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Note: This page contains sample records for the topic "determination install metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Determining the return of energy efficiency investments in domestic and deployed military installations .  

E-Print Network (OSTI)

??The purpose of this research is to determine the return on energy efficiency investments in domestic installations and military forward operating bases. This research considers… (more)

Gammache, Nathan J.

2007-01-01T23:59:59.000Z

2

Installation of reactive metals groundwater collection and treatment systems  

SciTech Connect

Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan`s Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium.

Hopkins, J.K.; Primrose, A.L. [Rocky Mountain Remediation Services, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site; Vogan, J. [EnviroMetal Technologies, Inc., Guelph, Ontario (Canada); Uhland, J. [Kaiser-Hill, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site

1998-07-01T23:59:59.000Z

3

Determining Ductile Fracture Toughness in Metals  

SciTech Connect

Ductile fracture toughness determination, such as the J-integral versus crack growth resistance (J-R) curve, is a useful tool for evaluating material structural integrity in the presence of pre-existing defects. The J-R curve represents a way to calculate the work (energy) per unit fracture surface area needed to drive the crack growth. A typical J-R curve is shown in Fig. 1 from which the material fracture toughness near the initiation of stable crack growth (Jq) can be derived. In addition, tearing modulus (TR), representing the material resistance to stable crack growth, can be calculated based on the slope of the J-R curve between two exclusion lines (red dashed lines in Fig. 1). Since the introduction of the J-R curve, extensive efforts have been continuously devoted to develop simplified and reliable methods for determining the material J-R curve. This article briefly reviews three widely-used J-R curve test methods in metals, i.e. elastic unloading compliance (EUC), normalization, and direct current potential drop (DCPD). The main difference in these methods relates to the determination of the crack size. More details of performing the J-R curve determination can be found in ASTM standard E1820-11.

Chen, Xiang [ORNL] [ORNL; Nanstad, Randy K [ORNL] [ORNL; Sokolov, Mikhail A [ORNL] [ORNL; Manneschmidt, Eric T [ORNL] [ORNL

2014-01-01T23:59:59.000Z

4

Charge Density of Divalent Metal Cations Determines RNA Stability  

E-Print Network (OSTI)

determined by a combination of counterion charge and the packing efficiency of condensed cations that depends RNAs that have regions of high negative potential interact even more strongly with counterions than of the phosphate charge arises from nonspecific condensation of counterions.4,10 The ionic radius of a metal cation

