rods of MnO and multi-walled carbon nanotubes as  

E-Print Network [OSTI]

Short communication The composite rods of MnO and multi-walled carbon nanotubes as anode materialsO as an anode material for lithium ion batteries are significantly improved. The MnO/MWNTs composite shows a Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong

Ceder, Gerbrand

256

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn  

E-Print Network [OSTI]

resembling the oxygen-evolving complex (OEC) in photosystem II and dimanganese catalase enzymes, resulting+ and Zn2LAc+ , the two metal centers are bridged by an acetate ligand. [Mn2LAc](ClO4)·(DMF)0.5, [Mn2LAc for substrate molecules bound to redox active metal centers.5-10 In 1970, Robson showed that dinuclear tetrakis

Dinolfo, Peter H.

257

Semimetallic antiferromagnetism in the half-Heusler compound CuMnSb Ruben Weht,2  

E-Print Network [OSTI]

CuMnSb, the first antiferromagnet AFM in the Mn-based class of Heuslers and half-Heuslers that contains several conventional and half metallic ferromagnets, shows a peculiar stability of its magnetic order in high magnetic fields. Density functional based studies reveal an unusual nature of its unstable

Pickett, Warren

258

NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network [OSTI]

Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

Hwang, S.

2010-01-01T23:59:59.000Z

259

Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma,  

E-Print Network [OSTI]

Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma, Burak Guzelturk, Talha report white-light-emitting Mn-doped ZnSe nanocrystals (NCs) that are synthesized using modified orange emission (580 nm), allowed us to achieve excitation wavelength tailorable white-light generation

Demir, Hilmi Volkan

260

Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1  

E-Print Network [OSTI]

Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. ©2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

austenitnoj cr-mn stali: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cr-mn stali First Page Previous Page 1 2 3 4 5 6 Next Page Last Page Topic Index 1 Cavitation erosion of laser processed Fe-Cr-Mn and Fe-Cr-Co alloys CiteSeer Summary: Received...

262

Surface alloys of icosahedral AlMnSi with phason distortions  

SciTech Connect (OSTI)

The microstructures produced by electron-beam melting and by ion-beam mixing Al/Mn and Al/Mn/Si layers on Si substrates are examined. The treatments were found to incorporate Si from the substrate into the surface alloy. Several phases formed, depending on treatment, including ..cap alpha..- and ..beta..-AlMnSi, ..mu..-AlMn (epitaxial on Si(111), and amorphous and icosahedral AlMnSi. The observed microstructures relate the novel icosahedral phase to other phases and elucidate its formation kinetics. Diffraction patterns from large icosahedral grains (up to 5 ..mu..m) show distortions in the position and shape of weak (but not strong) reflections, as predicted for phason defects in a quasicrystalline lattice, one of the structures proposed for icosahedral phases.

Follstaedt, D.M.; Knapp, J.A.

1986-12-01T23:59:59.000Z

263

Structural and Magnetic Properties of Co-Mn-Sb Thin films  

SciTech Connect (OSTI)

Thin Co-Mn-Sb films of different compositions were investigated and utilized as electrodes in alumina based magnetic tunnel junctions with CoFe counterelectrode. The preparation conditions were optimized with respect to magnetic and structural properties. The Co-Mn-Sb/Al-O interface was analyzed by x-ray absorption spectroscopy and magnetic circular dichroism with particular focus on the element-specific magnetic moments. Co-Mn-Sb crystallizes in different complex cubic structures depending on its composition. The magnetic moments of Co and Mn are ferromagnetically coupled in all cases. A tunnel magnetoresistance ratio of up to 24% at 13 K was found and indicates that Co-Mn-Sb is not a ferromagnetic half-metal. These results are compared to recent works on the structure and predictions of the electronic properties.

Meinert, M.; Schmalhorst, J.-M.; Ebke, D.; Liu, N. N.; Thomas, A.; Reiss, G.; Kanak, J.; Stobiecki, T.; Arenholz, E.

2009-12-17T23:59:59.000Z

264

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

SciTech Connect (OSTI)

We investigate the magnetic properties of the isostructural spinel-spinel interface of NiMn{sub 2}O{sub 4}(NMO)-Fe{sub 3}O{sub 4}. Although the magnetic transition temperature of the NMO film is preserved, both bulk and interface sensitive measurements demonstrate that the interface exhibits strong interfacial magnetic coupling up to room temperature. While NMO thin films have a ferrimagnetic transition temperature of 60 K, both NiFe{sub 2}O{sub 4} and MnFe{sub 2}O{sub 4} are ferrimagnetic at room temperature. Our experimental results suggest that these magnetic properties arise from a thin interdiffused region of (Fe,Mn,Ni){sub 3}O{sub 4} at the interface, leading to Mn and Ni magnetic properties similar to those of MnFe{sub 2}O{sub 4} and NiFe{sub 2}O{sub 4}.

Arenholz, Elke; Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Bettinger, J. S.; Arenholz, E.; Suzuki, Y.

2007-09-13T23:59:59.000Z

265

Neutron diffraction study of MnNiGa{sub 2}—Structural and magnetic behaviour  

SciTech Connect (OSTI)

MnNiGa{sub 2} crystallizes in the L21 (Heusler) structure and has a ferromagnetic ordering temperature T{sub C}???192?K. Rietveld refinement of the neutron diffraction patterns indicates that the Ga atoms occupy the equivalent 8c position, while Mn and Ni share the 4a (0, 0, 0) and 4b (0.5, 0.5, 0.5) sites with a mixed occupancy of Mn and Ni atoms. It is found that that ?83% of Mn and ?17% Ni are located at the 4a site while ?83% of Ni and ?17% Mn occupy the 4b site. There is no evidence of a magneto-volume effect around T{sub C}. In agreement with this finding, our detailed critical exponent analyses of isothermal magnetization curves and the related Arrott plots confirm that the magnetic phase transition at T{sub C} is second order.

Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Ma, L.; Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China); Hofmann, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Avdeev, M.; Kennedy, S. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Md Din, M. F.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Hoelzel, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Fachbereich Materialwissenschaften, Technische Universität Darmstadt, 64287 Darmstadt (Germany)

2014-05-07T23:59:59.000Z

266

Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,  

E-Print Network [OSTI]

Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

Cui, Yi

267

Electronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment  

E-Print Network [OSTI]

, Louisiana 70118 Received 27 November 2001; published 24 July 2002 The electronic structure of the Mn-based determined recently by Kurmoo and Kepert.2,3 More recently, x-ray structure of the Mn-based material has beenElectronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment M. R

Liu, Amy Y.

268

1Electricity from Sunlight: The Van Allen Probes Solar Panels NASA's twin Van Allen Probes spacecraft will be launched in 2012. The  

E-Print Network [OSTI]

1Electricity from Sunlight: The Van Allen Probes Solar Panels NASA's twin Van Allen Probes of the surrounding four solar panel `wings' that provide power to the spacecraft instruments. The small blue rectangles within each of the four solar panels show the location of the solar cells used to power

269

NONLINEAR OPTICAL EFFECTS IN ROTATIONALLY-TWINNED CRYSTALS: AN EVALUATION OF CdTe, ZnTe AND ZnSe  

E-Print Network [OSTI]

-frequency and wavelength- tunable radiation from the ultraviolet to the far infrared region of the spectrum. Typical optical coefficients, (iii) the crystal must resist damage at the high power densities required405 NONLINEAR OPTICAL EFFECTS IN ROTATIONALLY-TWINNED CRYSTALS: AN EVALUATION OF CdTe, ZnTe AND Zn

Boyer, Edmond

270

Hazard Analysis of Mortality Among Twins and Triplets in the United States: From 20 Weeks Gestation Through the First Year of Life  

E-Print Network [OSTI]

efforts or grasps? (Siegel and Swanson, 2004: 371-371). These recommendations were put into place to ensure that the vital registration data derived from birth and death certificates are valid and reliable. This will ensure the highest possible........................................................................ 10 Trends of Twin and Triplet Births in the United States ................. 10 Defining and Measuring Fetal and Infant Mortality ...................... 12 The Importance of Infant Mortality...

DeSalvo, Bethany S.

2011-08-08T23:59:59.000Z

271

Magnetic phase diagram of magnetoelectric LiMnPO4  

SciTech Connect (OSTI)

The nature of the spin-flop (SF) transition in the magnetoelectric quasi-2D Heisenberg system LiMnPO4 is studied in fields applied along the a axis. A refinement of the magnetic structure using neutron diffraction data in the SF phase reveals that the spins reorient from being parallel to the a axis to be nearly along the c axis at magnetic fields between 4 and 4.7 T, depending on temperature. The low-field antiferromagnetic phase boundary is shown to join the spin-flop line tangentially at the so-called bicritical point, where there is a suppression of the ordering temperature. At the bicritical field, we observe an increased intensity of the Lorentz broadened elastic scattering at magnetic Bragg peaks above TN as compared to zero field and 10 T, without an increase in peak width. This suggests an increased density of fluctuations at the bicritical field as compared to zero field.

Toft-Petersen, Rasmus; Andersen, Niels H.; Li, Haifeng; Li, Jiying; Tian, Wei; Budko, Serguei L.; Jensen, Thomas B.S.; Niedermayer, Christof; Laver, Mark; Zaharko, Oksana; Lynn, Jeffrey W.; Vaknin, David

2012-06-14T23:59:59.000Z

272

Low-temperature magnetization of (Ga,Mn) As semiconductors  

E-Print Network [OSTI]

of the Zeeman Hamil- tonian gS#3;BBS?z+gj#3;BBj?z, and from Eq. #1;1#2;: m ? mMF #14; mQF = ? #3;B j S + j #1;gS ? gj#2; . #1;5#2; When j=1/2 and gS=gj =2 the quantum fluctuation correc- tion to the magnetization vanishes even though the mean- field...Low-temperature magnetization of (Ga,Mn)As semiconductors T. Jungwirth,1,2 J. Ma?ek,3 K. Y. Wang,2 K. W. Edmonds,2 M. Sawicki,4 M. Polini,5 Jairo Sinova,6 A. H. MacDonald,7 R. P. Campion,2,8 L. X. Zhao,2,8 N. R. S. Farley,2,8 T. K. Johal,8 G. van...

Jungwirth, T.; Masek, J.; Wang, KY; Edmonds, KW; Sawicki, M.; Polini, M.; Sinova, Jairo; MacDonald, AH; Campion, RP; Zhao, LX; Farley, NRS; Johal, TK; van der Laan, G.; Foxon, CT; Gallagher, BL.

2006-01-01T23:59:59.000Z

273

Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)  

SciTech Connect (OSTI)

We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH{sub 4}) and methylgermane (CH{sub 3}GeH{sub 3}) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of 0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of 16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

Guchhait, S.; Jamil, M.; Ohldag, H.; Mehta, A.; Arenholz, E.; Lian, G.; Li Fatou, A.; Ferrer, D. A.; Markert, J. T.; Colombo, L.; Banerjee, S. K.

2011-01-05T23:59:59.000Z

274

Ferrimagnetism and disorder of epitaxial Mn2-xCoxVAl Heusler compound thin films  

SciTech Connect (OSTI)

The quaternary full Heusler compound Mn{sub 2-x}Co{sub x}VAl with x = 1 is predicted to be a half-metallic antiferromagnet. Thin films of the quaternary compounds with x = 0-2 were prepared by dc and RF magnetron co-sputtering on heated MgO (0 0 1) substrates. The magnetic structure was examined by x-ray magnetic circular dichroism and the chemical disorder was characterized by x-ray diffraction. Ferrimagnetic coupling of V to Mn was observed for Mn{sub 2}VAl (x = 0). For x = 0.5, we also found ferrimagnetic order with V and Co antiparallel to Mn. The observed reduced magnetic moments are interpreted with the help of band structure calculations in the coherent potential approximation. Mn{sub 2}VAl is very sensitive to disorder involving Mn, because nearest-neighbour Mn atoms couple antiferromagnetically. Co{sub 2}VAl has B2 order and has reduced magnetization. In the cases with x {ge} 0.9 conventional ferromagnetism was observed, closely related to the atomic disorder in these compounds.

Meinert, Markus; Schmalhorst, Jan-Michael; Reiss, Gunter; Arenholz, Elke

2011-01-29T23:59:59.000Z

275

Framework-incorporated Mn and Co analcime zeolites: Synthesis and characterization  

SciTech Connect (OSTI)

The framework-substituted cobalt and manganese analcime zeolites were synthesized via a direct hydrothermal approach. The obtained samples were characterized by XRD powder, SEM-EDX, nitrogen physical adsorption, Raman microscopy, diffuse reflectance UV-Vis and IR spectroscopy which complementarily demonstrated the incorporation of cobalt and manganese into the zeolites framework. The results showed that substitution of Mn and Co could be placed in two synthesis gels with same compositions containing Al/Mn=5 and Al/Co=4 mol ratios, respectively. In addition, with replacing Al with Mn and synthesis of Mn-modified analcime, zeolite with higher surface area and pore volume could be achieved than the Co modified analcime. - Graphical abstract: The images and adsorption-desorption isotherms of N{sub 2} at 77 K for (a) Co (b) Mn modified analcime. Highlights: Black-Right-Pointing-Pointer Synthesis of Co and Mn modified analcime for the first time. Black-Right-Pointing-Pointer Framework-incorporation of Co and Mn using the same silicate gel composition. Black-Right-Pointing-Pointer Applying several techniques to provide proofs for the characterization.

Azizi, Seyed Naser, E-mail: azizi@umz.ac.ir [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of); Ehsani Tilami, Salma [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)] [Analytical Division, Faculty of Chemistry, University of Mazandaran, P.O. Box 47416-95447, Babolsar (Iran, Islamic Republic of)

2013-02-15T23:59:59.000Z

276

Large interface diffusion in endotaxial growth of MnP films on GaP substrates  

SciTech Connect (OSTI)

The metal organic vapor deposition of MnP films on GaP (100) substrates is shown to have a substantial endotaxial component. A study of the growth time evolution of the endotaxial depths of MnP grains reveals a diffusion-controlled growth with a relatively large diffusion coefficient of Mn in GaP. The value (2.2?±?1.5)?×?10{sup ?15} (cm{sup 2}/s) obtained at 650?°C is at least two orders of magnitude larger than the reported Mn diffusion in bulk GaP. GaP surface mounds provide further indirect evidence that this large diffusion coefficient is concurrent with the out-diffusion of Ga atoms at the growing MnP/GaP interface. No trace of dislocations could be observed at or near this interface, which strongly suggests that Mn diffusion occurs through vacant sites generated by the difference between the crystallographic structures of MnP and GaP.

Nateghi, N., E-mail: seyyed-nima.nateghi@polymtl.ca; Ménard, D.; Masut, R. A. [Regroupement québécoise sur les matériaux de pointe (RQMP), Département de Génie Physique, Polytechnique Montréal, C.P. 6079, succ. Centre-ville, Montréal, Québec H3C 3A7 (Canada)

2014-10-07T23:59:59.000Z

277

Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ  

SciTech Connect (OSTI)

The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

2008-03-19T23:59:59.000Z

278

DAFS study of site-specific local structure of Mn in manganese ferrite films.  

SciTech Connect (OSTI)

Manganese ferrite (MnFe{sub 2}O{sub 4}) is a well-known magnetic material widely used in electronics for many years. It is well established that its magnetic behavior is strongly influenced by local structural properties of Mn ions, which are distributed between crystallographically inequivalent tetrahedral and octahedral sites in the unit cell. In order to understand and be able to tune properties of these structures, it is necessary to have detailed site-specific structural information on the system. Here we report on the application of diffraction-anomalous fine structure (DAFS) spectroscopy to resolve site-specific Mn local structures in manganese ferrite films. The DAFS measurements were done at undulator beamline 4-ID-D of the Advanced Photon Source at Argonne National Laboratory. The DAFS spectra (Fig. 1) were measured at several Bragg reflections in the vicinity of the Mn absorption K-edge, having probed separately contributions from tetrahedrally and octahedrally coordinated Mn sites. The DAFS data analysis done with an iterative Kramers-Kroenig algorithm made it possible to solve separately the local structure around different inequivalent Mn sites in the unit cell. The reliability of the data treatment was checked carefully, and it was showed that the site-specific structural parameters obtained with DAFS allow us to describe fluorescence EXAFS spectrum measured independently. Fig. 2 shows individual site contributions to the imaginary part of the resonant scattering amplitude obtained from the treatment of the data of Fig. 1. The analysis of the refined site-specific absorption spectra was done using EXAFS methods based on theoretical standards. We provided direct evidence for the tetrahedral Mn-O bond distance being increased relative to the corresponding Fe-O distance in bulk manganese ferrites. The first coordination shell number was found to be reduced significantly for Mn atoms at these sites. This finding is consistent with the well-known tendency of Mn to be tetrahedrally coordinated in these compounds.

Kravtsov, E.; Haskel, D.; Cady, A.; Yang, A.; Vittoria, C.; Zuo, X.; Harris, V. G.; X-Ray Science Division; Inst. of Metal Physics; Northeastern Univ.; Nankai Univ.

2006-01-01T23:59:59.000Z

279

Melt-Mixing by Novel Pitched-Tip Kneading Disks in a co-rotating Twin-Screw Extruder  

E-Print Network [OSTI]

Melt-mixing in twin-screw extruders is a key process for development of polymer composites, and quantification of mixing performance of kneading elements based on the physical process in them is a challenging problem. We discuss melt-mixing by novel kneading elements, called "pitched-tip kneading disk (ptKD)". Disk-stagger angle and tip angle are the main geometrical parameters of the ptKDs. We investigated four typical arrangements of the ptKDs, which are forwarding and backwarding disk-staggers combined with forwarding and backwarding tips, respectively. Numerical simulations under a certain feed rate and screw revolution speed were performed and mixing process was investigated by using Lagrangian statistics. It is found that the four types had different mixing characteristics, and their mixing processes were explained by a coupling effect of drag flow by disk staggering and pitched-tip and pressure flow, which is controlled by operational conditions.

Nakayama, Yasuya; Shigeishi, Takashi; Tomiyama, Hideki; Kajiwara, Toshihisa

2010-01-01T23:59:59.000Z

280

Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot  

E-Print Network [OSTI]

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

Trojnar, A; Kadantsev, E; Hawrylak, P; Goryca, M; Kazimierczuk, T; Kossacki, P; Wojnar, P; Potemski, M

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Quantum interference in exciton-Mn spin interactions in a CdTe semiconductor quantum dot  

E-Print Network [OSTI]

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole correlations, the short and long range exchange interaction of Mn ion with the heavy hole and with electron and anisotropy of the quantum dot, is compared with photoluminescence spectroscopy of CdTe dots with single magnetic ions. We show how design of the electronic levels of a quantum dot enable the design of an exciton, control of the quantum interference and hence engineering of light-Mn interaction.

A. Trojnar; M. Korkusinski; E. Kadantsev; P. Hawrylak; M. Goryca; T. Kazimierczuk; P. Kossacki; P. Wojnar; M. Potemski

2011-05-04T23:59:59.000Z

282

Melting point measurements for quasicrystalline phases. [Al-Mn; icosahedral and decagonal phases  

SciTech Connect (OSTI)

Melting transitions of metastable quasicrystalline phases of Al-Mn have been observed using rapid electron-beam heating of fine-grained icosahedral surface layers. The congruent melting point for icosahedral Al/sub 80/Mn/sub 20/ was directly measured to be 910 +- 20/sup 0/C. Heating to higher temperatures shows another transition which is inferred to correspond to the liquidus of the decagonal phase at 965 +- 20/sup 0/C for 20 at. % Mn. The microstructure and formation kinetics of the decagonal phase are discussed, and its electron diffraction is described.

Knapp, J.A.; Follstaedt, D.M.

1986-01-01T23:59:59.000Z

283

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

E-Print Network [OSTI]

Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

Nelson-Cheeseman, B. B.

2007-01-01T23:59:59.000Z

284

Synthesis and characterization of MnPS{sub 3} for hydrogen sorption  

SciTech Connect (OSTI)

Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

Ismail, N., E-mail: nahlaismail24@yahoo.co [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Temerk, Y.M. [Assiut University, Faculty of Science, Chemistry Department, Assuit (Egypt); El-Meligi, A.A. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Badr, M.A. [Mechanical Engineering Department, Cairo (Egypt); Madian, M. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt)

2010-05-15T23:59:59.000Z

285

Electrode Characteristics of Individual, MnO2 Coated Carbon Nanotubes  

E-Print Network [OSTI]

MnO2 Coated Carbon Nanotubes Brad L. Corso, Israel Perez,single- walled carbon nanotubes. Li ion cyclic voltammetrysingle-walled carbon nanotubes (SWNTs) that are grown in

Collins, Philip G

2011-01-01T23:59:59.000Z

286

Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition  

E-Print Network [OSTI]

LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

Xia, Hui

287

Frequency Response of Acoustic-Assisted Ni–Mn–Ga Ferromagnetic- Shape-Memory-Alloy Actuator  

E-Print Network [OSTI]

A prototype of Ni–Mn–Ga based ferromagnetic-shape-memory-alloy (FSMA) actuator was designed and built; an acoustic-assist technique was applied to the actuator to enhance its performance. A piezoelectric stack actuator was ...

Techapiesancharoenkij, Ratchatee

288

Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column  

E-Print Network [OSTI]

Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

Wehrli, Bernhard

289

DOI: 10.1002/ejic.200700164 Chlorido-Bridged MnII  

E-Print Network [OSTI]

geometry sharing an equatorial-to-axial edge with parallel equatorial planes. The hydrogen bonds be,[3] dicyanamide,[4] and car- boxylate.[5] Ferromagnetic exchange coupling among these MnII compounds

Gao, Song

290

Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals  

E-Print Network [OSTI]

Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

Techapiesancharoenkij, Ratchatee, 1979-

2007-01-01T23:59:59.000Z

291

Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1  

E-Print Network [OSTI]

Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano

Sparks, Donald L.

