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1

Crystallization and shear modulus of a forming biopolymer film determined by in situ x-ray diffraction and ultrasound reflection methods  

Science Journals Connector (OSTI)

The structure and the rigidity of a forming biopolymer film were determined using concurrent x-ray diffraction and ultrasonic reflection measurements. Film formation of a xylan solution (de-ionized water 10 g ? l xylan 4 g ? l glycerol) was studied during water evaporation at 24 ( ± 2 ) ° C 37 ( ± 5 ) % RH . X-ray diffraction(XRD) data showed the crystallization and ultrasonic data the increase of the shear modulus ( G ) during water evaporation. Xylan crystallized into small xylan dihydrate crystallites the number of which increased as water evaporated. Crystallization began earlier than the increase in G during film formation. The increase in G also continued after the crystallites were fully formed indicating still ongoing structural changes in the amorphous parts. The maximum value of G was 0.1 – 0.5 GPa . XRD measurements performed ex situ showed a crystallinity of 16%–19% ( ± 5 % ) and a fairly isotropic crystallite orientation in the surface plane of the films.

Marko Peura; Timo Karppinen; Annemai Soovre; Ari Salmi; Maija Tenkanen; Edward Hæggström; Ritva Serimaa

2008-01-01T23:59:59.000Z

2

Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction  

Science Journals Connector (OSTI)

A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction.

Emamzadah, S.

2009-08-06T23:59:59.000Z

3

Thermal expansion of manganese dioxide using high-temperature in situ X-ray diffraction  

Science Journals Connector (OSTI)

The thermal expansion behaviour of manganese dioxide, an important battery material, is reported using high-temperature in situ X-ray diffraction between 298 and 673 K.

Dose, W.M.

2013-08-03T23:59:59.000Z

4

In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents  

SciTech Connect

In situ electrochemical X-ray photoelectron spectroscopy (XPS) apparatus, which allows XPS at solid/liquid interfaces under potential control, was constructed utilizing a microcell with an ultra-thin Si membrane, which separates vacuum and a solution. Hard X-rays from a synchrotron source penetrate into the Si membrane surface exposed to the solution. Electrons emitted at the Si/solution interface can pass through the membrane and be analyzed by an analyzer placed in vacuum. Its operation was demonstrated for potential-induced Si oxide growth in water. Effect of potential and time on the thickness of Si and Si oxide layers was quantitatively determined at sub-nanometer resolution.

Masuda, Takuya [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 333-0012 (Japan); Yoshikawa, Hideki; Kobata, Masaaki; Kobayashi, Keisuke [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148 (Japan); Noguchi, Hidenori [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 333-0012 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan); Kawasaki, Tadahiro [Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603 (Japan)] [Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603 (Japan); Uosaki, Kohei [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan) [Global Research Center for Environment and Energy Based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS), Tsukuba 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan)

2013-09-09T23:59:59.000Z

5

Tracking the catalyzed growth process of nanowires by in situ x-ray diffraction  

E-Print Network (OSTI)

capacity.4­7 Silicon nanowires have also found application in solar cells, both as ab- sorber OF NANOSTRUCTURES Gold-catalyzed silicon nanowires were grown in an x-ray furnace so that in situ x-ray diffraction-type furnace attached to a Pana- lytical X'Pert PRO diffractometer. The temperature of the furnace

Wang, Zhong L.

6

In Situ X-Ray Probing Reveals Fingerprints of Surface Platinum Oxide  

SciTech Connect

In situ x-ray absorption spectroscopy (XAS) at the Pt L{sub 3} edge is a useful probe for Pt-O interactions at polymer electrolyte membrane fuel cell (PEMFC) cathodes. We show that XAS using the high energy resolution fluorescence detection (HERFD) mode, applied to a well-defined monolayer Pt/Rh(111) sample where the bulk penetrating hard x-rays probe only surface Pt atoms, provides a unique sensitivity to structure and chemical bonding at the Pt-electrolyte interface. Ab initio multiple-scattering calculations using the FEFF8 code and complementary extended x-ray absorption fine structure (EXAFS) results indicate that the commonly observed large increase of the white-line at high electrochemical potentials on PEMFC cathodes originates from platinum oxide formation, whereas previously proposed chemisorbed oxygen-containing species merely give rise to subtle spectral changes.

Friebel, Daniel

2011-08-24T23:59:59.000Z

7

A portable molecular beam epitaxy system for in situ x-ray investigations at synchrotron beamlines  

SciTech Connect

A portable synchrotron molecular beam epitaxy (MBE) system is designed and applied for in situ investigations. The growth chamber is equipped with all the standard MBE components such as effusion cells with shutters, main shutter, cooling shroud, manipulator, reflection high energy electron diffraction setup, and pressure gauges. The characteristic feature of the system is the beryllium windows which are used for in situ x-ray measurements. An UHV sample transfer case allows in vacuo transfer of samples prepared elsewhere. We describe the system design and demonstrate its performance by investigating the annealing process of buried InGaAs self-organized quantum dots.

Slobodskyy, T. [Institute for Synchrotron Radiation, Karlsruhe Institute of Technology - 76344 Eggenstein-Leopoldshafen (Germany); Institut fuer Angewandte Physik und Zentrum fuer Mikrostrukturforschung, Jungiusstrasse 11, D-20355 Hamburg (Germany); Schroth, P.; Grigoriev, D.; Minkevich, A. A.; Baumbach, T. [Institute for Synchrotron Radiation, Karlsruhe Institute of Technology - 76344 Eggenstein-Leopoldshafen (Germany); Hu, D. Z.; Schaadt, D. M. [Institute for Applied Physics/DFG-Center for Functional Nanostructures, Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany); Institute for Energy Research and Physical Technologies, Technical University Clausthal, Am Stollen 19B, 38640 Goslar (Germany)

2012-10-15T23:59:59.000Z

8

Development of in situ, at-wavelength metrology for soft x-ray nano-focusing  

SciTech Connect

At the Advanced Light Source (ALS), we are developing broadly applicable, high-accuracy, in situ, at-wavelength wavefront slope measurement techniques for Kirkpatrick-Baez (KB) mirror nano-focusing. We describe here details of the metrology beamline endstation, the at-wavelength tests, and an original alignment method that have already allowed us to precisely set a bendable KB mirror to achieve a FWHM focused spot size of ~;;120 nm, at 1-nm soft x-ray wavelength.

Yuan, Sheng Sam; Yashchuk, Valeriy V.; Goldberg, Kenneth A.; Celestre, Richard; McKinney, Wayne R.; Morrison, Gregory Y.; Warwick, Tony; Padmore, Howard A.

2010-09-19T23:59:59.000Z

9

Strains in Thermally Growing Alumina Films Measured in-situ usingSynchrotron X-rays  

SciTech Connect

Strains in thermally grown oxides have been measured in-situ, as the oxides develop and evolve. Extensive data have been acquired from oxides grown in air at elevated temperatures on different model alloys that form Al{sub 2}O{sub 3}. Using synchrotron x-rays at the Advanced Photon Source (Beamline 12BM, Argonne National Laboratory), Debye-Scherrer diffraction patterns from the oxidizing specimen were recorded every 5 minutes during oxidation and subsequent cooling. The diffraction patterns were analyzed to determine strains in the oxides, as well as phase changes and the degree of texture. To study a specimen's response to stress perturbation, the oxidizing temperature was quickly cooled from 1100 to 950 C to impose a compressive thermal stress in the scale. This paper describes this new experimental approach and gives examples from oxidized {beta}-NiAl, Fe-20Cr-10Al, Fe-28Al-5Cr and H{sub 2}-annealed Fe-28Al-5Cr (all at. %) alloys to illustrate some current understanding of the development and relaxation of growth stresses in Al{sub 2}O{sub 3}.

Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

2006-01-02T23:59:59.000Z

10

Instrument for x-ray absorption spectroscopy with in situ electrical control characterizations  

SciTech Connect

We report a synchrotron-based setup capable of performing x-ray absorption spectroscopy and x-ray magnetic circular dichroism with simultaneous electrical control characterizations. The setup can enable research concerning electrical transport, element- and orbital-selective magnetization with an in situ fashion. It is a unique approach to the real-time change of spin-polarized electronic state of a material/device exhibiting magneto-electric responses. The performance of the setup was tested by probing the spin-polarized states of cobalt and oxygen of Zn{sub 1-x}Co{sub x}O dilute magnetic semiconductor under applied voltages, both at low (?20 K) and room temperatures, and signal variations upon the change of applied voltage were clearly detected.

Huang, Chun-Chao; Chang, Shu-Jui; Yang, Chao-Yao; Tseng, Yuan-Chieh [Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan (China)] [Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan (China); Chou, Hsiung [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China)] [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China)

2013-12-15T23:59:59.000Z

11

In-Situ Silver Acetylide Silver Nitrate Explosive Deposition Measurements Using X-Ray Fluorescence.  

SciTech Connect

The Light Initiated High Explosive facility utilized a spray deposited coating of silver acetylide - silver nitrate explosive to impart a mechanical shock into targets of interest. A diagnostic was required to measure the explosive deposition in - situ. An X - ray fluorescence spectrometer was deployed at the facility. A measurement methodology was developed to measure the explosive quantity with sufficient accuracy. Through the use of a tin reference material under the silver based explosive, a field calibration relationship has been developed with a standard deviation of 3.2 % . The effect of the inserted tin material into the experiment configuration has been explored.

Covert, Timothy T.

2014-09-01T23:59:59.000Z

12

In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode  

Science Journals Connector (OSTI)

In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode ... Li-ion batteries; solid electrolyte interphase; graphene; graphite; X-ray scattering ...

Sudeshna Chattopadhyay; Albert L. Lipson; Hunter J. Karmel; Jonathan D. Emery; Timothy T. Fister; Paul A. Fenter; Mark C. Hersam; Michael J. Bedzyk

2012-07-23T23:59:59.000Z

13

In-situ X-ray diffraction activation study on an Fe/TiO2 pre-catalyst  

Science Journals Connector (OSTI)

It is well known that pre-treatment procedures affect catalyst performance. In situ X-ray diffraction was used in this study to monitor the changes in phase composition and crystallite size during the pre-treatment of Fe/TiO2 catalysts, yielding insight into crystalline and non-crystalline phase changes and metal-support interactions.

Rayner, M.K.

2014-05-31T23:59:59.000Z

14

An in-situ cell for characterization of solids by soft X-ray absorption  

E-Print Network (OSTI)

Scientific Instruments a Absorption (a.u. ) b d 0.01 abs cJ. Lynch, in X-ray Absorption Fine Structure for Catalysts18, pp. 431-512. X-ray Absorption: Principles, Applications,

2007-01-01T23:59:59.000Z

15

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

SciTech Connect

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state Li4+xTi5O12/LiPON/LixV2O5 cell and examine in situ the chemistry of Li-O2 reaction products on LixV2O5 as a function of applied voltage under ultra high vacuum (UHV) and near ambient-pressure of oxygen using X-ray photoelectron spectroscopy (APXPS). Oxygen reduction and evolution reactions take place on the surface of the mixed electronic and Li+ ionic conductor, LixV2O5, which eliminate parasitic reactions between oxygen reduction/evolution reaction intermediates and aprotic electrolytes used in Li-O2 batteries reported to date. Under UHV, reversible lithium intercalation and de-intercalation from LixV2O5 was noted, where the changes in the vanadium valence state revealed from XPS in this study were comparable to that reported previously from Li/LixV2O5 thin film batteries. In presence of oxygen near ambient pressure, the LixV2O5 surface was covered gradually by the reaction product of oxygen reduction, namely lithium peroxide (Li2O2) (approximately 1-2 unit cells) upon discharge. Interestingly, the LixV2O5 surface became re-exposed upon charging, and the oxidation of Li2O2 began at much lower overpotentials (~240 mV) than the charge overpotentials of Li-O2 cells (~1000 mV) with aprotic electrolytes, which can be attributed to subnanometer-thick Li2O2 with surfaces free of contaminants such as carbonate species. Our study provides first evidence of reversible lithium peroxide formation and decomposition in situ on an oxide surface using a solid-state cell, and new insights into the reaction mechanism of Li-O2 chemistry.

Lu, Yi-chun [Massachusetts Institute of Technology (MIT); Crumlin, Ethan [Massachusetts Institute of Technology (MIT); Veith, Gabriel M [ORNL; Harding, Jonathon [Massachusetts Institute of Technology (MIT); Dudney, Nancy J [ORNL; Liu, Zhi [Lawrence Berkeley National Laboratory (LBNL); Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)

2012-01-01T23:59:59.000Z

16

Dissolution dynamics of the calcite-water interface observed in situ by glancing-incidence X-ray scattering  

SciTech Connect

Glancing-incidence X-ray scattering measurements made at the National Synchrotron Light Source were used to investigate dissolution dynamics in situ at the calcite-water interface. The relation between calcite saturation state and roughness of the calcite (1014) cleavage surface as a function of time was examined during pH titrations of an initially calcite-saturated solution. Systematic variations in roughness were observed as a function of saturation state as pH was titrated to values below that of calcite saturation. Different steady-state values of roughness were evident at fixed values of {Delta}G{sub r}, and these were correlated with the extent of undersaturation. A significant increase in roughness begins to occur with increasing undersaturation at a {Delta}G{sub r} value of approximately {minus}2.0 kcal/mol. The dissolution rate corresponding to this increase is about 1.5 x 10{sup 7} mmol/cm {center_dot} sec. This increase in roughness is attributed to a transition in the principal rate-determining dissolution mechanism, and is consistent with both powder-reaction studies of dissolution kinetics and single-crystal dissolution studies by atomic force microscopy. These data indicate some important potential applications of GIXS in the study of mineral-water interface geochemistry.

Sturchio, N.C.; Chiarello, R.P.

1995-06-02T23:59:59.000Z

17

Scanning transmission X-ray microscopy probe for in situ mechanism study of graphene-oxide-based resistive random access memory  

Science Journals Connector (OSTI)

An in situ probe for scanning transmission X-ray microscopy has been developed and applied to the study of the bipolar resistive switching mechanism in an Al/graphene oxide/Al resistive random access memory device.

Nho, H.W.

2013-11-28T23:59:59.000Z

18

In-situ microscale through-silicon via strain measurements by synchrotron x-ray microdiffraction exploring the physics behind data interpretation  

SciTech Connect

In-situ microscale thermomechanical strain measurements have been performed in combination with synchrotron x-ray microdiffraction to understand the fundamental cause of failures in microelectronics devices with through-silicon vias. The physics behind the raster scan and data analysis of the measured strain distribution maps is explored utilizing the energies of indexed reflections from the measured data and applying them for beam intensity analysis and effective penetration depth determination. Moreover, a statistical analysis is performed for the beam intensity and strain distributions along the beam penetration path to account for the factors affecting peak search and strain refinement procedure.

Liu, Xi [The George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Thadesar, Paragkumar A.; Oh, Hanju; Bakir, Muhannad S. [School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Taylor, Christine L.; Sitaraman, Suresh K. [The George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Kunz, Martin; Tamura, Nobumichi [Advanced Light Source, Lawrence Berkeley National Laboratory Berkeley, California 94720 (United States)

2014-09-15T23:59:59.000Z

19

Design of a continuous-flow reactor for in situ x-ray absorption spectroscopy of solids in supercritical fluids  

SciTech Connect

This paper presents the design and performance of a novel high-temperature and high-pressure continuous-flow reactor, which allows for x-ray absorption spectroscopy or diffraction in supercritical water and other fluids under high pressure and temperature. The in situ cell consists of a tube of sintered, polycrystalline aluminum nitride, which is tolerant to corrosive chemical media, and was designed to be stable at temperatures up to 500 deg. C and pressures up to 30 MPa. The performance of the reactor is demonstrated by the measurement of extended x-ray absorption fine structure spectra of a carbon-supported ruthenium catalyst during the continuous hydrothermal gasification of ethanol in supercritical water at 400 deg. C and 24 MPa.

Dreher, M.; De Boni, E.; Nachtegaal, M.; Wambach, J.; Vogel, F. [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland)

2012-05-15T23:59:59.000Z

20

Novel Cell Design for Combined In Situ Acoustic Emission and X-ray Diffraction of Cycling Lithium Ion Batteries  

SciTech Connect

An in situ acoustic emission (AE) and X-ray diffraction (XRD) cell for use in the study of battery electrode materials has been devised and tested. This cell uses commercially available coin cell hardware retrofitted with a metalized polyethylene terephthalate (PET) disk which acts as both an X-ray window and a current collector. In this manner the use of beryllium and its associated cost and hazard is avoided. An AE sensor may be affixed to the cell face opposite the PET window in order to monitor degradation effects, such as particle fracture, during cell cycling. Silicon particles which were previously studied by the AE technique were tested in this cell as a model material. The performance of these cells compared well with unmodified coin cells while providing information about structural changes in the active material as the cell is repeatedly charged and discharged.

Rhodes, Kevin J [ORNL; Kirkham, Melanie J [ORNL; Meisner, Roberta Ann [ORNL; Parish, Chad M [ORNL; Dudney, Nancy J [ORNL; Daniel, Claus [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Novel cell design for combined in situ acoustic emission and x-ray diffraction study during electrochemical cycling of batteries  

SciTech Connect

An in situ acoustic emission (AE) and x-ray diffraction cell for use in the study of battery electrode materials has been designed and tested. This cell uses commercially available coin cell hardware retrofitted with a metalized polyethylene terephthalate (PET) disk, which acts as both an x-ray window and a current collector. In this manner, the use of beryllium and its associated cost and hazards is avoided. An AE sensor may be affixed to the cell face opposite the PET window in order to monitor degradation effects, such as particle fracture, during cell cycling. Silicon particles, which were previously studied by the AE technique, were tested in this cell as a model material. The performance of these cells compared well with unmodified coin cells, while providing information about structural changes in the active material as the cell is repeatedly charged and discharged.

Rhodes, Kevin; Meisner, Roberta; Daniel, Claus [Materials Science and Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Rd., MS 6083, Oak Ridge, Tennessee 37931-6083 (United States); Materials Science and Engineering Department, University of Tennessee, 434 Dougherty Hall, Knoxville, Tennessee 37996-2200 (United States); Kirkham, Melanie; Parish, Chad M.; Dudney, Nancy [Materials Science and Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Rd., MS 6083, Oak Ridge, Tennessee 37931-6083 (United States)

2011-07-15T23:59:59.000Z

22

In situ X-ray Characterization of Energy Storage Materials | Stanford  

NLE Websites -- All DOE Office Websites (Extended Search)

X-ray Characterization of Energy Storage Materials X-ray Characterization of Energy Storage Materials Tuesday, July 9, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Johanna Nelson, Stanford Postdoctoral Scholar, SSRL MSD Hard X-ray Department A key factor in the global move towards clean, renewable energy is the electrification of the automobile. Current battery technology limits EV (electric vehicles) to a short travel range, slow recharge, and costly price tag. Li-ion batteries promise the high specific capacity required for EVs to travel 300+ miles on a single charge with a number of possible earth abundant anode and cathode materials; however, set backs such as capacity fading hinder the full capability of these rechargeable batteries. In order to accurately characterize the dynamic electrochemical processes at the

23

In Situ X-ray Near-Edge Absorption Spectroscopy Investigation of the State of Charge of All-Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

all-vanadium flow battery; X-ray near-edge adsorption spectroscopy; synchrotron; in situ; state of charge; electrolyte ... Among different types of RFBs, the all-vanadium redox flow battery (VRB) displays excellent electrochemical activity and reversibility. ... To the best of our knowledge, this is the first report to use the in situ synchrotron techniques to study the redox flow battery. ...

Chuankun Jia; Qi Liu; Cheng-Jun Sun; Fan Yang; Yang Ren; Steve M. Heald; Yadong Liu; Zhe-Fei Li; Wenquan Lu; Jian Xie

2014-09-05T23:59:59.000Z

24

Triple-Energy X-Ray Absorptiometry for Determination of the Bone Mineral Content in Vivo  

Science Journals Connector (OSTI)

Dual-energy X-ray absorptiometry (DXA) is a ... method for the determination of the bone mineral content in vivo. It has a high precision ... bone. The present work describes a triple-energy X-ray absorptiometry ...

Janos Szücs; Ragnar Jonson; Tommy Hansson

1993-01-01T23:59:59.000Z

25

Characterization of Cathode Materials for Rechargeable Lithium Batteries using Synchrotron Based In Situ X-ray Techniques  

SciTech Connect

The emergence of portable telecommunication, computer equipment and ultimately hybrid electric vehicles has created a substantial interest in manufacturing rechargeable batteries that are less expensive, non-toxic, operate for longer time, small in size and weigh less. Li-ion batteries are taking an increasing share of the rechargeable battery market. The present commercial battery is based on a layered LiCoO{sub 2} cathode and a graphitized carbon anode. LiCoO{sub 2} is expensive but it has the advantage being easily manufactured in a reproducible manner. Other low cost layered compounds such as LiNiO{sub 2}, LiNi{sub 0.85}Co{sub 0.15}O{sub 2} or cubic spinels such as LiMn{sub 2}O{sub 4} have been considered. However, these suffer from cycle life and thermal stability problems. Recently, some battery companies have demonstrated a new concept of mixing two different types of insertion compounds to make a composite cathode, aimed at reducing cost and improving self-discharge. Reports clearly showed that this blending technique can prevent the decline in ·capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and phase transitions for these composite cathodes. Understanding the structure and structural changes of electrode materials during the electrochemical cycling is the key to develop better .lithium ion batteries. The successful commercialization of the· lithium-ion battery is mainly built on the advances in solid state chemistry of the intercalation compounds. Most of the progress in understanding the lithium ion battery materials has been obtained from x-ray diffraction studies. Up to now, most XRD studies on lithium-ion battery materials have been done ex situ. Although these ex situ XRD studies have provided important information· about the structures of battery materials, they do face three major problems. First of all, the pre-selected charge (discharge) states may not be representative for the full picture of the structural changes during charge (discharge). In other words, the important information might be missed for those charge (discharge) states which were not selected for ex situ XRD studies. Secondly, the structure of the sample may have changed after removed from the cell. Finally, it is impossible to use the ex situ XRD to study the dynamic effects during high rate charge-discharge, which is crucial for the application of lithium-ion batteries for electric vehicle. A few in situ studies have been done using conventional x-ray tube sources. All of the in situ XRD studies using conventional x-ray tube sources have been done in the reflection mode in cells with beryllium windows. Because of the weak signals, data collection takes a long time, often several hundred hours for a single charge-discharge cycle. This long time data collection is not suitable for dynamic studies at all. Furthermore, in the reflection mode, the x-ray beam probes mainly the surface layer of the cathode materials. Iri collaboration with LG Chemical Ltd., BNL group designed and constructed the cells for in situ studies. LG Chemical provided several blended samples and pouch cells to BNL for preliminary in situ study. The LG Chemical provided help on integrate the blended cathode into these cells. The BNL team carried out in situ XAS and XRD studies on the samples and pouch cells provided by LG Chemical under normal charge-discharge conditions at elevated temperature.

Yang, Xiao-Qing

2007-05-23T23:59:59.000Z

26

An in situ method for the study of strain broadening using synchrotron X-ray diffraction  

Science Journals Connector (OSTI)

A tensionometer for in situ powder diffraction studies of foils under stress has been constructed and used in a copper foil on beamline 2.3 of the Daresbury SRS. Both peak asymmetry and broadening were observed which was interpreted as being due to a cellular structure with cell walls and cell interiors possessing high and low dislocation densities.

Tang, C.C.

2007-07-13T23:59:59.000Z

27

X-ray bandwidth: Determination by on-edge absorption and effect on various absorption experiments  

E-Print Network (OSTI)

X-ray bandwidth: Determination by on-edge absorption and effect on various absorption experiments of an x-ray source is increasingly important in fundamental experi- ments and critical applications. The bandwidth of an x-ray beam, selected from a synchrotron radiation spectrum for example, ultimately defines

Chantler, Christopher T.

28

In situ x-ray absorption study of Zr(V0.29Ni0.71)3 hydride electrodes  

Science Journals Connector (OSTI)

We present an in situ x-ray absorption study of hydrogen absorption into the bulk of an electrode material while it is operating in an electrochemical cell. The active material is an overstoichiometric AB2-type alloy, namely, Zr(V0.29Ni0.71)3, with a cubic C15 Laves phase structure. Hydrogen absorption induces both structural and electronic changes due to the bonding between interstitial H atoms and each alloy element. The role of each element is revealed, allowing us to determine the inert role of Ni atoms and the dominant effect of the H-V interaction on the hydride formation process. Comparison between the alloyed element behavior and the H affinity of each pure element allows us to determine the influence of structural and alloying effects on bonding formation.

R. G. Agostino; G. Liberti; V. Formoso; E. Colavita; A. Züttel; C. Nützenadel; L. Schlapbach; A. Santaniello; C. Gauthier

2000-05-15T23:59:59.000Z

29

In-situ X-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions  

SciTech Connect

X-ray photoelectron spectroscopy (XPS) is a powerful tool for surface and interface analysis, providing the elemental composition of surfaces and the local chemical environment of adsorbed species. Conventional XPS experiments have been limited to ultrahigh vacuum (UHV) conditions due to a short mean free path of electrons in a gas phase. The recent advances in instrumentation coupled with third-generation synchrotron radiation sources enables in-situ XPS measurements at pressures above 5 Torr. In this review, we describe the basic design of the ambient pressure XPS setup that combines differential pumping with an electrostatic focusing. We present examples of the application of in-situ XPS to studies of water adsorption on the surface of metals and oxides including Cu(110), Cu(111), TiO2(110) under environmental conditions of water vapor pressure. On all these surfaces we observe a general trend where hydroxyl groups form first, followed by molecular water adsorption. The importance of surface OH groups and their hydrogen bonding to water molecules in water adsorption on surfaces is discussed in detail.

Salmeron, Miquel; Yamamoto, S.; Bluhm, H.; Andersson, K.; Ketteler, G.; Ogasawara, H.; Salmeron, M.; Nilsson, A.

2007-10-29T23:59:59.000Z

30

Determination of interfacial roughness using X-ray scattering  

SciTech Connect

Crystal truncation rod (CTR) scattering is shown to be a powerful technique for determining interfacial roughness non-destructively. By measuring the decay of scattering away from a Bragg reflection in the surface direction an rms roughness of the surface or interface can be extracted. The authors obtain rms roughness values with an accuracy of {+-} 0.1 {angstrom}. Sensitivity to lateral length scale roughness ranges from the wavelength of the x-rays to between 1,000--10,000 {angstrom} depending on the instrument function and the specific truncation rod. The influence of different cleans, as well as the thermal oxidation process, on the Si-SiO{sub 2} interface is investigated. A hot water treatment prior to the thermal oxidation is shown to roughen the Si-SiO{sub 2} interface. CTR scattering results also show a smoothing of the interface as a result of the oxidation process even for as little as 60 {angstrom} of thermal oxidation. Comparison between AFM and CTR scattering gives a consistent picture of the relative roughness of the wafers, although the absolute numbers do not agree. The differences in the absolute values can be explained by the lateral roughness scale that the two techniques measure, indicating that it is at periodicities below {approx} 100 {angstrom} that the increased roughness observed by the x-ray is found. Crystal truncation rods are shown to be perpendicular to the surface and not along the crystallographic axes of a miscut crystal. It is shown that for a crystal terminated by a regular step array both an atomistic and a continuum description of CTR scattering give identical results. Furthermore, the atomistic approach is used to show that a diamond cubic surface with a miscut is inherently rough. Even for a small miscut the tilt of the CTR with respect to the crystallographic axes results in complications for measuring the rod intensity. The authors present schemes for determining the exact position of the CTR in reciprocal space and for measuring the miscut of a single crystal. These methods were applied to the measurement of CTR intensities of silicon(001) wafers with miscuts of 0.1 and 4 degrees.

Munkholm, A.

1997-05-01T23:59:59.000Z

31

In-situ x-ray diffraction of layered LiCoO{sub 2}-Type cathode materials  

SciTech Connect

The authors have investigated LiNi{sub 0.8}Co{sub 0.2}O{sub 2} (Sumitomo) and LiNi{sub 5/8}Co{sub 1/4}Mn{sub 1/16}Al{sub 1/16}O{sub 2} (Sandia chemical preparation method) cathode powders via in-situ X-ray Diffraction and Cyclic Voltammetry using a coffee-bag type electrochemical cell. Both cathode materials did not show a monoclinic distortion during de-intercalation but sustained the hexagonal structure up to 4.3 V. The doping of Co into the LiNiO{sub 2} structure appears to stabilize this lattice as the hexagonal structure over the full range of charging (up to 4.3 V). The LiNi{sub 5/8}Co{sub 1/4}Mn{sub 1/16}Al{sub 1/16}O{sub 2} cathode material exhibited a 160 mAh/g capacity (to 4.1 V) on its 1{sup st} cycle, while displaying a much smaller volume change (as compared to LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) during de-intercalation. This reduced overall volume change (2.5 vol%) may have important implications for cycle life of this material.

Rodriguez, M.A.; Ingersoll, D.; Doughty, D.H.

1999-12-09T23:59:59.000Z

32

In-situ small-angle X-ray scattering study of the precipitation behavior in a Fe-25 at.%Co-9 at.%Mo alloy  

SciTech Connect

Fe-Co-Mo alloys show extraordinary mechanical properties which make them potential candidates for various high-performance applications. In the present study, for the first time, the precipitation behavior in a Fe-25 at.%Co-9 at.%Mo alloy was studied by small-angle X-ray scattering using high-energy synchrotron radiation. The specimens were isothermally aged in an in-situ furnace. The small-angle X-ray scattering patterns showed scaling behavior and were evaluated by employing a model function from the literature. This approach provides information about the characteristic length scale and the volume fraction of the precipitates in the alloy.

Zickler, Gerald A. [Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Christian Doppler Laboratory for Early Stages of Precipitation, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria)], E-mail: gerald.zickler@mu-leoben.at; Eidenberger, Elisabeth [Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Leitner, Harald [Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Christian Doppler Laboratory for Early Stages of Precipitation, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Stergar, Erich; Clemens, Helmut [Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Staron, Peter; Lippmann, Thomas; Schreyer, Andreas [GKSS Research Center Geesthacht, Max-Planck-Strasse 1, D-21502 Geesthacht (Germany)

2008-12-15T23:59:59.000Z

33

In-situ X-ray diffraction study of phase transformations in the Am-O system  

SciTech Connect

In the frame of minor actinides recycling, americium can be transmuted by adding it in UO{sub 2} or (U, Pu)O{sub 2} fuels. Americium oxides exhibiting a higher oxygen potential than U or Pu oxides, its addition alters the fuel properties. To comprehend its influence, a thorough knowledge of the Am-O phase equilibria diagram and of thermal expansion behavior is of main interest. Due to americium scarcity and high radiotoxicity, few experimental reports on this topic are available. Here we present in-situ high-temperature XRD results on the reduction from AmO{sub 2} to Am{sub 2}O{sub 3}. We show that fluorite (Fm-3m) AmO{sub 2} is reduced to cubic (Ia-3) C Prime -type Am{sub 2}O{sub 3+{delta}}, and then into hexagonal (P6{sub 3}/mmc) A-type Am{sub 2}O{sub 3}, which remains stable up to 1840 K. We also demonstrate the transitional existence of the monoclinic (C2/m) B-type Am{sub 2}O{sub 3}. At last, we describe, for the first time, the thermal expansion behavior of the hexagonal Am{sub 2}O{sub 3} between room temperature and 1840 K. - Graphical abstract: Americium dioxide was in situ studied by high-temperature X-ray diffraction. First, fluorite AmO{sub 2} is reduced to cubic C Prime -type Am{sub 2}O{sub 3+{delta}} and then transforms into hexagonal A-type Am{sub 2}O{sub 3}, which remains stable up to 1840 K. Then, we demonstrate the transitional existence of monoclinic B-type Am{sub 2}O{sub 3}. At last, we describe, for the first time, the thermal expansion of A-type Am{sub 2}O{sub 3} between room temperature and 1840 K. This work may contribute to a better understanding of Am oxide behavior. Highlights: Black-Right-Pointing-Pointer We realize an in-situ high-temperature X-ray diffraction study on an AmO{sub 2} sample. Black-Right-Pointing-Pointer Fluorite AmO{sub 2} transforms to cubic Am{sub 2}O{sub 3+{delta}} and then to hexagonal Am{sub 2}O{sub 3}. Black-Right-Pointing-Pointer Little-known monoclinic Am{sub 2}O{sub 3} is observed during the cubic-to-hexagonal transition. Black-Right-Pointing-Pointer Lattice parameter thermal expansion of hexagonal Am{sub 2}O{sub 3} is given up to 1840 K. Black-Right-Pointing-Pointer We give additional data on AmO{sub 2} lattice parameter expansion under self-irradiation.

Lebreton, Florent, E-mail: florent.lebreton@cea.fr [CEA Marcoule, DEN/DTEC/SDTC/LEMA, F-30207 Bagnols-sur-Ceze cedex (France) [CEA Marcoule, DEN/DTEC/SDTC/LEMA, F-30207 Bagnols-sur-Ceze cedex (France); GEMH, ENSCI, 87065 Limoges (France); Belin, Renaud C., E-mail: renaud.belin@cea.fr [CEA Cadarache, DEN/DEC/SPUA/LMPC, F-13108 Saint-Paul-Lez-Durance (France); Delahaye, Thibaud, E-mail: thibaud.delahaye@cea.fr [CEA Marcoule, DEN/DTEC/SDTC/LEMA, F-30207 Bagnols-sur-Ceze cedex (France)] [CEA Marcoule, DEN/DTEC/SDTC/LEMA, F-30207 Bagnols-sur-Ceze cedex (France); Blanchart, Philippe, E-mail: philippe.blanchart@unilim.fr [GEMH, ENSCI, 87065 Limoges (France)] [GEMH, ENSCI, 87065 Limoges (France)

2012-12-15T23:59:59.000Z

34

Lipid Bilayer Structure Determined by the Simultaneous Analysis of Neutron and X-Ray Scattering Data  

E-Print Network (OSTI)

Lipid Bilayer Structure Determined by the Simultaneous Analysis of Neutron and X-Ray Scattering) and dipalmitoylphosphatidylcholine (DPPC) bilayers by simultaneously analyzing x-ray and neutron scattering data. The neutron data electron and neutron scattering density profiles. A key result of the analysis is the molecular surface

Nagle, John F.

35

In Situ X-ray Absorption Near-Edge Structure Spectroscopy of ZnO Nanowire Growth During Chemical Bath Deposition  

SciTech Connect

Chemical bath deposition (CBD) offers a simple and inexpensive route to deposit semiconductor nanostructures, but lack of fundamental understanding and control of the underlying chemistry has limited its versatility. Here we report the first use of in situ X-ray absorption spectroscopy during CBD, enabling detailed investigation of both reaction mechanisms and kinetics of ZnO nanowire growth from zinc nitrate and hexamethylenetetramine (HMTA) precursors. Time-resolved X-ray absorption near-edge structure (XANES) spectra were used to quantify Zn(II) speciation in both solution and solid phases. ZnO crystallizes directly from [Zn(H{sub 2}O){sub 6}]{sup 2+} without long-lived intermediates. Using ZnO nanowire deposition as an example, this study establishes in situ XANES spectroscopy as an excellent quantitative tool to understand CBD of nanomaterials.

McPeak, Kevin M.; Becker, Matthew A.; Britton, Nathan G.; Majidi, Hasti; Bunker, Bruce A.; Baxter, Jason B. (Drexel); (Notre)

2010-12-03T23:59:59.000Z

36

A System for Conducting Sophisticated Mechanical Tests in Situ with High Energy Synchrotron X-Rays Final Technical Report  

SciTech Connect

This is the final technical report for the SBIR Phase I project titled 'A System for Conducting Sophisticated Mechanical Tests in Situ with High Energy Synchrotron X-Rays.' Experiments using diffraction of synchrotron radiation that help scientists understand engineering material failure modes, such as fracture and fatigue, require specialized machinery. This machinery must be able to induce these failure modes in a material specimen while adhering to strict size, weight, and geometric limitations prescribed by diffraction measurement techniques. During this Phase I project, Mechanical Solutions, Inc. (MSI) developed one such machine capable of applying uniaxial mechanical loading to a material specimen in both tension and compression, with zero backlash while transitioning between the two. Engineers currently compensate for a lack of understanding of fracture and fatigue by employing factors of safety in crucial system components. Thus, mechanical and structural parts are several times bigger, thicker, and heavier than they need to be. The scientific discoveries that result from diffraction experiments which utilize sophisticated mechanical loading devices will allow for broad material, weight, fuel, and cost savings in engineering design across all industries, while reducing the number of catastrophic failures in transportation, power generation, infrastructure, and all other engineering systems. With an existing load frame as the starting point, the research focused on two main areas: (1) the design of a specimen alignment and gripping system that enables pure uniaxial tension and compression loading (and no bending, shear, or torsion), and (2) development of a feedback control system that is adaptive and thus can maintain a load set point despite changing specimen material properties (e.g. a decreasing stiffness during yield).

Jeremy Weiss

2012-08-02T23:59:59.000Z

37

Method for improving x-ray diffraction determinations of residual stress in nickel-base alloys  

DOE Patents (OSTI)

A process for improving the technique of measuring residual stress by x-ray diffraction in pieces of nickel-base alloys is discussed. Part of a predetermined area of the surface of a nickel-base alloy is covered with a dispersion. This exposes the covered and uncovered portions of the surface of the alloy to x-rays by way of an x-ray diffractometry apparatus, making x-ray diffraction determinations of the exposed surface, and measuring the residual stress in the alloy based on these determinations. The dispersion is opaque to x-rays and serves a dual purpose, since it masks off unsatisfactory signals such that only a small portion of the surface is measured, and it supplies an internal standard by providing diffractogram peaks comparable to the peaks of the nickel alloy so that the alloy peaks can be very accurately located regardless of any sources of error external to the sample. 2 figs.

Berman, R.M.; Cohen, I.

1988-04-26T23:59:59.000Z

38

Kinetics of the sulfur oxidation on palladium: A combined in situ x-ray photoelectron spectroscopy and density-functional study  

SciTech Connect

We studied the reaction kinetics of sulfur oxidation on the Pd(100) surface by in situ high resolution x-ray photoelectron spectroscopy and ab initio density functional calculations. Isothermal oxidation experiments were performed between 400 and 500 K for small amounts ({approx}0.02 ML) of preadsorbed sulfur, with oxygen in large excess. The main stable reaction intermediate found on the surface is SO{sub 4}, with SO{sub 2} and SO{sub 3} being only present in minor amounts. Density-functional calculations depict a reaction energy profile, which explains the sequential formation of SO{sub 2}, SO{sub 3}, and eventually SO{sub 4}, also highlighting that the in-plane formation of SO from S and O adatoms is the rate limiting step. From the experiments we determined the activation energy of the rate limiting step to be 85 {+-} 6 kJ mol{sup -1} by Arrhenius analysis, matching the calculated endothermicity of the SO formation.

Gotterbarm, Karin; Hoefert, Oliver; Lorenz, Michael P. A.; Streber, Regine; Papp, Christian [Lehrstuhl fuer Physikalische Chemie II, Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058 Erlangen (Germany); Luckas, Nicola; Vines, Francesc [Lehrstuhl fuer Theoretische Chemie, Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058 Erlangen (Germany); Steinrueck, Hans-Peter [Lehrstuhl fuer Physikalische Chemie II, Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058 Erlangen (Germany); Erlangen Catalysis Resource Center (ECRC), Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058 Erlangen (Germany); Interdisciplinary Center for Interface Controlled Processes, Egerlandstr. 3, 91058 Erlangen (Germany); Goerling, Andreas [Lehrstuhl fuer Theoretische Chemie, Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058 Erlangen (Germany); Interdisciplinary Center for Interface Controlled Processes, Egerlandstr. 3, 91058 Erlangen (Germany)

2012-03-07T23:59:59.000Z

39

Plasma-Density Determination from X-Ray Radiography of Laser-Driven Spherical Implosions  

E-Print Network (OSTI)

The fuel layer density of an imploding laser-driven spherical shell is inferred from framed x-ray radiographs. The density distribution is determined by using Abel inversion to compute the radial distribution of the opacity ...

Frenje, Johan A.

40

Quantitative determination of mineral composition by powder x-ray diffraction  

DOE Patents (OSTI)

An external standard intensity ratio method is used for quantitatively determining mineralogic compositions of samples by x-ray diffraction. The method uses ratios of x-ray intensity peaks from a single run. Constants are previously determined for each mineral which is to be quantitatively measured. Ratios of the highest intensity peak of each mineral to be quantified in the sample and the highest intensity peak of a reference mineral contained in the sample are used to calculate sample composition.

Pawloski, G.A.

1984-08-10T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray  

NLE Websites -- All DOE Office Websites (Extended Search)

Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray Absorption Techniques Monday, September 9, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Dr. Vanessa Pool The dopant behavior of spinels has been investigated for over half a century and yet new insight into this class of materials is still being made today. In this work, the question of dopant site preference is explored for the nanoparticle regime. Iron oxide nanoparticles have numerous exciting applications. To realize these applications, controlling the preferred dopant site and valence within the host material is important. X-ray Absorption Spectroscopy (XAS) and X-ray Magnetic Circular Dichroism (XMCD) are element specific techniques with magnetic contrast that give insights into the material composition. Using both

42

In Situ Synchrotron Based X-ray Fluorescence and Scattering Measurements During Atomic Layer Deposition: Initial Growth of HfO2 on Si and Ge Substrates  

SciTech Connect

The initial growth of HfO{sub 2} was studied by means of synchrotron based in situ x-ray fluorescence (XRF) and grazing incidence small angle x-ray scattering (GISAXS). HfO{sub 2} was deposited by atomic layer deposition (ALD) using tetrakis(ethylmethylamino)hafnium and H{sub 2}O on both oxidized and H-terminated Si and Ge surfaces. XRF quantifies the amount of deposited material during each ALD cycle and shows an inhibition period on H-terminated substrates. No inhibition period is observed on oxidized substrates. The evolution of film roughness was monitored using GISAXS. A correlation is found between the inhibition period and the onset of surface roughness.

K Devloo-Casier; J Dendooven; K Ludwig; G Lekens; J DHaen; C Detavernier

2011-12-31T23:59:59.000Z

43

In situ dehydration behavior of zeolite-like pentagonite: A single-crystal X-ray study  

SciTech Connect

The structural modifications upon heating of pentagonite, Ca(VO)(Si{sub 4}O{sub 10}){center_dot}4H{sub 2}O (space group Ccm2{sub 1}, a=10.3708(2), b=14.0643(2), c=8.97810(10) A, V=1309.53(3) A{sup 3}) were investigated by in situ temperature dependent single-crystal X-ray structure refinements. Diffraction data of a sample from Poona district (India) have been measured in steps of 25 up to 250 Degree-Sign C and in steps of 50 Degree-Sign C between 250 and 400 Degree-Sign C. Pentagonite has a porous framework structure made up by layers of silicate tetrahedra connected by V{sup 4+}O{sub 5} square pyramids. Ca and H{sub 2}O molecules are extraframework occupants. Room temperature diffraction data allowed refinement of H positions. The hydrogen-bond system links the extraframework occupants to the silicate layers and also interconnects the H{sub 2}O molecules located inside the channels. Ca is seven-fold coordinated forming four bonds to O of the tetrahedral framework and three bonds to extraframework H{sub 2}O. The H{sub 2}O molecule at O9 showing a high displacement parameter is not bonded to Ca. The dehydration in pentagonite proceeds in three steps. At 100 Degree-Sign C the H{sub 2}O molecule at O8 was released while O9 moved towards Ca. As a consequence the displacement parameter of H{sub 2}O at O9 halved compared to that at room temperature. The unit-cell volume decreased to 1287.33(3) A{sup 3} leading to a formula with 3H{sub 2}O per formula unit (pfu). Ca remained seven-fold coordinated. At 175 Degree-Sign C Ca(VO)(Si{sub 4}O{sub 10}){center_dot}3H{sub 2}O transformed into a new phase with 1H{sub 2}O molecule pfu characterized by doubling of the c axis and the monoclinic space group Pn. Severe bending of specific T--O--T angles led to contraction of the porous three-dimensional framework. In addition, H{sub 2}O at O9 was expelled while H{sub 2}O at O7 approached a position in the center of the channel. The normalized volume decreased to 1069.44(9) A{sup 3}. The Ca coordination reduced from seven- to six-fold. At 225 Degree-Sign C a new anhydrous phase with space group Pna2{sub 1} but without doubling of c had formed. Release of H{sub 2}O at O7 caused additional contraction of T--O--T angles and volume reduction (V=1036.31(9) A{sup 3}). Ca adopted five-fold coordination. During heating excursion up to 400 Degree-Sign C this anhydrous phase remained preserved. Between room temperature and 225 Degree-Sign C the unit-cell volume decreased by 21% due to dehydration. The dehydration steps compare well with the thermo-gravimetric data reported in the literature. - Graphical abstract: Pentagonite structure at room temperature and at 225 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer We investigate the relationship between the removal of H{sub 2}O molecules and structural modifications of the framework of pentagonite. Black-Right-Pointing-Pointer Pentagonite undergoes phase transitions upon heating. Black-Right-Pointing-Pointer We analyze similarities and differences between pentagonite and related structures.

Danisi, Rosa Micaela, E-mail: rosa.danisi@krist.unibe.ch [Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, Bern CH-3012 (Switzerland); Armbruster, Thomas; Lazic, Biljana [Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, Bern CH-3012 (Switzerland)

2013-01-15T23:59:59.000Z

44

In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution  

SciTech Connect

A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

2010-03-31T23:59:59.000Z

45

Initial stages of ITO/Si interface formation: In situ x-ray photoelectron spectroscopy measurements upon magnetron sputtering and atomistic modelling using density functional theory  

SciTech Connect

Initial stages of indium tin oxide (ITO) growth on a polished Si substrate upon magnetron sputtering were studied experimentally using in-situ x-ray photoelectron spectroscopy measurements. The presence of pure indium and tin, as well as Si bonded to oxygen at the ITO/Si interface were observed. The experimental observations were compared with several atomistic models of ITO/Si interfaces. A periodic model of the ITO/Si interface was constructed, giving detailed information about the local environment at the interface. Molecular dynamics based on density functional theory was performed, showing how metal-oxygen bonds are broken on behalf of silicon-oxygen bonds. These theoretical results support and provide an explanation for the present as well as previous ex-situ and in-situ experimental observations pointing to the creation of metallic In and Sn along with the growth of SiO{sub x} at the ITO/Si interface.

Løvvik, O. M.; Diplas, S.; Ulyashin, A. [SINTEF Materials and Chemistry, Forskningsveien 1, NO-0314 Oslo (Norway); Romanyuk, A. [University of Basel, Kingelbergstr. 82, CH-4056 Basel (Switzerland)

2014-02-28T23:59:59.000Z

46

In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy  

E-Print Network (OSTI)

Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry feature...

Day, Sarah J; Evans, Aneurin; Parker, Julia E

2015-01-01T23:59:59.000Z

47

Online in situ x-ray diffraction setup for structural modification studies during swift heavy ion irradiation  

SciTech Connect

The high energy density of electronic excitations due to the impact of swift heavy ions can induce structural modifications in materials. We present an x-ray diffractometer called ALIX (''Analyse en Ligne sur IRRSUD par diffraction de rayons X''), which has been set up at the low-energy beamline (IRRadiation SUD - IRRSUD) of the Grand Accelerateur National d'Ions Lourds facility, to allow the study of structural modification kinetics as a function of the ion fluence. The x-ray setup has been modified and optimized to enable irradiation by swift heavy ions simultaneously to x-ray pattern recording. We present the capability of ALIX to perform simultaneous irradiation-diffraction by using energy discrimination between x-rays from diffraction and from ion-target interaction. To illustrate its potential, results of sequential or simultaneous irradiation-diffraction are presented in this article to show radiation effects on the structural properties of ceramics. Phase transition kinetics have been studied during xenon ion irradiation of polycrystalline MgO and SrTiO{sub 3}. We have observed that MgO oxide is radiation-resistant to high electronic excitations, contrary to the high sensitivity of SrTiO{sub 3}, which exhibits transition from the crystalline to the amorphous state during irradiation. By interpreting the amorphization kinetics of SrTiO{sub 3}, defect overlapping models are discussed as well as latent track characteristics. Together with a transmission electron microscopy study, we conclude that a single impact model describes the phase transition mechanism.