Thirumalai, Devarajan

5

SPECTROSCOPIC METALLICITY DETERMINATIONS FOR W UMa-TYPE BINARY STARS  

SciTech Connect

This study is the first attempt to determine the metallicities of W UMa-type binary stars using spectroscopy. We analyzed about 4500 spectra collected at the David Dunlap Observatory. To circumvent problems caused by the extreme spectral line broadening and blending and by the relatively low quality of the data, all spectra were subject to the same broadening function (BF) processing to determine the combined line strength in the spectral window centered on the Mg I triplet between 5080 A and 5285 A. All individual integrated BFs were subsequently orbital-phase averaged to derive a single line-strength indicator for each star. The star sample was limited to 90 W UMa-type (EW) binaries with the strict phase-constancy of colors and without spectral contamination by spectroscopic companions. The best defined results were obtained for an F-type sub-sample (0.32 < (B - V){sub 0} < 0.62) of 52 binaries for which integrated BF strengths could be interpolated in the model atmosphere predictions. The logarithmic relative metallicities, [M/H], for the F-type sub-sample indicate metal abundances roughly similar to the solar metallicity, but with a large scatter which is partly due to combined random and systematic errors. Because of the occurrence of a systematic color trend resulting from inherent limitations in our approach, we were forced to set the absolute scale of metallicities to correspond to that derived from the m{sub 1} index of the Stroemgren uvby photometry for 24 binaries of the F-type sub-sample. The trend-adjusted metallicities [M/H]{sub 1} are distributed within -0.65 < [M/H]{sub 1} < +0.50, with the spread reflecting genuine metallicity differences between stars. One half of the F-sub-sample binaries have [M/H]{sub 1} within -0.37 < [M/H]{sub 1} < +0.10, a median of -0.04 and a mean of -0.10, with a tail toward low metallicities, and a possible bias against very high metallicities. A parallel study of kinematic data, utilizing the most reliable and recently obtained proper motion and radial velocity data for 78 binaries of the full sample, shows that the F-type sub-sample binaries (44 stars with both velocities and metallicity determinations) have similar kinematic properties to solar-neighborhood, thin-disk dwarfs with space velocity component dispersions: {sigma}U = 33 km s{sup -1}, {sigma}V = 23 km s{sup -1} and {sigma}W = 14 km s{sup -1}. FU Dra with a large spatial velocity, V{sub tot} = 197 km s{sup -1} and [M/H]{sub 1} = -0.6 {+-} 0.2, appears to be the only thick-disk object in the F-type sub-sample. The kinematic data indicate that the F-type EW binaries are typical, thin-disk population stars with ages about 3-5.5 Gyr. The F-type binaries that appear to be older than the rest tend to have systematically smaller mass ratios than most of the EW binaries of the same period.

Rucinski, Slavek M. [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, Ontario M5S 3H4 (Canada); Pribulla, Theodor; Budaj, Jan, E-mail: rucinski@astro.utoronto.ca, E-mail: pribulla@ta3.sk, E-mail: budaj@ta3.sk [Astronomical Institute, Slovak Academy of Sciences, 059 60 Tatranska Lomnica (Slovakia)

2013-09-15T23:59:59.000Z

6

Interim guidance on determination and use of water-effect ratios for metals  

SciTech Connect

When a site-specific aquatic life criterion is derived for a metal, an adjustment procedure based on the toxicological determination of a water-effect ratio (WER) may be used to account for a difference between the toxicity of the metal in laboratory dilution water and its toxicity in the water at the site. The guidance contained herein replaces previous agency guidance concerning (1) the determination of WERs for use in the derivation of site-specific aquatic life criteria for metals and (2) the Recalculation Procedure. The guidance is designed to apply to metals, but the principles apply to most pollutants.

Stephan, C.E.; Peltier, W.H.; Hansen, D.J.; Delos, C.G.; Chapman, G.A.

1994-02-01T23:59:59.000Z

7

Determination of Wear Metals in Marine Lubricating Oils by Microwave Digestion and Atomic Absorption Spectrometry  

Science Journals Connector (OSTI)

?The difficulties associated with the development of a microwave-assisted acid digestion of lubricating oils in determination of wear metals are presented. The interest of this sample treatment lies in its bas...

Celestino Sanz-Segundo; María P. Hernández-Artiga…

1999-11-01T23:59:59.000Z

8

Developer Installed Treatment Plants  

E-Print Network (OSTI)

-installed treatment plants. These treatment plants are more commonly known as package wastewater treatment plants. 1

unknown authors

2008-01-01T23:59:59.000Z

9

Telecommunications Frontier Client Installation  

E-Print Network (OSTI)

Telecommunications Frontier Client Installation 1. Fax the completed form to 979.847.1111. 2 Signature Date Telecommunications Office Use Only Service Due Date: Installation Cost: Billed To: Print Form

10

Active Interrogation Observables for Enrichment Determination of DU Shielded HEU Metal Assemblies with Limited Geometrical Information  

SciTech Connect

Determining the enrichment of highly enriched uranium (HEU) metal assemblies shielded by depleted uranium (DU) proves a unique challenge to currently employed measurement techniques. Efforts to match time-correlated neutron distributions obtained through active interrogation to Monte Carlo simulations of the assemblies have shown promising results, given that the exact geometries of both the HEU metal assemblies and DU shields are known from imaging and fission site mapping. In certain situations, however, it is desirable to obtain enrichment with limited or no geometrical information of the assemblies being measured. This paper explores the possibility that the utilization of observables in the interrogation of assemblies by time-tagged D-T neutrons, including time-correlated distribution of neutrons and gammas using liquid scintillators operating on the fission chain time scale, can lead to enrichment determination without a complete set of geometrical information.

