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Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

LABORATORY EXPERIMENT 7 Determination of Copper in Copper Alloys  

E-Print Network [OSTI]

LABORATORY EXPERIMENT 7 Determination of Copper in Copper Alloys Two procedures for Cu Determination of Copper in Alloy A convenient example of an electrogravimetric method of analysis is the determination of copper in a sample of an alloy. Discussion This procedure is based on the deposition

Nazarenko, Alexander

2

Effects of copper doping on the electronic properties of CdS films sintered with CdCl2  

Science Journals Connector (OSTI)

Chlorine- and copper-doped polycrystalline CdS films were prepared by coating a slurry which consisted of CdS, CdCl2, CuCl2...and propylene glycol on a glass substrate and sintering in a nitrogen atmosphere, to i...

J. T. Moon; H. B. Im

1988-10-01T23:59:59.000Z

3

LABORATORY EXPERIMENT 7 The Iodometric Determination of Copper in Brass  

E-Print Network [OSTI]

LABORATORY EXPERIMENT 7 The Iodometric Determination of Copper in Brass Discussion The method. To perform it, a sample of pure copper foil (100% Cu with uncertainty lees than 0.2%) is treated as described above, simultaneously with your sample. From titration of pure copper standard you calculate the precise

Nazarenko, Alexander

4

Experimental Options for Determining the Temperature for the Onset of Sintering of Coal Ash  

Science Journals Connector (OSTI)

This paper presents a comparison of techniques that can be used to obtain the sintering temperature of coal ash. These techniques are thermal conductivity analysis (TCA), thermomechanical analysis (TMA), the compressive strength test (CS), and a proposed ...

A. Y. Al-Otoom; G. W. Bryant; L. K. Elliott; B. J. Skrifvars; M. Hupa; T. F. Wall

1999-12-29T23:59:59.000Z

5

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS  

SciTech Connect (OSTI)

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

Hoppe, Eric W.; LaFerriere, Brian D.; Maiti, Tapas C.; Soin, Aleksandr

2014-04-15T23:59:59.000Z

6

Measurement of the Sintering Kinetics of Coal Ash  

Science Journals Connector (OSTI)

Measurement of the Sintering Kinetics of Coal Ash ... A new technique has been developed to determine the sintering rate of coal ash based on the measurement of the pressure-drop across a pellet of ash. ... The technique developed in this study shows a good repeatability of the rate of sintering and confirms that viscous flow is the dominant mechanism for sintering of coal ash. ...

A. Y. Al-Otoom; L. K. Elliott; T. F. Wall; B. Moghtaderi

2000-08-16T23:59:59.000Z

7

River Sediment Analysis by Slurry Sampling FAAS: Determination of Copper, Zinc and Lead Flvia L. Alves, Solange Cadore, Wilson F. Jardim and Marco A. Z. Arruda*  

E-Print Network [OSTI]

Article River Sediment Analysis by Slurry Sampling FAAS: Determination of Copper, Zinc and Lead sediment analysis was developed. Using this procedure, copper, zinc and lead were determined. The influence of the nitric acid concentration on the slurry preparation, as well as the sediment particle size

Jardim, Wilson de Figueiredo

8

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

2000-07-18T23:59:59.000Z

9

Sintered wire annode  

DOE Patents [OSTI]

A plurality of high atomic number wires are sintered together to form a porous rod that is parted into porous disks which will be used as x-ray targets. A thermally conductive material is introduced into the pores of the rod, and when a stream of electrons impinges on the sintered wire target and generates x-rays, the heat generated by the impinging x-rays is removed by the thermally conductive material interspersed in the pores of the wires.

Falce, Louis R. (Surprise, AZ); Ives, R. Lawrence (Saratoga, CA)

2007-12-25T23:59:59.000Z

10

Fusibility and sintering characteristics of ash  

SciTech Connect (OSTI)

The temperature characteristics of ash fusibility are studied for a wide range of bituminous and brown coals, lignites, and shales with ratios R{sub B/A} of their alkaline and acid components between 0.03 and 4. Acritical value of R{sub B/A} is found at which the fusion temperatures are minimal. The sintering properties of the ashes are determined by measuring the force required to fracture a cylindrical sample. It is found that the strength of the samples increases sharply at certain temperatures. The alkali metal content of the ashes has a strong effect on their sintering characteristics.

Ots, A. A., E-mail: aots@sti.ttu.ee [Tallinn University of Technology (Estonia)

2012-03-15T23:59:59.000Z

11

Zone sintering of ceramic fuels  

DOE Patents [OSTI]

Cold pressed UC.sub.2 fuel compacts are sintered at temperatures greater than about 1850.degree. C. while in contact with a sintering facilitator material, e.g., tantalum, niobium, tungsten or a metal carbide such as uranium carbide, thereby allowing for a reduction in the overall porosity and leaving the desired product, i.e., a highly dense, large-grained uranium dicarbide. The process of using the sintering facilitator materials can be applied in the preparation of other carbide materials.

Matthews, R. Bruce (Falls Church, VA); Chidester, Kenneth M. (Los Alamos, NM); Moore, H. Gene (Los Alamos, NM)

1994-01-01T23:59:59.000Z

12

Properties of Bulk Sintered Silver As a Function of Porosity  

SciTech Connect (OSTI)

This report summarizes a study where various properties of bulk-sintered silver were investigated over a range of porosity. This work was conducted within the National Transportation Research Center's Power Device Packaging project that is part of the DOE Vehicle Technologies Advanced Power Electronics and Electric Motors Program. Sintered silver, as an interconnect material in power electronics, inherently has porosity in its produced structure because of the way it is made. Therefore, interest existed in this study to examine if that porosity affected electrical properties, thermal properties, and mechanical properties because any dependencies could affect the intended function (e.g., thermal transfer, mechanical stress relief, etc.) or reliability of that interconnect layer and alter how its performance is modeled. Disks of bulk-sintered silver were fabricated using different starting silver pastes and different sintering conditions to promote different amounts of porosity. Test coupons were harvested out of the disks to measure electrical resistivity and electrical conductivity, thermal conductivity, coefficient of thermal expansion, elastic modulus, Poisson's ratio, and yield stress. The authors fully recognize that the microstructure of processed bulk silver coupons may indeed not be identical to the microstructure produced in thin (20-50 microns) layers of sintered silver. However, measuring these same properties with such a thin actual structure is very difficult, requires very specialized specimen preparation and unique testing instrumentation, is expensive, and has experimental shortfalls of its own, so the authors concluded that the herein measured responses using processed bulk sintered silver coupons would be sufficient to determine acceptable values of those properties. Almost all the investigated properties of bulk sintered silver changed with porosity content within a range of 3-38% porosity. Electrical resistivity, electrical conductivity, thermal conductivity, elastic modulus, Poisson's ratio, and yield stress all depended on the porosity content in bulk-sintered silver. The only investigated property that was independent of porosity in that range was coefficient of thermal expansion.

Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL; Wang, Hsin [ORNL; Ferber, Mattison K [ORNL; Liang, Zhenxian [ORNL

2012-06-01T23:59:59.000Z

13

Copper studies for alternative salt disposition  

SciTech Connect (OSTI)

The purpose of this study is to determine, as functions of total copper loading and iron REDOX in glass, any dependence of the leaching behavior of borosilicate glass on metallic copper.

Brown, K.G.

2000-01-26T23:59:59.000Z

14

Dispersion strengthened copper  

DOE Patents [OSTI]

A composition of matter comprised of copper and particles which are dispersed throughout the copper, where the particles are comprised of copper oxide and copper having a coating of copper oxide, and a method for making this composition of matter.

Sheinberg, Haskell (Los Alamos, NM); Meek, Thomas T. (Knoxville, TN); Blake, Rodger D. (Santa Fe, NM)

1990-01-01T23:59:59.000Z

15

Dispersion strengthened copper  

DOE Patents [OSTI]

A composition of matter comprised of copper and particles which are dispersed throughout the copper, where the particles are comprised of copper oxide and copper having a coating of copper oxide, and a method for making this composition of matter.

Sheinberg, Haskell (Los Alamos, NM); Meek, Thomas T. (Knoxville, TN); Blake, Rodger D. (Santa Fe, NM)

1989-01-01T23:59:59.000Z

16

Intense pulsed light sintering of copper nanoink for printed electronics  

E-Print Network [OSTI]

During the arc plasma generation, the ?ash lamp emits anusing an arc plasma phenomenon in the xenon ?ash lamp [7].

Kim, Hak-Sung; Dhage, Sanjay R.; Shim, Dong-Eun; Hahn, H. Thomas

2009-01-01T23:59:59.000Z

17

Microwave sintering of boron carbide  

DOE Patents [OSTI]

A method for forming boron carbide into a particular shape and densifying the green boron carbide shape. Boron carbide in powder form is pressed into a green shape and then sintered, using a microwave oven, to obtain a dense boron carbide body. Densities of greater than 95% of theoretical density have been obtained. 1 tab.

Blake, R.D.; Katz, J.D.; Petrovic, J.J.; Sheinberg, H.

1988-06-10T23:59:59.000Z

18

Electroless copper plating  

DOE Patents [OSTI]

An optimized electroless copper plating technique is described suitable for plating electroless copper upon ceramics. 12 figs.

McHenry, M.R.

1998-12-15T23:59:59.000Z

19

Sintered wire cesium dispenser photocathode  

DOE Patents [OSTI]

A photoelectric cathode has a work function lowering material such as cesium placed into an enclosure which couples a thermal energy from a heater to the work function lowering material. The enclosure directs the work function lowering material in vapor form through a low diffusion layer, through a free space layer, and through a uniform porosity layer, one side of which also forms a photoelectric cathode surface. The low diffusion layer may be formed from sintered powdered metal, such as tungsten, and the uniform porosity layer may be formed from wires which are sintered together to form pores between the wires which are continuous from the a back surface to a front surface which is also the photoelectric surface.

Montgomery, Eric J; Ives, R. Lawrence; Falce, Louis R

2014-03-04T23:59:59.000Z

20

Copper fertilization in citrus seedlings  

E-Print Network [OSTI]

field (Boaventura, 2003). Copper deficiency is frequent inThe major association of copper with organic matter is instable complexes with copper. In citrus seedlings, copper

Almeida, Tatiana Rezende Pires; Leonel, Sarita

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Low temperature sintering of lanthanum strontium manganite-based...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Low temperature sintering of lanthanum strontium manganite-based contact pastes for SOFCs. Low temperature sintering of lanthanum strontium manganite-based contact pastes for...

22

Dispersion strengthened copper  

DOE Patents [OSTI]

A composition of matter is described which is comprised of copper and particles which are dispersed throughout the copper, where the particles are comprised of copper oxide and copper having a coating of copper oxide. A method for making this composition of matter is also described. This invention relates to the art of powder metallurgy and, more particularly, it relates to dispersion strengthened metals.

Sheinberg, H.; Meek, T.T.; Blake, R.D.

1990-01-09T23:59:59.000Z

23

Microwave sintering of nanocrystalline ceramics  

SciTech Connect (OSTI)

A single-mode cavity microwave furnace, operating in the TE{sub 103} mode at 2.45 GHz, has been set up at the Naval Research Laboratory (NRL) and is currently being used to investigate sintering of nanocrystalline ceramics. This presentation will discuss the apparatus used and the results obtained to date. The high purity Al{sub 2}O{sub 3} and TiO{sub 2} nanocrystalline powders were prepared by the sol-gel method. These powders were first uniaxially pressed to 14 MPa, CIP`ed to various pressures > 420 MPa and finally sectioned into wafers. The density of the green wafers was 30 to 38% TD. The wafers were heated in the microwave furnace for up to three hours at temperatures {<=} 1720{degrees}C. The temperature of the workpiece was monitored using an optical pyrometer. Final densities up to 80% TD have been obtained to date for Al{sub 2}O{sub 3} and up to 52% TD for TiO{sub 2}. Work is ongoing to characterize the sintered compacts, optimize the casketing for this furnace, and lay the groundwork for new studies using a 35 GHz gyrotron and quasioptical gyrotron tunable from 85 to 120 GHz.

Bruce, R.W. [United States Naval Academy, Annapolis, MD (United States); Rayne, R.; Chow, G.M. [Naval Research Lab., Washington, DC (United States)] [and others

1995-12-31T23:59:59.000Z

24

Compaction and Sintering of Mo Powders  

SciTech Connect (OSTI)

To support the development of Mo-99 production by NorthStar Medical Technologies, LLC, Mo metal powders were evaluated for compaction and sintering characteristics as they relate to Mo-100 accelerator target disk fabrication. Powders having a natural isotope distribution and enriched Mo-100 powder were examined. Various powder characteristics are shown to have an effect on both the compaction and sintering behavior. Natural Mo powders could be cold pressed directly to >90% density. All of the powders, including the Mo-100 samples, could be sintered after cold pressing to >90% density. As an example, a compacted Mo-100 disk reached 89.7% density (9.52 g/cm3) after sintering at 1000 C for 1 hr. in flowing Ar/4%H2. Higher sintering temperatures were required for other powder samples. The relationships between processing conditions and the resulting densities of consolidated Mo disks will be presented.

Nunn, Stephen D [ORNL] [ORNL; Kiggans, Jim [ORNL] [ORNL; Bryan, Chris [ORNL] [ORNL

2013-01-01T23:59:59.000Z

25

Pressureless sintering of whisker-toughened ceramic composites  

DOE Patents [OSTI]

A pressureless sintering method is disclosed for use in the production of whisker-toughened ceramic composites wherein the sintered density of composites containing up to about 20 vol. % SiC whiskers is improved by reducing the average aspect ratio of the whiskers to from about 10 to about 20. Sintering aids further improve the density, permitting the production of composites containing 20 vol. % SiC with sintered densities of 94% or better of theoretical density by a pressureless sintering method.

Tiegs, T.N.

1993-05-04T23:59:59.000Z

26

Sintered electrode for solid oxide fuel cells  

DOE Patents [OSTI]

A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

1999-01-01T23:59:59.000Z

27

Nanoparticle coalescence and sintering: molecular dynamics simulation  

Science Journals Connector (OSTI)

Molecular Dynamics (MD) simulations are employed to better understand coalescence and sintering processes of gold nanoparticles. During coalescence in the liquid phase, the initial neck growth can be well described by the viscous flow model. With initial temperature right below the single particle melting temperature, the initial neck growth is controlled by viscous flow at first and then, by grain boundary diffusion. At initial temperatures well below melting, the sintering process occurs very rapidly, which may be attributed to a formation of liquid-like neck regions. The sintering of two free Au nanoparticles irradiated by a femtosecond laser pulse is also simulated by combining the two-temperature and MD models. It is shown that by increasing laser input energy, nanoparticles can be melted forming a single larger nanoparticle. The effects of multinanoparticle melting, solidification and sintering are also investigated.

N. Wang; S.I. Rokhlin; D.F. Farson

2007-01-01T23:59:59.000Z

28

Solid-state sintering of tungsten heavy alloys  

SciTech Connect (OSTI)

Solid-state sintering is a technologically important step in the fabrication of tungsten heavy alloys. This work addresses practical variables affecting the sinterability: powder particle size, powder mixing, and sintering temperature and time. Compositions containing 1 to 10 micrometer ({mu}M) tungsten (W) powders can be fully densified at temperatures near the matrix solidus. Blending with an intensifier bar provided good dispersion of elemental powders and good as-sintered mechanical properties under adequate sintering conditions. Additional ball milling increases powder bulk density which primarily benefits mold and die filling. Although fine, 1 {mu}m W powder blends have high sinterability, higher as-sintered ductilities are reached in shorter sintering times with coarser, 5 {mu}m W powder blends; 10{mu}m W powder blends promise the highest as-sintered ductilities due to their coarse microstructural W.

Gurwell, W.E.

1994-10-01T23:59:59.000Z

29

CX-005780: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

80: Categorical Exclusion Determination 80: Categorical Exclusion Determination CX-005780: Categorical Exclusion Determination Sintered Copper Zinc Tin Selenium Nanoparticle Solar Cells on Metal Foil CX(s) Applied: A9, A11, B3.6 Date: 05/11/2011 Location(s): San Jose, California Office(s): Energy Efficiency and Renewable Energy, Golden Field Office The Photovoltaic (PV) Technology Incubator project represents a significant component of the United States (U.S.) Department of Energy (DOE) business strategy of partnering with U.S. industry to accelerate the commercialization of photovoltaic system research and development (R&D) to meet aggressive cost and installed capacity goals. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-005780.pdf More Documents & Publications Bertrand Fillon, Commissariat Ă  l'Energie Atomique et aux Energies

30

EFFECTS OF COPPER ON EARLY LIFE HISTORY STAGES OF NORTHERN ANCHOVY, ENGRAULIS MORDAX  

E-Print Network [OSTI]

EFFECTS OF COPPER ON EARLY LIFE HISTORY STAGES OF NORTHERN ANCHOVY, ENGRAULIS MORDAX D. W. RICE, JR.,l F. L. HARRISON,l AND A. JEARLD, JR.2 ABSTRACT The sensitivity to copper of embryonic and larval total copper concentrations and the percent copper in labile forms were determined. From the cumulative

31

Process for microwave sintering boron carbide  

DOE Patents [OSTI]

A method of microwave sintering boron carbide comprises leaching boron carbide powder with an aqueous solution of nitric acid to form a leached boron carbide powder. The leached boron carbide powder is coated with a glassy carbon precursor to form a coated boron carbide powder. The coated boron carbide powder is consolidated in an enclosure of boron nitride particles coated with a layer of glassy carbon within a container for microwave heating to form an enclosed coated boron carbide powder. The enclosed coated boron carbide powder is sintered within the container for microwave heating with microwave energy.

Holcombe, C.E.; Morrow, M.S.

1993-10-12T23:59:59.000Z

32

Process for microwave sintering boron carbide  

DOE Patents [OSTI]

A method of microwave sintering boron carbide comprises leaching boron carbide powder with an aqueous solution of nitric acid to form a leached boron carbide powder. The leached boron carbide powder is coated with a glassy carbon precursor to form a coated boron carbide powder. The coated boron carbide powder is consolidated in an enclosure of boron nitride particles coated with a layer of glassy carbon within a container for microwave heating to form an enclosed coated boron carbide powder. The enclosed coated boron carbide powder is sintered within the container for microwave heating with microwave energy.

Holcombe, Cressie E. (440 Sugarwood Dr., Knoxville, TN 37922); Morrow, Marvin S. (Rte. #3, Box 113, Kingston, TN 37763)

1993-01-01T23:59:59.000Z

33

Sintered electrode for solid oxide fuel cells  

DOE Patents [OSTI]

A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

Ruka, R.J.; Warner, K.A.

1999-06-01T23:59:59.000Z

34

Chapter 7 - Copper Recycling  

Science Journals Connector (OSTI)

Abstract This chapter gives a brief overview of copper recycling from a metallurgist's view. As it is deemed impossible to give an in-depth presentation of such a broad and complex subject, a selection of references is given for further reading. Secondary sources of copper include a large variety of raw materials, ranging from slags, sludge and low-grade copper scrap, containing only a few percent Cu up to very high-grade copper as well as pure copper close to 100% Cu. Thus there are several options for recycling processes, within both primary and secondary plants. Although there are good recycling rates for copper, some challenges can be foreseen such as a scarcity of pure and high-grade scrap and an increased amount of products containing a mixture of materials and with low copper concentrations.

Caisa Samuelsson; Bo Björkman

2014-01-01T23:59:59.000Z

35

COPPER DEFICIENCY PROPHYLAXIS IN GRAZING SHEEP BY COPPER OXIDE INJECTION  

E-Print Network [OSTI]

COPPER DEFICIENCY PROPHYLAXIS IN GRAZING SHEEP BY COPPER OXIDE INJECTION M. LAMAND Claudine LAB R of insoluble and non ionized form of injected copper has been shown in a previous paper (Lamand, 1978 it appeared that copper oxide was preferable to metallic copper, being slightly less caustic. Inflammation

Boyer, Edmond

36

The effects of copper and iron deficiencies in the chick  

E-Print Network [OSTI]

). Copper and iron content of all four diets were determined and the results reported in Table 2, III. Experiment 2. This experiment was carried out to determine the effects of adding cupric oxide to the diet in place of cupric sulfate as the copper... of Copper and Iron Deficiencies on Blood, Mortality and Weights of Four Week Old Chicks Analysis of Copper and Iron Content of Purified Diet" Experiment 3 Effects of Cupric Sulfate, Cupric Oxide, Ferrous Sul- fate and Ferric Oxide on Blood, Mortality...

McGhee, Flin Cameron

2012-06-07T23:59:59.000Z

37

Microwave sintering of pure and doped nanocrystalline alumina compacts  

SciTech Connect (OSTI)

A single-mode cavity microwave furnace, operating in the TE{sub 103} mode at 2.45 GHz is being used to investigate sintering of pure and doped nanocrystalline alumina. The purpose of these experiments is to determine the effect of additives on the sintering process in the nanocrystalline regime. Using the sol-gel method, high purity Al{sub 2}O{sub 3} nanocrystalline powders were synthesized. These powders were calcined at 700 C and then CIP`ed to 414 MPa, producing 0.4 in. diameter, 0.25 in. high cylindrical compacts. The compacts were heated in the microwave furnace to temperatures between 1,100 C to approximately 1,800 C and were then brought back to room temperature using a triangular heating profile of about 30 minutes duration. A two-color IR pyrometer was used to monitor the surface temperature of the workpiece. The additives tested in this work lowered the temperature needed for densification but this effect was offset by increased grain growth. Initial grain growth from <5 nm to {approximately}50 nm was closely correlated with the {gamma} to {alpha}-alumina phase transition.

Bruce, R.W. [SFA, Inc., Largo, MD (United States); Fliflet, A.W.; Lewis, D. III; Rayne, R.J.; Bender, B.A.; Chow, G.M.; Schoen, P.E. [Naval Research Lab., Washington, DC (United States); Kurihara, L.K. [Georgetown Univ., Washington, DC (United States). Dept. of Biochemistry

1996-12-31T23:59:59.000Z

38

Sintering aid for lanthanum chromite refractories  

DOE Patents [OSTI]

An electronically conductive interconnect layer for use in a fuel cell or other electrolytic device is formed with sintering additives to permit densification in a monolithic structure with the electrode materials. Additions including an oxide of boron and a eutectic forming composition of Group 2A metal fluorides with Group 3B metal fluorides and Group 2A metal oxides with Group 6B metal oxides lower the required firing temperature of lanthanum chromite to permit densification to in excess of 94% of theoretical density without degradation of electrode material lamina. The monolithic structure is formed by tape casting thin layers of electrode, interconnect and electrolyte materials and sintering the green lamina together under common densification conditions.

Flandermeyer, Brian K. (Bolingbrook, IL); Poeppel, Roger B. (Glen Ellyn, IL); Dusek, Joseph T. (Downers Grove, IL); Anderson, Harlan U. (Rolla, MO)

1988-01-01T23:59:59.000Z

39

Evaluation of chemical oxygen demand (COD) based on coulometric determination of electrochemical oxygen demand (EOD) using a surface oxidized copper electrode  

Science Journals Connector (OSTI)

Chemical oxygen demand (COD) was estimated by exhaustive electrolysis using a home-made cell with a copper working electrode in 0.1 M NaOH. The net Faradaic charge, corresponding to the number of electrons consumed in electrolyzing (oxidizing) the organic species, was correlated to the COD evaluated by the conventional methods using dichromate or permanganate. The time taken for a single measurement was about 30 min, much less than the 2–4 h required in the conventional methods. Known components of the secondary effluents from several waste water treatment plants in Japan (l-glutamate, glycine, d-glucose, phenol, lignin, tannic acid, hemicellulose, and humic acid) were chosen as standard samples, and each showed a linear response proportional to the concentration of the analytes. For real water samples from rivers and lakes, a linear relationship was observed between this method and both of the conventional methods between about 1 and 10 mg ml?1 COD, the range allowed by the Environmental Quality Standard of Japan. An artificial water sample was prepared and a calibration graph resembling the results of the real samples was obtained. NMR spectra of d-glucose, l-glutamate, glycine, phenol, quinone, hydroquinone, lignin, tannic acid, hemicellulose, and humic acid were obtained before and after electrolysis, and qualitative changes are discussed. Fluorescence measurements were also performed before and after the electrolysis of the polymeric compounds used in this experiment, allowing the oxidation ratios to be estimated.

Kyong-Hoon Lee; Tomoko Ishikawa; S.J McNiven; Yoko Nomura; Atsunori Hiratsuka; Satoshi Sasaki; Yoshiko Arikawa; Isao Karube

1999-01-01T23:59:59.000Z

40

Vacuum properties of sintered SmCo/sub 5/ magnets  

SciTech Connect (OSTI)

There are many desirable applications of powerful, rare-earth permanent magnets made of sintered SmCo/sub 5/ material within vacuum systems. One application is the use of large numbers of SmCo/sub 5/ magnets to provide the undulating magnetic field in a free-electron-laser wiggler structure. Tests were conducted at Los Alamos to determine the suitability of SmCo/sub 5/ magnets in a vacuum environment of approx. 10/sup -6/ torr. The vacuum performances of the wiggler system, with and without the SmCo/sub 5/ magnets (having approx. 11% of the total surface area) installed, were essentially identical. These tests indicate that SmCo/sub 5/ magnets have good vacuum properties and are suitable for use in many vacuum systems.

Warren, R.W.; DePaula, R.F.; Hansborough, L.D.

1981-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Effect of machining on the wear resistance of sintered materials  

Science Journals Connector (OSTI)

The machining and sizing of porous sintered materials produce an improvement in the wear resistance of thin surface layers of parts subjected...

V. A. Danilenko

1970-06-01T23:59:59.000Z

42

Atomic Absorption Method Guide Zn in Copper Alloys  

E-Print Network [OSTI]

Atomic Absorption Method Guide Zn in Copper Alloys Principle The sample is digested in nitric/hydrochloric acid, and zinc is determined by flame atomic absorption spectrometry using an air-acetylene flame · Copper Alloys · Zinc · Flame · Atomic Absorption Method Guide: 40158 #12;©2008 Thermo Fisher Scientific

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

43

Layer-by-Layer Assembly of Sintered CdSexTe1–x Nanocrystal Solar Cells  

Science Journals Connector (OSTI)

solar cell; nanocrystal; CdTe; CdSexTe1?x; layer-by-layer; solution-processed; sintered ... For instance, devices fabricated using cadmium telluride (CdTe) and copper indium gallium selenide (CIGS) based active layers have exhibited laboratory scale power conversion efficiencies up to 17.3%(1) and 20.3%,(2) respectively, at commercial production costs as low as US $0.75/Watt. ... (20) More recently, the graded device concept has been extended to solution-processed organic solar cells, through a series of complementary donor materials(21) and to PbS quantum dot devices, where bandgap grading was accomplished through variation of the QD diameter. ...

Brandon I. MacDonald; Alessandro Martucci; Sergey Rubanov; Scott E. Watkins; Paul Mulvaney; Jacek J. Jasieniak

2012-06-12T23:59:59.000Z

44

Method for sintering fuel cell electrodes using a carrier  

DOE Patents [OSTI]

A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

Donelson, R.; Bryson, E.S.

1995-03-28T23:59:59.000Z

45

Coated metal sintering carriers for fuel cell electrodes  

DOE Patents [OSTI]

A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a water-based carbon paint, the water-based carbon paint comprising water, powdered graphite, an organic binder, a wetting agent, a dispersing agent and a defoaming agent.

Donelson, R.; Bryson, E.S.

1998-11-10T23:59:59.000Z

46

Sintered silver joints via controlled topography of electronic packaging subcomponents  

SciTech Connect (OSTI)

Disclosed are sintered silver bonded electronic package subcomponents and methods for making the same. Embodiments of the sintered silver bonded EPSs include topography modification of one or more metal surfaces of semiconductor devices bonded together by the sintered silver joint. The sintered silver bonded EPSs include a first semiconductor device having a first metal surface, the first metal surface having a modified topography that has been chemically etched, grit blasted, uniaxial ground and/or grid sliced connected to a second semiconductor device which may also include a first metal surface with a modified topography, a silver plating layer on the first metal surface of the first semiconductor device and a silver plating layer on the first metal surface of the second semiconductor device and a sintered silver joint between the silver plating layers of the first and second semiconductor devices which bonds the first semiconductor device to the second semiconductor device.

Wereszczak, Andrew A.

2014-09-02T23:59:59.000Z

47

Effect of physicochemical form on copper availability to aquatic organisms  

SciTech Connect (OSTI)

Copper concentration and speciation were determined in influent and effluent waters collected from eight power stations that used copper alloys in their cooling systems. Quantities of copper associated with particles, colloids, and organic and inorganic ligands differed with the site, season, and mode of operation of the station. Under normal operating conditions, the differences between influent and effluent waters were generally small, and most of the copper was in bound (complexed) species. However, copper was high in concentration and present in labile species during start-up of water circulation through some cooling systems and during changeover from an open- to closed-cycle operation. Copper sensitivity of selected ecologically and economically important aquatic organisms was also evaluted. Our primary emphasis was on acute effects and most of the testing was performed under controlled laboratory conditions. However, sublethal effects of copper on a population of bluegills living in a power station cooling lake containing water of low pH were also assessed. The toxic response to copper differed with the species and life stage of the animal and with the chemical form of copper in the water.

Harrison, F.L.

1983-11-01T23:59:59.000Z

48

Inkjet printed electronics using copper nanoparticle ink  

E-Print Network [OSTI]

electronics using copper nanoparticle ink Jin Sung Kang •of electrode using copper nanoparticle ink is presented.of drop on demand copper nanoparticle inkjet printer system,

Kang, Jin Sung; Kim, Hak Sung; Ryu, Jongeun; Thomas Hahn, H.; Jang, Seonhee; Joung, Jae Woo

2010-01-01T23:59:59.000Z

49

Tribo-Chemical Modeling of Copper CMP  

E-Print Network [OSTI]

TRIBO-CHEMICAL MODELING OF COPPER CMP Shantanu Tripathi 1 ,Technical Area: CMP (Copper) Abstract We are developing antribo-chemical model of copper CMP that considers abrasive

Tripathi, Shantanu; Doyle, Fiona; Dornfeld, David

2006-01-01T23:59:59.000Z

50

Investigations on Cuprous Selenide and Copper Tellurides  

Science Journals Connector (OSTI)

The activity of copper in cuprous selenide and various phases of the system copper?tellurium as a function of the metal?to?nonmetal ratio has been determined with the help of coulometric titrations. At 400°C the homogeneity range of cuprous selenide extends from a Cu/Se ratio of 1.9975±0.001 to a value lower than 1.86. Homogeneous phases of the system Cu–Te have been found between Cu/Te ratios equal to about 2 to 1.92 1.43 to 1.39 and 1.32 to 1.30.

Gert Lorenz; Carl Wagner

1957-01-01T23:59:59.000Z

51

Radiation-effects limits on copper in superconducting magnets  

SciTech Connect (OSTI)

The determination of the response of copper stabilizers to neutron irradiation in fusion-reactor superconducting magnets requires information in four areas: (1) neutron flux and spectrum determination, (2) resistivity changes at zero field, (3) resistivity changes at field, and (4) the cyclic irradiation and annealing. Applications of our current understanding of the limits of copper stabilizers in fusion-reactor designs are explored in two examples. Recommendations for future additions to the data base are discussed.

Guinan, M.W.

1983-05-25T23:59:59.000Z

52

Spark Plasma Sintering of Fuel Cermets for Nuclear Reactor Applications  

SciTech Connect (OSTI)

The feasibility of the fabrication of tungsten based nuclear fuel cermets via Spark Plasma Sintering (SPS) is investigated in this work. CeO2 is used to simulate fuel loadings of UO2 or Mixed-Oxide (MOX) fuels within tungsten-based cermets due to the similar properties of these materials. This study shows that after a short time sintering, greater than 90 % density can be achieved, which is suitable to possess good strength as well as the ability to contain fission products. The mechanical properties and the densities of the samples are also investigated as functions of the applied pressures during the sintering.

Yang Zhong; Robert C. O'Brien; Steven D. Howe; Nathan D. Jerred; Kristopher Schwinn; Laura Sudderth; Joshua Hundley

2011-11-01T23:59:59.000Z

53

December 200 Copper Acquisition by  

E-Print Network [OSTI]

December 200 Copper Acquisition by Methanotrophic Bacteria 7 Term Paper HS2007 Major. One is soluble in the cytoplasm and the other is bound to the membrane. Since the expression of copper containing pMMO depends on copper availability it is supposed that some methanotrophs have developed

Fischlin, Andreas

54

Arabidopsis Adapts to Copper Deficient Conditions via SPL7, a Master Regulator for Copper Homeostasis  

E-Print Network [OSTI]

systemic down-regulation of copper protein expression inresponse to low copper availability in Arabidopsis. J. Biol.A regulator of nutritional copper signaling in Chlamydomonas

Yamasaki, Hiroaki; Shikanai, Toshiharu

2009-01-01T23:59:59.000Z

55

Fundamental Mechanisms of Copper CMP – Passivation Kinetics of Copper in CMP Slurry Constituents  

E-Print Network [OSTI]

Tribochemical Mechanisms of Copper Chemical MechanicalE06-02 Fundamental Mechanisms of Copper CMP – PassivationKinetics of Copper in CMP Slurry Constituents Shantanu

Tripathi, Shantanu; Doyle, F M; Dornfeld, David

2009-01-01T23:59:59.000Z

56

Precursors for formation of copper selenide, indium selenide, copper indium diselenide, and/or copper indium gallium diselenide films  

DOE Patents [OSTI]

Liquid-based precursors for formation of Copper Selenide, Indium Selenide, Copper Indium Diselenide, and/or copper Indium Galium Diselenide include copper-organoselenides, particulate copper selenide suspensions, copper selenide ethylene diamine in liquid solvent, nanoparticulate indium selenide suspensions, and indium selenide ethylene diamine coordination compounds in solvent. These liquid-based precursors can be deposited in liquid form onto substrates and treated by rapid thermal processing to form crystalline copper selenide and indium selenide films.

Curtis, Calvin J; Miedaner, Alexander; Van Hest, Maikel; Ginley, David S

2014-11-04T23:59:59.000Z

57

Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl pendant arm: synthesis,  

E-Print Network [OSTI]

Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl that were used for the preparation of the copper(II) complexes. The structures of three nickel(II) complexes and two copper(II) complexes were determined by X-ray crystallography. Protonation of the pendant arm (p

Nazarenko, Alexander

58

Apparatus for direct measurement of ash fusion and sintering behavior at elevated temperatures and pressures  

Science Journals Connector (OSTI)

Ash fusion sintering and deposition may impose serious operational difficulties in conventional and advanced coal?combustion systems. Conventional ash fusion techniques (e.g. ASTM methods) determine the qualitative behavior of ash samples at atmospheric pressure. Presently there is no known available technique that can measure the behavior of coal ash at elevated temperatures and pressures. In the literature methods based on electrical resistance or shrinkage of coal ash have been reported at atmospheric pressure (elevated temperatures) conditions. A high?pressure microdilatometer (HPMD) has been developed to investigate ash fusion and sintering behavior at elevated pressures and temperatures by the simultaneous measurement of the temperature of initial contraction and electrical resistivity of samples. This novel technique facilitates the measurement of ash properties over a wide range of temperature pressure and gas atmosphere (oxidizing reducing or inert). The operating principle of the HPMD includes measuring the temperature at which there is a significant ‘‘shift’’ in the electrical resistivity (and/or sample volume) that represents ash sintering and fusion. Sintering occurs through the formation of solid?state particle?to?particle ‘‘necks’’ or the appearance of a molten phase which allows a path for electrical conductance. The ability to perform both resistivity and shrinkage measurements simultaneously or independently at e l e v a t e d p r e s s u r e s makes the HPMD truly unique. The HPMD can also be used to investigate the swelling and softening behavior of pyrolyzing coal at elevated pressures and relatively rapid heating rates. The HPMD can provide insights into the sintering/fusion of coal ash or coal swelling at a range of conditions: (a) the influences of various gas atmospheres can be investigated (b) the effects of pressure can be studied (c) different temperature/heating rate schemes can be used (constant rates isothermal holds below or above the sinteringtemperature etc.) and (d) studies can be performed to investigate the influence of increased heating rate at elevated pressures (which were not performed previously) on coal swelling and plasticity.

M. Rashid Khan

1989-01-01T23:59:59.000Z

59

KENNECOTT COPPER CORPORATION  

Office of Legacy Management (LM)

* * ?a, a5 fF#LG 44 it .L &=d ,,*, " ~=iL.oeL~~ KENNECOTT COPPER CORPORATION 101 EAST 42.. STREET $7/$ ,2 : -$ NEW YORU 17, N. Y. AND KOPPERS COMPAN,Y, INC. KOppERS B",'o,,,,G PITTSBURGH 19. PA. Classification Officer, OR0 October ,30, l!% ?!r. S. R. Saptile, Mmagez Oak Ridge Operations Office II. S. Atomic Enerfg Comission P. 0. BOX R. Oak Ridge, Tennessee Attention; Hr. John It. Moore, Director Contract Dltisloa Subjects Addendum (A) to F~oposal for a Feed Materials Processing Plant, dated September 27, WS6 Dear !&. Moore: In the proposal for a feed materials proce.esGg plaut for the production of uranium hexafluoride that uas submitted ~olntly by, Koppers Cm, Inc. and Kennecott Copper Corporation uuder dateof September 27, W%, we described a

60

Method and device for microwave sintering large ceramic articles  

DOE Patents [OSTI]

A microwave sintering system and method are provided for extremely uniform sintering of large and/or irregular shaped ceramic articles at microwave frequencies of at least 28 GHz in the hundreds of kilowatts power range in an untuned cavity. A 28 GHz, 200 kw gyrotron with variable power output is used as the microwave source connected to an untuned microwave cavity formed of an electrically conductive housing through an overmoded waveguide arrangement which acts in conjunction with a mode promoter within the cavity to achieve unexpected field uniformity. The part to be sintered is placed in the cavity and supported on a removable high temperature table in a central location within the cavity. The part is surrounded by a microwave transparent bulk insulating material to reduce thermal heat loss at the part surfaces and maintain more uniform temperature. The cavity may be operated at a high vacuum to aid in preventing arcing. The system allows controlled increased heating rates of greater than 200.degree. C./min to provide rapid heating of a ceramic part to a selected sintering temperature where it is maintained by regulating the microwave power applied to the part. As a result of rapid heating, the extent of non-isothermal processes such as segregation of impurities to the grain boundaries are minimized and exaggerated grain growth is reduced, thereby strengthening the mechanical properties of the ceramic part being sintered.

Kimrey, Jr., Harold D. (Knoxville, TN)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Oxidation Protection of Uranium Nitride Fuel using Liquid Phase Sintering  

SciTech Connect (OSTI)

Two methods are proposed to increase the oxidation resistance of uranium nitride (UN) nuclear fuel. These paths are: (1) Addition of USi{sub x} (e.g. U3Si2) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with various compounds (followed by densification via Spark Plasma Sintering or Liquid Phase Sintering) that will greatly increase oxidation resistance. The advantages (high thermal conductivity, very high melting point, and high density) of nitride fuel have long been recognized. The sodium cooled BR-10 reactor in Russia operated for 18 years on uranium nitride fuel (UN was used as the driver fuel for two core loads). However, the potential advantages (large power up-grade, increased cycle lengths, possible high burn-ups) as a Light Water Reactor (LWR) fuel are offset by uranium nitride's extremely low oxidation resistance (UN powders oxidize in air and UN pellets decompose in hot water). Innovative research is proposed to solve this problem and thereby provide an accident tolerant LWR fuel that would resist water leaks and high temperature steam oxidation/spalling during an accident. It is proposed that we investigate two methods to increase the oxidation resistance of UN: (1) Addition of USi{sub x} (e.g. U{sub 3}Si{sub 2}) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with compounds (followed by densification via Spark Plasma Sintering) that will greatly increase oxidation resistance.

Dr. Paul A. Lessing

2012-03-01T23:59:59.000Z

62

Chronic Copper Poisoning in Sheep.  

E-Print Network [OSTI]

LIBRARY, - A & M COLLEGE, CAiQFUS. E-109-8M-L180 TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR COLLEGE STATION: BRAZOS COUNTY. TEXAS BULLETIN NO. 499 DECEMBER, 1934 DIVISION OF VETERINARY SCIENCE CHRONIC COPPER POISONING... of copper sulphate caused chronic copper poisoning among flocks of range sheep on several West Texas ranches during the past year. The salt licks were placed before the sheep as a means of preventing or controlling stomach worm infestation despite a...

Boughton, I. B. (Ivan Bertrand); Hardy, W. T. (William Tyree)

1934-01-01T23:59:59.000Z

63

High efficiency particulate removal with sintered metal filters  

SciTech Connect (OSTI)

Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for high efficiency particulate air (HEPA) filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to ensure trouble-free operation. Subsequence pilot scale testing was performed with flyash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90/sup 0/C and 24 vol % water vapor in the gas stream.

Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

1981-01-01T23:59:59.000Z

64

Copper stress response in marine Synechococcus  

E-Print Network [OSTI]

Maximum yield (cells/ml) of copper-treated and no-Cu control2.6. Growth assays after copper treatments in both wild typefold changes over control no-copper treatment. …………………………75

Stuart, Rhona Kayra

2012-01-01T23:59:59.000Z

65

Fabrication and characterization of porous NiTi Shape Memory Alloy by elevated pressure sintering  

E-Print Network [OSTI]

have not been adequately developed. Currently, three methods are commonly used for producing porous NiTi SMAs from elemental powders. These methods include conventional sintering, Self-propagating High-temperature Synthesis (SHS), and sintering...

Vandygriff, Eric Layton

2012-06-07T23:59:59.000Z

66

Roughening of the interface between grains and liquid matrix in sintered TaC-20Ni  

Science Journals Connector (OSTI)

The grains in TaC-20 wt pct Ni alloy prepared by liquidphase sintering at 1480°C have orthorhombic shapes with flat {100} faces and sharp edges. These grains show abnormal growth. When sintered at 2020°C, the gra...

Young Kyu Cho; Duk Yong Yoon; Jung Hoon Choi…

2005-09-01T23:59:59.000Z

67

Spark Plasma Sintering of W-UO2 Cermets  

SciTech Connect (OSTI)

About 50 vol.% 3 um depleted uranium dioxide (UO2) powder was encapsulated within a tungsten super alloy matrix produced from sub-micron tungsten powders using the Spark Plasma Sintering (SPS) process. An additive of 25 atom-percent (at.%) rhenium was included within the tungsten matrix to improve the ductility and fracture toughness of the ceramic–metallic (cermet) matrix. Cermet fabrication to 97.9% of the theoretical cermet density was achieved by sintering at 1500 degrees C with 40 MPa of applied pressure for 20 min. The results presented are from the first known trials of W–UO2 and nuclear cermet production via SPS.

R. C. O'Brien; N. D. Jerred

2013-02-01T23:59:59.000Z

68

Method and apparatus for radio frequency ceramic sintering  

DOE Patents [OSTI]

Radio frequency energy is used to sinter ceramic materials. A coaxial waveguide resonator produces a TEM mode wave which generates a high field capacitive region in which a sample of the ceramic material is located. Frequency of the power source is kept in the range of radio frequency, and preferably between 60-80 MHz. An alternative embodiment provides a tunable radio frequency circuit which includes a series input capacitor and a parallel capacitor, with the sintered ceramic connected by an inductive lead. This arrangement permits matching of impedance over a wide range of dielectric constants, ceramic volumes, and loss tangents. 6 figures.

Hoffman, D.J.; Kimrey, H.D. Jr.

1993-11-30T23:59:59.000Z

69

Method and apparatus for radio frequency ceramic sintering  

DOE Patents [OSTI]

Radio frequency energy is used to sinter ceramic materials. A coaxial waveguide resonator produces a TEM mode wave which generates a high field capacitive region in which a sample of the ceramic material is located. Frequency of the power source is kept in the range of radio frequency, and preferably between 60-80 MHz. An alternative embodiment provides a tunable radio frequency circuit which includes a series input capacitor and a parallel capacitor, with the sintered ceramic connected by an inductive lead. This arrangement permits matching of impedance over a wide range of dielectric constants, ceramic volumes, and loss tangents.