Grygiel, C.; Lebius, H.; Bouffard, S.; Quentin, A.; Ramillon, J. M.; Madi, T.; Guillous, S.; Been, T.; Guinement, P.; Lelievre, D.; Monnet, I. [CIMAP, CEA-CNRS-ENSICAEN-UCBN, BP 5133, 14070 Caen Cedex 5 (France)

2012-01-15T23:59:59.000Z

48

Hydrogen absorption in epitaxial W/Nb(001) and polycrystalline Fe/Nb(110) multilayers studied in-situ by X-ray/neutron scattering techniques and X-ray absorption spectroscopy  

SciTech Connect

Hydrogen can be absorbed in large quantities by 100 {angstrom} thin Nb layers embedded in epitaxial W/Nb and polycrystalline Fe/Nb multilayers. The solubility and the hydrogen-induced structural changes of the host lattice are explored in-situ by small-angle neutron/X-ray reflectometry and high-angle diffraction. These measurements reveal for both systems that the relative out-of-plane expansion of the Nb layers is considerably larger than the relative increase of the Nb interplanar spacing indicating two distinctly different mechanisms of hydrogen absorption. In Fe/Nb multilayers, hydrogen expands the Nb interplanar spacing in a continuous way as function of the external pressure. In contrast, the Nb lattice expansion is discontinuous in epitaxial W/Nb multilayers: A jump in the Nb(002) Bragg reflection position occurs at a critical hydrogen pressure of 1 mbar. In-situ EXAFS spectroscopy also exhibits an irreversible expansion of the Nb lattice in the film plane for p{sub H{sub 2}}> 1 mbar. This can be regarded as a structural phase transition from an exclusively out-of-plane to a three-dimensionally expanded state at low and high hydrogen pressures, respectively.

Klose, F.; Rehm, C.; Fieber-Erdmann, M.; Holub-Krappe, E.; Bleif, H. J.; Sowers, H.; Goyette, R.; Troger, L.; Maletta, H.

1999-11-02T23:59:59.000Z

49

In-situ stress analysis with X-Ray diffraction for yield locus characterization of sheet metals  

SciTech Connect

A main problem in the field of sheet metal characterization is the inhomogeneous plastic deformation in the gauge regions of specimens which causes the analytically calculated stresses to differ from the sought state of stress acting in the middle of the gauge region. To overcome this problem, application of X-Ray diffraction is analyzed. For that purpose a mobile X-ray diffractometer and an optical strain measurement system are mounted on a universal tensile testing machine. This enables the recording of the whole strain and stress history of a material point. The method is applied to uniaxial tension tests, plane strain tension tests and shear tests to characterize the interstitial free steel alloy DC06. The applicability of the concepts of stress factors is verified by uniaxial tension tests. The experimentally obtained values are compared with the theoretical values calculated with crystal elasticity models utilizing the orientation distribution functions (ODF). The relaxation problem is addressed which shows itself as drops in the stress values with the strain kept at a constant level. This drop is analyzed with elasto-viscoplastic material models to correct the measured stresses. Results show that the XRD is applicable to measure the stresses in sheet metals with preferred orientation. The obtained yield locus is expressed with the Yld2000–2D material model and an industry oriented workpiece is analyzed numerically. The comparison of the strain distribution on the workpiece verifies the identified material parameters.

Güner, A.; Tekkaya, A. E. [Institute of Forming Technology and Lightweight Construction, TU Dortmund University, Baroper Str. 301, 44227 Dortmund (Germany); Zillmann, B.; Lampke, T. [Institute of Materials Science and Engineering, Chemnitz University of Technology, Erfenschlager Strasse 73 D-09125 Chemnitz (Germany)

2013-12-16T23:59:59.000Z

50

Single x-ray transmission system for bone mineral density determination  

SciTech Connect

Bones are the support of the body. They are composed of many inorganic compounds and other organic materials that all together can be used to determine the mineral density of the bones. The bone mineral density is a measure index that is widely used as an indicator of the health of the bone. A typical manner to evaluate the quality of the bone is a densitometry study; a dual x-ray absorptiometry system based study that has been widely used to assess the mineral density of some animals' bones. However, despite the success stories of utilizing these systems in many different applications, it is a very expensive method that requires frequent calibration processes to work properly. Moreover, its usage in small species applications (e.g., rodents) has not been quite demonstrated yet. Following this argument, it is suggested that there is a need for an instrument that would perform such a task in a more reliable and economical manner. Therefore, in this paper we explore the possibility to develop a new, affordable, and reliable single x-ray absorptiometry system. The method consists of utilizing a single x-ray source, an x-ray image sensor, and a computer platform that all together, as a whole, will allow us to calculate the mineral density of the bone. Utilizing an x-ray transmission theory modified through a version of the Lambert-Beer law equation, a law that expresses the relationship among the energy absorbed, the thickness, and the absorption coefficient of the sample at the x-rays wavelength to calculate the mineral density of the bone can be advantageous. Having determined the parameter equation that defines the ratio of the pixels in radiographies and the bone mineral density [measured in mass per unit of area (g/cm{sup 2})], we demonstrated the utility of our novel methodology by calculating the mineral density of Wistar rats' femur bones.

Jimenez-Mendoza, Daniel; Vargas-Vazquez, Damian [Division de Investigacion y Posgrado, Facultad de Ingenieria, Universidad Autonoma de Queretaro, Cerro de las Campanas s/n., C.P. 76010, Queretaro, Qro. (Mexico); Espinosa-Arbelaez, Diego G. [Posgrado en Ciencia e Ingenieria en Materiales, Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Av. Universidad 3000, C.P. 04510, Coyoacan, Mexico D.F. (Mexico); Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Giraldo-Betancur, Astrid L. [Centro de Investigacion y de Estudios Avanzados del Instituto Politecnico Nacional, Libramiento Norponiente 2000, C.P. 76230, Fracc. Real de Juriquilla, Qro. (Mexico); Hernandez-Urbiola, Margarita I. [Posgrado en Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico); Rodriguez-Garcia, Mario E. [Departamento de Nanotecnologia, Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Campus Juriquilla, Boulevard Juriquilla 3001, C.P. 76230, A.P. 1-1010, Juriquilla, Qro. (Mexico)

2011-12-15T23:59:59.000Z

51

Stereochemistry Determination by Powder X-ray Diffraction Analysis and NMR Spectroscopy Residual Dipolar Couplings  

SciTech Connect

A matter of technique: For a new steroidal lactol, jaborosalactol 24 (1), isolated from Jaborosa parviflora, NMR spectroscopy residual dipolar couplings and powder X-ray diffraction analysis independently gave the same stereochemistry at C23-C26. Conventional NMR spectroscopic techniques, such as NOE and {sup 3}J coupling-constant analysis failed to unambiguously determine this stereochemistry.

Garcia, M.; Pagola, S; Navarro-Vasquez, A; Phillips, D; Gayathri, C; Krakauer, H; Stephens, P; Nicotra, V; Gil, R

2009-01-01T23:59:59.000Z

52

Fragmentation and Limits to Dynamical Scaling in Viscous Coarsening: An Interrupted in situ X-Ray Tomographic Study  

E-Print Network (OSTI)

X-Ray microtomography was used to follow the coarsening of the structure of a ternary silicate glass experiencing phase separation in the liquid state. The volumes, surfaces, mean and Gaussian curvatures of the domains of minority phase were measured after reconstruction of the 3D images and segmentation. A linear growth law of the characteristic length scale $\\ell \\sim t$ was observed. A detailed morphological study was performed. While dynamical scaling holds for most of the geometrical observables under study, a progressive departure from scaling invariance of the distributions of local curvatures was evidenced. The latter results from a gradual fragmentation of the structure in the less viscous phase that also leads to a power-law size distribution of isolated domains.

David Bouttes; Emmanuelle Gouillart; Elodie Boller; Davy Dalmas; Damien Vandembroucq

2014-09-04T23:59:59.000Z

53

In-situ x-ray diffraction study of the growth of highly strained epitaxial BaTiO{sub 3} thin films  

SciTech Connect

In-situ synchrotron x-ray diffraction was performed during the growth of BaTiO{sub 3} thin films on SrTiO{sub 3} substrates using both off-axis RF magnetron sputtering and pulsed laser deposition techniques. It was found that the films were ferroelectric during the growth process, and the presence or absence of a bottom SrRuO{sub 3} electrode played an important role in the growth of the films. Pulsed laser deposited films on SrRuO{sub 3} displayed an anomalously high tetragonality and unit volume, which may be connected to the previously predicted negative pressure phase of BaTiO{sub 3}.

Sinsheimer, J.; Callori, S. J.; Ziegler, B.; Bein, B.; Dawber, M. [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11794-3800 (United States)] [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11794-3800 (United States); Chinta, P. V.; Ashrafi, A.; Headrick, R. L. [Department of Physics, Cook Physical Science Building, University of Vermont, Burlington, Vermont 05405 (United States)] [Department of Physics, Cook Physical Science Building, University of Vermont, Burlington, Vermont 05405 (United States)

2013-12-09T23:59:59.000Z

54

Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy  

SciTech Connect

We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600?°C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

Benkert, A., E-mail: andreas.benkert@kit.edu, E-mail: l.weinhardt@kit.edu [Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology (KIT), Hermann-v.-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Gemeinschaftslabor für Nanoanalytik, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany); Blum, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Meyer, F. [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany)] [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Wilks, R. G. [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)] [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Yang, W. [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)] [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Bär, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus (Germany); and others

2014-01-15T23:59:59.000Z

55

Chain-length dependent growth dynamics of n-alkanes on silica investigated by energy-dispersive x-ray reflectivity in situ and in real-time  

SciTech Connect

We compare the growth dynamics of the three n-alkanes C{sub 36}H{sub 74}, C{sub 40}H{sub 82}, and C{sub 44}H{sub 90} on SiO{sub 2} using real-time and in situ energy-dispersive x-ray reflectivity. All molecules investigated align in an upright-standing orientation on the substrate and exhibit a transition from layer-by-layer growth to island growth after about 4 monolayers under the conditions employed. Simultaneous fits of the reflected intensity at five distinct points in reciprocal space show that films formed by longer n-alkanes roughen faster during growth. This behavior can be explained by a chain-length dependent height of the Ehrlich-Schwoebel barrier. Further x-ray diffraction measurements after growth indicate that films consisting of longer n-alkanes also incorporate more lying-down molecules in the top region. While the results reveal behavior typical for chain-like molecules, the findings can also be useful for the optimization of organic field effect transistors where smooth interlayers of n-alkanes without coexistence of two or more molecular orientations are required.

Weber, C.; Rukat, T.; Schaefer, P.; Kowarik, S. [Institut fuer Physik, Humboldt-Universitaet zu Berlin, Newtonstr. 15, 12489 Berlin (Germany); Frank, C.; Schreiber, F. [Institut fuer Angewandte Physik, Universitaet Tuebingen, Auf der Morgenstelle 10, 72076 Tuebingen (Germany); Bommel, S. [Institut fuer Physik, Humboldt-Universitaet zu Berlin, Newtonstr. 15, 12489 Berlin (Germany); Deutsches Elektronen-Synchrotron (DESY), Notkestrasse 85, 22607 Hamburg (Germany); Leitenberger, W. [Institut fuer Physik, Universitaet Potsdam, Karl-Liebknecht-Strasse 24/25,14476 Potsdam-Golm (Germany)

2012-05-28T23:59:59.000Z

56

In-situ synchrotron energy-dispersive x-ray diffraction study of thin Pd foils with Pd:D and Pd:H concentrations up to 1:1  

SciTech Connect

Time resolved, in-situ, energy dispersive x-ray diffraction was performed in an electrolysis cell during electrochemical loading of palladium foil cathodes with hydrogen and deuterium. Concentrations of H:Pd (D:Pd) up to 1:1 in 0.1 M LiOH (LiOD) in H{sub 2}O (D{sub 2}O) electrolyte were obtained, as determined by both the Pd lattice parameter and cathode resistivity. In addition, some indications on the kinetics of loading and deloading of hydrogen from the Pd surface were obtained. The alpha-beta phase transformations were clearly delineated but no new phases at high concentration were determined.

Knies, D. L.; Grabowski, K. S.; Dominguez, D. D.; Qadri, S. B.; Hubler, G. K. [U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Violante, V. [ENEA, Frascati (Italy); Hu, J. Z. [NSLS, Brookhaven National Laboratory, Brookhaven, New York 11973 (United States); He, J. H. [Nova Research, Alexandria, Virginia 22308 (United States)

2012-10-15T23:59:59.000Z

57

In situ x-ray photoelectron spectroscopy studies of gas/solidinterfaces at near-ambient conditions  

SciTech Connect

X-ray photoelectron spectroscopy (XPS) is a quantitative, chemically specific technique with a probing depth of a few angstroms to a few nanometers. It is therefore ideally suited to investigate the chemical nature of the surfaces of catalysts. Because of the scattering of electrons by gas molecules, XPS is generally performed under vacuum conditions. However, for thermodynamic and/or kinetic reasons, the catalyst's chemical state observed under vacuum reaction conditions is not necessarily the same as that of a catalyst under realistic operating pressures. Therefore, investigations of catalysts should ideally be performed under reaction conditions, i.e., in the presence of a gas or gas mixtures. Using differentially pumped chambers separated by small apertures, XPS can operate at pressures of up to 1 Torr, and with a recently developed differentially pumped lens system, the pressure limit has been raised to about 10 Torr. Here, we describe the technical aspects of high-pressure XPS and discuss recent applications of this technique to oxidation and heterogeneous catalytic reactions on metal surfaces.

Bluhm, Hendrik; Havecker, Michael; Knop-Gericke, Axel; Kiskinova,Maya; Schlogl, Robert; Salmeron, Miquel

2007-12-03T23:59:59.000Z

58

In situ X-ray diffraction strain-controlled study of Ti–Nb–Zr and Ti–Nb–Ta shape memory alloys: crystal lattice and transformation features  

SciTech Connect

Phase and structure transformations in biomedical Ti–21.8Nb–6.0Zr (TNZ) and Ti–19.7Nb–5.8Ta (TNT) shape memory alloys (at.%) under and without load in the ? 150 to 100 °S temperature range are studied in situ using an original tensile module for a low-temperature chamber of an X-ray diffractometer. Alpha?- and beta-phase lattice parameters, the crystallographic resource of recovery strain, phase and structure transformation sequences, and microstress appearance and disappearance are examined, compared and discussed. For both alloys, the crystallographic resource of recovery strain decreases with temperature increase to become 4.5% for TNZ and 2.5% for TNT alloy (at RT). Loading at low temperatures leads to additional ??-phase formation and reorientation. Heating under load, as compared to strain-free heating, affects the reverse transformation sequence of both alloys in different ways. For TNZ alloy, strain-free heating results in simultaneous ??? and ???? transformations, whereas during heating under stress, they are sequential: ? + ???? precedes ????. For TNT alloy, strain-free heating results in reverse ???? transformation, whereas during heating under stress, ???? transformation is preceded by ??-phase reorientation. - Highlights: • Comparative in situ XRD analysis of Ti–Nb–Zr(Ta) shape memory alloys is realized. • Lattice parameters of ?- and ??-phases are calculated in the ? 150 to + 100 °C range. • The higher the temperature, the lower the ???? transformation strain. • Loading at low temperatures results in ??-phase formation and reorientation. • Transformation sequences upon heating with and without loading are different.

Dubinskiy, S. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Prokoshkin, S. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Brailovski, V., E-mail: vladimir.brailovski@etsmtl.ca [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Inaekyan, K. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Korotitskiy, A. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation)

2014-02-15T23:59:59.000Z

59

Determination of the iron-sulfur distances in rubredoxin by x-ray absorption spectroscopy  

Science Journals Connector (OSTI)

...x-ray flux from the synchrotron radiation at the Stanford Synchroton Radiation Project has been used to study the extended x-ray...x-ray flux from the synchrotron radiation at the Stanford Synchroton Radiation Project has been used to study the extended x-ray...

R G Shulman; P Eisenberger; W E Blumberg; N A Stombaugh

1975-01-01T23:59:59.000Z

60

In-situ x-ray diffraction studies of host-guest properties in nanoporous zinc-triazolate-based framework materials.  

SciTech Connect

Two nanoporous metal-organic framework materials incorporating the exotridentate bridging ligand 3-amino-1,2,4-triazolate (AmTAZ) have been synthesized through variation of secondary bridging anions: [Zn{sub 3}(AmTAZ){sub 3}S](NO{sub 3}) {center_dot} (H{sub 2}O) (1 {center_dot} (H{sub 2}O)) and Zn{sub 7}(AmTAZ){sub 8}(CO{sub 3}){sub 2}(OH){sub 2} {center_dot} 2(EtOH) (2 {center_dot} 2(EtOH); EtOH = ethanol). 1 {center_dot} (H{sub 2}O) crystallizes in the cubic space group I23 and is constructed from triangular Zn{sub 3}S units that are bridged through AmTAZ ligands into a cationic three-dimensional (3D) network with nitrate and water molecules residing in the cavities. 2 {center_dot} 2(EtOH) crystallizes in the monoclinic space group C2/c and shows a complex 3D network constructed from seven crystallographically unique zinc centers bridged by AmTAZ, carbonate, and hydroxide anions. The porous nature of both materials has been explored by thermogravimetric analysis, nitrogen sorption, and in situ synchrotron-based powder X-ray diffraction.

Halder, G. J.; Park, H.; Funk, R. J.; Chapman, K. W.; Engerer, L. K.; Geiser, U.; Schlueter, J. A.

2009-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


61

Class H Oil Well Cement Hydration at Elevated Temperatures in the Presence of Retarding Agents: An In Situ High-Energy X-ray Diffraction Study  

SciTech Connect

In situ powder X-ray diffraction was used to examine the hydration of API Class H cement slurries, with a water-to-cement ratio of 0.394, at 66, 93, 121, and 177 C under autogenous pressure in the presence of varying amounts of the additives tartaric acid, modified lignosulfonate, and AMPS (2-acrylamido-2-methylpropanesulfonic acid) copolymer. All of these retarding agents inhibited the hydration of crystalline C{sub 3}S (Ca{sub 3}SiO{sub 5}), but other modes of action were also apparent. The formation of ettringite was suppressed when tartaric acid was used by itself or in combination with other additives. Changes in the hydration of C{sub 3}S vs time could not be correlated in a simple way with the observed pumping times for the cement slurries. The largest changes in pumping time as a function of temperature occurred in a temperature interval where ettringite/monosulfate decomposes and crystalline hydrogarnet starts to be formed.

Jupe, Andrew C.; Wilkinson, Angus P.; Luke, Karen; Funkhouser, Gary P. (Halliburton); (GIT)

2008-07-08T23:59:59.000Z

62

In situ X-ray diffraction study of the lithium excess layered oxide compound Li[Li0.2Ni0.2Mn0.6]O-2 during electrochemical cycling  

SciTech Connect

In situ X-ray diffraction patterns were collected using a laboratory X-ray diffractometer during the first electrochemical charge/discharge cycle of the layered lithium excess compound Li[Li{sub 0.2}Ni{sub 0.2}Mn{sub 0.6}]O{sub 2} in the family of Li[Ni{sub x}Li{sub 1/3 - 2x/3}Mn{sub 2/3 - x/3}]O{sub 2} (x = 1/5). Dynamic changes in peak positions, lattice parameters, and microstrain help to explain the lithium de-intercalation mechanism in this class of materials. Strong anisotropy is observed in the shifts of the lattice parameters during the first cycle. The in situ electrochemical measurement shows dynamically changing strain during the first electrochemical cycle that is explained by known lithium and transition metal (TM) migration mechanisms.

Fell, Christopher [University of Florida, Gainesville; Meng, Ying Shirley [University of California, San Diego; Jones, Jacob [University of Florida

2012-01-01T23:59:59.000Z

63

In situ X-ray diffraction study of the lithium excess layered oxide compound Li[Li0.2Ni0.2Mn0.6]O2 during electrochemical cycling  

Science Journals Connector (OSTI)

In situ X-ray diffraction patterns were collected using a laboratory X-ray diffractometer during the first electrochemical charge/discharge cycle of the layered lithium excess compound Li[Li0.2Ni0.2Mn0.6]O2 in the family of Li[NixLi1/3 ? 2x/3Mn2/3 ? x/3]O2 (x = 1/5). Dynamic changes in peak positions, lattice parameters, and microstrain help to explain the lithium de-intercalation mechanism in this class of materials. Strong anisotropy is observed in the shifts of the lattice parameters during the first cycle. The in situ electrochemical measurement shows dynamically changing strain during the first electrochemical cycle that is explained by known lithium and transition metal (TM) migration mechanisms.

Christopher R. Fell; Miaofang Chi; Ying Shirley Meng; Jacob L. Jones

2012-01-01T23:59:59.000Z

64

Brucite [Mg(OH2)] carbonation in wet supercritical CO2: An in situ high pressure X-ray diffraction study  

Science Journals Connector (OSTI)

Understanding mechanisms and kinetics of mineral carbonation reactions relevant to sequestering carbon dioxide as a supercritical fluid (scCO2) in geologic formations is crucial to accurately predicting long-term storage risks. Most attention so far has been focused on reactions occurring between silicate minerals and rocks in the aqueous dominated CO2-bearing fluid. However, water-bearing scCO2 also comprises a reactive fluid, and in this situation mineral carbonation mechanisms are poorly understood. Using in situ high-pressure X-ray diffraction, the carbonation of brucite [Mg(OH)2] in wet scCO2 was examined at pressure (82 bar) as a function of water concentration and temperature (50 and 75 °C). Exposing brucite to anhydrous scCO2 at either temperature resulted in little or no detectable reaction over three days. However, addition of trace amounts of water resulted in partial carbonation of brucite into nesquehonite [MgCO3·3H2O] within a few hours at 50 °C. By increasing water content to well above the saturation level of the scCO2, complete conversion of brucite into nesquehonite was observed. Tests conducted at 75 °C resulted in the conversion of brucite into magnesite [MgCO3] instead, apparently through an intermediate nesquehonite step. Raman spectroscopy applied to brucite reacted with 18O-labeled water in scCO2 show it was incorporated into carbonate at a relatively high concentration. This supports a carbonation mechanism with at least one step involving a direct reaction between the mineral and water molecules without mediation by a condensed aqueous layer.

H.T. Schaef; C.F. Windisch Jr.; B.P. McGrail; P.F. Martin; K.M. Rosso

2011-01-01T23:59:59.000Z

65

Influence of electron irradiation and heating on secondary electron yields from non-evaporable getter films observed with in situ x-ray photoelectron spectroscopy  

SciTech Connect

Nonevaporable getter (NEG) film has been used for the beam ducts of particle accelerators as a pump having a large area. NEG film has been considered to have a low outgas rate induced by energetic particle irradiation and a low secondary electron yield (SEY). In this article, we focused on SEY measurements and in situ surface characterization of four NEG film samples using x-ray photoelectron spectroscopy (XPS). The NEG samples were TiZrV thin films deposited by magnetron sputtering at 100 or 300 deg. C on stainless steel. In addition, NEG samples saturated by CO gas exposure were prepared. SEY and XPS measurements of the surfaces of NEG samples were carried out under the conditions of as received, after electron beam irradiation, and after heating at 200 deg. C for 24 h. The maximum SEY values of the primary electron energy dependence, {delta}{sub max}, of all NEG samples decreased to around 1 by electron beam irradiation owing to a change in the carbon impurities, such as carbon oxide, carbon hydroxide, and hydrocarbon, to graphite state (graphitization) during the irradiation. After heating, {delta}{sub max} values of the NEG samples without CO gas exposure were also around 1 owing to the carbonization of Ti, Zr, and V. The {delta}{sub max}{approx_equal}1 was remarkably lower than that of copper baked under the same conditions. However, in saturated NEG samples, metal carbides were not produced to a significant extent by heating, and the {delta}{sub max} values did not decrease, showing values of 1.5-1.7.

Nishiwaki, Michiru; Kato, Shigeki [High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan) and Department of Accelerator Science, The Graduate University for Advanced Studies, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan)

2007-07-15T23:59:59.000Z

66

Determination of the polarization state of x rays with the help of anomalous transmission  

SciTech Connect

Besides intensity and direction, the polarization of an electromagnetic wave provides characteristic information on the crossed medium. Here, we present two methods for the determination of the polarization state of x rays by polarizers based on anomalous transmission (Borrmann effect). Using a polarizer-analyzer setup, we have measured a polarization purity of less than 1.5?×?10{sup ?5}, three orders of magnitude better than obtained in earlier work. Using the analyzer crystal in multiple-beam case with slightly detuned azimuth, we show how the first three Stokes parameters can be determined with a single angular scan. Thus, polarization analyzers based on anomalous transmission make it possible to detect changes of the polarization in a range from degrees down to arcseconds.

Schulze, K. S., E-mail: kai.sven.schulze@uni-jena.de; Uschmann, I.; Förster, E. [Institut für Optik und Quantenelektronik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Helmholtz-Institut Jena, Fröbelstieg 3, D-07743 Jena (Germany); Marx, B.; Paulus, G. G. [Institut für Optik und Quantenelektronik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Stöhlker, T. [Helmholtz-Institut Jena, Fröbelstieg 3, D-07743 Jena (Germany)

2014-04-14T23:59:59.000Z

67

In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution  

E-Print Network (OSTI)

range requires the use of UHV instrumentation. However byseparate the samples from the UHV environment, soft x-rays1c) of the cell was made of a UHV compatible and chemically

Jiang, Peng

2010-01-01T23:59:59.000Z

68

Evaluation of X-ray Diffraction of Bit Cuttings as a Proxy for Core Data in Determining Bulk Mineralogy and Clay Species, Bakken Formation, Williston Basin.  

E-Print Network (OSTI)

??The principal question addressed in this study concerns the applicability of x-ray diffractometry to determine bulk rock mineralogy and clay species in the absence of… (more)

Barnes, Stuart Lee

2011-01-01T23:59:59.000Z

69

Edible oil structures at low and intermediate concentrations. II. Ultra-small angle X-ray scattering of in situ tristearin solids in triolein  

SciTech Connect

Ultra-small angle X-ray scattering has been used for the first time to elucidate, in situ, the aggregation structure of a model edible oil system. The three-dimensional nano- to micro-structure of tristearin solid particles in triolein solvent was investigated using 5, 10, 15, and 20% solids. Three different sample preparation procedures were investigated: two slow cooling rates of 0.5°/min, case 1 (22 days of storage at room temperature) and case 2 (no storage), and one fast cooling of 30°/min, case 3 (no storage). The length scale investigated, by using the Bonse-Hart camera at beamline ID-15D at the Advanced Photon Source, Argonne National Laboratory, covered the range from 300?Å to 10??m. The unified fit and the Guinier-Porod models in the Irena software were used to fit the data. The former was used to fit 3 structural levels. Level 1 structures showed that the primary scatterers were essentially 2-dimensional objects for the three cases. The scatterers possessed lateral dimensions between 1000 and 4300?Å. This is consistent with the sizes of crystalline nanoplatelets present which were observed using cryo-TEM. Level 2 structures were aggregates possessing radii of gyration, R{sub g2} between 1800?Å and 12000?Å and fractal dimensions of either D{sub 2}=1 for case 3 or 1.8?D{sub 2}?2.1 for case 1 and case 2. D{sub 2}?=?1 is consistent with unaggregated 1-dimensional objects. 1.8???D{sub 2}???2.1 is consistent with these 1-dimensional objects (below) forming structures characteristic of diffusion or reaction limited cluster-cluster aggregation. Level 3 structures showed that the spatial distribution of the level 2 structures was uniform, on the average, for case 1, with fractal dimension D{sub 3}?3 while for case 2 and case 3 the fractal dimension was D{sub 3}?2.2, which suggested that the large-scale distribution had not come to equilibrium. The Guinier-Porod model showed that the structures giving rise to the aggregates with a fractal dimension given by D{sub 2} in the unified fit level 2 model were cylinders described by the parameter s?1 in the Guinier-Porod model. The size of the base of these cylinders was in agreement with the cryo-TEM observations as well as with the results of the level 1 unified fit model. By estimating the size of the nanoplatelets and understanding the structures formed via their aggregation, it will be possible to engineer novel lipids systems that embody desired functional characteristics.

Peyronel, Fernanda; Marangoni, Alejandro G. [Food Science Department, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Ilavsky, Jan [Advanced Photon Source, Argonne National Laboratory, 9700S Cass Ave., Bldg. 434D, Argonne, Illinois 60439 (United States); Mazzanti, Gianfranco [Department of Process Engineering and Applied Science, Dalhousie University, Halifax, Nova Scotia B3H 4R2 (Canada); Pink, David A. [Food Science Department, University of Guelph, Guelph, Ontario N1G 2W1 (Canada); Physics Department, St. Francis Xavier University, Antigonish, Nova Scotia B2G 2W5 (Canada)

2013-12-21T23:59:59.000Z

70

Maximum Entropy Method and Charge Flipping, a Powerful Combination to Visualize the True Nature of Structural Disorder from in situ X-ray Powder Diffraction Data  

SciTech Connect

In a systematic approach, the ability of the Maximum Entropy Method (MEM) to reconstruct the most probable electron density of highly disordered crystal structures from X-ray powder diffraction data was evaluated. As a case study, the ambient temperature crystal structures of disordered {alpha}-Rb{sub 2}[C{sub 2}O{sub 4}] and {alpha}-Rb{sub 2}[CO{sub 3}] and ordered {delta}-K{sub 2}[C{sub 2}O{sub 4}] were investigated in detail with the aim of revealing the 'true' nature of the apparent disorder. Different combinations of F (based on phased structure factors) and G constraints (based on structure-factor amplitudes) from different sources were applied in MEM calculations. In particular, a new combination of the MEM with the recently developed charge-flipping algorithm with histogram matching for powder diffraction data (pCF) was successfully introduced to avoid the inevitable bias of the phases of the structure-factor amplitudes by the Rietveld model. Completely ab initio electron-density distributions have been obtained with the MEM applied to a combination of structure-factor amplitudes from Le Bail fits with phases derived from pCF. All features of the crystal structures, in particular the disorder of the oxalate and carbonate anions, and the displacements of the cations, are clearly obtained. This approach bears the potential of a fast method of electron-density determination, even for highly disordered materials. All the MEM maps obtained in this work were compared with the MEM map derived from the best Rietveld refined model. In general, the phased observed structure factors obtained from Rietveld refinement (applying F and G constraints) were found to give the closest description of the experimental data and thus lead to the most accurate image of the actual disorder.

Samy, A.; Dinnebier, R; van Smaalen, S; Jansen, M

2010-01-01T23:59:59.000Z

71

In situ synchrotron x-ray studies of dense thin-film strontium-doped lanthanum manganite solid oxide fuel cell cathodes.  

SciTech Connect

Using a model cathode-electrolyte system composed of epitaxial thin-films of La{sub 1-x}Sr{sub x}MnO{sub 3-{delta}} (LSM) on single crystal yttria-stabilized zirconia (YSZ), we investigated changes in the cation concentration profile in the LSM during heating and under applied potential using grazing incidence x-rays. Pulsed laser deposition (PLD) was used to grow epitaxial LSM(011) on YSZ(111). At room temperature, we find that Sr segregates to form Sr enriched nanoparticles and upon heating the sample to 700 C, Sr is slowly reincorporated into the film. We also find different amounts of Sr segregation as the X-ray beam is moved across the sample. The variation in the amount of Sr segregation is greater on the sample that has been subject to 72 hours of applied potential, suggesting that the electrochemistry plays a role in the Sr segregation.

Chang, K. C.; Ingram, B.; Kavaipatti, B.; Yildiz, B.; Hennessy, D.; Salvador, P.; Leyarovski, N.; You, H.; Carnegie Mellon Univ.; Massachusetts Inst. of Tech.

2009-01-01T23:59:59.000Z

72

X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats environmental technology  

SciTech Connect

X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO{sub 2+x}-type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO{sub 2+x}, and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO{sub 2+x} would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

Lezama-pacheco, Juan S [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

73

Local structure of amorphous \\{MO50Ni50\\} determined by anomalous x-ray scattering using synchroton radiation  

Science Journals Connector (OSTI)

Anomalous (resonance) x-ray scattering technique using synchrotron radiation was applied to determine the compositionally resolved local structure of sputter deposited amorphous Mo50Ni50. The local environments of Mo atoms and Ni atoms were found to be significantly different from each other, but similar to the corresponding local environments in crystalline MoNi. The results compare favorably with those of the EXAFS measurement.

S. Aur; D. Kofalt; Y. Waseda; T. Egami; R. Wang; H.S. Chen; Boon-Keng Teo

1983-01-01T23:59:59.000Z

74

Structure determination of thin CoFe films by anomalous x-ray diffraction  

SciTech Connect

This work reports on the investigation of structure-property relationships in thin CoFe films grown on MgO. Because of the very similar scattering factors of Fe and Co, it is not possible to distinguish the random A2 (W-type) structure from the ordered B2 (CsCl-type) structure with commonly used x-ray sources. Synchrotron radiation based anomalous x-ray diffraction overcomes this problem. It is shown that as grown thin films and 300 K post annealed films exhibit the A2 structure with a random distribution of Co and Fe. In contrast, films annealed at 400 K adopt the ordered B2 structure.

Gloskovskii, Andrei; Stryganyuk, Gregory; Ouardi, Siham [Institut fuer Anorganische und Analytische Chemie, Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Fecher, Gerhard H.; Felser, Claudia [Institut fuer Anorganische und Analytische Chemie, Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Max Planck Institute for Chemical Physics of Solids, D-01187 Dresden (Germany); Hamrle, Jaroslav; Pistora, Jaromir [Department of Physics and Nanotechnology Centre, VSB-Technical University of Ostrava, 70833 Ostrava (Czech Republic); Bosu, Subrojati; Saito, Kesami; Sakuraba, Yuya; Takanashi, Koki [Institute for Materials Research (IMR), Tohoku University, Sendai 980-8577 (Japan)

2012-10-01T23:59:59.000Z

75

Observation and simulation of hard x ray photoelectron diffraction to determine polarity of polycrystalline zinc oxide films with rotation domains  

SciTech Connect

X ray photoelectron diffraction (XPD) patterns of polar zinc oxide (ZnO) surfaces were investigated experimentally using hard x rays and monochromatized Cr K{alpha} radiation and theoretically using a cluster model approach and a dynamical Bloch wave approach. We focused on photoelectrons emitted from the Zn 2p{sub 3/2} and O 1s orbitals in the analysis. The obtained XPD patterns for the (0001) and (0001) surfaces of a ZnO single crystal were distinct for a given emitter and polarity. Polarity determination of c-axis-textured polycrystalline ZnO thin films was also achieved with the concept of XPD, even though the in-plane orientation of the columnar ZnO grains was random.

Williams, Jesse R.; Adachi, Yutaka; Ohashi, Naoki [International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); NIMS Saint-Gobain Research Center of Excellence for Advanced Materials, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Pis, Igor [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holesovickach 2, Prague 8 18000 (Czech Republic); Kobata, Masaaki [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Winkelmann, Aimo [Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Saale) (Germany); Matsushita, Tomohiro [Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Kobayashi, Keisuke [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Hiroshima Synchrotron Radiation Center, Hiroshima University, 2-313 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-0046 (Japan)

2012-02-01T23:59:59.000Z

76

Compressive deformation and yielding mechanisms in cellular Al alloys determined using X-ray tomography and surface strain mapping  

SciTech Connect

The mechanisms of compressive deformation that occur in closed cell Al alloys have been established. This has been achieved by using x-ray computed tomography (CT) and surface strain mapping to determine the deformation modes and the cell morphologies that control the onset of yielding. The deformation is found to localize in narrow bands having width of order of a cell diameter. Outside the bands, the material remains elastic. The cells within the bands that experience large permanent strains are primarily elliptical. A group of cells work collectively to allow large localized deformation. Size does not appear to be the initiator of the deformation bands. Equiaxed cells remain elastic. The implications for manufacturing materials with superior mechanical properties are discussed. Visualization of internal deformation of a closed cell Al alloy core, as part of a sandwich panel construction, is also possible using x-ray tomography. Preliminary results for a punch indentation test are presented.

Bart-Smith, H.; Bastawros, A.F.; Mumm, D.R.; Evans, A.G. [Harvard Univ., Cambridge, MA (United States). Div. of Engineering and Applied Sciences; Sypeck, D.J.; Wadley, H.N.G. [Univ. of Virginia, Charlottesville, VA (United States). School of Engineering and Applied Science

1998-12-31T23:59:59.000Z

77

Fulvic Acid Sorption on Muscovite Mica as a Function of pH and Time Using In Situ X-ray Reflectivity  

E-Print Network (OSTI)

Fulvic Acid Sorption on Muscovite Mica as a Function of pH and Time Using In Situ X molecules during sorption. The apparent thickness of the FA layer decreased from 12.3 to 7.2 to 6.4 Ã? as p to the slow sorption rate of FA molecules, or a fractionation effect, i.e., continuous subsitution of smaller

Illinois at Chicago, University of

78

Regeneration of high-silica zeolites after sulfamethoxazole antibiotic adsorption: a combined in situ high-temperature synchrotron X-ray powder diffraction and thermal degradation study  

Science Journals Connector (OSTI)

...end and heated in situ using a hot air stream. The TGA-MSEGA analyses...were previously treated thermally in air, were able to re-adsorb SMX in...to montmorillonite clay. Water, Air, Soil Pollution , 209 , 439-450. Baerlocher...

L. Leardini; A. Martucci; I. Braschi; S. Blasioli; S. Quartieri

79

In situ diagnostic of liquid water distribution in cathode catalyst layer in an operating PEMFC by high-resolution soft X-ray radiography  

Science Journals Connector (OSTI)

To investigate the water transport behavior in the cathode catalyst layer (CCL) of an operating proton exchange membrane fuel cell (PEMFC), we examined transversal liquid water distributions in the CCL by using high-resolution soft X-ray radiography. The liquid water concentration gradient across the CCL was observed at a spatial resolution of 1.5 ?m. More liquid water accumulated in the CCL at the gas diffusion layer side than at the polymer electrolyte membrane side. The effect of accumulated liquid water in the CCL on the charge-transfer resistance was confirmed by electrochemical impedance spectroscopy. Liquid water accumulation in the CCL corresponds to deterioration of charge-transfer in the electrode.

Phengxay Deevanhxay; Takashi Sasabe; Shohji Tsushima; Shuichiro Hirai

2012-01-01T23:59:59.000Z

80

The Reactivity and Structural Dynamics of Supported Metal Nanoclusters Using Electron Microscopy, in situ X-Ray Spectroscopy, Electronic Structure Theories, and Molecular Dynamics Simulations.  

SciTech Connect

The distinguishing feature of our collaborative program of study is the focus it brings to emergent phenomena originating from the unique structural/electronic environments found in nanoscale materials. We exploit and develop frontier methods of atomic-scale materials characterization based on electron microscopy (Yang) and synchrotron X-ray absorption spectroscopy (Frenkel) that are in turn coupled innately with advanced first principles theory and methods of computational modeling (Johnson). In the past year we have made significant experimental advances that have led to important new understandings of the structural dynamics of what are unquestionably the most important classes of heterogeneous catalysts—the materials used to both produce and mitigate the consequences of the use of liquid hydrocarbon fuels.

Judith C. Yang; Ralph G. Nuzzo, Duane Johnson, Anatoly Frenkel

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Energetic electron precipitation in the aurora as determined by x-ray imaging  

SciTech Connect

This work examines two aspects of energetic-particle dynamics in the Earth's magnetosphere through the use of an x-ray imager flown from a stratospheric balloon in the auroral zone. The design and theory of this instrument is completely described, including the technique of image formation using an on-board microprocessor and a statistical analysis of the imaging process. Day-side energetic-electron precipitation is examined in the context of global energy dissipation during the substorm process. It is found that the relationship between events on the night side and the day side are considerably more complex that can be modeled with just a simple picture of drifting particles that induced instabilities, wave growth, and pitch-angle diffusion into the loss cone. The driving force for precipitation is probably not the presence of the energetic electrons (>30 keV) alone, but is influenced either by local effects or the less energetic component. The presence of small-scale structure, including gradients and complex motions in the precipitation region in the morning sector, suggests a local process influencing the rate of electron precipitation. The spatial and temporal evolution of a classic 5-15 second pulsating aurora during the post-breakup phase is also examined with the x-ray imager.

Werden, S.C.

1988-01-01T23:59:59.000Z

82

Application of electron microscopy and x-ray structural analysis for the determination of sizes of structural elements in nanocrystalline materials (Review)  

Science Journals Connector (OSTI)

The possibilities of determining the sizes of structural elements in various nanocrystalline materials by electron microscopy and X-ray structural analysis are analyzed. It is shown that these sizes depend on ...

Yu. D. Yagodkin; S. V. Dobatkin

2008-12-01T23:59:59.000Z

83

Determination of the voltage applied to x-ray tubes from the bremsstrahlung spectrum obtained with a silicon PIN photodiode  

Science Journals Connector (OSTI)

This work describes a methodology for the obtainment of the electron accelerating potential (kVp) applied to an x-ray tube through the determination of the end point of the energy spectrum of the radiation emitted by the tube. The measurements have been performed utilizing alternatively two silicon PIN photodiodes directly irradiated by the x-ray beam. Both were operated at room temperature with low bias so avoiding the drawbacks presented by photomultiplier tubes and germanium detectors. The energy calibration of the system was performed with X- and ? -emitter radioactive sources which makes the method absolute. Each kVp value was determined by means of a linear regression in the end of the spectrum to give simultaneously a good fit of the straight line to the experimental data and a low standard deviation for the kVp value. Results of the measurements carried out with an x-ray tube connected to a three-phase generator using additional filtration between 1.5 and 4.0 mm of Cu are presented. This filtration was used in order to minimize the contribution of low energy photons and to reduce pulse pile-up. Errors determined for the values of kVp are between 0.06 and 0.16 kV in the potential range from 50 to 100 kV. As an example the methodology has been applied in the verification of the secondary calibration of a voltage divider utilized by its turn in the tertiary calibration of noninvasive kVp meters. All intrinsic sources of errors involved in the process are discussed and evaluated.

Marcia C. Silva; Silvio B. Herdade; Patr??cia Lammoglia; Paulo R. Costa; Ricardo A. Terini

2000-01-01T23:59:59.000Z

84

A highly modular beamline electrostatic levitation facility, optimized for in situ high-energy x-ray scattering studies of equilibrium and supercooled liquids  

SciTech Connect

High-energy x-ray diffraction studies of metallic liquids provide valuable information about structural evolution on the atomic length scale, leading to insights into the origin of the nucleation barrier and the processes of supercooling and glass formation. The containerless processing of the beamline electrostatic levitation (BESL) facility allows coordinated thermophysical and structural studies of equilibrium and supercooled liquids to be made in a contamination-free, high-vacuum ({approx}10{sup -8} Torr) environment. To date, the incorporation of electrostatic levitation facilities into synchrotron beamlines has been difficult due to the large footprint of the apparatus and the difficulties associated with its transportation and implementation. Here, we describe a modular levitation facility that is optimized for diffraction studies of high-temperature liquids at high-energy synchrotron beamlines. The modular approach used in the apparatus design allows it to be easily transported and quickly setup. Unlike most previous electrostatic levitation facilities, BESL can be operated by a single user instead of a user team.

Mauro, N.A.; Kelton, K.F. (WU)

2011-10-27T23:59:59.000Z

85

PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL  

SciTech Connect

State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratory’s Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

Phelan, B.T.; Myers, D.J.; Smith, M.C.

2009-01-01T23:59:59.000Z

86

In situ examination of oxygen non-stoichiometry in La{sub 0.80}Sr{sub 0.20}CoO{sub 3??} thin films at intermediate and low temperatures by x-ray diffraction  

SciTech Connect

Structural evolution of epitaxial La{sub 0.80}Sr{sub 0.20}CoO{sub 3??} thin films under chemical and voltage stimuli was examined in situ using X-ray diffraction. The changes in lattice parameter (chemical expansivity) were used to quantify oxygen reduction reaction processes and vacancy concentration changes in lanthanum strontium cobaltite. At 550?°C, the observed lattice parameter reduction at an applied bias of ?0.6?V was equivalent to that from the reducing condition of a 2% carbon monoxide atmosphere with an oxygen non-stoichiometry ? of 0.24. At lower temperatures (200?°C), the application of bias reduced the sample much more effectively than a carbon monoxide atmosphere and induced an oxygen non-stoichiometry ? of 0.47. Despite these large changes in oxygen concentration, the epitaxial thin film was completely re-oxidized and no signs of crystallinity loss or film amorphization were observed. This work demonstrates that the effects of oxygen evolution and reduction can be examined with applied bias at low temperatures, extending the ability to probe these processes with in-situ analytical techniques.

Biegalski, M. D.; Belianinov, A.; Kalinin, S. V. [Oak Ridge National Laboratory, Center for Nanophase Materials Science, Oak Ridge, Tennessee 37831 (United States); Crumlin, E.; Mutoro, E.; Shao-Horn, Y. [Electrochemical Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States)

2014-04-21T23:59:59.000Z

87

Application of polarized neutron reflectometry and x-ray resonant magnetic reflectometry for determining the inhomogeneous magnetic structure in Fe/Gd multilayers.  

SciTech Connect

The evolution of the magnetic structure of multilayer [Fe (35 {angstrom})/Gd (50 {angstrom}){sub 5}] with variation in temperature and an applied magnetic field was determined using a complementary approach combining polarized neutron and X-ray resonant magnetic reflectometry. Self-consistent simultaneous analysis of X-ray and neutron spectra allowed us to determine the elemental and depth profiles in the multilayer structure with unprecedented accuracy, including the identification of an inhomogeneous intralayer magnetic structure with near-atomic resolution.

Kravtsov, E. A.; Haskel, D.; te Velthuis, S. G. E.; Jiang, J. S.; Kirby, B. J. (Materials Science Division); ( XSD); (Russian Academy of Sciences and Ural Federal Univ.); (Ural State Technical Univ.); (NIST Center for Neutron Research)

2010-01-01T23:59:59.000Z

88

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES)  

Science Journals Connector (OSTI)

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES) ... Argonne National Laboratory, Argonne, Illinois 60439 ... Argonne premium coal samples are used by researchers worldwide as standards in coal research. ...

Trudy B. Bolin

2010-10-01T23:59:59.000Z

89

X-ray lithography using holographic images  

DOE Patents (OSTI)

A non-contact X-ray projection lithography method for producing a desired X-ray image on a selected surface of an X-ray-sensitive material, such as photoresist material on a wafer, the desired X-ray image having image minimum linewidths as small as 0.063 .mu.m, or even smaller. A hologram and its position are determined that will produce the desired image on the selected surface when the hologram is irradiated with X-rays from a suitably monochromatic X-ray source of a selected wavelength .lambda.. On-axis X-ray transmission through, or off-axis X-ray reflection from, a hologram may be used here, with very different requirements for monochromaticity, flux and brightness of the X-ray source. For reasonable penetration of photoresist materials by X-rays produced by the X-ray source, the wavelength X, is preferably chosen to be no more than 13.5 nm in one embodiment and more preferably is chosen in the range 1-5 nm in the other embodiment. A lower limit on linewidth is set by the linewidth of available microstructure writing devices, such as an electron beam.

Howells, Malcolm R. (Berkeley, CA); Jacobsen, Chris (Sound Beach, NY)

1995-01-01T23:59:59.000Z

90

Molecular structures of fluid phase phosphatidylglycerol bilayers as determined by small angle neutron and X-ray scattering  

E-Print Network (OSTI)

neutron and X-ray scattering Jianjun Pan a, , Frederick A. Heberle a , Stephanie Tristram-Nagle b Matter Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 378316100 Institute for Neutron Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 378316453, USA e Canadian

Nagle, John F.

91

Copyright The Discussion Group of X-Ray Analysis,  

E-Print Network (OSTI)

-2900. 3 In Situ Spatial and Time-Resolved Studies of Electrochemical Reactions by Scanning Transmission X the Signal-to-Noise Ratio of X-ray Diffraction Profiles by Smoothed Principal Component Analysis Zeng Ping

Jun, Kawai

92

Combined energy dispersive EXAFS and x?ray diffraction  

Science Journals Connector (OSTI)

An in situ experiment to measure both x?ray absorption spectroscopy and x?ray diffraction of aurichalcite is described. The experiment uses position sensitive detectors to enable both data sets to be collected while the sample is slowly decomposed in air and then reduced in hydrogen. ?