Pena, Kirsten E [ORNL] [ORNL; McConchie, Seth M [ORNL] [ORNL; Crye, Jason Michael [ORNL] [ORNL; Mihalczo, John T [ORNL] [ORNL

2011-01-01T23:59:59.000Z

11

Installation and Acceptance Stage  

Directives, Delegations, and Requirements

This chapter addresses activities required to install the software, data bases, or data that comprise the software product onto the hardware platform at sites of operation.

1997-05-21T23:59:59.000Z

12

Standard Test Method for Determination of the Susceptibility of Metallic Materials to Hydrogen Gas Embrittlement (HGE)  

E-Print Network (OSTI)

1.1 This test method covers the quantitative determination of the susceptibility of metallic materials to hydrogen embrittlement, when exposed to high pressure gaseous hydrogen. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2006-01-01T23:59:59.000Z

13

Determination of heavy metal pollution in Zonguldak (Turkey) by moss analysis (hypnum cupressiforme)  

SciTech Connect

This paper explores the first attempt at determining the levels of atmospheric heavy metal contamination in the Zonguldak province through the analysis of moss (Hypnum cupressiforme Hedw.). Sampling was performed at 24 sites after a wet period to avoid contamination from soil compounds in the province. Dried samples, which were unwashed but cleaned of soil particles and other extraneous material, were digested with HNO{sub 3}/HClO{sub 4}. Concentrations of heavy metals (Fe, Cu, Pb, Cr, Co, Ni, and As) were analyzed by ICP-OES to estimate the geographic distribution of the atmospheric heavy metal depositions. The general order of the concentrations of the heavy metal content in Hypnum cupressiforme Hedw. was observed to be Fe > Pb > Cu > Ni > Cr > As > Co. Mean levels of the measured elements were higher when compared to European levels. Arsenic, iron, and chromium were the most elevated elements when compared with European data. The mean concentrations of these elements in the studied area were 8.3 (Co), 6.7 (Fe), 5.2 (Cr), 4.6 (As), and 2.7 (Ni) times the background levels of the reference site (C3). Among the studied heavy metals, only lead showed little variation in measured values due to traffic in the area. Main sources of increased heavy metal content of the moss samples were found to be: I) the Catalagzi Power Plant (CATES); ii) the Eregli Iron-Steel Plant (ERDEMIR); iii) space heating; and iv) traffic-related emissions. Results are presented in the form of color-scaled contour maps using a Geographic Information System (GIS)-based mapping technique.

Uyar, G.; Avcil, E.; Oren, M.; Karaca, F.; Oncel, M.S. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Science & Arts

2009-01-15T23:59:59.000Z

14

Estimating SCR installation costs  

SciTech Connect

The EUCG surveyed 72 separate US installations of selective catalytic reduction (SCR) systems at coal-fired units totalling 41 GW of capacity to identify the systems' major cost drivers. The results, summarized in this article, provide excellent first-order estimates and guidance for utilities considering installing the downstream emissions-control technology. 4 figs., 1 tab.

Marano, M.; Sharp, G. [American Electric Power (United States)

2006-01-15T23:59:59.000Z

15

Solar installer's training program  

SciTech Connect

Instructions are given for the installation of solar domestic water heating systems, space heating systems, and pool heating systems. The basic procedures for installing any solar heating system are presented with reference to solar domestic hot water systems, and the space and pool systems are taught on that basis. (LEW)

Schmidt, W.J.; Philbin, J.