292

Prospects for high temperature ferromagnetism in (Ga,Mn)As semiconductors  

E-Print Network [OSTI]

-quality metallic samples increases linearly with the number of uncompensated local moments on Mn-Ga acceptors, with no sign of saturation. Room temperature ferromagnetism is expected for a 10% concentration of these local moments. Our magnetotransport...

Jungwirth, T.; Wang, KY; Masek, J.; Edmonds, KW; Konig, J.; Sinova, Jairo; Polini, M.; Goncharuk, NA; MacDonald, AH; Sawicki, M.; Rushforth, AW; Campion, RP; Zhao, LX; Foxon, CT; Gallagher, BL.

2005-01-01T23:59:59.000Z

293

Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy  

E-Print Network [OSTI]

Radiation-induced DNA damage is a precursor to mutagenesis and cytotoxicity. During radiotherapy, exposure of healthy tissues can lead to severe side effects. We explored the potential of mitochondrial SOD (MnSOD) gene ...

Niu, Yunyun

294

E-Print Network 3.0 - alloy ni-mn-ga single Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mathematics 35 Lattice dynamics and phonon softening in Ni-Mn-Al Heusler alloys Xavier Moya, Llus Maosa,* and Antoni Planes Summary: as 10% have been re- ported in single...

295

Effect of MnAs/GaAs(001) film accommodations on the phase-transition temperature  

SciTech Connect (OSTI)

The phase-transition temperature of MnAs epitaxial films grown by molecular-beam epitaxy on GaAs(001) with different crystalline accommodations was studied by specular and grazing incidence x-ray diffraction. The transition temperature of MnAs films with tilted hexagonal c-axis orientations with respect to the GaAs substrate is higher than the most investigated nontilted films and reaches a value above room temperature, which is more suitable for device applications.

Iikawa, F.; Brasil, M.J.S.P.; Couto, O.D.D.; Adriano, C.; Giles, C.; Daeweritz, L. [Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970 (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970, Brazil and Laboratorio Nacional de Luz Sincrotron, CP-6192, 13084-971 Campinas-SP (Brazil); Paul-Drude-Institut fuer Festkoerperelektronik, Hausvogteiplatz 5-7, 10117 Berlin (Germany)

2004-09-20T23:59:59.000Z

296

DC electrodeposition of Mn–Co alloys on stainless steels for SOFC interconnect application  

SciTech Connect (OSTI)

High conductivity coatings that resist oxide scale growth and reduce chromium evaporation are needed to make stainless steel interconnect materials viable for long-term stable operation of solid oxide fuel cells (SOFC). Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conductivity, good chromium retention capability, as well as good CTE match to ferritic stainless steels. Mn–Co electrodeposition followed by oxidization is potentially a low cost method for fabrication of (Mn,Co)3O4 spinel coatings. This work looks at the co-deposition of Mn–Co alloys for this application. As a guide to optimize the deposition process, characterizations of the cathodic reactions and reaction potentials are done using polarization curves. It was found that as cobalt concentration was varied that the alloy composition became richer in cobalt, indicating that the deposition is regular co-deposition process. It was also found that at 0.05M Co concentration in excess gluconate the Mn–Co alloys composition could be tuned by varying the current density. Coatings with Mn–Co around 1:1 could be obtained at a current density of 250 mA/cm2. However, the higher potential increased hydrogen production making the films more porous. Oxidation of the alloy coatings showed that much of the porosities could be eliminated during oxidation. It was found in a number of samples that fully dense coatings where obtained. The composition of the oxidized coating was found to become enriched in Mn, possibly due to the Mn fast diffusion from the substrate.

Wu, Junwei; Jiang, Yinglu; Johnson, Christopher; Liu, Xingbo

2008-03-01T23:59:59.000Z

297

(In,Mn)As quantum dots: Molecular-beam epitaxy and optical properties  

SciTech Connect (OSTI)

Self-assembled (In,Mn)As quantum dots are synthesized by molecular-beam epitaxy on GaAs (001) substrates. The experimental results obtained by transmission electron microscopy show that doping of the central part of the quantum dots with Mn does not bring about the formation of structural defects. The optical properties of the samples, including those in external magnetic fields, are studied.

Bouravleuv, A. D., E-mail: bour@mail.ioffe.ru; Nevedomskii, V. N. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Ubyivovk, E. V. [St. Petersburg State University (Russian Federation)] [St. Petersburg State University (Russian Federation); Sapega, V. F. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Khrebtov, A. I. [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation)] [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation); Samsonenko, Yu. B.; Cirlin, G. E.; Ustinov, V. M. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

2013-08-15T23:59:59.000Z

298

Magneto acoustical emission in nanocrystalline Mn–Zn ferrites  

SciTech Connect (OSTI)

Graphical abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE. - Highlights: • The AE been measured along the hysteresis loops from 80 K to Curie temperature. • The MAE activity along hysteresis loop is proportional to P{sub h} during the same loop. • It is found that the domain wall creation/or annihilation processes are the origin of the MAE. - Abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE.

Praveena, K., E-mail: praveenaou@gmail.com [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Department of Physics, Osmania University, Hyderabad 500007 (India); Murthty, S.R. [Department of Physics, Osmania University, Hyderabad 500007 (India)

2013-11-15T23:59:59.000Z

299

Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

Pei, L.Z., E-mail: lzpei@ahut.edu.cn; Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

2013-07-15T23:59:59.000Z

300

Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites  

SciTech Connect (OSTI)

This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

2013-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


301

Calcium EXAFS establishes the Mn-Ca cluster in the oxygen-evolving complex of Photosystem II  

SciTech Connect (OSTI)

The proximity of Ca to the Mn cluster of the photosynthetic water-oxidation complex is demonstrated by X-ray absorption spectroscopy. We have collected EXAFS data at the Ca K-edge using active PS II membrane samples that contain approximately 2 Ca per 4 Mn. These samples are much less perturbed than previously investigated Sr-substituted samples, which were prepared subsequent to Ca depletion. The new Ca EXAFS clearly shows backscattering from Mn at 3.4 angstroms, a distance that agrees with that surmised from previously recorded Mn EXAFS. This result is also consistent with earlier related experiments at the Sr K-edge, using samples that contained functional Sr, that show Mn is {approx}; 3.5 angstroms distant from Sr. The totality of the evidence clearly advances the notion that the catalytic center of oxygen evolution is a Mn-Ca heteronuclear cluster.

Cinco, Roehl M.; McFarlane Holman, Karen L.; Robblee, John H.; Yano, Junko; Pizarro, Shelly A.; Bellacchio, Emanuele; Sauer, Kenneth; Yachandra, Vittal K.

2002-08-02T23:59:59.000Z

302

Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions  

SciTech Connect (OSTI)

Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

2009-03-15T23:59:59.000Z

303

PVP-Assisted ZrO2 coating on LiMn2O4 spinel cathode nanoparticles prepared by MnO2 nanowire templates  

E-Print Network [OSTI]

solution. Upon annealing at 600 °C in air, an amorphous ZrO2 nanoscale coating layer was obtained [5­10]. Although Li-ion batteries are attractive power-storage devices that have high energy density metal oxide coatings have been reported, studies to improve both the rate capabilities of spinel LiMn2O4

Cho, Jaephil

304

X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes  

SciTech Connect (OSTI)

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and the metal ion 1s level (valence-to-core XES). The spectra, in connection with calculations based on density functional theory (DFT), provide information that is complementary to other spectroscopic techniques, in particular X-ray absorption (XANES and EXAFS). The spectral shape is sensitive to protonation of ligands and allows ligands, which differ only slightly in atomic number (e.g., C, N, O...), to be distinguished. A theoretical discussion of the main spectral features is presented in terms of molecular orbitals for a series of Mn model systems: [Mn(H2O)6]2+, [Mn(H2O)5OH]+, [Mn(H2O)5NH2]+, and [Mn(H2O)5NH3]2+. An application of the method, with comparison between theory and experiment, is presented for the solvated Mn2+ ion in water and three Mn coordination complexes, namely [LMn(acac)N3]BPh4, [LMn(B2O3Ph2)(ClO4)], and [LMn(acac)N]BPh4, where L represents 1,4,7-trimethyl-1,4,7-triazacyclononane, acac stands for the 2,4-pentanedionate anion, and B2O3Ph2 represents the 1,3-diphenyl-1,3-dibora-2-oxapropane-1,3-diolato dianion.

Smolentsev, Grigory; Soldatov, Alexander V; Messinger, Johannes; Merz, Kathrin; Weyhermuller, Thomas; Bergmann, Uwe; Pushkar, Yulia; Yano, Junko; Yachandra, Vittal K.; Glatzel, Pieter

2009-03-02T23:59:59.000Z

305

Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes  

SciTech Connect (OSTI)

Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

2012-11-15T23:59:59.000Z

306

The geochemical evolution of the Sonju Lake intrusion: assimilation and fractional crystallization in a layered mafic intrusion near Finland, Mn.  

E-Print Network [OSTI]

??The Sonju Lake Intrusion, located within the Beaver Bay Complex near Finland, MN, is the most completely differentiated intrusion related to the Midcontinent Rift System… (more)

Dayton, Ryan N.

2011-01-01T23:59:59.000Z

307

The Ring Nebula Around the Blue Supergiant SBW1: Pre-Explosion Snapshot of a SN 1987A Twin  

E-Print Network [OSTI]

SBW1 is a B supergiant surrounded by a ring nebula that is a nearby twin of SN 1987A. We present images and spectra of SBW1 obtained with HST, Spitzer, and Gemini South. HST images of SBW1 do not exhibit long Rayleigh-Taylor fingers, which are presumed to cause the hotspots in the SN1987A ring, but instead show a geometrically thin clumpy ring. The radial mass distribution and size scales of inhomogeneities in SBW1's ring closely resemble those in the SN1987A ring, but the more complete disk expected to reside at the base of the RT fingers is absent. This structure may explain why portions of the SN1987A ring between the hotspots have not yet brightened after more than 15 years. The model we suggest does not require a fast wind colliding with a previous red supergiant wind. More surprisingly, images of SBW1 also reveal diffuse emission filling the interior of the ring in H-alpha and thermal-IR emission; 190K dust dominates the 8-20 micron luminosity (but contains only 1e-5Msun). Cooler (85K dust resides in th...

Smith, Nathan; Bally, John; Ginsburg, Adam; Filippenko, Alexei V

2012-01-01T23:59:59.000Z

308

Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution  

SciTech Connect (OSTI)

Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

West, J. Palmer; Sulejmanovic, Dino [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States); Becht, Gregory [E. I. du Pont, Wilmington, DE 19880-0500 (United States); He, Jian; Hitchcock, Dale [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Yan, Yonggao [Wuhan University of Technology, Wuhan 430070 (China); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States)

2013-10-15T23:59:59.000Z

309

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

SciTech Connect (OSTI)

The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

2007-08-01T23:59:59.000Z

310

Oxidation State Changes of the Mn(4)Ca Cluster in Photosystem II  

SciTech Connect (OSTI)

A detailed electronic structure of the Mn{sub 4}Ca cluster is required before two key questions for understanding the mechanism of photosynthetic water oxidation can be addressed. They are whether all four oxidizing equivalents necessary to oxidize water to O{sub 2} accumulate on the four Mn ions of the oxygen-evolving complex, or do some ligand-centered oxidations take place before the formation and release of O{sub 2} during the S{sub 3} {yields} [S{sub 4}] {yields} S{sub 0} transition, and what are the oxidation state assignments for the Mn during S-state advancement. X-ray absorption and emission spectroscopy of Mn, including the newly introduced resonant inelastic X-ray scattering spectroscopy have been used to address these questions. The present state of understanding of the electronic structure and oxidation state changes of the Mn{sub 4}Ca cluster in all the S-states, particularly in the S{sub 2} to S{sub 3} transition, derived from these techniques is described in this review.

Yano, J.; Yachandra, V.K.

2009-06-04T23:59:59.000Z

311

Magnetoresistance in Mn ion-implanted GaAs:Zn nanowires  

SciTech Connect (OSTI)

We have investigated the magnetoresistance (MR) in a series of Zn doped (p-type) GaAs nanowires implanted with different Mn concentrations. The nanowires with the lowest Mn concentration (?0.0001%) exhibit a low resistance of a few k? at 300?K and a 4% positive MR at 1.6?K, which can be well described by invoking a spin-split subband model. In contrast, nanowires with the highest Mn concentration (4%) display a large resistance of several M? at 300?K and a large negative MR of 85% at 1.6?K. The large negative MR is interpreted in terms of spin-dependent hopping in a complex magnetic nanowire landscape of magnetic polarons, separated by intermediate regions of Mn impurity spins. Sweeping the magnetic field back and forth for the 4% sample reveals a hysteresis that indicates the presence of a weak ferromagnetic phase. We propose co-doping with Zn to be a promising way to reach the goal of realizing ferromagnetic Ga{sub 1?x}Mn{sub x}As nanowires for future nanospintronics.

Paschoal, W.; Kumar, Sandeep; Jain, V.; Pettersson, H., E-mail: hakan.pettersson@hh.se [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Department of Mathematics, Physics and Electrical Engineering, Halmstad University, Box 823, SE-301 18, Halmstad (Sweden); Jacobsson, D.; Samuelson, L. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Johannes, A.; Ronning, C. [Institute for Solid State Physics, Friedrich-Schiller-University Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Canali, C. M.; Pertsova, A. [Department of Physics and Electrical Engineering, Linneaus University, SE-39233 Kalmar (Sweden); Dick, K. A. [Solid State Physics/The Nanometer Structure Consortium, Lund University, Box 118, SE-221 00 Lund (Sweden); Center for Analysis and Synthesis, Lund University, Box 124, S-221 00 Lund (Sweden)

2014-04-14T23:59:59.000Z

312

Carbon/lambda-MnO{sub 2} composites for supercapacitor electrodes  

SciTech Connect (OSTI)

In the present work a composite of carbon with lambda-MnO{sub 2} have been synthesized by a simple two-step route. In the first step, to obtain LiMn{sub 2}O{sub 4}/carbon material, mesoporous activated carbon was impregnated with the solution of precursor metal salts and heated subsequently. As-prepared materials were acid treated which resulted in the formation of lambda-MnO{sub 2}/carbon. Physical properties, structure and specific surface area of electrode materials were studied by TEM, X-ray diffraction and nitrogen sorption measurements. Voltammetry cycling, galvanostatic charge/discharge and impedance spectroscopy measurements performed in two- and three-electrode cells have been applied in order to measure electrochemical parameters. TEM images confirmed well dispersed lambda-MnO{sub 2} particles on the surface of carbon material. The carbon in the composite plays an important role as the surface area enhancing component and a support of pseudocapacitive material. Furthermore, the through-connected porosity serves as a continuous pathway for electrolyte transport. A synergetic effect of the porous carbon framework and of the redox properties of the lambda-MnO{sub 2} is at the origin of improvement of specific capacitance values which has been observed for composites after delithiation. - Comparison of capacitance characteristics for initial carbon and synthesised composites for CB in 1 mol L{sup -1} Na{sub 2}SO{sub 4} solution.

Malak-Polaczyk, A., E-mail: agnieszka-malak@wp.p [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland); Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Matei-Ghimbeu, C.; Vix-Guterl, C. [Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Frackowiak, E. [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland)

2010-04-15T23:59:59.000Z

313

Unique light-induced degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor  

SciTech Connect (OSTI)

Photo-induced luminescence intensity degradation in yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K{sub 2}SiF{sub 6}:Mn{sup 2+} phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (??=?325?nm)?>?Ar{sup +} (488?nm)?>?He–Ne laser (632.8?nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn{sup 2+} to Mn{sup 3+} by the photooxidation (Mn{sup 2+} ? Mn{sup 3+}) or disproportionation reaction (2Mn{sup 2+} ? Mn{sup +} + Mn{sup 3+}). The ESR measurement confirms the decreased Mn{sup 2+} spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn{sup 3+} ions occurs through energy transfer upon absorption of exciting radiation by the Mn{sup 2+} ions. Thermal annealing of the degraded samples at ?200?°C causes a blueshift in the PL emission band with an appearance of the Mn{sup 4+}-related sharp red emission lines.

Oyama, Takuya; Adachi, Sadao, E-mail: adachi@el.gunma-u.ac.jp [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu-shi, Gunma 376-8515 (Japan)

2014-10-07T23:59:59.000Z

314

Anomalously large spin susceptibility enhancement in n-doped CdMnTe quantum wells  

SciTech Connect (OSTI)

We report on time-resolved Kerr rotation (TRKR) experiments done on n-doped CdMnTe quantum wells (QWs), in the regime where strong coupling between the electron and the Mn spin-flip excitations shows up. It has been proposed previously to deduce the 2D electron gas spin susceptibility from the coupling energy between these spin excitations. Here we measure the coupling energy on a high mobility sample down to very low excitation density, and compare the results with spin-flip Raman scattering (SFRS) on the same sample. The electron spin polarizations measured by TRKR and SFRS are found in relatively good agreement. However the spin susceptibility measured by TRKR exceeds systematically the values predicted by many-body theory. This could be an indication that the two-oscillator model used to describe mixed electron-Mn spin excitations needs to be improved.

Ben Cheikh, Z. [Laboratoire Charles Coulomb, UMR 5221, Département Semi-conducteurs, Matériaux et Capteurs, Université Montpellier 2, France and Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté (Tunisia); Cronenberger, S.; Vladimirova, M.; Scalbert, D. [Laboratoire Charles Coulomb, UMR 5221, Departement Semi-conducteurs, Materiaux et Capteurs, Universite Montpellier 2 (France); Boujdaria, K. [Laboratoire de Physique des Matériaux: Structures et Propriétés, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna (Tunisia); Baboux, F.; Perez, F. [Institut des NanoSciences de Paris, CNRS/Université Paris 6, 4 place Jussieu, F-75005 Paris (France); Wojtowicz, T.; Karczewski, G. [Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland)

2013-12-04T23:59:59.000Z

315

In-situ spectro-microscopy on organic films: Mn-Phthalocyanine on Ag(100)  

SciTech Connect (OSTI)

Metal phthalocyanines are attracting significant attention, owing to their potential for applications in chemical sensors, solar cells and organic magnets. As the electronic properties of molecular films are determined by their crystallinity and molecular packing, the optimization of film quality is important for improving the performance of organic devices. Here, we present the results of in situ low-energy electron microscopy / photoemission electron microscopy (LEEM/PEEM) studies of incorporation-limited growth [1] of manganese-phthalocyanine (MnPc) on Ag(100) surfaces. MnPc thin films were grown on both, bulk Ag(100) surface and thin Ag(100)/Fe(100) films, where substrate spin-polarized electronic states can be modified through tuning the thickness of the Ag film [2]. We also discuss the electronic structure and magnetic ordering in MnPc thin films, investigated by angle- and spin-resolved photoemission spectroscopy.

Al-Mahboob A.; Vescovo, E.; Sadowski, J.T.

2013-08-18T23:59:59.000Z

316

The resistance to cavitation erosion of CrMnN stainless steels  

SciTech Connect (OSTI)

The resistance to cavitation erosion (CE) was measured using a magnetostrictive device and a rotating disk device for some CrMnN stainless steels (Chinese patent ZL 90 1 02197.0). The microstructural changes in the surface layer before and after CE were analyzed by use of Mossbauer spectra. Results show that the resistance to CE of duplex austenitic-martensitic CrMnN stainless steels is much better than that of ZG0Cr13Ni4-6Mo and ZG0Cr16Ni5Mo steel, which are in common use for hydraulic turbine runners. The metastable austenite and its changes in the process of CE are the key factors why the CrMnN stainless steels have excellent resistance to cavitation erosion.

Fu, W.T. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Harbin Inst. of Tech. (China); Jing, T.F.; Zheng, Y.Z. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; Yang, Y.B. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Bohai Aluminum Industries Co., Ltd., Qinhuangdao (China); Yao, M. [Harbin Inst. of Tech. (China)] [Harbin Inst. of Tech. (China)

1998-12-01T23:59:59.000Z

317

Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers  

SciTech Connect (OSTI)

Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

2014-08-18T23:59:59.000Z

318

Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides  

SciTech Connect (OSTI)

Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

2014-10-23T23:59:59.000Z

319

Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling,  

E-Print Network [OSTI]

is performed by the oxygen-evolving center (OEC) of photo- system II (PSII).2 The OEC consists of a Mn4Ca, United States *S Supporting Information ABSTRACT: The oxygen-evolving complex (OEC) of photo- system IIOxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based

Goddard III, William A.

320

First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang  

E-Print Network [OSTI]

First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang Department to calculate the ground state, transition tem- perature, and thermodynamic properties of magnetic excitations in spinel MnO2 . The magnetic interactions are mapped onto a Heisenberg model whose exchange interactions

Ceder, Gerbrand

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Zn Sorption Mechanisms onto Sheathed Leptothrix Discophora and the Impact of the Nanoparticulate Biogenic Mn Oxide Coating  

SciTech Connect (OSTI)

Zinc sorption on sheathed Leptothrix discophora bacterium, the isolated extracellular polymeric substances (EPS) sheath, and Mn oxide-coated bacteria was investigated with macroscopic and spectroscopic techniques. Complexation with L. discophora was dominated by the outer membrane phosphoryl groups of the phospholipid bilayer while sorption to isolated EPS was dominated by carboxyl groups. Precipitation of nanoparticulate Mn oxide coatings on the cell surface increased site capacity by over twenty times with significant increase in metal sorption. XAS analysis of Zn sorption in the coated system showed Mn oxide phase contributions of 18 to 43% through mononuclear inner-sphere complexes. The coordination environments in coprecipitation samples were identical to those of sorption samples, indicating that, even in coprecipitation, Zn is not incorporated into the Mn oxide structure. Rather, through enzymatic oxidation by L. discophora, Mn(II) is oxidized and precipitated onto the biofilm providing a large surface for metal sequestration. The nanoparticulate Mn oxide coating exhibited significant microporosity (75%) suggesting contributions from intraparticle diffusion. Transient studies conducted over 7 months revealed a 170% increase in Zn loading. However, the intraparticle diffusivity of 10{sup -19} cm{sup 2} s{sup -1} is two orders of magnitude smaller than that for abiotic Mn oxide which we attribute to morphological changes such as reduced pore sizes in the nanoparticulate oxide. Our results demonstrate that the cell-bound Mn oxide particles can sorb significant amounts of Zn over long periods of time representing an important surface for sequestration of metal contaminants.