A. J. Dent; M. P. Wells; R. C. Farrow; C. A. Ramsdale; G. E. Derbyshire; G. N. Greaves; J. W. Couves; J. M. Thomas

1992-01-01T23:59:59.000Z

93

Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering  

Science Journals Connector (OSTI)

High-energy X-ray scattering data from turbostratic phyllomanganate nanosheets are analyzed in real-space by pair distribution function analysis and in reciprocal space by the Bragg-rod method and the Debye equation. The elastic deformation of the two-dimensional nanocrystals is modeled with (1) a new empirical strain function in Bragg-rod calculations and (2) explicit spherical and cylindrical mandrels implemented in the Debye equation.

Manceau, A.

2013-01-17T23:59:59.000Z

94

Determination of Fe charge-state distributions in the Princeton large torus by Bragg crystal x-ray spectroscopy  

Science Journals Connector (OSTI)

A curved-crystal Bragg x-ray spectrometer has been used to measure K? or 1s-2p radiation from highly stripped Fexviii-Fexxv impurity ions in the Princeton large torus tokamak. The spectrometer has sufficient energy resolution (?4 eV at 6400 eV) to distinguish between the different ionization states of iron by measuring the energy shift of the K? x rays. The measured wavelengths agree well with theory and with spectra from solar flares and from laser-produced plasmas. The distribution of Fe charge states in the center of the discharge has been inferred from a comparison of the measured x-ray spectrum with theory. The shape of the spectrum depends strongly on electron temperature (Te) in the range Te=800-1500 eV. Within the factor of 2 uncertainty in L-shell ionization cross sections, measured intensities agree with theory, which is based on coronal equilibrium, indicating that the ion lifetime in the center of the plasma is approximately equal to or greater than the equilibration time.

K. W. Hill; S. von Goeler; M. Bitter; L. Campbell; R. D. Cowan; B. Fraenkel; A. Greenberger; R. Horton; J. Hovey; W. Roney; N. R. Sauthoff; W. Stodiek

1979-04-01T23:59:59.000Z

95

High Pressure X-ray Diffraction Study of Potassium Azide  

SciTech Connect

Crystal structure and compressibility of potassium azide was investigated by in-situ synchrotron powder X-ray diffraction in a diamond anvil cell at room temperature up to 37.7 GPa. In the body-centered tetragonal (bct) phase, an anisotropic compressibility was observed with greater compressibility in the direction perpendicular to the plane containing N{sub 3}{sup -} ions than directions within that plane. The bulk modulus of the bct phase was determined to be 18.6(7) GPa. A pressure-induced phase transition may occur at 15.5 GPa.

C Ji; F Zhang; D Hong; H Zhu; J Wu; M Chyu; V Levitas; Y Ma

2011-12-31T23:59:59.000Z

96

X-ray determination of threading dislocation densities in GaN/Al{sub 2}O{sub 3}(0001) films grown by metalorganic vapor phase epitaxy  

SciTech Connect

Densities of a- and a+c-type threading dislocations for a series of GaN films grown in different modes by metalorganic vapor phase epitaxy are determined from the x-ray diffraction profiles in skew geometry. The reciprocal space maps are also studied. Theory of x-ray scattering from crystals with dislocations is extended in order to take into account contribution from both threading and misfit dislocations. The broadening of the reciprocal space maps along the surface normal and the rotation of the intensity distribution ellipse is attributed to misfit dislocations at the interface. We find that the presence of a sharp AlN/GaN interface leads to an ordering of misfit dislocations and reduces strain inhomogeneity in GaN films.

Kopp, Viktor S., E-mail: victor.kopp@pdi-berlin.de; Kaganer, Vladimir M. [Paul-Drude-Institut für Festkörperelektronik, Hausvogteiplatz 5–7, 10117 Berlin (Germany); Baidakova, Marina V.; Lundin, Wsevolod V.; Nikolaev, Andrey E.; Verkhovtceva, Elena V.; Yagovkina, Maria A. [Ioffe Physical-Technical Institute of the Russian Academy of Sciences, Politekhnicheskaya 26, 194021 St.-Petersburg (Russian Federation); Cherkashin, Nikolay [CEMES-CNRS and Université de Toulouse, 29 rue J. Marvig, 31055 Toulouse (France)

2014-02-21T23:59:59.000Z

97

Chest x-Rays  

Energy.gov (U.S. Department of Energy (DOE))

The B-reading is a special reading of a standard chest x-ray film performed by a physician certified by the National Institute for Occupational Safety and Health (NIOSH). The reading looks for changes on the chest x-ray that may indicate exposure and disease caused by agents such as asbestos or silica.

98

X-ray beamsplitter  

DOE Patents (OSTI)

An x-ray beamsplitter which splits an x-ray beam into two coherent parts by reflecting and transmitting some fraction of an incident beam has applications for x-ray interferometry, x-ray holography, x-ray beam manipulation, and x-ray laser cavity output couplers. The beamsplitter is formed of a wavelength selective multilayer thin film supported by a very thin x-ray transparent membrane. The beamsplitter resonantly transmits and reflects x-rays through thin film interference effects. A thin film is formed of 5--50 pairs of alternate Mo/Si layers with a period of 20--250 A. The support membrane is 10--200 nm of silicon nitride or boron nitride. The multilayer/support membrane structure is formed across a window in a substrate by first forming the structure on a solid substrate and then forming a window in the substrate to leave a free-standing structure over the window. 6 figs.

Ceglio, N.M.; Stearns, D.G.; Hawryluk, A.M.; Barbee, T.W. Jr.

1987-08-07T23:59:59.000Z

99

X-ray beamsplitter  

DOE Patents (OSTI)

An x-ray beamsplitter which splits an x-ray beam into two coherent parts by reflecting and transmitting some fraction of an incident beam has applications for x-ray interferometry, x-ray holography, x-ray beam manipulation, and x-ray laser cavity output couplers. The beamsplitter is formed of a wavelength selective multilayer thin film supported by a very thin x-ray transparent membrane. The beamsplitter resonantly transmits and reflects x-rays through thin film interference effects. A thin film is formed of 5-50 pairs of alternate Mo/Si layers with a period of 20-250 A. The support membrane is 10-200 nm of silicon nitride or boron nitride. The multilayer/support membrane structure is formed across a window in a substrate by first forming the structure on a solid substrate and then forming a window in the substrate to leave a free-standing structure over the window.

Ceglio, Natale M. (Livermore, CA); Stearns, Daniel S. (Mountain View, CA); Hawryluk, Andrew M. (Modesto, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

1989-01-01T23:59:59.000Z

100

X-ray binaries  

E-Print Network (OSTI)

We review the nuclear astrophysics aspects of accreting neutron stars in X-ray binaries. We summarize open astrophysical questions in light of recent observations and their relation to the underlying nuclear physics. Recent progress in the understanding of the nuclear physics, especially of X-ray bursts, is also discussed.

H. Schatz; K. E. Rehm

2006-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Determination of stress state in deep subsea formation by combination of hydraulic fracturing in situ test and core  

E-Print Network (OSTI)

Determination of stress state in deep subsea formation by combination of hydraulic fracturing January 2013. [1] In situ test of hydraulic fracturing (HF) provides the only way to observe in situ of stress state in deep subsea formation by combination of hydraulic fracturing in situ test and core

102

X-Ray Identification of Element 104  

Science Journals Connector (OSTI)

The daughter x-ray identification technique has been applied to the identification of element 104. The characteristic K-series x rays from the ?-decay daughter isotope, nobelium (Z=102), have been observed in coincidence with ? particles from the decay of 4.5-sec 104257, thus providing an unequivocal determination of the parent atomic number, Z=104.

C. E. Bemis; Jr.; R. J. Silva; D. C. Hensley; O. L. Keller; Jr.; J. R. Tarrant; L. D. Hunt; P. F. Dittner; R. L. Hahn; C. D. Goodman

1973-09-03T23:59:59.000Z

103

X-ray laser  

DOE Patents (OSTI)

An X-ray laser (10) that lases between the K edges of carbon and oxygen, i.e. between 44 and 23 Angstroms, is provided. The laser comprises a silicon (12) and dysprosium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like dysprosium ions (34) are resonantly photo-pumped to their upper X-ray laser state by line emission from hydrogen-like silicon ions (32). The novel X-ray laser should prove especially useful for the microscopy of biological specimens.

Nilsen, Joseph (Livermore, CA)

1991-01-01T23:59:59.000Z

104

X-ray absorption spectroscopy  

E-Print Network (OSTI)

009-9473-8 REVIEW X-ray absorption spectroscopy Junko Yano Æand application of X-ray absorption spectroscopy, bothX-ray absorption near-edge structure (XANES) and extended X-

Yano, Junko; Yachandra, Vittal K.

2009-01-01T23:59:59.000Z

105

X-ray Absorption Spectroscopy  

E-Print Network (OSTI)

type: Review X-ray Absorption Spectroscopy Junko Yano andPhotosystem II; XAS, X-ray absorption spectroscopy; EXAFS,X-ray absorption fine structure; EPR, electron paramagnetic

Yano, Junko

2010-01-01T23:59:59.000Z

106

X-ray-diffraction determination of the Ni-dopant site in single-crystal YBa2Cu3O7-?  

Science Journals Connector (OSTI)

Anomalous dispersive x-ray-diffraction measurements have determined the dopant-site distribution in Ni-doped single crystals of the high-temperature superconductor YBa2Cu3O7-?. The data from a YBa2(Cu0.83Ni0.17)3O7-? crystal show that over 95% of the Ni dopants occupy the Cu(2) site in the copper oxide planes, with negligible occupation of the Cu(1) copper oxide chain sites. General guidelines are presented for selecting the most effective hkl diffraction planes for measuring dopant concentration profiles. Direct measurement of the energy dependence of the dopant atomic scattering forces is also demonstrated.

S. A. Hoffman; M. A. Castro; G. C. Follis; S. M. Durbin

1994-05-01T23:59:59.000Z

107

Phosphorus determination in borophosphosilicate or phosphosilicate glass films on a Si wafer by wavelength dispersive x-ray spectroscopy  

SciTech Connect

In this report, peak shift effects in the SiO{sub 2}/Si(100) system due to chemical bonding are demonstrated. The detailed development of the equations appears in a paper submitted for publication in the Journal of X-ray Spectroscopy. These equations are for the spectral line intensity of Si and P from BPSG films and from the Si in the Si(100) substrate. They are subsequently integrated into two simultaneous equations that can be solved for the phosphorus content and the surface density by a computer program using iterative methods. The general expressions for the BPSG films and the computer program are also applicable to PSG films by setting the boron content to zero. The new procedure was then tested by analysis of a well-defined and carefully prepared set of PSG wafer samples. Preliminary analyses were also made on BPSG wafers. 3 refs., 4 figs., 3 tabs.

Levine, H.S.; Higgins, K.L.

1990-01-01T23:59:59.000Z

108

X-Ray Generators  

Science Journals Connector (OSTI)

There are many types of X-ray generators sold commercially. The following are some of ... that should be considered when selecting a particular generator for a particular purpose. All the companies listed below s...

Reuben Rudman

1972-01-01T23:59:59.000Z

109

The determination of the in situ structure by nuclear spin contrast variation  

SciTech Connect

Polarized neutron scattering from polarized nuclear spins in hydrogenous substances opens a new way of contrast variation. The enhanced contrast due to proton spin polarization was used for the in situ structure determination of tRNA of the functional complex of the E.coli ribosome.

Stuhrmann, H.B. [GKSS Forschungszentrum, Geesthacht (Germany); Nierhaus, K.H. [Max-Planch-Institut fuer Molekulare Genetik, Berlin (Germany)

1994-12-31T23:59:59.000Z

110

DETERMINATION OF THE INTRINSIC LUMINOSITY TIME CORRELATION IN THE X-RAY AFTERGLOWS OF GAMMA-RAY BURSTS  

SciTech Connect

Gamma-ray bursts (GRBs), which have been observed up to redshifts z Almost-Equal-To 9.5, can be good probes of the early universe and have the potential to test cosmological models. Dainotti's analysis of GRB Swift afterglow light curves with known redshifts and a definite X-ray plateau shows an anti-correlation between the rest-frame time when the plateau ends (the plateau end time) and the calculated luminosity at that time (or approximately an anti-correlation between plateau duration and luminosity). Here, we present an update of this correlation with a larger data sample of 101 GRBs with good light curves. Since some of this correlation could result from the redshift dependences of these intrinsic parameters, namely, their cosmological evolution, we use the Efron-Petrosian method to reveal the intrinsic nature of this correlation. We find that a substantial part of the correlation is intrinsic and describe how we recover it and how this can be used to constrain physical models of the plateau emission, the origin of which is still unknown. The present result could help to clarify the debated nature of the plateau emission.

Dainotti, Maria Giovanna; Petrosian, Vahe'; Singal, Jack; Ostrowski, Michal, E-mail: mdainott@stanford.edu, E-mail: vahep@stanford.edu, E-mail: jacks@slac.stanford.edu, E-mail: dainotti@oa.uj.edu.pl, E-mail: mio@oa.uj.edu.pl [Department of Physics and Astronomy, Stanford University, Via Pueblo Mall 382, Stanford, CA 94305-4060 (United States)

2013-09-10T23:59:59.000Z

111

Experimental determination of bulk modulus of 14 A tobermorite using high pressure synchrotron X-ray diffraction  

SciTech Connect

Using a diamond anvil cell, 14 A tobermorite, a structural analogue of calcium silicate hydrates (C-S-H), was examined by high-pressure synchrotron X-ray diffraction up to 4.8 GPa under hydrostatic conditions. The bulk modulus of 14 A tobermorite was calculated, K{sub o} = 47 GPa. Comparison of the current results with previous high pressure studies on C-S-H(I) indicates that: (1) the compression behavior of the lattice parameters a and b of 14 A tobermorite and C-S-H(I) are very similar, implying that both materials may have very similar Ca-O layers, and also implying that an introduction of structural defects into the Ca-O layers may not substantially change in-plane incompressibility of the ab plane of 14 A tobermorite; and (2) the bulk modulus values of 14 A tobermorite and C-S-H(I) are dominated by the incompressibility of the lattice parameter c, which is directly related to the interlayer spacing composed of dreierketten silicate chains, interlayer Ca, and water molecules.

Oh, Jae Eun [Department of Civil and Environmental Engineering, University of California, Berkeley, 94720, CA USA (United States); School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology, Ulsan Metropolitan City, 689-798 (Korea, Republic of); Clark, Simon M. [Department of Earth and Planetary Sciences, Maquarie University, Sydney, NSW 2109 (Australia); Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, 20015, CA (United States); Wenk, Hans-Rudolf [Department of Earth and Planetary Sciences, Maquarie University, Sydney, NSW 2109 (Australia); Monteiro, Paulo J.M., E-mail: monteiro@berkeley.edu [Department of Civil and Environmental Engineering, University of California, Berkeley, 94720, CA USA (United States)

2012-02-15T23:59:59.000Z

112

Origins of PM10 determined by the micro-proton induced X-ray emission spectra of single aerosol particles  

SciTech Connect

The micro-proton induced X-ray emission (micro-PIXE) spectrum of a single aerosol particle (SAP) was considered as its fingerprint for tracing its origin. A proton microprobe was used to extract fingerprints of SAPs. Environmental monitoring samples of PM10 were collected from a heavy industrial area of Shanghai and were analyzed by proton microprobe for finding their pollution sources. In order to find the sources of SAPs collected from environmental monitoring sites, a fingerprint database of SAPS collected from various pollution Sources was established. The origins of samples collected through environmental monitoring were identified by comparison of the micro-PIXE spectra of SAPs with those of SAPs in the fingerprint database using a pattern recognition technique. The results of this study show that most of the measured PM10 is derived from metallurgic industry, soil dust, coal combustion, automobile exhaust, and motorcycle exhaust. The study also shows that the proton microprobe is an ideal tool for the analysis of SAPs. The unidentified particles of PM10 are classified into seven classes by hierarchical cluster analysis based on the element peak intensity in the spectra.

Yue, W.S.; Li, X.L.; Wan, T.M.; Liu, J.F.; Zhang, G.L.; Li, Y. [Chinese Academy of Science, Shanghai (China). Shanghai Institute of Applied Physics

2006-06-15T23:59:59.000Z

113

In-situ determination of energy species yields of intense particle beams  

DOE Patents (OSTI)

An arrangement is provided for the in-situ determination of energy species yields of intense particle beams. The beam is directed onto a target surface of known composition, such that Rutherford backscattering of the beam occurs. The yield-energy characteristic response of the beam to backscattering from the target is analyzed using Rutherford backscattering techniques to determine the yields of energy species components of the beam.

Kugel, Henry W. (Somerset, NJ); Kaita, Robert (Englishtown, NJ)

1987-01-01T23:59:59.000Z

114

X-ray beam finder  

DOE Patents (OSTI)

An X-ray beam finder for locating a focal spot of an X-ray tube includes a mass of X-ray opaque material having first and second axially-aligned, parallel-opposed faces connected by a plurality of substantially identical parallel holes perpendicular to the faces and a film holder for holding X-ray sensitive film tightly against one face while the other face is placed in contact with the window of an X-ray head.

Gilbert, H.W.

1983-06-16T23:59:59.000Z

115

X-ray holography at Lawrence Livermore National Laboratory  

SciTech Connect

The x-ray holography program at the Lawrence Livermore National Laboratory has two principal goals: (1) the development of x-ray diffraction techniques for DNA sequence analysis and (2) the development of x-ray laser holography for structural analysis of intact biological cells and organelles. DNA sequence analysis will be accomplished by applying x-ray diffraction techniques to determine the ensemble average of the sequence of labels along the individual elements of crystalline DNA. X-ray laser holographic imaging will be accomplished by applying three dimensional x-ray holography to elucidate the structure of few hundred angstrom objects such as 300 {Angstrom} chromatin fibers, nuclear pores and nucleic acid replication complexes in living cells. Existing laboratory x-ray lasers will be utilized to produce flash x-ray holograms of the biological structures.

Trebes, J.; Annese, C.; Birdsall, D.; Brase, J.; Gray, J.; Lane, S.; London, R.; Matthews, D.; Peters, D.; Pinkel, D.; Stone, G.; Rapp, D.; Rosen, M.; Weier, U.; Yorkey, T.

1990-10-11T23:59:59.000Z

116

X-ray Spectrometry  

Science Journals Connector (OSTI)

These provide excellent energy resolution for a wide range of X-ray energies, from the optical range up to several kiloelectronvolts. ... The Astro-E2 launched in 2005 was the first mission that contained a low-temperature microcalorimeter-based observatory, and three more low-temperature detector-based observatories are being developed (NeXT, Constellation-X, ZEUS). ...

Imre Szalóki; János Osán; René E. Van Grieken

2006-05-10T23:59:59.000Z

117

A combined fit of total scattering and extended x-ray absorption fine structure data for local-structure determination in crystalline materials  

SciTech Connect

Reverse Monte Carlo (RMC) refinements of local structure using a simultaneous fit of X-ray/neutron total scattering and extended X-ray absorption fine structure (EXAFS) data were developed to incorporate an explicit treatment of both single- and multiple-scattering contributions to EXAFS. The refinement algorithm, implemented as an extension to the public domain computer software RMCProfile, enables accurate modeling of EXAFS over distances encompassing several coordination shells around the absorbing species. The approach was first tested on Ni, which exhibits extensive multiple scattering in EXAFS, and then applied to perovskite-like SrAl{sub 1/2}Nb{sub 1/2}O{sub 3}. This compound crystal1izes with a cubic double-perovskite structure but presents a challenge for local-structure determination using a total pair-distribution function (PDF) alone because of overlapping peaks of the constituent partial PDFs (e.g. Al-O and Nb-O or Sr-O and O-O). The results obtained here suggest that the combined use of the total scattering and EXAFS data provides sufficient constraints for RMC refinements to recover fine details of local structure in complex perovskites. Among other results, it was found that the probability density distribution for Sr in SrAl{sub 1/2}Nb{sub 1/2}O{sub 3} adopts T{sub d} point-group symmetry for the Sr sites, determined by the ordered arrangement of Al and Nb, as opposed to a spherical distribution commonly assumed in traditional Rietveld refinements.

Proffen, Thomas E [Los Alamos National Laboratory; Krayzman, Victor [NIST; Levin, Igor [NIST; Tucker, Matt [ISIS, UK

2009-01-01T23:59:59.000Z

118

In-Situ X-ray Spectroscopic Studies of the Fundamental Chemistry of Pb and Pb-Bi Corrosion Processes at High Temperatures: Development and Assessment of Composite Corrosion Resistant Materials.  

SciTech Connect

Over the course of this project, we have a number of accomplishments. The following list is presented as a summary statement for the project. Specific details from previous Quarterly Reports are given. (1) We established that it is possible to use EXAFS to study the interface layer between a material and the liquid Pb overlayer. We have discovered that molybdenum grows a selflimiting oxide layer which does not spall even at the highest temperatures studied. There have been 2 publications resulting from these studies. (2) We have fabricated a high temperature environmental chamber capable of extending the Pb overlayer studies by varying the incident x-ray beam angle to perform depth profiling of the Pb layer. This chamber will continue to be available to nuclear materials program researchers who wish to use the MRCAT beam line. (3) We have developed a collaboration with researchers at the Paul Scherrer Institute to study corrosion layers on zircalloy. One publication has resulted from this collaboration and another is in progress. (4) We have developed a collaboration with Prof. G.R. Odette of UCSB in which we studied the local structure of Ti and Y in nanoclusters found in oxygen dispersion strengthened steels. There are two publications in progress form this collaboration and we have extended the project to anomalous small angle x-ray scattering as well as EXAFS. (5) We have promoted the use of EXAFS for the study of nuclear materials to the community over the past 4 years and we have begun to see an increase in demand for EXAFS from the community at the MRCAT beam line. (6) This grant was instrumental in nucleating interest in establishing a new Collaborative Access Team at the Advanced Photon Source, the Nuclear and Radiological Research CAT (NRR-CAT). The co-PI (Jeff Terry) is the lead investigator on this project and it has been approved by the APS Scientific Advisory Committee for further planning. The status of the NRR-CAT project is being discussed in a series of workshops in 2009-2010 and has received exploratory funding from INL. This funding is being used to provide beam time and support at MRCAT for NRR-CAT related experiments. This will continue through 2010 as the development of a full NRR-CAT proposal develops. We believe that this has been a very successful project whose impact will continue to be felt for a number of years. Not only will there be additional publications coming from the work supported directly by this grant but the establishment of NRR-CAT will have a significant impact on the field of nuclear materials research for decades to come.

Carlo Segre

2009-12-30T23:59:59.000Z

119

Tunable X-ray source  

DOE Patents (OSTI)

A method for the production of X-ray bunches tunable in both time and energy level by generating multiple photon, X-ray, beams through the use of Thomson scattering. The method of the present invention simultaneously produces two X-ray pulses that are tunable in energy and/or time.

Boyce, James R. (Williamsburg, VA)

2011-02-08T23:59:59.000Z

120

Single-particle structure determination by correlations of snapshot X-ray diffraction patterns (CXIDB ID 20)  

DOE Data Explorer (OSTI)

This deposition includes the diffraction images generated by the paired polystyrene spheres in random orientations. These images were used to determine and phase the single particle diffraction volume from their autocorrelation functions.

Starodub, D.

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Photon Sciences | Beamlines | HXN: Hard X-ray Nanoprobe  

NLE Websites -- All DOE Office Websites (Extended Search)

HXN: Hard X-ray Nanoprobe HXN: Hard X-ray Nanoprobe Poster | Fact Sheet | Preliminary Design Report Scientific Scope The Hard X-ray Nanoprobe beamline and endstation instruments (HXN) will be designed and constructed to explore new frontiers of hard x-ray microscopy applications with the highest achievable spatial resolution. Currently the available spatial resolution for scientific applications, provided by scanning x-ray microscopes in the hard x-ray regime, is limited to ~50nm, which is still insufficient for probing the nanoscale interfacial structures critical in determining properties and functionalities of material and biological systems. The HXN beamline aims to enable x-ray experiments at spatial resolutions ranging from 10 to 30 nm with an ultimate goal of ~1 nm. Beamline Description

122

Introduction to Neutron and X-Ray Scattering  

NLE Websites -- All DOE Office Websites (Extended Search)

Scattering Studies of Thin Scattering Studies of Thin Polymer Films Introduction to Neutron and X-Ray Scattering Sunil K. Sinha UCSD/LANL Acknowledgements: Prof. R.Pynn( Indiana U.) Prof. M.Tolan (U. Dortmund) Wilhelm Conrad Röntgen 1845-1923 1895: Discovery of X-Rays 1901 W. C. Röntgen in Physics for the discovery of x-rays. 1914 M. von Laue in Physics for x-ray diffraction from crystals. 1915 W. H. Bragg and W. L. Bragg in Physics for crystal structure determination. 1917 C. G. Barkla in Physics for characteristic radiation of elements. 1924 K. M. G. Siegbahn in Physics for x-ray spectroscopy. 1927 A. H. Compton in Physics for scattering of x-rays by electrons. 1936 P. Debye in Chemistry for diffraction of x-rays and electrons in gases.

123

Validity of automated x-ray photoelectron spectroscopy algorithm to determine the amount of substance and the depth distribution of atoms  

Science Journals Connector (OSTI)

The author reports a systematic study of the range of validity of a previously developed algorithm for automated x-ray photoelectron spectroscopy analysis which takes into account the variation in both peak intensity and the intensity in the background of inelastically scattered electrons. This test was done by first simulating spectra for the Au4d peak with gold atoms distributed in the form of a wide range of nanostructures which includes overlayers with varying thickness a 5?Å layer of atoms buried at varying depths and a substrate covered with an overlayer of varying thickness. Next the algorithm was applied to analyze these spectra. The algorithm determines the number of atoms within the outermost 3 ? of the surface. This amount of substance is denoted AOS 3 ? (where ?   is the electron inelastic mean free path). In general the determined AOS 3 ? is found to be accurate to within ?10–20% depending on the depth distribution of the atoms. The algorithm also determines a characteristic length L which was found to give unambiguous information on the depth distribution of the atoms for practically all studied cases. A set of rules for this parameter which relates the value of L to the depths where the atoms are distributed was tested and these rules were found to be generally valid with only a few exceptions. The results were found to be rather independent of the spectral energy range (from 20 to 40?eV below the peak energy) used in the analysis.

Sven Tougaard

2013-01-01T23:59:59.000Z

124

Evaluation of a portable x-ray fluorescence survey meter for the quantitative determination of trace metals in welding fumes  

E-Print Network (OSTI)

of Radioisotope Sources Utilized II. Results of Sensitivity Determination III. Long-tenn Instrumental Variability IV. Short-term Instrumental Variability V. Instrumental Variability Due to Temperature Fluctuations Vl. Average 948ias for Each Element VII.... Average %Bias for Each Sample 46 47 48 49 52 INTRCUUCTI Gbl The analysis of the elemental composition of welding fumes is often done in indust, rial hygiene work, as the fumes generated are toxic in many cases. However, the standard analytical...

Fehrenbacher, Mary Catherine

1984-01-01T23:59:59.000Z

125

Determination of the structure of the violet pigment C22H12Cl2N6O4 from a non-indexed X-ray powder diagram  

Science Journals Connector (OSTI)

Global lattice energy minimizations were used to solve the crystal stucture of C22H12Cl2N6O4 from a low-quality X-ray powder diagram, which consisted of 12 visible peaks only.

Schmidt, M.U.

2005-01-19T23:59:59.000Z

126

Dependence of LTX plasma performance on surface conditions as determined by in situ analysis of plasma facing components  

Science Journals Connector (OSTI)

Abstract The Materials Analysis and Particle Probe (MAPP) diagnostic has been implemented on the Lithium Tokamak Experiment (LTX) at PPPL, providing the first in situ x-ray photoelectron spectroscopy (XPS) surface characterization of tokamak plasma facing components (PFCs). MAPP samples were exposed to argon glow discharge conditioning (GDC), lithium evaporations, and hydrogen tokamak discharges inside LTX. Samples were analyzed with XPS, and alterations to surface conditions were correlated against observed LTX plasma performance changes. Argon GDC caused the accumulation of nm-scale metal oxide layers on the PFC surface, which appeared to bury surface carbon and oxygen contamination and thus improve plasma performance. Lithium evaporation led to the rapid formation of a lithium oxide (Li2O) surface; plasma performance was strongly improved for sufficiently thick evaporative coatings. Results indicate that a 5 h argon GDC or a 50 nm evaporative lithium coating will both significantly improve LTX plasma performance.

M. Lucia; R. Kaita; R. Majeski; F. Bedoya; J.P. Allain; T. Abrams; R.E. Bell; D.P. Boyle; M.A. Jaworski; J.C. Schmitt

2014-01-01T23:59:59.000Z

127

X-ray Spectrometry  

Science Journals Connector (OSTI)

The segmented STJ operated at total count rates of above 105 counts/s, and the best-achieved energy resolution of their single STJ was found to be 10 eV for X-ray energies below 1 keV. ... The Mo?Au TES, with an operating temperature of 230 mK, was developed for the Constellation-X mission and the energy resolution of the spectrometer is ?28 eV at 3.3 keV. ...

Imre Szalóki; Szabina B. Török; Jasna Injuk; René E. Van Grieken

2002-05-18T23:59:59.000Z

128

Application of neutron activation analysis and high resolution x-ray spectrometry for the determination of trace quantities of elements with short-lived activation products  

E-Print Network (OSTI)

Conversion Interferences and Errors 3, PROCEDURES AND EXPERIMENTAL SETUP Sample Preparation Pneumatic Sample Transfer System Sample Irradiation X-ray Spectrometry Data Reduction 4. DISCUSSION AND RESULTS System Analysis Analysis Problems.... C. Roentgen made the classic observation that a highly penatrative radiation, unknown at that time, was produced when fast electrons impinged on matter. This radiation, which h called x-rays, was being studied in all parts of the world less than...

Marshall, John Richard

1974-01-01T23:59:59.000Z

129

Chapter 1 - The Impacts of X-Ray Absorption Spectroscopy on Understanding Soil Processes and Reaction Mechanisms  

SciTech Connect

During the last two decades, X-ray absorption spectroscopy (XAS) has developed into a mature technique for obtaining the speciation (e.g., oxidation state) and short-range structure of elements present in soils and sediments. XAS encompasses both X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy. XAS has a number of advantageous qualities for studying soils and sediments, which include elemental specificity, sensitivity to the local chemical and structural state of an element, and the ability to analyze materials in situ. This information allows accurate determination of oxidation state, type of nearest neighbors, coordination number, bond distance, and orbital symmetries of the X-ray absorbing element. In this review, we examine the application of a wide variety of synchrotron X-ray techniques to fundamental issues in environmental soil chemistry. Additionally, we examine the application of microfocused and time-resolved XAS to determine speciation (e.g., oxidation state and/or local coordination environment) and transformation kinetics of contaminants in heterogeneous environmental systems. During the last three decades, XAS has a played a critical role in furthering our understanding of a myriad of environmental systems and will continue to do so into the foreseeable future.

Ginder-Vogel, Matthew; Sparks, Donald L. (Delaware)

2011-11-17T23:59:59.000Z

130

Correlations to determine in-situ stress from open-hole logging data in sandstone reservoirs  

E-Print Network (OSTI)

Knowledge of in-situ stress distribution within reservoir sandstones and the surrounding formations is recognized as one of the most important factors in the design and analysis of hydraulic fractures. In-situ stress contrast between layers of rock...

Gongora, Cesar Augusto

2012-06-07T23:59:59.000Z

131

X-Ray Diffraction Microscopy of Magnetic Structures  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Diffraction Microscopy of Magnetic Structures Print X-Ray Diffraction Microscopy of Magnetic Structures Print science brief icon Scientists working at ALS Beamline 12.0.2.2 have demonstrated a new x-ray technique for producing short-exposure nanoscale images of the magnetic structure of materials. The new method combines aspects of coherent x-ray diffraction, which can determine 3-D charge distributions, and resonant magnetic scattering, which is sensitive to magnetic structures. Physicists have used coherent x-ray diffraction to measure the electron density of complicated molecules. The formula used to make these calculations contains terms that relate to the electron spin of magnetic atoms, but these terms are traditionally ignored since coherent x-ray diffraction has not been used to retrieve magnetic information. Using the full formula allows for the determination of not only the electron density, but also the magnetic spin distribution and its orientation.

132

X-Ray Diffraction Microscopy of Magnetic Structures  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Diffraction Microscopy of Magnetic Structures Print X-Ray Diffraction Microscopy of Magnetic Structures Print science brief icon Scientists working at ALS Beamline 12.0.2.2 have demonstrated a new x-ray technique for producing short-exposure nanoscale images of the magnetic structure of materials. The new method combines aspects of coherent x-ray diffraction, which can determine 3-D charge distributions, and resonant magnetic scattering, which is sensitive to magnetic structures. Physicists have used coherent x-ray diffraction to measure the electron density of complicated molecules. The formula used to make these calculations contains terms that relate to the electron spin of magnetic atoms, but these terms are traditionally ignored since coherent x-ray diffraction has not been used to retrieve magnetic information. Using the full formula allows for the determination of not only the electron density, but also the magnetic spin distribution and its orientation.

133

X-Ray Diffraction Microscopy of Magnetic Structures  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Diffraction Microscopy of Magnetic Structures Print X-Ray Diffraction Microscopy of Magnetic Structures Print science brief icon Scientists working at ALS Beamline 12.0.2.2 have demonstrated a new x-ray technique for producing short-exposure nanoscale images of the magnetic structure of materials. The new method combines aspects of coherent x-ray diffraction, which can determine 3-D charge distributions, and resonant magnetic scattering, which is sensitive to magnetic structures. Physicists have used coherent x-ray diffraction to measure the electron density of complicated molecules. The formula used to make these calculations contains terms that relate to the electron spin of magnetic atoms, but these terms are traditionally ignored since coherent x-ray diffraction has not been used to retrieve magnetic information. Using the full formula allows for the determination of not only the electron density, but also the magnetic spin distribution and its orientation.

134

TENDER ENERGY X-RAY ABSORPTION  

NLE Websites -- All DOE Office Websites (Extended Search)

TENDER ENERGY X-RAY ABSORPTION TENDER ENERGY X-RAY ABSORPTION SPECTROSCOPY (TES) Project Team: S. Bare 1,2 , J. Brandes 3 , T. Buonassisi 4 , J. Chen 5,2 , M. Croft 6 , E. DiMasi 7 , A. Frenkel 8,2 , D. Hesterberg 9 , S. Hulbert 7,2 , S. Khalid 7 , S. Myneni 10 , P. Northrup 7,11 , E.T. Rasbury 11 , B. Ravel 12 , R. Reeder 11 , J. Rodriguez 7,2 , D. Sparks 5,13 , V. Stojanoff 7 , G. Waychunas 14 1 UOP LLC, 2 Synchrotron Catalysis Consortium, 3 Skidaway Inst. of Oceanography, 4 MIT Laboratory for Photovoltaics Research, 5 Univ. of Delaware, 6 Rutgers Univ., 7 Brookhaven National Lab, 8 Yeshiva Univ., 9 North Carolina State Univ., 10 Princeton Univ., 11 Stony Brook Univ., 12 NIST, 13 Delaware Environmental Inst., 14 Lawrence Berkeley National Lab TECHNIQUES: High performance and in-situ X-ray absorption spectroscopy and spatially-resolved XAS of

135

X-ray Absorption Spectroscopy  

SciTech Connect

This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

Yano, Junko; Yachandra, Vittal K.

2009-07-09T23:59:59.000Z

136

X-ray fluorescence mapping  

NLE Websites -- All DOE Office Websites (Extended Search)

biololgical cells, over the measurement of impurities in solar cells, to the rare earth content of geological materials. A somewhat 'typical' layout for a X-ray fluorescence...

137

Nonlinear X-ray Compton Scattering  

E-Print Network (OSTI)

X-ray scattering is a weak linear probe of matter. It is primarily sensitive to the position of electrons and their momentum distribution. Elastic X-ray scattering forms the basis of atomic structural determination while inelastic Compton scattering is often used as a spectroscopic probe of both single-particle excitations and collective modes. X-ray free-electron lasers (XFELs) are unique tools for studying matter on its natural time and length scales due to their bright and coherent ultrashort pulses. However, in the focus of an XFEL the assumption of a weak linear probe breaks down, and nonlinear light-matter interactions can become ubiquitous. The field can be sufficiently high that even non-resonant multiphoton interactions at hard X-rays wavelengths become relevant. Here we report the observation of one of the most fundamental nonlinear X-ray-matter interactions, the simultaneous Compton scattering of two identical photons producing a single photon at nearly twice the photon energy. We measure scattered...

Fuchs, Matthias; Chen, Jian; Ghimire, Shambhu; Shwartz, Sharon; Kozina, Michael; Jiang, Mason; Henighan, Thomas; Bray, Crystal; Ndabashimiye, Georges; Bucksbaum, P H; Feng, Yiping; Herrmann, Sven; Carini, Gabriella; Pines, Jack; Hart, Philip; Kenney, Christopher; Guillet, Serge; Boutet, Sebastien; Williams, Garth; Messerschmidt, Marc; Seibert, Marvin; Moeller, Stefan; Hastings, Jerome B; Reis, David A

2015-01-01T23:59:59.000Z

138

Synchrotron x-ray fluorescence and extended x-ray absorption fine structure analysis  

SciTech Connect

The advent of dedicated synchrotron radiation sources has led to a significant increase in activity in many areas of science dealing with the interaction of x-rays with matter. Synchrotron radiation provides intense, linearly polarized, naturally collimated, continuously tunable photon beams, which are used to determine not only the elemental composition of a complex, polyatomic, dilute material but also the chemical form of the elements with improved accuracy. Examples of the application of synchrotron radiation include experiments in synchrotron x-ray fluorescence (SXRF) analysis and extended x-ray absorption fine structure (EXAFS) analysis. New synchrotron radiation x-ray microprobes for elemental analysis in the parts per billion range are under construction at several laboratories. 76 references, 24 figures.

Chen, J.R.; Gordon, B.M.; Hanson, A.L.; Jones, K.W.; Kraner, H.W.; Chao, E.C.T.; Minkin, J.A.

1984-01-01T23:59:59.000Z

139

X-ray imaging crystal spectrometer for extended X-ray sources  

DOE Patents (OSTI)

Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokomak fusion experiment to provide spatially and temporally resolved data on plasma parameters using the imaging properties for Bragg angles near 45. For a Bragg angle of 45.degree., the spherical crystal focuses a bundle of near parallel X-rays (the cross section of which is determined by the cross section of the crystal) from the plasma to a point on a detector, with parallel rays inclined to the main plain of diffraction focused to different points on the detector. Thus, it is possible to radially image the plasma X-ray emission in different wavelengths simultaneously with a single crystal.

Bitter, Manfred L. (Princeton, NJ); Fraenkel, Ben (Jerusalem, IL); Gorman, James L. (Bordentown, NJ); Hill, Kenneth W. (Lawrenceville, NJ); Roquemore, A. Lane (Cranbury, NJ); Stodiek, Wolfgang (Princeton, NJ); von Goeler, Schweickhard E. (Princeton, NJ)

2001-01-01T23:59:59.000Z

140

In situ determination of the spinel–post-spinel transition in Fe3O4 at high pressure and temperature by synchrotron X-ray diffraction  

Science Journals Connector (OSTI)

...Crystallography, 34, 210-213. Wang, Y., Rivers, M., Sutton...high-pressure facility for synchroton radiation research at GeoSoilEnviroCars...Technology, 7, 1490-1495. Wang, Y., Rivers, M., Sutton...Swiss-army-knife approach to synchroton-based experimental studies...

K. Schollenbruch; A.B. Woodland; D.J. Frost; Y. Wang; T. Sanehira; F. Langenhorst

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Definition: X-Ray Diffraction (XRD) | Open Energy Information  

Open Energy Info (EERE)

X-Ray Diffraction (XRD) X-Ray Diffraction (XRD) Jump to: navigation, search Dictionary.png X-Ray Diffraction (XRD) X-Ray Diffraction (XRD) is a laboratory-based technique commonly used for identification of crystalline materials and analysis of unit cell dimensions. One of two primary types of XRD analysis (X-ray powder diffraction and single-crystal XRD) is commonly applied to samples to obtain specific information about the crystalline material under investigation. X-ray powder diffraction is widely used in geology, environmental science, material science, and engineering to rapidly identify unknown crystalline substances (typically in less than 20 minutes). A pure, finely ground, and homogenized sample is required for determination of the bulk composition. Additional uses include detailed

142

Detection limits of high temperature superconducting materials on various substrates by energy dispersive X-ray fluorescence and proton induced X-ray emission methods  

Science Journals Connector (OSTI)

Application of energy dispersive X-ray fluorescence (EDXRF) and proton induced X-ray emission (PIXE) methods has been demonstrated for determining the elemental composition of thin film superconducting materia...

M Lal; H N Bajpai; D Joseph; R K Choudhury

1990-04-01T23:59:59.000Z

143

The Kinetic Effect on Structural Behavior of Mixed LiMn2O4–LiNi1/3Co1/3Mn1/3O2 Cathode Materials Studied by In Situ Time-resolved X-ray Diffraction Technique  

SciTech Connect

How the structural changes of each active material in mixed cathode systems take place at different charge-discharge rates is quite important in the application of the system in which the mixed cathode materials with different rate capabilities are formed into one composite electrode. Here we report the results of the real time structural change studies of mixed LiMn{sub 2}O{sub 4}-LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} composite cathode in a Li-ion cell by using in situ synchrotron-based time resolved x-ray diffraction (TR-XRD) technique. The layer structured component in the mixed composite cathode system shows less utilization at fast discharge rate (high power mode) whereas the spinel structured component is fully utilized. This clearly demonstrates that the reduced capacity at fast discharge rate for this system is caused by the less utilization of the layer structured component. The real time monitoring of the structural behavior at various discharge rates is a great tool to design the best ratios of active materials with different rate capabilities in the mixed cathode systems for different applications.

Yoon W. S.; Nam K.; Jang, D.; Chung, K.Y.; Cho, Y.-H.; Choi, S.; Hanson, J.C.; Yang, X.-Q.

2012-02-01T23:59:59.000Z

144

Beyond hard x-ray photoelectron spectroscopy: Simultaneous combination with x-ray diffraction  

SciTech Connect

Hard x-ray photoelectron spectroscopy (HAXPES) is a powerful and novel emerging technique for the nondestructive determination of electronic properties and chemical composition of bulk, buried interfaces and surfaces. It benefits from the exceptionally large escape depth of high kinetic energy photoelectrons, increasing the information depth up to several tens of nanometers. Complementing HAXPES with an atomic structure sensitive technique (such as x-ray diffraction) opens a new research field with major applications for materials science. At SpLine, the Spanish CRG beamline at the European Synchrotron Radiation Facility, we have developed a novel experimental set-up that combines HAXPES and x-ray diffraction (x-ray reflectivity, surface x-ray diffraction, grazing incidence x-ray diffraction, and reciprocal space maps). Both techniques can be operated simultaneously on the same sample and using the same excitation source. The set-up includes a robust 2S + 3D diffractometer hosting a ultrahigh vacuum chamber equipped with a unique photoelectron spectrometer (few eV < electron kinetic energy < 15 keV), x-ray tube (Mg/Ti), 15 keV electron gun, and auxiliary standard surface facilities (molecular beam epitaxy evaporator, ion gun, low energy electron diffraction, sample heating/cooling system, leak valves, load-lock sample transfer, etc.). This end-station offers the unique possibility of performing simultaneous HAXPES + x-ray diffraction studies. In the present work, we describe the experimental set-up together with two experimental examples that emphasize its outstanding capabilities: (i) nondestructive characterization of the Si/Ge and HfO{sub 2}/SiO{sub 2} interfaces on Ge-based CMOS devices, and (ii) strain study on La{sub 0.7}Ca{sub 0.3}MnO{sub 3} ultrathin films grown on SrTiO{sub 3}(001) substrate.

Rubio-Zuazo, Juan; Castro, German R. [SpLine, Spanish CRG beamline at the European Synchrotron Radiation Facility, B.P. 220, F-38043 Grenoble (France) and ICMM-CSIC Cantoblanco, E-28049 Madrid (Spain)

2013-05-15T23:59:59.000Z

145

X-ray shearing interferometer  

DOE Patents (OSTI)

An x-ray interferometer for analyzing high density plasmas and optically opaque materials includes a point-like x-ray source for providing a broadband x-ray source. The x-rays are directed through a target material and then are reflected by a high-quality ellipsoidally-bent imaging crystal to a diffraction grating disposed at 1.times. magnification. A spherically-bent imaging crystal is employed when the x-rays that are incident on the crystal surface are normal to that surface. The diffraction grating produces multiple beams which interfere with one another to produce an interference pattern which contains information about the target. A detector is disposed at the position of the image of the target produced by the interfering beams.

Koch, Jeffrey A. (Livermore, CA)

2003-07-08T23:59:59.000Z

146

X-Ray Interactions with Matter from the Center for X-Ray Optics (CXRO)  

DOE Data Explorer (OSTI)

The primary interactions of low-energy x-rays within condensed matter, viz. photoabsorption and coherent scattering, are described for photon energies outside the absorption threshold regions by using atomic scattering factors. The atomic scattering factors may be accurately determined from the atomic photoabsorption cross sections using modified Kramers-Kronig dispersion relations. From a synthesis of the currently available experimental data and recent theoretical calculations for photoabsorption, the angle-independent, forward-scattering components of the atomic scattering factors have been thus semiempirically determined and tabulated here for 92 elements and for the region 50-30,000 eV. Atomic scattering factors for all angles of coherent scattering and at the higher photon energies are obtained from these tabulated forward-scattering values by adding a simple angle-dependent form-factor correction. The incoherent scattering contributions that become significant for the light elements at the higher photon energies are similarly determined. The basic x-ray interaction relations that are used in applied x-ray physics are presented here in terms of the atomic scattering factors. The bulk optical constants are also related to the atomic scattering factors. These atomic and optical relations are applied to the detailed calculation of the reflectivity characteristics of a series of practical x-ray mirror, multilayer, and crystal monochromators. Comparisons of the results of this semiempirical,"atom-like", description of x-ray interactions for the low-energy region with those of experiment and ab initio theory are presented.

Henke, B.L.; Gullikson, E.M.; Davis, J.C.

147

Optics for X-Ray Laser and Laser Plasma Soft X-Ray Radiation  

Science Journals Connector (OSTI)

Focusing X-ray grazing incidence optics for X-ray laser and laser plasma soft X-ray radiation has been studied. ... computer code. Parabolic axisymmetric mirror for focusing Princeton X-ray laser beam and ellipso...

L. Pina; A. Inneman; R. Hudec

1996-01-01T23:59:59.000Z

148

Probing Spatial, Electronic Structures with X-ray Scattering, Spectroscopic  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing Spatial, Electronic Structures with X-ray Scattering, Spectroscopic Probing Spatial, Electronic Structures with X-ray Scattering, Spectroscopic Techniques Wednesday, September 5, 2012 - 10:45am SLAC, Bldg. 137, Room 226 Gang Chen Seminar: Structures at atomic scales are traditionally determined through X-ray crystallography that amplifies scattering intensities by introducing spatial periodicity. For amorphous materials and many macromolecules, such as viruses, proteins and biofilms, it is hard to determine structures due to their incapability to crystallize or change of configuration during crystallization. In this talk, I will present the application of X-ray reflectivity and a newly developed fluctuation X-ray scattering technique to study the structures of lipid membranes and randomly oriented nanoparticles. Three different types of domain registrations occurring with

149

Novel Application of X-ray Computed Tomography:? Determination of Gas/Liquid Contact Area and Liquid Holdup in Structured Packing  

Science Journals Connector (OSTI)

Figure 7 Flow system used with GE X-ray CT scanner:? from left, air?water column, water pump, and cart containing flow meters. ... In Figure 24, the results of experimental holdup measurements on the column used for imaging are compared with SRP data from the hydraulic testing of Mellapak 250Y. ... The two-fluid model proved powerful in the prediction of the column hydraulics under various operational conditions such as atm. ...