1981-01-01T23:59:59.000Z

16

HVAC Installed Performance  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HVAC Installed Performance HVAC Installed Performance ESI, Tim Hanes Context * The building envelope has historically been the focus in residential homes. * The largest consumer of energy in residential homes is typically the HVAC system. * Testing the performance of the HVAC system has not been pursued to its full potential. Technical Approach * Currently very little performance testing is being done to the HVAC system. * The only way to know if a HVAC system is operating correctly is to measure the Btu/h. * This should be done at the equipment and at the the system. Recommended Guidance * Training of HVAC technicians, installers, and salespeople is a must. * If only the technician is trained than implementing the change will not happen. * Public awareness of proper installation and its

17

HVAC Installed Performance  

Energy.gov (U.S. Department of Energy (DOE))

This presentation was given at the Summer 2012 DOE Building America meeting on July 25, 2012, and addressed the question HVAC proper installation energy savings: over-promising or under-delivering?"

18

Surface structure determinations of crystalline ionic thin films grown on transition metal single crystal surfaces by low energy electron diffraction  

SciTech Connect

The surface structures of NaCl(100), LiF(100) and alpha-MgCl2(0001) adsorbed on various metal single crystals have been determined by low energy electron diffraction (LEED). Thin films of these salts were grown on metal substrates by exposing the heated metal surface to a molecular flux of salt emitted from a Knudsen cell. This method of investigating thin films of insulators (ionic salts) on a conducting substrate (metal) circumvents surface charging problems that plagued bulk studies, thereby allowing the use of electron-based techniques to characterize the surface.

Roberts, J.G.

2000-05-01T23:59:59.000Z

19

Options for Determining Equivalent MHTM (Metric Tons of Heavy Metal) for DOE High Level Waste  

SciTech Connect

Section 114(d) of the Nuclear Waste Policy Act of 1982, as amended (NWPA), limits the overall capacity of the first repository to 70,000 metric tons of heavy metal (MTHM). Current DOE policy is to allocate DOE spent fuel and high-level waste (HLW) at 10 percent of the total, or 7,000 MTHM. For planning purposes, 4,667 MTHM will be allocated for HLW. While the NWPA provides a technical basis for determining the MTHM equivalence of HLW, it does not address the significant technical differences between DOE HLW and commercial spent nuclear fuel (SNF). Although more than 170,000 MTHM of DOE fuel has been reprocessed to produce the inventory of HLW, the amount of radioactive waste generated per metric ton of DOE fuel is only a few percent of that in a metric ton of commercial fuel. This study compares the results of four methods for determining the MTHM equivalence of DOE HLW. These methods include (1) using the actual weight of heavy metal in reprocessed DOE fuel, (2) assuming the historical equivalence of 0.5 MTHM/canister of vitrified DOE HLW, (3) comparing the total radioactivity in DOE HLW to the radioactivity of commercial SNF, and (4) comparing the total radiotoxicity of DOE HLW, as defined for those radionuclides identified in 10 CFR 20, with SNF at 1,000 and 10,000 years. This study concludes that either of the last two options would meet Congress’s stated purposes of the NWPA, which are to (1) provide "reasonable assurance that the public and the environment will be adequately protected from the hazards posed by high-level radioactive waste and such spent nuclear fuel as may be disposed of in a repository", and (2) to "define Federal policy for the disposal of such waste and spent fuel".