Hoffman, Daniel J. (Oak Ridge, TN); Kimrey, Jr., Harold D. (Knoxville, TN)

1993-01-01T23:59:59.000Z

70

Removal of copper from ferrous scrap  

DOE Patents [OSTI]

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Blander, M.; Sinha, S.N.

1987-07-30T23:59:59.000Z

71

Removal of copper from ferrous scrap  

DOE Patents [OSTI]

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Blander, Milton (12833 S. 82nd Ct., Palos Park, IL 60464); Sinha, Shome N. (5748 Drexel, 2A, Chicago, IL 60637)

1990-01-01T23:59:59.000Z

72

Stress Intensity of Delamination in a Sintered-Silver Interconnection: Preprint  

SciTech Connect (OSTI)

In automotive power electronics packages, conventional thermal interface materials such as greases, gels, and phase-change materials pose bottlenecks to heat removal and are also associated with reliability concerns. The industry trend is toward high thermal performance bonded interfaces for large-area attachments. However, because of coefficient of thermal expansion mismatches between materials/layers and resultant thermomechanical stresses, adhesive and cohesive fractures could occur, posing a reliability problem. These defects manifest themselves in increased thermal resistance. This research aims to investigate and improve the thermal performance and reliability of sintered-silver for power electronics packaging applications. This has been experimentally accomplished by the synthesis of large-area bonded interfaces between metalized substrates and copper base plates that have subsequently been subjected to thermal cycles. A finite element model of crack initiation and propagation in these bonded interfaces will allow for the interpretation of degradation rates by a crack-velocity (V)-stress intensity factor (K) analysis. A description of the experiment and the modeling approach are discussed.

DeVoto, D. J.; Paret, P. P.; Wereszczak, A. A.

2014-08-01T23:59:59.000Z

73

It's Elemental - The Element Copper  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nickel Nickel Previous Element (Nickel) The Periodic Table of Elements Next Element (Zinc) Zinc The Element Copper [Click for Isotope Data] 29 Cu Copper 63.546 Atomic Number: 29 Atomic Weight: 63.546 Melting Point: 1357.77 K (1084.62°C or 1984.32°F) Boiling Point: 2835 K (2562°C or 4644°F) Density: 8.933 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 11 Group Name: none What's in a name? From the Latin word cuprum, which means "from the island of Cyprus." Say what? Copper is pronounced as KOP-er. History and Uses: Archaeological evidence suggests that people have been using copper for at least 11,000 years. Relatively easy to mine and refine, people discovered methods for extracting copper from its ores at least 7,000 years ago. The

74

Hydrogen decrepitation of sintered NdFeB magnets  

SciTech Connect (OSTI)

The kinetics of the hydrogen absorption and desorption behavior of a NdFeB sintered magnet is studied. Hydrogenation at temperatures above 200 C is used to crumble the Nd-enriched phase. The grains of Nd{sub 2}Fe{sub 14}B phase remain undamaged. Hydrogen desorption occurs in several stages and is complete at approximately 400 C.

Stiller, C.; Roth, S.; Binner, A. [Inst. fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)] [Inst. fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)

1994-03-01T23:59:59.000Z

75

Method of making an air electrode material having controlled sinterability  

DOE Patents [OSTI]

A tubular, porous ceramic electrode structure is made from the sintered admixture of doped lanthanum manganite and an additive containing cerium where a solid electrolyte, substantially surrounds the air electrode, and a porous outer fuel electrode substantially surrounds the electrolyte, to form a fuel cell. 2 figs.

Vasilow, T.R.; Kuo, L.J.H.; Ruka, R.J.

1994-08-30T23:59:59.000Z

76

Promotion of atherogenesis by copper or iron-Which is more likely?  

SciTech Connect (OSTI)

Iron levels increase in atherosclerotic lesions in cholesterol fed-rabbits and play a role in atherosclerosis. We investigated whether copper also rises. Male New Zealand White rabbits were fed high-cholesterol diets for 8 weeks. After sacrifice, lesion sizes were determined, and elemental analyses of the lesion and unaffected artery wall performed using nuclear microscopy. Unlike iron, lesion copper is decreased by about half compared with the unaffected artery wall, and much less copper than iron is present. Our data suggest that iron may be more likely to play a role in the promotion of atherosclerosis than copper.

Rajendran, Reshmi [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore); Department of Biochemistry, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore); Ren, Minqin [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore); Ning, Pan [Department of Biochemistry, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore); Tan Kwong Huat, Benny [Department of Pharmacology, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore); Halliwell, Barry [Department of Biochemistry, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore)]. E-mail: bchbh@nus.edu.sg; Watt, Frank [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, MD7, 8 Medical Drive, Singapore 117597 (Singapore)

2007-02-02T23:59:59.000Z

77

Electric Discharge Sintering and Joining of Tungsten Carbide--Cobalt Composite with High-Speed Steel Substrate  

SciTech Connect (OSTI)

Simultaneous electro discharge sintering of high strength structure of tungsten carbide-cobalt composite and connection it with high-speed steel substrate is investigated and suitable operating parameters are defined. Tungsten carbide-cobalt and high-speed steel joining was produced by the method of high voltage electrical discharge together with application of mechanical pressure to powder compact. It was found that the density and hardness of composite material reach its maximum values at certain magnitudes of applied pressure and high voltage electrical discharge parameters. We show that there is an upper level for the discharge voltage beyond which the powder of composite material disintegrates like an exploding wire. Due to our results it is possible to determine optimal parameters for simultaneous electro discharge sintering of WC-Co and bonding it with high-speed steel substrate.

Grigoryev, Evgeny G. [General Physics Department, Moscow Engineering Physics Institute, Kashirskoe sh. 31, Moscow, 115409 (Russian Federation)

2011-01-17T23:59:59.000Z

78

Methanobactin: a copper binding compound having antibiotic and antioxidant activity isolated from methanotrophic bacteria  

DOE Patents [OSTI]

A means and method for treating bacterial infection, providing antioxidant activity, and chelating copper using a copper binding compound produced by methanotrophic bacteria is described. The compound, known as methanobactin, is the first of a new class of antibiotics having gram-positive activity. Methanobactin has been sequenced, and its structural formula determined.

DiSpirito, Alan A. (Ames, IA); Zahn, James A. (Harbor Beach, MI); Graham, David W. (Lawrence, KS); Kim, Hyung J. (St. Paul, MN); Alterman, Michail (Lawrence, KS); Larive, Cynthia (Lawrence, KS)

2007-04-03T23:59:59.000Z

79

Selecting copper and copper alloys; Part 2: Cast products  

SciTech Connect (OSTI)

This article provides an introduction to the properties, characteristics, and applications of cast coppers and copper alloys. An overview of alloy families is presented since it is impractical to describe all 130 standard grades in detail. However, additional technical information is readily available from the Copper Development Assn. Inc. (CDA) and the resources listed in the references and bibliography at the end of the article. Copper casting alloys are primarily selected for either their corrosion resistance, or their combination of corrosion resistance and mechanical properties. The materials also feature good castability, high machinability, and, compared with other corrosion-resistant alloys, reasonable cost. Additional benefits include biofouling resistance--important in marine applications--and a spectrum of attractive colors. Many of the alloys also have favorable tribological properties, which explains their widespread use for sleeve bearings, wear plates, gears, and other wear-prone components.

Peters, D.T. (Copper Development Association Inc., New York, NY (United States)); Kundig, K.J.A. (Kundig (Konrad J.A.), Randolph, NJ (United States))

1994-06-01T23:59:59.000Z

80

Effect of TiO{sub 2} additives to the sintering of Y{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The effect of sintering additive on the microstructure development of yttrium oxide was investigated. Different combinations of yttrium oxide with TiO{sub 2} were used as x-ray diffraction, differential thermal analysis (DTA) were sintering additive. The investigated and microstructure of resulting compacts were characterized by, using scanning electron microscopy, porosity and sintering density for all compacting samples sintered at different sintering temperature under static air.

Issa, Tarik Talib; Majeed, Kawakib Jassim; Ibrahim, Harith J. [University of Baghdad, College of Science, Physics Department, Jadiriya, Baghdad (Iraq)

2013-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Tissue sorbitol concentration can be altered by changing the type of dietary carbohydrate or copper status  

SciTech Connect (OSTI)

This study was designed to determine whether rehabilitation of tissue sorbitol concentration occurs when rats consuming a high-fructose, low-copper diet are changed to diets containing starch or copper. Weanling male rats were provided with a diet which contained 62.7% fructose and 0.6 or 6.0 {mu}g Cu/g (F-Cu) for 4 weeks and then changed to either a fructose diet which contained 6.0 {mu}g Cu/g or a starch diet which contained either 0.6 or 6.0 {mu}g Cu/g for 2 weeks. Hepatic copper concentration of rats eating copper-deficient diets was about 30% of copper adequate rats regardless of the type of dietary carbohydrate. Pancreatic fructose, glucose and sorbitol concentrations were significantly lowered in rats changed to a starch diet. Kidney fructose and sorbitol concentrations were significantly lowered in rats changed to a starch diet. For all dietary groups, pancreatic and kidney sorbitol concentrations returned to normal after removal of rats from the F-Cu diet. In general, changing rats from a high-fructose, low-copper diet to a fructose diet with copper or a starch diet with or without copper improved the copper deficiency symptoms which changed in concert with tissue sorbitol levels.

Beal, T.; Lewis, C.G.; Fields, M. (Univ. of Maryland, College Park (USA))

1989-02-09T23:59:59.000Z

82

Integrated Tribo-Chemical Modeling of Copper CMP  

E-Print Network [OSTI]

Tribochemical Mechanisms of Copper Chemical MechanicalEli, D. Starosvetsky, "Review on copper chemical–mechanicalY. Li, "Investigation of Copper Removal Mechanisms d uring

Shantanu Tripathi; Choi, Seungchoun; Doyle, Fiona M; Dornfeld, David

2009-01-01T23:59:59.000Z

83

Copper Toxicity in the San Francisco Bay-Delta  

E-Print Network [OSTI]

reducing the toxicity of copper that continues to leach fromothers to characterize copper bioaccumulation from distinctreview of total dissolved copper and its chemical speciation

Buck, Kristen N.

2012-01-01T23:59:59.000Z

84

Method of making bonded or sintered permanent magnets  

DOE Patents [OSTI]

An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density. 14 figs.

McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

1995-11-28T23:59:59.000Z

85

Method of making bonded or sintered permanent magnets  

DOE Patents [OSTI]

An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

1993-08-31T23:59:59.000Z

86

Method of making sintered ductile intermetallic-bonded ceramic composites  

DOE Patents [OSTI]

A method of making an intermetallic-bonded ceramic composite involves combining a particulate brittle intermetallic precursor with a particulate reactant metal and a particulate ceramic to form a mixture and heating the mixture in a non-oxidizing atmosphere at a sufficient temperature and for a sufficient time to react the brittle intermetallic precursor and the reactant metal to form a ductile intermetallic and sinter the mixture to form a ductile intermetallic-bonded ceramic composite. 2 figs.

Plucknett, K.; Tiegs, T.N.; Becher, P.F.

1999-05-18T23:59:59.000Z

87

Chromated Copper Arsenate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Peter S. Nico1, Scott E. Fendorf2, Yvette W. Lowney3, Stewart E. Holm4, and Michael V. Ruby3 Peter S. Nico1, Scott E. Fendorf2, Yvette W. Lowney3, Stewart E. Holm4, and Michael V. Ruby3 1Chemistry Department, Cal State University, Stanislaus, Turlock, CA 2Geological and Environmental Sciences, Stanford University, Stanford, CA 3Exponent, Boulder, CO 4Georgia-Pacific Corporation, Atlanta, Georgia wood playground In recent years, regulatory and public attention has become focused on the potential risks associated with exposure to chromated copper arsenate (CCA)-treated wood - the most widely used wood treatment product in the United States. CCA has been used to treat lumber for over 60 years (1), mainly because of the extended lifetime of CCA-treated wood as compared to untreated wood (2-5) and the higher costs of non-wood alternatives. Since the late 1980s, U.S. production of CCA-treated wood has averaged

88

Effect of sintering on thermally sprayed carbon nanotube reinforced aluminum nanocomposite  

Science Journals Connector (OSTI)

Reconsolidation of thermally spray formed (plasma and high velocity oxyfuel spraying) hypereutectic Al–Si nanocomposites with multiwalled carbon nanotube (MWCNT) reinforcement was carried out by inert atmosphere sintering for prolonged time periods. The sintering treatment resulted in the removal of porosity and residual stress, and increase in size and volume fraction of primary Si particles in the Al–Si matrix. The morphology of multiwalled carbon nanotubes in sintered nanocomposites remained unchanged after sintering. The interfacial ultrathin product layer of silicon carbide between MWCNT reinforcement and Al–Si matrix was unaltered. Microhardness and elastic modulus of the sintered nanocomposites were influenced by combined effect of multiple factors, i.e. reduction in porosity, residual stress removal and MWCNT distribution. Overall improvement of microhardness and elastic modulus of the sintered nanocomposites was observed. The experimentally measured elastic modulus values were compared with theoretically estimated values using micromechanics models.

T. Laha; A. Agarwal

2008-01-01T23:59:59.000Z

89

Effect of environment atmosphere on the sintering of Thai lignite fly ashes  

SciTech Connect (OSTI)

Sintering of ash particles, related to deposit formation in a pulverized coal-fired boiler, was investigated for two lignite fly ashes obtained from Mae Moh and Bangpudum coal seams. The tests involved measuring the compressive strength of cold sintered pellets at varying sintering temperature, both under oxidizing (air) and non-oxidizing atmospheres (CO{sub 2}). Under ambient air condition, Mae Moh fly ash which contained higher amount of glassy phase gave significantly higher sinter strength than Bangpudum fly ash. The role of glassy phase was confirmed by the lowering of sinter strength when HF-extracted fly ash was tested. Sintering under CO{sub 2} environment resulted in larger strength development than sintering in air. Under this non-oxidizing condition, the pellet color turned black, indicating that most of the iron was in the reduced state and could form additional low melting-point glassy phase, hence facilitated sintering rate. In addition, blending of the two ashes yielded intermediate maximum strength, under both air and CO{sub 2} environments. This observation substantiates the important role of glassy phase in the sintering process and indicates the possibility of lowering deposit strength by judicious mixing of different raw coal feeds.

Tangsathitkulchai, C.; Tangsathitkulchai, M. [Suranaree Univ. of Technology, Nakhon Ratchasima (Thailand)

1996-12-31T23:59:59.000Z

90

Design and Application of the Dry-FGD Process in Sanming Steel No. 2 Sintering Plant  

Science Journals Connector (OSTI)

In this paper, it summarizes the characteristics of sinter flue gas, and study the application of dry-type-FGD (flue gas desulphurization) process for...

Yu Zhijie; Li Qiyong; Xu Haijun; Lin Chunyuan

2009-01-01T23:59:59.000Z

91

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

DOE Patents [OSTI]

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Khan, M. Rashid (Morgantown, WV)

1990-01-01T23:59:59.000Z

92

Ris0-R-991(EN) Fatigue Performance of Copper and  

E-Print Network [OSTI]

Ris0-R-991(EN) inn DK9700117 Fatigue Performance of Copper and Copper alloys before and after ARE MISSING IN THE ORIGINAL DOCUMENT #12;Fatigue Performance of Copper and Copper alloys before and after performance of pure copper of the oxygen free, high conductivity (OFHC) grade and two copper alloys (Cu

93

Exploration Into Copper Catalyzed and Copper-less Click Reactions with Re(CO)3 Complexes  

E-Print Network [OSTI]

Exploration Into Copper Catalyzed and Copper-less Click Reactions with Re(CO)3 Complexes Nicholas that combines a alkyne and an oxime to generate a isoxazole cycloaddtion product. Compared to the copper and then proceeding with the typical copper(I) catalyzed "click" reaction procedure, while the other approach involves

Collins, Gary S.

94

Copper-mediated LDL oxidation by homocysteine and related compounds depends largely on copper ligation  

E-Print Network [OSTI]

Copper-mediated LDL oxidation by homocysteine and related compounds depends largely on copper of copper-mediated LDL oxidation (initiation, conjugated diene formation and aldehyde formation), whereas at high concentration, it acts as an antioxidant. The affinity for copper of homocysteine and related

Williamson, Mike P.

95

Copper doped polycrystalline silicon solar cell  

DOE Patents [OSTI]

Photovoltaic cells having improved performance are fabricated from polycrystalline silicon containing copper segregated at the grain boundaries.

Lovelace, Alan M. Administrator of the National Aeronautics and Space (La Canada, CA); Koliwad, Krishna M. (La Canada, CA); Daud, Taher (La Crescenta, CA)

1981-01-01T23:59:59.000Z

96

Osteogenic and Chondrogenic Differentiation of rBMSCs on Microsphere-Based Scaffolds Sintered Using Subcritical CO2  

E-Print Network [OSTI]

, sintered using subcritical carbon dioxide for osteogenic and chondrogenic tissue regeneration. As a next step in the fabrication of three-dimensional tissue engineered scaffolds, this thesis primarily focused on subcritical carbon dioxide sintering...

Bhamidipati, Manjari

2011-12-31T23:59:59.000Z

97

A sintering model for thermal barrier coatings R.G. Hutchinson a  

E-Print Network [OSTI]

Turbine blades in the high-pressure, high-temperature stages of gas turbines are manufactured from creep model is developed for the progressive sintering of ceramic columns in a thermal barrier coating made. Explicit calculations are reported for the evolution of sintering within an array of mud-cracked columns

Fleck, Norman A.

98

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect (OSTI)

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

99

Development of an energy efficient curtain flame ignition system for sintering of iron ore fines  

Science Journals Connector (OSTI)

Research and Development Centre for Iron and Steel (RDCIS) of Steel Authority of India Limited (SAIL) has developed a 'curtain flame' ignition system for sinter mix ignition. Conventionally, either horizontal fired burners or top fired or a combination of both are used for ignition of sinter mix. These burners big in size but few in number are mounted on a rectangular box type furnace. This is associated with non-uniform heating of sinter mix. In the new system, small capacity burners are installed on the roof across the sinter bed in a single row. Here, the top layer of the sinter bed gets heated by the direct impingement of the flame. This has resulted in reduction in specific fuel gas consumption by more than 30% and savings in refractory consumption. Implementation of the system led to reduction in green house gas (GHG) emission also.

V.T. Selvan; T.S. Reddy; A. Das

2012-01-01T23:59:59.000Z

100

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

1999-11-23T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Identification of copper-copper and copper-hydrogen complexes in silicon  

SciTech Connect (OSTI)

The centers formed in silicon as a result of interaction between the substitutional copper impurity (Cu{sub s}) and interstitial copper (Cu{sub i}) or hydrogen (H) atoms, which are mobile at room temperature, are investigated in this study using the deep-level transient spectroscopy (DLTS) technique. It is shown that a well-known photoluminescence center, which includes four copper atoms, is formed from Cu{sub s} via the subsequent addition of Cu{sub i}. Both intermediate complexes (Cu{sub s}-Cu{sub i} and Cu{sub s}-2Cu{sub i}) are identified by their deep levels in the lower half of the band gap. It is found that Cu{sub s} atoms form complexes with one, two, and three hydrogen atoms, with Cu{sub s}-H and Cu{sub s}-2H being electrically active. It is noted that the addition of either hydrogen or copper has a similar effect on the deep-level structure of Cu{sub s}.

Yarykin, N. A., E-mail: NAY@iptm.ru [Russian Academy of Sciences, Institute of Microelectronics Technology (Russian Federation); Weber, J. [Technische Universitaet Dresden (Germany)

2013-02-15T23:59:59.000Z

102

Morphology and utilization of smooth hydrogen-evolving Raney nickel cathode coatings and porous sintered-nickel cathodes  

SciTech Connect (OSTI)

The utilization of the inner surfaces of hydrogen-evolving, porous, sintered-nickel electrodes and Raney nickel-coated electrodes was investigated and compared by steady-state voltammetry, impedance spectroscopy, coulometric determination of catalyst surface, and scanning electron microscopy. Porous, sintered-nickel electrodes are shown to be utilized only to approximately 10%. On the time average, roughly 90% of the inner surface of these electrodes is gas-blanketed. Nanoporous, smooth Raney nickel coatings are divided by micron-scale cracks. The essential part of the catalytically active electrode surface of Raney nickel coatings is represented by the walls of nanopores whose diameter is around 2 nm. Tafel slopes of less than {minus}120 mV/dec, namely, {minus}50 to {minus}70 mV/dec, are measured at 50 {micro}m thick smooth Raney nickel coatings. These low Tafel slopes are explained by an increasing degree of nanopore utilization with increasing current density rising from less than 0.6 to {approximately}10% if the overpotential rises from {minus}30 to {minus}120 mV. The effect can be modeled for nanopores and is at variance with known micropore behavior under concentration polarization known for increased Tafel slopes. From pore modeling it follows also that in another type of Raney nickel coatings, the so-called composite coating composed of micrometer particles of Raney nickel, different from smooth Raney nickel coatings, the utilization of that part of particles which is contacted by the electrolyte is almost 100%. Since, as in sintered electrodes, only 10% of the particle surface are expected not to be gas-blanketed, the total utilization of composite coated nanoporous catalysts amounts to {approximately} 10%, independent of overpotential and current density.

Rausch, S.; Wendt, H. [TH Darmstadt (Germany). Inst. fuer Chemische Technologie

1996-09-01T23:59:59.000Z

103

Phase evolution in carbide dispersion strengthened nanostructured copper composite by high energy ball milling  

SciTech Connect (OSTI)

In this study, high-energy ball milling was applied to synthesis in situ nanostructured copper based composite reinforced with metal carbides. Cu, M (M=W or Ti) and graphite powder mixture were mechanically alloyed for various milling time in a planetary ball mill with composition of Cu-20vol%WC and Cu-20vol%TiC. Then the as-milled powder were compacted at 200 to 400 MPa and sintered in a vacuum furnace at 900 Degree-Sign C. The results of X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy analysis showed that formation of tungsten carbides (W{sub 2}C and WC phases) was observed after sintering of Cu-W-C mixture while TiC precipitated in as-milled powder of Cu-Ti-C composite after 5 h and become amorphous with longer milling. Mechanism of MA explained the cold welding and fracturing event during milling. Cu-W-C system shows fracturing event is more dominant at early stage of milling and W particle still existed after milling up to 60 h. While in Cu-Ti-C system, cold welding is more dominant and all Ti particles dissolved into Cu matrix.

Hussain, Zuhailawati; Nur Hawadah, M. S. [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)

2012-09-06T23:59:59.000Z

104

Studying the sintering behavior of BeO{sub x}-SiC{sub 1-x} Composite ceramic Material  

SciTech Connect (OSTI)

The sintering behavior for BeO-SiC compacts composite ceramic at different sintering temperatures in air were conducted, resulting data indicated that the percentage of SiC (Wt% 5) sintered at 800 C deg. lead to higher sintering density of (1.80 gm/cm3). The x-ray diffraction pattern analysis indicated nothing change concerning the crystal structure. Microstructure development has been studied as a function SiC content. Silicon carbide found to be suppressed the sinter ability of the matrix BeO powder.

Issa, Tarik Talib [Department of physics, College of Science, University of Baghdad, Jadiriya, Baghdad (Iraq)

2011-12-26T23:59:59.000Z

105

Sintering behavior of two roughened crystals just after contact  

E-Print Network [OSTI]

We consider two spherical, roughened crystals with approximately isotropic surface free energy which are brought into contact and begin to sinter. We argue that the geometry immediately post-contact is two dimensional and Cartesian and can be approximated by the evolution of a slot-shaped cavity. On this basis, we construct travelling wave solutions for the crystal shape in the limits of bulk diffusion limited and surface diffusion limited kinetics. These solutions are then used to calculate novel scalings for the neck size as a function of time $t$ after contact: We predict that neck size is proportional to $t^{1/4}$ for the bulk diffusion limited case and (following a single pinch-off event) approximately proportional to $t^{1/3}$ for the surface diffusion limited case.

R. S. Farr; M. J. Izzard

2010-01-22T23:59:59.000Z

106

Method for forming porous sintered bodies with controlled pore structure  

DOE Patents [OSTI]

The present invention is based, in part, on a method for combining a mixture of hydroxide and hydride functional siloxanes to form a polysiloxane polymer foam, that leaves no residue (zero char yield) upon thermal decomposition, with ceramic and/or metal powders and appropriate catalysts to produce porous foam structures having compositions, densities, porosities and structures not previously attainable. The siloxanes are mixed with the ceramic and/or metal powder, wherein the powder has a particle size of about 400 .mu.m or less, a catalyst is added causing the siloxanes to foam and crosslink, thereby forming a polysiloxane polymer foam having the metal or ceramic powder dispersed therein. The polymer foam is heated to thermally decompose the polymer foam and sinter the powder particles together. Because the system is completely nonaqueous, this method further provides for incorporating reactive metals such as magnesium and aluminum, which can be further processed, into the foam structure.

Whinnery, LeRoy Louis (4929 Julie St., Livermore, Alameda County, CA 94550); Nichols, Monte Carl (4070 Guilford Ave., Livermore, Alameda County, CA 94550)

2000-01-01T23:59:59.000Z

107

Sintering and crystallization of akermanite-based glass–ceramics  

Science Journals Connector (OSTI)

Akermanite-based glass–ceramics were successfully produced from the SiO2–Al2O3–B2O3–MgO–CaO–Na2O–F system via sintering and crystallization of glass-powder compacts at low temperatures between 750 and 800 °C. The experimental results indicated that the amount of Al2O3 in the parent glass composition is seemingly a key factor with regard to the potential of this system to crystallize into a mono-mineral akermanite glass–ceramic. The aesthetics and the mechanical, the chemical and the thermal properties of the produced glass–ceramics in conjunction with the evaluation of the economic processing route proposed qualify these glass–ceramics for further investigation as potential materials suitable for applications in restorative dentistry.

J.M.G. Ventura; D.U. Tulyaganov; S. Agathopoulos; J.M.F. Ferreira

2006-01-01T23:59:59.000Z

108

The effects of composition, temperature and sample size on the sintering of chem-prep high field varistors.  

SciTech Connect (OSTI)

The sintering behavior of Sandia chem-prep high field varistor materials was studied using techniques including in situ shrinkage measurements, optical and scanning electron microscopy and x-ray diffraction. A thorough literature review of phase behavior, sintering and microstructure in Bi{sub 2}O{sub 3}-ZnO varistor systems is included. The effects of Bi{sub 2}O{sub 3} content (from 0.25 to 0.56 mol%) and of sodium doping level (0 to 600 ppm) on the isothermal densification kinetics was determined between 650 and 825 C. At {ge} 750 C samples with {ge}0.41 mol% Bi{sub 2}O{sub 3} have very similar densification kinetics, whereas samples with {le}0.33 mol% begin to densify only after a period of hours at low temperatures. The effect of the sodium content was greatest at {approx}700 C for standard 0.56 mol% Bi{sub 2}O{sub 3} and was greater in samples with 0.30 mol% Bi{sub 2}O{sub 3} than for those with 0.56 mol%. Sintering experiments on samples of differing size and shape found that densification decreases and mass loss increases with increasing surface area to volume ratio. However, these two effects have different causes: the enhancement in densification as samples increase in size appears to be caused by a low oxygen internal atmosphere that develops whereas the mass loss is due to the evaporation of bismuth oxide. In situ XRD experiments showed that the bismuth is initially present as an oxycarbonate that transforms to metastable {beta}-Bi{sub 2}O{sub 3} by 400 C. At {approx}650 C, coincident with the onset of densification, the cubic binary phase, Bi{sub 38}ZnO{sub 58} forms and remains stable to >800 C, indicating that a eutectic liquid does not form during normal varistor sintering ({approx}730 C). Finally, the formation and morphology of bismuth oxide phase regions that form on the varistors surfaces during slow cooling were studied.

Garino, Terry J.

2007-09-01T23:59:59.000Z

109

Small-angle neutron scattering study of high-pressure sintered detonation nanodiamonds  

SciTech Connect (OSTI)

The structure of detonation diamonds sintered at a high pressure (7 GPa) and temperatures of 1200-1700 Degree-Sign C has been investigated by small-angle neutron scattering. It is shown that sintering leads to an increase in the particle size from 6 to 30 nm and established that this increase is due to the chainlike oriented attachment of particles. This study supplements the oriented-attachment model, which was suggested based on the X-ray diffraction spectra of detonation nanodiamonds (DNDs) sintered under the same conditions.

Kidalov, S. V.; Shakhov, F. M., E-mail: fedor.shakhov@mail.ioffe.ru [Ioffe Physical-Technical Institute of the Russian Academy of Sciences (Russian Federation); Lebedev, V. T.; Orlova, D. N.; Grushko, Yu. S. [Russian Academy of Sciences, Konstantinov St. Petersburg Nuclear Physics Institute (Russian Federation)

2011-12-15T23:59:59.000Z

110

Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell  

DOE Patents [OSTI]

A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Vora, Shailesh D. (Monroeville, PA)

2001-01-01T23:59:59.000Z

111

The Fission Yeast Copper-sensing Transcription Factor Cuf1 Regulates the Copper Transporter Gene Expression through an  

E-Print Network [OSTI]

The Fission Yeast Copper-sensing Transcription Factor Cuf1 Regulates the Copper Transporter Gene of copper transport is essential for copper homeostasis and growth in yeast. Analysis of regulatory regions in the promoter of the ctr4 copper transporter gene in fission yeast Schizosaccharomyces pombe re- veals

Labbé, Simon

112

MicroRNA-mediated Systemic Down-regulation of Copper Protein Expression in Response to Low Copper  

E-Print Network [OSTI]

MicroRNA-mediated Systemic Down-regulation of Copper Protein Expression in Response to Low Copper 44519, Egypt In plants, copper is an essential micronutrient required for photosynthesis. Two of the most abundant copper proteins, plastocyanin and copper/zinc superoxide dismutase, are found

113

Reciprocal influences of temperature and copper on survival of fathead minnows, Pimephales promelas  

SciTech Connect (OSTI)

Contemporary ecological concerns of accelerated global warming, increase in toxic chemicals and loss of biodiversity make relevant studies of tolerance of various organisms to abiotic variables. In this study, the reciprocal effects of temperature and copper on survival of fathead minnows, Pimephales promelas, were determined. Temperature tolerance of fishes is limited by a cornucopia of biotic and abiotic factors, including various toxicants. Not only do chemicals affect temperature tolerance of fishes, temperature influences the sensitivity of fish to toxic chemicals; however, the relationship between temperature and lethality is complex, difficult to predict, and has not been the focus of many studies. Copper, a necessary trace element in animal metabolism and ubiquitous in aquatic environments, was selected as our test toxicant. Hodson et al. (1979) reported copper concentrations of one to 29 {mu}g/L in unpolluted surface waters in the United States. Copper sulfate (CuSO{sub 4}), is an algicide, bactericide and herbicide for ponds, lakes and fish hatcheries. Also, copper is recommended as a fungicide for a variety of ornamental plants and crops, and in various chemical forms enters the environment through mining, smelting, and refining activities. Copper is toxic in parts per billion concentrations ({mu}g/L) and is an EPA priority pollutant. In this research two null hypotheses were tested: (1) temperature has no effect on the lethality of copper sulfate, and (2) sublethal concentrations of copper do not affect the upper temperature tolerance of fathead minnows. It was found that acclimation temperature significantly affects the 96-hr median lethal concentration. Exposure to copper adversely affects the ability of minnows to withstand high temperatures. 14 refs., 3 figs.

Richards, V.L.; Beitinger, T.L. [Univ. of North Texas, Denton, TX (United States)

1995-08-01T23:59:59.000Z

114

Copper(I) and copper(II) complexes of an ethylene cross-bridged cyclam  

E-Print Network [OSTI]

Copper(I) and copper(II) complexes of an ethylene cross-bridged cyclam Timothy J. Hubin,a Nathaniel and crystal structures of (4,11-dibenzyl- 1,4,8,11-tetraazabicyclo[6.6.2]hexadecane- 4 N)copper(I) hexa)- copper(II) bis(hexaÂŻuorophosphate), [Cu(C2H3N)(C26H38- N4)](PF6)2, are described. The CuI ion

Hubin, Tim

115

Precursors of copper/zinc oxide catalysts  

Science Journals Connector (OSTI)

Recent results on hydroxycarbonate precursors of copper/zinc oxide catalysts for methanol synthesis are reinterpreted, taking into account earlier work on these systems.

M.S. Spencer

116

Adsorption of hydrogen on copper catalysts  

SciTech Connect (OSTI)

Copper catalysts display a high activity and selectivity in the hydrogenation of various carbonyl compounds, and copper is a component of the complex catalysts for the synthesis of methanol from CO and H/sub 2/. The adsorption of H/sub 2/ on copper catalysts has been studied by means of thermal desorption. The molecular form of adsorption of H/sub 2/ has been established, the thermal desorption parameters calculated, and the heat of adsorption of H/sub 2/ on a copper surface estimated.

Pavlenko, N.V.; Tripol'skii, A.I.; Golodets, G.I.

1987-10-01T23:59:59.000Z

117

Stressing Out Copper TSVs with Temperature  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and failure in TSVs, a team of investigators from the National Institute of Standards and Technology, Argonne National Laboratory, and SEMATECH examined copper (Cu) TSVs with...

118

Cathodic Arc Deposition of Copper Oxide Thin Films  

E-Print Network [OSTI]

plasma source with a copper cathode was operated in an oxygen atmosphereplasma source with a copper cathode in an oxygen atmosphere.plasma source with a copper cathode (5 cm diameter) operated in an oxygen atmosphere.

MacGill, R.A.

2011-01-01T23:59:59.000Z

119

Nanograin Copper Deposition Using an Impinging Jet Electrode  

E-Print Network [OSTI]

T. ; Ong, C. K. ; Chew, J. Copper Interconnections for HighT. ; Ong, C. K. ; Chew, J. Copper Interconnections for Highof NanoCrystalline Copper. Nanostructured Materials 1993, 2,

Swingle, Karen Diane

120

The Copper Creek Clovis Point from Hells Canyon, Northeastern Oregon  

E-Print Network [OSTI]

No. 1 (2008) | pp. 75-84 The Copper Creek Clovis Point fromside of the Snake River to the Copper Creek point discovery1 (2008) 5 cm Figure 4. The Copper Creek Clovis point (tick

Reid, Kenneth C.; Root, Matthew J.; Hughes, Richard E.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Microbialsilica interactions in Icelandic hot spring sinter: possible analogues for some Precambrian siliceous stromatolites  

E-Print Network [OSTI]

Microbial±silica interactions in Icelandic hot spring sinter: possible analogues for some, UK àFossil Fuels and Environmental Geochemistry Postgraduate Institute, Drummond Building, University, in particular sections of microstromatolites growing at the Krisuvik hot spring, Iceland, reveals

Konhauser, Kurt

122

Observations on microstructure and crystal structure of sintered lithium metatitanate with excess Li  

Science Journals Connector (OSTI)

Crystal grain growth and crystallization of lithium metatitanate with excess Li (Li2+xTiO3+y), which is expected as an advanced ceramic breeder for a future DEMO fusion reactor, were studied in this paper. By the observation of sintered pellets using scanning electron microscope, it was shown that the Li2.1TiO3+y specimens, which have small grains (1–2 ?m) and narrow size distribution, can be obtained by sintering in the temperature range from 1000 to 1100 °C. The observation also showed the rapid grain growth in the Li2.1TiO3 specimens sintered above 1150 °C. The changes in the crystal structure and the phase transformation with the increase of sintering temperature were also investigated by means of powder X-ray diffraction. Finally, the relationship between the grain growth and the phase state at high temperature was discussed.

Keisuke Mukai; Kazuya Sasaki; Takayuki Terai; Akihiro Suzuki; Tsuyoshi Hoshino

2012-01-01T23:59:59.000Z

123

Title. ATP7B copper-regulated traffic and association with the tight junctions: copper excretion into Short title. ATP7B and copper excretion by liver  

E-Print Network [OSTI]

1 Title. ATP7B copper-regulated traffic and association with the tight junctions: copper excretion into the bile Short title. ATP7B and copper excretion by liver Authors. Sonia Hernandez*§ , Yo Tsuchiya manuscript Gastroenterology 2008;134(4):1215-23 #12;2 Abstract The copper transporter ATP7B plays a central

Boyer, Edmond

124

Ultrasonic evaluation of beryllium-copper diffusion bonds  

SciTech Connect (OSTI)

A study was performed to compare the effectiveness of several advanced ultrasonic techniques when used to determine the strength of diffusion bonded beryllium-copper, which heretofore have each been applied to only a few material systems. The use of integrated backscatter calculations, frequency domain reflection coefficients, and time-of-flight variance was compared in their ability to characterize the bond strength in a series of beryllium-copper diffusion bond samples having a wide variation in bond quality. Correlation of integrated backscatter calculations and time-of-flight variance with bond strength was good. Some correlation of the slope of the frequency based reflection coefficient was shown for medium and high strength bonds, while its Y-intercept showed moderate correlation for all bond strengths.

Jamieson, E.E.

2000-06-08T23:59:59.000Z

125

Copper isotope fractionation in acid mine drainage. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper isotope fractionation in acid mine drainage. Copper isotope fractionation in acid mine drainage. Abstract: We surveyed the Cu isotopic composition of primary minerals and...

126

An Updated Assessement of Copper Wire Thefts from Electric Utilities...  

Energy Savers [EERE]

An Updated Assessement of Copper Wire Thefts from Electric Utilities - October 2010 An Updated Assessement of Copper Wire Thefts from Electric Utilities - October 2010 The U.S....

127

Inertia of the Carrier of Electricity in Copper and Aluminum  

Science Journals Connector (OSTI)

In this experiment the mass-charge ratio of the carrier of an electric current in a metallic conductor was precisely determined. This was done by measuring the change in amplitude resulting from reversing the current in a cylindrical coil supported as a torsional pendulum. Determinations of me of the carrier were made for coils of both copper and aluminum and various current values were used in each coil. The average value obtained for me of the carrier is 5.69×10-9 gram per coulomb. The accepted value of this ratio for the electron is 5.68×10-9 gram per coulomb.

C. F. Kettering and G. G. Scott

1944-11-01T23:59:59.000Z

128

The New Face of Protein-bound Copper: The Type Zero Copper Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The New Face of Protein-bound Copper: The The New Face of Protein-bound Copper: The Type Zero Copper Site Nature adapts copper ions to a multitude of tasks, yet in doing so forces the metal into only a few different electronic structures [1]. Mononuclear copper sites observed in native proteins either adopt the type 1 (T1) or type 2 (T2) electronic structure. T1 sites exhibit intense charge-transfer absorption giving rise to their alternate title, blue copper sites, due to highly covalent coordination by a thiol ligand donated by a cysteine sidechain in their host proteins. This interaction has consequences for the spectroscopic features of the protein, but more importantly gives rise to dramatic enhancement of electron transfer activity. T2 sites on the other hand resemble more closely aqueous copper(II) ions, and are found in catalytic domains rather than electron transfer sites.

129

Fetal polyol metabolism in copper deficiency  

SciTech Connect (OSTI)

Since pregnant rats consuming fructose, copper deficient diets fail to give birth, the relationship between maternal copper deficiency, polyol metabolism and fetal mortality was investigated. Forty Sprague-Dawley rats were fed from conception one of the following diets: fructose, copper deficient; fructose, copper adequate; starch, copper deficient or starch, copper adequate. The deficient diets contained 0.6 ug Cu and the adequate 6.0 ug Cu/g diet. Pregnancy was terminated at day 19 of gestation. Glucose, sorbitol and fructose were measured in maternal blood, placenta and fetal liver. Fructose consumption during pregnancy resulted in higher levels of fructose and sorbitol in maternal blood when compared to starch. In the fructose dietary groups, the placenta and fetal liver contained extremely high levels of glucose, fructose and sorbitol compared to the corresponding metabolites from the starch dietary groups. Copper deficiency further elevated fructose and sorbitol concentrations in the placenta and fetal liver respectively. Since high tissue levels of glucose, fructose and sorbitol have been shown to have deleterious effects on cellular metabolism, these data suggest that when fructose was fed during pregnancy the combination of an aberration of carbohydrate metabolism with copper deficiency could be responsible for the pathology and mortality of the developing fetus.

Fields, M.; Lewis, C.G.; Beal, T. (Georgetown Univ. Medical Center, Washington, DC (USA))

1989-02-09T23:59:59.000Z

130

Concentration and distribution of copper in effluents from three freshwater nuclear power stations  

SciTech Connect (OSTI)

The concentrations and physicochemical forms of copper were determined in samples from the water column and bedload sediments in the intake and discharge zones of the Vermont Yankee, Kewaunee, and Fort St. Vrain Nuclear Power Stations. These stations differ in their mode of operation and in the composition of water circulated in their cooling systems. In addition, at Vermont Yankee, water samples were collected during changeover from open- to closed-cycle operation, and water and sediment samples were collected from the base of the cooling tower during closed-cycle operation. Copper concentrations were obtained for the soluble, including labile and bound, and particulate fractions of water samples and for bedload sediments collected in discharge and intake areas during the winter, spring, and summer months of 1978. The apparent copper complexing capacity (ACC), the dissolved organic carbon content (DOC), and the percentages of copper in different molecular-weight fractions were also determined for the soluble fraction of water samples. In addition, copper distribution coefficients (K/sub d/s of particles suspended in the water column and present in the bedload sediment were determined. 41 references, 10 figures, 20 tables.

Harrison, F.L.; Bishop, D.J.; Rice, D.W. Jr.; Emerson, R.; Smith, B.J.

1983-09-01T23:59:59.000Z

131

THE EFFECT OF AUFWUCHS COPPER ON SPAT SETTLEMENT OF THE  

E-Print Network [OSTI]

#12;#12;THE EFFECT OF AUFWUCHS COPPER ON SPAT SETTLEMENT OF THE OYSTER, CRASSOSTERA VIRGINICA Dr States Government." #12;THE EFFECT OF AUFWUCKS COPPER ON SPAT SETTLEMENT OF THE OYSTER, CRASSOSTREA is copper. Copper is used specifically as an antifouling agent on ship bottoms. Crisp and Austin (1960

District of Columbia, University of the

132

COPPER--1998 22.1 By Daniel L. Edelstein  

E-Print Network [OSTI]

COPPER--1998 22.1 COPPER By Daniel L. Edelstein Domestic survey data and tables were prepared of recoverable copper in the United States reversed its decade-long upward trend, declining by about 80,000 metric tons to the lowest level since 1995. Mine cutbacks and closures were attributed to low copper

133

Effects of organic matters coming from Chinese tea on soluble copper release from copper teapot  

Science Journals Connector (OSTI)

The morphology and elemental composition of the corrosion products of copper teapot's inner-surface were characterized by the scanning electron microscopy and energy dispersive X-ray surface analysis (SEM/EDS), X-ray powder diffraction (XRD) and X-ray photon spectroscopy (XPS) analysis. It was revealed that Cu, Fe, Ca, P, Si and Al were the main elements of corrosion by-products, and the ?-SiO2, Cu2O and CaCO3 as the main mineral components on the inner-surface of copper teapot. The effects of organic matters coming from Chinese tea on soluble copper release from copper teapots in tap water were also investigated. The results showed that the doses of organic matter (as TOC), temperate and stagnation time have significant effects on the concentration of soluble copper released from copper teapots in tap water.

Lixiao Ni; Shiyin Li

2008-01-01T23:59:59.000Z

134

Enery Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications  

SciTech Connect (OSTI)

This is the final technical report for the Department of Energy NETL project NT01931 Energy Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications. Titanium has been identified as one of the key materials with the required strength that can reduce the weight of automotive components and thereby reduce fuel consumption. Working with newly developed sources of titanium powder, Webster-Hoff will develop the processing technology to manufacture low cost vehicle components using the single press/single sinter techniques developed for iron based powder metallurgy today. Working with an automotive or truck manufacturer, Webster-Hoff will demonstrate the feasibility of manufacturing a press and sinter titanium component for a vehicle application. The project objective is two-fold, to develop the technology for manufacturing press and sinter titanium components, and to demonstrate the feasibility of producing a titanium component for a vehicle application. The lowest cost method for converting metal powder into a net shape part is the Powder Metallurgy Press and Sinter Process. The method involves compaction of the metal powder in a tool (usually a die and punches, upper and lower) at a high pressure (up to 60 TSI or 827 MPa) to form a green compact with the net shape of the final component. The powder in the green compact is held together by the compression bonds between the powder particles. The sinter process then converts the green compact to a metallurgically bonded net shape part through the process of solid state diffusion. The goal of this project is to expand the understanding and application of press and sinter technology to Titanium Powder applications, developing techniques to manufacture net shape Titanium components via the press and sinter process. In addition, working with a vehicle manufacturer, demonstrate the feasibility of producing a titanium component for a vehicle. This is not a research program, but rather a project to develop a process for press and sinter of net shape Titanium components. All of these project objectives have been successfully completed.