Christian W. Green; John Farone; Julie K. Briley; R. Bruce Eldridge; Richard A. Ketcham; Ben Nightingale

2007-07-24T23:59:59.000Z

150

SMB, X-Ray Spectroscopy & Imaging  

NLE Websites -- All DOE Office Websites (Extended Search)

Home X-Ray Spectroscopy & Imaging X-Ray Spectroscopy & Imaging SSRL has five hard X-ray Spectroscopy beamlines and three Microfocus Imaging beamlines dedicated to Biological and...

151

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

Lensless X-Ray Imaging in Reflection Lensless X-Ray Imaging in Reflection Print Wednesday, 26 October 2011 00:00 The advent of x-ray free-electron laser (XFEL) light sources has...

152

In situ X-ray Characterization of Energy Storage Materials |...  

NLE Websites -- All DOE Office Websites (Extended Search)

in the global move towards clean, renewable energy is the electrification of the automobile. Current battery technology limits EV (electric vehicles) to a short travel range,...

153

X-ray spectroscopy of manganese clusters  

SciTech Connect

Much of this thesis represents the groundwork necessary in order to probe Mn clusters more productively than with conventional Mn K-edge XAS and is presented in Part 1. Part 2 contains the application of x-ray techniques to Mn metalloproteins and includes a prognosis at the end of each chapter. Individual Mn oxidation states are more readily distinguishable in Mn L-edge spectra. An empirical mixed valence simulation routine for determining the average Mn oxidation state has been developed. The first Mn L-edge spectra of a metalloprotein were measured and interpreted. The energy of Mn K{beta} emission is strongly correlated with average Mn oxidation state. K{beta} results support oxidation states of Mn(III){sub 2}(IV){sub 2} for the S{sub 1} state of Photosystem II chemical chemically reduced preparations contain predominantly Mn(II). A strength and limitation of XAS is that it probes all of the species of a particular element in a sample. It would often be advantageous to selectively probe different forms of the same element. The first demonstration that chemical shifts in x-ray fluorescence energies can be used to obtain oxidation state-selective x-ray absorption spectra is presented. Spin-dependent spectra can also be used to obtain a more simplified picture of local structure. The first spin-polarized extended x-ray absorption fine structure using Mn K{beta} fluorescence detection is shown.

Grush, M.M. [Univ. of California, Davis, CA (United States). Dept. of Applied Science; [Lawrence Berkeley National Lab., CA (United States). Energy and Environment Div.

1996-06-01T23:59:59.000Z

154

X-ray attenuation properties of stainless steel (u)  

SciTech Connect

Stainless steel vessels are used to enclose solid materials for studying x-ray radiolysis that involves gas release from the materials. Commercially available stainless steel components are easily adapted to form a static or a dynamic condition to monitor the gas evolved from the solid materials during and after the x-ray irradiation. Experimental data published on the x-ray attenuation properties of stainless steel, however, are very scarce, especially over a wide range of x-ray energies. The objective of this work was to obtain experimental data that will be used to determine how a poly-energetic x-ray beam is attenuated by the stainless steel container wall. The data will also be used in conjunction with MCNP (Monte Carlos Nuclear Particle) modeling to develop an accurate method for determining energy absorbed in known solid samples contained in stainless steel vessels. In this study, experiments to measure the attenuation properties of stainless steel were performed for a range of bremsstrahlung x-ray beams with a maximum energy ranging from 150 keV to 10 MeV. Bremsstrahlung x-ray beams of these energies are commonly used in radiography of engineering and weapon components. The weapon surveillance community has a great interest in understanding how the x-rays in radiography affect short-term and long-term properties of weapon materials.

Wang, Lily L [Los Alamos National Laboratory; Berry, Phillip C [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

155

X-ray Imaging Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Imaging and Spectro-microscopy: Imaging and Spectro-microscopy: the Present and the Future Stanford Synchrotron Radiation Laboratory October 8-9, 2002 Organizers: John Miao & Keith Hodgson A workshop on "X-ray Imaging and Spectro-microscopy: the Present and the Future" was held on October 8-9, 2002. This workshop, organized by John Miao (SSRL) and Keith Hodgson (SSRL) provided a forum to discuss the scientific applications of a variety of imaging and spectro-microscopic techniques, including photoemission electron microscopy (PEEM), angle resolved photoemission spectroscopy (ARPES), coherent diffraction imaging, x-ray microscopy, micro-tomography, holographic imaging, and x-ray micro-probe. Twelve invited speakers discussed the important scientific applications of these techniques, and also predicted the future scientific directions with the advance of instrumentation and x-ray sources. The workshop was well attended with over fifty registered attendees.

156

Miniature x-ray source  

DOE Patents (OSTI)

A miniature x-ray source utilizing a hot filament cathode. The source has a millimeter scale size and is capable of producing broad spectrum x-ray emission over a wide range of x-ray energies. The miniature source consists of a compact vacuum tube assembly containing the hot filament cathode, an anode, a high voltage feedthru for delivering high voltage to the cathode, a getter for maintaining high vacuum, a connector for initial vacuum pump down and crimp-off, and a high voltage connection for attaching a compact high voltage cable to the high voltage feedthru. At least a portion of the vacuum tube wall is fabricated from highly x-ray transparent materials, such as sapphire, diamond, or boron nitride.

Trebes, James E. (Livermore, CA); Bell, Perry M. (Tracy, CA); Robinson, Ronald B. (Modesto, CA)

2000-01-01T23:59:59.000Z

157

Center for X-Ray Optics, 1992  

SciTech Connect

This report discusses the following topics: Center for X-Ray Optics; Soft X-Ray Imaging wit Zone Plate Lenses; Biological X-Ray microscopy; Extreme Ultraviolet Lithography for Nanoelectronic Pattern Transfer; Multilayer Reflective Optics; EUV/Soft X-ray Reflectometer; Photoemission Microscopy with Reflective Optics; Spectroscopy with Soft X-Rays; Hard X-Ray Microprobe; Coronary Angiography; and Atomic Scattering Factors.

Not Available

1993-08-01T23:59:59.000Z

158

X-ray Stacking 2008-Apr-22 Astrostats X-ray Stacking  

E-Print Network (OSTI)

X-ray Stacking 2008-Apr-22 Astrostats X-ray Stacking Tom Aldcroft SAO/CXC #12;X-ray Stacking 2008 analysis for a sample Stacking ­ mean properties of sample Chandra X-ray data (faint point sources) are photon-limited with low background => stacking in X-rays is very effective #12;X-ray Stacking 2008-Apr-22

Wolfe, Patrick J.

159

Photon Sciences | Beamlines | XPD: X-ray Powder Diffraction  

NLE Websites -- All DOE Office Websites (Extended Search)

XPD: X-ray Powder Diffraction XPD: X-ray Powder Diffraction Poster | Fact Sheet | Preliminary Design Report Scientific Scope XPD is a tunable facility with the ability to collect diffraction data at high x-ray energies (40keV-80keV), offering rapid acquisition (millisecond) and high angular resolution capabilities on the same instrument. XPD addresses future scientific challenges in, for example, hydrogen storage, CO2 sequestration, advanced structural ceramics, catalysis, and materials processing. Such materials of high technological value often are complex, nanostructured and heterogeneous. The scientific grand challenge is to obtain robust and quantitative (micro)structural information, not only in the ground state at ambient conditions, but also in situ or in operando with varying temperature, pressure, magnetic/electric/stress

160

Center for X-Ray Optics, 1991  

SciTech Connect

This report discusses: Soft-X-Ray imaging with zone-plate lenses; multilayer reflective optics; and spectroscopy with x-rays.

Not Available

1992-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

SMB, X-ray Absorption Spectroscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Absorption Spectroscopy X-ray Absorption Spectroscopy X-ray absorption spectroscopy (XAS) is a well-established technique for simultaneous local geometric and electronic structure...

162

Tokamak x ray diagnostic instrumentation  

SciTech Connect

Three classes of x-ray diagnostic instruments enable measurement of a variety of tokamak physics parameters from different features of the x-ray emission spectrum. (1) The soft x-ray (1 to 50 keV) pulse-height-analysis (PHA) diagnostic measures impurity concentrations from characteristic line intensities and the continuum enhancement, and measures the electron temperature from the continuum slope. (2) The Bragg x-ray crystal spectrometer (XCS) measures the ion temperature and neutral-beam-induced toroidal rotation velocity from the Doppler broadening and wavelength shift, respectively, of spectral lines of medium-Z impurity ions. Impurity charge state distributions, precise wavelengths, and inner-shell excitation and recombination rates can also be studied. X rays are diffracted and focused by a bent crystal onto a position-sensitive detector. The spectral resolving power E/..delta..E is greater than 10/sup 4/ and time resolution is 10 ms. (3) The x-ray imaging system (XIS) measures the spatial structure of rapid fluctuations (0.1 to 100 kHZ) providing information on MHD phenomena, impurity transport rates, toroidal rotation velocity, plasma position, and the electron temperature profile. It uses an array of silicon surface-barrier diodes which view different chords of the plasma through a common slot aperture and operate in current (as opposed to counting) mode. The effectiveness of shields to protect detectors from fusion-neutron radiation effects has been studied both theoretically and experimentally.

Hill, K.W.; Beiersdorfer, P.; Bitter, M.; Fredrickson, E.; Von Goeler, S.; Hsuan, H.; Johnson, L.C.; Liew, S.L.; McGuire, K.; Pare, V.

1987-01-01T23:59:59.000Z

163

Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism  

NLE Websites -- All DOE Office Websites (Extended Search)

Unexpected Angular Dependence of Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Print Wednesday, 29 August 2007 00:00 Using spectroscopic information for magnetometry and magnetic microscopy obviously requires detailed theoretical understanding of spectral shape and magnitude of dichroism signals. A research team at ALS Beamline 4.0.2 has now shown unambiguously that, contrary to common belief, spectral shape and magnitude of x-ray magnetic linear dichroism (XMLD) are not only determined by the relative orientation of magnetic moments and x-ray polarization, but their orientation relative to the crystallographic axes must be taken into account for accurate interpretation of XMLD data. Magnetism and X Rays

164

Fresnel and refractive lenses for X-rays  

Science Journals Connector (OSTI)

We present a Gaussian beam analysis of X-ray refractive and Fresnel lenses. The X-ray refractive lens is featured by an intrinsic soft (Gaussian) aperture due to strong absorption of X-rays by materials. We defined a parameter N0, the critical Fresnel number (CFN), to describe this optical property. The values of N0 for all practical materials are below 1000 for photon energies exceeding 30 eV, still lower for high-Z materials. The maximum effective Fresnel number of a lens is determined by its material to be 2N0 and its maximum enhancement of X-ray intensity is limited to (2?N0)2, independent of its shape. We found that the refractive lens is likely to be useful for manipulating nearly diffraction limited beam in the hard X-ray region and its application is severely restricted by available fabrication capabilities today. X-ray Fresnel lenses, both in cylindrical and linear forms, are proposed as superior focusing elements for hard X-rays. Their high efficiency, up to 100% in optimal construction, will enable us to manipulate beams with multiple lenses and obtain higher performance optics. Their design and fabrication are discussed in reference to those of X-ray Fresnel zone plates and micro Fresnel lenses for optoelectronics.

B.X. Yang

1993-01-01T23:59:59.000Z

165

Human genome sequencing with direct x-ray holographic imaging  

SciTech Connect

Direct holographic imaging of biological materials is widely applicable to the study of the structure, properties and action of genetic material. This particular application involves the sequencing of the human genome where prospective genomic imaging technology is composed of three subtechnologies, name an x-ray holographic camera, suitable chemistry and enzymology for the preparation of tagged DNA samples, and the illuminator in the form of an x-ray laser. We report appropriate x-ray camera, embodied by the instrument developed by MCR, is available and that suitable chemical and enzymatic procedures exist for the preparation of the necessary tagged DNA strands. Concerning the future development of the x-ray illuminator. We find that a practical small scale x-ray light source is indeed feasible. This outcome requires the use of unconventional physical processes in order to achieve the necessary power-compression in the amplifying medium. The understanding of these new physical mechanisms is developing rapidly. Importantly, although the x-ray source does not currently exist, the understanding of these new physical mechanisms is developing rapidly and the research has established the basic scaling laws that will determine the properties of the x-ray illuminator. When this x-ray source becomes available, an extremely rapid and cost effective instrument for 3-D imaging of biological materials can be applied to a wide range of biological structural assays, including the base-pair sequencing of the human genome and many questions regarding its higher levels of organization.

Rhodes, C.K.

1993-06-08T23:59:59.000Z

166

Synchroton X-Ray Studies of Liquid-Vapor Interfaces  

Science Journals Connector (OSTI)

The variation of density across the liquid-vapor interface from essentially zero density far out in the vapor phase to a homogeneous density deep in the liquid phase can be determined by X-ray reflectivity mea...

J. Als-Nielsen

1988-01-01T23:59:59.000Z

167

X-ray Emission from Massive Stars  

E-Print Network (OSTI)

X-ray Emission from Massive Stars David Cohen Department of Physics and Astronomy Swarthmore be related to the production of X-rays on massive stars. If so, massive stars' X-rays are much different than those found our own Sun and other cooler stars like the Sun that produce X-rays via magnetic activity

Cohen, David

168

X-ray Emission from Massive Stars  

E-Print Network (OSTI)

X-ray Emission from Massive Stars David Cohen Department of Physics and Astronomy Swarthmore #12;What is the mechanism by which massive stars produce x-rays? New results from the Chandra X-ray Observatory ­ high-resolution x-ray spectroscopy: measuring Doppler broadening in emission lines Testing

Cohen, David

169

Spectroscopic imaging, diffraction, and holography with x-ray photoemission  

SciTech Connect

X-ray probes are capable of determining the spatial structure of an atom in a specific chemical state, over length scales from about a micron all the way down to atomic resolution. Examples of these probes include photoemission microscopy, energy-dependent photoemission diffraction, photoelectron holography, and X-ray absorption microspectroscopy. Although the method of image formation, chemical-state sensitivity, and length scales can be very different, these X-ray techniques share a common goal of combining a capability for structure determination with chemical-state specificity. This workshop will address recent advances in holographic, diffraction, and direct imaging techniques using X-ray photoemission on both theoretical and experimental fronts. A particular emphasis will be on novel structure determinations with atomic resolution using photoelectrons.

Not Available

1992-02-01T23:59:59.000Z

170

Compact x-ray source and panel  

DOE Patents (OSTI)

A compact, self-contained x-ray source, and a compact x-ray source panel having a plurality of such x-ray sources arranged in a preferably broad-area pixelized array. Each x-ray source includes an electron source for producing an electron beam, an x-ray conversion target, and a multilayer insulator separating the electron source and the x-ray conversion target from each other. The multi-layer insulator preferably has a cylindrical configuration with a plurality of alternating insulator and conductor layers surrounding an acceleration channel leading from the electron source to the x-ray conversion target. A power source is connected to each x-ray source of the array to produce an accelerating gradient between the electron source and x-ray conversion target in any one or more of the x-ray sources independent of other x-ray sources in the array, so as to accelerate an electron beam towards the x-ray conversion target. The multilayer insulator enables relatively short separation distances between the electron source and the x-ray conversion target so that a thin panel is possible for compactness. This is due to the ability of the plurality of alternating insulator and conductor layers of the multilayer insulators to resist surface flashover when sufficiently high acceleration energies necessary for x-ray generation are supplied by the power source to the x-ray sources.

Sampayon, Stephen E. (Manteca, CA)

2008-02-12T23:59:59.000Z

171

Ultrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS)  

E-Print Network (OSTI)

: ultrafast x-rays, x-ray absorption spectroscopy, terawatt lasers, ultrafast reaction dynamics, atomic motion atomic motion by scrutinizing the changes in x- ray absorption spectra during reactions. FirstUltrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS) Guangjun

Guo, Ting

172

In Situ Study of Solid Electrolyte Interphase (SEI) Formation  

NLE Websites -- All DOE Office Websites (Extended Search)

M. J. Bedzyk, "In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode," Chemistry of Materials, 24(15), 3038 -3043...

173

Iran Thomas Auditorium, 8600 Materials For Energy: In Situ Synchrotron...  

NLE Websites -- All DOE Office Websites (Extended Search)

December 15, 2011 4:00 pm Iran Thomas Auditorium, 8600 Materials For Energy: In Situ Synchrotron X-Ray Studies for Materials Design and Discovery Stephen K. Streiffer Deputy...

174

Focused X-ray source  

DOE Patents (OSTI)

Disclosed is an intense, relatively inexpensive X-ray source (as compared to a synchrotron emitter) for technological, scientific, and spectroscopic purposes. A conical radiation pattern produced by a single foil or stack of foils is focused by optics to increase the intensity of the radiation at a distance from the conical radiator. 8 figs.

Piestrup, M.A.; Boyers, D.G.; Pincus, C.I.; Maccagno, P.

1990-08-21T23:59:59.000Z

175

Quantitative x-ray imager (abstract)  

SciTech Connect

We report on development of a quantitative x-ray imager (QXI) for the national Inertial Confinement Fusion Program. Included in this development is a study of photocathode response as a function of photon energy, 2--17.5 keV, which is related to diagnostic development on the National Ignition Facility (NIF). The QXI is defined as being a quantative imager due to the repeated characterization. This instrument is systematically checked out, electronically as well as its photocathode x-ray response, both on a direct current and pulsed x-ray sources, before and after its use on a shot campaign. The QXI is a gated x-ray imager1 used for a variety of experiments conducted in the Inertial Confinement Fusion and Radiation Physics Program. The camera was assembled in Los Alamos and has been under development since 1997 and has now become the workhorse framing camera by the program. The electronics were built by Grant Applied Physics of San Fransisco, CA.2 The QXI has been used at the LANL Trident, LLNL Nova, and University of Rochester Laboratory OMEGA laser facilities. The camera consists of a grated microchannel plate (MCP), a phosphor coated fiberoptic faceplate coupled to film for data readout, along with high speed electronic pulsers to drive the x-ray detector. The QXI has both a two-strip and a four-strip detection head and has the ability to individually bias the gain of each of the strips. The timing of the QXI was done at the Trident short pulse laboratory, using 211 nm light. Single strip jitter was looked at as well and determined to be <25 ps. Flatfielding of the photocathode across the MCP was done with the Trident main laser with 150 J on a gold disk with a 1 ns. Spatial resolution was determined to be <5 {mu}m by using the same laser conditions as before and a backlit 1000 lp/in. grid. The QXI has been used on cylindrical implosion work at the Nova Laser Facility, and on direct-drive cylinder mix and indirect-drive high convergence implosion experiments at OMEGA. Its two-strip module has provided the capability to look at point backlighters, as part of technique development for experiments on the NIF. Its next use will be in March 2000 with its off axis viewer nose at Omega, providing a perpendicular view of Rayleigh--Taylor spike dissipation.

Evans, Scott C.; Archuleta, Tom N.; Oertel, John A.; Walsh, Peter J.

2001-01-01T23:59:59.000Z

176

Application of synchrotron radiation to x-ray fluorescence analysis of trace elements  

SciTech Connect

The development of synchrotron radiation x-ray sources has provided the means to greatly extend the capabilities of x-ray fluorescence analysis for determinations of trace element concentrations. A brief description of synchrotron radiation properties provides a background for a discussion of the improved detection limits compared to existing x-ray fluorescence techniques. Calculated detection limits for x-ray microprobes with micrometer spatial resolutions are described and compared with experimental results beginning to appear from a number of laboratories. The current activities and future plans for a dedicated x-ray microprobe beam line at the National Synchrotron Light Source (NSLS) of Brookhaven National Laboratory are presented.

Gordon, B.M.; Jones, K.W.; Hanson, A.L.

1986-08-01T23:59:59.000Z

177

X-rays at Solid-Liquid Surfaces  

SciTech Connect

Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

2007-05-02T23:59:59.000Z

178

Microgap x-ray detector  

DOE Patents (OSTI)

An x-ray detector which provides for the conversion of x-ray photons into photoelectrons and subsequent amplification of these photoelectrons through the generation of electron avalanches in a thin gas-filled region subject to a high electric potential. The detector comprises a cathode (photocathode) and an anode separated by the thin, gas-filled region. The cathode may comprise a substrate, such a beryllium, coated with a layer of high atomic number material, such as gold, while the anode can be a single conducting plane of material, such as gold, or a plane of resistive material, such as chromium/silicon monoxide, or multiple areas of conductive or resistive material, mounted on a substrate composed of glass, plastic or ceramic. The charge collected from each electron avalanche by the anode is passed through processing electronics to a point of use, such as an oscilloscope.

Wuest, Craig R. (Danville, CA); Bionta, Richard M. (Livermore, CA); Ables, Elden (Livermore, CA)

1994-01-01T23:59:59.000Z

179

Chest x-Rays | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chest x-Rays Chest x-Rays Chest x-Rays Chest X-ray B-Reading The B-reading is a special reading of a standard chest x-ray film performed by a physician certified by the National Institute for Occupational Safety and Health (NIOSH). The reading looks for changes on the chest x-ray that may indicate exposure and disease caused by agents such as asbestos or silica. The B-reading is considered a special reading because doctors who are certified by NIOSH to perform B-readings use a specific protocol to read and record the findings as developed by the International Labour Organization (ILO). The ILO's protocol provides rules for systematically examining the x-ray in a step-by-step method and recording certain abnormalities or changes on the chest x-ray that can be attributable to

180

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs...

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Imaging in Reflection Print Wednesday, 26 October 2011 00:00 The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities...

182

Producing X-rays at the APS  

ScienceCinema (OSTI)

An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest X-ray beams in the Western Hemisphere, and the research carried out by scientists using those X-rays.

None

2013-04-19T23:59:59.000Z

183

SMB, X-ray Fluorescence Imaging  

NLE Websites -- All DOE Office Websites (Extended Search)

Fluorescence Imaging X-ray Fluorescence Imaging X-ray fluorescence imaging utilizes the high brightness of SPEAR3 and focused beam generated by the uses of K-B optics, capillaries...

184

Chandra X-ray Observatory Center  

E-Print Network (OSTI)

Chandra X-ray Observatory Center Harvard-Smithsonian Center for Astrophysics 60 Garden St in hot gas about 250 million light years from Earth. (Credit: X-ray: NASA/CXC/SAO/E.Bulbul, et al-Newton has revealed a mysterious X-ray signal in the data. This signal is represented in the circled data

185

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network (OSTI)

2/9/07 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 9, 07] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

186

Chandra X-ray Observatory Center  

E-Print Network (OSTI)

Chandra X-ray Observatory Center Harvard-Smithsonian Center for Astrophysics 60 Garden St million light years from Earth. (Credit: X-ray: NASA/CXC/Wesleyan Univ./R.Kilgard, et al; Optical: NASA with optical data from the Hubble Space Telescope (red, green, and blue). The X-ray data reveal hundreds

187

X-ray Spectroscopy of Cool Stars  

E-Print Network (OSTI)

High-resolution X-ray spectroscopy has addressed not only various topics in coronal physics of stars, but has also uncovered important features relevant for our understanding of stellar evolution and the stellar environment. I summarize recent progress in coronal X-ray spectroscopy and in particular also discuss new results from studies of X-rays from pre-main sequence stars.

M. Guedel

2006-09-11T23:59:59.000Z

188

X-Ray Physics Evan Berkowitz  

E-Print Network (OSTI)

X-Ray Physics Evan Berkowitz Junior, MIT Department of Physics (Dated: October 25, 2006) We measure a variety of phenomena related to X-Ray absorption and production. We present data which conforms within, as are 22 Na electron-positron annhilation lines. The importance of understanding x-rays is demonstrated

189

Chandra X-ray Observatory Center  

E-Print Network (OSTI)

Chandra X-ray Observatory Center Harvard-Smithsonian Center for Astrophysics 60 Garden St 200 million light years from Earth. (Credit: X-ray: NASA/CXC/UAH/M.Sun et al; Optical: NASA, ESA, & the Hubble Heritage Team (STScI/AURA) Caption: This composite image from the Chandra X-ray Observatory (blue

190

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network (OSTI)

9/6/09 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 6, 09] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

191

Chandra X-ray Observatory Center  

E-Print Network (OSTI)

Chandra X-ray Observatory Center Harvard-Smithsonian Center for Astrophysics 60 Garden St. Cambridge, MA 02138 USA http://chandra.harvard.edu Four Supernova Remnants: NASA's Chandra X-ray Observatory's Chandra X-ray Observatory, four newly processed images of supernova remnants dramatically illustrate

192

GC-MS determination of parabens, triclosan and methyl triclosan in water by in situ derivatisation and stir-bar sorptive extraction  

Science Journals Connector (OSTI)

Stir-bar sorptive extraction in combination with an in situ derivatisation reaction and thermal desorption–gas chromatography–mass spectrometry was successfully applied to determine parabens (methylparaben, is...

Ana María Casas Ferreira; Monika Möder…

2011-01-01T23:59:59.000Z

193

Using Light to Control How X Rays Interact with Matter  

NLE Websites -- All DOE Office Websites (Extended Search)

ultrafast x-ray spectroscopy. ALS femtosecond spectroscopy beamline layout. Femtosecond x-ray and laser pulses derive from a single 800-nm laser oscillator. Femtosecond x rays...

194

X-RAY SPECTROMETRY X-Ray Spectrom. 2007; 36: 336342  

E-Print Network (OSTI)

X-RAY SPECTROMETRY X-Ray Spectrom. 2007; 36: 336­342 Published online in Wiley InterScience (www.interscience.wiley.com) DOI: 10.1002/xrs.980 Fish otolith trace element maps: new approaches with synchrotron microbeam x-ray of elements as they accrete through a fish's life. We apply synchrotron microbeam x-ray fluorescence methods

Limburg, Karin E.

195

X-ray Pulsations in the Supersoft X-ray Binary CAL 83  

E-Print Network (OSTI)

X-ray data reveal that the supersoft X-ray binary CAL 83 exhibits 38.4 minute pulsations at some epochs. These X-ray variations are similar to those found in some novae and are likely to be caused by nonradial pulsations the white dwarf. This is the first detection of pulsations in a classical supersoft X-ray binary.

P. C. Schmidtke; A. P. Cowley

2005-09-28T23:59:59.000Z

196

Evaluation of a 6-wire thermocouple psychrometer for determination of in-situ water potentials  

SciTech Connect

A 6-wire, Peltier-type thermocouple psychrometer was designed and evaluated by the U.S. Geological Survey for monitoring in-situ water potentials in dry-drilled boreholes in the unsaturated zone at Yucca Mountain, Nye County, Nevada. The psychrometer consists of a wet-bulb, chromel-constantan, sensing junction and a separate dry-bulb, copper-constantan, reference junction. Two additional reference junctions are formed where the chromel and constantan wires of the wet-bulb sensing junction are soldered to separate, paired, copper, lead wires. In contrast, in the standard 3-wire thermocouple psychrometer, both the wet bulb and dry bulb share a common wire. The new design has resulted in a psychrometer that has an expanded range and greater reliability, sensitivity, and accuracy compared to the standard model.

Loskot, C.L.; Rousseau, J.P. [Geological Survey, Denver, CO (United States); Kurzmack, M.A. [Foothill Engineering Consultants, Golden, CO (United States)

1994-12-31T23:59:59.000Z

197

Changes in the Atomic Structure through Glass Transition Observed by X-Ray Scattering  

SciTech Connect

The glass transition involves a minor change in the internal energy, and yet the physical and mechanical properties of a glass change dramatically. In order to determine the evolution of the atomic structure through the glass transition, we employed in-situ synchrotron X-ray scattering measurements as a function of temperature on a model material: Zr-Cu-Al metallic glass. We found that the thermal expansion at the atomic level is smaller than the macroscopic thermal expansion, and significantly increases above the glass transition temperature. The observed changes in the pair-distribution function (PDF) are explained in terms of the fluctuations in the local atomic volume and their change through the glass transition.

Egami, Takeshi [ORNL

2012-01-01T23:59:59.000Z

198

X-ray Spectroscopy of Cooling Cluster  

SciTech Connect

We review the X-ray spectra of the cores of clusters of galaxies. Recent high resolution X-ray spectroscopic observations have demonstrated a severe deficit of emission at the lowest X-ray temperatures as compared to that expected from simple radiative cooling models. The same observations have provided compelling evidence that the gas in the cores is cooling below half the maximum temperature. We review these results, discuss physical models of cooling clusters, and describe the X-ray instrumentation and analysis techniques used to make these observations. We discuss several viable mechanisms designed to cancel or distort the expected process of X-ray cluster cooling.

Peterson, J.R.; /SLAC; Fabian, A.C.; /Cambridge U., Inst. of Astron.

2006-01-17T23:59:59.000Z

199

X-ray transmissive debris shield  

DOE Patents (OSTI)

An X-ray debris shield for use in X-ray lithography that is comprised of an X-ray window having a layer of low density foam exhibits increased longevity without a substantial increase in exposure time. The low density foam layer serves to absorb the debris emitted from the X-ray source and attenuate the shock to the window so as to reduce the chance of breakage. Because the foam is low density, the X-rays are hardly attenuated by the foam and thus the exposure time is not substantially increased.

Spielman, R.B.

1996-05-21T23:59:59.000Z

200

X-ray Spectroscopy of Cooling Clusters  

E-Print Network (OSTI)

We review the X-ray spectra of the cores of clusters of galaxies. Recent high resolution X-ray spectroscopic observations have demonstrated a severe deficit of emission at the lowest X-ray temperatures as compared to that expected from simple radiative cooling models. The same observations have provided compelling evidence that the gas in the cores is cooling below half the maximum temperature. We review these results, discuss physical models of cooling clusters, and describe the X-ray instrumentation and analysis techniques used to make these observations. We discuss several viable mechanisms designed to cancel or distort the expected process of X-ray cluster cooling.

J. R. Peterson; A. C. Fabian

2005-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

X-ray transmissive debris shield  

DOE Patents (OSTI)

An X-ray debris shield for use in X-ray lithography that is comprised of an X-ray window having a layer of low density foam exhibits increased longevity without a substantial increase in exposure time. The low density foam layer serves to absorb the debris emitted from the X-ray source and attenuate the shock to the window so as to reduce the chance of breakage. Because the foam is low density, the X-rays are hardly attenuated by the foam and thus the exposure time is not substantially increased.

Spielman, Rick B. (Albuquerque, NM)

1996-01-01T23:59:59.000Z

202

Diffracted X-ray tracking for monitoring intramolecular motion in individual protein molecules using broad band X-ray  

SciTech Connect

Diffracted X-ray tracking (DXT) enables the tilting and twisting motions of single protein molecules to be monitored with micro- to milliradian resolution using a highly brilliant X-ray source with a wide energy bandwidth. We have developed a technique to monitor single molecules using gold nanocrystals attached to individual protein molecules using the BL28B2 beamline at SPring-8. In this paper we present the installation of a single toroidal X-ray mirror at BL28B2 to focus X-rays in an energy range of 10–20 keV (?E/E = 82% for an X-ray with a wide energy bandwidth). With this beamline we tracked diffraction spots from gold nanocrystals over a wide angle range than that using quasi-monochromatic X-rays. Application of the wide angle DXT technique to biological systems enabled us to observe the on-site motions of single protein molecules that have been functionalized in vivo. We further extend the capability of DXT by observing the fractional tilting and twisting motions of inner proteins under various conditions. As a proof of this methodology and to determine instrumental performance the intramolecular motions of a human serum albumin complex with 2-anthracenecarboxylic acid was investigated using the BL28B2 beamline. The random tilting and twisting intramolecular motions are shown to be directly linked to the movement of individual protein molecules in the buffer solution.

Ichiyanagi, Kouhei; Sasaki, Yuji C. [Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 609 Kiban Building 5-1-5 Kashiwanoha, Kahiwashi, Chiba 277-8561 (Japan) [Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 609 Kiban Building 5-1-5 Kashiwanoha, Kahiwashi, Chiba 277-8561 (Japan); Japan Science and Technology Agency, CREST, CREST, Sasaki-Team, 609 Kiban Building, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Sekiguchi, Hiroshi; Hoshino, Masato; Kajiwara, Kentaro; Senba, Yasunori; Ohashi, Haruhiko; Ohta, Noboru [Japan Synchrotron Radiation Research Institute, SPring-8, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)] [Japan Synchrotron Radiation Research Institute, SPring-8, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan); Hoshisashi, Kentaro; Jae-won, Chang; Tokue, Maki; Matsushita, Yufuku [Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 609 Kiban Building 5-1-5 Kashiwanoha, Kahiwashi, Chiba 277-8561 (Japan)] [Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 609 Kiban Building 5-1-5 Kashiwanoha, Kahiwashi, Chiba 277-8561 (Japan); Nishijima, Masaki; Inoue, Yoshihisa [Department of Applied Chemistry and Office for University-Industry Collaboration, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)] [Department of Applied Chemistry and Office for University-Industry Collaboration, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan); Yagi, Naoto [Japan Science and Technology Agency, CREST, CREST, Sasaki-Team, 609 Kiban Building, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan) [Japan Science and Technology Agency, CREST, CREST, Sasaki-Team, 609 Kiban Building, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Japan Synchrotron Radiation Research Institute, SPring-8, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)

2013-10-15T23:59:59.000Z

203

A Versatile Multilayer Polarimeter for the Soft X-Ray Region  

SciTech Connect

As modern undulators can generate light with arbitrary polarization states, experiments exploiting this feature in the range of soft x-rays have become increasingly widespread. For the success of these experiments characterising the polarization at the sample position is vital. Therefore a versatile, multi-purpose, UHV compatible, multilayer polarimeter has been designed and developed for measuring the Stokes vector of a soft x-ray beam. This high-precision, ultra high vacuum compatible instrument is supported by a Hexapod to simplify its alignment. Furthermore, the instrument has its own independent control system and has been designed for portability so that it can be moved with relative ease between different synchrotron facilities. The polarization analysis requires the rotation of a phase retarder and a polarization analyser, both about a common axis of the photon beam. The polarimeter employs reflection / transmission multilayers as phase retarders / analysers. Several sets of multilayers are installed inside the UHV chamber so that they may be exchanged in-situ without breaking the vacuum. The polarimeter doubles-up as a reflectometer / ellipsometer that enable determination of the polarization properties of optical elements including multilayers with very small surface roughness and several hundred bi-layers. The design details of the polarimeter and the results of first experiments to characterise the polarization of a beamline will be presented.

Wagner, U. H.; Wang, H.; Dhesi, S. S; Sawhney, K. J. S. [Diamond Light Source Ltd., Didcot (United Kingdom); MacDonald, M. A.; Poole, I. B.; Quinn, F. M. [Daresbury Laboratories, STFC, Daresbury (United Kingdom)

2010-06-23T23:59:59.000Z

204

Equation of state of adamite up to 11 GPa: a synchrotron X-ray diffraction study  

Science Journals Connector (OSTI)

The compression behavior of natural adamite [Zn2AsO4OH] has been investigated up to 11.07 GPa at room temperature utilizing in situ angle-dispersive X-ray diffraction and a diamond anvil cell. No phase transitio...

Jingui Xu; Maining Ma; Shuyi Wei; Xianxu Hu…

2014-07-01T23:59:59.000Z

205

X-ray Observations of Mrk 231  

E-Print Network (OSTI)

This paper presents new X-ray observations of Mrk 231, an active galaxy of particular interest due to its large infrared luminosity and the presence of several blueshifted broad absorption line (BAL) systems, a phenomenon observed in a small fraction of QSOs. A ROSAT HRI image of Mrk 231 is presented, this shows an extended region of soft X-ray emission, covering several tens of kpc, consistent with the extent of the host galaxy. An ASCA observation of Mrk 231 is also presented. Hard X-rays are detected but the data show no significant variability in X-ray flux. The hard X-ray continuum is heavily attenuated and X-ray column estimates range from ~ 2 x 10^{22} - 10^{23} cm^{-2} depending on whether the material is assumed to be neutral or ionized, and on the model assumed for the extended X-ray component. These ASCA data provide only the second hard X-ray spectrum of a BAL AGN presented to date. The broad-band spectral-energy-distribution of the source is discussed. While Mrk 231 is X-ray weak compared to Seyfert 1 galaxies, it has an optical-to-X-ray spectrum typical of a QSO.

T. J. Turner

1998-08-10T23:59:59.000Z

206

Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism  

NLE Websites -- All DOE Office Websites (Extended Search)

Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Print Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Print Using spectroscopic information for magnetometry and magnetic microscopy obviously requires detailed theoretical understanding of spectral shape and magnitude of dichroism signals. A research team at ALS Beamline 4.0.2 has now shown unambiguously that, contrary to common belief, spectral shape and magnitude of x-ray magnetic linear dichroism (XMLD) are not only determined by the relative orientation of magnetic moments and x-ray polarization, but their orientation relative to the crystallographic axes must be taken into account for accurate interpretation of XMLD data. Magnetism and X Rays The ancient Greeks and also the Chinese knew about strange and rare stones with the power to attract iron. Moreover, when freely suspended these objects pointed north-south. Throughout the past, we have used this phenomenon-magnetism-for navigation and more recently for power production and digital information storage, all while trying to explore and understand its origins. In 1986 researchers at a facility similar to the ALS observed for the first time that the absorption of x rays depends not only on the composition of a material-that is, if it contains iron, nickel, or other elements-but also on its magnetism. The effect is unique in that it allows us to distinguish which atomic species magnetism originates from and provides information about their local atomic environment-for example, whether a magnetic species is surrounded by 4 or 6 oxygen atoms. A research team at the ALS has now shown that the relationship between magnetic order and absorption of x rays is even more complex and exciting than has been assumed for the past 20 years, leading to a reassessment of previous results.

207

Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism  

NLE Websites -- All DOE Office Websites (Extended Search)

Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Print Unexpected Angular Dependence of X-Ray Magnetic Linear Dichroism Print Using spectroscopic information for magnetometry and magnetic microscopy obviously requires detailed theoretical understanding of spectral shape and magnitude of dichroism signals. A research team at ALS Beamline 4.0.2 has now shown unambiguously that, contrary to common belief, spectral shape and magnitude of x-ray magnetic linear dichroism (XMLD) are not only determined by the relative orientation of magnetic moments and x-ray polarization, but their orientation relative to the crystallographic axes must be taken into account for accurate interpretation of XMLD data. Magnetism and X Rays The ancient Greeks and also the Chinese knew about strange and rare stones with the power to attract iron. Moreover, when freely suspended these objects pointed north-south. Throughout the past, we have used this phenomenon-magnetism-for navigation and more recently for power production and digital information storage, all while trying to explore and understand its origins. In 1986 researchers at a facility similar to the ALS observed for the first time that the absorption of x rays depends not only on the composition of a material-that is, if it contains iron, nickel, or other elements-but also on its magnetism. The effect is unique in that it allows us to distinguish which atomic species magnetism originates from and provides information about their local atomic environment-for example, whether a magnetic species is surrounded by 4 or 6 oxygen atoms. A research team at the ALS has now shown that the relationship between magnetic order and absorption of x rays is even more complex and exciting than has been assumed for the past 20 years, leading to a reassessment of previous results.

208

X-RAY PROPERTIES OF PREMAIN-SEQUENCE STARS IN THE ORION NEBULA CLUSTER WITH KNOWN ROTATION PERIODS  

E-Print Network (OSTI)

X-RAY PROPERTIES OF PRE­MAIN-SEQUENCE STARS IN THE ORION NEBULA CLUSTER WITH KNOWN ROTATION PERIODS Nebula Cluster (ONC) to study the X-ray properties of a large sample of pre­main-sequence (PMS) stars with optically determined rotation periods. Our goal is to elucidate the origins of X-rays in PMS stars

Barsony, Mary

209

Hard x-ray imaging from explorer  

SciTech Connect

Coded aperture X-ray detectors were applied to obtain large increases in sensitivity as well as angular resolution. A hard X-ray coded aperture detector concept is described which enables very high sensitivity studies persistent hard X-ray sources and gamma ray bursts. Coded aperture imaging is employed so that approx. 2 min source locations can be derived within a 3 deg field of view. Gamma bursts were located initially to within approx. 2 deg and X-ray/hard X-ray spectra and timing, as well as precise locations, derived for possible burst afterglow emission. It is suggested that hard X-ray imaging should be conducted from an Explorer mission where long exposure times are possible.

Grindlay, J.E.; Murray, S.S.

1981-11-01T23:59:59.000Z

210

Development of x-ray photoelectron microscope with an x-ray laser source  

Science Journals Connector (OSTI)

We have constructed an x-ray photoelectron microscopic system with an x-ray laser as an x-ray source. The lasing line is the Li-like Al 3d-4f transition at 15.47 nm where the recombining Al plasma is used as the x-ray laser medium. The beam from the x-ray laser cavity was then focused by using a Schwarzschild mirror coated with Mo/Si multilayers. The x-ray beam size with a diameter less than 0.5 ?m and the estimated photon number of about 2×10 6 ? photons/shot into the spot were achieved.

Tadayuki Ohchi; Naohiro Yamaguchi; Chiemi Fujikawa; Tamio Hara; Katsumi Watanabe; Ibuki Tanaka; Masami Taguchi

2000-01-01T23:59:59.000Z

211

Flow method and apparatus for screening chemicals using micro x-ray fluorescence  

DOE Patents (OSTI)

Method and apparatus for screening chemicals using micro x-ray fluorescence. A method for screening a mixture of potential pharmaceutical chemicals for binding to at least one target binder involves flow-separating a solution of chemicals and target binders into separated components, exposing them to an x-ray excitation beam, detecting x-ray fluorescence signals from the components, and determining from the signals whether or not a binding event between a chemical and target binder has occurred.

Warner, Benjamin P. (Los Alamos, NM); Havrilla, George J. (Los Alamos, NM); Miller, Thomasin C. (Bartlesville, OK); Lewis, Cris (Los Alamos, NM); Mahan, Cynthia A. (Los Alamos, NM); Wells, Cyndi A. (Los Alamos, NM)

2009-04-14T23:59:59.000Z

212

Applications of soft x-ray lasers  

SciTech Connect

The high brightness and short pulse duration of soft x-ray lasers provide unique advantages for novel applications. Imaging of biological specimens using x-ray lasers has been demonstrated by several groups. Other applications to fields such as chemistry, material science, plasma diagnostics, and lithography are beginning to emerge. We review the current status of soft x-ray lasers from the perspective of applications, and present an overview of the applications currently being developed.

Skinner, C.H.

1993-08-01T23:59:59.000Z

213

High speed x-ray beam chopper  

DOE Patents (OSTI)

A fast, economical, and compact x-ray beam chopper with a small mass and a small moment of inertia whose rotation can be synchronized and phase locked to an electronic signal from an x-ray source and be monitored by a light beam is disclosed. X-ray bursts shorter than 2.5 microseconds have been produced with a jitter time of less than 3 ns.

McPherson, Armon (Oswego, IL); Mills, Dennis M. (Naperville, IL)

2002-01-01T23:59:59.000Z

214

In situ characterization of AIPO-14 using synchrotron powder diffraction.  

SciTech Connect

The separation of propane/propylene mixtures is an important yet difficult industrial process that can be accomplished by a pressure swing adsorption process using AlPO-14 as the adsorbent. Although the AlPO-14 structure has been studied with different techniques, the detailed structure under conditions of the adsorption process has not been clarified. We have used synchrotron x-ray powder diffraction and an in situ reactor system to obtain detailed structural information of AlPO-14 with the Rietvield method. Molecular modeling using the structural data allowed determination of the diffusion path of propylene in AlPO-14. The design of the in situ reactor system allows different chemicals to be loaded and the system to be heated and pressurized up to 90 psi with various gases or liquids. For this work, AlPO-14 powder was loaded into a 1 mm capillary tube and attached to the cell. Diffraction scans were collected during treatments in nitrogen, propane and propylene at various temperatures up to 300 C and various pressures up to 90 psig. A selected region of the x-ray diffraction patterns under different experimental conditions is shown in Fig.1. The diffraction patterns for AlPO-14 in nitrogen and propane are very similar, whereas the pattern in propylene changes considerably suggesting structure changes caused by adsorption of propylene into the pores.

Yang, N.; Greenlay, N.; Karapetrova, J.; Zschack, P.; Gatter, M.; Wilson, S.; Broach, R. W.; Experimental Facilities Division (APS); UOP

2006-01-01T23:59:59.000Z

215

X-ray laser frequency near-doubling and generation of tunable coherent x rays in plasma  

E-Print Network (OSTI)

X-ray laser frequency near-doubling and generation of tunable coherent x rays in plasma P. L plasmas in which efficient x-ray laser frequency near-doubling is expected for a number of available x-ray of coherent x rays and tunable optical radiation may result in tunable coherent x-ray radiation powerful

Kaplan, Alexander

216

Determination of the moisture content in wood chips of Scots pine and Norway spruce using Mantex Desktop Scanner based on dual energy X-ray absorptiometry  

Science Journals Connector (OSTI)

Several studies have attempted to develop and evaluate other methods, such as radio frequency and near infrared, that could quickly and accurately determine the MC of wood chips; none of them have been truly s...

Mikael Hultnäs; Victor Fernandez-Cano

2012-08-01T23:59:59.000Z

217

Standard test method for determination of bromine and chlorine in UF6 and uranyl nitrate by X-Ray fluorescence (XRF) spectroscopy  

E-Print Network (OSTI)

1.1 This method covers the determination of bromine (Br) and chlorine (Cl) in uranium hexafluoride (UF6) and uranyl nitrate solution. The method as written covers the determination of bromine in UF6 over the concentration range of 0.2 to 8 ?g/g, uranium basis. The chlorine in UF6 can be determined over the range of 4 to 160 ?g/g, uranium basis. Higher concentrations may be covered by appropriate dilutions. The detection limit for Br is 0.2 ?g/g uranium basis and for Cl is 4 ?g/g uranium basis. 1.2 This standard may involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

218

Application of polarized neutron reflectometry and X-ray resonant magnetic reflectometry for determining the inhomogeneous magnetic structure in Fe/Gd multilayers  

Science Journals Connector (OSTI)

The evolution of the magnetic structure of multilayer [Fe (35 Å)/Gd (50 Å)5...] with variation in temperature and an applied magnetic field was determined using a complementary approach combining polarized neutron

E. A. Kravtsov; D. Haskel…

2010-10-01T23:59:59.000Z

219

Colloid Coalescence with Focused X Rays  

SciTech Connect

We show direct evidence that focused x rays enable us to merge polymer colloidal particles at room temperature. This phenomenon is ascribed to the photochemical scission of colloids with x rays, reducing the molecular weight, glass transition temperature, surface tension, and viscosity of colloids. The observation of the neck bridge growth with time shows that the x-ray-induced colloid coalescence is analogous to viscoelastic coalescence. This finding suggests a feasible protocol of photonic nanofabrication by sintering or welding of polymers, without thermal damage, using x-ray photonics.

Weon, B. M.; Kim, J. T.; Je, J. H. [X-ray Imaging Center, Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, 790-784 (Korea, Republic of); Yi, J. M. [Samsung Advanced Institute of Technology, Yongin, Gyeonggi, 446-712 (Korea, Republic of); Wang, S.; Lee, W.-K. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2011-07-01T23:59:59.000Z

220

X-RAY MICROBEAM SPEECH PRODUCTION DATABASE  

E-Print Network (OSTI)

X-RAY MICROBEAM SPEECH PRODUCTION DATABASE USER'S HANDBOOK Version 1.0 (June 1994) prepared by John . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Chapter Two: XRMB History

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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221

X-ray laser microscope apparatus  

DOE Patents (OSTI)

A microscope consisting of an x-ray contact microscope and an optical microscope. The optical, phase contrast, microscope is used to align a target with respect to a source of soft x-rays. The source of soft x-rays preferably comprises an x-ray laser but could comprise a synchrotron or other pulse source of x-rays. Transparent resist material is used to support the target. The optical microscope is located on the opposite side of the transparent resist material from the target and is employed to align the target with respect to the anticipated soft x-ray laser beam. After alignment with the use of the optical microscope, the target is exposed to the soft x-ray laser beam. The x-ray sensitive transparent resist material whose chemical bonds are altered by the x-ray beam passing through the target mater GOVERNMENT LICENSE RIGHTS This invention was made with government support under Contract No. De-FG02-86ER13609 awarded by the Department of Energy. The Government has certain rights in this invention.