Boonfueng, T.; Axe, L; Yee, N; Hahn, D; Ndiba, P

2009-01-01T23:59:59.000Z

322

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy AlAin MAnceAu,1,  

E-Print Network [OSTI]

Cedex 9, France 2 Advanced Light Source, Lawrence Berkeley National Laboratory, One Cyclotron Road and phyllomanganates with no or little Mn3+ in the MnO2 layer exhibit intensi- ties, shapes, and relative energy catalysis, hazardous waste remediation, and rechargeable battery technology (Thackeray 1997; Toupin et al

323

MnO spin-wave dispersion curves from neutron powder diffraction  

SciTech Connect (OSTI)

We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

Goodwin, Andrew L.; Dove, Martin T. [Department of Earth Sciences, Cambridge University, Downing Street, Cambridge CB2 3EQ (United Kingdom); Tucker, Matthew G. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Keen, David A. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics, Oxford University, Clarendon Laboratory, Parks Road, Oxford OX1 3PU (United Kingdom)

2007-02-15T23:59:59.000Z

324

A study of magnetic anisotropy energy in CuMn spin glass  

E-Print Network [OSTI]

A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1986... Major Subject: Physics A STUDY OF MAGNETIC ANISOTROPY ENERGY IN CuMn SPIN GLASS A Thesis by CHRISTINE ADELE ALLEN Approved as to style and content by: Thomas W. Adair, III (Chai man of Committee) Robert A. enefick (Member) Donald L. Parker...

Allen, Christine Adele

1986-01-01T23:59:59.000Z

325

Thickness dependent exchange bias in martensitic epitaxial Ni-Mn-Sn thin films  

SciTech Connect (OSTI)

A thickness dependent exchange bias in the low temperature martensitic state of epitaxial Ni-Mn-Sn thin films is found. The effect can be retained down to very small thicknesses. For a Ni{sub 50}Mn{sub 32}Sn{sub 18} thin film, which does not undergo a martensitic transformation, no exchange bias is observed. Our results suggest that a significant interplay between ferromagnetic and antiferromagnetic regions, which is the origin for exchange bias, is only present in the martensite. The finding is supported by ab initio calculations showing that the antiferromagnetic order is stabilized in the phase.

Behler, Anna [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Department of Physics, Institute for Solid State Physics, Dresden University of Technology, 01062 Dresden (Germany); Teichert, Niclas; Auge, Alexander; Hütten, Andreas [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany)] [Department of Physics, Thin Films and Physics of Nanostructures, Bielefeld University, 33501 Bielefeld (Germany); Dutta, Biswanath; Hickel, Tilmann [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany)] [Max-Planck Institut für Eisenforschung, 40237 Düsseldorf (Germany); Waske, Anja [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany)] [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Eckert, Jürgen [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany) [IFW Dresden, Institute for Complex Materials, P.O. Box 27 01 16, 01171 Dresden (Germany); Institute of Materials Science, Dresden University of Technology, 01062 Dresden (Germany)

2013-12-15T23:59:59.000Z

326

Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

2013-06-01T23:59:59.000Z

327

The Comparative Exploration of the Ice Giant Planets with Twin Spacecraft: Unveiling the History of our Solar System  

E-Print Network [OSTI]

In the course of the selection of the scientific themes for the second and third L-class missions of the Cosmic Vision 2015-2025 program of the European Space Agency, the exploration of the ice giant planets Uranus and Neptune was defined "a timely milestone, fully appropriate for an L class mission". Among the proposed scientific themes, we presented the scientific case of exploring both planets and their satellites in the framework of a single L-class mission and proposed a mission scenario that could allow to achieve this result. In this work we present an updated and more complete discussion of the scientific rationale and of the mission concept for a comparative exploration of the ice giant planets Uranus and Neptune and of their satellite systems with twin spacecraft. The first goal of comparatively studying these two similar yet extremely different systems is to shed new light on the ancient past of the Solar System and on the processes that shaped its formation and evolution. This, in turn, would reveal whether the Solar System and the very diverse extrasolar systems discovered so far all share a common origin or if different environments and mechanisms were responsible for their formation. A space mission to the ice giants would also open up the possibility to use Uranus and Neptune as templates in the study of one of the most abundant type of extrasolar planets in the galaxy. Finally, such a mission would allow a detailed study of the interplanetary and gravitational environments at a range of distances from the Sun poorly covered by direct exploration, improving the constraints on the fundamental theories of gravitation and on the behaviour of the solar wind and the interplanetary magnetic field.

Diego Turrini; Romolo Politi; Roberto Peron; Davide Grassi; Christina Plainaki; Mauro Barbieri; David M. Lucchesi; Gianfranco Magni; Francesca Altieri; Valeria Cottini; Nicolas Gorius; Patrick Gaulme; François-Xavier Schmider; Alberto Adriani; Giuseppe Piccioni

2014-09-11T23:59:59.000Z

328

Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes  

SciTech Connect (OSTI)

Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

Chen Yong [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Key Laboratory of Tropic Biological Resources, MOE, Hainan University, 58 Renmin Road, Haikou 570228 (China); Liu Chenguang; Liu Chang [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Lu Gaoqing [ARC Centre for Functional Nanomaterials, Australian Institute of Bioengineering and Nanotechnology, University of Queensland, QLD 4072 (Australia); Cheng Huiming [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China)], E-mail: cheng@imr.ac.cn

2007-11-06T23:59:59.000Z

329

Effect of Ti doping on high pressure behavior of BiMn{sub 2}O{sub 5}  

SciTech Connect (OSTI)

Our high pressure x-ray diffraction studies on BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} show iso-structural phase transition above 12 GPa similar to the one observed in undoped BiMn{sub 2}O{sub 5}; however anisotropic compressional behavior is found to be more enhanced in the doped case. Unlike undoped system, an anomalous lattice expansion along c axis has been observed in BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} above 12 GPa; whereas the b lattice parameter has been found to be more compressible as compared to BiMn{sub 2}O{sub 5}. As doping with Ti reduces the magnetic interactions among Mn ions, the observed changes are suggestive of having adverse magnetic implications in the observed iso-structural phase transition.

Pandey, K. K., E-mail: kkpandey@barc.gov.in; Poswal, H. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 40008 (India); Kumar, Ravi [Centre for Materials Science and Engineering, National Institute of Technology, Hamirpur-177005 (India)

2014-04-24T23:59:59.000Z

330

Redox Exchange Induced MnO2 Nanoparticle Enrichment in Poly(3,4-ethylenedioxythiophene) Nanowires for Electrochemical Energy Storage  

SciTech Connect (OSTI)

MnO{sub 2} nanoparticle enriched poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires are fabricated by simply soaking the PEDOT nanowires in potassium permanganate (KMnO{sub 4}) solution. The structures of these MnO{sub 2} nanoparticle enriched PEDOT nanowires are characterized by SEM and TEM, which show that the MnO{sub 2} nanoparticles have uniform sizes and are finely dispersed in the PEDOT matrix. The chemical constituents and bonding of these composite nanowires are characterized by energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, and infrared spectroscopy, which indicate that the formation and dispersion of these MnO{sub 2} nanoparticles into the nanoscale pores of the PEDOT nanowires are most likely triggered by the reduction of KMnO{sub 4} via the redox exchange of permanganate ions with the functional group on PEDOT. Varying the concentrations of KMnO{sub 4} and the reaction time controls the loading amount and size of the MnO{sub 2} nanoparticles. Cyclic voltammetry and galvanostatic charge?discharge are used to characterize the electrochemical properties of these MnO{sub 2} nanoparticle loaded PEDOT nanowires. Due to their extremely high exposed surface area with nanosizes, the pristine MnO{sub 2} nanoparticles in these MnO{sub 2} nanoparticle enriched PEDOT nanowires show very high specific capacitance (410 F/g) as the supercapacitor electrode materials as well as high Li+ storage capacity (300 mAh/g) as cathode materials of Li ion battery, which boost the energy storage capacity of PEDOT nanowires to 4 times without causing excessive volume expansion in the polymer. The highly conductive and porous PEDOT matrix facilitates fast charge/discharge of the MnO{sub 2} nanoparticles and prevents them from agglomerating. These synergic properties enable the MnO{sub 2} nanoparticle enriched PEDOT nanowires to be promising electrode materials for supercapacitors and lithium ion batteries.

Liu, R; Duay, Jonathon; Lee, Sang Bok

2010-01-01T23:59:59.000Z

331

Local Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual  

E-Print Network [OSTI]

Form Contact utility owners Utility Contact List available at http://www.dot.state.mn.us/utility/files/pdf/contacts/contact-utilityLocal Agency Project Manager Checklist The steps below follow those outlined in the Mn/DOT Utility Manual. A PDF of the manual and supporting documents are available at: http://www.dot.state.mn.us/utility

Minnesota, University of

332

Atomic and molecular adsorption on RhMn alloy surface: A first principles study  

E-Print Network [OSTI]

and hydrogen from reforming of natural gas and coal to hydro- carbon Fishcher-Tropsch synthesis and oxygenates- bon and partial oxidation of methane.15 The importance of Rh catalysts on catalytic reactions molecules in terms of the energetics and site preferences on Rh catalysts as well as the effects of Mn added

Li, Weixue

333

Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3  

E-Print Network [OSTI]

Crystallography of Interfaces and Grain Size Distributions in Sr-Doped LaMnO3 Qinyuan Liu,§ Sudip systems are similar. I. Introduction HIGH-TEMPERATURE solid oxide fuel cells (SOFCs) offer highly efficient, clean, direct conversion of chemical to electrical energy.1 SOFC performance is dictated

Rohrer, Gregory S.

334

Frustration and multiferroic behavior in Ca3CoMnO6  

SciTech Connect (OSTI)

Lu{sub 2}MnCoO{sub 6} and Ca{sub 3}MnCoO{sub 6} satisfy one of the primary goals of multiferroics research, namely ferromagnetic-like magnetization coupled to ferroelectric-like polarization. Thus the mechanism for magnetoelectric coupling in these materials deserves careful study. New data shows that the physics of these compound may be related to the classic 'ANNNI' model. Frustration between ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions between Ising spins creates an 'up up down down' magnetic structure in zero magnetic field, along c-axis chains that consist of alternating Co and Mn ions. In applied magnetic fields 'up up down,' 'up up up down' and other metastable variations can evolve, yielding hysteretic ferromagnetic-like magnetization. The key is that the phase slips between regions of 'up' and 'down' carries an electric polarization due to broken spatial inversion symmetry. Thus these phase slips can be manipulated with both electric and magnetic fields. The result is a profusion of magnetic and electric states that are closely-spaced in temperature, electric, and magnetic field. We present experimental studies of the magnetic, electric, and structural properties of these two compounds. We include very new data up to 100 Ton Ca{sub 3}CoMnO{sub 6} that resolves a key controversy of over the magnetic structure and the size of the moments.

Zapf, Vivien [Los Alamos National Laboratory

2012-06-01T23:59:59.000Z

335

Optical properties of metallic (III, Mn)V ferromagnetic semiconductors in the infrared to visible range  

E-Print Network [OSTI]

We report on a study of the ac conductivity and magneto-optical properties of metallic ferromagnetic (III, Mn)V semiconductors in the infrared to visible spectrum at zero temperature. Our analysis is based on the successful kinetic exchange model...

Hankiewicz, EM; Jungwirth, T.; Dietl, T.; Timm, C.; Sinova, Jairo.

2004-01-01T23:59:59.000Z

336

Microscopic mechanism of the noncrystalline anisotropic magnetoresistance in (Ga,Mn)As  

E-Print Network [OSTI]

Starting with a microscopic model based on the Kohn-Luttinger Hamiltonian and kinetic p-d exchange combined with Boltzmann formula for conductivity we identify the scattering from magnetic Mn combined with the strong spin-orbit interaction of the Ga...

Vyborny, Karel; Kucera, Jan; Sinova, Jairo; Rushforth, A. W.; Gallagher, B. L.; Jungwirth, T.

2009-01-01T23:59:59.000Z

337

Synthesis and Characterization of NiMnGa Ferromagnetic Shape Memory Alloy Thin Films  

E-Print Network [OSTI]

, it is very important to understand their behavior and examine their properties. This thesis is an effort to contribute to the literature of Ni-Mn-Ga thin films as ferromagnetic shape memory alloys. The focus of this project is to develop a recipe...

Jetta, Nishitha

2011-10-21T23:59:59.000Z

338

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

SciTech Connect (OSTI)

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

339

Giant magnetothermal conductivity in the NiMnIn ferromagnetic shape memory alloys  

E-Print Network [OSTI]

­10 It is well known that colossal magne- toresistance CMR in the Mn-based perovskites is closely related, this transition can be shifted to lower temperature and even totally suppressed by a magnetic field. The magnetic: 10.1063/1.2753710 Very recently, Kainuma et al. discovered magnetic-field- induced shape recovery

Zexian, Cao

340

Modified magnetic ground state in NiMn2O4 thin films  

SciTech Connect (OSTI)

We demonstrate the stabilization of a magnetic ground state in epitaxial NiMn2O4 (NMO) thin films not observed in their bulk counterpart. Bulk NMO exhibits a magnetic transition from a paramagnetic phase to a collinear ferrimagnetic moment configuration below 110 K and to a canted moment configuration below 70 K. By contrast, as-grown NMO films exhibit a single magnetic transition at 60 K and annealed films exhibit the magnetic behavior found in bulk. Cation inversion and epitaxial strain are ruled out as possible causes for the new magnetic ground state in the as-grown films. However, a decrease in the octahedral Mn{sup 4+}:Mn{sup 3+} concentration is observed and likely disrupts the double exchange that produces the magnetic state at intermediate temperatures. X-ray magnetic circular dichroism and bulk magnetometry indicate a canted ferrimagnetic state in all samples at low temperature. Together these results suggest that the collinear ferrimagnetic state observed in bulk NMO at intermediate temperatures is suppressed in the as grown NMO thin films due to a decrease in octahedral Mn{sup 4+} while the canted moment ferrimagnetic ordering is preserved below 60 K.

Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Toney, M. F.; Arenholz, E.; Suzuki, Y.; Iwata, J.M.

2010-08-03T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Reduced-activation austenitic stainless steels: The Fe--Mn--Cr--C system  

SciTech Connect (OSTI)

Nickel-free manganese-stabilized steels are being developed for fusion-reactor applications. As the first part of this effort, the austenite-stable region in the Fe--Mn--Cr--C system was determined. Results indicated that the Schaeffler diagram developed for Fe--Ni--Cr--C alloys cannot be used to predict the constituents expected for high-manganese steels. This is true because manganese is not as strong an austenite stabilizer relative to delta-ferrite formation as predicted by the diagram, but it is a stronger austenite stabilizer relative to martensite than predicted. Therefore, the austenite-stable region for Ne--Mn--Cr--C alloys occurs at lower chromium and hugher combinations of manganese and carbon than predicted by the Schaeffler diagram. Development of a manganese-stabilized stainless steel should be possible in the composition range of 20 to 25% Mn, 10 to 15% Cr, and 0.01 to 0.25%C. Tensile behavior of an Fe--20%Mn--12%Cr--0.25%C alloy was determined. The strength and ductility of this possible base composition was comparable to type 316 stainless steel in both the solution-annealed and cold-worked condition.

Klueh, R.L.; Maziasz, P.J.

1988-01-01T23:59:59.000Z

342

Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application  

SciTech Connect (OSTI)

Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

2007-09-01T23:59:59.000Z

343

Electrical gating effects on the magnetic properties of (Ga,Mn)As diluted magnetic semiconductors  

E-Print Network [OSTI]

-effect transistor (FET) based on low-doped Ga0.975Mn0.025As was fabricated. It has an in-built n-GaAs back-gate, which, in addition to being a normal gate, enhances the gating effects, especially in the depletion of the epilayer, by decreasing the effective channel...

Owen, Man Hon Samuel

2010-11-16T23:59:59.000Z

344

Chobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC  

E-Print Network [OSTI]

by chronic carbon tetrachloride (CCl4) administration for 6 weeks, in combination with chronic; CCl4, carbon tetrachloride; CK19, cytokeratin 19; CCR2, chemokine C-C motif receptor 2; EMTChobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC CARBON

Boyer, Edmond

345

A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection  

SciTech Connect (OSTI)

We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

2014-03-14T23:59:59.000Z

346

Helical antiferromagnetic ordering in Lu1-xScxMnSi  

SciTech Connect (OSTI)

Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

Goetsch, Ryan J [Ames Laboratory; Anand, V K [Ames Laboratory; Johnston, David C [Ames Laboratory

2014-08-01T23:59:59.000Z

347

High-field electroluminescence in semiconductor tunnel junctions with a Mn-doped GaAs layer  

SciTech Connect (OSTI)

We investigated high-field electroluminescence (EL) in semiconductor tunnel junctions with a Mn-doped GaAs layer (here, referred to as GaAs:Mn). Besides the band-gap emission of GaAs, the EL spectra show visible light emissions with two peaks at 1.94?eV and 2.19?eV, which are caused by d-d transitions of the Mn atoms excited by hot electrons. The threshold voltages for band-gap and visible light EL in the tunnel junctions with a GaAs:Mn electrode are 1.3?V higher than those of GaAs:Mn excited by hot holes in reserve biased p{sup +}-n junctions, which is consistent with the hot carrier transport in the band profiles of these structures. Our EL results at room temperature show that the electron temperature in GaAs:Mn can be as high as ?700?K for a low input electrical power density of 0.4?W/cm{sup 2}, while the lattice temperature of the GaAs:Mn layer can be kept at 340?K.

Hai, Pham Nam [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-0033 (Japan); Yatsui, Takashi; Ohtsu, Motoichi; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Nanophotonics Research Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

2014-09-21T23:59:59.000Z

348

Correlated vortex pinning in slightly orthorhombic twinned Ba(Fe1-xCox)2As2 single crystals: Possible shift of the vortex-glass/liquid transition  

SciTech Connect (OSTI)

The interest in twin-boundary (TB) planes as a source of vortex pinning has been recently renewed with the discovery of the new iron-arsenide pnictide superconductors. In the family of compounds Ba(Fe1-xCox)2As2 a structural transition from a tetragonal to orthorhombic lattice takes place for compounds with xxcr) there is no twinning and we find good agreement with the expected scaling function under uncorrelated disorder, with small anisotropy values similar to those reported in the literature. We show that in the orthorhombic samples (x

Bermudez, M. Marziali [Universidad de Buenos Aires; Pasquini, G. [Universidad de Buenos Aires; Budko, Sergey L. [Ames Laboratory; Canfield, Paul C. [Ames Laboratory

2013-02-28T23:59:59.000Z

349

Discovery of a nearby twin of SN1987A's nebula around the luminous blue variable HD168625: Was Sk--69 202 an LBV?  

E-Print Network [OSTI]

Spitzer images of the luminous blue variable (LBV) candidate HD168625 reveal the existence of a bipolar nebula several times larger than its previously-known equatorial dust torus. The outer nebula of HD168625 has a full extent of about 80 arcsec or 0.85 pc, and one of the lobes has a well-defined polar ring. The nebula is a near twin of the triple-ring system around SN1987A. Because of these polar rings, and accounting for stellar/progenitor luminosity, HD168625 is an even closer twin of SN1987A than the B supergiant Sher 25 in NGC3603. HD168625's nebula was probably ejected during a giant LBV eruption and not during a red supergiant phase, so its similarity to the nebula around SN1987A may open new possibilities for the creation of SN1987A's rings. Namely, the hypothesis that Sk-69 202 suffered an LBV-like eruption would avert the complete surrender of single star models for its bipolar nebula by offering an alternative to an unlikely binary merger scenario. It also hints that LBVs are the likely progenitors of some type II supernovae, and that HD168625's nebula is a good example of a pre-explosion environment.

Nathan Smith

2006-11-16T23:59:59.000Z

350

Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

Jamer M.; Sterbinsky G.; Assaf, B.; Arena, D.; Heiman, D.

2014-12-07T23:59:59.000Z

351

Precipitation in cold-rolled Al–Sc–Zr and Al–Mn–Sc–Zr alloys prepared by powder metallurgy  

SciTech Connect (OSTI)

The effects of cold-rolling on thermal, mechanical and electrical properties, microstructure and recrystallization behaviour of the AlScZr and AlMnScZr alloys prepared by powder metallurgy were studied. The powder was produced by atomising in argon with 1% oxygen and then consolidated by hot extrusion at 350 °C. The electrical resistometry and microhardness together with differential scanning calorimetry measurements were compared with microstructure development observed by transmission and scanning electron microscopy, X-ray diffraction and electron backscatter diffraction. Fine (sub)grain structure developed and fine coherent Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles precipitated during extrusion at 350 °C in the alloys studied. Additional precipitation of the Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles and/or their coarsening was slightly facilitated by the previous cold rolling. The presence of Sc,Zr-containing particles has a significant antirecrystallization effect that prevents recrystallization at temperatures minimally up to 420 °C. The precipitation of the Al{sub 6}Mn- and/or Al{sub 6}(Mn,Fe) particles of a size ? 1.0 ?m at subgrain boundaries has also an essential antirecrystallization effect and totally suppresses recrystallization during 32 h long annealing at 550 °C. The texture development of the alloys seems to be affected by high solid solution strengthening by Mn. The precipitation of the Mn-containing alloy is highly enhanced by a cold rolling. The apparent activation energy of the Al{sub 3}Sc particles formation and/or coarsening and that of the Al{sub 6}Mn and/or Al{sub 6}(Mn,Fe) particle precipitation in the powder and in the compacted alloys were determined. The cold deformation has no effect on the apparent activation energy values of the Al{sub 3}Sc-phase and the Al{sub 6}Mn-phase precipitation. - Highlights: • The Mn, Sc and Zr additions to Al totally suppresses recrystallization at 550 °C. • The Sc,Zr-containing particle precipitation is slightly facilitated by cold rolling. • The Mn-containing particle precipitation is highly enhanced by cold rolling. • Cold rolling has no effect on activation energy of the Al{sub 3}Sc and Al{sub 6}Mn precipitation. • The texture development is affected by high solid solution strengthening by Mn.