Thomas Zwitter; Phillip Nash; Xiaoyan Xu; Chadwick Johnson

2011-03-31T23:59:59.000Z

135

Low Temperature Constrained Sintering of Cerium Gadolinium OxideFilms for Solid Oxide Fuel Cell Applications  

SciTech Connect (OSTI)

Cerium gadolinium oxide (CGO) has been identified as an acceptable solid oxide fuel cell (SOFC) electrolyte at temperatures (500-700 C) where cheap, rigid, stainless steel interconnect substrates can be used. Unfortunately, both the high sintering temperature of pure CGO, >1200 C, and the fact that constraint during sintering often results in cracked, low density ceramic films, have complicated development of metal supported CGO SOFCs. The aim of this work was to find new sintering aids for Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95}, and to evaluate whether they could be used to produce dense, constrained Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} films at temperatures below 1000 C. To find the optimal sintering aid, Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} was doped with a variety of elements, of which lithium was found to be the most effective. Dilatometric studies indicated that by doping CGO with 3mol% lithium nitrate, it was possible to sinter pellets to a relative density of 98.5% at 800 C--a full one hundred degrees below the previous low temperature sintering record for CGO. Further, it was also found that a sintering aid's effectiveness could be explained in terms of its size, charge and high temperature mobility. A closer examination of lithium doped Ce0.9Gd0.1O1.95 indicated that lithium affects sintering by producing a Li{sub 2}O-Gd{sub 2}O{sub 3}-CeO{sub 2} liquid at the CGO grain boundaries. Due to this liquid phase sintering, it was possible to produce dense, crack-free constrained films of CGO at the record low temperature of 950 C using cheap, colloidal spray deposition processes. This is the first time dense constrained CGO films have been produced below 1000 C and could help commercialize metal supported ceria based solid oxide fuel cells.

Nicholas, Jason.D.

2007-06-30T23:59:59.000Z

136

Interaction of copper with cavities in silicon  

SciTech Connect (OSTI)

Copper in Si was shown to be strongly bound at cavities formed by He ion implantation and annealing. Evolution of this system during heating was observed by Rutherford backscattering spectrometry and transmission electron microscopy. Results were mathematically modeled to characterize quantitatively the binding of Cu in the cavities and, for comparison, in precipitates of the equilibrium silicide, {eta}-Cu{sub 3}Si. Binding of Cu to cavities occurred by chemisorption on the walls, and the binding energy was determined to be 2.2{plus_minus}0.2 eV relative to solution in Si. The heat of solution from the silicide was found to be 1.7 eV, consistent with the published phase diagram. These findings suggest the use of cavities for metal-impurity gettering in Si devices. Hydrogen in solution in equilibrium with external H{sub 2} gas displaced Cu atoms from cavity walls, a mechanistically illuminating effect that is also of practical concern for gettering applications.

Myers, S.M.; Follstaedt, D.M. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1056 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185-1056 (United States)

1996-02-01T23:59:59.000Z

137

X-Ray Diffraction Studies of Copper Nanopowder  

E-Print Network [OSTI]

Copper nanopowder preparation and its X-Ray diffraction studies are reported in this paper. Electrolytic cathode deposition method is simple and cheapest process for its preparation. Copper nanopowder has been prepared from aqueous copper sulphate solution. Wide range of experimental conditions has been adopted in this process and its X-Ray diffraction characterizations have been studied. The results confirming copper nanopowder with size below 30 nm. Uniformed size Copper nanopowder preparation, in normal room temperature is importance of this study.

T. Theivasanthi; M. Alagar

2010-03-31T23:59:59.000Z

138

Determination of chemical properties of a supported copper oxide catalyst  

E-Print Network [OSTI]

$) to the theoretioal oonsiderations upon whish the derivation of the B. E. T. equation is based, have bean made, tbe &. E. T, method (8) is still aooepted as giving reliable values for the surface area of an adsorbent. Esger~agg1EL3 Ngh~g pease (41) and Homfray... area of a catalyst ar adsorbent, Emmstt (15) des- cribed an apparatus of the constantmotums type, Modifications to this apparatus were suggested by ahura and Harld. ns (26~28) ~ One method used for the investigation of catalytic surfaoes consists...

Bandyopadhyay, Asok

2012-06-07T23:59:59.000Z

139

Electrolytic remediation of chromated copper arsenate wastes  

E-Print Network [OSTI]

While chromated copper arsenate (CCA) has proven to be exceptionally effective in protecting wood from rot and infestation, its toxic nature has led to the problem of disposal of CCA-treated lumber and remediation of waters ...

Stern, Heather A. G. (Heather Ann Ganung)

2006-01-01T23:59:59.000Z

140

The role of copper transporter 1 (CTR1) in the cellular accumulation of platinum drugs  

E-Print Network [OSTI]

Abstract #3260. 2009- AACR. Copper transporter 2 regulatesof bortezomib on the human copper transporter 1. Clin CancerChemotherapeutics ………………………………… 4 Copper Transporter

Larson, Christopher Alan

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

A molecular dynamics study of void initiation and growth in monocrystalline and nanocrystalline copper  

E-Print Network [OSTI]

of Nanocrystal Copper . . . . . . . 5.4.1 Base Crystallinebetween two crystals of copper undergoes uniaxial expansion.potentials used for copper. . . . . . . . . . . 62 Table of

Traiviratana, Sirirat

2008-01-01T23:59:59.000Z

142

Contribution of Arbuscular Mycorrhizal (Glomus Intraradices) Fungus with Tomato Plants grown under Copper Toxicity  

E-Print Network [OSTI]

of the toxic effect of copper. Therefore additionalpotassium, calcium, iron and copper from soil particles, anddifferent concentration of copper. Total protein content

Malekzadeh, Parviz; Khara, Jalil; Farshian, Shadi

2009-01-01T23:59:59.000Z

143

An experimental and computational investigation of shock effects in monocrystalline copper  

E-Print Network [OSTI]

of Monocrystalline Copper: Experiments and Simulation”, Buin Monocrystalline Copper”, Bu Yang Cao, David H. Lassila,Substructure in Single Crystal Copper”, Bu Yang Cao, David

Cao, Buyang

2006-01-01T23:59:59.000Z

144

EFFECT OF GRAIN SIZE ON THE ACOUSTIC EMISSION GENERATED DURING PLASTIC DEFORMATION OF COPPER  

E-Print Network [OSTI]

PLASTIC DEFORMATION OF COPPER J, Baram Materials Engineeringfrom plastically deformed copper specimens were analyzedrelated to the behavior of copper while undergoing plastic

Baram, J.

2011-01-01T23:59:59.000Z

145

Aluminum and copper in drinking water enhance inflammatory oroxidative events specifically in the brain  

E-Print Network [OSTI]

2000. Characterization of copper interactions with AlzheimerJ. , Flodman, T. , 1999. Copper in drinking water, Nebraska,the oxidative stress of copper-mediated melanin formation.

Bondy, Stephen Bondy C

2006-01-01T23:59:59.000Z

146

A model of material removal and post process surface topography for copper CMP  

E-Print Network [OSTI]

DA. Fundamental Mechanisms of Copper CMP - PassivationKinetics of Copper in CMP Slurry Constituents. Mater. Res.the Passivated Additives in Copper CMP. J. Electrochem. Sci.

Choi, Seungchoun; Doyle, Fiona M.; Dornfeld, David

2011-01-01T23:59:59.000Z

147

Arsenic and chromium partitioning in a podzolic soil contaminated by chromated copper arsenate  

E-Print Network [OSTI]

N. Leaching of chromated copper arsenate wood preservatives:EXAFS study of chromated copper arsenate timber preservative5) U.S. -EPA. Chromated Copper Arsenate (CCA). http://

Hopp, Luisa

2008-01-01T23:59:59.000Z

148

Effect of Sintering Temperature on Dielectric Properties of Iron Deficient Nickel-Ferrite  

SciTech Connect (OSTI)

Nickel Ferrite among all the magneto ceramic materials have been studied very much due to its large number of applications. But there is a large scope of modification of its properties. Thus people still working on it for improvisation of its properties via compositional and structural modifications. Present paper reporting the preparation and characterization of iron deficient Nickel ferrite for different sintering temperature. Ferrite samples having the general formula NiFe1.98O{sub 4} were prepared using the standard ceramic method. The phase formation was confirmed by X-ray diffraction technique. The effect of sintering temperature on the electrical properties and resistivity was studied. The data shows that dielectric properties are highly dependent on the sintering temperature.

Rani, Renu [Electroceramics Research Lab, GVM Girls College, Sonepat-131001 (India); School of Physics and Material Science, Thapar University, Patiala-147004 (India); Singh, Sangeeta [Department of Physics, GVM Girls College, Sonepat-131001 (India); Juneja, J. K. [Department of Physics, Hindu College, Sonepat-131001 (India); Prakash, Chandra [Directorate of ER and IPR, DRDO, DRDO Bhawan, New Delhi-110105 (India); Raina, K. K. [School of Physics and Material Science, Thapar University, Patiala-147004 (India)

2011-11-22T23:59:59.000Z

149

Effects of TiCl4 Purity on the Sinterability of Armstrong-Processed Ti Powder  

SciTech Connect (OSTI)

A series of high purity and low purity powders were synthesized from TiCl4 by the Armstrong process. While both powders displayed swelling when consolidated and sintered, the lower purity powder exhibited this phenomenon in significantly lower degree. The improvement is attributed to the increase in the onset of sintering temperature, which mitigates the entrapment of volatile impurities that would otherwise lead to pore formation and growth. The net effect is that the use of a lower purity TiCl4 may beneficial in two ways: (1) it is a potentially lower cost precursor to Ti powder production and (2) the trace impurities allow higher density components to be fabricated via a typical low-cost press and sinter approach.

Weil, K. Scott; Hovanski, Yuri; Lavender, Curt A.

2009-04-03T23:59:59.000Z

150

Sintering and fouling characterization of ashes with high calcium oxide content  

SciTech Connect (OSTI)

This research work has taken into consideration the behavior of Estonian oil shale ash with high calcium oxide content under typical FB conditions while focusing the main attention on bed agglomeration and fireside deposits. The different types of ashes tested included: (1) ash collected from the cyclone of a PF oil shale boiler, (2) ash collected from the electrostatic precipitator of the same boiler, and (3) oil shale ash prepared by standard laboratory procedures. The ashes were tested for their compression strength, a sintering test under laboratory conditions. First, cylindrical pellets were made from the ash samples. Then the pellets were exposed for four hours to various atmospheres, and various temperatures in the range 300--1,050 C, in a tube furnace. After the exposure, the pellets were tested for compression strength, and the pellet crushing stress was taken as an indicator for the degree of sintering. The compression tests were complemented with chemical analyses of heat treated ash pellets. Changes of mass and dimensions of the heat treated pellets were also recorded. Some experiments were also made to simulate the impact energy of different ash particles, to investigate the buildup of ash deposits on the heat transfer surfaces of boilers. The tests showed that significant sintering occurred under most of the conditions tested. The sintering of the oil shale ash was found to be dependent on both heat treatment temperature and gas atmosphere. Higher pressure at pellet making resulted in some cases in increased sintering. Based on these results, it was concluded that bed sintering would probably not be a problem in a FBC, but fouling of the heat transfer surfaces after the fluidized bed combustor could be a potential problem, in particular, at flue gas temperatures in the range 600 to 900 C.

Ots, A.; Parve, T. [Tallinn Technical Univ. (Estonia); Skrifvars, B.J.; Hupa, M. [Abo Akademi, Turku (Finland)

1995-12-31T23:59:59.000Z

151

Polycyclic aromatic hydrocarbon emission profiles and removal efficiency by electrostatic precipitator and wetfine scrubber in an iron ore sintering plant  

SciTech Connect (OSTI)

A monitoring campaign of polychlorinated dibenzo-p-dioxins and dibenzofurans, polyaromatic hydrocarbons (PAHs), and polychlorinated biphenyl was carried out in an Italian iron ore sintering plant by sampling the combustion gases at the electrostatic precipitator (ESP) outlet, at the Wetfine scrubber (WS) outlet, and by collecting the ESP dust. Few data are available on these micropollutants produced in iron ore sintering plants, particularly from Italian plants. This study investigates the PAH emission profiles and the removal efficiency of ESPs and WS. PAHs were determined at the stack, ESP outlet flue gases, and in ESP dust to characterize the emission profiles and the performance of the ESP and the WS for reducing PAH emission. The 11 PAHs monitored are listed in the Italian legislative decree 152/2006. The mean total PAH sum concentration in the stack flue gases is 3.96 {mu}g/N m{sup 3}, in ESP outlet flue gases is 9.73 {mu}g/N m{sup 3}, and in ESP dust is 0.53 {mu}g/g. Regarding the emission profiles, the most abundant compound is benzo(b)fluoranthene, which has a relative low BaP toxic equivalency factors (TEF) value, followed by dibenzo(a,l)pyrene, which has a very high BaP(TEF) value. The emission profiles in ESP dust and in the flue gases after the ESP show some changes, whereas the fingerprint in ESP and stack flue gases is very similar. The removal efficiency of the ESP and of WS on the total PAH concentration is 5.2 and 59.5%, respectively. 2 figs., 5 tabs.

Ettore Guerriero; Antonina Lutri; Rosanna Mabilia; Maria Concetta Tomasi Sciano; Mauro Rotatori [Istituto sull'Inquinamento Atmosferico, Monterotondo Scalo (Italy). Consiglio Nazionale delle Ricerche

2008-11-15T23:59:59.000Z

152

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers  

E-Print Network [OSTI]

Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

Volinsky, Alex A.

153

Effect of temperature and time on properties of Spark Plasma Sintered NiCuZn: Co ferrite  

E-Print Network [OSTI]

behavior and their applications in power electronics devices for from the radio frequency (300 kHz to 3 MHzEffect of temperature and time on properties of Spark Plasma Sintered NiCuZn: Co ferrite K. Zehani Plasma Sintering is a powerfal method to produce fine grain dense ferrite at low temperature. However

154

Method for providing uranium with a protective copper coating  

DOE Patents [OSTI]

The present invention is directed to a method for providing uranium metal with a protective coating of copper. Uranium metal is subjected to a conventional cleaning operation wherein oxides and other surface contaminants are removed, followed by etching and pickling operations. The copper coating is provided by first electrodepositing a thin and relatively porous flash layer of copper on the uranium in a copper cyanide bath. The resulting copper-layered article is then heated in an air or inert atmosphere to volatilize and drive off the volatile material underlying the copper flash layer. After the heating step an adherent and essentially non-porous layer of copper is electro-deposited on the flash layer of copper to provide an adherent, multi-layer copper coating which is essentially impervious to corrosion by most gases.

Waldrop, Forrest B. (Powell, TN); Jones, Edward (Knoxville, TN)

1981-01-01T23:59:59.000Z

155

Shapes of Spectral Lines of Nonuniform Plasma of Electric Arc Discharge Between Copper Electrodes  

SciTech Connect (OSTI)

The radial profiles of the temperature and electron density in the plasma of the free burning electric arc between copper electrodes are studied by optical spectroscopy techniques. The electron density and the temperature in plasma as initial parameters were used in the calculation of the plasma composition in local thermodynamic equilibrium (LTE) assumption. We used the Saha's equation for copper, nitrogen and oxygen, dissociation equation for nitrogen and oxygen, the equation of plasma electrical neutrality and Dalton's law as well. So, it would be possible to determine the amounts of metal vapours in plasma.

Babich, Ida L.; Boretskij, Viacheslav F.; Veklich, Anatoly N. [Radiophysics Faculty, Taras Shevchenko Kyiv National University, 64, Volodymyrs'ka Str., Kyiv 01033 (Ukraine)

2007-09-28T23:59:59.000Z

156

Copper intake and health threat by consuming seafood from copper-contaminated coastal environments in Taiwan  

SciTech Connect (OSTI)

The purpose of this paper is to describe the impact of copper pollution on the main aquaculture coast of Taiwan and the potential risk from eating the green oysters cultured along the polluted coast. The data show that the highest average concentration of copper in oysters was observed in the Erhjin Chi estuary from 1986 to 1990. The copper concentration in both the seawater and the sediment collected along the Erhjin Chi estuary was also the highest in all sampling locations. Copper concentration in oysters collected from Erhjin Chi, Hsiangshan, and Anping from 1988 to 1990 was, respectively, 61, 29, and 22 times higher than that of 10 years ago. The potential frisk from consuming oysters is relatively higher than that of other seafoods due the high bioaccumulation of oysters. The oysters in the Erhjin Chi estuary had an average concentration of copper of 3,075 [+-] 826 [mu]g/g during the past three years (1988--1990). The average copper intake from oysters for an adult with 70 kg body weight was 12.6 mg/d. The estimate indicated that the average copper intake from the oysters for female individuals is 14 times more than that of international limits. Based on the average value, long-term intake of copper through consumption of oysters cultured along the Erhjin Chi estuary be critical, especially for some high-risk groups.

Han, B.C. (Taipei Medical Coll. (Taiwan, Province of China). School of Public Health); Jeng, W.L.; Hung, T.C. (National Taiwan Univ., Taipei (Taiwan, Province of China). Inst. of Oceanography); Jeng, M.S. (Academia Sinica, Taipei (Taiwan, Province of China). Inst. of Zoology)

1994-05-01T23:59:59.000Z

157

Reduction of Sintering during Annealing of FePt Nanoparticles Coated with Iron Oxide  

E-Print Network [OSTI]

are first obtained by reduction of iron(III) acetylacetonate and platinum(II) acetylacetonateReduction of Sintering during Annealing of FePt Nanoparticles Coated with Iron Oxide Chao LiuVised Manuscript ReceiVed October 12, 2004 FePt/iron oxide core/shell nanoparticles are synthesized by a two step

Laughlin, David E.

158

Cu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials  

E-Print Network [OSTI]

relates electrical resistivity to thermal conductivity for materials where electrons are principleCu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials P to produce composite materials. A high melting phase (HMP) and low melting phase (LMP) are mixed

Collins, Gary S.

159

Sintered molybdenum for a metallized ceramic substrate packaging for the wide-  

E-Print Network [OSTI]

of thermal expansion (CTE) matching that of SiC are needed. A metallized ceramic substrate based on aluminium the metal layer) and thermal conductivity (of the metal and ceramic layers). The most substrate usedSintered molybdenum for a metallized ceramic substrate packaging for the wide- bandgap devices

Boyer, Edmond

160

Advantages of Microwave Sintering in Manufacturing of Anode Support Solid Oxide Fuel Cell  

E-Print Network [OSTI]

and facile method in the manufacturing of anode support solid oxide fuel cell(1). Two anode support SOFCsPage 5-211 Advantages of Microwave Sintering in Manufacturing of Anode Support Solid Oxide Fuel oxide fuel cell (SOFC, hereafter) has been identified as an attractive technique in the recent few

Kasagi, Nobuhide

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Anhydrous Phosphoric Acid Functionalized Sintered Mesoporous Silica Nanocomposite Proton Exchange Membranes for Fuel Cells  

Science Journals Connector (OSTI)

Anhydrous Phosphoric Acid Functionalized Sintered Mesoporous Silica Nanocomposite Proton Exchange Membranes for Fuel Cells ... The cell performance and stability may be further improved through an optimization of the interfacial contact between the electrocatalytic layer and the inorganic membrane. ... polycondensation procedure was optimized for individual case of PBI synthesis in order to obtain inherent viscosity of ?1 dL/g. ...

Jie Zeng; Beibei He; Krystina Lamb; Roland De Marco; Pei Kang Shen; San Ping Jiang

2013-10-14T23:59:59.000Z

162

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

163

Mechanical properties of WC10Co cemented carbides sintered from nanocrystalline spray conversion processed powders  

E-Print Network [OSTI]

Mechanical properties of WC±10Co cemented carbides sintered from nanocrystalline spray conversion as the spray conversion process [2]. The WC particle sizes in powders fabricated by the spray conversion: microstructural parameters such as WC grain size, Co mean free path and WC/WC contiguity; chemical factors

Hong, Soon Hyung

164

Isotope effects in methanol synthesis and the reactivity of copper...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

165

COPPER--2000 23.1 By Daniel L. Edelstein  

E-Print Network [OSTI]

discovered copper resource in the United States was estimated to be 350 Mt. U.S. copper smelter and refinery that predominantly yielded ore for direct shipping to smelters (80 smelters operated in 1907). By 1900, Montana

166

Effect of starting powders on the sintering of nanostructured ZrO2 ceramics by colloidal processing  

Science Journals Connector (OSTI)

The effect of starting powders on the sintering of nanostructured tetragonal zirconia was evaluated. Suspensions were prepared with a concentration of 10?vol.% by mixing a bicomponent mixture of commercial powders (97?mol.% monoclinic zirconia with 3?mol.% yttria) and by dispersing commercially available tetragonal zirconia (3YTZ, Tosoh). The preparation of the slurry by bead-milling was optimized. Colloidal processing using 50??m zirconia beads at 4000?rpm generated a fully deagglomerated suspension leading to the formation of high-density consolidated compacts (62% of the theoretical density (TD) for the bicomponent suspension). Optimum colloidal processing of the bicomponent suspension followed by the sintering of yttria and zirconia allowed us to obtain nanostructured tetragonal zirconia. Three different sintering techniques were investigated: normal sintering, two-step sintering and spark plasma sintering. The inhibition of grain growth in the bicomponent mixed powders in comparison with 3YTZ was demonstrated. The inhibition of the grain growth may have been caused by inter-diffusion of cations during the sintering.

Gustavo Suárez; Yoshio Sakka; Tohru S Suzuki; Tetsuo Uchikoshi; Xinwen Zhu; Esteban F Aglietti

2009-01-01T23:59:59.000Z

167

Laser Copper Plasma X-ray Source Debris Characterization  

E-Print Network [OSTI]

Laser Copper Plasma X-ray Source Debris Characterization A Thesis Presented by David Hurley 3, 2007 Vice President for Research and Dean of Graduate studies #12;Abstract Laser copper plasma for x-ray lithography. Copper debris in the form of vapor, ions, dust, and high-speed particles

Huston, Dryver R.

168

COPPER SENSITIVITY OF PACIFIC HERRING, CLUPEA HARENGUS PALLASI,  

E-Print Network [OSTI]

COPPER SENSITIVITY OF PACIFIC HERRING, CLUPEA HARENGUS PALLASI, DURING ITS EARLY LIFE HISTORY D. W pallasi, were exposed to copper, using a flow-through bioassay system. Herring embryos were exposed until yolk sac absorption. Embryos were also exposed to 36-h duration pulses of copper in order

169

Short communication Influence of molybdenum and sulfur on copper  

E-Print Network [OSTI]

Short communication Influence of molybdenum and sulfur on copper metabolism in sheep: comparison of molybdenum able to trigger the copper sulfur molybdenum interference in sheep was measured with either only) and 4 increasing molybdenum doses. The sulfur-molybdenum-copper interference was quantified

Paris-Sud XI, Université de

170

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP  

E-Print Network [OSTI]

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP M. LAMAND Claudine LAB in the injection site. Copper per os dosing is efficient for treating deficient animals (Lamand et al., 1969 consuming. Therefore we tried to per- fect a copper and zinc deficiency treatment allowing the injection

Paris-Sud XI, Université de

171

High energy X-ray diffraction study of a dental ceramics–titanium functional gradient material prepared by field assisted sintering technique  

Science Journals Connector (OSTI)

Abstract A functional gradient material with eleven layers composed of a dental ceramics and titanium was successfully consolidated using field assisted sintering technique in a two-step sintering process. High energy X-ray diffraction studies on the gradient were performed at High Energy Material Science beamline at Desy in Hamburg. Phase composition, crystal unit edges and lattice mismatch along the gradient were determined applying Rietveld refinement procedure. Phase analysis revealed that the main crystalline phase present in the gradient is ?-Ti. Crystallinity increases stepwisely along the gradient with a decreasing increment between every next layer, following rather the weight fraction of titanium. The crystal unit edge a of titanium remains approximately constant with a value of 2.9686(1) Ĺ, while c is reduced with increasing amount of titanium. In the layer with pure titanium the crystal unit edge c is constant with a value of 4.7174(2) Ĺ. The lattice mismatch leading to an internal stress was calculated over the whole gradient. It was found that the maximal internal stress in titanium embedded in the studied gradient is significantly smaller than its yield strength, which implies that the structure of titanium along the whole gradient is mechanically stable.

K. Witte; W. Bodnar; N. Schell; H. Lang; E. Burkel

2014-01-01T23:59:59.000Z

172

A Mathematical model of copper corrosion  

E-Print Network [OSTI]

A new partial differential model for monitoring and detecting copper corrosion products (mainly brochantite and cuprite) is proposed to provide predictive tools suitable for describing the evolution of damage induced on bronze specimens by sulfur dioxide (SO_2) pollution. This model is characterized by the movement of a double free boundary. Numerical simulations show a nice agreement with experimental result.

Clarelli, Fabrizio; Natalini, Roberto

2012-01-01T23:59:59.000Z

173

A Mathematical model of copper corrosion  

E-Print Network [OSTI]

A new partial differential model for monitoring and detecting copper corrosion products (mainly brochantite and cuprite) is proposed to provide predictive tools suitable for describing the evolution of damage induced on bronze specimens by sulfur dioxide (SO_2) pollution. This model is characterized by the movement of a double free boundary. Numerical simulations show a nice agreement with experimental result.

Fabrizio Clarelli; Barbara De Filippo; Roberto Natalini

2012-11-29T23:59:59.000Z

174

The Temperature of the Copper Arc  

Science Journals Connector (OSTI)

...Laboratory, General Electric Company. | Journal Article...TEMPERATURE OF THE COPPER ARC By C. G. SUITS RESEARCH LABORATORY, GENERAL ELECTRIC COMPANY Read before the...figure 1, where Fis an arc burning between the electrodes...experiment is a condensed discharge between the electrode...

C. G. Suits

1935-01-01T23:59:59.000Z

175

Prehistoric Copper Production and Technological Reproduction  

E-Print Network [OSTI]

. Results indicate a long-term improvement in the technical proficiency of Valley metalworkers, accompanied1 Prehistoric Copper Production and Technological Reproduction in the Khao Wong Prachan Valley of change in prehistoric extractive metallurgical behaviour in the Khao Wong Prachan Valley of central

Paris-Sud XI, Université de

176

Nanoscale Growth Twins in Sputtered Copper Films  

E-Print Network [OSTI]

.............................................................. 7 I.1.3. Chemical vapor deposition (CVD) .................................... 8 I.2. Fabrication of copper thin films .................................................... 12... to the exposure of the film growth surface to the solution, impurities may be introduced. I.1.3. Chemical vapor deposition (CVD) CVD is a chemical process used to produce high-purity, high-performance thin films and often used in the semiconductor industry...

Anderoglu, Osman

2011-08-08T23:59:59.000Z

177

Nanoparticle plasma ejected directly from solid copper by localized microwaves  

SciTech Connect (OSTI)

A plasma column ejected directly from solid copper by localized microwaves is studied. The effect stems from an induced hotspot that melts and emits ionized copper vapors as a confined fire column. Nanoparticles of {approx}20-120 nm size were revealed in the ejected column by in situ small-angle x-ray scattering. Optical spectroscopy confirmed the dominance of copper particles in the plasma column originating directly from the copper substrate. Nano- and macroparticles of copper were verified also by ex situ scanning electron microscopy. The direct conversion of solid metals to nanoparticles is demonstrated and various applications are proposed.

Jerby, E.; Golts, A.; Shamir, Y.; Wonde, S.; Ashkenazi, D.; Eliaz, N. [Faculty of Engineering, Tel Aviv University, Ramat Aviv 69978 (Israel); Mitchell, J. B. A.; LeGarrec, J. L. [IPR., U.M.R. No. 6251 du C.N.R.S., Universite de Rennes I, 35042 Rennes (France); Narayanan, T.; Sztucki, M. [European Synchrotron Radiation Facility, BP-220, 38043 Grenoble (France); Barkay, Z. [Wolfson Applied Materials Research Center, Tel Aviv University, Ramat-Aviv 69978 (Israel)

2009-11-09T23:59:59.000Z

178

Influence of sintering temperature on the characteristics of shale brick containing oil well-derived drilling waste  

Science Journals Connector (OSTI)

The influence of sintering temperature on the physico-mechanical characteristics (such as water absorption, apparent porosity, bulk density, weight loss on ignition, firing shrinkage, and compressive strength), l...

Xiang-Guo Li; Yang Lv; Bao-Guo Ma…

2011-11-01T23:59:59.000Z

179

Preparation and sintering of silica-doped zirconia by colloidal processing  

SciTech Connect (OSTI)

Silica-doped (SiO{sub 2} = 0--1.0 mass%) zirconia (3 mol% Y{sub 2}O{sub 3}-doped tetragonal ZrO{sub 2}) compacts are prepared from hetero-coagulated and well-dispersed suspensions by colloidal processing. The suspensions are consolidated by a pressure filtration technique. The green density of the compacts consolidated from the well-dispersed suspensions is higher than that from the hetero-coagulated suspensions. The lower density of the latter compacts is improved by a subsequent cold isostatic pressing (CIP) at 400 MPa. The sinterability of the compacts at 1,200 C is greatly affected by the amount of doped silica. The densification and grain growth are hindered by silica doping above 0.3 wt% at 1,200 C. All the compacts are densificated to a relative density of above 99% by sintering at 1,300 C for 2 h.

Uchikoshi, T.; Sakka, Y.; Ozawa, K.; Hiraga, K. [National Research Inst. for Metals, Tsukuba, Ibaraki (Japan)

1997-09-01T23:59:59.000Z

180

Method of preparing a sintered lithium aluminate structure for containing electrolyte  

DOE Patents [OSTI]

A porous sintered tile is formed of lithium aluminate for retaining molten lectrolyte within a fuel cell. The tile is prepared by reacting lithium hydroxide in aqueous solution with alumina particles to form beta lithium aluminate particles. The slurry is evaporated to dryness and the solids dehydrated to form a beta lithium aluminate powder. The powder is compacted into the desired shape and sintered at a temperature in excess of 1200 K. but less than 1900 K. to form a porous integral structure that is subsequently filled with molten electrolyte. A tile of this type is intended for use in containing molten alkali metal carbonates as electolyte for use in a fuel cell having porous metal or metal oxide electrodes for burning a fuel gas such as hydrogen and/or carbon monoxide with an oxidant gas containing oxygen.

Sim, James W. (Evergreen Park, IL); Kinoshita, Kimio (Cupertino, CA)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Development of an Innovative High-Thermal Conductivity UO2 Ceramic Composites Fuel Pellets with Carbon Nano-Tubes Using Spark Plasma Sintering  

SciTech Connect (OSTI)

Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. Despite its numerous advantages such as high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation, it suffers from low thermal conductivity that can result in large temperature gradients within the UO2 fuel pellet, causing it to crack and release fission gases. Thermal swelling of the pellets also limits the lifetime of UO2 fuel in the reactor. To mitigate these problems, we propose to develop novel UO2 fuel with uniformly distributed carbon nanotubes (CNTs) that can provide high-conductivity thermal pathways and can eliminate fuel cracking and fission gas release due to high temperatures. CNTs have been investigated extensively for the past decade to explore their unique physical properties and many potential applications. CNTs have high thermal conductivity (6600 W/mK for an individual single- walled CNT and >3000 W/mK for an individual multi-walled CNT) and high temperature stability up to 2800°C in vacuum and about 750°C in air. These properties make them attractive candidates in preparing nano-composites with new functional properties. The objective of the proposed research is to develop high thermal conductivity of UO2–CNT composites without affecting the neutronic property of UO2 significantly. The concept of this goal is to utilize a rapid sintering method (5–15 min) called spark plasma sintering (SPS) in which a mixture of CNTs and UO2 powder are used to make composites with different volume fractions of CNTs. Incorporation of these nanoscale materials plays a fundamentally critical role in controlling the performance and stability of UO2 fuel. We will use a novel in situ growth process to grow CNTs on UO2 particles for rapid sintering and develop UO2-CNT composites. This method is expected to provide a uniform distribution of CNTs at various volume fractions so that a high thermally conductive UO2-CNT composite is obtained with a minimal volume fraction of CNTs. The mixtures are sintered in the SPS facility at a range of temperatures, pressures, and time durations so as to identify the optimal processing conditions to obtain the desired microstructure of sintered UO2-CNT pellets. The second objective of the proposed work is to identify the optimal volume fraction of CNTs in the microstructure of the composites that provides the desired high thermal conductivity yet retaining the mechanical strength required for efficient function as a reactor fuel. We will systematically study the resulting microstructure (grain size, porosity, distribution of CNTs, etc.) obtained at various SPS processing conditions using optical microscopy, scanning electron microscopy (SEM), and transmission electron microscope (TEM). We will conduct indentation hardness measurements and uniaxial strength measurements as a function of volume fraction of CNTs to determine the mechanical strength and compare them to the properties of UO2. The fracture surfaces will be studied to determine the fracture characteristics that may relate to the observed cracking during service. Finally, we will perform thermal conductivity measurements on all the composites up to 1000° C. This study will relate the microstructure, mechanical properties, and thermal properties at various volume fractions of CNTs. The overall intent is to identify optimal processing conditions that will provide a well-consolidated compact with optimal microstructure and thermo-mechanical properties. The deliverables include: (1) fully characterized UO2-CNT composite with optimal CNT volume fraction and high thermal conductivity and (2) processing conditions for production of UO2-CNT composite pellets using SPS method.

Subhash, Ghatu; Wu, Kuang-Hsi; Tulenko, James

2014-03-10T23:59:59.000Z

182

Irradiation creep of nano-powder sintered silicon carbide at low neutron fluences  

SciTech Connect (OSTI)

The irradiation creep behavior of nano-powder sintered silicon carbide was investigated using the bend stress relaxation method under neutron irradiation up to 1.9 dpa. The creep deformation was observed at all temperatures ranging from 380 to 1180 °C mainly from the irradiation creep but with the increasing contributions from the thermal creep at higher temperatures. Microstructural observation and data analysis were performed.

Koyanagi, Takaaki [ORNL; Shimoda, Kazuya [Kyoto University, Japan; Kondo, Sosuke [Kyoto University, Japan; Hinoki, Tatsuya [Kyoto University, Japan; Ozawa, Kazumi [ORNL; Katoh, Yutai [ORNL

2014-01-01T23:59:59.000Z

183

Sintering and devitrification of glass-powder compacts in the akermanite–gehlenite system  

Science Journals Connector (OSTI)

The sintering and devitrification behavior of glass-powder compacts with four compositions, Ca2Mg0.5Al1.0Si1.5O7, Ca2Mg0.6Al0.8Si1.6O7, Ca2Mg0.7Al0.6Si1.7O7, and Ca2Mg0.8Al0.4Si1.8O7, corresponding to akermanite–...

Allu Amarnath Reddy; Dilshat U. Tulyaganov; Ashutosh Goel…

2013-06-01T23:59:59.000Z

184

Sintering behavior of lanthanide-containing glass-ceramic sealants for solid oxide fuel cells  

SciTech Connect (OSTI)

This article reports on the influence of different lanthanides (La, Nd, Gd and Yb) on sintering behavior of alkaline-earth aluminosilicate glass-ceramics sealants for their application in solid oxide fuel cells (SOFC). All the glasses have been prepared by melt-quench technique. The in situ follow up of sintering behavior of glass powders has been done by high temperature - environmental scanning electron microscope (HT-ESEM) and hot-stage microscope (HSM) while the crystalline phase evolution and assemblage has been analyzed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). All the glass compositions exhibit a glass-in-glass phase separation followed by two stage sintering resulting in well sintered glass powder compacts after heat treatment at 850 C for 1 h. Diopside (CaMgSi{sub 2}O{sub 6}) based phases constituted the major crystalline part in glass-ceramics followed by some minor phases. The increase in lanthanide content in glasses suppressed their tendency towards devitrification, thus, resulting in glass-ceramics with high amount of residual glassy phase (50-96 wt.%) which is expected to facilitate their self-healing behavior during SOFC operation. The electrical conductivity of the investigated glass-ceramics varied between (1.19 and 7.33) x 10{sup -7} S cm{sup -1} (750-800 C), and depended on the ionic field strength of lanthanide cations. Further experimentation with respect to the long term thermal and chemical stability of residual glassy phase under SOFC operation conditions along with high temperature viscosity measurements will be required in order to elucidate the potential of these glass-ceramics as self-healing sealants.

Goel, Ashutosh; Reddy, Allu Amarnath; Pascual, Maria J.; Gremillard, Laurent; Malchere, Annie; Ferreira, Jose M.

2012-05-01T23:59:59.000Z

185

Compaction and sintering behaviors of a Nd-Fe-B permanent magnet alloy  

SciTech Connect (OSTI)

Extensive x-ray diffraction (XRD) and magnetic measurements were done on Nd/sub 15/ Fe/sub 77/ B/sub 8/ magnet alloy green compacts after cold isostatic pressing following a pulsed 2-T field (CIP) and die-pressing under a static 1.2-T perpendicular field (DP1) or parallel field (DP2), and on those after sintering. An alignment factor F, through the calculation of the integrated diffraction intensity ratio of the XRD patterns, was adopted as the effectiveness of magnetic alignment. At the green compact state, DP1 has the best alignment while CIP the worst. However, after sintering the alignment factor was such that CIP>DPI>DP2, the same order as the magnetic properties. Three mechanisms were proposed for the evolution of the alignment factor at different stages of sintering, i.e., that both the appearance of a liquid phase at low temperatures and preferred grain growth at high temperatures enhance F, while recrystallization at intermediate temperatures deteriorates F. CIP results in less-defect green compact, hence less recrystallization, leading to better resultant alignment

Chin, T.; Hung, M.; Tsai, D.; Wu, K.; Chang, W.

1988-11-15T23:59:59.000Z

186

Accuracy of exchange-correlation functionals and effect of solvation on the surface energy of copper  

Science Journals Connector (OSTI)

Surface energies are important for predicting the shapes of nanocrystals and describing the faceting and roughening of surfaces. Copper surfaces are of particular interest in recent years since they are the preferred surfaces for growing graphene using chemical vapor deposition. In this study we calculate the surface energies of copper for the three low-index facets (111), (100), and (110) and one high-index facet, (210), using density-functional theory with both the local-density approximation and various parametrizations of the generalized-gradient approximation to the exchange-correlation functional. To assess the accuracy of the different functionals, we obtain the average surface energies of an isotropic crystal using a broken-bond model. We use this method, which can be generalized to other crystal structures, to compare calculated surface energies to experimental surface energies for fcc crystals. We find that the recent exchange-correlation functionals AM05 and PBEsol are the most accurate functionals for calculating the surface energies of copper. To determine how solvents affect the surface energies of copper, we perform calculations using a continuum solvation model. We find that aqueous solvation changes the overall magnitude of the surface energies only slightly but leads to more isotropic surface energies.

Matthew Fishman; Houlong L. Zhuang; Kiran Mathew; William Dirschka; Richard G. Hennig

2013-06-03T23:59:59.000Z

187

Precision micro drilling with copper vapor lasers  

SciTech Connect (OSTI)

The authors have developed a copper vapor laser based micro machining system using advanced beam quality control and precision wavefront tilting technologies. Micro drilling has been demonstrated through percussion drilling and trepanning using this system. With a 30 W copper vapor laser running at multi-kHz pulse repetition frequency, straight parallel holes with size varying from 500 microns to less than 25 microns and with aspect ratio up to 1:40 have been consistently drilled on a variety of metals with good quality. For precision trepanned holes, the hole-to-hole size variation is typically within 1% of its diameter. Hole entrance and exit are both well defined with dimension error less than a few microns. Materialography of sectioned holes shows little (sub-micron scale) recast layer and heat affected zone with surface roughness within 1--2 microns.

Chang, J.J.; Martinez, M.W.; Warner, B.E.; Dragon, E.P.; Huete, G.; Solarski, M.E.

1994-09-02T23:59:59.000Z

188

Rotating copper plasmoid in external magnetic field  

SciTech Connect (OSTI)

Effect of nonuniform magnetic field on the expanding copper plasmoid in helium and argon gases using optical emission spectroscopy and fast imaging is presented. We report a peculiar oscillatory rotation of plasmoid in magnetic field and argon ambient. The temporal variation and appearance of the dip in the electron temperature show a direct evidence of the threading and expulsion of the magnetic field lines from the plasmoid. Rayleigh Taylor instability produced at the interface separating magnetic field and plasma is discussed.

Pandey, Pramod K.; Thareja, Raj K. [Department of Physics, Indian Institute of Technology Kanpur, Uttar Pradesh 208 016 (India)

2013-02-15T23:59:59.000Z

189

Copper vapor laser modular packaging assembly  

DOE Patents [OSTI]

A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

1992-01-01T23:59:59.000Z

190

Atomistic insights into aqueous corrosion of copper.  

SciTech Connect (OSTI)

Corrosion is a fundamental problem in electrochemistry and represents a mode of failure of technologically important materials. Understanding the basic mechanism of aqueous corrosion of metals such as Cu in presence of halide ions is hence essential. Using molecular dynamics simulations incorporating reactive force-field (ReaxFF), the interaction of copper substrates and chlorine under aqueous conditions has been investigated. These simulations incorporate effects of proton transfer in the aqueous media and are suitable for modeling the bond formation and bond breakage phenomenon that is associated with complex aqueous corrosion phenomena. Systematic investigation of the corrosion process has been carried out by simulating different chlorine concentration and solution states. The structural and morphological differences associated with metal dissolution in the presence of chloride ions are evaluated using dynamical correlation functions. The simulated atomic trajectories are used to analyze the charged states, molecular structure and ion density distribution which are utilized to understand the atomic scale mechanism of corrosion of copper substrates under aqueous conditions. Increased concentration of chlorine and higher ambient temperature were found to expedite the corrosion of copper. In order to study the effect of solution states on the corrosion resistance of Cu, partial fractions of proton or hydroxide in water were configured, and higher corrosion rate at partial fraction hydroxide environment was observed. When the Cl{sup -} concentration is low, oxygen or hydroxide ion adsorption onto Cu surface has been confirmed in partial fraction hydroxide environment. Our study provides new atomic scale insights into the early stages of aqueous corrosion of metals such as copper.

Jeon, B.; Sankaranarayanan, S. K. R. S.; van Duin, A. C. T.; Ramanathan, S. (Center for Nanoscale Materials); (Harvard Univ.); (Penn State Univ.)

2011-06-21T23:59:59.000Z

191

Boron-copper neutron absorbing material and method of preparation  

DOE Patents [OSTI]

A composite, copper clad neutron absorbing material is comprised of copper powder and boron powder enriched with boron 10. The boron 10 content can reach over 30 percent by volume, permitting a very high level of neutron absorption. The copper clad product is also capable of being reduced to a thickness of 0.05 to 0.06 inches and curved to a radius of 2 to 3 inches, and can resist temperatures of 900.degree. C. A method of preparing the material includes the steps of compacting a boron-copper powder mixture and placing it in a copper cladding, restraining the clad assembly in a steel frame while it is hot rolled at 900.degree. C. with cross rolling, and removing the steel frame and further rolling the clad assembly at 650.degree. C. An additional sheet of copper can be soldered onto the clad assembly so that the finished sheet can be cold formed into curved shapes.