Suckewer, Szymon (Princeton, NJ); DiCicco, Darrell S. (Plainsboro, NJ); Hirschberg, Joseph G. (Coral Gables, FL); Meixler, Lewis D. (East Windsor, NJ); Sathre, Robert (Princeton, NJ); Skinner, Charles H. (Lawrenceville, NJ)

1990-01-01T23:59:59.000Z

222

Automation in X-Ray Crystallography  

Science Journals Connector (OSTI)

Automation in X-Ray Crystallography ... But in the past few years, automation procedures have been applied to intrinsically superior experimental methods. ...

S.C. ABRAHAMS

1963-06-03T23:59:59.000Z

223

X-Ray Laser Sources for Microscopy  

Science Journals Connector (OSTI)

Progress and prospects in soft X-ray laser development at Princeton are presented. A comparison to plasma and synchrotron sources is made with a...

C. H. Skinner; D. E. Kim; A. Wouters; D. Voorhees; S. Suckewer

1988-01-01T23:59:59.000Z

224

Compound refractive X-ray lens  

DOE Patents (OSTI)

An apparatus and method for focusing X-rays. In one embodiment, his invention is a commercial-grade compound refractive X-ray lens. The commercial-grade compound refractive X-ray lens includes a volume of low-Z material. The volume of low-Z material has a first surface which is adapted to receive X-rays of commercially-applicable power emitted from a commercial-grade X-ray source. The volume of low-Z material also has a second surface from which emerge the X-rays of commercially-applicable power which were received at the first surface. Additionally, the commercial-grade compound refractive X-ray lens includes a plurality of openings which are disposed between the first surface and the second surface. The plurality of openings are oriented such that the X-rays of commercially-applicable power which are received at the first surface, pass through the volume of low-Z material and through the plurality openings. In so doing, the X-rays which emerge from the second surface are refracted to a focal point.

Nygren, David R. (Berkeley, CA); Cahn, Robert (Walnut Creek, CA); Cederstrom, Bjorn (Traellborg, SE); Danielsson, Mats (Stocksund, SE); Vestlund, Jonas (Stockholm, SE)

2000-01-01T23:59:59.000Z

225

X-Ray Science Division (XSD)  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Science Division (XSD) Search Button About Welcome Overview Visiting the APS Mission & Goals Find People Organization Charts Committees Job Openings User Information...

226

Ultrafast x-ray diffraction of laser-irradiated crystals  

SciTech Connect

An apparatus has been developed for measuring time-dependent x-ray diffraction. X-ray pulses from an Advanced Light Source bend magnet are diffracted by a sagittally-focusing Si(111) crystal and then by a sample crystal, presently InSb(111). Laser pulses with 100 fs duration and a repetition rate of 1 KHz irradiate the sample inducing a phase transition. Two types of detectors are being employed: an x-ray streak camera and an avalanche photodiode. The streak camera is driven by a photoconductive switch and has a 2 ps temporal resolution determined by trigger jitter. The avalanche photodiode has high quantum efficiency and sufficient time resolution to detect single x-ray pulses in ALS two bunch or camshaft operation. A beamline is under construction dedicated for time resolved and micro-diffraction experiments. In the new beamline a toroidal mirror collects 3 mrad horizontally and makes a 1:1 image of the bend magnet source in the x-ray hutch. A laser induced phase transition has been observed in InSb occurring within 70 ps.

Heimann, P.A. [Lawrence Berkeley National Lab., CA (US). Advanced Light Source; Larsson, J. [Univ. of California, Berkeley, CA (US). Physics Dept.; Chang, Z. [Univ. of Michigan, Ann Arbor, MI (US). Center for Ultrafast Optical Science

1997-09-01T23:59:59.000Z

227

Interferometric phase detection at x-ray energies via Fano resonance control  

E-Print Network (OSTI)

Modern x-ray light sources promise access to structure and dynamics of matter in largely unexplored spectral regions. However, the desired information is encoded in the light intensity and phase, whereas detectors register only the intensity. This phase problem is ubiquitous in crystallography and imaging, and impedes the exploration of quantum effects at x-ray energies. Here, we demonstrate phase-sensitive measurements characterizing the quantum state of a nuclear two-level system at hard x-ray energies. The nuclei are initially prepared in a superposition state. Subsequently, the relative phase of this superposition is interferometrically reconstructed from the emitted x-rays. Our results form a first step towards x-ray quantum state tomography, and provide new avenues for structure determination and precision metrology via x-ray Fano interference.

K. P. Heeg; C. Ott; D. Schumacher; H. -C. Wille; R. Röhlsberger; T. Pfeifer; J. Evers

2014-11-06T23:59:59.000Z

228

Explosive hydrogen burning during type I X-ray bursts  

SciTech Connect

Explosive hydrogen burning in type I X-ray bursts (XRBs) is driven by charged particle reactions creating isotopes with masses up to A {approx} 100. Since charged particle reactions in a stellar environment are very temperature sensitive, we use a realistic time-dependent general relativistic and self-consistent model of type I X-ray bursts to provide accurate values of the burst temperatures and densities. This allows a detailed and accurate time-dependent identification of the reaction flow from the surface layers through the convective region and the ignition region to the neutron star ocean. Using this, we determine the relative importance of specific nuclear reactions in the X-ray burst.

Fisker, J L; Schatz, H; Thielemann, F

2007-06-11T23:59:59.000Z

229

Experiment Hazard Class 8.3 - X-Ray Generators  

NLE Websites -- All DOE Office Websites (Extended Search)

3 - X-Ray Generators 3 - X-Ray Generators Applicability This hazard classification applies to all experiments involving the use of X-Ray Generators (other than the APS storage ring). As specified in LMS-PROC-109 a Radiation Generating Device (RGD) must be registered with the Argonne RGD Safety Officer using the ANL-847 form. The RGD will be assigned an inventory number, hazard class, RWP requirement, and inspection and survey frequencies. Experiment Category Experiments the Experiment Hazard Class are always categorized as High Risk. Experiment Hazard Control Verification Statements Engineered Controls - As determined in LMS-PROC-109. Samples chambers and all beam paths are fully enclosed by barriers. Class 2 and higher RGDs require an interlock to fail-safe beam shutter/beam stop or radiation

230

High resolution collimator system for X-ray detector  

DOE Patents (OSTI)

High resolution in an X-ray computerized tomography (CT) inspection system is achieved by using a collimator/detector combination to limit the beam width of the X-ray beam incident on a detector element to the desired resolution width. In a detector such as a high pressure Xenon detector array, a narrow tapered collimator is provided above a wide detector element. The collimator slits have any desired width, as small as a few mils at the top, the slit width is easily controlled, and they are fabricated on standard machines. The slit length determines the slice thickness of the CT image.

Eberhard, Jeffrey W. (Schenectady, NY); Cain, Dallas E. (Scotia, NY)

1987-01-01T23:59:59.000Z

231

X-ray spectroscopy of neutron star low-mass X-ray binaries  

E-Print Network (OSTI)

In this thesis, I present work spanning a variety of topics relating to neutron star lowmass X-ray binaries (LMXBs) and utilize spectral information from X-ray observations to further our understanding of these sources. ...

Krauss, Miriam Ilana

2007-01-01T23:59:59.000Z

232

Ultraluminous X-ray Sources: The most extreme X-ray binaries  

E-Print Network (OSTI)

1 Ultraluminous X-ray Sources: The most extreme X-ray binaries Luca Zampieri INAF ULXs ­ Lubiana ­ May 11, 2012- LZ #12;6 · X-ray observations of nearby galaxies show a population of pointlike, off-nuclear sources with L >> Ledd for 1 Msun (L>1.0e39 erg/s) UltraLuminous X-ray Sources (e

Â?umer, Slobodan

233

X-ray Diffraction (XRD) 1.0 What is X-ray Diffraction  

E-Print Network (OSTI)

X-ray Diffraction (XRD) · 1.0 What is X-ray Diffraction · 2.0 Basics of Crystallography · 3.0 Production of X-rays · 4.0 Applications of XRD · 5.0 Instrumental Sources of Error · 6.0 Conclusions #12 why the cleavage faces of crystals appear to reflect X-ray beams at certain angles of incidence (theta

Moeck, Peter

234

Method and apparatus for producing sharp chromatic x-ray images of x-ray emitting objects  

SciTech Connect

Method and apparatus for producing sharp, chromatic, magnified images of X-ray emitting objects, are provided. The apparatus, which constitutes an X-ray microscope or telescope, comprises a connected collection of Bragg reflecting planes, comprised of either a bent crystal or a synthetic multilayer structure, disposed on and adjacent to a locus determined by a spherical surface. The individual Bragg planes are spatially oriented to Bragg reflect radiation from the object location toward the image location. This is accomplished by making the Bragg planes spatially coincident with the surfaces of either a nested series of prolate ellipsoids of revolution, or a nested series of spheres. The spacing between the Bragg reflecting planes can be tailored to control the wavelengths and the amount of the X-radiation that is Bragg reflected to form the X-ray image. 7 figs.

Thoe, R.S.

1990-01-09T23:59:59.000Z

235

Modeling Structural Heterogeneity in Proteins From X-Ray Data  

E-Print Network (OSTI)

Modeling Structural Heterogeneity in Proteins From X-Ray Data Ankur Dhanik1 , Henry van den Bedem2: In a crystallographic experiment, a protein is precipitated to obtain a crystalline sample (crystal) containing many determination and density calculation. The protein conformation is modeled by placing the atoms in 3-D space

Pratt, Vaughan

236

Aneta Siemiginowska Chandra X-ray Center  

E-Print Network (OSTI)

-ray and gamma-ray · High Energy Sky · Chandra X-ray Observatory · examples of typical X-ray data, · an example of a data analysis process · statistical challenges · what do we learn from the data? #12;What is Astronomy and phenomena do we study and how? Solar System: Sun and sollar wind, planets, moons, asteroids, comets Our

Wolfe, Patrick J.

237

Watershed in X-ray Astronomy  

Science Journals Connector (OSTI)

... extent the article on page 96 of this issue of Nature from the X-ray astronomy group at the Massachusetts Institute of Technology is a record of disappointments. That is ... near the galactic centre. Now that the first satellite to be devoted to X-ray astronomy has been launched, and is apparently working successfully, the MIT article and another from ...

1971-01-08T23:59:59.000Z

238

An experimental measurement of metal multilayer x-ray reflectivity degradation due to intense x-ray flux  

SciTech Connect

The degradation of the x-ray reflection characteristics of metal multilayer Bragg diffractors due to intense x-ray flux was investigated. The Z-pinch plasma produced by PROTO II of Sandia National Laboratories, Albuquerque, New Mexico, was used as the source. The plasma generated total x-ray yields of as much as 40 kJ with up to 15 kJ in the neon hydrogen- and helium-like resonance lines in nominal 20-ns pulses. Molybdenum-carbon, palladium-carbon, and tungsten-carbon metal multilayers were placed at 15 and 150 cm from the plasma center. The multilayers were at nominal angles of 5/sup 0/ and 10/sup 0/ to diffract the neon resonance lines. The time-integrated x-ray reflection of the metal multilayers was monitored by x-ray film. A fluorescer-fiber optic-visible streak camera detector system was then used to monitor the time-resolved x-ray reflection characteristics of 135 A- 2d tungsten-carbon multilayers. A large specular component in the reflectivity prevented determination of the rocking curve of the multilayer. For a neon implosion onto a vanadium-doped polyacrylic acid foam target shot, detailed modeling was attempted. The spectral flux was determined with data from 5 XRD channels and deconvolved using the code SHAZAM. The observed decay in reflectivity was assumed to correspond to the melting of the first tungsten layer. A ''conduction factor'' of 82 was required to manipulate the heat loading of the first tungsten layer such that the time of melting corresponded to the observed decay. The power at destruction was 141 MW/cm/sup 2/ and the integrated energy at destruction was 2.0 J/cm/sup 2/. 82 refs., 66 figs., 10 tabs.

Hockaday, M.Y.P.

1987-06-01T23:59:59.000Z

239

Optimized Volumetric Scanning for X-Ray Array Sources  

SciTech Connect

Non-destructive evaluation (NDE) is the science and technology of determining non-invasively the internal structure of manufactured parts, objects, and materials. NDE application areas include medicine, industrial manufacturing, military, homeland security, and airport luggage screening. X-ray measurement systems are most widely used because of their ability to image through a wide range of material densities (from human tissue in medical applications to the dense materials of weapon components). Traditional x-ray systems involve a single source and detector system that rotate and/or translate about the object under evaluation. At each angular location, the source projects x-rays through the object. The rays undergo attenuation proportional to the density of the object's constitutive material. The detector records a measure of the attenuation. Mathematical algorithms are used to invert the forward attenuated ray projection process to form images of the object. This is known as computed tomography (CT). In recent years, the single-source x-ray NDE systems have been generalized to arrays of x-ray sources. Array sources permit multiple views of the object with fewer rotations and translations of the source/detector system. The spatially diverse nature of x-ray array sources has the potential of reducing data collection time, reducing imaging artifacts, and increasing the resolution of the resultant images. Most of the existing CT algorithms were not derived from array source models with a spatially diverse set of viewing perspectives. Single-source x-ray CT data collection, processing, and imaging methods and algorithms are not applicable when the source location is expanded from one dimension (a rotating and/or translating point source) to two (a rotating and/or translating array). They must be reformulated. The goal of this project is to determine the applicability of x-ray array sources to problems of interest to LLNL and its customers. It is believed array source data collection will be faster while yielding higher resolution reconstructions with fewer artifacts. There are three tasks in the research: (1) Develop forward array source analytic and computational models; (2) Research and develop array source reconstruction algorithms; and (3) Perform experiments.

Lehman, S K; Foudray, A M; Wang, A; Kallman, J S; Martz, H

2009-09-29T23:59:59.000Z

240

Quantitative Measurements of X-ray Intensity  

SciTech Connect

This chapter describes the characterization of several X-ray sources and their use in calibrating different types of X-ray cameras at National Security Technologies, LLC (NSTec). The cameras are employed in experimental plasma studies at Lawrence Livermore National Laboratory (LLNL), including the National Ignition Facility (NIF). The sources provide X-rays in the energy range from several hundred eV to 110 keV. The key to this effort is measuring the X-ray beam intensity accurately and traceable to international standards. This is accomplished using photodiodes of several types that are calibrated using radioactive sources and a synchrotron source using methods and materials that are traceable to the U.S. National Institute of Standards and Technology (NIST). The accreditation procedures are described. The chapter begins with an introduction to the fundamental concepts of X-ray physics. The types of X-ray sources that are used for device calibration are described. The next section describes the photodiode types that are used for measuring X-ray intensity: power measuring photodiodes, energy dispersive photodiodes, and cameras comprising photodiodes as pixel elements. Following their description, the methods used to calibrate the primary detectors, the power measuring photodiodes and the energy dispersive photodiodes, as well as the method used to get traceability to international standards are described. The X-ray source beams can then be measured using the primary detectors. The final section then describes the use of the calibrated X-ray beams to calibrate X-ray cameras. Many of the references are web sites that provide databases, explanations of the data and how it was generated, and data calculations for specific cases. Several general reference books related to the major topics are included. Papers expanding some subjects are cited.

Haugh, M. J., Schneider, M.

2011-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High-pressure structural studies of dysprosium using angle-dispersive x-ray diffraction  

SciTech Connect

We present structural results under pressure for elemental dysprosium (Dy) up to 87 GPa using in situ angle-dispersive x-ray diffraction measurements with synchrotron x rays and a diamond-anvil cell. Dy exhibits the structural transition sequence, hP2{yields}hR9{yields}hP4{yields}distorted cF4, from Rietveld full-profile refinements. Clear evidence is documented for the high-pressure distorted cF4 phase observed above 45 GPa to be an orthorhombic oS8 (Cmmm) structure for Dy in the lanthanide phase diagram.

Shen Yongrong; Kumar, Ravhi S.; Cornelius, Andrew L.; Nicol, Malcolm F. [Department of Physics and High Pressure Science and Engineering Center, University of Nevada Las Vegas, Las Vegas, Nevada 89154-4002 (United States)

2007-02-01T23:59:59.000Z

242

In-situ determination of energy species yields of intense particle beams  

DOE Patents (OSTI)

Objects of the present invention are provided for a particle beam having a full energy component at least as great as 25 keV, which is directed onto a beamstop target, such that Rutherford backscattering, preferably near-surface backscattering occurs. The geometry, material composition and impurity concentration of the beam stop are predetermined, using any suitable conventional technique. The energy-yield characteristic response of backscattered particles is measured over a range of angles using a fast ion electrostatic analyzer having a microchannel plate array at its focal plane. The knee of the resulting yield curve, on a plot of yield versus energy, is analyzed to determine the energy species components of various beam particles having the same mass.

Kugel, H.W.; Kaita, R.

1983-09-26T23:59:59.000Z

243

A Miniature Maxthal Furnace for X-ray Spectroscopy and Scattering Experiments up to 1200 degrees C  

SciTech Connect

We have built a new small furnace to perform high temperature studies up to 1200 deg. C in vacuum or in oxygen atmosphere. This furnace was originally used as a catalytic reactor optimized for the in situ X-ray Absorption Spectroscopy experiments on beamline ID24. It has now been redesigned for use on the ESRF beamline ID01 for in situ Grazing Incidence Small Angle X-ray Scattering experiments. For these experiments high mechanical stability of the sample holder is necessary to keep the alignment of the sample during heating.

Gorges, Bernard; Vitoux, Hugo; Redondo, Pablo; Carbone, Gerardina [ESRF, BP220 38043 Grenoble CEDEX (France); Mocouta, Cristian [SOLEIL -BP48 91192 Gif-sur-Yvette CEDEX (France); Guilera, Gemma [ALBA CELLS 08290 Cerdanoyla Del Valles Barcelona (Spain)

2010-06-23T23:59:59.000Z

244

High-Resolution X-ray Imaging of the Colliding Wind Shock in WR147  

E-Print Network (OSTI)

We analyze new high-resolution Chandra X-ray images of the Wolf-Rayet binary system WR147. This system contains a WN8 star with an early-type companion located 0.6'' to its north, and is the only known early-type binary with a separation on the sky large enough for the wind-wind collision between the stars to currently be resolved at X-ray energies. The 5 ksec Chandra HRC-I image provides the first direct evidence for spatially extended X-ray emission in an early-type binary system. The X-ray emission peaks close to the position of the radio bow shock and north of the WN8 star. A deeper X-ray image is needed to accurately determine the degree of spatial extension, to exactly align the X-ray and optical/radio frames, and to determine whether part of the detected X-ray emission arises in the individual stellar winds. Simulated X-ray images of the wind-wind collision have a FWHM consistent with the data, and maximum likelihood fits suggest that a deeper observation may also constrain the inclination and wind momentum ratio of this system. However, as the WR wind dominates the colliding wind X-ray emission it appears unlikely that the mass-loss rate and the terminal velocity of the companion wind can be separately determined from X-ray observations. We also note an inconsistency between numerical and analytical estimates of the X-ray luminosity ratio of the stronger and weaker wind components, and conclude that the analytical results are in error.

J. M. Pittard; I. R. Stevens; P. M. Williams; A. M. T. Pollock; S. L. Skinner; M. F. Corcoran; A. F. J. Moffat

2002-04-12T23:59:59.000Z

245

X-ray Practicals Series 1 Advanced Data Reduction  

E-Print Network (OSTI)

X-ray Practicals Series 1 Advanced Data Reduction Instructor J. Reibenspies, Ph. D. Nattamai Bhuvanesh, Ph.D. Version 1.0.0 #12;X-ray Practicals Series 2 #12;X-ray Practicals Series 3 #12;X-ray is good. The y direction is shifting the most, but the shift is ok #12;X-ray Practicals Series 5 Other

Meagher, Mary

246

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

Lensless X-Ray Imaging in Lensless X-Ray Imaging in Reflection Lensless X-Ray Imaging in Reflection Print Wednesday, 26 October 2011 00:00 The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs combine the advantages of sychrotron light sources (high brightness and x-ray wavelengths relevant to atomic and molecular phenomena) with the advantages of visible-light lasers (highly coherent beams). All of these characteristics are important for coherent x-ray diffraction imaging-lensless imaging techniques that are proving to be integral to single-shot, high-resolution imaging of both complex materials and biological samples. Existing techniques are typically designed for transmission geometry, however, and use isolated objects, requiring special sample fabrication and restricting the type of samples under investigation. Recently, researchers from the ALS and the University of Oregon have shown at ALS Beamline 12.0.2 that it is possible to form x-ray holograms in reflection geometry by using the light scattered from a sample, opening the door to lensless imaging of a wealth of new material samples.

247

X-ray sources in globular clusters  

E-Print Network (OSTI)

The twelve bright (Lx>10(36) erg/s) X-ray sources in the globular clusters have lower luminosities than the brightest sources in the bulge of our galaxy. The dim (Lx<10(35) erg/s) X-ray sources in globular clusters reach higher luminosities than the cataclysmic variables in the disk of our galaxy. The first difference is a statistical fluke, as comparison with M31 indicates. The second difference is explained because the brightest of the dim sources are not cataclysmic variables, but soft X-ray transients in quiescence. This article describes the BeppoSAX, ROSAT and first Chandra observations leading to these conclusions.

Frank Verbunt

2001-11-22T23:59:59.000Z

248

X-RAY EMISSION FROM PLANETS AND COMETS: RELATIONSHIP WITH SOLAR X-RAYS AND SOLAR WIND  

E-Print Network (OSTI)

with the occurrence of solar X-ray flare, when light travel time delay is accounted, suggesting that X-rays fromX-RAY EMISSION FROM PLANETS AND COMETS: RELATIONSHIP WITH SOLAR X-RAYS AND SOLAR WIND ANIL BHARDWAJ Flight center, Greenbelt, MD 20771, USA Scattering of solar X-ray radiation mainly produces the non

Ã?stgaard, Nikolai

249

X-Ray Diffraction The X-Ray Diffraction facility is equipped with state-of-the-art  

E-Print Network (OSTI)

X-Ray Diffraction The X-Ray Diffraction facility is equipped with state-of-the-art diffractometers offering both single crystal and powder X-Ray diffraction. Powder X-Ray Diffraction High resolution data For more details on powder X-Ray analysis contact Dr J Hriljac on 0121 414 4458 or email: j

Birmingham, University of

250

Novel X-Ray Imaging Opportunities for the RPI Linear Accelerator's Tunable, Quasi-monochromatic X-ray Source  

E-Print Network (OSTI)

Novel X-Ray Imaging Opportunities for the RPI Linear Accelerator's Tunable, Quasi-monochromatic X-ray of an intense, tunable, polarized, and quasi-monochromatic X-ray source has been ongoing at Rensselaer Polytechnic Institute since 2001 [1, 2, 3, 4, 5, 6]. This X-ray source, known as Parametric X-rays (PXR

Danon, Yaron

251

X-ray absorption and resonant x-ray emission spectra by electric quadrupole excitation in light rare-earth systems  

Science Journals Connector (OSTI)

We have made precise theoretical calculations for both 2p3/2?4f x-ray absorption spectra and 3d?2p3/2 resonant x-ray emission spectra involving electric quadrupole excitations at the L3 edge of light rare-earth elements from La to Eu. It is shown that the energy separation of a double-peak structure observed by x-ray absorption spectroscopy (XAS) does not agree with that determined from resonant x-ray emission spectroscopy (RXES), in contrast to recent experimental results by Bartolomé et al. The reason for this difference is that the energy separation in XAS is determined by the 4f-4f interaction only, while that in RXES is determined by both 4f-4f and 3d-4f interactions.

M. Nakazawa; K. Fukui; H. Ogasawara; A. Kotani; C. F. Hague

2002-09-26T23:59:59.000Z

252

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network (OSTI)

308, Messer, B. M. X-ray Absorption Spectroscopy of AqueousSarcosine via X-ray Absorption Spectroscopy 5.1 Introductionwith Carboxylate by X-Ray Absorption Spectroscopy of Liquid

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

253

Compact X-Ray Light Source Workshop | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Compact X-Ray Light Source Workshop Compact X-Ray Light Source Workshop Teller R, Terminello L, Thevuthasan T, Moncton D. 2012. "Compact X-Ray Light Source Workshop Report."...

254

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Biological Imaging by Soft X-Ray Diffraction Microscopy Print Wednesday, 30 November 2005 00:00 Electron and x-ray...

255

ROSAT All-Sky Survey observations of IRAS galaxies; I. Soft X-ray and far-infrared properties  

E-Print Network (OSTI)

The 120,000 X-ray sources detected in the RASS II processing of the ROSAT All-Sky Survey are correlated with the 14,315 IRAS galaxies selected from the IRAS Point Source Catalogue: 372 IRAS galaxies show X-ray emission within a distance of 100 arcsec from the infrared position. By inspecting the structure of the X-ray emission in overlays on optical images we quantify the likelihood that the X-rays originate from the IRAS galaxy. For 197 objects the soft X-ray emission is very likely associated with the IRAS galaxy. Their soft X-ray properties are determined and compared with their far-infrared emission. X-ray contour plots overlaid on Palomar Digitized Sky Survey images are given for each of the 372 potential identifications. All images and tables displayed here are also available in electronic form.

Th. Boller; F. Bertoldi; M. Dennefeld; W. Voges

1997-10-16T23:59:59.000Z

256

Calibration of X-ray Imaging Devices for Accurate Intensity Measurement  

SciTech Connect

National Security Technologies (NSTec) has developed calibration procedures for X-ray imaging systems using NIST traceable sources. The X-ray sources that are used for calibration are both diode type and diode/fluorescer combinations. Calibrating the X-ray detectors is the key to accurate calibration of the X-ray sources. Both energy dispersive detectors and photodiodes measuring total flux were used. We have developed calibration techniques for the detectors using radioactive sources that are traceable to the National Institute of Standards and Technology (NIST). The German synchrotron at Physikalische Technische Bundestalt (PTB) is used to calibrate silicon photodiodes over the energy range from 50 eV to 60 keV. The measurements on X-ray cameras made using the NSTec X-ray sources have included the quantum efficiency averaged over all pixels, the camera counts per photon per pixel, and response variation across the sensor. The instrumentation required to accomplish the calibrations is described. X-ray energies ranged from 720 eV to 22.7 keV. The X-ray sources produce narrow energy bands, allowing us to determine the properties as a function of X-ray energy. The calibrations were done for several types of imaging devices. There were back illuminated and front illuminated CCD (charge coupled device) sensors, and a CID (charge injection device) type camera. The CCD and CID camera types differ significantly in some of their properties that affect the accuracy of X-ray intensity measurements. All cameras discussed here are silicon based. The measurements of quantum efficiency variation with X-ray energy are compared to models for the sensor structure. Cameras that are not back-thinned are compared to those that are.

Haugh, M. J., Charest, M., Ross, P., Lee, J. Schneider, M., Palmer, N., Teruya,

2012-06-01T23:59:59.000Z

257

APS Bending Magnet X-rays and  

NLE Websites -- All DOE Office Websites (Extended Search)

Irradiation of Nd-Fe-B Permanent Magnets with Irradiation of Nd-Fe-B Permanent Magnets with APS Bending Magnet X-rays and 60 Co γ-rays J. Alderman and P.K. Job APS Operations Division Advanced Photon Source J. Puhl Ionizing Radiation Division National Institute of Standards and Technology June 2000 Table of Contents Introduction Radiation-Induced Demagnetization of Permanent Magnets Resources Required γ-ray Irradiation Results and Analysis of γ-ray Irradiation X-ray Irradiation Results and Analysis of X-ray Irradiation Summary and Conclusions Acknowledgements References Tables and Figures Introduction The Advanced Photon Source (APS), as well as other third-generation synchrotron light sources, uses permanent magnets in the insertion devices to produce x-rays for scientific

258

X-ray source for mammography  

DOE Patents (OSTI)

An x-ray source utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms.

Logan, Clinton M. (Pleasanton, CA)

1994-01-01T23:59:59.000Z

259

Ultrafast X-Ray Sources and Science  

Science Journals Connector (OSTI)

X-ray science is entering the ultrafast and ultraintense era - spurred by developments in coherent, short-wavelength sources that range from tabletop to accelerator-based. These...

Young, Linda

260

X-ray induced optical reflectivity  

The change in optical reflectivity induced by intense x-ray pulses can now be used to study ultrafast many body responses in solids in the femtosecond time domain. X-ray absorption creates photoelectrons and core level holes subsequently filled by Auger or fluorescence processes, and these excitations ultimately add conduction and valence band carriers that perturb optical reflectivity.Optical absorption associated with band filling and band gap narrowing is shown to explain the basic features found in recent measurements on an insulator (silicon nitride, Si3N4), a semiconductor(gallium arsenide,GaAs), and a metal (gold,Au), obtained with ?100 fs x-ray pulses at 500-2000 eV and probed with 800 nm laser pulses. In particular GaAs exhibits an abrupt drop in reflectivity, persisting only for a time comparable to the x-ray excitation pulse duration, consistent with prompt band gap narrowing.

Durbin, Stephen M.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

SMB, X-ray Emission Spectroscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Emission Spectroscopy Beam Line 6-2b X-ray Emission Spectroscopy Beam Line 6-2b is an advanced spectroscopy experimental station on the multidisciplinary general user wiggler Beam...

262

X-raying galaxies: A Chandra legacy  

Science Journals Connector (OSTI)

...Astronomy, University of Massachusetts, Amherst, MA 01003 This presentation...stellar x-ray sources in the solar neighborhood (8). The...elements—Meteoritic and solar . Geochim Cosmochim Acta 53...Astronomy, University of Massachusetts, Amherst, MA 01003, USA...

Q. Daniel Wang

2010-01-01T23:59:59.000Z

263

Small Angle X-Ray Scattering Detector  

DOE Patents (OSTI)

A detector for time-resolved small-angle x-ray scattering includes a nearly constant diameter, evacuated linear tube having an end plate detector with a first fluorescent screen and concentric rings of first fiber optic bundles for low angle scattering detection and an annular detector having a second fluorescent screen and second fiber optic bundles concentrically disposed about the tube for higher angle scattering detection. With the scattering source, i.e., the specimen under investigation, located outside of the evacuated tube on the tube's longitudinal axis, scattered x-rays are detected by the fiber optic bundles, to each of which is coupled a respective photodetector, to provide a measurement resolution, i.e., dq/q, where q is the momentum transferred from an incident x-ray to an x-ray scattering specimen, of 2% over two (2) orders of magnitude in reciprocal space, i.e., qmax/qmin approx=lO0.

Hessler, Jan P.

2004-06-15T23:59:59.000Z

264

X-Ray Nanoimaging: Instruments and Methods  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Nanoimaging: Instruments and Methods To be held as part of SPIE. http:spie.orgOP318 August 28-29, 2013; San Diego, California, USA...

265

Femtosecond X-ray protein nanocrystallography  

NLE Websites -- All DOE Office Websites (Extended Search)

Femtosecond X-ray protein nanocrystallography Authors: Chapman, H.N., Fromme, P., Barty, A., White, T.A., Kirian, R.A., Aquila, A., Hunter, M.S., Schulz, J., DePonte, D.P.,...

266

X-ray source for mammography  

DOE Patents (OSTI)

An x-ray source is described utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms. 6 figures.

Logan, C.M.

1994-12-20T23:59:59.000Z

267

Overview of the ARGOS X-ray framing camera for Laser MegaJoule  

SciTech Connect

Commissariat à l’Énergie Atomique et aux Énergies Alternatives has developed the ARGOS X-ray framing camera to perform two-dimensional, high-timing resolution imaging of an imploding target on the French high-power laser facility Laser MegaJoule. The main features of this camera are: a microchannel plate gated X-ray detector, a spring-loaded CCD camera that maintains proximity focus in any orientation, and electronics packages that provide remotely-selectable high-voltages to modify the exposure-time of the camera. These components are integrated into an “air-box” that protects them from the harsh environmental conditions. A miniaturized X-ray generator is also part of the device for in situ self-testing purposes.

Trosseille, C., E-mail: clement.trosseille@cea.fr; Aubert, D.; Auger, L.; Bazzoli, S.; Brunel, P.; Burillo, M.; Chollet, C.; Jasmin, S.; Maruenda, P.; Moreau, I.; Oudot, G.; Raimbourg, J.; Soullié, G.; Stemmler, P.; Zuber, C. [CEA, DAM, DIF, F-91297 Arpajon (France); Beck, T. [CEA, DEN, CADARACHE, F-13108 St Paul lez Durance (France); Gazave, J. [CEA, DAM, CESTA, F-33116 Le Barp (France)

2014-11-15T23:59:59.000Z

268

Research and Design of a Sample Heater for Beam Line 6-2c Transmission X-ray Microscope  

SciTech Connect

There exists a need for environmental control of samples to be imaged by the Transmission X-Ray Microscope (TXM) at the SSRLs Beam Line 6-2c. In order to observe heat-driven chemical or morphological changes that normally occur in situ, microscopes require an additional component that effectively heats a given sample without heating any of the microscope elements. The confinement of the heat and other concerns about the heaters integrity limit which type of heater is appropriate for the TXM. The bulk of this research project entails researching different heating methods used previously in microscopes, but also in other industrial applications, with the goal of determining the best-fitting method, and finally in designing a preliminary sample heater.

Policht, Veronica; /Loyola U., Chicago /SLAC

2012-08-27T23:59:59.000Z

269

Using X-Ray Computed Tomography in Pore Structure Characterization...  

NLE Websites -- All DOE Office Websites (Extended Search)

Using X-Ray Computed Tomography in Pore Structure Characterization for a Berea Sandstone: Resolution Effect. Using X-Ray Computed Tomography in Pore Structure Characterization for...

270

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Imaging in Reflection Print X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs combine the advantages of sychrotron light sources (high brightness and x-ray wavelengths relevant to atomic and molecular phenomena) with the advantages of visible-light lasers (highly coherent beams). All of these characteristics are important for coherent x-ray diffraction imaging-lensless imaging techniques that are proving to be integral to single-shot, high-resolution imaging of both complex materials and biological samples. Existing techniques are typically designed for transmission geometry, however, and use isolated objects, requiring special sample fabrication and restricting the type of samples under investigation. Recently, researchers from the ALS and the University of Oregon have shown at ALS Beamline 12.0.2 that it is possible to form x-ray holograms in reflection geometry by using the light scattered from a sample, opening the door to lensless imaging of a wealth of new material samples.

271

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Imaging in Reflection Print X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs combine the advantages of sychrotron light sources (high brightness and x-ray wavelengths relevant to atomic and molecular phenomena) with the advantages of visible-light lasers (highly coherent beams). All of these characteristics are important for coherent x-ray diffraction imaging-lensless imaging techniques that are proving to be integral to single-shot, high-resolution imaging of both complex materials and biological samples. Existing techniques are typically designed for transmission geometry, however, and use isolated objects, requiring special sample fabrication and restricting the type of samples under investigation. Recently, researchers from the ALS and the University of Oregon have shown at ALS Beamline 12.0.2 that it is possible to form x-ray holograms in reflection geometry by using the light scattered from a sample, opening the door to lensless imaging of a wealth of new material samples.

272

Argonne CNM: X-Ray Microscopy Capabilities  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Microscopy Facilities X-Ray Microscopy Facilities The Hard X-Ray Nanoprobe (HXN) facility provides scanning fluorescence, scanning diffraction, and full-field transmission and tomographic imaging capabilities with a spatial resolution of 30 nm over a spectral range of 6-12 keV. Modes of Operation Full-Field Transmission Imaging and Nanotomography X-ray transmission imaging uses both the absorption and phase shift of the X-ray beam by the sample as contrast mechanisms. Absorption contrast is used to map the sample density. Elemental constituents can be located by using differential edge contrast in this mode. Phase contrast can be highly sensitive to edges and interfaces even when the X-ray absorption is weak. These contrast mechanisms are exploited to image samples rapidly in full-field transmission mode under various environmental conditions, or combined with nanotomography methods to study the three-dimensional structure of complex and amorphous nanomaterials with the HXN.

273

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

Lensless X-Ray Imaging in Reflection Print Lensless X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs combine the advantages of sychrotron light sources (high brightness and x-ray wavelengths relevant to atomic and molecular phenomena) with the advantages of visible-light lasers (highly coherent beams). All of these characteristics are important for coherent x-ray diffraction imaging-lensless imaging techniques that are proving to be integral to single-shot, high-resolution imaging of both complex materials and biological samples. Existing techniques are typically designed for transmission geometry, however, and use isolated objects, requiring special sample fabrication and restricting the type of samples under investigation. Recently, researchers from the ALS and the University of Oregon have shown at ALS Beamline 12.0.2 that it is possible to form x-ray holograms in reflection geometry by using the light scattered from a sample, opening the door to lensless imaging of a wealth of new material samples.

274

The Constellation X-ray mission  

Science Journals Connector (OSTI)

The Constellation-X mission is a large collecting area X-ray facility, emphasizing observations at high spectral resolution (E/?E?300–3000) while covering a broad energy band (0.25–40 keV). By increasing the telescope aperture and utilizing efficient spectrometers the mission will achieve a factor of 100 increased sensitivity over current high-resolution X-ray spectroscopy missions. The use of focussing optics across the 10–40 keV band will provide a similar factor of 100 increased sensitivity in this band. Key technologies under development for the mission include lightweight high throughput X-ray optics, multilayer coatings to enhance the hard X-ray performance of X-ray optics, micro-calorimeter spectrometer arrays with 2 eV resolution, low-power and low-weight CCD arrays, lightweight gratings and hard X-ray detectors. When observations commence towards the end of the next decade, Constellation-X will address many pressing questions concerning the extremes of gravity and the evolution of the Universe.

N.E White; H Tananbaum

1999-01-01T23:59:59.000Z

275

X-Ray Observations of Radio Galaxies  

E-Print Network (OSTI)

We review some of the ways that X-ray observations provide unique information on radio galaxies. Thermal bremsstrahlung X-ray emission provides detailed data on ambient densities and temperatures. These parameters in turn can be used for pressure balance calculations and can demonstrate how the ambient gas affects radio source structure. Additionally, many signatures of the interaction of radio jets and lobes with the hot gas are found in high resolution X-ray maps. Non-thermal X-ray emission from knots and hotspots of radio jets can give us constraints on the relativistic electron population for energies greater that that normally sampled in the radio (in the case of synchrotron emission) or can give us an independent estimate of the average magnetic field strength (if inverse Compton emission is the origin of the X-rays). From recent ROSAT HRI observations of 3C 390.3 and 3C 120, we show evidence that X-ray emission from knots and hotspots appears to be associated with regions of large gradients in the radio surface brightness; i.e. at the location of powerful shocks.

D. E. Harris

1998-04-20T23:59:59.000Z

276

Compton backscattered collimated x-ray source  

DOE Patents (OSTI)

A high-intensity, inexpensive and collimated x-ray source is disclosed for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications. 4 figs.

Ruth, R.D.; Huang, Z.

1998-10-20T23:59:59.000Z

277

Compton backscattered collmated X-ray source  

DOE Patents (OSTI)

A high-intensity, inexpensive and collimated x-ray source for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications.

Ruth, Ronald D. (Woodside, CA); Huang, Zhirong (Stanford, CA)

2000-01-01T23:59:59.000Z

278

Compton backscattered collimated x-ray source  

DOE Patents (OSTI)

A high-intensity, inexpensive and collimated x-ray source for applications such as x-ray lithography is disclosed. An intense pulse from a high power laser, stored in a high-finesse resonator, repetitively collides nearly head-on with and Compton backscatters off a bunched electron beam, having relatively low energy and circulating in a compact storage ring. Both the laser and the electron beams are tightly focused and matched at the interaction region inside the optical resonator. The laser-electron interaction not only gives rise to x-rays at the desired wavelength, but also cools and stabilizes the electrons against intrabeam scattering and Coulomb repulsion with each other in the storage ring. This cooling provides a compact, intense bunch of electrons suitable for many applications. In particular, a sufficient amount of x-rays can be generated by this device to make it an excellent and flexible Compton backscattered x-ray (CBX) source for high throughput x-ray lithography and many other applications.

Ruth, Ronald D. (Woodside, CA); Huang, Zhirong (Stanford, CA)

1998-01-01T23:59:59.000Z

279

Lensless X-Ray Imaging in Reflection  

NLE Websites -- All DOE Office Websites (Extended Search)

Lensless X-Ray Imaging in Reflection Print Lensless X-Ray Imaging in Reflection Print The advent of x-ray free-electron laser (XFEL) light sources has led to an outburst of research activities in the field of lensless imaging. XFELs combine the advantages of sychrotron light sources (high brightness and x-ray wavelengths relevant to atomic and molecular phenomena) with the advantages of visible-light lasers (highly coherent beams). All of these characteristics are important for coherent x-ray diffraction imaging-lensless imaging techniques that are proving to be integral to single-shot, high-resolution imaging of both complex materials and biological samples. Existing techniques are typically designed for transmission geometry, however, and use isolated objects, requiring special sample fabrication and restricting the type of samples under investigation. Recently, researchers from the ALS and the University of Oregon have shown at ALS Beamline 12.0.2 that it is possible to form x-ray holograms in reflection geometry by using the light scattered from a sample, opening the door to lensless imaging of a wealth of new material samples.

280

Development of x-ray laminography under an x-ray microscopic condition  

SciTech Connect

An x-ray laminography system under an x-ray microscopic condition was developed to obtain a three-dimensional structure of laterally-extended planar objects which were difficult to observe by x-ray tomography. An x-ray laminography technique was introduced to an x-ray transmission microscope with zone plate optics. Three prototype sample holders were evaluated for x-ray imaging laminography. Layered copper grid sheets were imaged as a laminated sample. Diatomite powder on a silicon nitride membrane was measured to confirm the applicability of this method to non-planar micro-specimens placed on the membrane. The three-dimensional information of diatom shells on the membrane was obtained at a spatial resolution of sub-micron. Images of biological cells on the membrane were also obtained by using a Zernike phase contrast technique.

Hoshino, Masato; Uesugi, Kentaro; Takeuchi, Akihisa; Suzuki, Yoshio; Yagi, Naoto [Japan Synchrotron Radiation Research Institute JASRI/SPring-8, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)

2011-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

X-ray views of neutron star low-mass X-ray binaries  

E-Print Network (OSTI)

A neutron star low-mass X-ray binary is a binary stellar system with a neutron star and a low-mass companion star rotating around each other. In this system the neutron star accretes mass from the companion, and as this matter falls into the deep potential well of the neutron star, the gravitational potential energy is released primarily in the X-ray wavelengths. Such a source was first discovered in X-rays in 1962, and this discovery formally gave birth to the "X-ray astronomy". In the subsequent decades, our knowledge of these sources has increased enormously by the observations with several X-ray space missions. Here we give a brief overview of our current understanding of the X-ray observational aspects of these systems.

Sudip Bhattacharyya

2010-02-24T23:59:59.000Z

282

Surface Slope Metrology on Deformable Soft X-ray Mirrors  

SciTech Connect

We report on the current state of surface slope metrology on deformable mirrors for soft x-rays at the Advanced Light Source (ALS). While we are developing techniques for in situ at-wavelength tuning, we are refining methods of ex situ visible-light optical metrology to achieve sub-100-nrad accuracy. This paper reports on laboratory studies, measurements and tuning of a deformable test-KB mirror prior to its use. The test mirror was bent to a much different optical configuration than its original design, achieving a 0.38 micro-radian residual slope error. Modeling shows that in some cases, by including the image conjugate distance as an additional free parameter in the alignment, along with the two force couples, fourth-order tangential shape errors (the so-called bird shape) can be reduced or eliminated.

Yuan Sheng; Yashchuk, Valeriy V.; Celestre, Rich; Church, Matthew; McKinney, Wayne R.; Morrison, Greg; Warwick, Tony [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Goldberg, Kenneth A. [Center for X-ray Optics, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

2010-06-23T23:59:59.000Z

283

The World's First Free-Electron X-ray Laser | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

First Free-Electron X-ray Laser First Free-Electron X-ray Laser The World's First Free-Electron X-ray Laser August 17, 2010 - 6:19pm Addthis The World's First Free-Electron X-ray Laser John Schueler John Schueler Former New Media Specialist, Office of Public Affairs Yesterday, Secretary Chu participated in the dedication of the world's first free-electron and most powerful X-ray laser, the Linac Coherent Light Source (LCLS). In light of this occasion (pun intended), we posted an in-depth look at the innovative nature of this new instrument and its potential to tackle some of life's biggest mysteries. The Secretary seemed just as geeked about the possibilities of the LCLS, stating that "this is a new instrument that will enable us to see the structure of materials that we could not determine by any other means ... Knowing those

284

Portable chamber for the study of UHV prepared electrochemical interfaces by hard x-ray diffraction  

SciTech Connect

We report on a new electrochemical cell setup, combined with a portable UHV chamber, for in situ x-ray diffraction using synchrotron radiation. In contrast to more traditional electrochemical sample preparation schemes, atomically clean and well-ordered surfaces are routinely prepared by UHV methods, even in the case of reactive elements or alloys. Samples can be transferred from larger UHV systems into the portable chamber without exposure to ambient air. They can then be studied successively in UHV, in controlled gas atmospheres, and in contact with electrolyte solutions under applied electrochemical potential. The electrochemical setup employs a droplet geometry, which guarantees good electrochemical conditions during in situ x-ray measurements combined with voltammetry. We present first experimental results of Cu deposition on GaAs(001) and on freshly produced nanometric Pd(001) islands on Cu{sub 0.83}Pd{sub 0.17}(001), respectively.

Renner, Frank Uwe; Gruender, Yvonne; Zegenhagen, Joerg [European Synchrotron Radiation Facility, BP 220, 38043 Grenoble (France)

2007-03-15T23:59:59.000Z

285

Human genome sequencing with direct x-ray holographic imaging. Final report  

SciTech Connect

Direct holographic imaging of biological materials is widely applicable to the study of the structure, properties and action of genetic material. This particular application involves the sequencing of the human genome where prospective genomic imaging technology is composed of three subtechnologies, name an x-ray holographic camera, suitable chemistry and enzymology for the preparation of tagged DNA samples, and the illuminator in the form of an x-ray laser. We report appropriate x-ray camera, embodied by the instrument developed by MCR, is available and that suitable chemical and enzymatic procedures exist for the preparation of the necessary tagged DNA strands. Concerning the future development of the x-ray illuminator. We find that a practical small scale x-ray light source is indeed feasible. This outcome requires the use of unconventional physical processes in order to achieve the necessary power-compression in the amplifying medium. The understanding of these new physical mechanisms is developing rapidly. Importantly, although the x-ray source does not currently exist, the understanding of these new physical mechanisms is developing rapidly and the research has established the basic scaling laws that will determine the properties of the x-ray illuminator. When this x-ray source becomes available, an extremely rapid and cost effective instrument for 3-D imaging of biological materials can be applied to a wide range of biological structural assays, including the base-pair sequencing of the human genome and many questions regarding its higher levels of organization.

Rhodes, C.K.

1993-06-08T23:59:59.000Z

286

The Host Galaxies of X-ray Quasars Are Not Strong Star Formers  

E-Print Network (OSTI)

We use ultradeep SCUBA-2 850um observations (~0.37 mJy rms) of the 2 Ms CDF-N and 4 Ms CDF-S X-ray fields to examine the amount of dusty star formation taking place in the host galaxies of high-redshift X-ray AGNs. Supplementing with COSMOS, we measure the submillimeter fluxes of the 4-8 keV sources at z>1, finding little flux at the highest X-ray luminosities but significant flux at intermediate luminosities. We determine grey body and MIR luminosities by fitting spectral energy distributions to each X-ray source and to each radio source in an ultradeep Karl G. Jansky VLA 1.4 GHz (11.5uJy at 5-sigma) image of the CDF-N. We confirm the FIR-radio and MIR-radio correlations to z=4 using the non-X-ray detected radio sources. Both correlations are also obeyed by the X-ray less luminous AGNs but not by the X-ray quasars. We interpret the low FIR luminosities relative to the MIR for the X-ray quasars as being due to a lack of star formation, while the MIR stays high due to the AGN contribution. We find that the FIR...

Barger, A J; Owen, F N; Chen, C -C; Hasinger, G; Hsu, L -Y; Li, Y

2014-01-01T23:59:59.000Z

287

Is linear response to x-rays suitable for digital dental x-ray imaging systems? —Theoretical and experimental considerations  

Science Journals Connector (OSTI)

The purpose of this study was to consider theoretically and experimentally the suitability of linear response to x-rays for digital dental x-ray imaging systems.