Vlach, M., E-mail: martin.vlach@mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Stulikova, I.; Smola, B.; Kekule, T.; Kudrnova, H.; Danis, S. [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Gemma, R. [King Abdullah University of Science and Technology (KAUST), Physical Sciences and Engineering Division, 23955-6900 Thuwal (Saudi Arabia); Ocenasek, V. [SVÚM a.s., Podnikatelská 565, CZ-190 11 Prague (Czech Republic); Malek, J. [Czech Technical University in Prague, Faculty of Mechanical Engineering, CZ-120 00 Prague (Czech Republic); Tanprayoon, D.; Neubert, V. [Institut für Materialprüfung und Werkstofftechnik, Freiberger Strasse 1, D-38678 Clausthal-Zellerfeld (Germany)

2013-12-15T23:59:59.000Z

352

A Single Layer of Mn in a GaAs Quantum Well: A Ferromagnet with Quantum Fluctuations  

SciTech Connect (OSTI)

Some of the highest transition temperatures achieved for Mn-doped GaAs have been in &-doped heterostructures with well-separated planes of Mn. But in the absense of magnetic anisotropy, the Mermin-Wagner theorem implies that a single plane of magnetic ions cannot be ferromagnetic. We show that the same mechanism that produces magnetic frustration and suppresses the transition can stabilize ferromagnetic order for a single layer of Mn in a GaAs quantum well. But this comes at the price of quantum fluctuations that suppress the ordered moment from that of a fully saturated ferromagnet.

Melko, Roger G [ORNL; Fishman, Randy Scott [ORNL; Reboredo, Fernando A [ORNL

2007-01-01T23:59:59.000Z

353

Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping  

SciTech Connect (OSTI)

Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr; Baltz, V., E-mail: vincent.baltz@cea.fr, E-mail: helene.bea@cea.fr [SPINTEC, UMR 8191 CNRS/INAC-CEA/UJF-Grenoble 1/Grenoble-INP, F-38054 Cedex (France); Bailey, W. E., E-mail: web54@columbia.edu [Mat. Sci. and Engn. Program, Department of Appl. Phys. and Appl. Math., Columbia University, New York, New York 10027 (United States)

2014-01-20T23:59:59.000Z

354

Mn concentration dependent structural and optical properties of a-plane Zn{sub 0.99-x}Mn{sub x}Na{sub 0.01}O  

SciTech Connect (OSTI)

Non-polar a-plane (112{sup ¯}0) Zn{sub 0.99?x}Mn{sub x}Na{sub 0.01}O (x?=?0, 0.02, 0.03, 0.04, and 0.05) thin films have been prepared on r-plane (112{sup ¯}0) sapphire substrates by pulsed laser deposition (PLD). The influences of Mn content on the structural and optical properties of the films have been studied. It is indicated that moderate Mn doping facilitates the non-polar growth of ZnO, and all the doped films are single phase with a hexagonal wurtzite structure. The transmittance spectra suggested that all films are transparent in the visible region exhibiting a transmittance above 80%. Mn{sup 2+} doped Zn{sub 0.99}Na{sub 0.01}O shows an initial decrease of optical band gap (OBG) for small concentration of Mn, followed by a monotonic increase. The anomalous decrease in OBG for low concentrations of Mn is attributed to the strong exchange interaction present between the sp electrons of the host matrix and d electrons of Mn. Emission studies were also performed showing suppressed blue-shifted ultraviolet band and dominant violet-blue bands, which might originate from the zinc vacancy (V{sub Zn}) and zinc interstitial (Zn{sub i}) defects. The intensity of defect-related emission peaks is Mn doping-level-dependent as well and the results coincide well with that from the structural analyses.

Lu, B., E-mail: binlu@zju.edu.cn; Zhou, T. T.; Ma, M. J.; Ye, Y. H.; Ye, Z. Z.; Lu, J. G.; Pan, X. H. [State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

2013-12-14T23:59:59.000Z

355

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten and molybdenum species  

E-Print Network [OSTI]

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten.g.. the tungsten ion readily oxidizes in aqueous acid [A. Samotus and B. Kosowicz-Czajkowska, Rocz. Chem., 45, 1623

Bodner, George M.

356

Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

2011-08-01T23:59:59.000Z

357

Electronic Structure of a Paramagnetic {MNO}[superscript 6] Complex: MnNO 5,5-Tropocoronand  

E-Print Network [OSTI]

Using density functional theory (OLYP/STO-TZP) calculations, we have investigated the electronic structure of [Mn(5,5-tropocoronand)(NO)], a rare paramagnetic {MNO}6 complex. Experimental methods, including magnetic ...

Tangen, Espen

358

Prediction of O2 Dissociation Kinetics on LaMnO3-Based Cathode Materials for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

First-principles and statistical-theory calculations were applied to examine the interactions between oxygen molecules and the (100) surfaces of LaMnO3 and La0.5Sr0.5MnO2.75, one of the most-used cathode materials in solid oxide fuel cells (SOFCs). To predict the rate constants for the interactions between O2 and LaMnO3 or La0.5Sr0.5MnO2.75, potential energy profiles were constructed using the nudged elastic band (NEB) method. Predicted rate constants for the dissociation of adsorbed oxygen species on LaMnO3 (lm) and La0.5Sr0.5MnO2.75 (lsm) can be expressed as kdiss,lm ) 2.35 × 1012 exp(-0.50 eV/RT) s-1 and kdiss,lsm ) 2.15 × 1012 exp(-0.23 eV/RT) s-1, respectively, in the temperature range of 873-1273 K at 1 atm. Because the activation energy for oxygen dissociation on La0.5Sr0.5MnO2.75 (0.23 eV) is much smaller than that on LaMnO3 (0.50 eV), oxygen vacancies greatly enhance O2 dissociation kinetics. The kinetic and mechanistic studies for the interactions at the molecular level are imperative to gaining a fundamental understanding of oxygen reduction kinetics on cathode materials and to providing important insight into the rational design of more catalytically active cathode materials for SOFCs.

Choi, Yongman; Lynch, Matthew E.; Lin, M. C.; Liu, Meilin

2009-04-30T23:59:59.000Z

359

Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3  

E-Print Network [OSTI]

Risø-PhD-5 Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Anders Reves: Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3 Department: Materials Research Department of magneto- caloric and magnetoresistive properties of a series of polycrystalline Ca- and Sr- doped

360

Coulomb interaction of acceptors in Cd{sub 1?x}Mn{sub x}Te/CdTe quantum dot  

SciTech Connect (OSTI)

The investigation on the effect of confining potential like isotropic harmonic oscillator type potential on the binding and the Coulomb interaction energy of the double acceptors in the presence of magnetic field in a Cd{sub 1?x}Mn{sub x}Te/CdTe Spherical Quantum Dot has been made for the Mn ion composition x=0.3 and compared with the results obtained from the square well type potential using variational procedure in the effective mass approximation.

Kalpana, P.; Nithiananthi, P., E-mail: kjkumar-gri@rediffmail.com; Jayakumar, K., E-mail: kjkumar-gri@rediffmail.com [Department of Physics, Gandhigram Rural University, Gandhigram-624302, TamilNadu (India); Reuben, A. Merwyn Jasper D. [Department of Physics, School of Engineering, Saveetha University, Thandalam, Chennai- 600104, TamilNadu (India)

2014-04-24T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
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361

Characterization of Al-Mn particles in AZ91D investment castings  

SciTech Connect (OSTI)

Manganese is currently added to Mg-Al alloys in order to improve the corrosion behavior of cast components. A part of this manganese is dissolved in the magnesium matrix and the balance is found as fine Al(Mn,Fe) particles dispersed within castings. For AZ91D specimens prepared using the plaster mould investment casting process, these particles were observed in very large quantity at the surface of castings. These particles were characterized by scanning electron microscopy and electron probe microanalysis. It was found that they consist of Al{sub 8}Mn{sub 5} phase and that their morphology and size depend on local solidification conditions. Their presence at the surface of the castings is related to low solidification rates and reduced thermal gradients at the mould/metal interface.

Lun Sin, S. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada); Dube, D. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)], E-mail: dominique.dube@gmn.ulaval.ca; Tremblay, R. [Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec, Quebec, G1K 7P4 (Canada)

2007-10-15T23:59:59.000Z

362

Preparation and Magnetic Properties of MnBi-based Hard/Soft Composite Magnets  

SciTech Connect (OSTI)

Bulk anisotropic composite magnets based on MnBi/Co(Fe) exhibiting the different morphology of the soft magnetic phase were prepared by powder metallurgy processing. First, single-phase MnBi bulk magnets were produced using a maximum energy product [(BH)m] of 6.3 MGOe at room temperature. The nanoscale soft phase with the different morphology was then added to form a composite magnet. It was observed that addition of magnetic soft-phase nanoparticles and nanoflakes causes a dramatic coercivity reduction. However, the addition of soft magnetic phase nanowires enhanced the composite magnetization without sacrificing the coercivity. Nevertheless, a kink was still observed on the demagnetization curves and the coercivity decreased when the soft-phase content was larger than 10 wt. %, which was caused by the agglomeration of the soft phase nanowires that also led to a decreased degree of texture.

Ma, Yilong; Liu, Xubo; Gandha, Kinjal; Vuong, Nguyen V.; Yang, Y. B.; Yang, Jinbo; Poudyal, Narayan; Cui, Jun; Liu, J.Ping

2014-05-07T23:59:59.000Z

363

Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}  

SciTech Connect (OSTI)

Structural and magnetic properties of polycrystalline Yb{sub 1?x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, ?{sub ac}(T), shows no signature of spin-glass behavior. ?”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

Sattibabu, Bhumireddi, E-mail: bsb.satti@gmail.com; Bhatnagar, Anil K., E-mail: bsb.satti@gmail.com; Mohan, Dasari, E-mail: bsb.satti@gmail.com; Das, Dibakar, E-mail: bsb.satti@gmail.com; Sundararaman, Mahadevan, E-mail: bsb.satti@gmail.com [School of Engineering Sciences and Technology, University of Hyderabad, Hyderabad-500046 (India); Siruguri, Vasudeva; Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, Mumbai Centre, R-5 Shed, Bhabha Atomic Research Centre, Mumbai-400085 (India)

2014-04-24T23:59:59.000Z

364

Abundance analysis of SB2 binary stars with HgMn primaries  

E-Print Network [OSTI]

We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

T. Ryabchikova

1998-05-06T23:59:59.000Z

365

Magneto-optical spectroscopy of ferromagnetic shape-memory Ni-Mn-Ga alloy  

SciTech Connect (OSTI)

Magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy in martensite and austenite phase were systematically studied. Crystal orientation was approximately along (100) planes of parent cubic austenite. At room temperature, the sample was in modulated 10M martensite phase and transformed to cubic austenite at 323?K. Spectral dependence of polar magneto-optical Kerr effect was obtained by generalized magneto-optical ellipsometry with rotating analyzer in the photon energy range from 1.2 to 4?eV, and from room temperature to temperature above the Curie point. The Kerr rotation spectra exhibit prominent features typical for complexes containing Mn atoms. Significant spectral changes during transformation to austenite can be explained by different optical properties caused by changes in density of states near the Fermi energy.

Veis, M., E-mail: veis@karlov.mff.cuni.cz; Beran, L.; Zahradnik, M.; Antos, R. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague (Czech Republic); Straka, L. [Aalto University School of Engineering, PL14200, FIN-00076 Aalto (Finland); Kopecek, J.; Fekete, L.; Heczko, O. [Institute of Physics, ASCR, Na Slovance 2, 182 21 Prague (Czech Republic)

2014-05-07T23:59:59.000Z

366

High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor  

SciTech Connect (OSTI)

Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochemical characteristics. A maximum capacitance value of 1260 F g{sup -1} could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L{sup -1} KOH electrolyte.

Luo Jianmin [Institute of Applied Chemistry, Xinjiang University, Urumqi 830046 (China); Gao Bo [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Zhang Xiaogang [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)], E-mail: azhangxg@163.com

2008-05-06T23:59:59.000Z

367

Optical transitions in MnGa{sub 2}Se{sub 4}  

SciTech Connect (OSTI)

The dependence of the absorption coefficient on incident photon energy in a MnGa{sub 2}Se{sub 4} single crystal has been investigated in the temperature range 110-295 K. Using group-theory analysis of the electron state symmetry and comparison of the symmetry of the energy spectrum of MnGa{sub 2}Se{sub 4} and its isoelectronic analogs, a conclusion about the character of optical transitions has been drawn. It is shown that the features observed at 2.31 and 2.45 eV are related to the intracenter transitions {sup 6}A{sub 1}{sup 1} {yields} {sup 4}T{sub 2}({sup 4}G) and {sup 6}A{sub 1}{sup 2} {yields} {sup 4}T{sub 2}({sup 4}G). The {sup 6}A{sub 1} state is split by the crystal field.

Tagiev, B. G.; Kerimova, T. G., E-mail: ktaira@physics.ab.az; Tagiev, O. B.; Asadullayeva, S. G.; Mamedova, I. A. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2012-06-15T23:59:59.000Z

368

Thermoelectric study of crossroads material MnTe via sulfur doping  

SciTech Connect (OSTI)

Here, we report thermoelectric study of crossroads material MnTe via iso-electronic doping S on the Te-site. MnTe{sub 1-x}S{sub x} samples with nominal S content of x?=?0.00, 0.05, and 0.10 were prepared using a melt-quench method followed by pulverization and spark plasma sintering. The X-ray powder diffraction, scanning electron microscopy, and ZAF-corrected compositional analysis confirmed that S uniformly substitutes Te up to slightly over 2%. A higher content of S in the starting materials led to the formation of secondary phases. The thermoelectric properties of MnTe{sub 1-x}S{sub x} samples were characterized by means of Seebeck coefficient, electrical conductivity, and thermal conductivity measurements from 300?K to 773?K. Furthermore, Hall coefficient measurements and a single parabolic band model were used to help gain insights on the effects of S-doping on the scattering mechanism and the carrier effective mass. As expected, S doping not only introduced hole charge carriers but also created short-range defects that effectively scatter heat-carrying phonons at elevated temperatures. On the other hand, we found that S doping degraded the effective mass. As a result, the ZT of MnTe{sub 0.9}S{sub 0.1} was substantially enhanced over the pristine sample near 400?K, while the improvement of ZT became marginal at elevated temperatures. A ZT???0.65 at 773?K was obtained in all three samples.

Xie, Wenjie, E-mail: xie@imw.uni-stuttgart.de; Populoh, Sascha; Sagarna, Leyre; Trottmann, Matthias [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Ga??zka, Krzysztof [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern (Switzerland); Xiao, Xingxing [Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany); Liu, Yufei; He, Jian [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634-0978 (United States); Weidenkaff, Anke [Empa–Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Uberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Institute for Materials Science, University of Stuttgart, DE-70569 Stuttgart (Germany)

2014-03-14T23:59:59.000Z

369

Preparation and characterization of nanostructured NiO/MnO{sub 2} composite electrode for electrochemical supercapacitors  

SciTech Connect (OSTI)

Nanostructured nickel-manganese oxides composite was prepared by the sol-gel and the chemistry deposition combination new route. The surface morphology and structure of the composite were characterized by scanning electron microscope and X-ray diffraction. The as-synthesized NiO/MnO{sub 2} samples exhibit higher surface area of 130-190 m{sup 2} g{sup -1}. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical performance of the composite electrodes with different ratios of NiO/MnO{sub 2}. When the mass ratio of MnO{sub 2} and NiO in composite material is 80:20, the specific capacitance value of NiO/MnO{sub 2} calculated from the cyclic voltammetry curves is 453 F g{sup -1}, for pure NiO and MnO{sub 2} are 209, 330 F g{sup -1} in 6 mol L{sup -1} KOH electrolyte and at scan rate of 10 mV s{sup -1}, respectively. The specific capacitance of NiO/MnO{sub 2} electrode is much larger than that of each pristine component. Moreover, the composite electrodes showed high power density and stable electrochemical properties.

Liu Enhui [College of Chemistry, Xiangtan University, Hunan 411105 (China)], E-mail: liuenhui99@sina.com.cn; Li Wen; Li Jian; Meng Xiangyun; Ding Rui; Tan Songting [College of Chemistry, Xiangtan University, Hunan 411105 (China)

2009-05-06T23:59:59.000Z

370

Construction of the Magnetic Phase Diagram of FeMn/Ni/Cu(001) Using Photoemission Electron Microscopy  

SciTech Connect (OSTI)

Single crystalline FeMn/Ni bilayer was epitaxially grown on Cu(001) substrate and investigated by photoemission electron microscopy (PEEM). The FeMn and Ni films were grown into two cross wedges to facilitate an independent control of the FeMn (0-20 ML) and Ni (0-20 ML) film thicknesses. The Ni magnetic phases were determined by Ni domain images as a function of the Ni thickness (d{sub Ni}) and the FeMn thickness (d{sub FeMn}). The result shows that as the Ni thickness increases, the Ni film undergoes a paramagnetic-to-ferromagnetic state transition at a critical thickness of d{sub FM} and an in-plane to out-of-plane spin reorientation transition at a thicker thickness d{sub SRT}. The phase diagram shows that both d{sub FM} and d{sub SRT} increase as the FeMn film establishes its antiferromagnetic order.

Wu, J.; Scholl, A.; Arenholz, E.; Hwang, C.; Qiu, Z. Q.

2011-01-04T23:59:59.000Z

371

Structural and Magnetic Properties of MCl2 (M = Fe, Mn, Co): Acetonitrile Solvates  

SciTech Connect (OSTI)

M{sup II}Cl{sub 2} (M = Mn, Fe, Co) as their acetonitrile solvates were isolated, and their structural, spectroscopic, and magnetic properties were studied. MCl{sub 2}(NCMe){sub 2} (M = Fe, Mn) form 1-D chains of octahedral M{sup II} ions with four bridging chlorides and two axial MeCN's. The presence of an axial distortion for MFe causes a significant magnetic anisotropy that increases significantly below 150 K; however, {chi}{sub av} [=({chi}{sub {parallel}} + 2{chi}{sub {perpendicular}})/3] almost coincides with the value obtained on a polycrystalline sample. MnCl{sub 2}(NCMe){sub 2} is a paramagnet with a weak antiferromagnetic coupling. Annealing FeCl{sub 2}(NCMe){sub 2} at 55 {sup o}C forms the monosolvate of FeCl{sub 2}(NCMe) composition in which two chains collapse into a double chain with formation of Fe-Cl bonding such that half of the {mu}-Cl's becomes {mu}{sub 3}-Cl's. This material orders magnetically below {Tc} = 4.3 K. For M = Co, paramagnetic tetrahedral [CoCl{sub 3}(NCMe)]{sup -} anions are isolated.

Pokhodnya,K.; Bonner, M.; DiPasquale, A.; Rheingold, A.; Her, J.; Stephens, P.; Park, J.; Kennon, B.; Arif, A.; Miller, J.

2007-01-01T23:59:59.000Z

372

Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?  

SciTech Connect (OSTI)

The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Retuerto, M. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Department of Chemistry, Rutgers State University of New Jersey, Piscataway, NJ 08854-8087 (United States); Calle, C. de la [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Porcher, Florence [Laboratoire Leon Brillouin, CEA/Saclay, 91191 Gif Sur Ivette Cedex, France. (France); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain)

2012-03-15T23:59:59.000Z

373

Economic Potential of CHP in Detroit Edison Service Area: The...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

a single 16 MW grid feeder circuit in Ann Arbor, Michigan, to determine whether there are economic incentives to use small distributed power generation systems that would offset...

374

PP-221 Detroit Edison Company | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15, 2010Energy6 Frontera Generation Limited1 British Columbia41

375

Detroit Beach, Michigan: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump to:52c8ff988c1Dering Harbor, New York: EnergyEnergygua Bonita

376

Secretary Moniz Applauds Detroit's LED Street Lighting Upgrades |  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas | Department ofof EnergyQuadrennial Energy Review

377

Secretary Chu's Remarks at Detroit Economic Club -- As Prepared for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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378

Detroit, MI Natural Gas Imports by Pipeline from Canada  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 4623 42YearDelawareDetails of

379

The Detroit Edison Company Smart Grid Demonstration Project | Open Energy  

Open Energy Info (EERE)

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380

NOTES AND COMMENTS REVERE COPPER AR! BRASS DETROIT, MICHIGAN  

Office of Legacy Management (LM)

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381

Detroit Edison Company Smart Grid Project | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power Basics (The following text09-0018-CXBasinDeseret Generation &Area

382

City of Detroit Lakes, Minnesota (Utility Company) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy InformationLakeWyoming (UtilityDeclo,Information

383

Magnetic ordering in the spinel compound LiMn2-xLixO4,,x=0,0.04... John Gaddy,1  

E-Print Network [OSTI]

.1063/1.3073660 The ground state properties of the known lithium-based cubic spinel compounds LiT2O4 range from BCS-range antiferromagnetic order. In contrast, whereas lithium-substituted Li Mn2-xLix O4 also undergoes a charge eightfold rings.6 The Mn4+ rings only interact with other rings via the intervening Mn3+ ions. When cooled

Montfrooij, Wouter

384

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.Materials for Lithium Batteries. J. Electrochem. Soc. 148,LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

385

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.4 V Cathode Materials for Lithium Batteries. J. Electrochem.LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

386

Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C  

SciTech Connect (OSTI)

Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

Rayment, J.J.; Thomas, G.