Wiencek, Thomas C. (Bolingbrook, IL); Domagala, Robert F. (Indian Head Park, IL); Thresh, Henry (Palos Hts., IL)

1991-01-01T23:59:59.000Z

192

Argonne CNM Highlight: Patterned Copper Nanowires with Novel Electrical  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Patterned Copper Nanowires with Novel Electrical Effects Patterned Copper Nanowires with Novel Electrical Effects Micrograph of copper nanowire A micrograph of the sample layout and the copper nanowire (l = 2.04 um, w = 90 nm, t = 50 nm) between the contact pads. Metallic nanowires have various applications such as sensors and high-density interconnects in field-effect transistors. Monitoring the influence of size and surface effects on material properties, such as electrical resistivity and failure properties, is important in designing new, reliable nanowires. Copper nanowires were patterned with e-beam lithography and fabricated with a copper film deposited by e-beam evaporation. Electrical measurements show that surface and size have effects on the electrical properties. Smaller values for the temperature coefficient of resistance and higher failure

193

NREL: Process Development and Integration Laboratory - Copper Indium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper Indium Gallium Diselenide Cluster Tool Capabilities Copper Indium Gallium Diselenide Cluster Tool Capabilities The Copper Indium Gallium Diselenide (CIGS) cluster tool in the Process Development and Integration Laboratory offers powerful capabilities with integrated chambers for depositing, processing, measuring, and characterizing photovoltaic materials and devices. You can read more on the rationale for developing this cluster tool and its capabilities, and check out the National Solar Technology Roadmap for CIGS Photovoltaics. Contact Miguel Contreras for more details on these capabilities. The Copper Indium Gallium Diselenide cluster tool, manufactured by DCA Instruments, will be operational in 2009. Techniques will include evaporation; radiofrequency, direct-current (DC), and pulsed DC sputtering;

194

Method of imaging the heart using copper-64 citrate  

DOE Patents [OSTI]

A method of imaging the heart to provide a distinct image using positron emission tomography comprises administering copper-64 citrate and a compatible carrier.

Crook, James E. (Oak Ridge, TN)

1988-01-01T23:59:59.000Z

195

Competition of copper, lead, and cadmium adsorption to goethite.  

E-Print Network [OSTI]

??Competition of copper, lead, and cadmium adsorption on goethite depends on metal ion and oxide surface characteristics. Goethite was characterized via X-ray diffraction, potentiometric titrations,… (more)

Christophi, Chris A.

1998-01-01T23:59:59.000Z

196

Resonant Inelastic X-ray Scattering of Rare-Earth and Copper Systems  

E-Print Network [OSTI]

2.3 Corrosion of Copper Films in Aqueous2.3.1 Cu 2p XAS of Copper Films in Various2.3.2 Cu 2p RIXS of Copper Film in Groundwater

Kvashnina, Kristina

2007-01-01T23:59:59.000Z

197

Copper Transporter 2 (CTR2) as a regulator of cisplatin accumulation and sensitivity  

E-Print Network [OSTI]

1997). "hCTR1: A human gene for copper uptake identified byKlomp, et al. (1997). "The copper chaperone for superoxidecharacterization of a copper transport protein in S.

Blair, Brian G.

2009-01-01T23:59:59.000Z

198

Copper nanocrystal modified activated carbon for supercapacitors with enhanced volumetric energy and power density  

E-Print Network [OSTI]

Copper nanocrystal modified activated carbon for supercapacitors with enhanced volumetric energy of copper nanocrystals in AC has little effect on the surface area and porosity of activated carbon. copper nanocrystals improves the electrical conductivity of the carbon network.

Cao, Guozhong

199

Products of High-Energy Deuteron and Helium Ion Bombardments of Copper  

E-Print Network [OSTI]

AND HELIUM ION BOHBARDMENTS OF COPPER D. R. Miller, R. C.observations made when natural copper (stable mass numbersof the Bombardment of Natural Copper with 190 Mev Deuterons

Miller, D.R.

2010-01-01T23:59:59.000Z

200

Development of a Scanning Probe Microscope and Studies of Graphene Grown on Copper  

E-Print Network [OSTI]

of Graphene Grown on Copper (100) Single Crystals,” JournalGraphene on Polycrystalline Copper,” Nano Letters 11, 251 (5 GRAPHENE GROWTH ON COPPER (100) SINGLE CRYSTALS 5.1

Rasool, Haider Imad

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

STRUCTURAL CONTROL AND ANISOTROPY OF MINERALIZATION THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT,  

E-Print Network [OSTI]

STRUCTURAL CONTROL AND ANISOTROPY OF MINERALIZATION WITHIN THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT CONTROL AND ANISOTROPY OF MINERALIZATION WITHIN THE CHUQUICAMATA PORPHYRY COPPER DEPOSIT, NORTHERN CHILE the Chuquicamata Porphyry Copper Deposit, northern Chile DEPARTMENT OR SCHOOL: Department of Earth Sciences DEGREE

Beaumont, Christopher

202

TEMPERATURE DEPENDENCE OF THE THRESHOLD ENERGY FOR FRENKEL PAIR PRODUCTION IN COPPER  

E-Print Network [OSTI]

FRENKEL PAIR PRODUCTION IN COPPER R. Drosd, T. Kosel, and J.FRENKEL PAIR PRODUCTION IN COPPER R. Drosd, T. Kosel and J.110) foils of high purity copper in the HVEM. At 575°K loops

Drosd, jR.

2010-01-01T23:59:59.000Z

203

10GBASE10GBASE--T:T: 10Gbit/s Ethernet over copper10Gbit/s Ethernet over copper  

E-Print Network [OSTI]

1 10GBASE10GBASE--T:T: 10Gbit/s Ethernet over copper10Gbit/s Ethernet over copper NEWCOM realization Start-up procedure Status and outlook #12;3 Ethernet over UTP copper is ubiquitousEthernet over UTP copper is ubiquitous 4-pair UTP cable + RJ-45 connector: fast, secure, cheap 4 Ethernet over UTP

Chen, Sheng

204

Spatial distribution of average charge state and deposition rate in high power impulse magnetron sputtering of copper  

E-Print Network [OSTI]

was Ľ inch (6. 25 mm) thick copper disk. The diameter of thevery high power de nsity. Copper was selected for this studythe high stability of HIPIMS copper discharges ( copper can

Horwat, David

2008-01-01T23:59:59.000Z

205

Experimental and finite-element study of residual stresses in Zircaloy-4(R) and OFHC copper tubes  

SciTech Connect (OSTI)

Nonhomogeneous plastic deformation associated with metal-forming operations results in a state of residual stress in the final product. In the experimental phase of this study, residual stress distribution in Zr-4(R) and copper tubes is determined by electropolishing the outer (or inner) and surface of the tubes while measuring the developed strains at the inner (or outer) surface. Material removal by electropolishing proved to be an efficient and suitable technique due to its constant mass removal rate under conditions which do not alter the patter of residual stresses in the specimen. In the case of Zr-4(R) specimens, experiments were conducted on the as-received (stress relieved) as well as specimens annealed at 500 C for one hour. The effect of various degrees of cold working on the residual stress patterns of drawn copper tubing is determined by performing similar experiments on soft, 1/4-hard, 1/2-hard, and hard temper, OFHC copper specimens. In the second phase of this investigation, an elastic-plastic finite-element code (ABAQUS) is employed in a parametric study to determined the optimum processing conditions for drawing copper tubes.

Rasty, J.

1987-01-01T23:59:59.000Z

206

Cluster size effects on sintering, CO adsorption, and implantation in Ir/SiO{sub 2}  

SciTech Connect (OSTI)

A series of planar model catalysts have been prepared via deposition of Ir{sub n}{sup +} on thermally grown amorphous SiO{sub 2}/Si(100) and ion scattering spectroscopy was used to probe surface structure as a function of cluster size, impact energy, and surface temperature. Deposition of Ir{sub 2} or Ir{sub 10} at low energies and room temperature results in stable clusters forming one- or two-dimensional single layer islands on the oxide surface. Heating the samples to 750 K leads to agglomeration, forming multilayer structures on the surface. Ir{sub 1} deposited under similar conditions sinters into large clusters at room temperature. Deposition at 110 K at least partially stabilizes the Ir atoms with respect to diffusion and sintering. At higher deposition energies, partial implantation into the surface is observed, but this appears to be insufficient to stabilize the clusters against sintering at elevated temperature. At low temperatures, substrate-mediated adsorption of CO is found to be highly efficient, leading to near saturation coverages of CO bound atop the Ir{sub n} clusters. The CO can be removed by careful He{sup +} sputtering. The deposition/binding behavior of Ir{sub n} on SiO{sub 2} is quite different from Ir{sub n}/TiO{sub 2}(110), for which the clusters bind in three-dimensional morphology, starting at Ir{sub 5}. That system also shows substrate-mediated adsorption of CO, but the CO preferentially binds at the periphery of the clusters rather than on top.

Kaden, W. E.; Kunkel, W. A.; Anderson, Scott L. [Department of Chemistry, University of Utah, 315 S. 1400 E. RM 2020, Salt Lake City, Utah 84112-0850 (United States)

2009-09-21T23:59:59.000Z

207

Dislocation density in copper and tantalum after shock loading up to 20-80 GPa  

National Nuclear Security Administration (NNSA)

4: Materials-EOS and Thermodynamic Properties 4: Materials-EOS and Thermodynamic Properties Dislocation Density in Copper And Tantalum After Shock Loading Up To 20-100 GPA A.M. Podurets, M.I. Tkachenko, O.N. Ignatova, A.I. Lebedev, V.V. Igonin, V.A. Raevsky RFNC-VNIIEF, Institute of Physics of Explosion, Sarov, Russia Introduction A microstructure of metals at shock loading is determined by the same processes, which occur at any deformation including a competition of two basic mechanisms of plastic strain - dislocation slip and twinning. The action of a specified mechanism of plastic deformation under the conditions of dynamic loading is usually defined by the help of the analysis of samples recovered after loading. We consider the dislocation structure of two metals having various crystal lattices: face-centered cubic copper and body-

208

E-Print Network 3.0 - andean porphyry copper Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Utah have recorded overKEY WORDS: alkaline magma; Bingham; porphyry copper... Bingham Canyon porphyry copper deposit range in may also have effectively removed magmatic...

209

Successful application of the Top-Layer-Sintering Process for recycling of ferrous residuals contaminated with organic substances  

SciTech Connect (OSTI)

The value of by-products and residues from steel production processes stem from their metal content and their inherent heat of combustion. However, the organic contents of sludge, scale and of other ferrous residuals make it difficult to recycle them via the conventional sinter process due to low burning rates. Insufficient burning rates will increase the dust load, could harm the ESTP and is responsible for the formation of the blue haze. The Top-Layer-Sintering Process using a second ignition hood which ignites the second layer on top of the main sinterbed has opened an economical and ecologically clean way for returning waste materials to valuable blast furnace burden by sintering. In pot grate test series and semi industrial tests the process was optimized. An industrial recycling plant for treatment of organic containing residuals is now in operation.

Kinzel, J.; Pammer, O. [Voest-Alpine Industrieanlagenbau GmbH, Linz (Austria); Trimmel, W. [Voest-Alpine Stahl Linz GmbH (Austria); Zellner, H. [Voest-Alpine Stahl Donawitz GmbH, Leoben-Donawitz (Austria)

1997-12-31T23:59:59.000Z

210

Copper Removal from A-01 Outfall by Ion Exchange  

SciTech Connect (OSTI)

Chelex100, a commercially available ion exchange resin, has been identified in this study as having a significant affinity for copper and zinc in the A-01 outfall water. Removal of copper and zinc from A-01 outfall water will ensure that the outfall meets the state of South Carolina's limit on these heavy metals.

Oji, L.N.

1999-02-17T23:59:59.000Z

211

Microstructure and properties of copper thin films on silicon substrates  

E-Print Network [OSTI]

copper thin films but on an expense of conductivity. This study proposes a technique to deposit high strength and high conductivity copper thin films on different silicon substrates at room temperature. Single crystal Cu (100) and Cu (111) have been grown...

Jain, Vibhor Vinodkumar

2009-05-15T23:59:59.000Z

212

Tungsten-yttria carbide coating for conveying copper  

DOE Patents [OSTI]

A method is provided for providing a carbided-tungsten-yttria coating on the interior surface of a copper vapor laser. The surface serves as a wick for the condensation of liquid copper to return the condensate to the interior of the laser for revolatilization.

Rothman, Albert J. (Livermore, CA)

1993-01-01T23:59:59.000Z

213

NANO-INDENTATION OF COPPER THIN FILMS ON SILICON SUBSTRATES  

E-Print Network [OSTI]

NANO-INDENTATION OF COPPER THIN FILMS ON SILICON SUBSTRATES S. Suresh1 , T.-G. Nieh2 and B.W. Choi2: Mechanical properties; Nano-indentation; Thin films; Copper; Dislocations Introduction Indentation methods films on substrates (e.g., [2,3]) using instrumented indentation. Nano-indentation studies of thin films

Suresh, Subra

214

Active/passive behavior of copper in strong sulfuric acid  

SciTech Connect (OSTI)

A combination of thermodynamic analyses and potentiodynamic polarization tests have been used to study the anodic behavior of Cu in strong H{sub 2}SO{sub 4} solutions in the concentration range 1--10 M. The studies were supplemented by chemical analyses of surface films. It was found that concentration-dependent changes in the activity of water played a major role in determining the anodic behavior and relative stability of corrosion product films. The anodic Tafel slope decreased from {approximately} 41 to {approximately} 31 mV with increasing acid concentration. The onset of limiting current and active-passive behaviors at higher potentials was determined by the formation of films of hydrated copper sulfate, CuSO{sub 4} {center_dot} xH{sub 2}O, and not by formation of oxides. Limiting current behavior was observed in 1 M solutions, where the degree of hydration was x = 5. Well-developed passivity occurred in 10 M solutions where x = 1. The results are relevant to industrial electrorefining operations for Cu and indicate that chloride contamination, if present in sufficient amounts, could cause the premature onset of limiting current behavior (anode passivity) during refining.

Tromans, D.; Ahmed, T. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Metals and Materials Engineering

1998-02-01T23:59:59.000Z

215

Two-stage sintering inhibits abnormal grain growth during beta to alpha transformation in SiC  

SciTech Connect (OSTI)

Free sintering of SiC with Al, B, and C additions in two successive stages, first under nitrogen and then under argon, produced a near full-density ceramic with equiaxed grain structure. The beta to alpha transformation proceeded to completion; however, the grain shape remained equiaxed due to the action of nitrogen present during the first stage of sintering. It is found that the beta to alpha transformation is necessary but not sufficient for producing the microstructure of interlocking plates found in high-toughness SiC.

Kueck, Aaron M.; De Jonghe, Lutgard C.

2007-09-17T23:59:59.000Z

216

Copper Valley Elec Assn, Inc | Open Energy Information  

Open Energy Info (EERE)

Copper Valley Elec Assn, Inc Copper Valley Elec Assn, Inc Place Alaska Utility Id 4329 Utility Location Yes Ownership C NERC Location AK Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Copper River Basin large commercial Commercial Copper River Basin small commercial Commercial Copper River Basin Residential Residential Valdez Residential Residential Valdez large commercial Commercial Valdez small commercial Commercial Average Rates Residential: $0.2520/kWh Commercial: $0.2150/kWh References ↑ "EIA Form EIA-861 Final Data File for 2010 - File1_a"

217

An Updated Assessement of Copper Wire Thefts from Electric Utilities -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

An Updated Assessement of Copper Wire Thefts from Electric An Updated Assessement of Copper Wire Thefts from Electric Utilities - October 2010 An Updated Assessement of Copper Wire Thefts from Electric Utilities - October 2010 The U.S. Department of Energy (DOE), Office of Electricity Delivery and Energy Reliability monitors changes, threats, and risks to the energy infrastructure in the United States. This report updates a previously published report on copper wire theft. The combined efforts of electric utilities, lawmakers, scrap metal dealers, and local law enforcement have succeeded in reducing the problem. Updated Assessment-Copper-Final October 2010.pdf More Documents & Publications Investigation Letter Report: I11IG002 Semiannual Report to Congress: for the first half of Fiscal Year (FY) 1998 Energy Infrastructure Events and Expansions Year-in-Review 2010

218

Copper-triazole interaction and coolant inhibitor depletion  

SciTech Connect (OSTI)

To a large extent, the depletion of tolyltriazole (TTZ) observed in several field tests may be attributed to the formation of a protective copper-triazole layer. Laboratory aging studies, shown to correlate with field experience, reveal that copper-TTZ layer formation depletes coolant TTZ levels in a fashion analogous to changes observed in the field. XPS and TPD-MS characterization of the complex formed indicates a strong chemical bond between copper and the adsorbed TTZ which can be desorbed thermally only at elevated temperatures. Electrochemical polarization experiments indicate that the layer provides good copper protection even when TTZ is absent from the coolant phase. Examination of copper cooling system components obtained after extensive field use reveals the presence of a similar protective layer.

Bartley, L.S.; Fritz, P.O.; Pellet, R.J.; Taylor, S.A.; Van de Ven, P. [Texaco Fuels and Lubricants Technology Dept., Beacon, NY (United States)

1999-08-01T23:59:59.000Z

219

Optimization of sintered AgI-Mordenite composites for {sup 129}I storage  

SciTech Connect (OSTI)

The thermal processing of a proposed durable waste form for {sup 129}I was investigated. The waste form is a composite with a matrix of low-temperature sintering glass that encapsulates particles of AgI-mordenite. Ag-mordenite, an ion-exchanged zeolite, is being considered as a capture medium for gaseous {sup 129}I{sub 2} as part of a spent nuclear fuel reprocessing scheme under development by the US Department of Energy/Nuclear Energy (NE). The thermal processing of the waste form is necessary to increase the density of the glass matrix by viscous sintering so that the final waste form does not have any open porosity. Other processes that can also occur during the thermal treatment include desorption of chemisorbed I{sub 2}, volatilization of AgI and crystallization of the glass matrix. We have optimized the thermal processing to achieve the desired high density with higher AgI-mordenite loading levels and with minimal loss of iodine. Using these conditions, 625 C. degrees for 20 minutes, the matrix crystallizes to form a eulytite phase. Results of durability tests indicate that the matrix crystallization does not significantly decrease the durability in aqueous environments. (authors)

Garino, T.J.; Nenoff, T.M.; Rodriguez, M.A.; Mowry, C.D.; Rademacher, D.X. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185-1411 (United States)

2013-07-01T23:59:59.000Z

220

Characterizations of WC-10Co nanocomposite powders and subsequently sinterhip sintered cemented carbide  

SciTech Connect (OSTI)

Ultrafine WC-Co cemented carbides, combining high hardness and high toughness, are expected to find broad applications. In this study, WC-10Co-0.4VC-0.4Cr{sub 3}C{sub 2} (wt.%) nanocomposite powders, whose average grain size was about 30 nm, were fabricated by spray pyrolysis-continuous reduction and carbonization technology. The as-prepared nanocomposite powders were characterized and analyzed by chemical methods, scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET analysis and atomic force microscopy (AFM). Furthermore, 'sinterhip' was used in the sintering process, by which ultrafine WC-10Co cemented carbides with an average grain size of 240 nm were prepared. The material exhibited high Rockwell A hardness of HRA 92.8, Vickers hardness HV{sub 1} 1918, and transverse rapture strength (TRS) of 3780 MPa. The homogeneously dispersed grain growth inhibitors such as VC, Cr{sub 3}C{sub 2} in nanocomposite powder and the special nonmetal-metal nanocomposite structure of WC-10Co nanocomposite powder played very important roles in obtaining ultrafine WC-10Co cemented carbide with the desired properties and microstructure. There was an abundance of triple junctions in the ultrafine WC-10Co cemented carbide; these triple junctions endowed the sintered specimen with high mechanical properties.

Shi, X.L. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China)]. E-mail: sxl071932@126.com; Shao, G.Q. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Duan, X.L. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Xiong, Z. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Yang, H. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China)

2006-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Geothermal energy resource investigations in the Eastern Copper River Basin, Alaska  

SciTech Connect (OSTI)

This report consists of a review of the geological, geochemical and geophysical data available for the Eastern Copper River basin with emphasis on the mud volcanoes, and the results of geophysical and geochemical studies carried out in the summers of 1982 and 1984. The purpose was to determine if there are geothermal energy resources in the Copper River Basin. The Eastern Copper River basin is situated on the flanks of a major volcano, Mt. Drum, which was active as late as 200,000 years ago and which is thought to have retained significant amounts of residual heat at high levels. Mt. Wrangell, farther to the east, has been volcanically active up to the present time. The 1982 geophysical and geochemical surveys located three principal areas of possible geothermal interest, one near Tazlina and two near the Klawasi mud volcanoes. The intensive survey work of 1984 was concentrated on those areas. We have integrated the results of soil helium, soil mercury, gravity, aeromagnetic, electrical, self-potential, and controlled-source audio magnetotelluric (CSAMT) surveys to evaluate the geothermal potential of the areas studied. 36 figs.

Wescott, E.M.; Turner, D.L.

1985-06-01T23:59:59.000Z

222

Survey of physical property data for several alloys. [Nitronic 33; copper C10400; copper C17510  

SciTech Connect (OSTI)

This report summarizes an examination of physical property data available in the literature for six alloys of potential interest to the Toroidal Fusion Core Experiment in the Fusion Energy Program. The properties of thermal expansion, density, specific heat, electrical resistivity, and thermal conductivity were compiled for six alloys: Nitronic 33, a low-nickel, high manganese stainless steel; nickel-base Inconnel Alloys 625, 718, and X-750; and copper alloys C10400 and C17510. The temperatures of interest were 4-500 K for the Nitronic 33 and the Inconels, and 250-400 K for the copper alloys. Where data were lacking, estimates were made based on theory or comparisons with similar materials.

Pawel, R.E.; Williams, R.K.

1985-08-01T23:59:59.000Z

223

Modeling Fossil Energy Demands of Primary Nonferrous Metal Production: The Case of Copper  

Science Journals Connector (OSTI)

Modeling Fossil Energy Demands of Primary Nonferrous Metal Production: The Case of Copper ... Alumbrera (Argentina) ...

Pilar Swart; Jo Dewulf

2013-11-22T23:59:59.000Z

224

Copper has proven to be a metal of great benefit to people throughout history.  

E-Print Network [OSTI]

Copper has proven to be a metal of great benefit to people throughout history. Copper has been molded into many instru- ments such as pots, weapons and jewelry. In recent history, copper and its alloys have been fashioned into plumbing pipes and fixtures. Although these applications of copper

225

T. Park, et al. 1 MIT-MTL Multi-level Pattern Effects in Copper CMP  

E-Print Network [OSTI]

T. Park, et al. 1 MIT-MTL Multi-level Pattern Effects in Copper CMP Multi-level Pattern Effects in Copper CMP T. Park, T. Tugbawa, D. Boning Massachusetts Institute of Technology http Effects in Copper CMP Copper CMP Process and Problems: Single Level I Non-Uniformity on a Single Layer

Boning, Duane S.

226

Copper Stress Causes an in Vivo Requirement for the Escherichia coli Disulfide Isomerase DsbC*  

E-Print Network [OSTI]

Copper Stress Causes an in Vivo Requirement for the Escherichia coli Disulfide Isomerase Dsb an increased sensitiv- ity to the redox-active metal copper. We find that copper catalyzes periplasmic disulfide bond formation under aerobic conditions and that copper catalyzes the formation of disulfide

Bardwell, James

227

PROOF COPY 019605JAP Effect of pulsing parameters on laser ablative cleaning of copper oxides  

E-Print Network [OSTI]

of copper oxides Jie Zhang,a Youneng Wang, Peng Cheng, and Y. Lawrence Yao Department of Mechanical; accepted 23 January 2006 The characteristics of copper oxide removal are comparably investigated under. Experiments are carried out on copper samples having different oxide layer thicknesses. The copper oxide layer

Yao, Y. Lawrence

228

Efficient and Regioselective Halogenations of 2-Amino-1,3-thiazoles with Copper Salts  

E-Print Network [OSTI]

Efficient and Regioselective Halogenations of 2-Amino-1,3-thiazoles with Copper Salts Fabrice G. Halogenations proceed easily in the presence of copper(I) or copper(II) chlorides, bromides, or iodides directly in solution or with supported copper halides. 1,3-Thiazole rings appear in many compounds that exhibit

Shen, Jun

229

Communications Copper Horizontal Cable 27 15 13-1 SECTION 27 15 13  

E-Print Network [OSTI]

Communications Copper Horizontal Cable 27 15 13-1 SECTION 27 15 13 COMMUNICATIONS COPPER HORIZONTAL of category copper horizontal cable. B. The cable performance (category 5e, category 6A) shall be as specified 20 Copper Testing 5. 27 11 19 Communications Terminations Blocks and Patch Panels 6. 27 15 43

Dawson, Clint N.

230

Laser-based diagnostics for condensation in laser-ablated copper plasmas  

SciTech Connect (OSTI)

We are investigating the thermodynamic conditions under which condensation occurs in laser-ablated copper plasma plumes. The plasma is created by XeCl excimer laser ablation (308 nm, 350 mJ/pulse) at power densities from 500--1000 MW/cm{sup 2}. The atomic vapor expands rapidly into backing pressures of helium ranging from 0--50 torr. The backing gas serves to slow the vapor before it rarefies and provides a third body to stabilize collision complexes between vapor atoms to produce small cluster species. The formation of these small clusters is indicative of the onset of condensation, a process which, under the proper conditions, eventually forms macroscopic particulate in the plume. We use laser-induced fluorescence (LIF) to probe both atomic copper and the copper dimer molecule, Cu{sub 2}. Velocities of atomic Cu have been obtained by a time-of-flight method under varying conditions of backing gas pressure. At low pressure (10 mtorr), the atomic Cu velocity peaks at approximately 2 {times} 10{sup 6} cm/s. Excitation scans of the Cu{sub 2} A {minus} X (0,0) and (1,1) bands yield both a rotational temperature and a vibrational temperature. Direct laser beam absorption is used to determine the number density of atomic copper. Rayleigh scattering from particulate is easily observable under conditions favorable to particulate production. The Cu{sub 2} LIF and Rayleigh-scattered signals disappear instantaneously in the absence of the ablation laser pulse indicating that the particulate is formed during a single laser shot. 10 refs., 9 figs.

Sappey, A.D.; Gamble, T.K.

1991-01-01T23:59:59.000Z

231

One component metal sintering additive for {beta}-SiC based on thermodynamic calculation and experimental observations  

SciTech Connect (OSTI)

Graphical abstract: . Standard Gibbs formation free energies vs. temperature for various metal carbides. The heavy line represents the standard Gibbs free energy for {beta}-SiC. The hatched area denotes the typical liquid phase hot pressing temperature of {beta}-SiC (1973-2123 K). Highlights: {yields} Various metal elements were examined as a sintering additive for {beta}-SiC. {yields} Al and Mg enhanced the density significantly without decomposing {beta}-SiC, as predicted by thermodynamic simulation. {yields} Cr, Fe, Ta, Ti, V and W additives formed metal carbide and/or silicide compounds by decomposing {beta}-SiC. {yields} This approach would be useful for selecting effective sintering additive for high temperature ceramics. -- Abstract: Various types of metals were examined as sintering additives for {beta}-SiC by considering the standard Gibbs formation free energy and vapor pressure under hot pressing conditions (1973-2123 K), particularly for applications in nuclear reactors. Metallic elements having the low long-term activation under neutron irradiation condition, such as Cr, Fe, Ta, Ti, V and W, as well as widely used elements, Al, Mg and B, were considered. The conclusions drawn from thermodynamic considerations were compared with the experimental observations. Al and Mg were found to be effective sintering additives, whereas the others were not due to the formation of metal carbides or silicides from the decomposition of SiC under hot pressing conditions.

Noviyanto, Alfian [School of Materials Science and Engineering, Yeungnam University, Gyeongsan 712-749 (Korea, Republic of)] [School of Materials Science and Engineering, Yeungnam University, Gyeongsan 712-749 (Korea, Republic of); Yoon, Dang-Hyok, E-mail: dhyoon@ynu.ac.kr [School of Materials Science and Engineering, Yeungnam University, Gyeongsan 712-749 (Korea, Republic of)] [School of Materials Science and Engineering, Yeungnam University, Gyeongsan 712-749 (Korea, Republic of)

2011-08-15T23:59:59.000Z

232

Evaluation of sintering effects on SiC incorporated UO2 kernels under Ar and Ar-4%H2 environments  

SciTech Connect (OSTI)

Silicon carbide (SiC) is suggested as an oxygen getter in UO2 kernels used for TRISO particle fuels to lower oxygen potential and prevent kernel migration during irradiation. Scanning electron microscopy and X-ray diffractometry analyses performed on sintered kernels verified that internal gelation process can be used to incorporate SiC in urania fuel kernels. Sintering in either Ar or Ar-4%H2 at 1500 C lowered the SiC content in the UO2 kernels to some extent. Formation of UC was observed as the major chemical phase in the process, while other minor phases such as U3Si2C2, USi2, U3Si2, and UC2 were also identified. UC formation was presumed to be occurred by two reactions. The first was the SiC reaction with its protective SiO2 oxide layer on SiC grains to produce volatile SiO and free carbon that subsequently reacted with UO2 to form UC. The second process was direct UO2 reaction with SiC grains to form SiO, CO, and UC, especially in Ar-4%H2. A slightly higher density and UC content was observed in the sample sintered in Ar-4%H2, but the use of both atmospheres produced kernels with ~95% of theoretical density. It is suggested that incorporating CO in the sintering gas would prevent UC formation and preserve the initial SiC content.

Silva, Chinthaka M [ORNL] [ORNL; Lindemer, Terrence [Harbach Engineering and Solutions] [Harbach Engineering and Solutions; Hunt, Rodney Dale [ORNL] [ORNL; Collins, Jack Lee [ORNL] [ORNL; Terrani, Kurt A [ORNL] [ORNL; Snead, Lance Lewis [ORNL] [ORNL

2013-01-01T23:59:59.000Z

233

Temperature dependence of magnetic behaviour in very fine grained, spark plasma sintered NiCuZn Ferrites  

E-Print Network [OSTI]

with wide bandwidth up to 30MHz. In this paper the frequency range of 100 kHz to 5 MHz is investigated the magnetization processes taking place in these nano grained materials, in the frequency interval of 100kHz to 5Temperature dependence of magnetic behaviour in very fine grained, spark plasma sintered Ni

Boyer, Edmond

234

Final Report: Sintered CZTS Nanoparticle Solar Cells on Metal Foil; July 26, 2011 - July 25, 2012  

SciTech Connect (OSTI)

This is the final report covering 12 months of this subcontract for research on high-efficiency copper zinc tin sulfide (CZTS)-based thin-film solar cells on flexible metal foil. Each of the first three quarters of the subcontract has been detailed in quarterly reports. In this final report highlights of the first three quarters will be provided and details will be given of the final quarter of the subcontract.

Leidholm, C.; Hotz, C.; Breeze, A.; Sunderland, C.; Ki, W.; Zehnder, D.

2012-09-01T23:59:59.000Z

235

It's Elemental - Isotopes of the Element Copper  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nickel Nickel Previous Element (Nickel) The Periodic Table of Elements Next Element (Zinc) Zinc Isotopes of the Element Copper [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 63 69.15% STABLE 65 30.85% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 52 No Data Available Proton Emission No Data Available 53 < 300 nanoseconds Electron Capture No Data Available Proton Emission No Data Available 54 < 75 nanoseconds Proton Emission No Data Available 55 27 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 15.0% 56 93 milliseconds Electron Capture 100.00%

236

Authorized limits for Fernald copper ingots  

SciTech Connect (OSTI)

This development document contains data and analysis to support the approval of authorized limits for the unrestricted release of 59 t of copper ingots containing residual radioactive material from the U.S. Department of Energy (DOE) Fernald Environmental Management Project (FEMP). The analysis presented in this document comply with the requirements of DOE Order 5400.5, {open_quotes}Radiation Protection of the Public and the Environment,{close_quotes} as well as the requirements of the proposed promulgation of this order as 10 CFR Part 834. The document was developed following the step-by-step process described in the Draft Handbook for Controlling Release for Reuse or Recycle Property Containing Residual Radioactive Material.

Frink, N.; Kamboj, S.; Hensley, J.; Chen, S.Y.

1997-09-01T23:59:59.000Z

237

Fracture toughness for copper oxide superconductors  

DOE Patents [OSTI]

An oxide-based strengthening and toughening agent, such as tetragonal Zro.sub.2 particles, has been added to copper oxide superconductors, such as superconducting YBa.sub.2 Cu.sub.3 O.sub.x (123) to improve its fracture toughness (K.sub.IC). A sol-gel coating which is non-reactive with the superconductor, such as Y.sub.2 BaCuO.sub.5 (211) on the ZrO.sub.2 particles minimized the deleterious reactions between the superconductor and the toughening agent dispersed therethrough. Addition of 20 mole percent ZrO.sub.2 coated with 211 yielded a 123 composite with a K.sub.IC of 4.5 MPa(m).sup.0.5.

Goretta, Kenneth C. (Downers Grove, IL); Kullberg, Marc L. (Lisle, IL)

1993-01-01T23:59:59.000Z

238

Fracture toughness for copper oxide superconductors  

DOE Patents [OSTI]

An oxide-based strengthening and toughening agent, such as tetragonal ZrO[sub 2] particles, has been added to copper oxide superconductors, such as superconducting YBa[sub 2]Cu[sub 3]O[sub x] (123) to improve its fracture toughness (K[sub IC]). A sol-gel coating which is non-reactive with the superconductor, such as Y[sub 2]BaCuO[sub 5] (211) on the ZrO[sub 2] particles minimized the deleterious reactions between the superconductor and the toughening agent dispersed therethrough. Addition of 20 mole percent ZrO[sub 2] coated with 211 yielded a 123 composite with a K[sub IC] of 4.5 MPa(m)[sup 0.5].

Goretta, K.C.; Kullberg, M.L.

1993-04-13T23:59:59.000Z

239

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents [OSTI]

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2001-01-01T23:59:59.000Z

240

Inert electrode containing metal oxides, copper and noble metal  

DOE Patents [OSTI]

A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Tantalum–tungsten oxide thermite composites prepared by sol–gel synthesis and spark plasma sintering  

Science Journals Connector (OSTI)

Energetic composite powders consisting of sol–gel derived nanostructured tungsten oxide were produced with various amounts of micrometer-scale tantalum fuel metal. Such energetic composite powders were ignition-tested and the results show that the powders are not sensitive to friction, spark and/or impact ignition. Initial consolidation experiments, using the High-Pressure Spark Plasma Sintering (HPSPS) technique, on the sol–gel derived nanostructured tungsten oxide produced samples with higher relative density than can be achieved with commercially available tungsten oxide. The sol–gel derived nanostructured tungsten oxide with immobilized tantalum fuel metal (Ta–WO3) energetic composite was consolidated to a density of 9.17 g cm?3 or 93% relative density. In addition, those samples were consolidated without significant pre-reaction of the constituents, thus retaining their stored chemical energy.

Joshua D. Kuntz; Octavio G. Cervantes; Alexander E. Gash; Zuhair A. Munir

2010-01-01T23:59:59.000Z

242

Copper Removal from Fuel by Solid-Supported Polyamine Chelating Agents  

Science Journals Connector (OSTI)

Copper Removal from Fuel by Solid-Supported Polyamine Chelating Agents ... The presence of copper in hydrocarbon fuels impairs fuel stability and jet-engine performance. ... The advantages of this approach are that the chelators have high specificity for transition metal ions, that copper ions are directly removed from the fuel, that no metal ions need to be exchanged for binding copper, that no chemicals need be added to the fuel, and that the copper may be recovered after treatment of the fuel. ...

Dhanajay B. Puranik; Yan Guo; Alok Singh; Robert E. Morris; A. Huang; L. Salvucci; R. Kamin; V. David; E. L. Chang

1998-05-27T23:59:59.000Z

243

The lime-soda sinter process for resource recovery from fly ash: A new look  

SciTech Connect (OSTI)

The lime-soda sinter process is one of the earliest and most thoroughly researched and evaluated of the several methods available for resource recovery from fly ash. The principle product, metallurgical grade alumina, is obtained with yields as high as 90% depending upon how much alumina needs to be left in the residue to form acceptable byproduct cement clinker. The process has the advantages of requiring a relatively low sintering temperature (1100-1200{degree}C), using conventional equipment of carbon steel construction, utilizing a variety of calcium and mineralizer raw materials, and producing only a single byproduct consisting of dicalcium silicate that has been shown to be an attractive raw material for the manufacture of portland cement. An economic feasibility study for a combined facility to produce alumina and cement from the fly ash generated by a 1000 MWe coal-fired power station shows a 10.5% return on average investment. This is increased to 14.2% when a disposal charge of $10/ton of fly ash consumed is credited to the process. Research has shown that the soda ash can be replaced by coal cleaning refuse or that the soda ash and one-fourth of the limestone can be replaced by FGD sludge with a savings in raw material cost in both cases. The return on average investment becomes 14.5% when the refuse is used and 15.2% when the sludge is used. The return could be increased further if an inexpensive fluxing agent were substituted for the alumina deliberately left in the residue. 12 refs., 2 figs., 7 tabs.

Burnet, G.

1991-01-01T23:59:59.000Z

244

Synthesis, characterization and properties of anti-sintering nickel incorporated MCM-41 methanation catalysts  

Science Journals Connector (OSTI)

Abstract Several nickel incorporated MCM-41 catalysts with a nickel molar content from 1% to 10% were prepared by a hydrothermal synthesis method, and investigated for their catalytic performances for the production of substitute natural gas (SNG) from syngas methanation in a continuous flow fixed-bed reactor. The catalysts were characterized by FTIR, ICP, XRD, H2-TPR, TG–DTA and TEM, and the results showed that the mesoporous structure of MCM-41 still maintained well when the incorporated Ni molar content was up to 10%. The Ni–M catalyst prepared by the hydrothermal synthesis method with a nickel molar content of 10% showed the best catalytic activity with a high CO conversion of almost 100%, and a CH4 yield of 95.7% at 350 °C with 3:1 molar ratio of H2 to CO under 1.0 MPa and 12000 ml/h/g. Compared with the 10%Ni/M catalyst prepared by the impregnation method, the 10%Ni–M catalyst showed a higher resistance to sintering and no decrease in catalytic activity after calcination at 700 °C for 2 h. In the 100 h stability test under atmospheric pressure, the CO conversion rate and the CH4 yield obtained on 10%Ni–M catalyst maintained at about 100% and 82%, respectively, suggesting an excellent catalytic stability of this catalyst. The results of XRD, H2-TPR and TG–DTA showed that there was a strong interaction between the Ni species and the support, which inhibited the catalyst sintering. And the amount of coke formed on the spent 10%Ni–M catalyst in the stability test was 3.0 wt%. The coke formation was relatively easily to remove by calcination because the deposited carbon had a small particle size and uniform dispersion on the catalyst.

Jiaying Zhang; Zhong Xin; Xin Meng; Miao Tao

2013-01-01T23:59:59.000Z

245

C:\Eco-SSLs\Contaminant Specific Documents\Copper\February 2007\Eco-SSL for Copper Feb 2007.wpd  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper Copper Interim Final OSWER Directive 9285.7-68 U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 Issued July 2006 Revised February 2007 This page intentionally left blank i TABLE OF CONTENTS 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2.0 SUMMARY OF ECO-SSLs FOR COPPER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 3.0 ECO-SSL FOR TERRESTRIAL PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 4.0 ECO-SSL FOR SOIL INVERTEBRATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 5.0 ECO-SSL FOR AVIAN WILDLIFE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.1 Avian TRV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.2 Estimation of Dose and Calculation of the Eco-SSL . . . . . .

246

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

247

Grain Refinement of Permanent Mold Cast Copper Base Alloys  

SciTech Connect (OSTI)

Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

2005-04-01T23:59:59.000Z

248

Rack-induced bonding in blue-copper proteins  

Science Journals Connector (OSTI)

The unique spectroscopic properties of blue-copper centers, i.e. the strong charge-transfer band at approximately 600 nm and the narrow hyperfine coupling in the EPR spectrum, are reviewed. The concept of rack-in...

Bo G. Malmström

1995-01-01T23:59:59.000Z

249

Copper Canyon, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Display map This article is a stub. You can help OpenEI by expanding it. Copper Canyon is a town in Denton County, Texas. It falls under Texas's 26th congressional...

250

An Updated Assessment of Copper Wire Thefts from Electric Utilities...  

Energy Savers [EERE]

of this report that these three sources reasonably represent copper theft, if not in terms of absolute numbers, at least in terms of trends. It is significant that although...

251

Nucleic acid based fluorescent sensor for copper detection  

DOE Patents [OSTI]

A nucleic acid enzyme responsive to copper, comprising an oligonucleotide comprising a nucleotide sequence of SEQ ID NO:1, wherein the nucleic acid enzyme is not self-cleaving.

Lu, Yi; Liu, Juewen

2013-04-02T23:59:59.000Z

252

Copper Aluminate as a potential material for high temperature...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper Aluminate as a potential material for high temperature thermoelectric power generation Home Author: D. T. Morelli, E. D. Case, B. D. Hall, S. Wang Year: 2008 Abstract: URL:...

253

Bioavailable copper modulates oxidative phosphorylation and growth of tumors  

Science Journals Connector (OSTI)

...formation of new blood vessels, and copper has been...acid (TCA) cycle and fuels oxidative phosphorylation...ATP (A), glucose consumption (B...which is consumed to fuel rapid proliferation...more invasive. Oxygen consumption is not quantitatively...

Seiko Ishida; Pénélope Andreux; Carole Poitry-Yamate; Johan Auwerx; Douglas Hanahan

2013-01-01T23:59:59.000Z

254

Magnesium and Copper (II) Chloride: A Curious Redox Reaction .  

E-Print Network [OSTI]

??The focus of this research is to follow the oxidation-reduction reaction of solid magnesium metal and an aqueous solution of copper (II) chloride (CuCl2), both… (more)

Mannard, Moira

2014-01-01T23:59:59.000Z

255

Tuning the photophysical properties of amidophosphine complexes of copper  

E-Print Network [OSTI]

A series of monomeric copper complexes that allow for the tuning of the emission properties is reported. Luminescence lifetimes up to 150 [mu]s are observed in benzene solution at ambient temperature, which are comparable ...

Mickenberg, Seth F. (Seth Fox)

2009-01-01T23:59:59.000Z

256

Enantioselective Copper-Catalyzed Reductive Coupling of Alkenylazaarenes with Ketones   

E-Print Network [OSTI]

Catalytic enantioselective methods for the preparation of chiral azaarene-containing compounds are of high value. By combining the utility of copper hydride catalysis with the ability of C?N-containing azaarenes to activate adjacent alkenes toward...

Saxena, Aakarsh; Choi, Bonnie; Hon, Lam Wai

2012-05-23T23:59:59.000Z

257

Chromated copper arsenate (CCA) has been used to treat lumber...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Chemical Structure of Arsenic and Chromium in Chromated Copper Arsenate (CCA) Treated Wood Peter S. Nico 1 , Scott E. Fendorf 2 , Yvette W. Lowney 3 , Stewart E. Holm 4 , and...

258

Removal of deposited copper from nuclear steam generators  

SciTech Connect (OSTI)

A review of the copper-removal process implemented during the cleaning of the NPD nuclear steam generator in Ontario revealed that major shortcomings in the process were depletion of the strong ammonia solution and relatively poor copper removal. Tests have shown that the concentration of the ammonia solution can be preserved close to its initial value, and high concentrations of complexed copper obtained, by sparging the ammonia solution with oxygen recirculating through a gas recirculation loop. Using recirculating oxygen for sparging at ambient air temperature, approximately 11 g/l of copper were dissolved by 100 g/l ammonia solution while the gaseous ammonia content of the recirculating gas remained well below the lower flammability limit. The corrosion rates of mild steel and commonly used nuclear steam generator tube materials in oxygenated ammonia solution were less than 30 mil/yr and no intergranular attack of samples was observed during tests. A second technique studied for the removal of copper is to ammoniate the spent iron-removal solvent to approximately pH 9.5 and sparge with recirculating oxygen. Complexed ferric iron in the spent iron-removal solvent was found to be the major oxidizing agent for metallic copper. The ferric iron can be derived from oxidation of dissolved ferrous iron to the ferric state or from dissolved oxides of iron directly. To extract copper from the secondary sides of nuclear steam generators, strong ammonia solution sparged with recirculating oxygen is recommended as the first stage, while ammoniated spent iron-removal solvent sparged with recirculating oxygen may be used to remove the copper freshly exposed during the removal of iron.