Knecht, Dieter August; Valentine, James Henry; Luptak, Alan Jay; Staiger, Merle Daniel; Loo, Henry Hung Yiu; Wichmann, Thomas Leonard

1999-04-01T23:59:59.000Z

20

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

Note: This page contains sample records for the topic "determination install metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Determination of the kinetic parameters of the CALIBAN metallic core reactor from stochastic neutron measurements  

SciTech Connect

Several experimental devices are operated by the Criticality and Neutron Science Research Dept. of the CEA Valduc Laboratory. One of these is the Caliban metallic core reactor. The purpose of this study is to develop and perform experiments allowing to determinate some of fundamental kinetic parameters of the reactor. The prompt neutron decay constant and particularly its value at criticality can be measured with reactor noise techniques such as Rossi-{alpha} and Feynman variance-to-mean methods. Subcritical, critical, and even supercritical experiments were performed. Fission chambers detectors were put nearby the core and measurements were analyzed with the Rossi-{alpha} technique. A new value of the prompt neutron decay constant at criticality was determined, which allows, using the Nelson number method, new evaluations of the effective delayed neutron fraction and the in core neutron lifetime. As an introduction of this paper, some motivations of this work are given in part 1. In part 2, principles of the noise measurements experiments performed at the CEA Valduc Laboratory are reminded. The Caliban reactor is described in part 3. Stochastic neutron measurements analysis techniques used in this study are then presented in part 4. Results of fission chamber experiments are summarized in part 5. Part 6 is devoted to the current work, improvement of the experimental device using He 3 neutron detectors and first results obtained with it. Finally, conclusions and perspectives are given in part 7. (authors)

Casoli, P.; Authier, N.; Chapelle, A. [Commissariat a l'Energie Atomique et Aux Energies Alternatives, CEA, DAM, F-21120 Is sur Tille (France)

2012-07-01T23:59:59.000Z

22

Structural Code Considerations for Solar Rooftop Installations.  

SciTech Connect

Residential rooftop solar panel installations are limited in part by the high cost of structural related code requirements for field installation. Permitting solar installations is difficult because there is a belief among residential permitting authorities that typical residential rooftops may be structurally inadequate to support the additional load associated with a photovoltaic (PV) solar installation. Typical engineering methods utilized to calculate stresses on a roof structure involve simplifying assumptions that render a complex non-linear structure to a basic determinate beam. This method of analysis neglects the composite action of the entire roof structure, yielding a conservative analysis based on a rafter or top chord of a truss. Consequently, the analysis can result in an overly conservative structural analysis. A literature review was conducted to gain a better understanding of the conservative nature of the regulations and codes governing residential construction and the associated structural system calculations.

Dwyer, Stephen F.; Dwyer, Brian P.; Sanchez, Alfred

2014-12-01T23:59:59.000Z

23

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both  

E-Print Network (OSTI)

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both

American Society for Testing and Materials. Philadelphia

1998-01-01T23:59:59.000Z

24

Determination of the Country of Origin of Farm-Raised Shrimp (Family Penaeide) Using Trace Metal Profiling and Multivariate Statistics  

Science Journals Connector (OSTI)

Determination of the Country of Origin of Farm-Raised Shrimp (Family Penaeide) Using Trace Metal Profiling and Multivariate Statistics ... The proximity of the sample data to either centroid was used by SAS statistical software to calculate the probability of membership. ... countrystatisticBCuZnRbSrMnFeBaTiAsSeSr/Ba ...

Ralph G. Smith; Carson A. Watts

2009-08-28T23:59:59.000Z

25

Determining the Heavy Metal Pollution in Mascara (Algeria) by Using Casuarina equisetifolia  

E-Print Network (OSTI)

Abstract. In this study, Casuarina equisetifolia needles were evaluated as the possible biomonitors of heavy metal air pollution in Mascara (Algeria). The needles were sampled from seven locations with different degrees of metal pollution (near roads) and from a control site. The concentrations of lead, zinc, copper and nickel were measured by using a flame atomic absorption spectrophotometer. The maximal values of these four metals were found in the samples collected near the roads and the minimal values were found in the control site. Furthermore, sites with high traffic density and frequency of cars stoppage showed high heavy metal concentrations. However, the comparison of concentrations of all metals showed that the zinc one had the highest concentration of all. The cluster analysis divided the selected sampling sites in three distinct clusters. With regard to the results of this study, Casuarina equisetifolia can be successfully applied in biomonitoring of air pollution. Key words: Casuarina equisetifolia, Mascara, biomonitors, pollution, heavy metals.