1982-03-01T23:59:59.000Z

387

Delocalization and hybridization enhance the magnetocaloric effect in Ni2Mn0.75Cu0.25Ga  

SciTech Connect (OSTI)

In view of the looming energy crisis facing our planet, attention increasingly focuses on materials potentially useful as a basis for energy saving technologies. The discovery of giant magnetocaloric (GMC) compounds - materials that exhibit especially large changes in temperature as the externally applied magnetic field is varied - is one such compound 1. These materials have potential for use in solid state cooling technology as a viable alternative to existing gas based refrigeration technologies that use choro-fluoro - and hydro-fluoro-carbon chemicals known to have a severe detrimental effect on human health and environment 2,3. Examples of GMC compounds include Gd5(SiGe)4 4, MnFeP1-xAsx 5 and Ni-Mn-Ga shape memory alloy based compounds 6-8. Here we explain how the properties of one of these compounds (Ni2MnGa) can be tuned as a function of temperature by adding dopants. By altering the free energy such that the structural and magnetic transitions coincide, a GMC compound that operates at just the right temperature for human requirements can be obtained 9. We show how Cu, substituted for Mn, pulls the magnetic transition downwards in temperature and also, counterintuitively, increases the delocalization of the Mn magnetism. At the same time, this reinforces the Ni-Ga chemical bond, raising the temperature of the martensite-austenite transition. At 25percent doping, the two transitions coincide at 317 K.

Roy, Sujoy; Blackburn, E.; Valvidares, S. M.; Fitzsimmons, M. R.; Vogel, Sven C.; Khan, M.; Dubenko, I.; Stadler, S.; Ali, N.; Sinha, S. K.; Kortright, J. B.

2008-11-26T23:59:59.000Z

388

Magnetovolume effect in Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds  

SciTech Connect (OSTI)

The structural and magnetic properties of seven compounds in the Ho{sub 2}Fe{sub 17-x}Mn{sub x} series (x = 0-5) have been investigated. The spontaneous magnetization M{sub s} at 10 K exhibits a minimum at x{approx_equal} 3.8 while the 3d-sublattice magnetization M{sub T} is found to decrease at {approx} -3.4 {mu}{sub B}/per Mn atom compared with the rate of {approx}-2.0 {mu}{sub B}/per Mn atom expected from a simple dilution model. All of the Ho{sub 2}Fe{sub 17-x}Mn{sub x} compounds exhibit anisotropic thermal expansion below their Curie temperatures leading to the presence of strong magnetovolume effects and Invar-type behavior below T{sub C}. An approximately zero volume thermal expansion has been detected between 10 K and 270 K for Ho{sub 2}Fe{sub 17}. The maximum magnetic entropy changes for Ho{sub 2}Fe{sub 17-x}Mn{sub x} with x = 0 and 2.0 are 3.2 J kg{sup -1} K{sup -1} around T{sub C} {approx} 336 K and 2.7 J kg{sup -1} K{sup -1} around T{sub C} {approx} 302 K, respectively, for magnetic field change of B = 0-5 T.

Wang, J. L. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia); Studer, A. J.; Kennedy, S. J. [Bragg Institute, ANSTO, Menai, NSW 2234 (Australia); Zeng, R.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, University of New South Wales, Canberra, ACT 2600 (Australia)

2012-04-01T23:59:59.000Z

389

Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals  

SciTech Connect (OSTI)

In this dissertation, the author reports on the surface structure of i-Al-Pd-Mn twofold, threefold, fivefold and i-Al-Cu-Fe fivefold surfaces. The LEED studies indicate the existence of two distinct stages in the regrowth of all four surfaces after Ar{sup +} sputtering. In the first stage, upon annealing at relatively low temperature: 500K--800K (depending on different surfaces), a cubic phase appears. The cubic LEED patterns transform irreversibly to unreconstructed quasicrystalline patterns upon annealing to higher temperatures, indicating that the cubic overlayers are metastable. Based upon the data for three chemically-identical, but symmetrically-inequivalent surfaces, a model is developed for the relation between the cubic overlayers and the quasicrystalline substrate. The model is based upon the related symmetries of cubic close-packed and icosahedral-packed materials. These results may be general among Al-rich, icosahedral materials. STM study of Al-Pd-Mn fivefold surface shows that terrace-step-kink structures start to form on the surface after annealing above 700K. Large, atomic ally-flat terraces were formed after annealing at 900K. Fine structures with fivefold icosahedral symmetry were found on those terraces. Data analysis and comparison of the STM images and structure model of icosahedral Al-Pd-Mn suggest that the fine structures in the STM images may be the pseudo Mackay (PMI) clusters which are the structure units of the structure model. Based upon his results, he can conclude that quasicrystalline structures are the stable structures of quasicrystal surfaces. In other words, quasicrystalline structures extend from the bulk to the surface. As a result of the effort reported in this dissertation, he believes that he has increased his understanding of the surface structure of icosahedral quasicrystals to a new level.

Shen, Z.

1999-02-12T23:59:59.000Z

390

Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si alloys  

SciTech Connect (OSTI)

Mechano-synthesis of Fe–32Mn–6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline Fe–Mn–Si alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the ?-to-? and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development. - Graphical abstract: Mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si shape memory alloys in the powder form: amorphous phase formation, ?-to-? phase transformation, mechano-crystallization of the amorphous, and martensite phase formation during the process. Highlights: • During MA, the ?-to-? phase transformation and amorphization occurred. • Mechano-crystallization of the amorphous phase occurred at sufficient milling time. • The formation of high amount of ?-martensite was evidenced at high milling times. • The platelet, spherical, and then irregular particle shapes was extended by MA. • By MA, the particles size was increased, then reduced, and afterward re-increased.

Amini, Rasool, E-mail: ramini2002@gmail.com [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Shamsipoor, Ali [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Ghaffari, Mohammad [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey); Alizadeh, Morteza [Department of Materials Science and Engineering, Shiraz University of Technology, 71555-313 Shiraz (Iran, Islamic Republic of); Okyay, Ali Kemal [Department of Electrical and Electronics Engineering, UNAM-National Institute of Materials Science and Nanotechnology Bilkent University, Ankara 06800 (Turkey)

2013-10-15T23:59:59.000Z

391

Magnetic and electrical properties of layered magnets Tl(Cr,Mn,Co)Se{sub 2}  

SciTech Connect (OSTI)

Tl(Cr,Mn,Co)Se{sub 2} crystals were synthesized at T {approx} 1050 K. X-ray diffraction analysis showed that TlCrSe{sub 2}, TlMnSe{sub 2}, and TlCoSe{sub 2} compounds crystallize in the hexagonal crystal system with the lattice parameters: a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3, {rho}{sub x} = 6.209 g/cm{sup 3}; a = 6.53 A, c = 23.96 A, c/a {approx} 3.669, z = 8, {rho}{sub x} = 6.71 g/cm{sup 3}; and a = 3.747 A, c = 22.772 A, c/a {approx} 6.077, z = 3, {rho}{sub x} = 7.577 g/cm{sup 3}, respectively. Magnetic and electrical studies in the temperature range from 80-400 K showed that TlCrSe{sub 2} is a semiconductor ferromagnet, TlMnSe{sub 2} is a semiconductor antiferromagnet, and TlCoSe{sub 2} is a ferrimagnet with a conductivity characteristic of metals. A rather large deviation in the experimental effective magnetic moment for TlCrSe{sub 2} (3.05 {mu}B) from the theoretical value (3.85 {mu}B) is attributed to two-dimensional magnetic ordering in the paramagnetic region of the noticeably layered ferromagnet TlCrSe{sub 2}. In TlCrSe{sub 2}, a correlation between magnetic and electrical properties was detected.

Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-02-15T23:59:59.000Z

392

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}  

SciTech Connect (OSTI)

The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

Giot, Maud [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Chapon, Laurent C.; Radaelli, Paolo G. [ISIS, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Chilton-Didcot, OX11 0QX, Oxfordshire (United Kingdom); Androulakis, John; Lappas, Alexandros [Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, 71110 Heraklion (Greece); Green, Mark A. [NIST Center for Neutron Research, 100 Bureau Drive, Gaithersburg, Maryland 20899-8562 (United States); Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115 (United States)

2007-12-14T23:59:59.000Z

393

Vacancy dynamic in Ni-Mn-Ga ferromagnetic shape memory alloys  

SciTech Connect (OSTI)

Vacancies control any atomic ordering process and consequently most of the order-dependent properties of the martensitic transformation in ferromagnetic shape memory alloys. Positron annihilation spectroscopy demonstrates to be a powerful technique to study vacancies in NiMnGa alloys quenched from different temperatures and subjected to post-quench isothermal annealing treatments. Considering an effective vacancy type the temperature dependence of the vacancy concentration has been evaluated. Samples quenched from 1173?K show a vacancy concentration of 1100?±?200?ppm. The vacancy migration and formation energies have been estimated to be 0.55?±?0.05?eV and 0.90?±?0.07?eV, respectively.

Merida, D., E-mail: david.merida@ehu.es [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); García, J. A. [Fisika Aplikatua II Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain); BC Materials (Basque Centre for Materials, Application and Nanostructures), 48040 Leioa (Spain); Sánchez-Alarcos, V.; Pérez-Landazábal, J. I.; Recarte, V. [Departamento de Física, Universidad Pública de Navarra, Campus de Arrosadia, 31006 Pamplona (Spain); Plazaola, F. [Elektrizitate eta Elektronika Saila, Euskal Herriko Unibertsitatea UPV/EHU, p.k. 644, 48080 Bilbao (Spain)

2014-06-09T23:59:59.000Z

394

Spin relaxation time dependence on optical pumping intensity in GaAs:Mn  

SciTech Connect (OSTI)

We analyze the dependence of electron spin relaxation time on optical pumping intensity in a partially compensated acceptor semiconductor GaAs:Mn using analytic solutions for the kinetic equations of the charge carrier concentrations. Our results are applied to previous experimental data of spin-relaxation time vs. excitation power for magnetic concentrations of approximately 10{sup 17}?cm{sup ?3}. The agreement of our analytic solutions with the experimental data supports the mechanism of the earlier-reported atypically long electron-spin relaxation time in the magnetic semiconductor.

Burobina, V. [Department of Physics and Astronomy, University of Utah, 115 South 1400 East, Salt Lake City, Utah 84112-0830 (United States); Binek, Ch. [Department of Physics and Astronomy, Nebraska Center for Materials and Nanoscience, Theodore Jorgensen Hall, 855 North 16th Street, University of Nebraska, P.O. Box 880299, Lincoln, Nebraska 68588-0299 (United States)

2014-04-28T23:59:59.000Z

395

Oxidation Characteristics of Fe-18Cr-18Mn-stainless alloys  

SciTech Connect (OSTI)

Air oxidation studies of Fe-18Cr-18Mn stainless steels were conducted at 525°C, 625°C, and 725°C. Alloys were evaluated with respect to changes in oxidation properties as a result of interstitial additions of nitrogen and carbon and of minor solute additions of silicon, molybdenum, and nickel. Interstitial concentrations possibly had a small, positive effect on oxidation resistance. Minor solute additions significantly improved oxidation resistance but could also reduce interstitial solubility resulting in formation of chromium carbides. Loss of solute chromium resulted in a slight reduction in oxidation protection. Oxidation lasting over 500 hours produced a manganese rich, duplex oxide structure: an outer sesquioxide and an inner spinel oxide.

James Rawers

2010-10-01T23:59:59.000Z

396

Ferromagnetic transition temperature enhancement in (Ga,Mn)As semiconductors by carbon codoping  

E-Print Network [OSTI]

-1829/2003/68~16!/161202~4!/$20.00 68 161202- t in ?Ga,Mn?As semiconductors codoping ,2,4 and A. H. MacDonald2 a? 10, 162 53 Praha 6, Czech Republic y Station C1600, Austin, Texas 78712-0264, USA 2, 182 21 Praha 8, Czech Republic y, College Station, Texas 77843-4242, USA d 13... Society1 RAPID COMMUNICATIONS JUNGWIRTH, MASE? K, SINOVA, AND MacDONALD PHYSICAL REVIEW B 68, 161202~R! ~2003! The above qualitative analysis of formation energies sug- gests that CAs codoping is favorable for achieving high Curie temperatures. Unlike...

Jungwirth, T.; Masek, J.; Sinova, Jairo; MacDonald, AH.

2003-01-01T23:59:59.000Z

397

Synthesis and Luminescence of ZnMgS:Mn2+ Nanoparticles. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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398

File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublicIDAPowerPlantSitingConstruction.pdfNotify98.pdf Jump to: navigation,storage planIL.pdf JumpMN.pdf Jump to:

399

Stabilization of ZnMnO3 Phase from Sol-gel Synthesized Nitrate Precursors .  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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400

Suppression of conductivity in Mn-Doped ZnO Thin Films. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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401

Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route  

SciTech Connect (OSTI)

Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, ? = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ? A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ? NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ? Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ? Thermal analysis, transport measurements complement characterization of this oxide. ? A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup ¯}m, Z = 8, with a = 8.3940(2) ? at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, ? = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at the octahedral sites provides the charge carriers that, by a hopping mechanism between Mn{sup 3+}/Mn{sup 4+} adjacent sites, leads to a significant conductivity, up to 0.85 S cm{sup ?1} at 800 °C in air.

Sagua, A.; Lescano, Gabriela M. [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina)] [Departamento de Química, Laboratorio de Fisicoquímica Inorgánica, Universidad Nacional del Sur, INQUISUR, 8000 Bahía Blanca (Argentina); Alonso, J.A., E-mail: jaalonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Martínez-Coronado, R. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, E-28049 Madrid (Spain); Fernández-Díaz, M.T. [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France)] [Institut Laue Langevin, BP 156X, Grenoble F-38042 (France); Morán, E. [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)] [Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid (Spain)

2012-06-15T23:59:59.000Z

402

LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries  

SciTech Connect (OSTI)

Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

2014-01-15T23:59:59.000Z

403

Solid-State 55Mn NMR Spectroscopy of bis(?-oxo)dimanganese(IV) [Mn2O2(salpn)2], a Model for the Oxygen Evolving Complex in Photosystem II  

SciTech Connect (OSTI)

Given the obvious global energy needs, it has become imperative to develop a catalytic process for converting water to molecular oxygen and protons. Many have sought to understand the details of photosynthesis and in particular the water splitting reaction to help in the development of the appropriate catalysis.1-3 While the scientific community has made great strides towards this goal, it has fallen short at the critical stage of the determination of the structure associated with the oxygen evolving complex (OEC) within photosystem II (PSII).4,5 Despite the existence of x-ray structures of PSII,6-8 the best data we have for the structure of the OEC comes from models derived from EPR and EXAFS measurements.9-14 This experimental situation has led to collaborations with theoreticians to enable the development of models for the structure of the OEC where the experimental observables (EXAFS and magnetic resonance parameters) serve as constraints to the theoretical calculations. Of particular interest to this study is the observation of the S1 state of the Kok cycle15 where the core of the OEC can be described as a tetranuclear manganese cluster composed of Mn4OxCa. The simplest model for the OEC can be thought of as two Mn-pairs and a Ca2+ where each Mn-pair is antiferromagnetically coupled to its partner. We utilize the term "pair" to describe the Mn atoms within the OEC with the same oxidation state, which for the S1 state is (Mn2(III, III) and Mn2(IV, IV)).16 It is unclear as to the degree of interaction between the pairs as well as the role of the Ca2+. At cryogenic temperatures the S1 state of the OEC is diamagnetic and in principle amenable to solid-state NMR experiments.

Ellis, Paul D.; Sears, Jesse A.; Yang, Ping; Dupuis, Michel; Boron, Ted; Pecoraro, Vince; Stich, Troy; Britt, R. David; Lipton, Andrew S.

2010-12-01T23:59:59.000Z

404

An analysis of the effects of Mn{sup 2+} on oxidative phosphorylation in liver, brain, and heart mitochondria using state 3 oxidation rate assays  

SciTech Connect (OSTI)

Manganese (Mn) toxicity is partially mediated by reduced ATP production. We have used oxidation rate assays-a measure of ATP production-under rapid phosphorylation conditions to explore sites of Mn{sup 2+} inhibition of ATP production in isolated liver, brain, and heart mitochondria. This approach has several advantages. First, the target tissue for Mn toxicity in the basal ganglia is energetically active and should be studied under rapid phosphorylation conditions. Second, Mn may inhibit metabolic steps which do not affect ATP production rate. This approach allows identification of inhibitions that decrease this rate. Third, mitochondria from different tissues contain different amounts of the components of the metabolic pathways potentially resulting in different patterns of ATP inhibition. Our results indicate that Mn{sup 2+} inhibits ATP production with very different patterns in liver, brain, and heart mitochondria. The primary Mn{sup 2+} inhibition site in liver and heart mitochondria, but not in brain mitochondria, is the F{sub 1}F{sub 0} ATP synthase. In mitochondria fueled by either succinate or glutamate + malate, ATP production is much more strongly inhibited in brain than in liver or heart mitochondria; moreover, Mn{sup 2+} inhibits two independent sites in brain mitochondria. The primary site of Mn-induced inhibition of ATP production in brain mitochondria when succinate is substrate is either fumarase or complex II, while the likely site of the primary inhibition when glutamate plus malate are the substrates is either the glutamate/aspartate exchanger or aspartate aminotransferase.

Gunter, Thomas E., E-mail: thomas_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gerstner, Brent, E-mail: brent_gerstner@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Lester, Tobias, E-mail: Tlester200@gmail.co [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Wojtovich, Andrew P., E-mail: andrew_wojtovich@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Malecki, Jon, E-mail: jon_malecki@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Swarts, Steven G., E-mail: steven_swarts@urmc.rochester.ed [Department of Radiation Oncology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Brookes, Paul S., E-mail: paul_brookes@urmc.rochester.ed [Department of Pharmacology and Physiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Department of Anesthesiology, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States); Gavin, Claire E., E-mail: candegavin@aol.com; Gunter, Karlene K., E-mail: karlene_gunter@urmc.rochester.ed [Department of Biochemistry and Biophysics, University of Rochester School of Medicine and Dentistry, Rochester, NY 14642 (United States)

2010-11-15T23:59:59.000Z

405

JOURNAL DE PHYSIQUE Colloque Cl, supplkment au no 4, Tome 38, Auril 1977, page Cl-303 MULTILAYER SINTERING OF MnZn FERRITES  

E-Print Network [OSTI]

SINTERING OF MnZn FERRITES IN CONTROLLED ATMOSPHERE M. I. ALAM, N. R. NAlR and T. V. RAMAMURTI Central dans la litterature que I'empilement depots de ferrites les uns sur les autres durant le traitement production des couches multiples d'echantillons de ferrite de Mn-Zn. On a utilise jusqu'a 10 couches d

Boyer, Edmond

406

Atomic-Scale Spin-Polarized Scanning Tunneling Microscopy Applied To Mn3N2(010) Haiqiang Yang and Arthur R. Smith  

E-Print Network [OSTI]

source effusion cell for Mn and a rf plasma source for N [5,6]. All STM imaging is performed at 300 K-centered tetragonal (fct) rock-salt type struc- ture. The bulk magnetic moments of the Mn atoms are FM within (001

407

Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power  

E-Print Network [OSTI]

Free-Standing LiNi0.5Mn1.5O4/Carbon Nanofiber Network Film as Light-Weight and High-Power Cathode Pure carbon nanofiber (CNF) network without LiNi0.5Mn1.5O4 was tested in the voltage window of 3.5-5 V

Zhou, Chongwu

408

A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with  

E-Print Network [OSTI]

/Mn3O4 composites were prepared by a simple hydrothermal process from KMnO4 using ethylene glycolA Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets in Faradaic electron-transfer processes of a metal oxide or conducting poly- mer.3 It is also possible

409

Suppression of the thermal hysteresis in magnetocaloric MnAs thin film by highly charged ion bombardment  

SciTech Connect (OSTI)

We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.

Trassinelli, M., E-mail: martino.trassinelli@insp.jussieu.fr; Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D. [CNRS, UMR 7588, Institut des NanoSciences de Paris (INSP), F-75005 Paris (France); Sorbonne Universités, UPMC Univ. Paris 06, UMR 7588, INSP, F-75005 Paris (France)

2014-02-24T23:59:59.000Z

410

Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/  

DOE Patents [OSTI]

A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

Robinson, P.R.; Bamberger, C.E.

1980-02-08T23:59:59.000Z

411

Enhancing structural transition by carrier and quantum confinement: Stabilization of cubic InN quantum dots by Mn incorporation  

SciTech Connect (OSTI)

We demonstrate in this work controllable synthesis of cubic InN nanocrystals through Mn doping. We show that the pristine nanocrystal has the wurtzite structure, but can be converted into the zinc-blende (ZB) structure when it is doped with Mn. Our first-principles calculations show that the phase transition is caused by the stronger p-d coupling between the host p valence state and the impurity d level in the ZB structure, which makes the hole generation in the ZB structure easier. Quantum confinement in the nanocrystals further enhanced this effect. This observation lays an important foundation for defects control of crystal phases.

Meng, Xiuqing; Wu, Fengmin [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China)] [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); Chen, Zhanghui; Li, Shu-Shen [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China)] [State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Chen, Zhuo [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China)] [Department of Physics, Beijing Institute of Technology, Beijing 100081 (China); Li, Jingbo, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China) [Zhejiang Normal University, Jinhua, Zhejiang Province 321004 (China); State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Wu, Junqiao [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States)] [Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States); Wei, Su-Huai, E-mail: jbli@semi.ac.cn, E-mail: swei@nrel.gov [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)] [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

2013-12-16T23:59:59.000Z

412

Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn[N(CN)2]2  

SciTech Connect (OSTI)

We report the discovery of a magnetic quantum critical transition in Mn[N(CN)2]2 that drives the system from a canted antiferromagnetic state to the fully polarized state with amplified magnetoelastic coupling as an intrinsic part of the process. The local lattice distortions, revealed through systematic phonon frequency shifts, suggest a combined MnN6 octahedra distortion+counterrotation mechanism that reduces antiferromagnetic interactions and acts to accommodate the field-induced state. These findings deepen our understanding of magnetoelastic coupling near a magnetic quantum critical point and away from the static limit.