McSweeney, P.

1982-05-01T23:59:59.000Z

259

Morphological differences in bromeliad leaf surfaces: influence on copper uptake  

E-Print Network [OSTI]

MORPHOLOGICAL DIFFERENCES IN BROMELIAD LEAF SURFACES: INFLUENCE ON COPPER UPTAKE A Thesis by BARBARA DEE FISHER Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE August 1978 Major Subject: Horticulture MORPHOLOGICAL DIFFERENCES IN BROMELIAD LEAF SURFACES: INFLUENCE ON COPPER UPTAKE A Thesis by BARBARA DEE FISHER Approved as to style and content by: hairman of Committee Member Head of Department M...

Fisher, Barbara Dee

1978-01-01T23:59:59.000Z

260

Measurement of the Young's modulus and internal friction of single crystal and polycrystalline copper, and copper-graphite composites as a function of temperature and orientation  

E-Print Network [OSTI]

MEASUREMENT OF THE YOUNG'S MODULUS AND INTERNAL FRICTION OF SINGLE CRYSTAL AND POLYCRYSTALLINE COPPER, AND COPPER- GRAPHITE COMPOSITES AS A FUNCTION OF TEMPERATURE AND ORIENTATION A Thesis by S teven Norman Wicks trom Submitted... AND POLYCRYSTALLINE COPPER, AND COPPER- GRAPHITE COMPOSITES AS A FUNCTION OF TEMPERATURE AND ORIENTATION A Thesis by Steven Norman Wickstrom Approved as to style and content by: A(J ~a Alan Wolfenden (Chairman of Committee) Don E. Bray (Member) Donald G...

Wickstrom, Steven Norman

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

By Daniel L. Edelstein The United States maintained its position as consumption. which was reopened in 1993. Several copper  

E-Print Network [OSTI]

1 COPPER By Daniel L. Edelstein The United States maintained its position as consumption. which was reopened in 1993. Several copper the world's second largest mine producer of Copper was consumed, both as refined mines were under development and slated for copper, accounting for about 19% of world copper

262

Finding new sources of copper in Zambia The Zambian Copperbelt is the largest known source of copper on Earth. Research at the  

E-Print Network [OSTI]

Finding new sources of copper in Zambia The Zambian Copperbelt is the largest known source of copper on Earth. Research at the University of Southampton has challenged conventional thinking about. There is great demand for copper throughout the world, particularly to supply fast-growing economies in countries

Anderson, Jim

263

Thin Film Solar Cells Derived from Sintered Semiconductor Quantum Dots: Cooperative Research and Development Final Report, CRADA number CRD-07-00226  

SciTech Connect (OSTI)

The NREL/Evident team will develop techniques to fabricate thin film solar cells where the absorption layers comprising the solar cells are derived from sintered semiconductor quantum dots.

Ginley, D. S.

2010-07-01T23:59:59.000Z

264

Near-field-enhanced, off-resonant laser sintering of semiconductor particles for additive manufacturing of dispersed Au–ZnO-micro/nano hybrid structures  

Science Journals Connector (OSTI)

Off-resonant near-field enhancement by gold nanoparticles adsorbed on crystalline zinc oxide significantly increases the energy efficiency of infrared laser sintering. In detail, ten different gold mass loads ...

Marcus Lau; Ralf G. Niemann; Mathias Bartsch; William O’Neill…

2014-03-01T23:59:59.000Z

265

Phase, Dielectric and Ferroelectric Properties of Microwave Sintered La and Ca Modified BaTiO{sub 3} Ceramics  

SciTech Connect (OSTI)

Lanthanum and calcium modified barium titanate, Ba{sub (1-x)}La{sub x}Ti{sub (1-x/4)}O{sub 3}/BLT and Ba({sub 1-x})Ca{sub x}TiO{sub 3}/BCT, where x = 0.02, ferroelectric ceramic samples were synthesized in single perovskite phase by microwave processing technique. Sintering temperature was optimized at 1100 deg. C for 1h. Presence of pore free micron size uniform grains suggested the advantage of using microwave sintering process. Transition temperature (T{sub c}) decreases with the substitution of La content in BT system. Temperature coefficient of capacitance is negligible from RT temperature to 75 deg. C for BLT ceramic samples. Polarization vs. electric field (P-E) hysteresis loop study confirms the ferroelectric nature of the modified BT ceramic samples.

Sonia, S.; Patel, R. K. [Department of Chemistry, National Institute of Technology, Rourkela - 769008 (India); Kumar, P. [Department of Physics, National Institute of Technology, Rourkela - 769008 (India); Prakash, Chandra [Directorate of IE and IPR, DRDO, DRDO Bhawan, New Delhi-110105 (India); Agrawal, D. K. [Materials Research Laboratory, Pennsylvania State University, University Park, PA 16802 (United States)

2011-11-22T23:59:59.000Z

266

Effects of sintering additives on dispersion properties of Al2O3 slurry containing polyacrylic acid dispersant  

Science Journals Connector (OSTI)

The effects of sintering aid adsorption on the dispersion properties of aluminum oxide slurries were investigated. We considered Al2O3 slurry without additives and Al2O3 slurry with a Mg additive with 0.1 mass% in oxide equivalent as a sintering aid. In this study, we evaluated the adsorption isotherm of polyacrylic acid (PAA) onto Al2O3 and the dispersion degree of Al2O3 slurries in sedimentation tests under gravity. The adsorption isotherm featured a characteristic adsorption isothermal line with a maximum value when Mg additive was present in Al2O3. In addition, the packing fractions did not correspond to the apparent viscosity. However, in slurry that was allowed to settle for several days, both of them agreed.Therefore, the disagreement between the packing fraction and the apparent viscosity immediately after preparation arose from changes of the dispersion state, such as the decrease of the distance between particles with time.

Hiromi Ohtsuka; Hidetoshi Mizutani; Satoshi IIO; Kazuki Asai; Takayoshi Kiguchi; Hiroshi Satone; Takamasa Mori; Junichiro Tsubaki

2011-01-01T23:59:59.000Z

267

Analysis of copper-rich precipitates in silicon: Chemical state, gettering, and impact on multicrystalline silicon solar cell material  

E-Print Network [OSTI]

thermodynamic considerations that unlike certain metal species, copper tends to form a silicide pathways. In all samples, copper silicide Cu3Si is the only phase of copper identified. It is noted from

268

Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials  

E-Print Network [OSTI]

123 Chapter 3: Copper/Titanium Catalysis Forms Fully-187 vi Chapter 4: Copper-Catalyzed Tandem Markovnikov237 III. Copper(II) Triflate in Dual-Catalytic Role is

Pierce, Conor John

2013-01-01T23:59:59.000Z

269

Copper CMP Modeling: Millisecond Scale Adsorption Kinetics of BTA in Glycine-Containing Solutions at pH 4  

E-Print Network [OSTI]

Society H1153 Copper CMP Modeling: Millisecond Scaleon the surface of a micro-copper electrode in pH 4 aqueousa Cu?I?BTA monolayer on the copper surface. Based on these

Choi, Seungchoun; Tripathi, Shantanu; Dornfeld, David; Doyle, F M

2010-01-01T23:59:59.000Z

270

The copper centers of tyramine ?-monooxygenase and its catalytic-site methionine variants: an X-ray absorption study  

E-Print Network [OSTI]

010-0677-3 ORIGINAL PAPER The copper centers of tyramine b-is a member of a family of copper monooxygenases containingtwo noncoupled copper centers, and includes peptidylgly-

Hess, Corinna R.; Klinman, Judith P.; Blackburn, Ninian J.

2010-01-01T23:59:59.000Z

271

Tribological performance of Al–12Si coatings created via Electrospark Deposition and Spark Plasma Sintering  

Science Journals Connector (OSTI)

Abstract Spark plasma sintering (SPS) and Electrospark deposition (ESD) were used as two manufacturing routes to create Al–12Si coatings with refined microstructures. The tribological performance of these coatings was tested using a linear reciprocating tribometer. The SPS and ESD coatings were compared to a conventionally as-cast ingot (AC) of Al–12Si to observe the effect of particle refinement and morphology changes. The ESD sample exhibited lower wear rates than the AC and SPS samples. During the wear process, the Al and Si phases on the surface of the AC sample were significantly refined. This refinement led to a microstructure near the surface that was similar to the sample generated by SPS, and therefore showed similar wear rates at the end of testing. Subsurface cracking, which is known to occur in the wear of powder metallurgy alloys, was observed for sample SPS. The refinement of the Al and Si phases achieved for ESD process was much greater than what resulted during the wear of the AC and SPS surfaces and as a result the ESD sample showed lower wear rates throughout the entire test.

J. Milligan; J.M. Shockley; R.R. Chromik; M. Brochu

2013-01-01T23:59:59.000Z

272

Lanthanum-promoted copper-based oxygen carriers for chemical looping combustion process  

Science Journals Connector (OSTI)

Copper-based oxygen carriers have high reactivity and favorable thermodynamic properties in the innovative chemical looping combustion (CLC), which results in the inherent...2. The major challenge of copper-based...

Yan Cao; Hou-Yin Zhao; Song P. Sit…

2014-06-01T23:59:59.000Z

273

An investigation of bulk nanocrystalline copper fabricated via severe plastic deformation and nanoparticle consolidation  

E-Print Network [OSTI]

obtained respectively by a top down approach of severe plastic deformation of wrought copper and a bottom up approach of consolidation of copper nanoparticles using equal channel angular extrusion (ECAE). A critical assessment and correlation...

Haouaoui, Mohammed

2007-04-25T23:59:59.000Z

274

Effects of copper catalytic reactions on the development of supersonic hydrogen flames  

SciTech Connect (OSTI)

Copper species are present in hydrogen flames in arc heated supersonic ramjet testing facilities. Homogeneous and heterogeneous copper catalytic reactions may affect the flame development by enhancing the recombination of hydrogen atoms. Computer simulation is used to investigate the effects of the catalytic reactions on the reaction and ignition times of the flames. The simulation uses a modified general chemical kinetics computer program to simulate the development of copper-contaminated hydrogen flames under scramjet testing conditions. Reaction times of hydrogen flames are found to be reduced due to the copper catalytic effects, but ignition times are much less sensitive to such effects. The reduction of reaction time depends on copper concentration, particle size (if copper is in the condensed phase), and Mach number (or initial temperature and pressure). As copper concentration increases or the particle size decreases, reaction time decreases. As Mach number increases (or pressure and temperature decrease), the copper catalytic effects are greater.

Chang, S.L.; Lottes, S.A.; Berry, G.F.

1992-10-01T23:59:59.000Z

275

TOF-SIMS investigations on thermally treated copper–molybdenum films on a carbon substrate  

Science Journals Connector (OSTI)

It was the aim of the work reported here to investigate the distribution of the elements copper, molybdenum and carbon and the carbide formation after different heat treatments of the copper/molybdenum/carbon sys...

Stefan Puchner; Herbert Hutter…

2008-03-01T23:59:59.000Z

276

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate Solutions  

E-Print Network [OSTI]

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate. The copper exchange capacity (CuEC) and Na-Cu exchange reactions on Wyoming montmo- rillonite were studied

Sparks, Donald L.

277

Aluminum and copper in drinking water enhance inflammatory oroxidative events specifically in the brain  

E-Print Network [OSTI]

T. , 1999. Copper in drinking water, Nebraska, 1994. Int. J.to aluminum in drinking water increases inflammatoryH.E. , Kappel, S. , 1984. Drinking-water-induced copper

Bondy, Stephen Bondy C

2006-01-01T23:59:59.000Z

278

Sexual differences in the expression of copper deficiency in rats  

SciTech Connect (OSTI)

The present investigation was undertaken to establish whether the severity of copper deficiency in rats fed diets containing fructose is affected by the presence and type of endogenous sex hormones. Intact and castrated male rats and intact and ovariectomized females were fed from weaning a copper-deficient diet (0.6 ppm) containing 62% fructose for 8 weeks. Regardless of castration, male rats were anemic, exhibited heart hypertrophy, and died of the deficiency. However, castration ameliorated the anemia and delayed the mortality. In contrast, none of the females died of the deficiency. It is suggested that in addition to the sex of the animal, levels of testosterone in the male may also play a role in the severity of copper deficiency.

Fields, M.; Lewis, C.G.; Beal, T.; Scholfield, D.; Patterson, K.; Smith, J.C.; Reiser, S.

1987-11-01T23:59:59.000Z

279

Steady Deflagration of PBX-9501 Within a Copper Cylinder  

SciTech Connect (OSTI)

A copper cylinder cook-off experiment has been designed to cause steady deflagration in PBX-9501 explosive material. The design is documented and preliminary copper expansion results are presented for steady deflagration with a reaction speed of 1092 +/- 24 m/s. The expansion of reaction products from the detonation of an explosive is something that is well understood, and reasonably simulated using documented equations of state (EOS) for many explosives of interest. These EOS were historically measured using a 'standard' copper cylinder test design; this design comprised an annealed, oxygen-free high conductivity (OFHC) copper tube filled with explosive material and detonated from one end. Expansion of the copper wall was measured as a function of time using either a streak camera (for classic testing), or more recently using laser velocimetry techniques. Expansion data were then used to derive the EOS in various preferred forms - which are not discussed here for the sake of brevity. [Catanach, et. al., 1999] When an explosive deflagrates rather than detonating, simulation becomes more difficult. Reaction products are released on a slower time scale, and the reactions are much more affected by the geometry and local temperature within the reaction environment. It is assumed that the standard, documented EOS will no longer apply. In an effort to establish a first order approximation of deflagration product behavior, a cook-off test has been designed to cause steady deflagration in PBX-9501 explosive material, and to record the copper expansion profile as a function of time during this test. The purpose of the current paper is to document the initial test design and report some preliminary results. A proposal for modification of the design is also presented.

Pemberton, Steven J. [Los Alamos National Laboratory; Herrera, Dennis H. [Los Alamos National Laboratory; Herrera, Tommy J. [Los Alamos National Laboratory; Arellano, Jesus C. [Los Alamos National Laboratory; Sandoval, Thomas D. [Los Alamos National Laboratory

2012-06-26T23:59:59.000Z

280

Observation of diamond turned OFHC copper using Scanning Tunneling Microscopy  

SciTech Connect (OSTI)

Diamond turned OFHC copper samples have been observed within the past few months using the Scanning Tunneling Microscope. Initial results have shown evidence of artifacts which may be used to better understand the diamond turning process. The STM`s high resolution capability and three dimensional data representation allows observation and study of surface features unobtainable with conventional profilometry systems. Also, the STM offers a better quantitative means by which to analyze surface structures than the SEM. This paper discusses findings on several diamond turned OFHC copper samples having different cutting conditions. Each sample has been cross referenced using STM and SEM.

Grigg, D.A.; Russell, P.E.; Dow, T.A.

1988-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Contrasting copper evolution in Omega Centauri and the Milky Way  

E-Print Network [OSTI]

Despite the many studies on stellar nucleosynthesis published so far, the scenario for the production of Cu in stars remains elusive. In particular, it is still debated whether copper originates mostly in massive stars or type Ia supernovae. To answer this question, we compute self-consistent chemical evolution models taking into account the results of updated stellar nucleosynthesis. By contrasting copper evolution in Omega Cen and the Milky Way, we end up with a picture where massive stars are the major responsible for the production of Cu in Omega Cen as well as the Galactic disc.

Donatella Romano; Francesca Matteucci

2007-03-29T23:59:59.000Z

282

Studies of Copper Nanoparticles Effects on Micro-organisms  

E-Print Network [OSTI]

We discuss about the antibacterial activities of copper nanoparticles on both Gram negative and Gram positive bacteria in this investigation. First time, we increase its antibacterial activities by using electrical power while on electrolysis synthesis and it is confirmed from its more antibacterial activities (For Escherichia coli bacteria). We investigate the changes of surface area to volume ratio of copper nanoparticles prepared in two different methods and its effects on antibacterial activities. We note that slight change of surface area to volume ratio results in the enhancement of its antibacterial activities.

T. Theivasanthi; M. Alagar

2011-10-05T23:59:59.000Z

283

Copper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis. Part 1. Diimine Ligands  

E-Print Network [OSTI]

materials derived from copper(I) halides.3 However, the resistance of copper(I) halides toward oxidationCopper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis. Part 1. Diimine are noted for the novel 4- and 5-coordinate Cu2- (CN)2 dimers. Thermal analyses show that most

Pike, Robert D.

284

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

285

EFFECT OF BACK-CONTACT COPPER CONCENTRATION ON CdTe CELL OPERATION  

E-Print Network [OSTI]

EFFECT OF BACK-CONTACT COPPER CONCENTRATION ON CdTe CELL OPERATION A.O. Pudov, M. Gloeckler, S of Mechanical Engineering Colorado State University, Ft. Collins, CO 80523 ABSTRACT CdTe solar cells were Copper is commonly used to form low-barrier contacts to p-type CdTe absorbers. Copper, however, is a fast

Sites, James R.

286

Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to cyclic enones with spirocyclic phosphoramidite ligands  

E-Print Network [OSTI]

Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to cyclic enones spirocyclic diol (R)-5. These monodentate ligands have been applied in copper-catalyzed conjugate addition ligands com- bined with copper salts have shown excellent enantio- selectivities in the conjugate addition

Zhang, Xumu

287

Porphyry Copper and Other Intrusion-Related Mineralization in Mexico MARK D. BARTON  

E-Print Network [OSTI]

Porphyry Copper and Other Intrusion-Related Mineralization in Mexico MARK D. BARTON JOHN-MARK G Inc., Tucson, Arizona ABSTRACT Intrusion-related copper-bearing ore deposits in Mexico span a wide. These deposits include world-class copper porphyry and skarn deposits as well as a continuum of similar skarn

Barton, Mark D.

288

Copper: An Essential Micronutrient for Beef Cattle Max Irsik DVM, MAB  

E-Print Network [OSTI]

Copper: An Essential Micronutrient for Beef Cattle Max Irsik DVM, MAB Beef Cattle Extension Veterinarian University of Florid College of Veterinary Medicine Throughout the world copper deficiency limits of phosphorous, copper deficiency is the most sever mineral limitation to grazing livestock throughout extensive

Watson, Craig A.

289

International Journal of Impact Engineering 32 (2005) 473507 Laser shock compression of copper  

E-Print Network [OSTI]

International Journal of Impact Engineering 32 (2005) 473­507 Laser shock compression of copper and copper­aluminum alloys Matthew S. Schneidera , Bimal Kada , Daniel H. Kalantarb , Bruce A. Remingtonb; received in revised form 20 May 2005; accepted 22 May 2005 Available online 25 August 2005 Abstract Copper

Meyers, Marc A.

290

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions  

E-Print Network [OSTI]

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions A novel coordination polymer of mixed-valence copper(I,II) with 4,4A-bipyridine and in situ oxidized and crystallographically char- acterized to be a laminated structure via weak copper(II)­ oxygen interactions. Extended

Li, Jing

291

Copper waveguide cavities with reduced surface loss for coupling to superconducting qubits  

E-Print Network [OSTI]

Copper waveguide cavities with reduced surface loss for coupling to superconducting qubits Daniela, other recent work has involved qubits coupled to copper cavities with coherence times approaching 0.1 ms. The copper provides a good path for thermalizing the cavity walls and qubit chip, although the substantial

Plourde, Britton L. T.

292

The crystal structure and growth direction of nanowire arraysCu fabricated on a copper surface  

E-Print Network [OSTI]

The crystal structure and growth direction of nanowire arraysCu 2 S fabricated on a copper surface We examine the crystal structure and growth direction of nanowire arrays grown from copper surfaces10 On this line, we have recently discovered that by exposing a surfactant-treated copper surface

Wang, Zhong L.

293

A Novel Copper A Containing Menaquinol NO Reductase from Bacillus azotoformans  

E-Print Network [OSTI]

A Novel Copper A Containing Menaquinol NO Reductase from Bacillus azotoformans Suharti, Marc J. F of one non-heme iron, two copper atoms and of two b-type hemes per enzyme complex. Heme c was absent features of this enzyme that distinguish it from other NO reductases. First, the enzyme contains copper

Schroeder, Imke

294

U-Broad Project To Develop Advanced Access Technologies Over Copper  

E-Print Network [OSTI]

U-Broad Project To Develop Advanced Access Technologies Over Copper Project Aims to Quadruple Total Bandwidth Available to the End User Using Legacy Copper Metalink Ltd., a global provider and developer in January 2004. The project's focus is on ultra high bit rate-over-copper technologies for broadband multi

Leshem, Amir

295

A novel copper-regulated promoter system for expression of heterologous proteins in Schizosaccharomyces pombe  

E-Print Network [OSTI]

A novel copper-regulated promoter system for expression of heterologous proteins the promoter of the ctr41 copper transporter gene from S. pombe, we created a series of vectors, named pctr41 -X, which regulate the expression of heterologous genes as a function of copper availability

Labbé, Simon

296

COPPER-UPTAKE KINETICS OF COASTAL AND OCEANIC DIATOMS1 , Amber L. Annett3  

E-Print Network [OSTI]

COPPER-UPTAKE KINETICS OF COASTAL AND OCEANIC DIATOMS1 Jian Guo2 , Amber L. Annett3 , Rebecca L We investigated copper (Cu) acquisition mecha- nisms and uptake kinetics of the marine diatoms organic Cu complexes. Key index words: copper; Cu; diatom; Fe; iron; kinetics; Thalassiosira; transport

297

Traveling Fronts of Copper Deposition Stephanie Thouvenel-Romans, Konstantin Agladze, and Oliver Steinbock*  

E-Print Network [OSTI]

Traveling Fronts of Copper Deposition Stephanie Thouvenel-Romans, Konstantin Agladze, and Oliver for propagating fronts that mediate the electroless deposition of copper on passivated steel. Under ap- propriate is essentially independent from the copper(II) concentration in the electrolyte, which indicates

Steinbock, Oliver

298

EFFECT of GROUND COPPER SLAG on the STRENGTH, and TOUGHNESS of CEMENTITIOUS MIXTURES  

E-Print Network [OSTI]

1 EFFECT of GROUND COPPER SLAG on the STRENGTH, and TOUGHNESS of CEMENTITIOUS MIXTURES A.M. Ariño1 , and B. Mobasher2 Abstract The effect of ground copper slag (GCS) on the strength and fracture of cement-based materials is studied. Up to 15% by mass of ground copper slag was used as a portland cement replacement

Mobasher, Barzin

299

Use of Copper in Marine Aquaculture and Aquarium Roy P. E. Yanong2  

E-Print Network [OSTI]

FA165 Use of Copper in Marine Aquaculture and Aquarium Systems1 Roy P. E. Yanong2 1. This document T. Place , Dean Introduction Copper has been used effectively for many years to control algae and fish parasites in freshwater and marine systems. Because copper does not discolor the water

Watson, Craig A.

300

Copper crystals on the (1120) sapphire plane: orientation relationships, triple line ridges and interface shape equilibrium  

E-Print Network [OSTI]

Copper crystals on the (1120) sapphire plane: orientation relationships, triple line ridges The orientation relationships (ORs) of copper crystals on a Ă°1120Ă? sapphire substrate equilibrated at 1253 K are presented. They barely depend on the proce- dures used in sample preparation, i.e. dewetting of a copper

Rohrer, Gregory S.

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

1. Introduction Copper, along with iron active sites dominate the field of  

E-Print Network [OSTI]

#12;1. Introduction Copper, along with iron active sites dominate the field of biological oxygen chemistry[1] and play important roles in homogeneous[2] and heterogeneous catalysis.[3, 4] Copper pro- teins heme ± iron centers).[8] The known copper proteins which are involved in dioxygen binding, activation

Chen, Peng

302

Copper CMP Planarization Length -MRS 2001 -April 19th , 2001 Paul Lefevre Page 1  

E-Print Network [OSTI]

Copper CMP Planarization Length - MRS 2001 - April 19th , 2001 ­ Paul Lefevre ­ Page 1 DIRECT MEASUREMENT OF PLANARIZATION LENGTH FOR COPPER CHEMICAL MECHANICAL POLISHING (CMP) PROCESSES USING A LARGE; Michael Gostein, Philips Analytical, Natick, MA; John Nguyen, SpeedFam-IPEC, Phoenix, AZ. #12;Copper CMP

Boning, Duane S.

303

Mitochondrial matrix copper complex used in metallation of cytochrome oxidase and superoxide dismutase  

E-Print Network [OSTI]

1 Mitochondrial matrix copper complex used in metallation of cytochrome oxidase and superoxide title: Mitochondrial copper transport * Address correspondence to: Dennis Winge, University of Utah.winge@hsc.utah.edu A mitochondrial matrix copper ligand (CuL) complex, conserved in mammalian cells, is shown for the first time

Paris-Sud XI, Université de

304

Copper dissolution in bromide medium in the absence and presence of hexamethylenetetramine (HMTA)  

E-Print Network [OSTI]

Copper dissolution in bromide medium in the absence and presence of hexamethylenetetramine (HMTA) A of copper in bromide medium, in the absence and presence of hexamethylenetetramine (HMTA), has been studied, using electrochemical and spectroelectrochemical techniques. The copper dissolution in the absence

Brolo, Alexandre G.

305

Structure and motion of junctions between coherent and incoherent twin boundaries in copper  

E-Print Network [OSTI]

Structure and motion of junctions between coherent and incoherent twin boundaries in copper J online 4 July 2009 Abstract The atomic mechanisms of twin boundary migration in copper under externally. Ă? 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. Keywords: Copper

Ghoniem, Nasr M.

306

Copper clusters built on bulky amidinate ligands: spin delocalization via superexchange rather than direct metalmetal bonding{  

E-Print Network [OSTI]

Copper clusters built on bulky amidinate ligands: spin delocalization via superexchange rather than metal­metal interaction is a prerequisite for spin delocalization in copper dimers that lack single tetra- and dicopper amidinate complexes. A copper(I) dimer having two- coordinate metal centers

Baik, Mu-Hyun

307

Control of surface gravity waves by variable fluid injection in a model of a copper  

E-Print Network [OSTI]

Control of surface gravity waves by variable fluid injection in a model of a copper converter splashing appears in copper converters when air is injected into the molten matte in order to carry out to the opposite extreme to where the nozzle injection is placed. Key words: Copper converter, gravity waves

Osses, Axel

308

Heteroleptic diimine copper (I) complexes with large extinction coefficients: synthesis, quantum chemistry calculations and physico-  

E-Print Network [OSTI]

1 Heteroleptic diimine copper (I) complexes with large extinction coefficients: synthesis, quantum. . Abstract Using the HETPHEN approach, five new heteroleptic copper(I) complexes composed of a push-pull 4 complexes experimentally demonstrate that large light harvesting properties with bis-diimine copper

Paris-Sud XI, Université de

309

OVERVIEW OF METHODS FOR CHARACTERIZATION OF PATTERN DEPENDENCIES IN COPPER CMP  

E-Print Network [OSTI]

OVERVIEW OF METHODS FOR CHARACTERIZATION OF PATTERN DEPENDENCIES IN COPPER CMP Tae Park, Tamba: (617) 253-0728, Fax: (617) 258-7393, E-mail: taepark@mtl.mit.edu ABSTRACT Copper CMP suffers from well" related to as-deposited copper pattern density, a "transi- tion length" on the order of 100 µm over which

Boning, Duane S.

310

The FAST Copper Project: Fundamental Research in Fiber/DSL Broadband Access  

E-Print Network [OSTI]

1 The FAST Copper Project: Fundamental Research in Fiber/DSL Broadband Access Yung Yi, Dahai Xu Abstract This is an overview of the ongoing FAST Copper project, which aims at at substantial improvements in rate, reach, reliability, and quality in copper-last-mile broadband access through fiber/DSL deployment

Yi, Yung

311

Human SCO1 and SCO2 have independent, cooperative functions in copper delivery  

E-Print Network [OSTI]

Human SCO1 and SCO2 have independent, cooperative functions in copper delivery to cytochrome c understood, roles in copper delivery to cytochrome c oxidase (COX). Mutations in these genes pro- duce tissue copper delivery pathway in SCO1 and SCO2 patient backgrounds. Immunoblot analysis of patient cell lines

Shoubridge, Eric

312

Corrosion Behavior of Copper Thin Films in Organic HF-Containing Cleaning Solution for Semiconductor Applications  

SciTech Connect (OSTI)

The corrosion behavior of electrochemically deposited copper thin films in deaerated and non-deaerated commercial cleaning solutions containing HF was investigated. Potentiodynamic polarization experiments were carried out to determine active, active-passive, passive, and transpassive regions. Corrosion rates were calculated from Tafel slopes. The addition of hydrogen peroxide to the solution and its influence on corrosion was also investigated by employing inductively coupled plasma-mass spectroscopy (ICP-MS) and X-ray photoelectron spectroscopy (XPS). The ICP-MS and potentiodynamic methods yielded comparable Cu dissolution rates. Surface analysis using atomic force microscopy and scanning electron microscopy, performed before and after the cleaning solution treatment, did not reveal any indication of pitting corrosion. The presence of hydrogen peroxide in the cleaning solution led to more than an order of magnitude suppression of copper dissolution rate. We ascribe this phenomenon to the formation of interfacial CuO detected by XPS on the wafer surface that dissolves at a slower rate in dilute HF.

Nabil G. Mistkawi,a,b Makarem A. Hussein,b Malgorzata Ziomek-Moroz,c and

2009-11-13T23:59:59.000Z

313

Determine Minimum Silver Flake Addition to GCM for Iodine Loaded AgZ  

SciTech Connect (OSTI)

The minimum amount of silver flake required to prevent loss of I{sub 2} during sintering in air for a SNL Glass Composite Material (GCM) Waste Form containing AgI-MOR (ORNL, 8.7 wt%) was determined to be 1.1 wt% Ag. The final GCM composition prior to sintering was 20 wt% AgI-MOR, 1.1 wt% Ag, and 80 wt% Bi-Si oxide glass. The amount of silver flake needed to suppress iodine loss was determined using thermo gravimetric analysis with mass spectroscopic off-gas analysis. These studies found that the ratio of silver to AgI-MOR required is lower in the presence of the glass than without it. Therefore an additional benefit of the GCM is that it serves to inhibit some iodine loss during processing. Alternatively, heating the AgI-MOR in inert atmosphere instead of air allowed for densified GCM formation without I{sub 2} loss, and no necessity for the addition of Ag. The cause of this behavior is found to be related to the oxidation of the metallic Ag to Ag{sup +} when heated to above ~300{degrees}C in air. Heating rate, iodine loading levels and atmosphere are the important variables that determine AgI migration and results suggest that AgI may be completely incorporated into the mordenite structure by the 550{degrees}C sintering temperature.

Terry J. Garino; Tina M. Nenoff; Mark A. Rodriguez

2014-04-01T23:59:59.000Z

314

(Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: Domestic mine production of copper in 2010 declined by about 5% to 1.12 million  

E-Print Network [OSTI]

48 COPPER (Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: Domestic mine production of copper in 2010 declined by about 5% to 1.12 million tons--Arizona, Utah, Nevada, New Mexico, and Montana--accounted for more than 99% of domestic production; copper also

315

(Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2012 increased by 4% to about 1.15 million tons,  

E-Print Network [OSTI]

48 COPPER (Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2012 increased by 4% to about 1.15 million tons of production--accounted for more than 99% of domestic mine production; copper also was recovered in Alaska

316

(Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2011 increased slightly to about 1.1 million tons  

E-Print Network [OSTI]

48 COPPER (Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2011 increased slightly to about 1.1 million tons order of production--accounted for more than 99% of domestic mine production; copper also was recovered

317

(Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2013 increased by 4% to about 1.22 million tons,  

E-Print Network [OSTI]

48 COPPER (Data in thousand metric tons of copper content unless otherwise noted) Domestic Production and Use: U.S. mine production of copper in 2013 increased by 4% to about 1.22 million tons of production--accounted for more than 99% of domestic mine production; copper also was recovered in Idaho

318

The investigation of die-pressing and sintering behavior of ITP CP-Ti and Ti-6Al-4V powders  

SciTech Connect (OSTI)

This paper investigated the die-pressing and sintering behavior of the low-cost CP-Ti and Ti-6Al- 4V powders made by the Armstrong Process . The Armstrong powders have an irregular coral like, dendritic morphology, with a dendrite size of approximately 2-5 m. As-received as well as milled powders were uniaxially pressed at designated pressures up to 690 MPa to form disk samples with different aspect ratios. In the studied pressure range, an empirical powder compaction equation was applied to linearize the green density pressure relationship, and powder compaction parameters were obtained. The Armstrong Ti-64 powder exhibited a significantly higher sinterability than the CP-Ti powder. This was explained to be due to the higher diffusivity of V at the sintering temperature. The Ti-64 samples with a green density of 71.0% increased to 99.6% after sintering at 1300oC for 1 hour. An ex-situ technique was used to track the powder morphology change before and after sintering.

Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Peter, William H [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Muth, Thomas R [ORNL; Blue, Craig A [ORNL; Williams, James C [Ohio State University; Fuller, Brian [International Titanium Powder; Akhtar, Kamal [International Titanium Powder

2012-01-01T23:59:59.000Z

319

Nanotube Boiler 1 Abstract--Controlled copper evaporation at attogram  

E-Print Network [OSTI]

Nanotube Boiler 1 Abstract-- Controlled copper evaporation at attogram level from individual carbon nanotube (CNT) vessels, which we call nanotube boilers, is investigated experimentally, and ionization in these CNT boilers, which can serve as sources for mass transport and deposition in nanofluidic

Paris-Sud XI, Université de

320

Spectroscopy of selected copper group minerals: ktenasite, orthoserpierite and kipushite  

Science Journals Connector (OSTI)

Orthoserpierite, Ca(Cu,Zn)4(SO4)2(OH)6·3H2O, a calcium copper sulphate hydroxide hydrate mineral, occurs as bright blue-green prismatic crystals commonly associated with aurichalcite and friedelite [11]. A review...

Ray L. Frost; B. Jagannadha Reddy; Eloise C. Keeffe

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

THE USE OF COPPER IN THE PURIFICATION OF WATER SUPPLIES  

Science Journals Connector (OSTI)

...or the amount of copper used to destroy algea and bacteria in the laboratory, is considerably...bodies of water is in the use of keros:ene oil. This, however, has the objection of...in small amounts for the destruction of algea, and for removing the offensive odor and...

George T. Moore; Henry Kraemer; Mary E. Pennington; Alfred M. Quick; C. L. Marlatt; H. W. Wiley; M. O. Leighton; A. H. Doty

1905-04-21T23:59:59.000Z

322

Copper oxide/N-silicon heterojunction photovoltaic device  

DOE Patents [OSTI]

A photovoltaic device having characteristics of a high efficiency solar cell comprising a Cu.sub.x O/n-Si heterojunction. The Cu.sub.x O layer is formed by heating a deposited copper layer in an oxygen containing ambient.

Feng, Tom (Morris Plains, NJ); Ghosh, Amal K. (New Providence, NJ)

1982-01-01T23:59:59.000Z

323

Method for extracting copper, silver and related metals  

DOE Patents [OSTI]

A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

Moyer, B.A.; McDowell, W.J.

1987-10-23T23:59:59.000Z

324

Effects of cryogenic equal channel angular deformation on copper 101  

E-Print Network [OSTI]

show an increase in strength due to a larger grain boundary surface area per unit volume. One way to obtain fine grained microstructures is through cold working and recrystallization of the material. In this study, oxygen-free high-conductivity copper...

Horan, Christopher Sean

2001-01-01T23:59:59.000Z

325

Fracture toughness and fatigue crack growth characteristics of nanotwinned copper  

E-Print Network [OSTI]

fracture and subcritical fatigue crack growth life. Possible mechanistic origins of these trends and the resistance to stable subcritical crack growth under mono- tonic and cyclic loading, especially at lowerFracture toughness and fatigue crack growth characteristics of nanotwinned copper A. Singh a,1 , L

Suresh, Subra

326

COPPER--2003 21.1 By Daniel L. Edelstein  

E-Print Network [OSTI]

. facilities operated in the United States. The three fire refineries processed scrap to recover unalloyed copper products; one of the refineries operated for only a portion of the year. Scrap was also consumed closed in October 2001. Smelter capacity remained unchanged at about 900,000 t, while refinery capacity

327

COPPER--2002 22.1 By Daniel L. Edelstein  

E-Print Network [OSTI]

place in world smelter and third place in refinery production. The principal mining States were that operated in the United States, just 12 mines accounted for more than 99% of production. The remaining 10 mines were either small leach operations or producers of byproduct copper. During the year, 3 primary

328

Inertia welding for assembly of copper squirrel cages for electric motors  

Science Journals Connector (OSTI)

Abstract The automotive industry is developing designs and manufacturing processes for new generations of electric motors intended for use in hybrid and electric vehicles. There is interest in replacing the aluminum traditionally used in induction motor rotors with copper to improve motor capability. This paper focuses on solid-state welding to join copper end rings to copper spokes in the fabrication of copper rotors. Inertia friction welding was explored to examine weldability of these copper components. A better understanding of inertia welding characteristics will help the advancements in its application for induction rotors. The limitations of this application are discussed.

John S. Agapiou

2014-01-01T23:59:59.000Z

329

Electron microprobe and X-ray microfluorescence analyses of copper binding to active and inactivated cells of Mucor rouxii  

SciTech Connect (OSTI)

Electron microprobe and x-ray microfluorescence spectroscopies have been used to study copper binding to active and inactivated Mucor rouxii copper-sensitive and copper-tolerant cells. A better understanding of metal resistance may help in the application of fungal biomass for the treatment of metal-contaminated water, and also in enrichment or recycling of valuable metals. After repeated culturing in progressively higher concentrations of copper sulfate, a copper-tolerant Mucor rouxii strain was obtained. The copper-tolerant strain differed from the sensitive parental strain in both shape and size. Copper binding studies using a laboratory batch technique revealed that the copper-tolerant strain cultured at higher copper levels bound large amounts of this metal. Electron microprobe and x-ray microfluorescence analyses showed that the copper characteristic x-ray signal on the cell surface of the copper-tolerant strain after copper binding was higher than the copper signal in sensitive cells. The copper signal in cross sections of the copper-tolerant cells also showed a statistically significant correlation with the sulfur signal but no correlation with the phosphorus signal. These results suggest that there are several mechanisms for metal detoxification inside and outside of the Mucor rouxii cells and that copper may be binding to sulfur-containing groups.

Cano-Aguilera, I.; Gardea-Torresdey, J.L.; Pingitore, N.E. Jr.; Webb, R. [Univ. of Texas, El Paso, TX (United States)

1997-12-31T23:59:59.000Z

330

Structurally Diverse Copper(II) Complexes of Polyaza Ligands Containing 1,2,3-Triazoles: Site Selectivity and Magnetic Properties  

E-Print Network [OSTI]

Structurally Diverse Copper(II) Complexes of Polyaza Ligands Containing 1,2,3-Triazoles: Site, Florida 32306-4390, United States *S Supporting Information ABSTRACT: Copper(II) acetate mediated coupling, was observed in the copper(II) complexes of L1 -L6 . The preference of copper(II) to two common bidentate 1

Weston, Ken

331

Two Chlamydomonas CTR Copper Transporters with a Novel Cys-Met Motif Are Localized to the Plasma Membrane and  

E-Print Network [OSTI]

Two Chlamydomonas CTR Copper Transporters with a Novel Cys-Met Motif Are Localized to the Plasma Membrane and Function in Copper Assimilation W M. Dudley Page, Janette Kropat, Patrice P. Hamel,1, California 90095-1569 Inducible high-affinity copper uptake is key to copper homeostasis in Chlamydomonas

Meier, Iris

332

IEEE TRANSACTIONS ON SEMICONDUCTOR MANUFACTURING, VOL. 18, NO. 2, MAY 2005 297 Dishing-Radius Model of Copper CMP  

E-Print Network [OSTI]

of Copper CMP Dishing Effects Runzi Chang, Member, IEEE, and Costas J. Spanos, Fellow, IEEE Abstract--Copper, a metric that assumes cylin- drically shaped post-CMP copper surface and directly captures the extent the interlayer dielectric (ILD) and metal surface. It has been the enabling technology for the copper damascene

California at Berkeley, University of

333

Alternatives to Copper Paint as Herbivore Deterrents Dena M. Leerberg1, Kristin M. Aquilino2, and Gary N. Cherr3  

E-Print Network [OSTI]

Alternatives to Copper Paint as Herbivore Deterrents Dena M. Leerberg1, Kristin M. Aquilino2 of deterrents, with copper coil being the most effective at preventing herbivore movement (ANOVA, p .05). ·DGT analysis revealed copper paint to leach the highest amount of copper. Elevated zinc was detected

Schladow, S. Geoffrey

334

Copper contamination effects on hydrogen-air combustion under SCRAMJET (supersonic combustion ramjet) testing conditions  

SciTech Connect (OSTI)

Two forms of copper catalytic reactions (homogeneous and heterogeneous) in hydrogen flames were found in a literature survey. Hydrogen atoms in flames recombine into hydrogen molecules through catalytic reactions, and these reactions which affect the timing of the combustion process. Simulations of hydrogen flames with copper contamination were conducted by using a modified general chemical kinetics program (GCKP). Results show that reaction times of hydrogen flames are shortened by copper catalytic reactions, but ignition times are relatively insensitive to the reactions. The reduction of reaction time depends on the copper concentration, copper phase, particle size (if copper is in the condensed phase), and initial temperature and pressure. The higher the copper concentration of the smaller the particle, the larger the reduction in reaction time. For a supersonic hydrogen flame (Mach number = 4.4) contaminated with 200 ppm of gaseous copper species, the calculated reaction times are reduced by about 9%. Similar reductions in reaction time are also computed for heterogeneous copper contamination. Under scramjet testing conditions, the change of combustion timing appears to be tolerable (less than 5%) if the Mach number is lower than 3 or the copper contamination is less than 100 ppm. The higher rate the Mach number, the longer the reaction time and the larger the copper catalytic effects. 7 tabs., 8 figs., 34 refs.

Chang, S.L.; Lottes, S.A.; Berry, G.F.

1990-01-01T23:59:59.000Z

335

Process for removing copper in a recoverable form from solid scrap metal  

DOE Patents [OSTI]

A process for removing copper in a recoverable form from a copper/solid ferrous scrap metal mix is disclosed. The process begins by placing a copper/solid ferrous scrap metal mix into a reactor vessel. The atmosphere within the reactor vessel is purged with an inert gas or oxidizing while the reactor vessel is heated in the area of the copper/solid ferrous scrap metal mix to raise the temperature within the reactor vessel to a selected elevated temperature. Air is introduced into the reactor vessel and thereafter hydrogen chloride is introduced into the reactor vessel to obtain a desired air-hydrogen chloride mix. The air-hydrogen chloride mix is operable to form an oxidizing and chloridizing atmosphere which provides a protective oxide coating on the surface of the solid ferrous scrap metal in the mix and simultaneously oxidizes/chloridizes the copper in the mix to convert the copper to a copper monochloride gas for transport away from the solid ferrous scrap metal. After the copper is completely removed from the copper/solid ferrous scrap metal mix, the flows of air and hydrogen chloride are stopped and the copper monochloride gas is collected for conversion to a recoverable copper species.

Hartman, Alan D. (Albany, OR); Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR)

1995-01-01T23:59:59.000Z

336

Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper/Niobium/Copper Interlayers  

E-Print Network [OSTI]

Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper and Engineering, University of California, Berkeley, California 94720 Interfacial fracture toughness and cyclic temperatures, and assessed in terms of interfacial chemistry and microstructure. The mean interfacial fracture

Ritchie, Robert

337

Cardiac catecholamines in rats fed copper deficient or copper adequate diets containing fructose or starch  

SciTech Connect (OSTI)

The symptoms of copper (Cu) deficiency are known to be more severe when rats are fed a diet with fructose (F) as the principal carbohydrate. Mortality, in males, due to cardiac abnormalities usually occurs after five weeks of a 62% F, 0.6 ppm Cu deficient diet. These effects are not observed if cornstarch (CS) is the carbohydrate (CHO) source. Studies with F containing diets have shown increased catecholamine (C) turnover rates while diets deficient in Cu result in decreased norepinephrine (N) levels in tissues. Dopamine B-hydroxylase (EC 1.14.17.1) is a Cu dependent enzyme which catalyzes the conversion of dopamine (D) to N. An experiment was designed to investigate the effects of CHO and dietary Cu on levels of three C in cardiac tissue. Thirty-two male and female Sprague-Dawley rats were fed Cu deficient or adequate diets with 60% of calories from F or CS for 6 weeks. N, epinephrine (E) and D were measured by HPLC. Statistical analysis indicates that Cu deficiency tends to decrease N levels, while having the reverse effect on E. D did not appear to change. These findings indicate that Cu deficiency but not dietary CHO can affect the concentration of N and E in rat cardiac tissue.