Lakhdari Aissa; Benabdeli Kéloufi

26

Standard test method for determining the superplastic properties of metallic sheet materials  

E-Print Network (OSTI)

1.1 This test method describes the procedure for determining the superplastic forming properties (SPF) of a metallic sheet material. It includes tests both for the basic SPF properties and also for derived SPF properties. The test for basic properties encompasses effects due to strain hardening or softening. 1.2 This test method covers sheet materials with thicknesses of at least 0.5 mm but not greater than 6 mm. It characterizes the material under a uni-axial tensile stress condition. Note 1—Most industrial applications of superplastic forming involve a multi-axial stress condition in a sheet; however it is more convenient to characterize a material under a uni-axial tensile stress condition. Tests should be performed in different orientations to the rolling direction of the sheet to ascertain initial anisotropy. 1.3 This method has been used successfully between strain rates of 10-5 to 10-1 per second. 1.4 This method has been used successfully on Aluminum and Titanium alloys. The use of the method wi...

American Society for Testing and Materials. Philadelphia

2008-01-01T23:59:59.000Z

27

Telecommunications Keyless Entry Hardware Install  

E-Print Network (OSTI)

Telecommunications Keyless Entry Hardware Install 1. Fax completed form to 979.847.1111. 2. If you Telecommunications Office Use Only Service Due Date: Installation Cost: Billed To: Print Form #12;

28

Installation Guide 1. PREFACE .................................................................................................................................................... 3  

E-Print Network (OSTI)

AoC Installation Guide #12;Contents 1. PREFACE....................................................................................................................................................... 4 3.2 AOC............................................................................................................................................................. 4 3.3 AOC ADMIN

Natvig, Lasse

29

Method to determine the position-dependant metal correction factor for dose-rate equivalent laser testing of semiconductor devices  

DOE Patents (OSTI)

A method reconstructs the charge collection from regions beneath opaque metallization of a semiconductor device, as determined from focused laser charge collection response images, and thereby derives a dose-rate dependent correction factor for subsequent broad-area, dose-rate equivalent, laser measurements. The position- and dose-rate dependencies of the charge-collection magnitude of the device are determined empirically and can be combined with a digital reconstruction methodology to derive an accurate metal-correction factor that permits subsequent absolute dose-rate response measurements to be derived from laser measurements alone. Broad-area laser dose-rate testing can thereby be used to accurately determine the peak transient current, dose-rate response of semiconductor devices to penetrating electron, gamma- and x-ray irradiation.

Horn, Kevin M.

2013-07-09T23:59:59.000Z

30

CX-004840: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0: Categorical Exclusion Determination 0: Categorical Exclusion Determination CX-004840: Categorical Exclusion Determination MetalZorb Best Management Practice for Storm Water Outfall K-02 CX(s) Applied: B1.8 Date: 12/13/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office This proposed activity will install MetalZorb, which is a high ion absorption media used to capture dissolved metals which are then held in the media so they won't leach out. MetalZorb is contained in a cube-sized, sponge-like material, that will be filled into mesh booms, and installed in the Outfall K-02 drainage ditches. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-004840.pdf More Documents & Publications CX-002207: Categorical Exclusion Determination CX-000820: Categorical Exclusion Determination

31

Determining the exchange parameters of spin-1 metal-organic molecular magnets in pulsed magnetic fields  