Brinzari, T. V.; Chen, P.; Sun, Q.-C.; Liu, J.; Tung, L.-C.; Wang, Y.; Schlueter, J. A.; Singleton, J.; Manson, J. L.; Whangbo, M.-H.; Litvinchuk, A. P.; Musfeldt, J. L.

2013-06-01T23:59:59.000Z

413

Effects of Ti substitution on structural and magnetic properties of Zn–Mn ferrospinels  

SciTech Connect (OSTI)

Highlights: ? Novel system ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} synthesized by sol–gel route. ? Nanocrystalline materials. ? Magnetic materials. - Abstract: Nanocrystalline ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} (1.0 ? x ? 0) ferrites were prepared by sol–gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction patterns. The lattice parameter shows an increasing trend with the increase in Ti content. These ferrite samples existed as crystalline nanoparticles of about 30–40 nm size as observed from transmission electron microscopy (TEM) technique. EDAX analysis indicated that the concentration of different elements in different compositions is in close agreement with the starting concentrations. Infrared spectra showed two main absorption bands in the range 400–800 cm{sup ?1} arising due to tetrahedral (A) and octahedral (B) stretching vibrations. The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution.

Patil, R.P., E-mail: raj_rbm_raj@yahoo.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Patil, N.M. [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Sasikala, R. [Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Hankare, P.P., E-mail: p_hankarep@rediffmail.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Delekar, S.D. [Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Sub-campus Osmanabad, 413501 (India)

2013-05-15T23:59:59.000Z

414

EPR in Mn2+ doped betaine calcium chloride dihydrate single crystals J. L. Ribeiro (1), J. C. Fayet (2), J. Emery (2), M. Pdzeril (2), J. Albers (3), A. Klpperpieper (3),  

E-Print Network [OSTI]

devil's staircase. In this paper we report a study of Electronic Paramagnetic Resonance of Mn2 + doped

Paris-Sud XI, Université de

415

Electrochemically induced deposition method to prepare {gamma}-MnO{sub 2}/multi-walled carbon nanotube composites as electrode material in supercapacitors  

SciTech Connect (OSTI)

The {gamma}-MnO{sub 2}/multi-walled carbon nanotube ({gamma}-MnO{sub 2}/MWNT) composite has been prepared by electrochemically induced deposition method. The morphology and crystal structure of the composite were investigated by X-ray diffraction and scanning electron microscopy, respectively. The capacitive properties of the {gamma}-MnO{sub 2}/MWNT composite have been investigated by cyclic voltammetry (CV). A specific capacitance (based on {gamma}-MnO{sub 2}) as high as 579 F g{sup -1} is obtained at a scan rate of 10 mV s{sup -1} in 0.1 M Na{sub 2}SO{sub 4} aqueous solution. Additionally, the {gamma}-MnO{sub 2}/MWNT composite electrode shows excellent long-term cycle stability (only 2.4% decrease of the specific capacitance is observed after 500 CV cycles)

Fan Zhen [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China); Chen Jinhua [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China)], E-mail: chenjinhua@hnu.cn; Zhang Bing; Sun Feng; Liu Bo; Kuang Yafei [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China)

2008-08-04T23:59:59.000Z

416

Radiation-induced instability of MnS precipitates and its possible consequences on irradiation-induced stress corrosion cracking of austenitic stainless steels  

SciTech Connect (OSTI)

Irradiation-assisted stress corrosion cracking (IASCC) is a significant materials issue for the light water reactor (LWR) industry and may also pose a problem for fusion power reactors that will use water as coolant. A new metallurgical process is proposed that involves the radiation-induced release into solution of minor impurity elements not usually thought to participate in IASCC. MnS-type precipitates, which contain most of the sulfur in stainless steels, are thought to be unstable under irradiation. First, Mn transmutes strongly to Fe in thermalized neutron spectra. Second, cascade-induced disordering and the inverse Kirkendall effect operating at the incoherent interfaces of MnS precipitates are thought to act as a pump to export Mn from the precipitate into the alloy matrix. Both of these processes will most likely allow sulfur, which is known to exert a deleterious influence on intergranular cracking, to re-enter the matrix. To test this hypothesis, compositions of MnS-type precipitates contained in several unirradiated and irradiated heats of Type 304, 316, and 348 stainless steels (SSs) were analyzed by Auger electron spectroscopy. Evidence is presented that shows a progressive compositional modification of MnS precipitates as exposure to neutrons increases in boiling water reactors. As the fluence increases, the Mn level in MnS decreases, whereas the Fe level increases. The S level also decreases relative to the combined level of Mn and Fe. MnS precipitates were also found to be a reservoir of other deleterious impurities such as F and O which could be also released due to radiation-induced instability of the precipitates.

Chung, H.M.; Sanecki, J.E. [Argonne National Lab., IL (United States); Garner, F.A. [Pacific Northwest National Lab., Richland, WA (United States)

1996-12-01T23:59:59.000Z

417

ON MASS CONSTRAINTS IMPLIED BY THE RELATIVISTIC PRECESSION MODEL OF TWIN-PEAK QUASI-PERIODIC OSCILLATIONS IN CIRCINUS X-1  

SciTech Connect (OSTI)

Boutloukos et al. discovered twin-peak quasi-periodic oscillations (QPOs) in 11 observations of the peculiar Z-source Circinus X-1. Among several other conjunctions the authors briefly discussed the related estimate of the compact object mass following from the geodesic relativistic precession model for kHz QPOs. Neglecting the neutron star rotation they reported the inferred mass M{sub 0} = 2.2 {+-} 0.3 M{sub sun}. We present a more detailed analysis of the estimate which involves the frame-dragging effects associated with rotating spacetimes. For a free mass we find acceptable fits of the model to data for (any) small dimensionless compact object angular momentum j = cJ/GM {sup 2}. Moreover, quality of the fit tends to increase very gently with rising j. Good fits are reached when M {approx} M{sub 0}[1 + 0.55(j + j {sup 2})]. It is therefore impossible to estimate the mass without independent knowledge of the angular momentum and vice versa. Considering j up to 0.3 the range of the feasible values of mass extends up to 3 M{sub sun}. We suggest that similar increase of estimated mass due to rotational effects can be relevant for several other sources.

Toeroek, Gabriel; Bakala, Pavel; Sramkova, Eva; StuchlIk, Zdenek; Urbanec, Martin, E-mail: terek@volny.c, E-mail: pavel.bakala@fpf.slu.c, E-mail: sram_eva@centrum.c, E-mail: zdenek.stuchlik@fpf.slu.c, E-mail: martin.urbanec@fpf.slu.c [Institute of Physics, Faculty of Philosophy and Science, Silesian University in Opava Bezrucovo nam. 13, CZ-746 01 Opava (Czech Republic)

2010-05-01T23:59:59.000Z

418

The production and decay of the top partner $T$ in the left-right twin higgs model at the ILC and CLIC  

E-Print Network [OSTI]

The left-right twin Higgs model (LRTHM) predicts the existence of the top partner $T$. In this work, we make a systematic investigation for the single and pair production of this top partner $T$ through the processes: $e^{+}e^{-}\\to t\\ov{T} + T\\bar{t}$ and $ T\\ov{T}$, the neutral scalar (the SM-like Higgs boson $h$ or neutral pseudoscalar boson $\\phi^{0}$) associate productions $e^{+}e^{-}\\to t\\ov{T}h +T\\bar{t}h$, $T\\ov{T}h$, $t\\ov{T}\\phi^{0}+T\\bar{t}\\phi^{0}$ and $ T\\ov{T}\\phi^{0}$. From the numerical evaluations for the production cross sections and relevant phenomenological analysis we find that (a) the production rates of these processes, in the reasonable parameter space, can reach the level of several or tens of fb; (b) for some cases, the peak value of the resonance production cross section can be enhanced significantly and reaches to the level of pb; (c) the subsequent decay of $T\\to \\phi^{+}b \\to t\\bar{b}b$ may generate typical phenomenological features rather different from the signals from other new physics models beyond the standard model(SM); and (d) since the relevant SM background is generally not large, some signals of the top partner $T$ predicted by the LRTHM may be detectable in the future ILC and CLIC experiments.

Yao-Bei Liu; Zhen-Jun Xiao

2014-12-13T23:59:59.000Z

419

Subsurface characterization of an oxidation-induced phase transformation and twinning in nickel-based superalloy exposed to oxy-combustion environments  

SciTech Connect (OSTI)

In the integration of oxy-fuel combustion to turbine power generation system, turbine alloys are exposed to high temperature and an atmosphere comprised of steam, CO{sub 2} and O{sub 2}. While surface and internal oxidation of the alloy takes place, the microstructure in the subsurface region also changes due to oxidation. In this study, bare metal coupons of Ni-base superalloys were exposed in oxy-fuel combustion environment for up to 1000 h and the oxidation-related microstructures were examined. Phase transformation occurred in the subsurface region in Ni-based superalloy and led to twinning. The transformation product phases were analyzed through thermodynamic equilibrium calculations and various electron microscopy techniques, including scanning electron microscopy (SEM), orientation imaging microscopy (OIM) and transmission electron microscopy (TEM). The mechanism by which the phase transformation and the formation of the microstructure occurred was also discussed. The possible effects of the product phases on the performance of the alloy in service were discussed.

Zhu, Jingxi; Holcomb, Gordon R.; Jablonski, Paul D.; Wise, Adam; Li, Jia; Laughlin, David E.; Sridhar, Seetharaman

2012-07-30T23:59:59.000Z

420

Competition between stripe and checkerboard magnetic instabilities in Mn-doped BaFe2As2  

SciTech Connect (OSTI)

The appearance of unconventional superconductivity often requires the suppression of an antiferromagnetic (AFM) ordered state by tuning the chemical composition. In BaFe2As2, the AFM ordered state is driven by Fermi surface nesting, resulting in stripe magnetic ordering with propagation vector Qstripe = (; 0) (in Fe square lattice notation). Co substitution acts as an electron donor that destabilizes the nesting condition,1 leading to suppression of the stripe AFM ordering2 and the appearance of superconductivity.3,4 Mn is nominally the hole-doping counterpart of Co which should also detune the Fermi surface nesting, but it is not a superconductor.5 Here we report that Mn doping does not act solely as a hole donor, but instead introduces strong spin uctuations at a wavevector (; ) that is unrelated to the Fermi surface topology of BaFe2As2. Spin uctuations at (; ) and (; 0) coexist, suggesting the Mn dopants act as local magnetic impurities that polarize neighbouring Fe/Mn spins, potentially disrupting superconductivity.

Pratt, Daniel [Ames Laboratory and Iowa State University; Kim, M. G. [Ames Laboratory and Iowa State University; Ran, S. [Ames Laboratory and Iowa State University; Thaler, A. [Ames Laboratory and Iowa State University; Granroth, Garrett E [ORNL; Marty, Karol J [ORNL; Tian, W. [University of Tennessee, Knoxville (UTK); Zarestky, J. L. [Ames Laboratory and Iowa State University; Lumsden, Mark D [ORNL; Budko, S L [Ames Laboratory and Iowa State University; Canfield, P. C. [Ames Laboratory; Goldman, A. I. [Ames Laboratory and Iowa State University; Mcqueeney, R J [Ames Laboratory and Iowa State University; Tucker, G. S. [Ames Laboratory and Iowa State University

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

EXAFS and FT-IR Characterization of Mn and Li Promoted Titania-Supported Rh Catalysts for CO Hydrogenation  

SciTech Connect (OSTI)

The effect of Li and Mn promoters on the structure and selectivity of supported Rh catalysts for CO hydrogenation reaction was examined. Infrared spectroscopy and X-ray absorption were used to investigate the adsorption of reactants and local structure of Rh. These techniques were used in combination with reactivity, H{sub 2} chemisorption, and temperature programmed studies to correlate structural characteristics with activity and selectivity during CO hydrogenation of unpromoted Rh/TiO{sub 2} and three promoted Rh catalysts: Rh-Li/TiO{sub 2}, Rh-Mn/TiO{sub 2}, and Rh-Li-Mn/TiO{sub 2}. The presence of a promoter slightly decreases the Rh clusters size; however, no evidence for an electronic effect induced by the presence of Li and Mn was found. Higher turnover frequencies were found for the promoted catalysts, which also showed the lower dispersion. The Li promoter introduces a weakened CO adsorption site that appears to enhance the selectivity to C{sub 2+} oxygenates. The selectivity to C{sub 2+} oxygenates varies inversely with the reducibility of Rh metal, that is, the lower the Rh reducibility, the higher the selectivity.

V Schwartz; A Campos; A Egbebi; J Spivey; S Overbury

2011-12-31T23:59:59.000Z

422

Microstructure, mechanical property and corrosion behaviors of interpenetrating C/Mg-Zn-Mn composite fabricated by suction casting  

E-Print Network [OSTI]

bonding between Mg-Zn-Mn alloy and carbon scaffold was very well. The composite had an ultimate. Introduction Carbon, in all its forms, such as carbon nanotubes, carbon fabric, carbon-carbon composites, glassy carbon, pyrocarbons and diamond- like layers, is considered as a promising material for biomedical

Zheng, Yufeng

423

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Citation: Zheng J, J Xiao, X Yu, L Kovarik, M Gu, F Omenya, X Chen, XQ Yang, J Liu, GL Graff, MS Whittingham, and J Zhang.2012."Enhanced Li+ ion transport in LiNi0.5Mn1.5O4...

424

Bioaccumulation of essential metals (Co, Mn and Zn) in the king scallop Pecten maximus: seawater, food and sediment exposures  

E-Print Network [OSTI]

, food and sediment exposures Marc Metiana,b , Michel Warnaua* , Laetitia Hédouina,b , Paco Bustamanteb-feeding mollusks living in soft sediments, the uptake and depuration kinetics of three elements (Co, Mn and Zn) were investigated in the king scallop Pecten maximus exposed via seawater, food, or sediment, using

Boyer, Edmond

425

Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations  

E-Print Network [OSTI]

A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, Ga...

Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

2007-01-01T23:59:59.000Z

426

pH Effects on the structure of biogenic Mn-oxides Mengqiang Zhu, mzhu@UDel.Edu1  

E-Print Network [OSTI]

metals. In this study, pH effects were investigated in CaCl2 and NaCl solutions at pH 6, 7 and 8 for 48. The structure of BioMnOx preformed at pH 8 in a CaCl2 solution was not modified by lower pHs of the CaCl2

Sparks, Donald L.

427

Unoccupied electronic states of icosahedral Al-Pd-Mn quasicrystals: Evidence of image potential resonance and pseudogap  

SciTech Connect (OSTI)

We study the unoccupied region of the electronic structure of the fivefold symmetric surface of an icosahedral (i) Al-Pd-Mn quasicrystal. A feature that exhibits parabolic dispersion with an effective mass of (1.15±0.1)me and tracks the change in the work function is assigned to an image potential resonance because our density functional calculation shows an absence of band gap in the respective energy region. We show that Sn grows pseudomorphically on i?Al?Pd?Mn as predicted by density functional theory calculations, and the energy of the image potential resonance tracks the change in the work function with Sn coverage. The image potential resonance appears much weaker in the spectrum from the related crystalline Al-Pd-Mn surface, demonstrating that its strength is related to the compatibility of the quasiperiodic wave functions in i?Al?Pd?Mn with the free-electron-like image potential states. Our investigation of the energy region immediately above EF provides unambiguous evidence for the presence of a pseudogap, in agreement with our density functional theory calculations.

Maniraj, M [UGC-DAE Confortium for Scientific Research; Rai, Abhishek [UGC-DAE Confortium for Scientific Research; Barman, S R [UGC-DAE Confortium for Scientific Research; Krajci, M [Slovak Academy of Sciences; Schlagel, Deborah L [Ames Laboratory; Lograsso, Thomas A [Ames Laboratory; Horn, K [Fritz-Haber-Institut der Max-Planck-Gesellschaft

2014-09-01T23:59:59.000Z

428

Transport properties of La1?xCaxMnO3 (Eur. Phys. J. B 26, 467?471...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Societ a Italiana di Fisica Springer-Verlag 2002 Transport properties of La 1-x Ca x MnO 3 (0.5 x < 1) H.-D. Zhou, R.-K. Zheng, G. Li, S.-J. Feng, F. Liu, X.-J. Fan,...

429

Physica B 322 (2002) 236247 The electronic properties of FeCo, Ni3Mn and Ni3Fe  

E-Print Network [OSTI]

1. Introduction The Fe- and Mn-based transition metal (TM) alloys possess a number of unusual with the local-density functional method. It is shown that the value of the magnetic moment is insensitive- stant and magnetization of Fe­Co alloys depend non-monotonically on Co concentration, and change

Kim, Jai Sam

430

Evidence for triplet superconductivity in Josephson junctions with barriers of the ferromagnetic Heusler alloy Cu2MnAl  

E-Print Network [OSTI]

Evidence for triplet superconductivity in Josephson junctions with barriers of the ferromagnetic have studied Josephson junctions with barriers prepared from the Heusler compound Cu2MnAl. In the as metal. Measurements on lateral Josephson junctions with half metallic CrO2 Ref. 7 and the rare

Martinis, John M.

431

Copyright 2010 IEEE. Reprinted from Proceedings of the 2010 IEEE Power & Energy Society General Meeting, Minneapolis, MN, USA.  

E-Print Network [OSTI]

General Meeting, Minneapolis, MN, USA. This material is posted here with permission of the IEEE and therefore is exposed to fluctuations in future electricity prices (day-ahead and real-time) and potential from participating in the wholesale electricity market. We propose a methodology to derive optimal day

Kemner, Ken

432

High-temperature stability, structure and thermoelectric properties of CaMn1xNbxO3 phases  

E-Print Network [OSTI]

technologies such as solid oxide fuel cells, thermoelectric (TE) modules and high-temperature superconductorsHigh-temperature stability, structure and thermoelectric properties of CaMn1Ã?xNbxO3 phases Laura diffraction and electron diffraction data. Thermogravi- metric heating/cooling studies showed a reversible

433

Unusual magnetic hysteresis and the weakened transition behavior induced by Sn substitution in Mn{sub 3}SbN  

SciTech Connect (OSTI)

Substitution of Sb with Sn was achieved in ferrimagnetic antiperovskite Mn{sub 3}SbN. The experimental results indicate that with an increase in Sn concentration, the magnetization continuously decreases and the crystal structure of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N changes from tetragonal to cubic phase at around x of 0.8. In the doping series, step-like anomaly in the isothermal magnetization was found and this behavior was highlighted at x?=?0.4. The anomaly could be attributed to the magnetic frustration, resulting from competition between the multiple spin configurations in the antiperovskite lattice. Meantime, H{sub c} of 18 kOe was observed at x?=?0.3, which is probably the highest among those of manganese antiperovskite materials reported so far. With increasing Sn content, the abrupt change of resistivity and the sharp peak of heat capacity in Mn{sub 3}SbN were gradually weakened. The crystal structure refinements indicate the weakened change at the magnetic transition is close related to the change of c/a ratio variation from tetragonal to cubic with Sn content. The results derived from this study indicate that the behavior of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N could potentially enhance its scientific and technical applications, such as spin torque transfer and hard magnets.

Sun, Ying, E-mail: sunying@buaa.edu.cn [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng; Li, Jun; Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Wang, Cong [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); Feng, Hai L.; Sathish, Clastin I.; Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Matsushita, Yoshitaka [Analysis Station, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan)

2014-01-28T23:59:59.000Z

434

Iron-based soft magnetic composites with MnZn ferrite nanoparticles coating obtained by solgel method  

E-Print Network [OSTI]

­gel method Shen Wu a , Aizhi Sun a,n , Wenhuan Xu a , Qian Zhang a , Fuqiang Zhai a , Philip Logan b , Alex A-ray spectroscopy and distribution maps show that the iron particle surface is covered with a thin layer of Mn compared with the epoxy resin coated samples at 10 kHz. The effects of heat treatment temperature

Volinsky, Alex A.

435

Mineralogical heterogeneities in the Earth's mantle: Constraints from Mn, Co, Ni and Zn partitioning during partial melting  

E-Print Network [OSTI]

Mineralogical heterogeneities in the Earth's mantle: Constraints from Mn, Co, Ni and Zn online 1 June 2011 Editor: L. Stixrude Keywords: transition metals mineralogical heterogeneities are sensitive to changes in mineralogy or major element composition, and thus, are promising to trace

Lee, Cin-Ty Aeolus

436

X-ray magnetic circular dichroism in (Ge,Mn) compounds: experiments and modeling Samuel Tardif,1, 2,  

E-Print Network [OSTI]

X-ray magnetic circular dichroism in (Ge,Mn) compounds: experiments and modeling Samuel Tardif,1, 2: July 29, 2013) X-ray absorption (XAS) and x-ray magnetic circular dichroism (XMCD) spectra at the L2),6 and x-ray spectroscopy (x-ray absorption spec- troscopy, XAS, and x-ray magnetic circular

437

Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy  

SciTech Connect (OSTI)

Light-driven oxidation of water to dioxygen in plants, algae and cyanobacteria iscatalyzed within photosystem II (PS II) by a Mn4Ca cluster. Although the cluster has been studied by many different methods, the structure and the mechanism have remained elusive. X-ray absorption and emission spectroscopy and EXAFS studies have been particularly useful in probing the electronic and geometric structure, and the mechanism of the water oxidation reaction. Recent progress, reviewed here, includes polarized X-ray absorption spectroscopy measurements of PS II single crystals. Analysis of those results has constrained the Mn4Ca cluster geometry to a setof three similar high-resolution structures. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 Angstrom-resolution X-ray structures or other previously proposed models. The differences between the models derived from X-rayspectroscopy and crystallography are predominantly because of damage to the Mn4Ca cluster by X-rays under the conditions used for structure determination by X-ray crystallography. X-ray spectroscopy studies are also used for studying the changes in the structure of the Mn4Ca catalytic center as it cycles through the five intermediate states known as the Si-states (i=0-4). The electronic structure of the Mn4Ca cluster has been studied more recently using resonant inelastic X-ray scattering spectroscopy (RIXS), in addition to the earlier X-ray absorption and emission spectroscopy methods. These studies are revealing that the assignment of formaloxidation states is overly simplistic. A more accurate description should consider the charge density on the Mn atoms that includes the covalency of the bonds and delocalization of the charge over the cluster. The geometric and electronic structure of the Mn4Ca cluster in the S-states derived from X-ray spectroscopy are leading to a detailed understanding of the mechanism of the O-O bond formation during the photosynthetic water splitting process.