Scholfield, D.J.; Fields, M.; Beal, T.; Lewis, C.G.; Behall, K.M. (Dept. og Agriculture, Beltsville, MD (USA))

1989-02-09T23:59:59.000Z

338

CX-004456: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

456: Categorical Exclusion Determination 456: Categorical Exclusion Determination CX-004456: Categorical Exclusion Determination Boysen-Copper Mountain Structure 98/1 Replacement Project, Fremont County, Wyoming CX(s) Applied: B1.3, B4.6 Date: 11/10/2010 Location(s): Fremont County, Wyoming Office(s): Western Area Power Administration-Rocky Mountain Region Western proposes to replace Structure 98/1 and conduct access road maintenance on Western's existing Boysen-Copper Mountain 115 kilovolt transmission line in Fremont County, Wyoming. Structure 98/1 is located on United States (US) Bureau of Reclamation land in the southeast 1/4 of Section 16, T. 5 north, R. 6 east, of the Wind River meridian, Wyoming near the Boysen State Park Headquarters. A cleared, level area (landing) will be constructed around the base of structure 98/1 for better equipment

339

CX-004886: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

86: Categorical Exclusion Determination 86: Categorical Exclusion Determination CX-004886: Categorical Exclusion Determination Copper Indium Gallium Sulfur-Selenide (CIGSS) Manufacturing Plant CX(s) Applied: B1.31 Date: 01/05/2011 Location(s): San Jose, California Office(s): Loan Guarantee Program Office The Department of Energy's proposed action is to issue a loan guarantee to Stion Corporation to retrofit Stion's solar panel manufacturing plant at 6321 San Ignacio Avenue in San Jose, California and expand into an adjacent building at 6331 San Ignacio Avenue in order to establish a 135 megawatt nameplate capacity manufacturing plant. Stion produces monolithically integrated thin film photovoltaic modules using single-junction Copper Indium Gallium Sulfur-Selenide (CIGSS) absorbers. DOCUMENT(S) AVAILABLE FOR DOWNLOAD

340

CX-002662: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

662: Categorical Exclusion Determination 662: Categorical Exclusion Determination CX-002662: Categorical Exclusion Determination Installation and Operation of Majorana Underground Electro-forming Research Project CX(s) Applied: B3.6 Date: 05/11/2010 Location(s): Lead, South Dakota Office(s): Oak Ridge Office, Science The Department of Energy Oak Ridge Office (DOE-ORO) proposes to perform research on electro-forming of copper parts that will be installed in ultra-low, background level, radiation detection instruments. This action is part of the Majorana Demonstrator (MJD) Research and Development Project, which is funded by the Department of Energy Office of Nuclear Physics. Electro-forming of the copper parts would take place in an underground lab, the Sanford Underground Laboratory, in Lead, South Dakota,

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
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341

Initial increase, ''peaking effect'', in the internal friction of copper following pulsed neutron and electron irradiation  

SciTech Connect (OSTI)

Under certain experimental conditions the internal friction in metals can first increase and following prolonged irradiation decrease. Many models have been proposed to account for this ''peaking effect''; however, in many of the cases, no effort is made to distinguish between the influence of interstitials and/or vacancies. To determine the nature of the point defect responsible for the peaking effect in high purity copper, we have performed a series of pulsed irradiations using neutrons and electrons. In all of the experiments an initial very rapid rise in the internal friction and Young's modulus was observed. These data show that a fast diffusing defect is responsible for the peaking effect: i.e. the interstitial.

Simpson, H.M.; Parkin, D.M.; Goldstone, J.A.; Hemsky, J.W.

1985-01-01T23:59:59.000Z

342

BIOMONITORING OF HEAVY METAL POLLUTION NEAR COPPER SMELTER IN BOR (SERBIA) USING ACACIA  

E-Print Network [OSTI]

The correlations between sampling sites situated in the close vicinity of copper smelter (Bor, Serbia) based on heavy metal (Pb, Cu, Zn) content in plant parts and soil of acacia (Robinia pseudoacacia L.) were determined. Very strong correlations (R 2>0.9) were observed between the sites Town park and Hospital in the urban-industiral zone due to high air pollution in this sampling area. The performed cluster analysis confirmed these results by grouping the sites with high metal content in plant and soil material of Robinia pseudoacacia into the same clusters. Also, strong correlations were noted between less polluted sampling sites (Bor lake and Brestovac spa) with the control site (Sumrakovac).

Ana A. Ilic; Snezana M. Serbula; Jelena V. Kalinovic; Tanja S. Kalinovic

343

Neutron energy spectrum from 120 GeV protons on a thick copper target  

E-Print Network [OSTI]

Neutron energy spectrum from 120 GeV protons on a thick copper target was measured at the Meson Test Beam Facility (MTBF) at Fermi National Accelerator Laboratory. The data allows for evaluation of neutron production process implemented in theoretical simulation codes. It also helps exploring the reasons for some disagreement between calculation results and shielding benchmark data taken at high energy accelerator facilities, since it is evaluated separately from neutron transport. The experiment was carried out using a 120 GeV proton beam of 3E5 protons/spill. Since the spill duration was 4 seconds, proton-induced events were counted pulse by pulse. The intensity was maintained using diffusers and collimators installed in the beam line to MTBF. The protons hit a copper block target the size of which is 5cm x 5cm x 60 cm long. The neutrons produced in the target were measured using NE213 liquid scintillator detectors, placed about 5.5 m away from the target at 30^{\\circ} and 5 m 90^{\\circ} with respect to the proton beam axis. The neutron energy was determined by time-of-flight technique using timing difference between the NE213 and a plastic scintillator located just before the target. Neutron detection efficiency of NE213 was determined on basis of experimental data from the high energy neutron beam line at Los Alamos National Laboratory. The neutron spectrum was compared with the results of multi-particle transport codes to validate the implemented theoretical models. The apparatus would be applied to future measurements to obtain a systematic data set for secondary particle production on various target materials.

Nobuhiro Shigyo; Toshiya Sanami; Tsuyoshi Kajimoto; Yosuke Iwamoto; Masayuki Hagiwara; Kiwamu Saito; Kenji Ishibashi; Hiroshi Nakashima; Yukio Sakamoto; Hee-Seock Lee; Erik Ramberg; Aria A. Meyhoefer; Rick Coleman; Doug Jensen; Anthony F. Leveling; David J. Boehnlein; Nikolai V. Mokhov

2012-02-07T23:59:59.000Z

344

Association of Copper to Riboflavin Binding Protein; Characterization by EPR and XAS  

SciTech Connect (OSTI)

The association of copper to Riboflavin Binding Protein (RBP) from egg white has been studied by electron paramagnetic resonance (EPR) and X-ray absorption (XAS) spectroscopies. The type II site contains a mix of copper I and II in an oxygen rich environment. The association of copper to Riboflavin Binding Protein (RBP) from egg white has been studied by electron paramagnetic resonance (EPR) and X-ray absorption (XAS) spectroscopies in order to provide insight into how this essential protein may transport and store copper in avian embryos. Riboflavin Binding Protein, RBP, purified from avian egg white, has been shown to bind copper in a 1:1 molar ratio when dialyzed against copper(II) [1]. While the egg is a unique environment and quite rich in copper, the mechanisms by which this copper is delivered during development and stored for eventual use remain unclear [2]. Since RBP is already identified in the active transport of the cofactor riboflavin to the egg, evidence of its copper binding ability may suggest an additional role for RBP in the transport and storage of copper.

Smith,S.; Bencze, K.; Wasiukanis, K.; Stemmler, T.; Benore-Parsons, M.

2008-01-01T23:59:59.000Z

345

Two Chlamydomonas CTR Copper Transporters with a Novel Cys-Met Motif Are Localized to the Plasma Membrane and Function in Copper Assimilation  

Science Journals Connector (OSTI)

...is as expected, since copper uptake in excess of requirements would be deleterious for...effluxer that is required in a situation of excess copper to maintain homeostasis. There...Zhou and Gitschier, 1997) using the lithium acetate method (Gietz and Schiestl...

M. Dudley Page; Janette Kropat; Patrice P. Hamel; Sabeeha S. Merchant

2009-03-24T23:59:59.000Z

346

Methods of making copper selenium precursor compositions with a targeted copper selenide content and precursor compositions and thin films resulting therefrom  

DOE Patents [OSTI]

Precursor compositions containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semi-conductor applications. Methods of forming the precursor compositions using primary amine solvents and methods of forming the thin films wherein the selection of temperature and duration of heating controls the formation of a targeted species of copper selenide.

Curtis, Calvin J. (Lakewood, CO); Miedaner, Alexander (Boulder, CO); van Hest, Marinus Franciscus Antonius Maria (Lakewood, CO); Ginley, David S. (Evergreen, CO); Leisch, Jennifer (Denver, CO); Taylor, Matthew (West Simsbury, CT); Stanbery, Billy J. (Austin, TX)

2011-09-20T23:59:59.000Z

347

NOTES AND COMMENTS REVERE COPPER AR! BRASS DETROIT, MICHIGAN  

Office of Legacy Management (LM)

* .t-* * .t-* . * * - -. _ _ ,.. .I AIT. 4 NOTES AND COMMENTS REVERE COPPER AR! BRASS DETROIT, MICHIGAN A preliminary (screening) survey was conducted in several areas of the Revere Copper and Brass Facility, 5851 W. Jefferson Street, Detroit, Michigan. The survey was conducted by the ANL Radiological Survey Group on April 22, 1981. The Survey Group, consisting of W. Smith, R. Mundis, K. Flynn (all of ANI), and E. Jascewsky (DOE-CH) met on site with J. Evans (Safety Engineer), D. Tratt (Asst. Engineer), -- M~37~se'Zanak~(Aeth6ds~De!@iFXi%itXiupe~isox$ and E. Betancourt (Personnel Manager) to discuss what information was available concerning the operations that transpired at the facility during the Manhattan Engineering District Atomic Energy Commission (MED/AEC) era. MrYWtisffaliab indicated that

348

Emf measurements on nanocrystalline copper-doped ceria  

SciTech Connect (OSTI)

Mixed oxide samples of nanostructured Cu{sub x}Ce{sub 1{minus}x}O{sub 2{minus}y} of various composition were generated by (i) chemical precipitation and ball milling and (ii) inert gas condensation. X-ray diffraction measurements suggested that copper oxide was dissolved in nanostructured cerium oxide up to concentrations of x = 0.15. Solid electrolyte cells of the type A, Cu{sub 2}O/CuBr/Cu{sub x}Ce{sub 1{minus}x}O{sub 2{minus}y} (A = Cu or CuO) showed reversible cell voltages. The ratio of the formal chemical activities of CuO and Cu{sub 2}O dissolved in nanostructured cerium oxide were calculated from the cell voltages. The results are discussed in terms of an apparent macroscopic solubility, due to interfacial segregation of copper oxide on nanostructured cerium oxide.

Knauth, P.; Villain, S. [Faculte des Sciences de Marseille-St. Jerome, Marseille (France). Lab. de Metallurgie EDIFIS] [Faculte des Sciences de Marseille-St. Jerome, Marseille (France). Lab. de Metallurgie EDIFIS; Schwitzgebel, G.; Tschoepe, A. [Univ. des Saarlandes, Saarbruecken (Germany)] [Univ. des Saarlandes, Saarbruecken (Germany)

1998-11-01T23:59:59.000Z

349

Preparation Of Copper Indium Gallium Diselenide Films For Solar Cells  

DOE Patents [OSTI]

High quality thin films of copper-indium-gallium-diselenide useful in the production of solar cells are prepared by electrodepositing at least one of the constituent metals onto a glass/Mo substrate, followed by physical vapor deposition of copper and selenium or indium and selenium to adjust the final stoichiometry of the thin film to approximately Cu(In,Ga)Se.sub.2. Using an AC voltage of 1-100 KHz in combination with a DC voltage for electrodeposition improves the morphology and growth rate of the deposited thin film. An electrodeposition solution comprising at least in part an organic solvent may be used in conjunction with an increased cathodic potential to increase the gallium content of the electrodeposited thin film.

Bhattacharya, Raghu N. (Littleton, CO); Contreras, Miguel A. (Golden, CO); Keane, James (Lakewood, CO); Tennant, Andrew L. (Denver, CO), Tuttle, John R. (Denver, CO); Ramanathan, Kannan (Lakewood, CO); Noufi, Rommel (Golden, CO)

1998-08-08T23:59:59.000Z

350

Copper-assisted, anti-reflection etching of silicon surfaces  

DOE Patents [OSTI]

A method (300) for etching a silicon surface (116) to reduce reflectivity. The method (300) includes electroless deposition of copper nanoparticles about 20 nanometers in size on the silicon surface (116), with a particle-to-particle spacing of 3 to 8 nanometers. The method (300) includes positioning (310) the substrate (112) with a silicon surface (116) into a vessel (122). The vessel (122) is filled (340) with a volume of an etching solution (124) so as to cover the silicon surface (116). The etching solution (124) includes an oxidant-etchant solution (146), e.g., an aqueous solution of hydrofluoric acid and hydrogen peroxide. The silicon surface (116) is etched (350) by agitating the etching solution (124) with, for example, ultrasonic agitation, and the etching may include heating (360) the etching solution (124) and directing light (365) onto the silicon surface (116). During the etching, copper nanoparticles enhance or drive the etching process.

Toor, Fatima; Branz, Howard

2014-08-26T23:59:59.000Z

351

Nanophase copper ferrite using an organic gelation technique  

SciTech Connect (OSTI)

Nanocrystalline copper ferrite (Cu{sub 0.5}Fe{sub 2.5}O{sub 4}) was synthesized using a forward strike gelation method with polyacrylic acid (PAA) as a gelating agent. The dried gel was calcined at a low temperature of 400 C to get the final powder. The effect of pH and the ratio of the cation to the carboxylic group in the initial gel were studied with respect to both the phases and the crystallite size of the final powders synthesized. Phase and crystallite size analysis were done using x-ray diffraction and TEM. Saturation magnetization results were obtained using a SQUID magnetometer. The reactions occurring in the nano-size copper ferrite, in air as a function of temperature, were tracked using a dynamic high temperature x-ray diffraction (HTXRD) system.

Sriram, D.; Amarakoon, V.R.W. [Alfred Univ., NY (United States). NYS Coll. of Ceramics; Snyder, R.L. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1997-09-01T23:59:59.000Z

352

Corrosion and ion release behavior of ultra-fine grained bulk pure copper fabricated by ECAP in Hanks solution as potential biomaterial for contraception  

E-Print Network [OSTI]

Corrosion and ion release behavior of ultra-fine grained bulk pure copper fabricated by ECAP-fine grained copper ECAP Corrosion behavior Ion release Ultra-fine grained (UFG) bulk pure copper has been revealed that the corrosion current of UFG copper ishigherthan that of the coarse grained copper

Zheng, Yufeng

353

Unexpected Copper-Catalyzed Cascade Synthesis of Quinazoline Derivatives  

Science Journals Connector (OSTI)

Unexpected Copper-Catalyzed Cascade Synthesis of Quinazoline Derivatives ... Nitrogen-containing heterocycles are present in a wide variety of bioactive natural products and biological molecules that may be good drug candidates. ... To our surprise, the trace of unexpected 2-phenylquinazoline (3a) was observed by gas chromatography/mass spectrometry (electron ionization) [GC/MS (EI)] analysis during the process of performing the above condensation reaction in the presence of ceric ammonium nitrate (CAN). ...

Zhongyan Chen; Jiuxi Chen; Miaochang Liu; Jinchang Ding; Wenxia Gao; Xiaobo Huang; Huayue Wu

2013-10-17T23:59:59.000Z

354

Determining whether metals nucleate homogeneously on graphite: A case study with copper  

SciTech Connect (OSTI)

We observe that Cu clusters grow on surface terraces of graphite as a result of physical vapor deposition in ultrahigh vacuum. We show that the observation is incompatible with a variety of models incorporating homogeneous nucleation and calculations of atomic-scale energetics. An alternative explanation, ion-mediated heterogeneous nucleation, is proposed and validated, both with theory and experiment. This serves as a case study in identifying when and whether the simple, common observation of metal clusters on carbon-rich surfaces can be interpreted in terms of homogeneous nucleation. We describe a general approach for making system-specific and laboratory-specific predictions.

Appy, David [Ames Laboratory; Lei, Huaping [Ames Laboratory; Han, Yong [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Tringides, Michael C [Ames Laboratory; Shao, Dahai [Ames Laboratory; Kwolek, Emma J [Iowa State University; Evans, J W [Ames Laboratory; Thiel, P A [Ames Laboratory

2014-11-01T23:59:59.000Z

355

CX-008370: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

8370: Categorical Exclusion Determination 8370: Categorical Exclusion Determination CX-008370: Categorical Exclusion Determination Operation of Tube Furnace for Synthesis of Hydrogen Storage Materials CX(s) Applied: B3.6 Date: 03/27/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office To recreate hydrogen storage materials from literature, a tube furnace will be used to form lithium-magnesium-nitride from pelletized powder precursors, lithium nitride (Li3N) and magnesium nitride (Mg3N2). The quartz tube will be heated to up 900 to 1000K while a carrier gas will flow through the tube and discharge to the fume hood. Rev.1 The procedure described above may be extended to the synthesis of other nitrides using the same procedure. The same furnace may also be employed in the sintering

356

Precursors of the copper-zinc oxide methanol synthesis catalysts  

Science Journals Connector (OSTI)

The coprecipitated hydroxycarbonate precursor of the methanol synthesis and shift reaction catalyst based on 30 at.% copper and 70 at.% zinc oxide, which was previously reported to be a mixture of hydrozincite Zn5(CO3)2(OH)6 and rosasite (Cu,Zn)2(CO3)(OH)2 (R. G. Herman, K. Klier, G. W. Simmons, B. P. Finn, J. B. Bulko, and T. P. Kobylinski, J. Catal. 56, 407, 1979) or a single-phase hydrozincite (G. Petrini, F. Montino, A. Bossi, and G. Gaybassi, in “Studies in Surface Science and Catalysis. Preparation of Catalysis III” (G. Poncelet, P. Grange, and P. A. Jacobs, Eds.), Vol. 16, p. 735. Elsevier, The Netherlands, 1983), is herein shown to be a single-phase aurichalcite (Cu0.3Zn0.7)5(CO3)2(OH)6. The orthorhombic B2212 aurichalcite is crystallograpically distinct from the monoclinic \\{C2m\\} hydrozincite, although these two compounds have the same ratio of metal ions to carbonate and hydroxyl anions. Both aurichalcite and hydrozincite are chemically and structurally distinct from the monoclinic \\{P21a\\} rosasite. The earlier erroneous assignments are attributed to the structural similarity of the three hydroxycarbonates in question. An energy-dispersive characteristic X-ray emission analysis of individual particles in the scanning transmission electron microscope reveals a uniform distribution of copper and zinc at the analytical concentration CuZn = 3070. Precursors with less than 30% copper consist of mixtures of aurichalcite and hydrozincite.

P.B. Himelfarb; G.W. Simmons; K. Klier; R.G. Herman

1985-01-01T23:59:59.000Z

357

Structural Dependence of Grain Boundary Resistance in Copper Nanowires  

SciTech Connect (OSTI)

The current choice of the interconnect metal in integrated circuits is copper due to its higher electrical conductivity and improved electromigration reliability in comparison with aluminum. However, with reducing feature sizes, the resistance of copper interconnects (lines) increases dramatically. Greater resistance will result in higher energy use, more heat generation, more failure due to electromigration, and slower switching speeds. To keep pace with the projected planar transistor density, the first challenge is to identify the dominant factors that contribute to the high interconnect resistance. Here we directly measure individual grain boundary (GB) resistances in copper nanowires with a one-to-one correspondence to the GB structure. The specific resistivities of particular GBs are measured using four-probe scanning tunneling microscopy (STM) to establish a direct link between GB structure and the resistance. High-angle random GBs contribute to a specific resistivity of about 25 10-12 cm2 for each boundary, while coincidence boundaries are significantly less-resistive than random boundaries. Thus, replacing random boundaries with coincidence ones would be a route to suppress the GB impact to the resistivity of polycrystalline conductors. Acknowledgement: The research was supported by the Division of Scientific User Facilities, U. S. Department of Energy.

Kim, Tae Hwan [ORNL; Zhang, Xiaoguang [ORNL; Nicholson, Don M [ORNL; Radhakrishnan, Bala [ORNL; Radhakrishnan, Balasubramaniam [ORNL; Evans III, Boyd Mccutchen [ORNL; Kulkarni, Nagraj S [ORNL; Kenik, Edward A [ORNL; Meyer III, Harry M [ORNL; Li, An-Ping [ORNL

2011-01-01T23:59:59.000Z

358

ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry: Chapter 5: Copper  

Broader source: Energy.gov (indexed) [DOE]

5 5 Copper For nearly 5,000 years, copper was the only metal known to man. It remains one of the most used and reused of all metals. The demand for copper is due to its good strength and fatigue resistance, excellent electrical and thermal conductivity, outstanding resistance to corrosion, and ease of fabrication. Copper offers moderate levels of density, elastic modulus, and low melting temperature. It is used in electrical cables and wires, switches, plumbing, heating, roofing and building construction, chemical and pharmaceutical machinery. It is also used in alloys such as brass and bronze, alloy castings, and electroplated protective coating in undercoats of nickel, chromium, and zinc. Forms of Copper Copper deposits are found in a variety of geological environments, depending on the

359

Infrared spectroscopic study of the adsorption of carbon monoxide on silica-supported copper oxide  

SciTech Connect (OSTI)

Adsorption of carbon monoxide at room temperature (0.1 to 50 Torr) on silica-supported copper oxide was studied by infrared spectroscopy. Catalysts were prepared by deposition-precipitation or impregnation. After calcination two types of adsorbed CO were identified showing absorption bands at 2136 +- 3 and 2204 +- 1 cm/sup -1/, which are ascribed to CO adsorbed on copper(II) oxide and on isolated copper(II) ions in the silica surface, respectively. Reduction and reoxidation removed the band at 2204 cm/sup -1/ with all samples and raised the intensity of the 2136-cm/sup -1/ band with the precipitated catalysts but not with the impregnation catalyst. Evidence is brought forward that the isolated copper ions are mobilized during reduction and generate new copper (oxide) surface. The change in background transmission of the samples could be used to obtain further information about the interaction of O/sub 2/ and CO with copper oxide.

De Jong, K.P.; Geus, J.W.; Joziasse, J.

1980-10-01T23:59:59.000Z

360

Responses to Copper in Fungi 571 Job: 943-9 Operator: Nettype  

E-Print Network [OSTI]

Responses to Copper in Fungi 571 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Template: Massar0(943-9)7X10 temp 35 Regulatory Responses to Copper Ions in Fungi Simon Labbé, Jude gain and lose electrons, copper (Cu) ions serve as catalytic centers of numerous proteins involved

Labbé, Simon

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

E-Print Network 3.0 - acute copper toxicity Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with additional metals analyses. Because copper concentrations were within the range toxic to bivalves and sample... -six hour acute toxicity tests were conducted using...

362

Incorporation of copper nanoparticles into paper for point-of-use water purification  

Science Journals Connector (OSTI)

Abstract As a cost-effective alternative to silver nanoparticles, we have investigated the use of copper nanoparticles in paper filters for point-of-use water purification. This work reports an environmentally benign method for the direct in situ preparation of copper nanoparticles (CuNPs) in paper by reducing sorbed copper ions with ascorbic acid. Copper nanoparticles were quickly formed in less than 10 min and were well distributed on the paper fiber surfaces. Paper sheets were characterized by x-ray diffraction, scanning electron microscopy, energy dispersive x-ray spectroscopy, and atomic absorption spectroscopy. Antibacterial activity of the CuNP sheets was assessed for by passing Escherichia coli bacteria suspensions through the papers. The effluent was analyzed for viable bacteria and copper release. The CuNP papers with higher copper content showed a high bacteria reduction of log 8.8 for E. coli. The paper sheets containing copper nanoparticles were effective in inactivating the test bacteria as they passed through the paper. The copper levels released in the effluent water were below the recommended limit for copper in drinking water (1 ppm).

Theresa A. Dankovich; James A. Smith

2014-01-01T23:59:59.000Z

363

Properties of copper/graphite/carbon nanotubes composite reinforced by carbon nanotubes  

Science Journals Connector (OSTI)

Electroless Cu plating was used for flake G powder and CNTs, Cu–G–CNTs (copper/graphite/carbon nanotubes) composites were manufactured by means of powder...

Xin-Ying Liu; Xiong-Zhi Xiang; Fei Niu; Xiao-Jun Bai

2013-06-01T23:59:59.000Z

364

E-Print Network 3.0 - aluminum copper iron Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aluminum alloy... to room temperature was also confirmed. Will investigate different additives, copper, pure aluminum... with aluminum ... Source: McDonald, Kirk - Department...

365

Laser Induced Breakdown Spectroscopy to Detect Copper Contamination in Transformer Insulation  

Science Journals Connector (OSTI)

Laser Induced Breakdown Spectroscopy combined with a laser-ablation based depth profiling technique is demonstrated for the detection of copper contamination in transformer insulation....

Aparna, N; Wazeem, M A; Vasa, Nilesh J; Sarathi, R; Sundara Rajan, J

366

Isentropic expansion of copper plasma in Mbar pressure range at “Luch” laser facility  

SciTech Connect (OSTI)

We present experimental results on thermodynamic properties of dense copper plasma in Mbar pressure range. The laser facility “Luch” with laser intensity 10{sup 14}?W/cm{sup 2} is used to compress copper up to ?8?Mbar by a strong shock wave; subsequent expansion of copper plasma into Al, Ti, Sn allows us to obtain release isentropes of copper by the impedance–matching method. A theoretical analysis and quantum simulations show that in our experiments strongly coupled quantum plasma is generated.

Bel'kov, S. A.; Derkach, V. N.; Garanin, S. G.; Mitrofanov, E. I.; Voronich, I. N. [Russian Federal Nuclear Center – VNIIEF, Sarov (Russian Federation); Fortov, V. E.; Levashov, P. R.; Minakov, D. V. [Joint Institute for High Temperatures, Moscow, Russia and Moscow Institute of Physics and Technology (State University), Dolgoprudny (Russian Federation)

2014-01-21T23:59:59.000Z

367

Corrosion of Aluminum-fin, Copper-tube Heat Exchange Coils  

E-Print Network [OSTI]

industry standard procedures to test process chemicals or application contaminants for copper tube corrosion potential. Industry supported research has begun to develop a bench test for this....

Field, J. E.

2002-01-01T23:59:59.000Z

368

Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper  

DOE Patents [OSTI]

An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

1982-08-10T23:59:59.000Z

369

E-Print Network 3.0 - acid copper sulfate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with chalcopyrite. 5239Cu isotopes in the supergene environment 12;with the copper isotope variation of acid-sulfate... bonding in the Cu mineral during acid- sulfate leaching...

370

E-Print Network 3.0 - alumbrera copper-gold deposit Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering and Materials Science, Rice University Collection: Materials Science 12 geology and Ranger 1 open-pit uranium mine in Australia Summary: contains iron, copper,...

371

Characterization using thermomechanical and differential thermal analysis of the sinterization of Portland clinker doped with CaF{sub 2}  

SciTech Connect (OSTI)

In this work, the sintering process of Portland cement was studied by combining thermomechanical analysis (TMA) and differential thermal analysis (DTA), together with X-ray diffraction (XRD) and scanning electron microscopy (SEM). Thermal analysis results employing both techniques indicted that phase transformations appeared at lower temperatures when CaF{sub 2} was incorporated in the raw materials. Besides, it was observed at high temperature that in some phase transformations TMA conducts to better resolution compared with the DTA measurements. Furthermore, mechanical properties and X-ray diffraction patterns corroborate the TMA and DTA results, corroborating that the final amount of alite (Ca{sub 3}SiO{sub 5}) is higher when a certain amount of CaF{sub 2} was present during the clinkerization process.

Dominguez, O., E-mail: nanoquimica@yahoo.com [Fac. de Quimica-UASLP, Av. Dr. Salvador Nava 6, CP 78210, San Luis Potosi, SLP (Mexico); Torres-Castillo, A. [Fac. de Quimica-UASLP, Av. Dr. Salvador Nava 6, CP 78210, San Luis Potosi, SLP (Mexico); Flores-Velez, L.M. [Instituto de Metalurgia-UASLP, Sierra Leona 550, CP 78210, San Luis Potosi, SLP (Mexico); Torres, R. [Mexichem Fluor S.A., Eje 106 s/n CP 78395, San Luis Potosi, SLP (Mexico)

2010-04-15T23:59:59.000Z

372

Fe-Cr-Mo based ODS alloys via spark plasma sintering: A combinational characterization study by TEM and APT  

SciTech Connect (OSTI)

Nanoscale oxides play an important role in oxide dispersion strengthened (ODS) alloys for improved high temperature creep resistance and enhanced radiation damage tolerance. In this study, transmission electron microscopy (TEM) and atom probe tomography (APT) were combined to investigate two novel Fe-16Cr-3Mo (wt.%) based ODS alloys. Spark plasma sintering (SPS) was used to consolidate the ODS alloys from powders that were milled with 0.5 wt.% Y2O3 powder only or with Y2O3 powder and 1 wt.% Ti. TEM characterization revealed that both alloys have a bimodal structure of nanometer-size (~ 100 – 500 nm) and micron-size grains with nanostructured oxide precipitates formed along and close to grain boundaries with diameters ranging from five to tens of nanometers. APT provides further quantitative analyses of the oxide precipitates, and also reveals Mo segregation at grain boundaries next to oxide precipitates. The alloys with and without Ti are compared based on their microstructures.

Y. Q. Wu; K. N. Allahar; J. Burns; B. Jacques; I Charit; D. P. Butt; J. I. Cole

2013-08-01T23:59:59.000Z

373

Categorical Exclusion Determinations: National Energy Technology Laboratory  

Broader source: Energy.gov (indexed) [DOE]

May 10, 2013 May 10, 2013 CX-010285: Categorical Exclusion Determination Advancing Low Temperature Combustion and Lean Burning Engines for Light-and Heavy-Duty Vehicles CX(s) Applied: A9, B3.6 Date: 05/10/2013 Location(s): CX: none Offices(s): National Energy Technology Laboratory May 10, 2013 CX-010284: Categorical Exclusion Determination Construction of an Autogas Refueling Network CX(s) Applied: B5.22 Date: 05/10/2013 Location(s): West Virginia Offices(s): National Energy Technology Laboratory May 8, 2013 CX-010287: Categorical Exclusion Determination Understanding Nitrous Oxide Selective Catalytic Reduction Mechanism and Activity on Copper/Chabazite Structures throughout the Catalyst Life CX(s) Applied: A9, B3.6 Date: 05/08/2013 Location(s): CX: none Offices(s): National Energy Technology Laboratory

374

Convergence of a MFEFV method for two phase flow with applications to heap leaching of copper ores  

E-Print Network [OSTI]

Convergence of a MFE­FV method for two phase flow with applications to heap leaching of copper ores in porous media, with applications to heap leaching of copper ores. These approximations are based on mixed

SepĂşlveda, Mauricio

375

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Metallic Copper Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print Wednesday, 26 March 2008 00:00 The first commercial fungicide-the "Bordeaux mixture" of copper sulfate and lime-was used to fight downy mildew in French vineyards. The fungicide worked by catalyzing the production of free radicals that damage proteins and enzymes involved in cycling copper between Cu(I) and Cu(II) oxidation states in the cellular electron transport chain. However, not all fungi are sensitive to copper toxicity. Some, called mycorrhizae, which live underground in symbiosis with host plants through intracellular or extracellular colonization of their roots, are resistant, although it is not known why. A team from the CNRS and Université Joseph Fourier in Grenoble in collaboration with researchers at the University of Illinois at Chicago and in partnership with the French company Phytorestore has discovered a new form of copper-metallic nanoparticles-in the rhizosphere (soil-root interface) that may explain how mycorrhizal (symbiotic) fungi detoxify copper.

376

Copper-induced oxidative stress in three-spined stickleback : relationship with hepatic metal levels  

E-Print Network [OSTI]

contamination of aquatic ecosystems by heavy metals. Among them, copper is a widespread pollutant found, 1999). Although this metal is a required element, high concentrations appear to be toxic to freshwater1 Copper-induced oxidative stress in three-spined stickleback : relationship with hepatic metal

Paris-Sud XI, Université de

377

Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere.  

E-Print Network [OSTI]

1 Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere. Part I the minimization of given thermodynamic functions or mass action laws even with plasmas out of thermal equilibrium- . Key Words: circuit breakers, SF6, PTFE, carbon formation, copper, dielectric gas, plasma composition

Paris-Sud XI, Université de

378

The effects of topology upon fluid-flow and heat-transfer within cellular copper structures  

E-Print Network [OSTI]

1 The effects of topology upon fluid-flow and heat-transfer within cellular copper structures J The fluid-flow and heat-transfer features of copper cellular metal structures made by the transient liquid media. The experimental results for pressure drop and heat transfer were expressed on the basis

Wadley, Haydn

379

Carbon 40 (2002) 781786 Copper and strontium adsorption by a novel carbon material  

E-Print Network [OSTI]

Carbon 40 (2002) 781­786 Copper and strontium adsorption by a novel carbon material manufactured a significantly higher capacity for copper and strontium sorption than that of 21 21 a commercial material used and strontium. CAC can be produced from different types of raw materi- als, including wood, coal, fruit stones

Shawabkeh, Reyad A.

380

Assessment of energy requirements in proven and new copper processes. Final report  

SciTech Connect (OSTI)

Energy requirements are presented for thirteen pyrometallurgical and eight hydrometallurgical processes for the production of copper. Front end processing, mining, mineral processing, gas cleaning, and acid plant as well as mass balances are included. Conventional reverberatory smelting is used as a basis for comparison. Recommendations for needed process research in copper production are presented.

Pitt, C.H.; Wadsworth, M.E.

1980-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

ULTRASONIC ARRAY TECHNIQUE FOR THE INSPECTION OF COPPER LINED CANISTERS FOR NUCLEAR WASTE FUEL  

E-Print Network [OSTI]

ULTRASONIC ARRAY TECHNIQUE FOR THE INSPECTION OF COPPER LINED CANISTERS FOR NUCLEAR WASTE FUEL and Waste Management Co.) for encapsulation of nuclear waste. Due to the radiation emitted by the nuclear, and characterization. The applicability of linear array technique for inspection of copper lined canisters for nuclear

382

Coordination of Copper to the Membrane-Bound Form of ?-Synuclein  

SciTech Connect (OSTI)

Aggregation of the 140 amino acid protein ?-synuclein (?-syn) is linked to the development of Parkinson's disease (PD). ?-Syn is a copper binding protein with potential function as a regulator of metal dependent redox activity. Epidemiological studies suggest that human exposure to excess copper increases the incidence of PD. ?-Syn exists in both solution and membrane bound forms. Previous work evaluated the Cu2+ uptake for ?-syn in solution and identified Met1-Asp2 and His50 as primary contributors to the coordination shell, with a dissociation constant of approximately 0.1 nM. When bound to the membrane bilayer, ?-syn takes on a predominantly helical conformation, which spatially separates His50 from the protein N-terminus and is therefore incompatible with the copper coordination geometry of the solution state. Here we use circular dichroism and electron paramagnetic resonance (continuous wave and pulsed) to evaluate copper coordination to the membrane bound form of ?-syn. In this molecular environment, Cu2+ binds exclusively to the protein N-terminus (Met1-Asp2) with no participation from His50. Copper does not alter the membrane bound ?-syn conformation, or enhance the protein's release from the bilayer. The Cu2+ affinity is similar to that identified for solution ?-syn suggesting that copper coordination is retained in the membrane. Consideration of these results suggests that copper exerts its greatest conformational affect on the solution form of ?-syn and this species may therefore be precursor to PD arising from environmental copper exposure.

Dudzik, Christopher G.; Walter, Eric D.; Abrams, Benjamin S.; Jurica, Melissa S.; Millhauser, Glenn L.

2013-01-01T23:59:59.000Z

383

Ugi post-condensation copper-triggered oxidative cascade towards pyrazoles  

E-Print Network [OSTI]

1310 Ugi post-condensation copper-triggered oxidative cascade towards pyrazoles Aurélie Dos Santos-component Ugi coupling, the resulting hydrazone was engaged in a copper triggered [3 + 2] cycloaddition/aerobic oxidation cascade. 1310 Introduction In the last twenty years, the Ugi reaction coupled with its various

Paris-Sud XI, Université de

384

Role of Surface Precipitation in Copper Sorption by the Hydrous Oxides of Iron and Aluminum  

E-Print Network [OSTI]

Role of Surface Precipitation in Copper Sorption by the Hydrous Oxides of Iron and Aluminum K. G precipitation; sorption; isotherms; X-ray diffraction; hydrous iron oxide; hydrous aluminum oxide; copper. INTRODUCTION Hydrous oxides of iron (HFO) and aluminum (HAO) are important mineral components of natural

Chorover, Jon

385

Sorbitol accumulation in male and female rats consuming starch or fructose diets with or without copper  

SciTech Connect (OSTI)

The present study was designed to examine the relationship between the sex of the rats, tissue sorbitol accumulation and copper deficiency in rats consuming dietary fructose. Rats were provided with a diet containing either 62.7% fructose or starch, and either 6.0 or 0.6 {mu}g copper/g for three weeks. Hepatic copper concentration of all rats consuming the copper-deficient diets was about 40% of copper sufficient rats. Hepatic, renal and thymic sorbitol concentrations were significantly elevated in males consuming the fructose, copper-deficient diet when compared to all other dietary groups regardless of the sex of the rat. Hepatic, renal the thymic fructose concentrations were significantly higher in rats eating fructose as compared to female rats. Hepatic glucose concentration was higher in males and females consuming the fructose, copper-deficient diet when compared to all other dietary groups. Renal glucose concentration was elevated in males as compared to females. These results demonstrate that the pathology and complications of copper deficiency in the male rat consuming fructose closely parallel aberration in tissue sorbitol accumulation.

Lewis, C.G.; Fields, M.; Beal, T. (Dept. of Agriculture, Beltsville, MD (USA))

1989-02-09T23:59:59.000Z

386

Research on Chrysomelidae, Volume 2, pp. 131151, Koninklijke Brill, Leiden, 2009 Flea beetle diversity of the Sierra Tarahumara, Copper  

E-Print Network [OSTI]

diversity of the Sierra Tarahumara, Copper Canyon, Mexico (Chrysomelidae: Alticinae)1 Plates 27­32 David G Tarahumara (Copper Canyon or Barranca del Cobre), a section of the Sierra Madre Occidental of Chihuahua. The biogeographical affinities and host plants of the Copper Canyon Alticinae are also discussed. Resumen. Este

Mathis, Wayne N.

387

Interactions between Copper(II) Complexes of Mono-, Bis-, and Tris(macrocyclic) Ligands and Inorganic or Organic Guests  

E-Print Network [OSTI]

FULL PAPER Interactions between Copper(II) Complexes of Mono-, Bis-, and Tris(macrocyclic) Ligands. Prikhod'ko,[b] and Hans Pritzkow[a] Keywords: Copper / Host-guest complexes / Macrocycles / Molecular recognition Template synthesis The copper(II)-assisted condensation of [Cu(2,3,2-tet)]2+ [2,3,2-tet = bis

Nazarenko, Alexander

388

SPACE WAR SPACE DAILY TERRA DAILY MARS DAILY SPACE MART SPACE TRAVEL GPS DAILY ENERGY DAILY Unique Porous Copper Structure  

E-Print Network [OSTI]

Unique Porous Copper Structure Enables New Generation Of Military Micro-Detonators by Staff Writers Athens GA (SPX) Dec 19, 2007 Tiny copper structures with pores at both the nanometer and micron size, the highly-uniform copper structures will be incorporated into integrated circuits - then chemically

Bennett, Gisele

389

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial  

E-Print Network [OSTI]

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial cytochrome c oxidase, which makes copper an essential element for all aerobic organisms (Soloman and Lowery, 1993). However, the redox properties of copper can cause rapid generation

Grosell, Martin

390

COPPER-CATALYZED CROSS-COUPLING REACTIONS: THE FORMATION OF CARBON-CARBON AND CARBON-SULFUR BONDS  

E-Print Network [OSTI]

COPPER-CATALYZED CROSS-COUPLING REACTIONS: THE FORMATION OF CARBON-CARBON AND CARBON-SULFUR BONDS Chemistry #12;© Copyright by Craig G. Bates 2005 All Rights Reserved #12;COPPER-CATALYZED CROSS without her. Thank You January 24, 2005 #12;vi ABSTRACT COPPER-CATALYZED CROSS-COUPLING REACTIONS

Venkataraman, Dhandapani "DV"

391

Computational Study of Copper(II) Complexation and Hydrolysis in Aqueous Solutions Using Mixed Cluster/Continuum Models  

E-Print Network [OSTI]

Computational Study of Copper(II) Complexation and Hydrolysis in Aqueous Solutions Using Mixed and thermodynamic properties of Cu(II) species in aqueous solution. 1. Introduction Copper is a key component evidence that copper may be involved in the pathogenesis of atherosclerosis, Alzheimer's diseases

Goddard III, William A.

392

Use of Copper in Freshwater Aquaculture and Farm Craig Watson and Roy P.E. Yanong2  

E-Print Network [OSTI]

FA-13 Use of Copper in Freshwater Aquaculture and Farm Ponds 1 Craig Watson and Roy P.E. Yanong2 1 Dean Introduction Copper has been used for many years as a chemical tool in freshwater farm ponds of copper is that there is a thin line that separates effective treatment levels from overdoses, which can

Watson, Craig A.

393

Copper-free click chemistry as an emerging tool for the programmed ligation of DNA-functionalised gold  

E-Print Network [OSTI]

Copper-free click chemistry as an emerging tool for the programmed ligation of DNA-modified gold nanoparticles using copper-free click chemistry. Gold nanoparticles functionalized with a discrete of the copper-free, `click-ligation' method allows for its universal applicability and opens up new avenues

Zheludev, Nikolay

394

Copper(III) Pyrophosphate Complexes in Aqueous Solution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper(III) Pyrophosphate Complexes in Aqueous Solution. A Pulse Radiolysis Copper(III) Pyrophosphate Complexes in Aqueous Solution. A Pulse Radiolysis Study at Ambient and High Pressure Diane E. Cabelli, James F. Wishart, Jerzy Holcman, Martin Meier, and Rudi van Eldik J. Phys. Chem. A 101, 5131-5136 (1997) [Find paper at ACS Publications] Abstract: The reaction between OH radicals and [CuII(P2O7)2(H2O) 2]6- results in the formation of a Cu(III) complex. No reaction is observed with N3· or Br2·-, whereas SO4·- initiates the same steps as seen with ·OH. This suggests that the mechanism probably involves a ligand interchange or H · atom abstraction process. The Cu(III) complex undergoes a rapid first-order reaction, probably loss of a P2O74- chelate, followed by addition of OH- (pKOH ~ 10) to yield a Cu(III) complex that is predominantly hydroxylated

395

Solar swimming pool heating -- A copper collector after 26 years  

SciTech Connect (OSTI)

This paper is a progress report and a technology overview for a do-it-yourself solar swimming pool heater built by the author. Since March 1973 the heater has operated successfully day in day out for over 26 years, as a simple component in the pool circulation system, for three successive homeowners. The heater project was sponsored by the Copper Development Association (CDA), and used a copper flat plate collector design mounted on a small building, which provided both the roofing and the solar collection function. The heater was built in Pasadena, California, at 34.2 degrees north latitude and 118.2 degrees west longitude. A do-it-yourself manual was written so others could build such heaters, and about 100,000 copies of this manual have been distributed. The manual has helped many to get a better understanding of solar energy, has allowed many around the world to build similar swimming pool heater, and caused this author to get into the solar energy field.