SciTech Connect

We nave measured the high-field magnetization of a number of Ni-based metal-organic molecular magnets. These materials are self-assembly coordination polymers formed from transition metal ions and organic ligands. The chemistry of the compounds is versatile allowing many structures with different magnetic properties to be formed. These studies follow on from previous measurements of the Cu-based analogues in which we showed it was possible to extract the exchange parameters of low-dimensional magnets using pulsed magnetic fields. In our recent experiments we have investigated the compound (Ni(HF{sub 2})(pyz){sub 2})PF{sub 6}, where pyz = pyrazine, and the Ni-ions are linked in a quasi-two-dimensional (Q2D) square lattice via the pyrazine molecules, with the layers held together by HF{sub 2} ligands. We also investigated Ni(NCS){sub 2}(pyzdo){sub 2}, where pyzdo = pyrazine dioxide. The samples are grown at Eastern Washington University using techniques described elsewhere. Measurements are performed at the pulsed magnetic field laboratory in Los Alamos. The magnetization of powdered samples is determined using a compensated coil magnetometer in a 65 T short pulse magnet. Temperatures as low as 500 mK are achievable using a {sup 3}He cryostat. The main figure shows the magnetization of the spin-1 [Ni(HF{sub 2})(pyz){sub 2}]PF{sub 6} compound at 1.43 K. The magnetization rises slowly at first, achieving a rounded saturation whose midpoint is around 19 T. A small anomaly is also seen in the susceptibility at low fields ({approx}3 T), which might be attributed to a spin-flop transition. In contrast, the spin-1/2 [Cu(HF{sub 2})(pyz){sub 2}]PF{sub 6} measured previously has a saturation magnetization of 35.5 T and a strongly concave form of M(B) below this field. This latter compound was shown to be a good example of a Q2D Heisenberg antiferromagnet with the strong exchange coupling (J{sub 2D} = 12.4 K, J{sub {perpendicular}}/J{sub 2D} {approx} 10{sup -2}) directed along the Cu-pyz-Cu directions. The structure of the two compounds is similar, but in the case of the Cu-compound the Cu-Cu pathways are linear, whereas in the Ni-compound they are kinked. The pulsed-field data combined with information from temperature-dependent susceptibility, muon-spin rotation, electron-spin resonance and ligand-field calculations suggest that, far from being magnetically Q2D, the Ni-compound is fairly one-dimensional with the dominant exchange (J{sub 1D} = 3.1 K and J{sub {perpendicular}}/J{sub 1D} = 0.63) directed along the Ni-FHF-Ni direction. Ni(NCS){sub 2}(pyzdo){sub 2} was also investigated. Previous ultra-high field measurements using the 100 T magnet have shown that this compound has a saturation field close to 80 T. The purpose of the present studies is to map out the phase diagram of this material at mid-range fields. The data are shown in the inset to the figure. This continuing project probes the ability of organic ligands to mediate magnetic exchange, the link between structure, dimensionality and bulk magnetic properties, as well as the role of spin number in quantum magnets. Ultimately the investigations aim to determine to what extent it is possible to produce self-assembly molecular materials with tailor-made magnetic characteristics.

Mcdonald, Ross D [Los Alamos National Laboratory; Singleton, John [Los Alamos National Laboratory; Lancaster, Tom [OXFORD UNIV.; Goddard, Paul [OXFORD UNIV.; Manson, Jamie [EASTERN WASHINGTON UNIV.

2011-01-14T23:59:59.000Z

32

Determination of Uranium Metal Concentration in Irradiated Fuel Storage Basin Sludge Using Selective Dissolution  

SciTech Connect

Uranium metal corroding in water-saturated sludges now held in the US Department of Energy Hanford Site K West irradiated fuel storage basin can create hazardous hydrogen atmospheres during handling, immobilization, or subsequent transport and storage. Knowledge of uranium metal concentration in sludge thus is essential to safe sludge management and process design, requiring an expeditious routine analytical method to detect uranium metal concentrations as low as 0.03 wt% in sludge even in the presence of 30 wt% or higher total uranium concentrations.

Delegard, Calvin H.; Sinkov, Sergey I.; Chenault, Jeffrey W.; Schmidt, Andrew J.; Welsh, Terri L.; Pool, Karl N.