Yano, Junko; Yano, Junko; Yachandra, Vittal K.

2007-10-24T23:59:59.000Z

438

Thermodynamic and transport properties of single-crystal Yb{sub 14}MnSb{sub 11}  

SciTech Connect (OSTI)

Relatively large (up to 250 mg) single crystals of the intermetallic compound Yb{sub 14}MnSb{sub 11} have been prepared by a flux-growth technique. The results of thermodynamic and transport measurements of these samples are presented. The compound orders ferromagnetically at approximately T{sub C}=53{plus_minus}1K, with a magnetization consistent with the assignment Mn{sup 3+} (3d{sup 4}) and Yb{sup 2+} (4f{sup 14}). The Mn moments are local in nature, with the full effective and saturated moment of the Hund{close_quote}s rule spin-only ground state. The electrical resistivity has a metallic temperature dependence, with only a modest anisotropy. Room-temperature values of the resistivity are relatively high for an intermetallic compound: 1630{plus_minus}160 {mu}{Omega}cm and 1250{plus_minus}130 {mu}{Omega}cm for currents flowing approximately parallel and perpendicular to the {ital c} axis, respectively. There is a distinct loss of spin-disorder scattering in the resistivity at T{sub C}. From the heat capacity, a rough estimation of the magnetic entropy gives {Delta}S{sub M}{approx}12.1 J/mol K, the value in reasonable agreement with the expected {Delta}S{sub M}{approx}R ln 5 from the assignment of these moments. All of these data are consistent with a picture of Mn{sup 3+} local moments being coupled via conduction electrons. To this end, Yb{sub 14}MnSb{sub 11} appears to be analogous to local-moment rare-earth intermetallic compounds, and may point the way toward a class of 3d Kondo lattice compounds. {copyright} {ital 1999} {ital The American Physical Society}

Fisher, I.R.; Wiener, T.A.; Budko, S.L.; Canfield, P.C. [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States)] [Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Chan, J.Y.; Kauzlarich, S.M. [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)] [Department of Chemistry, One Shields Avenue, University of California, Davis, California 95616 (United States)

1999-06-01T23:59:59.000Z

439

Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion  

SciTech Connect (OSTI)

Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Abraham, Daniel P [Argonne National Laboratory (ANL); Huq, Ashfia [ORNL; Payzant, E Andrew [ORNL; Wood III, David L [ORNL; Daniel, Claus [ORNL

2014-01-01T23:59:59.000Z

440

Facile synthesis of {alpha}-MnO{sub 2} one-dimensional (1D) nanostructure and energy storage ability studies  

SciTech Connect (OSTI)

The dense manganese oxide nanorods with an extremely narrow distribution are synthesized at a low temperature using first cathodic electrodeposition subsequently heat treatment. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that the nanorods have bar shapes, and their average diameter is less than 50 nm. The Fourier transform infrared (FT-IR) study, the selected area electron diffraction (SAED) pattern in TEM images and the X-ray diffraction (XRD) result show that the nanorods are {alpha}-MnO{sub 2} single crystal. The results of N{sub 2} adsorption-desorption analysis indicate that the BET surface area of the {alpha}-MnO{sub 2} nanorods is 93 m{sup 2} g{sup -1}. By recording the potential-time curve during the electrodeposition process, it is revealed that water reduction reaction has a major role in the electrogeneration of base at the cathode surface under the applied electrochemical conditions. Finally, based on the H{sub 2} bubbling on the cathode surface, the mechanism of the formation and the growth of {alpha}-MnO{sub 2} nanorods are proposed and discussed. For the electrochemical supercapacitor application, electrochemically prepared {alpha}-MnO{sub 2} is found to be stable for a large number of cycles with high specific capacitance, 338 F g{sup -1} at a scan rate of 10 mV s{sup -1}. Finally, the charge-discharge mechanism is discussed. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer New nanostructures of MnO{sub 2} is synthesized by simple method of cathodicelectrodeposition. Black-Right-Pointing-Pointer The product has unique one-dimensional morphology with average diameter size of 50 nm. Black-Right-Pointing-Pointer The experiment conditions (temperature, current density) has not been reported. Black-Right-Pointing-Pointer The one-nanostructures obtained without using of hard template or surfactant.

Yousefi, Taher, E-mail: anozadg@yahoo.com [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Golikand, Ahmad Nozad, E-mail: taher_yosefy@yahoo.com [Materials Research School, NSTRI, PO Box: 14395-836, Tehran (Iran, Islamic Republic of); Hossein Mashhadizadeh, Mohammad [Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of); Aghazadeh, Mustafa [Department of Optic and Spectroscopy, Lasers and Optics Research School, NSTRI, PO Box: 11365-8486, Tehran (Iran, Islamic Republic of)

2012-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "detroit mn twin" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Polarized X-Ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II  

SciTech Connect (OSTI)

High-valent Mn-oxo species have been suggested to have a catalytically important role in the water splitting reaction which occurs in the Photosystem II membrane protein. In this study, five- and six-coordinate mononuclear Mn(V) compounds were investigated by polarized X-ray absorption spectroscopy in order to understand the electronic structure and spectroscopic characteristics of high-valent Mn species. Single crystals of the Mn(V)-nitrido and Mn(V)-oxo compounds were aligned along selected molecular vectors with respect to the X-ray polarization vector using X-ray diffraction. The local electronic structure of the metal site was then studied by measuring the polarization dependence of X-ray absorption near-edge spectroscopy (XANES) pre-edge spectra (1s to 3d transition) and comparing with the results of density functional theory (DFT) calculations. The Mn(V)-nitrido compound, in which the manganese is coordinated in a tetragonally distorted octahedral environment, showed a single dominant pre-edge peak along the MnN axis that can be assigned to a strong 3dz2-4pz mixing mechanism. In the square pyramidal Mn(V)-oxo system, on the other hand, an additional peak was observed at 1 eV below the main pre-edge peak. This component was interpreted as a 1s to 3dxz,yz transition with 4px,y mixing, due to the displacement of the Mn atom out of the equatorial plane. The XANES results have been correlated to DFT calculations, and the spectra have been simulated using a TD (time-dependent)-DFT approach. The relevance of these results to understanding the mechanism of the photosynthetic water oxidation is discussed.

Yano, J.K.; Robblee, J.; Pushkar, Y.; Marcus, M.A.; Bendix, J.; Workman, J.M.; Collins, T.J.; Solomon, E.I.; George, S.D.; Yachandra, V.K.; /LBL, Berkeley /Copenhagen U. /Stanford U., Chem. Dept. /SLAC, SSRL

2007-10-16T23:59:59.000Z

442

Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures  

SciTech Connect (OSTI)

We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

2014-04-24T23:59:59.000Z

443

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode  

SciTech Connect (OSTI)

Electrochemically active LiMnPO4 nanoplates have been synthesized via novel single step solid state reaction in molten hydrocarbon. The LiMnPO4 prepared show unique porous nanoplate shape ~50nm in thickness with highly preferred crystallographic orientation. The reversible cycling of carbon coated LiMnPO4 show flat potential at 4.1 V vs. Li with specific capacity reaching up to 168mAh/g and excellent cycling performance using only galvanostatic charging / discharging mode.

Choi, Daiwon; Wang, Donghai; Bae, In-Tae; Xiao, Jie; Nie, Zimin; Wang, Wei; Viswanathan, Vilayanur V.; Lee, Yun Jung; Zhang, Jiguang; Graff, Gordon L.; Yang, Zhenguo; Liu, Jun

2010-08-11T23:59:59.000Z

444

Electronic Structure of the Mn(4)Ca Cluster in the Oxygen-Evolving Complex of Photosystem Ii Studied By Resonant Inelastic X-Ray Scattering  

SciTech Connect (OSTI)

Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i=0--4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra simultaneously. The second energy dimension separates the pre-edge (1s to 3d) transitions from the main K-edge (1s to 4p), and thus more precise analysis is possible. The 1s2p RIXS final state electron configuration along the energy transfer axis is identical to conventional L-edge absorption spectroscopy and the RIXS spectra are therefore sensitive to the metal spin state. We have collected data from PS II samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states are small compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms. The RIXS spectra of S{sub 0} and S{sub 3} states also showed characteristic features which were not clear from the K-edge spectroscopy.

Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.

2009-06-04T23:59:59.000Z

445

Heteroepitaxial growth and surface structure of L1{sub 0}-MnGa(111) ultra-thin films on GaN(0001)  

SciTech Connect (OSTI)

L1{sub 0}-structured MnGa(111) ultra-thin films were heteroepitaxially grown on GaN(0001) under lightly Mn-rich conditions using molecular beam epitaxy. Room-temperature scanning tunneling microscopy (STM) investigations reveal smooth terraces and angular step edges, with the surface structure consisting primarily of a 2 × 2 reconstruction along with small patches of 1 × 2. Theoretical calculations were carried out using density functional theory, and the simulated STM images were calculated using the Tersoff-Hamman approximation, revealing that a stoichiometric 1 × 2 and a Mn-rich 2 × 2 surface structure give the best agreement with the observed experimental images.

Mandru, Andrada-Oana; Wang, Kangkang; Cooper, Kevin; Ingram, David C.; Smith, Arthur R. [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States)] [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Garcia Diaz, Reyes; Takeuchi, Noboru [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States) [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Centro de Nanociencias y Nanotecnologia, Universidad Nacional Autónoma de México, Apartado Postal 14, Ensenada Baja California, Codigo Postal 22800 (Mexico); Haider, Muhammad [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States) [Department of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701 (United States); Department of Physics, King Fahd University of Petroleum and Minerals, Dhahran, 31261 (Saudi Arabia)

2013-10-14T23:59:59.000Z

446

Structure and Magnetic Ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) Organic-based Magnet (Tc = 171 K)  

SciTech Connect (OSTI)

Mn{sup II}(TCNE)I(OH{sub 2}) was isolated from the reaction of tetracyanoethylene (TCNE) and MnI{sub 2}(THF){sub 3}, and has a 2-D structure possessing an unusual, asymmetric bonded {mu}{sub 4}-[TCNE]{sup {sm_bullet}-}. Direct antiferromagnetic coupling between the S = 5/2 Mn{sup II} and S = 1/2 [TCNE]{sup {sm_bullet}-} leads to magnetic ordering as a canted antiferromagnet at a T{sub c} of 171 K.

S Lapidus; A McConnell; P Stephens; J Miller

2011-12-31T23:59:59.000Z

447

Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism  

SciTech Connect (OSTI)

Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

Jamer M.; Sterbinsky G.; Assaf, B.; Arena, D.; Heiman, D.

2014-12-07T23:59:59.000Z

448

Imaging Molecular Gas in the Luminous Merger NGC 3256 : Detection of High-Velocity Gas and Twin Gas Peaks in the Double Nucleus  

E-Print Network [OSTI]

Molecular gas in the merging starburst galaxy NGC 3256 has been imaged with the Submillimeter Array at a resolution of 1'' x 2'' (170 x 340 pc at 35 Mpc). This is the first interferometric imaging of molecular gas in the most luminous galaxy within z=0.01. There is a large disk of molecular gas (r > 3 kpc) in the center of the merger with a strong gas concentration toward the double nucleus. The gas disk having a mass of ~3*10^9 Msun in the central 3 kpc rotates around a point between the two nuclei that are 850 pc apart on the sky. The molecular gas is warm and turbulent and shows spatial variation of the intensity ratio between CO isotopomers. High-velocity molecular gas is discovered at the galactic center. Its velocity in our line of sight is up to 420 km/s offset from the systemic velocity of the galaxy; the terminal velocity is twice as large as that due to the rotation of the main gas disk. The high-velocity gas is most likely due to a molecular outflow from the gas disk, entrained by the starburst-driven superwind in the galaxy. The molecular outflow is estimated to have a rate of ~10 Msun/yr and to play a significant role in the dispersal or depletion of molecular gas from the galactic center. A compact gas concentration and steep velocity gradient are also found around each of the twin nuclei. They are suggestive of a small gas disk rotating around each nucleus. If these are indeed mini-disks, their dynamical masses are ~10^9 Msun within a radius of 170 pc.

Kazushi Sakamoto; Paul T. P. Ho; Alison B. Peck

2006-03-03T23:59:59.000Z

449

Oxygen reduction at a stabilized zirconia interface with Y[sub 1-x]Ca[sub x]MnO[sub 3] or La[sub 1-x]Sr[sub x]MnO[sub 3] cathode materials  

SciTech Connect (OSTI)

Impedance spectroscopy, combined with an unbonded interface cell, has been used to assess oxygen reduction behavior at interfaces between an yttria-stabilized zirconia electrolyte and perovskite or platinum cathode materials. Intrinsic oxygen reduction specific activities of Y[sub 1-x]Ca[sub x]MnO[sub 3] (x = 0.5, 0.6 and 0.7) and La[sub 1-x]Sr[sub x]MnO[sub 3] (x = 0.1 and 0.3) were determined as a function of temperature and oxygen partial pressure, independent of the interface morphology. The overall cathodic interfacial polarization consists of two or more fundamental processes. In the temperature range of 900--1000C and in air, the operating conditions for a solid oxide fuel cell, charge transfer and oxygen dissociation processes were approximately equivalent relative to the overall oxygen reduction kinetics.

Youngblood, G.E.; Pederson, L.R.; Bates, J.L. (Pacific Northwest Lab., Richland, WA (United States)); Rupaal, A.S. (Western Washington Univ., Bellingham, WA (United States))

1993-05-01T23:59:59.000Z

450

Oxygen reduction at a stabilized zirconia interface with Y{sub 1-x}Ca{sub x}MnO{sub 3} or La{sub 1-x}Sr{sub x}MnO{sub 3} cathode materials  

SciTech Connect (OSTI)

Impedance spectroscopy, combined with an unbonded interface cell, has been used to assess oxygen reduction behavior at interfaces between an yttria-stabilized zirconia electrolyte and perovskite or platinum cathode materials. Intrinsic oxygen reduction specific activities of Y{sub 1-x}Ca{sub x}MnO{sub 3} (x = 0.5, 0.6 and 0.7) and La{sub 1-x}Sr{sub x}MnO{sub 3} (x = 0.1 and 0.3) were determined as a function of temperature and oxygen partial pressure, independent of the interface morphology. The overall cathodic interfacial polarization consists of two or more fundamental processes. In the temperature range of 900--1000C and in air, the operating conditions for a solid oxide fuel cell, charge transfer and oxygen dissociation processes were approximately equivalent relative to the overall oxygen reduction kinetics.

Youngblood, G.E.; Pederson, L.R.; Bates, J.L. [Pacific Northwest Lab., Richland, WA (United States); Rupaal, A.S. [Western Washington Univ., Bellingham, WA (United States)

1993-05-01T23:59:59.000Z

451

Room-temperature photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seen via soft x-ray magnetic circular dichroism  

E-Print Network [OSTI]

photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seendoped garnets 1 , doped spinel ferrites 2 , doped perovskiteIn the doped garnets and ferrites, the microscopic origin of

Bettinger, J.S.

2010-01-01T23:59:59.000Z

452

Mon. Not. R. Astron. Soc. 000, 1?? (2002) Printed 3 November 2011 (MN LATEX style file v2.2) A generalised porosity formalism for isotropic and  

E-Print Network [OSTI]

the first X-ray line profiles computed directly from line-driven instability simulations using a 3-D patchMon. Not. R. Astron. Soc. 000, 1­?? (2002) Printed 3 November 2011 (MN LATEX style file v2

Cohen, David

453

Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO? and LiFePO? using Hybrid Density Functional Theory  

E-Print Network [OSTI]

Using hybrid density functional theory based on the Heyd-Scuseria-Ernzerhof (HSE06) functional, we compared polaron migration and phase separation in olivine LiMnPO? to LiFePO?. The barriers for free hole and electron ...

Ong, Shyue Ping

454

Effect of ball milling and post-annealing on magnetic properties of Ni49.8Mn28.5Ga21.7 alloy powders  

E-Print Network [OSTI]

, The University of Western Australia, Crawley WA6009, Australia c Department of Advanced Materials mechanical energy absorption [8,9]. Ni­Mn­Ga powders have been prepared by various methods, including spark

Zheng, Yufeng

455

doi:10.1016/j.gca.2005.03.018 Natural speciation of Mn, Ni, and Zn at the micrometer scale in a clayey paddy soil using  

E-Print Network [OSTI]

, Berkeley, CA 94720, USA 6 Department of Agricultural Chemistry, National Taiwan University, Taipei, Taiwan-supporting clay film from the 2 m fraction of the soil. Manganese was concentrated in Fe-Mn soft mottles (44.4 g

456

Electroluminescence of InGaAs/GaAs quantum-size heterostructures with (III, Mn)V and Ni ferromagnetic injectors  

SciTech Connect (OSTI)

Electroluminescence characteristics of light-emitting diodes based on InGaAs/GaAs quantum well heterostructures with an injector layer made of ferromagnetic metal (Ni), semimetal compound (MnSb), or magnetic semiconductor (InMnAs) were comparatively studied. The general feature is electroluminescence quenching as the spacer layer thickness between a quantum well and a magnetic injector decreases. It was found that the temperature dependence of the electroluminescence in diodes with Ni and MnSb is caused by thermal ejection of carriers from the quantum well; in diodes with InMnAs, it is caused by the temperature dependence of the carrier concentration in magnetic semiconductor and thermal ejection of carriers from the quantum well in the high-temperature region.

Prokof'eva, M. M., E-mail: marinaprkfeva@rambler.ru [Lobachevsky State University (Russian Federation); Dorokhin, M. V.; Danilov, Yu. A.; Kudrin, A. V.; Vikhrova, O. V. [Lobachevsky State University of Nizhni Novgorod, Physicotechnical Research Institute (Russian Federation)

2010-11-15T23:59:59.000Z

457

X-ray and neutron scattering studies of the Rb?MnF? and Cu?â??õxMgx̳GeO? in an external magnetic field  

E-Print Network [OSTI]

This thesis presents results of two scattering studies of low dimensional magnetic materials. The first is a neutron scattering study of Rb2MnF4, a nearly ideal two-dimensional square lattice Heisenberg antiferromagnet ...

Christianson, Rebecca J. (Rebecca Jean), 1973-

2001-01-01T23:59:59.000Z

458

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

G. J. Exarhos: Glycine-nitrate Combustion Synthesis of Oxideby the Nitrate-Citrate Combustion Method. Mat. Res. Bull.Combustion Synthesis of Nanoparticulate LiMg x Mn 1-x PO 4 (

Doeff, Marca M

2010-01-01T23:59:59.000Z

459

Bicolor Mn-doped CuInS{sub 2}/ZnS core/shell nanocrystals for white light-emitting diode with high color rendering index  

SciTech Connect (OSTI)

We synthesized bicolor Mn-doped CuInS{sub 2} (CIS)/ZnS core/shell nanocrystals (NCs), in which Mn{sup 2+} ions and the CIS core were separated with a ZnS layer, and both Mn{sup 2+} ions and CIS cores could emit simultaneously. Transmission electron microscopy and powder X-ray diffraction measurements indicated the epitaxial growth of ZnS shell on the CuInS{sub 2} core, and electron paramagnetic resonance spectrum indicated that Mn{sup 2+} ions were on the lattice points of ZnS shell. By integrating these bicolor NCs with commercial InGaN-based blue-emitting diodes, tricolor white light-emitting diodes with color rendering index of 83 were obtained.

Huang, Bo; Dai, Qian; Zhang, Huichao; Liao, Chen; Cui, Yiping; Zhang, Jiayu, E-mail: jyzhang@seu.edu.cn [Advanced Photonic Center, Southeast University, Nanjing 210096 (China); Zhuo, Ningze; Jiang, Qingsong; Shi, Fenghua; Wang, Haibo [Research Institute of Electric Light Source Materials, Nanjing University of Technology, Nanjing 210015 (China)

2014-09-07T23:59:59.000Z

460

Temperature dependence of magnetic properties of La0.7Sr0.3MnO3SrTiO3 thin films on silicon substrates  

E-Print Network [OSTI]

by a 20-nm-thick SrTiO3 001 buffer layer. X-ray diffraction and atomic force microscopy studies. INTRODUCTION Perovskite manganites RE 1-x AE xMnO3, where RE =rare earth and AE=alkaline earth formTemperature dependence of magnetic properties of La0.7Sr0.3MnO3Ã?SrTiO3 thin films on silicon

Boyer, Edmond

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461

Perpendicular-to-Parallel Spin Reorientation in a Mn-Doped GaAs Quantum Canting or Phase Separation  

SciTech Connect (OSTI)

It is well known that the magnetic anisotropy in a compressively-strained Mn-doped GaAs film changes from perpendicular to parallel with increasing hole concentration p. We study this reorientation transition at T = 0 for a quantum well with Mn impurities confined to the z = 0 plane. With increasing p, the angle 0 that minimizes the energy E increases continuously from 0 (perpendicular anisotropy) to /2 (parallel anisotropy) within some range of p. The shape of Emin(p) suggests that the quantum well becomes phase separated with regions containing low hole concentrations and perpendicular moments interspersed with other regions containing high hole concentrations and parallel moments. However, consideration of the Coulomb energy costs associated with phase separation suggests that the true magnetic state in the transition region is canted with 0 < < /2.