Winter, F. de

1999-07-01T23:59:59.000Z

396

A new copper borophosphate with novel polymeric chains and its structural correlation with raw materials in molten hydrated flux synthesis  

SciTech Connect (OSTI)

A novel copper borophosphate, Cu{sub 3}[B{sub 2}P{sub 3}O{sub 12}(OH){sub 3}] has been prepared by the molten hydrated flux method. Its crystal structure was determined by the single-crystal X-ray diffraction (monoclinic, Cc, a=6.1895 Ĺ, b=13.6209 Ĺ, c=11.9373 Ĺ, ?=97.62°, V=997.5 Ĺ{sup 3}, Z=4). The three-dimensional framework of the titled compound, is composed by two kinds of polymeric chains and isolated PO{sub 4} tetrahedral. One novel 4-membered tetrahedral rings has been observed in borophosphates. Magnetic measurements indicate that the title compound exits antiferromagnetic interactions. Due to the special reaction medium created by the molten hydrated flux method, a possible structural correlation between the final solids and the raw materials has been noted. - Graphical abstract: The 3D structure consists of a framework composed of CuO{sub x} polyhedra, BO{sub 4} and PO{sub 4} tetrahedra. A intersection angle between the metal chains and borophosphate chains can be noted. Display Omitted - Highlights: • A novel copper borophosphate has been prepared by the molten hydrated flux method. • One novel 4-membered tetrahedral ring has been observed firstly in borophosphates. • A possible structural correlation between the final solids and the raw materials has been noted.

Duan, Ruijing; Liu, Wei, E-mail: Weiliu@ouc.edu.cn; Cao, Lixin; Su, Ge; Xu, Hongmei; Zhao, Chenggong

2014-02-15T23:59:59.000Z

397

Selenium, Cadmium, Copper, and Zinc Concentrations in Sediments and Mullet (Mugil cephalus) from the Southern Basin of Lake Macquarie, NSW, Australia  

E-Print Network [OSTI]

Selenium, Cadmium, Copper, and Zinc Concentrations in Sediments and Mullet (Mugil cephalus) from. Selenium, cadmium, copper, and zinc concentrations were measured in sediments and the tissues of mullet­19; cadmium, 14­42; copper, 1.5­3.6; zinc, 0.77­2.2 times background). Selenium, cadmium, and copper in Lake

Canberra, University of

398

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print The first commercial fungicide-the "Bordeaux mixture" of copper sulfate and lime-was used to fight downy mildew in French vineyards. The fungicide worked by catalyzing the production of free radicals that damage proteins and enzymes involved in cycling copper between Cu(I) and Cu(II) oxidation states in the cellular electron transport chain. However, not all fungi are sensitive to copper toxicity. Some, called mycorrhizae, which live underground in symbiosis with host plants through intracellular or extracellular colonization of their roots, are resistant, although it is not known why. A team from the CNRS and Université Joseph Fourier in Grenoble in collaboration with researchers at the University of Illinois at Chicago and in partnership with the French company Phytorestore has discovered a new form of copper-metallic nanoparticles-in the rhizosphere (soil-root interface) that may explain how mycorrhizal (symbiotic) fungi detoxify copper.

399

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print The first commercial fungicide-the "Bordeaux mixture" of copper sulfate and lime-was used to fight downy mildew in French vineyards. The fungicide worked by catalyzing the production of free radicals that damage proteins and enzymes involved in cycling copper between Cu(I) and Cu(II) oxidation states in the cellular electron transport chain. However, not all fungi are sensitive to copper toxicity. Some, called mycorrhizae, which live underground in symbiosis with host plants through intracellular or extracellular colonization of their roots, are resistant, although it is not known why. A team from the CNRS and Université Joseph Fourier in Grenoble in collaboration with researchers at the University of Illinois at Chicago and in partnership with the French company Phytorestore has discovered a new form of copper-metallic nanoparticles-in the rhizosphere (soil-root interface) that may explain how mycorrhizal (symbiotic) fungi detoxify copper.

400

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print The first commercial fungicide-the "Bordeaux mixture" of copper sulfate and lime-was used to fight downy mildew in French vineyards. The fungicide worked by catalyzing the production of free radicals that damage proteins and enzymes involved in cycling copper between Cu(I) and Cu(II) oxidation states in the cellular electron transport chain. However, not all fungi are sensitive to copper toxicity. Some, called mycorrhizae, which live underground in symbiosis with host plants through intracellular or extracellular colonization of their roots, are resistant, although it is not known why. A team from the CNRS and Université Joseph Fourier in Grenoble in collaboration with researchers at the University of Illinois at Chicago and in partnership with the French company Phytorestore has discovered a new form of copper-metallic nanoparticles-in the rhizosphere (soil-root interface) that may explain how mycorrhizal (symbiotic) fungi detoxify copper.

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print Formation of Metallic Copper Nanoparticles at the Soil-Root Interface Print The first commercial fungicide-the "Bordeaux mixture" of copper sulfate and lime-was used to fight downy mildew in French vineyards. The fungicide worked by catalyzing the production of free radicals that damage proteins and enzymes involved in cycling copper between Cu(I) and Cu(II) oxidation states in the cellular electron transport chain. However, not all fungi are sensitive to copper toxicity. Some, called mycorrhizae, which live underground in symbiosis with host plants through intracellular or extracellular colonization of their roots, are resistant, although it is not known why. A team from the CNRS and Université Joseph Fourier in Grenoble in collaboration with researchers at the University of Illinois at Chicago and in partnership with the French company Phytorestore has discovered a new form of copper-metallic nanoparticles-in the rhizosphere (soil-root interface) that may explain how mycorrhizal (symbiotic) fungi detoxify copper.

402

Fabrication of Tungsten-Rhenium Cladding materials via Spark Plasma Sintering for Ultra High Temperature Reactor Applications  

SciTech Connect (OSTI)

This research will develop an optimized, cost-effective method for producing high-purity tungsten-rhenium alloyed fuel clad forms that are crucial for the development of a very high-temperature nuclear reactor. The study will provide critical insight into the fundamental behavior (processing-microstructure- property correlations) of W-Re alloys made using this new fabrication process comprising high-energy ball milling (HEBM) and spark plasma sintering (SPS). A broader goal is to re-establish the U.S. lead in the research field of refractory alloys, such as W-Re systems, with potential applications in very high-temperature nuclear reactors. An essential long-term goal for nuclear power is to develop the capability of operating nuclear reactors at temperatures in excess of 1,000K. This capability has applications in space exploration and some special terrestrial uses where high temperatures are needed in certain chemical or reforming processes. Refractory alloys have been identified as being capable of withstanding temperatures in excess of 1,000K and are considered critical for the development of ultra hightemperature reactors. Tungsten alloys are known to possess extraordinary properties, such as excellent high-temperature capability, including the ability to resist leakage of fissile materials when used as a fuel clad. However, there are difficulties with the development of refractory alloys: 1) lack of basic experimental data on thermodynamics and mechanical and physical properties, and 2) challenges associated with processing these alloys.

Indrajit Charit; Darryl Butt; Megan Frary; Mark Carroll

2012-11-05T23:59:59.000Z

403

Copper gettering by aluminum precipitates in aluminum-implanted silicon  

SciTech Connect (OSTI)

Copper in Si is shown to be strongly gettered by Al-rich precipitates formed by implanting Al to supersaturation and followed by annealing. At temperatures ranging from 600 to 800 C a layer containing Al precipitates is found to getter Cu from Cu silicide located on the opposite side of a 0.25-mm Si wafer, indicating a substantially lower chemical potential for the Cu in the molten-A1 phase. Cu gettering proceeds rapidly until an atomic ratio of approximately 2 Cu atoms to 1 Al atom is reached in the precipitated Al region, after which the gettering process slows. Redistribution of Cu from one Al-rich layer to another at low Cu concentrations demonstrates that a segregation-type gettering mechanism is operating. Cu gettering occurs primarily in the region containing the precipitated Al rather than the region where the Al is entirely substitutional.

PETERSEN,GARY A.; MYERS JR.,SAMUEL M.

2000-03-20T23:59:59.000Z

404

Order on disorder: Copper phthalocyanine thin films on technical substrates  

SciTech Connect (OSTI)

We have studied the molecular orientation of the commonly used organic semiconductor copper phthalocyanine (CuPC) grown as thin films on the technically relevant substrates indium tin oxide, oxidized Si, and polycrystalline gold using polarization-dependent x-ray absorption spectroscopy, and compare the results with those obtained from single crystalline substrates [Au(110) and GeS(001)]. Surprisingly, the 20{endash}50 nm thick CuPC films on the technical substrates are as highly ordered as on the single crystals. Importantly, however, the molecular orientation in the two cases is radically different: the CuPC molecules stand on the technical substrates and lie on the single crystalline substrates. The reasons for this and its consequences for our understanding of the behavior of CuPC films in devices are discussed. {copyright} 2001 American Institute of Physics.

Peisert, H.; Schwieger, T.; Auerhammer, J. M.; Knupfer, M.; Golden, M. S.; Fink, J.; Bressler, P. R.; Mast, M.

2001-07-01T23:59:59.000Z

405

Structural Dependence of Grain Boundary Resistivity in Copper Nanowires  

SciTech Connect (OSTI)

We report the direct measurement of individual grain boundary (GB) resistances and the critical role of GB structure in the increased resistivity in copper nanowires. By measuring both intra- and inter-grain resistance with a four-probe scanning tunneling microscope, large resistance jumps are revealed owing to successive scattering across high-angle random GBs, while the resistance changes at twin and other coincidence boundaries are negligibly small. The impurity distributions in the nanowires are characterized in correlating to the microstructures. The resistance of high symmetry coincidence GBs and the impurity contributions are then calculated using a first-principle method which confirms that the coincidence GBs have orders of magnitude smaller resistance than the high-angle random GBs.

Evans III, Boyd Mccutchen [ORNL; Kenik, Edward A [ORNL; Kim, Tae Hwan [ORNL; Kulkarni, Nagraj S [ORNL; Li, An-Ping [ORNL; Meyer III, Harry M [ORNL; Nicholson, Don M [ORNL; Radhakrishnan, Bala [ORNL; Zhang, Xiaoguang [ORNL

2011-01-01T23:59:59.000Z

406

Impact of Copper Thefts on the Department of Energy (OIG Case No.: I11IG002)  

Broader source: Energy.gov (indexed) [DOE]

August 17, 2011 August 17, 2011 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Impact of Copper Thefts on the Department of Energy (OIG Case No.: I11IG002) A series of news articles during the last several months have reported increased thefts of copper nationally, including several that have interrupted electrical distribution and telephone service in communities across the country. These thefts have also adversely impacted new construction projects, irrigation systems and other infrastructure projects. In fact, the Federal Bureau of Investigation reported in an unclassified intelligence assessment that copper thefts threaten the critical infrastructure of the United States.

407

Resistance mash welding for joining of copper conductors for electric motors  

Science Journals Connector (OSTI)

Abstract The automotive industry is developing designs and manufacturing processes for a new generation of electric motors intended for use in hybrid and electric vehicles. This paper is focused on using solid-state welding to join rectangular wires in the fabrication of motor stators. Resistance welding has not typically been applied to copper due to its very high electrical conductivity; however through optimization of the current and pressure profiles, excellent quality copper-to-copper joints have been demonstrated with a technique known as resistance mash welding. A better understanding of resistance mash welding characteristics will help advancements in its application for stators. The limitations of this application will be discussed.

John S. Agapiou; Thomas A. Perry

2013-01-01T23:59:59.000Z

408

Modeling pore corrosion in normally open gold- plated copper connectors.  

SciTech Connect (OSTI)

The goal of this study is to model the electrical response of gold plated copper electrical contacts exposed to a mixed flowing gas stream consisting of air containing 10 ppb H{sub 2}S at 30 C and a relative humidity of 70%. This environment accelerates the attack normally observed in a light industrial environment (essentially a simplified version of the Battelle Class 2 environment). Corrosion rates were quantified by measuring the corrosion site density, size distribution, and the macroscopic electrical resistance of the aged surface as a function of exposure time. A pore corrosion numerical model was used to predict both the growth of copper sulfide corrosion product which blooms through defects in the gold layer and the resulting electrical contact resistance of the aged surface. Assumptions about the distribution of defects in the noble metal plating and the mechanism for how corrosion blooms affect electrical contact resistance were needed to complete the numerical model. Comparisons are made to the experimentally observed number density of corrosion sites, the size distribution of corrosion product blooms, and the cumulative probability distribution of the electrical contact resistance. Experimentally, the bloom site density increases as a function of time, whereas the bloom size distribution remains relatively independent of time. These two effects are included in the numerical model by adding a corrosion initiation probability proportional to the surface area along with a probability for bloom-growth extinction proportional to the corrosion product bloom volume. The cumulative probability distribution of electrical resistance becomes skewed as exposure time increases. While the electrical contact resistance increases as a function of time for a fraction of the bloom population, the median value remains relatively unchanged. In order to model this behavior, the resistance calculated for large blooms has been weighted more heavily.

Battaile, Corbett Chandler; Moffat, Harry K.; Sun, Amy Cha-Tien; Enos, David George; Serna, Lysle M.; Sorensen, Neil Robert

2008-09-01T23:59:59.000Z

409

Photoconductivity in reactively evaporated copper indium selenide thin films  

SciTech Connect (OSTI)

Copper indium selenide thin films of composition CuInSe{sub 2} with thickness of the order of 130 nm are deposited on glass substrate at a temperature of 423 ±5 K and pressure of 10{sup ?5} mbar using reactive evaporation, a variant of Gunther's three temperature method with high purity Copper (99.999%), Indium (99.999%) and Selenium (99.99%) as the elemental starting materials. X-ray diffraction (XRD) studies shows that the films are polycrystalline in nature having preferred orientation of grains along the (112) plane. The structural type of the film is found to be tetragonal with particle size of the order of 32 nm. The structural parameters such as lattice constant, particle size, dislocation density, number of crystallites per unit area and strain in the film are also evaluated. The surface morphology of CuInSe{sub 2} films are studied using 2D and 3D atomic force microscopy to estimate the grain size and surface roughness respectively. Analysis of the absorption spectrum of the film recorded using UV-Vis-NIR Spectrophotometer in the wavelength range from 2500 nm to cutoff revealed that the film possess a direct allowed transition with a band gap of 1.05 eV and a high value of absorption coefficient (?) of 10{sup 6} cm{sup ?1} at 570 nm. Photoconductivity at room temperature is measured after illuminating the film with an FSH lamp (82 V, 300 W). Optical absorption studies in conjunction with the good photoconductivity of the prepared p-type CuInSe{sub 2} thin films indicate its suitability in photovoltaic applications.

Urmila, K. S., E-mail: urmilaks7@gmail.com; Asokan, T. Namitha, E-mail: urmilaks7@gmail.com; Pradeep, B., E-mail: urmilaks7@gmail.com [Solid State Physics Laboratory, Cochin University of Science and Technology, Kochi, Kerala (India); Jacob, Rajani; Philip, Rachel Reena [Thin Film Research Laboratory, Union Christian College, Aluva, Kerala (India)

2014-01-28T23:59:59.000Z

410

Oscillatory behavior of the agglomeration rate in island copper films  

Science Journals Connector (OSTI)

The post-deposition dc electrical-resistance increase of island copper films deposited on glass substrates at room temperature and at a pressure of 2×10-5 torr is studied. Films in the resistance range 10–95 M?/? were studied under different conditions to ascertain the role of residual gases and substrate-surface contaminants on the agglomeration rate. Mobility coalescence of small islands of Cu giving rise to an agglomerated film structure is assumed to explain the post-deposition resistance increase. It was found that the logarithm of the normalized resistance [ln(R/R0); R0 is the initial resistance of the film at a time t=0] varies linearly as the logarithm of the time elapsed after the cessation of deposition. The constant of proportionality in the above relationship, termed the agglomeration rate m, shows an interesting oscillatory dependence on the initial resistance of the film and the condition of study. Nearly all the maxima and minima of m for two of the conditions studied in detail as a function of the initial resistance occur at about the same initial resistance values with the films having almost the same structure at these points. An argument is put forward based on the oscillatory nature of the effective tunneling barrier as a function of the island size to explain this unusual behavior. It is found that the presence of a thin film of water vapor on the substrate surface impedes the agglomeration rate to a great extent while the presence of adsorbed O2 and N2 decreases the energy for surface migration of islands of copper thereby increasing the agglomeration rate.

V. Damodara Das and M. S. Murali Sastry

1986-05-15T23:59:59.000Z

411

Binding of copper and nickel to cavities in silicon formed by helium ion implantation  

SciTech Connect (OSTI)

Cavities formed in Si by He ion implantation and annealing are shown to be strong traps for Cu and Ni impurities. Experiments utilizing ion-beam analysis and transmission electron microscopy indicate that Cu is trapped at the internal surfaces of cavities up to {approximately}1 monolayer coverage with a binding energy of 2.2{plus_minus}0.2 eV relative to solution. This is greater than the heat of solution from the precipitated Cu{sub 3}Si phase, determined to be 1.7 eV in agreement with earlier work. Copper at cavity-wall sites is reversibly replaced by H during heating in H{sub 2} gas, indicating the relative stability of the two surface terminations. Initial results for Ni impurities indicate that trapping at cavities is again energetically preferred to silicide formation. The saturation coverage of Ni on the internal surfaces, however, is an order of magnitude smaller for Ni than Cu, consistent with published studies of external-surface adsorption. These results suggest that cavity trapping may getter metallic impurities in Si more effectively than methods based on silicide precipitation.

Myers, S.M.; Follstaedt, D.M.; Bishop, D.M.

1993-12-01T23:59:59.000Z

412

CX-008648: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

48: Categorical Exclusion Determination 48: Categorical Exclusion Determination CX-008648: Categorical Exclusion Determination Printed Circuit Board Through-Hole Plating, Masking, and Legending Process CX(s) Applied: B3.6 Date: 05/22/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office A MiniContac RS electrochemical plater is used to plate through-holes with copper between surface layers on electronic printed circuit boards . Additionally, a ProMask (solder mask) process and ProLegend (legend printing or silkscreening) are used to process the printed circuit boards. All equipment and chemical supplies are procured from LPKF Laser & Electronics. CX-008648.pdf More Documents & Publications CX-006931: Categorical Exclusion Determination CX-007668: Categorical Exclusion Determination

413

Size Dependence of a Temperature-Induced Solid-Solid Phase Transition in Copper(I) Sulfide  

SciTech Connect (OSTI)

Determination of the phase diagrams for the nanocrystalline forms of materials is crucial for our understanding of nanostructures and the design of functional materials using nanoscale building blocks. The ability to study such transformations in nanomaterials with controlled shape offers further insight into transition mechanisms and the influence of particular facets. Here we present an investigation of the size-dependent, temperature-induced solid-solid phase transition in copper sulfide nanorods from low- to high-chalcocite. We find the transition temperature to be substantially reduced, with the high chalcocite phase appearing in the smallest nanocrystals at temperatures so low that they are typical of photovoltaic operation. Size dependence in phase trans- formations suggests the possibility of accessing morphologies that are not found in bulk solids at ambient conditions. These other- wise-inaccessible crystal phases could enable higher-performing materials in a range of applications, including sensing, switching, lighting, and photovoltaics.

Rivest, Jessy B; Fong, Lam-Kiu; Jain, Prashant K; Toney, Michael F; Alivisatos, A Paul

2011-07-24T23:59:59.000Z

414

Results Of Copper Catalyzed Peroxide Oxidation (CCPO) Of Tank 48H Simulants  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed a series of laboratory-scale experiments that examined copper-catalyzed hydrogen peroxide (H{sub 2}O{sub 2}) aided destruction of organic components, most notably tetraphenylborate (TPB), in Tank 48H simulant slurries. The experiments were designed with an expectation of conducting the process within existing vessels of Building 241-96H with minimal modifications to the existing equipment. Results of the experiments indicate that TPB destruction levels exceeding 99.9% are achievable, dependent on the reaction conditions. A lower reaction pH provides faster reaction rates (pH 7 > pH 9 > pH 11); however, pH 9 reactions provide the least quantity of organic residual compounds within the limits of species analyzed. Higher temperatures lead to faster reaction rates and smaller quantities of organic residual compounds. A processing temperature of 50 ?C as part of an overall set of conditions appears to provide a viable TPB destruction time on the order of 4 days. Higher concentrations of the copper catalyst provide faster reaction rates, but the highest copper concentration (500 mg/L) also resulted in the second highest quantity of organic residual compounds. The data in this report suggests 100-250 mg/L as a minimum. Faster rates of H{sub 2}O{sub 2} addition lead to faster reaction rates and lower quantities of organic residual compounds. An addition rate of 0.4 mL/hour, scaled to the full vessel, is suggested for the process. SRNL recommends that for pH adjustment, an acid addition rate 42 mL/hour, scaled to the full vessel, is used. This is the same addition rate used in the testing. Even though the TPB and phenylborates can be destroyed in a relative short time period, the residual organics will take longer to degrade to <10 mg/L. Low level leaching on titanium occurred, however, the typical concentrations of released titanium are very low (~40 mg/L or less). A small amount of leaching under these conditions is not surprising and is consistent with a previous study. Acidification with phosphoric and formic acids, in lieu of nitric acid, provides benefits in reducing the amount of benzene emitted over the lifetime of a reaction. Analyses of the post-reaction residual material indicate that slurry initially adjusted down to a pH 7 produced a greater degree of energetic material than material initially adjusted to a pH of 9. No more than 140 {micro}g/m{sup 3} of mercury was indicated in reactor head spaces at any time. An estimation of less than 1% of the initial mercury was vaporized in each experiment. A limited number of replicate tests were performed to determine experimental reproducibility. These tests indicate a reasonable degree of reproducibility. The conclusion of the simulant testing has provided a set of reaction conditions that can destroy the TPB and phenylborates quickly. While longer times will be required to degrade the residual organics, the reactions appear to perform in a consistent manner. A real waste test or tests are recommended and further investigation into the use of phosphoric or formic acid is warranted.

Peters, T. B.; Pareizs, J. M.; Newell, J. D.; Fondeur, F. F.; Nash, C. A.; White, T. L.; Fink, S. D.

2012-12-13T23:59:59.000Z

415

CX-011470: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Digestion analysis of copper foil and silicon carbide samples CX(s) Applied: B3.6 Date: 11/26/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

416

CX-009801: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Copper Mountain to Boysen 34.5 Kilovolt Transmission Line Structure Replacement CX(s) Applied: B1.3 Date: 01/11/2013 Location(s): Wyoming Offices(s): Western Area Power Administration-Rocky Mountain Region

417

Hydrogenolysis of methyl formate over copper on silica. I. Study of surface species by in situ infrared spectroscopy  

SciTech Connect (OSTI)

The hydrogenolysis of methyl formate to methanol over silica-supported copper has been studied using in situ infrared spectroscopy coupled with simultaneous determination of rate. Under flow reaction conditions two forms of adsorbed methyl formate exist. One has a carbonyl absorption at 1726 cm/sup -1/ and is bound to the support by the hydrogen bonding with a heat of adsorption of 65 kJ mol/sup -1/. The second absorbs at 1666 cm/sup -1/ and is bound to copper with an approximate heat of adsorption of 140 kJ mol/sup -1/. At 457 K the hydrogenolysis rate is directly proportional to the band intensity of the latter and hence it, or another species in equilibrium with it, is involved in the rate-determining step. Adsorption of CO from CO/H/sub 2/ mixtures gives rise to a single infrared band at 2117 cm/sup -1/, the corresponding heat of adsorption being 60 kJ mol/sup -1/. Competitive measurements under hydrogenolysis conditions show that methyl formate will partially displace adsorbed CO and not vice versa. Nonetheless CO does reversibly inhibit the rate and this is attributed to its adsorption displacing hydrogen from the surface. The lower concentration of surface hydrogen also reduces the rate of hydrogenation of a formaldehyde intermediate leading to its deposition as a polymer as revealed by infrared bands at 1483 and 1375 cm/sup -1/. The same polymer accretes more rapidly during the reverse methanol to methyl formate reaction for which CO is a substantial by-product and hydrogen pressures are much lower than used for hydrogenolysis. Continuous deactivation of the catalyst is then observed.

Monti, D.M.; Cant, N.W.; Trimm, D.L.; Wainwright, M.S.

1986-07-01T23:59:59.000Z

418

Synchrotron x-ray reflectivity study of oxidation/passivation of copper and silicon.  

SciTech Connect (OSTI)

Synchrotron x-ray-scattering technique studies of copper and silicon electrochemical interfaces are reported. These two examples illustrate the application of synchrotron x-ray techniques for oxidation, passivation, and dissolution of metals and semiconductors.

Chu, Y.; Nagy, Z.; Parkhutik, V.; You, H.

1999-07-21T23:59:59.000Z

419

Effects of Chemical Additives of CMP Slurry on Surface Mechanical Characteristics and Material Removal of Copper  

Science Journals Connector (OSTI)

Copper has taken the place of aluminum as the interconnect material in multilevel structures of integrated circuits (ICs) as a result of its higher resistance to electromigration and lower resistivity [1–3]. Diff...

Chenglong Liao; Dan Guo; Shizhu Wen; Jianbin Luo

2012-02-01T23:59:59.000Z

420

Copper exclusion as a mechanism of heavy metal tolerance in a green alga  

Science Journals Connector (OSTI)

... with an Evans Electroselenium 240 atomic absorption spectrophotometer fitted with a Shandon Southern Instruments A3470 flameless attachment (carbon rod). Results are expressed as percentage dry weight as copper, computed ...

PATRICIA L. FOSTER

1977-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Resonant Inelastic X-ray Scattering of Rare-Earth and Copper Systems  

E-Print Network [OSTI]

100 nm Si 3 N 4 windows 100Ĺ copper films were deposited inthick Si 3 N 4 window, the 100Ĺ Fe film was deposited inis present in the film on the window membrane. Cu 2 O has

Kvashnina, Kristina

2007-01-01T23:59:59.000Z

422

Mechanistic Studies on the Copper-Catalyzed N-Arylation of Amides  

E-Print Network [OSTI]

The copper-catalyzed N-arylation of amides, i.e., the Goldberg reaction, is an efficient method for the construction of products relevant to both industry and academic settings. Herein, we present mechanistic details ...

Strieter, Eric R.

423

Room Temperature Aryl Trifluoromethylation via Copper- Mediated Oxidative Cross-Coupling  

E-Print Network [OSTI]

A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids has been developed. This protocol is amenable to normal benchtop setup and reactions typically require only 1?4 ...

Buchwald, Stephen Leffler

424

E-Print Network 3.0 - auracyanins blue copper Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 36 R E S E A R C H L E T T E R Copper deciency in potato dextrose agar causes reduced Summary: as a cofactor for a range of oxidases and oxygenases, including...

425

Polycrystalline Thin-Film Research: Copper Indium Gallium Diselenide (Fact Sheet)  

SciTech Connect (OSTI)

Capabilities fact sheet for the National Center for Photovoltaics: Polycrystalline Thin-Film Research: Copper Indium Gallium Diselenide that includes scope, core competencies and capabilities, and contact/web information.

Not Available

2011-06-01T23:59:59.000Z

426

1208 Organometallics1988,7,1208-1213 Copper(I) Alkyls. Synthesis and Characterization of Tertiary  

E-Print Network [OSTI]

-Champaign, Urbana, Illinois 61801 Received December 28. 1986 Alkylation of copper(I1)acetate reflections and 62 variables. Introduction Lithium dialkylcuprates, LiCuR2,are used extensively in organic

Girolami, Gregory S.

427

Modeling of pattern dependencies in the fabrication of multilevel copper metallization  

E-Print Network [OSTI]

Multilevel copper metallization for Ultra-Large-Scale-Integrated (ULSI) circuits is a critical technology needed to meet performance requirements for advanced interconnect technologies with sub-micron dimensions. It is ...

Cai, Hong, Ph. D. Massachusetts Institute of Technology

2007-01-01T23:59:59.000Z

428

Structures and Quantum Conduction of Copper Nanowires under Electric Fields Using First Principles  

Science Journals Connector (OSTI)

Structures and Quantum Conduction of Copper Nanowires under Electric Fields Using First Principles ... Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and Department of Materials Science and Engineering, Jilin University, Changchun 130022, China ...

C. He; P. Zhang; Y. F. Zhu; Q. Jiang

2008-05-22T23:59:59.000Z

429

Thermal contact conductance of metallic coated superconductor/copper interfaces at cryogenic temperatures  

E-Print Network [OSTI]

THERMAL CONTACT CONDUCTANCE OF METALLIC COATED SUPERCONDUCTOR/COPPER INTERFACES AT CRYOGENIC TEMPERATURES A Thesis by JAY MATTHEW OCHTERBECK Submitted to the 0%ce of Graduate Studies of Texas AJrM IJniversity in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1990 Major Subject: Mechanical Engineering THERMAL CONTACT CONDUCTANCE OF METALLIC COATED SUPERCONDUCTOR/COPPER INTERFACES AT CRYOGENIC TEMPERATURES A Thesis JA'r '(IATTHEW OCHTERBECK Approved...

Ochterbeck, Jay Matthew

2012-06-07T23:59:59.000Z

430

Copper induced osteopenia and its relationship to the development of postmenopausal osteoporosis in the rat  

E-Print Network [OSTI]

COPPER INDUCED OSTEOPENIA AND ITS RELATIONSHIP TO THE DEVELOPMENT OF POSTMENOPAUSAL OSTEOPOROSIS IN THE RAT A Thesis CINDY DEANN YEE Submitted to the Office of Graduate Studies of Texas ASM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1992 Major Subject: Nutrition COPPER INDUCED OSTEOPENIA AND ITS RELATIONSHIP TO THE DEVELOPMENT OF POSTMENOPAUSAL OSTEOPOROSIS IN THE RAT A Thesis CINDY DEANN YEE Approved as to style and content...

Yee, Cindy Deann

2012-06-07T23:59:59.000Z

431

Prenatal and postweaning dietary copper effects on cellular and humoral immunity in calves  

E-Print Network [OSTI]

PRENATAL AND POSTWEANING DIETARY COPPER EFFECTS ON CELLULAR AND HUMORAL IMMUNITY IN CALVES A Thesis by MICHAEL SHANE DAVIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfilhnent of the requircmcnts... for the degree ol' MASTER OF SCIENCE August 1999 Major Subject: Nutrition PRENATAL AND POSTWEANING DIETARY COPPER EFFECTS ON CELLULAR AND HUMORAL IMMUNITY IN CALVES A Thesis by Michael Shane Davis Submitted to Texas A&M University in partial fulfillment...

Davis, Michael Shane

1999-01-01T23:59:59.000Z

432

Pattern recognition of porphyry copper deposits in New Mexico and Texas  

E-Print Network [OSTI]

History Structure Igneous Activity . Tectonics Laramide Orogeny . PORPHYRY COPPER DEPOSITS Definition Geologic Setting . Mineralization and Alteration Primary or Hypogene Mineralization Supergene EnricHment Reactivation of Faulting Summary 1V...PATTERN RECOGNITION OF PORPHYRY COPPER DEPOSITS IN NEW MEXICO AND TEXAS A Thesis by DAVID ALLAN PIATT Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

Piatt, David Allan

2012-06-07T23:59:59.000Z

433

A surface science investigation of the formation of passivating layers on copper surfaces  

E-Print Network [OSTI]

The corrosion of copper and passive film formation due to various solution exposures has been investigated ex situ with temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), and Auger electron spectroscopy (AES). With the use of a... specially designed ultra high vacuum chamber, the exposure of thin copper films to corrosive water solutions was performed and subsequently analyzed with AES, XPS, and TPD. The TPD results verified the corrosive nature of chloride and sulfate ions...

Hamelin, Elizabeth I.

2012-06-07T23:59:59.000Z

434

The influence of copper and bicarbonate ions on the corrosion of aluminum alloys saline solutions  

E-Print Network [OSTI]

THE INFLUENCE OF COPPER AND BICARBONATE IONS ON THE CORROSION OF ALUMINUM ALLOYS IN SALINE SOLUTIONS A Thesis by ALCIBIADES BECERRA-DIAZ Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1972 Major Subject: Mechanical Engineerinq THE INFLUENCE OF COPPER AND BICARBONATE IONS ON THE CORROSION OF ALUMINUM ALLOYS IN SALINE SOLUTIONS A Thesis by ALCIBIADES BECERRA-DIAZ Approved as to sty1e...

Becerra-Diaz, Alcibiades

2012-06-07T23:59:59.000Z

435

Laser-induced chemical liquid phase deposition of copper from aqueous solutions without reducing agents  

SciTech Connect (OSTI)

Laser-induced chemical liquid phase deposition of copper without a traditional reducing agent has been used for the first time to obtain conductive patterns on a dielectric surface having a reducing ability. It is shown that phenol-formaldehyde binder of the dielectric (glass fibre) can successfully play the role of a reducing agent in this process. The resulting copper sediments have low electrical resistance and good topology. (interaction of laser radiation with matter. laser plasmas)

Kochemirovsky, V A; Tumkin, I I; Logunov, L S; Safonov, S V; Menchikov, Leonid G

2012-08-31T23:59:59.000Z

436

GRAIN REFINEMENT OF PERMANENT MOLD CAST COPPER BASE ALLOYS  

SciTech Connect (OSTI)

Grain refinement behavior of copper alloys cast in permanent molds was investigated. This is one of the least studied subjects in copper alloy castings. Grain refinement is not widely practiced for leaded copper alloys cast in sand molds. Aluminum bronzes and high strength yellow brasses, cast in sand and permanent molds, were usually fine grained due to the presence of more than 2% iron. Grain refinement of the most common permanent mold casting alloys, leaded yellow brass and its lead-free replacement EnviroBrass III, is not universally accepted due to the perceived problem of hard spots in finished castings and for the same reason these alloys contain very low amounts of iron. The yellow brasses and Cu-Si alloys are gaining popularity in North America due to their low lead content and amenability for permanent mold casting. These alloys are prone to hot tearing in permanent mold casting. Grain refinement is one of the solutions for reducing this problem. However, to use this technique it is necessary to understand the mechanism of grain refinement and other issues involved in the process. The following issues were studied during this three year project funded by the US Department of Energy and the copper casting industry: (1) Effect of alloying additions on the grain size of Cu-Zn alloys and their interaction with grain refiners; (2) Effect of two grain refining elements, boron and zirconium, on the grain size of four copper alloys, yellow brass, EnviroBrass II, silicon brass and silicon bronze and the duration of their effect (fading); (3) Prediction of grain refinement using cooling curve analysis and use of this method as an on-line quality control tool; (4) Hard spot formation in yellow brass and EnviroBrass due to grain refinement; (5) Corrosion resistance of the grain refined alloys; (6) Transfer the technology to permanent mold casting foundries; It was found that alloying elements such as tin and zinc do not change the grain size of Cu-Zn alloys. Aluminum promoted b phase formation and modified the grain structure from dendritic to equiaxed. Lead or bismuth reduces the size of grains, but not change the morphology of the structure in Cu-Zn alloys. The grain size of the Cu-Zn-alloy can be reduced from 3000 mm to 300 mm after the addition of aluminum and lead. Similar effects were observed in EnviroBrass III after the addition of aluminum and bismuth. Boron refined the structure of yellow brasses in the presence of iron. At least 50 ppm of iron and 3 ppm of boron are necessary to cause grain refinement in these alloys. Precipitation of iron from the melt is identified as the cause of grain refinement. Boron initiates the precipitation of iron which could not be explained at this time. On the other hand zirconium causes some reduction in grain size in all four alloys investigated. The critical limit for the zirconium was found to be around 100 ppm below which not much refinement could be observed. The mechanism of grain refinement in the presence of zirconium could not be explained. Grain refinement by boron and iron can remain over a long period of time, at least for 72 hours of holding or after remelting few times. It is necessary to have the iron and boron contents above the critical limits mentioned earlier. On the other hand, refinement by zirconium is lost quite rapidly, some times within one hour of holding, mostly due to the loss of zirconium, most probably by oxidation, from the melt. In all the cases it is possible to revive the refinement by adding more of the appropriate refining element. Cooling curve analysis (thermal analysis) can be used successfully to predict the grain refinement in yellow brasses. The precipitation of iron in the liquid metal causes the metal to solidify without undercooling. Absence of this reaction, as indicated by the time-temperature (t-T) and its first derivative (dt/dT) curves, proved to be an indicator of refinement. The viability of the technique as an on-line quality control tool was proved in two foundries. The method can also correctly predict the onset of fading. Th

M. SADAYAPPAN, J.P. THOMSON, M.ELBOUJDAINI, G. PING GU, M. SAHOO

2004-04-29T23:59:59.000Z

437

(Data in thousand metric tons of copper content, unless otherwise noted) Domestic Production and Use: Domestic mine production in 2003 declined to 1.12 million tons and was valued at  

E-Print Network [OSTI]

54 COPPER (Data in thousand metric tons of copper content, unless otherwise noted) Domestic% of domestic production; copper was also recovered at mines in three other States. Although copper-electrowinning facilities operated during the year. Refined copper and direct melt scrap were consumed at about 30 brass

438

Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy  

SciTech Connect (OSTI)

Spark plasma sintering (SPS) is evolving as an attractive process for the processing of multi-component Fe-based bulk amorphous alloys and their in-situ nanocomposites with controlled primary nanocrystallization. Extended Q-range small angle neutron scattering (EQ-SANS) analysis, complemented by x-ray diffraction and transmission electron microscopy, was performed to characterize nanocrystallization behavior of SPS sintered Fe-based bulk amorphous alloys. The SANS experiments show significant scattering for the samples sintered in the supercooled region indicating local structural/compositional changes associated with the profuse nucleation of nanoclusters (?4 nm). For the samples spark plasma sintered near and above crystallization temperature (>653 °C), the SANS data show the formation of interference maximum indicating the formation and growth of (Fe,Cr){sub 23}C{sub 6} crystallites. The SANS data also indicate the evolution of bimodal crystallite distribution at higher sintering temperatures (above T{sub x1}). The growth of primary nanocrystallites results in impingement of concentration gradient fields (soft impingement effect), leading to non-random nucleation of crystallites near the primary crystallization.

Singh, Ashish; Harimkar, Sandip P. [School of Mechanical and Aerospace Engineering, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)] [School of Mechanical and Aerospace Engineering, Oklahoma State University, Stillwater, Oklahoma 74078 (United States); Katakam, Shravana; Dahotre, Narendra B. [Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203 (United States)] [Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203 (United States); Ilavsky, Jan [Advanced Photon Source, Argonne National Laboratory, Chicago, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Chicago, Illinois 60439 (United States)

2013-08-07T23:59:59.000Z

439

Categorical Exclusion Determinations: South Carolina | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

January 24, 2012 January 24, 2012 CX-007626: Categorical Exclusion Determination Lapeyre Stair Installation CX(s) Applied: B2.5 Date: 01/24/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office January 24, 2012 CX-007625: Categorical Exclusion Determination Flush Fire Water Distribution Lines to Remove Sediment CX(s) Applied: B1.3 Date: 01/24/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office January 24, 2012 CX-007624: Categorical Exclusion Determination Copper Catalyzed Peroxide Destruction of Tank 48H Tetraphenylborate Wastes CX(s) Applied: B3.6 Date: 01/24/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office January 23, 2012 CX-007973: Categorical Exclusion Determination Concrete Culverts Storage in K-Area

440

CX-006931: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

1: Categorical Exclusion Determination 1: Categorical Exclusion Determination CX-006931: Categorical Exclusion Determination Printed Circuit Board Through-Hole Plating, Masking, and Legending Process CX(s) Applied: B3.6 Date: 10/12/2011 Location(s): Aiken, South Carolina Office(s): Environmental Management, National Energy Technology Laboratory A MiniContac RS electrochemical plater is used to plate through-holes with copper between surface layers on electronic printed circuit boards. Additionally, a ProMask (solder mask) process and ProLegend (legend printing or silkscreening) are used to process the printed circuit boards. All equipment and chemical supplies are procured from LPKF Laser & Electronics. CX-006931.pdf More Documents & Publications CX-008648: Categorical Exclusion Determination

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

CX-007644: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

44: Categorical Exclusion Determination 44: Categorical Exclusion Determination CX-007644: Categorical Exclusion Determination Copper Catalyzed peroxide Destruction of Tank 48H Tetraphenylborate Wastes CX(s) Applied: B3.6 Date: 01/17/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office At the Savannah River Site (SRS), Tank 48H currently holds approximately 240,000 gallons of slurry which contains potassium and cesium tetraphenylborate (KTPB and CsTPB). Personnel must remove or destroy the organics before the tank space can be utilized or closed. Savannah River Remediation and Savannah River National Laboratory are tasked with studying the decomposition of TPB slurries via the use of catalysts and hydrogen peroxide. CX-007644.pdf More Documents & Publications CX-007624: Categorical Exclusion Determination

442

CX-007624: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

4: Categorical Exclusion Determination 4: Categorical Exclusion Determination CX-007624: Categorical Exclusion Determination Copper Catalyzed Peroxide Destruction of Tank 48H Tetraphenylborate Wastes CX(s) Applied: B3.6 Date: 01/24/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office At the Savannah River Site (SRS), Tank 48H currently holds approximately 240,000 gallons of slurry which contains potassium and cesium tetraphenylborate (KTPB and CsTPB). Personnel must remove or destroy the organics before the tank space can be utilized or closed. Savannah River Remediation and Savannah River National Laboratory are tasked with studying the decomposition of TPB slurries via the use of catalysts and hydrogen peroxide. CX-007624.pdf More Documents & Publications CX-007644: Categorical Exclusion Determination

443

CX-004354: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

54: Categorical Exclusion Determination 54: Categorical Exclusion Determination CX-004354: Categorical Exclusion Determination Alaska-Tribe-Village of Kotlik CX(s) Applied: A9, B2.5, B5.1 Date: 11/02/2010 Location(s): Kotlik, Alaska Office(s): Energy Efficiency and Renewable Energy Energy Efficiency and Conservation Block Grant Program. The Native Village of Kotlik proposes to 1) hire an employee to conduct energy efficiency and conservation audits and 2) purchase Environmental Protection Agency-approved wood stoves and fuel efficient burning stoves, copper fuel tubing and oil filters, compact fluorescent lights, porcelain lamp holders, and surge protectors for retrofitting homes in the Kotlik community. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-004354.pdf More Documents & Publications CX-004781: Categorical Exclusion Determination

444

Rapid sintering of TiO{sub 2} photoelectrodes using intense pulsed white light for flexible dye-sensitized solar cells  

SciTech Connect (OSTI)

Intense pulsed white light (IPWL) sintering was carried out at room temperature, which is suitable dye-sensitized solar cells (DSSCs) fabrication process on plastic substrates for the mass production. Five seconds irradiation of IPWL on TiO{sub 2} electrode significantly improves the photocurrent density and power conversion efficiency of DSSCs by more than 110% and 115%, respectively, compared to the DSSCs without IPWL treatment. These improvements were mainly attributed to the enhanced interconnection between the TiO{sub 2} nanoparticles induced by IPWL illumination, which is confirmed by the impedance spectra analysis.

Jin, Hwa-Young [Photo-Electronic Hybrids Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Department of Chemical and Biological Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 136-701 (Korea, Republic of); Kim, Jae-Yup; Ah Lee, Jin; Lee, Kwangsoo; Yoo, Kicheon; Lee, Doh-Kwon; Kim, BongSoo; Young Kim, Jin; Kim, Honggon; Jung Son, Hae [Photo-Electronic Hybrids Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Kim, Jihyun [Department of Chemical and Biological Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 136-701 (Korea, Republic of); Ah Lim, Jung, E-mail: jalim@kist.re.kr, E-mail: mjko@kist.re.kr [Interface Control Research Center, Future Convergence Research Division, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Jae Ko, Min, E-mail: jalim@kist.re.kr, E-mail: mjko@kist.re.kr [Photo-Electronic Hybrids Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Green School, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 136-701 (Korea, Republic of)

2014-04-07T23:59:59.000Z

445

Production of SiC-Al?b2?sO?b3 ?scomposites by pressureless sintering and hot isostatic pressing  

E-Print Network [OSTI]

phases in the section Si0 -SiC- 2 A14C3-A1203 of the system Al-C-Si-0 20 3. Schematic of die used in unidirectional pressing 22 4. Cold isostatic press 26 5. Graphite resistance furnace 28 6. Calibration curve for BGT-2 thermocouple 7. Calibration... profile . The green body is then placed into a high temperature furnace and sintered. In hot pressing the ceramic powders are loaded in poco graphite or zirconium carbide dies or molds. The mold is heated to the specified temperature...