Keiichi Nishikawa PhD; Mamoru Wakoh DDS; PhD; Kinya Kuroyanagi DDS; PhD

2003-06-01T23:59:59.000Z

288

Materials Analysis Using New X-ray Microbeams  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Analysis Using New X-ray Microbeams Materials Analysis Using New X-ray Microbeams Materials ranging from massive steel girders to the microscopic aluminum wires in computer chips are made of grains - tiny crystals with diameters measured in millionths of a meter (microns). If scientists could "see" these individual grains, they could determine their orientation, as well as the effects of stress and chemical activity on them. They might also be able to determine how best to jam more circuits together in microelectronic components, making them smaller and faster, so computers could perform complex functions - such as speech recognition - more quickly. They could also find out to what extent grains of a superconducting material mimic the alignment of the substrate on which the material is grown; discovery of

289

X-ray diffraction study of thermal stress relaxation in ZnO films deposited by magnetron sputtering  

E-Print Network (OSTI)

are in a high compressive stress state. In situ X-ray diffraction measurements inside a furnace revealed a relaxation of the as-grown stresses at temperatures which vary with the atmosphere in the furnace and change in many application domains such as ultraviolet detectors, light-emitting diodes, solar cells. As a II

290

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

291

X-ray Pinhole Camera Measurements  

SciTech Connect

The development of the rod pinch diode [1] has led to high-resolution radiography for dynamic events such as explosive tests. Rod pinch diodes use a small diameter anode rod, which extends through the aperture of a cathode plate. Electrons borne off the aperture surface can self-insulate and pinch onto the tip of the rod, creating an intense, small x-ray source (Primary Pinch). This source has been utilized as the main diagnostic on numerous experiments that include high-value, single-shot events. In such applications there is an emphasis on machine reliability, x-ray reproducibility, and x-ray quality [2]. In tests with the baseline rod pinch diode, we have observed that an additional pinch (Secondary Pinch) occurs at the interface near the anode rod and the rod holder. This suggests that stray electrons exist that are not associated with the Primary Pinch. In this paper we present measurements on both pinches using an x-ray pinhole camera. The camera is placed downstream of the Primary Pinch at an angle of 60° with respect to the diode centerline. This diagnostic will be employed to diagnose x-ray reproducibility and quality. In addition, we will investigate the performance of hybrid diodes relating to the formation of the Primary and Secondary Pinches.

Nelson, D. S. [NSTec; Berninger, M. J. [NSTec; Flores, P. A. [NSTec; Good, D. E. [NSTec; Henderson, D. J. [NSTec; Hogge, K. W. [NSTec; Huber, S. R. [NSTec; Lutz, S. S. [NSTec; Mitchell, S. E. [NSTec; Howe, R. A. [NSTec; Mitton, C. V. [NSTec; Molina, I. [NSTec; Bozman, D. R. [SNL; Cordova, S. R. [SNL; Mitchell, D. R. [SNL; Oliver, B. V. [SNL; Ormond, E. C. [SNL

2013-07-01T23:59:59.000Z

292

X-ray lithography using holographic images  

DOE Patents (OSTI)

Methods for forming X-ray images having 0.25 {micro}m minimum line widths on X-ray sensitive material are presented. A holographic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required. 15 figs.

Howells, M.S.; Jacobsen, C.

1997-03-18T23:59:59.000Z

293

Oscillations During Thermonuclear X-ray Bursts  

E-Print Network (OSTI)

High amplitude, nearly coherent X-ray brightness oscillations during thermonuclear X-ray bursts were discovered with the Rossi X-ray Timing Explorer (RXTE) in early 1996. Spectral and timing evidence strongly supports the conclusion that these oscillations are caused by rotational modulation of the burst emission and that they reveal the spin frequency of neutron stars in low mass X-ray binaries, a long sought goal of X-ray astronomy. Studies carried out over the past year have led to the discovery of burst oscillations in four new sources, bringing to ten the number with confirmed burst oscillations. I review the status of our knowledge of these oscillations and indicate how they can be used to probe the physics of neutron stars. For a few burst oscillation sources it has been proposed that the strongest and most ubiquitous frequency is actually the first overtone of the spin frequency and hence that two nearly antipodal hot spots are present on the neutron star. This inference has important implications for both the physics of thermonuclear burning as well as the mass - radius relation for neutron stars, so its confirmation is crucial. I discuss recent attempts to confirm this hypothesis for 4U 1636-53, the source for which a signal at the putative fundamental (290 Hz) has been claimed.

Tod E. Strohmayer

2001-01-12T23:59:59.000Z

294

X-ray lithography using holographic images  

DOE Patents (OSTI)

Methods for forming X-ray images having 0.25 .mu.m minimum line widths on X-ray sensitive material are presented. A holgraphic image of a desired circuit pattern is projected onto a wafer or other image-receiving substrate to allow recording of the desired image in photoresist material. In one embodiment, the method uses on-axis transmission and provides a high flux X-ray source having modest monochromaticity and coherence requirements. A layer of light-sensitive photoresist material on a wafer with a selected surface is provided to receive the image(s). The hologram has variable optical thickness and variable associated optical phase angle and amplitude attenuation for transmission of the X-rays. A second embodiment uses off-axis holography. The wafer receives the holographic image by grazing incidence reflection from a hologram printed on a flat metal or other highly reflecting surface or substrate. In this second embodiment, an X-ray beam with a high degree of monochromaticity and spatial coherence is required.

Howells, Malcolm S. (Berkeley, CA); Jacobsen, Chris (Sound Beach, NY)

1997-01-01T23:59:59.000Z

295

An X-ray study of residual macrostresses in protective coatings for gas-turbine blades  

Science Journals Connector (OSTI)

The x-ray method is used to determine residual macrostresses in the surface layer of protective coatings on high-temperature alloys. Coatings deposited by the high-energy vacuum-plasma (HEVP) method were subje...

Yu. D. Yagodkin; K. M. Pastukhov; E. V. Milyaeva…

1997-11-01T23:59:59.000Z

296

Characterization of nuclear physics targets using Rutherford backscattering and particle induced x-ray emission  

E-Print Network (OSTI)

Rutherford backscattering and particle induced x-ray emission have been utilized to precisely characterize targets used in nuclear fission experiments. The method allows for a fast and non destructive determination of target thickness, homogeneity and element composition.

Th. Rubehn; G. J. Wozniak; L. Phair; L. G. Moretto; Kin M. Yu

1996-09-23T23:59:59.000Z

297

Predicted X-ray backgrounds for the International X-ray Observatory  

E-Print Network (OSTI)

The background that will be observed by IXO's X-ray detectors naturally separates into two components: (1) a Cosmic X-ray Background (CXB), primarily due to unresolved point sources at high energies (E>2 keV), along with ...

Bautz, Marshall W.

298

Reflection soft X-ray microscope and method  

DOE Patents (OSTI)

A reflection soft X-ray microscope is provided by generating soft X-ray beams, condensing the X-ray beams to strike a surface of an object at a predetermined angle, and focusing the X-ray beams reflected from the surface onto a detector, for recording an image of the surface or near surface features of the object under observation.

Suckewer, Szymon (Princeton, NJ); Skinner, Charles H. (Lawrenceville, NJ); Rosser, Roy (Princeton, NJ)

1993-01-01T23:59:59.000Z

299

Differential phase contrast X-ray imaging system and components  

DOE Patents (OSTI)

A differential phase contrast X-ray imaging system includes an X-ray illumination system, a beam splitter arranged in an optical path of the X-ray illumination system, and a detection system arranged in an optical path to detect X-rays after passing through the beam splitter.

Stutman, Daniel; Finkenthal, Michael

2014-07-01T23:59:59.000Z

300

X-ray variability in M87  

E-Print Network (OSTI)

We present the evidence for X-ray variability from the core and from knot A in the M87 jet based on data from two observations with the Einstein Observatory High Resolution Imager (HRI) and three observations with the ROSAT HRI. The core intensity showed a 16% increase in 17 months ('79-'80); a 12% increase in the 3 years '92 to '95; and a 17% drop in the last half of 1995. The intensity of knot A appears to have decreased by 16% between 92Jun and 95Dec. Although the core variability is consistent with general expectations for AGN nuclei, the changes in knot A provide constraints on the x-ray emission process and geometry. Thus we predict that the x-ray morphology of knot A will differ significantly from the radio and optical structure.

D. E. Harris; J. A. Biretta; W. Junor

1996-12-05T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Displaced Vertices from X-ray Lines  

E-Print Network (OSTI)

We present a simple model of weak-scale thermal dark matter that gives rise to X-ray lines. Dark matter consists of two nearly degenerate states near the weak scale, which are populated thermally in the early universe via co-annihilation with slightly heavier states that are charged under the Standard Model. The X-ray line arises from the decay of the heavier dark matter component into the lighter one via a radiative dipole transition, at a rate that is slow compared to the age of the universe. The model predicts observable signatures at the LHC in the form of exotic events with missing energy and displaced leptons and jets. As an application, we show how this model can explain the recently observed 3.55 keV X-ray line.

Adam Falkowski; Yonit Hochberg; Joshua T. Ruderman

2014-09-09T23:59:59.000Z

302

Acoustically Mounted Microcrystals Yield High-Resolution X-ray Structures  

SciTech Connect

We demonstrate a general strategy for determining structures from showers of microcrystals. It uses acoustic droplet ejection to transfer 2.5 nL droplets from the surface of microcrystal slurries, through the air, onto mounting micromesh pins. Individual microcrystals are located by raster-scanning a several-micrometer X-ray beam across the cryocooled micromeshes. X-ray diffraction data sets merged from several micrometer-sized crystals are used to determine 1.8 {angstrom} resolution crystal structures.

Soares, Alexei S.; Engel, Matthew A.; Stearns, Richard; Datwani, Sammy; Olechno, Joe; Ellson, Richard; Skinner, John M.; Allaire, Marc; Orville, Allen M. (Labcyte); (BNL)

2012-10-25T23:59:59.000Z

303

A comprehensive range of X-ray ionized reflection models  

E-Print Network (OSTI)

X-ray ionized reflection occurs when a surface is irradiated with X-rays so intense that its ionization state is determined by the ionization parameter xi propto F/n, where F is the incident flux and n the gas density. It occurs in accretion, onto compact objects including black holes in both active galaxies and stellar-mass binaries, and possibly in gamma-ray bursts. Computation of model reflection spectra is often time-consuming. Here we present the results from a comprehensive grid of models computed with our code, which has now been extended to include what we consider to be all energetically-important ionization states and transitions. This grid is being made available as an ionized-reflection model, REFLION, for XSPEC.

R. R. Ross; A. C. Fabian

2005-01-07T23:59:59.000Z

304

X-ray focal spot locating apparatus and method  

DOE Patents (OSTI)

An X-ray beam finder for locating a focal spot of an X-ray tube includes a mass of X-ray opaque material having first and second axially-aligned, parallel-opposed faces connected by a plurality of substantially identical parallel holes perpendicular to the faces and a film holder for holding X-ray sensitive film tightly against one face while the other face is placed in contact with the window of an X-ray head.

Gilbert, Hubert W. (Cedar Crest, NM)

1985-07-30T23:59:59.000Z

305

X-ray Science Division: Groups  

NLE Websites -- All DOE Office Websites (Extended Search)

Division: Groups Division: Groups Atomic, Molecular and Optical Physics (AMO) Primary Contact: Stephen Southworth Work focuses on understanding how strong optical and x-ray fields interact with matter, with an emphasis on photonic control of electronic, atomic and molecular motion. Chemical and Materials Science (CMS) Primary Contact: Randy Winans Research Disciplines: Chemistry, Materials Science Detectors (DET) Primary Contact: Antonino Miceli GMCA Structural Biology Facility (MX) Primary Contact: Robert Fischetti Research Disciplines: Biology, Life Sciences Imaging (IMG) Primary Contact: Francesco DeCarlo Research Disciplines: Materials Science, Biology, Physics, Life Sciences Inelastic X-ray & Nuclear Resonant Scattering (IXN) Primary Contact: Thomas Gog Research Disciplines: Condensed Matter Physics, Geophysics, Materials

306

Cosmology with X-ray Cluster Baryons  

SciTech Connect

X-ray cluster measurements interpreted with a universal baryon/gas mass fraction can theoretically serve as a cosmological distance probe. We examine issues of cosmological sensitivity for current (e.g., Chandra X-ray Observatory, XMM-Newton) and next generation (e.g., Con-X, XEUS) observations, along with systematic uncertainties and biases. To give competitive next generation constraints on dark energy, we find that systematics will need to be controlled to better than 1percent and any evolution in f_gas (and other cluster gas properties) must be calibrated so the residual uncertainty is weaker than (1+z)0.03.

Linder, Eric V.

2007-04-10T23:59:59.000Z

307

Phase recovery for x-ray crystallography  

Science Journals Connector (OSTI)

For many years people have believed that in conventional x-ray crystallography one can only record the diffraction intensities but not the phases. In order to obtain the atomic arrangements, one usually has to guess a structure and then fit the intensity data by refining its parameters. Here, we show that the phases are in fact hidden in the intensity data, and can be directly recovered from the peak profiles. This method is demonstrated by the normal two-beam x-ray diffraction of a noncentrosymmetric crystal, and nontrivial phases are recovered from the intensity data alone.

G. Xu, G. E. Zhou, and X. Y. Zhang

1999-04-01T23:59:59.000Z

308

Time-resolved x-ray diagnostics  

SciTech Connect

Techniques for time-resolved x-ray diagnostics will be reviewed with emphasis on systems utilizing x-ray diodes or scintillators. System design concerns for high-bandwidth (> 1 GHz) diagnostics will be emphasized. The limitations of a coaxial cable system and a technique for equalizing to improve bandwidth of such a system will be reviewed. Characteristics of new multi-GHz amplifiers will be presented. An example of a complete operational system on the Los Alamos Helios laser will be presented which has a bandwidth near 3 GHz over 38 m of coax. The system includes the cable, an amplifier, an oscilloscope, and a digital camera readout.

Lyons, P.B.

1981-01-01T23:59:59.000Z

309

A NEW CORRELATION BETWEEN GRB X-RAY FLARES AND THE PROMPT EMISSION  

SciTech Connect

From a sample of gamma-ray bursts (GRBs) detected by the Fermi and Swift missions, we have extracted the minimum variability timescales for temporal structures in the light curves associated with the prompt emission and X-ray flares. A comparison of this variability timescale with pulse parameters such as rise times, determined via pulse-fitting procedures, and spectral lags, extracted via the cross-correlation function, indicates a tight correlation between these temporal features for both the X-ray flares and the prompt emission. These correlations suggest a common origin for the production of X-ray flares and the prompt emission in GRBs.

Sonbas, E. [Department of Physics, University of Adiyaman, 02040 Adiyaman (Turkey); MacLachlan, G. A.; Shenoy, A.; Dhuga, K. S.; Parke, W. C., E-mail: edasonbas@yahoo.com [Department of Physics, George Washington University, Washington, DC 20052 (United States)

2013-04-20T23:59:59.000Z

310

X-ray absorption spectroscopy on solid krypton up to 20 GPa  

Science Journals Connector (OSTI)

High-pressure properties of krypton were investigated by energy-dispersive extended x-ray absorption fine-structure spectroscopy in a diamond anvil cell at room temperature. The equation of state agrees very well with x-ray diffraction data. The pressure dependence of the Debye-Waller factor was determined and compared with calculations using pair potentials. The analysis of the x-ray absorption near-edge structure part of the spectrum shows the possibility of measuring the pressure in bubbles of krypton implanted in metallic matrices.

A. Polian; J. P. Itie; E. Dartyge; A. Fontaine; G. Tourillon

1989-02-15T23:59:59.000Z

311

Method for detecting binding events using micro-X-ray fluorescence spectrometry  

DOE Patents (OSTI)

Method for detecting binding events using micro-X-ray fluorescence spectrometry. Receptors are exposed to at least one potential binder and arrayed on a substrate support. Each member of the array is exposed to X-ray radiation. The magnitude of a detectable X-ray fluorescence signal for at least one element can be used to determine whether a binding event between a binder and a receptor has occurred, and can provide information related to the extent of binding between the binder and receptor.

Warner, Benjamin P. (Los Alamos, NM); Havrilla, George J. (Los Alamos, NM); Mann, Grace (Hong Kong, HK)

2010-12-28T23:59:59.000Z

312

Ultraviolet observations of the X-ray photoionized wind of Cygnus X-1 during X-ray soft/high state  

E-Print Network (OSTI)

(Shortened) Ultraviolet observations of the black hole X-ray binary Cygnus X-1 were obtained using the STIS on HSTubble. We detect P Cygni line features show strong, broad absorption components when the X-ray source is behind the companion star and noticeably weaker absorption when the X-ray source is between us and the companion star. We fit the P Cygni profiles using the SEI method applied to a spherically symmetric stellar wind subject to X-ray photoionization from the black hole. The Si IV doublet provides the most reliable estimates of the parameters of the wind and X-ray illumination. The velocity $v$ increases with radius $r$ according to $v=v_\\infty(1-r_\\star/r)^\\beta$, with$\\beta\\approx0.75$ and $v_\\infty\\approx1420$ km s$^{-1}$.The microturbulent velocity was $\\approx160$ km s$^{-1}$. Our fit implies a ratio of X-ray luminosity to wind mass-loss rate of L$_{X,38}/\\dot M_{-6} \\approx 0.33$, measured at $\\dot M_{-6}$ = 4.8. Our models determine parameters that may be used to estimate the accretion rat...

Vrtilek, S D; Hunacek, A; Gies, D; Bolton, C T

2007-01-01T23:59:59.000Z

313

In situ testing to determination field-saturated hydraulic conductivity of UMTRA Project disposal cell covers, liners, and foundation areas. Special study  

SciTech Connect

This special study was conducted to prepare a guidance document for selecting in situ hydraulic conductivity (K) tests, comparing in situ testing methods, and evaluating the results of such tests. This report may be used as a practical decision-making tool by the Uranium Mill Tailings Remedial Action (UMTRA) Project staff to determine which testing method will most efficiently achieve the field-saturated K results needed for long-term planning. A detailed section on near-surface test methods discusses each method which may be applicable to characterization of UMTRA disposal cell covers, liners and foundation materials. These potentially applicable test methods include the sealed double-ring infiltrometer (SDRI), the air-entry permeameter (AEP), the guelph permeameter, the two-stage borehole technique (TSB), the pressure infiltrometer, and the disk permeameter. Analytical solutions for these methods are provided, and limitations of these solutions are discussed, and a description of testing equipment design and installation are provided.

Not Available

1994-02-01T23:59:59.000Z

314

In situ mercury stabilization  

SciTech Connect

BNL Royalty Project Internal Status Report. The funds from the allotment of royalty income were used to experimentally explore feasibility of related, potential new techniques based on the Environmental Sciences Department successful technology licensed for the ex situ treatment of mercury. Specifically, this work is exploring the concept of using Sulfur Polymer Cement (SPC) in an in situ application to stabilize and/or remove mercury (Hg) from surficial soil. Patent disclosure forms have been filed for this process. Soil was artificially spiked with 500 ppm Hg and a series of experiments were set up in which SPC rods were placed in the center of a mass of this soil. Some experiments were conducted at 20 C and others at 50 C. After times ranging from 11 to 24 days, these experiments were opened, photographed and the soil was sampled from discrete locations in the containers. The soil and SPC samples were analyzed for Fe and Hg by x-ray fluorescence. The Hg profile in the soil was significantly altered, with concentrations along the outer edge of the soil reduced by as much as 80% from the starting concentration. Conversely, closer to the treatment rod containing SPC, concentrations of Hg were significantly increased over the original concentration. Preliminary results for elevated temperature sample are shown graphically in Figure 2. Apparently the Hg had migrated toward the SPC and reacted with sulfur to form Hg S. This appears to be a reaction between gaseous phases of both S and Hg, with Hg having a greater vapor pressure. The concentration of low solubility HgS (i.e., low leaching properties) developed within 11 days at 50 C and 21 days at 20 C, confirming the potential of this concept.

Fuhrmann, M.; Kalb, P.; Adams, J.

2004-09-01T23:59:59.000Z

315

Sharper Focusing of Hard X-rays  

NLE Websites -- All DOE Office Websites (Extended Search)

Sharper Focusing of Hard X-rays FROM: Physics News Update Number 773 #1, April 12, 2006, by Phil Schewe and Ben Stein Note: This text has been slightly modified from the original. Sharper focusing of hard x-rays has been achieved with a device developed at Argonne National Lab. Because of their high energy, x-rays are hard to focus: they can be reflected from a surface but only at a glancing angle (less than a tenth of a degree); they can be refracted but the index of refraction is very close to 1, so that making efficient lenses becomes a problem; and they can be diffracted, but the relatively thick, variable pitch grating required for focusing is tricky to achieve. The Argonne device is of the diffraction type, and it consists of a stack of alternating layers of metal and silicon, made by depositing progressively thicker layers. When the x-rays fall on such a structure, nearly edge-on, what they see is a grating (called a linear zone plate) consisting of a sort of bar-code pattern.

316

Radioactive Thulium for X-Rays  

Science Journals Connector (OSTI)

Radioactive power from thulium makes Argonne x-ray unit a potential for medical and industrial use ... Active component of the instrument is a tiny particle (one-fifth gram) of thulium-170 which has been made radioactive in a heavy water nuclear reactor at Arco, Idaho. ...

1954-05-03T23:59:59.000Z

317

Multiple wavelength X-ray monochromators  

DOE Patents (OSTI)

An improved apparatus and method is provided for separating input x-ray radiation containing first and second x-ray wavelengths into spatially separate first and second output radiation which contain the first and second x-ray wavelengths, respectively. The apparatus includes a crystalline diffractor which includes a first set of parallel crystal planes, where each of the planes is spaced a predetermined first distance from one another. The crystalline diffractor also includes a second set of parallel crystal planes inclined at an angle with respect to the first set of crystal planes where each of the planes of the second set of parallel crystal planes is spaced a predetermined second distance from one another. In one embodiment, the crystalline diffractor is comprised of a single crystal. In a second embodiment, the crystalline diffractor is comprised of a stack of two crystals. In a third embodiment, the crystalline diffractor includes a single crystal that is bent for focusing the separate first and second output x-ray radiation wavelengths into separate focal points. 3 figs.

Steinmeyer, P.A.

1992-11-17T23:59:59.000Z

318

Soft x-ray laser microscope  

SciTech Connect

The program consisted of two phases (Phase I and Phase II). The goal of the Phase I (first year program) was to design and construct the Soft X-ray Laser Contact Microscope. Such microscope was constructed and adapted to PPL's 18.2nm soft X-ray Laser (SXL), which in turn was modified and prepared for microscopy experiments. Investigation of the photoresist response to 18.2nm laser radiation and transmissivity of 0.1m thick silicion-nitride (Si[sub 3]N[sub 4]) windows were important initial works. The goal of the first year of Phase II was to construct X-ray contact microscope in combination with existing optical phase microscope, already used by biologists. In the second year of Phase II study of dehydrated Horeseshoe Crab and Hela cancer cells were performed with COXRALM. Also during Phase II, the Imaging X-Ray Laser Microscope (IXRALM) was designed and constructed. This paper describes the development of each of the microscopes and their application for research.

Suckewer, P.I.

1990-10-01T23:59:59.000Z

319

Small Angle X-Ray Scattering Detector  

DOE Patents (OSTI)

A detector for time-resolved small-angle x-ray scattering includes a nearly constant diameter, evacuated linear tube having an end plate detector with a first fluorescent screen and concentric rings of first fiber optic bundles for low angle scattering detection and an annular detector having a second fluorescent screen and second fiber optic bundles concentrically disposed about the tube for higher angle scattering detection. With the scattering source, i.e., the specimen under investigation, located outside of the evacuated tube on the tube's longitudinal axis, scattered x-rays are detected by the fiber optic bundles, to each of which is coupled a respective photodetector, to provide a measurement resolution, i.e., dq/q, where q is the momentum transferred from an incident x-ray to an x-ray scattering specimen, of 2% over two (2) orders of magnitude in reciprocal space, i.e., q.sub.max /q.sub.min.congruent.100.

Hessler, Jan P. (Downers Grove, IL)

2004-06-15T23:59:59.000Z

320

SLAC All Access: X-ray Microscope  

ScienceCinema (OSTI)

SLAC physicists Johanna Nelson and Yijin Liu give a brief overview of the X-ray microscope at the Stanford Synchrotron Radiation Lightsource (SSRL) that is helping improve rechargeable-battery technology by letting researchers peek into the inner workings of batteries as they operate.

Nelson, Johanna; Liu, Yijin

2014-06-13T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

X-ray photon correlation spectroscopy under flow  

E-Print Network (OSTI)

X-ray photon correlation spectroscopy was used to probe the diffusive dynamics of colloidal particles in a shear flow. Combining X-ray techniques with microfluidics is an experimental strategy that reduces the risk of x-ray induced beam damage and also allows time-resolved studies of processes taking place in flowcells. The experimental results and theoretical predictions presented here, show that in the low shear limit, for a ``transverse flow'' scattering geometry (scattering wave vector q perpendicular to the direction of flow) the measured relaxation times are independent of the flow rate and determined only by the diffusive motion of the particles. This is not generally valid and in particular, for a ``longitudinal flow'' (q || flow) scattering geometry, the relaxation times are strongly affected by the flow-induced motion of the particles. Our results show that the Brownian diffusion of colloidal particles can be measured in a flowing sample and that, up to flux limitations, the experimental conditions under which this is possible are easier to achieve at higher values of q.

Andrei Fluerasu; Abdellatif Moussaid; Henri Gleyzolle; Peter Falus; Anders Madsen

2008-03-10T23:59:59.000Z

322

X-ray Emission Processes in Radio Jets  

E-Print Network (OSTI)

The emission processes responsible for the observed X-rays from radio jets are commonly believed to be non-thermal, but in any particular case, it is unclear if synchrotron emission or one or more varieties of inverse Compton emission predominates. We present a formulation of inverse Compton emission from a relativistically moving jet (``IC/beaming'') which relies on radio emitting synchrotron sources for which the energy densities in particles and fields are comparable. We include the non-isotropic nature of inverse Compton scattering of the relativistic electrons on photons of the cosmic microwave background (CMB) and provide beaming parameters for a number of jets. A list of X-ray emitting jets is given and the jets are classified on the basis of their morphology and spectral energy distribution to determine their likely emission process. We conclude that these jets have significant bulk relativistic velocities on kpc scales; that higher redshift sources require less beaming because the energy density of the CMB is significantly greater than locally; and that for some nearby sources, synchrotron X-ray emission predominates because the jet makes a large angle to the line of sight.

D. E. Harris; H. Krawczynski

2001-09-27T23:59:59.000Z

323

X-ray Diffraction of Cubic Gd2)3/Er under High Pressure  

SciTech Connect

In this paper, we report the in situ high pressure X-ray diffraction studies on Er{sup 3+} doped Gd{sub 2}O{sub 3} in a diamond anvil cell up to 39.8 GPa at room temperature. Several phase transitions have been identified in our studies. The structural transformation from a starting cubic phase to a hexagonal phase occurred during the sample compression process, at 8.57 GPa. And the hexagonal phase was stable from 12.5 GPa up to the highest pressure in this study but was not quenchable and transformed to a monoclinic phase after pressure release. An anomalous high pressure behavior in the hexagonal type Gd{sub 2}O{sub 3} phase was observed, which might be caused by an electron transition influenced by Er{sup 3+} ions doping. By fitting the compression data to the Birch-Murnaghan equation of state, the bulk moduli of the cubic and two hexagonal (at p < 19.9 GPa and p > 27.0 GPa) Gd{sub 2}O{sub 3} phases were determined to be 164 {+-} 3, 185 {+-} 7, and 150 {+-} 10 GPa with B'{sub 0} = 4, respectively.

X Zou; C Gong; B Liu; Q Li; Z Li; B Liu; R Liu; J Liu; Z Chen; et al.

2011-12-31T23:59:59.000Z

324

Neutron and X-Ray Studies of Advanced Materials V: CENTENNIAL  

SciTech Connect

In 2012 the diffraction community will celebrate 100 years since the prediction of X-ray diffraction by M. Laue, and following his suggestion the first beautiful diffraction experiment by W. Friedrich and P. Knipping. The significance of techniques based on the analysis of the diffraction of X-rays, neutrons, electrons and Mossbauer photons discovered later, has continued to increase in the past 100 years. The aim of this symposium is to provide a forum for discussion of using state-of-the-art neutron and X-ray scattering techniques for probing advanced materials. These techniques have been widely used to characterize materials structures across all length scales, from atomic to nano, meso, and macroscopic scales. With the development of sample environments, in-situ experiments, e.g., at temperatures and applied mechanical load, are becoming routine. The development of ultra-brilliant third-generation synchrotron X-ray sources, together with advances in X-ray optics, has created intense X-ray microbeams, which provide the best opportunities for in-depth understanding of mechanical behavior in a broad spectrum of materials. Important applications include ultra-sensitive elemental detection by X-ray fluorescence/absorption and microdiffraction to identify phase and strain with submicrometer spatial resolution. X-ray microdiffraction is a particularly exciting application compared with alternative probes of crystalline structure, orientation and strain. X-ray microdiffraction is non-destructive with good strain resolution, competitive or superior spatial resolution in thick samples, and with the ability to probe below the sample surface. Advances in neutron sources and instrumentation also bring new opportunities in neutron scattering research. In addition to characterizing the structures, neutrons are also a great tool for elucidating the dynamics of materials. Because neutrons are highly penetrating, neutrons have been used to map stress in engineering systems. Neutrons have also played a vital role in our understanding of the magnetism and magnetic properties. Specialized instruments have been built to gain physical insights of the fundamental mechanisms governing phase transformation and mechanical behaviors of materials. The application of those techniques, in combination with theoretical simulations and numerical modeling, will lead to major breakthroughs in materials science in the foreseeable future that will contribute to the development of materials technology and industrial innovation.

Spanos, George

2012-05-01T23:59:59.000Z

325

Rise Time Measurement for Ultrafast X-Ray Pulses  

DOE Patents (OSTI)

A pump-probe scheme measures the rise time of ultrafast x-ray pulses. Conventional high speed x-ray diagnostics (x-ray streak cameras, PIN diodes, diamond PCD devices) do not provide sufficient time resolution to resolve rise times of x-ray pulses on the order of 50 fs or less as they are being produced by modern fast x-ray sources. Here, we are describing a pump-probe technique that can be employed to measure events where detector resolution is insufficient to resolve the event. The scheme utilizes a diamond plate as an x-ray transducer and a p-polarized probe beam.

Celliers, Peter M.; Weber, Franz A.; Moon, Stephen J.

2005-04-05T23:59:59.000Z

326

X-ray microscopy using grazing-incidence reflection optics  

SciTech Connect

The Kirkpatrick-Baez microscopes are described along with their role as the workhorse of the x-ray imaging devices. This role is being extended with the development of a 22X magnification Kirkpatrick-Baez x-ray microscope with multilayer x-ray mirrors. These mirrors can operate at large angles, high x-ray energies, and have a narrow, well defined x-ray energy bandpass. This will make them useful for numerous experiments. However, where a large solid angle is needed, the Woelter microscope will still be necessary and the technology needed to build them will be useful for many other types of x-ray optics.

Price, R.H.

1981-08-06T23:59:59.000Z

327

X-RAY POINT-SOURCE POPULATIONS CONSTITUTING THE GALACTIC RIDGE X-RAY EMISSION  

SciTech Connect

Apparently diffuse X-ray emission has been known to exist along the central quarter of the Galactic Plane since the beginning of X-ray astronomy; this is referred to as the Galactic Ridge X-ray emission (GRXE). Recent deep X-ray observations have shown that numerous X-ray point sources account for a large fraction of the GRXE in the hard band (2-8 keV). However, the nature of these sources is poorly understood. Using the deepest X-ray observations made in the Chandra bulge field, we present the result of a coherent photometric and spectroscopic analysis of individual X-ray point sources for the purpose of constraining their nature and deriving their fractional contributions to the hard-band continuum and Fe K line emission of the GRXE. Based on the X-ray color-color diagram, we divided the point sources into three groups: A (hard), B (soft and broad spectrum), and C (soft and peaked spectrum). The group A sources are further decomposed spectrally into thermal and non-thermal sources with different fractions in different flux ranges. From their X-ray properties, we speculate that the group A non-thermal sources are mostly active galactic nuclei and the thermal sources are mostly white dwarf (WD) binaries such as magnetic and non-magnetic cataclysmic variables (CVs), pre-CVs, and symbiotic stars, whereas the group B and C sources are X-ray active stars in flares and quiescence, respectively. In the log N-log S curve of the 2-8 keV band, the group A non-thermal sources are dominant above Almost-Equal-To 10{sup -14} erg cm{sup -2} s{sup -1}, which is gradually taken over by Galactic sources in the fainter flux ranges. The Fe K{alpha} emission is mostly from the group A thermal (WD binaries) and the group B (X-ray active stars) sources.

Morihana, Kumiko [Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)] [Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Tsujimoto, Masahiro; Ebisawa, Ken [Japan Aerospace Exploration Agency, Institute of Space and Astronautical Science, 3-1-1 Yoshino-dai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan)] [Japan Aerospace Exploration Agency, Institute of Space and Astronautical Science, 3-1-1 Yoshino-dai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Yoshida, Tessei, E-mail: morihana@crab.riken.jp [National Astronomical Observatory of Japan, 2-21-1, Osawa, Mitaka, Tokyo 181-8588 (Japan)] [National Astronomical Observatory of Japan, 2-21-1, Osawa, Mitaka, Tokyo 181-8588 (Japan)

2013-03-20T23:59:59.000Z

328

In Situ Analytical Electron Microscopy for Probing Nanoscale Electrochemistry  

SciTech Connect

Oxides and their tailored structures are at the heart of electrochemical energy storage technologies and advances in understanding and controlling the dynamic behaviors in the complex oxides, particularly at the interfaces, during electrochemical processes will catalyze creative design concepts for new materials with enhanced and better-understood properties. Such knowledge is not accessible without new analytical tools. New innovative experimental techniques are needed for understanding the chemistry and structure of the bulk and interfaces, more importantly how they change with electrochemical processes in situ. Analytical Transmission Electron Microscopy (TEM) is used extensively to study electrode materials ex situ and is one of the most powerful tools to obtain structural, morphological, and compositional information at nanometer scale by combining imaging, diffraction and spectroscopy, e.g., EDS (energy dispersive X-ray spectrometry) and Electron Energy Loss Spectrometry (EELS). Determining the composition/structure evolution upon electrochemical cycling at the bulk and interfaces can be addressed by new electron microscopy technique with which one can observe, at the nanometer scale and in situ, the dynamic phenomena in the electrode materials. In electrochemical systems, for instance in a lithium ion battery (LIB), materials operate under conditions that are far from equilibrium, so that the materials studied ex situ may not capture the processes that occur in situ in a working battery. In situ electrochemical operation in the ultra-high vacuum column of a TEM has been pursued by two major strategies. In one strategy, a 'nano-battery' can be fabricated from an all-solid-state thin film battery using a focused ion beam (FIB). The electrolyte is either polymer based or ceramic based without any liquid component. As shown in Fig. 1a, the interfaces between the active electrode material/electrolyte can be clearly observed with TEM imaging, in contrast to the composite electrodes/electrolyte interfaces in conventional lithium ion batteries, depicted in Fig.1b, where quantitative interface characterization is extremely difficult if not impossible. A second strategy involves organic electrolyte, though this approach more closely resembles the actual operation conditions of a LIB, the extreme volatility In Situ Analytical Electron Microscopy for Probing Nanoscale Electrochemistry by Ying Shirley Meng, Thomas McGilvray, Ming-Che Yang, Danijel Gostovic, Feng Wang, Dongli Zeng, Yimei Zhu, and Jason Graetz of the organic electrolytes present significant challenges for designing an in situ cell that is suitable for the vacuum environment of the TEM. Significant progress has been made in the past few years on the development of in situ electron microscopy for probing nanoscale electrochemistry. In 2008, Brazier et al. reported the first cross-section observation of an all solid-state lithium ion nano-battery by TEM. In this study the FIB was used to make a 'nano-battery,' from an all solid-state battery prepared by pulsed laser deposition (PLD). In situ TEM observations were not possible at that time due to several key challenges such as the lack of a suitable biasing sample holder and vacuum transfer of sample. In 2010, Yamamoto et al. successfully observed changes of electric potential in an all-solid-state lithium ion battery in situ with electron holography (EH). The 2D potential distribution resulting from movement of lithium ions near the positive-electrode/electrolyte interface was quantified. More recently Huang et al. and Wang et al. reported the in situ observations of the electrochemical lithiation of a single SnO{sub 2} nanowire electrode in two different in situ setups. In their approach, a vacuum compatible ionic liquid is used as the electrolyte, eliminating the need for complicated membrane sealing to prevent the evaporation of carbonate based organic electrolyte into the TEM column. One main limitation of this approach is that EELS spectral imaging is not possible due to the high plasmon signal of the ionic li

Graetz J.; Meng, Y.S.; McGilvray, T.; Yang, M.-C.; Gostovic, D.; Wang, F.; Zeng, D.; Zhu, Y.

2011-10-31T23:59:59.000Z

329

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital and spin dynamics  

E-Print Network (OSTI)

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital of atomic species driven to ferromagnetic resonance. X-ray absorption measurements performed as a function of paramagnetic atoms can be determined by de- tecting the absorption or emission of light modulated by a MW field

Brune, Harald

330

Scaling Laws of Nitrogen Soft X-ray Yields from 1 to 200 kJ Plasma Focus  

Science Journals Connector (OSTI)

Numerical experiments are carried out systematically to determine the nitrogen soft X-ray yield for optimized nitrogen plasma focus with storage energy E0 from 1 to 200 kJ. Scaling laws on nitrogen soft X-ray yie...

M. Akel; S. Lee

2013-02-01T23:59:59.000Z

331

Low Dose Radiation Research Program: A Variable Energy Soft X-ray  

NLE Websites -- All DOE Office Websites (Extended Search)

Variable Energy Soft X-ray Microprobe to Investigate Mechanisms of the Variable Energy Soft X-ray Microprobe to Investigate Mechanisms of the Radiation-Induced Bystander Effect Melvyn Folkard Gray Cancer Institute Why This Project The aim of this project is to determine the effects of low radiation doses using a machine that makes it possible to radiate one cell at a time. Our soft X-ray microprobe can irradiate individual cells, or locations within cells with defined doses and with sub-micron precision. We can use low doses approaching that of a single electron track, which is of relevance to environmental level exposures. Much of our work is concentrating on irradiating specified individual cells within cell populations to identify "bystander responses" where non-radiated cells respond to signals from nearby radiated cells. Higher energy x-rays are being generated to extend

332

X-rays Illuminate Ancient Archimedes Text  

NLE Websites -- All DOE Office Websites (Extended Search)

Related Links: Related Links: May 2005 Headlines TIP Article Press Release Walters Art Museum SSRL Home Page SLAC Home Page Stanford Home Page Tuesday, 31 May 2005 X-rays Illuminate Ancient Archimedes Text (contact: Uwe Bergmann, bergmann@slac.stanford.edu) Archimedes Figure Image provided by Will Noel, The Walters Art Museum An early transcription of Archimedes' mathematical theories has been brought to light through the probing of high-intensity x-rays at SSRL's BL6-2. The text contains part of the Method of Mechanical Theorems, one of Archimedes' most important works, which was probably copied out by a scribe in the tenth century. The parchment on which it was written was later scraped down and reused as pages in a twelfth century prayer book, producing a document known as a palimpsest (which comes from the Greek,

333

HIGH BRILLIANCE X-RAY SCATTERING FOR  

NLE Websites -- All DOE Office Websites (Extended Search)

BRILLIANCE X-RAY SCATTERING FOR BRILLIANCE X-RAY SCATTERING FOR LIFE SCIENCES (LIX) Group Leader: Lin Yang Proposal Team: O. Bilsel 1 , B. Hsiao 2 , H. Huang 3 , T. Irving 4 , A. Menzel 5 , L. Pollack 6 , C. Riekel 7 , J. Rubert 8 , H. Tsuruta 9 , L. Yang 10 1 University of Massachusetts, 2 Stony Brook University, 3 Rice University, 4 IIT, 5SLS, 6 Cornell University, 7 European Synchrotron Radiation Facility, 8 NEU, 9 Stanford Synchrotron Radiation Lightsource, 10 Brookhaven National Laboratory TECHNIQUES AND CAPABILITIES APPLICATIONS ADDITIONAL INFORMATION * Energy range 2-20keV using undulator source. Simultaneous SAXS/WAXS to cover 0.003-3Å -1 at 12keV with 1 micron spot size * Time-resolved solution scattering with resolution of (1) microseconds to milliseconds using continuous-flow mixing (5µm x 10µm spot size) and (2) milliseconds using stopped-

334

Element 104 identified by characteristic x rays  

Science Journals Connector (OSTI)

A research team at the Oak Ridge National Laboratory has recently announced that they have conclusively identified the 257 isotope of element 104. This new work shows promise of shedding light on the controversy between Albert Ghiorso and Georgi N. Flerov the leaders respectively of the groups at Lawrence Berkeley Laboratory and the Joint Institute for Nuclear Research Dubna. The isotope 104 X 257 decays by alpha emission to 102 No 253 with a half?life of 4.3 seconds. The Oak Ridge group observed the K?series x rays from nobelium in coincidence with the alpha particles from 104 X 257 ; the observation of x?ray spectra has never been reported previously by the Berkeley or Dubna workers according to Curtis E. Bemis Jr spokesman for the group.

Ronald J. Cohn

1973-01-01T23:59:59.000Z

335

X-ray radiography for container inspection  

DOE Patents (OSTI)

Arrangements of X-ray inspection systems are described for inspecting high-z materials in voluminous objects such as containers. Inspection methods may involve generating a radiographic image based on detected attenuation corresponding to a pulsed beams of radiation transmitted through a voluminous object. The pulsed beams of radiation are generated by a high-energy source and transmitted substantially downward along an incident angle, of approximately 1.degree. to 30.degree., to a vertical axis extending through the voluminous object. The generated radiographic image may be analyzed to detect on localized high attenuation representative of high-z materials and to discriminate high-z materials from lower and intermediate-z materials on the basis of the high density and greater attenuation of high-z material for higher energy (3-10 MeV) X-rays, and the compact nature of threatening masses of fissionable materials.

Katz, Jonathan I. (Clayton, MO); Morris, Christopher L. (Los Alamos, NM)

2011-06-07T23:59:59.000Z

336

Thickness measurement of aluminum, titanium, titanium silicide, and tungsten silicide films by x-ray fluorescence  

SciTech Connect

X-ray fluorescence (XRF) has received a great deal of attention in the last few years as a quantitative means of determining both the stoichiometry and thickness of many different kinds of films. Examples include Ag and Cu films on mica substrates, Sn-Pb alloys on steel substrates, Al-Ti multilayers on Cu substrates and oxide films on silicon substrates. In XRF the sample is irradiated with x-rays which in turn cause x-rays to be given off by the sample. These x-rays that are given off by the sample can then be analyzed both for energy and intensity. The energy of the x-rays is characteristic of the elemental makeup of the sample and the intensity of the x-rays is dependent on how much of the particular element is present. The intensity then can be related to the thickness of a film if the stoichiometry of the film can be assumed constant. With the increased interest in silicides and more recently, the self-aligned silicide (salicide) process (8-10) for VLSI applications, in-line process monitoring of silicide film thickness has become important to integrated circuit manufacturing. In this study, the number of x-ray photons given of by Al, Ti, titanium silicide, and tungsten silicide films on silicon-based substrates was quantified so that a film thickness for an unknown sample could then be determined easily. In addition, XRF is a more accurate technique, limited principally by the accuracy technique, limited principally by the accuracy of the reference used and the amount of time the x-ray photons are counted.

Ernst, S.; Lee, C.O.; Lee, J.J. (Motorola, Inc., Advanced Products Research and Development Lab., Austin, TX (US))

1988-08-01T23:59:59.000Z

337

Sample holder for X-ray diffractometry  

DOE Patents (OSTI)

A sample holder for use with X-ray diffractometers with the capability to rotate the sample, as well as to adjust the position of the sample in the x, y, and z directions. Adjustment in the x direction is accomplished through loosening set screws, moving a platform, and retightening the set screws. Motion translators are used for adjustment in the y and z directions. An electric motor rotates the sample, and receives power from the diffractometer.

Hesch, Victor L. (Los Alamos, NM)

1992-01-01T23:59:59.000Z

338

Columbia University X-Ray Measurements  

E-Print Network (OSTI)

V-720 keV · NaI 2x2x2" detector views an energy range of 1 keV-3 MeV Store signal in the tree. computer configuration. Plasmas were created using multi-frequency ECRH, and we find that most of the plasma energy is stored in the fast electrons. The energy spectrum of the x-ray emission below 740 keV is measured

339

Silicon Absolute X-Ray Detectors  

SciTech Connect

The responsivity of silicon photodiodes having no loss in the entrance window, measured using synchrotron radiation in the 1.75 to 60 keV range, was compared to the responsivity calculated using the silicon thickness measured using near-infrared light. The measured and calculated responsivities agree with an average difference of 1.3%. This enables their use as absolute x-ray detectors.

Seely, John F. [Naval Research Laboratory, Washington, D.C. 20375 (United States); Korde, Raj; Sprunck, Jacob [International Radiation Detectors, Inc., Torrance, CA 90505-5243 (United States); Medjoubi, Kadda; Hustache, Stephanie [Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, 91192 Gif-sur-Yvette CEDEX (France)

2010-06-23T23:59:59.000Z

340

Ultrashort x-ray backlighters and applications  

SciTech Connect

Previously, using ultrashort laser pulses focused onto solid targets, we have experimentally studied a controllable ultrafast broadband radiation source in the extreme ultraviolet for time-resolved dynamical studies in ultrafast science [J. Workman, A. Maksimchuk, X. Llu, U. Ellenberger, J. S. Coe, C.-Y. Chien, and D. Umstadter, ``Control of Bright Picosecond X-Ray Emission from Intense Sub- Picosecond Laser-Plasma Interactions,`` Phys. Rev. Lett. 75, 2324 (1995)]. Once armed with a bright ultrafast broadband continuum x-ray source and appropriate detectors, we used the source as a backlighter to study a remotely produced plasma. The application of the source to a problem relevant to high-density matter completes the triad: creating and controlling, efficiently detecting, and applying the source. This work represented the first use of an ultrafast laser- produced x-ray source as a time-resolving probe in an application relevant to atomic, plasma and high-energy-density matter physics. Using the x-ray source as a backlighter, we adopted a pump-probe geometry to investigate the dynamic changes in electronic structure of a thin metallic film as it is perturbed by an ultrashort laser pulse. Because the laser deposits its energy in a skin depth of about 100 {Angstrom} before expansion occurs, up to gigabar pressure shock waves lasting picosecond in duration have been predicted to form in these novel plasmas. This raises the possibility of studying high- energy-density matter relevant to inertial confinement fusion (ICF) and astrophysics in small-scale laboratory experiments. In the past, time-resolved measurements of K-edge shifts in plasmas driven by nanosecond pulses have been used to infer conditions in highly compressed materials. In this study, we used 100-fs laser pulses to impulsively drive shocks into a sample (an untamped 1000 {Angstrom} aluminum film on 2000 {Angstrom} of parylene-n), measuring L-edge shifts.

Umstadter, D., University of Michigan

1997-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

X-Ray Diffraction Microscopy of Magnetic Structures  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Diffraction Microscopy of Magnetic Structures Print science brief icon Scientists working at ALS Beamline 12.0.2.2 have demonstrated a new x-ray technique for producing...

342

X-ray diffraction study of zirconia pillared clays  

Science Journals Connector (OSTI)

X-ray powder diffraction (XRPD) and X-ray radial electronic distribution density (RED) of initial and zirconia-pillared interlayered clays (Zr-PILC) were studied. After pillaring, the basal ... under air to 17.7 ...

D.A. Zyuzin; E.M. Moroz; T.G. Kuznetsova…

2004-01-01T23:59:59.000Z

343

Development of a Schwarzschild-type x-ray microscope  

Science Journals Connector (OSTI)

A Schwarzschild-type x-ray microscope has been designed, constructed, and tested. Ni/C multilayers were used as the x-ray mirrors, with a thickness (2d) of 7 nm and 30 layer pairs. The...