Fishman, Randy Scott [ORNL; Reboredo, Fernando A [ORNL; Brandt, Alex B [ORNL; Moreno, Juana [University of North Dakota, Grand Forks

2007-01-01T23:59:59.000Z

462

Conditions for spin-gapless semiconducting behavior in Mn{sub 2}CoAl inverse Heusler compound  

SciTech Connect (OSTI)

Employing ab initio electronic structure calculations, we investigate the conditions for spin-gapless semiconducting (SGS) behavior in the inverse Mn{sub 2}CoAl Heusler compound. We show that tetragonalization of the lattice, which can occur during films growth, keeps the SGS character of the perfect cubic compound. On the contrary, atomic swaps even between sites with different local symmetry destroy the SGS character giving rise to a half-metallic state. Furthermore, the occurrence of Co-surplus leads also to half-metallicity. Thus, we propose that in order to achieve SGS behavior during the growth of Mn{sub 2}CoAl (and similar SGS Heusler compounds) thin films, one should minimize the occurrence of defects, while small deformations of the lattice, due to the lattice mismatch with the substrate, do not play a crucial role.

Galanakis, I., E-mail: galanakis@upatras.gr [Department of Materials Science, School of Natural Sciences, University of Patras, GR-26504 Patra (Greece); Özdo?an, K., E-mail: kozdogan@yildiz.edu.tr [Department of Physics, Yildiz Technical University, 34210 ?stanbul (Turkey); ?a??o?lu, E.; Blügel, S. [Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, 52425 Jülich (Germany)

2014-03-07T23:59:59.000Z

463

Magneto-transport properties of oriented Mn{sub 2}CoAl films sputtered on thermally oxidized Si substrates  

SciTech Connect (OSTI)

Spin gapless semiconductors are interesting family of materials by embracing both magnetism and semiconducting due to their unique band structure. Its potential application in future spintronics requires realization in thin film form. In this Letter, we report fabrication and transport properties of spin gapless Mn{sub 2}CoAl films prepared on thermally oxidized Si substrates by magnetron sputtering deposition. The films deposited at 673?K are well oriented to (001) direction and display a uniform-crystalline surface. Magnetotransport measurements on the oriented films reveal a semiconducting-like resistivity, small anomalous Hall conductivity, and linear magnetoresistance representative of the transport signatures of spin gapless semiconductors. The magnetic properties of the films have also been investigated and compared to that of bulk Mn{sub 2}CoAl, showing small discrepancy induced by the composition deviation.

Xu, G. Z.; Du, Y.; Zhang, X. M.; Liu, E. K.; Wang, W. H., E-mail: wenhong.wang@iphy.ac.cn; Wu, G. H. [State Key Laboratory for Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Zhang, H. G. [College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124 (China)

2014-06-16T23:59:59.000Z

464

Electrode Materials with the Na0.44MnO2 Structure: Effect ofTitanium Substitution on Physical and Electrochemical Properties  

SciTech Connect (OSTI)

The physical and electrochemical properties of LixMnO2 and LixTi0.11Mn0.89O2 synthesized from precursors made by glycine-nitrate combustion (GNC) and solid-state synthesis methods (SS) are examined in this paper. The highest specific capacities in lithium cells are obtained for SS-LixMnO2 electrodes at low current densities, but GNC-LixTi0.11Mn0.89O2 electrodes show the best high rate performance. These results can be explained by changes in the voltage characteristics and differences in the particle morphologies induced by the Ti-substitution and synthesis method. Ti-substitution also results in a decrease in the electronic conductivity, but greatly improves the thermal properties and imparts dissolution resistance to the electrode. For these reasons, it is preferable to use LixTi0.11MnO0.89O2 in lithium battery configurations rather than LixMnO2. Suggestions for improving the electrochemical performance of the Ti-substituted variant are given based on the results described herein.

Doeff, Marca M; Saint, Juliette A.; Doeff, Marca M; Wilcox, James D.

2008-03-10T23:59:59.000Z

465

Nanometer-scale electrochemical patterning of LiMn2O4 surfaces by an atomic force microscope operating in air  

SciTech Connect (OSTI)

Electrochemical nanometer-scale patterning of the surface of a conducting lithium manganese oxide (LiMn{sub 2}O{sub 4}) by scanning probe microscopy (SPM) was studied. The ability to produce nanometer-size patterns of chemically modified oxide or nanometer-sized alterations of the oxide morphology is demonstrated and discussed with reference to possible mechanisms. It is demonstrated that unlike the SPM-based surface oxidation of metals and semiconductors, the LiMn{sub 2}O{sub 4} surface is altered via electrochemically generated species. We show that a localized surface chemical change can be confined to a depth which depends on the oxide-tip voltage difference and ambient humidity. In situ Raman microscopy measurements of localized electrochemical reaction products suggest complex mechanisms of processes induced at the LiMn{sub 2}O{sub 4} surface, such as delithiation through Li-proton exchange and disproportionation of LiMn{sub 2}O{sub 4} to MnO{sub 2} and soluble Mn{sup 2+} species.

Kostecki, Robert; Bonhomme, Frederic; Servant, Laurent; Argoul, Francoise; McLarnon, Frank

2001-06-22T23:59:59.000Z

466

Observation of the large magnetocaloric effect and suppression of orbital entropy change in Fe-doped MnV{sub 2}O{sub 4}  

SciTech Connect (OSTI)

We present the structural and magnetic properties of Mn{sub 1?x}Fe{sub x}V{sub 2}O{sub 4} (x = 0.1, 0.2, and 0.3), and investigate the magnetocaloric effect in those compounds. The ferrimagnetic spin ordering is enhanced with the Fe doping at Mn site of MnV{sub 2}O{sub 4}, while the orbital ordering is suppressed. Large magnetic entropy changes up to 3.8 J/kg?K as well as the relative cooling power up to 110 J/kg at the field change of 0-2 T for Mn{sub 1?x}Fe{sub x}V{sub 2}O{sub 4} are calculated from the isothermal magnetization measurements. The large orbital entropy change of MnV{sub 2}O{sub 4} is suppressed by the Fe doping, while the spin entropy contribution arising from the strong spin-orbit coupling remains. Moreover, the doping of Fe broadens the temperature span of the large magnetic entropy change and increases the relative cooling power of MnV{sub 2}O{sub 4} by 2.4 times.

Huang, Z. H. [High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031 (China); Luo, X., E-mail: xluo@issp.ac.cn, E-mail: ypsun@issp.ac.cn; Hu, L.; Tan, S. G.; Liu, Y.; Yuan, B.; Chen, J.; Song, W. H. [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China and University of Science and Technology of China, Hefei 230026 (China); Sun, Y. P., E-mail: xluo@issp.ac.cn, E-mail: ypsun@issp.ac.cn [High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031 (China); Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China and University of Science and Technology of China, Hefei 230026 (China)

2014-01-21T23:59:59.000Z

467

Threshold effects for resistance to optical damage and nonvolatile holographic storage properties in In:Mn:Fe:LiNbO3 crystals  

SciTech Connect (OSTI)

The threshold concentration for In2O3 was found in In:Mn:Fe:LiNbO3 crystals by measurement of the infrared spectra of the crystals. The resistance of the In:Mn:Fe:LiNbO3 crystals to optical damage is characterized by changes in photoinduced birefringence as well as by distortion of the transmitted beam pattern. The resistance increases remarkably when the concentration of In2O3 exceeds its threshold. The resistance to optical damage of a In(3.0 mol. %):Mn:Fe:LiNbO3 crystal is 2 orders of magnitude higher that of a Mn:Fe:LiNbO3 crystal. The dependence of defects on the resistance to optical damage of the In:Mn:Fe:LiNbO3 crystals is discussed in detail. Nonvolatile holographic storage was achieved for all crystals, and the sensitivity of the In(3.0 mol. %):Mn:Fe:LiNbO3 crystal is much higher than that of the others.

Zhen Xihe; Li Qiang; Xu Yuheng

2005-07-20T23:59:59.000Z

468

Investigations of the electronic and magnetic structures of Co{sub 2}YGa (Y=Cr, Mn) Heusler alloys and their (100) surfaces  

SciTech Connect (OSTI)

Density functional theory calculations are performed to investigate the structural, electronic, and magnetic properties of bulk structures of Co{sub 2}YGa (Y?=?Cr, Mn) Heusler alloys and the surfaces along the (100) orientation. The bulk structures of both alloys show a ferromagnetic behavior with total magnetic moments of 3.03?{sub B} and 4.09?{sub B} and high spin polarizations of 99% and 67% for Co{sub 2}CrGa and Co{sub 2}MnGa, respectively. The surfaces are found to exhibit corrugations due to different relaxations of the surface atoms. For the case of Co{sub 2}CrGa, two surfaces preserve the half metallicity, namely those with Cr-Ga and Ga– terminations with high spin polarizations above 90%, whereas it dropped to about 50% for the other surfaces. However, the spin polarizations of Co-Co and Mn-Ga terminated surfaces remain close to that of bulk Co{sub 2}MnGa alloy, whereas it is suppressed down to 17% for Co– termination. The highest local magnetic moments are found to be 3.26??{sub B} and 4.11??{sub B} for Cr and Mn surface atoms in Cr-Ga and Mn– terminated surfaces, respectively.

Hamad, Bothina, E-mail: b.hamad@ju.edu.jo [Physics Department, The University of Jordan, Amman-11942 (Jordan)

2014-03-21T23:59:59.000Z

469

The origin and evolution of the odd-Z iron-peak elements Sc, V, Mn, and Co in the Milky Way stellar disk  

E-Print Network [OSTI]

AIMS: The aim of this study is to investigate the origin and evolution of Sc, V, Mn, and Co for a homogeneous and statistically significant sample of stars probing the different populations of the Milky Way, in particular the thin and thick disks. METHODS: Using high-resolution spectra obtained with MIKE, FEROS, SOFIN, FIES, UVES and HARPS spectrographs, we determine Sc, V, Mn, and Co abundances for a large sample of F and G dwarfs in Solar neighbourhood. The method is based on spectral synthesis and using one-dimensional (1-D), plane-parallel, LTE model stellar atmospheres calculated with the MARCS 2012 code. NLTE corrections from literature were applied to Mn and Co. RESULTS: We find that the abundance trends derived for Sc (594 stars), V (466 stars), and Co (567 stars) are very similar to what has been observed for the alpha-elements in the thin and thick disks. On the contrary Mn (569 stars) is generally underabundant relative to the Sun (i.e. [Mn/Fe]<0) for [Fe/H]<0. Also, for Mn, when NLTE correct...

Battistini, Chiara

2015-01-01T23:59:59.000Z

470

Synthesis of Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures with excellent adsorption performance  

SciTech Connect (OSTI)

Large-scale Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures with cube-shaped and dumbbell-shaped morphologies have been synthesized trough a facile and low-cost method. The microscopy analyses indicate that the core-shell microcubes have an average edge length of 2.5 {mu}m with a shell thickness of about 150 nm, and the core-shell microdumbbells were formed with a length of about 3 {mu}m and shell thickness of about 160 nm. The possible formation mechanism was discussed on the basis of transmission electron microscopy observations. The novel homogeneous core/hollow-shell structures were found to exhibit excellent performance in wastewater treatment. - Graphical abstract: A simple method is described for fabrication of Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures and the as-prepared materials showed a good ability to remove an organic pollutant in waste water. Highlights: Black-Right-Pointing-Pointer The Mn{sub 2}O{sub 3} homogeneous core/hollow-shell structures were successfully prepared. Black-Right-Pointing-Pointer A simple and high yield method was employed to fabricate such novel structure. Black-Right-Pointing-Pointer The products showed a good ability to remove an organic pollutant in waste water.

Cao Jie, E-mail: candj@mail.ustc.edu.cn [Anhui Provincial Key Lab of Photonics Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China); Mao Qinghe [Anhui Provincial Key Lab of Photonics Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Qian Yitai [Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2012-07-15T23:59:59.000Z

471

MnSOD marks cord blood late outgrowth endothelial cells and accompanies robust resistance to oxidative stress  

SciTech Connect (OSTI)

Cord blood is source of colony-forming progenitors to vascular endothelial cells for potential use in cell therapies. These cells-called blood late outgrowth endothelial cells (OECs)-have undergone endothelial differentiation, but appear to still possess functional properties different from mature endothelial cells. A large-scale comparative proteomics screen of cord blood OECs versus human vein endothelial cells (HUVECs) using two-dimensional gel electrophoresis and mass spectrometry identified specific expression of manganese superoxide dismutase (MnSOD), a key antioxidant enzyme expressed in the mitochondria, in OECs but not in HUVECs. Immunoblotting verified significant MnSOD levels in all OEC isolates tested and maintained throughout passaging. Endothelial function and cell survival/proliferation assays in the presence of high cytotoxic doses of the superoxide generator compound LY83583 showed OECs profoundly better protected against oxidative stress than HUVECs. Such cytoprotective levels of MnSOD cells could give therapeutic cell transplants a survival advantage in necrotic or ischemic conditions.

Cai Hao [Department of Obstetrics, University Hospital Zurich (Switzerland); Gehrig, Peter [Functional Genomics Center Zurich, University of Zurich, Swiss Federal Institute of Technology, Zurich (Switzerland); Scott, Thomas M. [Functional Genomics Center Zurich, University of Zurich, Swiss Federal Institute of Technology, Zurich (Switzerland); Zimmermann, Roland [Department of Obstetrics, University Hospital Zurich (Switzerland); Schlapbach, Ralph [Functional Genomics Center Zurich, University of Zurich, Swiss Federal Institute of Technology, Zurich (Switzerland); Zisch, Andreas H. [Department of Obstetrics, University Hospital Zurich (Switzerland) and Center for Integrative Human Physiology, University of Zurich, Zurich (Switzerland)]. E-mail: andreas.zisch@usz.ch

2006-11-17T23:59:59.000Z

472

Determination of elastic properties of a MnO{sub 2} coating by surface acoustic wave velocity dispersion analysis  

SciTech Connect (OSTI)

MnO{sub 2} is a material of interest in the development of high energy-density batteries, specifically as a coating material for internal 3D structures, thus ensuring rapid energy deployment. Its electrochemical properties have been mapped extensively, but there are, to the best of the authors' knowledge, no records of the elastic properties of thin film MnO{sub 2}. Impulsive stimulated thermal scattering (ISTS), also known as the heterodyne diffraction or transient grating technique, was used to determine the Young's modulus (E) and porosity (?) of a 500?nm thick MnO{sub 2} coating on a Si(001) substrate. ISTS is an all optical method that is able to excite and detect surface acoustic waves (SAWs) on opaque samples. From the measured SAW velocity dispersion, the Young's modulus and porosity were determined to be E?=?25?±?1?GPa and ?=42±1%, respectively. These values were confirmed by independent techniques and determined by a most-squares analysis of the carefully fitted SAW velocity dispersion. This study demonstrates the ability of the presented technique to determine the elastic parameters of a thin, porous film on an anisotropic substrate.

Sermeus, J.; Glorieux, C., E-mail: christ.glorieux@fys.kuleuven.be [Laboratory for Acoustics and Thermal Physics, KU Leuven, University of Leuven, Celestijnenlaan 200D, B-3001 Heverlee (Belgium); Sinha, R.; Vereecken, P. M. [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Center for Surface Chemistry and Catalysis, KU Leuven, University of Leuven, Kasteelpark Arenberg 23, B-3001 Leuven (Belgium); Vanstreels, K. [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium)

2014-07-14T23:59:59.000Z

473

Neutron diffraction studies on the Heusler alloy Ni{sub 50}Mn{sub 37}Sb{sub 13}  

SciTech Connect (OSTI)

The evolution of martensitic to austenitic transformation in Ni{sub 50}Mn{sub 37}Sb{sub 13} has been studied usingtemperature dependent neutron diffraction, thermal property, and magnetization studies. Differential scanning calorimetric studies reveal a martensitic transformation T{sub M} around 291 K. The magnetization data yield a ferromagnetic ordering temperature of 329 K in the austenitic phase and 230 K in the martensitic phase. The analysis of the powder neutron diffraction data in the temperature range of 325-12 K indicates a structural transition from a high temperature cubic L2{sub 1} type structure to an orthorhombic structure. At 270 K, both cubic and orthorhombic phases coexist. Anisotropic unit cell changes are observed at the martensitic transformation: The unit cell expands by about 1.5% along the a axis, by about 2.5% along the c axis, and compresses by about 4.28% along the b axis. Both cubic and orthorhombic phases show commensurate collinear ferromagnetic ordering with a magnetic moment of {approx}3.67 {mu}{sub B}/Mn in Mn (2a and 2f) sites.

Rama Rao, N. V.; Chelvane, J. Arout; Chandrasekaran, V. [Defence Metallurgical Research Laboratory, Hyderabad 500 058 (India); Morozkin, A. V. [Department of Chemistry, Moscow Lomonosov State University, Moscow 119992 (Russian Federation); Lamsal, J. [Department of Physics and Astronomy, University of Missouri-Columbia, Columbia, Missouri 65211 (United States); Yelon, W. B. [Materials Research Center and Department of Chemistry, Missouri University of Science and Technology, Rolla, Missouri 65409 (United States); Nirmala, R. [Department of Physics, Indian Institute of Technology Madras, Chennai 600 036 (India); Suresh, K. G. [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400 076 (India); Malik, S. K. [International Institute of Physics (IIP)-UFRN, Natal, 59072-970 (Brazil)

2011-04-01T23:59:59.000Z

474

Setting temperature effect in polycrystalline exchange-biased IrMn/CoFe bilayers  

SciTech Connect (OSTI)

We study the effect of atomic interdiffusion on the exchange bias of polycrystalline IrMn/({sup 57}Fe + CoFe) multilayers due to the thermal setting process of exchange coupling during field annealing. Depth-resolved {sup 57}Fe conversion electron Moessbauer spectroscopy was used to quantify atomic interdiffusion. Vibrating sample magnetometry was used to monitor the variation of exchange bias and magnetisation. It was found that interface sharpness is only affected above {approx}350 Degree-Sign C. Three different stages for the setting of exchange bias can be inferred from our results. At the lower setting temperatures (up to 350 Degree-Sign C), the effect of field annealing involves alignment of spins and interfacial coupling due to the setting of both antiferromagnetic (AF) bulk and interface without significant interdiffusion. At a second stage (350-450 Degree-Sign C), where AF ordering dominates over diffusion effects, atomic migration and increased setting of AF spins co-exist to produce a peak in exchange bias field and coercivity. On a third stage (>450 Degree-Sign C), severe chemical intermixing reduces significantly the F/AF coupling.

Fernandez-Outon, L. E.; Araujo Filho, M. S.; Araujo, R. E.; Ardisson, J. D.; Macedo, W. A. A. [Laboratorio de Fisica Aplicada, Centro de Desenvolvimento da Tecnologia Nuclear, 31270-901 Belo Horizonte, MG (Brazil)

2013-05-07T23:59:59.000Z

475

Phase diagram and magnetocaloric effects in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} alloys  

SciTech Connect (OSTI)

The magnetocaloric and thermomagnetic properties of Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x}) NiGe{sub 1.05} systems for 0???x???0.105 and 0???x???0.1, respectively, have been studied by x-ray diffraction, differential scanning calorimetry, and magnetization measurements. Partial substitution of Cr for Mn in (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} results in a first order magnetostructural transition from a hexagonal paramagnetic to an orthorhombic paramagnetic phase near T{sub M}???380?K (for x?=?0.07). Partial substitution of Cr for In in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} shifts the magnetostructural transition to a higher temperature (T?=?T{sub M}???450?K) for x?=?0.1. Large magnetic entropy changes of ?S?=??12 (J/(kgK)) and ?S?=??11 (J/(kgK)), both for a magnetic field change of 5?T, were observed in the vicinity of T{sub M} for (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} and Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15}, respectively.

Quetz, Abdiel, E-mail: anorve2002@yahoo.com; Muchharla, Baleeswaraiah; Dubenko, Igor; Talapatra, Saikat; Ali, Naushad [Southern Illinois University, Carbondale, Illinois 62901 (United States); Samanta, Tapas; Stadler, Shane [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803 (United States)

2014-05-07T23:59:59.000Z

476

Insight into the Atomic Structure of High-Voltage Spinel 2 LiNi0.5Mn1.5O4 Cathode Material  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations of local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely related to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.

Huang, Xuejie [Chinese Academy of Sciences, Beijing (China); Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States); Lin, Mingxiang [Chinese Academy of Sciences, Beijing (China); Ben, Liubin [Chinese Academy of Sciences, Beijing (China); Sun, Yang [Chinese Academy of Sciences, Beijing (China); Wang, Hao [Chinese Academy of Sciences, Beijing (China); Yang, Zhenzhong [Chinese Academy of Sciences, Beijing (China); Gu, Lin [Chinese Academy of Sciences, Beijing (China); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zhao, Haofei [Chinese Academy of Sciences, Beijing (China); Yu, Richeng [Chinese Academy of Sciences, Beijing (China); Armand, Michel [CIC Energigune, Alava (Spain)

2015-01-13T23:59:59.000Z

477

Itinerant and localized magnetic moments in ferrimagnetic Mn{sub 2}CoGa thin films identified with x-ray magnetic linear dichroism: experiment and ab initio theory  

SciTech Connect (OSTI)

Epitaxial thin films of the half-metallic X{sub a}-compound Mn{sub 2}CoGa (Hg{sub 2}CuTi prototype) were prepared by dc magnetron co-sputtering with different heat treatments on MgO (001) substrates. High-quality #12;lms with a bulk magnetization of 1.95(5) {mu}{sub #22;}B per unit cell were obtained. The average Mn magnetic moment and the Co moment are parallel, in agreement with theory. The x-ray magnetic circular dichroism spectra agree with calculations based on density functional theory and reveal the antiparallel alignment of the two inequivalent Mn moments. X-ray magnetic linear dichroism allows to distinguish between itinerant and localized Mn moments. It is shown that one of the two Mn moments has localized character, whereas the other Mn moment and the Co moment are itinerant.

Meinert, M.; Schmalhorst, J; Klewe, C.; Reiss, G.; Arenholz, E.; Bohnert, T.; Nielsch, K.

2011-08-08T23:59:59.000Z