Boros, Stephen

2012-06-07T23:59:59.000Z

446

Fundamental studies of the mechanisms of slag deposit formation: Studies on initiation, growth and sintering in the formation of utility boiler deposits: Topical technical report  

SciTech Connect (OSTI)

Three laboratory-scale devices were utilized to investigate the mechanisms of the initiation, growth and sintering process involved in the formation of boiler deposits. Sticking apparatus investigations were conducted to study deposit initiation by comparing the adhesion behavior of the ash drops on four types of steel-based heat exchanger materials under the conditions found in a utility boiler and an entrained slagging gasifier. In addition, the adhesion behavior of the ash drops on a reduced steel surface were investigated. All the ash drops studied in this investigation were produced from bituminous coals.

Tangsathitkulchai, M.; Austin, L.G.

1986-03-01T23:59:59.000Z

447

Infrared spectroscopic studies of carbon monoxide adsorbed on a series of silica-supported copper catalysts in different oxidation states  

SciTech Connect (OSTI)

Infrared spectroscopy has been used to study the adsorption of carbon monoxide (358-493 K, 0.1-20 kPa) on four copper-on-silica (2-10 wt% Cu) catalysts prepared by the ion-exchange technique. The measurements are made for each sample in three different states: unreduced (predominantly Cu{sup 2+}), and reduced (Cu{sup 0}), and partially reoxidized in nitrous oxide (Cu{sup +}). On unreduced samples, a major absorption band between 2127 and 2132 cm{sup {minus}1} due to CO adsorbed on small CuO particles and a weak band at 2199 cm{sup {minus}1} due to CO on isolated Cu{sup 2+} ions incorporated in the silica surface have been identified. The former adsorption obeys a Langmuir isotherm with a heat of adsorption of 29 kJ/mol independent of CuO particle size and surface coverage. After catalyst reduction, the major absorption band lies between 2090 and 2113 cm{sup {minus}1} and arises from CO linearly bound to very small (1- to 5-nm) copper metal clusters. The observed frequency shifts indicate the presence of steps and terraces similar to low index Cu planes in very small particles (1- to 2-nm), and the presence of similar higher index Cu planes on larger clusters (2- to 5-nm). The absorption is described by a Freundlich isotherm with the heat of CO adsorption decreasing with coverage from 50 to 22 kJ/mol on bigger particles but more constant (27 to 22 kJ/mol) on small particles. A surface copper/CO atomic ratio increasing from 5 to 12 is established at equilibrium saturation between 358 and 493 K using extinction coefficients determined in this study. In the reduced catalysts, a weakly adsorbed ({Delta}H{sub a} = {minus}20 kJ/mol) species assigned to CO bound to isolated Cu{sup +} ions is also found and absorbs at 2175 cm{sup {minus}1}. The frequency of this band does not vary with catalyst loading and is not affected by reoxidation of the catalyst in nitrous oxide.

Kohler, M.A.; Wainwright, M.S.; Trimm, D.L.; Cant, N.W. (Macquarie Univ., New South Wales (Australia) Univ. of South Wales (Australia))

1989-05-01T23:59:59.000Z

448

YSL16 Is a Phloem-Localized Transporter of the Copper-Nicotianamine Complex That Is Responsible for Copper Distribution in Rice  

Science Journals Connector (OSTI)

...plants and is needed to deliver Cu to the ethylene receptors (Hirayama et al., 1999...A., Newville, M., Choi, Y., Price, A.H., and Meharg, A.A. (2011...disease-related copper transporter, is required for ethylene signaling in Arabidopsis. Cell 97 : 383-393...

Luqing Zheng; Naoki Yamaji; Kengo Yokosho; Jian Feng Ma

2012-09-25T23:59:59.000Z

449

On-Line Sorting of Wood Treated with Chromated Copper Arsenate Using Laser-Induced Breakdown Spectroscopy  

Science Journals Connector (OSTI)

This paper details the design, implementation, and field evaluation of an online detector system using laser-induced breakdown spectroscopy (LIBS) for the analysis of copper...

Moskal, T M; Hahn, D W

2002-01-01T23:59:59.000Z

450

Structure-Activity Relationship in Nanostructured Copper-Ceria-Based Preferential CO Oxidation Catalysts  

SciTech Connect (OSTI)

Two series of nanostructured oxidized copper-cerium catalysts with varying copper loadings, and prepared, respectively, by impregnation of ceria and by coprecipitation of the two components within reverse microemulsions, have been characterized in detail at structural and electronic levels by X-ray diffraction (XRD), Raman spectroscopy, high-resolution electron microscopy (HREM), X-ray energy dispersive spectroscopy (XEDS), X-ray photoelectron spectroscopy (XPS) (including Ar{sup +}-sputtering), and X-ray absorption fine structure (XAFS). These results have been correlated with analysis of their catalytic properties for preferential oxidation of CO in a H{sub 2}-rich stream (CO-PROX), complemented by Operando-DRIFTS. A relevant difference between the two series of catalysts concerns the nature of the support for the surface-dispersed copper oxide entities, which is essentially ceria for the samples prepared by impregnation and a Ce-Cu mixed oxide for those prepared by microemulsion-coprecipitation. The existence of copper segregation in the form of copper oxide or copper-enriched Cu-Ce mixed oxides for the latter type of samples is uniquely revealed by nanoprobe XEDS and XPS Ar{sup +}-sputtering experiments. The CO oxidation activity under CO-PROX conditions is correlated to the degree of support-promoted reduction achieved by the dispersed copper oxide particles under reaction conditions. Nevertheless, catalysts which display higher CO oxidation activity are generally more efficient also for the undesired H{sub 2} oxidation reaction. The balance between both reactions results in differences in the CO-PROX activity between the two series of catalysts which are examined on the basis of the structural differences found.

Gamarra,D.; Munuera, G.; Hungria, A.; Fernandez-Garcia, M.; Conesa, J.; Midgley, P.; Wang, X.; Hanson, J.; Rodriguez, J.; Martinez-Arias, A.

2007-01-01T23:59:59.000Z

451

Part I, copper(I) iodide dimethyl sulfide catalyzed 1,4- addition of alkenyl groups from alkenylzirconium and alkenylzinc reagents and their application toward the total synthesis of azaspirene : Part II, aqueous Wittig chemistry employing stabilized ylides and aldehydes  

E-Print Network [OSTI]

50, 1935-1954. A few stable copper(III) species have beenS. ; Bergdahl, M. Direct Copper(I) Iodide Dimethyl SulfideBatta, A. ; Bergdahl, M. Copper(I) Iodide Dimethyl Sulfide

El-Batta, Amer Adnan

2007-01-01T23:59:59.000Z

452

On the effects of common pollutants on the corrosion of copper-nickel alloys in sulfide polluted seawater  

SciTech Connect (OSTI)

Various pollutants are often introduced in seawater by wet and dry deposition and by improper dumping of municipal wastewater. These pollutants often affect the corrosivity of seawater on copper-based alloys which might be thought to be resistant in this environment and do not receive sufficient research efforts. In the present investigation the effect was determined of some common pollutants such as urea, sodium sulfite, sodium nitrate, sodium phosphate, copper sulfate, lead acetate, ammonium sulfate, and ammonium chloride at a level of 10 ppm and of chlorine at 1 ppm concentration on the corrosion characteristics of the 90Cu-10Ni and the 70Cu-30Ni alloys in seawater, both in the presence and in the absence of 10 ppm sulfide. Both small amplitude cyclic voltammetry (SACV) and the Tafel extrapolation technique were employed as test procedures. All pollutants under investigation have led to an increase in corrosion rate and their effect was more pronounced when sulfide was also present. The effects of pollutants were more intense on 90Cu-10Ni as compared to 70Cu-30Ni alloys. In unpolluted seawater, the worst pollutant for 90Cu-10Ni alloy is sulfide followed by urea and chlorine while for the 70Cu-30Ni alloy, the worst pollutant was ammonium chloride followed by sulfide and sodium phosphate. In unpolluted seawater, the introduction of pollutants led to a corrosion reaction which was under cathodic control except for sulfide where the reaction was under anodic control and resulted in a sharp negative shift in the corrosion potential. In sulfide polluted seawater, the worst pollutant for 90Cu-10Ni alloy was ammonium sulfate followed by urea while for 70Cu-30Ni alloy, the worst pollutant was urea followed by ammonium chloride, ammonium sulfate, and sulfite ions.

Alhajji, J.N.; Reda, M.R. [Kuwait Univ., Safat (Kuwait)

1995-09-01T23:59:59.000Z

453

Iron and copper accumulation in the brain of coxsackievirus-infected mice exposed to cadmium  

SciTech Connect (OSTI)

Cadmium (Cd) is a potentially toxic metal widely distributed in the environment and known to cause adverse health effects in humans. During coxsackievirus infection, the concentrations of essential and nonessential trace elements (e.g., iron (Fe), copper (Cu), and Cd) change in different target organs of the infection. Fe and Cu are recognized cofactors in host defence reactions, and Fe is known to be associated with certain pathological conditions of the brain. However, whether nonessential trace elements could influence the balance of essential trace elements in the brain is unknown. In this study the brain Fe, Cu, and Cd contents were measured through inductively coupled plasma mass spectrometry and their distributions determined by nuclear microscopy in the early phase (day 3) of coxsackievirus B3 (CB3) infection in nonexposed and in Cd-exposed female Balb/c mice. In CB3 infection the brain is a well-known target that has not been studied with regard to trace element balance. The brain concentration of Cu compared with that of noninfected control mice was increased by 9% (P<0.05) in infected mice not exposed to Cd and by 10% (not significant) in infected Cd-exposed mice. A similar response was seen for Fe, which in infected Cd-exposed mice, compared to noninfected control mice, tended to increase by 16%. Cu showed an even tissue distribution, whereas Fe was distributed in focal deposits. Changes in Cd concentration in the brain of infected mice were less consistent but evenly distributed. Further studies are needed to define whether the accumulation and distribution of trace elements in the brain have an impact on brain function.

Ilbaeck, N.-G. [Section of Infectious Diseases, Department of Medical Sciences, Uppsala University Hospital, S-751 85 Uppsala (Sweden) and Toxicology Division, National Food Administration, Uppsala (Sweden)]. E-mail: nils-gunnar.ilback@slv.se; Lindh, U. [Research in Metal Biology, Rudbeck Laboratory, Uppsala University, Uppsala (Sweden); Minqin, R. [Centre for Ion Beam Applications, Department of Physics, National University of Singapore (Singapore); Friman, G. [Section of Infectious Diseases, Department of Medical Sciences, Uppsala University Hospital, S-751 85 Uppsala (Sweden); Watt, F. [Centre for Ion Beam Applications, Department of Physics, National University of Singapore (Singapore)

2006-11-15T23:59:59.000Z

454

Transport of copper ammines through a cation-exchange membrane during electrodialysis  

SciTech Connect (OSTI)

Extraction of copper ammine complexes from waste waters in electroplating technology and in production of cuprammonium fibers is an important problem and electrodialysis with ion-exchange membranes is the most promising method of solving it. The authors aim was to study transport of copper(II) ammines through a commercial cation-exchange membrane of the MK-40 type. The electrodialyzer consisted of five Plexiglas compartments separated in alternating order by MK-40 cation-exchange and MA-40 anion-exchange membranes. The authors studied the dependence of the transport of copper(II) ammine complexes on the current density at copper concentration 0.025 M in the desalination compartment and 0.15 M ammonia concentration. The experiments lead to the conclusion that electrodialysis of copper(II) ammine complexes is possible only at current densities below the limiting values and that the transport is accompanied by decrease of the formation function of the complexes both in the membrane and in the solution of the concentrate receiving compartment.

Kireeva, L.D.; Shaposhnik, V.A.; Sorokina, V.I.

1987-09-10T23:59:59.000Z

455

Sintered Superhard Materials  

Science Journals Connector (OSTI)

...BUNDY, F.P., K NED AKAD WET AMS B 72 : 302 ( 1969...Poissonrswea compact Comof verse corn Simple Knoop velocity ratio...000 Cemented carbide 9 Milling oftype 380 aluminum line...1963); K. Ned. Akad. Wet.-Amsterdam Proc. Ser...

R. H. Wentorf; R. C. DeVries; F. P. Bundy

1980-05-23T23:59:59.000Z

456

CX-004150: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

50: Categorical Exclusion Determination 50: Categorical Exclusion Determination CX-004150: Categorical Exclusion Determination High Capacity Manufacturing of Non-Contact, Printable Metallic Inks for Silicon Solar Cells CX(s) Applied: B3.6, B5.1 Date: 09/14/2010 Location(s): Austin, Texas Office(s): Energy Efficiency and Renewable Energy Electrical contacts are a critical part of photovoltaic technology and in particular represent a difficult and costly area for silicon solar cell production. In particular, it would be desirable to non-contact printing processes which would be much more cost effective, environmentally benign and materials efficient compared with existing manufacturing methods. Although such printing methods have proved successful for silver and for nickel/copper top contacts, silver is too expensive and the use of a nickel

457

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

January 17, 2012 January 17, 2012 CX-007644: Categorical Exclusion Determination Copper Catalyzed peroxide Destruction of Tank 48H Tetraphenylborate Wastes CX(s) Applied: B3.6 Date: 01/17/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office January 17, 2012 CX-007543: Categorical Exclusion Determination Laboratory Demonstration of a New American Low-Head Hydropower Turbine CX(s) Applied: B3.6 Date: 01/17/2012 Location(s): Illinois Offices(s): Golden Field Office January 13, 2012 CX-007975: Categorical Exclusion Determination Washington River Protection Solutions and Advanced Technologies and Laboratories International- Proposed Actions For Calendar Year 2012 Scheduled To Take Place CX(s) Applied: B3.6 Date: 01/13/2012 Location(s): Washington Offices(s): River Protection-Richland Operations Office

458

CX-002207: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

07: Categorical Exclusion Determination 07: Categorical Exclusion Determination CX-002207: Categorical Exclusion Determination Thin Films for Whisker Growth CX(s) Applied: B3.6 Date: 04/16/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office Thin films of industrial available low melting point metals and metal alloys (e.g. SAC 305, SAC 105, SnBi58 (Tin-Bismuth), SnPb (Tin-Lead)) will be deposited onto foils or plates of metals (e.g. Aluminum, Copper, Alloy 42). Each sample will be 0.5x2.0 inches with a 10 micron thick coating of the low melting point metal. The samples will be run through multiple characterization tests including Sable systems oxygen analyzer, laser curvature, and x-ray diffraction to test for the amount of oxygen absorbed

459

CX-002541: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

41: Categorical Exclusion Determination 41: Categorical Exclusion Determination CX-002541: Categorical Exclusion Determination Emerging Renewables Industries: Copper, Indium, Gallium, Selenium (CIGS) Linear Source Thermal Deposition CX(s) Applied: B2.2, B5.1 Date: 05/19/2010 Location(s): St. Paul, Minnesota Office(s): Energy Efficiency and Renewable Energy, Golden Field Office The State of Minnesota plans to provide $800,000 in Recovery Act funds to Veeco Instrument, Inc. at 4900 Constellation Drive, St. Paul, Minnesota 55127 for the purchase of equipment and related activities in the manufacturing of thin film solar panels. Veeco Instruments, Inc. is a provider of process and metrology equipment used to manufacture data storage, semiconductor, wireless, lighting and solar equipment. Veeco's St.

460

CX-001737: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

1737: Categorical Exclusion Determination 1737: Categorical Exclusion Determination CX-001737: Categorical Exclusion Determination Complete Fiber/Copper Cable Solution for Long-Term Temperature and Pressure Measurement in Supercritical Reservoirs and Enhanced Geothermal System Wells CX(s) Applied: B3.6, B3.11 Date: 03/31/2010 Location(s): Massachusetts Office(s): Energy Efficiency and Renewable Energy, Golden Field Office Department of Energy and recipient cost share funds will be used by Draka Cableteq USA (Draka) to develop a complete, multi-purpose cable solution for long-term deployment in geothermal wells/reservoirs that can be used with the widest variety of sensors. This cable will incorporate specialty optical fibers, with specific glass chemistry and high temperature and pressure protective coatings for data communication and distributed

Note: This page contains sample records for the topic "determination sintered copper" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

CX-008831: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

31: Categorical Exclusion Determination 31: Categorical Exclusion Determination CX-008831: Categorical Exclusion Determination Algaecide Use at Wastewater Treatment Facility - Amendment 01 CX(s) Applied: B1.3 Date: 08/07/2012 Location(s): Texas Offices(s): Pantex Site Office This amended action would allow the use of an additional algaecide, AgriTec® 2, to control algae at the Wastewater Treatment Facility and in the Sub-surface Drip Irrigation System. The AgriTec® is a copper sulfate based algaecide that would remain in solution and provide a more even dispersal for better control of the algae than the previously approved Cutrine® Plus. The AgriTec® 2 would be applied separately to the facultative lagoon, each holding lagoon, and the drip irrigation system to control the algae. The application rates would be in accordance with the

462

Effect of pressure on the behavior of copper-, iron-, and nickel-based oxygen carriers for chemical-looping combustion  

SciTech Connect (OSTI)

This work analyzes the main characteristics related to the chemical looping combustion (CLC) process necessary to use the syngas obtained in an integrated gasification combined cycle (IGCC) power plant. The kinetics of reduction with H{sub 2} and CO and oxidation with O{sub 2} of three high-reactivity oxygen carriers used in the CLC system have been determined in a thermogravimetric analyzer at atmospheric pressure. The iron- and nickel-based oxygen carriers were prepared by freeze-granulation, and the copper-based oxygen carrier was prepared by impregnation. The changing grain size model (CGSM) was used for the kinetic determination, assuming spherical grains for the freeze-granulated particles containing iron and nickel and a platelike geometry for the reacting surface of the copper-based impregnated particles. The dependence of the reaction rates on temperature was low, with the activation energy values varying from 14 to 33 kJ mol{sup -1} for the reduction and 7 to 15 kJ mol{sup -1} for the oxidation. The reaction order depended on the reacting gas and oxygen carrier, with values ranging from 0.25 to 1. However, an increase in the operating pressure for the IGCC + CLC system increases the thermal efficiency of the process, and the CO{sub 2} is recovered as a high pressure gas, decreasing the energy demand for further compression. The effect of pressure on the behavior of the oxygen carriers has been analyzed in a pressurized thermogravimetric analyzer at 1073 K and pressures up to 30 atm. It has been found that an increase in total pressure has a negative effect on the reaction rates of all the oxygen carriers. Moreover, the use of the CGSM with the kinetic parameters obtained at atmospheric pressure predicted higher reaction rates than those experimentally obtained at higher pressures, and therefore, the kinetic parameters necessary to design pressurized CLC plants must be determined at the operating pressure. 34 refs., 8 figs., 2 tabs.

Francisco Garcia-Labiano; Juan Adanez; Luis F. de Diego; Pilar Gayan; Alberto Abad [Instituto de Carboquimica (CSIC), Zaragoza (Spain). Department of Energy and Environment

2006-02-01T23:59:59.000Z

463

Effects of low temperature annealing on the adhesion of electroless plated copper thin films in TiN deposited silicon integrated circuit substrates  

E-Print Network [OSTI]

The semiconductor manufacturing industry is increasingly using copper to design and fabricate faster and smaller integrated circuits. Despite copper's electrical advantages, few ways exist to deposit it uniformly into the steep vias and trenches...

Tate, Adam Timothy

2013-02-22T23:59:59.000Z

464

A Copper Crystal Lens for Ultra-High-Sensitivity Medical Imaging  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Copper Crystal Lens for Ultra-High-Sensitivity Medical Imaging A Copper Crystal Lens for Ultra-High-Sensitivity Medical Imaging A copper crystal lens developed at the Advanced Photon Source represents a new and promising approach in nuclear medicine for imaging very small tumors in the human body with higher sensitivity and higher spatial resolution than the cameras now in use. Conceptual view of the 6-lens array system. This system would provide sufficient data to generate a 3-dimensional image of a tumor. Conceptual view of the 6-lens array system. This system would provide sufficient data to generate a 3-dimensional image of a tumor. The lens is designed to focus gamma-ray energies of 100 to 200 keV, which makes it ideal for focusing the 140.6-keV gamma rays from Technetium-99m typically used in radioactive tracers. This new approach to medical imaging

465

New Physics in a Copper-Iridium Compound | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Key Target for Diabetes Drugs A Key Target for Diabetes Drugs Molten Metal Solidifies into a New Kind of Glass Organic Polymers Show Sunny Potential A New Family of Quasicrystals Cool Muscles: Storing Elastic Energy for Flight Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed New Physics in a Copper-Iridium Compound August 6, 2013 Bookmark and Share (a) Cu-Ir chain of Sr3CuIrO6. Oxygen atoms surround both copper (Cu2+) and iridium (Ir4+) cations (ions positively charged due to the loss of electrons to the oxygen atoms, which become negatively-charged anions). The copper cation forms a planar arrangement with the surrounding oxygen anions, while the iridium cation resides at the center of an octahedral

466

Diffusivity of hydrogen in dilute alloys of copper and niobium in palladium  

Science Journals Connector (OSTI)

An electrochemical technique has been used to measure the diffusion coefficient of hydrogen in palladium-copper and palladium-niobium alloys between 0 and 50°C. The range of concentration for the copper and niobium additions was 0–10 at.%. For all experiments the hydrogen content was kept below 0.1 at.% and it was found that the diffusivity of hydrogen is remarkably decreased by additions of niobium. This behavior is discussed within the framework of different trapping models. In agreement with these models no dependence of the diffusivity on hydrogen concentration was observed. Copper additions also decrease the hydrogen diffusivity in palladium, but the effect is less pronounced than niobium. A measurable change of the activation energy of diffusion was observed only for the niobium alloy with the highest niobium content of 6.5 at.%. The activation energy increased by abour 7 kJ/mol compared to pure palladium.

Reiner Kirchheim; Rex B. McLellan

1980-01-01T23:59:59.000Z

467

High Strain-Rate Mechanical Behaviour of a Copper Matrix Composite for Nuclear Applications  

E-Print Network [OSTI]

Aim of this work is the investigation of mechanical behaviour of an alumina dispersion strengthened copper, known by the trade name GLIDCOP®, subjected to dynamic loads: it is a composite material with a copper matrix strengthened with aluminium oxide ceramic particles. Since the particle content is quite small the material keeps the OFE copper physical properties, such as thermal and electrical conductivity, but with a higher yield strength, like a mild-carbon steel. Besides, with the addition of aluminium oxide, the good mechanical properties are retained also at high temperatures and the resistance to thermal softening is increased: the second phase blocks the dislocation movement preventing the grain growth. Thanks to these properties GLIDCOP® finds several applications in particle accelerator technologies, where problems of thermal management, combined with structural requirements, play a key role. Currently, it is used for the construction of structural and functional parts of the particle beam collim...

Peroni, L

2012-01-01T23:59:59.000Z

468

Copper waveguide cavities with reduced surface loss for coupling to superconducting qubits  

E-Print Network [OSTI]

Significant improvements in superconducting qubit coherence times have been achieved recently with three-dimensional microwave waveguide cavities coupled to transmon qubits. While many of the measurements in this direction have utilized superconducting aluminum cavities, other recent work has involved qubits coupled to copper cavities with coherence times approaching 0.1 ms. The copper provides a good path for thermalizing the cavity walls and qubit chip, although the substantial cavity loss makes conventional dispersive qubit measurements challenging. We are exploring various approaches for improving the quality factor of three-dimensional copper cavities, including electropolishing and coating with superconducting layers of tin. We have characterized these cavities on multiple cooldowns and found the tin-plating to be robust. In addition, we have performed coherence measurements on transmon qubits in these cavities and observed promising performance.

Daniela F. Bogorin; D. T. McClure; Matthew Ware; B. L. T. Plourde

2014-09-10T23:59:59.000Z

469

Modeling of interface cracking in copper–graphite composites by MD and CFE method  

Science Journals Connector (OSTI)

Abstract Molecular dynamics (MD) method was used to study mechanical properties of copper–graphite composite interface. Mode I fracture of the interface of copper–graphite composite was modeled by considering fixed and free boundary conditions, which means slipping constraint conditions for atomic layers in the composite. The stress near crack tip and the energy changes of the system are obtained. Then a cohesive traction–separation law of copper–graphite interface can also be obtained by using the MD simulation. For the purpose of comparisons, a modeling of interfacial fracture of the composite by using a zero-thickness cohesive finite element (CFE) was carried out. It is found that there is a stress concentration but no singularity for the normal stress at the crack tip in interface obtained by using the present MD simulation and CFE method. While in the interface away from the crack tip, the obtained stress is consistent with the solution of classical interfacial fracture mechanics.

Shi-Jun Guo; Qing-Sheng Yang; X.Q. He; K.M. Liew

2014-01-01T23:59:59.000Z

470

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor  

Science Journals Connector (OSTI)

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor ... Several groups using different flavonoids, such as quercetin, catechin, morin, rutin, fisetin, and gossypetin, also showed that flavonoids could inhibit copper-catalyzed and macrophage-mediated LDL oxidation (13?16). ... morin and fisetin 1 ?M; quercetin and gossypetin 2 ?M). ...

Miao-Jane Lee; Fen-Pi Chou; Tsui-Hwa Tseng; Ming-Hsun Hsieh; Ming-Cheng Lin; Chau-Jong Wang

2002-02-16T23:59:59.000Z

471

Old wood -new investigations. Dendrochronological results on mining timber from the prehistoric copper mine Kelchalm/Kitzbhel  

E-Print Network [OSTI]

copper-mining areas in the northern part of the Eastern Alps (map: Alpen Reliefkarte - Tirol Atlas (pichier et al. 2009). #12;Pichier et al. (TRACE Vol. 9) 123 Figure 2: Arial view of the Kelchalm copper. (TRACE Val. 9) (Nicolussi et al., 2009) which covers the last 9111 years and consists of sampies

Nicolussi, Kurt

472

Control of Black Spot of Roses with Sulphur-Copper Dust.  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, Director College Station, Texas BULLETIN NO. 648 APRIL, 1944 CONTROL OF BLACK SPOT OF ROSES WITH SULPHUR-COPPER DUST E. W. LYLE Division of Plant Pathology and Physiology l ,i- ' 7, r... - . /.~ric[~i L~jj c,, J: . i, , . t : :V~S @ollogs Stat hn, ieias AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS F. C. BOLTON, Acting President D-16-444-4M Fig. 1. Rose plants from commercial fields. On left, plant dusted with sulphur-copper mix- ture...

Lyle, E. W. (Eldon W.)

1944-01-01T23:59:59.000Z

473

The connection between the damping capacity and the crystal structure of some copper-manganese alloys  

E-Print Network [OSTI]

THE CONNECTION BETHEEN THE DANPIING CAPACIITY AND THE CRYSTAL STRUCTURE OF SOME COPPER-MANGANESE ALLOYS A Thesis By Leon Eldon McCrary Submitted to the Graduate School of the Agricultural and Mechanlcai College of Texas ln partial fulfil... lment of the requirements for the degree of MASTER OF SCIIENCE August 'l960 Major Sub)ect: Physics THE CONNECTION BETWEEN THE DAMPING CAPACITY AND THE CRYSTAL STRUCTURE OF SOME COPPER-MANGANESE ALLOYS A Thesis By Leon E I don McC ra ry Approved...

McCrary, Leon Eldon

1960-01-01T23:59:59.000Z

474

Behavior of palladium-copper catalysts for CO and NO elimination  

SciTech Connect (OSTI)

The behavior of a series of palladium and palladium-copper catalysts supported on ceria/alumina for the CO + NO + O{sub 2} reaction has been analyzed by a combination of electron transmission microscopy, infrared, and electron paramagnetic spectroscopies and catalytic test studies. In both systems, the catalytic behavior is dominated by the properties of the metal-ceria interface. The addition of copper to a palladium system leads to beneficial effects related to alloy formation in which both CO and NO elimination are enhanced. The chemical consequences and catalytic implications of Pd-Cu alloying are discussed.

Fernandez-Garcia, M.; Martinez-Arias, A.; Belver, C.; Anderson, J.A.; Conesa, J.C.; Soria, J.

2000-03-10T23:59:59.000Z

475

Growth and characterization of copper nanoclusters embedded in SiCmatrix  

SciTech Connect (OSTI)

Nanocrystalline copper clusters embedded in silicon carbidewere made by island growth during sputter deposition. The distributionand morphology of metal clusters were observed by high-resolutiontransmission electron microscopy. To investigate chemical bonding at thecopper silicon carbide interface, we studied the electronic states ofcopper and silicon using X-ray photoelectron spectroscopy (XPS). It wasfound that the formation of copper silicide was suppressed in this systemand that small shifts in binding energy were observed for different sizesof clusters, which was different from the chemical shift for coppersilicide formation.

Shin, Dong-Woon; Wang, Shan, X.; Marshall, Ann F.; Kimura,Wataru; Dong, Chungli; Augustsson, A.; Guo, Jinghua

2006-01-20T23:59:59.000Z

476

Surface Functionalization of Thin-Film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties  

Science Journals Connector (OSTI)

Copper is one such alternative, having a long history (>2400 years) as an effective biocide,(26) and both copper ions and nanoparticles (Cu-NPs) have demonstrated antibacterial activity against numerous bacterial strains. ... The MDMH-modified membranes were shown to possess high chlorine resistances with small changes in water fluxes and salt rejections after chlorination with 100-2000 ppm h chlorine at pH 4. The chlorinated MDMH-modified membranes demonstrated obvious sterilization effects on Escherchia coli and substantial preventions against microbial fouling. ...

Moshe Ben-Sasson; Katherine R. Zodrow; Qi Genggeng; Yan Kang; Emmanuel P. Giannelis; Menachem Elimelech

2013-12-05T23:59:59.000Z

477

The influence of chloride ions on the corrosion of copper in soil  

E-Print Network [OSTI]

THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RA JU K . H I RAN I Submitted to the Graduate College of Texas ASM University in Partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May... 1980 Major Subject: Chemical Engineering THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RAJU K. HIRANI Approved as to style and content by: (Chairman of Committee) '(2. (Member ) (Member) (Member) ( ea o Dep...

Hirani, Raju K

2012-06-07T23:59:59.000Z

478

Effect of copper and iron on the oxidative flavor deterioration of ice cream  

E-Print Network [OSTI]

for the degree of "ASTER CP SCIENCE Jhnuary I~ Nc )or Sub)catt Dairy &~actures EFFECT GF COFFER ARD IRON CR Tlm OXIDATIVE FLAVOR DETKRI/Z'TJ ' CF ICE CRE//P A Thesis Pi? Pbdul Hasid 'Pish Approved as to style and content by: I /'i'I /' ' / , r... Archihald (2? 3) reported results cf cariiar studies on the effect oi' feed and added coppex' or iron or. the coppex' and iron content of milk. Cn tne lamia of these earlier ?tudiss the effect of feeding supplemental copper and iron on the copper...

Miah, Md. Abdul Hamid

1961-01-01T23:59:59.000Z

479

Low resistance barrier layer for isolating, adhering, and passivating copper metal in semiconductor fabrication  

SciTech Connect (OSTI)

Cubic or metastable cubic refractory metal carbides act as barrier layers to isolate, adhere, and passivate copper in semiconductor fabrication. One or more barrier layers of the metal carbide are deposited in conjunction with copper metallizations to form a multilayer characterized by a cubic crystal structure with a strong (100) texture. Suitable barrier layer materials include refractory transition metal carbides such as vanadium carbide (VC), niobium carbide (NbC), tantalum carbide (TaC), chromium carbide (Cr.sub.3 C.sub.2), tungsten carbide (WC), and molybdenum carbide (MoC).

Weihs, Timothy P. (Baltimore, MD); Barbee, Jr., Troy W. (Palto Alto, CA)

2002-01-01T23:59:59.000Z

480

J. Phys. III Yance 7 (1997) 1495-1503 JULY 1997, PAGE 1495 Interaction of Copper with Dislocations in GaAs  

E-Print Network [OSTI]

. The interaction of copper with dislocations was studied in silicon-doped gallium arsenide by means growth or subsequent processing steps ill. In gallium arsenide, copper has two levels in the band gap solubility of Cu in GaAs at room temperature. The electrically inactive copper forms precipitates [3

Boyer, Edmond

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481

A New Copper-Catalyzed [3 + 2] Cycloaddition: Enantioselective Coupling of Terminal Alkynes with Azomethine Imines To Generate Five-Membered  

E-Print Network [OSTI]

A New Copper-Catalyzed [3 + 2] Cycloaddition: Enantioselective Coupling of Terminal Alkynes(I)-catalyzed 1,3-dipolar cycloadditions to terminal alkyness presumably proceeding via a copper acetylideshave, copper-catalyzed processes can overcome the poor regioselectivity observed in some of the corresponding

Fu, Gregory C.

482

Experimental and Computational Evidence of MetalO2 Activation and Rate-Limiting Proton-Coupled Electron Transfer in a Copper  

E-Print Network [OSTI]

-Coupled Electron Transfer in a Copper Amine Oxidase Yi Liu, Arnab Mukherjee, Nadav Nahumi, Mehmet Ozbil,§ Doreen 33146, United States *S Supporting Information ABSTRACT: The mechanism of O2 reduction by copper amine of copper amine oxidases, O2 reduction to H2O2 is physiologically significant,17 serving diverse functions

Roth, Justine P.

483

FAST Copper For Broadband Access Mung Chiang1, Jianwei Huang1, Dahai Xu1, Yung Yi1, Chee Wei Tan1, Raphael Cendrillon2  

E-Print Network [OSTI]

FAST Copper For Broadband Access Mung Chiang1, Jianwei Huang1, Dahai Xu1, Yung Yi1, Chee Wei Tan1 Abstract-- This is an overview of the ongoing FAST Copper project, which is aimed at substantial improvements in rate, reach, reliability, and quality in copper-last-mile broadband access through fiber

Yi, Yung

484

A novel copper(II)-Schiff base complex containing pyrrole ring: Synthesis, characterization and its modified electrodes applied in oxidation of aliphatic alcohols  

E-Print Network [OSTI]

1 A novel copper(II)-Schiff base complex containing pyrrole ring: Synthesis, characterization 35042 Rennes Cedex, France. Abstract A new copper(II) complex Cu(II)-L containing N2O2 donor atoms has of copper acetate monohydrate. It was characterized by spectroscopic methods such as FT-IR, UV­vis, mass

Boyer, Edmond

485

Determination of the Kink Formation Energy and Step-Step Interaction Energy for Vicinal Copper Faces by Thermal Roughening Studies  

Science Journals Connector (OSTI)

It is well known that when the surface temperature is raised, surface disorder increases, adatoms and vacancies are created and, in some cases, the roughening transition is reached before the bulk melting. ... go...

F. Fabre; B. Salanon; J. Lapujoulade

1988-01-01T23:59:59.000Z

486

Agglomeration and sintering in annealed FePt nanoparticle assemblies studied by small angle neutron scattering and x-ray diffraction  

Science Journals Connector (OSTI)

In this work we give a detailed account of complementary small angle neutron scattering and x-ray diffraction studies of polymer mediated, self-assembled FePt nanoparticle arrays as a function of annealing temperature. The combination of these two techniques provides significantly greater physical insight than is available using either individually. Since both methods integrate over a large number of particles statistically meaningful data can be obtained in contrast to imaging techniques where typically only small areas are analyzed. The data show that the median particle size increases with annealing at temperatures of 580°C and above. The data also demonstrate that the distribution of particle diameters is significant and increases with annealing temperature. These results allow a comprehensive structural model of the annealed assemblies to be developed in terms of particle sintering and agglomeration. This enhanced understanding will allow new strategies to be pursued in realizing the potential of nanoparticle assemblies as a monodispersed data storage medium.

T. Thomson; S. L. Lee; M. F. Toney; C. D. Dewhurst; F. Y. Ogrin; C. J. Oates; S. Sun

2005-08-19T23:59:59.000Z

487

What determines cell size?  

E-Print Network [OSTI]

as: Marshall WF, et al. : What determines cell size? BMC7007/10/101 FORUM Open Access What determines cell size?biologists have been wondering what determines the size of

2012-01-01T23:59:59.000Z

488

CX-012214: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Copper Mountain-Pilot Butte 34.5 Kilovolt Transmission Line Structure Pole Replacement Project, Fremont County, Wyoming CX(s) Applied: B1.3 Date: 05/05/2014 Location(s): Wyoming Offices(s): Western Area Power Administration-Rocky Mountain Region

489

Laser cleaning of tarnished silver and copper threads in museum textiles Christian Degrigny a,  

E-Print Network [OSTI]

Laser cleaning of tarnished silver and copper threads in museum textiles Christian Degrigny a, 44306 Nantes cedex 3, France d Laser and Applications Division, Institute of Electronic Structure and Laser (IESL9), FORTH, Vasilika Vouton, P.O. Box 1527, Heraklion 71110, Crete, Greece Abstract Recent

Boyer, Edmond

490

History of Ancient Copper Smelting Pollution During Roman and Medieval Times Recorded in Greenland Ice  

Science Journals Connector (OSTI)

...1991), pp. 13-42. 27. Natural copper flux was calculated...fullerenes by searching for noble gases trapped inside the fullerene...correlation of C and trapped noble gas atoms in meteorites is well...contain several trapped noble gas components that have anomalous...

Sungmin Hong; Jean-Pierre Candelone; Clair C. Patterson; Claude F. Boutron

1996-04-12T23:59:59.000Z

491

Evaluation of copper for divider subassembly in MCO Mark IA and Mark IV scrap fuel baskets  

SciTech Connect (OSTI)

The K Basin Spent Nuclear Fuel (SNF) Project Multi-Canister Overpack (MCO) subprojection eludes the design and fabrication of a canister that will be used to confine, contain, and maintain fuel in a critically safe array to enable its removal from the K Basins, vacuum drying, transport, staging, hot conditioning, and interim storage (Goldinann 1997). Each MCO consists of a shell, shield plug, fuel baskets (Mark IA or Mark IV), and other incidental equipment. The Mark IA intact and scrap fuel baskets are a safety class item for criticality control and components necessary for criticality control will be constructed from 304L stainless steel. It is proposed that a copper divider subassembly be used in both Mark IA and Mark IV scrap baskets to increase the safety basis margin during cold vacuum drying. The use of copper would increase the heat conducted away from hot areas in the baskets out to the wall of the MCO by both radiative and conductive heat transfer means. Thus copper subassembly will likely be a safety significant component of the scrap fuel baskets. This report examines the structural, cost and corrosion consequences associated with using a copper subassembly in the stainless steel MCO scrap fuel baskets.

Graves, C.E.

1997-09-29T23:59:59.000Z

492

The effects of topology upon fluid-flow and heat-transfer within cellular copper structures  

E-Print Network [OSTI]

The effects of topology upon fluid-flow and heat-transfer within cellular copper structures J. Tian February 2004 Available online 20 March 2004 Abstract The fluid-flow and heat-transfer features of cellular and packed beds, but also a function of orientation (open area ratio). The overall heat transfer depends

Wadley, Haydn

493

Copper activation deuterium-tritium neutron yield measurements at the National Ignition Facility  

E-Print Network [OSTI]

, New Mexico 87131, USA 2 Sandia National Laboratories, Albuquerque, New Mexico 87185, USA 3 Lawrence Livermore National Laboratories, Livermore, California 94550, USA 4 Plasma Science and Fusion Center, MIT(+ ) and 65 Cu(n,2n) 64 Cu(+ ), has been fielded at the National Ignition Facility (NIF). The induced copper

494

(N-heterocyclic-carbene)Copper(I)-catalyzed carbon-carbon bond formation using carbon dioxide  

E-Print Network [OSTI]

This thesis presents work towards the development of a new catalytic C-C bond forming reaction. Alkynes and olefins insert into [(IPr)CuH]2 (IPr = N,N-bis-(2,6-diisopropylphenyl)-1,3-imidazol-2-ylidene) to give copper vinyl ...

Sirokman, Gergely

2007-01-01T23:59:59.000Z

495

Copper Induces Cytoplasmic Retention of Fission Yeast Transcription Factor Cuf1  

Science Journals Connector (OSTI)

...copper-dependent manner by two-hybrid assay. (A) Schematic diagram...grant MOP-36450 to S.L. Infrastructure equipment that was essential...helix-loop-helix proteins with a two-hybrid system. Mol. Cell. Biol...interacting proteins with the two-hybrid system II, p. 29-42. In...

Jude Beaudoin; Simon Labbé

2006-02-01T23:59:59.000Z

496

Iron(II) and Copper(I) Coordination Polymers: Electrochromic Materials with and without Chiroptical Properties  

E-Print Network [OSTI]

Iron(II) and Copper(I) Coordination Polymers: Electrochromic Materials with and without Chiroptical of deterioration over 150 switching cycles. Additionally, in an effort to assemble an electrochromic device with chiroptical properties, the electrochromism of films generated from the enantiomerically pure CTPCT[FeII CTPCT

Bernhard, Stefan

497

The Bacterial Pathogen Xanthomonas oryzae Overcomes Rice Defenses by Regulating Host Copper Redistribution  

Science Journals Connector (OSTI)

...Figure 5B). Another explanation is that excess Cu is toxic to rice cells, which may...TRP1, lys2-801,his3) using the lithium acetate procedure (Pena et al., 1998...physiological, and structural effects of excess copper in plants. Bot. Rev. 57 : 246-273...

Meng Yuan; Zhaohui Chu; Xianghua Li; Caiguo Xu; Shiping Wang

2010-09-17T23:59:59.000Z

498

Investigations at Tal-i Iblis : evidence for copper smelting during the Chalcolithic period  

E-Print Network [OSTI]

This thesis examines a small corpus of artifacts from Tal-i Iblis, Iran dating to the mid-6th millennium BCE. When excavated in the late 1960s, these artifacts were presumed to be evidence of an early copper smelting ...

Frame, Lesley (Leslie Diana)

2004-01-01T23:59:59.000Z

499

Structure Effects on the Energetics of the Electrochemical Reduction of CO2 by Copper Surfaces  

SciTech Connect (OSTI)

Polycrystalline copper electrocatalysts have been experimentally shown to be capable of reducing CO{sub 2} into CH{sub 4} and C{sub 2}H{sub 4} with relatively high selectivity, and a mechanism has recently been proposed for this reduction on the fcc(211) surface of copper, which was assumed to be the most active facet. In the current work, we use computational methods to explore the effects of the nanostructure of the copper surface and compare the effects of the fcc(111), fcc(100) and fcc(211) facets of copper on the energetics of the electroreduction of CO{sub 2}. The calculations performed in this study generally show that the intermediates in CO{sub 2} reduction are most stabilized by the (211) facet, followed by the (100) facet, with the (111) surface binding the adsorbates most weakly. This leads to the prediction that the (211) facet is the most active surface among the three in producing CH{sub 4} from CO{sub 2}, as well as the by-products H{sub 2} and CO. HCOOH production may be mildly enhanced on the more close-packed surfaces ((111) and (100)) as compared to the (211) facet, due to a change in mechanism from a carboxyl intermediate to a formate intermediate. The results are compared to experimental data on these same surfaces; the predicted trends in voltage requirements are consistent between the experimental and computational data.

Durand, William

2011-08-19T23:59:59.000Z

500

Copper modified austenitic stainless steel alloys with improved high temperature creep resistance  

DOE Patents [OSTI]

An improved austenitic stainless steel that incorporates copper into a base Fe-Ni-Cr alloy having minor alloying substituents of Mo, Mn, Si, T, Nb, V, C, N, P, B which exhibits significant improvement in high temperature creep resistance over previous steels. 3 figs.

Swindeman, R.W.; Maziasz, P.J.

1987-04-28T23:59:59.000Z