Kado, M; Yamashita, K; Ohtani, M; Tanaka, K A; Kodama, R; Kitamoto, S; Yamanaka, T; Nakai, S

1991-01-01T23:59:59.000Z

344

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Print Electron and x-ray microscopes are a valuable tool for both the life and materials sciences, but they are limited in...

345

A Record Run for the APS X-ray Source  

NLE Websites -- All DOE Office Websites (Extended Search)

2004 | 2003 | 2002 | 2001 2000 Subscribe to APS News rss feed A Record Run for the APS X-ray Source FEBRUARY 23, 2012 Bookmark and Share The APS storage ring. X-ray beams and...

346

Resonant Soft X-Ray Scattering - Combining Structural with Spectroscop...  

NLE Websites -- All DOE Office Websites (Extended Search)

Resonant Soft X-Ray Scattering - Combining Structural with Spectroscopic Refinement Friday, September 28, 2012 - 10:00am SLAC, Bldg. 137, Room 322 SSRL Presents Kevin Stone X-ray...

347

CX-009554: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4: Categorical Exclusion Determination 4: Categorical Exclusion Determination CX-009554: Categorical Exclusion Determination In-situ X-ray Nanocharacterization of Defect Kinetics in Chalcogenide Solar Cell CX(s) Applied: A9, B3.6 Date: 12/04/2012 Location(s): Arizona Offices(s): Golden Field Office The U.S. DOE is proposing to provide federal funding to Arizona State University (ASU) to conduct research and development activities that advance solar photovoltaic technology. DOE funding would be used to develop an X-ray in-situ microscopy capability at the Advanced Photon Source laboratory and apply performance-governing defect kinetics in chalcogenide solar cell materials to it. CX-009554.pdf More Documents & Publications CX-007533: Categorical Exclusion Determination CX-002666: Categorical Exclusion Determination

348

The X-ray Telescope of CAST  

E-Print Network (OSTI)

The Cern Axion Solar Telescope (CAST) is in operation and taking data since 2003. The main objective of the CAST experiment is to search for a hypothetical pseudoscalar boson, the axion, which might be produced in the core of the sun. The basic physics process CAST is based on is the time inverted Primakoff effect, by which an axion can be converted into a detectable photon in an external electromagnetic field. The resulting X-ray photons are expected to be thermally distributed between 1 and 7 keV. The most sensitive detector system of CAST is a pn-CCD detector combined with a Wolter I type X-ray mirror system. With the X-ray telescope of CAST a background reduction of more than 2 orders off magnitude is achieved, such that for the first time the axion photon coupling constant g_agg can be probed beyond the best astrophysical constraints g_agg < 1 x 10^-10 GeV^-1.

M. Kuster; H. Bräuninger; S. Cébrian; M. Davenport; C. Elefteriadis; J. Englhauser; H. Fischer; J. Franz; P. Friedrich; R. Hartmann; F. H. Heinsius; D. H. H. Hoffmann; G. Hoffmeister; J. N. Joux; D. Kang; K. Königsmann; R. Kotthaus; T. Papaevangelou; C. Lasseur; A. Lippitsch; G. Lutz; J. Morales; A. Rodríguez; L. Strüder; J. Vogel; K. Zioutas

2007-05-10T23:59:59.000Z

349

Kinetics of alloy formation at the interfaces in a Ni-Ti multilayer: X-ray and neutron reflectometry study  

Science Journals Connector (OSTI)

Vacuum-deposited Ni/Ti multilayers on annealing at different temperatures exhibit formation of ordered alloy layers at interfaces. We have studied in detail the formation of alloy at interfaces of a Ni/Ti multilayer on annealing at 300?°C and 400?°C using powder x-ray diffraction, x-ray reflectometry, polarized neutron reflectometry, and off-specular x-ray reflectometry techniques. Correlation among structural, magnetic, and morphological properties in as-deposited Ni/Ti multilayer as well as in a sample annealed at 300?°C and 400?°C has been studied. X-ray diffraction technique was used to obtain crystal structure of the sample. Specular x-ray reflectometry and neutron reflectometry were used to determine the growth of alloy layers from density profile, as a function of depth in the sample. From off-specular x-ray reflectivity we found that the in-plane correlation lengths at the interfaces grew with annealing. This is associated with alloy crystallite growth obtained from x-ray reflectometry. Detailed magnetic-moment density profile of as-deposited as well as annealed multilayer sample has been determined by polarized neutron reflectometry measurements, which was used to determine the magnetic nature of the alloy layers. The results show formation of nonmagnetic alloy layers at the interfaces on annealing. From the Bragg-peak intensities of x-ray reflectivity and polarized neutron reflectivity measurements, we have estimated the diffusion lengths after annealing at 300?°C and 400?°C.

Surendra Singh; Saibal Basu; Pramod Bhatt; A. K. Poswal

2009-05-28T23:59:59.000Z

350

Applications of holography to x-ray imaging  

SciTech Connect

In this paper we consider various applications of holographic techniques to the problem of soft x-ray imaging. We give special attention to imaging biological material using x-rays in the wavelength range 24 to 45A. We describe some experiments on formation and reconstruction of x-ray holograms and propose some ways in which holographic techniques might contribute to the difficult problem of fabricating optical elements for use in the soft x-ray region.

Howells, M.; Iarocci, M.; Kenney, J.; Rarback, H.; Rosser, R.; Yun, W.

1985-03-01T23:59:59.000Z

351

Applications of holography to X-ray imaging  

SciTech Connect

In this paper the authors consider various applications of holographic techniques to the problem of soft x-ray imaging. Special attention is given to imaging biological material using x-rays in the wavelength range 24-45A. The authors describe some experiments on formation and reconstruction of x-ray holograms and propose some ways in which holographic techniques might contribute to the difficult problem of fabricating optical elements for use in the soft x-ray region.

Howells, M.; Iarocci, M.; Kenney, J.; Rarback, H.; Rosser, R.; Yun, W.

1985-01-01T23:59:59.000Z

352

X-ray MicroCT Training Presentation  

E-Print Network (OSTI)

X-ray MicroCT Training Presentation T. Fettah Kosar, PhD Center for Nanoscale Systems Harvard) Model: HMXST225 (max. 225 kV) #12;Overview 3 Introduction to X-ray imaging and Computed Tomography (CT) · What are X-rays and how do we generate and image them? · How do we magnify X-ray images and keep them

353

Kaonic hydrogen X-ray measurement in SIDDHARTA  

E-Print Network (OSTI)

Kaonic hydrogen atoms provide a unique laboratory to probe the kaon-nucleon strong interaction at the energy threshold, allowing an investigation of the interplay between spontaneous and explicit chiral symmetry breaking in low-energy QCD. The SIDDHARTA Collaboration has measured the $K$-series X rays of kaonic hydrogen atoms at the DA$\\Phi$NE electron-positron collider of Laboratori Nazionali di Frascati, and has determined the most precise values of the strong-interaction induced shift and width of the $1s$ atomic energy level. This result provides vital constraints on the theoretical description of the low-energy $\\bar{K}N$ interaction.

M. Bazzi; G. Beer; L. Bombelli; A. M. Bragadireanu; M. Cargnelli; G. Corradi; C. Curceanu; A. d'Uffizi; C. Fiorini; T. Frizzi; F. Ghio; C. Guaraldo; R. S. Hayano; M. Iliescu; T. Ishiwatari; M. Iwasaki; P. Kienle; P. Levi Sandri; A. Longoni; V. Lucherini; J. Marton; S. Okada; D. Pietreanu; T. Ponta; A. Rizzo; A. Romero Vidal; A. Scordo; H. Shi; D. L. Sirghi; F. Sirghi; H. Tatsuno; A. Tudorache; V. Tudorache; O. Vazquez Doce; E. Widmann; J. Zmeskal

2012-01-23T23:59:59.000Z

354

X-ray tomography system to investigate granular materials during mechanical loading  

E-Print Network (OSTI)

We integrate a small and portable medical x-ray device with mechanical testing equipment to enable in-situ, non-invasive measurements of a granular material's response to mechanical loading. We employ an orthopedic C-arm as the x-ray source and detector to image samples mounted in the materials tester. We discuss the design of a custom rotation stage, which allows for sample rotation and tomographic reconstruction under applied compressive stress. We then discuss the calibration of the system for 3d computed tomography, as well as the subsequent image reconstruction process. Using this system to reconstruct packings of 3d-printed particles, we resolve packing features with 0.52 mm resolution in a (60 mm)$^3$ field of view. By analyzing the performance bounds of the system, we demonstrate that the reconstructions exhibit only moderate noise.

Athanasios G Athanassiadis; Patrick J. La Rivière; Emil Sidky; Charles Pelizzari; Xiaochuan Pan; Heinrich M. Jaeger

2014-06-11T23:59:59.000Z

355

X-ray Photoelectron Spectroscopy Studies of Oxidized and Reduced CeO?(111) Surfaces  

SciTech Connect

We have studied the electronic structure of oxidized and reduced CeO? (111) surfaces using X-ray photoelectron spectroscopy (XPS). The 50 nm thick Co?(111) film was grown on a YSZ(111) substrate using oxygen plasma assisted molecular beam epitaxy (OPA-MBE). This film has been characterized using in-situ RHEED (reflection high energy electron diffraction) and ex-situ XRD (X-ray diffraction), HRTEM (high resolution transmission electron microscopy) and RBS (Rutherford backscattering spectroscopy). The lattice mismatch between CeO?(111) and YSZ(111) is less than 5% and yields a flat surface that is comprised of an equivalent number of Ce?? and O?? ions. Oxidation with O? at 773 K under UHV conditions was sufficient to fully oxidize the CeO?(111). Surface reduction was carried out by annealing in UHV at 973 K.

Engelhard, Mark H.; Azad, Samina; Peden, Charles HF; Thevuthasan, Suntharampillai

2004-12-01T23:59:59.000Z

356

X-ray Microscopy and Imaging: 2-BM  

NLE Websites -- All DOE Office Websites (Extended Search)

BM BM Introduction The 2-BM beamline offers measurement capabilities for x-ray microtomography, x-ray topography and x-ray microdiffraction. X-ray microtomography and x-ray diffraction instruments are installed on separate optical tables for independent operation with fast switch over time. Optically-coupled high-resolution CCD system is used for microtomography and topography with up to 1 micron spatial resolution. X-ray microdiffraction setup consists of KB microfocussing mirrors (~3 micron minimum spot), four-circle Huber diffractometer, high-precision translation sample stage, two orthogonally-mounted video cameras for viewing sample, fluorescence detector (Si-drift diode) and diffraction detector (a scintillation detector or a CCD). Three different levels of monochromaticity are available. Conventional monochromatic x-rays from a double-bounced Si (111) crystal monochromator (DCM, D E/E=1E-4), wide band-pass monochromatic x-rays from a double multilayer monochromator (DMM, D E/E=1~4E-2) and pink beam. The available x-ray range is from 5 keV to 30 keV. The lower limit is due to the x-ray windows and the upper limit is due to the critical angle of the x-ray mirror. Two different coatings (Cr and Pt) for the x-ray mirror allow either 20 keV or 30 keV energy cutoff.

357

Improvement of YOHKOH Hard X-Ray Imaging  

Science Journals Connector (OSTI)

......Figure la shows the X-ray penetration rate through a single, 0.5 mm...index Fig. 1. (a) X-ray penetration rate through a single tung- sten...the K-escape. (b) X-ray penetration rates averaged over the HXT M2 and......

Jun Sato; Takeo Kosugi; Kazuo Makishima

1999-02-01T23:59:59.000Z

358

Small Angle X-ray Scattering (SAXS) Laboratory Learning Experiences  

E-Print Network (OSTI)

.A. & Svergun D.I. (1987). Structure Analysis by Small-Angle X-Ray and Neutron Scattering. NY: Plenum PressSmall Angle X-ray Scattering (SAXS) Laboratory Learning Experiences o - Use of small angle X-ray scattering instrumentation o - Programs that you will use SAXS (BRUKER AXS) PRIMUS (Konarev, Volkov, Koch

Meagher, Mary

359

X-ray Diffraction Laboratory Department of Chemistry  

E-Print Network (OSTI)

X-ray Diffraction Laboratory Department of Chemistry Texas A & M University College Station, Texas Phone : 979-845-9125 www.chem.tamu.edu/xray xray@tamu.edu X-rayDiffractionLaboratory DepartmentofChemistry 3255TAMU CollegeStation,TX77843-3255 Mission The purpose of our laboratory is to provide X-ray

Meagher, Mary

360

X-ray Diffraction Practicals 1 Graphics Programs  

E-Print Network (OSTI)

X-ray Diffraction Practicals 1 Graphics Programs that will read SHELX or CIF files J. Reibenspies, N. Bhuvanesh ver 1.0.0 #12;X-ray Diffraction Practicals 2 Free software. Gretep : Reads SHELX files shelx files or output thermal ellipsoid plots. http://www.umass.edu/microbio/rasmol/ #12;X-ray

Meagher, Mary

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

X-ray Emission from Massive Stars David Cohen  

E-Print Network (OSTI)

X-ray Emission from Massive Stars David Cohen Department of Physics and Astronomy Swarthmore University, Oct. 13, 2005 astro.swarthmore.edu/~cohen/ #12;Outline 1. What you need to know: a. X-rays from the Sun - magnetic activity, x-ray spectra b. Hot stars c. Radiation-driven winds and the Doppler shift d

Cohen, David

362

X-Ray Photoelectron Spectroscopy XPS Mark Engelhard  

E-Print Network (OSTI)

X-Ray Photoelectron Spectroscopy XPS Mark Engelhard 1 #12;EMSL XPS Instrumentation 2 Physical Electronics Quantera XPS High Energy Resolution Focused X-ray Beam Capability Catalysis reaction and processing chamber with inert atmosphere glove box connected to a PHI Quantera Scanning X-ray Microprobe

363

X-ray power and yield measurements at the refurbished Z machine  

Science Journals Connector (OSTI)

Advancements have been made in the diagnostic techniques to measure accurately the total radiated x-ray yield and power from z-pinch implosion experiments at the Z machine with high accuracy. The Z machine is capable of outputting 2 MJ and 330 TW of x-ray yield and power and accurately measuring these quantities is imperative. We will describe work over the past several years which include the development of new diagnostics improvements to existing diagnostics and implementation of automated data analysis routines. A set of experiments on the Z machine were conducted in which the load and machine configuration were held constant. During this shot series it was observed that the total z-pinch x-ray emission power determined from the two common techniques for inferring the x-ray power a Kimfol filtered x-ray diode diagnostic and the total power and energy diagnostic gave 449 TW and 323 TW respectively. Our analysis shows the latter to be the more accurate interpretation. More broadly the comparison demonstrates the necessity to consider spectral response and field of view when inferring x-ray powers from z-pinch sources.

2014-01-01T23:59:59.000Z

364

Generation of first hard X-ray pulse at Tsinghua Thomson Scattering X-ray Source  

SciTech Connect

Tsinghua Thomson Scattering X-ray Source (TTX) is the first-of-its-kind dedicated hard X-ray source in China based on the Thomson scattering between a terawatt ultrashort laser and relativistic electron beams. In this paper, we report the experimental generation and characterization of the first hard X-ray pulses (51.7 keV) via head-on collision of an 800 nm laser and 46.7 MeV electron beams. The measured yield is 1.0 Multiplication-Sign 10{sup 6} per pulse with an electron bunch charge of 200 pC and laser pulse energy of 300 mJ. The angular intensity distribution and energy spectra of the X-ray pulse are measured with an electron-multiplying charge-coupled device using a CsI scintillator and silicon attenuators. These measurements agree well with theoretical and simulation predictions. An imaging test using the X-ray pulse at the TTX is also presented.

Du Yingchao; Yan Lixin; Hua Jianfei; Du Qiang; Zhang Zhen; Li Renkai; Qian Houjun; Huang Wenhui; Chen Huaibi; Tang Chuanxiang [Accelerator Laboratory, Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Key Laboratory of Particle and Radiation Imaging, Tsinghua University, Ministry of Education, Beijing 100084 (China); Key Laboratory of High Energy Radiation Imaging Fundamental Science for National Defense, Tsinghua University, Beijing 100084 (China)

2013-05-15T23:59:59.000Z

365

New reactor dedicated to in operando studies of model catalysts by means of surface x-ray diffraction and grazing incidence small angle x-ray scattering  

SciTech Connect

A new experimental setup has been developed to enable in situ studies of catalyst surfaces during chemical reactions by means of surface x-ray diffraction (SXRD) and grazing incidence small angle x-ray scattering. The x-ray reactor chamber was designed for both ultrahigh-vacuum (UHV) and reactive gas environments. A laser beam heating of the sample was implemented; the sample temperature reaches 1100 K in UHV and 600 K in the presence of reactive gases. The reactor equipment allows dynamical observations of the surface with various, perfectly mixed gases at controlled partial pressures. It can run in two modes: as a bath reactor in the pressure range of 1-1000 mbars and as a continuous flow cell for pressure lower than 10{sup -3} mbar. The reactor is connected to an UHV preparation chamber also equipped with low energy electron diffraction and Auger spectroscopy. This setup is thus perfectly well suited to extend in situ studies to more complex surfaces, such as epitaxial films or supported nanoparticles. It offers the possibility to follow the chemically induced changes of the morphology, the structure, the composition, and growth processes of the model catalyst surface during exposure to reactive gases. As an example the Pd{sub 8}Ni{sub 92}(110) surface structure was followed by SXRD under a few millibars of hydrogen and during butadiene hydrogenation while the reaction was monitored by quadrupole mass spectrometry. This experiment evidenced the great sensitivity of the diffracted intensity to the subtle interaction between the surface atoms and the gas molecules.

Saint-Lager, M.-C.; Bailly, A.; Dolle, P.; Baudoing-Savois, R.; Taunier, P.; Garaudee, S.; Cuccaro, S.; Douillet, S.; Geaymond, O.; Perroux, G.; Tissot, O.; Micha, J.-S.; Ulrich, O.; Rieutord, F. [Institut Neel, CNRS and Universite Joseph Fourier, BP 166, F-38042 Grenoble Cedex 9 (France); CEA/DRFMC, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France)

2007-08-15T23:59:59.000Z

366

The Role of Surface X-ray Scattering in Electrocatalysis  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 N. M. Markovi , LBNL and C. A. Lucas, University of Liverpool Ecological and political realities have moved discussions of, and advances in, fuel cell technology into mainstream public awareness. Electrocatalysis, the science of modifying the overall rates of electrochemical reactions so that selectivity, yield and efficiency are maximized, is the work from which those advances spring. Studies in electrocatalysis have resulted in highly selective multicomponent gas mixture sensors, human blood component sensors, new electrocatalysts for oxidation/reduction of inorganic and organic pollutants in air and water, as well as better electrocatalysts for the fuel cell conversion of renewable and fossil fuels to electrical work. Studies of the mechanisms by which these catalysts operate have been advanced through development of in-situ surface x-ray scattering (SXS) techniques. SXS capabilities at SSRL were recently used to investigate the interface structure of an ultrathin COad (adsorbed carbon monoxide) overlayer on platinum. This work has elevated the macroscopic description of the COad state at the solid-liquid interface to a microscopic level and enabled the relation between the reactivity and the interfacial structure of COad/Pt to be understood.

367

Investigation of white etching layers on rails by optical microscopy, electron microscopy, X-ray and synchrotron X-ray diffraction  

Science Journals Connector (OSTI)

Patches of white etching layers on rail surfaces were investigated using sophisticated techniques like cross-sectional transmission electron microscopy (XTEM) and synchroton X-ray diffraction. Optical microscopy failed to resolve the microstructure, but in the TEM submicron grains with high dislocation densities and occasional twins, which are characteristic features of high carbon martensite, were observed. The martensitic structure was confirmed by evaluation of synchroton X-ray diffraction line profiles. The latter technique also allowed to determine dislocation densities of the order of 1012 cm?2 and residual compressive stresses of about 200 MPa.

W. Österle; H. Rooch; A. Pyzalla; L. Wang

2001-01-01T23:59:59.000Z

368

Demonstration of Successful X-ray Thomson Scattering Using Picosecond K-(alpha) X-ray Sources for the Characterization of Dense Heated Matter  

SciTech Connect

We discuss the first successful K-{alpha} x-ray Thomson scattering experiment from solid density plasmas for use as a diagnostic in determining the temperature, density, and ionization state of warm dense matter with picosecond resolution. The development of this source as a diagnostic and stringent requirements for successful K-{alpha} x-ray Thomson scattering are addressed. Data for the experimental techniques described in this paper [1] suggest the capability of single shot characterization of warm dense matter and the ability to use this scattering source at future Free Electron Lasers (FEL) where comparable scattering signal levels are predicted.

Kritcher, A; Neumayer, P; Lee, H J; Doeppner, T; Falcone, R; Glenzer, S; Morse, E C

2008-05-05T23:59:59.000Z

369

Calibrating X-ray Imaging Devices for Accurate Intensity Measurement  

SciTech Connect

The purpose of the project presented is to develop methods to accurately calibrate X-ray imaging devices. The approach was to develop X-ray source systems suitable for this endeavor and to develop methods to calibrate solid state detectors to measure source intensity. NSTec X-ray sources used for the absolute calibration of cameras are described, as well as the method of calibrating the source by calibrating the detectors. The work resulted in calibration measurements for several types of X-ray cameras. X-ray camera calibration measured efficiency and efficiency variation over the CCD. Camera types calibrated include: CCD, CID, back thinned (back illuminated), front illuminated.

Haugh, M. J.

2011-07-28T23:59:59.000Z

370

Novel Approaches to Soft X-ray Spectroscopy: Scanning TransmissionX-ray Microscopy and Ambient Pressure X-Ray PhotoelectronSpectroscopy  

SciTech Connect

This workshop focused on novel spectroscopies at Beamlines 11.0.2, 5.3.2 and 9.3.2 at the ALS. The workshop brought together users from a wide range of fields to highlight recent experimental and technical developments both in scanning transmission X-ray spectroscopy (STXM) and ambient pressure photoelectron spectroscopy (APPES). The morning session featured talks on experiments involving new developments at the STXM, while the afternoon session was devoted to those using APXPS. In the morning session, Tolek Tyliszczak discussed the improved detector developments at the STXM, such as an avalanche photodiode detector and fluorescence and electron detection, as well as the continued development of in situ cells for heating, gas flow, and electrochemical cells. Of these, only the avalanche photodiode in combination with a novel multichannel photon-counting system is in routine use in time-resolved studies. Bartel Van Waeyenberge (Ghent University) presented results of magnetic imaging with a time resolution of 70-100 ps combined with a lateral resolution of 20-40 nm performed with the STXM (Beamline 11.0.2). As a complement to the time-domain ''pump-and-probe'' measurements, they developed a frequency-domain ''sine-excitation'' technique in order to study specific eigenmodes of these ferromagnetic patterns with high spatial resolution. This new approach was used to study the gyrotropic vortex motions in micron-sized ferromagnetic patterns. Adam Hitchcock (McMaster University) presented the development, in collaboration with Daniel Guay (INRS, Varennes) and Sherry Zhang, of the apparatus and techniques for applying STXM to in-situ studies of electrochemistry, in particular electrochromism in polyaniline. In addition, substantial progress was reported on a joint project to develop substrates and methods for chemically selective lithography of multilayer polymer systems. Selective patterns, such as that displayed in the figure, can now be written efficiently with the bend magnet STXM on Beamline 5.3.2. Yves Acremann (SSRL) discussed time and spatially resolved X-ray magnetic circular dichroism (XMCD) experiments on spin transfer devices at the STXM (Beamline 11.0.2). These elegant experiments explore time resolved measurements of the magnetization dynamics within a 100 x 150 nm sample influenced by a spin-polarized current. This experiment shows that the magnetization in these magnetic nanostructures are not uniform, as they are influenced by the Oersted field of the charge current needed to generate the spin current. The implementation of a novel multichannel photon counting system in combination with an avalanche photon detector decreased the data-acquisition time by a factor of 10, owing to its ability to resolve the structure of multi bunch mode. Gordon E. Brown, Jr. (Stanford University and SSRL) described ''Applications of STXM to Microbial Bioweathering and Biomineralization''. In the interaction of bacteria with ferrihydrite nanoparticles, microenvironments that were very different than the bulk material were observed, showing that bulk thermodynamics may not be useful for predicting micro phases. Gordon also presented work showing that iron nanoparticles are attracted to the negatively charged bacteria and form a coating that reduces iron oxide minerals. The afternoon session started with presentations by Simon Mun and Hendrik Bluhm, who discussed the current status and the future plans for the two APPES end-stations at the ALS, which are located at Beamlines 9.3.2 and 11.0.2, respectively. In both end-stations, samples can be measured in gaseous environments at pressures of up to several Torr, which makes possible the investigation of numerous phenomena, in particular in the fields of atmospheric and environmental science as well as heterogeneous catalysis. Specific examples of the application of APPES were shown in the following presentations. John Hemminger (University of California, Irvine) reported on APPES investigations at Beamlines 9.3.2 and 11.0.2 of the interaction of alkali halide surfaces with water. The m

Bluhm, Hendrik; Gilles, Mary K.; Mun, Simon B.; Tyliszczak, Tolek

2006-02-01T23:59:59.000Z

371

X-Ray Imaging Crystal Spectrometer for Extended X-Ray Sources  

SciTech Connect

Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokamak fusion experiment to provide spatially and temporally resolved data on plasma parameters such as ion temperature, toroidal and poloidal rotation, electron temperature, impurity ion charge-state distributions, and impurity transport. The imaging properties of these spherically or toroidally curved crystals provide both spectrally and spatially resolved X-ray data from the plasma using only one small spherically or toroidally curved crystal, thus eliminating the requirement for a large array of crystal spectrometers and the need to cross-calibrate the various crystals.

Bitter, Manfred L.; Fraekel, Benjamin; Gorman, James L.; Hill, Kenneth W.; Roquemore, Lane A.; Stodiek, Wolfgang; Goeler, Schweickhard von

1999-05-01T23:59:59.000Z

372

X-Ray Source Based on the Parametric X-Rays  

E-Print Network (OSTI)

Prospects of parametric x-rays (PXR) application for the development of a tuneable quasi-monochromatic x-ray source for medical imaging are discussed. Analysis of basic requirements for electron accelerator shows that it must be relatively low-energy and high-current linac. In comparison with known ultra-relativistic cases, at low energies PXR properties will be modified to a great extent by multiple scattering of the electrons. PXR intensity dependence on target thickness and beam energy are calculated taking multiple scattering into account. It is concluded that PXR source based on real medical accelerators is feasible and can provide x-ray flux needful for obtaining high quality medical images.

Alexander Lobko; Olga Lugovskaya

2005-09-02T23:59:59.000Z

373

Determining the effect of seawater on the interfacial strength of an interlayer E-glass-graphite/epoxy composite using observations of transverse cracking made in-situ in an environmental SEM  

E-Print Network (OSTI)

DETERMINING THE EFFECT OF SEAWATER ON THE INTERFACIAL STRENGTH OF AN INTERLAYER K-GLASS-GRAPHITE/EPOXY COMPOSITE USING OBSERVATIONS OF TRANSVERSE CRACKING MADE IN-SITU IN AN ENVIRONMENTAL SEM A Thesis by CATHERINE ANN WOOD Submitted... OF AN INTERLAYER E-GLASS-GRAPHITE/EPOXY COMPOSITE USING OBSERVATIONS OF TRANSVERSE CRACKING MADE IN-SITU IN AN ENVIRONMENTAL SEM A Thesis by CATHERINE ANN WOOD Submitted to Texas A&M University in partial fulfillment of the requirements for the degree...

Wood, Catherine Ann

2012-06-07T23:59:59.000Z

374

Apparatus for monitoring X-ray beam alignment  

DOE Patents (OSTI)

A self-contained, hand-held apparatus is provided for minitoring alignment of an X-ray beam in an instrument employing an X-ray source. The apparatus includes a transducer assembly containing a photoresistor for providing a range of electrical signals responsive to a range of X-ray beam intensities from the X-ray beam being aligned. A circuit, powered by a 7.5 VDC power supply and containing an audio frequency pulse generator whose frequency varies with the resistance of the photoresistor, is provided for generating a range of audible sounds. A portion of the audible range corresponds to low X-ray beam intensity. Another portion of the audible range corresponds to high X-ray beam intensity. The transducer assembly may include an a photoresistor, a thin layer of X-ray fluorescent material, and a filter layer transparent to X-rays but opaque to visible light. X-rays from the beam undergoing alignment penetrate the filter layer and excite the layer of fluorescent material. The light emitted from the fluorescent material alters the resistance of the photoresistor which is in the electrical circuit including the audio pulse generator and a speaker. In employing the apparatus, the X-ray beam is aligned to a complete alignment by adjusting the X-ray beam to produce an audible sound of the maximum frequency.

Steinmeyer, Peter A. (Arvada, CO)

1991-10-08T23:59:59.000Z

375

Hard X-ray tails and cyclotron features in X-ray pulsars  

E-Print Network (OSTI)

We review the physical processes occurring in the magnetosphere of accreting X-ray pulsars, with emphasis on those processes that give rise to observable effects in their high (E>10 keV) energy spectra. In the second part we compare the empirical spectral laws used to fit the observed spectra with theoretical models, at the light of the BeppoSAX results on the broad-band characterization of the X-ray pulsar continuum, and the discovery of new (multiple) cyclotron resonance features.

Mauro Orlandini; Daniele Dal Fiume

2001-07-27T23:59:59.000Z

376

The constellation X-ray mission  

Science Journals Connector (OSTI)

The Constellation-X mission is a large collecting area X-ray facility emphasizing observations at high spectral resolution (E/?E?300–3000) while covering a broad energy band (0.25–40 keV). This mission will achieve a factor of 100 increased sensitivity over current capabilities and is optimized to observe the effects of extreme gravity close to black holes and test models for the formation of large scale structure in the Universe. It is apart of NASA’s strategic plan for launch towards the end of the first decade of the 21st century.

N. E. White; H. Tananbaum

2001-01-01T23:59:59.000Z

377

13 - X-ray and Neutron Scattering  

Science Journals Connector (OSTI)

Abstract This chapter describes the use of neutrons and X-rays as probes in the study of structural and dynamic properties of metallic materials. Crystalline materials are characterized by their diffraction peaks related to their average crystallographic structure. In real crystals, locally displaced atoms and chemically (or isotopically for neutrons) different species may lead not only to changes of peak shapes and positions, but also to additional (diffuse) scattering between Bragg peak, including scattering around the primary beam (small-angle scattering). All these features can be used to extract information about the state of a sample, its compositional and structural variations on a scale depending on the scattering, in static and time-resolved kinetic studies. Energy-resolved scattering also offers an insight into solid-state dynamics on a microscopic scale. Some of the most important methods will be described and illustrated by instructive examples. The presentation offers a combined view of neutron and X-ray scattering, with the necessary simplifications dictated by space limitations. The special properties of thermal neutrons and of hard X-rays (now widely available at synchrotron radiation sources), their mutual combination, and combinations with other methods, in particular electron microscopy, offer ample opportunity to better understand and control materials properties. After a brief introduction to scattering from real crystals and some general ideas about long-range strains and Bragg peaks, the vicinity of Bragg peaks (displacement scattering at large scattering angles), the scattering far away from Bragg peaks (chemical heterogeneities, short-range order), and, in greater detail, small-angle scattering (which is not sensitive to the extent of crystallinity, but to nanoscale variations of chemical composition and of magnetization, precipitation) will be described, along with classical and more recent applications related to short-range ordering and precipitation in bulk and nanostructured alloys. Some other fields are only briefly addressed (grazing-incidence studies of surfaces, radiography, absorption spectroscopies, coherent X-rays). The final section offers some information on the influence of defects on lattice dynamics and on (slow) diffusive motion in materials.

Gernot Kostorz

2014-01-01T23:59:59.000Z

378

On the microstructure of nanoporous gold: an x-ray diffraction study  

SciTech Connect

The evolution of the grain structure, internal stresses, and the lattice misorientations of nanoporous gold (npAu) during dealloying of bulk (3D) Ag-Au alloy samples was studied by various in-situ and ex-situ X-ray diffraction techniques including powder and Laue diffraction. The experiments reveal that the dealloying process preserves the original crystallographic structure, but leads to a small spread in orientations within individual grains. Furthermore, most grains develop in-plane tensile stress. The feature size of the developing nanoporous structure increases with increasing dealloying time.

Van Petegem, S; Brandstetter, S; Maa?, R; Schmitt, B; Borca, C; Van Swygenhoven, H; Hodge, A M; El-Dasher, B S; Biener, J

2008-08-26T23:59:59.000Z

379

RYLLA. [X-ray transport code  

SciTech Connect

This paper describes a computer code, RYLLA, which models the deposition of x-rays into thin metal slabs, and transports the resulting photoelectrons, finding the distribution of electrons leaving the slab from both the front and back surfaces. The slab must be homogeneous, but can contain a mixture of up to 5 different elements. Due to the short electron mean free path at low electron energies, RYLLA should be used only for studying thin slabs, roughly < 100 mg/cm/sup 2/ for low Z metals, and < 10 mg/cm/sup 2/ for high Z metals. X-ray energies should be in the range of 1 to 150 keV, as they are deposited only via photoionization and Compton scattering processes. Following photoionization, a hole exists in the electron cloud of the absorbing atom. This fills either by Auger or fluoresence, resulting in lower energy holes which are also filled. Fluoresence photons are transported and absorbed in the same manner as the primary photons, except that they are isotropically produced. Once all photons have been transported and absorbed, and all holes have been filled, a space- and energy-dependent electron source spectrum has been obtained. This is used in a discrete ordinate expansion solution of the 1-D transport equation, which gives the output electron spectra at the two slab surfaces. This paper discusses both the physics and coding of RYLLA. Examples of user input are given, as are some comparisons with other codes.

Hyde, R.A.

1983-06-08T23:59:59.000Z

380

X-Ray Diffraction on NIF  

SciTech Connect

The National Ignition Facility (NIF) is currently a 192 beam, 1.6 MJ laser. NIF Ramp-Compression Experiments have already made the relevant exo-planet pressure range from 1 to 50 Mbar accessible. We Proposed to Study Carbon Phases by X-Ray Diffraction on NIF. Just a few years ago, ultra-high pressure phase diagrams for materials were very 'simple'. New experiments and theories point out surprising and decidedly complex behavior at the highest pressures considered. High pressures phases of aluminum are also predicted to be complex. Recent metadynamics survey of carbon proposed a dynamic pathway among multiple phases. We need to develop diagnostics and techniques to explore this new regime of highly compressed matter science. X-Ray Diffraction - Understand the phase diagram/EOS/strength/texture of materials to 10's of Mbar. Strategy and physics goals: (1) Powder diffraction; (2) Begin with diamond; (3) Continue with metals etc.; (4) Explore phase diagrams; (5) Develop liquid diffraction; and (6) Reduce background/improve resolution.

Eggert, J H; Wark, J

2012-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Critical opalescence points to thermodynamic instability: relevance to small-angle X-ray scattering of resorcinol-formaldehyde gel formation at low pH  

Science Journals Connector (OSTI)

In situ small-angle X-ray scattering exhibits a non-monotonic evolution during the formation of resorcinol-formaldehyde gels. The data can be analyzed in terms of critical fluctuations, which points to a reaction-induced phase separation process.

Gommes, C.J.

2008-06-06T23:59:59.000Z

382

THREE-DIMENSIONAL IMAGING OF NANOSCALE MATERIALS BY UISNG COHERENT X-RAYS  

SciTech Connect

X-ray crystallography is currently the primary methodology used to determine the 3D structure of materials and macromolecules. However, many nanostructures, disordered materials, biomaterials, hybrid materials and biological specimens are noncrystalline and, hence, their structures are not accessible by X-ray crystallography. Probing these structures therefore requires the employment of different approaches. A very promising technique currently under rapid development is X-ray diffraction microscopy (or lensless imaging), in which the coherent X-ray diffraction pattern of a noncrystalline specimen is measured and then directly phased to obtain a high-resolution image. Through the DOE support over the past three years, we have applied X-ray diffraction microscopy to quantitative imaging of GaN quantum dot particles, and revealed the internal GaN-Ga2O3 core shell structure in three dimensions. By exploiting the abrupt change in the scattering cross-section near electronic resonances, we carried out the first experimental demonstration of resonant X-ray diffraction microscopy for element specific imaging. We performed nondestructive and quantitative imaging of buried Bi structures inside a Si crystal by directly phasing coherent X-ray diffraction patterns acquired below and above the Bi M5 edge. We have also applied X-ray diffraction microscopy to nondestructive imaging of mineral crystals inside biological composite materials - intramuscular fish bone - at the nanometer scale resolution. We identified mineral crystals in collagen fibrils at different stages of mineralization and proposed a dynamic mechanism to account for the nucleation and growth of mineral crystals in the collagen matrix. In addition, we have also discovered a novel 3D imaging modality, denoted ankylography, which allows for complete 3D structure determination without the necessity of sample titling or scanning. We showed that when the diffraction pattern of a finite object is sampled at a sufficiently fine scale on the Ewald sphere, the 3D structure of the object is determined by the 2D spherical pattern. We confirmed the theoretical analysis by performing 3D numerical reconstructions of a sodium silicate glass structure at 2 Ã? resolution from a 2D spherical diffraction pattern alone. As X-ray free electron lasers are under rapid development worldwide, ankylography may open up a new horizon to obtain the 3D structure of a non-crystalline specimen from a single pulse and allow time-resolved 3D structure determination of disordered materials.

Jianwei Miao

2011-04-18T23:59:59.000Z

383

Band alignment of HfO{sub 2}/Al{sub 0.25}Ga{sub 0.75}N determined by x-ray photoelectron spectroscopy: Effect of SiH{sub 4} surface treatment  

SciTech Connect

The band-alignment of atomic layer deposited (ALD)-HfO{sub 2}/Al{sub 0.25}Ga{sub 0.75}N was studied by high resolution x-ray photoelectron spectroscopy measurements for both the non-passivated and SiH{sub 4} passivated AlGaN surfaces. The valence band offset and the conduction band offset for the ALD-HfO{sub 2}/Al{sub 0.25}Ga{sub 0.75}N interface were found to be 0.43?eV and 1.47?eV, respectively, for the non-passivated sample, and 0.59?eV and 1.31?eV, respectively, for the SiH{sub 4}-passivated sample. The difference in the band alignment is dominated by the band bending or band shift in the AlGaN substrate as a result of the different interlayers formed by the two surface preparations.

Samuel Owen, Man Hon, E-mail: m.owen.sg@ieee.org, E-mail: yeo@ieee.org; Amin Bhuiyan, Maruf; Zhou, Qian; Yeo, Yee-Chia, E-mail: m.owen.sg@ieee.org, E-mail: yeo@ieee.org [Department of Electrical and Computer Engineering, National University of Singapore, Singapore 119260 (Singapore); Zhang, Zheng; Sheng Pan, Ji [Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

2014-03-03T23:59:59.000Z

384

Development of procedures for refurbishing x-ray optics at the Advanced Light Source  

E-Print Network (OSTI)

Development of procedures for refurbishing x-ray optics atpractical and robust procedures for refurbishing x-ray

Yashchuk, Valeriy V.

2013-01-01T23:59:59.000Z

385

The X-ray Scaling Properties of Virialized Systems  

E-Print Network (OSTI)

Virialized systems, such as clusters and groups of galaxies, represent an ideal laboratory for investigating the formation and evolution of structure on the largest scales. Furthermore, the properties of the gaseous intracluster medium provide key insights into the influence of important non-gravitational processes like energy injection and radiative cooling, resulting from feedback associated with star formation, for example. We have assembled a very large X-ray sample of virialized systems, spanning over two decades in halo mass. Each object has high-quality X-ray data available, enabling a full deprojection analysis to be made; for a subsample we have additionally determined the deprojected optical light distribution. We find clear evidence of a departure from the simple expectations of self-similarity. The intracluster medium is more spatially extended and systematically less dense in smaller haloes, and there is evidence of an entropy excess in the hot gas. Our results favour a significant role for both non-gravitational heating and radiative cooling in modifying the properties of this gas, although we find no clear evidence of significantly enhanced star formation efficiency in groups.

Alastair J. R. Sanderson; Trevor J. Ponman

2003-03-17T23:59:59.000Z

386

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

SciTech Connect

The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

2007-08-01T23:59:59.000Z

387

Study of the correlation between the coal calorific value and coal ash content using X-ray fluorescence analysis  

Science Journals Connector (OSTI)

In this paper we have studied the possibility of determining the chemical elements in coal samples using X-ray fluorescence analysis and have found a relationship between the coal calorific value and its ash cont...

D. Bolortuya; P. Zuzaan; M. V. Gustova…

2013-12-01T23:59:59.000Z

388

X-ray power density spectra of black hole binaries : a new deadtime model for the RXTE PCA  

E-Print Network (OSTI)

The power density spectrum is an essential tool for determining the frequency content of X-ray radiation from astronomical sources. For neutron star systems, power density spectra reveal coherent oscillations for those ...

Wei, Dennis

2006-01-01T23:59:59.000Z

389

Assessment of the possibilities of the dual-energy X-ray absorptiometry of multicomponent samples with variable content  

Science Journals Connector (OSTI)

Possibility of the employment of a linear coupling equation of mass attenuation coefficients for two energies for the density determination by dual-energy X-ray absorptiometry of multicomponent samples with varia...

N. A. Antropov; D. A. Karpov; Yu. Yu. Kryuchkov

2012-09-01T23:59:59.000Z

390

A new method for nondestructive evaluation of solid wood moisture content based on dual-energy X-ray absorptiometry  

Science Journals Connector (OSTI)

This paper presents a new method to determine the moisture content of solid wood based on the principle of dual-energy X-ray absorptiometry. The study investigates the ... obtained equation is proposed to calcula...

Takashi Tanaka; Yasuo Kawai

2013-11-01T23:59:59.000Z

391

Characterization of atmospheric aerosols using Synchroton radiation total reflection X-ray fluorescence and Fe K-edge total reflection X-ray fluorescence-X-ray absorption near-edge structure  

Science Journals Connector (OSTI)

In this study a new procedure using Synchrotron total reflection X-ray fluorescence (SR-TXRF) to characterize elemental amounts in atmospheric aerosols down to particle sizes of 0.015 um is presented. The procedure was thoroughly evaluated regarding bounce off effects and blank values. Additionally the potential of total reflection X-ray fluorescence–X-ray absorption near edge structure (SR-TXRF-XANES) for speciation of FeII/III down to amounts of 34 pg in aerosols which were collected for 1 h is shown. The aerosols were collected in the city of Hamburg with a low pressure Berner impactor on Si carriers covered with silicone over time periods of 60 and 20 min each. The particles were collected in four and ten size fractions of 10.0–8.0 ?m, 8.0–2.0 ?m, 2.0–0.13 ?m 0.13–0.015 ?m (aerodynamic particle size) and 15–30 nm, 30–60 nm, 60–130 nm, 130–250 nm, 250–500 nm, 0.5–1 ?m, 1–2 ?m, 2–4 ?m, 4–8 ?m, 8–16 ?m. Prior to the sampling “bounce off” effects on Silicone and Vaseline coated Si carriers were studied with total reflection X-ray fluorescence. According to the results silicone coated carriers were chosen for the analysis. Additionally, blank levels originating from the sampling device and the calibration procedure were studied. Blank levels of Fe corresponded to 1–10% of Fe in the aerosol samples. Blank levels stemming from the internal standard were found to be negligible. The results from the Synchroton radiation total reflection X-ray fluorescence analysis of the aerosols showed that 20 min of sampling time gave still enough sample material for elemental determination of most elements. For the determination of the oxidation state of Fe in the aerosols different Fe salts were prepared as a reference from suspensions in isopropanol. The results from the Fe K-edge Synchroton radiation total reflection X-ray fluorescence-X-ray absorption near-edge structure analysis of the aerosol samples showed that mainly Fe(III) was present in all particle size fractions.

U.E.A. Fittschen; F. Meirer; C. Streli; P. Wobrauschek; J. Thiele; G. Falkenberg; G. Pepponi

2008-01-01T23:59:59.000Z

392

Chemical selective microstructural analysis of thin film using resonant x-ray reflectivity  

SciTech Connect

Strong modulations of the reflected x-ray intensities near the respective absorption edges of the constituent materials promise to determine layer composition of thin film structures along with spectroscopic like information. Near the absorption edge, the orders of magnitude more contrast beyond the pure electron density distributions of materials find an approach to overcome the low density difficulty of the conventional x-ray reflectivity technique. These aspects are explained by experimental studies on partially decomposed boron nitride thin films. Chemical composition profile is determined from free surface to the embedded buried layer with depth resolution in nanometer scale. The results of resonant reflectivity for chemical analysis are correlated with depth dependent x-ray photo electron spectroscopy.

Nayak, Maheswar; Lodha, G. S. [X-ray Optics Section, Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore 452013, Madhya Pradesh (India)

2013-07-14T23:59:59.000Z

393

In Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes  

E-Print Network (OSTI)

Division, Argonne National Laboratory, Argonne, Illinois 60439, USA b Department of Nuclear Science and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, USA We investigated the underlying

Yildiz, Bilge

394

In situ laser heating and radial synchrotron X-ray diffraction in a diamond anvil cell  

E-Print Network (OSTI)

Texture development in halite - comparison of taylor modeland texture development in halite polycrystals: comparisonbeen documented in isostructural halite, where a strong cube

Kunz, Martin; Caldwell, Wendel A.; Miyagi, Lowell; Wenk, Hans-Rudolf

2007-01-01T23:59:59.000Z

395

Gas cell for in situ soft X-ray transmission-absorption spectroscopy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Rev. Sci. Instrum. 85, 074103 (2014) DOI: 10.10631.4890816 1.4890816.figures.online.f1 Abstract: A simple gas cell design, constructed primarily from commercially available...

396

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

E-Print Network (OSTI)

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state ...

Lu, Yi-chun

397

In Situ Electrochemical X-ray Absorption Spectroscopy of Oxygen Reduction Electrocatalysis with High Oxygen Flux  

E-Print Network (OSTI)

to the widespread application of fuel cells and air-cathode batteries in automotive and stationary power a progressive evolution of the electronic structure of the metal clusters that is both potential) and the large overpotential (300 mV) in fuel cell cathodes necessitate the use of high loadings of precious-metal

Frenkel, Anatoly

398

Photon Sciences | Beamlines | IXS: Inelastic X-ray Scattering  

NLE Websites -- All DOE Office Websites (Extended Search)

IXS: Inelastic X-ray Scattering IXS: Inelastic X-ray Scattering Poster | Fact Sheet | Preliminary Design Report Scientific Scope Many hot topics related to the high frequency dynamics of condensed matter require both a narrower and steeper resolution function and access to a broader dynamic range than what are currently available. This represents a sort of "no man's land" that falls right in the dynamic gap lying between the high frequency spectroscopies, such as inelastic x-ray scattering (IXS), and the low frequency ones. New IXS spectrometers with improved energy and momentum resolutions would be required to fill this gap. To achieve this goal, a new x-ray optics concept for both the monochromatization and energy analysis of x-rays will be implemented at the NSLS-II Inelastic X-ray Scattering beamline. This solution exploits the

399

X-Ray Fluorescence (XRF) | Open Energy Information  

Open Energy Info (EERE)

X-Ray Fluorescence (XRF) X-Ray Fluorescence (XRF) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: X-Ray Fluorescence (XRF) Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Rock Lab Analysis Parent Exploration Technique: Rock Lab Analysis Information Provided by Technique Lithology: Bulk and trace element analysis of rocks, minerals, and sediments. Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png X-Ray Fluorescence (XRF): X-Ray Fluorescence is a lab-based technique used for bulk chemical analysis of rock, mineral, sediment, and fluid samples. The technique depends on the fundamental principles of x-ray interactions with solid materials, similar

400

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Print Biological Imaging by Soft X-Ray Diffraction Microscopy Print Electron and x-ray microscopes are a valuable tool for both the life and materials sciences, but they are limited in their ability to image with nanometer-scale resolution in three dimensions nonperiodic objects that are several microns in size. To fill this gap, the technique of coherent x-ray diffraction imaging now under development takes advantage of the penetrating power of x rays while simultaneously removing the limitations imposed by lens-based optical systems. Researchers from Stony Brook University, in collaboration with scientists at the ALS and Cornell University, have taken a large step in this direction by using a lensless x-ray diffraction microscope to image a freeze-dried yeast cell to better than 30-nm resolution. Images were made at several angular orientations of the cell.