2014-03-01T23:59:59.000Z

33

HTAR Client Configuration and Installation  

NLE Websites -- All DOE Office Websites (Extended Search)

Configuration and Installation Configuration and Installation HTAR Configuration and Installation HTAR is an archival utility similar to gnu-tar that allows for the archiving and extraction of local files into and out of HPSS. Configuration Instructions This distribution has default configuration settings which will work for most environments. If you want to use the default values (recommended) you can skip to the section labeled INSTALLATION INSTRUCTIONS. In certain environments, for example if your installation is on a machine which has more than one network interface, you may want to change some of these default settings. To help with this, an interactive Configure script is provided. To use it do $ ./Configure prior to installing. Configure will provide a description of the options

34

Examination of failed ex vivo metal-on-metal metatarsophalangeal prosthesis and comparison with theoretically determined lubrication regimes  

Science Journals Connector (OSTI)

Replacement of the first metatarsophalangeal (MTP) joint is a relatively uncommon procedure compared with hip and knee arthroplasty. A cobalt chrome-on-cobalt chrome MTP prosthesis, which had a diamond-like carbon (DLC) coating applied to its articulating faces, was obtained for ex vivo analysis. By modelling the ball and socket implant as an equivalent ball-on-plane model and employing elastohydrodynamic theory, the predicted lubrication regimes applicable to this implant design were determined. These calculations were undertaken for a 10–1500 N range of loading values and a 0–30 mm/s range of entraining velocities, for both worn and unworn situations. Calculations showed that the implant would almost always operate in the boundary lubrication regime. The presence of scratches on the articulating faces of the ex vivo sample further implied boundary lubrication. The DLC coating had been removed from the entire face of the phalangeal component and from most of the face of the metatarsal component. From the latter it appeared as if the coating had been scratched and then flaked away parallel to the scratches. In turn this suggested a corrosion based failure of the interface between the DLC coating and the cobalt chrome subsurface.

T.J. Joyce

2007-01-01T23:59:59.000Z

35

Determination of Interfacial Adhesion Strength between Oxide Scale and Substrate for Metallic SOFC Interconnects  

SciTech Connect

The interfacial adhesion strength between the oxide scale and the substrate is crucial to the reliability and durability of metallic interconnects in SOFC operating environments. It is necessary, therefore, to establish a methodology to quantify the interfacial adhesion strength between the oxide scale and the metallic interconnect substrate, and furthermore to design and optimize the interconnect material as well as the coating materials to meet the design life of an SOFC system. In this paper, we present an integrated experimental/analytical methodology for quantifying the interfacial adhesion strength between oxide scale and a ferritic stainless steel interconnect. Stair-stepping indentation tests are used in conjunction with subsequent finite element analyses to predict the interfacial strength between the oxide scale and Crofer 22 APU substrate.

Sun, Xin; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2008-01-21T23:59:59.000Z

36

Eliashberg Function in an Amorphous Simple Metal Alloy Sn1-Xcux Determined by Electron-Tunneling  

E-Print Network (OSTI)

dependence based on asymptotic expansions in different frequency re- gions. As discussed in a preliminary report of these tunneling measurements, the amorphous Sn& Cu system is the best characterized of simple metal amorphous superconductors and is well... between the experi- mental tunneling density of states and that calculated with u F(co). For most superconductors a quadratic dependence of n F(cu) below ui;?provides good agreement between the experimental and calculated tunneling density of states...

WATSON, PW; Naugle, Donald G.

1995-01-01T23:59:59.000Z

37

Determining the Behavior of RuO(x) Nanoparticles in Mixed-Metal Oxides:  

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Mechanism of Ethanol Synthesis from Syngas on Rh(111) Understanding of Mechanism of Ethanol Synthesis from Syngas on Rh(111) Understanding of ethanol decomposition on Rh(1 1 1) from density functional theory and kinetic Monte Carlo simulations Theoretical perspective of alcohol decomposition and synthesis from CO2 hydrogenation