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

APS 7-BM Beamline: X-Ray Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

Useful Websites Useful Websites X-Ray Interactions with Matter from CRXO at LBNL. Intuitive interface for x-ray transmission and reflectivity for a wide range of materials. X-Ray Data Booklet from LBNL. Slightly outdated in places, but many useful tables of edge energies, fluorescence lines, and crystal lattice spacings. NIST XCOM Database. Powerful database of photoelectric absorption, elastic scattering, and Compton scattering cross-sections for a wide range of materials. X-Ray Server. Maintained by Sergey Stepanov at GMCA at the APS, this website has several powerful calculators for simulating x-ray reflection and diffraction. Software X-Ray Oriented Programs (XOP). This program, written by scientists at the ESRF and APS, is widely used in the synchrotron research community.

402

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Print Biological Imaging by Soft X-Ray Diffraction Microscopy Print Electron and x-ray microscopes are a valuable tool for both the life and materials sciences, but they are limited in their ability to image with nanometer-scale resolution in three dimensions nonperiodic objects that are several microns in size. To fill this gap, the technique of coherent x-ray diffraction imaging now under development takes advantage of the penetrating power of x rays while simultaneously removing the limitations imposed by lens-based optical systems. Researchers from Stony Brook University, in collaboration with scientists at the ALS and Cornell University, have taken a large step in this direction by using a lensless x-ray diffraction microscope to image a freeze-dried yeast cell to better than 30-nm resolution. Images were made at several angular orientations of the cell.

403

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Print Biological Imaging by Soft X-Ray Diffraction Microscopy Print Electron and x-ray microscopes are a valuable tool for both the life and materials sciences, but they are limited in their ability to image with nanometer-scale resolution in three dimensions nonperiodic objects that are several microns in size. To fill this gap, the technique of coherent x-ray diffraction imaging now under development takes advantage of the penetrating power of x rays while simultaneously removing the limitations imposed by lens-based optical systems. Researchers from Stony Brook University, in collaboration with scientists at the ALS and Cornell University, have taken a large step in this direction by using a lensless x-ray diffraction microscope to image a freeze-dried yeast cell to better than 30-nm resolution. Images were made at several angular orientations of the cell.

404

X-Ray Diffraction (XRD) | Open Energy Information  

Open Energy Info (EERE)

X-Ray Diffraction (XRD) X-Ray Diffraction (XRD) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: X-Ray Diffraction (XRD) Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Rock Lab Analysis Parent Exploration Technique: Rock Lab Analysis Information Provided by Technique Lithology: Rapid and unambiguous identification of unknown minerals.[1] Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png X-Ray Diffraction (XRD): X-Ray Diffraction (XRD) is a laboratory-based technique commonly used for identification of crystalline materials and analysis of unit cell dimensions. One of two primary types of XRD analysis (X-ray powder diffraction and single-crystal XRD) is commonly applied to samples to

405

Density gradient free electron collisionally excited X-ray laser  

DOE Patents (OSTI)

An operational X-ray laser (30) is provided that amplifies 3p-3s transition X-ray radiation along an approximately linear path. The X-ray laser (30) is driven by a high power optical laser. The driving line focused optical laser beam (32) illuminates a free-standing thin foil (34) that may be associated with a substrate (36) for improved structural integrity. This illumination produces a generally cylindrically shaped plasma having an essentially uniform electron density and temperature, that exists over a long period of time, and provides the X-ray laser gain medium. The X-ray laser (30) may be driven by more than one optical laser beam (32, 44). The X-ray laser (30) has been successfully demonstrated to function in a series of experimental tests.

Campbell, Edward M. (Pleasanton, CA); Rosen, Mordecai D. (Berkeley, CA)

1989-01-01T23:59:59.000Z

406

Density gradient free electron collisionally excited x-ray laser  

DOE Patents (OSTI)

An operational x-ray laser is provided that amplifies 3p-3s transition x-ray radiation along an approximately linear path. The x-ray laser is driven by a high power optical laser. The driving line focused optical laser beam illuminates a free-standing thin foil that may be associated with a substrate for improved structural integrity. This illumination produces a generally cylindrically shaped plasma having an essentially uniform electron density and temperature, that exists over a long period of time, and provides the x-ray laser gain medium. The x-ray laser may be driven by more than one optical laser beam. The x-ray laser has been successfully demonstrated to function in a series of experimental tests.

Campbell, E.M.; Rosen, M.D.

1984-11-29T23:59:59.000Z

407

Formation of microbeam using tabletop soft X-ray laser  

Science Journals Connector (OSTI)

An X-ray microprobe with a sub-micron size beam and high intensity can provide X-ray analyses with a remarkable spatial resolution. We have performed focusing of an X-ray laser output into a sub-micron beam for the first time. In our experiment, an X-ray laser of Li-like Al 3d–4f transition at 15.47 nm was delivered from an unstable cavity consisting of a concave mirror and a flat mirror with a square orifice of 100×100 ?m in size. The beam from the orifice was then focused by using a Schwarzschild mirror coated with a Mo/Si multilayer. An X-ray beam size with a diameter of about 0.45 ?m and an estimated photon number of about 2×106 photons per shot was achieved. Such sources could be well suited for the realization of X-ray microprobes.

Tadayuki Ohchi; Naohiro Yamaguchi; Chiemi Fujikawa; Tamio Hara

1999-01-01T23:59:59.000Z

408

Portable X-Ray Diffraction (XRD) | Open Energy Information  

Open Energy Info (EERE)

Portable X-Ray Diffraction (XRD) Portable X-Ray Diffraction (XRD) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Portable X-Ray Diffraction (XRD) Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Data Collection and Mapping Parent Exploration Technique: Data Collection and Mapping Information Provided by Technique Lithology: Rapid and unambiguous identification of unknown minerals.[1] Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Portable X-Ray Diffraction (XRD): Portable X-Ray Diffraction (XRD) is a field-based technique that can be used for identification of crystalline materials and analysis of unit cell dimensions. Portable XRD analysis is similar to X-ray powder diffraction,

409

Biological Imaging by Soft X-Ray Diffraction Microscopy  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Imaging by Soft X-Ray Diffraction Microscopy Print Biological Imaging by Soft X-Ray Diffraction Microscopy Print Electron and x-ray microscopes are a valuable tool for both the life and materials sciences, but they are limited in their ability to image with nanometer-scale resolution in three dimensions nonperiodic objects that are several microns in size. To fill this gap, the technique of coherent x-ray diffraction imaging now under development takes advantage of the penetrating power of x rays while simultaneously removing the limitations imposed by lens-based optical systems. Researchers from Stony Brook University, in collaboration with scientists at the ALS and Cornell University, have taken a large step in this direction by using a lensless x-ray diffraction microscope to image a freeze-dried yeast cell to better than 30-nm resolution. Images were made at several angular orientations of the cell.

410

X-ray imaging performance of scintillator-filled silicon pore arrays  

SciTech Connect

The need for fine detail visibility in various applications such as dental imaging, mammography, but also neurology and cardiology, is the driver for intensive efforts in the development of new x-ray detectors. The spatial resolution of current scintillator layers is limited by optical diffusion. This limitation can be overcome by a pixelation, which prevents optical photons from crossing the interface between two neighboring pixels. In this work, an array of pores was etched in a silicon wafer with a pixel pitch of 50 {mu}m. A very high aspect ratio was achieved with wall thicknesses of 4-7 {mu}m and pore depths of about 400 {mu}m. Subsequently, the pores were filled with Tl-doped cesium iodide (CsI:Tl) as a scintillator in a special process, which includes powder melting and solidification of the CsI. From the sample geometry and x-ray absorption measurement the pore fill grade was determined to be 75%. The scintillator-filled samples have a circular active area of 16 mm diameter. They are coupled with an optical sensor binned to the same pixel pitch in order to measure the x-ray imaging performance. The x-ray sensitivity, i.e., the light output per absorbed x-ray dose, is found to be only 2.5%-4.5% of a commercial CsI-layer of similar thickness, thus very low. The efficiency of the pores to transport the generated light to the photodiode is estimated to be in the best case 6.5%. The modulation transfer function is 40% at 4 lp/mm and 10%-20% at 8 lp/mm. It is limited most likely by the optical gap between scintillator and sensor and by K-escape quanta. The detective quantum efficiency (DQE) is determined at different beam qualities and dose settings. The maximum DQE(0) is 0.28, while the x-ray absorption with the given thickness and fill factor is 0.57. High Swank noise is suspected to be the reason, mainly caused by optical scatter inside the CsI-filled pores. The results are compared to Monte Carlo simulations of the photon transport inside the pore array structure. In addition, some x-ray images of technical and anatomical phantoms are shown. This work shows that scintillator-filled pore arrays can provide x-ray imaging with high spatial resolution, but are not suitable in their current state for most of the applications in medical imaging, where increasing the x-ray doses cannot be tolerated.

Simon, Matthias; Engel, Klaus Juergen; Menser, Bernd; Badel, Xavier; Linnros, Jan [Philips Research Europe, Weisshausstr. 2, 52080 Aachen (Germany); Royal Institute of Technology, Electrum 229, 16440 Kista (Sweden)

2008-03-15T23:59:59.000Z

411

Investigation of near-infrared spectroscopy for periodic in situ cell culture media determination of glucose and lactate  

E-Print Network (OSTI)

, biosensors must be developed that are capable of monitoring the cell culture processes non-invasively and continuously. Non-invasive determinations of glucose and lactate in cell culture media were investigated via near-infrared spectroscopy (NIR) across...

Lewis, Christopher Bryan

2012-06-07T23:59:59.000Z

412

X-ray Pinhole Camera Measurements  

SciTech Connect

The rod pinch diode is made up of a cathode plate and a small diameter anode rod that extends through the cathode hole. The anode is charged positively. The rod tip is made of a high-z material which is chosen for its bremsstrahlung efficiency. When the diode is pulsed it produces an intense x-ray source used for pulsed radiography. The baseline or reference diode consists of a 0.75 mm diameter Tungsten (W) tapered anode rod which extends 10 mm through a 9 mm diameter 3 mm thick aluminum (Al) aperture. The majority of the current in the electron beam is created on the edges of the cathode aperture and when properly configured, the electrons will self insulate, travel down the extension of the rod, and pinch onto the tip of the rod. In this presentation, performance of hybrid diodes will be compared with the baseline diode.

Nelson, D. S. [NSTec; Berninger, M. J. [NSTec; Flores, P. A. [NSTec; Good, D. E. [NSTec; Henderson, D. J. [NSTec; Hogge, K. W. [NSTec; Huber, S. R. [NSTec; Lutz, S. S. [NSTec; Mitchell, S. E. [NSTec; Howe, R. A. [NSTec; Mitton, C. V. [NSTec; Molina, I. [NSTec; Bozman, D. R. [SNL; Cordova, S. R. [SNL; Mitchell, D. R. [SNL; Oliver, B. V. [SNL; Ormond, E. C. [SNL

2013-06-20T23:59:59.000Z

413

Gray scale x-ray mask  

DOE Patents (OSTI)

The present invention describes a method for fabricating an embossing tool or an x-ray mask tool, providing microstructures that smoothly vary in height from point-to-point in etched substrates, i.e., structure which can vary in all three dimensions. The process uses a lithographic technique to transfer an image pattern in the surface of a silicon wafer by exposing and developing the resist and then etching the silicon substrate. Importantly, the photoresist is variably exposed so that when developed some of the resist layer remains. The remaining undeveloped resist acts as an etchant barrier to the reactive plasma used to etch the silicon substrate and therefore provides the ability etch structures of variable depths.

Morales, Alfredo M. (Livermore, CA); Gonzales, Marcela (Seattle, WA)

2006-03-07T23:59:59.000Z

414

Nonlinear optics with focused x-ray lasers  

SciTech Connect

We have investigated the possibility of focusing x-ray lasers with the use of multilayered mirrors or zone plates. The results indicate that x-ray intensities as high as 10{sup 14} W/cm{sup 2} can be achieved by focusing saturated Ne-like x-ray lasers. These intensities should be adequate for studying nonlinear optical phenomena. 9 refs., 2 figs.

DaSilva, L.B.; Muendel, M.H.; Falcone, R.W.; Fields, D.J.; Kortright, J.B.; MacGowan, B.J.; Matthews, D.L.; Mrowka, S.; Shimkaveg, G.M.; Trebes, J.E.

1990-12-12T23:59:59.000Z

415

Process and device for x-ray system quality assurance  

SciTech Connect

This invention relates to medical radiography test systems, and more particularly to a method and apparatus for providing evaluation of a medical or dental x-ray system consisting of x-ray generator, film and processor on a daily basis and to thereby assure the production of useful radiographs from the system with no need to repeat patient exposure because of problems with the x-ray system.

Van Pelt, W.F.; Peterson, R.W.

1982-11-10T23:59:59.000Z

416

The first X-ray diffraction measurements on Mars  

Science Journals Connector (OSTI)

The X-ray diffraction/X-ray fluorescence instrument CheMin on the Curiosity rover is a shoebox-sized device using transmission geometry and an energy-discriminating CCD detector. The instrument has returned the first X-ray diffraction data for soil and drilled samples from Mars outcrops, revealing a suite of primary basaltic minerals, amorphous components and varied hydrous alteration products including phyllosilicates.

Bish, D.

2014-10-21T23:59:59.000Z

417

On X-Ray Waveguiding in Nanochannels: Channeling Formalism  

E-Print Network (OSTI)

The question on X-ray extreme focusing (smallest reachable spot size) brings us to the idea for using the wave features of X-ray propagation in media. As known, wave features are revealed at propagation in ultra-narrow collimators as well as at glancing reflection from smooth flat and/or strongly curved surfaces. All these phenomena can be described within the general formalism of X-ray channeling.

S. B. Dabagov

2006-11-20T23:59:59.000Z

418

THE GEODESIC X-RAY TRANSFORM WITH FOLD CAUSTICS The ...  

E-Print Network (OSTI)

Aug 28, 2012 ... THE GEODESIC X-RAY TRANSFORM WITH FOLD CAUSTICS. PLAMEN STEFANOV AND GUNTHER UHLMANN. ABSTRACT. We give a ...

2012-08-28T23:59:59.000Z

419

Inelastic X-ray and Nuclear Resonant Scattering  

NLE Websites -- All DOE Office Websites (Extended Search)

... Search About User Information News & Events Science & Education Beamlines Divisions Argonne Home > Advanced Photon Source > Inelastic X-ray and Nuclear Resonant Scattering...

420

Advances in X-Ray Diagnostics of Diesel Fuel Sprays  

Energy.gov (U.S. Department of Energy (DOE))

Recent advances in high-speed X-ray imaging has shown several distinct behaviors of commercial fuel injectors that cannot be seen with more conventional techniques.

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

New intraoral x-ray fluorographic imaging for dentistry  

SciTech Connect

A new dental x-ray fluorographic unit has been developed. This unit is composed of small intraoral x-ray tube, a compact x-ray image intensifier, and a high-resolution TV system. The purposes for developing this equipment were to (1) directly observe the tooth during endodontic procedures and (2) reduce x-ray exposure to the patient and the dentist. The radiation exposure can be reduced to about 1/600 the exposure used with conventional dental film. In clinical trials, a satisfactory fluorographic dental image for endodontic treatment was obtained with this new device.

Higashi, T.; Osada, T.; Aoyama, W.; Iguchi, M.; Suzuki, S.; Kanno, M.; Moriya, K.; Yoshimura, M.; Tusuda, M.

1983-06-01T23:59:59.000Z

422

Normal incidence x-ray mirror for chemical microanalysis  

DOE Patents (OSTI)

An x-ray mirror for both electron column instruments and micro x-ray fluorescence instruments for making chemical, microanalysis comprises a non-planar mirror having, for example, a spherical reflecting surface for x-rays comprised of a predetermined number of alternating layers of high atomic number material and low atomic number material contiguously formed on a substrate and whose layers have a thickness which is a multiple of the wavelength being reflected. For electron column instruments, the wavelengths of interest lie above 1.5nm, while for x-ray fluorescence instruments, the range of interest is below 0.2nm. 4 figs.

Carr, M.J.; Romig, A.D. Jr.

1987-08-05T23:59:59.000Z

423

Self-terminating diffraction gates femtosecond X-ray nanocrystallograp...  

NLE Websites -- All DOE Office Websites (Extended Search)

Self-terminating diffraction gates femtosecond X-ray nanocrystallography measurements Authors: Barty, A., Caleman, C., Aquila, A., Timneanu, N., Lomb, L., White, T. A., Andreasson,...

424

High intensity x-ray source using liquid gallium target  

DOE Patents (OSTI)

A high intensity x-ray source that uses a flowing stream of liquid gallium as a target with the electron beam impinging directly on the liquid metal.

Smither, Robert K. (Hinsdale, IL); Knapp, Gordon S. (Cupertino, CA); Westbrook, Edwin M. (Chicago, IL); Forster, George A. (Westmont, IL)

1990-01-01T23:59:59.000Z

425

X-ray Diffuse Scattering Measurements of Nucleation Dynamics...  

NLE Websites -- All DOE Office Websites (Extended Search)

X-ray Diffuse Scattering Measurements of Nucleation Dynamics at Femtosecond Resolution Real-time measurement and control of the non-equilibrium properties of materials represents...

426

XRMS: X-Ray Spectroscopy of Magnetic Solids  

NLE Websites -- All DOE Office Websites (Extended Search)

XRMS: X-Ray Spectroscopy of Magnetic Solids October 22-23, 2011 SLAC National Accelerator Laboratory, Menlo Park, CA More information...

427

X-ray absorption fine structure and magnetization characterization...  

NLE Websites -- All DOE Office Websites (Extended Search)

characterization of the metallic Co component in Co-doped ZnO thin films . X-ray absorption fine structure and magnetization characterization of the metallic Co...

428

Wet etching of GaAs using synchrotron radiation x rays  

Science Journals Connector (OSTI)

The results of room-temperature wet etching of GaAs using synchrotron-radiation x rays are described. Under x-rayillumination etching occurs on the n- GaAs surface in contact with an acid or base solution or even deionized water. The etching process is studied as functions of the electrolytes their concentration semiconductor doping level and x-ray intensity and energy. The etching mechanism is determined to be primarily electrochemical in nature but the x-ray radiation chemistry plays a role in the etching. Smoothly etchedsurfaces are achievable with a root-mean-square surface roughness of 0.7–2.0 nm. We also found that the etching rate increases substantially with the ratio of the sample size to the x-ray exposure size. This is accounted for by the rate-limiting effect on the charge transfer across the semiconductor-electrolyte junction. The chemistry of etchedsurfaces is studied using x-ray photoelectron spectroscopy and compared to that of as-received surfaces.

Qing Ma; Nicolaie Moldovan; Derrick C. Mancini; Richard A. Rosenberg

2001-01-01T23:59:59.000Z

429

Improved backscatter x-ray detection for anti-terrorist applications  

SciTech Connect

Currently the most common method to determine the contents of a package suspected of containing an explosive device is to use transmission radiography. This technique requires that an x-ray source and film be placed on opposite sides of the package. This poses a problem if the package is placed so that only one side is accessible, such as against a wall. There is also a threat to personnel and property since explosive devices may be booby trapped. The authors have developed a method to x-ray a package using backscattered x-rays based on similar work for landmine detection. This procedure eliminates the use of film behind the target. All of the detection is done from the same side as the source. Backscatter experiments at Sandia National Laboratories have been conducted on mock bombs in packages. They are able to readily identify the bomb components. The images that are obtained in this procedure are done in real time and the image is displayed on a computer screen. Preliminary experiments have also imaged objects within or behind a wall. They are currently using a scanning x-ray source and scintillating plastic detectors. It can take several hours to image a briefcase size object. This time could be reduced if better x-ray detection methods could be used. They have looked at using pinhole photography and CCD cameras to reduce this time.

Shope, S.L.; Lockwood, G.J.; Selph, M.M.; Wehlburg, J.C.

1999-12-01T23:59:59.000Z

430

The origins of X-ray emission from the hotspots of FRII radio sources  

E-Print Network (OSTI)

We use new and archival Chandra data to investigate the X-ray emission from a large sample of compact hotspots of FRII radio galaxies and quasars from the 3C catalogue. We find that only the most luminous hotspots tend to be in good agreement with the predictions of a synchrotron self-Compton model with equipartition magnetic fields. At low hotspot luminosities inverse-Compton predictions are routinely exceeded by several orders of magnitude, but this is never seen in more luminous hotspots. We argue that an additional synchrotron component of the X-ray emission is present in low-luminosity hotspots, and that the hotspot luminosity controls the ability of a given hotspot to produce synchrotron X-rays, probably by determining the high-energy cutoff of the electron energy spectrum. It remains plausible that all hotspots are close to the equipartition condition.

M. J. Hardcastle; D. E. Harris; D. M. Worrall; M. Birkinshaw

2004-06-22T23:59:59.000Z

431

High-energy x-ray diffractometer for nondestructive strain depth profile measurement  

SciTech Connect

We describe a lab-based high-energy x-ray diffraction system and a new approach to nondestructively measuring strain profiles in polycrystalline samples. This technique utilizes the tungsten K{sub ?1} characteristic radiation from a standard industrial x-ray tube. We introduce a simulation model that is used to determine strain values from data collected with this system. Examples of depth profiling are shown for shot peened aluminum and titanium samples. Profiles to 1 mm depth in aluminum and 300 ?m depth in titanium with a depth resolution of 20 ?m are presented.

Al-Shorman, M. Y. [Department of Physics, Yarmouk University, 21163 Irbid (Jordan)] [Department of Physics, Yarmouk University, 21163 Irbid (Jordan); Jensen, T. C.; Gray, J. N. [Center for Nondestructive Evaluation, Iowa State University, Ames, Iowa 50011 (United States)] [Center for Nondestructive Evaluation, Iowa State University, Ames, Iowa 50011 (United States)

2013-12-15T23:59:59.000Z

432

Optical identification of hard X-ray source IGRJ18257-0707  

E-Print Network (OSTI)

We present the results of the optical identification of hard X-ray source IGRJ18257-0707 trough the spectroscopic observations of its optical counterpart with RTT150 telescope. Accurate position of the X-ray source, determined using Chandra observations, allowed us to associate this source with the faint optical object (m_R=~20.4), which shows broad H_\\alpha emission line in its optical spectrum. Therefore we conclude that the source IGRJ18257-0707 is a type 1 Seyfert galaxy at redshift z=0.037.

R. A. Burenin; I. F. Bikmaev; M. G. Revnivtsev; J. A. Tomsick; S. Yu. Sazonov; M. N. Pavlinskiy; R. A. Sunyaev

2008-10-14T23:59:59.000Z

433

Soft x-ray imaging for spheromak-like plasmas (abstract)  

Science Journals Connector (OSTI)

A pinhole soft x-rayimagingcamera is being developed for use on the Caltech solar prominence simulation experiment and also the Caltech spheromak experiment. The camera is based upon a commercial gated intensifier which produces an image on a phosphor screen. Moderate signal level excellent time resolution and reasonable imaging have been obtained but there has not been any determination of the x-ray energy spectrum. An estimation of the spectrum is now underway using filtered AXUV diodes and it is expected that knowledge of the x-ray energy will enable further optimization of the camera.

P. M. Bellan; J. F. Hansen; S. Zweben; D. Stutman

2001-01-01T23:59:59.000Z

434

Energy Dispersive X-ray Fluorescence Analysis of Sulfur in Biomass  

Science Journals Connector (OSTI)

An energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method was developed to analyze low ppm level sulfur (S) in biomass feedstocks and in subsequent residues from pretreatment reactions. ... Representative biomass feedstocks and pretreatment residues were analyzed for S. ... The goal of this project was to determine whether an energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method is effective in conducting sulfur analysis of woody biomass feedstocks at an appropriately useful sensitivity, especially when used to effectively monitor the extent of sulfur removal after biomass pretreatment reactions. ...

J. Michael Robinson; Staci R. Barrett; Kevin Nhoy; Rajesh K. Pandey; Joseph Phillips; Oscar M. Ramirez; Richard I. Rodriguez

2009-03-06T23:59:59.000Z

435

X-RAY FLUORESCENCE ANALYSIS OF HANFORD LOW ACTIVITY WASTE SIMULANTS METHOD DEVELOPMENT  

SciTech Connect

The x-ray fluorescence laboratory (XRF) in the Analytical Development Directorate (ADD) of the Savannah River National Laboratory (SRNL) was requested to develop an x-ray fluorescence spectrometry method for elemental characterization of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) pretreated low activity waste (LAW) stream to the LAW Vitrification Plant. The WTP is evaluating the potential for using XRF as a rapid turnaround technique to support LAW product compliance and glass former batching. The overall objective of this task was to develop an XRF analytical method that provides rapid turnaround time (<8 hours), while providing sufficient accuracy and precision to determine variations in waste.

Jurgensen, A; David Missimer, D; Ronny Rutherford, R

2007-08-08T23:59:59.000Z

436

X-ray laser system, x-ray laser and method  

DOE Patents (OSTI)

Disclosed is an x-ray laser system comprising a laser containing generating means for emitting short wave length radiation, and means external to said laser for energizing said generating means, wherein when the laser is in an operative mode emitting radiation, the radiation has a transverse coherence length to width ratio of from about 0.05 to 1. Also disclosed is a method of adjusting the parameters of the laser to achieve the desired coherence length to laser width ratio.

London, Richard A. (Oakland, CA); Rosen, Mordecai D. (Berkeley, CA); Strauss, Moshe (Omer, IL)

1992-01-01T23:59:59.000Z

437

On the Cooling Tails of Thermonuclear X-ray Bursts: The IGR J17480–2446 Link  

Science Journals Connector (OSTI)

The neutron star transient and 11 Hz X-ray pulsar IGR J17480–2446, recently discovered in the globular cluster Terzan 5, showed unprecedented bursting activity during its 2010 October-November outburst. We analyzed all X-ray bursts detected with the Rossi X-ray Timing Explorer and find strong evidence that they all have a thermonuclear origin, despite the fact that many do not show the canonical spectral softening along the decay imprinted on type I X-ray bursts by the cooling of the neutron star photosphere. We show that the persistent-to-burst power ratio is fully consistent with the accretion-to-thermonuclear efficiency ratio along the whole outburst, as is typical for type I X-ray bursts. The burst energy, peak luminosity, and daily-averaged spectral profiles all evolve smoothly throughout the outburst, in parallel with the persistent (non-burst) luminosity. We also find that the peak-burst to persistent luminosity ratio determines whether or not cooling is present in the bursts from IGR J17480–2446, and argue that the apparent lack of cooling is due to the "non-cooling" bursts having both a lower peak temperature and a higher non-burst (persistent) emission. We conclude that the detection of cooling along the decay is a sufficient, but not a necessary condition to identify an X-ray burst as thermonuclear. Finally, we compare these findings with X-ray bursts from other rapidly accreting neutron stars.

M. Linares; D. Chakrabarty; M. van der Klis

2011-01-01T23:59:59.000Z

438

The crystal structure of the interrupted framework silicate K{sub 9.6}Ca{sub 1.2}Si{sub 12}O{sub 30} determined from laboratory X-ray diffraction data  

SciTech Connect

The crystal structure of a potassium calcium silicate with composition K{sub 9.6}Ca{sub 1.2}Si{sub 12}O{sub 30} (or K{sub 8}CaSi{sub 10}O{sub 25}) has been solved by direct methods aided by distance least squares optimization from laboratory X-ray powder diffraction data. The trigonal compound adopts the non-centrosymmetric space group R3c with the following basic crystallographic data: a=11.13623(5)A, c=21.9890(2)A, V=2361.63(2)A{sup 3}, Z=3, D{sub calc}=2.617gcm{sup -3}. The crystal structure can be classified as an interrupted framework with exclusively Q{sup 3}-units. It can be thought of as being built from layers parallel to (001) containing isolated six-membered tetrahedral rings in UDUDUD conformation. Corner sharing of tetrahedra belonging to adjacent sheets results in a tetrahedral framework. The framework density of the structure is 15.2 T-atoms/1000A{sup 3}. The coordination sequences are identical for both silicon atoms in the asymmetric unit: 3-6-11-20-32-46-60-80-102-122. The vertex symbols for the two tetrahedral centers are 10{sub 2}.10{sub 2}.6{sub 1}. Topologically, the structure can be described as an Archimedean three-dimensional 3-connected net. It can be derived from the diamond or cristobalite net by removing 20% of the knots. Charge compensation in the structure is achieved by the incorporation of mono- and divalent M-cations (M: K, Ca). These extra-framework ions are coordinated by six to nine oxygen ligands. Ca/K distributions for the five symmetrically independent M-sites were obtained from a combination of bond distance considerations, site occupancy refinements and the bulk chemical composition. The structural characterization is completed by a detailed Raman spectroscopic study. Furthermore, possible implications of the structural chemistry of interrupted framework silicates for the field of silicate glass research are addressed.

Kahlenberg, V. [Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck (Austria)]. E-mail: volker.kahlenberg@uibk.ac.at; Kaindl, R. [Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck (Austria); Christian-Doppler-Laboratory for Advanced Hard Coatings at the Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck (Austria); Toebbens, D.M. [Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck (Austria)

2006-07-15T23:59:59.000Z

439

Constraints on jet X-ray emission in low/hard state X-ray binaries  

E-Print Network (OSTI)

We show that the combination of the similarities between the X-ray properties of low luminosity accreting black holes and accreting neutron stars, combined with the differences in their radio properties argues that the X-rays from these systems are unlikely to be formed in the relativistic jets. Specifically, the spectra of extreme island state neutron stars and low/hard state black holes are known to be indistinguishable, while the power spectra from these systems are known to show only minor differences beyond what would be expected from scaling the characteristic variability frequencies by the mass of the compact object. The spectral and temporal similarities thus imply a common emission mechanism that has only minor deviations from having all key parameters scaling linearly with the mass of the compact object, while we show that this is inconsistent with the observations that the radio powers of neutron stars are typically about 30 times lower than those of black holes at the same X-ray luminosity. We also show that an abrupt luminosity change would be expected when a system makes a spectral state transition from a radiatively inefficient jet dominated accretion flow to a thin disk dominated flow, but that such a change is not seen.

Thomas J. Maccarone

2005-03-31T23:59:59.000Z

440

Isotropic star in low-mass X-ray binaries and X-ray pulsars  

E-Print Network (OSTI)

We present a model for compact stars in the low mass X-ray binaries(LMXBs) and X-ray pulsars using a metric given by John J. Matese and Patrick G. Whitman \\citep{Matese and Whitman1980}. Here the field equations are reduced to a system of two algebraic equations considering the isotropic pressure. Compact star candidates 4U 1820-30(radius=10km) in LMXBs, and Her X-1(radius=7.7km), SAX J 1808.4-3658(SS1)(radius=7.07km) and SAX J 1808.4-3658(SS2)(radius=6.35km) in X-ray pulsars satisfy all the energy conditions, TOV-equation and stability condition. From our model, we have derived mass($M$), central density($\\rho_{0}$), suface density($\\rho_{b}$), central pressure($p_{0}$), surface pressure($p_{b}$) and surface red-shift($Z_{s}$) of the above mentioned stars, which are very much consistant with the observed/reported datas\\citep{N. K. Glendenning1997,Gondek2000}. We have also observe the adiabatic index($\\gamma$>4/3) of the above steller objects.

Mehedi Kalam; Sk. Monowar Hossein; Sajahan Molla

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination in-situ x-ray" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Femtosecond x-ray absorption spectroscopy with hard x-ray free electron laser  

SciTech Connect

We have developed a method of dispersive x-ray absorption spectroscopy with a hard x-ray free electron laser (XFEL), generated by a self-amplified spontaneous emission (SASE) mechanism. A transmission grating was utilized for splitting SASE-XFEL light, which has a relatively large bandwidth (?E/E ? 5 × 10{sup ?3}), into several branches. Two primary split beams were introduced into a dispersive spectrometer for measuring signal and reference spectra simultaneously. After normalization, we obtained a Zn K-edge absorption spectrum with a photon-energy range of 210 eV, which is in excellent agreement with that measured by a conventional wavelength-scanning method. From the analysis of the difference spectra, the noise ratio was evaluated to be ?3 × 10{sup ?3}, which is sufficiently small to trace minute changes in transient spectra induced by an ultrafast optical laser. This scheme enables us to perform single-shot, high-accuracy x-ray absorption spectroscopy with femtosecond time resolution.

Katayama, Tetsuo; Togashi, Tadashi; Tono, Kensuke; Kameshima, Takashi [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)] [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Inubushi, Yuichi; Sato, Takahiro; Hatsui, Takaki; Yabashi, Makina [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan)] [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Obara, Yuki; Misawa, Kazuhiko [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588 (Japan)] [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588 (Japan); Bhattacharya, Atanu; Kurahashi, Naoya [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan)] [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Ogi, Yoshihiro [Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan)] [Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan); Suzuki, Toshinori [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan) [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan)

2013-09-23T23:59:59.000Z

442

Burning plasmas with ultrashort soft-x-ray flashing  

SciTech Connect

Fast ignition with narrow-band coherent x-ray pulses has been revisited for cryogenic deuterium-tritium (DT) plasma conditions achieved on the OMEGA Laser System. In contrast to using hard-x-rays (hv = 3-6 keV) proposed in the original x-ray fast-ignition proposal, we find that soft-x-ray sources with hv Almost-Equal-To 500 eV photons can be suitable for igniting the dense DT-plasmas achieved on OMEGA. Two-dimensional radiation-hydrodynamics simulations have identified the break-even conditions for realizing such a 'hybrid' ignition scheme (direct-drive compression with soft-x-ray heating) with 50-{mu}m-offset targets: {approx}10 ps soft-x-ray pulse (hv Almost-Equal-To 500 eV) with a total energy of 500-1000 J to be focused into a 10 {mu}m spot-size. A variety of x-ray pulse parameters have also been investigated for optimization. It is noted that an order of magnitude increase in neutron yield has been predicted even with x-ray energy as low as {approx}50 J. Scaling this idea to a 1 MJ large-scale target, a gain above {approx}30 can be reached with the same soft-x-ray pulse at 1.65 kJ energy. Even though such energetic x-ray sources do not currently exist, we hope that the proposed ignition scheme may stimulate efforts on generating powerful soft-x-ray sources in the near future.

Hu, S. X.; Goncharov, V. N.; Skupsky, S. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States)

2012-07-15T23:59:59.000Z

443

Shining Soft X-rays on Magnetic Structures  

Science Journals Connector (OSTI)

...2) demonstrate the power of x-ray magneto-optics in a synchroton study of single crystalline FePd layers, which provides...2) demonstrate the power of x-ray magneto-optics in a synchroton study of single crystalline FePd layers, which provides detailed...

Ulrich Hillebrecht

1999-06-25T23:59:59.000Z

444

Twelfth National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

Twelfth National School on Neutron and X-ray Scattering June 12 � June 26, 2010 at Argonne National of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang, Suzanne

Pennycook, Steve

445

National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

National School on Neutron and X-ray Scattering May 30 � June 13, 2009 at Argonne National of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang, Suzanne

Pennycook, Steve

446

National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

15th National School on Neutron and X-ray Scattering August 10 - 24, 2013 at Argonne National of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major Ridge National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang

447

Fourteenth National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

Fourteenth National School on Neutron and X-ray Scattering August 12 - 25, 2012 at Argonne National of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major Ridge National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang

Pennycook, Steve

448

Thirteenth National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

Thirteenth National School on Neutron and X-ray Scattering June 11 ­ June 25, 2011 at Argonne of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang, Suzanne

449

Neutron and X-ray Scattering Study of Magnetic Manganites  

E-Print Network (OSTI)

Neutron and X-ray Scattering Study of Magnetic Manganites Graeme Eoin Johnstone A Thesis submitted are performed using a variety of neutron scattering and x-ray scattering techniques. The electronic ground for analysing the results of the polarised neutron scattering experiment. There are a large number of people who

Boothroyd, Andrew

450

Sixteenth National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

Sixteenth National School on Neutron and X-ray Scattering June 14-28, 2014 at Argonne National of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major's Neutron Scattering Science Division. Scientific Directors: Suzanne G.E. te Velthuis, Esen Ercan Alp

Pennycook, Steve

451

Tenth National School on Neutron and X-ray Scattering  

E-Print Network (OSTI)

Tenth National School on Neutron and X-ray Scattering September 24 - October 11, 2008 at Argonne of the National School on Neutron and X-ray Scattering is to educate graduate students on the utilization of major National Laboratory's Neutron Scattering Science Division. Scientific Directors: Jonathan C. Lang, Suzanne

Pennycook, Steve

452

X-ray spectra transmitted through Compton-thick absorbers  

E-Print Network (OSTI)

X-ray spectra transmitted through matter which is optically thick to Compton scattering are computed by means of Monte Carlo simulations. Applications to the BeppoSAX data of the Seyfert 2 galaxy in Circinus, and to the spectral modeling of the Cosmic X-ray Background, are discussed.

Giorgio Matt; Fulvio Pompilio; Fabio La Franca

1999-04-24T23:59:59.000Z

453

Laser Copper Plasma X-ray Source Debris Characterization  

E-Print Network (OSTI)

Laser Copper Plasma X-ray Source Debris Characterization A Thesis Presented by David Hurley 3, 2007 Vice President for Research and Dean of Graduate studies #12;Abstract Laser copper plasma for x-ray lithography. Copper debris in the form of vapor, ions, dust, and high-speed particles

Huston, Dryver R.

454

Millisecond oscillations during thermonuclear X-ray bursts  

E-Print Network (OSTI)

I analyze 68 oscillation trains detected in a search of 159 thermonuclear bursts from eight neutron star X-ray binaries observed with the Rossi X-ray Timing Explorer. I use all data that were public as of September 2001. ...

Muno, Michael Patrick, 1975-

2002-01-01T23:59:59.000Z

455

X rays following the alpha decay of Pa231  

Science Journals Connector (OSTI)

More detailed information is presented concerning the L and K x-ray spectra due to internal conversion of the electromagnetic transitions following the ? decay of Pa231. Some of the difficulties discussed in Ref. 1 are clarified by the new results.[RADIOACTIVITY Pa231; measured L and K Ac x-ray components, ?? and ?XL coin Ac227 deduced levels, ICC.

A. G. de Pinho; L. T. Auler; A. G. da Silva

1974-05-01T23:59:59.000Z

456

Resonant Soft X-Ray Scattering - Combining Structural with Spectroscopic  

NLE Websites -- All DOE Office Websites (Extended Search)

Resonant Soft X-Ray Scattering - Combining Structural with Spectroscopic Resonant Soft X-Ray Scattering - Combining Structural with Spectroscopic Refinement Friday, September 28, 2012 - 10:00am SLAC, Bldg. 137, Room 322 SSRL Presents Kevin Stone X-ray absorption spectroscopy has become an important tool in understanding the electronic structure of materials. Resonant absorption edges in the soft x-ray regime are especially interesting as they allow the study of the lighter elements, such as in organic or organo-metallic substances, as well as important L-edges of the 3d transition metals important in magnetic and oxide systems. Measurements of soft x-ray absorption spectra are inherently surface sensitive, and are plagued by issues such as extinction (in electron yield measurements) or self absorption (in fluorescence yield

457

Incoherent x-ray scattering in single molecule imaging  

E-Print Network (OSTI)

Imaging of the structure of single proteins or other biomolecules with atomic resolution would be enormously beneficial to structural biology. X-ray free-electron lasers generate highly intense and ultrashort x-ray pulses, providing a route towards imaging of single molecules with atomic resolution. The information on molecular structure is encoded in the coherent x-ray scattering signal. In contrast to crystallography there are no Bragg reflections in single molecule imaging, which means the coherent scattering is not enhanced. Consequently, a background signal from incoherent scattering deteriorates the quality of the coherent scattering signal. This background signal cannot be easily eliminated because the spectrum of incoherently scattered photons cannot be resolved by usual scattering detectors. We present an ab initio study of incoherent x-ray scattering from individual carbon atoms, including the electronic radiation damage caused by a highly intense x-ray pulse. We find that the coherent scattering pa...

Slowik, Jan Malte; Dixit, Gopal; Jurek, Zoltan; Santra, Robin

2014-01-01T23:59:59.000Z

458

X-ray intravital microscopy for functional imaging in rat hearts using synchrotron radiation coronary microangiography  

SciTech Connect

An X-ray intravital microscopy technique was developed to enable in vivo visualization of the coronary, cerebral, and pulmonary arteries in rats without exposure of organs and with spatial resolution in the micrometer range and temporal resolution in the millisecond range. We have refined the system continually in terms of the spatial resolution and exposure time. X-rays transmitted through an object are detected by an X-ray direct-conversion type detector, which incorporates an X-ray SATICON pickup tube. The spatial resolution has been improved to 6 {mu}m, yielding sharp images of small arteries. The exposure time has been shortened to around 2 ms using a new rotating-disk X-ray shutter, enabling imaging of beating rat hearts. Quantitative evaluations of the X-ray intravital microscopy technique were extracted from measurements of the smallest-detectable vessel size and detection of the vessel function. The smallest-diameter vessel viewed for measurements is determined primarily by the concentration of iodinated contrast material. The iodine concentration depends on the injection technique. We used ex vivo rat hearts under Langendorff perfusion for accurate evaluation. After the contrast agent is injected into the origin of the aorta in an isolated perfused rat heart, the contrast agent is delivered directly into the coronary arteries with minimum dilution. The vascular internal diameter response of coronary arterial circulation is analyzed to evaluate the vessel function. Small blood vessels of more than about 50 {mu}m diameters were visualized clearly at heart rates of around 300 beats/min. Vasodilation compared to the control was observed quantitatively using drug manipulation. Furthermore, the apparent increase in the number of small vessels with diameters of less than about 50 {mu}m was observed after the vasoactive agents increased the diameters of invisible small blood vessels to visible sizes. This technique is expected to offer the potential for direct investigation of mechanisms of vascular dysfunctions.

Umetani, K. [Japan Synchrotron Radiation Research Institute, SPring-8, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Fukushima, K. [National Cerebral and Cardiovascular Center Hospital, Fujishirodai, Suita-shi, Osaka 565-8565 (Japan)

2013-03-15T23:59:59.000Z

459

X-ray Emission from Massive StarsX-ray Emission from Massive Stars David CohenDavid Cohen  

E-Print Network (OSTI)

X-ray Emission from Massive StarsX-ray Emission from Massive Stars David CohenDavid Cohen/s)Velocity (km/s) #12;absorption emission emission occulted emission emission UV telescope side side front back #12;absorption emission emission occulted emission emission UV telescope side side front back #12;The

Cohen, David

460

Flat panel X-ray detector with reduced internal scattering for improved attenuation accuracy and dynamic range  

DOE Patents (OSTI)

An x-ray detector is disclosed that has had all unnecessary material removed from the x-ray beam path, and all of the remaining material in the beam path made as light and as low in atomic number as possible. The resulting detector is essentially transparent to x-rays and, thus, has greatly reduced internal scatter. The result of this is that x-ray attenuation data measured for the object under examination are much more accurate and have an increased dynamic range. The benefits of this improvement are that beam hardening corrections can be made accurately, that computed tomography reconstructions can be used for quantitative determination of material properties including density and atomic number, and that lower exposures may be possible as a result of the increased dynamic range.

Smith, Peter D. (Santa Fe, NM); Claytor, Thomas N. (White Rock, NM); Berry, Phillip C. (Albuquerque, NM); Hills, Charles R. (Los Alamos, NM)

2010-10-12T23:59:59.000Z

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461

The X-Ray Microcalorimeter Spectrometer for the International X-Ray Observatory  

SciTech Connect

The International X-Ray Observatory (IXO) is under formulation by NASA, ESA and JAXA for deployment in 2022. IXO emerged over the last 18 months as the NASA Constellation-X and ESA/JAXA X-Ray Evolving Universe Spectrometer (XEUS) missions were combined. The driving performance requirements for the X-Ray Microcalorimeter Spectrometer (XMS) are a spectral resolution of 2.5 eV over the central 2'x2' in the 0.3-7.0 keV band, and 10 eV to the edge of the 5'x5' field of view (FOV). The XMS is now based on a microcalorimeter array of Transition-Edge Sensor (TES) thermometers with Au/Bi absorbers and a SQUID MUX readout. One of the concepts studied as part of the mission formulation has a core 40x40 array corresponding to a 2'x2' FOV with 3'' pixels surrounded by an outer, annular 52x52 array of 6'' pixels that extends the field of view to 5.4'x5.4' with better than 10 eV resolution. There are several options for implementing the readout and cooling system of the XMS under study in the US, Europe and Japan. The ADR system will have from two to five stages depending on the performance of the cryocooler. Mechanical coolers with sufficient cooling power at 4K are available now, and {approx}2K coolers are under development. In this paper we give an overview of the XMS instrument, and some of the tradeoffs to be addressed for this observatory instrument.

Kelley, R. L.; Bandler, S. R.; Kilbourne, C. A.; Porter, F. S.; Shirron, P.; Smith, S. J.; Whitehouse, P. [NASA/Goddard Space Flight Center, Greenbelt, MD (United States); Doriese, W. B.; Irwin, K. [National Institute of Standards and Technology, Boulder, CO (United States); Ezoe, Y.; Ishisaki, Y.; Ohashi, T. [Tokyo Metropolitan University, Hachioji, Tokyo (Japan); Fujimoto, R.; Sato, K. [Faculty of Mathematics and Physics, Kanazawa University, Kanazawa (Japan); Gottardi, L.; Hartog, R. den; Herder, J.-W. den; Hoevers, H.; Korte, P. de; Kuur, J. van der [SRON Netherlands Institute for Space Research, Utrecht (Netherlands)] (and others)

2009-12-16T23:59:59.000Z

462

SOFT X-RAY EMISSIONS FROM PLANETS, MOONS, AND COMETS A. Bhardwaj(1)  

E-Print Network (OSTI)

SOFT X-RAY EMISSIONS FROM PLANETS, MOONS, AND COMETS A. Bhardwaj(1) , G. R. Gladstone(2) , R. F to radiate in the soft x-ray energy ( the generation of soft x-rays from these objects, whereas in the hard x-ray energy range (>10 keV) x-rays mainly

Johnson, Robert E.

463

X-ray-induced phase transformation in congruent and vapor-transport-equilibrated lithium tantalate  

E-Print Network (OSTI)

X-ray-induced phase transformation in congruent and vapor-transport-equilibrated lithium tantalate an effect of a partially reversible x-ray-induced increase of diffuse x-ray scattering in both congruent been attributed to x-ray-induced decay of the ferroelectric phase at room temperature. The x-ray

Byer, Robert L.

464

A Hard X-ray View of Accreting X-ray Binary Pulsars  

E-Print Network (OSTI)

The study of the hard (E>10 keV) energy spectra of X-ray binary pulsars can give a wealth of information on the physical processes that occur close to the neutron star surface. Extreme matter regimes are probed, and precious information on how matter and radiation behave and interact in critical conditions can be obtained. We will give an overview on the most recent results obtained by RXTE and BeppoSAX on this class of objects, in order to pass the baton onto just launched experiments, like INTEGRAL, or soon to be launched, like AGILE and ASTRO-E2.

Mauro Orlandini

2004-02-26T23:59:59.000Z

465

Apparatus for generating x-ray holograms  

DOE Patents (OSTI)

Apparatus for x-ray microholography of living biological materials. A Fourier transform holographic configuration is described as being most suitable for the 3-dimensional recording of the physical characteristics of biological specimens. The use of a spherical scatterer as a reference and a charge-coupled device two-dimensional detector array placed in the forward direction relative to the incident x-radiation for viewing electromagnetic radiation simultaneously scattered from both the specimen and the reference scatterer permits the ready reconstruction of the details of the specimen from the fringe pattern detected by the charge-coupled device. For example, by using a nickel reference scatter at 4.5 nm, sufficient reference illumination is provided over a wide enough angle to allow similar resolution in both transverse and longitudinal directions. Both laser and synchrotron radiation sources are feasible for generating microholographs. Operation in the water window (2.4 to 4.5 nm) should provide maximum contrast for features of the specimen and spatial resolution on the order of the wavelength of x-radiation should be possible in all three dimensions, which is sufficient for the visualization of many biological features. It is anticipated that the present apparatus will find utility in other areas as well where mic